WA-26862_38040_CA_RPTS_20200219_CLO

UST CLOSURE REPORT

MALLARD FOOD SHOP 17
540 NC-55 EAST, CRAVEN COUNTY, BRIDGETON, NC 28560
FACILITY ID: #00-0-0000002260

NOVEMBER 19, 2019

UST OWNER/OPERATOR:
MALLARD OIL COMPANY
P.O. BOX 1008, KINSTON, NC 28503
PHONE NUMBER: [phone]

PROPERTY OWNER:
MALLARD OIL COMPANY
P.O. BOX 1008, KINSTON, NC 28503
PHONE NUMBER: [phone]

CONSULTANT:
HENRY NEMARGUT ENGINEERING SERVICES, INC.
2211 CHESTNUT STREET, WILMINGTON, NC 28405
PHONE NUMBER: [phone]

UST INFORMATION:
SIZE AND CONTENTS: (1) 12,000 GAL & (1) 8,000 GAL GASOLINE USTs
LATITUDE: N 35.121635o; LONGITUDE: W 77.005443o

The UST Closure Report for this site has been prepared by Henry Nemargut Engineering Services (sole proprietorship) under the direct supervision of a licensed engineer. I certify that the information contained in this report is correct and accurate to the best of my knowledge:
Henry Nemargut, P.E. North Carolina License #17669

February 19, 2020

Mr. Randy Godsell
Mallard Oil Company
P.O. Box 1008
Kinston, NC 28503

Reference: UST Closure Report
Mallard Food Shop 17
540 NC-55 East, Bridgeton, NC 28560
Facility ID#: 00-0-0000002260

Dear Mr. Godsell:

Please find enclosed a report summarizing the Underground Storage Tank (UST) closure for (2)
USTS formerly located at the above referenced facility. The UST Closure consisted of tank
removal, field sampling, and laboratory analyses of the soils and groundwater in the vicinity of
the underground storage tanks. A summary of these activities and our recommendations and
conclusions are contained herein.

In accordance with the North Carolina Administrative code, Title 15A, Chapter 2, Subchapter
2N, this report should be submitted to the Director of the Division of Waste Management. This
report is submitted in accordance with the outline provided in NCDEQ form GW/UST-12. If
you have questions regarding this report, please contact our office.

Sincerely,

Henry Nemargut, P.E.
Henry Nemargut Engineering Services

TABLE OF CONTENTS

Section Page

I. General Information

A. Ownership of USTs 1
B. Facility Information 1
C. Contacts 1
D. UST Information 2
E. Site Characteristics 2

II. Closure Procedures

A. Notification & Tank Preparation 2
B. Residuals 2
C. Tank Excavation 3
D. Contaminated Soil 3

III. Site Investigation

A. Soil Sampling 3
B. Groundwater Sampling 3
C. Quality Control Measures 3
D. Investigation Results 4

IV. Conclusions and Recommendations

A. Conclusions 4
B. Recommendations 4
C. Limitations 4

V. Professional Certification 5

VI. Enclosures

Figures

Figure 1: Project Location
Figure 2: Site Layout and Former UST Locations
Figure 3: Site Layout, Soil Sample Locations, and Soil TPH Map
Figure 4: Site Layout and Monitor Well Location Map

Tables

Table 1: TPH Field and Laboratory Analytical Results - Soil Samples
Table 2: Laboratory Analytical Results - Groundwater Sample

Appendices
Appendix A: Form GW/UST-2
Appendix B: Form GW/UST-3
Appendix C: Geologic Log of Excavation
Appendix D: Laboratory Analytical Reports
Appendix E: Tank/Liquids Disposal Manifests
Page - 1
UST CLOSURE REPORT
Mallard Food Shop 17
540 NC-55 East, Bridgeton, NC 28560
Facility ID#: 00-0-0000002260

I. General Information

A. Ownership

Mallard Oil Company
P.O. Box 1008
Kinston, NC 28503
[phone]

B. Facility Information

Facility: Mallard Food Shop 17
540 NC-55 East, Bridgeton, NC 28560
Facility ID#: 00-0-0000002260

C. Contacts

1. Primary Contact: Randy Godsell, Vice President
Mallard Oil Company
P.O. Box 1008
Kinston, NC 28503
[phone]

2. Closure Contractor: Quint Ocock, Project Manager
HEPACO, LLC
430 Bluff Hill Road
Leland, NC 28251
[phone]

3. Consultant: Henry Nemargut Engineering Services
2211 Chestnut Street, Wilmington, NC 28405
Contact: Henry Nemargut
[phone]

4. Laboratory: Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Huntersville, NC 28078
[phone]
Lab. Cert.: NCDEM #12

Page - 2
D. UST Information

Tank Installation Size Tank Last Previous
No Date (Gal) Dimensions Contents Contents
T1 5/20/1998 8,000 26’ x 8’ Gasoline N/A
T2 5/20/1998 12,000 37’ x 8’ Gasoline N/A

E. Site Characteristics

1. Past Releases: A previous releases has been reported at this facility and is
documented under Incident #38040.

2. Facility/UST Status: This facility is currently in operation as a tobacco &
convenience store. The date of last use for the USTs closed under this contract is 4/7/2017.

3. Surrounding Property Use: Commercial/Residential/Undeveloped

4. Site Geology: Native soils consist of sand, silt and clay of varying proportions.
Bedrock was not encountered. Appendix C contains a geologic log of excavation for this
project.

Other pertinent site information is contained on the GW/UST-2 Site Investigation Form
which is included in Appendix A.

II. Closure Procedures

A. Notification and Tank Preparation

NCDEQ: Henry Nemargut Engineering Services notified the NCDEQ UST Section
of the intent to permanently close by submitting a Notice of Intent: UST Permanent
Closure Form GW/UST-3. A copy of this form is included in Appendix B.

Tank Inerting: The USTs were inerted via interior tank cleaning. A LEL/O2 meter was
used to verify that the USTs were inert.

B. Residuals

Approximately 800 gallons of rinse water/residual gasoline was removed from this UST
system on January 29, 2020. Appendix E contains a disposal manifest for the liquids
disposed of from these USTs and product lines.

C. Excavation

The UST closure project at the Mallard Food Shop 17 facility was initiated on January 29,
2020. Following removal of residual liquids from the product lines and interior cleaning
Page - 3
of the USTs, HEPACO excavated and exhumed the UST #T1 from the ground on that date.
UST #T2 was excavated and removed from the ground on January 30, 2020. Following
removal, the USTs were transported by HEPACO to the New Hanover County landfill in
Wilmington, NC for disposal. Figure 2 illustrates the layout of the project site and the
locations of the UST removed during this closure project. Following removal of the USTs,
the excavation was visually inspected for the presence of free product and groundwater.
Water was observed in the excavation at a depth of 2.5’ to 3’ below grade. Free product
was not present in the UST excavation. Petroleum odors were noted in some soils collected
for confirmatory samples from the southwest perimeter of the UST basin. A tank disposal
manifest is included in Appendix E.

D. Contaminated Soil

Overburden soils removed during excavation activities consisted of pea gravel backfill
which did not exhibit elevated PID readings. All overburden soils removed were placed
back into the UST excavation to bridge over the water table encountered in the UST pit.

III. Site Investigation

A. Field Screening Methods

To evaluate the UST excavation area for the presence of petroleum hydrocarbons, soils
surrounding the USTs were screened utilizing a MiniRae Organic Vapor Meter (PID). The
unit was calibrated prior to use in accordance with manufacturer's recommended
procedures with a 100 parts per million (ppm) calibration gas standard. Samples selected
for field screening were sealed into "Ziploc" type bags, agitated and allowed to equilibrate
for a minimum of 15 minutes in order to obtain a representative value of soil off-gases.

B. Soil Sampling

To confirm site conditions, Henry Nemargut Engineering collected samples from in-situ
soils beneath the former UST in accordance with the NCDEQ "Guidelines for Tank
Closure" prepared by the NCDEQ UST Section. Due to the presence of groundwater in
the UST excavation, soil samples were obtained from the perimeter of the pea gravel filled
tank basin from a hand shovel or backhoe bucket at a depth of approximately 2.5’ below
surface, above the water table observed in the tank pit. Piping and dispenser samples were
obtained at depths of 3’ to 4’ from the native soils encountered beneath the pea gravel
piping bedding.

Confirmatory soil samples were submitted to Pace Analytical, Inc. for analysis according
to TPH-GRO. Figure 3 illustrates the sample locations for TPH soil samples collected
during this closure project.

Page - 4
C. Water Sampling

Per discussions with Allison Ward of the NCDEQ WaRO, a water sample was collected
from existing monitoring well MW-13. The well was developed prior to sampling by
removal of 3 well volumes via hand baling prior to sampling. Groundwater was observed
in MW-13 at a depth of 3.04’ below top of casing prior to development and sampling. The
water sample was submitted to Pace Analytical, Inc. for analyses according to Methods
6200B/Pb/VPH. Figure 4 illustrates the location of well MW-13.

D. Quality Control Measures

All samples were packed into new glass jars provided by the certified laboratory. Each
sample was labeled with sample location, analyses to be performed, time, date and the
sampler's name. They were then placed in a cooler and chilled with ice to approximately
4oC in preparation for transportation to the analytical laboratory, utilizing EPA approved
chain of custody procedures. Water and soil samples were collected on January 30, 2020
and stored at 4oC until they were picked up by the lab courier on February 3, 2020. The
samples were delivered to the lab via Fed-Ex on February 4, 2020.

E. Investigation Results

Analyses from soil samples indicate soils remain in place above NCDEQ Action Levels
for TPH-GRO compounds in the southwestern corner of the tank excavation, with a
maximum TPH-GRO level of 4,090 mg/kg noted in sample W5, near monitoring well MW-
14 which has historically contained floating petroleum liquids. The only other sample at
the site above NCDEQ Action Levels was noted in soil sample P3 which exhibited TPH-
GRO compounds at a concentration of 193 mg/kg.

Results from the groundwater sample from MW-13 were below laboratory detection limits
for all 6200B/Pb/VPH compounds. Appendix D contains the laboratory analytical report
and chain of custody for the samples collected at this project site.

IV. Conclusions and Recommendations

A. Conclusions

The UST closure activities for two regulated USTs at Mallard Food Shop 17 have been
completed. From a review of all information gathered during this removal project, Henry
Nemargut Engineering Services, Inc. makes the following conclusions:

o (1) 8,000 gallon & (1) 12,000 gallon gasoline USTs including liquid contents have
been properly closed at 540 NC-55 East in Bridgeton, NC.

Page - 5

o Analyses from soil samples indicate soils remain in place above NCDEQ Action
Levels for TPH-GRO compounds in the southwestern corner of the tank excavation, with
a maximum TPH-GRO level of 4,090 mg/kg noted in sample W5, near monitoring well
MW-14 which has historically contained floating petroleum liquids. The only other sample
at the site above NCDEQ Action Levels was noted in soil sample P3 which exhibited TPH-
GRO compounds at a concentration of 193 mg/kg.

o Per discussions with Allison Ward of the NCDEQ WaRO, a water sample was
collected from existing monitoring well MW-13. Results from the groundwater sample
from MW-13 were below laboratory detection limits for all 6200B/Pb/VPH compounds.

B. Recommendations

Based upon a review of all information gathered during this UST closure project, Henry
Nemargut Engineering makes the following recommendations in regards to the UST
closure project at this facility:

A copy of this report has been forwarded via email to the following address:

Ms. Allison Ward
NCDEQ – UST Section
943 Washington Square Mall
Washington, NC 27889

C. Limitations

This report has been prepared for the exclusive use of Mallard Oil Company for the specific
application to the referenced site located in Craven County, North Carolina. The
assessment was conducted based on the scope of work and level of effort desired by the
client. Our findings have been developed in accordance with generally accepted standards
in the practice of UST closures in the State of North Carolina, available information and
our professional judgment. No other warranty is expressed or implied. The data presented
in this report are indicative of conditions that existed at the precise locations sampled and
at the time the samples were collected. Additionally, the data obtained from the samples
would be interpreted as meaningful with respect to the parameters indicated in the
laboratory reports. No additional information can be logically inferred from this data.

Page - 6

V. Professional Certification

The UST closure report for this site has been prepared by Henry Nemargut Engineering
Services, Inc. under the direct supervision of a licensed engineer. Technical review of this
document has been provided by Henry Nemargut Engineering, P.E. All engineering work
performed on this project was conducted under my direct supervision:
Henry Nemargut, P.E.
North Carolina License #17669

FIGURES

TABLES

Sample Sample Sample Sample TPH DRO TPH GRO Field PID
ID Location Depth Date Result (ppm) Result (ppm) Result (ppm)
N1 Tank Excavation, North Wall 2.5' 1/30/2020 NR BDL <10
N2 Tank Excavation, North Wall 2.5' 1/30/2020 NR BDL <10
E1 Tank Excavation, East Wall 2.5' 1/30/2020 NR BDL <10
E2 Tank Excavation, East Wall 2.5' 1/30/2020 NR BDL <10
E3 Tank Excavation, East Wall 2.5' 1/30/2020 NR BDL <10
SE Tank Excavation, Southeast Wall 2.5' 1/30/2020 NR BDL <10
S1 Tank Excavation, South Wall 2.5' 1/30/2020 NR 75.5 230
S2 Tank Excavation, South Wall 2.5' 1/30/2020 NR 10.4 80
W1 Tank Excavation, West Wall 2.5' 1/30/2020 NR BDL <10
W2 Tank Excavation, West Wall 2.5' 1/30/2020 NR BDL <10
W3 Tank Excavation, West Wall 2.5' 1/30/2020 NR 253 1230
W4 Tank Excavation, West Wall 2.5' 1/30/2020 NR 4050 2500
W5 Tank Excavation, West Wall 2.5' 1/30/2020 NR 4090 1950
D1 Gasoline MPD Dispenser #1 4' 1/30/2020 NR 16.7 <10
D2 Gasoline MPD Dispenser #2 4' 1/30/2020 NR BDL <10
D3 Gasoline MPD Dispenser #3 4' 1/30/2020 NR BDL <10
D4 Gasoline MPD Dispenser #4 4' 1/30/2020 NR BDL <10
P1 Product Piping 3' 1/30/2020 NR 13.4 45
P2 Product Piping 3' 1/30/2020 NR BDL <10
P3 Product Piping 3' 1/30/2020 NR 193 340
P4 Product Piping 3' 1/30/2020 NR BDL <10
P5 Product Piping 3' 1/30/2020 NR BDL <10
P6 Product Piping 3' 1/30/2020 NR BDL <10
NR = Analyses not requested N/A = not analyzed <100 = below NCDEQ DRO action level
<50 = below NCDEQ GRO action level
TABLE 1: SUMMARY OF TPH SOIL ANALYTICAL AND FIELD SCREENING RESULTS
Mallard Food Shop 17, 540 NC-55 E, Bridgeton, NC 28560
Constituent MW-13 GCL 2L Standard

Date 1/30/2020
Standard Method 602 (ug/L)
Benzene BDL 5,000 1
Toluene BDL 260,000 600
Ethylbenzene BDL 84,500 600
Xylenes (total) BDL 85,500 500
BTEX (total) 0 NSE NSE
p-Isopropyltoluene BDL NSE NSE
Isopropylbenzene BDL 25,000 70
Diisopropyl Ether (DIPE) BDL 70,000 70
Naphthalene BDL 6,000 6
n-propylbenzene BDL 30,000 70
n-butylbenzene BDL 6,900 70
sec-butylbenzene BDL 8,500 70
Carbon Tetrachloride BDL NSE 0.3
Chloroform BDL 70,000 70
cis-1,2-Dichloroethene BDL 70,000 70
Tetrachloroethene BDL 700 1
Methyl-tert-butyl-ether (MTBE) BDL 20,000 20
1,2,4-Trimethylbenzene BDL 28,500 400
1,3,5-Trimethylbenzene BDL 25,000 400
Lead BDL 15,000 15
Method 625 (ug/L)
Acenaphthene NR 2,120 80
Naphthalene NR 6,000 6
1-Methylnaphthalene NR 1,000 1
2-Methylnaphthalene NR 125,000 30
TOTAL TICs NR NSE NSE
MADEP Aliphatic Fraction Classes (ug/L)
C5-C8 Volatile Aliphatics BDL NSE 400
C9-C12 Volatile Aliphatics BDL NSE NSE
C9-C18 Extractable Aliphatics NR NSE 700
C9-C18 Aliphatics (total) BDL NSE 700
C19-C36 Extractable Aliphatics NR NSE 10,000
MADEP Aromatic Fraction Classes (ug/L)
C9-C10 Volatile Aromatics BDL NSE NSE
C11-C22 Extractable Aromatics NR NSE NSE
C9-C22 Aromatics (total) BDL NSE 200
NR = Analyses Not Requested
BDL = Below Detection Limits
NSE = No Standard Established
TABLE 2
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
Mallard Food Shop 17
540 NC-55 East, Bridgeton, NC 28560

APPENDIX A

GW/UST-2

APPENDIX B

GW/UST-3

APPENDIX C

GEOLOGIC LOG OF EXCAVATION

SOIL BORING LOG
Henry Nemargut Engineering Services
Job Name: Mallard Food Shop 17
Address: 540 NC-55 E, Bridgeton, NC 28560
Job No.:
Start Date: 1/30/2020
Contractor: HEPACO, LLC
Sample ID: UST Closure Samples
Comments:

Sample Depth OVA
Number (FT.) Soil Decription (color, soil type, moisture) (ppm)
N1 2.5'dark-brown, Sand w/silt <10
N2 2.5'dark-brown, Sand w/silt <10
E1 2.5'dark gray-brown, Sand w/some silt <10
E2 2.5'dark gray-brown, Sand w/some silt <10
E3 2.5'dark gray-brown, Sand w/some silt <10
SE 2.5'darkgray, Sand w/some silt <10
S1 2.5'dark gray-black, Sand w/some silt 230
S2 2.5'dark gray-black, Sand w/some silt 80
W1 2.5'dark burgandy-brown, Sand w/some silt <10
W2 2.5'black, Sand w/silt <10
W3 2.5'dark burgandy-brown, Sand w/some silt 1230
W4 2.5'dark gray-brown, Sand w/some silt 2500
W5 2.5'dark gray-black, Sand w/some silt 1950
D1 4'gray, Sand w/silt & some clay <10
D2 4'med gray, Sand w/silt <10
D3 4'gray, Sand w/silt <10
D4 4'gray, Sand w/silt & some clay <10
P1 3'dark-brown, Sand w/silt 45
P2 3'dark-brown, Sand w/silt <10
P3 3'dark gray, Sand w/silt 340
P4 3'dark-brown, Sand w/silt <10
P5 3'dark gray, Sand w/silt <10
P6 3'dark gray, Sand w/silt <10

APPENDIX D

LABORATORY ANALYTICAL RESULTS
#=CL#
February 11, 2020
LIMS USE: FR - HENRY NEMARGUT
LIMS OBJECT ID: 92463493
92463493
Project:
Pace Project No.:
RE:
Henry Nemargut
Henry Nemargut Engineering
2211 Chestnut Street
Wilmington, NC 28405
Mallard Food Shop 17
Dear Henry Nemargut:
Enclosed are the analytical results for sample(s) received by the laboratory on February 04, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 52
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 52
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Lab ID Sample ID Matrix Date Collected Date Received
92463493001 N1 Solid 01/30/20 11:00 02/04/20 12:14
92463493002 N2 Solid 01/30/20 11:05 02/04/20 12:14
92463493003 E1 Solid 01/30/20 11:15 02/04/20 12:14
92463493004 E2 Solid 01/30/20 11:20 02/04/20 12:14
92463493005 E3 Solid 01/30/20 11:30 02/04/20 12:14
92463493006 SE Solid 01/30/20 11:45 02/04/20 12:14
92463493007 S1 Solid 01/30/20 12:00 02/04/20 12:14
92463493008 S2 Solid 01/30/20 12:10 02/04/20 12:14
92463493009 W1 Solid 01/30/20 12:50 02/04/20 12:14
92463493010 W2 Solid 01/30/20 12:55 02/04/20 12:14
92463493011 W3 Solid 01/30/20 13:05 02/04/20 12:14
92463493012 W4 Solid 01/30/20 13:15 02/04/20 12:14
92463493013 W5 Solid 01/30/20 13:25 02/04/20 12:14
92463493014 D1 Solid 01/30/20 14:10 02/04/20 12:14
92463493015 D2 Solid 01/30/20 14:25 02/04/20 12:14
92463493016 D3 Solid 01/30/20 14:40 02/04/20 12:14
92463493017 D4 Solid 01/30/20 15:00 02/04/20 12:14
92463493018 P1 Solid 01/30/20 15:30 02/04/20 12:14
92463493019 P2 Solid 01/30/20 15:55 02/04/20 12:14
92463493020 P3 Solid 01/30/20 16:20 02/04/20 12:14
92463493021 P4 Solid 01/30/20 16:40 02/04/20 12:14
92463493022 P5 Solid 01/30/20 17:00 02/04/20 12:14
92463493023 P6 Solid 01/30/20 17:20 02/04/20 12:14
92463493024 MW-13 Water 01/30/20 18:40 02/04/20 12:14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 52
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92463493001 N1 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493002 N2 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493003 E1 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493004 E2 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493005 E3 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493006 SE EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493007 S1 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493008 S2 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493009 W1 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493010 W2 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493011 W3 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493012 W4 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493013 W5 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493014 D1 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493015 D2 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493016 D3 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493017 D4 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493018 P1 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493019 P2 EPA 8015C Modified 2 PASI-CMAD
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 52
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
ASTM D2974-87 1 PASI-CKDF
92463493020 P3 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493021 P4 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493022 P5 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493023 P6 EPA 8015C Modified 2 PASI-CMAD
ASTM D2974-87 1 PASI-CKDF
92463493024 MW-13 MADEP VPH 6 PASI-CLMB
EPA 6010D 1 PASI-ADS
SM 6200B 68 PASI-CCL
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 52
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92463493001 N1
Percent Moisture 16.6 %02/04/20 16:530.10ASTM D2974-87
92463493002 N2
Percent Moisture 26.4 %02/04/20 16:540.10ASTM D2974-87
92463493003 E1
Percent Moisture 23.3 %02/04/20 16:540.10ASTM D2974-87
92463493004 E2
Percent Moisture 15.3 %02/04/20 16:540.10ASTM D2974-87
92463493005 E3
Percent Moisture 13.8 %02/04/20 16:540.10ASTM D2974-87
92463493006 SE
Percent Moisture 16.2 %02/04/20 16:540.10ASTM D2974-87
92463493007 S1
Gas Range Organics (C6-C10)75.5 mg/kg 02/06/20 05:025.2EPA 8015C Modified
Percent Moisture 12.8 %02/04/20 16:540.10ASTM D2974-87
92463493008 S2
Gas Range Organics (C6-C10)10.4 mg/kg 02/06/20 02:428.3EPA 8015C Modified
Percent Moisture 24.2 %02/04/20 16:540.10ASTM D2974-87
92463493009 W1
Percent Moisture 18.3 %02/04/20 16:550.10ASTM D2974-87
92463493010 W2
Percent Moisture 16.6 %02/04/20 16:550.10ASTM D2974-87
92463493011 W3
Gas Range Organics (C6-C10)253 mg/kg 02/06/20 04:067.5EPA 8015C Modified
Percent Moisture 10.8 %02/04/20 16:550.10ASTM D2974-87
92463493012 W4
Gas Range Organics (C6-C10)4050 mg/kg 02/08/20 07:1677.5EPA 8015C Modified
Percent Moisture 13.5 %02/04/20 16:550.10ASTM D2974-87
92463493013 W5
Gas Range Organics (C6-C10)4090 mg/kg 02/08/20 07:44136EPA 8015C Modified
Percent Moisture 16.0 %02/04/20 16:550.10ASTM D2974-87
92463493014 D1
Gas Range Organics (C6-C10)16.7 mg/kg 02/10/20 16:559.7EPA 8015C Modified
Percent Moisture 30.4 %02/04/20 16:550.10ASTM D2974-87
92463493015 D2
Percent Moisture 16.7 %02/04/20 16:550.10ASTM D2974-87
92463493016 D3
Percent Moisture 19.8 %02/04/20 16:550.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 52
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92463493017 D4
Percent Moisture 12.2 %02/04/20 16:550.10ASTM D2974-87
92463493018 P1
Gas Range Organics (C6-C10)13.4 mg/kg 02/08/20 01:385.9EPA 8015C Modified
Percent Moisture 18.7 %02/04/20 16:560.10ASTM D2974-87
92463493019 P2
Percent Moisture 14.0 %02/04/20 16:560.10ASTM D2974-87
92463493020 P3
Gas Range Organics (C6-C10)193 mg/kg 02/08/20 02:345.4EPA 8015C Modified
Percent Moisture 15.2 %02/04/20 16:560.10ASTM D2974-87
92463493021 P4
Percent Moisture 12.8 %02/05/20 12:390.10ASTM D2974-87
92463493022 P5
Percent Moisture 16.4 %02/05/20 12:390.10ASTM D2974-87
92463493023 P6
Percent Moisture 18.0 %02/05/20 12:390.10ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: N1 Lab ID: 92463493001 Collected: 01/30/20 11:00 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/05/20 23:5002/05/20 13:355.9 1
Surrogates
4-Bromofluorobenzene (S)117 %02/05/20 23:50 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.6 %02/04/20 16:530.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: N2 Lab ID: 92463493002 Collected: 01/30/20 11:05 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/06/20 00:1902/05/20 13:357.6 1
Surrogates
4-Bromofluorobenzene (S)112 %02/06/20 00:19 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 26.4 %02/04/20 16:540.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: E1 Lab ID: 92463493003 Collected: 01/30/20 11:15 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/06/20 00:4902/05/20 13:357.7 1
Surrogates
4-Bromofluorobenzene (S)114 %02/06/20 00:49 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 23.3 %02/04/20 16:540.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: E2 Lab ID: 92463493004 Collected: 01/30/20 11:20 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/06/20 01:1702/05/20 13:357.5 1
Surrogates
4-Bromofluorobenzene (S)105 %02/06/20 01:17 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.3 %02/04/20 16:540.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: E3 Lab ID: 92463493005 Collected: 01/30/20 11:30 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/06/20 01:4502/05/20 13:355.3 1
Surrogates
4-Bromofluorobenzene (S)106 %02/06/20 01:45 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.8 %02/04/20 16:540.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: SE Lab ID: 92463493006 Collected: 01/30/20 11:45 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/06/20 02:1302/05/20 13:356.6 1
Surrogates
4-Bromofluorobenzene (S)102 %02/06/20 02:13 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.2 %02/04/20 16:540.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: S1 Lab ID: 92463493007 Collected: 01/30/20 12:00 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)75.5 mg/kg 02/06/20 05:0202/05/20 13:355.2 1
Surrogates
4-Bromofluorobenzene (S)274 %02/06/20 05:02 460-00-4 S502/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 12.8 %02/04/20 16:540.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: S2 Lab ID: 92463493008 Collected: 01/30/20 12:10 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)10.4 mg/kg 02/06/20 02:4202/05/20 13:358.3 1
Surrogates
4-Bromofluorobenzene (S)126 %02/06/20 02:42 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 24.2 %02/04/20 16:540.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: W1 Lab ID: 92463493009 Collected: 01/30/20 12:50 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/06/20 03:1002/05/20 13:356.5 1
Surrogates
4-Bromofluorobenzene (S)108 %02/06/20 03:10 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 18.3 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: W2 Lab ID: 92463493010 Collected: 01/30/20 12:55 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/06/20 03:3802/05/20 13:358.0 1
Surrogates
4-Bromofluorobenzene (S)103 %02/06/20 03:38 460-00-402/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.6 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: W3 Lab ID: 92463493011 Collected: 01/30/20 13:05 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)253 mg/kg 02/06/20 04:0602/05/20 13:357.5 1
Surrogates
4-Bromofluorobenzene (S)237 %02/06/20 04:06 460-00-4 S502/05/20 13:3563-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 10.8 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: W4 Lab ID: 92463493012 Collected: 01/30/20 13:15 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)4050 mg/kg 02/08/20 07:1602/06/20 13:0377.5 12.5
Surrogates
4-Bromofluorobenzene (S)133 %02/08/20 07:16 460-00-4 S202/06/20 13:0363-130 12.5
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.5 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: W5 Lab ID: 92463493013 Collected: 01/30/20 13:25 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)4090 mg/kg 02/08/20 07:4402/06/20 13:03136 20
Surrogates
4-Bromofluorobenzene (S)98 %02/08/20 07:44 460-00-402/06/20 13:0363-130 20
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.0 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: D1 Lab ID: 92463493014 Collected: 01/30/20 14:10 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)16.7 mg/kg 02/10/20 16:5502/10/20 15:169.7 1
Surrogates
4-Bromofluorobenzene (S)99 %02/10/20 16:55 460-00-402/10/20 15:1663-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 30.4 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: D2 Lab ID: 92463493015 Collected: 01/30/20 14:25 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/08/20 00:1302/06/20 13:046.8 1
Surrogates
4-Bromofluorobenzene (S)91 %02/08/20 00:13 460-00-402/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.7 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: D3 Lab ID: 92463493016 Collected: 01/30/20 14:40 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/08/20 00:4102/06/20 13:046.1 1
Surrogates
4-Bromofluorobenzene (S)89 %02/08/20 00:41 460-00-402/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 19.8 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: D4 Lab ID: 92463493017 Collected: 01/30/20 15:00 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/08/20 01:1002/06/20 13:044.7 1
Surrogates
4-Bromofluorobenzene (S)91 %02/08/20 01:10 460-00-402/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 12.2 %02/04/20 16:550.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: P1 Lab ID: 92463493018 Collected: 01/30/20 15:30 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)13.4 mg/kg 02/08/20 01:3802/06/20 13:045.9 1
Surrogates
4-Bromofluorobenzene (S)98 %02/08/20 01:38 460-00-402/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 18.7 %02/04/20 16:560.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: P2 Lab ID: 92463493019 Collected: 01/30/20 15:55 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/08/20 02:0602/06/20 13:046.3 1
Surrogates
4-Bromofluorobenzene (S)89 %02/08/20 02:06 460-00-402/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 14.0 %02/04/20 16:560.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: P3 Lab ID: 92463493020 Collected: 01/30/20 16:20 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)193 mg/kg 02/08/20 02:3402/06/20 13:045.4 1
Surrogates
4-Bromofluorobenzene (S)181 %02/08/20 02:34 460-00-4 S502/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.2 %02/04/20 16:560.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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9800 Kincey Ave. Suite 100
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Page 27 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: P4 Lab ID: 92463493021 Collected: 01/30/20 16:40 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/10/20 17:2402/10/20 15:166.2 1
Surrogates
4-Bromofluorobenzene (S)97 %02/10/20 17:24 460-00-402/10/20 15:1663-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 12.8 %02/05/20 12:390.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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9800 Kincey Ave. Suite 100
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Page 28 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: P5 Lab ID: 92463493022 Collected: 01/30/20 17:00 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/08/20 03:3002/06/20 13:045.8 1
Surrogates
4-Bromofluorobenzene (S)95 %02/08/20 03:30 460-00-402/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 16.4 %02/05/20 12:390.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: P6 Lab ID: 92463493023 Collected: 01/30/20 17:20 Received: 02/04/20 12:14 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8015C Modified Preparation Method: EPA 5030BGasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 02/08/20 03:5902/06/20 13:048.2 1
Surrogates
4-Bromofluorobenzene (S)91 %02/08/20 03:59 460-00-402/06/20 13:0463-130 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 18.0 %02/05/20 12:390.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: MW-13 Lab ID: 92463493024 Collected: 01/30/20 18:40 Received: 02/04/20 12:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP VPHVPH NC Water
Aliphatic (C05-C08)ND ug/L 02/04/20 20:34 N250.0 1
Aliphatic (C09-C12)ND ug/L 02/04/20 20:34 N250.0 1
Aliphatic(C09-C12) Adjusted ND ug/L 02/04/20 20:34 N250.0 1
Aromatic (C09-C10)ND ug/L 02/04/20 20:34 N250.0 1
Surrogates
4-Bromofluorobenzene (FID) (S)96 %02/04/20 20:34 460-00-470-130 1
4-Bromofluorobenzene (PID) (S)98 %02/04/20 20:34 460-00-470-130 1
Analytical Method: EPA 6010D Preparation Method: EPA 3010A6010 MET ICP
Lead ND ug/L 02/09/20 19:17 7439-92-102/07/20 02:025.0 1
Analytical Method: SM 6200B6200B MSV
tert-Amyl Alcohol ND ug/L 02/08/20 18:23 75-85-42500 25
tert-Amylmethyl ether ND ug/L 02/08/20 18:23 994-05-8250 25
Benzene ND ug/L 02/08/20 18:23 71-43-212.5 25
Bromobenzene ND ug/L 02/08/20 18:23 108-86-112.5 25
Bromochloromethane ND ug/L 02/08/20 18:23 74-97-512.5 25
Bromodichloromethane ND ug/L 02/08/20 18:23 75-27-412.5 25
Bromoform ND ug/L 02/08/20 18:23 75-25-212.5 25
Bromomethane ND ug/L 02/08/20 18:23 74-83-9125 25
tert-Butyl Alcohol ND ug/L 02/08/20 18:23 75-65-0500 25
n-Butylbenzene ND ug/L 02/08/20 18:23 104-51-812.5 25
sec-Butylbenzene ND ug/L 02/08/20 18:23 135-98-812.5 25
tert-Butylbenzene ND ug/L 02/08/20 18:23 98-06-612.5 25
tert-Butyl Formate ND ug/L 02/08/20 18:23 762-75-4500 25
Carbon tetrachloride ND ug/L 02/08/20 18:23 56-23-512.5 25
Chlorobenzene ND ug/L 02/08/20 18:23 108-90-712.5 25
Chloroethane ND ug/L 02/08/20 18:23 75-00-325.0 25
Chloroform ND ug/L 02/08/20 18:23 67-66-312.5 25
Chloromethane ND ug/L 02/08/20 18:23 74-87-325.0 25
2-Chlorotoluene ND ug/L 02/08/20 18:23 95-49-812.5 25
4-Chlorotoluene ND ug/L 02/08/20 18:23 106-43-412.5 25
1,2-Dibromo-3-chloropropane ND ug/L 02/08/20 18:23 96-12-825.0 25
Dibromochloromethane ND ug/L 02/08/20 18:23 124-48-112.5 25
1,2-Dibromoethane (EDB)ND ug/L 02/08/20 18:23 106-93-412.5 25
Dibromomethane ND ug/L 02/08/20 18:23 74-95-312.5 25
1,2-Dichlorobenzene ND ug/L 02/08/20 18:23 95-50-112.5 25
1,3-Dichlorobenzene ND ug/L 02/08/20 18:23 541-73-112.5 25
1,4-Dichlorobenzene ND ug/L 02/08/20 18:23 106-46-712.5 25
Dichlorodifluoromethane ND ug/L 02/08/20 18:23 75-71-812.5 25
1,1-Dichloroethane ND ug/L 02/08/20 18:23 75-34-312.5 25
1,2-Dichloroethane ND ug/L 02/08/20 18:23 107-06-212.5 25
1,1-Dichloroethene ND ug/L 02/08/20 18:23 75-35-412.5 25
cis-1,2-Dichloroethene ND ug/L 02/08/20 18:23 156-59-212.5 25
trans-1,2-Dichloroethene ND ug/L 02/08/20 18:23 156-60-512.5 25
1,2-Dichloropropane ND ug/L 02/08/20 18:23 78-87-512.5 25
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Sample: MW-13 Lab ID: 92463493024 Collected: 01/30/20 18:40 Received: 02/04/20 12:14 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
1,3-Dichloropropane ND ug/L 02/08/20 18:23 142-28-912.5 25
2,2-Dichloropropane ND ug/L 02/08/20 18:23 594-20-712.5 25
1,1-Dichloropropene ND ug/L 02/08/20 18:23 563-58-612.5 25
cis-1,3-Dichloropropene ND ug/L 02/08/20 18:23 10061-01-512.5 25
trans-1,3-Dichloropropene ND ug/L 02/08/20 18:23 10061-02-612.5 25
Diisopropyl ether ND ug/L 02/08/20 18:23 108-20-312.5 25
Ethanol ND ug/L 02/08/20 18:23 64-17-55000 25
Ethylbenzene ND ug/L 02/08/20 18:23 100-41-412.5 25
Hexachloro-1,3-butadiene ND ug/L 02/08/20 18:23 87-68-350.0 25
Isopropylbenzene (Cumene)ND ug/L 02/08/20 18:23 98-82-812.5 25
Methylene Chloride ND ug/L 02/08/20 18:23 75-09-250.0 25
Methyl-tert-butyl ether ND ug/L 02/08/20 18:23 1634-04-412.5 25
Naphthalene ND ug/L 02/08/20 18:23 91-20-350.0 25
n-Propylbenzene ND ug/L 02/08/20 18:23 103-65-112.5 25
Styrene ND ug/L 02/08/20 18:23 100-42-512.5 25
1,1,1,2-Tetrachloroethane ND ug/L 02/08/20 18:23 630-20-612.5 25
1,1,2,2-Tetrachloroethane ND ug/L 02/08/20 18:23 79-34-512.5 25
Tetrachloroethene ND ug/L 02/08/20 18:23 127-18-412.5 25
Toluene ND ug/L 02/08/20 18:23 108-88-312.5 25
1,2,3-Trichlorobenzene ND ug/L 02/08/20 18:23 87-61-650.0 25
1,2,4-Trichlorobenzene ND ug/L 02/08/20 18:23 120-82-150.0 25
1,1,1-Trichloroethane ND ug/L 02/08/20 18:23 71-55-612.5 25
1,1,2-Trichloroethane ND ug/L 02/08/20 18:23 79-00-512.5 25
Trichloroethene ND ug/L 02/08/20 18:23 79-01-612.5 25
Trichlorofluoromethane ND ug/L 02/08/20 18:23 75-69-425.0 25
1,2,3-Trichloropropane ND ug/L 02/08/20 18:23 96-18-412.5 25
1,2,4-Trimethylbenzene ND ug/L 02/08/20 18:23 95-63-612.5 25
1,3,5-Trimethylbenzene ND ug/L 02/08/20 18:23 108-67-812.5 25
Vinyl chloride ND ug/L 02/08/20 18:23 75-01-425.0 25
m&p-Xylene ND ug/L 02/08/20 18:23 179601-23-125.0 25
o-Xylene ND ug/L 02/08/20 18:23 95-47-612.5 25
Surrogates
1,2-Dichloroethane-d4 (S)101 %02/08/20 18:23 17060-07-070-130 25
4-Bromofluorobenzene (S)104 %02/08/20 18:23 460-00-470-130 25
Toluene-d8 (S)101 %02/08/20 18:23 2037-26-570-130 25
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
523381
EPA 5030B
EPA 8015C Modified
Gasoline Range Organics
Associated Lab Samples:92463493001, 92463493002, 92463493003, 92463493004, 92463493005, 92463493006, 92463493007,
92463493008, 92463493009, 92463493010, 92463493011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2798573
Associated Lab Samples: 92463493001, 92463493002, 92463493003, 92463493004, 92463493005, 92463493006, 92463493007,
92463493008, 92463493009, 92463493010, 92463493011
Matrix: Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 02/05/20 15:01
4-Bromofluorobenzene (S)%108 63-130 02/05/20 15:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2798574LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 46.050.2 92 70-130
4-Bromofluorobenzene (S)%105 63-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2798576MATRIX SPIKE SAMPLE:
MSSpike
Result
92463460002
Gas Range Organics (C6-C10)mg/kg 10556.3 138 40-15527.5
4-Bromofluorobenzene (S)%107 63-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92463460001
2798575SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%119117
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
523685
EPA 5030B
EPA 8015C Modified
Gasoline Range Organics
Associated Lab Samples:92463493012, 92463493013, 92463493015, 92463493016, 92463493017, 92463493018, 92463493019,
92463493020, 92463493022, 92463493023
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2799832
Associated Lab Samples: 92463493012, 92463493013, 92463493015, 92463493016, 92463493017, 92463493018, 92463493019,
92463493020, 92463493022, 92463493023
Matrix: Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 02/07/20 22:49
4-Bromofluorobenzene (S)%92 63-130 02/07/20 22:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2799833LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 50.749.7 102 70-130
4-Bromofluorobenzene (S)%92 63-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2802327MATRIX SPIKE SAMPLE:
MSSpike
Result
92463493017
Gas Range Organics (C6-C10)mg/kg 46.039.2 115 40-155ND
4-Bromofluorobenzene (S)%98 63-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92463493016
2802326SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%10189
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
524254
EPA 5030B
EPA 8015C Modified
Gasoline Range Organics
Associated Lab Samples: 92463493014, 92463493021
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2802749
Associated Lab Samples:92463493014, 92463493021
Matrix: Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 02/10/20 15:02
4-Bromofluorobenzene (S)%94 63-130 02/10/20 15:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2802750LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 48.750.4 97 70-130
4-Bromofluorobenzene (S)%95 63-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2802752MATRIX SPIKE SAMPLE:
MSSpike
Result
92463493021
Gas Range Organics (C6-C10)mg/kg 61.752.1 117 40-155ND
4-Bromofluorobenzene (S)%94 63-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92463537007
2802870SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30<6.0
4-Bromofluorobenzene (S)%10098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
523188
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples: 92463493024
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2797772
Associated Lab Samples:92463493024
Matrix: Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N202/04/20 19:06
Aliphatic (C09-C12)ug/L ND 50.0 N202/04/20 19:06
Aromatic (C09-C10)ug/L ND 50.0 N202/04/20 19:06
4-Bromofluorobenzene (FID) (S)%93 70-130 02/04/20 19:06
4-Bromofluorobenzene (PID) (S)%97 70-130 02/04/20 19:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2797773LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2797774
Aliphatic (C05-C08)ug/L 328 N230010970-130109326 0 25
Aliphatic (C09-C12)ug/L 309 N230010330-130103310 0 25
Aromatic (C09-C10)ug/L 102 N210010270-130101101 1 25
4-Bromofluorobenzene (FID) (S)%93 70-13093
4-Bromofluorobenzene (PID) (S)%97 70-13096
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
523803
EPA 3010A
EPA 6010D
6010 MET
Associated Lab Samples: 92463493024
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2800565
Associated Lab Samples:92463493024
Matrix: Water
Analyzed
Lead ug/L ND 5.0 02/09/20 19:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2800566LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 488500 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2800567MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92463493024
2800568
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Lead ug/L 500 101 75-125101 0 20500ND506 507
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
523925
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92463493024
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2800845
Associated Lab Samples:92463493024
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/08/20 10:47
1,1,1-Trichloroethane ug/L ND 0.50 02/08/20 10:47
1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/08/20 10:47
1,1,2-Trichloroethane ug/L ND 0.50 02/08/20 10:47
1,1-Dichloroethane ug/L ND 0.50 02/08/20 10:47
1,1-Dichloroethene ug/L ND 0.50 02/08/20 10:47
1,1-Dichloropropene ug/L ND 0.50 02/08/20 10:47
1,2,3-Trichlorobenzene ug/L ND 2.0 02/08/20 10:47
1,2,3-Trichloropropane ug/L ND 0.50 02/08/20 10:47
1,2,4-Trichlorobenzene ug/L ND 2.0 02/08/20 10:47
1,2,4-Trimethylbenzene ug/L ND 0.50 02/08/20 10:47
1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/08/20 10:47
1,2-Dibromoethane (EDB)ug/L ND 0.50 02/08/20 10:47
1,2-Dichlorobenzene ug/L ND 0.50 02/08/20 10:47
1,2-Dichloroethane ug/L ND 0.50 02/08/20 10:47
1,2-Dichloropropane ug/L ND 0.50 02/08/20 10:47
1,3,5-Trimethylbenzene ug/L ND 0.50 02/08/20 10:47
1,3-Dichlorobenzene ug/L ND 0.50 02/08/20 10:47
1,3-Dichloropropane ug/L ND 0.50 02/08/20 10:47
1,4-Dichlorobenzene ug/L ND 0.50 02/08/20 10:47
2,2-Dichloropropane ug/L ND 0.50 02/08/20 10:47
2-Chlorotoluene ug/L ND 0.50 02/08/20 10:47
4-Chlorotoluene ug/L ND 0.50 02/08/20 10:47
Benzene ug/L ND 0.50 02/08/20 10:47
Bromobenzene ug/L ND 0.50 02/08/20 10:47
Bromochloromethane ug/L ND 0.50 02/08/20 10:47
Bromodichloromethane ug/L ND 0.50 02/08/20 10:47
Bromoform ug/L ND 0.50 02/08/20 10:47
Bromomethane ug/L ND 5.0 02/08/20 10:47
Carbon tetrachloride ug/L ND 0.50 02/08/20 10:47
Chlorobenzene ug/L ND 0.50 02/08/20 10:47
Chloroethane ug/L ND 1.0 02/08/20 10:47
Chloroform ug/L ND 0.50 02/08/20 10:47
Chloromethane ug/L ND 1.0 02/08/20 10:47
cis-1,2-Dichloroethene ug/L ND 0.50 02/08/20 10:47
cis-1,3-Dichloropropene ug/L ND 0.50 02/08/20 10:47
Dibromochloromethane ug/L ND 0.50 02/08/20 10:47
Dibromomethane ug/L ND 0.50 02/08/20 10:47
Dichlorodifluoromethane ug/L ND 0.50 02/08/20 10:47
Diisopropyl ether ug/L ND 0.50 02/08/20 10:47
Ethanol ug/L ND 200 02/08/20 10:47
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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Page 38 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2800845
Associated Lab Samples:92463493024
Matrix: Water
Analyzed
Ethylbenzene ug/L ND 0.50 02/08/20 10:47
Hexachloro-1,3-butadiene ug/L ND 2.0 02/08/20 10:47
Isopropylbenzene (Cumene)ug/L ND 0.50 02/08/20 10:47
m&p-Xylene ug/L ND 1.0 02/08/20 10:47
Methyl-tert-butyl ether ug/L ND 0.50 02/08/20 10:47
Methylene Chloride ug/L ND 2.0 02/08/20 10:47
n-Butylbenzene ug/L ND 0.50 02/08/20 10:47
n-Propylbenzene ug/L ND 0.50 02/08/20 10:47
Naphthalene ug/L ND 2.0 02/08/20 10:47
o-Xylene ug/L ND 0.50 02/08/20 10:47
sec-Butylbenzene ug/L ND 0.50 02/08/20 10:47
Styrene ug/L ND 0.50 02/08/20 10:47
tert-Amyl Alcohol ug/L ND 100 02/08/20 10:47
tert-Amylmethyl ether ug/L ND 10.0 02/08/20 10:47
tert-Butyl Alcohol ug/L ND 20.0 02/08/20 10:47
tert-Butyl Formate ug/L ND 20.0 02/08/20 10:47
tert-Butylbenzene ug/L ND 0.50 02/08/20 10:47
Tetrachloroethene ug/L ND 0.50 02/08/20 10:47
Toluene ug/L ND 0.50 02/08/20 10:47
trans-1,2-Dichloroethene ug/L ND 0.50 02/08/20 10:47
trans-1,3-Dichloropropene ug/L ND 0.50 02/08/20 10:47
Trichloroethene ug/L ND 0.50 02/08/20 10:47
Trichlorofluoromethane ug/L ND 1.0 02/08/20 10:47
Vinyl chloride ug/L ND 1.0 02/08/20 10:47
1,2-Dichloroethane-d4 (S)%96 70-130 02/08/20 10:47
4-Bromofluorobenzene (S)%100 70-130 02/08/20 10:47
Toluene-d8 (S)%110 70-130 02/08/20 10:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2800846LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 53.850 108 60-140
1,1,1-Trichloroethane ug/L 52.750 105 60-140
1,1,2,2-Tetrachloroethane ug/L 52.650 105 60-140
1,1,2-Trichloroethane ug/L 52.650 105 60-140
1,1-Dichloroethane ug/L 50.850 102 60-140
1,1-Dichloroethene ug/L 50.850 102 60-140
1,1-Dichloropropene ug/L 53.650 107 60-140
1,2,3-Trichlorobenzene ug/L 51.350 103 60-140
1,2,3-Trichloropropane ug/L 56.850 114 60-140
1,2,4-Trichlorobenzene ug/L 52.050 104 60-140
1,2,4-Trimethylbenzene ug/L 49.350 99 60-140
1,2-Dibromo-3-chloropropane ug/L 56.150 112 60-140
1,2-Dibromoethane (EDB)ug/L 53.150 106 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 39 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2800846LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/L 50.950 102 60-140
1,2-Dichloroethane ug/L 46.950 94 60-140
1,2-Dichloropropane ug/L 51.150 102 60-140
1,3,5-Trimethylbenzene ug/L 49.450 99 60-140
1,3-Dichlorobenzene ug/L 52.450 105 60-140
1,3-Dichloropropane ug/L 51.450 103 60-140
1,4-Dichlorobenzene ug/L 49.150 98 60-140
2,2-Dichloropropane ug/L 57.650 115 60-140
2-Chlorotoluene ug/L 49.650 99 60-140
4-Chlorotoluene ug/L 50.350 101 60-140
Benzene ug/L 49.550 99 60-140
Bromobenzene ug/L 50.850 102 60-140
Bromochloromethane ug/L 57.450 115 60-140
Bromodichloromethane ug/L 50.750 101 60-140
Bromoform ug/L 48.150 96 60-140
Bromomethane ug/L 45.250 90 60-140
Carbon tetrachloride ug/L 52.050 104 60-140
Chlorobenzene ug/L 49.550 99 60-140
Chloroethane ug/L 45.250 90 60-140
Chloroform ug/L 52.250 104 60-140
Chloromethane ug/L 39.450 79 60-140
cis-1,2-Dichloroethene ug/L 50.350 101 60-140
cis-1,3-Dichloropropene ug/L 54.050 108 60-140
Dibromochloromethane ug/L 55.350 111 60-140
Dibromomethane ug/L 51.850 104 60-140
Dichlorodifluoromethane ug/L 50.850 102 60-140
Diisopropyl ether ug/L 51.550 103 60-140
Ethanol ug/L 19702000 99 60-140
Ethylbenzene ug/L 47.850 96 60-140
Hexachloro-1,3-butadiene ug/L 51.950 104 60-140
Isopropylbenzene (Cumene)ug/L 50.750 101 60-140
m&p-Xylene ug/L 97.6100 98 60-140
Methyl-tert-butyl ether ug/L 51.550 103 60-140
Methylene Chloride ug/L 47.550 95 60-140
n-Butylbenzene ug/L 51.150 102 60-140
n-Propylbenzene ug/L 49.950 100 60-140
Naphthalene ug/L 51.550 103 60-140
o-Xylene ug/L 49.250 98 60-140
sec-Butylbenzene ug/L 50.650 101 60-140
Styrene ug/L 51.750 103 60-140
tert-Amyl Alcohol ug/L 9421000 94 60-140
tert-Amylmethyl ether ug/L 98.7100 99 60-140
tert-Butyl Alcohol ug/L 432500 86 60-140
tert-Butyl Formate ug/L 493400 123 60-140
tert-Butylbenzene ug/L 40.850 82 60-140
Tetrachloroethene ug/L 48.750 97 60-140
Toluene ug/L 46.850 94 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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Huntersville, NC 28078
[phone]
Page 40 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2800846LABORATORY CONTROL SAMPLE:
LCSSpike
trans-1,2-Dichloroethene ug/L 51.050 102 60-140
trans-1,3-Dichloropropene ug/L 48.150 96 60-140
Trichloroethene ug/L 48.950 98 60-140
Trichlorofluoromethane ug/L 48.950 98 60-140
Vinyl chloride ug/L 56.150 112 60-140
1,2-Dichloroethane-d4 (S)%106 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2800847MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92463205001
2800848
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 108 60-140112 3 3020ND21.7 22.3
1,1,1-Trichloroethane ug/L 20 108 60-140108 0 3020ND21.6 21.6
1,1,2,2-Tetrachloroethane ug/L 20 108 60-140109 0 3020ND21.7 21.8
1,1,2-Trichloroethane ug/L 20 111 60-140111 0 3020ND22.2 22.2
1,1-Dichloroethane ug/L 20 103 60-140102 1 3020ND20.6 20.3
1,1-Dichloroethene ug/L 20 106 60-140107 1 3020ND21.1 21.3
1,1-Dichloropropene ug/L 20 108 60-140111 3 3020ND21.6 22.2
1,2,3-Trichlorobenzene ug/L 20 100 60-140104 4 3020ND20.0 20.8
1,2,3-Trichloropropane ug/L 20 116 60-140116 0 3020ND23.2 23.2
1,2,4-Trichlorobenzene ug/L 20 99 60-140103 4 3020ND19.8 20.6
1,2,4-Trimethylbenzene ug/L 20 102 60-140106 4 3020ND20.4 21.2
1,2-Dibromo-3-
chloropropane ug/L 20 113 60-140113 0 3020ND22.7 22.6
1,2-Dibromoethane (EDB) ug/L 20 106 60-140107 1 3020ND21.2 21.4
1,2-Dichlorobenzene ug/L 20 105 60-140107 2 3020ND20.9 21.3
1,2-Dichloroethane ug/L 20 96 60-14096 0 3020ND19.2 19.2
1,2-Dichloropropane ug/L 20 108 60-140109 1 3020ND21.5 21.8
1,3,5-Trimethylbenzene ug/L 20 101 60-140106 5 3020ND20.2 21.3
1,3-Dichlorobenzene ug/L 20 107 60-140111 3 3020ND21.5 22.2
1,3-Dichloropropane ug/L 20 104 60-140103 1 3020ND20.8 20.6
1,4-Dichlorobenzene ug/L 20 101 60-140105 4 3020ND20.2 21.0
2,2-Dichloropropane ug/L 20 91 60-14085 7 3020ND18.1 17.0
2-Chlorotoluene ug/L 20 103 60-140108 5 3020ND20.5 21.6
4-Chlorotoluene ug/L 20 105 60-140108 3 3020ND21.0 21.7
Benzene ug/L 20 107 60-140109 1 3020ND21.4 21.7
Bromobenzene ug/L 20 105 60-140110 4 3020ND21.0 21.9
Bromochloromethane ug/L 20 112 60-140110 2 3020ND22.4 22.1
Bromodichloromethane ug/L 20 106 60-140105 1 3020ND21.2 21.1
Bromoform ug/L 20 94 60-14094 0 3020ND18.8 18.8
Bromomethane ug/L 20 88 60-14080 10 3020ND17.6 15.9
Carbon tetrachloride ug/L 20 113 60-140114 1 3020ND22.6 22.9
Chlorobenzene ug/L 20 104 60-140107 3 3020ND20.9 21.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2800847MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92463205001
2800848
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloroethane ug/L 20 112 60-140111 0 3020ND22.4 22.3
Chloroform ug/L 20 107 60-140107 0 3020ND21.3 21.4
Chloromethane ug/L 20 79 60-14078 2 3020ND15.8 15.5
cis-1,2-Dichloroethene ug/L 20 102 60-140103 1 3020ND20.3 20.6
cis-1,3-Dichloropropene ug/L 20 107 60-140106 1 3020ND21.3 21.2
Dibromochloromethane ug/L 20 108 60-140109 1 3020ND21.6 21.8
Dibromomethane ug/L 20 111 60-140111 0 3020ND22.2 22.2
Dichlorodifluoromethane ug/L 20 103 60-140104 0 3020ND20.7 20.8
Diisopropyl ether ug/L 20 102 60-140105 3 3020ND20.4 21.1
Ethanol ug/L 800 109 60-140105 4 30800ND870 837
Ethylbenzene ug/L 20 103 60-140106 3 3020ND20.6 21.2
Hexachloro-1,3-butadiene ug/L 20 99 60-140103 4 3020ND19.8 20.5
Isopropylbenzene
(Cumene)ug/L 20 110 60-140111 1 3020ND22.0 22.2
m&p-Xylene ug/L 40 106 60-140106 1 3040ND42.3 42.5
Methyl-tert-butyl ether ug/L 20 104 60-140105 1 30201.3 22.2 22.3
Methylene Chloride ug/L 20 100 60-14097 3 3020ND20.0 19.4
n-Butylbenzene ug/L 20 99 60-140104 5 3020ND19.8 20.8
n-Propylbenzene ug/L 20 102 60-140107 4 3020ND20.4 21.4
Naphthalene ug/L 20 103 60-140104 1 3020ND20.6 20.7
o-Xylene ug/L 20 105 60-140106 0 3020ND21.0 21.1
sec-Butylbenzene ug/L 20 103 60-140108 4 3020ND20.7 21.6
Styrene ug/L 20 106 60-140105 1 3020ND21.2 21.1
tert-Amyl Alcohol ug/L 400 116 60-140113 3 30400ND465 451
tert-Amylmethyl ether ug/L 40 104 60-140107 2 3040ND41.8 42.7
tert-Butyl Alcohol ug/L 200 140 60-140126 11 30200ND280 251
tert-Butyl Formate ug/L P5160 0 60-140030160ND ND ND
tert-Butylbenzene ug/L 20 85 60-14088 4 3020ND 17.0 17.6
Tetrachloroethene ug/L 20 101 60-140105 4 3020ND 20.2 20.9
Toluene ug/L 20 104 60-140108 3 3020ND 20.8 21.5
trans-1,2-Dichloroethene ug/L 20 103 60-140103 0 3020ND 20.5 20.6
trans-1,3-Dichloropropene ug/L 20 94 60-14091 2 3020ND 18.7 18.3
Trichloroethene ug/L 20 105 60-140107 2 3020ND 20.9 21.4
Trichlorofluoromethane ug/L 20 104 60-140105 1 3020ND 20.8 21.0
Vinyl chloride ug/L 20 117 60-140116 1 3020ND 23.5 23.3
1,2-Dichloroethane-d4 (S) % 101 70-13098
4-Bromofluorobenzene (S) % 103 70-13099
Toluene-d8 (S) % 101 70-130101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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Huntersville, NC 28078
[phone]
Page 42 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
523184
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92463493001, 92463493002, 92463493003, 92463493004, 92463493005, 92463493006, 92463493007,
92463493008, 92463493009, 92463493010, 92463493011, 92463493012, 92463493013, 92463493014,
92463493015, 92463493016, 92463493017, 92463493018, 92463493019, 92463493020
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92463493001
2797708SAMPLE DUPLICATE:
Percent Moisture %16.9 2 2516.6
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92463493020
2797709SAMPLE DUPLICATE:
Percent Moisture %16.0 5 2515.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
523369
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples: 92463493021, 92463493022, 92463493023
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92463493021
2798501SAMPLE DUPLICATE:
Percent Moisture %13.3 4 2512.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92463579072
2798502SAMPLE DUPLICATE:
Percent Moisture %15.2 9 2513.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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Huntersville, NC 28078
[phone]
Page 44 of 52
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.P5
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample
re-analysis).S2
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 52
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92463493001 523381 523404N1EPA 5030B EPA 8015C Modified
92463493002 523381 523404N2EPA 5030B EPA 8015C Modified
92463493003 523381 523404E1EPA 5030B EPA 8015C Modified
92463493004 523381 523404E2EPA 5030B EPA 8015C Modified
92463493005 523381 523404E3EPA 5030B EPA 8015C Modified
92463493006 523381 523404SEEPA 5030B EPA 8015C Modified
92463493007 523381 523404S1EPA 5030B EPA 8015C Modified
92463493008 523381 523404S2EPA 5030B EPA 8015C Modified
92463493009 523381 523404W1EPA 5030B EPA 8015C Modified
92463493010 523381 523404W2EPA 5030B EPA 8015C Modified
92463493011 523381 523404W3EPA 5030B EPA 8015C Modified
92463493012 523685 523711W4EPA 5030B EPA 8015C Modified
92463493013 523685 523711W5EPA 5030B EPA 8015C Modified
92463493014 524254 524285D1EPA 5030B EPA 8015C Modified
92463493015 523685 523711D2EPA 5030B EPA 8015C Modified
92463493016 523685 523711D3EPA 5030B EPA 8015C Modified
92463493017 523685 523711D4EPA 5030B EPA 8015C Modified
92463493018 523685 523711P1EPA 5030B EPA 8015C Modified
92463493019 523685 523711P2EPA 5030B EPA 8015C Modified
92463493020 523685 523711P3EPA 5030B EPA 8015C Modified
92463493021 524254 524285P4EPA 5030B EPA 8015C Modified
92463493022 523685 523711P5EPA 5030B EPA 8015C Modified
92463493023 523685 523711P6EPA 5030B EPA 8015C Modified
92463493024 523188MW-13 MADEP VPH
92463493024 523803 523834MW-13 EPA 3010A EPA 6010D
92463493024 523925MW-13 SM 6200B
92463493001 523184N1ASTM D2974-87
92463493002 523184N2ASTM D2974-87
92463493003 523184E1ASTM D2974-87
92463493004 523184E2ASTM D2974-87
92463493005 523184E3ASTM D2974-87
92463493006 523184SEASTM D2974-87
92463493007 523184S1ASTM D2974-87
92463493008 523184S2ASTM D2974-87
92463493009 523184W1ASTM D2974-87
92463493010 523184W2ASTM D2974-87
92463493011 523184W3ASTM D2974-87
92463493012 523184W4ASTM D2974-87
92463493013 523184W5ASTM D2974-87
92463493014 523184D1ASTM D2974-87
92463493015 523184D2ASTM D2974-87
92463493016 523184D3ASTM D2974-87
92463493017 523184D4ASTM D2974-87
92463493018 523184P1ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 52
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92463493
Mallard Food Shop 17
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92463493019 523184P2ASTM D2974-87
92463493020 523184P3ASTM D2974-87
92463493021 523369P4ASTM D2974-87
92463493022 523369P5ASTM D2974-87
92463493023 523369P6ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/11/2020 04:05 PM
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Huntersville, NC 28078
[phone]
Page 47 of 52
Page 48 of 52
Page 49 of 52
Page 50 of 52
Page 51 of 52
Page 52 of 52

APPENDIX E

TANK/LIQUIDS DISPOSAL MANIFEST