WA-29385_48541_CA_LSA_20220909

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

September 9, 2022

Ms. Anna Edwards
NCDEQ, UST Section
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: Phase I Limited Site Assessment Report
Johnny’s Convenience Mart
766 NC Highway 111
Goldsboro, Wayne County,
North Carolina
Incident Number: 48541
GRI Project Number: 6007

Dear Ms. Edwards,

Please find enclosed the referenced report for the above-mentioned site.

If you have any questions, please contact Scott Driscoll at 704.845.4010.

Sincerely,
Geological Resources, Inc.

Johanna Moats
AP/AR Coordinator

Enclosure

Cc. Mr. Jamal Bash, JB SZ LLC, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Phase I Limited Site Assessment Report
Johnny’s Convenience Mart
766 NC Highway 111
Goldsboro, Wayne County, North Carolina
Facility ID Number: 00-0-0000001576
Incident Number: 48541
GRI Project Number: 6007

Prepared for:

Mr. Jamal Bash
JB SZ LLC
1600 Tinos Overlook Way
Apex, North Carolina 27534

September 9, 2022

Scott Driscoll
Project Manager
William Regenthal, P. G.
Report Editor

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
i

EXECUTIVE SUMMARY
The Johnny’s Convenience Mart site is located at 766 NC Highway 111 in Goldsboro, Wayne County, North
Carolina. The property operates as a retail convenience store that uses USTs for storage and resale of
fuels. There are one 15,000-gallon and one 8,000-gallon gasoline USTs and associated piping and
dispensers are currently in use at the site. The site is covered by asphalt, concrete and grass.

A release was previously confirmed at the site in January 1995 during the removal of five USTs. NCDEQ
incident number 13668 was assigned. The USTs were owned and operated at the time by E.J. Pope & Son,
Inc. as part of the operation of the Handy Mart #25 business. In October 2012, E.J. Pope & Son, Inc.
received an NFA for the site. The site met the cleanup requirements for a low-risk site under the risk-
based assessment and corrective actions guidelines. A NRP was filed with the register of deeds and public
notice requirements were met, closing the incident.

In September 2021, NCDEQ conducted a UST compliance inspection at the site. Results of the paperwork
audit during the inspection noted a non-passing spill containment bucket test on the regular #1 gasoline
UST performed in 2018. The spill buckets were requested to be re-tested by NCDEQ. The spill buckets
were re-tested on October 1, 2021, and both the regular and premium spill buckets failed tightness tests.
The spill buckets were repaired and tested again on October 6, 2021, and received passing results. Based
on this information, NCDEQ requested that a site check be performed.

On April 13, 2022, GRI supervised the installation of one Type II monitoring well (GMW-1) adjacent to the
southwest end of the UST basin near the spill buckets. A soil sample was collected from the borehole at
a depth of 5 feet BGS during the installation of the well. All reported contaminant concentrations were
less than the applicable laboratory reporting limits for the soil sample.

A ground water sample was collected from the monitoring well and was submitted for laboratory
analyses. Concentrations of benzene, naphthalene, tert-amyl alcohol (TAA), tert-butyl alcohol (TBA) and
lead that exceeded the MACs were reported in the ground water sample collected from GMW-1. No
concentrations were reported above the GCLs and no free product was noted.
On August 17, 2022 an updated receptor survey was performed at the site. Public water is available to
the subject site and to all surrounding properties through the Eastern Wayne Sanitary District (EWSD),
PWS ID NC0496065. Thirteen non-potable wells were identified within 1,500 feet of the site. Calls were
placed to EWSD and active water accounts were associated with all the addresses where wells were
identified. No water supply wells were identified within a 250-foot radius of the site. EWSD receives its
water primarily from the Neuse River, however, the water supply is supplemented through wells. None
of the EWSD system wells are located within one mile of the site. The site is not located in a designated
wellhead protection area. No surface water bodies were identified within 500 feet of the site.

Based on this information, there does not appear to be evidence that the new release would change the

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
ii

risk ranking for the site, and the site should remain a low-risk site. GRI recommends closure of the
incident.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
iii

SITE INFORMATION
1. Site Identification
 Johnny’s Convenience Mart (Facility ID 00-0-0000001576)
 Incident Number 48541 – Risk Ranking Undetermined
 Location of Source Area: 766 NC Highway 111 (Figure 1)
Goldsboro, NC 27534
Wayne County
35.323353°N, 77.925849°W (GIS)
2. Information about Contacts Associated with the Leaking UST System (Table 1)

UST Owner
JBSZ LLC
1600 Tinos Overlook Way
Apex, NC 27520
[e-mail]
[phone]

UST Operator
JB SZ LLC
1600 Tinos Overlook Way
Apex, NC 27520
[e-mail]
[phone]

Property Owner
JB SZ LLC
1600 Tinos Overlook Way
Apex, NC 27520
[e-mail]
[phone]

Property Occupant
Johnny’s Convenience Mart
766 NC Highway 111
Goldsboro, NC 27530
Email: Unknown
[phone]

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
[phone]

Analytical Laboratory
SGS North America, Inc.
4405 Vineland Road, C-15
Orlando, Fla
[phone]
NC Certification No. 573

3. Information about Release
 Suspected release of petroleum from operation of the UST(s) at the site. One 15,000-gallon and one
8,000-gallon gasoline USTs are currently in use at the site. Refer to Table 1 and 2 for UST history and
ownership information.
 On September 13, 2021, NCDEQ conducted a UST compliance inspection at the site. Results of the
paperwork audit during the inspection noted a non-passing spill containment bucket test. Retesting was
completed by a third party and confirmed the results. The spill buckets were re-tested after repairs
were completed with passing results.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
iii

ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
SWAPR: Source Water Assessment Program
Report
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007

TABLE OF CONTENTS

EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iii
1. RISK CHARACTERIZATION .....................................................................................................1
2. RECEPTOR INFORMATION .....................................................................................................3
3. SITE GEOLOGY AND HYDROGEOLOGY ...................................................................................4
4. SITE INVESTIGATION .............................................................................................................5
5. CONCLUSIONS AND RECOMMENDATIONS ............................................................................6
6. LIMITATIONS ........................................................................................................................6

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Zoning Map
Figure 4: Site Map
Figure 5: Soil Quality Map
Figure 6: Ground Water Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Receptor Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Soil Sample Analytical Results
Table 7: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: Wayne County Property Cards
Appendix B: NCDEQ Correspondence
Appendix C: Site Check Report with Previous Analytical Data

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
1
1. RISK CHARACTERIZATION
Limited Site Assessment Risk Classification and Land Use Form
Part I – Groundwater/Surface Water/Vapor Impacts
High Risk
1. Has the release contaminated any water supply well including any well used for non-drinking
purposes? NO

2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the
release? NO

3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial cooling
water, filling swimming pools) located within 250 feet of the source area of the release?
NO

4. Does ground water within 500 feet of the source area of the release have the potential for future
use (there is no other source of water supply other than the groundwater)? NO

Public water is available through Eastern Wayne Sanitary District to the site and surrounding
properties.

5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a
confined space or pose any other serious threat to public health, public safety or the
environment?
NO

6. Are there any other factors that would cause the release to pose an imminent danger to public
health, public safety, or the environment? NO
If YES, explain:

Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the release? NO

If YES, does the maximum groundwater contaminant concentration exceed the surface water
quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10? N/A

8. Is the source area of the release located within an approved or planned wellhead protection area
as defined in 42 USC 300h-7(e)? NO

9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled
“Geology of North Carolina” published by the Department in 1985? YES

10. If YES, is the source area of the release located in an area in which there is recharge to an
unconfined or semi-confined deeper aquifer that is being used or may be used as a source of
drinking water? NO
If YES, describe.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
2
11. Do the levels of ground water contamination for any contaminant exceed the gross contamination
levels established by the Department? NO

Part II - Land Use
Property Containing Source Area of Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)? NO
Explain:

2. Does the property contain a school, daycare center, hospital, playground, park, recreation area,
church, nursing home, or other place of public assembly? NO
Explain:

3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.) or
industrial (e.g., manufacturing, utilities, industrial research and development,
chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial or industrial
enterprise, or is the land undeveloped? YES
Explain:
The subject property is an active retail business and convenience store.

4. Do children visit the property? YES
Explain:
The site is currently a convenience store and children would likely visit the property.

5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security
personnel or both)? NO
Explain:
The property is easily accessible to pedestrian and vehicular traffic.
6. Do pavement, buildings, or other structures cap the contaminated soil? YES
Explain:
The UST equipment at the site is currently covered by concrete and asphalt.

If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil
will remain capped in the foreseeable future?
The site is expected to remain in operation as an active convenience store and UST facility in the
near future.
7. What is the zoning status of the property?
According to the Wayne County GIS webpage, the site is zoned CS (Community Shopping).
(Figures 2 and 3).

8. Is the use of the property likely to change in the next 20 years? NO

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
3
Explain:

The subject property is currently an active convenience store and likely remain a convenience
store in the near future.
Property Surrounding Source Area of Release
The questions below pertain to the area within 1,500 feet of the source area of the release (excludes
property containing source area of the release):

9. What is the distance from the source area of the release to the nearest primary or secondary
residence (permanent or temporary)?

The closest primary residence is located 250 feet west of the site at 119 Forest Knolls Road.

10. What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home or other place of public
assembly?

The Goldsboro School of Ballet is located at 782 NC Highway 111 approximately 200 feet south of
the site.

11. What is the zoning status of properties in the surrounding area?

According to the Wayne County GIS webpage, the surrounding properties are zoned R-30. The R-
30 District is intended to promote a compatible mixture of single family residential and
agricultural use areas.

12. Briefly characterize the use and activities of the land in the surrounding area.

The area surrounding the site is a mixture of commercial and residential. Land use information
has been included in Figures 2 and 3.

2. RECEPTOR INFORMATION
1. Water Supply Wells:
On August 17, 2022, an updated receptor survey was conducted. Public water is available to the
subject site and to all surrounding properties through the Eastern Wayne Sanitary District (EWSD),
PWS ID NC0496065. Thirteen non-potable wells were identified within 1,500 feet of the site. Calls
were made to EWSD and active water accounts were associated with all of the addresses where
wells were identified. No water supply wells were identified within a 250-foot radius of the site.
EWSD receives its water primarily from the Neuse River, however, the water supply is
supplemented through wells. None of the EWSD system wells are located within one mile of the
site. The site is not located in a designated wellhead protection area. A Site Location Map is
provided as Figure 1 and a Site Vicinity Map showing property boundaries for the site and
surrounding properties has been included as Figure 2 and 3. Water supply well information has
been provided in Table 3.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
4

2. Public Water Supplies:
Are public water supplies available within 1,500 feet of the source area of the release? YES
If yes, where is the location of the nearest public water lines and the source(s) of the public water
supply. Explain:
Municipal water is available to the site and the surrounding properties. Water lines run along the
public streets in the area. Public water is supplied by the EWSD.

3. Surface Water:
Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the
source area of the release. This information must be shown on the USGS topographic map.
One drainage feature and associated low lying area was identified approximately 800 feet north
of the site and is identified as Fellows Branch (Figure 2 and 3).

4. Wellhead Protection Areas:
Identify all planned or approved wellhead protection areas in the vicinity of the source area. This
information must be shown on the USGS topographic map. Wellhead protection areas are defined
in 42 USC 300h-7(e).
The site is not located in a wellhead protection area.

5. Deep Aquifers in the Coastal Plain Physiographic Region:
The site is located in the Coastal Plain Physiographic Region. The surficial aquifer in the vicinity of
the site is underlain by the Black Creek Upper confining unit and Black Creek aquifer respectively.

6. Subsurface Structures:
No structures with basements were identified in the vicinity of the source area. Underground
utilities run along NC-111 and Spring Bank Road.

7. Property Owners and Occupants:
The names and addresses of the owners of properties adjacent to the site are presented in Table
4. Property boundaries are shown on Figure 2 and 3. Property cards for the adjacent property
owners are attached as Appendix A.

3. SITE GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is located in the Black Creek Formation.
The formation is generally described as greenish gray to black lignitic clays interbedded with lenses of fine
grained sands. The surficial aquifer at the site is estimated to be approximately 30 feet thick and underlain
by the upper confining unit of the Black Creek and Black Creek aquifer respectively. The site is located
approximately 120 feet above mean sea level. On April 13, 2022, GRI supervised the installation of one
Type II monitoring well (GMW-1) adjacent to the southwest end of the UST basin. Ground water was
encountered at a depth of 9.31 feet below the top of well casing. Copies of the well construction record

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
5
and subsurface log are included in the May 2022 Site Check report and are summarized in Table 5. A Site
Map showing the location of GMW-1 is included as Figure 4.

4. SITE INVESTIGATION
On March 31, 2022, GRI supervised the installation of a soil boring in the vicinity of the non-passing spill
buckets to satisfy Site Check requirements. Pea gravel was encountered during the attempt to install the
soil boring; therefore, a Type II monitoring well would be necessary to collect the samples to satisfy the
site check requirement. On April 13, 2022, GRI supervised the installation of one Type II monitoring well
(GMW-1) adjacent to the southwest end of the UST basin. One soil sample was collected during from the
borehole during the installation of the well at a depth of 5 feet BGS. The soil sample was submitted for
laboratory analyses of VOCs using EPA Method 8260B and VPH using the MADEP Method.

A ground water sample was collected from GMW-1 on the same date and was submitted for laboratory
analyses of VOCs + oxygenates by EPA Method 6200B, EDB by EPA Method 504.1, total lead by EPA
Method 6010 and VPH by the MADEP Method.

On August 17, 2022, an updated receptor survey was conducted within 1,500 feet of the site. It was found
that public water is available to the subject site and to all surrounding properties through the Eastern
Wayne Sanitary District (EWSD); PWS ID NC0496065. Thirteen non-potable wells were identified within
1,500 feet of the site. Calls were made to EWSD and active water accounts were associated with all of the
addresses where wells were identified. No water supply wells were identified within a 250-foot radius of
the site. EWSD receives its water primarily from the Neuse River, however, the water system is
supplemented through wells. None of the EWSD system wells are located within one mile of the site. The
site is not located in a designated wellhead protection area. One drainage ditch and associated low lying
area, identified as Fellows Branch, lies approximately 800 feet north of the site.

4.1 Previous Soil Sampling – Site Check:
All reported contaminant concentrations in the soil sample collected from the borehole of GMW-1 were
less than applicable laboratory reporting limits. A soil quality map is presented as Figure 5. A summary
of soil sample analytical results is presented in Table 6. An abbreviated summary of the results is below.
Sample ID Sample Depth (ft-BGS) Benzene Toluene Ethylbenzene Xylenes RAL (mg/kg) NE NE NE NE
Soil to Water MSCC 0.0072 5.4 8 6
Residential SCLs 12 1,250 60.3 3,120
GMW-1-5 5 <0.00120 <0.010 <0.0010 <0.0021

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
6
4.2 Previous Ground Water Sampling – Site Check:
Concentrations of benzene, naphthalene, tert-amyl alcohol (TAA), tert-butyl alcohol (TBA) and lead that
exceeded the MACs were reported in the ground water sample collected from GMW-1. No concentrations
were reported above the GCLs, and no free product was noted at the site. A summary of the analytical
results for ground water samples collected on April 13, 2022, is presented in Table 7. A Ground Water
Quality Map is included as Figure 6. An abbreviated summary of the ground water analytical data is
shown below:

Contaminant of
Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well ID
MAC (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 84,500 85,500 20,000 6,000
GMW-1 73.0 28.4 46.2 144 8.2 29.1
Trip Blank <0.13 <0.13 <0.13 <0.25 <0.13 <0.13

The complete report of laboratory analyses from the soil and ground water samples collected from the
monitoring well is included in the May 2022 Site Check report included as Appendix C. Please note, no
soil or ground water sampling was conducted during the August 2022 LSA activities.

5. CONCLUSIONS AND RECOMMENDATIONS
 On September 13, 2021, NCDEQ conducted a UST compliance inspection at the site. Results of the
paperwork audit noted a non-passing spill containment bucket test for the regular #1 gasoline UST
from 2018. Both the regular and premium spill buckets failed tightness tests conducted on October
1, 2021. The spill buckets were repaired and tested again on October 6, 2021, with passing results.
 On April 13, 2022, GRI supervised the installation of one Type II monitoring well adjacent to the
southwest end of the tank basin near the spill buckets. Ground water was encountered at a depth
of 9.31 feet below the top of well casing. A ground water sample collected from GMW-1 revealed
concentrations of benzene, naphthalene, TAA, TBA and lead that exceeded the MACs. No
concentrations were reported above the GCLs and no free product was noted.
 One soil sample (GMW-1-5’) was collected during the installation of GMW-1 at a depth of 5 feet BGS.
All of the reported contaminant concentrations in the soil sample collected from the GMW-1
borehole were less than the applicable laboratory reporting limits for the analyses.
 Based on this information, there does not appear to be evidence that the new release at the site
would change the risk ranking for the site, and the site should remain a low-risk site. GRI
recommends that the incident should be closed.
6. LIMITATIONS
This report has been prepared for the exclusive use of JB SZ LLC for specific application to the referenced
site in Wayne County, North Carolina. The assessment was conducted based on the scope of work and
level of effort specified by NCDEQ and with resources adequate only for that scope of work. Our findings

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: September 9, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
7
have been developed in accordance with generally accepted standards of geology and hydrogeology
practices in the State of North Carolina, available information and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site LocationJohnny’s Convenience Mart, Inc766 NC Highway 111 SouthGoldsboro, North CarolinaWayne CountyIncident No. 13668GRI Project No. 6007500 M2000 FTDate: 05/10/2022Location: 35.323353° N -77.925849° W Dad
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3517938796
3527030969
3527040599
3527040262
3527032319
3527042316
35270348093517939951
3517948908
3517956044
352704118235270441853527033627
3517938477
3527032588 3527045338WSW-9
WSW-8
WSW-7
WSW-6
WSW-5
WSW-4
WSW-3
WSW-2
WSW-1
WSW-13
WSW-12
WSW-11
WSW-10
UtF ellows B r anc h
S NC 111 HWYDALLAS RD
DOLLARD TOWN RD
S P R IN G B A N K R D
ANN STCOLONIAL DR
FOREST KNOLLS RD
GRANT DREARL RDROUSE STMANSION LNWINDSOR DRRUBY RDLAMM DRMERRITT LNMARLETTE DRBROOKWOOD DRCOLONIAL CT
OAK CIRCLE DRGARDEN CIRCURLEW STTHRASHER CIRFIG JOHNNY'S CONVENIENCE MART, INC.766 NC HIGHWAY 111 SOUTHGOLDSBORO, WAYNE COUNTYNORTH CAROLINAINCIDENT NO. 13668GRI PROJECT NO. 6007
PREPARED BY:GEOLOGICAL RESOURCES, INC.AUGUST 29, 2022
³
0 300150Feet
1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
LEGEND
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Wayne_County_Centerlines
All_Ditches_Streams_Rivers
Hydrology
Well Owners and Adjacent Properties
Wayne_County_Parcels
URE 2: SITE VICINITY MAP
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WSW-12
WSW-11
WSW-10
UtF ellows B r anc h
S NC 111 HWYDALLAS RD
DOLLARD TOWN RD
S P R IN G B A N K R D
ANN STCOLONIAL DR
FOREST KNOLLS RD
GRANT DREARL RDROUSE STMANSION LNWINDSOR DRRUBY RDLAMM DRMERRITT LNMARLETTE DRBROOKWOOD DRCOLONIAL CT
OAK CIRCLE DRGARDEN CIRDUTCH PINES CT
CURLEW STTHRASHER CIR FIGURE 3: ZONING MAPJOHNNY'S CONVENIENCE MART, INC.766 NC HIGHWAY 111 SOUTHGOLDSBORO, WAYNE COUNTYNORTH CAROLINAINCIDENT NO. 13668GRI PROJECT NO. 6007
PREPARED BY:GEOLOGICAL RESOURCES, INC.AUGUST 29, 2022
³
0 300150Feet
1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
LEGEND
"J Water Supply Well
Wayne_County_Centerlines
All_Ditches_Streams_Rivers
ZONING - RA-30
ZONING - RA-20
ZONING - CS
Hydrology
Wayne_County_Parcels

TABLES
UST ID Number 1 & 2 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1 & 2 Facility ID Number
Owner or Operator?
Owner/Operator
TABLE 1
UST OWNER/OPERATOR INFORMATION
JOHNNY'S CONVENIENCE MART (INCIDENT 48541)
Address Telephone Number
Name of Owner or Operator Dates of Ownership / Operation
00-0-0000001576
JB SZ LLC 8/15/2011 - Current
PO Drawer 649, Mount Olive, NC 28365 919-658-6566
1600 Tinos Overlook Way, Apex, NC 27520 [phone]
00-0-0000001576
E.J. Pope & Son, Inc.(Install) 02/7/1995 - 08/15/2011
Address Telephone Number
Name of Owner or Operator Dates of Ownership / Operation
Page 1 of 1
Date: 08/31/22 Facility ID #: 00-0-0000001576
Was Release
Associated
with UST
System?
(Yes / No)
1 (A1)Gasoline NA 15,000 02/07/1995 SW Steel/FRP 8' x 26' 8"DW Flex Current Yes
2 (A2)Gasoline NA 8,000 02/07/1995 Sw Steel/FRP 8' x 16'DW Flex Current Yes
005 Unknown Unknown 1,000 1/1/1964 Unknown Unknown Unknown Removed No
004 Unknown Unknown 750 1/1/1964 Unknown Unknown Unknown Removed No
003 Gasoline NA 3,000 2/29/1980 Single Wall Steel Unknown Unknown Removed No
002 Gasoline NA 6,000 3/1/1977 Single Wall Steel Unknown Unknown Removed No
001 Gasoline NA 6,000 3/1/1977 Single Wall Steel Unknown Unknown Removed No
UST
ID
No.
TABLE 2
UST SYSTEM INFORMATION
JOHNNY'S CONVENIENCE MART (INCIDENT NO. 48541)
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Facility ID # : 00-0-0000001576
Well ID.Parcel ID No.Well Owner Mailing Address Well Address
Well Status
(Active/In-
Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected to
Public Water
Yes/No
Distance from
source of
release
(ft.)
WSW-1 3527040599 Walker Jeffrey Lee Etal 516 Spring Bank Road,
Goldsboro, NC 119 Forest Knolls Road Unknown Non-Potable Yes Yes ~275 W
WSW-2 3527041182 Franklin Craig B 782 NC Highway 111,
Goldsboro, NC 798 NC Hwy 111 Unknown Non-Potable Yes Yes ~400 S
WSW-3 3527030969 New Hope Grange Unknown 804 NC Hwy 111 Unknown Non-Potable Yes Yes ~550 S
WSW-4 3517939951 Daly Lilly G 812 NC Hwy 111, Goldsboro,
NC 812 NC Highway 111 Unknown Non-Potable Yes Yes ~625 S
WSW-5 3517938796 Pride House Family Holdings 2903 McLain Street, Goldsboro,
NC NC Hwy 111 Unknown Non-Potable Yes Yes ~800 S
WSW-6 3517938477 Wheeler Jame Michael 846 NC Highway 111,
Goldsboro, NC 846 NC Highwa=y 111 Unknown Non-Potable Yes Yes ~1,100 S
WSW-7 3527032319 Malpass Christopher Barrett 75 Snipes Road, Hurdle Mills, NC 835 NC Highway 111 Unknown Non-Potable Yes Yes ~1,100 S
WSW-8 3527032588 Soria Joge Luis 222 Greenfield Cemetary Road,
Seven Springs, NC 827 NC Highway 111 Unknown Non-Potable Yes Yes ~850 S
WSW-9 3527033627 Norwood Toony Gregg 815 NC Highway 111,
Goldsboro, NC 815 NC Highway 111 Unknown Non-Potable Yes Yes ~800 S
WSW-10 3527039615 Boyd Brooke Patton 158 Dallas Road, Goldboro, NC 158 Dallas Road Unknown Non-Potable Yes Yes ~1025 SE
WSW-11 3527130600 Moore Earnest Percy 170 Dallas Road, Goldsboro, NC 170 Dallas Road Unknown Non-Potable Yes Yes ~1075 SE
WSW-12 3517948908 Jones Gregory O 154 Forest Knolls Road,
Goldsboro, NC
138/154/158 Forest Knolls
Road Unknown Non-Potable Yes Yes ~700 NW
WSW-13 3517956044 Moye Betty C Etal 450 NC Highway 111 S,
Goldsboro, NC 162 Forest Knolls Road Unknown Non-Potable Yes Yes ~800 S
Receptor ID
Latitude/
Longitude of
Any
Significant
Points
Distance from
the source area
of release (ft.)
Surface Water NA ~800' N
Notes:
• Receptors are shown on Figure 3.
• n/a: not applicable.
Unknown
TABLE 3
RECEPTOR INFORMATION
JOHNNY'S CONVENIENCE MART (48541)
Date: 09/2/22
Well Construction Details
(Depth, Screened Interval,
Type of Well, ect.)
Unknown
Unknown
Unknown
Unknown
Description Location Contact/Phone Number Usage
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Fellows Branch North NA Drainage Ditch/Low Lying Area
Date: 09/02/22 Facility ID #: 00-0-0000001576
PIN Number Property Owner Name Property Owner Address
3527042316 JB SZ LLC (Site)766 NC Highway 111 S, Goldsboro, NC
3527044185 Scott Joe Hart PO Box 263, Rose Hill, NC
3527040262 Cemetary Unknown (Not Listed)
3527042870 Walker Jeffrey Lee 516 Spring Bank Road, Goldsboro, NC
3527040599 Walker Jeffrey Lee 516 Spring Bank Road, Goldsboro, NC
3527041182 Franklin Craig B 782 NC Highway 111, Goldsboro, NC
3527158685 Maxwell Foods LLC PO Box 10009, Goldsboro, NC
3527045338 Scott Joe Hart PO Box 263, Rose Hill, NC
Note:
• Properties are keyed to Figure 2.

TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
JOHNNY'S CONVENIENCE MART (INCIDENT NO. 48541)
Date: 04/13/2022 Facility ID # : 00-0-0000001576
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)BenzeneTolueneEthylbenzeneXylenesMTBENaphthaleneC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics0.0072 5.4 8 6 0.085 0.2 68 540 31
12 1,250 60.3 3,120 156 5.5 625 1,500 469
GMW-1 04/13/22 5 <0.0012 <0.010 <0.0010 <0.0021 <0.0010 <0.0020 <1.9 <1.9 <1.9
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• Trip Blank results reported in ug/l (micrograms per liter)
• ft-BGS: feet below ground surface.
• MCCs: Maximum Contaminant Concentrations (soils).
• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type indicate the reported concentration exceeded the soil-to-water MCC.
• Concentrations in italics indicate the reported concentration exceeded the residential SCL.
Soil to Water MCC (mg/kg)
Residential SCLs (mg/kg)
TABLE 5
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
JOHNNY'S CONVENIENCE MART (INCIDENT 48541)
Analytical Method EPA Method 8260B MADEP VPH
Page 1 of 1
Date: 05/03/2022 Facility ID # : 00-0-0000001576
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
Thickness
(ft.)
Ground
Water
Elevation (ft.)
Comments
GMW-1 04/13/22 04/13/22 5 5 - 15 15 100.00 9.31 ---90.69
Notes:
• Elevation not relative to mean sea level.
• ft BGS : feet below ground surface.
TABLE 6
WELL CONSTRUCTION AND GAUGING INFORMATION
JOHNNY'S CONVENIENCE MART, INC. (INCIDENT NO. 48541)
Page 1 of 1
Date: 05/03/2022 Facility ID # : 00-0-0000001576
EPA
504.1 EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 0.02 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 50 15,000 NE NE NE
GMW-1 04/13/22 73.0 28.4 46.2 144 8.2 29.1 541 512 <0.0095 281 <35 <35 166
Trip Blank 04/13/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the MAC was below the reported concentration.
• J: Estimated value.
• NR: Not requested.
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.
MAC (μg/l)
GCL (μg/l)MTBENaphthaleneContaminant of Concern
BenzeneTolueneEthylbenzeneXylenesTABLE 7
GROUND WATER SAMPLE ANALYTICAL RESULTS
JOHNNY'S CONVENIENCE MART, INC. (INCIDENT NO. 48541)
Analytical Method
1,2-Dibromoethane(EDB)MADEP VPH
LeadC5-C8 AliphaticsC9-C12 AliphaticsC9-C12 AromaticsEPA 6200B
tert-Butyl alcohol(TBA)tert-Amyl alcohol(TAA)Page 1 of 1

APPENDICES

APPENDIX A
Wayne County Property Cards

APPENDIX B
NCDEQ Correspondence
NCDEQ Registered Tank Report
Facility Id 00-0-0000001576
Facility Name JOHNNY'S CONVENIENCE MART INC
Address 766 NC HIGHWAY 111 SOUTH
City GOLDSBORO State NC
Zip 27530County Wayne
Latitude 35.32367Longitude-77.92633
Tank Owner JB SZ LLC
Address 1600 TINOS OVERLOOK WAY
City APEX
State NC Zip 27502
Tank Information
Tank Id Product Name Capacity Installation Date Perm Close Date Tank Construction Piping Construction OverFill Protection Spill Protection Tank Status
A2 Gasoline, Gas Mix 8000 2/7/1995 Single Wall Steel/F Single Wall Steel Auto Shutoff Device Catchment Basin Current
A1 Gasoline, Gas Mix 15000 2/7/1995 Single Wall Steel/F Single Wall Steel Auto Shutoff Device Catchment Basin Current
005 Unknown 1000 1/1/1964 1/30/1995 Unknown Unknown Unknown Unknown Removed
004 Unknown 750 1/1/1964 1/30/1995 Unknown Unknown Unknown Unknown Removed
003 Gasoline, Gas Mix 3000 2/29/1980 1/30/1995 Single Wall Steel Other Auto Shutoff Device Catchment Basin Removed
002 Gasoline, Gas Mix 6000 3/1/1977 1/30/1995 Single Wall Steel Other Auto Shutoff Device Catchment Basin Removed
001 Gasoline, Gas Mix 6000 3/1/1977 1/30/1995 Single Wall Steel Other Auto Shutoff Device Catchment Basin Removed
Monday, May 2, 2022 Page 1 of 1

APPENDIX C
Site Check Report - Previous Analytical Data

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

May 18, 2022

Mr. Jared Edwards
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: Site Check Report
Johnny’s Convenience Mart
766 NC Highway 111
Goldsboro, Wayne County
North Carolina
Facility ID Number: 00-0-0000001576
Incident Numbers: Pending
GRI Project Number: 6007

Dear Mr. Edwards,

Please find enclosed the referenced report, for the above mentioned site.
If you have any questions, please contact Scott Driscoll at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Jamal Bash; JB SZ LLC, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Site Check Report
Johnny’s Convenience Mart
766 NC Highway 111
Goldsboro, Wayne County, North Carolina
Facility ID Number: 00-0-0000001576
Incident Number: Pending
GRI Project Number: 6007

Prepared for:

Mr. Jamal Bash
JB SZ LLC
1600 Tinos Overlook Way
Apex, North Carolina 27534

May 13, 2022

Scott Driscoll
Project Manager
William Regenthal, P.G.
Project Manager

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 13, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
ii
EXECUTIVE SUMMARY
The Johnny’s Convenience Mart site is located at 766 NC Highway 111 in Goldsboro, Wayne County, North
Carolina. The property operates as a petroleum retail facility and convenience store. The site is covered
by asphalt, concrete and grass. There are one 15,000-gallon and one 8,000-gallon gasoline USTs and
associated piping and dispensers in use at the site. One 750-gallon unknown contents, one 1,000-gallon
unknown contents, one 3,000-gallon gasoline and two 6,000-gallon gasoline USTs were removed from the
site in January 1995. Incident Number 13668 was issued following the January 1995 UST closure activities
and was closed in October 2012 upon the filing of a ground water NRP.

On September 13, 2021, NCDEQ conducted a UST compliance inspection at the site. Results of the
paperwork audit during the inspection noted a non-passing spill containment bucket test on the regular
#1 gasoline UST performed in 2018. The spill buckets were requested to be re-tested by NCDEQ. The spill
buckets were tested on October 1, 2021, and both the regular and premium spill buckets failed tightness
tests. The spill buckets were repaired and tested again on October 6, 2021, and received passing results.
Based on this information, NCDEQ requested that a site check be performed.

On March 31, 2022, GRI supervised the installation of soil borings in the vicinity of the spill buckets to
satisfy the site check requirement. Pea gravel was encountered during the attempt to so install the soil
borings; therefore, the installation of a Type II monitoring well and collection of a ground water sample
would be necessary to satisfy the site check requirement.

On April 13, 2022, GRI supervised the installation of one Type II monitoring well adjacent to the southwest
end of the UST basin near the spill buckets. Ground water was encountered at a depth of 9.31 feet below
the top of well casing. One soil sample (GMW-1-5’) was collected from a depth of 5 feet during the
installation of GMW-1. The soil sample was submitted for laboratory analyses of VOCs by EPA Method
8260B and VPH using the MADEP Method. All of the reported contaminant concentrations were less than
the applicable laboratory reporting limits for the soil sample.

A ground water sample was collected from the monitoring well, and was submitted for laboratory
analyses of VOCs + oxygenates using EPA Method 6200B, EDB by EPA Method 504.1, total lead by EPA
Method 6010 and VPH by the MADEP Method. Concentrations of benzene, naphthalene, tert-amyl
alcohol (TAA), tert-butyl alcohol (TBA) and lead that exceeded the MACs were reported in the ground
water sample collected from GMW-1. No concentrations were reported above the GCLs and no free
product was noted.

Based on this information, there does not appear to be evidence of a new release at the site that would
change the current risk ranking. In order to confirm the risk ranking, an updated receptor survey could
be completed prior to NCDEQ issuing a NFA for the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 13, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 13, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007

TABLE OF CONTENTS

SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
A. SITE HISTORY AND CHARACTERIZATION ......................................................................................1
B. SITE CHECK PROCEDURES ............................................................................................................2
C. SITE INVESTIGATION ...................................................................................................................3
D. SUMMARY AND CONCLUSIONS ...................................................................................................4
E. LIMITATIONS ..............................................................................................................................4

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Soil Quality Map
Figure 4: Ground Water Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Well Construction Information
Table 4: Summary of Soil Sample Analytical Results
Table 5: Summary of Ground Water Analytical Results

APPENDICES
Appendix A: State Correspondence
Appendix B: Well Construction Record and Boring Log
Appendix C: Site Specific Health and Safety Plan
Appendix D: Laboratory Report – Soil and Ground Water Samples

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 13, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
1
A. SITE HISTORY AND CHARACTERIZATION
1. UST Owner and Operator Information:
In accordance with the Site Check Report guidelines, the UST owner and operator information has been
summarized in the attached Table 1.

2. UST System Information:
There are one 15,000-gallon and one 8,000-gallon gasoline USTs, associated product piping and
dispensers in use at the site. One 750-gallon unknown contents, one 1,000-gallon unknown contents,
one 3,000-gallon gasoline and two 6,000-gallon gasoline USTs were removed from the site in January
1995. The dispenser island is located on the northeast portion of the site near the intersection of NC
Highway 111 and Spring Bank Road. The UST system information is summarized in Table 2. A copy of
the NCDEQ Registered Tank Report is shown below:

In October 2012, the site, then operated by E.J. Pope & Son, Inc. as the Handy Mart #25, received an NFA
under 15A NCAC 2L .0407 (d). The site met the cleanup requirements for a low-risk site under the risk-
based assessment and corrective actions. A NRP was filed with the register of deeds and public notice
requirements were met closing the incident. A copy of the NCDEQ correspondence is included in

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 13, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
2
Appendix A.

3. Non-UST Information:
No ASTs are currently located at the site.

4. Comprehensive Description of the Release:
On September 13, 2021, NCDEQ conducted a UST compliance inspection at the site. Results of the
paperwork audit during the inspection noted a non-passing spill containment bucket test for the regular
#1 gasoline UST that was performed in 2018. The spill buckets were requested to be re-tested by NCDEQ.
Superior Services tested the spill buckets on October 1, 2021, and both the regular and premium spill
buckets failed tightness tests. The spill buckets were repaired and tested again on October 6, 2021, by
Quality Maintenance Service with passing results. Based on this information, NCDEQ requested that a
site check be performed.

5. Description of the Site Characteristics:
The Johnny’s Convenience Mart site is located at 766 NC Highway 111 in Goldsboro, Wayne County, North
Carolina (Figure 1). The property operates as a petroleum retail facility and convenience store. The site
is covered by asphalt, concrete and grass. One 15,000-gallon gasoline, and one 8,000-gallon gasoline USTs
and associated product piping and dispensers are operated at the site. One 750-gallon unknown contents,
one 1,000-gallon unknown contents, one 3,000-gallon gasoline and two 6,000-gallon gasoline USTs were
removed from the site in January 1995. The surrounding properties are mainly residential and light
commercial/business. A Site Map has been included as Figure 2.

B. SITE CHECK PROCEDURES
1. Summary of Site Check Procedure:
On March 31, 2022, GRI supervised the installation of a soil boring in the vicinity of the non-passing spill
buckets in order to satisfy the Site Check requirements. Pea gravel was encountered during the attempt
to so install the soil borings; therefore, a Type II monitoring well would be necessary to take the samples
to satisfy the site check requirements.

On April 13, 2022, GRI supervised the installation of one Type II monitoring well adjacent to the southwest
end of the UST basin near the spill buckets. Ground water was encountered at a depth of 9.31 feet below
the top of well casing. Well construction information is contained in Table 3. The location of the well is
shown on Figure 2. A well construction record and boring log are included in Appendix B. A copy of the
site specific Health and Safety Plan is included as Appendix C.

2. Soil Excavation Activities:
No soil excavation activities were conducted by GRI.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 13, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
3
C. SITE INVESTIGATION
1. Field Screening:
The soil sample collected during the April 13, 2022 Site Check activities was not screened with a PID.

2. Soil Sampling Information:
One soil sample (GMW-1-5’) was collected during the installation of GMW-1 at a depth of 5 feet BGS on
April 13, 2022, and was submitted for laboratory analyses of VOCs using EPA Method 8260B and VPH
using the MADEP Method. All of the reported contaminant concentrations were less than the applicable
laboratory reporting limits for the analyses. A soil quality map is presented as Figure 3. A summary of
soil sample analytical results is presented in Table 4. The laboratory report is provided as Appendix D.
An abbreviated summary of the soil analytical results is below.
Sample ID Sample Depth (ft-BGS) Benzene Toluene Ethylbenzene Xylenes RAL (mg/kg) NE NE NE NE
Soil to Water MSCC 0.0072 5.4 8 6
Residential SCLs 12 1,250 60.3 3,120
GMW-1-5 5 <0.00120 <0.010 <0.0010 <0.0021

3. Ground water Sampling Information
A ground water sample was collected from GMW-1 on April 13, 2022, and was submitted for laboratory
analyses of VOCs + oxygenates by EPA Method 6200B, EDB by EPA Method 504.1, total lead by EPA
Method 6010 and VPH by the MADEP Method. Concentrations of benzene, naphthalene, tert-amyl alcohol
(TAA), tert-butyl alcohol (TBA) and lead that exceeded the MACs were reported in the ground water
sample collected from GMW-1. No concentrations were reported above the GCLs, and no free product
was noted at the site. A summary of the analytical results for ground water samples collected on April 13,
2022, is presented in Table 5. A Ground Water Quality Map based on the April 2022 data is included as
Figure 4. The complete report of laboratory analyses of the ground water samples collected from the
monitoring wells is included as Appendix D. An abbreviated summary of the current ground water
analytical data is shown below:

Contaminant of
Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well ID
MAC (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 84,500 85,500 20,000 6,000
GMW-1 73.0 28.4 46.2 144 8.2 29.1
Trip Blank <0.13 <0.13 <0.13 <0.25 <0.13 <0.13

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 13, 2022 Johnny’s Convenience Mart
Project Manager: Scott Driscoll GRI Project No. 6007
4
4. Quality-Control Measures:
Decontaminated drill and sampling barrels and clean, disposable nitrile gloves were used for the
collection of the soil sample and ground water samples. The samples were collected in laboratory
supplied containers and strict chain-of-custody procedures were followed.
D. SUMMARY AND CONCLUSIONS
 On September 13, 2021, NCDEQ conducted a UST compliance inspection at the site. Results of the
paperwork audit noted a non-passing spill containment bucket test for the regular #1 gasoline UST
from 2018. Both the regular and premium spill buckets failed tightness tests conducted on October
1, 2021. The spill buckets were repaired and tested again on October 6, 2021, with passing results.
 On March 31, 2022, GRI supervised the installation of a soil boring in the vicinity of the non-passing
spill buckets. Pea gravel was encountered and a soil sample could not be collected. A Type II
monitoring well was required to be installed in order to satisfy the Site Check requirements.
 On April 13, 2022, GRI supervised the installation of one Type II monitoring well adjacent to the
southwest end of the tank basin near the spill buckets. Ground water was encountered at a depth
of 9.31 feet below the top of well casing. One soil sample (GMW-1-5’) was collected during the
installation of GMW-1 at a depth of 5 feet BGS.
 All of the reported contaminant concentrations in the soil sample collected from GMW-1-5’ were
less than the applicable laboratory reporting limits for the analyses.
 Concentrations of benzene, naphthalene, TAA, TBA and lead that exceeded the MACs were reported
in the ground water sample collected from GMW-1 on April 13, 2022. No concentrations were
reported above the GCLs and no free product was noted.
 Based on this information, there does not appear to be evidence of a new release at the site that
would change the current risk ranking. In order to confirm the risk ranking, an updated receptor
survey could be completed prior to NCDEQ issuing a NFA for the site.
E. LIMITATIONS
This report has been prepared for the exclusive use of JB SZ LLC for the specific application to the
referenced site in Wayne County, North Carolina. The assessment was conducted based on the scope of
work and level of effort specified by NCDEQ and with resources adequate only for that scope of work. Our
findings have been developed in accordance with generally accepted standards of geology and
hydrogeology practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site LocationJohnny’s Convenience Mart, Inc766 NC Highway 111 SouthGoldsboro, North CarolinaWayne CountyIncident No. 13668GRI Project No. 6007500 M2000 FTDate: 05/10/2022Location: 35.323353° N -77.925849° W Dad

TABLES
UST ID Number 1 & 2 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1 & 2 Facility ID Number
Owner or Operator?
Owner/Operator
TABLE 1
UST OWNER/OPERATOR INFORMATION
JOHNNY'S CONVENIENCE MART
Address Telephone Number
Name of Owner or Operator Dates of Ownership / Operation
00-0-0000001576
JB SZ LLC 8/15/2011 - Current
PO Drawer 649, Mount Olive, NC 28365 919-658-6566
1600 Tinos Overlook Way, Apex, NC 27520 [phone]
00-0-0000001576
E.J. Pope & Son, Inc.(Install) 02/7/1995 - 08/15/2011
Address Telephone Number
Name of Owner or Operator Dates of Ownership / Operation
Page 1 of 1
Date: 05/05//22 Facility ID #: 00-0-0000001576
Was Release
Associated
with UST
System?
(Yes / No)
1 (A1)Gasoline NA 15,000 02/07/1995 SW Steel/FRP 8' x 26' 8"DW Flex Current Yes
2 (A2)Gasoline NA 8,000 02/07/1995 Sw Steel/FRP 8' x 16'DW Flex Current Yes
005 Unknown Unknown 1,000 1/1/1964 Unknown Unknown Unknown Removed No
004 Unknown Unknown 750 1/1/1964 Unknown Unknown Unknown Removed No
003 Gasoline NA 3,000 2/29/1980 Single Wall Steel Unknown Unknown Removed No
002 Gasoline NA 6,000 3/1/1977 Single Wall Steel Unknown Unknown Removed No
001 Gasoline NA 6,000 3/1/1977 Single Wall Steel Unknown Unknown Removed No
UST
ID
No.
TABLE 2
UST SYSTEM INFORMATION
JOHNNY'S CONVENIENCE MART (INCIDENT NO. 13668)
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Date: 04/13/2022
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)BenzeneTolueneEthylbenzeneXylenesMTBENaphthaleneC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics0.0072 5.4 8 6 0.085 0.2 68 540 31
12 1,250 60.3 3,120 156 5.5 625 1,500 469
GMW-1 04/13/22 5 <0.0012 <0.010 <0.0010 <0.0021 <0.0010 <0.0020 <1.9 <1.9 <1.9
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• Trip Blank results reported in ug/l (micrograms per liter)
• ft-BGS: feet below ground surface.
• MCCs: Maximum Contaminant Concentrations (soils).
• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type indicate the reported concentration exceeded the soil-to-water MCC.
• Concentrations in italic type indicate the reported concentration exceeded the residential SCL.
• NE: Not Established
• NR: Not Requested.
Soil to Water MCC (mg/kg)
Residential SCLs (mg/kg)
TABLE 3
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
JOHNNY'S CONVENIENCE MART
Analytical Method EPA Method 8260B MADEP VPH
Page 1 of 1
Date: 05/03/2022 Facility ID # : 00-0-0000001576
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
Thickness
(ft.)
Ground
Water
Elevation (ft.)
Comments
GMW-1 04/13/22 04/13/22 5 5 - 15 15 100.00 9.31 ---90.69
Notes:
• Elevation relative to mean sea level.
• ft BGS : feet below ground surface.
• NM : Not measured.
TABLE 4
WELL CONSTRUCTION AND GAUGING INFORMATION
JOHNNY'S CONVENIENCE MART, INC. (INCIDENT NO. 13668)
Page 1 of 1
Date: 05/03/2022 Facility ID # : 0-001576
EPA
504.1 EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 0.02 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 50 15,000 NE NE NE
GMW-1 04/13/22 73.0 28.4 46.2 144 8.2 29.1 541 512 <0.0095 281 <35 <35 166
Trip Blank 04/13/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the MAC was below the reported concentration.
• J: Estimated value.
• NE: Not established.
• NR: Not requested.
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.
MAC (μg/l)
GCL (μg/l)MTBENaphthaleneContaminant of Concern
BenzeneTolueneEthylbenzeneXylenesTABLE 5
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
JOHNNY'S CONVENIENCE MART, INC. (INCIDENT NO. 13668)
Analytical Method
1,2-Dibromoethane(EDB)MADEP VPH
LeadC5-C8 AliphaticsC9-C12 AliphaticsC9-C12 AromaticsEPA 6200B
tert-Butyl alcohol(TBA)tert-Amyl alcohol(TAA)Page 1 of 1

APPENDICES

Appendix A
State Correspondence

Appendix B
Well Construction Record and Boring Log

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)
3.WellUse(checkwelluse):WaterSupplyWell:□Agricultural□Municipal/Public□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)□Irrigation
Non-WaterSupplyWell:□Monitoring□Recovery
InjectionWell:□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)
4.DateWell(s)Completed:____________WellID#______________________5a.WellLocation:
Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip
CountyParcelIdentificationNo.(PIN)5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:(ifwellfield,onelat/longissufficient)N W
6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.
9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”
11.Boreholediameter:(in.)12.Wellconstructionmethod: (i.e.auger,rotary,cable,directpush,etc.)FORWATERSUPPLYWELLSONLY:13a.Yield(gpm) Methodoftest:13b.Disinfectiontype:Amount:

14.WATERZONESFROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREENFROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:
SignatureofCertifiedWellContractorDate
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a
copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwellconstructiondetails.Youmayalsoattachadditionalpagesifnecessary.SUBMITTALINSTUCTIONS24a.ForAllWells:Submitthis formwithin30daysofcompletionofwellconstructiontothefollowing:DivisionofWaterResources,InformationProcessingUnit,1617MailServiceCenter,Raleigh,NC27699-161724b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30daysofcompletion ofwellconstructiontothefollowing:DivisionofWaterResources,UndergroundInjectionControlProgram,1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submit one copyof this form within30days ofcompletionofwellconstructiontothecountyhealthdepartmentofthecountywhereconstructed.
ForInternalUseONLY:
Justin Radford
3270 A
Geological Resources, Inc.
NA
04/13/2022 GMW-1
Johnny's Convenience Mart, Inc.00-0-0000001576
766 NC Highway 111 South, Goldsboro, NC
Wayne 3527-04-2316
35.323391 77.926393
1
15
9.31
6
Direct push
0 5 2"sch 40 PVC
5 15 2 0.010 sch 40 PVC
0 3 Grout Pour
3 4 Bentonite Pour
4 15 Sand Pour
0 0.25 Asphalt
0.25 1.5 ABC gravel
1.5 3 Tan sandy clay
3 5 Gray gravely sand
5 15 DPT; no recovery
04/15/2022

Appendix C
Site Specific Health and Safety Plan

1
GEOLOGICAL RESOURCES, INC.
Site Specific Health and Safety Plan

1.0 General Information:
a. Project name: Johnny's Covenience Mart
b. Location: 766 Highway 111, Goldsboror, NC 27530
c. GRI Job #: 6007

2.0 Project Organization:
a. Site Supervisor/H&S Officer: Scott Driscoll
b. Project Manager: Scott Driscoll
c. Subcontractor(s):
3.0 Safety Plan Preparation:
a. Prepared by & date: Scott Driscoll
b. Reviewed/approved by & date: Justin Radford 03/12/2022
4.0 Site History and Description:
a. Type of site (i.e., spill, leaking UST system, etc.): Petroleum retail facility
b. Site/project description: Site Check Investigation/Drilling

5.0 Potential Hazards:
Physical Hazards: (check)
X Slips X Explosion Sun burn Electricity
X Trips
Overhead
utilities X Noise Cold Weather Pressurized line/vessels
X Falls X Underground X Pinch points Hot Weather
X Fire utilities Burns Crush

Chemical Hazards: (check)
X Gasoline Used Oil
Diesel Solvents
Kerosene Antifreeze
New Oil Acid (sample preservative)

Equipment/Vehicular/Other: (i.e., Geoprobe, drill rig, back hoe, track hoe, traffic, skid steer etc.)

Hand auger, Shovel, Geoprobe

Biological Hazards: (i.e., toxic insects, spiders, poisonous plants, poisonous snakes, aggressive dogs)

2
6.0 Site Organization and Safety Control: (Evaluate the need for site control to protect
persons from exposure to hazardous conditions; i.e. work permits, cones, barricade tape,
exclusion zones, etc.)
a. Work area(s) identified: ____________________________________________________
b. Work area marked _____ Yes_____ No
c. Work area barricaded _____ Yes _____ No
d. Support area established: __________________________________________________
e. Entry and escape routes identified: ___________________________________________
f. Rally point identified: _____ Yes ____ No Location:________________
g. Emergency shut-off for water identified _____ Yes _____ No
h. Emergency fuel shut-off identified _____ Yes _____ No
i. Site map attached: __X__ Yes _____ No
**Emergency Response Procedures**
Action (i.e. shut off all power equipment) Assemble at rally point
Call 911 for medical or utilities emergency Do NOT enter confined spaces
Discuss what to do if …..cut product line, water line, cable/electric line

7.0 Job Activities in Work Plan:
Manual FP Recovery
_ Other (specify)
___ AST Removal

UST Removal
Soil Excavation
X Drilling
X Hand Augering
X Soil Sampling
System O&M
MMPE/AFVR
XWater sampling __________________

8.0 Required Education and/or Training:
X OSHA 40 hr X Annual 8 hr Refresher OSHA Site Supervisor

9.0 Air Monitoring:
If, in the opinion of the site supervisor, petroleum hydrocarbon vapor concentrations are
excessive, site activities will cease until petroleum hydrocarbon vapor concentrations diminish to
acceptable levels.

10.0 Equipment:
X FID/PID X Combustible gas indicator Interface
Probe
X O2 meter Other

11.0 Personnel Protection Equipment:
X Hard hat Rubber boots Respirator X Hearing
X Safety glasses X Work gloves Sun screen protection
X Steel toe boots X First aid kit Repellent X Nitrile
Tyvek suit x Fire extinguisher Dust mask gloves

12.0 Decontamination Procedures: (evaluate need for decon, describe procedures)

3
13.0 Emergency Contacts:
a. Local Assistance:
Site Phone [phone] Fire Department 911
Police 911 Ambulance 911
Water Department Sanitary Sewer
Natural Gas Power Company

Nearest Urgent Care (directions attached)
Name
Address
Wayne Memorial Hospital
2700 Wayne Memorial Drive, Godsboro, NC 28534

Number [phone]

b. National or Regional Sources of Assistance:
1) Geological Resources, Inc. [phone]
2) Chemtrec (24 Hours) [phone]
3) Bureau of Explosives (24 Hours) [phone]
4) National Response Center, NRC [phone]
(Oil/Hazardous Substances)
5) DOT, Off. Of Haz. Operations [phone]

14.0 Signatures:

This plan has been reviewed by all on-site personnel and all provisions are clear (signatures
required).

Project Manager:
Site Supervisor:
Other personnel:

4
15.0 Amendments:

a. Site Specific Health and Safety Plans are based on information available at the time of
plan preparation. Unexpected conditions may arise. It is important that personal
protective measures be thoroughly assessed prior to and during the planned activities.
Unplanned activities and/or changes in the hazard status should initiate a review of this
plan and may result in major changes to it.
b. Changes in the hazard status or unplanned activities are to be submitted on “Amendment
to the Site Specific Health and Safety Plan” which is included bellow.
c. Amendment must be approved by the Project Manager prior to implementation of the
amendment.

AMENDMENT TO THE SITE SPECIFIC HEALTH AND SAFETY PLAN

A. Changes in field activities or hazards:

B. Proposed amendment:

C. Approval:

Proposed by: ___________________________________date ______________________

Approved by: ___________________________________date _____________________

Amendment number: ____________________________

Amendment effective date: _______________________

Appendix D
Laboratory Report – Soil and Ground Water Samples
05/10/22
Technical Report for
GRI (Geological Resources Inc.)
Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
SGS Job Number: FA94850
Sampling Date: 04/13/22
Report to:
GRI (Geological Resources Inc.)
[e-mail]
ATTN: Scott Driscoll
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 05/10/22
e-Hardcopy 2.0
Automated Report
53
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 53
FA94850
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA94850-1: GMW-1-5' .................................................................................................7
3.2: FA94850-2: GMW-1 .....................................................................................................10
3.3: FA94850-3: TRIP BLANK ...........................................................................................16
Section 4: Misc. Forms ............................................................................................................18
4.1: Chain of Custody ...........................................................................................................19
Section 5: MS Volatiles - QC Data Summaries .....................................................................21
5.1: Method Blank Summary ................................................................................................22
5.2: Blank Spike Summary ...................................................................................................27
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................32
Section 6: GC Volatiles - QC Data Summaries .....................................................................37
6.1: Method Blank Summary ................................................................................................38
6.2: Blank Spike Summary ...................................................................................................41
6.3: Blank Spike/Blank Spike Duplicate Summary ..............................................................42
6.4: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................44
6.5: Duplicate Summary .......................................................................................................45
Section 7: Metals Analysis - QC Data Summaries ................................................................47
7.1: Prep QC MP40574: Pb ..................................................................................................48 12345672 of 53
FA94850
SGS LabLink@224113 09:46 10-May-2022
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA94850
Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA94850-1 04/13/22 13:15 ER 04/14/22 SO Soil GMW-1-5'
FA94850-2 04/13/22 13:50 ER 04/14/22 AQ Ground Water GMW-1
FA94850-3 04/13/22 13:30 ER 04/14/22 AQ Trip Blank Water TRIP BLANK
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
3 of 53
FA948501
Summary of Hits Page 1 of 2
Job Number:FA94850
Account:GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Collected:04/13/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA94850-1 GMW-1-5'
Carbon Disulfide a 0.0018 J 0.0051 0.0010 mg/kg SW846 8260D
Methyl Acetate b 0.0496 B 0.026 0.0091 mg/kg SW846 8260D
FA94850-2 GMW-1
Benzene 73.0 1.0 0.25 ug/l SM 6200B
n-Butylbenzene 1.4 1.0 0.25 ug/l SM 6200B
sec-Butylbenzene 0.50 J 1.0 0.25 ug/l SM 6200B
o-Chlorotoluene 0.26 J 1.0 0.25 ug/l SM 6200B
Di-Isopropyl Ether 0.87 J 1.0 0.25 ug/l SM 6200B
Ethylbenzene 46.2 1.0 0.25 ug/l SM 6200B
Ethyl Tert Butyl Ether 0.39 J 1.0 0.25 ug/l SM 6200B
Isopropylbenzene 1.8 1.0 0.25 ug/l SM 6200B
p-Isopropyltoluene 0.44 J 1.0 0.25 ug/l SM 6200B
Methyl Tert Butyl Ether 8.2 1.0 0.25 ug/l SM 6200B
Naphthalene 29.1 1.0 0.25 ug/l SM 6200B
n-Propylbenzene 2.9 1.0 0.25 ug/l SM 6200B
Tert-Amyl Alcohol 541 20 4.0 ug/l SM 6200B
Tert-Butyl Alcohol 512 20 4.0 ug/l SM 6200B
Toluene 28.4 1.0 0.25 ug/l SM 6200B
1,2,4-Trimethylbenzene 31.8 1.0 0.25 ug/l SM 6200B
1,3,5-Trimethylbenzene 2.1 1.0 0.25 ug/l SM 6200B
m,p-Xylene 135 2.0 0.25 ug/l SM 6200B
o-Xylene 8.7 1.0 0.25 ug/l SM 6200B
Xylene (total)144 3.0 0.50 ug/l SM 6200B
Benzene 61.5 1.0 1.0 ug/l MADEP VPH REV 2.1
Ethylbenzene 42.9 2.0 1.0 ug/l MADEP VPH REV 2.1
Methyl Tert Butyl Ether 7.1 2.0 1.0 ug/l MADEP VPH REV 2.1
Naphthalene c 30.8 5.0 3.0 ug/l MADEP VPH REV 2.1
Toluene 27.6 2.0 1.0 ug/l MADEP VPH REV 2.1
m,p-Xylene 151 4.0 2.0 ug/l MADEP VPH REV 2.1
o-Xylene 6.4 2.0 1.0 ug/l MADEP VPH REV 2.1
C5- C8 Aliphatics (Unadj.)109 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics (Unadj.)166 100 35 ug/l MADEP VPH REV 2.1
C9- C10 Aromatics 166 100 35 ug/l MADEP VPH REV 2.1
Lead 281 5.0 ug/l SW846 6010D
FA94850-3 TRIP BLANK
No hits reported in this sample.
(a) Results reported from Bisulfate preserved sample. Associated BS recovery outside control limits high.
Confirmed ND by re-analysis.
4 of 53
FA948502
Summary of Hits Page 2 of 2
Job Number:FA94850
Account:GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Collected:04/13/22
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
(b) Results reported from Bisulfate preserved sample. Confirmed ND by re-analysis.
(c) Associated ECC outside control limits low. Confirmed by re-analysis (DUP).
5 of 53
FA948502
SGS LabLink@224113 09:46 10-May-2022
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 53
FA948503
SGS LabLink@224113 09:46 10-May-2022
Report of Analysis Page 1 of 2
Client Sample ID:GMW-1-5'
Lab Sample ID:FA94850-1 Date Sampled:04/13/22
Matrix:SO - Soil Date Received:04/14/22
Method:SW846 8260D Percent Solids:95.0
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 2B18829.D 1 04/20/22 00:07 JG n/a n/a V2B804
Run #2 b 2B18871.D 1 04/23/22 19:00 JG n/a n/a V2B805
Initial Weight Final Volume
Run #1 5.15 g 5.0 ml
Run #2 4.91 g 5.0 ml
VOA Special List
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 0.20 0.10 mg/kg
71-43-2 Benzene ND 0.0051 0.0012 mg/kg
75-27-4 Bromodichloromethane ND 0.0051 0.0010 mg/kg
75-25-2 Bromoform ND 0.0051 0.0010 mg/kg
78-93-3 2-Butanone (MEK)ND 0.026 0.0074 mg/kg
104-51-8 n-Butylbenzene ND 0.0051 0.0010 mg/kg
75-15-0 Carbon Disulfide c 0.0018 0.0051 0.0010 mg/kg J
56-23-5 Carbon Tetrachloride d ND 0.0051 0.0010 mg/kg
108-90-7 Chlorobenzene ND 0.0051 0.0010 mg/kg
75-00-3 Chloroethane ND 0.0051 0.0020 mg/kg
67-66-3 Chloroform ND 0.0051 0.0014 mg/kg
110-82-7 Cyclohexane ND 0.0051 0.0013 mg/kg
124-48-1 Dibromochloromethane ND 0.0051 0.0010 mg/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 0.0051 0.0020 mg/kg
106-93-4 1,2-Dibromoethane ND 0.0051 0.0010 mg/kg
75-71-8 Dichlorodifluoromethane d ND 0.0051 0.0020 mg/kg
95-50-1 1,2-Dichlorobenzene ND 0.0051 0.0010 mg/kg
541-73-1 1,3-Dichlorobenzene ND 0.0051 0.0010 mg/kg
106-46-7 1,4-Dichlorobenzene ND 0.0051 0.0012 mg/kg
75-34-3 1,1-Dichloroethane ND 0.0051 0.0018 mg/kg
107-06-2 1,2-Dichloroethane d ND 0.0051 0.0010 mg/kg
75-35-4 1,1-Dichloroethylene ND 0.0051 0.0010 mg/kg
156-59-2 cis-1,2-Dichloroethylene ND 0.0051 0.0014 mg/kg
156-60-5 trans-1,2-Dichloroethylene ND 0.0051 0.0010 mg/kg
78-87-5 1,2-Dichloropropane ND 0.0051 0.0010 mg/kg
10061-01-5 cis-1,3-Dichloropropene ND 0.0051 0.0010 mg/kg
10061-02-6 trans-1,3-Dichloropropene ND 0.0051 0.0010 mg/kg
100-41-4 Ethylbenzene ND 0.0051 0.0010 mg/kg
591-78-6 2-Hexanone ND 0.026 0.0077 mg/kg
98-82-8 Isopropylbenzene ND 0.0051 0.0010 mg/kg
79-20-9 Methyl Acetate e 0.0496 0.026 0.0091 mg/kg B
74-83-9 Methyl Bromide ND 0.0051 0.0020 mg/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA9485033.1
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Report of Analysis Page 2 of 2
Client Sample ID:GMW-1-5'
Lab Sample ID:FA94850-1 Date Sampled:04/13/22
Matrix:SO - Soil Date Received:04/14/22
Method:SW846 8260D Percent Solids:95.0
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
VOA Special List
CAS No.Compound Result RL MDL Units Q
74-87-3 Methyl Chloride ND 0.0051 0.0020 mg/kg
108-87-2 Methylcyclohexane f ND 0.0051 0.0017 mg/kg
75-09-2 Methylene Chloride d ND 0.020 0.011 mg/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 0.026 0.0077 mg/kg
1634-04-4 Methyl Tert Butyl Ether g ND 0.0051 0.0010 mg/kg
91-20-3 Naphthalene ND 0.0051 0.0020 mg/kg
103-65-1 n-Propylbenzene ND 0.0051 0.0010 mg/kg
100-42-5 Styrene ND 0.0051 0.0010 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 0.0051 0.0010 mg/kg
127-18-4 Tetrachloroethylene ND 0.0051 0.0013 mg/kg
108-88-3 Toluene ND 0.020 0.010 mg/kg
120-82-1 1,2,4-Trichlorobenzene ND 0.0051 0.0010 mg/kg
71-55-6 1,1,1-Trichloroethane ND 0.0051 0.0010 mg/kg
79-00-5 1,1,2-Trichloroethane ND 0.0051 0.0010 mg/kg
79-01-6 Trichloroethylene d ND 0.0051 0.0010 mg/kg
75-69-4 Trichlorofluoromethane d ND 0.0051 0.0020 mg/kg
95-63-6 1,2,4-Trimethylbenzene ND 0.0051 0.0010 mg/kg
108-67-8 1,3,5-Trimethylbenzene ND 0.0051 0.0010 mg/kg
75-01-4 Vinyl Chloride ND 0.0051 0.0010 mg/kg
1330-20-7 Xylene (total)ND 0.015 0.0021 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%103%75-124%
17060-07-0 1,2-Dichloroethane-D4 98%106%72-135%
2037-26-5 Toluene-D8 97%94%75-126%
460-00-4 4-Bromofluorobenzene 102%98%71-133%
(a) Results reported from Bisulfate preserved sample.
(b) Sample was analyzed beyond the 12 hour analysis window. Results reported from Bisulfate preserved sample.
Confirmation run.
(c) Associated BS recovery outside control limits high. Confirmed ND by re-analysis.
(d) Associated CCV outside of control limits high, sample was ND.
(e) Confirmed ND by re-analysis.
(f) Associated CCV and BS recovery outside control limits high, sample was ND.
(g) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA9485033.1
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Report of Analysis Page 1 of 1
Client Sample ID:GMW-1-5'
Lab Sample ID:FA94850-1 Date Sampled:04/13/22
Matrix:SO - Soil Date Received:04/14/22
Method:MADEP VPH REV 2.1 Percent Solids:95.0
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U9790.D 1 04/23/22 06:48 KB n/a n/a G1U432
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 5.13 g 5.1 ml 100 ul
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.055 0.055 mg/kg
100-41-4 Ethylbenzene ND 0.11 0.055 mg/kg
1634-04-4 Methyl Tert Butyl Ether ND 0.11 0.055 mg/kg
91-20-3 Naphthalene ND 0.27 0.16 mg/kg
108-88-3 Toluene ND 0.11 0.055 mg/kg
m,p-Xylene ND 0.22 0.11 mg/kg
95-47-6 o-Xylene ND 0.11 0.055 mg/kg
C5- C8 Aliphatics (Unadj.)ND 5.5 1.9 mg/kg
C9- C12 Aliphatics (Unadj.)ND 5.5 1.9 mg/kg
C9- C10 Aromatics (Unadj.)ND 5.5 1.9 mg/kg
C5- C8 Aliphatics ND 5.5 1.9 mg/kg
C9- C12 Aliphatics ND 5.5 1.9 mg/kg
C9- C10 Aromatics ND 5.5 1.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 88%70-130%
460-00-4 BFB 83%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA9485033.1
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Report of Analysis Page 1 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA94850-2 Date Sampled:04/13/22
Matrix:AQ - Ground Water Date Received:04/14/22
Method:SM 6200B Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231812.D 2 04/22/22 18:26 JL n/a n/a VA3120
Run #2 a A0231747.D 2 04/20/22 21:43 JL n/a n/a VA3118
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 73.0 1.0 0.25 ug/l
108-86-1 Bromobenzene ND 1.0 0.25 ug/l
74-97-5 Bromochloromethane ND 1.0 0.25 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.25 ug/l
75-25-2 Bromoform ND 1.0 0.25 ug/l
104-51-8 n-Butylbenzene 1.4 1.0 0.25 ug/l
135-98-8 sec-Butylbenzene 0.50 1.0 0.25 ug/l J
98-06-6 tert-Butylbenzene ND 1.0 0.25 ug/l
56-23-5 Carbon Tetrachloride ND 1.0 0.25 ug/l
108-90-7 Chlorobenzene ND 1.0 0.25 ug/l
75-00-3 Chloroethane b ND 1.0 0.40 ug/l
67-66-3 Chloroform ND 1.0 0.25 ug/l
95-49-8 o-Chlorotoluene 0.26 1.0 0.25 ug/l J
106-43-4 p-Chlorotoluene ND 1.0 0.25 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 1.0 0.49 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.25 ug/l
75-71-8 Dichlorodifluoromethane ND 1.0 0.40 ug/l
95-50-1 1,2-Dichlorobenzene ND 1.0 0.25 ug/l
541-73-1 1,3-Dichlorobenzene ND 1.0 0.25 ug/l
106-46-7 1,4-Dichlorobenzene ND 1.0 0.25 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.25 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.25 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.25 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.25 ug/l
142-28-9 1,3-Dichloropropane ND 1.0 0.25 ug/l
594-20-7 2,2-Dichloropropane ND 1.0 0.25 ug/l
563-58-6 1,1-Dichloropropene ND 1.0 0.25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.25 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.25 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA94850-2 Date Sampled:04/13/22
Matrix:AQ - Ground Water Date Received:04/14/22
Method:SM 6200B Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.87 1.0 0.25 ug/l J
64-17-5 Ethyl Alcohol c ND 200 130 ug/l
100-41-4 Ethylbenzene 46.2 1.0 0.25 ug/l
637-92-3 Ethyl Tert Butyl Ether 0.39 1.0 0.25 ug/l J
87-68-3 Hexachlorobutadiene d ND 1.0 0.25 ug/l
98-82-8 Isopropylbenzene 1.8 1.0 0.25 ug/l
99-87-6 p-Isopropyltoluene 0.44 1.0 0.25 ug/l J
74-83-9 Methyl Bromide b ND 1.0 0.40 ug/l
74-87-3 Methyl Chloride ND 1.0 0.40 ug/l
74-95-3 Methylene Bromide ND 1.0 0.25 ug/l
75-09-2 Methylene Chloride ND 4.0 2.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 8.2 1.0 0.25 ug/l
91-20-3 Naphthalene 29.1 1.0 0.25 ug/l
103-65-1 n-Propylbenzene 2.9 1.0 0.25 ug/l
100-42-5 Styrene ND 1.0 0.25 ug/l
75-85-4 Tert-Amyl Alcohol 541 20 4.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 2.0 0.40 ug/l
75-65-0 Tert-Butyl Alcohol 512 20 4.0 ug/l
762-75-4 Tert-Butyl Formate ND 20 4.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.25 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.25 ug/l
108-88-3 Toluene 28.4 1.0 0.25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 1.0 0.25 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.25 ug/l
79-01-6 Trichloroethylene ND 1.0 0.25 ug/l
75-69-4 Trichlorofluoromethane ND 1.0 0.40 ug/l
96-18-4 1,2,3-Trichloropropane ND 1.0 0.25 ug/l
95-63-6 1,2,4-Trimethylbenzene 31.8 1.0 0.25 ug/l
108-67-8 1,3,5-Trimethylbenzene 2.1 1.0 0.25 ug/l
75-01-4 Vinyl Chloride ND 1.0 0.25 ug/l
m,p-Xylene 135 2.0 0.25 ug/l
95-47-6 o-Xylene 8.7 1.0 0.25 ug/l
1330-20-7 Xylene (total)144 3.0 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 110%106%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:GMW-1
Lab Sample ID:FA94850-2 Date Sampled:04/13/22
Matrix:AQ - Ground Water Date Received:04/14/22
Method:SM 6200B Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
17060-07-0 1,2-Dichloroethane-D4 110%106%70-130%
2037-26-5 Toluene-D8 93%96%70-130%
460-00-4 4-Bromofluorobenzene 94%95%70-130%
(a) Confirmation run.
(b) Associated CCV outside of control limits high, sample is ND.
(c) Associated CCV and ECC outside control limits low.
(d) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA9485033.2
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Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FA94850-2 Date Sampled:04/13/22
Matrix:AQ - Ground Water Date Received:04/14/22
Method:EPA 504.1 SW846 8011 Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 CC081790.D 1 04/19/22 19:21 NJ 04/19/22 12:20 OP90813 GCC2071
Run #2
Initial Volume Final Volume
Run #1 36.9 ml 2.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.019 0.0095 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 74%63-137%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA9485033.2
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Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FA94850-2 Date Sampled:04/13/22
Matrix:AQ - Ground Water Date Received:04/14/22
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U9693.D 1 04/19/22 12:56 KB n/a n/a G1U429
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 61.5 1.0 1.0 ug/l
100-41-4 Ethylbenzene 42.9 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 7.1 2.0 1.0 ug/l
91-20-3 Naphthalene a 30.8 5.0 3.0 ug/l
108-88-3 Toluene 27.6 2.0 1.0 ug/l
m,p-Xylene 151 4.0 2.0 ug/l
95-47-6 o-Xylene 6.4 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)109 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)166 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics 166 100 35 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 107%70-130%
460-00-4 BFB 97%70-130%
(a) Associated ECC outside control limits low. Confirmed by re-analysis (DUP).
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA9485033.2
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Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FA94850-2 Date Sampled:04/13/22
Matrix:AQ - Ground Water Date Received:04/14/22
Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 281 5.0 ug/l 1 04/18/22 04/19/22 LM SW846 6010D 1 SW846 3010A 2
(1) Instrument QC Batch: MA18615
(2) Prep QC Batch: MP40574
RL = Reporting Limit
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Report of Analysis Page 1 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FA94850-3 Date Sampled:04/13/22
Matrix:AQ - Trip Blank Water Date Received:04/14/22
Method:SM 6200B Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0231803.D 1 04/22/22 14:56 JL n/a n/a VA3120
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane a ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FA94850-3 Date Sampled:04/13/22
Matrix:AQ - Trip Blank Water Date Received:04/14/22
Method:SM 6200B Percent Solids:n/a
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene b ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide a ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 95%70-130%
(a) Associated CCV outside of control limits high, sample is ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
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FA948504
FA94850: Chain of Custody
Page 1 of 2
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FA9485044.1
Job Number:FA94850 Client:GRI
Date / Time Received:4/14/2022 10:00:00 AM Delivery Method:FX
Project:JOHNNYS CONVENIENCE MART
Airbill #'s:100963789381
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments FROZEN @ 1245 // 4/14/22
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (2.6);
Cooler 1: (3.0);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.4; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:NATHANS Date:Date:4/14/2022 10:00:00 A
FA94850: Chain of Custody
Page 2 of 2
20 of 53
FA9485044.1
SGS LabLink@224113 09:46 10-May-2022
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
21 of 53
FA948505
Method Blank Summary Page 1 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3120-MB A0231802.D 1 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
64-17-5 Ethyl Alcohol ND 100 65 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
22 of 53
FA9485055.1.1
Method Blank Summary Page 2 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3120-MB A0231802.D 1 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
CAS No.Compound Result RL MDL Units Q
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
23 of 53
FA9485055.1.1
Method Blank Summary Page 3 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3120-MB A0231802.D 1 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 104%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 95%70-130%
24 of 53
FA9485055.1.1
Method Blank Summary Page 1 of 2
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B804-MB 2B18812.D 1 04/19/22 JG n/a n/a V2B804
The QC reported here applies to the following samples:Method: SW846 8260D
FA94850-1
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 200 100 ug/kg
71-43-2 Benzene ND 5.0 1.2 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
75-15-0 Carbon Disulfide ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
110-82-7 Cyclohexane ND 5.0 1.3 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 1.9 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
79-20-9 Methyl Acetate 10.5 25 8.9 ug/kg J
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
108-87-2 Methylcyclohexane ND 5.0 1.7 ug/kg
75-09-2 Methylene Chloride ND 20 11 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
25 of 53
FA9485055.1.2
Method Blank Summary Page 2 of 2
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B804-MB 2B18812.D 1 04/19/22 JG n/a n/a V2B804
The QC reported here applies to the following samples:Method: SW846 8260D
FA94850-1
CAS No.Compound Result RL MDL Units Q
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/kg
108-88-3 Toluene ND 20 10 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 93%75-124%
17060-07-0 1,2-Dichloroethane-D4 102%72-135%
2037-26-5 Toluene-D8 93%75-126%
460-00-4 4-Bromofluorobenzene 105%71-133%
26 of 53
FA9485055.1.2
Blank Spike Summary Page 1 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3120-BS A0231800.D 1 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 12.4 124 70-130
108-86-1 Bromobenzene 10 12.2 122 70-130
74-97-5 Bromochloromethane 10 12.3 123 70-130
75-27-4 Bromodichloromethane 10 12.1 121 70-130
75-25-2 Bromoform 10 11.7 117 70-130
104-51-8 n-Butylbenzene 10 12.0 120 70-130
135-98-8 sec-Butylbenzene 10 13.0 130 70-130
98-06-6 tert-Butylbenzene 10 12.4 124 70-130
56-23-5 Carbon Tetrachloride 10 12.6 126 70-130
108-90-7 Chlorobenzene 10 12.3 123 70-130
75-00-3 Chloroethane 10 8.9 89 60-140
67-66-3 Chloroform 10 11.8 118 70-130
95-49-8 o-Chlorotoluene 10 12.1 121 70-130
106-43-4 p-Chlorotoluene 10 12.0 120 70-130
124-48-1 Dibromochloromethane 10 11.7 117 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 11.3 113 70-130
106-93-4 1,2-Dibromoethane 10 12.1 121 70-130
75-71-8 Dichlorodifluoromethane 10 8.1 81 60-140
95-50-1 1,2-Dichlorobenzene 10 12.1 121 70-130
541-73-1 1,3-Dichlorobenzene 10 12.6 126 70-130
106-46-7 1,4-Dichlorobenzene 10 12.2 122 70-130
75-34-3 1,1-Dichloroethane 10 12.3 123 70-130
107-06-2 1,2-Dichloroethane 10 11.7 117 70-130
75-35-4 1,1-Dichloroethylene 10 12.8 128 70-130
156-59-2 cis-1,2-Dichloroethylene 10 12.2 122 70-130
156-60-5 trans-1,2-Dichloroethylene 10 12.5 125 70-130
78-87-5 1,2-Dichloropropane 10 12.0 120 70-130
142-28-9 1,3-Dichloropropane 10 11.5 115 70-130
594-20-7 2,2-Dichloropropane 10 12.3 123 70-130
563-58-6 1,1-Dichloropropene 10 12.5 125 70-130
10061-01-5 cis-1,3-Dichloropropene 10 12.3 123 70-130
10061-02-6 trans-1,3-Dichloropropene 10 12.2 122 70-130
108-20-3 Di-Isopropyl Ether 10 12.0 120 70-130
64-17-5 Ethyl Alcohol 500 449 90 70-130
100-41-4 Ethylbenzene 10 12.3 123 70-130
637-92-3 Ethyl Tert Butyl Ether 10 10.9 109 70-130
* = Outside of Control Limits.
27 of 53
FA9485055.2.1
Blank Spike Summary Page 2 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3120-BS A0231800.D 1 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
87-68-3 Hexachlorobutadiene 10 13.8 138*70-130
98-82-8 Isopropylbenzene 10 12.9 129 70-130
99-87-6 p-Isopropyltoluene 10 12.6 126 70-130
74-83-9 Methyl Bromide 10 10.9 109 60-140
74-87-3 Methyl Chloride 10 9.7 97 60-140
74-95-3 Methylene Bromide 10 11.1 111 70-130
75-09-2 Methylene Chloride 10 11.3 113 70-130
1634-04-4 Methyl Tert Butyl Ether 10 12.2 122 70-130
91-20-3 Naphthalene 10 12.3 123 70-130
103-65-1 n-Propylbenzene 10 12.2 122 70-130
100-42-5 Styrene 10 12.4 124 70-130
75-85-4 Tert-Amyl Alcohol 100 110 110 70-130
994-05-8 Tert-Amyl Methyl Ether 10 11.5 115 70-130
75-65-0 Tert-Butyl Alcohol 100 102 102 70-130
762-75-4 Tert-Butyl Formate 100 79.0 79 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 12.5 125 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 12.9 129 70-130
127-18-4 Tetrachloroethylene 10 12.9 129 70-130
108-88-3 Toluene 10 12.0 120 70-130
87-61-6 1,2,3-Trichlorobenzene 10 12.7 127 70-130
120-82-1 1,2,4-Trichlorobenzene 10 12.8 128 70-130
71-55-6 1,1,1-Trichloroethane 10 12.3 123 70-130
79-00-5 1,1,2-Trichloroethane 10 12.0 120 70-130
79-01-6 Trichloroethylene 10 12.2 122 70-130
75-69-4 Trichlorofluoromethane 10 8.6 86 60-140
96-18-4 1,2,3-Trichloropropane 10 11.4 114 70-130
95-63-6 1,2,4-Trimethylbenzene 10 12.0 120 70-130
108-67-8 1,3,5-Trimethylbenzene 10 12.5 125 70-130
75-01-4 Vinyl Chloride 10 8.9 89 60-140
m,p-Xylene 20 24.5 123 70-130
95-47-6 o-Xylene 10 12.2 122 70-130
1330-20-7 Xylene (total)30 36.7 122 70-130
* = Outside of Control Limits.
28 of 53
FA9485055.2.1
Blank Spike Summary Page 3 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA3120-BS A0231800.D 1 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 106%70-130%
17060-07-0 1,2-Dichloroethane-D4 98%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
* = Outside of Control Limits.
29 of 53
FA9485055.2.1
Blank Spike Summary Page 1 of 2
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B804-BS 2B18811.D 1 04/19/22 JG n/a n/a V2B804
The QC reported here applies to the following samples:Method: SW846 8260D
FA94850-1
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 329 132 61-152
71-43-2 Benzene 50 61.4 123 76-126
75-27-4 Bromodichloromethane 50 56.1 112 74-130
75-25-2 Bromoform 50 49.6 99 76-127
78-93-3 2-Butanone (MEK)250 296 118 75-137
104-51-8 n-Butylbenzene 50 58.3 117 71-128
75-15-0 Carbon Disulfide 50 62.7 125*72-122
56-23-5 Carbon Tetrachloride 50 62.5 125 78-133
108-90-7 Chlorobenzene 50 58.5 117 81-129
75-00-3 Chloroethane 50 59.1 118 68-133
67-66-3 Chloroform 50 59.7 119 72-123
110-82-7 Cyclohexane 50 61.3 123 73-126
124-48-1 Dibromochloromethane 50 50.4 101 76-127
96-12-8 1,2-Dibromo-3-chloropropane 50 51.1 102 70-137
106-93-4 1,2-Dibromoethane 50 51.7 103 77-126
75-71-8 Dichlorodifluoromethane 50 66.2 132 68-168
95-50-1 1,2-Dichlorobenzene 50 59.1 118 80-129
541-73-1 1,3-Dichlorobenzene 50 60.0 120 81-129
106-46-7 1,4-Dichlorobenzene 50 58.9 118 76-130
75-34-3 1,1-Dichloroethane 50 61.4 123 73-125
107-06-2 1,2-Dichloroethane 50 64.1 128 74-128
75-35-4 1,1-Dichloroethylene 50 64.6 129 81-136
156-59-2 cis-1,2-Dichloroethylene 50 61.8 124 74-126
156-60-5 trans-1,2-Dichloroethylene 50 62.8 126 70-127
78-87-5 1,2-Dichloropropane 50 54.8 110 74-125
10061-01-5 cis-1,3-Dichloropropene 50 53.9 108 80-123
10061-02-6 trans-1,3-Dichloropropene 50 52.3 105 75-131
100-41-4 Ethylbenzene 50 59.9 120 77-123
591-78-6 2-Hexanone 250 293 117 72-133
98-82-8 Isopropylbenzene 50 62.3 125 80-136
79-20-9 Methyl Acetate 250 322 129 67-137
74-83-9 Methyl Bromide 50 65.5 131 65-139
74-87-3 Methyl Chloride 50 57.4 115 71-144
108-87-2 Methylcyclohexane 50 65.9 132*75-128
75-09-2 Methylene Chloride 50 68.7 137 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 289 116 76-132
* = Outside of Control Limits.
30 of 53
FA9485055.2.2
Blank Spike Summary Page 2 of 2
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B804-BS 2B18811.D 1 04/19/22 JG n/a n/a V2B804
The QC reported here applies to the following samples:Method: SW846 8260D
FA94850-1
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
1634-04-4 Methyl Tert Butyl Ether 50 60.8 122*77-120
91-20-3 Naphthalene 50 56.3 113 79-129
103-65-1 n-Propylbenzene 50 57.9 116 80-135
100-42-5 Styrene 50 61.2 122 78-125
79-34-5 1,1,2,2-Tetrachloroethane 50 50.8 102 71-126
127-18-4 Tetrachloroethylene 50 59.2 118 79-130
108-88-3 Toluene 50 57.8 116 76-124
120-82-1 1,2,4-Trichlorobenzene 50 64.6 129 78-130
71-55-6 1,1,1-Trichloroethane 50 60.6 121 70-129
79-00-5 1,1,2-Trichloroethane 50 51.6 103 74-124
79-01-6 Trichloroethylene 50 63.8 128 75-128
75-69-4 Trichlorofluoromethane 50 65.6 131 73-145
95-63-6 1,2,4-Trimethylbenzene 50 58.9 118 74-123
108-67-8 1,3,5-Trimethylbenzene 50 59.7 119 73-122
75-01-4 Vinyl Chloride 50 62.3 125 76-141
1330-20-7 Xylene (total)150 184 123 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 105%75-124%
17060-07-0 1,2-Dichloroethane-D4 107%72-135%
2037-26-5 Toluene-D8 96%75-126%
460-00-4 4-Bromofluorobenzene 100%71-133%
* = Outside of Control Limits.
31 of 53
FA9485055.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA94581-13MS A0231825.D 5 04/22/22 JL n/a n/a VA3120
FA94581-13MSD A0231826.D 5 04/22/22 JL n/a n/a VA3120
FA94581-13 a A0231811.D 5 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
FA94581-13 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 212 50 243 62* b 50 237 50* b 3 70-130/20
108-86-1 Bromobenzene ND 50 57.0 114 50 56.7 113 1 70-130/20
74-97-5 Bromochloromethane ND 50 57.4 115 50 57.6 115 0 70-130/20
75-27-4 Bromodichloromethane ND 50 54.2 108 50 52.1 104 4 70-130/20
75-25-2 Bromoform ND 50 48.0 96 50 46.2 92 4 70-130/20
104-51-8 n-Butylbenzene 0.92 J 50 53.3 105 50 53.3 105 0 70-130/20
135-98-8 sec-Butylbenzene ND 50 59.5 119 50 59.6 119 0 70-130/20
98-06-6 tert-Butylbenzene ND 50 56.6 113 50 56.7 113 0 70-130/20
56-23-5 Carbon Tetrachloride ND 50 56.8 114 50 56.2 112 1 70-130/20
108-90-7 Chlorobenzene ND 50 57.0 114 50 56.1 112 2 70-130/20
75-00-3 Chloroethane ND 50 58.9 118 50 61.8 124 5 60-140/20
67-66-3 Chloroform 2.3 J 50 58.3 112 50 57.1 110 2 70-130/20
95-49-8 o-Chlorotoluene ND 50 55.5 111 50 55.2 110 1 70-130/20
106-43-4 p-Chlorotoluene ND 50 53.5 107 50 53.0 106 1 70-130/20
124-48-1 Dibromochloromethane ND 50 50.3 101 50 48.9 98 3 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 50 52.1 104 50 52.4 105 1 70-130/20
106-93-4 1,2-Dibromoethane ND 50 55.5 111 50 54.7 109 1 70-130/20
75-71-8 Dichlorodifluoromethane ND 50 48.5 97 50 51.2 102 5 60-140/20
95-50-1 1,2-Dichlorobenzene ND 50 56.4 113 50 55.9 112 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 57.0 114 50 56.7 113 1 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 55.9 112 50 55.3 111 1 70-130/20
75-34-3 1,1-Dichloroethane ND 50 57.2 114 50 56.8 114 1 70-130/20
107-06-2 1,2-Dichloroethane ND 50 54.9 110 50 55.0 110 0 70-130/20
75-35-4 1,1-Dichloroethylene ND 50 60.2 120 50 58.5 117 3 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 50 57.3 115 50 56.3 113 2 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 50 58.5 117 50 57.9 116 1 70-130/20
78-87-5 1,2-Dichloropropane ND 50 55.2 110 50 54.3 109 2 70-130/20
142-28-9 1,3-Dichloropropane ND 50 52.5 105 50 52.4 105 0 70-130/20
594-20-7 2,2-Dichloropropane ND 50 49.6 99 50 48.3 97 3 70-130/20
563-58-6 1,1-Dichloropropene ND 50 58.1 116 50 57.9 116 0 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 50 52.6 105 50 52.0 104 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 50 52.0 104 50 51.6 103 1 70-130/20
108-20-3 Di-Isopropyl Ether 45.6 50 96.9 103 50 95.1 99 2 70-130/20
64-17-5 Ethyl Alcohol ND 2500 1990 80 2500 2240 90 12 70-130/20
100-41-4 Ethylbenzene 1.1 J 50 57.5 113 50 57.0 112 1 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 50 48.0 96 50 48.3 97 1 70-130/20
* = Outside of Control Limits.
32 of 53
FA9485055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA94581-13MS A0231825.D 5 04/22/22 JL n/a n/a VA3120
FA94581-13MSD A0231826.D 5 04/22/22 JL n/a n/a VA3120
FA94581-13 a A0231811.D 5 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
FA94581-13 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
87-68-3 Hexachlorobutadiene ND 50 62.1 124 50 62.9 126 1 70-130/20
98-82-8 Isopropylbenzene 5.2 50 63.7 117 50 63.4 116 0 70-130/20
99-87-6 p-Isopropyltoluene ND 50 57.7 115 50 58.2 116 1 70-130/20
74-83-9 Methyl Bromide ND 50 67.7 135 50 70.5 141*4 60-140/20
74-87-3 Methyl Chloride ND 50 58.4 117 50 60.4 121 3 60-140/20
74-95-3 Methylene Bromide ND 50 52.0 104 50 51.5 103 1 70-130/20
75-09-2 Methylene Chloride ND 50 46.3 93 50 46.2 92 0 70-130/20
1634-04-4 Methyl Tert Butyl Ether 90.1 50 139 98 50 139 98 0 70-130/20
91-20-3 Naphthalene 3.4 50 59.7 113 50 60.6 114 1 70-130/20
103-65-1 n-Propylbenzene 1.4 J 50 56.7 111 50 56.6 110 0 70-130/20
100-42-5 Styrene ND 50 55.0 110 50 55.1 110 0 70-130/20
75-85-4 Tert-Amyl Alcohol 573 500 1060 97 500 1080 101 2 70-130/20
994-05-8 Tert-Amyl Methyl Ether 4.3 J 50 53.7 99 50 54.9 101 2 70-130/20
75-65-0 Tert-Butyl Alcohol ND 500 524 105 500 536 107 2 70-130/20
762-75-4 Tert-Butyl Formate ND 500 282 56*500 291 58*3 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 50 57.7 115 50 56.8 114 2 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 50 62.6 125 50 62.7 125 0 70-130/20
127-18-4 Tetrachloroethylene ND 50 59.2 118 50 58.5 117 1 70-130/20
108-88-3 Toluene 2.1 J 50 57.2 110 50 56.7 109 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 50 58.0 116 50 59.0 118 2 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 50 58.1 116 50 59.0 118 2 70-130/20
71-55-6 1,1,1-Trichloroethane ND 50 57.5 115 50 56.2 112 2 70-130/20
79-00-5 1,1,2-Trichloroethane ND 50 55.2 110 50 54.4 109 1 70-130/20
79-01-6 Trichloroethylene ND 50 53.8 108 50 53.4 107 1 70-130/20
75-69-4 Trichlorofluoromethane ND 50 54.6 109 50 57.9 116 6 60-140/20
96-18-4 1,2,3-Trichloropropane ND 50 52.6 105 50 52.6 105 0 70-130/20
95-63-6 1,2,4-Trimethylbenzene 31.0 50 83.9 106 50 83.3 105 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 4.0 50 60.3 113 50 60.5 113 0 70-130/20
75-01-4 Vinyl Chloride ND 50 52.2 104 50 57.5 115 10 60-140/20
m,p-Xylene 67.2 100 172 105 100 168 101 2 70-130/20
95-47-6 o-Xylene 19.1 50 74.0 110 50 73.2 108 1 70-130/20
1330-20-7 Xylene (total)86.3 150 246 106 150 242 104 2 70-130/20
* = Outside of Control Limits.
33 of 53
FA9485055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA94581-13MS A0231825.D 5 04/22/22 JL n/a n/a VA3120
FA94581-13MSD A0231826.D 5 04/22/22 JL n/a n/a VA3120
FA94581-13 a A0231811.D 5 04/22/22 JL n/a n/a VA3120
The QC reported here applies to the following samples:Method: SM 6200B
FA94850-2, FA94850-3
CAS No.Surrogate Recoveries MS MSD FA94581-13 Limits
1868-53-7 Dibromofluoromethane 107%107%105%70-130%
17060-07-0 1,2-Dichloroethane-D4 99%100%105%70-130%
2037-26-5 Toluene-D8 99%100%97%70-130%
460-00-4 4-Bromofluorobenzene 95%96%95%70-130%
(a) Sample re-analyzed beyond hold time.
(b) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
34 of 53
FA9485055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA94864-4MS a 2B18836.D 1 04/20/22 JG n/a n/a V2B804
FA94864-4MSD a 2B18837.D 1 04/20/22 JG n/a n/a V2B804
FA94864-4 a 2B18818.D 1 04/19/22 JG n/a n/a V2B804
The QC reported here applies to the following samples:Method: SW846 8260D
FA94850-1
FA94864-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone ND 272 371 136 262 375 143 1 61-152/27
71-43-2 Benzene ND 54.4 58.0 107 52.4 56.5 108 3 76-126/26
75-27-4 Bromodichloromethane ND 54.4 50.4 93 52.4 48.7 93 3 74-130/25
75-25-2 Bromoform ND 54.4 42.7 78 52.4 40.9 78 4 76-127/26
78-93-3 2-Butanone (MEK)ND 272 270 99 262 257 98 5 75-137/25
104-51-8 n-Butylbenzene ND 54.4 42.1 77 52.4 40.0 76 5 71-128/35
75-15-0 Carbon Disulfide ND 54.4 53.6 98 52.4 52.7 101 2 72-122/29
56-23-5 Carbon Tetrachloride ND 54.4 49.3 91 52.4 49.3 94 0 78-133/29
108-90-7 Chlorobenzene ND 54.4 50.5 93 52.4 47.3 90 7 81-129/29
75-00-3 Chloroethane ND 54.4 52.0 96 52.4 51.5 98 1 68-133/29
67-66-3 Chloroform ND 54.4 52.1 96 52.4 51.5 98 1 72-123/26
110-82-7 Cyclohexane ND 54.4 55.7 102 52.4 55.2 105 1 73-126/32
124-48-1 Dibromochloromethane ND 54.4 44.4 82 52.4 42.9 82 3 76-127/27
96-12-8 1,2-Dibromo-3-chloropropane ND 54.4 35.9 66*52.4 37.0 71 3 70-137/29
106-93-4 1,2-Dibromoethane ND 54.4 46.8 86 52.4 44.2 84 6 77-126/26
75-71-8 Dichlorodifluoromethane ND 54.4 50.5 93 52.4 50.6 97 0 68-168/29
95-50-1 1,2-Dichlorobenzene ND 54.4 41.0 75*52.4 40.2 77*2 80-129/32
541-73-1 1,3-Dichlorobenzene ND 54.4 41.7 77*52.4 39.2 75*6 81-129/33
106-46-7 1,4-Dichlorobenzene ND 54.4 40.4 74*52.4 37.7 72*7 76-130/32
75-34-3 1,1-Dichloroethane ND 54.4 55.8 102 52.4 55.9 107 0 73-125/27
107-06-2 1,2-Dichloroethane ND 54.4 54.2 100 52.4 52.3 100 4 74-128/23
75-35-4 1,1-Dichloroethylene ND 54.4 52.6 97 52.4 52.1 99 1 81-136/28
156-59-2 cis-1,2-Dichloroethylene ND 54.4 56.9 105 52.4 55.0 105 3 74-126/26
156-60-5 trans-1,2-Dichloroethylene ND 54.4 51.0 94 52.4 50.1 96 2 70-127/27
78-87-5 1,2-Dichloropropane ND 54.4 53.9 99 52.4 52.5 100 3 74-125/25
10061-01-5 cis-1,3-Dichloropropene ND 54.4 48.1 88 52.4 44.7 85 7 80-123/26
10061-02-6 trans-1,3-Dichloropropene ND 54.4 43.4 80 52.4 41.3 79 5 75-131/28
100-41-4 Ethylbenzene ND 54.4 51.8 95 52.4 49.1 94 5 77-123/31
591-78-6 2-Hexanone ND 272 177 65*262 168 64*5 72-133/26
98-82-8 Isopropylbenzene ND 54.4 51.7 95 52.4 50.0 95 3 80-136/32
79-20-9 Methyl Acetate ND 272 50.4 19*262 47.9 18*5 67-137/30
74-83-9 Methyl Bromide ND 54.4 57.1 105 52.4 56.6 108 1 65-139/31
74-87-3 Methyl Chloride ND 54.4 49.0 90 52.4 49.6 95 1 71-144/27
108-87-2 Methylcyclohexane ND 54.4 61.1 112 52.4 59.4 113 3 75-128/31
75-09-2 Methylene Chloride ND 54.4 59.4 109 52.4 57.7 110 3 74-137/28
108-10-1 4-Methyl-2-pentanone (MIBK)ND 272 248 91 262 249 95 0 76-132/26
* = Outside of Control Limits.
35 of 53
FA9485055.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA94864-4MS a 2B18836.D 1 04/20/22 JG n/a n/a V2B804
FA94864-4MSD a 2B18837.D 1 04/20/22 JG n/a n/a V2B804
FA94864-4 a 2B18818.D 1 04/19/22 JG n/a n/a V2B804
The QC reported here applies to the following samples:Method: SW846 8260D
FA94850-1
FA94864-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
1634-04-4 Methyl Tert Butyl Ether ND 54.4 54.9 101 52.4 54.6 104 1 77-120/24
91-20-3 Naphthalene ND 54.4 24.7 45*52.4 28.5 54*14 79-129/33
103-65-1 n-Propylbenzene ND 54.4 48.1 88 52.4 44.7 85 7 80-135/33
100-42-5 Styrene ND 54.4 26.0 48*52.4 26.3 50*1 78-125/30
79-34-5 1,1,2,2-Tetrachloroethane ND 54.4 44.8 82 52.4 43.5 83 3 71-126/30
127-18-4 Tetrachloroethylene ND 54.4 51.8 95 52.4 49.6 95 4 79-130/31
108-88-3 Toluene ND 54.4 52.9 97 52.4 51.6 98 2 76-124/30
120-82-1 1,2,4-Trichlorobenzene ND 54.4 29.9 55*52.4 33.1 63*10 78-130/34
71-55-6 1,1,1-Trichloroethane ND 54.4 49.1 90 52.4 49.0 93 0 70-129/27
79-00-5 1,1,2-Trichloroethane ND 54.4 50.3 92 52.4 48.3 92 4 74-124/28
79-01-6 Trichloroethylene ND 54.4 54.7 100 52.4 52.9 101 3 75-128/27
75-69-4 Trichlorofluoromethane ND 54.4 49.5 91 52.4 49.9 95 1 73-145/31
95-63-6 1,2,4-Trimethylbenzene ND 54.4 44.3 81 52.4 42.7 81 4 74-123/34
108-67-8 1,3,5-Trimethylbenzene ND 54.4 46.1 85 52.4 44.3 84 4 73-122/33
75-01-4 Vinyl Chloride ND 54.4 50.9 93 52.4 52.8 101 4 76-141/27
1330-20-7 Xylene (total)ND 163 153 94 157 145 92 5 80-129/30
CAS No.Surrogate Recoveries MS MSD FA94864-4 Limits
1868-53-7 Dibromofluoromethane 95%97%91%75-124%
17060-07-0 1,2-Dichloroethane-D4 88%89%94%72-135%
2037-26-5 Toluene-D8 96%99%93%75-126%
460-00-4 4-Bromofluorobenzene 101%100%103%71-133%
(a) Results reported from Bisulfate preserved sample.
* = Outside of Control Limits.
36 of 53
FA9485055.3.2
SGS LabLink@224113 09:46 10-May-2022
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
37 of 53
FA948506
Method Blank Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U429-MB 1U9692.D 1 04/19/22 KB n/a n/a G1U429
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA94850-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 91%70-130%
460-00-4 BFB 78%70-130%
38 of 53
FA9485066.1.1
Method Blank Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U432-MB 1U9769.D 1 04/22/22 KB n/a n/a G1U432
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA94850-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 51 51 ug/kg
100-41-4 Ethylbenzene ND 100 51 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 100 51 ug/kg
91-20-3 Naphthalene ND 260 150 ug/kg
108-88-3 Toluene ND 100 51 ug/kg
m,p-Xylene ND 200 100 ug/kg
95-47-6 o-Xylene ND 100 51 ug/kg
C5- C8 Aliphatics (Unadj.)ND 5100 1800 ug/kg
C9- C12 Aliphatics (Unadj.)ND 5100 1800 ug/kg
C9- C10 Aromatics (Unadj.)ND 5100 1800 ug/kg
C5- C8 Aliphatics ND 5100 1800 ug/kg
C9- C12 Aliphatics ND 5100 1800 ug/kg
C9- C10 Aromatics ND 5100 1800 ug/kg
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 95%70-130%
460-00-4 BFB 93%70-130%
39 of 53
FA9485066.1.2
Method Blank Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90813-MB CC081785.D 1 04/19/22 NJ 04/19/22 OP90813 GCC2071
The QC reported here applies to the following samples:Method: EPA 504.1
FA94850-2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.020 0.010 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 85%63-137%
40 of 53
FA9485066.1.3
Blank Spike Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90813-BS CC081786.D 1 04/19/22 NJ 04/19/22 OP90813 GCC2071
The QC reported here applies to the following samples:Method: EPA 504.1
FA94850-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
106-93-4 1,2-Dibromoethane 0.25 0.23 92 70-130
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 85%63-137%
* = Outside of Control Limits.
41 of 53
FA9485066.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U429-BS 1U9690.D 1 04/19/22 KB n/a n/a G1U429
G1U429-BSD 1U9691.D 1 04/19/22 KB n/a n/a G1U429
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA94850-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 73.1 91 71.5 89 2 70-130/25
100-41-4 Ethylbenzene 80 76.0 95 72.8 91 4 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 68.5 86 65.5 82 4 70-130/25
91-20-3 Naphthalene 80 67.1 84 61.8 77 8 70-130/25
108-88-3 Toluene 80 74.5 93 72.6 91 3 70-130/25
m,p-Xylene 160 155 97 148 93 5 70-130/25
95-47-6 o-Xylene 80 77.0 96 74.2 93 4 70-130/25
C5- C8 Aliphatics (Unadj.)240 229 95 215 90 6 70-130/25
C9- C12 Aliphatics (Unadj.)160 166 104 148 93 11 70-130/25
C9- C10 Aromatics (Unadj.)80 71.3 89 68.4 86 4 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 111%100%70-130%
460-00-4 BFB 96%92%70-130%
* = Outside of Control Limits.
42 of 53
FA9485066.3.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U432-BS 1U9767.D 1 04/22/22 KB n/a n/a G1U432
G1U432-BSD 1U9768.D 1 04/22/22 KB n/a n/a G1U432
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA94850-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
71-43-2 Benzene 4160 4060 98 4090 98 1 70-130/25
100-41-4 Ethylbenzene 4160 4110 99 4120 99 0 70-130/25
1634-04-4 Methyl Tert Butyl Ether 4160 3880 93 3870 93 0 70-130/25
91-20-3 Naphthalene 4160 3740 90 3690 89 1 70-130/25
108-88-3 Toluene 4160 4010 96 4030 97 0 70-130/25
m,p-Xylene 8320 8210 99 8220 99 0 70-130/25
95-47-6 o-Xylene 4160 4080 98 4120 99 1 70-130/25
C5- C8 Aliphatics (Unadj.)12500 12200 98 12300 99 1 70-130/25
C9- C12 Aliphatics (Unadj.)8320 8090 97 8150 98 1 70-130/25
C9- C10 Aromatics (Unadj.)4160 3990 96 4090 98 2 70-130/25
C9- C10 Aromatics 4160 3990 96 4090 98 2 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 92%93%70-130%
460-00-4 BFB 90%90%70-130%
* = Outside of Control Limits.
43 of 53
FA9485066.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP90813-MS CC081787.D 1 04/19/22 NJ 04/19/22 OP90813 GCC2071
OP90813-MSD CC081788.D 1 04/19/22 NJ 04/19/22 OP90813 GCC2071
FA94921-1 CC081793.D 1 04/19/22 NJ 04/19/22 OP90813 GCC2071
The QC reported here applies to the following samples:Method: EPA 504.1
FA94850-2
FA94921-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
106-93-4 1,2-Dibromoethane 0.019 U 0.237 0.21 89 0.238 0.20 84 5 70-130/25
CAS No.Surrogate Recoveries MS MSD FA94921-1 Limits
460-00-4 4-Bromofluorobenzene 81%76%71%63-137%
* = Outside of Control Limits.
44 of 53
FA9485066.4.1
Duplicate Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA94850-2DUP 1U9694.D 1 04/19/22 KB n/a n/a G1U429
FA94850-2 1U9693.D 1 04/19/22 KB n/a n/a G1U429
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA94850-2
FA94850-2 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene 61.5 61.3 0 50
100-41-4 Ethylbenzene 42.9 42.8 0 50
1634-04-4 Methyl Tert Butyl Ether 7.1 6.9 3 50
91-20-3 Naphthalene 30.8 27.2 12 50
108-88-3 Toluene 27.6 27.5 0 50
m,p-Xylene 151 150 1 50
95-47-6 o-Xylene 6.4 6.3 2 50
C5- C8 Aliphatics (Unadj.)109 108 1 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)166 161 3 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics 166 161 3 50
CAS No.Surrogate Recoveries DUP FA94850-2 Limits
460-00-4 BFB 98%107%70-130%
460-00-4 BFB 87%97%70-130%
* = Outside of Control Limits.
45 of 53
FA9485066.5.1
Duplicate Summary Page 1 of 1
Job Number:FA94850
Account:GRINCC GRI (Geological Resources Inc.)
Project:Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA94706-1DUP 1U9771.D 1 04/22/22 KB n/a n/a G1U432
FA94706-1 1U9770.D 1 04/22/22 KB n/a n/a G1U432
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA94850-1
FA94706-1 DUP
CAS No.Compound ug/kg Q ug/kg Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA94706-1 Limits
460-00-4 BFB 156%* a 154%* a 70-130%
460-00-4 BFB 152%* a 150%* a 70-130%
(a) Outside control limits, sample is ND.
* = Outside of Control Limits.
46 of 53
FA9485066.5.2
SGS LabLink@224113 09:46 10-May-2022
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Orlando, FL
Section 7
47 of 53
FA948507
BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA94850
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
QC Batch ID: MP40574 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/18/22
MB
Metal RL IDL MDL raw final
Aluminum 200 14 14
Antimony 6.0 1 1
Arsenic 10 1.3 1.3
Barium 200 .5 1
Beryllium 4.0 .1 .2
Cadmium 5.0 .1 .2
Calcium 1000 50 50
Chromium 10 .5 1
Cobalt 50 .2 .2
Copper 25 1 1
Iron 300 15 17
Lead 5.0 1 1.1 -0.50 <5.0
Magnesium 5000 35 35
Manganese 15 .25 1
Molybdenum 50 .3 .3
Nickel 40 .4 .4
Potassium 10000 100 200
Selenium 10 2 2.9
Silver 10 .5 .7
Sodium 10000 250 500
Strontium 10 .25 .5
Thallium 10 1 1.4
Tin 50 .5 1
Titanium 10 .5 1
Vanadium 50 .5 .6
Zinc 20 3 4.4
Associated samples MP40574: FA94850-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
48 of 53
FA9485077.1.1
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA94850
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
QC Batch ID: MP40574 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/18/22 04/18/22
FA94647-2 QC FA94647-2 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony anr
Arsenic anr
Barium anr
Beryllium anr
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper anr
Iron anr
Lead 0.0 0.0 NC 0-20 0.0 498 500 99.6 80-120
Magnesium anr
Manganese anr
Molybdenum anr
Nickel anr
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium anr
Tin
Titanium
Vanadium anr
Zinc anr
Associated samples MP40574: FA94850-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
49 of 53
FA9485077.1.2
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA94850
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
QC Batch ID: MP40574 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/18/22
FA94647-2 Spikelot MSD QC
Metal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony anr
Arsenic anr
Barium anr
Beryllium anr
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper anr
Iron anr
Lead 0.0 494 500 98.8 0.8 20
Magnesium anr
Manganese anr
Molybdenum anr
Nickel anr
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium anr
Tin
Titanium
Vanadium anr
Zinc anr
Associated samples MP40574: FA94850-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 2
50 of 53
FA9485077.1.2
SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA94850
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
QC Batch ID: MP40574 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/18/22
BSP Spikelot QC
Metal Result MPFLICP2 % Rec Limits
Aluminum
Antimony anr
Arsenic anr
Barium anr
Beryllium anr
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper anr
Iron anr
Lead 499 500 99.8 80-120
Magnesium anr
Manganese anr
Molybdenum anr
Nickel anr
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium anr
Tin
Titanium
Vanadium anr
Zinc anr
Associated samples MP40574: FA94850-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
51 of 53
FA9485077.1.3
SERIAL DILUTION RESULTS SUMMARY
Login Number: FA94850
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
QC Batch ID: MP40574 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/18/22
FA94647-2 QC
Metal Original SDL 1:5 %DIF Limits
Aluminum
Antimony anr
Arsenic anr
Barium anr
Beryllium anr
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper anr
Iron anr
Lead 0.00 0.00 NC 0-10
Magnesium anr
Manganese anr
Molybdenum anr
Nickel anr
Potassium
Selenium anr
Silver anr
Sodium
Strontium
Thallium anr
Tin
Titanium
Vanadium anr
Zinc anr
Associated samples MP40574: FA94850-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
52 of 53
FA9485077.1.4
POST DIGESTATE SPIKE SUMMARY
Login Number: FA94850
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Johnny's Convenience Mart; 766 Hwy 11, Goldsboro, NC
QC Batch ID: MP40574 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/18/22
Sample Final FA94647-2 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 9.8 10 48.9 0.2 2.5 50 97.8 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP40574: FA94850-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
53 of 53
FA9485077.1.5