WA-27812_47122_CA_RPTS_20200702_LSA

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

May 12, 2020

Ms. Sylvia Hunneke
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: Phase I Limited Site Assessment Report
Handy Mart 33
101 Ketner Boulevard
Havelock, Craven County,
North Carolina
Facility ID Number: 00-0-0000001074
Incident Number: Pending
GRI Project No. 5390

Dear Ms. Hunneke,

Please find attached the referenced report for the above mentioned site.
If you have any questions, please contact William Regenthal at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Scott Driscoll; E. J. Pope & Son, Inc., file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Phase I Limited Site Assessment Report
Handy Mart 33
101 Ketner Boulevard
Havelock, Craven County
North Carolina
Facility ID Number: 00-0-0000001074
Incident Number: Pending
GRI Project Number: 5390

Prepared for:

Scott Driscoll
E. J. Pope & Son, Inc.
1092 North Breazeale Avenue
Mount Olive, North Carolina 28365

July 2, 2020

William Regenthal, P.G.
Project Manager
Matthew Schroeder, P.G.
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
i

EXECUTIVE SUMMARY
The Handy Mart 33 site is located at 101 Ketner Boulevard in Havelock, Craven County, North Carolina.
The property operates as a petroleum retail facility and convenience store. The site is covered by concrete
and asphalt. There are three 10,000-gallon gasoline USTs currently in use at the site with two associated
gasoline dispenser islands. The surrounding properties are commercial and residential.

On April 27, 2020, a Phase II Environmental Site Assessment (Phase II ESA) was conducted at the site and
soil and groundwater samples were collected. The Regulatory Action Levels (RALs) and/or the Maximum
Allowable Concentrations (MACs) were below the contaminant concentrations reported in the soil and/or
ground water samples. Based on these results, a Limited Site Assessment was required.

On May 22, 2022, a receptor survey was conducted. Three inactive non-potable water supply wells were
identified within 1,500 feet of the site. No potable water supply wells were identified within 250 feet of
the site. Public water is available to the subject site and to all surrounding properties. No surface water
bodies were identified within 500 feet of the site.

On May 20, 2020, one monitoring well (MW-1) was installed adjacent to the UST system. A soil sample
was collected at 1 foot below ground surface during the installation of monitoring well MW-1. The soil-
to-water maximum contaminant concentration was below the estimated concentration of benzene
reported in soil sample MW-1-1’.

On May 20, 2020, a ground water sample was collected from MW-1. The MACs were below the
concentrations of benzene, unadjusted C5-C8 aliphatics and unadjusted C9-C10 aromatics reported in the
ground water sample. All contaminant concentrations were below the Gross Contamination Levels (GCLs)
reported in MW-1.

No receptors were identified and contaminant concentrations were reported below GCLs; therefore, the
site should be classified as low risk and no further assessment is warranted subsequent to filing a Notice
of Residual Petroleum for ground water.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390

TABLE OF CONTENTS

1. RISK CHARACTERIZATION .....................................................................................................1
2. RECEPTOR INFORMATION .....................................................................................................3
3. SITE GEOLOGY AND HYDROGEOLOGY ...................................................................................4
4. SITE INVESTIGATION .............................................................................................................5
5. CONCLUSIONS AND RECOMMENDATIONS ............................................................................7
6. LIMITATIONS ........................................................................................................................7

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Soil Quality Map
Figure 5: Ground Water Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Soil Sample Analytical Results
Table 7: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: Craven County Property Cards
Appendix B: Well Construction Record and Subsurface Log
Appendix C: Terraquest Phase II ESA Report
Appendix D: Laboratory Analytical Reports – Soil and Ground Water

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
1
1. RISK CHARACTERIZATION
Limited Site Assessment Risk Classification and Land Use Form
Part I – Groundwater/Surface Water/Vapor Impacts
High Risk
1. Has the release contaminated any water supply well including any well used for non-drinking
purposes? NO

2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the
release? NO

3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial cooling
water, filling swimming pools) located within 250 feet of the source area of the release?
NO

4. Does ground water within 500 feet of the source area of the release have the potential for future
use (there is no other source of water supply other than the groundwater)? NO

Public water is available to the site and surrounding properties.

5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a
confined space or pose any other serious threat to public health, public safety or the
environment?
NO

6. Are there any other factors that would cause the release to pose an imminent danger to public
health, public safety, or the environment? NO
If YES, explain:

Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the release? NO

If YES, does the maximum groundwater contaminant concentration exceed the surface water
quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10? N/A

8. Is the source area of the release located within an approved or planned wellhead protection area
as defined in 42 USC 300h-7(e)? NO

9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled
“Geology of North Carolina” published by the Department in 1985? YES

10. If YES, is the source area of the release located in an area in which there is recharge to an
unconfined or semi-confined deeper aquifer that is being used or may be used as a source of
drinking water? NO
If YES, describe.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
2
11. Do the levels of ground water contamination for any contaminant exceed the gross contamination
levels established by the Department? NO

Part II - Land Use
Property Containing Source Area of Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)? NO
Explain:
The subject property is an active convenience store and petroleum retail facility.

2. Does the property contain a school, daycare center, hospital, playground, park, recreation area,
church, nursing home, or other place of public assembly? NO
Explain:

The subject property is an active convenience store and petroleum retail facility.

3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.) or
industrial (e.g., manufacturing, utilities, industrial research and development,
chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial or industrial
enterprise, or is the land undeveloped? YES
Explain:

The subject property is an active convenience store and petroleum retail facility.

4. Do children visit the property? YES
Explain:

The site is currently a convenience store and children would likely visit the property.

5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security
personnel or both)? NO
Explain:
The property is easily accessible to pedestrian and vehicular traffic.
6. Do pavement, buildings, or other structures cap the contaminated soil? YES
Explain:
The site is currently covered with concrete and asphalt.

If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil
will remain capped in the foreseeable future?
The site is expected to remain in operation as an active convenience store and petroleum retail

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
3
facility in the near future.
7. What is the zoning status of the property?
According to the Craven County Official Zoning Map, the site is zoned HC (Highway-Commercial).
8. Is the use of the property likely to change in the next 20 years? NO
Explain:

The subject property is currently an active convenience store and petroleum retail facility and
likely remain a convenience store in the near future.
Property Surrounding Source Area of Release
The questions below pertain to the area within 1,500 feet of the source area of the release (excludes
property containing source area of the release):

9. What is the distance from the source area of the release to the nearest primary or secondary
residence (permanent or temporary)?

The closest primary residence is 105 Ketner Boulevard located approximately 75 feet northeast
of the UST basin.

10. What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home or other place of public
assembly?

Havelock Community Missionary Baptist Church is located at 262 US Highway 70, approximately
644 feet north of the source area at the site.

11. What is the zoning status of properties in the surrounding area?

According to the Craven County Official Zoning Map, the surrounding areas are zoned Highway-
Commercial (HC) and Single Family Residential (R-20)

12. Briefly characterize the use and activities of the land in the surrounding area.

The area surrounding the site is a mixture of commercial and residential.

2. RECEPTOR INFORMATION
1. Water Supply Wells:
A receptor survey was conducted on May 22, 2020. Two non-potable water supply wells were
identified within 1,500 feet of the site. No water supply wells were located within 250 feet of the
site. A Site Location Map is provided as Figure 1 and a Site Vicinity Map showing property
boundaries for the site and surrounding properties has been included as Figure 2. Water supply

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
4
well information has been provided in Table 3.

2. Public Water Supplies:
Are public water supplies available within 1,500 feet of the source area of the release? YES
If yes, where is the location of the nearest public water lines and the source(s) of the public water
supply. Explain:
Municipal water is available to the site and the surrounding properties. Water lines run along the
public streets in the area. Public water is supplied by Craven County Water.

3. Surface Water:
Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the
source area of the release. This information must be shown on the USGS topographic map.
No surface water bodies were identified during the May 2020 receptor survey activities.

4. Wellhead Protection Areas:
Identify all planned or approved wellhead protection areas in the vicinity of the source area. This
information must be shown on the USGS topographic map. Wellhead protection areas are defined
in 42 USC 300h-7(e).
On May 22, 2020, GRI personnel accessed the NCDEQ Source Water Assessment and Protection
(SWAP) Program’s website to identify wellhead protection areas in the vicinity of the subject site.
The site is not located within a wellhead protection area.

5. Deep Aquifers in the Coastal Plain Physiographic Region:
The site is located in the Coastal Plain Physiographic Region. The surficial aquifer in the vicinity of
the site is approximately 150 feet deep and is underlain by the Yorktown confining unit and the
Yorktown aquifer, respectively.

6. Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. The water main
and other underground utilities run along Ketner Boulevard and US Highway 70.

7. Property Owners and Occupants:
The names and addresses of the owners of properties adjacent to the site are presented in Table
4. Property boundaries are shown on Figure 2. Property cards for the adjacent property owners
are attached as Appendix A.

3. SITE GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is located within the Coastal Plain
Physiographic Province of North Carolina. The Coastal Plain is part of an extensive geologic province that
roughly parallels the Atlantic Ocean and continues northward and southward through the neighboring

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
5
states. The soil sample collected during well installation activities was gray clay and fine sand. The depth
to ground water during the May 2020 gauging event was 1.99 feet below the top of well casing. Copies
of the well construction record and subsurface log have been included as Appendix B. A Site Map is
included as Figure 3. Well construction and gauging information is presented in Table 5. A photo of the
newly installed monitoring well is shown below:

MW-1

4. SITE INVESTIGATION
On April 27, 2020, Terraquest Environmental Consultants, P.C (Terraquest) conducted a Phase II
Environmental Site Assessment (Phase II ESA). During the Phase II ESA soil and groundwater samples were
collected. The applicable Regulatory Action Levels (RALs) and the Maximum Allowable Concentrations
(MACs) specified in T15A NCAC 2L.0202 were below the contaminant concentrations reported in the soil
and ground water samples collected, respectively. A copy of the Terraquest Phase II ESA has been
included in Appendix C.

Based on the Phase II ESA results, Geological Resources Inc. was contracted to conduct a Phase I Limited
Site Assessment (LSA) at the subject site. On May 20, 2020, one monitoring well (MW-1) was installed by
a North Carolina licensed well contractor to assess the identified release at the site. MW-1 was installed
to a total depth of 12 feet below ground surface (bgs) with a 10-foot screened interval set to bracket the
water table at the time of installation. Monitoring well MW-1 was installed on the eastern side of the UST
basin, the location where soil contamination was identified during Phase II ESA activities conducted in
April 2020.

MW-1 was gauged following its installation. The depth to ground water measured 3.04 feet bgs. Gauging
data from the May 2020 gauging event has been included in Table 5. A summary of the current gauging
data is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
6
Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Groundwater
Elevation
(ft.)
MW-1 2 - 12 12 NM 1.99 NM

1. Soil Sampling:
During the Terraquest Phase II ESA activities conducted in April 2020, soil samples were collected from
around the UST basin and along the product lines and dispensers. These soil samples were submitted
for laboratory analyses of TPH-GRO and TPH-DRO by UVF Trilogy Technology. The applicable RALs
were below the concentrations of GRO and DRO in the soil samples collected.

On May 20, 2020, one soil sample (MW-1-1’) was collected at 1 foot bgs during the installation of
monitoring well MW-1. The soil sample was submitted for analysis of volatile organic compounds
(VOCs) by EPA Method 8260B and volatile petroleum hydrocarbons (VPH) by the MADEP Method.

The soil-to-water maximum contaminant concentration (MCC) was below the estimated
concentration of benzene reported in soil sample MW-1-1’. A Soil Quality Map has been included as
Figure 4. A summary of the soil sample analytical results is presented in Table 6. A copy of the
laboratory analytical report from the May 2020 soil sampling event has been included in Appendix D.
A copy of the current soil sampling data collected during the LSA activities is shown below:
Sample ID Sample Depth (ft-BGS) Benzene Toluene Ethylbenzene Total Xylenes Soil to Water MCC (mg/kg) 0.0056 4.3 4.9 4.6
Residential SCLs (mg/kg) 18 1,200 1,560 3,129
MW-1-1’ 1 0.235 J 0.0542 0.111 0.132

2. Ground Water Sampling:
On May 20, 2020, MW-1 was gauged purged and sampled. The ground water sample was submitted
for analysis of VOCs by EPA Method 6200B, EDB by EPA Method 504.1, total lead by EPA Method 6010
and VPH by the MADEP Method. The MACs were below the concentrations of benzene, unadjusted
C5-C8 aliphatics and unadjusted C9-C10 aromatics reported in the ground water sample collected
from MW-1. All contaminant concentrations were below the Gross Contamination Levels (GCLs). No
free product was observed at the site. A Ground Water Quality Map has been included as Figure 5.
A summary of the ground water analytical data has been included in Table 7. Copies of the laboratory
analytical reports have been included in Appendix D. A summary of the current ground water
sampling data is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
7
Contaminant of
Concern
 Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MAC (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 84,500 85,500 20,000 6,000
MW-1 489 2.6 J 33 11.6 J <1.3 2.9 J

3. Quality Control:
The soil and ground water samples were immediately placed in laboratory-supplied containers after
collection, which were then placed in iced coolers. New disposable bailers were used to sample the
monitoring well and new nitrile gloves were worn during soil and ground water sampling. Samples
were logged using proper chain-of-custody procedures. The samples were transported to a North
Carolina certified laboratory for analysis.

5. CONCLUSIONS AND RECOMMENDATIONS
 The site is an active convenience store and petroleum retail facility. Land use in the area consists
of a mixture of commercial and residential properties.
 In April 2020, soil and ground water contamination were identified at the site when a Phase II ESA
was conducted.
 On May 22, 2022, a receptor survey was conducted. Two inactive non-potable water supply wells
were identified within 1,500- feet of the site. No potable water supply well was identified within
250 feet of the site. Public water is available to the subject site and to all surrounding properties.
 No surface water bodies were identified within 500 feet of the site.
 On May 20, 2020, one monitoring well (MW-1) was installed adjacent the UST system.
 The soil-to-water MCC was below the estimated concentration of benzene reported in soil sample
MW-1-1’ collected during the installation of MW-1.
 On May 20, 2020, a ground water sample was collected from MW-1. The MACs were below the
concentrations of benzene, unadjusted C5-C8 aliphatics and unadjusted C9-C10 aromatics
reported in the ground water sample.
 No receptors were identified and contaminant concentrations were below GCLs; therefore, the
site risk should be classified as low and no further assessment should be warranted subsequent
to filing a Notice of Residual for ground water.

6. LIMITATIONS
This report has been prepared for the exclusive use of E. J. Pope & Son, Inc. for specific application to the
referenced site in Craven County, North Carolina. The assessment was conducted based on the scope of
work and level of effort specified by NCDEQ and with resources adequate only for that scope of work. Our

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Phase I Limited Site Assessment Report
Prepared on: July 2, 2020 Handy Mart 33
Project Manager: William Regenthal, P.G. GRI Project No. 5390
8
findings have been developed in accordance with generally accepted standards of geology and
hydrogeology practices in the State of North Carolina, available information and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site LocationHandy Mart 33101 Ketner Boulevard Havelock, Craven County, NCIncident No. N/AGRI Project No. 5390500 M2000 FTDate: 06/27/2020Location: 34.900007° N -76.929353° W Dad
"J "J
SITE
6-044 -044
6-044 -0276-044 -0366-044 -052
6-045 -018
6-045 -002
6-045 -0196-045 -014
6-045 -001
WSW-3WSW-1
WOLF PIT BRANCH CEDAR CREEKL
E
E

D
R
U
S 70 H
WY KETNER BLVD
M E LO D Y LN
RIV
E
R
SID
E D
RSANDY LNS TO NEBR IDG E TR LR O S E STM A N ILA S T
S TR A TFO R D R D
PINECONE LN
CRYSTAL LAKE DR
LAKESIDE DRB A D G ER LN GREENWAY CTCO YO TE TRLC O U G AR PLPARADI
SE CI
RGREEN COVE DRB
A
R
N
E
Y F
O
N
E
S D
R
D
E
V
O
N
S
HIR
E D
R
SALEM CT
ARNOLD CT
U
S 7
0 H
W
Y
U
S 7
0 H
W
Y
U
S 7
0 H
W
Y
K E T N E R B LV D
W ILLO W R U N
SWEETBRIAR LN
A N N S THAWTHORNE CTSTONEBRIDGE SQ
CREEKBRIDGE CT
B
E
R
KS
HIR
E D
R SUNNY DR70 CROSSOVER 70 CROSSOVER 70 CROSSOVER 70 C R O SSO VER 70 CROSSO VER FIGURE 2: SITE VICINITY MAPHANDY MART #33101 KETNER BOULEVARDHAVELOCK, CRAVEN COUNTYNORTH CAROLINAINCIDENT NO. <PENDING>GRI PROJECT NO. 5390
PREPARED BY:GEOLOGICAL RESOURCES, INC.MAY 19, 2020
³
0 300150
Feet
1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS
500-FOOT RADIUS 250-FOOT RADIUS
LEGEND
"J Water Supply Well
ncrivers
roads
hydromaj_poly
Well Owners and Adjacent Parcels
Craven County NC Parcels

TABLES
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 001-003 Facility ID Number
Owner or Operator?
Owner/Operator
P.O. Drawer 649, Mount Olive, NC 28365 919-658-6566
Name of Owner or Operator Dates of Ownership / Operation
E.J Pope & Son, Inc.01/01/1990 - Current
Address Telephone Number
00-0-0000001074
TABLE 1
UST OWNER/OPERATOR INFORMATION
HANDY MART 33 (INCIDENT NO. PENDING)
Address Telephone Number
Unknown Unknown
00-0-0000001074
Name of Owner or Operator Dates of Ownership / Operation
Unknown 05/10/1971 - 01/01/1990
Page 1 of 1
Date: 06/24/20
Was Release
Associated
with UST
System?
(Yes / No)
001 Gasoline NA 4,000 5/10/1971 Single Wall Steel 64" x 24'Unknown Removed No
002 Gasoline NA 4,000 5/10/1971 Single Wall Steel 64" x 24'Unknown Removed No
003 Gasoline NA 4,000 5/10/1971 Single Wall Steel 64" x 24'Unknown Removed No
004 Gasoline NA 4,000 5/10/1971 Single Wall Steel 64" x 24'Unknown Removed No
1 Gasoline NA 10,000 8/28/1990 Single Wall FRP 8' x 26'8"Single Wall FRP Current Yes
2 Gasoline NA 10,000 8/28/1990 Single Wall FRP 8' x 26'8"Single Wall FRP Current Yes
3 Gasoline NA 10,000 8/28/1990 Single Wall FRP 8' x 26'8"Single Wall FRP Current Yes
TABLE 2
UST SYSTEM INFORMATION
HANDY MART 33 (INCIDENT NO. PENDING)
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Facility ID #: 0-00-0000001074
Page 1 of 1
Date: 06/24/20 Facility ID #: 0-00-0000001074
Well ID Parcel ID No.Well Owner Mailing Address Well Location Address
Well Use
(Potable/
Agriculture, etc.)
Public Water
Connected
Distance from
source area of
release
(ft.)
WSW-1 6-044-036 Rodgers, Philip David & Virginia 616 Lee Dr.
Havelock, NC 28532
616 Lee Dr.
Havelock, NC 28532 Not in use Yes ~1,200 NW
WSW-2 6-045-002 Fletcher, Dana M 1117 Salem Church Rd.
Elizabeth City, NC 27909
105 Ketner Blvd.
Havelock, NC 28532
Abandoned
6/16/20 Yes ~75 NE
WSW-3 6-045-014 Town, Jeffrey J 175 West Clarion Rd.
Brockway, PA 15824
114 Ketner Blvd.
Havelock, NC 28532
Not connected,
no power Yes ~650 NE
Notes:
• Water supply wells are shown on Figure 2
• Ft. BGS : Feet below ground surface
TABLE 3
WATER SUPPLY WELL INFORMATION
HANDY MART 33 (INCIDENT NO. PENDING)
Page 1 of 1
Date: 06/19/20
PIN Number Property Owner Name Property Owner Address
6-045-001 (site)MLP/CPL LLC P.O. Box 649
Mount Olive, NC 28365
6-044-052 American Eagle Rentals LLC 252 US Highway 70 West
Havelock, NC 28532
6-045-019 Grays Havelock LLC P.O. Box 1596
Havelock, NC 28532
6-045-020 Grays Havelock LLC P.O. Box 1596
Havelock, NC 28532
6-045-021 Grays Havelock LLC P.O. Box 1596
Havelock, NC 28532
6-045-002 Fletcher, Dana M 1117 Selm Church Rd.
ELIZABETH CITY, NC 27909
6-045-018 Diaz, Tomas 104 Ketner Blvd.
Havelock, NC 28532
6-044-044 MNM Investments LLC 33 Cherokee Dr.
Havelock, NC 28532
6-044-027 MNM Investments LLC 33 Cherokee Dr.
Havelock, NC 28532
Note:
• Properties are keyed to Figure 2.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
HANDY MART 33 (INCIDENT NO. PENDING)
Facility ID #: Facility ID #: 0-00-0000001074
Page 1 of 1
Date: 06/19/20 Facility ID #: 0-00-0000001074
Well ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Free Product
Thickness
(ft.)
Groundwater
Elevation
(ft.)
Comments
MW-1 05/20/20 05/20/20 2 2 - 12 12 NA 1.99 ---NA
Notes:
• ft BGS : feet below ground surface.
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
HANDY MART 33 (INCIDENT NO. PENDING)
Page 1 of 1
Date: 06/19/20 Facility ID #: 0-00-0000001074
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)BenzeneTolueneEthylbenzeneTotal XylenesC5-C8 AliphaticsC9-C12 AliphaticsUnadjusted C9-C10 AromaticsNE NE NE NE NE NE NE
0.0056 4.3 4.9 4.6 68 540 31
18 1,200 1,560 3,129 939 1,500 469
MW-1-1'05/20/20 1 0.235 J 0.0542 0.111 0.132 <2.6 <2.6 4.45 J
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• ft-BGS: feet below ground surface.
• RAL: Regulatory Action Level.
• MCCs: Maximum Contaminant Concentrations (soils).
• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type indicate the soil to water MCCs were below the reported concentrations.
• Concentrations in italic type indicate the Residential SCLs were below the report concentrations.
• NE: Not Established
Residential SCLs (mg/kg)
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Analytical Method EPA Method 8260B
TABLE 6
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
HANDY MART 33 (INCIDENT NO. PENDING)
MADEP VPH
Page 1 of 1
Date: 06/24/20 Facility ID #: 0-00-0000001074
EPA
504.1 EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 0.02 15 400 700 200
5,000 260,000 84,500 85,500 20,000 6,000 50 15,000 NE NE NE
MW-1 05/20/20 489 2.6 J 33 11.6 J <1.3 2.9 J <0.0093 <5.00 515 <70 348
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the MAC was below the reported concentration.
• Results in italics indicate the GCLs were below the reported concentrations.
• J: Estimated value.
• NE: Not established.
TABLE 7
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
HANDY MART 33 (INCIDENT NO. PENDING)
Analytical Method
EPA 6200B MADEP VPH
EDBLeadUnadjusted C5-C8 AliphaticsC9-C12 AliphaticsUnadjusted C9-C10 AromaticsMAC (μg/l)
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.
GCL (μg/l)MTBENaphthaleneContaminant of Concern
BenzeneTolueneEthylbenzeneXylenesPage 1 of 1

APPENDICES

APPENDIX A
Craven County Property Cards
6-045 -018
DIAZ, TOMAS
104 KETNER BLVD HAVELOCK NC 28532
104 KETNER BLVDProperty Address :
Parcel ID :
6 C R DUKEDescription :
0.578Assessed Acreage :Calculated Acreage :
2440-0634Deed Reference :4 12 2006Recorded Date :
$128,330
$35,000
$93,330
Total Value :
Land Value :
Improvement Value :2# of Improvements :
Owner :
Mailing Address :
City Name :
Drainage District :
Fire tax District :
Special District :
HAVELOCK
0.580
Tax Exempt :No
Land use :RESIDENTIAL - ONE FAMILY UNIT
Lot Description :Subdivision :
Recorded Survey :
Estate Number :
Recent Sales Information
1/1/1951 SHELTON, JOSEPH R JARMAN, DIXIE L &
SHELTON, JIMMY D
STRAIGHT
TRANSFER
$0
4/12/2006 TYLER, HORACE LEE JR
& REBECCA H
DIAZ, TOMAS STRAIGHT
TRANSFER
$128,000
3/31/2005 JARMAN, DIXIE L &
SHELTON, JIMMY D
TYLER, HORACE LEE JR &
REBECCA H
STRAIGHT
TRANSFER
$65,000
SALE DATE Sellers Name Buyers Name Sale Type Sale Price
GARAGE/SHOP-DETACHED 1963 480 $5,190
RESIDENTIAL CONSTRUCTION 1950 1684 $88,140
Type of Structure Year Built Base Area 1st Floor Value
List of Improvements to Site
Craven County Geographic Information System
Craven County does NOT warrant the information shown on this page and should be used ONLY for tax assessment purposes.
This report was created by Craven County GIS reporting services on 5/21/2020 9:17:11 AM
6-045 -002
FLETCHER, DANA M
1117 SALEM CHURCH RD ELIZABETH CITY NC 27909
105 KETNER BLVDProperty Address :
Parcel ID :
LOT 15 CENTRAL HWYDescription :
0.488Assessed Acreage :Calculated Acreage :
2472-0499Deed Reference :6 26 2006Recorded Date :
$114,030
$35,000
$79,030
Total Value :
Land Value :
Improvement Value :2# of Improvements :
Owner :
Mailing Address :
City Name :
Drainage District :
Fire tax District :
Special District :
HAVELOCK
0.480
Tax Exempt :No
Land use :RESIDENTIAL - ONE FAMILY UNIT
Lot Description :Subdivision :
Recorded Survey :
Estate Number :
Recent Sales Information
2/20/1987 RUSSELL, DALE B BRYSON, DAVID L & MAMIE
J
BUILDING SALE $41,500
4/16/1999 BRYSON, DAVID L &
MAMIE J
BRYSON, DAVID L STRAIGHT
TRANSFER
$0
9/10/2003 BRYSON, DAVID L DIGH, DEREK J &
STEPHANIE OWENS
VETERANS
ADMINISTRATIO
N LOAN
$84,000
6/26/2006 DIGH, DEREK J &
STEPHANIE OWENS
FLETCHER, DANA M STRAIGHT
TRANSFER
$109,000
SALE DATE Sellers Name Buyers Name Sale Type Sale Price
GARAGE/SHOP-DETACHED 1967 336 $6,850
RESIDENTIAL CONSTRUCTION 1955 1020 $72,180
Type of Structure Year Built Base Area 1st Floor Value
List of Improvements to Site
Craven County Geographic Information System
Craven County does NOT warrant the information shown on this page and should be used ONLY for tax assessment purposes.
This report was created by Craven County GIS reporting services on 5/21/2020 9:16:15 AM
6-044 -052
AMERICAN EAGLE RENTALS LLC
252 US HIGHWAY 70 W HAVELOCK NC 28532
252 W US 70 HWYProperty Address :
Parcel ID :
24 DUKE SD US 70Description :
0.701Assessed Acreage :Calculated Acreage :
2878-0322Deed Reference :12 11 2009Recorded Date :
$287,100
$122,500
$164,600
Total Value :
Land Value :
Improvement Value :3# of Improvements :
Owner :
Mailing Address :
City Name :
Drainage District :
Fire tax District :
Special District :
HAVELOCK
0.700
Tax Exempt :No
Land use :COMM - GENERAL COMMERCIAL USE
Lot Description :Subdivision :
Recorded Survey :
Estate Number :
Recent Sales Information
12/11/2009 WELLS, NORMAN EARL AMERICAN EAGLE
RENTALS LLC
STRAIGHT
TRANSFER
$125,000
SALE DATE Sellers Name Buyers Name Sale Type Sale Price
ASPHALT PAVING 1969 0 $2,100
WAREHOUSE - STORAGE 1969 9315 $66,700
RETAIL STORE 1969 6461 $95,800
Type of Structure Year Built Base Area 1st Floor Value
List of Improvements to Site
Craven County Geographic Information System
Craven County does NOT warrant the information shown on this page and should be used ONLY for tax assessment purposes.
This report was created by Craven County GIS reporting services on 5/21/2020 9:15:43 AM
6-045 -001
MLP/CPL LLC
PO BOX 649 MOUNT OLIVE NC 28365
101 KETNER BLVDProperty Address :
Parcel ID :
COR HWY 70 KETNERDescription :
0.610Assessed Acreage :Calculated Acreage :
2843-0586Deed Reference :7 22 2009Recorded Date :
$195,150
$106,750
$88,400
Total Value :
Land Value :
Improvement Value :3# of Improvements :
Owner :
Mailing Address :
City Name :
Drainage District :
Fire tax District :
Special District :
HAVELOCK
0.610
Tax Exempt :No
Land use :COMM - CONVENIENCE STORE
Lot Description :Subdivision :
Recorded Survey :
Estate Number :
Recent Sales Information
1/28/2003 MAOLA MILK & ICE
CREAM CO INC
EXP PROPERTIES LLC STRAIGHT
TRANSFER
$0
7/22/2009 POPE, E J JR MLP/CPL LLC STRAIGHT
TRANSFER
$0
8/3/2004 EXP PROPERTIES LLC POPE, E J JR STRAIGHT
TRANSFER
$180,000
SALE DATE Sellers Name Buyers Name Sale Type Sale Price
ASPHALT PAVING 1990 0 $3,400
CONVENIENCE STORE 1970 2442 $77,200
SERVICE STATION PUMP CANOPY 1990 0 $7,800
Type of Structure Year Built Base Area 1st Floor Value
List of Improvements to Site
Craven County Geographic Information System
Craven County does NOT warrant the information shown on this page and should be used ONLY for tax assessment purposes.
This report was created by Craven County GIS reporting services on 5/21/2020 9:15:13 AM
6-045 -019
GRAYS HAVELOCK LLC
PO BOX 1596 HAVELOCK NC 28532
248 W US 70 HWYProperty Address :
Parcel ID :
2 CENTRAL HWYDescription :
0.460Assessed Acreage :Calculated Acreage :
2155-1029Deed Reference :3 5 2004Recorded Date :
$132,100
$80,500
$51,600
Total Value :
Land Value :
Improvement Value :2# of Improvements :
Owner :
Mailing Address :
City Name :
Drainage District :
Fire tax District :
Special District :
HAVELOCK
0.460
Tax Exempt :No
Land use :COMM - AUTO SERVICE/REPAIR
Lot Description :Subdivision :
Recorded Survey :
Estate Number :
Recent Sales Information
4/27/2001 STOCKS, VERNON H G & H TIRE & AUTO INC MULTI-PARCEL-
SALE*
$89,500
3/5/2004 G & H TIRE & AUTO INC GRAYS HAVELOCK LLC MULTI-PARCEL-
SALE*
$0
SALE DATE Sellers Name Buyers Name Sale Type Sale Price
ASPHALT PAVING 1950 0 $3,600
GARAGES - SERVICE 1950 4095 $48,000
Type of Structure Year Built Base Area 1st Floor Value
List of Improvements to Site
Craven County Geographic Information System
Craven County does NOT warrant the information shown on this page and should be used ONLY for tax assessment purposes.
This report was created by Craven County GIS reporting services on 5/21/2020 9:17:37 AM
6-044 -044
MNM INVESTMENTS LLC
33 CHEROKEE DR HAVELOCK NC 28532
249 W US 70 HWYProperty Address :
Parcel ID :
13,14 TILTON & 4 BLK D SEC 1 DONLEE HGTSDescription :
1.620Assessed Acreage :Calculated Acreage :
2649-0285Deed Reference :9 21 2007Recorded Date :
$584,412
$283,500
$300,912
Total Value :
Land Value :
Improvement Value :5# of Improvements :
Owner :
Mailing Address :
City Name :
Drainage District :
Fire tax District :
Special District :
HAVELOCK
1.620
Tax Exempt :No
Land use :COMM - STG UNITS/MINI & MAXI
Lot Description :Subdivision :
Recorded Survey :
Estate Number :
Recent Sales Information
12/14/1998 CIESZKO TRUST
EDWARD N CIESZKO
TRS
CIESZKO CONSTRUCTION
CO INC
STRAIGHT
TRANSFER
$0
9/21/2007 MNM INVESTMENTS LLC MNM INVESTMENTS LLC MULTI-PARCEL-
SALE*
$0
1/5/2007 CIESZKO
CONSTRUCTION CO INC
MNM INVESTMENTS LLC STRAIGHT
TRANSFER
$560,000
SALE DATE Sellers Name Buyers Name Sale Type Sale Price
CHAIN LINK FENCING 1976 0 $3,200
ASPHALT PAVING 1985 0 $5,300
GENERAL OFFICE 1985 4000 $237,500
SITE VALUE 1984 0 $6,912
WAREHOUSE - STORAGE 1976 6000 $48,000
Type of Structure Year Built Base Area 1st Floor Value
List of Improvements to Site
Craven County Geographic Information System
Craven County does NOT warrant the information shown on this page and should be used ONLY for tax assessment purposes.
This report was created by Craven County GIS reporting services on 5/21/2020 9:18:09 AM
6-044 -027
MNM INVESTMENTS LLC
33 CHEROKEE DR HAVELOCK NC 28532
102 MANILA STProperty Address :
Parcel ID :
CENTRAL HWYDescription :
1.040Assessed Acreage :Calculated Acreage :
3036-0401Deed Reference :10 28 2011Recorded Date :
$182,000
$182,000
$0
Total Value :
Land Value :
Improvement Value :0# of Improvements :
Owner :
Mailing Address :
City Name :
Drainage District :
Fire tax District :
Special District :
HAVELOCK
1.040
Tax Exempt :No
Land use :COMM - GENERAL COMMERCIAL USE
Lot Description :Subdivision :
Recorded Survey :
Estate Number :
Recent Sales Information
9/1/1999 ROBINSON, WILLIAM
JAMES
ROBINSON, WILLIAM JAMES
HRS
MULTI-PARCEL-
SALE*
$0
9/1/1999 ROBINSON, WILLIAM
JAMES
TOON, ALBERT H STRAIGHT
TRANSFER
$0
9/1/1999 TOON, ALBERT H ROBINSON, WILLIAM JAMES STRAIGHT
TRANSFER
$0
4/8/2004 DARDEN, LINDA
ROBINSON & SILAS
ROBINSON, LORIS M &
DARDEN, LINDA
STRAIGHT
TRANSFER
$0
3/31/2004 ROBINSON, WILLIAM
JAMES HRS
DARDEN, LINDA ROBINSON
& SILAS
STRAIGHT
TRANSFER
$0
10/28/2011 BRANCH BANKING &
TRUST COMPANY
MNM INVESTMENTS LLC STRAIGHT
TRANSFER
$71,000
7/27/2011 ROBINSON, LORIS M &
DARDEN, LINDA
BRANCH BANKING & TRUST
COMPANY
STRAIGHT
TRANSFER
$66,500
SALE DATE Sellers Name Buyers Name Sale Type Sale Price
No improvements listed for this parcel
List of Improvements to Site
Craven County Geographic Information System
Craven County does NOT warrant the information shown on this page and should be used ONLY for tax assessment purposes.
This report was created by Craven County GIS reporting services on 5/21/2020 9:18:36 AM

APPENDIX B
Well Construction Record and Subsurface Log

Geological Resources, Inc.Phone: [phone]
3502 Hayes Road FAX: [phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Handy Mart 33
Address 101 Ketner Boulevard, Havelock, NC 28532
Boring Number MW-1 Date Drilled 5/20/20
Sample Method NA Drilling Method DPT 3.5"
Completion Details
Driller Justin Radford (Cert # 3270 A), GRI Log By Mike Ellis
Lab Sample OVA
Depth Sample Interval(ft)ppm LITHOLOGY
0
2
4
6
8
10

12
14
16

18
20
22

24
26
28

30
32
34
36
38
40
42
44
46
48
50
6' - 12' No recovery
Well set at 12'
Depth of 12' w/ 10' of screen; sand 1'-12'; bentionite 0.5'-1'; grout 0'-0.5'
0' - 0.5' Asphalt
0.5' - 6' Gray Clay and Fine Sand

APPENDIX C
Terraquest Phase II ESA Report

100 East Ruffin Street ꞏMebane, North Carolina 27302
Telephone [phone] ꞏFacsimile [phone]
www.terraquestpc.com

May 1, 2020 

Citizens Bank 
300 Broad St. 
Elizabethton, TN 37643 

Re: Phase II Environmental Site Assessment Letter 
MLP/CPL, LLC/Handy Mart #33 
101 Ketner Blvd. 
Havelock, NC 28532 
TerraQuest Project No. 03720 

To whom it may concern: 

Terraquest Environmental Consultants, P.C. (Terraquest) has completed this Phase II Environmental Site 
Assessment (ESA) letter summarizing the soil and groundwater sampling activities at the Handy Mart #33 
facility located at 101 Ketner Blvd. in Havelock, Craven County, NC (herein referred to as the subject 
property).  The purpose of this letter is to document the findings of the limited soil and groundwater 
assessment performed at the subject property by Terraquest and explains the ramifications of what was 
discovered.  The location of the subject property is depicted in the attached Figure 1. 

Site Summary 

The subject property totals 0.610‐acres in size and contains a convenience store, UST system and a fuel 
dispenser canopy that were built in 1970.  The subject property is located inside the city limits of Havelock, 
NC.  Residential properties are located to the east of the property along Ketner Blvd.  Commercial 
properties including a furniture store, an automotive repair garage, and construction company are located  
to the north, south, and west, respectively.  The subject property is relatively flat with a slight slope to the 
south.  City water and city sewer are connected to the subject property convenience store building. 

Initial Site Survey 

The Phase I ESA completed for the subject property identified one Recognized Environmental Condition 
(RECs): 1) the former commercial UST system consisting of four (4) 4,000‐gallon gasoline USTs, 2 
dispensers, and piping {North Carolina Division of Waste Management – Underground Storage Tank 
(NCDWM‐UST) Facility ID 00‐0‐0000001074}.  The USTs and product lines were of steel construction and 
were installed in 1971 and removed in 1990.  The UST system is believed to have been located in the same 
location as the current system USTs, dispensers, and product lines. 

The concerns with this REC is the threat to the soil and groundwater quality at the subject property given 
that the former UST system operated without cathodic protection, over‐fill protection, and spill 
containment from 1971 to 1990. 

MLP/CPL, LLC/Handy Mart #33 
101 Ketner Blvd., Havelock, NC 28532 
Page 2 
May 1, 2020 

Geophysical Investigation 

On March 20, 2020, Terraquest contracted the completion of geophysical investigation of the subject 
property. The survey was conducted by Southeastern Locating Services, LLC of New Bern, NC.  The 
geophysical investigation, consisting of metal detection and ground penetrating radar (GPR) surveys, was 
completed to identify the location of the current three USTs and their corresponding product lines and 
determine if any USTs associated with the former gas station on the subject property were still in the 
ground.  Private utilities were also marked.   

No large buried metallic objects or product lines were noted during the geophysical investigation beneath 
the asphalt parking lot surrounding the convenience store building.  The USTs and product line trenches 
of the current UST system were found.  

Phase II ESA 

The focus of the Phase II ESA performed by Terraquest is to determine the soil and groundwater quality 
of the subject property in the vicinity of the former UST system, including the four former USTs, three 
current USTs, two current dispensers, and current product line piping.  Soil borings were not advanced 
along the northern and western side of the UST basin given the presence of buried utilities. 

Soil Sampling  

To determine soil quality at the subject property, Terraquest advanced the following soil borings: 

 SB1 – SB6 at the extents of the former and current UST system 
 PL1 and PL2 along the product line   
 D1 and D2 at each dispenser. 

All of the soil borings were advanced using direct push technology and a Macro‐Core tube retrieval 
sampling system.  Direct push technology consists of advancing a sampling device into the subsurface soils 
by applying static pressure, by applying impacts, by applying vibration, or any combination thereof, to the 
above ground portion of the sampler extensions until the sampler has advanced to the desired depth 
(ASTM D6282).  A single tube Macro‐Core sample system was utilized to collect soil samples in five‐foot 
intervals.  A single tube sample system used a hollow extension / drive rod to advance and retrieve the 
sampler.  Within the hollow extension, a new, single‐use, poly‐vinyl chloride (PVC) liner retained the soil 
sample as the tube is driven into the ground.  The specific direct push equipment utilized was a Geoprobe 
7822DT.  The Macro‐Core tube was decontaminated between each 5‐foot sample interval in a soil boring 
using a Liquinox and tap‐water mixture. A new PVC liner was used to collect soil from each sample interval 
in a soil boring.  Technical Methods and Standard Procedures utilized by Terraquest are attached.   

The soil boring depths were determined based upon the depth of the component sampled and to 
determine if a potential release had migrated vertically.  A listing of the soil boring depths is included in 
the attached soil boring logs.  In each soil boring, soils from the sample intervals were placed in sealable 
plastic bags and screened for volatile organic compounds (VOCs) and semi‐volatile organic compounds 
(SVOCs) utilizing a Photoionization Detector (PID).  The soil type was also logged.  The locations of the soil 

MLP/CPL, LLC/Handy Mart #33 
101 Ketner Blvd., Havelock, NC 28532 
Page 3 
May 1, 2020 

borings are identified in the attached Figure 2.  Soil sample intervals and their associated PID screening 
readings are listed in the attached soil boring logs.   

The soils to be submitted for analysis were determined by the PID screening readings. The soil samples 
having the greatest PID screening results were: 

 SB2 – along southern side of UST basin 
 SB5 –along eastern side of UST basin 
 PL1 – along product line trench 
 D1 – at dispenser island 

The soil samples collected for analysis were placed in the proper laboratory‐prepared sampling 
containers, labeled with the project name, project number, sample identification, required analysis, and 
date and time of collection.  The samples were immediately placed on ice and analyzed before the 
expiration of an analytical method’s prescribed holding time.  The soil samples were analyzed for total 
petroleum hydrocarbons (TPH) for low boiling point petroleum hydrocarbons (GRO) and medium to high 
boiling point petroleum hydrocarbons (DRO) by UVF Trilogy technology.  Chain‐of‐custody documentation 
was maintained for the soil samples.   

Soil Sample Analytical Results  

The NCDEQ DWM‐UST Action Limit of 50 milligram/kilogram (mg/kg) for TPH GRO and/or 100 mg/kg for 
TPH DRO were exceeded in the following soil samples:   

 SB2  (216 mg/kg GRO) 
 SB5  (860 mg/kg GRO and 200 mg/kg DRO) 
 D1 (104 mg/kg GRO) 

No concentrations above the NCDEQ DWM‐UST Action Limits were detected in the PL1 soil sample.  The 
attached Table 1 summarizes the sample depth and detected concentrations of the soil samples.  The 
locations of the soil samples are identified in the attached Figure 2.  The complete analytical report is 
attached. 

Groundwater Sampling  

To determine groundwater quality, Terraquest personnel advanced an SP16 groundwater sampling 
apparatus at two locations on the subject property: 1) off the eastern edge of the UST basin (GW1); and 
2) off the western dispenser island (GW2). The SP16 sampling apparatus was advanced at each location 
using the Geoprobe 7822DT to a depth of 9 feet BGL. The outer sample sheath was retracted revealing a 
36‐inch stainless‐steel screen that allowed groundwater to enter.  Groundwater samples were collected 
using a stainless‐steel check valve attached to new disposable polyvinyl tubing.  The valve was lowered 
into the sampler through steel rods, and the groundwater sample was brought to the ground surface by 
field personnel wearing disposable nitrile gloves moving the check valve up and down.  Groundwater was 
transferred directly from the tubing into laboratory‐prepared sampling containers to reduce the chance 
of contamination loss through volatilization.  The samples were labeled with the project name, project 

MLP/CPL, LLC/Handy Mart #33 
101 Ketner Blvd., Havelock, NC 28532 
Page 4 
May 1, 2020 

number, sample identification, required analysis, and date and time of collection.  The samples were 
placed on ice, sent to a North Carolina‐certified laboratory, and analyzed before the expiration of an 
analytical method’s prescribed holding time.  Chain‐of‐custody documentation was maintained for the 
collected samples.  Prior to collecting each groundwater sample, the stainless‐steel check valve was 
decontaminated using a Liquinox and tap water cleaning solution in order to prevent sample cross‐
contamination and new polyvinyl tubing was used for the groundwater sample.  Technical Methods and 
Standard Procedures utilized by Terraquest are attached.  The locations of the GW1 and GW2 
groundwater samples are depicted in the attached Figure 2. 

Both groundwater samples were analyzed by EPA Method 6200B plus 5 Oxygenates for VOCs. 

Groundwater Sample Analytical Results  

Analytical results of both the GW1 and GW2 groundwater samples revealed detected concentrations 
greater than the Title 15A NCAC 2L .0202 Groundwater Quality Standards (2L Standards) for numerous 
compounds common in gasoline including benzene, ethylbenzene, total xylenes, and naphthalene.  One 
oxygenate compound (T‐Amyl Alcohol) was detected in the GW2 sample above its 2L Standard.  
Oxygenate compounds were not used in gasoline during the operation of first UST system from 1971 to 
1990.  No concentrations were reported at levels in excess of Gross Contamination Levels (GCLs) in both 
groundwater samples.  The attached Table 2 summarizes the GW1 and GW2 groundwater sample 
analytical results.  The complete analytical report is also attached.  

Findings 

The soil sample results reveal levels of soil contamination in excess of the NCDEQ DWM‐UST Action Limits 
for GRO and DRO in two of the soil samples collected from the southern and eastern side of the UST basin 
and one soil sample collected at the dispenser island.  Groundwater analytical results reveal contaminant 
concentrations above their 2L Standards in the GW1 and GW2 samples.    

The soil and groundwater contamination is likely associated with a release from the former UST system 
and the current UST system. The presence of T‐Amyl Alcohol in the groundwater sample collected at the 
dispenser island typically indicates a newer release associated with the use of ethanol gasoline in the 
current UST system.  

No prior UST release incidents have been reported for the subject property.   

Recommendations 

Terraquest recommends the following scope of work to address the findings of the Phase II ESA: 

1) Report the discovery of the release incident to the NCDEQ DWM‐UST Washington Regional Office; 
2) Confirmation that the current UST system is not actively leaking through completion of tank and 
line tightness tests and leak detector test; 
3) Completion of a Limited Site Assessment to determine the risk‐classification of the release 
incident per the NCDEQ DWM‐UST regulations; 

MLP/CPL, LLC/Handy Mart #33 
101 Ketner Blvd., Havelock, NC 28532 
Page 5 
May 1, 2020 

We appreciate the opportunity to provide environmental services.  If you have any questions regarding 
this letter, please call me at (919) 563‐9091 or (919) 906‐0707.  

Sincerely, 

TERRAQUEST ENVIRONMENTAL CONSULTANTS, P.C. 

Jonathan R. Grubbs, P.G.      
Vice President     

Attachments 

Table 1: Summary of Soil Sampling Results 
Table 2: Summary of Groundwater Sampling Results 
Figure 1: Site Location Map 
Figure 2: Site Layout & Sample Location Map 
Technical Methods and Standard Procedures 
Soil Boring Logs 
Analytical Report 
Table 1
4/30/2020
3550/DRO5030/GRODate Collected Sample Depth PID (ppm)
SB2 4/27/2020 3  ‐ 5 804.1 70 216
SB5 4/27/2020 3  ‐ 5 2,457 200 860
PL1 4/27/2020 3  ‐ 5 22.1 0.5 4.44
D1 4/27/2020 4  ‐ 5 61.5 <10 104
100 50
Notes:
1. All TPH results in mg/kg.  PhotoIonization Readings are listed in parts per million (ppm)
2.Bold denotes a compound detection.
3. Shading denotes a TPH Action Limit violation.
4. "<" = less than sample detection limit
5. Sample depths are in feet below ground level.TPH low fractionBarn 1
TPH Action Limit
SUMMARY OF SOIL SAMPLING RESULTS
 Incident Name: Handy Mart #33 ‐ 101 Ketner Blvd. Havelock, NC   Incident No.: Pending       
Analytical Method  
Sample ID
Contaminant of Concern
TPH high fraction
Table 2Date: 5/1/206200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200BWell IDDate CollectedBenzeneTolueneEthylbenzeneTotal XylenesMethyl tert‐butyl ether (MTBE)1,2,4‐Trimethylbenzene1,3,5‐trimethylbenzeneT‐Amyl Alcoholn‐ButylbenzeneNaphthaleneDiisopropyl etherSec‐ButylbenzeneIsopropylbenzenen‐Propylbenzenep‐IsopropyltouleneGW1 4/27/20201,530 51 2,060 2,033< 8.452,930 790< 1321,190 1,030< 4.60558649 2,180 245GW2 4/27/202062.6 1.84 9.58 5.34 0.540 11.7 1.41 43.2 14.1 35.0 1.154.025.83 21.1< 0.08901 600 600 500 20 400 4004070 6 70707070255,000 260,000 84,500 85,500 20,000 28,500 25,00040,000 6,900 6,000 70,000 8,500 25,000 30,000 11,700Notes:1. All results in µg/L.2.Bold denotes a detected concentration.3. Shading denotes a 2L Standard exceedence4.Italics denotes a GCL exceedence 5. < ‐ denotes less than sample detection limit.6. NE ‐ Not Established; Analytical Method:GROUNDWATER SAMPLING RESULTS Incident Name: Handy Mart #33 ‐ 101 Ketner Blvd. Havelock, NC   Incident No.: Pending       2L StandardGCL
ONSULTANTS, P.C.CENVIRONMENTAL
ENVIRONMENTAL ACRONYMS

2L Standard Groundwater Standards under Title 15A NCAC 2L 0.0202(g)
2B Standard Surface Water Standards under Title 15A NCAC 2B
AFVR Aggressive Fluid-Vapor Recovery
AST Aboveground Storage Tank
BGL Below Ground Level
BNA Base Neutral and Acid Extractables
C&D Construction and Demolition
CAP Corrective Action Plan
CSA Comprehensive Site Assessment
EPA Environmental Protection Agency
EPH Extractable Petroleum Hydrocarbons
ESA Environmental Site Assessment
GCL Gross Contamination Level
LEL Lower Explosive Limit
LSA Limited Site Assessment
IPE di-Isopropyl Ether
MADEP Massachusetts Department of Environmental Protection
mg/kg Milligrams per kilogram
MMPE Mobile Multi Phase Extraction
MSCC Maximum Soil Contaminant Concentration
MSW Municipal Solid Waste
MTBE Methyl tertiary-Butyl Ether
NC North Carolina
NCAC NC Administrative Code
NCDEQ NC Department of Environmental Quality
NCDOT NC Department of Transportation
NCDWM-SW NC Division of Waste Management’s Solid Waste Section
NCDWM-UST NC Division of Waste Management’s UST Section
NORR Notice of Regulatory Requirements
NORP Notice of Residual Petroleum
NOV Notice of Violation
NPDES National Pollutant Discharge Elimination System
OVM Organic Vapor Meter
PID Photo Ionization Detector
PLC Programmable Logic Controller
POE Point of Entry (water treatment system)
POTW Publicly Owned Treatment Works
RBCA Risk Based Corrective Action
SVE Soil Vapor Extraction
stg Soil to Groundwater (MSCC)
TA Task Authorization
TCC Target Cleanup Concentrations
Terraquest Terraquest Environmental Consultants, P.C.
TPH Total Petroleum Hydrocarbon
UST Underground Storage Tank
VOA Volatile Organic Analysis
VOC Volatile Organic Compound
VPH Volatile Petroleum Hydrocarbons
MNA Monitored Natural Attenuation
TECHNICAL METHODS/STANDARD PROCEDURES

Equipment Decontamination

All soil sampling equipment utilized during site assessment activities is decontaminated according
to standard and accepted protocol. Cleaning solutions range from clean potable water to acidic
solutions or organic solvents depending on the contaminants present at the site. Equipment
utilized at sites, such as hand augers, contaminated with petroleum hydrocarbons, is generally
decontaminated with a low-sudsing detergent such as Luiquinox® and triple rinsed with distilled
water. Larger equipment, such as drill rigs and associated tools, is steam cleaned. All
decontamination procedures are completed within an established decontamination area which is
located away from the active study area. Frequency of equipment decontamination depends on
the nature of work being performed, but in no case is decontamination performed less frequently
than once per test (i.e., soil boring, well installation, sample collection, etc.). Equipment blanks are
collected as a quality control measure when required by job specifications.

Soil Boring Installation

Soil borings are completed using hand-operated sampling tools, truck-mounted drills, or
Geoprobe® drilling rigs depending on the depth of sample collection and other site-specific
conditions. Hand operated stainless-steel bucket augers are utilized to collect soil samples at
regular intervals to determine site stratigraphy and to test for the presence of volatile organic
compounds. Samples retrieved from the hand auger are necessarily disturbed during the augering
process, but can provide accurate information on soil type and contaminant concentrations when
properly interpreted. Soil samples from hand augered borings are generally retrieved at one to
two foot intervals.

Truck-mounted or Geoprobe® drilling equipment is often utilized when sample retrieval depths
exceed twenty feet or subsurface conditions prevent utilization of hand augers (i.e., buried rocks,
wood, bricks or other materials occur in the subsurface). Truck-mounted drilling rigs usually
retrieve soil via a hollow-stem auger/split spoon collection method. Geoprobe® rigs usually employ
a Macro-Core® tube retrieval system.

Hollow stem augers provide relatively undisturbed 2-foot cores of soil samples. Soil samples are
generally collected at five foot intervals utilizing standard penetration test procedures as defined
by the American Society for Testing and Materials (ASTM) or are pushed to the desired depth using
the head of the drill rig. The standard penetration test involves driving a 2" outside diameter by 1-
3/8" inside diameter split-spoon sampler a minimum distance of one foot with a 340-lb. slide
hammer falling a distance of 30 inches.

A Geoprobe® rig is a hydraulically-powered soil probing machine. The probe utilizes static force
and percussion to advance a small diameter sampling device into the subsurface. The sampling
apparatus provides relatively undisturbed 5-foot cores of soil samples. Soil samples are collected
continuously. The Macro-Core® tube contains an inserted poly-vinyl chloride (PVC) liner which
retains the soil sample as the tube is driven into the ground. The Macro-Core® tube is
decontaminated between each 5-foot sample interval in a soil boring using a Liquinox and tap-
water mixture. A new PVC liner is used to collect soil from each sample interval in a soil boring.

Soil samples retrieved from the hollow-stem augers or Geoprobe are then carefully described
according to the Unified Soil Classification System. Soil descriptions are recorded on a soil
boring log.

Soil Sampling

Soils to be analyzed by a North Carolina-certified laboratory are prepared according to the specified
analytical method. Initially, soil samples are removed from the ground using either a hand auger,
backhoe bucket, spilt spoon auger, or a Macro-Core® sampling tube. During the removal, care is
taken to keep the disturbance of the soil structure to a minimum to reduce the loss of
contaminants. Once removed, the samples are placed in the proper sample container for the
specified analytical method. For samples collected for the MADEP VPH and EPA Method 8260, a
TerraCore® sampler is used to collect one 5-gram allotment of soil. The allotment is placed in
methanol-preserved 40 mL vials. Also, one 5-gram allotment of soil is placed into sodium bisulfate-
preserved 40 mL vials (one 5-gram allotment per vial, 2 vials per sample) for the 8260 low
concentration method. A 250-mL glass jar of the sampled soil is also collected to provide moisture
content information. Soils sampled for MADEP EPH, EPA Method 8270 and TPH 5030 and 3550 are
placed in a 250-mL glass jar (for MADEP EPH analysis an amber jar is required). TPH 5030 samples
are preserved in methanol similar to the 8260 analysis. Field personnel wear new, disposable
nitrile gloves during the collection of each sample.

The soil samples are labeled with the sample location, sample identification, date and time of
collection, and the analytical method. The samples are placed on ice, sent to a laboratory, and
analyzed before the expiration of an analytical method’s prescribed holding time. Chain-of-custody
documentation is maintained for each sample collected in the field.

If the soil is being sampled for volatile or semi-volatile compounds, a portion of the collected soil is
placed in a sealable bag and screened for volatile organic vapors. Head screening procedures are
described in the following paragraph.

Headspace Screening

Collected soil samples are routinely tested for the presence of volatile organic compounds (VOCs).
After retrieval from the ground, a portion of a soil sample is placed in a sealable plastic bag. The
soil samples are then set aside for approximately five minutes so that volatile constituents present
in the sample can reach equilibrium concentrations with headspace gases in the bag. Once a
suitable time period has passed, the probe of the sampling instrument, typically an Organic Vapor
Monitor (OVM) or a Photo Ionization Detector (PID), is inserted into the bag and the relative
concentration of total VOCs is measured and permanently recorded in a field note book. VOC
concentrations are measured using either a Thermo Electron Corp. Innova Series catalytic OVM or
an Ion Science PhoCheck PID. Both the OVM and PID instrumentation are periodically calibrated
according to the manufacturer’s recommended procedures.

The OVM and PID are qualitative tools employed to detect and estimate the concentration of
organic or hydrocarbon vapors. A thin probe is inserted through a small break in the seal of a
bagged soil sample. For the OVM, an air sample from the headspace of the bag is drawn through
the probe into an internal chamber where the vapors are catalyzed. The concentration of the VOCs
is registered on a digital scale in parts per million (ppm). For the PID, an air sample from the
headspace of the bag is drawn across the face of a lamp causing the sample to emit photons, the
presence of which are converted into a VOC ppm reading that is displayed. Oxygen levels are field
calibrated prior to each use. VOC calibration occurs periodically depending upon use by using a
span gas of known concentration in a process recommended by the manufacturer.

Well Installation/Construction

Monitoring wells are installed using hand-operated sampling tools, a truck-mounted drill rig, or a
Geoprobe drilling rig depending on the depth of well and other site-specific conditions. All
monitoring wells are installed according to the requirements of 15A NCAC 2C-Well Construction
Standards. Specifically, individual monitoring wells are constructed of 2-inch diameter, schedule 40
PVC casing riser and screen. The screen interval is generally 10 to 15 feet of machine slotted PVC
with a slot size of 0.010". Only flush threaded joints are used. The annulus space around the
screen is filled with washed filter pack No. 2 sand. The filter pack extends one to two feet above
the top of the screen. A one to two foot-thick bentonite pellet seal is then placed above the filter
pack. The remainder of the well annulus is completely filled with a Portland (Type I/II) cement
grout mixture. A protective outer steel manhole, locking cap, and concrete pad is installed for each
well.

Type II Monitoring Well Construction

Single-cased monitoring wells are generally used in delineation of groundwater quality within the
surficial aquifer. The wells are constructed of 2-inch diameter, schedule 40 PVC casing and screen.
The screen interval is generally 10 to 15 feet of machine slotted PVC with a slot size of 0.010". Only
flush threaded joints are used. The annulus space around the screen is filled with washed filter
pack No. 2 sand. The filter pack extends one to two feet above the top of the screen. A one to two
foot-thick bentonite pellet seal is then placed above the filter pack. The remainder of the well
annulus is completely filled with a Portland (Type I/II) cement grout mixture. A protective outer
steel manhole, locking cap, and concrete pad are installed for each well.

Type III Monitoring Well Construction

Double-cased monitoring wells are used in the delineation of groundwater quality within a deeper
portion of the surficial aquifer or an additional aquifer (e.g. aquitard, bedrock). A four to six-inch
outer casing is installed through the surficial aquifer until a sufficient depth or until the deeper
aquifer is encountered. The casing is secured with a Portland-grout collar that is tremmied into the
annular spaced from the bottom of the bore hole to the surface. Once the grout has sufficiently
cured, the bore hole is continued through the bottom of the outer casing to a depth approximately
15 - 20 feet beneath the outer casing. The inner casing is constructed of 2-inch diameter, schedule
40 PVC casing riser and screen. The screen interval is generally 5 to 10 feet of machine slotted PVC
with a slot size of 0.010". Only flush threaded joints are used. The annulus space around the
screen is filled with washed filter pack No. 2 sand. The filter pack extends one to two feet above
the top of the screen. A one to two foot-thick bentonite pellet seal is then placed above the filter
pack. The remainder of the well annulus is completely filled with the same Portland grout mixture
used in the outer casing. A protective outer steel manhole, locking cap, and concrete pad are
installed for each well.

Well Development

Following installation of each well, surging and pumping or bailing techniques will be used to
remove fines from the screened interval. Groundwater is removed from each well until clear water
is retrieved or a noticeable reduction in the amount of silt is achieved. Purged groundwater is
disposed of in an environmentally safe manner.

Groundwater Sampling

Petroleum Sites

Groundwater samples are collected from temporary or permanent monitoring wells according to
established sampling protocol. When multiple monitoring wells or sampling points are sampled,
sampling is completed beginning with the least contaminated well to the most contaminated well,
if it is known. When permanent monitoring wells for petroleum sites are sampled, the well is
purged of a minimum of three well-bore volumes prior to sample collection in order to assure that
sampled water is representative of aquifer conditions. In temporary wells, the first water which
migrates into the open borehole is sampled. Samples from both temporary and permanent
monitoring wells are collected using individually wrapped disposable polyethylene bailers by field
personnel wearing disposable nitrile gloves. Only one well is sampled with a given bailer in order to
prevent sample cross-contamination. During both well purging and sampling, proper protective
clothing and equipment is used and is dependent upon the type and level of contaminants present.
Also, field personnel change gloves between different samples to reduce the chance of cross-
contamination. Water samples are transferred from the bailer to laboratory-prepared sampling
containers using slow emptying devices to reduce the chance of contamination loss through
volatilization. Preservatives, such as acids, are provided by the laboratory in pre-prepared
containers in which collected samples are placed if in-field preservation is necessary. The samples
are labeled with the project name, project number, sample identification, required analysis, and
date and time of collection. The samples are placed on ice, shipped to a certified laboratory, and
analyzed before the expiration of an analytical method’s prescribed holding time. Chain-of-custody
documentation is maintained for each sample collected in the field.

Other Groundwater Sampling Protocols

When required by state or federal regulations, low-flow groundwater sampling procedures are
instituted. Groundwater samples collected in low-flow situations are collected using a peristaltic
pump. A peristaltic pump is a type of positive displacement pump. The fluid is contained within a
flexible tube fitted inside a circular pump casing. A rotor with a number of rollers attached to the
external circumference compresses the flexible tube. As the rotor turns, the part of tube under
compression closes thus forcing the fluid to be pumped to move through the tube. Groundwater
parameters such as water level drawdown, pH, conductivity, dissolved oxygen (DO) and turbidity.
Pumping rate, drawdown, and the time or volume required to obtain stabilization of parameter
readings can be used as a future guide to purge the well. Measurements are collected at a pre-
pumping established interval (typically five to ten minutes). Once all or a majority of the
parameters have stabilized for three successive readings, stabilization has been achieved. In lieu of
measuring all five parameters, a minimum subset would include pH, conductivity, and turbidity or
DO. Three successive readings should be within ± 0.1 for pH, ± 3% for conductivity, and ± 10% for
turbidity and DO.

Upon parameter stabilization, sampling is initiated. Sampling flow rate is maintained at the estab-
lished purge rate or is adjusted slightly to minimize aeration, bubble formation, turbulent filling of
sample bottles, or loss of volatiles due to extended residence time in tubing. The same device used
for purging is used to collect the groundwater sample. Generally, volatile parameters are sampled
first. The sequence in which samples for inorganic parameters are collected is not determined
unless filtered (dissolved) samples are collected. Preservatives, such as acids, are provided by the
laboratory in pre-prepared containers in which collected samples are placed if in-field preservation
is necessary. The samples are labeled with the project name, project number, sample
identification, required analysis, and date and time of collection. The samples are placed on ice,
shipped to a certified laboratory, and analyzed before the expiration of an analytical method’s
prescribed holding time. Chain-of-custody documentation is maintained for each sample collected
in the field.

During both well purging and sampling, proper protective clothing and equipment is used and is
dependent upon the type and level of contaminants present. Also, field personnel change gloves
between different monitoring wells or sampling points to reduce the chance of cross-
contamination. When multiple monitoring wells or sampling points are sampled, sampling is
completed beginning with the least contaminated well to the most contaminated well, if it is
known.

Stockpile Sampling

The number of composite samples collected from a stockpile or a total quantity of excavated soil is
based upon the cubic yardage. One composite sample is collected for every 100 cubic yards of
contaminated soil excavated. The volume of a stockpile or total quantity of excavated soil is
calculated by approximating the general geometry of a stockpile or estimating the capacity of the
dump trucks used for hauling. If a stockpile is sampled, a grid pattern is laid out on the stockpile,
dividing the stockpile into segments of approximately 200 cubic yards. Two soil borings are
advanced within a grid and three soil samples are collected from each soil boring at various depths.
The six soil samples are mixed into a composite sample by a trained TerraQuest technician. If truck
loads are sampled, an aliquot sample is collected from the hauling trucks at a frequency based
upon the capacity of the hauling trucks.

Aliquots are gently mixed into a composite sample by a trained TerraQuest technician. Every effort
is made to minimize the loss of contaminants through volatilization. The composited soil samples
are jarred in the appropriate laboratory-prepared containers, labeled with the sample location,
sample identification, date of collection, time of collection, the analytical method, and the
preservative. The samples are placed on ice, shipped to a laboratory, and analyzed before the
expiration of an analytical method’s prescribed holding time. Chain-of-custody documentation is
maintained for each sample collected in the field.

Surface Water Sampling

Surface water samples, specifically samples from creeks or streams, are collected from a
moving/flowing portion of the creek or stream to ensure that stagnant water is not collected. Field
personnel are careful to collect samples from flowing areas that are not so turbulent as to cause a
loss of volatile contaminants which might have been contained in the creek’s/stream’s water.
Samples are collected by field personnel wearing disposable nitrile gloves. Field personnel change
gloves between different locations to reduce the chance of cross-contamination. Samples are
collected directly from the appropriate creek or stream location and placed into the appropriate
laboratory-prepared containers. Preservatives, such as acids, are provided by the laboratory in pre-
prepared containers in which collected samples are placed if in-field preservation is necessary. The
samples are labeled with the project name, project number, sample identification, required
analysis, and date and time of collection. The samples are cooled on ice to approximately four
degrees centigrade, shipped to a certified laboratory, and analyzed before the expiration of an
analytical method’s prescribed holding time. Chain-of-custody documentation is maintained for
each sample collected in the field.

Potable Well Sampling

Groundwater samples from potable wells are collected from sampling points, typically spigots,
located in the closest proximity to the potable well pump house as possible. Prior to sample
collection, the water is run for a sufficient amount of time to purge the bladder tank and assure
that sampled water is representative of aquifer conditions. Once purged, the flow rate is reduced
and samples are placed in the appropriate laboratory prepared containers with the appropriate
acid preservatives added if preservation of the sample is necessary. The samples are labeled with
the project name, project number, sample identification, required analysis, and date and time of
collection. The samples are placed on ice, shipped to a laboratory, and analyzed before the
expiration of an analytical method’s prescribed holding time. Chain-of-custody documentation is
maintained for each sample collected in the field.
Public Water Supply Line Sampling

Groundwater samples from public water supply lines are collected from sampling points, typically
spigots. To sample the spigot, the flow rate is reduced and samples are placed in the appropriate
laboratory prepared containers. The samples are labeled with the sample location, sample
identification, date of collection, time of collection, and required analytical method. The samples
are placed on ice, shipped to a laboratory, and analyzed before the expiration of an analytical
method’s prescribed holding time. Chain-of-custody documentation is maintained for each sample
collected in the field.

Air Sampling

Air samples are collected with the aide of a manually operated MityVac® pump manufactured by
Pristech, Inc. The air sampling process begins by connecting a length of rubber hose from the
MityVac® pump to the port to be sampled, or by hanging the hose inside of an emissions stack in
such a manner as to ensure no outside air causes dilution. Another length of hose is fixed to the
outlet port of the pump and is connected to a new Tedlar bag. Once the pump is hooked up, a
valve on the Tedlar collection bag is opened and air is manually forced into the bag by the pumping
action of sampling personnel.

Field Measurements

Field measurements taken to determine the pH, conductivity, temperature, and dissolved oxygen
concentration of a particular groundwater sample are taken directly after a particular monitoring
well has been adequately purged. This ensures that the groundwater parameter data collected is
representative of the aquifer conditions at a given location. Once purging of the monitoring well is
complete, the decontaminated probe head and cord of the appropriate unit is lowered into the
required monitoring well. If the depth to water in a specific monitoring well is greater than the
length of cord for a particular unit, a new, disposable bailer is slowly lowered into the appropriate
monitoring well and a representative groundwater sample is retrieved. A slow pouring device is
fitted onto the end of the disposable bailer and the sample is slowly poured into a new, disposable
plastic cup. Groundwater parameter data are then collected from the groundwater in the cup
using the required unit.

For pH, conductivity, and temperature, a Hanna Instruments Model 991300 portable meter is
utilized. This unit is periodically calibrated and maintained in accordance with the unit’s operations
manual by field personnel. Prior to data collection, the unit is properly decontaminated to prevent
cross-contamination. The unit is decontaminated between each sample. The procedure used for
sample measurement involves lowering the meter’s probe into the new, disposable cup containing
the groundwater sample to be measured and slowly stirring the probe to force groundwater across
the probe’s membrane. The measurements displayed by the meter are then recorded.

For dissolved oxygen concentration measurements, a YSI® Model 55 Handheld Dissolved Oxygen
System is utilized. This unit is periodically calibrated and maintained in accordance with the unit’s
operations manual by field personnel. Prior to data collection, the unit is properly decontaminated
to prevent cross-contamination. The unit is decontaminated between each sample. The procedure
used for sample measurement involves adjusting the unit for the correct altitude where the
sampling will take place and adjusting the reported units desired. Once this is done, the unit’s
probe is inserted into the groundwater sample to be measured and the probe is slowly stirred to
force the groundwater across the probe’s membrane. The measurements displayed by the unit are
then recorded.

For turbidity measurements, a Hach 2100P Portable Turbidity meter or equal equivalent is utilized.
The unit is calibrated prior to use in accordance with the unit’s operations manual by field
personnel. Groundwater samples are collected in glass containers for measurement by the
instrument. The glass containers are washed with bottled-water between each measurement
collection. Once the sample is collected and inserted into the instrument, the measurements
displayed by the instrument are then recorded.

5
10
Asphalt
Sandy Clay (CL)
grey, soft, mostly clay, some fine sand, moist at 5' BGL.
Clayey Sand (SC)
grey, loose, mostly fine-grained sand, some clay, wet
Boring Terminated at 10' BGL
NA
NA
44.5
0.4
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs SB1
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
10
Asphalt/Gravel
Sandy Clay (CL)
grey, soft, mostly clay, some fine sand
Pea Gravel
Clayey Sand (SC)
grey, loose, mostly fine-grained sand, some clay, wet
Boring Terminated at 10' BGL
NA
NA
804.1
1,643
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs SB2
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
10
Asphalt
Sandy Clay (CL)
grey, soft, mostly clay, some fine sand, moist at 5' BGL.
Clayey Sand (SC)
grey, loose, mostly fine-grained sand, some clay, wet
Boring Terminated at 10' BGL
NA
NA
54.1
15.7
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs SB3
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
10
Asphalt
Sandy Clay (CL)
grey, soft, mostly clay, some fine sand, moist at 5' BGL.
Clayey Sand (SC)
grey, loose, mostly fine-grained sand, some clay, wet
Boring Terminated at 10' BGL
NA
NA
83.6
40.3
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs SB4
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
10
Asphalt
Sandy Clay (CL)
grey, soft, mostly clay, some fine sand, peagravel 4.5'-4.75' BGL,
moist at 5' BGL.
Clayey Sand (SC)
grey, loose, mostly fine-grained sand, some clay, wet
Boring Terminated at 10' BGL
NA
NA
2,457
253.7
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs SB5
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
10
Asphalt/peagravel
Sandy Clay (CL)
grey, soft, mostly clay, some fine sand, moist at 5' BGL.
Clayey Sand (SC)
grey, loose, mostly fine-grained sand, some clay, wet
Boring Terminated at 10' BGL
NA
NA
40.6
12.9
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs SB6
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
10
Asphalt/peagravel
Fat Clay w/Sand (CH)
grey/yellowish-orange, med. stiff to soft, mostly clay, some fine sand,
moist at 5' BGL.
Clayey Sand (SC)
grey, loose, mostly fine-grained sand, some clay, wet
Boring Terminated at 10' BGL
NA
NA
22.1
8.3
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs PL1
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
10
Asphalt/peagravel
Fat Clay (CH)
grey/yellowish-orange, med. stiff to soft, mostly clay, some fine sand,
moist at 5' BGL.
Sandy Clay w/Organics (CL)grey/black, soft, mostly clay, some organics, little fine-grained sand,
wet
Boring Terminated at 10' BGL
NA
NA
10.7
8.4
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs PL2
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
Concrete
Sandy Clay (CL)
grey, soft, mostly clay, little fine sand, moist
Boring Terminated at 5' BGL
NA
NA
NA
NA
NA
NA
0.6
0.6
0.4
0.5
0.7
61.5
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs D1
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
5
Concrete
Sandy Clay (CL)
grey, soft, mostly clay, little fine sand, moist
Boring Terminated at 5' BGL
NA
NA
NA
NA
NA
2.6
1.7
5.7
10.2
16.2
BORING LOG
4/27/20
03720
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Handy Mart #33101 Ketner Ave.Havelock, NC
J Grubbs D2
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Citizens Bank300 Broad St.Elizabethton, TN 37643
Geoprobe 4/27/20
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel
0
UVF TRILOGY ANALYTICAL REPORT
Project Name: Handy Mart #33
101 Ketner Blvd, Havelock, NC
Project Number: 03720
Date: 4/28/20
Standard Technical Procedures

The UVF TRILOGY instrument is a fixed-wavelength fluorometer but uses deep UV LEDS to detect
monoaromatic and polyaromatic hydrocarbons.
SITELAB’s CAL-025 GRO Module is used to detect volatile petroleum hydrocarbons in the C6 to C10
range. This test matches well to EPA Methods for GRO, BTEX, BPH or VOC’s using GC/FID
instrumentation.
SITELAB’s CAL-042 EDRO Module is used to detect petroleum hydrocarbons in the C10 to C36 diesel and
oil range. This test matches well to EPA methods for TPH, EPH, DRO, and others using GC-FID
instrumentation.
Prior to field usage, the UVF TRILOGY is calibrated with five calibration standard solutions per targeted
analyte.
Soil samples are weighed to the nearest gram (i.e. 5.0 g) and added to a 1-ounce HDPE Nalgene bottle
with a measured amount of laboratory grade methanol to the nearest mL (i.e. 10 mL) to create a sample
extract. After addition of both the soil and methanol, the bottle is agitated for several minutes. Next,
the sample rests for several minutes allowing for the soil and methanol extract to separate.
After ample resting time, the methanol extract is collected with a syringe. A filter is connected to the
end of the syringe and dispensed into a clean sample test tube. The test tube is labeled with sample ID
and extract dilution factor (i.e. 2X).
Known amounts of extract are pipetted into a second test tube and diluted with methanol. The sample
ID and dilution factor are labeled on the test tube (i.e. 100X).
Samples are placed into a clean cuvette and carefully inserted into the selected UV Module. Prior to
analyzing the sample, the stored calibration that matches the UV Module being used, is selected. The
UVF TRILOGY produces a result that when multiplied to the dilution factor equals the true TPH value.
Quenching occurs when the detector is swamped by too many or certain type of hydrocarbons,
producing low or negative concentrations. The sample is tested at multiple dilutions to confirm the
results are linear and accurate.
Solvent blank samples are periodically analyzed to confirm the solvent is clean and the calibration of the
machine is maintained.

UVF Analytical Report
Project Name 101 Ketner Blvd. Havelock NC
Project Number 03720
Method UVF Trilogy
Sample Name D1
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
D1 4-5 4/27/2020 DRO 100 <10 10 mg/kg
D1 4-5 4/27/2020 GRO 200 104 100 mg/kg
Tuesday, April 28, 2020 Page 1 of 4
Project Name 101 Ketner Blvd. Havelock NC
Project Number 03720
Method UVF Trilogy
Sample Name PL1
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
PL1 3-5 4/27/2020 DRO 2 0.5 0.2 mg/kg
PL1 3-5 4/27/2020 GRO 2 4.44 1 mg/kg
Tuesday, April 28, 2020 Page 2 of 4
Project Name 101 Ketner Blvd. Havelock NC
Project Number 03720
Method UVF Trilogy
Sample Name SB2
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB2 3-5 4/27/2020 DRO 200 70 20 mg/kg
SB2 3-5 4/27/2020 GRO 200 216 100 mg/kg
Tuesday, April 28, 2020 Page 3 of 4
Project Name 101 Ketner Blvd. Havelock NC
Project Number 03720
Method UVF Trilogy
Sample Name SB5
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB5 3-5 4/27/2020 DRO 1000 200 100 mg/kg
SB5 3-5 4/27/2020 GRO 1000 860 500 mg/kg
Tuesday, April 28, 2020 Page 4 of 4
Analytical Report 660048
for
Terraquest Environmental Consultants, P.C.
Project Manager: Jonathan Grubbs
Handy Mart #33
03720
05.01.2020
Xenco Laboratories
1412 Tech Blvd.
Tampa, FL 33619
Ph:[phone] Fax:[phone]
Xenco-Houston (EPA Lab Code: TX00122):
Texas (T104704215-19-30), Arizona (AZ0765), Florida (E871002-24), Louisiana (03054)
Oklahoma (2019-058), North Carolina (681), Arkansas (19-037-0)
Xenco-Dallas (EPA Lab Code: TX01468):
Texas (TX104704295-19-22), Arizona (AZ0809), Arkansas (17-063-0)
Xenco-El Paso (EPA Lab Code: TX00127): Texas (T104704221-19-16)
Xenco-Lubbock (EPA Lab Code: TX00139): Texas (T104704219-19-21)
Xenco-Midland (EPA Lab Code: TX00158): Texas (T104704400-19-19)
Xenco-Carlsbad (LELAP): Louisiana (05092)
Xenco-San Antonio (EPA Lab Code: TNI02385): Texas (T104704534-19-5)
Xenco Phoenix (EPA Lab Code: AZ00901): Arizona (AZ0757)
Xenco-Tampa: Florida (E87429), North Carolina (483)
Page 1 of 14 Final 1.000
A Small Business and Minority Company
Houston - Dallas - Midland - Tampa - Phoenix - Lubbock - San Antonio - El Paso - Atlanta - New Mexico
Project Manager: Jonathan Grubbs
Terraquest Environmental Consultants, P.C.
100 E. Ruffin Street
Mebane, NC 27302
Reference: XENCO Report No(s): 660048
Handy Mart #33
Project Address:
Jonathan Grubbs:
We are reporting to you the results of the analyses performed on the samples received under the project name
referenced above and identified with the XENCO Report Number(s) 660048. All results being reported under
this Report Number apply to the samples analyzed and properly identified with a Laboratory ID number.
Subcontracted analyses are identified in this report with either the NELAC certification number of the
subcontract lab in the analyst ID field, or the complete subcontracted report attached to this report.
Unless otherwise noted in a Case Narrative, all data reported in this Analytical Report are in compliance with
NELAC standards. The uncertainty of measurement associated with the results of analysis reported is available
upon request. Should insufficient sample be provided to the laboratory to meet the method and NELAC Matrix
Duplicate and Matrix Spike requirements, then the data will be analyzed, evaluated and reported using all
other available quality control measures.
The validity and integrity of this report will remain intact as long as it is accompanied by this letter and
reproduced in full, unless written approval is granted by XENCO Laboratories. This report will be filed for at
least 5 years in our archives after which time it will be destroyed without further notice, unless otherwise
arranged with you. The samples received, and described as recorded in Report No. 660048 will be filed for 45
days, and after that time they will be properly disposed without further notice, unless otherwise arranged with
you. We reserve the right to return to you any unused samples, extracts or solutions related to them if we
consider so necessary (e.g., samples identified as hazardous waste, sample sizes exceeding analytical standard
practices, controlled substances under regulated protocols, etc).
We thank you for selecting XENCO Laboratories to serve your analytical needs. If you have any questions
concerning this report, please feel free to contact us at any time.
Respectfully,
05.01.2020
Project Manager
Chad Bechtold
Page 2 of 14 Final 1.000
Sample Cross Reference 660048
Terraquest Environmental Consultants, P.C., Mebane, NC
Handy Mart #33
Sample Id
GW1
GW2
04.27.2020 13:15
04.27.2020 13:45
Date Collected Lab Sample Id
660048-001
660048-002
Sample DepthMatrix
W
W
Page 3 of 14 Final 1.000
CASE NARRATIVE
660048Work Order Number(s):
05.01.2020Report Date: 03720Project ID:
Date Received:
Client Name: Terraquest Environmental Consultants, P.C.
Project Name: Handy Mart #33
04.29.2020
None
Sample receipt non conformances and comments:
Sample receipt non conformances and comments per sample:
Page 4 of 14 Final 1.000
Hits Summary 660048
Terraquest Environmental Consultants, P.C., Mebane, NC
Handy Mart #33
Sample ID: 660048-001
Sample ID: 660048-002
Date/Time Sampled: 04.27.2020 13:15
Date/Time Sampled: 04.27.2020 13:45
Matrix: Water
Matrix: Water
1,2,4-Trimethylbenzene
1,3,5-trimethylbenzene
Benzene
Ethylbenzene
Naphthalene
Sec-Butylbenzene
Toluene
Total Xylenes
isopropylbenzene
m,p-Xylenes
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Cymene (p-Isopropyltoluene)
1,2,4-Trimethylbenzene
1,3,5-trimethylbenzene
Benzene
Diisopropyl ether
Ethylbenzene
Methyl tert-butyl ether (MTBE)
Naphthalene
Sec-Butylbenzene
T-Amyl Alcohol
Toluene
Total Xylenes
isopropylbenzene
m,p-Xylenes
n-Butylbenzene
n-Propylbenzene
o-Xylene
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
SM6200B
100
50
50
50
50
50
50
100
50
50
50
50
50
50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
10.3
4.35
5.95
4.60
4.70
4.60
2.85
6.1
4.90
8.80
3.00
3.25
6.10
4.45
0.103
0.0870
0.119
0.0920
0.0920
0.169
0.0940
0.0920
2.64
0.0570
0.122
0.0980
0.176
0.0600
0.0650
0.122
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
95-63-6
108-67-8
71-43-2
100-41-4
91-20-3
135-98-8
108-88-3
1330-20-7
98-82-8
179601-23-1
104-51-8
103-65-1
95-47-6
99-87-6
95-63-6
108-67-8
71-43-2
108-20-3
100-41-4
1634-04-4
91-20-3
135-98-8
75-85-4
108-88-3
1330-20-7
98-82-8
179601-23-1
104-51-8
103-65-1
95-47-6
100
25.0
50.0
25.0
25.0
25.0
25.0
50
25.0
50.0
25.0
25.0
50.0
50.0
1.00
0.500
1.00
0.500
0.500
1.00
0.500
0.500
5.00
0.500
1
0.500
1.00
0.500
0.500
1.00
D
J
Sample ID: GW1
Sample ID: GW2
Analyte Name
Analyte Name
CAS No.
CAS No.
Dil.
Dil.
Result
Result
RL/PQL
RL/PQL
MDL
MDL
Units
Units
Qual
Qual
2930
790
1530
2060
1030
558
51.0
2033
649
1480
1190
2180
553
245
11.7
1.41
62.6
1.15
9.58
0.540
35.0
4.02
43.2
1.84
5.34
5.83
2.94
14.1
21.1
2.40
Method
Method
Below is a summary of the analytes which were found to be present in the samples associated with this work order. This should only
be used in conjunction with the included analytical results.
Page 5 of 14 Final 1.000
Certificate of Analytical Results 660048
Terraquest Environmental Consultants, P.C., Mebane, NC
Handy Mart #33
04.29.2020 09:21 Date Received:
04.27.2020 13:15 Date Collected:660048-001Lab Sample Id:
Ground WaterMatrix: GW1Sample Id:
VOCs + Oxygenates by GC/MS by SM6200B Analytical Method:
JNLAnalyst:
SM6200B_PREPPrep Method:
04.30.2020 11:44 Date Prep:
JNLTech:
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
3,3-Dimethyl-1-butanol
4-Chlorotoluene
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
Parameter
9.00
3.80
3.50
5.65
6.05
5.20
3.00
5.90
6.90
3.45
10.3
9.00
4.70
4.50
6.10
4.35
4.90
6.65
3.35
4.85
14.0
4.40
16.0
134
4.50
12.7
17.6
5.95
6.60
5.60
6.20
7.95
4.85
4.99
5.25
2.10
8.00
4.25
5.70
Result
U
U
U
U
U
U
U
U
U
U
D
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
50.0
25.0
25.0
50.0
50.0
50.0
25.0
50.0
50.0
25.0
100
125
25.0
25.0
50.0
25.0
25.0
50.0
25.0
25.0
100
25.0
100
250
25.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
25.0
25.0
50.0
25.0
50.0
50.0
50.0
Flag
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Units
50
50
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
DilCas Number
630-20-6
71-55-6
79-34-5
79-00-5
75-34-3
75-35-4
563-58-6
87-61-6
96-18-4
120-82-1
95-63-6
106-93-4
95-50-1
107-06-2
78-87-5
108-67-8
541-73-1
142-28-9
106-46-7
594-20-7
78-93-3
95-49-8
591-78-6
624-95-3
106-43-4
108-10-1
67-64-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
156-59-2
9.00 U
3.80 U
3.50 U
5.65 U
6.05 U
5.20 U
3.00 U
5.90 U
6.90 U
3.45 U
2930
9.00 U
4.70 U
4.50 U
6.10 U
790
4.90 U
6.65 U
3.35 U
4.85 U
14.0 U
4.40 U
16.0 U
134 U
4.50 U
12.7 U
17.6 U
1530
6.60 U
5.60 U
6.20 U
7.95 U
4.85 U
4.99 U
5.25 U
2.10 U
8.00 U
4.25 U
5.70 U
3124713Seq Number:
RL MDL
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 16:30
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
Analysis Date
% Moisture:
Page 6 of 14 Final 1.000
Certificate of Analytical Results 660048
Terraquest Environmental Consultants, P.C., Mebane, NC
Handy Mart #33
04.29.2020 09:21 Date Received:
04.27.2020 13:15 Date Collected:660048-001Lab Sample Id:
Ground WaterMatrix: GW1Sample Id:
VOCs + Oxygenates by GC/MS by SM6200B Analytical Method:
JNLAnalyst:
SM6200B_PREPPrep Method:
04.30.2020 11:44 Date Prep:
JNLTech:
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Diisopropyl ether
Ethanol
Ethyl tert butyl Ether
Ethylbenzene
T-Amyl Alcohol
isopropylbenzene
tert-Butyl formate
m,p-Xylenes
Methylene Chloride
Methyl tert-butyl ether (MTBE)
Naphthalene
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Cymene (p-Isopropyltoluene)
Sec-Butylbenzene
Styrene
tert-Amyl methyl Ether
tert-Butylbenzene
Tetrachloroethylene
Toluene
Total Xylenes
trans-1,2-dichloroethene
trans-1,3-dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Acetate
Vinyl Chloride
Parameter
5.00
9.00
3.35
4.60
150
100
4.60
132
4.90
50.0
8.80
9.50
8.45
4.70
3.00
3.25
6.10
4.45
4.60
3.70
100
17.0
2.70
2.85
6.1
9.40
5.50
6.95
2.70
36.0
4.05
Result
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
50.0
50.0
25.0
25.0
1500
250
25.0
250
25.0
250
50.0
50.0
50.0
25.0
25.0
25.0
50.0
50.0
25.0
25.0
250
125
25.0
25.0
50
50.0
50.0
50.0
25.0
25.0
25.0
Flag
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Units
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
100
50
50
50
50
50
50
DilCas Number
10061-01-5
124-48-1
75-71-8
108-20-3
64-17-5
637-92-3
100-41-4
75-85-4
98-82-8
762-75-4
179601-23-1
75-09-2
1634-04-4
91-20-3
104-51-8
103-65-1
95-47-6
99-87-6
135-98-8
100-42-5
994-05-8
98-06-6
127-18-4
108-88-3
1330-20-7
156-60-5
10061-02-6
79-01-6
75-69-4
108-05-4
75-01-4
5.00 U
9.00 U
3.35 U
4.60 U
150 U
100 U
2060
132 U
649
50.0 U
1480
9.50 U
8.45 U
1030
1190
2180
553
245
558
3.70 U
100 U
17.0 U
2.70 U
51.0
2033
9.40 U
5.50 U
6.95 U
2.70 U
36.0 U
4.05 U
3124713Seq Number:
RL MDL
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
Analysis Date
Surrogate
60-146
60-140
60-140
% Recovery Flag
%
%
%
93
97
96
04.30.2020 15:47
04.30.2020 15:47
04.30.2020 15:47
Cas Number
17060-07-0
460-00-4
2037-26-5
Units Analysis Date
1,2-Dichloroethane-D4
4-Bromofluorobenzene
Toluene-D8
Limits
% Moisture:
Page 7 of 14 Final 1.000
Certificate of Analytical Results 660048
Terraquest Environmental Consultants, P.C., Mebane, NC
Handy Mart #33
04.29.2020 09:21 Date Received:
04.27.2020 13:45 Date Collected:660048-002Lab Sample Id:
Ground WaterMatrix: GW2Sample Id:
VOCs + Oxygenates by GC/MS by SM6200B Analytical Method:
JNLAnalyst:
SM6200B_PREPPrep Method:
04.30.2020 11:44 Date Prep:
JNLTech:
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
3,3-Dimethyl-1-butanol
4-Chlorotoluene
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
Parameter
0.180
0.0760
0.0700
0.113
0.121
0.104
0.0600
0.118
0.138
0.0690
0.103
0.180
0.0940
0.0900
0.122
0.0870
0.0980
0.133
0.0670
0.0970
0.280
0.0880
0.320
2.68
0.0900
0.253
0.352
0.119
0.132
0.112
0.124
0.159
0.0970
0.0998
0.105
0.0420
0.160
0.0850
0.114
Result
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
1.00
0.500
0.500
1.00
1.00
1.00
0.500
1.00
1.00
0.500
1.00
2.50
0.500
0.500
1.00
0.500
0.500
1.00
0.500
0.500
2.00
0.500
2.00
5.00
0.500
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.500
0.500
1.00
0.500
1.00
1.00
1.00
Flag
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Units
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
DilCas Number
630-20-6
71-55-6
79-34-5
79-00-5
75-34-3
75-35-4
563-58-6
87-61-6
96-18-4
120-82-1
95-63-6
106-93-4
95-50-1
107-06-2
78-87-5
108-67-8
541-73-1
142-28-9
106-46-7
594-20-7
78-93-3
95-49-8
591-78-6
624-95-3
106-43-4
108-10-1
67-64-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
156-59-2
0.180 U
0.0760 U
0.0700 U
0.113 U
0.121 U
0.104 U
0.0600 U
0.118 U
0.138 U
0.0690 U
11.7
0.180 U
0.0940 U
0.0900 U
0.122 U
1.41
0.0980 U
0.133 U
0.0670 U
0.0970 U
0.280 U
0.0880 U
0.320 U
2.68 U
0.0900 U
0.253 U
0.352 U
62.6
0.132 U
0.112 U
0.124 U
0.159 U
0.0970 U
0.0998 U
0.105 U
0.0420 U
0.160 U
0.0850 U
0.114 U
3124713Seq Number:
RL MDL
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
Analysis Date
% Moisture:
Page 8 of 14 Final 1.000
Certificate of Analytical Results 660048
Terraquest Environmental Consultants, P.C., Mebane, NC
Handy Mart #33
04.29.2020 09:21 Date Received:
04.27.2020 13:45 Date Collected:660048-002Lab Sample Id:
Ground WaterMatrix: GW2Sample Id:
VOCs + Oxygenates by GC/MS by SM6200B Analytical Method:
JNLAnalyst:
SM6200B_PREPPrep Method:
04.30.2020 11:44 Date Prep:
JNLTech:
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Diisopropyl ether
Ethanol
Ethyl tert butyl Ether
Ethylbenzene
T-Amyl Alcohol
isopropylbenzene
tert-Butyl formate
m,p-Xylenes
Methylene Chloride
Methyl tert-butyl ether (MTBE)
Naphthalene
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Cymene (p-Isopropyltoluene)
Sec-Butylbenzene
Styrene
tert-Amyl methyl Ether
tert-Butylbenzene
Tetrachloroethylene
Toluene
Total Xylenes
trans-1,2-dichloroethene
trans-1,3-dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Acetate
Vinyl Chloride
Parameter
0.100
0.180
0.0670
0.0920
3.00
2.00
0.0920
2.64
0.0980
1.00
0.176
0.190
0.169
0.0940
0.0600
0.0650
0.122
0.0890
0.0920
0.0740
2.00
0.339
0.0540
0.0570
0.122
0.188
0.110
0.139
0.0540
0.720
0.0810
Result
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
1.00
1.00
0.500
0.500
30.0
5.00
0.500
5.00
0.500
5.00
1.00
1.00
1.00
0.500
0.500
0.500
1.00
1.00
0.500
0.500
5.00
2.50
0.500
0.500
1
1.00
1.00
1.00
0.500
0.500
0.500
Flag
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Units
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
DilCas Number
10061-01-5
124-48-1
75-71-8
108-20-3
64-17-5
637-92-3
100-41-4
75-85-4
98-82-8
762-75-4
179601-23-1
75-09-2
1634-04-4
91-20-3
104-51-8
103-65-1
95-47-6
99-87-6
135-98-8
100-42-5
994-05-8
98-06-6
127-18-4
108-88-3
1330-20-7
156-60-5
10061-02-6
79-01-6
75-69-4
108-05-4
75-01-4
0.100 U
0.180 U
0.0670 U
1.15
3.00 U
2.00 U
9.58
43.2
5.83
1.00 U
2.94
0.190 U
0.540
35.0
14.1
21.1
2.40
0.0890 U
4.02
0.0740 U
2.00 U
0.339 U
0.0540 U
1.84
5.34
0.188 U
0.110 U
0.139 U
0.0540 U
0.720 U
0.0810 U
3124713Seq Number:
RL MDL
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
Analysis Date
Surrogate
60-146
60-140
60-140
% Recovery Flag
%
%
%
99
92
92
04.30.2020 17:07
04.30.2020 17:07
04.30.2020 17:07
Cas Number
17060-07-0
460-00-4
2037-26-5
Units Analysis Date
1,2-Dichloroethane-D4
4-Bromofluorobenzene
Toluene-D8
Limits
% Moisture:
Page 9 of 14 Final 1.000
Flagging Criteria
X In our quality control review of the data a QC deficiency was observed and flagged as noted. MS/MSD recoveries were found to be
outside of the laboratory control limits due to possible matrix /chemical interference, or a concentration of target analyte high enough
to affect the recovery of the spike concentration. This condition could also affect the relative percent difference in the MS/MSD.
B A target analyte or common laboratory contaminant was identified in the method blank. Its presence indicates possible field or
laboratory contamination.
D The sample(s) were diluted due to targets detected over the highest point of the calibration curve, or due to matrix interference.
Dilution factors are included in the final results. The result is from a diluted sample.
E The data exceeds the upper calibration limit; therefore, the concentration is reported as estimated.
F RPD exceeded lab control limits.
J The target analyte was positively identified below the quantitation limit and above the detection limit.
U Analyte was not detected.
L The LCS data for this analytical batch was reported below the laboratory control limits for this analyte. The department supervisor and
QA Director reviewed data. The samples were either reanalyzed or flagged as estimated concentrations.
H The LCS data for this analytical batch was reported above the laboratory control limits. Supporting QC Data were reviewed by the
Department Supervisor and QA Director. Data were determined to be valid for reporting.
K Sample analyzed outside of recommended hold time.

JN A combination of the "N" and the "J" qualifier. The analysis indicates that the analyte is "tentatively identified" and the associated
numerical value may not be consistent with the amount actually present in the environmental sample.
** Surrogate recovered outside laboratory control limit.
BRL Below Reporting Limit. ND Not Detected.
RL Reporting Limit
MDL Method Detection Limit SDL Sample Detection Limit LOD Limit of Detection
PQL Practical Quantitation Limit MQL Method Quantitation Limit LOQ Limit of Quantitation
DL Method Detection Limit
NC Non-Calculable
SMP Client Sample BLK Method Blank
BKS/LCS Blank Spike/Laboratory Control Sample BKSD/LCSD Blank Spike Duplicate/Laboratory Control Sample Duplicate
MD/SD Method Duplicate/Sample Duplicate MS Matrix Spike MSD: Matrix Spike Duplicate
+ NELAC certification not offered for this compound.

* (Next to analyte name or method description) = Outside XENCO's scope of NELAC accreditation
Page 10 of 14 Final 1.000
QC Summary 660048
Terraquest Environmental Consultants, P.C.
Handy Mart #33
MS/MSD Percent Recovery [D] = 100*(C-A) / B
Relative Percent Difference RPD = 200* | (C-E) / (C+E) |
LCS/LCSD Recovery [D] = 100 * (C) / [B]
Log Difference Log Diff. = Log(Sample Duplicate) - Log(Original Sample)
LCS = Laboratory Control Sample MS = Matrix Spike
A = Parent Result B = Spike Added
C = MS/LCS Result D = MSD/LCSD % Rec
E = MSD/LCSD Result
7702394-1-BLKMB Sample Id:
WaterMatrix:
VOCs + Oxygenates by GC/MS by SM6200BAnalytical Method:SM6200B_PREPPrep Method:
04.30.2020Date Prep:
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3,5-trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
3,3-Dimethyl-1-butanol
4-Chlorotoluene
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon Tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
Dichlorodifluoromethane
Diisopropyl ether
Ethanol
Ethyl tert butyl Ether
Ethylbenzene
T-Amyl Alcohol
isopropylbenzene
tert-Butyl formate
m,p-Xylenes
Parameter %RPD Flag
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
RPD
Limit
1
8
6
10
5
1
6
16
3
15
2
0
1
9
8
3
3
8
3
1
10
3
4
4
4
2
8
7
0
9
16
3
2
8
0
4
4
9
9
7
3
12
4
11
7
3
11
4
7
7
3124713Seq Number:
Analysis
Date
Limits
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
82-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
LCSD
%Rec
91
106
82
88
110
110
103
92
83
92
101
86
95
90
90
102
102
86
102
129
83
97
76
74
103
77
111
96
95
106
104
87
114
112
99
110
98
107
107
102
93
119
101
96
102
100
73
101
86
107
LCSD
Result
22.7
26.5
20.5
21.9
27.5
27.5
25.8
23.1
20.8
23.1
25.2
21.4
23.7
22.5
22.5
25.5
25.4
21.5
25.4
32.2
41.7
24.3
38.1
184
25.8
38.7
55.4
24.1
23.8
26.4
25.9
21.7
28.5
28.0
24.7
27.6
24.4
26.8
26.7
25.6
23.2
29.7
25.3
962
25.4
24.9
183
25.2
108
53.6
LCS
%Rec
90
98
78
79
105
108
97
108
80
108
102
85
96
82
83
99
98
79
99
128
92
94
73
71
99
76
102
90
95
96
88
84
112
104
98
114
94
98
98
96
90
105
97
87
94
97
82
97
81
100
22.5
24.4
19.4
19.8
26.2
27.1
24.2
27.0
20.1
26.9
25.6
21.3
24.0
20.6
20.8
24.7
24.6
19.8
24.7
31.9
46.0
23.6
36.5
177
24.8
37.8
51.2
22.4
23.8
24.1
22.1
21.0
28.0
25.9
24.6
28.6
23.4
24.5
24.4
23.9
22.6
26.3
24.3
865
23.6
24.2
204
24.2
101
49.9
Spike
Amount
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
50.0
25.0
50.0
250
25.0
50.0
50.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
1000
25.0
25.0
250
25.0
125
50.0
MB
Result
<0.180
<0.0760
<0.0700
<0.113
<0.121
<0.104
<0.0600
<0.118
<0.138
<0.0690
<0.103
<0.180
<0.0940
<0.0900
<0.122
<0.0870
<0.0980
<0.133
<0.0670
<0.0970
<0.280
<0.0880
<0.320
<2.68
<0.0900
<0.253
<0.352
<0.119
<0.132
<0.112
<0.124
<0.159
<0.0970
<0.0998
<0.105
<0.0420
<0.160
<0.0850
<0.114
<0.100
<0.180
<0.0670
<0.0920
<3.00
<2.00
<0.0920
<2.64
<0.0980
<1.00
<0.176
7702394-1-BKSLCS Sample Id:7702394-1-BSDLCSD Sample Id:
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
UnitsLCS
Result
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
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Page 11 of 14 Final 1.000
QC Summary 660048
Terraquest Environmental Consultants, P.C.
Handy Mart #33
MS/MSD Percent Recovery [D] = 100*(C-A) / B
Relative Percent Difference RPD = 200* | (C-E) / (C+E) |
LCS/LCSD Recovery [D] = 100 * (C) / [B]
Log Difference Log Diff. = Log(Sample Duplicate) - Log(Original Sample)
LCS = Laboratory Control Sample MS = Matrix Spike
A = Parent Result B = Spike Added
C = MS/LCS Result D = MSD/LCSD % Rec
E = MSD/LCSD Result
7702394-1-BLKMB Sample Id:
WaterMatrix:
VOCs + Oxygenates by GC/MS by SM6200BAnalytical Method:SM6200B_PREPPrep Method:
04.30.2020Date Prep:
Methylene Chloride
Methyl tert-butyl ether (MTBE)
Naphthalene
n-Butylbenzene
n-Propylbenzene
o-Xylene
p-Cymene (p-Isopropyltoluene)
Sec-Butylbenzene
Styrene
tert-Amyl methyl Ether
tert-Butylbenzene
Tetrachloroethylene
Toluene
trans-1,2-dichloroethene
trans-1,3-dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl Acetate
Vinyl Chloride
Parameter %RPD Flag
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
RPD
Limit
10
3
3
7
1
6
0
1
6
7
0
5
8
4
5
7
3
9
6
3124713Seq Number:
Analysis
Date
Limits
70-130
70-130
70-130
70-130
70-130
70-130
75-125
70-130
70-130
70-130
74-124
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
LCSD
%Rec
88
93
82
102
103
102
104
105
99
87
96
102
96
110
99
104
120
100
117
LCSD
Result
21.9
46.3
20.4
25.5
25.7
25.5
26.1
26.2
24.7
21.7
24.0
25.5
24.0
27.5
24.8
26.0
29.9
25.1
29.3
LCS
%Rec
80
90
84
109
102
96
105
104
93
81
96
97
89
105
94
97
116
92
111
19.9
44.9
21.1
27.3
25.5
24.1
26.2
26.0
23.3
20.3
24.1
24.2
22.2
26.3
23.6
24.2
29.0
22.9
27.7
Spike
Amount
25.0
50.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
MB
Result
<0.190
<0.169
<0.0940
<0.0600
<0.0650
<0.122
<0.0890
<0.0920
<0.0740
<2.00
<0.339
<0.0540
<0.0570
<0.188
<0.110
<0.139
<0.0540
<0.720
<0.0810
7702394-1-BKSLCS Sample Id:7702394-1-BSDLCSD Sample Id:
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
UnitsLCS
Result
1,2-Dichloroethane-D4
4-Bromofluorobenzene
Toluene-D8
Surrogate LCSD
Flag
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
Analysis
Date
Limits
60-146
60-140
60-140
LCSD
%Rec
97
102
92
LCS
%Rec
93
98
84
MB
%Rec
96
109
72
%
%
%
UnitsLCS
Flag
MB
Flag
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
04.30.2020 13:34
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Page 12 of 14 Final 1.000
Page 13 of 14 Final 1.000
Prelogin/Nonconformance Report- Sample Log-In
XENCO Laboratories
660048Work Order #:
04.29.2020 09.21.00 AMDate/ Time Received:
Terraquest Environmental Consultants, PClient:
Sample Receipt Checklist
Checklist completed by: Date:
Checklist reviewed by:
Date:
Chad Bechtold
04.29.2020
04.29.2020
#2 *Shipping container in good condition?
#3 *Samples received on ice?
#4 *Custody Seals intact on shipping container/ cooler?
#5 Custody Seals intact on sample bottles?
#6*Custody Seals Signed and dated?
#7 *Chain of Custody present?
#8 Any missing/extra samples?
#9 Chain of Custody signed when relinquished/ received?
#10 Chain of Custody agrees with sample labels/matrix?
#11 Container label(s) legible and intact?
#12 Samples in proper container/ bottle?
#13 Samples properly preserved?
#14 Sample container(s) intact?
#15 Sufficient sample amount for indicated test(s)?
#16 All samples received within hold time?
#17 Subcontract of sample(s)?
#18 Water VOC samples have zero headspace?
Yes
Yes
N/A
N/A
N/A
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No
Yes

#1 *Temperature of cooler(s)?2.1
Acceptable Temperature Range: 0 - 6 degC
Air and Metal samples Acceptable Range: Ambient
* Must be completed for after-hours delivery of samples prior to placing in the refrigerator
Analyst: PH Device/Lot#:
Comments
Lourdes Arevalo
Temperature Measuring device used : T-111
Page 14 of 14 Final 1.000
Table 2Date: 5/1/206200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200BWell IDDate CollectedBenzeneTolueneEthylbenzeneTotal XylenesMethyl tert‐butyl ether (MTBE)1,2,4‐Trimethylbenzene1,3,5‐trimethylbenzeneT‐Amyl Alcoholn‐ButylbenzeneNaphthaleneDiisopropyl etherSec‐ButylbenzeneIsopropylbenzenen‐Propylbenzenep‐IsopropyltouleneGW1 4/27/20201,530 51 2,060 2,033< 8.452,930 790< 1321,190 1,030< 4.60558649 2,180 245GW2 4/27/202062.6 1.84 9.58 5.34 0.540 11.7 1.41 43.2 14.1 35.0 1.154.025.83 21.1< 0.08901 600 600 500 20 400 4004070 6 70707070255,000 260,000 84,500 85,500 20,000 28,500 25,00040,000 6,900 6,000 70,000 8,500 25,000 30,000 11,700Notes:1. All results in µg/L.2.Bold denotes a detected concentration.3. Shading denotes a 2L Standard exceedence4.Italics denotes a GCL exceedence 5. < ‐ denotes less than sample detection limit.6. NE ‐ Not Established; Analytical Method:GROUNDWATER SAMPLING RESULTS Incident Name: Handy Mart #33 ‐ 101 Ketner Blvd. Havelock, NC   Incident No.: Pending       2L StandardGCL
Table 1
4/30/2020
3550/DRO5030/GRODate Collected Sample Depth PID (ppm)
SB2 4/27/2020 3  ‐ 5 804.1 70 216
SB5 4/27/2020 3  ‐ 5 2,457 200 860
PL1 4/27/2020 3  ‐ 5 22.1 0.5 4.44
D1 4/27/2020 4  ‐ 5 61.5 <10 104
100 50
Notes:
1. All TPH results in mg/kg.  PhotoIonization Readings are listed in parts per million (ppm)
2.Bold denotes a compound detection.
3. Shading denotes a TPH Action Limit violation.
4. "<" = less than sample detection limit
5. Sample depths are in feet below ground level.TPH low fractionBarn 1
TPH Action Limit
SUMMARY OF SOIL SAMPLING RESULTS
 Incident Name: Handy Mart #33 ‐ 101 Ketner Blvd. Havelock, NC   Incident No.: Pending       
Analytical Method  
Sample ID
Contaminant of Concern
TPH high fraction
Table 2Date: 5/1/206200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200B6200BWell IDDate CollectedBenzeneTolueneEthylbenzeneTotal XylenesMethyl tert‐butyl ether (MTBE)1,2,4‐Trimethylbenzene1,3,5‐trimethylbenzeneT‐Amyl Alcoholn‐ButylbenzeneNaphthaleneDiisopropyl etherSec‐ButylbenzeneIsopropylbenzenen‐Propylbenzenep‐IsopropyltouleneGW1 4/27/20201,530 51 2,060 2,033< 8.452,930 790< 1321,190 1,030< 4.60558649 2,180 245GW2 4/27/202062.6 1.84 9.58 5.34 0.540 11.7 1.41 43.2 14.1 35.0 1.154.025.83 21.1< 0.08901 600 600 500 20 400 4004070 6 70707070255,000 260,000 84,500 85,500 20,000 28,500 25,00040,000 6,900 6,000 70,000 8,500 25,000 30,000 11,700Notes:1. All results in µg/L.2.Bold denotes a detected concentration.3. Shading denotes a 2L Standard exceedence4.Italics denotes a GCL exceedence 5. < ‐ denotes less than sample detection limit.6. NE ‐ Not Established; Analytical Method:GROUNDWATER SAMPLING RESULTS Incident Name: Handy Mart #33 ‐ 101 Ketner Blvd. Havelock, NC   Incident No.: Pending       2L StandardGCL

APPENDIX D
Laboratory Analytical Reports – Soil and Ground Water
05/28/20
Technical Report for
GRI (Geological Resources Inc.)
Handy Mart 33; Havelock, NC
5390
SGS Job Number: FA75142
Sampling Date: 05/20/20
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 05/28/20
e-Hardcopy 2.0
Automated Report
53
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 53
FA75142
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA75142-1: MW-1-1 ....................................................................................................7
3.2: FA75142-2: MW-1 ........................................................................................................10
Section 4: Misc. Forms ............................................................................................................15
4.1: Chain of Custody ...........................................................................................................16
Section 5: MS Volatiles - QC Data Summaries .....................................................................18
5.1: Method Blank Summary ................................................................................................19
5.2: Blank Spike Summary ...................................................................................................24
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................29
Section 6: GC Volatiles - QC Data Summaries .....................................................................34
6.1: Method Blank Summary ................................................................................................35
6.2: Blank Spike Summary ...................................................................................................38
6.3: Blank Spike/Blank Spike Duplicate Summary ..............................................................39
6.4: Matrix Spike Summary ..................................................................................................41
6.5: Duplicate Summary .......................................................................................................44
Section 7: Metals Analysis - QC Data Summaries ................................................................47
7.1: Prep QC MP37264: Pb ..................................................................................................48 12345672 of 53
FA75142
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA75142
Handy Mart 33; Havelock, NC
Project No: 5390
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA75142-1 05/20/20 10:00 MEJR 05/21/20 SO Soil MW-1-1
FA75142-2 05/20/20 10:26 MEJR 05/21/20 AQ Ground Water MW-1
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
3 of 53
FA751421
Summary of Hits Page 1 of 2
Job Number:FA75142
Account:GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Collected:05/20/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA75142-1 MW-1-1
Benzene 0.235 J 0.70 0.17 mg/kg SW846 8260D
n-Butylbenzene a 0.0682 0.0048 0.00097 mg/kg SW846 8260D
Cyclohexane a 0.0576 0.0048 0.0012 mg/kg SW846 8260D
Ethylbenzene a 0.111 0.0048 0.00097 mg/kg SW846 8260D
Isopropylbenzene a 0.0535 0.0048 0.00097 mg/kg SW846 8260D
Methylcyclohexane a 0.0642 0.0048 0.0016 mg/kg SW846 8260D
Methyl Tert Butyl Ether a 0.0018 J 0.0048 0.00097 mg/kg SW846 8260D
Naphthalene a 0.0186 0.0048 0.0019 mg/kg SW846 8260D
n-Propylbenzene b 0.206 E 0.0048 0.00097 mg/kg SW846 8260D
Toluene a 0.0542 0.019 0.0097 mg/kg SW846 8260D
1,2,4-Trimethylbenzene 0.339 J 0.70 0.14 mg/kg SW846 8260D
1,3,5-Trimethylbenzene a 0.132 0.0048 0.00097 mg/kg SW846 8260D
Xylene (total) a 0.132 0.015 0.0020 mg/kg SW846 8260D
Benzene 0.275 0.073 0.073 mg/kg MADEP VPH REV 1.1
Ethylbenzene 0.0914 J 0.15 0.073 mg/kg MADEP VPH REV 1.1
o-Xylene 0.0959 J 0.15 0.073 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.)4.45 J 7.3 2.6 mg/kg MADEP VPH REV 1.1
C9- C10 Aromatics 4.45 J 7.3 2.6 mg/kg MADEP VPH REV 1.1
FA75142-2 MW-1
Benzene 489 5.0 1.3 ug/l SM 6200B
n-Butylbenzene 5.2 5.0 1.3 ug/l SM 6200B
sec-Butylbenzene 7.0 5.0 1.3 ug/l SM 6200B
Ethylbenzene 32.5 5.0 1.3 ug/l SM 6200B
Isopropylbenzene 15.1 5.0 1.3 ug/l SM 6200B
p-Isopropyltoluene 1.7 J 5.0 1.3 ug/l SM 6200B
Naphthalene 2.9 J 5.0 1.3 ug/l SM 6200B
n-Propylbenzene 51.7 5.0 1.3 ug/l SM 6200B
Toluene 2.6 J 5.0 1.3 ug/l SM 6200B
1,2,4-Trimethylbenzene 139 5.0 1.3 ug/l SM 6200B
1,3,5-Trimethylbenzene 28.9 5.0 1.3 ug/l SM 6200B
m,p-Xylene 7.8 J 10 1.3 ug/l SM 6200B
o-Xylene 3.8 J 5.0 1.3 ug/l SM 6200B
Xylene (total)11.6 J 15 2.5 ug/l SM 6200B
Benzene 258 2.0 2.0 ug/l MADEP VPH REV 1.1
Ethylbenzene 24.8 4.0 2.0 ug/l MADEP VPH REV 1.1
Methyl Tert Butyl Ether 5.3 4.0 2.0 ug/l MADEP VPH REV 1.1
m,p-Xylene 9.5 8.0 4.0 ug/l MADEP VPH REV 1.1
o-Xylene 4.4 4.0 2.0 ug/l MADEP VPH REV 1.1
C5- C8 Aliphatics (Unadj.)515 200 70 ug/l MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.)348 200 70 ug/l MADEP VPH REV 1.1
C5- C8 Aliphatics 252 200 70 ug/l MADEP VPH REV 1.1
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FA751422
Summary of Hits Page 2 of 2
Job Number:FA75142
Account:GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Collected:05/20/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
C9- C10 Aromatics 348 200 70 ug/l MADEP VPH REV 1.1
(a) Result reported from Bisulfate preserved sample.
(b) Result reported from Bisulfate preserved sample. Compound was below calibration range in methanol extract.
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SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
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FA751423
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-1-1
Lab Sample ID:FA75142-1 Date Sampled:05/20/20
Matrix:SO - Soil Date Received:05/21/20
Method:SW846 8260D Percent Solids:81.1
Project:Handy Mart 33; Havelock, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a 2B14442.D 1 05/27/20 19:35 SP n/a n/a V2B569
Run #2 3C10084.D 1 05/22/20 17:30 SP n/a n/a V3C424
Initial Weight Final Volume Methanol Aliquot
Run #1 6.37 g 5.0 ml
Run #2 5.31 g 5.0 ml 50.0 ul
VOA Special List
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 0.19 0.097 mg/kg
71-43-2 Benzene 0.235 b 0.70 0.17 mg/kg J
75-27-4 Bromodichloromethane ND 0.0048 0.00097 mg/kg
75-25-2 Bromoform ND 0.0048 0.00097 mg/kg
78-93-3 2-Butanone (MEK)ND 0.024 0.0070 mg/kg
104-51-8 n-Butylbenzene 0.0682 0.0048 0.00097 mg/kg
75-15-0 Carbon Disulfide ND 0.0048 0.00097 mg/kg
56-23-5 Carbon Tetrachloride ND 0.0048 0.00099 mg/kg
108-90-7 Chlorobenzene ND 0.0048 0.00097 mg/kg
75-00-3 Chloroethane c ND 0.0048 0.0019 mg/kg
67-66-3 Chloroform ND 0.0048 0.0013 mg/kg
110-82-7 Cyclohexane 0.0576 0.0048 0.0012 mg/kg
124-48-1 Dibromochloromethane ND 0.0048 0.00097 mg/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 0.0048 0.0019 mg/kg
106-93-4 1,2-Dibromoethane ND 0.0048 0.00097 mg/kg
75-71-8 Dichlorodifluoromethane ND 0.0048 0.0019 mg/kg
95-50-1 1,2-Dichlorobenzene ND 0.0048 0.00097 mg/kg
541-73-1 1,3-Dichlorobenzene ND 0.0048 0.00097 mg/kg
106-46-7 1,4-Dichlorobenzene ND 0.0048 0.0011 mg/kg
75-34-3 1,1-Dichloroethane ND 0.0048 0.0017 mg/kg
107-06-2 1,2-Dichloroethane ND 0.0048 0.00097 mg/kg
75-35-4 1,1-Dichloroethylene ND 0.0048 0.00097 mg/kg
156-59-2 cis-1,2-Dichloroethylene ND 0.0048 0.0013 mg/kg
156-60-5 trans-1,2-Dichloroethylene ND 0.0048 0.00097 mg/kg
78-87-5 1,2-Dichloropropane ND 0.0048 0.00097 mg/kg
10061-01-5 cis-1,3-Dichloropropene ND 0.0048 0.00097 mg/kg
10061-02-6 trans-1,3-Dichloropropene ND 0.0048 0.00097 mg/kg
100-41-4 Ethylbenzene 0.111 0.0048 0.00097 mg/kg
591-78-6 2-Hexanone ND 0.024 0.0073 mg/kg
98-82-8 Isopropylbenzene 0.0535 0.0048 0.00097 mg/kg
79-20-9 Methyl Acetate ND 0.024 0.0086 mg/kg
74-83-9 Methyl Bromide ND 0.0048 0.0019 mg/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA7514233.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-1-1
Lab Sample ID:FA75142-1 Date Sampled:05/20/20
Matrix:SO - Soil Date Received:05/21/20
Method:SW846 8260D Percent Solids:81.1
Project:Handy Mart 33; Havelock, NC
VOA Special List
CAS No.Compound Result RL MDL Units Q
74-87-3 Methyl Chloride ND 0.0048 0.0019 mg/kg
108-87-2 Methylcyclohexane 0.0642 0.0048 0.0016 mg/kg
75-09-2 Methylene Chloride ND 0.019 0.011 mg/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 0.024 0.0073 mg/kg
1634-04-4 Methyl Tert Butyl Ether 0.0018 0.0048 0.00097 mg/kg J
91-20-3 Naphthalene 0.0186 0.0048 0.0019 mg/kg
103-65-1 n-Propylbenzene d 0.206 0.0048 0.00097 mg/kg E
100-42-5 Styrene ND 0.0048 0.00097 mg/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 0.0048 0.00097 mg/kg
127-18-4 Tetrachloroethylene ND 0.0048 0.0012 mg/kg
108-88-3 Toluene 0.0542 0.019 0.0097 mg/kg
120-82-1 1,2,4-Trichlorobenzene ND 0.0048 0.00097 mg/kg
71-55-6 1,1,1-Trichloroethane ND 0.0048 0.00097 mg/kg
79-00-5 1,1,2-Trichloroethane ND 0.0048 0.00097 mg/kg
79-01-6 Trichloroethylene ND 0.0048 0.00097 mg/kg
75-69-4 Trichlorofluoromethane ND 0.0048 0.0019 mg/kg
95-63-6 1,2,4-Trimethylbenzene 0.339 b 0.70 0.14 mg/kg J
108-67-8 1,3,5-Trimethylbenzene 0.132 0.0048 0.00097 mg/kg
75-01-4 Vinyl Chloride ND 0.0048 0.00097 mg/kg
1330-20-7 Xylene (total)0.132 0.015 0.0020 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 95%97%75-124%
17060-07-0 1,2-Dichloroethane-D4 103%99%72-135%
2037-26-5 Toluene-D8 105%95%75-126%
460-00-4 4-Bromofluorobenzene 107%91%71-133%
(a) Result reported from Bisulfate preserved sample.
(b) Result is from Run# 2
(c) Associated ICV and BS outside control limits high, however sample ND.
(d) Compound was below calibration range in methanol extract.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA7514233.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1-1
Lab Sample ID:FA75142-1 Date Sampled:05/20/20
Matrix:SO - Soil Date Received:05/21/20
Method:MADEP VPH REV 1.1 Percent Solids:81.1
Project:Handy Mart 33; Havelock, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1S2599.D 1 05/22/20 20:51 EG n/a n/a G1S36
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 4.99 g 5.0 ml 100 ul
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 0.275 0.073 0.073 mg/kg
100-41-4 Ethylbenzene 0.0914 0.15 0.073 mg/kg J
1634-04-4 Methyl Tert Butyl Ether ND 0.15 0.073 mg/kg
91-20-3 Naphthalene ND 0.37 0.22 mg/kg
108-88-3 Toluene ND 0.15 0.073 mg/kg
m,p-Xylene ND 0.29 0.15 mg/kg
95-47-6 o-Xylene 0.0959 0.15 0.073 mg/kg J
C5- C8 Aliphatics (Unadj.)ND 7.3 2.6 mg/kg
C9- C12 Aliphatics (Unadj.)ND 7.3 2.6 mg/kg
C9- C10 Aromatics (Unadj.)4.45 7.3 2.6 mg/kg J
C5- C8 Aliphatics ND 7.3 2.6 mg/kg
C9- C12 Aliphatics ND 7.3 2.6 mg/kg
C9- C10 Aromatics 4.45 7.3 2.6 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 150% a 70-130%
460-00-4 BFB 148% a 70-130%
(a) Outside control limits due to moisture content.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA7514233.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-1
Lab Sample ID:FA75142-2 Date Sampled:05/20/20
Matrix:AQ - Ground Water Date Received:05/21/20
Method:SM 6200B Percent Solids:n/a
Project:Handy Mart 33; Havelock, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0222453.D 10 05/22/20 14:28 AB n/a n/a VA2741
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 489 5.0 1.3 ug/l
108-86-1 Bromobenzene ND 5.0 1.3 ug/l
74-97-5 Bromochloromethane ND 5.0 1.3 ug/l
75-27-4 Bromodichloromethane ND 5.0 1.3 ug/l
75-25-2 Bromoform ND 5.0 1.3 ug/l
104-51-8 n-Butylbenzene 5.2 5.0 1.3 ug/l
135-98-8 sec-Butylbenzene 7.0 5.0 1.3 ug/l
98-06-6 tert-Butylbenzene ND 5.0 1.3 ug/l
56-23-5 Carbon Tetrachloride ND 5.0 1.3 ug/l
108-90-7 Chlorobenzene ND 5.0 1.3 ug/l
75-00-3 Chloroethane ND 5.0 2.0 ug/l
67-66-3 Chloroform ND 5.0 1.3 ug/l
95-49-8 o-Chlorotoluene ND 5.0 1.3 ug/l
106-43-4 p-Chlorotoluene ND 5.0 1.3 ug/l
124-48-1 Dibromochloromethane ND 5.0 1.3 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 2.5 ug/l
106-93-4 1,2-Dibromoethane ND 5.0 1.3 ug/l
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 5.0 1.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 5.0 1.3 ug/l
106-46-7 1,4-Dichlorobenzene ND 5.0 1.3 ug/l
75-34-3 1,1-Dichloroethane ND 5.0 1.3 ug/l
107-06-2 1,2-Dichloroethane ND 5.0 1.3 ug/l
75-35-4 1,1-Dichloroethylene ND 5.0 1.3 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.3 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.3 ug/l
78-87-5 1,2-Dichloropropane ND 5.0 1.3 ug/l
142-28-9 1,3-Dichloropropane ND 5.0 1.3 ug/l
594-20-7 2,2-Dichloropropane ND 5.0 1.3 ug/l
563-58-6 1,1-Dichloropropene ND 5.0 1.3 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA7514233.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-1
Lab Sample ID:FA75142-2 Date Sampled:05/20/20
Matrix:AQ - Ground Water Date Received:05/21/20
Method:SM 6200B Percent Solids:n/a
Project:Handy Mart 33; Havelock, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 5.0 1.3 ug/l
100-41-4 Ethylbenzene 32.5 5.0 1.3 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 1.3 ug/l
98-82-8 Isopropylbenzene 15.1 5.0 1.3 ug/l
99-87-6 p-Isopropyltoluene 1.7 5.0 1.3 ug/l J
74-83-9 Methyl Bromide ND 5.0 2.0 ug/l
74-87-3 Methyl Chloride ND 5.0 2.0 ug/l
74-95-3 Methylene Bromide ND 5.0 1.3 ug/l
75-09-2 Methylene Chloride ND 20 10 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.3 ug/l
91-20-3 Naphthalene 2.9 5.0 1.3 ug/l J
103-65-1 n-Propylbenzene 51.7 5.0 1.3 ug/l
100-42-5 Styrene ND 5.0 1.3 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.3 ug/l
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/l
108-88-3 Toluene 2.6 5.0 1.3 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.3 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.3 ug/l
71-55-6 1,1,1-Trichloroethane ND 5.0 1.3 ug/l
79-00-5 1,1,2-Trichloroethane ND 5.0 1.3 ug/l
79-01-6 Trichloroethylene ND 5.0 1.3 ug/l
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/l
95-63-6 1,2,4-Trimethylbenzene 139 5.0 1.3 ug/l
108-67-8 1,3,5-Trimethylbenzene 28.9 5.0 1.3 ug/l
75-01-4 Vinyl Chloride ND 5.0 1.3 ug/l
m,p-Xylene 7.8 10 1.3 ug/l J
95-47-6 o-Xylene 3.8 5.0 1.3 ug/l J
1330-20-7 Xylene (total)11.6 15 2.5 ug/l J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 110%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA7514233.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FA75142-2 Date Sampled:05/20/20
Matrix:AQ - Ground Water Date Received:05/21/20
Method:EPA 504.1 EPA 504.1 Percent Solids:n/a
Project:Handy Mart 33; Havelock, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 DD1120547.D 1 05/22/20 17:05 CV 05/22/20 14:00 OP80320 GDD3229
Run #2
Initial Volume Final Volume
Run #1 37.6 ml 2.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.019 0.0093 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 101%63-137%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 53
FA7514233.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FA75142-2 Date Sampled:05/20/20
Matrix:AQ - Ground Water Date Received:05/21/20
Method:MADEP VPH REV 1.1 Percent Solids:n/a
Project:Handy Mart 33; Havelock, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1S2584.D 2 05/21/20 16:57 SH n/a n/a G1S35
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 258 2.0 2.0 ug/l
100-41-4 Ethylbenzene 24.8 4.0 2.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 5.3 4.0 2.0 ug/l
91-20-3 Naphthalene ND 10 6.0 ug/l
108-88-3 Toluene ND 4.0 2.0 ug/l
m,p-Xylene 9.5 8.0 4.0 ug/l
95-47-6 o-Xylene 4.4 4.0 2.0 ug/l
C5- C8 Aliphatics (Unadj.)515 200 70 ug/l
C9- C12 Aliphatics (Unadj.)ND 200 70 ug/l
C9- C10 Aromatics (Unadj.)348 200 70 ug/l
C5- C8 Aliphatics 252 200 70 ug/l
C9- C12 Aliphatics ND 200 70 ug/l
C9- C10 Aromatics 348 200 70 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 101%70-130%
460-00-4 BFB 99%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 53
FA7514233.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-1
Lab Sample ID:FA75142-2 Date Sampled:05/20/20
Matrix:AQ - Ground Water Date Received:05/21/20
Percent Solids:n/a
Project:Handy Mart 33; Havelock, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead <5.0 5.0 ug/l 1 05/22/20 05/26/20 LM SW846 6010D 1 SW846 3010A 2
(1) Instrument QC Batch: MA16771
(2) Prep QC Batch: MP37264
RL = Reporting Limit
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FA7514233.2
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
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FA751424
FA75142: Chain of Custody
Page 1 of 2
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FA7514244.1
Job Number:FA75142 Client:GEOLOGICAL RESOURCES
Date / Time Received:5/21/2020 9:00:00 AM Delivery Method:FX
Project:HANDY MART 33
Airbill #'s:1009 6378 0476
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (5.2);
Cooler 1: (4.4);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:1Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.8; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:PETERH Date:Date:5/21/2020 9:00:00 AM
FA75142: Chain of Custody
Page 2 of 2
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FA7514244.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
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FA751425
Method Blank Summary Page 1 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2741-MB A0222441.D 1 05/22/20 AB n/a n/a VA2741
The QC reported here applies to the following samples:Method: SM 6200B
FA75142-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
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FA7514255.1.1
Method Blank Summary Page 2 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2741-MB A0222441.D 1 05/22/20 AB n/a n/a VA2741
The QC reported here applies to the following samples:Method: SM 6200B
FA75142-2
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 104%70-130%
17060-07-0 1,2-Dichloroethane-D4 113%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
20 of 53
FA7514255.1.1
Method Blank Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C424-MB 3C10083.D 1 05/22/20 SP n/a n/a V3C424
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 5.0 1.2 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%75-124%
17060-07-0 1,2-Dichloroethane-D4 101%72-135%
2037-26-5 Toluene-D8 95%75-126%
460-00-4 4-Bromofluorobenzene 93%71-133%
21 of 53
FA7514255.1.2
Method Blank Summary Page 1 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B569-MB 2B14441.D 1 05/27/20 SP n/a n/a V2B569
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 200 100 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
75-15-0 Carbon Disulfide ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
110-82-7 Cyclohexane ND 5.0 1.3 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 1.9 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
79-20-9 Methyl Acetate 10.9 25 8.9 ug/kg J
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
108-87-2 Methylcyclohexane ND 5.0 1.7 ug/kg
75-09-2 Methylene Chloride ND 20 11 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
22 of 53
FA7514255.1.3
Method Blank Summary Page 2 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B569-MB 2B14441.D 1 05/27/20 SP n/a n/a V2B569
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
CAS No.Compound Result RL MDL Units Q
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/kg
108-88-3 Toluene ND 20 10 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 95%75-124%
17060-07-0 1,2-Dichloroethane-D4 100%72-135%
2037-26-5 Toluene-D8 100%75-126%
460-00-4 4-Bromofluorobenzene 97%71-133%
23 of 53
FA7514255.1.3
Blank Spike Summary Page 1 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2741-BS A0222439.D 1 05/22/20 AB n/a n/a VA2741
The QC reported here applies to the following samples:Method: SM 6200B
FA75142-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.3 103 70-130
108-86-1 Bromobenzene 10 9.0 90 70-130
74-97-5 Bromochloromethane 10 9.7 97 70-130
75-27-4 Bromodichloromethane 10 9.2 92 70-130
75-25-2 Bromoform 10 7.0 70 70-130
104-51-8 n-Butylbenzene 10 9.8 98 70-130
135-98-8 sec-Butylbenzene 10 9.9 99 70-130
98-06-6 tert-Butylbenzene 10 9.4 94 70-130
56-23-5 Carbon Tetrachloride 10 10.9 109 70-130
108-90-7 Chlorobenzene 10 9.3 93 70-130
75-00-3 Chloroethane 10 10.1 101 60-140
67-66-3 Chloroform 10 9.7 97 70-130
95-49-8 o-Chlorotoluene 10 9.5 95 70-130
106-43-4 p-Chlorotoluene 10 9.2 92 70-130
124-48-1 Dibromochloromethane 10 8.1 81 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 7.7 77 70-130
106-93-4 1,2-Dibromoethane 10 8.4 84 70-130
75-71-8 Dichlorodifluoromethane 10 7.1 71 60-140
95-50-1 1,2-Dichlorobenzene 10 8.7 87 70-130
541-73-1 1,3-Dichlorobenzene 10 9.0 90 70-130
106-46-7 1,4-Dichlorobenzene 10 9.1 91 70-130
75-34-3 1,1-Dichloroethane 10 10.5 105 70-130
107-06-2 1,2-Dichloroethane 10 10.1 101 70-130
75-35-4 1,1-Dichloroethylene 10 11.7 117 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.4 94 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.4 104 70-130
78-87-5 1,2-Dichloropropane 10 9.7 97 70-130
142-28-9 1,3-Dichloropropane 10 8.6 86 70-130
594-20-7 2,2-Dichloropropane 10 10.4 104 70-130
563-58-6 1,1-Dichloropropene 10 10.8 108 70-130
10061-01-5 cis-1,3-Dichloropropene 10 8.9 89 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.0 90 70-130
108-20-3 Di-Isopropyl Ether 10 10.4 104 70-130
100-41-4 Ethylbenzene 10 9.3 93 70-130
87-68-3 Hexachlorobutadiene 10 9.0 90 70-130
98-82-8 Isopropylbenzene 10 9.0 90 70-130
* = Outside of Control Limits.
24 of 53
FA7514255.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2741-BS A0222439.D 1 05/22/20 AB n/a n/a VA2741
The QC reported here applies to the following samples:Method: SM 6200B
FA75142-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.4 94 70-130
74-83-9 Methyl Bromide 10 9.2 92 60-140
74-87-3 Methyl Chloride 10 9.5 95 60-140
74-95-3 Methylene Bromide 10 8.9 89 70-130
75-09-2 Methylene Chloride 10 10.7 107 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.5 105 70-130
91-20-3 Naphthalene 10 7.6 76 70-130
103-65-1 n-Propylbenzene 10 9.5 95 70-130
100-42-5 Styrene 10 8.4 84 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.1 91 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.4 94 70-130
127-18-4 Tetrachloroethylene 10 9.3 93 70-130
108-88-3 Toluene 10 9.3 93 70-130
87-61-6 1,2,3-Trichlorobenzene 10 8.0 80 70-130
120-82-1 1,2,4-Trichlorobenzene 10 7.9 79 70-130
71-55-6 1,1,1-Trichloroethane 10 10.2 102 70-130
79-00-5 1,1,2-Trichloroethane 10 9.1 91 70-130
79-01-6 Trichloroethylene 10 10.1 101 70-130
75-69-4 Trichlorofluoromethane 10 10.5 105 60-140
96-18-4 1,2,3-Trichloropropane 10 8.9 89 70-130
95-63-6 1,2,4-Trimethylbenzene 10 8.5 85 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.2 92 70-130
75-01-4 Vinyl Chloride 10 9.0 90 60-140
m,p-Xylene 20 17.9 90 70-130
95-47-6 o-Xylene 10 8.4 84 70-130
1330-20-7 Xylene (total)30 26.3 88 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 112%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
* = Outside of Control Limits.
25 of 53
FA7514255.2.1
Blank Spike Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C424-BS 3C10082.D 1 05/22/20 SP n/a n/a V3C424
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
71-43-2 Benzene 50 49.4 99 76-126
95-63-6 1,2,4-Trimethylbenzene 50 49.8 100 74-123
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%75-124%
17060-07-0 1,2-Dichloroethane-D4 96%72-135%
2037-26-5 Toluene-D8 99%75-126%
460-00-4 4-Bromofluorobenzene 97%71-133%
* = Outside of Control Limits.
26 of 53
FA7514255.2.2
Blank Spike Summary Page 1 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B569-BS 2B14440.D 1 05/27/20 SP n/a n/a V2B569
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 224 90 61-152
75-27-4 Bromodichloromethane 50 54.4 109 74-130
75-25-2 Bromoform 50 48.9 98 76-127
78-93-3 2-Butanone (MEK)250 232 93 75-137
104-51-8 n-Butylbenzene 50 57.8 116 71-128
75-15-0 Carbon Disulfide 50 53.2 106 72-122
56-23-5 Carbon Tetrachloride 50 53.1 106 78-133
108-90-7 Chlorobenzene 50 51.5 103 81-129
75-00-3 Chloroethane 50 74.5 149*68-133
67-66-3 Chloroform 50 51.1 102 72-123
110-82-7 Cyclohexane 50 53.9 108 73-126
124-48-1 Dibromochloromethane 50 50.1 100 76-127
96-12-8 1,2-Dibromo-3-chloropropane 50 48.9 98 70-137
106-93-4 1,2-Dibromoethane 50 50.9 102 77-126
75-71-8 Dichlorodifluoromethane 50 40.5 81 68-168
95-50-1 1,2-Dichlorobenzene 50 50.9 102 80-129
541-73-1 1,3-Dichlorobenzene 50 51.9 104 81-129
106-46-7 1,4-Dichlorobenzene 50 51.0 102 76-130
75-34-3 1,1-Dichloroethane 50 51.4 103 73-125
107-06-2 1,2-Dichloroethane 50 50.7 101 74-128
75-35-4 1,1-Dichloroethylene 50 50.9 102 81-136
156-59-2 cis-1,2-Dichloroethylene 50 52.2 104 74-126
156-60-5 trans-1,2-Dichloroethylene 50 51.2 102 70-127
78-87-5 1,2-Dichloropropane 50 52.3 105 74-125
10061-01-5 cis-1,3-Dichloropropene 50 53.3 107 80-123
10061-02-6 trans-1,3-Dichloropropene 50 52.4 105 75-131
100-41-4 Ethylbenzene 50 53.0 106 77-123
591-78-6 2-Hexanone 250 241 96 72-133
98-82-8 Isopropylbenzene 50 55.1 110 80-136
79-20-9 Methyl Acetate 250 235 94 67-137
74-83-9 Methyl Bromide 50 50.9 102 65-139
74-87-3 Methyl Chloride 50 45.5 91 71-144
108-87-2 Methylcyclohexane 50 56.5 113 75-128
75-09-2 Methylene Chloride 50 50.6 101 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 245 98 76-132
1634-04-4 Methyl Tert Butyl Ether 50 53.5 107 77-120
* = Outside of Control Limits.
27 of 53
FA7514255.2.3
Blank Spike Summary Page 2 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B569-BS 2B14440.D 1 05/27/20 SP n/a n/a V2B569
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
91-20-3 Naphthalene 50 55.2 110 79-129
103-65-1 n-Propylbenzene 50 52.4 105 80-135
100-42-5 Styrene 50 53.1 106 78-125
79-34-5 1,1,2,2-Tetrachloroethane 50 51.4 103 71-126
127-18-4 Tetrachloroethylene 50 52.9 106 79-130
108-88-3 Toluene 50 50.9 102 76-124
120-82-1 1,2,4-Trichlorobenzene 50 57.0 114 78-130
71-55-6 1,1,1-Trichloroethane 50 50.2 100 70-129
79-00-5 1,1,2-Trichloroethane 50 50.1 100 74-124
79-01-6 Trichloroethylene 50 52.9 106 75-128
75-69-4 Trichlorofluoromethane 50 55.7 111 73-145
108-67-8 1,3,5-Trimethylbenzene 50 54.2 108 73-122
75-01-4 Vinyl Chloride 50 48.3 97 76-141
1330-20-7 Xylene (total)150 161 107 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 102%75-124%
17060-07-0 1,2-Dichloroethane-D4 99%72-135%
2037-26-5 Toluene-D8 99%75-126%
460-00-4 4-Bromofluorobenzene 95%71-133%
* = Outside of Control Limits.
28 of 53
FA7514255.2.3
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA75153-3MS A0222455.D 5 05/22/20 AB n/a n/a VA2741
FA75153-3MSD A0222456.D 5 05/22/20 AB n/a n/a VA2741
FA75153-3 A0222443.D 1 05/22/20 AB n/a n/a VA2741
The QC reported here applies to the following samples:Method: SM 6200B
FA75142-2
FA75153-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene ND 50 54.1 108 50 56.8 114 5 70-130/20
108-86-1 Bromobenzene ND 50 45.8 92 50 48.8 98 6 70-130/20
74-97-5 Bromochloromethane ND 50 50.2 100 50 53.3 107 6 70-130/20
75-27-4 Bromodichloromethane ND 50 44.8 90 50 47.4 95 6 70-130/20
75-25-2 Bromoform ND 50 29.6 59*50 31.7 63*7 70-130/20
104-51-8 n-Butylbenzene ND 50 48.3 97 50 52.2 104 8 70-130/20
135-98-8 sec-Butylbenzene ND 50 49.8 100 50 53.1 106 6 70-130/20
98-06-6 tert-Butylbenzene ND 50 46.9 94 50 50.4 101 7 70-130/20
56-23-5 Carbon Tetrachloride ND 50 53.3 107 50 55.2 110 4 70-130/20
108-90-7 Chlorobenzene ND 50 47.1 94 50 49.8 100 6 70-130/20
75-00-3 Chloroethane ND 50 53.2 106 50 62.6 125 16 60-140/20
67-66-3 Chloroform ND 50 50.6 101 50 52.7 105 4 70-130/20
95-49-8 o-Chlorotoluene ND 50 49.0 98 50 51.7 103 5 70-130/20
106-43-4 p-Chlorotoluene ND 50 46.0 92 50 49.3 99 7 70-130/20
124-48-1 Dibromochloromethane ND 50 36.6 73 50 38.5 77 5 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 50 38.5 77 50 41.6 83 8 70-130/20
106-93-4 1,2-Dibromoethane ND 50 42.1 84 50 44.8 90 6 70-130/20
75-71-8 Dichlorodifluoromethane ND 50 36.5 73 50 43.3 87 17 60-140/20
95-50-1 1,2-Dichlorobenzene ND 50 44.1 88 50 46.9 94 6 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 45.7 91 50 48.3 97 6 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 46.5 93 50 49.1 98 5 70-130/20
75-34-3 1,1-Dichloroethane ND 50 54.1 108 50 57.2 114 6 70-130/20
107-06-2 1,2-Dichloroethane ND 50 52.0 104 50 54.8 110 5 70-130/20
75-35-4 1,1-Dichloroethylene ND 50 60.1 120 50 63.1 126 5 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 50 48.2 96 50 50.6 101 5 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 50 54.7 109 50 57.2 114 4 70-130/20
78-87-5 1,2-Dichloropropane ND 50 50.4 101 50 53.0 106 5 70-130/20
142-28-9 1,3-Dichloropropane ND 50 43.3 87 50 46.2 92 6 70-130/20
594-20-7 2,2-Dichloropropane ND 50 49.7 99 50 51.0 102 3 70-130/20
563-58-6 1,1-Dichloropropene ND 50 55.9 112 50 59.4 119 6 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 50 37.4 75 50 40.1 80 7 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 50 42.0 84 50 44.2 88 5 70-130/20
108-20-3 Di-Isopropyl Ether ND 50 52.6 105 50 55.8 112 6 70-130/20
100-41-4 Ethylbenzene ND 50 47.6 95 50 50.4 101 6 70-130/20
87-68-3 Hexachlorobutadiene ND 50 42.3 85 50 46.2 92 9 70-130/20
98-82-8 Isopropylbenzene ND 50 45.0 90 50 47.9 96 6 70-130/20
* = Outside of Control Limits.
29 of 53
FA7514255.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA75153-3MS A0222455.D 5 05/22/20 AB n/a n/a VA2741
FA75153-3MSD A0222456.D 5 05/22/20 AB n/a n/a VA2741
FA75153-3 A0222443.D 1 05/22/20 AB n/a n/a VA2741
The QC reported here applies to the following samples:Method: SM 6200B
FA75142-2
FA75153-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 50 46.5 93 50 49.9 100 7 70-130/20
74-83-9 Methyl Bromide ND 50 51.9 104 50 59.2 118 13 60-140/20
74-87-3 Methyl Chloride 0.21 J 50 46.4 92 50 52.8 105 13 60-140/20
74-95-3 Methylene Bromide ND 50 45.8 92 50 48.5 97 6 70-130/20
75-09-2 Methylene Chloride ND 50 56.8 114 50 60.1 120 6 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 50 52.0 104 50 55.2 110 6 70-130/20
91-20-3 Naphthalene ND 50 34.9 70 50 38.9 78 11 70-130/20
103-65-1 n-Propylbenzene ND 50 48.1 96 50 51.7 103 7 70-130/20
100-42-5 Styrene ND 50 41.5 83 50 44.3 89 7 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 50 46.0 92 50 48.4 97 5 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 50 49.4 99 50 52.0 104 5 70-130/20
127-18-4 Tetrachloroethylene ND 50 47.4 95 50 50.0 100 5 70-130/20
108-88-3 Toluene ND 50 48.0 96 50 50.6 101 5 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 50 38.3 77 50 41.8 84 9 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 50 37.4 75 50 40.9 82 9 70-130/20
71-55-6 1,1,1-Trichloroethane ND 50 52.9 106 50 55.6 111 5 70-130/20
79-00-5 1,1,2-Trichloroethane ND 50 46.1 92 50 50.1 100 8 70-130/20
79-01-6 Trichloroethylene ND 50 51.8 104 50 53.9 108 4 70-130/20
75-69-4 Trichlorofluoromethane ND 50 55.8 112 50 65.8 132 16 60-140/20
96-18-4 1,2,3-Trichloropropane ND 50 44.5 89 50 46.2 92 4 70-130/20
95-63-6 1,2,4-Trimethylbenzene ND 50 43.3 87 50 46.1 92 6 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 50 46.5 93 50 49.2 98 6 70-130/20
75-01-4 Vinyl Chloride ND 50 46.6 93 50 55.7 111 18 60-140/20
m,p-Xylene ND 100 92.0 92 100 97.4 97 6 70-130/20
95-47-6 o-Xylene ND 50 42.4 85 50 45.1 90 6 70-130/20
1330-20-7 Xylene (total)ND 150 134 89 150 143 95 6 70-130/20
CAS No.Surrogate Recoveries MS MSD FA75153-3 Limits
1868-53-7 Dibromofluoromethane 103%103%106%70-130%
17060-07-0 1,2-Dichloroethane-D4 112%109%114%70-130%
2037-26-5 Toluene-D8 97%97%99%70-130%
460-00-4 4-Bromofluorobenzene 95%95%99%70-130%
* = Outside of Control Limits.
30 of 53
FA7514255.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA75182-3MS 3C10091.D 1 05/22/20 SP n/a n/a V3C424
FA75182-3MSD 3C10092.D 1 05/22/20 SP n/a n/a V3C424
FA75182-3 3C10087.D 1 05/22/20 SP n/a n/a V3C424
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
FA75182-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
71-43-2 Benzene 3700 U 37200 37100 100 37200 37400 100 1 76-126/26
95-63-6 1,2,4-Trimethylbenzene 233000 E 37200 259000 70* a 37200 254000 56* a 2 74-123/34
CAS No.Surrogate Recoveries MS MSD FA75182-3 Limits
1868-53-7 Dibromofluoromethane 96%96%92%75-124%
17060-07-0 1,2-Dichloroethane-D4 93%94%97%72-135%
2037-26-5 Toluene-D8 109%109%105%75-126%
460-00-4 4-Bromofluorobenzene 105%104%107%71-133%
(a) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
31 of 53
FA7514255.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA75237-1MS a 2B14450.D 1 05/27/20 SP n/a n/a V2B569
FA75237-1MSD a 2B14451.D 1 05/27/20 SP n/a n/a V2B569
FA75237-1 a 2B14443.D 1 05/27/20 SP n/a n/a V2B569
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
FA75237-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone ND 401 336 84 401 301 75 11 61-152/27
75-27-4 Bromodichloromethane ND 80.3 86.4 108 80.3 81.0 101 6 74-130/25
75-25-2 Bromoform ND 80.3 73.3 91 80.3 68.0 85 8 76-127/26
78-93-3 2-Butanone (MEK)ND 401 311 77 401 287 72*8 75-137/25
104-51-8 n-Butylbenzene ND 80.3 85.8 107 80.3 80.3 100 7 71-128/35
75-15-0 Carbon Disulfide ND 80.3 84.5 105 80.3 75.1 94 12 72-122/29
56-23-5 Carbon Tetrachloride ND 80.3 86.4 108 80.3 77.1 96 11 78-133/29
108-90-7 Chlorobenzene ND 80.3 83.3 104 80.3 77.4 96 7 81-129/29
75-00-3 Chloroethane ND 80.3 130 162*80.3 117 146*11 68-133/29
67-66-3 Chloroform ND 80.3 83.5 104 80.3 75.8 94 10 72-123/26
110-82-7 Cyclohexane ND 80.3 90.7 113 80.3 78.7 98 14 73-126/32
124-48-1 Dibromochloromethane ND 80.3 78.1 97 80.3 75.2 94 4 76-127/27
96-12-8 1,2-Dibromo-3-chloropropane ND 80.3 65.8 82 80.3 61.7 77 6 70-137/29
106-93-4 1,2-Dibromoethane ND 80.3 77.0 96 80.3 73.8 92 4 77-126/26
75-71-8 Dichlorodifluoromethane ND 80.3 61.9 77 80.3 50.9 63*20 68-168/29
95-50-1 1,2-Dichlorobenzene ND 80.3 77.0 96 80.3 73.0 91 5 80-129/32
541-73-1 1,3-Dichlorobenzene ND 80.3 77.5 97 80.3 73.9 92 5 81-129/33
106-46-7 1,4-Dichlorobenzene ND 80.3 76.3 95 80.3 72.8 91 5 76-130/32
75-34-3 1,1-Dichloroethane ND 80.3 84.0 105 80.3 76.1 95 10 73-125/27
107-06-2 1,2-Dichloroethane ND 80.3 80.2 100 80.3 75.4 94 6 74-128/23
75-35-4 1,1-Dichloroethylene ND 80.3 83.9 105 80.3 74.3 93 12 81-136/28
156-59-2 cis-1,2-Dichloroethylene ND 80.3 83.4 104 80.3 75.4 94 10 74-126/26
156-60-5 trans-1,2-Dichloroethylene ND 80.3 83.9 105 80.3 75.0 93 11 70-127/27
78-87-5 1,2-Dichloropropane ND 80.3 84.3 105 80.3 79.1 99 6 74-125/25
10061-01-5 cis-1,3-Dichloropropene ND 80.3 81.7 102 80.3 77.7 97 5 80-123/26
10061-02-6 trans-1,3-Dichloropropene ND 80.3 79.3 99 80.3 75.2 94 5 75-131/28
100-41-4 Ethylbenzene ND 80.3 87.4 109 80.3 80.3 100 8 77-123/31
591-78-6 2-Hexanone ND 401 339 84 401 312 78 8 72-133/26
98-82-8 Isopropylbenzene ND 80.3 91.4 114 80.3 81.8 102 11 80-136/32
79-20-9 Methyl Acetate ND 401 201 50*401 175 44*14 67-137/30
74-83-9 Methyl Bromide ND 80.3 82.8 103 80.3 73.4 91 12 65-139/31
74-87-3 Methyl Chloride ND 80.3 70.3 88 80.3 62.7 78 11 71-144/27
108-87-2 Methylcyclohexane ND 80.3 95.4 119 80.3 83.0 103 14 75-128/31
75-09-2 Methylene Chloride ND 80.3 109 136 80.3 101 126 8 74-137/28
108-10-1 4-Methyl-2-pentanone (MIBK)ND 401 355 88 401 329 82 8 76-132/26
1634-04-4 Methyl Tert Butyl Ether ND 80.3 79.1 99 80.3 69.1 86 13 77-120/24
* = Outside of Control Limits.
32 of 53
FA7514255.3.3
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA75237-1MS a 2B14450.D 1 05/27/20 SP n/a n/a V2B569
FA75237-1MSD a 2B14451.D 1 05/27/20 SP n/a n/a V2B569
FA75237-1 a 2B14443.D 1 05/27/20 SP n/a n/a V2B569
The QC reported here applies to the following samples:Method: SW846 8260D
FA75142-1
FA75237-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
91-20-3 Naphthalene ND 80.3 53.6 67*80.3 50.3 63*6 79-129/33
103-65-1 n-Propylbenzene ND 80.3 82.6 103 80.3 76.7 96 7 80-135/33
100-42-5 Styrene ND 80.3 45.1 56*80.3 37.8 47*18 78-125/30
79-34-5 1,1,2,2-Tetrachloroethane ND 80.3 75.5 94 80.3 71.7 89 5 71-126/30
127-18-4 Tetrachloroethylene ND 80.3 87.8 109 80.3 80.3 100 9 79-130/31
108-88-3 Toluene ND 80.3 83.7 104 80.3 77.0 96 8 76-124/30
120-82-1 1,2,4-Trichlorobenzene ND 80.3 72.3 90 80.3 72.5 90 0 78-130/34
71-55-6 1,1,1-Trichloroethane ND 80.3 83.2 104 80.3 73.8 92 12 70-129/27
79-00-5 1,1,2-Trichloroethane ND 80.3 78.5 98 80.3 76.2 95 3 74-124/28
79-01-6 Trichloroethylene ND 80.3 87.5 109 80.3 80.0 100 9 75-128/27
75-69-4 Trichlorofluoromethane ND 80.3 96.1 120 80.3 83.8 104 14 73-145/31
108-67-8 1,3,5-Trimethylbenzene ND 80.3 84.6 105 80.3 78.1 97 8 73-122/33
75-01-4 Vinyl Chloride ND 80.3 76.3 95 80.3 67.5 84 12 76-141/27
1330-20-7 Xylene (total)ND 241 262 109 241 240 100 9 80-129/30
CAS No.Surrogate Recoveries MS MSD FA75237-1 Limits
1868-53-7 Dibromofluoromethane 101%100%99%75-124%
17060-07-0 1,2-Dichloroethane-D4 97%95%101%72-135%
2037-26-5 Toluene-D8 101%100%101%75-126%
460-00-4 4-Bromofluorobenzene 93%94%94%71-133%
(a) Result reported from Bisulfate preserved sample.
* = Outside of Control Limits.
33 of 53
FA7514255.3.3
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
34 of 53
FA751426
Method Blank Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S35-MB 1S2576.D 1 05/21/20 SH n/a n/a G1S35
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 102%70-130%
460-00-4 BFB 102%70-130%
35 of 53
FA7514266.1.1
Method Blank Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S36-MB 1S2593.D 1 05/22/20 EG n/a n/a G1S36
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 50 50 ug/kg
100-41-4 Ethylbenzene ND 100 50 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 100 50 ug/kg
91-20-3 Naphthalene ND 250 150 ug/kg
108-88-3 Toluene ND 100 50 ug/kg
m,p-Xylene ND 200 100 ug/kg
95-47-6 o-Xylene ND 100 50 ug/kg
C5- C8 Aliphatics (Unadj.)ND 5000 1800 ug/kg
C9- C12 Aliphatics (Unadj.)ND 5000 1800 ug/kg
C9- C10 Aromatics (Unadj.)ND 5000 1800 ug/kg
C5- C8 Aliphatics ND 5000 1800 ug/kg
C9- C12 Aliphatics ND 5000 1800 ug/kg
C9- C10 Aromatics ND 5000 1800 ug/kg
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 94%70-130%
460-00-4 BFB 94%70-130%
36 of 53
FA7514266.1.2
Method Blank Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP80320-MB DD1120545.D 1 05/22/20 CV 05/22/20 OP80320 GDD3229
The QC reported here applies to the following samples:Method: EPA 504.1
FA75142-2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.020 0.010 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 105%63-137%
37 of 53
FA7514266.1.3
Blank Spike Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP80320-BS DD1120544.D 1 05/22/20 CV 05/22/20 OP80320 GDD3229
The QC reported here applies to the following samples:Method: EPA 504.1
FA75142-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
106-93-4 1,2-Dibromoethane 0.25 0.23 92 70-130
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 96%63-137%
* = Outside of Control Limits.
38 of 53
FA7514266.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S35-BS 1S2574.D 1 05/21/20 SH n/a n/a G1S35
G1S35-BSD 1S2575.D 1 05/21/20 SH n/a n/a G1S35
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-2
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 82.5 103 79.0 99 4 70-130/25
100-41-4 Ethylbenzene 80 84.1 105 80.9 101 4 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 85.9 107 87.2 109 2 70-130/25
91-20-3 Naphthalene 80 83.3 104 81.0 101 3 70-130/25
108-88-3 Toluene 80 85.2 107 81.4 102 5 70-130/25
m,p-Xylene 160 169 106 163 102 4 70-130/25
95-47-6 o-Xylene 80 84.1 105 80.9 101 4 70-130/25
C5- C8 Aliphatics (Unadj.)240 225 94 230 96 2 70-130/25
C9- C12 Aliphatics (Unadj.)160 172 108 161 101 7 70-130/25
C9- C10 Aromatics (Unadj.)80 82.7 103 78.7 98 5 70-130/25
C9- C10 Aromatics 80 82.7 103 78.7 98 5 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 107%105%70-130%
460-00-4 BFB 109%107%70-130%
* = Outside of Control Limits.
39 of 53
FA7514266.3.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S36-BS 1S2591.D 1 05/22/20 EG n/a n/a G1S36
G1S36-BSD 1S2592.D 1 05/22/20 EG n/a n/a G1S36
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/kg ug/kg %ug/kg %RPD Rec/RPD
71-43-2 Benzene 4080 3700 91 3650 89 1 70-130/25
100-41-4 Ethylbenzene 4080 3830 94 3800 93 1 70-130/25
1634-04-4 Methyl Tert Butyl Ether 4080 4220 103 4090 100 3 70-130/25
91-20-3 Naphthalene 4080 3690 90 3770 92 2 70-130/25
108-88-3 Toluene 4080 3800 93 3760 92 1 70-130/25
m,p-Xylene 8160 7710 94 7660 94 1 70-130/25
95-47-6 o-Xylene 4080 3870 95 3850 94 1 70-130/25
C5- C8 Aliphatics (Unadj.)12200 11300 92 10600 87 6 70-130/25
C9- C12 Aliphatics (Unadj.)8160 7620 93 7090 87 7 70-130/25
C9- C10 Aromatics (Unadj.)4080 3810 93 3800 93 0 70-130/25
C9- C10 Aromatics 4080 3810 93 3800 93 0 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 94%96%70-130%
460-00-4 BFB 94%96%70-130%
* = Outside of Control Limits.
40 of 53
FA7514266.3.2
Matrix Spike Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA75015-1MS 1S2579.D 1 05/21/20 SH n/a n/a G1S35
FA75015-1 1S2577.D 1 05/21/20 SH n/a n/a G1S35
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-2
FA75015-1 Spike MS MS
CAS No.Compound ug/l Q ug/l ug/l %Limits
71-43-2 Benzene ND 80 72.4 91 70-130
100-41-4 Ethylbenzene ND 80 74.5 93 70-130
1634-04-4 Methyl Tert Butyl Ether ND 80 80.3 100 70-130
91-20-3 Naphthalene ND 80 74.7 93 70-130
108-88-3 Toluene ND 80 74.3 93 70-130
m,p-Xylene ND 160 150 94 70-130
95-47-6 o-Xylene ND 80 74.4 93 70-130
C5- C8 Aliphatics (Unadj.)ND 480 442 92 70-130
C9- C12 Aliphatics (Unadj.)ND 400 552 138*70-130
C9- C10 Aromatics (Unadj.)ND 240 118 49*70-130
C9- C10 Aromatics ND 240 118 49*70-130
CAS No.Surrogate Recoveries MS FA75015-1 Limits
460-00-4 BFB 102%97%70-130%
460-00-4 BFB 105%97%70-130%
* = Outside of Control Limits.
41 of 53
FA7514266.4.1
Matrix Spike Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA74923-7RMS 1S2600.D 1 05/22/20 EG n/a n/a G1S36
FA74923-7R 1S2596.D 1 05/22/20 EG n/a n/a G1S36
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-1
FA74923-7R Spike MS MS
CAS No.Compound ug/kg Q ug/kg ug/kg %Limits
71-43-2 Benzene 563 9120 9660 100 70-130
100-41-4 Ethylbenzene 3080 9120 12800 107 70-130
1634-04-4 Methyl Tert Butyl Ether 220 U 9120 9670 106 70-130
91-20-3 Naphthalene 659 9120 9700 99 70-130
108-88-3 Toluene 7820 9120 17100 102 70-130
m,p-Xylene 12200 18200 31000 103 70-130
95-47-6 o-Xylene 6180 9120 16000 108 70-130
C5- C8 Aliphatics (Unadj.)36400 54700 88700 96 70-130
C9- C12 Aliphatics (Unadj.)51500 L 45600 113000 135*70-130
C9- C10 Aromatics (Unadj.)47100 L 27400 60200 48*70-130
C9- C10 Aromatics 47100 L 27400 60200 48*70-130
CAS No.Surrogate Recoveries MS FA74923-7R Limits
460-00-4 BFB 126%140%* a 70-130%
460-00-4 BFB 125%122%70-130%
(a) Outside control limits due to dilution.
* = Outside of Control Limits.
42 of 53
FA7514266.4.2
Matrix Spike Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP80320-MS DD1120548.D 1 05/22/20 CV 05/22/20 OP80320 GDD3229
FA75141-1 DD1120546.D 1 05/22/20 CV 05/22/20 OP80320 GDD3229
The QC reported here applies to the following samples:Method: EPA 504.1
FA75142-2
FA75141-1 Spike MS MS
CAS No.Compound ug/l Q ug/l ug/l %Limits
106-93-4 1,2-Dibromoethane ND 0.232 0.20 86 70-130
CAS No.Surrogate Recoveries MS FA75141-1 Limits
460-00-4 4-Bromofluorobenzene 75%76%63-137%
* = Outside of Control Limits.
43 of 53
FA7514266.4.3
Duplicate Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA75015-1DUP 1S2578.D 1 05/21/20 SH n/a n/a G1S35
FA75015-1 1S2577.D 1 05/21/20 SH n/a n/a G1S35
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-2
FA75015-1 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA75015-1 Limits
460-00-4 BFB 99%97%70-130%
460-00-4 BFB 97%97%70-130%
* = Outside of Control Limits.
44 of 53
FA7514266.5.1
Duplicate Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA74923-7RDUP 1S2597.D 1 05/22/20 EG n/a n/a G1S36
FA74923-7R 1S2596.D 1 05/22/20 EG n/a n/a G1S36
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA75142-1
FA74923-7R DUP
CAS No.Compound ug/kg Q ug/kg Q RPD Limits
71-43-2 Benzene 563 555 1 50
100-41-4 Ethylbenzene 3080 3040 1 50
1634-04-4 Methyl Tert Butyl Ether 220 U ND nc 50
91-20-3 Naphthalene 659 642 3 50
108-88-3 Toluene 7820 7660 2 50
m,p-Xylene 12200 12200 0 50
95-47-6 o-Xylene 6180 6130 1 50
C5- C8 Aliphatics (Unadj.)36400 35300 3 50
C9- C12 Aliphatics (Unadj.)51500 L 48700 E 6 50
C9- C10 Aromatics (Unadj.)47100 L 46800 E 1 50
C5- C8 Aliphatics 28000 27100 3 50
C9- C12 Aliphatics 30000 L 27300 E 9 50
C9- C10 Aromatics 47100 L 46800 E 1 50
CAS No.Surrogate Recoveries DUP FA74923-7R Limits
460-00-4 BFB 136%*140%* a 70-130%
460-00-4 BFB 123%122%70-130%
(a) Outside control limits due to dilution.
* = Outside of Control Limits.
45 of 53
FA7514266.5.2
Duplicate Summary Page 1 of 1
Job Number:FA75142
Account:GRINCC GRI (Geological Resources Inc.)
Project:Handy Mart 33; Havelock, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP80320-DUP DD1120549.D 1 05/22/20 CV 05/22/20 OP80320 GDD3229
FA75142-2 DD1120547.D 1 05/22/20 CV 05/22/20 OP80320 GDD3229
The QC reported here applies to the following samples:Method: EPA 504.1
FA75142-2
FA75142-2 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
106-93-4 1,2-Dibromoethane ND ND nc 25
CAS No.Surrogate Recoveries DUP FA75142-2 Limits
460-00-4 4-Bromofluorobenzene 95%101%63-137%
* = Outside of Control Limits.
46 of 53
FA7514266.5.3
SGS North America Inc.
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Orlando, FL
Section 7
47 of 53
FA751427
BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA75142
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Handy Mart 33; Havelock, NC
QC Batch ID: MP37264 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/20
MB
Metal RL IDL MDL raw final
Aluminum 200 14 14
Antimony 6.0 1 1
Arsenic 10 1.3 1.3
Barium 200 1 1
Beryllium 4.0 .2 .2
Cadmium 5.0 .2 .2
Calcium 1000 50 50
Chromium 10 1 1
Cobalt 50 .2 .2
Copper 25 1 1
Iron 300 17 17
Lead 5.0 1 1.1 -0.30 <5.0
Magnesium 5000 35 35
Manganese 15 .5 1
Molybdenum 50 .3 .3
Nickel 40 .4 .4
Potassium 10000 200 200
Selenium 10 2.4 2.9
Silver 10 .7 .7
Sodium 10000 500 500
Strontium 10 .5 .5
Thallium 10 1.1 1.4
Tin 50 .9 1
Titanium 10 .5 1
Vanadium 50 .5 .6
Zinc 20 3 4.4
Associated samples MP37264: FA75142-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
48 of 53
FA7514277.1.1
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75142
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Handy Mart 33; Havelock, NC
QC Batch ID: MP37264 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/20 05/22/20
FA75036-5 QC FA75036-5 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt
Copper
Iron
Lead 2.8 3.0 6.9 0-20 2.8 464 500 92.2 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37264: FA75142-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
49 of 53
FA7514277.1.2
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA75142
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Handy Mart 33; Havelock, NC
QC Batch ID: MP37264 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/20
FA75036-5 Spikelot MSD QC
Metal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt
Copper
Iron
Lead 2.8 453 500 90.0 2.4 20
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37264: FA75142-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 2
50 of 53
FA7514277.1.2
SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA75142
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Handy Mart 33; Havelock, NC
QC Batch ID: MP37264 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/20
BSP Spikelot QC
Metal Result MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt
Copper
Iron
Lead 456 500 91.2 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37264: FA75142-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
51 of 53
FA7514277.1.3
SERIAL DILUTION RESULTS SUMMARY
Login Number: FA75142
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Handy Mart 33; Havelock, NC
QC Batch ID: MP37264 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/20
FA75036-5 QC
Metal Original SDL 1:5 %DIF Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium anr
Calcium
Chromium anr
Cobalt
Copper
Iron
Lead 2.80 0.00 100.0(a) 0-10
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37264: FA75142-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
_________________________________________________________________________________________________________
Page 1
52 of 53
FA7514277.1.4
POST DIGESTATE SPIKE SUMMARY
Login Number: FA75142
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Handy Mart 33; Havelock, NC
QC Batch ID: MP37264 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/20
Sample Final FA75036-5 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 9.8 10 2.8 2.744 44.8 0.2 2.5 50 84.1 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37264: FA75142-2
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
53 of 53
FA7514277.1.5