WS-4579_14873_CA_MRP_20230331

Chevron Environmental Management Company
Groundwater Monitoring
Report – First Quarter 2023
Former Chevron Facility (Gulf Oil) #205513
600 South Main Street (formerly 500 South Main Street) High Point, North Carolina 27260
Guilford County
UST Incident Numbers 14873
Risk Classification: Intermediate
Release Information
Date Discovered: October 1995
Estimated Quantity of Release: Unknown
Cause of Release: Unknown
Source of Release: 5 – 1,000-gallon gasoline tanks (USTs 4, 5, 6, 7, and 8) and 1 – 650-gallon waste
oil tank (UST 9); (Incident # 14874 also associated with this property had
documented releases from 3 – 6,000-gallon gasoline tanks (USTs 11, 12, and
13)
Site latitude: 35°56’56” N (NAD 27)
Site Longitude: 80°00’18” W (NAD 27)
Location Method: GPS Surveyed
Groundwater Monitoring Report – First Quarter 2023
This document is intended only for the use of the individual or entity for which it was prepared and may contain information
that is privileged, confidential and exempt from disclosure under applicable law. Any dissemination, distribution or copying of
this document is strictly prohibited.
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Groundwater Monitoring Report – First
Quarter 2023
Former Chevron Facility (Gulf Oil) #205513
March 31, 2023
Prepared By: Prepared For:
Arcadis G&M of North Carolina, Inc. (Certification C-1869). North Carolina Department of Environmental
3540 Toringdon Way Quality, Division of Waste Management
Suite 220 UST Section
Charlotte
North Carolina 28277
Phone: [phone]
Fax: [phone]
Our Ref:
30064349
________________________________________
Sherrie Lang
Certified Project Manager
_______________________________________
Scott Bostian, P.E. #25659
Principal Chemical Engineer
Groundwater Monitoring Report – First Quarter 2023
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Contents
Acronyms and Abbreviations ................................................................................................................................ iv
1 Executive Summary ......................................................................................................................................... 1
2 Site Location and Characterization ............................................................................................................... 1
2.1 Facility Ownership and Well Installation History ................................................................................. 2
3 Receptor Information ...................................................................................................................................... 2
4 Geology and Hydrogeology ............................................................................................................................ 2
4.1 Regional Geology and Hydrogeology ................................................................................................... 2
4.2 Site Geology ............................................................................................................................................. 3
5 Groundwater Monitoring ................................................................................................................................. 3
5.1 Groundwater Gauging ............................................................................................................................. 3
5.2 Groundwater Sampling ........................................................................................................................... 3
5.3 Groundwater Analytical Results ............................................................................................................ 4
6 Investigative Derived Waste ........................................................................................................................... 5
7 Conclusion and Recommendations .............................................................................................................. 5
8 References ....................................................................................................................................................... 6
9 Statements and Certification .......................................................................................................................... 7
Groundwater Monitoring Report – First Quarter 2023
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Tables
Table 1 - UST System Information
Table 2 - UST Owner/Operator Information
Table 3 - Groundwater Monitoring Well Construction and Elevation Data
Table 4 - January 2023 Sampling Analysis Plan
Table 5 - Groundwater Analytical Results
Table 6 - MNA Parameter Analytical Results
Table 7 - Proposed Sampling Analysis Plan
Figures
Figure 1 - Site Location Map
Figure 2 - Land Use Map
Figure 3 - Site Map
Figure 4 - Groundwater Contour Map January 23, 2023
Figure 5 - Groundwater Analytical Map January 24-27, 2023
Figure 6 - Benzene Isoconcentration Contour Map
Figure 7 - 1,2-DCA Isoconcentration Contour Map
Figure 8 - EDB Concentration Map
Appendices
Regulatory Correspondence
Groundwater Sampling Field Logs
Laboratory Analytical and Validation Reports
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Acronyms and Abbreviations
Arcadis Arcadis U.S., Inc.
BBL Blasland, Bouck, and Lee, Inc.
bgs below ground surface
btoc below top of casing
PreCAP Pre-Corrective Action Plan Groundwater Assessment Report
CEMC Chevron Environmental Management Company
DO dissolved oxygen
EDB ethylene dibromide
GCL Gross Contaminant Level
GEX Geologic Exploration, Inc.
Gulf Oil Gulf Oil Company
Ilderton Oil Ilderton Oil Company
MS/MSD matrix spike/matrix spike duplicate
NCDEQ North Carolina Department of Environmental Quality
ORP oxygen reduction potential
PSH phase-separated hydrocarbon
PWR partially weathered rock
QA/QC quality assurance/quality control
µg/L microgram per liter
USEPA United States Environmental Protection Agency
USGS United States Geological Survey
US Survey United States Survey
UST underground storage tank
1,2-DCA 1,2-dichloroethane
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1 Executive Summary
On behalf of Chevron Environmental Management Company (CEMC), Arcadis U.S., Inc. (Arcadis) is pleased to
submit this Groundwater Monitoring Report – First Quarter 2023 (report). This report summarizes the groundwater
monitoring/sampling completed between January 24 and 27, 2023 at the former Chevron facility (Gulf Oil
Company #205513; the site; Incident #14873) located at 600 South Main Street in High Point, North Carolina. It
has been established that because Ilderton Oil (additional responsible party) had dissolved in 2012, North
Carolina Department of Environmental Quality (NCDEQ) Underground Storage Tank (UST) Section, Division of
Waste Management, Winston-Salem Regional Office would take over Incident #14874 under the state lead
program. It has also been proposed by NCDEQ that CEMC would clean up 1,2-dichloroethane (1,2-DCA) and
ethylene dibromide (EDB) concentrations to below the Gross Contamination Levels (GCLs), and once 1,2-DCA
and EDB were below the GCLs, NCDEQ would assume the remaining liability at the site.
The previous groundwater samples were collected in July 2022 and the results were submitted in the
Groundwater Monitoring Report – Third Quarter 2022, dated January 26, 2023. NCDEQ issued an
Acknowledgement of Report Receipt on February 6, 2023 and requested the next semiannual groundwater
monitoring event be completed in the first quarter of 2023 with a report summarizing data be submitted by March
31, 2023.
Groundwater data/samples collected between January 23 and 27, 2023 indicate methyl tertiary butyl ether
(MTBE) concentrations were above GCLs in one well (MW-8), and benzene concentrations were above GCLs in
four wells (MW-2, MW-7, and MW-8 and MW-9). This report was prepared in accordance with the NCDEQ
cleanup requirements pursuant to Title 15A North Carolina Administrative Code 2L, Title 15A Department of
Environmental Quality 0407(d) Risk-based Assessment and Corrective Action for Petroleum USTs for
intermediate risk. Regulatory correspondence is included in Appendix A.
2 Site Location and Characterization
The site is located at the southwest corner of Grimes Avenue and South Main Street in High Point, North
Carolina, as shown on the United States Geologic Survey (USGS) Topographic Quadrangle for High Point West
(Figures 1 and 2). High Point is located in the southwestern portion of Guilford County, North Carolina. The area
is urban in character and primarily commercial to the north, east, and south of the site. The area to the west is a
combination of commercial and residential. The local land use map is included on Figure 2.
The site currently operates as a retail oriental rug supplier, consisting of a large showroom and warehouse
structure with an asphalt parking lot. A two-door warehouse delivery bay exists on the southeast side of the facility
along Taylor Avenue. Additional customer and employee parking is situated along Taylor Avenue on the
southeast side of the property. The current site structure encompasses an area much larger than the original retail
petroleum station. At the time when the site operated as a petroleum retail station, the legal deed reported the site
dimensions as approximately 0.33 acre. The current property is greater than one acre in size and is listed as 600
South Main Steet.
The properties contiguous to the west were zoned as residential multi-family, although an area of commercial
properties was also shown as located to the west of the site. Beyond the immediate vicinity of the site, most
properties in the High Point Main Street area were shown to be zoned as commercial (2022 Arcadis). A site map
showing former site features and underground storage tank data is included on Figure 3.
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2.1 Facility Ownership and Well Installation History
Based on the information provided in the Phase I Environmental Site Assessment (ENSCI Environmental, Inc.
1995), the site was most likely used for residential purposes prior to 1929. In 1929, Gulf Oil purchased the
property, and USTs were installed at some point between 1929 and 1938, when they are evident on aerial
photographs of the area. Three 6,000-gallon USTs (ID numbers 1, 2, and 3) used for storage and distribution of
gasoline were installed in the UST field located on the northwest portion of the property in 1971. In 1979, Ilderton
Oil purchased the property and the existing 6,000-gallon USTs. Ilderton Oil operated USTs 1, 2, and 3 until they
were removed and replaced in October 1988 with three new 6,000-gallon USTs (ID numbers 11, 12, and 13). Gulf
Oil and its successors never owned or operated USTs 11, 12, and 13. In October 1995 and prior to the sale of the
property, Ilderton Oil removed USTs 11, 12, and 13. During these removal activities, seven additional USTs were
encountered and removed. Five 1,000-gallon USTs (ID numbers 4, 5, 6, 7, and 8), which appeared to have been
used for storage and distribution of gasoline, were encountered in a UST pit located on the northeastern portion of
the property. One 650-gallon UST used for the storage of used oil, and one 750-gallon UST used for the storage
of kerosene were located in a UST pit on the southern portion of the property. The seven additional USTs were
owned and operated by Gulf Oil and had previously been abandoned in place. A summary of USTs previously
located at the site is included in Table 1, and a summary of UST ownership is included in Table 2.
Between June 13 and 14, 2005, representatives of Blasland, Bouck and Lee, Inc. (BBL) and Geologic
Exploration, Inc. (GEX) (a North Carolina licensed well driller) installed groundwater monitoring wells MW-1,
MW-2, and MW-3 (BBL 2005). Between September 13 and 14, 2005, wells MW-5 and MW-6 were installed at
locations expected to be downgradient from the former Gulf Oil gasoline UST area as specified in the UST
Section Guidelines, and deep well MW-4D was installed adjacent to monitoring well MW-2 (BBL 2005). Between
February 24 and 25, 2014, representatives of Arcadis and GEX installed monitoring wells MW-7, MW-8, and
MW-9 (Arcadis 2014).
3 Receptor Information
A sensitive receptor survey was completed in April 2011. Potable water is obtained from a municipal supply in the
area of the site. Additionally, no potable water wells were identified within 1,500-feet of the site. The nearest
surface water body is an intermittent tributary of the Richland Creek, which has its headwater approximately
2,500-feet to the west of the former UST areas (Arcadis 2022).
4 Geology and Hydrogeology
The geology and hydrogeology for this area and the site are summarized below.
4.1 Regional Geology and Hydrogeology
The site is located within the Piedmont Physiographic Province in central North Carolina, which is characterized
by gently rolling landscape and broad ridges that lie between the Coastal Plain to the east and the Blue Ridge
Mountains to the west. The site is located within the Carolina Slate Belt. Rocks of this area generally consist of
metamorphosed igneous intrusive granitic rock ranging in age from 520 to 650 million years old (Brown, et al.
1985). The primary rock type in the area is metamorphosed granite with some intrusions of granodiorite and
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quartz diorite. This rock is best described as white to gray, and fine to coarse grained with massive foliation
(Carpenter 1982). Weathering of the rock in this area produces an overlying soil material identified as saprolite
which resembles soil but retains some of the structure of the parent bedrock. Saprolite is produced by chemical
weathering of the underlying crystalline rock. Saprolite grades with depth to a semi-consolidated material known
as partially weathered rock (PWR).
Regionally, groundwater is found in saprolite, PWR, and underlying bedrock. Typically, these units may behave
as separate, unconfined, and semi-confined units within the aquifer system. PWR can be included as part of the
unconfined unit because it reacts hydraulically with saprolite. The saprolite and PWR typically have the capacity
to store large volumes of groundwater and act as a groundwater reservoir due to their high porosity relative to the
underlying bedrock unit. Groundwater storied in the saprolite generally flows horizontally toward surface water
features mimicking the local topography. Metavolcanic rocks generally have almost no porosity features such as
joints and fractures that contain groundwater. Groundwater flow within bedrock fractures is controlled by the
number, size, spacing, orientation, and interconnectedness of the fractures (USGS 1997).
4.2 Site Geology
Based on data collected during previous monitoring well installations at the site, surficial soil and saprolite are
present from the ground surface to approximately 58 below ground surface (bgs) and consist of a clayey to sandy
silt.
5 Groundwater Monitoring
Groundwater sampling at the site was completed as summarized below.
5.1 Groundwater Gauging
On January 23, 2023, the nine site monitoring wells were gauged with an oil/water interface probe to measure
depth to groundwater, and phase separated hydrocarbon (PSH) if present. Depths to water ranged from 15.80
feet below top-of-casing (btoc) in monitoring well MW-3 to 30.47 feet btoc in monitoring well MW-6. The
corresponding groundwater elevations ranged from 880.65 United States survey (US survey) feet in well MW-8 to
882.03 US survey feet in well MW-6. PSH was not detected in the monitoring wells during the January 2023
gauging activities. Historical groundwater gauging data indicate PSH has not been detected in the nine site
monitoring wells. Groundwater gauging data from the most recent event (January 2023) and the historical
groundwater gauging data are provided in Table 3; well construction and location information for the nine
monitoring wells are also summarized. Data from the January 2023 event indicated that, although relatively flat,
the horizontal component of shallow groundwater flow was to the south.A groundwater contour map is included
on Figure 4.
5.2 Groundwater Sampling
Upon completion of gauging activities, groundwater samples were collected for the nine site monitoring wells
between January 24 and 27, 2023, in accordance with the January 2023 sampling plan (Table 4). Groundwater
samples were collected using low flow sampling methodologies in accordance with current United States
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Environmental Protection Agency (USEPA) practices (USEPA 2013). Throughout the sampling process at each
well, temperature, pH, specific conductance, dissolved oxygen (DO), oxygen reduction potential (ORP), and
turbidity measurements were recorded using a calibrated multiparameter water quality meter and turbidity meter.
The field parameters and sampling information were recorded on field sampling logs and are included in
Appendix B. The groundwater samples were collected in pre-preserved laboratory-supplied containers and
immediately placed in a cooler with wet ice following collection. At the completion of sampling activities, the
samples were delivered in properly cooled and sealed containers to Pace Analytical National, a North Carolina
certified laboratory in Mount Juliet, Tennessee under appropriate chain-of-custody procedure. Samples were
analyzed for volatile organic compounds by USEPA Method 6200B and monitored natural attenuation (MNA)
parameters, including nitrate+nitrite nitrogen, nitrate nitrogen, nitrite nitrogen, ammonia nitrogen, total organic
nitrogen, total and ferric iron (+3), sulfate, sulfide, maximum dissolved methane, total organic carbon/biochemical
oxygen/chemical oxygen demand, alkalinity, carbon dioxide, and manganese.
Quality assurance/quality control (QA/QC) samples were collected to provide additional data for evaluating the
quality of the chemical analysis. QA/QC samples included a blind duplicate, a matrix spike/matrix spike duplicate
(MS/MSD), equipment rinsate blank, and a field blank.
The laboratory and data validation reports are included in Appendix C. Analytical data were validated in
accordance with USEPA National Functional Guidelines. Validation provided the means to determine the
reliability of the chemical analysis, the accuracy, and the precision of information acquired by the laboratory.
5.3 Groundwater Analytical Results
Groundwater concentrations exceeding the GCLs were detected in samples collected from four of the nine
monitoring wells during the January 2023 groundwater sampling event. Select groundwater results for the nine
wells are summarized in Table 5 and shown on Figure 5. Historical analytical results between June 2005 and
January 2023 are also summarized in Table 5.
Dissolved-phase benzene concentrations exceeded the GCL of 5,000 µg/L in groundwater samples collected
from monitoring wells MW-2 (12,000 micrograms per liter [µg/L]), MW-7 (7,500 µg/L), MW-8 (19,700 µg/L) and
MW-9 (8,240 µg/L). Dissolved phase 1,2-DCA and EDB concentrations did not exceed the GCL standard of 400
µg/L and 50 µg/L, respectively; however, reporting limits exceeded the GCL standards at wells MW-2, MW-7,
MW-8, and MW-9 due to laboratory sample dilution. The 1,2-DCA concentration reporting limit at well MW-8 was
reported at <2,500 µg/L; however, the method detection limit was reported at <205 µg/L, which is below the GCL.
The EDB reporting limits at wells MW-2, MW-7, and MW-9 were reported at <200 µg/L, <100 µg/L, and <200
µg/L, respectively; however, the method detection limits were reported at <25.2 µg/L, <12.6 µg/L, and <25.2 µg/L,
respectively, which are below the GCL. MTBE exceeded the GCL of 20,000 µg/L in the groundwater sample
collected from well MW-8 (75,800 µg/L). Benzene, 1,2-DCA, and EDB isoconcentration maps are provided on
Figures 6, 7, and 8.
MNA parameters listed in Section 5.2 of this report were required by NCDEQ UST Section guidance (NCDEQ
2022) and were analyzed during this baseline MNA sampling event; the data are summarized in Table 6. Overall,
the results indicate groundwater geochemistry is relatively reducing in areas with elevated VOC concentrations
(i.e., at monitoring wells MW-2, MW-7, MW-8, and MW-9) compared to other areas of the site. A summary of
select MNA results is provided below:
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 Total organic carbon (TOC) was detected above the reporting limit in five of the nine wells sampled, with
concentrations ranging from 1,190 micrograms per liter (µg/L) at MW-3 to 261,000 µg/L at MW-8. TOC
concentrations were generally higher in wells with elevated VOC concentrations.
 Nitrate-nitrogen was detected above the reporting limit in seven of the nine wells sampled, with
concentrations ranging from 271 µg/L at MW-2 (DUP) to 11,300 µg/L at MW-5. Concentrations of
nitrate-nitrogen were generally lower in wells with elevated VOC concentrations.
 Total iron was detected above the reporting limit in the nine wells sampled with concentrations ranging
from 11 µg/L at MW-3 to 21,400 µg/L at MW-8. Ferrous (i.e., dissolved) iron was measured at six of the
nine wells sampled, with concentrations ranging from 50.0 J µg/L at MW-1 to 18,000 µg/L at MW-8.
Concentrations of ferrous iron were generally higher in wells with elevated VOC concentrations.
 Sulfate was detected above the reporting limit in five of the nine wells sampled, with concentrations
ranging from 3,750 J µg/L at MW-9 to 100,000 µg/L at MW-3. Concentrations of sulfate were generally
lower in wells with elevated VOC concentrations.
 Dissolved methane was detected above the reporting limit in four of the nine wells sampled, with
concentrations ranging from 85.7 µg/L at MW-8 to 199 µg/L at MW-2. Methane was only detected in wells
with elevated VOC concentrations.
As summarized above, MNA parameters indicate that groundwater geochemistry is generally reducing in wells
with elevated VOC concentrations. This includes reduced levels of nitrate and sulfate and increased levels of iron
and methane. Based on the results, samples from the nine wells will be collected during future semiannual
groundwater sampling events for the following MNA parameters: TOC, nitrate nitrogen, total iron, ferrous iron,
sulfate, and maximum dissolved methane. The proposed sampling plan is provided in Table 7.
6 Investigative Derived Waste
Purge water generated in January 2023 was containerized and appropriately labeled onsite in a 55-gallon
stainless steel drum. The waste will be transferred to an appropriate disposal facility pending profile sampling.
The waste manifest will be included in the next groundwater report.
7 Conclusion and Recommendations
 During the January 2023 groundwater monitoring event groundwater elevations were gauged and
samples were collected from the nine site monitoring wells.
 Benzene concentrations were detected above the GCL at four monitoring wells (MW-2, MW-7,
MW-8 and MW-9).
 MTBE concentrations were detected above the GCL at monitoring well MW-8.
 Semiannual groundwater monitoring will continue in 2023 (Third quarter) and 2024 and (first quarter); the
results will be provided in subsequent groundwater monitoring reports.
 Arcadis recommends reducing the MNA parameters to include only TOC, nitrate nitrogen, total iron,
ferrous iron, sulfate, and maximum dissolved methane.
Data gathered during the semiannual groundwater monitoring events will be used for the corrective action
plan for the site. A remedial strategy will be proposed once sufficient data can be evaluated.
Groundwater Monitoring Report – First Quarter 2023
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8 References
Arcadis, 2014. Well Installation Report, Former Gulf Oil / Chevron #205513, 500 South Main Street, High Point,
Guilford County, North Carolina. March 2014.
Arcadis 2022. Pre-Corrective Action Plan Groundwater Assessment Report, Former Chevron Facility (Gulf Oil)
#205513, 600 South Main Street (formerly 500 South Main Street), High Point, North Carolina. May 27.
Blasland, Bouck & Lee, Inc. (BBL), 2005. Limited Site Assessment Report, Illoco Mart – High Point B, Former
Chevron Facility 205512, 500 South Main Street, High Point, Guilford County, North Carolina, Groundwater
Incident No. 14873. November.
Brown, et al., 1985. Geologic Map of North Carolina: North Carolina Geological Survey, 1:500,000.
Carpenter, 1982. Geologic Map of Region G (Alamance, Caswell, Davidson, Guilford, Randolph, and Rockingham
counties North Carolina). Regional Geology Series 2. North Carolina Geological Survey.
ENSCI Engineering Group, P.A., 1995. UST Closure Report, Iloco Convenience Store/Gas Station, 500 South
Main Street, High Point, North Carolina. November.
NCDEQ, 2022. UST Guidelines for Monitored Natural Attenuation (MNA). UST Section, North Carolina
Department of Environmental Quality, Division of Waste Management. March 30.
USEPA, 2013. Groundwater Sampling Operating Procedure. U.S. Environmental Protection Agency, Science and
Ecosystem Support Division, Athens, Georgia. March.
USGS, 1997. Groundwater Atlas of the United States, Segment 11, Hydrogeologic Investigations Atlas 730-L.
United States Geological Survey. Reston, Virginia.
Tables
Table 1
UST System Information
Chevron
600 South Main Street
High Point, North Carolina
11 Gasoline Gasoline 6,000 Unknown Unknown Unknown 1971 Removed - 1988 Unknown
21 Gasoline Gasoline 6,000 Unknown Unknown Unknown 1971 Removed - 1988 Unknown
31 Gasoline Gasoline 6,000 Unknown Unknown Unknown 1971 Removed - 1988 Unknown
42 Gasoline Gasoline 1,000 Unknown 4' x 10.5'Unknown Unknown Closed - 1979; Removed - 1995 Unknown
52 Gasoline Gasoline 1,000 Unknown 4' x 10.5'Unknown Unknown Closed - 1979; Removed - 1995 Unknown
62 Gasoline Gasoline 1,000 Unknown 4' x 10.5'Unknown Unknown Closed - 1979; Removed - 1995 Unknown
72 Gasoline Gasoline 1,000 Unknown 4' x 10.5'Unknown Unknown Closed - 1979; Removed - 1995 Unknown
82 Gasoline Gasoline 1,000 Unknown 4' x 10.5'Unknown Unknown Closed - 1979; Removed - 1995 Unknown
9 Waste Oil Waste Oil 560 Unknown 3.5' x 7.67'Unknown Unknown Removed - 1995 Unknown
10 Kerosene Kerosene 560 Unknown 3.5' x 7.67'Unknown Unknown Removed - 1995 Unknown
113 Gasoline Gasoline 6,000 Unknown 8' x 16'Unknown 1988 Removed - 1995 Unknown
123 Gasoline Gasoline 6,000 Unknown 8' x 16'Unknown 1988 Removed - 1995 Unknown
133 Gasoline Gasoline 6,000 Unknown 8' x 16'Unknown 1988 Removed - 1995 Unknown
Notes:
1 - Operated by Gulf Oil Company & Ilderton Oil Company.
2 - Abandoned in place with sand/cement prior to Ilderton Oil Company's purchase of the property in 1979.
3 - Owned and operated solely by Ilderton Oil Company.
4 - UST dimensions obtained from Southern Pump & Tank Company Tank Chart Information.
UST = underground storage tank.
Associated Piping
and Pumps
Description
Date Tank
Installed Status of UST Release associated
with the UST System?
UST ID
Number
Current/Last
Contents
Previous
Contents
Capacity
(gallons)
Construction
Details
Tank
Dimensions4
T1_UST Details 1/1
Table 2
UST Owner/Operator Information
Chevron
600 South Main Street
High Point, North Carolina
UST ID
Number
Name of Owner or
Operator
Dates of
Ownership/Operation
Owner or
Operator?
11, 12, and 13 Ilderton Oil Company 1995 to 1998 owner/operator
UST ID
Number
Name of Owner or
Operator
Dates of
Ownership/Operation
Owner or
Operator?
4, 5, 6, 7, 8, 9,
and 10 Gulf Oil Company unknown owner
UST ID
Number
Name of Owner or
Operator
Dates of
Ownership/Operation
Owner or
Operator?
1, 2, and 3 Ilderton Oil Company 1979 to 1988 owner/operator
UST ID
Number
Name of Owner or
Operator
Dates of
Ownership/Operation
Owner or
Operator?
1, 2, and 3 Gulf Oil Company 1971 to 1979 owner/operator
Note:
UST = underground storage tank
Address:Telephone Number:
(Chevron Environmental Management
Company) 1500 Louisiana Street 38154,
Houston, Texas, 77002
832.854.5667
(Chevron Environmental Management
Company) 1500 Louisiana Street 38154,
Houston, Texas, 77002
832.854.5667
Address:Telephone Number:
Ilderton Oil Company was dissolved in 2012
Address:Telephone Number:
Ilderton Oil Company was dissolved in 2012
Address:Telephone Number:
T2_UST Ownership 1/1
Table 3
Groundwater Monitoring Well Construction and Elevation Data
Chevron
600 South Main Street
High Point, North Carolina
Well ID Latitude /
Longitude
Date
Installed
(mm/dd/yr)
Well
Diameter
(inches)
Total Depth
(feet btoc)
Screened
Interval
(feet btoc)
Top of
Casing
Elevation
(feet msl)
Gauging Date
(mm/dd/yr)
Depth to Water
(feet btoc)
Depth to
Product
(feet btoc)
Free Product
Thickness
(feet)
Corrected
Groundwater
Elevation
(feet msl)
06/14/05 27.85 ND ND 883.07
09/13/05 29.11 ND ND 881.81
09/26/05 29.25 ND ND 881.67
10/11/05 29.30 ND ND 881.62
06/22/10 28.36 ND ND 882.56
02/25/14 29.84 ND ND 881.08
12/14/21 28.48 ND ND 882.44
7/19/2022a --------
01/23/23 29.64 ND ND 881.28
06/14/05 27.44 ND ND 882.64
09/13/05 27.92 ND ND 882.16
09/26/05 28.20 ND ND 881.88
10/11/05 28.30 ND ND 881.78
06/22/10 27.37 ND ND 882.71
02/25/14 28.88 ND ND 881.20
12/14/21 27.45 ND ND 882.63
07/19/22 28.12 ND ND 881.96
01/23/23 28.60 ND ND 881.48
06/14/05 13.90 ND ND 882.89
09/13/05 15.17 ND ND 881.62
09/26/05 15.35 ND ND 881.44
10/11/05 15.40 ND ND 881.39
06/22/10 14.63 ND ND 882.16
02/25/14 16.01 ND ND 880.78
12/14/21 15.09 ND ND 881.70
7/19/2022a --------
01/23/23 15.80 ND ND 880.99
09/13/05 26.30 ND ND 884.27
09/26/05 28.80 ND ND 881.77
10/11/05 28.89 ND ND 881.68
06/22/10 27.97 ND ND 882.60
02/25/14 29.47 ND ND 881.10
12/14/21 28.06 ND ND 882.51
07/20/22 28.76 ND ND 881.81
01/23/23 29.20 ND ND 881.37
MW-1 801926.639 N
1702730.838 S 6/13/2005 2 37.00
896.79
57.70
910.08
22-37 910.92
53-58
25.00
6/13/2005 2 37.00 22-37
10-256/14/2005 2
9/13/2005 910.57
58.00
6
MW-2
MW-4D 802074.968 N
1702747.309 E
802078.392 N
1702745.238 E
MW-3 802079.517 N
1702402.193 E
T3_Well Construction & GW Elev 1/2
Table 3
Groundwater Monitoring Well Construction and Elevation Data
Chevron
600 South Main Street
High Point, North Carolina
Well ID Latitude /
Longitude
Date
Installed
(mm/dd/yr)
Well
Diameter
(inches)
Total Depth
(feet btoc)
Screened
Interval
(feet btoc)
Top of
Casing
Elevation
(feet msl)
Gauging Date
(mm/dd/yr)
Depth to Water
(feet btoc)
Depth to
Product
(feet btoc)
Free Product
Thickness
(feet)
Corrected
Groundwater
Elevation
(feet msl)
09/13/05 26.94 ND ND 882.24
09/26/05 27.12 ND ND 882.06
10/11/05 27.22 ND ND 881.96
06/22/10 26.32 ND ND 882.86
02/25/14 27.80 ND ND 881.38
12/14/21 26.53 ND ND 882.65
7/19/2022a --------
01/23/23 27.56 ND ND 881.62
09/13/05 29.96 ND ND 882.54
09/26/05 29.60 ND ND 882.90
10/11/05 30.18 ND ND 882.32
06/22/10 29.31 ND ND 883.19
02/25/14 30.83 ND ND 881.67
12/14/21 29.16 ND ND 883.34
07/20/22 29.90 ND ND 882.60
01/23/23 30.47 ND ND 882.03
02/25/14 29.76 ND ND 880.49
12/14/21 28.33 ND ND 881.92
07/19/22 29.02 ND ND 881.23
01/23/23 29.51 ND ND 880.74
02/25/14 29.39 ND ND 880.38
12/14/21 27.98 ND ND 881.79
07/20/22 28.65 ND ND 881.12
01/23/23 29.12 ND ND 880.65
02/25/14 29.43 ND ND 880.41
12/14/21 28.04 ND ND 881.80
07/20/22 28.72 ND ND 881.12
01/23/23 29.17 ND ND 880.67
Notes:
btoc = below top of well casing
msl = mean sea level
ND = not detected
mm/dd/yr = month/day/year
a = Groundwater gauging data collected from wells MW-1, MW-3, and MW-5 in July 2022 were inadvertantly lost because of damaged equipment.
40.00 25-40 909.18
40.01
37.28
40.00
MW-7
2/24/2014 2 22-37
802054.562 N
1702760.910 E 2/24/2014 2 22-37
37.10
MW-8 802045.978 N
1702724.309 E
37.00
MW-9 802063.491 N
1702710.205 E 2/24/2014 2
37.40
22-37 909.84
37.00
37.00
909.77
910.25
912.509/14/2005 2 25-40
9/13/2005 2
MW-6 802198.116 N
1702897.303 E
MW-5 802152.810 N
1702634.365 E
T3_Well Construction & GW Elev 2/2
Table 4
January 2023 Sampling Analysis Plan
Chevron
600 South Main Street
High Point, North Carolina
Well ID Date Installed
(mm/dd/year)
Total Depth
(feet btoc)
Screened
Interval
(feet btoc)
EPA Method
6200B
Field/MNA
Parameters1, 2
MW-1 6/13/2005 37.00 22-37 X X
MW-2 6/13/2005 37.00 22-37 X X
MW-3 6/14/2005 25.00 10-25 X X
MW-4D 9/13/2005 58.00 53-58 X X
MW-5 9/13/2005 40.00 25-40 X X
MW-6 9/14/2005 40.00 25-40 X X
MW-7 2/24/2014 37.00 22-37 X X
MW-8 2/24/2014 37.00 22-37 X X
MW-9 2/24/2014 37.00 22-37 X X
Notes:
btoc = below top of well casing.
DO = dissolved oxygen.
EPA = environmental protection agency.
mS/cm = millisiemens per centimeter.
NA = not applicable.
ND = not detected.
ORP = oxidation reduction potential.
TOC/BOD/COD = total organic carbon/biochemical oxygen demand/chemical oxygen demand
mm/dd/yr = month/day/year.
1Field parameters = pH, specific conductance (mS/cm), temperature, DO, ORP, and turbidity.
2Monitoried Natural Attenuation (MNA) parameters = nitrate + nitrite nitrogen, nitrate nitrogen, nitrite
nitrogen, ammonia nitrogen, total organic nitrogen, total and ferric iron (+3), sulfate, sulfide, maximum
dissolved methane, TOC/BOD/COD, alkalinity, carbon dioxide, and manganese.
T4_Jan2023SAP 1/1
Table 5
Groundwater Analytical Results
Chevron
600 South Main Street
High Point, North Carolina
5,000 260,000 84,500 85,500 25,000 6,000 30,000 20,000 28,500 25,000 70,000 400 600 50
06/14/05 1.3 3.0 NA NA NA < 1.0 NA NA < 1.0 < 1.00 < 1.00 NA
06/22/10 2.3 < 0.70 < 0.50 < 1.6 NA NA NA < 0.74 NA NA < 0.50 < 0.50 < 0.50 NA
02/25/14 < 5.0 < 1.0 < 1.0 < 5.0 NA NA NA < 1.0 NA NA < 1.0 < 1.0 < 1.0 < 0.019
12/15/21 < 1.0 < 1.0 < 1.0 < 2.0 < 1.0 < 5.0 < 1.0 U 0.645 J < 1.0 < 1.0 < 1.0 0.238 J < 1.0 < 1.0
07/18/22 < 1.00 < 1.00 < 1.00 < 3.00 < 1.00 < 5.00 < 1.00 0.904 J < 1.00 < 1.00 0.105 J < 1.00 < 1.00 < 1.00
DUP 07/18/22 < 1.00 < 1.00 < 1.00 < 3.00 < 1.00 < 5.00 < 1.00 0.875 J < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00
01/24/23 15.7 8.04 3.26 16.4 0.114 J < 5.00 0.236 J 2.49 1.59 0.407 J <1.00 < 1.00 < 1.00 0.130 J
06/14/05 9,840 2,540 2,500 NA NA NA 475 NA NA 90.0 414 4.70 NA
06/22/10 12,000 770 1,400 2,000 NA NA NA 3,200 NA NA 59 520 < 50 NA
02/25/14 16,000 550 3,100 2,800 120 800 270 6,100 860 200 < 100 250 < 100 1.4
12/14/21 11,700 D 475 J 2,730 3,285 104 J 665 235 J 5,620 1,400 336 J 52.5 J 121 J < 50 UJ < 50 UJ
07/19/22 9,280 204 1,560 1,217 J 50.6 J 313 J 149 J 6,510 735 186 J 38.5 J 147 J < 200 < 200
01/25/23 12,000 291 2,650 1,896 J 84.1 J 499 J 219 5,800 927 230 44.8 J < 200 < 200 < 200
DUP 01/25/23 11,600 270 2,620 1,777.7 J 85.8 J 543 216 5,710 949 231 42.1 J < 100 < 100 < 100
06/14/05 < 1.0 < 1.0 < 1.0 < 3.0 NA NA NA < 1.0 NA NA < 1.0 < 1.00 < 1.00 NA
06/22/10 < 0.30 < 0.70 < 0.50 < 1.6 NA NA NA < 0.74 NA NA < 0.50 < 0.50 < 0.50 NA
02/25/14 < 1.0 < 1.0 < 1.0 < 5.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 0.020
12/15/21 < 1.0 < 1.0 < 1.0 < 2.0 < 1.0 < 5.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0
07/18/22 < 1.00 < 1.00 < 1.00 < 3.00 < 1.00 < 5.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 <1.00 <1.00
01/26/23 0.609 J < 1.00 0.244 J 0.174 J < 1.00 < 5.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00
10/11/05 < 1.00 < 1.00 < 1.00 < 2.00 NA NA NA < 1.00 NA NA < 1.00 6.03 < 1.00 NA
06/22/10 < 0.30 < 0.70 < 0.50 < 1.6 NA NA NA < 0.74 NA NA < 0.50 2.8 < 0.50 NA
02/25/14 1.1 < 1.0 < 1.0 < 5.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 0.019
12/14/21 0.367 J < 1.0 < 1.0 < 2.0 < 1.0 < 5.0 < 1.0 6.04 < 1.0 < 1.0 0.804 J 0.584 J < 1.0 < 1.0
07/20/22 < 1.00 < 1.00 < 1.00 < 3.00 < 1.00 < 5.00 < 1.00 12.6 < 1.00 < 1.00 1.64 1.19 <1.00 <1.00
01/26/23 2.82 < 1.00 0.874 J 1.159 J < 1.00 < 5.00 < 1.00 7.21 0.322 J < 1.00 0.523 J < 1.00 < 1.00 < 1.00
10/11/05 < 1.00 < 1.00 < 1.00 < 2.00 NA NA NA < 1.00 NA NA < 1.00 < 1.00 < 1.00 NA
06/22/10 < 0.30 < 0.70 < 0.50 < 1.6 NA NA NA < 0.74 NA NA < 0.50 < 0.50 < 0.50 NA
02/25/14 < 1.0 < 1.0 < 1.0 < 5.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 0.019
12/15/21 < 1.0 < 1.0 < 1.0 < 2.0 < 1.0 < 5.0 < 1.0 0.149 J < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0
07/19/22 < 1.00 < 1.00 < 1.00 < 3.00 < 1.00 < 5.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 <1.00 <1.00
01/27/23 3.14 0.549 J 2.80 3.291 J 0.150 J < 5.00 0.335 J 0.131 J 0.889 J 0.308 J < 1.00 < 1.00 < 1.00 < 1.00
10/11/05 < 1.00 < 1.00 < 1.00 < 2.00 NA NA NA < 1.00 NA NA < 1.0 < 1.00 < 1.00 NA
06/23/10 < 0.30 < 0.70 < 0.50 < 1.6 NA NA NA < 0.74 NA NA < 0.50 < 0.50 < 0.50 NAMW-6
MW-5
MW-4D
MW-3
MW-2
GCL (µg/L)Isopropyl etherIsopropylbenzeneNaphthalenen-PropylbenzeneMethyl tert-butyl etherWell Date Collected
(mm/dd/yr)
Volatile Organic Compounds (VOCs) by EPA 625 & SM 6200B
MW-1 Benzene TolueneEthylbenzeneTotal Xylenes1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene1,2-Dichloroethane1,2-DichloropropaneEthylene dibromide (EDB)T5_GW Analytical 1/2
Table 5
Groundwater Analytical Results
Chevron
600 South Main Street
High Point, North Carolina
5,000 260,000 84,500 85,500 25,000 6,000 30,000 20,000 28,500 25,000 70,000 400 600 50GCL (µg/L)Isopropyl etherIsopropylbenzeneNaphthalenen-PropylbenzeneMethyl tert-butyl etherWell Date Collected
(mm/dd/yr)
Volatile Organic Compounds (VOCs) by EPA 625 & SM 6200B
Benzene TolueneEthylbenzeneTotal Xylenes1,2,4-Trimethylbenzene1,3,5-Trimethylbenzene1,2-Dichloroethane1,2-DichloropropaneEthylene dibromide (EDB)02/25/14 < 1.0 < 1.0 < 1.0 < 5.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 <1.0 < 0.019
12/15/21 < 1.0 < 1.0 < 1.0 < 2.0 < 1.0 < 5.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0 < 1.0
07/20/22 < 1.00 < 1.00 < 1.00 < 3.00 < 1.00 < 5.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 < 1.00 <1.00 <1.00
01/27/23 6.90 0.470 J 3.52 2.529 J 0.155 J < 5.00 0.374 J 0.255 J 0.635 J 0.232 J < 1.00 < 1.00 < 1.00 <1.00
02/25/14 9,400 77 820 < 250 82 420 73 2,500 < 50 < 50 52 < 50 < 50 0.84
12/14/21 7,980 D 198 D 2160 D 2,800 D 95.4 636 D 180 D 3,960 D 1090 D 328 D 44.2 93.4 < 1 11.4
07/19/22 5,930 53.8 1,300 823 56.1 302 130 3,310 427 161 32.4 J 120 <50.0 <50.0
07/19/22 5,930 53.8 1,300 823 56.1 302 130 3,310 427 161 32.4 J 120 <50.0 <50.0
01/26/23 7,500 94.2 J 2,230 1,242 79.3 J 235 J 167 3,160 407 177 31.6 J 102 < 100 < 100
02/26/14 22,000 3,200 2,400 8,100 NA NA NA 36,000 NA NA NA 2,000 < 200 210
12/16/21 2,730 D 96.9 D 974 D 476.6 D 62.6 185 D 126 D 7,400 D 200 D 73.2 12.5 18 < 1 < 1.0
07/20/22 23,800 12,100 J 1,820 9,120 71.4 342 199 <25.0 1,310 335 315 1,240 <25.0 222
01/24/23 19,700 3,960 1,930 J 9,110 < 2,500 < 12,500 < 2,500 75,800 1,130 J 284 J < 2,500 < 2,500 < 2,500 < 2,500
02/26/14 9,800 3,800 3,400 9,300 NA NA NA 9,000 NA NA NA 330 < 50 8.7
12/15/21 19,700 15,400 2,100 7,280 90 J 432 J 187 J 88,200 D 1,260 311 242 J 742 < 250 193 J
07/20/22 4,250 <1,000 1,000 J <3,000 <1,000 1,240 J <1,000 6,950 <1,000 <1,000 <1,000 <1,000 <1,000 <1,000
01/27/23 8,240 86.4 J 2,960 561 J 142 J 251 J 370 11,300 417 140 J < 200 47.7 J < 200 < 200
Notes:
Results reported in micrograms per liter (µg/L).
GCL = Gross Contamination Levels for Groundwater.
D = Concentration is based on a diluted sample analysis.
DNE = Does not exist.
< = Not detected at or above indicated laboratory reporting limit
J = The compound was positively identified; however, the associated numerical value is an estimated concentration only.
NA = Not analyzed / not available.
Bold analytical values indicate concentration exceeds the applicable GCL.
DUP = Duplicate Sample Result
mm/dd/yr = month/day/year.
MW-9
MW-8
MW-7
MW-6
continued
T5_GW Analytical 2/2
Table 6
MNA Parameter Analytical Results
Chevron
600 South Main Street
High Point, North Carolina
MW-1 01/24/23 1,740 J <250 55,300 114,000 J <250 50.0 J <250 1,520 <20,000 R <1.00 1,240 <100 <5,000 UB <1,000 UB 1,790 47.4 <10.0
MW-2 01/25/23 <100 UJ 208 J 306,000 41,800 UB J <250 11,100 J 208 J <500 255,000 R 6,910 J <100 <100 <5,000 49,900 11,100 12,400 199
DUP 01/25/23 <100 UJ 204 J 309,000 78,900 J <250 11,700 J 204 J <500 259,000 R 12,100 J 271 <100 <5,000 50,500 11,200 12,800 184
MW-3 01/26/23 452 J <250 98,100 61,100 J <250 34.0 J <250 3,330 <20,000 R <2,000 UJ 3,420 <100 100,000 1,190 486 11.0 <10.0
MW-4D 01/26/23 38.6 J <250 71,500 64,400 J <250 <50.0 UJ <250 2,760 <20,000 R 2,940 J 4,670 85.4 12,300 <1,000 UB 38.6 J 473 <10.0
MW-5 01/27/23 2,860 J <250 11,600 J 72,500 J <250 <50.0 UJ <250 UJ 11,600 <20,000 R <2,000 UJ 11,300 <100 12,400 <1,000 UB 2,860 56.7 <10.0
MW-6 01/27/23 351 J <250 <20,000 <20,000 UJ <250 <50.0 UJ <250 UJ 1,180 <20,000 R <2,000 UJ 1,240 <100 19,100 <1,000 UB 351 16.7 <10.0
MW-7 01/26/23 <100 UJ <250 241,000 144,000 J <250 5,420 J <250 <100 101,000 R 14,100 J <100 <100 <5,000 13,700 4,970 16,200 205
MW-8 01/24/23 <100 UJ 266 233,000 112,000 J <250 18,000 J 266 <100 980,000 R 110,000 <100 <100 <5,000 UB 261,000 17,200 21,400 85.7
MW-9 01/27/23 <100 UJ <250 226,000 62,500 J <250 5,770 J <250 UJ <100 122,000 R 9,980 J 2,010 <100 3,750 J 19,200 5,770 5,480 97.1
Notes:
Results reported in micrograms per liter (µg/L).
GCL = Gross Contamination Levels for Groundwater.
D = Concentration is based on a diluted sample analysis.
< = Not detected at or above indicated laboratory reporting limit
J = The compound was positively identified; however, the associated numerical value is an estimated concentration only.
B = The compound has been found in the sample as well as its associated blank, its presence in the sample may be suspect.
R = The sample results are rejected. The associated value is unusable due to significant quality control problems. The analysis provides no information as to whether the compound is present or not.
UB = Compound considered non-detect at the listed value due to associated blank contamination.
UJ = The compound was not detected above the reported sample quantitation limit. However, thereported limit is approximate and may or may not represent the actual limit of quantitation
NA = Not analyzed / not available.
Bold analytical values indicate concentration exceeds the applicable GCL.
DUP = Duplicate Sample Result
mm/dd/yr = month/day/year.
Well
Ferric
Iron
Organic
Nitrogen NitriteNitrogenNitrate-
Nitrite COD Sulfide BOD Nitrate
Date
Collected
(mm/dd/yr)
Calculated
Results
Wet Chemistry by
Method 2320
B-2011/4500CO2
D-2011
Wet
Chemistry
by Method
350.1
Alkalinity MethaneSulfateTOCIron
Wet
Chemistry
by Method
353.2
Metals by EPA
6010 D
Wet
Chemistry
by Method
410.4
Wet
Chemistry
by Method
9060A
Volatile
Organic
Compounds
by Method
RSK175
Free
Carbon
Dioxide
Ammonia
Nitrogen
Ferrous
Iron
Manganes
e
Wet
Chemistry
by Method
4500S2
D-2011
Wet
Chemistry
by Method
5210
B-2016
Wet
Chemistry
by Method
3500Fe
B-2011
Wet Chemistry by
Method 9056A
Wet
Chemistry
by Method
351.2
T6_GW_MNA_Analytical 1/1
Table 7
Proposed Sampling Analysis Plan
Chevron
600 South Main Street
High Point, North Carolina
Well ID Date Installed
(mm/dd/year)
Total Depth
(feet btoc)
Screened
Interval
(feet btoc)
EPA Method
6200B
Field/MNA
Parameters1, 2
MW-1 6/13/2005 37.00 22-37 X X
MW-2 6/13/2005 37.00 22-37 X X
MW-3 6/14/2005 25.00 10-25 X X
MW-4D 9/13/2005 58.00 53-58 X X
MW-5 9/13/2005 40.00 25-40 X X
MW-6 9/14/2005 40.00 25-40 X X
MW-7 2/24/2014 37.00 22-37 X X
MW-8 2/24/2014 37.00 22-37 X X
MW-9 2/24/2014 37.00 22-37 X X
Notes:
btoc = below top of well casing.
DO = dissolved oxygen.
EPA = environmental protection agency.
mS/cm = millisiemens per centimeter.
NA = not applicable.
ND = not detected.
ORP = oxidation reduction potential.
mm/dd/yr = month/day/year.
1Field parameters = pH, specific conductance (mS/cm), temperature, DO, ORP, and turbidity.
2Monitoried Natural Attenuation (MNA) parameters = total organic carbon, nitrate-nitrogen, total iron,
ferrous iron, sulfate, and dissolved methane.
T7_ProposedSAP 1/1
Figures
NORTH CAROLINA
SITE LOCATION MAP
1C:\Users\ari00071\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2022\01-In Progress\01-DWG\GEN-F01-SLM.dwg LAYOUT: 1 SAVED: 5/19/2022 11:36 PM ACADVER: 24.1S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: ARCADIS.CTB PLOTTED: 10/18/2022 9:25PM BY: R, ANITAHIGH POINT
SITE
LOCATION
REFERENCE: BASE MAP USGS 7.5. MIN. TOPO. QUAD., HIGH POINT EAST AND HIGH POINT WEST, NORTH CAROLINA, 2019.
Approximate Scale: 1 in. = 2000 ft.
0 2000'4000'
FIGURE
CHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
SCHOOL
DAYCARE
PARK/
RECREATION
CENTER 1,500 FTSITE
SOUTH MAIN ST.TAYLOR AVE.S. ELM ST.LAND USE MAP
IMAGES: Arcadis Logo_2021.PNGXREFS:PROJECTNAME: ----IMAGE: BING MAPS
C:\Users\jlharris\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2022\01-In Progress\01-DWG\GEN-F02-LAND USE.dwg LAYOUT: 2 SAVED: 2/9/2022 5:24 PM ACADVER: 24.1S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: PLTFULL.CTB PLOTTED: 5/19/202211:00 AM BY: HARRIS, JESSCHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
2
FIGURE
0
GRAPHIC SCALE
500'1000'
ZAKI ORIENTAL RUGS
W. GRI
M
E
S

A
V
E
N
U
E
60' R/W
BRICK BUILDING
S. ELM STREET68' R/WTAYLOR AVE
N
U
E
VARIABLE WI
D
T
H

R
/
W S. MAIN STREET100' R/W
MW-3
MW-5
MW-6
MW-1
MW-8
MW-9
MW-2
MW-7
MW-4D
470 S MAIN STREET
465 S MAIN STREET
IMAGES: Arcadis Logo_2021.PNG GEN-X-IMAGE1.jpgXREFS:PROJECTNAME: ----SOURCE: Base map digitized from 'WELL LOCATION SURVEY' provided by 'Taylor Wiseman & Taylor',
4101-F Stuart Andrew Blvd., Charlotte, NC. [phone], map date June 30, 2005, map scale 1"=50'.
Wells surveyed by Taylor Wiseman & Taylor 11/23/2021. Aerial image from Google Earth Pro.C:\Users\ari00071\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2022\01-In Progress\01-DWG\GWM-3Q22-F02-SITE PLAN_1.dwg LAYOUT: 2 SAVED: 10/18/2022 11:16 PM ACADVER: 24.2S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: PLTFULL.CTB PLOTTED:10/19/2022 10:27 AM BY: R, ANITACHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
0
GRAPHIC SCALE
100'200'
PROPERTY LINE
SHALLOW MONITORING WELL
DEEP MONITORING WELL
LEGEND
SITE MAP
FIGURE3
ZAKI ORIENTAL RUGS
W. GRI
M
E
S

A
V
E
N
U
E
60' R/W
BRICK BUILDING
S. ELM STREET68' R/W
TAYLOR AVE
N
U
E
VARIABLE WI
D
T
H

R
/
W S. MAIN STREET100' R/W
MW-3
(880.99)
MW-5(881.62)
MW-6(882.03)
MW-1(881.28)*
MW-8(880.65)
MW-9(880.67)
MW-2
(881.48)
MW-7(880.74)
MW-4D
(881.37)
882.00
882.
0
0
881.50
881
.
5
0
881.00 881.00
IMAGES: Arcadis Logo_2021.PNG GEN-X-IMAGE1.jpgXREFS:PROJECTNAME: ----SOURCE: Base map digitized from 'WELL LOCATION SURVEY' provided by 'Taylor Wiseman & Taylor',
4101-F Stuart Andrew Blvd., Charlotte, NC. [phone], map date June 30, 2005, map scale 1"=50'.
Wells surveyed by Taylor Wiseman & Taylor 11/23/2021. Aerial image from Google Earth Pro.C:\Users\ari00071\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2023\01-In Progress\01-DWG\GWM-2023Q1-F04-GWE.dwg LAYOUT: 4 SAVED: 3/6/2023 3:58 PM ACADVER: 24.2S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: PLTFULL.CTB PLOTTED: 3/7/20233:35 PM BY: R, ANITACHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
4
FIGURE
0
GRAPHIC SCALE
100'200'
PROPERTY LINE
SHALLOW MONITORING WELL
DEEP MONITORING WELL
GROUNDWATER ELEVATION (FEET)
POTENTIOMETRIC SURFACE CONTOUR
(FEET)
GROUNDWATER FLOW DIRECTION
WELL NOT USED FOR CONTOURING
LEGEND
GROUNDWATER CONTOUR MAP
JANUARY 23, 2023
(882.03)
882.00
*
ZAKI ORIENTAL RUGS
W. GRI
M
E
S

A
V
E
N
U
E
60' R/W
BRICK BUILDING
S. ELM STREET68' R/WTAYLOR AVE
N
U
E
VARIABLE WI
D
T
H

R
/
W S. MAIN STREET100' R/W
MW-3
MW-5
MW-6
MW-1
MW-8
MW-9
MW-2
MW-7
MW-4D
IMAGES: Arcadis Logo_2021.PNG GEN-X-IMAGE1.jpgXREFS:PROJECTNAME: ----SOURCE: Base map digitized from 'WELL LOCATION SURVEY' provided by 'Taylor Wiseman & Taylor',
4101-F Stuart Andrew Blvd., Charlotte, NC. [phone], map date June 30, 2005, map scale 1"=50'.
Wells surveyed by Taylor Wiseman & Taylor 11/23/2021. Aerial image from Google Earth Pro.C:\Users\ari00071\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2023\01-In Progress\01-DWG\GWM-2023Q1-F05-GWA.dwg LAYOUT: 5 SAVED: 3/9/2023 1:01 PM ACADVER: 24.2S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: PLTFULL.CTB PLOTTED: 3/9/20231:02 PM BY: R, ANITACHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
5
FIGURE
0
GRAPHIC SCALE
100'200'
PROPERTY LINE
SHALLOW MONITORING WELL
DEEP MONITORING WELL
GROSS CONTAMINATION LEVELS FOR
GROUNDWATER.
THE COMPOUND WAS POSITIVELY
IDENTIFIED; HOWEVER, THE ASSOCIATED
NUMERICAL VALUE IS AN ESTIMATED
CONCENTRATION ONLY
BOLD VALUES INDICATE CONCENTRATION
EXCEEDS THE APPLICABLE GCL.
DUPLICATE SAMPLE RESULT
METHYL TERT-BUTYL ETHER
NOT DETECTED AT OR ABOVE THE
REPORTED DETECTION LIMIT (RDL)
LEGEND
GROUNDWATER ANALYTICAL MAP
JANUARY 24 - 27, 2023
GCLs
MW-1
Date 1/24/2023
Benzene 15.7
Toluene 8.04
Ethylbenzene 3.26
Xylenes (Total)16.4
MTBE 2.49
1,2-DCA <1.00
EDB 0.130 J
MW-2
Date 1/25/2023
Benzene 12,000 [11,600]
Toluene 291 [270]
Ethylbenzene 2,650 [2,620]
Xylenes (Total)1,896 J [1,7777.7 J]
MTBE 5,800 [5,710]
1,2-DCA <200 [<100]
EDB <200 [<100]
MW-3
Date 1/26/2023
Benzene 0.609 J
Toluene <1.00
Ethylbenzene 0.244 J
Xylenes (Total)0.174 J
MTBE <1.00
1,2-DCA <1.00
EDB <1.00
MW-4D
Date 1/26/2023
Benzene 2.82
Toluene <1.00
Ethylbenzene 0.874 J
Xylenes (Total)1.159 J
MTBE 7.21
1,2-DCA <1.00
EDB <1.00
MW-5
Date 1/27/2023
Benzene 3.14
Toluene 0.549 J
Ethylbenzene 2.80
Xylenes (Total)3.291 J
MTBE 0.131 J
1,2-DCA <1.00
EDB <1.00
MW-6
Date 1/27/2023
Benzene 6.90
Toluene 0.470 J
Ethylbenzene 3.52
Xylenes (Total)2.529 J
MTBE 0.255 J
1,2-DCA <1.00
EDB <1.00
MW-7
Date 1/26/2023
Benzene 7,500
Toluene 94.2 J
Ethylbenzene 2,230
Xylenes (Total)1,242
MTBE 3,160
1,2-DCA 102
EDB <100
MW-8
Date 1/24/2023
Benzene 19,700
Toluene 3,960
Ethylbenzene 1,930 J
Xylenes (Total)9,110
MTBE 75,800
1,2-DCA <2,500
EDB <2,500
J
BOLD
[ ]
MTBE
NOTE:
1.RESULTS REPORTED IN MICROGRAMS PER LITER (µg/L).
MW-9
Date 1/27/2023
Benzene 8,240
Toluene 86.4 J
Ethylbenzene 2,960
Xylenes (Total)561 J
MTBE 11,300
1,2-DCA 47.7 J
EDB <200
1,2-DICHLOROETHANE
ETHYLENE DIBROMIDEEDB
1,2-DCA
Analytes GCL (ug/l)
Benzene 5,000
Toluene 260,000
Ethylbenzene 84,500
Xylenes (Total)85,500
MTBE 20,000
1,2-DCA 400
EDB 50
<1.00
ZAKI ORIENTAL RUGS
W. GRI
M
E
S

A
V
E
N
U
E
60' R/W
BRICK BUILDING
S. ELM STREET68' R/W
TAYLOR AVE
N
U
E
VARIABLE WI
D
T
H

R
/
W S. MAIN STREET100' R/W
MW-3
0.609 J
MW-53.14
MW-66.90
MW-1
15.7 5,000500MW-2
12,000 [11,600]
MW-8
19,700
MW-77,500
MW-9
8,240
MW-4D
2.82*10,000IMAGES: Arcadis Logo_2021.PNG GEN-X-IMAGE1.jpgXREFS:PROJECTNAME: ----C:\Users\ari00071\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2023\01-In Progress\01-DWG\GWM-2023Q1-F06-BENZENE.dwg LAYOUT: 6 SAVED: 3/9/2023 1:00 PM ACADVER: 24.2S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: PLTFULL.CTB PLOTTED:3/9/2023 1:07 PM BY: R, ANITACHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
6
FIGURE
0
GRAPHIC SCALE
100'200'
SOURCE: Base map digitized from 'WELL LOCATION SURVEY' provided by 'Taylor Wiseman & Taylor',
4101-F Stuart Andrew Blvd., Charlotte, NC. [phone], map date June 30, 2005, map scale 1"=50'.
Wells surveyed by Taylor Wiseman & Taylor 11/23/2021. Aerial image from Google Earth Pro.
1.RESULTS REPORTED IN MICROGRAMS PER LITER (µg/L).
2.GROUNDWATER SAMPLES COLLECTED JANUARY 24-27, 2023.
3.GROSS CONTAMINANT LEVEL FOR BENZENE IS 5,000 μg/L.
PROPERTY LINE
SHALLOW MONITORING WELL
DEEP MONITORING WELL
BENZENE CONCENTRATION (µg/L)
BENZENE CONCENTRATION CONTOUR
(µg/L, DASHED WHERE INFERRED)
THE COMPOUND WAS POSITIVELYIDENTIFIED; HOWEVER, THE ASSOCIATED
NUMERICAL VALUE IS AN ESTIMATED
CONCENTRATION ONLY
DUPLICATE SAMPLES
WELL NOT USED FOR CONTOURING
LEGEND NOTES:
BENZENE ISOCONCENTRATION
CONTOUR MAP
7,500
500
*
[ ]
J
ZAKI ORIENTAL RUGS
W. GRI
M
E
S

A
V
E
N
U
E
60' R/W
BRICK BUILDING
S. ELM STREET68' R/W
TAYLOR AVE
N
U
E
VARIABLE WI
D
T
H

R
/
W S. MAIN STREET100' R/W
MW-3
<1.00
MW-5<1.00
MW-6<1.00
MW-1
<1.00
40
MW-2
<200 [<100]
MW-8<2,500
MW-7102
MW-9
47.7 J
MW-4D
<1.00
IMAGES: Arcadis Logo_2021.PNG GEN-X-IMAGE1.jpgXREFS:PROJECTNAME: ----C:\Users\ari00071\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2023\01-In Progress\01-DWG\GWM-2023Q1-F07-12DCA.dwg LAYOUT: 7 SAVED: 3/9/2023 1:08 PM ACADVER: 24.2S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: PLTFULL.CTB PLOTTED:3/9/2023 1:08 PM BY: R, ANITACHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
7
FIGURE
0
GRAPHIC SCALE
100'200'
1,2-DCA ISOCONCENTRATION
CONTOUR MAP
1.RESULTS REPORTED IN MICROGRAMS PER LITER (µg/L).
2.GROUNDWATER SAMPLES COLLECTED JANUARY 24-27, 2023.
3.GROSS CONTAMINANT LEVEL FOR 1,2-DCA IS 400 μg/L.
PROPERTY LINE
SHALLOW MONITORING WELL
DEEP MONITORING WELL
1,2-DCA CONCENTRATION (µg/L)
1,2-DCA CONCENTRATION CONTOUR
(µg/L, DASHED WHERE INFERRED)
1,2-DICHLOROETHANE
THE COMPOUND WAS POSITIVELY IDENTIFIED;
HOWEVER, THE ASSOCIATED NUMERICAL VALUE
IS AN ESTIMATED CONCENTRATION ONLY
LESS THAN REPORTING LIMIT SHOWN
DUPLICATE SAMPLES
LEGEND
NOTES:
102
40
1,2-DCA
SOURCE: Base map digitized from 'WELL LOCATION SURVEY' provided by 'Taylor Wiseman & Taylor',
4101-F Stuart Andrew Blvd., Charlotte, NC. [phone], map date June 30, 2005, map scale 1"=50'.
Wells surveyed by Taylor Wiseman & Taylor 11/23/2021. Aerial image from Google Earth Pro.
[ ]
J
<1.00
ZAKI ORIENTAL RUGS
W. GRI
M
E
S

A
V
E
N
U
E
60' R/W
BRICK BUILDING
S. ELM STREET68' R/WTAYLOR AVE
N
U
E
VARIABLE WI
D
T
H

R
/
W S. MAIN STREET100' R/W
MW-3
<1.00
MW-5<1.00
MW-6<1.00
MW-10.130 J
MW-2
<200 [<100]
MW-7<100
MW-4D<1.00
MW-8
<2,500
MW-9
<200
IMAGES: Arcadis Logo_2021.PNG GEN-X-IMAGE1.jpgXREFS:PROJECTNAME: ----C:\Users\ari00071\ACCDocs\Arcadis\AUS-CHEVRON-205513-HIGH POINT North Carolina\Project Files\2023\01-In Progress\01-DWG\GWM-2023Q1-F08-EDB.dwg LAYOUT: 8 SAVED: 3/9/2023 1:09 PM ACADVER: 24.2S (LMS TECH) PAGESETUP: ---- PLOTSTYLETABLE: PLTFULL.CTB PLOTTED: 3/9/20231:09 PM BY: R, ANITACHEVRON FACILITY #205513
600 SOUTH MAIN STREET
HIGH POINT, NORTH CAROLINA
8
FIGURE
0
GRAPHIC SCALE
100'200'
EDB CONCENTRATION MAP
SOURCE: Base map digitized from 'WELL LOCATION SURVEY' provided by 'Taylor Wiseman & Taylor',
4101-F Stuart Andrew Blvd., Charlotte, NC. [phone], map date June 30, 2005, map scale 1"=50'.
Wells surveyed by Taylor Wiseman & Taylor 11/23/2021. Aerial image from Google Earth Pro.
1.RESULTS REPORTED IN MICROGRAMS PER LITER (µg/L).
2.GROUNDWATER SAMPLES COLLECTED JANUARY 24-27, 2023.
3.GROSS CONTAMINANT LEVEL FOR EDB IS 50 μg/L.
PROPERTY LINE
SHALLOW MONITORING WELL
DEEP MONITORING WELL
ETHYLENE DIBROMIDE
LESS THAN REPORTING LIMIT SHOWN
LEGEND NOTES:
EDB
<
Appendix A
Regulatory Correspondence

North Carolina Department of Environmental Quality | Division of Waste Management
Guilford County Environmental Health | 400 West Market Street | Suite 300 |
Greensboro, NC 27401 | [phone]

February 6, 2023

Chevron Products Company
Attn: Christine Lametrie
1400 Smith Street
Houston, TX 77022-7327

Re: Acknowledgement of Report Receipt
Iloco Mart – High Point – B
500 S. Main Street
High Point, Guilford County
Incident Number: 14873
Risk Classification: Intermediate
Ranking: I140D
Dear Ms. Lametrie:
The UST Section, Division of Waste Management, is in receipt of the report dated January 26, 2023. The
report has been reviewed and will maintained in the Guilford County Department of Health and Human
Services Office. The next semi-annual groundwater monitoring event is to be completed in the first quarter
of 2023 with a report summarizing the findings due by March 31, 2023.
If you have questions regarding the information contained in this letter, please contact Jordan Lerew at
the Guilford County Department of Health and Human Services, 400 W. Market Street, Suite 300,
Greensboro, NC 27401 or [phone].

Sincerely,

James W. Brown
Regional Supervisor
Winston-Salem Regional Office
UST Section, Division of Waste Management, NCDEQ

cc: Sherrie Lang, Arcadis US, Inc., [e-mail]
Appendix B
Groundwater Sampling Field Logs
Well ID Date Static Water Level
(ft bmp)
Total Depth (ft
bmp)
PID Reading
(ppm)
Comments
MW-1 01/23/2023 29.64 37.00 0 --
MW-2 01/23/2023 28.60 37.00 0 --
MW-3 01/23/2023 15.80 25.00 0 --
MW-4D 01/23/2023 29.20 57.70 0 --
MW-5 01/23/2023 27.56 40.00 0 --
MW-6 01/23/2023 30.47 40.00 0 --
MW-7 01/23/2023 29.51 37.28 0 --
MW-8 01/23/2023 29.12 37.10 0 Well smells like product but
interface did not detect
product in water.MW-9 01/23/2023 29.17 37.40 0 --
ppm = parts per million -- = Not Recorded
14:20 ND --
ft-bmp = feet below measuring point ND = Not Detected PID = Photoionization Detector Reading
14:48 ND --
14:09 ND --
13:10 ND --
13:33 ND --
12:51 ND --
14:38 ND --
13:51 ND --
14:29 ND --
Gauging Equipment:Interface Probe
Gauging
Time
Depth to
Product (ft
LNAPL Removed
(gal)
Measuring Point:Top of Casing
Date(s):01/23/2023
Sampler(s):Ariel Guggino Rivera
Client: Chevron
Site ID:205513
Site Location:High Point, North Carolina
Groundwater Gauging Log
Project Number 30064349
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-1 Date 1/24/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)22 to 37
Casing
Diameter
(in.)
2 Well Casing
Material PVC
Static Water
Level (ft-bmp)29.59 Total Depth (ft-bmp)37.75
Water
Column
(ft)
8.16 Gallons in
Well 1.33
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 14:12
Purge Start 13:35
Purge End 14:52
Well Volumes
Purged
1.13
Gallons Purged 1.5
Total Purge Time
(h:m)
1:17
Sample ID MW-1
Duplicate
ID
--
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
13:35 50 29.76 5.75 220 24.5 2.44 17.20 46.1 Brown None
13:42 50 29.73 5.67 200 789 1.96 16.60 80 Brown None
13:52 50 29.73 5.57 204 601 1.97 16.90 103.9 Milky white None
13:59 50 29.7 5.54 202 477 1.68 17.80 115.7 Milky white None
14:08 50 29.71 5.65 205 381 1.71 17.40 114.2 Milky white None
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-1 Sample Time:14:12 Sample Depth (ft-bmp):37
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-2 Date 1/25/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Raining Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)22 to 37
Casing
Diameter
(in.)
2 Well Casing
Material PVC
Static Water
Level (ft-bmp)28.52 Total Depth (ft-bmp)37
Water
Column
(ft)
8.48 Gallons in
Well 1.38
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 09:52
Purge Start 09:11
Purge End 09:51
Well Volumes
Purged
1.45
Gallons Purged 2
Total Purge Time
(h:m)
0:40
Sample ID MW-2
Duplicate
ID
DUP-01
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
09:14 50 28.52 6.43 729 253 2.61 14.40 5 Clear None
09:26 50 28.93 6.50 733 77.5 0.87 15.20 -41.4 Clear None
09:38 50 29.5 6.50 736 18.7 0.93 15.10 -48.6 Clear None
09:47 50 29.31 6.53 725 3.2 1.11 15.50 -50.4 Clear None
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-2 Sample Time:09:52 Sample Depth (ft-bmp):37
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-3 Date 1/26/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)10 to 25
Casing
Diameter
(in.)
2 Well Casing
Material PVC
Static Water
Level (ft-bmp)15.74 Total Depth (ft-bmp)25
Water
Column
(ft)
9.26 Gallons in
Well 1.5
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 09:44
Purge Start 08:54
Purge End 09:44
Well Volumes
Purged
1.33
Gallons Purged 2
Total Purge Time
(h:m)
0:50
Sample ID Mw-3
Duplicate
ID
--
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
08:55 50 15.74 7.48 0.508 1000 7.45 14.40 24.9 Brown --
09:06 50 15.96 6.55 0.423 849 5.93 16.10 81.6 Milky white --
09:20 50 16.04 6.30 0.436 376 6.03 16.20 100.9 Clear --
09:31 50 16.06 6.28 0.466 138 5.77 16.70 100.6 Clear --
09:42 50 16.05 6.27 0.489 55.9 5.78 16.80 107.3 Clear --
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:Mw-3 Sample Time:09:44 Sample Depth (ft-bmp):25
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-4D Date 1/26/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)53 to 58
Casing
Diameter
(in.)
6 Well Casing
Material PVC
Static Water
Level (ft-bmp)29.08 Total Depth (ft-bmp)57
Water
Column
(ft)
27.92 Gallons in
Well 40.83
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 13:50
Purge Start 13:21
Purge End 13:49
Well Volumes
Purged
0.01
Gallons Purged 0.5
Total Purge Time
(h:m)
0:28
Sample ID MW-4D
Duplicate
ID
--
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
13:23 50 29.08 6.39 0.350 40.6 2.83 16.40 55.7 Clear --
13:28 50 29.11 6.24 0.355 35.9 1.33 17.60 54.4 Clear --
13:35 50 29.15 6.42 0.352 3.5 1.90 17.00 56.8 Clear --
13:40 50 29.15 6.41 0.355 0.75 1.04 17.20 58.1 Clear --
13:46 50 29.15 6.35 0.356 0.30 1.08 17.10 60.6 Clear --
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-4D Sample Time:13:50 Sample Depth (ft-bmp):57
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-5 Date 1/27/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)25 to 40
Casing
Diameter
(in.)
2 Well Casing
Material PVC
Static Water
Level (ft-bmp)27.46 Total Depth (ft-bmp)40
Water
Column
(ft)
12.54 Gallons in
Well 2.04
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 14:35
Purge Start 13:43
Purge End 14:32
Well Volumes
Purged
0.74
Gallons Purged 1.5
Total Purge Time
(h:m)
0:49
Sample ID MW-5
Duplicate
ID
Msmsd
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
13:45 50 27.46 5.39 0.204 1000 8.89 18.00 133.6 Brown --
13:55 50 27.9 5.42 0.207 1000 5.04 17.90 138.1 Brown --
14:04 50 27.93 5.42 0.208 573 4.94 17.80 143.4 Brown --
14:14 50 27.95 5.35 0.207 386 4.98 17.70 151.4 Brown --
14:30 50 27.95 5.48 0.208 341 4.77 18.30 141.8 Brown --
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-5 Sample Time:14:35 Sample Depth (ft-bmp):40
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-6 Date 1/27/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)25 to 40
Casing
Diameter
(in.)
2 Well Casing
Material PVC
Static Water
Level (ft-bmp)30.44 Total Depth (ft-bmp)40
Water
Column
(ft)
9.56 Gallons in
Well 1.55
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 12:22
Purge Start 11:02
Purge End 12:22
Well Volumes
Purged
1.29
Gallons Purged 2
Total Purge Time
(h:m)
1:20
Sample ID MW-6
Duplicate
ID
--
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
11:02 50 30.44 6.43 0.107 1000 10.00 17.00 -0.3 Brown --
11:10 50 30.55 5.43 0.100 1000 6.75 16.20 48.4 Brown --
11:29 50 30.55 5.15 0.094 1000 6.09 16.00 90.2 Brown --
11:44 50 30.6 5.20 0.096 240 6.44 15.60 113.1 Milk white --
12:02 50 30.6 5.18 230 12.84 15.90 126.7 Milk white --
12:18 50 30.6 5.08 0.102 132 6.60 15.60 137.2 Milk white --
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-6 Sample Time:12:22 Sample Depth (ft-bmp):40
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-7 Date 1/26/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)22 to 37
Casing
Diameter
(in.)
2 Well Casing
Material
Static Water
Level (ft-bmp)29.47 Total Depth (ft-bmp)37.28
Water
Column
(ft)
7.81 Gallons in
Well 1.27
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 11:36
Purge Start 10:39
Purge End 11:36
Well Volumes
Purged
1.18
Gallons Purged 1.5
Total Purge Time
(h:m)
0:57
Sample ID MW-7
Duplicate
ID
--
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
10:33 50 29.47 6.35 0.536 121 2.92 15.60 25.3 Clear --
10:56 50 29.8 6.56 0.539 0.00 1.22 17.40 -27.5 Clear --
11:04 50 29.85 6.52 0.543 75.9 1.24 17.30 -34.7 Clear --
11:20 50 29.94 6.48 0.543 0.22 1.25 17.80 -38.8 Clear --
11:33 50 29.9 6.50 0.548 31.0 1.20 17.90 -39 Clear --
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-7 Sample Time:11:36 Sample Depth (ft-bmp):37
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-8 Date 1/24/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)22 to 37
Casing
Diameter
(in.)
2 Well Casing
Material PVC
Static Water
Level (ft-bmp)29.12 Total Depth (ft-bmp)37.2
Water
Column
(ft)
8.08 Gallons in
Well 1.31
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 10:37
Purge Start 09:55
Purge End 11:02
Well Volumes
Purged
1.53
Gallons Purged 2
Total Purge Time
(h:m)
1:7
Sample ID MW-8
Duplicate
ID
--
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
09:56 50 29.53 6.42 754 88.3 4.52 13.40 -50 Milky white Mild
10:06 50 29.65 6.50 619 79.4 3.55 15.40 -56.2 Milky white Mild
10:13 50 29.72 6.55 601 45.4 3.43 16.10 -54 Clear Mild
10:23 50 29.8 6.58 595 30.9 3.30 16.30 -50.2 Clear Mild
10:31 50 29.88 6.53 607 24.5 3.15 16.20 -47.2 Clear Mild
Comments:None2 gallons of water was purged from well.
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-8 Sample Time:10:37 Sample Depth (ft-bmp):40
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Chevron Groundwater Sampling Form
Project Number 30064349 Well ID MW-9 Date 1/27/2023
Site Location High Point, North
Carolina Site ID 205513 Weather
(°F)Clear Sampled by
Ariel
Guggino
Rivera
Measuring Point
Description Top of Casing Screen
Depth Interval (ft-bmp)22 to 37
Casing
Diameter
(in.)
2 Well Casing
Material PVC
Static Water
Level (ft-bmp)29.12 Total Depth (ft-bmp)37.4
Water
Column
(ft)
8.28 Gallons in
Well 1.35
Water Quality Meter
Make/Model YSI Pro Plus Purge Method Low-Flow Sample Method Grab
Sample Time 09:42
Purge Start 08:41
Purge End 09:42
Well Volumes
Purged
1.48
Gallons Purged 2
Total Purge Time
(h:m)
1:1
Sample ID MW-9
Duplicate
ID
--
Purge
Equipment Bladder
Sample
Equipment
Bladder
Appearance
Time Rate
(ml/min)
Depth to
Water
(ft)
pH
(standard
units)
Conductivity
(mS/cm)
Turbidity
(NTU)
Dissolved
Oxygen
(mg/L)
Temperature
(°C)Redox
(mV)Color Odor
08:44 50 29.12 6.32 0.541 23.2 3.88 14.30 -10.2 Clear --
08:57 50 29.59 6.47 0.518 0.00 1.32 15.50 -58.9 Clear --
09:11 50 29.96 6.48 0.496 0.00 1.39 15.50 -66.5 Clear --
09:19 50 30.16 6.45 0.496 0.00 1.04 15.80 -67.3 Clear --
09:41 50 30.63 6.38 0.523 0.00 1.17 14.70 -68.5 Clear --
Comments:None
Well Casing Volume Conversion
Well diameter (in.) =
gallons per foot
1 = 0.04 1.5 = 0.09 2.5 = 0.26 3.5 = 0.50 6 = 1.47
1.25 = 0.06 2 = 0.16 3 = 0.37 4 = 0.65
Sample Information
Sample ID:MW-9 Sample Time:09:42 Sample Depth (ft-bmp):37
Analytes and Methods:See Chain-of-Custody.
ft-bmp = feet below measuring point mS/cm = milliSiemens per centimeter mV = millivolts
in. = inches NTU = Nephelometric Turbidity Unit °F = degrees Fahrenheit
ft = feet mg/L = milligrams per liter °C = degrees Celsius
mL/min = milliliters per minute PVC = Polyvinyl Chloride -- = Not Recorded
Appendix C
Laboratory Analytical and Validation Reports
ANALYTICAL REPORT
February 07, 2023
Arcadis - Chevron - NC
Sample Delivery Group:L1580432
Samples Received:01/30/2023
Project Number:30064349
Description:Pod 2 - High Point, NC #205513
Site:205513
Report To:Andrew DrMarco
801 Corporate Center Drive
Suite 300
Raleigh, NC 27607
Entire Report Reviewed By:
February 07, 2023
[Preliminary Report]
Chris McCord
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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February 07, 2023
Chris McCord
Project Manager
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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TABLE OF CONTENTS
Cp: Cover Page 1
Tc: Table of Contents 2
Ss: Sample Summary 3
Cn: Case Narrative 5
Sr: Sample Results 6
MW-3-W-20230126 L1580432-01 6
MW-4D-W-20230126 L1580432-02 9
MW-7-W-20230126 L1580432-03 12
FB-2-W-20230126 L1580432-04 15
Qc: Quality Control Summary 18
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 18
Wet Chemistry by Method 350.1 20
Wet Chemistry by Method 3500Fe B-2011 21
Wet Chemistry by Method 351.2 22
Wet Chemistry by Method 353.2 24
Wet Chemistry by Method 410.4 25
Wet Chemistry by Method 4500S2 D-2011 26
Wet Chemistry by Method 5210 B-2016 27
Wet Chemistry by Method 9056A 28
Wet Chemistry by Method 9060A 30
Metals (ICP) by Method 6010D 31
Volatile Organic Compounds (GC) by Method RSK175 32
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 33
Gl: Glossary of Terms 44
Al: Accreditations & Locations 45
Sc: Sample Chain of Custody 46
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW-3-W-20230126 L1580432-01 GW Ariel Guggino-Boyd 01/26/23 09:44 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996965 1 01/31/23 08:04 01/31/23 08:04 ABL Mt. Juliet, TN
Calculated Results WG1997036 1 01/31/23 18:44 01/31/23 18:44 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG2000611 1 02/06/23 14:49 02/06/23 14:49 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG2000611 1 02/06/23 14:49 02/06/23 14:49 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1997036 1 01/30/23 14:31 01/30/23 14:31 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1996879 1 01/30/23 16:34 01/30/23 16:34 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1997080 1 01/31/23 10:19 01/31/23 18:44 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1997093 1 02/01/23 20:34 02/01/23 20:34 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1997000 1 01/30/23 14:01 01/30/23 17:56 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1997328 1 01/31/23 11:33 01/31/23 11:33 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1997413 1 01/31/23 12:27 02/05/23 08:11 ABA Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1997393 1 01/31/23 14:58 01/31/23 14:58 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1997261 1 01/31/23 08:16 01/31/23 08:16 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 1 01/30/23 17:49 01/31/23 08:04 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1997438 1 01/31/23 11:55 01/31/23 11:55 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2000115 1 02/05/23 15:58 02/05/23 15:58 ACG Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW-4D-W-20230126 L1580432-02 GW Ariel Guggino-Boyd 01/26/23 13:50 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996965 1 01/31/23 08:12 01/31/23 08:12 ABL Mt. Juliet, TN
Calculated Results WG1997036 1 01/31/23 18:45 01/31/23 18:45 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG2000611 1 02/06/23 14:54 02/06/23 14:54 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG2000611 1 02/06/23 14:54 02/06/23 14:54 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1997036 1 01/30/23 14:34 01/30/23 14:34 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1996879 1 01/30/23 16:35 01/30/23 16:35 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1997080 1 01/31/23 10:19 01/31/23 18:45 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1997093 1 02/01/23 20:35 02/01/23 20:35 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1997000 1 01/30/23 14:01 01/30/23 17:57 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1997328 1 01/31/23 11:34 01/31/23 11:34 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1997413 1 01/31/23 12:33 02/05/23 08:15 ABA Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1997393 1 01/31/23 15:10 01/31/23 15:10 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1997261 1 01/31/23 08:48 01/31/23 08:48 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 1 01/30/23 17:49 01/31/23 08:12 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1997438 1 01/31/23 13:14 01/31/23 13:14 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2000115 1 02/05/23 16:47 02/05/23 16:47 ACG Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW-7-W-20230126 L1580432-03 GW Ariel Guggino-Boyd 01/26/23 11:36 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996965 1 01/31/23 08:15 01/31/23 08:15 ABL Mt. Juliet, TN
Calculated Results WG1997036 1 01/31/23 18:46 01/31/23 18:46 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG2000611 1 02/06/23 14:59 02/06/23 14:59 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG2000611 1 02/06/23 14:59 02/06/23 14:59 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1997036 1 01/30/23 14:36 01/30/23 14:36 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1996879 10 01/30/23 16:44 01/30/23 16:44 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1997080 1 01/31/23 10:19 01/31/23 18:46 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1997093 1 02/01/23 20:36 02/01/23 20:36 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1997000 1 01/30/23 14:01 01/30/23 17:57 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1997328 1 01/31/23 11:34 01/31/23 11:34 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1997413 1 01/31/23 12:40 02/05/23 08:19 ABA Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW-7-W-20230126 L1580432-03 GW Ariel Guggino-Boyd 01/26/23 11:36 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Wet Chemistry by Method 9056A WG1997393 1 01/31/23 15:23 01/31/23 15:23 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1997261 1 01/31/23 09:05 01/31/23 09:05 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 1 01/30/23 17:49 01/31/23 08:15 ABL Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 5 01/30/23 17:49 02/01/23 02:34 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1997438 1 01/31/23 13:21 01/31/23 13:21 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2000693 100 02/07/23 15:25 02/07/23 15:25 JHH Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2001829 100 02/07/23 16:13 02/07/23 16:13 JAH Mt. Juliet, TN
Collected by Collected date/time Received date/time
FB-2-W-20230126 L1580432-04 GW Ariel Guggino-Boyd 01/26/23 14:30 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996965 1 01/31/23 08:18 01/31/23 08:18 ABL Mt. Juliet, TN
Calculated Results WG1997036 1 01/31/23 18:48 01/31/23 18:48 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG2000611 1 02/06/23 15:03 02/06/23 15:03 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG2000611 1 02/06/23 15:03 02/06/23 15:03 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1997036 1 01/30/23 14:37 01/30/23 14:37 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1996879 1 01/30/23 16:44 01/30/23 16:44 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1997080 1 01/31/23 10:19 01/31/23 18:48 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1997093 1 02/01/23 20:37 02/01/23 20:37 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1997000 1 01/30/23 14:01 01/30/23 17:57 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1997328 1 01/31/23 11:34 01/31/23 11:34 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1997413 1 01/31/23 12:49 02/05/23 08:24 ABA Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1997393 1 01/31/23 15:35 01/31/23 15:35 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1997261 1 01/31/23 09:21 01/31/23 09:21 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 1 01/30/23 17:49 01/31/23 08:18 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1997438 1 01/31/23 13:24 01/31/23 13:24 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2000115 1 02/05/23 17:07 02/05/23 17:07 ACG Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
[Preliminary Report]
Chris McCord
Project Manager
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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Chris McCord
Project Manager
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 01
L1580432
MW-3-W-20230126
Collected date/time: 01/26/23 09:44
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 452 15.0 50.0 1 01/31/2023 08:04 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:44 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 98100 20000 1 02/06/2023 14:49 WG2000611
Free Carbon Dioxide 61100 B T8 20000 1 02/06/2023 14:49 WG2000611
Sample Narrative:
L1580432-01 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:31 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 34.0 J T8 15.0 50.0 1 01/30/2023 16:34 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:44 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 3330 50.0 100 1 02/01/2023 20:34 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 17:56 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:33 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K6 T8 2.00 1 02/05/2023 08:11 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 6 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 6 of 49
SAMPLE RESULTS - 01
L1580432
MW-3-W-20230126
Collected date/time: 01/26/23 09:44
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 3420 T8 48.0 100 1 01/31/2023 14:58 WG1997393
Nitrite U T8 42.0 100 1 01/31/2023 14:58 WG1997393
Sulfate 100000 T8 594 5000 1 01/31/2023 14:58 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)1190 B 102 1000 1 01/31/2023 08:16 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 486 18.0 100 1 01/31/2023 08:04 WG1996965
Manganese 11.0 0.934 10.0 1 01/31/2023 08:04 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 11:55 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 15:58 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 15:58 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 15:58 WG2000115
Benzene 0.609 J 0.0941 1.00 1 02/05/2023 15:58 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 15:58 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 15:58 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 15:58 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 15:58 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 15:58 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 15:58 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 15:58 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 15:58 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 15:58 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 15:58 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 15:58 WG2000115
Chloroform U 0.111 5.00 1 02/05/2023 15:58 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 15:58 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 15:58 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 15:58 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 15:58 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 15:58 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 15:58 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 15:58 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 15:58 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 15:58 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 15:58 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 15:58 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 15:58 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 15:58 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 15:58 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 15:58 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 7 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 7 of 49
SAMPLE RESULTS - 01
L1580432
MW-3-W-20230126
Collected date/time: 01/26/23 09:44
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 15:58 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 15:58 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 15:58 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 15:58 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 15:58 WG2000115
Ethylbenzene 0.244 J 0.137 1.00 1 02/05/2023 15:58 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 15:58 WG2000115
Isopropylbenzene U 0.105 1.00 1 02/05/2023 15:58 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 15:58 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 15:58 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 15:58 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 15:58 WG2000115
Methyl tert-butyl ether U 0.101 1.00 1 02/05/2023 15:58 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 15:58 WG2000115
n-Propylbenzene U 0.0993 1.00 1 02/05/2023 15:58 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 15:58 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 15:58 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 15:58 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 15:58 WG2000115
Toluene U 0.278 1.00 1 02/05/2023 15:58 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 15:58 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 15:58 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 15:58 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 15:58 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 15:58 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 15:58 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 15:58 WG2000115
1,2,4-Trimethylbenzene U 0.322 1.00 1 02/05/2023 15:58 WG2000115
1,3,5-Trimethylbenzene U 0.104 1.00 1 02/05/2023 15:58 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 15:58 WG2000115
o-Xylene 0.174 J 0.174 1.00 1 02/05/2023 15:58 WG2000115
m&p-Xylenes U 0.430 2.00 1 02/05/2023 15:58 WG2000115
(S) Toluene-d8 91.6 80.0-120 02/05/2023 15:58 WG2000115
(S) 4-Bromofluorobenzene 84.6 77.0-126 02/05/2023 15:58 WG2000115
(S) 1,2-Dichloroethane-d4 110 70.0-130 02/05/2023 15:58 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 8 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 8 of 49
SAMPLE RESULTS - 02
L1580432
MW-4D-W-20230126
Collected date/time: 01/26/23 13:50
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 38.6 J 15.0 50.0 1 01/31/2023 08:12 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:45 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 71500 20000 1 02/06/2023 14:54 WG2000611
Free Carbon Dioxide 64400 B T8 20000 1 02/06/2023 14:54 WG2000611
Sample Narrative:
L1580432-02 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:34 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/30/2023 16:35 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:45 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 2760 50.0 100 1 02/01/2023 20:35 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:34 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 2.94 K1 K6 T8 2.00 1 02/05/2023 08:15 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 9 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 9 of 49
SAMPLE RESULTS - 02
L1580432
MW-4D-W-20230126
Collected date/time: 01/26/23 13:50
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 4670 T8 48.0 100 1 01/31/2023 15:10 WG1997393
Nitrite 85.4 J T8 42.0 100 1 01/31/2023 15:10 WG1997393
Sulfate 12300 T8 594 5000 1 01/31/2023 15:10 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)912 B J 102 1000 1 01/31/2023 08:48 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 38.6 J 18.0 100 1 01/31/2023 08:12 WG1996965
Manganese 473 0.934 10.0 1 01/31/2023 08:12 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 13:14 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 16:47 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 16:47 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 16:47 WG2000115
Benzene 2.82 0.0941 1.00 1 02/05/2023 16:47 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 16:47 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 16:47 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 16:47 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 16:47 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 16:47 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 16:47 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 16:47 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 16:47 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 16:47 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 16:47 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 16:47 WG2000115
Chloroform 0.594 J 0.111 5.00 1 02/05/2023 16:47 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 16:47 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 16:47 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 16:47 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 16:47 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 16:47 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 16:47 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 16:47 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 16:47 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 16:47 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 16:47 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 16:47 WG2000115
1,2-Dichloroethane 0.495 J 0.0819 1.00 1 02/05/2023 16:47 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 16:47 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 16:47 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 16:47 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 10 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 10 of 49
SAMPLE RESULTS - 02
L1580432
MW-4D-W-20230126
Collected date/time: 01/26/23 13:50
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 16:47 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 16:47 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 16:47 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 16:47 WG2000115
Di-isopropyl ether 0.523 J 0.105 1.00 1 02/05/2023 16:47 WG2000115
Ethylbenzene 0.874 J 0.137 1.00 1 02/05/2023 16:47 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 16:47 WG2000115
Isopropylbenzene U 0.105 1.00 1 02/05/2023 16:47 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 16:47 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 16:47 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 16:47 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 16:47 WG2000115
Methyl tert-butyl ether 7.21 0.101 1.00 1 02/05/2023 16:47 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 16:47 WG2000115
n-Propylbenzene U 0.0993 1.00 1 02/05/2023 16:47 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 16:47 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 16:47 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 16:47 WG2000115
Tetrachloroethene 0.651 J 0.300 1.00 1 02/05/2023 16:47 WG2000115
Toluene U 0.278 1.00 1 02/05/2023 16:47 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 16:47 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 16:47 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 16:47 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 16:47 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 16:47 WG2000115
Trichlorofluoromethane 1.59 J 0.160 5.00 1 02/05/2023 16:47 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 16:47 WG2000115
1,2,4-Trimethylbenzene 0.322 J 0.322 1.00 1 02/05/2023 16:47 WG2000115
1,3,5-Trimethylbenzene U 0.104 1.00 1 02/05/2023 16:47 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 16:47 WG2000115
o-Xylene 0.311 J 0.174 1.00 1 02/05/2023 16:47 WG2000115
m&p-Xylenes 0.848 J 0.430 2.00 1 02/05/2023 16:47 WG2000115
(S) Toluene-d8 88.8 80.0-120 02/05/2023 16:47 WG2000115
(S) 4-Bromofluorobenzene 79.1 77.0-126 02/05/2023 16:47 WG2000115
(S) 1,2-Dichloroethane-d4 109 70.0-130 02/05/2023 16:47 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 11 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 11 of 49
SAMPLE RESULTS - 03
L1580432
MW-7-W-20230126
Collected date/time: 01/26/23 11:36
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/31/2023 08:15 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:46 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 241000 20000 1 02/06/2023 14:59 WG2000611
Free Carbon Dioxide 144000 T8 20000 1 02/06/2023 14:59 WG2000611
Sample Narrative:
L1580432-03 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:36 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 5420 T8 150 500 10 01/30/2023 16:44 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:46 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 02/01/2023 20:36 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 101000 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:34 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 14.1 K1 K6 T8 2.00 1 02/05/2023 08:19 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 12 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 12 of 49
SAMPLE RESULTS - 03
L1580432
MW-7-W-20230126
Collected date/time: 01/26/23 11:36
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/31/2023 15:23 WG1997393
Nitrite U T8 42.0 100 1 01/31/2023 15:23 WG1997393
Sulfate U T8 594 5000 1 01/31/2023 15:23 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)13700 102 1000 1 01/31/2023 09:05 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 4970 18.0 100 1 01/31/2023 08:15 WG1996965
Manganese 16200 4.67 50.0 5 02/01/2023 02:34 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 205 2.91 10.0 1 01/31/2023 13:21 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 1130 5000 100 02/07/2023 15:25 WG2000693
Acrolein U 254 5000 100 02/07/2023 15:25 WG2000693
Acrylonitrile U 67.1 1000 100 02/07/2023 15:25 WG2000693
Benzene 7500 9.41 100 100 02/07/2023 15:25 WG2000693
Bromobenzene U 11.8 100 100 02/07/2023 15:25 WG2000693
Bromodichloromethane U 13.6 100 100 02/07/2023 15:25 WG2000693
Bromoform U 12.9 100 100 02/07/2023 15:25 WG2000693
Bromomethane U 60.5 500 100 02/07/2023 16:13 WG2001829
n-Butylbenzene U 15.7 100 100 02/07/2023 15:25 WG2000693
sec-Butylbenzene U 12.5 100 100 02/07/2023 15:25 WG2000693
tert-Butylbenzene U 12.7 100 100 02/07/2023 15:25 WG2000693
Carbon tetrachloride U 12.8 100 100 02/07/2023 15:25 WG2000693
Chlorobenzene U 11.6 100 100 02/07/2023 15:25 WG2000693
Chlorodibromomethane U 14.0 100 100 02/07/2023 15:25 WG2000693
Chloroethane U 19.2 500 100 02/07/2023 16:13 WG2001829
Chloroform U 11.1 500 100 02/07/2023 15:25 WG2000693
Chloromethane U 96.0 250 100 02/07/2023 15:25 WG2000693
2-Chlorotoluene U 10.6 100 100 02/07/2023 15:25 WG2000693
4-Chlorotoluene U 11.4 100 100 02/07/2023 15:25 WG2000693
1,2-Dibromo-3-Chloropropane U 27.6 500 100 02/07/2023 15:25 WG2000693
1,2-Dibromoethane U 12.6 100 100 02/07/2023 15:25 WG2000693
Dibromomethane U 12.2 100 100 02/07/2023 15:25 WG2000693
1,2-Dichlorobenzene U 10.7 100 100 02/07/2023 15:25 WG2000693
1,3-Dichlorobenzene U 11.0 100 100 02/07/2023 15:25 WG2000693
1,4-Dichlorobenzene U 12.0 100 100 02/07/2023 15:25 WG2000693
Dichlorodifluoromethane U 37.4 500 100 02/07/2023 15:25 WG2000693
1,1-Dichloroethane U 10.0 100 100 02/07/2023 15:25 WG2000693
1,2-Dichloroethane 102 8.19 100 100 02/07/2023 15:25 WG2000693
1,1-Dichloroethene U 18.8 100 100 02/07/2023 15:25 WG2000693
cis-1,2-Dichloroethene U 12.6 100 100 02/07/2023 15:25 WG2000693
trans-1,2-Dichloroethene U 14.9 100 100 02/07/2023 15:25 WG2000693
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 03
L1580432
MW-7-W-20230126
Collected date/time: 01/26/23 11:36
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 14.9 100 100 02/07/2023 15:25 WG2000693
1,1-Dichloropropene U 14.2 100 100 02/07/2023 15:25 WG2000693
1,3-Dichloropropane U 11.0 100 100 02/07/2023 15:25 WG2000693
2,2-Dichloropropane U 16.1 100 100 02/07/2023 15:25 WG2000693
Di-isopropyl ether 31.6 J 10.5 100 100 02/07/2023 15:25 WG2000693
Ethylbenzene 2230 13.7 100 100 02/07/2023 15:25 WG2000693
Hexachloro-1,3-butadiene U 33.7 100 100 02/07/2023 15:25 WG2000693
Isopropylbenzene 79.3 J 10.5 100 100 02/07/2023 15:25 WG2000693
p-Isopropyltoluene U 12.0 100 100 02/07/2023 15:25 WG2000693
2-Butanone (MEK)U 119 1000 100 02/07/2023 15:25 WG2000693
Methylene Chloride U 43.0 500 100 02/07/2023 15:25 WG2000693
4-Methyl-2-pentanone (MIBK)U 47.8 1000 100 02/07/2023 15:25 WG2000693
Methyl tert-butyl ether 3160 10.1 100 100 02/07/2023 15:25 WG2000693
Naphthalene 235 J 100 500 100 02/07/2023 15:25 WG2000693
n-Propylbenzene 167 9.93 100 100 02/07/2023 15:25 WG2000693
Styrene U 11.8 100 100 02/07/2023 15:25 WG2000693
1,1,1,2-Tetrachloroethane U 14.7 100 100 02/07/2023 15:25 WG2000693
1,1,2,2-Tetrachloroethane U 13.3 100 100 02/07/2023 15:25 WG2000693
Tetrachloroethene U 30.0 100 100 02/07/2023 15:25 WG2000693
Toluene 94.2 J 27.8 100 100 02/07/2023 15:25 WG2000693
1,2,3-Trichlorobenzene U 23.0 100 100 02/07/2023 15:25 WG2000693
1,2,4-Trichlorobenzene U 48.1 100 100 02/07/2023 15:25 WG2000693
1,1,1-Trichloroethane U 14.9 100 100 02/07/2023 15:25 WG2000693
1,1,2-Trichloroethane U 15.8 100 100 02/07/2023 15:25 WG2000693
Trichloroethene U 19.0 100 100 02/07/2023 15:25 WG2000693
Trichlorofluoromethane U 16.0 500 100 02/07/2023 15:25 WG2000693
1,2,3-Trichloropropane U 23.7 250 100 02/07/2023 15:25 WG2000693
1,2,4-Trimethylbenzene 407 32.2 100 100 02/07/2023 15:25 WG2000693
1,3,5-Trimethylbenzene 177 10.4 100 100 02/07/2023 15:25 WG2000693
Vinyl chloride U 23.4 100 100 02/07/2023 15:25 WG2000693
o-Xylene 273 17.4 100 100 02/07/2023 15:25 WG2000693
m&p-Xylenes 969 43.0 200 100 02/07/2023 15:25 WG2000693
(S) Toluene-d8 103 80.0-120 02/07/2023 15:25 WG2000693
(S) Toluene-d8 90.8 80.0-120 02/07/2023 16:13 WG2001829
(S) 4-Bromofluorobenzene 98.8 77.0-126 02/07/2023 15:25 WG2000693
(S) 4-Bromofluorobenzene 84.3 77.0-126 02/07/2023 16:13 WG2001829
(S) 1,2-Dichloroethane-d4 90.1 70.0-130 02/07/2023 15:25 WG2000693
(S) 1,2-Dichloroethane-d4 103 70.0-130 02/07/2023 16:13 WG2001829
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 04
L1580432
FB-2-W-20230126
Collected date/time: 01/26/23 14:30
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 15.0 50.0 1 01/31/2023 08:18 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:48 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity U 20000 1 02/06/2023 15:03 WG2000611
Free Carbon Dioxide ND T8 20000 1 02/06/2023 15:03 WG2000611
Sample Narrative:
L1580432-04 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:37 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/30/2023 16:44 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:48 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 02/01/2023 20:37 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:34 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K1 K6 T8 2.00 1 02/05/2023 08:24 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 04
L1580432
FB-2-W-20230126
Collected date/time: 01/26/23 14:30
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/31/2023 15:35 WG1997393
Nitrite U T8 42.0 100 1 01/31/2023 15:35 WG1997393
Sulfate U T8 594 5000 1 01/31/2023 15:35 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)197 B J 102 1000 1 01/31/2023 09:21 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron U 18.0 100 1 01/31/2023 08:18 WG1996965
Manganese 1.18 J 0.934 10.0 1 01/31/2023 08:18 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 13:24 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 17:07 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 17:07 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 17:07 WG2000115
Benzene U 0.0941 1.00 1 02/05/2023 17:07 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 17:07 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 17:07 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 17:07 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 17:07 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 17:07 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 17:07 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 17:07 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 17:07 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 17:07 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 17:07 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 17:07 WG2000115
Chloroform U 0.111 5.00 1 02/05/2023 17:07 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 17:07 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 17:07 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 17:07 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 17:07 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 17:07 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 17:07 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 17:07 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 17:07 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 17:07 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 17:07 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 17:07 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 17:07 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 17:07 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 17:07 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 17:07 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 04
L1580432
FB-2-W-20230126
Collected date/time: 01/26/23 14:30
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 17:07 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 17:07 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 17:07 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 17:07 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 17:07 WG2000115
Ethylbenzene U 0.137 1.00 1 02/05/2023 17:07 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 17:07 WG2000115
Isopropylbenzene U 0.105 1.00 1 02/05/2023 17:07 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 17:07 WG2000115
2-Butanone (MEK)2.24 J 1.19 10.0 1 02/05/2023 17:07 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 17:07 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 17:07 WG2000115
Methyl tert-butyl ether U 0.101 1.00 1 02/05/2023 17:07 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 17:07 WG2000115
n-Propylbenzene U 0.0993 1.00 1 02/05/2023 17:07 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 17:07 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 17:07 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 17:07 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 17:07 WG2000115
Toluene 0.470 J 0.278 1.00 1 02/05/2023 17:07 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 17:07 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 17:07 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 17:07 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 17:07 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 17:07 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 17:07 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 17:07 WG2000115
1,2,4-Trimethylbenzene U 0.322 1.00 1 02/05/2023 17:07 WG2000115
1,3,5-Trimethylbenzene U 0.104 1.00 1 02/05/2023 17:07 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 17:07 WG2000115
o-Xylene U 0.174 1.00 1 02/05/2023 17:07 WG2000115
m&p-Xylenes U 0.430 2.00 1 02/05/2023 17:07 WG2000115
(S) Toluene-d8 92.1 80.0-120 02/05/2023 17:07 WG2000115
(S) 4-Bromofluorobenzene 81.8 77.0-126 02/05/2023 17:07 WG2000115
(S) 1,2-Dichloroethane-d4 108 70.0-130 02/05/2023 17:07 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000611
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3887929-2 02/06/23 12:36
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Alkalinity U 8450 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
Method Blank (MB)
(MB) R3887929-3 02/06/23 12:36
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Free Carbon Dioxide 11500 J 6670 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
L1581143-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581143-01 02/06/23 12:54 • (DUP) R3887929-4 02/06/23 12:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity 186000 187000 1 0.857 20
Sample Narrative:
OS: Endpoint pH 4.5
DUP: Endpoint pH 4.5
L1581143-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581143-01 02/06/23 12:54 • (DUP) R3887929-5 02/06/23 12:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide U U 1 0.000 20
Sample Narrative:
OS: Endpoint pH 4.5
DUP: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000611
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1580432-01,02,03,04
L1581910-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581910-01 02/06/23 14:23 • (DUP) R3887929-6 02/06/23 14:29
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity 177000 176000 1 0.638 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
L1581910-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581910-01 02/06/23 14:23 • (DUP) R3887929-7 02/06/23 14:29
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide 7800 7850 1 0.587 J 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
Laboratory Control Sample (LCS)
(LCS) R3887929-1 02/06/23 12:25
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Alkalinity 100000 102000 102 90.0-110
Sample Narrative:
LCS: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997036
Wet Chemistry by Method 350.1 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3885732-1 01/30/23 14:27
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ammonia Nitrogen U 117 250
L1580432-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-01 01/30/23 14:31 • (DUP) R3885732-3 01/30/23 14:33
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ammonia Nitrogen U U 1 0.000 10
Laboratory Control Sample (LCS)
(LCS) R3885732-2 01/30/23 14:28
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ammonia Nitrogen 7500 7570 101 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/30/23 14:46 • (MS) R3885732-4 01/30/23 14:48 • (MSD) R3885732-5 01/30/23 14:49
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ammonia Nitrogen 5000 U 4890 5050 97.8 101 1 90.0-110 3.10 10
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996879
Wet Chemistry by Method 3500Fe B-2011 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3885786-1 01/30/23 16:26
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ferrous Iron U 15.0 50.0
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 01/30/23 16:53 • (DUP) R3885786-6 01/30/23 16:54
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ferrous Iron U 15.0 1 200 J P1 20
L1579789-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579789-01 01/30/23 16:32 • (DUP) R3885786-3 01/30/23 16:32
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ferrous Iron 142 145 1 2.09 20
Laboratory Control Sample (LCS)
(LCS) R3885786-2 01/30/23 16:27
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ferrous Iron 1000 910 91.0 85.0-115
L1580443-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-02 01/30/23 16:52 • (MS) R3885786-4 01/30/23 16:53 • (MSD) R3885786-5 01/30/23 16:53
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ferrous Iron 1000 U 908 903 90.8 90.3 1 80.0-120 0.552 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997080
Wet Chemistry by Method 351.2 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3886231-1 01/31/23 18:22
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Kjeldahl Nitrogen, TKN U 140 250
L1580130-05 Original Sample (OS) • Duplicate (DUP)
(OS) L1580130-05 01/31/23 18:30 • (DUP) R3886231-3 01/31/23 18:31
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 1430 1400 1 2.12 20
L1580130-07 Original Sample (OS) • Duplicate (DUP)
(OS) L1580130-07 01/31/23 18:38 • (DUP) R3886231-5 01/31/23 18:40
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 1590 1630 1 2.48 20
Laboratory Control Sample (LCS)
(LCS) R3886231-2 01/31/23 18:23
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 14700 13800 93.9 75.2-120
L1580130-06 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580130-06 01/31/23 18:33 • (MS) R3886231-4 01/31/23 18:34
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Kjeldahl Nitrogen, TKN 5000 596 5480 97.7 1 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 18:54 • (MS) R3886231-6 01/31/23 18:56 • (MSD) R3886231-7 01/31/23 18:57
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Kjeldahl Nitrogen, TKN 5000 U 1530 1910 30.6 38.2 1 90.0-110 J6 J3 J6 22.1 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997080
Wet Chemistry by Method 351.2 L1580432-01,02,03,04
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 18:54 • (MS) R3886231-6 01/31/23 18:56 • (MSD) R3886231-7 01/31/23 18:57
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Sample Narrative:
MS: Matrix spike failure due to matrix.
MSD: Matrix spike fialure due to matrix.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997093
Wet Chemistry by Method 353.2 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3886549-1 02/01/23 20:15
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate-Nitrite U 50.0 100
L1580005-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580005-01 02/01/23 20:17 • (DUP) R3886549-3 02/01/23 20:18
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 2070 2080 1 0.482 20
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 02/01/23 20:41 • (DUP) R3886549-5 02/01/23 20:46
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 11600 11500 5 1.30 20
Laboratory Control Sample (LCS)
(LCS) R3886549-2 02/01/23 20:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate-Nitrite 2500 2600 104 90.0-110
L1580005-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580005-01 02/01/23 20:17 • (MS) R3886549-4 02/01/23 20:20
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Nitrate-Nitrite 2500 2070 4590 101 1 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/01/23 20:41 • (MS) R3886549-6 02/01/23 20:48 • (MSD) R3886549-7 02/01/23 20:49
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate-Nitrite 12500 11600 23600 24100 95.6 100 5 90.0-110 2.31 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997000
Wet Chemistry by Method 410.4 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3885806-1 01/30/23 17:52
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
COD U 11700 20000
L1579311-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579311-01 01/30/23 17:53 • (DUP) R3885806-3 01/30/23 17:53
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
COD 60800 69800 1 13.8 20
L1580443-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-01 01/30/23 17:57 • (DUP) R3885806-4 01/30/23 18:03
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
COD 122000 116000 1 5.18 20
Laboratory Control Sample (LCS)
(LCS) R3885806-2 01/30/23 17:52
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
COD 500000 473000 94.6 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/30/23 18:29 • (MS) R3885806-5 01/30/23 18:30 • (MSD) R3885806-6 01/30/23 18:31
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
COD 500000 U 528000 480000 106 96.1 1 80.0-120 9.50 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997328
Wet Chemistry by Method 4500S2 D-2011 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3886035-1 01/31/23 11:17
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Sulfide U 25.0 50.0
L1580432-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-01 01/31/23 11:33 • (DUP) R3886035-3 01/31/23 11:33
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Sulfide U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3886035-2 01/31/23 11:17
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Sulfide 500 521 104 85.0-115
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 11:35 • (MS) R3886035-4 01/31/23 11:35 • (MSD) R3886035-5 01/31/23 11:36
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Sulfide 500 U 485 503 97.0 101 1 80.0-120 3.64 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997413
Wet Chemistry by Method 5210 B-2016 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3887618-1 02/05/23 10:30
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/l mg/l mg/l
BOD U 0.200 0.200
L1580536-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580536-01 02/05/23 08:46 • (DUP) R3887618-3 02/05/23 08:49
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD ND ND 1 0 30
L1580577-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580577-01 02/05/23 09:26 • (DUP) R3887618-4 02/05/23 09:31
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD 55.2 47.3 1 15.3 30
Laboratory Control Sample (LCS)
(LCS) R3887618-2 02/05/23 08:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 147 74.1 84.6-115 J-
Laboratory Control Sample (LCS)
(LCS) R3887618-5 02/05/23 09:37
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 169 85.1 84.6-115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997393
Wet Chemistry by Method 9056A L1580432-01,02,03,04
Method Blank (MB)
(MB) R3886482-1 01/31/23 09:51
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate U 48.0 100
Nitrite U 42.0 100
Sulfate U 594 5000
L1580405-11 Original Sample (OS) • Duplicate (DUP)
(OS) L1580405-11 01/31/23 12:53 • (DUP) R3886482-3 01/31/23 13:05
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate 88.9 89.9 1 1.12 J 15
Nitrite U U 1 0.000 15
Sulfate 24300 24300 1 0.110 15
L1580562-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580562-01 01/31/23 17:40 • (DUP) R3886482-6 01/31/23 17:52
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate 1150 1140 1 0.841 15
Nitrite U U 1 0.000 15
Sulfate 43300 43300 1 0.172 15
Laboratory Control Sample (LCS)
(LCS) R3886482-2 01/31/23 10:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate 8000 7600 95.0 80.0-120
Nitrite 8000 7790 97.4 80.0-120
Sulfate 40000 38900 97.3 80.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997393
Wet Chemistry by Method 9056A L1580432-01,02,03,04
L1580405-11 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580405-11 01/31/23 12:53 • (MS) R3886482-4 01/31/23 13:18 • (MSD) R3886482-5 01/31/23 13:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate 5000 88.9 4950 4930 97.3 96.8 1 80.0-120 0.532 15
Nitrite 5000 U 5130 5120 103 102 1 80.0-120 0.205 15
Sulfate 50000 24300 73100 72500 97.6 96.4 1 80.0-120 0.771 15
L1580562-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580562-01 01/31/23 17:40 • (MS) R3886482-7 01/31/23 18:04
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Nitrate 5000 1150 6210 101 1 80.0-120
Nitrite 5000 U 5260 105 1 80.0-120
Sulfate 50000 43300 91800 97.0 1 80.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997261
Wet Chemistry by Method 9060A L1580432-01,02,03,04
Method Blank (MB)
(MB) R3886050-2 01/31/23 07:02
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
TOC (Total Organic Carbon)245 J 102 1000
L1580432-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-01 01/31/23 08:16 • (DUP) R3886050-3 01/31/23 08:32
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)1190 1160 1 2.38 20
Laboratory Control Sample (LCS)
(LCS) R3886050-1 01/31/23 06:46
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)75000 78000 104 85.0-115
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 10:48 • (MS) R3886050-4 01/31/23 11:08 • (MSD) R3886050-5 01/31/23 11:29
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
TOC (Total Organic Carbon)50000 551 52500 53100 104 105 1 80.0-120 1.08 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996965
Metals (ICP) by Method 6010D L1580432-01,02,03,04
Method Blank (MB)
(MB) R3886057-1 01/31/23 07:39
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Iron U 18.0 100
Manganese U 0.934 10.0
Laboratory Control Sample (LCS)
(LCS) R3886057-2 01/31/23 07:42
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Iron 10000 9580 95.8 80.0-120
Manganese 1000 948 94.8 80.0-120
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 07:45 • (MS) R3886057-4 01/31/23 07:50 • (MSD) R3886057-5 01/31/23 07:53
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Iron 10000 2860 13200 13600 104 107 1 75.0-125 2.53 20
Manganese 1000 56.7 1020 1010 96.2 95.5 1 75.0-125 0.653 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997438
Volatile Organic Compounds (GC) by Method RSK175 L1580432-01,02,03,04
Method Blank (MB)
(MB) R3886040-2 01/31/23 11:20
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Methane U 2.91 10.0
L1580432-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-02 01/31/23 13:14 • (DUP) R3886040-3 01/31/23 13:19
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane U U 1 0.000 20
L1580443-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-02 01/31/23 13:59 • (DUP) R3886040-4 01/31/23 14:21
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane U U 1 0.000 20
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3886040-1 01/31/23 11:16 • (LCSD) R3886040-7 01/31/23 14:32
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Methane 67.8 73.6 65.7 109 96.9 85.0-115 11.3 20
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 14:04 • (MS) R3886040-5 01/31/23 14:27 • (MSD) R3886040-6 01/31/23 14:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Methane 67.8 U 75.4 74.3 111 110 1 50.0-150 1.47 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-01,02,04
Method Blank (MB)
(MB) R3887703-2 02/05/23 12:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
Bromomethane U 0.605 5.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-01,02,04
Method Blank (MB)
(MB) R3887703-2 02/05/23 12:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 94.3 80.0-120
(S) 4-Bromofluorobenzene 80.7 77.0-126
(S) 1,2-Dichloroethane-d4 107 70.0-130
Laboratory Control Sample (LCS)
(LCS) R3887703-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acetone 25.0 21.2 84.8 19.0-160
Acrolein 25.0 10.3 41.2 10.0-160
Acrylonitrile 25.0 23.4 93.6 55.0-149
Benzene 5.00 4.73 94.6 70.0-123
Bromobenzene 5.00 5.23 105 73.0-121
Bromodichloromethane 5.00 5.30 106 75.0-120
Bromoform 5.00 4.49 89.8 68.0-132
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-01,02,04
Laboratory Control Sample (LCS)
(LCS) R3887703-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Bromomethane 5.00 5.77 115 10.0-160
n-Butylbenzene 5.00 4.71 94.2 73.0-125
sec-Butylbenzene 5.00 4.99 99.8 75.0-125
tert-Butylbenzene 5.00 4.79 95.8 76.0-124
Carbon tetrachloride 5.00 5.06 101 68.0-126
Chlorobenzene 5.00 4.40 88.0 80.0-121
Chlorodibromomethane 5.00 4.59 91.8 77.0-125
Chloroethane 5.00 5.89 118 47.0-150
Chloroform 5.00 5.41 108 73.0-120
Chloromethane 5.00 5.01 100 41.0-142
2-Chlorotoluene 5.00 5.18 104 76.0-123
4-Chlorotoluene 5.00 4.85 97.0 75.0-122
1,2-Dibromo-3-Chloropropane 5.00 4.27 85.4 58.0-134
1,2-Dibromoethane 5.00 4.73 94.6 80.0-122
Dibromomethane 5.00 4.97 99.4 80.0-120
1,2-Dichlorobenzene 5.00 4.89 97.8 79.0-121
1,3-Dichlorobenzene 5.00 5.15 103 79.0-120
1,4-Dichlorobenzene 5.00 5.02 100 79.0-120
Dichlorodifluoromethane 5.00 6.52 130 51.0-149
1,1-Dichloroethane 5.00 4.54 90.8 70.0-126
1,2-Dichloroethane 5.00 5.28 106 70.0-128
1,1-Dichloroethene 5.00 4.97 99.4 71.0-124
cis-1,2-Dichloroethene 5.00 4.78 95.6 73.0-120
trans-1,2-Dichloroethene 5.00 4.97 99.4 73.0-120
1,2-Dichloropropane 5.00 4.45 89.0 77.0-125
1,1-Dichloropropene 5.00 4.77 95.4 74.0-126
1,3-Dichloropropane 5.00 4.70 94.0 80.0-120
2,2-Dichloropropane 5.00 5.77 115 58.0-130
Di-isopropyl ether 5.00 4.38 87.6 58.0-138
Ethylbenzene 5.00 4.27 85.4 79.0-123
Hexachloro-1,3-butadiene 5.00 5.48 110 54.0-138
Isopropylbenzene 5.00 4.16 83.2 76.0-127
p-Isopropyltoluene 5.00 4.81 96.2 76.0-125
2-Butanone (MEK)25.0 24.0 96.0 44.0-160
Methylene Chloride 5.00 5.13 103 67.0-120
4-Methyl-2-pentanone (MIBK)25.0 22.5 90.0 68.0-142
Methyl tert-butyl ether 5.00 5.07 101 68.0-125
Naphthalene 5.00 4.18 83.6 54.0-135
n-Propylbenzene 5.00 4.77 95.4 77.0-124
Styrene 5.00 3.98 79.6 73.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-01,02,04
Laboratory Control Sample (LCS)
(LCS) R3887703-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
1,1,1,2-Tetrachloroethane 5.00 4.51 90.2 75.0-125
1,1,2,2-Tetrachloroethane 5.00 5.35 107 65.0-130
Tetrachloroethene 5.00 4.73 94.6 72.0-132
Toluene 5.00 4.40 88.0 79.0-120
1,2,3-Trichlorobenzene 5.00 4.69 93.8 50.0-138
1,2,4-Trichlorobenzene 5.00 4.70 94.0 57.0-137
1,1,1-Trichloroethane 5.00 5.51 110 73.0-124
1,1,2-Trichloroethane 5.00 4.68 93.6 80.0-120
Trichloroethene 5.00 4.58 91.6 78.0-124
Trichlorofluoromethane 5.00 5.84 117 59.0-147
1,2,3-Trichloropropane 5.00 5.66 113 73.0-130
1,2,4-Trimethylbenzene 5.00 4.75 95.0 76.0-121
1,3,5-Trimethylbenzene 5.00 4.87 97.4 76.0-122
Vinyl chloride 5.00 5.41 108 67.0-131
o-Xylene 5.00 4.01 80.2 80.0-122
m&p-Xylenes 10.0 8.65 86.5 80.0-122
(S) Toluene-d8 91.2 80.0-120
(S) 4-Bromofluorobenzene 83.8 77.0-126
(S) 1,2-Dichloroethane-d4 106 70.0-130
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/05/23 17:48 • (MS) R3887703-3 02/06/23 00:10 • (MSD) R3887703-4 02/06/23 00:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Acetone 25.0 U 25.7 23.1 103 92.4 1 10.0-160 10.7 35
Acrolein 25.0 U 23.7 21.6 94.8 86.4 1 10.0-160 9.27 39
Acrylonitrile 25.0 U 27.4 25.3 110 101 1 21.0-160 7.97 32
Benzene 5.00 3.14 9.19 8.26 121 102 1 17.0-158 10.7 27
Bromobenzene 5.00 U 5.72 5.65 114 113 1 30.0-149 1.23 28
Bromodichloromethane 5.00 U 5.79 5.89 116 118 1 31.0-150 1.71 27
Bromoform 5.00 U 4.95 5.06 99.0 101 1 29.0-150 2.20 29
Bromomethane 5.00 U 6.38 6.28 128 126 1 10.0-160 1.58 38
n-Butylbenzene 5.00 U 5.35 5.26 107 105 1 31.0-150 1.70 30
sec-Butylbenzene 5.00 U 5.62 5.65 112 113 1 33.0-155 0.532 29
tert-Butylbenzene 5.00 U 5.42 5.54 108 111 1 34.0-153 2.19 28
Carbon tetrachloride 5.00 U 5.91 5.74 118 115 1 23.0-159 2.92 28
Chlorobenzene 5.00 U 5.03 4.93 101 98.6 1 33.0-152 2.01 27
Chlorodibromomethane 5.00 U 5.09 5.10 102 102 1 37.0-149 0.196 27
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-01,02,04
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/05/23 17:48 • (MS) R3887703-3 02/06/23 00:10 • (MSD) R3887703-4 02/06/23 00:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Chloroethane 5.00 U 6.74 6.77 135 135 1 10.0-160 0.444 30
Chloroform 5.00 0.297 6.59 6.28 126 120 1 29.0-154 4.82 28
Chloromethane 5.00 U 5.73 5.84 115 117 1 10.0-160 1.90 29
2-Chlorotoluene 5.00 U 5.68 5.48 114 110 1 32.0-153 3.58 28
4-Chlorotoluene 5.00 U 5.29 5.24 106 105 1 32.0-150 0.950 28
1,2-Dibromo-3-Chloropropane 5.00 U 4.78 4.93 95.6 98.6 1 22.0-151 3.09 34
1,2-Dibromoethane 5.00 U 5.18 5.01 104 100 1 34.0-147 3.34 27
Dibromomethane 5.00 U 5.30 5.60 106 112 1 30.0-151 5.50 27
1,2-Dichlorobenzene 5.00 U 5.45 5.52 109 110 1 34.0-149 1.28 28
1,3-Dichlorobenzene 5.00 U 5.67 5.55 113 111 1 36.0-146 2.14 27
1,4-Dichlorobenzene 5.00 U 5.40 5.37 108 107 1 35.0-142 0.557 27
Dichlorodifluoromethane 5.00 U 7.07 7.26 141 145 1 10.0-160 2.65 29
1,1-Dichloroethane 5.00 U 5.60 5.16 112 103 1 25.0-158 8.18 27
1,2-Dichloroethane 5.00 U 5.98 5.91 120 118 1 29.0-151 1.18 27
1,1-Dichloroethene 5.00 U 6.02 5.98 120 120 1 11.0-160 0.667 29
cis-1,2-Dichloroethene 5.00 U 5.71 5.24 114 105 1 10.0-160 8.58 27
trans-1,2-Dichloroethene 5.00 U 5.97 5.50 119 110 1 17.0-153 8.20 27
1,2-Dichloropropane 5.00 U 4.83 4.94 96.6 98.8 1 30.0-156 2.25 27
1,1-Dichloropropene 5.00 U 5.77 5.37 115 107 1 25.0-158 7.18 27
1,3-Dichloropropane 5.00 U 5.19 5.14 104 103 1 38.0-147 0.968 27
2,2-Dichloropropane 5.00 U 6.38 5.96 128 119 1 24.0-152 6.81 29
Di-isopropyl ether 5.00 U 5.18 4.85 104 97.0 1 21.0-160 6.58 28
Ethylbenzene 5.00 2.80 7.95 7.60 103 96.0 1 30.0-155 4.50 27
Hexachloro-1,3-butadiene 5.00 U 6.50 6.65 130 133 1 20.0-154 2.28 34
Isopropylbenzene 5.00 0.150 4.96 4.81 96.2 93.2 1 28.0-157 3.07 27
p-Isopropyltoluene 5.00 U 5.44 5.34 109 107 1 30.0-154 1.86 29
2-Butanone (MEK)25.0 U 29.0 26.9 116 108 1 10.0-160 7.51 32
Methylene Chloride 5.00 U 5.95 5.64 119 113 1 23.0-144 5.35 28
4-Methyl-2-pentanone (MIBK)25.0 U 25.2 25.6 101 102 1 29.0-160 1.57 29
Methyl tert-butyl ether 5.00 0.131 5.86 5.69 115 111 1 28.0-150 2.94 29
Naphthalene 5.00 U 4.88 5.10 97.6 102 1 12.0-156 4.41 35
n-Propylbenzene 5.00 0.335 5.68 5.62 107 106 1 31.0-154 1.06 28
Styrene 5.00 U 4.55 4.39 91.0 87.8 1 33.0-155 3.58 28
1,1,1,2-Tetrachloroethane 5.00 U 5.12 5.25 102 105 1 36.0-151 2.51 29
1,1,2,2-Tetrachloroethane 5.00 U 5.98 6.12 120 122 1 33.0-150 2.31 28
Tetrachloroethene 5.00 U 5.48 5.38 110 108 1 10.0-160 1.84 27
Toluene 5.00 0.549 5.51 5.41 99.2 97.2 1 26.0-154 1.83 28
1,2,3-Trichlorobenzene 5.00 U 4.89 5.02 97.8 100 1 17.0-150 2.62 36
1,2,4-Trichlorobenzene 5.00 U 4.94 4.90 98.8 98.0 1 24.0-150 0.813 33
1,1,1-Trichloroethane 5.00 U 6.37 6.34 127 127 1 23.0-160 0.472 28
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-01,02,04
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/05/23 17:48 • (MS) R3887703-3 02/06/23 00:10 • (MSD) R3887703-4 02/06/23 00:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
1,1,2-Trichloroethane 5.00 U 5.28 5.22 106 104 1 35.0-147 1.14 27
Trichloroethene 5.00 U 4.92 5.06 98.4 101 1 10.0-160 2.81 25
Trichlorofluoromethane 5.00 U 6.56 6.66 131 133 1 17.0-160 1.51 31
1,2,3-Trichloropropane 5.00 U 6.18 6.15 124 123 1 34.0-151 0.487 29
1,2,4-Trimethylbenzene 5.00 0.889 6.31 6.30 108 108 1 26.0-154 0.159 27
1,3,5-Trimethylbenzene 5.00 0.308 5.80 5.71 110 108 1 28.0-153 1.56 27
Vinyl chloride 5.00 U 6.17 6.39 123 128 1 10.0-160 3.50 27
o-Xylene 5.00 0.901 5.66 5.46 95.2 91.2 1 45.0-144 3.60 26
m&p-Xylenes 10.0 2.39 12.6 12.1 102 97.1 1 43.0-146 4.05 26
(S) Toluene-d8 90.3 90.9 80.0-120
(S) 4-Bromofluorobenzene 85.2 85.6 77.0-126
(S) 1,2-Dichloroethane-d4 112 108 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-03
Method Blank (MB)
(MB) R3888349-2 02/07/23 09:49
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-03
Method Blank (MB)
(MB) R3888349-2 02/07/23 09:49
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 103 80.0-120
(S) 4-Bromofluorobenzene 98.8 77.0-126
(S) 1,2-Dichloroethane-d4 89.5 70.0-130
Laboratory Control Sample (LCS)
(LCS) R3888349-1 02/07/23 09:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acetone 25.0 29.7 119 19.0-160
Acrolein 25.0 31.2 125 10.0-160
Acrylonitrile 25.0 25.7 103 55.0-149
Benzene 5.00 5.01 100 70.0-123
Bromobenzene 5.00 5.04 101 73.0-121
Bromodichloromethane 5.00 4.69 93.8 75.0-120
Bromoform 5.00 4.23 84.6 68.0-132
n-Butylbenzene 5.00 5.00 100 73.0-125
sec-Butylbenzene 5.00 4.92 98.4 75.0-125
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-03
Laboratory Control Sample (LCS)
(LCS) R3888349-1 02/07/23 09:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
tert-Butylbenzene 5.00 4.73 94.6 76.0-124
Carbon tetrachloride 5.00 4.99 99.8 68.0-126
Chlorobenzene 5.00 5.04 101 80.0-121
Chlorodibromomethane 5.00 4.52 90.4 77.0-125
Chloroform 5.00 4.84 96.8 73.0-120
Chloromethane 5.00 5.83 117 41.0-142
2-Chlorotoluene 5.00 5.11 102 76.0-123
4-Chlorotoluene 5.00 4.96 99.2 75.0-122
1,2-Dibromo-3-Chloropropane 5.00 4.23 84.6 58.0-134
1,2-Dibromoethane 5.00 5.09 102 80.0-122
Dibromomethane 5.00 4.96 99.2 80.0-120
1,2-Dichlorobenzene 5.00 4.75 95.0 79.0-121
1,3-Dichlorobenzene 5.00 4.67 93.4 79.0-120
1,4-Dichlorobenzene 5.00 4.86 97.2 79.0-120
Dichlorodifluoromethane 5.00 6.23 125 51.0-149
1,1-Dichloroethane 5.00 5.35 107 70.0-126
1,2-Dichloroethane 5.00 4.91 98.2 70.0-128
1,1-Dichloroethene 5.00 4.87 97.4 71.0-124
cis-1,2-Dichloroethene 5.00 4.95 99.0 73.0-120
trans-1,2-Dichloroethene 5.00 5.09 102 73.0-120
1,2-Dichloropropane 5.00 4.92 98.4 77.0-125
1,1-Dichloropropene 5.00 5.12 102 74.0-126
1,3-Dichloropropane 5.00 5.05 101 80.0-120
2,2-Dichloropropane 5.00 5.32 106 58.0-130
Di-isopropyl ether 5.00 4.85 97.0 58.0-138
Ethylbenzene 5.00 4.97 99.4 79.0-123
Hexachloro-1,3-butadiene 5.00 5.35 107 54.0-138
Isopropylbenzene 5.00 4.76 95.2 76.0-127
p-Isopropyltoluene 5.00 5.04 101 76.0-125
2-Butanone (MEK)25.0 24.1 96.4 44.0-160
Methylene Chloride 5.00 5.19 104 67.0-120
4-Methyl-2-pentanone (MIBK)25.0 25.3 101 68.0-142
Methyl tert-butyl ether 5.00 4.72 94.4 68.0-125
Naphthalene 5.00 3.97 79.4 54.0-135
n-Propylbenzene 5.00 5.00 100 77.0-124
Styrene 5.00 4.49 89.8 73.0-130
1,1,1,2-Tetrachloroethane 5.00 4.80 96.0 75.0-125
1,1,2,2-Tetrachloroethane 5.00 5.44 109 65.0-130
Tetrachloroethene 5.00 4.85 97.0 72.0-132
Toluene 5.00 5.07 101 79.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-03
Laboratory Control Sample (LCS)
(LCS) R3888349-1 02/07/23 09:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
1,2,3-Trichlorobenzene 5.00 4.46 89.2 50.0-138
1,2,4-Trichlorobenzene 5.00 4.13 82.6 57.0-137
1,1,1-Trichloroethane 5.00 4.89 97.8 73.0-124
1,1,2-Trichloroethane 5.00 5.06 101 80.0-120
Trichloroethene 5.00 4.58 91.6 78.0-124
Trichlorofluoromethane 5.00 6.29 126 59.0-147
1,2,3-Trichloropropane 5.00 5.53 111 73.0-130
1,2,4-Trimethylbenzene 5.00 4.89 97.8 76.0-121
1,3,5-Trimethylbenzene 5.00 4.89 97.8 76.0-122
Vinyl chloride 5.00 6.26 125 67.0-131
o-Xylene 5.00 4.93 98.6 80.0-122
m&p-Xylenes 10.0 10.1 101 80.0-122
(S) Toluene-d8 101 80.0-120
(S) 4-Bromofluorobenzene 100 77.0-126
(S) 1,2-Dichloroethane-d4 90.7 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001829
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580432-03
Method Blank (MB)
(MB) R3888368-5 02/07/23 12:57
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Bromomethane U 0.605 5.00
Chloroethane U 0.192 5.00
(S) Toluene-d8 91.5 80.0-120
(S) 4-Bromofluorobenzene 86.8 77.0-126
(S) 1,2-Dichloroethane-d4 105 70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3888368-1 02/07/23 10:25 • (LCSD) R3888368-2 02/07/23 10:46
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Bromomethane 5.00 6.24 6.08 125 122 10.0-160 2.60 25
Chloroethane 5.00 6.51 6.34 130 127 47.0-150 2.65 20
(S) Toluene-d8 91.4 90.2 80.0-120
(S) 4-Bromofluorobenzene 82.1 81.8 77.0-126
(S) 1,2-Dichloroethane-d4 112 111 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec.Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Dilution
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Limits
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
Qualifier
This column provides a letter and/or number designation that corresponds to additional information concerning the result
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
Result
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL”
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)Confidence level of 2 sigma.
Case Narrative (Cn)
A brief discussion about the included sample results, including a discussion of any non-conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
Summary (Qc)
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
Sample Chain of
Custody (Sc)
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
Sample Results (Sr)
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
B The same analyte is found in the associated blank.
C4 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low.
Data is likely to show a low bias concerning the result.
J The identification of the analyte is acceptable; the reported value is an estimate.
J3 The associated batch QC was outside the established quality control range for precision.
J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.
J-The associated batch QC was outside the lower control limits; associated data has a potential negative bias.
K1 The sample dilutions set-up for the BOD/CBOD analysis did not meet the oxygen depletion criteria of at least 2 mg/L. Reported result is an estimated value.
K6 Glucose/glutamic acid BOD/CBOD was below method acceptance criteria.
P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.
T8 Sample(s) received past/too close to holding time expiration.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN000032021-1
Arizona AZ0612 New Hampshire 2975
Arkansas 88-0469 New Jersey–NELAP TN002
California 2932 New Mexico ¹TN00003
Colorado TN00003 New York 11742
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina ¹DW21704
Georgia NELAP North Carolina ³41
Georgia ¹923 North Dakota R-140
Idaho TN00003 Ohio–VAP CL0069
Illinois 200008 Oklahoma 9915
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979
Kansas E-10277 Rhode Island LAO00356
Kentucky ¹ ⁶KY90010 South Carolina 84004002
Kentucky ²16 South Dakota n/a
Louisiana AI30792 Tennessee ¹ ⁴2006
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas ⁵LAB0152
Maryland 324 Utah TN000032021-11
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033
Minnesota 047-999-395 Washington C847
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA – ISO 17025 ⁵1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA–Crypto TN00003
ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Chevron - 205513

DATA REVIEW
High point

Volatile organic compounds, Dissolved gases, Metals and General Chemistry

SDG# L1580432

Analyses Performed By:
Pace Analytical National
Mount Juliet, TN 37122

Report # 48698R
Review Level: Tier II
Project: 30064349.19.61

DATA REVIEW REPORT
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SUMMARY
This data quality assessment summarizes the review of Sample Delivery Groups (SDGs) # L1580432
for samples collected in association with the Chevron 205513 High Point Site. The review was conducted as a Tier II evaluation and included review of data package completeness. Only analytical data associated with constituents of concern were reviewed for this validation. Field documentation was not included in this review. Included with this assessment are the validation annotated sample result sheets and chain of custody. Analyses were performed on the following samples:
Sample ID Lab ID Matrix Sample Collection Date Parent Sample Analysis
VOC RSK175 Met. Misc.
MW-3-W-20230126 L1580432-01 Water 01/26/2023 X X X X
MW-4D-W-20230126 L1580432-02 Water 01/26/2023 X X X X
MW-7-W-20230126 L1580432-03 Water 01/26/2023 X X X X
FB-2-W-20230126 L1580432-04 Water 01/26/2023 X X X X

Notes:
VOC = volatile organic compounds.
RSK 175 = Dissolved Gases
Met = Metals
Misc. = General Chemistry

DATA REVIEW REPORT
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ANALYTICAL DATA PACKAGE DOCUMENTATION
The table below is the evaluation of the data package completeness.
Items Reviewed Reported Performance Acceptable Not Required No Yes No Yes
1. Sample receipt condition X X
2. Requested analyses and sample results X X
3. Master tracking list X X
4. Methods of analysis X X
5. Reporting limits X X
6. Sample collection date X X
7. Laboratory sample received date X X
8. Sample preservation verification (as applicable) X X
9. Sample preparation/extraction/analysis dates X X
10. Fully executed Chain-of-Custody (COC) form X X
11. Narrative summary of QA or sample problems provided X X
12. Data Package Completeness and Compliance X X
Note: QA - Quality Assurance
DATA REVIEW REPORT
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ORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6200B. Data were reviewed in accordance with the method specified criteria, USEPA National
Functional Guidelines NFG for Organic Superfund Methods Data Review, EPA-540-R-20-005 (November
2020), with reference to the historical (USEPA Contract Laboratory Program National Functional
Guidelines for Organic Data Review, OSWER 9240.1-05A-P, October 1999, as appropriate).
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and had already been subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with USEPA National Functional
Guidelines:
• Concentration (C) Qualifiers
U The compound was analyzed for but not detected. The associated value is the compound
quantitation limit.
B The compound has been found in the sample as well as its associated blank, its presence in
the sample may be suspect.
• Quantitation (Q) Qualifiers
E The compound was quantitated above the calibration range.
D Concentration is based on a diluted sample analysis.
• Validation Qualifiers
J The compound was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The compound was not detected above the reported sample quantitation limit. However, the
reported limit is approximate and may or may not represent the actual limit of quantitation.
JN The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification. The associated numerical value is an estimated concentration
only.
UB Compound considered non-detect at the listed value due to associated blank contamination.
N The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
DATA REVIEW REPORT
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that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

DATA REVIEW REPORT
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VOLATILE ORGANIC COMPOUND (VOC) ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
SW-846 6200B Water 14 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2 s.u.
Note:
s.u. Standard units
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds 2-butanone (MEK) and toluene were detected in the associated QA blanks; however, the
associated sample results were greater than the BAL and/or were non-detect. Therefore, sample results
greater than the BAL resulted in the removal of the laboratory qualifier (B). No other qualification of the
sample results was required.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique. VOC
analysis requires that all surrogates associated with the analysis exhibit recoveries within the laboratory-
established acceptance limits.
All surrogate recoveries were within the control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analyses
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit a percent recovery within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS/MSD recoveries must exhibit
an RPD within the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on sample locations
where the compound concentration detected in the parent sample exceeds the MS/MSD concentration by
a factor of four or greater.
MS/MSD analysis was not performed on any of the samples from this SDG.

DATA REVIEW REPORT
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5. Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Analysis
The LCS/LCSD analysis is used to assess the precision and accuracy of the analytical method
independent of matrix interferences. The compounds associated with the LCS/LCSD analysis must
exhibit a percent recovery within the laboratory-established acceptance limits.
All compounds associated with the LCS/LCSD analysis exhibited recoveries within the control limits.
6. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to 5 times the RL, a control limit of two times the RL is applied for water matrices.
Field duplicate sample was not collected from this SDG.

7. System Performance and Overall Assessment
The case narrative noted that the CCVs for acrolein were outside the control limit with a high bias. The
associated field samples MW-3-W-20230126, MW-4D-W-20230126 and FB-2-W-20230126 were qualified
as estimated (UJ) for the above listed compound.
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.
DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR VOCs

VOCs: SW-846 8260B Reported Performance
Acceptable Not
Required No Yes No Yes
GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS)
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
C. Trip blanks X X
Laboratory Control Sample (LCS) X X
Laboratory Control Sample Duplicate(LCSD) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) X X
Matrix Spike Duplicate (MSD) X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Surrogate Spike Recoveries X X
Dilution Factor X X
Notes:
%R Percent recovery
RPD Relative percent difference

DATA REVIEW REPORT
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DISSOLVED GASES ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
RSK-175 Water 14 days from collection to analysis Cool to < 6 °C; pH > 10 with TSP
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e. method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds were not detected above the SDL in the associated blanks; therefore, detected sample
results were not associated with blank contamination.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique.
Dissolved gases analysis requires that all surrogates associated with the analysis exhibit recoveries
within the laboratory-established acceptance limits.
All surrogate recoveries were within control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analysis
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit recoveries within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS and MSD results must be within
the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on samples where the
compound concentration detected in the parent sample exceeds the MS/MSD concentration by a factor of
four or greater.
The MS/MSD analysis was not performed on any of the sample from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The compounds associated with the LCS analysis must exhibit a percent recovery within
the laboratory-established acceptance limits.
DATA REVIEW REPORT
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All compounds associated with the LCS analysis exhibited recoveries within the control limits.
6. Field Duplicate Sample Analysis
The field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 25% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to five times the RL, a control limit of two times the RL is applied to the difference
between the results for water matrices.
Field duplicate sample was not collected from this SDG.
7. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR DISSOLVED GASES

Dissolved Gases: RSK-175 Reported Performance Acceptable Not Required No Yes No Yes
Gas Chromatography/Thermal Conductivity Detector (GC/TCD)
Tier II Validation
Holding times/Temperature/Preservation X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
Laboratory Control Sample (LCS) Accuracy (%R) X X
Laboratory Control Sample Duplicate (LCSD) (%R) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike Sample (MS) (%R) X X
Matrix Spike Duplicate Sample (MSD) (%R) X X
MS/MSD Precision (RPD) X X
Laboratory Duplicate Sample (RPD) X X
Field Duplicate Sample (RPD) X X
Surrogate Spike Recoveries (%R) X X
Dilution Factor X X
Notes: %R Percent recovery RPD Relative percent difference
DATA REVIEW REPORT
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INORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6010D, 2320B, 4500, 350.1, 3500Fe, 351.2, 353.2,410.4, 4500S2, 5210B, 9056A and 9060A.
Data were reviewed in accordance with USEPA National Functional Guidelines of October 2004.
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and that it was already subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with the USEPA National
Functional Guidelines:
• Concentration (C) Qualifiers
U The analyte was analyzed for but not detected. The associated value is the analyte
instrument detection limit.
J The reported value was obtained from a reading less than the reporting limit (RL), but
greater than or equal to the method detection limit (MDL).
• Quantitation (Q) Qualifiers
E The reported value is estimated due to the presence of interference.
N Spiked sample recovery is not within control limits.
* Duplicate analysis is not within control limits.
• Validation Qualifiers
J The analyte was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The analyte was not detected above the reporting limit. However, the reported limit is
approximate and may or may not represent the actual limit of detection.
UB Analyte is considered non-detect at the listed value due to associated blank contamination.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

DATA REVIEW REPORT
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METALS ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
SW-846 6010D Water 180 days from collection to analysis Preserved to a pH of less
than 2.
All samples were analyzed within the specified holding times.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
Analyte manganese was detected in the associated QA blanks; however, the associated sample results
were greater than the BAL. Therefore, sample results greater than the BAL resulted in the removal of the
laboratory qualifier (B). No other qualification of the sample results was required.
3. Matrix Spike / Matrix Spike Duplicate (MS/MSD) /Laboratory Duplicate Analysis
MS/MSD and laboratory duplicate data are used to assess the precision and accuracy of the analytical
method.
3.1 MS/MSD Analysis
All metal analytes must exhibit a percent recovery within the established acceptance limits of 75% to
125%. The MS recovery control limits do not apply for MS performed on sample locations where the
analyte’s concentration detected in the parent sample exceeds the MS concentration by a factor of four or
greater.
The MS/MSD analysis was not performed on any of the samples from this SDG.
3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was not performed on any of the samples from this SDG.
4. Field Duplicate Analysis
DATA REVIEW REPORT
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Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices and 50% for soil matrices is applied to the
RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Field duplicate sample was not collected from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
The LCS analysis exhibited recoveries within the control limits.
8. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR METAL

METALS; SW-846 6010D Reported
Performance
Acceptable Not
Required No Yes No Yes
Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES)
Tier II Validation
Holding Times X X
Reporting limits (units) X X
Blanks
A. Instrument Blanks X X
B. Method Blanks X X
C. Equipment/Field Blanks X X
Laboratory Control Sample (LCS) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate (MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Reporting Limit Verification X X
Notes:
%R = Percent recovery
RPD = Relative percent difference

DATA REVIEW REPORT
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GENERAL CHEMISTRY ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
Alkalinity by SM 2320 B-11 Water 14 days from collection to
analysis Cool to <6 °C.
Free Carbon Dioxide by 4500CO2 Water 24 hours from collection to
analysis
Preserved to a pH of less
than 2.
Ammonia Nitrogen by 350.1 Water 28 days from collection to
analysis
Preserved to a pH of less
than 2.
Ferrous iron by 3500Fe Water 24 hours from collection to
analysis
Preserved to a pH of less
than 2.
Total Kjeldahl Nitrogen
by EPA 351.2 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Nitrogen, Nitrate-N + Nitrite-N
(combined result) by EPA 353.2 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Chemical Oxygen Demand (COD) by
SM5220 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Sulfide by 4500S2 Water 15 mins from collection to
analysis
Preserved to a pH of less
than 2.
Biological Oxygen Demand (BOD) by
SM5210 B-11 Water 48 hours from collection to
analysis Cool to <6 °C.
Sulfate by SW-846 300/9056A Water 28 days from collection to
analysis Cool to <6 °C.
Total Organic Carbon by SM5310 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
The analyses that exceeded the holding time are presented in the following table.
DATA REVIEW REPORT
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Sample Locations Analyte Holding Time Criteria
MW-3-W-20230126
MW-4D-W-20230126
MW-7-W-20230126
FB-2-W-20230126
Free Carbon Dioxide Analysis completed less
than two times holding time 24 hours from collection to analysis Ferrous Iron
Sulfide Analysis completed greater
than two times holding time 15 mins from collection to analysis
Sample results associated with sample locations analyzed by analytical methods mentioned above were
qualified, as specified in the table below. All other holding times were met.

Criteria
Qualification
Detected
Analytes
Non-detect
Analytes
Analysis completed less than two times holding time J UJ

2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
All analytes associated with the QA blanks exhibited a concentration less than the MDL, with the
exception of the analytes listed in the following table. Sample results associated with QA blank
contamination that were greater than the BAL resulted in the removal of the laboratory qualifier (B) of
data. Sample results less than the BAL associated with the following sample locations were qualified as
listed in the following table.

DATA REVIEW REPORT
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Sample Locations Analytes Sample Result Qualificatio
n
MW-4D-W-20230126 Free Carbon Dioxide (FB, MB) Detected sample results <RL and
<BAL “UB” at the RL
Note:
RL Reporting limit
3. Matrix Spike (MS)/Laboratory Duplicate Analysis
MS and laboratory duplicate data are used to assess the precision and accuracy of the analytical method.
3.1 MS Analysis
All analytes must exhibit a percent recovery within the established acceptance limits of 75% to 125%.
The MS recovery control limits do not apply for MS performed on sample locations where the analyte’s
concentration detected in the parent sample exceeds the MS concentration by a factor of four or greater.
In instance where this is true, the data will not be qualified even if the percent recovery does not meet the
control limits and the laboratory flag will be removed.
The MS/MSD analysis was not performed on any of the samples from this SDG.
3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was performed on sample ID MW-3-W-20230126, exhibited acceptable
RPDs.
4. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 50% for water matrices and 100% for soil matrices is applied to the
RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Field duplicate sample was not collected from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
All LCS recoveries were within control limits, with the exception of the analytes associated with sample
locations, as presented in the following table.
Sample Location Analytes LCS Recovery
MW-3-W-20230126
MW-4D-W-20230126 BOD <LL but >10%
DATA REVIEW REPORT
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Sample Location Analytes LCS Recovery
MW-7-W-20230126
FB-2-W-20230126
The criteria used to evaluate LCS recoveries are presented in the following table. In the case of an LCS
deviation, the sample results are qualified.
Control Limit Sample Result Qualification
> the upper control limit (UL) Non-detect No Action
Detect J
< the lower control limit (LL) but > 10% Non-detect UJ
Detect J
< 10% Non-detect R
Detect J

6. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR GENERAL CHEMISTRY

General Chemistry Reported Performance
Acceptable Not
Required No Yes No Yes
Miscellaneous Instrumentation
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
D. Method blanks X X
E. Equipment blanks X X
Laboratory Control Sample (LCS) %R X X
Laboratory Control Sample Duplicate(LCSD) %R X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate(MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Dilution Factor X X
Moisture Content X X
Notes:
%R - percent recovery
RPD - relative percent difference,
%D – difference

DATA REVIEW REPORT
arcadis.com

VALIDATION PERFORMED BY: Bhagyashree Fulzele
SIGNATURE:
DATE: February 21, 2023

PEER REVIEW: Dennis Capria
DATE: March 2, 2023

CHAIN OF CUSTODY
CORRECTED SAMPLE ANALYSIS DATA
SHEETS

SAMPLE RESULTS - 01
L1580432
MW-3-W-20230126
Collected date/time: 01/26/23 09:44
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 452 15.0 50.0 1 01/31/2023 08:04 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:44 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 98100 20000 1 02/06/2023 14:49 WG2000611
Free Carbon Dioxide 61100 B T8 20000 1 02/06/2023 14:49 WG2000611
Sample Narrative:
L1580432-01 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:31 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 34.0 J T8 15.0 50.0 1 01/30/2023 16:34 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:44 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 3330 50.0 100 1 02/01/2023 20:34 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 17:56 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:33 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K6 T8 2.00 1 02/05/2023 08:11 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1580432
MW-3-W-20230126
Collected date/time: 01/26/23 09:44
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 3420 T8 48.0 100 1 01/31/2023 14:58 WG1997393
Nitrite U T8 42.0 100 1 01/31/2023 14:58 WG1997393
Sulfate 100000 T8 594 5000 1 01/31/2023 14:58 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)1190 B 102 1000 1 01/31/2023 08:16 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 486 18.0 100 1 01/31/2023 08:04 WG1996965
Manganese 11.0 0.934 10.0 1 01/31/2023 08:04 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 11:55 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 15:58 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 15:58 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 15:58 WG2000115
Benzene 0.609 J 0.0941 1.00 1 02/05/2023 15:58 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 15:58 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 15:58 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 15:58 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 15:58 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 15:58 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 15:58 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 15:58 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 15:58 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 15:58 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 15:58 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 15:58 WG2000115
Chloroform U 0.111 5.00 1 02/05/2023 15:58 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 15:58 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 15:58 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 15:58 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 15:58 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 15:58 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 15:58 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 15:58 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 15:58 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 15:58 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 15:58 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 15:58 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 15:58 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 15:58 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 15:58 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 15:58 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 01
L1580432
MW-3-W-20230126
Collected date/time: 01/26/23 09:44
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 15:58 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 15:58 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 15:58 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 15:58 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 15:58 WG2000115
Ethylbenzene 0.244 J 0.137 1.00 1 02/05/2023 15:58 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 15:58 WG2000115
Isopropylbenzene U 0.105 1.00 1 02/05/2023 15:58 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 15:58 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 15:58 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 15:58 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 15:58 WG2000115
Methyl tert-butyl ether U 0.101 1.00 1 02/05/2023 15:58 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 15:58 WG2000115
n-Propylbenzene U 0.0993 1.00 1 02/05/2023 15:58 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 15:58 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 15:58 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 15:58 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 15:58 WG2000115
Toluene U 0.278 1.00 1 02/05/2023 15:58 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 15:58 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 15:58 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 15:58 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 15:58 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 15:58 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 15:58 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 15:58 WG2000115
1,2,4-Trimethylbenzene U 0.322 1.00 1 02/05/2023 15:58 WG2000115
1,3,5-Trimethylbenzene U 0.104 1.00 1 02/05/2023 15:58 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 15:58 WG2000115
o-Xylene 0.174 J 0.174 1.00 1 02/05/2023 15:58 WG2000115
m&p-Xylenes U 0.430 2.00 1 02/05/2023 15:58 WG2000115
(S) Toluene-d8 91.6 80.0-120 02/05/2023 15:58 WG2000115
(S) 4-Bromofluorobenzene 84.6 77.0-126 02/05/2023 15:58 WG2000115
(S) 1,2-Dichloroethane-d4 110 70.0-130 02/05/2023 15:58 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 02
L1580432
MW-4D-W-20230126
Collected date/time: 01/26/23 13:50
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 38.6 J 15.0 50.0 1 01/31/2023 08:12 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:45 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 71500 20000 1 02/06/2023 14:54 WG2000611
Free Carbon Dioxide 64400 B T8 20000 1 02/06/2023 14:54 WG2000611
Sample Narrative:
L1580432-02 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:34 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/30/2023 16:35 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:45 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 2760 50.0 100 1 02/01/2023 20:35 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:34 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 2.94 K1 K6 T8 2.00 1 02/05/2023 08:15 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 02
L1580432
MW-4D-W-20230126
Collected date/time: 01/26/23 13:50
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 4670 T8 48.0 100 1 01/31/2023 15:10 WG1997393
Nitrite 85.4 J T8 42.0 100 1 01/31/2023 15:10 WG1997393
Sulfate 12300 T8 594 5000 1 01/31/2023 15:10 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)912 B J 102 1000 1 01/31/2023 08:48 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 38.6 J 18.0 100 1 01/31/2023 08:12 WG1996965
Manganese 473 0.934 10.0 1 01/31/2023 08:12 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 13:14 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 16:47 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 16:47 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 16:47 WG2000115
Benzene 2.82 0.0941 1.00 1 02/05/2023 16:47 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 16:47 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 16:47 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 16:47 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 16:47 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 16:47 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 16:47 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 16:47 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 16:47 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 16:47 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 16:47 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 16:47 WG2000115
Chloroform 0.594 J 0.111 5.00 1 02/05/2023 16:47 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 16:47 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 16:47 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 16:47 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 16:47 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 16:47 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 16:47 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 16:47 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 16:47 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 16:47 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 16:47 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 16:47 WG2000115
1,2-Dichloroethane 0.495 J 0.0819 1.00 1 02/05/2023 16:47 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 16:47 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 16:47 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 16:47 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 10 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 10 of 49
SAMPLE RESULTS - 02
L1580432
MW-4D-W-20230126
Collected date/time: 01/26/23 13:50
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 16:47 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 16:47 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 16:47 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 16:47 WG2000115
Di-isopropyl ether 0.523 J 0.105 1.00 1 02/05/2023 16:47 WG2000115
Ethylbenzene 0.874 J 0.137 1.00 1 02/05/2023 16:47 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 16:47 WG2000115
Isopropylbenzene U 0.105 1.00 1 02/05/2023 16:47 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 16:47 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 16:47 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 16:47 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 16:47 WG2000115
Methyl tert-butyl ether 7.21 0.101 1.00 1 02/05/2023 16:47 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 16:47 WG2000115
n-Propylbenzene U 0.0993 1.00 1 02/05/2023 16:47 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 16:47 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 16:47 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 16:47 WG2000115
Tetrachloroethene 0.651 J 0.300 1.00 1 02/05/2023 16:47 WG2000115
Toluene U 0.278 1.00 1 02/05/2023 16:47 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 16:47 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 16:47 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 16:47 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 16:47 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 16:47 WG2000115
Trichlorofluoromethane 1.59 J 0.160 5.00 1 02/05/2023 16:47 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 16:47 WG2000115
1,2,4-Trimethylbenzene 0.322 J 0.322 1.00 1 02/05/2023 16:47 WG2000115
1,3,5-Trimethylbenzene U 0.104 1.00 1 02/05/2023 16:47 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 16:47 WG2000115
o-Xylene 0.311 J 0.174 1.00 1 02/05/2023 16:47 WG2000115
m&p-Xylenes 0.848 J 0.430 2.00 1 02/05/2023 16:47 WG2000115
(S) Toluene-d8 88.8 80.0-120 02/05/2023 16:47 WG2000115
(S) 4-Bromofluorobenzene 79.1 77.0-126 02/05/2023 16:47 WG2000115
(S) 1,2-Dichloroethane-d4 109 70.0-130 02/05/2023 16:47 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 11 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 11 of 49
SAMPLE RESULTS - 03
L1580432
MW-7-W-20230126
Collected date/time: 01/26/23 11:36
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/31/2023 08:15 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:46 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 241000 20000 1 02/06/2023 14:59 WG2000611
Free Carbon Dioxide 144000 T8 20000 1 02/06/2023 14:59 WG2000611
Sample Narrative:
L1580432-03 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:36 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 5420 T8 150 500 10 01/30/2023 16:44 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:46 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 02/01/2023 20:36 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 101000 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:34 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 14.1 K1 K6 T8 2.00 1 02/05/2023 08:19 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 12 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 12 of 49
SAMPLE RESULTS - 03
L1580432
MW-7-W-20230126
Collected date/time: 01/26/23 11:36
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/31/2023 15:23 WG1997393
Nitrite U T8 42.0 100 1 01/31/2023 15:23 WG1997393
Sulfate U T8 594 5000 1 01/31/2023 15:23 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)13700 102 1000 1 01/31/2023 09:05 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 4970 18.0 100 1 01/31/2023 08:15 WG1996965
Manganese 16200 4.67 50.0 5 02/01/2023 02:34 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 205 2.91 10.0 1 01/31/2023 13:21 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 1130 5000 100 02/07/2023 15:25 WG2000693
Acrolein U 254 5000 100 02/07/2023 15:25 WG2000693
Acrylonitrile U 67.1 1000 100 02/07/2023 15:25 WG2000693
Benzene 7500 9.41 100 100 02/07/2023 15:25 WG2000693
Bromobenzene U 11.8 100 100 02/07/2023 15:25 WG2000693
Bromodichloromethane U 13.6 100 100 02/07/2023 15:25 WG2000693
Bromoform U 12.9 100 100 02/07/2023 15:25 WG2000693
Bromomethane U 60.5 500 100 02/07/2023 16:13 WG2001829
n-Butylbenzene U 15.7 100 100 02/07/2023 15:25 WG2000693
sec-Butylbenzene U 12.5 100 100 02/07/2023 15:25 WG2000693
tert-Butylbenzene U 12.7 100 100 02/07/2023 15:25 WG2000693
Carbon tetrachloride U 12.8 100 100 02/07/2023 15:25 WG2000693
Chlorobenzene U 11.6 100 100 02/07/2023 15:25 WG2000693
Chlorodibromomethane U 14.0 100 100 02/07/2023 15:25 WG2000693
Chloroethane U 19.2 500 100 02/07/2023 16:13 WG2001829
Chloroform U 11.1 500 100 02/07/2023 15:25 WG2000693
Chloromethane U 96.0 250 100 02/07/2023 15:25 WG2000693
2-Chlorotoluene U 10.6 100 100 02/07/2023 15:25 WG2000693
4-Chlorotoluene U 11.4 100 100 02/07/2023 15:25 WG2000693
1,2-Dibromo-3-Chloropropane U 27.6 500 100 02/07/2023 15:25 WG2000693
1,2-Dibromoethane U 12.6 100 100 02/07/2023 15:25 WG2000693
Dibromomethane U 12.2 100 100 02/07/2023 15:25 WG2000693
1,2-Dichlorobenzene U 10.7 100 100 02/07/2023 15:25 WG2000693
1,3-Dichlorobenzene U 11.0 100 100 02/07/2023 15:25 WG2000693
1,4-Dichlorobenzene U 12.0 100 100 02/07/2023 15:25 WG2000693
Dichlorodifluoromethane U 37.4 500 100 02/07/2023 15:25 WG2000693
1,1-Dichloroethane U 10.0 100 100 02/07/2023 15:25 WG2000693
1,2-Dichloroethane 102 8.19 100 100 02/07/2023 15:25 WG2000693
1,1-Dichloroethene U 18.8 100 100 02/07/2023 15:25 WG2000693
cis-1,2-Dichloroethene U 12.6 100 100 02/07/2023 15:25 WG2000693
trans-1,2-Dichloroethene U 14.9 100 100 02/07/2023 15:25 WG2000693
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 13 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 13 of 49
SAMPLE RESULTS - 03
L1580432
MW-7-W-20230126
Collected date/time: 01/26/23 11:36
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 14.9 100 100 02/07/2023 15:25 WG2000693
1,1-Dichloropropene U 14.2 100 100 02/07/2023 15:25 WG2000693
1,3-Dichloropropane U 11.0 100 100 02/07/2023 15:25 WG2000693
2,2-Dichloropropane U 16.1 100 100 02/07/2023 15:25 WG2000693
Di-isopropyl ether 31.6 J 10.5 100 100 02/07/2023 15:25 WG2000693
Ethylbenzene 2230 13.7 100 100 02/07/2023 15:25 WG2000693
Hexachloro-1,3-butadiene U 33.7 100 100 02/07/2023 15:25 WG2000693
Isopropylbenzene 79.3 J 10.5 100 100 02/07/2023 15:25 WG2000693
p-Isopropyltoluene U 12.0 100 100 02/07/2023 15:25 WG2000693
2-Butanone (MEK)U 119 1000 100 02/07/2023 15:25 WG2000693
Methylene Chloride U 43.0 500 100 02/07/2023 15:25 WG2000693
4-Methyl-2-pentanone (MIBK)U 47.8 1000 100 02/07/2023 15:25 WG2000693
Methyl tert-butyl ether 3160 10.1 100 100 02/07/2023 15:25 WG2000693
Naphthalene 235 J 100 500 100 02/07/2023 15:25 WG2000693
n-Propylbenzene 167 9.93 100 100 02/07/2023 15:25 WG2000693
Styrene U 11.8 100 100 02/07/2023 15:25 WG2000693
1,1,1,2-Tetrachloroethane U 14.7 100 100 02/07/2023 15:25 WG2000693
1,1,2,2-Tetrachloroethane U 13.3 100 100 02/07/2023 15:25 WG2000693
Tetrachloroethene U 30.0 100 100 02/07/2023 15:25 WG2000693
Toluene 94.2 J 27.8 100 100 02/07/2023 15:25 WG2000693
1,2,3-Trichlorobenzene U 23.0 100 100 02/07/2023 15:25 WG2000693
1,2,4-Trichlorobenzene U 48.1 100 100 02/07/2023 15:25 WG2000693
1,1,1-Trichloroethane U 14.9 100 100 02/07/2023 15:25 WG2000693
1,1,2-Trichloroethane U 15.8 100 100 02/07/2023 15:25 WG2000693
Trichloroethene U 19.0 100 100 02/07/2023 15:25 WG2000693
Trichlorofluoromethane U 16.0 500 100 02/07/2023 15:25 WG2000693
1,2,3-Trichloropropane U 23.7 250 100 02/07/2023 15:25 WG2000693
1,2,4-Trimethylbenzene 407 32.2 100 100 02/07/2023 15:25 WG2000693
1,3,5-Trimethylbenzene 177 10.4 100 100 02/07/2023 15:25 WG2000693
Vinyl chloride U 23.4 100 100 02/07/2023 15:25 WG2000693
o-Xylene 273 17.4 100 100 02/07/2023 15:25 WG2000693
m&p-Xylenes 969 43.0 200 100 02/07/2023 15:25 WG2000693
(S) Toluene-d8 103 80.0-120 02/07/2023 15:25 WG2000693
(S) Toluene-d8 90.8 80.0-120 02/07/2023 16:13 WG2001829
(S) 4-Bromofluorobenzene 98.8 77.0-126 02/07/2023 15:25 WG2000693
(S) 4-Bromofluorobenzene 84.3 77.0-126 02/07/2023 16:13 WG2001829
(S) 1,2-Dichloroethane-d4 90.1 70.0-130 02/07/2023 15:25 WG2000693
(S) 1,2-Dichloroethane-d4 103 70.0-130 02/07/2023 16:13 WG2001829
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 14 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 14 of 49
SAMPLE RESULTS - 04
L1580432
FB-2-W-20230126
Collected date/time: 01/26/23 14:30
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 15.0 50.0 1 01/31/2023 08:18 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:48 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity U 20000 1 02/06/2023 15:03 WG2000611
Free Carbon Dioxide ND T8 20000 1 02/06/2023 15:03 WG2000611
Sample Narrative:
L1580432-04 WG2000611: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:37 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/30/2023 16:44 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:48 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 02/01/2023 20:37 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:34 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K1 K6 T8 2.00 1 02/05/2023 08:24 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 15 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 15 of 49
SAMPLE RESULTS - 04
L1580432
FB-2-W-20230126
Collected date/time: 01/26/23 14:30
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/31/2023 15:35 WG1997393
Nitrite U T8 42.0 100 1 01/31/2023 15:35 WG1997393
Sulfate U T8 594 5000 1 01/31/2023 15:35 WG1997393
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)197 B J 102 1000 1 01/31/2023 09:21 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron U 18.0 100 1 01/31/2023 08:18 WG1996965
Manganese 1.18 J 0.934 10.0 1 01/31/2023 08:18 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 13:24 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 17:07 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 17:07 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 17:07 WG2000115
Benzene U 0.0941 1.00 1 02/05/2023 17:07 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 17:07 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 17:07 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 17:07 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 17:07 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 17:07 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 17:07 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 17:07 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 17:07 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 17:07 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 17:07 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 17:07 WG2000115
Chloroform U 0.111 5.00 1 02/05/2023 17:07 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 17:07 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 17:07 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 17:07 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 17:07 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 17:07 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 17:07 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 17:07 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 17:07 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 17:07 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 17:07 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 17:07 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 17:07 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 17:07 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 17:07 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 17:07 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:03 16 of 49
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580432 02/07/23 20:34 16 of 49
SAMPLE RESULTS - 04
L1580432
FB-2-W-20230126
Collected date/time: 01/26/23 14:30
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 17:07 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 17:07 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 17:07 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 17:07 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 17:07 WG2000115
Ethylbenzene U 0.137 1.00 1 02/05/2023 17:07 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 17:07 WG2000115
Isopropylbenzene U 0.105 1.00 1 02/05/2023 17:07 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 17:07 WG2000115
2-Butanone (MEK)2.24 J 1.19 10.0 1 02/05/2023 17:07 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 17:07 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 17:07 WG2000115
Methyl tert-butyl ether U 0.101 1.00 1 02/05/2023 17:07 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 17:07 WG2000115
n-Propylbenzene U 0.0993 1.00 1 02/05/2023 17:07 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 17:07 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 17:07 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 17:07 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 17:07 WG2000115
Toluene 0.470 J 0.278 1.00 1 02/05/2023 17:07 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 17:07 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 17:07 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 17:07 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 17:07 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 17:07 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 17:07 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 17:07 WG2000115
1,2,4-Trimethylbenzene U 0.322 1.00 1 02/05/2023 17:07 WG2000115
1,3,5-Trimethylbenzene U 0.104 1.00 1 02/05/2023 17:07 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 17:07 WG2000115
o-Xylene U 0.174 1.00 1 02/05/2023 17:07 WG2000115
m&p-Xylenes U 0.430 2.00 1 02/05/2023 17:07 WG2000115
(S) Toluene-d8 92.1 80.0-120 02/05/2023 17:07 WG2000115
(S) 4-Bromofluorobenzene 81.8 77.0-126 02/05/2023 17:07 WG2000115
(S) 1,2-Dichloroethane-d4 108 70.0-130 02/05/2023 17:07 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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ANALYTICAL REPORT
February 16, 2023
Arcadis - Chevron - NC
Sample Delivery Group:L1580443
Samples Received:01/30/2023
Project Number:30064349
Description:Pod 2 - High Point, NC #205513
Site:205513
Report To:Andrew DrMarco
801 Corporate Center Drive
Suite 300
Raleigh, NC 27607
Entire Report Reviewed By:
February 16, 2023
[Preliminary Report]
Chris McCord
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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February 16, 2023
Chris McCord
Project Manager
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TABLE OF CONTENTS
Cp: Cover Page 1
Tc: Table of Contents 2
Ss: Sample Summary 3
Cn: Case Narrative 5
Sr: Sample Results 6
MW-9-W-20230127 L1580443-01 6
MW-6-W-20230127 L1580443-02 9
MW-5-W-20230127 L1580443-03 12
Qc: Quality Control Summary 15
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 15
Wet Chemistry by Method 350.1 17
Wet Chemistry by Method 3500Fe B-2011 18
Wet Chemistry by Method 351.2 19
Wet Chemistry by Method 353.2 21
Wet Chemistry by Method 410.4 23
Wet Chemistry by Method 4500S2 D-2011 24
Wet Chemistry by Method 5210 B-2016 25
Wet Chemistry by Method 9056A 26
Wet Chemistry by Method 9060A 28
Metals (ICP) by Method 6010D 29
Volatile Organic Compounds (GC) by Method RSK175 30
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 31
Gl: Glossary of Terms 42
Al: Accreditations & Locations 44
Sc: Sample Chain of Custody 45
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW-9-W-20230127 L1580443-01 GW Ariel Guggino-Boyd 01/27/23 09:42 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996965 1 01/31/23 08:20 01/31/23 08:20 ABL Mt. Juliet, TN
Calculated Results WG1997036 1 01/31/23 18:49 01/31/23 18:49 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1998655 1 02/06/23 08:35 02/06/23 08:35 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1998655 1 02/06/23 08:35 02/06/23 08:35 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1997036 1 01/30/23 14:39 01/30/23 14:39 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1996879 10 01/30/23 16:52 01/30/23 16:52 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1997080 1 01/31/23 10:19 01/31/23 18:49 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG2001845 1 02/08/23 21:56 02/08/23 21:56 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1997000 1 01/30/23 14:01 01/30/23 17:57 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1997328 1 01/31/23 11:35 01/31/23 11:35 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1997413 1 01/31/23 12:56 02/05/23 08:28 ABA Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1997192 1 01/31/23 01:48 01/31/23 01:48 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1997261 5 01/31/23 09:38 01/31/23 09:38 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 1 01/30/23 17:49 01/31/23 08:20 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1997438 1 01/31/23 13:56 01/31/23 13:56 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2000693 200 02/07/23 15:47 02/07/23 15:47 JHH Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2001829 200 02/07/23 16:33 02/07/23 16:33 JAH Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW-6-W-20230127 L1580443-02 GW Ariel Guggino-Boyd 01/27/23 12:22 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996965 1 01/31/23 08:23 01/31/23 08:23 ABL Mt. Juliet, TN
Calculated Results WG1997036 1 01/31/23 18:50 01/31/23 18:50 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1998655 1 02/06/23 08:39 02/06/23 08:39 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1998655 1 02/06/23 08:39 02/06/23 08:39 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1997036 1 01/30/23 14:40 01/30/23 14:40 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1996879 1 01/30/23 16:52 01/30/23 16:52 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1997080 1 01/31/23 10:19 01/31/23 18:50 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1997093 1 02/01/23 20:40 02/01/23 20:40 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1997000 1 01/30/23 14:01 01/30/23 18:20 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1997328 1 01/31/23 11:35 01/31/23 11:35 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1997413 1 01/31/23 13:02 02/05/23 08:33 ABA Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1997192 1 01/31/23 02:52 01/31/23 02:52 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1997261 1 01/31/23 10:32 01/31/23 10:32 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 1 01/30/23 17:49 01/31/23 08:23 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1997438 1 01/31/23 13:59 01/31/23 13:59 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2000115 1 02/05/23 17:28 02/05/23 17:28 ACG Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW-5-W-20230127 L1580443-03 GW Ariel Guggino-Boyd 01/27/23 14:35 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996965 1 01/31/23 07:45 01/31/23 07:45 ABL Mt. Juliet, TN
Calculated Results WG1997036 1 01/31/23 18:54 01/31/23 18:54 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1998655 1 02/06/23 08:44 02/06/23 08:44 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1998655 1 02/06/23 08:44 02/06/23 08:44 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1997036 1 01/30/23 14:46 01/30/23 14:46 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1996879 1 01/30/23 16:53 01/30/23 16:53 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1997080 1 01/31/23 10:19 01/31/23 18:54 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1997093 5 02/01/23 20:41 02/01/23 20:41 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1997000 1 01/30/23 14:01 01/30/23 18:29 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1997328 1 01/31/23 11:35 01/31/23 11:35 CAH Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW-5-W-20230127 L1580443-03 GW Ariel Guggino-Boyd 01/27/23 14:35 01/30/23 09:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Wet Chemistry by Method 5210 B-2016 WG1997413 1 01/31/23 13:08 02/05/23 08:37 ABA Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1997192 1 01/31/23 03:07 01/31/23 03:07 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1997261 1 01/31/23 10:48 01/31/23 10:48 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996965 1 01/30/23 17:49 01/31/23 07:45 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1997438 1 01/31/23 14:04 01/31/23 14:04 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG2000115 1 02/05/23 17:48 02/05/23 17:48 ACG Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
[Preliminary Report]
Chris McCord
Project Manager
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Chris McCord
Project Manager
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SAMPLE RESULTS - 01
L1580443
MW-9-W-20230127
Collected date/time: 01/27/23 09:42
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/31/2023 08:20 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:49 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 226000 20000 1 02/06/2023 08:35 WG1998655
Free Carbon Dioxide 62500 B T8 20000 1 02/06/2023 08:35 WG1998655
Sample Narrative:
L1580443-01 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:39 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 5770 T8 150 500 10 01/30/2023 16:52 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:49 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 02/08/2023 21:56 WG2001845
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 122000 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:35 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 9.98 K6 T8 2.00 1 02/05/2023 08:28 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1580443
MW-9-W-20230127
Collected date/time: 01/27/23 09:42
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 2010 Q 48.0 100 1 01/31/2023 01:48 WG1997192
Nitrite U Q 42.0 100 1 01/31/2023 01:48 WG1997192
Sulfate 3750 J 594 5000 1 01/31/2023 01:48 WG1997192
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)19200 510 5000 5 01/31/2023 09:38 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 5570 18.0 100 1 01/31/2023 08:20 WG1996965
Manganese 5480 0.934 10.0 1 01/31/2023 08:20 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 97.1 2.91 10.0 1 01/31/2023 13:56 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 2260 10000 200 02/07/2023 15:47 WG2000693
Acrolein U 508 10000 200 02/07/2023 15:47 WG2000693
Acrylonitrile U 134 2000 200 02/07/2023 15:47 WG2000693
Benzene 8240 18.8 200 200 02/07/2023 15:47 WG2000693
Bromobenzene U 23.6 200 200 02/07/2023 15:47 WG2000693
Bromodichloromethane U 27.2 200 200 02/07/2023 15:47 WG2000693
Bromoform U 25.8 200 200 02/07/2023 15:47 WG2000693
Bromomethane U 121 1000 200 02/07/2023 16:33 WG2001829
n-Butylbenzene U 31.4 200 200 02/07/2023 15:47 WG2000693
sec-Butylbenzene U 25.0 200 200 02/07/2023 15:47 WG2000693
tert-Butylbenzene U 25.4 200 200 02/07/2023 15:47 WG2000693
Carbon tetrachloride U 25.6 200 200 02/07/2023 15:47 WG2000693
Chlorobenzene U 23.2 200 200 02/07/2023 15:47 WG2000693
Chlorodibromomethane U 28.0 200 200 02/07/2023 15:47 WG2000693
Chloroethane U 38.4 1000 200 02/07/2023 16:33 WG2001829
Chloroform U 22.2 1000 200 02/07/2023 15:47 WG2000693
Chloromethane U 192 500 200 02/07/2023 15:47 WG2000693
2-Chlorotoluene U 21.2 200 200 02/07/2023 15:47 WG2000693
4-Chlorotoluene U 22.8 200 200 02/07/2023 15:47 WG2000693
1,2-Dibromo-3-Chloropropane U 55.2 1000 200 02/07/2023 15:47 WG2000693
1,2-Dibromoethane U 25.2 200 200 02/07/2023 15:47 WG2000693
Dibromomethane U 24.4 200 200 02/07/2023 15:47 WG2000693
1,2-Dichlorobenzene U 21.4 200 200 02/07/2023 15:47 WG2000693
1,3-Dichlorobenzene U 22.0 200 200 02/07/2023 15:47 WG2000693
1,4-Dichlorobenzene U 24.0 200 200 02/07/2023 15:47 WG2000693
Dichlorodifluoromethane U 74.8 1000 200 02/07/2023 15:47 WG2000693
1,1-Dichloroethane U 20.0 200 200 02/07/2023 15:47 WG2000693
1,2-Dichloroethane 47.7 J 16.4 200 200 02/07/2023 15:47 WG2000693
1,1-Dichloroethene U 37.6 200 200 02/07/2023 15:47 WG2000693
cis-1,2-Dichloroethene U 25.2 200 200 02/07/2023 15:47 WG2000693
trans-1,2-Dichloroethene U 29.8 200 200 02/07/2023 15:47 WG2000693
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1580443
MW-9-W-20230127
Collected date/time: 01/27/23 09:42
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 29.8 200 200 02/07/2023 15:47 WG2000693
1,1-Dichloropropene U 28.4 200 200 02/07/2023 15:47 WG2000693
1,3-Dichloropropane U 22.0 200 200 02/07/2023 15:47 WG2000693
2,2-Dichloropropane U 32.2 200 200 02/07/2023 15:47 WG2000693
Di-isopropyl ether U 21.0 200 200 02/07/2023 15:47 WG2000693
Ethylbenzene 2960 27.4 200 200 02/07/2023 15:47 WG2000693
Hexachloro-1,3-butadiene U 67.4 200 200 02/07/2023 15:47 WG2000693
Isopropylbenzene 142 J 21.0 200 200 02/07/2023 15:47 WG2000693
p-Isopropyltoluene U 24.0 200 200 02/07/2023 15:47 WG2000693
2-Butanone (MEK)U 238 2000 200 02/07/2023 15:47 WG2000693
Methylene Chloride U 86.0 1000 200 02/07/2023 15:47 WG2000693
4-Methyl-2-pentanone (MIBK)U 95.6 2000 200 02/07/2023 15:47 WG2000693
Methyl tert-butyl ether 11300 20.2 200 200 02/07/2023 15:47 WG2000693
Naphthalene 251 J 200 1000 200 02/07/2023 15:47 WG2000693
n-Propylbenzene 370 19.9 200 200 02/07/2023 15:47 WG2000693
Styrene U 23.6 200 200 02/07/2023 15:47 WG2000693
1,1,1,2-Tetrachloroethane U 29.4 200 200 02/07/2023 15:47 WG2000693
1,1,2,2-Tetrachloroethane U 26.6 200 200 02/07/2023 15:47 WG2000693
Tetrachloroethene U 60.0 200 200 02/07/2023 15:47 WG2000693
Toluene 86.4 J 55.6 200 200 02/07/2023 15:47 WG2000693
1,2,3-Trichlorobenzene U 46.0 200 200 02/07/2023 15:47 WG2000693
1,2,4-Trichlorobenzene U 96.2 200 200 02/07/2023 15:47 WG2000693
1,1,1-Trichloroethane U 29.8 200 200 02/07/2023 15:47 WG2000693
1,1,2-Trichloroethane U 31.6 200 200 02/07/2023 15:47 WG2000693
Trichloroethene U 38.0 200 200 02/07/2023 15:47 WG2000693
Trichlorofluoromethane U 32.0 1000 200 02/07/2023 15:47 WG2000693
1,2,3-Trichloropropane U 47.4 500 200 02/07/2023 15:47 WG2000693
1,2,4-Trimethylbenzene 417 64.4 200 200 02/07/2023 15:47 WG2000693
1,3,5-Trimethylbenzene 140 J 20.8 200 200 02/07/2023 15:47 WG2000693
Vinyl chloride U 46.8 200 200 02/07/2023 15:47 WG2000693
o-Xylene 129 J 34.8 200 200 02/07/2023 15:47 WG2000693
m&p-Xylenes 432 86.0 400 200 02/07/2023 15:47 WG2000693
(S) Toluene-d8 103 80.0-120 02/07/2023 15:47 WG2000693
(S) Toluene-d8 91.8 80.0-120 02/07/2023 16:33 WG2001829
(S) 4-Bromofluorobenzene 100 77.0-126 02/07/2023 15:47 WG2000693
(S) 4-Bromofluorobenzene 83.7 77.0-126 02/07/2023 16:33 WG2001829
(S) 1,2-Dichloroethane-d4 92.8 70.0-130 02/07/2023 15:47 WG2000693
(S) 1,2-Dichloroethane-d4 104 70.0-130 02/07/2023 16:33 WG2001829
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 8 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 8 of 47
SAMPLE RESULTS - 02
L1580443
MW-6-W-20230127
Collected date/time: 01/27/23 12:22
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 351 15.0 50.0 1 01/31/2023 08:23 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:50 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity U 20000 1 02/06/2023 08:39 WG1998655
Free Carbon Dioxide ND T8 20000 1 02/06/2023 08:39 WG1998655
Sample Narrative:
L1580443-02 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:40 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/30/2023 16:52 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:50 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 1180 50.0 100 1 02/01/2023 20:40 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 18:20 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:35 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K1 K6 T8 2.00 1 02/05/2023 08:33 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 9 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 9 of 47
SAMPLE RESULTS - 02
L1580443
MW-6-W-20230127
Collected date/time: 01/27/23 12:22
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 1240 Q 48.0 100 1 01/31/2023 02:52 WG1997192
Nitrite U Q 42.0 100 1 01/31/2023 02:52 WG1997192
Sulfate 19100 594 5000 1 01/31/2023 02:52 WG1997192
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)320 B J 102 1000 1 01/31/2023 10:32 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 351 18.0 100 1 01/31/2023 08:23 WG1996965
Manganese 16.7 0.934 10.0 1 01/31/2023 08:23 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 13:59 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 17:28 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 17:28 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 17:28 WG2000115
Benzene 6.90 0.0941 1.00 1 02/05/2023 17:28 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 17:28 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 17:28 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 17:28 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 17:28 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 17:28 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 17:28 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 17:28 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 17:28 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 17:28 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 17:28 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 17:28 WG2000115
Chloroform U 0.111 5.00 1 02/05/2023 17:28 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 17:28 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 17:28 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 17:28 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 17:28 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 17:28 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 17:28 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 17:28 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 17:28 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 17:28 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 17:28 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 17:28 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 17:28 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 17:28 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 17:28 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 17:28 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 10 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 10 of 47
SAMPLE RESULTS - 02
L1580443
MW-6-W-20230127
Collected date/time: 01/27/23 12:22
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 17:28 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 17:28 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 17:28 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 17:28 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 17:28 WG2000115
Ethylbenzene 3.52 0.137 1.00 1 02/05/2023 17:28 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 17:28 WG2000115
Isopropylbenzene 0.155 J 0.105 1.00 1 02/05/2023 17:28 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 17:28 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 17:28 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 17:28 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 17:28 WG2000115
Methyl tert-butyl ether 0.255 J 0.101 1.00 1 02/05/2023 17:28 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 17:28 WG2000115
n-Propylbenzene 0.374 J 0.0993 1.00 1 02/05/2023 17:28 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 17:28 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 17:28 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 17:28 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 17:28 WG2000115
Toluene 0.470 J 0.278 1.00 1 02/05/2023 17:28 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 17:28 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 17:28 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 17:28 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 17:28 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 17:28 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 17:28 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 17:28 WG2000115
1,2,4-Trimethylbenzene 0.635 J 0.322 1.00 1 02/05/2023 17:28 WG2000115
1,3,5-Trimethylbenzene 0.232 J 0.104 1.00 1 02/05/2023 17:28 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 17:28 WG2000115
o-Xylene 0.699 J 0.174 1.00 1 02/05/2023 17:28 WG2000115
m&p-Xylenes 1.83 J 0.430 2.00 1 02/05/2023 17:28 WG2000115
(S) Toluene-d8 91.5 80.0-120 02/05/2023 17:28 WG2000115
(S) 4-Bromofluorobenzene 83.4 77.0-126 02/05/2023 17:28 WG2000115
(S) 1,2-Dichloroethane-d4 114 70.0-130 02/05/2023 17:28 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 11 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 11 of 47
SAMPLE RESULTS - 03
L1580443
MW-5-W-20230127
Collected date/time: 01/27/23 14:35
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 2860 15.0 50.0 1 01/31/2023 07:45 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:54 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 11600 J 20000 1 02/06/2023 08:44 WG1998655
Free Carbon Dioxide 72500 B T8 20000 1 02/06/2023 08:44 WG1998655
Sample Narrative:
L1580443-03 WG1998655: Endpoint pH 4.5
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:46 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U P1 T8 15.0 50.0 1 01/30/2023 16:53 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U J3 J6 140 250 1 01/31/2023 18:54 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 11600 250 500 5 02/01/2023 20:41 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 18:29 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:35 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K1 K6 T8 2.00 1 02/05/2023 08:37 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 12 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 12 of 47
SAMPLE RESULTS - 03
L1580443
MW-5-W-20230127
Collected date/time: 01/27/23 14:35
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 11300 Q 48.0 100 1 01/31/2023 03:07 WG1997192
Nitrite U Q 42.0 100 1 01/31/2023 03:07 WG1997192
Sulfate 12400 594 5000 1 01/31/2023 03:07 WG1997192
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)551 B J 102 1000 1 01/31/2023 10:48 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 2860 18.0 100 1 01/31/2023 07:45 WG1996965
Manganese 56.7 0.934 10.0 1 01/31/2023 07:45 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 14:04 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 17:48 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 17:48 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 17:48 WG2000115
Benzene 3.14 0.0941 1.00 1 02/05/2023 17:48 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 17:48 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 17:48 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 17:48 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 17:48 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 17:48 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 17:48 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 17:48 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 17:48 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 17:48 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 17:48 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 17:48 WG2000115
Chloroform 0.297 J 0.111 5.00 1 02/05/2023 17:48 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 17:48 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 17:48 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 17:48 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 17:48 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 17:48 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 17:48 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 17:48 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 17:48 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 17:48 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 17:48 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 17:48 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 17:48 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 17:48 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 17:48 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 17:48 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 13 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 13 of 47
SAMPLE RESULTS - 03
L1580443
MW-5-W-20230127
Collected date/time: 01/27/23 14:35
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 17:48 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 17:48 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 17:48 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 17:48 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 17:48 WG2000115
Ethylbenzene 2.80 0.137 1.00 1 02/05/2023 17:48 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 17:48 WG2000115
Isopropylbenzene 0.150 J 0.105 1.00 1 02/05/2023 17:48 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 17:48 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 17:48 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 17:48 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 17:48 WG2000115
Methyl tert-butyl ether 0.131 J 0.101 1.00 1 02/05/2023 17:48 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 17:48 WG2000115
n-Propylbenzene 0.335 J 0.0993 1.00 1 02/05/2023 17:48 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 17:48 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 17:48 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 17:48 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 17:48 WG2000115
Toluene 0.549 J 0.278 1.00 1 02/05/2023 17:48 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 17:48 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 17:48 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 17:48 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 17:48 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 17:48 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 17:48 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 17:48 WG2000115
1,2,4-Trimethylbenzene 0.889 J 0.322 1.00 1 02/05/2023 17:48 WG2000115
1,3,5-Trimethylbenzene 0.308 J 0.104 1.00 1 02/05/2023 17:48 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 17:48 WG2000115
o-Xylene 0.901 J 0.174 1.00 1 02/05/2023 17:48 WG2000115
m&p-Xylenes 2.39 0.430 2.00 1 02/05/2023 17:48 WG2000115
(S) Toluene-d8 91.6 80.0-120 02/05/2023 17:48 WG2000115
(S) 4-Bromofluorobenzene 82.1 77.0-126 02/05/2023 17:48 WG2000115
(S) 1,2-Dichloroethane-d4 108 70.0-130 02/05/2023 17:48 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 14 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 14 of 47
QUALITY CONTROL SUMMARYWG1998655
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1580443-01,02,03
Method Blank (MB)
(MB) R3887799-2 02/06/23 07:54
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Alkalinity U 8450 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
Method Blank (MB)
(MB) R3887799-3 02/06/23 07:54
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Free Carbon Dioxide 10600 J 6670 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 02/06/23 08:44 • (DUP) R3887799-4 02/06/23 08:48
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity ND 11800 1 1.01 J 20
Sample Narrative:
OS: Endpoint pH 4.5
DUP: Endpoint pH 4.5
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 02/06/23 08:44 • (DUP) R3887799-5 02/06/23 08:48
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide 72500 69800 1 3.80 20
Sample Narrative:
OS: Endpoint pH 4.5
DUP: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998655
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1580443-01,02,03
L1581078-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581078-01 02/06/23 09:28 • (DUP) R3887799-6 02/06/23 09:35
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity 94000 94900 1 0.982 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
L1581078-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581078-01 02/06/23 09:28 • (DUP) R3887799-7 02/06/23 09:35
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide U U 1 0.000 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
Laboratory Control Sample (LCS)
(LCS) R3887799-1 02/06/23 07:43
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Alkalinity 100000 100000 100 90.0-110
Sample Narrative:
LCS: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997036
Wet Chemistry by Method 350.1 L1580443-01,02,03
Method Blank (MB)
(MB) R3885732-1 01/30/23 14:27
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ammonia Nitrogen U 117 250
L1580432-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-01 01/30/23 14:31 • (DUP) R3885732-3 01/30/23 14:33
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ammonia Nitrogen U U 1 0.000 10
Laboratory Control Sample (LCS)
(LCS) R3885732-2 01/30/23 14:28
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ammonia Nitrogen 7500 7570 101 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/30/23 14:46 • (MS) R3885732-4 01/30/23 14:48 • (MSD) R3885732-5 01/30/23 14:49
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ammonia Nitrogen 5000 U 4890 5050 97.8 101 1 90.0-110 3.10 10
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1996879
Wet Chemistry by Method 3500Fe B-2011 L1580443-01,02,03
Method Blank (MB)
(MB) R3885786-1 01/30/23 16:26
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ferrous Iron U 15.0 50.0
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 01/30/23 16:53 • (DUP) R3885786-6 01/30/23 16:54
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ferrous Iron U 15.0 1 200 J P1 20
L1579789-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579789-01 01/30/23 16:32 • (DUP) R3885786-3 01/30/23 16:32
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ferrous Iron 142 145 1 2.09 20
Laboratory Control Sample (LCS)
(LCS) R3885786-2 01/30/23 16:27
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ferrous Iron 1000 910 91.0 85.0-115
L1580443-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-02 01/30/23 16:52 • (MS) R3885786-4 01/30/23 16:53 • (MSD) R3885786-5 01/30/23 16:53
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ferrous Iron 1000 U 908 903 90.8 90.3 1 80.0-120 0.552 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997080
Wet Chemistry by Method 351.2 L1580443-01,02,03
Method Blank (MB)
(MB) R3886231-1 01/31/23 18:22
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Kjeldahl Nitrogen, TKN U 140 250
L1580130-05 Original Sample (OS) • Duplicate (DUP)
(OS) L1580130-05 01/31/23 18:30 • (DUP) R3886231-3 01/31/23 18:31
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 1430 1400 1 2.12 20
L1580130-07 Original Sample (OS) • Duplicate (DUP)
(OS) L1580130-07 01/31/23 18:38 • (DUP) R3886231-5 01/31/23 18:40
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 1590 1630 1 2.48 20
Laboratory Control Sample (LCS)
(LCS) R3886231-2 01/31/23 18:23
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 14700 13800 93.9 75.2-120
L1580130-06 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580130-06 01/31/23 18:33 • (MS) R3886231-4 01/31/23 18:34
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Kjeldahl Nitrogen, TKN 5000 596 5480 97.7 1 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 18:54 • (MS) R3886231-6 01/31/23 18:56 • (MSD) R3886231-7 01/31/23 18:57
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Kjeldahl Nitrogen, TKN 5000 U 1530 1910 30.6 38.2 1 90.0-110 J6 J3 J6 22.1 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997080
Wet Chemistry by Method 351.2 L1580443-01,02,03
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 18:54 • (MS) R3886231-6 01/31/23 18:56 • (MSD) R3886231-7 01/31/23 18:57
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Sample Narrative:
MS: Matrix spike failure due to matrix.
MSD: Matrix spike fialure due to matrix.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997093
Wet Chemistry by Method 353.2 L1580443-02,03
Method Blank (MB)
(MB) R3886549-1 02/01/23 20:15
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate-Nitrite U 50.0 100
L1580005-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580005-01 02/01/23 20:17 • (DUP) R3886549-3 02/01/23 20:18
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 2070 2080 1 0.482 20
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 02/01/23 20:41 • (DUP) R3886549-5 02/01/23 20:46
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 11600 11500 5 1.30 20
Laboratory Control Sample (LCS)
(LCS) R3886549-2 02/01/23 20:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate-Nitrite 2500 2600 104 90.0-110
L1580005-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580005-01 02/01/23 20:17 • (MS) R3886549-4 02/01/23 20:20
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Nitrate-Nitrite 2500 2070 4590 101 1 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/01/23 20:41 • (MS) R3886549-6 02/01/23 20:48 • (MSD) R3886549-7 02/01/23 20:49
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate-Nitrite 12500 11600 23600 24100 95.6 100 5 90.0-110 2.31 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG2001845
Wet Chemistry by Method 353.2 L1580443-01
Method Blank (MB)
(MB) R3888894-1 02/08/23 21:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate-Nitrite U 50.0 100
L1582942-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1582942-01 02/08/23 21:59 • (DUP) R3888894-3 02/08/23 22:01
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 105 101 1 3.88 20
L1583139-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1583139-01 02/08/23 22:17 • (DUP) R3888894-6 02/08/23 22:19
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 1410 1300 1 8.12 20
Laboratory Control Sample (LCS)
(LCS) R3888894-2 02/08/23 21:54
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate-Nitrite 2500 2520 101 90.0-110
L1582942-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1582942-01 02/08/23 21:59 • (MS) R3888894-4 02/08/23 22:02 • (MSD) R3888894-5 02/08/23 22:03
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate-Nitrite 2500 105 2680 2620 103 101 1 90.0-110 2.26 20
L1583139-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1583139-01 02/08/23 22:17 • (MS) R3888894-7 02/08/23 22:20
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Nitrate-Nitrite 2500 1410 3890 99.2 1 90.0-110
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997000
Wet Chemistry by Method 410.4 L1580443-01,02,03
Method Blank (MB)
(MB) R3885806-1 01/30/23 17:52
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
COD U 11700 20000
L1579311-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579311-01 01/30/23 17:53 • (DUP) R3885806-3 01/30/23 17:53
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
COD 60800 69800 1 13.8 20
L1580443-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-01 01/30/23 17:57 • (DUP) R3885806-4 01/30/23 18:03
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
COD 122000 116000 1 5.18 20
Laboratory Control Sample (LCS)
(LCS) R3885806-2 01/30/23 17:52
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
COD 500000 473000 94.6 90.0-110
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/30/23 18:29 • (MS) R3885806-5 01/30/23 18:30 • (MSD) R3885806-6 01/30/23 18:31
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
COD 500000 U 528000 480000 106 96.1 1 80.0-120 9.50 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997328
Wet Chemistry by Method 4500S2 D-2011 L1580443-01,02,03
Method Blank (MB)
(MB) R3886035-1 01/31/23 11:17
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Sulfide U 25.0 50.0
L1580432-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-01 01/31/23 11:33 • (DUP) R3886035-3 01/31/23 11:33
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Sulfide U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3886035-2 01/31/23 11:17
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Sulfide 500 521 104 85.0-115
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 11:35 • (MS) R3886035-4 01/31/23 11:35 • (MSD) R3886035-5 01/31/23 11:36
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Sulfide 500 U 485 503 97.0 101 1 80.0-120 3.64 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997413
Wet Chemistry by Method 5210 B-2016 L1580443-01,02,03
Method Blank (MB)
(MB) R3887618-1 02/05/23 10:30
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/l mg/l mg/l
BOD U 0.200 0.200
L1580536-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580536-01 02/05/23 08:46 • (DUP) R3887618-3 02/05/23 08:49
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD ND ND 1 0 30
L1580577-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580577-01 02/05/23 09:26 • (DUP) R3887618-4 02/05/23 09:31
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD 55.2 47.3 1 15.3 30
Laboratory Control Sample (LCS)
(LCS) R3887618-2 02/05/23 08:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 147 74.1 84.6-115 J-
Laboratory Control Sample (LCS)
(LCS) R3887618-5 02/05/23 09:37
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 169 85.1 84.6-115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997192
Wet Chemistry by Method 9056A L1580443-01,02,03
Method Blank (MB)
(MB) R3886096-1 01/30/23 13:08
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate U 48.0 100
Nitrite U 42.0 100
Sulfate U 594 5000
L1580367-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1580367-02 01/31/23 00:28 • (DUP) R3886096-3 01/31/23 00:44
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate 7870 7900 1 0.301 15
Nitrite U U 1 0.000 15
Sulfate 480000 481000 1 0.132 E 15
L1580443-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-01 01/31/23 01:48 • (DUP) R3886096-5 01/31/23 02:04
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate 2010 2020 1 0.438 15
Nitrite U U 1 0.000 15
Sulfate 3750 3290 1 13.1 J 15
Laboratory Control Sample (LCS)
(LCS) R3886096-2 01/30/23 13:24
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate 8000 8000 99.9 80.0-120
Nitrite 8000 8420 105 80.0-120
Sulfate 40000 41400 103 80.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1997192
Wet Chemistry by Method 9056A L1580443-01,02,03
L1580367-02 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580367-02 01/31/23 00:28 • (MS) R3886096-4 01/31/23 01:00
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Nitrate 5000 7870 12700 96.7 1 80.0-120
Nitrite 5000 U 5220 104 1 80.0-120
Sulfate 50000 480000 517000 73.2 1 80.0-120 E V
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 03:07 • (MS) R3886096-6 01/31/23 03:26 • (MSD) R3886096-7 01/31/23 03:42
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate 5000 11300 15300 15400 80.1 82.1 1 80.0-120 0.665 15
Nitrite 5000 U 4810 4840 96.3 96.8 1 80.0-120 0.518 15
Sulfate 50000 12400 57800 57900 90.8 91.1 1 80.0-120 0.261 15
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 27 of 47
QUALITY CONTROL SUMMARYWG1997261
Wet Chemistry by Method 9060A L1580443-01,02,03
Method Blank (MB)
(MB) R3886050-2 01/31/23 07:02
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
TOC (Total Organic Carbon)245 J 102 1000
L1580432-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-01 01/31/23 08:16 • (DUP) R3886050-3 01/31/23 08:32
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)1190 1160 1 2.38 20
Laboratory Control Sample (LCS)
(LCS) R3886050-1 01/31/23 06:46
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)75000 78000 104 85.0-115
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 10:48 • (MS) R3886050-4 01/31/23 11:08 • (MSD) R3886050-5 01/31/23 11:29
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
TOC (Total Organic Carbon)50000 551 52500 53100 104 105 1 80.0-120 1.08 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996965
Metals (ICP) by Method 6010D L1580443-01,02,03
Method Blank (MB)
(MB) R3886057-1 01/31/23 07:39
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Iron U 18.0 100
Manganese U 0.934 10.0
Laboratory Control Sample (LCS)
(LCS) R3886057-2 01/31/23 07:42
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Iron 10000 9580 95.8 80.0-120
Manganese 1000 948 94.8 80.0-120
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 07:45 • (MS) R3886057-4 01/31/23 07:50 • (MSD) R3886057-5 01/31/23 07:53
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Iron 10000 2860 13200 13600 104 107 1 75.0-125 2.53 20
Manganese 1000 56.7 1020 1010 96.2 95.5 1 75.0-125 0.653 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997438
Volatile Organic Compounds (GC) by Method RSK175 L1580443-01,02,03
Method Blank (MB)
(MB) R3886040-2 01/31/23 11:20
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Methane U 2.91 10.0
L1580432-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1580432-02 01/31/23 13:14 • (DUP) R3886040-3 01/31/23 13:19
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane U U 1 0.000 20
L1580443-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-02 01/31/23 13:59 • (DUP) R3886040-4 01/31/23 14:21
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane U U 1 0.000 20
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3886040-1 01/31/23 11:16 • (LCSD) R3886040-7 01/31/23 14:32
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Methane 67.8 73.6 65.7 109 96.9 85.0-115 11.3 20
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 01/31/23 14:04 • (MS) R3886040-5 01/31/23 14:27 • (MSD) R3886040-6 01/31/23 14:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Methane 67.8 U 75.4 74.3 111 110 1 50.0-150 1.47 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-02,03
Method Blank (MB)
(MB) R3887703-2 02/05/23 12:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
Bromomethane U 0.605 5.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-02,03
Method Blank (MB)
(MB) R3887703-2 02/05/23 12:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 94.3 80.0-120
(S) 4-Bromofluorobenzene 80.7 77.0-126
(S) 1,2-Dichloroethane-d4 107 70.0-130
Laboratory Control Sample (LCS)
(LCS) R3887703-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acetone 25.0 21.2 84.8 19.0-160
Acrolein 25.0 10.3 41.2 10.0-160
Acrylonitrile 25.0 23.4 93.6 55.0-149
Benzene 5.00 4.73 94.6 70.0-123
Bromobenzene 5.00 5.23 105 73.0-121
Bromodichloromethane 5.00 5.30 106 75.0-120
Bromoform 5.00 4.49 89.8 68.0-132
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-02,03
Laboratory Control Sample (LCS)
(LCS) R3887703-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Bromomethane 5.00 5.77 115 10.0-160
n-Butylbenzene 5.00 4.71 94.2 73.0-125
sec-Butylbenzene 5.00 4.99 99.8 75.0-125
tert-Butylbenzene 5.00 4.79 95.8 76.0-124
Carbon tetrachloride 5.00 5.06 101 68.0-126
Chlorobenzene 5.00 4.40 88.0 80.0-121
Chlorodibromomethane 5.00 4.59 91.8 77.0-125
Chloroethane 5.00 5.89 118 47.0-150
Chloroform 5.00 5.41 108 73.0-120
Chloromethane 5.00 5.01 100 41.0-142
2-Chlorotoluene 5.00 5.18 104 76.0-123
4-Chlorotoluene 5.00 4.85 97.0 75.0-122
1,2-Dibromo-3-Chloropropane 5.00 4.27 85.4 58.0-134
1,2-Dibromoethane 5.00 4.73 94.6 80.0-122
Dibromomethane 5.00 4.97 99.4 80.0-120
1,2-Dichlorobenzene 5.00 4.89 97.8 79.0-121
1,3-Dichlorobenzene 5.00 5.15 103 79.0-120
1,4-Dichlorobenzene 5.00 5.02 100 79.0-120
Dichlorodifluoromethane 5.00 6.52 130 51.0-149
1,1-Dichloroethane 5.00 4.54 90.8 70.0-126
1,2-Dichloroethane 5.00 5.28 106 70.0-128
1,1-Dichloroethene 5.00 4.97 99.4 71.0-124
cis-1,2-Dichloroethene 5.00 4.78 95.6 73.0-120
trans-1,2-Dichloroethene 5.00 4.97 99.4 73.0-120
1,2-Dichloropropane 5.00 4.45 89.0 77.0-125
1,1-Dichloropropene 5.00 4.77 95.4 74.0-126
1,3-Dichloropropane 5.00 4.70 94.0 80.0-120
2,2-Dichloropropane 5.00 5.77 115 58.0-130
Di-isopropyl ether 5.00 4.38 87.6 58.0-138
Ethylbenzene 5.00 4.27 85.4 79.0-123
Hexachloro-1,3-butadiene 5.00 5.48 110 54.0-138
Isopropylbenzene 5.00 4.16 83.2 76.0-127
p-Isopropyltoluene 5.00 4.81 96.2 76.0-125
2-Butanone (MEK)25.0 24.0 96.0 44.0-160
Methylene Chloride 5.00 5.13 103 67.0-120
4-Methyl-2-pentanone (MIBK)25.0 22.5 90.0 68.0-142
Methyl tert-butyl ether 5.00 5.07 101 68.0-125
Naphthalene 5.00 4.18 83.6 54.0-135
n-Propylbenzene 5.00 4.77 95.4 77.0-124
Styrene 5.00 3.98 79.6 73.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-02,03
Laboratory Control Sample (LCS)
(LCS) R3887703-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
1,1,1,2-Tetrachloroethane 5.00 4.51 90.2 75.0-125
1,1,2,2-Tetrachloroethane 5.00 5.35 107 65.0-130
Tetrachloroethene 5.00 4.73 94.6 72.0-132
Toluene 5.00 4.40 88.0 79.0-120
1,2,3-Trichlorobenzene 5.00 4.69 93.8 50.0-138
1,2,4-Trichlorobenzene 5.00 4.70 94.0 57.0-137
1,1,1-Trichloroethane 5.00 5.51 110 73.0-124
1,1,2-Trichloroethane 5.00 4.68 93.6 80.0-120
Trichloroethene 5.00 4.58 91.6 78.0-124
Trichlorofluoromethane 5.00 5.84 117 59.0-147
1,2,3-Trichloropropane 5.00 5.66 113 73.0-130
1,2,4-Trimethylbenzene 5.00 4.75 95.0 76.0-121
1,3,5-Trimethylbenzene 5.00 4.87 97.4 76.0-122
Vinyl chloride 5.00 5.41 108 67.0-131
o-Xylene 5.00 4.01 80.2 80.0-122
m&p-Xylenes 10.0 8.65 86.5 80.0-122
(S) Toluene-d8 91.2 80.0-120
(S) 4-Bromofluorobenzene 83.8 77.0-126
(S) 1,2-Dichloroethane-d4 106 70.0-130
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/05/23 17:48 • (MS) R3887703-3 02/06/23 00:10 • (MSD) R3887703-4 02/06/23 00:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Acetone 25.0 U 25.7 23.1 103 92.4 1 10.0-160 10.7 35
Acrolein 25.0 U 23.7 21.6 94.8 86.4 1 10.0-160 9.27 39
Acrylonitrile 25.0 U 27.4 25.3 110 101 1 21.0-160 7.97 32
Benzene 5.00 3.14 9.19 8.26 121 102 1 17.0-158 10.7 27
Bromobenzene 5.00 U 5.72 5.65 114 113 1 30.0-149 1.23 28
Bromodichloromethane 5.00 U 5.79 5.89 116 118 1 31.0-150 1.71 27
Bromoform 5.00 U 4.95 5.06 99.0 101 1 29.0-150 2.20 29
Bromomethane 5.00 U 6.38 6.28 128 126 1 10.0-160 1.58 38
n-Butylbenzene 5.00 U 5.35 5.26 107 105 1 31.0-150 1.70 30
sec-Butylbenzene 5.00 U 5.62 5.65 112 113 1 33.0-155 0.532 29
tert-Butylbenzene 5.00 U 5.42 5.54 108 111 1 34.0-153 2.19 28
Carbon tetrachloride 5.00 U 5.91 5.74 118 115 1 23.0-159 2.92 28
Chlorobenzene 5.00 U 5.03 4.93 101 98.6 1 33.0-152 2.01 27
Chlorodibromomethane 5.00 U 5.09 5.10 102 102 1 37.0-149 0.196 27
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-02,03
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/05/23 17:48 • (MS) R3887703-3 02/06/23 00:10 • (MSD) R3887703-4 02/06/23 00:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Chloroethane 5.00 U 6.74 6.77 135 135 1 10.0-160 0.444 30
Chloroform 5.00 0.297 6.59 6.28 126 120 1 29.0-154 4.82 28
Chloromethane 5.00 U 5.73 5.84 115 117 1 10.0-160 1.90 29
2-Chlorotoluene 5.00 U 5.68 5.48 114 110 1 32.0-153 3.58 28
4-Chlorotoluene 5.00 U 5.29 5.24 106 105 1 32.0-150 0.950 28
1,2-Dibromo-3-Chloropropane 5.00 U 4.78 4.93 95.6 98.6 1 22.0-151 3.09 34
1,2-Dibromoethane 5.00 U 5.18 5.01 104 100 1 34.0-147 3.34 27
Dibromomethane 5.00 U 5.30 5.60 106 112 1 30.0-151 5.50 27
1,2-Dichlorobenzene 5.00 U 5.45 5.52 109 110 1 34.0-149 1.28 28
1,3-Dichlorobenzene 5.00 U 5.67 5.55 113 111 1 36.0-146 2.14 27
1,4-Dichlorobenzene 5.00 U 5.40 5.37 108 107 1 35.0-142 0.557 27
Dichlorodifluoromethane 5.00 U 7.07 7.26 141 145 1 10.0-160 2.65 29
1,1-Dichloroethane 5.00 U 5.60 5.16 112 103 1 25.0-158 8.18 27
1,2-Dichloroethane 5.00 U 5.98 5.91 120 118 1 29.0-151 1.18 27
1,1-Dichloroethene 5.00 U 6.02 5.98 120 120 1 11.0-160 0.667 29
cis-1,2-Dichloroethene 5.00 U 5.71 5.24 114 105 1 10.0-160 8.58 27
trans-1,2-Dichloroethene 5.00 U 5.97 5.50 119 110 1 17.0-153 8.20 27
1,2-Dichloropropane 5.00 U 4.83 4.94 96.6 98.8 1 30.0-156 2.25 27
1,1-Dichloropropene 5.00 U 5.77 5.37 115 107 1 25.0-158 7.18 27
1,3-Dichloropropane 5.00 U 5.19 5.14 104 103 1 38.0-147 0.968 27
2,2-Dichloropropane 5.00 U 6.38 5.96 128 119 1 24.0-152 6.81 29
Di-isopropyl ether 5.00 U 5.18 4.85 104 97.0 1 21.0-160 6.58 28
Ethylbenzene 5.00 2.80 7.95 7.60 103 96.0 1 30.0-155 4.50 27
Hexachloro-1,3-butadiene 5.00 U 6.50 6.65 130 133 1 20.0-154 2.28 34
Isopropylbenzene 5.00 0.150 4.96 4.81 96.2 93.2 1 28.0-157 3.07 27
p-Isopropyltoluene 5.00 U 5.44 5.34 109 107 1 30.0-154 1.86 29
2-Butanone (MEK)25.0 U 29.0 26.9 116 108 1 10.0-160 7.51 32
Methylene Chloride 5.00 U 5.95 5.64 119 113 1 23.0-144 5.35 28
4-Methyl-2-pentanone (MIBK)25.0 U 25.2 25.6 101 102 1 29.0-160 1.57 29
Methyl tert-butyl ether 5.00 0.131 5.86 5.69 115 111 1 28.0-150 2.94 29
Naphthalene 5.00 U 4.88 5.10 97.6 102 1 12.0-156 4.41 35
n-Propylbenzene 5.00 0.335 5.68 5.62 107 106 1 31.0-154 1.06 28
Styrene 5.00 U 4.55 4.39 91.0 87.8 1 33.0-155 3.58 28
1,1,1,2-Tetrachloroethane 5.00 U 5.12 5.25 102 105 1 36.0-151 2.51 29
1,1,2,2-Tetrachloroethane 5.00 U 5.98 6.12 120 122 1 33.0-150 2.31 28
Tetrachloroethene 5.00 U 5.48 5.38 110 108 1 10.0-160 1.84 27
Toluene 5.00 0.549 5.51 5.41 99.2 97.2 1 26.0-154 1.83 28
1,2,3-Trichlorobenzene 5.00 U 4.89 5.02 97.8 100 1 17.0-150 2.62 36
1,2,4-Trichlorobenzene 5.00 U 4.94 4.90 98.8 98.0 1 24.0-150 0.813 33
1,1,1-Trichloroethane 5.00 U 6.37 6.34 127 127 1 23.0-160 0.472 28
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000115
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-02,03
L1580443-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580443-03 02/05/23 17:48 • (MS) R3887703-3 02/06/23 00:10 • (MSD) R3887703-4 02/06/23 00:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
1,1,2-Trichloroethane 5.00 U 5.28 5.22 106 104 1 35.0-147 1.14 27
Trichloroethene 5.00 U 4.92 5.06 98.4 101 1 10.0-160 2.81 25
Trichlorofluoromethane 5.00 U 6.56 6.66 131 133 1 17.0-160 1.51 31
1,2,3-Trichloropropane 5.00 U 6.18 6.15 124 123 1 34.0-151 0.487 29
1,2,4-Trimethylbenzene 5.00 0.889 6.31 6.30 108 108 1 26.0-154 0.159 27
1,3,5-Trimethylbenzene 5.00 0.308 5.80 5.71 110 108 1 28.0-153 1.56 27
Vinyl chloride 5.00 U 6.17 6.39 123 128 1 10.0-160 3.50 27
o-Xylene 5.00 0.901 5.66 5.46 95.2 91.2 1 45.0-144 3.60 26
m&p-Xylenes 10.0 2.39 12.6 12.1 102 97.1 1 43.0-146 4.05 26
(S) Toluene-d8 90.3 90.9 80.0-120
(S) 4-Bromofluorobenzene 85.2 85.6 77.0-126
(S) 1,2-Dichloroethane-d4 112 108 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-01
Method Blank (MB)
(MB) R3888349-2 02/07/23 09:49
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-01
Method Blank (MB)
(MB) R3888349-2 02/07/23 09:49
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 103 80.0-120
(S) 4-Bromofluorobenzene 98.8 77.0-126
(S) 1,2-Dichloroethane-d4 89.5 70.0-130
Laboratory Control Sample (LCS)
(LCS) R3888349-1 02/07/23 09:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acetone 25.0 29.7 119 19.0-160
Acrolein 25.0 31.2 125 10.0-160
Acrylonitrile 25.0 25.7 103 55.0-149
Benzene 5.00 5.01 100 70.0-123
Bromobenzene 5.00 5.04 101 73.0-121
Bromodichloromethane 5.00 4.69 93.8 75.0-120
Bromoform 5.00 4.23 84.6 68.0-132
n-Butylbenzene 5.00 5.00 100 73.0-125
sec-Butylbenzene 5.00 4.92 98.4 75.0-125
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-01
Laboratory Control Sample (LCS)
(LCS) R3888349-1 02/07/23 09:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
tert-Butylbenzene 5.00 4.73 94.6 76.0-124
Carbon tetrachloride 5.00 4.99 99.8 68.0-126
Chlorobenzene 5.00 5.04 101 80.0-121
Chlorodibromomethane 5.00 4.52 90.4 77.0-125
Chloroform 5.00 4.84 96.8 73.0-120
Chloromethane 5.00 5.83 117 41.0-142
2-Chlorotoluene 5.00 5.11 102 76.0-123
4-Chlorotoluene 5.00 4.96 99.2 75.0-122
1,2-Dibromo-3-Chloropropane 5.00 4.23 84.6 58.0-134
1,2-Dibromoethane 5.00 5.09 102 80.0-122
Dibromomethane 5.00 4.96 99.2 80.0-120
1,2-Dichlorobenzene 5.00 4.75 95.0 79.0-121
1,3-Dichlorobenzene 5.00 4.67 93.4 79.0-120
1,4-Dichlorobenzene 5.00 4.86 97.2 79.0-120
Dichlorodifluoromethane 5.00 6.23 125 51.0-149
1,1-Dichloroethane 5.00 5.35 107 70.0-126
1,2-Dichloroethane 5.00 4.91 98.2 70.0-128
1,1-Dichloroethene 5.00 4.87 97.4 71.0-124
cis-1,2-Dichloroethene 5.00 4.95 99.0 73.0-120
trans-1,2-Dichloroethene 5.00 5.09 102 73.0-120
1,2-Dichloropropane 5.00 4.92 98.4 77.0-125
1,1-Dichloropropene 5.00 5.12 102 74.0-126
1,3-Dichloropropane 5.00 5.05 101 80.0-120
2,2-Dichloropropane 5.00 5.32 106 58.0-130
Di-isopropyl ether 5.00 4.85 97.0 58.0-138
Ethylbenzene 5.00 4.97 99.4 79.0-123
Hexachloro-1,3-butadiene 5.00 5.35 107 54.0-138
Isopropylbenzene 5.00 4.76 95.2 76.0-127
p-Isopropyltoluene 5.00 5.04 101 76.0-125
2-Butanone (MEK)25.0 24.1 96.4 44.0-160
Methylene Chloride 5.00 5.19 104 67.0-120
4-Methyl-2-pentanone (MIBK)25.0 25.3 101 68.0-142
Methyl tert-butyl ether 5.00 4.72 94.4 68.0-125
Naphthalene 5.00 3.97 79.4 54.0-135
n-Propylbenzene 5.00 5.00 100 77.0-124
Styrene 5.00 4.49 89.8 73.0-130
1,1,1,2-Tetrachloroethane 5.00 4.80 96.0 75.0-125
1,1,2,2-Tetrachloroethane 5.00 5.44 109 65.0-130
Tetrachloroethene 5.00 4.85 97.0 72.0-132
Toluene 5.00 5.07 101 79.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000693
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-01
Laboratory Control Sample (LCS)
(LCS) R3888349-1 02/07/23 09:04
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
1,2,3-Trichlorobenzene 5.00 4.46 89.2 50.0-138
1,2,4-Trichlorobenzene 5.00 4.13 82.6 57.0-137
1,1,1-Trichloroethane 5.00 4.89 97.8 73.0-124
1,1,2-Trichloroethane 5.00 5.06 101 80.0-120
Trichloroethene 5.00 4.58 91.6 78.0-124
Trichlorofluoromethane 5.00 6.29 126 59.0-147
1,2,3-Trichloropropane 5.00 5.53 111 73.0-130
1,2,4-Trimethylbenzene 5.00 4.89 97.8 76.0-121
1,3,5-Trimethylbenzene 5.00 4.89 97.8 76.0-122
Vinyl chloride 5.00 6.26 125 67.0-131
o-Xylene 5.00 4.93 98.6 80.0-122
m&p-Xylenes 10.0 10.1 101 80.0-122
(S) Toluene-d8 101 80.0-120
(S) 4-Bromofluorobenzene 100 77.0-126
(S) 1,2-Dichloroethane-d4 90.7 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001829
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1580443-01
Method Blank (MB)
(MB) R3888368-5 02/07/23 12:57
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Bromomethane U 0.605 5.00
Chloroethane U 0.192 5.00
(S) Toluene-d8 91.5 80.0-120
(S) 4-Bromofluorobenzene 86.8 77.0-126
(S) 1,2-Dichloroethane-d4 105 70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3888368-1 02/07/23 10:25 • (LCSD) R3888368-2 02/07/23 10:46
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Bromomethane 5.00 6.24 6.08 125 122 10.0-160 2.60 25
Chloroethane 5.00 6.51 6.34 130 127 47.0-150 2.65 20
(S) Toluene-d8 91.4 90.2 80.0-120
(S) 4-Bromofluorobenzene 82.1 81.8 77.0-126
(S) 1,2-Dichloroethane-d4 112 111 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec.Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Dilution
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Limits
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
Qualifier
This column provides a letter and/or number designation that corresponds to additional information concerning the result
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
Result
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL”
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)Confidence level of 2 sigma.
Case Narrative (Cn)
A brief discussion about the included sample results, including a discussion of any non-conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
Summary (Qc)
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
Sample Chain of
Custody (Sc)
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
Sample Results (Sr)
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
B The same analyte is found in the associated blank.
C4 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low.
Data is likely to show a low bias concerning the result.
E The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial calibration (ICAL).
J The identification of the analyte is acceptable; the reported value is an estimate.
J3 The associated batch QC was outside the established quality control range for precision.
J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.
J-The associated batch QC was outside the lower control limits; associated data has a potential negative bias.
K1 The sample dilutions set-up for the BOD/CBOD analysis did not meet the oxygen depletion criteria of at least 2 mg/L. Reported result is an estimated value.
K6 Glucose/glutamic acid BOD/CBOD was below method acceptance criteria.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Qualifier Description
P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.
Q Sample was prepared and/or analyzed past holding time as defined in the method. Concentrations should be
considered minimum values.
T8 Sample(s) received past/too close to holding time expiration.
V The sample concentration is too high to evaluate accurate spike recoveries.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN000032021-1
Arizona AZ0612 New Hampshire 2975
Arkansas 88-0469 New Jersey–NELAP TN002
California 2932 New Mexico ¹TN00003
Colorado TN00003 New York 11742
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina ¹DW21704
Georgia NELAP North Carolina ³41
Georgia ¹923 North Dakota R-140
Idaho TN00003 Ohio–VAP CL0069
Illinois 200008 Oklahoma 9915
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979
Kansas E-10277 Rhode Island LAO00356
Kentucky ¹ ⁶KY90010 South Carolina 84004002
Kentucky ²16 South Dakota n/a
Louisiana AI30792 Tennessee ¹ ⁴2006
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas ⁵LAB0152
Maryland 324 Utah TN000032021-11
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033
Minnesota 047-999-395 Washington C847
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA – ISO 17025 ⁵1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA–Crypto TN00003
ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Chevron - 205513

DATA REVIEW
High point

Volatile organic compounds, Dissolved gases, Metals and General Chemistry

SDG# L1580443

Analyses Performed By:
Pace Analytical National
Mount Juliet, TN 37122

Report # 48699R
Review Level: Tier II
Project: 30064349.19.61

DATA REVIEW REPORT
arcadis.com
SUMMARY
This data quality assessment summarizes the review of Sample Delivery Groups (SDGs) # L1580443
for samples collected in association with the Chevron 205513 High Point Site. The review was conducted as a Tier II evaluation and included review of data package completeness. Only analytical data associated with constituents of concern were reviewed for this validation. Field documentation was not included in this review. Included with this assessment are the validation annotated sample result sheets and chain of custody. Analyses were performed on the following samples:
Sample ID Lab ID Matrix Sample Collection Date Parent Sample Analysis
VOC RSK175 Met. Misc.
MW-9-W-20230127 L1580443-01 Water 01/27/2023 X X X X
MW-6-W-20230127 L1580443-02 Water 01/27/2023 X X X X
MW-5-W-20230127 L1580443-03 Water 01/27/2023 X X X X

Notes:
VOC = volatile organic compounds.
RSK 175 = Dissolved Gases
Met = Metals
Misc. = General Chemistry

DATA REVIEW REPORT
arcadis.com

ANALYTICAL DATA PACKAGE DOCUMENTATION
The table below is the evaluation of the data package completeness.
Items Reviewed Reported Performance Acceptable Not Required No Yes No Yes
1. Sample receipt condition X X
2. Requested analyses and sample results X X
3. Master tracking list X X
4. Methods of analysis X X
5. Reporting limits X X
6. Sample collection date X X
7. Laboratory sample received date X X
8. Sample preservation verification (as applicable) X X
9. Sample preparation/extraction/analysis dates X X
10. Fully executed Chain-of-Custody (COC) form X X
11. Narrative summary of QA or sample problems provided X X
12. Data Package Completeness and Compliance X X
Note: QA - Quality Assurance
DATA REVIEW REPORT
arcadis.com
ORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6200B. Data were reviewed in accordance with the method specified criteria, USEPA National
Functional Guidelines NFG for Organic Superfund Methods Data Review, EPA-540-R-20-005 (November
2020), with reference to the historical (USEPA Contract Laboratory Program National Functional
Guidelines for Organic Data Review, OSWER 9240.1-05A-P, October 1999, as appropriate).
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and had already been subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with USEPA National Functional
Guidelines:
• Concentration (C) Qualifiers
U The compound was analyzed for but not detected. The associated value is the compound
quantitation limit.
B The compound has been found in the sample as well as its associated blank, its presence in
the sample may be suspect.
• Quantitation (Q) Qualifiers
E The compound was quantitated above the calibration range.
D Concentration is based on a diluted sample analysis.
• Validation Qualifiers
J The compound was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The compound was not detected above the reported sample quantitation limit. However, the
reported limit is approximate and may or may not represent the actual limit of quantitation.
JN The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification. The associated numerical value is an estimated concentration
only.
UB Compound considered non-detect at the listed value due to associated blank contamination.
N The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
DATA REVIEW REPORT
arcadis.com
that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

DATA REVIEW REPORT
arcadis.com
VOLATILE ORGANIC COMPOUND (VOC) ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
SW-846 6200B Water 14 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2 s.u.
Note:
s.u. Standard units
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds were not detected above the MDL in the associated blanks; therefore, detected sample
results were not associated with blank contamination.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique. VOC
analysis requires that all surrogates associated with the analysis exhibit recoveries within the laboratory-
established acceptance limits.
All surrogate recoveries were within the control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analyses
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit a percent recovery within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS/MSD recoveries must exhibit
an RPD within the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on sample locations
where the compound concentration detected in the parent sample exceeds the MS/MSD concentration by
a factor of four or greater.
MS/MSD analysis was performed on sample ID MW-5-W-20230127, exhibited acceptable recoveries and
RPDs.
5. Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Analysis
The LCS/LCSD analysis is used to assess the precision and accuracy of the analytical method
independent of matrix interferences. The compounds associated with the LCS/LCSD analysis must
exhibit a percent recovery within the laboratory-established acceptance limits.
DATA REVIEW REPORT
arcadis.com
All compounds associated with the LCS/LCSD analysis exhibited recoveries within the control limits.
6. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to 5 times the RL, a control limit of two times the RL is applied for water matrices.
Field duplicate sample was not collected from this SDG.

7. System Performance and Overall Assessment
The case narrative noted that the CCVs for acrolein were outside the control limit with a high bias. The
associated field samples MW-6-W-20230127 and MW-5-W-20230127 were qualified as estimated (UJ)
for the above listed compound.
Other than for those deviations specifically mentioned in this review, the overall data quality is within the
guidelines specified in the method.
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DATA VALIDATION CHECKLIST FOR VOCs

VOCs: SW-846 6200B Reported Performance
Acceptable Not
Required No Yes No Yes
GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS)
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
C. Trip blanks X X
Laboratory Control Sample (LCS) X X
Laboratory Control Sample Duplicate(LCSD) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) X X
Matrix Spike Duplicate (MSD) X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Surrogate Spike Recoveries X X
Dilution Factor X X
Notes:
%R Percent recovery
RPD Relative percent difference

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DISSOLVED GASES ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
RSK-175 Water 14 days from collection to analysis Cool to < 6 °C; pH > 10 with TSP
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e. method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds were not detected above the SDL in the associated blanks; therefore, detected sample
results were not associated with blank contamination.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique.
Dissolved gases analysis requires that all surrogates associated with the analysis exhibit recoveries
within the laboratory-established acceptance limits.
All surrogate recoveries were within control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analysis
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit recoveries within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS and MSD results must be within
the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on samples where the
compound concentration detected in the parent sample exceeds the MS/MSD concentration by a factor of
four or greater.
The MS/MSD analysis was performed on sample ID MW-5-W-20230127, exhibited acceptable recoveries
and RPDs.
5. Laboratory Control Sample (LCS) Analysis
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The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The compounds associated with the LCS analysis must exhibit a percent recovery within
the laboratory-established acceptance limits.
All compounds associated with the LCS analysis exhibited recoveries within the control limits.
6. Field Duplicate Sample Analysis
The field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 25% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to five times the RL, a control limit of two times the RL is applied to the difference
between the results for water matrices.
Field duplicate sample was not collected from this SDG.
7. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

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DATA VALIDATION CHECKLIST FOR DISSOLVED GASES

Dissolved Gases: RSK-175 Reported Performance Acceptable Not Required No Yes No Yes
Gas Chromatography/Thermal Conductivity Detector (GC/TCD)
Tier II Validation
Holding times/Temperature/Preservation X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
Laboratory Control Sample (LCS) Accuracy (%R) X X
Laboratory Control Sample Duplicate (LCSD) (%R) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike Sample (MS) (%R) X X
Matrix Spike Duplicate Sample (MSD) (%R) X X
MS/MSD Precision (RPD) X X
Laboratory Duplicate Sample (RPD) X X
Field Duplicate Sample (RPD) X X
Surrogate Spike Recoveries (%R) X X
Dilution Factor X X
Notes: %R Percent recovery RPD Relative percent difference
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INORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6010D, 2320B, 4500, 350.1, 3500Fe, 351.2, 353.2,410.4, 4500S2, 5210B, 9056A and 9060A.
Data were reviewed in accordance with USEPA National Functional Guidelines of October 2004.
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and that it was already subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with the USEPA National
Functional Guidelines:
• Concentration (C) Qualifiers
U The analyte was analyzed for but not detected. The associated value is the analyte
instrument detection limit.
J The reported value was obtained from a reading less than the reporting limit (RL), but
greater than or equal to the method detection limit (MDL).
• Quantitation (Q) Qualifiers
E The reported value is estimated due to the presence of interference.
N Spiked sample recovery is not within control limits.
* Duplicate analysis is not within control limits.
• Validation Qualifiers
J The analyte was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The analyte was not detected above the reporting limit. However, the reported limit is
approximate and may or may not represent the actual limit of detection.
UB Analyte is considered non-detect at the listed value due to associated blank contamination.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

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METALS ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
SW-846 6010D Water 180 days from collection to analysis Preserved to a pH of less
than 2.
All samples were analyzed within the specified holding times.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
Analytes were not detected above the MDL in the associated blanks; therefore, detected sample results
were not associated with blank contamination.
3. Matrix Spike / Matrix Spike Duplicate (MS/MSD) /Laboratory Duplicate Analysis
MS/MSD and laboratory duplicate data are used to assess the precision and accuracy of the analytical
method.
3.1 MS/MSD Analysis
All metal analytes must exhibit a percent recovery within the established acceptance limits of 75% to
125%. The MS recovery control limits do not apply for MS performed on sample locations where the
analyte’s concentration detected in the parent sample exceeds the MS concentration by a factor of four or
greater.
The MS/MSD analysis was performed on sample ID MW-5-W-20230127, exhibited acceptable recoveries
and RPDs.
3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was not performed on any of the samples from this SDG.
4. Field Duplicate Analysis
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Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices and 50% for soil matrices is applied to the
RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Field duplicate sample was not collected from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
The LCS analysis exhibited recoveries within the control limits.
8. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR METAL

METALS; SW-846 6010D Reported
Performance
Acceptable Not
Required No Yes No Yes
Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES)
Tier II Validation
Holding Times X X
Reporting limits (units) X X
Blanks
A. Instrument Blanks X X
B. Method Blanks X X
C. Equipment/Field Blanks X X
Laboratory Control Sample (LCS) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate (MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Reporting Limit Verification X X
Notes:
%R = Percent recovery
RPD = Relative percent difference

DATA REVIEW REPORT
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GENERAL CHEMISTRY ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
Alkalinity by SM 2320 B-11 Water 14 days from collection to
analysis Cool to <6 °C.
Free Carbon Dioxide by 4500CO2 Water 24 hours from collection to
analysis
Preserved to a pH of less
than 2.
Ammonia Nitrogen by 350.1 Water 28 days from collection to
analysis
Preserved to a pH of less
than 2.
Ferrous iron by 3500Fe Water 24 hours from collection to
analysis
Preserved to a pH of less
than 2.
Total Kjeldahl Nitrogen
by EPA 351.2 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Nitrogen, Nitrate-N + Nitrite-N
(combined result) by EPA 353.2 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Chemical Oxygen Demand (COD) by
SM5220 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Sulfide by 4500S2 Water 15 mins from collection to
analysis
Preserved to a pH of less
than 2.
Biological Oxygen Demand (BOD) by
SM5210 B-11 Water 48 hours from collection to
analysis Cool to <6 °C.
Sulfate by SW-846 300/9056A Water 28 days from collection to
analysis Cool to <6 °C.
Total Organic Carbon by SM5310 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
The analyses that exceeded the holding time are presented in the following table.
DATA REVIEW REPORT
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Sample Locations Analyte Holding Time Criteria
MW-9-W-20230127
MW-6-W-20230127
MW-5-W-20230127
Free Carbon Dioxide
Analysis completed greater
than two times holding time
24 hours from collection to analysis
Ferrous Iron
Sulfide 15 mins from collection to analysis
Sample results associated with sample locations analyzed by analytical methods mentioned above were
qualified, as specified in the table below. All other holding times were met.

Criteria
Qualification
Detected
Analytes
Non-detect
Analytes
Analysis completed less than two times holding time J UJ

2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
All analytes associated with the QA blanks exhibited a concentration less than the MDL, with the
exception of the analytes listed in the following table. Sample results associated with QA blank
contamination that were greater than the BAL resulted in the removal of the laboratory qualifier (B) of
data. Sample results less than the BAL associated with the following sample locations were qualified as
listed in the following table.

DATA REVIEW REPORT
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Sample Locations Analytes Sample Result Qualification
MW-6-W-20230127
MW-5-W-20230127 TOC (Total Organic Carbon) Detected sample results <RL and
<BAL “UB” at the RL
Note:
RL Reporting limit
3. Matrix Spike (MS)/Laboratory Duplicate Analysis
MS and laboratory duplicate data are used to assess the precision and accuracy of the analytical method.
3.1 MS Analysis
All analytes must exhibit a percent recovery within the established acceptance limits of 75% to 125%.
The MS recovery control limits do not apply for MS performed on sample locations where the analyte’s
concentration detected in the parent sample exceeds the MS concentration by a factor of four or greater.
In instance where this is true, the data will not be qualified even if the percent recovery does not meet the
control limits and the laboratory flag will be removed.
The MS/MSD analysis was performed on sample MW-5-W-20230127, exhibited acceptable recoveries.
Sample Location Analyte MS Recovery MSD Recovery
MW-5-W-20230127 Kjeldahl Nitrogen, TKN <LL but >10% <LL but >10%

The criteria used to evaluate MS/MSD recoveries are presented in the following table. In the case of an
MS/MSD deviation, the sample results are qualified. The qualifications are applied to all sample results
associated with this SDG.

Control limit Sample Result Qualification
MS/MSD percent recovery 30% to 74% Non-detect UJ
Detect J
MS/MSD percent recovery <30% Non-detect R
Detect J
MS/MSD percent recovery >125% Non-detect No Action
Detect J
Sample locations associated with MS/MSD recoveries exhibiting an RPD greater than of the control limit
are presented in the following table.

Sample Location Analytes
MW-5-W-20230127 Kjeldahl Nitrogen, TKN
The criteria used to evaluate MS/MSD RPD are presented in the following table. In the case of a
MS/MSD RPD deviation, the sample results are qualified. The qualifications are applied to the all sample
results associated with this SDG.
DATA REVIEW REPORT
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Control Limit Sample Result Qualification
>UL Non-detect UJ
Detect J

3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was performed on sample ID MW-5-W-20230127 and MW-9-W-
20230127, exhibited acceptable RPDs.
4. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 50% for water matrices and 100% for soil matrices is applied to the
RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Field duplicate sample was not collected from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
Sample locations associated with LCS analysis exhibiting recoveries outside of the control limits
presented in the following table.
Sample Locations Compound LCS Recovery
MW-9-W-20230127
MW-6-W-20230127
MW-5-W-20230127
BOD <LL but >10%
The criteria used to evaluate the LCS recoveries are presented in the following table. In the case of an
LCS deviation, the sample results are qualified as documented in the table below.

Control Limit Sample Result Qualification
> the upper control limit (UL) Non-detect No Action
Detect J
< the lower control limit (LL) but > 10% Non-detect UJ
Detect J
DATA REVIEW REPORT
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Control Limit Sample Result Qualification
< 10% Non-detect R
Detect J

6. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR GENERAL CHEMISTRY

General Chemistry Reported Performance
Acceptable Not
Required No Yes No Yes
Miscellaneous Instrumentation
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Field blanks X X
Laboratory Control Sample (LCS) %R X X
Laboratory Control Sample Duplicate (LCSD) %R X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate (MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Dilution Factor X X
Moisture Content X X
Notes:
%R - percent recovery
RPD - relative percent difference,
%D – difference

DATA REVIEW REPORT
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VALIDATION PERFORMED BY: Bhagyashree Fulzele
SIGNATURE:
DATE: February 21, 2023

PEER REVIEW: Dennis Capria
DATE: March 2, 2023

CHAIN OF CUSTODY
CORRECTED SAMPLE ANALYSIS DATA
SHEETS

SAMPLE RESULTS - 01
L1580443
MW-9-W-20230127
Collected date/time: 01/27/23 09:42
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/31/2023 08:20 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:49 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 226000 20000 1 02/06/2023 08:35 WG1998655
Free Carbon Dioxide 62500 B T8 20000 1 02/06/2023 08:35 WG1998655
Sample Narrative:
L1580443-01 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:39 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 5770 T8 150 500 10 01/30/2023 16:52 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:49 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 02/08/2023 21:56 WG2001845
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 122000 11700 20000 1 01/30/2023 17:57 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:35 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 9.98 K6 T8 2.00 1 02/05/2023 08:28 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 01
L1580443
MW-9-W-20230127
Collected date/time: 01/27/23 09:42
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 2010 Q 48.0 100 1 01/31/2023 01:48 WG1997192
Nitrite U Q 42.0 100 1 01/31/2023 01:48 WG1997192
Sulfate 3750 J 594 5000 1 01/31/2023 01:48 WG1997192
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)19200 510 5000 5 01/31/2023 09:38 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 5570 18.0 100 1 01/31/2023 08:20 WG1996965
Manganese 5480 0.934 10.0 1 01/31/2023 08:20 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 97.1 2.91 10.0 1 01/31/2023 13:56 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 2260 10000 200 02/07/2023 15:47 WG2000693
Acrolein U 508 10000 200 02/07/2023 15:47 WG2000693
Acrylonitrile U 134 2000 200 02/07/2023 15:47 WG2000693
Benzene 8240 18.8 200 200 02/07/2023 15:47 WG2000693
Bromobenzene U 23.6 200 200 02/07/2023 15:47 WG2000693
Bromodichloromethane U 27.2 200 200 02/07/2023 15:47 WG2000693
Bromoform U 25.8 200 200 02/07/2023 15:47 WG2000693
Bromomethane U 121 1000 200 02/07/2023 16:33 WG2001829
n-Butylbenzene U 31.4 200 200 02/07/2023 15:47 WG2000693
sec-Butylbenzene U 25.0 200 200 02/07/2023 15:47 WG2000693
tert-Butylbenzene U 25.4 200 200 02/07/2023 15:47 WG2000693
Carbon tetrachloride U 25.6 200 200 02/07/2023 15:47 WG2000693
Chlorobenzene U 23.2 200 200 02/07/2023 15:47 WG2000693
Chlorodibromomethane U 28.0 200 200 02/07/2023 15:47 WG2000693
Chloroethane U 38.4 1000 200 02/07/2023 16:33 WG2001829
Chloroform U 22.2 1000 200 02/07/2023 15:47 WG2000693
Chloromethane U 192 500 200 02/07/2023 15:47 WG2000693
2-Chlorotoluene U 21.2 200 200 02/07/2023 15:47 WG2000693
4-Chlorotoluene U 22.8 200 200 02/07/2023 15:47 WG2000693
1,2-Dibromo-3-Chloropropane U 55.2 1000 200 02/07/2023 15:47 WG2000693
1,2-Dibromoethane U 25.2 200 200 02/07/2023 15:47 WG2000693
Dibromomethane U 24.4 200 200 02/07/2023 15:47 WG2000693
1,2-Dichlorobenzene U 21.4 200 200 02/07/2023 15:47 WG2000693
1,3-Dichlorobenzene U 22.0 200 200 02/07/2023 15:47 WG2000693
1,4-Dichlorobenzene U 24.0 200 200 02/07/2023 15:47 WG2000693
Dichlorodifluoromethane U 74.8 1000 200 02/07/2023 15:47 WG2000693
1,1-Dichloroethane U 20.0 200 200 02/07/2023 15:47 WG2000693
1,2-Dichloroethane 47.7 J 16.4 200 200 02/07/2023 15:47 WG2000693
1,1-Dichloroethene U 37.6 200 200 02/07/2023 15:47 WG2000693
cis-1,2-Dichloroethene U 25.2 200 200 02/07/2023 15:47 WG2000693
trans-1,2-Dichloroethene U 29.8 200 200 02/07/2023 15:47 WG2000693
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 01
L1580443
MW-9-W-20230127
Collected date/time: 01/27/23 09:42
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 29.8 200 200 02/07/2023 15:47 WG2000693
1,1-Dichloropropene U 28.4 200 200 02/07/2023 15:47 WG2000693
1,3-Dichloropropane U 22.0 200 200 02/07/2023 15:47 WG2000693
2,2-Dichloropropane U 32.2 200 200 02/07/2023 15:47 WG2000693
Di-isopropyl ether U 21.0 200 200 02/07/2023 15:47 WG2000693
Ethylbenzene 2960 27.4 200 200 02/07/2023 15:47 WG2000693
Hexachloro-1,3-butadiene U 67.4 200 200 02/07/2023 15:47 WG2000693
Isopropylbenzene 142 J 21.0 200 200 02/07/2023 15:47 WG2000693
p-Isopropyltoluene U 24.0 200 200 02/07/2023 15:47 WG2000693
2-Butanone (MEK)U 238 2000 200 02/07/2023 15:47 WG2000693
Methylene Chloride U 86.0 1000 200 02/07/2023 15:47 WG2000693
4-Methyl-2-pentanone (MIBK)U 95.6 2000 200 02/07/2023 15:47 WG2000693
Methyl tert-butyl ether 11300 20.2 200 200 02/07/2023 15:47 WG2000693
Naphthalene 251 J 200 1000 200 02/07/2023 15:47 WG2000693
n-Propylbenzene 370 19.9 200 200 02/07/2023 15:47 WG2000693
Styrene U 23.6 200 200 02/07/2023 15:47 WG2000693
1,1,1,2-Tetrachloroethane U 29.4 200 200 02/07/2023 15:47 WG2000693
1,1,2,2-Tetrachloroethane U 26.6 200 200 02/07/2023 15:47 WG2000693
Tetrachloroethene U 60.0 200 200 02/07/2023 15:47 WG2000693
Toluene 86.4 J 55.6 200 200 02/07/2023 15:47 WG2000693
1,2,3-Trichlorobenzene U 46.0 200 200 02/07/2023 15:47 WG2000693
1,2,4-Trichlorobenzene U 96.2 200 200 02/07/2023 15:47 WG2000693
1,1,1-Trichloroethane U 29.8 200 200 02/07/2023 15:47 WG2000693
1,1,2-Trichloroethane U 31.6 200 200 02/07/2023 15:47 WG2000693
Trichloroethene U 38.0 200 200 02/07/2023 15:47 WG2000693
Trichlorofluoromethane U 32.0 1000 200 02/07/2023 15:47 WG2000693
1,2,3-Trichloropropane U 47.4 500 200 02/07/2023 15:47 WG2000693
1,2,4-Trimethylbenzene 417 64.4 200 200 02/07/2023 15:47 WG2000693
1,3,5-Trimethylbenzene 140 J 20.8 200 200 02/07/2023 15:47 WG2000693
Vinyl chloride U 46.8 200 200 02/07/2023 15:47 WG2000693
o-Xylene 129 J 34.8 200 200 02/07/2023 15:47 WG2000693
m&p-Xylenes 432 86.0 400 200 02/07/2023 15:47 WG2000693
(S) Toluene-d8 103 80.0-120 02/07/2023 15:47 WG2000693
(S) Toluene-d8 91.8 80.0-120 02/07/2023 16:33 WG2001829
(S) 4-Bromofluorobenzene 100 77.0-126 02/07/2023 15:47 WG2000693
(S) 4-Bromofluorobenzene 83.7 77.0-126 02/07/2023 16:33 WG2001829
(S) 1,2-Dichloroethane-d4 92.8 70.0-130 02/07/2023 15:47 WG2000693
(S) 1,2-Dichloroethane-d4 104 70.0-130 02/07/2023 16:33 WG2001829
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 8 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 8 of 47
SAMPLE RESULTS - 02
L1580443
MW-6-W-20230127
Collected date/time: 01/27/23 12:22
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 351 15.0 50.0 1 01/31/2023 08:23 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:50 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity U 20000 1 02/06/2023 08:39 WG1998655
Free Carbon Dioxide ND T8 20000 1 02/06/2023 08:39 WG1998655
Sample Narrative:
L1580443-02 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:40 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/30/2023 16:52 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/31/2023 18:50 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 1180 50.0 100 1 02/01/2023 20:40 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 18:20 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:35 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K1 K6 T8 2.00 1 02/05/2023 08:33 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 9 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 9 of 47
SAMPLE RESULTS - 02
L1580443
MW-6-W-20230127
Collected date/time: 01/27/23 12:22
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 1240 Q 48.0 100 1 01/31/2023 02:52 WG1997192
Nitrite U Q 42.0 100 1 01/31/2023 02:52 WG1997192
Sulfate 19100 594 5000 1 01/31/2023 02:52 WG1997192
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)320 B J 102 1000 1 01/31/2023 10:32 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 351 18.0 100 1 01/31/2023 08:23 WG1996965
Manganese 16.7 0.934 10.0 1 01/31/2023 08:23 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 13:59 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 17:28 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 17:28 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 17:28 WG2000115
Benzene 6.90 0.0941 1.00 1 02/05/2023 17:28 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 17:28 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 17:28 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 17:28 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 17:28 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 17:28 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 17:28 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 17:28 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 17:28 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 17:28 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 17:28 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 17:28 WG2000115
Chloroform U 0.111 5.00 1 02/05/2023 17:28 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 17:28 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 17:28 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 17:28 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 17:28 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 17:28 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 17:28 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 17:28 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 17:28 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 17:28 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 17:28 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 17:28 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 17:28 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 17:28 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 17:28 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 17:28 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 10 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 10 of 47
SAMPLE RESULTS - 02
L1580443
MW-6-W-20230127
Collected date/time: 01/27/23 12:22
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 17:28 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 17:28 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 17:28 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 17:28 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 17:28 WG2000115
Ethylbenzene 3.52 0.137 1.00 1 02/05/2023 17:28 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 17:28 WG2000115
Isopropylbenzene 0.155 J 0.105 1.00 1 02/05/2023 17:28 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 17:28 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 17:28 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 17:28 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 17:28 WG2000115
Methyl tert-butyl ether 0.255 J 0.101 1.00 1 02/05/2023 17:28 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 17:28 WG2000115
n-Propylbenzene 0.374 J 0.0993 1.00 1 02/05/2023 17:28 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 17:28 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 17:28 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 17:28 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 17:28 WG2000115
Toluene 0.470 J 0.278 1.00 1 02/05/2023 17:28 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 17:28 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 17:28 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 17:28 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 17:28 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 17:28 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 17:28 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 17:28 WG2000115
1,2,4-Trimethylbenzene 0.635 J 0.322 1.00 1 02/05/2023 17:28 WG2000115
1,3,5-Trimethylbenzene 0.232 J 0.104 1.00 1 02/05/2023 17:28 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 17:28 WG2000115
o-Xylene 0.699 J 0.174 1.00 1 02/05/2023 17:28 WG2000115
m&p-Xylenes 1.83 J 0.430 2.00 1 02/05/2023 17:28 WG2000115
(S) Toluene-d8 91.5 80.0-120 02/05/2023 17:28 WG2000115
(S) 4-Bromofluorobenzene 83.4 77.0-126 02/05/2023 17:28 WG2000115
(S) 1,2-Dichloroethane-d4 114 70.0-130 02/05/2023 17:28 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 11 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 11 of 47
SAMPLE RESULTS - 03
L1580443
MW-5-W-20230127
Collected date/time: 01/27/23 14:35
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 2860 15.0 50.0 1 01/31/2023 07:45 WG1996965
Organic Nitrogen U 117 250 1 01/31/2023 18:54 WG1997036
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 11600 J 20000 1 02/06/2023 08:44 WG1998655
Free Carbon Dioxide 72500 B T8 20000 1 02/06/2023 08:44 WG1998655
Sample Narrative:
L1580443-03 WG1998655: Endpoint pH 4.5
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/30/2023 14:46 WG1997036
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U P1 T8 15.0 50.0 1 01/30/2023 16:53 WG1996879
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U J3 J6 140 250 1 01/31/2023 18:54 WG1997080
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 11600 250 500 5 02/01/2023 20:41 WG1997093
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/30/2023 18:29 WG1997000
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/31/2023 11:35 WG1997328
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K1 K6 T8 2.00 1 02/05/2023 08:37 WG1997413
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 12 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 12 of 47
SAMPLE RESULTS - 03
L1580443
MW-5-W-20230127
Collected date/time: 01/27/23 14:35
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 11300 Q 48.0 100 1 01/31/2023 03:07 WG1997192
Nitrite U Q 42.0 100 1 01/31/2023 03:07 WG1997192
Sulfate 12400 594 5000 1 01/31/2023 03:07 WG1997192
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)551 B J 102 1000 1 01/31/2023 10:48 WG1997261
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 2860 18.0 100 1 01/31/2023 07:45 WG1996965
Manganese 56.7 0.934 10.0 1 01/31/2023 07:45 WG1996965
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/31/2023 14:04 WG1997438
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 17:48 WG2000115
Acrolein U C4 2.54 50.0 1 02/05/2023 17:48 WG2000115
Acrylonitrile U 0.671 10.0 1 02/05/2023 17:48 WG2000115
Benzene 3.14 0.0941 1.00 1 02/05/2023 17:48 WG2000115
Bromobenzene U 0.118 1.00 1 02/05/2023 17:48 WG2000115
Bromodichloromethane U 0.136 1.00 1 02/05/2023 17:48 WG2000115
Bromoform U 0.129 1.00 1 02/05/2023 17:48 WG2000115
Bromomethane U 0.605 5.00 1 02/05/2023 17:48 WG2000115
n-Butylbenzene U 0.157 1.00 1 02/05/2023 17:48 WG2000115
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 17:48 WG2000115
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 17:48 WG2000115
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 17:48 WG2000115
Chlorobenzene U 0.116 1.00 1 02/05/2023 17:48 WG2000115
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 17:48 WG2000115
Chloroethane U 0.192 5.00 1 02/05/2023 17:48 WG2000115
Chloroform 0.297 J 0.111 5.00 1 02/05/2023 17:48 WG2000115
Chloromethane U 0.960 2.50 1 02/05/2023 17:48 WG2000115
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 17:48 WG2000115
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 17:48 WG2000115
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 17:48 WG2000115
1,2-Dibromoethane U 0.126 1.00 1 02/05/2023 17:48 WG2000115
Dibromomethane U 0.122 1.00 1 02/05/2023 17:48 WG2000115
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 17:48 WG2000115
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 17:48 WG2000115
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 17:48 WG2000115
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 17:48 WG2000115
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 17:48 WG2000115
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 17:48 WG2000115
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 17:48 WG2000115
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 17:48 WG2000115
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 17:48 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 17:44 13 of 47
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1580443 02/16/23 18:01 13 of 47
SAMPLE RESULTS - 03
L1580443
MW-5-W-20230127
Collected date/time: 01/27/23 14:35
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 17:48 WG2000115
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 17:48 WG2000115
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 17:48 WG2000115
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 17:48 WG2000115
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 17:48 WG2000115
Ethylbenzene 2.80 0.137 1.00 1 02/05/2023 17:48 WG2000115
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 17:48 WG2000115
Isopropylbenzene 0.150 J 0.105 1.00 1 02/05/2023 17:48 WG2000115
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 17:48 WG2000115
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 17:48 WG2000115
Methylene Chloride U 0.430 5.00 1 02/05/2023 17:48 WG2000115
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 17:48 WG2000115
Methyl tert-butyl ether 0.131 J 0.101 1.00 1 02/05/2023 17:48 WG2000115
Naphthalene U 1.00 5.00 1 02/05/2023 17:48 WG2000115
n-Propylbenzene 0.335 J 0.0993 1.00 1 02/05/2023 17:48 WG2000115
Styrene U 0.118 1.00 1 02/05/2023 17:48 WG2000115
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 17:48 WG2000115
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 17:48 WG2000115
Tetrachloroethene U 0.300 1.00 1 02/05/2023 17:48 WG2000115
Toluene 0.549 J 0.278 1.00 1 02/05/2023 17:48 WG2000115
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 17:48 WG2000115
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 17:48 WG2000115
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 17:48 WG2000115
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 17:48 WG2000115
Trichloroethene U 0.190 1.00 1 02/05/2023 17:48 WG2000115
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 17:48 WG2000115
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 17:48 WG2000115
1,2,4-Trimethylbenzene 0.889 J 0.322 1.00 1 02/05/2023 17:48 WG2000115
1,3,5-Trimethylbenzene 0.308 J 0.104 1.00 1 02/05/2023 17:48 WG2000115
Vinyl chloride U 0.234 1.00 1 02/05/2023 17:48 WG2000115
o-Xylene 0.901 J 0.174 1.00 1 02/05/2023 17:48 WG2000115
m&p-Xylenes 2.39 0.430 2.00 1 02/05/2023 17:48 WG2000115
(S) Toluene-d8 91.6 80.0-120 02/05/2023 17:48 WG2000115
(S) 4-Bromofluorobenzene 82.1 77.0-126 02/05/2023 17:48 WG2000115
(S) 1,2-Dichloroethane-d4 108 70.0-130 02/05/2023 17:48 WG2000115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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ANALYTICAL REPORT
February 06, 2023
Arcadis - Chevron - NC
Sample Delivery Group:L1579449
Samples Received:01/26/2023
Project Number:30064349
Description:Pod 2 - High Point, NC #205513
Site:205513
Report To:Andrew DrMarco
801 Corporate Center Drive
Suite 300
Raleigh, NC 27607
Entire Report Reviewed By:
February 06, 2023
[Preliminary Report]
Chris McCord
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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February 06, 2023
Chris McCord
Project Manager
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TABLE OF CONTENTS
Cp: Cover Page 1
Tc: Table of Contents 2
Ss: Sample Summary 3
Cn: Case Narrative 5
Sr: Sample Results 6
FB-W-20230124 L1579449-01 6
MW-1-W-20230124 L1579449-02 9
MW-8-W-20230124 L1579449-03 12
Qc: Quality Control Summary 15
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 15
Wet Chemistry by Method 350.1 17
Wet Chemistry by Method 3500Fe B-2011 18
Wet Chemistry by Method 351.2 19
Wet Chemistry by Method 353.2 21
Wet Chemistry by Method 410.4 22
Wet Chemistry by Method 4500S2 D-2011 23
Wet Chemistry by Method 5210 B-2016 24
Wet Chemistry by Method 9056A 25
Wet Chemistry by Method 9060A 27
Metals (ICP) by Method 6010D 29
Volatile Organic Compounds (GC) by Method RSK175 30
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 31
Gl: Glossary of Terms 43
Al: Accreditations & Locations 45
Sc: Sample Chain of Custody 46
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
FB-W-20230124 L1579449-01 GW AVGB 01/24/23 15:30 01/26/23 09:30
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1995451 1 01/27/23 19:21 01/27/23 19:21 ZSA Mt. Juliet, TN
Calculated Results WG1996518 1 01/30/23 20:34 01/30/23 20:34 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1996728 1 01/30/23 11:57 01/30/23 11:57 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1996728 1 01/30/23 11:57 01/30/23 11:57 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1996518 1 01/29/23 12:23 01/29/23 12:23 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1995406 1 01/26/23 16:09 01/26/23 16:09 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1995623 1 01/29/23 17:32 01/30/23 20:34 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1995337 1 01/26/23 23:25 01/26/23 23:25 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1995674 1 01/27/23 08:33 01/27/23 11:03 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1995699 1 01/27/23 09:37 01/27/23 09:37 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1995348 1 01/26/23 15:10 01/31/23 11:46 EAO Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1995168 1 01/26/23 12:45 01/26/23 12:45 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1995911 1 01/28/23 14:07 01/28/23 14:07 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1995451 1 01/26/23 17:06 01/27/23 19:21 ZSA Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1995695 1 01/27/23 11:07 01/27/23 11:07 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1997802 1 01/31/23 22:44 01/31/23 22:44 ADM Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW-1-W-20230124 L1579449-02 GW AVGB 01/24/23 14:12 01/26/23 09:30
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1995451 1 01/27/23 19:29 01/27/23 19:29 ZSA Mt. Juliet, TN
Calculated Results WG1996518 1 01/30/23 20:36 01/30/23 20:36 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1996728 1 01/30/23 12:00 01/30/23 12:00 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1996728 1 01/30/23 12:00 01/30/23 12:00 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1996518 1 01/29/23 12:24 01/29/23 12:24 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1995406 1 01/26/23 16:09 01/26/23 16:09 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1995623 1 01/29/23 17:32 01/30/23 20:36 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1995337 1 01/26/23 23:29 01/26/23 23:29 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1995674 1 01/27/23 08:33 01/27/23 11:05 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1995699 1 01/27/23 09:39 01/27/23 09:39 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1995348 1 01/26/23 14:11 01/31/23 11:48 EAO Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1995168 1 01/26/23 12:59 01/26/23 12:59 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1995911 1 01/28/23 15:04 01/28/23 15:04 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1995451 1 01/26/23 17:06 01/27/23 19:29 ZSA Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1995695 1 01/27/23 11:09 01/27/23 11:09 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1999697 1 02/05/23 16:27 02/05/23 16:27 ACG Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW-8-W-20230124 L1579449-03 GW AVGB 01/24/23 10:37 01/26/23 09:30
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1995451 1 01/27/23 19:31 01/27/23 19:31 ABL Mt. Juliet, TN
Calculated Results WG1996518 1 01/30/23 20:37 01/30/23 20:37 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1996728 1 01/30/23 12:03 01/30/23 12:03 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1996728 1 01/30/23 12:03 01/30/23 12:03 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1996518 1 01/29/23 12:29 01/29/23 12:29 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1995406 20 01/26/23 16:16 01/26/23 16:16 CAH Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1995623 1 01/29/23 17:32 01/30/23 20:37 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG1995337 1 01/26/23 23:30 01/26/23 23:30 JCS Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1995674 5 01/27/23 08:33 01/27/23 11:05 NEF Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1995699 1 01/27/23 09:39 01/27/23 09:39 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1995348 10 01/26/23 15:19 01/31/23 11:54 EAO Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW-8-W-20230124 L1579449-03 GW AVGB 01/24/23 10:37 01/26/23 09:30
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Wet Chemistry by Method 9056A WG1995168 1 01/26/23 13:48 01/26/23 13:48 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1996504 5 01/30/23 09:41 01/30/23 09:41 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1995451 1 01/26/23 17:06 01/27/23 19:31 ZSA Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1995451 5 01/26/23 17:06 01/29/23 22:32 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1995695 1 01/27/23 11:12 01/27/23 11:12 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1998813 2500 02/02/23 16:17 02/02/23 16:17 DWR Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
[Preliminary Report]
Chris McCord
Project Manager
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Chris McCord
Project Manager
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SAMPLE RESULTS - 01
L1579449
FB-W-20230124
Collected date/time: 01/24/23 15:30
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 15.0 50.0 1 01/27/2023 19:21 WG1995451
Organic Nitrogen U 117 250 1 01/30/2023 20:34 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity U 20000 1 01/30/2023 11:57 WG1996728
Free Carbon Dioxide ND T8 20000 1 01/30/2023 11:57 WG1996728
Sample Narrative:
L1579449-01 WG1996728: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:23 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/26/2023 16:09 WG1995406
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/30/2023 20:34 WG1995623
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 01/26/2023 23:25 WG1995337
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/27/2023 11:03 WG1995674
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/27/2023 09:37 WG1995699
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 1.07 K1 K5 1.00 1 01/31/2023 11:46 WG1995348
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1579449
FB-W-20230124
Collected date/time: 01/24/23 15:30
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U 48.0 100 1 01/26/2023 12:45 WG1995168
Nitrite U 42.0 100 1 01/26/2023 12:45 WG1995168
Sulfate 1370 J 594 5000 1 01/26/2023 12:45 WG1995168
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)532 B J 102 1000 1 01/28/2023 14:07 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron U 18.0 100 1 01/27/2023 19:21 WG1995451
Manganese U 0.934 10.0 1 01/27/2023 19:21 WG1995451
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/27/2023 11:07 WG1995695
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 01/31/2023 22:44 WG1997802
Acrolein U 2.54 50.0 1 01/31/2023 22:44 WG1997802
Acrylonitrile U 0.671 10.0 1 01/31/2023 22:44 WG1997802
Benzene U 0.0941 1.00 1 01/31/2023 22:44 WG1997802
Bromobenzene U 0.118 1.00 1 01/31/2023 22:44 WG1997802
Bromodichloromethane U 0.136 1.00 1 01/31/2023 22:44 WG1997802
Bromoform U 0.129 1.00 1 01/31/2023 22:44 WG1997802
Bromomethane U 0.605 5.00 1 01/31/2023 22:44 WG1997802
n-Butylbenzene U 0.157 1.00 1 01/31/2023 22:44 WG1997802
sec-Butylbenzene U 0.125 1.00 1 01/31/2023 22:44 WG1997802
tert-Butylbenzene U 0.127 1.00 1 01/31/2023 22:44 WG1997802
Carbon tetrachloride U 0.128 1.00 1 01/31/2023 22:44 WG1997802
Chlorobenzene U 0.116 1.00 1 01/31/2023 22:44 WG1997802
Chlorodibromomethane U 0.140 1.00 1 01/31/2023 22:44 WG1997802
Chloroethane U J3 0.192 5.00 1 01/31/2023 22:44 WG1997802
Chloroform U 0.111 5.00 1 01/31/2023 22:44 WG1997802
Chloromethane U J3 0.960 2.50 1 01/31/2023 22:44 WG1997802
2-Chlorotoluene U 0.106 1.00 1 01/31/2023 22:44 WG1997802
4-Chlorotoluene U 0.114 1.00 1 01/31/2023 22:44 WG1997802
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/31/2023 22:44 WG1997802
1,2-Dibromoethane U 0.126 1.00 1 01/31/2023 22:44 WG1997802
Dibromomethane U 0.122 1.00 1 01/31/2023 22:44 WG1997802
1,2-Dichlorobenzene U 0.107 1.00 1 01/31/2023 22:44 WG1997802
1,3-Dichlorobenzene U 0.110 1.00 1 01/31/2023 22:44 WG1997802
1,4-Dichlorobenzene U 0.120 1.00 1 01/31/2023 22:44 WG1997802
Dichlorodifluoromethane U 0.374 5.00 1 01/31/2023 22:44 WG1997802
1,1-Dichloroethane U 0.100 1.00 1 01/31/2023 22:44 WG1997802
1,2-Dichloroethane U 0.0819 1.00 1 01/31/2023 22:44 WG1997802
1,1-Dichloroethene U 0.188 1.00 1 01/31/2023 22:44 WG1997802
cis-1,2-Dichloroethene U 0.126 1.00 1 01/31/2023 22:44 WG1997802
trans-1,2-Dichloroethene U 0.149 1.00 1 01/31/2023 22:44 WG1997802
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1579449
FB-W-20230124
Collected date/time: 01/24/23 15:30
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 01/31/2023 22:44 WG1997802
1,1-Dichloropropene U 0.142 1.00 1 01/31/2023 22:44 WG1997802
1,3-Dichloropropane U 0.110 1.00 1 01/31/2023 22:44 WG1997802
2,2-Dichloropropane U 0.161 1.00 1 01/31/2023 22:44 WG1997802
Di-isopropyl ether U 0.105 1.00 1 01/31/2023 22:44 WG1997802
Ethylbenzene U 0.137 1.00 1 01/31/2023 22:44 WG1997802
Hexachloro-1,3-butadiene U 0.337 1.00 1 01/31/2023 22:44 WG1997802
Isopropylbenzene U 0.105 1.00 1 01/31/2023 22:44 WG1997802
p-Isopropyltoluene U 0.120 1.00 1 01/31/2023 22:44 WG1997802
2-Butanone (MEK)U 1.19 10.0 1 01/31/2023 22:44 WG1997802
Methylene Chloride 1.59 J 0.430 5.00 1 01/31/2023 22:44 WG1997802
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 01/31/2023 22:44 WG1997802
Methyl tert-butyl ether U 0.101 1.00 1 01/31/2023 22:44 WG1997802
Naphthalene U 1.00 5.00 1 01/31/2023 22:44 WG1997802
n-Propylbenzene U 0.0993 1.00 1 01/31/2023 22:44 WG1997802
Styrene U 0.118 1.00 1 01/31/2023 22:44 WG1997802
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/31/2023 22:44 WG1997802
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/31/2023 22:44 WG1997802
Tetrachloroethene U 0.300 1.00 1 01/31/2023 22:44 WG1997802
Toluene 0.469 J 0.278 1.00 1 01/31/2023 22:44 WG1997802
1,2,3-Trichlorobenzene U 0.230 1.00 1 01/31/2023 22:44 WG1997802
1,2,4-Trichlorobenzene U 0.481 1.00 1 01/31/2023 22:44 WG1997802
1,1,1-Trichloroethane U 0.149 1.00 1 01/31/2023 22:44 WG1997802
1,1,2-Trichloroethane U 0.158 1.00 1 01/31/2023 22:44 WG1997802
Trichloroethene U 0.190 1.00 1 01/31/2023 22:44 WG1997802
Trichlorofluoromethane 0.809 J 0.160 5.00 1 01/31/2023 22:44 WG1997802
1,2,3-Trichloropropane U 0.237 2.50 1 01/31/2023 22:44 WG1997802
1,2,4-Trimethylbenzene U 0.322 1.00 1 01/31/2023 22:44 WG1997802
1,3,5-Trimethylbenzene U 0.104 1.00 1 01/31/2023 22:44 WG1997802
Vinyl chloride U 0.234 1.00 1 01/31/2023 22:44 WG1997802
o-Xylene U J4 0.174 1.00 1 01/31/2023 22:44 WG1997802
m&p-Xylenes U 0.430 2.00 1 01/31/2023 22:44 WG1997802
(S) Toluene-d8 90.3 80.0-120 01/31/2023 22:44 WG1997802
(S) 4-Bromofluorobenzene 79.7 77.0-126 01/31/2023 22:44 WG1997802
(S) 1,2-Dichloroethane-d4 107 70.0-130 01/31/2023 22:44 WG1997802
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 02
L1579449
MW-1-W-20230124
Collected date/time: 01/24/23 14:12
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 1740 15.0 50.0 1 01/27/2023 19:29 WG1995451
Organic Nitrogen U 117 250 1 01/30/2023 20:36 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 55300 20000 1 01/30/2023 12:00 WG1996728
Free Carbon Dioxide 114000 T8 20000 1 01/30/2023 12:00 WG1996728
Sample Narrative:
L1579449-02 WG1996728: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:24 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 50.0 J T8 15.0 50.0 1 01/26/2023 16:09 WG1995406
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/30/2023 20:36 WG1995623
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 1520 50.0 100 1 01/26/2023 23:29 WG1995337
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/27/2023 11:05 WG1995674
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/27/2023 09:39 WG1995699
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K5 1.00 1 01/31/2023 11:48 WG1995348
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 02
L1579449
MW-1-W-20230124
Collected date/time: 01/24/23 14:12
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 1240 48.0 100 1 01/26/2023 12:59 WG1995168
Nitrite U 42.0 100 1 01/26/2023 12:59 WG1995168
Sulfate 3280 J 594 5000 1 01/26/2023 12:59 WG1995168
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)810 B J 102 1000 1 01/28/2023 15:04 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 1790 18.0 100 1 01/27/2023 19:29 WG1995451
Manganese 47.4 0.934 10.0 1 01/27/2023 19:29 WG1995451
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/27/2023 11:09 WG1995695
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 16:27 WG1999697
Acrolein U C4 2.54 50.0 1 02/05/2023 16:27 WG1999697
Acrylonitrile U 0.671 10.0 1 02/05/2023 16:27 WG1999697
Benzene 15.7 0.0941 1.00 1 02/05/2023 16:27 WG1999697
Bromobenzene U 0.118 1.00 1 02/05/2023 16:27 WG1999697
Bromodichloromethane U 0.136 1.00 1 02/05/2023 16:27 WG1999697
Bromoform U 0.129 1.00 1 02/05/2023 16:27 WG1999697
Bromomethane U 0.605 5.00 1 02/05/2023 16:27 WG1999697
n-Butylbenzene U 0.157 1.00 1 02/05/2023 16:27 WG1999697
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 16:27 WG1999697
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 16:27 WG1999697
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 16:27 WG1999697
Chlorobenzene U 0.116 1.00 1 02/05/2023 16:27 WG1999697
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 16:27 WG1999697
Chloroethane U 0.192 5.00 1 02/05/2023 16:27 WG1999697
Chloroform U 0.111 5.00 1 02/05/2023 16:27 WG1999697
Chloromethane U 0.960 2.50 1 02/05/2023 16:27 WG1999697
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 16:27 WG1999697
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 16:27 WG1999697
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 16:27 WG1999697
1,2-Dibromoethane 0.130 J 0.126 1.00 1 02/05/2023 16:27 WG1999697
Dibromomethane U 0.122 1.00 1 02/05/2023 16:27 WG1999697
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 16:27 WG1999697
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 16:27 WG1999697
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 16:27 WG1999697
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 16:27 WG1999697
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 16:27 WG1999697
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 16:27 WG1999697
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 16:27 WG1999697
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 16:27 WG1999697
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 16:27 WG1999697
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 02
L1579449
MW-1-W-20230124
Collected date/time: 01/24/23 14:12
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 16:27 WG1999697
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 16:27 WG1999697
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 16:27 WG1999697
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 16:27 WG1999697
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 16:27 WG1999697
Ethylbenzene 3.26 0.137 1.00 1 02/05/2023 16:27 WG1999697
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 16:27 WG1999697
Isopropylbenzene 0.114 J 0.105 1.00 1 02/05/2023 16:27 WG1999697
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 16:27 WG1999697
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 16:27 WG1999697
Methylene Chloride U 0.430 5.00 1 02/05/2023 16:27 WG1999697
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 16:27 WG1999697
Methyl tert-butyl ether 2.49 0.101 1.00 1 02/05/2023 16:27 WG1999697
Naphthalene U 1.00 5.00 1 02/05/2023 16:27 WG1999697
n-Propylbenzene 0.236 J 0.0993 1.00 1 02/05/2023 16:27 WG1999697
Styrene U 0.118 1.00 1 02/05/2023 16:27 WG1999697
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 16:27 WG1999697
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 16:27 WG1999697
Tetrachloroethene U 0.300 1.00 1 02/05/2023 16:27 WG1999697
Toluene 8.04 0.278 1.00 1 02/05/2023 16:27 WG1999697
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 16:27 WG1999697
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 16:27 WG1999697
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 16:27 WG1999697
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 16:27 WG1999697
Trichloroethene U 0.190 1.00 1 02/05/2023 16:27 WG1999697
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 16:27 WG1999697
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 16:27 WG1999697
1,2,4-Trimethylbenzene 1.59 0.322 1.00 1 02/05/2023 16:27 WG1999697
1,3,5-Trimethylbenzene 0.407 J 0.104 1.00 1 02/05/2023 16:27 WG1999697
Vinyl chloride U 0.234 1.00 1 02/05/2023 16:27 WG1999697
o-Xylene 5.44 0.174 1.00 1 02/05/2023 16:27 WG1999697
m&p-Xylenes 11.0 0.430 2.00 1 02/05/2023 16:27 WG1999697
(S) Toluene-d8 92.3 80.0-120 02/05/2023 16:27 WG1999697
(S) 4-Bromofluorobenzene 85.6 77.0-126 02/05/2023 16:27 WG1999697
(S) 1,2-Dichloroethane-d4 110 70.0-130 02/05/2023 16:27 WG1999697
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 03
L1579449
MW-8-W-20230124
Collected date/time: 01/24/23 10:37
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/27/2023 19:31 WG1995451
Organic Nitrogen 266 117 250 1 01/30/2023 20:37 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 233000 20000 1 01/30/2023 12:03 WG1996728
Free Carbon Dioxide 112000 T8 20000 1 01/30/2023 12:03 WG1996728
Sample Narrative:
L1579449-03 WG1996728: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:29 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 18000 T8 300 1000 20 01/26/2023 16:16 WG1995406
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN 266 140 250 1 01/30/2023 20:37 WG1995623
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 01/26/2023 23:30 WG1995337
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 980000 58500 100000 5 01/27/2023 11:05 WG1995674
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/27/2023 09:39 WG1995699
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 110 K5 Q 10.0 10 01/31/2023 11:54 WG1995348
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 21:43 12 of 46
SAMPLE RESULTS - 03
L1579449
MW-8-W-20230124
Collected date/time: 01/24/23 10:37
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/26/2023 13:48 WG1995168
Nitrite U T8 42.0 100 1 01/26/2023 13:48 WG1995168
Sulfate 1640 J T8 594 5000 1 01/26/2023 13:48 WG1995168
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)261000 510 5000 5 01/30/2023 09:41 WG1996504
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 17200 18.0 100 1 01/27/2023 19:31 WG1995451
Manganese 21400 4.67 50.0 5 01/29/2023 22:32 WG1995451
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 85.7 2.91 10.0 1 01/27/2023 11:12 WG1995695
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 28200 125000 2500 02/02/2023 16:17 WG1998813
Acrolein U 6350 125000 2500 02/02/2023 16:17 WG1998813
Acrylonitrile U 1680 25000 2500 02/02/2023 16:17 WG1998813
Benzene 19700 235 2500 2500 02/02/2023 16:17 WG1998813
Bromobenzene U 295 2500 2500 02/02/2023 16:17 WG1998813
Bromodichloromethane U 340 2500 2500 02/02/2023 16:17 WG1998813
Bromoform U 322 2500 2500 02/02/2023 16:17 WG1998813
Bromomethane U 1510 12500 2500 02/02/2023 16:17 WG1998813
n-Butylbenzene U 393 2500 2500 02/02/2023 16:17 WG1998813
sec-Butylbenzene U 313 2500 2500 02/02/2023 16:17 WG1998813
tert-Butylbenzene U 318 2500 2500 02/02/2023 16:17 WG1998813
Carbon tetrachloride U 320 2500 2500 02/02/2023 16:17 WG1998813
Chlorobenzene U 290 2500 2500 02/02/2023 16:17 WG1998813
Chlorodibromomethane U 350 2500 2500 02/02/2023 16:17 WG1998813
Chloroethane U 480 12500 2500 02/02/2023 16:17 WG1998813
Chloroform U 278 12500 2500 02/02/2023 16:17 WG1998813
Chloromethane U 2400 6250 2500 02/02/2023 16:17 WG1998813
2-Chlorotoluene U 265 2500 2500 02/02/2023 16:17 WG1998813
4-Chlorotoluene U 285 2500 2500 02/02/2023 16:17 WG1998813
1,2-Dibromo-3-Chloropropane U 690 12500 2500 02/02/2023 16:17 WG1998813
1,2-Dibromoethane U 315 2500 2500 02/02/2023 16:17 WG1998813
Dibromomethane U 305 2500 2500 02/02/2023 16:17 WG1998813
1,2-Dichlorobenzene U 268 2500 2500 02/02/2023 16:17 WG1998813
1,3-Dichlorobenzene U 275 2500 2500 02/02/2023 16:17 WG1998813
1,4-Dichlorobenzene U 300 2500 2500 02/02/2023 16:17 WG1998813
Dichlorodifluoromethane U 935 12500 2500 02/02/2023 16:17 WG1998813
1,1-Dichloroethane U 250 2500 2500 02/02/2023 16:17 WG1998813
1,2-Dichloroethane U 205 2500 2500 02/02/2023 16:17 WG1998813
1,1-Dichloroethene U 470 2500 2500 02/02/2023 16:17 WG1998813
cis-1,2-Dichloroethene U 315 2500 2500 02/02/2023 16:17 WG1998813
trans-1,2-Dichloroethene U 373 2500 2500 02/02/2023 16:17 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 03
L1579449
MW-8-W-20230124
Collected date/time: 01/24/23 10:37
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 373 2500 2500 02/02/2023 16:17 WG1998813
1,1-Dichloropropene U 355 2500 2500 02/02/2023 16:17 WG1998813
1,3-Dichloropropane U 275 2500 2500 02/02/2023 16:17 WG1998813
2,2-Dichloropropane U 403 2500 2500 02/02/2023 16:17 WG1998813
Di-isopropyl ether U 263 2500 2500 02/02/2023 16:17 WG1998813
Ethylbenzene 1930 J 343 2500 2500 02/02/2023 16:17 WG1998813
Hexachloro-1,3-butadiene U 843 2500 2500 02/02/2023 16:17 WG1998813
Isopropylbenzene U 263 2500 2500 02/02/2023 16:17 WG1998813
p-Isopropyltoluene U 300 2500 2500 02/02/2023 16:17 WG1998813
2-Butanone (MEK)8190 J 2980 25000 2500 02/02/2023 16:17 WG1998813
Methylene Chloride U 1080 12500 2500 02/02/2023 16:17 WG1998813
4-Methyl-2-pentanone (MIBK)U 1200 25000 2500 02/02/2023 16:17 WG1998813
Methyl tert-butyl ether 75800 253 2500 2500 02/02/2023 16:17 WG1998813
Naphthalene U 2500 12500 2500 02/02/2023 16:17 WG1998813
n-Propylbenzene U 248 2500 2500 02/02/2023 16:17 WG1998813
Styrene U 295 2500 2500 02/02/2023 16:17 WG1998813
1,1,1,2-Tetrachloroethane U 368 2500 2500 02/02/2023 16:17 WG1998813
1,1,2,2-Tetrachloroethane U 333 2500 2500 02/02/2023 16:17 WG1998813
Tetrachloroethene U 750 2500 2500 02/02/2023 16:17 WG1998813
Toluene 3960 695 2500 2500 02/02/2023 16:17 WG1998813
1,2,3-Trichlorobenzene U 575 2500 2500 02/02/2023 16:17 WG1998813
1,2,4-Trichlorobenzene U 1200 2500 2500 02/02/2023 16:17 WG1998813
1,1,1-Trichloroethane U 373 2500 2500 02/02/2023 16:17 WG1998813
1,1,2-Trichloroethane U 395 2500 2500 02/02/2023 16:17 WG1998813
Trichloroethene U 475 2500 2500 02/02/2023 16:17 WG1998813
Trichlorofluoromethane U 400 12500 2500 02/02/2023 16:17 WG1998813
1,2,3-Trichloropropane U 592 6250 2500 02/02/2023 16:17 WG1998813
1,2,4-Trimethylbenzene 1130 J 805 2500 2500 02/02/2023 16:17 WG1998813
1,3,5-Trimethylbenzene 284 J 260 2500 2500 02/02/2023 16:17 WG1998813
Vinyl chloride U 585 2500 2500 02/02/2023 16:17 WG1998813
o-Xylene 2890 435 2500 2500 02/02/2023 16:17 WG1998813
m&p-Xylenes 6220 1080 5000 2500 02/02/2023 16:17 WG1998813
(S) Toluene-d8 92.1 80.0-120 02/02/2023 16:17 WG1998813
(S) 4-Bromofluorobenzene 86.9 77.0-126 02/02/2023 16:17 WG1998813
(S) 1,2-Dichloroethane-d4 107 70.0-130 02/02/2023 16:17 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1996728
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1579449-01,02,03
Method Blank (MB)
(MB) R3885690-2 01/30/23 10:48
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Alkalinity U 8450 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
Method Blank (MB)
(MB) R3885690-3 01/30/23 10:48
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Free Carbon Dioxide 8670 J 6670 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
L1578681-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1578681-01 01/30/23 11:05 • (DUP) R3885690-4 01/30/23 11:10
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity 1280000 1270000 1 1.09 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
L1578681-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1578681-01 01/30/23 11:05 • (DUP) R3885690-5 01/30/23 11:10
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide 108000 103000 1 5.40 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1996728
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1579449-01,02,03
L1579789-05 Original Sample (OS) • Duplicate (DUP)
(OS) L1579789-05 01/30/23 12:40 • (DUP) R3885690-6 01/30/23 12:45
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity 169000 168000 1 0.546 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
L1579789-05 Original Sample (OS) • Duplicate (DUP)
(OS) L1579789-05 01/30/23 12:40 • (DUP) R3885690-7 01/30/23 12:45
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide ND ND 1 1.88 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
Laboratory Control Sample (LCS)
(LCS) R3885690-1 01/30/23 10:42
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Alkalinity 100000 103000 103 90.0-110
Sample Narrative:
LCS: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG1996518
Wet Chemistry by Method 350.1 L1579449-01,02,03
Method Blank (MB)
(MB) R3885445-1 01/29/23 11:59
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ammonia Nitrogen U 117 250
L1579449-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1579449-03 01/29/23 12:29 • (DUP) R3885445-5 01/29/23 12:30
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ammonia Nitrogen U U 1 0.000 10
L1580376-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1580376-02 01/29/23 12:51 • (DUP) R3885445-7 01/29/23 12:53
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ammonia Nitrogen 4070 4110 1 0.904 10
Laboratory Control Sample (LCS)
(LCS) R3885445-2 01/29/23 12:00
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ammonia Nitrogen 7500 7240 96.6 90.0-110
L1579449-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579449-02 01/29/23 12:24 • (MS) R3885445-3 01/29/23 12:26 • (MSD) R3885445-4 01/29/23 12:27
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ammonia Nitrogen 5000 U 4910 4960 98.2 99.3 1 90.0-110 1.05 10
L1580376-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580376-01 01/29/23 12:48 • (MS) R3885445-6 01/29/23 12:50
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Ammonia Nitrogen 5000 3020 7680 93.2 1 90.0-110
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995406
Wet Chemistry by Method 3500Fe B-2011 L1579449-01,02,03
Method Blank (MB)
(MB) R3884812-1 01/26/23 16:05
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ferrous Iron U 15.0 50.0
L1577328-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1577328-01 01/26/23 16:08 • (DUP) R3884812-3 01/26/23 16:09
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ferrous Iron U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3884812-2 01/26/23 16:05
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ferrous Iron 1000 906 90.6 85.0-115
L1579449-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579449-02 01/26/23 16:09 • (MS) R3884812-4 01/26/23 16:10 • (MSD) R3884812-5 01/26/23 16:10
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ferrous Iron 1000 50.0 954 966 90.4 91.6 1 80.0-120 1.25 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995623
Wet Chemistry by Method 351.2 L1579449-01,02,03
Method Blank (MB)
(MB) R3885847-1 01/30/23 20:11
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Kjeldahl Nitrogen, TKN U 140 250
L1579208-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579208-01 01/30/23 20:21 • (DUP) R3885847-3 01/30/23 20:22
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 13400 13100 1 2.26 20
L1579208-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1579208-02 01/30/23 20:29 • (DUP) R3885847-6 01/30/23 20:30
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 12100 11200 1 7.73 20
Laboratory Control Sample (LCS)
(LCS) R3885847-2 01/30/23 20:13
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 14700 14900 101 75.2-120
L1579208-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579208-01 01/30/23 20:21 • (MS) R3885847-4 01/30/23 20:23 • (MSD) R3885847-5 01/30/23 20:27
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Kjeldahl Nitrogen, TKN 5000 13400 17300 17400 78.0 80.0 1 90.0-110 J6 J6 0.576 20
Sample Narrative:
MS: Matrix spike failure due to matrix.
MSD: Matrix spike failure due to matrix.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995623
Wet Chemistry by Method 351.2 L1579449-01,02,03
L1579208-02 Original Sample (OS) • Matrix Spike (MS)
(OS) L1579208-02 01/30/23 20:29 • (MS) R3885847-7 01/30/23 20:32
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Kjeldahl Nitrogen, TKN 5000 12100 15800 74.0 1 90.0-110 J6
Sample Narrative:
MS: Matrix spike failure due to matrix.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995337
Wet Chemistry by Method 353.2 L1579449-01,02,03
Method Blank (MB)
(MB) R3884882-1 01/26/23 23:03
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate-Nitrite U 50.0 100
L1579449-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579449-01 01/26/23 23:25 • (DUP) R3884882-6 01/26/23 23:26
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite U U 1 0.000 20
L1579377-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579377-01 01/26/23 23:42 • (DUP) R3884882-8 01/26/23 23:43
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 2620 2640 1 0.760 20
Laboratory Control Sample (LCS)
(LCS) R3884882-2 01/26/23 23:05
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate-Nitrite 2500 2630 105 90.0-110
L1579449-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1579449-01 01/26/23 23:25 • (MS) R3884882-7 01/26/23 23:28
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Nitrate-Nitrite 2500 U 2630 105 1 90.0-110
L1579377-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579377-01 01/26/23 23:42 • (MS) R3884882-9 01/26/23 23:44 • (MSD) R3884882-10 01/26/23 23:45
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate-Nitrite 2500 2620 5060 5150 97.6 101 1 90.0-110 E E 1.76 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995674
Wet Chemistry by Method 410.4 L1579449-01,02,03
Method Blank (MB)
(MB) R3885019-1 01/27/23 10:58
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
COD U 11700 20000
L1579365-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579365-01 01/27/23 10:58 • (DUP) R3885019-3 01/27/23 10:58
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
COD 67800 59000 1 13.9 20
L1579449-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579449-01 01/27/23 11:03 • (DUP) R3885019-6 01/27/23 11:04
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
COD U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3885019-2 01/27/23 10:58
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
COD 500000 511000 102 90.0-110
L1579420-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579420-01 01/27/23 11:01 • (MS) R3885019-4 01/27/23 11:01 • (MSD) R3885019-5 01/27/23 11:01
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
COD 500000 105000 594000 597000 97.9 98.4 1 80.0-120 0.474 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995699
Wet Chemistry by Method 4500S2 D-2011 L1579449-01,02,03
Method Blank (MB)
(MB) R3884980-1 01/27/23 09:36
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Sulfide U 25.0 50.0
L1579449-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579449-01 01/27/23 09:37 • (DUP) R3884980-3 01/27/23 09:39
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Sulfide U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3884980-2 01/27/23 09:37
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Sulfide 500 517 103 85.0-115
L1579550-07 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579550-07 01/27/23 09:52 • (MS) R3884980-4 01/27/23 09:53 • (MSD) R3884980-5 01/27/23 09:53
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Sulfide 500 25300 7410 7340 0.000 0.000 10 80.0-120 V V 0.922 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995348
Wet Chemistry by Method 5210 B-2016 L1579449-01,02,03
Method Blank (MB)
(MB) R3886088-1 01/31/23 12:29
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/l mg/l mg/l
BOD 0.212 B1 0.200 0.200
L1579425-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1579425-02 01/31/23 11:40 • (DUP) R3886088-3 01/31/23 11:43
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD 4.07 3.54 1 13.9 30
L1579467-07 Original Sample (OS) • Duplicate (DUP)
(OS) L1579467-07 01/31/23 12:13 • (DUP) R3886088-4 01/31/23 12:15
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD ND ND 1 0 30
Laboratory Control Sample (LCS)
(LCS) R3886088-2 01/31/23 11:38
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 178 89.7 84.6-115
Laboratory Control Sample (LCS)
(LCS) R3886088-5 01/31/23 12:20
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 185 93.4 84.6-115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995168
Wet Chemistry by Method 9056A L1579449-01,02,03
Method Blank (MB)
(MB) R3885040-1 01/26/23 10:46
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate U 48.0 100
Nitrite U 42.0 100
Sulfate U 594 5000
L1579404-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1579404-02 01/26/23 16:32 • (DUP) R3885040-5 01/26/23 16:46
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate 741 741 1 0.0405 15
Nitrite U U 1 0.000 15
Sulfate 7980 7960 1 0.250 15
L1579387-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579387-01 01/26/23 12:02 • (DUP) R3885040-2 01/26/23 14:01
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate 332 364 1 9.11 15
Nitrite U U 1 0.000 15
Sulfate 12900 12500 1 3.00 15
Laboratory Control Sample (LCS)
(LCS) R3885040-8 01/26/23 20:39
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate 8000 7500 93.7 80.0-120
Nitrite 8000 8300 104 80.0-120
Sulfate 40000 40700 102 80.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995168
Wet Chemistry by Method 9056A L1579449-01,02,03
L1579404-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579404-02 01/26/23 16:32 • (MS) R3885040-6 01/26/23 16:59 • (MSD) R3885040-7 01/26/23 17:13
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate 5000 741 6150 6080 108 107 1 80.0-120 1.09 15
Nitrite 5000 U 5950 5900 119 118 1 80.0-120 0.870 15
Sulfate 50000 7980 60100 61400 104 107 1 80.0-120 2.14 15
L1579387-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579387-01 01/26/23 12:02 • (MS) R3885040-3 01/26/23 14:15 • (MSD) R3885040-4 01/26/23 14:29
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate 5000 332 5350 5220 100 97.8 1 80.0-120 2.38 15
Nitrite 5000 U 5280 5230 106 105 1 80.0-120 1.02 15
Sulfate 50000 12900 62800 57000 99.8 88.2 1 80.0-120 9.72 15
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995911
Wet Chemistry by Method 9060A L1579449-01,02
Method Blank (MB)
(MB) R3885405-2 01/28/23 10:43
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
TOC (Total Organic Carbon)564 J 102 1000
L1579449-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1579449-02 01/28/23 15:04 • (DUP) R3885405-7 01/28/23 15:20
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)810 691 1 15.9 J 20
Laboratory Control Sample (LCS)
(LCS) R3885405-1 01/28/23 09:45
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)75000 77100 103 85.0-115
L1579404-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579404-02 01/28/23 11:20 • (MS) R3885405-3 01/28/23 11:46 • (MSD) R3885405-4 01/28/23 12:13
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
TOC (Total Organic Carbon)50000 3890 54300 53900 101 100 1 80.0-120 0.592 20
L1579404-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579404-03 01/28/23 12:31 • (MS) R3885405-5 01/28/23 12:56 • (MSD) R3885405-6 01/28/23 13:20
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
TOC (Total Organic Carbon)50000 2460 53300 51400 102 97.9 1 80.0-120 3.57 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996504
Wet Chemistry by Method 9060A L1579449-03
Method Blank (MB)
(MB) R3885885-2 01/30/23 08:14
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
TOC (Total Organic Carbon)U 102 1000
Laboratory Control Sample (LCS)
(LCS) R3885885-1 01/30/23 07:45
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
TOC 75000 70900 94.6 85.0-115
L1580194-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580194-01 01/30/23 11:31 • (MS) R3885885-3 01/30/23 11:56 • (MSD) R3885885-4 01/30/23 12:21
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
TOC 50000 3180 58700 55400 111 104 1 80.0-120 5.75 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995451
Metals (ICP) by Method 6010D L1579449-01,02,03
Method Blank (MB)
(MB) R3885456-1 01/27/23 18:57
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Iron U 18.0 100
Manganese U 0.934 10.0
Laboratory Control Sample (LCS)
(LCS) R3885456-2 01/27/23 18:59
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Iron 10000 9500 95.0 80.0-120
Manganese 1000 894 89.4 80.0-120
L1579411-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579411-01 01/27/23 19:02 • (MS) R3885456-4 01/27/23 19:07 • (MSD) R3885456-5 01/27/23 19:10
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Iron 10000 74.1 9610 9460 95.4 93.9 1 75.0-125 1.59 20
Manganese 1000 617 1510 1490 89.0 87.6 1 75.0-125 0.961 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995695
Volatile Organic Compounds (GC) by Method RSK175 L1579449-01,02,03
Method Blank (MB)
(MB) R3885073-2 01/27/23 10:44
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Methane U 2.91 10.0
L1579526-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1579526-03 01/27/23 11:44 • (DUP) R3885073-3 01/27/23 11:46
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane U U 1 0.000 20
L1579526-05 Original Sample (OS) • Duplicate (DUP)
(OS) L1579526-05 01/27/23 11:51 • (DUP) R3885073-4 01/27/23 12:03
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane U U 1 0.000 20
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3885073-1 01/27/23 10:33 • (LCSD) R3885073-7 01/27/23 12:20
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Methane 67.8 77.7 64.8 115 95.6 85.0-115 18.1 20
L1579404-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579404-02 01/27/23 10:47 • (MS) R3885073-5 01/27/23 12:11 • (MSD) R3885073-6 01/27/23 12:16
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Methane 67.8 U 72.8 81.0 107 119 1 50.0-150 10.7 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997802
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-01
Method Blank (MB)
(MB) R3886744-3 01/31/23 21:39
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
Bromomethane U 0.605 5.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997802
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-01
Method Blank (MB)
(MB) R3886744-3 01/31/23 21:39
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 91.3 80.0-120
(S) 4-Bromofluorobenzene 81.6 77.0-126
(S) 1,2-Dichloroethane-d4 107 70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3886744-1 01/31/23 20:22 • (LCSD) R3886744-2 01/31/23 20:42
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Acetone 25.0 19.3 17.7 77.2 70.8 19.0-160 8.65 27
Acrolein 25.0 16.0 14.3 64.0 57.2 10.0-160 11.2 26
Acrylonitrile 25.0 21.3 19.2 85.2 76.8 55.0-149 10.4 20
Benzene 5.00 4.94 4.35 98.8 87.0 70.0-123 12.7 20
Bromobenzene 5.00 4.73 4.37 94.6 87.4 73.0-121 7.91 20
Bromodichloromethane 5.00 5.26 4.88 105 97.6 75.0-120 7.50 20
Bromoform 5.00 4.76 4.32 95.2 86.4 68.0-132 9.69 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997802
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-01
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3886744-1 01/31/23 20:22 • (LCSD) R3886744-2 01/31/23 20:42
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Bromomethane 5.00 5.17 4.72 103 94.4 10.0-160 9.10 25
n-Butylbenzene 5.00 4.69 4.18 93.8 83.6 73.0-125 11.5 20
sec-Butylbenzene 5.00 4.68 4.23 93.6 84.6 75.0-125 10.1 20
tert-Butylbenzene 5.00 4.42 4.07 88.4 81.4 76.0-124 8.25 20
Carbon tetrachloride 5.00 4.82 4.38 96.4 87.6 68.0-126 9.57 20
Chlorobenzene 5.00 4.75 4.20 95.0 84.0 80.0-121 12.3 20
Chlorodibromomethane 5.00 4.83 4.47 96.6 89.4 77.0-125 7.74 20
Chloroethane 5.00 5.49 4.42 110 88.4 47.0-150 J3 21.6 20
Chloroform 5.00 5.63 5.00 113 100 73.0-120 11.9 20
Chloromethane 5.00 4.26 3.48 85.2 69.6 41.0-142 J3 20.2 20
2-Chlorotoluene 5.00 4.67 4.21 93.4 84.2 76.0-123 10.4 20
4-Chlorotoluene 5.00 4.50 4.09 90.0 81.8 75.0-122 9.55 20
1,2-Dibromo-3-Chloropropane 5.00 4.22 4.29 84.4 85.8 58.0-134 1.65 20
1,2-Dibromoethane 5.00 4.91 4.51 98.2 90.2 80.0-122 8.49 20
Dibromomethane 5.00 5.13 4.65 103 93.0 80.0-120 9.82 20
1,2-Dichlorobenzene 5.00 4.90 4.59 98.0 91.8 79.0-121 6.53 20
1,3-Dichlorobenzene 5.00 5.08 4.55 102 91.0 79.0-120 11.0 20
1,4-Dichlorobenzene 5.00 5.01 4.69 100 93.8 79.0-120 6.60 20
Dichlorodifluoromethane 5.00 5.50 5.13 110 103 51.0-149 6.96 20
1,1-Dichloroethane 5.00 4.78 4.18 95.6 83.6 70.0-126 13.4 20
1,2-Dichloroethane 5.00 5.38 4.78 108 95.6 70.0-128 11.8 20
1,1-Dichloroethene 5.00 5.41 4.58 108 91.6 71.0-124 16.6 20
cis-1,2-Dichloroethene 5.00 4.97 4.47 99.4 89.4 73.0-120 10.6 20
trans-1,2-Dichloroethene 5.00 5.13 4.43 103 88.6 73.0-120 14.6 20
1,2-Dichloropropane 5.00 4.65 4.12 93.0 82.4 77.0-125 12.1 20
1,1-Dichloropropene 5.00 4.95 4.38 99.0 87.6 74.0-126 12.2 20
1,3-Dichloropropane 5.00 4.82 4.46 96.4 89.2 80.0-120 7.76 20
2,2-Dichloropropane 5.00 5.34 4.96 107 99.2 58.0-130 7.38 20
Di-isopropyl ether 5.00 4.35 3.91 87.0 78.2 58.0-138 10.7 20
Ethylbenzene 5.00 4.66 4.12 93.2 82.4 79.0-123 12.3 20
Hexachloro-1,3-butadiene 5.00 5.65 5.27 113 105 54.0-138 6.96 20
Isopropylbenzene 5.00 4.45 3.93 89.0 78.6 76.0-127 12.4 20
p-Isopropyltoluene 5.00 4.63 4.09 92.6 81.8 76.0-125 12.4 20
2-Butanone (MEK)25.0 23.5 21.8 94.0 87.2 44.0-160 7.51 20
Methylene Chloride 5.00 5.58 5.15 112 103 67.0-120 8.01 20
4-Methyl-2-pentanone (MIBK)25.0 23.4 21.8 93.6 87.2 68.0-142 7.08 20
Methyl tert-butyl ether 5.00 4.90 4.71 98.0 94.2 68.0-125 3.95 20
Naphthalene 5.00 3.99 4.08 79.8 81.6 54.0-135 2.23 20
n-Propylbenzene 5.00 4.42 4.06 88.4 81.2 77.0-124 8.49 20
Styrene 5.00 4.18 3.70 83.6 74.0 73.0-130 12.2 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1997802
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-01
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3886744-1 01/31/23 20:22 • (LCSD) R3886744-2 01/31/23 20:42
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
1,1,1,2-Tetrachloroethane 5.00 4.90 4.29 98.0 85.8 75.0-125 13.3 20
1,1,2,2-Tetrachloroethane 5.00 4.73 4.72 94.6 94.4 65.0-130 0.212 20
Tetrachloroethene 5.00 5.29 4.55 106 91.0 72.0-132 15.0 20
Toluene 5.00 4.69 4.13 93.8 82.6 79.0-120 12.7 20
1,2,3-Trichlorobenzene 5.00 4.61 4.65 92.2 93.0 50.0-138 0.864 20
1,2,4-Trichlorobenzene 5.00 4.65 4.37 93.0 87.4 57.0-137 6.21 20
1,1,1-Trichloroethane 5.00 5.62 5.00 112 100 73.0-124 11.7 20
1,1,2-Trichloroethane 5.00 4.99 4.51 99.8 90.2 80.0-120 10.1 20
Trichloroethene 5.00 4.95 4.31 99.0 86.2 78.0-124 13.8 20
Trichlorofluoromethane 5.00 5.13 4.99 103 99.8 59.0-147 2.77 20
1,2,3-Trichloropropane 5.00 5.12 5.19 102 104 73.0-130 1.36 20
1,2,4-Trimethylbenzene 5.00 4.49 4.15 89.8 83.0 76.0-121 7.87 20
1,3,5-Trimethylbenzene 5.00 4.68 4.20 93.6 84.0 76.0-122 10.8 20
Vinyl chloride 5.00 4.82 4.26 96.4 85.2 67.0-131 12.3 20
o-Xylene 5.00 4.37 3.82 87.4 76.4 80.0-122 J4 13.4 20
m&p-Xylenes 10.0 9.40 8.32 94.0 83.2 80.0-122 12.2 20
(S) Toluene-d8 92.1 91.6 80.0-120
(S) 4-Bromofluorobenzene 86.7 84.4 77.0-126
(S) 1,2-Dichloroethane-d4 106 106 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-03
Method Blank (MB)
(MB) R3887201-2 02/02/23 11:05
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
Bromomethane U 0.605 5.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-03
Method Blank (MB)
(MB) R3887201-2 02/02/23 11:05
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 92.4 80.0-120
(S) 4-Bromofluorobenzene 85.8 77.0-126
(S) 1,2-Dichloroethane-d4 105 70.0-130
Laboratory Control Sample (LCS)
(LCS) R3887201-1 02/02/23 09:25
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acetone 25.0 25.4 102 19.0-160
Acrolein 25.0 16.0 64.0 10.0-160
Acrylonitrile 25.0 22.6 90.4 55.0-149
Benzene 5.00 4.97 99.4 70.0-123
Bromobenzene 5.00 4.92 98.4 73.0-121
Bromodichloromethane 5.00 5.41 108 75.0-120
Bromoform 5.00 4.81 96.2 68.0-132
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-03
Laboratory Control Sample (LCS)
(LCS) R3887201-1 02/02/23 09:25
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Bromomethane 5.00 5.62 112 10.0-160
n-Butylbenzene 5.00 4.95 99.0 73.0-125
sec-Butylbenzene 5.00 4.76 95.2 75.0-125
tert-Butylbenzene 5.00 4.51 90.2 76.0-124
Carbon tetrachloride 5.00 5.02 100 68.0-126
Chlorobenzene 5.00 4.64 92.8 80.0-121
Chlorodibromomethane 5.00 4.73 94.6 77.0-125
Chloroethane 5.00 5.63 113 47.0-150
Chloroform 5.00 5.53 111 73.0-120
Chloromethane 5.00 3.89 77.8 41.0-142
2-Chlorotoluene 5.00 4.89 97.8 76.0-123
4-Chlorotoluene 5.00 4.63 92.6 75.0-122
1,2-Dibromo-3-Chloropropane 5.00 4.30 86.0 58.0-134
1,2-Dibromoethane 5.00 4.87 97.4 80.0-122
Dibromomethane 5.00 5.16 103 80.0-120
1,2-Dichlorobenzene 5.00 5.10 102 79.0-121
1,3-Dichlorobenzene 5.00 5.17 103 79.0-120
1,4-Dichlorobenzene 5.00 5.21 104 79.0-120
Dichlorodifluoromethane 5.00 6.40 128 51.0-149
1,1-Dichloroethane 5.00 4.66 93.2 70.0-126
1,2-Dichloroethane 5.00 5.29 106 70.0-128
1,1-Dichloroethene 5.00 5.21 104 71.0-124
cis-1,2-Dichloroethene 5.00 4.78 95.6 73.0-120
trans-1,2-Dichloroethene 5.00 4.92 98.4 73.0-120
1,2-Dichloropropane 5.00 4.57 91.4 77.0-125
1,1-Dichloropropene 5.00 4.66 93.2 74.0-126
1,3-Dichloropropane 5.00 4.77 95.4 80.0-120
2,2-Dichloropropane 5.00 5.50 110 58.0-130
Di-isopropyl ether 5.00 4.21 84.2 58.0-138
Ethylbenzene 5.00 4.44 88.8 79.0-123
Hexachloro-1,3-butadiene 5.00 5.94 119 54.0-138
Isopropylbenzene 5.00 4.20 84.0 76.0-127
p-Isopropyltoluene 5.00 4.69 93.8 76.0-125
2-Butanone (MEK)25.0 25.1 100 44.0-160
Methylene Chloride 5.00 4.97 99.4 67.0-120
4-Methyl-2-pentanone (MIBK)25.0 22.9 91.6 68.0-142
Methyl tert-butyl ether 5.00 5.04 101 68.0-125
Naphthalene 5.00 4.28 85.6 54.0-135
n-Propylbenzene 5.00 4.53 90.6 77.0-124
Styrene 5.00 3.97 79.4 73.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-03
Laboratory Control Sample (LCS)
(LCS) R3887201-1 02/02/23 09:25
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
1,1,1,2-Tetrachloroethane 5.00 4.79 95.8 75.0-125
1,1,2,2-Tetrachloroethane 5.00 5.39 108 65.0-130
Tetrachloroethene 5.00 4.99 99.8 72.0-132
Toluene 5.00 4.63 92.6 79.0-120
1,2,3-Trichlorobenzene 5.00 4.87 97.4 50.0-138
1,2,4-Trichlorobenzene 5.00 4.86 97.2 57.0-137
1,1,1-Trichloroethane 5.00 5.59 112 73.0-124
1,1,2-Trichloroethane 5.00 4.82 96.4 80.0-120
Trichloroethene 5.00 4.57 91.4 78.0-124
Trichlorofluoromethane 5.00 6.02 120 59.0-147
1,2,3-Trichloropropane 5.00 5.64 113 73.0-130
1,2,4-Trimethylbenzene 5.00 4.72 94.4 76.0-121
1,3,5-Trimethylbenzene 5.00 4.66 93.2 76.0-122
Vinyl chloride 5.00 4.45 89.0 67.0-131
o-Xylene 5.00 4.21 84.2 80.0-122
m&p-Xylenes 10.0 9.15 91.5 80.0-122
(S) Toluene-d8 92.4 80.0-120
(S) 4-Bromofluorobenzene 84.4 77.0-126
(S) 1,2-Dichloroethane-d4 108 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1999697
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-02
Method Blank (MB)
(MB) R3887702-2 02/05/23 12:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
Bromomethane U 0.605 5.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1999697
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-02
Method Blank (MB)
(MB) R3887702-2 02/05/23 12:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 94.3 80.0-120
(S) 4-Bromofluorobenzene 80.7 77.0-126
(S) 1,2-Dichloroethane-d4 107 70.0-130
Laboratory Control Sample (LCS)
(LCS) R3887702-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acetone 25.0 21.2 84.8 19.0-160
Acrolein 25.0 10.3 41.2 10.0-160
Acrylonitrile 25.0 23.4 93.6 55.0-149
Benzene 5.00 4.73 94.6 70.0-123
Bromobenzene 5.00 5.23 105 73.0-121
Bromodichloromethane 5.00 5.30 106 75.0-120
Bromoform 5.00 4.49 89.8 68.0-132
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1999697
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-02
Laboratory Control Sample (LCS)
(LCS) R3887702-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Bromomethane 5.00 5.77 115 10.0-160
n-Butylbenzene 5.00 4.71 94.2 73.0-125
sec-Butylbenzene 5.00 4.99 99.8 75.0-125
tert-Butylbenzene 5.00 4.79 95.8 76.0-124
Carbon tetrachloride 5.00 5.06 101 68.0-126
Chlorobenzene 5.00 4.40 88.0 80.0-121
Chlorodibromomethane 5.00 4.59 91.8 77.0-125
Chloroethane 5.00 5.89 118 47.0-150
Chloroform 5.00 5.41 108 73.0-120
Chloromethane 5.00 5.01 100 41.0-142
2-Chlorotoluene 5.00 5.18 104 76.0-123
4-Chlorotoluene 5.00 4.85 97.0 75.0-122
1,2-Dibromo-3-Chloropropane 5.00 4.27 85.4 58.0-134
1,2-Dibromoethane 5.00 4.73 94.6 80.0-122
Dibromomethane 5.00 4.97 99.4 80.0-120
1,2-Dichlorobenzene 5.00 4.89 97.8 79.0-121
1,3-Dichlorobenzene 5.00 5.15 103 79.0-120
1,4-Dichlorobenzene 5.00 5.02 100 79.0-120
Dichlorodifluoromethane 5.00 6.52 130 51.0-149
1,1-Dichloroethane 5.00 4.54 90.8 70.0-126
1,2-Dichloroethane 5.00 5.28 106 70.0-128
1,1-Dichloroethene 5.00 4.97 99.4 71.0-124
cis-1,2-Dichloroethene 5.00 4.78 95.6 73.0-120
trans-1,2-Dichloroethene 5.00 4.97 99.4 73.0-120
1,2-Dichloropropane 5.00 4.45 89.0 77.0-125
1,1-Dichloropropene 5.00 4.77 95.4 74.0-126
1,3-Dichloropropane 5.00 4.70 94.0 80.0-120
2,2-Dichloropropane 5.00 5.77 115 58.0-130
Di-isopropyl ether 5.00 4.38 87.6 58.0-138
Ethylbenzene 5.00 4.27 85.4 79.0-123
Hexachloro-1,3-butadiene 5.00 5.48 110 54.0-138
Isopropylbenzene 5.00 4.16 83.2 76.0-127
p-Isopropyltoluene 5.00 4.81 96.2 76.0-125
2-Butanone (MEK)25.0 24.0 96.0 44.0-160
Methylene Chloride 5.00 5.13 103 67.0-120
4-Methyl-2-pentanone (MIBK)25.0 22.5 90.0 68.0-142
Methyl tert-butyl ether 5.00 5.07 101 68.0-125
Naphthalene 5.00 4.18 83.6 54.0-135
n-Propylbenzene 5.00 4.77 95.4 77.0-124
Styrene 5.00 3.98 79.6 73.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1999697
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579449-02
Laboratory Control Sample (LCS)
(LCS) R3887702-1 02/05/23 10:16
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
1,1,1,2-Tetrachloroethane 5.00 4.51 90.2 75.0-125
1,1,2,2-Tetrachloroethane 5.00 5.35 107 65.0-130
Tetrachloroethene 5.00 4.73 94.6 72.0-132
Toluene 5.00 4.40 88.0 79.0-120
1,2,3-Trichlorobenzene 5.00 4.69 93.8 50.0-138
1,2,4-Trichlorobenzene 5.00 4.70 94.0 57.0-137
1,1,1-Trichloroethane 5.00 5.51 110 73.0-124
1,1,2-Trichloroethane 5.00 4.68 93.6 80.0-120
Trichloroethene 5.00 4.58 91.6 78.0-124
Trichlorofluoromethane 5.00 5.84 117 59.0-147
1,2,3-Trichloropropane 5.00 5.66 113 73.0-130
1,2,4-Trimethylbenzene 5.00 4.75 95.0 76.0-121
1,3,5-Trimethylbenzene 5.00 4.87 97.4 76.0-122
Vinyl chloride 5.00 5.41 108 67.0-131
o-Xylene 5.00 4.01 80.2 80.0-122
m&p-Xylenes 10.0 8.65 86.5 80.0-122
(S) Toluene-d8 91.2 80.0-120
(S) 4-Bromofluorobenzene 83.8 77.0-126
(S) 1,2-Dichloroethane-d4 106 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec.Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Dilution
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Limits
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
Qualifier
This column provides a letter and/or number designation that corresponds to additional information concerning the result
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
Result
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL”
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)Confidence level of 2 sigma.
Case Narrative (Cn)
A brief discussion about the included sample results, including a discussion of any non-conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
Summary (Qc)
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
Sample Chain of
Custody (Sc)
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
Sample Results (Sr)
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
B The same analyte is found in the associated blank.
B1 The blank depletion was greater than the recommended maximum depletion of 0.2mg/L.
C4 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low.
Data is likely to show a low bias concerning the result.
E The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial calibration (ICAL).
J The identification of the analyte is acceptable; the reported value is an estimate.
J3 The associated batch QC was outside the established quality control range for precision.
J4 The associated batch QC was outside the established quality control range for accuracy.
J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.
K1 The sample dilutions set-up for the BOD/CBOD analysis did not meet the oxygen depletion criteria of at least 2 mg/L. Reported result is an estimated value.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Qualifier Description
K5 The Dilution water D.O. depletion was > 0.2 mg/L.
Q Sample was prepared and/or analyzed past holding time as defined in the method. Concentrations should be
considered minimum values.
T8 Sample(s) received past/too close to holding time expiration.
V The sample concentration is too high to evaluate accurate spike recoveries.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN000032021-1
Arizona AZ0612 New Hampshire 2975
Arkansas 88-0469 New Jersey–NELAP TN002
California 2932 New Mexico ¹TN00003
Colorado TN00003 New York 11742
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina ¹DW21704
Georgia NELAP North Carolina ³41
Georgia ¹923 North Dakota R-140
Idaho TN00003 Ohio–VAP CL0069
Illinois 200008 Oklahoma 9915
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979
Kansas E-10277 Rhode Island LAO00356
Kentucky ¹ ⁶KY90010 South Carolina 84004002
Kentucky ²16 South Dakota n/a
Louisiana AI30792 Tennessee ¹ ⁴2006
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas ⁵LAB0152
Maryland 324 Utah TN000032021-11
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033
Minnesota 047-999-395 Washington C847
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA – ISO 17025 ⁵1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA–Crypto TN00003
ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Chevron - 205513

DATA REVIEW
High point

Volatile organic compounds, Dissolved gases, Metals and General Chemistry

SDG# L1579449

Analyses Performed By:
Pace Analytical National
Mount Juliet, TN 37122

Report # 48696R
Review Level: Tier II
Project: 30064349.19.61

DATA REVIEW REPORT
arcadis.com
SUMMARY
This data quality assessment summarizes the review of Sample Delivery Groups (SDGs) # L1579449
for samples collected in association with the Chevron 205513 High Point Site. The review was conducted as a Tier II evaluation and included review of data package completeness. Only analytical data associated with constituents of concern were reviewed for this validation. Field documentation was not included in this review. Included with this assessment are the validation annotated sample result sheets and chain of custody. Analyses were performed on the following samples:
Sample ID Lab ID Matrix Sample Collection Date Parent Sample Analysis
VOC RSK175 Met. Misc.
FB-W-20230124 L1579449-01 Water 01/24/2023 X X X X
MW-1-W-20230124 L1579449-02 Water 01/24/2023 X X X X
MW-8-W-20230124 L1579449-03 Water 01/24/2023 X X X X

Notes:
VOC = volatile organic compounds.
RSK 175 = Dissolved Gases
Met = Metals
Misc. = General Chemistry

DATA REVIEW REPORT
arcadis.com

ANALYTICAL DATA PACKAGE DOCUMENTATION
The table below is the evaluation of the data package completeness.
Items Reviewed Reported Performance Acceptable Not Required No Yes No Yes
1. Sample receipt condition X X
2. Requested analyses and sample results X X
3. Master tracking list X X
4. Methods of analysis X X
5. Reporting limits X X
6. Sample collection date X X
7. Laboratory sample received date X X
8. Sample preservation verification (as applicable) X X
9. Sample preparation/extraction/analysis dates X X
10. Fully executed Chain-of-Custody (COC) form X X
11. Narrative summary of QA or sample problems provided X X
12. Data Package Completeness and Compliance X X
Note: QA - Quality Assurance
DATA REVIEW REPORT
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ORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6200B. Data were reviewed in accordance with the method specified criteria, USEPA National
Functional Guidelines NFG for Organic Superfund Methods Data Review, EPA-540-R-20-005 (November
2020), with reference to the historical (USEPA Contract Laboratory Program National Functional
Guidelines for Organic Data Review, OSWER 9240.1-05A-P, October 1999, as appropriate).
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and had already been subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with USEPA National Functional
Guidelines:
• Concentration (C) Qualifiers
U The compound was analyzed for but not detected. The associated value is the compound
quantitation limit.
B The compound has been found in the sample as well as its associated blank, its presence in
the sample may be suspect.
• Quantitation (Q) Qualifiers
E The compound was quantitated above the calibration range.
D Concentration is based on a diluted sample analysis.
• Validation Qualifiers
J The compound was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The compound was not detected above the reported sample quantitation limit. However, the
reported limit is approximate and may or may not represent the actual limit of quantitation.
JN The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification. The associated numerical value is an estimated concentration
only.
UB Compound considered non-detect at the listed value due to associated blank contamination.
N The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
DATA REVIEW REPORT
arcadis.com
that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

DATA REVIEW REPORT
arcadis.com
VOLATILE ORGANIC COMPOUND (VOC) ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
SW-846 6200B Water 14 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2 s.u.
Note:
s.u. Standard units
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds methylene chloride, toluene and trichlorofluoromethane were detected in the associated QA
blanks; however, the associated sample results were non-detect. Therefore, no other qualification of the
sample results was required.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique. VOC
analysis requires that all surrogates associated with the analysis exhibit recoveries within the laboratory-
established acceptance limits.
All surrogate recoveries were within the control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analyses
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit a percent recovery within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS/MSD recoveries must exhibit
an RPD within the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on sample locations
where the compound concentration detected in the parent sample exceeds the MS/MSD concentration by
a factor of four or greater.
MS/MSD analysis was not performed on any of the samples from this SDG.
5. Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Analysis
The LCS/LCSD analysis is used to assess the precision and accuracy of the analytical method
independent of matrix interferences. The compounds associated with the LCS/LCSD analysis must
exhibit a percent recovery within the laboratory-established acceptance limits.
DATA REVIEW REPORT
arcadis.com
Sample locations associated with LCS/LCSD analysis exhibiting recoveries outside of the control limits
presented in the following table.

Sample Locations Compound LCS Recovery LCSD Recovery
FB-W-20230124 o-Xylene AC <LL but >10%
The criteria used to evaluate the LCS/LCSD recoveries are presented in the following table. In the case
of an LCS/LCSD deviation, the sample results are qualified as documented in the table below.

Control Limit Sample Result Qualification
> the upper control limit (UL) Non-detect No Action
Detect J
< the lower control limit (LL) but > 10% Non-detect UJ
Detect J
< 10% Non-detect R
Detect J
Sample locations associated with LCS/LCSD recoveries exhibiting an RPD greater than of the control
limit presented in the following table.

Sample Locations Compound
FB-W-20230124 Chloroethane
Chloromethane
The criteria used to evaluate the RPD between the LCS/LCSD recoveries are presented in the following
table. In the case of an RPD deviation, the sample results are qualified as documented in the table
below.

Control Limit Sample Result Qualification
> UL Non-detect UJ
Detect J

6. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to 5 times the RL, a control limit of two times the RL is applied for water matrices.
Field duplicate sample was not collected from this SDG.

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7. System Performance and Overall Assessment
The case narrative noted that the CCVs for acrolein were outside the control limit with a high bias. The
associated field sample MW-1-W-20230124 was qualified as estimated (UJ) for the above listed
compound.
Other than for those deviations specifically mentioned in this review, the overall data quality is within the
guidelines specified in the method.
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DATA VALIDATION CHECKLIST FOR VOCs

VOCs: SW-846 6200B Reported Performance
Acceptable Not
Required No Yes No Yes
GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS)
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
C. Trip blanks X X
Laboratory Control Sample (LCS) X X
Laboratory Control Sample Duplicate(LCSD) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) X X
Matrix Spike Duplicate (MSD) X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Surrogate Spike Recoveries X X
Dilution Factor X X
Notes:
%R Percent recovery
RPD Relative percent difference

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DISSOLVED GASES ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
RSK-175 Water 14 days from collection to analysis Cool to < 6 °C; pH > 10 with TSP
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e. method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds were not detected above the MDL in the associated blanks; therefore, detected sample
results were not associated with blank contamination.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique.
Dissolved gases analysis requires that all surrogates associated with the analysis exhibit recoveries
within the laboratory-established acceptance limits.
All surrogate recoveries were within control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analysis
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit recoveries within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS and MSD results must be within
the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on samples where the
compound concentration detected in the parent sample exceeds the MS/MSD concentration by a factor of
four or greater.
The MS/MSD analysis was not performed on any of the samples from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The compounds associated with the LCS analysis must exhibit a percent recovery within
the laboratory-established acceptance limits.
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All compounds associated with the LCS analysis exhibited recoveries within the control limits.
6. Field Duplicate Sample Analysis
The field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 25% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to five times the RL, a control limit of two times the RL is applied to the difference
between the results for water matrices.
Field duplicate sample was not collected from this SDG.
7. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

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DATA VALIDATION CHECKLIST FOR DISSOLVED GASES

Dissolved Gases: RSK-175 Reported Performance Acceptable Not Required No Yes No Yes
Gas Chromatography/Thermal Conductivity Detector (GC/TCD)
Tier II Validation
Holding times/Temperature/Preservation X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
Laboratory Control Sample (LCS) Accuracy (%R) X X
Laboratory Control Sample Duplicate (LCSD) (%R) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike Sample (MS) (%R) X X
Matrix Spike Duplicate Sample (MSD) (%R) X X
MS/MSD Precision (RPD) X X
Laboratory Duplicate Sample (RPD) X X
Field Duplicate Sample (RPD) X X
Surrogate Spike Recoveries (%R) X X
Dilution Factor X X
Notes: %R Percent recovery RPD Relative percent difference
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INORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6010D, 2320B, 4500, 350.1, 3500Fe, 351.2, 353.2,410.4, 4500S2, 5210B, 9056A and 9060A.
Data were reviewed in accordance with USEPA National Functional Guidelines of October 2004.
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and that it was already subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with the USEPA National
Functional Guidelines:
• Concentration (C) Qualifiers
U The analyte was analyzed for but not detected. The associated value is the analyte
instrument detection limit.
J The reported value was obtained from a reading less than the reporting limit (RL), but
greater than or equal to the method detection limit (MDL).
• Quantitation (Q) Qualifiers
E The reported value is estimated due to the presence of interference.
N Spiked sample recovery is not within control limits.
* Duplicate analysis is not within control limits.
• Validation Qualifiers
J The analyte was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The analyte was not detected above the reporting limit. However, the reported limit is
approximate and may or may not represent the actual limit of detection.
UB Analyte is considered non-detect at the listed value due to associated blank contamination.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

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METALS ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
SW-846 6010D Water 180 days from collection to analysis Preserved to a pH of less
than 2.
All samples were analyzed within the specified holding times.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
Analytes were not detected above the MDL in the associated blanks; therefore, detected sample results
were not associated with blank contamination.
3. Matrix Spike / Matrix Spike Duplicate (MS/MSD) /Laboratory Duplicate Analysis
MS/MSD and laboratory duplicate data are used to assess the precision and accuracy of the analytical
method.
3.1 MS/MSD Analysis
All metal analytes must exhibit a percent recovery within the established acceptance limits of 75% to
125%. The MS recovery control limits do not apply for MS performed on sample locations where the
analyte’s concentration detected in the parent sample exceeds the MS concentration by a factor of four or
greater.
The MS/MSD analysis was not performed on any of the samples from this SDG.
3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was not performed on any of the samples from this SDG.
4. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices and 50% for soil matrices is applied to the
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RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Field duplicate sample was not collected from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
The LCS analysis exhibited recoveries within the control limits.
8. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

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DATA VALIDATION CHECKLIST FOR METAL

METALS; SW-846 6010D Reported
Performance
Acceptable Not
Required No Yes No Yes
Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES)
Tier II Validation
Holding Times X X
Reporting limits (units) X X
Blanks
A. Instrument Blanks X X
B. Method Blanks X X
C. Equipment/Field Blanks X X
Laboratory Control Sample (LCS) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate (MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Reporting Limit Verification X X
Notes:
%R = Percent recovery
RPD = Relative percent difference

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GENERAL CHEMISTRY ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
Alkalinity by SM 2320 B-11 Water 14 days from collection to
analysis Cool to <6 °C.
Free Carbon Dioxide by 4500CO2 Water 24 hours from collection to
analysis
Preserved to a pH of less
than 2.
Ammonia Nitrogen by 350.1 Water 28 days from collection to
analysis
Preserved to a pH of less
than 2.
Ferrous iron by 3500Fe Water 24 hours from collection to
analysis
Preserved to a pH of less
than 2.
Total Kjeldahl Nitrogen
by EPA 351.2 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Nitrogen, Nitrate-N + Nitrite-N
(combined result) by EPA 353.2 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Chemical Oxygen Demand (COD) by
SM5220 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
Sulfide by 4500S2 Water 15 mins from collection to
analysis
Preserved to a pH of less
than 2.
Biological Oxygen Demand (BOD) by
SM5210 B-11 Water 48 hours from collection to
analysis Cool to <6 °C.
Sulfate by SW-846 300/9056A Water 28 days from collection to
analysis Cool to <6 °C.
Total Organic Carbon by SM5310 Water 28 days from collection to
analysis
Cool to <6 °C; preserved to
a pH of less than 2.
The analyses that exceeded the holding time are presented in the following table.
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Sample Locations Analyte Holding Time Criteria
FB-W-20230124
MW-1-W-20230124
MW-8-W-20230124
Ferrous Iron Analysis completed less
than two times holding time 24 hours from collection to analysis
Free Carbon Dioxide Analysis completed greater
than two times holding time Sulfide 15 mins from collection to analysis
Sample results associated with sample locations analyzed by analytical methods mentioned above were
qualified, as specified in the table below. All other holding times were met.

Criteria
Qualification
Detected
Analytes
Non-detect
Analytes
Analysis completed less than two times holding time J UJ

2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
All analytes associated with the QA blanks exhibited a concentration less than the MDL, with the
exception of the analytes listed in the following table. Sample results associated with QA blank
contamination that were greater than the BAL resulted in the removal of the laboratory qualifier (B) of
data. Sample results less than the BAL associated with the following sample locations were qualified as
listed in the following table.

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Sample Locations Analytes Sample Result Qualification
MW-1-W-20230124
MW-8-W-20230124 Sulfate (FB, MB) Detected sample results <RL and
<BAL “UB” at the RL
MW-1-W-20230124 TOC (Total Organic Carbon)
(FB)
Detected sample results <RL and
<BAL “UB” at the RL
Note:
RL Reporting limit
3. Matrix Spike (MS)/Laboratory Duplicate Analysis
MS and laboratory duplicate data are used to assess the precision and accuracy of the analytical method.
3.1 MS Analysis
All analytes must exhibit a percent recovery within the established acceptance limits of 75% to 125%.
The MS recovery control limits do not apply for MS performed on sample locations where the analyte’s
concentration detected in the parent sample exceeds the MS concentration by a factor of four or greater.
In instance where this is true, the data will not be qualified even if the percent recovery does not meet the
control limits and the laboratory flag will be removed.
The MS/MSD analysis was performed on sample MW-1-W-20230124, exhibited acceptable recoveries.
3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was performed on sample ID MW-8-W-20230124, exhibited acceptable
RPDs.
4. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 50% for water matrices and 100% for soil matrices is applied to the
RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Field duplicate sample was not collected from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
All LCS recoveries were within control limits.
6. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.
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DATA VALIDATION CHECKLIST FOR GENERAL CHEMISTRY

General Chemistry Reported Performance
Acceptable Not
Required No Yes No Yes
Miscellaneous Instrumentation
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Field blanks X X
Laboratory Control Sample (LCS) %R X X
Laboratory Control Sample Duplicate(LCSD) %R X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate(MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Dilution Factor X X
Moisture Content X X
Notes:
%R - percent recovery
RPD - relative percent difference,
%D – difference

DATA REVIEW REPORT
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VALIDATION PERFORMED BY: Bhagyashree Fulzele
SIGNATURE:
DATE: February 21, 2023

PEER REVIEW: Dennis Capria
DATE: March 2, 2023

CHAIN OF CUSTODY
CORRECTED SAMPLE ANALYSIS DATA
SHEETS

SAMPLE RESULTS - 01
L1579449
FB-W-20230124
Collected date/time: 01/24/23 15:30
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 15.0 50.0 1 01/27/2023 19:21 WG1995451
Organic Nitrogen U 117 250 1 01/30/2023 20:34 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity U 20000 1 01/30/2023 11:57 WG1996728
Free Carbon Dioxide ND T8 20000 1 01/30/2023 11:57 WG1996728
Sample Narrative:
L1579449-01 WG1996728: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:23 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron U T8 15.0 50.0 1 01/26/2023 16:09 WG1995406
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/30/2023 20:34 WG1995623
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 01/26/2023 23:25 WG1995337
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/27/2023 11:03 WG1995674
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/27/2023 09:37 WG1995699
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 1.07 K1 K5 1.00 1 01/31/2023 11:46 WG1995348
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 01
L1579449
FB-W-20230124
Collected date/time: 01/24/23 15:30
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U 48.0 100 1 01/26/2023 12:45 WG1995168
Nitrite U 42.0 100 1 01/26/2023 12:45 WG1995168
Sulfate 1370 J 594 5000 1 01/26/2023 12:45 WG1995168
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)532 B J 102 1000 1 01/28/2023 14:07 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron U 18.0 100 1 01/27/2023 19:21 WG1995451
Manganese U 0.934 10.0 1 01/27/2023 19:21 WG1995451
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/27/2023 11:07 WG1995695
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 01/31/2023 22:44 WG1997802
Acrolein U 2.54 50.0 1 01/31/2023 22:44 WG1997802
Acrylonitrile U 0.671 10.0 1 01/31/2023 22:44 WG1997802
Benzene U 0.0941 1.00 1 01/31/2023 22:44 WG1997802
Bromobenzene U 0.118 1.00 1 01/31/2023 22:44 WG1997802
Bromodichloromethane U 0.136 1.00 1 01/31/2023 22:44 WG1997802
Bromoform U 0.129 1.00 1 01/31/2023 22:44 WG1997802
Bromomethane U 0.605 5.00 1 01/31/2023 22:44 WG1997802
n-Butylbenzene U 0.157 1.00 1 01/31/2023 22:44 WG1997802
sec-Butylbenzene U 0.125 1.00 1 01/31/2023 22:44 WG1997802
tert-Butylbenzene U 0.127 1.00 1 01/31/2023 22:44 WG1997802
Carbon tetrachloride U 0.128 1.00 1 01/31/2023 22:44 WG1997802
Chlorobenzene U 0.116 1.00 1 01/31/2023 22:44 WG1997802
Chlorodibromomethane U 0.140 1.00 1 01/31/2023 22:44 WG1997802
Chloroethane U J3 0.192 5.00 1 01/31/2023 22:44 WG1997802
Chloroform U 0.111 5.00 1 01/31/2023 22:44 WG1997802
Chloromethane U J3 0.960 2.50 1 01/31/2023 22:44 WG1997802
2-Chlorotoluene U 0.106 1.00 1 01/31/2023 22:44 WG1997802
4-Chlorotoluene U 0.114 1.00 1 01/31/2023 22:44 WG1997802
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/31/2023 22:44 WG1997802
1,2-Dibromoethane U 0.126 1.00 1 01/31/2023 22:44 WG1997802
Dibromomethane U 0.122 1.00 1 01/31/2023 22:44 WG1997802
1,2-Dichlorobenzene U 0.107 1.00 1 01/31/2023 22:44 WG1997802
1,3-Dichlorobenzene U 0.110 1.00 1 01/31/2023 22:44 WG1997802
1,4-Dichlorobenzene U 0.120 1.00 1 01/31/2023 22:44 WG1997802
Dichlorodifluoromethane U 0.374 5.00 1 01/31/2023 22:44 WG1997802
1,1-Dichloroethane U 0.100 1.00 1 01/31/2023 22:44 WG1997802
1,2-Dichloroethane U 0.0819 1.00 1 01/31/2023 22:44 WG1997802
1,1-Dichloroethene U 0.188 1.00 1 01/31/2023 22:44 WG1997802
cis-1,2-Dichloroethene U 0.126 1.00 1 01/31/2023 22:44 WG1997802
trans-1,2-Dichloroethene U 0.149 1.00 1 01/31/2023 22:44 WG1997802
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1579449
FB-W-20230124
Collected date/time: 01/24/23 15:30
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 01/31/2023 22:44 WG1997802
1,1-Dichloropropene U 0.142 1.00 1 01/31/2023 22:44 WG1997802
1,3-Dichloropropane U 0.110 1.00 1 01/31/2023 22:44 WG1997802
2,2-Dichloropropane U 0.161 1.00 1 01/31/2023 22:44 WG1997802
Di-isopropyl ether U 0.105 1.00 1 01/31/2023 22:44 WG1997802
Ethylbenzene U 0.137 1.00 1 01/31/2023 22:44 WG1997802
Hexachloro-1,3-butadiene U 0.337 1.00 1 01/31/2023 22:44 WG1997802
Isopropylbenzene U 0.105 1.00 1 01/31/2023 22:44 WG1997802
p-Isopropyltoluene U 0.120 1.00 1 01/31/2023 22:44 WG1997802
2-Butanone (MEK)U 1.19 10.0 1 01/31/2023 22:44 WG1997802
Methylene Chloride 1.59 J 0.430 5.00 1 01/31/2023 22:44 WG1997802
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 01/31/2023 22:44 WG1997802
Methyl tert-butyl ether U 0.101 1.00 1 01/31/2023 22:44 WG1997802
Naphthalene U 1.00 5.00 1 01/31/2023 22:44 WG1997802
n-Propylbenzene U 0.0993 1.00 1 01/31/2023 22:44 WG1997802
Styrene U 0.118 1.00 1 01/31/2023 22:44 WG1997802
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/31/2023 22:44 WG1997802
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/31/2023 22:44 WG1997802
Tetrachloroethene U 0.300 1.00 1 01/31/2023 22:44 WG1997802
Toluene 0.469 J 0.278 1.00 1 01/31/2023 22:44 WG1997802
1,2,3-Trichlorobenzene U 0.230 1.00 1 01/31/2023 22:44 WG1997802
1,2,4-Trichlorobenzene U 0.481 1.00 1 01/31/2023 22:44 WG1997802
1,1,1-Trichloroethane U 0.149 1.00 1 01/31/2023 22:44 WG1997802
1,1,2-Trichloroethane U 0.158 1.00 1 01/31/2023 22:44 WG1997802
Trichloroethene U 0.190 1.00 1 01/31/2023 22:44 WG1997802
Trichlorofluoromethane 0.809 J 0.160 5.00 1 01/31/2023 22:44 WG1997802
1,2,3-Trichloropropane U 0.237 2.50 1 01/31/2023 22:44 WG1997802
1,2,4-Trimethylbenzene U 0.322 1.00 1 01/31/2023 22:44 WG1997802
1,3,5-Trimethylbenzene U 0.104 1.00 1 01/31/2023 22:44 WG1997802
Vinyl chloride U 0.234 1.00 1 01/31/2023 22:44 WG1997802
o-Xylene U J4 0.174 1.00 1 01/31/2023 22:44 WG1997802
m&p-Xylenes U 0.430 2.00 1 01/31/2023 22:44 WG1997802
(S) Toluene-d8 90.3 80.0-120 01/31/2023 22:44 WG1997802
(S) 4-Bromofluorobenzene 79.7 77.0-126 01/31/2023 22:44 WG1997802
(S) 1,2-Dichloroethane-d4 107 70.0-130 01/31/2023 22:44 WG1997802
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 17:02 8 of 46
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 21:43 8 of 46
SAMPLE RESULTS - 02
L1579449
MW-1-W-20230124
Collected date/time: 01/24/23 14:12
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron 1740 15.0 50.0 1 01/27/2023 19:29 WG1995451
Organic Nitrogen U 117 250 1 01/30/2023 20:36 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 55300 20000 1 01/30/2023 12:00 WG1996728
Free Carbon Dioxide 114000 T8 20000 1 01/30/2023 12:00 WG1996728
Sample Narrative:
L1579449-02 WG1996728: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:24 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 50.0 J T8 15.0 50.0 1 01/26/2023 16:09 WG1995406
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN U 140 250 1 01/30/2023 20:36 WG1995623
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite 1520 50.0 100 1 01/26/2023 23:29 WG1995337
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD U 11700 20000 1 01/27/2023 11:05 WG1995674
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/27/2023 09:39 WG1995699
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD ND K5 1.00 1 01/31/2023 11:48 WG1995348
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 17:02 9 of 46
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 21:43 9 of 46
SAMPLE RESULTS - 02
L1579449
MW-1-W-20230124
Collected date/time: 01/24/23 14:12
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 1240 48.0 100 1 01/26/2023 12:59 WG1995168
Nitrite U 42.0 100 1 01/26/2023 12:59 WG1995168
Sulfate 3280 J 594 5000 1 01/26/2023 12:59 WG1995168
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)810 B J 102 1000 1 01/28/2023 15:04 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 1790 18.0 100 1 01/27/2023 19:29 WG1995451
Manganese 47.4 0.934 10.0 1 01/27/2023 19:29 WG1995451
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane U 2.91 10.0 1 01/27/2023 11:09 WG1995695
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/05/2023 16:27 WG1999697
Acrolein U C4 2.54 50.0 1 02/05/2023 16:27 WG1999697
Acrylonitrile U 0.671 10.0 1 02/05/2023 16:27 WG1999697
Benzene 15.7 0.0941 1.00 1 02/05/2023 16:27 WG1999697
Bromobenzene U 0.118 1.00 1 02/05/2023 16:27 WG1999697
Bromodichloromethane U 0.136 1.00 1 02/05/2023 16:27 WG1999697
Bromoform U 0.129 1.00 1 02/05/2023 16:27 WG1999697
Bromomethane U 0.605 5.00 1 02/05/2023 16:27 WG1999697
n-Butylbenzene U 0.157 1.00 1 02/05/2023 16:27 WG1999697
sec-Butylbenzene U 0.125 1.00 1 02/05/2023 16:27 WG1999697
tert-Butylbenzene U 0.127 1.00 1 02/05/2023 16:27 WG1999697
Carbon tetrachloride U 0.128 1.00 1 02/05/2023 16:27 WG1999697
Chlorobenzene U 0.116 1.00 1 02/05/2023 16:27 WG1999697
Chlorodibromomethane U 0.140 1.00 1 02/05/2023 16:27 WG1999697
Chloroethane U 0.192 5.00 1 02/05/2023 16:27 WG1999697
Chloroform U 0.111 5.00 1 02/05/2023 16:27 WG1999697
Chloromethane U 0.960 2.50 1 02/05/2023 16:27 WG1999697
2-Chlorotoluene U 0.106 1.00 1 02/05/2023 16:27 WG1999697
4-Chlorotoluene U 0.114 1.00 1 02/05/2023 16:27 WG1999697
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/05/2023 16:27 WG1999697
1,2-Dibromoethane 0.130 J 0.126 1.00 1 02/05/2023 16:27 WG1999697
Dibromomethane U 0.122 1.00 1 02/05/2023 16:27 WG1999697
1,2-Dichlorobenzene U 0.107 1.00 1 02/05/2023 16:27 WG1999697
1,3-Dichlorobenzene U 0.110 1.00 1 02/05/2023 16:27 WG1999697
1,4-Dichlorobenzene U 0.120 1.00 1 02/05/2023 16:27 WG1999697
Dichlorodifluoromethane U 0.374 5.00 1 02/05/2023 16:27 WG1999697
1,1-Dichloroethane U 0.100 1.00 1 02/05/2023 16:27 WG1999697
1,2-Dichloroethane U 0.0819 1.00 1 02/05/2023 16:27 WG1999697
1,1-Dichloroethene U 0.188 1.00 1 02/05/2023 16:27 WG1999697
cis-1,2-Dichloroethene U 0.126 1.00 1 02/05/2023 16:27 WG1999697
trans-1,2-Dichloroethene U 0.149 1.00 1 02/05/2023 16:27 WG1999697
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 21:43 10 of 46
SAMPLE RESULTS - 02
L1579449
MW-1-W-20230124
Collected date/time: 01/24/23 14:12
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 0.149 1.00 1 02/05/2023 16:27 WG1999697
1,1-Dichloropropene U 0.142 1.00 1 02/05/2023 16:27 WG1999697
1,3-Dichloropropane U 0.110 1.00 1 02/05/2023 16:27 WG1999697
2,2-Dichloropropane U 0.161 1.00 1 02/05/2023 16:27 WG1999697
Di-isopropyl ether U 0.105 1.00 1 02/05/2023 16:27 WG1999697
Ethylbenzene 3.26 0.137 1.00 1 02/05/2023 16:27 WG1999697
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/05/2023 16:27 WG1999697
Isopropylbenzene 0.114 J 0.105 1.00 1 02/05/2023 16:27 WG1999697
p-Isopropyltoluene U 0.120 1.00 1 02/05/2023 16:27 WG1999697
2-Butanone (MEK)U 1.19 10.0 1 02/05/2023 16:27 WG1999697
Methylene Chloride U 0.430 5.00 1 02/05/2023 16:27 WG1999697
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/05/2023 16:27 WG1999697
Methyl tert-butyl ether 2.49 0.101 1.00 1 02/05/2023 16:27 WG1999697
Naphthalene U 1.00 5.00 1 02/05/2023 16:27 WG1999697
n-Propylbenzene 0.236 J 0.0993 1.00 1 02/05/2023 16:27 WG1999697
Styrene U 0.118 1.00 1 02/05/2023 16:27 WG1999697
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/05/2023 16:27 WG1999697
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/05/2023 16:27 WG1999697
Tetrachloroethene U 0.300 1.00 1 02/05/2023 16:27 WG1999697
Toluene 8.04 0.278 1.00 1 02/05/2023 16:27 WG1999697
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/05/2023 16:27 WG1999697
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/05/2023 16:27 WG1999697
1,1,1-Trichloroethane U 0.149 1.00 1 02/05/2023 16:27 WG1999697
1,1,2-Trichloroethane U 0.158 1.00 1 02/05/2023 16:27 WG1999697
Trichloroethene U 0.190 1.00 1 02/05/2023 16:27 WG1999697
Trichlorofluoromethane U 0.160 5.00 1 02/05/2023 16:27 WG1999697
1,2,3-Trichloropropane U 0.237 2.50 1 02/05/2023 16:27 WG1999697
1,2,4-Trimethylbenzene 1.59 0.322 1.00 1 02/05/2023 16:27 WG1999697
1,3,5-Trimethylbenzene 0.407 J 0.104 1.00 1 02/05/2023 16:27 WG1999697
Vinyl chloride U 0.234 1.00 1 02/05/2023 16:27 WG1999697
o-Xylene 5.44 0.174 1.00 1 02/05/2023 16:27 WG1999697
m&p-Xylenes 11.0 0.430 2.00 1 02/05/2023 16:27 WG1999697
(S) Toluene-d8 92.3 80.0-120 02/05/2023 16:27 WG1999697
(S) 4-Bromofluorobenzene 85.6 77.0-126 02/05/2023 16:27 WG1999697
(S) 1,2-Dichloroethane-d4 110 70.0-130 02/05/2023 16:27 WG1999697
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 17:02 11 of 46
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 21:43 11 of 46
SAMPLE RESULTS - 03
L1579449
MW-8-W-20230124
Collected date/time: 01/24/23 10:37
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/27/2023 19:31 WG1995451
Organic Nitrogen 266 117 250 1 01/30/2023 20:37 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 233000 20000 1 01/30/2023 12:03 WG1996728
Free Carbon Dioxide 112000 T8 20000 1 01/30/2023 12:03 WG1996728
Sample Narrative:
L1579449-03 WG1996728: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:29 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 18000 T8 300 1000 20 01/26/2023 16:16 WG1995406
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN 266 140 250 1 01/30/2023 20:37 WG1995623
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 50.0 100 1 01/26/2023 23:30 WG1995337
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 980000 58500 100000 5 01/27/2023 11:05 WG1995674
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/27/2023 09:39 WG1995699
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 110 K5 Q 10.0 10 01/31/2023 11:54 WG1995348
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 21:43 12 of 46
SAMPLE RESULTS - 03
L1579449
MW-8-W-20230124
Collected date/time: 01/24/23 10:37
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/26/2023 13:48 WG1995168
Nitrite U T8 42.0 100 1 01/26/2023 13:48 WG1995168
Sulfate 1640 J T8 594 5000 1 01/26/2023 13:48 WG1995168
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)261000 510 5000 5 01/30/2023 09:41 WG1996504
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 17200 18.0 100 1 01/27/2023 19:31 WG1995451
Manganese 21400 4.67 50.0 5 01/29/2023 22:32 WG1995451
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 85.7 2.91 10.0 1 01/27/2023 11:12 WG1995695
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 28200 125000 2500 02/02/2023 16:17 WG1998813
Acrolein U 6350 125000 2500 02/02/2023 16:17 WG1998813
Acrylonitrile U 1680 25000 2500 02/02/2023 16:17 WG1998813
Benzene 19700 235 2500 2500 02/02/2023 16:17 WG1998813
Bromobenzene U 295 2500 2500 02/02/2023 16:17 WG1998813
Bromodichloromethane U 340 2500 2500 02/02/2023 16:17 WG1998813
Bromoform U 322 2500 2500 02/02/2023 16:17 WG1998813
Bromomethane U 1510 12500 2500 02/02/2023 16:17 WG1998813
n-Butylbenzene U 393 2500 2500 02/02/2023 16:17 WG1998813
sec-Butylbenzene U 313 2500 2500 02/02/2023 16:17 WG1998813
tert-Butylbenzene U 318 2500 2500 02/02/2023 16:17 WG1998813
Carbon tetrachloride U 320 2500 2500 02/02/2023 16:17 WG1998813
Chlorobenzene U 290 2500 2500 02/02/2023 16:17 WG1998813
Chlorodibromomethane U 350 2500 2500 02/02/2023 16:17 WG1998813
Chloroethane U 480 12500 2500 02/02/2023 16:17 WG1998813
Chloroform U 278 12500 2500 02/02/2023 16:17 WG1998813
Chloromethane U 2400 6250 2500 02/02/2023 16:17 WG1998813
2-Chlorotoluene U 265 2500 2500 02/02/2023 16:17 WG1998813
4-Chlorotoluene U 285 2500 2500 02/02/2023 16:17 WG1998813
1,2-Dibromo-3-Chloropropane U 690 12500 2500 02/02/2023 16:17 WG1998813
1,2-Dibromoethane U 315 2500 2500 02/02/2023 16:17 WG1998813
Dibromomethane U 305 2500 2500 02/02/2023 16:17 WG1998813
1,2-Dichlorobenzene U 268 2500 2500 02/02/2023 16:17 WG1998813
1,3-Dichlorobenzene U 275 2500 2500 02/02/2023 16:17 WG1998813
1,4-Dichlorobenzene U 300 2500 2500 02/02/2023 16:17 WG1998813
Dichlorodifluoromethane U 935 12500 2500 02/02/2023 16:17 WG1998813
1,1-Dichloroethane U 250 2500 2500 02/02/2023 16:17 WG1998813
1,2-Dichloroethane U 205 2500 2500 02/02/2023 16:17 WG1998813
1,1-Dichloroethene U 470 2500 2500 02/02/2023 16:17 WG1998813
cis-1,2-Dichloroethene U 315 2500 2500 02/02/2023 16:17 WG1998813
trans-1,2-Dichloroethene U 373 2500 2500 02/02/2023 16:17 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579449 02/06/23 21:43 13 of 46
SAMPLE RESULTS - 03
L1579449
MW-8-W-20230124
Collected date/time: 01/24/23 10:37
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 373 2500 2500 02/02/2023 16:17 WG1998813
1,1-Dichloropropene U 355 2500 2500 02/02/2023 16:17 WG1998813
1,3-Dichloropropane U 275 2500 2500 02/02/2023 16:17 WG1998813
2,2-Dichloropropane U 403 2500 2500 02/02/2023 16:17 WG1998813
Di-isopropyl ether U 263 2500 2500 02/02/2023 16:17 WG1998813
Ethylbenzene 1930 J 343 2500 2500 02/02/2023 16:17 WG1998813
Hexachloro-1,3-butadiene U 843 2500 2500 02/02/2023 16:17 WG1998813
Isopropylbenzene U 263 2500 2500 02/02/2023 16:17 WG1998813
p-Isopropyltoluene U 300 2500 2500 02/02/2023 16:17 WG1998813
2-Butanone (MEK)8190 J 2980 25000 2500 02/02/2023 16:17 WG1998813
Methylene Chloride U 1080 12500 2500 02/02/2023 16:17 WG1998813
4-Methyl-2-pentanone (MIBK)U 1200 25000 2500 02/02/2023 16:17 WG1998813
Methyl tert-butyl ether 75800 253 2500 2500 02/02/2023 16:17 WG1998813
Naphthalene U 2500 12500 2500 02/02/2023 16:17 WG1998813
n-Propylbenzene U 248 2500 2500 02/02/2023 16:17 WG1998813
Styrene U 295 2500 2500 02/02/2023 16:17 WG1998813
1,1,1,2-Tetrachloroethane U 368 2500 2500 02/02/2023 16:17 WG1998813
1,1,2,2-Tetrachloroethane U 333 2500 2500 02/02/2023 16:17 WG1998813
Tetrachloroethene U 750 2500 2500 02/02/2023 16:17 WG1998813
Toluene 3960 695 2500 2500 02/02/2023 16:17 WG1998813
1,2,3-Trichlorobenzene U 575 2500 2500 02/02/2023 16:17 WG1998813
1,2,4-Trichlorobenzene U 1200 2500 2500 02/02/2023 16:17 WG1998813
1,1,1-Trichloroethane U 373 2500 2500 02/02/2023 16:17 WG1998813
1,1,2-Trichloroethane U 395 2500 2500 02/02/2023 16:17 WG1998813
Trichloroethene U 475 2500 2500 02/02/2023 16:17 WG1998813
Trichlorofluoromethane U 400 12500 2500 02/02/2023 16:17 WG1998813
1,2,3-Trichloropropane U 592 6250 2500 02/02/2023 16:17 WG1998813
1,2,4-Trimethylbenzene 1130 J 805 2500 2500 02/02/2023 16:17 WG1998813
1,3,5-Trimethylbenzene 284 J 260 2500 2500 02/02/2023 16:17 WG1998813
Vinyl chloride U 585 2500 2500 02/02/2023 16:17 WG1998813
o-Xylene 2890 435 2500 2500 02/02/2023 16:17 WG1998813
m&p-Xylenes 6220 1080 5000 2500 02/02/2023 16:17 WG1998813
(S) Toluene-d8 92.1 80.0-120 02/02/2023 16:17 WG1998813
(S) 4-Bromofluorobenzene 86.9 77.0-126 02/02/2023 16:17 WG1998813
(S) 1,2-Dichloroethane-d4 107 70.0-130 02/02/2023 16:17 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ANALYTICAL REPORT
February 06, 2023
Arcadis - Chevron - NC
Sample Delivery Group:L1579828
Samples Received:01/27/2023
Project Number:30064349
Description:Pod 2 - High Point, NC #205513
Site:205513
Report To:Andrew DrMarco
801 Corporate Center Drive
Suite 300
Raleigh, NC 27607
Entire Report Reviewed By:
February 06, 2023
[Preliminary Report]
Chris McCord
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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February 06, 2023
Chris McCord
Project Manager
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TABLE OF CONTENTS
Cp: Cover Page 1
Tc: Table of Contents 2
Ss: Sample Summary 3
Cn: Case Narrative 4
Sr: Sample Results 5
MW-2-W-20230125 L1579828-01 5
DUP-01-W-20230125 L1579828-02 8
Qc: Quality Control Summary 11
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 11
Wet Chemistry by Method 350.1 13
Wet Chemistry by Method 3500Fe B-2011 14
Wet Chemistry by Method 351.2 15
Wet Chemistry by Method 353.2 17
Wet Chemistry by Method 410.4 18
Wet Chemistry by Method 4500S2 D-2011 19
Wet Chemistry by Method 5210 B-2016 20
Wet Chemistry by Method 9056A 21
Wet Chemistry by Method 9060A 23
Metals (ICP) by Method 6010D 24
Volatile Organic Compounds (GC) by Method RSK175 25
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 26
Gl: Glossary of Terms 30
Al: Accreditations & Locations 31
Sc: Sample Chain of Custody 32
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW-2-W-20230125 L1579828-01 GW Ariel Guggino-Boyd 01/25/23 09:52 01/27/23 08:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996029 1 01/30/23 10:55 01/30/23 10:55 ABL Mt. Juliet, TN
Calculated Results WG1996518 1 01/30/23 22:44 01/30/23 22:44 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1998655 1 02/06/23 08:22 02/06/23 08:22 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1998655 1 02/06/23 08:22 02/06/23 08:22 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1996518 1 01/29/23 12:33 01/29/23 12:33 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1995970 10 01/27/23 14:54 01/27/23 14:54 JAR Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1996244 1 01/30/23 16:13 01/30/23 22:44 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG200069
7 5 02/06/23 12:54 02/06/23 12:54 CAT Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1996209 1 01/27/23 19:00 01/27/23 21:27 TQP Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1996774 1 01/30/23 09:59 01/30/23 09:59 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1995769 1 01/27/23 12:56 02/01/23 09:13 ABA Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1995863 1 01/27/23 13:10 01/27/23 13:10 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1995911 1 01/28/23 20:55 01/28/23 20:55 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996029 1 01/28/23 09:46 01/30/23 10:55 ABL Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996029 5 01/28/23 09:46 01/30/23 13:49 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1995909 1 01/27/23 15:47 01/27/23 15:47 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1998813 200 02/02/23 16:37 02/02/23 16:37 DWR Mt. Juliet, TN
Collected by Collected date/time Received date/time
DUP-01-W-20230125 L1579828-02 GW Ariel Guggino-Boyd 01/25/23 00:00 01/27/23 08:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Calculated Results WG1996029 1 01/30/23 10:58 01/30/23 10:58 ABL Mt. Juliet, TN
Calculated Results WG1996518 1 01/30/23 22:46 01/30/23 22:46 LDT Mt. Juliet, TN
Wet Chemistry by Method 2320 B-2011 WG1998655 1 02/06/23 08:27 02/06/23 08:27 ARD Mt. Juliet, TN
Wet Chemistry by Method 4500CO2 D-2011 WG1998655 1 02/06/23 08:27 02/06/23 08:27 ARD Mt. Juliet, TN
Wet Chemistry by Method 350.1 WG1996518 1 01/29/23 12:35 01/29/23 12:35 BMD Mt. Juliet, TN
Wet Chemistry by Method 3500Fe B-2011 WG1995970 10 01/27/23 14:55 01/27/23 14:55 JAR Mt. Juliet, TN
Wet Chemistry by Method 351.2 WG1996244 1 01/30/23 16:13 01/30/23 22:46 LDT Mt. Juliet, TN
Wet Chemistry by Method 353.2 WG200069
7 5 02/06/23 12:56 02/06/23 12:56 CAT Mt. Juliet, TN
Wet Chemistry by Method 410.4 WG1996209 1 01/27/23 19:00 01/27/23 21:27 TQP Mt. Juliet, TN
Wet Chemistry by Method 4500S2 D-2011 WG1996774 1 01/30/23 10:02 01/30/23 10:02 CAH Mt. Juliet, TN
Wet Chemistry by Method 5210 B-2016 WG1995769 1 01/27/23 13:05 02/01/23 09:20 EAO Mt. Juliet, TN
Wet Chemistry by Method 9056A WG1995863 1 01/27/23 14:46 01/27/23 14:46 LBR Mt. Juliet, TN
Wet Chemistry by Method 9060A WG1995911 1 01/28/23 21:14 01/28/23 21:14 LOH Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996029 1 01/28/23 09:46 01/30/23 10:58 ABL Mt. Juliet, TN
Metals (ICP) by Method 6010D WG1996029 5 01/28/23 09:46 01/30/23 13:51 ABL Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method RSK175 WG1995909 1 01/27/23 15:52 01/27/23 15:52 BAW Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 WG1998813 100 02/02/23 16:57 02/02/23 16:57 DWR Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
[Preliminary Report]
Chris McCord
Project Manager
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Chris McCord
Project Manager
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SAMPLE RESULTS - 01
L1579828
MW-2-W-20230125
Collected date/time: 01/25/23 09:52
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/30/2023 10:55 WG1996029
Organic Nitrogen 208 J 117 250 1 01/30/2023 22:44 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 306000 20000 1 02/06/2023 08:22 WG1998655
Free Carbon Dioxide 41800 B T8 20000 1 02/06/2023 08:22 WG1998655
Sample Narrative:
L1579828-01 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:33 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 11100 T8 150 500 10 01/27/2023 14:54 WG1995970
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN 208 J 140 250 1 01/30/2023 22:44 WG1996244
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 250 500 5 02/06/2023 12:54 WG2000697
Sample Narrative:
L1579828-01 WG2000697: Dilution due to matrix.
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 255000 11700 20000 1 01/27/2023 21:27 WG1996209
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/30/2023 09:59 WG1996774
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 6.91 K5 K6 Q 1.00 1 02/01/2023 09:13 WG1995769
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1579828
MW-2-W-20230125
Collected date/time: 01/25/23 09:52
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/27/2023 13:10 WG1995863
Nitrite U T8 42.0 100 1 01/27/2023 13:10 WG1995863
Sulfate U T8 594 5000 1 01/27/2023 13:10 WG1995863
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)49900 102 1000 1 01/28/2023 20:55 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 11000 18.0 100 1 01/30/2023 10:55 WG1996029
Manganese 12400 4.67 50.0 5 01/30/2023 13:49 WG1996029
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 199 2.91 10.0 1 01/27/2023 15:47 WG1995909
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 2260 10000 200 02/02/2023 16:37 WG1998813
Acrolein U 508 10000 200 02/02/2023 16:37 WG1998813
Acrylonitrile U 134 2000 200 02/02/2023 16:37 WG1998813
Benzene 12000 18.8 200 200 02/02/2023 16:37 WG1998813
Bromobenzene U 23.6 200 200 02/02/2023 16:37 WG1998813
Bromodichloromethane U 27.2 200 200 02/02/2023 16:37 WG1998813
Bromoform U 25.8 200 200 02/02/2023 16:37 WG1998813
Bromomethane U 121 1000 200 02/02/2023 16:37 WG1998813
n-Butylbenzene U 31.4 200 200 02/02/2023 16:37 WG1998813
sec-Butylbenzene U 25.0 200 200 02/02/2023 16:37 WG1998813
tert-Butylbenzene U 25.4 200 200 02/02/2023 16:37 WG1998813
Carbon tetrachloride U 25.6 200 200 02/02/2023 16:37 WG1998813
Chlorobenzene U 23.2 200 200 02/02/2023 16:37 WG1998813
Chlorodibromomethane U 28.0 200 200 02/02/2023 16:37 WG1998813
Chloroethane U 38.4 1000 200 02/02/2023 16:37 WG1998813
Chloroform U 22.2 1000 200 02/02/2023 16:37 WG1998813
Chloromethane U 192 500 200 02/02/2023 16:37 WG1998813
2-Chlorotoluene U 21.2 200 200 02/02/2023 16:37 WG1998813
4-Chlorotoluene U 22.8 200 200 02/02/2023 16:37 WG1998813
1,2-Dibromo-3-Chloropropane U 55.2 1000 200 02/02/2023 16:37 WG1998813
1,2-Dibromoethane U 25.2 200 200 02/02/2023 16:37 WG1998813
Dibromomethane U 24.4 200 200 02/02/2023 16:37 WG1998813
1,2-Dichlorobenzene U 21.4 200 200 02/02/2023 16:37 WG1998813
1,3-Dichlorobenzene U 22.0 200 200 02/02/2023 16:37 WG1998813
1,4-Dichlorobenzene U 24.0 200 200 02/02/2023 16:37 WG1998813
Dichlorodifluoromethane U 74.8 1000 200 02/02/2023 16:37 WG1998813
1,1-Dichloroethane U 20.0 200 200 02/02/2023 16:37 WG1998813
1,2-Dichloroethane U 16.4 200 200 02/02/2023 16:37 WG1998813
1,1-Dichloroethene U 37.6 200 200 02/02/2023 16:37 WG1998813
cis-1,2-Dichloroethene U 25.2 200 200 02/02/2023 16:37 WG1998813
trans-1,2-Dichloroethene U 29.8 200 200 02/02/2023 16:37 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1579828
MW-2-W-20230125
Collected date/time: 01/25/23 09:52
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 29.8 200 200 02/02/2023 16:37 WG1998813
1,1-Dichloropropene U 28.4 200 200 02/02/2023 16:37 WG1998813
1,3-Dichloropropane U 22.0 200 200 02/02/2023 16:37 WG1998813
2,2-Dichloropropane U 32.2 200 200 02/02/2023 16:37 WG1998813
Di-isopropyl ether 44.8 J 21.0 200 200 02/02/2023 16:37 WG1998813
Ethylbenzene 2650 27.4 200 200 02/02/2023 16:37 WG1998813
Hexachloro-1,3-butadiene U 67.4 200 200 02/02/2023 16:37 WG1998813
Isopropylbenzene 84.1 J 21.0 200 200 02/02/2023 16:37 WG1998813
p-Isopropyltoluene U 24.0 200 200 02/02/2023 16:37 WG1998813
2-Butanone (MEK)U 238 2000 200 02/02/2023 16:37 WG1998813
Methylene Chloride U 86.0 1000 200 02/02/2023 16:37 WG1998813
4-Methyl-2-pentanone (MIBK)U 95.6 2000 200 02/02/2023 16:37 WG1998813
Methyl tert-butyl ether 5800 20.2 200 200 02/02/2023 16:37 WG1998813
Naphthalene 499 J 200 1000 200 02/02/2023 16:37 WG1998813
n-Propylbenzene 219 19.9 200 200 02/02/2023 16:37 WG1998813
Styrene 55.2 J 23.6 200 200 02/02/2023 16:37 WG1998813
1,1,1,2-Tetrachloroethane U 29.4 200 200 02/02/2023 16:37 WG1998813
1,1,2,2-Tetrachloroethane U 26.6 200 200 02/02/2023 16:37 WG1998813
Tetrachloroethene U 60.0 200 200 02/02/2023 16:37 WG1998813
Toluene 291 55.6 200 200 02/02/2023 16:37 WG1998813
1,2,3-Trichlorobenzene U 46.0 200 200 02/02/2023 16:37 WG1998813
1,2,4-Trichlorobenzene U 96.2 200 200 02/02/2023 16:37 WG1998813
1,1,1-Trichloroethane U 29.8 200 200 02/02/2023 16:37 WG1998813
1,1,2-Trichloroethane U 31.6 200 200 02/02/2023 16:37 WG1998813
Trichloroethene U 38.0 200 200 02/02/2023 16:37 WG1998813
Trichlorofluoromethane U 32.0 1000 200 02/02/2023 16:37 WG1998813
1,2,3-Trichloropropane U 47.4 500 200 02/02/2023 16:37 WG1998813
1,2,4-Trimethylbenzene 927 64.4 200 200 02/02/2023 16:37 WG1998813
1,3,5-Trimethylbenzene 230 20.8 200 200 02/02/2023 16:37 WG1998813
Vinyl chloride U 46.8 200 200 02/02/2023 16:37 WG1998813
o-Xylene 106 J 34.8 200 200 02/02/2023 16:37 WG1998813
m&p-Xylenes 1790 86.0 400 200 02/02/2023 16:37 WG1998813
(S) Toluene-d8 94.2 80.0-120 02/02/2023 16:37 WG1998813
(S) 4-Bromofluorobenzene 85.7 77.0-126 02/02/2023 16:37 WG1998813
(S) 1,2-Dichloroethane-d4 107 70.0-130 02/02/2023 16:37 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 02
L1579828
DUP-01-W-20230125
Collected date/time: 01/25/23 00:00
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/30/2023 10:58 WG1996029
Organic Nitrogen 204 J 117 250 1 01/30/2023 22:46 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 309000 20000 1 02/06/2023 08:27 WG1998655
Free Carbon Dioxide 78900 B T8 20000 1 02/06/2023 08:27 WG1998655
Sample Narrative:
L1579828-02 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:35 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 11700 T8 150 500 10 01/27/2023 14:55 WG1995970
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN 204 J 140 250 1 01/30/2023 22:46 WG1996244
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 250 500 5 02/06/2023 12:56 WG2000697
Sample Narrative:
L1579828-02 WG2000697: Dilution due to matrix.
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 259000 11700 20000 1 01/27/2023 21:27 WG1996209
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/30/2023 10:02 WG1996774
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 12.1 K5 K6 K9 T8 1.00 1 02/01/2023 09:20 WG1995769
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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SAMPLE RESULTS - 02
L1579828
DUP-01-W-20230125
Collected date/time: 01/25/23 00:00
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 271 T8 48.0 100 1 01/27/2023 14:46 WG1995863
Nitrite U T8 42.0 100 1 01/27/2023 14:46 WG1995863
Sulfate U T8 594 5000 1 01/27/2023 14:46 WG1995863
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)50500 102 1000 1 01/28/2023 21:14 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 11200 18.0 100 1 01/30/2023 10:58 WG1996029
Manganese 12800 4.67 50.0 5 01/30/2023 13:51 WG1996029
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 184 2.91 10.0 1 01/27/2023 15:52 WG1995909
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 1130 5000 100 02/02/2023 16:57 WG1998813
Acrolein U 254 5000 100 02/02/2023 16:57 WG1998813
Acrylonitrile U 67.1 1000 100 02/02/2023 16:57 WG1998813
Benzene 11600 9.41 100 100 02/02/2023 16:57 WG1998813
Bromobenzene U 11.8 100 100 02/02/2023 16:57 WG1998813
Bromodichloromethane U 13.6 100 100 02/02/2023 16:57 WG1998813
Bromoform U 12.9 100 100 02/02/2023 16:57 WG1998813
Bromomethane U 60.5 500 100 02/02/2023 16:57 WG1998813
n-Butylbenzene 15.8 J 15.7 100 100 02/02/2023 16:57 WG1998813
sec-Butylbenzene U 12.5 100 100 02/02/2023 16:57 WG1998813
tert-Butylbenzene U 12.7 100 100 02/02/2023 16:57 WG1998813
Carbon tetrachloride U 12.8 100 100 02/02/2023 16:57 WG1998813
Chlorobenzene U 11.6 100 100 02/02/2023 16:57 WG1998813
Chlorodibromomethane U 14.0 100 100 02/02/2023 16:57 WG1998813
Chloroethane U 19.2 500 100 02/02/2023 16:57 WG1998813
Chloroform U 11.1 500 100 02/02/2023 16:57 WG1998813
Chloromethane U 96.0 250 100 02/02/2023 16:57 WG1998813
2-Chlorotoluene U 10.6 100 100 02/02/2023 16:57 WG1998813
4-Chlorotoluene U 11.4 100 100 02/02/2023 16:57 WG1998813
1,2-Dibromo-3-Chloropropane U 27.6 500 100 02/02/2023 16:57 WG1998813
1,2-Dibromoethane U 12.6 100 100 02/02/2023 16:57 WG1998813
Dibromomethane U 12.2 100 100 02/02/2023 16:57 WG1998813
1,2-Dichlorobenzene U 10.7 100 100 02/02/2023 16:57 WG1998813
1,3-Dichlorobenzene U 11.0 100 100 02/02/2023 16:57 WG1998813
1,4-Dichlorobenzene U 12.0 100 100 02/02/2023 16:57 WG1998813
Dichlorodifluoromethane U 37.4 500 100 02/02/2023 16:57 WG1998813
1,1-Dichloroethane U 10.0 100 100 02/02/2023 16:57 WG1998813
1,2-Dichloroethane U 8.19 100 100 02/02/2023 16:57 WG1998813
1,1-Dichloroethene U 18.8 100 100 02/02/2023 16:57 WG1998813
cis-1,2-Dichloroethene U 12.6 100 100 02/02/2023 16:57 WG1998813
trans-1,2-Dichloroethene U 14.9 100 100 02/02/2023 16:57 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 02
L1579828
DUP-01-W-20230125
Collected date/time: 01/25/23 00:00
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 14.9 100 100 02/02/2023 16:57 WG1998813
1,1-Dichloropropene U 14.2 100 100 02/02/2023 16:57 WG1998813
1,3-Dichloropropane U 11.0 100 100 02/02/2023 16:57 WG1998813
2,2-Dichloropropane U 16.1 100 100 02/02/2023 16:57 WG1998813
Di-isopropyl ether 42.1 J 10.5 100 100 02/02/2023 16:57 WG1998813
Ethylbenzene 2620 13.7 100 100 02/02/2023 16:57 WG1998813
Hexachloro-1,3-butadiene U 33.7 100 100 02/02/2023 16:57 WG1998813
Isopropylbenzene 85.8 J 10.5 100 100 02/02/2023 16:57 WG1998813
p-Isopropyltoluene U 12.0 100 100 02/02/2023 16:57 WG1998813
2-Butanone (MEK)U 119 1000 100 02/02/2023 16:57 WG1998813
Methylene Chloride U 43.0 500 100 02/02/2023 16:57 WG1998813
4-Methyl-2-pentanone (MIBK)U 47.8 1000 100 02/02/2023 16:57 WG1998813
Methyl tert-butyl ether 5710 10.1 100 100 02/02/2023 16:57 WG1998813
Naphthalene 543 100 500 100 02/02/2023 16:57 WG1998813
n-Propylbenzene 216 9.93 100 100 02/02/2023 16:57 WG1998813
Styrene 48.6 J 11.8 100 100 02/02/2023 16:57 WG1998813
1,1,1,2-Tetrachloroethane U 14.7 100 100 02/02/2023 16:57 WG1998813
1,1,2,2-Tetrachloroethane U 13.3 100 100 02/02/2023 16:57 WG1998813
Tetrachloroethene U 30.0 100 100 02/02/2023 16:57 WG1998813
Toluene 270 27.8 100 100 02/02/2023 16:57 WG1998813
1,2,3-Trichlorobenzene U 23.0 100 100 02/02/2023 16:57 WG1998813
1,2,4-Trichlorobenzene U 48.1 100 100 02/02/2023 16:57 WG1998813
1,1,1-Trichloroethane U 14.9 100 100 02/02/2023 16:57 WG1998813
1,1,2-Trichloroethane U 15.8 100 100 02/02/2023 16:57 WG1998813
Trichloroethene U 19.0 100 100 02/02/2023 16:57 WG1998813
Trichlorofluoromethane U 16.0 500 100 02/02/2023 16:57 WG1998813
1,2,3-Trichloropropane U 23.7 250 100 02/02/2023 16:57 WG1998813
1,2,4-Trimethylbenzene 949 32.2 100 100 02/02/2023 16:57 WG1998813
1,3,5-Trimethylbenzene 231 10.4 100 100 02/02/2023 16:57 WG1998813
Vinyl chloride U 23.4 100 100 02/02/2023 16:57 WG1998813
o-Xylene 97.7 J 17.4 100 100 02/02/2023 16:57 WG1998813
m&p-Xylenes 1680 43.0 200 100 02/02/2023 16:57 WG1998813
(S) Toluene-d8 91.4 80.0-120 02/02/2023 16:57 WG1998813
(S) 4-Bromofluorobenzene 84.9 77.0-126 02/02/2023 16:57 WG1998813
(S) 1,2-Dichloroethane-d4 106 70.0-130 02/02/2023 16:57 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998655
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1579828-01,02
Method Blank (MB)
(MB) R3887799-2 02/06/23 07:54
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Alkalinity U 8450 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
Method Blank (MB)
(MB) R3887799-3 02/06/23 07:54
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Free Carbon Dioxide 10600 J 6670 20000
Sample Narrative:
BLANK: Endpoint pH 4.5
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 02/06/23 08:44 • (DUP) R3887799-4 02/06/23 08:48
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity ND ND 1 1.01 20
Sample Narrative:
OS: Endpoint pH 4.5
DUP: Endpoint pH 4.5
L1580443-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1580443-03 02/06/23 08:44 • (DUP) R3887799-5 02/06/23 08:48
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide 72500 69800 1 3.80 20
Sample Narrative:
OS: Endpoint pH 4.5
DUP: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998655
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011 L1579828-01,02
L1581078-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581078-01 02/06/23 09:28 • (DUP) R3887799-6 02/06/23 09:35
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Alkalinity 94000 94900 1 0.982 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
L1581078-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1581078-01 02/06/23 09:28 • (DUP) R3887799-7 02/06/23 09:35
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Free Carbon Dioxide ND ND 1 0.000 20
Sample Narrative:
OS: Endpoint pH 4.5 Headspace
DUP: Endpoint pH 4.5
Laboratory Control Sample (LCS)
(LCS) R3887799-1 02/06/23 07:43
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Alkalinity 100000 100000 100 90.0-110
Sample Narrative:
LCS: Endpoint pH 4.5
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996518
Wet Chemistry by Method 350.1 L1579828-01,02
Method Blank (MB)
(MB) R3885445-1 01/29/23 11:59
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ammonia Nitrogen U 117 250
L1579449-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1579449-03 01/29/23 12:29 • (DUP) R3885445-5 01/29/23 12:30
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ammonia Nitrogen U U 1 0.000 10
L1580376-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1580376-02 01/29/23 12:51 • (DUP) R3885445-7 01/29/23 12:53
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ammonia Nitrogen 4070 4110 1 0.904 10
Laboratory Control Sample (LCS)
(LCS) R3885445-2 01/29/23 12:00
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ammonia Nitrogen 7500 7240 96.6 90.0-110
L1579449-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579449-02 01/29/23 12:24 • (MS) R3885445-3 01/29/23 12:26 • (MSD) R3885445-4 01/29/23 12:27
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ammonia Nitrogen 5000 U 4910 4960 98.2 99.3 1 90.0-110 1.05 10
L1580376-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1580376-01 01/29/23 12:48 • (MS) R3885445-6 01/29/23 12:50
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Ammonia Nitrogen 5000 3020 7680 93.2 1 90.0-110
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995970
Wet Chemistry by Method 3500Fe B-2011 L1579828-01,02
Method Blank (MB)
(MB) R3885167-1 01/27/23 14:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ferrous Iron U 15.0 50.0
L1579870-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579870-01 01/27/23 14:56 • (DUP) R3885167-3 01/27/23 14:58
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ferrous Iron U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3885167-2 01/27/23 14:54
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Ferrous Iron 1000 921 92.1 85.0-115
L1579870-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579870-06 01/27/23 15:01 • (MS) R3885167-4 01/27/23 15:02 • (MSD) R3885167-5 01/27/23 15:03
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Ferrous Iron 1000 489 1400 1390 91.2 89.9 1 80.0-120 0.932 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996244
Wet Chemistry by Method 351.2 L1579828-01,02
Method Blank (MB)
(MB) R3885866-1 01/30/23 22:35
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Kjeldahl Nitrogen, TKN U 140 250
L1579811-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579811-01 01/30/23 22:39 • (DUP) R3885866-3 01/30/23 22:40
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 4380 4320 1 1.38 20
L1579996-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579996-01 01/30/23 22:51 • (DUP) R3885866-6 01/30/23 22:52
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3885866-2 01/30/23 22:36
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Kjeldahl Nitrogen, TKN 14700 15200 103 75.2-120
L1579811-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579811-01 01/30/23 22:39 • (MS) R3885866-4 01/30/23 22:42 • (MSD) R3885866-5 01/30/23 22:43
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Kjeldahl Nitrogen, TKN 5000 4380 9780 9970 108 112 1 90.0-110 J5 1.92 20
Sample Narrative:
MS: Matrix spike failure due to matrix.
MSD: Matrix spike failure due to matrix.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996244
Wet Chemistry by Method 351.2 L1579828-01,02
L1579996-01 Original Sample (OS) • Matrix Spike (MS)
(OS) L1579996-01 01/30/23 22:51 • (MS) R3885866-7 01/30/23 22:54
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Kjeldahl Nitrogen, TKN 5000 U 3850 77.0 1 90.0-110 J6
Sample Narrative:
MS: Matrix spike failure due to matrix.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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QUALITY CONTROL SUMMARYWG2000697
Wet Chemistry by Method 353.2 L1579828-01,02
Method Blank (MB)
(MB) R3887874-1 02/06/23 12:52
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate-Nitrite U 50.0 100
L1582417-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1582417-02 02/06/23 12:59 • (DUP) R3887874-3 02/06/23 13:01
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate-Nitrite 446 439 1 1.58 20
Laboratory Control Sample (LCS)
(LCS) R3887874-2 02/06/23 12:53
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate-Nitrite 2500 2580 103 90.0-110
L1582417-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1582417-02 02/06/23 12:59 • (MS) R3887874-4 02/06/23 13:02 • (MSD) R3887874-5 02/06/23 13:07
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate-Nitrite 2500 446 3010 2960 103 101 1 90.0-110 1.68 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996209
Wet Chemistry by Method 410.4 L1579828-01,02
Method Blank (MB)
(MB) R3885288-1 01/27/23 21:21
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
COD U 11700 20000
Laboratory Control Sample (LCS)
(LCS) R3885288-2 01/27/23 21:21
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
COD 500000 475000 95.1 90.0-110
L1579980-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579980-01 01/27/23 21:28 • (MS) R3885288-5 01/27/23 21:29 • (MSD) R3885288-6 01/27/23 21:31
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
COD 500000 87300 563000 517000 95.2 86.0 1 80.0-120 8.49 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996774
Wet Chemistry by Method 4500S2 D-2011 L1579828-01,02
Method Blank (MB)
(MB) R3885577-1 01/30/23 09:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Sulfide U 25.0 50.0
L1579789-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579789-01 01/30/23 09:55 • (DUP) R3885577-3 01/30/23 09:57
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Sulfide U U 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3885577-2 01/30/23 09:54
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Sulfide 500 430 86.0 85.0-115
L1580194-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1580194-01 01/30/23 10:02 • (MS) R3885577-4 01/30/23 10:03 • (MSD) R3885577-5 01/30/23 10:03
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Sulfide 500 U 153 136 30.6 27.2 1 80.0-120 J6 J6 11.8 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995769
Wet Chemistry by Method 5210 B-2016 L1579828-01,02
Method Blank (MB)
(MB) R3886373-1 02/01/23 11:28
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/l mg/l mg/l
BOD 0.308 B1 0.200 0.200
L1579298-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579298-01 02/01/23 08:16 • (DUP) R3886373-3 02/01/23 08:20
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD ND ND 1 0 30
L1579834-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579834-01 02/01/23 09:22 • (DUP) R3886373-4 02/01/23 09:26
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/l mg/l %%
BOD 6.21 5.81 1 6.66 30
Laboratory Control Sample (LCS)
(LCS) R3886373-2 02/01/23 08:10
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 166 83.6 84.6-115 J-
Laboratory Control Sample (LCS)
(LCS) R3886373-5 02/01/23 09:43
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte mg/l mg/l %%
BOD 198 162 81.6 84.6-115 J-
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995863
Wet Chemistry by Method 9056A L1579828-01,02
Method Blank (MB)
(MB) R3885391-1 01/27/23 09:50
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Nitrate U 48.0 100
Nitrite U 42.0 100
Sulfate U 594 5000
L1579828-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1579828-01 01/27/23 13:10 • (DUP) R3885391-3 01/27/23 13:26
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate U U 1 0.000 15
Nitrite U U 1 0.000 15
Sulfate U U 1 0.000 15
L1579870-07 Original Sample (OS) • Duplicate (DUP)
(OS) L1579870-07 01/27/23 12:22 • (DUP) R3885391-6 01/27/23 18:13
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Nitrate 208 180 1 14.9 15
Nitrite U U 1 0.000 15
Sulfate 14800 14800 1 0.0623 15
Laboratory Control Sample (LCS)
(LCS) R3885391-2 01/27/23 10:06
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Nitrate 8000 7880 98.5 80.0-120
Nitrite 8000 8350 104 80.0-120
Sulfate 40000 41000 102 80.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995863
Wet Chemistry by Method 9056A L1579828-01,02
L1579828-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579828-01 01/27/23 13:10 • (MS) R3885391-4 01/27/23 13:42 • (MSD) R3885391-5 01/27/23 14:30
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Nitrate 5000 U 5080 5050 102 101 1 80.0-120 0.637 15
Nitrite 5000 U 5280 5200 106 104 1 80.0-120 1.59 15
Sulfate 50000 U 51800 51000 104 102 1 80.0-120 1.51 15
L1579870-07 Original Sample (OS) • Matrix Spike (MS)
(OS) L1579870-07 01/27/23 12:22 • (MS) R3885391-7 01/27/23 18:29
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Nitrate 5000 208 5180 99.4 1 80.0-120
Nitrite 5000 U 5220 104 1 80.0-120
Sulfate 50000 14800 64300 99.0 1 80.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995911
Wet Chemistry by Method 9060A L1579828-01,02
Method Blank (MB)
(MB) R3885405-2 01/28/23 10:43
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
TOC (Total Organic Carbon)564 J 102 1000
L1579449-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1579449-02 01/28/23 15:04 • (DUP) R3885405-7 01/28/23 15:20
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)810 691 1 15.9 J 20
Laboratory Control Sample (LCS)
(LCS) R3885405-1 01/28/23 09:45
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
TOC (Total Organic Carbon)75000 77100 103 85.0-115
L1579404-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579404-02 01/28/23 11:20 • (MS) R3885405-3 01/28/23 11:46 • (MSD) R3885405-4 01/28/23 12:13
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
TOC (Total Organic Carbon)50000 3890 54300 53900 101 100 1 80.0-120 0.592 20
L1579404-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579404-03 01/28/23 12:31 • (MS) R3885405-5 01/28/23 12:56 • (MSD) R3885405-6 01/28/23 13:20
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
TOC (Total Organic Carbon)50000 2460 53300 51400 102 97.9 1 80.0-120 3.57 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1996029
Metals (ICP) by Method 6010D L1579828-01,02
Method Blank (MB)
(MB) R3885661-1 01/30/23 10:39
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Iron U 18.0 100
Manganese U 0.934 10.0
Laboratory Control Sample (LCS)
(LCS) R3885661-2 01/30/23 10:41
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Iron 10000 9770 97.7 80.0-120
Manganese 1000 923 92.3 80.0-120
L1579988-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579988-04 01/30/23 10:44 • (MS) R3885661-4 01/30/23 10:50 • (MSD) R3885661-5 01/30/23 10:52
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Iron 10000 24.1 9540 9520 95.1 95.0 1 75.0-125 0.152 20
Manganese 1000 428 1320 1310 89.1 88.6 1 75.0-125 0.355 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1995909
Volatile Organic Compounds (GC) by Method RSK175 L1579828-01,02
Method Blank (MB)
(MB) R3885209-2 01/27/23 13:51
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Methane U 2.91 10.0
L1579708-14 Original Sample (OS) • Duplicate (DUP)
(OS) L1579708-14 01/27/23 14:47 • (DUP) R3885209-3 01/27/23 14:54
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane 768 777 1 1.17 20
L1579777-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1579777-03 01/27/23 15:40 • (DUP) R3885209-4 01/27/23 15:57
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Methane U U 1 0.000 20
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3885209-1 01/27/23 13:48 • (LCSD) R3885209-9 01/27/23 16:20
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Methane 67.8 68.6 67.1 101 99.0 85.0-115 2.21 20
L1579708-10 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579708-10 01/27/23 14:34 • (MS) R3885209-5 01/27/23 16:10 • (MSD) R3885209-6 01/27/23 16:13
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Methane 67.8 49.7 114 121 94.8 105 1 50.0-150 5.96 20
L1579777-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1579777-01 01/27/23 15:35 • (MS) R3885209-7 01/27/23 16:15 • (MSD) R3885209-8 01/27/23 16:18
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Methane 67.8 U 77.0 75.3 114 111 1 50.0-150 2.23 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579828-01,02
Method Blank (MB)
(MB) R3887201-2 02/02/23 11:05
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
Bromomethane U 0.605 5.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579828-01,02
Method Blank (MB)
(MB) R3887201-2 02/02/23 11:05
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
(S) Toluene-d8 92.4 80.0-120
(S) 4-Bromofluorobenzene 85.8 77.0-126
(S) 1,2-Dichloroethane-d4 105 70.0-130
Laboratory Control Sample (LCS)
(LCS) R3887201-1 02/02/23 09:25
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acetone 25.0 25.4 102 19.0-160
Acrolein 25.0 16.0 64.0 10.0-160
Acrylonitrile 25.0 22.6 90.4 55.0-149
Benzene 5.00 4.97 99.4 70.0-123
Bromobenzene 5.00 4.92 98.4 73.0-121
Bromodichloromethane 5.00 5.41 108 75.0-120
Bromoform 5.00 4.81 96.2 68.0-132
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579828-01,02
Laboratory Control Sample (LCS)
(LCS) R3887201-1 02/02/23 09:25
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Bromomethane 5.00 5.62 112 10.0-160
n-Butylbenzene 5.00 4.95 99.0 73.0-125
sec-Butylbenzene 5.00 4.76 95.2 75.0-125
tert-Butylbenzene 5.00 4.51 90.2 76.0-124
Carbon tetrachloride 5.00 5.02 100 68.0-126
Chlorobenzene 5.00 4.64 92.8 80.0-121
Chlorodibromomethane 5.00 4.73 94.6 77.0-125
Chloroethane 5.00 5.63 113 47.0-150
Chloroform 5.00 5.53 111 73.0-120
Chloromethane 5.00 3.89 77.8 41.0-142
2-Chlorotoluene 5.00 4.89 97.8 76.0-123
4-Chlorotoluene 5.00 4.63 92.6 75.0-122
1,2-Dibromo-3-Chloropropane 5.00 4.30 86.0 58.0-134
1,2-Dibromoethane 5.00 4.87 97.4 80.0-122
Dibromomethane 5.00 5.16 103 80.0-120
1,2-Dichlorobenzene 5.00 5.10 102 79.0-121
1,3-Dichlorobenzene 5.00 5.17 103 79.0-120
1,4-Dichlorobenzene 5.00 5.21 104 79.0-120
Dichlorodifluoromethane 5.00 6.40 128 51.0-149
1,1-Dichloroethane 5.00 4.66 93.2 70.0-126
1,2-Dichloroethane 5.00 5.29 106 70.0-128
1,1-Dichloroethene 5.00 5.21 104 71.0-124
cis-1,2-Dichloroethene 5.00 4.78 95.6 73.0-120
trans-1,2-Dichloroethene 5.00 4.92 98.4 73.0-120
1,2-Dichloropropane 5.00 4.57 91.4 77.0-125
1,1-Dichloropropene 5.00 4.66 93.2 74.0-126
1,3-Dichloropropane 5.00 4.77 95.4 80.0-120
2,2-Dichloropropane 5.00 5.50 110 58.0-130
Di-isopropyl ether 5.00 4.21 84.2 58.0-138
Ethylbenzene 5.00 4.44 88.8 79.0-123
Hexachloro-1,3-butadiene 5.00 5.94 119 54.0-138
Isopropylbenzene 5.00 4.20 84.0 76.0-127
p-Isopropyltoluene 5.00 4.69 93.8 76.0-125
2-Butanone (MEK)25.0 25.1 100 44.0-160
Methylene Chloride 5.00 4.97 99.4 67.0-120
4-Methyl-2-pentanone (MIBK)25.0 22.9 91.6 68.0-142
Methyl tert-butyl ether 5.00 5.04 101 68.0-125
Naphthalene 5.00 4.28 85.6 54.0-135
n-Propylbenzene 5.00 4.53 90.6 77.0-124
Styrene 5.00 3.97 79.4 73.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG1998813
Volatile Organic Compounds (GC/MS) by Method 6200B-2011 L1579828-01,02
Laboratory Control Sample (LCS)
(LCS) R3887201-1 02/02/23 09:25
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
1,1,1,2-Tetrachloroethane 5.00 4.79 95.8 75.0-125
1,1,2,2-Tetrachloroethane 5.00 5.39 108 65.0-130
Tetrachloroethene 5.00 4.99 99.8 72.0-132
Toluene 5.00 4.63 92.6 79.0-120
1,2,3-Trichlorobenzene 5.00 4.87 97.4 50.0-138
1,2,4-Trichlorobenzene 5.00 4.86 97.2 57.0-137
1,1,1-Trichloroethane 5.00 5.59 112 73.0-124
1,1,2-Trichloroethane 5.00 4.82 96.4 80.0-120
Trichloroethene 5.00 4.57 91.4 78.0-124
Trichlorofluoromethane 5.00 6.02 120 59.0-147
1,2,3-Trichloropropane 5.00 5.64 113 73.0-130
1,2,4-Trimethylbenzene 5.00 4.72 94.4 76.0-121
1,3,5-Trimethylbenzene 5.00 4.66 93.2 76.0-122
Vinyl chloride 5.00 4.45 89.0 67.0-131
o-Xylene 5.00 4.21 84.2 80.0-122
m&p-Xylenes 10.0 9.15 91.5 80.0-122
(S) Toluene-d8 92.4 80.0-120
(S) 4-Bromofluorobenzene 84.4 77.0-126
(S) 1,2-Dichloroethane-d4 108 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec.Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Dilution
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Limits
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
Qualifier
This column provides a letter and/or number designation that corresponds to additional information concerning the result
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
Result
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL”
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)Confidence level of 2 sigma.
Case Narrative (Cn)
A brief discussion about the included sample results, including a discussion of any non-conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
Summary (Qc)
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
Sample Chain of
Custody (Sc)
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
Sample Results (Sr)
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
B The same analyte is found in the associated blank.
B1 The blank depletion was greater than the recommended maximum depletion of 0.2mg/L.
J The identification of the analyte is acceptable; the reported value is an estimate.
J5 The sample matrix interfered with the ability to make any accurate determination; spike value is high.
J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.
J-The associated batch QC was outside the lower control limits; associated data has a potential negative bias.
K5 The Dilution water D.O. depletion was > 0.2 mg/L.
K6 Glucose/glutamic acid BOD/CBOD was below method acceptance criteria.
K9 Test replicates show more than 30% difference between high and low values.
Q Sample was prepared and/or analyzed past holding time as defined in the method. Concentrations should be considered minimum values.
T8 Sample(s) received past/too close to holding time expiration.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Louisiana AI30792 Tennessee ¹ ⁴2006
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas ⁵LAB0152
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ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 21:59 31 of 34
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 22:11 31 of 34

Chevron - 205513

DATA REVIEW
High point

Volatile organic compounds, Dissolved gases, Metals and General Chemistry

SDG# L1579828

Analyses Performed By:
Pace Analytical National
Mount Juliet, TN 37122

Report # 48697R
Review Level: Tier II
Project: 30064349.19.61

DATA REVIEW REPORT
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SUMMARY
This data quality assessment summarizes the review of Sample Delivery Groups (SDGs) # L1579828
for samples collected in association with the Chevron 205513 High Point Site. The review was conducted as a Tier II evaluation and included review of data package completeness. Only analytical data associated with constituents of concern were reviewed for this validation. Field documentation was not included in this review. Included with this assessment are the validation annotated sample result sheets and chain of custody. Analyses were performed on the following samples:
Sample ID Lab ID Matrix Sample Collection Date Parent Sample Analysis
VOC RSK175 Met. Misc.
MW-2-W-20230125 L1579828-01 Water 01/25/2023 X X X X
DUP-01-W-20230125 L1579828-02 Water 01/25/2023 MW-2-W-20230125 X X X X

Notes:
VOC = volatile organic compounds.
RSK 175 = Dissolved Gases
Met = Metals
Misc. = General Chemistry

DATA REVIEW REPORT
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ANALYTICAL DATA PACKAGE DOCUMENTATION
The table below is the evaluation of the data package completeness.
Items Reviewed Reported Performance Acceptable Not Required No Yes No Yes
1. Sample receipt condition X X
2. Requested analyses and sample results X X
3. Master tracking list X X
4. Methods of analysis X X
5. Reporting limits X X
6. Sample collection date X X
7. Laboratory sample received date X X
8. Sample preservation verification (as applicable) X X
9. Sample preparation/extraction/analysis dates X X
10. Fully executed Chain-of-Custody (COC) form X X
11. Narrative summary of QA or sample problems provided X X
12. Data Package Completeness and Compliance X X
Note: QA - Quality Assurance
DATA REVIEW REPORT
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ORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6200B. Data were reviewed in accordance with the method specified criteria, USEPA National
Functional Guidelines NFG for Organic Superfund Methods Data Review, EPA-540-R-20-005 (November
2020), with reference to the historical (USEPA Contract Laboratory Program National Functional
Guidelines for Organic Data Review, OSWER 9240.1-05A-P, October 1999, as appropriate).
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and had already been subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with USEPA National Functional
Guidelines:
• Concentration (C) Qualifiers
U The compound was analyzed for but not detected. The associated value is the compound
quantitation limit.
B The compound has been found in the sample as well as its associated blank, its presence in
the sample may be suspect.
• Quantitation (Q) Qualifiers
E The compound was quantitated above the calibration range.
D Concentration is based on a diluted sample analysis.
• Validation Qualifiers
J The compound was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The compound was not detected above the reported sample quantitation limit. However, the
reported limit is approximate and may or may not represent the actual limit of quantitation.
JN The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification. The associated numerical value is an estimated concentration
only.
UB Compound considered non-detect at the listed value due to associated blank contamination.
N The analysis indicates the presence of a compound for which there is presumptive evidence to
make a tentative identification.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
DATA REVIEW REPORT
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that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

DATA REVIEW REPORT
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VOLATILE ORGANIC COMPOUND (VOC) ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
SW-846 6200B Water 14 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2 s.u.
Note:
s.u. Standard units
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds were not detected above the SDL in the associated blanks; therefore, detected sample
results were not associated with blank contamination.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique. VOC
analysis requires that all surrogates associated with the analysis exhibit recoveries within the laboratory-
established acceptance limits.
All surrogate recoveries were within the control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analyses
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit a percent recovery within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS/MSD recoveries must exhibit
an RPD within the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on sample locations
where the compound concentration detected in the parent sample exceeds the MS/MSD concentration by
a factor of four or greater.
MS/MSD analysis was not performed on any of the samples from this SDG.
5. Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Analysis
The LCS/LCSD analysis is used to assess the precision and accuracy of the analytical method
independent of matrix interferences. The compounds associated with the LCS/LCSD analysis must
exhibit a percent recovery within the laboratory-established acceptance limits.
DATA REVIEW REPORT
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All compounds associated with the LCS/LCSD analysis exhibited recoveries within the control limits.
6. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to 5 times the RL, a control limit of two times the RL is applied for water matrices.
Results for duplicate samples are summarized in the following table.

Sample ID/Duplicate ID Compound
Sample
Result
Duplicate
Result RPD
MW-2-W-20230125 / DUP-01-W-
20230125
Benzene 12000 11600 3%
Di-isopropyl ether 44.8 42.1 AC
Ethylbenzene 2650 2620 1%
Isopropylbenzene 84.1 85.8 AC
Methyl tert-butyl ether 5800 5710 2%
Naphthalene 499 543 AC
n-Propylbenzene 219 216 AC
Styrene 55.2 48.6 AC
Toluene 291 270 AC
1,2,4-Trimethylbenzene 927 949 AC
1,3,5-Trimethylbenzene 230 231 AC
o-Xylene 106 97.7 AC
m&p-Xylenes 1790 1680 AC
n-Butylbenzene 200 U 15.8 AC
Notes:
AC Acceptable
The calculated RPDs between the parent sample and field duplicate were acceptable.

7. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.
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DATA VALIDATION CHECKLIST FOR VOCs

VOCs: SW-846 6200B Reported Performance
Acceptable Not
Required No Yes No Yes
GAS CHROMATOGRAPHY/MASS SPECTROMETRY (GC/MS)
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
C. Trip blanks X X
Laboratory Control Sample (LCS) X X
Laboratory Control Sample Duplicate(LCSD) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) X X
Matrix Spike Duplicate (MSD) X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Surrogate Spike Recoveries X X
Dilution Factor X X
Notes:
%R Percent recovery
RPD Relative percent difference

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DISSOLVED GASES ANALYSES
1. Holding Times
The specified holding times for the following methods are presented in the following table.
Method Matrix Holding Time Preservation
RSK-175 Water 14 days from collection to analysis Cool to < 6 °C; pH > 10 with TSP
All samples were analyzed within the specified holding time criteria.
2. Blank Contamination
Quality assurance (QA) blanks (i.e. method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
(common laboratory contaminant compounds are calculated at ten times) is calculated for QA blanks
containing concentrations greater than the sample detection limit (SDL). The BAL is compared to the
associated sample results to determine the appropriate qualification of the sample results, if needed.
Compounds were not detected above the SDL in the associated blanks; therefore, detected sample
results were not associated with blank contamination.
3. Surrogates/System Monitoring Compounds
All samples to be analyzed for organic compounds are spiked with surrogate compounds prior to sample
preparation to evaluate overall laboratory performance and efficiency of the analytical technique.
Dissolved gases analysis requires that all surrogates associated with the analysis exhibit recoveries
within the laboratory-established acceptance limits.
All surrogate recoveries were within control limits.
4. Matrix Spike/Matrix Spike Duplicate (MS/MSD) Analysis
MS/MSD data are used to assess the precision and accuracy of the analytical method. The compounds
used to perform the MS/MSD analysis must exhibit recoveries within the laboratory-established
acceptance limits. The relative percent difference (RPD) between the MS and MSD results must be within
the laboratory-established acceptance limits.
Note: The MS/MSD recovery control limits do not apply for MS/MSD performed on samples where the
compound concentration detected in the parent sample exceeds the MS/MSD concentration by a factor of
four or greater.
The MS/MSD analysis was not performed on any of the sample from this SDG.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The compounds associated with the LCS analysis must exhibit a percent recovery within
the laboratory-established acceptance limits.
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All compounds associated with the LCS analysis exhibited recoveries within the control limits.
6. Field Duplicate Sample Analysis
The field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 25% for water matrices is applied to the RPD between the parent
sample and the field duplicate. In the instance when the parent and/or duplicate sample concentrations
are less than or equal to five times the RL, a control limit of two times the RL is applied to the difference
between the results for water matrices.
Results for duplicate samples are summarized in the following table.

Sample ID/Duplicate ID Compound
Sample
Result
Duplicate
Result RPD
MW-2-W-20230125 / DUP-01-W-
20230125 Methane 199 184 8%
Notes:
AC Acceptable
The calculated RPDs between the parent sample and field duplicate were acceptable.
7. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR DISSOLVED GASES

Dissolved Gases: RSK-175 Reported Performance Acceptable Not Required No Yes No Yes
Gas Chromatography/Thermal Conductivity Detector (GC/TCD)
Tier II Validation
Holding times/Temperature/Preservation X X
Reporting limits (units) X X
Blanks
A. Method blanks X X
B. Equipment blanks X X
Laboratory Control Sample (LCS) Accuracy (%R) X X
Laboratory Control Sample Duplicate (LCSD) (%R) X X
LCS/LCSD Precision (RPD) X X
Matrix Spike Sample (MS) (%R) X X
Matrix Spike Duplicate Sample (MSD) (%R) X X
MS/MSD Precision (RPD) X X
Laboratory Duplicate Sample (RPD) X X
Field Duplicate Sample (RPD) X X
Surrogate Spike Recoveries (%R) X X
Dilution Factor X X
Notes: %R Percent recovery RPD Relative percent difference
DATA REVIEW REPORT
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INORGANIC ANALYSIS INTRODUCTION
Analyses were performed according to United States Environmental Protection Agency (USEPA) SW-846
Methods 6010D, 2320B, 4500, 350.1, 3500Fe, 351.2, 353.2,410.4, 4500S2, 5210B, 9056A and 9060A.
Data were reviewed in accordance with USEPA National Functional Guidelines of October 2004.
The data review process is an evaluation of data on a technical basis rather than a determination of
contract compliance. As such, the standards against which the data are being weighed may differ from
those specified in the analytical method. It is assumed that the data package represents the best efforts
of the laboratory and that it was already subjected to adequate and sufficient quality review prior to
submission.
During the review process, laboratory qualified and unqualified data are verified against the supporting
documentation. Based on this evaluation, qualifier codes may be added, deleted, or modified by the data
reviewer. Results are qualified with the following codes in accordance with the USEPA National
Functional Guidelines:
• Concentration (C) Qualifiers
U The analyte was analyzed for but not detected. The associated value is the analyte
instrument detection limit.
J The reported value was obtained from a reading less than the reporting limit (RL), but
greater than or equal to the method detection limit (MDL).
• Quantitation (Q) Qualifiers
E The reported value is estimated due to the presence of interference.
N Spiked sample recovery is not within control limits.
* Duplicate analysis is not within control limits.
• Validation Qualifiers
J The analyte was positively identified; however, the associated numerical value is an
estimated concentration only.
UJ The analyte was not detected above the reporting limit. However, the reported limit is
approximate and may or may not represent the actual limit of detection.
UB Analyte is considered non-detect at the listed value due to associated blank contamination.
R The sample results are rejected.
Two facts should be noted by all data users. First, the "R" flag means that the associated value is
unusable. In other words, due to significant quality control (QC) problems, the analysis is invalid and
provides no information as to whether the compound is present or not. "R" values should not appear on
data tables because they cannot be relied upon, even as a last resort. The second fact to keep in mind is
that no compound concentration, even if it has passed all QC tests, is guaranteed to be accurate. Strict
QC serves to increase confidence in data but any value potentially contains error.

DATA REVIEW REPORT
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METALS ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
SW-846 6010D Water 180 days from collection to analysis Preserved to a pH of less
than 2.
All samples were analyzed within the specified holding times.
2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
Analytes were not detected above the MDL in the associated blanks; therefore, detected sample results
were not associated with blank contamination.
3. Matrix Spike / Matrix Spike Duplicate (MS/MSD) /Laboratory Duplicate Analysis
MS/MSD and laboratory duplicate data are used to assess the precision and accuracy of the analytical
method.
3.1 MS/MSD Analysis
All metal analytes must exhibit a percent recovery within the established acceptance limits of 75% to
125%. The MS recovery control limits do not apply for MS performed on sample locations where the
analyte’s concentration detected in the parent sample exceeds the MS concentration by a factor of four or
greater.
The MS/MSD analysis was not performed on any of the samples from this SDG.
3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was not performed on any of the samples from this SDG.
4. Field Duplicate Analysis
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Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 30% for water matrices and 50% for soil matrices is applied to the
RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Results for duplicate samples are summarized in the following table.

Sample ID/Duplicate ID Analyte Sample Result
Duplicate
Result RPD
MW-2-W-20230125 / DUP-01-W-20230125 Iron 11000 11200 2%
Manganese 12400 12800 3%
Notes:
AC = Acceptable

The calculated RPDs between the parent sample and field duplicate were acceptable.
5. Laboratory Control Sample (LCS) Analysis
The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
The LCS analysis exhibited recoveries within the control limits.
8. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR METAL

METALS; SW-846 6010D Reported
Performance
Acceptable Not
Required No Yes No Yes
Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES)
Tier II Validation
Holding Times X X
Reporting limits (units) X X
Blanks
A. Instrument Blanks X X
B. Method Blanks X X
C. Equipment/Field Blanks X X
Laboratory Control Sample (LCS) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate (MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Reporting Limit Verification X X
Notes:
%R = Percent recovery
RPD = Relative percent difference

DATA REVIEW REPORT
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GENERAL CHEMISTRY ANALYSES

1. Holding Times
The specified holding times for the following methods are presented in the following table.

Method Matrix Holding Time Preservation
Alkalinity by SM 2320 B-11 Water 14 days from collection to analysis Cool to <6 °C.
Free Carbon Dioxide by 4500CO2 Water 24 hours from collection to analysis Preserved to a pH of less
than 2.
Ammonia Nitrogen by 350.1 Water 28 days from collection to analysis Preserved to a pH of less
than 2.
Ferrous iron by 3500Fe Water 24 hours from collection to analysis Preserved to a pH of less
than 2.
Total Kjeldahl Nitrogen
by EPA 351.2 Water 28 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2.
Nitrogen, Nitrate-N + Nitrite-N
(combined result) by EPA 353.2 Water 28 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2.
Chemical Oxygen Demand (COD)
by SM5220 Water 28 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2.
Sulfide by 4500S2 Water 15 mins from collection to analysis Preserved to a pH of less
than 2.
Biological Oxygen Demand (BOD)
by SM5210 B-11 Water 48 hours from collection to analysis Cool to <6 °C.
Sulfate by SW-846 300/9056A Water 28 days from collection to analysis Cool to <6 °C.
Total Organic Carbon by SM5310 Water 28 days from collection to analysis Cool to <6 °C; preserved to
a pH of less than 2.
The analyses that exceeded the holding time are presented in the following table.

Sample Locations Analyte Holding Time Criteria
MW-2-W-20230125
DUP-01-W-20230125
Free Carbon Dioxide Analysis completed less than two
times holding time
24 hours from
collection to analysis Ferrous Iron
Sulfide Analysis completed greater than two
times holding time
15 mins from collection
to analysis

DATA REVIEW REPORT
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Sample results associated with sample locations analyzed by analytical methods mentioned above were
qualified, as specified in the table below. All other holding times were met.

Criteria
Qualification
Detected
Analytes
Non-detect
Analytes
Analysis completed less than two times holding time J UJ
Analysis completed greater than two times holding time J R

2. Blank Contamination
Quality assurance (QA) blanks (i.e., method and rinse blanks) are prepared to identify any contamination
which may have been introduced into the samples during sample preparation or field activity. Method
blanks measure laboratory contamination. Rinse blanks measure contamination of samples during field
operations.
A blank action level (BAL) of five times the concentration of a detected compound in an associated blank
is calculated for QA blanks containing concentrations greater than the method detection limit (MDL). The
BAL is compared to the associated sample results to determine the appropriate qualification of the
sample results, if needed.
All analytes associated with the QA blanks exhibited a concentration less than the MDL, with the
exception of the compounds listed in the following table. Sample results associated with QA blank
contamination that were greater than the BAL resulted in the removal of the laboratory qualifier (B) of
data. Sample results less than the BAL associated with the following sample locations were qualified as
listed in the following table.

Sample
Locations Analytes Sample Result Qualification
MW-2-W-20230125 Free Carbon
Dioxide Detected sample results >RL and <BAL “UB” at detected
sample concentration
Note:
RL Reporting limit

3. Matrix Spike (MS)/Laboratory Duplicate Analysis
MS and laboratory duplicate data are used to assess the precision and accuracy of the analytical method.
3.1 MS Analysis
All analytes must exhibit a percent recovery within the established acceptance limits of 75% to 125%.
The MS recovery control limits do not apply for MS performed on sample locations where the analyte’s
concentration detected in the parent sample exceeds the MS concentration by a factor of four or greater.
In instance where this is true, the data will not be qualified even if the percent recovery does not meet the
control limits and the laboratory flag will be removed.
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The MS/MSD analysis performed on sample ID MW-2-W-20230125, exhibited acceptable recoveries and
RPDs.
3.2 Laboratory Duplicate Analysis
The laboratory duplicate relative percent difference (RPD) criterion is applied when parent and duplicate
sample concentrations are greater than or equal to 5 times the RL. A control limit of 20% for water
matrices and 35% for soil matrices is applied when the criteria above is true. In the instance when the
parent and/or duplicate sample concentrations are less than or equal to 5 times the RL, a control limit of
one times the RL is applied for water matrices and two times the RL for soil matrices.
The laboratory duplicate analysis was performed on sample ID MW-2-W-20230125, exhibited acceptable
RPDs.
4. Field Duplicate Analysis
Field duplicate analysis is used to assess the overall precision of the field sampling procedures and
analytical method. A control limit of 50% for water matrices and 100% for soil matrices is applied to the
RPD between the parent sample and the field duplicate. In the instance when the parent and/or duplicate
sample concentrations are less than or equal to 5 times the RL, a control limit of two times the RL is
applied for water matrices or three times the RL is applied for soil matrices.
Results for duplicate samples are summarized in the following table.

Sample ID/Duplicate ID Analyte
Sample
Result
Duplicate
Result RPD
MW-2-W-20230125 / DUP-01-W-20230125
Organic Nitrogen 208 204 AC
Alkalinity 306000 309000 1%
Free Carbon Dioxide 41800 78900 AC
Ferrous Iron 11100 11700 5%
Kjeldahl Nitrogen, TKN 208 204 AC
COD 255000 259000 2%
BOD 6.91 12.1 55%
Nitrate 100 271 AC
TOC (Total Organic Carbon) 49900 50500 1%
Notes:
ND = Not detected
AC = Acceptable
NC = Non-compliant

The analyte BOD associated with samples locations MW-2-W-20230125 / DUP-01-W-20230125 exhibited
a field duplicate RPD greater than the control limit. The associated sample results from sample locations
for the listed analyte were qualified as estimated.
5. Laboratory Control Sample (LCS) Analysis
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The LCS analysis is used to assess the accuracy of the analytical method independent of matrix
interferences. The analytes associated with the LCS analysis must exhibit a percent recovery between
the control limits of 80% and 120%.
All LCS recoveries were within control limits, with the exception of the analytes associated with sample
locations, as presented in the following table.

Sample Location Analytes LCS
Recovery
MW-2-W-20230125
DUP-01-W-20230125 BOD >LL but <10%
The criteria used to evaluate LCS recoveries are presented in the following table. In the case of an LCS
deviation, the sample results are qualified.

Control limit Sample
Result Qualification
> the upper control limit (UL) Non-detect No Action
Detect J
< the lower control limit (LL) but > 10% Non-detect UJ
Detect J
< 10% Non-detect R
Detect J
6. System Performance and Overall Assessment
Overall system performance was acceptable. Other than for those deviations specifically mentioned in
this review, the overall data quality is within the guidelines specified in the method.

DATA REVIEW REPORT
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DATA VALIDATION CHECKLIST FOR GENERAL CHEMISTRY

General Chemistry Reported Performance
Acceptable Not
Required No Yes No Yes
Miscellaneous Instrumentation
Tier II Validation
Holding times X X
Reporting limits (units) X X
Blanks
D. Method blanks X X
E. Equipment blanks X X
Laboratory Control Sample (LCS) %R X X
Laboratory Control Sample Duplicate(LCSD) %R X X
LCS/LCSD Precision (RPD) X X
Matrix Spike (MS) %R X X
Matrix Spike Duplicate(MSD) %R X X
MS/MSD Precision (RPD) X X
Field/Lab Duplicate (RPD) X X
Dilution Factor X X
Moisture Content X X
Notes:
%R - percent recovery
RPD - relative percent difference,
%D – difference

DATA REVIEW REPORT
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VALIDATION PERFORMED BY: Bhagyashree Fulzele
SIGNATURE:
DATE: February 21, 2023

PEER REVIEW: Dennis Capria
DATE: March 2, 2023

CHAIN OF CUSTODY
CORRECTED SAMPLE ANALYSIS DATA
SHEETS

SAMPLE RESULTS - 01
L1579828
MW-2-W-20230125
Collected date/time: 01/25/23 09:52
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/30/2023 10:55 WG1996029
Organic Nitrogen 208 J 117 250 1 01/30/2023 22:44 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 306000 20000 1 02/06/2023 08:22 WG1998655
Free Carbon Dioxide 41800 B T8 20000 1 02/06/2023 08:22 WG1998655
Sample Narrative:
L1579828-01 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:33 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 11100 T8 150 500 10 01/27/2023 14:54 WG1995970
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN 208 J 140 250 1 01/30/2023 22:44 WG1996244
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 250 500 5 02/06/2023 12:54 WG2000697
Sample Narrative:
L1579828-01 WG2000697: Dilution due to matrix.
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 255000 11700 20000 1 01/27/2023 21:27 WG1996209
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/30/2023 09:59 WG1996774
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 6.91 K5 K6 Q 1.00 1 02/01/2023 09:13 WG1995769
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 21:59 5 of 34
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 22:11 5 of 34
SAMPLE RESULTS - 01
L1579828
MW-2-W-20230125
Collected date/time: 01/25/23 09:52
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate U T8 48.0 100 1 01/27/2023 13:10 WG1995863
Nitrite U T8 42.0 100 1 01/27/2023 13:10 WG1995863
Sulfate U T8 594 5000 1 01/27/2023 13:10 WG1995863
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)49900 102 1000 1 01/28/2023 20:55 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 11000 18.0 100 1 01/30/2023 10:55 WG1996029
Manganese 12400 4.67 50.0 5 01/30/2023 13:49 WG1996029
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 199 2.91 10.0 1 01/27/2023 15:47 WG1995909
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 2260 10000 200 02/02/2023 16:37 WG1998813
Acrolein U 508 10000 200 02/02/2023 16:37 WG1998813
Acrylonitrile U 134 2000 200 02/02/2023 16:37 WG1998813
Benzene 12000 18.8 200 200 02/02/2023 16:37 WG1998813
Bromobenzene U 23.6 200 200 02/02/2023 16:37 WG1998813
Bromodichloromethane U 27.2 200 200 02/02/2023 16:37 WG1998813
Bromoform U 25.8 200 200 02/02/2023 16:37 WG1998813
Bromomethane U 121 1000 200 02/02/2023 16:37 WG1998813
n-Butylbenzene U 31.4 200 200 02/02/2023 16:37 WG1998813
sec-Butylbenzene U 25.0 200 200 02/02/2023 16:37 WG1998813
tert-Butylbenzene U 25.4 200 200 02/02/2023 16:37 WG1998813
Carbon tetrachloride U 25.6 200 200 02/02/2023 16:37 WG1998813
Chlorobenzene U 23.2 200 200 02/02/2023 16:37 WG1998813
Chlorodibromomethane U 28.0 200 200 02/02/2023 16:37 WG1998813
Chloroethane U 38.4 1000 200 02/02/2023 16:37 WG1998813
Chloroform U 22.2 1000 200 02/02/2023 16:37 WG1998813
Chloromethane U 192 500 200 02/02/2023 16:37 WG1998813
2-Chlorotoluene U 21.2 200 200 02/02/2023 16:37 WG1998813
4-Chlorotoluene U 22.8 200 200 02/02/2023 16:37 WG1998813
1,2-Dibromo-3-Chloropropane U 55.2 1000 200 02/02/2023 16:37 WG1998813
1,2-Dibromoethane U 25.2 200 200 02/02/2023 16:37 WG1998813
Dibromomethane U 24.4 200 200 02/02/2023 16:37 WG1998813
1,2-Dichlorobenzene U 21.4 200 200 02/02/2023 16:37 WG1998813
1,3-Dichlorobenzene U 22.0 200 200 02/02/2023 16:37 WG1998813
1,4-Dichlorobenzene U 24.0 200 200 02/02/2023 16:37 WG1998813
Dichlorodifluoromethane U 74.8 1000 200 02/02/2023 16:37 WG1998813
1,1-Dichloroethane U 20.0 200 200 02/02/2023 16:37 WG1998813
1,2-Dichloroethane U 16.4 200 200 02/02/2023 16:37 WG1998813
1,1-Dichloroethene U 37.6 200 200 02/02/2023 16:37 WG1998813
cis-1,2-Dichloroethene U 25.2 200 200 02/02/2023 16:37 WG1998813
trans-1,2-Dichloroethene U 29.8 200 200 02/02/2023 16:37 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 21:59 6 of 34
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 22:11 6 of 34
SAMPLE RESULTS - 01
L1579828
MW-2-W-20230125
Collected date/time: 01/25/23 09:52
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 29.8 200 200 02/02/2023 16:37 WG1998813
1,1-Dichloropropene U 28.4 200 200 02/02/2023 16:37 WG1998813
1,3-Dichloropropane U 22.0 200 200 02/02/2023 16:37 WG1998813
2,2-Dichloropropane U 32.2 200 200 02/02/2023 16:37 WG1998813
Di-isopropyl ether 44.8 J 21.0 200 200 02/02/2023 16:37 WG1998813
Ethylbenzene 2650 27.4 200 200 02/02/2023 16:37 WG1998813
Hexachloro-1,3-butadiene U 67.4 200 200 02/02/2023 16:37 WG1998813
Isopropylbenzene 84.1 J 21.0 200 200 02/02/2023 16:37 WG1998813
p-Isopropyltoluene U 24.0 200 200 02/02/2023 16:37 WG1998813
2-Butanone (MEK)U 238 2000 200 02/02/2023 16:37 WG1998813
Methylene Chloride U 86.0 1000 200 02/02/2023 16:37 WG1998813
4-Methyl-2-pentanone (MIBK)U 95.6 2000 200 02/02/2023 16:37 WG1998813
Methyl tert-butyl ether 5800 20.2 200 200 02/02/2023 16:37 WG1998813
Naphthalene 499 J 200 1000 200 02/02/2023 16:37 WG1998813
n-Propylbenzene 219 19.9 200 200 02/02/2023 16:37 WG1998813
Styrene 55.2 J 23.6 200 200 02/02/2023 16:37 WG1998813
1,1,1,2-Tetrachloroethane U 29.4 200 200 02/02/2023 16:37 WG1998813
1,1,2,2-Tetrachloroethane U 26.6 200 200 02/02/2023 16:37 WG1998813
Tetrachloroethene U 60.0 200 200 02/02/2023 16:37 WG1998813
Toluene 291 55.6 200 200 02/02/2023 16:37 WG1998813
1,2,3-Trichlorobenzene U 46.0 200 200 02/02/2023 16:37 WG1998813
1,2,4-Trichlorobenzene U 96.2 200 200 02/02/2023 16:37 WG1998813
1,1,1-Trichloroethane U 29.8 200 200 02/02/2023 16:37 WG1998813
1,1,2-Trichloroethane U 31.6 200 200 02/02/2023 16:37 WG1998813
Trichloroethene U 38.0 200 200 02/02/2023 16:37 WG1998813
Trichlorofluoromethane U 32.0 1000 200 02/02/2023 16:37 WG1998813
1,2,3-Trichloropropane U 47.4 500 200 02/02/2023 16:37 WG1998813
1,2,4-Trimethylbenzene 927 64.4 200 200 02/02/2023 16:37 WG1998813
1,3,5-Trimethylbenzene 230 20.8 200 200 02/02/2023 16:37 WG1998813
Vinyl chloride U 46.8 200 200 02/02/2023 16:37 WG1998813
o-Xylene 106 J 34.8 200 200 02/02/2023 16:37 WG1998813
m&p-Xylenes 1790 86.0 400 200 02/02/2023 16:37 WG1998813
(S) Toluene-d8 94.2 80.0-120 02/02/2023 16:37 WG1998813
(S) 4-Bromofluorobenzene 85.7 77.0-126 02/02/2023 16:37 WG1998813
(S) 1,2-Dichloroethane-d4 107 70.0-130 02/02/2023 16:37 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 21:59 7 of 34
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 22:11 7 of 34
SAMPLE RESULTS - 02
L1579828
DUP-01-W-20230125
Collected date/time: 01/25/23 00:00
Calculated Results
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferric Iron U 18.0 100 1 01/30/2023 10:58 WG1996029
Organic Nitrogen 204 J 117 250 1 01/30/2023 22:46 WG1996518
Wet Chemistry by Method 2320 B-2011/4500CO2 D-2011
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/l ug/l date / time
Alkalinity 309000 20000 1 02/06/2023 08:27 WG1998655
Free Carbon Dioxide 78900 B T8 20000 1 02/06/2023 08:27 WG1998655
Sample Narrative:
L1579828-02 WG1998655: Endpoint pH 4.5 Headspace
Wet Chemistry by Method 350.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ammonia Nitrogen U 117 250 1 01/29/2023 12:35 WG1996518
Wet Chemistry by Method 3500Fe B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ferrous Iron 11700 T8 150 500 10 01/27/2023 14:55 WG1995970
Wet Chemistry by Method 351.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Kjeldahl Nitrogen, TKN 204 J 140 250 1 01/30/2023 22:46 WG1996244
Wet Chemistry by Method 353.2
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate-Nitrite U 250 500 5 02/06/2023 12:56 WG2000697
Sample Narrative:
L1579828-02 WG2000697: Dilution due to matrix.
Wet Chemistry by Method 410.4
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
COD 259000 11700 20000 1 01/27/2023 21:27 WG1996209
Wet Chemistry by Method 4500S2 D-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Sulfide U 25.0 50.0 1 01/30/2023 10:02 WG1996774
Wet Chemistry by Method 5210 B-2016
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/l mg/l date / time
BOD 12.1 K5 K6 K9 T8 1.00 1 02/01/2023 09:20 WG1995769
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 21:59 8 of 34
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 22:11 8 of 34
SAMPLE RESULTS - 02
L1579828
DUP-01-W-20230125
Collected date/time: 01/25/23 00:00
Wet Chemistry by Method 9056A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Nitrate 271 T8 48.0 100 1 01/27/2023 14:46 WG1995863
Nitrite U T8 42.0 100 1 01/27/2023 14:46 WG1995863
Sulfate U T8 594 5000 1 01/27/2023 14:46 WG1995863
Wet Chemistry by Method 9060A
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
TOC (Total Organic Carbon)50500 102 1000 1 01/28/2023 21:14 WG1995911
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Iron 11200 18.0 100 1 01/30/2023 10:58 WG1996029
Manganese 12800 4.67 50.0 5 01/30/2023 13:51 WG1996029
Volatile Organic Compounds (GC) by Method RSK175
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Methane 184 2.91 10.0 1 01/27/2023 15:52 WG1995909
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 1130 5000 100 02/02/2023 16:57 WG1998813
Acrolein U 254 5000 100 02/02/2023 16:57 WG1998813
Acrylonitrile U 67.1 1000 100 02/02/2023 16:57 WG1998813
Benzene 11600 9.41 100 100 02/02/2023 16:57 WG1998813
Bromobenzene U 11.8 100 100 02/02/2023 16:57 WG1998813
Bromodichloromethane U 13.6 100 100 02/02/2023 16:57 WG1998813
Bromoform U 12.9 100 100 02/02/2023 16:57 WG1998813
Bromomethane U 60.5 500 100 02/02/2023 16:57 WG1998813
n-Butylbenzene 15.8 J 15.7 100 100 02/02/2023 16:57 WG1998813
sec-Butylbenzene U 12.5 100 100 02/02/2023 16:57 WG1998813
tert-Butylbenzene U 12.7 100 100 02/02/2023 16:57 WG1998813
Carbon tetrachloride U 12.8 100 100 02/02/2023 16:57 WG1998813
Chlorobenzene U 11.6 100 100 02/02/2023 16:57 WG1998813
Chlorodibromomethane U 14.0 100 100 02/02/2023 16:57 WG1998813
Chloroethane U 19.2 500 100 02/02/2023 16:57 WG1998813
Chloroform U 11.1 500 100 02/02/2023 16:57 WG1998813
Chloromethane U 96.0 250 100 02/02/2023 16:57 WG1998813
2-Chlorotoluene U 10.6 100 100 02/02/2023 16:57 WG1998813
4-Chlorotoluene U 11.4 100 100 02/02/2023 16:57 WG1998813
1,2-Dibromo-3-Chloropropane U 27.6 500 100 02/02/2023 16:57 WG1998813
1,2-Dibromoethane U 12.6 100 100 02/02/2023 16:57 WG1998813
Dibromomethane U 12.2 100 100 02/02/2023 16:57 WG1998813
1,2-Dichlorobenzene U 10.7 100 100 02/02/2023 16:57 WG1998813
1,3-Dichlorobenzene U 11.0 100 100 02/02/2023 16:57 WG1998813
1,4-Dichlorobenzene U 12.0 100 100 02/02/2023 16:57 WG1998813
Dichlorodifluoromethane U 37.4 500 100 02/02/2023 16:57 WG1998813
1,1-Dichloroethane U 10.0 100 100 02/02/2023 16:57 WG1998813
1,2-Dichloroethane U 8.19 100 100 02/02/2023 16:57 WG1998813
1,1-Dichloroethene U 18.8 100 100 02/02/2023 16:57 WG1998813
cis-1,2-Dichloroethene U 12.6 100 100 02/02/2023 16:57 WG1998813
trans-1,2-Dichloroethene U 14.9 100 100 02/02/2023 16:57 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 21:59 9 of 34
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 22:11 9 of 34
SAMPLE RESULTS - 02
L1579828
DUP-01-W-20230125
Collected date/time: 01/25/23 00:00
Volatile Organic Compounds (GC/MS) by Method 6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
1,2-Dichloropropane U 14.9 100 100 02/02/2023 16:57 WG1998813
1,1-Dichloropropene U 14.2 100 100 02/02/2023 16:57 WG1998813
1,3-Dichloropropane U 11.0 100 100 02/02/2023 16:57 WG1998813
2,2-Dichloropropane U 16.1 100 100 02/02/2023 16:57 WG1998813
Di-isopropyl ether 42.1 J 10.5 100 100 02/02/2023 16:57 WG1998813
Ethylbenzene 2620 13.7 100 100 02/02/2023 16:57 WG1998813
Hexachloro-1,3-butadiene U 33.7 100 100 02/02/2023 16:57 WG1998813
Isopropylbenzene 85.8 J 10.5 100 100 02/02/2023 16:57 WG1998813
p-Isopropyltoluene U 12.0 100 100 02/02/2023 16:57 WG1998813
2-Butanone (MEK)U 119 1000 100 02/02/2023 16:57 WG1998813
Methylene Chloride U 43.0 500 100 02/02/2023 16:57 WG1998813
4-Methyl-2-pentanone (MIBK)U 47.8 1000 100 02/02/2023 16:57 WG1998813
Methyl tert-butyl ether 5710 10.1 100 100 02/02/2023 16:57 WG1998813
Naphthalene 543 100 500 100 02/02/2023 16:57 WG1998813
n-Propylbenzene 216 9.93 100 100 02/02/2023 16:57 WG1998813
Styrene 48.6 J 11.8 100 100 02/02/2023 16:57 WG1998813
1,1,1,2-Tetrachloroethane U 14.7 100 100 02/02/2023 16:57 WG1998813
1,1,2,2-Tetrachloroethane U 13.3 100 100 02/02/2023 16:57 WG1998813
Tetrachloroethene U 30.0 100 100 02/02/2023 16:57 WG1998813
Toluene 270 27.8 100 100 02/02/2023 16:57 WG1998813
1,2,3-Trichlorobenzene U 23.0 100 100 02/02/2023 16:57 WG1998813
1,2,4-Trichlorobenzene U 48.1 100 100 02/02/2023 16:57 WG1998813
1,1,1-Trichloroethane U 14.9 100 100 02/02/2023 16:57 WG1998813
1,1,2-Trichloroethane U 15.8 100 100 02/02/2023 16:57 WG1998813
Trichloroethene U 19.0 100 100 02/02/2023 16:57 WG1998813
Trichlorofluoromethane U 16.0 500 100 02/02/2023 16:57 WG1998813
1,2,3-Trichloropropane U 23.7 250 100 02/02/2023 16:57 WG1998813
1,2,4-Trimethylbenzene 949 32.2 100 100 02/02/2023 16:57 WG1998813
1,3,5-Trimethylbenzene 231 10.4 100 100 02/02/2023 16:57 WG1998813
Vinyl chloride U 23.4 100 100 02/02/2023 16:57 WG1998813
o-Xylene 97.7 J 17.4 100 100 02/02/2023 16:57 WG1998813
m&p-Xylenes 1680 43.0 200 100 02/02/2023 16:57 WG1998813
(S) Toluene-d8 91.4 80.0-120 02/02/2023 16:57 WG1998813
(S) 4-Bromofluorobenzene 84.9 77.0-126 02/02/2023 16:57 WG1998813
(S) 1,2-Dichloroethane-d4 106 70.0-130 02/02/2023 16:57 WG1998813
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 21:59 10 of 34
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Arcadis - Chevron - NC 30064349 L1579828 02/06/23 22:11 10 of 34
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