MO-29861_0_CA_LSA_20230127_Phase II Site Assessment

GEOTECHNICAL • CONSTRUCTION MATERIALS • ENVIRONMENTAL

PHASE II
ENVIRONMENTAL SITE ASSESSMENT

Iredell County Parcel ID 4727479287 and 4727479359
3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina

January 27, 2023
CVET Project No. 22-431

PREPARED FOR:

Teramore Development, LLC.
P.O. Box 6460
Thomasville, GA 31758

PREPARED BY:

CATAWBA VALLEY ENGINEERING AND TESTING, P.C.
HICKORY, NORTH CAROLINA

PO Box 747
Hickory, NC 28603
161 Lenoir Rhyne Blvd Hickory, NC 28602
828 578 9972 O 828 322 1801 F
NC Firm No. C-3833 SC Firm No. 5201
Geotechnical Engineering
Environmental Services
CMT/Special Inspections
January 27, 2023
Ms. Danielle Stewart
Teramore Development, LLC.
P.O. Box 6460
Thomasville, GA 31758
[e-mail]
Re: Phase II Environmental Site Assessment
Iredell County Parcel ID 4727479287 and 4727479359
3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
Project Number: 22-431
Dear Ms. Stewart,
Catawba Valley Engineering & Testing (CVET) is pleased to submit this Phase II
Environmental Site Assessment (ESA) Report for the above referenced property.
CVET appreciates the opportunity to provide our environmental engineering
services for this project. If you have any questions regarding the contents of this
report, or if we can provide additional services, please do not hesitate to contact
us.
Sincerely,
CATAWBA VALLEY ENGINEERING AND TESTING, P.C.
Nathan S. Simmons, P.G. David M. LeGrand, Jr., P.E.
Environmental Professional Owner/Principal Engineer
01-27-2023
3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

TABLE OF CONTENTS
1.0 BACKGROUND .......................................................................................................................... 1
2.0 SCOPE OF WORK ...................................................................................................................... 1
2.1 Ground Penetrating Radar (GPR) Survey ........................................................................... 1
2.11 GPR Findings ............................................................................................................. 1
2.2 Soil Assessment .................................................................................................................. 1
2.21 Soil Laboratory Analytical Results and Discussion ................................................... 2
2.3 Groundwater Assessment .................................................................................................. 2
2.31 Groundwater Laboratory Analytical Results and Discussion ................................... 3
3.0 CONCLUSIONS AND RECOMMENDATIONS .............................................................................. 3
APPENDIX A – FIGURE
APPENDIX B – TABLES
APPENDIX C – LABORATORY ANALYTICAL REPORT

3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

1

1.0 BACKGROUND

The subject site consists of two parcels of land totaling approximately 1.98-acres in size. Based
on the results of an Environmental Data Resources (EDR) Summary Report submitted for the
subject site by CVET on September 26, 2022, a filling station is located on the adjacent property
to the south. Based on the up-gradient site location of the adjacent filling station, proximity to
the subject site, a compliance violation in 2021, and age of the facility, the potential for an
unreported, undiscovered, or future release capable of impacting the subject site could not be
ruled out.

Based on these findings, Teramore authorized CVET to perform a Phase II ESA at the subject site.

2.0 SCOPE OF WORK

As part of this Phase II ESA, CVET performed the following scope of work:

2.1 Ground Penetrating Radar (GPR) Survey

Ground Penetrating Radar Systems, LLC (GPRS) performed a GPR survey at the subject site. The
survey was performed to screen for USTs and other potential subsurface environmental concerns
that might be present in association with current and former development at the subject site.

2.11 GPR Findings

GPR equipment located on-site utilities and a potential septic system, which was located
to the west of the vacant dwelling. No obvious evidence of USTs or other environmental
concerns were observed.

2.2 Soil Assessment

On November 28, 2022, CVET mobilized to the site to complete soil borings in the vicinity of the
potential septic system, former structures, and also along the southern border of the site as part
of groundwater well installation. CVET performed a total of four soil borings (1, 2, 3, and 4).
Borings 3 and 4 were completed during installation of temporary groundwater monitoring wells
TW-1 and TW-2, respectively. Boring locations are depicted in Appendix A – Figure 1. At each
location, soil was continuously screened for visual and olfactory evidence of impact. Soil was also
screened utilizing a calibrated photo-ionizing detector (PID). Soil borings are summarized in the
following table:

3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

2

Boring
ID
Area Being
Investigated
Approximate
Depth (fbgs)
Maximum
PID Reading
(ppm)
Field Observations
Laboratory
Sample
Collected
1 Septic/Former
Buildings 0.0 – 20.0 0.0 No obvious odors or staining. B-1
(Soil)
2 Septic/Former
Buildings 0.0 – 20.0 0.0 No obvious odors or staining. B-2
(Soil)
3 Well
Installation 0.0 – 15.0 0.0 No obvious odors or staining. TW-1
(Groundwater)
4 Well
Installation 0.0 – 25.0 0.0 No obvious odors or staining. TW-2
(Groundwater)

Following completion of the borings, CVET selected samples from borings 1 and 2. Samples (1,
2, and 3) were collected from depth intervals appearing most likely to have been impacted, as
depicted in Appendix A - Figure 1. Samples were placed in laboratory supplied bottles and were
immediately placed on ice. Samples were submitted to Pace Analytical Laboratories of
Huntersville, North Carolina to be analyzed for a combination of total petroleum hydrocarbons –
gasoline range organics (TPH-GRO) and total petroleum hydrocarbons – diesel range organics
(TPH-DRO).

2.21 Soil Laboratory Analytical Results and Discussion

Based on laboratory analytical results, TPH-DRO was detected at a concentration of 9.3
mg/kg in soil sample B-1. This concentration is below the NCDEQ Action Level of 100
mg/kg for TPH-DRO. No other constituents were detected. Laboratory results are
summarized in Appendix B – Table 1 and Appendix C.

Based on these results, it appears that low levels of petroleum compounds may be
present in the vicinity of soil sample 1. However, laboratory results did not detect TPH-
DRO above the applicable standard.

2.3 Groundwater Assessment

On November 28, 2022, CVET mobilized to the site for the installation of two temporary
groundwater monitoring wells, TW-1 and TW-2 (Appendix A – Figure 2). Temporary well TW-1
was installed at soil boring location 3 and TW-2 was installed at soil boring location 4. At each
well location, direct push technology was used to continuously screen the soil for potential
evidence of impact, to characterize general lithology, and to identify zones of preferential
groundwater flow.

Each boring was advanced until groundwater was encountered, following which, the boring was
extended below the water table. Wells were installed to span the water table surface. A one-
3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

3

inch temporary PVC monitoring well with 10 - 15 feet of slotted one-inch screen was installed in
each open borehole.

Following installation, wells were allowed to equilibrate for approximately one hour, static water
levels were recorded, and wells were developed by purging at least three well volumes. Well
development was performed to remove any fine grained sediment that may have entered the
well during installation, to promote hydraulic communication with the surrounding materials,
and to ensure that water is representative of the surrounding aquifer. Static groundwater levels
were encountered at approximately 10.05-fbgs in TW-1 and at approximately 19.10-fbgs in TW-
2. Following well development and removal of approximately three well volumes, groundwater
samples were collected from TW-1 and TW-2. A peristaltic pump and new dedicated tubing were
used to sample each well. The samples were immediately placed on ice and were submitted to
Pace Analytical Laboratories of Huntersville, North Carolina to be analyzed for volatile organic
compounds (VOCs) and semi-volatile organic compounds (SVOCs). Following collection of
groundwater samples, each well was abandoned in accordance with state and local regulations.

2.31 Groundwater Laboratory Analytical Results and Discussion

Based on laboratory analytical results, diisopropyl ether (DIPE) and methyl-tert butyl
ether (MTBE) were detected at a concentration of 0.39 ug/L and 159 ug/L, respectively,
in sample TW-2. DIPE concentrations are below the applicable 15A NCAC 2L
groundwater standard of 70 ug/L, however, concentrations of MTBE are above the 2L
standard of 20 ug/L. No other compounds were detected in TW-1 or TW-2. Laboratory
results are summarized in Appendix B – Table 2 and Appendix C.

Based on these results, petroleum impacted groundwater was identified at sample
location TW-2. Impact was characterized by two gasoline additives, which suggest that
the source of impact is the adjacent filling station to the south. Levels of MTBE were
detected above the applicable groundwater standard in TW-2. No impact was identified
in TW-1. (Appendix A – Figure 2).

3.0 CONCLUSIONS AND RECOMMENDATIONS

Based on the results of this assessment, petroleum impacted groundwater was detected at a
concentration above the applicable groundwater screening level on the southeastern portion of
the subject property. Impact appears to be the result of impact migrating from the adjacent
filling station to the south. CVET recommends reporting the results of this assessment to the
NCDEQ immediately.

To the extent feasible, CVET has assessed for the presence of impacted soil and groundwater at
the subject site. Assessment was performed as allowed by site conditions/equipment limitations
and is not a guarantee of subsurface conditions. Environmental impact may exist in areas of the
3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

4

site not accessible to CVET or in other areas that were not evaluated. Bedrock and deeper aquifer
conditions were not evaluated. No other areas or aspects of the site were investigated.

3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

1

APPENDIX A – FIGURE

NSS
Figure 1
P.O.B. 747 NORTH CAROLINAHICKORY
FAX: [phone]TELE: 828-578-9972
CATAWBA VALLEY
ENGINEERING & TESTING
Site Location Map
Subject Pro
p
e
r
t
y
115 Country Store/Yogi Foods
3023 and 3027 Wilkesboro Highway
Statesville, North Carolina
22-431
January 25, 2022
3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

2

APPENDIX B – TABLES

Table 1 - Soil Analytical Results for Detected Constituents
Phase II ESA
3023 3027 Wilkesboro highway
Statesville, North Carolina
Sample ID B-1 B-2
Date 11/28/22 11/28/22
Detected Constituent CAS No.NCDEQ Action
Level
TPH-GRO --50 < 2.90 < 2.70
TPH-DRO --100 9.30 < 4.90
Notes:TPHUnits in mg/kg
VOCs - Volatile Organic Compounds
-- No standard available/Not analyzed
mg/kg - milligrams per kilogram.
TPH-DRO: Total Petroleum Hydrocarbon - Diesel Range Organics
TPH-GRO: Total Petroleum Hydrocarbon - Gasoline Range Organics
Table 2 - Groundwater Analytical Results for Detected Constituents
Phase II Environmental Site Assessment
3023 3027 Wilkesboro Highway
Statesville, North Carolina
Sample ID TW-1 TW-3
Date 11/28/2022 11/28/2022
Detected Constituent CAS No.
NCDEQ 15A NCAC 2L
Groundwater Standard
(ug/L)
NCDEQ Gross
Contamination Levels
(ug/L)
diisopropyl ether (DIPE)108-20-3 70 70,000 < 0.310 0.390 J
methyl-tert butyl ether
(MTBE)1634-04-4 20 20,000 < 0.420 159
Notes:
ug/L - micrograms per liter
Units in ug/L
VOCs VOC's - Volatile Organic Compounds
NCDEQ - North Carolina Department of Environmental Quality
3023 and 3027 Wilkesboro Highway
Statesville, Iredell County, North Carolina
January 27, 2023
CVET Project No. 22-431

2

APPENDIX C – LABORATORY ANALYTICAL REPORT

#=CL#
December 05, 2022
LIMS USE: FR - NATHAN SIMMONS
LIMS OBJECT ID: 92638465
92638465
Project:
Pace Project No.:
RE:
Nathan Simmons
Catawba Valley Engineering & Testing
161 Lenoir Rhyne Blvd SE
Hickory, NC 28603
22-431
Dear Nathan Simmons:
Enclosed are the analytical results for sample(s) received by the laboratory on November 28, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 33
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92638465
22-431
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 33
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92638465
22-431
Lab ID Sample ID Matrix Date Collected Date Received
92638465001 TW-1 Water 11/28/22 11:00 11/28/22 14:00
92638465002 TW-2 Water 11/28/22 11:50 11/28/22 14:00
92638465003 B-1 Solid 11/28/22 11:30 11/28/22 14:00
92638465004 B-2 Solid 11/28/22 11:40 11/28/22 14:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 33
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92638465
22-431
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92638465001 TW-1 EPA 8270E 74 PASI-CPKS
EPA 8260D 63 PASI-CCL
92638465002 TW-2 EPA 8270E 74 PASI-CPKS
EPA 8260D 63 PASI-CCL
92638465003 B-1 EPA 8015C 2 PASI-CBAJ
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92638465004 B-2 EPA 8015C 2 PASI-CBAJ
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-1 Lab ID:92638465001 Collected:11/28/22 11:00 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Acenaphthene ND ug/L 11/30/22 00:03 83-32-911/29/22 12:409.1 1.8 1
Acenaphthylene ND ug/L 11/30/22 00:03 208-96-811/29/22 12:409.1 1.8 1
Aniline ND ug/L 11/30/22 00:03 62-53-311/29/22 12:409.1 1.5 1
Anthracene ND ug/L 11/30/22 00:03 120-12-711/29/22 12:409.1 2.1 1
Benzo(a)anthracene ND ug/L 11/30/22 00:03 56-55-311/29/22 12:409.1 2.4 1
Benzo(a)pyrene ND ug/L 11/30/22 00:03 50-32-811/29/22 12:409.1 2.5 1
Benzo(b)fluoranthene ND ug/L 11/30/22 00:03 205-99-211/29/22 12:409.1 2.4 1
Benzo(g,h,i)perylene ND ug/L 11/30/22 00:03 191-24-211/29/22 12:409.1 2.6 1
Benzo(k)fluoranthene ND ug/L 11/30/22 00:03 207-08-911/29/22 12:409.1 2.5 1
Benzoic Acid ND ug/L 11/30/22 00:03 65-85-0 M1,v2,
v311/29/22 12:4045.5 20.0 1
Benzyl alcohol ND ug/L 11/30/22 00:03 100-51-611/29/22 12:4018.2 2.6 1
4-Bromophenylphenyl ether ND ug/L 11/30/22 00:03 101-55-311/29/22 12:409.1 1.6 1
Butylbenzylphthalate ND ug/L 11/30/22 00:03 85-68-711/29/22 12:409.1 2.9 1
4-Chloro-3-methylphenol ND ug/L 11/30/22 00:03 59-50-711/29/22 12:409.1 3.0 1
4-Chloroaniline ND ug/L 11/30/22 00:03 106-47-811/29/22 12:4018.2 3.3 1
bis(2-Chloroethoxy)methane ND ug/L 11/30/22 00:03 111-91-111/29/22 12:409.1 1.7 1
bis(2-Chloroethyl) ether ND ug/L 11/30/22 00:03 111-44-4 R111/29/22 12:409.1 1.7 1
2-Chloronaphthalene ND ug/L 11/30/22 00:03 91-58-711/29/22 12:409.1 1.6 1
2-Chlorophenol ND ug/L 11/30/22 00:03 95-57-8 R111/29/22 12:409.1 1.1 1
4-Chlorophenylphenyl ether ND ug/L 11/30/22 00:03 7005-72-311/29/22 12:409.1 1.8 1
Chrysene ND ug/L 11/30/22 00:03 218-01-911/29/22 12:409.1 2.5 1
Dibenz(a,h)anthracene ND ug/L 11/30/22 00:03 53-70-311/29/22 12:409.1 2.7 1
Dibenzofuran ND ug/L 11/30/22 00:03 132-64-911/29/22 12:409.1 1.9 1
1,2-Dichlorobenzene ND ug/L 11/30/22 00:03 95-50-111/29/22 12:409.1 1.6 1
1,3-Dichlorobenzene ND ug/L 11/30/22 00:03 541-73-111/29/22 12:409.1 1.5 1
1,4-Dichlorobenzene ND ug/L 11/30/22 00:03 106-46-711/29/22 12:409.1 1.5 1
3,3'-Dichlorobenzidine ND ug/L 11/30/22 00:03 91-94-1 v111/29/22 12:4018.2 7.4 1
2,4-Dichlorophenol ND ug/L 11/30/22 00:03 120-83-2 R111/29/22 12:409.1 1.3 1
Diethylphthalate ND ug/L 11/30/22 00:03 84-66-211/29/22 12:409.1 1.9 1
2,4-Dimethylphenol ND ug/L 11/30/22 00:03 105-67-911/29/22 12:409.1 1.5 1
Dimethylphthalate ND ug/L 11/30/22 00:03 131-11-311/29/22 12:409.1 1.9 1
Di-n-butylphthalate ND ug/L 11/30/22 00:03 84-74-211/29/22 12:409.1 2.0 1
4,6-Dinitro-2-methylphenol ND ug/L 11/30/22 00:03 534-52-111/29/22 12:4018.2 7.1 1
2,4-Dinitrophenol ND ug/L 11/30/22 00:03 51-28-5 M111/29/22 12:4045.5 23.6 1
2,4-Dinitrotoluene ND ug/L 11/30/22 00:03 121-14-211/29/22 12:409.1 1.5 1
2,6-Dinitrotoluene ND ug/L 11/30/22 00:03 606-20-211/29/22 12:409.1 1.6 1
Di-n-octylphthalate ND ug/L 11/30/22 00:03 117-84-011/29/22 12:409.1 3.6 1
bis(2-Ethylhexyl)phthalate ND ug/L 11/30/22 00:03 117-81-711/29/22 12:405.5 3.4 1
Fluoranthene ND ug/L 11/30/22 00:03 206-44-011/29/22 12:409.1 2.0 1
Fluorene ND ug/L 11/30/22 00:03 86-73-711/29/22 12:409.1 1.9 1
Hexachloro-1,3-butadiene ND ug/L 11/30/22 00:03 87-68-311/29/22 12:409.1 1.6 1
Hexachlorobenzene ND ug/L 11/30/22 00:03 118-74-111/29/22 12:409.1 2.0 1
Hexachlorocyclopentadiene ND ug/L 11/30/22 00:03 77-47-4 R111/29/22 12:409.1 1.4 1
Hexachloroethane ND ug/L 11/30/22 00:03 67-72-111/29/22 12:409.1 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-1 Lab ID:92638465001 Collected:11/28/22 11:00 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Indeno(1,2,3-cd)pyrene ND ug/L 11/30/22 00:03 193-39-511/29/22 12:409.1 2.6 1
Isophorone ND ug/L 11/30/22 00:03 78-59-111/29/22 12:409.1 1.5 1
1-Methylnaphthalene ND ug/L 11/30/22 00:03 90-12-0 R111/29/22 12:409.1 1.8 1
2-Methylnaphthalene ND ug/L 11/30/22 00:03 91-57-6 R111/29/22 12:409.1 1.7 1
2-Methylphenol(o-Cresol)ND ug/L 11/30/22 00:03 95-48-711/29/22 12:409.1 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 11/30/22 00:03 15831-10-411/29/22 12:409.1 1.1 1
Naphthalene ND ug/L 11/30/22 00:03 91-20-3 R111/29/22 12:409.1 1.9 1
2-Nitroaniline ND ug/L 11/30/22 00:03 88-74-411/29/22 12:4018.2 2.7 1
3-Nitroaniline ND ug/L 11/30/22 00:03 99-09-211/29/22 12:4018.2 3.4 1
4-Nitroaniline ND ug/L 11/30/22 00:03 100-01-611/29/22 12:4018.2 4.6 1
Nitrobenzene ND ug/L 11/30/22 00:03 98-95-3 R111/29/22 12:409.1 1.7 1
2-Nitrophenol ND ug/L 11/30/22 00:03 88-75-5 R1,v111/29/22 12:409.1 1.3 1
4-Nitrophenol ND ug/L 11/30/22 00:03 100-02-7 M111/29/22 12:4045.5 6.0 1
N-Nitrosodimethylamine ND ug/L 11/30/22 00:03 62-75-911/29/22 12:409.1 1.7 1
N-Nitroso-di-n-propylamine ND ug/L 11/30/22 00:03 621-64-7 R111/29/22 12:409.1 1.2 1
N-Nitrosodiphenylamine ND ug/L 11/30/22 00:03 86-30-611/29/22 12:409.1 2.7 1
2,2'-Oxybis(1-chloropropane)ND ug/L 11/30/22 00:03 108-60-1 R1,v2,
v311/29/22 12:409.1 1.0 1
Pentachlorophenol ND ug/L 11/30/22 00:03 87-86-5 M111/29/22 12:4018.2 3.4 1
Phenanthrene ND ug/L 11/30/22 00:03 85-01-811/29/22 12:409.1 1.8 1
Phenol ND ug/L 11/30/22 00:03 108-95-2 R111/29/22 12:409.1 1.2 1
Pyrene ND ug/L 11/30/22 00:03 129-00-011/29/22 12:409.1 2.0 1
1,2,4-Trichlorobenzene ND ug/L 11/30/22 00:03 120-82-1 R111/29/22 12:409.1 1.6 1
2,4,5-Trichlorophenol ND ug/L 11/30/22 00:03 95-95-4 R111/29/22 12:409.1 1.3 1
2,4,6-Trichlorophenol ND ug/L 11/30/22 00:03 88-06-211/29/22 12:409.1 1.4 1
Surrogates
Nitrobenzene-d5 (S)62 %11/30/22 00:03 4165-60-011/29/22 12:4010-144 1
2-Fluorobiphenyl (S)70 %11/30/22 00:03 321-60-811/29/22 12:4010-130 1
Terphenyl-d14 (S)114 %11/30/22 00:03 1718-51-011/29/22 12:4034-163 1
Phenol-d6 (S)40 %11/30/22 00:03 13127-88-311/29/22 12:4010-130 1
2-Fluorophenol (S)45 %11/30/22 00:03 367-12-411/29/22 12:4010-130 1
2,4,6-Tribromophenol (S)113 %11/30/22 00:03 118-79-611/29/22 12:4010-144 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Acetone ND ug/L 11/30/22 21:31 67-64-125.0 5.1 1
Benzene ND ug/L 11/30/22 21:31 71-43-21.0 0.34 1
Bromobenzene ND ug/L 11/30/22 21:31 108-86-11.0 0.29 1
Bromochloromethane ND ug/L 11/30/22 21:31 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 11/30/22 21:31 75-27-41.0 0.31 1
Bromoform ND ug/L 11/30/22 21:31 75-25-21.0 0.34 1
Bromomethane ND ug/L 11/30/22 21:31 74-83-92.0 1.7 1
2-Butanone (MEK)ND ug/L 11/30/22 21:31 78-93-3 v15.0 4.0 1
Carbon tetrachloride ND ug/L 11/30/22 21:31 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 11/30/22 21:31 108-90-71.0 0.28 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-1 Lab ID:92638465001 Collected:11/28/22 11:00 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Chloroethane ND ug/L 11/30/22 21:31 75-00-31.0 0.65 1
Chloroform ND ug/L 11/30/22 21:31 67-66-31.0 0.43 1
Chloromethane ND ug/L 11/30/22 21:31 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 11/30/22 21:31 95-49-81.0 0.32 1
4-Chlorotoluene ND ug/L 11/30/22 21:31 106-43-41.0 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 11/30/22 21:31 96-12-82.0 0.34 1
Dibromochloromethane ND ug/L 11/30/22 21:31 124-48-11.0 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 11/30/22 21:31 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/30/22 21:31 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 11/30/22 21:31 95-50-11.0 0.34 1
1,3-Dichlorobenzene ND ug/L 11/30/22 21:31 541-73-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 11/30/22 21:31 106-46-71.0 0.33 1
Dichlorodifluoromethane ND ug/L 11/30/22 21:31 75-71-81.0 0.35 1
1,1-Dichloroethane ND ug/L 11/30/22 21:31 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 11/30/22 21:31 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 11/30/22 21:31 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 11/30/22 21:31 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 11/30/22 21:31 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 11/30/22 21:31 78-87-51.0 0.36 1
1,3-Dichloropropane ND ug/L 11/30/22 21:31 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 11/30/22 21:31 594-20-71.0 0.39 1
1,1-Dichloropropene ND ug/L 11/30/22 21:31 563-58-61.0 0.43 1
cis-1,3-Dichloropropene ND ug/L 11/30/22 21:31 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 11/30/22 21:31 10061-02-61.0 0.36 1
Diisopropyl ether ND ug/L 11/30/22 21:31 108-20-31.0 0.31 1
Ethylbenzene ND ug/L 11/30/22 21:31 100-41-41.0 0.30 1
Hexachloro-1,3-butadiene ND ug/L 11/30/22 21:31 87-68-32.0 1.5 1
2-Hexanone ND ug/L 11/30/22 21:31 591-78-65.0 0.48 1
p-Isopropyltoluene ND ug/L 11/30/22 21:31 99-87-61.0 0.41 1
Methylene Chloride ND ug/L 11/30/22 21:31 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/22 21:31 108-10-15.0 2.7 1
Methyl-tert-butyl ether ND ug/L 11/30/22 21:31 1634-04-41.0 0.42 1
Naphthalene ND ug/L 11/30/22 21:31 91-20-31.0 0.64 1
Styrene ND ug/L 11/30/22 21:31 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/22 21:31 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/22 21:31 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 11/30/22 21:31 127-18-41.0 0.29 1
Toluene ND ug/L 11/30/22 21:31 108-88-31.0 0.24 1
1,2,3-Trichlorobenzene ND ug/L 11/30/22 21:31 87-61-61.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 11/30/22 21:31 120-82-11.0 0.64 1
1,1,1-Trichloroethane ND ug/L 11/30/22 21:31 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 11/30/22 21:31 79-00-51.0 0.32 1
Trichloroethene ND ug/L 11/30/22 21:31 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 11/30/22 21:31 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 11/30/22 21:31 96-18-41.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-1 Lab ID:92638465001 Collected:11/28/22 11:00 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Vinyl acetate ND ug/L 11/30/22 21:31 108-05-4 v12.0 1.3 1
Vinyl chloride ND ug/L 11/30/22 21:31 75-01-41.0 0.39 1
Xylene (Total)ND ug/L 11/30/22 21:31 1330-20-71.0 0.34 1
m&p-Xylene ND ug/L 11/30/22 21:31 179601-23-12.0 0.71 1
o-Xylene ND ug/L 11/30/22 21:31 95-47-61.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)100 %11/30/22 21:31 460-00-470-130 1
1,2-Dichloroethane-d4 (S)91 %11/30/22 21:31 17060-07-070-130 1
Toluene-d8 (S)108 %11/30/22 21:31 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-2 Lab ID:92638465002 Collected:11/28/22 11:50 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Acenaphthene ND ug/L 11/30/22 01:18 83-32-911/29/22 12:409.1 1.8 1
Acenaphthylene ND ug/L 11/30/22 01:18 208-96-811/29/22 12:409.1 1.8 1
Aniline ND ug/L 11/30/22 01:18 62-53-311/29/22 12:409.1 1.5 1
Anthracene ND ug/L 11/30/22 01:18 120-12-711/29/22 12:409.1 2.1 1
Benzo(a)anthracene ND ug/L 11/30/22 01:18 56-55-311/29/22 12:409.1 2.4 1
Benzo(a)pyrene ND ug/L 11/30/22 01:18 50-32-811/29/22 12:409.1 2.5 1
Benzo(b)fluoranthene ND ug/L 11/30/22 01:18 205-99-211/29/22 12:409.1 2.4 1
Benzo(g,h,i)perylene ND ug/L 11/30/22 01:18 191-24-211/29/22 12:409.1 2.6 1
Benzo(k)fluoranthene ND ug/L 11/30/22 01:18 207-08-911/29/22 12:409.1 2.5 1
Benzoic Acid ND ug/L 11/30/22 01:18 65-85-0 v211/29/22 12:4045.5 20.0 1
Benzyl alcohol ND ug/L 11/30/22 01:18 100-51-611/29/22 12:4018.2 2.6 1
4-Bromophenylphenyl ether ND ug/L 11/30/22 01:18 101-55-311/29/22 12:409.1 1.6 1
Butylbenzylphthalate ND ug/L 11/30/22 01:18 85-68-711/29/22 12:409.1 2.9 1
4-Chloro-3-methylphenol ND ug/L 11/30/22 01:18 59-50-711/29/22 12:409.1 3.0 1
4-Chloroaniline ND ug/L 11/30/22 01:18 106-47-811/29/22 12:4018.2 3.3 1
bis(2-Chloroethoxy)methane ND ug/L 11/30/22 01:18 111-91-111/29/22 12:409.1 1.7 1
bis(2-Chloroethyl) ether ND ug/L 11/30/22 01:18 111-44-411/29/22 12:409.1 1.7 1
2-Chloronaphthalene ND ug/L 11/30/22 01:18 91-58-711/29/22 12:409.1 1.6 1
2-Chlorophenol ND ug/L 11/30/22 01:18 95-57-811/29/22 12:409.1 1.1 1
4-Chlorophenylphenyl ether ND ug/L 11/30/22 01:18 7005-72-311/29/22 12:409.1 1.8 1
Chrysene ND ug/L 11/30/22 01:18 218-01-911/29/22 12:409.1 2.5 1
Dibenz(a,h)anthracene ND ug/L 11/30/22 01:18 53-70-311/29/22 12:409.1 2.7 1
Dibenzofuran ND ug/L 11/30/22 01:18 132-64-911/29/22 12:409.1 1.9 1
1,2-Dichlorobenzene ND ug/L 11/30/22 01:18 95-50-111/29/22 12:409.1 1.6 1
1,3-Dichlorobenzene ND ug/L 11/30/22 01:18 541-73-111/29/22 12:409.1 1.5 1
1,4-Dichlorobenzene ND ug/L 11/30/22 01:18 106-46-711/29/22 12:409.1 1.5 1
3,3'-Dichlorobenzidine ND ug/L 11/30/22 01:18 91-94-1 v111/29/22 12:4018.2 7.4 1
2,4-Dichlorophenol ND ug/L 11/30/22 01:18 120-83-211/29/22 12:409.1 1.3 1
Diethylphthalate ND ug/L 11/30/22 01:18 84-66-211/29/22 12:409.1 1.9 1
2,4-Dimethylphenol ND ug/L 11/30/22 01:18 105-67-911/29/22 12:409.1 1.5 1
Dimethylphthalate ND ug/L 11/30/22 01:18 131-11-311/29/22 12:409.1 1.9 1
Di-n-butylphthalate ND ug/L 11/30/22 01:18 84-74-211/29/22 12:409.1 2.0 1
4,6-Dinitro-2-methylphenol ND ug/L 11/30/22 01:18 534-52-111/29/22 12:4018.2 7.1 1
2,4-Dinitrophenol ND ug/L 11/30/22 01:18 51-28-511/29/22 12:4045.5 23.6 1
2,4-Dinitrotoluene ND ug/L 11/30/22 01:18 121-14-211/29/22 12:409.1 1.5 1
2,6-Dinitrotoluene ND ug/L 11/30/22 01:18 606-20-211/29/22 12:409.1 1.6 1
Di-n-octylphthalate ND ug/L 11/30/22 01:18 117-84-011/29/22 12:409.1 3.6 1
bis(2-Ethylhexyl)phthalate ND ug/L 11/30/22 01:18 117-81-711/29/22 12:405.5 3.4 1
Fluoranthene ND ug/L 11/30/22 01:18 206-44-011/29/22 12:409.1 2.0 1
Fluorene ND ug/L 11/30/22 01:18 86-73-711/29/22 12:409.1 1.9 1
Hexachloro-1,3-butadiene ND ug/L 11/30/22 01:18 87-68-311/29/22 12:409.1 1.6 1
Hexachlorobenzene ND ug/L 11/30/22 01:18 118-74-111/29/22 12:409.1 2.0 1
Hexachlorocyclopentadiene ND ug/L 11/30/22 01:18 77-47-411/29/22 12:409.1 1.4 1
Hexachloroethane ND ug/L 11/30/22 01:18 67-72-111/29/22 12:409.1 1.3 1
Indeno(1,2,3-cd)pyrene ND ug/L 11/30/22 01:18 193-39-511/29/22 12:409.1 2.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-2 Lab ID:92638465002 Collected:11/28/22 11:50 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Isophorone ND ug/L 11/30/22 01:18 78-59-111/29/22 12:409.1 1.5 1
1-Methylnaphthalene ND ug/L 11/30/22 01:18 90-12-011/29/22 12:409.1 1.8 1
2-Methylnaphthalene ND ug/L 11/30/22 01:18 91-57-611/29/22 12:409.1 1.7 1
2-Methylphenol(o-Cresol)ND ug/L 11/30/22 01:18 95-48-711/29/22 12:409.1 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 11/30/22 01:18 15831-10-411/29/22 12:409.1 1.1 1
Naphthalene ND ug/L 11/30/22 01:18 91-20-311/29/22 12:409.1 1.9 1
2-Nitroaniline ND ug/L 11/30/22 01:18 88-74-411/29/22 12:4018.2 2.7 1
3-Nitroaniline ND ug/L 11/30/22 01:18 99-09-211/29/22 12:4018.2 3.4 1
4-Nitroaniline ND ug/L 11/30/22 01:18 100-01-611/29/22 12:4018.2 4.6 1
Nitrobenzene ND ug/L 11/30/22 01:18 98-95-311/29/22 12:409.1 1.7 1
2-Nitrophenol ND ug/L 11/30/22 01:18 88-75-5 v111/29/22 12:409.1 1.3 1
4-Nitrophenol ND ug/L 11/30/22 01:18 100-02-711/29/22 12:4045.5 6.0 1
N-Nitrosodimethylamine ND ug/L 11/30/22 01:18 62-75-911/29/22 12:409.1 1.7 1
N-Nitroso-di-n-propylamine ND ug/L 11/30/22 01:18 621-64-711/29/22 12:409.1 1.2 1
N-Nitrosodiphenylamine ND ug/L 11/30/22 01:18 86-30-611/29/22 12:409.1 2.7 1
2,2'-Oxybis(1-chloropropane)ND ug/L 11/30/22 01:18 108-60-1 v211/29/22 12:409.1 1.0 1
Pentachlorophenol ND ug/L 11/30/22 01:18 87-86-511/29/22 12:4018.2 3.4 1
Phenanthrene ND ug/L 11/30/22 01:18 85-01-811/29/22 12:409.1 1.8 1
Phenol ND ug/L 11/30/22 01:18 108-95-211/29/22 12:409.1 1.2 1
Pyrene ND ug/L 11/30/22 01:18 129-00-011/29/22 12:409.1 2.0 1
1,2,4-Trichlorobenzene ND ug/L 11/30/22 01:18 120-82-111/29/22 12:409.1 1.6 1
2,4,5-Trichlorophenol ND ug/L 11/30/22 01:18 95-95-411/29/22 12:409.1 1.3 1
2,4,6-Trichlorophenol ND ug/L 11/30/22 01:18 88-06-211/29/22 12:409.1 1.4 1
Surrogates
Nitrobenzene-d5 (S)72 %11/30/22 01:18 4165-60-011/29/22 12:4010-144 1
2-Fluorobiphenyl (S)66 %11/30/22 01:18 321-60-811/29/22 12:4010-130 1
Terphenyl-d14 (S)96 %11/30/22 01:18 1718-51-011/29/22 12:4034-163 1
Phenol-d6 (S)26 %11/30/22 01:18 13127-88-311/29/22 12:4010-130 1
2-Fluorophenol (S)19 %11/30/22 01:18 367-12-411/29/22 12:4010-130 1
2,4,6-Tribromophenol (S)32 %11/30/22 01:18 118-79-611/29/22 12:4010-144 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Acetone ND ug/L 11/30/22 21:48 67-64-125.0 5.1 1
Benzene ND ug/L 11/30/22 21:48 71-43-21.0 0.34 1
Bromobenzene ND ug/L 11/30/22 21:48 108-86-11.0 0.29 1
Bromochloromethane ND ug/L 11/30/22 21:48 74-97-51.0 0.47 1
Bromodichloromethane ND ug/L 11/30/22 21:48 75-27-41.0 0.31 1
Bromoform ND ug/L 11/30/22 21:48 75-25-21.0 0.34 1
Bromomethane ND ug/L 11/30/22 21:48 74-83-92.0 1.7 1
2-Butanone (MEK)ND ug/L 11/30/22 21:48 78-93-3 v15.0 4.0 1
Carbon tetrachloride ND ug/L 11/30/22 21:48 56-23-51.0 0.33 1
Chlorobenzene ND ug/L 11/30/22 21:48 108-90-71.0 0.28 1
Chloroethane ND ug/L 11/30/22 21:48 75-00-31.0 0.65 1
Chloroform ND ug/L 11/30/22 21:48 67-66-31.0 0.43 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-2 Lab ID:92638465002 Collected:11/28/22 11:50 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Chloromethane ND ug/L 11/30/22 21:48 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 11/30/22 21:48 95-49-81.0 0.32 1
4-Chlorotoluene ND ug/L 11/30/22 21:48 106-43-41.0 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 11/30/22 21:48 96-12-82.0 0.34 1
Dibromochloromethane ND ug/L 11/30/22 21:48 124-48-11.0 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 11/30/22 21:48 106-93-41.0 0.27 1
Dibromomethane ND ug/L 11/30/22 21:48 74-95-31.0 0.39 1
1,2-Dichlorobenzene ND ug/L 11/30/22 21:48 95-50-11.0 0.34 1
1,3-Dichlorobenzene ND ug/L 11/30/22 21:48 541-73-11.0 0.34 1
1,4-Dichlorobenzene ND ug/L 11/30/22 21:48 106-46-71.0 0.33 1
Dichlorodifluoromethane ND ug/L 11/30/22 21:48 75-71-81.0 0.35 1
1,1-Dichloroethane ND ug/L 11/30/22 21:48 75-34-31.0 0.37 1
1,2-Dichloroethane ND ug/L 11/30/22 21:48 107-06-21.0 0.32 1
1,1-Dichloroethene ND ug/L 11/30/22 21:48 75-35-41.0 0.35 1
cis-1,2-Dichloroethene ND ug/L 11/30/22 21:48 156-59-21.0 0.38 1
trans-1,2-Dichloroethene ND ug/L 11/30/22 21:48 156-60-51.0 0.40 1
1,2-Dichloropropane ND ug/L 11/30/22 21:48 78-87-51.0 0.36 1
1,3-Dichloropropane ND ug/L 11/30/22 21:48 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 11/30/22 21:48 594-20-71.0 0.39 1
1,1-Dichloropropene ND ug/L 11/30/22 21:48 563-58-61.0 0.43 1
cis-1,3-Dichloropropene ND ug/L 11/30/22 21:48 10061-01-51.0 0.36 1
trans-1,3-Dichloropropene ND ug/L 11/30/22 21:48 10061-02-61.0 0.36 1
Diisopropyl ether 0.39J ug/L 11/30/22 21:48 108-20-31.0 0.31 1
Ethylbenzene ND ug/L 11/30/22 21:48 100-41-41.0 0.30 1
Hexachloro-1,3-butadiene ND ug/L 11/30/22 21:48 87-68-32.0 1.5 1
2-Hexanone ND ug/L 11/30/22 21:48 591-78-65.0 0.48 1
p-Isopropyltoluene ND ug/L 11/30/22 21:48 99-87-61.0 0.41 1
Methylene Chloride ND ug/L 11/30/22 21:48 75-09-25.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 11/30/22 21:48 108-10-15.0 2.7 1
Methyl-tert-butyl ether 159 ug/L 11/30/22 21:48 1634-04-41.0 0.42 1
Naphthalene ND ug/L 11/30/22 21:48 91-20-31.0 0.64 1
Styrene ND ug/L 11/30/22 21:48 100-42-51.0 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 11/30/22 21:48 630-20-61.0 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 11/30/22 21:48 79-34-51.0 0.22 1
Tetrachloroethene ND ug/L 11/30/22 21:48 127-18-41.0 0.29 1
Toluene ND ug/L 11/30/22 21:48 108-88-31.0 0.24 1
1,2,3-Trichlorobenzene ND ug/L 11/30/22 21:48 87-61-61.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 11/30/22 21:48 120-82-11.0 0.64 1
1,1,1-Trichloroethane ND ug/L 11/30/22 21:48 71-55-61.0 0.33 1
1,1,2-Trichloroethane ND ug/L 11/30/22 21:48 79-00-51.0 0.32 1
Trichloroethene ND ug/L 11/30/22 21:48 79-01-61.0 0.38 1
Trichlorofluoromethane ND ug/L 11/30/22 21:48 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 11/30/22 21:48 96-18-41.0 0.26 1
Vinyl acetate ND ug/L 11/30/22 21:48 108-05-4 v12.0 1.3 1
Vinyl chloride ND ug/L 11/30/22 21:48 75-01-41.0 0.39 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:TW-2 Lab ID:92638465002 Collected:11/28/22 11:50 Received:11/28/22 14:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Xylene (Total)ND ug/L 11/30/22 21:48 1330-20-71.0 0.34 1
m&p-Xylene ND ug/L 11/30/22 21:48 179601-23-12.0 0.71 1
o-Xylene ND ug/L 11/30/22 21:48 95-47-61.0 0.34 1
Surrogates
4-Bromofluorobenzene (S)99 %11/30/22 21:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %11/30/22 21:48 17060-07-070-130 1
Toluene-d8 (S)105 %11/30/22 21:48 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:B-1 Lab ID:92638465003 Collected:11/28/22 11:30 Received:11/28/22 14:00 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-
C28)9.3 mg/kg 12/02/22 12:0612/01/22 14:087.2 5.1 1
Surrogates
n-Pentacosane (S)73 %12/02/22 12:06 629-99-212/01/22 14:0810-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/29/22 15:0811/29/22 11:2210.4 2.9 1
Surrogates
4-Bromofluorobenzene (S)97 %11/29/22 15:08 460-00-411/29/22 11:2266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 29.7 %11/29/22 16:54 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638465
22-431
Sample:B-2 Lab ID:92638465004 Collected:11/28/22 11:40 Received:11/28/22 14:00 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-
C28)ND mg/kg 12/02/22 12:2212/01/22 14:086.9 4.9 1
Surrogates
n-Pentacosane (S)77 %12/02/22 12:22 629-99-212/01/22 14:0810-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/29/22 15:5911/29/22 11:229.7 2.7 1
Surrogates
4-Bromofluorobenzene (S)96 %11/29/22 15:59 460-00-411/29/22 11:2266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 27.4 %11/29/22 16:55 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739756
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638465003, 92638465004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3848892
Associated Lab Samples:92638465003, 92638465004
Matrix:Solid
AnalyzedMDL
Gas Range Organics (C6-C10)mg/kg ND 6.0 11/29/22 13:501.7
4-Bromofluorobenzene (S)%96 66-130 11/29/22 13:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3848893LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 61.350.1 122 70-130
4-Bromofluorobenzene (S)%97 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3848895MATRIX SPIKE SAMPLE:
MSSpike
Result
92638465004
Gas Range Organics (C6-C10)mg/kg 91.380.9 112 65-146ND
4-Bromofluorobenzene (S)%97 66-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638465003
3848894SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%9897
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739908
EPA 8260D
EPA 8260D
8260D MSV Low Level
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638465001, 92638465002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3849927
Associated Lab Samples:92638465001, 92638465002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 11/30/22 18:040.31
1,1,1-Trichloroethane ug/L ND 1.0 11/30/22 18:040.33
1,1,2,2-Tetrachloroethane ug/L ND 1.0 11/30/22 18:040.22
1,1,2-Trichloroethane ug/L ND 1.0 11/30/22 18:040.32
1,1-Dichloroethane ug/L ND 1.0 11/30/22 18:040.37
1,1-Dichloroethene ug/L ND 1.0 11/30/22 18:040.35
1,1-Dichloropropene ug/L ND 1.0 11/30/22 18:040.43
1,2,3-Trichlorobenzene ug/L ND 1.0 11/30/22 18:040.81
1,2,3-Trichloropropane ug/L ND 1.0 11/30/22 18:040.26
1,2,4-Trichlorobenzene ug/L ND 1.0 11/30/22 18:040.64
1,2-Dibromo-3-chloropropane ug/L ND 2.0 11/30/22 18:040.34
1,2-Dibromoethane (EDB)ug/L ND 1.0 11/30/22 18:040.27
1,2-Dichlorobenzene ug/L ND 1.0 11/30/22 18:040.34
1,2-Dichloroethane ug/L ND 1.0 11/30/22 18:040.32
1,2-Dichloropropane ug/L ND 1.0 11/30/22 18:040.36
1,3-Dichlorobenzene ug/L ND 1.0 11/30/22 18:040.34
1,3-Dichloropropane ug/L ND 1.0 11/30/22 18:040.28
1,4-Dichlorobenzene ug/L ND 1.0 11/30/22 18:040.33
2,2-Dichloropropane ug/L ND 1.0 11/30/22 18:040.39
2-Butanone (MEK)ug/L ND 5.0 v111/30/22 18:044.0
2-Chlorotoluene ug/L ND 1.0 11/30/22 18:040.32
2-Hexanone ug/L ND 5.0 11/30/22 18:040.48
4-Chlorotoluene ug/L ND 1.0 11/30/22 18:040.32
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 11/30/22 18:042.7
Acetone ug/L ND 25.0 11/30/22 18:045.1
Benzene ug/L ND 1.0 11/30/22 18:040.34
Bromobenzene ug/L ND 1.0 11/30/22 18:040.29
Bromochloromethane ug/L ND 1.0 11/30/22 18:040.47
Bromodichloromethane ug/L ND 1.0 11/30/22 18:040.31
Bromoform ug/L ND 1.0 11/30/22 18:040.34
Bromomethane ug/L ND 2.0 11/30/22 18:041.7
Carbon tetrachloride ug/L ND 1.0 11/30/22 18:040.33
Chlorobenzene ug/L ND 1.0 11/30/22 18:040.28
Chloroethane ug/L ND 1.0 11/30/22 18:040.65
Chloroform ug/L ND 1.0 11/30/22 18:040.43
Chloromethane ug/L ND 1.0 11/30/22 18:040.54
cis-1,2-Dichloroethene ug/L ND 1.0 11/30/22 18:040.38
cis-1,3-Dichloropropene ug/L ND 1.0 11/30/22 18:040.36
Dibromochloromethane ug/L ND 1.0 11/30/22 18:040.36
Dibromomethane ug/L ND 1.0 11/30/22 18:040.39
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3849927
Associated Lab Samples:92638465001, 92638465002
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L ND 1.0 11/30/22 18:040.35
Diisopropyl ether ug/L ND 1.0 11/30/22 18:040.31
Ethylbenzene ug/L ND 1.0 11/30/22 18:040.30
Hexachloro-1,3-butadiene ug/L ND 2.0 11/30/22 18:041.5
m&p-Xylene ug/L ND 2.0 11/30/22 18:040.71
Methyl-tert-butyl ether ug/L ND 1.0 11/30/22 18:040.42
Methylene Chloride ug/L ND 5.0 11/30/22 18:042.0
Naphthalene ug/L ND 1.0 11/30/22 18:040.64
o-Xylene ug/L ND 1.0 11/30/22 18:040.34
p-Isopropyltoluene ug/L ND 1.0 11/30/22 18:040.41
Styrene ug/L ND 1.0 11/30/22 18:040.29
Tetrachloroethene ug/L ND 1.0 11/30/22 18:040.29
Toluene ug/L ND 1.0 11/30/22 18:040.24
trans-1,2-Dichloroethene ug/L ND 1.0 11/30/22 18:040.40
trans-1,3-Dichloropropene ug/L ND 1.0 11/30/22 18:040.36
Trichloroethene ug/L ND 1.0 11/30/22 18:040.38
Trichlorofluoromethane ug/L ND 1.0 11/30/22 18:040.30
Vinyl acetate ug/L ND 2.0 v111/30/22 18:041.3
Vinyl chloride ug/L ND 1.0 11/30/22 18:040.39
Xylene (Total)ug/L ND 1.0 11/30/22 18:040.34
1,2-Dichloroethane-d4 (S)%106 70-130 11/30/22 18:04
4-Bromofluorobenzene (S)%101 70-130 11/30/22 18:04
Toluene-d8 (S)%108 70-130 11/30/22 18:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3849928LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 53.050 106 70-130
1,1,1-Trichloroethane ug/L 54.550 109 70-130
1,1,2,2-Tetrachloroethane ug/L 53.350 107 70-130
1,1,2-Trichloroethane ug/L 55.450 111 70-130
1,1-Dichloroethane ug/L 53.250 106 70-130
1,1-Dichloroethene ug/L 53.750 107 70-130
1,1-Dichloropropene ug/L 61.550 123 70-130
1,2,3-Trichlorobenzene ug/L 51.050 102 70-130
1,2,3-Trichloropropane ug/L 50.450 101 70-130
1,2,4-Trichlorobenzene ug/L 49.950 100 70-130
1,2-Dibromo-3-chloropropane ug/L 53.050 106 70-131
1,2-Dibromoethane (EDB)ug/L 54.650 109 70-130
1,2-Dichlorobenzene ug/L 50.350 101 70-130
1,2-Dichloroethane ug/L 55.750 111 70-130
1,2-Dichloropropane ug/L 52.650 105 70-130
1,3-Dichlorobenzene ug/L 50.550 101 70-130
1,3-Dichloropropane ug/L 50.750 101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3849928LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dichlorobenzene ug/L 50.250 100 70-130
2,2-Dichloropropane ug/L 53.750 107 68-135
2-Butanone (MEK)ug/L 125 v110012570-134
2-Chlorotoluene ug/L 51.450 103 70-130
2-Hexanone ug/L 112100 112 70-131
4-Chlorotoluene ug/L 50.250 100 70-130
4-Methyl-2-pentanone (MIBK)ug/L 115100 115 70-130
Acetone ug/L 113100 113 70-133
Benzene ug/L 50.850 102 70-130
Bromobenzene ug/L 50.550 101 70-130
Bromochloromethane ug/L 55.550 111 70-130
Bromodichloromethane ug/L 52.450 105 70-130
Bromoform ug/L 53.450 107 70-130
Bromomethane ug/L 50.350 101 45-151
Carbon tetrachloride ug/L 50.350 101 70-130
Chlorobenzene ug/L 51.050 102 70-130
Chloroethane ug/L 55.450 111 39-152
Chloroform ug/L 54.550 109 70-130
Chloromethane ug/L 55.950 112 58-130
cis-1,2-Dichloroethene ug/L 54.850 110 70-130
cis-1,3-Dichloropropene ug/L 56.150 112 70-130
Dibromochloromethane ug/L 52.250 104 70-130
Dibromomethane ug/L 52.650 105 70-130
Dichlorodifluoromethane ug/L 50.450 101 54-133
Diisopropyl ether ug/L 60.250 120 70-130
Ethylbenzene ug/L 50.550 101 70-130
Hexachloro-1,3-butadiene ug/L 49.650 99 70-135
m&p-Xylene ug/L 102100 102 70-130
Methyl-tert-butyl ether ug/L 61.050 122 70-130
Methylene Chloride ug/L 53.450 107 66-130
Naphthalene ug/L 55.150 110 70-130
o-Xylene ug/L 50.950 102 70-130
p-Isopropyltoluene ug/L 51.750 103 70-130
Styrene ug/L 53.750 107 70-130
Tetrachloroethene ug/L 51.550 103 70-130
Toluene ug/L 50.950 102 70-130
trans-1,2-Dichloroethene ug/L 53.950 108 70-130
trans-1,3-Dichloropropene ug/L 56.650 113 70-130
Trichloroethene ug/L 53.150 106 70-130
Trichlorofluoromethane ug/L 52.850 106 62-130
Vinyl acetate ug/L 129 v110012970-144
Vinyl chloride ug/L 54.650 109 62-130
Xylene (Total)ug/L 153150 102 70-130
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3849929MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92638681006
3849930
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 114 70-141119 4 3020ND22.9 23.8
1,1,1-Trichloroethane ug/L 20 122 70-150125 3 3020ND24.4 25.1
1,1,2,2-Tetrachloroethane ug/L 20 110 69-142112 2 3020ND21.9 22.4
1,1,2-Trichloroethane ug/L 20 125 70-138132 5 3020ND25.0 26.3
1,1-Dichloroethane ug/L 20 121 70-150129 6 3020ND24.2 25.7
1,1-Dichloroethene ug/L 20 107 70-156111 4 30202.3 23.6 24.5
1,1-Dichloropropene ug/L 20 127 70-150136 6 3020ND25.4 27.1
1,2,3-Trichlorobenzene ug/L 20 110 70-148116 5 3020ND22.0 23.2
1,2,3-Trichloropropane ug/L 20 106 70-140108 2 3020ND21.2 21.6
1,2,4-Trichlorobenzene ug/L 20 109 70-146111 2 3020ND21.9 22.3
1,2-Dibromo-3-
chloropropane ug/L 20 112 68-146111 1 3020ND22.5 22.1
1,2-Dibromoethane (EDB)ug/L 20 113 70-138119 5 3020ND22.6 23.9
1,2-Dichlorobenzene ug/L 20 102 70-141103 1 3020ND20.5 20.7
1,2-Dichloroethane ug/L 20 113 69-143122 7 30200.91J 23.5 25.3
1,2-Dichloropropane ug/L 20 117 68-156125 7 3020ND23.4 25.0
1,3-Dichlorobenzene ug/L 20 105 70-143106 1 3020ND21.0 21.2
1,3-Dichloropropane ug/L 20 110 70-138114 4 3020ND21.9 22.8
1,4-Dichlorobenzene ug/L 20 102 70-142103 0 3020ND20.4 20.5
2,2-Dichloropropane ug/L 20 129 52-170132 2 3020ND25.9 26.4
2-Butanone (MEK)ug/L 40 123 60-157130 5 3040ND49.3 52.0
2-Chlorotoluene ug/L 20 97 70-147100 4 3020ND19.3 20.1
2-Hexanone ug/L 40 107 68-146113 5 3040ND42.8 45.0
4-Chlorotoluene ug/L 20 97 70-14299 2 3020ND19.5 19.8
4-Methyl-2-pentanone
(MIBK)ug/L 40 112 70-141120 7 3040ND44.8 47.9
Acetone ug/L 40 110 58-157117 6 3040ND44.1 47.0
Benzene ug/L 20 112 70-142116 4 3020ND22.3 23.2
Bromobenzene ug/L 20 107 70-143109 2 3020ND21.5 21.9
Bromochloromethane ug/L 20 124 70-146132 6 3020ND24.8 26.4
Bromodichloromethane ug/L 20 119 70-139123 3 3020ND23.8 24.6
Bromoform ug/L 20 116 64-140120 4 3020ND23.2 24.0
Bromomethane ug/L 20 79 28-19286 8 3020ND15.8 17.1
Carbon tetrachloride ug/L 20 116 70-148121 4 3020ND23.2 24.1
Chlorobenzene ug/L 20 113 70-141115 2 3020ND22.5 23.0
Chloroethane ug/L 20 104 58-191108 4 3020ND20.7 21.5
Chloroform ug/L 20 119 70-148130 8 3020ND23.9 26.0
Chloromethane ug/L 20 67 43-16270 4 3020ND13.4 14.0
cis-1,2-Dichloroethene ug/L 20 123 68-151127 3 3020ND24.6 25.3
cis-1,3-Dichloropropene ug/L 20 123 70-139128 4 3020ND24.5 25.6
Dibromochloromethane ug/L 20 117 70-144120 3 3020ND23.3 24.0
Dibromomethane ug/L 20 128 70-139133 4 3020ND25.5 26.7
Dichlorodifluoromethane ug/L M1202939-17129 1 3020ND5.8 5.9
Diisopropyl ether ug/L 20 118 67-142129 9 3020ND23.6 25.7
Ethylbenzene ug/L 20 105 70-143109 4 3020ND20.9 21.8
Hexachloro-1,3-butadiene ug/L 20 127 64-163130 2 3020ND25.5 26.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3849929MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92638681006
3849930
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
m&p-Xylene ug/L 40 105 70-144107 3 3040ND41.8 43.0
Methyl-tert-butyl ether ug/L 20 122 65-143132 8 3020ND24.4 26.5
Methylene Chloride ug/L 20 111 62-149118 6 3020ND22.3 23.6
Naphthalene ug/L 20 102 67-147106 5 3020ND20.3 21.3
o-Xylene ug/L 20 110 70-145111 2 3020ND22.0 22.3
p-Isopropyltoluene ug/L 20 106 70-147112 5 3020ND21.3 22.4
Styrene ug/L 20 110 70-143113 3 3020ND22.0 22.7
Tetrachloroethene ug/L 20 128 70-145132 1 302040.7 66.4 67.1
Toluene ug/L 20 113 70-142118 4 3020ND22.7 23.6
trans-1,2-Dichloroethene ug/L 20 121 70-151124 3 3020ND24.1 24.8
trans-1,3-Dichloropropene ug/L 20 123 70-139127 3 3020ND24.7 25.4
Trichloroethene ug/L 20 131 62-146135 3 3020ND26.2 27.0
Trichlorofluoromethane ug/L 20 95 63-15396 1 3020ND19.0 19.3
Vinyl acetate ug/L 40 124 61-162133 7 3040ND49.5 53.0
Vinyl chloride ug/L 20 82 61-16388 6 3020ND16.5 17.5
Xylene (Total)ug/L 60 106 70-143109 2 3060ND63.8 65.3
1,2-Dichloroethane-d4 (S)%89 70-13087
4-Bromofluorobenzene (S)%98 70-13097
Toluene-d8 (S)%98 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
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[phone]
Page 20 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
740411
EPA 3546
EPA 8015C
8015 Solid GCSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638465003, 92638465004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3852048
Associated Lab Samples:92638465003, 92638465004
Matrix:Solid
AnalyzedMDL
Diesel Range Organics(C10-C28)mg/kg ND 5.0 12/02/22 11:333.5
n-Pentacosane (S)%89 10-130 12/02/22 11:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3852049LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 61.366.9 92 44-130
n-Pentacosane (S)%91 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3852050MATRIX SPIKE SAMPLE:
MSSpike
Result
92638412001
Diesel Range Organics(C10-C28)mg/kg 78.080.2 80 10-13013.7
n-Pentacosane (S)%89 10-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638465003
3852051SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg 5.6J 309.3
n-Pentacosane (S)%8073
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739726
EPA 3510C
EPA 8270E
8270E Water MSSV RVE
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638465001, 92638465002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3848772
Associated Lab Samples:92638465001, 92638465002
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 10.0 11/29/22 20:521.7
1,2-Dichlorobenzene ug/L ND 10.0 11/29/22 20:521.8
1,3-Dichlorobenzene ug/L ND 10.0 11/29/22 20:521.6
1,4-Dichlorobenzene ug/L ND 10.0 11/29/22 20:521.7
1-Methylnaphthalene ug/L ND 10.0 11/29/22 20:522.0
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 11/29/22 20:521.2
2,4,5-Trichlorophenol ug/L ND 10.0 11/29/22 20:521.4
2,4,6-Trichlorophenol ug/L ND 10.0 11/29/22 20:521.6
2,4-Dichlorophenol ug/L ND 10.0 11/29/22 20:521.4
2,4-Dimethylphenol ug/L ND 10.0 v211/29/22 20:521.7
2,4-Dinitrophenol ug/L ND 50.0 11/29/22 20:5226.0
2,4-Dinitrotoluene ug/L ND 10.0 11/29/22 20:521.6
2,6-Dinitrotoluene ug/L ND 10.0 11/29/22 20:521.7
2-Chloronaphthalene ug/L ND 10.0 11/29/22 20:521.7
2-Chlorophenol ug/L ND 10.0 11/29/22 20:521.2
2-Methylnaphthalene ug/L ND 10.0 11/29/22 20:521.9
2-Methylphenol(o-Cresol)ug/L ND 10.0 11/29/22 20:521.9
2-Nitroaniline ug/L ND 20.0 11/29/22 20:523.0
2-Nitrophenol ug/L ND 10.0 11/29/22 20:521.4
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 11/29/22 20:521.2
3,3'-Dichlorobenzidine ug/L ND 20.0 11/29/22 20:528.1
3-Nitroaniline ug/L ND 20.0 11/29/22 20:523.8
4,6-Dinitro-2-methylphenol ug/L ND 20.0 11/29/22 20:527.8
4-Bromophenylphenyl ether ug/L ND 10.0 11/29/22 20:521.8
4-Chloro-3-methylphenol ug/L ND 10.0 11/29/22 20:523.3
4-Chloroaniline ug/L ND 20.0 11/29/22 20:523.6
4-Chlorophenylphenyl ether ug/L ND 10.0 11/29/22 20:522.0
4-Nitroaniline ug/L ND 20.0 11/29/22 20:525.1
4-Nitrophenol ug/L ND 50.0 11/29/22 20:526.6
Acenaphthene ug/L ND 10.0 11/29/22 20:522.0
Acenaphthylene ug/L ND 10.0 11/29/22 20:522.0
Aniline ug/L ND 10.0 11/29/22 20:521.6
Anthracene ug/L ND 10.0 11/29/22 20:522.3
Benzo(a)anthracene ug/L ND 10.0 11/29/22 20:522.7
Benzo(a)pyrene ug/L ND 10.0 11/29/22 20:522.8
Benzo(b)fluoranthene ug/L ND 10.0 11/29/22 20:522.6
Benzo(g,h,i)perylene ug/L ND 10.0 11/29/22 20:522.8
Benzo(k)fluoranthene ug/L ND 10.0 11/29/22 20:522.7
Benzoic Acid ug/L ND 50.0 11/29/22 20:5222.0
Benzyl alcohol ug/L ND 20.0 11/29/22 20:522.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3848772
Associated Lab Samples:92638465001, 92638465002
Matrix:Water
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/L ND 10.0 11/29/22 20:521.8
bis(2-Chloroethyl) ether ug/L ND 10.0 11/29/22 20:521.9
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 11/29/22 20:523.7
Butylbenzylphthalate ug/L ND 10.0 11/29/22 20:523.1
Chrysene ug/L ND 10.0 11/29/22 20:522.8
Di-n-butylphthalate ug/L ND 10.0 11/29/22 20:522.2
Di-n-octylphthalate ug/L ND 10.0 11/29/22 20:523.9
Dibenz(a,h)anthracene ug/L ND 10.0 11/29/22 20:523.0
Dibenzofuran ug/L ND 10.0 11/29/22 20:522.1
Diethylphthalate ug/L ND 10.0 11/29/22 20:522.0
Dimethylphthalate ug/L ND 10.0 11/29/22 20:522.1
Fluoranthene ug/L ND 10.0 11/29/22 20:522.2
Fluorene ug/L ND 10.0 11/29/22 20:522.1
Hexachloro-1,3-butadiene ug/L ND 10.0 11/29/22 20:521.8
Hexachlorobenzene ug/L ND 10.0 11/29/22 20:522.2
Hexachlorocyclopentadiene ug/L ND 10.0 11/29/22 20:521.6
Hexachloroethane ug/L ND 10.0 11/29/22 20:521.4
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 11/29/22 20:522.9
Isophorone ug/L ND 10.0 11/29/22 20:521.7
N-Nitroso-di-n-propylamine ug/L ND 10.0 11/29/22 20:521.3
N-Nitrosodimethylamine ug/L ND 10.0 11/29/22 20:521.9
N-Nitrosodiphenylamine ug/L ND 10.0 11/29/22 20:523.0
Naphthalene ug/L ND 10.0 11/29/22 20:522.1
Nitrobenzene ug/L ND 10.0 11/29/22 20:521.9
Pentachlorophenol ug/L ND 20.0 11/29/22 20:523.8
Phenanthrene ug/L ND 10.0 11/29/22 20:522.0
Phenol ug/L ND 10.0 11/29/22 20:521.4
Pyrene ug/L ND 10.0 11/29/22 20:522.2
2,4,6-Tribromophenol (S)%62 10-144 11/29/22 20:52
2-Fluorobiphenyl (S)%83 10-130 11/29/22 20:52
2-Fluorophenol (S)%39 10-130 11/29/22 20:52
Nitrobenzene-d5 (S)%73 10-144 11/29/22 20:52
Phenol-d6 (S)%36 10-130 11/29/22 20:52
Terphenyl-d14 (S)%127 34-163 11/29/22 20:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3848773LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 32.550 65 18-130
1,2-Dichlorobenzene ug/L 27.550 55 20-130
1,3-Dichlorobenzene ug/L 25.350 51 18-130
1,4-Dichlorobenzene ug/L 25.550 51 18-130
1-Methylnaphthalene ug/L 40.650 81 29-130
2,2'-Oxybis(1-chloropropane)ug/L 24.450 49 28-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3848773LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-Trichlorophenol ug/L 45.850 92 35-130
2,4,6-Trichlorophenol ug/L 41.550 83 31-130
2,4-Dichlorophenol ug/L 40.450 81 35-130
2,4-Dimethylphenol ug/L 43.0 v3508634-130
2,4-Dinitrophenol ug/L 76.0250 30 10-153
2,4-Dinitrotoluene ug/L 46.250 92 37-136
2,6-Dinitrotoluene ug/L 48.350 97 33-136
2-Chloronaphthalene ug/L 42.850 86 26-130
2-Chlorophenol ug/L 34.150 68 37-130
2-Methylnaphthalene ug/L 38.650 77 29-130
2-Methylphenol(o-Cresol)ug/L 34.550 69 35-130
2-Nitroaniline ug/L 69.9100 70 37-130
2-Nitrophenol ug/L 38.850 78 32-130
3&4-Methylphenol(m&p Cresol)ug/L 31.650 63 34-130
3,3'-Dichlorobenzidine ug/L 93.4100 93 34-136
3-Nitroaniline ug/L 87.8100 88 37-138
4,6-Dinitro-2-methylphenol ug/L 65.4100 65 21-157
4-Bromophenylphenyl ether ug/L 47.050 94 38-130
4-Chloro-3-methylphenol ug/L 78.9100 79 37-130
4-Chloroaniline ug/L 77.3100 77 38-130
4-Chlorophenylphenyl ether ug/L 43.150 86 33-130
4-Nitroaniline ug/L 79.5100 80 42-137
4-Nitrophenol ug/L 54.1250 22 10-130
Acenaphthene ug/L 45.750 91 33-130
Acenaphthylene ug/L 45.150 90 35-130
Aniline ug/L 27.850 56 22-130
Anthracene ug/L 46.450 93 48-130
Benzo(a)anthracene ug/L 49.450 99 48-137
Benzo(a)pyrene ug/L 48.050 96 49-138
Benzo(b)fluoranthene ug/L 49.950 100 52-138
Benzo(g,h,i)perylene ug/L 47.150 94 48-140
Benzo(k)fluoranthene ug/L 51.550 103 48-139
Benzoic Acid ug/L 47.5J250 19 10-130
Benzyl alcohol ug/L 69.1100 69 35-130
bis(2-Chloroethoxy)methane ug/L 39.250 78 34-130
bis(2-Chloroethyl) ether ug/L 34.350 69 36-130
bis(2-Ethylhexyl)phthalate ug/L 54.550 109 32-165
Butylbenzylphthalate ug/L 54.650 109 34-161
Chrysene ug/L 50.650 101 47-131
Di-n-butylphthalate ug/L 46.350 93 39-144
Di-n-octylphthalate ug/L 53.250 106 30-170
Dibenz(a,h)anthracene ug/L 47.450 95 49-138
Dibenzofuran ug/L 45.450 91 33-130
Diethylphthalate ug/L 45.350 91 38-131
Dimethylphthalate ug/L 45.150 90 37-130
Fluoranthene ug/L 47.350 95 46-137
Fluorene ug/L 46.050 92 37-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3848773LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachloro-1,3-butadiene ug/L 27.950 56 11-130
Hexachlorobenzene ug/L 47.750 95 38-130
Hexachlorocyclopentadiene ug/L 34.550 69 10-130
Hexachloroethane ug/L 25.450 51 14-130
Indeno(1,2,3-cd)pyrene ug/L 48.750 97 41-130
Isophorone ug/L 39.350 79 33-130
N-Nitroso-di-n-propylamine ug/L 37.950 76 36-130
N-Nitrosodimethylamine ug/L 34.850 70 34-130
N-Nitrosodiphenylamine ug/L 49.750 99 37-130
Naphthalene ug/L 34.050 68 30-130
Nitrobenzene ug/L 35.850 72 36-130
Pentachlorophenol ug/L 75.0100 75 23-149
Phenanthrene ug/L 49.450 99 44-130
Phenol ug/L 22.150 44 18-130
Pyrene ug/L 56.750 113 47-134
2,4,6-Tribromophenol (S)%104 10-144
2-Fluorobiphenyl (S)%86 10-130
2-Fluorophenol (S)%54 10-130
Nitrobenzene-d5 (S)%78 10-144
Phenol-d6 (S)%47 10-130
Terphenyl-d14 (S)%118 34-163
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3848774MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92638465001
3848775
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L R190.9 61 10-13030 68 3090.9ND 55.5 27.2
1,2-Dichlorobenzene ug/L 90.9 46 10-13015 3090.9ND 42.0 13.6J
1,3-Dichlorobenzene ug/L 90.9 41 10-13013 3090.9ND 37.1 11.7J
1,4-Dichlorobenzene ug/L 90.9 44 10-13014 3090.9ND 40.2 12.5J
1-Methylnaphthalene ug/L R190.9 81 10-13058 32 3090.9ND 73.4 53.1
2,2'-Oxybis(1-
chloropropane)
ug/L R1,v2,
v3
90.9 50 12-14228 57 3090.9ND 45.8 25.5
2,4,5-Trichlorophenol ug/L R190.9 94 10-14332 99 3090.9ND 85.9 28.9
2,4,6-Trichlorophenol ug/L 90.9 90 10-14720 3090.9ND 81.4 18.0J
2,4-Dichlorophenol ug/L R190.9 90 10-13842 72 3090.9ND 81.6 38.3
2,4-Dimethylphenol ug/L 90.9 106 25-13091 16 3090.9ND 96.6 82.4
2,4-Dinitrophenol ug/L M14553310-1650 30455ND150ND
2,4-Dinitrotoluene ug/L 90.9 118 29-148107 10 3090.9ND 108 97.4
2,6-Dinitrotoluene ug/L 90.9 114 26-146107 7 3090.9ND 104 97.0
2-Chloronaphthalene ug/L 90.9 88 11-13068 26 3090.9ND 80.1 61.5
2-Chlorophenol ug/L R190.9 72 10-13331 80 3090.9ND 65.2 28.0
2-Methylnaphthalene ug/L R190.9 78 13-13054 36 3090.9ND 70.5 49.2
2-Methylphenol(o-Cresol)ug/L 90.9 71 20-13053 29 3090.9ND 64.7 48.4
2-Nitroaniline ug/L 182 92 24-13681 13 30182ND167147
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
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Page 25 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3848774MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92638465001
3848775
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Nitrophenol ug/L R1,v190.9 94 10-15332 98 3090.9ND 85.4 29.1
3&4-Methylphenol(m&p
Cresol)ug/L 90.9 64 16-13052 20 3090.9ND 57.9 47.3
3,3'-Dichlorobenzidine ug/L v118210610-153111 4 30182ND194202
3-Nitroaniline ug/L 182 106 22-15197 9 30182ND192176
4,6-Dinitro-2-methylphenol ug/L 182 65 10-18015 30182ND11926.5J
4-Bromophenylphenyl ether ug/L 90.9 94 25-13090 5 3090.9ND 85.7 81.7
4-Chloro-3-methylphenol ug/L 182 86 25-13374 16 30182ND157134
4-Chloroaniline ug/L 182 78 14-13271 10 30182ND142129
4-Chlorophenylphenyl ether ug/L 90.9 98 19-13084 15 3090.9ND 88.7 76.6
4-Nitroaniline ug/L 182 109 29-15094 15 30182ND198170
4-Nitrophenol ug/L M14552610-1300 30455ND118ND
Acenaphthene ug/L 90.9 92 16-13079 15 3090.9ND 83.5 71.6
Acenaphthylene ug/L 90.9 93 15-13779 16 3090.9ND 84.2 71.7
Aniline ug/L 90.9 50 10-13040 23 3090.9ND 45.2 36.0
Anthracene ug/L 90.9 96 37-13692 5 3090.9ND 87.6 83.3
Benzo(a)anthracene ug/L 90.9 101 40-145100 1 3090.9ND 91.7 91.2
Benzo(a)pyrene ug/L 90.9 103 41-14699 4 3090.9ND 93.7 89.7
Benzo(b)fluoranthene ug/L 90.9 99 39-15193 6 3090.9ND 89.6 84.2
Benzo(g,h,i)perylene ug/L 90.9 112 40-147106 6 3090.9ND 102 96.1
Benzo(k)fluoranthene ug/L 90.9 105 40-146103 2 3090.9ND 95.3 93.8
Benzoic Acid ug/L M1,v2,
v3455910-1300 30455NDNDND
Benzyl alcohol ug/L 182 74 25-13058 25 30182ND134105
bis(2-
Chloroethoxy)methane ug/L 90.9 76 23-13059 26 3090.9ND 69.2 53.4
bis(2-Chloroethyl) ether ug/L R190.9 79 25-13047 50 3090.9ND 71.6 42.9
bis(2-Ethylhexyl)phthalate ug/L 90.9 114 28-166112 2 3090.9ND 104 102
Butylbenzylphthalate ug/L 90.9 118 33-165112 5 3090.9ND 107 101
Chrysene ug/L 90.9 102 38-141103 1 3090.9ND 92.6 93.9
Di-n-butylphthalate ug/L 90.9 113 32-153107 5 3090.9ND 102 97.4
Di-n-octylphthalate ug/L 90.9 109 30-175108 1 3090.9ND 99.4 98.5
Dibenz(a,h)anthracene ug/L 90.9 116 39-148116 1 3090.9ND 106 105
Dibenzofuran ug/L 90.9 99 20-13085 15 3090.9ND 89.6 77.4
Diethylphthalate ug/L 90.9 110 28-14297 12 3090.9ND 99.7 88.6
Dimethylphthalate ug/L 90.9 104 26-13695 9 3090.9ND 94.9 86.8
Fluoranthene ug/L 90.9 110 39-143104 5 3090.9ND 99.9 94.6
Fluorene ug/L 90.9 101 24-13289 12 3090.9ND 91.9 81.4
Hexachloro-1,3-butadiene ug/L 90.9 51 10-13018 3090.9ND 46.8 16.7J
Hexachlorobenzene ug/L 90.9 106 29-130101 5 3090.9ND 96.8 91.9
Hexachlorocyclopentadiene ug/L R190.9 64 10-13034 60 3090.9ND 58.2 31.2
Hexachloroethane ug/L 90.9 38 10-13011 3090.9ND 34.8 9.6J
Indeno(1,2,3-cd)pyrene ug/L 90.9 119 39-148114 4 3090.9ND 108 104
Isophorone ug/L 90.9 84 23-13068 21 3090.9ND 76.5 62.0
N-Nitroso-di-n-propylamine ug/L R190.9 86 25-13063 32 3090.9ND 78.5 56.9
N-Nitrosodimethylamine ug/L 90.9 79 22-13059 29 3090.9ND 72.3 53.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3848774MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92638465001
3848775
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
N-Nitrosodiphenylamine ug/L 90.9 97 26-13495 3 3090.9ND 88.4 86.1
Naphthalene ug/L R190.9 62 14-13034 59 3090.9ND 56.7 30.7
Nitrobenzene ug/L R190.9 79 25-13052 41 3090.9ND 71.9 47.3
Pentachlorophenol ug/L M11826810-1759 30182ND12416.5J
Phenanthrene ug/L 90.9 100 36-13395 5 3090.9ND 90.9 86.3
Phenol ug/L R190.9 37 10-13024 41 3090.9ND 33.5 22.2
Pyrene ug/L 90.9 97 40-14395 2 3090.9ND 88.0 86.1
2,4,6-Tribromophenol (S)%125 10-14441
2-Fluorobiphenyl (S)%84 10-13056
2-Fluorophenol (S)%53 10-13013
Nitrobenzene-d5 (S)%78 10-14450
Phenol-d6 (S)%48 10-13032
Terphenyl-d14 (S)%105 34-163105
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638465
22-431
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739852
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638465003, 92638465004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638477001
3849543SAMPLE DUPLICATE:
Percent Moisture %7.3 N23257.0
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638482008
3849544SAMPLE DUPLICATE:
Percent Moisture %15.9 N242516.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
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Huntersville, NC 28078
[phone]
Page 28 of 33
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92638465
22-431
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
RPD value was outside control limits.R1
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 33
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92638465
22-431
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92638465003 740411 740770B-1 EPA 3546 EPA 8015C
92638465004 740411 740770B-2 EPA 3546 EPA 8015C
92638465003 739756 739813B-1 EPA 5030B EPA 8015C
92638465004 739756 739813B-2 EPA 5030B EPA 8015C
92638465001 739726 739887TW-1 EPA 3510C EPA 8270E
92638465002 739726 739887TW-2 EPA 3510C EPA 8270E
92638465001 739908TW-1 EPA 8260D
92638465002 739908TW-2 EPA 8260D
92638465003 739852B-1 SW-846
92638465004 739852B-2 SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:04 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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