WA-86891_86891_CA_MRP_20181107

EXECUTIVE SUMMARY
The Murfreesboro Bulk Plant site is located at 862 West Main Street, Murfreesboro, Hertford County,
North Carolina. According to the available information, a total of five ASTs were formerly located on the
property. Petroleum products, including dyed and highway diesel fuel, unleaded and premium-grade
gasoline and kerosene, and wastewater generated during AFVR events and aquifer tests at UST sites were
previously stored in the ASTs. Only one AST containing petroleum-contaminated water remains on-site.
An inactive ground water treatment system is located on-site. A petroleum release at the site reportedly
occurred from leaks caused by freezing at the pipe fittings from the kerosene and wastewater ASTs on
January 11, 2004. Free product has been measured in MW-2 during previous sampling events.

On October 17, 2018, six type II monitoring wells (MW-2, MW-4, and MW-8 through MW-11) were
gauged, purged and sampled. Concentrations of requested method constituents that exceeded the
Maximum Allowable Concentrations specified in T15A NCAC 2L.0202 were reported in the ground
water samples collected from MW-4 and MW-9. None of the reported contaminant concentrations
exceeded the Gross Contamination Levels.

Based on this information, the site risk classification for this incident should be evaluated. An updated
receptor survey should be completed for the site. If no high risk receptors are identified during updated
receptor survey activities, a land use restriction should be filed on the deed of the subject property and the
incident should be closed.

TABLE OF CONTENTS

1.0 SITE HISTORY AND CHARACTERIZATION ....................................................................... 1
2.0 CURRENT SITE ASSESSMENT ................................................................................................ 1
3.0 GROUND WATER QUALITY .................................................................................................... 1
4.0 CONCLUSIONS AND RECOMMENDATIONS ....................................................................... 2
5.0 LIMITATIONS .............................................................................................................................. 2

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Water Table Surface Map
Figure 4: Ground Water Quality Map

TABLES
Table 1: Well Construction and Gauging Information
Table 2: Summary of Ground Water Sample Analytical Results

APPENDIX
Appendix A: Laboratory Report – Ground Water Samples

1
1.0 SITE HISTORY AND CHARACTERIZATION
The former Murfreesboro Bulk Plant facility is located at 862 West Main Street, in Murfreesboro,
Hertford County, North Carolina (Figure 1). According to the available information, a total of five ASTs
were formerly located on the property. Petroleum products, including dyed and highway diesel fuel,
unleaded and premium-grade gasoline and kerosene, and wastewater generated during AFVR events and
aquifer tests at UST sites were previously stored in the ASTs. Only one AST containing petroleum-
contaminated water remains on-site. An inactive ground water treatment system is located on-site. A
petroleum release reportedly occurred at the site from leaks caused by freezing at the pipe fittings from
the kerosene and wastewater ASTs on January 11, 2004. Eleven monitoring wells (MW-1 through MW-
11) were installed at the site during past ground water assessment activities. Free product has been
measured in MW-2 during previous sampling events.

Past assessment were conducted by previous consultants, although Geological Resources, Inc. (GRI)
cannot verify the accuracy of information obtained from previous reports, for the purposes of this report,
it is assumed to be correct. Please refer to previous submittals for further historical information regarding
the site.

2.0 CURRENT SITE ASSESSMENT
The purpose of this report is to present the results of ground water sampling activities conducted on
October 17, 2018. The activities were conducted in accordance with GRI proposal number 18-542 which
was approved on October 15, 2018, by North East Oil Company, Inc. The purpose of the activities was to
obtain current ground water quality data for the site.

3.0 GROUND WATER QUALITY
Six Type II monitoring wells (MW-2, MW-4 and MW-8 through MW-11) were gauged, purged and
sampled on October 17, 2018. No free product was observed during the October 2018 sampling event.
Please note, MW-1, MW-3, MW-6 and MW-7 were not located and are presumed to have been destroyed.
The depths to ground water in the Type II monitoring wells during the October 2018 sampling event
ranged from 3.65 to 4.79 feet below the top of casings. Ground water elevations in the Type II
monitoring wells relative to a temporary benchmark with an assumed datum of 100.00 feet ranged from
95.42 to 96.67. The general ground water flow direction was toward the northeast. The average
horizontal hydraulic gradient across the site was less than 0.01 feet per foot. A Site Map showing the

2
locations of monitoring wells and structures on-site is included as Figure 2. A Water Table Surface Map
for the October 17, 2018 sampling event has been included as Figure 3. Well construction and gauging
information are presented in Table 1.

Laboratory analyses were performed on the ground water samples collected from the monitoring wells
during the October 2018 sampling event for volatile organic compounds using EPA Method 6200B.
Concentrations of benzene, naphthalene and/or n-propylbenzene that exceeded the Maximum Allowable
Concentrations (MACs) specified in T15A NCAC 2L.0202 were reported in the ground water samples
collected from MW-4 and MW-9. None of the reported contaminant concentrations exceeded the Gross
Contamination Levels (GCLs). A Ground Water Quality Map based on data from the October 2018
sampling event has been included as Figure 4. A summary of ground water sample analytical results is
presented in Table 2. A complete laboratory report has been included as Appendix A.

4.0 CONCLUSIONS AND RECOMMENDATIONS
 The average depth to ground water in the monitoring wells during the October 2018 sampling
event was 4.24 feet. Ground water flow for the site during the October 2018 gauging event was
generally toward the northeast with an average horizontal hydraulic gradient of less than 0.01 feet
per foot.
 Concentrations of benzene, naphthalene and/or n- propylbenzene that exceeded the MACs were
reported in the ground water samples collected from MW-4 and MW-9.
 Based on this information, the site risk classification for this incident should be evaluated. An
updated receptor survey should be completed for the site. If no high risk receptors are identified,
a land use restriction should be filed on the deed of the subject property and the incident should
be closed.

5.0 LIMITATIONS
This report has been prepared for the exclusive use of North East Oil Company, Inc. for specific
application to the referenced site in Hertford County, North Carolina. The assessment was conducted
based on the scope of work and level of effort desired by NCDEQ and with resources adequate only for
that scope of work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

3
The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would be
interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data. Although the accuracy of this
information cannot be verified, for the purpose of this report GRI assumes that it is correct.

FIGURES

TABLES
Date: 10/24/18 Facility ID: N/A
MW-1 05/20/05 07/27/10 5.5 5.5-15.5 15.5 100.00 6.14 ---93.86
07/27/10 6.73 ---94.06
10/17/18 4.62 ---96.17
MW-3 10/04/05 07/27/10 5 5-15 15 99.95 6.78 ---93.17
07/27/10 6.72 ---93.48
10/17/18 4.04 ---96.16
MW-5 01/04/06 07/27/10 2 2-12 12 100.16 7.36 ---92.80
MW-6 01/03/06 07/27/10 2 2-12 12 100.62 7.22 ---93.40
MW-7 01/04/06 07/27/10 2 2-12 12 101.06 6.75 ---94.31
07/27/10 6.42 ---94.50
10/17/18 4.42 ---96.50
07/27/10 6.22 ---94.10
10/17/18 3.65 ---96.67
07/27/10 6.85 ---92.81
10/17/18 3.92 ---95.74
07/27/10 7.17 ---93.04
10/17/18 4.79 ---95.42
TW-1 01/05/06 07/27/10 35.5 35.5-40.5 40.5 100.76 NA ---NA
HLE-11 02/28/03 07/27/10 5 5-20 20 NA 7.75 ---NA
HLE-12 NA 07/27/10 NA NA NA NA 6.68 ---NA
Notes:
CES Engineering, P.C., as well as well construction records and well identification tags.
100.79183-18305/27/05MW-2
100.20122-12201/03/06MW-4
01/04/06MW-9
100.92122-12201/04/06MW-8
MW-11
99.66122-12201/04/06MW-10
Comments
100.21122-12201/04/06
100.32122-122
• Top-of-Casing elevations and well construction information reproduced from report titled 'Semi Annual Ground Water Monitoring Report (August 31, 2004)', dated September 30, 2004, and prepared by
• NM: Not Measured.
• ft BGS : feet below ground surface.
Depth to Water
from
Top of Casing
(ft)
TABLE 1
WELL CONSTRUCTION AND GAUGING INFORMATION
MURFEESBORO BULK PLANT (INCIDENT NO. 86891)
Date Installed
(mm/dd/yy)
Free Product
Thickness**
(ft.)
Top of Casing
Elevation*
(ft.)
• **: If free product is present in a well, ground water elevation calculated by: (Top of Casing Elevation - Depth to Water) + (Free Product thickness x 0.8581)
• *: Reference point for elevation measurements; assumed elevation 100.00 ft.
Ground Water
Elevation
(ft.)
Bottom of Well
(ft. BGS)
• NA: Not Available
Well ID
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft. BGS)
Page 1 of 1
Date : 10/24/18
Well ID Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 70 70 70 70 400 400
5,000 260,000 84,500 85,500 20,000 6,000 6,900 25,000 70,000 30,000 28,500 25,000
MW-1 07/27/10 1.91 <0.190 3.15 <0.220 196 4.93 NR NR <0.200 NR NR NR
07/27/10 21.1 <1.90 19.7 8.82 1,080 53.0 NR NR 5.75 J NR NR NR
10/17/18 0.14 J <0.13 <0.13 <0.25 5.5 2.8 1.9 2.3 <0.13 4.0 <0.13 <0.13
MW-3 07/27/10 26.1 <0.950 13.9 <1.10 406 39.8 NR NR 2.62 J NR NR NR
07/27/10 89.6 2.14 J 263 26.4 141 226 NR NR 6.74 J NR NR NR
10/17/18 53.1 1.8 J 195 56.0 9.7 245 8.5 29.9 0.98 J 77.1 190 20.7
MW-5 07/27/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 NR NR <0.200 NR NR NR
MW-6 07/27/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 NR NR <0.200 NR NR NR
MW-7 07/27/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 NR NR <0.200 NR NR NR
07/27/10 <0.140 <0.190 <0.150 <0.220 6.02 <0.500 NR NR 0.264 J NR NR NR
10/17/18 <0.13 <0.13 <0.13 <0.25 4.0 <0.13 <0.13 0.34 J 0.21 J <0.13 <0.13 <0.13
07/27/10 3.58 0.228 J 0.429 J 2.29 27.9 18.2 NR NR 4.31 NR NR NR
10/17/18 0.52 0.17 J 0.26 J 1.7 1.7 22.5 3.0 5.2 0.18 J 10.0 20.0 0.96
07/27/10 <0.140 <0.190 <0.150 <0.220 17.1 <0.500 NR NR 0.674 J NR NR NR
10/17/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
07/27/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 NR NR <0.200 NR NR NR
10/17/18 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13
HLE-11 07/27/10 3.03 <0.190 <0.150 <0.220 94.2 <0.500 NR NR 0.268 J NR NR NR
HLE-12 07/27/10 <0.140 <0.190 <0.150 <0.220 1.09 <0.500 NR NR 3.73 NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• NR: Not Requested.
• NE: Standard not established.
• Concentrations in bold face type exceeded the 2L standards.
• J: Estimated value.
• < : Less than the method detection limit specified in the laboratory report.
EPA Method 6200B
TABLE 2
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
MURFEESBORO BULK PLANT (INCIDENT NO. 86891)1,3,5-Trimethylbenzene1,2,4-Trimethylbenzenen-PropylbenzeneIsopropylbenzeneDi-isopropyl etherMW-10
MW-9
MW-8
MW-4
MW-2 BenzeneFacility ID: N/A
GCL (mg/l)
Contaminant of Concern
MTBEn-ButylbenzeneAnalytical Method
TolueneEthylbenzeneXylenes• Other constituents were detected that did not exceed the 2L Standards, see the laboratory report for details
• 2L Standard as specified in T15A NCAC 2L.0202.
• GCL : Gross contamination level.Naphthalene2L Standard (mg/l)
MW-11
Page 1 of 1

APPENDIX

APPENDIX A
Laboratory Report – Ground Water Samples
10/22/18
Technical Report for
GRI (Geological Resources Inc.)
Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
2262
SGS Job Number: FA58500
Sampling Date: 10/17/18
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 10/22/18
e-Hardcopy 2.0
Automated Report
28
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
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FA58500
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA58500-1: MW-2 ........................................................................................................7
3.2: FA58500-2: MW-4 ........................................................................................................9
3.3: FA58500-3: MW-8 ........................................................................................................11
3.4: FA58500-4: MW-9 ........................................................................................................13
3.5: FA58500-5: MW-10 ......................................................................................................15
3.6: FA58500-6: MW-11 ......................................................................................................17
Section 4: Misc. Forms ............................................................................................................19
4.1: Chain of Custody ...........................................................................................................20
Section 5: MS Volatiles - QC Data Summaries .....................................................................22
5.1: Method Blank Summary ................................................................................................23
5.2: Blank Spike Summary ...................................................................................................25
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................27 123452 of 28
FA58500
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA58500
Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Project No: 2262
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA58500-1 10/17/18 14:29 ER 10/18/18 AQ Ground Water MW-2
FA58500-2 10/17/18 14:46 ER 10/18/18 AQ Ground Water MW-4
FA58500-3 10/17/18 14:24 ER 10/18/18 AQ Ground Water MW-8
FA58500-4 10/17/18 14:54 ER 10/18/18 AQ Ground Water MW-9
FA58500-5 10/17/18 15:05 ER 10/18/18 AQ Ground Water MW-10
FA58500-6 10/17/18 15:19 ER 10/18/18 AQ Ground Water MW-11
3 of 28
FA585001
Summary of Hits Page 1 of 2
Job Number:FA58500
Account:GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Collected:10/17/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA58500-1 MW-2
Benzene 0.14 J 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 1.9 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 2.1 0.50 0.13 ug/l SM 6200B
tert-Butylbenzene 0.28 J 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 2.3 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.48 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 5.5 0.50 0.13 ug/l SM 6200B
Naphthalene 2.8 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 4.0 0.50 0.13 ug/l SM 6200B
FA58500-2 MW-4
Benzene 53.1 2.5 0.63 ug/l SM 6200B
n-Butylbenzene 8.5 2.5 0.63 ug/l SM 6200B
sec-Butylbenzene 6.9 2.5 0.63 ug/l SM 6200B
tert-Butylbenzene 1.1 J 2.5 0.63 ug/l SM 6200B
o-Chlorotoluene 2.6 2.5 0.63 ug/l SM 6200B
Di-Isopropyl Ether 0.98 J 2.5 0.63 ug/l SM 6200B
Ethylbenzene 195 2.5 0.63 ug/l SM 6200B
Isopropylbenzene 29.9 2.5 0.63 ug/l SM 6200B
p-Isopropyltoluene 3.6 2.5 0.63 ug/l SM 6200B
Methyl Tert Butyl Ether 9.7 2.5 0.63 ug/l SM 6200B
Naphthalene 245 5.0 1.3 ug/l SM 6200B
n-Propylbenzene 77.1 2.5 0.63 ug/l SM 6200B
Toluene 1.8 J 2.5 0.63 ug/l SM 6200B
1,2,4-Trimethylbenzene 190 2.5 0.63 ug/l SM 6200B
1,3,5-Trimethylbenzene 20.7 2.5 0.63 ug/l SM 6200B
m,p-Xylene 53.5 5.0 0.63 ug/l SM 6200B
o-Xylene 2.4 J 2.5 0.63 ug/l SM 6200B
Xylene (total)56.0 7.5 1.3 ug/l SM 6200B
FA58500-3 MW-8
sec-Butylbenzene 0.32 J 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 0.21 J 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 0.34 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 4.0 0.50 0.13 ug/l SM 6200B
FA58500-4 MW-9
Benzene 0.52 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 3.0 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 5.8 0.50 0.13 ug/l SM 6200B
4 of 28
FA585002
Summary of Hits Page 2 of 2
Job Number:FA58500
Account:GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Collected:10/17/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
tert-Butylbenzene 0.81 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 0.18 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 0.26 J 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 5.2 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 2.0 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 1.7 0.50 0.13 ug/l SM 6200B
Naphthalene 22.5 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 10.0 0.50 0.13 ug/l SM 6200B
Toluene 0.17 J 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 20.0 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.96 0.50 0.13 ug/l SM 6200B
m,p-Xylene 1.2 1.0 0.13 ug/l SM 6200B
o-Xylene 0.44 J 0.50 0.13 ug/l SM 6200B
Xylene (total)1.7 1.5 0.25 ug/l SM 6200B
FA58500-5 MW-10
No hits reported in this sample.
FA58500-6 MW-11
No hits reported in this sample.
5 of 28
FA585002
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 28
FA585003
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-2
Lab Sample ID:FA58500-1 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215628.D 1 10/19/18 13:16 AB n/a n/a VA2470
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 0.14 0.50 0.13 ug/l J
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 1.9 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 2.1 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 0.28 0.50 0.13 ug/l J
56-23-5 Carbon Tetrachloride a ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA5850033.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-2
Lab Sample ID:FA58500-1 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 2.3 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 0.48 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 5.5 0.50 0.13 ug/l
91-20-3 Naphthalene 2.8 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 4.0 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 28
FA5850033.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-4
Lab Sample ID:FA58500-2 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215621.D 5 10/19/18 10:34 AB n/a n/a VA2470
Run #2 A0215629.D 10 10/19/18 13:40 AB n/a n/a VA2470
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 53.1 2.5 0.63 ug/l
108-86-1 Bromobenzene ND 2.5 0.63 ug/l
74-97-5 Bromochloromethane ND 2.5 0.63 ug/l
75-27-4 Bromodichloromethane ND 2.5 0.63 ug/l
75-25-2 Bromoform ND 2.5 0.63 ug/l
104-51-8 n-Butylbenzene 8.5 2.5 0.63 ug/l
135-98-8 sec-Butylbenzene 6.9 2.5 0.63 ug/l
98-06-6 tert-Butylbenzene 1.1 2.5 0.63 ug/l J
56-23-5 Carbon Tetrachloride a ND 2.5 0.63 ug/l
108-90-7 Chlorobenzene ND 2.5 0.63 ug/l
75-00-3 Chloroethane ND 2.5 1.0 ug/l
67-66-3 Chloroform ND 2.5 0.63 ug/l
95-49-8 o-Chlorotoluene 2.6 2.5 0.63 ug/l
106-43-4 p-Chlorotoluene ND 2.5 0.63 ug/l
124-48-1 Dibromochloromethane ND 2.5 0.63 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.5 1.2 ug/l
106-93-4 1,2-Dibromoethane ND 2.5 0.63 ug/l
75-71-8 Dichlorodifluoromethane ND 2.5 1.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 2.5 0.63 ug/l
541-73-1 1,3-Dichlorobenzene ND 2.5 0.63 ug/l
106-46-7 1,4-Dichlorobenzene ND 2.5 0.63 ug/l
75-34-3 1,1-Dichloroethane ND 2.5 0.63 ug/l
107-06-2 1,2-Dichloroethane ND 2.5 0.63 ug/l
75-35-4 1,1-Dichloroethylene ND 2.5 0.63 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 2.5 0.63 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 2.5 0.63 ug/l
78-87-5 1,2-Dichloropropane ND 2.5 0.63 ug/l
142-28-9 1,3-Dichloropropane ND 2.5 0.63 ug/l
594-20-7 2,2-Dichloropropane ND 2.5 0.63 ug/l
563-58-6 1,1-Dichloropropene ND 2.5 0.63 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 2.5 0.63 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 2.5 0.63 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 28
FA5850033.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-4
Lab Sample ID:FA58500-2 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.98 2.5 0.63 ug/l J
100-41-4 Ethylbenzene 195 2.5 0.63 ug/l
87-68-3 Hexachlorobutadiene ND 2.5 0.63 ug/l
98-82-8 Isopropylbenzene 29.9 2.5 0.63 ug/l
99-87-6 p-Isopropyltoluene 3.6 2.5 0.63 ug/l
74-83-9 Methyl Bromide ND 2.5 1.0 ug/l
74-87-3 Methyl Chloride ND 2.5 1.0 ug/l
74-95-3 Methylene Bromide ND 2.5 0.63 ug/l
75-09-2 Methylene Chloride ND 10 5.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 9.7 2.5 0.63 ug/l
91-20-3 Naphthalene 245 b 5.0 1.3 ug/l
103-65-1 n-Propylbenzene 77.1 2.5 0.63 ug/l
100-42-5 Styrene ND 2.5 0.63 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 2.5 0.63 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 2.5 0.63 ug/l
127-18-4 Tetrachloroethylene ND 2.5 0.63 ug/l
108-88-3 Toluene 1.8 2.5 0.63 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 2.5 0.63 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 2.5 0.63 ug/l
71-55-6 1,1,1-Trichloroethane ND 2.5 0.63 ug/l
79-00-5 1,1,2-Trichloroethane ND 2.5 0.63 ug/l
79-01-6 Trichloroethylene ND 2.5 0.63 ug/l
75-69-4 Trichlorofluoromethane ND 2.5 1.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.5 0.63 ug/l
95-63-6 1,2,4-Trimethylbenzene 190 2.5 0.63 ug/l
108-67-8 1,3,5-Trimethylbenzene 20.7 2.5 0.63 ug/l
75-01-4 Vinyl Chloride ND 2.5 0.63 ug/l
m,p-Xylene 53.5 5.0 0.63 ug/l
95-47-6 o-Xylene 2.4 2.5 0.63 ug/l J
1330-20-7 Xylene (total)56.0 7.5 1.3 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%99%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%104%70-130%
2037-26-5 Toluene-D8 95%98%70-130%
460-00-4 4-Bromofluorobenzene 104%106%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
(b) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 28
FA5850033.2
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-8
Lab Sample ID:FA58500-3 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215623.D 1 10/19/18 11:22 AB n/a n/a VA2470
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 0.32 0.50 0.13 ug/l J
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride a ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 28
FA5850033.3
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-8
Lab Sample ID:FA58500-3 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.21 0.50 0.13 ug/l J
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 0.34 0.50 0.13 ug/l J
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 4.0 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 96%70-130%
460-00-4 4-Bromofluorobenzene 107%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 28
FA5850033.3
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-9
Lab Sample ID:FA58500-4 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215624.D 1 10/19/18 11:45 AB n/a n/a VA2470
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 0.52 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 3.0 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 5.8 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 0.81 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride a ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 28
FA5850033.4
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-9
Lab Sample ID:FA58500-4 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.18 0.50 0.13 ug/l J
100-41-4 Ethylbenzene 0.26 0.50 0.13 ug/l J
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 5.2 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 2.0 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 1.7 0.50 0.13 ug/l
91-20-3 Naphthalene 22.5 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 10.0 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 0.17 0.50 0.13 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 20.0 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.96 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 1.2 1.0 0.13 ug/l
95-47-6 o-Xylene 0.44 0.50 0.13 ug/l J
1330-20-7 Xylene (total)1.7 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 28
FA5850033.4
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-10
Lab Sample ID:FA58500-5 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215625.D 1 10/19/18 12:08 AB n/a n/a VA2470
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride a ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 28
FA5850033.5
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-10
Lab Sample ID:FA58500-5 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 28
FA5850033.5
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-11
Lab Sample ID:FA58500-6 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215626.D 1 10/19/18 12:31 AB n/a n/a VA2470
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride a ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
17 of 28
FA5850033.6
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-11
Lab Sample ID:FA58500-6 Date Sampled:10/17/18
Matrix:AQ - Ground Water Date Received:10/18/18
Method:SM 6200B Percent Solids:n/a
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 28
FA5850033.6
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
19 of 28
FA585004
FA58500: Chain of Custody
Page 1 of 2
20 of 28
FA5850044.1
Job Number:FA58500 Client:GRI
Date / Time Received:10/18/2018 9:00:00 AM Delivery Method:FED EX
Project:2262
Airbill #'s:1015899952560003281100812565568290
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (4.2);
Cooler 1: (4.0);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.2; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SHAYLAP BRW Date:10/18/2018Date:10/18/2018 9:00:00 A
FA58500: Chain of Custody
Page 2 of 2
21 of 28
FA5850044.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
22 of 28
FA585005
Method Blank Summary Page 1 of 2
Job Number:FA58500
Account:GRINCC GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2470-MB A0215620.D 1 10/19/18 AB n/a n/a VA2470
The QC reported here applies to the following samples:Method: SM 6200B
FA58500-1, FA58500-2, FA58500-3, FA58500-4, FA58500-5, FA58500-6
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
23 of 28
FA5850055.1.1
Method Blank Summary Page 2 of 2
Job Number:FA58500
Account:GRINCC GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2470-MB A0215620.D 1 10/19/18 AB n/a n/a VA2470
The QC reported here applies to the following samples:Method: SM 6200B
FA58500-1, FA58500-2, FA58500-3, FA58500-4, FA58500-5, FA58500-6
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
24 of 28
FA5850055.1.1
Blank Spike Summary Page 1 of 2
Job Number:FA58500
Account:GRINCC GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2470-BS A0215618.D 1 10/19/18 AB n/a n/a VA2470
The QC reported here applies to the following samples:Method: SM 6200B
FA58500-1, FA58500-2, FA58500-3, FA58500-4, FA58500-5, FA58500-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.3 93 70-130
108-86-1 Bromobenzene 10 10.5 105 70-130
74-97-5 Bromochloromethane 10 8.0 80 70-130
75-27-4 Bromodichloromethane 10 10.3 103 70-130
75-25-2 Bromoform 10 8.9 89 70-130
104-51-8 n-Butylbenzene 10 10.9 109 70-130
135-98-8 sec-Butylbenzene 10 11.0 110 70-130
98-06-6 tert-Butylbenzene 10 10.8 108 70-130
56-23-5 Carbon Tetrachloride 10 11.7 117 70-130
108-90-7 Chlorobenzene 10 10.1 101 70-130
75-00-3 Chloroethane 10 8.2 82 60-140
67-66-3 Chloroform 10 9.3 93 70-130
95-49-8 o-Chlorotoluene 10 10.6 106 70-130
106-43-4 p-Chlorotoluene 10 10.7 107 70-130
124-48-1 Dibromochloromethane 10 9.7 97 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.6 86 70-130
106-93-4 1,2-Dibromoethane 10 9.9 99 70-130
75-71-8 Dichlorodifluoromethane 10 8.9 89 60-140
95-50-1 1,2-Dichlorobenzene 10 10.2 102 70-130
541-73-1 1,3-Dichlorobenzene 10 10.6 106 70-130
106-46-7 1,4-Dichlorobenzene 10 10.4 104 70-130
75-34-3 1,1-Dichloroethane 10 9.5 95 70-130
107-06-2 1,2-Dichloroethane 10 9.5 95 70-130
75-35-4 1,1-Dichloroethylene 10 8.7 87 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.2 92 70-130
156-60-5 trans-1,2-Dichloroethylene 10 9.3 93 70-130
78-87-5 1,2-Dichloropropane 10 9.9 99 70-130
142-28-9 1,3-Dichloropropane 10 9.7 97 70-130
594-20-7 2,2-Dichloropropane 10 9.9 99 70-130
563-58-6 1,1-Dichloropropene 10 9.6 96 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.2 92 70-130
10061-02-6 trans-1,3-Dichloropropene 10 10.5 105 70-130
108-20-3 Di-Isopropyl Ether 10 7.9 79 70-130
100-41-4 Ethylbenzene 10 10.1 101 70-130
87-68-3 Hexachlorobutadiene 10 10.7 107 70-130
98-82-8 Isopropylbenzene 10 10.7 107 70-130
* = Outside of Control Limits.
25 of 28
FA5850055.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA58500
Account:GRINCC GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2470-BS A0215618.D 1 10/19/18 AB n/a n/a VA2470
The QC reported here applies to the following samples:Method: SM 6200B
FA58500-1, FA58500-2, FA58500-3, FA58500-4, FA58500-5, FA58500-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 11.0 110 70-130
74-83-9 Methyl Bromide 10 8.2 82 60-140
74-87-3 Methyl Chloride 10 9.3 93 60-140
74-95-3 Methylene Bromide 10 9.7 97 70-130
75-09-2 Methylene Chloride 10 8.7 87 70-130
1634-04-4 Methyl Tert Butyl Ether 10 7.9 79 70-130
91-20-3 Naphthalene 10 9.7 97 70-130
103-65-1 n-Propylbenzene 10 10.7 107 70-130
100-42-5 Styrene 10 10.1 101 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10.6 106 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.8 108 70-130
127-18-4 Tetrachloroethylene 10 10.0 100 70-130
108-88-3 Toluene 10 9.8 98 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.9 99 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10 100 70-130
71-55-6 1,1,1-Trichloroethane 10 9.8 98 70-130
79-00-5 1,1,2-Trichloroethane 10 10.1 101 70-130
79-01-6 Trichloroethylene 10 9.7 97 70-130
75-69-4 Trichlorofluoromethane 10 9.9 99 60-140
96-18-4 1,2,3-Trichloropropane 10 10.6 106 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.3 103 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.7 107 70-130
75-01-4 Vinyl Chloride 10 8.8 88 60-140
m,p-Xylene 20 20.6 103 70-130
95-47-6 o-Xylene 10 9.8 98 70-130
1330-20-7 Xylene (total)30 30.4 101 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
* = Outside of Control Limits.
26 of 28
FA5850055.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA58500
Account:GRINCC GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA58500-2MS A0215630.D 10 10/19/18 AB n/a n/a VA2470
FA58500-2MSD A0215631.D 10 10/19/18 AB n/a n/a VA2470
FA58500-2 A0215621.D 5 10/19/18 AB n/a n/a VA2470
FA58500-2 A0215629.D 10 10/19/18 AB n/a n/a VA2470
The QC reported here applies to the following samples:Method: SM 6200B
FA58500-1, FA58500-2, FA58500-3, FA58500-4, FA58500-5, FA58500-6
FA58500-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 53.1 100 144 91 100 146 93 1 70-130/20
108-86-1 Bromobenzene ND 100 103 103 100 106 106 3 70-130/20
74-97-5 Bromochloromethane ND 100 78.9 79 100 81.5 82 3 70-130/20
75-27-4 Bromodichloromethane ND 100 88.4 88 100 90.2 90 2 70-130/20
75-25-2 Bromoform ND 100 44.6 45*100 43.7 44*2 70-130/20
104-51-8 n-Butylbenzene 8.5 100 118 110 100 120 112 2 70-130/20
135-98-8 sec-Butylbenzene 6.9 100 116 109 100 118 111 2 70-130/20
98-06-6 tert-Butylbenzene 1.1 J 100 107 106 100 110 109 3 70-130/20
56-23-5 Carbon Tetrachloride ND 100 104 104 100 107 107 3 70-130/20
108-90-7 Chlorobenzene ND 100 101 101 100 104 104 3 70-130/20
75-00-3 Chloroethane ND 100 81.0 81 100 89.5 90 10 60-140/20
67-66-3 Chloroform ND 100 91.0 91 100 93.5 94 3 70-130/20
95-49-8 o-Chlorotoluene 2.6 100 108 105 100 110 107 2 70-130/20
106-43-4 p-Chlorotoluene ND 100 104 104 100 106 106 2 70-130/20
124-48-1 Dibromochloromethane ND 100 67.3 67*100 66.7 67*1 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 100 101 101 100 105 105 4 70-130/20
106-93-4 1,2-Dibromoethane ND 100 96.9 97 100 97.3 97 0 70-130/20
75-71-8 Dichlorodifluoromethane ND 100 86.8 87 100 103 103 17 60-140/20
95-50-1 1,2-Dichlorobenzene ND 100 102 102 100 103 103 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 100 105 105 100 107 107 2 70-130/20
106-46-7 1,4-Dichlorobenzene ND 100 102 102 100 103 103 1 70-130/20
75-34-3 1,1-Dichloroethane ND 100 92.8 93 100 94.7 95 2 70-130/20
107-06-2 1,2-Dichloroethane ND 100 94.0 94 100 94.2 94 0 70-130/20
75-35-4 1,1-Dichloroethylene ND 100 85.2 85 100 87.6 88 3 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 100 90.3 90 100 92.2 92 2 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 100 89.7 90 100 92.4 92 3 70-130/20
78-87-5 1,2-Dichloropropane ND 100 97.1 97 100 98.2 98 1 70-130/20
142-28-9 1,3-Dichloropropane ND 100 94.3 94 100 95.9 96 2 70-130/20
594-20-7 2,2-Dichloropropane ND 100 97.2 97 100 97.3 97 0 70-130/20
563-58-6 1,1-Dichloropropene ND 100 94.4 94 100 96.3 96 2 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 100 74.4 74 100 74.3 74 0 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 100 81.3 81 100 80.6 81 1 70-130/20
108-20-3 Di-Isopropyl Ether 0.98 J 100 78.2 77 100 79.1 78 1 70-130/20
100-41-4 Ethylbenzene 195 100 290 95 100 291 96 0 70-130/20
87-68-3 Hexachlorobutadiene ND 100 108 108 100 112 112 4 70-130/20
98-82-8 Isopropylbenzene 29.9 100 134 104 100 137 107 2 70-130/20
* = Outside of Control Limits.
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FA5850055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA58500
Account:GRINCC GRI (Geological Resources Inc.)
Project:Murfreesboro Bulk Plant; 862 W Main St, Murfreesboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA58500-2MS A0215630.D 10 10/19/18 AB n/a n/a VA2470
FA58500-2MSD A0215631.D 10 10/19/18 AB n/a n/a VA2470
FA58500-2 A0215621.D 5 10/19/18 AB n/a n/a VA2470
FA58500-2 A0215629.D 10 10/19/18 AB n/a n/a VA2470
The QC reported here applies to the following samples:Method: SM 6200B
FA58500-1, FA58500-2, FA58500-3, FA58500-4, FA58500-5, FA58500-6
FA58500-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene 3.6 100 114 110 100 115 111 1 70-130/20
74-83-9 Methyl Bromide ND 100 80.1 80 100 85.7 86 7 60-140/20
74-87-3 Methyl Chloride ND 100 93.7 94 100 106 106 12 60-140/20
74-95-3 Methylene Bromide ND 100 97.1 97 100 96.8 97 0 70-130/20
75-09-2 Methylene Chloride ND 100 86.2 86 100 89.1 89 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether 9.7 100 84.7 75 100 87.3 78 3 70-130/20
91-20-3 Naphthalene 245 a 100 366 121 100 367 122 0 70-130/20
103-65-1 n-Propylbenzene 77.1 100 182 105 100 185 108 2 70-130/20
100-42-5 Styrene ND 100 92.7 93 100 94.6 95 2 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 100 97.6 98 100 99.2 99 2 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 100 108 108 100 109 109 1 70-130/20
127-18-4 Tetrachloroethylene ND 100 95.2 95 100 98.0 98 3 70-130/20
108-88-3 Toluene 1.8 J 100 96.0 94 100 97.9 96 2 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 100 101 101 100 104 104 3 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 100 103 103 100 107 107 4 70-130/20
71-55-6 1,1,1-Trichloroethane ND 100 95.8 96 100 97.4 97 2 70-130/20
79-00-5 1,1,2-Trichloroethane ND 100 102 102 100 104 104 2 70-130/20
79-01-6 Trichloroethylene ND 100 94.0 94 100 96.0 96 2 70-130/20
75-69-4 Trichlorofluoromethane ND 100 96.4 96 100 113 113 16 60-140/20
96-18-4 1,2,3-Trichloropropane ND 100 102 102 100 104 104 2 70-130/20
95-63-6 1,2,4-Trimethylbenzene 190 100 296 106 100 297 107 0 70-130/20
108-67-8 1,3,5-Trimethylbenzene 20.7 100 130 109 100 133 112 2 70-130/20
75-01-4 Vinyl Chloride ND 100 86.3 86 100 102 102 17 60-140/20
m,p-Xylene 53.5 200 256 101 200 260 103 2 70-130/20
95-47-6 o-Xylene 2.4 J 100 98.2 96 100 100 98 2 70-130/20
1330-20-7 Xylene (total)56.0 300 354 99 300 360 101 2 70-130/20
CAS No.Surrogate Recoveries MS MSD FA58500-2 FA58500-2 Limits
1868-53-7 Dibromofluoromethane 99%98%98%99%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%102%104%104%70-130%
2037-26-5 Toluene-D8 97%97%95%98%70-130%
460-00-4 4-Bromofluorobenzene 104%104%104%106%70-130%
(a) Result is from Run #2.
* = Outside of Control Limits.
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