WA-27712_47028_CA_RPTS_20200512_SCH

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Site Check Report
Grantham Supply & Supermarket
3388 US 13 South
Goldsboro, Wayne County
North Carolina
Facility ID Number: 00-0-0000005216
Incident Number: NA
GRI Project Number: 5370

Prepared for:

Grantham Supply & Supermarket
Mr. Ted Grantham
3396 US 13 South
Goldsboro, NC 27530

May 12, 2020

Matthew Schroeder, P.G.
Project Manager

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 12, 2020 Grantham Supply & Supermarket
Project Manager: Matthew Schroeder, P.G. GRI Project No. 5370
i
EXECUTIVE SUMMARY
The Grantham Supply & Supermarket site is located at 3388 US 13 South in Goldsboro, Wayne County,
North Carolina. The property operates as a petroleum retail facility, hardware and convenience store.
The site is covered by concrete and asphalt. One 8,000-gallon gasoline, one 8,000-gallon off-road diesel
and one 8,000-gallon highway diesel USTs are currently in use at the site with three associated dispensers.

On June 18, 2018, during annual compliance testing activities, the regular gasoline tank #1 spill bucket
failed tightness testing. A liner was installed and the spill bucket passed tightness testing on August 13,
2018. A site check was required by NCDEQ following the June 2018 compliance testing.

Two previous incidents (13426 and 16371) have been documented at this site. The site risk classification
was ranked as low risk and both incidents were closed with the filing of a Notice of Residual Petroleum
(NRP) in May 2002.

On April 17, 2020, GRI conducted a site check. A ground water sample was collected from a preexisting
monitoring well (RW-1) located within the UST basin. The Maximum Allowable Concentrations (MACs) as
specified in T15A NCAC 2L.0202 were below the concentration of requested method constituents
reported in the ground water sample collected from RW-1. All of the reported contaminant
concentrations were below the Gross Contamination Levels (GCLs).

Based on this information, the ground water contamination is consistent with previous releases
documented at the site. With a NRP already in place, no further assessment is warranted for this incident.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 12, 2020 Grantham Supply & Supermarket
Project Manager: Matthew Schroeder, P.G. GRI Project No. 5370

TABLE OF CONTENTS

A. SITE HISTORY AND CHARACTERIZATION .....................................................................1
B. SITE CHECK PROCEDURES ...........................................................................................2
C. SITE INVESTIGATION ..................................................................................................2
D. SUMMARY AND CONCLUSIONS ..................................................................................3
E. LIMITATIONS .............................................................................................................3

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Soil Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Summary of Ground water Sample Analytical Results

APPENDICES
Appendix A: State Correspondence
Appendix B: Laboratory Report – Ground Water Sample

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 12, 2020 Grantham Supply & Supermarket
Project Manager: Matthew Schroeder, P.G. GRI Project No. 5370
1
A. SITE HISTORY AND CHARACTERIZATION
1. UST Owner and Operator Information:
In accordance with the Site Check Report guidelines, the underground storage tank (UST) owner and
operator information has been summarized in the attached Table 1.

2. UST System Information:
In accordance with the Site Check Report guidelines, the UST system information has been summarized
in the attached Table 2. There are one 8,000-gallon gasoline UST, one 8,000-gallon off-road diesel and
one 8,000-gallon highway diesel USTs currently in use at the site with two associated dispensers. One
1,000-gallon kerosene UST was removed from the site in December 1994. A copy of the NCDEQ
Registered Tank Report is shown below:

3. Non-UST Information:
There are currently no above ground petroleum storage tanks (ASTs) and no known ASTs formerly at
the site.

4. Comprehensive Description of the Release:
The spill bucket associated with the 8,000-gallon regular #1 gasoline UST failed tightness testing during
triennial compliance testing conducted on June 18, 2018. A liner was installed and the spill bucket passed
integrity testing on August 13, 2018. A Notice of Violation directing a site check was issued by NCDEQ on
March 23, 2020. Copies of NCDEQ correspondence are included as Appendix A.

Two previous incidents (13426 and 16371) been documented at this site. The site was raked as low risk
and both incident closed with the filing of a Notice of Residual Petroleum (NRP) in May 2002. On April 17,
2020, a ground water sample was collected from a preexisting monitoring well located in the UST basin.
The laboratory results are representative of past releases at the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 12, 2020 Grantham Supply & Supermarket
Project Manager: Matthew Schroeder, P.G. GRI Project No. 5370
2

5. Description of the Site Characteristics:
The Grantham Supply & Supermarket site is located at 3388 US 13 South in Goldsboro, Wayne County,
North Carolina. (Figure 1). The property operates as a petroleum retail facility, hardware and
convenience store. The site is covered by concrete and grass. There are one 8,000-gallon gasoline, one
8,000-gallon off-road diesel and one 8,000-gallon highway diesel USTs currently in use at the site with
three associated dispensers. The surrounding properties are commercial, agricultural and public
institutional. A Site Map has been included as Figure 2.

B. SITE CHECK PROCEDURES
1. Results of Tank and Line Tightness Testing:
According to available information, the spill bucket was repaired and passed integrity testing on August
13, 2018.

2. Summary of Site Check Procedure:
GRI performed a site check on April 17, 2020, that included the collection of a ground water sample from
an existing monitoring well (RW-1) located within the UST basin.

3. Soil Excavation Activities:
No soil excavation activities were conducted.

C. SITE INVESTIGATION
1. Field Screening:
No Field screening was conducted during the April 2020 site check.

2. Soil Sampling Information:
A soil sample was not collected on April 17, 2020 site check.

3. Ground Water and Surface Water Sampling Information:
On April 17, 2020, RW-1 was gauged, purged and sampled. Depth to ground water was measured at
4.84 feet bgs. A ground water sample was collected form a preexisting monitoring well RW-1 located
within the UST basin. The ground water sample was submitted for laboratory analyses of volatile
organic compounds (VOCs) and 5-oxygenates by EPA Method 6200B, semi-VOCs by EPA Method 610 +
10 highest tentatively identified compounds, EDB by EPA Method 504.1, lead by EPA Method 6010B, as
well as VPH and EPH using the MADEP Methods. The Maximum Allowable Concentrations (MACs) as
specified in T15A NCAC 2L.0202 were below the concentrations of benzene, naphthalene, TAA, TBA, 1-
methylnaphthalene, C5-C8 aliphatics, C9-C10 aromatics and C11-C22 aromatics reported in the ground
water sample collected from RW-1. All of the reported contaminant concentrations were below the
Gross Contamination Levels (GCLs). No free product was observed at the site. A ground water quality
map is presented as Figure 3. A summary of ground water sample analytical results is presented in

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 12, 2020 Grantham Supply & Supermarket
Project Manager: Matthew Schroeder, P.G. GRI Project No. 5370
3
Table 3. The laboratory report is provided as Appendix B. A summary of the ground water sampling
data from the April 2020 site check activities is show below:

Contaminant of
Concern
 Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MAC (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 84,500 85,500 20,000 6,000
RW-1 555 122 70.7 81.2 14.3 61.0

4. Quality-Control Measures:
Clean, disposable nitrile gloves and a new disposable bailer were used in the collection of the ground
water sample. The sample was collected in laboratory supplied containers and shipped to the
laboratory in a cooler following proper chain-of-custody procedures.

D. SUMMARY AND CONCLUSIONS
 The site is commercial and surrounding properties are commercial, agricultural and public
institutional.
 On June 18, 2018, during triennial compliance testing activities, the regular gasoline tank #1 spill
bucket failed tightness testing. A site check was required by NCDEQ following the June 18, 2018,
compliance testing. The non-passing UST spill bucket was repaired and passed integrity testing
on August 13, 2018.
 Two previous incidents (13426 and 16371) been documented at this site. The site was raked as
low risk and both incidents were closed with the filing of a NRP in May 2002.
 A Site Check was conducted on April 17, 2020, which consisted of collecting a ground water
sample from a preexisting monitoring well located within the UST basin.
 The MACs were below the concentrations of benzene, naphthalene, TAA, TBA, 1-
methylnaphthalene, C5-C8 aliphatics, C9-C10 aromatics and C11-C22 aromatics reported in the
ground water sample collected from RW-1. All of the reported contaminant concentrations were
below the GCLs.
 Based on this information, the ground water contamination is consistent with previous releases
documented at the site. With a NRP already in place, no further assessment is warranted for this
incident.
E. LIMITATIONS
This report has been prepared for the exclusive use of Grantham Supply & Supermarket for the specific
application to the referenced site in Wayne County, North Carolina. The assessment was conducted based
on the scope of work and level of effort specified by NCDEQ and with resources adequate only for that
scope of work. Our findings have been developed in accordance with generally accepted standards of

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: May 12, 2020 Grantham Supply & Supermarket
Project Manager: Matthew Schroeder, P.G. GRI Project No. 5370
4
geology and hydrogeology practices in the State of North Carolina, available information, and our
professional judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site Location Grantham Supply & Supermarket3388 US 13 South Goldsboro, Wayne County, NC Incident No. 13426-16371GRI Project No. 5370500 M2000 FTDate: 05/05/2020Location: 35.297280° N -78.164464 ° W Dad

TABLES
UST ID Number 1, 2 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 3 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 4 Facility ID Number
Owner or Operator?
Owner/Operator
Address Telephone Number
3388 US 13 South, Goldsboro NC 27530 919-920-1613
00-0-0000005216
Name of Owner or Operator Dates of Ownership / Operation
Granham Suppy & Supermarket 03/26/1983 - 12/29/1994
00-0-0000005216
TABLE 1
UST OWNER/OPERATOR INFORMATION
GRANTHAM SUPPLY & SUPERMARKET (INCIDENT NO. N/A)
3388 US 13 South, Goldsboro NC 27530 919-920-1613
Name of Owner or Operator Dates of Ownership / Operation
Granham Suppy & Supermarket 03/29/1971 - Current
Address Telephone Number
Address Telephone Number
3388 US 13 South, Goldsboro NC 27530 919-920-1613
00-0-0000005216
Name of Owner or Operator Dates of Ownership / Operation
Granham Suppy & Supermarket 03/27/1976 - Current
Page 1 of 1
Date: 05/04/2020
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline NA 8,000 3/29/1971 Single Wall Steel 8' X 21' 4"Single Wall FRP Current Yes
(UST Incident No. 16371)
2 Highway
Diesel NA 8,000 3/29/1971 Single Wall Steel 8' X 21' 4"Single Wall FRP Current Yes
(UST Incident No. 16371)
3 Off-Road
Diesel Gasoline 8,000 3/27/1976 Single Wall Steel 8' X 21' 4"Single Wall FRP Current Yes
(UST Incident No. 16371)
4 Kerosene NA 1,000 3/26/1983 Single Wall Steel 64" X 72"Single Wall Steel Removed
12/29/1994 No
TABLE 2
UST SYSTEM INFORMATION
GRANTHAM SUPPLY & SUPERMARKET (INCIDENT NO. N/A)
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Facility ID # : 00-0-0000005216
Page 1 of 1
Date: 05/04/2020 Facility ID # : 00-0-0000005216
EPA
504.1
EPA
625.1 EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 0.02 1 15 400 700 200 700 10,000 200
5,000 260,000 84,500 85,500 20,000 6,000 40,000 10,000 50 1,000 15,000 NE NE NE NE NE NE
RW-1 04/17/20 555 122 70.7 81.2 14.3 61.0 1,700 3,390 <0.0095 15.3 <5.0 1,150 83.1 J 320 <51 <51 346
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the MAC was below the reported concentration.
• J: Estimated value.
• NE: Not established.
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.
MAC (μg/l)
GCL (μg/l)MTBENaphthaleneC9-C10 AromaticsContaminant of Concern
BenzeneTolueneEthylbenzeneXylenesEPA 6200B
TABLE 3
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
GRANTHAM SUPPLY & SUPERMARKET (INCIDENT NO. N/A)
Analytical Method
1,2-Dibromoethane(EDB)MADEP EPHMADEP VPH
C9-C18 AliphaticsC19-C36 AliphaticsLeadC5-C8 AliphaticsC9-C12 AliphaticsC11-C22 Aromaticstert-Amyl alcohol(TAA)tert-Butyl alcohol (TBA)1-MethylnaphthalenePage 1 of 1

APPENDICES

Appendix A
State Correspondence

NORTH CAROLINA
Environmental Quality
ROY COOPER
Governor
MICHAEL S. REGAN
Secretary
MICHAEL SCOTT
Director

North Carolina Department of Environmental Quality | Division of Waste Management
217 West Jones Street | 1646 Mail Service Center | Raleigh, North Carolina 27699-1646
919.707.8171

March 23, 2020

CERTIFIED MAIL 9414 8118 9956 2844 6120 59
RETURN RECEIPT REQUESTED

James H. Grantham, Registered Agent
Grantham Supply & Supermarket
3388 US 13 South
Goldsboro, NC 27530-1024

Re: NOTICE OF VIOLATION OF 15A NCAC 2N .0504(LD17), .0603(RLS7)
Grantham Supply & Supermarket
3388 US 13 South, Goldsboro, NC 27530-1024
Wayne County
Facility ID#: 00-0-0000005216

Dear James H. Grantham:

On March 10, 2020, I conducted a compliance inspection at the above-referenced facility. I observed that underground
storage tanks (USTs) at Grantham Supply & Supermarket are not in compliance with North Carolina UST regulations
(North Carolina Administrative Code [NCAC] 2N "Criteria and Standards Applicable to Underground Storage Tanks).
According to those rules (15A NCAC 2N .0203) Grantham Supply & Supermarket is identified as the owner and/or
operator of UST(s) at Grantham Supply & Supermarket.

The following violations of the state rules (15A NCAC 2N) were observed on March 10, 2020 at Grantham Supply &
Supermarket. Following each violation are the actions required to correct the violations:

Violation 1: 15A NCAC 2N .0504 LD17; Failure to conduct 0.2 gallons per hour leak rate tests, according to the
automatic tank gauge requirements of federal regulation 40 CFR 280.43(d)(1) (as incorporated by 15A NCAC
2N .0504) at least every 30 days as required by federal regulation 40 CFR 280.41(a) (as incorporated by 15A
NCAC 2N .0502).
Comment: Tank #1 Reg, Hwy Diesel, #3 Off Rd: November and December 2019 tank leak detection records were
not available for review.

Corrective Action(s):

1) The Division of Waste Management UST Section has determined that the 0.2 gallons per hour leak rate tests have
not been conducted for the subject tank(s). The 0.2 gallons per hour leak rate tests are required to be conducted at least
once a month. Within 30 days of receipt of this notice, submit copies of the tests for the month following the date of
receipt of this notice to the inspector at the address provided. Please include in your response the date that monthly
automatic tank gauge testing has been initiated. The Division of Waste Management UST Section recommends that
you conduct tests as often as possible during the month to ensure that you will obtain tests that are conducted within
the testing parameters established by the automatic tank gauge system's third party standard evaluation.

Violation 2: 15A NCAC 2N .0603 RLS7; Failure to investigate a suspected release in accordance with federal
regulation 40 CFR 280.52 (as incorporated by 15A NCAC 2N .0603) after a failing tightness test of the spill
containment, the presence of fuel in spill containment buckets or the degradation of the spill containment
equipment to the point where that equipment can not reasonably be expected to perform its intended function was
observed.
Comment: Tank #1 Reg: Regular spill bucket failed the integrity test completed on 6-18-2018. Liner was installed
and passed on 8-13-2018.

Corrective Action(s):
Tank owners or operators must investigate a suspected release as directed below.
1) The spill containment bucket failed a tightness test or the condition of the spill containment bucket has deteriorated
such that it may need repairing or replacing. All replaced spill buckets must meet the secondary containment
requirements of 15A NCAC 2N .0900. You must complete the actions listed below.
If any spill containment bucket fails the tightness test, you must complete all of the following tasks: (a) Conduct a site
check around the spill containment bucket for the tanks listed above in accordance with 40 CFR 280.52(b) (as
incorporated by 15A NCAC 2N .0603) using the sampling protocol and methodology of the most recent version of
the UST Section Guidelines for Site Checks, Tank Closure, and Initial Response and Abatement and submit, within
30 days of receipt of this notice, a site check report or initial abatement report (whichever is applicable) to the inspector
at the address provided

Notice of Deficiency:

Deficiency 1: NCGS 143-215.94NN-SS OPTR4; Failure to maintain compliance with UST regulations which
requires Primary Operator retraining as required by NCGS 143-215.94NN - 143.215.94SS.

Corrective Action(s):
Please perform the following corrective action:
1) Within 30 days of receipt of this notice, submit to the inspector at the address provided documentation that
shows the other violations listed on this notice have been corrected. If they are not corrected within the next
30 days, then the Primary Operator designated for this facility must go to the following
website http://tankschool.nc.gov and register for one of the next Tank School courses being conducted over
the next 90 days. Tank School must be completed and a Primary Operator training certificate achieved within 90
days of receipt of this notice.

Corrective actions must be completed and reported to the inspector at the address provided within 30 days of receipt
of this notice, unless otherwise noted in one of the corrective actions listed above. Assessment of civil penalties may
be recommended for violations described in this NOV, as well as, operating permit revocation/denial unless the
violations are corrected. If Grantham Supply & Supermarket believes that the inspection findings are in error, or if
Grantham Supply & Supermarket has any questions pertaining to this NOV and/or corrective actions please have it
contact me at [phone] or [e-mail].

Sincerely,

Gina Williams, Environmental Specialist
Division of Waste Management, NC DEQD

Enclosures: UST-10B (UST Inspection Checklist)

cc: Michael Phelps w/ Enclosures (electronic)
Files (electronic)

Appendix B
Laboratory Report – Ground Water Sample
05/04/20
Technical Report for
GRI (Geological Resources Inc.)
Grantham Supply & Super Market; Goldsboro, NC
5370
SGS Job Number: FA74369
Sampling Date: 04/17/20
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: Matthew Schroeder
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 05/04/20
Reissue #1
e-Hardcopy 2.0
Automated Report
54
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 54
FA74369
Florida ♦ 4405 Vineland Road ♦ Suite C-15 ♦ Orlando, FL 32811 ♦ tel: [phone] ♦ fax: [phone]

May 4, 2020 Mr. Matt Schroeder Geological Resources Inc. 3502 Hayes Road Monroe, NC 28110 RE: SGS North America Inc. - Orlando job FA74369 Reissue Dear Mr. Schroeder, The final report for job number FA74369 has been edited to reflect requested corrections. These edits have been incorporated into the revised report. Total Xylenes have been reported.
SGS North America Inc. - Orlando apologies for any inconvenience this may have caused.
Please feel free to contact us if we can be of further assistance.
Sincerely,

SGS North America, Inc. - Orlando
2 of 54
FA74369
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................4
Section 2: Summary of Hits ....................................................................................................5
Section 3: Sample Results ........................................................................................................6
3.1: FA74369-1: RW-1 .........................................................................................................7
Section 4: Misc. Forms ............................................................................................................17
4.1: Chain of Custody ...........................................................................................................18
Section 5: MS Volatiles - QC Data Summaries .....................................................................21
5.1: Method Blank Summary ................................................................................................22
5.2: Blank Spike Summary ...................................................................................................25
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................28
Section 6: MS Semi-volatiles - QC Data Summaries ............................................................31
6.1: Method Blank Summary ................................................................................................32
6.2: Blank Spike Summary ...................................................................................................34
Section 7: GC Volatiles - QC Data Summaries .....................................................................36
7.1: Method Blank Summary ................................................................................................37
7.2: Blank Spike Summary ...................................................................................................39
7.3: Blank Spike/Blank Spike Duplicate Summary ..............................................................40
7.4: Matrix Spike Summary ..................................................................................................41
7.5: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................42
7.6: Duplicate Summary .......................................................................................................43
Section 8: GC/LC Semi-volatiles - QC Data Summaries .....................................................44
8.1: Method Blank Summary ................................................................................................45
8.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................46
Section 9: Metals Analysis - QC Data Summaries ................................................................48
9.1: Prep QC MP37122: Pb ..................................................................................................49 1234567893 of 54
FA74369
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA74369
Grantham Supply & Super Market; Goldsboro, NC
Project No: 5370
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA74369-1 04/17/20 08:11 ME 04/18/20 AQ Ground Water RW-1
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FA743691
Summary of Hits Page 1 of 1
Job Number:FA74369
Account:GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Collected:04/17/20
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA74369-1 RW-1
Benzene 555 10 2.5 ug/l SM 6200B
Di-Isopropyl Ether 25.7 10 2.5 ug/l SM 6200B
Ethylbenzene 70.7 10 2.5 ug/l SM 6200B
Isopropylbenzene 11.3 10 2.5 ug/l SM 6200B
Methyl Tert Butyl Ether 14.3 10 2.5 ug/l SM 6200B
Naphthalene 61.0 10 2.5 ug/l SM 6200B
n-Propylbenzene 7.9 J 10 2.5 ug/l SM 6200B
Tert-Amyl Alcohol 1700 200 40 ug/l SM 6200B
Tert-Butyl Alcohol 3390 200 40 ug/l SM 6200B
Toluene 122 10 2.5 ug/l SM 6200B
1,2,4-Trimethylbenzene 5.2 J 10 2.5 ug/l SM 6200B
1,3,5-Trimethylbenzene 3.0 J 10 2.5 ug/l SM 6200B
m,p-Xylene 60.6 20 2.5 ug/l SM 6200B
o-Xylene 20.5 10 2.5 ug/l SM 6200B
Xylene (total)81.2 30 5.0 ug/l SM 6200B
2,4-Dimethylphenol 1.7 J 5.0 0.74 ug/l EPA 625.1
Phenol 1.4 J 5.0 0.50 ug/l EPA 625.1
1-Methylnaphthalene 15.3 5.0 0.53 ug/l EPA 625.1
2-Methylnaphthalene 22.9 5.0 0.60 ug/l EPA 625.1
Naphthalene 38.6 5.0 0.50 ug/l EPA 625.1
Total TIC, Semi-Volatile 385 J ug/l
Benzene 428 2.0 2.0 ug/l MADEP VPH REV 1.1
Ethylbenzene 63.8 4.0 2.0 ug/l MADEP VPH REV 1.1
Methyl Tert Butyl Ether 14.9 4.0 2.0 ug/l MADEP VPH REV 1.1
Naphthalene 58.8 10 6.0 ug/l MADEP VPH REV 1.1
Toluene 92.2 4.0 2.0 ug/l MADEP VPH REV 1.1
m,p-Xylene 45.9 8.0 4.0 ug/l MADEP VPH REV 1.1
o-Xylene 19.1 4.0 2.0 ug/l MADEP VPH REV 1.1
C5- C8 Aliphatics (Unadj.)1690 200 70 ug/l MADEP VPH REV 1.1
C9- C12 Aliphatics (Unadj.)212 200 70 ug/l MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.)320 200 70 ug/l MADEP VPH REV 1.1
C5- C8 Aliphatics 1150 200 70 ug/l MADEP VPH REV 1.1
C9- C12 Aliphatics 83.1 J 200 70 ug/l MADEP VPH REV 1.1
C9- C10 Aromatics 320 200 70 ug/l MADEP VPH REV 1.1
2-Methylnaphthalene 18.1 4.1 2.0 ug/l MADEP EPH REV 1.1
Naphthalene 36.3 4.1 2.0 ug/l MADEP EPH REV 1.1
C11-C22 Aromatics (Unadj.)400 200 82 ug/l MADEP EPH REV 1.1
C11-C22 Aromatics 346 200 82 ug/l MADEP EPH REV 1.1
5 of 54
FA743692
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 54
FA743693
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:SM 6200B Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0222026.D 20 04/20/20 12:16 AB n/a n/a VA2722
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 555 10 2.5 ug/l
108-86-1 Bromobenzene ND 10 2.5 ug/l
74-97-5 Bromochloromethane ND 10 2.5 ug/l
75-27-4 Bromodichloromethane ND 10 2.5 ug/l
75-25-2 Bromoform ND 10 2.5 ug/l
104-51-8 n-Butylbenzene ND 10 2.5 ug/l
135-98-8 sec-Butylbenzene ND 10 2.5 ug/l
98-06-6 tert-Butylbenzene ND 10 2.5 ug/l
56-23-5 Carbon Tetrachloride ND 10 2.5 ug/l
108-90-7 Chlorobenzene ND 10 2.5 ug/l
75-00-3 Chloroethane ND 10 4.0 ug/l
67-66-3 Chloroform ND 10 2.5 ug/l
95-49-8 o-Chlorotoluene ND 10 2.5 ug/l
106-43-4 p-Chlorotoluene ND 10 2.5 ug/l
124-48-1 Dibromochloromethane ND 10 2.5 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 10 4.9 ug/l
106-93-4 1,2-Dibromoethane ND 10 2.5 ug/l
75-71-8 Dichlorodifluoromethane ND 10 4.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 10 2.5 ug/l
541-73-1 1,3-Dichlorobenzene ND 10 2.5 ug/l
106-46-7 1,4-Dichlorobenzene ND 10 2.5 ug/l
75-34-3 1,1-Dichloroethane ND 10 2.5 ug/l
107-06-2 1,2-Dichloroethane ND 10 2.5 ug/l
75-35-4 1,1-Dichloroethylene ND 10 2.5 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 10 2.5 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 10 2.5 ug/l
78-87-5 1,2-Dichloropropane ND 10 2.5 ug/l
142-28-9 1,3-Dichloropropane ND 10 2.5 ug/l
594-20-7 2,2-Dichloropropane ND 10 2.5 ug/l
563-58-6 1,1-Dichloropropene ND 10 2.5 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 10 2.5 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 10 2.5 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:SM 6200B Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 25.7 10 2.5 ug/l
100-41-4 Ethylbenzene 70.7 10 2.5 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 10 2.5 ug/l
87-68-3 Hexachlorobutadiene ND 10 2.5 ug/l
98-82-8 Isopropylbenzene 11.3 10 2.5 ug/l
99-87-6 p-Isopropyltoluene ND 10 2.5 ug/l
74-83-9 Methyl Bromide ND 10 4.0 ug/l
74-87-3 Methyl Chloride ND 10 4.0 ug/l
74-95-3 Methylene Bromide ND 10 2.5 ug/l
75-09-2 Methylene Chloride ND 40 20 ug/l
1634-04-4 Methyl Tert Butyl Ether 14.3 10 2.5 ug/l
91-20-3 Naphthalene 61.0 10 2.5 ug/l
103-65-1 n-Propylbenzene 7.9 10 2.5 ug/l J
100-42-5 Styrene ND 10 2.5 ug/l
75-85-4 Tert-Amyl Alcohol 1700 200 40 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 20 4.0 ug/l
75-65-0 Tert-Butyl Alcohol 3390 200 40 ug/l
762-75-4 Tert-Butyl Formate ND 200 40 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 10 2.5 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 10 2.5 ug/l
127-18-4 Tetrachloroethylene ND 10 2.5 ug/l
108-88-3 Toluene 122 10 2.5 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 10 2.5 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 10 2.5 ug/l
71-55-6 1,1,1-Trichloroethane ND 10 2.5 ug/l
79-00-5 1,1,2-Trichloroethane ND 10 2.5 ug/l
79-01-6 Trichloroethylene ND 10 2.5 ug/l
75-69-4 Trichlorofluoromethane ND 10 4.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 10 2.5 ug/l
95-63-6 1,2,4-Trimethylbenzene 5.2 10 2.5 ug/l J
108-67-8 1,3,5-Trimethylbenzene 3.0 10 2.5 ug/l J
75-01-4 Vinyl Chloride ND 10 2.5 ug/l
m,p-Xylene 60.6 20 2.5 ug/l
95-47-6 o-Xylene 20.5 10 2.5 ug/l
1330-20-7 Xylene (total)81.2 30 5.0 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 109%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:SM 6200B Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
VOA 6200B List
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 3
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 X070117.D 1 04/21/20 17:19 MV 04/20/20 10:00 OP79851 SX2880
Run #2
Initial Volume Final Volume
Run #1 1000 ml 1.0 ml
Run #2
ABN Special List
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 50 10 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.0 0.59 ug/l
95-57-8 2-Chlorophenol ND 5.0 0.63 ug/l
120-83-2 2,4-Dichlorophenol ND 5.0 0.84 ug/l
105-67-9 2,4-Dimethylphenol 1.7 5.0 0.74 ug/l J
51-28-5 2,4-Dinitrophenol ND 25 5.0 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 10 2.0 ug/l
95-48-7 2-Methylphenol ND 5.0 0.56 ug/l
3&4-Methylphenol ND 5.0 0.98 ug/l
88-75-5 2-Nitrophenol ND 5.0 0.85 ug/l
100-02-7 4-Nitrophenol ND 25 5.0 ug/l
87-86-5 Pentachlorophenol ND 25 5.0 ug/l
108-95-2 Phenol 1.4 5.0 0.50 ug/l J
88-06-2 2,4,6-Trichlorophenol ND 5.0 0.75 ug/l
83-32-9 Acenaphthene ND 5.0 0.63 ug/l
208-96-8 Acenaphthylene ND 5.0 0.64 ug/l
120-12-7 Anthracene ND 5.0 0.80 ug/l
56-55-3 Benzo(a)anthracene ND 5.0 0.76 ug/l
50-32-8 Benzo(a)pyrene ND 5.0 0.78 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.0 0.78 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.0 0.82 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.0 0.86 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.0 0.85 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.0 1.0 ug/l
106-47-8 4-Chloroaniline ND 5.0 0.63 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.0 0.81 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.0 0.73 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane) aND 5.0 0.76 ug/l
91-58-7 2-Chloronaphthalene ND 5.0 0.50 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.0 0.54 ug/l
218-01-9 Chrysene ND 5.0 0.85 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.0 0.80 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 2 of 3
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
ABN Special List
CAS No.Compound Result RL MDL Units Q
132-64-9 Dibenzofuran ND 5.0 0.60 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.64 ug/l
84-66-2 Diethyl Phthalate ND 5.0 1.0 ug/l
131-11-3 Dimethyl Phthalate ND 5.0 1.0 ug/l
84-74-2 Di-n-butyl Phthalate ND 5.0 1.0 ug/l
117-84-0 Di-n-octyl Phthalate ND 5.0 1.0 ug/l
121-14-2 2,4-Dinitrotoluene ND 5.0 0.81 ug/l
606-20-2 2,6-Dinitrotoluene ND 5.0 0.71 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 1.0 ug/l
206-44-0 Fluoranthene ND 5.0 0.55 ug/l
86-73-7 Fluorene ND 5.0 0.70 ug/l
118-74-1 Hexachlorobenzene ND 5.0 0.69 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 0.50 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.0 1.8 ug/l
67-72-1 Hexachloroethane ND 5.0 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.0 0.71 ug/l
78-59-1 Isophorone ND 5.0 0.78 ug/l
90-12-0 1-Methylnaphthalene 15.3 5.0 0.53 ug/l
91-57-6 2-Methylnaphthalene 22.9 5.0 0.60 ug/l
91-20-3 Naphthalene 38.6 5.0 0.50 ug/l
98-95-3 Nitrobenzene ND 5.0 0.93 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.0 0.67 ug/l
86-30-6 N-Nitrosodiphenylamine ND 5.0 0.81 ug/l
85-01-8 Phenanthrene ND 5.0 0.86 ug/l
129-00-0 Pyrene ND 5.0 0.68 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 30%14-67%
4165-62-2 Phenol-d5 21%10-50%
118-79-6 2,4,6-Tribromophenol 75%33-118%
4165-60-0 Nitrobenzene-d5 70%42-108%
321-60-8 2-Fluorobiphenyl 74%40-106%
1718-51-0 Terphenyl-d14 73%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
590-36-3 2-Pentanol, 2-methyl-3.05 88 ug/l JN
77-74-7 3-Pentanol, 3-methyl-3.27 23 ug/l JN
108-88-3 Toluene 3.41 57 ug/l JN
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 3 of 3
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:EPA 625.1 SW846 3510C Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
ABN Special List
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
1462-03-9 Cyclopentanol, 1-methyl-3.69 29 ug/l JN
19550-46-0 1,3-Dimethyl cyclopentanol 4.26 33 ug/l JN
100-41-4 Ethylbenzene 4.43 49 ug/l JN
95-47-6 Benzene, 1,2-dimethyl-4.76 21 ug/l JN
496-11-7 Indane 6.13 39 ug/l JN
2039-89-6 Benzene, 2-ethenyl-1,4-dimethyl-7.07 25 ug/l JN
6331-04-0 Acetic acid, (2,4-xylyl)-9.05 21 ug/l JN
Total TIC, Semi-Volatile 385 ug/l J
(a) Associated CCV outside of control limits low.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA7436933.1
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Report of Analysis Page 1 of 1
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:EPA 504.1 EPA 504.1 Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 DD111733.D 1 04/20/20 18:09 KB 04/20/20 12:30 OP79855 GDD3212
Run #2
Initial Volume Final Volume
Run #1 36.9 ml 2.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane a ND 0.019 0.0095 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 116%63-137%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:MADEP VPH REV 1.1 Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1S2336.D 2 04/23/20 16:08 SH n/a n/a G1S22
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 428 2.0 2.0 ug/l
100-41-4 Ethylbenzene 63.8 4.0 2.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 14.9 4.0 2.0 ug/l
91-20-3 Naphthalene 58.8 10 6.0 ug/l
108-88-3 Toluene 92.2 4.0 2.0 ug/l
m,p-Xylene 45.9 8.0 4.0 ug/l
95-47-6 o-Xylene 19.1 4.0 2.0 ug/l
C5- C8 Aliphatics (Unadj.)1690 200 70 ug/l
C9- C12 Aliphatics (Unadj.)212 200 70 ug/l
C9- C10 Aromatics (Unadj.)320 200 70 ug/l
C5- C8 Aliphatics 1150 200 70 ug/l
C9- C12 Aliphatics 83.1 200 70 ug/l J
C9- C10 Aromatics 320 200 70 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 89%70-130%
460-00-4 BFB 93%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Method:MADEP EPH REV 1.1 SW846 3510C Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN028633.D 1 04/28/20 13:42 JA 04/24/20 12:25 OP79920 GNN1388
Run #2
Initial Volume Final Volume
Run #1 980 ml 2.0 ml
Run #2
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.1 2.0 ug/l
208-96-8 Acenaphthylene ND 4.1 2.0 ug/l
120-12-7 Anthracene ND 4.1 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.1 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.1 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.1 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.1 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.1 2.0 ug/l
218-01-9 Chrysene ND 4.1 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.1 2.0 ug/l
206-44-0 Fluoranthene ND 4.1 2.0 ug/l
86-73-7 Fluorene ND 4.1 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.1 2.0 ug/l
91-57-6 2-Methylnaphthalene 18.1 4.1 2.0 ug/l
91-20-3 Naphthalene 36.3 4.1 2.0 ug/l
85-01-8 Phenanthrene ND 4.1 2.0 ug/l
129-00-0 Pyrene ND 4.1 2.0 ug/l
C11-C22 Aromatics (Unadj.)400 200 82 ug/l
C11-C22 Aromatics 346 200 82 ug/l
C9-C18 Aliphatics ND 200 51 ug/l
C19-C36 Aliphatics ND 200 51 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 77%40-140%
580-13-2 2-Bromonaphthalene 78%40-140%
84-15-1 o-Terphenyl 69%40-140%
321-60-8 2-Fluorobiphenyl 63%40-140%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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Report of Analysis Page 1 of 1
Client Sample ID:RW-1
Lab Sample ID:FA74369-1 Date Sampled:04/17/20
Matrix:AQ - Ground Water Date Received:04/18/20
Percent Solids:n/a
Project:Grantham Supply & Super Market; Goldsboro, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead <5.0 5.0 ug/l 1 04/20/20 04/21/20 LM SW846 6010D 1 SW846 3010A 2
(1) Instrument QC Batch: MA16695
(2) Prep QC Batch: MP37122
RL = Reporting Limit
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Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
17 of 54
FA743694
FA74369: Chain of Custody
Page 1 of 3
18 of 54
FA7436944.1
Job Number:FA74369 Client:GRI
Date / Time Received:4/18/2020 11:30:00 AM Delivery Method:FED EX
Project:5370
Airbill #'s:1001893372560003281100100963779715
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (3.5);
Cooler 1: (2.7);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.8; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SHAYLAP Date:Date:4/18/2020 11:30:00 A
FA74369: Chain of Custody
Page 2 of 3
19 of 54
FA7436944.1
TAT (Days):7
Received Date:4/18/2020
Due Date:4/27/2020
Project Description:Grantham Supply & Super Market; Goldsboro, NC
Account Name:GRI (Geological Resources Inc.)
Deliverable:COMMB
CSR:MM
Requested Date:4/20/2020
Job Change Order:FA74369
Sample #:FA74369-1
RW-1
Change:
Per client also report NC oxygenates- XVOXY5NC.Dept:
====================================================================================================================
====================================================================================================================
TAT:7
Above Changes Per:
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Date/Time:4/20/2020 9:26:41 PM
Page 1 of 1
Corey Buchanan
FA74369: Chain of Custody
Page 3 of 3
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MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
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FA743695
Method Blank Summary Page 1 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2722-MB A0222022.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
637-92-3 Ethyl Tert Butyl Ether ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
22 of 54
FA7436955.1.1
Method Blank Summary Page 2 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2722-MB A0222022.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
CAS No.Compound Result RL MDL Units Q
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
75-85-4 Tert-Amyl Alcohol ND 10 2.0 ug/l
994-05-8 Tert-Amyl Methyl Ether ND 1.0 0.20 ug/l
75-65-0 Tert-Butyl Alcohol ND 10 2.0 ug/l
762-75-4 Tert-Butyl Formate ND 10 2.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 102%70-130%
23 of 54
FA7436955.1.1
Method Blank Summary Page 3 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2722-MB A0222022.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
CAS No.Surrogate Recoveries Limits
17060-07-0 1,2-Dichloroethane-D4 108%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
24 of 54
FA7436955.1.1
Blank Spike Summary Page 1 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2722-BS A0222020.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.2 92 70-130
108-86-1 Bromobenzene 10 9.6 96 70-130
74-97-5 Bromochloromethane 10 8.4 84 70-130
75-27-4 Bromodichloromethane 10 9.5 95 70-130
75-25-2 Bromoform 10 9.5 95 70-130
104-51-8 n-Butylbenzene 10 9.7 97 70-130
135-98-8 sec-Butylbenzene 10 9.9 99 70-130
98-06-6 tert-Butylbenzene 10 9.7 97 70-130
56-23-5 Carbon Tetrachloride 10 10.4 104 70-130
108-90-7 Chlorobenzene 10 9.2 92 70-130
75-00-3 Chloroethane 10 8.4 84 60-140
67-66-3 Chloroform 10 9.3 93 70-130
95-49-8 o-Chlorotoluene 10 10.2 102 70-130
106-43-4 p-Chlorotoluene 10 10 100 70-130
124-48-1 Dibromochloromethane 10 9.6 96 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.3 83 70-130
106-93-4 1,2-Dibromoethane 10 9.1 91 70-130
75-71-8 Dichlorodifluoromethane 10 6.3 63 60-140
95-50-1 1,2-Dichlorobenzene 10 9.2 92 70-130
541-73-1 1,3-Dichlorobenzene 10 9.7 97 70-130
106-46-7 1,4-Dichlorobenzene 10 9.5 95 70-130
75-34-3 1,1-Dichloroethane 10 9.4 94 70-130
107-06-2 1,2-Dichloroethane 10 9.1 91 70-130
75-35-4 1,1-Dichloroethylene 10 9.7 97 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.2 92 70-130
156-60-5 trans-1,2-Dichloroethylene 10 9.4 94 70-130
78-87-5 1,2-Dichloropropane 10 9.2 92 70-130
142-28-9 1,3-Dichloropropane 10 9.1 91 70-130
594-20-7 2,2-Dichloropropane 10 10.7 107 70-130
563-58-6 1,1-Dichloropropene 10 10.1 101 70-130
10061-01-5 cis-1,3-Dichloropropene 10 8.8 88 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.5 95 70-130
108-20-3 Di-Isopropyl Ether 10 9.0 90 70-130
100-41-4 Ethylbenzene 10 9.8 98 70-130
637-92-3 Ethyl Tert Butyl Ether 10 7.0 70 70-130
87-68-3 Hexachlorobutadiene 10 9.8 98 70-130
* = Outside of Control Limits.
25 of 54
FA7436955.2.1
Blank Spike Summary Page 2 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2722-BS A0222020.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
98-82-8 Isopropylbenzene 10 9.7 97 70-130
99-87-6 p-Isopropyltoluene 10 9.4 94 70-130
74-83-9 Methyl Bromide 10 8.3 83 60-140
74-87-3 Methyl Chloride 10 8.4 84 60-140
74-95-3 Methylene Bromide 10 9.2 92 70-130
75-09-2 Methylene Chloride 10 8.2 82 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.7 87 70-130
91-20-3 Naphthalene 10 7.6 76 70-130
103-65-1 n-Propylbenzene 10 10.1 101 70-130
100-42-5 Styrene 10 8.7 87 70-130
75-85-4 Tert-Amyl Alcohol 100 96.6 97 70-130
994-05-8 Tert-Amyl Methyl Ether 10 7.4 74 70-130
75-65-0 Tert-Butyl Alcohol 100 109 109 70-130
762-75-4 Tert-Butyl Formate 100 94.3 94 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.5 95 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.4 94 70-130
127-18-4 Tetrachloroethylene 10 10.1 101 70-130
108-88-3 Toluene 10 9.3 93 70-130
87-61-6 1,2,3-Trichlorobenzene 10 8.3 83 70-130
120-82-1 1,2,4-Trichlorobenzene 10 8.5 85 70-130
71-55-6 1,1,1-Trichloroethane 10 10.2 102 70-130
79-00-5 1,1,2-Trichloroethane 10 9.4 94 70-130
79-01-6 Trichloroethylene 10 9.6 96 70-130
75-69-4 Trichlorofluoromethane 10 9.1 91 60-140
96-18-4 1,2,3-Trichloropropane 10 9.3 93 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.0 90 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.5 95 70-130
75-01-4 Vinyl Chloride 10 7.2 72 60-140
m,p-Xylene 20 20.3 102 70-130
95-47-6 o-Xylene 10 9.8 98 70-130
1330-20-7 Xylene (total)30 30.0 100 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
* = Outside of Control Limits.
26 of 54
FA7436955.2.1
Blank Spike Summary Page 3 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2722-BS A0222020.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
CAS No.Surrogate Recoveries BSP Limits
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
* = Outside of Control Limits.
27 of 54
FA7436955.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA74368-1MS A0222027.D 5 04/20/20 AB n/a n/a VA2722
FA74368-1MSD A0222028.D 5 04/20/20 AB n/a n/a VA2722
FA74368-1 A0222024.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
FA74368-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene ND 50 51.0 102 50 55.0 110 8 70-130/20
108-86-1 Bromobenzene ND 50 50.6 101 50 56.2 112 10 70-130/20
74-97-5 Bromochloromethane ND 50 48.5 97 50 52.0 104 7 70-130/20
75-27-4 Bromodichloromethane ND 50 50.8 102 50 56.0 112 10 70-130/20
75-25-2 Bromoform ND 50 47.4 95 50 52.3 105 10 70-130/20
104-51-8 n-Butylbenzene ND 50 51.8 104 50 56.4 113 9 70-130/20
135-98-8 sec-Butylbenzene ND 50 52.9 106 50 57.7 115 9 70-130/20
98-06-6 tert-Butylbenzene ND 50 52.5 105 50 57.4 115 9 70-130/20
56-23-5 Carbon Tetrachloride ND 50 58.4 117 50 63.6 127 9 70-130/20
108-90-7 Chlorobenzene ND 50 50.2 100 50 54.6 109 8 70-130/20
75-00-3 Chloroethane ND 50 47.6 95 50 51.2 102 7 60-140/20
67-66-3 Chloroform ND 50 52.6 105 50 56.2 112 7 70-130/20
95-49-8 o-Chlorotoluene ND 50 55.3 111 50 60.1 120 8 70-130/20
106-43-4 p-Chlorotoluene ND 50 53.2 106 50 58.7 117 10 70-130/20
124-48-1 Dibromochloromethane ND 50 48.7 97 50 53.5 107 9 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 50 46.6 93 50 48.9 98 5 70-130/20
106-93-4 1,2-Dibromoethane ND 50 49.0 98 50 54.5 109 11 70-130/20
75-71-8 Dichlorodifluoromethane ND 50 36.0 72 50 39.1 78 8 60-140/20
95-50-1 1,2-Dichlorobenzene ND 50 50.0 100 50 54.8 110 9 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 51.3 103 50 56.5 113 10 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 49.7 99 50 54.9 110 10 70-130/20
75-34-3 1,1-Dichloroethane ND 50 53.9 108 50 57.1 114 6 70-130/20
107-06-2 1,2-Dichloroethane ND 50 51.8 104 50 56.1 112 8 70-130/20
75-35-4 1,1-Dichloroethylene ND 50 58.7 117 50 61.6 123 5 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 50 51.0 102 50 54.9 110 7 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 50 54.1 108 50 57.3 115 6 70-130/20
78-87-5 1,2-Dichloropropane ND 50 50.3 101 50 55.4 111 10 70-130/20
142-28-9 1,3-Dichloropropane ND 50 47.3 95 50 52.8 106 11 70-130/20
594-20-7 2,2-Dichloropropane ND 50 58.9 118 50 61.2 122 4 70-130/20
563-58-6 1,1-Dichloropropene ND 50 57.4 115 50 62.5 125 9 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 50 43.1 86 50 48.4 97 12 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 50 48.1 96 50 54.1 108 12 70-130/20
108-20-3 Di-Isopropyl Ether ND 50 51.7 103 50 55.6 111 7 70-130/20
100-41-4 Ethylbenzene 0.15 J 50 53.5 107 50 57.9 116 8 70-130/20
637-92-3 Ethyl Tert Butyl Ether ND 50 37.4 75 50 39.6 79 6 70-130/20
87-68-3 Hexachlorobutadiene ND 50 49.6 99 50 53.9 108 8 70-130/20
* = Outside of Control Limits.
28 of 54
FA7436955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA74368-1MS A0222027.D 5 04/20/20 AB n/a n/a VA2722
FA74368-1MSD A0222028.D 5 04/20/20 AB n/a n/a VA2722
FA74368-1 A0222024.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
FA74368-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
98-82-8 Isopropylbenzene ND 50 52.7 105 50 57.1 114 8 70-130/20
99-87-6 p-Isopropyltoluene ND 50 50.6 101 50 55.3 111 9 70-130/20
74-83-9 Methyl Bromide ND 50 46.0 92 50 50.8 102 10 60-140/20
74-87-3 Methyl Chloride ND 50 47.3 95 50 48.7 97 3 60-140/20
74-95-3 Methylene Bromide ND 50 49.8 100 50 54.7 109 9 70-130/20
75-09-2 Methylene Chloride ND 50 48.5 97 50 52.0 104 7 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 50 47.9 96 50 50.8 102 6 70-130/20
91-20-3 Naphthalene ND 50 39.1 78 50 41.9 84 7 70-130/20
103-65-1 n-Propylbenzene ND 50 54.1 108 50 59.3 119 9 70-130/20
100-42-5 Styrene ND 50 46.1 92 50 50.9 102 10 70-130/20
75-85-4 Tert-Amyl Alcohol ND 500 488 98 500 491 98 1 70-130/20
994-05-8 Tert-Amyl Methyl Ether ND 50 37.8 76 50 40.3 81 6 70-130/20
75-65-0 Tert-Butyl Alcohol ND 500 555 111 500 538 108 3 70-130/20
762-75-4 Tert-Butyl Formate ND 500 451 90 500 440 88 2 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 50 52.2 104 50 56.3 113 8 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 50 52.0 104 50 56.4 113 8 70-130/20
127-18-4 Tetrachloroethylene ND 50 55.7 111 50 60.5 121 8 70-130/20
108-88-3 Toluene ND 50 50.0 100 50 54.8 110 9 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 50 42.7 85 50 45.9 92 7 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 50 43.1 86 50 47.5 95 10 70-130/20
71-55-6 1,1,1-Trichloroethane ND 50 57.9 116 50 62.1 124 7 70-130/20
79-00-5 1,1,2-Trichloroethane ND 50 50.1 100 50 54.8 110 9 70-130/20
79-01-6 Trichloroethylene ND 50 53.2 106 50 57.1 114 7 70-130/20
75-69-4 Trichlorofluoromethane ND 50 50.6 101 50 55.2 110 9 60-140/20
96-18-4 1,2,3-Trichloropropane ND 50 50.0 100 50 55.0 110 10 70-130/20
95-63-6 1,2,4-Trimethylbenzene ND 50 49.0 98 50 53.6 107 9 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 50 51.0 102 50 55.9 112 9 70-130/20
75-01-4 Vinyl Chloride ND 50 40.7 81 50 43.9 88 8 60-140/20
m,p-Xylene 0.29 J 100 110 110 100 120 120 9 70-130/20
95-47-6 o-Xylene 0.17 J 50 53.7 107 50 58.0 116 8 70-130/20
1330-20-7 Xylene (total)0.46 J 150 164 109 150 178 118 8 70-130/20
CAS No.Surrogate Recoveries MS MSD FA74368-1 Limits
1868-53-7 Dibromofluoromethane 103%101%105%70-130%
* = Outside of Control Limits.
29 of 54
FA7436955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA74368-1MS A0222027.D 5 04/20/20 AB n/a n/a VA2722
FA74368-1MSD A0222028.D 5 04/20/20 AB n/a n/a VA2722
FA74368-1 A0222024.D 1 04/20/20 AB n/a n/a VA2722
The QC reported here applies to the following samples:Method: SM 6200B
FA74369-1
CAS No.Surrogate Recoveries MS MSD FA74368-1 Limits
17060-07-0 1,2-Dichloroethane-D4 108%107%113%70-130%
2037-26-5 Toluene-D8 100%99%95%70-130%
460-00-4 4-Bromofluorobenzene 98%99%96%70-130%
* = Outside of Control Limits.
30 of 54
FA7436955.3.1
SGS North America Inc.
MS Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
31 of 54
FA743696
Method Blank Summary Page 1 of 2
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79851-MB X070114.D 1 04/21/20 MV 04/20/20 OP79851 SX2880
The QC reported here applies to the following samples:Method: EPA 625.1
FA74369-1
CAS No.Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 50 10 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.0 0.59 ug/l
95-57-8 2-Chlorophenol ND 5.0 0.63 ug/l
120-83-2 2,4-Dichlorophenol ND 5.0 0.84 ug/l
105-67-9 2,4-Dimethylphenol ND 5.0 0.74 ug/l
51-28-5 2,4-Dinitrophenol ND 25 5.0 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 10 2.0 ug/l
95-48-7 2-Methylphenol ND 5.0 0.56 ug/l
3&4-Methylphenol ND 5.0 0.98 ug/l
88-75-5 2-Nitrophenol ND 5.0 0.85 ug/l
100-02-7 4-Nitrophenol ND 25 5.0 ug/l
87-86-5 Pentachlorophenol ND 25 5.0 ug/l
108-95-2 Phenol ND 5.0 0.50 ug/l
88-06-2 2,4,6-Trichlorophenol ND 5.0 0.75 ug/l
83-32-9 Acenaphthene ND 5.0 0.63 ug/l
208-96-8 Acenaphthylene ND 5.0 0.64 ug/l
120-12-7 Anthracene ND 5.0 0.80 ug/l
56-55-3 Benzo(a)anthracene ND 5.0 0.76 ug/l
50-32-8 Benzo(a)pyrene ND 5.0 0.78 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.0 0.78 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.0 0.82 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.0 0.86 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.0 0.85 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.0 1.0 ug/l
106-47-8 4-Chloroaniline ND 5.0 0.63 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.0 0.81 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.0 0.73 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.0 0.76 ug/l
91-58-7 2-Chloronaphthalene ND 5.0 0.50 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.0 0.54 ug/l
218-01-9 Chrysene ND 5.0 0.85 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.0 0.80 ug/l
132-64-9 Dibenzofuran ND 5.0 0.60 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.64 ug/l
84-66-2 Diethyl Phthalate ND 5.0 1.0 ug/l
131-11-3 Dimethyl Phthalate ND 5.0 1.0 ug/l
32 of 54
FA7436966.1.1
Method Blank Summary Page 2 of 2
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79851-MB X070114.D 1 04/21/20 MV 04/20/20 OP79851 SX2880
The QC reported here applies to the following samples:Method: EPA 625.1
FA74369-1
CAS No.Compound Result RL MDL Units Q
84-74-2 Di-n-butyl Phthalate ND 5.0 1.0 ug/l
117-84-0 Di-n-octyl Phthalate ND 5.0 1.0 ug/l
121-14-2 2,4-Dinitrotoluene ND 5.0 0.81 ug/l
606-20-2 2,6-Dinitrotoluene ND 5.0 0.71 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 1.0 ug/l
206-44-0 Fluoranthene ND 5.0 0.55 ug/l
86-73-7 Fluorene ND 5.0 0.70 ug/l
118-74-1 Hexachlorobenzene ND 5.0 0.69 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 0.50 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.0 1.8 ug/l
67-72-1 Hexachloroethane ND 5.0 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.0 0.71 ug/l
78-59-1 Isophorone ND 5.0 0.78 ug/l
90-12-0 1-Methylnaphthalene ND 5.0 0.53 ug/l
91-57-6 2-Methylnaphthalene ND 5.0 0.60 ug/l
91-20-3 Naphthalene ND 5.0 0.50 ug/l
98-95-3 Nitrobenzene ND 5.0 0.93 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.0 0.67 ug/l
86-30-6 N-Nitrosodiphenylamine ND 5.0 0.81 ug/l
85-01-8 Phenanthrene ND 5.0 0.86 ug/l
129-00-0 Pyrene ND 5.0 0.68 ug/l
CAS No.Surrogate Recoveries Limits
367-12-4 2-Fluorophenol 30%14-67%
4165-62-2 Phenol-d5 22%10-50%
118-79-6 2,4,6-Tribromophenol 59%33-118%
4165-60-0 Nitrobenzene-d5 59%42-108%
321-60-8 2-Fluorobiphenyl 60%40-106%
1718-51-0 Terphenyl-d14 60%39-121%
CAS No.Tentatively Identified Compounds R.T.Est. Conc.Units Q
Total TIC, Semi-Volatile 0 ug/l
33 of 54
FA7436966.1.1
Blank Spike Summary Page 1 of 2
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79851-BS a X070113.D 1 04/21/20 MV 04/20/20 OP79851 SX2880
The QC reported here applies to the following samples:Method: EPA 625.1
FA74369-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
65-85-0 Benzoic Acid 100 20.6 21 10-69
59-50-7 4-Chloro-3-methyl Phenol 50 34.3 69 54-103
95-57-8 2-Chlorophenol 50 32.0 64 52-98
120-83-2 2,4-Dichlorophenol 50 39.4 79 53-103
105-67-9 2,4-Dimethylphenol 50 36.1 72 43-90
51-28-5 2,4-Dinitrophenol 100 79.9 80 44-112
534-52-1 4,6-Dinitro-o-cresol 100 84.4 84 66-121
95-48-7 2-Methylphenol 50 25.4 51 43-90
3&4-Methylphenol 100 47.6 48 36-88
88-75-5 2-Nitrophenol 50 42.5 85 53-102
100-02-7 4-Nitrophenol 100 29.5 30 18-62
87-86-5 Pentachlorophenol 100 83.0 83 61-115
108-95-2 Phenol 50 12.9 26 19-56
88-06-2 2,4,6-Trichlorophenol 50 44.4 89 59-107
83-32-9 Acenaphthene 50 40.8 82 61-107
208-96-8 Acenaphthylene 50 43.6 87 60-104
120-12-7 Anthracene 50 40.5 81 65-108
56-55-3 Benzo(a)anthracene 50 42.6 85 66-111
50-32-8 Benzo(a)pyrene 50 42.4 85 62-107
205-99-2 Benzo(b)fluoranthene 50 45.6 91 65-114
191-24-2 Benzo(g,h,i)perylene 50 44.9 90 66-116
207-08-9 Benzo(k)fluoranthene 50 45.4 91 65-114
101-55-3 4-Bromophenyl Phenyl Ether 50 45.9 92 65-109
85-68-7 Butyl Benzyl Phthalate 50 43.4 87 65-112
106-47-8 4-Chloroaniline 50 35.3 71 49-105
111-91-1 bis(2-Chloroethoxy)methane 50 39.3 79 51-102
111-44-4 bis(2-Chloroethyl)ether 50 37.0 74 53-100
108-60-1 2,2'-Oxybis(1-chloropropane)50 30.9 62 45-106
91-58-7 2-Chloronaphthalene 50 41.7 83 57-103
7005-72-3 4-Chlorophenyl Phenyl Ether 50 43.7 87 62-105
218-01-9 Chrysene 50 43.5 87 66-111
53-70-3 Dibenzo(a,h)anthracene 50 41.3 83 66-119
132-64-9 Dibenzofuran 50 42.1 84 61-106
91-94-1 3,3'-Dichlorobenzidine 50 44.1 88 46-117
84-66-2 Diethyl Phthalate 50 42.2 84 64-108
131-11-3 Dimethyl Phthalate 50 42.6 85 63-106
* = Outside of Control Limits.
34 of 54
FA7436966.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79851-BS a X070113.D 1 04/21/20 MV 04/20/20 OP79851 SX2880
The QC reported here applies to the following samples:Method: EPA 625.1
FA74369-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
84-74-2 Di-n-butyl Phthalate 50 43.2 86 65-107
117-84-0 Di-n-octyl Phthalate 50 42.1 84 62-118
121-14-2 2,4-Dinitrotoluene 50 43.3 87 61-110
606-20-2 2,6-Dinitrotoluene 50 42.3 85 63-108
117-81-7 bis(2-Ethylhexyl)phthalate 50 40.6 81 61-117
206-44-0 Fluoranthene 50 42.3 85 63-106
86-73-7 Fluorene 50 42.4 85 62-108
118-74-1 Hexachlorobenzene 50 43.4 87 63-108
87-68-3 Hexachlorobutadiene 50 47.1 94 42-102
77-47-4 Hexachlorocyclopentadiene 50 41.5 83 39-102
67-72-1 Hexachloroethane 50 40.5 81 42-100
193-39-5 Indeno(1,2,3-cd)pyrene 50 41.6 83 64-119
78-59-1 Isophorone 50 36.6 73 43-87
90-12-0 1-Methylnaphthalene 50 39.3 79 53-102
91-57-6 2-Methylnaphthalene 50 41.3 83 51-102
91-20-3 Naphthalene 50 39.9 80 47-100
98-95-3 Nitrobenzene 50 40.1 80 50-104
621-64-7 N-Nitrosodi-n-propylamine 50 35.3 71 52-104
86-30-6 N-Nitrosodiphenylamine 50 41.4 83 64-108
85-01-8 Phenanthrene 50 41.2 82 66-110
129-00-0 Pyrene 50 41.0 82 64-113
CAS No.Surrogate Recoveries BSP Limits
367-12-4 2-Fluorophenol 38%14-67%
4165-62-2 Phenol-d5 26%10-50%
118-79-6 2,4,6-Tribromophenol 79%33-118%
4165-60-0 Nitrobenzene-d5 81%42-108%
321-60-8 2-Fluorobiphenyl 83%40-106%
1718-51-0 Terphenyl-d14 79%39-121%
(a) Insufficient sample for MS/MSD.
* = Outside of Control Limits.
35 of 54
FA7436966.2.1
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 7
36 of 54
FA743697
Method Blank Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S22-MB 1S2331.D 1 04/23/20 SH n/a n/a G1S22
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA74369-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 89%70-130%
460-00-4 BFB 91%70-130%
37 of 54
FA7436977.1.1
Method Blank Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79855-MB DD111731.D 1 04/20/20 KB 04/20/20 OP79855 GDD3212
The QC reported here applies to the following samples:Method: EPA 504.1
FA74369-1
CAS No.Compound Result RL MDL Units Q
106-93-4 1,2-Dibromoethane ND 0.020 0.010 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 110%63-137%
38 of 54
FA7436977.1.2
Blank Spike Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79855-BS DD111730.D 1 04/20/20 KB 04/20/20 OP79855 GDD3212
The QC reported here applies to the following samples:Method: EPA 504.1
FA74369-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
106-93-4 1,2-Dibromoethane 0.25 0.28 112 70-130
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 110%63-137%
* = Outside of Control Limits.
39 of 54
FA7436977.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S22-BS 1S2329.D 1 04/23/20 SH n/a n/a G1S22
G1S22-BSD 1S2330.D 1 04/23/20 SH n/a n/a G1S22
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA74369-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 72.9 91 75.2 94 3 70-130/25
100-41-4 Ethylbenzene 80 75.0 94 77.3 97 3 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 64.9 81 67.6 85 4 70-130/25
91-20-3 Naphthalene 80 69.7 87 71.5 89 3 70-130/25
108-88-3 Toluene 80 74.3 93 76.5 96 3 70-130/25
m,p-Xylene 160 154 96 159 99 3 70-130/25
95-47-6 o-Xylene 80 74.1 93 76.4 96 3 70-130/25
C5- C8 Aliphatics (Unadj.)240 240 100 242 101 1 70-130/25
C9- C12 Aliphatics (Unadj.)160 147 92 161 101 9 70-130/25
C9- C10 Aromatics (Unadj.)80 74.7 93 75.8 95 1 70-130/25
C9- C10 Aromatics 80 74.7 93 75.8 95 1 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 89%87%70-130%
460-00-4 BFB 93%90%70-130%
* = Outside of Control Limits.
40 of 54
FA7436977.3.1
Matrix Spike Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA74420-2MS 1S2338.D 1 04/23/20 SH n/a n/a G1S22
FA74420-2 1S2333.D 1 04/23/20 SH n/a n/a G1S22
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA74369-1
FA74420-2 Spike MS MS
CAS No.Compound ug/l Q ug/l ug/l %Limits
71-43-2 Benzene ND 80 67.7 85 70-130
100-41-4 Ethylbenzene ND 80 71.3 89 70-130
1634-04-4 Methyl Tert Butyl Ether ND 80 66.7 83 70-130
91-20-3 Naphthalene ND 80 68.7 86 70-130
108-88-3 Toluene 2.3 80 71.5 87 70-130
m,p-Xylene ND 160 147 92 70-130
95-47-6 o-Xylene ND 80 71.2 89 70-130
C5- C8 Aliphatics (Unadj.)ND 480 401 84 70-130
C9- C12 Aliphatics (Unadj.)ND 400 462 116 70-130
C9- C10 Aromatics (Unadj.)ND 240 121 50*70-130
C9- C10 Aromatics ND 240 121 50*70-130
CAS No.Surrogate Recoveries MS FA74420-2 Limits
460-00-4 BFB 91%89%70-130%
460-00-4 BFB 93%91%70-130%
* = Outside of Control Limits.
41 of 54
FA7436977.4.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79855-MS DD111734.D 1 04/20/20 KB 04/20/20 OP79855 GDD3212
OP79855-MSD DD111735.D 1 04/20/20 KB 04/20/20 OP79855 GDD3212
FA74338-1 DD111732.D 1 04/20/20 KB 04/20/20 OP79855 GDD3212
The QC reported here applies to the following samples:Method: EPA 504.1
FA74369-1
FA74338-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
106-93-4 1,2-Dibromoethane 0.020 U 0.243 0.30 123 0.239 0.27 113 11 70-130/25
CAS No.Surrogate Recoveries MS MSD FA74338-1 Limits
460-00-4 4-Bromofluorobenzene 121%109%114%63-137%
* = Outside of Control Limits.
42 of 54
FA7436977.5.1
Duplicate Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA74420-2DUP 1S2337.D 1 04/23/20 SH n/a n/a G1S22
FA74420-2 1S2333.D 1 04/23/20 SH n/a n/a G1S22
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA74369-1
FA74420-2 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene 2.3 2.3 0 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA74420-2 Limits
460-00-4 BFB 88%89%70-130%
460-00-4 BFB 89%91%70-130%
* = Outside of Control Limits.
43 of 54
FA7436977.6.1
SGS North America Inc.
GC/LC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 8
44 of 54
FA743698
Method Blank Summary Page 1 of 1
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79920-MB NN028630.D 1 04/28/20 JA 04/24/20 OP79920 GNN1388
The QC reported here applies to the following samples:Method: MADEP EPH REV 1.1
FA74369-1
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.0 2.0 ug/l
208-96-8 Acenaphthylene ND 4.0 2.0 ug/l
120-12-7 Anthracene ND 4.0 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.0 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.0 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.0 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.0 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.0 2.0 ug/l
218-01-9 Chrysene ND 4.0 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.0 2.0 ug/l
206-44-0 Fluoranthene ND 4.0 2.0 ug/l
86-73-7 Fluorene ND 4.0 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.0 2.0 ug/l
91-57-6 2-Methylnaphthalene ND 4.0 2.0 ug/l
91-20-3 Naphthalene ND 4.0 2.0 ug/l
85-01-8 Phenanthrene ND 4.0 2.0 ug/l
129-00-0 Pyrene ND 4.0 2.0 ug/l
C11-C22 Aromatics (Unadj.)ND 200 80 ug/l
C11-C22 Aromatics ND 200 80 ug/l
C9-C18 Aliphatics ND 200 50 ug/l
C19-C36 Aliphatics ND 200 50 ug/l
CAS No.Surrogate Recoveries Limits
3386-33-2 1-Chlorooctadecane 79%40-140%
580-13-2 2-Bromonaphthalene 118%40-140%
84-15-1 o-Terphenyl 73%40-140%
321-60-8 2-Fluorobiphenyl 108%40-140%
45 of 54
FA7436988.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 2
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79920-BS a NN028631.D 1 04/28/20 JA 04/24/20 OP79920 GNN1388
OP79920-BSD a NN028632.D 1 04/28/20 JA 04/24/20 OP79920 GNN1388
The QC reported here applies to the following samples:Method: MADEP EPH REV 1.1
FA74369-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
83-32-9 Acenaphthene 100 67.0 67 61.1 61 9 40-140/30
208-96-8 Acenaphthylene 100 64.2 64 58.8 59 9 40-140/30
120-12-7 Anthracene 100 76.1 76 69.2 69 9 40-140/30
56-55-3 Benzo(a)anthracene 100 84.3 84 77.6 78 8 40-140/30
50-32-8 Benzo(a)pyrene 100 85.2 85 78.3 78 8 40-140/30
205-99-2 Benzo(b)fluoranthene 100 85.1 85 78.4 78 8 40-140/30
191-24-2 Benzo(g,h,i)perylene 100 85.3 85 78.2 78 9 40-140/30
207-08-9 Benzo(k)fluoranthene 100 88.0 88 81.0 81 8 40-140/30
218-01-9 Chrysene 100 86.6 87 79.9 80 8 40-140/30
53-70-3 Dibenzo(a,h)anthracene 100 90.4 90 83.4 83 8 40-140/30
206-44-0 Fluoranthene 100 82.2 82 75.0 75 9 40-140/30
86-73-7 Fluorene 100 70.7 71 64.5 65 9 40-140/30
193-39-5 Indeno(1,2,3-cd)pyrene 100 89.6 90 82.3 82 8 40-140/30
91-57-6 2-Methylnaphthalene 100 56.9 57 51.7 52 10 40-140/30
91-20-3 Naphthalene 100 50.4 50 45.8 46 10 40-140/30
85-01-8 Phenanthrene 100 69.7 70 63.0 63 10 40-140/30
129-00-0 Pyrene 100 83.1 83 75.9 76 9 40-140/30
C11-C22 Aromatics (Unadj.)1700 1360 80 1260 74 8 40-140/30
C11-C22 Aromatics 1700 ND 0*ND 0*nc 50-150/30 b
C9-C18 Aliphatics 600 381 64 353 59 8 40-140/30
C19-C36 Aliphatics 800 703 88 679 85 3 40-140/30
CAS No.Surrogate Recoveries BSP BSD Limits
3386-33-2 1-Chlorooctadecane 38%* c 82%40-140%
580-13-2 2-Bromonaphthalene 67%66%40-140%
84-15-1 o-Terphenyl 76%68%40-140%
321-60-8 2-Fluorobiphenyl 59%58%40-140%
Sample Compound Col #1 Col #2 Breakthrough Limit
OP79920-BS 2-Methylnaphthalene 56.9 ND 0.0%5.0
OP79920-BS Naphthalene 50.4 ND 0.0%5.0
OP79920-BSD 2-Methylnaphthalene 51.7 ND 0.0%5.0
OP79920-BSD Naphthalene 45.8 ND 0.0%5.0
* = Outside of Control Limits.
46 of 54
FA7436988.2.1
Blank Spike/Blank Spike Duplicate Summary Page 2 of 2
Job Number:FA74369
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grantham Supply & Super Market; Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP79920-BS a NN028631.D 1 04/28/20 JA 04/24/20 OP79920 GNN1388
OP79920-BSD a NN028632.D 1 04/28/20 JA 04/24/20 OP79920 GNN1388
The QC reported here applies to the following samples:Method: MADEP EPH REV 1.1
FA74369-1
(a) Insufficient sample for batch duplicate.
(b) Advisory control limits.
(c) Outside control limits.
* = Outside of Control Limits.
47 of 54
FA7436988.2.1
SGS North America Inc.
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Orlando, FL
Section 9
48 of 54
FA743699
BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA74369
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Grantham Supply & Super Market; Goldsboro, NC
QC Batch ID: MP37122 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/20/20
MB
Metal RL IDL MDL raw final
Aluminum 200 14 14
Antimony 6.0 1 1
Arsenic 10 1.3 1.3
Barium 200 1 1
Beryllium 4.0 .2 .2
Cadmium 5.0 .2 .2
Calcium 1000 50 50
Chromium 10 1 1
Cobalt 50 .2 .2
Copper 25 1 1
Iron 300 17 17
Lead 5.0 1 1.1 -0.60 <5.0
Magnesium 5000 35 35
Manganese 15 .5 1
Molybdenum 50 .3 .3
Nickel 40 .4 .4
Potassium 10000 200 200
Selenium 10 2.4 2.9
Silver 10 .7 .7
Sodium 10000 500 500
Strontium 10 .5 .5
Thallium 10 1.1 1.4
Tin 50 .9 1
Titanium 10 .5 1
Vanadium 50 .5 .6
Zinc 20 3 4.4
Associated samples MP37122: FA74369-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
49 of 54
FA7436999.1.1
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA74369
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Grantham Supply & Super Market; Goldsboro, NC
QC Batch ID: MP37122 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/20/20 04/20/20
FA74369-1 QC FA74369-1 Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 0.0 0.0 NC 0-20 0.0 463 500 92.6 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37122: FA74369-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
50 of 54
FA7436999.1.2
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA74369
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Grantham Supply & Super Market; Goldsboro, NC
QC Batch ID: MP37122 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/20/20
FA74369-1 Spikelot MSD QC
Metal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 0.0 462 500 92.4 0.2 20
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37122: FA74369-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 2
51 of 54
FA7436999.1.2
SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA74369
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Grantham Supply & Super Market; Goldsboro, NC
QC Batch ID: MP37122 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/20/20
BSP Spikelot QC
Metal Result MPFLICP2 % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 447 500 89.4 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37122: FA74369-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
52 of 54
FA7436999.1.3
SERIAL DILUTION RESULTS SUMMARY
Login Number: FA74369
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Grantham Supply & Super Market; Goldsboro, NC
QC Batch ID: MP37122 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/20/20
FA74369-1 QC
Metal Original SDL 1:5 %DIF Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 0.00 0.00 NC 0-10
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37122: FA74369-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
53 of 54
FA7436999.1.4
POST DIGESTATE SPIKE SUMMARY
Login Number: FA74369
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Grantham Supply & Super Market; Goldsboro, NC
QC Batch ID: MP37122 Methods: SW846 6010D
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 04/20/20
Sample Final FA74369-1 PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 9.8 10 41.7 0.2 2.5 50 83.4 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP37122: FA74369-1
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
54 of 54
FA7436999.1.5