9209_Wake_NorthWake_Unlined_MSWLF_April23GW_FID1809293_20230623

North Wake Unlined Landfill
Facility Permit No. 9209-MSWLF-1984
Semi -Annual -Groundwater Sampling Report
(April 2023 Sampling Event)
Wake County
Prepared June 2023
WAKE
COUNTY
NORTH CAROLI NA

Reporting Form
Division o Waste Management - Solid Waste
Notice: for Nrmctio any murnm an n by and e d are Public Records" as General
St m NC32-6). SfaNte 132-1. As such, these tlocumenis are
available for inspection and examina0on by any person upon request (NC General Statute 132E).
Instructions:
Prepare one forth for each individually monitored unit
• Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source. pre-existing
condition, etc.).
Atiaoh a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 138.1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owned:
Consultant - CDM Smith. Inc.
Contact for questions about data formatting. Include data preparers nano, telephone number and E-mail address:
Name: Mathew F. Color Phone: [phone]
E-mail: colonemfAcdmsmtih.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit (.0500 or.1600) Octoher26-24 2I061
aks County -North Wake
Ckn:etl Unlined Landfill
19004 Deponie Drive
Ralegh, North Carolir 27615
9209-MSWLF-
1984
.1600
Aptl145, 2023
Environmental status: (Check all that apply)
InNalteack,round Monitoring ❑X Detection Monitoring Assessment Monitoring ❑X Corrective Action
f data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells Methane gas mentioning data
Groundwater monitoring data from private water supply wells ® Corrective action data (specify) MNA Sampling Results
Leachate monitoring data
Surface water monitanno data n Other(specily)
Nottticaden attached?
No. No groundwater or surface water standards were exceeded.
J( Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analyficai values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
ro me east or my Knowledge, me lntormation reported and statements made on this data submittal and attachments aria true and correct
Furthermore, 1 have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or codification including the possibility of a fine and imprisonment.
Mathew F. Color Consultant [phone]
Affix NC
6400 Glenwood Avenue, Suite 400, Raleigh, North Carolina 27612
I /��.�
Facility Representative Address
(/ 7 p
F-0412
NC PE Firm License Number (If applicable effective May 1, 2009)
Revised
','% 1
82009

Smith
5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: [phone]
June 23, 2023
Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Subject: April 2023 Semi -Annual Groundwater Sampling Report
North Wake Closed Unlined Landfill
Facility Permit Number 9209-MSWLF-1984
Dear Ms. Drummond:
CDM Smith Inc. (CDM Smith), on behalf of Wake County (County), is submitting an electronic copy of the
April 2023 semi-annual sampling event report. This letter report presents the results of the semi-annual
sampling event that was recently completed at the North Wake Closed Unlined Landfill (Site) and
constitutes the first semi-annual sampling event for 2023. The groundwater monitoring network consists
of the following wells: MW-11 (shallow background well), -11d (deep background well), -511, -6, -6d, -7,
-8, -8d, -9, -10, -10d, -22, -23, -23d, -24, -28, -28d, -29d, -30, -31, -31d, -32, -33, -34, -34d, -35, -36, -36d,
TB-1a and TB-1a deep. Surface water sampling locations include SW-2, -3, -7, and -8. Field activities,
sampling results for all wells and surface water locations, an evaluation of the groundwater corrective
action effectiveness, and recommendations are discussed below.
Field Activities
Groundwater and surface water samples from the Site were collected on April 4-5, 2023, except for
MW-22, -24, -30, -31, and TB-1a, which were dry during the April 2023 sampling event. Monitoring well
and surface water sample locations are shown on Figure 1. Construction details for each monitoring well
are summarized in Table 1.
Samples were collected from the monitoring wells by use of a peristaltic pump or disposable, laboratory
decontaminated bailers. Groundwater elevations were measured at each well on April 3, 2023, prior to
sampling using an electronic water level indicator with an accuracy of 0.01 feet and are presented in
Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling
event and are shown on Figure 1. The groundwater elevations and potentiometric contours were also
used to estimate groundwater velocities at each well as presented in Table 2.
WATER+ENVIRONMENT+TRANSPORTATION+ENERGY+FACILITIES ,

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Ms. Jaclynne Drummond
June 23, 2023
Page 2
Alternate Source Demonstration
On August 17, 2020, CDM Smith submitted an Alternate Source Demonstration (ASD) for the Site on
behalf of the County. The purpose of the ASD was to demonstrate that metals exceeding the 15A NCAC
02L .0202 (NC 2L) Groundwater Standards or Interim Maximum Allowable Concentrations (IMAC) are
naturally occurring and not related to a release from the landfill. The ASD was prepared using analytical
data from the background monitoring wells, MW-11 and -11D, that was collected on a quarterly basis
from January 2018 to April 2020 to develop upper tolerance limits (UTLs) for specific analytes that
historically exceeded their respective NC 2L Groundwater Standard or IMAC. Based on statistical
analysis, a UTL of 6 parts per billion (ppb) was proposed for cobalt and a UTL of 23 ppb was proposed for
vanadium. The North Carolina Department of Environmental Quality's Solid Waste Section (SWS)
approved these proposed UTLs on August 17, 2020.
Sampling Results
All groundwater and surface water samples were analyzed by Pace Analytical Services, LLC located in
West Columbia, South Carolina, for North Carolina Appendix I volatile organic compounds (VOCs) plus
dichlorodifluoromethane and Appendix I metals plus mercury. Samples from monitoring wells MW-51R,
-6, -8, -9, -10, -11, -34, -34d, and -36 were also analyzed for natural attenuation parameters (i.e.,
biochemical oxygen demand, chemical oxygen demand, alkalinity, nitrate, chloride, sulfate, sulfide, total
organic carbon, carbon dioxide, methane, ethane, ethene, ferrous iron, volatile fatty acids, and dissolved
hydrogen) per the Corrective Action Plan (CAP) and CAP Addendum that were approved by the SWS in
March 2010 and on June 10, 2019, respectively. Monitoring wells MW-51R, -34, and -34d were also
analyzed for total iron, sodium, and total dissolved solids. The CAP and CAP Addendum are discussed
below.
In a letter dated May 29, 2018, the SWS stated that all groundwater and surface water samples
collected from landfills be analyzed for 1,4-dioxane after July 1, 2018. On June 26, 2019, the SWS
approved the removal of 1,4-dioxane from the sampling program for all monitoring wells and surface
water locations, with the exceptions of MW-6, -8, and -9, due to two non -detect events (October 2018
and April 2019). Samples were collected from the wells requiring the 1,4-dioxane analysis during the
April 2023 sampling event and the analytical results are provided below.
The analytical results were reported to the laboratory specific method detection limit (MDL) and are
quantifiable at or below the laboratory limit of quantitation (LOQ). All monitoring wells for the Site had
detections of analytes above the MDL but below the LOQ that were qualified as estimated or "J" flags.
In samples collected from MW-9, the detection of barium had a "D" flag, indicating that the analyte was
analyzed at a dilution. In samples collected from MW-6, -10, -34, -34d, and -36, detections of nitrate also
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June 23, 2023
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had "D" flags. Additionally, detections of methane in MW-5R and -10 and the detection of iron in MW-
5R had "D" flags.
In samples collected from MW-6d, the detection of methylene chloride had an "H" flag, indicating that
the analyte was analyzed outside of hold time. In samples collected from MW-5R, -6, -8, -9, -10, -11, -34,
-34d, and -36, detections of methane had "B" flags, indicating that the analyte was detected in the
method blank. Samples collected from MW-34 also had a detection of iron with an "S" flag, indicating a
matrix spike/matrix spike duplicate failure.
The following list summarizes which analytes were detected above the LOQ at each sample location.
Underlined analytes exceeded the NC 2L Groundwater Standard, UTL, or 15A NCAC 02B or North
Carolina In -Stream Target Value Surface Water Quality Standard for Class C Waters (NC 2B Surface
Water Standards). No "J" flag detections are listed. A complete summary of all detected and estimated
concentrations from the April 2012 through the April 2023 sampling events is presented in Table 4. The
Laboratory data reports are provided in Appendix A.
MW-11 (Shallow Background)
Metals:
Volatile Organic Compounds:
MW-11d (Deep Background)
Metals:
Volatile Organic Compounds:
MW-5R
Metals:
Volatile Organic Compounds:
Barium
None Detected
Barium
None Detected
Barium, Cobalt, Nickel
None Detected
MW-6
Metals: Barium
Volatile Organic Compounds: 1,4-Dichlorobenzene, 1,1-Dichloroethane
MW-6d
Metals:
Barium
Volatile Organic Compounds: Chloroform, 1,4-Dichlorobenzene, Dichlorodifluoromethane,
1,1-Dichloroethane, cis-1,2-Dichloroethene, Methylene Chloride,
Trichloroethene (TCE), Trichlorofluoromethane
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MW-7
Metals: Barium, Cobalt, Nickel, Zinc
Volatile Organic Compounds: Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene
MW-8
Metals: Barium, Cobalt, Nickel
Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene, cis-1,2-Dichloroethene,
1,4-Dioxane
MW-8d
Metals: Barium
Volatile Organic Compounds: None Detected
MW-9
Metals: Barium, Cadmium, Cobalt, Copper, Lead, Nickel, Thallium, Zinc
Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene,
1,1-Dichloroethane, cis-1,2-Dichloroethene, 1,4-Dioxane, Vinyl Chloride
MW-10
Metals: Barium, Mercury, Zinc
Volatile Organic Compounds: 1,4-Dichloeobenzene, 1,1-Dichloroethane, cis-1,2-Dichloroethene,
Tetra chloroethene (PCE), TCE, Vinyl Chloride
MW-10d
Metals: None Detected
Volatile Organic Compounds: 1,1-Dichloroethane
MW-22
Metals: Dry
Volatile Organic Compounds: Dry
MW-23
Metals: Barium, Lead, Vanadium
Volatile Organic Compounds: None Detected
MW-23d
Metals: Barium
Volatile Organic Compounds: None Detected
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June 23, 2023
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M W-24
Metals: Dry
Volatile Organic Compounds: Dry
MW-28
Metals: Barium, Chromium, Vanadium, Zinc
Volatile Organic Compounds: None Detected
MW-28d
Metals: Barium, Vanadium, Zinc
Volatile Organic Compounds: None Detected
MW-29d
Metals: Barium, Chromium, Copper, Zinc
Volatile Organic Compounds: None Detected
MW-30
Metals: Dry
Volatile Organic Compounds: Dry
MW-31
Metals: Dry
Volatile Organic Compounds: Dry
MW-31 d
Metals: Barium, Zinc
Volatile Organic Compounds: Chloroform
MW-32
Metals: Barium, Beryllium, Copper, Vanadium
Volatile Organic Compounds: Chloroform
TB-1a
Metals: Dry
Volatile Organic Compounds: Dry
TB-1a deep
Metals: Barium, Zinc
Volatile Organic Compounds: Chloroform
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MW-33
Metals: Barium
Volatile Organic Compounds: None Detected
Metals: Barium, Chromium, Zinc
Volatile Organic Compounds: Benzene, 1,4-Dichlorobenzene, Dichlorodifluoromethane,
1,1-Dichloroethane, cis-1,2-Dichloroethene, Methylene Chloride, PCE,
TCE, Trichlorofluoromethane
MW-34d
Metals: Barium, Chromium
Volatile Organic Compounds: 1,1-Dichloroethane, cis-1,2-Dichloroethene
MW-35
Metals: Barium, Zinc
Volatile Organic Compounds: Dichlorodifluoromethane, 1,1-Dichloroethane, cis-1,2-Dichloroethene,
Methylene Chloride, PCE, TCE, Trichlorofluoromethane
MW-36
Metals: Barium, Chromium, Copper, Vanadium
Volatile Organic Compounds: 1,4-Dichlorobenzene, 1,1-Dichloroethane, cis-1,2-Dichloroethene, Vinyl
Chloride
MW-36d
Metals: Barium, Copper, Zinc
Volatile Organic Compounds: 1,1-Dichloroethane, cis-1,2-Dichloroethene
SW-2
Metals: Barium
Volatile Organic Compounds: None Detected
SW-3
Metals: Barium
Volatile Organic Compounds: None Detected
SW-7
Metals: Barium
Volatile Organic Compounds: None Detected
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SW-8
Metals: Barium
Volatile Organic Compounds: None Detected
"J" flags were not included in the previous list, but several sampling locations had "J" flag detections
that exceeded the standards. The "J" flag constituents above the standards along with their location are
listed below:
Antimony: MW-28d and -31d
Bis(2-ethylhexyl) Phthalate: MW-29d
Vinyl Chloride: MW-8
It is likely that the recent and historic detections of chloroform in wells MW-6d, -24, -31, -31d, -32,
TB-1a, and -1a deep are attributed to a release from a municipal water line in the Falls River
development and are not related to a release from the Site.
In a letter dated March 22, 2012, the SWS approved the County's request to discontinue collecting
samples from select wells for herbicide and pesticide analyses during the semi-annual spring sampling
event. However, the SWS requested that MW-29d continue to be sampled for bis(2-ethylhexyl)
phthalate during spring sampling events due to a detection from the March 2011 event. Bis(2-
ethylhexyl) phthalate was detected above the NC 2L Groundwater Standard (3 ppb) at 28.5 ppb in
samples collected from MW-29d during the April 2014 sampling event. A confirmatory sample collected
from MW-29d during the November 2014 sampling event had an estimated detection of bis(2-
ethylhexyl) phthalate at 4.61 ppb, which is above the standard. Bis(2-ethylhexyl) phthalate has been
detected as estimated detections below the NC 2L Groundwater Standard in samples collected from
MW-29d during the 2018, April 2020, and March 2022 events. Bis (2-ethylhexyl) phthalate was detected
as an estimated concentration above the standard in samples collected during the April 2023 event. The
concentration trend for bis(2-ethylhexyl) phthalate in MW-29d will continue to be evaluated.
An equipment blank was analyzed for quality control. A duplicate sample was also collected for quality
control. A trip blank was not analyzed due to an oversight by the sampler. Acetone was detected in the
equipment blank as an estimated concentration below the NC 2L Groundwater Standard. The duplicate
sample, identified as DUP, was collected from MW-6d, and had similar analyte concentrations as those
detected in MW-6d. Table 5 presents a summary of all analytes detected during the April 2023 sampling
event that exceeded the NC 2L Groundwater Standards or UTLs.
Additional metals samples were collected from monitoring wells MW-23, -28, -28d, and -36 during the
April 2023 sampling event for the laboratory to filter and analyze due to elevated turbidity (i.e., greater
than 10 Nephelometric Turbidity Units) at the time samples were collected. In samples collected from
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MW-29d, dissolved antimony was analyzed due to an estimated total antimony detection above the NC
2L Groundwater Standards. Dissolved antimony was also detected in MW-29d as an estimated
concentration above the standard.
Based on qualitative and quantitative evaluation of current and historic groundwater sampling data, the
NC 2L Groundwater Standard and UTL metal exceedances from the April 2023 sampling event were
determined to be indicative of naturally occurring background concentrations as opposed to a release
from the landfill. Dissolved metal sample results are provided in Table 4 and the laboratory data report
is provided in Appendix A.
Corrective Action via Air Sparging
The SWS expressed concern in May 2008 that VOCs may be migrating beyond the Site property
boundary and into Abbott's Creek based on detections above the NC 2L Groundwater Standard in
monitoring well MW-9. As a result, the SWS directed the County to install and sample groundwater
monitoring wells, one shallow and one deep (i.e., MW-36 and -36d), downgradient of MW-9 to
determine if VOCs may be migrating beyond the Site property boundary, possibly discharging into
Abbott's Creek. Initial groundwater samples collected from MW-36 and -36d in December 2008 had
detections of VOCs above NC 2L Groundwater Standards.
Surface water sample locations SW-7 and -8, located on Abbott's Creek, were added to the semi-annual
monitoring program in November 2008. Samples collected from SW-7 and -8 since being added to the
monitoring program have never had VOCs detected above the NC 2B Surface Water Quality Standards.
An Assessment of Corrective Measures Report was submitted to the SWS in accordance with the North
Carolina Solid Waste Management Rule 15 NCAC 13B .1635 and approved in December 2009. The SWS
approved the selected remedy of monitored natural attenuation paired with in situ remediation by air
sparging to address groundwater contamination at the facility. A pilot test was conducted in July and
August 2010 near MW-6 and -6d to evaluate the effectiveness of the air sparging remedy and to collect
data for the full-scale system design in accordance with the CAP. The pilot test successfully reduced the
concentrations of 1,1-dichloroethane and vinyl chloride to below their respective NC 2L Groundwater
Standard in MW-6d and vinyl chloride was not detected in samples collected from MW-6 during the
October 2010 semi-annual sampling event.
The full-scale system was installed in October 2011 and was operational in August 2012. The air sparging
system consists of 15 shallow wells screened across saturated saprolite and partially weathered rock and
14 wells screened in the shallow fractured bedrock. In addition to the air sparging wells, the system also
consists of an air compressor and control panel that are housed in a secured on -site control building.
Routine inspections are performed on the system and a Field Inspection Log completed during each
inspection is kept on file at the facility. The system has been off for some wells since the fall
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2022 sampling event as the County replaces flow and pressure control gauges as part of ongoing system
maintenance, which is estimated to be completed prior to the fall 2023 sampling event.
The County installed a vacuum extraction system around the perimeter of the Site in January 2002 to
prevent offsite migration of soil gas. The air sparging system was designed to work in tandem with the
existing perimeter migration control system (PMCS) by recovering air and gas vapors produced by the air
sparging system. Since previous work has indicated a relationship between the soil gas and the
contaminated groundwater, the installation of the PMCS is likely to further reduce groundwater
contaminant concentrations. As discussed in the approved CAP, the vacuum extraction system will be
used in conjunction with the air sparging system to reduce VOCs in the bedrock and partially weathered
rock between MW-9 and the MW-6 nested pair.
As part of the corrective action effectiveness evaluation, contaminant concentration trends for
monitoring wells MW-6, -6d, -9, -36, and -36d were evaluated. Total VOC concentration trends for each
well are presented on Figures 2 through 6. Trend results for each well are discussed below.
Figure 2 presents a total VOC concentration trend analysis for samples collected from MW-6. VOCs in
MW-6 significantly decreased after January 2002 when the PMCS was operational and were not
detected from November 2004 to April 2007. The total VOC concentration in MW-6 increased in May
2008 to 24 ppb compared to the November 2007 concentration of 14 ppb. The total VOC concentration
in MW-6 showed a decreasing trend from May 2008 to April 2018 but has increased since the
introduction of the 1,4-dioxane analysis in October 2018. The total VOC concentration in MW-6 has
fluctuated since October 2018.
Vinyl chloride has not been detected above the laboratory MDL in MW-6 since the April 2013 sampling
event. Benzene detections in MW-6, which historically have exceeded the NC 2L Groundwater Standard,
have been below the laboratory MDL since April 2013 except for the November 2014 sampling event
when it was detected slightly above the standard at 1.1 ppb and October 2018 when it was detected
above the MDL at 0.61 ppb.
The trend analysis for total VOC concentrations in MW-6d is presented on Figure 3. VOCs were not
detected at MW-6d from December 2001 through November 2007. The increase in total VOCs from
samples collected during the May 2008 sampling event is a result of reporting "J" flag detections as
required by the SWS. VOC concentrations in MW-6d have been below the NC 2L Groundwater Standards
since the March 2011 sampling event but show an increasing trend.
Figure 4 presents a total VOC concentration trend analysis for samples collected from MW-9
Historically, MW-9 has had the highest concentration of VOCs compared to the other monitoring wells.
VOCs were not detected above the NC 2L Groundwater Standards in MW-9 from October 2012 through
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April 2015. Benzene, 1,4-dichlorobenzene, 1,2-dichloroethane, 1,4-dioxane, and vinyl chloride have
recently been detected above their respective NC 2L Groundwater Standards in MW-9. The total VOC
concentration trend has been slightly increasing at MW-9 since the October 2018 sampling event.
Trend analyses for total VOC concentrations in MW-36 and -36d are presented on Figures 5 and 6,
respectively. Vinyl chloride was detected above its NC 2L Groundwater Standard during the October
2020 sampling event for the first time in samples collected from MW-36 since March 2011, and was also
detected above the standard from November 2021 through April 2023. Additionally, total VOC
concentrations have shown an increasing trend since the March 2021 sampling event, but are expected
to decrease when the air sparging system maintenance is complete. No VOCs have been detected above
the NC 2L Groundwater Standards in MW-36d since the October 2015 sampling event. Total VOC
concentrations in both monitoring wells will continue to be monitored.
Additional groundwater samples were collected from MW-5R, -6, -8, -9, -10, -11, and -36 for evaluation
of monitored natural attenuation parameters as part of the corrective action program as required by
SWS guidelines. Geochemical results are presented in Table 6. The laboratory data for the additional
parameters is included in Appendix A.
As discussed in the approved CAP, concentrations of some of the natural attenuation data from select
wells indicates that environments are present which favor reductive dechlorination; notably, the
concentrations of nitrate, ferrous iron, sulfate, and carbon dioxide. The following evidence indicates that
one or more mechanisms of natural attenuation and/or reductive dechlorination may be occurring at
the site:
■ VOC concentrations in contaminated wells continue to decline;
■ The ratio of parent to daughter compounds continues to decrease over time;
■ Nitrate, ferrous iron, sulfate, and carbon dioxide continue to be detected at concentrations
favoring reductive dechlorination; and
■ Concentrations of cis-1,2-dichloroethene continue to be greater than dichloroethene isomers
trans-1,2-dichloroethene and 1,1-dichloroethene.
Corrective Action via In Situ Bioremediation Injection
VOCs that exceed the NC 2L Groundwater Standards, including benzene, 1,4-dichlorobenzene, 1,1-
dichloroethane, methylene chloride, PCE, TCE, and vinyl chloride, have been detected in the area of
MW-5R, -34, and -34d. MW-5R is located near the Site property line and the MW-34 cluster is located
east of MW-5R on the adjacent parcel, more than 900 feet from the air sparging system. The VOC
exceedances are likely from the migration of leachate from the Site into the surficial aquifer.
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June 23, 2023
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In accordance with the CAP Addendum that was approved by the SWS on July 10, 2019, and an injection
permit obtained from the Division of Water Quality — Underground Injection Control Program on July 24,
2019, an in situ enhanced anaerobic bioremediation (EAB) injection was completed by adding sodium
lactate and emulsified vegetable oil (EVO) substrates through a biobarrier injection system to reduce
total VOC concentrations at the property line. Sodium lactate and EVO enhance biologically reducing
conditions that favor and support dechlorination of VOCs to non -toxic end products.
On August 26-28, 2019, eight injection wells (i.e., NWIW-1 through -8) were installed upgradient of
MW-5R, -35, and -34d, as shown on Figure 1. An initial injection of sodium lactate was completed from
October 8-16, 2019. A total of 54,181 gallons of a 2.4 percent sodium lactate solution were injected.
Post -sodium lactate injection samples were collected 1 month after the injection during the November
2019 semi-annual sampling event. Samples collected from monitoring wells MW-5R, -34, and -34d were
analyzed for natural attenuation parameters, sodium, total iron, and total dissolved solids. Analytical
results are summarized in Tables 4 and 6.
The EVO injection was completed on November 18-30 and December 1-6, 2019, with a 3.3 percent
solution of 98 percent LactOil® EVO formulation. A total of 80,751 gallons of the solution was injected.
The effectiveness of the EAB injection was evaluated with quarterly sampling of MW-5R, -34, and -34d
on February 4, April 8, July 30, and October 15, 2020. A report summarizing the results of the EAB
injection was submitted to the SWS on June 23, 2021. Chlorinated VOC data were reviewed to evaluate
concentration trends over time and to determine if dechlorination is occurring. Total VOC concentration
trends for each well are presented on Figures 7 through 9. Trend results for each well are discussed
below.
The VOC trend analysis for MW-SR is presented on Figure 7. TCE has never been detected above the NC
2L Groundwater Standard in MW-5R and PCE has never been detected above the MDL, except during
the April 2019 sampling event when PCE was detected as an estimated concentration below the
standard. Vinyl chloride was the most recent analyte detected above the NC 2L Groundwater Standard
(April 2019). The geochemical data indicates reducing conditions to support anaerobic dechlorination at
MW-5R, shown by decreasing levels of sulfate, nitrate, DO, and negative values of ORP. Additionally,
total VOC concentrations show a decreasing trend since the injection events and VOCs have not been
detected above the MDLs since March 2022.
The trend analyses for MW-34 and -34d are presented on Figures 8 and 9, respectively. Since the
injections, total VOC, PCE, TCE, and 1,1-dichloroethane concentrations have fluctuated. Concentrations
of methylene chloride show a decreasing trend and cis-1,2-dichloroethene concentrations have
fluctuated in MW-34. Total VOC concentrations in MW-34d have decreased as the reducing conditions
at the upgradient biobarrier support dechlorination.
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Recommendations
The County will continue with the semi-annual assessment monitoring program. In addition to sampling
for Appendix I metals plus mercury, Appendix I VOCs plus dichlorodifluoromethane, and the Appendix II
constituent, bis(2-ethylhexyl) phthalate (sampled at MW-29d only during the spring sampling event),
samples collected from MW-5R, -6, -8, -9, -10, -11, -34, -34d, and -36 will continue to be analyzed for
natural attenuation parameters during the semi-annual events. MW-6, -8, and -9 will continue to be
analyzed for 1,4-dioxane. Following completion of repairs and system maintenance, the air sparging
system will continue to operate and the effectiveness of the system will be re-evaluated after the next
semi-annual sampling event in the fall of 2023.
If you have any questions or require further explanation, do not hesitate to call me at [phone].
Sincerely,
%&4 IVJU-
Mathew F. Colone, P.G.
CDM Smith Inc.
cc: John Roberson, WCSWM
Elliott Cornell, WCSWM
04

Table 1
Monitoring Well Construction Summary and Groundwater Elevations
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
DepthDepths
DiameterFacility Permit Monitoring Completion Screened Total Number Well Code Date Lattitude Longitude Lithology (feet below Screen, Filter Seal I I I I I TOC) Casing I Interva Interval Interval (inches) ElevalCon Ground% Elevation
9209-MSWLF-1984 MW-5R 1/30/2004 35.91192 78.57159 Regolith 27.5 10.0-25.0 8.0-25.0 6.0-8.0 2 225.28 15.44 209.84
9209-MSWLF-1984
MW-6
March-94
35.91423
78.57122
Regolith
22.0
--
10.0-20.0
8.0-20.0
6.0-8.0
2
219.80
12.38
207.42
9209-MSWLF-1984
MW-6d
5/1/2001
35.91423
78.57122
Bedrock
65.0
0-45.0
52.0-62.0
50.0-62.0
48.0-50.0
2
218.61
12.76
205.85
9209-MSWLF-1984
MW-7
March-94
35.91098
78.57436
Regolith
21.5
9.0-19.0
7.0-19.0
5.0-7.0
2
234.15
12.45
221.70
9209-MSWLF-1984
MW-8
March-94
35.91078
78.57266
Regolith
21.5
--
9.0-19.0
7.0-19.0
5.0-7.0
2
226.38
11.56
214.82
9209-MSWLF-1984
MW-8d
1 5/3/2001
35.91078
78.57266
Bedrock
45.0
0-30.0
37.0-42.0
35.0-42.0
29.0-35.0
2
226.16
12.45
213.71
9209-MSWLF-1984
MW-9
March-94
35.91484
78.57273
Regolith
44.0
32.0-42.0
30.0-42.0
28.0-30.0
2
242.69
30.11
212.58
9209-MSWLF-1984
MW-10
4/1/1998
35.91499
78.57494
Bedrock
55.5
43.0-53.0
41.0-53.0
39.0-41.0
2
274.76
45.70
229.06
9209-MSWLF-1984
MW-10d
5/1/2001
35.91499
78.57494
Bedrock
93.0
80.0-90.0
78.0-92.0
75.0-78.0
2
274.54
48.89
225.65
9209-MSWLF-1984
MW-11
October-95
35.90574
78.58251
Regolith
57.0
39.0-54.0
37.0-54.0
35.0-37.0
2
343.63
44.31
299.32
9209-MSWLF-1984
MW-11d
October-95
35.90578
78.58248
Bedrock
72.0
64.0-69.0
62.0-69.0
60.0-62.0
2
343.27
44.45
298.82
9209-MSWLF-1984
MW-22
June-97
35.91596
78.57453
Regolith
39.0
27.0-37.0
25.0-37.0
23.0-25.0
2
254.62
35.79
218.83
9209-MSWLF-1984
MW-23
June-97
35.91373
78.57540
Regolith
50.0
38.0-48.0
36.0-48.0
34.0-36.0
2
274.83
47.02
227.81
9209-MSWLF-1984
MW-23d
4/27/1998
35.91373
78.57540
Bedrock
91.0
0-43.0
78.0-88.0
76.0-88.0
74.0-76.0
2
274.89
47.01
227.88
9209-MSWLF-1984
MW-24
June-97
35.91232
78.57546
Regolith
47.5
35.0-45.0
33.0-45.0
31.0-33.0
2
266.64
46.05
220.59
9209-MSWLF-1984
MW-28
4/9/1998
35.91644
78.57439
Regolith
30.0
--
20.0-30.0
18.0-30.0
16.0-18.0
2
237.89
18.88
219.01
9209-MSWLF-1984
MW-28d
4/22/1998
35.91644
78.57439
Bedrock
51.0
0-28.0
41.0-51.0
39.0-51.0
37.0-39.0
2
238.44
18.90
219.54
9209-MSWLF-1984
MW-29d
4/22/1998
35.91472
78.57572
Bedrock
52.0
0-40.5
47.0-52.0
45.0-52.0
43.0-45.0
2
275.06
43.90
231.16
9209-MSWLF-1984
MW-30
4/14/1998
35.91374
78.57596
Regolith
55.0
40.0-55.0
38.0-55.0
36.0-38.0
2
282.32
51.00
231.32
9209-MSWLF-1984
MW-31
4/2/1998
35.91231
78.57595
Regolith
35.5
--
25.5-35.5
23.0-35.5
21.0-23.0
2
261.67
33.72
227.95
9209-MSWLF-1984
MW-31d
4/23/1998
35.91231
78.57595
Bedrock
66.0
0-51.0
56.0-66.0
54.0-66.0
52.0-54.0
2
260.92
33.18
227.74
9209-MSWLF-1984
MW-32
4/3/1998
35.91142
78.57564
Regolith
26.0
13.0-23.0
11.0-23.0
9.0-11.0
2
242.99
16.86
226.13
9209-MSWLF-1984
TB-1a
4/7/1998
35.91188
78.57595
Regolith
30.0
--
20.0-30.0
17.5-30.0
14.0-17.5
2
255.05
28.75
226.30
9209-MSWLF-1984
TB-1a deep
5/7/2001
35.91188
78.57595
Bedrock
62.0
0-23.0
52.0-62.0
50.0-62.0
47.0-50.0
2
256.01
31.00
225.01
9209-MSWLF-1984
MW-33
7/22/1998
35.91077
78.57169
Regolith
28.0
10.0-25.0
8.0-25.0
6.0-8.0
2
222.01
11.30
210.71
9209-MSWLF-1984
MW-34
7/23/1998
35.91192
78.57116
Regolith
28.0
--
15.0-25.0
13.0-25.0
11.013.0
2
221.96
13.17
208.79
9209-MSWLF-1984
MW-34d
7/23/1998
35.91192
78.57116
Bedrock
58.0
0-38.0
45.0-55.0
43.0-55.0
41.0-43.0
2
222.16
13.56
208.60
9209-MSWLF-1984
MW-35
7/23/1998
35.91322
78.57052
Regolith
28.0
10.0-25.0
8.0-25.0
6.0-8.0
2
223.48
16.36
207.12
9209-MSWLF-1984
MW-36
11/25/2008
35.91491
78.57193
Regolith
40.0
--
25.0-40.0
23.0-40.0
21.0-23.0
1 2
1 237.40
1 26.79
1 210.61
9209-MSWLF-1984
MW-36d
1 11/25/2008
1 35.91491
1 78.57193
Bedrock
55.0
0-45.0
50.0-55.0
48.0-55.0
45.0-48.0
1 2
1 237.68
1 27.03
1 210.65
Notes:
1. TOC - Top of Casing
2. bgs - Below Ground Surface
3. Latitude and Longitude Coordinates - World Geodetic System 1983
Smith Page 1 of 1 June 2023

Table 2
Summary of Calculated Groundwater Flow Velocities
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Hydraulic
Conductivity
9209-MSWLF-1984
MW-5R
feet/day (cm/s)
0.33 0.18
=OEM
q4.27E-02
0.0233
4.28E-02
0.0241
4.43E-02
0.0235
4.31E-02
0.0257
4.72E-02
0.0233
1.16E-04
9209-MSWLF-1984
MW-6
10.58
0.13
0.0206
1.68E+00
0.0209
1.70E+00
0.0208
1.69E+00
0.0206
1.68E+00
0.0204
1.66E+00
3.73E-03
9209-MSWLF-1984
MW-7
1.15
0.18
0.0257
1.64E-01
0.0261
1.66E-01
0.0256
1.64E-01
0.0257
1.64E-01
0.0255
1.63E-01
4.06E-04
9209-MSWLF-1984
MW-8
3.61
0.18
0.0249
5.00E-01
0.0252
5.06E-01
0.0248
4.98E-01
0.0249
4.99E-01
0.0247
4.96E-01
1.27E-03
9209-MSWLF-1984
MW-9
1.22
0.30
0.0201
8.16E-02
0.0199
8.10E-02
0.0200
8.15E-02
0.0198
8.06E-02
0.0200
8.12E-02
4.30E-04
9209-MSWLF-1984
MW-10
0.509
0.05
0.0168
1.72E-01
0.0171
1.74E-01
0.0171
1.74E-01
0.0172
1.75E-01
0.0174
1.78E-01
1.80E-04
9209-MSWLF-1984
MW-11
5.66
0.13
0.0214
9.31E-01
0.0217
9.44E-01
0.0215
9.35E-01
0.0217
9.46E-01
0.0215
9.35E-01
2.00E-03
9209-MSWLF-1984
MW-22
0.07
0.18
0.0182
7.09E-03
0.0185
7.21E-03
0.0182
7.07E-03
0.0185
7.21E-03
0.0185
7.21E-03
2.47E-05
9209-MSWLF-1984
MW-23
3.59
0.30
0.0196
2.35E-01
0.0198
2.36E-01
0.0197
2.36E-01
0.0198
2.37E-01
0.0198
2.37E-01
1.27E-03
9209-MSWLF-1984
MW-24
0.34
0.30
0.0248
2.81E-02
0.0253
2.86E-02
0.0251
2.84E-02
0.0251
2.85E-02
0.0251
2.85E-02
1.20E-04
9209-MSWLF-1984
MW-36
17.56
0.30
0.0197
1.16E+00
0.0200
1.17E+00
0.0197
1.15E+00
0.0197
1.16E+00
0.0197
1.16E+00
6.19E-03
9209-MSWLF-1984
MW-36D
0.78
0.10
0.0196
1.53E-01
0.0199
1.55E-01
0.0195
1.52E-01
0.0196
1.53E-01
0.0196
1.53E-01
2.75E-04
Notes:
1. cm/s - centimeters per second
2. Hydraulic conductivity and effective porosity values are estimated from previously perfomed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-11 are based on the average of all the listed wells, with the exception of MW-36D.
CDM
Smith Page 1 of 3 June 2023

Table 2
Summary of Calculated Groundwater Flow Velocities
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Hydraulic
Conductivity
9209-MSWLF-1984IMIW-!5R
feet/day (cm/s)
0.33 0.18
0.0233
4.27E-02
0.0229
4.20E-02
0.0238
4.36E-02
0.0233
4.27E-02
0.0236
4.33E-021.16E-049209-MSWLF-1984
10.58
0.13
0.0203
1.65E+00
0.0204
1.66E+00
0.0206
1.67E+00
0.0205
1.66E+00
0.0206
1.68E+00
3.73E-03
9209-MSWLF-1984
MW-7
1.15
0.18
0.0253
1.62E-01
0.0256
1.64E-01
0.0257
1.64E-01
0.0256
1.63E-01
0.0257
1.64E-01
4.06E-04
9209-MSWLF-1984
MW-8
3.61
0.18
0.0245
4.92E-01
0.0249
4.98E-01
0.0249
4.99E-01
0.0248
4.98E-01
0.0250
5.01E-01
1.27E-03
9209-MSWLF-1984
MW-9
1.22
0.30
0.0198
8.06E-02
0.0199
8.10E-02
0.0201
8.18E-02
0.0200
8.13E-02
0.0202
8.20E-02
4.30E-04
9209-MSWLF-1984
MW-10
0.509
0.05
0.0173
1.76E-01
0.0169
1.72E-01
0.0170
1.73E-01
0.0169
1.72E-01
0.0171
1.74E-01
1.80E-04
9209-MSWLF-1984
MW-11
5.66
0.13
0.0213
9.28E-01
0.0213
9.27E-01
0.0215
9.36E-01
0.0214
9.30E-01
0.0215
9.37E-01
2.00E-03
9209-MSWLF-1984
MW-22
0.07
0.18
0.0183
7.12E-03
0.0181
7.04E-03
0.0184
7.16E-03
0.0183
7.11E-03
0.0184
7.17E-03
2.47E-05
9209-MSWLF-1984
MW-23
3.59
0.30
0.0199
2.38E-01
0.0197
2.36E-01
0.0197
2.36E-01
0.0197
2.35E-01
0.0198
2.37E-01
1.27E-03
9209-MSWLF-1984
MW-24
0.34
0.30
0.0250
2.83E-02
0.0248
2.82E-02
0.0251
2.84E-02
0.0249
2.83E-02
0.0251
2.85E-02
1.20E-04
9209-MSWLF-1984
MW-36
17.56
0.30
0.0195
1.14E+00
0.0196
1.15E+00
0.0198
1.16E+00
0.0196
1.15E+00
0.0198
1.16E+00
6.19E-03
9209-MSWLF-1984
MW-36D
0.78
0.10
0.0194
1.51E-01
0.0195
1.52E-01
0.0043
3.35E-02
0.0195
1.52E-01
0.0197
1.53E-01
2.75E-04
1
Notes:
1. cm/s - centimeters per second
2. Hydraulic conductivity and effective porosity values are estimated from previously perfomed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-11 are based on the average of all the listed wells, with the exception of MW-36D.
CDM
Smith Page 2 of 3 June 2023

Table 2
Summary of Calculated Groundwater Flow Velocities
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
...
Linear Velocity
M
Linear Velocity
9209-MSWLF-1984
MW-512
0.33 0.18
FO.0237rttt�
0.0236
4.33E-02
0.0235
4.32E-02
0.0232
4.26E-02
0.0230
4.22E-02
1.16E-04
9209-MSWLF-1984
MW-6
10.58
0.13
0.0206
1.68E+00
0.0205
1.67E+00
0.0204
1.66E+00
0.0205
1.67E+00
0.0202
1.65E+00
3.73E-03
9209-MSWLF-1984
MW-7
1.15
0.18
0.0257
1.64E-01
0.0256
1.63E-01
0.0256
1.63E-01
0.0257
1.64E-01
0.0253
1.62E-01
4.06E-04
9209-MSWLF-1984
MW-8
3.61
0.18
0.0250
5.01E-01
0.0248
4.97E-01
0.0248
4.97E-01
0.0249
4.99E-01
0.0246
4.93E-01
1.27E-03
9209-MSWLF-1984
MW-9
1.22
0.30
0.0202
8.20E-02
0.0200
8.12E-02
0.0200
8.12E-02
0.0201
8.16E-02
0.0198
8.04E-02
4.30E-04
9209-MSWLF-1984
MW-10
0.509
0.05
0.0171
1.74E-01
0.0168
1.71E-01
0.0172
1.75E-01
0.0175
1.79E-01
0.0174
1.77E-01
1.80E-04
9209-MSWLF-1984
MW-11
5.66
0.13
0.0215
9.37E-01
0.0214
9.30E-01
0.0214
9.32E-01
0.0216
9.41E-01
0.0213
9.27E-01
2.00E-03
9209-MSWLF-1984
MW-22
0.07
0.18
0.0184
7.16E-03
0.0183
7.13E-03
0.0184
7.15E-03
0.0186
7.23E-03
0.0183
7.11E-03
2.47E-05
9209-MSWLF-1984
MW-23
3.59
0.30
0.0198
2.37E-01
0.0194
2.32E-01
0.0198
2.37E-01
0.0202
2.41E-01
0.0200
2.39E-01
1.27E-03
9209-MSWLF-1984
MW-24
0.34
0.30
0.0251
2.85E-02
0.0251
2.84E-02
0.0250
2.83E-02
0.0253
2.86E-02
0.0249
2.82E-02
1.20E-04
9209-MSWLF-1984
MW-36
17.56
0.30
0.0198
1.16E+00
0.0196
1.15E+00
0.0196
1.15E+00
0.0197
1.15E+00
0.0194
1.14E+00
6.19E-03
9209-MSWLF-1984
MW-36D
0.78
0.10
0.0199
1.55E-01
0.0196
1.53E-01
0.0041
3.23E-02
0.0042
3.31E-02
0.0193
1.51E-01
2.75E-04
Notes:
1. cm/s - centimeters per second
2. Hydraulic conductivity and effective porosity values are estimated from previously perfomed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-11 are based on the average of all the listed wells, with the exception of MW-36D.
CDM
Smith Page 3 of 3 June 2023

Table 3
Water Quality Parameters
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill
Permit Number 9209-MSWLF-1984
Facility Permit
Number
9209-MSWLF-1984
Monitoring
Well Code
MW-5R
Water Quality Parameters
PH Conductivity Temperature Turbidity D. ...
(S.U.) (VS/cm) (degrees Celsius) (NTUs) (mg/L) (mVs)
6.58 537 17.4 8 0.68 -66.5
9209-MSWLF-1984
MW-6
6.56
801
16.4
10
6.19
257.3
9209-MSWLF-1984
MW-6d
5.75
158
17.9
2
0.92
439.1
9209-MSWLF-1984
MW-7
6.11
606
16.0
9
2.33
-33.3
9209-MSWLF-1984
MW-8
6.18
639
16.5
9
0.49
59.1
9209-MSWLF-1984
MW-8d
6.03
170
17.3
5
1.43
147.9
9209-MSWLF-1984
MW-9
6.29
943
20.1
8
3.44
-10.6
9209-MSWLF-1984
MW-10
5.52
234
18.0
3
2.23
99.5
9209-MSWLF-1984
MW-10d
6.07
183
18.8
9
1.94
144.4
9209-MSWLF-1984
MW-11
5.99
101
18.4
8
7.01
231.3
9209-MSWLF-1984
MW-11d
5.90
r 108
17.7
5
6.93
190.2
9209-MSWLF-1984
MW-22
Dry
9209-MSWLF-1984
MW-23
5.80
122
16.6
45
7.84
202.0
9209-MSWLF-1984
MW-23d
5.81
170
16.5
8
6.19
202.2
9209-MSWLF-1984
MW-24
Dry
9209-MSWLF-1984
MW-28
5.91
193
17.4
22
7.90
116.2
9209-MSWLF-1984
MW-28d
6.49
72
17.4
28
0.65
-2.4
9209-MSWLF-1984
MW-29d
5.90
138
16.5
8
1 7.74
1 139.5
9209-MSWLF-1984
MW-30
Dry
9209-MSWLF-1984
MW-31
Dry
9209-MSWLF-1984
MW-31d
6.06
173
17.0
74.42
122.4
9209-MSWLF-1984
MW 32
5.18
89
15.8
9
1 3.29
171.4
9209-MSWLF-1984
TB-1a
Dry
9209-MSWLF-1984
TB -la deep
5.37
170
16.2
9
3.11
187.3
9209-MSWLF-1984
MW-33
5.91
146
15.1
9
1.68
130.8
9209-MSWLF-1984
MW-34
5.42
152
16.1
9
0.56
190.6
9209-MSWLF-1984
MW-34d
5.86
259
15.8
1
2.23
207.9
9209-MSWLF-1984
MW-35
4.92
44
15.7
7
1.61
195.5
9209-MSWLF-1984
MW-36
5.82
258
17.3
46
1.10
81.5
9209-MSWLF-1984
9209-MSWLF-1984
MW-36d
Surface Water Sample
SW-2
6.22
6.85
291
125
17.0
18.5
9
4
0.56
8.67
24.9
110.1
9209-MSWLF-1984
SW-3
7.44
145
20.2
2
12.36
110.0
9209-MSWLF-1984
SW-7
7.13
111
19.7
5
10.32
131.6
9209-MSWLF-1984
SW-8
7.06
104
19.7
3
10.40
138.3
Notes:
1. Water quality measurements were collected on April 3-5, 2023.
2. Turbidity readings were recorded at the time samples were collected.
3. µS/cm - Microsiemens per centimeter
4. mg/L - Milligrams per liter
5. ORP - Oxidation -Reduction Potential
6. NTUs - Nephelometric Turbidity Units
7. mVs - Millivolts
8. S.U. - Standard Units
9. DO - Dissolved Oxygen
Smith Page 1 of 1 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
0.
,,,
15
1
,,,
100„
M W-11
25-Apr-12
65.3J
2.37J
3.231 12.1
MW-11
23-Oct-12
80.6J
1.42J
3.66J
5.321 19.7
MW-11
17-Apr-13
901
0.2J
2J
2J
8J
11
11
91 20B
MW-11
16-Oct-13
100
0.1J
0.2J
2J
iJ
4J
0.5J
0.91
51 15B
MW-11
16-Apr-14
170
0.5J
0.2J
4J
6J
18
3J
3J
0.081
40 50B
MW-11
12-Nov-14
901
0.2J
0.2J
2J
21
8J
11
11
0.05J
7J 24
MW-11
30-Apr-15
100
0.2J
2J
3J
101
11
2J
0.06J
12J 27
MW-11
15-Oct-15
110
0.3J
0.1J
3J
3J
11
11
0.04J
2J
0.05J
13JB 27
MW-11
21-Apr-16
0.5J
130
0.3J
1
4J
16
2J
2J
O.116
181 32
MW-11
1-5ep-16
90J
0.28J
0.54J
2.4J
2.6J
8.3J
1.3J
1.6J
111 20
M W-11
20-Apr-17
61J
1.2J
1.51 11
MW-11
22-Sep-17
45J
2.4J
1.81
3.7J 6.3J
MW-11
13-Apr-18
61J
2.1
2.OJ
0.27J
12
MW-11
25-Oct-18
71J
2.2J
3.9J
0.50J
5.11 66
MW-11 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11
26-Feb-19
57J
2.OJ
1.4J
10
MW-11
25-Apr-19
120
0.30J
3.8J
3.3J
20
2.2J
1.8J
17J 28
MW-11 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11
2-Jul-19
170
0.70
5.1
7.4
25
4.1
4.1
33 45B
MW-11 (dissolved)
2-Jul-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11
7-Nov-19
59
2.1J
4.1
0.66J
0.48
5.6 25
MW-11 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11
22-Jan-20
87
0.27J
3.7J
2.lJ
12
1.9
1.5J
3.1
9.2 21
MW-11 (dissolved)
22-Jan-20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
M W-11
9-Apr-20
55
2.1
7.3J
M W-11
15-Oct-20
55
1.5J
10
MW-11
31-Mar-21
52
2.1
2.6J 5.5J
M W-11
11-Nov-21
47
5.5J
MW-11
31-Mar-22
53
1.7J
0.45J
3.6J 7.9J
M W-11
13-Oct-22
45
1.4J
4.1J
M W-11
5-Apr-23
50
1.1
5.5J
MW-lld
26-Apr-12
0.247J
44.2J
3.04J
9.68JB
3.31J
2.05J
4.62J
MW-lld
24-Oct-12
43.7J
0.375J
2.40J
2.53J
5.10J
MW-lld
18-Apr-13
0.4J
50J
0.11
2JB
0.2J
1J
0.6J
4JB
MW-lld
17-Oct-13
0.61
0.61
50J
0.3J
1J
0.2J
1J
0.02J
0.6J
2J
2JB
MW-lld
17-Apr-14
300
2.1
0.2J
15
13
56
11
91
0.2J
99
88
MW-lld
13-Nov-14
150
0.7J
0.11
5J
4J
18
4J
1
0.07J
37
35
MW-lld
29-Apr-15
0.61
0.51
60J
0.1J
0.11
2J
0.61
1
0.6J
0.91
5J
8J
MW-lld
15-Oct-15
0.4J
901
0.3J
0.11
1
2J
91
2J
0.05J
2J
14JB
16
MW-lld
21-Apr-16
0.3J
60J
2J
0.3J
4J
0.5J
2J
12
MW-lld
1-Sep-16
0.43BJ
45J
0.076J
1.2J
2.1J
0.25J
0.75J
2.7J
9.2JB
MW-lld
20-Apr-17
48J
2.2J
2.2J
2.2J
5.OJ
MW-lld
22-Sep-17
45J
2.8J
1.6J
3.3J
5.1J
MW-lld
12-Apr-18
43J
5.8J
2.8J
4.41
MW-lld
23-Oct-18
46J
25
13J
4.2J
MW-lld
25-Feb-19
46J
7.OJ
3.4J
3.6J
MW-lld (dup)
25-Feb-19
45J
9.91
4.9J
4.OJ
MW-lld
25-Apr-19
46J
5.OJ
2.2J
2.8J
MW-lld
2-Jul-19
90
0.42
4.1J
2.5J
12
1.8
2.4J
17
18B
MW-lld (dissolved)
2-Jul-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-lld
5-Nov-19
43
2.1
2.6J
0.29J
1.91
13B
MW-lld (dup)
5-Nov-19
44
2.5J
2.1J
0.26J
1.8J
11B
MW-lld
21-Jan-20
0.65J
46
2.8J
2.1J
0.29J
8.41
MW-lld (dup)
21-Jan-20
0.86J
48
3.4J
2.1J
0.37J
9.5J
MW-lld
8-Apr-20
44
0.18J
5.3
1.1
2.8J
9.91
MW-lid
13-Oct-20
0.841
45
0.371
3.OJ
12
MW-lid
31-Mar-21
0.661
46
0.401
3.213J
4.61
0.25J
1.41
10
MW-lid
9-Nov-21
44
1.91
3.5J
MW-lid
30-Mar-22
44
2.5J
1.7J
3.41
MW-lid
12-Oct-22
43
7.3
3.9J
2.8J
MW-11d
5-Apr-23
42
1.91
3.9J
CDIN Page 1 of 31 June 2023
Smith

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
In
24-Apr-12
0.411J
97.31
2.79J
,,,
15
1
100
2.47J
0.170J
,,,
4.28.1
MW-5R
MW-5R
22-Oct-12
99.31
1.82J
3.61J
0.114J
23.9
MW-5R
17-Apr-13
801
0.081
2J
0.31
1
0.11
5J13
MW-5R
16-Oct-13
90J
0.051
11
0.51
0.41
3J
0.11
5J13
MW-5R
16-Apr-14
80J
0.1
0.1
0.21
0.5J
iJ
0.21
21
5J13
MW-5R
12-Nov-14
80J
2J
0.21
21
0.31
6J13
MW-5R
30-Apr-15
70J
0.11
0.81
0.11
11
0.11
4.1
MW-5R
15-Oct-15
110
0.2J
7J
0.81
2J
0.61
0.04.1
4J
0.11
6.1
MW-5R
21-Apr-16
60J
0.071
11
0.21
0.4J
11
0.11B
2.1
MW-5R
14-Sep-16
79J
0.061
1.7J
0.45113
0.046JB
2.4J
0.080.1
1.11
5.3JB
MW-5R
20-Apr-17
71J
1.5J
MW-5R
20-Sep-17
430
13
1.71
1.4J
5.8.1
MW-5R
11-Apr-18
76J
1.4J
1.5J
2.6.1
MW-5R
24-Oct-18
84J
2.1J
3.3.1
MW-5R
22-Apr-19
68J
0.231
MW-5R
6-Nov-19
130
2.2J
2.1
5.7
15
MW-5R
9-Apr-20
300
0.20.1
0.131
3.4J
290
2.9J
0.52J
100
0.51
4.1
51
MW-5R (dissolved)
9-Apr-20
NA
NA NA
NA
NA
NA
390
NA
NA
NA
140
NA
NA
0.32.1
NA
MW-5R
15-Oct-20
1.31 170
0.43
0.231
18
93
8.3
3.4
18
1.1
0.18.1
16
22
MW-5R (dissolved)
15-Oct-20
NA
NA NA
NA
NA
91
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-5R
31-Mar-21
64
0.15.1
4.9J
75
1.5J
0.52J
12
2.7J
11
MW-5R
11-Nov-21
84
76
17
6.5.1
MW-5R
30-Mar-22
40
0.15.1
39
1.9J
0.26J
7.9
4.3.1
MW-5R (dissolved)
30-Mar-22
NA
NA NA
NA
NA
NA
19
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-5R
12-Oct-22
85
55
15
MW-5R
4-Apr-23
68
0.16.1
36
0.39J
9.0
2.9J
2.6.1
MW-6
24-Apr-12
0.244J
182
3.49J
54.9
8.45J
2.18J
0.134.1
117
MW-6
22-Oct-12
258
0.148J
1.59J
80.4
15.1J
MW-6
17-Apr-13
100J
0.05.1
1.6
35
4J
0.17.1
6J
0.1
9JB
MW-6
16-Oct-13
90J
0.04J
0.31
34
2J
0.02.1
5J
2.1
0.2J
3J
5JB
MW-6(dup)
16-Oct-13
90.1
0.21
0.6J
35
2J
0.04J
6J
2.1
0.2J
3J
MW-6
16-Apr-14
0.21
60J
0.10J
0.81
11
18
1
0.21
4J
0.1
2J
8JB
MW-6(dup)
16-Apr-14
60J
0.071
0.7J
1J
18
2J
0.21
4J
0.2J
3J
8JB
MW-6
12-Nov-14
0.81
310
49
11
0.02.1
15J
2.1
0.1J
2JB
MW-6
30-Apr-15
70J
0.06.1
0.1J
25
11
0.08.1
4J
0.1J
3.1
MW-6
14-Oct-15
230
0.2.1
32
4J
0.03.1
13J
2.1
0.1
MW-6
20-Apr-16
70J
0.04J
8.1
0.5J
0.03.1
1
1.1
0.08.1
MW-6(dup)
20-Apr-16
70J
0.1
7.1
0.6J
0.03.1
1
1.1
0.07.1
MW-6
14-Sep-16
0.191E
0.29J
210
0.131
19
2.1JB
0.032JB
9.1
1.1J
0.084.1
1.2J
6.OJB
MW-6
20-Apr-17
120
2.5J
8.3J
0.98.1
0.40
4.2J
MW-6(dup)
20-Apr-17
130
2.6J
8.2J
1.OJ
0.41
4.8J
21
MW-6
21-Sep-17
160
5.3.1
2.2J
7.6J
MW-6
12-Apr-18
130
0.14J
7.9J
4.6J
MW-6
24-Oct-18
240
0.13.1
1.1
18
1.5J
6.9J
MW-6
22-Apr-19
120
0.17.1
0.13.1
19
0.17.1
4.5J
MW-6
7-Nov-19
270
0.18.1
67
1.6J
0.1613.1
18
2.5J
0.281
6.4.1
MW-6(dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
77
NA
NA
NA
NA
NA
NA
0.321
NA
NA
MW-6
7-Apr-20
130
0.49
0.25.1
8
20
5.5
1.6
0.19.1
6.4
5.2
8.6.1
MW-6
15-Oct-20
160
0.14J
33
8.5
0.201
2.61
MW-6
31-Mar-21
94
0.32.1
0.17.1
3.8J
23
2.31
0.88J
0.19.1
3.8J
3.8J
4.41
MW-6(dissolved)
31-Mar-21
NA
NA
NA
NA
NA
NA
25
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-6
10-Nov-21
230
0.24.1
9.0
2.2J
7.9
MW-6
29-Mar-22
220
0.17.1
11
1.7J
0.14J
7.0
1.7J
MW-6
11-Oct-22
270
0.14J
5.1
2.1J
7.2
MW-6
5-Apr-23
140
2.8J
4.0J
1.31
0.25J
0.16J
3.31
3.21
2.6J
CDM
Smith Page 2 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Ln
26-Apr-12
1.591
72J
5.68J
,,,
7.24JB
15
2.37J
1
100
2.61J
41
,,,
6.97.1
MW-6d
MW-6d (dup)
26-Apr-12
1.22J
66J
5.531
6.45JB
2.10J
2.20J
3.78.1
5.88.1
MW-6d
23-Oct-12
1.21J
2.84.1
71.1.1
0.407J
4.831
2.83.1
2.11J
3.59.1
6.02.1
MW-6d
18-Apr-13
3.11
80J
0.11
0.5.1
4J
0.91
3J
0.4.1
21
8JB
MW-6d (dup)
18-Apr-13
2.81
70J
0.09.1
0.4.1
4J
0.8J
3J
0.4.1
21
6J13
MW-6d
17-Oct-13
6.9
80J
0.11
0.5.1
4J
1.1
4J
0.6J
0.03.1
31
31
7J13
MW-6d
17-Apr-14
1.21
60J
0.11
0.1J
4J
1.0.1
2J
0.3.1
21
61
7J13
MW-6d
12-Nov-14
1.21
60J
0.11
0.2.1
3J
1.1
2J
0.3.1
21
4J13
MW-6d
30-Apr-15
1.71
0.6J
50J
0.08.1
0.1J
4J
0.91
2J
0.2.1
21
31
4.1
MW-6d (dup)
30-Apr-15
2.11
80J
0.05.1
0.2.1
4J
0.91
2J
0.3.1
0.05.1
21
31
6J13
MW-6d
15-Oct-15
1.11
60J
0.11
0.2.1
4J
0.6J
2J
0.4.1
0.04.1
3J
21B
6.1
MW-6d
20-Apr-16
0.41
50J
0.07.1
0.1J
4J
0.6J
2J
3J
4.1
MW-6d
12-Sep-16
1.01
65J
0.21.1
4.4J
0.85J
6.6JB
1.7J
2.41
0.341
4.7J
15
MW-6d
20-Apr-17
51J
2.6J
2.41
1.6J
2.6J
9.1J
MW-6d
22-Sep-17
0.66.1
33J
4.2J
3.1J
4.1J
6.3.1
MW-6d
13-Apr-18
1.01
41J
3.8J
1.4J
7.6.1
MW-6d
24-Oct-18
31J
7.9J
2.41
3.5J
MW-6d
23-Apr-19
57J
0.15.1
8.2J
5.31
0.51J
2.9J
8.2J
6.5.1
MW-6d
6-Nov-19
0.55.1
70
0.81
4.41
3.5J
0.39J
2.2J
3.5J
16
MW-6d
7-Apr-20
0.75.1
69
0.36.1
4.41
2.41
0.39J
1.91
9.5.1
MW-6d
13-Oct-20
2.8
130
0.25.1
3.4J
1.5J
0.33J
1.7J
19
MW-6d
31-Mar-21
0.781
85
0.17.1
4.2J
2.1J
0.25J
1.6J
3.OJ
8.5.1
MW-6d
10-Nov-21
32
0.16.1
0.20.1
3.2J
0.097J
3.2J
2.5.1
MW-6d
29-Mar-22
27
3.7J
1.1
1.7J
2.8J
MW-6d
11-Oct-22
31
2.OJ
2.9J
MW-6d
5-Apr-23
31
3.7J
3.1J
MW-6d (dup)
5-Apr-23
31
3.7J
3.1J
MW-7
26-Apr-12
50.3J
0.8051
13.3
27.1
10.76
4.04J
10.91
3.63J
7.24J
13.9
MW-7
22-Oct-12
80.7J
29.6
30.8
37.4
6.69J
11.5J
2.02J
0.152J
24.2J
24.1
MW-7
16-Apr-13
80.1
0.5J
0.6J
35
27
61
9.1
0.18.1
13J
2J
0.21
24J
25B
MW-7
16-Oct-13
60J
0.1J
0.61
5J
37
11
1.1
0.04.1
12J
3J
12J
11B
MW-7
16-Apr-14
50J
0.2J
1.1
101
46
19
3.1
0.04.1
17J
3J
0.091
23J
40B
MW-7
11-Nov-14
0.5.1
70J
0.4J
0.7J
23
26
45
7.1
0.28
13J
2J
0.21
5J
22
MW-7
30-Apr-15
60J
0.11
0.91
5J
48
11
2.1
0.04.1
17J
0.08J
33
MW-7
14-Oct-15
40J
0.1J
0.4J
7J
30
10
2.1
0.02.1
10J
1J
0.05J
31
MW-7
20-Apr-16
40J
0.06J
1.0
2J
52
7J
2.1
0.03.1
17J
2J
11
MW-7
13-Sep-16
0.24.1
44J
1.6
1.4J
41
5.5JB
1.1J
12J
4.OJ
13
MW-7
18-Apr-17
34J
0.13J
0.83J
6.1J
31
30
16
0.037J
9.2J
8.11
7.4J
MW-7
18-Sep-17
0.52.1
27J
23
1.11
6.8J
MW-7
11-Apr-18
41J
1.5
3.7J
32
7.6J
1.1J
111
5.7J
29
MW-7(dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
31
NA
NA
NA
NA
NA
NA
NA
NA
MW-7
25-Oct-18
52J
1.3
3.1
34
22
8.6.1
101
8.6J
30
MW-7 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
37
NA
NA
NA
NA
NA
NA
NA
NA
MW-7
24-Apr-19
35J
17
6.4J
12
MW-7
4-Nov-19
46
0.381
0.84
13
27
38
10
0.17131
8.9
0.261
0.181
26
24B
MW-7
8-Apr-20
48
0.451
3.8J
41
9.8
2.8
11
5.7
41
MW-7 (dissolved)
8-Apr-20
NA
NA
NA
NA
NA
NA
44
NA
NA
NA
NA
NA
NA
NA
NA
MW-7
14-Oct-20
40
0.301
35
1.4J
9.1
9.11
MW-7
31-Mar-21
46
0.371
3.2J
47
10
2.5
13
8.1
17
MW-7 (dissolved)
31-Mar-21
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-7
9-Nov-21
28
0.20J
20
0.29J
7.0
MW-7
30-Mar-22
32
34
3.2J
10
5.41
M W -7
12-Oct-22
29
40
10
2.91
MW-7
4-Apr-23
34
0.42.1
32
8.5
16
CDM
Smith Page 3 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
In
,,,
15
1
100
,,,
MW-8
24-Apr-12
0.937J
41.3.1
1.21J
3.19J
1.83.1
515
MW-8
22-Oct-12
41.8.1
0.146.1
0.404J
1.20J
2.76J
1.97.1
MW-8
17-Apr-13
0.8.1
50J
0.08.1
2J
1.1
0.03.1
4J
9J13
MW-8
16-Oct-13
50J
0.1J
0.2.1
2J
2.1
41
MW-8
16-Apr-14
50J
0.07.1
11
1.1
51
51
107
MW-8
12-Nov-14
50J
0.6J
0.4.1
51
51B
MW-8
30-Apr-15
801
0.11
0.1J
4J
2.1
2J
0.2.1
71
14
MW-8
15-Oct-15
801
0.08.1
0.1J
2J
2.1
0.3J
0.04.1
61
6.1
MW-8
21-Apr-16
70J
0.8J
2.1
0.02.1
6J
0.05J13
6.1
MW-8
14-5ep-16
65J
0.13.1
1.9.1
0.27J13
6.6J
2.9J
8.5JB
MW-8
20-Apr-17
61J
4.9J
1.81
4.7.1
MW-8
18-5ep-17
73J
0.14J
0.85J
4.6J
3.01
5.7.1
M W -8
12-Apr-18
65J
4.2.1
5.2J
4.5.1
MW-8
24-Oct-18
71J
2.71
5.OJ
7.0.1
MW-8
22-Apr-19
110
1.1
9.4J
0.11.1
8.2J
2.6J
120
MW-8 (dup)
22-Apr-19
110
9.5J
8.1J
2.5J
5.6.1
MW-8
7-Nov-19
48
6.4
1.61
2.5J
0.326
5.4
6.0
12
MW-8 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
1.5.1
NA
NA
NA
NA NA
NA NA
2.6J
NA
MW-8
9-Apr-20
43
2.5J
4.8J
8.4.1
M W -8
15-Oct-20
81
6.6
8.1
5.8.1
MW-8
31-Mar-21
63
0.63
13
2.3.1
3.1
0.51J
6.4
8.9
11
M W -8
10-Nov-21
95
4.7.1
8.4
5.1J
MW-8
29-Mar-22
86
8.8
11 1.41
5.6.1
MW-8
11-Oct-22
110
1.4J
11
1.4J
12
0.161
2.6J
5.9.1
MW-8
5-Apr-23
90
2.1
9.8
9.9
5.7.1
MW-8d
26-Apr-12
1.63J
34.5.1
11B
2.82J
4.15.1
7.52.1
MW-8d
24-Oct-12
1.591
30.6.1
0.481
5.46J
3.21.1
4.79.1
9.99.1
MW-8d
18-Apr-13
0.6J
20J
4J
0.3.1
11
0.2.1
11
0.061
2JB
MW-8d
17-Oct-13
40J
0.2J
0.3.1
6J
1.1
6J
1.1
0.03.1
2J
7J
MW-8d
17-Apr-14
0.9.1
20J
0.1J
4J
0.4.1
2J
0.3.1
0.8J
7J
5JB
MW-8d
12-Nov-14
1.01
20J
4J
0.3.1
2J
0.3.1
0.91
2JB
MW-8d
30-Apr-15
2.5J
0.61
20J
0.1J
1
0.4.1
11
0.4.1
11
2J
4.1
MW-8d
15-Oct-15
0.2.1
20J
3J
0.06J
0.05.1
0.5J
1JB
MW-8d
21-Apr-16
20J
1
0.5J
MW-8d
14-5ep-16
16J
1.7J
0.60JB
0.047JB
0.72J
4.8J
2.OJB
MW-8d
20-Apr-17
19.1
2.6J
4.1
4.OJ
3.1J
MW-8d
18-5ep-17
16J
2.9J
3.1
MW-8d (dup)
18-5ep-17
17J
3.2J
2.8J
MW-8d
12-Apr-18
17J
3.5J
MW-8d
23-Oct-18
18J
6.5J
2.2J
4.4J
MW-8d (dup)
23-Oct-18
17J
6.1
2.OJ
4.5J
MW-8d
23-Apr-19
17J
4.OJ
3.9J
MW-8d
6-Nov-19
21
0.22.1
3.9J
3.2J
1.4J
3.9J
14
MW-8d
8-Apr-20
0.50.1
28
0.25.1
4.5J
0.45J
5.81
MW-8d
13-Oct-20
1.3J
25
0.55
3.7J
1.7J
0.25J
3.9J
15
MW-8d
31-Mar-21
1.51
35
0.21.1
4.8J
3.2J
1.5
1.1
6.1
8.41
MW-8d (dup)
31-Mar-21
2.6
35
0.23.1
6.9
4.7J
1.8
2.5J
8.4
12
MW-8d
10-Nov-21
16
3.1J
4.2J
MW-8d
29-Mar-22
17
3.6J
4.1
MW-8d
11-Oct-22
3.2.1
3.51
MW-8d
5-Apr-23
16
3.1J
4.01
CDIN Page 4 of 31 June 2023
Smith

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-9
25-Apr-12
176
0.220J
5.68J
4.81J
2.72J
13.5
MW-9
23-Oct-12
5.17J
210
0.711J
4.13
19.7
6.96J 17.1
27.2 3.41J 7.491
0.5211
iliiiii§ 141
MW-9
17-Apr-13
160
0.31B
2
3J
41 4J
4J 4J
0.3.1
8J 27B
MW-9
16-Oct-13
120
0.2J
1.1
2J
0.41 2J
1J 2J
0.2.1
6J 16B
MW-9
16-Apr-14
130
0.4J
1.3
4J
0.81 5J
4J 3J
0.3.1
16J 36B
MW-9
12-Nov-14
120
0.3J
0.41
4J
0.61 4J
3J 2J
0.2.1
17
MW-9 (dup)
12-Nov-14
140
0.5J
0.41
6J
11 6J
6J 21
0.3J
4.1 28
MW-9
29-Apr-15
0.7J
901
0.11
0.31
2J
0.11 1J
0.8J 0.8J
0.2.1
3.1 81
MW-9
15-Oct-15
160
0.71
0.21
91
11 6J
71 0.071 1J
0.3.1
111E 31
MW-9
20-Apr-16
150
0.21
2J
0.21 1J
0.A 0.91
0.1J
31
MW-9
13-Sep-16
100
0.151
0.121
1.7J
1.3JB
1.01 1.2J
0.161
111E 9.41
MW-9
19-Apr-17
130
2.11
1.OJ
0.52J
7.4.1 4.61
MW-9
21-Sep-17
160
1.4
0.37J
1.9J 11
M 2.1J
0.40J
34 49
M
MW-9 (dissolved)
21-Sep-17
NA
NA
NA
NA
NA
NA
NA NA NA NA
NA
111 NA
MW-9
11-Apr-18
130
0.16J
3.2J
0.61J 3.OJ
0.20J
5.5.1 4.5J
MW-9 (dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
NA NA
NA NA NA NA
NA
5.6.1 NA
MW-9
25-Oct-18
89J
2.1J
0.151
111
MW-9
25-Apr-19
150
1.1
2.3J
0.39J 2.41
7.1.1 6.9J
MW-9
7-Nov-19
230
0.17J
1.5
3.8J
11
2.1 0.22 4.7J 1.7.1
0.22J
10 57
MW-9 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
NA NA
NA NA NA NA
NA
0.21J
6.7 NA
MW-9
9-Apr-20
270
2.8J
0.44J 6.4
0.21J
3.9J 30
MW-9
15-Oct-20
0.96J
320
1.3
2.3J
0.58J 5.5
0.21J
9.9 14
MW-9
31-Mar-21
390
0.15J
2.7
2.41
1.4J 11
1.4 8.9
0.16J
9.3 25
MW-9
9-Nov-21
360
2.8
4.4J 8.5
0.25J 9.2
0.25J
31
MW-9
30-Mar-22
370
0.33J
7.8
3.9J
4.4J 65
3.4 10
0.60J
0.36J
6.7 47
MW-9 (dissolved)
30-Mar-22
NA
NA
NA
NA
6.4
NA
NA NA
NA NA NA NA
NA
NA
NA NA
MW-9
12-Oct-22
0.58J
340D
0.23J
2.1
2.OJ
6.8 23
0.92J 7.9
0.25J
0.22J
3.6J 24
MW-9
4-Apr-23
360D
0.23J
4.4
1.3J
7.2 16
1.6 0.18J 5.6
0.55
2.8J 31
MW-10
25-Apr-12
34.7J
0.320J
0.438J
1.79J
2.04J
4.81J
2.64J
0.538
2.25J
21.7
MW-10
23-Oct-12
31.1J
0.302J
0.965J
2.07J
2.511
2.57J
0.910
2.07J
16.5
MW-10
17-Apr-13
30J
0.3JB
0.4J
0.4J
2J
2JB
11
0.43
3J
0.06J
14B
MW-10
16-Oct-13
30J
0.3J
0.2J
0.4J
2J
2J
11
0.29
3J
0.05J
4J
9JB
MW-10
16-Apr-14
30J
0.3J
0.2J
2J
11
0.5J
0.05J
3J
4J
38B
MW-10
12-Nov-14
30J
0.3J
2J
0.03J
3J
9JB
MW-10
29-Apr-15
0.2J
40J
0.3J
0.1J
3J
2J
11
0.101
5J
0.05J
10
MW-10
14-Oct-15
30J
0.3J
0.2J
2J
0.8J
0.4J
0.08J
3J
27
MW-10
20-Apr-16
30J
0.3J
0.1J
4J
0.6J
0.3J
0.03J
5J
11
0.05J
4J
MW-10
13-Sep-16
0.47J
31J
0.36J
0.19J
3.8J
2.OJB
1.2J
0.14J
4.8J
3.6J
280
MW-10
19-Apr-17
27J
0.32J
2.9J
0.93J
0.38J
0.064J
3.4J
17
MW-10
22-Sep-17
17J
0.18J
1.3J
2.2J
0.30J
2.3J
2.1.1
8.91
MW-10
11-Apr-18
20J
0.32J
0.87J
1.9J
2.4J
1.3J
0.55J
0.27
2.5J
51
MW-10
25-Oct-18
24J
0.16J
0.72J
2.3J
0.57J
0.39
2.7J
7.4J
77
MW-10 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
2.6J
NA
NA
NA
NA
NA
NA
NA
NA
MW-10
25-Apr-19
25J
1.7J
2.7J
0.45J
5.1J
2.5J
MW-10
7-Nov-19
20
0.24J
2.6J
2.6J
0.50J
0.12J
4.3J
2.5J
66
MW-10(dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
2.2J
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-10
7-Apr-20
23
0.17J
1.3J
2.7J
0.61J
0.14J
4.OJ
15
MW-10
15-Oct-20
12
0.49J
1.41
1.5J
0.32J
2.41
33
MW-10
31-Mar-21
16
0.16J
1.1
5.8
0.47J
0.097J
4.OJ
4.5J
31
MW-10
10-Nov-21
17
0.20J
0.65
2.3J
17
MW-10
30-Mar-22
17
0.16J
0.77
2.8J
1.4J
6.7
0.271
3.7J
19
MW-10
12-Oct-22
16
0.19J
0.44J
1.81
15
MW-10
5-Apr-23
27
0.221
0.351
3.21
0.27
2.8J
30
Smith Page 5 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-10d
26-Apr-12
0.232J
4.36J
3.50J
3.47JB
4.57J
MW-10d
24-Oct-12
3.11J
MW-10d
18-Apr-13
4JB
11B
0.07J
0.7J
i1
MW-10d
16-Oct-13
0.3J
3JB
0.2J
i1
0.05J
0.7J
0.6J
MW-10d
17-Apr-14
2J
0.4J
0.6J
41
3JB
MW-10d
12-Nov-14
3J
0.5J
0.04J
0.4J
MW-10d
30-Apr-15
0.81
0.5J
3J
0.3J
0.1
0.05J
0.6J
4J
MW-10d
15-Oct-15
0.5J
5J
0.07J
0.81
0.081
11
0.2J
0.07J
0.6J
5J
MW-10d
21-Apr-16
0.3J
5J
0.2J
2J
i1
2J
6J
MW-10d
14-Sep-16
2.5J
0.67JB
0.15J
3.31
5.5JB
MW-10d
19-Apr-17
2.5J
0.14J
0.70J
MW-10d
18-Sep-17
4.1J
0.35J
1.4J
3.1J
0.32J
6.9J
MW-10d
11-Apr-18
0.60J
3.7J
0.60J
1.8J
2.11
0.34J
14
MW-10d
25-Oct-18
2.5J
MW-10d
25-Apr-19
2.8J
3.OJ
MW-10d
5-Nov-19
3.7J
0.14J
1.1
0.34J
0.098BJ
6.2BJ
MW-10d
9-Apr-20
2.8J
2.7J
MW-10d
14-Oct-20
2.3J
3.4J
MW-10d
31-Mar-21
1.4)
4.5J
0.27J
3.6J
2.OJ
0.29J
3.4J
10
MW-10d
9-Nov-21
0.72J
4.3J
0.53
2.31
4.4J
0.45J
2.OJ
8.6J
MW-10d
29-Mar-22
0.59J
5.5
0.70
3.OJ
12
0.81J
1.5J
10
MW-10d
12-Oct-22
17
3.5J
4.4J
MW-10d
5-Apr-23
0.85J
4.6J
0.29J
1.7J
0.31J
9.3J
MW-22
25-Apr-12
61.5J
0.224J
4.78
4.77J
63.8
14J
2.56J 0.162J
33.1
18.4
MW-22
23-Oct-12
34.7J
8.27
2.28J
44.7
16.8J
4.02J
19.2
MW-22
17-Apr-13
70J
0.11
4
0.91
76
11B
0.7J
15J
0.06J
12B
MW-22
16-Oct-13
50J
0.1J
3.5
11
25
11
11
101
1
8JB
MW-22
16-Apr-14
50J
0.1J
2.5
0.91
43
11
11
14J
4J
14B
MW-22
12-Nov-14
40J
0.1J
2.5
3J
17
2J
21
101
91
MW-22
30-Apr-15
50J
1.5
0.6J
31
0.7J
0.61
101
91
MW-22
15-Oct-15
801
0.7J
3.4
91
29
5J
91 0.051
13J
4J 0.2J
14JB
56
MW-22
20-Apr-16
40J
0.07J
1.3
18
0.5J
0.31
7J
6J
MW-22
13-Sep-16
82J
0.82J
3.1
12
38
6.9JB
11
14J
3.11 0.20J
181
47
MW-22
19-Apr-17
45J
0.261
2.8
1.91
18
2.6J
1.61
6.5J
0.93J
6.41
13
M W-22
18-Sep-17
M W-22
13-Apr-18
MW-22
23-Oct-18
3
Not Sampled
MW-22
23-Apr-19
MW-22
4-Nov-19
MW-22
8-Apr-20
MW-22
14-Oct-20
48
0.16J
1.5
2.31
40
1.71
3.2
11
3.6J
14
MW-22
31-Mar-21
27
0.91
18
0.271
4.81
7.61
MW-22
10-Nov-21
31
1.9
1.7J
34
2.5J
0.351
12
15
MW-22
30-Mar-22
30
0.371
40
11
8.81
MW-22
13-Oct-22
37
3.3
29
13
8.21
MW-22
3-Apr-23
Not Sampled
(3�
CDM
Smith Page 6 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
LI
,,,
15
1
,,,
100
MW-23
26-Apr-12
42.7J
6.68J
1.61
10.413
7.07J
4.20J
12.5J 17.5
MW-23
24-Oct-12
38.9J
5.76J
1.81
8.02J
4.12J
3.92J
13.3J 18.5
MW-23
18-Apr-13
0.2J
240
1.8
0.11
30
15
56
30
0.06J
28J
11
106 147
MW-23
16-Oct-13
30J
0.2J
0.1J
3J
0.7J
4J
2J
0.02J
2J
5J 6JB
MW-23
16-Apr-14
50J
0.1
0.2J
7J
2J
10
5J
4J
0.11
16J 25B
MW-23
12-Nov-14
50J
0.4J
7J
2J
12
6J
0.02J
5J
0.11
12J 19
MW-23
30-Apr-15
0.4J
50J
0.1
7J
21
13
6J
0.03J
6J
0.11
15J 26
MW-23
15-Oct-15
110
1.1
20
7J
34
18
0.06J
16J
0.51
39 69
MW-23 (dup)
15-Oct-15
170
1.6
32
11
51
30
0.12J
25J
0.81
60 112
MW-23
20-Apr-16
40J
0.1
5J
11
91
5J
4J
0.11
91 21
MW-23
13-Sep-16
54J
0.59J
0.081
8.9J
3.3J
15B
7.7J
6.91
0.22J
23J 39
MW-23
19-Apr-17
26J
0.191
3.1
4.5J
2.1J
2.4J
6.51 7.2J
MW-23
20-Sep-17
110
1.5
0.14J
19
6.6J
33
17
16J
0.48J
59 67
MW-23 (dissolved)
20-Sep-17
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.1 NA
MW-23
11-Apr-18
85J
0.86J
0.22J
12
4.4J
21
11
14J
0.28J
30 44
MW-23 (dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-23
25-Oct-18
51J
0.26J
0.62J
9.2J
3.1J
12
5.6J
8.1
0.191
21J 45
MW-23 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-23
25-Apr-19
42J
0.19J
5.6J
1.81
8.OJ
4.6J
4.2J
13J 30
MW-23 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-23
5-Nov-19
39
0.35J
6.0
1.7J
10
5.3
4.1
0.23J
13 24B
MW-23 (dissolved)
5-Nov-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.20J
NA
MW-23
8-Apr-20
110
0.44
12
4.6J
26
18
9.2
0.23J
28 39
MW-23 (dissolved)
8-Apr-20
NA
NA
NA
NA
NA
1.7J
NA
NA
NA
NA
NA
NA
MW-23
14-Oct-20
19
1.91
1.8J
1.0
3.8J 2.8J
MW-23
31-Mar-21
25
4.2J
6.2
3.0
2.7J
9.1 12
MW-23
10-Nov-21
11
1.4J
0.39J
3.OJ
MW-23
30-Mar-22
26
2.5J
14J
MW-23
13-Oct-22
19
0.171
3.6J
2.9J
1.6
2.4J
6.1 4.6J
MW-23
4-Apr-23
23
3.OJ
2.7J
1.3
1.5J
5.2 4.51
MW-23d
25-Apr-12
0.754J
35J
0.746J
4.03J
16.86
3.32J
4.05J
6.65J
MW-23d
23-Oct-12
0.552J
33.2J
0.644J
4.73J
4.38J
4.48J
8.66J
MW-23d
18-Apr-13
2.6J
40J
1.5
3JB
0.3J
4J
0.4J
1J
12B
MW-23d
17-Oct-13
1.71
40J
0.05J
0.7J
2J
0.3J
31
0.3J
0.02J
1J
3J
3JB
MW-23d
17-Apr-14
1.3J
30J
0.3J
2J
0.3J
21
0.3J
1J
6J
8JB
MW-23d
13-Nov-14
1.11
40J
0.2J
2J
0.3J
21
0.3J
0.81
2J
6J
MW-23d
29-Apr-15
1.6J
40J
0.2J
2J
0.3J
2J
0.3J
0.91
2J
6J
MW-23d
15-Oct-15
3.6J
40J
0.04J
0.5J
3J
0.4J
4J
0.6J
0.05J
1J
2JB
13
MW-23d
20-Apr-16
1.11
40J
0.2J
3J
0.3J
2J
0.2J
4J
7J
MW-23d
13-Sep-16
1.2J
37J
0.23J
2.1
0.26J
2.5JB
0.48J
2.5J
6.1J
13
MW-23d (dup)
13-Sep-16
0.971
36J
0.22J
1.9J
2.2JB
0.36J
2.2J
5.7J
10
MW-23d
19-Apr-17
0.531
34J
0.24J
2.OJ
4.9J
1.4J
3.7J
6.9J
MW-23d
21-Sep-17
34J
2.7J
3.8J
3.51
5.81
MW-23d
10-Apr-18
38J
5.2J
2.4J
0.32J
1.8J
2.61
3.41
MW-23d (dup)
10-Apr-18
36J
4.8J
2.31
1.7J
3.11
MW-23d
23-Oct-18
36J
14
7.OJ
4.01
MW-23d
23-Apr-19
41J
2.2J
3.91
MW-23d
4-Nov-19
1.71
34
0.91
2.2J
4.11
0.35J
0.09613J
1.31
3.81
21B
MW-23d
8-Apr-20
1.11
33
0.80
3.5J
3.5J
0.47J
1.5J
29
MW-23d
13-Oct-20
7.3
34
0.93
2.1J
3.2J
0.51J
1.5J
3.71
29
MW-23d (dup)
13-Oct-20
7.6
35
0.92
2.4J
3.4J
0.64J
1.6J
3.6J
25
MW-23d
31-Mar-21
0.61J
37
0.21J
9.8
2.9J
0.26J
1.1
3.7J
14
MW-23d
9-Nov-21
35
2.OJ
3.9J
MW-23d (dup)
9-Nov-21
35
1.91
3.8J
MW-23d
29-Mar-22
35
2.OJ
1.6J
1.1
3.8J
MW-23d (dup)
29-Mar-22
36
2.2J
4.1J
MW-23d
12-Oct-22
39
2.4J
3.9J
MW-23d (dup)
12-Oct-22
39
2.5J
4.2J
MW-23d
4-Apr-23
0.681
41
0.231
1.6J
1.91
4.01
8.6J
CDIN Page 7 of 31 June 2023
Smith

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-24
26-Apr-12
57.61
0.2811
7.541
7.0916
9.80J
3.35J
1.821
0.190J
8.381
58.7
MW-24
23-Oct-12
35.91
2.101
2.501
4.01J
0.120J
5.341
28.3
MW-24
17-Apr-13
120
1.41
0.11
91
21
11
17
0.24
51
0.5.1
17J
128
MW-24
16-Oct-13
60J
0.61
0.11
41
0.91
5J
7.1
0.091
2J
0.2.1
8.1
46
MW-24
16-Apr-14
120
1.1
61
21
91
14
0.171
4J
0.4.1
22J
120
MW-24
12-Nov-14
130
1.5
81
21
11
17
0.21
51
0.6.1
14J
117
MW-24
29-Apr-15
80J
0.81
41
11
7J
9.1
0.121
1
0.3.1
101
69
MW-24
14-Oct-15
240
2.5
0.21
41
18
0.43
7J
0.9.1
182
MW-24
20-Apr-16
170
1.8
31
13
0.21
6J
0.7.1
140
MW-24
13-Sep-16
34J
0.371
0.0861
1.41
0.551
2.31B
3.61
1.51
0.121
7.5.1
31
MW-24
19-Apr-17
66J
0.771
3.81
0.981
5.0J
7.91
0.0861
2.51
0.241
9.1J
56
MW-24
20-Sep-17
51J
0.761
3.91
0.711
4.6J
5.81
2.4.1
0.191
7.5.1
47
MW-24 (dissolved)
20-Sep-17
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.6J
NA
MW-24
11-Apr-18
62J
0.75.1
4.81
5.0J
7.11
2.6J
0.221
6.9.1
49
MW-24 (dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-24
23-Oct-18
MW-24
24-Apr-19
(')
Not Sampled
MW-24
4-Nov-19
MW-24
8-Apr-20
0
2.51
MW-24
31-Mar 21
I
15
10.20J
I 1.71
I
I
0.801
I
3.2J
I 7.6.1
MW-24
9-Nov-21
Not Sampled(')
MW-24
30-Mar-22
I
I 19
I
I
I 2.91
I
I
10.61J
I
I 1.81
I
I
I 2.6.1
I 5.6.1
M W-24
13-Oct-22
(3)
Not Sampled
MW-24
3-Apr-23
MW-28
26-Apr-12
67.7.1
14.2
3.901
2.81.113
5.18J
5.84J
0.2291
20.71
69.8
MW-28
18-Apr-13
60J
0.31
10
3.1
11
11
41
0.2J
101
34B
MW-28
17-Apr-14
170
1.5
41
14
5J
71
0.021
20J
1.0.1
53
159
MW-28
30-Apr-15
801
0.51
16
5J
2J
21
0.021
71
0.4J
22J
62
MW-28
21-Apr-16
20J
4J
0.06J
91
MW-28
20-Apr-17
29J
0.181
3.9J
0.301
1.31
6.1.1
11
MW-28
13-Apr-18
55J
0.411
11
2.7J
1.3.1
5.11
0.161
15J
22
MW-28 (dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2.6.1
NA
MW-28
25-Apr-19
56J
0.171
8.91
2.6J
1.21
4.41
0.151
15J
37
MW-28 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2.8J
NA
MW-28
8-Apr-20
76
0.311
4.7J
2.5
7.1
0.381
24
54
=
MW-28 (dissolved)
8-Apr-20
NA
NA
NA
NA
NA
3.21
NA
NA
NA
NA
NA
NA
NA
MW-28
31-Mar-21
32
0.161
5.7
2.6J
1.1
1.91
8.4
29
MW-28
29-Mar-22
33
0.201
6.3
1.31
1.6J
0.90J
2.21
1.1
9.5
22
MW-28
5-Apr-23
33
0.231
5.9
0.69J
1.81
9.4
15
MW-28d
26-Apr-12
1.46.1
28.7.1
10.1
1.341
13.36
4.99J
9.42J
4.731
106
MW-28d
18-Apr-13
0.31
91B
2113
0.11
0.91
0.91
4113
MW28d
17-Apr-14
0.41
11
6J
41
0.41
31
1.01
51
61
106
MW28d
30-Apr-15
0.21
10J
21
0.091
0.61
0.91
71
MW28d
21-Apr-16
9.1
21
0.81
91
91
MW28d
20-Apr-17
8.1J
1.31
0.681
3.3.1
5.91
MW28d
13-Apr-18
5.8.1
1.91
6.91
MW28d
25-Apr-19
7.1J
2.01
1.51
1.5J
3.31
9.91
MW-28d (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2.51
NA
MW28d
8-Apr-20
7.3
2.61
1.31
9.11
MW28d
31-Mar-21
15
2.91
3.81
1.2
6.3
6.7
15
MW28d
29-Mar-22
0.551
13
2.61
7.0
1.4
2.41
1.31
5.2
31
MW28d
5-Apr-23
1.9J
6.8
2.8J
0.681
2.11
11
11
MW-28d (dissolved)
5-Aor-23
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Smith Page 8 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-29d
26-Apr-12
0.317J
41.5J
6.48J
8.73JB
3.94J
1.97J
3.72J
23.2
MW-29d
24-Oct-12
38.OJ
4.87J
6.36J
2.48J
4.36J
7.64J
MW-29d
18-Apr-13
40J
0.081
4J
0.4J
5J
0.3J
11
0.05J
3JB
MW-29d
17-Oct-13
40J
0.11
4J
0.2J
3J
11
MW-29d
17-Apr-14
40J
0.081
3J
0.2J
3J
0.81
5J
25B
MW-29d
13-Nov-14
40J
0.07J
3J
0.5J
4J
0.3J
2J
2J
MW-29d
29-Apr-15
0.2J
0.5J
40J
0.11
4J
0.3J
41
0.3J
11
13
MW-29d
15-Oct-15
0.2J
40J
0.11
4J
0.3J
41
0.6J
0.04J
11
81
MW-29d
21-Apr-16
0.6J
40J
4J
0.3J
5J
0.2J
11
6J
MW-29d
12-Sep-16
0.38J
39J
2.7J
3.11B
0.251
0.901
4.8J
22
MW-29d
19-Apr-17
36J
2.7J
1.91
2.3J
13
MW-29d
22-Sep-17
35J
3.9J
2.81
5.9J
MW-29d
12-Apr-18
34J
3.7J
1.1
5.4J
MW-29d
24-Oct-18
34J
3.2J
3.1
2.7J
MW-29d
25-Apr-19
38J
3.1
MW-29d
5-Nov-19
33
3.4J
3.9J
0.36J
0.092BJ
2.OJ
39B
MW-29d
6-Apr-20
1.4J
43
0.241
11
19
2.5
4.1J
3.8J
30
MW-29d
14-Oct-20
1.3J
37
0.13J
3.6J
2.5J
0.38J
45
MW-29d
31-Mar-21
0.641
45
5.6
6.9
0.73J
2.0
3.31
88
MW-29d
9-Nov-21
35
2.1
MW-29d
29-Mar-22
0.67J
25
4.9J
8.9
1.4
3.1J
0.29J
140
MW-29d
13-Oct-22
1.1)
34
10
6.2
0.71J
5.0
3.5J
36
MW-29d
5-Apr-23
34
7.0
7.0
0.89J
2.5J
3.7J
56
MW-30
25-Apr-12
169
0.773J
58
9.94J
73.9
9.17J
22.7J
2.15J
0.360J
51.7
54.7
MW-30
23-Oct-12
197
57.5
11.3
80.2
9.44J
26.3
0.359J
54.4
62.6
MW-30
17-Apr-13
450
2.8
0.1J
124
24
155
17
0.04J
56
11
146
141
MW-30
16-Oct-13
220
1.4
49
91
63
6J
0.03J
21J
0.31
50
40
MW-30
16-Apr-14
220
1.4
66
11
78
7J
0.02J
26J
0.5J
73
71
MW-30
12-Nov-14
500
3.0
0.21
148
24
169
19
0.07J
59
2J
1.11
154
148
MW-30
29-Apr-15
180
1.2
59
91
67
6J
23J
0.4J
48
53
MW-30
15-Oct-15
0.41
60J
1.2
0.71
48
11
12
2J
0.05J
10J
0.06J
63
44
MW-30
21-Apr-16
150
0.81
46
7J
54
5J
0.02J
18J
0.3JB
29
38
MW-30
14-Sep-16
0.171B
50J
0.36J
0.053J
8.8J
1.61
11B
0.95J
4.5J
111
18B
MW-30
20-Apr-17
79J
0.56J
25
3.1J
28
2.2J
8.7J
0.14J
191
22
MW-30
22-Sep-17
M W-30
12-Apr-18
MW-30
24-Oct-18
3
Not Sampled
MW-30
25-Apr-19
MW-30
5-Nov-19
MW-30
8-Apr-20
MW-30
15-Oct-20
1.4J
67
0.32J
0.46J
7.1
1.3J
11
2.4
4.2J
8.4
29
MW-30 (dissolved)
15-Oct-20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
NA
MW-30
31-Mar-21
78
0.261
0.161
13
2.51
9.4
2.5
4.2J
11
24
MW-30 (dissolved)
31-Mar-21
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
NA
MW-30
9-Nov-21
MW-30
28-Mar-22
3
Not Sampled
MW-30
13-Oct-22
MW-30
3-Aor-23
CDM
Smith Page 9 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-31
25-Apr-12
33.4J
0.1221
13.1
6.71J
3.56J
5.40J
0.904J
9.25J
33.1
MW-31
23-Oct-12
35.7J
14
6.52J
3.76J
5.09J
9.26J
53.6
MW-31
17-Apr-13
70J
0.4J
24
11
14
7J
0.03J
8J
0.05J
181
29B
MW-31
16-Oct-13
30J
0.11
11
0.4J
5J
2J
5J
SJ
13B
MW-31
16-Apr-14
901
0.5J
0.21
32
2J
18
10
0.07J
8J
0.07J
35
70
MW-31
12-Nov-14
0.5J
110
0.7J
41
2J
26
14
0.081
111
0.11
37
29
MW-31
29-Apr-15
50J
0.2J
14
0.6J
7J
4J
0.03J
3J
13J
14
MW-31
14-Oct-15
0.5J
120
0.6J
38
2J
24
13
0.111
91
0.081
37
37
MW-31
21-Apr-16
0.61
70J
0.5J
30
2J
17
12
0.14J
5J
0.07JB
26
17
MW-31
13-5ep-16
29J
0.23J
13
0.64J
5.6B
3.4J
2.OJ
12J
12
MW-31
19-Apr-17
28J
8.1
3.9J
1.8J
2.6J
0.22J
5.2.1
12
M W-31
21-5ep-17
M W-31
12-Apr-18
MW-31
24-Oct-18
Not Sampledi3
M W-31
24-Apr-19
MW-31
5-Nov-19
M W-31
8-Apr-20
MW-31
15-Oct-20
41
0.221
16
7.8
3.9
7.4
14
14
MW-31 (dissolved)
15-Oct-20
NA
NA
NA
NA
NA
3.0
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
MW-31
31-Mar-21
25
115
5.3
2.1
1.6J
12
6.3J
MW-31
10-Nov-21
17
3.OJ
1.5J
4.1J
9.2J
MW-31
29-Mar-22
17
3.7J
1.1
0.33J
1.91
3.1
5.6J
MW-31
13-Oct-22
Not Sampled(3)
M W-31
3-Apr-23
MW-31d
24-Apr-12
1.68)
17. 11
6.79J
26.5
0.944J
7.62J
12.6
MW-31d
22-Oct-12
7.20J
19.3J
8.24J
1.82J
7.99J
43.5
MW-31d
16-Apr-13
O.SJ
20J
6J
0.08J
0.8JB
1J
6J
21B
MW-31d
15-Oct-13
0.81
20J
6J
0.06J
11
0.8J
SJ
16B
MW-31d
15-Apr-14
0.71
20J
5J
0.09J
0.8J
0.91
91
24B
MW-31d
11-Nov-14
O.SJ
20J
6J
0.08J
0.8J
0.7J
2J
7J
MW-31d
28-Apr-15
1.1J
20J
6J
0.07J
0.9J
0.8J
51
24
MW-31d
13-Oct-1S
1.2J
20J
0.3J
6J
0.05J
3J
0.2J
0.04J
1J
4J
30
MW-31d
21-Apr-16
20J
4J
0.7J
0.91
2J
5J
MW-31d
13-Sep-16
0.591
18J
0.14J
5.1
1.5JB
1.2J
7.2J
56
MW-31d
19-Apr-17
181
5.4J
2.6J
6.6J
53
MW-31d
18-Sep-17
191
4.4J
1.01
7.8J
2.6J
MW-31d
13-Apr-18
0.511
181
5.1
4.6J
25
MW-31d (dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4.3J
NA
MW-31d
24-Oct-18
21J
6.6J
0.28.1
1.81
9.91
4.OJ
MW-31d
24-Apr-19
21J
4.2J
7.8J
MW-31d
S-Nov-19
0.631
17
0.21J
4.1J
1.6J
0.092J
6.3
84B
MW-31d
8-Apr-20
18
4.41
0.431
7.6
20
MW-31d (dissolved)
8-Apr-20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7.3
NA
MW-31d
15-Oct-20
0.80J
19
4.41
6.6
26
MW-31d
31-Mar-21
0.99J
20
0.20J
4.9J
1.91
6.6
87
MW-31d
9-Nov-21
21
3.8J
0.28J
8.7
4.01
MW-31d
29-Mar-22
0.95J
23
0.27J
5.8
6.5
0.55J
2.6J
1.41
6.5
100
MW-31d
12-Oct-22
21
3.9J
7.7
3.41
MW-31d
4-Apr-23
1.6J
25
0.241
2.91
3.9J
0.68J
1.91
4.91
86
CDIN Page 10 of 31 June 2023
Smith

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
25-Apr-12
0.393J
3.37J
15.41
0.261J
1.92J
2.34J
,,,
8.49J
15
1
100
1.96J
5.711
,,,
6.22J
MW-32
MW-32
23-Oct-12
30J
6.71J
3.30J
27.2
5.04J
11.81
13.1
MW-32
17-Apr-13
30J
0.1
5J
3J
22
0.5J
5J
91
8JB
MW-32
16-Oct-13
70J
0.6J
0.3J
11
6J
50
0.91
101
0.11
32
25
MW-32
16-Apr-14
20J
0.1
21
21
8J
0.2J
2J
7J
10B
MW-32
12-Nov-14
50J
0.5J
11
51
37
0.91
91
0.11
15J
18
MW-32
29-Apr-15
0.6J
140
1.6
0.11
27
18
131
3J
24J
0.31
77
58
MW-32
14-Oct-15
170
1.4
0.11
29
18
135
2J
0.04J
25J
0.31
91
53
MW-32
21-Apr-16
40J
0.5J
6J
51
28
0.5J
6J
0.08JB
17J
18
MW-32
13-Sep-16
40J
0.63J
0.20J
8.5J
5.6J
27B
0.751
7.21
0.086J
181
19
MW-32
20-Apr-17
111
0.30J
1.6J
0.90J
5.1J
1.4J
2.7J
3.5J
MW-32
22-Sep-17
0.66J
14J
0.17J
1.6J
1.3J
1.3J
4.OJ
MW-32
13-Apr-18
8.5J
0.30J
1.5J
2.7J
MW-32
25-Oct-18
13J
0.26J
3.11
1.8J
1.6J
2.5J
MW-32 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
NA
MW-32
25-Apr-19
26J
0.33J
0.30J
2.6J
11
9.5J
5.OJ
4.7J
27
MW-32 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
6.2
NA
NA
NA
NA NA
NA
NA
MW-32
7-Nov-19
13
0.21J
2.41
3.6J
0.28
2.2J
3.OJ
MW-32 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
NA
MW-32
8-Apr-20
14
0.24J
3.5J
2.41
13
0.42J
3.OJ
2.5J
14
MW-32 (dissolved)
8-Apr-20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
MW-32
15-Oct-20
5.6
0.27J
5.9J
MW-32
31-Mar-21
0.62J
11
0.27J
1.81
3.5J
4.2J
1.8J
3.6J
11
MW-32
9-Nov-21
16
0.20J
2.4J
7.7
2.1J
3.1
5.2J
MW-32
29-Mar-22
9.1
0.46
1.4J
2.1J
3.2J
1.4J
5.4
2.8J
MW-32
13-Oct-22
8.0
0.17J
1.7J
3.6J
MW-32
4-Apr-23
14
0.47
2.4J
2.2J
8.3
2.1J
6.8
4.7J
TB-1a
25-Apr-12
0.269J
190
1.5
29
22
158
7.33J
0.348
27.9J
0.186J
61.3
89.4
TB-1a
23-Oct-12
85.4J
0.584J
11.3
14.8
59.6
2.35J
13.31
25
48.2
TB-1a
17-Apr-13
40J
0.06J
0.3J
5J
91
24
0.91
0.11
6J
91
11B
TB-1a
16-Oct-13
60J
0.08J
0.3J
6J
10
35
11
0.12J
91
14J
14B
TB-1a
16-Apr-14
101
1.2
0.7J
51
3J
0.3J
0.13J
3J
5J
16B
TB-1a
12-Nov-14
801
0.2J
2.7
101
91
54
2J
0.34
12J
0.08J
191
41
TB-1a
29-Apr-15
0.61
30J
0.06J
1.9
4J
51
18
11
0.22
6J
6J
17
TB-1a
15-Oct-15
70J
0.1J
2.5
8J
11
40
2J
0.22
13J
17JB
45
TB-1a
21-Apr-16
50J
0.7J
6J
6J
33
11
0.22
7J
0.06JB
6J
18
TB-1a
14-Sep-16
0.171B
99J
0.23J
1.7
12
11
72B
3.5J
0.72B
15J
0.111
29
49B
TB-1a
20-Apr-17
17J
0.37J
1.0J
3.6J
0.050J
1.9J
5.1J
5.5J
TB-1a
22-Sep-17
TB-1a
12-Apr-18
TB-1a
24-Oct-18
TB-1a
24-Apr-19
Not Sampled(3)
TB -la
5-Nov-19
TB-1a
8-Apr-20
TB -la
14-Oct-20
TB-1a
31-Mar-21
I I
19
I
I 6.6 I
6.5
I 3.2J I
4.7J
10.48J I
0.10J I
4.7J I
I
I I
3.1J
I 21
TB -la
9-Nov-21
TB -la
28-Mar-22
3
Not Sampled
TB -la
13-Oct-22
TB-1a
I 3-Apr-23
CDM
Smith Page 11 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
off
II
TB-1a deep
24-Apr-12
0.9281
15.51
11.5
3.87J
1.231
6.581
8.41J
TB-1a deep
23-Oct-12
18.01
6.851
8.29J
6.511
10.4
TB-1a deep
16-Apr-13
2.3J
20J
70.11
F6JI
81
0.51
5J
2J
16B
TB-1a deep
15-Oct-13
2.2J
201
6J
51
4J
3J
916TB-1a
deep
15-Apr-14
2.1J
20J
5J
0.41
3J
8J
17B
TB-1a deep
11-Nov-14
2.9J
30J
.
7J
5J
0.51
4J
18
TB-1a deep
28-Apr-15
2.41
30J
0.11
7.1
0.81
4J
0.41
5J
2J
12
TB-1a deep
14-Oct-15
101
4.1
0.04J
1.1
TB-1a deep
20-Apr-16
0.4J
20J
4.1
0.71
2J
0.21
3J
61
TB-1a deep
13-Sep-16
0.66J
22J
0.0701
3.1.1
0.46.1
1.7J13
0.26J
3.2.1
6.4.1
12
TB-1a deep
19-Apr-17
0.74J
25J
3.2.1
3.OJ
3.3.1
3.9.1
13
TB-1a deep
22-Sep-17
0.76J
151
3.4J
3.4J
6.8J
TB-1a deep
13-Apr-18
13J
3.1J
1.4J
0.28J
13
TB-1a deep
24-Oct-18
13J
5.2J
1.6J
6.5J
TB-1a deep
24-Apr-19
13J
151
3.9J
2.4J
TB-1a deep
5-Nov-19
1.7J
23
0.66
5.0
0.64J
2.8J
4.1J
38B
TB-1a deep
6-Apr-20
1.51
24
0.29J
2.8J
3.6J
0.61J
2.9J
65
TB-1a deep (dup)
6-Apr-20
1.91
23
0.27J
3.7J
0.55J
3.5J
70
TB -la deep
14-Oct-20
2.2
27
0.44J
2.01
2.4J
0.99J
2.41
3.1J
82
TB -la deep
31-Mar-21
0.53J
17
0.28J
4.81
2.3J
3.4J
25
TB -la deep
9-Nov-21
14
2.11
0.25J
5.6
TB -la deep
29-Mar-22
31
0.46J
2.31
3.2J
0.68J
2.4J
4.3J
71
TB -la deep
13-Oct-22
15
2.41
0.28J
5.2
4.9J
TB -la deep
4-Apr-23
15
0.19J
3.21
2.2J
0.57J
1.31
4.3J
20
MW-33
25-Apr-12
112
0.208J
44.4
15.1
37
6.44J
20.2J
0.917J
72.1
102
MW-33
17-Apr-13
70J
0.31
17
5J
13
2J
7J
34
33
51
MW-33
15-Apr-14
40J
0.6J
11
21
8J
9JB
MW-33
29-Apr-15
50J
0.07J
71
1J
3J
0.4J
3J
8J
15
MW-33
21-Apr-16
0.51
1001
0.11
4J
12
2J
71
21J
35
MW-33
20-Apr-17
29J
5.11
1.5J
5.9J
7.4J
MW-33
13-Apr-18
28J
5.31
3.3.1
6.3.1
MW-33
24-Apr-19
59J
4.31
1.6J
1.71
4.0.1
4.8.1
MW-33
8-Apr-20
71
0.25J
0.66
22
2.7
14
AM
77
3.81
MW-33 (dissolved)
8-Apr-20
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-33
31-Mar-21
56
7.3
1.71
3.7J
5.21
MW-33
29-Mar-22
31
3.21
4.11
3.21
MW-33
5-Apr-23
36
3.81
4.8.1
4.71
MW-34
26-Apr-12
0.2611
184
1.27
4.771
23.86
8.31
0.255
13.2J
37.4
53.7
MW-34
17-Apr-13
560
0.3J
90
0.45
49J
0.3J
239
282
=
M
MW-34
15-Apr-14
110
0.31
0.2J
31
1.1
0.81
0.25
21
3.1
16B
MW-34
29-Apr-15
220
1.5
0.2J
5.1
24
5.1
0.33
15J
0.1J
76
MW-34
21-Apr-16
150
0.51
91
2.1
5J
0.8.1
0.17.1
5J
0.08J13
2.1
32
MW-34
20-Apr-17
84J
0.291
4.41
1.4J
0.25
2.OJ
1.5J
13
MW-34
13-Apr-18
130
0.631
8.61
1.81
6.81
1.21
5.21
7.1J
21
NA
MW-34 (dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-34
25-Apr-19
170
0.621
0.211
14
2.51
10
1.91
0.30
6.9J
14J
30
MW-34 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
2.01
1.71
NA
NA
NA
NA
NA
NA
NA
NA
MW-34
7-Nov-19
190
1.7
0.9613
31
4.OJ
26
5.0
16
1.5J
0.2081
49
11111111
MW-34 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
4.21
NA
NA
0.49
NA
NA
NA
NA
MW-34
9-Apr-20
120
0.47
0.311
=
1.9J
7.6
1.4
0.28
6.4
7.0
35
MW-34 (dissolved)
9-Apr-20
NA
NA
NA
NA
NA
2.91
NA
NA
NA
NA
NA
NA
NA
NA
MW-34
15-Oct-20
89
0.261
4.11
1.31
2.6J
13
MW-34
31-Mar-21
240
0.91
0.301
28
13
2.4
0.131
11
16
36
MW-34 (dissolved)
31-Mar-21
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-34
11-Nov-21
83
0.291
3.41
1.71
0.181
2.6J
9.21
MW-34
30-Mar-22
150
1.11
191
12J
1.91
0.171
8.8J
17J
24J
MW-34 (dissolved)
30-Mar-22
NA
NA
NA
NA
NA
3.61
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-34
11-Oct-22
88
0.291
4.51
1.31
1.61
0.27J
0.28
3.21
14
MW-34
I 4-Apr-23
1
100
1 0.34J
5.3
1.7.1
3.OJ
0.51J
0.13.1
2.9.1
3.9J
1 13
Smith Page 12 of 31 June 2023

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
,,, 15 1 100 ,,,
MW-34d 25-Apr-12 0.575J 32.5J 8.02J 5.86JB 2.66J 1.57J 7.83J
MW-34d 16-Apr-13 0.61 20J 0.1J 0.3J 4J 0.11 1JB 0.6J 0.7J 2JB
MW-34d 15-Apr-14 0.4J 0.51 20J 0.1J 0.2J 4J 0.091 2J 0.5J 41 11B
MW-34d 28-Apr-15 0.81 20J 0.1J 0.3J 5J 0.081 1J 0.5J 0.05J 0.5J 6J
MW-34d 21-Apr-16 180 0.81 0.11 15 3J 12 2J 0.191 8J 11 0.11E 12J 35
MW-34d 20-Apr-17 20J 0.14J 6.4J 0.073J 2.01 3.OJ
MW-34d 11-Apr-18 20J 0.15J 12
MW-34d 23-Apr-19 21J 6.5J 0.46
MW-34d 6-Nov-19 25 1.8 8.7 4.3J 0.90J 0.20B 1.4J 19
MW-34d 8-Apr-20 1.2J 27 1.7 7.9 4.9J 0.90J 1.5J 19
MW-34d 15-Oct-20 3.1 28 0.82 7.1 1.6J 22
MW-34d 31-Mar-21 26 2.2 9.8 2.9J 0.27J 12
MW-34d 10-Nov-21 0.601 25 0.22J 0.20J 6.8 0.111 2.6J
MW-34d 29-Mar-22 27 0.16J 9.7
MW-34d 11-Oct-22 28 0.16J 7.4 2.5J 2.9J
MW-34d 4-Apr-23 30 7.0
MW-35
25-Apr-12
51.3J
0.616J
3.96J
2.36J
5.67J
3.101
11.3J
17.8
MW-35
17-Apr-13
60J
0.8J
0.1J
5J
2J
71
2J
41
16J
12B
MW-35
16-Apr-14
60J
1.OJ
0.3J
6J
3J
8J
2J
4J
22J
26B
MW-35
29-Apr-15
70J
1.0
0.11
7J
4J
91
2J
0.02J
5J
0.06J
22J
20
MW-35
20-Apr-16
50J
0.7J
4J
2J
5J
11
31
11J
12
MW-35
20-Apr-17
38J
0.39J
2.1
6.5.1
2.41
5.OJ
3.7J
3.9J
66
MW-35
13-Apr-18
29J
0.28J
0.24J
1.5J
3.3J
0.48J
32
MW-35
24-Apr-19
38J
0.41J
2.1J
1.61
1.6J
0.38J
1.31
3.1J
14
MW-35
9-Apr-20
36
0.4
2.2J
1.61
1.9J
0.48J
1.8J
33
MW-35
31-Mar-21
36
0.40
4.11
0.61J
3.1
11
MW-35
29-Mar-22
38
0.51
1.6J
4.4J
0.831
1.5J
1.4J
4.7J
24
MW-35
4-Apr-23
38
0.36J
1.4J
12
MW-36
25-Apr-12
64.7J
7.90J
2.61J
9.44J
4.31
12.5J
12.1
MW-36
23-Oct-12
216
68.8
18.8
84
8.62J
29.1
0.420J
91.7
72
MW-36(dup)
23-Oct-12
73.7J
11.6
3.49J
13.4
6.09J
0.121J
16.8J
18.4
MW-36
17-Apr-13
50J
0.1J
6J
2J
6J
0.5J
4J
81
12B
MW-36
16-Oct-13
0.61
60J
0.2J
7J
2J
8J
0.6J
4J
0.05J
10J
4JB
MW-36
16-Apr-14
901
0.3J
19
51
23
2J
91
0.1J
33
32B
MW-36
12-Nov-14
130
0.6J
32
91
39
3J
15J
0.1
40
46
MW-36
30-Apr-15
0.61
100J
0.3J
24
7J
27
2J
0.02J
11J
0.2J
29
27
MW-36
15-Oct-15
130
0.7J
38
10
46
3J
0.05J
16J
0.1
37
41
MW-36
20-Apr-16
70J
0.3J
13
3J
15
11
6J
0.1J
11J
17
MW-36
13-Sep-16
62J
0.24J
0.047J
11
3.OJ
10B
0.88J
5.1
0.088J
14J
16
MW-36
20-Apr-17
40J
2.8J
2.9J
1.8J
4.4J
11
MW-36
22-Sep-17
70J
0.32J
16
3.3J
18
1.3J
6.6J
20J
16
MW-36(dissolved)
22-Sep-17
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4.9J
NA
MW-36
13-Apr-18
54J
0.29J
5.41
3.31
0.75J
1.8J
3.2J
4.OJ
MW-36(dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-36
25-Oct-18
80J
0.20J
27
4.8J
20
1.6J
12J
25
25
MW-36(dissolved)
25-Oct-18
NA
NA
NA
NA
NA
2.3J
NA
NA
NA
NA
NA
NA
NA
NA
MW-36
25-Apr-19
180
0.33J
57
11
55
4.3J
18J
0.31J
55
59
MW-36(dissolved)
25-Apr-19
NA
NA
NA
NA
NA
3.8J
NA
NA
NA
NA
NA
NA
NA
MW-36
7-Nov-19
81
0.40
21
4.5J
23
1.5
0.21
8.2
0.17BJ
23
25
MW-36(dissolved)
7-Nov-19
NA
NA
NA
NA
NA
1.5J
NA
NA
NA
NA
NA
NA
NA
NA
MW-36
9-Apr-20
120
0.31J
35
7.8
35
2.8
14
0.23J
35
33
MW-36(dissolved)
9-Apr-20
NA
NA
NA
NA
NA
1.91
NA
NA
NA
NA
NA
NA
1.6
NA
MW-36
15-Oct-20
51
4.8J
3.8J
0.27J
2.6J
5.5
7.OJ
MW-36
31-Mar-21
65
21
2.81
12
0.97J
4.9J
14
12
MW-36 (dissolved)
31-Mar-21
NA
NA
NA
NA
NA
5.7
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
M W-36
11-Nov-21
46
1.31
2.4J
6.6J
MW-36
30-Mar-22
83
17J
191
7.4J
20J
21J
MW-36 (dissolved)
30-Mar-22
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-36
12-Oct-22
60
0.201
3.5J
1.51
4.2J
0.32J
2.8J
5.5
9.4J
MW-36
4-Apr-23
69
0.161
5.6
1.41
5.1
0.39J
0.13J
3.OJ
6.3
9.9J
CDIN Page 13 of 31 June 2023
Smith

Table 4a
Detected Groundwater Constituents - Metals
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Notes:
1. All units are in micrograms per liter (parts per billion).
2. * - The upper tolerance limits (UTL) were calculated as part of the North Wake Unlined Alternate Source Demonstration and were approved by the
Solid Waste Section on August 17, 2020.
3. (3) - Monitoring wells were not sampled due to an insufficient volume of water in the well.
4. dup - Duplicate Sample
5.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
6. S - Matrix spike/matrix spike duplicate failure
7. B - The analyte concentration detected in the method blank was greater than the method detection limit.
8. D - Dilution greater than 1
9. Monitoring wells MW-28, -28d, -33, and -35 are sampled yearly during the spring event.
10. Dissolved metal samples were collected to evaluate the influence of turbidity on total metal concentrations.
11. NA - Not Analyzed
Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) or UTL.
Indicates the result is below the detection limit.
CDM
Smith Page 14 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 15 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 16 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 17 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 18 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 19 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 20 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 21 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 22 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 23 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 24 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 25 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 26 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-34
26-Apr-12
0.60J
0.621
0.601
1.2
1.81
14
9
7.6
2.2
3.3
0.92J
MW-34
17-Apr-13
0.56J
0.60J
0.52J
1.1
1.8J
13
9.1
7.6
2.1
2.6
0.70J
0.191
MW-34
15-Apr-14
0.501
0.991
0.41J
1.0
1.4J
14
7.5
4.1J
1.0
2.2
0.591
MW-34
29-Apr-15
0.85J
0.35J
0.51J
0.65J
1.5
1.7J
18
0.341
10
7.2
1.3
3.0
0.64J
1.7J
MW-34
21-Apr-16
0.77J
0.71J
1.9
2.OJ
17
0.30J
11
6.4
2.3
1.01
MW-34
20-Apr-17
0.75J
0.65J
1.4
2.6J
13
0.51J
12
9.3
2.4
2.9
1.2
MW-34
13-Apr-18
0.57J
0.44J
2.1J
8.2
12
9.7
1.8
2.1
0.77J
MW-34
25-Apr-19
0.65
0.56
1.4
12
8.2
7.1
1.4
0.79
=
1.6
MW-34
6-Nov-19
0.42J
0.61
1.1
1.4
6.8
7.7
--
6.6
1.3
0.72
MW-34
4-F6-20
0.47J
0.41J
1.2
1.6
6.1
12
--
8.5
1.9
2.1
0.71
MW-34
8-Apr-20
0.67
0.54
1.5
2.1
9.1
11
--
9.9
1.9
2.6
0.91
MW-34
30-Jul-20
0.52
0.64
1.2
2.2
7.6
8.7
--
8.4
1.5
1.9
1.0
MW-34
15-Ott-20
0.41J
0.51
1.2
1.9
6.7
9.4
--
4.4
1.9
2.2
0.80
MW-34
31-Mar-21
0.43J
7.0
3.3
--
1.4
0.87
1.3
MW-34
11-Nov-21
0.49J
0.56
1.2
7.2
9.5
--
5.9
1.6
1.9
0.74
0.481
MW-34
30-Mar-22
0.53
0.52
1.1
1.6
8.8
12
--
1-1
1.6
2.3
0.57
MW-34
12-Ott-22
0.45J
0.51
1.0
5.6
7.6
--
4.9
1.3
1.5
0.62
MW-34
4-Apr-23
0.62
0.42J
1.5
1.5
8.0
11
4.5
1.6
2.1
0.54
MW-34d
25-Apr-12
0.771
0.931
MW-34d
16-Apr-13
0.83JJ
1.11
MW-34d
15-Apr-14
0.46J
0.99J
3.41
2.71
0.96J
0.58J
0.76J
0.75J
MW-34d
28-Apr-15
0.27J
0.42J
0.65J
0.70J
3.1J
2.3J
2.1J
0.54J
0.67J
0.38J
MW-34d
21-Apr-16
0.79J
0.66J
2.0
2.11
17
0.331
30
1.1
MW-34d
20-Apr-17
0.49J
1.0J
3.1J
2.9J
0.78J
0.85J
0.59J
MW-34d
11-Apr-18
1.71
1.41
0.57J
MW-34d
23-Apr-19
2.0
1.9
0.80
0.45J
0.52
MW-34d
6-N0v-19
0.40J
0.75
2.9
2.4
--
0.93
0.48J
0.55
MW-34d
4-Feb-20
0.58
0.96
1.9
--
MW-34d
8-Apr-20
0.43J
1.5
1.7
--
0.59
MW-34d
30-Jul-20
0.76
1.8
3.2
--
0.46J
0.48J
0.57
MW-34d
15-0tt-20
0.55
1.5
1.9
--
0.54
MW-34d
31-Mar-21
4.1JL
0.45J
2.3
2.2
--
1.0
0.41J
MW-34d
10-Nov-21
0.42J
0.59
1.8
3.6
--
0.65
0.65
MW-34d
29-Mar-22
1.3
2.5
-
0.451
MW-34d
11-Oct-22
0.74
1.9
--
MW-34d
4-Apr-23
1.0
2.2
-
Smith Page 27 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 28 of 31 June 2023

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Notes.
1. All units are in micrograms per liter (parts per billion(.
2. dup - Duplicate Sample
3. n) - Monitoring wells were not sampled due to an insufficient volume of water in the well.
4. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
5. B -The analyte concentration detected in the method blank was greater than the method detection limit.
6. L - Laboratory control spike/laboratory control spike duplicate failure
7. H -The analyte was out of holding time.
B. (—) - Not Analyzed. 1,4-Dioxane was removed from the sampling program for all wells on June 26, 2019, with the exceptions of MW-6, -8, and -9, due to two consecutive non -detect events.
Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2Q.
-Indicates the result is below the detection limits.
Smith Page 29 of 31 June 2023

Table 4c
Detected Surface Water Constituents - Metals and Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 30 of 31 June 2023

Table 4c
Detected Surface Water Constituents - Metals and Volatile Organic Compounds
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Notes:
1. All units are in micrograms per liter (parts per billion).
2. uI - A Standard for total chromium has not been established. The value provided is for chromium (III).
3. INS - No Standard
4. 14) - North Carolina 15A NCAC 02B (NC 28) Fish Consumption Standard
5.151- North Carolina In -Stream Target Value Freshwater Aquatic Life Standard
6. (6) - NC 2B Freshwater Aquatic Life Standard
7. lil - North Carolina In -Stream Target Value Fish Consumption Standard
8.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
9. B - The analyte concentration detected in the method blank was greater than the method detection limit.
Concentration exceeds the NC 2B or In -Stream Target Value Freshwater Aquatic Life or Fish Consumption Standard for Class C Waters -July 2021
- Indicates the result is below the detection limit.
Smith Page 31 of 31 June 2023

Table 5
Constiuents Exceeding Standards
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Facility Permit Number Monitoring April 2023 Parameters Exceeding the North Carolina 2L Monitoring April 2023 Parameters Exceeding the North Carolina 2L
Well Code or Upper Tolerance Limit Well Code or Upper Tolerance Limit
9209-MSWLF-1984 MW-11 None Detected MW-28 None Detected
9209-MSWLF-1984
MW-11d
None Detected
MW-28d
Antimony
9209-MSWLF-1984
MW-5R
Cobalt*
MW-29d
bis(2-ethylhexyl) phthalate
9209-MSWLF-1984
MW-6
None Detected
MW-30
Not Sampled (3)
9209-MSWLF-1984
MW-6d
None Detected
MW-31
Not Sampled (3)
9209-MSWLF-1984
MW-7
Cobalt*
MW-31d
Antimony
9209-MSWLF-1984
MW-8
Cobalt*, 1,4-Dioxane, Vinyl Chloride
MW-32
None Detected
9209-MSWLF-1984
MW-8d
None Detected
TB-1a
Not Sampled (3)
9209-MSWLF-1984
MW-9
Cadmium, Cobalt*, Benzene, 1,4-Dichlorobenzene,
1,4-Dioxane, Vinyl Chloride
TB-1a deep
None Detected
9209-MSWLF-1984
MW-10
Tetrachloroethene, Vinyl Chloride
MW-33
None Detected
9209-MSWLF-1984
MW-10d
None Detected
MW-34
1,1-Dichloroethane, Tetrachloroethene
9209-MSWLF-1984
MW-22
Not Sampled (3)
MW-34d
None Detected
9209-MSWLF-1984
MW-23
None Detected
MW-35
Tetrachloroethene
9209-MSWLF-1984
MW-23d
None Detected
MW-36
Vinyl Chloride
9209-MSWLF-1984
MW-24
Not Sampled (3)
MW-36d
None Detected
Notes:
1. * - Upper Tolerance Limit - Calculated as part of the North Wake Unlined Alternate Source Demonstration and were approved by the Solid Waste Section on August 17, 2020.
2. Bold - Indicates a 1 flag detection in which the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
3. (3) - MW-22, -24, -30, -31, and TB-1a were dry during the April 2023 sampling event.
CDM
Smith Page 1 of 1 June 2023

Table 6
Geochemical Data
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - 9209-MSWLF-1984
MW-5R
24-Apr-12 192.5 5.72 1.48 <2
<70
--
<0.43
<0.2 <0.54 -- --
2.2J
10.0
1.1
110
3.41 <0.01 321D <0.046
<0.04
<0.24 <0.87
<0.62
<O.048
<0.057
<0.061
o
2.4
MW-5R
22-Oct-12 96.1 6.20 2.22 <2
13
--
1.64
<0.2 <0.54 -- --
3.118
4.3J
1.4
190
51
<0.01
375D
<0.046
<0.031
<0.031 <0.078
<0.095
<0.052
<0.063
<0.01
9.1
MW-5R
17-Apr-13 110.1 6.46 0.73 <4
<16
--
0.31J
<0.061 <0,069 -- --
1.4
9.07
1.4
135
2.11
<0.4
180
0*
<0.5
<1
<0.5
<0.5
<0.25
0.381
MW-5R
16-Oct-13 132.5 6.08 1.88 <4
<16
--
2.3
<0.061 <0,069 -- --
1.70
9.90
1.1
184
2.98
<0.4
210B
0.2*
<0.5
<1
<0.5
<0.5
<0.25
0.82
MW-5R
16-Apr-14 139.7 5.48 3.09 (1)
<16
--
<1.3
<0.61 <0.069 -- --
1.4
9.35
0.7J
11.5
1.3
<0.4
180
0*
<0.5
<1
<0.5
<0.5
<0.25
1.2
MW-5R
12-Nov-14 -116.7 6.74 1.41 (1)
<16
--
1.1J
<0,61 <0,069 -- --
2.1
6.25
<0,09
211
2.98
0.4JB
130
0*
<0.5
<1
<0.5
<0.5
<0.25
11
MW-5R
30-Apr-15 14.4 5.39 2.41 <2
<16
--
<0.30
<0,61 <0,069 -- --
1.6
8.00
0.91
62.1
1.5
<0.4
120
0*
<0.5
<1
<0.5
<0.5
<0.25
2.8
MW-5R
15-Oct-15 156.1 6.38 2.12 <2.0
<16
--
1.9
<0.061 <0,069 -- --
2.8
0,137
1.0
272
9.5
0.5J
110
0*
<0.50
<1.0
<0.50
<0.50
<0.020
2.4
MW-5R
21-Apr-16 116.7 5.54 1.36 <2.0
<16
--
<0.30
<0.061 <0,069 -- --
1.6
3.65
0.91
39.1
1.1
<0.4
110
0.5*
<0.50
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MW-5R
14-Sep-16 109.2 5.88 1.99 <2.0
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2.6
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0.56)
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MW-5R
20-Apr-17 94.2 6.29 1.30 <2.0
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3.6
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2.6
1.6
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MW-5R
20-Sep-17 -29.0 6.60 2.58 <2.0
55
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4,100D
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220D
0.23
0.67
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11D
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MW-5R
11-Apr-18 40.9 5.90 1.56 <2.0
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3.6
0.96)
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130
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MW-5R
24-Oct-18 52.8 6.33 0.24 <2.0
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11B
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4.6
0.064
1.6
260
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MW-5R
22-Apr-19 179.2 4.83 2.27 <2.0
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1.8
5.1
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71
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MW-5R
6-Nov-19 229.2 6.11 1.98 <2.0
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MW-5R
4-Feb-20 179.2 4.83 2.27 --
13,OOOC
2,300
1,700D
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--
0.23
--
150
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--
4,500
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520.0
49.0 6.5
3.7
4.3
230.0
1.0
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MW-5R
8-Apr-20 37.1 5.26 0.82 >82(1"
2,800D
860
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4.9
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MW-5R
30-Jul-20 -55.9 6.04 1.21 1,200D
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MW-5R
15-Oct-20 -28.2 6.16 0.53 >100"I
920
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4,400BD
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0.12BJD
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7.71 <1.2
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MW-5R
31-Mar-21 -76.2 6.16 0.13 100'0'
280
290
7,000BD
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3.41D
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58
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MW-5R
11-Nov-21 -45.5 6.53 0.42 21(131
170
350
5,900E
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6.3D
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15.0
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MW-5R
30-Mar-22 -42.3 6.38 0.82 16
59
170B
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12
170
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320
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0.381
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1.41
MW-5R
11-Oct-22 -69.9 6.38 0.61 13
57
150
5,100BH
110 110 68,000D 4,600
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260
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MW-5R
4-Apr-23 -66.5 6.58 0,68 12
42
1,400
13,OOOBD
110 110 60,000D 3,900
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27
2.0*
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MW-6
24-Apr-12
168.6
5.85
2.14
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--
5,660D
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97
0.251
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3.51
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MW-6
22-Oct-12
-134.6
6.34
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732D
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160BD
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430D
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26
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MW-6
17-Apr-13
-158.3
6.25
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54.4
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105
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110
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0.76
MW-6
16-Oct-13
12.9
6.32
1.81
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40
--
45
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93
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5.2
136
2.63
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0.93
MW-6
16-Apr-14
43.1
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51
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--
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40.3
0.42
1.6
40.2
1.5
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69
0.5*
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1.3
MW-6
12-Nov-14
-121.4
6.81
0.87
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74
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--
184
0.091
14.4
607
47.3
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180
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MW-6
30-Apr-15
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23
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--
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50.9
0.161
2.6
192
5.9
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0.5*
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MW-6
14-Oct-15
58.9
6.68
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0.62J
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208
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422
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MW-6
20-Apr-16
38.7
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1.53
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0.32J
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--
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58.5
0.37
2.3
164
4.1
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62
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12
MW-6
14-Sep-16
11.0
6.42
1.40
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44
--
3.7J
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--
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210D
0.037
11
390
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470
1.5*
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3.8
MW-6
20-Apr-17
119.3
6.70
2.16
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22
--
4.2J
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--
--
130
0.46
6.4
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11
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22
MW-6
21-Sep-17
-59.0
7.54
2.87
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31
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140
0.069
30
430
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3.4
MW-6
12-Apr-18
13.0
6.34
1.74
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15
--
140
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1.5
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140B
5.5
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150
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3.6
MW-6
24-Oct-18
49.6
6.64
0.60
3.6
37
--
1,900B
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160
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590
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10
MW-6
22-Apr-19
100.4
6.12
0.51
5.3
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1,800
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74
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220
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450
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MW-6
6-Nov-19
39.3
6.38
1.11
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--
56B
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180
0.48HD
14
410
7.7
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750
1.0*
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0.76
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MW-6
7-Apr-20
79.2
5.85
3.66
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78
0.57
2.5
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5.4
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4.3
MW-6
15-Oct-20
-29.1
6.06
2.08
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22
--
260
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--
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120D
1.8BD
7.6
210
7.61D
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350
2.0*
3.21
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0.54J
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MW-6
31-Mar-21
117.4
5.43
1.75
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--
100
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--
--
68
0.92
2.7
140
3.7
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350
0*
0.24J
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MW-6
10-Nov-21
74.8
6.52
2.60
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24
--
83
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130
18EHD
8.5
310
13D
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350
0.5*
2.61
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0.591
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MW-6
29-Mar-22
239.0
6.35
1.44
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245
--
3.181
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120
7.1H
7.4
410
6.8
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520
0*
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0.611
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0.75J
MW-6
11-0ct-22
89.2
6.75
1.64
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30
--
9.681
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160
48HD
11
410
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500
0.5*
1.91
0.701
1.4J
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0.791
MW-6
5-A r-23
257.3
6.56
6.19
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9.281
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72
5.8D
4.2
360
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470
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2.01
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0.751
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3.2
MW-8
24-Apr-12
161.7
5.64
1.67
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1,870D
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12
0.19J
0.95J
74
2.6J
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324D
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MW-8
22-Oct-12
128.4
5.86
2.11
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477D
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--
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14B
0.32J
0.820J
77
3.1J
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323D
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1.1
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9.8
MW-8
17-Apr-13
96.8
6.23
0.48
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520
0.14J
0.11
--
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16.9
0.2J
1.4
86.8
1.49
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180
0.9*
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0.72
MW-8
16-Oct-13
146.8
5.79
1.74
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430
0.111
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--
--
19.7
0.18J
1.5
86.8
1.57
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200B
0.8*
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0.85
MW-8
16-Apr-14
122.9
5.79
0.19
(1)
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180
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--
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23.7
0.18J
1.3
87.7
1.7
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230
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1.4
MW-8
12-Nov-14
-84.6
6.09
0.79
(1)
20
--
320
0.13J
0.17J
--
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29.4
0.12J
1.5
95.5
2.2B
0.4JB
160
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17
MW-8
30-Apr-15
22.5
5.62
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160
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--
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44.0
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2.8
132
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MW-8
15-Oct-15
113.1
5.93
1.63
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150
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44.9
0.007J
2.3
114
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130
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0.681
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MW-8
21-Apr-16
81.5
5.99
1.86
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110
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39.6
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150
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15
MW-8
14-Sep-16
116.9
5.75
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640
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45
0.021
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120
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370
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MW-8
20-Apr-17
113.7
5.97
1.25
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180
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37
0.069
1.8
110
0.98J
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300
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1.6
MW-8
20-Sep-17
154.0
6.41
1.78
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9.3
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150
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44
0.055
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120
1.5
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320
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4.4
MW-8
12-Apr-18
25.6
5.79
1.21
2.2
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150
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45
0.035
2.2
140B
1.2
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150
0*
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2.8
MW-8
24-Oct-18
68.9
5.87
0.10
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200B
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--
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49
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130
2.2
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0.5*
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3.4
MW-8
22-Apr-19
55.7
5.94
1.29
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350
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78
0.042
5.1
170
1.6
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1.0*
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0.10
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MW-8
6-Nov-19
116.9
6.07
0.49
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71
--
410B
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29
0.016J
3.6
110
2.0
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340
0.5*
0.14
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MW-8
7-Apr-20
68.9
5.84
3.80
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76
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43
0.028
1.8
130
2.1
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170
1.0*
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2.1
MW-8
15-Oct-20
-19.3
5.86
0.49
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590
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81
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150
1.2
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240
1.5*
0.35J
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0.49J
MW-8
31-Mar-21
58.0
5.75
0.23
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150
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130
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3.4
210
1.0
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280
1.0*
1.7J
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2.1
MW-8
10-Nov-21
67.1
6.19
1.05
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490
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--
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70
<0.020
4.2
170
1.9
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250
1.0*
0.21J
<0.058
0.077J
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0.080J
2.1
MW-8
29-Mar-22
51.1
6.03
2.36
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150B
<2.5
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--
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76
0.35H1
4.5
180
1.5
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340
0*
0.21J
<0.058
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0.42J
<0.056
<0.053
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0.921
MW-8
11-Oct-22
52.5
5.92
0.64
<2.0
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--
320B
<30
<30
--
--
79
<0.20
6.0
190
2.1
<1.0
430
0.5*
1.81
<0.58
<0.58
<0.53
<0.56
<0.53
<0.60
0.831
MW-8
5-Apr-23
59.1
6.18
0.49
<2.0
<20
400B
<30
<30
82
<0.10
5.3
210
2.0
<1.0
400
1.5*
1.7J
<0.58
<0.58
<0.53
<0.56
<0.53
1 <0.60
2.4
COM Page 1 of 3 June 2023
Smith

Table 6
Geochemical Data
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - 9209-MSWLF-1984
MW-9
o
o
25-Apr-12 94.8 5.95 3.11 5.4
34
75
75
-- 2,810D
<0.2 1.591
-- -- 18
0.0791
6.1
250D
2.81 <0.01 503D
7.8
o
<0.24 <0.87 <0.62 <O.048 1.7 <0.061 --
MW-9
23-Oct-12 83.4 6.72 8.77 <2
61
-- 5.47
<0.2 <0.54
-- -- 17B
<0.025
3.2
120
8.81 <0.01
16.6
<0.230<0.031
<0.078 <0.095 <0.052 0.840 0.017MW-9
17-Apr-13 91.3 6.88 6.84 3.1
22
-- 8.5
<0.061 <0,069
-- -- 17.1
<0.03
3.5
130
7.42 <0.4
10
2.1*
<1 <0.5 <0.5 <0.25MW-9
16-Oct-13 165.7 6.88 7.89 <4
28
-- 0.531
<0.061 <0,069
-- -- 20.4
0.171
2.9
117
5.60 <0.4
27B
0*
7<0.031
<1 <0.5 <0.5 <0.25MW-9
16-Apr-14 160.2 6.44 3.69 (1)
17J
-- 17
<0.061 <0,069
-- -- 18.5
0.151
3.1
127
4.8 <0.4
39
0*
<1 <0.5 <0.5 <0.25MW-9
12-Nov-14 33.5 6.80 5.67 (1)
30
-- 1.8
<0.061 <0,069
-- -- 22.7
0.101
<0,09
136
3.98 0.4JB
28
0*
<1 <0.5 <0.5 <0.25MW-9
29-Apr-15 20.6 6.57 9.69 2.8
17J
-- 2.9
<0.061 <0,069
-- -- 19.2
<0.03
3.8
156
3.6 <0.4
27
0*
<1 <0.5 <0.5 <0.25 --
MW-9
15-Oct-15 132.2 6.65 4.66 6.5
<16
-- <0.30
<0.061 <0,069
-- -- 25.4
0,040
2.0
171
5.4 <0.4
53
0*
<0.50
<1.0 <0.50 <0.50 <0.020 --
MW-9
20-Apr-15 75.9 6.81 5.40 <2.0
<12
-- 7.8
<0.061 <0,069
-- -- 18.2
0.051
1.7
182
3.4 <0.4
46
0*
<0.50
<1.0 <0.50 <0.50 <0.020 --
MW-9
13-Sep-16 151.7 6.72 7.15 <4.0
8.01
-- -
- -
-- -- 25
0,052
1.6
200
3.8 <1.0
-
1.0*
-
- - - - --
MW-9
19-Apr-17 130.8 6.93 7.28 <2.0
<10
-- 6.1BJ
<SO <10
-- -- 24
0.0096)
1.8
210
2.1 <1.0
240
1.0*
<1.0
<1.0 <2.0 <2.0 <1.0 <1.0 <1.o --
MW-9
21-Sep-17 140.0 7.57 6.01 <2.0
<10
-- <10
<10 <10
-- -- 24
0.056
1.9
200
2.8 <1.0
220
1.0*
<0.10
<0.10 <0.20 <0.20 <0.10 <0. 10 <0.10 --
MW-9
11-Apr-18 41.4 6.79 7.50 <2.0
<10
-- <10
<10 <10
-- -- 23
0.080
1.8
190B
2.2 <1.0
180
1.5*
<0.10
<0.10 <0.20 <0.20 <0. 10 <0. 10 <0.10 --
MW-9
25-Oct-18 51.1 7.07 8.83 2.6
<20
-- 6.9BJ
<10 <10
-- -- 22
<0.020
2.2
210
2.5 1.5
190
0*
<0.10
<0.10 <0.20 <0.20 <0. 10 <0. 10 <0.10 --
MW-9
25-Apr-19 102.7 6.46 1.63 <2.0
<20
-- 1,500
<10 <10
-- -- 11
<0.020
3.7
270
1.4 <1.0
680
0*
<0.10
<0.10 <0.20 <0.20 <0.10 <0. 10 <0.10 --
MW-9
5-Nov-19 105.4 6.50 1.55 <2.0
<20
-- 530B
<30 <30
-- -- 30
<O.30
3.5
370
2.7 <1.0
990
0*
<0.10
<0.10 <0.20 <0.20 <0.10 <0. 10 <0.10 --
MW-9
7-Apr-20 37.1 6.11 0.86 2.4""
<20
-- 1,800B
<10 <10
-- -- 31
0.0079J
4.4
430
3.2 <1.0
570
0*
<0.10
<0.10 <0.20 <0.20 <0.10 <0.10 <0.10 --
MW-9
15-Oct-20 -36.7 6.12 0.76 7.4")
21
-- 1,400
<10 <10
-- -- 41
<0.020
6.0
440
2.0 <1.0
570
0*
0.5
<0.058 0.111 0.0601 <0.056 0.066J <0.060 --
MW-9
31-Mar-21 -4.4 6.01 0.19 4.3")
36
-- 1,800
<10 <10
-- -- 45
<O.10
9.4
490
0.611 <1.0
820
0*
0.27J
0.141 <0.058 <0.053 <0.056 <0.053 <0.060 --
MW-9
10-Nov-21 -36.3 6.39 0.66 2.6"v)
29
-- 3,100EHD
<10 130
-- -- 53
<0.020
9.0
250
0.98B1 3.0
750
0*
0.26J
<0.058 <0.058 <0.053 <0.056 <0.053 0.092J --
MW-9
30-Mar-22 -4.4 6.21 0.08 2.4
30
-- 1,600B
<2.5 <2.5
-- -- 45
0.37HJC
9.1
550
5.0 <3.0
720
1.5*
<0.12
<0.058 <0.058 0.0591 <0.056 <0.053 <0.060 --
MW-9
11-Oct-22 -23.8 6.24 0.52 2.2
20
-- 1,100B
<10 <10
-- -- 39
10.020
6.1
500
0.861 <1.0
6M)
1 0.5*
1.71
<0.58 <0.58 <0.53 <0.56 <0.53 <0.60 --
MW-9
4-Apr-23 -10.6 6.29 3,44 4.4
35
-- 2,000B
<10 <30
-- -- 48
<O.30
9.1
510
0.711 <1.0
1,300
2.5*
1.61
<0.58 <0.58 <0.53 <0.56 <0.53 <0.60 --
MW-10
25-Apr-12
127.9
5.41
2.62
<2
30
--
10,300D
<0.2
<0.54
--
--
3.5J
<0.025
3.3
120
3.11
<0.01
832D
0.17
0.26
<0.24
0.59
0.17
<O.048
<0.057
<0.061
--
MW-10
23-Oct-12
99.2
5.68
2.94
<2
28
--
8,220D
<0.2
<0.54
--
--
3.71B
<0.025
3.6
120
2.41
<0.01
646D
0.083
0.087
<0.031
<0.078
<0.095
<0.052
<0.063
0.0111
--
MW-10
17-Apr-13
113.9
6.08
2.93
<4
<16
--
920
<0.061
<0.069
--
--
2.71
<0.03
1.5
132
0.75
<0.4
370
1.4*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-10
16-Oct-13
84.8
5.65
4.05
<4
191
--
3,100
<0.061
<0.069
--
--
2.74
<0.03
0.91
117
0.73
<0.4
300B
1.8*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-10
16-Apr-14
68.9
5.71
3.11
(1)
<16
--
3,200
<0.061
<0.069
--
--
3.4
<0.03
2.3
129
0.71
<0.4
400
1.5*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-10
12-Nov-14
10.9
5.84
1.81
(1)
27
--
3,900
0.094J
0.111
--
--
3.0
<0.03
2.5
147
1.1B
<0.4
360
2.0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-10
29-Apr-15
30.6
5.56
2.82
3.1
<16
--
1,300
<0.061
<0.069
--
--
3.4
<0.03
3.0
184
0.91
<0.4
320
2.0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-10
14-Oct-15
89.3
5.74
2.44
5.6
<16
--
1,200
<0.061
<0.069
--
--
3.3
<0.002
1.0
140
<1.8
<0.4
250
1.5*
0.67J
<1.0
<0.050
<0.50
<0.020
--
MW-10
20-Apr-16
30.9
5.79
2.34
6.5
16J
--
1,200
<0.061
<0.069
--
--
3.4
<0.04
1.6
128
<0.06
<0.4
200
1.0*
0.57J
<1.0
<0.20
<0.50
<0.020
--
MW-10
13-Sep-16
28.2
5.44
1.61
4.3
10
--
-
-
-
--
--
3.6
0.024
<1.0
160
<1.0
<1.0
-
4.5*
-
-
-
-
-
--
MW-10
19-Apr-17
125.9
5.74
3.39
8.3
<10
--
4,800B
<10
<10
--
--
3.6
0.0141
1.2
160
<1.0
<1.0
720
3.0*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
--
MW-10
22-Sep-17
118.0
6.20
1.90
<2.0
<SO
--
1,100
<SO
<SO
--
--
3.0
0.017
1.9
110
<1.0
<1.0
440
3.0*
<0.30
<0.30
<0.20
<0.20
<0.10
<0. 10
<0.10
--
MW-10
11-Apr-18
44.1
5.60
0.71
<2.0
9.41
--
750
<10
<10
--
--
3.0
0.089
0.9
88B
0.43J
<1.0
140
2.5*
<0.30
<0.30
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-10
25-Oct-18
74.0
5.61
3.64
5.5
<20
--
3,200
<10
<10
--
--
3.2
<0.020
1.3
120
<1.0
<1.0
450
3.5*
<0.30
<0.30
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-10
25-Apr-19
7.9
5.47
0.39
5.1""
<20
--
4,200D
<10
<10
--
--
3.9
<0.020
2.9
130
<1.0
<1.0
1,300
3.0*
0.34
<0.30
<0.20
<0.20
<0.30
<0.10
<0.30
--
MW-10
5-Nov-19
44.3
5.85
0.80
5.4
<20
--
4,300BD
<10
<10
--
--
3.5
0.0161
1.2
120
0.49J
<1.0
770
3.0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-10
7-Apr-20
22.3
5.50
0.42
4.8""
<20
--
3,300D
<10
<10
--
--
3.8
0.0171
1.5
120
<1.0
<1.0
350
2.5*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-10
15-Oct-20
-33.9
5.64
2.61
3.8"'
<20
--
1,600
<10
<10
--
--
3.3
0.032B
<1.0
88
<1.0
<1.0
210
3.0*
0.37J
<0.058
<0.058
<0.053
<0.056
<0.053
<0.060
--
MW-10
31-Mar-21
167.3
5.11
0.19
<2.0
<20
--
18
<30
<30
--
--
3.1
2.0
2.1
27
0.321
<3.0
220
2.5*
0.22J
<0.058
<0.058
<0.053
<0.056
<0.053
<0.060
--
MW-10
10-Nov-21
153.4
5.87
0.38
<2.0
<20
--
350
<10
<10
--
--
3.1
0.59
0.71J
57
0.63B1
<1.0
130
2.5*
0.21J
<0.058
0.20J
<0.053
<0.056
<0.053
<0.060
--
MW-10
30-Mar-22
158.7
5.63
0.18
<0.18
<20
--
330
<2.5
<2.5
--
--
2.8
0.61
<1.0
75
0.59J
<1.0
190
2.0*
<0.12
<0.058
<0.058
0.063J
<0.056
<0.053
<0.060
--
MW-10
12-Oct-22
130.2
5.80
0.76
<2.0
<20
--
4.5BJ
<10
<10
--
--
2.7
0.38HL
1.6
100
4.OH
<1.0
490
2.5*
1.6J
<0.58
<0.58
<0.53
<0.56
<0.53
<0.60
--
MW-10
5-A r-23
99.5
5.52
2.23
2.7
<20
8,500BD
<10
<10
2.9
0.13D
<1.0
140
0.281
<1.0
530
2.0*
0.471
<0.058
0.221
<0.053
<0.056
0.0641
<0.060
MW-11
25-Apr-12
112.2
5.47
6.22
<2
<10
--
<0.43
<0.2
<0.54
--
--
3.1J
0.086J
0.76J
22
1.7J
<0.01
161D
<0.046
<0.04
<0.24
<0.87
0.13J
<O.048
<0.057
<0.061
--
MW-11
23-Oct-12
237.1
5.82
7.22
<2
13
--
<0.43
<0.2
<0.54
--
--
3.7JB
0.150J
1.5
27
2.1J
<0.01
147D
<0.046
<0.031
<0.031
<0.078
<0.095
<0.052
<0.063
<0.01
--
MW-11
17-Apr-13
102.3
5.94
5.73
<4
<16
--
<0.30
<0.061
<0.069
--
--
2.62
0.23
1.1
33.1
0.69
<0.4
100
0.8*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-11
16-Oct-13
211.6
5.49
7.94
<4
<16
--
<0.30
<0.061
<0.069
--
--
3.16
0.26
0.7J
34.8
0.66
<0.4
82B
0.4*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-11
16-Apr-14
198.8
5.62
5.63
(1)
34
--
0.59
<0.061
<0.069
--
--
3.4
0.36
0.5J
38.9
0.7J
<0.4
110
0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-11
12-Nov-14
116.3
5.80
4.68
(1)
57
--
<0.30
<0.061
<0.069
--
--
4.1
0.46
O.SJ
36.4
0.91E
0.5JB
82
0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-11
30-Apr-15
20.1
5.52
7.18
<2
<16
--
<0.30
<0.061
<0.069
--
--
3.9
0.43
0.9J
35.8
0.91E
<0.4
82
0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-11
15-Oct-15
196.8
5.91
5.70
<2.0
<16
--
<0.30
<0.061
<0.069
--
--
3.6
0.480
0.3J
34.9
<1.8
<0.4
66
0*
<0.50
<1.0
<0.50
<0.50
<0.020
--
MW-11
21-Apr-16
135.3
5.72
5.75
<2.0
<12
--
<0.30
<0.061
<0.069
--
--
4.0
0.53
0.5J
33.9
0.7J
0.5JB
75
1.5*
<0.50
<1.0
<0.50
<0.50
<0.020
--
MW-11
1-Sep-16
149.9
5.56
6.49
15
<10
--
-
-
-
--
--
5.1
0.81
<1.0
42
<1.0
<1.0
-
1.5*
-
-
-
-
-
--
MW-11
20-Apr-17
142.3
5.87
4.82
<2.0
<10
--
2.71
<10
<10
--
--
4.8
0.89
<1.0
36
<1.0
<1.0
150.0
0.5*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
--
MW-11
22-Sep-17
244.0
6.39
4.55
<2.0
<10
--
<30
<10
<10
--
--
5.2
0.88
<1.0
47
<1.0
<1.0
130
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0. 10
<0.10
--
MW-11
13-Apr-18
46.3
5.71
5.74
<2.0
<30
--
<30
<30
<30
--
--
5.4
0.89
<1.0
46B
0.27J
<1.0
75
0*
<0. 10
<0.10
<0.20
<0.20
<0.10
<0. 10
<0.10
--
MW-11
25-Oct-18
44.6
6.02
5.97
<2.0
<20
--
2.5BJ
<10
<30
--
--
5.9
0.95
<1.0
46
<1.0
<1.0
82
0*
<0. 10
<0.10
<0.20
<0.20
<0.10
<0. 10
<0.10
--
MW-11
25-Apr-19
87.8
5.91
5.94
3.4""
<20
--
<10
<10
<SO
--
--
5.8
0.94
1.9
49
<1.0
<1.0
170
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0. 10
<0.10
--
MW-11
5-Nov-19
183.2
6.16
6.46
2.1
<20
--
<30
<10
<30
--
--
5.5
0.90
<1.0
42
0.26J
<1.0
230
0*
0.51
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-11
8-Apr-20
144.7
5.88
6.44
6.2""
<20
--
3.2J
<10
<10
--
--
5.7
0.94
<1.0
44
0.31J
<1.0
100
0*
0.16'la�
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-11
14-Oct-20
33.2
5.84
6.33
16("'
<20
--
2.8BJ
<10
<10
--
--
5.7
0.88
<1.0
43
<1.0
<1.0
86
0*
0.43J
<0.058
<0.058
<0.053
<0.061
<0.053
<0.060
--
MW-11
31-Mar-21
132.4
5.57
6.58
<2.0
<20
--
42
<10
<10
--
--
5.6
0.77
<1.0
38
<1.0
<1.0
110
0*
0.50J
<0.12
<0.12
<0.11
<0.11
<0.11
<0.12
-
MW-11
11-Nov-21
982.0
6.07
7.33
<2.0
<20
--
<10
<30
<30
--
--
5.1
0.71D
<1.0
35
<1.0
<1.0
130
0*
0.24J
<0.058
<0.058
<0.053
<0.056
<0.053
<0.060
-
MW-11
30-Mar-22
257.8
5.69
4.71
<0.18
<20
--
<2.5
<2.5
<2.5
--
--
5.1
0.88
<1.0
42
<0.25
<1.0
180
0*
<0.12
<0.058
<0.058
<0.053
<0.056
<0.053
<0.060
-
MW-11
13-Oct-22
181.4
5.92
6.91
<2.0
<20
--
<10
<10
<30
--
--
5.5
0.79L5
<1.0
39
0.28H1
<1.0
180
0*
0.261
<0.058
<0.058
0.20J
<0.056
<0.053
<0.060
-
MW-11
5-Apr-23
231.3
5.99
7.01
<2.0
<20
4.OBJ
<30
<30
5.6
0.85
<S.0
46
<1.0
<S.0
120
0*
0.461
<0.058
0.0621
<0.053
<0.056
0.059J
<0.060
C�t Page 2 of 3 June 2023

Table 6
Geochemical Data
April 2023 Semi -Annual Sampling Event
North Wake Unlined Landfill - 9209-MSWLF-1984
MW-34
6-Nov-19
195.8
5.63
1.52
<2.0
<20
--
260B
<10
<10
--
7,300
11
0.14
1.0
35
0.471
<1.0
330
0*
0.12
0.29
<0.20
<0.20
<0.10
0.21
<0.10
MW-34
4-Feb-20
157.2
5.15
1.25
--
<20
74
470
<10
<10
470
8,700
--
0.20
--
24
<1.0
--
570
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
MW-34
8-Apr-20
96.9
5.21
0.78
<2.0
<20
85
350
<10
<10
3,900
8,300
14
0.14
<1.0
40
0.50J
1.4
120
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
MW-34
30-Jul-20
-13.4
5.30
0.18
--
<20
150
370
<10
<10
6,700
8,000
--
0.10
--
--
<1.0
--
110
0*
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
MW-34
15-Oct-20
-22.1
5.29
0.91
<2.0
<20
99
300
<10
<10
610
8,200
14
0.091B
<1.0
36
<1.0
<1.0
120
0*
0.43J
<0.058
<0.058
<0.053
<0.056
<0.053
<0.06(
MW-34
31-Mar-21
197.4
4.57
1.80
<2.0
<20
140
26
<10
<10
6,100
24,000
54
0,020
<3.0
<20
5.7
<3.0
190
0*
1.11
<0.29
<0.29
<0.26
<0.28
<0.26
<0.30
MW-34
11-14ov-21
194.1
5.63
0.39
<2.0
<20
77
310
<10
<10
1505
11,000
15D
0.10D
0.65J
35
1.5
<1.0
210
0*
0.23J
<0.058
0.0611
<0.053
<0.056
<0.053
<0.06(
MW-34
30-Mar-22
200.4
5.15
0.20
<0.18
<20
78B
280E
<2.5
<2.5
5,900
11,000
21
0,110
1.1
35
0.54J
<1.0
350
0*
0.25J
<0.058
0.211
0.331
<0.056
<0.053
<0.06(
MW-34
11-Oct-22
235.0
5.35
0.63
<2.0
<20
<25
320B
<10
<10
5105
9,700
13
0.12B
<3.0
34
0.38)
<1.0
210
0*
1.71
0.611
<0.58
<0.53
<0.56
<0.53
<0.60
MW-34d
6-Nov-19
466.9
6.08
0.61
2.8
<20
--
3.OB1
<10
<10
--
12,000
9.2
1.0
1.6
65
1.4
<3.0
150
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
MW-34d
4-Feb-20
347.9
5.88
0.28
--
<20
130
26
<10
<10
550
12,000
--
2.0
--
52
3.2
--
550
0*
<0. 10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
MW-34d
8-Apr-20
129.4
5.85
1.40
2.6j1s1
<20
120
3.OJ
<10
<10
110
13,000
10
1.0
1.2
70
1.8
<1.0
87
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
MW-34d
30-Jul-20
-13.3
5.83
0.93
--
<20
120
2.81
<10
<10
120
12,000
--
1.7
--
--
5.9
--
100
0*
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
MW-34d
15-0ct-20
-22.1
5.82
1.39
3.6j1'
<20
150
4.OJ
<10
<10
86
14,000
11
1.313
<1.0
75
2.2
<1.0
88
0*
0.43J
<0.058
<0.058
<0.053
<0.056
<0.053
<0.06(
MW-34d
31-Mar-21
223.4
5.46
0.35
<2.0
<20
110
6.7J
<30
<30
160
8,600
9.9
0.50
<3.0
59
1.2
<3.0
110
0*
0.27J
<0.058
<0.058
<0.053
<0.056
<0.053
<0.06(
MW-34d
10-14ov-21
428.9
6.09
0.83
<2.0
<20
150
<10
<10
<10
<50
13,000
16
2.0
<1.0
68
5.3
<1.0
96
0*
0.25J
<0.058
<0.058
<0.053
<0.056
<0.053
<0.06(
MW-34d
29-Mar-22
220.2
5.73
1.48
<0.18
<20
25
5.9B1
<2.5
<2.5
17
3.8H
<3.0
63
14
<3.0
27
0*
<0. 12
<0.058
<0.058
0.0541
<0.056
<0.053
<0.06(
MW-34d
11-Oct-22
207.7
5.90
2.20
<2.0
<20
180
4.OB1
<10
<10
140
13,000
16
3.213
<1.0
66
18
<1.0
190
0*
2.01
<0.58
<0.58
<0.53
<0.56
<0.53
<0.60
MW-36
25-Apr-12
122.2
5.71
2.94
5.2
29
--
186D
<0.2
<0.54
--
--
5.9
0.5J
1.1
60
3.91
<0.01
336D
<0.046
<0.04
<0.24
<0.87
0.0731
<0.048
<0.057
<0.061
--
MW-36
23-Oct-12
139.1
5.92
8.39
<2
<30
--
39.6
<0.2
<0.54
--
--
6B
0.4901
1.7
67
3.91
<0.01
196D
<0.046
<0.031
<0.031
<0.078
<0.095
<0.052
<0.063
<0.01
--
MW-36
17-Apr-13
118.1
6.05
2.44
12
<16
--
6.4
<0.061
<0.069
--
--
5.59
0.59
1.1
66.3
2.19
<0.4
98
0.8*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-36
16-Oct-13
188.5
5.82
3.89
<4
38
--
9.8
<0.061
<0.069
--
--
5.50
0.73
1.1
59.2
2.19
<0.4
81B
1.5*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-36
16-Apr-14
165.3
5.76
3.08
(1)
71
--
17
<0.061
<0.069
--
--
5.8
0.86
0.61
55.6
2.3
<0.4
110
0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-36
12-Nov-14
96.2
5.76
2.23
(1)
37
--
25
<0.061
<0.069
--
--
5.8
0.98
<0.09
55.3
2.68
<0.4
83
0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-36
30-Apr-15
1.6
5.69
3.15
4.10
<16
--
3.6
<0.061
<0.069
--
--
5.8
0.89
1.4
58.4
2.3
<0.4
81
0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-36
15-Oct-15
167.8
5.97
3.78
<2.0
33
--
2.5
<0.061
<0.069
--
--
5.5
0.704
1.2
59.3
3.0
0.4J
72
0*
<0.50
<1.0
<0.50
<0.50
<0.020
--
MW-36
20-Apr-16
125.4
5.80
2.49
12.0
<12
--
2.5
<0.061
<0.069
--
--
5.9
0.60
1.0
53.7
2.3
<0.4
76
2.0*
<0.50
<1.0
<0.50
<0.50
<0.020
--
MW-36
13-Sep-16
176.6
5.13
2.15
<2.0
<10
--
-
-
-
--
--
6.7
0.81
<1.0
55
2.5
<1.0
-
0.5*
-
-
-
-
-
--
MW-36
20-Apr-17
143.0
5.79
1.77
<2.0
<10
--
5.OJ
<10
<10
--
--
6.9
0.79
0.70J
51
1.3
<1.0
190.0
2.0*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
--
MW-36
22-Sep-17
143.0
6.00
1.95
<2.0
<10
--
2.9
<10
<10
--
--
7.3
0.66
0.78
63
2.4
<1.0
220.0
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-36
13-Apr-18
45.2
5.81
1.35
<2.0
<10
--
<10
<10
<10
--
--
6.9
0.66
0.83J
58B
3.3
<1.0
71.0
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-36
25-Oct-18
98.4
5.53
0.86
<2.0
20
--
3.9B1
<10
<10
--
--
7.8
0.64
1.5
60
1.8
<1.0
190
0*
<0. 10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-36
25-Apr-19
123.4
5.77
0.94
<2.0
<20
--
<10
<10
<10
--
--
8.9
0.62
1.0
61
2.3
<1.0
280
0*
<0. 10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-36
5-Nov-19
146.4
6.00
0.57
<2.0
<20
--
4.5B1
<10
<10
--
--
8.8
0.60
1.0
58
1.9
1.1
390
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-36
7-Apr-20
63.9
5.69
0.74
<2.0
<20
--
5.6B1
<10
<10
--
--
9.1
0.57
<1.0
59
2.0
<1.0
120
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-36
15-Oct-20
-33.1
5.67
0.67
<2.0
<20
--
5.5J
<10
<10
--
--
9.6
0.4013
<1.0
63
2.5
<1.0
150
0*
4.11
<0.58
<0.58
<0.53
<0.56
<0.53
<0.60
--
MW-36
31-Mar-21
125.9
5.22
1.93
<2.0
<20
--
47
<10
<10
--
--
9.3
0.16
<1.0
56
2.9
1.3
140
0*
1.21
<0.29
<0.29
<0.26
<0.28
<0.26
<0.30
--
MW-36
11-Nov-21
14.6
5.95
0.78
<2.0
<20
--
37
<10
<10
--
--
11D
0.21D
1.2
88
3.5
<1.0
290
0*
0.271
<0.058
0.0591
<0.053
<0.056
<0.053
<0.060
--
MW-36
30-Mar-22
112.7
5.68
0.08
<0.18
<20
--
14
<2.5
<2.5
--
--
11D
0.42H1
1.4
86
<2.5
<1.0
280
0*
<0 12
<0.058
<0.058
<0.053
<0.056
<0.053
<0.060
--
MW-36
11-Oct-22
41.0
5.79
0.60
<2.0
75
--
89B
<10
<10
--
--
12
0.2313
1.2
110
4.3
<1.0
260
0*
1.81
<0.58
<0.58
<0.53
<0.56
<0.53
<0.60
--
MW-36
4-Aor-23
81.5
5.82
0.56
<2.1
<20
--
86B
<10
<10
--
--
14
0.26D
1.7
110
4.0
<1.0
470
0*
0.42J
<0.058
0.0641
0.181
<0.056
<0.053
<0.060
--
Notes:
1. All units are in milligrams per liter ((mg/L) parts per million), unless otherwise noted.
2. µg/L- micrograms per liter (parts per billion)
3. CaCO3 - Calcium Carbonate
4. MW-11 is a background well for the North Wake Unlined Landfill.
5. * - Field analysis performed using a HACH kit.
6. (--) - Not Measured
7.1- Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
8. B -The analyte concentration detected in the method blank was greater than the method detection limit.
9. D, d - Analyzed as dilution.
10. U% - The compound was analyzed for, but not detected. 1 mL HNO3 was added to MW-6 for metals upon receipt to get the pH to less than 2.
11. (1) - BOD was measured following dilution and did not meet the oxygen depletion criterion of at least 2 mg/L. The elevated BOD concentrations are a result of laboratory error and were not used to evaluate natural attenuation for the April and
November 2014 sampling events.
12. l"l 1 flag - The average BOD for MW-9, -10, -36, and -11 is lower than the valid range.
13. (-) Samples not collected and analyzed for the spring 2016 sampling event.
14. H -The analyte was analyzed outside of holding time.
15l"I - 7 flag - The seed correction factor was above the method range. Results may be biased low.
16. l.sl- 75 flag - The sample became depleted. The reported result was computed using the greatest dilution and the least amount of sample.
17. l"l- M3 flag - The matrix spike duplicate sample recovery was outside laboratory control limits.
18. lssl - MS flag - The matrix spike sample recovery was outside laboratory control limits.
19. 47 flag- Indicates a blank depletion less than 0.20 mg/L and a seed correction factor out of range.
20. 1201- 4 flag - The method blank result was higher than the method required limit of 0.20 mg/L.
21. E -The quantitation of the compound exceeded the calibration range.
22. L- Laboratory control spike/laboratory control spike duplicate failure
23. S - Matrix spike/matrix spike duplicate failure
�- Blank cells indicate no data collected
SmithPage 3 of 3 June 2023

N LEGEND
wE MW-28 MW-28d Groundwater Monitoring Well
X/ 219.01 219.54 • Surface Water Sample Location
4N • Injection Well Location
MW-22 Air Sparging Well Area
> 218.83 Potentiometric Contour
218 — (dashed where inferred)
`'' • Contour Interval = 2 Feet
z1 SW-8
'
�M9/ MW-36
MW-10�1�21IW258 21061
229.06
MW-3.6d
rMW-29d 21065
,1231.16 W10dM25.65
rI
SW-7
N N� N
sP4 N '
�r'N`MW-6
V
CN c ' i 207.42
MW-30 tN °•-D t MW-6d
231.32.:. N r v 1 \ 205.85
N N 04 O O
N N N
IIMW-23d
227.88
MW-23 /
227.81
MW-31d
227.74
r
MW-31
227.95
MW-2[
TB 1a
226.30.,
TB-1 a deep
225.01
,'Unlined Landfill
I
NWIVI
IBiobarrier Injection ,
;Area t NWIW.
' ' i NWIW-3
\220.59 t` U, IfNWIW-4
WIW-5
NWIW-6 `a
NWIW-8
MW-32 ! ,
226.13
SW-3 1I ,
MW-7 N MW-8
221.70 214.82 MW-8d
213.71
MW-33
210.71
MW-34
208.79
MW-34d
208.60
MW-5R
209.84
44. Map Data Source: February 2021 Aerial Photograph,
MW-35
207.12
County, North FarneR1

300
250
c 200
M
L
Q
N
L
150
50
Figure 2
MW-6 - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
t Vl Ln 1.0 l0 I� n w w M M O O rl ri N N M M-;t t Vl Ln O lD I, n M M M M O O rl ri N N M M�-;t Ln Ln LD lD I, n W M M M O O rl e 4 N N M
�OIOI�OITTOI��OIOIOOOOOOOOOOOOOOOOOOOOrl1l1l1l1l1- 1� N N N N N N N
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Q c.� Q u Q u Q c.i Q :.: Q c.i Cl :.i Q u Q :.i Q :.: Q �.� Cl :.i Q �.� Q :.i Cl c.i � �.� Q :.i Q �.� � c.� Cl :.) Q �.� Cl c.i Q �..% � <.� Q :.) Q <.� Q c.i Q :.� Q c.i Q
Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q
Date
�Smith

20
18
16
14
c
0
C
0
+w
M
c 8
v
U
C
0
U
4
2
n
Figure 3
MW-6d - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
i--I r-I fV N M M -:T -:T Ill Ln l0 l0 r- r- W W M M O O rq r-I N N M M :T :T Ln Ln to l0 r, r, w w M M O O a--1 r-I N N M
O O O O O O O O O O O O O O O O O O r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I N N N N N N N
L L L }�.L L �J L
Q U Q U U Q U Q U Q U Q U Q U Q U Q U Q U Q U U Q U Q U Q U Q U Q U Q U Q U Q U Q U Q U Q U Q
a 0 Q 0 a 0 a 0 a 0 Q 0 a 0 a 0 a 0 Q 0 a 0 0 0 a 0 a 0 a 0 Q 0 a 0 a 0 a 0 Q 0 a 0 a 0 a
Date
Smith

Figure 4
MW-9 - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
900
Completion of the Perimeter Migration Control System Air Sparging System
Landfill Cap (July Operational (January 2002) Operational (August
800 1997) 2012)
700
Addition of 1,4-
Dioxane to the
c600 Sampling Program
_ (July 2018)
L
500
a
c
400
ra
c
v
U
C
u 300
200
100
0
IZT -zt Ln Ln l0 1,0 I- n 00 00 O1 M O O r-I i--I N N M M IzT Ln Ln l0 l0 I� n 00 00 0) M O O r-I ri N N M M -:T zt Ln Ln l0 l0 I- n 00 00 Ol M O O r-I r-I N N M
Ql C l C l T T T T 9) T T T T 0 0 0 O O O O O O O O O O O O O O O O O
L }.Q U U
VQ}i U..U C U }U.i 0-L U..QL }UJ QL }i.0-L VU QL U C }U.i 0-L }U.i 0-L U..QL U..0-L }V.i 0-L U..Qi }U.i 0-L }i.0-L }V.i 0-L U..0-L .i.0-L }U.0-L U..C }U.i 0-L }V.i L
Q
Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q
Date
Smith

50
45
40
35
c
0
v
30
Q-
LA
Q- 25
C
0
20
v
U
C
0
U
15
10
5
a
Figure 5
MW-36 - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Air Sparging System Operational
(August 2012)
Addition of 1,4-Dioxane to the
Sampling Program (July 2018)
M M M M 00 O O r-I r-I r-I .--I N N N N M M M M��-;t I:T Ln u1 Ln Ln lO l0 iO lO I- r- n r- W W W W M M M M O O O O r-I r-I r-I r-I N N N N M M
99 O O r-I r-I r-I r-I
C L U C L U C L U C C U C L U C L U C L U C C U C L U C L U C L U L U C C U C L U C L
� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q 7 U� Q
a,0,a,0,a,0,a,0,a,0,a,0,a,0,a,0,a,0,a,0,a,0,a,0,a,0,a,0,a
Date
Smith

35
30
25
c
0
EL 20
H
L
Q
10
Figure 6
MW-36d - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
m m m m o o O o -I r-I c-I ri N N N N M M M M -:t -tT -:i, m Ln m m LD to w lD I- n r, n W w W w m m m m o o o o r-I r-I r -I -4 N N N N M M
0 0 0 0 ry r- ry ry 1- r- r- I 1- r- I l i IV 1- c r- r- 1i r- r- r- 1- 1- r- r- I l i r- r- ry IV 1- c N N N N N N N N N N N N N N
C -�+ C i �+ C L ++ C " ++ C " ++ C L �+ C L ++ C " ++ C " ++ C " �+ C L �+ C i ++ C " ++ C " ++ C "
Q 7 U, Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q 7 U M Q
a,o,a,o,a,o,a,o-< 0-<,0-< 0-a,0-< 0-<,0-a,0,a,0-< 0 - < 0 - <
Date
Smith

70
50
c
0
Q. 40
LA
L
Q
C
0 30
c
d
U
C
0
U
W
10
Figure 7
MW-5R - Volatile Organic Compounds Concentration Trends
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Total Volatile Organic
Compounds
—0--Tetrachloroethene
fTrichloroethene
f1,1-Dichloroethane
tcis-1,2-Dichloroethene
—4--Methvlene Chloride
Addition of 1,4-Dioxane to the Sodium EVO Injection
Sampling Program (July 2018) Lactate (December 2019)
Injection
(October
2019)
O
r-1 i--I r1 ri N
N N
N
M M M
M
Z zt
Ln Ln Ln ill 110 l0 110 l0
I- r- r-
r-
W w
w w
M M M
M
O O O O
r-I
r-I r-I r-I r-I r-I
r-I r-I
r-I
r-I r-I r-I
r-I
r-I r-I r-I
r-I r-I r-I r-I r-I r-I r-I r-I r-I
r-I r-I r-I
r-I
r-I r-I
r-I r-I
r-I r-I r-I
r-I
N N N N
N N N
N N N N N
N N
�J
u
L
(�aU
QL
U
QL
U
aL
U QL U QL U
QL
U
aL
U
QL
U
QL U
� QL �
U aL U
Q
o,Q,o,a,o,a,o,Q,o,a,o,a,o,a,o,Q,o,a,o,a,o,a,o,Q,o,L
a
Date
Smith

M
c 40
a
Q.
LA
L
Q- 30
C
0
.w
M
c
a�
U
u 20
10
M
Figure 8
MW-34 - Volatile Organic Compounds Concentration Trends
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
—Total Volatile Organic Compounds Addition of 1,4- Sodium EVO Injection
Dioxane to the Lactate (December 2019)
tTetrachloroethene Sampling Program Injection
Trichloroethene (July 2018) (October
— —1,1-Dichloroethane 2019)
Methylene
— —cis-1,2-Dichloroethene
Chloride
ri a-i r-I N N N N M M M M u1 u1 Ln Ln l0 l0 l0 l0 r" r" r- r- w w w w M M M M O O O O i--I r-I r-I ri N N N N M M
r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I N N N N N N N N N N N N N N
Q 7 U M ii 7 U M Q 7 U M Q 7 U (c Q 7 U f6 Q 7 U f6 Q 7 U (c Q 7 U f6 Q 7 U (u Q 7 U (u Q 7 U f6 Q 7 U(� a
a o, a o, a o, a o, a o, a o, a o, a o, a o, a o, a o, a o, Q
Date
Smith

Figure 9
MW-34d - Volatile Organic Compounds Concentration Trends
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
45
Total Volatile Organic Compounds Addition of 1,4- Sodium EVO Injection
Dioxane to the Lactate (December 2019)
tTetrachloroethene Sampling Program Injection
40 (July 2018) (October
❑ Trichloroethene
2019)
f1,1-Dichloroethane
35
cis-1,2-Dichloroethene
O Methylene Chloride
c 30
L
CL 25
L
Q
2 20
U
C
u 15
10
NIS
<�L
r-1 r-I r-1 N N N N M M M M1:T Ln Ln Ln Ln l0 1.0 l0 l0 r- n r- r- w w w w M M M M O O O O -1 r-1 r-1 r-1 N N N N M M
r-I r-I r-I r-I r-I r-I r-I r-I rl ri ri ri ri rl ri ri ri ri ri rl ri ri ri rl ri rl ri ri ri ri ri rl ri ri ri N N N N N N N N N N N N N N
Q 7 U M ii 7 U M Q 7 U (6 Q 7 U (c Q 7 U f6 Q 7 U f6 Q 7 U (c Q 7 U f6 Q 7 U (u Q 7 U (u Q 7 U f6 Q 7 (,.) (.0 a
a o, a o, a o, a o, a o, a o, a o, a o, a o, a o, a o, a o, Q
Date
Smith

Appendix A
Analytical Data

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: North Wake Unlined Landfill
Lot Number:YD05007
Date Completed:05/12/2023
05/14/2023 10:14 PM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�4 aecRFo���A16
TNI /
AM Amflvue Acm^rmm Fvu rj
('
4eOfFAi�
ACC R E OI TEO
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 257

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: YD05007
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
VOA 8260D
The laboratory control sample (LCS) for analytical batch 72347 exceeded acceptance criteria for the
following analyte: Vinyl Chloride (136%). This analyte was biased high and was not detected in the
associated samples: YD05007-007, YD05007-009, YD05007-010, YD05007-011, YD05007-012, and
YD05007-013.
YD05007-007 (MW-32) (Run 1) (Analysis Batch 72347)
YD05007-009 (MW-31d) (Run 1) (Analysis Batch 72347)
YD05007-010 (MW-23) (Run 1) (Analysis Batch 72347)
YD05007-011 (MW-23d) (Run 1) (Analysis Batch 72347)
YD05007-012 (MW-35) (Run 1) (Analysis Batch 72347)
YD05007-013 (MW-36d) (Run 1) (Analysis Batch 72347)
The laboratory control sample (LCS) for analytical batch 72379 exceeded acceptance criteria for the
following analytes: Acetone, Acrylonitrile and 2-Butanone. These analytes were biased high and were not
detected in the associated samples above the LOQ: YD05007-014, YD05007-015, YD05007-016,
YD05007-017, YD05007-018, YD05007-019, YD05007-020, YD05007-021, YD05007-022, YD05007-023,
YD05007-024, YD05007-025, YD05007-026, YD05007-027, YD05007-028, and YD05007-029.
YD05007-014 (MW-10) (Run 1) (Analysis Batch 72379)
YD05007-015 (MW-6) (Run 1) (Analysis Batch 72379)
YD05007-016 (MW-8) (Run 1) (Analysis Batch 72379)
YD05007-017 (MW-11) (Run 1) (Analysis Batch 72379)
YD05007-018 (SW-2) (Run 1) (Analysis Batch 72379)
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PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
YD05007-019 (SW-3) (Run 1) (Analysis Batch 72379)
YD05007-020 (SW-7) (Run 1) (Analysis Batch 72379)
YD05007-021 (SW-8) (Run 1) (Analysis Batch 72379)
YD05007-022 (MW-10D) (Run 1) (Analysis Batch 72379)
YD05007-023 (MW-6d) (Run 1) (Analysis Batch 72379)
YD05007-024 (DUP) (Run 1) (Analysis Batch 72379)
YD05007-025 (ME-8d) (Run 1) (Analysis Batch 72379)
YD05007-026 (MW-1d) (Run 1) (Analysis Batch 72379)
YD05007-027 (MW-29d) (Run 1) (Analysis Batch 72379)
YD05007-028 (MW-28d) (Run 1) (Analysis Batch 72379)
YD05007-029 (MW-28) (Run 1) (Analysis Batch 72379)
The following samples had an air bubble > 6mm in the sample vial: YD05007-015, YD05007-017 and
YD05007-031.
YD05007-015 (MW-6) (Run 1) (Analysis Batch 72379)
YD05007-017 (MW-11) (Run 1) (Analysis Batch 72379)
YD05007-031 (EQ Blank) (Run 1) (Analysis Batch 72381)
The laboratory control sample (LCS) for analytical batch 72381 exceeded acceptance criteria for Vinyl
Chloride (134%). This analyte was biased high and was not detected in the associated sample:
YD05007-031.
YD05007-031 (EQ Blank) (Run 1) (Analysis Batch 72381)
The laboratory control sample (LCS) for analytical batch 72496 exceeded acceptance criteria for the
following analytes: Acetone, Methylene Chloride, Acrylonitrile, and 2-Butanone. These analytes were
biased high and were not detected in the associated sample: YD05007-030
YD05007-030 (MW-33) (Run 1) (Analysis Batch 72496)
Reanalysis of the following samples was performed outside of the analytical holding time for Methylene
Chloride due to failure in the original CCV: YD05007-023 and YD05007-024.
YD05007-023 (MW-6d) (Run 2) (Analysis Batch 73259)
YD05007-024 (DUP) (Run 2) (Analysis Batch 73259)
The continuing calibration verification (CCV) associated with samples YD05007-001 and YD05007-002
was outside of criteria for vinyl chloride. Samples were outside of holding time; therefore the data has
been reported.
YD05007-001 (MW-9) (Run 1) (Analysis Batch 72287)
YD05007-002 (MW-36) (Run 1) (Analysis Batch 72287)
The continuing calibration verification (CCV) associated with sample YD05007-012 was outside of criteria
for dichlorodifluoromethane. The sample was outside of holding time; therefore the data has been
reported.
YD05007-012 (MW-35) (Run 1) (Analysis Batch 72347)
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
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PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
1,4-Dioxane SIM 8260D
The following sample(s) was received with headspace in the sample vial: YD05007-001, YD05007-002,
YD05007-003, YD05007-005, YD05007-016, YD05007-0172.
YD05007-001 (MW-9) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-002 (MW-36) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-003 (MW-34) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-005 (MW-5R) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-016 (MW-8) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-017 (MW-11) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
Internal standard recoveries in the duplicate and matrix spike (DUP/MS) for batch 72429 were outside the
lower control limit. The samples affected: YD05007-001, YD05007-002, YD05007-003, YD05007-004,
YD05007-005, YD05007-016, YD05007-017, and YD05007-031. The CCV and LCS associated with
BATCH YQ72429 passed acceptance criteria; therefore the data has been reported.
YD05007-001 (MW-9) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-002 (MW-36) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-003 (MW-34) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-004 (MW-34d) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-005 (MW-5R) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-016 (MW-8) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-017 (MW-11) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
YD05007-031 (EQ Blank) (Run 1) (Analysis Batch 72429) 1,4-Dioxane (SIM) 1,2-DCA-d4 surrogate
Dissolved Gases RSK175
The method blank associated with batch 72481 had Methane detected at a concentration that was above
the DL but below the LOQ. All samples associated with this method blank that have detections for
Methane have been flagged with a "B".
Metals 6020B
The MS/MSD for batch 72256 and parent sample YD05007-003 (MW-34), recovered outside the upper
control limit. The associated LCS passed acceptance criteria.
Nitrate 300.0
The following samples were diluted due to the nature of the sample matrix: YD05007-001, YD05007-005
and YD05007-016. The LOQ has been elevated to reflect the dilution.
YD05007-001 (MW-9) (Run 1) (Analysis Batch 71960) Nitrate - N
YD05007-005 (MW-5R) (Run 1) (Analysis Batch 71960) Nitrate - N
YD05007-016 (MW-8) (Run 1) (Analysis Batch 72051) Nitrate - N
Sulfide SM4500 S2-F
The sulfide for batch 72342 and parent sample YD05007-003 (MW-34), recovered outside the lower
control limit. The associated LCS passed acceptance criteria.
The sulfide for batch 72458 and parent sample YD05007-017 (MW-11), recovered marginally outside the
lower control limit. The associated LCS passed acceptance criteria.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
Page 4 of 257

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
BOD
No sample dilutions resulted in a depletion of at least 2.0 mg/L. The reported BOD/CBOD value is <2.1
mg/L, which was computed using the lowest BOD/CBOD value that can be calculated with the available
data. COD approximate values were used to determine sample dilutions. The data have been 6-flagged
accordingly for sample YD05007-002 (MW-36).
YD05007-002 (MW-36) (Run 1) (Analysis Batch 71899) BOD, 5 day
For samples: YD05007-001, YD05007-002, YD05007-003, YD05007-004, and YD05007-005 QC bottles
1-10 for BOD_71899 were recorded with initial DO values below the criteria minimum of 8.56 mg/L for
setup procedure.
YD05007-001 (MW-9) (Run 1) (Analysis Batch 71899) BOD, 5 day
YD05007-002 (MW-36) (Run 1) (Analysis Batch 71899) BOD, 5 day
YD05007-003 (MW-34) (Run 1) (Analysis Batch 71899) BOD, 5 day
YD05007-004 (MW-34d) (Run 1) (Analysis Batch 71899) BOD, 5 day
YD05007-005 (MW-5R) (Run 1) (Analysis Batch 71899) BOD, 5 day
For samples YD05007-014, YD05007-015, YD05007-016, YD05007-017 QC bottles 2, 4, 5, 6, and 8 for
BOD _72001 were recorded with initial DO values below the criteria minimum of 8.56 mg/L for setup
procedure.
YD05007-014 (MW-10) (Run 1) (Analysis Batch 72001) BOD, 5 day
YD05007-015 (MW-6) (Run 1) (Analysis Batch 72001) BOD, 5 day
YD05007-016 (MW-8) (Run 1) (Analysis Batch 72001) BOD, 5 day
YD05007-017 (MW-11) (Run 1) (Analysis Batch 72001) BOD, 5 day
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 257

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: YD05007
Project Name: North Wake Unlined Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-9
Aqueous
04/04/20231210
04/05/2023
002
MW-36
Aqueous
04/04/20231245
04/05/2023
003
MW-34
Aqueous
04/04/20231420
04/05/2023
004
MW-34d
Aqueous
04/04/20231500
04/05/2023
005
MW-5R
Aqueous
04/04/20231540
04/05/2023
006
MW-7
Aqueous
04/04/20231050
04/05/2023
007
MW-32
Aqueous
04/04/20231105
04/05/2023
008
TB-1 a deep
Aqueous
04/04/2023 1115
04/05/2023
009
MW-31d
Aqueous
04/04/20231130
04/05/2023
010
MW-23
Aqueous
04/04/20231140
04/05/2023
011
MW-23d
Aqueous
04/04/20231150
04/05/2023
012
MW-35
Aqueous
04/04/20231335
04/05/2023
013
MW-36d
Aqueous
04/04/20231255
04/05/2023
014
MW-10
Aqueous
04/05/2023 0915
04/06/2023
015
MW-6
Aqueous
04/05/20231110
04/06/2023
016
MW-8
Aqueous
04/05/20231242
04/06/2023
017
MW-11
Aqueous
04/05/20231645
04/06/2023
018
SW-2
Aqueous
04/05/20231740
04/06/2023
019
SW-3
Aqueous
04/05/20231800
04/06/2023
020
SW-7
Aqueous
04/05/20231725
04/06/2023
021
SW-8
Aqueous
04/05/20231730
04/06/2023
022
MW-1OD
Aqueous
04/05/2023 0955
04/06/2023
023
MW-6d
Aqueous
04/05/20231040
04/06/2023
024
DUP
Aqueous
04/05/2023 0800
04/06/2023
025
ME-8d
Aqueous
04/05/20231310
04/06/2023
026
MW-1d
Aqueous
04/05/20231345
04/06/2023
027
MW-29d
Aqueous
04/05/20231410
04/06/2023
028
MW-28d
Aqueous
04/05/20231440
04/06/2023
029
MW-28
Aqueous
04/05/20231515
04/06/2023
030
MW-33
Aqueous
04/05/20231705
04/06/2023
031
EQ Blank
Aqueous
04/05/2023 1455
04/06/2023
032
MW-5R
Aqueous
04/05/20231152
04/06/2023
033
MW-6
Aqueous
04/05/20231128
04/06/2023
034
MW-8
Aqueous
04/05/20231242
04/06/2023
(34 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-001
Description: MW-9 Matrix: Aqueous
Date Sampled:04/04/2023 1210 Project Name: North Wake Unlined Landfill
Date Received: 04/05/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
04/06/2023 1938
JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1
04/10/2023 1555
HDT
04/05/2023 1847 71899
1
(Chloride) 300.0
1
04/05/2023 1927
SJL
71959
1
(CO2 (calcula) SM 4500-CO2 D
1
04/06/2023 1938
JJM
1
(COD) SM 5220D-2011
1
04/10/2023 1330
GGC
72111
1
(Nitrate - N) 300.0
5
04/05/2023 1946
SJL
71960
1
(Sulfate) 300.0
1
04/05/2023 1927
SJL
71961
1
(Sulfide) SM 4500-S2 F-2011
1
04/11/2023 1201
CVR
72342
1
(TOC) SM 531 OC-2014
1
04/15/2023 0523
DMA
72721
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
510
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
4.4
2.0
0.18
mg/L
1
Chloride
300.0
48
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
1300
27
27
mg/L
1
COD
SM 5220D-2011
35
20
20
mg/L
1
Nitrate - N
300.0
0.10 U
0.10
0.025
mg/L
1
Sulfate
300.0
0.71 J
1.0
0.25
mg/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
TOC
SM 531OC-2014
9.1
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-001
Description: MW-9 Matrix: Aqueous
Date Sampled:04/04/2023 1210 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 0426 CDA
72287
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
1.8
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.82
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
1.3
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.42 J
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
15
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
5.0
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
3.1
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.42 J
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-001
Description: MW-9 Matrix: Aqueous
Date Sampled:04/04/2023 1210 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 0426 CDA 72287
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
20
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
94 70-130
104 70-130
102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-001
Description: MW-9 Matrix: Aqueous
Date Sampled:04/04/2023 1210 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 5030B 8260D (SIM) 1 04/13/2023 1205 AMR2 72586
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 11 3.0 1.0 ug/L 2
Run 2 Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
101 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-001
Description: MW-9 Matrix: Aqueous
Date Sampled:04/04/2023 1210 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/11/2023 1245 JM1 72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
74-82-8 RSK - 175 2000 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-001
Description: MW-9 Matrix: Aqueous
Date Sampled:04/04/2023 1210 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1522 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00018 J 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-001
Description: MW-9 Matrix: Aqueous
Date Sampled:04/04/2023 1210 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
2 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1619 BNW
6020B 5 04/13/2023 1522 BNW
Prep Date Batch
04/10/2023 1837 72256
04/10/2023 1837 72256
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0 6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
360 D
25
6.3
ug/L
2
Beryllium
7440-41-7 6020B
0.23 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
4.4
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
1.3 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
7.2
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
16
5.0
1.3
ug/L
1
Lead
7439-92-1 6020B
1.6
1.0
0.25
ug/L
1
Nickel
7440-02-0 6020B
5.6
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
0.55
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
2.8 J
5.0
2.5
ug/L
1
Zinc
7440-66-6 6020B
31
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-002
Description: MW-36 Matrix: Aqueous
Date Sampled:04/04/2023 1245 Project Name: North Wake Unlined Landfill
Date Received: 04/05/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
04/06/2023 1945
JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1
04/10/2023 1559
HDT
04/05/2023 1854 71899
1
(Chloride) 300.0
1
04/05/2023 2043
SJL
71959
1
(CO2 (calcula) SM 4500-CO2 D
1
04/06/2023 1945
JJM
1
(COD) SM 5220D-2011
1
04/10/2023 1331
GGC
72111
1
(Nitrate - N) 300.0
5
04/05/2023 2102
SJL
71960
1
(Sulfate) 300.0
1
04/05/2023 2043
SJL
71961
1
(Sulfide) SM 4500-S2 F-2011
1
04/11/2023 1201
CVR
72342
1
(TOC) SM 531 OC-2014
1
04/15/2023 0534
DMA
72721
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
110
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
<2.1 6
2.0
0.18
mg/L
1
Chloride
300.0
14
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
470
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
300.0
0.26 D
0.10
0.025
mg/L
1
Sulfate
300.0
4.0
1.0
0.25
mg/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
TOC
SM 531OC-2014
1.7
1.0
1.0
mg/L
1
Footnote(s): 6-D.O. depletion < 2.00 mg/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-002
Description: MW-36 Matrix: Aqueous
Date Sampled:04/04/2023 1245 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 0451 CDA
72287
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.7
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
2.8
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
5.0
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
Footnote(s): 6-D.O. depletion < 2.00 mg/L
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-002
Description: MW-36 Matrix: Aqueous
Date Sampled:04/04/2023 1245 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 0451 CDA 72287
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
2.4
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
91 70-130
104 70-130
99 70-130
Footnote(s): 6-D.O. depletion < 2.00 mg/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-002
Description: MW-36 Matrix: Aqueous
Date Sampled:04/04/2023 1245 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 04/12/2023 1350 AMR2 72429
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 2.6 J 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
94 40-170
Footnote(s): 6-D.O. depletion < 2.00 mg/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-002
Description: MW-36 Matrix: Aqueous
Date Sampled:04/04/2023 1245 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/11/2023 1301 JM1 72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
74-82-8 RSK - 175 86 B 10 2.5 ug/L 1
Footnote(s): 6-D.O. depletion < 2.00 mg/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-002
Description: MW-36 Matrix: Aqueous
Date Sampled:04/04/2023 1245 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1525 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00013 J 0.00020 0.000091 mg/L 1
Footnote(s): 6-D.O. depletion < 2.00 mg/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 19 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-002
Description: MW-36 Matrix: Aqueous
Date Sampled:04/04/2023 1245 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1630 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
69
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.16 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.6
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.4 J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.1
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.39 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
3.0 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
6.3
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
9.9 J
10
2.5
ug/L
1
Footnote(s): 6-D.O. depletion < 2.00 mg/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
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Page 20 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-003
Description: MW-34 Matrix: Aqueous
Date Sampled:04/04/2023 1420 Project Name: North Wake Unlined Landfill
Date Received: 04/05/2023 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1 04/06/2023 1952 JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1 04/10/2023 1600 HDT
04/05/2023 1856
71899
1
(Chloride) 300.0
1 04/05/2023 2121 SJL
71959
1
(CO2 (calcula) SM 4500-CO2 D
1 04/06/2023 1952 JJM
1
(COD) SM 5220D-2011
1 04/10/2023 1333 GGC
72111
1
(Nitrate - N) 300.0
5 04/05/2023 2140 SJL
71960
1
(Sulfate) 300.0
1 04/05/2023 2121 SJL
71961
1
(Sulfide) SM 4500-S2 F-2011
1 04/11/2023 1201 CVR
72342
1
(TDS) SM 2540C-2015
1 04/11/2023 0235 CBP
72284
1
(TOC) SM 531 OC-2014
1 04/15/2023 0545 DMA
72721
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
43
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
23
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2 D
280
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
300.0
0.21 D
0.10
0.025
mg/L
1
Sulfate
300.0
1.0 U
1.0
0.25
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-2
1.0 US
1.0
1.0
mg/L
1
TDS
SM 254OC-2015
100
25
25
mg/L
1
TOC
SM 531OC-2014
1.0 U
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-003
Description: MW-34 Matrix: Aqueous
Date Sampled:04/04/2023 1420 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 0515 CDA
72287
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.62
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.42 J
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.5
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
1.5
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
8.0
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
11
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
4.5
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
1.6
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
2.1
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.54
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-003
Description: MW-34 Matrix: Aqueous
Date Sampled:04/04/2023 1420 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 0515 CDA 72287
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
102 70-130
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-003
Description: MW-34 Matrix: Aqueous
Date Sampled:04/04/2023 1420 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 04/12/2023 1414 AMR2 72429
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
95 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-003
Description: MW-34 Matrix: Aqueous
Date Sampled:04/04/2023 1420 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/11/2023 1317 JM1 72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
74-82-8 RSK - 175 550 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-003
Description: MW-34 Matrix: Aqueous
Date Sampled:04/04/2023 1420 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1528 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00013 J 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-003
Description: MW-34 Matrix: Aqueous
Date Sampled:04/04/2023 1420 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1739 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
100
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.34 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.3
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.7 J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
3.0 J
5.0
1.3
ug/L
1
Iron
7439-89-6
6020B
1600 S
50
13
ug/L
1
Lead
7439-92-1
6020B
0.51 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.9 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Sodium
7440-23-5
6020B
9100
400
150
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.9 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
13
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-004
Description: MW-34d Matrix: Aqueous
Date Sampled:04/04/2023 1500 Project Name: North Wake Unlined Landfill
Date Received: 04/05/2023 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1 04/06/2023 1958 JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1 04/10/2023 1623 HDT
04/05/2023 1913
71899
1
(Chloride) 300.0
1 04/05/2023 2159 SJL
71959
1
(CO2 (calcula) SM 4500-CO2 D
1 04/06/2023 1958 JJM
1
(COD) SM 5220D-2011
1 04/10/2023 1332 GGC
72111
1
(Nitrate - N) 300.0
5 04/05/2023 2217 SJL
71960
1
(Sulfate) 300.0
1 04/05/2023 2159 SJL
71961
1
(Sulfide) SM 4500-S2 F-2011
1 04/11/2023 1201 CVR
72342
1
(TDS) SM 2540C-2015
1 04/11/2023 0235 CBP
72284
1
(TOC) SM 531 OC-2014
1 04/15/2023 0641 DMA
72721
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
64
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
19
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2 D
180
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
300.0
4.3 D
0.10
0.025
mg/L
1
Sulfate
300.0
24
1.0
0.25
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
TDS
SM 254OC-2015
280
25
25
mg/L
1
TOC
SM 531OC-2014
1.0 U
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-004
Description: MW-34d Matrix: Aqueous
Date Sampled:04/04/2023 1500 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 0540 CDA
72287
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.0
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
2.2
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-004
Description: MW-34d Matrix: Aqueous
Date Sampled:04/04/2023 1500 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 0540 CDA 72287
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
103 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-004
Description: MW-34d Matrix: Aqueous
Date Sampled:04/04/2023 1500 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 04/12/2023 1437 AMR2 72429
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
96 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-004
Description: MW-34d Matrix: Aqueous
Date Sampled:04/04/2023 1500 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/11/2023 1332 JM1 72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
74-82-8 RSK - 175 7.4 BJ 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-004
Description: MW-34d Matrix: Aqueous
Date Sampled:04/04/2023 1500 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1530 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-004
Description: MW-34d Matrix: Aqueous
Date Sampled:04/04/2023 1500 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1642 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
30
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
7.0
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Iron
7439-89-6
6020B
21 J
50
13
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Sodium
7440-23-5
6020B
12000
400
150
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-005
Description: MW-5R Matrix: Aqueous
Date Sampled:04/04/2023 1540 Project Name: North Wake Unlined Landfill
Date Received: 04/05/2023 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1 04/06/2023 2005 JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1 04/10/2023 1623 HDT
04/05/2023 1913
71899
1
(Chloride) 300.0
1 04/05/2023 2236 SJL
71959
1
(CO2 (calcula) SM 4500-CO2 D
1 04/06/2023 2005 JJM
1
(COD) SM 5220D-2011
1 04/10/2023 1332 GGC
72111
1
(Nitrate - N) 300.0
5 04/05/2023 2255 SJL
71960
1
(Sulfate) 300.0
1 04/05/2023 2236 SJL
71961
1
(Sulfide) SM 4500-S2 F-2011
1 04/11/2023 1201 CVR
72342
1
(TDS) SM 2540C-2015
1 04/11/2023 0235 CBP
72284
1
(TOC) SM 531 OC-2014
1 04/15/2023 0653 DMA
72721
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
230
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
12
2.0
0.18
mg/L
1
Chloride
300.0
4.5
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2 D
730
27
27
mg/L
1
COD
SM 5220D-2011
42
20
20
mg/L
1
Nitrate - N
300.0
0.10 U
0.10
0.025
mg/L
1
Sulfate
300.0
1.0 U
1.0
0.25
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
TDS
SM 2540C-2015
1400
25
25
mg/L
1
TOC
SM 531OC-2014
9.9
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-005
Description: MW-5R Matrix: Aqueous
Date Sampled:04/04/2023 1540 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 0605 CDA
72287
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-005
Description: MW-5R Matrix: Aqueous
Date Sampled:04/04/2023 1540 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 0605 CDA 72287
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
92 70-130
101 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-005
Description: MW-5R Matrix: Aqueous
Date Sampled:04/04/2023 1540 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 04/12/2023 1501 AMR2 72429
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
90 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-005
Description: MW-5R Matrix: Aqueous
Date Sampled:04/04/2023 1540 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
RSK - 175
1
04/11/2023 1348 JM1
72481
2
RSK - 175
10
04/11/2023 1824 JM1
72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 13000 BD 100 25 ug/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-005
Description: MW-5R Matrix: Aqueous
Date Sampled:04/04/2023 1540 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1533 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-005
Description: MW-5R Matrix: Aqueous
Date Sampled:04/04/2023 1540 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
2 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1653 BNW
6020B 5 04/14/2023 1242 BNW
Prep Date Batch
04/10/2023 1837 72256
04/10/2023 1837 72256
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0 6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
68
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
0.16 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
36
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
5.0 U
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
60000 D
250
63
ug/L
2
Lead
7439-92-1 6020B
0.39 J
1.0
0.25
ug/L
1
Nickel
7440-02-0 6020B
9.0
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
1.0 U
1.0
0.25
ug/L
1
Sodium
7440-23-5 6020B
3900
400
150
ug/L
1
Thallium
7440-28-0 6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
2.9 J
5.0
2.5
ug/L
1
Zinc
7440-66-6 6020B
2.6 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-006
Description: MW-7 Matrix: Aqueous
Date Sampled:04/04/2023 1050 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 0629 CDA
72287
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.78
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.53
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.1
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-006
Description: MW-7 Matrix: Aqueous
Date Sampled:04/04/2023 1050 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 0629 CDA 72287
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
104 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-006
Description: MW-7 Matrix: Aqueous
Date Sampled:04/04/2023 1050 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1536 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-006
Description: MW-7 Matrix: Aqueous
Date Sampled:04/04/2023 1050 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1705 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
34
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.42 J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
32
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
8.5
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
16
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-007
Description: MW-32 Matrix: Aqueous
Date Sampled:04/04/2023 1105 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/20231353 JWO
72347
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.79
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-007
Description: MW-32 Matrix: Aqueous
Date Sampled:04/04/2023 1105 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/20231353 JWO 72347
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 UL
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
91 70-130
102 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-007
Description: MW-32 Matrix: Aqueous
Date Sampled:04/04/2023 1105 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1538 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 48 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-007
Description: MW-32 Matrix: Aqueous
Date Sampled:04/04/2023 1105 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1836 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
14
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.47
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020E
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.4 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
2.2 J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
8.3
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.1 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
6.8
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
4.7 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-008
Description: TB-1 a deep Matrix: Aqueous
Date Sampled:04/04/2023 1115 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 0046 CDA
72287
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
0.56
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 50 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-008
Description: TB-1 a deep Matrix: Aqueous
Date Sampled:04/04/2023 1115 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 0046 CDA 72287
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
90 70-130
102 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 51 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-008
Description: TB-1 a deep Matrix: Aqueous
Date Sampled:04/04/2023 1115 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1541 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 52 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-008
Description: TB-1 a deep Matrix: Aqueous
Date Sampled:04/04/2023 1115 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1847 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
15
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.19 J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.2 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.2 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.57 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.3 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.3 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
20
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 53 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-009
Description: MW-31d Matrix: Aqueous
Date Sampled:04/04/2023 1130 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/20231418 JWO
72347
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
2.8
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 54 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-009
Description: MW-31d Matrix: Aqueous
Date Sampled:04/04/2023 1130 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/20231418 JWO 72347
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 UL
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
105 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 55 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-009
Description: MW-31d Matrix: Aqueous
Date Sampled:04/04/2023 1130 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1544 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 56 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-009
Description: MW-31d Matrix: Aqueous
Date Sampled:04/04/2023 1130 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1859 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
1.6 J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
25
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.24 J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.9 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
3.9 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.68 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.9 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.9 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
86
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 57 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-010
Description: MW-23 Matrix: Aqueous
Date Sampled:04/04/2023 1140 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/20231443 JWO
72347
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 58 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-010
Description: MW-23 Matrix: Aqueous
Date Sampled:04/04/2023 1140 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/20231443 JWO 72347
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 UL
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
105 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 59 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-010
Description: MW-23 Matrix: Aqueous
Date Sampled:04/04/2023 1140 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1547 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 60 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-010
Description: MW-23 Matrix: Aqueous
Date Sampled:04/04/2023 1140 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1910 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
23
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.0 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.7 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.3
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.5 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.2
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
4.5 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 61 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-011
Description: MW-23d Matrix: Aqueous
Date Sampled:04/04/2023 1150 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/20231508 JWO
72347
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 62 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-011
Description: MW-23d Matrix: Aqueous
Date Sampled:04/04/2023 1150 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/20231508 JWO 72347
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 UL
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
104 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 63 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-011
Description: MW-23d Matrix: Aqueous
Date Sampled:04/04/2023 1150 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1600 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 64 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-011
Description: MW-23d Matrix: Aqueous
Date Sampled:04/04/2023 1150 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1922 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
0.68 J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
41
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.23 J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
1.6 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.9 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.0 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
8.6 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 65 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-012
Description: MW-35 Matrix: Aqueous
Date Sampled:04/04/2023 1335 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/20231533 JWO
72347
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
2.6
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
4.2
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
0.84
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.51
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
1.9
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
1.1
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
3.1
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 66 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-012
Description: MW-35 Matrix: Aqueous
Date Sampled:04/04/2023 1335 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/20231533 JWO 72347
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 UL
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
108 70-130
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 67 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-012
Description: MW-35 Matrix: Aqueous
Date Sampled:04/04/2023 1335 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1603 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 68 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-012
Description: MW-35 Matrix: Aqueous
Date Sampled:04/04/2023 1335 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 1956 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
38
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.36 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.4 J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
12
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 69 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-013
Description: MW-36d Matrix: Aqueous
Date Sampled:04/04/2023 1255 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/20231558 JWO
72347
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.8
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
3.0
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 70 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-013
Description: MW-36d Matrix: Aqueous
Date Sampled:04/04/2023 1255 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/20231558 JWO 72347
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 UL
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
94 70-130
104 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 71 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-013
Description: MW-36d Matrix: Aqueous
Date Sampled:04/04/2023 1255 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1605 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 72 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-013
Description: MW-36d Matrix: Aqueous
Date Sampled:04/04/2023 1255 Project Name: North Wake Unlined Landfill
Date Received:04/05/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2007 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
53
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.4 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
13
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.55 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.2 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
2.9 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
40
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 73 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-014
Description: MW-10 Matrix: Aqueous
Date Sampled:04/05/2023 0915 Project Name: North Wake Unlined Landfill
Date Received: 04/06/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
04/06/2023 2012
JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1
04/11/2023 1623
HDT
04/06/2023 2012 72001
1
(Chloride) 300.0
1
04/06/2023 1523
SJL
72050
1
(CO2 (calcula) SM 4500-CO2 D
1
04/06/2023 2012
JJM
1
(COD) SM 5220D-2011
1
04/10/2023 1338
GGC
72111
1
(Nitrate - N) 300.0
5
04/06/2023 1542
SJL
72051
1
(Sulfate) 300.0
1
04/06/2023 1523
SJL
72052
1
(Sulfide) SM 4500-S2 F-2011
1
04/12/2023 1226
CVR
72458
1
(TOC) SM 531 OC-2014
1
04/15/2023 0704
DMA
72721
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
140
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
2.7
2.0
0.18
mg/L
1
Chloride
300.0
2.9
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
510
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
300.0
0.13 D
0.10
0.025
mg/L
1
Sulfate
300.0
0.28 J
1.0
0.25
mg/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
TOC
SM 531OC-2014
1.0 U
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 74 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-014
Description: MW-10 Matrix: Aqueous
Date Sampled:04/05/2023 0915 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2050 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.51
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.75
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
1.2
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.42 J
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.82
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.81
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 75 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-014
Description: MW-10 Matrix: Aqueous
Date Sampled:04/05/2023 0915 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2050 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
1.1
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
103 70-130
116 70-130
92 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 76 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-014
Description: MW-10 Matrix: Aqueous
Date Sampled:04/05/2023 0915 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
RSK - 175
1
04/11/2023 1404 JM1
72481
2
RSK - 175
5
04/11/2023 1840 JM1
72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 8500 BD 50 13 ug/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 77 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-014
Description: MW-10 Matrix: Aqueous
Date Sampled:04/05/2023 0915 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1608 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00027 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 78 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-014
Description: MW-10 Matrix: Aqueous
Date Sampled:04/05/2023 0915 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2019 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
27
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.22 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.35 J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
3.2 J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.8 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
30
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 79 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-015
Description: MW-6 Matrix: Aqueous
Date Sampled:04/05/2023 1110 Project Name: North Wake Unlined Landfill
Date Received: 04/06/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
04/06/2023 2020
JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1
04/11/2023 1625
HDT
04/06/2023 2015 72001
1
(Chloride) 300.0
1
04/06/2023 1600
SJL
72050
1
(CO2 (calcula) SM 4500-CO2 D
1
04/06/2023 2020
JJM
1
(COD) SM 5220D-2011
1
04/10/2023 1336
GGC
72111
1
(Nitrate - N) 300.0
5
04/06/2023 1619
SJL
72051
1
(Sulfate) 300.0
1
04/06/2023 1600
SJL
72052
1
(Sulfide) SM 4500-S2 F-2011
1
04/12/2023 1226
CVR
72458
1
(TOC) SM 531 OC-2014
1
04/15/2023 0715
DMA
72721
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
360
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
72
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
470
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
300.0
5.8 D
0.10
0.025
mg/L
1
Sulfate
300.0
4.5
1.0
0.25
mg/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
TOC
SM 531OC-2014
4.2
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 80 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-015
Description: MW-6 Matrix: Aqueous
Date Sampled:04/05/2023 1110 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2115 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.91
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.53
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 81 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-015
Description: MW-6 Matrix: Aqueous
Date Sampled:04/05/2023 1110 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2115 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
106 70-130
116 70-130
93 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 82 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-015
Description: MW-6 Matrix: Aqueous
Date Sampled:04/05/2023 1110 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/11/2023 1420 JM1 72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
74-82-8 RSK - 175 9.2 BJ 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 83 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-015
Description: MW-6 Matrix: Aqueous
Date Sampled:04/05/2023 1110 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1611 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00016 J 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 84 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-015
Description: MW-6 Matrix: Aqueous
Date Sampled:04/05/2023 1110 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2030 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
140
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.8 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
4.0 J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.3 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.25 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
3.3 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.2 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
2.6 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 85 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-016
Description: MW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1242 Project Name: North Wake Unlined Landfill
Date Received: 04/06/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
04/06/2023 2036
JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1
04/11/2023 1629
HDT
04/06/2023 2040 72001
1
(Chloride) 300.0
1
04/06/2023 1638
SJL
72050
1
(CO2 (calcula) SM 4500-CO2 D
1
04/06/2023 2036
JJM
1
(COD) SM 5220D-2011
1
04/10/2023 1336
GGC
72111
1
(Nitrate - N) 300.0
5
04/06/2023 1657
SJL
72051
1
(Sulfate) 300.0
1
04/06/2023 1638
SJL
72052
1
(Sulfide) SM 4500-S2 F-2011
1
04/12/2023 1226
CVR
72458
1
(TOC) SM 531 OC-2014
1
04/15/2023 0727
DMA
72721
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
210
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
82
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
400
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
300.0
0.10 U
0.10
0.025
mg/L
1
Sulfate
300.0
2.0
1.0
0.25
mg/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
TOC
SM 531OC-2014
5.3
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 86 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-016
Description: MW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1242 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2140 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.81
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.91
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
2.5
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
20
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 87 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-016
Description: MW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1242 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2140 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.49 J
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
108 70-130
121 70-130
94 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 88 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-016
Description: MW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1242 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 04/12/2023 1525 AMR2 72429
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 11 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
95 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 89 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-016
Description: MW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1242 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/11/2023 1436 JM1 72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
74-82-8 RSK - 175 400 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 90 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-016
Description: MW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1242 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1613 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 91 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-016
Description: MW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1242 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2042 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
90
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020E
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.3 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
9.8
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
9.9
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
5.7 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 92 of 257

Inorganic non-metals
Client:CDM Smith Laboratory ID:YD05007-017
Description: MW-11 Matrix: Aqueous
Date Sampled:04/05/2023 1645 Project Name: North Wake Unlined Landfill
Date Received: 04/06/2023 Project Number:
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
04/06/2023 2043
JJM
72016
1
(BOD, 5 day) SM 521OB-2016
1
04/11/2023 1630
HDT
04/06/2023 2026 72001
1
(Chloride) 300.0
1
04/07/2023 1625
SJL
72112
1
(CO2 (calcula) SM 4500-CO2 D
1
04/06/2023 2043
JJM
1
(COD) SM 5220D-2011
1
04/10/2023 1337
GGC
72111
1
(Nitrate - N) 300.0
1
04/07/2023 1625
SJL
72114
2
(Sulfate) 300.0
1
04/10/2023 1548
SJL
72321
1
(Sulfide) SM 4500-S2 F-2011
1
04/12/2023 1226
CVR
72458
1
(TOC) SM 531 OC-2014
1
04/15/2023 0738
DMA
72721
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
46
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2016
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
5.6
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
120
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
300.0
0.85
0.020
0.0050
mg/L
1
Sulfate
300.0
1.0 U
1.0
0.25
mg/L
2
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0 US
1.0
1.0
mg/L
1
TOC
SM 531OC-2014
1.0 U
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 93 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-017
Description: MW-11 Matrix: Aqueous
Date Sampled:04/05/2023 1645 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2204 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 94 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-017
Description: MW-11 Matrix: Aqueous
Date Sampled:04/05/2023 1645 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2204 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
102 70-130
118 70-130
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 95 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-017
Description: MW-11 Matrix: Aqueous
Date Sampled:04/05/2023 1645 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 04/12/2023 1550 AMR2 72429
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
96 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 96 of 257

Dissolved Gases
Client:CDM Smith Laboratory ID:YD05007-017
Description: MW-11 Matrix: Aqueous
Date Sampled:04/05/2023 1645 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/11/2023 1452 JM1 72481
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
74-82-8 RSK - 175 4.0 BJ 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 97 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-017
Description: MW-11 Matrix: Aqueous
Date Sampled:04/05/2023 1645 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1616 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 98 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-017
Description: MW-11 Matrix: Aqueous
Date Sampled:04/05/2023 1645 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2053 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
50
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
1.3 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
5.5 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 99 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-018
Description: SW-2 Matrix: Aqueous
Date Sampled:04/05/2023 1740 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2229 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 100 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-018
Description: SW-2 Matrix: Aqueous
Date Sampled:04/05/2023 1740 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2229 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
104 70-130
121 70-130
93 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 101 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-018
Description: SW-2 Matrix: Aqueous
Date Sampled:04/05/2023 1740 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1619 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 102 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-018
Description: SW-2 Matrix: Aqueous
Date Sampled:04/05/2023 1740 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2105 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
38
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
2.5 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 103 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-019
Description: SW-3 Matrix: Aqueous
Date Sampled:04/05/2023 1800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2254 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 104 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-019
Description: SW-3 Matrix: Aqueous
Date Sampled:04/05/2023 1800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2254 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
103 70-130
116 70-130
92 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 105 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-019
Description: SW-3 Matrix: Aqueous
Date Sampled:04/05/2023 1800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1627 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 106 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-019
Description: SW-3 Matrix: Aqueous
Date Sampled:04/05/2023 1800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2116 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
38
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.5 J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.5 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.40 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.0 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
4.6 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 107 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-020
Description: SW-7 Matrix: Aqueous
Date Sampled:04/05/2023 1725 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2319 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 108 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-020
Description: SW-7 Matrix: Aqueous
Date Sampled:04/05/2023 1725 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2319 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
108 70-130
124 70-130
94 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 109 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-020
Description: SW-7 Matrix: Aqueous
Date Sampled:04/05/2023 1725 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 04/27/2023 1630 KAJ 04/12/2023 1239 72166
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 110 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-020
Description: SW-7 Matrix: Aqueous
Date Sampled:04/05/2023 1725 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2127 BNW
Prep Date Batch
04/10/2023 1837 72256
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
24
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 111 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-021
Description: SW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1730 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/11/2023 2343 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 112 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-021
Description: SW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1730 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/11/2023 2343 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
99 70-130
113 70-130
91 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 113 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-021
Description: SW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1730 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231429 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 114 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-021
Description: SW-8 Matrix: Aqueous
Date Sampled:04/05/2023 1730 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2247 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
24
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 115 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-022
Description: MW-10D Matrix: Aqueous
Date Sampled:04/05/2023 0955 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0009 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.81
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 116 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-022
Description: MW-10D Matrix: Aqueous
Date Sampled:04/05/2023 0955 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/2023 0009 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
107 70-130
122 70-130
93 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 117 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-022
Description: MW-10D Matrix: Aqueous
Date Sampled:04/05/2023 0955 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231431 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 118 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-022
Description: MW-10D Matrix: Aqueous
Date Sampled:04/05/2023 0955 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2259 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
0.85 J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
4.6 J
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.29 J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.7 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.31 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
9.3 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 119 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-023
Description: MW-6d Matrix: Aqueous
Date Sampled:04/05/2023 1040 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0033 JMM2
72379
2 5030B 8260D
1 04/21/2023 0241 CDA
73259
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.82
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.52
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
1.2
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
3.1
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
1.3
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.71 H
0.50
0.40
ug/L
2
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.49 J
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.62
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 120 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-023
Description: MW-6d Matrix: Aqueous
Date Sampled:04/05/2023 1040 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run
Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
5030B
8260D
1 04/12/2023 0033 JMM2
72379
2
5030B
8260D
1 04/21/2023 0241 CDA
73259
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.52
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2 Acceptance
Surrogate
Q % Recovery Limits
Q %
Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
102 70-130 H 94 70-130
120 70-130 H 99 70-130
91 70-130 H 98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 121 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-023
Description: MW-6d Matrix: Aqueous
Date Sampled:04/05/2023 1040 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231434 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 122 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-023
Description: MW-6d Matrix: Aqueous
Date Sampled:04/05/2023 1040 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2310 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
31
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.7 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.1 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 123 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-024
Description: DUP Matrix: Aqueous
Date Sampled:04/05/2023 0800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0058 JMM2
72379
2 5030B 8260D
1 04/21/2023 0304 CDA
73259
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.80
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.55
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
1.1
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
3.0
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
1.4
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.74 H
0.50
0.40
ug/L
2
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.56
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 124 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-024
Description: DUP Matrix: Aqueous
Date Sampled:04/05/2023 0800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run
Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
5030B
8260D
1 04/12/2023 0058 JMM2
72379
2
5030B
8260D
1 04/21/2023 0304 CDA
73259
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.46 J
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2 Acceptance
Surrogate
Q % Recovery Limits
Q %
Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
103 70-130 H 99 70-130
114 70-130 H 103 70-130
91 70-130 H 100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 125 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-024
Description: DUP Matrix: Aqueous
Date Sampled:04/05/2023 0800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231437 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 126 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-024
Description: DUP Matrix: Aqueous
Date Sampled:04/05/2023 0800 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2322 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
31
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.7 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.1 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 127 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-025
Description: ME-8d Matrix: Aqueous
Date Sampled:04/05/2023 1310 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0123 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 128 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-025
Description: ME-8d Matrix: Aqueous
Date Sampled:04/05/2023 1310 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/2023 0123 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
107 70-130
120 70-130
94 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 129 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-025
Description: ME-8d Matrix: Aqueous
Date Sampled:04/05/2023 1310 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231439 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 130 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-025
Description: ME-8d Matrix: Aqueous
Date Sampled:04/05/2023 1310 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/13/2023 0053 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
16
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.1 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.0 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 131 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-026
Description: MW-1d Matrix: Aqueous
Date Sampled:04/05/2023 1345 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0147 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 132 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-026
Description: MW-1d Matrix: Aqueous
Date Sampled:04/05/2023 1345 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/2023 0147 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
109 70-130
124 70-130
96 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 133 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-026
Description: MW-1d Matrix: Aqueous
Date Sampled:04/05/2023 1345 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231442 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 134 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-026
Description: MW-1d Matrix: Aqueous
Date Sampled:04/05/2023 1345 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2333 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
42
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
1.9 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
3.9 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 135 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-027
Description: MW-29d Matrix: Aqueous
Date Sampled:04/05/2023 1410 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0212 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 136 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-027
Description: MW-29d Matrix: Aqueous
Date Sampled:04/05/2023 1410 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/2023 0212 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
105 70-130
119 70-130
93 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 137 of 257

Semivolatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-027
Description: MW-29d Matrix: Aqueous
Date Sampled:04/05/2023 1410 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3520C 8270E 1 04/11/2023 1701 CMF 04/10/2023 1000 72208
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
bis(2-Ethylhexyl)phthalate 117-81-7 8270E 3.9 J 4.0 1.5 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
75 37-129
43 24-127
79 38-127
50 28-128
94 10-148
77 35-144
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 138 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-027
Description: MW-29d Matrix: Aqueous
Date Sampled:04/05/2023 1410 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231455 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 139 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-027
Description: MW-29d Matrix: Aqueous
Date Sampled:04/05/2023 1410 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2344 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
34
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
7.0
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
7.0
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.89 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.5 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.7 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
56
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 140 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-028
Description: MW-28d Matrix: Aqueous
Date Sampled:04/05/2023 1440 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0236 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 141 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-028
Description: MW-28d Matrix: Aqueous
Date Sampled:04/05/2023 1440 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/2023 0236 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
103 70-130
121 70-130
92 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 142 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-028
Description: MW-28d Matrix: Aqueous
Date Sampled:04/05/2023 1440 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231458 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 143 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-028
Description: MW-28d Matrix: Aqueous
Date Sampled:04/05/2023 1440 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/12/2023 2356 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
1.1 J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
1.9 J
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
6.8
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.8 J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.68 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.1 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
11
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
11
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 144 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-029
Description: MW-28 Matrix: Aqueous
Date Sampled:04/05/2023 1515 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0301 JMM2
72379
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 145 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-029
Description: MW-28 Matrix: Aqueous
Date Sampled:04/05/2023 1515 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/2023 0301 JMM2 72379
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
107 70-130
125 70-130
95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 146 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-029
Description: MW-28 Matrix: Aqueous
Date Sampled:04/05/2023 1515 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231501 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 147 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-029
Description: MW-28 Matrix: Aqueous
Date Sampled:04/05/2023 1515 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/13/2023 0007 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
33
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.23 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.9
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.69 J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.8 J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
9.4
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
15
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 148 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-030
Description: MW-33 Matrix: Aqueous
Date Sampled:04/05/2023 1705 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/20231501 JWO
72496
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10 UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 UL
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 149 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-030
Description: MW-33 Matrix: Aqueous
Date Sampled:04/05/2023 1705 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/20231501 JWO 72496
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
107 70-130
118 70-130
96 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 150 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-030
Description: MW-33 Matrix: Aqueous
Date Sampled:04/05/2023 1705 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231503 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 151 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-030
Description: MW-33 Matrix: Aqueous
Date Sampled:04/05/2023 1705 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/13/2023 0019 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
36
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.8 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.8 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
4.7 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 152 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-031
Description: EQ Blank Matrix: Aqueous
Date Sampled:04/05/2023 1455 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 04/12/2023 0133 CDA
72381
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
4.8 J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0 U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50 U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50 U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50 U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50 U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10 U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50 U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50 U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50 U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50 U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0 U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50 U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50 U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50 U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50 U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50 U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50 U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50 U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50 U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10 U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0 U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10 U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50 U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50 U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50 U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50 U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50 U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50 U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50 U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of compound exceeded the
calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 153 of 257

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:YD05007-031
Description: EQ Blank Matrix: Aqueous
Date Sampled:04/05/2023 1455 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 04/12/2023 0133 CDA 72381
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50 UL
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
91 70-130
105 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 154 of 257

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:YD05007-031
Description: EQ Blank Matrix: Aqueous
Date Sampled:04/05/2023 1455 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 04/12/2023 1150 AMR2 72429
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
95 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 155 of 257

CVAA
Client:CDM Smith Laboratory ID:YD05007-031
Description: EQ Blank Matrix: Aqueous
Date Sampled:04/05/2023 1455 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 7470A 1 04/27/20231506 KAJ 04/24/20231021 73236
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 156 of 257

ICP-MS Metals
Client:CDM Smith Laboratory ID:YD05007-031
Description: EQ Blank Matrix: Aqueous
Date Sampled:04/05/2023 1455 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 04/13/2023 0150 BNW
Prep Date Batch
04/10/2023 1837 72257
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
5.0 U
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0 U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0 U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 157 of 257

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 158 of 257

Inorganic non-metals - BOD Blank and GGA
Matrix: Aqueous
Batch: 71899 SCF: 1.1
Analytical Method: SM 521 OB-2016 SCF Range: 0.6 - 1.0
Result Avg. Result
Sample ID
Depl
Avg. Depl (mg/L) (mg/L) Q
Limit
Prep Date
Analysis Date
YQ71899-041 (Blank)
-0.01
0.2
04/05/2023 1804
04/10/2023 1530
YQ71899-141 (Blank)
-0.02
0.2
04/05/2023 1805
04/10/2023 1530
YQ71899-241 (Blank)
0.08
0.02
0.2
04/05/2023 1804
04/10/2023 1530
YQ71899-035 (GGA)
183.8
167.5-228.5
04/05/2023 1811
04/10/2023 1535
YQ71899-135 (GGA)
191.8
167.5-228.5
04/05/2023 1811
04/10/2023 1535
YQ71899-235 (GGA)
193.8 189.8
167.5-228.5
04/05/2023 1811
04/10/2023 1535
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 159 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ71959-001 Matrix: Aqueous
Batch: 71959
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.25 mg/L 04/05/20231440
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 160 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ71959-002 Matrix: Aqueous
Batch: 71959
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 21 1 106 90-110 04/05/20231517
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 161 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ71960-001 Matrix: Aqueous
Batch: 71960
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 04/05/2023 1440
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 162 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ71960-002 Matrix: Aqueous
Batch: 71960
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.84 1 104 90-110 04/05/2023 1517
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 163 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ71961-001 Matrix: Aqueous
Batch:71961
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.25 mg/L 04/05/20231440
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 164 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ71961-002 Matrix: Aqueous
Batch:71961
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 21 1 103 90-110 04/05/20231517
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 165 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - BOD Blank and GGA
Matrix: Aqueous
Batch: 72001 SCF: 1.1
Analytical Method: SM 521 OB-2016 SCF Range: 0.6 - 1.0
Result Avg. Result
Sample ID
Depl
Avg. Depl (mg/L) (mg/L) Q
Limit
Prep Date
Analysis Date
YQ72001-041 (Blank)
0.11
0.2
04/06/2023 1959
04/11/2023 1613
YQ72001-141 (Blank)
0.13
0.2
04/06/2023 1959
04/11/2023 1613
YQ72001-241 (Blank)
0.16
0.13
0.2
04/06/2023 1959
04/11/2023 1613
YQ72001-035 (GGA)
184.1
167.5-228.5
04/06/2023 2006
04/11/2023 1618
YQ72001-135 (GGA)
162.1 1
167.5-228.5
04/06/2023 2006
04/11/2023 1619
YQ72001-235 (GGA)
195.1 180.4
167.5-228.5
04/06/2023 2006
04/11/2023 1617
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 166 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72016-002 Matrix: Aqueous
Batch: 72016
Analytical Method: SM 2320B-2011
Spike
Amount Result %Rec
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date
Alkalinity @ pH 4.5 su 100 100 1 104 90-110 04/06/2023 1930
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 167 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72050-001 Matrix: Aqueous
Batch: 72050
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.25 mg/L 04/06/20231407
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 168 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72050-002 Matrix: Aqueous
Batch: 72050
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 20 1 101 90-110 04/06/20231445
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 169 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72051-001 Matrix: Aqueous
Batch: 72051
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 04/06/2023 1407
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 170 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72051-002 Matrix: Aqueous
Batch: 72051
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.79 1 99 90-110 04/06/2023 1445
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 171 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72052-001 Matrix: Aqueous
Batch: 72052
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.25 mg/L 04/06/20231407
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 172 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72052-002 Matrix: Aqueous
Batch: 72052
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 20 1 100 90-110 04/06/20231445
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 173 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72111-001 Matrix: Aqueous
Batch:72111
Analytical Method: SM 5220D-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
COD 20 U 1 20 20 mg/L 04/10/20231325
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 174 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72111-002 Matrix: Aqueous
Batch:72111
Analytical Method: SM 5220D-2011
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
COD 40 40 1 101 95-105 04/10/20231328
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 175 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MS
Sample ID: YD05007-003MS Matrix: Aqueous
Batch:72111
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
COD 0.0 40 40 1 101 90-110 04/10/20231333
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 176 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MSD
Sample ID: YD05007-003MD Matrix: Aqueous
Batch:72111
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
COD 0.0 40 42 1 106 4.7 90-110 20 04/10/20231334
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 177 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MS
Sample ID: YD05007-014MS Matrix: Aqueous
Batch:72111
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
COD 0.0 40 41 1 103 90-110 04/10/20231339
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 178 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MSD
Sample ID: YD05007-014MD Matrix: Aqueous
Batch:72111
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
COD 0.0 40 41 1 103 0.00 90-110 20 04/10/20231339
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 179 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72112-001 Matrix: Aqueous
Batch: 72112
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.25 mg/L 04/07/2023 0924
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 180 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72112-002 Matrix: Aqueous
Batch: 72112
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 20 1 101 90-110 04/07/20231002
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 181 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72114-001 Matrix: Aqueous
Batch: 72114
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 04/07/2023 0924
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 182 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72114-002 Matrix: Aqueous
Batch: 72114
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.82 1 102 90-110 04/07/2023 1002
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 183 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72284-001 Matrix: Aqueous
Batch:72284
Analytical Method: SM 2540C-2015
Parameter Result Q Dil LOQ DL Units Analysis Date
TDS 25 U 1 25 25 mg/L 04/11/2023 0235
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 184 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72284-002 Matrix: Aqueous
Batch:72284
Analytical Method: SM 2540C-2015
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
TDS 50 49 1 98 90-110 04/11/2023 0235
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 185 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - Duplicate
Sample ID: YD05007-003DU Matrix: Aqueous
Batch:72284
Analytical Method: SM 2540C-2015
Sample
Amount Result %RPD
Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date
TDS 100 100 1 0.00 20 04/11/2023 0235
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 186 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72321-001 Matrix: Aqueous
Batch:72321
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.25 mg/L 04/10/20231452
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 187 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72321-002 Matrix: Aqueous
Batch:72321
Analytical Method: 300.0
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 20 1 98 90-110 04/10/20231530
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 188 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MS
Sample ID: YD05007-017MS Matrix: Aqueous
Batch:72321
Analytical Method: 300.0
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 0.0 10 9.4 1 94 90-110 04/10/20231607
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 189 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MSD
Sample ID: YD05007-017MD Matrix: Aqueous
Batch:72321
Analytical Method: 300.0
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfate 0.0 10 9.4 1 94 0.33 90-110 20 04/10/20231626
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 190 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72342-001 Matrix: Aqueous
Batch:72342
Analytical Method: SM 4500-S2 F-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfide 1.0 U 1 1.0 1.0 mg/L 04/11/20231201
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 191 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72342-002 Matrix: Aqueous
Batch:72342
Analytical Method: SM 4500-S2 F-2011
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 10 9.5 1 95 80-120 04/11/20231201
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 192 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MS
Sample ID: YD05007-003MS Matrix: Aqueous
Batch:72342
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 0.0 10 5.8 N 1 58 70-130 04/11/20231201
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 193 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MSD
Sample ID: YD05007-003MD Matrix: Aqueous
Batch:72342
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfide 0.0 10 6.2 N 1 62 7.5 70-130 20 04/11/20231201
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 194 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72458-001 Matrix: Aqueous
Batch: 72458
Analytical Method: SM 4500-S2 F-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfide 1.0 U 1 1.0 1.0 mg/L 04/12/20231226
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 195 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72458-002 Matrix: Aqueous
Batch: 72458
Analytical Method: SM 4500-S2 F-2011
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 10 9.2 1 92 80-120 04/12/20231226
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 196 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MS
Sample ID: YD05007-017MS Matrix: Aqueous
Batch: 72458
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 0.0 10 6.7 N 1 67 70-130 04/12/20231226
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 197 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MSD
Sample ID: YD05007-017MD Matrix: Aqueous
Batch: 72458
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfide 0.0 10 6.4 N 1 64 3.8 70-130 20 04/12/20231226
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 198 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MB
Sample ID: YQ72721-001 Matrix: Aqueous
Batch:72721
Analytical Method: SM 531 OC-2014
Parameter Result Q Dil LOQ DL Units Analysis Date
TOC 1.0 U 1 1.0 1.0 mg/L 04/15/2023 0212
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 199 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - LCS
Sample ID: YQ72721-002 Matrix: Aqueous
Batch:72721
Analytical Method: SM 531 OC-2014
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
TOC 20 18 1 92 90-110 04/15/2023 0223
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 200 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MS
Sample ID: YD05007-003MS Matrix: Aqueous
Batch:72721
Analytical Method: SM 531 OC-2014
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
TOC 0.0 50 50 1 100 70-130 04/15/2023 0556
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 201 of 257
QC Data for Lot Number: YD05007

Inorganic non-metals - MSD
Sample ID: YD05007-003MD Matrix: Aqueous
Batch:72721
Analytical Method: SM 531 OC-2014
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
TOC 0.0 50 49 1 98 1.1 70-130 20 04/15/2023 0608
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 202 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72287-001 Matrix: Aqueous
Batch: 72287 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
04/10/2023 2254
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
04/10/2023 2254
Benzene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Bromoform
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
04/10/2023 2254
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Chloroethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Chloroform
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
04/10/2023 2254
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
04/10/2023 2254
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
04/10/2023 2254
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
04/10/2023 2254
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/10/2023 2254
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/10/2023 2254
Dichlorodifluoromethane
0.50
u
1
0.50
0.40
ug/L
04/10/2023 2254
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
04/10/2023 2254
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
2-Hexanone
10
U
1
10
2.0
ug/L
04/10/2023 2254
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
04/10/2023 2254
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
04/10/2023 2254
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Styrene
0.50
U
1
0.50
0.41
ug/L
04/10/2023 2254
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Toluene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 203 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72287-001 Matrix: Aqueous
Batch:72287 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
04/10/2023 2254
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
04/10/2023 2254
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
04/10/2023 2254
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 94 70-130
1,2-Dichloroethane-d4 100 70-130
Toluene-d8 101 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 204 of 257

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72287-002
Matrix: Aqueous
Batch: 72287
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
94
1
94
60-140
04/10/2023 2108
Acrylonitrile
100
110
1
113
70-130
04/10/2023 2108
Benzene
50
56
1
112
70-130
04/10/2023 2108
Bromochloromethane
50
51
1
103
70-130
04/10/2023 2108
Bromodichloromethane
50
50
1
101
70-130
04/10/2023 2108
Bromoform
50
47
1
95
70-130
04/10/2023 2108
Bromomethane (Methyl bromide)
50
43
1
87
70-130
04/10/2023 2108
2-Butanone (MEK)
100
98
1
98
70-130
04/10/2023 2108
Carbon disulfide
50
53
1
106
70-130
04/10/2023 2108
Carbon tetrachloride
50
53
1
107
70-130
04/10/2023 2108
Chlorobenzene
50
53
1
105
70-130
04/10/2023 2108
Chloroethane
50
56
1
112
70-130
04/10/2023 2108
Chloroform
50
50
1
101
70-130
04/10/2023 2108
Chloromethane (Methyl chloride)
50
58
1
115
60-140
04/10/2023 2108
1,2-Dibromo-3-chloropropane (DBCP)
50
51
1
102
70-130
04/10/2023 2108
Dibromochloromethane
50
50
1
101
70-130
04/10/2023 2108
1,2-Dibromoethane (EDB)
50
52
1
104
70-130
04/10/2023 2108
Dibromomethane (Methylene bromide)
50
52
1
104
70-130
04/10/2023 2108
trans- 1,4-Dichloro-2-butene
50
48
1
97
70-130
04/10/2023 2108
1,2-Dichlorobenzene
50
52
1
103
70-130
04/10/2023 2108
1,4-Dichlorobenzene
50
51
1
103
70-130
04/10/2023 2108
Dichlorodifluoromethane
50
54
1
108
60-140
04/10/2023 2108
1,1-Dichloroethane
50
55
1
109
70-130
04/10/2023 2108
1,2-Dichloroethane
50
53
1
106
70-130
04/10/2023 2108
1,1-Dichloroethene
50
51
1
102
70-130
04/10/2023 2108
cis- 1,2-Dichloroethene
50
53
1
105
70-130
04/10/2023 2108
trans- 1,2-Dichloroethene
50
52
1
103
70-130
04/10/2023 2108
1,2-Dichloropropane
50
51
1
102
70-130
04/10/2023 2108
cis- 1,3-Dichloropropene
50
54
1
107
70-130
04/10/2023 2108
trans- 1,3-Dichloropropene
50
54
1
107
70-130
04/10/2023 2108
Ethylbenzene
50
53
1
106
70-130
04/10/2023 2108
2-Hexanone
100
100
1
102
70-130
04/10/2023 2108
Methyl iodide (lodomethane)
50
53
1
106
70-130
04/10/2023 2108
4-Methyl-2-pentanone
100
110
1
106
70-130
04/10/2023 2108
Methylene chloride
50
55
1
110
70-130
04/10/2023 2108
Styrene
50
54
1
107
70-130
04/10/2023 2108
1,1,1,2-Tetrachloroethane
50
52
1
104
70-130
04/10/2023 2108
1,1,2,2-Tetrachloroethane
50
51
1
103
70-130
04/10/2023 2108
Tetrachloroethene
50
51
1
101
70-130
04/10/2023 2108
Toluene
50
53
1
107
70-130
04/10/2023 2108
1,1,1-Trichloroethane
50
53
1
106
70-130
04/10/2023 2108
1,1,2-Trichloroethane
50
50
1
101
70-130
04/10/2023 2108
Trichloroethene
50
52
1
104
70-130
04/10/2023 2108
Trichlorofluoromethane
50
53
1
106
70-130
04/10/2023 2108
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 205 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72287-002
Matrix: Aqueous
Batch:72287
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
58
1 116
70-130
04/10/2023 2108
Vinyl acetate
50
54
1 108
60-140
04/10/2023 2108
Vinyl chloride
50
61
1 122
70-130
04/10/2023 2108
Xylenes (total)
100
110
1 106
70-130
04/10/2023 2108
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 99 70-130
Toluene-d8 103 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 206 of 257

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72347-001 Matrix: Aqueous
Batch: 72347 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
04/11/2023 1055
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
04/11/2023 1055
Benzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Bromoform
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
04/11/2023 1055
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Chloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Chloroform
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1055
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1055
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1055
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
04/11/2023 1055
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1055
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1055
Dichlorodifluoromethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1055
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1055
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
2-Hexanone
10
U
1
10
2.0
ug/L
04/11/2023 1055
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
04/11/2023 1055
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
04/11/2023 1055
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Styrene
0.50
U
1
0.50
0.41
ug/L
04/11/2023 1055
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Toluene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 207 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72347-001 Matrix: Aqueous
Batch:72347 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
04/11/2023 1055
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1055
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
04/11/2023 1055
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 95 70-130
1,2-Dichloroethane-d4 103 70-130
Toluene-d8 102 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 208 of 257

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72347-002
Matrix: Aqueous
Batch: 72347
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
88
1
88
60-140
04/11/2023 0919
Acrylonitrile
100
110
1
108
70-130
04/11/2023 0919
Benzene
50
59
1
118
70-130
04/11/2023 0919
Bromochloromethane
50
54
1
107
70-130
04/11/2023 0919
Bromodichloromethane
50
53
1
107
70-130
04/11/2023 0919
Bromoform
50
47
1
94
70-130
04/11/2023 0919
Bromomethane (Methyl bromide)
50
47
1
95
70-130
04/11/2023 0919
2-Butanone (MEK)
100
100
1
104
70-130
04/11/2023 0919
Carbon disulfide
50
60
1
120
70-130
04/11/2023 0919
Carbon tetrachloride
50
58
1
117
70-130
04/11/2023 0919
Chlorobenzene
50
53
1
106
70-130
04/11/2023 0919
Chloroethane
50
63
1
126
70-130
04/11/2023 0919
Chloroform
50
54
1
109
70-130
04/11/2023 0919
Chloromethane (Methyl chloride)
50
64
1
127
60-140
04/11/2023 0919
1,2-Dibromo-3-chloropropane (DBCP)
50
51
1
103
70-130
04/11/2023 0919
Dibromochloromethane
50
51
1
101
70-130
04/11/2023 0919
1,2-Dibromoethane (EDB)
50
51
1
102
70-130
04/11/2023 0919
Dibromomethane (Methylene bromide)
50
54
1
108
70-130
04/11/2023 0919
trans- 1,4-Dichloro-2-butene
50
47
1
95
70-130
04/11/2023 0919
1,2-Dichlorobenzene
50
53
1
105
70-130
04/11/2023 0919
1,4-Dichlorobenzene
50
52
1
104
70-130
04/11/2023 0919
Dichlorodifluoromethane
50
61
1
121
60-140
04/11/2023 0919
1,1-Dichloroethane
50
60
1
119
70-130
04/11/2023 0919
1,2-Dichloroethane
50
56
1
113
70-130
04/11/2023 0919
1,1-Dichloroethene
50
56
1
112
70-130
04/11/2023 0919
cis- 1,2-Dichloroethene
50
55
1
110
70-130
04/11/2023 0919
trans- 1,2-Dichloroethene
50
56
1
112
70-130
04/11/2023 0919
1,2-Dichloropropane
50
53
1
107
70-130
04/11/2023 0919
cis- 1,3-Dichloropropene
50
57
1
113
70-130
04/11/2023 0919
trans- 1,3-Dichloropropene
50
55
1
111
70-130
04/11/2023 0919
Ethylbenzene
50
53
1
107
70-130
04/11/2023 0919
2-Hexanone
100
100
1
102
70-130
04/11/2023 0919
Methyl iodide (lodomethane)
50
55
1
111
70-130
04/11/2023 0919
4-Methyl-2-pentanone
100
100
1
105
70-130
04/11/2023 0919
Methylene chloride
50
59
1
117
70-130
04/11/2023 0919
Styrene
50
54
1
109
70-130
04/11/2023 0919
1,1,1,2-Tetrachloroethane
50
53
1
106
70-130
04/11/2023 0919
1,1,2,2-Tetrachloroethane
50
54
1
108
70-130
04/11/2023 0919
Tetrachloroethene
50
51
1
101
70-130
04/11/2023 0919
Toluene
50
55
1
109
70-130
04/11/2023 0919
1,1,1-Trichloroethane
50
59
1
117
70-130
04/11/2023 0919
1,1,2-Trichloroethane
50
51
1
102
70-130
04/11/2023 0919
Trichloroethene
50
54
1
107
70-130
04/11/2023 0919
Trichlorofluoromethane
50
58
1
117
70-130
04/11/2023 0919
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 209 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72347-002
Matrix: Aqueous
Batch:72347
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
52
1 104
70-130
04/11/2023 0919
Vinyl acetate
50
62
1 125
60-140
04/11/2023 0919
Vinyl chloride
50
68 N
1 136
70-130
04/11/2023 0919
Xylenes (total)
100
110
1 107
70-130
04/11/2023 0919
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 98 70-130
1,2-Dichloroethane-d4 104 70-130
Toluene-d8 104 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 210 of 257

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72379-001 Matrix: Aqueous
Batch: 72379 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
04/11/2023 1910
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
04/11/2023 1910
Benzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Bromoform
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
04/11/2023 1910
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Chloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Chloroform
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1910
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1910
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1910
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
04/11/2023 1910
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1910
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1910
Dichlorodifluoromethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1910
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 1910
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
2-Hexanone
10
U
1
10
2.0
ug/L
04/11/2023 1910
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
04/11/2023 1910
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
04/11/2023 1910
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Styrene
0.50
U
1
0.50
0.41
ug/L
04/11/2023 1910
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Toluene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 211 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72379-001 Matrix: Aqueous
Batch:72379 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
04/11/2023 1910
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 1910
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
04/11/2023 1910
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 106 70-130
1,2-Dichloroethane-d4 118 70-130
Toluene-d8 94 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 212 of 257

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72379-002
Matrix: Aqueous
Batch: 72379
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q
Dil
% Rec
Limit
Analysis Date
Acetone
100
200
N
1
205
60-140
04/11/2023 1821
Acrylonitrile
100
170
N
1
165
70-130
04/11/2023 1821
Benzene
50
51
1
102
70-130
04/11/2023 1821
Bromochloromethane
50
51
1
103
70-130
04/11/2023 1821
Bromodichloromethane
50
52
1
104
70-130
04/11/2023 1821
Bromoform
50
44
1
87
70-130
04/11/2023 1821
Bromomethane (Methyl bromide)
50
46
1
93
70-130
04/11/2023 1821
2-Butanone (MEK)
100
140
N
1
139
70-130
04/11/2023 1821
Carbon disulfide
50
55
1
110
70-130
04/11/2023 1821
Carbon tetrachloride
50
50
1
100
70-130
04/11/2023 1821
Chlorobenzene
50
49
1
98
70-130
04/11/2023 1821
Chloroethane
50
59
1
117
70-130
04/11/2023 1821
Chloroform
50
55
1
111
70-130
04/11/2023 1821
Chloromethane (Methyl chloride)
50
60
1
120
60-140
04/11/2023 1821
1,2-Dibromo-3-chloropropane (DBCP)
50
57
1
114
70-130
04/11/2023 1821
Dibromochloromethane
50
51
1
102
70-130
04/11/2023 1821
1,2-Dibromoethane (EDB)
50
52
1
104
70-130
04/11/2023 1821
Dibromomethane (Methylene bromide)
50
56
1
113
70-130
04/11/2023 1821
trans- 1,4-Dichloro-2-butene
50
40
1
81
70-130
04/11/2023 1821
1,2-Dichlorobenzene
50
49
1
99
70-130
04/11/2023 1821
1,4-Dichlorobenzene
50
48
1
96
70-130
04/11/2023 1821
Dichlorodifluoromethane
50
51
1
101
60-140
04/11/2023 1821
1,1-Dichloroethane
50
52
1
105
70-130
04/11/2023 1821
1,2-Dichloroethane
50
58
1
116
70-130
04/11/2023 1821
1,1-Dichloroethene
50
51
1
101
70-130
04/11/2023 1821
cis- 1,2-Dichloroethene
50
51
1
101
70-130
04/11/2023 1821
trans- 1,2-Dichloroethene
50
49
1
97
70-130
04/11/2023 1821
1,2-Dichloropropane
50
54
1
107
70-130
04/11/2023 1821
cis- 1,3-Dichloropropene
50
53
1
105
70-130
04/11/2023 1821
trans- 1,3-Dichloropropene
50
53
1
105
70-130
04/11/2023 1821
Ethylbenzene
50
49
1
97
70-130
04/11/2023 1821
2-Hexanone
100
100
1
102
70-130
04/11/2023 1821
Methyl iodide (lodomethane)
50
52
1
105
70-130
04/11/2023 1821
4-Methyl-2-pentanone
100
120
1
121
70-130
04/11/2023 1821
Methylene chloride
50
63
1
127
70-130
04/11/2023 1821
Styrene
50
49
1
98
70-130
04/11/2023 1821
1,1,1,2-Tetrachloroethane
50
53
1
105
70-130
04/11/2023 1821
1,1,2,2-Tetrachloroethane
50
57
1
114
70-130
04/11/2023 1821
Tetrachloroethene
50
46
1
92
70-130
04/11/2023 1821
Toluene
50
50
1
100
70-130
04/11/2023 1821
1,1,1-Trichloroethane
50
52
1
104
70-130
04/11/2023 1821
1,1,2-Trichloroethane
50
51
1
101
70-130
04/11/2023 1821
Trichloroethene
50
46
1
93
70-130
04/11/2023 1821
Trichlorofluoromethane
50
52
1
103
70-130
04/11/2023 1821
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 213 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72379-002
Matrix: Aqueous
Batch:72379
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
53
1 105
70-130
04/11/2023 1821
Vinyl acetate
50
57
1 115
60-140
04/11/2023 1821
Vinyl chloride
50
57
1 114
70-130
04/11/2023 1821
Xylenes (total)
100
99
1 99
70-130
04/11/2023 1821
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 116 70-130
Toluene-d8 92 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 214 of 257

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72381-001 Matrix: Aqueous
Batch: 72381 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
04/11/2023 2328
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
04/11/2023 2328
Benzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Bromoform
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
04/11/2023 2328
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Chloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Chloroform
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 2328
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
04/11/2023 2328
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
04/11/2023 2328
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
04/11/2023 2328
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/11/2023 2328
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/11/2023 2328
Dichlorodifluoromethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 2328
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
04/11/2023 2328
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
2-Hexanone
10
U
1
10
2.0
ug/L
04/11/2023 2328
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
04/11/2023 2328
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
04/11/2023 2328
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Styrene
0.50
U
1
0.50
0.41
ug/L
04/11/2023 2328
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Toluene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 215 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72381-001 Matrix: Aqueous
Batch:72381 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
04/11/2023 2328
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
04/11/2023 2328
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
04/11/2023 2328
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 93 70-130
1,2-Dichloroethane-d4 104 70-130
Toluene-d8 100 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 216 of 257

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72381-002
Matrix: Aqueous
Batch: 72381
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
92
1
92
60-140
04/11/2023 2138
Acrylonitrile
100
120
1
116
70-130
04/11/2023 2138
Benzene
50
57
1
114
70-130
04/11/2023 2138
Bromochloromethane
50
52
1
104
70-130
04/11/2023 2138
Bromodichloromethane
50
50
1
100
70-130
04/11/2023 2138
Bromoform
50
43
1
86
70-130
04/11/2023 2138
Bromomethane (Methyl bromide)
50
45
1
90
70-130
04/11/2023 2138
2-Butanone (MEK)
100
99
1
99
70-130
04/11/2023 2138
Carbon disulfide
50
54
1
108
70-130
04/11/2023 2138
Carbon tetrachloride
50
54
1
108
70-130
04/11/2023 2138
Chlorobenzene
50
52
1
103
70-130
04/11/2023 2138
Chloroethane
50
63
1
126
70-130
04/11/2023 2138
Chloroform
50
53
1
106
70-130
04/11/2023 2138
Chloromethane (Methyl chloride)
50
65
1
129
60-140
04/11/2023 2138
1,2-Dibromo-3-chloropropane (DBCP)
50
53
1
106
70-130
04/11/2023 2138
Dibromochloromethane
50
47
1
95
70-130
04/11/2023 2138
1,2-Dibromoethane (EDB)
50
50
1
101
70-130
04/11/2023 2138
Dibromomethane (Methylene bromide)
50
51
1
103
70-130
04/11/2023 2138
trans- 1,4-Dichloro-2-butene
50
51
1
102
70-130
04/11/2023 2138
1,2-Dichlorobenzene
50
52
1
105
70-130
04/11/2023 2138
1,4-Dichlorobenzene
50
52
1
103
70-130
04/11/2023 2138
Dichlorodifluoromethane
50
58
1
116
60-140
04/11/2023 2138
1,1-Dichloroethane
50
58
1
117
70-130
04/11/2023 2138
1,2-Dichloroethane
50
54
1
108
70-130
04/11/2023 2138
1,1-Dichloroethene
50
52
1
104
70-130
04/11/2023 2138
cis- 1,2-Dichloroethene
50
54
1
108
70-130
04/11/2023 2138
trans- 1,2-Dichloroethene
50
53
1
106
70-130
04/11/2023 2138
1,2-Dichloropropane
50
53
1
106
70-130
04/11/2023 2138
cis- 1,3-Dichloropropene
50
53
1
107
70-130
04/11/2023 2138
trans- 1,3-Dichloropropene
50
53
1
106
70-130
04/11/2023 2138
Ethylbenzene
50
53
1
105
70-130
04/11/2023 2138
2-Hexanone
100
100
1
103
70-130
04/11/2023 2138
Methyl iodide (lodomethane)
50
51
1
102
70-130
04/11/2023 2138
4-Methyl-2-pentanone
100
110
1
108
70-130
04/11/2023 2138
Methylene chloride
50
57
1
115
70-130
04/11/2023 2138
Styrene
50
54
1
107
70-130
04/11/2023 2138
1,1,1,2-Tetrachloroethane
50
49
1
99
70-130
04/11/2023 2138
1,1,2,2-Tetrachloroethane
50
54
1
108
70-130
04/11/2023 2138
Tetrachloroethene
50
49
1
97
70-130
04/11/2023 2138
Toluene
50
54
1
108
70-130
04/11/2023 2138
1,1,1-Trichloroethane
50
55
1
109
70-130
04/11/2023 2138
1,1,2-Trichloroethane
50
50
1
99
70-130
04/11/2023 2138
Trichloroethene
50
49
1
98
70-130
04/11/2023 2138
Trichlorofluoromethane
50
56
1
112
70-130
04/11/2023 2138
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 217 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72381-002
Matrix: Aqueous
Batch:72381
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
59
1 119
70-130
04/11/2023 2138
Vinyl acetate
50
55
1 111
60-140
04/11/2023 2138
Vinyl chloride
50
67 N
1 134
70-130
04/11/2023 2138
Xylenes (total)
100
100
1 104
70-130
04/11/2023 2138
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 94 70-130
1,2-Dichloroethane-d4 99 70-130
Toluene-d8 99 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 218 of 257

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: YQ72429-001 Matrix: Aqueous
Batch:72429 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 04/12/20231003
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
90 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 219 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: YQ72429-002 Matrix: Aqueous
Batch:72429 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 52 1 104 70-130 04/12/2023 0901
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
94 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 220 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72496-001 Matrix: Aqueous
Batch: 72496 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
04/12/2023 1147
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
04/12/2023 1147
Benzene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Bromoform
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
04/12/2023 1147
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Chloroethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Chloroform
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
04/12/2023 1147
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
04/12/2023 1147
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
04/12/2023 1147
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
04/12/2023 1147
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/12/2023 1147
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
04/12/2023 1147
Dichlorodifluoromethane
0.50
u
1
0.50
0.40
ug/L
04/12/2023 1147
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
04/12/2023 1147
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
2-Hexanone
10
U
1
10
2.0
ug/L
04/12/2023 1147
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
04/12/2023 1147
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
04/12/2023 1147
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Styrene
0.50
U
1
0.50
0.41
ug/L
04/12/2023 1147
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Toluene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 221 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ72496-001 Matrix: Aqueous
Batch:72496 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
04/12/2023 1147
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
04/12/2023 1147
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
04/12/2023 1147
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 108 70-130
1,2-Dichloroethane-d4 119 70-130
Toluene-d8 96 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 222 of 257

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72496-002
Matrix: Aqueous
Batch: 72496
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q
Dil
% Rec
Limit
Analysis Date
Acetone
100
300
N
1
300
60-140
04/12/2023 1009
Acrylonitrile
100
180
N
1
177
70-130
04/12/2023 1009
Benzene
50
52
1
105
70-130
04/12/2023 1009
Bromochloromethane
50
50
1
99
70-130
04/12/2023 1009
Bromodichloromethane
50
52
1
105
70-130
04/12/2023 1009
Bromoform
50
46
1
93
70-130
04/12/2023 1009
Bromomethane (Methyl bromide)
50
44
1
88
70-130
04/12/2023 1009
2-Butanone (MEK)
100
160
N
1
158
70-130
04/12/2023 1009
Carbon disulfide
50
65
1
130
70-130
04/12/2023 1009
Carbon tetrachloride
50
51
1
103
70-130
04/12/2023 1009
Chlorobenzene
50
50
1
101
70-130
04/12/2023 1009
Chloroethane
50
55
1
110
70-130
04/12/2023 1009
Chloroform
50
55
1
110
70-130
04/12/2023 1009
Chloromethane (Methyl chloride)
50
56
1
113
60-140
04/12/2023 1009
1,2-Dibromo-3-chloropropane (DBCP)
50
58
1
116
70-130
04/12/2023 1009
Dibromochloromethane
50
53
1
106
70-130
04/12/2023 1009
1,2-Dibromoethane (EDB)
50
53
1
107
70-130
04/12/2023 1009
Dibromomethane (Methylene bromide)
50
56
1
112
70-130
04/12/2023 1009
trans- 1,4-Dichloro-2-butene
50
54
1
109
70-130
04/12/2023 1009
1,2-Dichlorobenzene
50
51
1
101
70-130
04/12/2023 1009
1,4-Dichlorobenzene
50
51
1
102
70-130
04/12/2023 1009
Dichlorodifluoromethane
50
46
1
93
60-140
04/12/2023 1009
1,1-Dichloroethane
50
53
1
106
70-130
04/12/2023 1009
1,2-Dichloroethane
50
58
1
116
70-130
04/12/2023 1009
1,1-Dichloroethene
50
56
1
112
70-130
04/12/2023 1009
cis- 1,2-Dichloroethene
50
50
1
100
70-130
04/12/2023 1009
trans- 1,2-Dichloroethene
50
50
1
100
70-130
04/12/2023 1009
1,2-Dichloropropane
50
54
1
109
70-130
04/12/2023 1009
cis- 1,3-Dichloropropene
50
54
1
107
70-130
04/12/2023 1009
trans- 1,3-Dichloropropene
50
55
1
109
70-130
04/12/2023 1009
Ethylbenzene
50
52
1
103
70-130
04/12/2023 1009
2-Hexanone
100
100
1
102
70-130
04/12/2023 1009
Methyl iodide (lodomethane)
50
57
1
113
70-130
04/12/2023 1009
4-Methyl-2-pentanone
100
130
1
127
70-130
04/12/2023 1009
Methylene chloride
50
67
N
1
134
70-130
04/12/2023 1009
Styrene
50
51
1
102
70-130
04/12/2023 1009
1,1,1,2-Tetrachloroethane
50
54
1
107
70-130
04/12/2023 1009
1,1,2,2-Tetrachloroethane
50
59
1
117
70-130
04/12/2023 1009
Tetrachloroethene
50
49
1
98
70-130
04/12/2023 1009
Toluene
50
53
1
106
70-130
04/12/2023 1009
1,1,1-Trichloroethane
50
52
1
105
70-130
04/12/2023 1009
1,1,2-Trichloroethane
50
52
1
104
70-130
04/12/2023 1009
Trichloroethene
50
47
1
95
70-130
04/12/2023 1009
Trichlorofluoromethane
50
50
1
100
70-130
04/12/2023 1009
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 223 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72496-002
Matrix: Aqueous
Batch:72496
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
58
1 115
70-130
04/12/2023 1009
Vinyl acetate
50
59
1 118
60-140
04/12/2023 1009
Vinyl chloride
50
54
1 107
70-130
04/12/2023 1009
Xylenes (total)
100
100
1 103
70-130
04/12/2023 1009
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 97 70-130
1,2-Dichloroethane-d4 113 70-130
Toluene-d8 93 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 224 of 257

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: YQ72586-001 Matrix: Aqueous
Batch:72586 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 04/13/20231049
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
96 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 225 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: YQ72586-002 Matrix: Aqueous
Batch:72586 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 53 1 106 70-130 04/13/2023 0930
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
101 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 226 of 257
QC Data for Lot Number: YD05007

Volatile Organic Compounds by GC/MS - MB
Sample ID: YQ73259-001 Matrix: Aqueous
Batch:73259 Prep Method: 5030E
Analytical Method: 8260D
Parameter Result Q Dil LOQ DL Units Analysis Date
Methylene chloride 0.50 U 1 0.50 0.40 ug/L 04/21/2023 0000
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 94 70-130
1,2-Dichloroethane-d4 103 70-130
Toluene-d8 98 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 227 of 257

Volatile Organic Compounds by GC/MS - LCS
Sample ID: YQ73259-002
Matrix: Aqueous
Batch:73259
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
Methylene chloride
50
44
1 88 70-130 04/20/2023 2202
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 88 70-130
1,2-Dichloroethane-d4 83 70-130
Toluene-d8 89 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 228 of 257

Semivolatile Organic Compounds by GC/MS - MB
Sample ID: YQ72208-001 Matrix: Aqueous
Batch:72208 Prep Method: 3520C
Analytical Method: 8270E Prep Date: 04/10/2023 1000
Parameter Result Q Dil LOQ DL Units Analysis Date
bis(2-Ethy1hexy1)phtha1ate 4.0 U 1 4.0 1.5 ug/L 04/11/20231158
Acceptance
Surrogate Q % Rec Limit
2-Fluorobiphenyl
76
37-129
2-Fluorophenol
45
24-127
Nitrobenzene-d5
82
38-127
Phenol-d5
53
28-128
TerphenyIA14
93
10-148
2,4,6-Tribromophenol
69
35-144
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 229 of 257

Semivolatile Organic Compounds by GC/MS - LCS
Sample ID: YQ72208-002
Matrix: Aqueous
Batch:72208
Prep Method: 3520C
Analytical Method: 8270E
Prep Date: 04/10/2023 1000
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
bis(2-Ethy1hexy1)phtha1ate
40
40
1 100 30-130 04/11/20231223
Surrogate
Q % Rec
Acceptance
Limit
2-Fluorobiphenyl
79
37-129
2-Fluorophenol
80
24-127
Nitrobenzene-d5
94
38-127
Phenol-d5
86
28-128
TerphenyIA14
89
10-148
2,4,6-Tribromophenol
76
35-144
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05007
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 230 of 257

Dissolved Gases - MB
Sample ID: YQ72481-001 Matrix: Aqueous
Batch:72481
Analytical Method: RSK - 175
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Ethane
10
U
1
10
2.5
ug/L
04/11/20231056
Ethene
10
U
1
10
2.5
ug/L
04/11/20231056
Methane
3.2
J
1
10
2.5
ug/L
04/11/20231056
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 231 of 257
QC Data for Lot Number: YD05007

Dissolved Gases - LCS
Sample ID: YQ72481-002
Matrix: Aqueous
Batch:72481
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Ethane
550
580
1 105
70-130
04/11/2023 0943
Ethene
520
530
1 102
70-130
04/11/2023 0943
Methane
300
280
1 96
70-130
04/11/2023 0943
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 232 of 257
QC Data for Lot Number: YD05007

Dissolved Gases - LCSD
Sample ID: YQ72481-003
Matrix: Aqueous
Batch:72481
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L) Q
Dil % Rec % RPD
Limit
Limit
Analysis Date
Ethane
550
590
1 107 2.0
70-130
30
04/11/20231040
Ethene
520
540
1 104 2.0
70-130
30
04/11/20231040
Methane
300
290
1 98 1.8
70-130
30
04/11/20231040
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 233 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - MB
Sample ID: YQ72256-001 Matrix: Aqueous
Batch: 72256 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 04/10/2023 1837
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
04/12/20231556
Arsenic
2.0
U
1
2.0
1.3
ug/L
04/12/20231556
Barium
5.0
U
1
5.0
1.3
ug/L
04/12/20231556
Beryllium
0.40
U
1
0.40
0.15
ug/L
04/12/20231556
Cadmium
0.50
U
1
0.50
0.13
ug/L
04/12/20231556
Chromium
5.0
U
1
5.0
1.3
ug/L
04/12/20231556
Cobalt
5.0
U
1
5.0
1.3
ug/L
04/12/20231556
Copper
5.0
U
1
5.0
1.3
ug/L
04/12/20231556
Iron
50
U
1
50
13
ug/L
04/12/20231556
Lead
1.0
U
1
1.0
0.25
ug/L
04/12/20231556
Nickel
5.0
U
1
5.0
1.3
ug/L
04/12/20231556
Selenium
5.0
U
1
5.0
1.3
ug/L
04/12/20231556
Silver
1.0
U
1
1.0
0.25
ug/L
04/12/20231556
Sodium
400
U
1
400
150
ug/L
04/12/20231556
Thallium
0.50
U
1
0.50
0.15
ug/L
04/12/20231556
Vanadium
5.0
U
1
5.0
2.5
ug/L
04/12/20231556
Zinc
10
U
1
10
2.5
ug/L
04/12/20231556
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 234 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - LCS
Sample ID: YQ72256-002
Matrix: Aqueous
Batch: 72256
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
04/10/2023 1837
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
96
1
96
80-120
04/12/20231608
Arsenic
100
95
1
95
80-120
04/12/20231608
Barium
100
99
1
99
80-120
04/12/20231608
Beryllium
100
92
1
92
80-120
04/12/20231608
Cadmium
100
93
1
93
80-120
04/12/20231608
Chromium
100
100
1
101
80-120
04/12/20231608
Cobalt
100
99
1
99
80-120
04/12/20231608
Copper
100
110
1
106
80-120
04/12/20231608
Iron
1000
1000
1
103
80-120
04/12/20231608
Lead
100
100
1
104
80-120
04/12/20231608
Nickel
100
98
1
98
80-120
04/12/20231608
Selenium
100
87
1
87
80-120
04/12/20231608
Silver
100
100
1
102
80-120
04/12/20231608
Sodium
1000
960
1
96
80-120
04/12/20231608
Thallium
100
100
1
103
80-120
04/12/20231608
Vanadium
100
99
1
99
80-120
04/12/20231608
Zinc
100
95
1
95
80-120
04/12/20231608
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 235 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - MS
Sample ID: YD05007-003MS
Matrix: Aqueous
Batch: 72256
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 04/10/2023 1837
Sample
Spike
Amount
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
94
1
94
75-125
04/12/20231750
Arsenic
0.0
100
87
1
87
75-125
04/12/20231750
Barium
100
100
200
1
97
75-125
04/12/20231750
Beryllium
0.34
100
95
1
94
75-125
04/12/20231750
Cadmium
0.0
100
95
1
95
75-125
04/12/20231750
Chromium
5.3
100
100
1
98
75-125
04/12/20231750
Cobalt
1.7
100
85
1
84
75-125
04/12/2023 1750
Copper
3.0
100
100
1
97
75-125
04/12/20231750
Iron
1600
1000
3300
N 1
174
75-125
04/12/20231750
Lead
0.51
100
99
1
98
75-125
04/12/20231750
Nickel
2.9
100
86
1
83
75-125
04/12/20231750
Selenium
0.0
100
84
1
84
75-125
04/12/20231750
Silver
0.0
100
95
1
95
75-125
04/12/20231750
Sodium
9100
1000
10000
1
97
75-125
04/12/20231750
Thallium
0.0
100
98
1
98
75-125
04/12/20231750
Vanadium
3.9
100
100
1
97
75-125
04/12/20231750
Zinc
13
100
100
1
91
75-125
04/12/20231750
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 236 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - MSD
Sample ID: YD05007-003MD
Matrix: Aqueous
Batch: 72256
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
04/10/2023 1837
Sample
Spike
Amount
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec % RPD
Limit
Limit
Analysis Date
Antimony
0.0
100
93
1
93
1.9
75-125
20
04/12/20231802
Arsenic
0.0
100
86
1
86
1.3
75-125
20
04/12/20231802
Barium
100
100
200
1
94
1.5
75-125
20
04/12/20231802
Beryllium
0.34
100
93
1
93
1.7
75-125
20
04/12/20231802
Cadmium
0.0
100
93
1
93
1.3
75-125
20
04/12/20231802
Chromium
5.3
100
100
1
95
3.0
75-125
20
04/12/20231802
Cobalt
1.7
100
85
1
83
0.72
75-125
20
04/12/2023 1802
Copper
3.0
100
97
1
94
2.6
75-125
20
04/12/20231802
Iron
1600
1000
3200
N 1
159
4.5
75-125
20
04/12/20231802
Lead
0.51
100
97
1
96
2.0
75-125
20
04/12/20231802
Nickel
2.9
100
85
1
82
0.85
75-125
20
04/12/20231802
Selenium
0.0
100
82
1
82
1.9
75-125
20
04/12/20231802
Silver
0.0
100
93
1
93
3.0
75-125
20
04/12/20231802
Sodium
9100
1000
9900
1
80
1.7
75-125
20
04/12/20231802
Thallium
0.0
100
96
1
96
2.1
75-125
20
04/12/20231802
Vanadium
3.9
100
98
1
94
2.5
75-125
20
04/12/20231802
Zinc
13
100
100
1
89
2.1
75-125
20
04/12/20231802
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 237 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - MB
Sample ID: YQ72257-001 Matrix: Aqueous
Batch: 72257 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 04/10/2023 1837
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
04/12/2023 2139
Arsenic
2.0
U
1
2.0
1.3
ug/L
04/12/2023 2139
Barium
5.0
U
1
5.0
1.3
ug/L
04/12/2023 2139
Beryllium
0.40
U
1
0.40
0.15
ug/L
04/12/2023 2139
Cadmium
0.50
U
1
0.50
0.13
ug/L
04/12/2023 2139
Chromium
5.0
U
1
5.0
1.3
ug/L
04/12/2023 2139
Cobalt
5.0
U
1
5.0
1.3
ug/L
04/12/2023 2139
Copper
5.0
U
1
5.0
1.3
ug/L
04/12/2023 2139
Lead
1.0
U
1
1.0
0.25
ug/L
04/12/2023 2139
Nickel
5.0
U
1
5.0
1.3
ug/L
04/12/2023 2139
Selenium
5.0
U
1
5.0
1.3
ug/L
04/12/2023 2139
Silver
1.0
U
1
1.0
0.25
ug/L
04/12/2023 2139
Thallium
0.50
U
1
0.50
0.15
ug/L
04/12/2023 2139
Vanadium
5.0
U
1
5.0
2.5
ug/L
04/12/2023 2139
Zinc
10
U
1
10
2.5
ug/L
04/12/2023 2139
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 238 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - LCS
Sample ID: YQ72257-002
Matrix: Aqueous
Batch: 72257
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
04/10/2023 1837
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
95
1
95
80-120
04/12/2023 2236
Arsenic
100
96
1
96
80-120
04/12/2023 2236
Barium
100
96
1
96
80-120
04/12/2023 2236
Beryllium
100
90
1
90
80-120
04/12/2023 2236
Cadmium
100
94
1
94
80-120
04/12/2023 2236
Chromium
100
100
1
102
80-120
04/12/2023 2236
Cobalt
100
100
1
104
80-120
04/12/2023 2236
Copper
100
110
1
107
80-120
04/12/2023 2236
Lead
100
100
1
100
80-120
04/12/2023 2236
Nickel
100
100
1
102
80-120
04/12/2023 2236
Selenium
100
85
1
85
80-120
04/12/2023 2236
Silver
100
100
1
103
80-120
04/12/2023 2236
Thallium
100
99
1
99
80-120
04/12/2023 2236
Vanadium
100
98
1
98
80-120
04/12/2023 2236
Zinc
100
94
1
94
80-120
04/12/2023 2236
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 239 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - MS
Sample ID: YD05007-025MS
Matrix: Aqueous
Batch: 72257
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 04/10/2023 1837
Sample
Spike
Amount
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
99
1
99
75-125
04/13/2023 0104
Arsenic
0.0
100
100
1
101
75-125
04/13/2023 0104
Barium
16
100
110
1
98
75-125
04/13/2023 0104
Beryllium
0.0
100
96
1
96
75-125
04/13/2023 0104
Cadmium
0.0
100
98
1
98
75-125
04/13/2023 0104
Chromium
3.1
100
110
1
104
75-125
04/13/2023 0104
Cobalt
0.0
100
100
1
102
75-125
04/13/2023 0104
Copper
0.0
100
110
1
108
75-125
04/13/2023 0104
Lead
0.0
100
100
1
102
75-125
04/13/2023 0104
Nickel
0.0
100
100
1
101
75-125
04/13/2023 0104
Selenium
0.0
100
94
1
94
75-125
04/13/2023 0104
Silver
0.0
100
100
1
101
75-125
04/13/2023 0104
Thallium
0.0
100
100
1
103
75-125
04/13/2023 0104
Vanadium
4.0
100
100
1
101
75-125
04/13/2023 0104
Zinc
0.0
100
100
1
102
75-125
04/13/2023 0104
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 240 of 257
QC Data for Lot Number: YD05007

ICP-MS Metals - MSD
Sample ID: YD05007-025MD
Matrix: Aqueous
Batch: 72257
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
04/10/2023 1837
Sample
Spike
Amount
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec % RPD
Limit
Limit
Analysis Date
Antimony
0.0
100
97
1
97
1.2
75-125
20
04/13/2023 0116
Arsenic
0.0
100
100
1
100
0.76
75-125
20
04/13/2023 0116
Barium
16
100
110
1
97
1.3
75-125
20
04/13/2023 0116
Beryllium
0.0
100
95
1
95
1.1
75-125
20
04/13/2023 0116
Cadmium
0.0
100
98
1
98
0.0066
75-125
20
04/13/2023 0116
Chromium
3.1
100
110
1
104
0.36
75-125
20
04/13/2023 0116
Cobalt
0.0
100
100
1
101
0.51
75-125
20
04/13/2023 0116
Copper
0.0
100
110
1
107
0.93
75-125
20
04/13/2023 0116
Lead
0.0
100
100
1
100
2.0
75-125
20
04/13/2023 0116
Nickel
0.0
100
100
1
101
0.25
75-125
20
04/13/2023 0116
Selenium
0.0
100
94
1
94
0.29
75-125
20
04/13/2023 0116
Silver
0.0
100
100
1
100
1.5
75-125
20
04/13/2023 0116
Thallium
0.0
100
100
1
101
1.6
75-125
20
04/13/2023 0116
Vanadium
4.0
100
100
1
100
0.40
75-125
20
04/13/2023 0116
Zinc
0.0
100
100
1
101
1.0
75-125
20
04/13/2023 0116
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 241 of 257
QC Data for Lot Number: YD05007

CVAA -MB
Sample ID: YQ72166-001 Matrix: Aqueous
Batch: 72166 Prep Method:
Analytical Method: 7470A Prep Date: 04/12/2023 1239
Parameter Result Q Dil LOQ DL Units Analysis Date
Mercury 0.00020 U 1 0.00020 0.000091 mg/L 04/27/20231512
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 242 of 257
QC Data for Lot Number: YD05007

CVAA - LCS
Sample ID: YQ72166-002 Matrix: Aqueous
Batch: 72166 Prep Method:
Analytical Method: 7470A Prep Date: 04/12/2023 1239
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.0020 0.0022 1 108 80-120 04/27/20231514
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 243 of 257
QC Data for Lot Number: YD05007

CVAA - MS
Sample ID: YD05007-01OMS Matrix: Aqueous
Batch: 72166 Prep Method:
Analytical Method: 7470A Prep Date: 04/12/2023 1239
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.0 0.0020 0.0021 1 106 80-120 04/27/20231555
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 244 of 257
QC Data for Lot Number: YD05007

CVAA - MSD
Sample ID: YD05007-01OMD Matrix: Aqueous
Batch: 72166 Prep Method:
Analytical Method: 7470A Prep Date: 04/12/2023 1239
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Mercury 0.0 0.0020 0.0021 1 105 1.2 80-120 20 04/27/20231557
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 245 of 257
QC Data for Lot Number: YD05007

CVAA -MB
Sample ID: YQ73236-001 Matrix: Aqueous
Batch:73236 Prep Method:
Analytical Method: 7470A Prep Date: 04/24/2023 1021
Parameter Result Q Dil LOQ DL Units Analysis Date
Mercury 0.00020 U 1 0.00020 0.000091 mg/L 04/27/20231423
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 246 of 257
QC Data for Lot Number: YD05007

CVAA - LCS
Sample ID: YQ73236-002 Matrix: Aqueous
Batch:73236 Prep Method:
Analytical Method: 7470A Prep Date: 04/24/2023 1021
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.0020 0.0019 1 96 80-120 04/27/20231426
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 247 of 257
QC Data for Lot Number: YD05007

CVAA - MS
Sample ID: YD05007-026MS Matrix: Aqueous
Batch:73236 Prep Method:
Analytical Method: 7470A Prep Date: 04/24/2023 1021
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.0 0.0020 0.0020 1 98 80-120 04/27/20231450
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 248 of 257
QC Data for Lot Number: YD05007

CVAA - MSD
Sample ID: YD05007-026MD Matrix: Aqueous
Batch:73236 Prep Method:
Analytical Method: 7470A Prep Date: 04/24/2023 1021
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Mercury 0.0 0.0020 0.0019 1 94 4.0 80-120 20 04/27/20231453
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 249 of 257
QC Data for Lot Number: YD05007

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 250 of 257

PACE ANALYTICAL SERVICES, LLC
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Page 252 of 257

PACE ANALYTICAL SERVICES, LLC
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 253 of 257

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Page 254 of 257

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Page 256 of 257

PACE ANALYTICAL SERVICES, LLC
I?C#_iide: FNV FRM WOOL•U286vt12_SamplesReceipt Ciiecoistisr;q
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 257 of 257

(� aceAna/ytical
Deliver To
Cathy Dover
Pace
LELAP Certificate Number: 01955
A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01
ANALYTICAL RESULTS
•:I
Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]
Report Date 05/01/2023
Report Y 223041439
�1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III
Project North Wake YD05007
Samples Collected 4/4/23 - 4/5/23
106 Vantage Point Drive
West Columbia, SC 29172
[phone]
Additional Recipients
NONE
ACCREDITED
CERT # 6429.01
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 1 of 16

Report#: 223041439
ace k k+ytUh
Project ID: North Wake YD05007 Report Date: 05/O1/2023
Laboratory Endorsement
Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.
Common Abbreviations that may be Utilized in this Report
ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub -Contracted
FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re -analysis
CF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM
Reporting Flags that may be Utilized in this Report
J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non -compliant QC Result (See Q Flag Application Report)
" Indicates a non -compliant or not applicable QC recovery or RPD — see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk -based limit.
P RPD between primary and confirmation result is greater than 40
DL Diluted analysis — when appended to Client Sample ID
Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.
This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results
contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.
I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this
hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.
Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.
�� Y�29a
Authorized Signature
Pace Gulf Coast Report 223041439
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 2 of 16

PaceA;U44Uh'
Report#: 223041439
Project ID: North Wake YD05007
Certifications
Report Date: 05/01/2023
Certification
Certification Number
A2LA Accredited DoD ELAP-QSM 5.4
6429.01
Alabama
01955
Arkansas
88-0655
Colorado
01955
Delaware
01955
Florida
E87854
Georgia
01955
Hawaii
01955
Idaho
01955
Illinois
200048
Indiana
01955
Kansas
E-10354
Kentucky
95
Louisiana
01955
Maryland
01955
Massachusetts
01955
Michigan
01955
Mississippi
01955
Missouri
01955
Montana
N/A
Nebraska
01955
New Mexico
01955
North Carolina
618
North Dakota
R-195
Oklahoma
9403
South Carolina
73006001
South Dakota
01955
Tennessee
01955
Texas
T104704178
Vermont
01955
Virginia
460215
Washington
C929
USDA Soil Permit
P330-16-00234
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 3 of 16

Report#: 223041439
ace k k+ytUh
Project ID: North Wake YD05007 Report Date: 05/01/2023
Case Narrative
Client: Pace Analytical Services South Carolina Report: 223041439
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
No anomalies were found for the analyzed sample(s).
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 4 of 16

ace k k+ytUh
Report#: 223041439
Project ID: North Wake YD05007
Report Date:
05/01/2023
Sample Summary
Lab ID
Client ID
Matrix
Collect Date
Receive Date
22304143901
MW-9
Water
4/04/23 12:10
4/14/23 09:39
22304143902
MW-36
Water
4/04/23 12:45
4/14/23 09:39
22304143903
MW-34
Water
4/04/23 14:20
4/14/23 09:39
22304143904
MW-34d
Water
4/04/23 15:00
4/14/23 09:39
22304143905
MW-5R
Water
4/04/23 15:40
4/14/23 09:39
22304143906
MW-10
Water
4/05/23 09:15
4/14/23 09:39
22304143907
MW-6
Water
4/05/23 11:10
4/14/23 09:39
22304143908
MW-8
Water
4/05/23 12:42
4/14/23 09:39
22304143909
MW-11
Water
4/05/23 16:45
4/14/23 09:39
22304143910
MW-5R
Bubble Strip
4/05/23 11:52
4/14/23 09:39
22304143911
MW-6
Bubble Strip
4/05/23 11:28
4/14/23 09:39
22304143912
MW-8
Bubble Strip
4/05/23 12:42
4/14/23 09:39
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 5 of 16

k
Report#: 223041439
ace k+ytUh
Project ID: North Wake YD05007
Report Date:
05/01/2023
Detect Summary
Results and Detection Limits
are adjusted for dilution and moisture when applicable
AM23G
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22304143901
MW-9
Acetic Acid
mg/L
1.6J
10
NA
22304143901
MW-9
Formic Acid
mg/L
54
10
NA
22304143902
MW-36
Acetic Acid
mg/L
0.42J
1
NA
22304143902
MW-36
Formic Acid
mg/L
6.5
1
NA
22304143902
MW-36
Hexanoic Acid
mg/L
0.064J
1
NA
22304143902
MW-36
Lactic Acid
mg/L
0.18J
1
NA
22304143903
MW-34
Acetic Acid
mg/L
0.43J
1
NA
22304143903
MW-34
Formic Acid
mg/L
6.3
1
NA
22304143904
MW-34d
Acetic Acid
mg/L
0.40J
1
NA
22304143904
MW-34d
Formic Acid
mg/L
6.1
1
NA
22304143905
MW-5R
Acetic Acid
mg/L
0.73
1
NA
22304143905
MW-5R
Formic Acid
mg/L
6.5
1
NA
22304143905
MW-5R
Hexanoic Acid
mg/L
0.071J
1
NA
22304143906
MW-10
Acetic Acid
mg/L
0.47J
1
NA
22304143906
MW-10
Formic Acid
mg/L
6.5
1
NA
22304143906
MW-10
Hexanoic Acid
mg/L
0.22J
1
NA
22304143906
MW-10
Propionic Acid
mg/L
0.064J
1
NA
22304143907
MW-6
Acetic Acid
mg/L
2.OJ
10
NA
22304143907
MW-6
Formic Acid
mg/L
61
10
NA
22304143907
MW-6
Hexanoic Acid
mg/L
0.75J
10
NA
22304143908
MW-8
Acetic Acid
mg/L
1.7J
10
NA
22304143908
MW-8
Formic Acid
mg/L
51
10
NA
22304143909
MW-11
Acetic Acid
mg/L
0.46J
1
NA
22304143909
MW-11
Formic Acid
mg/L
6.7
1
NA
22304143909
MW-11
Hexanoic Acid
mg/L
0.062J
1
NA
22304143909
MW-11
Propionic Acid
mg/L
0.059J
1
NA
AM20GAX
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22304143910
MW-5R
Hydrogen
nM
3.4
1
NA
22304143911
MW-6
Hydrogen
nM
3.2
1
NA
22304143912
MW-8
Hydrogen
nM
2.4
1
NA
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 6 of 16

Report#: 223041439
Project ID: North Wake YD05007 Report Date: 05/O1/2023
Sample Results
MW-9 Collect Date 04/04/2023 12:10 Lab ID 22304143901
Receive Date 04/14/2023 09:39 Matrix Water
AM23G "Results and limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 04/29/2310:23 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
1.6J
1.2
5.0
mg/L
107-92-6
Butyric Acid
0.58U
0.58
5.0
mg/L
64-18-6
Formic Acid
54
0.55
5.0
mg/L
142-62-1
Hexanoic Acid
0.58U
0.58
5.0
mg/L
646-07-1
i-Hexanoic Acid
0.56U
0.56
5.0
mg/L
503-74-2
i-Pentanoic Acid
0.61 U
0.61
5.0
mg/L
50-21-5
Lactic Acid
0.53U
0.53
5.0
mg/L
109-52-4
Pentanoic Acid
0.56U
0.56
5.0
mg/L
79-09-4
Propionic Acid
0.53U
0.53
5.0
mg/L
127-17-3
Pyruvic Acid
0.60U
0.60
5.0
mg/L
MW-36 Collect Date 04/04/2023 12:45 Lab ID 22304143902
Receive Date 04/14/2023 09:39 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2311:15 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.42J
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
6.5
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.064J
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.181
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 04/04/2023 14:20 Lab ID 22304143903
MW�34 Receive Date 04/14/2023 09:39 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2312:06 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.43J
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
6.3
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.058U
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 7 of 16

..-] Report#: 223041439
Project ID: North Wake YD05007 Report Date: 05/O1/2023
Sample Results
MW-34 Collect Date 04/04/2023 14:20 Lab ID 22304143903
Receive Date 04/14/2023 09:39 Matrix Water
G (Continued)
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2312:06 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.053U
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
MW-34d Collect Date 04/04/2023 15:00 Lab ID 22304143904
Receive Date 04/14/2023 09:39 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2312:58 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.40J
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
6.1
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.058U
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.053U
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
G Collect Date 04/04/2023 15:40 Lab ID 22304143905
MW-5fZ Receive Date 04/14/2023 09:39 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2313:49 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.73
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
6.5
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.071J
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.053U
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 8 of 16

--] Report#: 223041439
Project ID: North Wake YD05007 Report Date: 05/O1/2023
Sample Results
MW-5R Collect Date 04/04/2023 15:40 Lab ID 22304143905
Receive Date 04/14/2023 09:39 Matrix Water
AM23G (Continued)
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2313:49 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
MW-1 O Collect Date 04/05/2023 09:15 Lab ID 22304143906
Receive Date 04/14/2023 09:39 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2314:41 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.47J
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
6.5
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.22J
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.053U
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.064J
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 04/05/2023 11:10 Lab ID 22304143907
MW-6 Receive Date 04/14/2023 09:39 Matrix Water
AM23G *Results and limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 04/29/2315:32 764777 LHM NA
CAS#
Parameter
64-19-7
Acetic Acid
107-92-6
Butyric Acid
64-18-6
Formic Acid
142-62-1
Hexanoic Acid
646-07-1
i-Hexanoic Acid
503-74-2
i-Pentanoic Acid
50-21-5
Lactic Acid
109-52-4
Pentanoic Acid
79-09-4
Propionic Acid
127-17-3
Pyruvic Acid
Result
DL
LOQ
Units
2.0,1
1.2
5.0
mg/L
0.58U
0.58
5.0
mg/L
61
0.55
5.0
mg/L
0.75J
0.58
5.0
mg/L
0.56U
0.56
5.0
mg/L
0.61 U
0.61
5.0
mg/L
0.53U
0.53
5.0
mg/L
0.56U
0.56
5.0
mg/L
0.53U
0.53
5.0
mg/L
0.60U
0.60
5.0
mg/L
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 9 of 16

Report#: 223041439
Project ID: North Wake YD05007 Report Date: 05/O1/2023
Sample Results
MW-8 Collect Date 04/05/2023 12:42 Lab ID 22304143908
Receive Date 04/14/2023 09:39 Matrix Water
AM23G "Results and limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 04/29/2316:24 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
1.7J
1.2
5.0
mg/L
107-92-6
Butyric Acid
0.58U
0.58
5.0
mg/L
64-18-6
Formic Acid
51
0.55
5.0
mg/L
142-62-1
Hexanoic Acid
0.58U
0.58
5.0
mg/L
646-07-1
i-Hexanoic Acid
0.56U
0.56
5.0
mg/L
503-74-2
i-Pentanoic Acid
0.61 U
0.61
5.0
mg/L
50-21-5
Lactic Acid
0.53U
0.53
5.0
mg/L
109-52-4
Pentanoic Acid
0.56U
0.56
5.0
mg/L
79-09-4
Propionic Acid
0.53U
0.53
5.0
mg/L
127-17-3
Pyruvic Acid
0.60U
0.60
5.0
mg/L
MW-1 1 Collect Date 04/05/2023 16:45 Lab ID 22304143909
Receive Date 04/14/2023 09:39 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/29/2317:15 764777 LHM NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.46J
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
6.7
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.062J
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.053U
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.059J
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 04/05/2023 11:52 Lab ID 22304143910
MW�GR Receive Date 04/14/2023 09:39 Matrix Bubble Strip
GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/18/23 08:21 764048 LMB NA
CAS# Parameter
1333-74-0 Hydrogen
Result
DL
LOQ
Units
3.4
0.49
1.9
nM
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 10 of 16

Report#: 223041439
Project ID: North Wake YD05007 Report Date: 05/01/2023
Sample Results
MW-c Collect Date 04/05/2023 11:28 Lab ID 22304143911
v Receive Date 04/14/2023 09:39 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/18/23 08:33 764048 LMB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
3.2
0.49
1.9
nM
MW-Q Collect Date 04/05/2023 12:42 Lab ID 22304143912
v Receive Date 04/14/2023 09:39 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 04/18/23 08:46 764048 LMB NA
CAS# Parameter
1333-74-0 Hydrogen
Result
DL
LOQ
Units
2.4
0.49
1.9
nM
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 11 of 16

Report#: 223041439
Project ID: North Wake YD05007
General Chemistry QC Summary
Report Date: 05/01/2023
Analytical Batch Client ID
MB764777
LCS764777
LCSD764777
764777 Lab ID
2478030
2478031
2478032
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
04/29/23 07:48
04/29/23 08:40
04/29/23 09:32
Matrix
Water
Water
Water
AM23G
Units
mg/L
Spike
Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Acetic Acid
64-19-7
0.12U
0.12
2.0
2.0
100
70 - 130
2.0
2.1
103
3
20
Butyric Acid
107-92-6
0.058U
0.058
2.0
2.0
99
70 - 130
2.0
2.0
102
3
20
Formic Acid
64-18-6
0.055U
0.055
2.0
1.9
94
70 - 130
2.0
1.9
97
3
20
Hexanoic Acid
142-62-1
0.058U
0.058
2.0
1.9
94
70 - 130
2.0
2.1
104
11
20
i-Hexanoic Acid
646-07-1
0.056U
0.056
2.0
1.9
97
70 - 130
2.0
1.8
91
6
20
i-Pentanoic Acid
503-74-2
0.061 U
0.061
2.0
2.0
98
70 - 130
2.0
2.0
98
1
20
Lactic Acid
50-21-5
0.053U
0.053
2.0
2.1
104
70 - 130
2.0
2.1
107
3
20
Pentanoic Acid
109-52-4
0.056U
0.056
2.0
2.0
101
70 - 130
2.0
2.0
102
1
20
Propionic Acid
79-09-4
0.053U
0.053
2.0
2.0
100
70 - 130
2.0
2.0
102
2
20
Pyruvic Acid
127-17-3
0.060U
0.060
2.0
1.9
97
70 - 130
2.0
2.0
100
3
20
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 12 of 16

Report#: 223041439
Project ID: North Wake YD05007
General Chromatography QC Summary
Report Date: 05/01/2023
Analytical Batch Client ID
MB764048
LCS764048
LCSD764048
764048 Lab ID
2473551
2473552
2473553
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
04/18/23 08:09
04/18/23 07:41
04/18/23 07:53
Matrix
Bubble Strip
Bubble Strip
Bubble Strip
AM20GAX
Units
nM
Spike
Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Hydrogen 1333-74-0
0.49U
1 0.491
121
101
88
1 70 - 130
1 121
11
190
1 2
1 20
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 13 of 16

Client ID: Shealy Enwrr - Pare Analytical Services South Carolina I)
SDG: 223041439
Pace Analytical Services, a_LC.
aeeAnalylcal Chain of custody 106 Vantage Point Drive PM' RWe
Record West Columbia, South Carolina 29172
Telephone No. [phone] Fax No. [phone]
www. acelabs.com
Cflanl Report to Contact Telephone Ne.I E-mail Quote No.
Pace Analytical Services -West Columbia Catherine S- Dover cathy.dover0pacelabs.com
Address Sampler's Signature Analysis [Attach list it more space is needed] Page
106 Vantage Point Drive
City State lip Code
1 of 2
X Lot >i Bar Code
West Columbia I SC 129172 Printed Name (lab use only)
Project Name
North Wake Unlined Landfill-yd05007
Project Number P-o, No. No of Containers by 4,
Matrix P
Preservative Type a
Sample ID I Description Collection Collection T a c e m M Y Y x
(rOnlalnem ror each sampra may ba Combined on ona ana) ❑ate(S} Time ' c ry Q z 0 M ¢ UNl Remarks 1 Cooler I-D-
[militaryj ¢ _ z aor LL
7
MW-9 4/4/2023 1210 G X 2 X YD05007.001 I
MW-36 4/4/2023 1245 G X +1 2 X YD05007-002 d-
MW-34 4/4/2023 1420 G X 2 X YI705007-003
MW-34d 4/4/2023 1500 G X 2 X YD05007-004
MW-5R 4/4/2023 1540 G X 2 X YD05007-005 J
MW-10 4/5/2023 0915 G X 2 X YD05007-014
MW-6 4/5/2023 1110 G X 2 X YD05007-015 7
MW-8 4/5/2023 1242 G ]( 2 X YD05007-016
MW-11 4/5/2023 1645 G X 2 X YD05007-017
MW-5R 4/5/2023 1152 G X 1 X YD05007-032
Tom Around Time Required (Prier lab approval required for aa<peciled TAT) Sample Disposal Possible Hazard Identification (List any known hazards In the remarks) OC Requirements
standard ❑ Rush (Please speay) 10 BUSINESS DAYS ❑Saturn to Client Disposal by Lab ❑ Non•Ha arduus ❑ Flammable ❑ Skin Imiani ❑ SIDS provided ❑ Unknown
1. Relinquished b t . � 2,02 Time 1. Received by + 7 L Date Time
2, Relinquished by ws ❑a T e r 2. Receiv ' by J ❑ to Time
3. Relinquished by Date Time 3. Received by Date Time
4. Relinquished by Dale Time 4. Laboratory Received by Date Time
Note: All samples are retained for four weeks from LAB USE ONLY Receipt Temp. temp. Blank
receipt unless other arran ements are made Received on Ice (Check) ❑ Y ❑ N ❑ Ice Pack ° C ❑ Y 1 ❑N
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 14 of 16

Analytical m Chain of Custody
Record
Pace Analytical Services -West Columbia Catherine S. Dover
Client ID: Shealy Envn - Pace Analytical services South Carolina
Pace Analytical Services, LLC. 5DG' 223041439
106 Vantage Point Drive PIN: R',i e
West Columbia, South Carolina 29172
Telephone No. [phone] Fax No. (803) 791-B11 z
Address
Sampler's Signature
106 Vantage Point Ddvo
City
Stale
zip code
West Columbia
SC
29172
X
Printed Name
Project Name
North Wake Unlined Landfill-YD05007
Project Number
P.D- No.
Matrix
ro ;;
Sample ID / Description
Collection
Collection
c .
(Containers for each sampla may be comtolned on one line)
Date 8
{ }
Time
o
to
o !
a
(military)
a
K
MW-6
4/5/2023
1128
G
X
4
MW-8
1 4/5/2023
1242
1 G
X
a
a
a
v
o
to
X
X
more space
urn Around Time Required (Prior lab approval required for expedited TAT) Sample Disposal Possibla Hazard Identification (List any laid.. hazards In the remarks)
0 Slandacd ❑ Rush (Please Specify) 10 business days ❑ Return to Client 0 Disposal by Lab ❑ Non•Hazarduus ❑ rlammable ❑ Swn rrrilanr ❑ SM pr idaa ❑ unknown
Ralinqui d Time
y � ] 1. Received by Dale
Ra11 uishe ale / Time 2- Received b pate
Relinquished by ale Time 3, Received
Date
Relinquished by Dale Time 4. Laboratory Received by Date
Note: All samples are retained for four weeks from LAB USE ONLY Receipt Temp,
receipt unless other arrangements are made I Received on Ice (Check) ❑ Y ❑ N ❑ Ice Pack (�
of
.ot #Bar Codi
(lab use only)
Remarks 1 Cooler I. D-
YD05007-033 1`
YD05007-034 ,
NCDEQ EQUIS
Requirements
Blank
Y / ❑N
Pace Gulf Coast Report#: 223041439 05/01/2023 12:52 Page 15 of 16

/.5navivfica' SAMPLE RECEIVING CHECKLIST IIIIII1 II3III
SAMPLE DELIVERY GROUP
223041439
CHECKLIST
YES
NO
Client PM RWe
Transport Method
Samples received with proper thermal preservation?
*❑
❑
Shealy Envir - Pace Analytical
FEDDC
Services South Carolina
Radioactivity is <1600 cpm? If no, record cpm value in notes section.
COC relinquished and complete (including samplelDs, collect times, and sampler)?
❑
*❑
❑
❑
Profile Number
Received By
284727
Henderson, Jacob R
All containers received in good condition and within hold time?
All sample labels and containers received match the chain of custody?
0
0
❑
❑
Line Item(s)
Receive Date(s)
1 - LL VFA
04/14/23
2- Hydrogen
Preservative added to any containers?
❑
*❑
If received, was headspace for VOC water containers < 6mm?
*❑
❑
Samples collected in containers provided by Pace Gulf Coast?
❑❑
COOLERS
DISCREPANCIES
LAB PRESERVATIONS
Airbill Thermometer ID: E43
Temp °C
None
None
1663 3469 8190
0.4
NOTES
Revision 1.6
Page 1 of 1
Pace Gulf Coast Report#: 223041439
05/01 /2023 12:52
Page 16 of 16

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: North Wake Unlined Landfill
Lot Number:YD05008
Date Completed:05/12/2023
05/14/2023 10:55 PM
Approved and released by:
Project Manager II: Cathy S. Dover
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The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 13

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: YD05008
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Metals 6020B
Dissolved metals sample YD05008-003 (MW-28d) was taken off hold per client.
The method blank associated with batch 74283 had Antimony detected at a concentration that was above
the DL but below the LOQ. All samples associated with this method blank that have detections for
Antimony have been flagged with a "B".
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
Page 2 of 13

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: YD05008
Project Name: North Wake Unlined Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-36
Aqueous
04/04/20231245
04/05/2023
002
MW-23
Aqueous
04/04/20231140
04/05/2023
003
MW-28d
Aqueous
04/05/20231440
04/06/2023
004
MW-28
Aqueous
04/05/20231515
04/06/2023
(4 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 13

ICP-MS
Client:CDM Smith Laboratory ID:YD05008-003
Description: MW-28d Matrix: Aqueous
Date Sampled:04/05/2023 1440 Project Name: North Wake Unlined Landfill
Date Received:04/06/2023 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 05/10/2023 1830 BNW 05/04/2023 2035 74283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Antimony
7440-36-0 6020B 1.4 BJ 2.0 0.50 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 13

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: YD05008
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 13

ICP-MS - MB
Sample ID: YQ74283-001 Matrix: Aqueous
Batch: 74283 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 05/04/2023 2035
Parameter Result Q Dil LOQ DL Units Analysis Date
Dissolved Antimony 0.80 J 1 2.0 0.50 ug/L 05/10/2023 1656
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 13
QC Data for Lot Number: YD05008

ICP-MS - LCS
Sample ID: YQ74283-002 Matrix: Aqueous
Batch: 74283 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 05/04/2023 2035
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Dissolved Antimony 100 110 1 105 80-120 05/10/2023 1703
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 13
QC Data for Lot Number: YD05008

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 13

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PACE ANALYTICAL SERVICES, LLC
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PACE ANALYTICAL SERVICES, LLC
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Page 13 of 13