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HomeMy WebLinkAboutWS-7265_30671_CA_WSW_20230428_WW36-Results04/27/23 Technical Report for Atlas Pantry 161 1031 Hwy 87 N, Elon College, NC PANT1612023 SGS Job Number: LA89956 Sampling Date: 04/19/23 Report to: ATC Group Services LLC. 2725 East Millbrook Road Suite 121 Raleigh, NC 27604 maureen.jackson@oneatlas.com ATTN: Maureen Jackson Total number of pages in report: Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31), NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257) This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: 337-237-4775 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable. Client Service contact: Rebecca Hebert 337-237-4775 Kesavalu Bagawandoss General Manager Scott, LA 04/27/23 e-Hardcopy 2.0 Automated Report 19 SGS is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. Review standard terms at: http://www.sgs.com/en/terms-and-conditions The results set forth herein are provided by SGS North America Inc. Please share your ideas about how we can serve you better at: EHS.US.CustomerCare@sgs.com 1 of 19 LA89956 Table of Contents -1- Sections: Section 1: Sample Summary ................................................................................................... 3 Section 2: Summary of Hits .................................................................................................... 4 Section 3: Sample Results ........................................................................................................5 3.1: LA89956-1: WW36 ...................................................................................................... 6 Section 4: Misc. Forms ............................................................................................................9 4.1: Chain of Custody ........................................................................................................... 10 Section 5: MS Volatiles - QC Data Summaries ..................................................................... 13 5.1: Method Blank Summary ................................................................................................ 14 5.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 17 123452 of 19 LA89956 SGS North America Inc. Sample Summary Atlas Job No:LA89956 Pantry 161 1031 Hwy 87 N, Elon College, NC Project No: PANT1612023 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID This report contains results reported as ND = Not detected. The following applies: Organics ND = Not detected above the MDL LA89956-1 04/19/23 10:50 BB 04/25/23 AQ Water WW36 3 of 19 LA899561 Summary of Hits Page 1 of 1 Job Number:LA89956 Account:Atlas Project:Pantry 161 1031 Hwy 87 N, Elon College, NC Collected:04/19/23 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method LA89956-1 WW36 Di-Isopropyl Ether 0.55 0.50 0.073 ug/l SM 6200B Methyl Tert Butyl Ether 0.78 0.50 0.068 ug/l SM 6200B Toluene 0.75 0.50 0.29 ug/l SM 6200B 4 of 19 LA899562 SGS North America Inc. Sample Results Report of Analysis Scott, LA Section 3 5 of 19 LA899563 SGS North America Inc. Report of Analysis Page 1 of 3 Client Sample ID:WW36 Lab Sample ID:LA89956-1 Date Sampled:04/19/23 Matrix:AQ - Water Date Received:04/25/23 Method:SM 6200B Percent Solids:n/a Project:Pantry 161 1031 Hwy 87 N, Elon College, NC File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2K0145997.D 1 04/26/23 13:21 MB n/a n/a V2K4086 Run #2 Purge Volume Run #1 25.0 ml Run #2 VOA Special List CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone a ND 10 1.2 ug/l 71-43-2 Benzene ND 0.50 0.27 ug/l 108-86-1 Bromobenzene ND 0.50 0.18 ug/l 74-97-5 Bromochloromethane ND 0.50 0.12 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.18 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.092 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.16 ug/l 56-23-5 Carbon Tetrachloride ND 0.20 0.092 ug/l 108-90-7 Chlorobenzene ND 0.50 0.16 ug/l 75-00-3 Chloroethane ND 0.50 0.055 ug/l 67-66-3 Chloroform ND 0.50 0.094 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.16 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.20 ug/l 124-48-1 Dibromochloromethane ND 0.20 0.075 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.13 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.24 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.12 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.063 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.20 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.22 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.20 0.12 ug/l 75-35-4 1,1-Dichloroethylene ND 0.50 0.094 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.11 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.15 ug/l 78-87-5 1,2-Dichloropropane ND 0.30 0.13 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.21 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.079 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.12 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.20 0.10 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 6 of 19 LA8995633.1 SGS North America Inc. Report of Analysis Page 2 of 3 Client Sample ID:WW36 Lab Sample ID:LA89956-1 Date Sampled:04/19/23 Matrix:AQ - Water Date Received:04/25/23 Method:SM 6200B Percent Solids:n/a Project:Pantry 161 1031 Hwy 87 N, Elon College, NC VOA Special List CAS No. Compound Result RL MDL Units Q 10061-02-6 trans-1,3-Dichloropropene ND 0.20 0.056 ug/l 108-20-3 Di-Isopropyl Ether 0.55 0.50 0.073 ug/l 64-17-5 Ethyl Alcohol ND 50 8.4 ug/l 100-41-4 Ethylbenzene ND 0.50 0.20 ug/l 637-92-3 Ethyl Tert-Butyl Ether ND 0.50 0.056 ug/l 591-78-6 2-Hexanone ND 1.0 0.42 ug/l 87-68-3 Hexachlorobutadiene ND 0.20 0.11 ug/l 98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l 74-83-9 Methyl Bromide ND 0.50 0.23 ug/l 74-87-3 Methyl Chloride ND 0.50 0.066 ug/l 74-95-3 Methylene Bromide ND 0.50 0.11 ug/l 75-09-2 Methylene Chloride ND 0.50 0.080 ug/l 78-93-3 Methyl Ethyl Ketone ND 25 0.28 ug/l 108-10-1 4-Methyl-2-pentanone ND 0.50 0.24 ug/l 1634-04-4 Methyl Tert Butyl Ether 0.78 0.50 0.068 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.22 ug/l 100-42-5 Styrene ND 0.50 0.13 ug/l 75-85-4 Tert-Amyl Alcohol b ND 25 0.77 ug/l 994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.084 ug/l 75-65-0 Tert-Butyl Alcohol ND 10 1.0 ug/l 762-75-4 tert-Butyl Formate ND 5.0 0.035 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.18 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 0.12 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.22 ug/l 108-88-3 Toluene 0.75 0.50 0.29 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.16 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.17 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.30 0.17 ug/l 79-01-6 Trichloroethylene ND 0.50 0.18 ug/l 75-69-4 Trichlorofluoromethane ND 0.50 0.073 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.023 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.15 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.16 ug/l 108-05-4 Vinyl Acetate ND 0.50 0.069 ug/l 75-01-4 Vinyl Chloride ND 0.10 0.075 ug/l m,p-Xylene ND 1.0 0.34 ug/l 95-47-6 o-Xylene ND 0.50 0.15 ug/l ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7 of 19 LA8995633.1 SGS North America Inc. Report of Analysis Page 3 of 3 Client Sample ID:WW36 Lab Sample ID:LA89956-1 Date Sampled:04/19/23 Matrix:AQ - Water Date Received:04/25/23 Method:SM 6200B Percent Solids:n/a Project:Pantry 161 1031 Hwy 87 N, Elon College, NC VOA Special List CAS No. Compound Result RL MDL Units Q 1330-20-7 Xylene (total)ND 0.50 0.16 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 102%70-130% 2037-26-5 Toluene-D8 104%70-130% 460-00-4 4-Bromofluorobenzene 101%70-130% (a) CCV recovery was above method acceptance criteria. No compounds detected above client requested RLs. (b) Associated CCV outside of control limits high, sample was ND. ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 8 of 19 LA8995633.1 SGS North America Inc. Misc. Forms Custody Documents and Other Forms Includes the following where applicable: • Chain of Custody Scott, LA Section 4 9 of 19 LA899564 CHAIN OF CUSTODY PAGE I or SGS l{orth Amorica lnc. - Scott 500 Ambassador Caffery Pa*way, Scon, LA 70583 TEL.337.237 4715 FAX: 337 237.7838 4-tul '"'i'a,]*T n nl*zfif, g pywffrot\b ^?tttb.l"N-, u6rl ^rLELoN "'""'?*Nlqzb'L)iiiili"ffiil W0) sAs.-9 4A *vm3 Hffi*S'd qnarc-ttff."frfl{i,p"urJ o;F€/scJ LAA USE ONLYo 3 aField lD / Point ol Colleciion x ')rIDSOt9,DM 3wGV$/L1 Commenls / SPecial lnslructimoala oelNerable lntohationII Note: Sample inventory is verified upon receiplflI 6 Laboratory {3S. D conm.E 'r"c" E (nhd- Coffi.t l 'A' = R6ults Only, Comrcial'B'= R.sulh +qC Summary com6r@l'C = R6s![s + o!.S.rndt+ Pania R.w Oala E RECAP E staro F.m3 fl Eoo Fom.rE FULlri ( L.v.r 3+4 ) E REorl lL6wr!+t) comm.rcrar "A" (L.wl1) comi.Gltl "B' ( L.v.r 2)E 5 B!.I.s o.ys RU3H E a Bo.lnd! o.ys Rt SH E 3 B!.hs o.yE RUSH n 2 Au.ln.$ Dlyr RUSH E 1 Bu.h6! D.y HTERGE IcY E@rooncv 8 Rush T/A data ara labl6 via Lablit[ AppmvaL needed ,b. RUSH/E@rgenc, TAT Ee*-, **,*".*"y"&provdd By (scs Prrr): / o!ro: Gi"r,-g. p"""""",on.,n.lod'ns cou.'er dehvsry.musl be docum€nled below Wil24lW1:Ellilhl rooD 1 idr'ili;;; sy, 43)3 a5 Pn'frdal@..,A<.bl-.-.V .-" nr FHsA,oAC.oo2eoO FORM-S6n . Slandad COC FINAI httpJ/www sgs.com/enterms_and condilions I +, Clienl / hTL I II I III II II ttI I IIIII III II IIIIII Ittl 'lI ) I I LA89956: Chain of Custody Page 1 of 3 10 of 19 LA8995644.1 -tslillPLERcr,rrvIfrU'''o;Gs scoTT LA LABORATORYr(ts coMMISSION BLVD'JTAYETTE LA 705081,,i- 1f75\oo$E--utrrlItlllilIilillillllllllll I I ll llll lllil lllllllllllI llledExExpla..TUE -PRIORIAFROllTBNIGHT70508LA-u8 LFT11ol 31707 9051 1947L rrR *rr## MA8tLFTAXHillilffiiltilffilt[wlr\'lJe<--\\i\J=-{1-)1Et:iIc{t0201<)oLA89956: Chain of Custody Page 2 of 3 11 of 19 LA8995644.1 SGS Sample Receipt Summary Job Number:LA89956 Client:ATC Date / Time Received:4/25/2023 9:50:00 AM Delivery Method:FEDEX Project:PANTRY #161 4. No. Coolers:1 Airbill #'s:570790511947 Cooler Security 1. Custody Seals Present: Y or N 2. Custody Seals Intact: 3. COC Present: 4. Smpl Dates/Time OK 2. Thermometer ID: Cooler Temperature Y or N 1. Temp criteria achieved: 3. Cooler media: IR002; Ice (direct contact) Quality Control Preservation Y or N N/A 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: 3. Samples preserved properly: 4. VOCs headspace free: Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3. Sample container label / COC agree: Sample Integrity - Condition Y or N 1. Sample recvd within HT: 3. Condition of sample: 2. All containers accounted for: Sample Integrity - Instructions 1. Analysis requested is clear: 2. Bottles received for unspecified tests 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Intact Y or N Comments Y or N N/A Cooler Temps (Initial/Adjusted):#1: (1.8/1.6); LA89956: Chain of Custody Page 3 of 3 12 of 19 LA8995644.1 SGS North America Inc. MS Volatiles QC Data Summaries Includes the following where applicable: • Method Blank Summaries • Blank Spike Summaries • Matrix Spike and Duplicate Summaries Scott, LA Section 5 13 of 19 LA899565 Method Blank Summary Page 1 of 3 Job Number:LA89956 Account:ATCNCR Atlas Project:Pantry 161 1031 Hwy 87 N, Elon College, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2K4086-MB1 2K0145996.D 1 04/26/23 MB n/a n/a V2K4086 The QC reported here applies to the following samples:Method: SM 6200B LA89956-1 CAS No. Compound Result RL MDL Units Q 67-64-1 Acetone ND 10 1.2 ug/l 71-43-2 Benzene ND 0.50 0.27 ug/l 108-86-1 Bromobenzene ND 0.50 0.18 ug/l 74-97-5 Bromochloromethane ND 0.50 0.12 ug/l 75-27-4 Bromodichloromethane ND 0.50 0.18 ug/l 75-25-2 Bromoform ND 0.50 0.10 ug/l 104-51-8 n-Butylbenzene ND 0.50 0.092 ug/l 135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l 98-06-6 tert-Butylbenzene ND 0.50 0.16 ug/l 56-23-5 Carbon Tetrachloride ND 0.20 0.092 ug/l 108-90-7 Chlorobenzene ND 0.50 0.16 ug/l 75-00-3 Chloroethane ND 0.50 0.055 ug/l 67-66-3 Chloroform ND 0.50 0.094 ug/l 95-49-8 o-Chlorotoluene ND 0.50 0.16 ug/l 106-43-4 p-Chlorotoluene ND 0.50 0.20 ug/l 124-48-1 Dibromochloromethane ND 0.20 0.075 ug/l 96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.13 ug/l 106-93-4 1,2-Dibromoethane ND 0.50 0.24 ug/l 75-71-8 Dichlorodifluoromethane ND 0.50 0.12 ug/l 541-73-1 m-Dichlorobenzene ND 0.50 0.063 ug/l 95-50-1 o-Dichlorobenzene ND 0.50 0.20 ug/l 106-46-7 p-Dichlorobenzene ND 0.50 0.22 ug/l 75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l 107-06-2 1,2-Dichloroethane ND 0.20 0.12 ug/l 75-35-4 1,1-Dichloroethylene ND 0.50 0.094 ug/l 156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.11 ug/l 156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.15 ug/l 78-87-5 1,2-Dichloropropane ND 0.30 0.13 ug/l 142-28-9 1,3-Dichloropropane ND 0.50 0.21 ug/l 594-20-7 2,2-Dichloropropane ND 0.50 0.079 ug/l 563-58-6 1,1-Dichloropropene ND 0.50 0.12 ug/l 10061-01-5 cis-1,3-Dichloropropene ND 0.20 0.10 ug/l 10061-02-6 trans-1,3-Dichloropropene ND 0.20 0.056 ug/l 108-20-3 Di-Isopropyl Ether ND 0.50 0.073 ug/l 64-17-5 Ethyl Alcohol ND 50 8.4 ug/l 100-41-4 Ethylbenzene ND 0.50 0.20 ug/l 14 of 19 LA8995655.1.1 Method Blank Summary Page 2 of 3 Job Number:LA89956 Account:ATCNCR Atlas Project:Pantry 161 1031 Hwy 87 N, Elon College, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2K4086-MB1 2K0145996.D 1 04/26/23 MB n/a n/a V2K4086 The QC reported here applies to the following samples:Method: SM 6200B LA89956-1 CAS No. Compound Result RL MDL Units Q 637-92-3 Ethyl Tert-Butyl Ether ND 0.50 0.056 ug/l 591-78-6 2-Hexanone ND 1.0 0.42 ug/l 87-68-3 Hexachlorobutadiene 0.15 0.20 0.11 ug/l J 98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l 99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l 74-83-9 Methyl Bromide ND 0.50 0.23 ug/l 74-87-3 Methyl Chloride ND 0.50 0.066 ug/l 74-95-3 Methylene Bromide ND 0.50 0.11 ug/l 75-09-2 Methylene Chloride ND 0.50 0.080 ug/l 78-93-3 Methyl Ethyl Ketone ND 25 0.28 ug/l 108-10-1 4-Methyl-2-pentanone ND 0.50 0.24 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.068 ug/l 91-20-3 Naphthalene ND 0.50 0.10 ug/l 103-65-1 n-Propylbenzene ND 0.50 0.22 ug/l 100-42-5 Styrene ND 0.50 0.13 ug/l 75-85-4 Tert-Amyl Alcohol ND 25 0.77 ug/l 994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.084 ug/l 75-65-0 Tert-Butyl Alcohol ND 10 1.0 ug/l 762-75-4 tert-Butyl Formate ND 5.0 0.035 ug/l 630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.18 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 0.20 0.12 ug/l 127-18-4 Tetrachloroethylene ND 0.50 0.22 ug/l 108-88-3 Toluene ND 0.50 0.29 ug/l 87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.16 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.17 ug/l 71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l 79-00-5 1,1,2-Trichloroethane ND 0.30 0.17 ug/l 79-01-6 Trichloroethylene ND 0.50 0.18 ug/l 75-69-4 Trichlorofluoromethane ND 0.50 0.073 ug/l 96-18-4 1,2,3-Trichloropropane ND 0.50 0.023 ug/l 95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.15 ug/l 108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.16 ug/l 108-05-4 Vinyl Acetate ND 0.50 0.069 ug/l 75-01-4 Vinyl Chloride ND 0.10 0.075 ug/l m,p-Xylene ND 1.0 0.34 ug/l 95-47-6 o-Xylene ND 0.50 0.15 ug/l 15 of 19 LA8995655.1.1 Method Blank Summary Page 3 of 3 Job Number:LA89956 Account:ATCNCR Atlas Project:Pantry 161 1031 Hwy 87 N, Elon College, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2K4086-MB1 2K0145996.D 1 04/26/23 MB n/a n/a V2K4086 The QC reported here applies to the following samples:Method: SM 6200B LA89956-1 CAS No. Compound Result RL MDL Units Q 1330-20-7 Xylene (total)ND 0.50 0.16 ug/l CAS No. Surrogate Recoveries Limits 17060-07-0 1,2-Dichloroethane-D4 104% 70-130% 2037-26-5 Toluene-D8 105% 70-130% 460-00-4 4-Bromofluorobenzene 105% 70-130% 16 of 19 LA8995655.1.1 Blank Spike/Blank Spike Duplicate Summary Page 1 of 3 Job Number:LA89956 Account:ATCNCR Atlas Project:Pantry 161 1031 Hwy 87 N, Elon College, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2K4086-BS1 2K0145993.D 1 04/26/23 MB n/a n/a V2K4086 V2K4086-BSD1 2K0145994.D 1 04/26/23 MB n/a n/a V2K4086 The QC reported here applies to the following samples:Method: SM 6200B LA89956-1 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD 67-64-1 Acetone 50 71.7 143* a 68.1 136* a 5 70-130/30 71-43-2 Benzene 20 19.1 96 20.3 102 6 70-130/30 108-86-1 Bromobenzene 20 18.3 92 18.9 95 3 70-130/30 74-97-5 Bromochloromethane 20 23.1 116 23.0 115 0 70-130/30 75-27-4 Bromodichloromethane 20 23.0 115 24.3 122 5 70-130/30 75-25-2 Bromoform 20 19.5 98 20.0 100 3 70-130/30 104-51-8 n-Butylbenzene 20 21.8 109 22.0 110 1 70-130/30 135-98-8 sec-Butylbenzene 20 21.0 105 21.2 106 1 70-130/30 98-06-6 tert-Butylbenzene 20 20.6 103 20.8 104 1 70-130/30 56-23-5 Carbon Tetrachloride 20 23.0 115 23.9 120 4 70-130/30 108-90-7 Chlorobenzene 20 19.0 95 19.8 99 4 70-130/30 75-00-3 Chloroethane 20 21.9 110 21.8 109 0 60-140/30 67-66-3 Chloroform 20 20.5 103 20.8 104 1 70-130/30 95-49-8 o-Chlorotoluene 20 19.4 97 19.7 99 2 70-130/30 106-43-4 p-Chlorotoluene 20 20.4 102 20.6 103 1 70-130/30 124-48-1 Dibromochloromethane 20 19.9 100 20.7 104 4 70-130/30 96-12-8 1,2-Dibromo-3-chloropropane 20 20.4 102 19.5 98 5 70-130/30 106-93-4 1,2-Dibromoethane 20 21.4 107 22.0 110 3 70-130/30 75-71-8 Dichlorodifluoromethane 20 17.9 90 18.1 91 1 60-140/30 541-73-1 m-Dichlorobenzene 20 19.4 97 19.2 96 1 70-130/30 95-50-1 o-Dichlorobenzene 20 20.0 100 20.0 100 0 70-130/30 106-46-7 p-Dichlorobenzene 20 20.1 101 20.0 100 0 70-130/30 75-34-3 1,1-Dichloroethane 20 20.9 105 21.6 108 3 70-130/30 107-06-2 1,2-Dichloroethane 20 19.9 100 20.8 104 4 70-130/30 75-35-4 1,1-Dichloroethylene 20 20.6 103 21.9 110 6 70-130/30 156-59-2 cis-1,2-Dichloroethylene 20 20.3 102 21.0 105 3 70-130/30 156-60-5 trans-1,2-Dichloroethylene 20 20.4 102 21.1 106 3 70-130/30 78-87-5 1,2-Dichloropropane 20 20.3 102 21.2 106 4 70-130/30 142-28-9 1,3-Dichloropropane 20 20.4 102 20.7 104 1 70-130/30 594-20-7 2,2-Dichloropropane 20 23.7 119 24.8 124 5 70-130/30 563-58-6 1,1-Dichloropropene 20 21.7 109 22.1 111 2 70-130/30 10061-01-5 cis-1,3-Dichloropropene 20 25.5 128 26.9 135* a 5 70-130/30 10061-02-6 trans-1,3-Dichloropropene 20 24.9 125 25.9 130 4 70-130/30 108-20-3 Di-Isopropyl Ether 20 22.3 112 22.9 115 3 70-130/30 64-17-5 Ethyl Alcohol 400 673 168* a 572 143* a 16 70-130/30 100-41-4 Ethylbenzene 20 19.2 96 19.8 99 3 70-130/30 * = Outside of Control Limits. 17 of 19 LA8995655.2.1 Blank Spike/Blank Spike Duplicate Summary Page 2 of 3 Job Number:LA89956 Account:ATCNCR Atlas Project:Pantry 161 1031 Hwy 87 N, Elon College, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2K4086-BS1 2K0145993.D 1 04/26/23 MB n/a n/a V2K4086 V2K4086-BSD1 2K0145994.D 1 04/26/23 MB n/a n/a V2K4086 The QC reported here applies to the following samples:Method: SM 6200B LA89956-1 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD 637-92-3 Ethyl Tert-Butyl Ether 20 22.3 112 22.8 114 2 70-130/30 591-78-6 2-Hexanone 50 58.0 116 58.0 116 0 70-130/30 87-68-3 Hexachlorobutadiene 20 22.0 110 22.0 110 0 70-130/30 98-82-8 Isopropylbenzene 20 19.5 98 20.4 102 5 70-130/30 99-87-6 p-Isopropyltoluene 20 21.2 106 21.2 106 0 70-130/30 74-83-9 Methyl Bromide 20 17.4 87 18.3 92 5 60-140/30 74-87-3 Methyl Chloride 20 19.8 99 20.5 103 3 60-140/30 74-95-3 Methylene Bromide 20 21.0 105 22.2 111 6 70-130/30 75-09-2 Methylene Chloride 20 21.4 107 21.9 110 2 70-130/30 78-93-3 Methyl Ethyl Ketone 50 62.2 124 61.1 122 2 70-130/30 108-10-1 4-Methyl-2-pentanone 50 58.4 117 59.8 120 2 70-130/30 1634-04-4 Methyl Tert Butyl Ether 20 21.8 109 22.2 111 2 70-130/30 91-20-3 Naphthalene 20 23.7 119 23.1 116 3 70-130/30 103-65-1 n-Propylbenzene 20 20.0 100 20.2 101 1 70-130/30 100-42-5 Styrene 20 22.8 114 23.8 119 4 70-130/30 75-85-4 Tert-Amyl Alcohol 200 268 134 257 129 4 50-150/30 b 994-05-8 Tert-Amyl Methyl Ether 20 20.6 103 21.5 108 4 70-130/30 75-65-0 Tert-Butyl Alcohol 100 144 144* a 136 136* a 6 70-130/30 762-75-4 tert-Butyl Formate 20 17.0 85 17.8 89 5 50-150/30 b 630-20-6 1,1,1,2-Tetrachloroethane 20 21.5 108 22.4 112 4 70-130/30 79-34-5 1,1,2,2-Tetrachloroethane 20 22.8 114 21.8 109 4 70-130/30 127-18-4 Tetrachloroethylene 20 17.1 86 18.3 92 7 70-130/30 108-88-3 Toluene 20 19.3 97 20.1 101 4 70-130/30 87-61-6 1,2,3-Trichlorobenzene 20 21.6 108 20.9 105 3 70-130/30 120-82-1 1,2,4-Trichlorobenzene 20 22.5 113 22.6 113 0 70-130/30 71-55-6 1,1,1-Trichloroethane 20 22.1 111 23.0 115 4 70-130/30 79-00-5 1,1,2-Trichloroethane 20 20.5 103 20.8 104 1 70-130/30 79-01-6 Trichloroethylene 20 20.4 102 21.7 109 6 70-130/30 75-69-4 Trichlorofluoromethane 20 24.3 122 24.6 123 1 60-140/30 96-18-4 1,2,3-Trichloropropane 20 20.4 102 20.7 104 1 70-130/30 95-63-6 1,2,4-Trimethylbenzene 20 20.5 103 20.5 103 0 70-130/30 108-67-8 1,3,5-Trimethylbenzene 20 21.1 106 21.0 105 0 70-130/30 108-05-4 Vinyl Acetate 20 26.2 131* a 26.7 134* a 2 70-130/30 75-01-4 Vinyl Chloride 20 21.3 107 22.0 110 3 60-140/30 m,p-Xylene 40 40.6 102 42.2 106 4 70-130/30 95-47-6 o-Xylene 20 19.5 98 20.3 102 4 70-130/30 * = Outside of Control Limits. 18 of 19 LA8995655.2.1 Blank Spike/Blank Spike Duplicate Summary Page 3 of 3 Job Number:LA89956 Account:ATCNCR Atlas Project:Pantry 161 1031 Hwy 87 N, Elon College, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2K4086-BS1 2K0145993.D 1 04/26/23 MB n/a n/a V2K4086 V2K4086-BSD1 2K0145994.D 1 04/26/23 MB n/a n/a V2K4086 The QC reported here applies to the following samples:Method: SM 6200B LA89956-1 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD 1330-20-7 Xylene (total)60 60.1 100 62.5 104 4 70-130/30 CAS No. Surrogate Recoveries BSP BSD Limits 17060-07-0 1,2-Dichloroethane-D4 102%104% 70-130% 2037-26-5 Toluene-D8 103%105% 70-130% 460-00-4 4-Bromofluorobenzene 96%101% 70-130% (a) Outside control limits biased high. Analyte not detected in associated samples. (b) Advisory control limits. * = Outside of Control Limits. 19 of 19 LA8995655.2.1