FA-29655_48901_CA_UST-61_20230308

UST-61 24-Hour Release and UST Leak Reporting Form.
For Releases
in NC
This form should be completed and submitted to the UST Section’s regional office following a known or suspected release from an underground storage tank (UST) system. This form is required to be submitted within 24 hours of discovery of a known or
suspected release
(DWM USE ONLY) Incident # ________ Risk (H,I,L,U)_______ Received On ________ Received By ________
Reported by (circle one): Phone, Fax or Report Region _______
Suspected Contamination? (Y/N) ________ Confirmed GW Contamination? (Y/N) ______ Confirmed Soil Contamination ?(Y/N) ______
Samples Taken?(Y/N) ______ Free Product? (Y/N) _____ If Yes, State Greatest Thickness ______________
Facility ID Number ______________ Date Leak Discovered ___________ Comm/Non-Commercial? ________
Reg/Non-regulated? _____________
INCIDENT DESCRIPTION
Incident Name:
Address: County:
City/Town: Zip Code: Regional Office (circle one): Asheville, Mooresville, Fayetteville, Raleigh, Washington, Wilmington, Winston-Salem
Latitude (decimal degrees): Longitude (decimal degrees) : Obtained by:
Briefly describe suspected or confirmed release: (including but not limited to: nature of release, date of release, amount
of release, amount of free product present and recovery efforts, initial responses conducted, impacts to receptors)  GPS
 Topographic map
 GIS Address matching
 Other
 Unknown
Describe location:
HOW RELEASE WAS DISCOVERED (Release Code)
(Check one)
 Release Detection Equipment or Methods
 During UST Closure/Removal
 Property Transfer
 Visual/Odor
 Water in Tank
 Water Supply Well Contamination
 Groundwater Contamination
 Surface Water Contamination
 Other (specify) _______________
SOURCE OF CONTAMINATION
Source of Release (Check primary source) Cause of Release (Check primary cause) Type of Release (Check one) Product Type Released (Check primary product type released)
 Tank
 Piping
 Dispenser
 Submersible Turbine Pump
 Delivery Problem
 Spill Bucket
 Other
 Unknown
Definitions presented on reverse
 Spill
 Overfill
 Corrosion
 Physical/Mechanical
Damage
 Install Problem
 Other
 Unknown
Definitions presented on reverse
 Petroleum
 Non-Petroleum
 Both
Location
(Check one)
 Facility
 Residence
 Other
 Gasoline/ Diesel/
Kerosene
 Heating Oil
 Other Petroleum
Products
 Metals
 Other Inorganics
 Other Organics
 Diesel/Veg. Oil
Blend
 Vegetable Oil 100%
 E10 – E20
 E21 – E84
 E85 – E99
 Ethanol 100%
 E01 – E09
Ownership
1.Municipal 2. Military 3. Unknown 4. Private 5. Federal 6. County 7. State
Operation Type 1. Public Service 2. Agricultural 3. Residential 4. Education/Relig. 5. Industrial 6. Commercial 7. Mining
UST Form 61 (02/19) Page 1 of 2
N
NYY
N Reg
NA
3/7/2023
Commercial
Murphy USA #8549
37042
4993 NC 42 Highway West
Garner
Johnston
X
35.6112 78.5537
27529
GES conducted a site check during the week of February 20th. Lab results indicate the presence of petroleum impact.
X Soil Contamination
X
X
X
X
X

IMPACT ON DRINKING WATER SUPPLIES
Water Supply Wells Affected? 1. Yes 2. No 3. Unknown Number of Water Supply Wells Affected __________________
Water Supply Wells Contaminated: (Include Users Names, Addresses and Phone Numbers. Attach additional sheet if necessary) 1. 2. 3.
UST SYSTEM OWNER UST Owner/Company
Point of Contact Address
City State Zip Code Telephone Number
UST SYSTEM OPERATOR
UST Operator/Company Address
City State Zip Code Telephone Number
LANDOWNER AT LOCATION OF UST INCIDENT
Landowner Address
City State Zip Code Telephone Number
Draw Sketch of Area (showing two major road intersections) or Attach Map
Person Reporting Incident Company Telephone Number
Title Address Date
UST Form 61 (02/19) Page 2 of 2
Definitions of Sources Tank: means the tank that stores the product and is part of the underground storage tank system Piping: means the piping and connectors running from the tank or submersible turbine pump to the dispenser or other end-use equipment (Vent, vapor recovery, or fill lines are excluded.) Dispenser: includes the dispenser and the equipment used to connect the dispenser to the piping (e.g., a release from a suction pump or from components located above the shear valve) Submersible Turbine Pump (STP) Area includes the submersible turbine pump head (typically located in the tank sump), the line leak detector, and the piping that connects the submersible turbine pump to the tank Delivery Problem: identifies releases that occurred during product delivery to the tank. (Typical causes associated with this source are spills and overfills.)
Other: serves as the option to use when the release source is known but does not fit into one of the preceding categories (e.g., for releases from vent lines, vapor recovery lines, and fill lines) Unknown: identifies releases for which the source has not been determined Definitions of Causes
Spill: use this cause when a spill occurs (e.g., when the delivery hose is disconnected from the tank fill pipe or when the nozzle is removed from the dispenser) Overfill: use when an overfill occurs (e.g., overfills may occur from the fill pipe at the tank or when the nozzle fails to shut off at the dispenser) Physical or Mechanical Damage: use for all types of physical or mechanical damage, except corrosion (e.g., puncture of tank or piping, loose fittings, broken components, and components that have changed dimension) Corrosion: use when a metal tank, piping, or other component has a release due to corrosion (e.g., for steel, corrosion takes the form of rust) Installation Problem: use when the problem is determined to have occurred specifically because the UST system was not installed properly Other: use this option when the cause is known but does not fit into one of the preceding categories (e.g., putting regulated substances into monitoring wells) Unknown: use when the cause has not been determined
Soil Sample Location Map
Murphy USA
Station #8549
4993 NC-42
Garner, North Carolina
Designed
Approved
Scale In Feet
0 20
W.G.S.
Drawn
N
Figure
3/6/23
Date
Groundwater & Environmental Services, Inc.M:\Graphics\2700-Columbia\MISC\Murphy Oil USA\8549 Garner\8549 Garner SM.dwg, B20soil, WShea
03/07/23
Technical Report for
Murphy Oil USA
GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
2701997
SGS Job Number: FC2879
Sampling Dates: 02/20/23 - 02/21/23
Report to:
Groundwater & Environmental Services
104 Corporate Blvd Suite 411
West Columbia, SC 29169
[e-mail]
ATTN: Aaron Williamson
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Rosa Junkin 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 03/07/23
e-Hardcopy 2.0
Automated Report
123
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
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1 of 123
FC2879
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................7
3.1: FC2879-1: SB-1 ............................................................................................................8
3.2: FC2879-2: SB-2 ............................................................................................................11
3.3: FC2879-3: SB-3 ............................................................................................................16
3.4: FC2879-4: SB-4 ............................................................................................................21
3.5: FC2879-5: SB-5 ............................................................................................................26
3.6: FC2879-6: SB-6 ............................................................................................................31
3.7: FC2879-7: SB-7 ............................................................................................................36
3.8: FC2879-8: SB-8 ............................................................................................................41
3.9: FC2879-9: SB-9 ............................................................................................................46
3.10: FC2879-10: SB-10 ......................................................................................................51
3.11: FC2879-11: SB-11 ......................................................................................................56
3.12: FC2879-12: SB-17 ......................................................................................................61
Section 4: Misc. Forms ............................................................................................................66
4.1: Chain of Custody ...........................................................................................................67
Section 5: MS Volatiles - QC Data Summaries .....................................................................70
5.1: Method Blank Summary ................................................................................................71
5.2: Blank Spike Summary ...................................................................................................85
5.3: Matrix Spike Summary ..................................................................................................99
5.4: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................100
Section 6: GC Volatiles - QC Data Summaries .....................................................................110
6.1: Method Blank Summary ................................................................................................111
6.2: Blank Spike Summary ...................................................................................................114
6.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................117
Section 7: GC/LC Semi-volatiles - QC Data Summaries .....................................................120
7.1: Method Blank Summary ................................................................................................121
7.2: Blank Spike Summary ...................................................................................................122
7.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................123 12345672 of 123
FC2879
SGS North America Inc.
Sample Summary
Murphy Oil USA
Job No:FC2879
GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Project No: 2701997
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FC2879-1 02/20/23 15:45 AW 02/22/23 SO Soil SB-1
FC2879-2 02/20/23 16:00 AW 02/22/23 SO Soil SB-2
FC2879-3 02/20/23 16:30 AW 02/22/23 SO Soil SB-3
FC2879-4 02/20/23 16:45 AW 02/22/23 SO Soil SB-4
FC2879-5 02/20/23 17:00 AW 02/22/23 SO Soil SB-5
FC2879-6 02/20/23 12:31 AW 02/22/23 SO Soil SB-6
FC2879-7 02/20/23 14:18 AW 02/22/23 SO Soil SB-7
FC2879-8 02/20/23 15:05 AW 02/22/23 SO Soil SB-8
FC2879-9 02/20/23 15:20 AW 02/22/23 SO Soil SB-9
FC2879-10 02/21/23 09:57 AW 02/22/23 SO Soil SB-10
FC2879-11 02/21/23 11:15 AW 02/22/23 SO Soil SB-11
FC2879-12 02/21/23 10:20 AW 02/22/23 SO Soil SB-17
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
3 of 123
FC28791
Summary of Hits Page 1 of 3
Job Number:FC2879
Account:Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Collected:02/20/23 thru 02/21/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC2879-1 SB-1
1,2,4-Trimethylbenzene 60200 2900 590 ug/kg SW846 8260D
TPH-GRO (C6-C10)300 100 41 mg/kg SW846 8015C
TPH (C10-C28)32.3 5.8 2.9 mg/kg SW846 8015C
FC2879-2 SB-2
No hits reported in this sample.
FC2879-3 SB-3
Benzene 1.2 J 3.1 0.75 ug/kg SW846 8260D
2-Butanone (MEK)9.2 J 15 4.5 ug/kg SW846 8260D
Methyl Bromide 1.8 J 3.1 1.2 ug/kg SW846 8260D
TPH (C10-C28)3.86 J 5.8 2.9 mg/kg SW846 8015C
FC2879-4 SB-4
No hits reported in this sample.
FC2879-5 SB-5
TPH (C10-C28)3.78 J 5.7 2.9 mg/kg SW846 8015C
FC2879-6 SB-6
n-Butylbenzene 1890 J 2300 460 ug/kg SW846 8260D
Ethylbenzene 34300 2300 460 ug/kg SW846 8260D
Isopropylbenzene 3680 2300 460 ug/kg SW846 8260D
p-Isopropyltoluene 574 J 2300 460 ug/kg SW846 8260D
Naphthalene 5810 2300 920 ug/kg SW846 8260D
n-Propylbenzene 11600 2300 460 ug/kg SW846 8260D
Toluene 38300 9200 4600 ug/kg SW846 8260D
1,2,4-Trimethylbenzene 70400 2300 460 ug/kg SW846 8260D
1,3,5-Trimethylbenzene 19300 2300 460 ug/kg SW846 8260D
m,p-Xylene 144000 4600 510 ug/kg SW846 8260D
o-Xylene 61300 2300 460 ug/kg SW846 8260D
Xylene (total)206000 6900 970 ug/kg SW846 8260D
TPH-GRO (C6-C10)1750 480 190 mg/kg SW846 8015C
TPH (C10-C28)22.1 5.8 2.9 mg/kg SW846 8015C
FC2879-7 SB-7
Benzene 145 4.3 1.0 ug/kg SW846 8260D
4 of 123
FC28792
Summary of Hits Page 2 of 3
Job Number:FC2879
Account:Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Collected:02/20/23 thru 02/21/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
2-Butanone (MEK) a 73.1 21 6.2 ug/kg SW846 8260D
n-Butylbenzene 16.6 4.3 0.85 ug/kg SW846 8260D
Ethylbenzene 1980 250 49 ug/kg SW846 8260D
Isopropylbenzene 54.3 4.3 0.85 ug/kg SW846 8260D
p-Isopropyltoluene 32.0 4.3 0.85 ug/kg SW846 8260D
4-Methyl-2-pentanone (MIBK) b 19.4 J 21 6.4 ug/kg SW846 8260D
Naphthalene 87.7 4.3 1.7 ug/kg SW846 8260D
n-Propylbenzene 130 4.3 0.85 ug/kg SW846 8260D
Toluene 8200 2000 980 ug/kg SW846 8260D
1,2,4-Trimethylbenzene 4380 250 49 ug/kg SW846 8260D
1,3,5-Trimethylbenzene 1040 250 49 ug/kg SW846 8260D
m,p-Xylene 9520 490 54 ug/kg SW846 8260D
o-Xylene 4060 250 49 ug/kg SW846 8260D
Xylene (total)13600 740 100 ug/kg SW846 8260D
TPH-GRO (C6-C10)14.8 5.6 2.2 mg/kg SW846 8015C
TPH (C10-C28)5.36 J 6.3 3.1 mg/kg SW846 8015C
FC2879-8 SB-8
TPH (C10-C28)4.32 J 5.7 2.8 mg/kg SW846 8015C
FC2879-9 SB-9
2-Butanone (MEK)5.9 J 17 5.1 ug/kg SW846 8260D
n-Butylbenzene 1.0 J 3.5 0.70 ug/kg SW846 8260D
sec-Butylbenzene 1.0 J 3.5 0.70 ug/kg SW846 8260D
Ethylbenzene 5.4 3.5 0.70 ug/kg SW846 8260D
Isopropylbenzene 2.2 J 3.5 0.70 ug/kg SW846 8260D
Naphthalene 2.1 J 3.5 1.4 ug/kg SW846 8260D
n-Propylbenzene 6.0 3.5 0.70 ug/kg SW846 8260D
1,2,4-Trimethylbenzene 25.2 3.5 0.70 ug/kg SW846 8260D
1,3,5-Trimethylbenzene 8.1 3.5 0.70 ug/kg SW846 8260D
TPH-GRO (C6-C10)2.19 J 4.5 1.8 mg/kg SW846 8015C
TPH (C10-C28)4.44 J 5.9 2.9 mg/kg SW846 8015C
FC2879-10 SB-10
TPH (C10-C28)5.27 J 5.7 2.8 mg/kg SW846 8015C
FC2879-11 SB-11
TPH (C10-C28)4.10 J 5.8 2.9 mg/kg SW846 8015C
5 of 123
FC28792
Summary of Hits Page 3 of 3
Job Number:FC2879
Account:Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Collected:02/20/23 thru 02/21/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC2879-12 SB-17
Acetone 261 180 92 ug/kg SW846 8260D
Benzene 1.6 J 4.6 1.1 ug/kg SW846 8260D
2-Butanone (MEK)52.0 23 6.7 ug/kg SW846 8260D
Ethyl Alcohol 189 J 370 69 ug/kg SW846 8260D
(a) Associated CCV outside control limits high. Compound was below calibration range in higher dilution.
(b) Associated CCV outside control limits high. ND at higher dilution.
6 of 123
FC28792
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
7 of 123
FC28793
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-1
Lab Sample ID:FC2879-1 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C185573.D 1 03/02/23 16:57 AL n/a n/a V3C943
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 5.76 g 5.0 ml 10.0 ul
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
95-63-6 1,2,4-Trimethylbenzene 60200 2900 590 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%75-124%
17060-07-0 1,2-Dichloroethane-D4 108%72-135%
2037-26-5 Toluene-D8 102%75-126%
460-00-4 4-Bromofluorobenzene 96%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 123
FC287933.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-1
Lab Sample ID:FC2879-1 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14161.D 1 02/27/23 20:50 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 6.65 g 5.0 ml 5.0 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)300 100 41 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 113%56-149%
98-08-8 aaa-Trifluorotoluene 100%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 123
FC287933.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-1
Lab Sample ID:FC2879-1 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37926.D 1 02/24/23 16:52 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)32.3 5.8 2.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 69%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 123
FC287933.1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-2
Lab Sample ID:FC2879-2 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C185463.D 1 02/24/23 18:24 AL n/a n/a V3C939
Run #2
Initial Weight Final Volume
Run #1 7.80 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 150 75 ug/kg
71-43-2 Benzene ND 3.7 0.91 ug/kg
108-86-1 Bromobenzene ND 3.7 0.75 ug/kg
74-97-5 Bromochloromethane ND 3.7 1.1 ug/kg
75-27-4 Bromodichloromethane ND 3.7 0.75 ug/kg
75-25-2 Bromoform ND 3.7 0.75 ug/kg
78-93-3 2-Butanone (MEK)ND 19 5.4 ug/kg
104-51-8 n-Butylbenzene ND 3.7 0.75 ug/kg
135-98-8 sec-Butylbenzene ND 3.7 0.75 ug/kg
98-06-6 tert-Butylbenzene ND 3.7 0.75 ug/kg
56-23-5 Carbon Tetrachloride ND 3.7 0.76 ug/kg
108-90-7 Chlorobenzene ND 3.7 0.75 ug/kg
75-00-3 Chloroethane b ND 3.7 1.5 ug/kg
67-66-3 Chloroform ND 3.7 0.99 ug/kg
95-49-8 o-Chlorotoluene ND 3.7 0.75 ug/kg
106-43-4 p-Chlorotoluene ND 3.7 0.75 ug/kg
124-48-1 Dibromochloromethane ND 3.7 0.75 ug/kg
106-93-4 1,2-Dibromoethane ND 3.7 0.75 ug/kg
75-71-8 Dichlorodifluoromethane c ND 3.7 1.5 ug/kg
95-50-1 1,2-Dichlorobenzene ND 3.7 0.75 ug/kg
541-73-1 1,3-Dichlorobenzene ND 3.7 0.75 ug/kg
106-46-7 1,4-Dichlorobenzene ND 3.7 0.86 ug/kg
75-34-3 1,1-Dichloroethane ND 3.7 1.3 ug/kg
107-06-2 1,2-Dichloroethane ND 3.7 0.75 ug/kg
75-35-4 1,1-Dichloroethylene ND 3.7 0.75 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 3.7 1.0 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 3.7 0.75 ug/kg
78-87-5 1,2-Dichloropropane ND 3.7 0.75 ug/kg
142-28-9 1,3-Dichloropropane ND 3.7 0.75 ug/kg
594-20-7 2,2-Dichloropropane ND 3.7 0.75 ug/kg
563-58-6 1,1-Dichloropropene ND 3.7 0.76 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 3.7 0.75 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 123
FC287933.2
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-2
Lab Sample ID:FC2879-2 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 3.7 0.75 ug/kg
108-20-3 Di-Isopropyl Ether ND 3.7 1.7 ug/kg
64-17-5 Ethyl Alcohol c ND 300 56 ug/kg
100-41-4 Ethylbenzene ND 3.7 0.75 ug/kg
591-78-6 2-Hexanone ND 19 5.6 ug/kg
98-82-8 Isopropylbenzene ND 3.7 0.75 ug/kg
99-87-6 p-Isopropyltoluene ND 3.7 0.75 ug/kg
74-83-9 Methyl Bromide ND 3.7 1.5 ug/kg
74-87-3 Methyl Chloride c ND 3.7 1.5 ug/kg
75-09-2 Methylene Chloride ND 15 8.2 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 19 5.6 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 3.7 0.75 ug/kg
91-20-3 Naphthalene ND 3.7 1.5 ug/kg
103-65-1 n-Propylbenzene ND 3.7 0.75 ug/kg
100-42-5 Styrene ND 3.7 0.75 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 3.7 0.77 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 3.7 0.75 ug/kg
127-18-4 Tetrachloroethylene ND 3.7 0.95 ug/kg
108-88-3 Toluene ND 15 7.5 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 3.7 1.0 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 3.7 0.75 ug/kg
71-55-6 1,1,1-Trichloroethane ND 3.7 0.75 ug/kg
79-00-5 1,1,2-Trichloroethane ND 3.7 0.75 ug/kg
79-01-6 Trichloroethylene ND 3.7 0.75 ug/kg
75-69-4 Trichlorofluoromethane ND 3.7 1.5 ug/kg
96-18-4 1,2,3-Trichloropropane ND 3.7 0.93 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 3.7 0.75 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 3.7 0.75 ug/kg
108-05-4 Vinyl Acetate d ND 19 12 ug/kg
75-01-4 Vinyl Chloride ND 3.7 0.75 ug/kg
m,p-Xylene ND 7.5 0.82 ug/kg
95-47-6 o-Xylene ND 3.7 0.75 ug/kg
1330-20-7 Xylene (total)ND 11 1.6 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 95%75-124%
17060-07-0 1,2-Dichloroethane-D4 109%72-135%
2037-26-5 Toluene-D8 102%75-126%
460-00-4 4-Bromofluorobenzene 96%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 123
FC287933.2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-2
Lab Sample ID:FC2879-2 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits low.
(d) Associated ICV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 123
FC287933.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-2
Lab Sample ID:FC2879-2 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14137.D 1 02/27/23 11:06 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 7.64 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 4.6 1.8 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 103%56-149%
98-08-8 aaa-Trifluorotoluene 94%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 123
FC287933.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-2
Lab Sample ID:FC2879-2 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:86.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37928.D 1 02/24/23 17:52 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)ND 5.8 2.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 66%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 123
FC287933.2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-3
Lab Sample ID:FC2879-3 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C185464.D 1 02/24/23 18:49 AL n/a n/a V3C939
Run #2
Initial Weight Final Volume
Run #1 9.49 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 120 62 ug/kg
71-43-2 Benzene 1.2 3.1 0.75 ug/kg J
108-86-1 Bromobenzene ND 3.1 0.62 ug/kg
74-97-5 Bromochloromethane ND 3.1 0.91 ug/kg
75-27-4 Bromodichloromethane ND 3.1 0.62 ug/kg
75-25-2 Bromoform ND 3.1 0.62 ug/kg
78-93-3 2-Butanone (MEK)9.2 15 4.5 ug/kg J
104-51-8 n-Butylbenzene ND 3.1 0.62 ug/kg
135-98-8 sec-Butylbenzene ND 3.1 0.62 ug/kg
98-06-6 tert-Butylbenzene ND 3.1 0.62 ug/kg
56-23-5 Carbon Tetrachloride ND 3.1 0.63 ug/kg
108-90-7 Chlorobenzene ND 3.1 0.62 ug/kg
75-00-3 Chloroethane b ND 3.1 1.2 ug/kg
67-66-3 Chloroform ND 3.1 0.82 ug/kg
95-49-8 o-Chlorotoluene ND 3.1 0.62 ug/kg
106-43-4 p-Chlorotoluene ND 3.1 0.62 ug/kg
124-48-1 Dibromochloromethane ND 3.1 0.62 ug/kg
106-93-4 1,2-Dibromoethane ND 3.1 0.62 ug/kg
75-71-8 Dichlorodifluoromethane c ND 3.1 1.2 ug/kg
95-50-1 1,2-Dichlorobenzene ND 3.1 0.62 ug/kg
541-73-1 1,3-Dichlorobenzene ND 3.1 0.62 ug/kg
106-46-7 1,4-Dichlorobenzene ND 3.1 0.71 ug/kg
75-34-3 1,1-Dichloroethane ND 3.1 1.1 ug/kg
107-06-2 1,2-Dichloroethane ND 3.1 0.62 ug/kg
75-35-4 1,1-Dichloroethylene ND 3.1 0.62 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 3.1 0.85 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 3.1 0.62 ug/kg
78-87-5 1,2-Dichloropropane ND 3.1 0.62 ug/kg
142-28-9 1,3-Dichloropropane ND 3.1 0.62 ug/kg
594-20-7 2,2-Dichloropropane ND 3.1 0.62 ug/kg
563-58-6 1,1-Dichloropropene ND 3.1 0.63 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 3.1 0.62 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 123
FC287933.3
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-3
Lab Sample ID:FC2879-3 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 3.1 0.62 ug/kg
108-20-3 Di-Isopropyl Ether ND 3.1 1.4 ug/kg
64-17-5 Ethyl Alcohol c ND 250 46 ug/kg
100-41-4 Ethylbenzene ND 3.1 0.62 ug/kg
591-78-6 2-Hexanone ND 15 4.6 ug/kg
98-82-8 Isopropylbenzene ND 3.1 0.62 ug/kg
99-87-6 p-Isopropyltoluene ND 3.1 0.62 ug/kg
74-83-9 Methyl Bromide 1.8 3.1 1.2 ug/kg J
74-87-3 Methyl Chloride c ND 3.1 1.2 ug/kg
75-09-2 Methylene Chloride ND 12 6.8 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 15 4.6 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 3.1 0.62 ug/kg
91-20-3 Naphthalene ND 3.1 1.2 ug/kg
103-65-1 n-Propylbenzene ND 3.1 0.62 ug/kg
100-42-5 Styrene ND 3.1 0.62 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 3.1 0.64 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 3.1 0.62 ug/kg
127-18-4 Tetrachloroethylene ND 3.1 0.79 ug/kg
108-88-3 Toluene ND 12 6.2 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 3.1 0.86 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 3.1 0.62 ug/kg
71-55-6 1,1,1-Trichloroethane ND 3.1 0.62 ug/kg
79-00-5 1,1,2-Trichloroethane ND 3.1 0.62 ug/kg
79-01-6 Trichloroethylene ND 3.1 0.62 ug/kg
75-69-4 Trichlorofluoromethane ND 3.1 1.2 ug/kg
96-18-4 1,2,3-Trichloropropane ND 3.1 0.77 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 3.1 0.62 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 3.1 0.62 ug/kg
108-05-4 Vinyl Acetate d ND 15 10 ug/kg
75-01-4 Vinyl Chloride ND 3.1 0.62 ug/kg
m,p-Xylene ND 6.2 0.68 ug/kg
95-47-6 o-Xylene ND 3.1 0.62 ug/kg
1330-20-7 Xylene (total)ND 9.3 1.3 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 96%75-124%
17060-07-0 1,2-Dichloroethane-D4 111%72-135%
2037-26-5 Toluene-D8 102%75-126%
460-00-4 4-Bromofluorobenzene 94%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
17 of 123
FC287933.3
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-3
Lab Sample ID:FC2879-3 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated CCV and BS outside control limits low.
(c) Associated CCV outside control limits low.
(d) Associated ICV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 123
FC287933.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-3
Lab Sample ID:FC2879-3 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:85.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14138.D 1 02/27/23 11:30 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 8.68 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 4.2 1.7 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 107%56-149%
98-08-8 aaa-Trifluorotoluene 98%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 123
FC287933.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-3
Lab Sample ID:FC2879-3 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:85.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37929.D 1 02/24/23 18:22 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.2 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)3.86 5.8 2.9 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 70%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 123
FC287933.3
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-4
Lab Sample ID:FC2879-4 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.6
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2B21556.D 1 03/01/23 15:47 AL n/a n/a V2B907
Run #2
Initial Weight Final Volume
Run #1 5.05 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 230 120 ug/kg
71-43-2 Benzene ND 5.8 1.4 ug/kg
108-86-1 Bromobenzene ND 5.8 1.2 ug/kg
74-97-5 Bromochloromethane ND 5.8 1.7 ug/kg
75-27-4 Bromodichloromethane a ND 5.8 1.2 ug/kg
75-25-2 Bromoform ND 5.8 1.2 ug/kg
78-93-3 2-Butanone (MEK)ND 29 8.4 ug/kg
104-51-8 n-Butylbenzene ND 5.8 1.2 ug/kg
135-98-8 sec-Butylbenzene ND 5.8 1.2 ug/kg
98-06-6 tert-Butylbenzene ND 5.8 1.2 ug/kg
56-23-5 Carbon Tetrachloride a ND 5.8 1.2 ug/kg
108-90-7 Chlorobenzene ND 5.8 1.2 ug/kg
75-00-3 Chloroethane b ND 5.8 2.3 ug/kg
67-66-3 Chloroform ND 5.8 1.5 ug/kg
95-49-8 o-Chlorotoluene ND 5.8 1.2 ug/kg
106-43-4 p-Chlorotoluene ND 5.8 1.2 ug/kg
124-48-1 Dibromochloromethane ND 5.8 1.2 ug/kg
106-93-4 1,2-Dibromoethane ND 5.8 1.2 ug/kg
75-71-8 Dichlorodifluoromethane c ND 5.8 2.3 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.8 1.2 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.8 1.2 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.8 1.3 ug/kg
75-34-3 1,1-Dichloroethane ND 5.8 2.0 ug/kg
107-06-2 1,2-Dichloroethane ND 5.8 1.2 ug/kg
75-35-4 1,1-Dichloroethylene a ND 5.8 1.2 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.8 1.6 ug/kg
156-60-5 trans-1,2-Dichloroethylene a ND 5.8 1.2 ug/kg
78-87-5 1,2-Dichloropropane ND 5.8 1.2 ug/kg
142-28-9 1,3-Dichloropropane ND 5.8 1.2 ug/kg
594-20-7 2,2-Dichloropropane a ND 5.8 1.2 ug/kg
563-58-6 1,1-Dichloropropene a ND 5.8 1.2 ug/kg
10061-01-5 cis-1,3-Dichloropropene a ND 5.8 1.2 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 123
FC287933.4
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-4
Lab Sample ID:FC2879-4 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.6
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 5.8 1.2 ug/kg
108-20-3 Di-Isopropyl Ether a ND 5.8 2.7 ug/kg
64-17-5 Ethyl Alcohol ND 460 87 ug/kg
100-41-4 Ethylbenzene ND 5.8 1.2 ug/kg
591-78-6 2-Hexanone ND 29 8.7 ug/kg
98-82-8 Isopropylbenzene ND 5.8 1.2 ug/kg
99-87-6 p-Isopropyltoluene ND 5.8 1.2 ug/kg
74-83-9 Methyl Bromide b ND 5.8 2.3 ug/kg
74-87-3 Methyl Chloride c ND 5.8 2.3 ug/kg
75-09-2 Methylene Chloride ND 23 13 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 29 8.7 ug/kg
1634-04-4 Methyl Tert Butyl Ether a ND 5.8 1.2 ug/kg
91-20-3 Naphthalene ND 5.8 2.3 ug/kg
103-65-1 n-Propylbenzene ND 5.8 1.2 ug/kg
100-42-5 Styrene ND 5.8 1.2 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 5.8 1.2 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.8 1.2 ug/kg
127-18-4 Tetrachloroethylene ND 5.8 1.5 ug/kg
108-88-3 Toluene ND 23 12 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 5.8 1.6 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.8 1.2 ug/kg
71-55-6 1,1,1-Trichloroethane a ND 5.8 1.2 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.8 1.2 ug/kg
79-01-6 Trichloroethylene ND 5.8 1.2 ug/kg
75-69-4 Trichlorofluoromethane c ND 5.8 2.3 ug/kg
96-18-4 1,2,3-Trichloropropane ND 5.8 1.4 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.8 1.2 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.8 1.2 ug/kg
108-05-4 Vinyl Acetate ND 29 19 ug/kg
75-01-4 Vinyl Chloride c ND 5.8 1.2 ug/kg
m,p-Xylene ND 12 1.3 ug/kg
95-47-6 o-Xylene ND 5.8 1.2 ug/kg
1330-20-7 Xylene (total)ND 17 2.4 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 93%75-124%
17060-07-0 1,2-Dichloroethane-D4 101%72-135%
2037-26-5 Toluene-D8 114%75-126%
460-00-4 4-Bromofluorobenzene 108%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
22 of 123
FC287933.4
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-4
Lab Sample ID:FC2879-4 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.6
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated CCV and BS outside control limits high, sample is ND.
(c) Associated ICV and CCV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 123
FC287933.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-4
Lab Sample ID:FC2879-4 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:85.6
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14141.D 1 02/27/23 12:47 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 8.48 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 4.3 1.7 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 108%56-149%
98-08-8 aaa-Trifluorotoluene 98%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
24 of 123
FC287933.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-4
Lab Sample ID:FC2879-4 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:85.6
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37930.D 1 02/24/23 18:51 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.3 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)ND 5.8 2.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 70%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 123
FC287933.4
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-5
Lab Sample ID:FC2879-5 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:86.8
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2B21557.D 1 03/01/23 16:12 AL n/a n/a V2B907
Run #2
Initial Weight Final Volume
Run #1 5.91 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 190 97 ug/kg
71-43-2 Benzene ND 4.9 1.2 ug/kg
108-86-1 Bromobenzene ND 4.9 0.97 ug/kg
74-97-5 Bromochloromethane ND 4.9 1.4 ug/kg
75-27-4 Bromodichloromethane a ND 4.9 0.97 ug/kg
75-25-2 Bromoform ND 4.9 0.97 ug/kg
78-93-3 2-Butanone (MEK)ND 24 7.1 ug/kg
104-51-8 n-Butylbenzene ND 4.9 0.97 ug/kg
135-98-8 sec-Butylbenzene ND 4.9 0.97 ug/kg
98-06-6 tert-Butylbenzene ND 4.9 0.97 ug/kg
56-23-5 Carbon Tetrachloride a ND 4.9 0.99 ug/kg
108-90-7 Chlorobenzene ND 4.9 0.97 ug/kg
75-00-3 Chloroethane b ND 4.9 1.9 ug/kg
67-66-3 Chloroform ND 4.9 1.3 ug/kg
95-49-8 o-Chlorotoluene ND 4.9 0.97 ug/kg
106-43-4 p-Chlorotoluene ND 4.9 0.97 ug/kg
124-48-1 Dibromochloromethane ND 4.9 0.97 ug/kg
106-93-4 1,2-Dibromoethane ND 4.9 0.97 ug/kg
75-71-8 Dichlorodifluoromethane c ND 4.9 1.9 ug/kg
95-50-1 1,2-Dichlorobenzene ND 4.9 0.97 ug/kg
541-73-1 1,3-Dichlorobenzene ND 4.9 0.97 ug/kg
106-46-7 1,4-Dichlorobenzene ND 4.9 1.1 ug/kg
75-34-3 1,1-Dichloroethane ND 4.9 1.7 ug/kg
107-06-2 1,2-Dichloroethane ND 4.9 0.97 ug/kg
75-35-4 1,1-Dichloroethylene a ND 4.9 0.97 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 4.9 1.3 ug/kg
156-60-5 trans-1,2-Dichloroethylene a ND 4.9 0.97 ug/kg
78-87-5 1,2-Dichloropropane ND 4.9 0.97 ug/kg
142-28-9 1,3-Dichloropropane ND 4.9 0.97 ug/kg
594-20-7 2,2-Dichloropropane a ND 4.9 0.97 ug/kg
563-58-6 1,1-Dichloropropene a ND 4.9 0.99 ug/kg
10061-01-5 cis-1,3-Dichloropropene a ND 4.9 0.97 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
26 of 123
FC287933.5
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-5
Lab Sample ID:FC2879-5 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:86.8
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 4.9 0.97 ug/kg
108-20-3 Di-Isopropyl Ether a ND 4.9 2.3 ug/kg
64-17-5 Ethyl Alcohol ND 390 73 ug/kg
100-41-4 Ethylbenzene ND 4.9 0.97 ug/kg
591-78-6 2-Hexanone ND 24 7.3 ug/kg
98-82-8 Isopropylbenzene ND 4.9 0.97 ug/kg
99-87-6 p-Isopropyltoluene ND 4.9 0.97 ug/kg
74-83-9 Methyl Bromide b ND 4.9 1.9 ug/kg
74-87-3 Methyl Chloride c ND 4.9 1.9 ug/kg
75-09-2 Methylene Chloride ND 19 11 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 24 7.3 ug/kg
1634-04-4 Methyl Tert Butyl Ether a ND 4.9 0.97 ug/kg
91-20-3 Naphthalene ND 4.9 1.9 ug/kg
103-65-1 n-Propylbenzene ND 4.9 0.97 ug/kg
100-42-5 Styrene ND 4.9 0.97 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 4.9 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 4.9 0.97 ug/kg
127-18-4 Tetrachloroethylene ND 4.9 1.2 ug/kg
108-88-3 Toluene ND 19 9.7 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 4.9 1.4 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 4.9 0.97 ug/kg
71-55-6 1,1,1-Trichloroethane a ND 4.9 0.97 ug/kg
79-00-5 1,1,2-Trichloroethane ND 4.9 0.97 ug/kg
79-01-6 Trichloroethylene ND 4.9 0.97 ug/kg
75-69-4 Trichlorofluoromethane c ND 4.9 1.9 ug/kg
96-18-4 1,2,3-Trichloropropane ND 4.9 1.2 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 4.9 0.97 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 4.9 0.97 ug/kg
108-05-4 Vinyl Acetate ND 24 16 ug/kg
75-01-4 Vinyl Chloride c ND 4.9 0.97 ug/kg
m,p-Xylene ND 9.7 1.1 ug/kg
95-47-6 o-Xylene ND 4.9 0.97 ug/kg
1330-20-7 Xylene (total)ND 15 2.0 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 92%75-124%
17060-07-0 1,2-Dichloroethane-D4 101%72-135%
2037-26-5 Toluene-D8 113%75-126%
460-00-4 4-Bromofluorobenzene 108%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
27 of 123
FC287933.5
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-5
Lab Sample ID:FC2879-5 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:86.8
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated CCV and BS outside control limits high, sample is ND.
(c) Associated ICV and CCV outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
28 of 123
FC287933.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-5
Lab Sample ID:FC2879-5 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:86.8
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14142.D 1 02/27/23 13:11 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 8.12 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 4.3 1.7 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 108%56-149%
98-08-8 aaa-Trifluorotoluene 98%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
29 of 123
FC287933.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-5
Lab Sample ID:FC2879-5 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:86.8
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37931.D 1 02/24/23 19:21 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.2 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)3.78 5.7 2.9 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 68%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
30 of 123
FC287933.5
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-6
Lab Sample ID:FC2879-6 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C185574.D 1 03/02/23 17:22 AL n/a n/a V3C943
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 7.86 g 5.0 ml 10.0 ul
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 92000 46000 ug/kg
71-43-2 Benzene ND 2300 560 ug/kg
108-86-1 Bromobenzene ND 2300 460 ug/kg
74-97-5 Bromochloromethane ND 2300 680 ug/kg
75-27-4 Bromodichloromethane ND 2300 460 ug/kg
75-25-2 Bromoform ND 2300 460 ug/kg
78-93-3 2-Butanone (MEK) a ND 12000 3400 ug/kg
104-51-8 n-Butylbenzene 1890 2300 460 ug/kg J
135-98-8 sec-Butylbenzene ND 2300 460 ug/kg
98-06-6 tert-Butylbenzene ND 2300 460 ug/kg
56-23-5 Carbon Tetrachloride a ND 2300 470 ug/kg
108-90-7 Chlorobenzene ND 2300 460 ug/kg
75-00-3 Chloroethane b ND 2300 920 ug/kg
67-66-3 Chloroform ND 2300 620 ug/kg
95-49-8 o-Chlorotoluene ND 2300 460 ug/kg
106-43-4 p-Chlorotoluene ND 2300 460 ug/kg
124-48-1 Dibromochloromethane a ND 2300 460 ug/kg
106-93-4 1,2-Dibromoethane ND 2300 460 ug/kg
75-71-8 Dichlorodifluoromethane a ND 2300 920 ug/kg
95-50-1 1,2-Dichlorobenzene ND 2300 460 ug/kg
541-73-1 1,3-Dichlorobenzene ND 2300 460 ug/kg
106-46-7 1,4-Dichlorobenzene ND 2300 530 ug/kg
75-34-3 1,1-Dichloroethane ND 2300 820 ug/kg
107-06-2 1,2-Dichloroethane a ND 2300 460 ug/kg
75-35-4 1,1-Dichloroethylene ND 2300 460 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 2300 640 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 2300 460 ug/kg
78-87-5 1,2-Dichloropropane ND 2300 460 ug/kg
142-28-9 1,3-Dichloropropane ND 2300 460 ug/kg
594-20-7 2,2-Dichloropropane ND 2300 460 ug/kg
563-58-6 1,1-Dichloropropene ND 2300 470 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 2300 460 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
31 of 123
FC287933.6
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-6
Lab Sample ID:FC2879-6 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 2300 460 ug/kg
108-20-3 Di-Isopropyl Ether ND 2300 1100 ug/kg
64-17-5 Ethyl Alcohol a ND 180000 35000 ug/kg
100-41-4 Ethylbenzene 34300 2300 460 ug/kg
591-78-6 2-Hexanone a ND 12000 3500 ug/kg
98-82-8 Isopropylbenzene 3680 2300 460 ug/kg
99-87-6 p-Isopropyltoluene 574 2300 460 ug/kg J
74-83-9 Methyl Bromide ND 2300 920 ug/kg
74-87-3 Methyl Chloride ND 2300 920 ug/kg
75-09-2 Methylene Chloride a ND 9200 5100 ug/kg
108-10-1 4-Methyl-2-pentanone (MIB a ND 12000 3500 ug/kg
1634-04-4 Methyl Tert Butyl Ether a ND 2300 460 ug/kg
91-20-3 Naphthalene 5810 2300 920 ug/kg
103-65-1 n-Propylbenzene 11600 2300 460 ug/kg
100-42-5 Styrene ND 2300 460 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane a ND 2300 480 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 2300 460 ug/kg
127-18-4 Tetrachloroethylene ND 2300 590 ug/kg
108-88-3 Toluene 38300 9200 4600 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 2300 650 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 2300 460 ug/kg
71-55-6 1,1,1-Trichloroethane a ND 2300 460 ug/kg
79-00-5 1,1,2-Trichloroethane ND 2300 460 ug/kg
79-01-6 Trichloroethylene ND 2300 460 ug/kg
75-69-4 Trichlorofluoromethane a ND 2300 920 ug/kg
96-18-4 1,2,3-Trichloropropane ND 2300 580 ug/kg
95-63-6 1,2,4-Trimethylbenzene 70400 2300 460 ug/kg
108-67-8 1,3,5-Trimethylbenzene 19300 2300 460 ug/kg
108-05-4 Vinyl Acetate c ND 12000 7600 ug/kg
75-01-4 Vinyl Chloride ND 2300 460 ug/kg
m,p-Xylene 144000 4600 510 ug/kg
95-47-6 o-Xylene 61300 2300 460 ug/kg
1330-20-7 Xylene (total)206000 6900 970 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%75-124%
17060-07-0 1,2-Dichloroethane-D4 106%72-135%
2037-26-5 Toluene-D8 104%75-126%
460-00-4 4-Bromofluorobenzene 94%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
32 of 123
FC287933.6
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-6
Lab Sample ID:FC2879-6 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits low.
(c) Associated ICV and CCV outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
33 of 123
FC287933.6
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-6
Lab Sample ID:FC2879-6 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:85.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14216.D 10 03/01/23 16:16 JR n/a n/a G1U619
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 7.48 g 5.0 ml 10.0 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)1750 480 190 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 132%56-149%
98-08-8 aaa-Trifluorotoluene 89%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
34 of 123
FC287933.6
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-6
Lab Sample ID:FC2879-6 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:85.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37932.D 1 02/24/23 19:51 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.3 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)22.1 5.8 2.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 67%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
35 of 123
FC287933.6
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-7
Lab Sample ID:FC2879-7 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:79.7
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C185567.D 1 03/02/23 14:28 AL n/a n/a V3C943
Run #2 2B21609.D 1 03/03/23 12:52 AL n/a n/a V2B909
Run #3 3C185617.D 1 03/04/23 11:40 AL n/a n/a V3C945
Initial Weight Final Volume Methanol Aliquot
Run #1 7.38 g 5.0 ml
Run #2 8.64 g 5.0 ml 100 ul
Run #3 8.64 g 5.0 ml 50.0 ul
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 170 85 ug/kg
71-43-2 Benzene 145 4.3 1.0 ug/kg
108-86-1 Bromobenzene ND 4.3 0.85 ug/kg
74-97-5 Bromochloromethane ND 4.3 1.3 ug/kg
75-27-4 Bromodichloromethane ND 4.3 0.85 ug/kg
75-25-2 Bromoform ND 4.3 0.85 ug/kg
78-93-3 2-Butanone (MEK) b 73.1 21 6.2 ug/kg
104-51-8 n-Butylbenzene 16.6 4.3 0.85 ug/kg
135-98-8 sec-Butylbenzene ND 4.3 0.85 ug/kg
98-06-6 tert-Butylbenzene ND 4.3 0.85 ug/kg
56-23-5 Carbon Tetrachloride a ND 4.3 0.87 ug/kg
108-90-7 Chlorobenzene ND 4.3 0.85 ug/kg
75-00-3 Chloroethane c ND 4.3 1.7 ug/kg
67-66-3 Chloroform ND 4.3 1.1 ug/kg
95-49-8 o-Chlorotoluene ND 4.3 0.85 ug/kg
106-43-4 p-Chlorotoluene ND 4.3 0.85 ug/kg
124-48-1 Dibromochloromethane a ND 4.3 0.85 ug/kg
106-93-4 1,2-Dibromoethane ND 4.3 0.85 ug/kg
75-71-8 Dichlorodifluoromethane a ND 4.3 1.7 ug/kg
95-50-1 1,2-Dichlorobenzene ND 4.3 0.85 ug/kg
541-73-1 1,3-Dichlorobenzene ND 4.3 0.85 ug/kg
106-46-7 1,4-Dichlorobenzene ND 4.3 0.98 ug/kg
75-34-3 1,1-Dichloroethane ND 4.3 1.5 ug/kg
107-06-2 1,2-Dichloroethane a ND 4.3 0.85 ug/kg
75-35-4 1,1-Dichloroethylene ND 4.3 0.85 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 4.3 1.2 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 4.3 0.85 ug/kg
78-87-5 1,2-Dichloropropane ND 4.3 0.85 ug/kg
142-28-9 1,3-Dichloropropane ND 4.3 0.85 ug/kg
594-20-7 2,2-Dichloropropane ND 4.3 0.85 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
36 of 123
FC287933.7
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-7
Lab Sample ID:FC2879-7 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:79.7
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
563-58-6 1,1-Dichloropropene ND 4.3 0.87 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 4.3 0.85 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 4.3 0.85 ug/kg
108-20-3 Di-Isopropyl Ether ND 4.3 2.0 ug/kg
64-17-5 Ethyl Alcohol a ND 340 64 ug/kg
100-41-4 Ethylbenzene 1980 d 250 49 ug/kg
591-78-6 2-Hexanone a ND 21 6.4 ug/kg
98-82-8 Isopropylbenzene 54.3 4.3 0.85 ug/kg
99-87-6 p-Isopropyltoluene 32.0 4.3 0.85 ug/kg
74-83-9 Methyl Bromide ND 4.3 1.7 ug/kg
74-87-3 Methyl Chloride ND 4.3 1.7 ug/kg
75-09-2 Methylene Chloride a ND 17 9.4 ug/kg
108-10-1 4-Methyl-2-pentanone (MIB e 19.4 21 6.4 ug/kg J
1634-04-4 Methyl Tert Butyl Ether a ND 4.3 0.85 ug/kg
91-20-3 Naphthalene 87.7 4.3 1.7 ug/kg
103-65-1 n-Propylbenzene 130 4.3 0.85 ug/kg
100-42-5 Styrene ND 4.3 0.85 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane a ND 4.3 0.88 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 4.3 0.85 ug/kg
127-18-4 Tetrachloroethylene ND 4.3 1.1 ug/kg
108-88-3 Toluene 8200 f 2000 980 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 4.3 1.2 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 4.3 0.85 ug/kg
71-55-6 1,1,1-Trichloroethane a ND 4.3 0.85 ug/kg
79-00-5 1,1,2-Trichloroethane ND 4.3 0.85 ug/kg
79-01-6 Trichloroethylene ND 4.3 0.85 ug/kg
75-69-4 Trichlorofluoromethane a ND 4.3 1.7 ug/kg
96-18-4 1,2,3-Trichloropropane ND 4.3 1.1 ug/kg
95-63-6 1,2,4-Trimethylbenzene 4380 d 250 49 ug/kg
108-67-8 1,3,5-Trimethylbenzene 1040 d 250 49 ug/kg
108-05-4 Vinyl Acetate g ND 21 14 ug/kg
75-01-4 Vinyl Chloride ND 4.3 0.85 ug/kg
m,p-Xylene 9520 d 490 54 ug/kg
95-47-6 o-Xylene 4060 d 250 49 ug/kg
1330-20-7 Xylene (total)13600 d 740 100 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
1868-53-7 Dibromofluoromethane 98%92%98%75-124%
17060-07-0 1,2-Dichloroethane-D4 124%101%118%72-135%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
37 of 123
FC287933.7
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-7
Lab Sample ID:FC2879-7 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:79.7
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
2037-26-5 Toluene-D8 105%103%101%75-126%
460-00-4 4-Bromofluorobenzene 103%103%94%71-133%
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated CCV outside control limits high. Compound was below calibration range in higher dilution.
(c) Associated BS recovery outside control limits low.
(d) Result is from Run# 2
(e) Associated CCV outside control limits high. ND at higher dilution.
(f) Result is from Run# 3
(g) Associated ICV and CCV outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
38 of 123
FC287933.7
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-7
Lab Sample ID:FC2879-7 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:79.7
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14215.D 1 03/01/23 15:50 JR n/a n/a G1U619
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 7.30 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)14.8 5.6 2.2 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 126%56-149%
98-08-8 aaa-Trifluorotoluene 85%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
39 of 123
FC287933.7
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-7
Lab Sample ID:FC2879-7 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:79.7
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37933.D 1 02/24/23 20:20 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)5.36 6.3 3.1 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 70%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
40 of 123
FC287933.7
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-8
Lab Sample ID:FC2879-8 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:88.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2B21610.D 1 03/03/23 13:17 AL n/a n/a V2B909
Run #2
Initial Weight Final Volume
Run #1 5.04 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 230 110 ug/kg
71-43-2 Benzene ND 5.6 1.4 ug/kg
108-86-1 Bromobenzene ND 5.6 1.1 ug/kg
74-97-5 Bromochloromethane ND 5.6 1.7 ug/kg
75-27-4 Bromodichloromethane ND 5.6 1.1 ug/kg
75-25-2 Bromoform ND 5.6 1.1 ug/kg
78-93-3 2-Butanone (MEK)ND 28 8.2 ug/kg
104-51-8 n-Butylbenzene ND 5.6 1.1 ug/kg
135-98-8 sec-Butylbenzene ND 5.6 1.1 ug/kg
98-06-6 tert-Butylbenzene ND 5.6 1.1 ug/kg
56-23-5 Carbon Tetrachloride ND 5.6 1.1 ug/kg
108-90-7 Chlorobenzene ND 5.6 1.1 ug/kg
75-00-3 Chloroethane a ND 5.6 2.3 ug/kg
67-66-3 Chloroform ND 5.6 1.5 ug/kg
95-49-8 o-Chlorotoluene ND 5.6 1.1 ug/kg
106-43-4 p-Chlorotoluene ND 5.6 1.1 ug/kg
124-48-1 Dibromochloromethane ND 5.6 1.1 ug/kg
106-93-4 1,2-Dibromoethane ND 5.6 1.1 ug/kg
75-71-8 Dichlorodifluoromethane b ND 5.6 2.3 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.6 1.1 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.6 1.1 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.6 1.3 ug/kg
75-34-3 1,1-Dichloroethane ND 5.6 2.0 ug/kg
107-06-2 1,2-Dichloroethane ND 5.6 1.1 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.6 1.1 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.6 1.6 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.6 1.1 ug/kg
78-87-5 1,2-Dichloropropane ND 5.6 1.1 ug/kg
142-28-9 1,3-Dichloropropane ND 5.6 1.1 ug/kg
594-20-7 2,2-Dichloropropane ND 5.6 1.1 ug/kg
563-58-6 1,1-Dichloropropene ND 5.6 1.1 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.6 1.1 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
41 of 123
FC287933.8
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-8
Lab Sample ID:FC2879-8 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:88.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 5.6 1.1 ug/kg
108-20-3 Di-Isopropyl Ether ND 5.6 2.6 ug/kg
64-17-5 Ethyl Alcohol ND 450 85 ug/kg
100-41-4 Ethylbenzene ND 5.6 1.1 ug/kg
591-78-6 2-Hexanone ND 28 8.5 ug/kg
98-82-8 Isopropylbenzene ND 5.6 1.1 ug/kg
99-87-6 p-Isopropyltoluene ND 5.6 1.1 ug/kg
74-83-9 Methyl Bromide c ND 5.6 2.3 ug/kg
74-87-3 Methyl Chloride b ND 5.6 2.3 ug/kg
75-09-2 Methylene Chloride ND 23 12 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 28 8.5 ug/kg
1634-04-4 Methyl Tert Butyl Ether c ND 5.6 1.1 ug/kg
91-20-3 Naphthalene ND 5.6 2.3 ug/kg
103-65-1 n-Propylbenzene ND 5.6 1.1 ug/kg
100-42-5 Styrene ND 5.6 1.1 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 5.6 1.2 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.6 1.1 ug/kg
127-18-4 Tetrachloroethylene ND 5.6 1.4 ug/kg
108-88-3 Toluene ND 23 11 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 5.6 1.6 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.6 1.1 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.6 1.1 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.6 1.1 ug/kg
79-01-6 Trichloroethylene ND 5.6 1.1 ug/kg
75-69-4 Trichlorofluoromethane c ND 5.6 2.3 ug/kg
96-18-4 1,2,3-Trichloropropane ND 5.6 1.4 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.6 1.1 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.6 1.1 ug/kg
108-05-4 Vinyl Acetate ND 28 18 ug/kg
75-01-4 Vinyl Chloride b ND 5.6 1.1 ug/kg
m,p-Xylene ND 11 1.2 ug/kg
95-47-6 o-Xylene ND 5.6 1.1 ug/kg
1330-20-7 Xylene (total)ND 17 2.4 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 92%75-124%
17060-07-0 1,2-Dichloroethane-D4 95%72-135%
2037-26-5 Toluene-D8 110%75-126%
460-00-4 4-Bromofluorobenzene 104%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
42 of 123
FC287933.8
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-8
Lab Sample ID:FC2879-8 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:88.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV and BS outside control limits high, sample is ND.
(b) Associated ICV and CCV outside control limits high, sample is ND.
(c) Associated CCV outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
43 of 123
FC287933.8
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-8
Lab Sample ID:FC2879-8 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:88.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14148.D 1 02/27/23 15:35 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 8.53 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 4.0 1.6 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 110%56-149%
98-08-8 aaa-Trifluorotoluene 98%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
44 of 123
FC287933.8
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-8
Lab Sample ID:FC2879-8 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:88.0
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37937.D 1 02/24/23 22:19 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)4.32 5.7 2.8 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 70%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
45 of 123
FC287933.8
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-9
Lab Sample ID:FC2879-9 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.4
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2B21611.D 1 03/03/23 13:42 AL n/a n/a V2B909
Run #2
Initial Weight Final Volume
Run #1 8.38 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 140 70 ug/kg
71-43-2 Benzene ND 3.5 0.85 ug/kg
108-86-1 Bromobenzene ND 3.5 0.70 ug/kg
74-97-5 Bromochloromethane ND 3.5 1.0 ug/kg
75-27-4 Bromodichloromethane ND 3.5 0.70 ug/kg
75-25-2 Bromoform ND 3.5 0.70 ug/kg
78-93-3 2-Butanone (MEK)5.9 17 5.1 ug/kg J
104-51-8 n-Butylbenzene 1.0 3.5 0.70 ug/kg J
135-98-8 sec-Butylbenzene 1.0 3.5 0.70 ug/kg J
98-06-6 tert-Butylbenzene ND 3.5 0.70 ug/kg
56-23-5 Carbon Tetrachloride ND 3.5 0.71 ug/kg
108-90-7 Chlorobenzene ND 3.5 0.70 ug/kg
75-00-3 Chloroethane a ND 3.5 1.4 ug/kg
67-66-3 Chloroform ND 3.5 0.93 ug/kg
95-49-8 o-Chlorotoluene ND 3.5 0.70 ug/kg
106-43-4 p-Chlorotoluene ND 3.5 0.70 ug/kg
124-48-1 Dibromochloromethane ND 3.5 0.70 ug/kg
106-93-4 1,2-Dibromoethane ND 3.5 0.70 ug/kg
75-71-8 Dichlorodifluoromethane b ND 3.5 1.4 ug/kg
95-50-1 1,2-Dichlorobenzene ND 3.5 0.70 ug/kg
541-73-1 1,3-Dichlorobenzene ND 3.5 0.70 ug/kg
106-46-7 1,4-Dichlorobenzene ND 3.5 0.80 ug/kg
75-34-3 1,1-Dichloroethane ND 3.5 1.2 ug/kg
107-06-2 1,2-Dichloroethane ND 3.5 0.70 ug/kg
75-35-4 1,1-Dichloroethylene ND 3.5 0.70 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 3.5 0.96 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 3.5 0.70 ug/kg
78-87-5 1,2-Dichloropropane ND 3.5 0.70 ug/kg
142-28-9 1,3-Dichloropropane ND 3.5 0.70 ug/kg
594-20-7 2,2-Dichloropropane ND 3.5 0.70 ug/kg
563-58-6 1,1-Dichloropropene ND 3.5 0.71 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 3.5 0.70 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
46 of 123
FC287933.9
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-9
Lab Sample ID:FC2879-9 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.4
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 3.5 0.70 ug/kg
108-20-3 Di-Isopropyl Ether ND 3.5 1.6 ug/kg
64-17-5 Ethyl Alcohol ND 280 52 ug/kg
100-41-4 Ethylbenzene 5.4 3.5 0.70 ug/kg
591-78-6 2-Hexanone ND 17 5.2 ug/kg
98-82-8 Isopropylbenzene 2.2 3.5 0.70 ug/kg J
99-87-6 p-Isopropyltoluene ND 3.5 0.70 ug/kg
74-83-9 Methyl Bromide c ND 3.5 1.4 ug/kg
74-87-3 Methyl Chloride b ND 3.5 1.4 ug/kg
75-09-2 Methylene Chloride ND 14 7.7 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 17 5.2 ug/kg
1634-04-4 Methyl Tert Butyl Ether c ND 3.5 0.70 ug/kg
91-20-3 Naphthalene 2.1 3.5 1.4 ug/kg J
103-65-1 n-Propylbenzene 6.0 3.5 0.70 ug/kg
100-42-5 Styrene ND 3.5 0.70 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 3.5 0.72 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 3.5 0.70 ug/kg
127-18-4 Tetrachloroethylene ND 3.5 0.89 ug/kg
108-88-3 Toluene ND 14 7.0 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 3.5 0.98 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 3.5 0.70 ug/kg
71-55-6 1,1,1-Trichloroethane ND 3.5 0.70 ug/kg
79-00-5 1,1,2-Trichloroethane ND 3.5 0.70 ug/kg
79-01-6 Trichloroethylene ND 3.5 0.70 ug/kg
75-69-4 Trichlorofluoromethane c ND 3.5 1.4 ug/kg
96-18-4 1,2,3-Trichloropropane ND 3.5 0.87 ug/kg
95-63-6 1,2,4-Trimethylbenzene 25.2 3.5 0.70 ug/kg
108-67-8 1,3,5-Trimethylbenzene 8.1 3.5 0.70 ug/kg
108-05-4 Vinyl Acetate ND 17 11 ug/kg
75-01-4 Vinyl Chloride b ND 3.5 0.70 ug/kg
m,p-Xylene ND 7.0 0.77 ug/kg
95-47-6 o-Xylene ND 3.5 0.70 ug/kg
1330-20-7 Xylene (total)ND 10 1.5 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 96%75-124%
17060-07-0 1,2-Dichloroethane-D4 100%72-135%
2037-26-5 Toluene-D8 108%75-126%
460-00-4 4-Bromofluorobenzene 110%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
47 of 123
FC287933.9
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-9
Lab Sample ID:FC2879-9 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.4
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV and BS outside control limits high, sample is ND.
(b) Associated ICV and CCV outside control limits high, sample is ND.
(c) Associated CCV outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
48 of 123
FC287933.9
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-9
Lab Sample ID:FC2879-9 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:85.4
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14149.D 1 02/27/23 16:00 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 8.12 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)2.19 4.5 1.8 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 108%56-149%
98-08-8 aaa-Trifluorotoluene 100%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
49 of 123
FC287933.9
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-9
Lab Sample ID:FC2879-9 Date Sampled:02/20/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:85.4
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37938.D 1 02/24/23 22:48 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)4.44 5.9 2.9 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 68%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
50 of 123
FC287933.9
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-10
Lab Sample ID:FC2879-10 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:87.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C185570.D 1 03/02/23 15:43 AL n/a n/a V3C943
Run #2
Initial Weight Final Volume
Run #1 7.82 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 150 73 ug/kg
71-43-2 Benzene ND 3.7 0.89 ug/kg
108-86-1 Bromobenzene ND 3.7 0.73 ug/kg
74-97-5 Bromochloromethane ND 3.7 1.1 ug/kg
75-27-4 Bromodichloromethane ND 3.7 0.73 ug/kg
75-25-2 Bromoform ND 3.7 0.73 ug/kg
78-93-3 2-Butanone (MEK) a ND 18 5.3 ug/kg
104-51-8 n-Butylbenzene ND 3.7 0.73 ug/kg
135-98-8 sec-Butylbenzene ND 3.7 0.73 ug/kg
98-06-6 tert-Butylbenzene ND 3.7 0.73 ug/kg
56-23-5 Carbon Tetrachloride a ND 3.7 0.75 ug/kg
108-90-7 Chlorobenzene ND 3.7 0.73 ug/kg
75-00-3 Chloroethane b ND 3.7 1.5 ug/kg
67-66-3 Chloroform ND 3.7 0.97 ug/kg
95-49-8 o-Chlorotoluene ND 3.7 0.73 ug/kg
106-43-4 p-Chlorotoluene ND 3.7 0.73 ug/kg
124-48-1 Dibromochloromethane a ND 3.7 0.73 ug/kg
106-93-4 1,2-Dibromoethane ND 3.7 0.73 ug/kg
75-71-8 Dichlorodifluoromethane a ND 3.7 1.5 ug/kg
95-50-1 1,2-Dichlorobenzene ND 3.7 0.73 ug/kg
541-73-1 1,3-Dichlorobenzene ND 3.7 0.73 ug/kg
106-46-7 1,4-Dichlorobenzene ND 3.7 0.84 ug/kg
75-34-3 1,1-Dichloroethane ND 3.7 1.3 ug/kg
107-06-2 1,2-Dichloroethane a ND 3.7 0.73 ug/kg
75-35-4 1,1-Dichloroethylene ND 3.7 0.73 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 3.7 1.0 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 3.7 0.73 ug/kg
78-87-5 1,2-Dichloropropane ND 3.7 0.73 ug/kg
142-28-9 1,3-Dichloropropane ND 3.7 0.73 ug/kg
594-20-7 2,2-Dichloropropane ND 3.7 0.73 ug/kg
563-58-6 1,1-Dichloropropene ND 3.7 0.75 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 3.7 0.73 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
51 of 123
FC287933.10
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-10
Lab Sample ID:FC2879-10 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:87.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 3.7 0.73 ug/kg
108-20-3 Di-Isopropyl Ether ND 3.7 1.7 ug/kg
64-17-5 Ethyl Alcohol a ND 290 55 ug/kg
100-41-4 Ethylbenzene ND 3.7 0.73 ug/kg
591-78-6 2-Hexanone a ND 18 5.5 ug/kg
98-82-8 Isopropylbenzene ND 3.7 0.73 ug/kg
99-87-6 p-Isopropyltoluene ND 3.7 0.73 ug/kg
74-83-9 Methyl Bromide ND 3.7 1.5 ug/kg
74-87-3 Methyl Chloride ND 3.7 1.5 ug/kg
75-09-2 Methylene Chloride a ND 15 8.1 ug/kg
108-10-1 4-Methyl-2-pentanone (MIB a ND 18 5.5 ug/kg
1634-04-4 Methyl Tert Butyl Ether a ND 3.7 0.73 ug/kg
91-20-3 Naphthalene ND 3.7 1.5 ug/kg
103-65-1 n-Propylbenzene ND 3.7 0.73 ug/kg
100-42-5 Styrene ND 3.7 0.73 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane a ND 3.7 0.75 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 3.7 0.73 ug/kg
127-18-4 Tetrachloroethylene ND 3.7 0.94 ug/kg
108-88-3 Toluene ND 15 7.3 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 3.7 1.0 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 3.7 0.73 ug/kg
71-55-6 1,1,1-Trichloroethane a ND 3.7 0.73 ug/kg
79-00-5 1,1,2-Trichloroethane ND 3.7 0.73 ug/kg
79-01-6 Trichloroethylene ND 3.7 0.73 ug/kg
75-69-4 Trichlorofluoromethane a ND 3.7 1.5 ug/kg
96-18-4 1,2,3-Trichloropropane ND 3.7 0.92 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 3.7 0.73 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 3.7 0.73 ug/kg
108-05-4 Vinyl Acetate c ND 18 12 ug/kg
75-01-4 Vinyl Chloride ND 3.7 0.73 ug/kg
m,p-Xylene ND 7.3 0.81 ug/kg
95-47-6 o-Xylene ND 3.7 0.73 ug/kg
1330-20-7 Xylene (total)ND 11 1.5 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%75-124%
17060-07-0 1,2-Dichloroethane-D4 114%72-135%
2037-26-5 Toluene-D8 100%75-126%
460-00-4 4-Bromofluorobenzene 94%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
52 of 123
FC287933.10
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-10
Lab Sample ID:FC2879-10 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:87.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits low.
(c) Associated ICV and CCV outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
53 of 123
FC287933.10
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-10
Lab Sample ID:FC2879-10 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:87.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14150.D 1 02/27/23 16:24 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 7.07 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 4.8 1.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 108%56-149%
98-08-8 aaa-Trifluorotoluene 97%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
54 of 123
FC287933.10
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-10
Lab Sample ID:FC2879-10 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:87.3
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37939.D 1 02/24/23 23:18 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.1 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)5.27 5.7 2.8 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 71%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
55 of 123
FC287933.10
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-11
Lab Sample ID:FC2879-11 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3C185571.D 1 03/02/23 16:08 AL n/a n/a V3C943
Run #2
Initial Weight Final Volume
Run #1 8.33 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone a ND 140 70 ug/kg
71-43-2 Benzene ND 3.5 0.86 ug/kg
108-86-1 Bromobenzene ND 3.5 0.70 ug/kg
74-97-5 Bromochloromethane ND 3.5 1.0 ug/kg
75-27-4 Bromodichloromethane ND 3.5 0.70 ug/kg
75-25-2 Bromoform ND 3.5 0.70 ug/kg
78-93-3 2-Butanone (MEK) a ND 18 5.1 ug/kg
104-51-8 n-Butylbenzene ND 3.5 0.70 ug/kg
135-98-8 sec-Butylbenzene ND 3.5 0.70 ug/kg
98-06-6 tert-Butylbenzene ND 3.5 0.70 ug/kg
56-23-5 Carbon Tetrachloride a ND 3.5 0.72 ug/kg
108-90-7 Chlorobenzene ND 3.5 0.70 ug/kg
75-00-3 Chloroethane b ND 3.5 1.4 ug/kg
67-66-3 Chloroform ND 3.5 0.94 ug/kg
95-49-8 o-Chlorotoluene ND 3.5 0.70 ug/kg
106-43-4 p-Chlorotoluene ND 3.5 0.70 ug/kg
124-48-1 Dibromochloromethane a ND 3.5 0.70 ug/kg
106-93-4 1,2-Dibromoethane ND 3.5 0.70 ug/kg
75-71-8 Dichlorodifluoromethane a ND 3.5 1.4 ug/kg
95-50-1 1,2-Dichlorobenzene ND 3.5 0.70 ug/kg
541-73-1 1,3-Dichlorobenzene ND 3.5 0.70 ug/kg
106-46-7 1,4-Dichlorobenzene ND 3.5 0.81 ug/kg
75-34-3 1,1-Dichloroethane ND 3.5 1.2 ug/kg
107-06-2 1,2-Dichloroethane a ND 3.5 0.70 ug/kg
75-35-4 1,1-Dichloroethylene ND 3.5 0.70 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 3.5 0.97 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 3.5 0.70 ug/kg
78-87-5 1,2-Dichloropropane ND 3.5 0.70 ug/kg
142-28-9 1,3-Dichloropropane ND 3.5 0.70 ug/kg
594-20-7 2,2-Dichloropropane ND 3.5 0.70 ug/kg
563-58-6 1,1-Dichloropropene ND 3.5 0.72 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 3.5 0.70 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
56 of 123
FC287933.11
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-11
Lab Sample ID:FC2879-11 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 3.5 0.70 ug/kg
108-20-3 Di-Isopropyl Ether ND 3.5 1.6 ug/kg
64-17-5 Ethyl Alcohol a ND 280 53 ug/kg
100-41-4 Ethylbenzene ND 3.5 0.70 ug/kg
591-78-6 2-Hexanone a ND 18 5.3 ug/kg
98-82-8 Isopropylbenzene ND 3.5 0.70 ug/kg
99-87-6 p-Isopropyltoluene ND 3.5 0.70 ug/kg
74-83-9 Methyl Bromide ND 3.5 1.4 ug/kg
74-87-3 Methyl Chloride ND 3.5 1.4 ug/kg
75-09-2 Methylene Chloride a ND 14 7.7 ug/kg
108-10-1 4-Methyl-2-pentanone (MIB a ND 18 5.3 ug/kg
1634-04-4 Methyl Tert Butyl Ether a ND 3.5 0.70 ug/kg
91-20-3 Naphthalene ND 3.5 1.4 ug/kg
103-65-1 n-Propylbenzene ND 3.5 0.70 ug/kg
100-42-5 Styrene ND 3.5 0.70 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane a ND 3.5 0.73 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 3.5 0.70 ug/kg
127-18-4 Tetrachloroethylene ND 3.5 0.90 ug/kg
108-88-3 Toluene ND 14 7.0 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 3.5 0.99 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 3.5 0.70 ug/kg
71-55-6 1,1,1-Trichloroethane a ND 3.5 0.70 ug/kg
79-00-5 1,1,2-Trichloroethane ND 3.5 0.70 ug/kg
79-01-6 Trichloroethylene ND 3.5 0.70 ug/kg
75-69-4 Trichlorofluoromethane a ND 3.5 1.4 ug/kg
96-18-4 1,2,3-Trichloropropane ND 3.5 0.88 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 3.5 0.70 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 3.5 0.70 ug/kg
108-05-4 Vinyl Acetate c ND 18 12 ug/kg
75-01-4 Vinyl Chloride ND 3.5 0.70 ug/kg
m,p-Xylene ND 7.0 0.77 ug/kg
95-47-6 o-Xylene ND 3.5 0.70 ug/kg
1330-20-7 Xylene (total)ND 11 1.5 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%75-124%
17060-07-0 1,2-Dichloroethane-D4 116%72-135%
2037-26-5 Toluene-D8 99%75-126%
460-00-4 4-Bromofluorobenzene 95%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
57 of 123
FC287933.11
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-11
Lab Sample ID:FC2879-11 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:85.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV outside control limits high, sample is ND.
(b) Associated BS recovery outside control limits low.
(c) Associated ICV and CCV outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
58 of 123
FC287933.11
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-11
Lab Sample ID:FC2879-11 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:85.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14151.D 1 02/27/23 16:48 JR n/a n/a G1U617
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 6.59 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.3 2.1 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 108%56-149%
98-08-8 aaa-Trifluorotoluene 96%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
59 of 123
FC287933.11
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-11
Lab Sample ID:FC2879-11 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:85.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37940.D 1 02/24/23 23:47 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.1 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)4.10 5.8 2.9 mg/kg J
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 69%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
60 of 123
FC287933.11
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:SB-17
Lab Sample ID:FC2879-12 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:88.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 2B21612.D 1 03/03/23 14:07 AL n/a n/a V2B909
Run #2
Initial Weight Final Volume
Run #1 6.18 g 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone 261 180 92 ug/kg
71-43-2 Benzene 1.6 4.6 1.1 ug/kg J
108-86-1 Bromobenzene ND 4.6 0.92 ug/kg
74-97-5 Bromochloromethane ND 4.6 1.4 ug/kg
75-27-4 Bromodichloromethane ND 4.6 0.92 ug/kg
75-25-2 Bromoform ND 4.6 0.92 ug/kg
78-93-3 2-Butanone (MEK)52.0 23 6.7 ug/kg
104-51-8 n-Butylbenzene ND 4.6 0.92 ug/kg
135-98-8 sec-Butylbenzene ND 4.6 0.92 ug/kg
98-06-6 tert-Butylbenzene ND 4.6 0.92 ug/kg
56-23-5 Carbon Tetrachloride ND 4.6 0.94 ug/kg
108-90-7 Chlorobenzene ND 4.6 0.92 ug/kg
75-00-3 Chloroethane a ND 4.6 1.8 ug/kg
67-66-3 Chloroform ND 4.6 1.2 ug/kg
95-49-8 o-Chlorotoluene ND 4.6 0.92 ug/kg
106-43-4 p-Chlorotoluene ND 4.6 0.92 ug/kg
124-48-1 Dibromochloromethane ND 4.6 0.92 ug/kg
106-93-4 1,2-Dibromoethane ND 4.6 0.92 ug/kg
75-71-8 Dichlorodifluoromethane b ND 4.6 1.8 ug/kg
95-50-1 1,2-Dichlorobenzene ND 4.6 0.92 ug/kg
541-73-1 1,3-Dichlorobenzene ND 4.6 0.92 ug/kg
106-46-7 1,4-Dichlorobenzene ND 4.6 1.1 ug/kg
75-34-3 1,1-Dichloroethane ND 4.6 1.6 ug/kg
107-06-2 1,2-Dichloroethane ND 4.6 0.92 ug/kg
75-35-4 1,1-Dichloroethylene ND 4.6 0.92 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 4.6 1.3 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 4.6 0.92 ug/kg
78-87-5 1,2-Dichloropropane ND 4.6 0.92 ug/kg
142-28-9 1,3-Dichloropropane ND 4.6 0.92 ug/kg
594-20-7 2,2-Dichloropropane ND 4.6 0.92 ug/kg
563-58-6 1,1-Dichloropropene ND 4.6 0.94 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 4.6 0.92 ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
61 of 123
FC287933.12
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:SB-17
Lab Sample ID:FC2879-12 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:88.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 4.6 0.92 ug/kg
108-20-3 Di-Isopropyl Ether ND 4.6 2.1 ug/kg
64-17-5 Ethyl Alcohol 189 370 69 ug/kg J
100-41-4 Ethylbenzene ND 4.6 0.92 ug/kg
591-78-6 2-Hexanone ND 23 6.9 ug/kg
98-82-8 Isopropylbenzene ND 4.6 0.92 ug/kg
99-87-6 p-Isopropyltoluene ND 4.6 0.92 ug/kg
74-83-9 Methyl Bromide c ND 4.6 1.8 ug/kg
74-87-3 Methyl Chloride b ND 4.6 1.8 ug/kg
75-09-2 Methylene Chloride ND 18 10 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 23 6.9 ug/kg
1634-04-4 Methyl Tert Butyl Ether c ND 4.6 0.92 ug/kg
91-20-3 Naphthalene ND 4.6 1.8 ug/kg
103-65-1 n-Propylbenzene ND 4.6 0.92 ug/kg
100-42-5 Styrene ND 4.6 0.92 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 4.6 0.94 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 4.6 0.92 ug/kg
127-18-4 Tetrachloroethylene ND 4.6 1.2 ug/kg
108-88-3 Toluene ND 18 9.2 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 4.6 1.3 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 4.6 0.92 ug/kg
71-55-6 1,1,1-Trichloroethane ND 4.6 0.92 ug/kg
79-00-5 1,1,2-Trichloroethane ND 4.6 0.92 ug/kg
79-01-6 Trichloroethylene ND 4.6 0.92 ug/kg
75-69-4 Trichlorofluoromethane c ND 4.6 1.8 ug/kg
96-18-4 1,2,3-Trichloropropane ND 4.6 1.1 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 4.6 0.92 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 4.6 0.92 ug/kg
108-05-4 Vinyl Acetate ND 23 15 ug/kg
75-01-4 Vinyl Chloride b ND 4.6 0.92 ug/kg
m,p-Xylene ND 9.2 1.0 ug/kg
95-47-6 o-Xylene ND 4.6 0.92 ug/kg
1330-20-7 Xylene (total)ND 14 1.9 ug/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 96%75-124%
17060-07-0 1,2-Dichloroethane-D4 97%72-135%
2037-26-5 Toluene-D8 110%75-126%
460-00-4 4-Bromofluorobenzene 110%71-133%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
62 of 123
FC287933.12
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:SB-17
Lab Sample ID:FC2879-12 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8260D Percent Solids:88.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
VOA List for NC, May 2012
CAS No.Compound Result RL MDL Units Q
(a) Associated CCV and BS outside control limits high, sample is ND.
(b) Associated ICV and CCV outside control limits high, sample is ND.
(c) Associated CCV outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
63 of 123
FC287933.12
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-17
Lab Sample ID:FC2879-12 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C Percent Solids:88.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U14169.D 1 02/28/23 11:02 JR n/a n/a G1U618
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 5.80 g 5.0 ml 100 ul
Run #2
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.6 2.2 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 111%56-149%
98-08-8 aaa-Trifluorotoluene 89%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
64 of 123
FC287933.12
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-17
Lab Sample ID:FC2879-12 Date Sampled:02/21/23
Matrix:SO - Soil Date Received:02/22/23
Method:SW846 8015C SW846 3546 Percent Solids:88.2
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW37941.D 1 02/25/23 00:17 EG 02/24/23 08:00 OP95605 GWW1484
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)ND 5.7 2.8 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 66%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
65 of 123
FC287933.12
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
66 of 123
FC28794
FC2879: Chain of Custody
Page 1 of 3
67 of 123
FC287944.1
FC2879: Chain of Custody
Page 2 of 3
68 of 123
FC287944.1
Job Number:FC2879 Client:GES
Date / Time Received:2/22/2023 9:30:00 AM Delivery Method:FX
Project:MURPHY # 2701997
Airbill #'s:570790507267
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments FROZEN @ 1400 // 2/22/23
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (2.4);
Cooler 1: (2.6);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.2; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:NATHANS Date:Date:2/22/2023 9:30:00 AM
FC2879: Chain of Custody
Page 3 of 3
69 of 123
FC287944.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
70 of 123
FC28795
Method Blank Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C939-MB 3C185449.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 200 100 ug/kg
71-43-2 Benzene ND 5.0 1.2 ug/kg
108-86-1 Bromobenzene ND 5.0 1.0 ug/kg
74-97-5 Bromochloromethane ND 5.0 1.5 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
135-98-8 sec-Butylbenzene ND 5.0 1.0 ug/kg
98-06-6 tert-Butylbenzene ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
95-49-8 o-Chlorotoluene ND 5.0 1.0 ug/kg
106-43-4 p-Chlorotoluene ND 5.0 1.0 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
142-28-9 1,3-Dichloropropane ND 5.0 1.0 ug/kg
594-20-7 2,2-Dichloropropane ND 5.0 1.0 ug/kg
563-58-6 1,1-Dichloropropene ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
108-20-3 Di-Isopropyl Ether ND 5.0 2.3 ug/kg
64-17-5 Ethyl Alcohol ND 400 75 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
71 of 123
FC287955.1.1
Method Blank Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C939-MB 3C185449.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
CAS No.Compound Result RL MDL Units Q
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
99-87-6 p-Isopropyltoluene ND 5.0 1.0 ug/kg
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
75-09-2 Methylene Chloride ND 20 11 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/kg
108-88-3 Toluene ND 20 10 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.4 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
108-05-4 Vinyl Acetate ND 25 16 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
m,p-Xylene ND 10 1.1 ug/kg
95-47-6 o-Xylene ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 94%75-124%
17060-07-0 1,2-Dichloroethane-D4 101%72-135%
2037-26-5 Toluene-D8 102%75-126%
72 of 123
FC287955.1.1
Method Blank Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C939-MB 3C185449.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 96%71-133%
73 of 123
FC287955.1.1
Method Blank Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C941-MB 3C185503.D 1 02/28/23 DB n/a n/a V3C941
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1
CAS No.Compound Result RL MDL Units Q
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%75-124%
17060-07-0 1,2-Dichloroethane-D4 104%72-135%
2037-26-5 Toluene-D8 103%75-126%
460-00-4 4-Bromofluorobenzene 95%71-133%
74 of 123
FC287955.1.2
Method Blank Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B907-MB 2B21545.D 1 03/01/23 AL n/a n/a V2B907
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-4, FC2879-5
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 200 100 ug/kg
71-43-2 Benzene ND 5.0 1.2 ug/kg
108-86-1 Bromobenzene ND 5.0 1.0 ug/kg
74-97-5 Bromochloromethane ND 5.0 1.5 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
135-98-8 sec-Butylbenzene ND 5.0 1.0 ug/kg
98-06-6 tert-Butylbenzene ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
95-49-8 o-Chlorotoluene ND 5.0 1.0 ug/kg
106-43-4 p-Chlorotoluene ND 5.0 1.0 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
142-28-9 1,3-Dichloropropane ND 5.0 1.0 ug/kg
594-20-7 2,2-Dichloropropane ND 5.0 1.0 ug/kg
563-58-6 1,1-Dichloropropene ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
108-20-3 Di-Isopropyl Ether ND 5.0 2.3 ug/kg
64-17-5 Ethyl Alcohol ND 400 75 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
75 of 123
FC287955.1.3
Method Blank Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B907-MB 2B21545.D 1 03/01/23 AL n/a n/a V2B907
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-4, FC2879-5
CAS No.Compound Result RL MDL Units Q
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
99-87-6 p-Isopropyltoluene ND 5.0 1.0 ug/kg
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
75-09-2 Methylene Chloride ND 20 11 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/kg
108-88-3 Toluene ND 20 10 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.4 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
108-05-4 Vinyl Acetate ND 25 16 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
m,p-Xylene ND 10 1.1 ug/kg
95-47-6 o-Xylene ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 95%75-124%
17060-07-0 1,2-Dichloroethane-D4 99%72-135%
2037-26-5 Toluene-D8 110%75-126%
76 of 123
FC287955.1.3
Method Blank Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B907-MB 2B21545.D 1 03/01/23 AL n/a n/a V2B907
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-4, FC2879-5
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 107%71-133%
77 of 123
FC287955.1.3
Method Blank Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C943-MB 3C185559.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 200 100 ug/kg
71-43-2 Benzene ND 5.0 1.2 ug/kg
108-86-1 Bromobenzene ND 5.0 1.0 ug/kg
74-97-5 Bromochloromethane ND 5.0 1.5 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
135-98-8 sec-Butylbenzene ND 5.0 1.0 ug/kg
98-06-6 tert-Butylbenzene ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
95-49-8 o-Chlorotoluene ND 5.0 1.0 ug/kg
106-43-4 p-Chlorotoluene ND 5.0 1.0 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
142-28-9 1,3-Dichloropropane ND 5.0 1.0 ug/kg
594-20-7 2,2-Dichloropropane ND 5.0 1.0 ug/kg
563-58-6 1,1-Dichloropropene ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
108-20-3 Di-Isopropyl Ether ND 5.0 2.3 ug/kg
64-17-5 Ethyl Alcohol ND 400 75 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
78 of 123
FC287955.1.4
Method Blank Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C943-MB 3C185559.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
CAS No.Compound Result RL MDL Units Q
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
99-87-6 p-Isopropyltoluene ND 5.0 1.0 ug/kg
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
75-09-2 Methylene Chloride a 21.4 20 11 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/kg
108-88-3 Toluene ND 20 10 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.4 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
108-05-4 Vinyl Acetate ND 25 16 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
m,p-Xylene ND 10 1.1 ug/kg
95-47-6 o-Xylene ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 102%75-124%
17060-07-0 1,2-Dichloroethane-D4 110%72-135%
2037-26-5 Toluene-D8 102%75-126%
79 of 123
FC287955.1.4
Method Blank Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C943-MB 3C185559.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 92%71-133%
(a) Suspected laboratory contaminant.
80 of 123
FC287955.1.4
Method Blank Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B909-MB 2B21605.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
CAS No.Compound Result RL MDL Units Q
67-64-1 Acetone ND 200 100 ug/kg
71-43-2 Benzene ND 5.0 1.2 ug/kg
108-86-1 Bromobenzene ND 5.0 1.0 ug/kg
74-97-5 Bromochloromethane ND 5.0 1.5 ug/kg
75-27-4 Bromodichloromethane ND 5.0 1.0 ug/kg
75-25-2 Bromoform ND 5.0 1.0 ug/kg
78-93-3 2-Butanone (MEK)ND 25 7.3 ug/kg
104-51-8 n-Butylbenzene ND 5.0 1.0 ug/kg
135-98-8 sec-Butylbenzene ND 5.0 1.0 ug/kg
98-06-6 tert-Butylbenzene ND 5.0 1.0 ug/kg
56-23-5 Carbon Tetrachloride ND 5.0 1.0 ug/kg
108-90-7 Chlorobenzene ND 5.0 1.0 ug/kg
75-00-3 Chloroethane ND 5.0 2.0 ug/kg
67-66-3 Chloroform ND 5.0 1.3 ug/kg
95-49-8 o-Chlorotoluene ND 5.0 1.0 ug/kg
106-43-4 p-Chlorotoluene ND 5.0 1.0 ug/kg
124-48-1 Dibromochloromethane ND 5.0 1.0 ug/kg
106-93-4 1,2-Dibromoethane ND 5.0 1.0 ug/kg
75-71-8 Dichlorodifluoromethane ND 5.0 2.0 ug/kg
95-50-1 1,2-Dichlorobenzene ND 5.0 1.0 ug/kg
541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/kg
106-46-7 1,4-Dichlorobenzene ND 5.0 1.2 ug/kg
75-34-3 1,1-Dichloroethane ND 5.0 1.8 ug/kg
107-06-2 1,2-Dichloroethane ND 5.0 1.0 ug/kg
75-35-4 1,1-Dichloroethylene ND 5.0 1.0 ug/kg
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.4 ug/kg
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.0 ug/kg
78-87-5 1,2-Dichloropropane ND 5.0 1.0 ug/kg
142-28-9 1,3-Dichloropropane ND 5.0 1.0 ug/kg
594-20-7 2,2-Dichloropropane ND 5.0 1.0 ug/kg
563-58-6 1,1-Dichloropropene ND 5.0 1.0 ug/kg
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.0 ug/kg
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.0 ug/kg
108-20-3 Di-Isopropyl Ether ND 5.0 2.3 ug/kg
64-17-5 Ethyl Alcohol ND 400 75 ug/kg
100-41-4 Ethylbenzene ND 5.0 1.0 ug/kg
81 of 123
FC287955.1.5
Method Blank Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B909-MB 2B21605.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
CAS No.Compound Result RL MDL Units Q
591-78-6 2-Hexanone ND 25 7.5 ug/kg
98-82-8 Isopropylbenzene ND 5.0 1.0 ug/kg
99-87-6 p-Isopropyltoluene ND 5.0 1.0 ug/kg
74-83-9 Methyl Bromide ND 5.0 2.0 ug/kg
74-87-3 Methyl Chloride ND 5.0 2.0 ug/kg
75-09-2 Methylene Chloride ND 20 11 ug/kg
108-10-1 4-Methyl-2-pentanone (MIBK)ND 25 7.5 ug/kg
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.0 ug/kg
91-20-3 Naphthalene ND 5.0 2.0 ug/kg
103-65-1 n-Propylbenzene ND 5.0 1.0 ug/kg
100-42-5 Styrene ND 5.0 1.0 ug/kg
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.0 ug/kg
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.0 ug/kg
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/kg
108-88-3 Toluene ND 20 10 ug/kg
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.4 ug/kg
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.0 ug/kg
71-55-6 1,1,1-Trichloroethane ND 5.0 1.0 ug/kg
79-00-5 1,1,2-Trichloroethane ND 5.0 1.0 ug/kg
79-01-6 Trichloroethylene ND 5.0 1.0 ug/kg
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/kg
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/kg
95-63-6 1,2,4-Trimethylbenzene ND 5.0 1.0 ug/kg
108-67-8 1,3,5-Trimethylbenzene ND 5.0 1.0 ug/kg
108-05-4 Vinyl Acetate ND 25 16 ug/kg
75-01-4 Vinyl Chloride ND 5.0 1.0 ug/kg
m,p-Xylene ND 10 1.1 ug/kg
95-47-6 o-Xylene ND 5.0 1.0 ug/kg
1330-20-7 Xylene (total)ND 15 2.1 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 95%75-124%
17060-07-0 1,2-Dichloroethane-D4 102%72-135%
2037-26-5 Toluene-D8 109%75-126%
82 of 123
FC287955.1.5
Method Blank Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B909-MB 2B21605.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 108%71-133%
83 of 123
FC287955.1.5
Method Blank Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C945-MB 3C185616.D 1 03/04/23 AL n/a n/a V3C945
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7
CAS No.Compound Result RL MDL Units Q
108-88-3 Toluene ND 20 10 ug/kg
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%75-124%
17060-07-0 1,2-Dichloroethane-D4 110%72-135%
2037-26-5 Toluene-D8 100%75-126%
460-00-4 4-Bromofluorobenzene 95%71-133%
84 of 123
FC287955.1.6
Blank Spike Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C939-BS 3C185447.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 285 114 61-152
71-43-2 Benzene 50 48.9 98 76-126
108-86-1 Bromobenzene 50 52.4 105 76-122
74-97-5 Bromochloromethane 50 51.2 102 77-120
75-27-4 Bromodichloromethane 50 47.2 94 74-130
75-25-2 Bromoform 50 49.1 98 76-127
78-93-3 2-Butanone (MEK)250 246 98 75-137
104-51-8 n-Butylbenzene 50 50.9 102 71-128
135-98-8 sec-Butylbenzene 50 47.2 94 79-135
98-06-6 tert-Butylbenzene 50 47.9 96 77-133
56-23-5 Carbon Tetrachloride 50 49.8 100 78-133
108-90-7 Chlorobenzene 50 53.2 106 81-129
75-00-3 Chloroethane 50 30.0 60* a 68-133
67-66-3 Chloroform 50 49.0 98 72-123
95-49-8 o-Chlorotoluene 50 48.4 97 77-129
106-43-4 p-Chlorotoluene 50 47.5 95 80-134
124-48-1 Dibromochloromethane 50 55.9 112 76-127
106-93-4 1,2-Dibromoethane 50 53.8 108 77-126
75-71-8 Dichlorodifluoromethane 50 74.2 148 68-168
95-50-1 1,2-Dichlorobenzene 50 49.6 99 80-129
541-73-1 1,3-Dichlorobenzene 50 49.4 99 81-129
106-46-7 1,4-Dichlorobenzene 50 50.0 100 76-130
75-34-3 1,1-Dichloroethane 50 46.9 94 73-125
107-06-2 1,2-Dichloroethane 50 48.7 97 74-128
75-35-4 1,1-Dichloroethylene 50 47.9 96 81-136
156-59-2 cis-1,2-Dichloroethylene 50 48.0 96 74-126
156-60-5 trans-1,2-Dichloroethylene 50 47.7 95 70-127
78-87-5 1,2-Dichloropropane 50 49.9 100 74-125
142-28-9 1,3-Dichloropropane 50 52.6 105 76-122
594-20-7 2,2-Dichloropropane 50 51.0 102 77-133
563-58-6 1,1-Dichloropropene 50 50.3 101 75-130
10061-01-5 cis-1,3-Dichloropropene 50 49.8 100 80-123
10061-02-6 trans-1,3-Dichloropropene 50 49.8 100 75-131
108-20-3 Di-Isopropyl Ether 50 47.0 94 75-122
64-17-5 Ethyl Alcohol 1000 1120 112 53-154
100-41-4 Ethylbenzene 50 52.6 105 77-123
* = Outside of Control Limits.
85 of 123
FC287955.2.1
Blank Spike Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C939-BS 3C185447.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
591-78-6 2-Hexanone 250 264 106 72-133
98-82-8 Isopropylbenzene 50 52.7 105 80-136
99-87-6 p-Isopropyltoluene 50 47.6 95 77-131
74-83-9 Methyl Bromide 50 55.9 112 65-139
74-87-3 Methyl Chloride 50 50.8 102 71-144
75-09-2 Methylene Chloride 50 47.8 96 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 272 109 76-132
1634-04-4 Methyl Tert Butyl Ether 50 53.6 107 77-120
91-20-3 Naphthalene 50 52.6 105 79-129
103-65-1 n-Propylbenzene 50 48.5 97 80-135
100-42-5 Styrene 50 54.9 110 78-125
630-20-6 1,1,1,2-Tetrachloroethane 50 54.5 109 78-126
79-34-5 1,1,2,2-Tetrachloroethane 50 49.9 100 71-126
127-18-4 Tetrachloroethylene 50 56.1 112 79-130
108-88-3 Toluene 50 52.5 105 76-124
87-61-6 1,2,3-Trichlorobenzene 50 52.1 104 77-128
120-82-1 1,2,4-Trichlorobenzene 50 52.2 104 78-130
71-55-6 1,1,1-Trichloroethane 50 50.1 100 70-129
79-00-5 1,1,2-Trichloroethane 50 52.2 104 74-124
79-01-6 Trichloroethylene 50 49.3 99 75-128
75-69-4 Trichlorofluoromethane 50 53.4 107 73-145
96-18-4 1,2,3-Trichloropropane 50 53.6 107 74-127
95-63-6 1,2,4-Trimethylbenzene 50 49.0 98 74-123
108-67-8 1,3,5-Trimethylbenzene 50 50.1 100 73-122
108-05-4 Vinyl Acetate 250 260 104 48-164
75-01-4 Vinyl Chloride 50 52.9 106 76-141
m,p-Xylene 100 107 107 80-128
95-47-6 o-Xylene 50 52.1 104 80-132
1330-20-7 Xylene (total)150 159 106 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 97%75-124%
17060-07-0 1,2-Dichloroethane-D4 99%72-135%
2037-26-5 Toluene-D8 106%75-126%
* = Outside of Control Limits.
86 of 123
FC287955.2.1
Blank Spike Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C939-BS 3C185447.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 97%71-133%
(a) Sporadic marginal failure.
* = Outside of Control Limits.
87 of 123
FC287955.2.1
Blank Spike Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C941-BS 3C185501.D 1 02/28/23 DB n/a n/a V3C941
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 101%75-124%
17060-07-0 1,2-Dichloroethane-D4 103%72-135%
2037-26-5 Toluene-D8 103%75-126%
460-00-4 4-Bromofluorobenzene 96%71-133%
* = Outside of Control Limits.
88 of 123
FC287955.2.2
Blank Spike Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B907-BS a 2B21543.D 1 03/01/23 AL n/a n/a V2B907
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-4, FC2879-5
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 292 117 61-152
71-43-2 Benzene 50 51.2 102 76-126
108-86-1 Bromobenzene 50 45.6 91 76-122
74-97-5 Bromochloromethane 50 50.8 102 77-120
75-27-4 Bromodichloromethane 50 55.6 111 74-130
75-25-2 Bromoform 50 52.6 105 76-127
78-93-3 2-Butanone (MEK)250 269 108 75-137
104-51-8 n-Butylbenzene 50 47.7 95 71-128
135-98-8 sec-Butylbenzene 50 47.4 95 79-135
98-06-6 tert-Butylbenzene 50 46.9 94 77-133
56-23-5 Carbon Tetrachloride 50 58.2 116 78-133
108-90-7 Chlorobenzene 50 50.3 101 81-129
75-00-3 Chloroethane 50 69.2 138*68-133
67-66-3 Chloroform 50 52.2 104 72-123
95-49-8 o-Chlorotoluene 50 46.8 94 77-129
106-43-4 p-Chlorotoluene 50 46.0 92 80-134
124-48-1 Dibromochloromethane 50 52.0 104 76-127
106-93-4 1,2-Dibromoethane 50 49.2 98 77-126
75-71-8 Dichlorodifluoromethane 50 77.9 156 68-168
95-50-1 1,2-Dichlorobenzene 50 45.8 92 80-129
541-73-1 1,3-Dichlorobenzene 50 46.2 92 81-129
106-46-7 1,4-Dichlorobenzene 50 48.0 96 76-130
75-34-3 1,1-Dichloroethane 50 52.9 106 73-125
107-06-2 1,2-Dichloroethane 50 51.1 102 74-128
75-35-4 1,1-Dichloroethylene 50 55.9 112 81-136
156-59-2 cis-1,2-Dichloroethylene 50 51.3 103 74-126
156-60-5 trans-1,2-Dichloroethylene 50 55.9 112 70-127
78-87-5 1,2-Dichloropropane 50 51.2 102 74-125
142-28-9 1,3-Dichloropropane 50 48.1 96 76-122
594-20-7 2,2-Dichloropropane 50 55.2 110 77-133
563-58-6 1,1-Dichloropropene 50 51.6 103 75-130
10061-01-5 cis-1,3-Dichloropropene 50 54.3 109 80-123
10061-02-6 trans-1,3-Dichloropropene 50 52.6 105 75-131
108-20-3 Di-Isopropyl Ether 50 54.2 108 75-122
64-17-5 Ethyl Alcohol 1000 1140 114 53-154
100-41-4 Ethylbenzene 50 51.1 102 77-123
* = Outside of Control Limits.
89 of 123
FC287955.2.3
Blank Spike Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B907-BS a 2B21543.D 1 03/01/23 AL n/a n/a V2B907
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-4, FC2879-5
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
591-78-6 2-Hexanone 250 262 105 72-133
98-82-8 Isopropylbenzene 50 50.0 100 80-136
99-87-6 p-Isopropyltoluene 50 47.7 95 77-131
74-83-9 Methyl Bromide 50 69.8 140*65-139
74-87-3 Methyl Chloride 50 64.2 128 71-144
75-09-2 Methylene Chloride 50 49.6 99 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 261 104 76-132
1634-04-4 Methyl Tert Butyl Ether 50 54.2 108 77-120
91-20-3 Naphthalene 50 46.1 92 79-129
103-65-1 n-Propylbenzene 50 46.8 94 80-135
100-42-5 Styrene 50 51.8 104 78-125
630-20-6 1,1,1,2-Tetrachloroethane 50 52.6 105 78-126
79-34-5 1,1,2,2-Tetrachloroethane 50 46.6 93 71-126
127-18-4 Tetrachloroethylene 50 49.4 99 79-130
108-88-3 Toluene 50 47.8 96 76-124
87-61-6 1,2,3-Trichlorobenzene 50 45.7 91 77-128
120-82-1 1,2,4-Trichlorobenzene 50 47.7 95 78-130
71-55-6 1,1,1-Trichloroethane 50 55.0 110 70-129
79-00-5 1,1,2-Trichloroethane 50 48.8 98 74-124
79-01-6 Trichloroethylene 50 51.1 102 75-128
75-69-4 Trichlorofluoromethane 50 63.9 128 73-145
96-18-4 1,2,3-Trichloropropane 50 45.1 90 74-127
95-63-6 1,2,4-Trimethylbenzene 50 48.4 97 74-123
108-67-8 1,3,5-Trimethylbenzene 50 47.3 95 73-122
108-05-4 Vinyl Acetate 250 297 119 48-164
75-01-4 Vinyl Chloride 50 65.1 130 76-141
m,p-Xylene 100 108 108 80-128
95-47-6 o-Xylene 50 49.8 100 80-132
1330-20-7 Xylene (total)150 158 105 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 105%75-124%
17060-07-0 1,2-Dichloroethane-D4 103%72-135%
2037-26-5 Toluene-D8 96%75-126%
* = Outside of Control Limits.
90 of 123
FC287955.2.3
Blank Spike Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B907-BS a 2B21543.D 1 03/01/23 AL n/a n/a V2B907
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-4, FC2879-5
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 90%71-133%
(a) No MS/MSD available for this run.
* = Outside of Control Limits.
91 of 123
FC287955.2.3
Blank Spike Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C943-BS 3C185557.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 274 110 61-152
71-43-2 Benzene 50 47.1 94 76-126
108-86-1 Bromobenzene 50 49.4 99 76-122
74-97-5 Bromochloromethane 50 51.2 102 77-120
75-27-4 Bromodichloromethane 50 52.0 104 74-130
75-25-2 Bromoform 50 51.7 103 76-127
78-93-3 2-Butanone (MEK)250 240 96 75-137
104-51-8 n-Butylbenzene 50 48.5 97 71-128
135-98-8 sec-Butylbenzene 50 49.0 98 79-135
98-06-6 tert-Butylbenzene 50 50.1 100 77-133
56-23-5 Carbon Tetrachloride 50 53.9 108 78-133
108-90-7 Chlorobenzene 50 51.2 102 81-129
75-00-3 Chloroethane 50 32.2 64* a 68-133
67-66-3 Chloroform 50 50.8 102 72-123
95-49-8 o-Chlorotoluene 50 48.5 97 77-129
106-43-4 p-Chlorotoluene 50 47.7 95 80-134
124-48-1 Dibromochloromethane 50 55.4 111 76-127
106-93-4 1,2-Dibromoethane 50 52.5 105 77-126
75-71-8 Dichlorodifluoromethane 50 45.8 92 68-168
95-50-1 1,2-Dichlorobenzene 50 50.2 100 80-129
541-73-1 1,3-Dichlorobenzene 50 50.2 100 81-129
106-46-7 1,4-Dichlorobenzene 50 49.0 98 76-130
75-34-3 1,1-Dichloroethane 50 48.4 97 73-125
107-06-2 1,2-Dichloroethane 50 52.0 104 74-128
75-35-4 1,1-Dichloroethylene 50 48.4 97 81-136
156-59-2 cis-1,2-Dichloroethylene 50 48.8 98 74-126
156-60-5 trans-1,2-Dichloroethylene 50 48.4 97 70-127
78-87-5 1,2-Dichloropropane 50 46.5 93 74-125
142-28-9 1,3-Dichloropropane 50 47.9 96 76-122
594-20-7 2,2-Dichloropropane 50 50.0 100 77-133
563-58-6 1,1-Dichloropropene 50 49.8 100 75-130
10061-01-5 cis-1,3-Dichloropropene 50 49.7 99 80-123
10061-02-6 trans-1,3-Dichloropropene 50 52.9 106 75-131
108-20-3 Di-Isopropyl Ether 50 48.5 97 75-122
64-17-5 Ethyl Alcohol 1000 985 99 53-154
100-41-4 Ethylbenzene 50 50.6 101 77-123
* = Outside of Control Limits.
92 of 123
FC287955.2.4
Blank Spike Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C943-BS 3C185557.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
591-78-6 2-Hexanone 250 250 100 72-133
98-82-8 Isopropylbenzene 50 51.9 104 80-136
99-87-6 p-Isopropyltoluene 50 48.4 97 77-131
74-83-9 Methyl Bromide 50 47.9 96 65-139
74-87-3 Methyl Chloride 50 45.4 91 71-144
75-09-2 Methylene Chloride 50 46.1 92 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 269 108 76-132
1634-04-4 Methyl Tert Butyl Ether 50 50.0 100 77-120
91-20-3 Naphthalene 50 52.1 104 79-129
103-65-1 n-Propylbenzene 50 48.0 96 80-135
100-42-5 Styrene 50 51.9 104 78-125
630-20-6 1,1,1,2-Tetrachloroethane 50 55.2 110 78-126
79-34-5 1,1,2,2-Tetrachloroethane 50 48.5 97 71-126
127-18-4 Tetrachloroethylene 50 53.3 107 79-130
108-88-3 Toluene 50 49.2 98 76-124
87-61-6 1,2,3-Trichlorobenzene 50 52.0 104 77-128
120-82-1 1,2,4-Trichlorobenzene 50 53.4 107 78-130
71-55-6 1,1,1-Trichloroethane 50 53.3 107 70-129
79-00-5 1,1,2-Trichloroethane 50 50.7 101 74-124
79-01-6 Trichloroethylene 50 50.3 101 75-128
75-69-4 Trichlorofluoromethane 50 50.9 102 73-145
96-18-4 1,2,3-Trichloropropane 50 49.0 98 74-127
95-63-6 1,2,4-Trimethylbenzene 50 48.6 97 74-123
108-67-8 1,3,5-Trimethylbenzene 50 48.6 97 73-122
108-05-4 Vinyl Acetate 250 321 128 48-164
75-01-4 Vinyl Chloride 50 44.3 89 76-141
m,p-Xylene 100 103 103 80-128
95-47-6 o-Xylene 50 51.6 103 80-132
1330-20-7 Xylene (total)150 155 103 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 104%75-124%
17060-07-0 1,2-Dichloroethane-D4 107%72-135%
2037-26-5 Toluene-D8 101%75-126%
* = Outside of Control Limits.
93 of 123
FC287955.2.4
Blank Spike Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C943-BS 3C185557.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 97%71-133%
(a) Sporadic marginal failure.
* = Outside of Control Limits.
94 of 123
FC287955.2.4
Blank Spike Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B909-BS 2B21603.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
67-64-1 Acetone 250 286 114 61-152
71-43-2 Benzene 50 52.6 105 76-126
108-86-1 Bromobenzene 50 51.5 103 76-122
74-97-5 Bromochloromethane 50 53.5 107 77-120
75-27-4 Bromodichloromethane 50 56.4 113 74-130
75-25-2 Bromoform 50 53.7 107 76-127
78-93-3 2-Butanone (MEK)250 268 107 75-137
104-51-8 n-Butylbenzene 50 52.9 106 71-128
135-98-8 sec-Butylbenzene 50 52.3 105 79-135
98-06-6 tert-Butylbenzene 50 52.2 104 77-133
56-23-5 Carbon Tetrachloride 50 54.8 110 78-133
108-90-7 Chlorobenzene 50 52.3 105 81-129
75-00-3 Chloroethane 50 68.0 136*68-133
67-66-3 Chloroform 50 53.4 107 72-123
95-49-8 o-Chlorotoluene 50 52.7 105 77-129
106-43-4 p-Chlorotoluene 50 51.8 104 80-134
124-48-1 Dibromochloromethane 50 52.4 105 76-127
106-93-4 1,2-Dibromoethane 50 52.9 106 77-126
75-71-8 Dichlorodifluoromethane 50 75.9 152 68-168
95-50-1 1,2-Dichlorobenzene 50 51.5 103 80-129
541-73-1 1,3-Dichlorobenzene 50 51.6 103 81-129
106-46-7 1,4-Dichlorobenzene 50 52.6 105 76-130
75-34-3 1,1-Dichloroethane 50 53.2 106 73-125
107-06-2 1,2-Dichloroethane 50 54.2 108 74-128
75-35-4 1,1-Dichloroethylene 50 56.5 113 81-136
156-59-2 cis-1,2-Dichloroethylene 50 52.1 104 74-126
156-60-5 trans-1,2-Dichloroethylene 50 56.5 113 70-127
78-87-5 1,2-Dichloropropane 50 53.4 107 74-125
142-28-9 1,3-Dichloropropane 50 50.8 102 76-122
594-20-7 2,2-Dichloropropane 50 55.3 111 77-133
563-58-6 1,1-Dichloropropene 50 52.1 104 75-130
10061-01-5 cis-1,3-Dichloropropene 50 55.1 110 80-123
10061-02-6 trans-1,3-Dichloropropene 50 56.1 112 75-131
108-20-3 Di-Isopropyl Ether 50 54.7 109 75-122
64-17-5 Ethyl Alcohol 1000 1180 118 53-154
100-41-4 Ethylbenzene 50 52.8 106 77-123
* = Outside of Control Limits.
95 of 123
FC287955.2.5
Blank Spike Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B909-BS 2B21603.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
591-78-6 2-Hexanone 250 272 109 72-133
98-82-8 Isopropylbenzene 50 51.9 104 80-136
99-87-6 p-Isopropyltoluene 50 53.2 106 77-131
74-83-9 Methyl Bromide 50 66.8 134 65-139
74-87-3 Methyl Chloride 50 63.0 126 71-144
75-09-2 Methylene Chloride 50 51.1 102 74-137
108-10-1 4-Methyl-2-pentanone (MIBK)250 270 108 76-132
1634-04-4 Methyl Tert Butyl Ether 50 55.2 110 77-120
91-20-3 Naphthalene 50 53.2 106 79-129
103-65-1 n-Propylbenzene 50 51.8 104 80-135
100-42-5 Styrene 50 52.3 105 78-125
630-20-6 1,1,1,2-Tetrachloroethane 50 55.1 110 78-126
79-34-5 1,1,2,2-Tetrachloroethane 50 53.0 106 71-126
127-18-4 Tetrachloroethylene 50 50.7 101 79-130
108-88-3 Toluene 50 50.1 100 76-124
87-61-6 1,2,3-Trichlorobenzene 50 52.5 105 77-128
120-82-1 1,2,4-Trichlorobenzene 50 53.1 106 78-130
71-55-6 1,1,1-Trichloroethane 50 53.8 108 70-129
79-00-5 1,1,2-Trichloroethane 50 51.5 103 74-124
79-01-6 Trichloroethylene 50 52.7 105 75-128
75-69-4 Trichlorofluoromethane 50 63.9 128 73-145
96-18-4 1,2,3-Trichloropropane 50 51.9 104 74-127
95-63-6 1,2,4-Trimethylbenzene 50 54.0 108 74-123
108-67-8 1,3,5-Trimethylbenzene 50 52.9 106 73-122
108-05-4 Vinyl Acetate 250 312 125 48-164
75-01-4 Vinyl Chloride 50 66.7 133 76-141
m,p-Xylene 100 107 107 80-128
95-47-6 o-Xylene 50 52.1 104 80-132
1330-20-7 Xylene (total)150 160 107 80-129
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 102%75-124%
17060-07-0 1,2-Dichloroethane-D4 106%72-135%
2037-26-5 Toluene-D8 95%75-126%
* = Outside of Control Limits.
96 of 123
FC287955.2.5
Blank Spike Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V2B909-BS 2B21603.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 96%71-133%
* = Outside of Control Limits.
97 of 123
FC287955.2.5
Blank Spike Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3C945-BS 3C185614.D 1 03/04/23 AL n/a n/a V3C945
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7
Spike BSP BSP
CAS No.Compound ug/kg ug/kg %Limits
108-88-3 Toluene 50 54.0 108 76-124
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 104%75-124%
17060-07-0 1,2-Dichloroethane-D4 104%72-135%
2037-26-5 Toluene-D8 101%75-126%
460-00-4 4-Bromofluorobenzene 98%71-133%
* = Outside of Control Limits.
98 of 123
FC287955.2.6
Matrix Spike Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2958-14MS 3C185638.D 1 03/04/23 AL n/a n/a V3C945
FC2958-14 a 3C185621.D 1 03/04/23 AL n/a n/a V3C945
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7
FC2958-14 Spike MS MS
CAS No.Compound ug/kg Q ug/kg ug/kg %Limits
108-88-3 Toluene ND 48.3 49.6 103 76-124
CAS No.Surrogate Recoveries MS FC2958-14 Limits
1868-53-7 Dibromofluoromethane 99%99%75-124%
17060-07-0 1,2-Dichloroethane-D4 97%112%72-135%
2037-26-5 Toluene-D8 103%101%75-126%
460-00-4 4-Bromofluorobenzene 97%94%71-133%
(a) Confirmation run.
* = Outside of Control Limits.
99 of 123
FC287955.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2909-1MS 3C185468.D 1 02/24/23 AL n/a n/a V3C939
FC2909-1MSD 3C185469.D 1 02/24/23 AL n/a n/a V3C939
FC2909-1 3C185454.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
FC2909-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone ND 290 247 85 274 209 76 17 61-152/27
71-43-2 Benzene ND 57.9 47.1 81 54.9 40.9 75*14 76-126/26
108-86-1 Bromobenzene ND 57.9 37.2 64*54.9 30.6 56*19 76-122/32
74-97-5 Bromochloromethane ND 57.9 49.8 86 54.9 43.7 80 13 77-120/24
75-27-4 Bromodichloromethane ND 57.9 43.0 74 54.9 37.8 69*13 74-130/25
75-25-2 Bromoform ND 57.9 37.4 65*54.9 33.6 61*11 76-127/26
78-93-3 2-Butanone (MEK)ND 290 228 79 274 197 72*15 75-137/25
104-51-8 n-Butylbenzene ND 57.9 28.2 49*54.9 23.0 42*20 71-128/35
135-98-8 sec-Butylbenzene ND 57.9 31.9 55*54.9 26.6 48*18 79-135/34
98-06-6 tert-Butylbenzene ND 57.9 36.5 63*54.9 30.6 56*18 77-133/34
56-23-5 Carbon Tetrachloride ND 57.9 45.7 79 54.9 40.3 73*13 78-133/29
108-90-7 Chlorobenzene ND 57.9 41.5 72*54.9 35.2 64*16 81-129/29
75-00-3 Chloroethane ND 57.9 35.2 61*54.9 34.2 62*3 68-133/29
67-66-3 Chloroform ND 57.9 48.6 84 54.9 43.2 79 12 72-123/26
95-49-8 o-Chlorotoluene ND 57.9 34.3 59*54.9 28.4 52*19 77-129/33
106-43-4 p-Chlorotoluene ND 57.9 31.0 54*54.9 25.5 46*19 80-134/33
124-48-1 Dibromochloromethane ND 57.9 47.1 81 54.9 39.8 73*17 76-127/27
106-93-4 1,2-Dibromoethane ND 57.9 48.3 83 54.9 42.2 77 13 77-126/26
75-71-8 Dichlorodifluoromethane ND 57.9 81.8 141 54.9 71.6 130 13 68-168/29
95-50-1 1,2-Dichlorobenzene ND 57.9 28.6 49*54.9 23.2 42*21 80-129/32
541-73-1 1,3-Dichlorobenzene ND 57.9 27.7 48*54.9 22.8 42*19 81-129/33
106-46-7 1,4-Dichlorobenzene ND 57.9 27.9 48*54.9 22.9 42*20 76-130/32
75-34-3 1,1-Dichloroethane ND 57.9 47.6 82 54.9 42.2 77 12 73-125/27
107-06-2 1,2-Dichloroethane ND 57.9 48.2 83 54.9 42.2 77 13 74-128/23
75-35-4 1,1-Dichloroethylene ND 57.9 48.8 84 54.9 43.1 79*12 81-136/28
156-59-2 cis-1,2-Dichloroethylene ND 57.9 46.9 81 54.9 41.3 75 13 74-126/26
156-60-5 trans-1,2-Dichloroethylene ND 57.9 47.7 82 54.9 41.4 75 14 70-127/27
78-87-5 1,2-Dichloropropane ND 57.9 49.4 85 54.9 42.7 78 15 74-125/25
142-28-9 1,3-Dichloropropane ND 57.9 52.5 91 54.9 45.1 82 15 76-122/26
594-20-7 2,2-Dichloropropane ND 57.9 51.9 90 54.9 45.5 83 13 77-133/28
563-58-6 1,1-Dichloropropene ND 57.9 45.8 79 54.9 39.8 73*14 75-130/28
10061-01-5 cis-1,3-Dichloropropene ND 57.9 43.1 74*54.9 37.5 68*14 80-123/26
10061-02-6 trans-1,3-Dichloropropene ND 57.9 41.8 72*54.9 35.7 65*16 75-131/28
108-20-3 Di-Isopropyl Ether ND 57.9 48.8 84 54.9 42.8 78 13 75-122/25
64-17-5 Ethyl Alcohol ND 1160 1330 115 1100 1220 111 9 53-154/42
100-41-4 Ethylbenzene ND 57.9 43.2 75*54.9 36.9 67*16 77-123/31
* = Outside of Control Limits.
100 of 123
FC287955.4.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2909-1MS 3C185468.D 1 02/24/23 AL n/a n/a V3C939
FC2909-1MSD 3C185469.D 1 02/24/23 AL n/a n/a V3C939
FC2909-1 3C185454.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
FC2909-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
591-78-6 2-Hexanone ND 290 219 76 274 184 67*17 72-133/26
98-82-8 Isopropylbenzene ND 57.9 42.0 73*54.9 35.0 64*18 80-136/32
99-87-6 p-Isopropyltoluene ND 57.9 31.4 54*54.9 25.8 47*20 77-131/34
74-83-9 Methyl Bromide ND 57.9 60.0 104 54.9 48.3 88 22 65-139/31
74-87-3 Methyl Chloride ND 57.9 56.1 97 54.9 51.2 93 9 71-144/27
75-09-2 Methylene Chloride ND 57.9 77.0 133 54.9 69.6 127 10 74-137/28
108-10-1 4-Methyl-2-pentanone (MIBK)ND 290 259 89 274 224 82 14 76-132/26
1634-04-4 Methyl Tert Butyl Ether ND 57.9 54.2 94 54.9 47.9 87 12 77-120/24
91-20-3 Naphthalene ND 57.9 21.3 37*54.9 17.3 32*21 79-129/33
103-65-1 n-Propylbenzene ND 57.9 35.0 60*54.9 29.0 53*19 80-135/33
100-42-5 Styrene ND 57.9 38.2 66*54.9 31.4 57*20 78-125/30
630-20-6 1,1,1,2-Tetrachloroethane ND 57.9 48.0 83 54.9 40.6 74*17 78-126/27
79-34-5 1,1,2,2-Tetrachloroethane ND 57.9 43.1 74 54.9 37.0 67*15 71-126/30
127-18-4 Tetrachloroethylene ND 57.9 44.4 77*54.9 37.4 68*17 79-130/31
108-88-3 Toluene ND 57.9 46.4 80 54.9 39.7 72*16 76-124/30
87-61-6 1,2,3-Trichlorobenzene ND 57.9 19.4 33*54.9 15.6 28*22 77-128/35
120-82-1 1,2,4-Trichlorobenzene ND 57.9 19.2 33*54.9 14.8 27*26 78-130/34
71-55-6 1,1,1-Trichloroethane ND 57.9 49.9 86 54.9 42.7 78 16 70-129/27
79-00-5 1,1,2-Trichloroethane ND 57.9 49.6 86 54.9 43.9 80 12 74-124/28
79-01-6 Trichloroethylene ND 57.9 44.8 77 54.9 38.1 69*16 75-128/27
75-69-4 Trichlorofluoromethane ND 57.9 51.2 88 54.9 45.7 83 11 73-145/31
96-18-4 1,2,3-Trichloropropane ND 57.9 47.0 81 54.9 40.4 74 15 74-127/27
95-63-6 1,2,4-Trimethylbenzene ND 57.9 34.4 59*54.9 28.5 52*19 74-123/34
108-67-8 1,3,5-Trimethylbenzene ND 57.9 36.7 63*54.9 30.2 55*19 73-122/33
108-05-4 Vinyl Acetate ND 290 ND 0*274 ND 0*nc 48-164/37
75-01-4 Vinyl Chloride ND 57.9 55.6 96 54.9 50.4 92 10 76-141/27
m,p-Xylene ND 116 85.7 74*110 72.0 66*17 80-128/30
95-47-6 o-Xylene ND 57.9 42.7 74*54.9 35.4 65*19 80-132/30
1330-20-7 Xylene (total)ND 174 128 74*165 107 65*18 80-129/30
CAS No.Surrogate Recoveries MS MSD FC2909-1 Limits
1868-53-7 Dibromofluoromethane 96%98%96%75-124%
17060-07-0 1,2-Dichloroethane-D4 100%100%109%72-135%
2037-26-5 Toluene-D8 103%103%104%75-126%
* = Outside of Control Limits.
101 of 123
FC287955.4.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2909-1MS 3C185468.D 1 02/24/23 AL n/a n/a V3C939
FC2909-1MSD 3C185469.D 1 02/24/23 AL n/a n/a V3C939
FC2909-1 3C185454.D 1 02/24/23 AL n/a n/a V3C939
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-2, FC2879-3
CAS No.Surrogate Recoveries MS MSD FC2909-1 Limits
460-00-4 4-Bromofluorobenzene 98%98%98%71-133%
* = Outside of Control Limits.
102 of 123
FC287955.4.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2913-10MS 3C185524.D 1 03/01/23 DB n/a n/a V3C941
FC2913-10MSD 3C185525.D 1 03/01/23 DB n/a n/a V3C941
FC2913-10 3C185508.D 1 02/28/23 DB n/a n/a V3C941
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1
FC2913-10 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
CAS No.Surrogate Recoveries MS MSD FC2913-10 Limits
1868-53-7 Dibromofluoromethane 103%102%102%75-124%
17060-07-0 1,2-Dichloroethane-D4 107%108%112%72-135%
2037-26-5 Toluene-D8 103%102%103%75-126%
460-00-4 4-Bromofluorobenzene 97%96%95%71-133%
* = Outside of Control Limits.
103 of 123
FC287955.4.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3064-2MS 3C185579.D 1 03/02/23 AL n/a n/a V3C943
FC3064-2MSD 3C185580.D 1 03/02/23 AL n/a n/a V3C943
FC3064-2 3C185561.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
FC3064-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone 140 U 256 257 100 259 259 100 1 61-152/27
71-43-2 Benzene 3.5 U 51.3 43.4 85 51.8 48.1 93 10 76-126/26
108-86-1 Bromobenzene 3.5 U 51.3 40.6 79 51.8 45.7 88 12 76-122/32
74-97-5 Bromochloromethane 3.5 U 51.3 48.0 94 51.8 52.3 101 9 77-120/24
75-27-4 Bromodichloromethane 3.5 U 51.3 45.7 89 51.8 50.6 98 10 74-130/25
75-25-2 Bromoform 3.5 U 51.3 42.0 82 51.8 47.6 92 13 76-127/26
78-93-3 2-Butanone (MEK)18 U 256 226 88 259 237 92 5 75-137/25
104-51-8 n-Butylbenzene 3.5 U 51.3 34.0 66*51.8 37.5 72 10 71-128/35
135-98-8 sec-Butylbenzene 3.5 U 51.3 36.2 71*51.8 40.3 78*11 79-135/34
98-06-6 tert-Butylbenzene 3.5 U 51.3 37.9 74*51.8 42.3 82 11 77-133/34
56-23-5 Carbon Tetrachloride 3.5 U 51.3 45.7 89 51.8 51.9 100 13 78-133/29
108-90-7 Chlorobenzene 3.5 U 51.3 44.7 87 51.8 49.5 96 10 81-129/29
75-00-3 Chloroethane 3.5 U 51.3 35.4 69 51.8 35.1 68 1 68-133/29
67-66-3 Chloroform 3.5 U 51.3 47.1 92 51.8 51.2 99 8 72-123/26
95-49-8 o-Chlorotoluene 3.5 U 51.3 38.6 75*51.8 42.5 82 10 77-129/33
106-43-4 p-Chlorotoluene 3.5 U 51.3 38.1 74*51.8 41.5 80 9 80-134/33
124-48-1 Dibromochloromethane 3.5 U 51.3 47.1 92 51.8 52.8 102 11 76-127/27
106-93-4 1,2-Dibromoethane 3.5 U 51.3 48.1 94 51.8 51.7 100 7 77-126/26
75-71-8 Dichlorodifluoromethane 3.5 U 51.3 39.4 77 51.8 44.6 86 12 68-168/29
95-50-1 1,2-Dichlorobenzene 3.5 U 51.3 37.2 73*51.8 40.7 79*9 80-129/32
541-73-1 1,3-Dichlorobenzene 3.5 U 51.3 37.1 72*51.8 41.4 80*11 81-129/33
106-46-7 1,4-Dichlorobenzene 3.5 U 51.3 37.7 74*51.8 40.8 79 8 76-130/32
75-34-3 1,1-Dichloroethane 3.5 U 51.3 44.7 87 51.8 49.6 96 10 73-125/27
107-06-2 1,2-Dichloroethane 3.5 U 51.3 48.1 94 51.8 51.9 100 8 74-128/23
75-35-4 1,1-Dichloroethylene 3.5 U 51.3 43.2 84 51.8 48.4 94 11 81-136/28
156-59-2 cis-1,2-Dichloroethylene 3.5 U 51.3 45.1 88 51.8 49.4 95 9 74-126/26
156-60-5 trans-1,2-Dichloroethylene 3.5 U 51.3 44.3 86 51.8 48.2 93 8 70-127/27
78-87-5 1,2-Dichloropropane 3.5 U 51.3 43.6 85 51.8 48.0 93 10 74-125/25
142-28-9 1,3-Dichloropropane 3.5 U 51.3 43.5 85 51.8 48.2 93 10 76-122/26
594-20-7 2,2-Dichloropropane 3.5 U 51.3 41.9 82 51.8 47.3 91 12 77-133/28
563-58-6 1,1-Dichloropropene 3.5 U 51.3 44.3 86 51.8 48.9 94 10 75-130/28
10061-01-5 cis-1,3-Dichloropropene 3.5 U 51.3 44.7 87 51.8 49.3 95 10 80-123/26
10061-02-6 trans-1,3-Dichloropropene 3.5 U 51.3 46.3 90 51.8 51.5 100 11 75-131/28
108-20-3 Di-Isopropyl Ether 3.5 U 51.3 44.2 86 51.8 49.4 95 11 75-122/25
64-17-5 Ethyl Alcohol 280 U 1030 1160 113 1040 1240 120 7 53-154/42
100-41-4 Ethylbenzene 3.5 U 51.3 43.9 86 51.8 48.7 94 10 77-123/31
* = Outside of Control Limits.
104 of 123
FC287955.4.3
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3064-2MS 3C185579.D 1 03/02/23 AL n/a n/a V3C943
FC3064-2MSD 3C185580.D 1 03/02/23 AL n/a n/a V3C943
FC3064-2 3C185561.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
FC3064-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
591-78-6 2-Hexanone 18 U 256 224 87 259 244 94 9 72-133/26
98-82-8 Isopropylbenzene 3.5 U 51.3 42.3 83 51.8 46.6 90 10 80-136/32
99-87-6 p-Isopropyltoluene 3.5 U 51.3 35.8 70*51.8 39.4 76*10 77-131/34
74-83-9 Methyl Bromide 3.5 U 51.3 46.5 91 51.8 52.2 101 12 65-139/31
74-87-3 Methyl Chloride 3.5 U 51.3 41.4 81 51.8 44.8 87 8 71-144/27
75-09-2 Methylene Chloride 14 U 51.3 49.8 97 51.8 52.5 101 5 74-137/28
108-10-1 4-Methyl-2-pentanone (MIBK)18 U 256 251 98 259 270 104 7 76-132/26
1634-04-4 Methyl Tert Butyl Ether 3.5 U 51.3 45.1 88 51.8 51.1 99 12 77-120/24
91-20-3 Naphthalene 3.5 U 51.3 34.4 67*51.8 37.6 73*9 79-129/33
103-65-1 n-Propylbenzene 3.5 U 51.3 37.8 74*51.8 42.1 81 11 80-135/33
100-42-5 Styrene 3.5 U 51.3 43.7 85 51.8 48.4 94 10 78-125/30
630-20-6 1,1,1,2-Tetrachloroethane 3.5 U 51.3 47.3 92 51.8 52.6 102 11 78-126/27
79-34-5 1,1,2,2-Tetrachloroethane 3.5 U 51.3 42.9 84 51.8 47.3 91 10 71-126/30
127-18-4 Tetrachloroethylene 3.5 U 51.3 46.7 91 51.8 50.3 97 7 79-130/31
108-88-3 Toluene 14 U 51.3 44.1 86 51.8 49.3 95 11 76-124/30
87-61-6 1,2,3-Trichlorobenzene 3.5 U 51.3 30.6 60*51.8 32.7 63*7 77-128/35
120-82-1 1,2,4-Trichlorobenzene 3.5 U 51.3 31.8 62*51.8 34.5 67*8 78-130/34
71-55-6 1,1,1-Trichloroethane 3.5 U 51.3 46.7 91 51.8 52.3 101 11 70-129/27
79-00-5 1,1,2-Trichloroethane 3.5 U 51.3 47.4 92 51.8 51.9 100 9 74-124/28
79-01-6 Trichloroethylene 3.5 U 51.3 45.9 90 51.8 49.8 96 8 75-128/27
75-69-4 Trichlorofluoromethane 3.5 U 51.3 46.1 90 51.8 50.5 98 9 73-145/31
96-18-4 1,2,3-Trichloropropane 3.5 U 51.3 43.5 85 51.8 48.6 94 11 74-127/27
95-63-6 1,2,4-Trimethylbenzene 3.5 U 51.3 37.6 73*51.8 41.7 81 10 74-123/34
108-67-8 1,3,5-Trimethylbenzene 3.5 U 51.3 38.1 74 51.8 42.2 82 10 73-122/33
108-05-4 Vinyl Acetate 18 U 256 ND 0*259 ND 0*nc 48-164/37
75-01-4 Vinyl Chloride 3.5 U 51.3 41.8 82 51.8 46.5 90 11 76-141/27
m,p-Xylene 7.0 U 103 88.5 86 104 96.4 93 9 80-128/30
95-47-6 o-Xylene 3.5 U 51.3 43.0 84 51.8 48.6 94 12 80-132/30
1330-20-7 Xylene (total)11 U 154 132 86 155 145 93 9 80-129/30
CAS No.Surrogate Recoveries MS MSD FC3064-2 Limits
1868-53-7 Dibromofluoromethane 101%100%98%75-124%
17060-07-0 1,2-Dichloroethane-D4 108%105%111%72-135%
2037-26-5 Toluene-D8 103%102%103%75-126%
* = Outside of Control Limits.
105 of 123
FC287955.4.3
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3064-2MS 3C185579.D 1 03/02/23 AL n/a n/a V3C943
FC3064-2MSD 3C185580.D 1 03/02/23 AL n/a n/a V3C943
FC3064-2 3C185561.D 1 03/02/23 AL n/a n/a V3C943
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-1, FC2879-6, FC2879-7, FC2879-10, FC2879-11
CAS No.Surrogate Recoveries MS MSD FC3064-2 Limits
460-00-4 4-Bromofluorobenzene 98%97%98%71-133%
* = Outside of Control Limits.
106 of 123
FC287955.4.3
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2964-2MS 2B21627.D 1 03/03/23 AL n/a n/a V2B909
FC2964-2MSD 2B21628.D 1 03/03/23 AL n/a n/a V2B909
FC2964-2 2B21615.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
FC2964-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
67-64-1 Acetone ND 276 216 78 284 216 76 0 61-152/27
71-43-2 Benzene ND 55.2 54.7 99 56.9 59.2 104 8 76-126/26
108-86-1 Bromobenzene ND 55.2 51.8 94 56.9 55.4 97 7 76-122/32
74-97-5 Bromochloromethane ND 55.2 53.5 97 56.9 56.6 99 6 77-120/24
75-27-4 Bromodichloromethane ND 55.2 53.9 98 56.9 60.6 107 12 74-130/25
75-25-2 Bromoform ND 55.2 41.5 75*56.9 45.8 80 10 76-127/26
78-93-3 2-Butanone (MEK)ND 276 188 68*284 193 68*3 75-137/25
104-51-8 n-Butylbenzene ND 55.2 48.1 87 56.9 53.7 94 11 71-128/35
135-98-8 sec-Butylbenzene ND 55.2 53.0 96 56.9 59.4 104 11 79-135/34
98-06-6 tert-Butylbenzene ND 55.2 55.2 100 56.9 60.5 106 9 77-133/34
56-23-5 Carbon Tetrachloride ND 55.2 57.2 104 56.9 61.4 108 7 78-133/29
108-90-7 Chlorobenzene ND 55.2 52.8 96 56.9 57.3 101 8 81-129/29
75-00-3 Chloroethane ND 55.2 73.8 134*56.9 78.1 137*6 68-133/29
67-66-3 Chloroform ND 55.2 57.1 103 56.9 61.0 107 7 72-123/26
95-49-8 o-Chlorotoluene ND 55.2 53.5 97 56.9 58.6 103 9 77-129/33
106-43-4 p-Chlorotoluene ND 55.2 51.8 94 56.9 57.1 100 10 80-134/33
124-48-1 Dibromochloromethane ND 55.2 48.6 88 56.9 53.2 93 9 76-127/27
106-93-4 1,2-Dibromoethane ND 55.2 46.8 85 56.9 51.0 90 9 77-126/26
75-71-8 Dichlorodifluoromethane ND 55.2 67.6 122 56.9 75.3 132 11 68-168/29
95-50-1 1,2-Dichlorobenzene ND 55.2 47.4 86 56.9 52.1 92 9 80-129/32
541-73-1 1,3-Dichlorobenzene ND 55.2 49.1 89 56.9 53.9 95 9 81-129/33
106-46-7 1,4-Dichlorobenzene ND 55.2 48.6 88 56.9 54.4 96 11 76-130/32
75-34-3 1,1-Dichloroethane ND 55.2 58.5 106 56.9 60.5 106 3 73-125/27
107-06-2 1,2-Dichloroethane ND 55.2 52.7 95 56.9 56.7 100 7 74-128/23
75-35-4 1,1-Dichloroethylene ND 55.2 59.4 108 56.9 63.5 112 7 81-136/28
156-59-2 cis-1,2-Dichloroethylene ND 55.2 54.6 99 56.9 59.0 104 8 74-126/26
156-60-5 trans-1,2-Dichloroethylene ND 55.2 59.4 108 56.9 63.5 112 7 70-127/27
78-87-5 1,2-Dichloropropane ND 55.2 54.3 98 56.9 59.4 104 9 74-125/25
142-28-9 1,3-Dichloropropane ND 55.2 48.9 89 56.9 52.7 93 7 76-122/26
594-20-7 2,2-Dichloropropane ND 55.2 56.1 102 56.9 59.5 105 6 77-133/28
563-58-6 1,1-Dichloropropene ND 55.2 55.8 101 56.9 58.8 103 5 75-130/28
10061-01-5 cis-1,3-Dichloropropene ND 55.2 52.6 95 56.9 58.7 103 11 80-123/26
10061-02-6 trans-1,3-Dichloropropene ND 55.2 51.2 93 56.9 56.8 100 10 75-131/28
108-20-3 Di-Isopropyl Ether ND 55.2 59.6 108 56.9 61.2 108 3 75-122/25
64-17-5 Ethyl Alcohol ND 1100 723 65 1140 792 70 9 53-154/42
100-41-4 Ethylbenzene ND 55.2 54.6 99 56.9 59.5 105 9 77-123/31
* = Outside of Control Limits.
107 of 123
FC287955.4.4
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2964-2MS 2B21627.D 1 03/03/23 AL n/a n/a V2B909
FC2964-2MSD 2B21628.D 1 03/03/23 AL n/a n/a V2B909
FC2964-2 2B21615.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
FC2964-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/kg Q ug/kg ug/kg %ug/kg ug/kg %RPD Rec/RPD
591-78-6 2-Hexanone ND 276 177 64*284 188 66*6 72-133/26
98-82-8 Isopropylbenzene ND 55.2 52.3 95 56.9 58.1 102 11 80-136/32
99-87-6 p-Isopropyltoluene ND 55.2 52.8 96 56.9 58.6 103 10 77-131/34
74-83-9 Methyl Bromide ND 55.2 65.7 119 56.9 73.6 129 11 65-139/31
74-87-3 Methyl Chloride ND 55.2 66.2 120 56.9 71.4 125 8 71-144/27
75-09-2 Methylene Chloride ND 55.2 62.1 112 56.9 64.3 113 3 74-137/28
108-10-1 4-Methyl-2-pentanone (MIBK)ND 276 194 70*284 204 72*5 76-132/26
1634-04-4 Methyl Tert Butyl Ether ND 55.2 53.3 96 56.9 53.8 95 1 77-120/24
91-20-3 Naphthalene ND 55.2 33.3 60*56.9 36.4 64*9 79-129/33
103-65-1 n-Propylbenzene ND 55.2 54.1 98 56.9 59.4 104 9 80-135/33
100-42-5 Styrene ND 55.2 50.4 91 56.9 55.5 98 10 78-125/30
630-20-6 1,1,1,2-Tetrachloroethane ND 55.2 54.1 98 56.9 60.3 106 11 78-126/27
79-34-5 1,1,2,2-Tetrachloroethane ND 55.2 44.1 80 56.9 48.1 85 9 71-126/30
127-18-4 Tetrachloroethylene ND 55.2 52.8 96 56.9 57.3 101 8 79-130/31
108-88-3 Toluene ND 55.2 53.7 97 56.9 58.2 102 8 76-124/30
87-61-6 1,2,3-Trichlorobenzene ND 55.2 37.6 68*56.9 43.0 76*13 77-128/35
120-82-1 1,2,4-Trichlorobenzene ND 55.2 40.3 73*56.9 45.2 79 11 78-130/34
71-55-6 1,1,1-Trichloroethane ND 55.2 58.7 106 56.9 60.8 107 4 70-129/27
79-00-5 1,1,2-Trichloroethane ND 55.2 48.6 88 56.9 52.6 92 8 74-124/28
79-01-6 Trichloroethylene ND 55.2 54.3 98 56.9 59.7 105 9 75-128/27
75-69-4 Trichlorofluoromethane ND 55.2 66.6 121 56.9 69.1 121 4 73-145/31
96-18-4 1,2,3-Trichloropropane ND 55.2 41.8 76 56.9 44.9 79 7 74-127/27
95-63-6 1,2,4-Trimethylbenzene ND 55.2 55.1 100 56.9 60.3 106 9 74-123/34
108-67-8 1,3,5-Trimethylbenzene ND 55.2 54.3 98 56.9 60.3 106 10 73-122/33
108-05-4 Vinyl Acetate ND 276 55.6 20*284 41.8 15*28 48-164/37
75-01-4 Vinyl Chloride ND 55.2 66.8 121 56.9 70.3 124 5 76-141/27
m,p-Xylene ND 110 111 100 114 120 105 8 80-128/30
95-47-6 o-Xylene ND 55.2 53.7 97 56.9 58.9 104 9 80-132/30
1330-20-7 Xylene (total)ND 166 165 100 171 179 105 8 80-129/30
CAS No.Surrogate Recoveries MS MSD FC2964-2 Limits
1868-53-7 Dibromofluoromethane 103%98%94%75-124%
17060-07-0 1,2-Dichloroethane-D4 95%95%103%72-135%
2037-26-5 Toluene-D8 100%101%111%75-126%
* = Outside of Control Limits.
108 of 123
FC287955.4.4
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2964-2MS 2B21627.D 1 03/03/23 AL n/a n/a V2B909
FC2964-2MSD 2B21628.D 1 03/03/23 AL n/a n/a V2B909
FC2964-2 2B21615.D 1 03/03/23 AL n/a n/a V2B909
The QC reported here applies to the following samples:Method: SW846 8260D
FC2879-7, FC2879-8, FC2879-9, FC2879-12
CAS No.Surrogate Recoveries MS MSD FC2964-2 Limits
460-00-4 4-Bromofluorobenzene 99%98%111%71-133%
* = Outside of Control Limits.
109 of 123
FC287955.4.4
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
110 of 123
FC28796
Method Blank Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U617-MB 1U14135.D 1 02/27/23 JR n/a n/a G1U617
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-1, FC2879-2, FC2879-3, FC2879-4, FC2879-5, FC2879-8, FC2879-9, FC2879-10, FC2879-11
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.0 2.0 mg/kg
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 106%56-149%
98-08-8 aaa-Trifluorotoluene 97%66-132%
111 of 123
FC287966.1.1
Method Blank Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U618-MB 1U14168.D 1 02/28/23 JR n/a n/a G1U618
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-12
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.0 2.0 mg/kg
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 117%56-149%
98-08-8 aaa-Trifluorotoluene 95%66-132%
112 of 123
FC287966.1.2
Method Blank Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U619-MB 1U14203.D 1 03/01/23 JR n/a n/a G1U619
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-6, FC2879-7
CAS No.Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.0 2.0 mg/kg
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 128%56-149%
98-08-8 aaa-Trifluorotoluene 89%66-132%
113 of 123
FC287966.1.3
Blank Spike Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U617-BS 1U14134.D 1 02/27/23 JR n/a n/a G1U617
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-1, FC2879-2, FC2879-3, FC2879-4, FC2879-5, FC2879-8, FC2879-9, FC2879-10, FC2879-11
Spike BSP BSP
CAS No.Compound mg/kg mg/kg %Limits
TPH-GRO (C6-C10)20 17.7 89 74-128
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 106%56-149%
98-08-8 aaa-Trifluorotoluene 97%66-132%
* = Outside of Control Limits.
114 of 123
FC287966.2.1
Blank Spike Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U618-BS 1U14167.D 1 02/28/23 JR n/a n/a G1U618
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-12
Spike BSP BSP
CAS No.Compound mg/kg mg/kg %Limits
TPH-GRO (C6-C10)20 17.8 89 74-128
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 118%56-149%
98-08-8 aaa-Trifluorotoluene 97%66-132%
* = Outside of Control Limits.
115 of 123
FC287966.2.2
Blank Spike Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U619-BS 1U14202.D 1 03/01/23 JR n/a n/a G1U619
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-6, FC2879-7
Spike BSP BSP
CAS No.Compound mg/kg mg/kg %Limits
TPH-GRO (C6-C10)20 17.4 87 74-128
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 129%56-149%
98-08-8 aaa-Trifluorotoluene 90%66-132%
* = Outside of Control Limits.
116 of 123
FC287966.2.3
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2879-2MS 1U14139.D 1 02/27/23 JR n/a n/a G1U617
FC2879-2MSD 1U14140.D 1 02/27/23 JR n/a n/a G1U617
FC2879-2 1U14137.D 1 02/27/23 JR n/a n/a G1U617
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-1, FC2879-2, FC2879-3, FC2879-4, FC2879-5, FC2879-8, FC2879-9, FC2879-10, FC2879-11
FC2879-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound mg/kg Q mg/kg mg/kg %mg/kg mg/kg %RPD Rec/RPD
TPH-GRO (C6-C10)ND 18.5 17.6 95 18.5 16.7 90 5 74-128/17
CAS No.Surrogate Recoveries MS MSD FC2879-2 Limits
460-00-4 4-Bromofluorobenzene 106%109%103%56-149%
98-08-8 aaa-Trifluorotoluene 96%99%94%66-132%
* = Outside of Control Limits.
117 of 123
FC287966.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2879-12MS 1U14170.D 1 02/28/23 JR n/a n/a G1U618
FC2879-12MSD 1U14171.D 1 02/28/23 JR n/a n/a G1U618
FC2879-12 1U14169.D 1 02/28/23 JR n/a n/a G1U618
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-12
FC2879-12 Spike MS MS Spike MSD MSD Limits
CAS No.Compound mg/kg Q mg/kg mg/kg %mg/kg mg/kg %RPD Rec/RPD
TPH-GRO (C6-C10)ND 22.2 20.9 94 22.2 20.0 90 4 74-128/17
CAS No.Surrogate Recoveries MS MSD FC2879-12 Limits
460-00-4 4-Bromofluorobenzene 120%120%111%56-149%
98-08-8 aaa-Trifluorotoluene 94%92%89%66-132%
* = Outside of Control Limits.
118 of 123
FC287966.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC2964-1MS 1U14205.D 1 03/01/23 JR n/a n/a G1U619
FC2964-1MSD 1U14206.D 1 03/01/23 JR n/a n/a G1U619
FC2964-1 1U14204.D 1 03/01/23 JR n/a n/a G1U619
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-6, FC2879-7
FC2964-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound mg/kg Q mg/kg mg/kg %mg/kg mg/kg %RPD Rec/RPD
TPH-GRO (C6-C10)ND 25.3 22.3 88 25.3 23.4 93 5 74-128/17
CAS No.Surrogate Recoveries MS MSD FC2964-1 Limits
460-00-4 4-Bromofluorobenzene 123%128%121%56-149%
98-08-8 aaa-Trifluorotoluene 85%87%84%66-132%
* = Outside of Control Limits.
119 of 123
FC287966.3.3
SGS North America Inc.
GC/LC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 7
120 of 123
FC28797
Method Blank Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP95605-MB WW37923.D 1 02/24/23 EG 02/24/23 OP95605 GWW1484
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-1, FC2879-2, FC2879-3, FC2879-4, FC2879-5, FC2879-6, FC2879-7, FC2879-8, FC2879-9, FC2879-10,
FC2879-11, FC2879-12
CAS No.Compound Result RL MDL Units Q
TPH (C10-C28)ND 5.0 2.5 mg/kg
CAS No.Surrogate Recoveries Limits
84-15-1 o-Terphenyl 66%56-122%
121 of 123
FC287977.1.1
Blank Spike Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP95605-BS WW37924.D 1 02/24/23 EG 02/24/23 OP95605 GWW1484
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-1, FC2879-2, FC2879-3, FC2879-4, FC2879-5, FC2879-6, FC2879-7, FC2879-8, FC2879-9, FC2879-10,
FC2879-11, FC2879-12
Spike BSP BSP
CAS No.Compound mg/kg mg/kg %Limits
TPH (C10-C28)50 44.1 88 62-116
CAS No.Surrogate Recoveries BSP Limits
84-15-1 o-Terphenyl 77%56-122%
* = Outside of Control Limits.
122 of 123
FC287977.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FC2879
Account:MURPHY Murphy Oil USA
Project:GESSCC: Murphy USA 8549; 4993 NC-42, Garner, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP95605-MS WW37946.D 1 02/25/23 EG 02/24/23 OP95605 GWW1484
OP95605-MSD WW37962.D 1 02/27/23 EG 02/24/23 OP95605 GWW1485
FC2879-1 WW37926.D 1 02/24/23 EG 02/24/23 OP95605 GWW1484
The QC reported here applies to the following samples:Method: SW846 8015C
FC2879-1, FC2879-2, FC2879-3, FC2879-4, FC2879-5, FC2879-6, FC2879-7, FC2879-8, FC2879-9, FC2879-10,
FC2879-11, FC2879-12
FC2879-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound mg/kg Q mg/kg mg/kg %mg/kg mg/kg %RPD Rec/RPD
TPH (C10-C28)32.3 57.6 88.1 97 58.1 85.1 91 3 62-116/35
CAS No.Surrogate Recoveries MS MSD FC2879-1 Limits
84-15-1 o-Terphenyl 86%81%69%56-122%
* = Outside of Control Limits.
123 of 123
FC287977.3.1