WI-29241_48413_CA_RPTS_20230324

March 24, 2023

James Washburn
S.T. Wooten Corporation
P.O. Box 2408, Wilson, NC 27894

Reference: Well Sampling Letter Report
S.T. Wooten Corporation - Broad Creek
3931 NC Hwy 24
Newport, Carteret County, North Carolina 28570
Incident #48413; Facility ID #00-0-0000034888

Dear Mr. Washburn:

Contained herein is a report summarizing groundwater assessment activities for the above
referenced incident. Specifically, (1) existing monitoring wells were gauged and/or sampled to
assess for current groundwater conditions. Figure 1 illustrates the location of the project site on
a USGS topographic map, and Figure 2 illustrates the approximate locations of the USTs,
dispensers and monitoring well at this facility.

On February 4, 2023, HN Engineering mobilized to the site to collect water samples from MW-
1. Figure 3 illustrates the location of monitoring well MW-1. Prior to sampling, the well was
developed by removal of 3 well volumes via hand baler. Following development, samples were
obtained from the disposable baler. The water samples were submitted to Pace Analytical, Inc.
for analyses according to Method 602, 625 + TICs, and MADEP VPH/EPH as approved by the
NCDEQ to assess for dissolved diesel constituents. The water samples were obtained as
specified in the collection, preservation, and handling section of the specific method. Each
container was labeled with sample location, analyses to be performed, time, date, and the
sampler's name. They were then placed in a cooler and chilled with ice to approximately 4oC in
preparation for transportation to the analytical laboratory utilizing EPA approved chain of
custody procedures.

Laboratory analytical results failed to indicate the presence of any 602/625/VPH/EPH target
compounds exceeding laboratory detection limits. The 625 library search indicated TICs at a
total concentration of 68.3 ug/l; however, there are no 2L Standards for TICs. Table 1 contains
current & historical groundwater analytical results for samples obtained from this release site.
Attachment A contains a copy of the laboratory analytical report for the groundwater samples
collected on February 4, 2023.

Based on the data obtained from the current groundwater assessment, Henry Nemargut
Engineering Services recommends that a Notice of No Further Action be issued for the spill
bucket release at this facility. It is also recommended that the monitoring well be properly
abandoned following closure of this incident by the NCDEQ.

Mr. Washburn, please contact me at [phone] if you have questions regarding this report.

Sincerely,
Henry Nemargut, P.E.
Henry Nemargut Engineering Services

FIGURES

FIGURE 1: PROJECT LOCATION - USGS TOPO MAP
Project Location
IHHW
PHWHUV


Diesel Dispensers
Locations
FIGURE 2: SITE LAYOUT, UST & DISPENSER LOCATIONS
Diesel USTs
Location










 









FIGURE 3: SUBSURFACE
UTILITIES MAP
4K Off-Rd Cmpt
8K Hwy Diesel Cmpt
Hwy Diesel Pump
Off-Rd Diesel Pump
Electrical Conduit
Electrical Conduit
MW-1

TABLE

Constituent MW-1 MW-1 TW-1 GCL 2L Standard

Date 6/4/2022 2/4/2023 2/24/2017
Standard Method 602 (ug/L)
Benzene BDL BDL BDL 5,000 1
Toluene BDL BDL BDL 260,000 600
Ethylbenzene BDL BDL BDL 80,000 600
Xylenes (total) BDL BDL BDL 50,000 500
BTEX (total) BDL BDL BDL NSE NSE
p-Isopropyltoluene BDL BDL BDL 11,700 25
Isopropylbenzene BDL BDL BDL 30,500 70
Diisopropyl Ether (DIPE) BDL BDL BDL 70,000 70
1,2-Dibromoethane (EDB) BDL BDL BDL 50 0.02
1,2-Dichlorooethane BDL BDL BDL 400 0.4
Naphthalene BDL BDL BDL 6,000 6
n-propylbenzene BDL BDL BDL 26,100 70
n-butylbenzene BDL BDL BDL 5,900 70
sec-butylbenzene BDL BDL BDL 8,800 70
Styrene BDL BDL BDL 70,000 70
Methyl-tert-butyl-ether (MTBE) BDL BDL BDL 20,000 20
1,2,4-Trimethylbenzene BDL BDL BDL 28,500 400
1,3,5-Trimethylbenzene BDL BDL BDL 24,100 400
Total 6200B 0 0 0 15,000 15
Method 625 (ug/L)
Pyrene BDL BDL BDL 200 200
Naphthalene BDL BDL BDL 6,000 6
1-Methylnaphthalene BDL BDL BDL 1,000 1
2-Methylnaphthalene BDL BDL BDL 125,000 30
TOTAL TICs 113.4 68.9 77.2 NSE NSE
MADEP Aliphatic Fraction Classes (ug/L)
C5-C8 Volatile Aliphatics BDL BDL BDL NSE 400
C9-C12 Volatile Aliphatics BDL BDL BDL NSE NSE
C9-C18 Extractable Aliphatics BDL BDL BDL NSE 700
C9-C18 Aliphatics (total) BDL BDL BDL NSE 700
C19-C36 Extractable Aliphatics BDL BDL BDL NSE 10,000
MADEP Aromatic Fraction Classes (ug/L)
C9-C10 Volatile Aromatics BDL BDL BDL NSE NSE
C11-C22 Extractable Aromatics BDL BDL BDL NSE NSE
C9-C22 Aromatics (total) BDL BDL BDL NSE 200
NR = Analyses Not Requested
BDL = Below Detection Limits
NSE = No Standard Established
TABLE 1
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
S.T. Wooten Corporation
3931 NC Hwy 24, Newport, NC 28570

ATTACHMENT A

ANALYTICAL REPORT

#=CL#
February 15, 2023
LIMS USE: FR - HENRY NEMARGUT
LIMS OBJECT ID: 92650720
92650720
Project:
Pace Project No.:
RE:
Henry Nemargut
Henry Nemargut Engineering
2211 Chestnut Street
Wilmington, NC 28405
ST WOOTEN-BROAD CREEK
Dear Henry Nemargut:
Enclosed are the analytical results for sample(s) received by the laboratory on February 06, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 40
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: AI30792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TN003
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TN002
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LAO00356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A2LA 2926.01
A2LA-ISO 17025 Certification #: 1461.01
A2LA-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 40
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Lab ID Sample ID Matrix Date Collected Date Received
92650720001 MW1 Water 02/04/23 09:25 02/06/23 16:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 40
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92650720001 MW1 MADEP VPH 6 PANACG
EPA 625.1 67 PASI-CPKS
SM 6200B 69 PASI-CLMB
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 40
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92650720001 MW1
4.089:Unknown 5.5J ug/L 02/11/23 03:16EPA 625.1
5.611:Unknown 6.9J ug/L 02/11/23 03:16EPA 625.1
5.959:Unknown 15.5J ug/L 02/11/23 03:16EPA 625.1
6.232:Unknown 6.7J ug/L 02/11/23 03:16EPA 625.1
6.251:Unknown 10.0J ug/L 02/11/23 03:16EPA 625.1
12.228:Unknown 4.4J ug/L 02/11/23 03:16EPA 625.1
13.304:Unknown 6.3J ug/L 02/11/23 03:16EPA 625.1
13.676:Unknown 4.9J ug/L 02/11/23 03:16EPA 625.1
14.396:Tetraethylene glycol mo 8.7J ug/L 02/11/23 03:16 NEPA 625.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Sample:MW1 Lab ID:92650720001 Collected:02/04/23 09:25 Received:02/06/23 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND ug/L 02/11/23 05:4102/11/23 05:411001
Aliphatic (C09-C12)ND ug/L 02/11/23 05:4102/11/23 05:411001
Aromatic (C09-C10),Unadjusted ND ug/L 02/11/23 05:41 TPHC9C10A02/11/23 05:411001
Total VPH ND ug/L 02/11/23 05:41 VPH02/11/23 05:411001
Surrogates
2,5-Dibromotoluene (FID)98.9 %02/11/23 05:41 615-59-8FID02/11/23 05:4170.0-130 1
2,5-Dibromotoluene (PID)93.9 %02/11/23 05:41 615-59-8PID02/11/23 05:4170.0-130 1
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 02/11/23 03:16 83-32-902/09/23 15:254.2 1
Acenaphthylene ND ug/L 02/11/23 03:16 208-96-802/09/23 15:254.2 1
Anthracene ND ug/L 02/11/23 03:16 120-12-702/09/23 15:254.2 1
Benzo(a)anthracene ND ug/L 02/11/23 03:16 56-55-302/09/23 15:254.2 1
Benzo(a)pyrene ND ug/L 02/11/23 03:16 50-32-802/09/23 15:254.2 1
Benzo(b)fluoranthene ND ug/L 02/11/23 03:16 205-99-202/09/23 15:254.2 1
Benzo(g,h,i)perylene ND ug/L 02/11/23 03:16 191-24-202/09/23 15:254.2 1
Benzo(k)fluoranthene ND ug/L 02/11/23 03:16 207-08-902/09/23 15:254.2 1
4-Bromophenylphenyl ether ND ug/L 02/11/23 03:16 101-55-302/09/23 15:254.2 1
Butylbenzylphthalate ND ug/L 02/11/23 03:16 85-68-702/09/23 15:254.2 1
4-Chloro-3-methylphenol ND ug/L 02/11/23 03:16 59-50-702/09/23 15:254.2 1
bis(2-Chloroethoxy)methane ND ug/L 02/11/23 03:16 111-91-102/09/23 15:258.3 1
bis(2-Chloroethyl) ether ND ug/L 02/11/23 03:16 111-44-402/09/23 15:254.2 1
2-Chloronaphthalene ND ug/L 02/11/23 03:16 91-58-702/09/23 15:254.2 1
2-Chlorophenol ND ug/L 02/11/23 03:16 95-57-802/09/23 15:254.2 1
4-Chlorophenylphenyl ether ND ug/L 02/11/23 03:16 7005-72-302/09/23 15:254.2 1
Chrysene ND ug/L 02/11/23 03:16 218-01-902/09/23 15:254.2 1
Dibenz(a,h)anthracene ND ug/L 02/11/23 03:16 53-70-302/09/23 15:254.2 1
3,3'-Dichlorobenzidine ND ug/L 02/11/23 03:16 91-94-102/09/23 15:258.3 1
2,4-Dichlorophenol ND ug/L 02/11/23 03:16 120-83-202/09/23 15:254.2 1
Diethylphthalate ND ug/L 02/11/23 03:16 84-66-202/09/23 15:254.2 1
2,4-Dimethylphenol ND ug/L 02/11/23 03:16 105-67-9 L102/09/23 15:258.3 1
Dimethylphthalate ND ug/L 02/11/23 03:16 131-11-302/09/23 15:254.2 1
Di-n-butylphthalate ND ug/L 02/11/23 03:16 84-74-202/09/23 15:254.2 1
4,6-Dinitro-2-methylphenol ND ug/L 02/11/23 03:16 534-52-102/09/23 15:258.3 1
2,4-Dinitrophenol ND ug/L 02/11/23 03:16 51-28-502/09/23 15:2541.7 1
2,4-Dinitrotoluene ND ug/L 02/11/23 03:16 121-14-202/09/23 15:254.2 1
2,6-Dinitrotoluene ND ug/L 02/11/23 03:16 606-20-202/09/23 15:254.2 1
Di-n-octylphthalate ND ug/L 02/11/23 03:16 117-84-002/09/23 15:254.2 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/11/23 03:16 117-81-702/09/23 15:254.2 1
Fluoranthene ND ug/L 02/11/23 03:16 206-44-002/09/23 15:254.2 1
Fluorene ND ug/L 02/11/23 03:16 86-73-702/09/23 15:254.2 1
Hexachloro-1,3-butadiene ND ug/L 02/11/23 03:16 87-68-302/09/23 15:254.2 1
Hexachlorobenzene ND ug/L 02/11/23 03:16 118-74-102/09/23 15:254.2 1
Hexachlorocyclopentadiene ND ug/L 02/11/23 03:16 77-47-402/09/23 15:258.3 1
Hexachloroethane ND ug/L 02/11/23 03:16 67-72-102/09/23 15:254.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Sample:MW1 Lab ID:92650720001 Collected:02/04/23 09:25 Received:02/06/23 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Indeno(1,2,3-cd)pyrene ND ug/L 02/11/23 03:16 193-39-502/09/23 15:254.2 1
Isophorone ND ug/L 02/11/23 03:16 78-59-102/09/23 15:258.3 1
Naphthalene ND ug/L 02/11/23 03:16 91-20-302/09/23 15:254.2 1
Nitrobenzene ND ug/L 02/11/23 03:16 98-95-302/09/23 15:254.2 1
2-Nitrophenol ND ug/L 02/11/23 03:16 88-75-502/09/23 15:254.2 1
4-Nitrophenol ND ug/L 02/11/23 03:16 100-02-702/09/23 15:258.3 1
N-Nitrosodimethylamine ND ug/L 02/11/23 03:16 62-75-902/09/23 15:254.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/11/23 03:16 621-64-702/09/23 15:254.2 1
N-Nitrosodiphenylamine ND ug/L 02/11/23 03:16 86-30-602/09/23 15:258.3 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/11/23 03:16 108-60-102/09/23 15:254.2 1
Pentachlorophenol ND ug/L 02/11/23 03:16 87-86-502/09/23 15:258.3 1
Phenanthrene ND ug/L 02/11/23 03:16 85-01-802/09/23 15:254.2 1
Phenol ND ug/L 02/11/23 03:16 108-95-202/09/23 15:254.2 1
Pyrene ND ug/L 02/11/23 03:16 129-00-002/09/23 15:254.2 1
1,2,4-Trichlorobenzene ND ug/L 02/11/23 03:16 120-82-102/09/23 15:254.2 1
2,4,6-Trichlorophenol ND ug/L 02/11/23 03:16 88-06-202/09/23 15:258.3 1
Surrogates
Nitrobenzene-d5 (S)76 %02/11/23 03:16 4165-60-002/09/23 15:2510-120 1
2-Fluorobiphenyl (S)44 %02/11/23 03:16 321-60-802/09/23 15:2515-120 1
Terphenyl-d14 (S)140 %02/11/23 03:16 1718-51-0 S302/09/23 15:2511-131 1
Phenol-d6 (S)58 %02/11/23 03:16 13127-88-302/09/23 15:2510-120 1
2-Fluorophenol (S)64 %02/11/23 03:16 367-12-402/09/23 15:2510-120 1
2,4,6-Tribromophenol (S)114 %02/11/23 03:16 118-79-602/09/23 15:2510-137 1
Tentatively Identified Compounds
Unknown 5.5J ug/L 02/11/23 03:1602/09/23 15:251
Unknown 6.9J ug/L 02/11/23 03:1602/09/23 15:251
Unknown 15.5J ug/L 02/11/23 03:1602/09/23 15:251
Unknown 6.7J ug/L 02/11/23 03:1602/09/23 15:251
Unknown 10.0J ug/L 02/11/23 03:1602/09/23 15:251
Unknown 4.4J ug/L 02/11/23 03:1602/09/23 15:251
Unknown 6.3J ug/L 02/11/23 03:1602/09/23 15:251
Unknown 4.9J ug/L 02/11/23 03:1602/09/23 15:251
Tetraethylene glycol mo 8.7J ug/L 02/11/23 03:16 5274-68-0 N02/09/23 15:251
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol ND ug/L 02/08/23 16:09 75-85-41001
tert-Amylmethyl ether ND ug/L 02/08/23 16:09 994-05-810.0 1
Benzene ND ug/L 02/08/23 16:09 71-43-20.50 1
Bromobenzene ND ug/L 02/08/23 16:09 108-86-10.50 1
Bromochloromethane ND ug/L 02/08/23 16:09 74-97-50.50 1
Bromodichloromethane ND ug/L 02/08/23 16:09 75-27-40.50 1
Bromoform ND ug/L 02/08/23 16:09 75-25-20.50 1
Bromomethane ND ug/L 02/08/23 16:09 74-83-95.0 1
tert-Butyl Alcohol ND ug/L 02/08/23 16:09 75-65-050.0 1
n-Butylbenzene ND ug/L 02/08/23 16:09 104-51-80.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Sample:MW1 Lab ID:92650720001 Collected:02/04/23 09:25 Received:02/06/23 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
sec-Butylbenzene ND ug/L 02/08/23 16:09 135-98-80.50 1
tert-Butylbenzene ND ug/L 02/08/23 16:09 98-06-60.50 1
tert-Butyl Formate ND ug/L 02/08/23 16:09 762-75-450.0 1
Carbon tetrachloride ND ug/L 02/08/23 16:09 56-23-50.50 1
Chlorobenzene ND ug/L 02/08/23 16:09 108-90-70.50 1
Chloroethane ND ug/L 02/08/23 16:09 75-00-31.0 1
Chloroform ND ug/L 02/08/23 16:09 67-66-30.50 1
Chloromethane ND ug/L 02/08/23 16:09 74-87-31.0 1
2-Chlorotoluene ND ug/L 02/08/23 16:09 95-49-80.50 1
4-Chlorotoluene ND ug/L 02/08/23 16:09 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 02/08/23 16:09 96-12-81.0 1
Dibromochloromethane ND ug/L 02/08/23 16:09 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 02/08/23 16:09 106-93-40.50 1
Dibromomethane ND ug/L 02/08/23 16:09 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 02/08/23 16:09 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 02/08/23 16:09 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 02/08/23 16:09 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 02/08/23 16:09 75-71-80.50 1
1,1-Dichloroethane ND ug/L 02/08/23 16:09 75-34-30.50 1
1,2-Dichloroethane ND ug/L 02/08/23 16:09 107-06-20.50 1
1,1-Dichloroethene ND ug/L 02/08/23 16:09 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 02/08/23 16:09 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 02/08/23 16:09 156-60-50.50 1
1,2-Dichloropropane ND ug/L 02/08/23 16:09 78-87-50.50 1
1,3-Dichloropropane ND ug/L 02/08/23 16:09 142-28-90.50 1
2,2-Dichloropropane ND ug/L 02/08/23 16:09 594-20-70.50 1
1,1-Dichloropropene ND ug/L 02/08/23 16:09 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 02/08/23 16:09 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 02/08/23 16:09 10061-02-60.50 1
Diisopropyl ether ND ug/L 02/08/23 16:09 108-20-30.50 1
Ethanol ND ug/L 02/08/23 16:09 64-17-52001
Ethylbenzene ND ug/L 02/08/23 16:09 100-41-40.50 1
Ethyl-tert-butyl ether ND ug/L 02/08/23 16:09 637-92-310.0 1
Hexachloro-1,3-butadiene ND ug/L 02/08/23 16:09 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 02/08/23 16:09 98-82-80.50 1
Methylene Chloride ND ug/L 02/08/23 16:09 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 02/08/23 16:09 1634-04-40.50 1
Naphthalene ND ug/L 02/08/23 16:09 91-20-32.0 1
n-Propylbenzene ND ug/L 02/08/23 16:09 103-65-10.50 1
Styrene ND ug/L 02/08/23 16:09 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 02/08/23 16:09 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 02/08/23 16:09 79-34-50.50 1
Tetrachloroethene ND ug/L 02/08/23 16:09 127-18-40.50 1
Toluene ND ug/L 02/08/23 16:09 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 02/08/23 16:09 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 02/08/23 16:09 120-82-12.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Sample:MW1 Lab ID:92650720001 Collected:02/04/23 09:25 Received:02/06/23 16:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,1-Trichloroethane ND ug/L 02/08/23 16:09 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 02/08/23 16:09 79-00-50.50 1
Trichloroethene ND ug/L 02/08/23 16:09 79-01-60.50 1
Trichlorofluoromethane ND ug/L 02/08/23 16:09 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 02/08/23 16:09 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 02/08/23 16:09 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 02/08/23 16:09 108-67-80.50 1
Vinyl chloride ND ug/L 02/08/23 16:09 75-01-41.0 1
m&p-Xylene ND ug/L 02/08/23 16:09 179601-23-11.0 1
o-Xylene ND ug/L 02/08/23 16:09 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)92 %02/08/23 16:09 17060-07-070-130 1
4-Bromofluorobenzene (S)102 %02/08/23 16:09 460-00-470-130 1
Toluene-d8 (S)104 %02/08/23 16:09 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
2004012
KS LRH/MADEPV/VPH
MADEP VPH
MADEPV
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92650720001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3890460-2
Associated Lab Samples:92650720001
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 100 02/10/23 19:18
Aliphatic (C09-C12)ug/L ND 100 02/10/23 19:18
Aromatic (C09-C10),Unadjusted ug/L ND 100 02/10/23 19:18
Total VPH ug/L ND 100 02/10/23 19:18
2,5-Dibromotoluene (FID)%89.1 70.0-130 02/10/23 19:18
2,5-Dibromotoluene (PID)%84.8 70.0-130 02/10/23 19:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3890460-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3890460-3
Aliphatic (C05-C08)ug/L 12701200 106 70.0-1301021220 4.02 25
Aliphatic (C09-C12)ug/L 12901400 92.1 70.0-13087.11220 5.58 25
Aromatic (C09-C10),Unadjusted ug/L 182200 91.0 70.0-13087.5175 3.92 25
Total VPH ug/L 27402800 97.9 70.0-13093.62620 4.48 25
2,5-Dibromotoluene (FID)%90.1 70.0-130100
2,5-Dibromotoluene (PID)%86.3 70.0-13097.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
754639
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92650720001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3920600
Associated Lab Samples:92650720001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/08/23 15:51
1,1,1-Trichloroethane ug/L ND 0.50 02/08/23 15:51
1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/08/23 15:51
1,1,2-Trichloroethane ug/L ND 0.50 02/08/23 15:51
1,1-Dichloroethane ug/L ND 0.50 02/08/23 15:51
1,1-Dichloroethene ug/L ND 0.50 02/08/23 15:51
1,1-Dichloropropene ug/L ND 0.50 02/08/23 15:51
1,2,3-Trichlorobenzene ug/L ND 2.0 02/08/23 15:51
1,2,3-Trichloropropane ug/L ND 0.50 02/08/23 15:51
1,2,4-Trichlorobenzene ug/L ND 2.0 02/08/23 15:51
1,2,4-Trimethylbenzene ug/L ND 0.50 02/08/23 15:51
1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/08/23 15:51
1,2-Dibromoethane (EDB)ug/L ND 0.50 02/08/23 15:51
1,2-Dichlorobenzene ug/L ND 0.50 02/08/23 15:51
1,2-Dichloroethane ug/L ND 0.50 02/08/23 15:51
1,2-Dichloropropane ug/L ND 0.50 02/08/23 15:51
1,3,5-Trimethylbenzene ug/L ND 0.50 02/08/23 15:51
1,3-Dichlorobenzene ug/L ND 0.50 02/08/23 15:51
1,3-Dichloropropane ug/L ND 0.50 02/08/23 15:51
1,4-Dichlorobenzene ug/L ND 0.50 02/08/23 15:51
2,2-Dichloropropane ug/L ND 0.50 02/08/23 15:51
2-Chlorotoluene ug/L ND 0.50 02/08/23 15:51
4-Chlorotoluene ug/L ND 0.50 02/08/23 15:51
Benzene ug/L ND 0.50 02/08/23 15:51
Bromobenzene ug/L ND 0.50 02/08/23 15:51
Bromochloromethane ug/L ND 0.50 02/08/23 15:51
Bromodichloromethane ug/L ND 0.50 02/08/23 15:51
Bromoform ug/L ND 0.50 02/08/23 15:51
Bromomethane ug/L ND 5.0 02/08/23 15:51
Carbon tetrachloride ug/L ND 0.50 02/08/23 15:51
Chlorobenzene ug/L ND 0.50 02/08/23 15:51
Chloroethane ug/L ND 1.0 02/08/23 15:51
Chloroform ug/L ND 0.50 02/08/23 15:51
Chloromethane ug/L ND 1.0 02/08/23 15:51
cis-1,2-Dichloroethene ug/L ND 0.50 02/08/23 15:51
cis-1,3-Dichloropropene ug/L ND 0.50 02/08/23 15:51
Dibromochloromethane ug/L ND 0.50 02/08/23 15:51
Dibromomethane ug/L ND 0.50 02/08/23 15:51
Dichlorodifluoromethane ug/L ND 0.50 02/08/23 15:51
Diisopropyl ether ug/L ND 0.50 02/08/23 15:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3920600
Associated Lab Samples:92650720001
Matrix:Water
Analyzed
Ethanol ug/L ND 200 02/08/23 15:51
Ethyl-tert-butyl ether ug/L ND 10.0 02/08/23 15:51
Ethylbenzene ug/L ND 0.50 02/08/23 15:51
Hexachloro-1,3-butadiene ug/L ND 2.0 02/08/23 15:51
Isopropylbenzene (Cumene)ug/L ND 0.50 02/08/23 15:51
m&p-Xylene ug/L ND 1.0 02/08/23 15:51
Methyl-tert-butyl ether ug/L ND 0.50 02/08/23 15:51
Methylene Chloride ug/L ND 2.0 02/08/23 15:51
n-Butylbenzene ug/L ND 0.50 02/08/23 15:51
n-Propylbenzene ug/L ND 0.50 02/08/23 15:51
Naphthalene ug/L ND 2.0 02/08/23 15:51
o-Xylene ug/L ND 0.50 02/08/23 15:51
sec-Butylbenzene ug/L ND 0.50 02/08/23 15:51
Styrene ug/L ND 0.50 02/08/23 15:51
tert-Amyl Alcohol ug/L ND 100 02/08/23 15:51
tert-Amylmethyl ether ug/L ND 10.0 02/08/23 15:51
tert-Butyl Alcohol ug/L ND 50.0 02/08/23 15:51
tert-Butyl Formate ug/L ND 50.0 02/08/23 15:51
tert-Butylbenzene ug/L ND 0.50 02/08/23 15:51
Tetrachloroethene ug/L ND 0.50 02/08/23 15:51
Toluene ug/L ND 0.50 02/08/23 15:51
trans-1,2-Dichloroethene ug/L ND 0.50 02/08/23 15:51
trans-1,3-Dichloropropene ug/L ND 0.50 02/08/23 15:51
Trichloroethene ug/L ND 0.50 02/08/23 15:51
Trichlorofluoromethane ug/L ND 1.0 02/08/23 15:51
Vinyl chloride ug/L ND 1.0 02/08/23 15:51
1,2-Dichloroethane-d4 (S)%92 70-130 02/08/23 15:51
4-Bromofluorobenzene (S)%104 70-130 02/08/23 15:51
Toluene-d8 (S)%102 70-130 02/08/23 15:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3920601LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.020 100 60-140
1,1,1-Trichloroethane ug/L 19.920 99 60-140
1,1,2,2-Tetrachloroethane ug/L 20.120 100 60-140
1,1,2-Trichloroethane ug/L 18.720 94 60-140
1,1-Dichloroethane ug/L 18.920 95 60-140
1,1-Dichloroethene ug/L 20.220 101 60-140
1,1-Dichloropropene ug/L 19.820 99 60-140
1,2,3-Trichlorobenzene ug/L 19.720 99 60-140
1,2,3-Trichloropropane ug/L 18.820 94 60-140
1,2,4-Trichlorobenzene ug/L 19.920 100 60-140
1,2,4-Trimethylbenzene ug/L 18.820 94 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3920601LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/L 19.120 96 60-140
1,2-Dibromoethane (EDB)ug/L 19.620 98 60-140
1,2-Dichlorobenzene ug/L 19.020 95 60-140
1,2-Dichloroethane ug/L 19.120 95 60-140
1,2-Dichloropropane ug/L 19.520 98 60-140
1,3,5-Trimethylbenzene ug/L 19.220 96 60-140
1,3-Dichlorobenzene ug/L 19.220 96 60-140
1,3-Dichloropropane ug/L 19.720 98 60-140
1,4-Dichlorobenzene ug/L 18.420 92 60-140
2,2-Dichloropropane ug/L 19.420 97 60-140
2-Chlorotoluene ug/L 18.820 94 60-140
4-Chlorotoluene ug/L 18.920 94 60-140
Benzene ug/L 18.520 92 60-140
Bromobenzene ug/L 18.620 93 60-140
Bromochloromethane ug/L 19.720 98 60-140
Bromodichloromethane ug/L 19.620 98 60-140
Bromoform ug/L 20.120 100 60-140
Bromomethane ug/L 12.220 61 60-140
Carbon tetrachloride ug/L 20.720 103 60-140
Chlorobenzene ug/L 19.120 95 60-140
Chloroethane ug/L 18.720 94 60-140
Chloroform ug/L 18.620 93 60-140
Chloromethane ug/L 15.920 79 60-140
cis-1,2-Dichloroethene ug/L 19.020 95 60-140
cis-1,3-Dichloropropene ug/L 19.920 100 60-140
Dibromochloromethane ug/L 20.320 101 60-140
Dibromomethane ug/L 19.520 98 60-140
Dichlorodifluoromethane ug/L 14.420 72 60-140
Diisopropyl ether ug/L 17.920 89 60-140
Ethanol ug/L 667800 83 60-140
Ethyl-tert-butyl ether ug/L 34.540 86 60-140
Ethylbenzene ug/L 19.420 97 60-140
Hexachloro-1,3-butadiene ug/L 20.120 100 60-140
Isopropylbenzene (Cumene)ug/L 19.220 96 60-140
m&p-Xylene ug/L 39.440 99 60-140
Methyl-tert-butyl ether ug/L 17.820 89 60-140
Methylene Chloride ug/L 20.020 100 60-140
n-Butylbenzene ug/L 19.520 98 60-140
n-Propylbenzene ug/L 18.620 93 60-140
Naphthalene ug/L 19.520 98 60-140
o-Xylene ug/L 19.220 96 60-140
sec-Butylbenzene ug/L 19.120 95 60-140
Styrene ug/L 19.420 97 60-140
tert-Amyl Alcohol ug/L 346400 86 60-140
tert-Amylmethyl ether ug/L 37.240 93 60-140
tert-Butyl Alcohol ug/L 174200 87 60-140
tert-Butyl Formate ug/L 143160 89 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3920601LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/L 15.520 77 60-140
Tetrachloroethene ug/L 18.920 94 60-140
Toluene ug/L 18.420 92 60-140
trans-1,2-Dichloroethene ug/L 19.920 100 60-140
trans-1,3-Dichloropropene ug/L 19.320 97 60-140
Trichloroethene ug/L 20.120 100 60-140
Trichlorofluoromethane ug/L 18.320 91 60-140
Vinyl chloride ug/L 17.220 86 60-140
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3920602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92650939001
3920603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 110 60-140113 3 3020ND21.9 22.7
1,1,1-Trichloroethane ug/L 20 117 60-140124 6 3020ND23.4 24.7
1,1,2,2-Tetrachloroethane ug/L 20 102 60-140111 9 3020ND20.3 22.2
1,1,2-Trichloroethane ug/L 20 107 60-140107 1 3020ND21.4 21.5
1,1-Dichloroethane ug/L 20 109 60-140114 5 3020ND21.7 22.7
1,1-Dichloroethene ug/L 20 118 60-140120 2 3020ND23.6 24.1
1,1-Dichloropropene ug/L 20 120 60-140124 3 3020ND24.0 24.8
1,2,3-Trichlorobenzene ug/L 20 97 60-140106 9 3020ND19.3 21.1
1,2,3-Trichloropropane ug/L 20 97 60-140102 5 3020ND19.4 20.5
1,2,4-Trichlorobenzene ug/L 20 96 60-140106 9 3020ND19.3 21.1
1,2,4-Trimethylbenzene ug/L 20 102 60-140105 3 3020ND20.4 21.1
1,2-Dibromo-3-
chloropropane ug/L 20 95 60-140106 12 3020ND19.0 21.3
1,2-Dibromoethane (EDB)ug/L 20 107 60-140113 5 3020ND21.3 22.5
1,2-Dichlorobenzene ug/L 20 98 60-140106 7 3020ND19.7 21.2
1,2-Dichloroethane ug/L 20 111 60-140113 2 3020ND22.2 22.7
1,2-Dichloropropane ug/L 20 108 60-140111 2 3020ND21.6 22.1
1,3,5-Trimethylbenzene ug/L 20 104 60-140109 4 3020ND20.9 21.7
1,3-Dichlorobenzene ug/L 20 103 60-140106 3 3020ND20.7 21.2
1,3-Dichloropropane ug/L 20 109 60-140114 4 3020ND21.8 22.7
1,4-Dichlorobenzene ug/L 20 99 60-140103 4 3020ND19.7 20.5
2,2-Dichloropropane ug/L 20 110 60-140114 4 3020ND21.9 22.9
2-Chlorotoluene ug/L 20 99 60-140104 5 3020ND19.7 20.7
4-Chlorotoluene ug/L 20 102 60-140104 2 3020ND20.4 20.8
Benzene ug/L 20 110 60-140109 1 3020ND22.0 21.7
Bromobenzene ug/L 20 102 60-140107 5 3020ND20.4 21.4
Bromochloromethane ug/L 20 113 60-140113 0 3020ND22.6 22.6
Bromodichloromethane ug/L 20 108 60-140111 3 3020ND21.6 22.2
Bromoform ug/L 20 104 60-140109 5 3020ND20.8 21.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3920602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92650939001
3920603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromomethane ug/L 20 60 60-14077 25 3020ND12.0 15.4
Carbon tetrachloride ug/L 20 120 60-140119 1 3020ND23.9 23.8
Chlorobenzene ug/L 20 106 60-140109 3 3020ND21.1 21.7
Chloroethane ug/L 20 107 60-140111 3 3020ND21.4 22.1
Chloroform ug/L 20 110 60-140112 2 3020ND22.0 22.4
Chloromethane ug/L 20 95 60-14099 4 3020ND19.0 19.8
cis-1,2-Dichloroethene ug/L 20 112 60-140115 3 3020ND22.4 23.0
cis-1,3-Dichloropropene ug/L 20 111 60-140111 1 3020ND22.1 22.3
Dibromochloromethane ug/L 20 109 60-140115 5 3020ND21.8 22.9
Dibromomethane ug/L 20 109 60-140109 0 3020ND21.8 21.9
Dichlorodifluoromethane ug/L 20 82 60-14083 1 3020ND16.4 16.5
Diisopropyl ether ug/L 20 106 60-140110 4 3020ND21.3 22.1
Ethanol ug/L 800 85 60-14094 9 30800ND682749
Ethyl-tert-butyl ether ug/L 40 104 60-140107 3 3040ND41.6 42.8
Ethylbenzene ug/L 20 107 60-140108 1 3020ND21.4 21.6
Hexachloro-1,3-butadiene ug/L 20 103 60-140112 9 3020ND20.5 22.5
Isopropylbenzene
(Cumene)ug/L 20 105 60-140106 0 3020ND21.0 21.1
m&p-Xylene ug/L 40 106 60-140108 1 3040ND42.5 43.1
Methyl-tert-butyl ether ug/L 20 100 60-140104 4 3020ND19.9 20.8
Methylene Chloride ug/L 20 106 60-140108 2 3020ND21.1 21.6
n-Butylbenzene ug/L 20 102 60-140112 9 3020ND20.5 22.3
n-Propylbenzene ug/L 20 100 60-140105 4 3020ND20.0 20.9
Naphthalene ug/L 20 90 60-140101 11 3020ND19.2 21.3
o-Xylene ug/L 20 107 60-140108 1 3020ND21.4 21.7
sec-Butylbenzene ug/L 20 103 60-140107 4 3020ND20.6 21.5
Styrene ug/L 20 105 60-140109 4 3020ND20.9 21.8
tert-Amyl Alcohol ug/L 400 95 60-14097 3 30400ND379389
tert-Amylmethyl ether ug/L 40 104 60-140107 2 3040ND41.7 42.6
tert-Butyl Alcohol ug/L 200 119 60-140124 4 30200ND238248
tert-Butyl Formate ug/L M1160260-1401 30160NDNDND
tert-Butylbenzene ug/L 20 87 60-14089 3 3020ND17.3 17.7
Tetrachloroethene ug/L 20 102 60-140106 4 3020ND20.4 21.2
Toluene ug/L 20 105 60-140103 2 3020ND20.9 20.5
trans-1,2-Dichloroethene ug/L 20 116 60-140116 0 3020ND23.1 23.1
trans-1,3-Dichloropropene ug/L 20 111 60-140109 2 3020ND22.2 21.8
Trichloroethene ug/L 20 119 60-140117 2 3020ND23.9 23.4
Trichlorofluoromethane ug/L 20 108 60-140111 2 3020ND21.6 22.1
Vinyl chloride ug/L 20 104 60-140103 1 3020ND20.8 20.5
1,2-Dichloroethane-d4 (S)%99 70-130108
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%97 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
754854
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92650720001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3921561
Associated Lab Samples:92650720001
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 02/10/23 09:42
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 02/10/23 09:42
2,4,6-Trichlorophenol ug/L ND 10.0 02/10/23 09:42
2,4-Dichlorophenol ug/L ND 5.0 02/10/23 09:42
2,4-Dimethylphenol ug/L ND 10.0 02/10/23 09:42
2,4-Dinitrophenol ug/L ND 50.0 02/10/23 09:42
2,4-Dinitrotoluene ug/L ND 5.0 02/10/23 09:42
2,6-Dinitrotoluene ug/L ND 5.0 02/10/23 09:42
2-Chloronaphthalene ug/L ND 5.0 02/10/23 09:42
2-Chlorophenol ug/L ND 5.0 02/10/23 09:42
2-Nitrophenol ug/L ND 5.0 02/10/23 09:42
3,3'-Dichlorobenzidine ug/L ND 10.0 02/10/23 09:42
4,6-Dinitro-2-methylphenol ug/L ND 10.0 02/10/23 09:42
4-Bromophenylphenyl ether ug/L ND 5.0 02/10/23 09:42
4-Chloro-3-methylphenol ug/L ND 5.0 02/10/23 09:42
4-Chlorophenylphenyl ether ug/L ND 5.0 02/10/23 09:42
4-Nitrophenol ug/L ND 10.0 02/10/23 09:42
Acenaphthene ug/L ND 5.0 02/10/23 09:42
Acenaphthylene ug/L ND 5.0 02/10/23 09:42
Anthracene ug/L ND 5.0 02/10/23 09:42
Benzo(a)anthracene ug/L ND 5.0 02/10/23 09:42
Benzo(a)pyrene ug/L ND 5.0 02/10/23 09:42
Benzo(b)fluoranthene ug/L ND 5.0 02/10/23 09:42
Benzo(g,h,i)perylene ug/L ND 5.0 02/10/23 09:42
Benzo(k)fluoranthene ug/L ND 5.0 02/10/23 09:42
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/10/23 09:42
bis(2-Chloroethyl) ether ug/L ND 5.0 02/10/23 09:42
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 02/10/23 09:42
Butylbenzylphthalate ug/L ND 5.0 02/10/23 09:42
Chrysene ug/L ND 5.0 02/10/23 09:42
Di-n-butylphthalate ug/L ND 5.0 02/10/23 09:42
Di-n-octylphthalate ug/L ND 5.0 02/10/23 09:42
Dibenz(a,h)anthracene ug/L ND 5.0 02/10/23 09:42
Diethylphthalate ug/L ND 5.0 02/10/23 09:42
Dimethylphthalate ug/L ND 5.0 02/10/23 09:42
Fluoranthene ug/L ND 5.0 02/10/23 09:42
Fluorene ug/L ND 5.0 02/10/23 09:42
Hexachloro-1,3-butadiene ug/L ND 5.0 02/10/23 09:42
Hexachlorobenzene ug/L ND 5.0 02/10/23 09:42
Hexachlorocyclopentadiene ug/L ND 10.0 02/10/23 09:42
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3921561
Associated Lab Samples:92650720001
Matrix:Water
Analyzed
Hexachloroethane ug/L ND 5.0 02/10/23 09:42
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 02/10/23 09:42
Isophorone ug/L ND 10.0 02/10/23 09:42
N-Nitroso-di-n-propylamine ug/L ND 5.0 02/10/23 09:42
N-Nitrosodimethylamine ug/L ND 5.0 02/10/23 09:42
N-Nitrosodiphenylamine ug/L ND 10.0 02/10/23 09:42
Naphthalene ug/L ND 5.0 02/10/23 09:42
Nitrobenzene ug/L ND 5.0 02/10/23 09:42
Pentachlorophenol ug/L ND 10.0 02/10/23 09:42
Phenanthrene ug/L ND 5.0 02/10/23 09:42
Phenol ug/L ND 5.0 02/10/23 09:42
Pyrene ug/L ND 5.0 02/10/23 09:42
2,4,6-Tribromophenol (S)%32 10-137 02/10/23 09:42
2-Fluorobiphenyl (S)%52 15-120 02/10/23 09:42
2-Fluorophenol (S)%7 10-120 S002/10/23 09:42
Nitrobenzene-d5 (S)%59 10-120 02/10/23 09:42
Phenol-d6 (S)%27 10-120 02/10/23 09:42
Terphenyl-d14 (S)%137 11-131 S302/10/23 09:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3921562LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 40.650 81 44-142
2,2'-Oxybis(1-chloropropane)ug/L 52.350 105 36-166
2,4,6-Trichlorophenol ug/L 51.150 102 37-144
2,4-Dichlorophenol ug/L 51.950 104 1-191
2,4-Dimethylphenol ug/L 70.8 L15014232-119
2,4-Dinitrophenol ug/L 303250 121 1-181
2,4-Dinitrotoluene ug/L 53.350 107 39-139
2,6-Dinitrotoluene ug/L 52.350 105 50-158
2-Chloronaphthalene ug/L 45.150 90 60-118
2-Chlorophenol ug/L 45.750 91 23-134
2-Nitrophenol ug/L 59.750 119 29-182
3,3'-Dichlorobenzidine ug/L 87.5100 87 1-262
4,6-Dinitro-2-methylphenol ug/L 127100 127 1-181
4-Bromophenylphenyl ether ug/L 49.150 98 53-127
4-Chloro-3-methylphenol ug/L 103100 103 22-147
4-Chlorophenylphenyl ether ug/L 47.850 96 25-158
4-Nitrophenol ug/L 152250 61 1-132
Acenaphthene ug/L 48.050 96 47-145
Acenaphthylene ug/L 48.050 96 33-145
Anthracene ug/L 45.350 91 1-166
Benzo(a)anthracene ug/L 48.550 97 33-143
Benzo(a)pyrene ug/L 48.250 96 17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3921562LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 52.250 104 24-159
Benzo(g,h,i)perylene ug/L 41.150 82 1-219
Benzo(k)fluoranthene ug/L 51.550 103 11-162
bis(2-Chloroethoxy)methane ug/L 53.650 107 33-184
bis(2-Chloroethyl) ether ug/L 51.450 103 12-158
bis(2-Ethylhexyl)phthalate ug/L 56.950 114 8-158
Butylbenzylphthalate ug/L 62.850 126 1-152
Chrysene ug/L 47.650 95 17-168
Di-n-butylphthalate ug/L 52.250 104 1-118
Di-n-octylphthalate ug/L 60.250 120 4-146
Dibenz(a,h)anthracene ug/L 41.350 83 1-227
Diethylphthalate ug/L 51.350 103 1-114
Dimethylphthalate ug/L 49.150 98 1-112
Fluoranthene ug/L 47.150 94 26-137
Fluorene ug/L 46.750 93 59-121
Hexachloro-1,3-butadiene ug/L 41.250 82 24-116
Hexachlorobenzene ug/L 47.050 94 1-152
Hexachlorocyclopentadiene ug/L 42.350 85 25-150
Hexachloroethane ug/L 35.750 71 40-113
Indeno(1,2,3-cd)pyrene ug/L 41.850 84 1-171
Isophorone ug/L 57.650 115 21-196
N-Nitroso-di-n-propylamine ug/L 54.850 110 1-230
N-Nitrosodimethylamine ug/L 59.050 118 25-150
N-Nitrosodiphenylamine ug/L 49.450 99 25-150
Naphthalene ug/L 47.750 95 21-133
Nitrobenzene ug/L 52.250 104 35-180
Pentachlorophenol ug/L 98.7100 99 14-176
Phenanthrene ug/L 47.450 95 54-120
Phenol ug/L 34.650 69 5-112
Pyrene ug/L 52.850 106 52-115
2,4,6-Tribromophenol (S)%104 10-137
2-Fluorobiphenyl (S)%89 15-120
2-Fluorophenol (S)%69 10-120
Nitrobenzene-d5 (S)%103 10-120
Phenol-d6 (S)%59 10-120
Terphenyl-d14 (S)%97 11-131
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 40
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The reported TIC has an 85% or higher match on a mass spectral library search.N
Surrogate recovery outside laboratory control limits.S0
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 40
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92650720
ST WOOTEN-BROAD CREEK
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92650720001 2004012 2004012MW1MADEPVMADEP VPH
92650720001 754854 755136MW1EPA 625.1 EPA 625.1
92650720001 754639MW1SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/15/2023 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 40
Page 21 of 40
Page 22 of 40
Page 23 of 40
Page 24 of 40
Page 25 of 40
Page 26 of 40
Page 27 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
February 15, 2023
Bonnie Vang
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: St Wooten- Borad Creek
Client Job Number:
Project Number: 92650720
Laboratory Work Order Number: 23B1093
Enclosed are results of analyses for samples as received by the laboratory on February 9, 2023. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Rebecca Faust
Project Manager
Page 1 of 13
Table of Contents
Page 28 of 40
Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
23B1093-01 5
Sample Preparation Information 6
QC Data 7
Petroleum Hydrocarbons Analyses - EPH 7
B331181 7
Flag/Qualifier Summary 9
Certifications 10
Chain of Custody/Sample Receipt 11
Page 2 of 13
Table of Contents
Page 29 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
2/15/2023
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Bonnie Vang
92650720
23B1093
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
St Wooten- Borad Creek
MW1 23B1093-01 Water MADEP EPH rev 2.1
[TOC_1]Sample Summary[TOC]
Page 3 of 13
Table of Contents
Page 30 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method MA EPH, only hydrocarbon ranges were requested and reported.
[TOC_1]Case Narrative[TOC]
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Meghan E. Kelley
Reporting Specialist
Page 4 of 13
Table of Contents
Page 31 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 2/9/2023
Work Order: 23B1093Sample Description:Project Location: St Wooten- Borad Creek
Sample ID: 23B1093-01
Field Sample #: MW1
Sample Matrix: Water
Sampled: 2/4/2023 09:25
[TOC_2]23B1093-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Petroleum Hydrocarbons Analyses - EPH
ND 96 2/13/23 21:14 GJBg/L 2/10/23MADEP EPH rev 2.11C9-C18 Aliphatics
ND 96 2/13/23 21:14 GJBg/L 2/10/23MADEP EPH rev 2.11C19-C36 Aliphatics
ND 96 2/13/23 21:14 GJBg/L 2/10/23MADEP EPH rev 2.11Unadjusted C11-C22 Aromatics
ND 96 2/13/23 21:14 GJBg/L 2/10/23MADEP EPH rev 2.11C11-C22 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
Chlorooctadecane (COD)52.6 2/13/23 21:1440-140
o-Terphenyl (OTP)72.7 2/13/23 21:1440-140
2-Bromonaphthalene 99.8 2/13/23 21:1440-140
2-Fluorobiphenyl 100 2/13/23 21:1440-140
[TOC_1]Sample Results[TOC]
Page 5 of 13
Table of Contents
Page 32 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 3510C Analytical Method: MADEP EPH rev 2.1
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B331181 02/10/23990 1.9023B1093-01 [MW1]
[TOC_1]Sample Preparation Information[TOC]
Page 6 of 13
Table of Contents
Page 33 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - EPH[TOC]
Batch B331181 - SW-846 3510C
[TOC_3]B331181[TOC]
Blank (B331181-BLK1) Prepared: 02/10/23 Analyzed: 02/13/23
C9-C18 Aliphatics g/L100ND
C19-C36 Aliphatics g/L100ND
Unadjusted C11-C22 Aromatics g/L100ND
C11-C22 Aromatics g/L100ND
Acenaphthene g/L2.0ND
Acenaphthylene g/L2.0ND
Anthracene g/L2.0ND
Benzo(a)anthracene g/L2.0ND
Benzo(a)pyrene g/L2.0ND
Benzo(b)fluoranthene g/L2.0ND
Benzo(g,h,i)perylene g/L2.0ND
Benzo(k)fluoranthene g/L2.0ND
Chrysene g/L2.0ND
Dibenz(a,h)anthracene g/L2.0ND
Fluoranthene g/L2.0ND
Fluorene g/L2.0ND
Indeno(1,2,3-cd)pyrene g/L2.0ND
2-Methylnaphthalene g/L2.0ND
Naphthalene g/L2.0ND
Phenanthrene g/L2.0ND
Pyrene g/L2.0ND
Naphthalene-aliphatic fraction g/L2.0ND
2-Methylnaphthalene-aliphatic fraction g/L2.0ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)71.771.7
g/L 100 40-140Surrogate: o-Terphenyl (OTP)76.776.7
g/L 100 40-140Surrogate: 2-Bromonaphthalene 104104
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 104104
LCS (B331181-BS1) Prepared: 02/10/23 Analyzed: 02/13/23
C9-C18 Aliphatics g/L100 600 40-14066.8401
C19-C36 Aliphatics g/L100 800 40-14079.9639
Unadjusted C11-C22 Aromatics g/L100 1700 40-14074.41260
Acenaphthene g/L2.0 100 40-14068.768.7
Acenaphthylene g/L2.0 100 40-14063.263.2
Anthracene g/L2.0 100 40-14070.170.1
Benzo(a)anthracene g/L2.0 100 40-14072.472.4
Benzo(a)pyrene g/L2.0 100 40-14073.473.4
Benzo(b)fluoranthene g/L2.0 100 40-14070.670.6
Benzo(g,h,i)perylene g/L2.0 100 40-14069.069.0
Benzo(k)fluoranthene g/L2.0 100 40-14069.369.3
Chrysene g/L2.0 100 40-14076.776.7
Dibenz(a,h)anthracene g/L2.0 100 40-14072.272.2
Fluoranthene g/L2.0 100 40-14070.470.4
Fluorene g/L2.0 100 40-14070.070.0
Indeno(1,2,3-cd)pyrene g/L2.0 100 40-14070.370.3
2-Methylnaphthalene g/L2.0 100 40-14063.863.8
Naphthalene g/L2.0 100 40-14059.459.4
Phenanthrene g/L2.0 100 40-14070.870.8
Pyrene g/L2.0 100 40-14071.771.7
Naphthalene-aliphatic fraction g/L2.0 100 0-5ND
2-Methylnaphthalene-aliphatic fraction g/L2.0 100 0-5ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)66.666.6
[TOC_1]QC Data[TOC]
Page 7 of 13
Table of Contents
Page 34 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - EPH - Quality Control
QUALITY CONTROL
Batch B331181 - SW-846 3510C
LCS (B331181-BS1) Prepared: 02/10/23 Analyzed: 02/13/23
g/L 100 40-140Surrogate: o-Terphenyl (OTP)69.069.0
g/L 100 40-140Surrogate: 2-Bromonaphthalene 98.698.6
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 99.399.3
LCS Dup (B331181-BSD1) Prepared: 02/10/23 Analyzed: 02/13/23
C9-C18 Aliphatics g/L100 600 2540-14076.3 13.3458
C19-C36 Aliphatics g/L100 800 2540-14095.7 18.0765
Unadjusted C11-C22 Aromatics g/L100 1700 2540-14083.2 11.21410
Acenaphthene g/L2.0 100 2540-14075.0 8.7775.0
Acenaphthylene g/L2.0 100 2540-14068.2 7.6668.2
Anthracene g/L2.0 100 2540-14080.6 13.980.6
Benzo(a)anthracene g/L2.0 100 2540-14083.4 14.183.4
Benzo(a)pyrene g/L2.0 100 2540-14083.5 12.983.5
Benzo(b)fluoranthene g/L2.0 100 2540-14081.1 13.781.1
Benzo(g,h,i)perylene g/L2.0 100 2540-14079.2 13.879.2
Benzo(k)fluoranthene g/L2.0 100 2540-14078.6 12.778.6
Chrysene g/L2.0 100 2540-14087.9 13.687.9
Dibenz(a,h)anthracene g/L2.0 100 2540-14082.4 13.282.4
Fluoranthene g/L2.0 100 2540-14081.5 14.681.5
Fluorene g/L2.0 100 2540-14077.1 9.6377.1
Indeno(1,2,3-cd)pyrene g/L2.0 100 2540-14079.9 12.979.9
2-Methylnaphthalene g/L2.0 100 2540-14067.3 5.3367.3
Naphthalene g/L2.0 100 2540-14061.1 2.8061.1
Phenanthrene g/L2.0 100 2540-14081.8 14.481.8
Pyrene g/L2.0 100 2540-14083.0 14.783.0
Naphthalene-aliphatic fraction g/L2.0 100 0-5ND
2-Methylnaphthalene-aliphatic fraction g/L2.0 100 0-5ND
g/L 100 40-140Surrogate: Chlorooctadecane (COD)80.080.0
g/L 100 40-140Surrogate: o-Terphenyl (OTP)79.179.1
g/L 100 40-140Surrogate: 2-Bromonaphthalene 94.594.5
g/L 100 40-140Surrogate: 2-Fluorobiphenyl 96.296.2
Page 8 of 13
Table of Contents
Page 35 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
[TOC_1]Flag/Qualifier Summary[TOC]
Page 9 of 13
Table of Contents
Page 36 of 40
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
MADEP EPH rev 2.1 in Water
CT,NC,ME,NH-PC9-C18 Aliphatics
CT,NC,ME,NH-PC19-C36 Aliphatics
CT,NC,ME,NH-PUnadjusted C11-C22 Aromatics
CT,NC,ME,NH-PC11-C22 Aromatics
[TOC_1]Certifications[TOC]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
PH-0821Connecticut Department of Public HealthCT 12/31/2024
652North Carolina Div. of Water QualityNC 12/31/2023
MA00100State of MaineME 06/9/2023
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2023
Page 10 of 13
Table of Contents
Page 37 of 40
Page 11 of 13
Table of Contents
Page 38 of 40
Page 12 of 13
Table of Contents
Page 39 of 40
Page 13 of 13
Table of Contents
Page 40 of 40