RA-3620_3620_CA_MRP_20150612

GROUND WATER MONITORING REPORT
WILSON PETROLEUM BULK PLANT
420 SOUTH DOUGLAS STREET
WILSON, WILSON COUNTY
NORTH CAROLINA
INCIDENT NO. 3620
GRI PROJECT NO. 3249

Prepared for:

Mr. Michael Barnes
Wilson Petroleum Company, Inc.
314 Lafayette Drive, Suite 203
Wilson, North Carolina 27893

Prepared by:

Geological Resources, Inc.
3502 Hayes Road
Monroe, North Carolina 28110

June 12, 2015

Corey Buchanan

EXECUTIVE SUMMARY
The former Wilson Petroleum Bulk Plant was located at 420 South Douglas Street in Wilson, Wilson
County, North Carolina. The adjoining properties are commercial. In 1988, approximately 1,400 gallons
of petroleum was released to the ground surface from the AST system. In 1990, a ground water treatment
system was installed at the site and operated until 1995. Semi-annual and annual ground water sampling
has been conducted at the site since 1995. The site is located within the city limits of Wilson. No
structures remain on site and property ownership has transferred to the City of Wilson.

Ground water monitoring activities were conducted in May 2015. Monitoring wells MW-1, MW-4, MW-
10, and MW-11 were not located during sampling activities and are assumed to have been destroyed
during site renovations. Detectable concentrations of benzene and/or MTBE that exceeded the maximum
allowable concentrations (MACs) specified in T15A NCAC 2L.0202 were found in the samples collected
from MW-2 and MW-8; and, concentrations of lead in samples collected from MW-2, MW-5 through
MW-8, and MW-12 exceeded the MAC. No detectable concentrations exceeded the gross contaminant
levels.

Based on this information, ground water monitoring is required to continue until the ground water
contamination has attenuated below the MACs or until risked based rules are applied to this incident. The
next ground water monitoring event should occur in March 2016.

TABLE OF CONTENTS

1.0 SITE HISTORY AND CHARACTERIZATION .............................................................................. 1 
2.0 CURRENT SITE ASSESSMENT ....................................................................................................... 1 
3.0 GROUND WATER SAMPLING ACTIVITIES ............................................................................... 1 
4.0 GROUND WATER QUALITY ........................................................................................................... 2 
5.0 SUMMARY AND CONCLUSIONS ................................................................................................... 2 
6.0 LIMITATIONS .................................................................................................................................... 2 

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Water Table Surface Map
Figure 4: Ground Water Quality Map

TABLES

Table 1: Well Construction & Gauging Information
Table 2: Summary of Ground Water Sample Analytical Results
APPENDIX

Appendix A: Historical Gauging Data
Appendix B: Historical Ground Water Quality Data
Appendix C: Laboratory Report

1

1.0 SITE HISTORY AND CHARACTERIZATION
The former Wilson Petroleum Bulk Plant was located at 420 South Douglas Street in Wilson, Wilson
County, North Carolina (Figure 1). According to the “Annual Status Report” dated September 2, 2011,
submitted by Antea Group, approximately 1,400 gallons of petroleum were released to the ground surface
from the AST system in 1988. In 1990, a ground water treatment system was installed at the site and
operated until 1995. Semi-annual and annual ground water sampling has been conducted at the site since
1995. Please refer to previous submittals for additional historical information regarding the site. Please
note, the buildings on the site property have been demolished and the property ownership has transferred
to the City of Wilson.

2.0 CURRENT SITE ASSESSMENT
The purpose of this report is to present the results of ground water sampling activities conducted on May
20, 2015 at the former Wilson Petroleum Bulk Plant site. The activities were conducted in accordance
with GRI Proposal Number 15-184. The scope of work includes obtaining current ground water quality
data.

3.0 GROUND WATER SAMPLING ACTIVITIES
3.1 Site Hydrogeology
On May 20, 2015, six Type II monitoring wells (MW-2, MW-5 through MW-8, and MW-12) were
gauged, purged, and sampled. Monitoring wells MW-1, MW-4, MW-10, and MW-11 were not located
during sampling activities and are assumed to have been destroyed during site renovations. The depths to
ground water in the Type II monitoring wells during the May 2015 sampling event ranged from 2.06 to
6.15 feet below the tops of well casings. Ground water elevations in the Type II monitoring wells relative
to a temporary benchmark assumed by the previous consultant ranged from 45.77 to 48.04 feet. Based on
these data, the ground water flow direction at the site is toward the southwest. The horizontal hydraulic
gradient between MW-2 and MW-7 was 0.01 feet per foot toward the southwest.

A Site Map showing the locations of the monitoring wells is included as Figure 3. A Water Table
Surface Map for the May 20, 2015 sampling event has been included as Figure 4. A summary of well
construction information including ground water elevation data is presented in Table 1. Historical
gauging data are included in Appendix A.

2

3.2 Ground Water Sampling
Laboratory analyses were performed on the ground water samples collected on May 20, 2015 from the
monitoring wells for volatile organic compounds by EPA Method 6200 and for lead by EPA Method
6010.

4.0 GROUND WATER QUALITY
Concentrations of benzene and/or MTBE that exceeded the maximum allowable concentrations (MACs)
specified in T15A NCAC 2L.0202 were reported in samples collected from MW-2 and MW-8.
Concentrations of lead in samples collected from MW-2, MW-5 through MW-8, and MW-12 exceeded
the MACs. No contaminant concentrations exceeded the gross contaminant levels (GCLs). A Ground
Water Quality Map based on data from the May 20, 2015 sampling event has been included as Figure 5.
A summary of historical ground water quality data is included in Appendix B. A complete laboratory
report has been included in Appendix C.

5.0 SUMMARY AND CONCLUSIONS
 The site is located within the city limits of Wilson. No structures remain on-site and the property
ownership has transferred to the City of Wilson.
 Monitoring wells MW-1, MW-4, MW-10, and MW-11 were not located during sampling
activities and are assumed to have been destroyed during site renovations.
 The average depth to ground water in the Type II monitoring wells in May was 4.46 feet. The
general ground water flow direction at the site was southwest with an average horizontal
hydraulic gradient of 0.01 feet per foot.
 Concentrations of benzene and/or MTBE reported in MW-2 and MW-8 exceeded the MACs.
Concentrations of lead in MW-2, MW-5 through MW-8, and MW-12 exceeded the MACs. No
contaminant concentrations exceeded the GCLs.
 Based on this information, ground water monitoring is required to continue until the ground water
contamination has attenuated below the MACs or until risked based rules can be applied to this
incident. The next ground water monitoring event should occur in March 2016.

6.0 LIMITATIONS
This report has been prepared for the exclusive use of Wilson Petroleum Company, Inc. for specific

3

application to the referenced site in Wilson County, North Carolina. The assessment was conducted
based on the scope of work and level of effort specified by NCDENR and with resources adequate only
for that scope of work. Our findings have been developed in accordance with generally accepted
standards of geology and hydrogeology practices in the State of North Carolina, available information,
and our professional judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would be
interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES

TABLES
Facility ID # : N/A
03/26/13 2 2-30 30 54.49 5.02 ---49.47
03/05/14
03/26/13 4.23 ---46.69
03/05/14 4.29 ---46.63
05/20/15 4.53 ---46.39
03/26/13 3 3-15 15 48.98 2.11 ---46.87
03/05/14
03/26/13 4.62 ---45.59
03/05/14 4.26 ---45.95
05/20/15 4.44 ---45.77
03/26/13 4.98 ---48.81
03/05/14 5.85 ---47.94
05/20/15 6.15 ---47.64
03/26/13 4.30 ---48.07
03/05/14 4.77 ---47.60
05/20/15 4.33 ---48.04
202-20206/30/88MW-5
152-15206/30/88MW-6
TABLE 1
WELL CONSTRUCTION AND GUAGING INFORMATION
WILSON PETROLEUM BULK PLANT (INCIDENT NO. 3620)
Bottom
of Well
(ft.
BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Ground
Water
from Top
of Casing
(ft.)
Well
Casing
Depth
(ft. BGS)
Date
Installed
(mm/dd/yy)
Date
Water
Level
Measured
(mm/dd/yy)
Free
Product
Thickness
(ft.)
Well
ID
Date: 3/12/14
Ground
Water
Elevation
(ft.)
Screened
Interval
(x to y
ft. BGS)
06/27/88
MW-7 NA
06/30/88
MW-1
MW-4
MW-2
06/29/88
Destroyed
7.95 52.37NANA
50.21
53.79
Destroyed
50.92122-122
page 1 of 3
Facility ID # : N/A
TABLE 1
WELL CONSTRUCTION AND GUAGING INFORMATION
WILSON PETROLEUM BULK PLANT (INCIDENT NO. 3620)
Bottom
of Well
(ft.
BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Ground
Water
from Top
of Casing
(ft.)
Well
Casing
Depth
(ft. BGS)
Date
Installed
(mm/dd/yy)
Date
Water
Level
Measured
(mm/dd/yy)
Free
Product
Thickness
(ft.)
Well
ID
Date: 3/12/14
Ground
Water
Elevation
(ft.)
Screened
Interval
(x to y
ft. BGS)
03/26/13 4.88 ---47.12
03/05/14 5.04 ---46.96
05/20/15 5.29 ---46.71
03/26/13 3.5 3.5-14 14 50.14 2.03 ---48.11
03/05/14
03/26/13 3.5 3.5-14 14 50.33 3.62 ---46.71
03/05/14
03/26/13 1.97 ---46.09
03/05/14 1.76 ---46.30
05/20/15 2.06 ---46.00
03/26/13 5.83 ---46.80
03/05/14 6.64 ---45.99
03/26/13 NA NA 23.9 49.21 1.58 ---47.63
03/05/14
03/26/13 2.40 ---49.14
03/05/14 2.98 ---48.56
NA
MW-10
MW-11
RW-2
RW-3
Destroyed07/23/96
07/23/96MW-12
RW-1
07/23/96
NA
NA
NAMW-8 52.008.73NANA
Destroyed
Destroyed
NA NA 10.02 51.54
NA NA 25.32 52.63
48.06143.5-143.5
page 2 of 3
Facility ID # : N/A
TABLE 1
WELL CONSTRUCTION AND GUAGING INFORMATION
WILSON PETROLEUM BULK PLANT (INCIDENT NO. 3620)
Bottom
of Well
(ft.
BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Ground
Water
from Top
of Casing
(ft.)
Well
Casing
Depth
(ft. BGS)
Date
Installed
(mm/dd/yy)
Date
Water
Level
Measured
(mm/dd/yy)
Free
Product
Thickness
(ft.)
Well
ID
Date: 3/12/14
Ground
Water
Elevation
(ft.)
Screened
Interval
(x to y
ft. BGS)
Notes:
• *: Top-of-casing elevations and well construction data are reproduced from the Groundwater Monitoring Report (Sept. 2011) prepared by Antea Group.
• NA: Information unavaialable.
• ft BGS: feet below ground surface
page 3 of 3
Facility ID # : N/A
EPA Method
6010/3030C
Well
ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 15
5,000 260,000 84,500 85,500 20,000 6,000 25,000 30,000 28,500 25,000 15,000
3/26/2013 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 0.23 J <0.10 <0.10 <0.10 27.0
3/5/2014
3/26/2013 0.39 J <0.10 <0.10 <0.22 59.6 0.50 1.1 0.12 J <0.10 <0.10 74.3
3/5/2014 <0.10 0.25 J 0.18 J 0.50 J 94.0 <0.10 0.59 <0.10 <0.10 <0.10 7.7
5/20/2015 <1.7 <1.7 <1.5 <4.3 242 <1.2 <1.2 <1.6 <1.4 <1.4 61.6
3/26/2013 28.7 39.0 1,200 2,050 <2.0 658 135 328 505 1,710 151
3/5/2014
3/26/2013 <0.10 <0.10 <0.10 <0.22 4.6 0.37 J <0.10 <0.10 <0.10 <0.10 22.5
3/5/2014 <0.10 <0.10 <0.10 <0.20 0.34 J <0.10 <0.10 <0.10 <0.10 <0.10 9.3
5/20/2015 <0.17 <0.17 <0.15 <0.43 1.5 <0.12 <0.12 <0.16 <0.14 <0.14 160.0
3/26/2013 <0.10 <0.10 <0.10 <0.22 <0.10 <0.15 <0.10 <0.10 <0.10 <0.10 46.1
3/5/2014 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 10.4
5/20/2015 0.21 J <0.17 <0.15 <0.43 1.6 <0.12 <0.12 <0.16 <0.14 <0.14 298.0
3/26/2013 <0.10 0.65 0.32 J 1.3 J <0.10 0.27 J <0.10 0.11 J 0.12 J 0.46 J 12.9
3/5/2014 <0.10 <0.10 <0.10 <0.20 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 367
5/20/2015 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.12 <0.16 <0.14 <0.14 102
3/26/2013 11.5 0.81 0.47 J 1.8 27.2 8.6 5.4 4.9 <0.10 0.21 J 21.1
3/5/2014 0.13 J <0.10 <0.10 <0.20 14.9 <0.10 <0.10 <0.10 <0.10 <0.10 13.8
5/20/2015 8.5 0.29 J <0.15 <0.43 34.2 <0.12 0.40 J 0.33 J <0.14 <0.14 303
3/26/2013 61.0 8.3 11.8 15.1 17.2 90.5 24.6 49.6 0.14 J 0.63 5.3
3/5/2014
3/26/2013 <0.10 <0.10 <0.10 <0.22 3.6 <0.15 0.11 J <0.10 <0.10 <0.10 10.21,2,4-TrimethylbenzeneTABLE 2
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
WILSON PETROLEUM BULK PLANT (INCIDENT NO. 3620)TolueneEthylbenzeneNaphthalene1,3,5-TrimethylbenzeneIsoprpylbenzenen-PropylbenzneAnalytical Method EPA 6200B
Date: 06/02/15
Contaminant of Concern
LeadMTBEGCL
MAC XylenesDestroyed
Destroyed
DestroyedBenzeneMW-1
MW-4
MW-10
MW-11
MW-2
MW-5
MW-6
MW-7
MW-8
Page 1 of 2
Facility ID # : N/A
EPA Method
6010/3030C
Well
ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 15
5,000 260,000 84,500 85,500 20,000 6,000 25,000 30,000 28,500 25,000 15,0001,2,4-TrimethylbenzeneTABLE 2
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
WILSON PETROLEUM BULK PLANT (INCIDENT NO. 3620)TolueneEthylbenzeneNaphthalene1,3,5-TrimethylbenzeneIsoprpylbenzenen-PropylbenzneAnalytical Method EPA 6200B
Date: 06/02/15
Contaminant of Concern
LeadMTBEGCL
MAC XylenesBenzene3/5/2014
3/26/2013 <0.10 <0.10 <0.10 <0.22 1.8 0.30 J 0.20 J <0.10 <0.10 <0.10 151
3/5/2014 <0.10 <0.10 <0.10 <0.20 0.55 <0.10 <0.10 <0.10 <0.10 <0.10 10.0
5/20/2015 <0.17 <0.17 <0.15 <0.43 0.30 J <0.12 <0.12 <0.16 <0.14 <0.14 34.7
Notes:
MW-12
• The following contaminant concentrations reported in samples collected March 2013 exceeded the MACs but not the GCL: benzo(a) anthracene (0.071 J
mg/L) and benzo(a)pyrene (0.16 J mg/L) in MW-4.
• Concentrations in bold face type exceed the MACs; concentrations in italics exceed the GCLs.
• J: Estimated concentration.
• Results reported in µg/l.
• MAC: Maximum allowable concentration specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level
• < : Less than the method detection limit specified in the analytical report.
• NR: Analyses not requested.
Destroyed
MW-11
Page 2 of 2

APPENDICES

APPENDIX A Historical Gauging Data

APPENDIX B Historical Ground Water Quality Data

APPENDIX C
Laboratory Report
05/29/15
Technical Report for
GRI (Geological Resources Inc.)
Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
3620
Accutest Job Number: FA24542
Sampling Date: 05/20/15
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: Rae Brown
Total number of pages in report:
Certifications: FL (E83510), LA (03051), KS (E-10327), IA (366), IL (200063), NC (573), NJ (FL002), SC (96038001)
DoD ELAP (L-A-B L2229), CA (2937), TX (T104704404), PA (68-03573), VA (460177),
AK, AR, GA, KY, MA, NV, OK, UT, WA
This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories.
Test results relate only to samples analyzed.
Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone] • http://www.accutest.com
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Southeast
05/29/15
e-Hardcopy 2.0
Automated Report
47
Accutest Laboratories is the sole authority for authorizing edits or modifications to this
document. Unauthorized modification of this report is strictly prohibited.
1 of 47
FA24542
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FA24542-1: MW-2 ........................................................................................................6
3.2: FA24542-2: MW-5 ........................................................................................................9
3.3: FA24542-3: MW-6 ........................................................................................................12
3.4: FA24542-4: MW-7 ........................................................................................................15
3.5: FA24542-5: MW-8 ........................................................................................................18
3.6: FA24542-6: MW-12 ......................................................................................................21
Section 4: Misc. Forms ............................................................................................................24
4.1: Chain of Custody ...........................................................................................................25
Section 5: GC/MS Volatiles - QC Data Summaries ..............................................................28
5.1: Method Blank Summary ................................................................................................29
5.2: Blank Spike Summary ...................................................................................................33
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................37
Section 6: Metals Analysis - QC Data Summaries ................................................................41
6.1: Prep QC MP28959: Pb ..................................................................................................42 1234562 of 47
FA24542
Accutest Laboratories
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA24542
Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Project No: 3620
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA24542-1 05/20/15 09:47 CB 05/21/15 AQ Ground Water MW-2
FA24542-2 05/20/15 09:16 CB 05/21/15 AQ Ground Water MW-5
FA24542-3 05/20/15 09:08 CB 05/21/15 AQ Ground Water MW-6
FA24542-4 05/20/15 08:57 CB 05/21/15 AQ Ground Water MW-7
FA24542-5 05/20/15 09:33 CB 05/21/15 AQ Ground Water MW-8
FA24542-6 05/20/15 09:27 CB 05/21/15 AQ Ground Water MW-12
3 of 47
FA24542 1
Summary of Hits Page 1 of 1
Job Number:FA24542
Account:GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Collected:05/20/15
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA24542-1 MW-2
Methyl Tert Butyl Ether 242 5.0 1.6 ug/l SM 6200B
Lead 61.6 5.0 ug/l SW846 6010C
FA24542-2 MW-5
Methyl Tert Butyl Ether 1.5 0.50 0.16 ug/l SM 6200B
Lead 160 5.0 ug/l SW846 6010C
FA24542-3 MW-6
Benzene 0.21 J 0.50 0.17 ug/l SM 6200B
Methyl Tert Butyl Ether 1.6 0.50 0.16 ug/l SM 6200B
Lead 298 5.0 ug/l SW846 6010C
FA24542-4 MW-7
Lead 102 5.0 ug/l SW846 6010C
FA24542-5 MW-8
Benzene 8.5 0.50 0.17 ug/l SM 6200B
Isopropylbenzene 0.40 J 0.50 0.12 ug/l SM 6200B
Methyl Tert Butyl Ether 34.2 0.50 0.16 ug/l SM 6200B
n-Propylbenzene 0.33 J 0.50 0.16 ug/l SM 6200B
Toluene 0.29 J 0.50 0.17 ug/l SM 6200B
Lead 303 5.0 ug/l SW846 6010C
FA24542-6 MW-12
Methyl Tert Butyl Ether 0.30 J 0.50 0.16 ug/l SM 6200B
Lead 34.7 5.0 ug/l SW846 6010C
4 of 47
FA24542 2
Accutest Laboratories
Sample Results
Report of Analysis
Southeast
Section 3
5 of 47
FA24542 3
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-2
Lab Sample ID:FA24542-1 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E038653.D 10 05/28/15 TD n/a n/a VE1284
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 5.0 1.7 ug/l
108-86-1 Bromobenzene ND 5.0 1.6 ug/l
74-97-5 Bromochloromethane ND 5.0 1.6 ug/l
75-27-4 Bromodichloromethane ND 5.0 1.5 ug/l
75-25-2 Bromoform ND 5.0 1.1 ug/l
104-51-8 n-Butylbenzene ND 5.0 1.4 ug/l
135-98-8 sec-Butylbenzene ND 5.0 1.4 ug/l
98-06-6 tert-Butylbenzene ND 5.0 1.5 ug/l
56-23-5 Carbon Tetrachloride ND 5.0 1.5 ug/l
108-90-7 Chlorobenzene ND 5.0 1.6 ug/l
75-00-3 Chloroethane ND 5.0 2.1 ug/l
67-66-3 Chloroform ND 5.0 1.7 ug/l
95-49-8 o-Chlorotoluene ND 5.0 1.5 ug/l
106-43-4 p-Chlorotoluene ND 5.0 1.4 ug/l
124-48-1 Dibromochloromethane ND 5.0 1.2 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 2.0 ug/l
106-93-4 1,2-Dibromoethane ND 5.0 1.4 ug/l
75-71-8 Dichlorodifluoromethane ND 5.0 1.3 ug/l
95-50-1 1,2-Dichlorobenzene ND 5.0 1.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 5.0 1.4 ug/l
106-46-7 1,4-Dichlorobenzene ND 5.0 1.5 ug/l
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/l
107-06-2 1,2-Dichloroethane ND 5.0 1.6 ug/l
75-35-4 1,1-Dichloroethylene ND 5.0 1.7 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.8 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.7 ug/l
78-87-5 1,2-Dichloropropane ND 5.0 1.7 ug/l
142-28-9 1,3-Dichloropropane ND 5.0 1.5 ug/l
594-20-7 2,2-Dichloropropane ND 5.0 1.2 ug/l
563-58-6 1,1-Dichloropropene ND 5.0 1.6 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 of 47
FA24542 33.1
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-2
Lab Sample ID:FA24542-1 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 5.0 1.6 ug/l
100-41-4 Ethylbenzene ND 5.0 1.5 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 1.2 ug/l
98-82-8 Isopropylbenzene ND 5.0 1.2 ug/l
99-87-6 p-Isopropyltoluene ND 5.0 1.2 ug/l
74-83-9 Methyl Bromide ND 5.0 1.8 ug/l
74-87-3 Methyl Chloride ND 5.0 1.6 ug/l
74-95-3 Methylene Bromide ND 5.0 1.7 ug/l
75-09-2 Methylene Chloride ND 20 10 ug/l
1634-04-4 Methyl Tert Butyl Ether 242 5.0 1.6 ug/l
91-20-3 Naphthalene ND 5.0 1.2 ug/l
103-65-1 n-Propylbenzene ND 5.0 1.6 ug/l
100-42-5 Styrene ND 5.0 1.2 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.4 ug/l
127-18-4 Tetrachloroethylene ND 5.0 1.5 ug/l
108-88-3 Toluene ND 5.0 1.7 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.4 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.3 ug/l
71-55-6 1,1,1-Trichloroethane ND 5.0 1.6 ug/l
79-00-5 1,1,2-Trichloroethane ND 5.0 1.4 ug/l
79-01-6 Trichloroethylene ND 5.0 1.5 ug/l
75-69-4 Trichlorofluoromethane ND 5.0 1.6 ug/l
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.4 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.4 ug/l
75-01-4 Vinyl Chloride ND 5.0 1.3 ug/l
m,p-Xylene ND 10 3.0 ug/l
95-47-6 o-Xylene ND 5.0 1.3 ug/l
1330-20-7 Xylene (total)ND 15 4.3 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 109%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 47
FA24542 33.1
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-2
Lab Sample ID:FA24542-1 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 61.6 5.0 ug/l 1 05/22/15 05/22/15 LM SW846 6010C 1 SW846 3010A 2
(1) Instrument QC Batch: MA12420
(2) Prep QC Batch: MP28959
RL = Reporting Limit
8 of 47
FA24542 33.1
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-5
Lab Sample ID:FA24542-2 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E038654.D 1 05/28/15 TD n/a n/a VE1284
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.17 ug/l
108-86-1 Bromobenzene ND 0.50 0.16 ug/l
74-97-5 Bromochloromethane ND 0.50 0.16 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.15 ug/l
75-25-2 Bromoform ND 0.50 0.11 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.14 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.15 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.15 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.21 ug/l
67-66-3 Chloroform ND 0.50 0.17 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.15 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.14 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.12 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.14 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.14 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.15 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.18 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.16 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.17 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.18 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.17 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.17 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.15 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.12 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.16 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 47
FA24542 33.2
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-5
Lab Sample ID:FA24542-2 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.16 ug/l
100-41-4 Ethylbenzene ND 0.50 0.15 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.12 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.12 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.12 ug/l
74-83-9 Methyl Bromide ND 0.50 0.18 ug/l
74-87-3 Methyl Chloride ND 0.50 0.16 ug/l
74-95-3 Methylene Bromide ND 0.50 0.17 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 1.5 0.50 0.16 ug/l
91-20-3 Naphthalene ND 0.50 0.12 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.16 ug/l
100-42-5 Styrene ND 0.50 0.12 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.14 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.15 ug/l
108-88-3 Toluene ND 0.50 0.17 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.14 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.14 ug/l
79-01-6 Trichloroethylene ND 0.50 0.15 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.16 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.14 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.14 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.30 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.43 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 47
FA24542 33.2
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-5
Lab Sample ID:FA24542-2 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 160 5.0 ug/l 1 05/22/15 05/22/15 LM SW846 6010C 1 SW846 3010A 2
(1) Instrument QC Batch: MA12420
(2) Prep QC Batch: MP28959
RL = Reporting Limit
11 of 47
FA24542 33.2
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-6
Lab Sample ID:FA24542-3 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E038655.D 1 05/28/15 TD n/a n/a VE1284
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 0.21 0.50 0.17 ug/l J
108-86-1 Bromobenzene ND 0.50 0.16 ug/l
74-97-5 Bromochloromethane ND 0.50 0.16 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.15 ug/l
75-25-2 Bromoform ND 0.50 0.11 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.14 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.15 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.15 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.21 ug/l
67-66-3 Chloroform ND 0.50 0.17 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.15 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.14 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.12 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.14 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.14 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.15 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.18 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.16 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.17 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.18 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.17 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.17 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.15 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.12 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.16 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 47
FA24542 33.3
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-6
Lab Sample ID:FA24542-3 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.16 ug/l
100-41-4 Ethylbenzene ND 0.50 0.15 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.12 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.12 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.12 ug/l
74-83-9 Methyl Bromide ND 0.50 0.18 ug/l
74-87-3 Methyl Chloride ND 0.50 0.16 ug/l
74-95-3 Methylene Bromide ND 0.50 0.17 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 1.6 0.50 0.16 ug/l
91-20-3 Naphthalene ND 0.50 0.12 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.16 ug/l
100-42-5 Styrene ND 0.50 0.12 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.14 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.15 ug/l
108-88-3 Toluene ND 0.50 0.17 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.14 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.14 ug/l
79-01-6 Trichloroethylene ND 0.50 0.15 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.16 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.14 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.14 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.30 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.43 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 47
FA24542 33.3
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-6
Lab Sample ID:FA24542-3 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 298 5.0 ug/l 1 05/22/15 05/22/15 LM SW846 6010C 1 SW846 3010A 2
(1) Instrument QC Batch: MA12420
(2) Prep QC Batch: MP28959
RL = Reporting Limit
14 of 47
FA24542 33.3
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-7
Lab Sample ID:FA24542-4 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E038612.D 1 05/28/15 TD n/a n/a VE1283
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.17 ug/l
108-86-1 Bromobenzene ND 0.50 0.16 ug/l
74-97-5 Bromochloromethane ND 0.50 0.16 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.15 ug/l
75-25-2 Bromoform ND 0.50 0.11 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.14 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.15 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.15 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.21 ug/l
67-66-3 Chloroform ND 0.50 0.17 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.15 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.14 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.12 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.14 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.14 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.15 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.18 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.16 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.17 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.18 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.17 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.17 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.15 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.12 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.16 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 47
FA24542 33.4
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-7
Lab Sample ID:FA24542-4 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.16 ug/l
100-41-4 Ethylbenzene ND 0.50 0.15 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.12 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.12 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.12 ug/l
74-83-9 Methyl Bromide ND 0.50 0.18 ug/l
74-87-3 Methyl Chloride ND 0.50 0.16 ug/l
74-95-3 Methylene Bromide ND 0.50 0.17 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.16 ug/l
91-20-3 Naphthalene ND 0.50 0.12 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.16 ug/l
100-42-5 Styrene ND 0.50 0.12 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.14 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.15 ug/l
108-88-3 Toluene ND 0.50 0.17 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.14 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.14 ug/l
79-01-6 Trichloroethylene ND 0.50 0.15 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.16 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.14 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.14 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.30 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.43 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 83%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 47
FA24542 33.4
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-7
Lab Sample ID:FA24542-4 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 102 5.0 ug/l 1 05/22/15 05/22/15 LM SW846 6010C 1 SW846 3010A 2
(1) Instrument QC Batch: MA12420
(2) Prep QC Batch: MP28959
RL = Reporting Limit
17 of 47
FA24542 33.4
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-8
Lab Sample ID:FA24542-5 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E038656.D 1 05/28/15 TD n/a n/a VE1284
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 8.5 0.50 0.17 ug/l
108-86-1 Bromobenzene ND 0.50 0.16 ug/l
74-97-5 Bromochloromethane ND 0.50 0.16 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.15 ug/l
75-25-2 Bromoform ND 0.50 0.11 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.14 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.15 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.15 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.21 ug/l
67-66-3 Chloroform ND 0.50 0.17 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.15 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.14 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.12 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.14 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.14 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.15 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.18 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.16 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.17 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.18 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.17 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.17 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.15 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.12 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.16 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 47
FA24542 33.5
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-8
Lab Sample ID:FA24542-5 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.16 ug/l
100-41-4 Ethylbenzene ND 0.50 0.15 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.12 ug/l
98-82-8 Isopropylbenzene 0.40 0.50 0.12 ug/l J
99-87-6 p-Isopropyltoluene ND 0.50 0.12 ug/l
74-83-9 Methyl Bromide ND 0.50 0.18 ug/l
74-87-3 Methyl Chloride ND 0.50 0.16 ug/l
74-95-3 Methylene Bromide ND 0.50 0.17 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 34.2 0.50 0.16 ug/l
91-20-3 Naphthalene ND 0.50 0.12 ug/l
103-65-1 n-Propylbenzene 0.33 0.50 0.16 ug/l J
100-42-5 Styrene ND 0.50 0.12 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.14 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.15 ug/l
108-88-3 Toluene 0.29 0.50 0.17 ug/l J
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.14 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.14 ug/l
79-01-6 Trichloroethylene ND 0.50 0.15 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.16 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.14 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.14 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.30 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.43 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 105%70-130%
17060-07-0 1,2-Dichloroethane-D4 109%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 47
FA24542 33.5
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-8
Lab Sample ID:FA24542-5 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 303 5.0 ug/l 1 05/22/15 05/22/15 LM SW846 6010C 1 SW846 3010A 2
(1) Instrument QC Batch: MA12420
(2) Prep QC Batch: MP28959
RL = Reporting Limit
20 of 47
FA24542 33.5
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-12
Lab Sample ID:FA24542-6 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E038657.D 1 05/28/15 TD n/a n/a VE1284
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.17 ug/l
108-86-1 Bromobenzene ND 0.50 0.16 ug/l
74-97-5 Bromochloromethane ND 0.50 0.16 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.15 ug/l
75-25-2 Bromoform ND 0.50 0.11 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.14 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.15 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.15 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.21 ug/l
67-66-3 Chloroform ND 0.50 0.17 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.15 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.14 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.12 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.14 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.14 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.15 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.18 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.16 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.17 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.18 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.17 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.17 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.15 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.12 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.16 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 47
FA24542 33.6
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-12
Lab Sample ID:FA24542-6 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Method:SM 6200B Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.16 ug/l
100-41-4 Ethylbenzene ND 0.50 0.15 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.12 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.12 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.12 ug/l
74-83-9 Methyl Bromide ND 0.50 0.18 ug/l
74-87-3 Methyl Chloride ND 0.50 0.16 ug/l
74-95-3 Methylene Bromide ND 0.50 0.17 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.30 0.50 0.16 ug/l J
91-20-3 Naphthalene ND 0.50 0.12 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.16 ug/l
100-42-5 Styrene ND 0.50 0.12 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.14 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.15 ug/l
108-88-3 Toluene ND 0.50 0.17 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.14 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.14 ug/l
79-01-6 Trichloroethylene ND 0.50 0.15 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.16 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.14 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.14 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.30 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.43 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 109%70-130%
2037-26-5 Toluene-D8 93%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
22 of 47
FA24542 33.6
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-12
Lab Sample ID:FA24542-6 Date Sampled:05/20/15
Matrix:AQ - Ground Water Date Received:05/21/15
Percent Solids:n/a
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Total Metals Analysis
Analyte Result RL Units DF Prep Analyzed By Method Prep Method
Lead 34.7 5.0 ug/l 1 05/22/15 05/22/15 LM SW846 6010C 1 SW846 3010A 2
(1) Instrument QC Batch: MA12420
(2) Prep QC Batch: MP28959
RL = Reporting Limit
23 of 47
FA24542 33.6
Accutest Laboratories
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Southeast
Section 4
24 of 47
FA24542 4
FA24542: Chain of Custody
Page 1 of 3
25 of 47
FA24542 44.1
FA24542: Chain of Custody
Page 2 of 3
26 of 47
FA24542 44.1
FA24542: Chain of Custody
Page 3 of 3
27 of 47
FA24542 44.1
Accutest Laboratories
GC/MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
Section 5
28 of 47
FA24542 5
Method Blank Summary Page 1 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1283-MB E038608.D 1 05/28/15 TD n/a n/a VE1283
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-4
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.17 ug/l
108-86-1 Bromobenzene ND 0.50 0.16 ug/l
74-97-5 Bromochloromethane ND 0.50 0.16 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.15 ug/l
75-25-2 Bromoform ND 0.50 0.11 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.14 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.15 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.15 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.21 ug/l
67-66-3 Chloroform ND 0.50 0.17 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.15 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.14 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.12 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.14 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.14 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.15 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.18 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.16 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.17 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.18 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.17 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.17 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.15 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.12 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.16 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.16 ug/l
100-41-4 Ethylbenzene ND 0.50 0.15 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.12 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.12 ug/l
29 of 47
FA24542 55.1.1
Method Blank Summary Page 2 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1283-MB E038608.D 1 05/28/15 TD n/a n/a VE1283
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-4
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.12 ug/l
74-83-9 Methyl Bromide ND 0.50 0.18 ug/l
74-87-3 Methyl Chloride ND 0.50 0.16 ug/l
74-95-3 Methylene Bromide ND 0.50 0.17 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.16 ug/l
91-20-3 Naphthalene ND 0.50 0.12 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.16 ug/l
100-42-5 Styrene ND 0.50 0.12 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.14 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.15 ug/l
108-88-3 Toluene ND 0.50 0.17 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.14 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.14 ug/l
79-01-6 Trichloroethylene ND 0.50 0.15 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.16 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.14 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.14 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.30 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.43 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 84%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
30 of 47
FA24542 55.1.1
Method Blank Summary Page 1 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1284-MB E038649.D 1 05/28/15 TD n/a n/a VE1284
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-1, FA24542-2, FA24542-3, FA24542-5, FA24542-6
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.17 ug/l
108-86-1 Bromobenzene ND 0.50 0.16 ug/l
74-97-5 Bromochloromethane ND 0.50 0.16 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.15 ug/l
75-25-2 Bromoform ND 0.50 0.11 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.14 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.14 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.15 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.15 ug/l
108-90-7 Chlorobenzene ND 0.50 0.16 ug/l
75-00-3 Chloroethane ND 0.50 0.21 ug/l
67-66-3 Chloroform ND 0.50 0.17 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.15 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.14 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.12 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.20 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.14 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.13 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.14 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.15 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.18 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.16 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.17 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.18 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.17 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.17 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.15 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.12 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.16 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.16 ug/l
100-41-4 Ethylbenzene ND 0.50 0.15 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.12 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.12 ug/l
31 of 47
FA24542 55.1.2
Method Blank Summary Page 2 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1284-MB E038649.D 1 05/28/15 TD n/a n/a VE1284
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-1, FA24542-2, FA24542-3, FA24542-5, FA24542-6
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.12 ug/l
74-83-9 Methyl Bromide ND 0.50 0.18 ug/l
74-87-3 Methyl Chloride ND 0.50 0.16 ug/l
74-95-3 Methylene Bromide ND 0.50 0.17 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.16 ug/l
91-20-3 Naphthalene ND 0.50 0.12 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.16 ug/l
100-42-5 Styrene ND 0.50 0.12 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.14 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.15 ug/l
108-88-3 Toluene ND 0.50 0.17 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.14 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.16 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.14 ug/l
79-01-6 Trichloroethylene ND 0.50 0.15 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.16 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.14 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.14 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.30 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.43 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
32 of 47
FA24542 55.1.2
Blank Spike Summary Page 1 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1283-BS E038606.D 1 05/27/15 TD n/a n/a VE1283
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-4
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 11.1 111 70-130
108-86-1 Bromobenzene 10 11.1 111 70-130
74-97-5 Bromochloromethane 10 9.9 99 70-130
75-27-4 Bromodichloromethane 10 8.4 84 70-130
75-25-2 Bromoform 10 9.3 93 70-130
104-51-8 n-Butylbenzene 10 10.1 101 70-130
135-98-8 sec-Butylbenzene 10 9.8 98 70-130
98-06-6 tert-Butylbenzene 10 10.1 101 70-130
56-23-5 Carbon Tetrachloride 10 10.0 100 70-130
108-90-7 Chlorobenzene 10 11.1 111 70-130
75-00-3 Chloroethane 10 8.4 84 60-140
67-66-3 Chloroform 10 10.0 100 70-130
95-49-8 o-Chlorotoluene 10 10.4 104 70-130
106-43-4 p-Chlorotoluene 10 10.4 104 70-130
124-48-1 Dibromochloromethane 10 9.3 93 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 7.9 79 70-130
106-93-4 1,2-Dibromoethane 10 9.6 96 70-130
75-71-8 Dichlorodifluoromethane 10 6.2 62 60-140
95-50-1 1,2-Dichlorobenzene 10 10.7 107 70-130
541-73-1 1,3-Dichlorobenzene 10 10.2 102 70-130
106-46-7 1,4-Dichlorobenzene 10 10.9 109 70-130
75-34-3 1,1-Dichloroethane 10 10.6 106 70-130
107-06-2 1,2-Dichloroethane 10 8.2 82 70-130
75-35-4 1,1-Dichloroethylene 10 8.7 87 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.8 108 70-130
156-60-5 trans-1,2-Dichloroethylene 10 11.1 111 70-130
78-87-5 1,2-Dichloropropane 10 10.2 102 70-130
142-28-9 1,3-Dichloropropane 10 9.8 98 70-130
594-20-7 2,2-Dichloropropane 10 8.5 85 70-130
563-58-6 1,1-Dichloropropene 10 10.6 106 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.6 96 70-130
10061-02-6 trans-1,3-Dichloropropene 10 10.2 102 70-130
108-20-3 Di-Isopropyl Ether 10 8.5 85 70-130
100-41-4 Ethylbenzene 10 10.5 105 70-130
87-68-3 Hexachlorobutadiene 10 10.4 104 70-130
98-82-8 Isopropylbenzene 10 9.1 91 70-130
* = Outside of Control Limits.
33 of 47
FA24542 55.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1283-BS E038606.D 1 05/27/15 TD n/a n/a VE1283
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-4
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 10.6 106 70-130
74-83-9 Methyl Bromide 10 8.5 85 60-140
74-87-3 Methyl Chloride 10 7.3 73 60-140
74-95-3 Methylene Bromide 10 9.1 91 70-130
75-09-2 Methylene Chloride 10 8.7 87 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.9 89 70-130
91-20-3 Naphthalene 10 10.7 107 70-130
103-65-1 n-Propylbenzene 10 10.9 109 70-130
100-42-5 Styrene 10 9.1 91 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.2 92 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 8.9 89 70-130
127-18-4 Tetrachloroethylene 10 11.6 116 70-130
108-88-3 Toluene 10 11.0 110 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.9 99 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.2 102 70-130
71-55-6 1,1,1-Trichloroethane 10 9.5 95 70-130
79-00-5 1,1,2-Trichloroethane 10 10.5 105 70-130
79-01-6 Trichloroethylene 10 11.8 118 70-130
75-69-4 Trichlorofluoromethane 10 7.9 79 60-140
96-18-4 1,2,3-Trichloropropane 10 9.9 99 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.6 106 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.5 95 70-130
75-01-4 Vinyl Chloride 10 8.4 84 60-140
m,p-Xylene 20 20.6 103 70-130
95-47-6 o-Xylene 10 10.2 102 70-130
1330-20-7 Xylene (total)30 30.8 103 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 78%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
* = Outside of Control Limits.
34 of 47
FA24542 55.2.1
Blank Spike Summary Page 1 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1284-BS E038648.D 1 05/28/15 TD n/a n/a VE1284
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-1, FA24542-2, FA24542-3, FA24542-5, FA24542-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.9 99 70-130
108-86-1 Bromobenzene 10 9.6 96 70-130
74-97-5 Bromochloromethane 10 9.7 97 70-130
75-27-4 Bromodichloromethane 10 8.0 80 70-130
75-25-2 Bromoform 10 9.0 90 70-130
104-51-8 n-Butylbenzene 10 8.8 88 70-130
135-98-8 sec-Butylbenzene 10 8.9 89 70-130
98-06-6 tert-Butylbenzene 10 8.5 85 70-130
56-23-5 Carbon Tetrachloride 10 8.1 81 70-130
108-90-7 Chlorobenzene 10 9.6 96 70-130
75-00-3 Chloroethane 10 10.7 107 60-140
67-66-3 Chloroform 10 9.7 97 70-130
95-49-8 o-Chlorotoluene 10 10 100 70-130
106-43-4 p-Chlorotoluene 10 9.9 99 70-130
124-48-1 Dibromochloromethane 10 8.6 86 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.2 82 70-130
106-93-4 1,2-Dibromoethane 10 8.5 85 70-130
75-71-8 Dichlorodifluoromethane 10 9.2 92 60-140
95-50-1 1,2-Dichlorobenzene 10 9.6 96 70-130
541-73-1 1,3-Dichlorobenzene 10 9.0 90 70-130
106-46-7 1,4-Dichlorobenzene 10 9.6 96 70-130
75-34-3 1,1-Dichloroethane 10 10.3 103 70-130
107-06-2 1,2-Dichloroethane 10 9.0 90 70-130
75-35-4 1,1-Dichloroethylene 10 9.0 90 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.4 94 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.6 106 70-130
78-87-5 1,2-Dichloropropane 10 9.8 98 70-130
142-28-9 1,3-Dichloropropane 10 9.6 96 70-130
594-20-7 2,2-Dichloropropane 10 8.7 87 70-130
563-58-6 1,1-Dichloropropene 10 8.9 89 70-130
10061-01-5 cis-1,3-Dichloropropene 10 8.4 84 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.2 92 70-130
108-20-3 Di-Isopropyl Ether 10 9.1 91 70-130
100-41-4 Ethylbenzene 10 9.7 97 70-130
87-68-3 Hexachlorobutadiene 10 9.4 94 70-130
98-82-8 Isopropylbenzene 10 8.6 86 70-130
* = Outside of Control Limits.
35 of 47
FA24542 55.2.2
Blank Spike Summary Page 2 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1284-BS E038648.D 1 05/28/15 TD n/a n/a VE1284
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-1, FA24542-2, FA24542-3, FA24542-5, FA24542-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 8.5 85 70-130
74-83-9 Methyl Bromide 10 9.4 94 60-140
74-87-3 Methyl Chloride 10 9.9 99 60-140
74-95-3 Methylene Bromide 10 8.2 82 70-130
75-09-2 Methylene Chloride 10 8.7 87 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.6 86 70-130
91-20-3 Naphthalene 10 9.5 95 70-130
103-65-1 n-Propylbenzene 10 10.3 103 70-130
100-42-5 Styrene 10 8.3 83 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 8.4 84 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.4 94 70-130
127-18-4 Tetrachloroethylene 10 8.7 87 70-130
108-88-3 Toluene 10 9.6 96 70-130
87-61-6 1,2,3-Trichlorobenzene 10 8.9 89 70-130
120-82-1 1,2,4-Trichlorobenzene 10 8.6 86 70-130
71-55-6 1,1,1-Trichloroethane 10 9.4 94 70-130
79-00-5 1,1,2-Trichloroethane 10 8.8 88 70-130
79-01-6 Trichloroethylene 10 8.5 85 70-130
75-69-4 Trichlorofluoromethane 10 9.4 94 60-140
96-18-4 1,2,3-Trichloropropane 10 9.6 96 70-130
95-63-6 1,2,4-Trimethylbenzene 10 8.7 87 70-130
108-67-8 1,3,5-Trimethylbenzene 10 8.6 86 70-130
75-01-4 Vinyl Chloride 10 9.9 99 60-140
m,p-Xylene 20 17.0 85 70-130
95-47-6 o-Xylene 10 8.5 85 70-130
1330-20-7 Xylene (total)30 25.5 85 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 96%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
* = Outside of Control Limits.
36 of 47
FA24542 55.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA24543-2MS E038630.D 500 05/28/15 TD n/a n/a VE1283
FA24543-2MSD E038631.D 500 05/28/15 TD n/a n/a VE1283
FA24543-2 a E038611.D 500 05/28/15 TD n/a n/a VE1283
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-4
FA24543-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 7090 5000 12700 112 5000 12600 110 1 70-130/20
108-86-1 Bromobenzene ND 5000 5700 114 5000 5640 113 1 70-130/20
74-97-5 Bromochloromethane ND 5000 5210 104 5000 5260 105 1 70-130/20
75-27-4 Bromodichloromethane ND 5000 5040 101 5000 5100 102 1 70-130/20
75-25-2 Bromoform ND 5000 5220 104 5000 5290 106 1 70-130/20
104-51-8 n-Butylbenzene ND 5000 5300 106 5000 5130 103 3 70-130/20
135-98-8 sec-Butylbenzene ND 5000 5190 104 5000 5060 101 3 70-130/20
98-06-6 tert-Butylbenzene ND 5000 5680 114 5000 5500 110 3 70-130/20
56-23-5 Carbon Tetrachloride ND 5000 6400 128 5000 6190 124 3 70-130/20
108-90-7 Chlorobenzene ND 5000 5840 117 5000 5720 114 2 70-130/20
75-00-3 Chloroethane ND 5000 5350 107 5000 5110 102 5 60-140/20
67-66-3 Chloroform ND 5000 5810 116 5000 5800 116 0 70-130/20
95-49-8 o-Chlorotoluene ND 5000 5700 114 5000 5540 111 3 70-130/20
106-43-4 p-Chlorotoluene ND 5000 5470 109 5000 5440 109 1 70-130/20
124-48-1 Dibromochloromethane ND 5000 5150 103 5000 5320 106 3 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 5000 4620 92 5000 4490 90 3 70-130/20
106-93-4 1,2-Dibromoethane ND 5000 5050 101 5000 5090 102 1 70-130/20
75-71-8 Dichlorodifluoromethane ND 5000 4420 88 5000 4230 85 4 60-140/20
95-50-1 1,2-Dichlorobenzene ND 5000 5650 113 5000 5570 111 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 5000 5280 106 5000 5300 106 0 70-130/20
106-46-7 1,4-Dichlorobenzene ND 5000 5630 113 5000 5660 113 1 70-130/20
75-34-3 1,1-Dichloroethane ND 5000 5910 118 5000 5910 118 0 70-130/20
107-06-2 1,2-Dichloroethane ND 5000 5370 107 5000 5300 106 1 70-130/20
75-35-4 1,1-Dichloroethylene ND 5000 5240 105 5000 5080 102 3 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 5000 5680 114 5000 5660 113 0 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 5000 6170 123 5000 6140 123 0 70-130/20
78-87-5 1,2-Dichloropropane ND 5000 5400 108 5000 5330 107 1 70-130/20
142-28-9 1,3-Dichloropropane ND 5000 5160 103 5000 5210 104 1 70-130/20
594-20-7 2,2-Dichloropropane ND 5000 4220 84 5000 4030 81 5 70-130/20
563-58-6 1,1-Dichloropropene ND 5000 5940 119 5000 5880 118 1 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 5000 5120 102 5000 5110 102 0 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 5000 5470 109 5000 5480 110 0 70-130/20
108-20-3 Di-Isopropyl Ether ND 5000 4620 92 5000 4660 93 1 70-130/20
100-41-4 Ethylbenzene 3560 5000 9130 111 5000 9000 109 1 70-130/20
87-68-3 Hexachlorobutadiene ND 5000 5530 111 5000 5480 110 1 70-130/20
98-82-8 Isopropylbenzene 112 J 5000 5170 101 5000 5070 99 2 70-130/20
* = Outside of Control Limits.
37 of 47
FA24542 55.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA24543-2MS E038630.D 500 05/28/15 TD n/a n/a VE1283
FA24543-2MSD E038631.D 500 05/28/15 TD n/a n/a VE1283
FA24543-2 a E038611.D 500 05/28/15 TD n/a n/a VE1283
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-4
FA24543-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 5000 5570 111 5000 5470 109 2 70-130/20
74-83-9 Methyl Bromide ND 5000 5740 115 5000 5490 110 4 60-140/20
74-87-3 Methyl Chloride ND 5000 4700 94 5000 4640 93 1 60-140/20
74-95-3 Methylene Bromide ND 5000 5250 105 5000 5270 105 0 70-130/20
75-09-2 Methylene Chloride ND 5000 5120 102 5000 5040 101 2 70-130/20
1634-04-4 Methyl Tert Butyl Ether 2000 5000 7110 102 5000 7210 104 1 70-130/20
91-20-3 Naphthalene 1080 5000 6570 110 5000 6640 111 1 70-130/20
103-65-1 n-Propylbenzene 433 5000 6110 114 5000 5940 110 3 70-130/20
100-42-5 Styrene ND 5000 4960 99 5000 4910 98 1 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 5000 5180 104 5000 5210 104 1 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 5000 4940 99 5000 4890 98 1 70-130/20
127-18-4 Tetrachloroethylene ND 5000 5920 118 5000 5880 118 1 70-130/20
108-88-3 Toluene 26500 E 5000 31000 90 5000 30900 88 0 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 5000 5270 105 5000 5280 106 0 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 5000 5270 105 5000 5400 108 2 70-130/20
71-55-6 1,1,1-Trichloroethane ND 5000 6030 121 5000 5850 117 3 70-130/20
79-00-5 1,1,2-Trichloroethane ND 5000 5320 106 5000 5550 111 4 70-130/20
79-01-6 Trichloroethylene ND 5000 5790 116 5000 5870 117 1 70-130/20
75-69-4 Trichlorofluoromethane ND 5000 5800 116 5000 5490 110 5 60-140/20
96-18-4 1,2,3-Trichloropropane ND 5000 5240 105 5000 5100 102 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 3220 5000 8730 110 5000 8610 108 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 708 5000 5770 101 5000 5600 98 3 70-130/20
75-01-4 Vinyl Chloride ND 5000 5380 108 5000 5240 105 3 60-140/20
m,p-Xylene 11500 10000 23100 116 10000 22800 113 1 70-130/20
95-47-6 o-Xylene 5600 5000 11300 114 5000 11400 116 1 70-130/20
1330-20-7 Xylene (total)17100 15000 34400 115 15000 34100 113 1 70-130/20
CAS No.Surrogate Recoveries MS MSD FA24543-2 Limits
1868-53-7 Dibromofluoromethane 104%105%96%70-130%
17060-07-0 1,2-Dichloroethane-D4 98%97%78%70-130%
2037-26-5 Toluene-D8 99%99%100%70-130%
460-00-4 4-Bromofluorobenzene 97%97%96%70-130%
(a) Confirmation run.
* = Outside of Control Limits.
38 of 47
FA24542 55.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA24543-4MS E038666.D 250 05/28/15 TD n/a n/a VE1284
FA24543-4MSD E038667.D 250 05/29/15 TD n/a n/a VE1284
FA24543-4 E038661.D 250 05/28/15 TD n/a n/a VE1284
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-1, FA24542-2, FA24542-3, FA24542-5, FA24542-6
FA24543-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 2330 2500 5130 112 2500 5060 109 1 70-130/20
108-86-1 Bromobenzene ND 2500 2750 110 2500 2650 106 4 70-130/20
74-97-5 Bromochloromethane ND 2500 2730 109 2500 2700 108 1 70-130/20
75-27-4 Bromodichloromethane ND 2500 2410 96 2500 2340 94 3 70-130/20
75-25-2 Bromoform ND 2500 2630 105 2500 2540 102 3 70-130/20
104-51-8 n-Butylbenzene 37.9 J 2500 2500 98 2500 2500 98 0 70-130/20
135-98-8 sec-Butylbenzene ND 2500 2530 101 2500 2510 100 1 70-130/20
98-06-6 tert-Butylbenzene ND 2500 2450 98 2500 2440 98 0 70-130/20
56-23-5 Carbon Tetrachloride ND 2500 2420 97 2500 2280 91 6 70-130/20
108-90-7 Chlorobenzene ND 2500 2770 111 2500 2710 108 2 70-130/20
75-00-3 Chloroethane ND 2500 3550 142*2500 3460 138 3 60-140/20
67-66-3 Chloroform ND 2500 2860 114 2500 2750 110 4 70-130/20
95-49-8 o-Chlorotoluene ND 2500 2950 118 2500 2920 117 1 70-130/20
106-43-4 p-Chlorotoluene ND 2500 2760 110 2500 2770 111 0 70-130/20
124-48-1 Dibromochloromethane ND 2500 2410 96 2500 2400 96 0 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 2500 2460 98 2500 2390 96 3 70-130/20
106-93-4 1,2-Dibromoethane ND 2500 2400 96 2500 2390 96 0 70-130/20
75-71-8 Dichlorodifluoromethane ND 2500 2950 118 2500 2850 114 3 60-140/20
95-50-1 1,2-Dichlorobenzene ND 2500 2770 111 2500 2730 109 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 2500 2490 100 2500 2480 99 0 70-130/20
106-46-7 1,4-Dichlorobenzene ND 2500 2690 108 2500 2680 107 0 70-130/20
75-34-3 1,1-Dichloroethane ND 2500 2890 116 2500 2840 114 2 70-130/20
107-06-2 1,2-Dichloroethane ND 2500 2750 110 2500 2690 108 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 2500 2580 103 2500 2480 99 4 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 2500 2610 104 2500 2660 106 2 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 2500 3060 122 2500 2970 119 3 70-130/20
78-87-5 1,2-Dichloropropane ND 2500 2790 112 2500 2730 109 2 70-130/20
142-28-9 1,3-Dichloropropane ND 2500 2700 108 2500 2630 105 3 70-130/20
594-20-7 2,2-Dichloropropane ND 2500 2320 93 2500 2220 89 4 70-130/20
563-58-6 1,1-Dichloropropene ND 2500 2540 102 2500 2470 99 3 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 2500 2350 94 2500 2350 94 0 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 2500 2560 102 2500 2560 102 0 70-130/20
108-20-3 Di-Isopropyl Ether ND 2500 2540 102 2500 2550 102 0 70-130/20
100-41-4 Ethylbenzene 2920 2500 5750 113 2500 5620 108 2 70-130/20
87-68-3 Hexachlorobutadiene ND 2500 2630 105 2500 2640 106 0 70-130/20
98-82-8 Isopropylbenzene 106 J 2500 2600 100 2500 2530 97 3 70-130/20
* = Outside of Control Limits.
39 of 47
FA24542 55.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA24542
Account:GRINCC GRI (Geological Resources Inc.)
Project:Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA24543-4MS E038666.D 250 05/28/15 TD n/a n/a VE1284
FA24543-4MSD E038667.D 250 05/29/15 TD n/a n/a VE1284
FA24543-4 E038661.D 250 05/28/15 TD n/a n/a VE1284
The QC reported here applies to the following samples:Method: SM 6200B
FA24542-1, FA24542-2, FA24542-3, FA24542-5, FA24542-6
FA24543-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 2500 2430 97 2500 2410 96 1 70-130/20
74-83-9 Methyl Bromide ND 2500 3010 120 2500 3020 121 0 60-140/20
74-87-3 Methyl Chloride ND 2500 3050 122 2500 3190 128 4 60-140/20
74-95-3 Methylene Bromide ND 2500 2430 97 2500 2340 94 4 70-130/20
75-09-2 Methylene Chloride ND 2500 2590 104 2500 2510 100 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether 216 2500 2770 102 2500 2650 97 4 70-130/20
91-20-3 Naphthalene 768 2500 3460 108 2500 3480 108 1 70-130/20
103-65-1 n-Propylbenzene 431 2500 3320 116 2500 3330 116 0 70-130/20
100-42-5 Styrene ND 2500 2410 96 2500 2370 95 2 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 2500 2450 98 2500 2390 96 2 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 2500 2690 108 2500 2670 107 1 70-130/20
127-18-4 Tetrachloroethylene ND 2500 2470 99 2500 2400 96 3 70-130/20
108-88-3 Toluene 9550 2500 12300 110 2500 12100 102 2 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 2500 2420 97 2500 2490 100 3 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 2500 2410 96 2500 2480 99 3 70-130/20
71-55-6 1,1,1-Trichloroethane ND 2500 2800 112 2500 2670 107 5 70-130/20
79-00-5 1,1,2-Trichloroethane ND 2500 2540 102 2500 2480 99 2 70-130/20
79-01-6 Trichloroethylene ND 2500 2410 96 2500 2350 94 3 70-130/20
75-69-4 Trichlorofluoromethane ND 2500 3070 123 2500 2910 116 5 60-140/20
96-18-4 1,2,3-Trichloropropane ND 2500 2700 108 2500 2690 108 0 70-130/20
95-63-6 1,2,4-Trimethylbenzene 2910 2500 5500 104 2500 5470 102 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 747 2500 3200 98 2500 3210 99 0 70-130/20
75-01-4 Vinyl Chloride ND 2500 3090 124 2500 3120 125 1 60-140/20
m,p-Xylene 8190 5000 13500 106 5000 13100 98 3 70-130/20
95-47-6 o-Xylene 3490 2500 6160 107 2500 5980 100 3 70-130/20
1330-20-7 Xylene (total)11700 7500 19700 107 7500 19100 99 3 70-130/20
CAS No.Surrogate Recoveries MS MSD FA24543-4 Limits
1868-53-7 Dibromofluoromethane 101%97%101%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%99%105%70-130%
2037-26-5 Toluene-D8 100%100%100%70-130%
460-00-4 4-Bromofluorobenzene 99%100%103%70-130%
* = Outside of Control Limits.
40 of 47
FA24542 55.3.2
Accutest Laboratories
Metals Analysis
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Control Sample Summaries
• Serial Dilution Summaries
Southeast
Section 6
41 of 47
FA24542 6
BLANK RESULTS SUMMARY
Part 2 - Method Blanks
Login Number: FA24542
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
QC Batch ID: MP28959 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/15
MB
Metal RL IDL MDL raw final
Aluminum 200 14 14
Antimony 6.0 1 1
Arsenic 10 1.3 1.3
Barium 200 1 1
Beryllium 4.0 .2 .2
Cadmium 5.0 .2 .2
Calcium 1000 50 50
Chromium 10 1 1
Cobalt 50 .2 .2
Copper 25 1 1
Iron 300 17 17
Lead 5.0 1 1.1 0.20 <5.0
Magnesium 5000 35 35
Manganese 15 .5 1
Molybdenum 50 .3 .3
Nickel 40 .4 .4
Potassium 10000 200 200
Selenium 10 2.4 2.9
Silver 10 .7 .7
Sodium 10000 500 500
Strontium 10 .5 .5
Thallium 10 1.1 1.4
Tin 50 .9 1
Titanium 10 .5 1
Vanadium 50 .5 .6
Zinc 20 3 4.4
Associated samples MP28959: FA24542-1, FA24542-2, FA24542-3, FA24542-4, FA24542-5, FA24542-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
42 of 47
FA24542 66.1.1
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA24542
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
QC Batch ID: MP28959 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/15 05/22/15
FA24530-15F QC FA24530-15F Spikelot QC
Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits
Aluminum anr
Antimony anr
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron anr
Lead 3.0 2.8 6.9 0-20 3.0 506 500 100.6 80-120
Magnesium anr
Manganese anr
Molybdenum
Nickel
Potassium anr
Selenium anr
Silver
Sodium anr
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP28959: FA24542-1, FA24542-2, FA24542-3, FA24542-4, FA24542-5, FA24542-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
43 of 47
FA24542 66.1.2
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Login Number: FA24542
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
QC Batch ID: MP28959 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/15
FA24530-15F Spikelot MSD QC
Metal Original MSD MPFLICP2 % Rec RPD Limit
Aluminum anr
Antimony anr
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron anr
Lead 3.0 512 500 101.8 1.2 20
Magnesium anr
Manganese anr
Molybdenum
Nickel
Potassium anr
Selenium anr
Silver
Sodium anr
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP28959: FA24542-1, FA24542-2, FA24542-3, FA24542-4, FA24542-5, FA24542-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 2
44 of 47
FA24542 66.1.2
SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY
Login Number: FA24542
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
QC Batch ID: MP28959 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/15
BSP Spikelot QC
Metal Result MPFLICP2 % Rec Limits
Aluminum anr
Antimony anr
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron anr
Lead 506 500 101.2 80-120
Magnesium anr
Manganese anr
Molybdenum
Nickel
Potassium anr
Selenium anr
Silver
Sodium anr
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP28959: FA24542-1, FA24542-2, FA24542-3, FA24542-4, FA24542-5, FA24542-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
45 of 47
FA24542 66.1.3
SERIAL DILUTION RESULTS SUMMARY
Login Number: FA24542
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
QC Batch ID: MP28959 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/15
FA24530-15F QC
Metal Original SDL 1:5 %DIF Limits
Aluminum anr
Antimony anr
Arsenic anr
Barium
Beryllium
Cadmium anr
Calcium anr
Chromium anr
Cobalt
Copper
Iron anr
Lead 3.00 0.00 100.0(a) 0-10
Magnesium anr
Manganese anr
Molybdenum
Nickel
Potassium anr
Selenium anr
Silver
Sodium anr
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP28959: FA24542-1, FA24542-2, FA24542-3, FA24542-4, FA24542-5, FA24542-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(anr) Analyte not requested
(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).
_________________________________________________________________________________________________________
Page 1
46 of 47
FA24542 66.1.4
POST DIGESTATE SPIKE SUMMARY
Login Number: FA24542
Account: GRINCC - GRI (Geological Resources Inc.)
Project: Wilson Petroleum Bulk Plant; 442 S Douglas St, Wilson, NC
QC Batch ID: MP28959 Methods: SW846 6010C
Matrix Type: AQUEOUS Units: ug/l
Prep Date: 05/22/15
Sample Final FA24530-15F PS Spike Spike Spike QC
Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead 9.8 10 3 2.94 52.4 0.2 2.5 50 98.9 80-120
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Tin
Titanium
Vanadium
Zinc
Associated samples MP28959: FA24542-1, FA24542-2, FA24542-3, FA24542-4, FA24542-5, FA24542-6
Results < IDL are shown as zero for calculation purposes
(*) Outside of QC limits
(**) Corr. sample result = Raw * (sample volume / final volume)
(anr) Analyte not requested
_________________________________________________________________________________________________________
Page 1
47 of 47
FA24542 66.1.5