WA-240_6433_CA_RPTS_20190131_MRP

01/30/19
Technical Report for
GRI (Geological Resources Inc.)
Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
6433/3243/0-000432
SGS Job Number: FA61067
Sampling Date: 01/23/19
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: Justin Radford
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 01/30/19
e-Hardcopy 2.0
Automated Report
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FA61067
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FA61067-1: MW-11R ...................................................................................................6
3.2: FA61067-2: MW-12 ......................................................................................................8
Section 4: Misc. Forms ............................................................................................................10
4.1: Chain of Custody ...........................................................................................................11
Section 5: MS Volatiles - QC Data Summaries .....................................................................13
5.1: Method Blank Summary ................................................................................................14
5.2: Blank Spike Summary ...................................................................................................17
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................20 123452 of 22
FA61067
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA61067
Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Project No: 6433/3243/0-000432
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA61067-1 01/23/19 11:42 MS 01/24/19 AQ Ground Water MW-11R
FA61067-2 01/23/19 11:45 MS 01/24/19 AQ Ground Water MW-12
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FA610671
Summary of Hits Page 1 of 1
Job Number:FA61067
Account:GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Collected:01/23/19
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA61067-1 MW-11R
Benzene 1.1 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 0.23 J 0.50 0.13 ug/l SM 6200B
Methyl Chloride 0.77 0.50 0.20 ug/l SM 6200B
Methyl Tert Butyl Ether 60.0 1.0 0.25 ug/l SM 6200B
FA61067-2 MW-12
Benzene 12.8 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 1.7 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 1.6 0.50 0.13 ug/l SM 6200B
Chloroethane 0.28 J 0.50 0.20 ug/l SM 6200B
Ethylbenzene 25.2 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 4.0 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.36 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 6.5 0.50 0.13 ug/l SM 6200B
Naphthalene 16.0 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 11.0 0.50 0.13 ug/l SM 6200B
Toluene 5.1 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 36.2 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.90 0.50 0.13 ug/l SM 6200B
m,p-Xylene 11.5 1.0 0.13 ug/l SM 6200B
o-Xylene 8.2 0.50 0.13 ug/l SM 6200B
Xylene (total)19.7 1.5 0.25 ug/l SM 6200B
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FA610672
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
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FA610673
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-11R
Lab Sample ID:FA61067-1 Date Sampled:01/23/19
Matrix:AQ - Ground Water Date Received:01/24/19
Method:SM 6200B Percent Solids:n/a
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E097827.D 1 01/28/19 16:45 AB n/a n/a VE2067
Run #2 E097843.D 2 01/29/19 12:11 AB n/a n/a VE2068
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1.1 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA6106733.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-11R
Lab Sample ID:FA61067-1 Date Sampled:01/23/19
Matrix:AQ - Ground Water Date Received:01/24/19
Method:SM 6200B Percent Solids:n/a
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.23 0.50 0.13 ug/l J
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.77 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 60.0 a 1.0 0.25 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%100%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%107%70-130%
2037-26-5 Toluene-D8 100%97%70-130%
460-00-4 4-Bromofluorobenzene 102%108%70-130%
(a) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA6106733.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-12
Lab Sample ID:FA61067-2 Date Sampled:01/23/19
Matrix:AQ - Ground Water Date Received:01/24/19
Method:SM 6200B Percent Solids:n/a
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E097828.D 1 01/28/19 17:09 AB n/a n/a VE2067
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 12.8 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 1.7 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 1.6 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane 0.28 0.50 0.20 ug/l J
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA6106733.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-12
Lab Sample ID:FA61067-2 Date Sampled:01/23/19
Matrix:AQ - Ground Water Date Received:01/24/19
Method:SM 6200B Percent Solids:n/a
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 25.2 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 4.0 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 0.36 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 6.5 0.50 0.13 ug/l
91-20-3 Naphthalene 16.0 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 11.0 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 5.1 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 36.2 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.90 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 11.5 1.0 0.13 ug/l
95-47-6 o-Xylene 8.2 0.50 0.13 ug/l
1330-20-7 Xylene (total)19.7 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA6106733.2
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
10 of 22
FA610674
FA61067: Chain of Custody
Page 1 of 2
11 of 22
FA6106744.1
Job Number:FA61067 Client:GRI
Date / Time Received:1/24/2019 10:15:00 AM Delivery Method:FED EX
Project:3243
Airbill #'s:1015899983460003281100812565570154
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (3.6);
Cooler 1: (3.4);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.2; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SHAYLAP Date:Date:1/24/2019 10:15:00 A
FA61067: Chain of Custody
Page 2 of 2
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FA6106744.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
13 of 22
FA610675
Method Blank Summary Page 1 of 2
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE2067-MB E097812.D 1 01/28/19 AB n/a n/a VE2067
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1, FA61067-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
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FA6106755.1.1
Method Blank Summary Page 2 of 2
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE2067-MB E097812.D 1 01/28/19 AB n/a n/a VE2067
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1, FA61067-2
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 98%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
15 of 22
FA6106755.1.1
Method Blank Summary Page 1 of 1
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE2068-MB E097839.D 1 01/29/19 AB n/a n/a VE2068
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1
CAS No.Compound Result RL MDL Units Q
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
16 of 22
FA6106755.1.2
Blank Spike Summary Page 1 of 2
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE2067-BS E097810.D 1 01/28/19 AB n/a n/a VE2067
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1, FA61067-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.7 107 70-130
108-86-1 Bromobenzene 10 10.6 106 70-130
74-97-5 Bromochloromethane 10 9.8 98 70-130
75-27-4 Bromodichloromethane 10 10.5 105 70-130
75-25-2 Bromoform 10 9.7 97 70-130
104-51-8 n-Butylbenzene 10 11.5 115 70-130
135-98-8 sec-Butylbenzene 10 11.3 113 70-130
98-06-6 tert-Butylbenzene 10 10.8 108 70-130
56-23-5 Carbon Tetrachloride 10 10.6 106 70-130
108-90-7 Chlorobenzene 10 10.4 104 70-130
75-00-3 Chloroethane 10 9.7 97 60-140
67-66-3 Chloroform 10 10.1 101 70-130
95-49-8 o-Chlorotoluene 10 10.9 109 70-130
106-43-4 p-Chlorotoluene 10 10.9 109 70-130
124-48-1 Dibromochloromethane 10 10.2 102 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 11.0 110 70-130
106-93-4 1,2-Dibromoethane 10 10.3 103 70-130
75-71-8 Dichlorodifluoromethane 10 12.6 126 60-140
95-50-1 1,2-Dichlorobenzene 10 10.4 104 70-130
541-73-1 1,3-Dichlorobenzene 10 10.8 108 70-130
106-46-7 1,4-Dichlorobenzene 10 10.3 103 70-130
75-34-3 1,1-Dichloroethane 10 11.0 110 70-130
107-06-2 1,2-Dichloroethane 10 10.2 102 70-130
75-35-4 1,1-Dichloroethylene 10 11.3 113 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.3 103 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.6 106 70-130
78-87-5 1,2-Dichloropropane 10 10.8 108 70-130
142-28-9 1,3-Dichloropropane 10 10.1 101 70-130
594-20-7 2,2-Dichloropropane 10 10.3 103 70-130
563-58-6 1,1-Dichloropropene 10 11.2 112 70-130
10061-01-5 cis-1,3-Dichloropropene 10 10.4 104 70-130
10061-02-6 trans-1,3-Dichloropropene 10 11.1 111 70-130
108-20-3 Di-Isopropyl Ether 10 10.4 104 70-130
100-41-4 Ethylbenzene 10 10.7 107 70-130
87-68-3 Hexachlorobutadiene 10 10.9 109 70-130
98-82-8 Isopropylbenzene 10 11.1 111 70-130
* = Outside of Control Limits.
17 of 22
FA6106755.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE2067-BS E097810.D 1 01/28/19 AB n/a n/a VE2067
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1, FA61067-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 11.2 112 70-130
74-83-9 Methyl Bromide 10 9.0 90 60-140
74-87-3 Methyl Chloride 10 12.2 122 60-140
74-95-3 Methylene Bromide 10 9.9 99 70-130
75-09-2 Methylene Chloride 10 11.4 114 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.9 99 70-130
91-20-3 Naphthalene 10 11.2 112 70-130
103-65-1 n-Propylbenzene 10 11.2 112 70-130
100-42-5 Styrene 10 10.3 103 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10.1 101 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.6 106 70-130
127-18-4 Tetrachloroethylene 10 10.8 108 70-130
108-88-3 Toluene 10 10.6 106 70-130
87-61-6 1,2,3-Trichlorobenzene 10 11.2 112 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.9 109 70-130
71-55-6 1,1,1-Trichloroethane 10 10.3 103 70-130
79-00-5 1,1,2-Trichloroethane 10 10.5 105 70-130
79-01-6 Trichloroethylene 10 10.6 106 70-130
75-69-4 Trichlorofluoromethane 10 9.9 99 60-140
96-18-4 1,2,3-Trichloropropane 10 10.2 102 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.4 104 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.9 109 70-130
75-01-4 Vinyl Chloride 10 10.4 104 60-140
m,p-Xylene 20 21.3 107 70-130
95-47-6 o-Xylene 10 10.3 103 70-130
1330-20-7 Xylene (total)30 31.6 105 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
* = Outside of Control Limits.
18 of 22
FA6106755.2.1
Blank Spike Summary Page 1 of 1
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE2068-BS E097837.D 1 01/29/19 AB n/a n/a VE2068
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
1634-04-4 Methyl Tert Butyl Ether 10 10.1 101 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 106%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
* = Outside of Control Limits.
19 of 22
FA6106755.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA60923-2MS E097822.D 5 01/28/19 AB n/a n/a VE2067
FA60923-2MSD E097823.D 5 01/28/19 AB n/a n/a VE2067
FA60923-2 E097813.D 1 01/28/19 AB n/a n/a VE2067
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1, FA61067-2
FA60923-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 0.50 U 50 53.8 108 50 51.9 104 4 70-130/20
108-86-1 Bromobenzene 0.50 U 50 53.5 107 50 49.2 98 8 70-130/20
74-97-5 Bromochloromethane 0.50 U 50 48.6 97 50 46.8 94 4 70-130/20
75-27-4 Bromodichloromethane 0.50 U 50 45.5 91 50 44.0 88 3 70-130/20
75-25-2 Bromoform 0.50 U 50 27.5 55*50 25.9 52*6 70-130/20
104-51-8 n-Butylbenzene 0.50 U 50 58.1 116 50 55.3 111 5 70-130/20
135-98-8 sec-Butylbenzene 0.50 U 50 59.2 118 50 55.8 112 6 70-130/20
98-06-6 tert-Butylbenzene 0.50 U 50 57.3 115 50 53.3 107 7 70-130/20
56-23-5 Carbon Tetrachloride 0.50 U 50 52.5 105 50 51.7 103 2 70-130/20
108-90-7 Chlorobenzene 0.50 U 50 52.6 105 50 50.0 100 5 70-130/20
75-00-3 Chloroethane 0.50 U 50 44.3 89 50 54.1 108 20 60-140/20
67-66-3 Chloroform 0.50 U 50 51.5 103 50 50.4 101 2 70-130/20
95-49-8 o-Chlorotoluene 0.50 U 50 56.3 113 50 52.9 106 6 70-130/20
106-43-4 p-Chlorotoluene 0.50 U 50 56.2 112 50 52.1 104 8 70-130/20
124-48-1 Dibromochloromethane 0.50 U 50 36.8 74 50 34.8 70 6 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane 0.50 U 50 52.2 104 50 48.7 97 7 70-130/20
106-93-4 1,2-Dibromoethane 0.50 U 50 51.2 102 50 47.9 96 7 70-130/20
75-71-8 Dichlorodifluoromethane 0.50 U 50 57.1 114 50 68.3 137 18 60-140/20
95-50-1 1,2-Dichlorobenzene 0.50 U 50 52.6 105 50 49.4 99 6 70-130/20
541-73-1 1,3-Dichlorobenzene 0.50 U 50 54.5 109 50 51.3 103 6 70-130/20
106-46-7 1,4-Dichlorobenzene 0.50 U 50 52.5 105 50 49.6 99 6 70-130/20
75-34-3 1,1-Dichloroethane 0.50 U 50 55.4 111 50 54.1 108 2 70-130/20
107-06-2 1,2-Dichloroethane 0.50 U 50 51.4 103 50 50.0 100 3 70-130/20
75-35-4 1,1-Dichloroethylene 0.50 U 50 57.6 115 50 56.5 113 2 70-130/20
156-59-2 cis-1,2-Dichloroethylene 0.50 U 50 52.0 104 50 50.4 101 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene 0.50 U 50 53.8 108 50 52.9 106 2 70-130/20
78-87-5 1,2-Dichloropropane 0.50 U 50 54.3 109 50 52.7 105 3 70-130/20
142-28-9 1,3-Dichloropropane 0.50 U 50 51.1 102 50 47.6 95 7 70-130/20
594-20-7 2,2-Dichloropropane 0.50 U 50 56.5 113 50 55.0 110 3 70-130/20
563-58-6 1,1-Dichloropropene 0.50 U 50 56.5 113 50 55.0 110 3 70-130/20
10061-01-5 cis-1,3-Dichloropropene 0.50 U 50 45.8 92 50 43.6 87 5 70-130/20
10061-02-6 trans-1,3-Dichloropropene 0.50 U 50 49.8 100 50 45.9 92 8 70-130/20
108-20-3 Di-Isopropyl Ether 0.50 U 50 53.4 107 50 52.1 104 2 70-130/20
100-41-4 Ethylbenzene 0.50 U 50 55.0 110 50 52.8 106 4 70-130/20
87-68-3 Hexachlorobutadiene 0.50 U 50 51.4 103 50 49.2 98 4 70-130/20
98-82-8 Isopropylbenzene 0.50 U 50 57.0 114 50 54.9 110 4 70-130/20
* = Outside of Control Limits.
20 of 22
FA6106755.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA60923-2MS E097822.D 5 01/28/19 AB n/a n/a VE2067
FA60923-2MSD E097823.D 5 01/28/19 AB n/a n/a VE2067
FA60923-2 E097813.D 1 01/28/19 AB n/a n/a VE2067
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1, FA61067-2
FA60923-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene 0.50 U 50 57.6 115 50 53.7 107 7 70-130/20
74-83-9 Methyl Bromide 0.50 U 50 41.3 83 50 50.0 100 19 60-140/20
74-87-3 Methyl Chloride 0.50 U 50 57.9 116 50 66.3 133 14 60-140/20
74-95-3 Methylene Bromide 0.50 U 50 50.0 100 50 48.1 96 4 70-130/20
75-09-2 Methylene Chloride 2.0 U 50 60.2 120 50 58.8 118 2 70-130/20
1634-04-4 Methyl Tert Butyl Ether 0.50 U 50 52.0 104 50 48.9 98 6 70-130/20
91-20-3 Naphthalene 0.50 U 50 50.8 102 50 48.9 98 4 70-130/20
103-65-1 n-Propylbenzene 0.50 U 50 57.9 116 50 54.4 109 6 70-130/20
100-42-5 Styrene 0.50 U 50 50.0 100 50 48.4 97 3 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane 0.50 U 50 49.8 100 50 48.2 96 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane 0.50 U 50 54.1 108 50 49.8 100 8 70-130/20
127-18-4 Tetrachloroethylene 0.50 U 50 53.5 107 50 51.1 102 5 70-130/20
108-88-3 Toluene 0.50 U 50 54.1 108 50 51.7 103 5 70-130/20
87-61-6 1,2,3-Trichlorobenzene 0.50 U 50 49.9 100 50 48.9 98 2 70-130/20
120-82-1 1,2,4-Trichlorobenzene 0.50 U 50 51.2 102 50 49.2 98 4 70-130/20
71-55-6 1,1,1-Trichloroethane 0.50 U 50 52.4 105 50 51.1 102 3 70-130/20
79-00-5 1,1,2-Trichloroethane 0.50 U 50 51.8 104 50 49.3 99 5 70-130/20
79-01-6 Trichloroethylene 0.50 U 50 52.9 106 50 51.7 103 2 70-130/20
75-69-4 Trichlorofluoromethane 0.50 U 50 44.7 89 50 53.7 107 18 60-140/20
96-18-4 1,2,3-Trichloropropane 0.50 U 50 51.4 103 50 46.9 94 9 70-130/20
95-63-6 1,2,4-Trimethylbenzene 0.50 U 50 53.4 107 50 50.2 100 6 70-130/20
108-67-8 1,3,5-Trimethylbenzene 0.50 U 50 56.4 113 50 52.9 106 6 70-130/20
75-01-4 Vinyl Chloride 0.50 U 50 48.1 96 50 57.2 114 17 60-140/20
m,p-Xylene 1.0 U 100 108 108 100 105 105 3 70-130/20
95-47-6 o-Xylene 0.50 U 50 52.7 105 50 50.8 102 4 70-130/20
1330-20-7 Xylene (total)1.5 U 150 161 107 150 155 103 4 70-130/20
CAS No.Surrogate Recoveries MS MSD FA60923-2 Limits
1868-53-7 Dibromofluoromethane 98%99%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%104%97%70-130%
2037-26-5 Toluene-D8 102%102%100%70-130%
460-00-4 4-Bromofluorobenzene 105%102%102%70-130%
* = Outside of Control Limits.
21 of 22
FA6106755.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA61067
Account:GRINCC GRI (Geological Resources Inc.)
Project:Tripp's Service Station; 6682 NC Hwy 258, Farmville, Greene Co, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA61046-4MS E097850.D 5 01/29/19 AB n/a n/a VE2068
FA61046-4MSD E097851.D 5 01/29/19 AB n/a n/a VE2068
FA61046-4 E097840.D 1 01/29/19 AB n/a n/a VE2068
The QC reported here applies to the following samples:Method: SM 6200B
FA61067-1
FA61046-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
1634-04-4 Methyl Tert Butyl Ether 3.8 50 53.9 100 50 56.1 105 4 70-130/20
CAS No.Surrogate Recoveries MS MSD FA61046-4 Limits
1868-53-7 Dibromofluoromethane 102%102%101%70-130%
17060-07-0 1,2-Dichloroethane-D4 109%108%106%70-130%
2037-26-5 Toluene-D8 104%103%99%70-130%
460-00-4 4-Bromofluorobenzene 103%105%108%70-130%
* = Outside of Control Limits.
22 of 22
FA6106755.3.2