MO-29901_48992_CA_LAB_20230510_Lab Results

 
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

5/10/2023
Geological Resources, Inc. Joanna Alley
3502 Hayes Road Monroe, NC, 28110
Ref: Analytical Testing
Lab Report Number: 23-121-0003 Client Project Description: Handy Corner
GRI #6389
Dear Joanna Alley:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 5/1/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 51
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-121-0003
Page 2 of 51
Report Number:
Sample Summary Table
Client Project Description:
23-121-0003
Handy Corner
GRI #6389
Lab No Client Sample ID Matrix Date Collected Date Received
04/26/2023 14:14Aqueous 95155 MW-1 05/01/2023 16:51
04/26/2023 09:56Solids 95156 MW-1-5'05/01/2023 16:51
04/26/2023 10:08Solids 95157 MW-1-10'05/01/2023 16:51
04/26/2023 10:12Solids 95158 MW-1-15'05/01/2023 16:51
04/26/2023 10:19Solids 95159 MW-1-20'05/01/2023 16:51
04/26/2023 08:30Aqueous 95160 TB 05/01/2023 16:51
Page 3 of 51
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-121-0003
Report Limit
Project:Handy Corner
V 95155MW-1
0.414 05/04/2023 15:296010DLeadmg/L 0.120
38.7 05/07/2023 23:486200BBenzeneµg/L 0.180
0.929 05/07/2023 23:486200BBromodichloromethaneµg/L 0.160
J0.211 05/07/2023 23:486200Bn-Butylbenzene µg/L 0.180
J0.450 05/07/2023 23:486200Bsec-Butyl benzene µg/L 0.200
30.5 05/07/2023 23:486200BChloroformµg/L 0.220
1.61 05/07/2023 23:486200BDi-Isopropyl Ether (DIPE)µg/L 0.500
41.6 05/07/2023 23:486200BEthylbenzeneµg/L 0.170
20.0 05/07/2023 23:486200B2-Hexanone µg/L 0.380
3.07 05/07/2023 23:486200BIsopropylbenzeneµg/L 0.180
J0.241 05/07/2023 23:486200B4-Isopropyl toluene µg/L 0.089
7.98 05/07/2023 23:486200BMethyl Ethyl Ketone (MEK)µg/L 0.710
J0.969 05/07/2023 23:486200BMethyl tert-butyl ether (MTBE)µg/L 0.140
25.7 05/07/2023 23:486200B4-Methyl-2-Pentanone µg/L 0.078
J0.416 05/07/2023 23:486200BMethylene Chloride µg/L 0.330
4.91 05/07/2023 23:486200Bn-Propylbenzene µg/L 0.190
135 05/08/2023 20:366200BTolueneµg/L 2.20
48.4 05/07/2023 23:486200B1,2,4-Trimethylbenzene µg/L 0.190
26.9 05/07/2023 23:486200B1,3,5-Trimethylbenzene µg/L 0.180
131 05/08/2023 20:366200Bo-Xylene µg/L 2.10
246 05/08/2023 20:366200Bm,p-Xylene µg/L 4.20
377 05/08/2023 20:366200BXylene (Total)µg/L 2.10
235 05/01/2023 14:22CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
241 05/01/2023 14:22CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
409 05/01/2023 14:22MADEP-VPH Aliphatic C5-C8 µg/L 11.5
665 05/01/2023 14:22MADEP-VPH Aliphatic C9-C12 µg/L 25.8
241 05/01/2023 14:22MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 95156MW-1-5'
J0.013 05/02/2023 12:328260DAcetonemg/Kg - dry 0.002
J0.0009 05/02/2023 12:328260DMethyl tert-butyl ether (MTBE)mg/Kg - dry 0.0008
19.6 05/03/2023 10:50SW-DRYWT Moisture %
V 95159MW-1-20'
0.098 05/02/2023 12:598260DAcetonemg/Kg - dry 0.003
0.032 05/02/2023 12:598260DMethyl Ethyl Ketone (MEK)mg/Kg - dry 0.0008
J0.002 05/02/2023 12:598260DMethyl tert-butyl ether (MTBE)mg/Kg - dry 0.0008
J0.0009 05/02/2023 12:598260DToluenemg/Kg - dry 0.0009
Page 4 of 51
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-121-0003
Report Limit
Project:Handy Corner
V 95159MW-1-20'
J0.001 05/02/2023 12:598260D1,2,4-Trimethylbenzene mg/Kg - dry 0.0006
J0.0007 05/02/2023 12:598260D1,3,5-Trimethylbenzene mg/Kg - dry 0.0007
J0.002 05/02/2023 12:598260Do-Xylene mg/Kg - dry 0.0007
J0.002 05/02/2023 12:598260Dm,p-Xylene mg/Kg - dry 0.001
J0.005 05/02/2023 12:598260DXylene (Total)mg/Kg - dry 0.0007
23.5 05/03/2023 10:50SW-DRYWT Moisture %
Page 5 of 51

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Handy Corner Lab Report Number: 23-121-0003
Date: 5/10/2023
EDB and DBCP by Microextraction GC/ECD Method EPA-504.1 Analyte: 1,2-Dibromoethane QC Batch No: V32736/V32711
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable. Massachusetts VPH Method MADEP-VPH Sample 95156 (MW-1-5')
QC Batch No: V32693 No VPH vials received. Sample prepared from bulk container.
Sample 95159 (MW-1-20')
QC Batch No: V32693 No VPH vials received. Sample prepared from bulk container.
Sample 95156 (MW-1-5')
Analyte: 2,5-Dibromotoluene (PID) QC Batch No: V32693/V32692
Surrogate(s) exhibited a high bias in this project sample where no target analytes were detected. The high recovery(s) had no impact on the data. Batch QC samples (method blank and laboratory control samples) all showed surrogates within QC limits.
Sample 95159 (MW-1-20') Analyte: 2,5-Dibromotoluene (PID)
QC Batch No: V32693/V32692 Surrogate(s) exhibited a high bias in this project sample where no target analytes were detected. The high
recovery(s) had no impact on the data. Batch QC samples (method blank and laboratory control samples) all showed surrogates within QC limits. Metals Analysis Method 6010D Sample 95155 (MW-1) QC Batch No: V32792/V32658
The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Sample 94887 Analyte: Lead QC Batch No: V32755/V32658 LLC failed high. Sample concentration BRL. Result not affected.
Volatile Organic Compounds - GC/MS Method 8260D Analyte: 2-Butanone QC Batch No: V32695/V32694 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 6 of 51

Analyte: 2-Hexanone
QC Batch No: V32695/V32694 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Trichloroethene
QC Batch No: V32695/V32694 CCV result is above control limits but within method parameters. Results are reported but considered estimated.

Page 7 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1
95155 Matrix:
4/26/2023 14:14
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
0.414 mg/L 0.120 0.300Lead 50 05/04/23 15:29 6010DJKC
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 8 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1
95155 Matrix:
4/26/2023 14:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00 V32972 05/08/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 05/07/23 23:48 V32934MSA
38.7 µg/L 0.180 0.500Benzene 1 05/07/23 23:48 V32934MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 05/07/23 23:48 V32934MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 05/07/23 23:48 V32934MSA
0.929 µg/L 0.160 0.500Bromodichloromethane 1 05/07/23 23:48 V32934MSA
<1.50 µg/L 1.50 5.00Bromoform 1 05/07/23 23:48 V32934MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 05/07/23 23:48 V32934MSA
0.211 J µg/L 0.180 0.500n-Butylbenzene 1 05/07/23 23:48 V32934MSA
0.450 J
µg/L 0.200 0.500
sec-Butyl benzene 1 05/07/23 23:48 V32934MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 05/07/23 23:48 V32934MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 05/07/23 23:48 V32934MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 05/07/23 23:48 V32934MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 05/07/23 23:48 V32934MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 05/07/23 23:48 V32934MSA
30.5 µg/L 0.220 0.500Chloroform 1 05/07/23 23:48 V32934MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 05/07/23 23:48 V32934MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 05/07/23 23:48 V32934MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 05/07/23 23:48 V32934MSA
1.61 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 05/07/23 23:48 V32934MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 05/07/23 23:48 V32934MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 05/07/23 23:48 V32934MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 05/07/23 23:48 V32934MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 9 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1
95155 Matrix:
4/26/2023 14:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00 V32972 05/08/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 05/07/23 23:48 V32934MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 05/07/23 23:48 V32934MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 05/07/23 23:48 V32934MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 05/07/23 23:48 V32934MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 05/07/23 23:48 V32934MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 05/07/23 23:48 V32934MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 05/07/23 23:48 V32934MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 05/07/23 23:48 V32934MSA
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 05/07/23 23:48 V32934MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 05/07/23 23:48 V32934MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 05/07/23 23:48 V32934MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 05/07/23 23:48 V32934MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 05/07/23 23:48 V32934MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 05/07/23 23:48 V32934MSA
<42.0 µg/L 42.0 200Ethanol 1 05/07/23 23:48 V32934MSA
41.6 µg/L 0.170 0.500
Ethylbenzene 1 05/07/23 23:48 V32934MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 05/07/23 23:48 V32934MSA
20.0 µg/L 0.380 1.002-Hexanone 1 05/07/23 23:48 V32934MSA
3.07 µg/L 0.180 0.500Isopropylbenzene 1 05/07/23 23:48 V32934MSA
0.241 J µg/L 0.089 0.5004-Isopropyl toluene 1 05/07/23 23:48 V32934MSA
7.98 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 05/07/23 23:48 V32934MSA
0.969 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 05/07/23 23:48 V32934MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 10 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1
95155 Matrix:
4/26/2023 14:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00 V32972 05/08/23 09:00
25.7 µg/L 0.078 1.004-Methyl-2-Pentanone 1 05/07/23 23:48 V32934MSA
0.416 J µg/L 0.330 2.00Methylene Chloride 1 05/07/23 23:48 V32934MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 05/07/23 23:48 V32934MSA
4.91 µg/L 0.190 0.500n-Propylbenzene 1 05/07/23 23:48 V32934MSA
<0.220 µg/L 0.220 0.500Styrene 1 05/07/23 23:48 V32934MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 05/07/23 23:48 V32934MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 05/07/23 23:48 V32934MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 05/07/23 23:48 V32934MSA
135 µg/L 2.20 5.00
Toluene 10 05/08/23 20:36 V32973MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 05/07/23 23:48 V32934MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 05/07/23 23:48 V32934MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 05/07/23 23:48 V32934MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 05/07/23 23:48 V32934MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 05/07/23 23:48 V32934MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 05/07/23 23:48 V32934MSA
<0.270 µg/L 0.270 0.500
1,2,3-Trichloropropane 1 05/07/23 23:48 V32934MSA
48.4 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 05/07/23 23:48 V32934MSA
26.9 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 05/07/23 23:48 V32934MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 05/07/23 23:48 V32934MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 05/07/23 23:48 V32934MSA
131 µg/L 2.10 5.00o-Xylene 10 05/08/23 20:36 V32973MSA
246 µg/L 4.20 10.0m,p-Xylene 10 05/08/23 20:36 V32973MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 11 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1
95155 Matrix:
4/26/2023 14:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00 V32972 05/08/23 09:00
377 µg/L 2.10 5.00Xylene (Total)10 05/08/23 20:36 V32973
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%05/07/23 23:481 MSA V32934
Surrogate: Dibromofluoromethane 103 Limits: 70-130%05/07/23 23:481 MSA V32934
Surrogate: 1,2-Dichloroethane - d4 104 Limits: 70-130%05/07/23 23:481 MSA V32934
Surrogate: Toluene-d8 99.4 Limits: 70-130%05/07/23 23:481 MSA V32934
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%05/08/23 20:3610 MSA V32973
Surrogate: Dibromofluoromethane 106 Limits: 70-130%05/08/23 20:3610 MSA V32973
Surrogate: 1,2-Dichloroethane - d4 106 Limits: 70-130%05/08/23 20:3610 MSA V32973
Surrogate: Toluene-d8 97.2 Limits: 70-130%05/08/23 20:3610 MSA V32973
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V32711 05/03/23 10:20
<0.00338 µg/L 0.00338 0.02051,2-Dibromoethane 1 05/03/23 13:55 V32736TJW
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 12 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1
95155 Matrix:
4/26/2023 14:14
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
235 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 05/01/23 14:22
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 05/01/23 14:22
241 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 05/01/23 14:22
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V32650 05/01/23 08:00
409 µg/L 11.5 50.0Aliphatic C5-C8 1 05/01/23 14:22 V32651TBL
665 µg/L 25.8 50.0Aliphatic C9-C12 1 05/01/23 14:22 V32651TBL
241 µg/L 4.02 50.0Aromatic C9-C10 1 05/01/23 14:22 V32651TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)88.1 Limits: 70-130%05/01/23 14:221 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)100 Limits: 70-130%05/01/23 14:221 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 13 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-5'
95156 Matrix:
4/26/2023 9:56
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
19.6 %Moisture 1 05/03/23 10:50 SW-DRYWTPEB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 14 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-5'
95156 Matrix:
4/26/2023 9:56
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
0.013 J mg/Kg - dry 0.002 0.024Acetone 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.024Acrolein 1 05/02/23 12:32 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.024Acrylonitrile 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006Benzene 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006Bromobenzene 1 05/02/23 12:32 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.006Bromochloromethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Bromodichloromethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Bromoform 1 05/02/23 12:32 V32695TBL
<0.002 mg/Kg - dry 0.002 0.012
Bromomethane 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006n-Butylbenzene 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006sec-Butyl benzene 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006tert-Butyl benzene 1 05/02/23 12:32 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.006Carbon Disulfide 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Carbon Tetrachloride 1 05/02/23 12:32 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.006Chlorobenzene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006
Chlorodibromomethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.012Chloroethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Chloroform 1 05/02/23 12:32 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.012Chloromethane 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.0062-Chlorotoluene 1 05/02/23 12:32 V32695TBL
<0.0005 mg/Kg - dry 0.0005 0.0064-Chlorotoluene 1 05/02/23 12:32 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.006Di-Isopropyl Ether (DIPE)1 05/02/23 12:32 V32695TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 15 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-5'
95156 Matrix:
4/26/2023 9:56
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
<0.0005 mg/Kg - dry 0.0005 0.0121,2-Dibromo-3-Chloropropane 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,2-Dibromoethane 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006Dibromomethane 1 05/02/23 12:32 V32695TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,2-Dichlorobenzene 1 05/02/23 12:32 V32695TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,3-Dichlorobenzene 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,4-Dichlorobenzene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.012Dichlorodifluoromethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloroethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006
1,2-Dichloroethane 1 05/02/23 12:32 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,1-Dichloroethene 1 05/02/23 12:32 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.006cis-1,2-Dichloroethene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,2-Dichloroethene 1 05/02/23 12:32 V32695TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,2-Dichloropropane 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3-Dichloropropane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0062,2-Dichloropropane 1 05/02/23 12:32 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.006
1,1-Dichloropropene 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006cis-1,3-Dichloropropene 1 05/02/23 12:32 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.006trans-1,3-Dichloropropene 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006Ethylbenzene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.062Ethyl Tertiary Butyl Ether (ETBE)1 05/02/23 12:32 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.012Hexachlorobutadiene 1 05/02/23 12:32 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.012n-Hexane 1 05/02/23 12:32 V32695TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 16 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-5'
95156 Matrix:
4/26/2023 9:56
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
<0.0008 mg/Kg - dry 0.0008 0.0242-Hexanone 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006Isopropylbenzene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0064-Isopropyl toluene 1 05/02/23 12:32 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.024Methyl Ethyl Ketone (MEK)1 05/02/23 12:32 V32695TBL
0.0009 J mg/Kg - dry 0.0008 0.006Methyl tert-butyl ether (MTBE)1 05/02/23 12:32 V32695TBL
<0.018 mg/Kg - dry 0.018 0.0244-Methyl-2-Pentanone 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.012Methylene Chloride 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.012Naphthalene 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006
n-Propylbenzene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Styrene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1,2-Tetrachloroethane 1 05/02/23 12:32 V32695TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,1,2,2-Tetrachloroethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Tetrachloroethene 1 05/02/23 12:32 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.006Toluene 1 05/02/23 12:32 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.0121,2,3-Trichlorobenzene 1 05/02/23 12:32 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.012
1,2,4-Trichlorobenzene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1-Trichloroethane 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,1,2-Trichloroethane 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Trichloroethene 1 05/02/23 12:32 V32695TBL
<0.002 mg/Kg - dry 0.002 0.012Trichlorofluoromethane 1 05/02/23 12:32 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,2,3-Trichloropropane 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2,4-Trimethylbenzene 1 05/02/23 12:32 V32695TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 17 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-5'
95156 Matrix:
4/26/2023 9:56
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
<0.0007 mg/Kg - dry 0.0007 0.0061,3,5-Trimethylbenzene 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Acetate 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Chloride 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006o-Xylene 1 05/02/23 12:32 V32695TBL
<0.001 mg/Kg - dry 0.001 0.012m,p-Xylene 1 05/02/23 12:32 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006Xylene (Total)1 05/02/23 12:32 V32695
Surrogate: 4-Bromofluorobenzene 85.1 Limits: 70-130%05/02/23 12:321 TBL V32695
Surrogate: Dibromofluoromethane 101 Limits: 84-123%05/02/23 12:321 TBL V32695
Surrogate: Toluene-d8 88.5 Limits: 76-129%05/02/23 12:321 TBL V32695
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 18 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-5'
95156 Matrix:
4/26/2023 9:56
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.52 mg/Kg - dry 1.52 9.95Aliphatic C5-C8 (Adjusted)1 05/02/23 12:32
<5.67 mg/Kg - dry 5.67 9.95Aliphatics C9-C12 (Adjusted)1 05/02/23 12:32
<0.776 mg/Kg - dry 0.776 9.95Aromatic C9-C10 (Adjusted)100 05/02/23 17:08
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V32692 05/02/23 08:00
<1.52 mg/Kg - dry 1.52 9.95Aliphatic C5-C8 100 05/02/23 17:08 V32693TBL
<5.67 mg/Kg - dry 5.67 9.95Aliphatic C9-C12 100 05/02/23 17:08 V32693TBL
<0.776 mg/Kg - dry 0.776 9.95Aromatic C9-C10 100 05/02/23 17:08 V32693TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)94.4 Limits: 70-130%05/02/23 17:08100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)145 *Limits: 70-130%05/02/23 17:08100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 19 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-10'
95157 Matrix:
4/26/2023 10:08
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V32692 05/02/23 08:00
<1.22 mg/Kg 1.22 8.00Aliphatic C5-C8 100 05/02/23 17:31 V32693TBL
<4.56 mg/Kg 4.56 8.00Aliphatic C9-C12 100 05/02/23 17:31 V32693TBL
<0.624 mg/Kg 0.624 8.00Aromatic C9-C10 100 05/02/23 17:31 V32693TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)91.2 Limits: 70-130%05/02/23 17:31100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)92.2 Limits: 70-130%05/02/23 17:31100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 20 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-15'
95158 Matrix:
4/26/2023 10:12
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V32692 05/02/23 08:00
<1.22 mg/Kg 1.22 8.00Aliphatic C5-C8 100 05/02/23 17:55 V32693TBL
<4.56 mg/Kg 4.56 8.00Aliphatic C9-C12 100 05/02/23 17:55 V32693TBL
<0.624 mg/Kg 0.624 8.00Aromatic C9-C10 100 05/02/23 17:55 V32693TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)98.1 Limits: 70-130%05/02/23 17:55100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)100 Limits: 70-130%05/02/23 17:55100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 21 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-20'
95159 Matrix:
4/26/2023 10:19
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
23.5 %Moisture 1 05/03/23 10:50 SW-DRYWTPEB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 22 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-20'
95159 Matrix:
4/26/2023 10:19
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
0.098 mg/Kg - dry 0.003 0.026Acetone 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.026Acrolein 1 05/02/23 12:59 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.026Acrylonitrile 1 05/02/23 12:59 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.006Benzene 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006Bromobenzene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Bromochloromethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Bromodichloromethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Bromoform 1 05/02/23 12:59 V32695TBL
<0.002 mg/Kg - dry 0.002 0.013
Bromomethane 1 05/02/23 12:59 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006n-Butylbenzene 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006sec-Butyl benzene 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006tert-Butyl benzene 1 05/02/23 12:59 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.006Carbon Disulfide 1 05/02/23 12:59 V32695TBL
<0.002 mg/Kg - dry 0.002 0.006Carbon Tetrachloride 1 05/02/23 12:59 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.006Chlorobenzene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006
Chlorodibromomethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.013Chloroethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Chloroform 1 05/02/23 12:59 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.013Chloromethane 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.0062-Chlorotoluene 1 05/02/23 12:59 V32695TBL
<0.0005 mg/Kg - dry 0.0005 0.0064-Chlorotoluene 1 05/02/23 12:59 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.006Di-Isopropyl Ether (DIPE)1 05/02/23 12:59 V32695TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 23 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-20'
95159 Matrix:
4/26/2023 10:19
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
<0.0006 mg/Kg - dry 0.0006 0.0131,2-Dibromo-3-Chloropropane 1 05/02/23 12:59 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,2-Dibromoethane 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006Dibromomethane 1 05/02/23 12:59 V32695TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,2-Dichlorobenzene 1 05/02/23 12:59 V32695TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,3-Dichlorobenzene 1 05/02/23 12:59 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,4-Dichlorobenzene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.013Dichlorodifluoromethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloroethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006
1,2-Dichloroethane 1 05/02/23 12:59 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.0061,1-Dichloroethene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006cis-1,2-Dichloroethene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,2-Dichloroethene 1 05/02/23 12:59 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2-Dichloropropane 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3-Dichloropropane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0062,2-Dichloropropane 1 05/02/23 12:59 V32695TBL
<0.0010 mg/Kg - dry 0.0010 0.006
1,1-Dichloropropene 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006cis-1,3-Dichloropropene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,3-Dichloropropene 1 05/02/23 12:59 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.006Ethylbenzene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.065Ethyl Tertiary Butyl Ether (ETBE)1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.013Hexachlorobutadiene 1 05/02/23 12:59 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.013n-Hexane 1 05/02/23 12:59 V32695TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 24 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-20'
95159 Matrix:
4/26/2023 10:19
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
<0.0008 mg/Kg - dry 0.0008 0.0262-Hexanone 1 05/02/23 12:59 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.006Isopropylbenzene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0064-Isopropyl toluene 1 05/02/23 12:59 V32695TBL
0.032 mg/Kg - dry 0.0008 0.026Methyl Ethyl Ketone (MEK)1 05/02/23 12:59 V32695TBL
0.002 J mg/Kg - dry 0.0008 0.006Methyl tert-butyl ether (MTBE)1 05/02/23 12:59 V32695TBL
<0.019 mg/Kg - dry 0.019 0.0264-Methyl-2-Pentanone 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.013Methylene Chloride 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.013Naphthalene 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.006
n-Propylbenzene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Styrene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1,2-Tetrachloroethane 1 05/02/23 12:59 V32695TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,1,2,2-Tetrachloroethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Tetrachloroethene 1 05/02/23 12:59 V32695TBL
0.0009 J mg/Kg - dry 0.0009 0.006Toluene 1 05/02/23 12:59 V32695TBL
<0.0007 mg/Kg - dry 0.0007 0.0131,2,3-Trichlorobenzene 1 05/02/23 12:59 V32695TBL
<0.0008 mg/Kg - dry 0.0008 0.013
1,2,4-Trichlorobenzene 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1-Trichloroethane 1 05/02/23 12:59 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,1,2-Trichloroethane 1 05/02/23 12:59 V32695TBL
<0.001 mg/Kg - dry 0.001 0.006Trichloroethene 1 05/02/23 12:59 V32695TBL
<0.002 mg/Kg - dry 0.002 0.013Trichlorofluoromethane 1 05/02/23 12:59 V32695TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,2,3-Trichloropropane 1 05/02/23 12:59 V32695TBL
0.001 J mg/Kg - dry 0.0006 0.0061,2,4-Trimethylbenzene 1 05/02/23 12:59 V32695TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 25 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-20'
95159 Matrix:
4/26/2023 10:19
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V32694 05/02/23 08:00
0.0007 J mg/Kg - dry 0.0007 0.0061,3,5-Trimethylbenzene 1 05/02/23 12:59 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.013Vinyl Acetate 1 05/02/23 12:59 V32695TBL
<0.0006 mg/Kg - dry 0.0006 0.013Vinyl Chloride 1 05/02/23 12:59 V32695TBL
0.002 J mg/Kg - dry 0.0007 0.006o-Xylene 1 05/02/23 12:59 V32695TBL
0.002 J mg/Kg - dry 0.001 0.013m,p-Xylene 1 05/02/23 12:59 V32695TBL
0.005 J mg/Kg - dry 0.0007 0.006Xylene (Total)1 05/02/23 12:59 V32695KCC
Surrogate: 4-Bromofluorobenzene 96.5 Limits: 70-130%05/02/23 12:591 TBL V32695
Surrogate: Dibromofluoromethane 100 Limits: 84-123%05/02/23 12:591 TBL V32695
Surrogate: Toluene-d8 87.8 Limits: 76-129%05/02/23 12:591 TBL V32695
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 26 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:MW-1-20'
95159 Matrix:
4/26/2023 10:19
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.59 mg/Kg - dry 1.59 10.5Aliphatic C5-C8 (Adjusted)100 05/02/23 18:18
<5.96 mg/Kg - dry 5.96 10.5Aliphatics C9-C12 (Adjusted)100 05/02/23 18:18
<0.815 mg/Kg - dry 0.815 10.5Aromatic C9-C10 (Adjusted)100 05/02/23 18:18
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V32692 05/02/23 08:00
<1.59 mg/Kg - dry 1.59 10.5Aliphatic C5-C8 100 05/02/23 18:18 V32693TBL
<5.96 mg/Kg - dry 5.96 10.5Aliphatic C9-C12 100 05/02/23 18:18 V32693TBL
<0.815 mg/Kg - dry 0.815 10.5Aromatic C9-C10 100 05/02/23 18:18 V32693TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)95.3 Limits: 70-130%05/02/23 18:18100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)134 *Limits: 70-130%05/02/23 18:18100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 27 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:TB
95160 Matrix:
4/26/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.500Benzene 1 05/07/23 20:37 V32934MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 05/07/23 20:37 V32934MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 05/07/23 20:37 V32934MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 05/07/23 20:37 V32934MSA
<1.50 µg/L 1.50 5.00Bromoform 1 05/07/23 20:37 V32934MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 05/07/23 20:37 V32934MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 05/07/23 20:37 V32934MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 05/07/23 20:37 V32934MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 05/07/23 20:37 V32934MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 05/07/23 20:37 V32934MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 05/07/23 20:37 V32934MSA
<0.220 µg/L 0.220 0.500Chloroform 1 05/07/23 20:37 V32934MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 05/07/23 20:37 V32934MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 05/07/23 20:37 V32934MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 05/07/23 20:37 V32934MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 05/07/23 20:37 V32934MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 05/07/23 20:37 V32934MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 05/07/23 20:37 V32934MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 05/07/23 20:37 V32934MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 28 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:TB
95160 Matrix:
4/26/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 05/07/23 20:37 V32934MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 05/07/23 20:37 V32934MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 05/07/23 20:37 V32934MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 05/07/23 20:37 V32934MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 05/07/23 20:37 V32934MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 05/07/23 20:37 V32934MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 05/07/23 20:37 V32934MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 05/07/23 20:37 V32934MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 05/07/23 20:37 V32934MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 05/07/23 20:37 V32934MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 05/07/23 20:37 V32934MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 05/07/23 20:37 V32934MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 05/07/23 20:37 V32934MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 05/07/23 20:37 V32934MSA
<42.0 µg/L 42.0 200
Ethanol 1 05/07/23 20:37 V32934MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 05/07/23 20:37 V32934MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 05/07/23 20:37 V32934MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 05/07/23 20:37 V32934MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 05/07/23 20:37 V32934MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 05/07/23 20:37 V32934MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 29 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:TB
95160 Matrix:
4/26/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 05/07/23 20:37 V32934MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 05/07/23 20:37 V32934MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 05/07/23 20:37 V32934MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 05/07/23 20:37 V32934MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 05/07/23 20:37 V32934MSA
<0.220 µg/L 0.220 0.500Styrene 1 05/07/23 20:37 V32934MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 05/07/23 20:37 V32934MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 05/07/23 20:37 V32934MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 05/07/23 20:37 V32934MSA
<0.220 µg/L 0.220 0.500Toluene 1 05/07/23 20:37 V32934MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 05/07/23 20:37 V32934MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 05/07/23 20:37 V32934MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 05/07/23 20:37 V32934MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 05/07/23 20:37 V32934MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 05/07/23 20:37 V32934MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 05/07/23 20:37 V32934MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 05/07/23 20:37 V32934MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 05/07/23 20:37 V32934MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 05/07/23 20:37 V32934MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 05/07/23 20:37 V32934MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 30 of 51
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-121-0003
00087
Geological Resources, Inc.
3502 Hayes Road
Joanna Alley
Monroe
Danyale Love
Project Manager
GRI #6389 Received : 05/01/2023
Handy Corner
Report Date : 05/10/2023
Sample ID :
Lab No :
Sampled:TB
95160 Matrix:
4/26/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32933 05/07/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 05/07/23 20:37 V32934MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 05/07/23 20:37 V32934
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%05/07/23 20:371 MSA V32934
Surrogate: Dibromofluoromethane 103 Limits: 70-130%05/07/23 20:371 MSA V32934
Surrogate: 1,2-Dichloroethane - d4 103 Limits: 70-130%05/07/23 20:371 MSA V32934
Surrogate: Toluene-d8 96.8 Limits: 70-130%05/07/23 20:371 MSA V32934
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 31 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Metals Analysis
6010D
V32755QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V32658
Associated Lab Samples: 95155
LRB-V32658 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
05/03/23 14:160.0060.002<0.002mg/LLead
LCS-V32658Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1050.1050.100mg/LLead 80-120
V 94887-MS-V32658 V 94887-MSD-V32658Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.103 1030.1080.1000.100< 0.002mg/LLead 108 75-125 4.7 20.0
V 94887-PDS-V32658Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
05/03/23 16:441010.252mg/LLead
Page 1 of 18Date:05/10/2023 04:30 PM
Page 32 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32934QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32933
Associated Lab Samples: 95155, 95160
LRB-V32933 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/07/23 19:4310.01.80<1.80µg/LAcetone
05/07/23 19:430.5000.180<0.180µg/LBenzene
05/07/23 19:430.5000.210<0.210µg/LBromobenzene
05/07/23 19:431.000.420<0.420µg/LBromochloromethane
05/07/23 19:430.5000.160<0.160µg/LBromodichloromethane
05/07/23 19:435.001.50<1.50µg/LBromoform
05/07/23 19:431.000.280<0.280µg/LBromomethane
05/07/23 19:430.5000.180<0.180µg/Ln-Butylbenzene
05/07/23 19:430.5000.200<0.200µg/Lsec-Butyl benzene
05/07/23 19:432.000.920<0.920µg/Ltert-Butyl benzene
05/07/23 19:430.5000.180<0.180µg/LCarbon Tetrachloride
05/07/23 19:430.5000.190<0.190µg/LChlorobenzene
05/07/23 19:430.5000.190<0.190µg/LChlorodibromomethane
05/07/23 19:431.000.430<0.430µg/LChloroethane
05/07/23 19:430.5000.220<0.220µg/LChloroform
05/07/23 19:430.5000.220<0.220µg/LChloromethane
05/07/23 19:430.5000.200<0.200µg/L2-Chlorotoluene
05/07/23 19:430.5000.200<0.200µg/L4-Chlorotoluene
05/07/23 19:430.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
05/07/23 19:432.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
05/07/23 19:430.5000.200<0.200µg/L1,2-Dibromoethane
05/07/23 19:430.5000.230<0.230µg/LDibromomethane
05/07/23 19:430.5000.220<0.220µg/L1,2-Dichlorobenzene
05/07/23 19:430.5000.190<0.190µg/L1,3-Dichlorobenzene
05/07/23 19:430.5000.210<0.210µg/L1,4-Dichlorobenzene
05/07/23 19:435.001.20<1.20µg/LDichlorodifluoromethane
05/07/23 19:430.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 18Date:05/10/2023 04:30 PM
Page 33 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32934QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32933
Associated Lab Samples: 95155, 95160
LRB-V32933 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/07/23 19:430.5000.150<0.150µg/L1,2-Dichloroethane
05/07/23 19:430.5000.150<0.150µg/L1,1-Dichloroethene
05/07/23 19:430.5000.200<0.200µg/Lcis-1,2-Dichloroethene
05/07/23 19:430.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
05/07/23 19:430.5000.190<0.190µg/L1,2-Dichloropropane
05/07/23 19:430.5000.130<0.130µg/L1,3-Dichloropropane
05/07/23 19:432.000.210<0.210µg/L2,2-Dichloropropane
05/07/23 19:430.5000.200<0.200µg/L1,1-Dichloropropene
05/07/23 19:430.5000.210<0.210µg/Lcis-1,3-Dichloropropene
05/07/23 19:430.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
05/07/23 19:4320042.0<42.0µg/LEthanol
05/07/23 19:430.5000.170<0.170µg/LEthylbenzene
05/07/23 19:433.000.350<0.350µg/LHexachlorobutadiene
05/07/23 19:431.000.380<0.380µg/L2-Hexanone
05/07/23 19:430.5000.180<0.180µg/LIsopropylbenzene
05/07/23 19:430.5000.089<0.089µg/L4-Isopropyl toluene
05/07/23 19:435.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
05/07/23 19:431.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
05/07/23 19:431.000.078<0.078µg/L4-Methyl-2-Pentanone
05/07/23 19:432.000.330<0.330µg/LMethylene Chloride
05/07/23 19:431.000.470<0.470µg/LNaphthalene
05/07/23 19:430.5000.190<0.190µg/Ln-Propylbenzene
05/07/23 19:430.5000.220<0.220µg/LStyrene
05/07/23 19:430.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
05/07/23 19:430.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
05/07/23 19:430.5000.220<0.220µg/LTetrachloroethene
05/07/23 19:430.5000.220<0.220µg/LToluene
Page 3 of 18Date:05/10/2023 04:30 PM
Page 34 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32934QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32933
Associated Lab Samples: 95155, 95160
LRB-V32933 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/07/23 19:430.5000.380<0.380µg/L1,2,3-Trichlorobenzene
05/07/23 19:430.5000.310<0.310µg/L1,2,4-Trichlorobenzene
05/07/23 19:430.5000.160<0.160µg/L1,1,1-Trichloroethane
05/07/23 19:430.5000.096<0.096µg/L1,1,2-Trichloroethane
05/07/23 19:430.5000.180<0.180µg/LTrichloroethene
05/07/23 19:430.5000.180<0.180µg/LTrichlorofluoromethane
05/07/23 19:430.5000.270<0.270µg/L1,2,3-Trichloropropane
05/07/23 19:430.5000.190<0.190µg/L1,2,4-Trimethylbenzene
05/07/23 19:430.5000.180<0.180µg/L1,3,5-Trimethylbenzene
05/07/23 19:435.001.00<1.00µg/LVinyl Acetate
05/07/23 19:430.5000.170<0.170µg/LVinyl Chloride
05/07/23 19:430.5000.210<0.210µg/Lo-Xylene
05/07/23 19:431.000.420<0.420µg/Lm,p-Xylene
05/07/23 19:434-Bromofluorobenzene (S)101 70-130
05/07/23 19:43Dibromofluoromethane (S)102 70-130
05/07/23 19:431,2-Dichloroethane - d4 (S)105 70-130
05/07/23 19:43Toluene-d8 (S)97.0 70-130
LCS-V32933 LCSD-V32933Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
36.1 90.295.538.240.0µg/LAcetone 40-160 5.6 20.0
19.4 97.010320.620.0µg/LBenzene 70-130 6.0 20.0
19.9 99.510320.620.0µg/LBromobenzene 70-130 3.4 20.0
20.7 10410721.420.0µg/LBromochloromethane 70-130 3.3 20.0
20.9 10511021.920.0µg/LBromodichloromethane 70-130 4.6 20.0
Page 4 of 18Date:05/10/2023 04:30 PM
Page 35 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32934QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32933
LCS-V32933 LCSD-V32933Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.6 10310520.920.0µg/LBromoform 70-130 1.4 20.0
19.2 96.098.019.620.0µg/LBromomethane 60-140 2.0 20.0
18.3 91.597.519.520.0µg/Ln-Butylbenzene 70-130 6.3 20.0
19.0 95.010020.020.0µg/Lsec-Butyl benzene 70-130 5.1 20.0
19.6 98.010320.520.0µg/Ltert-Butyl benzene 70-130 4.4 20.0
22.1 11111623.220.0µg/LCarbon Tetrachloride 70-130 4.8 20.0
19.4 97.010721.320.0µg/LChlorobenzene 70-130 9.3 20.0
21.6 10811322.620.0µg/LChlorodibromomethane 70-130 4.5 20.0
20.7 10411021.920.0µg/LChloroethane 60-140 5.6 20.0
21.3 10711222.420.0µg/LChloroform 70-130 5.0 20.0
18.4 92.097.019.420.0µg/LChloromethane 60-140 5.2 20.0
19.1 95.510220.320.0µg/L2-Chlorotoluene 70-130 6.0 20.0
19.6 98.010420.720.0µg/L4-Chlorotoluene 70-130 5.4 20.0
19.3 96.599.019.820.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.5 20.0
20.4 10210420.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.9 20.0
20.9 10510320.520.0µg/L1,2-Dibromoethane 70-130 1.9 20.0
20.3 10210020.020.0µg/LDibromomethane 70-130 1.4 20.0
19.7 98.510220.420.0µg/L1,2-Dichlorobenzene 70-130 3.4 20.0
20.2 10110320.520.0µg/L1,3-Dichlorobenzene 70-130 1.4 20.0
19.4 97.010220.420.0µg/L1,4-Dichlorobenzene 70-130 5.0 20.0
21.5 10810921.720.0µg/LDichlorodifluoromethane 60-140 0.9 20.0
20.2 10110821.620.0µg/L1,1-Dichloroethane 70-130 6.6 20.0
20.6 10311022.020.0µg/L1,2-Dichloroethane 70-130 6.5 20.0
20.6 10311021.920.0µg/L1,1-Dichloroethene 70-130 6.1 20.0
19.7 98.510721.420.0µg/Lcis-1,2-Dichloroethene 70-130 8.2 20.0
21.3 10711322.620.0µg/Ltrans-1,2-Dichloroethene 70-130 5.9 20.0
Page 5 of 18Date:05/10/2023 04:30 PM
Page 36 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32934QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32933
LCS-V32933 LCSD-V32933Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.1 95.510621.120.0µg/L1,2-Dichloropropane 70-130 9.9 20.0
19.3 96.598.019.620.0µg/L1,3-Dichloropropane 70-130 1.5 20.0
22.4 11211322.520.0µg/L2,2-Dichloropropane 70-130 0.4 20.0
21.1 10611723.420.0µg/L1,1-Dichloropropene 70-130 10.3 20.0
19.8 99.010721.320.0µg/Lcis-1,3-Dichloropropene 70-130 7.2 20.0
20.8 10410821.620.0µg/Ltrans-1,3-Dichloropropene 70-130 3.7 20.0
543 10993.2466500µg/LEthanol 60-140 15.2 20.0
19.7 98.510320.620.0µg/LEthylbenzene 70-130 4.4 20.0
20.8 10410821.520.0µg/LHexachlorobutadiene 70-130 3.3 20.0
17.6 88.091.018.220.0µg/L2-Hexanone 60-140 3.3 20.0
20.2 10110521.020.0µg/LIsopropylbenzene 70-130 3.8 20.0
20.1 10110520.920.0µg/L4-Isopropyl toluene 70-130 3.9 20.0
17.1 85.574.014.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 14.4 20.0
20.1 10110721.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.2 20.0
17.4 87.090.018.020.0µg/L4-Methyl-2-Pentanone 60-140 3.3 20.0
20.5 10310320.620.0µg/LMethylene Chloride 70-130 0.4 20.0
15.8 79.079.515.920.0µg/LNaphthalene 70-130 0.6 20.0
19.1 95.597.519.520.0µg/Ln-Propylbenzene 70-130 2.0 20.0
20.4 10210220.420.0µg/LStyrene 70-130 0.0 20.0
20.9 10511222.320.0µg/L1,1,1,2-Tetrachloroethane 70-130 6.4 20.0
18.6 93.094.518.920.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.6 20.0
20.8 10410721.420.0µg/LTetrachloroethene 70-130 2.8 20.0
20.1 10110420.820.0µg/LToluene 70-130 3.4 20.0
21.4 10710220.320.0µg/L1,2,3-Trichlorobenzene 70-130 5.2 20.0
19.0 95.097.019.420.0µg/L1,2,4-Trichlorobenzene 70-130 2.0 20.0
22.0 11011322.620.0µg/L1,1,1-Trichloroethane 70-130 2.6 20.0
Page 6 of 18Date:05/10/2023 04:30 PM
Page 37 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32934QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32933
LCS-V32933 LCSD-V32933Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.1 10110320.520.0µg/L1,1,2-Trichloroethane 70-130 1.9 20.0
21.6 10811021.920.0µg/LTrichloroethene 70-130 1.3 20.0
22.1 11111322.620.0µg/LTrichlorofluoromethane 60-140 2.2 20.0
20.3 10299.519.920.0µg/L1,2,3-Trichloropropane 70-130 1.9 20.0
19.9 99.510120.220.0µg/L1,2,4-Trimethylbenzene 70-130 1.4 20.0
20.0 10010520.920.0µg/L1,3,5-Trimethylbenzene 70-130 4.4 20.0
19.8 99.093.018.620.0µg/LVinyl Acetate 60-140 6.2 20.0
20.8 10411222.320.0µg/LVinyl Chloride 60-140 6.9 20.0
19.8 99.010420.720.0µg/Lo-Xylene 70-130 4.4 20.0
41.2 10310843.040.0µg/Lm,p-Xylene 70-130 4.2 20.0
97.699.04-Bromofluorobenzene (S)70-130
102104Dibromofluoromethane (S)70-130
1051061,2-Dichloroethane - d4 (S)70-130
97.898.0Toluene-d8 (S)70-130
Page 7 of 18Date:05/10/2023 04:30 PM
Page 38 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32973QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32972
Associated Lab Samples: 95155
LRB-V32972 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/08/23 15:090.5000.220<0.220µg/LToluene
05/08/23 15:090.5000.210<0.210µg/Lo-Xylene
05/08/23 15:091.000.420<0.420µg/Lm,p-Xylene
05/08/23 15:094-Bromofluorobenzene (S)98.2 70-130
05/08/23 15:09Dibromofluoromethane (S)104 70-130
05/08/23 15:091,2-Dichloroethane - d4 (S)106 70-130
05/08/23 15:09Toluene-d8 (S)96.2 70-130
LCS-V32972 LCSD-V32972Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.9 99.510220.320.0µg/LToluene 70-130 1.9 20.0
20.3 10210120.220.0µg/Lo-Xylene 70-130 0.4 20.0
41.1 10310642.240.0µg/Lm,p-Xylene 70-130 2.6 20.0
99.099.44-Bromofluorobenzene (S)70-130
101103Dibromofluoromethane (S)70-130
1071051,2-Dichloroethane - d4 (S)70-130
96.896.2Toluene-d8 (S)70-130
Page 8 of 18Date:05/10/2023 04:30 PM
Page 39 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V32695QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V32694
Associated Lab Samples: 95156, 95159
LRB-V32694 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/02/23 11:110.0200.002<0.002mg/KgAcetone
05/02/23 11:110.0200.001<0.001mg/KgAcrolein
05/02/23 11:110.0200.0008<0.0008mg/KgAcrylonitrile
05/02/23 11:110.0050.0006<0.0006mg/KgBenzene
05/02/23 11:110.0050.0005<0.0005mg/KgBromobenzene
05/02/23 11:110.0050.0008<0.0008mg/KgBromochloromethane
05/02/23 11:110.0050.001<0.001mg/KgBromodichloromethane
05/02/23 11:110.0050.001<0.001mg/KgBromoform
05/02/23 11:110.0100.001<0.001mg/KgBromomethane
05/02/23 11:110.0050.0005<0.0005mg/Kgn-Butylbenzene
05/02/23 11:110.0050.0006<0.0006mg/Kgsec-Butyl benzene
05/02/23 11:110.0050.0005<0.0005mg/Kgtert-Butyl benzene
05/02/23 11:110.0050.0006<0.0006mg/KgCarbon Disulfide
05/02/23 11:110.0050.001<0.001mg/KgCarbon Tetrachloride
05/02/23 11:110.0050.0007<0.0007mg/KgChlorobenzene
05/02/23 11:110.0050.0009<0.0009mg/KgChlorodibromomethane
05/02/23 11:110.0100.0009<0.0009mg/KgChloroethane
05/02/23 11:110.0050.001<0.001mg/KgChloroform
05/02/23 11:110.0100.0006<0.0006mg/KgChloromethane
05/02/23 11:110.0050.0005<0.0005mg/Kg2-Chlorotoluene
05/02/23 11:110.0050.0004<0.0004mg/Kg4-Chlorotoluene
05/02/23 11:110.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
05/02/23 11:110.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
05/02/23 11:110.0050.0006<0.0006mg/Kg1,2-Dibromoethane
05/02/23 11:110.0050.0006<0.0006mg/KgDibromomethane
05/02/23 11:110.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
05/02/23 11:110.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 9 of 18Date:05/10/2023 04:30 PM
Page 40 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V32695QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V32694
Associated Lab Samples: 95156, 95159
LRB-V32694 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/02/23 11:110.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
05/02/23 11:110.0100.001<0.001mg/KgDichlorodifluoromethane
05/02/23 11:110.0050.0008<0.0008mg/Kg1,1-Dichloroethane
05/02/23 11:110.0050.001<0.001mg/Kg1,2-Dichloroethane
05/02/23 11:110.0050.0007<0.0007mg/Kg1,1-Dichloroethene
05/02/23 11:110.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
05/02/23 11:110.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
05/02/23 11:110.0050.0004<0.0004mg/Kg1,2-Dichloropropane
05/02/23 11:110.0050.0006<0.0006mg/Kg1,3-Dichloropropane
05/02/23 11:110.0050.001<0.001mg/Kg2,2-Dichloropropane
05/02/23 11:110.0050.0008<0.0008mg/Kg1,1-Dichloropropene
05/02/23 11:110.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
05/02/23 11:110.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
05/02/23 11:110.0050.0006<0.0006mg/KgEthylbenzene
05/02/23 11:110.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
05/02/23 11:110.0100.0008<0.0008mg/KgHexachlorobutadiene
05/02/23 11:110.0100.0007<0.0007mg/Kgn-Hexane
05/02/23 11:110.0200.0006<0.0006mg/Kg2-Hexanone
05/02/23 11:110.0050.0005<0.0005mg/KgIsopropylbenzene
05/02/23 11:110.0050.001<0.001mg/Kg4-Isopropyl toluene
05/02/23 11:110.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
05/02/23 11:110.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
05/02/23 11:110.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
05/02/23 11:110.0100.001<0.001mg/KgMethylene Chloride
05/02/23 11:110.0100.0010<0.0010mg/KgNaphthalene
05/02/23 11:110.0050.0005<0.0005mg/Kgn-Propylbenzene
05/02/23 11:110.0050.001<0.001mg/KgStyrene
Page 10 of 18Date:05/10/2023 04:30 PM
Page 41 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V32695QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V32694
Associated Lab Samples: 95156, 95159
LRB-V32694 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/02/23 11:110.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
05/02/23 11:110.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
05/02/23 11:110.0050.0009<0.0009mg/KgTetrachloroethene
05/02/23 11:110.0050.0007<0.0007mg/KgToluene
05/02/23 11:110.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
05/02/23 11:110.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
05/02/23 11:110.0050.001<0.001mg/Kg1,1,1-Trichloroethane
05/02/23 11:110.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
05/02/23 11:110.0050.0009<0.0009mg/KgTrichloroethene
05/02/23 11:110.0100.002<0.002mg/KgTrichlorofluoromethane
05/02/23 11:110.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
05/02/23 11:110.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
05/02/23 11:110.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
05/02/23 11:110.0100.0005<0.0005mg/KgVinyl Acetate
05/02/23 11:110.0100.0005<0.0005mg/KgVinyl Chloride
05/02/23 11:110.0050.0005<0.0005mg/Kgo-Xylene
05/02/23 11:110.0100.001<0.001mg/Kgm,p-Xylene
05/02/23 11:114-Bromofluorobenzene (S)97.8 70-130
05/02/23 11:11Dibromofluoromethane (S)96.6 84-123
05/02/23 11:11Toluene-d8 (S)90.2 76-129
LCS-V32694 LCSD-V32694Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.105 1051200.1200.100mg/KgAcetone 29-198 13.3 20
0.088 88.090.30.0900.100mg/KgAcrolein 70-130 2.5 20
Page 11 of 18Date:05/10/2023 04:30 PM
Page 42 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V32695QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V32694
LCS-V32694 LCSD-V32694Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.101 10197.20.0970.100mg/KgAcrylonitrile 65-134 3.8 20
0.055 1101110.0550.050mg/KgBenzene 74-127 0.7 20
0.044 88.692.80.0460.050mg/KgBromobenzene 73-125 4.6 20
0.059 1201190.0590.050mg/KgBromochloromethane 72-134 1.0 20
0.057 1161160.0580.050mg/KgBromodichloromethane 75-122 0.5 20
0.052 1051060.0530.050mg/KgBromoform 66-135 1.5 20
0.056 11395.00.0470.050mg/KgBromomethane 20-180 17.1 20
0.045 90.695.20.0470.050mg/Kgn-Butylbenzene 65-135 4.9 20
0.044 89.493.40.0460.050mg/Kgsec-Butyl benzene 66-131 4.3 20
0.044 89.293.00.0460.050mg/Kgtert-Butyl benzene 67-132 4.1 20
0.052 1061110.0550.050mg/KgCarbon Disulfide 61-129 4.7 20
0.058 1161180.0590.050mg/KgCarbon Tetrachloride 64-143 1.8 20
0.050 1021040.0520.050mg/KgChlorobenzene 74-118 2.5 20
0.051 1041040.0520.050mg/KgChlorodibromomethane 73-122 0.5 20
0.049 99.81080.0540.050mg/KgChloroethane 33-149 8.2 20
0.056 1141170.0580.050mg/KgChloroform 73-127 2.9 20
0.052 1041040.0520.050mg/KgChloromethane 45-143 0.3 20
0.044 89.893.20.0460.050mg/Kg2-Chlorotoluene 67-124 3.7 20
0.044 89.893.20.0460.050mg/Kg4-Chlorotoluene 71-126 3.7 20
0.054 1091100.0540.050mg/KgDi-Isopropyl Ether (DIPE)59-159 0.7 20
0.050 1011020.0510.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 1.1 20
0.054 1081050.0520.050mg/Kg1,2-Dibromoethane 70-132 2.6 20
0.055 1111170.0580.050mg/KgDibromomethane 74-133 4.5 20
0.046 92.497.40.0480.050mg/Kg1,2-Dichlorobenzene 72-123 5.2 20
0.046 93.495.80.0470.050mg/Kg1,3-Dichlorobenzene 71-120 2.5 20
0.045 91.095.00.0470.050mg/Kg1,4-Dichlorobenzene 71-123 4.3 20
Page 12 of 18Date:05/10/2023 04:30 PM
Page 43 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V32695QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V32694
LCS-V32694 LCSD-V32694Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.050 1001040.0510.050mg/KgDichlorodifluoromethane 26-146 3.5 20
0.053 1071130.0560.050mg/Kg1,1-Dichloroethane 74-127 4.7 20
0.053 1061080.0530.050mg/Kg1,2-Dichloroethane 68-128 1.1 20
0.052 1061120.0550.050mg/Kg1,1-Dichloroethene 67-149 5.5 20
0.054 1081090.0540.050mg/Kgcis-1,2-Dichloroethene 76-134 0.9 20
0.052 1061110.0550.050mg/Kgtrans-1,2-Dichloroethene 73-132 4.6 20
0.053 1071130.0560.050mg/Kg1,2-Dichloropropane 73-130 5.2 20
0.051 1021030.0510.050mg/Kg1,3-Dichloropropane 75-124 0.3 20
0.055 1101140.0570.050mg/Kg2,2-Dichloropropane 50-142 3.3 20
0.055 1101160.0580.050mg/Kg1,1-Dichloropropene 71-130 5.4 20
0.057 1151150.0570.050mg/Kgcis-1,3-Dichloropropene 71-125 0.3 20
0.059 1181190.0590.050mg/Kgtrans-1,3-Dichloropropene 68-123 0.5 20
0.048 96.898.60.0490.050mg/KgEthylbenzene 74-128 1.8 20
0.107 1071080.1080.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.9 20
0.047 94.81010.0500.050mg/KgHexachlorobutadiene 64-125 6.1 20
0.055 1111250.0620.050mg/Kgn-Hexane 70-130 11.6 20
0.049 98.41220.0610.050mg/Kg2-Hexanone 61-157 21.4*20
0.045 90.494.80.0470.050mg/KgIsopropylbenzene 68-126 4.7 20
0.045 90.695.40.0470.050mg/Kg4-Isopropyl toluene 68-129 5.1 20
0.040 80.499.80.0490.050mg/KgMethyl Ethyl Ketone (MEK)63-149 21.5*20
0.055 1101100.0540.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.3 20
0.058 1161200.0600.050mg/Kg4-Methyl-2-Pentanone 57-162 3.2 20
0.045 91.892.00.0460.050mg/KgMethylene Chloride 74-129 0.2 20
0.046 93.499.20.0490.050mg/KgNaphthalene 57-157 6.0 20
0.044 89.492.40.0460.050mg/Kgn-Propylbenzene 67-130 3.3 20
0.051 1031040.0520.050mg/KgStyrene 77-121 1.3 20
Page 13 of 18* QC Fail Date:05/10/2023 04:30 PM
Page 44 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V32695QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V32694
LCS-V32694 LCSD-V32694Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.050 1011010.0500.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 0.0 20
0.045 90.093.00.0460.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 3.2 20
0.056 1121160.0570.050mg/KgTetrachloroethene 68-130 3.3 20
0.053 1081080.0540.050mg/KgToluene 71-129 0.7 20
0.047 95.01050.0520.050mg/Kg1,2,3-Trichlorobenzene 68-130 10.1 20
0.049 99.41060.0520.050mg/Kg1,2,4-Trichlorobenzene 66-125 6.0 20
0.055 1101140.0560.050mg/Kg1,1,1-Trichloroethane 67-131 2.8 20
0.051 1031050.0520.050mg/Kg1,1,2-Trichloroethane 70-133 1.7 20
0.055 1121160.0580.050mg/KgTrichloroethene 75-133 4.2 20
0.042 85.482.00.0410.050mg/KgTrichlorofluoromethane 44-146 4.0 20
0.048 97.694.00.0470.050mg/Kg1,2,3-Trichloropropane 60-137 3.7 20
0.045 90.892.80.0460.050mg/Kg1,2,4-Trimethylbenzene 69-129 2.1 20
0.044 88.493.60.0460.050mg/Kg1,3,5-Trimethylbenzene 69-128 5.7 20
0.058 11897.80.0480.050mg/KgVinyl Acetate 60-140 18.5 20
0.051 1021060.0530.050mg/KgVinyl Chloride 48-147 4.0 20
0.048 96.499.20.0490.050mg/Kgo-Xylene 74-126 2.8 20
0.099 99.31020.1020.100mg/Kgm,p-Xylene 75-124 2.6 20
97.81014-Bromofluorobenzene (S)70-130
10196.2Dibromofluoromethane (S)84-123
90.289.6Toluene-d8 (S)76-129
Page 14 of 18Date:05/10/2023 04:30 PM
Page 45 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V32736QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V32711
Associated Lab Samples: 95155
LRB-V32711 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
05/03/23 10:590.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V32711 LCSD-V32711Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.329 132*1290.3220.250µg/L1,2-Dibromoethane 70-130 2.1 20.0
V 94925-DUP-V32711Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 05/03/23 12:180.9<0.0209< 0.0209µg/L1,2-Dibromoethane
V 94924-MS-V32711Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.330 1260.2610.0105µg/L1,2-Dibromoethane 70-130
Page 15 of 18* QC Fail Date:05/10/2023 04:30 PM
Page 46 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V32651QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V32650
Associated Lab Samples: 95155
LRB-V32650 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/01/23 13:5850.011.5<11.5µg/LAliphatic C5-C8
05/01/23 13:5850.025.8<25.8µg/LAliphatic C9-C12
05/01/23 13:5850.04.02<4.02µg/LAromatic C9-C10
05/01/23 13:582,5-Dibromotoluene (FID) (S)80.3 70-130
05/01/23 13:582,5-Dibromotoluene (PID) (S)89.2 70-130
LCS-V32650 LCSD-V32650Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
358 119120359300µg/LAliphatic C5-C8 70-130 0.2 50.0
336 112110331300µg/LAliphatic C9-C12 70-130 1.4 50.0
111 111104104100µg/LAromatic C9-C10 70-130 6.5 50.0
98.81022,5-Dibromotoluene (FID) (S)70-130
12096.22,5-Dibromotoluene (PID) (S)70-130
Page 16 of 18Date:05/10/2023 04:30 PM
Page 47 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V32693QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V32692
Associated Lab Samples: 95156, 95157, 95158, 95159
LRB-V32692 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
05/02/23 16:208.001.22<1.22mg/KgAliphatic C5-C8
05/02/23 16:208.004.56<4.56mg/KgAliphatic C9-C12
05/02/23 16:208.000.624<0.624mg/KgAromatic C9-C10
05/02/23 16:202,5-Dibromotoluene (FID) (S)80.8 70-130
05/02/23 16:202,5-Dibromotoluene (PID) (S)112 70-130
LCS-V32692 LCSD-V32692Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
32.1 10097.531.232.0mg/KgAliphatic C5-C8 70-130 2.8 50
35.9 11211035.132.0mg/KgAliphatic C9-C12 70-130 2.2 50
13.1 12212313.210.7mg/KgAromatic C9-C10 70-130 0.7 50
81.677.02,5-Dibromotoluene (FID) (S)70-130
1121122,5-Dibromotoluene (PID) (S)70-130
Page 17 of 18Date:05/10/2023 04:30 PM
Page 48 of 51
Quality Control Data
23-121-0003Report No:
Project Description:
Client ID:Geological Resources, Inc.
Handy Corner
Dry Weight Determination
SW-DRYWT
V32710QC Analytical Batch:
Analysis Method:
Analysis Description:
V 95156-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 05/03/23 10:501.519.319.6%Moisture
V 95200-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 05/03/23 10:500.921.521.7%Moisture
Page 18 of 18Date:05/10/2023 04:30 PM
Page 49 of 51
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-121-0003
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 3.1C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Did not receive containers for moisture for samples MW-1-10' & MW-1-15'.
Signature:Angelo Norvell Date & Time:05/01/2023 10:33:04
Special precautions or instructions included?
Comments:
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