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Home My WebLink AboutFA-96046_96933_CA_IAR_20230403 Initial Abatement Action Report GFL Environmental Inc. Stewart Road Ditch Remediation Wade, North Carolina Prepared for: GFL Environmental Inc. Fayetteville, North Carolina April 2023 Prepared by: © 2023 Smith Gardner, Inc. This document is intended for the sole use of the client for which it was prepared and for the purpose agreed upon by the client and Smith Gardner, Inc. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Initial Abatement Action Report GFL Environmental Inc. Stewart Road Ditch Remediation Wade, North Carolina Prepared For: GFL Environmental Inc. Fayetteville, North Carolina S+G Project No. GFL Wade 23-1 Lou J. Krasuski Staff Engineer Joan A. Smyth, P.G. Senior Hydrogeologist April 2023 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 4/3/2023 This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 GFL Environmental Inc. Ditch Remediation Initial Abatement Action Report April 2023 Table of Contents Page i GFL Environmental Inc. Stewart Road Ditch Remediation Wade, North Carolina Initial Abatement Action Report Table of Contents Page 1.0 OVERVIEW .................................................................................................................. 1 1.1 Regulatory Framework ........................................................................................... 1 1.2 Initial Site Assessment ........................................................................................... 1 1.2.1 Site Characterization .................................................................................. 1 1.2.2 Free Product Investigation .......................................................................... 2 1.2.3 Summary of Initial Response and Abatement Actions ............................... 2 2.0 REMEDIATION ............................................................................................................ 2 3.0 SOIL SAMPLING ......................................................................................................... 3 3.1 Results .................................................................................................................... 3 4.0 CONCLUSION ............................................................................................................. 3 FIGURES Figure 1 Site Location APPENDICES Appendix 1 Detected Constituents – GFL Wade Ditch Remediation Appendix 2 Laboratory Report DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 GFL Environmental Inc. Ditch Remediation Initial Abatement Action Report April 2023 Table of Contents Page ii This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 GFL Environmental Inc. Ditch Remediation Initial Abatement Action Report April 2023 Page 1 1.0 OVERVIEW GFL Environmental Inc. (GFL) received a Notice of Regulatory Requirements1 letter dated January 30, 2023 from the North Carolina Department of Environmental Quality (NCDEQ). The letter states that the Division of Waste Management (DWM) confirmed a release or discharge of petroleum near 4836 Stewart Road, in Wade, North Carolina, and based on information received on January 16, 2023 has determined GFL as the responsible party for the assessment and cleanup of the release or discharge. In late December of 2022, a residential waste collection vehicle released an unknown amount of hydraulic fluid at the above referenced location. After receiving the above reference letter, GFL contacted Smith Gardner Inc. to assist with an initial assessment and additional corrective actions. 1.1 Regulatory Framework The initial response and remediation actions were performed in accordance with 15A NCAC 02L .0504, Guidelines for Site Checks, Tank Closure, and Initial Response and Abatement, as well as Comprehensive Tables for Corrective Action Guidelines. Analytical methods for sampling following the release consist of EPA Method 8270 (EPA 8270) and Method for the Determination of Extractable Petroleum Hydrocarbons (MADEP EPH) per Table 3 Approved Soil Analyses Methods for Petroleum UST Closures, Over-Excavation and Site Checks in the Comprehensive Tables for Corrective Action Guidelines. 1.2 Initial Site Assessment 1.2.1 Site Characterization GFL personnel met with Lou Krasuski of Smith Gardner Inc. (S+G) on February 6, 2023 to initially assess the release and develop a remediation plan. It was determined the residential waste collection vehicle ruptured a hydraulic line outside of a residence while on a collection route, releasing an unknown amount of hydraulic fluid causing an “initial release”. The collection vehicle then pulled north on Stewart Road approximately 150’ as to not block the residence driveway. While waiting for a tow truck, an unknown amount of hydraulic fluid leaked from the line causing a “secondary release”. Cumberland County GIS2 indicates an Eastover public watermain running parallel to Stewart Road. NC OneMap3 shows zero (0) public water supply wells within a 2.5-mile radius of site. Given this information, it is assumed there were no drinking water wells in the vicinity of the release. 1NCDEQ Notice of Regulatory Requirements letter dated January 30, 2023. 2 Cumberland County GIS Data Viewer Powered by ESRI 3 NC OneMap Public Water Supply Water Sources DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 GFL Environmental Inc. Ditch Remediation Initial Abatement Action Report April 2023 Page 2 1.2.2 Free Product Investigation Two areas of discolored grass were noted at the locations of the releases, as well as an oily sheen on standing water within the ditch between the two releases. GFL personnel placed oil absorbent socks within the ditch to capture any remaining hydraulic fluid on the surface. On February 8, 2023, preliminary samples were taken at the site. To determine if soils had been impacted as well as to receive disposal approval, two (2) discrete composite samples of the initial spill locations and downstream locations were collected. Each soil sample was collected via a hand auger from a depth between six (6) to 10 inches below grade. Soil samples “P01 pre-ex” and “P02 pre-ex” were analyzed using EPA 8270 and MADEP EPH as indicated in Table 3 Approved Soil Analyses Methods for Petroleum UST Closures, Over-Excavation and Site Checks4 for their identified constituents by Waypoint Analytical (Waypoint), a North Carolina certified laboratory. To receive disposal approval from the Ann Street Subtitle D MSW Landfill (Ann St.), located in Fayetteville, North Carolina, the preliminary samples were also analyzed via a Toxicity Characteristic Leaching Procedure (TCLP). The results indicated the soil to be remediated was non-hazardous and approved for disposal at the Cumberland County Ann Street landfill. Results are summarized in Appendix 1, the full laboratory report is attached as Appendix 2. 1.2.3 Summary of Initial Response and Abatement Actions Following the release, GFL immediately contacted ERTS, a corporate partnered environmental response group, to respond to the release. Standing hydraulic fluid was cleaned up and removed, and properly disposed of. Oil absorbent was then placed in areas of the spills to soak up any remaining hydraulic fluid. Oil absorbent socks were also placed within the ditch to capture any remaining hydraulic fluid that may convene downstream. It was determined approximately 300-feet of ditch, approximately four feet wide, and six (6) to 12-inches deep would be remediated and replaced with clean fill material. 2.0 REMEDIATION Capital Construction Company (CapCon) mobilized to the site on March 7, 2023 to conduct the ditch remediation. A four-foot-wide area, varying six (6) to twelve (12) inches deep, within a 300’ section of ditch along Stewart Road was excavated for remediation purposes. A total of approximately 25 cubic yards of material was removed from the ditch and adjacent spill locations. Removed material was taken to the Cumberland County Ann Street landfill for 4 Comprehensive Tables for Corrective Action Guidelines, September 7, 2022 Version, Change 5 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 GFL Environmental Inc. Ditch Remediation Initial Abatement Action Report April 2023 Page 3 approved disposal within the Subtitle D lined landfill. Soils remaining in the ditch after removal were sampled to evaluate whether all impacted soils were removed. Soil sample collection and analysis is summarized in Section 3.0 below. The remediated material was then replaced with clean fill material that came from the Cumberland County Ann Street facility. The compacted clean material was then reseeded and a single net erosion control blanket stapled on top of the remediated areas. 3.0 SOIL SAMPLING During the remediation, S+G personnel mobilized to the site. To evaluate soil quality and determine if contaminated soils had been removed, five (5) grab samples were taken as shown on the attached Figure 1. Each soil sample was collected via a hand auger from a depth of approximately 12 to 18-inches below grade. Soil samples “Post-01” through “Post-05” were then analyzed via Waypoint, using EPA 8270 and MADEP EPH for their identified constituents. Results were was onsite to conduct soil samples. A total of five soil samples were taken in the remediation area as well as downstream. 3.1 Results Data was compared to both Soil-to-Water Maximum Contaminant Concentration and Residential Soil Cleanup Levels of the Maximum Soil Contaminant Concentration Levels (MSCCs)5. Of the constituents analyzed, only aliphatic C-19 to C-36 were detected in one soil sample after site remediation. The detected concentration is well below the residential soil clean-up levels. 4.0 CONCLUSION Site remediation activities, including initial spill clean-up followed by soil removal and replacement along a section of the drainage ditch where the spill occurred have been successful. Sampling of soils remaining after soil removal (and prior to placement of clean soil) indicate only one constituent (aliphatic C-19 to C-36) detected in the remaining soils. The concentrations of this constituent were well below residential clean-up goals. Based on this information, no further action should be required at this time. 5 Comprehensive Tables for Corrective Action Guidelines, September 7, 2022 Version, Change 5 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 GFL Environmental Inc. Ditch Remediation Initial Abatement Action Report April 2023 Page 4 This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Figure 1 Site Location Initial Abatement Action Report GFL Environmental Inc. Ditch Remediation Wade, North Carolina DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 This Page Intentionally Left Blank DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Appendix 1 Detected Constituents GFL Wade – Ditch Remediation Initial Abatement Action Report GFL Environmental Inc. Ditch Remediation Wade, North Carolina DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Table 1Hydraulic Release Sampling ResultsGFL Environmental Inc. Ditch RemediationMarch 2023By: LJKDate: 03/20/20232/7/2023 2/7/2023 3/8/2023 3/8/2023 3/8/2023 3/8/2023 3/8/2023Aliphatic C19-C36100NE#31200161 300BDL BDL193BDL BDLNote:Comprehensive Tables for Corrective Action Guidelines, September 7, 2022 Version, Change 5NA - Not AvailbleNE - No standard EstablishedBDL - Below Detection LimitJ - "J-qualified" defined by the laboratory as "Detected but below the Reporting Limit; therefore, result is an estimated concentration."Bold - concentrations above PSRG groundwater standard# -Health based level >100%Post-05Post-01ParameterEPA 8270 Minimum Reporting Limit, mg/kgMADEP EPHAction Level, mg/kgP01 pre-exP02pre-exSoil-to-Water Maximum Contaminant Concentrationmg/kgResidential Soil Cleanup Levelsmg/kgPost-02 Post-03 Post-04H:\Projects\GFL Environmental\GFL WADE-23-1\Sample Results\GFL Hydraulic Release Soil DataDocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Appendix 2 Laboratory Results Initial Abatement Action Report GFL Environmental Inc. Ditch Remediation Wade, North Carolina DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 This page intentionally left blank. DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. 2/27/2023 Smith & Gardner, Inc. Seth C. Rickerts 14 N. Boylan Avenue Raleigh, NC, 27603 Ref: Analytical Testing Lab Report Number: 23-040-0007 Client Project Description: GFL Wade Dear Seth C. Rickerts: Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/9/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date 02/28/202340750State ProgramAlabama 02/07/202388-0650State ProgramArkansas 06/30/20232904State ProgramCalifornia 06/30/2023E871157State Program - NELAPFlorida 02/18/2023C044State ProgramGeorgia 06/30/202304015State ProgramGeorgia 10/10/2023200078State Program - NELAPIllinois 06/30/202380215State ProgramKentucky 12/31/2023KY90047State ProgramKentucky 12/31/2023LA037State Program - NELAPLouisiana 06/30/202304015State Program - NELAPLouisiana 02/11/2023MSState ProgramMississippi 07/31/202347701State ProgramNorth Carolina 12/31/2023415State ProgramNorth Carolina 05/31/202368-03195State Program - NELAPPennsylvania 06/30/202384002State ProgramSouth Carolina 11/14/202502027State ProgramTennessee 09/30/2023T104704180State Program - NELAPTexas 06/30/202300106State ProgramVirginia 09/14/2023460181State Program - NELAPVirginia Page 1 of 1 00016/23-040-0007 Page 2 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Report Number: Sample Summary Table Client Project Description: 23-040-0007 GFL Wade Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 02/08/2023 09:30Solids 99278 P01 pre-ex 02/09/2023 10:10 02/08/2023 09:30Solids 99279 P02 pre-ex 02/09/2023 10:10 02/08/2023 09:30TCLP 99825 P01 pre-ex 02/09/2023 10:10 02/08/2023 09:30TCLP 99825 P01 pre-ex 02/09/2023 10:10 8270C WP MTN - 02/08/2023 09:30TCLP 99825 P01 pre-ex 02/09/2023 10:10 SW-1311 WP MTN - 02/08/2023 09:30TCLP 99826 P02 pre-ex 02/09/2023 10:10 02/08/2023 09:30TCLP 99826 P02 pre-ex 02/09/2023 10:10 SW-1311 WP MTN - 02/08/2023 09:30TCLP 99826 P02 pre-ex 02/09/2023 10:10 8270C WP MTN - WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-040-0007 Report Limit Project:GFL Wade V 99278P01 pre-ex 161 02/13/2023 15:56MADEP-EPH Aliphatic C19-C36 mg/Kg - dry 14.2 14.1 02/09/2023 16:38SW-DRYWT Moisture % V 99279P02 pre-ex 300 02/13/2023 16:32MADEP-EPH Aliphatic C19-C36 mg/Kg - dry 14.3 14.9 02/09/2023 16:38SW-DRYWT Moisture % V 99825P01 pre-ex Leachate 02/23/2023 14:30SW-1311 TCLP SVOC Extraction Leachate 02/16/2023 13:00SW-1311 (ZHE)TCLP VOC ZHE Extraction V 99826P02 pre-ex 0.392 02/17/2023 13:568260DTCLP Methyl Ethyl Ketone (MEK)mg/L 0.0078 Leachate 02/23/2023 14:30SW-1311 TCLP SVOC Extraction Leachate 02/16/2023 13:00SW-1311 (ZHE)TCLP VOC ZHE Extraction Page 4 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Client: Smith & Gardner, Inc. CASE NARRATIVE Project: GFL Wade Lab Report Number: 23-040-0007 Date: 2/27/2023 Semivolatile Organic Compounds - GC/MS Method 8270E Sample 98922 Analyte: Hexachloroethane QC Batch No: V29814/V29772 Matrix spike/matrix spike duplicate recoveries are outside of control limits. Acceptable LCS recovery indicates the system was in control, but the reported result could be affected by matrix interference. Page 5 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99278 Matrix: 2/8/2023 9:30 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 14.1 %Moisture 1 02/09/23 16:38 SW-DRYWTAMB Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 6 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99278 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.135 mg/Kg - dry 0.135 0.769Acenaphthene 1 02/15/23 19:44 V29814JMV <0.122 mg/Kg - dry 0.122 0.769 Acenaphthylene 1 02/15/23 19:44 V29814JMV <0.176 mg/Kg - dry 0.176 0.769Aniline 1 02/15/23 19:44 V29814JMV <0.166 mg/Kg - dry 0.166 0.769Anthracene 1 02/15/23 19:44 V29814JMV <0.161 mg/Kg - dry 0.161 0.769Benzo(a)anthracene 1 02/15/23 19:44 V29814JMV <0.171 mg/Kg - dry 0.171 0.769Benzo(a)pyrene 1 02/15/23 19:44 V29814JMV <0.169 mg/Kg - dry 0.169 0.769Benzo(b)fluoranthene 1 02/15/23 19:44 V29814JMV <0.158 mg/Kg - dry 0.158 0.769Benzo(g,h,i)perylene 1 02/15/23 19:44 V29814JMV <0.159 mg/Kg - dry 0.159 0.769 Benzo(k)fluoranthene 1 02/15/23 19:44 V29814JMV <0.675 mg/Kg - dry 0.675 2.33Benzoic Acid 1 02/15/23 19:44 V29814JMV <0.122 mg/Kg - dry 0.122 0.769Benzyl alcohol 1 02/15/23 19:44 V29814JMV <0.137 mg/Kg - dry 0.137 0.769Bis(2-Chloroethoxy)methane 1 02/15/23 19:44 V29814JMV <0.124 mg/Kg - dry 0.124 0.769Bis(2-Chloroethyl)ether 1 02/15/23 19:44 V29814JMV <0.158 mg/Kg - dry 0.158 0.385Bis(2-Chloroisopropyl)ether 1 02/15/23 19:44 V29814JMV <0.139 mg/Kg - dry 0.139 0.769Bis(2-ethylhexyl)phthalate 1 02/15/23 19:44 V29814JMV <0.126 mg/Kg - dry 0.126 0.7694-Bromophenyl phenyl ether 1 02/15/23 19:44 V29814JMV <0.131 mg/Kg - dry 0.131 0.385Butyl benzyl phthalate 1 02/15/23 19:44 V29814JMV <0.107 mg/Kg - dry 0.107 0.7694-Chloro-3-methylphenol 1 02/15/23 19:44 V29814JMV <0.130 mg/Kg - dry 0.130 0.3854-Chloroaniline 1 02/15/23 19:44 V29814JMV <0.135 mg/Kg - dry 0.135 0.7692-Chloronaphthalene 1 02/15/23 19:44 V29814JMV <0.114 mg/Kg - dry 0.114 0.7692-Chlorophenol 1 02/15/23 19:44 V29814JMV <0.146 mg/Kg - dry 0.146 1.164-Chlorophenyl phenyl ether 1 02/15/23 19:44 V29814JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 7 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99278 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.165 mg/Kg - dry 0.165 0.769Chrysene 1 02/15/23 19:44 V29814JMV <0.267 mg/Kg - dry 0.267 0.769 Dibenz(a,h)anthracene 1 02/15/23 19:44 V29814JMV <0.138 mg/Kg - dry 0.138 0.769Dibenzofuran 1 02/15/23 19:44 V29814JMV <0.110 mg/Kg - dry 0.110 0.7691,2-Dichlorobenzene 1 02/15/23 19:44 V29814JMV <0.113 mg/Kg - dry 0.113 0.7691,3-Dichlorobenzene 1 02/15/23 19:44 V29814JMV <0.113 mg/Kg - dry 0.113 0.3851,4-Dichlorobenzene 1 02/15/23 19:44 V29814JMV <0.171 mg/Kg - dry 0.171 0.7693,3'-Dichlorobenzidine 1 02/15/23 19:44 V29814JMV <0.111 mg/Kg - dry 0.111 0.7692,4-Dichlorophenol 1 02/15/23 19:44 V29814JMV <0.209 mg/Kg - dry 0.209 0.769 Diethyl phthalate 1 02/15/23 19:44 V29814JMV <0.202 mg/Kg - dry 0.202 0.769Dimethyl phthalate 1 02/15/23 19:44 V29814JMV <0.125 mg/Kg - dry 0.125 0.3852,4-Dimethylphenol 1 02/15/23 19:44 V29814JMV <0.124 mg/Kg - dry 0.124 0.769Di-n-butyl phthalate 1 02/15/23 19:44 V29814JMV <0.279 mg/Kg - dry 0.279 1.754,6-Dinitro-2-methylphenol 1 02/15/23 19:44 V29814JMV <0.605 mg/Kg - dry 0.605 1.752,4-Dinitrophenol 1 02/15/23 19:44 V29814JMV <0.112 mg/Kg - dry 0.112 0.7692,4-Dinitrotoluene 1 02/15/23 19:44 V29814JMV <0.125 mg/Kg - dry 0.125 0.7692,6-Dinitrotoluene 1 02/15/23 19:44 V29814JMV <0.166 mg/Kg - dry 0.166 0.385Di-n-Octyl Phthalate 1 02/15/23 19:44 V29814JMV <0.143 mg/Kg - dry 0.143 0.769Fluoranthene 1 02/15/23 19:44 V29814JMV <0.149 mg/Kg - dry 0.149 0.769Fluorene 1 02/15/23 19:44 V29814JMV <0.123 mg/Kg - dry 0.123 0.769Hexachlorobenzene 1 02/15/23 19:44 V29814JMV <0.113 mg/Kg - dry 0.113 0.769Hexachlorobutadiene 1 02/15/23 19:44 V29814JMV <0.182 mg/Kg - dry 0.182 0.769Hexachlorocyclopentadiene 1 02/15/23 19:44 V29814JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 8 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99278 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.092 mg/Kg - dry 0.092 0.769Hexachloroethane 1 02/15/23 19:44 V29814JMV <0.208 mg/Kg - dry 0.208 0.769 Indeno(1,2,3-cd)pyrene 1 02/15/23 19:44 V29814JMV <0.222 mg/Kg - dry 0.222 0.769Isophorone 1 02/15/23 19:44 V29814JMV <0.123 mg/Kg - dry 0.123 0.7691-Methylnaphthalene 1 02/15/23 19:44 V29814JMV <0.116 mg/Kg - dry 0.116 0.7692-Methylnaphthalene 1 02/15/23 19:44 V29814JMV <0.113 mg/Kg - dry 0.113 0.7692-Methylphenol 1 02/15/23 19:44 V29814JMV <0.098 mg/Kg - dry 0.098 0.7693&4 Methylphenol 1 02/15/23 19:44 V29814JMV <0.167 mg/Kg - dry 0.167 0.769Naphthalene 1 02/15/23 19:44 V29814JMV <0.112 mg/Kg - dry 0.112 0.769 2-Nitroaniline 1 02/15/23 19:44 V29814JMV <0.139 mg/Kg - dry 0.139 0.7693-Nitroaniline 1 02/15/23 19:44 V29814JMV <0.108 mg/Kg - dry 0.108 0.3854-Nitroaniline 1 02/15/23 19:44 V29814JMV <0.135 mg/Kg - dry 0.135 0.385Nitrobenzene 1 02/15/23 19:44 V29814JMV <0.103 mg/Kg - dry 0.103 0.7692-Nitrophenol 1 02/15/23 19:44 V29814JMV <0.136 mg/Kg - dry 0.136 0.7694-Nitrophenol 1 02/15/23 19:44 V29814JMV <0.306 mg/Kg - dry 0.306 0.769N-Nitrosodimethylamine 1 02/15/23 19:44 V29814JMV <0.210 mg/Kg - dry 0.210 0.769N-Nitrosodiphenylamine 1 02/15/23 19:44 V29814JMV <0.137 mg/Kg - dry 0.137 0.769N-Nitroso-di-n-propylamine 1 02/15/23 19:44 V29814JMV <0.403 mg/Kg - dry 0.403 1.16Pentachlorophenol 1 02/15/23 19:44 V29814JMV <0.242 mg/Kg - dry 0.242 0.769Phenanthrene 1 02/15/23 19:44 V29814JMV <0.130 mg/Kg - dry 0.130 0.769Phenol 1 02/15/23 19:44 V29814JMV <0.155 mg/Kg - dry 0.155 0.769Pyrene 1 02/15/23 19:44 V29814JMV <0.092 mg/Kg - dry 0.092 0.385Pyridine 1 02/15/23 19:44 V29814JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 9 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99278 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.124 mg/Kg - dry 0.124 0.7691,2,4-Trichlorobenzene 1 02/15/23 19:44 V29814JMV <0.112 mg/Kg - dry 0.112 0.769 2,4,5-Trichlorophenol 1 02/15/23 19:44 V29814JMV <0.112 mg/Kg - dry 0.112 0.7692,4,6-Trichlorophenol 1 02/15/23 19:44 V29814JMV 8270ESurrogate: Phenol-d5 68.3 Limits: 34-121%02/15/23 19:441 JMV Surrogate: 2-Fluorobiphenyl 89.2 Limits: 44-115%02/15/23 19:441 JMV V29814 Surrogate: 2-Fluorophenol 72.8 Limits: 35-115%02/15/23 19:441 JMV V29814 Surrogate: Nitrobenzene-d5 79.0 Limits: 37-122%02/15/23 19:441 JMV V29814 Surrogate: 4-Terphenyl-d14 95.2 Limits: 54-127%02/15/23 19:441 JMV V29814 Surrogate: 2,4,6-Tribromophenol 78.7 Limits: 39-132%02/15/23 19:441 JMV V29814 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 10 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99278 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V29676 02/10/23 10:45 <10.7 mg/Kg - dry 10.7 58.3Aliphatic C9-C18 1 02/13/23 15:56 V29727AMP 161 mg/Kg - dry 14.2 58.3 Aliphatic C19-C36 1 02/13/23 15:56 V29727AMP <16.5 mg/Kg - dry 16.5 58.3Aromatic C11-C22 1 02/13/23 15:56 V29727AMP MADEP-EPHSurrogate: 2-Bromonaphthalene 111 Limits: 40-140%02/13/23 15:561 AMP MADEP-EPHSurrogate: Chlorooctadecane 87.0 Limits: 40-140%02/13/23 15:561 AMP MADEP-EPHSurrogate: OTP Surrogate 90.5 Limits: 40-140%02/13/23 15:561 AMP Surrogate: 2-Fluorobiphenyl 114 Limits: 40-140%02/13/23 15:561 AMP V29727 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 11 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99279 Matrix: 2/8/2023 9:30 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 14.9 %Moisture 1 02/09/23 16:38 SW-DRYWTAMB Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 12 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99279 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.136 mg/Kg - dry 0.136 0.775Acenaphthene 1 02/15/23 16:22 V29814JMV <0.123 mg/Kg - dry 0.123 0.775 Acenaphthylene 1 02/15/23 16:22 V29814JMV <0.178 mg/Kg - dry 0.178 0.775Aniline 1 02/15/23 16:22 V29814JMV <0.168 mg/Kg - dry 0.168 0.775Anthracene 1 02/15/23 16:22 V29814JMV <0.163 mg/Kg - dry 0.163 0.775Benzo(a)anthracene 1 02/15/23 16:22 V29814JMV <0.172 mg/Kg - dry 0.172 0.775Benzo(a)pyrene 1 02/15/23 16:22 V29814JMV <0.171 mg/Kg - dry 0.171 0.775Benzo(b)fluoranthene 1 02/15/23 16:22 V29814JMV <0.159 mg/Kg - dry 0.159 0.775Benzo(g,h,i)perylene 1 02/15/23 16:22 V29814JMV <0.160 mg/Kg - dry 0.160 0.775 Benzo(k)fluoranthene 1 02/15/23 16:22 V29814JMV <0.681 mg/Kg - dry 0.681 2.35Benzoic Acid 1 02/15/23 16:22 V29814JMV <0.123 mg/Kg - dry 0.123 0.775Benzyl alcohol 1 02/15/23 16:22 V29814JMV <0.138 mg/Kg - dry 0.138 0.775Bis(2-Chloroethoxy)methane 1 02/15/23 16:22 V29814JMV <0.125 mg/Kg - dry 0.125 0.775Bis(2-Chloroethyl)ether 1 02/15/23 16:22 V29814JMV <0.159 mg/Kg - dry 0.159 0.387Bis(2-Chloroisopropyl)ether 1 02/15/23 16:22 V29814JMV <0.141 mg/Kg - dry 0.141 0.775Bis(2-ethylhexyl)phthalate 1 02/15/23 16:22 V29814JMV <0.128 mg/Kg - dry 0.128 0.7754-Bromophenyl phenyl ether 1 02/15/23 16:22 V29814JMV <0.132 mg/Kg - dry 0.132 0.387Butyl benzyl phthalate 1 02/15/23 16:22 V29814JMV <0.108 mg/Kg - dry 0.108 0.7754-Chloro-3-methylphenol 1 02/15/23 16:22 V29814JMV <0.131 mg/Kg - dry 0.131 0.3874-Chloroaniline 1 02/15/23 16:22 V29814JMV <0.136 mg/Kg - dry 0.136 0.7752-Chloronaphthalene 1 02/15/23 16:22 V29814JMV <0.115 mg/Kg - dry 0.115 0.7752-Chlorophenol 1 02/15/23 16:22 V29814JMV <0.148 mg/Kg - dry 0.148 1.184-Chlorophenyl phenyl ether 1 02/15/23 16:22 V29814JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 13 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99279 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.166 mg/Kg - dry 0.166 0.775Chrysene 1 02/15/23 16:22 V29814JMV <0.270 mg/Kg - dry 0.270 0.775 Dibenz(a,h)anthracene 1 02/15/23 16:22 V29814JMV <0.139 mg/Kg - dry 0.139 0.775Dibenzofuran 1 02/15/23 16:22 V29814JMV <0.110 mg/Kg - dry 0.110 0.7751,2-Dichlorobenzene 1 02/15/23 16:22 V29814JMV <0.114 mg/Kg - dry 0.114 0.7751,3-Dichlorobenzene 1 02/15/23 16:22 V29814JMV <0.114 mg/Kg - dry 0.114 0.3871,4-Dichlorobenzene 1 02/15/23 16:22 V29814JMV <0.172 mg/Kg - dry 0.172 0.7753,3'-Dichlorobenzidine 1 02/15/23 16:22 V29814JMV <0.112 mg/Kg - dry 0.112 0.7752,4-Dichlorophenol 1 02/15/23 16:22 V29814JMV <0.211 mg/Kg - dry 0.211 0.775 Diethyl phthalate 1 02/15/23 16:22 V29814JMV <0.204 mg/Kg - dry 0.204 0.775Dimethyl phthalate 1 02/15/23 16:22 V29814JMV <0.126 mg/Kg - dry 0.126 0.3872,4-Dimethylphenol 1 02/15/23 16:22 V29814JMV <0.125 mg/Kg - dry 0.125 0.775Di-n-butyl phthalate 1 02/15/23 16:22 V29814JMV <0.282 mg/Kg - dry 0.282 1.764,6-Dinitro-2-methylphenol 1 02/15/23 16:22 V29814JMV <0.611 mg/Kg - dry 0.611 1.762,4-Dinitrophenol 1 02/15/23 16:22 V29814JMV <0.113 mg/Kg - dry 0.113 0.7752,4-Dinitrotoluene 1 02/15/23 16:22 V29814JMV <0.126 mg/Kg - dry 0.126 0.7752,6-Dinitrotoluene 1 02/15/23 16:22 V29814JMV <0.168 mg/Kg - dry 0.168 0.387Di-n-Octyl Phthalate 1 02/15/23 16:22 V29814JMV <0.144 mg/Kg - dry 0.144 0.775Fluoranthene 1 02/15/23 16:22 V29814JMV <0.150 mg/Kg - dry 0.150 0.775Fluorene 1 02/15/23 16:22 V29814JMV <0.124 mg/Kg - dry 0.124 0.775Hexachlorobenzene 1 02/15/23 16:22 V29814JMV <0.114 mg/Kg - dry 0.114 0.775Hexachlorobutadiene 1 02/15/23 16:22 V29814JMV <0.184 mg/Kg - dry 0.184 0.775Hexachlorocyclopentadiene 1 02/15/23 16:22 V29814JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 14 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99279 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.093 mg/Kg - dry 0.093 0.775Hexachloroethane 1 02/15/23 16:22 V29814JMV <0.210 mg/Kg - dry 0.210 0.775 Indeno(1,2,3-cd)pyrene 1 02/15/23 16:22 V29814JMV <0.224 mg/Kg - dry 0.224 0.775Isophorone 1 02/15/23 16:22 V29814JMV <0.124 mg/Kg - dry 0.124 0.7751-Methylnaphthalene 1 02/15/23 16:22 V29814JMV <0.117 mg/Kg - dry 0.117 0.7752-Methylnaphthalene 1 02/15/23 16:22 V29814JMV <0.113 mg/Kg - dry 0.113 0.7752-Methylphenol 1 02/15/23 16:22 V29814JMV <0.099 mg/Kg - dry 0.099 0.7753&4 Methylphenol 1 02/15/23 16:22 V29814JMV <0.169 mg/Kg - dry 0.169 0.775Naphthalene 1 02/15/23 16:22 V29814JMV <0.113 mg/Kg - dry 0.113 0.775 2-Nitroaniline 1 02/15/23 16:22 V29814JMV <0.141 mg/Kg - dry 0.141 0.7753-Nitroaniline 1 02/15/23 16:22 V29814JMV <0.109 mg/Kg - dry 0.109 0.3874-Nitroaniline 1 02/15/23 16:22 V29814JMV <0.136 mg/Kg - dry 0.136 0.387Nitrobenzene 1 02/15/23 16:22 V29814JMV <0.104 mg/Kg - dry 0.104 0.7752-Nitrophenol 1 02/15/23 16:22 V29814JMV <0.137 mg/Kg - dry 0.137 0.7754-Nitrophenol 1 02/15/23 16:22 V29814JMV <0.309 mg/Kg - dry 0.309 0.775N-Nitrosodimethylamine 1 02/15/23 16:22 V29814JMV <0.212 mg/Kg - dry 0.212 0.775N-Nitrosodiphenylamine 1 02/15/23 16:22 V29814JMV <0.138 mg/Kg - dry 0.138 0.775N-Nitroso-di-n-propylamine 1 02/15/23 16:22 V29814JMV <0.407 mg/Kg - dry 0.407 1.18Pentachlorophenol 1 02/15/23 16:22 V29814JMV <0.244 mg/Kg - dry 0.244 0.775Phenanthrene 1 02/15/23 16:22 V29814JMV <0.131 mg/Kg - dry 0.131 0.775Phenol 1 02/15/23 16:22 V29814JMV <0.157 mg/Kg - dry 0.157 0.775Pyrene 1 02/15/23 16:22 V29814JMV <0.093 mg/Kg - dry 0.093 0.387Pyridine 1 02/15/23 16:22 V29814JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 15 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99279 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V29772 02/14/23 17:50 <0.125 mg/Kg - dry 0.125 0.7751,2,4-Trichlorobenzene 1 02/15/23 16:22 V29814JMV <0.113 mg/Kg - dry 0.113 0.775 2,4,5-Trichlorophenol 1 02/15/23 16:22 V29814JMV <0.113 mg/Kg - dry 0.113 0.7752,4,6-Trichlorophenol 1 02/15/23 16:22 V29814JMV 8270ESurrogate: Phenol-d5 58.9 Limits: 34-121%02/15/23 16:221 JMV Surrogate: 2-Fluorobiphenyl 76.6 Limits: 44-115%02/15/23 16:221 JMV V29814 Surrogate: 2-Fluorophenol 64.0 Limits: 35-115%02/15/23 16:221 JMV V29814 Surrogate: Nitrobenzene-d5 67.7 Limits: 37-122%02/15/23 16:221 JMV V29814 Surrogate: 4-Terphenyl-d14 87.4 Limits: 54-127%02/15/23 16:221 JMV V29814 Surrogate: 2,4,6-Tribromophenol 71.5 Limits: 39-132%02/15/23 16:221 JMV V29814 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 16 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99279 Matrix: 2/8/2023 9:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V29676 02/10/23 10:45 <10.8 mg/Kg - dry 10.8 58.9Aliphatic C9-C18 1 02/13/23 16:32 V29727AMP 300 mg/Kg - dry 14.3 58.9 Aliphatic C19-C36 1 02/13/23 16:32 V29727AMP <16.7 mg/Kg - dry 16.7 58.9Aromatic C11-C22 1 02/13/23 16:32 V29727AMP MADEP-EPHSurrogate: 2-Bromonaphthalene 106 Limits: 40-140%02/13/23 16:321 AMP MADEP-EPHSurrogate: Chlorooctadecane 103 Limits: 40-140%02/13/23 16:321 AMP MADEP-EPHSurrogate: OTP Surrogate 90.5 Limits: 40-140%02/13/23 16:321 AMP Surrogate: 2-Fluorobiphenyl 110 Limits: 40-140%02/13/23 16:321 AMP V29727 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 17 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99825 Matrix: 2/8/2023 9:30 TCLP Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF LeachateTCLP SVOC Extraction 1 02/23/23 14:30 SW-1311ALM LeachateTCLP VOC ZHE Extraction 1 02/16/23 13:00 SW-1311 (ZHE)TBL Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 5030B 8260D Prep Batch(es):V29922 02/17/23 09:00 <0.0018 mg/L 0.0018 0.0050TCLP Benzene 10 02/17/23 13:32 V29923MSA <0.0054 mg/L 0.0054 0.0200TCLP Carbon Tetrachloride 10 02/17/23 13:32 V29923MSA <0.0033 mg/L 0.0033 0.0050TCLP Chlorobenzene 10 02/17/23 13:32 V29923MSA <0.0047 mg/L 0.0047 0.0050TCLP Chloroform 10 02/17/23 13:32 V29923MSA <0.0042 mg/L 0.0042 0.0050 TCLP 1,4-Dichlorobenzene 10 02/17/23 13:32 V29923MSA <0.0040 mg/L 0.0040 0.0050TCLP 1,2-Dichloroethane 10 02/17/23 13:32 V29923MSA <0.0034 mg/L 0.0034 0.0050TCLP 1,1-Dichloroethene 10 02/17/23 13:32 V29923MSA <0.0078 mg/L 0.0078 0.0500TCLP Methyl Ethyl Ketone (MEK)10 02/17/23 13:32 V29923MSA <0.0030 mg/L 0.0030 0.0050TCLP Tetrachloroethene 10 02/17/23 13:32 V29923MSA <0.0046 mg/L 0.0046 0.0050TCLP Trichloroethene 10 02/17/23 13:32 V29923MSA <0.0041 mg/L 0.0041 0.0050TCLP Vinyl Chloride 10 02/17/23 13:32 V29923MSA Surrogate: 4-Bromofluorobenzene 98.0 Limits: 80-124%02/17/23 13:3210 MSA V29923 Surrogate: Dibromofluoromethane 88.2 Limits: 75-129%02/17/23 13:3210 MSA V29923 Surrogate: Toluene-d8 102 Limits: 77-123%02/17/23 13:3210 MSA V29923 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 18 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P01 pre-ex 99825 Matrix: 2/8/2023 9:30 TCLP Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3510C 8270C Prep Batch(es):L666075 02/24/23 11:05 <0.0007 mg/L 0.0007 0.0050TCLP 2-Methylphenol 1 02/24/23 18:51 L666202VBW <0.0006 mg/L 0.0006 0.0050TCLP 3&4 Methylphenol 1 02/24/23 18:51 L666202VBW <0.0004 mg/L 0.0004 0.0050TCLP 2,4-Dinitrotoluene 1 02/24/23 18:51 L666202VBW <0.0025 mg/L 0.002 0.0050TCLP Hexachlorobenzene 1 02/24/23 18:51 L666202VBW <0.0004 mg/L 0.0004 0.0050TCLP Hexachlorobutadiene 1 02/24/23 18:51 L666202VBW <0.0002 mg/L 0.0002 0.0050TCLP Hexachloroethane 1 02/24/23 18:51 L666202VBW <0.0005 mg/L 0.0005 0.0050TCLP Nitrobenzene 1 02/24/23 18:51 L666202VBW <0.0024 mg/L 0.002 0.0100TCLP Pentachlorophenol 1 02/24/23 18:51 L666202VBW <0.0006 mg/L 0.0006 0.0100 TCLP Pyridine 1 02/24/23 18:51 L666202VBW <0.0003 mg/L 0.0003 0.0050TCLP 2,4,5-Trichlorophenol 1 02/24/23 18:51 L666202VBW <0.0003 mg/L 0.0003 0.0050TCLP 2,4,6-Trichlorophenol 1 02/24/23 18:51 L666202VBW Surrogate: TCLP 2,4,6-Tribromophenol 68.3 Limits: 42-102%02/24/23 18:511 VBW L666202 Surrogate: TCLP 2-Fluorobiphenyl 63.8 Limits: 24-86%02/24/23 18:511 VBW L666202 Surrogate: TCLP 2-Fluorophenol 27.5 Limits: 13-37%02/24/23 18:511 VBW L666202 Surrogate: TCLP 4-Terphenyl-d14 76.3 Limits: 30-122%02/24/23 18:511 VBW L666202 Surrogate: TCLP Nitrobenzene-d5 67.0 Limits: 25-78%02/24/23 18:511 VBW L666202 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 19 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99826 Matrix: 2/8/2023 9:30 TCLP Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF LeachateTCLP SVOC Extraction 1 02/23/23 14:30 SW-1311ALM LeachateTCLP VOC ZHE Extraction 1 02/16/23 13:00 SW-1311 (ZHE)TBL Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 5030B 8260D Prep Batch(es):V29922 02/17/23 09:00 <0.0018 mg/L 0.0018 0.0050TCLP Benzene 10 02/17/23 13:56 V29923MSA <0.0054 mg/L 0.0054 0.0200TCLP Carbon Tetrachloride 10 02/17/23 13:56 V29923MSA <0.0033 mg/L 0.0033 0.0050TCLP Chlorobenzene 10 02/17/23 13:56 V29923MSA <0.0047 mg/L 0.0047 0.0050TCLP Chloroform 10 02/17/23 13:56 V29923MSA <0.0042 mg/L 0.0042 0.0050 TCLP 1,4-Dichlorobenzene 10 02/17/23 13:56 V29923MSA <0.0040 mg/L 0.0040 0.0050TCLP 1,2-Dichloroethane 10 02/17/23 13:56 V29923MSA <0.0034 mg/L 0.0034 0.0050TCLP 1,1-Dichloroethene 10 02/17/23 13:56 V29923MSA 0.392 mg/L 0.0078 0.0500TCLP Methyl Ethyl Ketone (MEK)10 02/17/23 13:56 V29923MSA <0.0030 mg/L 0.0030 0.0050TCLP Tetrachloroethene 10 02/17/23 13:56 V29923MSA <0.0046 mg/L 0.0046 0.0050TCLP Trichloroethene 10 02/17/23 13:56 V29923MSA <0.0041 mg/L 0.0041 0.0050TCLP Vinyl Chloride 10 02/17/23 13:56 V29923MSA Surrogate: 4-Bromofluorobenzene 96.6 Limits: 80-124%02/17/23 13:5610 MSA V29923 Surrogate: Dibromofluoromethane 89.4 Limits: 75-129%02/17/23 13:5610 MSA V29923 Surrogate: Toluene-d8 102 Limits: 77-123%02/17/23 13:5610 MSA V29923 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 20 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-040-0007 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 02/09/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 02/27/2023 Sample ID : Lab No : Sampled:P02 pre-ex 99826 Matrix: 2/8/2023 9:30 TCLP Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3510C 8270C Prep Batch(es):L666075 02/24/23 11:05 <0.0007 mg/L 0.0007 0.0050TCLP 2-Methylphenol 1 02/24/23 19:14 L666202VBW <0.0006 mg/L 0.0006 0.0050TCLP 3&4 Methylphenol 1 02/24/23 19:14 L666202VBW <0.0004 mg/L 0.0004 0.0050TCLP 2,4-Dinitrotoluene 1 02/24/23 19:14 L666202VBW <0.0025 mg/L 0.002 0.0050TCLP Hexachlorobenzene 1 02/24/23 19:14 L666202VBW <0.0004 mg/L 0.0004 0.0050TCLP Hexachlorobutadiene 1 02/24/23 19:14 L666202VBW <0.0002 mg/L 0.0002 0.0050TCLP Hexachloroethane 1 02/24/23 19:14 L666202VBW <0.0005 mg/L 0.0005 0.0050TCLP Nitrobenzene 1 02/24/23 19:14 L666202VBW <0.0024 mg/L 0.002 0.0100TCLP Pentachlorophenol 1 02/24/23 19:14 L666202VBW <0.0006 mg/L 0.0006 0.0100 TCLP Pyridine 1 02/24/23 19:14 L666202VBW <0.0003 mg/L 0.0003 0.0050TCLP 2,4,5-Trichlorophenol 1 02/24/23 19:14 L666202VBW <0.0003 mg/L 0.0003 0.0050TCLP 2,4,6-Trichlorophenol 1 02/24/23 19:14 L666202VBW Surrogate: TCLP 2,4,6-Tribromophenol 70.8 Limits: 42-102%02/24/23 19:141 VBW L666202 Surrogate: TCLP 2-Fluorobiphenyl 67.8 Limits: 24-86%02/24/23 19:141 VBW L666202 Surrogate: TCLP 2-Fluorophenol 28.3 Limits: 13-37%02/24/23 19:141 VBW L666202 Surrogate: TCLP 4-Terphenyl-d14 101 Limits: 30-122%02/24/23 19:141 VBW L666202 Surrogate: TCLP Nitrobenzene-d5 70.0 Limits: 25-78%02/24/23 19:141 VBW L666202 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 21 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Volatile Organic Compounds - GC/MS (TCLP) 8260D V29923QC Analytical Batch(es): Analysis Method: Analysis Description: 5030B QC Prep:V29922 Associated Lab Samples: 99825, 99826 LRB-V29922 Matrix: TCLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/17/23 12:440.00050.0001<0.0001mg/LTCLP Benzene 02/17/23 12:440.00200.0005<0.0005mg/LTCLP Carbon Tetrachloride 02/17/23 12:440.00050.0003<0.0003mg/LTCLP Chlorobenzene 02/17/23 12:440.00050.0004<0.0004mg/LTCLP Chloroform 02/17/23 12:440.00050.0004<0.0004mg/LTCLP 1,4-Dichlorobenzene 02/17/23 12:440.00050.0004<0.0004mg/LTCLP 1,2-Dichloroethane 02/17/23 12:440.00050.0003<0.0003mg/LTCLP 1,1-Dichloroethene 02/17/23 12:440.00500.0007<0.0007mg/LTCLP Methyl Ethyl Ketone (MEK) 02/17/23 12:440.00050.0003<0.0003mg/LTCLP Tetrachloroethene 02/17/23 12:440.00050.0004<0.0004mg/LTCLP Trichloroethene 02/17/23 12:440.00050.0004<0.0004mg/LTCLP Vinyl Chloride 02/17/23 12:444-Bromofluorobenzene (S)97.8 80-124 02/17/23 12:44Dibromofluoromethane (S)90.0 75-129 02/17/23 12:44Toluene-d8 (S)102 77-123 LCS-V29922 LCSD-V29922Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.0212 1061040.02070.0200mg/LTCLP Benzene 77-128 2.3 20 0.0205 10399.00.01980.0200mg/LTCLP Carbon Tetrachloride 72-142 3.4 20 0.0208 10499.50.01990.0200mg/LTCLP Chlorobenzene 78-119 4.4 20 0.0195 97.594.50.01890.0200mg/LTCLP Chloroform 80-120 3.1 20 0.0206 1031030.02050.0200mg/LTCLP 1,4-Dichlorobenzene 75-126 0.4 20 0.0185 92.592.50.01850.0200mg/LTCLP 1,2-Dichloroethane 70-130 0.0 20 0.0218 1091090.02170.0200mg/LTCLP 1,1-Dichloroethene 70-154 0.4 20 0.0146 73.075.00.01500.0200mg/LTCLP Methyl Ethyl Ketone (MEK)71-134 2.7 20 Page 1 of 15Date:02/27/2023 04:24 PM Page 22 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Volatile Organic Compounds - GC/MS (TCLP) 8260D V29923QC Analytical Batch(es): Analysis Method: Analysis Description: 5030B QC Prep:V29922 LCS-V29922 LCSD-V29922Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.0232 1161110.02220.0200mg/LTCLP Tetrachloroethene 80-129 4.4 20 0.0218 1091060.02120.0200mg/LTCLP Trichloroethene 70-125 2.7 20 0.0226 1131090.02170.0200mg/LTCLP Vinyl Chloride 57-141 4.0 20 95.496.24-Bromofluorobenzene (S)80-124 89.089.0Dibromofluoromethane (S)75-129 104101Toluene-d8 (S)77-123 Page 2 of 15Date:02/27/2023 04:24 PM Page 23 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS (TCLP) 8270C L666202QC Analytical Batch(es): Analysis Method: Analysis Description: 3510C QC Prep:L666075 Associated Lab Samples: 99825, 99826 LRB-L666075 Matrix: TCLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/24/23 16:120.0050.0007<0.0007mg/LTCLP 2-Methylphenol 02/24/23 16:120.0050.0006<0.0006mg/LTCLP 3&4 Methylphenol 02/24/23 16:120.0050.0004<0.0004mg/LTCLP 2,4-Dinitrotoluene 02/24/23 16:120.0050.002<0.002mg/LTCLP Hexachlorobenzene 02/24/23 16:120.0050.0004<0.0004mg/LTCLP Hexachlorobutadiene 02/24/23 16:120.0050.0002<0.0002mg/LTCLP Hexachloroethane 02/24/23 16:120.0050.0005<0.0005mg/LTCLP Nitrobenzene 02/24/23 16:120.0100.002<0.002mg/LTCLP Pentachlorophenol 02/24/23 16:120.0100.0006<0.0006mg/LTCLP Pyridine 02/24/23 16:120.0050.0003<0.0003mg/LTCLP 2,4,6-Trichlorophenol 02/24/23 16:12TCLP 2,4,6-Tribromophenol (S)68.2 42-102 02/24/23 16:12TCLP 2-Fluorobiphenyl (S)71.7 24-86 02/24/23 16:12TCLP 2-Fluorophenol (S)26.5 13-37 02/24/23 16:12TCLP 4-Terphenyl-d14 (S)92.2 30-122 02/24/23 16:12TCLP Nitrobenzene-d5 (S)73.7 25-78 02/24/23 16:12TCLP Phenol-d6 (S)17.6 9-27 LCS-L666075 LCSD-L666075Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.086 43.348.40.0960.200mg/LTCLP 2-Methylphenol 22-97 11.1 20 0.085 42.547.60.0950.200mg/LTCLP 3&4 Methylphenol 21-96 11.4 20 0.162 81.084.50.1690.200mg/LTCLP 2,4-Dinitrotoluene 24-147 4.2 20 0.168 84.089.00.1780.200mg/LTCLP Hexachlorobenzene 18-136 5.7 20 0.094 47.356.00.1120.200mg/LTCLP Hexachlorobutadiene 22-109 16.7 20 0.081 40.848.00.0960.200mg/LTCLP Hexachloroethane 16-107 16.1 20 Page 3 of 15Date:02/27/2023 04:24 PM Page 24 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS (TCLP) 8270C L666202QC Analytical Batch(es): Analysis Method: Analysis Description: 3510C QC Prep:L666075 LCS-L666075 LCSD-L666075Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 0.120 60.067.00.1340.200mg/LTCLP Nitrobenzene 27-117 11.0 20 0.174 87.01020.2030.200mg/LTCLP Pentachlorophenol 17-142 15.3 20 0.059 29.934.40.0680.200mg/LTCLP Pyridine 10-71 13.9 20 0.151 75.583.00.1660.200mg/LTCLP 2,4,5-Trichlorophenol 26-118 9.4 20 0.152 76.083.00.1660.200mg/LTCLP 2,4,6-Trichlorophenol 26-115 8.8 20 67.771.5TCLP 2,4,6-Tribromophenol (S)42-102 64.770.0TCLP 2-Fluorobiphenyl (S)24-86 21.624.1TCLP 2-Fluorophenol (S)13-37 79.294.0TCLP 4-Terphenyl-d14 (S)30-122 63.070.5TCLP Nitrobenzene-d5 (S)25-78 14.516.4TCLP Phenol-d6 (S)9-27 Page 4 of 15Date:02/27/2023 04:24 PM Page 25 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 Associated Lab Samples: 99278, 99279 LRB-V29772 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/15/23 14:520.6600.116<0.116mg/KgAcenaphthene 02/15/23 14:520.6600.105<0.105mg/KgAcenaphthylene 02/15/23 14:520.6600.152<0.152mg/KgAniline 02/15/23 14:520.6600.143<0.143mg/KgAnthracene 02/15/23 14:520.6600.139<0.139mg/KgBenzo(a)anthracene 02/15/23 14:520.6600.147<0.147mg/KgBenzo(a)pyrene 02/15/23 14:520.6600.146<0.146mg/KgBenzo(b)fluoranthene 02/15/23 14:520.6600.136<0.136mg/KgBenzo(g,h,i)perylene 02/15/23 14:520.6600.137<0.137mg/KgBenzo(k)fluoranthene 02/15/23 14:522.000.580<0.580mg/KgBenzoic Acid 02/15/23 14:520.6600.105<0.105mg/KgBenzyl alcohol 02/15/23 14:520.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane 02/15/23 14:520.6600.107<0.107mg/KgBis(2-Chloroethyl)ether 02/15/23 14:520.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether 02/15/23 14:520.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate 02/15/23 14:520.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether 02/15/23 14:520.3300.113<0.113mg/KgButyl benzyl phthalate 02/15/23 14:520.6600.092<0.092mg/Kg4-Chloro-3-methylphenol 02/15/23 14:520.3300.112<0.112mg/Kg4-Chloroaniline 02/15/23 14:520.6600.116<0.116mg/Kg2-Chloronaphthalene 02/15/23 14:520.6600.098<0.098mg/Kg2-Chlorophenol 02/15/23 14:521.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether 02/15/23 14:520.6600.142<0.142mg/KgChrysene 02/15/23 14:520.6600.230<0.230mg/KgDibenz(a,h)anthracene 02/15/23 14:520.6600.119<0.119mg/KgDibenzofuran 02/15/23 14:520.6600.094<0.094mg/Kg1,2-Dichlorobenzene 02/15/23 14:520.6600.097<0.097mg/Kg1,3-Dichlorobenzene Page 5 of 15Date:02/27/2023 04:24 PM Page 26 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 Associated Lab Samples: 99278, 99279 LRB-V29772 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/15/23 14:520.3300.097<0.097mg/Kg1,4-Dichlorobenzene 02/15/23 14:520.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine 02/15/23 14:520.6600.095<0.095mg/Kg2,4-Dichlorophenol 02/15/23 14:520.6600.180<0.180mg/KgDiethyl phthalate 02/15/23 14:520.6600.174<0.174mg/KgDimethyl phthalate 02/15/23 14:520.3300.108<0.108mg/Kg2,4-Dimethylphenol 02/15/23 14:520.6600.107<0.107mg/KgDi-n-butyl phthalate 02/15/23 14:521.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol 02/15/23 14:521.500.520<0.520mg/Kg2,4-Dinitrophenol 02/15/23 14:520.6600.096<0.096mg/Kg2,4-Dinitrotoluene 02/15/23 14:520.6600.108<0.108mg/Kg2,6-Dinitrotoluene 02/15/23 14:520.3300.143<0.143mg/KgDi-n-Octyl Phthalate 02/15/23 14:520.6600.123<0.123mg/KgFluoranthene 02/15/23 14:520.6600.128<0.128mg/KgFluorene 02/15/23 14:520.6600.106<0.106mg/KgHexachlorobenzene 02/15/23 14:520.6600.097<0.097mg/KgHexachlorobutadiene 02/15/23 14:520.6600.157<0.157mg/KgHexachlorocyclopentadiene 02/15/23 14:520.6600.079<0.079mg/KgHexachloroethane 02/15/23 14:520.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene 02/15/23 14:520.6600.191<0.191mg/KgIsophorone 02/15/23 14:520.6600.106<0.106mg/Kg1-Methylnaphthalene 02/15/23 14:520.6600.100<0.100mg/Kg2-Methylnaphthalene 02/15/23 14:520.6600.097<0.097mg/Kg2-Methylphenol 02/15/23 14:520.6600.084<0.084mg/Kg3&4 Methylphenol 02/15/23 14:520.6600.144<0.144mg/KgNaphthalene 02/15/23 14:520.6600.096<0.096mg/Kg2-Nitroaniline 02/15/23 14:520.6600.120<0.120mg/Kg3-Nitroaniline Page 6 of 15Date:02/27/2023 04:24 PM Page 27 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 Associated Lab Samples: 99278, 99279 LRB-V29772 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/15/23 14:520.3300.093<0.093mg/Kg4-Nitroaniline 02/15/23 14:520.3300.116<0.116mg/KgNitrobenzene 02/15/23 14:520.6600.088<0.088mg/Kg2-Nitrophenol 02/15/23 14:520.6600.117<0.117mg/Kg4-Nitrophenol 02/15/23 14:520.6600.263<0.263mg/KgN-Nitrosodimethylamine 02/15/23 14:520.6600.181<0.181mg/KgN-Nitrosodiphenylamine 02/15/23 14:520.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine 02/15/23 14:521.000.347<0.347mg/KgPentachlorophenol 02/15/23 14:520.6600.208<0.208mg/KgPhenanthrene 02/15/23 14:520.6600.112<0.112mg/KgPhenol 02/15/23 14:520.6600.134<0.134mg/KgPyrene 02/15/23 14:520.3300.079<0.079mg/KgPyridine 02/15/23 14:520.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene 02/15/23 14:520.6600.096<0.096mg/Kg2,4,5-Trichlorophenol 02/15/23 14:520.6600.096<0.096mg/Kg2,4,6-Trichlorophenol 02/15/23 14:522-Fluorobiphenyl (S)83.8 44-115 02/15/23 14:522-Fluorophenol (S)70.5 35-115 02/15/23 14:52Nitrobenzene-d5 (S)74.2 37-122 02/15/23 14:524-Terphenyl-d14 (S)93.4 54-127 02/15/23 14:522,4,6-Tribromophenol (S)75.0 39-132 02/15/23 14:52Phenol-d5 (S)66.6 34-121 LCS-V29772Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 83.81.401.67mg/KgAcenaphthene 40-123 85.61.431.67mg/KgAcenaphthylene 32-132 Page 7 of 15Date:02/27/2023 04:24 PM Page 28 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 LCS-V29772Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 1442.401.67mg/KgAniline 12-197 94.01.571.67mg/KgAnthracene 47-123 92.21.541.67mg/KgBenzo(a)anthracene 49-126 81.41.361.67mg/KgBenzo(a)pyrene 45-129 76.61.281.67mg/KgBenzo(b)fluoranthene 45-132 73.01.221.67mg/KgBenzo(g,h,i)perylene 43-134 73.01.221.67mg/KgBenzo(k)fluoranthene 47-132 39.00.6521.67mg/KgBenzoic Acid 10-83 88.01.471.67mg/KgBenzyl alcohol 29-122 76.61.281.67mg/KgBis(2-Chloroethoxy)methane 36-121 76.01.271.67mg/KgBis(2-Chloroethyl)ether 31-120 79.01.321.67mg/KgBis(2-Chloroisopropyl)ether 33-131 1021.701.67mg/KgBis(2-ethylhexyl)phthalate 51-133 94.01.571.67mg/Kg4-Bromophenyl phenyl ether 46-124 97.61.631.67mg/KgButyl benzyl phthalate 48-132 79.61.331.67mg/Kg4-Chloro-3-methylphenol 45-122 77.81.301.67mg/Kg4-Chloroaniline 17-106 85.61.431.67mg/Kg2-Chloronaphthalene 41-114 85.01.421.67mg/Kg2-Chlorophenol 34-121 91.61.531.67mg/Kg4-Chlorophenyl phenyl ether 45-121 92.81.551.67mg/KgChrysene 50-124 74.21.241.67mg/KgDibenz(a,h)anthracene 45-134 86.21.441.67mg/KgDibenzofuran 44-120 77.21.291.67mg/Kg1,2-Dichlorobenzene 33-117 75.41.261.67mg/Kg1,3-Dichlorobenzene 30-115 76.01.271.67mg/Kg1,4-Dichlorobenzene 31-115 71.81.201.67mg/Kg3,3'-Dichlorobenzidine 22-121 Page 8 of 15Date:02/27/2023 04:24 PM Page 29 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 LCS-V29772Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 81.41.361.67mg/Kg2,4-Dichlorophenol 40-122 92.21.541.67mg/KgDiethyl phthalate 50-124 91.61.531.67mg/KgDimethyl phthalate 48-124 1041.731.67mg/Kg2,4-Dimethylphenol 30-127 1001.671.67mg/KgDi-n-butyl phthalate 51-128 88.61.481.67mg/Kg4,6-Dinitro-2-methylphenol 29-132 81.41.361.67mg/Kg2,4-Dinitrophenol 27-129 89.81.501.67mg/Kg2,4-Dinitrotoluene 48-126 89.21.491.67mg/Kg2,6-Dinitrotoluene 46-124 80.81.351.67mg/KgDi-n-Octyl Phthalate 45-140 87.41.461.67mg/KgFluoranthene 50-127 90.41.511.67mg/KgFluorene 43-125 91.01.521.67mg/KgHexachlorobenzene 45-122 77.21.291.67mg/KgHexachlorobutadiene 32-123 82.01.371.67mg/KgHexachlorocyclopentadiene 32-117 74.21.241.67mg/KgHexachloroethane 28-117 74.21.241.67mg/KgIndeno(1,2,3-cd)pyrene 45-133 63.41.061.67mg/KgIsophorone 30-122 74.21.241.67mg/Kg1-Methylnaphthalene 40-119 73.01.221.67mg/Kg2-Methylnaphthalene 38-122 87.41.461.67mg/Kg2-Methylphenol 32-122 77.21.291.67mg/Kg3&4 Methylphenol 34-119 70.01.171.67mg/KgNaphthalene 35-123 89.21.491.67mg/Kg2-Nitroaniline 44-127 83.21.391.67mg/Kg3-Nitroaniline 33-119 97.61.631.67mg/Kg4-Nitroaniline 63-147 68.21.141.67mg/KgNitrobenzene 34-122 Page 9 of 15Date:02/27/2023 04:24 PM Page 30 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 LCS-V29772Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 74.81.251.67mg/Kg2-Nitrophenol 36-123 1061.771.67mg/Kg4-Nitrophenol 30-132 62.81.051.67mg/KgN-Nitrosodimethylamine 10-146 1081.801.67mg/KgN-Nitrosodiphenylamine 38-127 81.41.361.67mg/KgN-Nitroso-di-n-propylamine 36-120 1081.811.67mg/KgPentachlorophenol 25-133 90.41.511.67mg/KgPhenanthrene 50-121 82.01.371.67mg/KgPhenol 34-121 91.61.531.67mg/KgPyrene 47-127 54.60.9121.67mg/KgPyridine 10-80 72.41.211.67mg/Kg1,2,4-Trichlorobenzene 34-118 92.81.551.67mg/Kg2,4,5-Trichlorophenol 41-124 86.21.441.67mg/Kg2,4,6-Trichlorophenol 39-126 89.82-Fluorobiphenyl (S)44-115 77.12-Fluorophenol (S)35-115 71.2Nitrobenzene-d5 (S)37-122 99.44-Terphenyl-d14 (S)54-127 84.32,4,6-Tribromophenol (S)39-132 72.9Phenol-d5 (S)34-121 V 98922-MS-V29772 V 98922-MSD-V29772Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.39 83.21.341.671.67<0.116mg/KgAcenaphthene 80.2 40-123 3.6 20 1.40 83.81.331.671.67<0.105mg/KgAcenaphthylene 79.6 32-132 5.1 20 2.40 1442.191.671.67<0.152mg/KgAniline 131 12-197 9.1 20 Page 10 of 15Date:02/27/2023 04:24 PM Page 31 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 V 98922-MS-V29772 V 98922-MSD-V29772Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.55 92.81.461.671.67<0.143mg/KgAnthracene 87.4 47-123 5.9 20 1.50 89.81.461.671.67<0.139mg/KgBenzo(a)anthracene 87.4 49-126 2.7 20 1.32 79.01.251.671.67<0.147mg/KgBenzo(a)pyrene 74.8 45-129 5.4 20 1.24 74.21.181.671.67<0.146mg/KgBenzo(b)fluoranthene 70.6 45-132 4.9 20 1.19 71.21.121.671.67<0.136mg/KgBenzo(g,h,i)perylene 67.0 43-134 6.0 20 1.18 70.61.101.671.67<0.137mg/KgBenzo(k)fluoranthene 65.8 47-132 7.0 20 1.35 80.81.331.671.67<0.580mg/KgBenzoic Acid 79.6 10-83 1.4 20 1.45 86.81.381.671.67<0.105mg/KgBenzyl alcohol 82.6 29-122 4.9 20 1.29 77.21.241.671.67<0.118mg/KgBis(2-Chloroethoxy)methane 74.2 36-121 3.9 20 1.11 66.41.071.671.67<0.107mg/KgBis(2-Chloroethyl)ether 64.0 31-120 3.6 20 1.25 74.81.151.671.67<0.136mg/KgBis(2-Chloroisopropyl)ether 68.8 33-131 8.3 20 1.68 1011.611.671.67<0.120mg/KgBis(2-ethylhexyl)phthalate 96.4 51-133 4.2 20 1.53 91.61.481.671.67<0.109mg/Kg4-Bromophenyl phenyl ether 88.6 46-124 3.3 20 1.60 95.81.541.671.67<0.113mg/KgButyl benzyl phthalate 92.2 48-132 3.8 20 1.28 76.61.221.671.67<0.092mg/Kg4-Chloro-3-methylphenol 73.0 45-122 4.8 20 1.31 78.41.271.671.67<0.112mg/Kg4-Chloroaniline 76.0 17-106 3.1 20 1.44 86.21.351.671.67<0.116mg/Kg2-Chloronaphthalene 80.8 41-114 6.4 20 1.40 83.81.311.671.67<0.098mg/Kg2-Chlorophenol 78.4 34-121 6.6 20 1.54 92.21.451.671.67<0.126mg/Kg4-Chlorophenyl phenyl ether 86.8 45-121 6.0 20 1.51 90.41.451.671.67<0.142mg/KgChrysene 86.8 50-124 4.0 20 1.20 71.81.141.671.67<0.230mg/KgDibenz(a,h)anthracene 68.2 45-134 5.1 20 1.43 85.61.351.671.67<0.119mg/KgDibenzofuran 80.8 44-120 5.7 20 1.25 74.81.181.671.67<0.094mg/Kg1,2-Dichlorobenzene 70.6 33-117 5.7 20 1.20 71.81.131.671.67<0.097mg/Kg1,3-Dichlorobenzene 67.6 30-115 6.0 20 1.23 73.61.161.671.67<0.097mg/Kg1,4-Dichlorobenzene 69.4 31-115 5.8 20 1.36 81.41.331.671.67<0.147mg/Kg3,3'-Dichlorobenzidine 79.6 22-121 2.2 20 Page 11 of 15Date:02/27/2023 04:24 PM Page 32 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 V 98922-MS-V29772 V 98922-MSD-V29772Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.30 77.81.261.671.67<0.095mg/Kg2,4-Dichlorophenol 75.4 40-122 3.1 20 1.52 91.01.441.671.67<0.180mg/KgDiethyl phthalate 86.2 50-124 5.4 20 1.51 90.41.421.671.67<0.174mg/KgDimethyl phthalate 85.0 48-124 6.1 30 1.86 1111.771.671.67<0.108mg/Kg2,4-Dimethylphenol 106 30-127 4.9 20 1.70 1021.591.671.67<0.107mg/KgDi-n-butyl phthalate 95.2 51-128 6.6 20 1.32 79.01.211.671.67<0.240mg/Kg4,6-Dinitro-2-methylphenol 72.4 29-132 8.6 20 1.42 85.01.281.671.67<0.520mg/Kg2,4-Dinitrophenol 76.6 27-129 10.3 20 1.48 88.61.401.671.67<0.096mg/Kg2,4-Dinitrotoluene 83.8 48-126 5.5 20 1.45 86.81.381.671.67<0.108mg/Kg2,6-Dinitrotoluene 82.6 46-124 4.9 20 1.36 81.41.261.671.67<0.143mg/KgDi-n-Octyl Phthalate 75.4 45-140 7.6 20 1.45 86.81.371.671.67<0.123mg/KgFluoranthene 82.0 50-127 5.6 20 1.49 89.21.411.671.67<0.128mg/KgFluorene 84.4 43-125 5.5 20 1.49 89.21.461.671.67<0.106mg/KgHexachlorobenzene 87.4 45-122 2.0 20 1.30 77.81.221.671.67<0.097mg/KgHexachlorobutadiene 73.0 32-123 6.3 20 1.10 65.81.081.671.67<0.157mg/KgHexachlorocyclopentadiene 64.6 32-117 1.8 20 2.34 140*2.231.671.67<0.079mg/KgHexachloroethane 134*28-117 4.8 20 1.22 73.01.151.671.67<0.179mg/KgIndeno(1,2,3-cd)pyrene 68.8 45-133 5.9 20 1.13 67.61.101.671.67<0.191mg/KgIsophorone 65.8 30-122 2.6 20 1.46 74.01.411.671.670.224mg/Kg1-Methylnaphthalene 71.0 40-119 3.4 20 1.67 75.51.641.671.670.408mg/Kg2-Methylnaphthalene 73.7 38-122 1.8 20 1.39 83.21.361.671.67<0.097mg/Kg2-Methylphenol 81.4 32-122 2.1 20 1.35 80.81.241.671.67<0.084mg/Kg3&4 Methylphenol 74.2 34-119 8.4 20 1.46 87.41.441.671.67<0.144mg/KgNaphthalene 86.2 35-123 1.3 20 1.52 91.01.461.671.67<0.096mg/Kg2-Nitroaniline 87.4 44-127 4.0 20 1.38 82.61.341.671.67<0.120mg/Kg3-Nitroaniline 80.2 33-119 2.9 20 1.57 94.01.491.671.67<0.093mg/Kg4-Nitroaniline 89.2 63-147 5.2 20 Page 12 of 15* QC Fail Date:02/27/2023 04:24 PM Page 33 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V29814QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V29772 V 98922-MS-V29772 V 98922-MSD-V29772Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 1.19 71.21.151.671.67<0.116mg/KgNitrobenzene 68.8 34-122 3.4 20 1.31 78.41.251.671.67<0.088mg/Kg2-Nitrophenol 74.8 32-123 4.6 20 1.68 1011.441.671.67<0.117mg/Kg4-Nitrophenol 86.2 30-132 15.3 20 1.02 61.00.9651.671.67<0.263mg/KgN-Nitrosodimethylamine 57.7 10-146 5.5 30 1.81 1081.711.671.67<0.181mg/KgN-Nitrosodiphenylamine 102 38-127 5.6 20 1.43 85.61.401.671.67<0.118mg/KgN-Nitroso-di-n-propylamine 83.8 36-120 2.1 20 1.87 1121.781.671.67<0.347mg/KgPentachlorophenol 107 25-133 4.9 20 1.48 88.61.421.671.67<0.208mg/KgPhenanthrene 85.0 50-121 4.1 20 1.35 80.81.261.671.67<0.112mg/KgPhenol 75.4 34-121 6.8 20 1.54 92.21.471.671.67<0.134mg/KgPyrene 88.0 47-127 4.6 20 0.917 54.90.8831.671.67<0.079mg/KgPyridine 52.8 10-80 3.7 20 1.19 71.21.151.671.67<0.107mg/Kg1,2,4-Trichlorobenzene 68.8 34-118 3.4 20 1.53 91.61.451.671.67<0.096mg/Kg2,4,5-Trichlorophenol 86.8 41-124 5.3 20 1.45 86.81.361.671.67<0.096mg/Kg2,4,6-Trichlorophenol 81.4 39-126 6.4 20 88.02-Fluorobiphenyl (S)82.0 44-115 73.52-Fluorophenol (S)67.8 35-115 70.0Nitrobenzene-d5 (S)66.4 37-122 98.24-Terphenyl-d14 (S)93.4 54-127 80.72,4,6-Tribromophenol (S)76.5 39-132 68.7Phenol-d5 (S)62.7 34-121 Page 13 of 15Date:02/27/2023 04:24 PM Page 34 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Massachusetts EPH MADEP-EPH V29727QC Analytical Batch(es): Analysis Method: Analysis Description: MAEPH (Prep) QC Prep:V29676 Associated Lab Samples: 99278, 99279 LRB-V29676 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/13/23 11:4250.09.20<9.20mg/KgAliphatic C9-C18 02/13/23 11:4250.012.2<12.2mg/KgAliphatic C19-C36 02/13/23 11:4250.014.2<14.2mg/KgAromatic C11-C22 02/13/23 11:422-Fluorobiphenyl (S)97.5 40-140 02/13/23 11:422-Bromonaphthalene (S)96.2 40-140 02/13/23 11:42Chlorooctadecane (S)84.5 40-140 02/13/23 11:42OTP Surrogate (S)83.5 40-140 LCS-V29676 LCSD-V29676Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 41.4 69.064.838.960.0mg/KgAliphatic C9-C18 40-140 6.2 50 78.9 98.688.370.780.0mg/KgAliphatic C19-C36 40-140 10.9 50 176 10491.7156170mg/KgAromatic C11-C22 40-140 12.0 50 10397.02-Fluorobiphenyl (S)40-140 10397.02-Bromonaphthalene (S)40-140 10797.0Chlorooctadecane (S)40-140 88.582.5OTP Surrogate (S)40-140 Page 14 of 15Date:02/27/2023 04:24 PM Page 35 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-040-0007Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade Dry Weight Determination SW-DRYWT V29652QC Analytical Batch: Analysis Method: Analysis Description: V 99278-DUPDuplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 02/09/23 16:383.613.614.1%Moisture Page 15 of 15Date:02/27/2023 04:24 PM Page 36 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-040-0007 Smith & Gardner, Inc. 01186 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT15 2.7C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)?Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:02/09/2023 11:03:03 Special precautions or instructions included? Comments: Page 37 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Page 38 of 38 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. 3/17/2023 Smith & Gardner, Inc. Seth C. Rickerts 14 N. Boylan Avenue Raleigh, NC, 27603 Ref: Analytical Testing Lab Report Number: 23-067-0018 Client Project Description: GFL Wade Dear Seth C. Rickerts: Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/8/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/23-067-0018 Page 2 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Report Number: Sample Summary Table Client Project Description: 23-067-0018 GFL Wade Lab No Client Sample ID Matrix Date Collected Date Received 03/07/2023 08:20Solids 90565 Post - 01 03/08/2023 12:30 03/07/2023 09:10Solids 90566 Post - 02 03/08/2023 12:30 03/07/2023 11:00Solids 90567 Post - 03 03/08/2023 12:30 03/07/2023 11:45Solids 90568 Post - 04 03/08/2023 12:30 03/07/2023 12:30Solids 90569 Post - 05 03/08/2023 12:30 Page 3 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-067-0018 Report Limit Project:GFL Wade V 90565Post - 01 18.7 03/13/2023 16:38SW-DRYWT Moisture % V 90566Post - 02 7.39 03/14/2023 17:16SW-DRYWT Moisture % V 90567Post - 03 193 03/13/2023 17:58MADEP-EPH Aliphatic C19-C36 mg/Kg - dry 13.8 11.9 03/14/2023 17:16SW-DRYWT Moisture % V 90568Post - 04 22.6 03/14/2023 17:16SW-DRYWT Moisture % V 90569Post - 05 16.8 03/14/2023 17:16SW-DRYWT Moisture % Page 4 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Client: Smith & Gardner, Inc. CASE NARRATIVE Project: GFL Wade Lab Report Number: 23-067-0018 Date: 3/17/2023 Semivolatile Organic Compounds - GC/MS Method 8270E Analyte: 2,4-Dinitrophenol QC Batch No: V30934/V30852 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Benzoic Acid QC Batch No: V30934/V30852 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. This target analyte was flagged for recoveries outside QC limits in the associated LCS. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. Analyte: N-Nitrosodiphenylamine QC Batch No: V30934/V30852 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Page 5 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 01 90565 Matrix: 3/7/2023 8:20 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 18.7 %Moisture 1 03/13/23 16:38 SW-DRYWTAMB Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 6 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 01 90565 Matrix: 3/7/2023 8:20 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.142 mg/Kg - dry 0.142 0.811Acenaphthene 1 03/16/23 17:35 V30934JMV <0.129 mg/Kg - dry 0.129 0.811 Acenaphthylene 1 03/16/23 17:35 V30934JMV <0.186 mg/Kg - dry 0.186 0.811Aniline 1 03/16/23 17:35 V30934JMV <0.175 mg/Kg - dry 0.175 0.811Anthracene 1 03/16/23 17:35 V30934JMV <0.170 mg/Kg - dry 0.170 0.811Benzo(a)anthracene 1 03/16/23 17:35 V30934JMV <0.180 mg/Kg - dry 0.180 0.811Benzo(a)pyrene 1 03/16/23 17:35 V30934JMV <0.179 mg/Kg - dry 0.179 0.811Benzo(b)fluoranthene 1 03/16/23 17:35 V30934JMV <0.167 mg/Kg - dry 0.167 0.811Benzo(g,h,i)perylene 1 03/16/23 17:35 V30934JMV <0.168 mg/Kg - dry 0.168 0.811 Benzo(k)fluoranthene 1 03/16/23 17:35 V30934JMV <0.713 mg/Kg - dry 0.713 2.46Benzoic Acid 1 03/16/23 17:35 V30934JMV <0.129 mg/Kg - dry 0.129 0.811Benzyl alcohol 1 03/16/23 17:35 V30934JMV <0.145 mg/Kg - dry 0.145 0.811Bis(2-Chloroethoxy)methane 1 03/16/23 17:35 V30934JMV <0.131 mg/Kg - dry 0.131 0.811Bis(2-Chloroethyl)ether 1 03/16/23 17:35 V30934JMV <0.167 mg/Kg - dry 0.167 0.405Bis(2-Chloroisopropyl)ether 1 03/16/23 17:35 V30934JMV <0.147 mg/Kg - dry 0.147 0.811Bis(2-ethylhexyl)phthalate 1 03/16/23 17:35 V30934JMV <0.134 mg/Kg - dry 0.134 0.8114-Bromophenyl phenyl ether 1 03/16/23 17:35 V30934JMV <0.138 mg/Kg - dry 0.138 0.405Butyl benzyl phthalate 1 03/16/23 17:35 V30934JMV <0.113 mg/Kg - dry 0.113 0.8114-Chloro-3-methylphenol 1 03/16/23 17:35 V30934JMV <0.137 mg/Kg - dry 0.137 0.4054-Chloroaniline 1 03/16/23 17:35 V30934JMV <0.142 mg/Kg - dry 0.142 0.8112-Chloronaphthalene 1 03/16/23 17:35 V30934JMV <0.120 mg/Kg - dry 0.120 0.8112-Chlorophenol 1 03/16/23 17:35 V30934JMV <0.154 mg/Kg - dry 0.154 1.234-Chlorophenyl phenyl ether 1 03/16/23 17:35 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 7 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 01 90565 Matrix: 3/7/2023 8:20 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.174 mg/Kg - dry 0.174 0.811Chrysene 1 03/16/23 17:35 V30934JMV <0.282 mg/Kg - dry 0.282 0.811 Dibenz(a,h)anthracene 1 03/16/23 17:35 V30934JMV <0.146 mg/Kg - dry 0.146 0.811Dibenzofuran 1 03/16/23 17:35 V30934JMV <0.116 mg/Kg - dry 0.116 0.8111,2-Dichlorobenzene 1 03/16/23 17:35 V30934JMV <0.119 mg/Kg - dry 0.119 0.8111,3-Dichlorobenzene 1 03/16/23 17:35 V30934JMV <0.119 mg/Kg - dry 0.119 0.4051,4-Dichlorobenzene 1 03/16/23 17:35 V30934JMV <0.180 mg/Kg - dry 0.180 0.8113,3'-Dichlorobenzidine 1 03/16/23 17:35 V30934JMV <0.117 mg/Kg - dry 0.117 0.8112,4-Dichlorophenol 1 03/16/23 17:35 V30934JMV <0.221 mg/Kg - dry 0.221 0.811 Diethyl phthalate 1 03/16/23 17:35 V30934JMV <0.214 mg/Kg - dry 0.214 0.811Dimethyl phthalate 1 03/16/23 17:35 V30934JMV <0.132 mg/Kg - dry 0.132 0.4052,4-Dimethylphenol 1 03/16/23 17:35 V30934JMV <0.131 mg/Kg - dry 0.131 0.811Di-n-butyl phthalate 1 03/16/23 17:35 V30934JMV <0.295 mg/Kg - dry 0.295 1.854,6-Dinitro-2-methylphenol 1 03/16/23 17:35 V30934JMV <0.639 mg/Kg - dry 0.639 1.852,4-Dinitrophenol 1 03/16/23 17:35 V30934JMV <0.118 mg/Kg - dry 0.118 0.8112,4-Dinitrotoluene 1 03/16/23 17:35 V30934JMV <0.132 mg/Kg - dry 0.132 0.8112,6-Dinitrotoluene 1 03/16/23 17:35 V30934JMV <0.175 mg/Kg - dry 0.175 0.405Di-n-Octyl Phthalate 1 03/16/23 17:35 V30934JMV <0.132 mg/Kg - dry 0.132 0.8111,2-Diphenylhydrazine/Azobenzene 1 03/16/23 17:35 V30934JMV <0.151 mg/Kg - dry 0.151 0.811Fluoranthene 1 03/16/23 17:35 V30934JMV <0.157 mg/Kg - dry 0.157 0.811Fluorene 1 03/16/23 17:35 V30934JMV <0.130 mg/Kg - dry 0.130 0.811Hexachlorobenzene 1 03/16/23 17:35 V30934JMV <0.120 mg/Kg - dry 0.120 0.811Hexachlorobutadiene 1 03/16/23 17:35 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 8 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 01 90565 Matrix: 3/7/2023 8:20 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.193 mg/Kg - dry 0.193 0.811Hexachlorocyclopentadiene 1 03/16/23 17:35 V30934JMV <0.097 mg/Kg - dry 0.097 0.811 Hexachloroethane 1 03/16/23 17:35 V30934JMV <0.220 mg/Kg - dry 0.220 0.811Indeno(1,2,3-cd)pyrene 1 03/16/23 17:35 V30934JMV <0.234 mg/Kg - dry 0.234 0.811Isophorone 1 03/16/23 17:35 V30934JMV <0.130 mg/Kg - dry 0.130 0.8111-Methylnaphthalene 1 03/16/23 17:35 V30934JMV <0.123 mg/Kg - dry 0.123 0.8112-Methylnaphthalene 1 03/16/23 17:35 V30934JMV <0.119 mg/Kg - dry 0.119 0.8112-Methylphenol 1 03/16/23 17:35 V30934JMV <0.104 mg/Kg - dry 0.104 0.8113&4 Methylphenol 1 03/16/23 17:35 V30934JMV <0.177 mg/Kg - dry 0.177 0.811 Naphthalene 1 03/16/23 17:35 V30934JMV <0.118 mg/Kg - dry 0.118 0.8112-Nitroaniline 1 03/16/23 17:35 V30934JMV <0.147 mg/Kg - dry 0.147 0.8113-Nitroaniline 1 03/16/23 17:35 V30934JMV <0.114 mg/Kg - dry 0.114 0.4054-Nitroaniline 1 03/16/23 17:35 V30934JMV <0.142 mg/Kg - dry 0.142 0.405Nitrobenzene 1 03/16/23 17:35 V30934JMV <0.109 mg/Kg - dry 0.109 0.8112-Nitrophenol 1 03/16/23 17:35 V30934JMV <0.143 mg/Kg - dry 0.143 0.8114-Nitrophenol 1 03/16/23 17:35 V30934JMV <0.323 mg/Kg - dry 0.323 0.811N-Nitrosodimethylamine 1 03/16/23 17:35 V30934JMV <0.222 mg/Kg - dry 0.222 0.811N-Nitrosodiphenylamine 1 03/16/23 17:35 V30934JMV <0.145 mg/Kg - dry 0.145 0.811N-Nitroso-di-n-propylamine 1 03/16/23 17:35 V30934JMV <0.426 mg/Kg - dry 0.426 1.23Pentachlorophenol 1 03/16/23 17:35 V30934JMV <0.255 mg/Kg - dry 0.255 0.811Phenanthrene 1 03/16/23 17:35 V30934JMV <0.137 mg/Kg - dry 0.137 0.811Phenol 1 03/16/23 17:35 V30934JMV <0.164 mg/Kg - dry 0.164 0.811Pyrene 1 03/16/23 17:35 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 9 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 01 90565 Matrix: 3/7/2023 8:20 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.097 mg/Kg - dry 0.097 0.405Pyridine 1 03/16/23 17:35 V30934JMV <0.131 mg/Kg - dry 0.131 0.811 1,2,4-Trichlorobenzene 1 03/16/23 17:35 V30934JMV <0.118 mg/Kg - dry 0.118 0.8112,4,5-Trichlorophenol 1 03/16/23 17:35 V30934JMV <0.118 mg/Kg - dry 0.118 0.8112,4,6-Trichlorophenol 1 03/16/23 17:35 V30934JMV 8270ESurrogate: Phenol-d5 84.7 Limits: 34-121%03/16/23 17:351 JMV Surrogate: 2-Fluorobiphenyl 95.8 Limits: 44-115%03/16/23 17:351 JMV V30934 Surrogate: 2-Fluorophenol 88.6 Limits: 35-115%03/16/23 17:351 JMV V30934 Surrogate: Nitrobenzene-d5 91.6 Limits: 37-122%03/16/23 17:351 JMV V30934 Surrogate: 4-Terphenyl-d14 104 Limits: 54-127%03/16/23 17:351 JMV V30934 Surrogate: 2,4,6-Tribromophenol 95.5 Limits: 39-132%03/16/23 17:351 JMV V30934 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 10 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 01 90565 Matrix: 3/7/2023 8:20 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V30678 03/10/23 10:30 <5.66 mg/Kg - dry 5.66 30.8Aliphatic C9-C18 1 03/13/23 16:45 V30725AMP <7.50 mg/Kg - dry 7.50 30.8 Aliphatic C19-C36 1 03/13/23 16:45 V30725AMP <8.73 mg/Kg - dry 8.73 30.8Aromatic C11-C22 1 03/13/23 16:45 V30725AMP MADEP-EPHSurrogate: 2-Bromonaphthalene 83.2 Limits: 40-140%03/13/23 16:451 AMP MADEP-EPHSurrogate: Chlorooctadecane 86.5 Limits: 40-140%03/13/23 16:451 AMP MADEP-EPHSurrogate: OTP Surrogate 81.0 Limits: 40-140%03/13/23 16:451 AMP Surrogate: 2-Fluorobiphenyl 89.3 Limits: 40-140%03/13/23 16:451 AMP V30725 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 11 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 02 90566 Matrix: 3/7/2023 9:10 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 7.39 %Moisture 1 03/14/23 17:16 SW-DRYWTAMB Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 12 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 02 90566 Matrix: 3/7/2023 9:10 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.125 mg/Kg - dry 0.125 0.712Acenaphthene 1 03/16/23 17:58 V30934JMV <0.113 mg/Kg - dry 0.113 0.712 Acenaphthylene 1 03/16/23 17:58 V30934JMV <0.164 mg/Kg - dry 0.164 0.712Aniline 1 03/16/23 17:58 V30934JMV <0.154 mg/Kg - dry 0.154 0.712Anthracene 1 03/16/23 17:58 V30934JMV <0.150 mg/Kg - dry 0.150 0.712Benzo(a)anthracene 1 03/16/23 17:58 V30934JMV <0.158 mg/Kg - dry 0.158 0.712Benzo(a)pyrene 1 03/16/23 17:58 V30934JMV <0.157 mg/Kg - dry 0.157 0.712Benzo(b)fluoranthene 1 03/16/23 17:58 V30934JMV <0.146 mg/Kg - dry 0.146 0.712Benzo(g,h,i)perylene 1 03/16/23 17:58 V30934JMV <0.147 mg/Kg - dry 0.147 0.712 Benzo(k)fluoranthene 1 03/16/23 17:58 V30934JMV <0.626 mg/Kg - dry 0.626 2.16Benzoic Acid 1 03/16/23 17:58 V30934JMV <0.113 mg/Kg - dry 0.113 0.712Benzyl alcohol 1 03/16/23 17:58 V30934JMV <0.127 mg/Kg - dry 0.127 0.712Bis(2-Chloroethoxy)methane 1 03/16/23 17:58 V30934JMV <0.115 mg/Kg - dry 0.115 0.712Bis(2-Chloroethyl)ether 1 03/16/23 17:58 V30934JMV <0.146 mg/Kg - dry 0.146 0.356Bis(2-Chloroisopropyl)ether 1 03/16/23 17:58 V30934JMV <0.129 mg/Kg - dry 0.129 0.712Bis(2-ethylhexyl)phthalate 1 03/16/23 17:58 V30934JMV <0.117 mg/Kg - dry 0.117 0.7124-Bromophenyl phenyl ether 1 03/16/23 17:58 V30934JMV <0.122 mg/Kg - dry 0.122 0.356Butyl benzyl phthalate 1 03/16/23 17:58 V30934JMV <0.099 mg/Kg - dry 0.099 0.7124-Chloro-3-methylphenol 1 03/16/23 17:58 V30934JMV <0.120 mg/Kg - dry 0.120 0.3564-Chloroaniline 1 03/16/23 17:58 V30934JMV <0.125 mg/Kg - dry 0.125 0.7122-Chloronaphthalene 1 03/16/23 17:58 V30934JMV <0.106 mg/Kg - dry 0.106 0.7122-Chlorophenol 1 03/16/23 17:58 V30934JMV <0.136 mg/Kg - dry 0.136 1.084-Chlorophenyl phenyl ether 1 03/16/23 17:58 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 13 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 02 90566 Matrix: 3/7/2023 9:10 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.153 mg/Kg - dry 0.153 0.712Chrysene 1 03/16/23 17:58 V30934JMV <0.248 mg/Kg - dry 0.248 0.712 Dibenz(a,h)anthracene 1 03/16/23 17:58 V30934JMV <0.128 mg/Kg - dry 0.128 0.712Dibenzofuran 1 03/16/23 17:58 V30934JMV <0.101 mg/Kg - dry 0.101 0.7121,2-Dichlorobenzene 1 03/16/23 17:58 V30934JMV <0.105 mg/Kg - dry 0.105 0.7121,3-Dichlorobenzene 1 03/16/23 17:58 V30934JMV <0.105 mg/Kg - dry 0.105 0.3561,4-Dichlorobenzene 1 03/16/23 17:58 V30934JMV <0.158 mg/Kg - dry 0.158 0.7123,3'-Dichlorobenzidine 1 03/16/23 17:58 V30934JMV <0.103 mg/Kg - dry 0.103 0.7122,4-Dichlorophenol 1 03/16/23 17:58 V30934JMV <0.194 mg/Kg - dry 0.194 0.712 Diethyl phthalate 1 03/16/23 17:58 V30934JMV <0.187 mg/Kg - dry 0.187 0.712Dimethyl phthalate 1 03/16/23 17:58 V30934JMV <0.116 mg/Kg - dry 0.116 0.3562,4-Dimethylphenol 1 03/16/23 17:58 V30934JMV <0.115 mg/Kg - dry 0.115 0.712Di-n-butyl phthalate 1 03/16/23 17:58 V30934JMV <0.259 mg/Kg - dry 0.259 1.624,6-Dinitro-2-methylphenol 1 03/16/23 17:58 V30934JMV <0.561 mg/Kg - dry 0.561 1.622,4-Dinitrophenol 1 03/16/23 17:58 V30934JMV <0.104 mg/Kg - dry 0.104 0.7122,4-Dinitrotoluene 1 03/16/23 17:58 V30934JMV <0.116 mg/Kg - dry 0.116 0.7122,6-Dinitrotoluene 1 03/16/23 17:58 V30934JMV <0.154 mg/Kg - dry 0.154 0.356Di-n-Octyl Phthalate 1 03/16/23 17:58 V30934JMV <0.116 mg/Kg - dry 0.116 0.7121,2-Diphenylhydrazine/Azobenzene 1 03/16/23 17:58 V30934JMV <0.132 mg/Kg - dry 0.132 0.712Fluoranthene 1 03/16/23 17:58 V30934JMV <0.138 mg/Kg - dry 0.138 0.712Fluorene 1 03/16/23 17:58 V30934JMV <0.114 mg/Kg - dry 0.114 0.712Hexachlorobenzene 1 03/16/23 17:58 V30934JMV <0.105 mg/Kg - dry 0.105 0.712Hexachlorobutadiene 1 03/16/23 17:58 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 14 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 02 90566 Matrix: 3/7/2023 9:10 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.169 mg/Kg - dry 0.169 0.712Hexachlorocyclopentadiene 1 03/16/23 17:58 V30934JMV <0.085 mg/Kg - dry 0.085 0.712 Hexachloroethane 1 03/16/23 17:58 V30934JMV <0.193 mg/Kg - dry 0.193 0.712Indeno(1,2,3-cd)pyrene 1 03/16/23 17:58 V30934JMV <0.206 mg/Kg - dry 0.206 0.712Isophorone 1 03/16/23 17:58 V30934JMV <0.114 mg/Kg - dry 0.114 0.7121-Methylnaphthalene 1 03/16/23 17:58 V30934JMV <0.107 mg/Kg - dry 0.107 0.7122-Methylnaphthalene 1 03/16/23 17:58 V30934JMV <0.104 mg/Kg - dry 0.104 0.7122-Methylphenol 1 03/16/23 17:58 V30934JMV <0.091 mg/Kg - dry 0.091 0.7123&4 Methylphenol 1 03/16/23 17:58 V30934JMV <0.155 mg/Kg - dry 0.155 0.712 Naphthalene 1 03/16/23 17:58 V30934JMV <0.104 mg/Kg - dry 0.104 0.7122-Nitroaniline 1 03/16/23 17:58 V30934JMV <0.129 mg/Kg - dry 0.129 0.7123-Nitroaniline 1 03/16/23 17:58 V30934JMV <0.100 mg/Kg - dry 0.100 0.3564-Nitroaniline 1 03/16/23 17:58 V30934JMV <0.125 mg/Kg - dry 0.125 0.356Nitrobenzene 1 03/16/23 17:58 V30934JMV <0.095 mg/Kg - dry 0.095 0.7122-Nitrophenol 1 03/16/23 17:58 V30934JMV <0.126 mg/Kg - dry 0.126 0.7124-Nitrophenol 1 03/16/23 17:58 V30934JMV <0.283 mg/Kg - dry 0.283 0.712N-Nitrosodimethylamine 1 03/16/23 17:58 V30934JMV <0.195 mg/Kg - dry 0.195 0.712N-Nitrosodiphenylamine 1 03/16/23 17:58 V30934JMV <0.127 mg/Kg - dry 0.127 0.712N-Nitroso-di-n-propylamine 1 03/16/23 17:58 V30934JMV <0.374 mg/Kg - dry 0.374 1.08Pentachlorophenol 1 03/16/23 17:58 V30934JMV <0.224 mg/Kg - dry 0.224 0.712Phenanthrene 1 03/16/23 17:58 V30934JMV <0.120 mg/Kg - dry 0.120 0.712Phenol 1 03/16/23 17:58 V30934JMV <0.144 mg/Kg - dry 0.144 0.712Pyrene 1 03/16/23 17:58 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 15 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 02 90566 Matrix: 3/7/2023 9:10 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.085 mg/Kg - dry 0.085 0.356Pyridine 1 03/16/23 17:58 V30934JMV <0.115 mg/Kg - dry 0.115 0.712 1,2,4-Trichlorobenzene 1 03/16/23 17:58 V30934JMV <0.103 mg/Kg - dry 0.103 0.7122,4,5-Trichlorophenol 1 03/16/23 17:58 V30934JMV <0.104 mg/Kg - dry 0.104 0.7122,4,6-Trichlorophenol 1 03/16/23 17:58 V30934JMV 8270ESurrogate: Phenol-d5 82.3 Limits: 34-121%03/16/23 17:581 JMV Surrogate: 2-Fluorobiphenyl 94.6 Limits: 44-115%03/16/23 17:581 JMV V30934 Surrogate: 2-Fluorophenol 85.9 Limits: 35-115%03/16/23 17:581 JMV V30934 Surrogate: Nitrobenzene-d5 86.2 Limits: 37-122%03/16/23 17:581 JMV V30934 Surrogate: 4-Terphenyl-d14 105 Limits: 54-127%03/16/23 17:581 JMV V30934 Surrogate: 2,4,6-Tribromophenol 95.2 Limits: 39-132%03/16/23 17:581 JMV V30934 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 16 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 02 90566 Matrix: 3/7/2023 9:10 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V30678 03/10/23 10:30 <9.93 mg/Kg - dry 9.93 54.0Aliphatic C9-C18 1 03/13/23 17:21 V30725AMP <13.2 mg/Kg - dry 13.2 54.0 Aliphatic C19-C36 1 03/13/23 17:21 V30725AMP <15.3 mg/Kg - dry 15.3 54.0Aromatic C11-C22 1 03/13/23 17:21 V30725AMP MADEP-EPHSurrogate: 2-Bromonaphthalene 85.3 Limits: 40-140%03/13/23 17:211 AMP MADEP-EPHSurrogate: Chlorooctadecane 92.8 Limits: 40-140%03/13/23 17:211 AMP MADEP-EPHSurrogate: OTP Surrogate 80.8 Limits: 40-140%03/13/23 17:211 AMP Surrogate: 2-Fluorobiphenyl 94.5 Limits: 40-140%03/13/23 17:211 AMP V30725 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 17 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 03 90567 Matrix: 3/7/2023 11:00 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 11.9 %Moisture 1 03/14/23 17:16 SW-DRYWTAMB Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 18 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 03 90567 Matrix: 3/7/2023 11:00 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.131 mg/Kg - dry 0.131 0.749Acenaphthene 1 03/16/23 18:20 V30934JMV <0.119 mg/Kg - dry 0.119 0.749 Acenaphthylene 1 03/16/23 18:20 V30934JMV <0.172 mg/Kg - dry 0.172 0.749Aniline 1 03/16/23 18:20 V30934JMV <0.162 mg/Kg - dry 0.162 0.749Anthracene 1 03/16/23 18:20 V30934JMV <0.157 mg/Kg - dry 0.157 0.749Benzo(a)anthracene 1 03/16/23 18:20 V30934JMV <0.166 mg/Kg - dry 0.166 0.749Benzo(a)pyrene 1 03/16/23 18:20 V30934JMV <0.165 mg/Kg - dry 0.165 0.749Benzo(b)fluoranthene 1 03/16/23 18:20 V30934JMV <0.154 mg/Kg - dry 0.154 0.749Benzo(g,h,i)perylene 1 03/16/23 18:20 V30934JMV <0.155 mg/Kg - dry 0.155 0.749 Benzo(k)fluoranthene 1 03/16/23 18:20 V30934JMV <0.658 mg/Kg - dry 0.658 2.27Benzoic Acid 1 03/16/23 18:20 V30934JMV <0.119 mg/Kg - dry 0.119 0.749Benzyl alcohol 1 03/16/23 18:20 V30934JMV <0.133 mg/Kg - dry 0.133 0.749Bis(2-Chloroethoxy)methane 1 03/16/23 18:20 V30934JMV <0.121 mg/Kg - dry 0.121 0.749Bis(2-Chloroethyl)ether 1 03/16/23 18:20 V30934JMV <0.154 mg/Kg - dry 0.154 0.374Bis(2-Chloroisopropyl)ether 1 03/16/23 18:20 V30934JMV <0.136 mg/Kg - dry 0.136 0.749Bis(2-ethylhexyl)phthalate 1 03/16/23 18:20 V30934JMV <0.123 mg/Kg - dry 0.123 0.7494-Bromophenyl phenyl ether 1 03/16/23 18:20 V30934JMV <0.128 mg/Kg - dry 0.128 0.374Butyl benzyl phthalate 1 03/16/23 18:20 V30934JMV <0.104 mg/Kg - dry 0.104 0.7494-Chloro-3-methylphenol 1 03/16/23 18:20 V30934JMV <0.127 mg/Kg - dry 0.127 0.3744-Chloroaniline 1 03/16/23 18:20 V30934JMV <0.131 mg/Kg - dry 0.131 0.7492-Chloronaphthalene 1 03/16/23 18:20 V30934JMV <0.111 mg/Kg - dry 0.111 0.7492-Chlorophenol 1 03/16/23 18:20 V30934JMV <0.143 mg/Kg - dry 0.143 1.144-Chlorophenyl phenyl ether 1 03/16/23 18:20 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 19 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 03 90567 Matrix: 3/7/2023 11:00 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.161 mg/Kg - dry 0.161 0.749Chrysene 1 03/16/23 18:20 V30934JMV <0.261 mg/Kg - dry 0.261 0.749 Dibenz(a,h)anthracene 1 03/16/23 18:20 V30934JMV <0.135 mg/Kg - dry 0.135 0.749Dibenzofuran 1 03/16/23 18:20 V30934JMV <0.107 mg/Kg - dry 0.107 0.7491,2-Dichlorobenzene 1 03/16/23 18:20 V30934JMV <0.110 mg/Kg - dry 0.110 0.7491,3-Dichlorobenzene 1 03/16/23 18:20 V30934JMV <0.110 mg/Kg - dry 0.110 0.3741,4-Dichlorobenzene 1 03/16/23 18:20 V30934JMV <0.166 mg/Kg - dry 0.166 0.7493,3'-Dichlorobenzidine 1 03/16/23 18:20 V30934JMV <0.108 mg/Kg - dry 0.108 0.7492,4-Dichlorophenol 1 03/16/23 18:20 V30934JMV <0.204 mg/Kg - dry 0.204 0.749 Diethyl phthalate 1 03/16/23 18:20 V30934JMV <0.197 mg/Kg - dry 0.197 0.749Dimethyl phthalate 1 03/16/23 18:20 V30934JMV <0.122 mg/Kg - dry 0.122 0.3742,4-Dimethylphenol 1 03/16/23 18:20 V30934JMV <0.121 mg/Kg - dry 0.121 0.749Di-n-butyl phthalate 1 03/16/23 18:20 V30934JMV <0.272 mg/Kg - dry 0.272 1.704,6-Dinitro-2-methylphenol 1 03/16/23 18:20 V30934JMV <0.590 mg/Kg - dry 0.590 1.702,4-Dinitrophenol 1 03/16/23 18:20 V30934JMV <0.109 mg/Kg - dry 0.109 0.7492,4-Dinitrotoluene 1 03/16/23 18:20 V30934JMV <0.122 mg/Kg - dry 0.122 0.7492,6-Dinitrotoluene 1 03/16/23 18:20 V30934JMV <0.162 mg/Kg - dry 0.162 0.374Di-n-Octyl Phthalate 1 03/16/23 18:20 V30934JMV <0.122 mg/Kg - dry 0.122 0.7491,2-Diphenylhydrazine/Azobenzene 1 03/16/23 18:20 V30934JMV <0.139 mg/Kg - dry 0.139 0.749Fluoranthene 1 03/16/23 18:20 V30934JMV <0.145 mg/Kg - dry 0.145 0.749Fluorene 1 03/16/23 18:20 V30934JMV <0.120 mg/Kg - dry 0.120 0.749Hexachlorobenzene 1 03/16/23 18:20 V30934JMV <0.110 mg/Kg - dry 0.110 0.749Hexachlorobutadiene 1 03/16/23 18:20 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 20 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 03 90567 Matrix: 3/7/2023 11:00 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.178 mg/Kg - dry 0.178 0.749Hexachlorocyclopentadiene 1 03/16/23 18:20 V30934JMV <0.089 mg/Kg - dry 0.089 0.749 Hexachloroethane 1 03/16/23 18:20 V30934JMV <0.203 mg/Kg - dry 0.203 0.749Indeno(1,2,3-cd)pyrene 1 03/16/23 18:20 V30934JMV <0.216 mg/Kg - dry 0.216 0.749Isophorone 1 03/16/23 18:20 V30934JMV <0.120 mg/Kg - dry 0.120 0.7491-Methylnaphthalene 1 03/16/23 18:20 V30934JMV <0.113 mg/Kg - dry 0.113 0.7492-Methylnaphthalene 1 03/16/23 18:20 V30934JMV <0.110 mg/Kg - dry 0.110 0.7492-Methylphenol 1 03/16/23 18:20 V30934JMV <0.096 mg/Kg - dry 0.096 0.7493&4 Methylphenol 1 03/16/23 18:20 V30934JMV <0.163 mg/Kg - dry 0.163 0.749 Naphthalene 1 03/16/23 18:20 V30934JMV <0.109 mg/Kg - dry 0.109 0.7492-Nitroaniline 1 03/16/23 18:20 V30934JMV <0.136 mg/Kg - dry 0.136 0.7493-Nitroaniline 1 03/16/23 18:20 V30934JMV <0.105 mg/Kg - dry 0.105 0.3744-Nitroaniline 1 03/16/23 18:20 V30934JMV <0.131 mg/Kg - dry 0.131 0.374Nitrobenzene 1 03/16/23 18:20 V30934JMV <0.100 mg/Kg - dry 0.100 0.7492-Nitrophenol 1 03/16/23 18:20 V30934JMV <0.132 mg/Kg - dry 0.132 0.7494-Nitrophenol 1 03/16/23 18:20 V30934JMV <0.298 mg/Kg - dry 0.298 0.749N-Nitrosodimethylamine 1 03/16/23 18:20 V30934JMV <0.205 mg/Kg - dry 0.205 0.749N-Nitrosodiphenylamine 1 03/16/23 18:20 V30934JMV <0.133 mg/Kg - dry 0.133 0.749N-Nitroso-di-n-propylamine 1 03/16/23 18:20 V30934JMV <0.393 mg/Kg - dry 0.393 1.14Pentachlorophenol 1 03/16/23 18:20 V30934JMV <0.236 mg/Kg - dry 0.236 0.749Phenanthrene 1 03/16/23 18:20 V30934JMV <0.127 mg/Kg - dry 0.127 0.749Phenol 1 03/16/23 18:20 V30934JMV <0.152 mg/Kg - dry 0.152 0.749Pyrene 1 03/16/23 18:20 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 21 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 03 90567 Matrix: 3/7/2023 11:00 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.089 mg/Kg - dry 0.089 0.374Pyridine 1 03/16/23 18:20 V30934JMV <0.121 mg/Kg - dry 0.121 0.749 1,2,4-Trichlorobenzene 1 03/16/23 18:20 V30934JMV <0.109 mg/Kg - dry 0.109 0.7492,4,5-Trichlorophenol 1 03/16/23 18:20 V30934JMV <0.109 mg/Kg - dry 0.109 0.7492,4,6-Trichlorophenol 1 03/16/23 18:20 V30934JMV 8270ESurrogate: Phenol-d5 76.3 Limits: 34-121%03/16/23 18:201 JMV Surrogate: 2-Fluorobiphenyl 88.0 Limits: 44-115%03/16/23 18:201 JMV V30934 Surrogate: 2-Fluorophenol 79.9 Limits: 35-115%03/16/23 18:201 JMV V30934 Surrogate: Nitrobenzene-d5 78.4 Limits: 37-122%03/16/23 18:201 JMV V30934 Surrogate: 4-Terphenyl-d14 102 Limits: 54-127%03/16/23 18:201 JMV V30934 Surrogate: 2,4,6-Tribromophenol 90.1 Limits: 39-132%03/16/23 18:201 JMV V30934 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 22 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 03 90567 Matrix: 3/7/2023 11:00 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V30678 03/10/23 10:30 <10.4 mg/Kg - dry 10.4 56.8Aliphatic C9-C18 1 03/13/23 17:58 V30725AMP 193 mg/Kg - dry 13.8 56.8 Aliphatic C19-C36 1 03/13/23 17:58 V30725AMP <16.1 mg/Kg - dry 16.1 56.8Aromatic C11-C22 1 03/13/23 17:58 V30725AMP MADEP-EPHSurrogate: 2-Bromonaphthalene 85.5 Limits: 40-140%03/13/23 17:581 AMP MADEP-EPHSurrogate: Chlorooctadecane 88.4 Limits: 40-140%03/13/23 17:581 AMP MADEP-EPHSurrogate: OTP Surrogate 79.0 Limits: 40-140%03/13/23 17:581 AMP Surrogate: 2-Fluorobiphenyl 91.3 Limits: 40-140%03/13/23 17:581 AMP V30725 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 23 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 04 90568 Matrix: 3/7/2023 11:45 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 22.6 %Moisture 1 03/14/23 17:16 SW-DRYWTAMB Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 24 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 04 90568 Matrix: 3/7/2023 11:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.149 mg/Kg - dry 0.149 0.854Acenaphthene 1 03/16/23 18:43 V30934JMV <0.135 mg/Kg - dry 0.135 0.854 Acenaphthylene 1 03/16/23 18:43 V30934JMV <0.196 mg/Kg - dry 0.196 0.854Aniline 1 03/16/23 18:43 V30934JMV <0.184 mg/Kg - dry 0.184 0.854Anthracene 1 03/16/23 18:43 V30934JMV <0.179 mg/Kg - dry 0.179 0.854Benzo(a)anthracene 1 03/16/23 18:43 V30934JMV <0.189 mg/Kg - dry 0.189 0.854Benzo(a)pyrene 1 03/16/23 18:43 V30934JMV <0.188 mg/Kg - dry 0.188 0.854Benzo(b)fluoranthene 1 03/16/23 18:43 V30934JMV <0.175 mg/Kg - dry 0.175 0.854Benzo(g,h,i)perylene 1 03/16/23 18:43 V30934JMV <0.177 mg/Kg - dry 0.177 0.854 Benzo(k)fluoranthene 1 03/16/23 18:43 V30934JMV <0.749 mg/Kg - dry 0.749 2.58Benzoic Acid 1 03/16/23 18:43 V30934JMV <0.135 mg/Kg - dry 0.135 0.854Benzyl alcohol 1 03/16/23 18:43 V30934JMV <0.152 mg/Kg - dry 0.152 0.854Bis(2-Chloroethoxy)methane 1 03/16/23 18:43 V30934JMV <0.138 mg/Kg - dry 0.138 0.854Bis(2-Chloroethyl)ether 1 03/16/23 18:43 V30934JMV <0.175 mg/Kg - dry 0.175 0.426Bis(2-Chloroisopropyl)ether 1 03/16/23 18:43 V30934JMV <0.155 mg/Kg - dry 0.155 0.854Bis(2-ethylhexyl)phthalate 1 03/16/23 18:43 V30934JMV <0.140 mg/Kg - dry 0.140 0.8544-Bromophenyl phenyl ether 1 03/16/23 18:43 V30934JMV <0.145 mg/Kg - dry 0.145 0.426Butyl benzyl phthalate 1 03/16/23 18:43 V30934JMV <0.119 mg/Kg - dry 0.119 0.8544-Chloro-3-methylphenol 1 03/16/23 18:43 V30934JMV <0.144 mg/Kg - dry 0.144 0.4264-Chloroaniline 1 03/16/23 18:43 V30934JMV <0.149 mg/Kg - dry 0.149 0.8542-Chloronaphthalene 1 03/16/23 18:43 V30934JMV <0.127 mg/Kg - dry 0.127 0.8542-Chlorophenol 1 03/16/23 18:43 V30934JMV <0.162 mg/Kg - dry 0.162 1.294-Chlorophenyl phenyl ether 1 03/16/23 18:43 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 25 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 04 90568 Matrix: 3/7/2023 11:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.183 mg/Kg - dry 0.183 0.854Chrysene 1 03/16/23 18:43 V30934JMV <0.297 mg/Kg - dry 0.297 0.854 Dibenz(a,h)anthracene 1 03/16/23 18:43 V30934JMV <0.153 mg/Kg - dry 0.153 0.854Dibenzofuran 1 03/16/23 18:43 V30934JMV <0.122 mg/Kg - dry 0.122 0.8541,2-Dichlorobenzene 1 03/16/23 18:43 V30934JMV <0.125 mg/Kg - dry 0.125 0.8541,3-Dichlorobenzene 1 03/16/23 18:43 V30934JMV <0.125 mg/Kg - dry 0.125 0.4261,4-Dichlorobenzene 1 03/16/23 18:43 V30934JMV <0.189 mg/Kg - dry 0.189 0.8543,3'-Dichlorobenzidine 1 03/16/23 18:43 V30934JMV <0.123 mg/Kg - dry 0.123 0.8542,4-Dichlorophenol 1 03/16/23 18:43 V30934JMV <0.232 mg/Kg - dry 0.232 0.854 Diethyl phthalate 1 03/16/23 18:43 V30934JMV <0.224 mg/Kg - dry 0.224 0.854Dimethyl phthalate 1 03/16/23 18:43 V30934JMV <0.139 mg/Kg - dry 0.139 0.4262,4-Dimethylphenol 1 03/16/23 18:43 V30934JMV <0.138 mg/Kg - dry 0.138 0.854Di-n-butyl phthalate 1 03/16/23 18:43 V30934JMV <0.310 mg/Kg - dry 0.310 1.944,6-Dinitro-2-methylphenol 1 03/16/23 18:43 V30934JMV <0.671 mg/Kg - dry 0.671 1.942,4-Dinitrophenol 1 03/16/23 18:43 V30934JMV <0.124 mg/Kg - dry 0.124 0.8542,4-Dinitrotoluene 1 03/16/23 18:43 V30934JMV <0.139 mg/Kg - dry 0.139 0.8542,6-Dinitrotoluene 1 03/16/23 18:43 V30934JMV <0.184 mg/Kg - dry 0.184 0.426Di-n-Octyl Phthalate 1 03/16/23 18:43 V30934JMV <0.139 mg/Kg - dry 0.139 0.8541,2-Diphenylhydrazine/Azobenzene 1 03/16/23 18:43 V30934JMV <0.158 mg/Kg - dry 0.158 0.854Fluoranthene 1 03/16/23 18:43 V30934JMV <0.165 mg/Kg - dry 0.165 0.854Fluorene 1 03/16/23 18:43 V30934JMV <0.136 mg/Kg - dry 0.136 0.854Hexachlorobenzene 1 03/16/23 18:43 V30934JMV <0.126 mg/Kg - dry 0.126 0.854Hexachlorobutadiene 1 03/16/23 18:43 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 26 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 04 90568 Matrix: 3/7/2023 11:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.202 mg/Kg - dry 0.202 0.854Hexachlorocyclopentadiene 1 03/16/23 18:43 V30934JMV <0.102 mg/Kg - dry 0.102 0.854 Hexachloroethane 1 03/16/23 18:43 V30934JMV <0.231 mg/Kg - dry 0.231 0.854Indeno(1,2,3-cd)pyrene 1 03/16/23 18:43 V30934JMV <0.246 mg/Kg - dry 0.246 0.854Isophorone 1 03/16/23 18:43 V30934JMV <0.136 mg/Kg - dry 0.136 0.8541-Methylnaphthalene 1 03/16/23 18:43 V30934JMV <0.129 mg/Kg - dry 0.129 0.8542-Methylnaphthalene 1 03/16/23 18:43 V30934JMV <0.125 mg/Kg - dry 0.125 0.8542-Methylphenol 1 03/16/23 18:43 V30934JMV <0.109 mg/Kg - dry 0.109 0.8543&4 Methylphenol 1 03/16/23 18:43 V30934JMV <0.186 mg/Kg - dry 0.186 0.854 Naphthalene 1 03/16/23 18:43 V30934JMV <0.125 mg/Kg - dry 0.125 0.8542-Nitroaniline 1 03/16/23 18:43 V30934JMV <0.155 mg/Kg - dry 0.155 0.8543-Nitroaniline 1 03/16/23 18:43 V30934JMV <0.120 mg/Kg - dry 0.120 0.4264-Nitroaniline 1 03/16/23 18:43 V30934JMV <0.149 mg/Kg - dry 0.149 0.426Nitrobenzene 1 03/16/23 18:43 V30934JMV <0.114 mg/Kg - dry 0.114 0.8542-Nitrophenol 1 03/16/23 18:43 V30934JMV <0.151 mg/Kg - dry 0.151 0.8544-Nitrophenol 1 03/16/23 18:43 V30934JMV <0.339 mg/Kg - dry 0.339 0.854N-Nitrosodimethylamine 1 03/16/23 18:43 V30934JMV <0.233 mg/Kg - dry 0.233 0.854N-Nitrosodiphenylamine 1 03/16/23 18:43 V30934JMV <0.152 mg/Kg - dry 0.152 0.854N-Nitroso-di-n-propylamine 1 03/16/23 18:43 V30934JMV <0.448 mg/Kg - dry 0.448 1.29Pentachlorophenol 1 03/16/23 18:43 V30934JMV <0.268 mg/Kg - dry 0.268 0.854Phenanthrene 1 03/16/23 18:43 V30934JMV <0.144 mg/Kg - dry 0.144 0.854Phenol 1 03/16/23 18:43 V30934JMV <0.173 mg/Kg - dry 0.173 0.854Pyrene 1 03/16/23 18:43 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 27 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 04 90568 Matrix: 3/7/2023 11:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.102 mg/Kg - dry 0.102 0.426Pyridine 1 03/16/23 18:43 V30934JMV <0.138 mg/Kg - dry 0.138 0.854 1,2,4-Trichlorobenzene 1 03/16/23 18:43 V30934JMV <0.124 mg/Kg - dry 0.124 0.8542,4,5-Trichlorophenol 1 03/16/23 18:43 V30934JMV <0.124 mg/Kg - dry 0.124 0.8542,4,6-Trichlorophenol 1 03/16/23 18:43 V30934JMV 8270ESurrogate: Phenol-d5 76.0 Limits: 34-121%03/16/23 18:431 JMV Surrogate: 2-Fluorobiphenyl 85.6 Limits: 44-115%03/16/23 18:431 JMV V30934 Surrogate: 2-Fluorophenol 79.9 Limits: 35-115%03/16/23 18:431 JMV V30934 Surrogate: Nitrobenzene-d5 78.4 Limits: 37-122%03/16/23 18:431 JMV V30934 Surrogate: 4-Terphenyl-d14 97.6 Limits: 54-127%03/16/23 18:431 JMV V30934 Surrogate: 2,4,6-Tribromophenol 85.9 Limits: 39-132%03/16/23 18:431 JMV V30934 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 28 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 04 90568 Matrix: 3/7/2023 11:45 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V30678 03/10/23 10:30 <11.9 mg/Kg - dry 11.9 64.5Aliphatic C9-C18 1 03/13/23 18:34 V30725AMP <15.8 mg/Kg - dry 15.8 64.5 Aliphatic C19-C36 1 03/13/23 18:34 V30725AMP <18.3 mg/Kg - dry 18.3 64.5Aromatic C11-C22 1 03/13/23 18:34 V30725AMP MADEP-EPHSurrogate: 2-Bromonaphthalene 77.7 Limits: 40-140%03/13/23 18:341 AMP MADEP-EPHSurrogate: Chlorooctadecane 97.9 Limits: 40-140%03/13/23 18:341 AMP MADEP-EPHSurrogate: OTP Surrogate 73.8 Limits: 40-140%03/13/23 18:341 AMP Surrogate: 2-Fluorobiphenyl 86.7 Limits: 40-140%03/13/23 18:341 AMP V30725 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 29 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 05 90569 Matrix: 3/7/2023 12:30 Solids Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 16.8 %Moisture 1 03/14/23 17:16 SW-DRYWTAMB Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 30 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 05 90569 Matrix: 3/7/2023 12:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.139 mg/Kg - dry 0.139 0.793Acenaphthene 1 03/16/23 19:05 V30934JMV <0.126 mg/Kg - dry 0.126 0.793 Acenaphthylene 1 03/16/23 19:05 V30934JMV <0.182 mg/Kg - dry 0.182 0.793Aniline 1 03/16/23 19:05 V30934JMV <0.171 mg/Kg - dry 0.171 0.793Anthracene 1 03/16/23 19:05 V30934JMV <0.167 mg/Kg - dry 0.167 0.793Benzo(a)anthracene 1 03/16/23 19:05 V30934JMV <0.176 mg/Kg - dry 0.176 0.793Benzo(a)pyrene 1 03/16/23 19:05 V30934JMV <0.175 mg/Kg - dry 0.175 0.793Benzo(b)fluoranthene 1 03/16/23 19:05 V30934JMV <0.163 mg/Kg - dry 0.163 0.793Benzo(g,h,i)perylene 1 03/16/23 19:05 V30934JMV <0.164 mg/Kg - dry 0.164 0.793 Benzo(k)fluoranthene 1 03/16/23 19:05 V30934JMV <0.697 mg/Kg - dry 0.697 2.40Benzoic Acid 1 03/16/23 19:05 V30934JMV <0.126 mg/Kg - dry 0.126 0.793Benzyl alcohol 1 03/16/23 19:05 V30934JMV <0.141 mg/Kg - dry 0.141 0.793Bis(2-Chloroethoxy)methane 1 03/16/23 19:05 V30934JMV <0.128 mg/Kg - dry 0.128 0.793Bis(2-Chloroethyl)ether 1 03/16/23 19:05 V30934JMV <0.163 mg/Kg - dry 0.163 0.396Bis(2-Chloroisopropyl)ether 1 03/16/23 19:05 V30934JMV <0.144 mg/Kg - dry 0.144 0.793Bis(2-ethylhexyl)phthalate 1 03/16/23 19:05 V30934JMV <0.131 mg/Kg - dry 0.131 0.7934-Bromophenyl phenyl ether 1 03/16/23 19:05 V30934JMV <0.135 mg/Kg - dry 0.135 0.396Butyl benzyl phthalate 1 03/16/23 19:05 V30934JMV <0.111 mg/Kg - dry 0.111 0.7934-Chloro-3-methylphenol 1 03/16/23 19:05 V30934JMV <0.134 mg/Kg - dry 0.134 0.3964-Chloroaniline 1 03/16/23 19:05 V30934JMV <0.139 mg/Kg - dry 0.139 0.7932-Chloronaphthalene 1 03/16/23 19:05 V30934JMV <0.118 mg/Kg - dry 0.118 0.7932-Chlorophenol 1 03/16/23 19:05 V30934JMV <0.151 mg/Kg - dry 0.151 1.204-Chlorophenyl phenyl ether 1 03/16/23 19:05 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 31 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 05 90569 Matrix: 3/7/2023 12:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.170 mg/Kg - dry 0.170 0.793Chrysene 1 03/16/23 19:05 V30934JMV <0.276 mg/Kg - dry 0.276 0.793 Dibenz(a,h)anthracene 1 03/16/23 19:05 V30934JMV <0.143 mg/Kg - dry 0.143 0.793Dibenzofuran 1 03/16/23 19:05 V30934JMV <0.113 mg/Kg - dry 0.113 0.7931,2-Dichlorobenzene 1 03/16/23 19:05 V30934JMV <0.116 mg/Kg - dry 0.116 0.7931,3-Dichlorobenzene 1 03/16/23 19:05 V30934JMV <0.117 mg/Kg - dry 0.117 0.3961,4-Dichlorobenzene 1 03/16/23 19:05 V30934JMV <0.176 mg/Kg - dry 0.176 0.7933,3'-Dichlorobenzidine 1 03/16/23 19:05 V30934JMV <0.115 mg/Kg - dry 0.115 0.7932,4-Dichlorophenol 1 03/16/23 19:05 V30934JMV <0.216 mg/Kg - dry 0.216 0.793 Diethyl phthalate 1 03/16/23 19:05 V30934JMV <0.209 mg/Kg - dry 0.209 0.793Dimethyl phthalate 1 03/16/23 19:05 V30934JMV <0.129 mg/Kg - dry 0.129 0.3962,4-Dimethylphenol 1 03/16/23 19:05 V30934JMV <0.128 mg/Kg - dry 0.128 0.793Di-n-butyl phthalate 1 03/16/23 19:05 V30934JMV <0.288 mg/Kg - dry 0.288 1.804,6-Dinitro-2-methylphenol 1 03/16/23 19:05 V30934JMV <0.625 mg/Kg - dry 0.625 1.802,4-Dinitrophenol 1 03/16/23 19:05 V30934JMV <0.116 mg/Kg - dry 0.116 0.7932,4-Dinitrotoluene 1 03/16/23 19:05 V30934JMV <0.129 mg/Kg - dry 0.129 0.7932,6-Dinitrotoluene 1 03/16/23 19:05 V30934JMV <0.171 mg/Kg - dry 0.171 0.396Di-n-Octyl Phthalate 1 03/16/23 19:05 V30934JMV <0.129 mg/Kg - dry 0.129 0.7931,2-Diphenylhydrazine/Azobenzene 1 03/16/23 19:05 V30934JMV <0.147 mg/Kg - dry 0.147 0.793Fluoranthene 1 03/16/23 19:05 V30934JMV <0.153 mg/Kg - dry 0.153 0.793Fluorene 1 03/16/23 19:05 V30934JMV <0.127 mg/Kg - dry 0.127 0.793Hexachlorobenzene 1 03/16/23 19:05 V30934JMV <0.117 mg/Kg - dry 0.117 0.793Hexachlorobutadiene 1 03/16/23 19:05 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 32 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 05 90569 Matrix: 3/7/2023 12:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.188 mg/Kg - dry 0.188 0.793Hexachlorocyclopentadiene 1 03/16/23 19:05 V30934JMV <0.095 mg/Kg - dry 0.095 0.793 Hexachloroethane 1 03/16/23 19:05 V30934JMV <0.215 mg/Kg - dry 0.215 0.793Indeno(1,2,3-cd)pyrene 1 03/16/23 19:05 V30934JMV <0.229 mg/Kg - dry 0.229 0.793Isophorone 1 03/16/23 19:05 V30934JMV <0.127 mg/Kg - dry 0.127 0.7931-Methylnaphthalene 1 03/16/23 19:05 V30934JMV <0.120 mg/Kg - dry 0.120 0.7932-Methylnaphthalene 1 03/16/23 19:05 V30934JMV <0.116 mg/Kg - dry 0.116 0.7932-Methylphenol 1 03/16/23 19:05 V30934JMV <0.102 mg/Kg - dry 0.102 0.7933&4 Methylphenol 1 03/16/23 19:05 V30934JMV <0.173 mg/Kg - dry 0.173 0.793 Naphthalene 1 03/16/23 19:05 V30934JMV <0.116 mg/Kg - dry 0.116 0.7932-Nitroaniline 1 03/16/23 19:05 V30934JMV <0.144 mg/Kg - dry 0.144 0.7933-Nitroaniline 1 03/16/23 19:05 V30934JMV <0.112 mg/Kg - dry 0.112 0.3964-Nitroaniline 1 03/16/23 19:05 V30934JMV <0.139 mg/Kg - dry 0.139 0.396Nitrobenzene 1 03/16/23 19:05 V30934JMV <0.106 mg/Kg - dry 0.106 0.7932-Nitrophenol 1 03/16/23 19:05 V30934JMV <0.140 mg/Kg - dry 0.140 0.7934-Nitrophenol 1 03/16/23 19:05 V30934JMV <0.316 mg/Kg - dry 0.316 0.793N-Nitrosodimethylamine 1 03/16/23 19:05 V30934JMV <0.217 mg/Kg - dry 0.217 0.793N-Nitrosodiphenylamine 1 03/16/23 19:05 V30934JMV <0.141 mg/Kg - dry 0.141 0.793N-Nitroso-di-n-propylamine 1 03/16/23 19:05 V30934JMV <0.417 mg/Kg - dry 0.417 1.20Pentachlorophenol 1 03/16/23 19:05 V30934JMV <0.250 mg/Kg - dry 0.250 0.793Phenanthrene 1 03/16/23 19:05 V30934JMV <0.134 mg/Kg - dry 0.134 0.793Phenol 1 03/16/23 19:05 V30934JMV <0.161 mg/Kg - dry 0.161 0.793Pyrene 1 03/16/23 19:05 V30934JMV Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 33 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 05 90569 Matrix: 3/7/2023 12:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 3546 8270E Prep Batch(es):V30852 03/15/23 12:00 <0.095 mg/Kg - dry 0.095 0.396Pyridine 1 03/16/23 19:05 V30934JMV <0.128 mg/Kg - dry 0.128 0.793 1,2,4-Trichlorobenzene 1 03/16/23 19:05 V30934JMV <0.115 mg/Kg - dry 0.115 0.7932,4,5-Trichlorophenol 1 03/16/23 19:05 V30934JMV <0.116 mg/Kg - dry 0.116 0.7932,4,6-Trichlorophenol 1 03/16/23 19:05 V30934JMV 8270ESurrogate: Phenol-d5 85.6 Limits: 34-121%03/16/23 19:051 JMV Surrogate: 2-Fluorobiphenyl 95.2 Limits: 44-115%03/16/23 19:051 JMV V30934 Surrogate: 2-Fluorophenol 88.9 Limits: 35-115%03/16/23 19:051 JMV V30934 Surrogate: Nitrobenzene-d5 87.4 Limits: 37-122%03/16/23 19:051 JMV V30934 Surrogate: 4-Terphenyl-d14 106 Limits: 54-127%03/16/23 19:051 JMV V30934 Surrogate: 2,4,6-Tribromophenol 96.7 Limits: 39-132%03/16/23 19:051 JMV V30934 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 34 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 , REPORT OF ANALYSISReport Number : Project Information : NC 27603 23-067-0018 01186 Smith & Gardner, Inc. 14 N. Boylan Avenue Seth C. Rickerts Raleigh Received : 03/08/2023 GFL Wade Revised Report Date : 03/24/2023 Original Report Date : 03/17/2023 Sample ID : Lab No : Sampled:Post - 05 90569 Matrix: 3/7/2023 12:30 Solids Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAEPH (Prep) MADEP-EPH Prep Batch(es):V30678 03/10/23 10:30 <11.1 mg/Kg - dry 11.1 60.3Aliphatic C9-C18 1 03/13/23 19:10 V30725AMP <14.7 mg/Kg - dry 14.7 60.3 Aliphatic C19-C36 1 03/13/23 19:10 V30725AMP <17.2 mg/Kg - dry 17.2 60.3Aromatic C11-C22 1 03/13/23 19:10 V30725AMP MADEP-EPHSurrogate: 2-Bromonaphthalene 94.3 Limits: 40-140%03/13/23 19:101 AMP MADEP-EPHSurrogate: Chlorooctadecane 82.6 Limits: 40-140%03/13/23 19:101 AMP MADEP-EPHSurrogate: OTP Surrogate 68.1 Limits: 40-140%03/13/23 19:101 AMP Surrogate: 2-Fluorobiphenyl 101 Limits: 40-140%03/13/23 19:101 AMP V30725 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 35 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V30934QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V30852 Associated Lab Samples: 90565, 90566, 90567, 90568, 90569 LRB-V30852 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 03/16/23 14:580.6600.116<0.116mg/KgAcenaphthene 03/16/23 14:580.6600.105<0.105mg/KgAcenaphthylene 03/16/23 14:580.6600.152<0.152mg/KgAniline 03/16/23 14:580.6600.143<0.143mg/KgAnthracene 03/16/23 14:580.6600.139<0.139mg/KgBenzo(a)anthracene 03/16/23 14:580.6600.147<0.147mg/KgBenzo(a)pyrene 03/16/23 14:580.6600.146<0.146mg/KgBenzo(b)fluoranthene 03/16/23 14:580.6600.136<0.136mg/KgBenzo(g,h,i)perylene 03/16/23 14:580.6600.137<0.137mg/KgBenzo(k)fluoranthene 03/16/23 14:582.000.580<0.580mg/KgBenzoic Acid 03/16/23 14:580.6600.105<0.105mg/KgBenzyl alcohol 03/16/23 14:580.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane 03/16/23 14:580.6600.107<0.107mg/KgBis(2-Chloroethyl)ether 03/16/23 14:580.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether 03/16/23 14:580.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate 03/16/23 14:580.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether 03/16/23 14:580.3300.113<0.113mg/KgButyl benzyl phthalate 03/16/23 14:580.6600.092<0.092mg/Kg4-Chloro-3-methylphenol 03/16/23 14:580.3300.112<0.112mg/Kg4-Chloroaniline 03/16/23 14:580.6600.116<0.116mg/Kg2-Chloronaphthalene 03/16/23 14:580.6600.098<0.098mg/Kg2-Chlorophenol 03/16/23 14:581.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether 03/16/23 14:580.6600.142<0.142mg/KgChrysene 03/16/23 14:580.6600.230<0.230mg/KgDibenz(a,h)anthracene 03/16/23 14:580.6600.119<0.119mg/KgDibenzofuran 03/16/23 14:580.6600.094<0.094mg/Kg1,2-Dichlorobenzene 03/16/23 14:580.6600.097<0.097mg/Kg1,3-Dichlorobenzene Page 1 of 9Date:03/17/2023 04:19 PM Page 36 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V30934QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V30852 Associated Lab Samples: 90565, 90566, 90567, 90568, 90569 LRB-V30852 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 03/16/23 14:580.3300.097<0.097mg/Kg1,4-Dichlorobenzene 03/16/23 14:580.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine 03/16/23 14:580.6600.095<0.095mg/Kg2,4-Dichlorophenol 03/16/23 14:580.6600.180<0.180mg/KgDiethyl phthalate 03/16/23 14:580.6600.174<0.174mg/KgDimethyl phthalate 03/16/23 14:580.3300.108<0.108mg/Kg2,4-Dimethylphenol 03/16/23 14:580.6600.107<0.107mg/KgDi-n-butyl phthalate 03/16/23 14:581.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol 03/16/23 14:581.500.520<0.520mg/Kg2,4-Dinitrophenol 03/16/23 14:580.6600.096<0.096mg/Kg2,4-Dinitrotoluene 03/16/23 14:580.6600.108<0.108mg/Kg2,6-Dinitrotoluene 03/16/23 14:580.3300.143<0.143mg/KgDi-n-Octyl Phthalate 03/16/23 14:580.6600.123<0.123mg/KgFluoranthene 03/16/23 14:580.6600.128<0.128mg/KgFluorene 03/16/23 14:580.6600.106<0.106mg/KgHexachlorobenzene 03/16/23 14:580.6600.097<0.097mg/KgHexachlorobutadiene 03/16/23 14:580.6600.157<0.157mg/KgHexachlorocyclopentadiene 03/16/23 14:580.6600.079<0.079mg/KgHexachloroethane 03/16/23 14:580.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene 03/16/23 14:580.6600.191<0.191mg/KgIsophorone 03/16/23 14:580.6600.106<0.106mg/Kg1-Methylnaphthalene 03/16/23 14:580.6600.100<0.100mg/Kg2-Methylnaphthalene 03/16/23 14:580.6600.097<0.097mg/Kg2-Methylphenol 03/16/23 14:580.6600.084<0.084mg/Kg3&4 Methylphenol 03/16/23 14:580.6600.144<0.144mg/KgNaphthalene 03/16/23 14:580.6600.096<0.096mg/Kg2-Nitroaniline 03/16/23 14:580.6600.120<0.120mg/Kg3-Nitroaniline Page 2 of 9Date:03/17/2023 04:19 PM Page 37 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V30934QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V30852 Associated Lab Samples: 90565, 90566, 90567, 90568, 90569 LRB-V30852 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 03/16/23 14:580.3300.093<0.093mg/Kg4-Nitroaniline 03/16/23 14:580.3300.116<0.116mg/KgNitrobenzene 03/16/23 14:580.6600.088<0.088mg/Kg2-Nitrophenol 03/16/23 14:580.6600.117<0.117mg/Kg4-Nitrophenol 03/16/23 14:580.6600.263<0.263mg/KgN-Nitrosodimethylamine 03/16/23 14:580.6600.181<0.181mg/KgN-Nitrosodiphenylamine 03/16/23 14:580.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine 03/16/23 14:581.000.347<0.347mg/KgPentachlorophenol 03/16/23 14:580.6600.208<0.208mg/KgPhenanthrene 03/16/23 14:580.6600.112<0.112mg/KgPhenol 03/16/23 14:580.6600.134<0.134mg/KgPyrene 03/16/23 14:580.3300.079<0.079mg/KgPyridine 03/16/23 14:580.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene 03/16/23 14:580.6600.096<0.096mg/Kg2,4,5-Trichlorophenol 03/16/23 14:580.6600.096<0.096mg/Kg2,4,6-Trichlorophenol 03/16/23 14:582-Fluorobiphenyl (S)98.2 44-115 03/16/23 14:582-Fluorophenol (S)89.4 35-115 03/16/23 14:58Nitrobenzene-d5 (S)90.4 37-122 03/16/23 14:584-Terphenyl-d14 (S)107 54-127 03/16/23 14:582,4,6-Tribromophenol (S)94.5 39-132 03/16/23 14:58Phenol-d5 (S)86.7 34-121 LCS-V30852 LCSD-V30852Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 1.72 10397.61.631.67mg/KgAcenaphthene 40-123 5.3 20 Page 3 of 9Date:03/17/2023 04:19 PM Page 38 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V30934QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V30852 LCS-V30852 LCSD-V30852Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 1.72 10398.21.641.67mg/KgAcenaphthylene 32-132 4.7 20 3.14 1881903.171.67mg/KgAniline 12-197 0.9 20 1.81 1081051.761.67mg/KgAnthracene 47-123 2.8 20 1.79 1071011.691.67mg/KgBenzo(a)anthracene 49-126 5.7 20 2.06 1231181.971.67mg/KgBenzo(a)pyrene 45-129 4.4 20 1.89 1131111.851.67mg/KgBenzo(b)fluoranthene 45-132 2.1 20 1.85 1111061.771.67mg/KgBenzo(g,h,i)perylene 43-134 4.4 20 1.82 1091041.731.67mg/KgBenzo(k)fluoranthene 47-132 5.0 20 0.581 34.70.0*<0.5801.67mg/KgBenzoic Acid 10-83 0.1 20 1.65 98.894.01.571.67mg/KgBenzyl alcohol 29-122 4.9 20 1.60 95.889.21.491.67mg/KgBis(2-Chloroethoxy)methane 36-121 7.1 20 1.57 94.088.01.471.67mg/KgBis(2-Chloroethyl)ether 31-120 6.5 20 1.58 94.688.01.471.67mg/KgBis(2-Chloroisopropyl)ether 33-131 7.2 20 1.91 1141111.851.67mg/KgBis(2-ethylhexyl)phthalate 51-133 3.1 20 1.76 1051021.701.67mg/Kg4-Bromophenyl phenyl ether 46-124 3.4 20 1.98 1191131.881.67mg/KgButyl benzyl phthalate 48-132 5.1 20 1.48 88.684.41.411.67mg/Kg4-Chloro-3-methylphenol 45-122 4.8 20 1.19 71.271.21.191.67mg/Kg4-Chloroaniline 17-106 0.0 20 1.71 10298.21.641.67mg/Kg2-Chloronaphthalene 41-114 4.1 20 1.52 91.089.21.491.67mg/Kg2-Chlorophenol 34-121 1.9 20 1.69 1011001.671.67mg/Kg4-Chlorophenyl phenyl ether 45-121 1.1 20 1.78 1071041.731.67mg/KgChrysene 50-124 2.8 20 1.71 10296.41.611.67mg/KgDibenz(a,h)anthracene 45-134 6.0 20 1.71 10299.41.661.67mg/KgDibenzofuran 44-120 2.9 20 1.50 89.883.21.391.67mg/Kg1,2-Dichlorobenzene 33-117 7.6 20 1.48 88.682.01.371.67mg/Kg1,3-Dichlorobenzene 30-115 7.7 20 Page 4 of 9* QC Fail Date:03/17/2023 04:19 PM Page 39 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V30934QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V30852 LCS-V30852 LCSD-V30852Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 1.46 87.481.41.361.67mg/Kg1,4-Dichlorobenzene 31-115 7.0 20 0.971 58.155.30.9241.67mg/Kg3,3'-Dichlorobenzidine 22-121 4.9 20 1.51 90.485.61.431.67mg/Kg2,4-Dichlorophenol 40-122 5.4 20 1.76 1051031.721.67mg/KgDiethyl phthalate 50-124 2.2 20 1.75 1051011.691.67mg/KgDimethyl phthalate 48-124 3.4 20 1.61 96.490.41.511.67mg/Kg2,4-Dimethylphenol 30-127 6.4 20 1.95 1171131.891.67mg/KgDi-n-butyl phthalate 51-128 3.1 20 1.71 10292.81.551.67mg/Kg4,6-Dinitro-2-methylphenol 29-132 9.8 20 1.46 87.467.61.131.67mg/Kg2,4-Dinitrophenol 27-129 25.4*20 1.77 1061041.731.67mg/Kg2,4-Dinitrotoluene 48-126 2.2 20 1.79 1071041.731.67mg/Kg2,6-Dinitrotoluene 46-124 3.4 20 1.93 1161111.851.67mg/KgDi-n-Octyl Phthalate 45-140 4.2 20 1.79 1071021.711.67mg/KgFluoranthene 50-127 4.5 20 1.74 1041021.701.67mg/KgFluorene 43-125 2.3 20 1.71 10298.81.651.67mg/KgHexachlorobenzene 45-122 3.5 20 1.49 89.282.61.381.67mg/KgHexachlorobutadiene 32-123 7.6 20 1.61 96.492.81.551.67mg/KgHexachlorocyclopentadiene 32-117 3.7 20 1.42 85.079.01.321.67mg/KgHexachloroethane 28-117 7.2 20 1.78 1071041.731.67mg/KgIndeno(1,2,3-cd)pyrene 45-133 2.8 20 1.53 91.686.21.441.67mg/KgIsophorone 30-122 6.0 20 1.49 89.285.01.421.67mg/Kg1-Methylnaphthalene 40-119 4.8 20 1.42 85.081.41.361.67mg/Kg2-Methylnaphthalene 38-122 4.3 20 1.56 93.488.61.481.67mg/Kg2-Methylphenol 32-122 5.2 20 1.38 82.677.21.291.67mg/Kg3&4 Methylphenol 34-119 6.7 20 1.45 86.882.01.371.67mg/KgNaphthalene 35-123 5.6 20 1.67 10098.21.641.67mg/Kg2-Nitroaniline 44-127 1.8 20 Page 5 of 9* QC Fail Date:03/17/2023 04:19 PM Page 40 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Semivolatile Organic Compounds - GC/MS 8270E V30934QC Analytical Batch(es): Analysis Method: Analysis Description: 3546 QC Prep:V30852 LCS-V30852 LCSD-V30852Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 1.46 87.482.61.381.67mg/Kg3-Nitroaniline 33-119 5.6 20 1.71 10297.61.631.67mg/Kg4-Nitroaniline 63-147 4.7 20 1.45 86.883.21.391.67mg/KgNitrobenzene 34-122 4.2 20 1.44 86.281.41.361.67mg/Kg2-Nitrophenol 36-123 5.7 20 1.83 1101041.741.67mg/Kg4-Nitrophenol 30-132 5.0 20 1.16 69.467.01.121.67mg/KgN-Nitrosodimethylamine 10-146 3.5 20 2.19 131*1272.121.67mg/KgN-Nitrosodiphenylamine 38-127 3.2 20 1.51 90.485.61.431.67mg/KgN-Nitroso-di-n-propylamine 36-120 5.4 20 1.81 1081021.711.67mg/KgPentachlorophenol 25-133 5.6 20 1.80 1081041.731.67mg/KgPhenanthrene 50-121 3.9 20 1.63 97.692.81.551.67mg/KgPhenol 34-121 5.0 20 1.85 1111051.751.67mg/KgPyrene 47-127 5.5 20 1.12 67.059.40.9931.67mg/KgPyridine 10-80 12.0 20 1.46 87.482.01.371.67mg/Kg1,2,4-Trichlorobenzene 34-118 6.3 20 1.63 97.694.01.571.67mg/Kg2,4,5-Trichlorophenol 41-124 3.7 20 1.66 99.494.01.571.67mg/Kg2,4,6-Trichlorophenol 39-126 5.5 20 99.499.42-Fluorobiphenyl (S)44-115 94.592.72-Fluorophenol (S)35-115 83.882.0Nitrobenzene-d5 (S)37-122 1091074-Terphenyl-d14 (S)54-127 99.095.42,4,6-Tribromophenol (S)39-132 90.689.4Phenol-d5 (S)34-121 Page 6 of 9* QC Fail Date:03/17/2023 04:19 PM Page 41 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade QC Prep Batch Method: Massachusetts EPH MADEP-EPH V30725QC Analytical Batch(es): Analysis Method: Analysis Description: MAEPH (Prep) QC Prep:V30678 Associated Lab Samples: 90565, 90566, 90567, 90568, 90569 LRB-V30678 Matrix: SOLLab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 03/13/23 11:1850.09.20<9.20mg/KgAliphatic C9-C18 03/13/23 11:1850.012.2<12.2mg/KgAliphatic C19-C36 03/13/23 11:1850.014.2<14.2mg/KgAromatic C11-C22 03/13/23 11:182-Fluorobiphenyl (S)91.2 40-140 03/13/23 11:182-Bromonaphthalene (S)81.5 40-140 03/13/23 11:18Chlorooctadecane (S)91.1 40-140 03/13/23 11:18OTP Surrogate (S)79.6 40-140 LCS-V30678 LCSD-V30678Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 45.7 76.166.539.960.0mg/KgAliphatic C9-C18 40-140 13.5 50 79.2 99.097.177.780.0mg/KgAliphatic C19-C36 40-140 1.9 50 158 92.9122208170mg/KgAromatic C11-C22 40-140 27.3 50 87.01132-Fluorobiphenyl (S)40-140 75.01032-Bromonaphthalene (S)40-140 96.192.0Chlorooctadecane (S)40-140 76.894.1OTP Surrogate (S)40-140 Page 7 of 9Date:03/17/2023 04:19 PM Page 42 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade Dry Weight Determination SW-DRYWT V30748QC Analytical Batch: Analysis Method: Analysis Description: V 90828-DUPDuplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 03/13/23 16:381.623.523.9%Moisture V 90987-DUPDuplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 03/13/23 16:380.041.141.1%Moisture Page 8 of 9Date:03/17/2023 04:19 PM Page 43 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Quality Control Data 23-067-0018Report No: Project Description: Client ID:Smith & Gardner, Inc. GFL Wade Dry Weight Determination SW-DRYWT V30808QC Analytical Batch: Analysis Method: Analysis Description: V 90566-DUPDuplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 03/14/23 17:1610.06.687.39%Moisture V 90569-DUPDuplicate Max RPD Parameter AnalyzedRPDDUP Result Result Units 20.0 03/14/23 17:163.616.216.8%Moisture Page 9 of 9Date:03/17/2023 04:19 PM Page 44 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-067-0018 Smith & Gardner, Inc. 01186 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT15 20.5C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)?Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:03/08/2023 16:45:23 Special precautions or instructions included? Comments: Page 45 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322 Page 46 of 46 DocuSign Envelope ID: 82501D66-20A2-4B33-BEBE-20AE09BED322