WA-18083_18083_CA_RPTS_20160726

July 26, 2016

Ms. Sylvia Newsom-Hunneke North Carolina Department of Environmental Quality Division of Waste Management – Underground Storage Tank Section Washington Regional Office
943 Washington Square Mall,
Washington, North Carolina 27889
Re: Results of Soil Sampling
Former Munchie Mart (Handy Mart #59)
3920 US Highway 70 East
New Bern, Craven County, North Carolina NCDENR Incident #18083
ATC Project No. EJP107P01

Dear Ms. Hunneke:
On behalf of E.J. Pope & Son, Inc. (Pope), ATC Associates of North Carolina, P.C. (ATC) is pleased
to submit the results of the soil sampling activities conducted at the above refenced site on June 3,
2016, as directed in the Notice of Regualtory Requirements (NORR) letter dated December 9, 2015.

Background
Pope has been performing groundwater monitoring at the site, most recently on an annual basis, since
1999 to track the progress of restoration of groundwater quality by natural attenuation. Monitored
natural attenuation (MNA) was the groundwater remedial approach specified in the Corrective Action
Plan (CAP) dated November 13, 1998 and approved by the North Carolina Division of Waste Management, Underground Storage Tank Section (NC UST Section) on January 8, 1999. As outlined
in the October 8, 2015 “Groundwater Monitoring Report” prepared by Cardno MM&A,
concentrations of targeted petroleum constituents in groundwater had reduced to below 15A NCAC
2L groundwater quality standards.
Subsequent to review of the October 8, 2015 report, the NC UST Section issued the above-referenced
NORR. The NORR stated that historical analysis of soil samples, previously collected in 1998,
indicated impacted soils remained at the site with levels of total petroleum hydrocarbons (TPH)
exceeding 10 parts per million (ppm). However, the historical soil samples were collected at depths
of 3-4 feet (ft) below ground surface (bgs). Groundwater level data collected during several subsequent sampling events, indicated that these samples were collected in the saturated soil. The
NORR stated that in order to qualify for “No Further Action”, soil sampling would need to be
performed in the unsaturated zone in the area where the highest TPH concentrations were detected in
1998.

SITE MAP

THURMAN ROAD SR #1116 (20' PAVEMENT)GRASS
S
R

#
1
9
6
0

(
2
0
'

P
A
V
E
M
E
N
T
)
CANOPY
GRASS
KEROSENE UST
GRASS
ASPHALT
ASPHALT
ASPHALT
CONCRETE PAD
AST CONTAINMENT AREA
3" BLOCK WALL
18" CONCRETEUNDERGROUNDCULVERT
WATERMETER
6' WOODFENCE
PL
CONCRETEPAD
TELEPHONE
SHOPPING CENTER
MARTFORMER MUNCHIE
x
x
x
x
x
x
x x
xxÒA
ÒA
ÒA
ÒA
ÒA
ÒA
§ÒA
ÒA
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ÒA
ÒA
ÒA
MW10
MW3
MW2
MW8
MW9
DW1
MW5
MW7
MW4
MW1
MW6
MW11
E.J. POPE & SON, INC.FORMER MUNCHIE MART #5NEW BERN, CRAVEN COUNTY, NC
SITE MAP
DM
EMC
LR
4/4/2013
XE122 Fig 2 - Site Map.mxd
XE122
RALEIGH
1 " = 50 '
NO. DATE REVISION
50 0 50'
1 " = 50 '
N
DESIGNED:
DRAWN:
CHECKED:
DATE:
SCALE:
FILE NO.:
PROJECT NO.:
OFFICE LOC.:
'FIGURE #2
LEGEND
ÒA TYPE II MONITORING WELL
§ÒA TYPE III MONITORING WELL
ÒA TYPE II MONITORING WELL - SUSPECTED DESTROYED
APPROXIMATE PROPERTY LINE
DISPENSER
LIGHT POST
1 4/3/2013 - add two tanks to ast containment area, nw corner

LABORAOTRY ANALYTICAL RESULTS

Report Number:31601092
Client Project:Handy Mart 59
Laboratory Report of Analysis
Larry George
ATC Group Services, LLC
2725 E. Millbrook Road
Suite 121
Raleigh, NC 27604
To:
Dear Larry George,
Enclosed are the results of the analytical services performed under the referenced project for the received
samples and associated QC as applicable. The samples analyzed at the SGS Wilmington location are certified to
meet the requirements of the National Environmental Laboratory Accreditation Conference Standards, unless
otherwise noted. Copies of this report and supporting data will be retained in our files for a period of five years in
the event they are required for future reference. All results are intended to be used in their entirety and SGS is not
responsible for use of less than the complete report. Any samples submitted to our laboratory will be retained for a
maximum of thirty (30) days from the date of this report unless other arrangements are requested.
If there are any questions about the report or services performed during this project, please call Michael D. Page
at [phone]. We will be happy to answer any questions or concerns which you may have.
Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you
again on any additional analytical needs.
Sincerely,
SGS North America Inc.
__________________________________________________________________
Michael D. Page Date
Project Manager
[e-mail]
Print Date: 06/14/2016 N.C. Certification # 481
Terms and Conditions:
All services are rendered in accordance with the applicable SGS General Conditions of Service accessible via:
http://www.sgs.com/terms_and_conditions.htm
Page 1 of 25
Laboratory Qualifiers
Report Definitions
DL Method, Instrument, or Estimated Detection Limit per Analytical Method
CL Control Limits for the recovery result of a parameter
LOQ Reporting Limit
DF Dilution Factor
RPD Relative Percent Difference
LCS(D)Laboratory Control Spike (Duplicate)
MS(D)Matrix Spike (Duplicate)
MB Method Blank
Qualifier Definitions
*Recovery or RPD outside of control limits
B Analyte was detected in the Lab Method Blank at a level above the LOQ
U Undetected (Reported as ND or < DL)
J Estimated Concentration.
E Amount detected is greater than the Upper Calibration Limit
TIC Tentatively Identified Compound
ND Not Detected
P RPD > 40% between results of dual columns
D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration
range
Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A
code definition is provided below:
M1 Mis-identified peak
M2 Software did not integrate peak
M3 Incorrect baseline construction (i.e. not all of peak included; two peaks integrated as one)
M4 Pattern integration required (i.e. DRO, GRO, PCB, Toxaphene and Technical Chlordane)
M5 Other - Explained in case narrative
Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content.
Print Date: 06/14/2016 N.C. Certification # 481
Page 2 of 25
Sample Summary
Client Sample ID Lab Sample ID Collected Received Matrix
HA-1 - 1.5-2.0ft 31601092001 06/03/2016 11:30 06/03/2016 14:01 Soil-Solid as dry weight
Trip Blank 31601092002 06/03/2016 14:01 Soil-Solid as received
Print Date: 06/14/2016 N.C. Certification # 481
Page 3 of 25
Case Narrative
HA-1 - 1.5-2.0ft(202068MS)
8260B - VMS4012: Low analyte recoveries due to sample matrix interaction.
Print Date: 06/14/2016 N.C. Certification # 481
Page 4 of 25
Detectable Results Summary
Client Sample ID: HA-1 - 1.5-2.0ft
Lab Sample ID: 31601092001-A UnitsParameterResult
Benzene ug/KgSW-846 8260B 20.2
Print Date: 06/14/2016 N.C. Certification # 481
Page 5 of 25
Client Sample ID: HA-1 - 1.5-2.0ft
Client Project ID: Handy Mart 59
Lab Sample ID: 31601092001-A
Lab Project ID: 31601092
Collection Date: 06/03/2016 11:30
Received Date: 06/03/2016 14:01
Matrix: Soil-Solid as dry weight
Solids (%): 80.60
LOQ/CLResultQual Units DFParameter
Results by SW-846 8260B
Results of HA-1 - 1.5-2.0ft
Date Analyzed
1,1,1,2-Tetrachloroethane ND ug/Kg 14.53 06/6/2016 17:27
1,1,1-Trichloroethane ND ug/Kg 14.53 06/6/2016 17:27
1,1,2,2-Tetrachloroethane ND ug/Kg 14.53 06/6/2016 17:27
1,1,2-Trichloroethane ND ug/Kg 14.53 06/6/2016 17:27
1,1-Dichloroethane ND ug/Kg 14.53 06/6/2016 17:27
1,1-Dichloroethene ND ug/Kg 14.53 06/6/2016 17:27
1,1-Dichloropropene ND ug/Kg 14.53 06/6/2016 17:27
1,2,3-Trichlorobenzene ND ug/Kg 14.53 06/6/2016 17:27
1,2,3-Trichloropropane ND ug/Kg 14.53 06/6/2016 17:27
1,2,4-Trichlorobenzene ND ug/Kg 14.53 06/6/2016 17:27
1,2,4-Trimethylbenzene ND ug/Kg 14.53 06/6/2016 17:27
1,2-Dibromo-3-chloropropane ND ug/Kg 127.2 06/6/2016 17:27
1,2-Dibromoethane ND ug/Kg 14.53 06/6/2016 17:27
1,2-Dichlorobenzene ND ug/Kg 14.53 06/6/2016 17:27
1,2-Dichloroethane ND ug/Kg 14.53 06/6/2016 17:27
1,2-Dichloropropane ND ug/Kg 14.53 06/6/2016 17:27
1,3,5-Trimethylbenzene ND ug/Kg 14.53 06/6/2016 17:27
1,3-Dichlorobenzene ND ug/Kg 14.53 06/6/2016 17:27
1,3-Dichloropropane ND ug/Kg 14.53 06/6/2016 17:27
1,4-Dichlorobenzene ND ug/Kg 14.53 06/6/2016 17:27
2,2-Dichloropropane ND ug/Kg 14.53 06/6/2016 17:27
2-Butanone ND ug/Kg 122.6 06/6/2016 17:27
2-Chlorotoluene ND ug/Kg 14.53 06/6/2016 17:27
2-Hexanone ND ug/Kg 111.3 06/6/2016 17:27
4-Chlorotoluene ND ug/Kg 14.53 06/6/2016 17:27
4-Isopropyltoluene ND ug/Kg 14.53 06/6/2016 17:27
4-Methyl-2-pentanone ND ug/Kg 111.3 06/6/2016 17:27
Acetone ND ug/Kg 145.3 06/6/2016 17:27
Benzene 20.2 ug/Kg 14.53 06/6/2016 17:27
Bromobenzene ND ug/Kg 14.53 06/6/2016 17:27
Bromochloromethane ND ug/Kg 14.53 06/6/2016 17:27
Bromoform ND ug/Kg 14.53 06/6/2016 17:27
Bromomethane ND ug/Kg 14.53 06/6/2016 17:27
n-Butylbenzene ND ug/Kg 14.53 06/6/2016 17:27
Carbon disulfide ND ug/Kg 14.53 06/6/2016 17:27
Carbon tetrachloride ND ug/Kg 14.53 06/6/2016 17:27
Chlorobenzene ND ug/Kg 14.53 06/6/2016 17:27
Chlorodibromomethane ND ug/Kg 14.53 06/6/2016 17:27
Chloroethane ND ug/Kg 14.53 06/6/2016 17:27
Chloroform ND ug/Kg 14.53 06/6/2016 17:27
Chloromethane ND ug/Kg 14.53 06/6/2016 17:27
Dibromomethane ND ug/Kg 14.53 06/6/2016 17:27
Print Date: 06/14/2016 N.C. Certification # 481
Page 6 of 25
Client Sample ID: HA-1 - 1.5-2.0ft
Client Project ID: Handy Mart 59
Lab Sample ID: 31601092001-A
Lab Project ID: 31601092
Collection Date: 06/03/2016 11:30
Received Date: 06/03/2016 14:01
Matrix: Soil-Solid as dry weight
Solids (%): 80.60
LOQ/CLResultQual Units DFParameter
Results by SW-846 8260B
Results of HA-1 - 1.5-2.0ft
Date Analyzed
Dichlorobromomethane ND ug/Kg 14.53 06/6/2016 17:27
Dichlorodifluoromethane ND ug/Kg 14.53 06/6/2016 17:27
cis-1,3-Dichloropropene ND ug/Kg 14.53 06/6/2016 17:27
trans-1,3-Dichloropropene ND ug/Kg 14.53 06/6/2016 17:27
Diisopropyl Ether ND ug/Kg 14.53 06/6/2016 17:27
Ethyl Benzene ND ug/Kg 14.53 06/6/2016 17:27
Hexachlorobutadiene ND ug/Kg 14.53 06/6/2016 17:27
Isopropylbenzene (Cumene)ND ug/Kg 14.53 06/6/2016 17:27
Methyl iodide ND ug/Kg 14.53 06/6/2016 17:27
Methylene chloride ND ug/Kg 118.1 06/6/2016 17:27
Naphthalene ND ug/Kg 14.53 06/6/2016 17:27
Styrene ND ug/Kg 14.53 06/6/2016 17:27
Tetrachloroethene ND ug/Kg 14.53 06/6/2016 17:27
Toluene ND ug/Kg 14.53 06/6/2016 17:27
Trichloroethene ND ug/Kg 14.53 06/6/2016 17:27
Trichlorofluoromethane ND ug/Kg 14.53 06/6/2016 17:27
Vinyl chloride ND ug/Kg 14.53 06/6/2016 17:27
Xylene (total)ND ug/Kg 19.05 06/6/2016 17:27
cis-1,2-Dichloroethene ND ug/Kg 14.53 06/6/2016 17:27
m,p-Xylene ND ug/Kg 19.05 06/6/2016 17:27
n-Propylbenzene ND ug/Kg 14.53 06/6/2016 17:27
o-Xylene ND ug/Kg 14.53 06/6/2016 17:27
sec-Butylbenzene ND ug/Kg 14.53 06/6/2016 17:27
tert-Butyl methyl ether (MTBE)ND ug/Kg 14.53 06/6/2016 17:27
tert-Butylbenzene ND ug/Kg 14.53 06/6/2016 17:27
trans-1,2-Dichloroethene ND ug/Kg 14.53 06/6/2016 17:27
trans-1,4-Dichloro-2-butene ND ug/Kg 122.6 06/6/2016 17:27
Surrogates
1,2-Dichloroethane-d4 104 %190.9-137 06/6/2016 17:27
4-Bromofluorobenzene 106 %174.6-125 06/6/2016 17:27
Toluene d8 100 %188.8-113 06/6/2016 17:27
Batch Information
Prep Batch: VXX6534
Prep Method: SW-846 5035 SL
Prep Date/Time: 06/06/2016 11:20
Prep Initial Wt./Vol.: 6.85 g
Prep Extract Vol: 5 mL
Analytical Batch: VMS4012
Analytical Method: SW-846 8260B
Instrument: MSD4
Analyst: JHL
Print Date: 06/14/2016 N.C. Certification # 481
Page 7 of 25
Client Sample ID: HA-1 - 1.5-2.0ft
Client Project ID: Handy Mart 59
Lab Sample ID: 31601092001-D
Lab Project ID: 31601092
Collection Date: 06/03/2016 11:30
Received Date: 06/03/2016 14:01
Matrix: Soil-Solid as dry weight
Solids (%): 80.60
LOQ/CLResultQual Units DFParameter
Results by MADEP VPH
Results of HA-1 - 1.5-2.0ft
Date Analyzed
C5-C8 Aliphatics ND mg/kg 14.81 06/7/2016 3:17
C9-C10 Aromatics ND mg/kg 14.81 06/7/2016 3:17
C9-C12 Aliphatics ND mg/kg 14.81 06/7/2016 3:17
Surrogates
FID - 4-Bromofluorobenzene 108 %170.0-130 06/7/2016 3:17
PID - 4-Bromofluorobenzene 88.0 %170.0-130 06/7/2016 3:17
Batch Information
Prep Batch: VXX6536
Prep Method: SW-846 5035 VPH prep
Prep Date/Time: 06/06/2016 15:36
Prep Initial Wt./Vol.: 6.45 g
Prep Extract Vol: 5 mL
Analytical Batch: VGC2843
Analytical Method: MADEP VPH
Instrument: GC7
Analyst: BWS
Print Date: 06/14/2016 N.C. Certification # 481
Page 8 of 25
Client Sample ID: Trip Blank
Client Project ID: Handy Mart 59
Lab Sample ID: 31601092002-A
Lab Project ID: 31601092
Collection Date:
Received Date: 06/03/2016 14:01
Matrix: Soil-Solid as received
Solids (%):
LOQ/CLResultQual Units DFParameter
Results by SW-846 8260B
Results of Trip Blank
Date Analyzed
1,1,1,2-Tetrachloroethane ND ug/Kg 15.00 06/6/2016 16:30
1,1,1-Trichloroethane ND ug/Kg 15.00 06/6/2016 16:30
1,1,2,2-Tetrachloroethane ND ug/Kg 15.00 06/6/2016 16:30
1,1,2-Trichloroethane ND ug/Kg 15.00 06/6/2016 16:30
1,1-Dichloroethane ND ug/Kg 15.00 06/6/2016 16:30
1,1-Dichloroethene ND ug/Kg 15.00 06/6/2016 16:30
1,1-Dichloropropene ND ug/Kg 15.00 06/6/2016 16:30
1,2,3-Trichlorobenzene ND ug/Kg 15.00 06/6/2016 16:30
1,2,3-Trichloropropane ND ug/Kg 15.00 06/6/2016 16:30
1,2,4-Trichlorobenzene ND ug/Kg 15.00 06/6/2016 16:30
1,2,4-Trimethylbenzene ND ug/Kg 15.00 06/6/2016 16:30
1,2-Dibromo-3-chloropropane ND ug/Kg 130.0 06/6/2016 16:30
1,2-Dibromoethane ND ug/Kg 15.00 06/6/2016 16:30
1,2-Dichlorobenzene ND ug/Kg 15.00 06/6/2016 16:30
1,2-Dichloroethane ND ug/Kg 15.00 06/6/2016 16:30
1,2-Dichloropropane ND ug/Kg 15.00 06/6/2016 16:30
1,3,5-Trimethylbenzene ND ug/Kg 15.00 06/6/2016 16:30
1,3-Dichlorobenzene ND ug/Kg 15.00 06/6/2016 16:30
1,3-Dichloropropane ND ug/Kg 15.00 06/6/2016 16:30
1,4-Dichlorobenzene ND ug/Kg 15.00 06/6/2016 16:30
2,2-Dichloropropane ND ug/Kg 15.00 06/6/2016 16:30
2-Butanone ND ug/Kg 125.0 06/6/2016 16:30
2-Chlorotoluene ND ug/Kg 15.00 06/6/2016 16:30
2-Hexanone ND ug/Kg 112.5 06/6/2016 16:30
4-Chlorotoluene ND ug/Kg 15.00 06/6/2016 16:30
4-Isopropyltoluene ND ug/Kg 15.00 06/6/2016 16:30
4-Methyl-2-pentanone ND ug/Kg 112.5 06/6/2016 16:30
Acetone ND ug/Kg 150.0 06/6/2016 16:30
Benzene ND ug/Kg 15.00 06/6/2016 16:30
Bromobenzene ND ug/Kg 15.00 06/6/2016 16:30
Bromochloromethane ND ug/Kg 15.00 06/6/2016 16:30
Bromoform ND ug/Kg 15.00 06/6/2016 16:30
Bromomethane ND ug/Kg 15.00 06/6/2016 16:30
n-Butylbenzene ND ug/Kg 15.00 06/6/2016 16:30
Carbon disulfide ND ug/Kg 15.00 06/6/2016 16:30
Carbon tetrachloride ND ug/Kg 15.00 06/6/2016 16:30
Chlorobenzene ND ug/Kg 15.00 06/6/2016 16:30
Chlorodibromomethane ND ug/Kg 15.00 06/6/2016 16:30
Chloroethane ND ug/Kg 15.00 06/6/2016 16:30
Chloroform ND ug/Kg 15.00 06/6/2016 16:30
Chloromethane ND ug/Kg 15.00 06/6/2016 16:30
Dibromomethane ND ug/Kg 15.00 06/6/2016 16:30
Print Date: 06/14/2016 N.C. Certification # 481
Page 9 of 25
Client Sample ID: Trip Blank
Client Project ID: Handy Mart 59
Lab Sample ID: 31601092002-A
Lab Project ID: 31601092
Collection Date:
Received Date: 06/03/2016 14:01
Matrix: Soil-Solid as received
Solids (%):
LOQ/CLResultQual Units DFParameter
Results by SW-846 8260B
Results of Trip Blank
Date Analyzed
Dichlorobromomethane ND ug/Kg 15.00 06/6/2016 16:30
Dichlorodifluoromethane ND ug/Kg 15.00 06/6/2016 16:30
cis-1,3-Dichloropropene ND ug/Kg 15.00 06/6/2016 16:30
trans-1,3-Dichloropropene ND ug/Kg 15.00 06/6/2016 16:30
Diisopropyl Ether ND ug/Kg 15.00 06/6/2016 16:30
Ethyl Benzene ND ug/Kg 15.00 06/6/2016 16:30
Hexachlorobutadiene ND ug/Kg 15.00 06/6/2016 16:30
Isopropylbenzene (Cumene)ND ug/Kg 15.00 06/6/2016 16:30
Methyl iodide ND ug/Kg 15.00 06/6/2016 16:30
Methylene chloride ND ug/Kg 120.0 06/6/2016 16:30
Naphthalene ND ug/Kg 15.00 06/6/2016 16:30
Styrene ND ug/Kg 15.00 06/6/2016 16:30
Tetrachloroethene ND ug/Kg 15.00 06/6/2016 16:30
Toluene ND ug/Kg 15.00 06/6/2016 16:30
Trichloroethene ND ug/Kg 15.00 06/6/2016 16:30
Trichlorofluoromethane ND ug/Kg 15.00 06/6/2016 16:30
Vinyl chloride ND ug/Kg 15.00 06/6/2016 16:30
Xylene (total)ND ug/Kg 110.0 06/6/2016 16:30
cis-1,2-Dichloroethene ND ug/Kg 15.00 06/6/2016 16:30
m,p-Xylene ND ug/Kg 110.0 06/6/2016 16:30
n-Propylbenzene ND ug/Kg 15.00 06/6/2016 16:30
o-Xylene ND ug/Kg 15.00 06/6/2016 16:30
sec-Butylbenzene ND ug/Kg 15.00 06/6/2016 16:30
tert-Butyl methyl ether (MTBE)ND ug/Kg 15.00 06/6/2016 16:30
tert-Butylbenzene ND ug/Kg 15.00 06/6/2016 16:30
trans-1,2-Dichloroethene ND ug/Kg 15.00 06/6/2016 16:30
trans-1,4-Dichloro-2-butene ND ug/Kg 125.0 06/6/2016 16:30
Surrogates
1,2-Dichloroethane-d4 107 %190.9-137 06/6/2016 16:30
4-Bromofluorobenzene 108 %174.6-125 06/6/2016 16:30
Toluene d8 103 %188.8-113 06/6/2016 16:30
Batch Information
Prep Batch: VXX6534
Prep Method: SW-846 5035 SL
Prep Date/Time: 06/06/2016 11:20
Prep Initial Wt./Vol.: 5 g
Prep Extract Vol: 5 mL
Analytical Batch: VMS4012
Analytical Method: SW-846 8260B
Instrument: MSD4
Analyst: JHL
Print Date: 06/14/2016 N.C. Certification # 481
Page 10 of 25
Batch Summary
SW-846 8260B SW-846 5035 SLAnalytical Method:Prep Method:
VXX6534
06/06/2016 11:20
Prep Batch:
Prep Date:
Client Sample ID Analysis Date Instrument AnalystLab Sample ID Analytical Batch
LCS-S for HBN 116960 [VXX/6534 06/06/2016 12:10 MSD4 JHL202155VMS4012
LCSD-S for HBN 116960 [VXX/653 06/06/2016 12:38 MSD4 JHL202156VMS4012
MB-S for HBN 116960 [VXX/6534]06/06/2016 13:34 MSD4 JHL202157VMS4012
2520-0528 R36103...(201790DUP)06/06/2016 16:02 MSD4 JHL202251VMS4012
HA-1 - 1.5-2.0ft(202068MS)06/06/2016 17:55 MSD4 JHL202252VMS4012
HA-1 - 1.5-2.0ft 06/06/2016 17:27 MSD4 JHL31601092001VMS4012
Trip Blank 06/06/2016 16:30 MSD4 JHL31601092002VMS4012
Print Date: 06/14/2016 N.C. Certification # 481
Page 11 of 25
Blank ID: MB-S for HBN 116960 [VXX/6534]
Blank Lab ID: 202157
Matrix: Soil-Solid as dry weight
Results by SW-846 8260B
Method Blank
Parameter Result LOQ/CL Units DFQual
QC for Samples:
31601092001, 31601092002
1,1,1,2-Tetrachloroethane ND 5.00 ug/Kg 1
1,1,1-Trichloroethane ND 5.00 ug/Kg 1
1,1,2,2-Tetrachloroethane ND 5.00 ug/Kg 1
1,1,2-Trichloroethane ND 5.00 ug/Kg 1
1,1-Dichloroethane ND 5.00 ug/Kg 1
1,1-Dichloroethene ND 5.00 ug/Kg 1
1,1-Dichloropropene ND 5.00 ug/Kg 1
1,2,3-Trichlorobenzene ND 5.00 ug/Kg 1
1,2,3-Trichloropropane ND 5.00 ug/Kg 1
1,2,4-Trichlorobenzene ND 5.00 ug/Kg 1
1,2,4-Trimethylbenzene ND 5.00 ug/Kg 1
1,2-Dibromo-3-chloropropane ND 30.0 ug/Kg 1
1,2-Dibromoethane ND 5.00 ug/Kg 1
1,2-Dichlorobenzene ND 5.00 ug/Kg 1
1,2-Dichloroethane ND 5.00 ug/Kg 1
1,2-Dichloropropane ND 5.00 ug/Kg 1
1,3,5-Trimethylbenzene ND 5.00 ug/Kg 1
1,3-Dichlorobenzene ND 5.00 ug/Kg 1
1,3-Dichloropropane ND 5.00 ug/Kg 1
1,4-Dichlorobenzene ND 5.00 ug/Kg 1
2,2-Dichloropropane ND 5.00 ug/Kg 1
2-Butanone ND 25.0 ug/Kg 1
2-Chlorotoluene ND 5.00 ug/Kg 1
2-Hexanone ND 12.5 ug/Kg 1
4-Chlorotoluene ND 5.00 ug/Kg 1
4-Isopropyltoluene ND 5.00 ug/Kg 1
4-Methyl-2-pentanone ND 12.5 ug/Kg 1
Acetone ND 50.0 ug/Kg 1
Benzene ND 5.00 ug/Kg 1
Bromobenzene ND 5.00 ug/Kg 1
Bromochloromethane ND 5.00 ug/Kg 1
Bromoform ND 5.00 ug/Kg 1
Bromomethane ND 5.00 ug/Kg 1
Carbon disulfide ND 5.00 ug/Kg 1
Carbon tetrachloride ND 5.00 ug/Kg 1
Chlorobenzene ND 5.00 ug/Kg 1
Chlorodibromomethane ND 5.00 ug/Kg 1
Chloroethane ND 5.00 ug/Kg 1
Chloroform ND 5.00 ug/Kg 1
Chloromethane ND 5.00 ug/Kg 1
cis-1,2-Dichloroethene ND 5.00 ug/Kg 1
Print Date: 06/14/2016 N.C. Certification # 481
Page 12 of 25
Blank ID: MB-S for HBN 116960 [VXX/6534]
Blank Lab ID: 202157
Matrix: Soil-Solid as dry weight
Results by SW-846 8260B
Method Blank
Parameter Result LOQ/CL Units DFQual
QC for Samples:
31601092001, 31601092002
cis-1,3-Dichloropropene ND 5.00 ug/Kg 1
Dibromomethane ND 5.00 ug/Kg 1
Dichlorobromomethane ND 5.00 ug/Kg 1
Dichlorodifluoromethane ND 5.00 ug/Kg 1
Diisopropyl Ether ND 5.00 ug/Kg 1
Ethyl Benzene ND 5.00 ug/Kg 1
Hexachlorobutadiene ND 5.00 ug/Kg 1
Isopropylbenzene (Cumene)ND 5.00 ug/Kg 1
m,p-Xylene ND 10.0 ug/Kg 1
Methyl iodide ND 5.00 ug/Kg 1
Methylene chloride ND 20.0 ug/Kg 1
Naphthalene ND 5.00 ug/Kg 1
n-Butylbenzene ND 5.00 ug/Kg 1
n-Propylbenzene ND 5.00 ug/Kg 1
o-Xylene ND 5.00 ug/Kg 1
sec-Butylbenzene ND 5.00 ug/Kg 1
Styrene ND 5.00 ug/Kg 1
tert-Butyl methyl ether (MTBE)ND 5.00 ug/Kg 1
tert-Butylbenzene ND 5.00 ug/Kg 1
Tetrachloroethene ND 5.00 ug/Kg 1
Toluene ND 5.00 ug/Kg 1
trans-1,2-Dichloroethene ND 5.00 ug/Kg 1
trans-1,3-Dichloropropene ND 5.00 ug/Kg 1
trans-1,4-Dichloro-2-butene ND 25.0 ug/Kg 1
Trichloroethene ND 5.00 ug/Kg 1
Trichlorofluoromethane ND 5.00 ug/Kg 1
Vinyl chloride ND 5.00 ug/Kg 1
Xylene (total)ND 10.0 ug/Kg 1
Surrogates
1,2-Dichloroethane-d4 104 90.9-137 %1
4-Bromofluorobenzene 106 74.6-125 %1
Toluene d8 102 88.8-113 %1
Batch Information
Prep Batch: VXX6534
Prep Method: SW-846 5035 SL
Prep Date/Time: 6/6/2016 11:20:20AM
Prep Initial Wt./Vol.: 5 g
Prep Extract Vol: 5 mL
Analytical Batch: VMS4012
Analytical Method: SW-846 8260B
Instrument: MSD4
Analyst: JHL
Print Date: 06/14/2016 N.C. Certification # 481
Page 13 of 25
Blank Spike ID: LCS-S for HBN 116960 [VXX/6534
Blank Spike Lab ID: 202155
Date Analyzed: 06/06/2016 12:10
Spike Duplicate ID: LCSD-S for HBN 116960 [VXX/653
Spike Duplicate Lab ID: 202156
Date Analyzed: 06/06/2016 12:38
Results by SW-846 8260B
Blank Spike Summary
Matrix: Soil-Solid as dry weight
Parameter Spike Result Rec (%)Spike Result Rec (%)RPD (%)CL
Blank Spike (ug/Kg)
RPD CL
Spike Duplicate (ug/Kg)
31601092001, 31601092002QC for Samples:
1,1,1,2-Tetrachloroethane 30.0 30.5 0.6510230.0 30.7 102 78.7-117 30.00
1,1,1-Trichloroethane 30.0 31.7 0.9510630.0 31.4 105 73.4-123 30.00
1,1,2,2-Tetrachloroethane 30.0 31.2 0.9610430.0 31.5 105 74.5-135 30.00
1,1,2-Trichloroethane 30.0 29.7 0.349930.0 29.8 99 81.5-119 30.00
1,1-Dichloroethane 30.0 32.1 0.9410730.0 31.8 106 72.0-126 30.00
1,1-Dichloroethene 30.0 33.7 1.211230.0 33.3 111 69.1-121 30.00
1,1-Dichloropropene 30.0 31.6 0.3210530.0 31.5 105 70.8-125 30.00
1,2,3-Trichlorobenzene 30.0 27.6 1.19230.0 27.3 91 80.6-118 30.00
1,2,3-Trichloropropane 30.0 30.4 2.610130.0 31.2 104 74.8-133 30.00
1,2,4-Trichlorobenzene 30.0 28.0 1.19330.0 27.7 92 79.7-120 30.00
1,2,4-Trimethylbenzene 30.0 28.4 0.719530.0 28.2 94 74.1-120 30.00
1,2-Dibromo-3-chloropropane 180 178 4.49918018610368.6-135 30.00
1,2-Dibromoethane 30.0 30.2 1.610130.0 30.7 102 79.4-122 30.00
1,2-Dichlorobenzene 30.0 28.0 0.369330.0 28.1 94 80.5-116 30.00
1,2-Dichloroethane 30.0 31.1 0.9610430.0 31.4 105 79.7-123 30.00
1,2-Dichloropropane 30.0 31.0 0.3210330.0 30.9 103 78.1-122 30.00
1,3,5-Trimethylbenzene 30.0 28.4 0.359530.0 28.3 94 72.5-120 30.00
1,3-Dichlorobenzene 30.0 28.4 0.359530.0 28.3 94 77.3-118 30.00
1,3-Dichloropropane 30.0 29.8 1.09930.0 30.1 100 80.4-119 30.00
1,4-Dichlorobenzene 30.0 28.2 0.359430.0 28.3 94 78.6-118 30.00
2,2-Dichloropropane 30.0 34.8 1.711630.0 34.2 114 73.7-124 30.00
2-Butanone 75.0 74.9 9.210075.0 82.1 109 57.7-161 30.00
2-Chlorotoluene 30.0 28.1 0.369430.0 28.2 94 73.4-117 30.00
2-Hexanone 75.0 76.4 3.110275.0 78.8 105 67.0-143 30.00
4-Chlorotoluene 30.0 28.3 0.719430.0 28.1 94 74.5-118 30.00
4-Isopropyltoluene 30.0 28.5 0.359530.0 28.4 95 72.3-121 30.00
4-Methyl-2-pentanone 75.0 80.6 2.310775.0 82.5 110 68.1-145 30.00
Acetone 75.0 71.5 149575.0 82.4 110 38.3-190 30.00
Benzene 30.0 31.4 0.9610530.0 31.1 104 76.1-122 30.00
Bromobenzene 30.0 29.7 1.09930.0 30.0 100 81.3-116 30.00
Bromochloromethane 30.0 33.4 0.8911130.0 33.7 112 78.9-126 30.00
Bromoform 30.0 32.4 2.110830.0 33.1 110 70.3-132 30.00
Print Date: 06/14/2016 N.C. Certification # 481
Page 14 of 25
Blank Spike ID: LCS-S for HBN 116960 [VXX/6534
Blank Spike Lab ID: 202155
Date Analyzed: 06/06/2016 12:10
Spike Duplicate ID: LCSD-S for HBN 116960 [VXX/653
Spike Duplicate Lab ID: 202156
Date Analyzed: 06/06/2016 12:38
Results by SW-846 8260B
Blank Spike Summary
Matrix: Soil-Solid as dry weight
Parameter Spike Result Rec (%)Spike Result Rec (%)RPD (%)CL
Blank Spike (ug/Kg)
RPD CL
Spike Duplicate (ug/Kg)
31601092001, 31601092002QC for Samples:
Bromomethane 30.0 37.7 0.2612630.0 37.8 126 43.9-141 30.00
Carbon disulfide 30.0 44.3 1.4148*30.0 43.7 146*61.5-131 30.00
Carbon tetrachloride 30.0 32.9 1.511030.0 32.4 108 72.2-123 30.00
Chlorobenzene 30.0 29.7 0.679930.0 29.9 100 79.0-116 30.00
Chlorodibromomethane 30.0 31.3 0.6410430.0 31.5 105 78.0-120 30.00
Chloroethane 30.0 34.2 2.711430.0 33.3 111 59.7-133 30.00
Chloroform 30.0 33.4 0.6011130.0 33.2 111 75.8-124 30.00
Chloromethane 30.0 28.0 1.19330.0 28.3 94 53.5-124 30.00
cis-1,2-Dichloroethene 30.0 33.7 0.6011230.0 33.5 112 73.9-124 30.00
cis-1,3-Dichloropropene 30.0 33.4 0.3011130.0 33.5 112 78.9-126 30.00
Dibromomethane 30.0 32.4 0.3110830.0 32.5 108 77.1-129 30.00
Dichlorobromomethane 30.0 31.9 0.9410630.0 31.6 105 77.7-123 30.00
Dichlorodifluoromethane 30.0 29.6 0.09930.0 29.6 99 21.3-143 30.00
Diisopropyl Ether 30.0 29.6 0.349930.0 29.5 98 73.0-126 30.00
Ethyl Benzene 30.0 28.3 1.19430.0 28.0 93 70.9-118 30.00
Hexachlorobutadiene 30.0 26.9 1.99030.0 26.4 88 69.6-119 30.00
Isopropylbenzene (Cumene)30.0 28.7 0.09630.0 28.7 96 70.1-121 30.00
m,p-Xylene 60.0 57.8 0.529660.0 57.5 96 71.8-120 30.00
Methyl iodide 30.0 46.2 1.1154*30.0 45.7 152*63.8-133 30.00
Methylene chloride 30.0 28.9 0.359630.0 28.8 96 73.0-121 30.00
Naphthalene 30.0 28.6 1.79530.0 29.1 97 75.8-126 30.00
n-Butylbenzene 30.0 28.8 1.09630.0 28.5 95 72.6-122 30.00
n-Propylbenzene 30.0 28.7 0.359630.0 28.8 96 71.1-122 30.00
o-Xylene 30.0 28.3 0.719430.0 28.1 94 71.9-118 30.00
sec-Butylbenzene 30.0 28.6 0.709530.0 28.4 95 71.6-121 30.00
Styrene 30.0 28.9 0.699630.0 28.7 96 72.8-119 30.00
tert-Butyl methyl ether (MTBE)30.0 30.7 0.3310230.0 30.8 103 74.4-127 30.00
tert-Butylbenzene 30.0 28.3 0.359430.0 28.2 94 70.9-119 30.00
Tetrachloroethene 30.0 29.7 0.349930.0 29.6 99 75.2-117 30.00
Toluene 30.0 31.2 0.6410430.0 31.0 103 74.6-125 30.00
trans-1,2-Dichloroethene 30.0 31.6 0.9510530.0 31.3 104 72.0-121 30.00
trans-1,3-Dichloropropene 30.0 33.4 0.3011130.0 33.5 112 80.0-127 30.00
Print Date: 06/14/2016 N.C. Certification # 481
Page 15 of 25
Blank Spike ID: LCS-S for HBN 116960 [VXX/6534
Blank Spike Lab ID: 202155
Date Analyzed: 06/06/2016 12:10
Spike Duplicate ID: LCSD-S for HBN 116960 [VXX/653
Spike Duplicate Lab ID: 202156
Date Analyzed: 06/06/2016 12:38
Results by SW-846 8260B
Blank Spike Summary
Matrix: Soil-Solid as dry weight
Parameter Spike Result Rec (%)Spike Result Rec (%)RPD (%)CL
Blank Spike (ug/Kg)
RPD CL
Spike Duplicate (ug/Kg)
31601092001, 31601092002QC for Samples:
trans-1,4-Dichloro-2-butene 150 157 2.510415016110873.5-133 30.00
Trichloroethene 30.0 30.3 0.3310130.0 30.4 101 73.0-124 30.00
Trichlorofluoromethane 30.0 30.5 5.010230.0 29.0 97 58.1-131 30.00
Vinyl chloride 30.0 31.9 0.3110630.0 31.8 106 62.4-123 30.00
Surrogates
1,2-Dichloroethane-d4 102 102 90.9-137
4-Bromofluorobenzene 104 106 74.6-125
Toluene d8 102 102 88.8-113
Batch Information
Analytical Batch: VMS4012
Analytical Method: SW-846 8260B
Instrument: MSD4
Analyst: JHL
Prep Batch: VXX6534
Prep Method: SW-846 5035 SL
Prep Date/Time: 06/06/2016 11:20
Spike Init Wt./Vol.: 5 g Extract Vol: 5 mL
Dupe Init Wt./Vol.: 5 g Extract Vol: 5 mL
Print Date: 06/14/2016 N.C. Certification # 481
Page 16 of 25
Original Sample ID: 31601092001 (HA-1 - 1.5-2.0ft)
MS Sample ID: 202252
MSD Sample ID:
Analysis Date: 06/06/2016 17:27
Analysis Date: 06/06/2016 17:55
Analysis Date:
Matrix: Soil-Solid as dry weight
Results by SW-846 8260B
Matrix Spike Summary
Parameter Sample Spike Result Rec (%)Spike Result Rec (%)RPD (%)
Matrix Spike (ug/Kg)Spike Duplicate (ug/Kg)
CL RPD CL
QC for Samples:31601092001, 31601092002
1,1,1,2-Tetrachloroethane ND 27.2 13.0 48 *69.0-120
1,1,1-Trichloroethane ND 27.2 15.2 56 *78.0-121
1,1,2,2-Tetrachloroethane ND 27.2 12.2 45 *76.0-136
1,1,2-Trichloroethane ND 27.2 12.3 45 *65.0-128
1,1-Dichloroethane ND 27.2 15.3 56 *72.0-139
1,1-Dichloroethene ND 27.2 18.3 67 *72.0-135
1,1-Dichloropropene ND 27.2 16.1 59 *69.0-137
1,2,3-Trichlorobenzene ND 27.2 8.53 31 *61.0-126
1,2,3-Trichloropropane ND 27.2 12.1 44 10.0-218
1,2,4-Trichlorobenzene ND 27.2 8.87 33 *61.0-125
1,2,4-Trimethylbenzene ND 27.2 13.6 50 31.0-172
1,2-Dibromo-3-chloropropane ND 163 70.7 43 43.0-229
1,2-Dibromoethane ND 27.2 11.6 43 *78.0-148
1,2-Dichlorobenzene ND 27.2 11.1 41 *58.0-148
1,2-Dichloroethane ND 27.2 12.8 47 *73.0-146
1,2-Dichloropropane ND 27.2 13.9 51 *76.0-136
1,3,5-Trimethylbenzene ND 27.2 13.7 50 *68.0-132
1,3-Dichlorobenzene ND 27.2 11.7 43 *55.0-145
1,3-Dichloropropane ND 27.2 12.0 44 33.0-137
1,4-Dichlorobenzene ND 27.2 11.5 42 *53.0-146
2,2-Dichloropropane ND 27.2 15.8 58 58.0-150
2-Butanone ND 67.9 26.9 40 *41.0-256
2-Chlorotoluene ND 27.2 12.5 46 *60.0-144
2-Hexanone ND 67.9 27.8 41 *42.0-111
4-Chlorotoluene ND 27.2 12.2 45 *59.0-141
4-Isopropyltoluene ND 27.2 12.1 44 *75.0-122
4-Methyl-2-pentanone ND 67.9 31.5 46 6.90-166
Acetone ND 67.9 ND 28 6.80-355
Benzene 20.2 27.2 23.6 13 *75.0-133
Bromobenzene ND 27.2 13.2 48 *66.0-140
Bromochloromethane ND 27.2 14.0 51 *85.0-136
Bromoform ND 27.2 10.8 40 *75.0-151
Bromomethane ND 27.2 18.3 68 30.0-127
n-Butylbenzene ND 27.2 11.5 42 41.0-147
Carbon disulfide ND 27.2 22.2 82 64.0-145
Carbon tetrachloride ND 27.2 15.1 55 *64.0-142
Print Date: 06/14/2016 N.C. Certification # 481
Page 17 of 25
Original Sample ID: 31601092001 (HA-1 - 1.5-2.0ft)
MS Sample ID: 202252
MSD Sample ID:
Analysis Date: 06/06/2016 17:27
Analysis Date: 06/06/2016 17:55
Analysis Date:
Matrix: Soil-Solid as dry weight
Results by SW-846 8260B
Matrix Spike Summary
Parameter Sample Spike Result Rec (%)Spike Result Rec (%)RPD (%)
Matrix Spike (ug/Kg)Spike Duplicate (ug/Kg)
CL RPD CL
QC for Samples:31601092001, 31601092002
Chlorobenzene ND 27.2 14.0 52 *66.0-135
Chlorodibromomethane ND 27.2 11.4 42 *78.0-141
Chloroethane ND 27.2 17.2 64 21.0-182
Chloroform ND 27.2 15.3 56 *71.0-143
Chloromethane ND 27.2 15.0 55 *69.0-138
Dibromomethane ND 27.2 12.4 46 *80.0-150
Dichlorobromomethane ND 27.2 12.8 47 *77.0-140
Dichlorodifluoromethane ND 27.2 16.8 62 *82.0-130
cis-1,3-Dichloropropene ND 27.2 12.8 47 *72.0-146
trans-1,3-Dichloropropene ND 27.2 12.8 47 45.0-144
Diisopropyl Ether ND 27.2 13.4 49 *79.0-122
Ethyl Benzene ND 27.2 13.4 49 *74.0-126
Hexachlorobutadiene ND 27.2 8.78 32 *52.0-134
Isopropylbenzene (Cumene)ND 27.2 13.7 50 *74.0-123
Methyl iodide ND 27.2 20.6 76 41.0-126
Methylene chloride ND 27.2 ND 49 49.0-155
Naphthalene ND 27.2 9.74 36 *55.0-140
Styrene ND 27.2 12.3 45 *73.0-123
Tetrachloroethene ND 27.2 14.2 52 46.0-153
Toluene ND 27.2 15.4 57 *66.0-128
Trichloroethene ND 27.2 14.9 55 35.0-136
Trichlorofluoromethane ND 27.2 14.8 55 *77.0-132
Vinyl chloride ND 27.2 17.5 65 *68.0-137
cis-1,2-Dichloroethene ND 27.2 16.1 59 *77.0-134
m,p-Xylene ND 54.3 29.3 54 *80.0-118
n-Propylbenzene ND 27.2 13.3 49 *72.0-128
o-Xylene ND 27.2 13.9 51 *80.0-121
sec-Butylbenzene ND 27.2 12.4 46 *57.0-138
tert-Butyl methyl ether (MTBE)ND 27.2 12.2 45 *67.0-135
tert-Butylbenzene ND 27.2 12.7 47 *61.0-142
trans-1,2-Dichloroethene ND 27.2 16.1 59 *72.0-135
trans-1,4-Dichloro-2-butene ND 135 58.2 43 *49.0-211
Surrogates
1,2-Dichloroethane-d4 104 90.9-137
4-Bromofluorobenzene 106 74.6-125
Toluene d8 101 88.8-113
Print Date: 06/14/2016 N.C. Certification # 481
Page 18 of 25
Original Sample ID: 31601092001 (HA-1 - 1.5-2.0ft)
MS Sample ID: 202252
MSD Sample ID:
Analysis Date: 06/06/2016 17:27
Analysis Date: 06/06/2016 17:55
Analysis Date:
Matrix: Soil-Solid as dry weight
Results by SW-846 8260B
Matrix Spike Summary
Parameter Sample Spike Result Rec (%)Spike Result Rec (%)RPD (%)
Matrix Spike (%)Spike Duplicate (%)
CL RPD CL
QC for Samples:31601092001, 31601092002
Batch Information
Analytical Batch: VMS4012
Analytical Method: SW-846 8260B
Instrument: MSD4
Analyst: JHL
Prep Batch: VXX6534
Prep Method: SW-846 5035 SL
Prep Date/Time: 06/06/2016 11:20
MS Init Wt./Vol.: 6.85 g Extract Vol.: 5 mL
MSD Init Wt./Vol.: Extract Vol.:
Print Date: 06/14/2016 N.C. Certification # 481
Page 19 of 25
Batch Summary
MADEP VPH SW-846 5035 VPH prepAnalytical Method:Prep Method:
VXX6536
06/06/2016 15:36
Prep Batch:
Prep Date:
Client Sample ID Analysis Date Instrument AnalystLab Sample ID Analytical Batch
LCS for HBN 116967 [VXX/6536]06/07/2016 01:21 GC7 BWS202177VGC2843
LCSD for HBN 116967 [VXX/6536]06/07/2016 01:50 GC7 BWS202178VGC2843
MB for HBN 116967 [VXX/6536]06/07/2016 02:48 GC7 BWS202179VGC2843
HA-1 - 1.5-2.0ft(202068MS)06/07/2016 03:46 GC7 BWS202180VGC2843
HA-1 - 1.5-2.0ft(202068MSD)06/07/2016 04:16 GC7 BWS202181VGC2843
HA-1 - 1.5-2.0ft 06/07/2016 03:17 GC7 BWS31601092001VGC2843
Print Date: 06/14/2016 N.C. Certification # 481
Page 20 of 25
Blank ID: MB for HBN 116967 [VXX/6536]
Blank Lab ID: 202179
Matrix: Soil-Solid as dry weight
Results by MADEP VPH
Method Blank
Parameter Result LOQ/CL Units DFQual
QC for Samples:
31601092001
C5-C8 Aliphatics ND 5.00 mg/kg 1
C9-C10 Aromatics ND 5.00 mg/kg 1
C9-C12 Aliphatics ND 5.00 mg/kg 1
Surrogates
FID - 4-Bromofluorobenzene 110 70.0-130 %1
PID - 4-Bromofluorobenzene 89.0 70.0-130 %1
Batch Information
Prep Batch: VXX6536
Prep Method: SW-846 5035 VPH prep
Prep Date/Time: 6/6/2016 3:36:49PM
Prep Initial Wt./Vol.: 5 g
Prep Extract Vol: 5 mL
Analytical Batch: VGC2843
Analytical Method: MADEP VPH
Instrument: GC7
Analyst: BWS
Print Date: 06/14/2016 N.C. Certification # 481
Page 21 of 25
Blank Spike ID: LCS for HBN 116967 [VXX/6536]
Blank Spike Lab ID: 202177
Date Analyzed: 06/07/2016 01:21
Spike Duplicate ID: LCSD for HBN 116967 [VXX/6536]
Spike Duplicate Lab ID: 202178
Date Analyzed: 06/07/2016 01:50
Results by MADEP VPH
Blank Spike Summary
Matrix: Soil-Solid as dry weight
Parameter Spike Result Rec (%)Spike Result Rec (%)RPD (%)CL
Blank Spike (mg/kg)
RPD CL
Spike Duplicate (mg/kg)
31601092001QC for Samples:
C5-C8 Aliphatics 136 146 5.610713613810170.0-130 30.00
C9-C10 Aromatics 16.0 14.0 5.98816.0 13.2 82 70.0-130 30.00
C9-C12 Aliphatics 112 122 5.910911211510370.0-130 30.00
Surrogates
FID - 4-Bromofluorobenzene 106 109 70.0-130
PID - 4-Bromofluorobenzene 88 90 70.0-130
Batch Information
Analytical Batch: VGC2843
Analytical Method: MADEP VPH
Instrument: GC7
Analyst: BWS
Prep Batch: VXX6536
Prep Method: SW-846 5035 VPH prep
Prep Date/Time: 06/06/2016 15:36
Spike Init Wt./Vol.: 5 g Extract Vol: 5 mL
Dupe Init Wt./Vol.: 5 g Extract Vol: 5 mL
Print Date: 06/14/2016 N.C. Certification # 481
Page 22 of 25
Original Sample ID: 31601092001 (HA-1 - 1.5-2.0ft)
MS Sample ID: 202180
MSD Sample ID: 202181
Analysis Date: 06/07/2016 03:17
Analysis Date: 06/07/2016 03:46
Analysis Date: 06/07/2016 04:16
Matrix: Soil-Solid as dry weight
Results by MADEP VPH
Matrix Spike Summary
Parameter Sample Spike Result Rec (%)Spike Result Rec (%)RPD (%)
Matrix Spike (mg/kg)Spike Duplicate (mg/kg)
CL RPD CL
QC for Samples:31601092001
C5-C8 Aliphatics ND 130 148 130 145 111 1.7113 30.0070.0-130
C9-C10 Aromatics ND 15.4 13.3 15.4 13.6 89 2.887 30.0070.0-130
C9-C12 Aliphatics ND 108 117 108 118 110 1.1108 30.0070.0-130
Surrogates
FID - 4-Bromofluorobenzene 106113 70.0-130
PID - 4-Bromofluorobenzene 8793 70.0-130
Batch Information
Analytical Batch: VGC2843
Analytical Method: MADEP VPH
Instrument: GC7
Analyst: BWS
Prep Batch: VXX6536
Prep Method: SW-846 5035 VPH prep
Prep Date/Time: 06/06/2016 15:36
MS Init Wt./Vol.: 6.45 g Extract Vol.: 5 mL
MSD Init Wt./Vol.: 6.45 g Extract Vol.: 5 mL
Print Date: 06/14/2016 N.C. Certification # 481
Page 23 of 25
Page 24 of 25
Page 25 of 25