WA-1267_14864_CA_RPTS_20221108_MRP

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

November 08, 2022

Mr. Jared Edwards
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: Ground Water Monitoring Report
September 2022
Pitt Country Mart
4787 NC Highway 11 North
Bethel, Pitt County
North Carolina
Facility ID Number: 00-0-0000019586
Incident Numbers: 14864
GRI Project Number: 3753

Dear Mr. Edwards,

Please find enclosed the referenced report, for the abovementioned site.
If you have any questions, please contact Rae Brown at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Pitt Country Mart, Inc., file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Ground Water Monitoring Report
September 2022
Pitt Country Mart
4787 NC Highway 11 North
Bethel, Pitt County
North Carolina
Facility ID Number: 00-0-0000019586
Incident Number: 14864
GRI Project Number: 3753

Prepared for:

Pitt Country Mart, Inc.
PO Box 965
Bethel, North Carolina 27812

November 8, 2022

Rae Troiano Brown, P. G.
Project Manager
Sharon Lowther
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
i
SITE INFORMATION
1. Site Identification
 Pitt Country Mart (Facility ID 00-0-0000019586)
 Incident Number 14864 – Intermediate Risk (I195D)
 Location of Source Area: 4787 NC Highway 11 North
Bethel, NC 27812
Pitt County
35.7156139°N, 77.3649037°W (Topographical Map)

2. Information about Contacts Associated with the Leaking UST System

3. Information about Release
 Release was discovered on June 1, 1995.
 An unknown amount of product was released from the leaking UST System.
 One 10,000-gallon gasoline UST, one 8,000-gallon gasoline UST, one 6,000-gallon gasoline UST,
one 10,000-gallon diesel and one 4,000-gallon diesel were removed October 30, 1997. None of
the components of the former UST system remain on-site.
UST Owner
Pitt Country Mart, Inc.
PO Box 965
Bethel, NC 27812
[e-mail]
252-758-5397
Property Owner
S&S Realty of Pitt County LLC
PO Box 965
Bethel, NC 27812

Property Occupant
Pitt Country Mart, Inc.
PO Box 965
Bethel, NC 27812
252-758-5397

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010
UST Operator
Pitt Country Mart, Inc.
PO Box 965
Bethel, NC 27812
[e-mail]
252-758-5397
Analytical Laboratory
Waypoint Analytical, LLC
449 Springbrook Road
Charlotte, NC 28217
State Certification No. 402
704-529-6364

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
ii
EXECUTIVE SUMMARY
Pitt Country Mart is located at 4787 NC Highway 11 North in Bethel, Pitt County, North Carolina. The site
is currently owned by Pitt Country Mart, Inc. One 10,000-gallon gasoline UST, one 8,000-gallon gasoline
UST, one 6,000-gallon gasoline UST, one 10,000-gallon diesel and one 4,000-gallon diesel were removed
October 30, 1997. None of the components of the former UST system remain on-site. The site is a
convenience store and retail petroleum facility.

A release was discovered at the site on June 1, 1995. During 1997 tank removal activities, approximately
900 tons of contaminated soil and 7,550 gallons of contaminated water and product were removed.

In 2003, a CAP was approved for the site but not implemented. A MMPE event was performed on MW-
22 and approximately 10,307 gallons of groundwater and free product were removed.

In September 2022, GRI conducted an updated receptor survey. Municipal water is available to the site
and properties within 1,500 feet of the site. The on-site supply well has been closed. Well surveys were
mailed to supply wells PW1 through PW5 and PW8 through PW11. Well survey responses indicated two
potable water supply wells (PW-1 and PW-8) are still in use and confirmed that PW-3 is not used. No
other well survey responses were received.

On September 21, 2022, twelve monitoring wells (MW-5, MW-17, MW-19 through MW-21, MW-24, MW-
27, MW-28, and MW-36 through MW-39) were purged and sampled. MW-23 was gauged but not sampled
due to the presence of free product (0.11 feet). MW-26 was dry and MW-29 could not be located.
Concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, n-propylbenzene, 1,3,5-
Trimethylbenzene 1,2,4-Trimethylbenzene, C5-C8 aliphatics, C9-C12 aliphatics, C9C-18 aliphatics, C9-C10
aromatics, and/or C11-C22 aromatics that exceeded the MACs were reported in the ground water samples
collected from MW-19, MW-20, MW-21, MW-24, MW-36, and MW-38. None of the concentrations
exceeded the GCLs.

Based on this information, the site should be classified high risk. Free product recovery should be
conducted in MW-23 if access is permitted by the NCDOT. A feasibility study should be completed.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality

NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753

TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
3.0 FREE PRODUCT REMOVAL ........................................................................................................5
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................5
5.0 CONCLUSIONS .........................................................................................................................5
6.0 LIMITATIONS ...........................................................................................................................6
7.0 STATEMENTS AND CERTIFICATION ...........................................................................................6
FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Water Table Surface Map
Figure 5: Ground Water Quality Map
Figure 6: Benzene Isoconcentration Map
Figure 7: Toluene Isoconcentration Map
Figure 8: Ethylbenzene Isoconcentration Map
Figure 9: Xylenes Isoconcentration Map
Figure 10: Naphthalene Isoconcentration Map
Figure 11: Contaminant Area Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Owner Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Ground Water Sample Analytical Results
Table 7: Summary of Field Parameters

APPENDICES
Appendix A: State Correspondence
Appendix B: Historical Ground Water Gauging Data
Appendix C: Historical Ground Water Quality Data
Appendix D: Well Surveys
Appendix E: Laboratory Report – Ground Water Samples
Appendix F: Contaminant Mass Reduction Calculations

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
1
1.0 SITE HISTORY AND CHARACTERIZATION
Pitt Country Mart is located at 4787 NC Highway 11 North in Bethel, Pitt County, North Carolina. GRI
presents the results of the September 2022 ground water sampling event at the Pitt Country Mart site
(Figures 1 and 2). These activities were conducted in accordance with GRI Proposal No. 22-554, which
was submitted to NCDEQ on August 15, 2022, and was approved as Task Authorization No. 14864-22 on
August 22, 2022. State correspondence has been included as Appendix A.

The site is currently owned by Pitt Country Mart, Inc. and functions as a convenience store and retail
facility. One 10,000-gallon gasoline UST, one 8,000-gallon gasoline UST, one 6,000-gallon gasoline UST,
one 10,000-gallon diesel and one 4,000-gallon diesel were removed October 30, 1997. None of the
components of the former UST system remain on-site.

UST owner/operator information and UST system information are included as Tables 1 and 2, respectively.
The Registered Tank Report is shown below:

A release was discovered at the site on June 1, 1995. During 1997 tank removal activities, approximately
900 tons of contaminated soil and 7,550 gallons of contaminated water and product were removed.

Historically, free product has been present at the site. In June 2002, a MMPE event was performed on
MW-22 and approximately 10,307 gallons of groundwater and free product were removed. In 2003, a
CAP was approved for the site but not implemented.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
2
Type II monitoring wells were installed at the site for various phases of assessment. A Site Map showing
the locations of the monitoring wells and the structures on-site has been included as Figure 3. Historical
ground water gauging and quality information are included as Appendix B and Appendix C, respectively.

According to receptor survey conducted by a previous consultant for the 2002 CAP, two potable wells are
located within 1,000 feet of the site. In addition, seven wells identified within 1,000 feet of the site are
either used for irrigation or are no longer active.

In September 2022, an updated receptor survey conducted by GRI confirmed the site and surrounding
areas are serviced with municipal water. Well surveys were mailed to supply wells PW1 through PW5 and
PW8 through PW11. Well survey responses to PW1 and PW8 confirmed the residences do not use
municipal water and that the wells remain in use. The survey response for PW3 confirmed the residence
uses municipal water and the well is inactive. No other well survey responses were received. Copies of
well survey responses are included in Appendix D.

The surrounding area is a mixture of residential, commercial, and undeveloped land. The site contains
one building and is capped with concrete and asphalt. The overall topography at the site is relatively flat.
A Site Vicinity Map depicting the locations of water supply wells has been included as Figure 2. Well
owner information is summarized in Table 3. Adjacent property owner information is presented in Table
4.

Although GRI cannot verify the accuracy of information obtained from previous reports, for the purposes
of this report, it is assumed to be correct. Please refer to previous submittals for further historical
information regarding the site.
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On September 21, 2022, thirteen Type II monitoring wells (MW-5, MW-17, MW-19 through MW-21, MW-
23, MW-24, MW-27, MW-28, and MW-36 through MW-39) were gauged. Well MW-26 was dry and MW-
29 could not be located. Depths to ground water in the Type II monitoring wells ranged from 5.67 feet to
10.17 feet. Tops of casing elevation for the monitoring wells were established by a previous consultant.
On September 21, 2022, ground water elevations ranged from 93.15 to 95.41 feet. Based on this
information, ground water flow on the site property is generally toward the south. The horizontal
hydraulic gradient across the site from MW-21 to MW-22 was approximately 0.01 feet per foot. Well
construction and gauging information is presented in Table 5. A Water Table Surface Map is included as
Figure 4. A summary of the current ground water gauging data is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
3
Well
ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to Water
from Top of
Casing
(ft.)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-5 2 - 10 10 99.19 5.67 0.00 93.52
MW-17 2 - 10 10 101.65 8.31 0.00 93.34
MW-19 2 - 12 12 102.36 8.56 0.00 93.80
MW-20 2 - 12 12 102.04 8.89 0.00 93.15
MW-21 2 - 12 12 102.43 8.43 0.00 94.00
MW-23 2 - 12 12 102.20 8.67 0.11 93.53
MW-24 2 - 12 12 102.54 8.22 0.00 94.32
MW-27 2 - 12 12 102.00 8.79 0.00 93.21
MW-28 2 - 12 12 99.77 6.22 0.00 93.55
MW-36 5 - 15 15 104.22 8.81 0.00 95.41
MW-37 5 - 15 15 104.57 10.17 0.00 94.40
MW-38 2 - 12 12 101.02 6.06 0.00 94.96
MW-39 2 - 12 12 102.33 8.23 0.00 94.10

On September 21, 2022, twelve monitoring wells (MW-5, MW-17, MW-19 through MW-21, MW-24, MW-
27, MW-28, and MW-36 through MW-39) were purged and sampled. MW-23 was gauged but not sampled
due to the presence of free product. Field parameters were collected during the sampling event.

Ground water samples collected from the monitoring wells were submitted for laboratory analyses using
EPA Method 6200B, MADEP VPH and EPH, and SM 6010B. In addition, all samples were submitted for
laboratory analyses of methane, ferrous iron, nitrates, and sulfates. Concentrations of benzene, toluene,
ethylbenzene, xylenes, MTBE, naphthalene, n-propylbenzene, 1,3,5-trimethylbenzene 1,2,4-
trimethylbenzene, C5-C8 aliphatics, C9-C12 aliphatics, C9C-18 aliphatics, C9-C10 aromatics, and/or C11-
C22 aromatics that exceeded the MACs were reported in the ground water samples collected from MW-
19, MW-20, MW-21, MW-24, MW-36, and MW-38. Concentrations of lead exceeded the MAC in all of the
wells sampled except MW-17. Concentrations of ferrous iron exceeded the MAC in MW-17, MW-19, MW-
20, MW-28, and MW-36 through MW-39. None of the concentrations exceeded the GCLs.

A summary of the analytical results for ground water samples collected in September 2022 is presented
in Table 6. A summary of the field parameters for ground water samples collected in September 2022 is
presented in Table 7. A Ground Water Quality Map based on the September 21, 2022 data is included as
Figure 5. Isoconcentration maps for benzene, toluene, ethylbenzene, xylenes, and naphthalene are
included as Figures 6, 7, 8, 9 and 10, respectively. A complete report of laboratory analyses of the ground
water samples collected during the September 2022 sampling event has been included as Appendix E. A
summary of the current ground water analytical data is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
4
Contaminant of
Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well ID
MAC (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-5 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-17 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-19 911 2,040 691 5,570 10.9 489
MW-20 3,290 3,930 897 3,910 202 1,960
MW-21 3.97 0.345 J 2.62 1.89 J <0.140 1.44
MW-23 FP FP FP FP FP FP
MW-24 170 3.54 69.6 65.4 <0.140 17.8
MW-27 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-28 <0.180 0.539 0.265 J 1.16 J <0.140 0.950 J
MW-36 188 46.4 25.2 116 4.61 47.7
MW-37 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-38 43.2 2.22 25.4 14.5 2.19 22.0
MW-39 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470

The site is in the Coastal Plain Physiographic Province of North Carolina. The water table has a seasonal
high depth to water of approximately 6 to 12 feet BGS.

The baseline contaminant mass at the site was determined based on the total BTEX and naphthalene
concentrations as well as the maximum historical water column height from the 2015 water sampling
event. A theoretical contaminant mass area was calculated around MW-19, MW-20, MW-21, MW-23,
MW-24, MW-36, and MW-39 and used in the contaminant mass calculations. The total contaminant mass
at the site has decreased 87% since 2015. Contaminant mass calculations have been included as Appendix
F. A map of the contaminant mass areas has been included as Figure 11. A chart depicting the overall
trend in contaminant mass is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
5

3.0 FREE PRODUCT REMOVAL
Historically, free product has been found at the site. In June 2002, a MMPE event was performed on MW-
22 and approximately 10,307 gallons of groundwater and free product were removed. In 2003, a CAP was
approved for the site but not implemented.

In September 2022, free product (0.11 feet) was reported in the monitoring well MW-23.
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
No natural attenuation monitoring plan is currently in place at the site.
5.0 CONCLUSIONS
 Pitt Country Mart is a convenience store and retail petroleum facility. One 10,000-gallon gasoline
UST, one 8,000-gallon gasoline UST, one 6,000-gallon gasoline UST, one 10,000-gallon diesel and
one 4,000-gallon diesel were removed October 30, 1997. None of the components of the former
UST system remain on-site.
 In September 2022, GRI conducted an updated receptor survey. Municipal water is available to the
site and properties within 1,500 feet of the site. Two potable wells are located within 1,000 feet of
the site.
 On September 21, 2022, twelve monitoring wells (MW-5, MW-17, MW-19 through MW-21, MW-
24, MW-27, MW-28 and MW-36 through MW-39) were purged and sampled. MW-23 was gauged
but not sampled due to the presence of free product (0.11 feet). MW-26 was dry and MW-29 could
not be located.
 Concentrations of benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, n-propylbenzene,
1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene, C5-C8 aliphatics, C9-C12 aliphatics, C9C-18
7.25
7.3
7.35
7.4
7.45
7.5
7.55
7.6
7.65
7.7
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
Average Water Column Height (ft)Contaminant Mass (grams)Time
Total Contaminant Mass vs. Time
Contaminant Mass (grams)Water Column Height (ft)

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
6
aliphatics, C9-C10 aromatics, and/or C11-C22 aromatics that exceeded the MACs were reported in
the ground water samples collected from MW-19, MW-20, MW-21, MW-24, MW-36, and MW-38.
None of the concentrations exceeded the GCLs.
 Based on this information, the site should be classified as high risk. Free product recovery should
be conducted in MW-23 if access is permitted by the NCDOT. A feasibility study should be
completed.
6.0 LIMITATIONS
This report has been prepared for the exclusive use of Pitt Country Mart Inc for specific application to the
referenced site in Pitt County, North Carolina. The assessment was conducted based on the scope of work
and level of effort desired by NCDEQ and with resources adequate only for that scope of work. Our
findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
7.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. N/A Will this report be submitted after the
established due date?
YES NO
2 Was any required information from the above template missing from this report? YES NO
IF the answer to question #1 or# 2 is “YES”, please provide additional information in this cell to explain
what was missing and why.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved
in the Corrective Action Plan not be met? (within a reasonable margin of error)
YES NO
IF the answer to question #3 is “NO”, skip to the certification under #8 below.
IF the answer to question #3 is “YES”, please generally describe in this cell the possible reason(s) and
outline proposed remedies. (This should be described in more detail in the report text above.)

N/A
4 Does any known or suspected source zone soil contamination or free product remain
outside of the assessed area that could be inhibiting natural attenuation?
YES NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a
potential new release from a separate on-site or offsite source?
YES NO

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: November 8, 2022 Pitt Country Mart
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 3753
7
IF the answer to either question #4 or #5 is “YES”, generally describe in this cell any actions
recommended to further assess or clean up this known or suspected source. (This should be described
in more detail in the report text above.)

6 Certification:
I, Rae Troiano Brown, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice engineering and geology in North Carolina. The
certification number of the company or corporation is C-2727/C-127.

FIGURES
"J
"J
DH
DH
!P
!P
!P
!P
!P
!P
!P
SITE
4781492006
4781592383
4781594792
4781587844
4782601165
4781597175
4781690710
4781597001
4781599403
4781598239
4781599556
4781690871
4781691913
4782600093
PW-9
PW-5
PW-4
PW-3
PW-2
PW-11
PW-10
PW-7
PW-6
PW-8
PW-1
GRINDLE CREEK
P
U
G M
O
O
R
E R
D
FOXBORO RD
US-13SR-1572
US-13FIGURE 2: SITE VICINITY MAPPITT COUNTRY MART4787 NC HIGHWAY 11 NORTHBETHEL, PITT COUNTYNORTH CAROLINAINCIDENT NO. 14864GRI NO. 3753
PREPARED BY:GEOLOGICAL RESOURCES, INC.SEPTEMBER 19, 2022
³
0 300150Feet1 inch = 300 feet
1,500-FOOT RADIUS
1,000-FOOT RADIUS 250-FOOT RADIUS
500-FOOT RADIUS
LEGEND
"J Potable Water Supply Well
DH Potable Well (Abandoned)
!P Irrigation or Inactive Well
ncrivers
Pitt_County_Roads
LRS_Route
Well Owners and Adjacent Properties
nc_pitt_parcels_poly

TABLES
UST ID Number 1-5 Facility ID Number
Owner or
Operator?
OwnerPitt Country Mart, Inc. 1983 - 1997
Address Telephone Number
P.O. Box 965, Bethel, NC 27812 252-758-5397
TABLE 1
UST OWNER/OPERATOR INFORMATION
PITT COUNTRY MART (INCIDENT NO. 14864)
00-0-0000019586
Name of Owner or Operator Dates of Ownership / Operation
Date: 10/20/22 Facility ID # : 00-0-0000019586
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline NA 10,000 7/1/1983
Single Wall
Steel 8' x 26'8" Single Wall Steel
Removed
1997 Yes
2 Diesel NA 10,000 7/1/1983
Single Wall
Steel 8' x 26'8" Single Wall Steel
Removed
1997 Yes
3 Gasoline NA 8,000 7/1/1983
Single Wall
Steel 8' x 21'4" Single Wall Steel
Removed
1997 Yes
4 Gasoline NA 6,000 7/1/1983
Single Wall
Steel 8' x 16' Single Wall Steel
Removed
1997 Yes
5 Diesel NA 4,000 7/1/1983
Single Wall
Steel 64" x 24' Single Wall Steel
Removed
1997 Yes
Notes:
• FRP: Fiberglass reinforced plastic.
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
TABLE 2
UST SYSTEM INFORMATION
PITT COUNTRY MART (INCIDENT NO. 14864)
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Well ID. Parcel ID No. NC PIN Well Owner Mailing Address Well Address
Well Use
(Potable / Non-
Potable
etc.)
Connected to
Municipal Water
Yes/No
Distance from source
area of release
(ft.)
Comments
PW1 36997 4781690710 Perry G Best
4806 NC 11 N
Bethel, NC 27812
4806 NC 11 N
Bethel, NC 27812 Potable No ~700' NE Well survey received
PW2 36998 4781599556 Beverly J Wilkins
4792 NC 11 N
Bethel, NC 27812
4792 NC 11 N
Bethel, NC 27812 Inactive Yes ~740' NE As reported in 2002 CAP
PW3 36999 4781599403 Amber Styons
4782 NC 11 N
Bethel, NC 27812
4782 NC 11 N
Bethel, NC 27812 Inactive Yes ~500' NE Well survey received
PW4 37001 4781597175 Carla Sue Hanson Life Estate
500 Treybrook Cl, Apt 11
Greenville, NC 27834
4758 NC 11 N
Bethel, NC 27812 Inactive Yes ~450' SE As reported in 2002 CAP
PW5 37003 4781587844 Carla Sue Hanson Life Estate
500 Treybrook Cl, Apt 11
Greenville, NC 27834
NC 11 N
Bethel, NC 27812 Irrigation Yes ~560' SE As reported in 2002 CAP
PW6 62105
(Site)4781594792 S&S Realty Of Pitt County LLC
PO Box 965
Bethel, NC 27812
4787 NC 11 N
Bethel, NC 27812 Closed Yes N/A As reported in 1996 Rpt
PW7 78985 4781592383 Kenneth L Smith
PO Box 965
Bethel, NC 27812
4787 NC 11 N
Bethel, NC 27812 Closed Yes ~265' NE As reported in 1996 Rpt
PW8 36996 4781690871 Joe and Levonne Smith 4812 NC 11 N
Bethel, NC 27812
4812 NC 11 N
Bethel, NC 27812 Potable No ~980' NE Well survey received
PW9 36995 4781691913
Clifton and Mary
Wanda Williams
6582 NC 30 East
Bethel, NC 27812
4824 NC 11 N
Bethel, NC 27812 Inactive Yes ~900' NE As reported in 2002 CAP
PW10 36994 4782600093 William and Gwendolyn
Harkley
4828 NC 11 N
Bethel, NC 27812
4828 NC 11 N
Bethel, NC 27812 Irrigation Yes ~1,050' NE As reported in 2002 CAP
PW11 36993 4782601165 David Earl Jones
4840 NC 11 N
Bethel, NC 27812
4840 NC 11 N
Bethel, NC 27812 Inactive Yes ~1,200' NE As reported in 2002 CAP
Note:
• Water supply wells are keyed to Figure 2.
Date: 11/2/22 Facility ID # : 00-0-0000019586
TABLE 3
WATER SUPPLY WELL INFORMATION
PITT COUNTRY MART (INCIDENT NO. 14864)
Page 1 of 1
Date: 09/29/22 Facility ID # : 00-0-0000019586
Parcel Number Owner Name Address
62105 (Site) S&S Realty Of Pitt County LLC
PO Box 965
Bethel, NC 27812
78985 Kenneth L Smith
PO Box 965
Bethel, NC 27812
36996 Joe M Smith
4812 NC 11 N
Bethel, NC 27812
36997 Perry G Best
4806 NC 11 N
Bethel, NC 27812
36998 Beverly J Wilkins
4792 NC 11 N
Bethel, NC 27812
36999 Amber Styons
4782 NC 11 N
Bethel, NC 27812
37000 Beverly J Wilkins
4792 NC 11 N
Bethel, NC 27812
37001 Carla Sue Hanson
Remainder
4792 NC 11 N
Bethel, NC 27812
37002 Beverly J Wilkins
4792 NC 11 N
Bethel, NC 27812
37003 Beverly J Wilkins 4792 NC 11 N
Bethel, NC 27812
82233 Kenneth L Smith
PO Box 965
Bethel, NC 27812
24522 Alyce E Green
516 Cedarhurst Rd
Greenville, NC 27834
Note:
• Properties are keyed to Figure 2.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
PITT COUNTRY MART (INCIDENT NO. 14864)
Date: 10/12/22
08/13/07 4.19 0.00 95.00
05/20/10 4.17 0.00 95.02
03/24/15 2.62 0.00 96.57
09/21/22 5.67 0.00 93.52
08/13/07 6.85 0.00 94.80
05/20/10 6.78 0.00 94.87
03/23/15 5.29 0.00 96.36
09/21/22 8.31 0.00 93.34
08/13/07 6.92 0.00 95.44
05/20/10 6.68 0.00 95.68
03/23/15 4.67 0.00 97.69
06/08/16 5.76 0.00 96.60
09/21/22 8.56 0.00 93.80
08/13/07 7.54 0.00 94.50
05/20/10 7.34 0.00 94.70
03/23/15 5.94 0.00 96.10
06/08/16 6.24 0.00 95.80
09/21/22 8.89 0.00 93.15
08/13/07 6.71 0.00 95.72
05/20/10 6.65 0.00 95.78
03/23/15 4.69 0.00 97.74
09/21/22 8.43 0.00 94.00
08/13/07 7.08 0.00 95.12
05/20/10 6.81 0.00 95.39
03/23/15 5.21 0.00 96.99
06/08/16 5.71 0.00 96.49
09/21/22 8.67 0.11 93.62 8.56' DTP
05/20/10 6.10 0.00 96.44
03/23/15 3.11 0.00 99.43
09/21/22 8.22 0.00 94.32
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
PITT COUNTRY MART (INCIDENT NO. 14864)
102.54
MW-23 09/11/01 2 2 - 12 12 102.20
MW-24 09/11/01 2 2 - 12 12
MW-21 04/18/96 2 2 - 12 12 102.43
Ground
Water
Elevation*
(ft.)
Well
ID
Date
Installed
(mm/dd/yy)
Date
Water
Level
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y
ft. BGS)
Facility ID #: 00-0-0000019586
Comments
MW-5 02/28/96 2 2 - 10 10
Bottom
of Well
(ft.
BGS)
MW-19 09/11/01 2 2 - 12 12 102.36
Depth to
Ground
Water
from Top
of Casing
(ft.)
Free
Product
Thickness**
(ft.)
MW-20 09/11/01 2 2 - 12 12 102.04
Top of
Casing
Elevation*
(ft.)
99.19
MW-17 05/22/96 2 2 - 10 10 101.65
Page 1 of 3
Date: 10/12/22
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
PITT COUNTRY MART (INCIDENT NO. 14864)
Ground
Water
Elevation*
(ft.)
Well
ID
Date
Installed
(mm/dd/yy)
Date
Water
Level
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y
ft. BGS)
Facility ID #: 00-0-0000019586
Comments
Bottom
of Well
(ft.
BGS)
Depth to
Ground
Water
from Top
of Casing
(ft.)
Free
Product
Thickness**
(ft.)
Top of
Casing
Elevation*
(ft.)
08/13/07 4.80 0.00 96.20
05/20/10 5.55 0.00 95.45
03/24/15 2.79 0.00 98.21
06/08/16 3.93 0.00 97.07
09/21/22 NM 0.00 NM Dry
08/13/07 7.36 0.00 94.64
05/20/10 7.22 0.00 94.78
03/24/15 5.82 0.00 96.18
09/21/22 8.79 0.00 93.21
08/13/07 3.62 0.00 96.15
05/20/10 3.70 0.00 96.07
03/23/15 1.31 0.00 98.46
09/21/22 6.22 0.00 93.55
MW-28 06/10/02 2 2 - 12 12 99.77
MW-26 09/12/01 2 2 - 12 12 101.00
MW-27 06/10/02 2 2 - 12 12 102.00
Page 2 of 3
Date: 10/12/22
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
PITT COUNTRY MART (INCIDENT NO. 14864)
Ground
Water
Elevation*
(ft.)
Well
ID
Date
Installed
(mm/dd/yy)
Date
Water
Level
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y
ft. BGS)
Facility ID #: 00-0-0000019586
Comments
Bottom
of Well
(ft.
BGS)
Depth to
Ground
Water
from Top
of Casing
(ft.)
Free
Product
Thickness**
(ft.)
Top of
Casing
Elevation*
(ft.)
08/13/07 4.98 0.00 94.59
05/20/10 4.67 0.00 94.90
03/23/15 1.91 0.00 97.66
09/21/22 NM 0.00 NM Not found
05/20/10 7.21 0.00 97.01
03/24/15 5.82 0.00 98.40
09/21/22 8.81 0.00 95.41
05/20/10 7.78 0.00 96.79
03/24/15 6.07 0.00 98.50
09/21/22 10.17 0.00 94.40
05/20/10 4.67 0.00 96.35
03/23/16 3.37 0.00 96.35
06/08/16 5.45 0.00 95.57
09/21/22 6.06 0.00 94.96
05/20/10 4.35 0.00 97.98
03/23/15 4.28 0.00 98.05
09/21/22 8.23 0.00 94.10
Notes:
• **: If free product is present in a well, ground water elevation should be calculated by: (Top of Casing Elevation - Depth to Water) +
(Free Product thickness x 0.8581)
• NM: Not Measured.
• NA: Not Applicable.
• Depths measured prior to September 2022 were not collected under GRI supervision.
MW-38 5/12/10 2 2 - 12 12 101.02
• *: Top-of-casing elevation and well construction details are reproduced from the Groundwater Monitoring Report dated
February 8, 2012 from TERRAquest obtained during the file review; assumed elevation 100.00 ft.
• ft BGS: feet below ground surface
MW-39 05/19/10 2 2 - 12 12 102.33
MW-36 05/12/10 5 5 - 15 15 104.22
MW-37 05/12/10 5 5 - 15 15 104.57
MW-29 06/10/02 2 2 - 12 2 99.57
Page 3 of 3
Date: 11/08/22
SW-
6010D RSK-175 SM-3500-
FE-B
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 400 400 15 400 700 200 700 10,000 200 NE 300 10,000 250,000
5,000 260,000 80,000 50,000 20,000 6,000 26,100 28,500 24,100 15,000 NE NE NE NE NE NE NE NE NE NE
05/20/10 <0.2 <0.2 <0.2 <1.0 <0.5 <0.5 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/09/12 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.190 <0.190 <0.180 717 <11.5 <25.8 <4.02 <28.6 <126 <62.2 <4.39 160 J 569 13,400
05/20/10 NS NS NS NS NS NS NS NS NS NR NS NR NR NS NS NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.190 <0.190 <0.180 8 <11.5 <25.8 <4.02 <28.2 <124 <61.2 7,290 7,090 <76.0 3,250
05/20/10 2,295 5,670 655 9,070 168 2,377 285 1,230 2,150 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 4,400 6,200 2,300 13,700 140 950 240 2,900 790 NR 20,000 NR NR 55,000 NR NR NR NR NR NR
03/23/15 6,600 17,000 3,400 16,300 250 1,300 490 4,700 1,300 NR NR NR NR NR NR NR NR NR NR NR
06/08/16 5,200 13,000 3,100 14,800 140 1,000 370 3,800 1,000 NR NR NR NR NR NR NR NR NR NR NR
09/12/17 2,300 4,600 870 9,800 72 620 120 2,500 1,200 NR NR NR NR NR NR NR NR NR NR NR
12/11/18 4,100 6,900 1,200 10,600 75 490 130 2,700 1,000 NR NR NR NR NR NR NR NR NR NR NR
10/28/19 3,200 6,600 1,900 12,500 53 860 190 3,400 1,200 NR NR NR NR NR NR NR NR NR NR NR
01/13/21 1,300 2,300 1,400 8,100 <25 560 160 3,100 1,100 NR NR NR NR NR NR NR NR NR NR NR
04/21/22 380 1,400 800 5,300 <25 300 200 3,100 940 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 911 2,040 691 5,570 10.9 489 126 2,690 672 60 8,350 16,500 10,500 1,240 <139 1,140 542 1,960 <76.0 <650
Facility ID #: 00-0-0000019586
MW-5
MW-17
MW-19 Sulfate2L Standard (µg/l)
GCL (µg/l)
SM-6200
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
PITT COUNTRY MART (INCIDENT NO. 14864)C19-C36 AliphaticsC11-C22 AromaticsMethaneFerrous IronNitrateC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsLeadC5-C8 Aliphatics1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneSW-9056A
Contaminant of Concern
BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)NaphthaleneAnalytical Method MAD VPH MAD EPH
Page 1 of 5
Date: 11/08/22
SW-
6010D RSK-175 SM-3500-
FE-B
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 400 400 15 400 700 200 700 10,000 200 NE 300 10,000 250,000
5,000 260,000 80,000 50,000 20,000 6,000 26,100 28,500 24,100 15,000 NE NE NE NE NE NE NE NE NE NE
Facility ID #: 00-0-0000019586
Sulfate2L Standard (µg/l)
GCL (µg/l)
SM-6200
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
PITT COUNTRY MART (INCIDENT NO. 14864)C19-C36 AliphaticsC11-C22 AromaticsMethaneFerrous IronNitrateC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsLeadC5-C8 Aliphatics1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneSW-9056A
Contaminant of Concern
BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)NaphthaleneAnalytical Method MAD VPH MAD EPH
05/20/10 2,160 2,805 1,820 6,886 817 464 165 1,220 325 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 3,300 3900 930 3,500 260 260 94 680 180 NR NR NR NR NR NR NR NR NR NR NR
03/23/15 680 180 250 600 56 70 34 180 51 NR NR NR NR NR NR NR NR NR NR NR
06/08/16 1,900 2,700 900 NR 95 270 92 690 170 NR NR NR NR NR NR NR NR NR NR NR
09/12/17 2,900 3,700 1,200 4,800 110 290 120 880 230 NR NR NR NR NR NR NR NR NR NR NR
12/11/18 2,200 3,400 980 3,700 110 260 110 790 210 NR NR NR NR NR NR NR NR NR NR NR
10/28/19 4,300 6,900 1,700 6,900 200 460 170 1,400 350 NR NR NR NR NR NR NR NR NR NR NR
01/13/21 390 110 180 540 25 420 29 180 50 NR NR NR NR NR NR NR NR NR NR NR
04/21/22 5,100 10,000 1,900 7,600 210 420 180 1,300 280 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 3,290 3,930 897 3,910 202 1,960 103 757 183 14 7,880 1,030 2,260 262 J <124 336 5,020 3,180 <76.0 <650
05/20/10 <0.2 <0.2 <0.2 <0.6 <1.0 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 400 430 130 356 <2.0 46 16 82 15 NR 2,000 NR NR 2,100 NR NR NR NR NR NR
03/23/15 140 11 93 37 <5 34 24 <5 <5 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 3.97 0.345 J 2.62 1.89 J <0.140 1.44 0.470 J 1.13 0.346 J 117 <11.5 <25.8 <4.02 <28.8 <126 <62.4 453 80.0 J 101 J 4,890
05/20/10 3,950 10,990 700 3,250 1,054 1,823 347 430 995 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 3,900 15,000 2,500 11,700 150 660 210 1,800 480 NR 35,000 NR NR 48,000 NR NR NR NR NR NR
03/23/15 9,600 22,000 3,000 13,300 960 850 270 2,100 540 NR <75 NR NR <175 <100 NR NR NR NR NR
06/08/16 7,700 23,000 2,500 12,500 300 740 230 1,900 440 NR NR NR NR NR NR NR NR NR NR NR
09/12/17 59 2.7 19 7.4 <0.5 22 5.7 9.4 0.54 NR NR NR NR NR NR NR NR NR NR NR
12/11/18 7,700 13,000 1,800 9,700 890 490 200 1,500 420 NR NR NR NR NR NR NR NR NR NR NR
10/28/19 5,900 10,000 2,300 8,600 490 590 280 2,100 510 NR NR NR NR NR NR NR NR NR NR NR
01/13/21 10,000 17,000 1,900 9,000 740 580 210 1,700 440 NR NR NR NR NR NR NR NR NR NR NR
04/21/22 1,800 2,800 1,400 5,200 <100 440 230 1,500 410 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
MW-24 09/21/22 170 3.54 69.6 65.4 <0.140 17.8 6.71 24.8 1.85 122 654 291 139 <31.8 <140 69.3 J 2,350 220 <76.0 2,820
MW-20
MW-21
MW-23
Page 2 of 5
Date: 11/08/22
SW-
6010D RSK-175 SM-3500-
FE-B
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 400 400 15 400 700 200 700 10,000 200 NE 300 10,000 250,000
5,000 260,000 80,000 50,000 20,000 6,000 26,100 28,500 24,100 15,000 NE NE NE NE NE NE NE NE NE NE
Facility ID #: 00-0-0000019586
Sulfate2L Standard (µg/l)
GCL (µg/l)
SM-6200
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
PITT COUNTRY MART (INCIDENT NO. 14864)C19-C36 AliphaticsC11-C22 AromaticsMethaneFerrous IronNitrateC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsLeadC5-C8 Aliphatics1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneSW-9056A
Contaminant of Concern
BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)NaphthaleneAnalytical Method MAD VPH MAD EPH
05/20/10 <0.2 <0.2 <0.2 <0.6 <1.0 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 NS NS NS NS NS NS NS NR NS NR NR NR NR NR NR NR NR NR NR NR
05/20/10 2,400 28,000 1,900 9,000 <50 340 150 1,000 260 NR 66,000 NR NR 17,000 NR NR NR NR NR NR
06/19/12 <0.5 18 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
06/08/16 <0.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
05/20/10 <0.2 <0.2 <0.2 <0.6 <1.0 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 1.00 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.190 <0.190 <0.180 24 14.0 J <25.8 <4.02 <30.5 <134 <66.1 575 160 J 314 16,700
05/20/10 <0.2 <0.2 <0.2 <0.6 <1.0 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 1.00 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 <0.180 0.539 0.265 J 1.16 J <0.140 0.950 J <0.190 0.713 0.212 J 36 <11.5 <25.8 <4.02 <30.6 <135 <66.6 189 420 84.0 J 13,400
05/20/10 NS NS NS NS NS NS NS NS NS NR NS NR NR NS NS NR NR NR NR NR
06/19/12 2,000 14000 2,300 13,900 <50 800 270 2,900 920 NR 26,000 NR NR 70,000 NR NR NR NR NR NR
03/23/15 NS NS NS NS NS NS NS NS NS NR NS NR NR NS NR NR NR NR NR NR
05/20/10 <0.2 <0.2 <0.2 <0.6 <1.0 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 3.7 <0.5 <0.5 <.0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 NS NS NS NS NS NS NS NS NS NR NS NR NR NS NR NR NR NR NR NR
MW-25
MW-26
MW-27
MW-28
MW-32
MW-35
Page 3 of 5
Date: 11/08/22
SW-
6010D RSK-175 SM-3500-
FE-B
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 400 400 15 400 700 200 700 10,000 200 NE 300 10,000 250,000
5,000 260,000 80,000 50,000 20,000 6,000 26,100 28,500 24,100 15,000 NE NE NE NE NE NE NE NE NE NE
Facility ID #: 00-0-0000019586
Sulfate2L Standard (µg/l)
GCL (µg/l)
SM-6200
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
PITT COUNTRY MART (INCIDENT NO. 14864)C19-C36 AliphaticsC11-C22 AromaticsMethaneFerrous IronNitrateC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsLeadC5-C8 Aliphatics1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneSW-9056A
Contaminant of Concern
BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)NaphthaleneAnalytical Method MAD VPH MAD EPH
05/20/10 <0.2 <0.2 <0.2 <0.6 <1.0 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
09/12/17 <0.5 0.58 0.77 1.84 <0.5 2 <0.5 5.7 <0.5 NR NR NR NR NR NR NR NR NR NR NR
12/11/18 12 0.53 7.1 18.9 <0.5 1.6 <0.5 10 1 NR NR NR NR NR NR NR NR NR NR NR
10/28/19 98 7.2 110 404 <0.5 30 20 160 40 NR NR NR NR NR NR NR NR NR NR NR
01/13/21 37 8.8 57 197 0.90 34 35 210 78 NR NR NR NR NR NR NR NR NR NR NR
04/21/22 95 7.5 66 281.5 2 56 36 430 110 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 188 46.4 25.2 116 4.61 47.7 10.4 188 20.7 10 549 <25.8 706 35.3 J <124 148 J 3,080 11,900 <76.0 13,800
05/20/10 <0.2 <0.2 <0.2 <0.6 <1.0 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <1.0 <0.5 2.2 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.190 <0.190 <0.180 194 <11.5 <25.8 <4.02 <28.8 <126 <62.4 5,390 23,800 <76.0 678 J
05/20/10 <0.2 <0.2 <0.2 <0.6 4.2 <1.0 <0.2 <0.2 <0.2 NR <100 NR NR <100 NR NR NR NR NR NR
06/19/12 <0.5 <0.5 <0.5 <0.5 3.7 <0.5 <0.5 <0.5 <0.5 NR <75 NR NR <75 NR NR NR NR NR NR
03/23/15 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
06/08/16 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NR NR NR NR NR NR NR NR NR NR NR
09/21/22 43.2 2.22 25.4 14.5 2.19 22 5.85 81.5 2.24 39 92.6 159 208 34.5 J <124 <61.2 2,800 3,740 <76.0 4,550
MW-39 09/21/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.190 <0.190 <0.180 789 <11.5 <25.8 <4.02 <29.2 <128 <63.4 408 2,930 87.0 J 6,020
Trip Blank 09/21/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR NR
MW-36
MW-37
MW-38
Page 4 of 5
Date: 11/08/22
SW-
6010D RSK-175 SM-3500-
FE-B
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 400 400 15 400 700 200 700 10,000 200 NE 300 10,000 250,000
5,000 260,000 80,000 50,000 20,000 6,000 26,100 28,500 24,100 15,000 NE NE NE NE NE NE NE NE NE NE
Facility ID #: 00-0-0000019586
Sulfate2L Standard (µg/l)
GCL (µg/l)
SM-6200
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
PITT COUNTRY MART (INCIDENT NO. 14864)C19-C36 AliphaticsC11-C22 AromaticsMethaneFerrous IronNitrateC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsLeadC5-C8 Aliphatics1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneSW-9056A
Contaminant of Concern
BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)NaphthaleneAnalytical Method MAD VPH MAD EPH
Notes:
• Results reported in micrograms per liter (µg/l).
• < : Less than the method detection limit specified in the laboratory report.
• 2L Standard specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Not Established
• Concentrations in bold face type exceeded the 2L standards.
• Concentrations in italics exceeded the gross contamination levels.
• NR: Analysis not requested.
• Refer to laboratory report for detected constituents that did not exceed the MACs, or for which no standard has been established.
• Samples prior to September 2022 were not collected under GRI supervision.
Page 5 of 5
Facility ID #: 00-0-0000019586
Well No.Sampled Date
(mm/dd/yy)
DO
(mg/L)Temp (oC)pH ORP
(mv)
Conductivity
(mho)
MW-5 09/21/22 1.45 24.15 5.1 71.6 68
MW-17 09/21/22 1.06 27.25 4.64 2.2 136
MW-19 09/21/22 1.16 25.13 5.59 -26.1 145
MW-20 09/21/22 1.37 25.4 5.34 -57.4 160
MW-21 09/21/22 1.92 25.42 6 -40.9 261
MW-24 09/21/22 1.26 24.79 5.89 -64.5 257
MW-27 09/21/22 1.38 26.82 4.81 136.9 170
MW-28 09/21/22 1.88 22.28 5.12 39.7 47
MW-36 09/21/22 1.27 23.21 5.09 -33.7 50
MW-37 09/21/22 1.11 23.71 4.5 -6.8 324
MW-38 09/21/22 1.22 23.22 5.13 -63.7 115
MW-39 09/21/22 1.02 25.07 5.31 -37.4 215
Notes:
TABLE 7
SUMMARY OF FIELD PARAMETER RESULTS
PITT COUNTRY MART (INCIDENT NO. 14864)
Date: 09/27/2022

APPENDICES

APPENDIX A
State Correspondence
Site Name City / County /Pitt Incident #14864
Resp Pty Name / Contact Incident Mgr Region WAS
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #21
Consultant / Project Mgr /Rae Troiano Brown
Telephone / Fax Number /Task Authorization Number:22 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I 195 D RRA Date:8/18/2022
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
 Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode
RO AuthProposed
Rate/Price
(Consultant)CO AuthProposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
4.031 15 /wells y $110.00 y $1,650.00 $1,650.00 /
4.090 #272 16 /6200B+y $66.00 y $1,056.00 $1,056.00 /
4.090 #330 15 /Pb y $14.00 y $210.00 $210.00 /
4.090 #341 15 /VPH-W y $56.00 y $840.00 $840.00 /
4.090 #342 15 /EPH-W y $100.00 y $1,500.00 $1,500.00 /
4.090 #441 15 /Nitrate y $14.00 y $210.00 $210.00 /
4.090 #490 15 /Fe2+y $20.00 y $300.00 $300.00 /
4.090 #510 15 /Sulfate y $15.00 y $225.00 $225.00 /
4.090 #521 15 /Methane y $70.00 y $1,050.00 $1,050.00 /
4.091 S/H 3 /shipments y $60.00 y $180.00 $180.00 /
6.090 1 /report y $1,125.00 y $1,125.00 $1,125.00 /
12.050 1 /trip y $250.00 y $250.00 $250.00 /
12.055 1 /TEI y $50.00 y $50.00 $50.00 /
//
1.025 0 /SvyUpd 1 $740.00 y $0.00 $740.00 /
//
//
//
//
//
//
//
//
//
//
//
//
Requested Preapproved Claimed 3
TOTAL:$8,646.00 $9,386.00 TOTAL:
Total Standard Costs (Not Third Party)$8,646.00 $9,386.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:8/15/22 by:(PM)(Reserved for RO)
RO Review:8/17/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 8/22/2022
CO Review:8/19/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee and returned to the Trust Fund within a week of approval. Signature
indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work proceeding. Scope/cost
negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the UST Section and RP
is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
RTB
Proposed
Units / Type
(Consultant)
Jared Edwards
ActiveYES
22-554 September 2022
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
100.00%
No
[e-mail]
Mr. Kenneth Smith
Geological Resources, Inc.
DIRECTED COSTS
Bethel
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Pitt Country Mart
Note:This Electronic Preapproval Task Authorization (ePATA)shall be used to receive preapproval from the UST Section.A proposal,including maps and figures,must be attached to
elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If,following completion of this ePATA,you discover that
unexpected tasks must be performed,incurring costs for tasks not originally included with this form,you must complete and submit a separate ePATA request designated as a "Change
Order"in the provided space above prior to conducting those tasks.Include a copy of the prior ePATA form for confirmation.Please attach this form to the cover of the corresponding
claim when requesting reimbursement.IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been completed within 12 months of the
completion date of the FIRST completed task to remain within the Statute of Limitations.All ePATAs submitted within a claim are closed with that claim,and may not be re-used in a
separate submittal, even for costs or tasks that were not originally claimed.Final reimbursement of costs associated with the Total Claimed amount below may be affected by the
eligibility status of the site (i.e., deductibles, apportionment,etc.),and the documentary validation of incurred costs as reasonable and necessary expenses per 15A NCAC 2P .0402 and
.0404.
JME
HB
(Initials)
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality -Division of Waste Management
Site remains Intermediate Risk due to persistent GCL-level contamination in plume core.
Comprehensive sampling event for first time since 2015-2016 for many wells, with MNA parameters to evaluate whether NSZD/MNA is a viable
strategy or form the basis for a proposed alternative in the report prior to a request for a formal CAP Feasibility Study.
Receptor survey update added to evaluate 3 historic receptors to determine if still present and confirm no receptors missed by prior survey.

APPENDIX B
Historic Ground Water Gauging Data

APPENDIX C
Historic Ground Water Quality Data

APPENDIX D
Well Surveys

APPENDIX E
Laboratory Report – Ground Water Samples

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

10/6/2022
Geological Resources, Inc. Rae Brown
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-265-0006 Client Project Description: Pitt County Mart
GRI #3753
Dear Rae Brown:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 9/22/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 115
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-265-0006
Page 2 of 115
Report Number:
Sample Summary Table
Client Project Description:
22-265-0006
Pitt County Mart
GRI #3753
Lab No Client Sample ID Matrix Date Collected Date Received
09/21/2022 08:31Aqueous 89032 Trip Blank 09/22/2022 10:00
09/21/2022 11:02Aqueous 89033 MW-27 09/22/2022 10:00
09/21/2022 11:26Aqueous 89034 MW-17 09/22/2022 10:00
09/21/2022 11:48Aqueous 89035 MW-5 09/22/2022 10:00
09/21/2022 12:06Aqueous 89036 MW-37 09/22/2022 10:00
09/21/2022 12:23Aqueous 89037 MW-36 09/22/2022 10:00
09/21/2022 12:44Aqueous 89038 MW-39 09/22/2022 10:00
09/21/2022 13:06Aqueous 89039 MW-38 09/22/2022 10:00
09/21/2022 13:27Aqueous 89040 MW-20 09/22/2022 10:00
09/21/2022 13:48Aqueous 89041 MW-19 09/22/2022 10:00
09/21/2022 14:09Aqueous 89042 MW-21 09/22/2022 10:00
09/21/2022 14:31Aqueous 89043 MW-24 09/22/2022 10:00
09/21/2022 14:54Aqueous 89044 MW-28 09/22/2022 10:00
Page 3 of 115
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-265-0006
Report Limit
Project:Pitt County Mart
V 89032Trip Blank
J0.441 10/04/2022 16:246200BMethylene Chloride µg/L 0.330
V 89033MW-27
0.024 09/27/2022 17:076010DLeadmg/L 0.002
J7.86 10/04/2022 16:486200BAcetoneµg/L 1.80
314 09/22/2022 18:139056ANitrate (NO3-N)µg/L 76.0
16700 09/22/2022 18:139056ASulfateµg/L 650
J14.0 09/23/2022 15:28CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J14.0 09/23/2022 15:28MADEP-VPH Aliphatic C5-C8 µg/L 11.5
575 09/27/2022 13:15RSK-175 Methane µg/L 4.39
J16009/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
V 89034MW-17
0.008 09/27/2022 17:126010DLeadmg/L 0.002
J4.00 10/04/2022 17:366200BAcetoneµg/L 1.80
3250 09/22/2022 15:179056ASulfateµg/L 650
7290 09/28/2022 07:26RSK-175 Methane µg/L 43.9
7090 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 500
V 89035MW-5
0.717 09/27/2022 17:176010DLeadmg/L 0.012
J4.60 10/04/2022 17:126200BAcetoneµg/L 1.80
569 09/22/2022 16:219056ANitrate (NO3-N)µg/L 76.0
13400 09/22/2022 16:219056ASulfateµg/L 650
J16009/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
V 89036MW-37
0.194 09/27/2022 17:216010DLeadmg/L 0.012
J4.40 10/04/2022 18:256200BAcetoneµg/L 1.80
J67809/22/2022 15:499056ASulfateµg/L 650
5390 09/28/2022 07:39RSK-175 Methane µg/L 43.9
23800 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 500
V 89037MW-36
0.010 09/27/2022 17:256010DLeadmg/L 0.002
20.9 10/04/2022 18:496200BAcetoneµg/L 1.80
188 10/05/2022 17:266200BBenzeneµg/L 1.80
1.96 10/04/2022 18:496200Bn-Butylbenzene µg/L 0.180
1.20 10/04/2022 18:496200Bsec-Butyl benzene µg/L 0.200
Page 4 of 115
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-265-0006
Report Limit
Project:Pitt County Mart
V 89037MW-36
4.63 10/04/2022 18:496200BDi-Isopropyl Ether (DIPE)µg/L 0.500
25.2 10/04/2022 18:496200BEthylbenzeneµg/L 0.170
3.31 10/04/2022 18:496200BIsopropylbenzeneµg/L 0.180
1.54 10/04/2022 18:496200B4-Isopropyl toluene µg/L 0.089
4.61 10/04/2022 18:496200BMethyl tert-butyl ether (MTBE)µg/L 0.140
47.7 10/04/2022 18:496200BNaphthaleneµg/L 0.470
10.4 10/04/2022 18:496200Bn-Propylbenzene µg/L 0.190
46.4 10/04/2022 18:496200BTolueneµg/L 0.220
188 10/05/2022 17:266200B1,2,4-Trimethylbenzene µg/L 1.90
20.7 10/04/2022 18:496200B1,3,5-Trimethylbenzene µg/L 0.180
14.5 10/04/2022 18:496200Bo-Xylene µg/L 0.210
101 10/04/2022 18:496200Bm,p-Xylene µg/L 0.420
116 10/04/2022 18:496200BXylene (Total)µg/L 0.210
13800 09/22/2022 15:019056ASulfateµg/L 650
549 09/26/2022 11:21CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
706 09/26/2022 11:21CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
J35.3 10/02/2022 13:03MADEP-EPH Aliphatic C9-C18 µg/L 28.2
J14810/02/2022 13:03MADEP-EPH Aromatic C11-C22 µg/L 61.2
783 09/26/2022 11:21MADEP-VPH Aliphatic C5-C8 µg/L 11.5
826 09/26/2022 11:21MADEP-VPH Aliphatic C9-C12 µg/L 25.8
706 09/26/2022 11:21MADEP-VPH Aromatic C9-C10 µg/L 4.02
3080 09/28/2022 07:52RSK-175 Methane µg/L 43.9
11900 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 500
V 89038MW-39
0.789 09/27/2022 17:306010DLeadmg/L 0.012
J3.71 10/04/2022 18:016200BAcetoneµg/L 1.80
J87.0 09/22/2022 17:419056ANitrate (NO3-N)µg/L 76.0
6020 09/22/2022 17:419056ASulfateµg/L 650
408 09/27/2022 14:07RSK-175 Methane µg/L 4.39
2930 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
V 89039MW-38
0.039 09/27/2022 17:346010DLeadmg/L 0.002
J4.73 10/04/2022 19:146200BAcetoneµg/L 1.80
43.2 10/04/2022 19:146200BBenzeneµg/L 0.180
0.527 10/04/2022 19:146200Bn-Butylbenzene µg/L 0.180
J0.431 10/04/2022 19:146200Bsec-Butyl benzene µg/L 0.200
Page 5 of 115
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-265-0006
Report Limit
Project:Pitt County Mart
V 89039MW-38
25.4 10/04/2022 19:146200BEthylbenzeneµg/L 0.170
2.82 10/04/2022 19:146200BIsopropylbenzeneµg/L 0.180
J0.381 10/04/2022 19:146200B4-Isopropyl toluene µg/L 0.089
2.19 10/04/2022 19:146200BMethyl tert-butyl ether (MTBE)µg/L 0.140
22.0 10/04/2022 19:146200BNaphthaleneµg/L 0.470
5.85 10/04/2022 19:146200Bn-Propylbenzene µg/L 0.190
2.22 10/04/2022 19:146200BTolueneµg/L 0.220
81.5 10/04/2022 19:146200B1,2,4-Trimethylbenzene µg/L 0.190
2.24 10/04/2022 19:146200B1,3,5-Trimethylbenzene µg/L 0.180
0.831 10/04/2022 19:146200Bo-Xylene µg/L 0.210
13.7 10/04/2022 19:146200Bm,p-Xylene µg/L 0.420
14.5 10/04/2022 19:146200BXylene (Total)µg/L 0.210
4550 09/22/2022 17:579056ASulfateµg/L 650
92.6 09/26/2022 11:45CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
159 09/26/2022 11:45CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
208 09/26/2022 11:45CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
J34.5 10/02/2022 14:15MADEP-EPH Aliphatic C9-C18 µg/L 28.2
138 09/26/2022 11:45MADEP-VPH Aliphatic C5-C8 µg/L 11.5
407 09/26/2022 11:45MADEP-VPH Aliphatic C9-C12 µg/L 25.8
208 09/26/2022 11:45MADEP-VPH Aromatic C9-C10 µg/L 4.02
2800 09/28/2022 08:05RSK-175 Methane µg/L 43.9
3740 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 250
V 89040MW-20
0.014 09/27/2022 17:396010DLeadmg/L 0.002
3290 10/04/2022 23:416200BBenzeneµg/L 18.0
897 10/04/2022 23:416200BEthylbenzeneµg/L 17.0
J35.6 10/04/2022 23:416200BIsopropylbenzeneµg/L 18.0
202 10/04/2022 23:416200BMethyl tert-butyl ether (MTBE)µg/L 14.0
1960 10/04/2022 23:416200BNaphthaleneµg/L 47.0
103 10/04/2022 23:416200Bn-Propylbenzene µg/L 19.0
3930 10/04/2022 23:416200BTolueneµg/L 22.0
757 10/04/2022 23:416200B1,2,4-Trimethylbenzene µg/L 19.0
183 10/04/2022 23:416200B1,3,5-Trimethylbenzene µg/L 18.0
1130 10/04/2022 23:416200Bo-Xylene µg/L 21.0
2780 10/04/2022 23:416200Bm,p-Xylene µg/L 42.0
3910 10/04/2022 23:416200BXylene (Total)µg/L 21.0
Page 6 of 115
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-265-0006
Report Limit
Project:Pitt County Mart
V 89040MW-20
7880 09/23/2022 19:51CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 1150
1030 09/26/2022 12:57CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 258
2260 09/26/2022 12:57CALCULATIONAromatic C9-C10 (Adjusted)µg/L 40.2
J26210/02/2022 14:51MADEP-EPH Aliphatic C9-C18 µg/L 28.2
336 10/02/2022 14:51MADEP-EPH Aromatic C11-C22 µg/L 61.2
15100 09/23/2022 19:51MADEP-VPH Aliphatic C5-C8 µg/L 1150
8100 09/26/2022 12:57MADEP-VPH Aliphatic C9-C12 µg/L 258
2260 09/26/2022 12:57MADEP-VPH Aromatic C9-C10 µg/L 40.2
5020 09/28/2022 08:18RSK-175 Methane µg/L 43.9
3180 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
V 89041MW-19
0.060 09/27/2022 17:446010DLeadmg/L 0.002
911 10/04/2022 23:176200BBenzeneµg/L 1.80
9.57 10/04/2022 23:176200Bn-Butylbenzene µg/L 1.80
10.0 10/04/2022 23:176200Bsec-Butyl benzene µg/L 2.00
691 10/04/2022 23:176200BEthylbenzeneµg/L 1.70
43.3 10/04/2022 23:176200BIsopropylbenzeneµg/L 1.80
10.2 10/04/2022 23:176200B4-Isopropyl toluene µg/L 0.890
10.9 10/04/2022 23:176200BMethyl tert-butyl ether (MTBE)µg/L 1.40
489 10/05/2022 18:126200BNaphthaleneµg/L 47.0
126 10/04/2022 23:176200Bn-Propylbenzene µg/L 1.90
6.06 10/04/2022 23:176200BStyreneµg/L 2.20
2040 10/05/2022 18:126200BTolueneµg/L 22.0
2690 10/05/2022 18:126200B1,2,4-Trimethylbenzene µg/L 19.0
672 10/04/2022 23:176200B1,3,5-Trimethylbenzene µg/L 1.80
1220 10/05/2022 18:126200Bo-Xylene µg/L 21.0
4350 10/05/2022 18:126200Bm,p-Xylene µg/L 42.0
5570 10/05/2022 18:126200BXylene (Total)µg/L 21.0
8350 09/23/2022 20:39CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 1150
16500 09/23/2022 20:39CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 2580
10500 09/23/2022 20:39CALCULATIONAromatic C9-C10 (Adjusted)µg/L 402
1240 10/02/2022 15:28MADEP-EPH Aliphatic C9-C18 µg/L 31.7
1140 10/02/2022 15:28MADEP-EPH Aromatic C11-C22 µg/L 68.8
11300 09/23/2022 20:39MADEP-VPH Aliphatic C5-C8 µg/L 1150
33300 09/23/2022 20:39MADEP-VPH Aliphatic C9-C12 µg/L 2580
10500 09/23/2022 20:39MADEP-VPH Aromatic C9-C10 µg/L 402
Page 7 of 115
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-265-0006
Report Limit
Project:Pitt County Mart
V 89041MW-19
542 09/27/2022 15:51RSK-175 Methane µg/L 4.39
1960 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
V 89042MW-21
0.117 09/27/2022 17:486010DLeadmg/L 0.012
J3.99 10/04/2022 20:516200BAcetoneµg/L 1.80
3.97 10/04/2022 20:516200BBenzeneµg/L 0.180
2.62 10/04/2022 20:516200BEthylbenzeneµg/L 0.170
1.44 10/04/2022 20:516200BNaphthaleneµg/L 0.470
J0.470 10/04/2022 20:516200Bn-Propylbenzene µg/L 0.190
J0.345 10/04/2022 20:516200BTolueneµg/L 0.220
1.13 10/04/2022 20:516200B1,2,4-Trimethylbenzene µg/L 0.190
J0.346 10/04/2022 20:516200B1,3,5-Trimethylbenzene µg/L 0.180
J0.344 10/04/2022 20:516200Bo-Xylene µg/L 0.210
1.55 10/04/2022 20:516200Bm,p-Xylene µg/L 0.420
J1.89 10/04/2022 20:516200BXylene (Total)µg/L 0.210
J10109/22/2022 17:099056ANitrate (NO3-N)µg/L 76.0
4890 09/22/2022 17:099056ASulfateµg/L 650
453 09/27/2022 14:33RSK-175 Methane µg/L 4.39
J80.0 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
V 89043MW-24
0.122 09/28/2022 15:156010DLeadmg/L 0.012
170 10/05/2022 17:496200BBenzeneµg/L 1.80
J0.417 10/04/2022 21:156200Bn-Butylbenzene µg/L 0.180
J0.274 10/04/2022 21:156200Bsec-Butyl benzene µg/L 0.200
69.6 10/04/2022 21:156200BEthylbenzeneµg/L 0.170
2.64 10/04/2022 21:156200BIsopropylbenzeneµg/L 0.180
17.8 10/04/2022 21:156200BNaphthaleneµg/L 0.470
6.71 10/04/2022 21:156200Bn-Propylbenzene µg/L 0.190
3.54 10/04/2022 21:156200BTolueneµg/L 0.220
24.8 10/04/2022 21:156200B1,2,4-Trimethylbenzene µg/L 0.190
1.85 10/04/2022 21:156200B1,3,5-Trimethylbenzene µg/L 0.180
0.887 10/04/2022 21:156200Bo-Xylene µg/L 0.210
64.5 10/04/2022 21:156200Bm,p-Xylene µg/L 0.420
65.4 10/04/2022 21:156200BXylene (Total)µg/L 0.210
2820 09/22/2022 16:059056ASulfateµg/L 650
654 09/23/2022 19:03CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
Page 8 of 115
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-265-0006
Report Limit
Project:Pitt County Mart
V 89043MW-24
291 09/26/2022 12:09CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
139 09/26/2022 12:09CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
J69.3 10/02/2022 16:40MADEP-EPH Aromatic C11-C22 µg/L 69.0
828 09/23/2022 19:03MADEP-VPH Aliphatic C5-C8 µg/L 115
565 09/26/2022 12:09MADEP-VPH Aliphatic C9-C12 µg/L 25.8
139 09/26/2022 12:09MADEP-VPH Aromatic C9-C10 µg/L 4.02
2350 09/27/2022 15:12RSK-175 Methane µg/L 4.39
220 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
V 89044MW-28
0.039 09/28/2022 15:196010DLeadmg/L 0.002
J3.99 10/04/2022 22:046200BAcetoneµg/L 1.80
J0.265 10/04/2022 22:046200BEthylbenzeneµg/L 0.170
J0.950 10/04/2022 22:046200BNaphthaleneµg/L 0.470
0.539 10/04/2022 22:046200BTolueneµg/L 0.220
0.713 10/04/2022 22:046200B1,2,4-Trimethylbenzene µg/L 0.190
J0.212 10/04/2022 22:046200B1,3,5-Trimethylbenzene µg/L 0.180
J0.325 10/04/2022 22:046200Bo-Xylene µg/L 0.210
J0.830 10/04/2022 22:046200Bm,p-Xylene µg/L 0.420
J1.16 10/04/2022 22:046200BXylene (Total)µg/L 0.210
J84.0 09/22/2022 17:259056ANitrate (NO3-N)µg/L 76.0
13400 09/22/2022 17:259056ASulfateµg/L 650
189 09/27/2022 14:20RSK-175 Methane µg/L 4.39
420 09/23/2022 10:30SM-3500-FE-B Ferrous Iron µg/L 50.0
Page 9 of 115

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Pitt County Mart Lab Report Number: 22-265-0006
Date: 10/6/2022
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,1-Dichloropropene QC Batch No: V24709/V24708
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable. Metals Analysis Method 6010D Sample 89035 (MW-5)
QC Batch No: V24421/V24276 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Sample 89036 (MW-37)
QC Batch No: V24421/V24276 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Sample 89038 (MW-39)
QC Batch No: V24421/V24276 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Sample 89042 (MW-21) QC Batch No: V24421/V24276 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Analyte: Lead
QC Batch No: V24470/V24276 CCB failed above MDL. Result 10X concentration. Result not affected.

Page 10 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:Trip Blank
89032 Matrix:
9/21/2022 8:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/04/22 16:24 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 16:24 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 16:24 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 16:24 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 16:24 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 16:24 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 16:24 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 16:24 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 16:24 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 16:24 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 16:24 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 16:24 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 16:24 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 16:24 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 16:24 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 16:24 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 16:24 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 16:24 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 16:24 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:Trip Blank
89032 Matrix:
9/21/2022 8:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 16:24 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 16:24 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 16:24 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 16:24 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 16:24 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 16:24 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 16:24 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 16:24 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 16:24 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 16:24 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 16:24 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 16:24 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 16:24 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 16:24 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 16:24 V24709MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 16:24 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 16:24 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 16:24 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 16:24 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 16:24 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:Trip Blank
89032 Matrix:
9/21/2022 8:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 16:24 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 16:24 V24709MSA
0.441 J µg/L 0.330 2.00Methylene Chloride 1 10/04/22 16:24 V24709MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 10/04/22 16:24 V24709MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 16:24 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 16:24 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 16:24 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 16:24 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 16:24 V24709MSA
<0.220 µg/L 0.220 0.500Toluene 1 10/04/22 16:24 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 16:24 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 16:24 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 16:24 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 16:24 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 16:24 V24709MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 16:24 V24709MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 16:24 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 16:24 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 16:24 V24709MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/04/22 16:24 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:Trip Blank
89032 Matrix:
9/21/2022 8:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 16:24 V24709MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 10/04/22 16:24 V24709
Surrogate: 4-Bromofluorobenzene 96.6 Limits: 70-130%10/04/22 16:241 MSA V24709
Surrogate: Dibromofluoromethane 98.4 Limits: 70-130%10/04/22 16:241 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%10/04/22 16:241 MSA V24709
Surrogate: Toluene-d8 84.4 Limits: 70-130%10/04/22 16:241 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-27
89033 Matrix:
9/21/2022 11:02
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
160 J µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
575 µg/L 4.39 17.5Methane 1 09/27/22 13:15 RSK-175TBL
314 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 18:13 9056ACMJ
16700 µg/L 650 2000Sulfate 1 09/22/22 18:13 9056ACMJ
0.024 mg/L 0.002 0.006Lead 1 09/27/22 17:07 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-27
89033 Matrix:
9/21/2022 11:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
7.86 J µg/L 1.80 10.0Acetone 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/04/22 16:48 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 16:48 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 16:48 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 16:48 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 16:48 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 16:48 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 16:48 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 16:48 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 16:48 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 16:48 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 16:48 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 16:48 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 16:48 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 16:48 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 16:48 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 16:48 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 16:48 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 16:48 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 16:48 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-27
89033 Matrix:
9/21/2022 11:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 16:48 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 16:48 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 16:48 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 16:48 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 16:48 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 16:48 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 16:48 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 16:48 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 16:48 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 16:48 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 16:48 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 16:48 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 16:48 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 16:48 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 16:48 V24709MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 16:48 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 16:48 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 16:48 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 16:48 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 16:48 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-27
89033 Matrix:
9/21/2022 11:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 16:48 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 16:48 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 16:48 V24709MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 10/04/22 16:48 V24709MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 16:48 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 16:48 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 16:48 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 16:48 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 16:48 V24709MSA
<0.220 µg/L 0.220 0.500Toluene 1 10/04/22 16:48 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 16:48 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 16:48 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 16:48 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 16:48 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 16:48 V24709MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 16:48 V24709MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 16:48 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 16:48 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 16:48 V24709MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/04/22 16:48 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-27
89033 Matrix:
9/21/2022 11:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 16:48 V24709MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 10/04/22 16:48 V24709
Surrogate: 4-Bromofluorobenzene 96.6 Limits: 70-130%10/04/22 16:481 MSA V24709
Surrogate: Dibromofluoromethane 98.2 Limits: 70-130%10/04/22 16:481 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 89.6 Limits: 70-130%10/04/22 16:481 MSA V24709
Surrogate: Toluene-d8 84.4 Limits: 70-130%10/04/22 16:481 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-27
89033 Matrix:
9/21/2022 11:02
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
14.0 J µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/23/22 15:28
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/23/22 15:28
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/23/22 15:28
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<30.5 µg/L 30.5 378Aliphatic C9-C18 1 09/30/22 17:47 V24581JLK
<134 µg/L 134 541Aliphatic C19-C36 1 09/30/22 17:47 V24581JLK
<66.1 µg/L 66.1 270Aromatic C11-C22 1 09/30/22 17:47 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 103 Limits: 40-140%09/30/22 17:471 JLK
MADEP-EPHSurrogate: Chlorooctadecane 51.9 Limits: 40-140%09/30/22 17:471 JLK
MADEP-EPHSurrogate: OTP Surrogate 63.4 Limits: 40-140%09/30/22 17:471 JLK
Surrogate: 2-Fluorobiphenyl 105 Limits: 40-140%09/30/22 17:471 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
14.0 J µg/L 11.5 50.0Aliphatic C5-C8 1 09/23/22 15:28 V24260TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 09/23/22 15:28 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-27
89033 Matrix:
9/21/2022 11:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 09/23/22 15:28 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)80.5 Limits: 70-130%09/23/22 15:281 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)85.4 Limits: 70-130%09/23/22 15:281 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-17
89034 Matrix:
9/21/2022 11:26
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
7090 µg/L 500 2000Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
7290 µg/L 43.9 175Methane 10 09/28/22 07:26 RSK-175TBL
<76.0 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 15:17 9056ACMJ
3250 µg/L 650 2000Sulfate 1 09/22/22 15:17 9056ACMJ
0.008 mg/L 0.002 0.006Lead 1 09/27/22 17:12 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-17
89034 Matrix:
9/21/2022 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
4.00 J µg/L 1.80 10.0Acetone 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/04/22 17:36 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 17:36 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 17:36 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 17:36 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 17:36 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 17:36 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 17:36 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 17:36 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 17:36 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 17:36 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 17:36 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 17:36 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 17:36 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 17:36 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 17:36 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 17:36 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 17:36 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 17:36 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 17:36 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-17
89034 Matrix:
9/21/2022 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 17:36 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 17:36 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 17:36 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 17:36 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 17:36 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 17:36 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 17:36 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 17:36 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 17:36 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 17:36 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 17:36 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 17:36 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 17:36 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 17:36 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 17:36 V24709MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 17:36 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 17:36 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 17:36 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 17:36 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 17:36 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-17
89034 Matrix:
9/21/2022 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 17:36 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 17:36 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 17:36 V24709MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 10/04/22 17:36 V24709MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 17:36 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 17:36 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 17:36 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 17:36 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 17:36 V24709MSA
<0.220 µg/L 0.220 0.500Toluene 1 10/04/22 17:36 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 17:36 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 17:36 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 17:36 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 17:36 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 17:36 V24709MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 17:36 V24709MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 17:36 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 17:36 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 17:36 V24709MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/04/22 17:36 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-17
89034 Matrix:
9/21/2022 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 17:36 V24709MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 10/04/22 17:36 V24709
Surrogate: 4-Bromofluorobenzene 92.8 Limits: 70-130%10/04/22 17:361 MSA V24709
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%10/04/22 17:361 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 89.4 Limits: 70-130%10/04/22 17:361 MSA V24709
Surrogate: Toluene-d8 84.2 Limits: 70-130%10/04/22 17:361 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-17
89034 Matrix:
9/21/2022 11:26
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/23/22 17:28
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/23/22 17:28
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/23/22 17:28
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 10/02/22 11:13 V24581JLK
<124 µg/L 124 500Aliphatic C19-C36 1 10/02/22 11:13 V24581JLK
<61.2 µg/L 61.2 250Aromatic C11-C22 1 10/02/22 11:13 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 96.0 Limits: 40-140%10/02/22 11:131 JLK
MADEP-EPHSurrogate: Chlorooctadecane 61.5 Limits: 40-140%10/02/22 11:131 JLK
MADEP-EPHSurrogate: OTP Surrogate 71.0 Limits: 40-140%10/02/22 11:131 JLK
Surrogate: 2-Fluorobiphenyl 95.0 Limits: 40-140%10/02/22 11:131 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 09/23/22 17:28 V24260TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 09/23/22 17:28 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-17
89034 Matrix:
9/21/2022 11:26
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 09/23/22 17:28 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)93.8 Limits: 70-130%09/23/22 17:281 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)101 Limits: 70-130%09/23/22 17:281 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-5
89035 Matrix:
9/21/2022 11:48
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
160 J µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
<4.39 µg/L 4.39 17.5Methane 1 09/27/22 13:41 RSK-175TBL
569 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 16:21 9056ACMJ
13400 µg/L 650 2000Sulfate 1 09/22/22 16:21 9056ACMJ
0.717 mg/L 0.012 0.030Lead 5 09/27/22 17:17 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-5
89035 Matrix:
9/21/2022 11:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
4.60 J µg/L 1.80 10.0Acetone 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/04/22 17:12 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 17:12 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 17:12 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 17:12 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 17:12 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 17:12 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 17:12 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 17:12 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 17:12 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 17:12 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 17:12 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 17:12 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 17:12 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 17:12 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 17:12 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 17:12 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 17:12 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 17:12 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 17:12 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-5
89035 Matrix:
9/21/2022 11:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 17:12 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 17:12 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 17:12 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 17:12 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 17:12 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 17:12 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 17:12 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 17:12 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 17:12 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 17:12 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 17:12 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 17:12 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 17:12 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 17:12 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 17:12 V24709MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 17:12 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 17:12 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 17:12 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 17:12 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 17:12 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-5
89035 Matrix:
9/21/2022 11:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 17:12 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 17:12 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 17:12 V24709MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 10/04/22 17:12 V24709MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 17:12 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 17:12 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 17:12 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 17:12 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 17:12 V24709MSA
<0.220 µg/L 0.220 0.500Toluene 1 10/04/22 17:12 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 17:12 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 17:12 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 17:12 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 17:12 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 17:12 V24709MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 17:12 V24709MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 17:12 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 17:12 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 17:12 V24709MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/04/22 17:12 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-5
89035 Matrix:
9/21/2022 11:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 17:12 V24709MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 10/04/22 17:12 V24709
Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%10/04/22 17:121 MSA V24709
Surrogate: Dibromofluoromethane 97.0 Limits: 70-130%10/04/22 17:121 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 92.0 Limits: 70-130%10/04/22 17:121 MSA V24709
Surrogate: Toluene-d8 84.4 Limits: 70-130%10/04/22 17:121 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-5
89035 Matrix:
9/21/2022 11:48
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/23/22 15:52
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/23/22 15:52
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/23/22 15:52
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<28.6 µg/L 28.6 355Aliphatic C9-C18 1 10/02/22 11:50 V24581JLK
<126 µg/L 126 508Aliphatic C19-C36 1 10/02/22 11:50 V24581JLK
<62.2 µg/L 62.2 254Aromatic C11-C22 1 10/02/22 11:50 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 91.9 Limits: 40-140%10/02/22 11:501 JLK
MADEP-EPHSurrogate: Chlorooctadecane 57.1 Limits: 40-140%10/02/22 11:501 JLK
MADEP-EPHSurrogate: OTP Surrogate 68.0 Limits: 40-140%10/02/22 11:501 JLK
Surrogate: 2-Fluorobiphenyl 94.8 Limits: 40-140%10/02/22 11:501 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 09/23/22 15:52 V24260TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 09/23/22 15:52 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-5
89035 Matrix:
9/21/2022 11:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 09/23/22 15:52 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)99.3 Limits: 70-130%09/23/22 15:521 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)109 Limits: 70-130%09/23/22 15:521 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-37
89036 Matrix:
9/21/2022 12:06
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
23800 µg/L 500 2000Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
5390 µg/L 43.9 175Methane 10 09/28/22 07:39 RSK-175TBL
<76.0 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 15:49 9056ACMJ
678 J µg/L 650 2000Sulfate 1 09/22/22 15:49 9056ACMJ
0.194 mg/L 0.012 0.030Lead 5 09/27/22 17:21 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-37
89036 Matrix:
9/21/2022 12:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
4.40 J µg/L 1.80 10.0Acetone 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/04/22 18:25 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 18:25 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 18:25 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 18:25 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 18:25 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 18:25 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 18:25 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 18:25 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 18:25 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 18:25 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 18:25 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 18:25 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 18:25 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 18:25 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 18:25 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 18:25 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 18:25 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 18:25 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 18:25 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-37
89036 Matrix:
9/21/2022 12:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 18:25 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 18:25 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 18:25 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 18:25 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 18:25 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 18:25 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 18:25 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 18:25 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 18:25 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 18:25 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 18:25 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 18:25 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 18:25 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 18:25 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 18:25 V24709MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 18:25 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 18:25 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 18:25 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 18:25 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 18:25 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-37
89036 Matrix:
9/21/2022 12:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 18:25 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 18:25 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 18:25 V24709MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 10/04/22 18:25 V24709MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 18:25 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 18:25 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 18:25 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 18:25 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 18:25 V24709MSA
<0.220 µg/L 0.220 0.500Toluene 1 10/04/22 18:25 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 18:25 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 18:25 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 18:25 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 18:25 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 18:25 V24709MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 18:25 V24709MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 18:25 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 18:25 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 18:25 V24709MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/04/22 18:25 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-37
89036 Matrix:
9/21/2022 12:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 18:25 V24709MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 10/04/22 18:25 V24709
Surrogate: 4-Bromofluorobenzene 94.2 Limits: 70-130%10/04/22 18:251 MSA V24709
Surrogate: Dibromofluoromethane 97.6 Limits: 70-130%10/04/22 18:251 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 91.6 Limits: 70-130%10/04/22 18:251 MSA V24709
Surrogate: Toluene-d8 84.6 Limits: 70-130%10/04/22 18:251 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-37
89036 Matrix:
9/21/2022 12:06
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/23/22 17:04
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/23/22 17:04
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/23/22 17:04
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<28.8 µg/L 28.8 357Aliphatic C9-C18 1 10/02/22 12:26 V24581JLK
<126 µg/L 126 510Aliphatic C19-C36 1 10/02/22 12:26 V24581JLK
<62.4 µg/L 62.4 255Aromatic C11-C22 1 10/02/22 12:26 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 113 Limits: 40-140%10/02/22 12:261 JLK
MADEP-EPHSurrogate: Chlorooctadecane 48.9 Limits: 40-140%10/02/22 12:261 JLK
MADEP-EPHSurrogate: OTP Surrogate 71.6 Limits: 40-140%10/02/22 12:261 JLK
Surrogate: 2-Fluorobiphenyl 110 Limits: 40-140%10/02/22 12:261 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 09/23/22 17:04 V24260TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 09/23/22 17:04 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-37
89036 Matrix:
9/21/2022 12:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 09/23/22 17:04 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)91.1 Limits: 70-130%09/23/22 17:041 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)105 Limits: 70-130%09/23/22 17:041 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-36
89037 Matrix:
9/21/2022 12:23
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
11900 µg/L 500 2000Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
3080 µg/L 43.9 175Methane 10 09/28/22 07:52 RSK-175TBL
<76.0 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 15:01 9056ACMJ
13800 µg/L 650 2000Sulfate 1 09/22/22 15:01 9056ACMJ
0.010 mg/L 0.002 0.006Lead 1 09/27/22 17:25 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-36
89037 Matrix:
9/21/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
20.9 µg/L 1.80 10.0Acetone 1 10/04/22 18:49 V24709MSA
188 µg/L 1.80 5.00Benzene 10 10/05/22 17:26 V24774ANG
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 18:49 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 18:49 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 18:49 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 18:49 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 18:49 V24709MSA
1.96 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 18:49 V24709MSA
1.20 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 18:49 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 18:49 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 18:49 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 18:49 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 18:49 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 18:49 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 18:49 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 18:49 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 18:49 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 18:49 V24709MSA
4.63 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 18:49 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 18:49 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 18:49 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 18:49 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 44 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-36
89037 Matrix:
9/21/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 18:49 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 18:49 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 18:49 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 18:49 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 18:49 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 18:49 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 18:49 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 18:49 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 18:49 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 18:49 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 18:49 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 18:49 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 18:49 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 18:49 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 18:49 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 18:49 V24709MSA
25.2 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 18:49 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 18:49 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 18:49 V24709MSA
3.31 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 18:49 V24709MSA
1.54 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 18:49 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 18:49 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 45 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-36
89037 Matrix:
9/21/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
4.61 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 18:49 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 18:49 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 18:49 V24709MSA
47.7 µg/L 0.470 1.00Naphthalene 1 10/04/22 18:49 V24709MSA
10.4 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 18:49 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 18:49 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 18:49 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 18:49 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 18:49 V24709MSA
46.4 µg/L 0.220 0.500Toluene 1 10/04/22 18:49 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 18:49 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 18:49 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 18:49 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 18:49 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 18:49 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 18:49 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 18:49 V24709MSA
188 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 10/05/22 17:26 V24774ANG
20.7 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 18:49 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 18:49 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 18:49 V24709MSA
14.5 µg/L 0.210 0.500o-Xylene 1 10/04/22 18:49 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 46 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-36
89037 Matrix:
9/21/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
101 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 18:49 V24709MSA
116 µg/L 0.210 0.500Xylene (Total)1 10/04/22 18:49 V24709KCC
Surrogate: 4-Bromofluorobenzene 91.0 Limits: 70-130%10/04/22 18:491 MSA V24709
Surrogate: Dibromofluoromethane 96.6 Limits: 70-130%10/04/22 18:491 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 95.6 Limits: 70-130%10/04/22 18:491 MSA V24709
Surrogate: Toluene-d8 83.6 Limits: 70-130%10/04/22 18:491 MSA V24709
Surrogate: 4-Bromofluorobenzene 105 Limits: 70-130%10/05/22 17:2610 ANG V24774
Surrogate: Dibromofluoromethane 99.8 Limits: 70-130%10/05/22 17:2610 ANG V24774
Surrogate: 1,2-Dichloroethane - d4 94.4 Limits: 70-130%10/05/22 17:2610 ANG V24774
Surrogate: Toluene-d8 98.0 Limits: 70-130%10/05/22 17:2610 ANG V24774
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 47 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-36
89037 Matrix:
9/21/2022 12:23
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
549 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/26/22 11:21
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/26/22 11:21
706 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/26/22 11:21
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
35.3 J µg/L 28.2 350Aliphatic C9-C18 1 10/02/22 13:03 V24581JLK
<124 µg/L 124 500Aliphatic C19-C36 1 10/02/22 13:03 V24581JLK
148 J µg/L 61.2 250Aromatic C11-C22 1 10/02/22 13:03 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 114 Limits: 40-140%10/02/22 13:031 JLK
MADEP-EPHSurrogate: Chlorooctadecane 57.0 Limits: 40-140%10/02/22 13:031 JLK
MADEP-EPHSurrogate: OTP Surrogate 73.0 Limits: 40-140%10/02/22 13:031 JLK
Surrogate: 2-Fluorobiphenyl 112 Limits: 40-140%10/02/22 13:031 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24363 09/26/22 08:00
783 µg/L 11.5 50.0Aliphatic C5-C8 1 09/26/22 11:21 V24364TBL
826 µg/L 25.8 50.0Aliphatic C9-C12 1 09/26/22 11:21 V24364TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 48 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-36
89037 Matrix:
9/21/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24363 09/26/22 08:00
706 µg/L 4.02 50.0Aromatic C9-C10 1 09/26/22 11:21 V24364TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)82.1 Limits: 70-130%09/26/22 11:211 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)83.2 Limits: 70-130%09/26/22 11:211 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 49 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-39
89038 Matrix:
9/21/2022 12:44
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
2930 µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
408 µg/L 4.39 17.5Methane 1 09/27/22 14:07 RSK-175TBL
87.0 J µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 17:41 9056ACMJ
6020 µg/L 650 2000Sulfate 1 09/22/22 17:41 9056ACMJ
0.789 mg/L 0.012 0.030Lead 5 09/27/22 17:30 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 50 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-39
89038 Matrix:
9/21/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
3.71 J µg/L 1.80 10.0Acetone 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/04/22 18:01 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 18:01 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 18:01 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 18:01 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 18:01 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 18:01 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 18:01 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 18:01 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 18:01 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 18:01 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 18:01 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 18:01 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 18:01 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 18:01 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 18:01 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 18:01 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 18:01 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 18:01 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 18:01 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 51 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-39
89038 Matrix:
9/21/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 18:01 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 18:01 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 18:01 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 18:01 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 18:01 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 18:01 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 18:01 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 18:01 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 18:01 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 18:01 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 18:01 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 18:01 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 18:01 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 18:01 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 18:01 V24709MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 18:01 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 18:01 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 18:01 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 18:01 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 18:01 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 52 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-39
89038 Matrix:
9/21/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 18:01 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 18:01 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 18:01 V24709MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 10/04/22 18:01 V24709MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 18:01 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 18:01 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 18:01 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 18:01 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 18:01 V24709MSA
<0.220 µg/L 0.220 0.500Toluene 1 10/04/22 18:01 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 18:01 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 18:01 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 18:01 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 18:01 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 18:01 V24709MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 18:01 V24709MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 18:01 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 18:01 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 18:01 V24709MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/04/22 18:01 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 53 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-39
89038 Matrix:
9/21/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 18:01 V24709MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 10/04/22 18:01 V24709
Surrogate: 4-Bromofluorobenzene 93.8 Limits: 70-130%10/04/22 18:011 MSA V24709
Surrogate: Dibromofluoromethane 96.8 Limits: 70-130%10/04/22 18:011 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 94.0 Limits: 70-130%10/04/22 18:011 MSA V24709
Surrogate: Toluene-d8 83.2 Limits: 70-130%10/04/22 18:011 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 54 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-39
89038 Matrix:
9/21/2022 12:44
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/23/22 17:51
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/23/22 17:51
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/23/22 17:51
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<29.2 µg/L 29.2 363Aliphatic C9-C18 1 10/02/22 13:39 V24581JLK
<128 µg/L 128 518Aliphatic C19-C36 1 10/02/22 13:39 V24581JLK
<63.4 µg/L 63.4 259Aromatic C11-C22 1 10/02/22 13:39 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 100 Limits: 40-140%10/02/22 13:391 JLK
MADEP-EPHSurrogate: Chlorooctadecane 47.8 Limits: 40-140%10/02/22 13:391 JLK
MADEP-EPHSurrogate: OTP Surrogate 58.0 Limits: 40-140%10/02/22 13:391 JLK
Surrogate: 2-Fluorobiphenyl 98.1 Limits: 40-140%10/02/22 13:391 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 09/23/22 17:51 V24260TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 09/23/22 17:51 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 55 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-39
89038 Matrix:
9/21/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 09/23/22 17:51 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)82.0 Limits: 70-130%09/23/22 17:511 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)91.3 Limits: 70-130%09/23/22 17:511 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 56 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-38
89039 Matrix:
9/21/2022 13:06
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
3740 µg/L 250 1000Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
2800 µg/L 43.9 175Methane 10 09/28/22 08:05 RSK-175TBL
<76.0 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 17:57 9056ACMJ
4550 µg/L 650 2000Sulfate 1 09/22/22 17:57 9056ACMJ
0.039 mg/L 0.002 0.006Lead 1 09/27/22 17:34 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 57 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-38
89039 Matrix:
9/21/2022 13:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
4.73 J µg/L 1.80 10.0Acetone 1 10/04/22 19:14 V24709MSA
43.2 µg/L 0.180 0.500Benzene 1 10/04/22 19:14 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 19:14 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 19:14 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 19:14 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 19:14 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 19:14 V24709MSA
0.527 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 19:14 V24709MSA
0.431 J
µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 19:14 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 19:14 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 19:14 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 19:14 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 19:14 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 19:14 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 19:14 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 19:14 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 19:14 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 19:14 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 19:14 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 19:14 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 19:14 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 19:14 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 58 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-38
89039 Matrix:
9/21/2022 13:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 19:14 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 19:14 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 19:14 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 19:14 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 19:14 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 19:14 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 19:14 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 19:14 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 19:14 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 19:14 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 19:14 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 19:14 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 19:14 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 19:14 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 19:14 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 19:14 V24709MSA
25.4 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 19:14 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 19:14 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 19:14 V24709MSA
2.82 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 19:14 V24709MSA
0.381 J µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 19:14 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 19:14 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 59 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-38
89039 Matrix:
9/21/2022 13:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
2.19 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 19:14 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 19:14 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 19:14 V24709MSA
22.0 µg/L 0.470 1.00Naphthalene 1 10/04/22 19:14 V24709MSA
5.85 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 19:14 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 19:14 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 19:14 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 19:14 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 19:14 V24709MSA
2.22 µg/L 0.220 0.500Toluene 1 10/04/22 19:14 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 19:14 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 19:14 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 19:14 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 19:14 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 19:14 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 19:14 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 19:14 V24709MSA
81.5 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 19:14 V24709MSA
2.24 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 19:14 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 19:14 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 19:14 V24709MSA
0.831 µg/L 0.210 0.500o-Xylene 1 10/04/22 19:14 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 60 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-38
89039 Matrix:
9/21/2022 13:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
13.7 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 19:14 V24709MSA
14.5 µg/L 0.210 0.500Xylene (Total)1 10/04/22 19:14 V24709
Surrogate: 4-Bromofluorobenzene 92.4 Limits: 70-130%10/04/22 19:141 MSA V24709
Surrogate: Dibromofluoromethane 96.6 Limits: 70-130%10/04/22 19:141 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 92.8 Limits: 70-130%10/04/22 19:141 MSA V24709
Surrogate: Toluene-d8 83.2 Limits: 70-130%10/04/22 19:141 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 61 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-38
89039 Matrix:
9/21/2022 13:06
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
92.6 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/26/22 11:45
159 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/26/22 11:45
208 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/26/22 11:45
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
34.5 J µg/L 28.2 350Aliphatic C9-C18 1 10/02/22 14:15 V24581JLK
<124 µg/L 124 500Aliphatic C19-C36 1 10/02/22 14:15 V24581JLK
<61.2 µg/L 61.2 250Aromatic C11-C22 1 10/02/22 14:15 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 102 Limits: 40-140%10/02/22 14:151 JLK
MADEP-EPHSurrogate: Chlorooctadecane 55.0 Limits: 40-140%10/02/22 14:151 JLK
MADEP-EPHSurrogate: OTP Surrogate 78.5 Limits: 40-140%10/02/22 14:151 JLK
Surrogate: 2-Fluorobiphenyl 108 Limits: 40-140%10/02/22 14:151 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24363 09/26/22 08:00
138 µg/L 11.5 50.0Aliphatic C5-C8 1 09/26/22 11:45 V24364TBL
407 µg/L 25.8 50.0Aliphatic C9-C12 1 09/26/22 11:45 V24364TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 62 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-38
89039 Matrix:
9/21/2022 13:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24363 09/26/22 08:00
208 µg/L 4.02 50.0Aromatic C9-C10 1 09/26/22 11:45 V24364TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)87.6 Limits: 70-130%09/26/22 11:451 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)91.5 Limits: 70-130%09/26/22 11:451 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 63 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-20
89040 Matrix:
9/21/2022 13:27
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
3180 µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
5020 µg/L 43.9 175Methane 10 09/28/22 08:18 RSK-175TBL
<76.0 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 14:46 9056ACMJ
<650 µg/L 650 2000Sulfate 1 09/22/22 14:46 9056ACMJ
0.014 mg/L 0.002 0.006Lead 1 09/27/22 17:39 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 64 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-20
89040 Matrix:
9/21/2022 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<180 µg/L 180 1000Acetone 100 10/04/22 23:41 V24709MSA
3290 µg/L 18.0 50.0Benzene 100 10/04/22 23:41 V24709MSA
<21.0 µg/L 21.0 50.0Bromobenzene 100 10/04/22 23:41 V24709MSA
<42.0 µg/L 42.0 100Bromochloromethane 100 10/04/22 23:41 V24709MSA
<16.0 µg/L 16.0 50.0Bromodichloromethane 100 10/04/22 23:41 V24709MSA
<150 µg/L 150 500Bromoform 100 10/04/22 23:41 V24709MSA
<28.0 µg/L 28.0 100Bromomethane 100 10/04/22 23:41 V24709MSA
<18.0 µg/L 18.0 50.0n-Butylbenzene 100 10/04/22 23:41 V24709MSA
<20.0 µg/L 20.0 50.0
sec-Butyl benzene 100 10/04/22 23:41 V24709MSA
<92.0 µg/L 92.0 200tert-Butyl benzene 100 10/04/22 23:41 V24709MSA
<18.0 µg/L 18.0 50.0Carbon Tetrachloride 100 10/04/22 23:41 V24709MSA
<19.0 µg/L 19.0 50.0Chlorobenzene 100 10/04/22 23:41 V24709MSA
<19.0 µg/L 19.0 50.0Chlorodibromomethane 100 10/04/22 23:41 V24709MSA
<43.0 µg/L 43.0 100Chloroethane 100 10/04/22 23:41 V24709MSA
<22.0 µg/L 22.0 50.0Chloroform 100 10/04/22 23:41 V24709MSA
<22.0 µg/L 22.0 50.0
Chloromethane 100 10/04/22 23:41 V24709MSA
<20.0 µg/L 20.0 50.02-Chlorotoluene 100 10/04/22 23:41 V24709MSA
<20.0 µg/L 20.0 50.04-Chlorotoluene 100 10/04/22 23:41 V24709MSA
<50.0 µg/L 50.0 50.0Di-Isopropyl Ether (DIPE)100 10/04/22 23:41 V24709MSA
<110 µg/L 110 2001,2-Dibromo-3-Chloropropane 100 10/04/22 23:41 V24709MSA
<20.0 µg/L 20.0 50.01,2-Dibromoethane 100 10/04/22 23:41 V24709MSA
<23.0 µg/L 23.0 50.0Dibromomethane 100 10/04/22 23:41 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 65 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-20
89040 Matrix:
9/21/2022 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<22.0 µg/L 22.0 50.01,2-Dichlorobenzene 100 10/04/22 23:41 V24709MSA
<19.0 µg/L 19.0 50.01,3-Dichlorobenzene 100 10/04/22 23:41 V24709MSA
<21.0 µg/L 21.0 50.01,4-Dichlorobenzene 100 10/04/22 23:41 V24709MSA
<120 µg/L 120 500Dichlorodifluoromethane 100 10/04/22 23:41 V24709MSA
<24.0 µg/L 24.0 50.01,1-Dichloroethane 100 10/04/22 23:41 V24709MSA
<15.0 µg/L 15.0 50.01,2-Dichloroethane 100 10/04/22 23:41 V24709MSA
<15.0 µg/L 15.0 50.01,1-Dichloroethene 100 10/04/22 23:41 V24709MSA
<20.0 µg/L 20.0 50.0cis-1,2-Dichloroethene 100 10/04/22 23:41 V24709MSA
<18.0 µg/L 18.0 50.0
trans-1,2-Dichloroethene 100 10/04/22 23:41 V24709MSA
<19.0 µg/L 19.0 50.01,2-Dichloropropane 100 10/04/22 23:41 V24709MSA
<13.0 µg/L 13.0 50.01,3-Dichloropropane 100 10/04/22 23:41 V24709MSA
<21.0 µg/L 21.0 2002,2-Dichloropropane 100 10/04/22 23:41 V24709MSA
<20.0 µg/L 20.0 50.01,1-Dichloropropene 100 10/04/22 23:41 V24709MSA
<21.0 µg/L 21.0 50.0cis-1,3-Dichloropropene 100 10/04/22 23:41 V24709MSA
<15.0 µg/L 15.0 50.0trans-1,3-Dichloropropene 100 10/04/22 23:41 V24709MSA
<4200 µg/L 4200 20000
Ethanol 100 10/04/22 23:41 V24709MSA
897 µg/L 17.0 50.0Ethylbenzene 100 10/04/22 23:41 V24709MSA
<35.0 µg/L 35.0 300Hexachlorobutadiene 100 10/04/22 23:41 V24709MSA
<38.0 µg/L 38.0 1002-Hexanone 100 10/04/22 23:41 V24709MSA
35.6 J µg/L 18.0 50.0Isopropylbenzene 100 10/04/22 23:41 V24709MSA
<8.90 µg/L 8.90 50.04-Isopropyl toluene 100 10/04/22 23:41 V24709MSA
<71.0 µg/L 71.0 500Methyl Ethyl Ketone (MEK)100 10/04/22 23:41 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 66 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-20
89040 Matrix:
9/21/2022 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
202 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 10/04/22 23:41 V24709MSA
<7.80 µg/L 7.80 1004-Methyl-2-Pentanone 100 10/04/22 23:41 V24709MSA
<33.0 µg/L 33.0 200Methylene Chloride 100 10/04/22 23:41 V24709MSA
1960 µg/L 47.0 100Naphthalene 100 10/04/22 23:41 V24709MSA
103 µg/L 19.0 50.0n-Propylbenzene 100 10/04/22 23:41 V24709MSA
<22.0 µg/L 22.0 50.0Styrene 100 10/04/22 23:41 V24709MSA
<16.0 µg/L 16.0 50.01,1,1,2-Tetrachloroethane 100 10/04/22 23:41 V24709MSA
<16.0 µg/L 16.0 50.01,1,2,2-Tetrachloroethane 100 10/04/22 23:41 V24709MSA
<22.0 µg/L 22.0 50.0
Tetrachloroethene 100 10/04/22 23:41 V24709MSA
3930 µg/L 22.0 50.0Toluene 100 10/04/22 23:41 V24709MSA
<38.0 µg/L 38.0 50.01,2,3-Trichlorobenzene 100 10/04/22 23:41 V24709MSA
<31.0 µg/L 31.0 50.01,2,4-Trichlorobenzene 100 10/04/22 23:41 V24709MSA
<16.0 µg/L 16.0 50.01,1,1-Trichloroethane 100 10/04/22 23:41 V24709MSA
<9.60 µg/L 9.60 50.01,1,2-Trichloroethane 100 10/04/22 23:41 V24709MSA
<18.0 µg/L 18.0 50.0Trichloroethene 100 10/04/22 23:41 V24709MSA
<18.0 µg/L 18.0 50.0
Trichlorofluoromethane 100 10/04/22 23:41 V24709MSA
<27.0 µg/L 27.0 50.01,2,3-Trichloropropane 100 10/04/22 23:41 V24709MSA
757 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 10/04/22 23:41 V24709MSA
183 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 10/04/22 23:41 V24709MSA
<100 µg/L 100 500Vinyl Acetate 100 10/04/22 23:41 V24709MSA
<17.0 µg/L 17.0 50.0Vinyl Chloride 100 10/04/22 23:41 V24709MSA
1130 µg/L 21.0 50.0o-Xylene 100 10/04/22 23:41 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 67 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-20
89040 Matrix:
9/21/2022 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
2780 µg/L 42.0 100m,p-Xylene 100 10/04/22 23:41 V24709MSA
3910 µg/L 21.0 50.0Xylene (Total)100 10/04/22 23:41 V24709
Surrogate: 4-Bromofluorobenzene 96.2 Limits: 70-130%10/04/22 23:41100 MSA V24709
Surrogate: Dibromofluoromethane 94.0 Limits: 70-130%10/04/22 23:41100 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 87.2 Limits: 70-130%10/04/22 23:41100 MSA V24709
Surrogate: Toluene-d8 83.4 Limits: 70-130%10/04/22 23:41100 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 68 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-20
89040 Matrix:
9/21/2022 13:27
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
7880 µg/L 1150 5000Aliphatic C5-C8 (Adjusted)100 09/23/22 19:51
1030 µg/L 258 500Aliphatics C9-C12 (Adjusted)10 09/26/22 12:57
2260 µg/L 40.2 500Aromatic C9-C10 (Adjusted)10 09/26/22 12:57
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
262 J µg/L 28.2 350Aliphatic C9-C18 1 10/02/22 14:51 V24581JLK
<124 µg/L 124 500Aliphatic C19-C36 1 10/02/22 14:51 V24581JLK
336 µg/L 61.2 250Aromatic C11-C22 1 10/02/22 14:51 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 105 Limits: 40-140%10/02/22 14:511 JLK
MADEP-EPHSurrogate: Chlorooctadecane 56.0 Limits: 40-140%10/02/22 14:511 JLK
MADEP-EPHSurrogate: OTP Surrogate 73.5 Limits: 40-140%10/02/22 14:511 JLK
Surrogate: 2-Fluorobiphenyl 111 Limits: 40-140%10/02/22 14:511 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
15100 µg/L 1150 5000Aliphatic C5-C8 100 09/23/22 19:51 V24260TBL
8100 µg/L 258 500Aliphatic C9-C12 10 09/26/22 12:57 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 69 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-20
89040 Matrix:
9/21/2022 13:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
2260 µg/L 40.2 500Aromatic C9-C10 10 09/26/22 12:57 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)78.9 Limits: 70-130%09/26/22 12:5710 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)77.2 Limits: 70-130%09/26/22 12:5710 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 70 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-19
89041 Matrix:
9/21/2022 13:48
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
1960 µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
542 µg/L 4.39 17.5Methane 1 09/27/22 15:51 RSK-175TBL
<76.0 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 15:33 9056ACMJ
<650 µg/L 650 2000Sulfate 1 09/22/22 15:33 9056ACMJ
0.060 mg/L 0.002 0.006Lead 1 09/27/22 17:44 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 71 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-19
89041 Matrix:
9/21/2022 13:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
<18.0 µg/L 18.0 100Acetone 10 10/04/22 23:17 V24709MSA
911 µg/L 1.80 5.00Benzene 10 10/04/22 23:17 V24709MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 10/04/22 23:17 V24709MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 10/04/22 23:17 V24709MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 10/04/22 23:17 V24709MSA
<15.0 µg/L 15.0 50.0Bromoform 10 10/04/22 23:17 V24709MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 10/04/22 23:17 V24709MSA
9.57 µg/L 1.80 5.00n-Butylbenzene 10 10/04/22 23:17 V24709MSA
10.0 µg/L 2.00 5.00
sec-Butyl benzene 10 10/04/22 23:17 V24709MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 10/04/22 23:17 V24709MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 10/04/22 23:17 V24709MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 10/04/22 23:17 V24709MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 10/04/22 23:17 V24709MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 10/04/22 23:17 V24709MSA
<2.20 µg/L 2.20 5.00Chloroform 10 10/04/22 23:17 V24709MSA
<2.20 µg/L 2.20 5.00
Chloromethane 10 10/04/22 23:17 V24709MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 10/04/22 23:17 V24709MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 10/04/22 23:17 V24709MSA
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 10/04/22 23:17 V24709MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 10/04/22 23:17 V24709MSA
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 10/04/22 23:17 V24709MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 10/04/22 23:17 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 72 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-19
89041 Matrix:
9/21/2022 13:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 10/04/22 23:17 V24709MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 10/04/22 23:17 V24709MSA
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 10/04/22 23:17 V24709MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 10/04/22 23:17 V24709MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 10/04/22 23:17 V24709MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 10/04/22 23:17 V24709MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 10/04/22 23:17 V24709MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 10/04/22 23:17 V24709MSA
<1.80 µg/L 1.80 5.00
trans-1,2-Dichloroethene 10 10/04/22 23:17 V24709MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 10/04/22 23:17 V24709MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 10/04/22 23:17 V24709MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 10/04/22 23:17 V24709MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 10/04/22 23:17 V24709MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 10/04/22 23:17 V24709MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 10/04/22 23:17 V24709MSA
<420 µg/L 420 2000
Ethanol 10 10/04/22 23:17 V24709MSA
691 µg/L 1.70 5.00Ethylbenzene 10 10/04/22 23:17 V24709MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 10/04/22 23:17 V24709MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 10/04/22 23:17 V24709MSA
43.3 µg/L 1.80 5.00Isopropylbenzene 10 10/04/22 23:17 V24709MSA
10.2 µg/L 0.890 5.004-Isopropyl toluene 10 10/04/22 23:17 V24709MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 10/04/22 23:17 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 73 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-19
89041 Matrix:
9/21/2022 13:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
10.9 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 10/04/22 23:17 V24709MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 10/04/22 23:17 V24709MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 10/04/22 23:17 V24709MSA
489 µg/L 47.0 100Naphthalene 100 10/05/22 18:12 V24774ANG
126 µg/L 1.90 5.00n-Propylbenzene 10 10/04/22 23:17 V24709MSA
6.06 µg/L 2.20 5.00Styrene 10 10/04/22 23:17 V24709MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 10/04/22 23:17 V24709MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 10/04/22 23:17 V24709MSA
<2.20 µg/L 2.20 5.00
Tetrachloroethene 10 10/04/22 23:17 V24709MSA
2040 µg/L 22.0 50.0Toluene 100 10/05/22 18:12 V24774ANG
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 10/04/22 23:17 V24709MSA
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 10/04/22 23:17 V24709MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 10/04/22 23:17 V24709MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 10/04/22 23:17 V24709MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 10/04/22 23:17 V24709MSA
<1.80 µg/L 1.80 5.00
Trichlorofluoromethane 10 10/04/22 23:17 V24709MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 10/04/22 23:17 V24709MSA
2690 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 10/05/22 18:12 V24774ANG
672 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 10/04/22 23:17 V24709MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 10/04/22 23:17 V24709MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 10/04/22 23:17 V24709MSA
1220 µg/L 21.0 50.0o-Xylene 100 10/05/22 18:12 V24774ANG
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 74 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-19
89041 Matrix:
9/21/2022 13:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
4350 µg/L 42.0 100m,p-Xylene 100 10/05/22 18:12 V24774ANG
5570 µg/L 21.0 50.0Xylene (Total)100 10/05/22 18:12 V24774
Surrogate: 4-Bromofluorobenzene 91.8 Limits: 70-130%10/04/22 23:1710 MSA V24709
Surrogate: Dibromofluoromethane 96.2 Limits: 70-130%10/04/22 23:1710 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 90.8 Limits: 70-130%10/04/22 23:1710 MSA V24709
Surrogate: Toluene-d8 82.0 Limits: 70-130%10/04/22 23:1710 MSA V24709
Surrogate: 4-Bromofluorobenzene 106 Limits: 70-130%10/05/22 18:12100 ANG V24774
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%10/05/22 18:12100 ANG V24774
Surrogate: 1,2-Dichloroethane - d4 97.6 Limits: 70-130%10/05/22 18:12100 ANG V24774
Surrogate: Toluene-d8 97.8 Limits: 70-130%10/05/22 18:12100 ANG V24774
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 75 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-19
89041 Matrix:
9/21/2022 13:48
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
8350 µg/L 1150 5000Aliphatic C5-C8 (Adjusted)10 09/23/22 20:39
16500 µg/L 2580 5000Aliphatics C9-C12 (Adjusted)10 09/23/22 20:39
10500 µg/L 402 5000Aromatic C9-C10 (Adjusted)100 09/23/22 20:39
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
1240 µg/L 31.7 393Aliphatic C9-C18 1 10/02/22 15:28 V24581JLK
<139 µg/L 139 562Aliphatic C19-C36 1 10/02/22 15:28 V24581JLK
1140 µg/L 68.8 281Aromatic C11-C22 1 10/02/22 15:28 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 102 Limits: 40-140%10/02/22 15:281 JLK
MADEP-EPHSurrogate: Chlorooctadecane 63.6 Limits: 40-140%10/02/22 15:281 JLK
MADEP-EPHSurrogate: OTP Surrogate 73.8 Limits: 40-140%10/02/22 15:281 JLK
Surrogate: 2-Fluorobiphenyl 108 Limits: 40-140%10/02/22 15:281 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
11300 µg/L 1150 5000Aliphatic C5-C8 100 09/23/22 20:39 V24260TBL
33300 µg/L 2580 5000Aliphatic C9-C12 100 09/23/22 20:39 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 76 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-19
89041 Matrix:
9/21/2022 13:48
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
10500 µg/L 402 5000Aromatic C9-C10 100 09/23/22 20:39 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)81.9 Limits: 70-130%09/23/22 20:39100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)92.3 Limits: 70-130%09/23/22 20:39100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 77 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-21
89042 Matrix:
9/21/2022 14:09
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
80.0 J µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
453 µg/L 4.39 17.5Methane 1 09/27/22 14:33 RSK-175TBL
101 J µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 17:09 9056ACMJ
4890 µg/L 650 2000Sulfate 1 09/22/22 17:09 9056ACMJ
0.117 mg/L 0.012 0.030Lead 5 09/27/22 17:48 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 78 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-21
89042 Matrix:
9/21/2022 14:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
3.99 J µg/L 1.80 10.0Acetone 1 10/04/22 20:51 V24709MSA
3.97 µg/L 0.180 0.500Benzene 1 10/04/22 20:51 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 20:51 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 20:51 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 20:51 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 20:51 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 20:51 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 20:51 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 20:51 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 20:51 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 20:51 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 20:51 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 20:51 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 20:51 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 20:51 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 20:51 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 20:51 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 20:51 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 20:51 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 20:51 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 20:51 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 20:51 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 79 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-21
89042 Matrix:
9/21/2022 14:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 20:51 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 20:51 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 20:51 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 20:51 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 20:51 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 20:51 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 20:51 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 20:51 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 20:51 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 20:51 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 20:51 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 20:51 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 20:51 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 20:51 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 20:51 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 20:51 V24709MSA
2.62 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 20:51 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 20:51 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 20:51 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 20:51 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 20:51 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 20:51 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 80 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-21
89042 Matrix:
9/21/2022 14:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 20:51 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 20:51 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 20:51 V24709MSA
1.44 µg/L 0.470 1.00Naphthalene 1 10/04/22 20:51 V24709MSA
0.470 J µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 20:51 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 20:51 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 20:51 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 20:51 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 20:51 V24709MSA
0.345 J µg/L 0.220 0.500Toluene 1 10/04/22 20:51 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 20:51 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 20:51 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 20:51 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 20:51 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 20:51 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 20:51 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 20:51 V24709MSA
1.13 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 20:51 V24709MSA
0.346 J µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 20:51 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 20:51 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 20:51 V24709MSA
0.344 J µg/L 0.210 0.500o-Xylene 1 10/04/22 20:51 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 81 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-21
89042 Matrix:
9/21/2022 14:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
1.55 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 20:51 V24709MSA
1.89 J µg/L 0.210 0.500Xylene (Total)1 10/04/22 20:51 V24709KCC
Surrogate: 4-Bromofluorobenzene 93.8 Limits: 70-130%10/04/22 20:511 MSA V24709
Surrogate: Dibromofluoromethane 97.4 Limits: 70-130%10/04/22 20:511 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 91.2 Limits: 70-130%10/04/22 20:511 MSA V24709
Surrogate: Toluene-d8 83.8 Limits: 70-130%10/04/22 20:511 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 82 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-21
89042 Matrix:
9/21/2022 14:09
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/23/22 16:16
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/23/22 16:16
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/23/22 16:16
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<28.8 µg/L 28.8 357Aliphatic C9-C18 1 10/02/22 16:04 V24581JLK
<126 µg/L 126 510Aliphatic C19-C36 1 10/02/22 16:04 V24581JLK
<62.4 µg/L 62.4 255Aromatic C11-C22 1 10/02/22 16:04 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 117 Limits: 40-140%10/02/22 16:041 JLK
MADEP-EPHSurrogate: Chlorooctadecane 49.5 Limits: 40-140%10/02/22 16:041 JLK
MADEP-EPHSurrogate: OTP Surrogate 73.5 Limits: 40-140%10/02/22 16:041 JLK
Surrogate: 2-Fluorobiphenyl 116 Limits: 40-140%10/02/22 16:041 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 09/23/22 16:16 V24260TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 09/23/22 16:16 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 83 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-21
89042 Matrix:
9/21/2022 14:09
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 09/23/22 16:16 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)90.4 Limits: 70-130%09/23/22 16:161 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)100 Limits: 70-130%09/23/22 16:161 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 84 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-24
89043 Matrix:
9/21/2022 14:31
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
220 µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
2350 µg/L 4.39 17.5Methane 1 09/27/22 15:12 RSK-175TBL
<76.0 µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 16:05 9056ACMJ
2820 µg/L 650 2000Sulfate 1 09/22/22 16:05 9056ACMJ
0.122 mg/L 0.012 0.030Lead 5 09/28/22 15:15 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 85 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-24
89043 Matrix:
9/21/2022 14:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 10/04/22 21:15 V24709MSA
170 µg/L 1.80 5.00Benzene 10 10/05/22 17:49 V24774ANG
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 21:15 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 21:15 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 21:15 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 21:15 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 21:15 V24709MSA
0.417 J µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 21:15 V24709MSA
0.274 J
µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 21:15 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 21:15 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 21:15 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 21:15 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 21:15 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 21:15 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 21:15 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 21:15 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 21:15 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 21:15 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 21:15 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 21:15 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 21:15 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 21:15 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 86 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-24
89043 Matrix:
9/21/2022 14:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 21:15 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 21:15 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 21:15 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 21:15 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 21:15 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 21:15 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 21:15 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 21:15 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 21:15 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 21:15 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 21:15 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 21:15 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 21:15 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 21:15 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 21:15 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 21:15 V24709MSA
69.6 µg/L 0.170 0.500Ethylbenzene 1 10/04/22 21:15 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 21:15 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 21:15 V24709MSA
2.64 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 21:15 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 21:15 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 21:15 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 87 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-24
89043 Matrix:
9/21/2022 14:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 21:15 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 21:15 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 21:15 V24709MSA
17.8 µg/L 0.470 1.00Naphthalene 1 10/04/22 21:15 V24709MSA
6.71 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 21:15 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 21:15 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 21:15 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 21:15 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 21:15 V24709MSA
3.54 µg/L 0.220 0.500Toluene 1 10/04/22 21:15 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 21:15 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 21:15 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 21:15 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 21:15 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 21:15 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 21:15 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 21:15 V24709MSA
24.8 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 21:15 V24709MSA
1.85 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 21:15 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 21:15 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 21:15 V24709MSA
0.887 µg/L 0.210 0.500o-Xylene 1 10/04/22 21:15 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 88 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-24
89043 Matrix:
9/21/2022 14:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00 V24772 10/05/22 09:00
64.5 µg/L 0.420 1.00m,p-Xylene 1 10/04/22 21:15 V24709MSA
65.4 µg/L 0.210 0.500Xylene (Total)1 10/04/22 21:15 V24709
Surrogate: 4-Bromofluorobenzene 94.0 Limits: 70-130%10/04/22 21:151 MSA V24709
Surrogate: Dibromofluoromethane 94.2 Limits: 70-130%10/04/22 21:151 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 93.0 Limits: 70-130%10/04/22 21:151 MSA V24709
Surrogate: Toluene-d8 82.8 Limits: 70-130%10/04/22 21:151 MSA V24709
Surrogate: 4-Bromofluorobenzene 106 Limits: 70-130%10/05/22 17:4910 ANG V24774
Surrogate: Dibromofluoromethane 102 Limits: 70-130%10/05/22 17:4910 ANG V24774
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%10/05/22 17:4910 ANG V24774
Surrogate: Toluene-d8 96.8 Limits: 70-130%10/05/22 17:4910 ANG V24774
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 89 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-24
89043 Matrix:
9/21/2022 14:31
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
654 µg/L 115 500Aliphatic C5-C8 (Adjusted)1 09/23/22 19:03
291 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/26/22 12:09
139 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/26/22 12:09
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<31.8 µg/L 31.8 395Aliphatic C9-C18 1 10/02/22 16:40 V24581JLK
<140 µg/L 140 565Aliphatic C19-C36 1 10/02/22 16:40 V24581JLK
69.3 J µg/L 69.0 282Aromatic C11-C22 1 10/02/22 16:40 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 128 Limits: 40-140%10/02/22 16:401 JLK
MADEP-EPHSurrogate: Chlorooctadecane 57.5 Limits: 40-140%10/02/22 16:401 JLK
MADEP-EPHSurrogate: OTP Surrogate 89.4 Limits: 40-140%10/02/22 16:401 JLK
Surrogate: 2-Fluorobiphenyl 127 Limits: 40-140%10/02/22 16:401 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
828 µg/L 115 500Aliphatic C5-C8 10 09/23/22 19:03 V24260TBL
565 µg/L 25.8 50.0Aliphatic C9-C12 1 09/26/22 12:09 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 90 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-24
89043 Matrix:
9/21/2022 14:31
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
139 µg/L 4.02 50.0Aromatic C9-C10 1 09/26/22 12:09 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)81.9 Limits: 70-130%09/26/22 12:091 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.6 Limits: 70-130%09/26/22 12:091 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 91 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-28
89044 Matrix:
9/21/2022 14:54
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
420 µg/L 50.0 200Ferrous Iron 1 09/23/22 10:30 SM-3500-FE-BSLO
189 µg/L 4.39 17.5Methane 1 09/27/22 14:20 RSK-175TBL
84.0 J µg/L 76.0 200Nitrate (NO3-N)1 09/22/22 17:25 9056ACMJ
13400 µg/L 650 2000Sulfate 1 09/22/22 17:25 9056ACMJ
0.039 mg/L 0.002 0.006Lead 1 09/28/22 15:19 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 92 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-28
89044 Matrix:
9/21/2022 14:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
3.99 J µg/L 1.80 10.0Acetone 1 10/04/22 22:04 V24709MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/04/22 22:04 V24709MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/04/22 22:04 V24709MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/04/22 22:04 V24709MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/04/22 22:04 V24709MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/04/22 22:04 V24709MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/04/22 22:04 V24709MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/04/22 22:04 V24709MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/04/22 22:04 V24709MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/04/22 22:04 V24709MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/04/22 22:04 V24709MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/04/22 22:04 V24709MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/04/22 22:04 V24709MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/04/22 22:04 V24709MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/04/22 22:04 V24709MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/04/22 22:04 V24709MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/04/22 22:04 V24709MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/04/22 22:04 V24709MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/04/22 22:04 V24709MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/04/22 22:04 V24709MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/04/22 22:04 V24709MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/04/22 22:04 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 93 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-28
89044 Matrix:
9/21/2022 14:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/04/22 22:04 V24709MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/04/22 22:04 V24709MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/04/22 22:04 V24709MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/04/22 22:04 V24709MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/04/22 22:04 V24709MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/04/22 22:04 V24709MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/04/22 22:04 V24709MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/04/22 22:04 V24709MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/04/22 22:04 V24709MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/04/22 22:04 V24709MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/04/22 22:04 V24709MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/04/22 22:04 V24709MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/04/22 22:04 V24709MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/04/22 22:04 V24709MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/04/22 22:04 V24709MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/04/22 22:04 V24709MSA
0.265 J µg/L 0.170 0.500Ethylbenzene 1 10/04/22 22:04 V24709MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/04/22 22:04 V24709MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/04/22 22:04 V24709MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/04/22 22:04 V24709MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/04/22 22:04 V24709MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/04/22 22:04 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 94 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-28
89044 Matrix:
9/21/2022 14:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/04/22 22:04 V24709MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/04/22 22:04 V24709MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/04/22 22:04 V24709MSA
0.950 J µg/L 0.470 1.00Naphthalene 1 10/04/22 22:04 V24709MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/04/22 22:04 V24709MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/04/22 22:04 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/04/22 22:04 V24709MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/04/22 22:04 V24709MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/04/22 22:04 V24709MSA
0.539 µg/L 0.220 0.500Toluene 1 10/04/22 22:04 V24709MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/04/22 22:04 V24709MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/04/22 22:04 V24709MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/04/22 22:04 V24709MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/04/22 22:04 V24709MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/04/22 22:04 V24709MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/04/22 22:04 V24709MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/04/22 22:04 V24709MSA
0.713 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/04/22 22:04 V24709MSA
0.212 J µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/04/22 22:04 V24709MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/04/22 22:04 V24709MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/04/22 22:04 V24709MSA
0.325 J µg/L 0.210 0.500o-Xylene 1 10/04/22 22:04 V24709MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 95 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-28
89044 Matrix:
9/21/2022 14:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V24708 10/04/22 09:00
0.830 J µg/L 0.420 1.00m,p-Xylene 1 10/04/22 22:04 V24709MSA
1.16 J µg/L 0.210 0.500Xylene (Total)1 10/04/22 22:04 V24709KCC
Surrogate: 4-Bromofluorobenzene 96.4 Limits: 70-130%10/04/22 22:041 MSA V24709
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%10/04/22 22:041 MSA V24709
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%10/04/22 22:041 MSA V24709
Surrogate: Toluene-d8 83.6 Limits: 70-130%10/04/22 22:041 MSA V24709
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 96 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-28
89044 Matrix:
9/21/2022 14:54
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 09/23/22 16:40
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 09/23/22 16:40
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 09/23/22 16:40
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24466 09/29/22 09:03
<30.6 µg/L 30.6 380Aliphatic C9-C18 1 10/02/22 17:16 V24581JLK
<135 µg/L 135 543Aliphatic C19-C36 1 10/02/22 17:16 V24581JLK
<66.6 µg/L 66.6 272Aromatic C11-C22 1 10/02/22 17:16 V24581JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 99.8 Limits: 40-140%10/02/22 17:161 JLK
MADEP-EPHSurrogate: Chlorooctadecane 56.2 Limits: 40-140%10/02/22 17:161 JLK
MADEP-EPHSurrogate: OTP Surrogate 71.0 Limits: 40-140%10/02/22 17:161 JLK
Surrogate: 2-Fluorobiphenyl 101 Limits: 40-140%10/02/22 17:161 JLK V24581
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 09/23/22 16:40 V24260TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 09/23/22 16:40 V24260TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 97 of 115
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-265-0006
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #3753 Received : 09/22/2022
Pitt County Mart
Report Date : 10/06/2022
Sample ID :
Lab No :
Sampled:MW-28
89044 Matrix:
9/21/2022 14:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24259 09/23/22 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 09/23/22 16:40 V24260TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)92.2 Limits: 70-130%09/23/22 16:401 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)99.6 Limits: 70-130%09/23/22 16:401 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 98 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Metals Analysis
6010D
V24386,V24421QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V24276
Associated Lab Samples: 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB-V24276 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/27/22 13:300.0060.002<0.002mg/LLead
LCS-V24276Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1080.1080.100mg/LLead 80-120
V 89083-MS-V24276 V 89083-MSD-V24276Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.108 1060.1100.1000.1000.002mg/LLead 108 75-125 1.8 20.0
V 89083-PDS-V24276Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
09/27/22 16:221090.272mg/LLead
Page 1 of 14Date:10/06/2022 01:54 PM
Page 99 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V24709QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V24708
Associated Lab Samples: 89032, 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB-V24708 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/04/22 15:5910.01.80<1.80µg/LAcetone
10/04/22 15:590.5000.180<0.180µg/LBenzene
10/04/22 15:590.5000.210<0.210µg/LBromobenzene
10/04/22 15:591.000.420<0.420µg/LBromochloromethane
10/04/22 15:590.5000.160<0.160µg/LBromodichloromethane
10/04/22 15:595.001.50<1.50µg/LBromoform
10/04/22 15:591.000.280<0.280µg/LBromomethane
10/04/22 15:590.5000.180<0.180µg/Ln-Butylbenzene
10/04/22 15:590.5000.200<0.200µg/Lsec-Butyl benzene
10/04/22 15:592.000.920<0.920µg/Ltert-Butyl benzene
10/04/22 15:590.5000.180<0.180µg/LCarbon Tetrachloride
10/04/22 15:590.5000.190<0.190µg/LChlorobenzene
10/04/22 15:590.5000.190<0.190µg/LChlorodibromomethane
10/04/22 15:591.000.430<0.430µg/LChloroethane
10/04/22 15:590.5000.220<0.220µg/LChloroform
10/04/22 15:590.5000.220<0.220µg/LChloromethane
10/04/22 15:590.5000.200<0.200µg/L2-Chlorotoluene
10/04/22 15:590.5000.200<0.200µg/L4-Chlorotoluene
10/04/22 15:590.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
10/04/22 15:592.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
10/04/22 15:590.5000.200<0.200µg/L1,2-Dibromoethane
10/04/22 15:590.5000.230<0.230µg/LDibromomethane
10/04/22 15:590.5000.220<0.220µg/L1,2-Dichlorobenzene
10/04/22 15:590.5000.190<0.190µg/L1,3-Dichlorobenzene
10/04/22 15:590.5000.210<0.210µg/L1,4-Dichlorobenzene
10/04/22 15:595.001.20<1.20µg/LDichlorodifluoromethane
10/04/22 15:590.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 14Date:10/06/2022 01:54 PM
Page 100 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V24709QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V24708
Associated Lab Samples: 89032, 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB-V24708 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/04/22 15:590.5000.150<0.150µg/L1,2-Dichloroethane
10/04/22 15:590.5000.150<0.150µg/L1,1-Dichloroethene
10/04/22 15:590.5000.200<0.200µg/Lcis-1,2-Dichloroethene
10/04/22 15:590.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
10/04/22 15:590.5000.190<0.190µg/L1,2-Dichloropropane
10/04/22 15:590.5000.130<0.130µg/L1,3-Dichloropropane
10/04/22 15:592.000.210<0.210µg/L2,2-Dichloropropane
10/04/22 15:590.5000.200<0.200µg/L1,1-Dichloropropene
10/04/22 15:590.5000.210<0.210µg/Lcis-1,3-Dichloropropene
10/04/22 15:590.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
10/04/22 15:5920042.0<42.0µg/LEthanol
10/04/22 15:590.5000.170<0.170µg/LEthylbenzene
10/04/22 15:593.000.350<0.350µg/LHexachlorobutadiene
10/04/22 15:591.000.380<0.380µg/L2-Hexanone
10/04/22 15:590.5000.180<0.180µg/LIsopropylbenzene
10/04/22 15:590.5000.089<0.089µg/L4-Isopropyl toluene
10/04/22 15:595.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
10/04/22 15:591.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
10/04/22 15:591.000.078<0.078µg/L4-Methyl-2-Pentanone
10/04/22 15:592.000.330<0.330µg/LMethylene Chloride
10/04/22 15:591.000.470<0.470µg/LNaphthalene
10/04/22 15:590.5000.190<0.190µg/Ln-Propylbenzene
10/04/22 15:590.5000.220<0.220µg/LStyrene
10/04/22 15:590.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
10/04/22 15:590.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
10/04/22 15:590.5000.220<0.220µg/LTetrachloroethene
10/04/22 15:590.5000.220<0.220µg/LToluene
Page 3 of 14Date:10/06/2022 01:54 PM
Page 101 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V24709QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V24708
Associated Lab Samples: 89032, 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB-V24708 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/04/22 15:590.5000.380<0.380µg/L1,2,3-Trichlorobenzene
10/04/22 15:590.5000.310<0.310µg/L1,2,4-Trichlorobenzene
10/04/22 15:590.5000.160<0.160µg/L1,1,1-Trichloroethane
10/04/22 15:590.5000.096<0.096µg/L1,1,2-Trichloroethane
10/04/22 15:590.5000.180<0.180µg/LTrichloroethene
10/04/22 15:590.5000.180<0.180µg/LTrichlorofluoromethane
10/04/22 15:590.5000.270<0.270µg/L1,2,3-Trichloropropane
10/04/22 15:590.5000.190<0.190µg/L1,2,4-Trimethylbenzene
10/04/22 15:590.5000.180<0.180µg/L1,3,5-Trimethylbenzene
10/04/22 15:595.001.00<1.00µg/LVinyl Acetate
10/04/22 15:590.5000.170<0.170µg/LVinyl Chloride
10/04/22 15:590.5000.210<0.210µg/Lo-Xylene
10/04/22 15:591.000.420<0.420µg/Lm,p-Xylene
10/04/22 15:594-Bromofluorobenzene (S)94.4 70-130
10/04/22 15:59Dibromofluoromethane (S)95.4 70-130
10/04/22 15:591,2-Dichloroethane - d4 (S)88.4 70-130
10/04/22 15:59Toluene-d8 (S)84.6 70-130
LCS-V24708 LCSD-V24708Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
42.9 10711244.940.0µg/LAcetone 40-160 4.5 20.0
25.1 12612925.820.0µg/LBenzene 70-130 2.7 20.0
18.0 90.091.018.220.0µg/LBromobenzene 70-130 1.1 20.0
24.5 12312525.020.0µg/LBromochloromethane 70-130 2.0 20.0
22.1 11111623.120.0µg/LBromodichloromethane 70-130 4.4 20.0
Page 4 of 14Date:10/06/2022 01:54 PM
Page 102 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V24709QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V24708
LCS-V24708 LCSD-V24708Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.4 97.010320.520.0µg/LBromoform 70-130 5.5 20.0
26.6 13313727.420.0µg/LBromomethane 60-140 2.9 20.0
19.0 95.095.019.020.0µg/Ln-Butylbenzene 70-130 0.0 20.0
18.5 92.593.018.620.0µg/Lsec-Butyl benzene 70-130 0.5 20.0
18.5 92.591.518.320.0µg/Ltert-Butyl benzene 70-130 1.0 20.0
25.3 12712524.920.0µg/LCarbon Tetrachloride 70-130 1.5 20.0
20.7 10410520.920.0µg/LChlorobenzene 70-130 0.9 20.0
19.3 96.598.019.620.0µg/LChlorodibromomethane 70-130 1.5 20.0
24.1 12113026.020.0µg/LChloroethane 60-140 7.5 20.0
24.4 12212324.620.0µg/LChloroform 70-130 0.8 20.0
19.9 99.510521.020.0µg/LChloromethane 60-140 5.3 20.0
19.0 95.096.019.220.0µg/L2-Chlorotoluene 70-130 1.0 20.0
18.5 92.593.518.720.0µg/L4-Chlorotoluene 70-130 1.0 20.0
23.0 11511923.820.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.4 20.0
18.5 92.595.019.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 2.6 20.0
20.1 10110320.520.0µg/L1,2-Dibromoethane 70-130 1.9 20.0
24.3 12213025.920.0µg/LDibromomethane 70-130 6.3 20.0
19.3 96.597.019.420.0µg/L1,2-Dichlorobenzene 70-130 0.5 20.0
19.3 96.598.019.620.0µg/L1,3-Dichlorobenzene 70-130 1.5 20.0
19.1 95.596.019.220.0µg/L1,4-Dichlorobenzene 70-130 0.5 20.0
25.4 12713126.120.0µg/LDichlorodifluoromethane 60-140 2.7 20.0
24.1 12112525.020.0µg/L1,1-Dichloroethane 70-130 3.6 20.0
23.6 11812224.320.0µg/L1,2-Dichloroethane 70-130 2.9 20.0
23.2 11611923.720.0µg/L1,1-Dichloroethene 70-130 2.1 20.0
23.8 11912424.720.0µg/Lcis-1,2-Dichloroethene 70-130 3.7 20.0
23.9 12012224.320.0µg/Ltrans-1,2-Dichloroethene 70-130 1.6 20.0
Page 5 of 14Date:10/06/2022 01:54 PM
Page 103 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V24709QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V24708
LCS-V24708 LCSD-V24708Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
24.5 12312625.220.0µg/L1,2-Dichloropropane 70-130 2.8 20.0
20.5 10310320.620.0µg/L1,3-Dichloropropane 70-130 0.4 20.0
23.8 11912424.720.0µg/L2,2-Dichloropropane 70-130 3.7 20.0
25.4 127133*26.520.0µg/L1,1-Dichloropropene 70-130 4.2 20.0
23.6 11812024.020.0µg/Lcis-1,3-Dichloropropene 70-130 1.6 20.0
23.6 11812024.020.0µg/Ltrans-1,3-Dichloropropene 70-130 1.6 20.0
501 100105526500µg/LEthanol 60-140 4.8 20.0
20.8 10410521.020.0µg/LEthylbenzene 70-130 0.9 20.0
19.4 97.098.019.620.0µg/LHexachlorobutadiene 70-130 1.0 20.0
16.9 84.586.517.320.0µg/L2-Hexanone 60-140 2.3 20.0
18.9 94.594.518.920.0µg/LIsopropylbenzene 70-130 0.0 20.0
19.2 96.096.519.320.0µg/L4-Isopropyl toluene 70-130 0.5 20.0
22.0 11010921.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.9 20.0
23.8 11912224.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.4 20.0
21.4 10711122.120.0µg/L4-Methyl-2-Pentanone 60-140 3.2 20.0
23.2 11612023.920.0µg/LMethylene Chloride 70-130 2.9 20.0
18.3 91.593.518.720.0µg/LNaphthalene 70-130 2.1 20.0
18.7 93.594.018.820.0µg/Ln-Propylbenzene 70-130 0.5 20.0
21.1 10610621.220.0µg/LStyrene 70-130 0.4 20.0
20.6 10310520.920.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.4 20.0
18.1 90.592.018.420.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.6 20.0
20.7 10410420.820.0µg/LTetrachloroethene 70-130 0.4 20.0
25.1 12612925.820.0µg/LToluene 70-130 2.7 20.0
21.0 10510320.620.0µg/L1,2,3-Trichlorobenzene 70-130 1.9 20.0
19.5 97.599.519.920.0µg/L1,2,4-Trichlorobenzene 70-130 2.0 20.0
24.4 12212224.420.0µg/L1,1,1-Trichloroethane 70-130 0.0 20.0
Page 6 of 14* QC Fail Date:10/06/2022 01:54 PM
Page 104 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V24709QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V24708
LCS-V24708 LCSD-V24708Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
24.1 12112625.220.0µg/L1,1,2-Trichloroethane 70-130 4.4 20.0
23.8 11912324.520.0µg/LTrichloroethene 70-130 2.8 20.0
25.4 12713226.420.0µg/LTrichlorofluoromethane 60-140 3.8 20.0
16.7 83.593.018.620.0µg/L1,2,3-Trichloropropane 70-130 10.7 20.0
18.5 92.593.018.620.0µg/L1,2,4-Trimethylbenzene 70-130 0.5 20.0
18.6 93.094.018.820.0µg/L1,3,5-Trimethylbenzene 70-130 1.0 20.0
26.6 13313526.920.0µg/LVinyl Acetate 60-140 1.1 20.0
25.1 12612925.720.0µg/LVinyl Chloride 60-140 2.3 20.0
20.6 10310320.620.0µg/Lo-Xylene 70-130 0.0 20.0
44.3 11111345.040.0µg/Lm,p-Xylene 70-130 1.5 20.0
93.892.04-Bromofluorobenzene (S)70-130
96.298.2Dibromofluoromethane (S)70-130
95.097.21,2-Dichloroethane - d4 (S)70-130
86.285.4Toluene-d8 (S)70-130
Page 7 of 14Date:10/06/2022 01:54 PM
Page 105 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V24774QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V24772
Associated Lab Samples: 89037, 89041, 89043
LRB-V24772 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/05/22 13:180.5000.180<0.180µg/LBenzene
10/05/22 13:181.000.470<0.470µg/LNaphthalene
10/05/22 13:180.5000.220<0.220µg/LToluene
10/05/22 13:180.5000.190<0.190µg/L1,2,4-Trimethylbenzene
10/05/22 13:180.5000.210<0.210µg/Lo-Xylene
10/05/22 13:181.000.420<0.420µg/Lm,p-Xylene
10/05/22 13:184-Bromofluorobenzene (S)106 70-130
10/05/22 13:18Dibromofluoromethane (S)103 70-130
10/05/22 13:181,2-Dichloroethane - d4 (S)97.8 70-130
10/05/22 13:18Toluene-d8 (S)97.0 70-130
LCS-V24772 LCSD-V24772Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.0 10011222.420.0µg/LBenzene 70-130 11.3 20.0
19.7 98.510320.520.0µg/LNaphthalene 70-130 3.9 20.0
20.1 10111022.020.0µg/LToluene 70-130 9.0 20.0
18.3 91.510520.920.0µg/L1,2,4-Trimethylbenzene 70-130 13.2 20.0
19.1 95.510521.020.0µg/Lo-Xylene 70-130 9.4 20.0
40.8 10210943.440.0µg/Lm,p-Xylene 70-130 6.1 20.0
1051074-Bromofluorobenzene (S)70-130
127122Dibromofluoromethane (S)70-130
1041001,2-Dichloroethane - d4 (S)70-130
97.697.6Toluene-d8 (S)70-130
Page 8 of 14Date:10/06/2022 01:54 PM
Page 106 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Anions by Ion Chromatography
9056A
V24265QC Analytical Batch(es):
Analysis Method:
Analysis Description:
SW-9056A (PREP)
QC Prep:V24264
Associated Lab Samples: 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB-V24264 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/22/22 09:2220076.0<76.0µg/LNitrate (NO3-N)
09/22/22 09:222000650<650µg/LSulfate
LCS-V24264Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
97.038704000µg/LNitrate (NO3-N)80-120
97.03860040000µg/LSulfate 80-120
V 89037-MS-V24264 V 89037-MSD-V24264Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
4310 108430040004000<79.0µg/LNitrate (NO3-N)108 80-120 0.2 20
54800 10354100400004000013800µg/LSulfate 101 80-120 1.2 20
V 89040-MS-V24264 V 89040-MSD-V24264Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
4180 105409040004000<79.0µg/LNitrate (NO3-N)102 80-120 2.1 20
44700 112438004000040000<676µg/LSulfate 110 80-120 2.0 20
Page 9 of 14Date:10/06/2022 01:54 PM
Page 107 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V24581QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V24466
Associated Lab Samples: 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB-V24466 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/30/22 15:5735028.2<28.2µg/LAliphatic C9-C18
09/30/22 15:57500124<124µg/LAliphatic C19-C36
09/30/22 15:5725061.2<61.2µg/LAromatic C11-C22
09/30/22 15:572-Fluorobiphenyl (S)96.2 40-140
09/30/22 15:572-Bromonaphthalene (S)94.7 40-140
09/30/22 15:57Chlorooctadecane (S)55.5 40-140
09/30/22 15:57OTP Surrogate (S)58.5 40-140
LCS-V24466 LCSD-V24466Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
316 52.650.6304600µg/LAliphatic C9-C18 40-140 3.8 50.0
546 68.259.1473800µg/LAliphatic C19-C36 40-140 14.3 50.0
1640 96.482.314001700µg/LAromatic C11-C22 40-140 15.7 50.0
10699.72-Fluorobiphenyl (S)40-140
1051042-Bromonaphthalene (S)40-140
69.561.5Chlorooctadecane (S)40-140
78.570.5OTP Surrogate (S)40-140
Page 10 of 14Date:10/06/2022 01:54 PM
Page 108 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V24260QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V24259
Associated Lab Samples: 89033, 89034, 89035, 89036, 89038, 89040, 89041, 89042, 89043, 89044
LRB-V24259 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/23/22 15:0450.011.5<11.5µg/LAliphatic C5-C8
09/23/22 15:0450.025.8<25.8µg/LAliphatic C9-C12
09/23/22 15:0450.04.02<4.02µg/LAromatic C9-C10
09/23/22 15:042,5-Dibromotoluene (FID) (S)79.7 70-130
09/23/22 15:042,5-Dibromotoluene (PID) (S)84.8 70-130
LCS-V24259 LCSD-V24259Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
364 121119357300µg/LAliphatic C5-C8 70-130 1.9 50.0
372 124123369300µg/LAliphatic C9-C12 70-130 0.8 50.0
119 119123123100µg/LAromatic C9-C10 70-130 3.3 50.0
83.680.32,5-Dibromotoluene (FID) (S)70-130
84.576.52,5-Dibromotoluene (PID) (S)70-130
Page 11 of 14Date:10/06/2022 01:54 PM
Page 109 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V24364QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V24363
Associated Lab Samples: 89037, 89039
LRB-V24363 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/26/22 10:5750.011.5<11.5µg/LAliphatic C5-C8
09/26/22 10:5750.025.8<25.8µg/LAliphatic C9-C12
09/26/22 10:5750.04.02<4.02µg/LAromatic C9-C10
09/26/22 10:572,5-Dibromotoluene (FID) (S)106 70-130
09/26/22 10:572,5-Dibromotoluene (PID) (S)101 70-130
LCS-V24363 LCSD-V24363Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
322 107106318300µg/LAliphatic C5-C8 70-130 1.2 50.0
356 119120359300µg/LAliphatic C9-C12 70-130 0.8 50.0
112 112110110100µg/LAromatic C9-C10 70-130 1.8 50.0
10587.22,5-Dibromotoluene (FID) (S)70-130
92.288.52,5-Dibromotoluene (PID) (S)70-130
Page 12 of 14Date:10/06/2022 01:54 PM
Page 110 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
QC Prep Batch Method:
RSK-175
RSK-175
V24397QC Analytical Batch(es):
Analysis Method:
Analysis Description:
RSK-175 (Prep)
QC Prep:V24396
Associated Lab Samples: 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB-V24396 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/27/22 13:0217.54.39<4.39µg/LMethane
LCS-V24396Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
105288273µg/LMethane 85-115
V 89035-DUP-V24396Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 09/28/22 08:300.0<17.5< 17.5µg/LMethane
Page 13 of 14Date:10/06/2022 01:54 PM
Page 111 of 115
Quality Control Data
22-265-0006Report No:
Project Description:
Client ID:Geological Resources, Inc.
Pitt County Mart
Ferrous Iron
SM-3500-FE-B
V24234QC Analytical Batch:
Analysis Method:
Analysis Description:
Associated Lab Samples: 89033, 89034, 89035, 89036, 89037, 89038, 89039, 89040, 89041, 89042, 89043, 89044
LRB Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/23/22 10:3020050.0<50.0µg/LFerrous Iron
LCSLaboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
98.019502000µg/LFerrous Iron 90-110
V 89033-MS V 89033-MSDMatrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
2130 107207020002000<50.0µg/LFerrous Iron 103 80-120 2.8 20
Page 14 of 14Date:10/06/2022 01:54 PM
Page 112 of 115
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-265-0006
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 2.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
One of the HCL amber liters for sample MW-17 arrived broken.
Analyze samples for lead as well per Rae Brown.
Signature:Angelo Norvell Date & Time:09/22/2022 12:11:05
Special precautions or instructions included?
Comments:
Page 113 of 115
Page 114 of 115
Page 115 of 115

APPENDIX F
Contaminant Mass Reduction Calculations
Area ID Well ID
Area
(ft²)
Average Well
Depth
(ft.)
Average
Depth to
Water
(ft.)
Water Column
Height
(ft)
Volume
(ft³)
Volume
(L)
Effective
Porosity
Effective
Volume
(L)
MW-19
MW-20
MW-21
MW-23
MW-24
MW-36
MW-38
Area Date Well
Benzene
(μ/L)
Toluene
(μ/L)
Ethylbenzene
(μ/L)
Xylenes
(μ/L)
MTBE
(μ/L)
Naphthalene
(μ/L)
Total
(μ/L)
DTW
(ft.)
Average
Water
Column
Height
(ft.)
Total Average
Mass
(g)
Percent Red. To Date Red.
MW-19 6,600 17000.00 3400.00 16300.00 250.00 1300.00 44850.00 4.67
MW-20 680 180.00 250.00 600.00 56.00 70.00 1836.00 5.94
MW-21 140 11.00 93.00 37.00 0.00 34.00 315.00 4.69
MW-23 9,600 22,000 3,000 13,300 960 850 49710.00 5.21
MW-24 0.00 0.00 0.00 0.00 0.00 0.00 0.00 3.11
MW-36 0.00 0.00 0.00 0.00 0.00 0.00 0.00 5.82
MW-38 0.00 0.00 0.00 0.00 0.00 0.00 0.00 3.37
Avg. 2431.43 5598.71 963.29 4319.57 180.86 322.00 13815.86 4.69
MW-19 911 2040.00 691.00 5570.00 10.90 489.00 9711.90 8.56
MW-20 3,290 3930.00 897.00 3910.00 202.00 1960.00 14189.00 8.89
MW-21 3.97 0.35 2.62 0.00 0.00 1.44 8.38 8.43
MW-23 FP FP FP FP FP FP 0.00 FP
MW-24 170 3.54 69.60 65.40 <0.140 17.80 326.34 8.22
MW-36 188 46.40 25.20 116.00 4.61 47.70 427.91 8.81
MW-38 43.2 2.22 25.40 14.50 2.19 22.00 109.51 6.06
Avg. 767.70 1003.75 285.14 1612.65 43.94 422.99 3539.01 8.16
Date
Average Water
Column Height
(ft.)
03/23/15 7.31 49,176
09/21/22 3.84 6612
Notes:
• FP: Free Product
• Area of the contaminant plume is calculated from Figure 11
• Height of the water column is calculated by subtracting the average depth to water from the average well depth of the referenced monitoring wells
• Volume of the contaminant plume is calculated by multiplying the area of the plume by the average height of the water column during each sampling event
• Effective porosity is assumed based on the sub-surface soil profile obtained from well construction records and soil boring logs
• Total mass was calculated by multiplying the total contaminant concentrations for the sampling event with effective volume
• Contaminant mass cannot be calculated in wells containing FP; therefore, the total contaminant mass is based on the known concentrations in the area for each sampling event.
• Concentrations in MW-21 and MW-24 were not available for the 03/23/15 calculations. The last known concentrations, from 03/23/13 for MW-21 and 06/27/02 for MW-24, were used instead.
• Naphthalene concentrations were not available for the 3/1/03 and 10/16/03 sampling events.
86.6%87%
Total Contaminant Mass
(g)
Percent Reduction
Compared to Previous
Event
Percent Reduction To Date
--- ---
Area 1
03/23/15 49,175.88 --- ---7.31
09/21/22 3.84 6,611.67 86.6% 86.6%
PERCENTAGE REDUCTIONS
PITT COUNTRY MART (INCIDENT NO. 14864)
Baseline Event
1 85,943.5 12 4.69 7.31 628,247 17,789,944 0.20 3,557,989
7.25
7.3
7.35
7.4
7.45
7.5
7.55
7.6
7.65
7.7
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
Average Water Column Height (ft)Contaminant Mass (grams)Time
Total Contaminant Mass vs. Time
Pitt Country Mart (Incident NO. 14864)
Contaminant Mass (grams)Water Column Height (ft)Linear (Contaminant Mass (grams))