WA-17830_17830_CA_RPTS_20140429_MRP

2725 East Millbrook Road Suite 121 Raleigh, NC 27604 Tel: [phone]
Fax: [phone] www.atcassociates.com N.C. Engineering License No. C-1598

April 29, 2014

Ms. Sylvia Newsom-Hunneke
North Carolina Department of Environment and Natural Resources
Washington Regional Office Division of Waste Management - UST Section
943 Washington Square Mall
Washington, North Carolina 27889

Re: Groundwater Monitoring Report
Former Craven Oil
1915 Glenburnie Road
New Bern, Craven County, North Carolina
NCDENR Incident No. 17830
Priority Site Ranking: High
ATC Project No. 45.40675.2005

Dear Ms. Hunneke:

ATC Associates of North Carolina, P.C. (ATC), on behalf of Worsley Family Holdings,
LLC, is submitting this Monitoring Report to document the recent groundwater sampling
event and summary of laboratory analytical data.

If you have any questions or require additional information, please do not hesitate to
contact our office at [phone].

Sincerely,

ATC Associates of North Carolina, P.C.

Maureen Jackson, P.G.
Project Manager

cc: Ms. Greta Stanley, Worsley Family Holdings, LLC

Groundwater Monitoring Report
Former Craven Oil
1915 South Glenburnie Road
New Bern, North Carolina
ATC Project No. 45.40675.2005
April 29, 2014

TABLE OF CONTENTS

1.0 INTRODUCTION........................................................................................................1
2.0 SITE BACKGROUND ................................................................................................1
3.0 GROUNDWATER MONITORING ..........................................................................2
3.1 Groundwater Elevations .......................................................................................2
3.2 Analytical Results ................................................................................................2
4.0 CONCLUSIONS ..........................................................................................................3

TABLES

Table 1 Monitoring Well Construction Details
Table 2 Historical Groundwater Elevation Data
Table 3 Groundwater Analytical Summary
Table 4 Historical Groundwater Analytical Results
Table 5 Water Supply Well Analytical Summary

FIGURES

Figure 1 Site Topographic Map
Figure 2 Site Plan
Figure 3 Groundwater Elevation Contour Map
Figure 4 Contaminants of Concern Map

APPENDICES

Appendix A Laboratory Analytical Results

Groundwater Monitoring Report April 29, 2014
NCDENR Incident No. 17830 ATC Project No. 45.40675.2005
Page 1

1.0 INTRODUCTION

ATC Associates of North Carolina, P.C. (ATC), on behalf of Worsley Family Holdings, LLC
(Worsley), is submitting this sampling report for the Former Craven Oil facility located at 1915
Glenburnie Road, New Bern, North Carolina (Incident #17830). A site topographic map is
presented as Figure 1 and site map is presented as Figure 2. Currently, the site operates as an
active retail fuel outlet and convenience store. This report includes the laboratory analytical results
for the groundwater sampling event of April 7, 2014.

2.0 SITE BACKGROUND

Historically, the facility operated as a bulk aboveground storage tank (AST) facility. The former
ASTs were owned by Worsley Companies, Inc. (Worsley) of Wilmington, North Carolina. At an
unknown date, the site’s AST systems were removed.

Site activities conducted to date have included the installation and sampling of seven Type II and
one Type III monitoring wells, soil samples collected during soil assessment activities and
monitoring well construction, and aquifer slug tests. Interim remedial actions have included the
excavation of approximately 1,155 tons of petroleum-impacted soil from the subject facility.

Previous reports submitted include: Comprehensive Site Assessment (CSA) Report, dated
November 1999, Clark Environmental Services, P.C. (CES); CSA Report Addendum, dated June
16, 2000, Delta Environmental Consultants, Inc. (Delta); Corrective Action Plan (CAP) and
addendum, dated December 29, 2000, and October 3, 2001, by Delta; Groundwater Monitoring
Reports submitted between May 2002 and March 2007 by Delta; Groundwater Monitoring
Reports submitted by Environmental Services & Solutions, PLLC (ESS) submitted March 2009
and August 2010.

In August 2010, Worsley awarded an environmental services contract to ATC for continuing
environmental services at the site.

This report describes the groundwater sampling results for April 7, 2014 sampling event.
Groundwater Monitoring Report April 29, 2014 NCDENR Incident No. 17830 ATC Project No. 45.40675.2005

Page 2
3.0 GROUNDWATER MONITORING
3.1 Groundwater Elevations

On April 7, 2014, ATC collected static water level measurements from monitoring wells
MW-3A, MW-4A, and MW-7A. Depths to water measurements were collected using an
electronic oil/water interface probe. The groundwater depths were converted to relative elevations
using an assumed datum of 100 feet relative to an arbitrary on-site benchmark. Monitoring well
construction details are included in Table 1. Current and historical groundwater elevation data are
included in Table 2. A groundwater elevation contour map based on the April 2014 static water
level data is included as Figure 3. Based on the recent groundwater level measurements,
groundwater flows east across the site.

3.2 Analytical Results

On April 7, 2014, groundwater samples were collected from monitoring wells MW-3A, MW-4A,
and MW-7A. Groundwater samples were collected into laboratory-approved containers, packed
in ice and delivered under chain-of-custody to Pace Analytical Services (Pace), in Huntersville,
North Carolina, for analyses. Groundwater samples were analyzed for volatile organic
compounds (VOCs) via EPA Method 6200B including methyl tertiary-butyl ether (MTBE) and
isopropyl ether (IPE). A summary of the recent groundwater analytical data is presented in Table
3 and a historical summary of groundwater analytical data is presented in Table 4.

The laboratory analytical results from the April 7, 2014 sampling event indicates that dissolved
naphthalene exceeded its established Title 15A NCAC 2L.0202 (2L) standard in the groundwater
samples collected from monitoring wells MW-4A and MW-7A.

A contaminants of concern map is included as Figure 4. A copy of the laboratory analytical report
is included as Appendix A.

It should be noted an attempt was made to the sample the water supply well located at Martin’s
Auto Repair; however, the owner would not grant ATC personnel access to the well. A summary
of historical groundwater analytical data for the water supply well is presented in Table 5.

Groundwater Monitoring Report April 29, 2014 NCDENR Incident No. 17830 ATC Project No. 45.40675.2005

Page 3
4.0 CONCLUSIONS

ATC has performed a groundwater sampling event at the former Craven Oil facility in New Bern,
North Carolina. Based on field activities, observations, and groundwater analytical results, ATC
concludes the following:

• Depth to groundwater measurements ranged from 2.29 feet to 2.51 feet below ground surface
in MW-3A and MW-7A, respectively. The inferred shallow groundwater flow direction
across the site is to the east.
• Free product has not been associated with the release.
• The site is not located within a designated wellhead protection area.
• The site is connected to the public water supply system. The surrounding properties have the
option of being connected to the public water supply system.
• Dissolved target compound concentrations appear to be decreasing at the facility.
• An attempt was made to sample the water supply well at Martin’s Auto Repair. The property
owner would not allow ATC access to the well to collect a sample. The person at the repair
facility stated the repair facility was connected to the public water supply system.

Based on the above information, it appears impacts of petroleum contaminant concentrations are
limited to the site and the area of the former fueling system. ATC recommends continuation of
annual groundwater sampling activities.

TABLES
TABLE 1
MONITORING WELL CONSTRUCTION DETAILS
FORMER CRAVEN OIL
1915 SOUTH GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATC PROJECT NO. 45.40675.2005
Depth of
Water (feet)

Elevation
(feet)
MW-1 Unknown 2 1.5-11.5 11.5 96.15
MW-2 Unknown 2 1.5-11.5 11.5 96.99
MW-3A Unknown 2 1.5-11.5 11.5 96.07 2.29 93.78
MW-4A Unknown 2 2.0-12.0 12 96.68 2.43 94.25
MW-5A Unknown 2 2.0-12.0 12 96.14
MW-6 Unknown 2 2.0-12.0 12 96.94
MW-7A Unknown 2 2.0-12.0 12 96.87 2.51 94.36
T-1A Unknown 2 26.0-31.0 31 97.07
Notes:
1. Elevations are referenced to an arbitrary on-site benchmark of 100.00 feet.
2. Total well depths measured from top of casing.
3. NM - Depth to water not measured
NM
NM
NM
Depth of Well
(feet)
Top of Casing
(feet)
Date Measured: 4/7/14
NM
NM
Monitoring
Well ID Date Installed
Well Casing
Diameter
(Inches)
Screened
Interval
(feet)
TABLE 2
HISTORICAL GROUNDWATER ELEVATION DATA
FORMER CRAVEN OIL
1915 SOUTH GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATCPROJECT NO. 45.40675.2005
Page 2 of 9
Well
No.Date Top of Casing
Elevation (Feet)
Depth to Water
(Feet)
Depth to
Product (Feet)
Groundwater
Elevation
(Feet)
8/21/2007 3.95 --92.20
2/6/2008 3.44 --92.71
8/19/2008 4.21 --91.94
2/19/2009 3.38 --92.77
8/11/2009 3.11 --93.04
2/17/2010 2.67 --93.48
8/9/2010 3.58 --92.57
2/8/2011 2.52 --93.63
10/9/2012
7/1/2013
4/7/2014
8/21/2007 2.91 --94.08
2/6/2008 2.27 --94.72
8/19/2008 3.06 --93.93
2/19/2009 2.24 --94.75
8/11/2009 2.08 --94.91
2/17/2010 1.68 --95.31
8/9/2010 2.51 --94.48
2/8/2011 1.66 --95.33
11/7/2011 2.65 --94.34
10/9/2012
7/1/2013
4/7/2014
8/21/2007 3.23 --92.84
2/6/2008 2.37 --93.70
8/19/2008 3.28 --92.79
2/19/2009 2.13 --93.94
8/11/2009 2.45 --93.62
2/17/2010 1.91 --94.16
8/9/2010 2.89 --93.18
2/8/2011 1.84 --94.23
10/9/2012
7/1/2013
4/7/2014 2.29 --93.78
8/21/2007 3.37 --93.31
2/6/2008 2.63 --94.05
8/19/2008 3.32 --93.36
2/19/2009 2.48 --94.20
8/11/2009 2.60 --94.08
2/17/2010 2.13 --94.55
8/9/2010 2.97 --93.71
2/8/2011 1.91 --94.77
11/7/2011 2.95 --93.73
10/9/2012 2.58 --94.10
7/1/2013 2.04 --94.64
4/7/2014 2.43 --94.25
8/21/2007 3.63 --92.51
2/6/2008 1.21 --94.93
8/19/2008 3.86 --92.28
2/19/2009 0.96 --95.18
8/11/2009
2/17/2010 0.86 --95.28
8/9/2010 0.99 --95.15
2/8/2011
10/9/2012
7/1/2013
4/7/2014
Not Measured
Not Measured
Not Measured
96.68
96.14
Not Measured
Unable to Locate
96.15
Not Measured
96.99
Not Measured
96.07
Not Measured
Not Measured
Not Measured
Not Measured
Well Not Accessible
Not Measured
MW-1
MW-2
MW-3A
MW-4A
MW-5A
TABLE 2
HISTORICAL GROUNDWATER ELEVATION DATA
FORMER CRAVEN OIL
1915 SOUTH GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATCPROJECT NO. 45.40675.2005
Page 3 of 9
Well
No.Date Top of Casing
Elevation (Feet)
Depth to Water
(Feet)
Depth to
Product (Feet)
Groundwater
Elevation
(Feet)
8/21/2007 3.22 --93.72
2/6/2008 1.56 --95.38
8/19/2008 3.22 --93.72
2/19/2009 1.73 --95.21
8/11/2009 1.97 --94.97
2/17/2010 1.35 --95.59
8/9/2010 2.50 --94.44
2/8/2011
10/9/2012
7/1/2013
4/7/2014
8/21/2007 3.38 --93.49
2/6/2008 2.76 --94.11
8/19/2008 3.55 --93.32
2/19/2009 2.95 --93.92
8/11/2009 2.63 --94.24
2/17/2010 2.04 --94.83
8/9/2010 3.13 --93.74
2/8/2011 2.19 --94.68
11/7/2011 3.14 --93.73
10/9/2012 2.74 --94.13
7/1/2013 2.31 --94.56
4/7/2014 2.51 --94.36
8/21/2007 8.66 --88.41
2/6/2008 9.56 --87.51
8/19/2008 10.25 --86.82
2/19/2009 9.11 --87.96
8/11/2009 9.13 --87.94
2/17/2010 5.65 --91.42
8/9/2010 9.17 --87.90
2/8/2011 6.54 --90.53
10/9/2012
7/1/2013
4/7/2014
Not Measured
97.07
Not Measured
96.94
96.87
Not Measured
Not Measured
Unable to Access - Car Parked Over
T-1A
Not Measured
MW-7A
Not Measured
MW-6
TABLE 3
GROUNDWATER ANALYTICAL SUMMARY
FORMER CRAVEN OIL
1915 SOUTH GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATC PROJECT NO. 45.40675.2005
Well ID
Date
Collected
MW-1 4/7/2014
MW-2 4/7/2014
MW-3A 4/7/2014 <0.50 <0.50 <0.50 <1.50 <3.0 2.5 <0.50 0.65 <0.50 <0.50 <0.50 <2.0 <0.50
MW-4A 4/7/2014 <0.50 <0.50 <0.50 <1.50 <3.0 <0.50 <0.50 4.8 1.3 4.2 1.0 11.0 6.0
MW-5A 4/7/2014
MW-6 4/7/2014
MW-7A 4/7/2014 0.76 <0.50 61.7 1.84 64.30 <0.50 <0.50 4.3 <0.50 <0.50 <0.50 7.8 7.3
T-1A 4/7/2014
1 600 600 500 NE 20 70 70 70 70 40 6 70
5,000 260,000 84,500 85,500 NE 20,000 70,000 25,000 6,900 8,500 40,000 6,000 30,000
Notes:
1. "<" or ND = Not detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (µg/l) = parts per billion.
3. Concentrations in bold print equal or exceed the NCDENR 2L Standard (2L).
4. NCDENR = North Carolina Department of Environment and Natural Resources.
5. GCL = Gross Contaminant Level.
6. NE = Not Established.
7. MTBE = Methyl Tertiary Butyl Ether.
8. Gross Contaminant Levels for Groundwater are referenced in the Guidelines for Assessment
and Corrective Action, November 2008, updated January 2010.
9. BTEX = Benzene, Toluene, Ethylbenzene, Total Xylenes
Not Sampled
2L Standard (µg/l)
GCL (µg/l)
Not Sampled
Not Sampled
Not Sampled
Not Sampled n-PropylbenzeneTotal XylenesTotal BTEXn-Butylbenzenesec-Butylbenzenetert-ButylbenzeneAnalytical Method Standard Method 6200B
Contaminant of
Concern
BenzeneTolueneNaphthaleneEthylbenzeneMTBEIsopropyl etherIsopropylbenzene
TABLE 4
HISTORICAL GROUNDWATER ANALYTICAL SUMMARY
FORMER CRAVEN OIL
1915 GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATC PROJECT NO. 45.40675.2005
Well ID
Date
Collected
8/21/2007 <1.0 <5.0 <1.0 <3.0 <10.0 3.5 1.0 <5.0
2/19/2009 <1.00 <1.00 <1.00 <3.00 <6.00 4.31 <1.00 <1.00
2/8/2011 <1 <1 <1 <1 <4 <1 <1 <10
10/9/2012
7/1/2013
4/7/2014
4/24/2002 <0.5 <0.5 <0.5 <0.5 <2.0 <10 ----
7/24/2002 <1.0 <1.0 <1.0 <4.0 <7.0 5.0 <1.0 --
11/21/2002 <2.0 <2.0 <2.0 <2.0 <8.0 234 <10 --
1/28/2003 <0.5 <0.5 <0.5 <0.5 <2.0 31 <5 --
5/28/2003 <1.0 <1.0 <1.0 <4.0 <7.0 170 <1.0 --
11/11/2003 <0.5 <0.5 <0.5 <0.5 <2.0 188 <5.0 --
6/22/2004 <5.0 <5.0 <5.0 <5.0 <20.0 148 <50.0 --
1/17/2005 <0.5 <0.5 <0.5 <0.5 <2.0 101 <5.0 --
9/1/2005 <1.0 <1.0 <1.0 <2.0 <5.0 39 <1.0 --
2/1/2006 <1.0 <1.0 <1.0 <2.0 <5.0 46.0 <5.0 --
6/15/2006 <1.0 <1.0 <1.0 <2.0 <5.0 39 <1.0 --
8/21/2007 <1.0 <5.0 <1.0 <3.0 <10.0 41 <1.0 <5.0
2/19/2009 <1.00 <1.00 <1.00 <3.00 <6.00 26.5 <1.00 <1.00
2/8/2011 <1 <1 <1 <1 <4 9.6 <1 <10
11/7/2011 <1 <1 <1 <1 <4 9.0 <1 <10
10/9/2012
7/1/2013
4/7/2014
4/24/2002 <0.5 <0.5 1.2 25 26.2 <10 ----
7/24/2002 <1.0 <1.0 <1.0 <4.0 <7.0 3.0 <1.0 --
11/21/2002 <1.0 <1.0 <1.0 <1.0 <4.0 <5.0 <5.0 --
1/28/2003 <0.5 <0.5 <0.5 <0.5 <2.0 <5.0 <5.0 --
5/28/2003 <1.0 <1.0 <1.0 <4.0 <7.0 <2.0 <1.0 --
11/11/2003 <0.5 <0.5 <0.5 <0.5 <2.0 5.4 <5.0 --
6/22/2004 <0.5 <0.5 <0.5 <0.5 <2.0 5.4 <5.0 --
1/17/2005 <0.5 <0.5 <0.5 <0.5 <2.0 5.0 <5.0 --
8/21/2007 <1.0 <5.0 <1.0 <3.0 <10.0 5.0 <1.0 <5.0
2/19/2009 <1.00 <1.00 <1.00 <3.00 <6.00 9.15 <1.00 1.96
2/8/2011
10/9/2012
7/1/20134/7/2014 <0.50 <0.50 <0.50 <1.50 <3.0 2.5 <0.50 <2.0
1 600 600 500 NE 20 70 6
5,000 260,000 84,500 85,500 NE 20,000 70,000 6,000
Notes:
1. "<" or ND = Not detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (µg/l) = parts per billion.
3. Concentrations in bold print equal or exceed the NCDENR 2L Standard (2L).
4. NCDENR = North Carolina Department of Environment and Natural Resources.
5. GCL = Gross Contaminantion Level.
6. NE = Not Established.
7. MTBE = Methyl Tertiary Butyl Ether.
8. Gross Contamination Levels for Groundwater are referenced in the Guidelines for Assessment
and Corrective Action, November 2008, updated January 2010.
9. BTEX = Benzene, Toluene, Ethylbenzene, Total Xylenes
Not Sampled
Could Not Sample - Bent or Broken Casing
Not Sampled
Not Sampled
MW-3A
Not Sampled
Not Sampled
Not Sampled
Not Sampled
Not SampledEthylbenzeneTotal XylenesTotal BTEXMW-1
MW-2
Analytical Method
Contaminant of Concern
BenzeneTolueneStandard Method 6200B
Isopropyl etherNaphthaleneMTBE2L Standard (µg/l)
GCL (µg/l)
TABLE 4
HISTORICAL GROUNDWATER ANALYTICAL SUMMARY
FORMER CRAVEN OIL
1915 GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATC PROJECT NO. 45.40675.2005
Well ID
Date
Collected EthylbenzeneTotal XylenesTotal BTEXAnalytical Method
Contaminant of Concern
BenzeneTolueneStandard Method 6200B
Isopropyl etherNaphthaleneMTBE4/24/2002 5.1 <0.5 21 10 36.1 13.0 ----
7/24/2002 5.0 1.00 16 8 30.0 11.0 <1.0 --
11/21/2002 1.5 <1.0 24 3.7 29.2 <5 <5 --
1/28/2003 2.3 <0.5 29 1.5 32.8 <5 <5 --
5/28/2003 1.3 <1.0 12 <4.0 13.3 <2.0 <1.0 --
11/11/2003 0.8 <0.5 7.9 0.8 9.5 <5.0 <5.0 --
6/22/2004 0.8 <0.5 2.6 <0.5 3.4 <5.0 <5.0 --
1/17/2005 <0.5 <0.5 3.1 0.5 3.6 <5.0 <5.0 --
9/1/2005 <1.0 <1.0 4.9 <2.0 4.9 <2.0 <1.0 --
2/1/2006 <0.5 <1.0 3.8 <3.0 3.8 <5.0 <5.0 --
6/15/2006 <0.5 <1.0 6.3 <3.0 6.3 <5.0 <1.0 --
8/21/2007 <1.0 <5.0 <1.0 <3.0 <10.0 <1.0 <1.0 27.00
2/6/2008 <1.0 <1.0 <1.0 <4.0 <7.0 <2.0 <1.0 19.5
8/19/2008 <4.00 <4.00 <4.00 <16.00 <28.00 <8.00 <4.00 42.1
2/19/2009 <1.00 1.17 <1.00 <3.00 1.17 <1.00 <1.00 34.9
8/11/2009 <1.00 <1.00 <1.00 <4.00 <7.00 <2.00 <1.00 67.1
2/17/2010 <1.0 <1.0 <1.0 <2.0 <5.0 <1.0 <1.0 27.3
8/9/2010 <4.00 <4.00 <4.00 <16.00 <28.00 <8.00 <4.00 46.9
2/8/2011 <1 <1 <1 <1 <4 <1 <1 48
11/7/2011 <1 <1 <1 <1 <4 <8 <1 43
10/9/2012 <1 <1 <1 <1 <4 <8 <1 56
7/1/2013 <1 <1 <1 <1 <4 <8 <1 95
4/7/2014 <0.50 <0.50 <0.50 <1.50 <3.0 <0.50 <0.50 11.0
4/24/2002 <0.5 <0.5 <0.5 <0.5 <2.0 91 ----
7/24/2002 <1.0 <1.0 <1.0 <4.0 <7.0 53 <1.0 --
11/21/2002 <1.0 <1.0 <1.0 <1.0 <4.0 61 <5.0 --
1/28/2003 <0.5 <0.5 <0.5 <0.5 <2.0 48 <5.0 --
5/28/2003 <1.0 <1.0 <1.0 <4.0 <7.0 24 <1.0 --
11/11/2003 <0.5 <0.5 <0.5 <0.5 <2.0 24.7 <5.0 --
6/22/2004 <0.5 <0.5 <0.5 <0.5 <2.0 16.7 <5.0 --
1/17/2005 <0.5 <0.5 <0.5 <0.5 <2.0 209 <5.0 --
9/1/2005 <1.0 <1.0 <1.0 <2.0 <5.0 6.2 <1.0 --
2/1/2006 <0.5 <0.5 <0.5 <3.0 <4.5 12 <5.0 --
6/15/2006 <1.0 <1.0 <1.0 <3.0 <6.0 11 <5.0 --
8/21/2007 <1.0 <5.0 <1.0 <3.0 <10.0 16 <1.0 <5.0
2/19/2009 <1.00 <1.00 <1.00 <3.00 <6.00 10.2 <1.00 <1.00
2/8/2011
10/9/2012
7/1/20134/7/2014
1 600 600 500 NE 20 70 6
5,000 260,000 84,500 85,500 NE 20,000 70,000 6,000
Notes:
1. "<" or ND = Not detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (µg/l) = parts per billion.
3. Concentrations in bold print equal or exceed the NCDENR 2L Standard (2L).
4. NCDENR = North Carolina Department of Environment and Natural Resources.
5. GCL = Gross Contaminantion Level.
6. NE = Not Established.
7. MTBE = Methyl Tertiary Butyl Ether.
8. Gross Contamination Levels for Groundwater are referenced in the Guidelines for Assessment
and Corrective Action, November 2008, updated January 2010.
9. BTEX = Benzene, Toluene, Ethylbenzene, Total Xylenes
Well Not Accessible - Vehicle Parked Over
Not Sampled
Not Sampled
MW-4A
Not Sampled
2L Standard (µg/l)
GCL (µg/l)
MW-5A
TABLE 4
HISTORICAL GROUNDWATER ANALYTICAL SUMMARY
FORMER CRAVEN OIL
1915 GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATC PROJECT NO. 45.40675.2005
Well ID
Date
Collected EthylbenzeneTotal XylenesTotal BTEXAnalytical Method
Contaminant of Concern
BenzeneTolueneStandard Method 6200B
Isopropyl etherNaphthaleneMTBE4/24/2002 <0.5 <0.5 <0.5 <0.5 <2.0 337 ----
7/24/2002 <1.0 <1.0 <1.0 <4.0 <7.0 190 <1.0 --
11/21/2002 <1.0 <1.0 <1.0 <1.0 <4.0 93 <5.0 --
1/28/2003 <0.5 <0.5 <0.5 <0.5 <2.0 260 <5.0 --
5/28/2003 <1.0 <1.0 <1.0 <4.0 <7.0 130 <1.0 --
11/11/2003 <0.5 <0.5 <0.5 <0.5 <2.0 250 <5.0 --
6/22/2004 <0.5 <0.5 <0.5 <0.5 <2.0 177 <5.0 --
1/17/2005 <0.5 <0.5 <0.5 <0.5 <2.0 129 <5.0 --
9/1/2005 <1.0 <1.0 <1.0 <2.0 <5.0 31 <1.0 --
6/15/2006 <1.0 <1.0 <1.0 <3.0 <6.0 22 <1.0 --
8/21/2007 <1.0 <5.0 <1.0 <3.0 <10.0 9.7 <1.0 <5.0
2/19/2009 <1.00 <1.00 <1.00 <3.00 <6.00 4.50 <1.00 <1.00
2/8/2011
10/9/2012
7/1/2013
4/7/2014
4/24/2002 149 279 289 1,810 2,527 <100 ----
7/24/2002 290 570 430 2,650 3,940 81 <40 --
11/21/2002 119 115 325 1,270 1,829 <50 <50 --
1/28/2003 80 16 366 177 639 <25 <25 --
5/28/2003 34 3 240 54 331 4.7 <1.0 --
11/11/2003 23.3 <0.5 214 59 296.3 <5.0 <5.0 --
6/22/2004 14.8 <5.0 1,789 19.5 1,823.8 <50.0 <50 --
1/17/2005 23.4 6.3 233 159 421.7 <50.0 <50 --
9/1/2005 <1.0 <1.0 8 <2.0 8 <2.0 <1.0 --
8/21/2007 11 <5.0 140 100 251 4.2 <1.0 140
2/6/2008 3.36 <2.0 64.4 21.1 88.9 <4.0 <2.0 56.1
8/19/2008 <16.0 <16.0 270 184 454 <32.0 <16.0 274
2/19/2009 <10.0 <10.0 149 84 233 <10.0 <10.0 148
8/11/2009 7.67 <1.00 <1.00 <4.00 7.67 <2.00 <1.00 142
2/17/2010 4.2 <2.0 85.9 <4.0 90.1 <2.0 <2.0 87.4
8/9/2010 1.12 <1.00 <1.00 <4.00 1.12 <2.00 <1.00 3.53
2/8/2011 1.3 <1 5.8 <1 7.1 <8 <1 <10
11/7/2011 1.6 <1 22 1.6 25.2 <8 <1 22
10/9/2012 <1 <1 28 <1 28 <8 <1 21
7/1/2013 1.2 <1 59 <1 60.2 <8 <1 47
4/7/2014 0.76 <0.50 61.7 1.84 64.30 <0.50 <0.50 7.8
1 600 600 500 NE 20 70 6
5,000 260,000 84,500 85,500 NE 20,000 70,000 6,000
Notes:
1. "<" or ND = Not detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (µg/l) = parts per billion.
3. Concentrations in bold print equal or exceed the NCDENR 2L Standard (2L).
4. NCDENR = North Carolina Department of Environment and Natural Resources.
5. GCL = Gross Contaminantion Level.
6. NE = Not Established.
7. MTBE = Methyl Tertiary Butyl Ether.
8. Gross Contamination Levels for Groundwater are referenced in the Guidelines for Assessment
and Corrective Action, November 2008, updated January 2010.
9. BTEX = Benzene, Toluene, Ethylbenzene, Total Xylenes
Not Sampled
Well Not Accessible - Vehicle Parked Over
Not Sampled
2L Standard (µg/l)
Not Sampled
GCL (µg/l)
MW-6
MW-7A
TABLE 4
HISTORICAL GROUNDWATER ANALYTICAL SUMMARY
FORMER CRAVEN OIL
1915 GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATC PROJECT NO. 45.40675.2005
Well ID
Date
Collected EthylbenzeneTotal XylenesTotal BTEXAnalytical Method
Contaminant of Concern
BenzeneTolueneStandard Method 6200B
Isopropyl etherNaphthaleneMTBE4/24/2002 <0.5 <0.5 <0.5 <0.5 <2.0 <10 ----
7/24/2002 <1.0 <1.0 <1.0 <4.0 <7.0 <2.0 <1.0 --
11/21/2002 <1.0 <1.0 <1.0 <1.0 <4.0 <5.0 <5.0 --
1/28/2003 <0.5 <0.5 <0.5 <0.5 <2.0 <5.0 <5.0 --
5/28/2003 <1.0 <1.0 <1.0 <4.0 <7.0 <2.0 <1.0 --
11/11/2003 <0.5 <0.5 <0.5 <0.5 <2.0 <5.0 <5.0 --
6/22/2004 <0.5 <0.5 <0.5 <0.5 <2.0 <5.0 <5.0 --
1/17/2005 <0.5 <0.5 <0.5 <0.5 <2.0 <5.0 <5.0 --
9/1/2005 <1.0 <1.0 <1.0 <2.0 <5.0 <2.0 <1.0 --
2/1/2006 <1.0 <1.0 <1.0 <3.0 <6.0 <5.0 <5.0 --
2/19/2009 <1.00 <1.00 <1.00 <3.00 <6.00 <1.00 <1.00 <1.00
2/8/2011 <1 <1 <1 <1 <4 <8 <1 <10
10/9/2012
7/1/2013
4/7/2014
1 600 600 500 NE 20 70 6
5,000 260,000 84,500 85,500 NE 20,000 70,000 6,000
Notes:
1. "<" or ND = Not detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (µg/l) = parts per billion.
3. Concentrations in bold print equal or exceed the NCDENR 2L Standard (2L).
4. NCDENR = North Carolina Department of Environment and Natural Resources.
5. GCL = Gross Contaminantion Level.
6. NE = Not Established.
7. MTBE = Methyl Tertiary Butyl Ether.
8. Gross Contamination Levels for Groundwater are referenced in the Guidelines for Assessment
and Corrective Action, November 2008, updated January 2010.
9. BTEX = Benzene, Toluene, Ethylbenzene, Total Xylenes
Not Sampled
Not Sampled
Not Sampled
GCL (µg/l)
2L Standard (µg/l)
T-1A
TABLE 5
WATER SUPPLY WELL ANALYTICAL SUMMARY
FORMER CRAVEN OIL
1915 GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY, NORTH CAROLINA
NCDENR INCIDENT NO. 17830
ATC PROJECT NO. 45.40675.2005
Sample ID
Date
Collected
8/9/2010 <1.00 <1.00 <1.00 <4.00 <7.00 <2.00 <1.00 <1.00
2/8/2011 <1 <1 <1 <1 ND <8 <1 <10
10/9/2012
7/1/2013
4/7/2014
5 1,000 700 10,000 NE NE NE NE
Notes:
1. "<" or ND = Not detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (µg/l) = parts per billion.
3. US EPA MCLs denotes United States Environmental Protection Agency Maximum Contaminant Levels.
4. NE = Not Established.
5. MTBE = Methyl Tertiary Butyl Ether.
6. BTEX = Benzene, Toluene, Ethylbenzene, Total Xylenes
Martin's
Auto
(Potable)
Property owner would not allow well to be sampled NaphthaleneNot Sampled
US EPA MCLs
Not Sampled
Analytical Method Standard Method 6200B
Contaminant of
Concern
BenzeneTolueneEthylbenzeneTotal XylenesTotal BTEXMTBEIsopropyl ether

FIGURES
2725 E. Millbrook Road, Ste 121
Raleigh, NC 27604
[phone]
PROJECT NO: 45.40675.2005
DATE: 3/2011 REVIEWED BY: EAA
FORMER CRAVEN OIL
1915 SOUTH GLENBURNIE ROAD
NEW BERN, CRAVEN COUNTY,
NORTH CAROLINA
SOURCE: 1994 TOPOGRAPHIC MAP - MSRMAPS.COM.
SCALE: SEE ABOVE
SITE
FIGURE 1: SITE TOPOGRAPHIC MAP

APPENDIX A

LABORATORY ANALYTICAL RESULTS

#=CL#
April 21, 2014
LIMS USE: FR - MAUREEN JACKSON
LIMS OBJECT ID: 92196391
92196391
Project:
Pace Project No.:
RE:
Maureen JacksonCardno AtC2725 E. Millbrook RoadSuite 121Raleigh, NC 27604
045.40675.2005 (Craven Oil)
Dear Maureen Jackson:
Enclosed are the analytical results for sample(s) received by the laboratory on April 08, 2014. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analytepage for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 23
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 23
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92196391001 MW7A SM 6200B 63 PASI-CCAH
92196391002 MW4A SM 6200B 63 PASI-CCAH
92196391003 MW3A SM 6200B 63 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Sample:MW7A Lab ID:92196391001 Collected:04/07/14 13:25 Received:04/08/14 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 0.76 ug/L 04/09/14 21:21 71-43-20.50 1
Bromobenzene ND ug/L 04/09/14 21:21 108-86-10.50 1
Bromochloromethane ND ug/L 04/09/14 21:21 74-97-50.50 1
Bromodichloromethane ND ug/L 04/09/14 21:21 75-27-40.50 1
Bromoform ND ug/L 04/09/14 21:21 75-25-20.50 1
Bromomethane ND ug/L 04/09/14 21:21 74-83-95.0 1
n-Butylbenzene ND ug/L 04/09/14 21:21 104-51-80.50 1
sec-Butylbenzene ND ug/L 04/09/14 21:21 135-98-80.50 1
tert-Butylbenzene ND ug/L 04/09/14 21:21 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/09/14 21:21 56-23-50.50 1
Chlorobenzene ND ug/L 04/09/14 21:21 108-90-70.50 1
Chloroethane ND ug/L 04/09/14 21:21 75-00-31.0 1
Chloroform ND ug/L 04/09/14 21:21 67-66-30.50 1
Chloromethane ND ug/L 04/09/14 21:21 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/09/14 21:21 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/09/14 21:21 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/09/14 21:21 96-12-81.0 1
Dibromochloromethane ND ug/L 04/09/14 21:21 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/09/14 21:21 106-93-40.50 1
Dibromomethane ND ug/L 04/09/14 21:21 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/09/14 21:21 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/09/14 21:21 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/09/14 21:21 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/09/14 21:21 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/09/14 21:21 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/09/14 21:21 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/09/14 21:21 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/09/14 21:21 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/09/14 21:21 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/09/14 21:21 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/09/14 21:21 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/09/14 21:21 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/09/14 21:21 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/09/14 21:21 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/09/14 21:21 10061-02-60.50 1
Diisopropyl ether ND ug/L 04/09/14 21:21 108-20-30.50 1
Ethylbenzene 61.7 ug/L 04/09/14 21:21 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/09/14 21:21 87-68-32.0 1
Isopropylbenzene (Cumene)4.3 ug/L 04/09/14 21:21 98-82-80.50 1
Methylene Chloride ND ug/L 04/09/14 21:21 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 04/09/14 21:21 1634-04-40.50 1
Naphthalene 7.8 ug/L 04/09/14 21:21 91-20-32.0 1
n-Propylbenzene 7.3 ug/L 04/09/14 21:21 103-65-10.50 1
Styrene ND ug/L 04/09/14 21:21 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/09/14 21:21 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/09/14 21:21 79-34-50.50 1
Tetrachloroethene ND ug/L 04/09/14 21:21 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Sample:MW7A Lab ID:92196391001 Collected:04/07/14 13:25 Received:04/08/14 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 04/09/14 21:21 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/09/14 21:21 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/09/14 21:21 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/09/14 21:21 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/09/14 21:21 79-00-50.50 1
Trichloroethene ND ug/L 04/09/14 21:21 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/09/14 21:21 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/09/14 21:21 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/09/14 21:21 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/09/14 21:21 108-67-80.50 1
Vinyl chloride ND ug/L 04/09/14 21:21 75-01-41.0 1
m&p-Xylene 1.0 ug/L 04/09/14 21:21 179601-23-11.0 1
o-Xylene 0.84 ug/L 04/09/14 21:21 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %04/09/14 21:21 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %04/09/14 21:21 460-00-470-130 1
Toluene-d8 (S)101 %04/09/14 21:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Sample:MW4A Lab ID:92196391002 Collected:04/07/14 13:55 Received:04/08/14 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 04/17/14 00:13 71-43-20.50 1
Bromobenzene ND ug/L 04/17/14 00:13 108-86-10.50 1
Bromochloromethane ND ug/L 04/17/14 00:13 74-97-50.50 1
Bromodichloromethane ND ug/L 04/17/14 00:13 75-27-40.50 1
Bromoform ND ug/L 04/17/14 00:13 75-25-20.50 1
Bromomethane ND ug/L 04/17/14 00:13 74-83-95.0 1
n-Butylbenzene 1.3 ug/L 04/17/14 00:13 104-51-80.50 1
sec-Butylbenzene 4.2 ug/L 04/17/14 00:13 135-98-80.50 1
tert-Butylbenzene 1.0 ug/L 04/17/14 00:13 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/17/14 00:13 56-23-50.50 1
Chlorobenzene ND ug/L 04/17/14 00:13 108-90-70.50 1
Chloroethane ND ug/L 04/17/14 00:13 75-00-31.0 1
Chloroform ND ug/L 04/17/14 00:13 67-66-30.50 1
Chloromethane ND ug/L 04/17/14 00:13 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/17/14 00:13 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/17/14 00:13 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/17/14 00:13 96-12-81.0 1
Dibromochloromethane ND ug/L 04/17/14 00:13 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/17/14 00:13 106-93-40.50 1
Dibromomethane ND ug/L 04/17/14 00:13 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/17/14 00:13 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/17/14 00:13 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/17/14 00:13 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/17/14 00:13 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/17/14 00:13 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/17/14 00:13 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/17/14 00:13 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/17/14 00:13 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/17/14 00:13 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/17/14 00:13 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/17/14 00:13 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/17/14 00:13 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/17/14 00:13 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/17/14 00:13 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/17/14 00:13 10061-02-60.50 1
Diisopropyl ether ND ug/L 04/17/14 00:13 108-20-30.50 1
Ethylbenzene ND ug/L 04/17/14 00:13 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/17/14 00:13 87-68-32.0 1
Isopropylbenzene (Cumene)4.8 ug/L 04/17/14 00:13 98-82-80.50 1
Methylene Chloride ND ug/L 04/17/14 00:13 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 04/17/14 00:13 1634-04-40.50 1
Naphthalene 11.0 ug/L 04/17/14 00:13 91-20-32.0 1
n-Propylbenzene 6.0 ug/L 04/17/14 00:13 103-65-10.50 1
Styrene ND ug/L 04/17/14 00:13 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/17/14 00:13 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/17/14 00:13 79-34-50.50 1
Tetrachloroethene ND ug/L 04/17/14 00:13 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Sample:MW4A Lab ID:92196391002 Collected:04/07/14 13:55 Received:04/08/14 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 04/17/14 00:13 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/17/14 00:13 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/17/14 00:13 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/17/14 00:13 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/17/14 00:13 79-00-50.50 1
Trichloroethene ND ug/L 04/17/14 00:13 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/17/14 00:13 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/17/14 00:13 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/17/14 00:13 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/17/14 00:13 108-67-80.50 1
Vinyl chloride ND ug/L 04/17/14 00:13 75-01-41.0 1
m&p-Xylene ND ug/L 04/17/14 00:13 179601-23-11.0 1
o-Xylene ND ug/L 04/17/14 00:13 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %04/17/14 00:13 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/17/14 00:13 460-00-470-130 1
Toluene-d8 (S)101 %04/17/14 00:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Sample:MW3A Lab ID:92196391003 Collected:04/07/14 13:00 Received:04/08/14 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 04/09/14 20:48 71-43-20.50 1
Bromobenzene ND ug/L 04/09/14 20:48 108-86-10.50 1
Bromochloromethane ND ug/L 04/09/14 20:48 74-97-50.50 1
Bromodichloromethane ND ug/L 04/09/14 20:48 75-27-40.50 1
Bromoform ND ug/L 04/09/14 20:48 75-25-20.50 1
Bromomethane ND ug/L 04/09/14 20:48 74-83-95.0 1
n-Butylbenzene ND ug/L 04/09/14 20:48 104-51-80.50 1
sec-Butylbenzene ND ug/L 04/09/14 20:48 135-98-80.50 1
tert-Butylbenzene ND ug/L 04/09/14 20:48 98-06-60.50 1
Carbon tetrachloride ND ug/L 04/09/14 20:48 56-23-50.50 1
Chlorobenzene ND ug/L 04/09/14 20:48 108-90-70.50 1
Chloroethane ND ug/L 04/09/14 20:48 75-00-31.0 1
Chloroform ND ug/L 04/09/14 20:48 67-66-30.50 1
Chloromethane ND ug/L 04/09/14 20:48 74-87-31.0 1
2-Chlorotoluene ND ug/L 04/09/14 20:48 95-49-80.50 1
4-Chlorotoluene ND ug/L 04/09/14 20:48 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 04/09/14 20:48 96-12-81.0 1
Dibromochloromethane ND ug/L 04/09/14 20:48 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 04/09/14 20:48 106-93-40.50 1
Dibromomethane ND ug/L 04/09/14 20:48 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 04/09/14 20:48 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 04/09/14 20:48 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 04/09/14 20:48 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 04/09/14 20:48 75-71-80.50 1
1,1-Dichloroethane ND ug/L 04/09/14 20:48 75-34-30.50 1
1,2-Dichloroethane ND ug/L 04/09/14 20:48 107-06-20.50 1
1,1-Dichloroethene ND ug/L 04/09/14 20:48 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 04/09/14 20:48 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 04/09/14 20:48 156-60-50.50 1
1,2-Dichloropropane ND ug/L 04/09/14 20:48 78-87-50.50 1
1,3-Dichloropropane ND ug/L 04/09/14 20:48 142-28-90.50 1
2,2-Dichloropropane ND ug/L 04/09/14 20:48 594-20-70.50 1
1,1-Dichloropropene ND ug/L 04/09/14 20:48 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 04/09/14 20:48 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 04/09/14 20:48 10061-02-60.50 1
Diisopropyl ether ND ug/L 04/09/14 20:48 108-20-30.50 1
Ethylbenzene ND ug/L 04/09/14 20:48 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 04/09/14 20:48 87-68-32.0 1
Isopropylbenzene (Cumene)0.65 ug/L 04/09/14 20:48 98-82-80.50 1
Methylene Chloride ND ug/L 04/09/14 20:48 75-09-22.0 1
Methyl-tert-butyl ether 2.5 ug/L 04/09/14 20:48 1634-04-40.50 1
Naphthalene ND ug/L 04/09/14 20:48 91-20-32.0 1
n-Propylbenzene ND ug/L 04/09/14 20:48 103-65-10.50 1
Styrene ND ug/L 04/09/14 20:48 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 04/09/14 20:48 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 04/09/14 20:48 79-34-50.50 1
Tetrachloroethene ND ug/L 04/09/14 20:48 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
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Page 8 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Sample:MW3A Lab ID:92196391003 Collected:04/07/14 13:00 Received:04/08/14 09:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene ND ug/L 04/09/14 20:48 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 04/09/14 20:48 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 04/09/14 20:48 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 04/09/14 20:48 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 04/09/14 20:48 79-00-50.50 1
Trichloroethene ND ug/L 04/09/14 20:48 79-01-60.50 1
Trichlorofluoromethane ND ug/L 04/09/14 20:48 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 04/09/14 20:48 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 04/09/14 20:48 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 04/09/14 20:48 108-67-80.50 1
Vinyl chloride ND ug/L 04/09/14 20:48 75-01-41.0 1
m&p-Xylene ND ug/L 04/09/14 20:48 179601-23-11.0 1
o-Xylene ND ug/L 04/09/14 20:48 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %04/09/14 20:48 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/09/14 20:48 460-00-470-130 1
Toluene-d8 (S)102 %04/09/14 20:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
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[phone]
Page 9 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/26386
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92196391001, 92196391003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1174836
Associated Lab Samples:92196391001, 92196391003
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/09/14 16:08
1,1,1-Trichloroethane ug/L ND 0.50 04/09/14 16:08
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/09/14 16:08
1,1,2-Trichloroethane ug/L ND 0.50 04/09/14 16:08
1,1-Dichloroethane ug/L ND 0.50 04/09/14 16:08
1,1-Dichloroethene ug/L ND 0.50 04/09/14 16:08
1,1-Dichloropropene ug/L ND 0.50 04/09/14 16:08
1,2,3-Trichlorobenzene ug/L ND 2.0 04/09/14 16:08
1,2,3-Trichloropropane ug/L ND 0.50 04/09/14 16:08
1,2,4-Trichlorobenzene ug/L ND 2.0 04/09/14 16:08
1,2,4-Trimethylbenzene ug/L ND 0.50 04/09/14 16:08
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/09/14 16:08
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/09/14 16:08
1,2-Dichlorobenzene ug/L ND 0.50 04/09/14 16:08
1,2-Dichloroethane ug/L ND 0.50 04/09/14 16:08
1,2-Dichloropropane ug/L ND 0.50 04/09/14 16:08
1,3,5-Trimethylbenzene ug/L ND 0.50 04/09/14 16:08
1,3-Dichlorobenzene ug/L ND 0.50 04/09/14 16:08
1,3-Dichloropropane ug/L ND 0.50 04/09/14 16:08
1,4-Dichlorobenzene ug/L ND 0.50 04/09/14 16:08
2,2-Dichloropropane ug/L ND 0.50 04/09/14 16:08
2-Chlorotoluene ug/L ND 0.50 04/09/14 16:08
4-Chlorotoluene ug/L ND 0.50 04/09/14 16:08
Benzene ug/L ND 0.50 04/09/14 16:08
Bromobenzene ug/L ND 0.50 04/09/14 16:08
Bromochloromethane ug/L ND 0.50 04/09/14 16:08
Bromodichloromethane ug/L ND 0.50 04/09/14 16:08
Bromoform ug/L ND 0.50 04/09/14 16:08
Bromomethane ug/L ND 5.0 04/09/14 16:08
Carbon tetrachloride ug/L ND 0.50 04/09/14 16:08
Chlorobenzene ug/L ND 0.50 04/09/14 16:08
Chloroethane ug/L ND 1.0 04/09/14 16:08
Chloroform ug/L ND 0.50 04/09/14 16:08
Chloromethane ug/L ND 1.0 04/09/14 16:08
cis-1,2-Dichloroethene ug/L ND 0.50 04/09/14 16:08
cis-1,3-Dichloropropene ug/L ND 0.50 04/09/14 16:08
Dibromochloromethane ug/L ND 0.50 04/09/14 16:08
Dibromomethane ug/L ND 0.50 04/09/14 16:08
Dichlorodifluoromethane ug/L ND 0.50 04/09/14 16:08
Diisopropyl ether ug/L ND 0.50 04/09/14 16:08
Ethylbenzene ug/L ND 0.50 04/09/14 16:08
Hexachloro-1,3-butadiene ug/L ND 2.0 04/09/14 16:08
Isopropylbenzene (Cumene)ug/L ND 0.50 04/09/14 16:08
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 10 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1174836
Associated Lab Samples:92196391001, 92196391003
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 04/09/14 16:08
Methyl-tert-butyl ether ug/L ND 0.50 04/09/14 16:08
Methylene Chloride ug/L ND 2.0 04/09/14 16:08
n-Butylbenzene ug/L ND 0.50 04/09/14 16:08
n-Propylbenzene ug/L ND 0.50 04/09/14 16:08
Naphthalene ug/L ND 2.0 04/09/14 16:08
o-Xylene ug/L ND 0.50 04/09/14 16:08
sec-Butylbenzene ug/L ND 0.50 04/09/14 16:08
Styrene ug/L ND 0.50 04/09/14 16:08
tert-Butylbenzene ug/L ND 0.50 04/09/14 16:08
Tetrachloroethene ug/L ND 0.50 04/09/14 16:08
Toluene ug/L ND 0.50 04/09/14 16:08
trans-1,2-Dichloroethene ug/L ND 0.50 04/09/14 16:08
trans-1,3-Dichloropropene ug/L ND 0.50 04/09/14 16:08
Trichloroethene ug/L ND 0.50 04/09/14 16:08
Trichlorofluoromethane ug/L ND 1.0 04/09/14 16:08
Vinyl chloride ug/L ND 1.0 04/09/14 16:08
1,2-Dichloroethane-d4 (S)%96 70-130 04/09/14 16:08
4-Bromofluorobenzene (S)%99 70-130 04/09/14 16:08
Toluene-d8 (S)%103 70-130 04/09/14 16:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1174837LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 56.450 113 60-140
1,1,1-Trichloroethane ug/L 53.650 107 60-140
1,1,2,2-Tetrachloroethane ug/L 47.850 96 60-140
1,1,2-Trichloroethane ug/L 53.850 108 60-140
1,1-Dichloroethane ug/L 49.850 100 60-140
1,1-Dichloroethene ug/L 50.550 101 60-140
1,1-Dichloropropene ug/L 52.450 105 60-140
1,2,3-Trichlorobenzene ug/L 55.450 111 60-140
1,2,3-Trichloropropane ug/L 48.850 98 60-140
1,2,4-Trichlorobenzene ug/L 53.050 106 60-140
1,2,4-Trimethylbenzene ug/L 55.350 111 60-140
1,2-Dibromo-3-chloropropane ug/L 65.650 131 60-140
1,2-Dibromoethane (EDB)ug/L 55.750 111 60-140
1,2-Dichlorobenzene ug/L 53.150 106 60-140
1,2-Dichloroethane ug/L 50.950 102 60-140
1,2-Dichloropropane ug/L 51.650 103 60-140
1,3,5-Trimethylbenzene ug/L 51.950 104 60-140
1,3-Dichlorobenzene ug/L 52.850 106 60-140
1,3-Dichloropropane ug/L 52.850 106 60-140
1,4-Dichlorobenzene ug/L 52.450 105 60-140
2,2-Dichloropropane ug/L 56.050 112 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
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[phone]
Page 11 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1174837LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorotoluene ug/L 48.250 96 60-140
4-Chlorotoluene ug/L 52.050 104 60-140
Benzene ug/L 51.850 104 60-140
Bromobenzene ug/L 50.050 100 60-140
Bromochloromethane ug/L 48.950 98 60-140
Bromodichloromethane ug/L 57.050 114 60-140
Bromoform ug/L 47.350 95 60-140
Bromomethane ug/L 50.950 102 60-140
Carbon tetrachloride ug/L 55.650 111 60-140
Chlorobenzene ug/L 51.150 102 60-140
Chloroethane ug/L 43.950 88 60-140
Chloroform ug/L 50.850 102 60-140
Chloromethane ug/L 44.650 89 60-140
cis-1,2-Dichloroethene ug/L 49.750 99 60-140
cis-1,3-Dichloropropene ug/L 58.150 116 60-140
Dibromochloromethane ug/L 50.450 101 60-140
Dibromomethane ug/L 52.850 106 60-140
Dichlorodifluoromethane ug/L 54.850 110 60-140
Diisopropyl ether ug/L 50.450 101 60-140
Ethylbenzene ug/L 51.550 103 60-140
Hexachloro-1,3-butadiene ug/L 54.050 108 60-140
Isopropylbenzene (Cumene)ug/L 54.350 109 60-140
m&p-Xylene ug/L 108100 108 60-140
Methyl-tert-butyl ether ug/L 52.450 105 60-140
Methylene Chloride ug/L 51.150 102 60-140
n-Butylbenzene ug/L 54.450 109 60-140
n-Propylbenzene ug/L 53.050 106 60-140
Naphthalene ug/L 56.950 114 60-140
o-Xylene ug/L 52.650 105 60-140
sec-Butylbenzene ug/L 55.250 110 60-140
Styrene ug/L 56.250 112 60-140
tert-Butylbenzene ug/L 54.650 109 60-140
Tetrachloroethene ug/L 52.650 105 60-140
Toluene ug/L 51.850 104 60-140
trans-1,2-Dichloroethene ug/L 49.950 100 60-140
trans-1,3-Dichloropropene ug/L 60.150 120 60-140
Trichloroethene ug/L 51.750 103 60-140
Trichlorofluoromethane ug/L 49.050 98 60-140
Vinyl chloride ug/L 49.150 98 60-140
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%95 70-130
Toluene-d8 (S)%103 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
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[phone]
Page 12 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1174838MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92196502002
1174839
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 113 60-140108 420ND22.5 21.7
1,1,1-Trichloroethane ug/L 20 117 60-140113 420ND23.4 22.5
1,1,2,2-Tetrachloroethane ug/L 20 104 60-14097 720ND20.8 19.5
1,1,2-Trichloroethane ug/L 20 110 60-140105 520ND22.0 20.9
1,1-Dichloroethane ug/L 20 104 60-140101 320ND20.8 20.2
1,1-Dichloroethene ug/L 20 112 60-140107 520ND22.4 21.3
1,1-Dichloropropene ug/L 20 113 60-140109 420ND22.6 21.8
1,2,3-Trichlorobenzene ug/L 20 103 60-14099 420ND20.7 19.9
1,2,3-Trichloropropane ug/L 20 109 60-140102 720ND21.9 20.4
1,2,4-Trichlorobenzene ug/L 20 99 60-14097 220ND19.9 19.4
1,2,4-Trimethylbenzene ug/L 20 108 60-140106 220ND21.7 21.3
1,2-Dibromo-3-chloropropane ug/L 20 128 60-140121 520ND25.5 24.2
1,2-Dibromoethane (EDB)ug/L 20 111 60-140104 720ND22.3 20.8
1,2-Dichlorobenzene ug/L 20 108 60-140104 320ND21.5 20.8
1,2-Dichloroethane ug/L 20 109 60-140106 320ND21.8 21.1
1,2-Dichloropropane ug/L 20 104 60-14098 620ND20.8 19.6
1,3,5-Trimethylbenzene ug/L 20 110 60-140105 520ND22.1 21.0
1,3-Dichlorobenzene ug/L 20 104 60-140103 120ND20.8 20.6
1,3-Dichloropropane ug/L 20 105 60-140100 520ND20.9 19.9
1,4-Dichlorobenzene ug/L 20 104 60-140101 320ND20.8 20.1
2,2-Dichloropropane ug/L 20 113 60-140107 520ND22.6 21.4
2-Chlorotoluene ug/L 20 104 60-14097 620ND20.8 19.5
4-Chlorotoluene ug/L 20 108 60-140105 320ND21.6 20.9
Benzene ug/L 20 106 60-140101 420ND21.2 20.3
Bromobenzene ug/L 20 104 60-140100 420ND20.8 20.0
Bromochloromethane ug/L 20 103 60-140100 320ND20.6 20.0
Bromodichloromethane ug/L 20 110 60-140106 420ND22.0 21.3
Bromoform ug/L 20 91 60-14087 520ND18.2 17.3
Bromomethane ug/L 20 88 60-14097 920ND17.7 19.4
Carbon tetrachloride ug/L 20 116 60-140112 420ND23.2 22.4
Chlorobenzene ug/L 20 106 60-140101 420ND21.1 20.2
Chloroethane ug/L 20 106 60-14099 720ND21.2 19.8
Chloroform ug/L 20 108 60-140104 420ND21.6 20.7
Chloromethane ug/L 20 96 60-14091 520ND19.3 18.2
cis-1,2-Dichloroethene ug/L 20 105 60-14099 620ND21.1 19.9
cis-1,3-Dichloropropene ug/L 20 105 60-140104 120ND20.9 20.8
Dibromochloromethane ug/L 20 97 60-14093 420ND19.4 18.6
Dibromomethane ug/L 20 105 60-140102 320ND21.0 20.4
Dichlorodifluoromethane ug/L 20 127 60-140121 520ND25.4 24.1
Diisopropyl ether ug/L 20 103 60-14099 420ND20.7 19.8
Ethylbenzene ug/L 20 107 60-140103 320ND21.3 20.6
Hexachloro-1,3-butadiene ug/L 20 107 60-140105 220ND21.4 21.0
Isopropylbenzene (Cumene)ug/L 20 114 60-140110 420ND22.9 22.0
m&p-Xylene ug/L 40 111 60-140108 340ND44.3 43.2
Methyl-tert-butyl ether ug/L 20 107 60-140102 420ND21.3 20.4
Methylene Chloride ug/L 20 100 60-14096 420ND20.0 19.2
n-Butylbenzene ug/L 20 106 60-140103 220ND21.1 20.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
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Page 13 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1174838MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92196502002
1174839
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 113 60-140111 220ND22.6 22.2
Naphthalene ug/L 20 110 60-140104 620ND21.9 20.7
o-Xylene ug/L 20 111 60-140106 5200.77 22.9 21.9
sec-Butylbenzene ug/L 20 111 60-140109 220ND22.3 21.9
Styrene ug/L 20 110 60-140107 320ND22.0 21.3
tert-Butylbenzene ug/L 20 114 60-140111 320ND22.7 22.1
Tetrachloroethene ug/L 20 109 60-140107 220ND21.8 21.4
Toluene ug/L 20 105 60-140101 420ND21.0 20.1
trans-1,2-Dichloroethene ug/L 20 104 60-140101 320ND20.8 20.2
trans-1,3-Dichloropropene ug/L 20 108 60-140105 320ND21.6 21.1
Trichloroethene ug/L 20 109 60-140104 520ND21.8 20.8
Trichlorofluoromethane ug/L 20 116 60-140115 120ND23.1 22.9
Vinyl chloride ug/L 20 106 60-14099 720ND21.3 19.8
1,2-Dichloroethane-d4 (S)%98 70-13099
4-Bromofluorobenzene (S)%102 70-130101
Toluene-d8 (S)%101 70-130101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
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Page 14 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/26469
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92196391002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1179318
Associated Lab Samples:92196391002
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/16/14 19:32
1,1,1-Trichloroethane ug/L ND 0.50 04/16/14 19:32
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/16/14 19:32
1,1,2-Trichloroethane ug/L ND 0.50 04/16/14 19:32
1,1-Dichloroethane ug/L ND 0.50 04/16/14 19:32
1,1-Dichloroethene ug/L ND 0.50 04/16/14 19:32
1,1-Dichloropropene ug/L ND 0.50 04/16/14 19:32
1,2,3-Trichlorobenzene ug/L ND 2.0 04/16/14 19:32
1,2,3-Trichloropropane ug/L ND 0.50 04/16/14 19:32
1,2,4-Trichlorobenzene ug/L ND 2.0 04/16/14 19:32
1,2,4-Trimethylbenzene ug/L ND 0.50 04/16/14 19:32
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/16/14 19:32
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/16/14 19:32
1,2-Dichlorobenzene ug/L ND 0.50 04/16/14 19:32
1,2-Dichloroethane ug/L ND 0.50 04/16/14 19:32
1,2-Dichloropropane ug/L ND 0.50 04/16/14 19:32
1,3,5-Trimethylbenzene ug/L ND 0.50 04/16/14 19:32
1,3-Dichlorobenzene ug/L ND 0.50 04/16/14 19:32
1,3-Dichloropropane ug/L ND 0.50 04/16/14 19:32
1,4-Dichlorobenzene ug/L ND 0.50 04/16/14 19:32
2,2-Dichloropropane ug/L ND 0.50 04/16/14 19:32
2-Chlorotoluene ug/L ND 0.50 04/16/14 19:32
4-Chlorotoluene ug/L ND 0.50 04/16/14 19:32
Benzene ug/L ND 0.50 04/16/14 19:32
Bromobenzene ug/L ND 0.50 04/16/14 19:32
Bromochloromethane ug/L ND 0.50 04/16/14 19:32
Bromodichloromethane ug/L ND 0.50 04/16/14 19:32
Bromoform ug/L ND 0.50 04/16/14 19:32
Bromomethane ug/L ND 5.0 04/16/14 19:32
Carbon tetrachloride ug/L ND 0.50 04/16/14 19:32
Chlorobenzene ug/L ND 0.50 04/16/14 19:32
Chloroethane ug/L ND 1.0 04/16/14 19:32
Chloroform ug/L ND 0.50 04/16/14 19:32
Chloromethane ug/L ND 1.0 04/16/14 19:32
cis-1,2-Dichloroethene ug/L ND 0.50 04/16/14 19:32
cis-1,3-Dichloropropene ug/L ND 0.50 04/16/14 19:32
Dibromochloromethane ug/L ND 0.50 04/16/14 19:32
Dibromomethane ug/L ND 0.50 04/16/14 19:32
Dichlorodifluoromethane ug/L ND 0.50 04/16/14 19:32
Diisopropyl ether ug/L ND 0.50 04/16/14 19:32
Ethylbenzene ug/L ND 0.50 04/16/14 19:32
Hexachloro-1,3-butadiene ug/L ND 2.0 04/16/14 19:32
Isopropylbenzene (Cumene)ug/L ND 0.50 04/16/14 19:32
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
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Huntersville, NC 28078
[phone]
Page 15 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1179318
Associated Lab Samples:92196391002
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 04/16/14 19:32
Methyl-tert-butyl ether ug/L ND 0.50 04/16/14 19:32
Methylene Chloride ug/L ND 2.0 04/16/14 19:32
n-Butylbenzene ug/L ND 0.50 04/16/14 19:32
n-Propylbenzene ug/L ND 0.50 04/16/14 19:32
Naphthalene ug/L ND 2.0 04/16/14 19:32
o-Xylene ug/L ND 0.50 04/16/14 19:32
sec-Butylbenzene ug/L ND 0.50 04/16/14 19:32
Styrene ug/L ND 0.50 04/16/14 19:32
tert-Butylbenzene ug/L ND 0.50 04/16/14 19:32
Tetrachloroethene ug/L ND 0.50 04/16/14 19:32
Toluene ug/L ND 0.50 04/16/14 19:32
trans-1,2-Dichloroethene ug/L ND 0.50 04/16/14 19:32
trans-1,3-Dichloropropene ug/L ND 0.50 04/16/14 19:32
Trichloroethene ug/L ND 0.50 04/16/14 19:32
Trichlorofluoromethane ug/L ND 1.0 04/16/14 19:32
Vinyl chloride ug/L ND 1.0 04/16/14 19:32
1,2-Dichloroethane-d4 (S)%98 70-130 04/16/14 19:32
4-Bromofluorobenzene (S)%98 70-130 04/16/14 19:32
Toluene-d8 (S)%100 70-130 04/16/14 19:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1179319LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 45.850 92 60-140
1,1,1-Trichloroethane ug/L 44.250 88 60-140
1,1,2,2-Tetrachloroethane ug/L 44.250 88 60-140
1,1,2-Trichloroethane ug/L 44.450 89 60-140
1,1-Dichloroethane ug/L 40.750 81 60-140
1,1-Dichloroethene ug/L 42.750 85 60-140
1,1-Dichloropropene ug/L 43.650 87 60-140
1,2,3-Trichlorobenzene ug/L 47.450 95 60-140
1,2,3-Trichloropropane ug/L 43.450 87 60-140
1,2,4-Trichlorobenzene ug/L 46.450 93 60-140
1,2,4-Trimethylbenzene ug/L 46.950 94 60-140
1,2-Dibromo-3-chloropropane ug/L 44.450 89 60-140
1,2-Dibromoethane (EDB)ug/L 46.650 93 60-140
1,2-Dichlorobenzene ug/L 43.950 88 60-140
1,2-Dichloroethane ug/L 41.250 82 60-140
1,2-Dichloropropane ug/L 43.950 88 60-140
1,3,5-Trimethylbenzene ug/L 45.550 91 60-140
1,3-Dichlorobenzene ug/L 42.350 85 60-140
1,3-Dichloropropane ug/L 45.450 91 60-140
1,4-Dichlorobenzene ug/L 43.650 87 60-140
2,2-Dichloropropane ug/L 36.250 72 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1179319LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorotoluene ug/L 42.650 85 60-140
4-Chlorotoluene ug/L 44.550 89 60-140
Benzene ug/L 44.850 90 60-140
Bromobenzene ug/L 45.250 90 60-140
Bromochloromethane ug/L 43.050 86 60-140
Bromodichloromethane ug/L 46.450 93 60-140
Bromoform ug/L 38.650 77 60-140
Bromomethane ug/L 41.150 82 60-140
Carbon tetrachloride ug/L 47.050 94 60-140
Chlorobenzene ug/L 42.250 84 60-140
Chloroethane ug/L 40.150 80 60-140
Chloroform ug/L 42.450 85 60-140
Chloromethane ug/L 41.450 83 60-140
cis-1,2-Dichloroethene ug/L 43.050 86 60-140
cis-1,3-Dichloropropene ug/L 46.250 92 60-140
Dibromochloromethane ug/L 39.150 78 60-140
Dibromomethane ug/L 43.950 88 60-140
Dichlorodifluoromethane ug/L 37.950 76 60-140
Diisopropyl ether ug/L 41.850 84 60-140
Ethylbenzene ug/L 44.850 90 60-140
Hexachloro-1,3-butadiene ug/L 46.150 92 60-140
Isopropylbenzene (Cumene)ug/L 45.650 91 60-140
m&p-Xylene ug/L 91.2100 91 60-140
Methyl-tert-butyl ether ug/L 44.550 89 60-140
Methylene Chloride ug/L 41.850 84 60-140
n-Butylbenzene ug/L 46.750 93 60-140
n-Propylbenzene ug/L 45.350 91 60-140
Naphthalene ug/L 47.750 95 60-140
o-Xylene ug/L 45.450 91 60-140
sec-Butylbenzene ug/L 45.350 91 60-140
Styrene ug/L 48.650 97 60-140
tert-Butylbenzene ug/L 45.050 90 60-140
Tetrachloroethene ug/L 44.050 88 60-140
Toluene ug/L 44.150 88 60-140
trans-1,2-Dichloroethene ug/L 41.550 83 60-140
trans-1,3-Dichloropropene ug/L 40.550 81 60-140
Trichloroethene ug/L 43.250 86 60-140
Trichlorofluoromethane ug/L 38.550 77 60-140
Vinyl chloride ug/L 47.950 96 60-140
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
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Huntersville, NC 28078
[phone]
Page 17 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1179320MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92197108002
1179321
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 50 107 60-140109 250ND53.6 54.7
1,1,1-Trichloroethane ug/L 50 106 60-140109 350ND53.2 54.6
1,1,2,2-Tetrachloroethane ug/L 50 97 60-140102 550ND48.6 50.9
1,1,2-Trichloroethane ug/L 50 102 60-140104 250ND51.0 51.9
1,1-Dichloroethane ug/L 50 91 60-14095 450ND45.7 47.7
1,1-Dichloroethene ug/L 50 97 60-140101 350ND48.7 50.4
1,1-Dichloropropene ug/L 50 105 60-140107 250ND52.4 53.4
1,2,3-Trichlorobenzene ug/L 50 109 60-140111 250ND54.3 55.5
1,2,3-Trichloropropane ug/L 50 98 60-140103 450ND49.2 51.5
1,2,4-Trichlorobenzene ug/L 50 107 60-140109 250ND53.7 54.7
1,2,4-Trimethylbenzene ug/L 50 106 60-140108 250ND53.1 54.2
1,2-Dibromo-3-chloropropane ug/L 50 101 60-140110 850ND50.7 54.9
1,2-Dibromoethane (EDB)ug/L 50 105 60-140108 350ND52.3 54.0
1,2-Dichlorobenzene ug/L 50 98 60-140101 350ND49.0 50.5
1,2-Dichloroethane ug/L 50 94 60-14096 250ND47.0 47.8
1,2-Dichloropropane ug/L 50 98 60-14099 150ND49.0 49.6
1,3,5-Trimethylbenzene ug/L 50 103 60-140105 250ND51.7 52.7
1,3-Dichlorobenzene ug/L 50 96 60-14099 350ND48.1 49.4
1,3-Dichloropropane ug/L 50 101 60-140105 450ND50.5 52.4
1,4-Dichlorobenzene ug/L 50 101 60-140102 150ND50.7 51.0
2,2-Dichloropropane ug/L 50 107 60-140112 450ND53.5 55.8
2-Chlorotoluene ug/L 50 96 60-14099 350ND48.1 49.6
4-Chlorotoluene ug/L 50 101 60-140104 250ND50.7 51.8
Benzene ug/L 50 105 60-140107 250ND52.5 53.3
Bromobenzene ug/L 50 100 60-140102 250ND49.9 51.0
Bromochloromethane ug/L 50 94 60-14098 450ND47.0 48.8
Bromodichloromethane ug/L 50 110 60-140113 350ND55.0 56.4
Bromoform ug/L 50 90 60-14095 550ND45.1 47.4
Bromomethane ug/L 50 64 60-14080 2150ND32.2 39.9
Carbon tetrachloride ug/L 50 119 60-140120 150ND59.3 59.9
Chlorobenzene ug/L 50 98 60-140100 250ND48.9 49.9
Chloroethane ug/L 50 100 60-140105 550ND50.0 52.4
Chloroform ug/L 50 99 60-140101 250ND49.5 50.5
Chloromethane ug/L 50 68 60-14070 450ND33.9 35.2
cis-1,2-Dichloroethene ug/L 50 96 60-14098 250ND48.1 49.0
cis-1,3-Dichloropropene ug/L 50 112 60-140114 250ND56.0 56.9
Dibromochloromethane ug/L 50 89 60-14092 350ND44.7 45.8
Dibromomethane ug/L 50 105 60-140108 250ND52.7 53.8
Dichlorodifluoromethane ug/L 50 103 60-140106 350ND51.4 52.8
Diisopropyl ether ug/L 50 85 60-14089 550ND42.3 44.3
Ethylbenzene ug/L 50 105 60-140106 250ND52.4 53.2
Hexachloro-1,3-butadiene ug/L 50 114 60-140117 350ND57.1 58.7
Isopropylbenzene (Cumene)ug/L 50 107 60-140108 150ND53.7 54.2
m&p-Xylene ug/L 100 107 60-140108 0100ND107108
Methyl-tert-butyl ether ug/L 50 99 60-140104 550ND49.4 51.8
Methylene Chloride ug/L 50 85 60-14090 550ND42.5 44.8
n-Butylbenzene ug/L 50 108 60-140109 150ND54.0 54.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 18 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1179320MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92197108002
1179321
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 50 103 60-140105 250ND51.3 52.5
Naphthalene ug/L 50 105 60-140109 450ND52.4 54.3
o-Xylene ug/L 50 107 60-140107 050ND53.4 53.6
sec-Butylbenzene ug/L 50 103 60-140106 350ND51.5 52.9
Styrene ug/L 50 113 60-140114 050ND56.7 56.9
tert-Butylbenzene ug/L 50 103 60-140107 350ND51.6 53.3
Tetrachloroethene ug/L 50 109 60-140110 150ND54.3 54.9
Toluene ug/L 50 105 60-140105 050ND52.4 52.6
trans-1,2-Dichloroethene ug/L 50 93 60-14097 550ND46.3 48.5
trans-1,3-Dichloropropene ug/L 50 98 60-140100 150ND49.2 49.9
Trichloroethene ug/L 50 105 60-140107 250ND52.5 53.4
Trichlorofluoromethane ug/L 50 95 60-14098 350ND47.5 49.1
Vinyl chloride ug/L 50 114 60-140117 350ND57.1 58.7
1,2-Dichloroethane-d4 (S)%95 70-13096
4-Bromofluorobenzene (S)%105 70-130105
Toluene-d8 (S)%101 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 23
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
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Huntersville, NC 28078
[phone]
Page 20 of 23
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92196391
045.40675.2005 (Craven Oil)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92196391001 MSV/26386MW7ASM 6200B
92196391002 MSV/26469MW4ASM 6200B
92196391003 MSV/26386MW3ASM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/21/2014 11:03 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 23
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