RA-28382_47635_CA_LSA_20210409

MINERAL SPRINGS ENVIRONMENTAL, P.C.
4600 MINERAL SPRINGS LANE
RALEIGH, NORTH CAROLINA, 27616
919.261.8186
PHASE I LIMITED SITE
ASSESSMENT
REPORT

70 WEST BP SITE
6200 GLENWOOD AVENUE
RALEIGH, WAKE COUNTY,
NORTH CAROLINA
APRIL 9, 2021
MSE JOB NO. 1126

Prepared For:
CHARLES BRIGHT
800 SALEM DRIVE, SUITE 104
RALEIGH, NORTH CAROLINA, 27615

TABLE OF CONTENTS
1 INTRODUCTION 2
2 SITE CHECK ACTIVITIES 2
3 RECEPTOR SURVEY 3
4 SITE GEOLOGY 4
5 GROUNDWATER INVESTIGATION 4
6 SUMMARY 5

DRAWINGS

Drawing 1 Topographic Site Map
Drawing 2 Site Map
Drawing 3 Adjoining Properties Location Map

TABLES

Table 1 Adjacent Property Owners
Table 2 Soil Laboratory Analytical Data

APPENDICES

Appendix A Risk Classification and Land Use Form and
Receptor Survey Notification Letter
Appendix B Well Construction Record
Appendix C Laboratory Analytical Reports and Chain-of-Custody Records

PHASE I LIMITED SITE ASSESSMENT
70 WEST BP SITE
6200 Glenwood Avenue
Raleigh, Wake County, North Carolina
April 9, 2021

1.0 INTRODUCTION

The site is the 70 West BP located at 6200 Glenwood Avenue near Raleigh, Wake County, North
Carolina (Drawing 1). Five tanks were used at the site to store petroleum product (Drawing 2).
Two tanks were 10,000 capacity tanks (T-1 and T-4) and were used to store gasoline and diesel
product. The tanks measured 32 feet long and eight feet in diameter. Two tanks were 8,000
capacity tanks (T-2 and T-3) and were used to store gasoline product. The tanks measured 25
feet long and eight feet in diameter. Tank 5 was a 4,000 capacity tank and was 24 feet long
and five feet in diameter and previously used to store diesel. The tanks were fiberglass and in
good condition and were removed on February 23 and 24, 2021.

It is our understanding soil impact was identified in at the site as a result of an environmental
investigation in 1993. The release was assigned UST Incident 10421. A no further action letter
was issued in 2006 for the incident.

2.0 UST CLOSURE AND INTIAL ABATEMENT ACTIVITIES

Prior to tank removal, a permit to remove the five tanks was obtained from the City of Raleigh.
In addition, an UST 3 Notice of Intent form was sent to the NC UST Section in January 2021
(see Appendix A). On March 18, 2021, an UST 2 form was sent to the NC UST Section’s
Permitting Branch via email.

The bulk of the petroleum product was removed by others prior to between February 8 and 11,
2021. Between February 15, 2021 and February 17, 2021 steps were taken to remove the
dispensers and lines associated with the tanks. After the petroleum product had been removed
from the tanks by others, steps were taken to pressure wash the interior of the tanks and
simultaneously inert the tanks on February 23, 2021. Subsequent to approval from the City of
Raleigh Fire Marshall, the tank removal activities commenced on February 24, 2021. Oakes then
began the removal of the 4,000 gallon kerosene and 10,000 gallon diesel USTs. The remaining
USTs were then removed accordingly. Soils above and around the sides of the tanks were
removed using a track-hoe. Limited petroleum odors were noted during the removal process.
The excavation for the tanks measured approximately 60 feet long by 38 feet wide and 11 feet
deep.

Once the tanks, product lines and dispensers were removed, soil samples were collected from
beneath the tank locations (Drawings 3). The samples for the USTs are as follows: S1-1, S1-2,
S1-3, S1-4, S2-1, S2-2, S2-3, S3-1, S3-2, S3-3, S4-1, S4-2, S4-3, S4-4, S5-1, S5-2 and S5-3.
The samples for the product lines are as follows: LS-1 thru LS-17. The samples for the
dispensers are as follows: DS-1, DS-2, DS-3, DS-4, DS-5, DS-6 and DS-7. Soil samples were
submitted to Cohesion for the analysis of TPH as diesel (DRO) and TPH GRO according to EPA
Method 3550 and 5035 using the state approved Ultraviolet Fluorescent analytical technology.

MINERAL SPRINGS ENVIRONMENTAL, P.C.
Phase I Limited Site Assessment April 9, 2021
70 West BP Site Page 2

Regarding the 41 closure samples collected for the USTs, product lines and dispensers, TPH
concentrations were detected in six soil samples (DS-7, LS-2, S1-3, S5-1, S5-2 and S5-3) above
the North Carolina UST Sections cleanup value of 50 milligrams per kilogram (mg/kg) for gas
and/or 100 mg/kg for diesel.

TPH as gas was identified at concentrations of 50.8 mg/kg (LS-2), 99.5 mg/kg (S1-3), 270
mg/kg (S5-1) and 193 mg/kg (S5-2). In addition, TPH as diesel was identified at concentrations
of 114 mg/kg (DS-7), 307 mg/kg (S1-3), 2,314 mg/kg (S5-1), 471 mg/kg (S5-2) and 284 mg/kg
(S5-3).

Based on the presence of TPH as GRO and/or DRO in the above mentioned soil samples the
submitted samples were analyzed according to approved analytical methods to determine
concentrations of compounds which comprise gasoline and or diesel. In addition the samples
were analyzed for the presence of volatile petroleum hydrocarbons (VPH) and/or extractable
petroleum hydrocarbons (EPH).

Soil sample LS-2 was analyzed for volatile organic compounds (VOCs) according to SW-846
Methods 8260 and VPH. Soil samples S1-3, S5-1 and S5-2 were analyzed for VOCs, semi VOCs
(SVOCs) according to SW 846 Method 8270 and VPH/EPH. The remaining soil samples DS-7 and
S5-3 were analyzed for SVOCs and EPH. Based on the analytical results no VOCs, SVOCs and/or
VPH/EPH were detected at a concentration in excess of the Soil-to-Groundwater Maximum Soil
Contaminant Concentration (MSCC), except the following. EPH compounds were detected above
the soil-to-groundwater MSCCs in soil samples DS-7, S5-1 and S5-3, but were below the
residential MSCCs.

Based on the soil confirmation analytical results, Phase I Limited Site Assessment (LSA)
activities have been performed at the site. The results of the Phase I LSA are presented below.

3 RECEPTOR SURVEY

The following details the results of the receptor survey conducted in March and April 2021. A
completed Risk Classification and Land Use Form is attached in Appendix A.

3.1 Water Supply Wells

MSE personnel visited the site on March 31, 2021 to determine the location of water-supply wells
within a 1,500-foot radius of the site. A visual survey was conducted by Mr. Evan Pollard to locate
well houses and water meters. Letters were mailed to property owners within a 500-foot radius of
the site and adjoining property owners (Appendix A).

Based on the limited survey responses and site visit, MSE confirmed that no water-supply wells are
located within 1,000 feet of the source area.

3.2 Public Water Supply

City water supply is available to all residents and businesses in the area.

MINERAL SPRINGS ENVIRONMENTAL, P.C.
Phase I Limited Site Assessment April 9, 2021
70 West BP Site Page 3
3.3 Surface Water

According to the USGS topographic map of the site (Drawing 1), an unnamed creek is located
northeast of the site and a large creek is located to the north and east. The closest surface water
feature is located approximately 900 to 1,000 feet northeast of the site.

3.4 Wellhead Protection Areas

According to the North Carolina Division of Public Health, Public Water Supply Section (Public
Water Supply) website, there is one wellhead protection plans currently approved for Wake
County in Rolesville, North Carolina and is not within 1,500 feet of the site.

3.5 Coastal Plain Physiographic Province

According to the Geologic Map of North Carolina (1986), published by the North Carolina
Department of Environment and Natural Resources, the site is not in the Coastal Plain
Physiographic Province.

3.6 Subsurface Structures

Underground utilities, including water, electrical, and product lines are present on the site.

3.7 Surrounding Land Use

Nearby properties are used for commercial and residential purposes. MSE has prepared a map
showing the adjacent parcels and their associated parcel numbers (Drawing 3). Table 1
summarizes the contact information for the owners of these adjacent parcels.

4 SITE GEOLOGY AND HYDROGEOLOGY

Shallow soils consist of tan sandy silt to 30 feet below land surface (BLS). Hard rock was
encountered from 30 feet BLS to 80 feet BLS during well installation activities. No water was
present in the temporary monitoring well after an extended period of time.

5 SOIL AND GROUNDWATER INVESTIGATION

5.1 Soil Sampling Activities

On March 25, 2021, an attempt to install a temporary well at the site was conducted. The
boring was advanced to 30 feet using direct-push technology. At 30 feet rock was encountered
and the boring could not be advanced further and water was not present after a period of time.
To determine the concentrations of chemical specific compounds at monitoring well TW-1, two
soil samples (TW-20 and TW-30) were collected from the boring at a depth of 20 and 30 feet
BLS. The 10 foot depth samples were collected and analyzed at the time of the UST removal
activities. The soil samples were placed in pre-labeled laboratory provided glassware, packed on
ice, and transported under chain-of-custody protocol to Environmental Conservation
Laboratories (ENCO), of Cary, North Carolina. Soil sample TW-20 collected from the TW-1
boring was analyzed for the presence of volatile petroleum hydrocarbons (VPH) and extractable
petroleum hydrocarbons (EPH) according to MADEP method. While soil sample TW-30 collected
DRAWINGSDRAWINGSDRAWINGSDRAWINGS
DRAWING NO. 1

TOPOGRAPHIC SITE MAP
70 WEST BP SITE
6200 GLENWOOD AVENUE
RALEIGH, NORTH CAROLINA
Date: March 2021
Job No.: MSE 1126
File: 1126/Drawing 1
By: KP
SITE
123SITE11DisclaimeriMaps makes every effort to produce and publish the most current and accurate information possible.However, the maps are produced for information purposes,and are NOT surveys. No warranties, expressed or implied,are provided for the data therein, its use,or its interpretation.DRAWING 3-ADJOINING PROPERTIES0 210 420105 ft1 inch = 200 feet±
TABLESTABLESTABLESTABLES
Map ID NumberProperty Identification NumberOwners Name Owners Mailing Address Property Address1 0786874371 KIMCO Raleigh LP 3333 New Hyde Park, New Hyde Park, New York 11042-1204 6204 Glenwood Avenue, Raleigh, NC2 0786769542 TRP Golden Corral LLC 11100 W. Broad Street, Glen Allen, VA. 23060-5813 6129 Glenwood Avenue, Raleigh, NC3 0786878298 Carlton Investment Group 6124 Saint Giles St., Raleigh, NC 27612-7042 6109 Glenwood Avenue, Raleigh, NCNotes:MSE Job 1126TABLE 1ADJACENT PROPERTY OWNERS LOCATIONS70 WEST BPRALEIGH, NORTH CAROLINA
TW-20 TW-30Acetone NA 0.03 24 14,000Methyl tert butyl ether NA 0.017 0.091 350C9-C10 Aromatics BQL BQL 31 469C11-C22 Aromatics BQL BQL 31 469C5-C8 Aliphatics BQL BQL 68 939C9-C18 Aliphatics BQL BQL 540 1,500C19-C36 Aliphatics BQL BQL immobile 31,000C9-C12 Aliphatics BQL BQL 540 1,500Notes: mg/Kg - Milligrams per kilogramMSCC - Maximum Soil Contaminant ConcentrationValues shown in bold type exceed their respective soil-to-groundwater MSCCBQL - Below Quantitation LimitNA - Not AnalyzedNE - None establishedVolatile and Extractable Petroleum HydrocarbonsResidential MSCC (mg/Kg)Constituent (mg/Kg)MSE JOB 1126 Sample NumberSoil to Groundwater MSCC (mg/Kg)Volatile Organic CompoundsTABLE 2PHASE I LSA SOIL SAMPLE LABORATORY ANALYTICAL RESULTS70 WEST BPRALEIGH, NORTH CAROLINA
APPENDICESAPPENDICESAPPENDICESAPPENDICES

APPENDIX A

RISK CLASSIFICATION AND LAND USE AND
RECEPTOR SURVEY NOTIFICATION LETTER

APPENDIX B

WELL CONSTRUCTION
RECORD

APPENDIX C

LABORATORY ANALYTICAL RESULTS

102-A Woodwinds Industrial Court
Cary NC, 27511
919.467.3090 919.467.3515Phone:FAX:[TOC_1]ENCO Laboratories, Inc.[TOC]
ENCO Workorder(s): CE04642
Raleigh, NC 27616
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative if applicable. This report shall not be reproduced except in
full, without the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Enclosure(s)
Project Number: [none], Project Name/Desc: 70 West BP
Attn: Kirk Pollard
Mineral Springs Environmental (MI017)
4600 Mineral Springs Lane
Bill Scott
Project Manager
Wednesday, April 7, 2021
RE: Laboratory Results for
Dear Kirk Pollard,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Thursday, March 25, 2021.
Enclosure(s)
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 1 of 16Page 1 of 16
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PROJECT NARRATIVE [TOC_1]Project Narrative[TOC]
Client:Mineral Springs Environmental (MI017)
Project:70 West BP
Lab ID:CE04642
Overview
Environmental Conservation Laboratories, Inc. (ENCO) analyzed all submitted samples in accordance with the methods
referenced in the laboratory report. Any particular difficulties encountered during sample handling by ENCO are discussed in
the QC Remarks section below.
Quality Control Samples
No Comments
Quality Control Remarks
No Comments
Other Comments
Report generated without J values reported.
The analytical data presented in this report are consistent with the methods as referenced in the analytical report. Any
exceptions or deviations are noted in the QC remarks section of this narrative or in the Flags/Notes and Definitions section of
the report.
Released By:
Environmental Conservation Laboratories, Inc.
Bill Scott
Project Manager
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 2 of 16Page 2 of 16
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SAMPLE SUMMARY/LABORATORY CHRONICLE [TOC_1]Sample Chronical[TOC]
TW-20 CE04642-01 Sampled:03/24/21 13:30 Received:03/25/21 13:26Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)Preparation
MAEPH 04/07/21 03/27/21 01:23 03/27/21 12:2305/06/21EPA 3550C
MAVPH 04/21/21 03/30/21 13:01 03/31/21 09:51EPA 5035
TW-30 CE04642-02 Sampled:03/24/21 13:30 Received:03/25/21 13:26Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)Preparation
EPA 8260D 04/07/21 04/02/21 12:39 04/03/21 00:51EPA 5035_MS
EPA 8270E 04/07/21 03/29/21 22:10 03/30/21 19:0705/08/21EPA 3550C_MS
MAEPH 04/07/21 03/27/21 01:23 03/27/21 12:5705/06/21EPA 3550C
MAVPH 04/21/21 03/30/21 13:01 03/31/21 10:43EPA 5035
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SAMPLE DETECTION SUMMARY [TOC_1]Detection Summary[TOC]
Lab ID:Client ID:TW-30 CE04642-02
Analyte MethodUnitsPQLResultsFlag NotesMDL
30 20 ug/kg dry EPA 8260D Acetone 14
17 1.0 ug/kg dry EPA 8260D Methyl-tert-Butyl Ether 0.31
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ANALYTICAL RESULTS
[TOC_1]Analytical Results[TOC]
TW-20Description:Lab Sample ID:CE04642-01 03/25/21 13:26Received:
CE04642Work Order:03/24/21 13:30Sampled:SoilMatrix:
87.14% Solids:Evan L PollardSampled By:Project:70 West BP
[TOC_2]TW-20[TOC]
Volatile Petroleum Hydrocarbons by GC
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
mg/kg dry MAVPH 03/31/21 09:51C5-C8 Aliphatics^OWS1C300263.44ND 1
mg/kg dry MAVPH 03/31/21 09:51C9-C10 Aromatics^OWS1C300261.15ND 1
mg/kg dry MAVPH 03/31/21 09:51C9-C12 Aliphatics^OWS1C300263.44ND 1
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene (FID)70-13078 %OWSMAVPH03/31/21 09:511C300269.78 12.5 1
2,5-Dibromotoluene (PID)70-13086 %OWSMAVPH03/31/21 09:511C3002610.8 12.5 1
Extractable Petroleum Hydrocarbons by GC
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
mg/kg dry MAEPH 03/27/21 12:23C11-C22 Aromatics^LSK1C2700119ND 1
mg/kg dry MAEPH 03/27/21 12:23C19-C36 Aliphatics^LSK1C2700119ND 1
mg/kg dry MAEPH 03/27/21 12:23C9-C18 Aliphatics^LSK1C2700119ND 1
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
Chloro-octadecane 40-140119 %LSKMAEPH03/27/21 12:231C270011.8 1.53 1
o-Terphenyl 40-140110 %LSKMAEPH03/27/21 12:231C270011.7 1.53 1
TW-30Description:Lab Sample ID:CE04642-02 03/25/21 13:26Received:
CE04642Work Order:03/24/21 13:30Sampled:SoilMatrix:
84.29% Solids:Evan L PollardSampled By:Project:70 West BP
[TOC_2]TW-30[TOC]
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
ug/kg dry EPA 8260D 04/03/21 00:511,1,1,2-Tetrachloroethane [630-20-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,1,1-Trichloroethane [71-55-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,1,2,2-Tetrachloroethane [79-34-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,1,2-Trichloroethane [79-00-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,1-Dichloroethane [75-34-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,1-Dichloroethene [75-35-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,1-Dichloropropene [563-58-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2,3-Trichlorobenzene [87-61-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2,3-Trichloropropane [96-18-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2,4-Trichlorobenzene [120-82-1]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2,4-Trimethylbenzene [95-63-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2-Dibromo-3-chloropropane [96-12-8]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2-Dibromoethane [106-93-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2-Dichlorobenzene [95-50-1]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,2-Dichloroethane [107-06-2]^RKY1D020201.0ND QV-010.859
ug/kg dry EPA 8260D 04/03/21 00:511,2-Dichloropropane [78-87-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,3,5-Trimethylbenzene [108-67-8]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,3-Dichlorobenzene [541-73-1]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,3-Dichloropropane [142-28-9]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:511,4-Dichlorobenzene [106-46-7]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:512,2-Dichloropropane [594-20-7]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:512-Butanone [78-93-3]^RKY1D020205.1ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:512-Chloroethyl Vinyl Ether [110-75-8]^RKY1D020205.1ND QV-010.859
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ANALYTICAL RESULTS
TW-30Description:Lab Sample ID:CE04642-02 03/25/21 13:26Received:
CE04642Work Order:03/24/21 13:30Sampled:SoilMatrix:
84.29% Solids:Evan L PollardSampled By:Project:70 West BP
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
ug/kg dry EPA 8260D 04/03/21 00:512-Chlorotoluene [95-49-8]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:512-Hexanone [591-78-6]^RKY1D020205.1ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:514-Chlorotoluene [106-43-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:514-Isopropyltoluene [99-87-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:514-Methyl-2-pentanone [108-10-1]^RKY1D020205.1ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Acetone [67-64-1]^RKY1D020202030 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Benzene [71-43-2]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Bromobenzene [108-86-1]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Bromochloromethane [74-97-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Bromodichloromethane [75-27-4]^RKY1D020201.0ND QV-010.859
ug/kg dry EPA 8260D 04/03/21 00:51Bromoform [75-25-2]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Bromomethane [74-83-9]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Carbon disulfide [75-15-0]^RKY1D020205.1ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Carbon Tetrachloride [56-23-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Chlorobenzene [108-90-7]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Chloroethane [75-00-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Chloroform [67-66-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Chloromethane [74-87-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51cis-1,2-Dichloroethene [156-59-2]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51cis-1,3-Dichloropropene [10061-01-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Dibromochloromethane [124-48-1]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Dibromomethane [74-95-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Dichlorodifluoromethane [75-71-8]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Ethylbenzene [100-41-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Hexachlorobutadiene [87-68-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Isopropyl Ether [108-20-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Isopropylbenzene [98-82-8]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51m,p-Xylenes [108-38-3/106-42-3]^RKY1D020202.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Methylene Chloride [75-09-2]^RKY1D020202.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Methyl-tert-Butyl Ether [1634-04-4]^RKY1D020201.017 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Naphthalene [91-20-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51n-Butyl Benzene [104-51-8]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51n-Propyl Benzene [103-65-1]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51o-Xylene [95-47-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51sec-Butylbenzene [135-98-8]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Styrene [100-42-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51tert-Butylbenzene [98-06-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Tetrachloroethene [127-18-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Toluene [108-88-3]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51trans-1,2-Dichloroethene [156-60-5]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51trans-1,3-Dichloropropene [10061-02-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Trichloroethene [79-01-6]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Trichlorofluoromethane [75-69-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Vinyl chloride [75-01-4]^RKY1D020201.0ND 0.859
ug/kg dry EPA 8260D 04/03/21 00:51Xylenes (Total) [1330-20-7]^RKY1D020203.1ND 0.859
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
4-Bromofluorobenzene 50-12771 %RKYEPA 8260D 04/03/21 00:511D020203650.0 0.859
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 6 of 16Page 6 of 16
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ANALYTICAL RESULTS
TW-30Description:Lab Sample ID:CE04642-02 03/25/21 13:26Received:
CE04642Work Order:03/24/21 13:30Sampled:SoilMatrix:
84.29% Solids:Evan L PollardSampled By:Project:70 West BP
Volatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
Dibromofluoromethane 52-12877 %RKYEPA 8260D 04/03/21 00:511D020203950.0 0.859
Toluene-d8 57-12473 %RKYEPA 8260D 04/03/21 00:511D020203750.0 0.859
Semivolatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
ug/kg dry EPA 8270E 03/30/21 19:071,2,4-Trichlorobenzene [120-82-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:071,2-Dichlorobenzene [95-50-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:071,3-Dichlorobenzene [541-73-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:071,4-Dichlorobenzene [106-46-7]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:071-Methylnaphthalene [90-12-0]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:072,4-Dinitrotoluene [121-14-2]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:072,6-Dinitrotoluene [606-20-2]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:072-Chloronaphthalene [91-58-7]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:072-Methylnaphthalene [91-57-6]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:072-Nitroaniline [88-74-4]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:073,3’-Dichlorobenzidine [91-94-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:073-Nitroaniline [99-09-2]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:074-Bromophenyl-phenylether [101-55-3]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:074-Chloroaniline [106-47-8]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:074-Chlorophenyl-phenylether [7005-72-3]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:074-Nitroaniline [100-01-6]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Acenaphthene [83-32-9]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Acenaphthylene [208-96-8]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Anthracene [120-12-7]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Benzidine [92-87-5]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Benzo(a)anthracene [56-55-3]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Benzo(a)pyrene [50-32-8]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Benzo(b)fluoranthene [205-99-2]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Benzo(g,h,i)perylene [191-24-2]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Benzo(k)fluoranthene [207-08-9]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Benzyl alcohol [100-51-6]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07bis(2-Chloroethoxy)methane [111-91-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Bis(2-Chloroethyl)ether [111-44-4]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Bis(2-chloroisopropyl)ether [108-60-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Bis(2-Ethylhexyl)phthalate [117-81-7]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Butylbenzylphthalate [85-68-7]^DFM1C29036390ND QV-011
ug/kg dry EPA 8270E 03/30/21 19:07Carbazole [86-74-8]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Chrysene [218-01-9]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Dibenzo(a,h)anthracene [53-70-3]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Dibenzofuran [132-64-9]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Diethylphthalate [84-66-2]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Dimethylphthalate [131-11-3]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Di-n-butylphthalate [84-74-2]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Di-n-octylphthalate [117-84-0]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Fluoranthene [206-44-0]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Fluorene [86-73-7]^DFM1C29036390ND 1
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 7 of 16Page 7 of 16
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ANALYTICAL RESULTS
TW-30Description:Lab Sample ID:CE04642-02 03/25/21 13:26Received:
CE04642Work Order:03/24/21 13:30Sampled:SoilMatrix:
84.29% Solids:Evan L PollardSampled By:Project:70 West BP
Semivolatile Organic Compounds by GCMS
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
ug/kg dry EPA 8270E 03/30/21 19:07Hexachlorobenzene [118-74-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Hexachlorobutadiene [87-68-3]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Hexachlorocyclopentadiene [77-47-4]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Hexachloroethane [67-72-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Indeno(1,2,3-cd)pyrene [193-39-5]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Isophorone [78-59-1]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Nitrobenzene [98-95-3]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07N-Nitrosodimethylamine [62-75-9]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07N-Nitroso-di-n-propylamine [621-64-7]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07N-nitrosodiphenylamine/Diphenylamine
[86-30-6/122-39-4]^
DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Phenanthrene [85-01-8]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Pyrene [129-00-0]^DFM1C29036390ND 1
ug/kg dry EPA 8270E 03/30/21 19:07Pyridine [110-86-1]^DFM1C29036390ND 1
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2-Fluorobiphenyl 56-12096 %DFMEPA 8270E 03/30/21 19:071C290361900 1980 1
Nitrobenzene-d5 50-11781 %DFMEPA 8270E 03/30/21 19:071C290361600 1980 1
Terphenyl-d14 36-15180 %DFMEPA 8270E 03/30/21 19:071C290361600 1980 1
Volatile Petroleum Hydrocarbons by GC
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
mg/kg dry MAVPH 03/31/21 10:43C5-C8 Aliphatics^OWS1C300263.56ND 1.1
mg/kg dry MAVPH 03/31/21 10:43C9-C10 Aromatics^OWS1C300261.19ND 1.1
mg/kg dry MAVPH 03/31/21 10:43C9-C12 Aliphatics^OWS1C300263.56ND 1.1
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene (FID)70-13088 %OWSMAVPH03/31/21 10:431C3002611.5 13.1 1.1
2,5-Dibromotoluene (PID)70-13095 %OWSMAVPH03/31/21 10:431C3002612.5 13.1 1.1
Extractable Petroleum Hydrocarbons by GC
^ - ENCO Cary certified analyte [NC 591]
NotesFlagPQLBatchByAnalyzedMethodResultsUnitsDFAnalyte [CAS Number]
mg/kg dry MAEPH 03/27/21 12:57C11-C22 Aromatics^LSK1C2700120ND 1
mg/kg dry MAEPH 03/27/21 12:57C19-C36 Aliphatics^LSK1C2700120ND 1
mg/kg dry MAEPH 03/27/21 12:57C9-C18 Aliphatics^LSK1C2700120ND 1
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
Chloro-octadecane 40-140102 %LSKMAEPH03/27/21 12:571C270011.6 1.58 1
o-Terphenyl 40-140104 %LSKMAEPH03/27/21 12:571C270011.6 1.58 1
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 8 of 16Page 8 of 16
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QUALITY CONTROL DATA [TOC_1]QC Data[TOC]
Volatile Organic Compounds by GCMS - Quality Control
Batch 1D02020 - EPA 5035_MS
Prepared: 04/02/2021 12:39 Analyzed: 04/02/2021 18:40Blank (1D02020-BLK1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet1.01.0 U 1,1,1,2-Tetrachloroethane
ug/kg wet1.01.0 U 1,1,1-Trichloroethane
ug/kg wet1.01.0 U 1,1,2,2-Tetrachloroethane
ug/kg wet1.01.0 U 1,1,2-Trichloroethane
ug/kg wet1.01.0 U 1,1-Dichloroethane
ug/kg wet1.01.0 U 1,1-Dichloroethene
ug/kg wet1.01.0 U 1,1-Dichloropropene
ug/kg wet1.01.0 U 1,2,3-Trichlorobenzene
ug/kg wet1.01.0 U 1,2,3-Trichloropropane
ug/kg wet1.01.0 U 1,2,4-Trichlorobenzene
ug/kg wet1.01.0 U 1,2,4-Trimethylbenzene
ug/kg wet1.01.0 U 1,2-Dibromo-3-chloropropane
ug/kg wet1.01.0 U 1,2-Dibromoethane
ug/kg wet1.01.0 U 1,2-Dichlorobenzene
ug/kg wet1.01.0 U 1,2-Dichloroethane
ug/kg wet1.01.0 U 1,2-Dichloropropane
ug/kg wet1.01.0 U 1,3,5-Trimethylbenzene
ug/kg wet1.01.0 U 1,3-Dichlorobenzene
ug/kg wet1.01.0 U 1,3-Dichloropropane
ug/kg wet1.01.0 U 1,4-Dichlorobenzene
ug/kg wet1.01.0 U 2,2-Dichloropropane
ug/kg wet5.05.0 U 2-Butanone
ug/kg wet5.05.0 U 2-Chloroethyl Vinyl Ether
ug/kg wet1.01.0 U 2-Chlorotoluene
ug/kg wet5.05.0 U 2-Hexanone
ug/kg wet1.01.0 U 4-Chlorotoluene
ug/kg wet1.01.0 U 4-Isopropyltoluene
ug/kg wet5.05.0 U 4-Methyl-2-pentanone
ug/kg wet2020U Acetone
ug/kg wet1.01.0 U Benzene
ug/kg wet1.01.0 U Bromobenzene
ug/kg wet1.01.0 U Bromochloromethane
ug/kg wet1.01.0 U Bromodichloromethane
ug/kg wet1.01.0 U Bromoform
ug/kg wet1.01.0 U Bromomethane
ug/kg wet5.05.0 U Carbon disulfide
ug/kg wet1.01.0 U Carbon Tetrachloride
ug/kg wet1.01.0 U Chlorobenzene
ug/kg wet1.01.0 U Chloroethane
ug/kg wet1.01.0 U Chloroform
ug/kg wet1.01.0 U Chloromethane
ug/kg wet1.01.0 U cis-1,2-Dichloroethene
ug/kg wet1.01.0 U cis-1,3-Dichloropropene
ug/kg wet1.01.0 U Dibromochloromethane
ug/kg wet1.01.0 U Dibromomethane
ug/kg wet1.01.0 U Dichlorodifluoromethane
ug/kg wet1.01.0 U Ethylbenzene
ug/kg wet1.01.0 U Hexachlorobutadiene
ug/kg wet1.01.0 U Isopropyl Ether
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 9 of 16Page 9 of 16
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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 1D02020 - EPA 5035_MS - Continued
Prepared: 04/02/2021 12:39 Analyzed: 04/02/2021 18:40Blank (1D02020-BLK1) Continued
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet1.01.0 U Isopropylbenzene
ug/kg wet2.02.0 U m,p-Xylenes
ug/kg wet2.02.0 U Methylene Chloride
ug/kg wet1.01.0 U Methyl-tert-Butyl Ether
ug/kg wet1.01.0 U Naphthalene
ug/kg wet1.01.0 U n-Butyl Benzene
ug/kg wet1.01.0 U n-Propyl Benzene
ug/kg wet1.01.0 U o-Xylene
ug/kg wet1.01.0 U sec-Butylbenzene
ug/kg wet1.01.0 U Styrene
ug/kg wet1.01.0 U tert-Butylbenzene
ug/kg wet1.01.0 U Tetrachloroethene
ug/kg wet1.01.0 U Toluene
ug/kg wet1.01.0 U trans-1,2-Dichloroethene
ug/kg wet1.01.0 U trans-1,3-Dichloropropene
ug/kg wet1.01.0 U Trichloroethene
ug/kg wet1.01.0 U Trichlorofluoromethane
ug/kg wet1.01.0 U Vinyl chloride
ug/kg wet3.03.0 U Xylenes (Total)
ug/L 50.0 50-1274-Bromofluorobenzene 7337
ug/L 50.0 52-128Dibromofluoromethane7437
ug/L 50.0 57-124Toluene-d8 7437
Prepared: 04/02/2021 12:39 Analyzed: 04/02/2021 16:34LCS (1D02020-BS1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet1.0 20.0 64-13313327 1,1-Dichloroethene
ug/kg wet1.0 20.0 79-12911723 Benzene
ug/kg wet1.0 20.0 79-12110421 Chlorobenzene
ug/kg wet1.0 20.0 77-1209920 Toluene
ug/kg wet1.0 20.0 78-12011723 Trichloroethene
ug/L 50.0 50-1274-Bromofluorobenzene 7638
ug/L 50.0 52-128Dibromofluoromethane7738
ug/L 50.0 57-124Toluene-d8 7538
Prepared: 04/02/2021 12:39 Analyzed: 04/02/2021 17:05Matrix Spike (1D02020-MS1)
Source: CE04877-08
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet1.0 20.0 64-1331251.0 U25 1,1-Dichloroethene
ug/kg wet1.0 20.0 79-1291111.0 U22 Benzene
ug/kg wet1.0 20.0 79-1211001.0 U20 Chlorobenzene
ug/kg wet1.0 20.0 77-120981.0 U20 Toluene
ug/kg wet1.0 20.0 78-1201141.0 U23 Trichloroethene
ug/L 50.0 50-1274-Bromofluorobenzene 7537
ug/L 50.0 52-128Dibromofluoromethane7738
ug/L 50.0 57-124Toluene-d8 7538
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 10 of 16Page 10 of 16
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QUALITY CONTROL DATA
Volatile Organic Compounds by GCMS - Quality Control
Batch 1D02020 - EPA 5035_MS - Continued
Prepared: 04/02/2021 12:39 Analyzed: 04/02/2021 17:37Matrix Spike Dup (1D02020-MSD1)
Source: CE04877-08
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet1.0 20.0 2364-133125 0.41.0 U25 1,1-Dichloroethene
ug/kg wet1.0 20.0 2379-129112 0.81.0 U22 Benzene
ug/kg wet1.0 20.0 2579-121102 31.0 U20 Chlorobenzene
ug/kg wet1.0 20.0 2377-12098 0.51.0 U20 Toluene
ug/kg wet1.0 20.0 2478-120114 0.61.0 U23 Trichloroethene
ug/L 50.0 50-1274-Bromofluorobenzene 7437
ug/L 50.0 52-128Dibromofluoromethane7940
ug/L 50.0 57-124Toluene-d8 7437
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 1C29036 - EPA 3550C_MS
Prepared: 03/29/2021 22:10 Analyzed: 03/30/2021 16:09Blank (1C29036-BLK1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet330330U 1,2,4-Trichlorobenzene
ug/kg wet330330U 1,2-Dichlorobenzene
ug/kg wet330330U 1,3-Dichlorobenzene
ug/kg wet330330U 1,4-Dichlorobenzene
ug/kg wet330330U 1-Methylnaphthalene
ug/kg wet330330U 2,4-Dinitrotoluene
ug/kg wet330330U 2,6-Dinitrotoluene
ug/kg wet330330U 2-Chloronaphthalene
ug/kg wet330330U 2-Methylnaphthalene
ug/kg wet330330U 2-Nitroaniline
ug/kg wet330330U 3,3’-Dichlorobenzidine
ug/kg wet330330U 3-Nitroaniline
ug/kg wet330330U 4-Bromophenyl-phenylether
ug/kg wet330330U 4-Chloroaniline
ug/kg wet330330U 4-Chlorophenyl-phenylether
ug/kg wet330330U 4-Nitroaniline
ug/kg wet330330U Acenaphthene
ug/kg wet330330U Acenaphthylene
ug/kg wet330330U Anthracene
ug/kg wet330330U Benzidine
ug/kg wet330330U Benzo(a)anthracene
ug/kg wet330330U Benzo(a)pyrene
ug/kg wet330330U Benzo(b)fluoranthene
ug/kg wet330330U Benzo(g,h,i)perylene
ug/kg wet330330U Benzo(k)fluoranthene
ug/kg wet330330U Benzyl alcohol
ug/kg wet330330U bis(2-Chloroethoxy)methane
ug/kg wet330330U Bis(2-Chloroethyl)ether
ug/kg wet330330U Bis(2-chloroisopropyl)ether
ug/kg wet330330U Bis(2-Ethylhexyl)phthalate
ug/kg wet330330U QV-01Butylbenzylphthalate
ug/kg wet330330U Carbazole
ug/kg wet330330U Chrysene
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 11 of 16Page 11 of 16
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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 1C29036 - EPA 3550C_MS - Continued
Prepared: 03/29/2021 22:10 Analyzed: 03/30/2021 16:09Blank (1C29036-BLK1) Continued
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet330330U Dibenzo(a,h)anthracene
ug/kg wet330330U Dibenzofuran
ug/kg wet330330U Diethylphthalate
ug/kg wet330330U Dimethylphthalate
ug/kg wet330330U Di-n-butylphthalate
ug/kg wet330330U Di-n-octylphthalate
ug/kg wet330330U Fluoranthene
ug/kg wet330330U Fluorene
ug/kg wet330330U Hexachlorobenzene
ug/kg wet330330U Hexachlorobutadiene
ug/kg wet330330U Hexachlorocyclopentadiene
ug/kg wet330330U Hexachloroethane
ug/kg wet330330U Indeno(1,2,3-cd)pyrene
ug/kg wet330330U Isophorone
ug/kg wet330330U Nitrobenzene
ug/kg wet330330U N-Nitrosodimethylamine
ug/kg wet330330U N-Nitroso-di-n-propylamine
ug/kg wet330330U N-nitrosodiphenylamine/Diphenylamine
ug/kg wet330330U Phenanthrene
ug/kg wet330330U Pyrene
ug/kg wet330330U Pyridine
ug/kg wet 1670 56-1202-Fluorobiphenyl 961600
ug/kg wet 1670 50-117Nitrobenzene-d5 851400
ug/kg wet 1670 36-151Terphenyl-d14 951600
Prepared: 03/29/2021 22:10 Analyzed: 03/30/2021 17:10LCS (1C29036-BS1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg wet330 1670 51-121921500 1,2,4-Trichlorobenzene
ug/kg wet330 1670 48-118901500 1,4-Dichlorobenzene
ug/kg wet330 1670 63-127951600 2,4-Dinitrotoluene
ug/kg wet330 1670 64-131951600 Acenaphthene
ug/kg wet330 1670 55-135951600 N-Nitroso-di-n-propylamine
ug/kg wet330 1670 65-146911500 Pyrene
ug/kg wet 1670 56-1202-Fluorobiphenyl 1011700
ug/kg wet 1670 50-117Nitrobenzene-d5 941600
ug/kg wet 1670 36-151Terphenyl-d14 971600
Prepared: 03/29/2021 22:10 Analyzed: 03/30/2021 19:36Matrix Spike (1C29036-MS1)
Source: CE04642-02
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg dry390 1980 51-12187390 U1700 1,2,4-Trichlorobenzene
ug/kg dry390 1980 48-11885390 U1700 1,4-Dichlorobenzene
ug/kg dry390 1980 63-12797390 U1900 2,4-Dinitrotoluene
ug/kg dry390 1980 64-13192390 U1800 Acenaphthene
ug/kg dry390 1980 55-13591390 U1800 N-Nitroso-di-n-propylamine
ug/kg dry390 1980 65-14686390 U1700 Pyrene
ug/kg dry 1980 56-1202-Fluorobiphenyl 951900
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 12 of 16Page 12 of 16
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QUALITY CONTROL DATA
Semivolatile Organic Compounds by GCMS - Quality Control
Batch 1C29036 - EPA 3550C_MS - Continued
Prepared: 03/29/2021 22:10 Analyzed: 03/30/2021 19:36Matrix Spike (1C29036-MS1) Continued
Source: CE04642-02
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg dry 1980 50-117Nitrobenzene-d5 891800
ug/kg dry 1980 36-151Terphenyl-d14 911800
Prepared: 03/29/2021 22:10 Analyzed: 03/30/2021 20:04Matrix Spike Dup (1C29036-MSD1)
Source: CE04642-02
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
ug/kg dry390 1980 1051-12189 2390 U1800 1,2,4-Trichlorobenzene
ug/kg dry390 1980 1348-11886 1390 U1700 1,4-Dichlorobenzene
ug/kg dry390 1980 1063-12794 3390 U1900 2,4-Dinitrotoluene
ug/kg dry390 1980 1964-13191 1390 U1800 Acenaphthene
ug/kg dry390 1980 1055-13592 1390 U1800 N-Nitroso-di-n-propylamine
ug/kg dry390 1980 5065-14686 0.1390 U1700 Pyrene
ug/kg dry 1980 56-1202-Fluorobiphenyl 951900
ug/kg dry 1980 50-117Nitrobenzene-d5 901800
ug/kg dry 1980 36-151Terphenyl-d14 881700
Volatile Petroleum Hydrocarbons by GC - Quality Control
Batch 1C30026 - EPA 5035
Prepared: 03/30/2021 13:01 Analyzed: 03/30/2021 16:20Blank (1C30026-BLK1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
mg/kg wet3.003.00 U C5-C8 Aliphatics
mg/kg wet1.001.00 U C9-C10 Aromatics
mg/kg wet3.003.00 U C9-C12 Aliphatics
mg/kg wet 9.60 70-1302,5-Dibromotoluene (FID)938.94
mg/kg wet 9.60 70-1302,5-Dibromotoluene (PID)989.37
Prepared: 03/30/2021 13:01 Analyzed: 03/30/2021 14:34LCS (1C30026-BS1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
mg/kg wet3.00 11.9 70-130789.26 C5-C8 Aliphatics
mg/kg wet1.00 3.97 70-1301154.54 C9-C10 Aromatics
mg/kg wet3.00 11.9 70-1308610.2 C9-C12 Aliphatics
mg/kg wet 9.92 70-1302,5-Dibromotoluene (FID)979.63
mg/kg wet 9.92 70-1302,5-Dibromotoluene (PID)11811.8
Prepared: 03/30/2021 13:01 Analyzed: 03/30/2021 15:17LCS Dup (1C30026-BSD1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
mg/kg wet3.00 11.8 2570-13080 29.45 C5-C8 Aliphatics
mg/kg wet1.00 3.92 2570-130107 84.20 C9-C10 Aromatics
mg/kg wet3.00 11.8 2570-13089 310.5 C9-C12 Aliphatics
mg/kg wet 9.80 70-1302,5-Dibromotoluene (FID)10910.6
mg/kg wet 9.80 70-1302,5-Dibromotoluene (PID)11411.2
Extractable Petroleum Hydrocarbons by GC - Quality Control
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 13 of 16Page 13 of 16
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QUALITY CONTROL DATA
Extractable Petroleum Hydrocarbons by GC - Quality Control
Batch 1C27001 - EPA 3550C
Prepared: 03/27/2021 01:23 Analyzed: 03/27/2021 10:39Blank (1C27001-BLK1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
mg/kg wet1717U C11-C22 Aromatics
mg/kg wet1717U C19-C36 Aliphatics
mg/kg wet1717U C9-C18 Aliphatics
mg/kg wet 1.33 40-140Chloro-octadecane 1081.4
mg/kg wet 1.33 40-140o-Terphenyl 1131.5
Prepared: 03/27/2021 01:23 Analyzed: 03/27/2021 11:14LCS (1C27001-BS1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
mg/kg wet17 22.7 40-14012228 C11-C22 Aromatics
mg/kg wet17 21.3 40-14014531 QL-02C19-C36 Aliphatics
mg/kg wet17 16.0 40-14011919 C9-C18 Aliphatics
mg/kg wet 1.33 40-140Chloro-octadecane 1131.5
mg/kg wet 1.33 40-140o-Terphenyl 1171.6
Prepared: 03/27/2021 01:23 Analyzed: 03/27/2021 11:48LCS Dup (1C27001-BSD1)
FlagResult Units Level Result %REC Limits RPD Limit Notes Analyte PQL
Spike Source %REC RPD
mg/kg wet17 22.7 2540-140127 429 C11-C22 Aromatics
mg/kg wet17 21.3 2540-140150 332 QL-02C19-C36 Aliphatics
mg/kg wet17 16.0 2540-140123 320 C9-C18 Aliphatics
mg/kg wet 1.33 40-140Chloro-octadecane 1111.5
mg/kg wet 1.33 40-140o-Terphenyl 1161.5
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.FINAL Page 14 of 16Page 14 of 16
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FLAGS/NOTES AND DEFINITIONS [TOC_1]Flags/Notes[TOC]
The sample was analyzed at dilution.
The analyte was detected in the associated method blank.
The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
MRL
E
U
J
D
B
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL.PQL
Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses.[CALC]
The associated laboratory control sample exhibited high bias; since the result is ND, there is no impact.QL-02
The associated continuing calibration verification standard exhibited high bias; since the result is ND, there
is no impact.
QV-01
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