FA-29152_48332_CA_CSA_20230131

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
February 6, 2023

Mr. Ken Currie
NCDEQ-UST Section
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, NC 28301-5043

Re: Comprehensive Site Assessment Report
January 2023
Breeden’s
22900 Aberdeen Road
Laurinburg, Scotland County
North Carolina
Facility ID Number: 00-0-0000000347
Incident Number: 48332
GRI Project Number: 5991

Dear Mr. Currie,

Please find attached the referenced revised, report for the abovementioned site.
If you have any questions, please contact Ethan Rogerson at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Jimmy McDonald; Quality Oil & Gas, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Comprehensive Site Assessment Report
January 2023
Breeden’s 66
22900 Aberdeen Road
Laurinburg, Scotland County
North Carolina
Facility ID Number: 0-00-0000000347
Incident Number: 48332
GRI Project Number: 5991

Prepared for:

Mr. Jimmy McDonald
Quality Oil & Gas
203 West Broad Avenue
Rockingham, North Carolina 28379

January 31, 2023

William Regenthal, P.G.
Project Manager
Eric M. Eubanks, P.G.
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
i
EXECUTIVE SUMMARY
The Breeden’s 66 site is an active convenience store and gasoline retail facility located at 22900 Aberdeen
Road in Laurinburg, Scotland County, North Carolina. The site is covered by asphalt, concrete, and grass.
There is one 4,000-gallon regular gasoline UST, one 1,500-gallon plus gasoline UST, one 1,000-gallon
premium gasoline UST and two 1,000-gallon diesel USTs currently in use at the site with five associated
dispensers on one dispenser island. The surrounding properties are zoned residential (R-1) and
residential-agricultural (RA).

On November 30, 2021, during routine compliance inspection activities, two damaged/defective UST spill
buckets associated with the 1,000-gallon diesel and 1,500-gallon plus gasoline USTs, as well as a suspected
release beneath the off-road diesel dispenser were reported at the site. GRI conducted a site check at the
subject site on March 16 and March 17, 2022. Site Check results confirmed a release at the site and an
LSA was required.

A receptor survey was conducted on April 13, 2022. Five potable water supply wells were identified within
a 1,500-foot radius of the site. Two of the identified water supply wells were located within a 1,000-foot
radius of the site; one of the water supply wells was located within a 250-foot radius of the site. Public
water is available to the subject site and to some of the surrounding properties.

On April 13, 2022, one monitoring well was installed and sampled as part of the LSA activities. The site
risk conditions warranted a High-Risk LSA, and three additional monitoring wells were installed and
sampled on June 23, 2022. Based on the results of LSA activities, a CSA was required.

Between January 3 and January 6, 2023, four Type II monitoring wells and one Type III telescoping well
were installed as part of CSA activities. The contaminant concentrations of benzene, toluene, xylenes,
MTBE, naphthalene, TAA, TBA, n-butylbenzene, isopropylbenzene, n-propylbenzene, 1,2,4-
trimethylbenzene, 1-methylnaphthalene, lead, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics,
and/or C11-C22 aromatics reported in the ground water samples collected from MW-1 and MW-3 through
MW-8 exceeded the MACs. All contaminant concentrations were below the GCLs. No free product was
observed at the site.

During CSA activities, six soil borings were advanced to twenty-five feet BGS, and PID readings were
collected every two feet. Fifteen soil samples were collected from the borings and analyzed for TPH-GRO
and TPH-DRO using UVF technology. The concentrations of TPH-GRO and/or TPH-DRO reported in SB-3-
22’, SB-3-24’, and SB-5-22’ exceeded the RALs.

Based on observations made during assessment activities, surficial soils observed at the site consist of
various clays, silts, and sands to a depth of 55 feet. Ground water flow was generally toward the
northeast. The horizontal hydraulic gradient was calculated as 0.003 ft/ft. The vertical hydraulic gradient
was calculated as 0.083ft/ft downward. Rising head slug tests were conducted on MW-1, MW-8, and TW-

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
ii
1. The average hydraulic conductivity and seepage velocity for the Type II monitoring wells were 3.053 x
10-4 feet per minute (0.4396 feet per day) and 8.792 x 10-3 feet per day (3.209 feet per year). The hydraulic
conductivity and seepage velocity in the Type III monitoring were 7.378 x 10-4 feet per minute (1.062 feet
per day) and 1.06 x 10-2 feet per day (3.88 feet per year), respectively.

The site risk classification is determined to be high risk based on the presence of MAC exceedances and
the presence of active, potable water supply wells within 1,000 feet of the source of contamination.
Therefore, in order to reduce the risk classification, ground water contamination must be remediated to
concentrations less than the MACs and/or the owners of the water supply wells change over to public
water and the water supply well (WSW-1) within 250’ must be abandoned.

GRI recommends conducting comprehensive quarterly ground water sampling events beginning in April
2023. Sampling data should be incorporated into a contaminant Fate and Transport model to make further
recommendations towards incident closure.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
iii
SITE INFORMATION
1. Site Identification
ú Breeden’s 66 (Facility ID 0-00-0000000347)
ú Incident Number 48332 – High Risk (H210A)
ú Location of Source Area: 22900 Aberdeen Road
Laurinburg, NC 27533
Scotland County
34.865101°N, 79.455527°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST Owner/Operator
Quality Oil & Gas
203 West Broad Avenue
Rockingham, NC, 28379
[e-mail]
Phone: [phone]

Property Owner
S&H Rental, Inc.
Post Office Box 2048
Raeford, NC 28376
Email: Unknown
Phone: Unknown

Property Occupant
Breeden’s 66
22900 Aberdeen Road
Laurinburg, NC 28352
E-mail: Unknown
Phone: [phone]

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
Phone: [phone]

Mobile Laboratory
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical
449 Springbrook Road
Charlotte, NC 28217
704-549-6364
State Certification No. 402/37735
3. Information about Release
ú Release was discovered on March 18, 2022
ú An unknown amount of product was released from the UST System via the damaged/defective
UST spill buckets associated with the 1,000-gallon diesel and 1,500-gallon plus gasoline USTs and
the leaking off-road diesel dispenser.
ú One 4,000-gallon regular gasoline, one 1,500-gallon plus gasoline, one 1,000-gallon premium
gasoline and two 1,000-gallon diesel USTs are in use at the site (Tables 1 and 2).

Certification:

I, Samuel L. McKay, III, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice geology and engineering in North Carolina. The
certification numbers of the company are C-127 and C-2727, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
iv
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
TABLE OF CONTENTS
EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 RECEPTOR INFORMATION ........................................................................................................2
3.0 LAND USE ................................................................................................................................3
4.0 SOIL ASSESSMENT ...................................................................................................................3
5.0 GROUND WATER ASSESSMENT ................................................................................................4
6.0 HYDROGEOLOGIC INVESTIGATION ...........................................................................................5
7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY .............................................................................6
8.0 SITE GEOLOGY AND HYDROGEOLOGY ......................................................................................6
9.0 DISCUSSION ............................................................................................................................7
10.0 CONCLUSIONS AND RECOMMENDATIONS ...............................................................................7
11.0 PUBLIC NOTICE ........................................................................................................................8
12.0 LIMITATIONS ...........................................................................................................................8
13.0 REFERENCES ............................................................................................................................8

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3A: Site Vicinity Map
Figure 3B: Zoning Map
Figure 4: Soil Quality Map
Figure 5: Cross-Section A-A’
Figure 6: Cross-Section B-B’
Figure 7: Ground Water Quality Map
Figure 8: Benzene Isoconcentration Map
Figure 9: Toluene Isoconcentration Map
Figure 10: Xylenes Isoconcentration Map
Figure 11: MTBE Isoconcentration Map
Figure 12: Naphthalene Isoconcentration Map
Figure 13: Water Table Surface Map
TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Land Use Information

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
Table 6: Summary of Soil Sample Analytical Results
Table 7: Summary of Ground Water Sample Analytical Results
Table 8: Well Construction and Gauging Information
Table 9: Summary of Slug Test Analyses
APPENDICES
Appendix A: State Correspondence
Appendix B: Site-Specific Health and Safety Plan
Appendix C: UVF Analytical Report
Appendix D: RTEs, Well Permits, Well Construction Records, and Subsurface Logs
Appendix E: Laboratory Analytical Report
Appendix F: Slug Test Data
Appendix G: Public Notification

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the January 2023 CSA activities at the Breeden’s 66 site, located at 22900
Aberdeen Road in Laurinburg, Scotland County, North Carolina. A topographic map showing the general
site location and the surrounding area is included as Figure 1. These activities were conducted in
accordance with GRI Proposal No 22-569, which was submitted to the NCDEQ on August 12, 2022, and
was approved as Task Authorization Number 48332-1 on August 17, 2022. Two change orders were
submitted to NCDEQ on October 11, 2022, and November 11, 2022, and were approved as Task
Authorization Numbers 48332-001.1 and 48332-001.2 on October 21, 2022 and November 14, 2022,
respectively. State correspondence is included as Appendix A.

The site is currently owned and operated by S&H Rental, Inc. as a petroleum retail facility. One 4,000-
gallon regular gasoline, one 1,500-gallon plus gasoline, one 1,000-gallon premium gasoline and two 1,000-
gallon diesel USTs are currently in use at the site with one associated dispenser island. UST
owner/operator information and UST system information are included as Tables 1 and 2, respectively.
The Registered Tank Report is shown below:

On November 30, 2021, during routine compliance inspection activities, two damaged/defective UST spill
buckets associated with the 1,000-gallon diesel and 1,500-gallon plus gasoline USTs, as well as a suspected
release beneath the off-road diesel dispenser were reported at the site. On March 16 and 17, 2022, GRI
conducted a site check at the subject site. Three soil samples were collected adjacent to the defective
spill buckets and from beneath the diesel dispenser. Concentrations of GRO and DRO that exceeded the

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
2
RALs were reported in the soil sample (ORD-1) collected from beneath the diesel dispenser. Site Check
results confirmed a release at the site and an LSA was required by NCDEQ.

On April 13, 2022, one monitoring well (MW-1) was installed adjacent to the UST basin. Two soil samples
were collected at 5 and 15 feet BGS during the installation of MW-1. No concentrations of requested
method constituents that exceeded the MCCs were reported in the soil samples collected from MW-1.
On April 13, 2022, a ground water sample was collected from MW-1. Contaminant concentrations of
benzene, MTBE, naphthalene, TAA, 1-methylnaphthalene, lead, C5-C8 aliphatics, and C9-C10 aromatics
that exceeded the MACs were reported in the ground water sample collected from MW-1. Three
additional Type II monitoring wells (MW-2 through MW-4) were installed, gauged, and sampled on June
23, 2022 as part of High-Risk LSA activities. Contaminant concentrations of benzene, toluene,
ethylbenzene, xylenes, MTBE, naphthalene, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene,
1,3,5-trimethylbenzene, EDB, 1-methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C12
aliphatics, C9-C10 aromatics, C9-C18 aliphatics, and/or C11-C22 aromatics exceeded the MACs in the
ground water samples collected from MW-2 through MW-4. All contaminant concentrations were below
the GCLs. Based on the results of LSA activities, a CSA was required.

Between January 3 and January 6, 2023, four additional Type II monitoring wells (MW-5 through MW-8)
and one Type III telescoping well (TW-1) were installed as part of CSA activities. The contaminant
concentrations of benzene, toluene, xylenes, MTBE, naphthalene, TAA, TBA, n-butylbenzene,
isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1-methylnaphthalene, lead, C5-C8
aliphatics, C9-C12 aliphatics, C9-C10 aromatics, and/or C11-C22 aromatics reported in the ground water
samples collected from MW-1 and MW-3 through MW-8 exceeded the MACs. All contaminant
concentrations were below the GCLs. No free product was observed at the site.

During CSA activities, six soil borings (SB-1 through SB-6) were advanced to twenty-five feet BGS, and PID
readings were collected every two feet. Fifteen soil samples (SB-2-16’, SB-2-18’, SB-2-20’, SB-2-24’, SB-3-
8’, SB-3-14’, SB-3-16’, SB-3-18’, SB-3-22’, SB-3-24’, SB-4-22’, SB-4-24’, SB-5-18’, SB-5-22’, and SB-5-24’)
were collected from the borings and analyzed for TPH-GRO and TPH-DRO using UVF technology. The
concentrations of TPH-GRO and/or TPH-DRO reported in SB-3-22’, SB-3-24’, and SB-5-22’ exceeded the
RALs. A Site Map showing the locations of the monitoring wells and the structures on-site is included as
Figure 2. A copy of the site-specific Health and Safety Plan is included as Appendix B.
2.0 RECEPTOR INFORMATION
Water Supply Wells:
According to the information determined during receptor survey activities conducted on April 13, 2022,
five potable water supply wells were identified within 1,500 feet of the site. Of the identified water supply
wells, two of the wells were located within a 1,000-foot radius of the site, and one of the wells was located
within a 250-foot radius of the site. A table summarizing the Water Supply Well owner information is
included as Table 3. A Site Vicinity Map showing the locations of the water supply wells is included as
Figure 3A.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
3
Public Water Supplies:
Municipal water is available to the site and some of the surrounding properties. Water lines run along
Aberdeen Road and Monroe Road. Public water is supplied by the Laurinburg Public Works.

Surface Water:
No surface waters were identified within 1,000’ of the site.

Wellhead Protection Areas:
On April 28, 2022, GRI personnel accessed the NCDEQ SWAP Program’s website to identify wellhead
protection areas in the vicinity of the subject site. The site is not located within a wellhead protection
area.

Deep Aquifers in the Coastal Plain Physiographic Region:
The site is in the Coastal Plain Physiographic Region. The surficial aquifer in the vicinity of the site is
relatively thin and is underlain by the Black Creek confining unit and Black Creek aquifer, respectively.

Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. The water main and other
underground utilities run along Aberdeen Road and Monroe Road.

3.0 LAND USE
The site is currently occupied by an active petroleum retail facility and convenience store. The closest
primary residence is 22920 Aberdeen Road located approximately 115 feet northwest of the site. Cool
Spring Methodist Church is located at 16301 Scotch Grove Road, approximately 5,220 feet southeast of
the source area at the site. The adjoining properties are residential and agricultural. According to the
Scotland County Official property cards, the surrounding areas are zoned residential (R-1) and residential
agricultural (RA). Adjacent property owner information and land use information have been summarized
in Tables 4 and 5. Land use and zoning information is presented on Figure 3B.

4.0 SOIL ASSESSMENT
On November 30, 2021, two damaged/defective UST spill buckets associated with the 1,000-gallon diesel
and 1,500-gallon plus gasoline USTs, as well as a suspected release beneath the off-road diesel dispenser
were reported at the site. GRI conducted a site check at the subject site on March 16 and March 17, 2022.
Two soil samples (Blue-3’ and Yellow-3’) were collected approximately 3 feet BGS adjacent to the non-
passing spill buckets and one soil sample (ORD-1) was collected beneath the off-road diesel dispenser.
Concentrations of GRO and DRO that exceeded the RALs were reported in the soil sample collected from
ORD-1.

On April 13, 2022, during the installation of MW-1, two soil samples (MW-1-5’ and MW-1-15’) were
collected at 5 and 15 feet BGS, respectively, and were submitted for laboratory analyses of VOCs using
EPA Method 8260, SVOCs using EPA Method 8270, and VPH and EPH by the MADEP Methods. The

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
4
reported contaminant concentrations did not exceed the soil-to-water MCCs for the submitted soil
samples.

During CSA activities, six soil borings (SB-1 through SB-6) were advanced to twenty-five feet BGS, and PID
readings were collected every two feet. Fifteen soil samples (SB-2-16’, SB-2-18’, SB-2-20’, SB-2-24’, SB-3-
8’, SB-3-14’, SB-3-16’, SB-3-18’, SB-3-22’, SB-3-24’, SB-4-22’, SB-4-24’, SB-5-18’, SB-5-22’, and SB-5-24’)
were collected from the borings and analyzed for TPH-GRO and TPH-DRO using UVF technology. The
concentrations of TPH-GRO and/or TPH-DRO reported in SB-3-22’, SB-3-24’, and SB-5-22’ exceeded the
RALs. The soil sampling analytical results are presented in Table 6. A Soil Quality Map with the results of
the soil sampling in January 2023 is included as Figure 4. The UVF Analytical report is included as Appendix
C. A summary of the soil sampling data from the January 2023 CSA activities is shown below:
Sample ID Sample Depth (ft-BGS) PID Reading Gasoline-Range TPH Diesel-Range TPH RAL (mg/kg) NE 50 100
SB-2-16' 16 1.0 11.6 5.4
SB-2-18' 18 5.0 <20 4.4
SB-2-20' 20 1.0 <20 4.4
SB-2-24' 24 1.0 24.8 4.0
SB-3-8' 8 1.0 21.6 4.4
SB-3-14' 14 3.0 <10 2.8
SB-3-16' 16 5.0 24.2 4.8
SB-3-18' 18 3.0 <20 5.2
SB-3-22' 22 26.0 641 259
SB-3-24' 24 34.0 79.2 20.8
SB-4-22' 22 4.0 <20 4.0
SB-4-24' 24 3.0 27.6 4.0
SB-5-18' 18 3.0 11.6 2.0
SB-5-22' 22 27.0 78.4 83.6
SB-5-24' 24 38.0 10.2 3.2

5.0 GROUND WATER ASSESSMENT
On April 13, 2022, one monitoring well (MW-1) was installed adjacent to the UST basin. Based on the
analytical results from the ground water sample collected from MW-1, a High-Risk LSA was required.
Three additional Type II monitoring wells (MW-2 through MW-4) were installed, gauged, and sampled on
June 23, 2022. Based on the results of LSA activities, additional assessment was required.

Between January 3 and January 6, 2023, four additional Type II monitoring wells (MW-5 through MW-8)
and one Type III telescoping well (TW-1) were installed as part of CSA activities. Monitoring wells MW-5
through MW-8 were each installed to total depth of 25 feet BGS with a 15-foot screened interval for each
well. Telescoping well TW-1 was installed to a total depth of 55 feet BGS with a 5-foot screened interval.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
5
On January 10, 2023, all wells were gauged, purged, and sampled. The contaminant concentrations of
benzene, toluene, xylenes, MTBE, naphthalene, TAA, TBA, n-butylbenzene, isopropylbenzene, n-
propylbenzene, 1,2,4-trimethylbenzene, 1-methylnaphthalene, lead, C5-C8 aliphatics, C9-C12 aliphatics,
C9-C10 aromatics, and/or C11-C22 aromatics reported in the ground water samples collected from MW-
1 and MW-3 through MW-8 exceeded the MACs. Water supply well WSW-1 could not be sampled because
the electricity was cut off and the well was not operating. All contaminant concentrations were below
the GCLs. No free product was observed at the site. Based on correspondence with NCDEQ dated January
30, 2023, it was determined that no additional delineation is required at this time. A summary of the
January 10, 2023 ground water analytical data is shown below:

Contaminant of
Concern Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MACs (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 550 362 361 1,360 864 40.5
MW-2 0.239 J <0.220 <0.170 <0.210 <0.140 <0.470
MW-3 168 1,910 522 2,860 43.3 65
MW-4 0.64 <0.220 <0.170 <0.210 249 <0.470
MW-5 14.6 62.8 68.3 413 15.6 25.5
MW-6 26.0 148.0 48.9 206 38.9 13.5
MW-7 382 2,130 448 2,620 440 157
MW-8 2.28 4.2 4.8 20.7 0.228 J <0.470
TW-1 0.57 0.7 0.473 J 2.03 0.972 J <0.470

All samples were collected in accordance with the NCDEQ guidelines. Clean, disposable bailers and nitrile
gloves were used for the collection of the ground water samples. The samples were collected in
laboratory supplied containers and shipped to the laboratory in a cooler following proper chain-of-custody
procedures. A laboratory supplied trip blank was included in the sample cooler. No detectable
concentrations of requested method constituents were reported in the trip blank.

The locations of the monitoring wells are shown on Figure 2. The RTEs, well permits, well construction
records, and boring logs for the monitoring wells installed during CSA activities are included as Appendix
D.

Cross sections A-A’ and B-B’ are included as Figures 5 and 6; the lines of cross section are included on
Figure 2. A Ground Water Quality Map for the January 2023 ground water sampling event in association
with the CSA activities is included as Figure 7. Contaminant-specific isoconcentration maps for benzene,
toluene, xylenes, MTBE, and naphthalene are included as Figures 8-13, respectively. A summary of
laboratory analyses for the ground water samples collected during CSA activities is included as Table 7. A
complete copy of the laboratory report for the ground water samples is included as Appendix E.

6.0 HYDROGEOLOGIC INVESTIGATION

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
6
The depths to ground water in the Type II monitoring wells (MW-1 through MW-8) measured on January
10, 2023, ranged from 17.93 to 20.54 feet below the tops of well casings. Ground water elevations at the
site, based on an assumed datum of 100.00 feet assigned to MW-1, ranged from 80.15 to 80.44 feet.
Based on this information, the ground water flow direction was generally toward the northeast. The
horizontal hydraulic gradient across the site was approximately 0.003 feet per foot. The vertical hydraulic
gradient calculated for paired wells MW-1/TW-1 was approximately 0.083 feet per foot in the downward
direction. A summary of ground water elevation data obtained during assessment activities to date is
presented in Table 8. A Water Table Surface Map based on the January 10, 2023 gauging data is included
as Figure 13.

Rising head slug tests were conducted in MW-1, MW-8, and TW-1 on January 10, 2023. Hydraulic
conductivities in the Type II monitoring wells, calculated using the Bouwer and Rice method, ranged from
3.565 x 10-5 feet per minute (0.0513 feet per day) to 5.749 x 10-4 feet per minute (0.8279 feet per day). The
average hydraulic conductivity was 3.053 x 10-4 feet per minute (0.4396 feet per day). Seepage velocities,
calculated using the equation V = K(dh/dl)/ne, ranged from 1.03 x 10-3 to 1.66 x 10-2 feet per day (0.375 to
6.04 feet per year). The average seepage velocity was 8.792 x 10-3 feet per day (3.209 feet per year). The
hydraulic conductivity in the Type III monitoring well calculated using the Bouwer and Rice method was
7.378 x 10-4 feet per minute (1.062 feet per day). The seepage velocity calculated for the Type III
monitoring well was 1.06 x 10-2 feet per day (3.88 feet per year). A summary of the results of slug test
analyses is presented in Table 9. Calculations and raw data from the slug tests are included as Appendix
F.

7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is in the Middendorf Formation. This
formation is generally described as coarse detrital sand, sandstone, and mudstone. No bedrock was
encountered during monitoring well installation activities.
8.0 SITE GEOLOGY AND HYDROGEOLOGY
Based on observations made during assessment activities, surficial soils observed at the site consist of
various clays, silts, and sands to 55 feet BGS. A summary of the current ground water gauging data is
shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-1 10 - 25 25 100.00 19.58 --- 80.42
MW-2 10 - 25 25 100.98 20.54 --- 80.44
MW-3 10 - 25 25 99.50 19.20 --- 80.30
MW-4 10 - 25 25 100.50 20.07 --- 80.43
MW-5 10 - 25 25 99.13 18.90 --- 80.23
MW-6 10 - 25 25 98.41 18.24 --- 80.17
MW-7 10 - 25 25 98.08 17.93 --- 80.15
MW-8 10 - 25 25 99.98 19.65 --- 80.33

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
7
TW-1 50 – 55 55 99.81 22.15 --- 77.66

On January 10, 2023, monitoring wells MW-1 through MW-8 and TW-1 were gauged, purged, and
sampled. Depths to ground water in the Type II monitoring wells ranged from 17.93 to 20.54 feet below
the tops of well casings. Ground water elevations at the site, based on an assumed datum of 100.00 feet
assigned to MW-1, ranged from 80.15 to 80.44 feet. Ground water flow was generally toward the
northeast.
9.0 DISCUSSION
On November 30, 2021, two damaged/defective UST spill buckets associated with the 1,000-gallon diesel
and 1,500-gallon plus gasoline USTs, as well as a suspected release beneath the off-road diesel dispenser
were reported at the site. GRI conducted a site check at the subject site on March 16 and March 17, 2022,
and a release was confirmed on March 18, 2022.

To date, eight Type II monitoring wells and one telescoping well have been installed to determine the
horizontal and vertical extent of the release. No free product has been observed at the site. All
contaminant concentrations are below the GCLs. Based on NCDEQ correspondence dating January 30,
2023, it was determined that the contaminant plume is sufficiently delineated.

The risk ranking for the site has been established as High based on MAC exceedances and the presence of
active, potable water supply wells within 1,000 feet of the source of contamination. In order to reduce
the risk classification, ground water contamination must be remediated to concentrations less than the
MACs or the owners of the water supply wells change over to public water and the water supply well
(WSW-1) within 250’ must be abandoned. It appears that the plume of contamination is migrating to the
northeast, away from all identified water supply wells. GRI recommends conducting comprehensive
quarterly ground water sampling events beginning in April 2023. Sampling data can be incorporated into
a contaminant Fate and Transport model to make further recommendations towards incident closure.
10.0 CONCLUSIONS AND RECOMMENDATIONS
· Ground water elevations at the site, based on an assumed datum of 100.00 feet assigned to MW-
1, ranged from 80.15 to 80.44 feet. Based on this information, the ground water flow direction
was generally toward the northeast, away from all identified water supply wells. The horizontal
hydraulic gradient across the site was approximately 0.003 feet per foot. The vertical hydraulic
gradient calculated for paired wells MW-1/TW-1 was approximately 0.083 feet per foot in the
downward direction.
· During CSA activities, six soil borings (SB-1 through SB-6) were advanced to twenty-five feet BGS.
The concentrations of GRO and/or DRO reported in SB-3-22’, SB-3-24’, and SB-5-22’ exceeded the
RALs.
· Between January 3 and January 6, 2023, four additional Type II monitoring wells (MW-5 through
MW-8) and one Type III telescoping well (TW-1) were installed at the site.
· The contaminant concentrations of benzene, toluene, xylenes, MTBE, naphthalene, TAA, TBA, n-
butylbenzene, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1-

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
8
methylnaphthalene, lead, C5-C8 aliphatics, C9-C12 aliphatics, C9-C10 aromatics, and/or C11-C22
aromatics reported in the ground water samples collected from MW-1 and MW-3 through MW-8
exceeded the MACs. All contaminant concentrations were below the GCLs. No free product was
observed at the site.
· The ground water contaminant plume is defined vertically, as well as horizontally to the west;
however, the NCDEQ Incident Manager has determined it to be sufficiently delineated for the
site-specific cleanup goals.
· Based on this site assessment, the site risk classification should remain High.
· GRI recommends conducting comprehensive quarterly ground water sampling events beginning
in April 2023. Sampling data can be incorporated into a contaminant Fate and Transport model to
make further recommendations towards incident closure.
11.0 PUBLIC NOTICE
Copies of the applicable portions of this CSA report have been forwarded to the appropriate local officials
by certified mail. Copies of the cover letters are included in Appendix G.
12.0 LIMITATIONS
This report has been prepared for the exclusive use of Quality Oil and Gas for specific application to the
referenced site in Scotland County, North Carolina. The assessment was conducted based on the scope
of work and level of effort desired by the NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that is presented in this report is indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from this data.
13.0 REFERENCES
Bouwer, H., 1989, The Bouwer and Rice slug test - an update, Ground Water, vol.27, no. 3, pp.304-309
Bouwer, H. and R.C. Rice, 1976, A slug test method for determining hydraulic conductivity of unconfined
aquifers with completely or partially penetrating wells, Water Resources Research, vol. 12, no.3,
pp. 423-428
Department of Natural Resources and Community Development, 1985, Geologic Map of North Carolina,
1 sheet
Fetter, C. W., 1988, Applied Hydrogeology, Second Edition, Macmillan Publishing Company, 592 p.
North Carolina Department of Environment and Natural Resources, 2000, Ground Water Section
Guidelines for the Investigation and Remediation of Soil and Ground Water, 79 p.
North Carolina Department of Environmental Quality, Division of Waste Management – UST Section
Assessment Guidelines: Petroleum and Hazardous Substances UST Releases; Petroleum Non-UST
Releases, January 19, 2021 Version

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: January 31, 2023 Breeden’s 66
Project Manager: William Regenthal, P.G. GRI Project No. 5991
9
Site Check Report, Breeden’s 66, Geological Resources, Inc., March 23, 2022
Limited Site Assessment Report, Breeden’s 66, Geological Resources, Inc., July 19, 2022

FIGURES
SITE LOCATION
Figure 1
Site Location
Breeden’s 66
22900 Aberdeen Road
Laurinburg, North Carolina
Scotland County
Incident No. 48332
GRI Project No. 5991
500 M
2000 FT
Date: 07/20/2022 Location: 34.865101° N -79.455527° W
D
a
d
"J
"J
"J
"J
"J
SITE
020316 01001
020314 01024
020322 01033
020314 01033
020314 01034
020314 01036020314 01037020314 0103401
WSW-5
WSW-4
WSW-3
WSW-2
WSW-1
Sources: Esri, HERE, Garmin, USGS, Intermap, INCREMENT P, NRCan, Esri Japan, METI, Esri China (Hong Kong), Esri Korea, Esri (Thailand), NGCC, ©
OpenStreetMap contributors, and the GIS User Community
³
0 300150
Feet
1 inch = 300 feet

BREEDEN'S 66
22900 ABERDEEN ROAD
LAURINBURG, SCOTLAND COUNTY
NORTH CAROLINA
INCIDENT NO. 48332
GRI NO. 5991
PREPARED BY:
GEOLOGICAL RESOURCES, INC.
APRIL 8, 2022
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
LEGEND
"J Water Supply Well
ncrivers
Well Owners and Adjacent Properties
nc_scotland_parcels_poly
FIGURE 3A:SITE VICINITY MAP
"J
"J
"J
"J
"J
SITE
WSW-5
WSW-4
WSW-3
WSW-2
WSW-1
Sources: Esri, HERE, Garmin, USGS, Intermap, INCREMENT P, NRCan, Esri Japan, METI, Esri China (Hong Kong), Esri Korea, Esri (Thailand), NGCC, ©
OpenStreetMap contributors, and the GIS User Community
³
0 300150
Feet
1 inch = 300 feet
FIGURE 3B: ZONING MAP
BREEDEN'S 66
22900 ABERDEEN ROAD
LAURINBURG, SCOTLAND COUNTY
NORTH CAROLINA
INCIDENT NO. 48332
GRI NO. 5991
PREPARED BY:
GEOLOGICAL RESOURCES, INC.
APRIL 8, 2022
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
LEGEND
"J Water Supply Well
ncrivers
ZONING - R1
ZONING - RA
nc_scotland_parcels_poly

TABLES
UST ID Number 1-5 Facility ID Number
Owner or Operator?
Owner
TABLE 1
UST OWNER/OPERATOR INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
00-0-000000347
Address Telephone Number
203 West Broad Avenue, Rockingham, NC 28379 910-997-3101
Name of Owner or Operator Dates of Ownership / Operation
4/4/1968 - CurrentQuality Oil Company
Page 1 of 1
Date: 04/28/2022 Facility ID #: 00-0-000000347
Was Release
Associated
with UST
System?
(Yes / No)
5 Off-Road
Diesel 1,000 4/4/1968 Single Wall Steel 46" x 12' Single Wall FRP Current Yes
4 Diesel 1,000 4/4/1968 Single Wall Steel 46" x 12' Single Wall FRP Current No
3 Gasoline 1,500 4/4/1968 Single Wall Steel 64" x 9' Single Wall FRP Current No
2 Gasoline 1,000 4/4/1968 Single Wall Steel 46" x 12' Single Wall FRP Current No
1 Gasoline 4,000 4/4/1968 Single Wall Steel 64" x 24' Single Wall FRP Current No
UST
ID
No.
TABLE 2
UST SYSTEM INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Well ID. Parcel ID No. Well Owner Mailing Address Well Address
Well Status
(Active/In-Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
WSW-1 020314 01034 David Breeden 22920 Aberdeen Road,
Laurinburg, NC 28352
22920 Aberdeen Road,
Laurinburg, NC 28352 In-Active Non-Potable Yes Yes ~180 NW
WSW-2 020314 01033 Janet Stack 15900 Monroe Road
Laurinburg, NC 28352
15900 Monroe Road
Laurinburg, NC 28352 Active Potable Yes No ~460 W
WSW-3 020314 01036 Harry E Clark 15825 Monroe Road
Laurinburg, NC 28352
15825 Monroe Road
Laurinburg, NC 28352 Active Potable No No ~1,060 NW
WSW-4 020314 01037 Sharon Monroe 15781 Monroe Road
Laurinburg, NC 28352
15781 Monroe Road
Laurinburg, NC 28352 Active Potable No No ~1,120 NW
WSW-5 020322 01033 Thomas C Tapp
Patricia McMillan Tapp
23040 Aberdeen Road
Laurinburg, NC 28352
23040 Aberdeen Road
Laurinburg, NC 28352 Active Potable No No ~1,070 NW
Notes:
• Receptors are shown on Figure 3A.
• N/A: Not Applicable.
TABLE 3
RECEPTOR INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Date: 04/28/22
Well Construction Details
(Depth, Screened Interval, Type of Well, ect.)
Facility ID #: 00-0-000000347
Unknown
Unknown
Unknown
Unknown
Unknown
Page 1 of 1
Date: 04/28/22 Facility ID #: 00-0-000000347
PIN Number Property Owner Name Property Owner Address
020314 0103401
(site)S & H Rental Inc. P.O. Box 2048 Raeford, NC 28376
020314 01034
020314 01039
020314 01033 Janet Stack
15900 Monroe Road
Laurinburg, NC 28352
020314 01024
020316 01001
Note:
• Properties are keyed to Figure 3a.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Howell Land Co. 2 LLC.P.O. Box 1151,
Laurinburg, NC 28353
David Breeden 22900 Aberdeen Road
Laurinburg, NC 28352
Page 1 of 1
Date: 07/19/22
Map ID No. Land Use Feature Zoning Description Address
Distance from
Source Area
(feet)
N/A RA Residential Agricultural N/A ~50
N/A R-1 Residential
15900 Monroe Road, Laurinburg, NC
28355 ~1,030
Note:
• Properties are keyed to Figure 3B.
TABLE 5
LAND USE INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Facility ID #: 00-0-000000347
Page 1 of 1
Date: 01/30/2023
UVF UVF
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)Gasoline-Range TPHDiesel-Range TPHBenzeneMTBE2-Butanone (MEK)50 100 NE NE NE
NE NE 0.0072 0.085 16
NE NE 12 156 9,380
ORD-1 03/16/22 1 1,864 1,820 NR NR NR
Yellow-3'03/17/22 3 13.2 18 NR NR NR
Blue-3'03/17/22 3 14 36 NR NR NR
MW-1-5'04/13/22 5 NR NR <0.0013 <0.0077 <0.0011
MW-1-15'04/13/22 15 NR NR 0.0020 J 0.0124 J 0.0071
SB-2-16'01/05/23 16 11.6 5.4 NR NR NR
SB-2-18'01/05/23 18 <20 4.4 NR NR NR
SB-2-20'01/05/23 20 <20 4.4 NR NR NR
SB-2-24'01/05/23 24 24.8 4.0 NR NR NR
SB-3-8'01/05/23 8 21.6 4.4 NR NR NR
SB-3-14'01/05/23 14 <10 2.8 NR NR NR
SB-3-16'01/05/23 16 24.2 4.8 NR NR NR
SB-3-18'01/05/23 18 <20 5.2 NR NR NR
SB-3-22'01/05/23 22 641 259 NR NR NR
SB-3-24'01/05/23 24 79.2 20.8 NR NR NR
SB-4-22'01/05/23 22 <20 4.0 NR NR NR
SB-4-24'01/05/23 24 27.6 4.0 NR NR NR
SB-5-18'01/05/23 18 11.6 2.0 NR NR NR
SB-5-22'01/05/23 22 78.4 83.6 NR NR NR
SB-5-24' 01/05/23 24 10.2 3.2 NR NR NR
Notes:
• UVF: Ultraviolet Fluorescent technology
• Results reported in mg/kg (milligrams per kilograms)
• ft-BGS: feet below ground surface.
• RAL: Regulatory Action Level.
• MCCs: Maximum Contaminant Concentrations (soil).
• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type indicate the reported concentrations exceeded the soil-to-water MCCs.
• Concentrations in italics indicate reported concentration exceeded the residential SCLs.
• NE: Not Established
• NR: Not Requested.
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Residential SCLs (mg/kg)
TABLE 6
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
BREEDEN'S 66 (INCIDENT NO. 48332)
Analytical Method 8260
Facility ID #: 00-0-000000347
Page 1 of 1
Date: 01/30/2023
EPA
504.1 EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 70 70 70 400 400 0.02 1 30 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 5,900 30,500 26,100 28,500 24,100 50 1,000 12,000 15,000 NE NE NE NE NE NE
04/13/22 303 180 170 420 419 27.9 266 <20 6.2 16.9 33.6 120 70.2 <0.018 3.9 J 7.4 212 662 61.5 J 365 <50 <50 172 J
01/10/23 550 362 361 1,360 864 40.5 1,350 187 9.97 22.2 40.6 343 150 NR NR NR NR NR NR NR NR NR NR
06/23/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.180 <0.190 <0.190 <0.180 0.0219 <1.27 <7.96 0.049 <11.5 <25.8 <4.02 <38.1 <168 <82.7
01/10/23 0.239 J <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 6.00 J <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
06/23/22 587 15,500 3,680 20,000 111 851 <190 <160 61.3 251 760 5,520 1,550 0.0360 66.5 132 0.269 23,400 15,900 12,400 783 <177 771
01/10/23 168 1,910 522 2,860 43.3 65 76.1 18.6 81.8 34.3 92.3 810 251 NR NR NR NR NR NR NR NR NR NR
06/23/22 2.08 52.6 17.8 102 175 <0.470 <1.90 <1.60 1.25 1.99 6.98 52.9 15.5 0.0407 1.64 J <8.51 0.022 412 332 429 <36.4 <160 <79.1
01/10/23 0.64 <0.220 <0.170 <0.210 249 <0.470 68.8 15.6 <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
MW-5 01/10/23 14.6 62.8 68.3 413 15.6 25.5 98.2 88.6 2.1 4.67 8.63 109 28.9 <0.00337 2.63 5.05 <10.0 545 644 475 NA*NA*NA*
MW-6 01/10/23 26.0 148.0 48.9 206 38.9 13.5 71.8 15.7 0.319 J 3.90 4.60 44.7 9.10 <0.00342 <1.26 1.53 J 18.9 266 189 114 <29.4 <129 <63.6
MW-7 01/10/23 382 2,130 448 2,620 440 157 532 J 139 4.96 19.1 37.4 594 171 0.0133 JQ 8.67 15.3 <10.0 1,550 1,060 1,240 58.1 J <124 208
MW-8 01/10/23 2.28 4.2 4.8 20.7 0.228 J <0.470 <1.90 4.44 J <0.180 0.364 J 0.89 5.61 2.30 <0.00333 <1.17 <0.682 34.8 <11.5 55.3 J 13.6 J NA*NA*NA*
TW-1 01/10/23 0.57 0.7 0.473 J 2.03 0.972 J <0.470 3.08 J 5.47 J <0.180 <0.180 <0.190 0.918 0.305 J <0.00343 <1.26 <0.735 <10.0 <11.5 <25.8 <4.02 <29.1 <128 <63.2
06/23/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR NA <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
01/10/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• 2B Standard: North Carolina surface water standards for Class C waters specified in T15A NCAC 2B.0200 or EPA Nathional Criteria.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the reported contaminant concentration exceeded the MAC.
• Results in italics indicate the reported contaminant concentration exceeded the GCL.
• J: Estimated value.
• J: Relative percent difference >40% dual column results.
• NE: Not established.
• NA: Not analyzed.
• NR: Not reported.
• Refer to laboratory report for other detectable concentrations which did not exceed the MAC.
• *Analysis of MADEP EPH was not performed on the ground water samples collected on 01/10/23 from MW-5 and MW-8 due to limited volume.
GCL (μg/l)MTBENaphthaleneContaminant of Concern
MAC (μg/l)1-Methylnaphthalenetert-Amyl alcohol(TAA)BenzeneTolueneEthylbenzene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneEDBn-PropylbenzeneIsopropylbenzenetert-Butyl alcohol(TBA)n-ButylbenzeneMADEP EPH
C9-C18 AliphaticsC19-C36 AliphaticsC11-C22 AromaticsTABLE 7
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
BREEDEN'S 66 (INCIDENT NO. 48332)
Facility ID #: 00-0-000000347
XylenesC9-C10 AromaticsC9-C12 AliphaticsAnalytical Method MADEP VPHEPA 625.1
LeadC5-C8 Aliphatics2-MethylnaphthaleneEPA 6200B
MW-1
MW-2
MW-3
MW-4
Trip Blank
Page 1 of 1
Date: 01/26/23
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Free Product
Thickness
(ft.)
Groundwater
Elevation
(ft.)
Comments
04/13/22 16.79 ---83.21
06/23/22 17.53 ---82.47
01/10/23 19.58 ---80.42
06/23/22 19.03 ---81.95
01/10/23 20.54 ---80.44
06/23/22 17.72 ---81.78
01/10/23 19.20 ---80.30
06/23/22 18.41 ---82.09
01/10/23 20.07 ---80.43
MW-5 01/03/23 01/10/23 10 10-25 25 99.13 18.90 ---80.23
MW-6 01/04/23 01/10/23 10 10-25 25 98.41 18.24 ---80.17
MW-7 01/04/23 01/10/23 10 10-25 25 98.08 17.93 ---80.15
MW-8 01/05/23 01/10/23 10 10-25 25 99.98 19.65 ---80.33
TW-1 01/06/23 01/10/23 10 50-55 55 99.81 22.15 ---77.66
Notes:
• ft BGS : feet below ground surface.
• NA: Not available.
• NM: Not measured.
10
10
10
04/13/22
06/23/22
06/23/22
100.50
100.00
100.98
99.50
10-25
10-25
10-25
10-25
25
25
25
25MW-4 06/23/22
MW-1
MW-2
MW-3
TABLE 8
WELL CONSTRUCTION AND GAUGING INFORMATION
BREEDEN'S 66 (INCIDENT NO. 48332)
Facility ID #: 00-0-000000347
10
Page 1 of 1
Facility ID#: 0-000347
ft/min ft/day ft/day ft/year
MW-1 3.565E-05 5.134E-02 1.03E-03 3.75E-01
MW-8 5.749E-04 8.279E-01 1.66E-02 6.04E+00
Averages 3.053E-04 4.396E-01 8.792E-03 3.209E+00
TW-1 7.378E-04 1.062E+00 1.06E-02 3.88E+00
Note:
Seepage velocities calculated using the equation v = K(dh/dl)/ne , where:
K = hydraulic conductivity
ne = effective porosity = 0.15 for the Type II wells; 0.30 for Type III well
dh/dl = hydraulic gradient = 0.003 ft/ft
TABLE 9
SUMMARY OF SLUG TEST ANALYSES
BREEDEN'S 66 (INCIDENT NO. 48332)
Date : 01/30/23
Well Hydraulic Conductivity (K)Seepage Velocity (v)
Page 1 of 1

APPENDICES

APPENDIX A
State Correspondence
5991 Received AUG 18 2022
5991 Received OCT 24 202
5991 Received NOV 15 2022

APPENDIX B
Site-Specific Health and Safety Plan

1
GEOLOGICALRESOURCES,INC.
SiteSpecificHealthandSafetyPlan

1.0GeneralInformation:
a.Projectname:Breeden’s66
b.Location:22900AberdeenRoad,Laurinburg,ScotlandCounty
c.GRIJob#:5991

2.0ProjectOrganization:
a.SiteSupervisor/H&SOfficer:
b.ProjectManager:WilliamRegenthal
c.Subcontractor(s):

3.0SafetyPlanPreparation:
a.Preparedby&date:WilliamRegenthal,04/07/22
b.Reviewed/approvedby&date:JustinRadford,04/07/22

4.0SiteHistoryandDescription:
a.Typeofsite(i.e.,spill,leakingUSTsystem,etc.):LSA
b.Site/projectdescription:PetroleumRetailFacility

5.0PotentialHazards:
PhysicalHazards:(check)
SlipsXOverheadXExplosionXSunburnXElectricity
XTripsutilitiesXNoiseXColdWeatherXPressurizedline/vessels
XFallsXUndergroundXPinchpointsHotWeather
XFireutilitiesXBurnsXCrush

ChemicalHazards:(check)
XGasolineUsedOil
XDieselSolvents
KeroseneAntifreeze
NewOilAcid(samplepreservative)

Equipment/Vehicular/Other:(i.e.,Geoprobe,drillrig,backhoe,trackhoe,traffic,skidsteeretc.)

Geoprobe/DrillRig

BiologicalHazards:(i.e.,toxicinsects,spiders,poisonousplants,poisonoussnakes,aggressivedogs)

2
6.0SiteOrganizationandSafetyControl:(Evaluatetheneedforsitecontroltoprotect
personsfromexposuretohazardousconditions;i.e.workpermits,cones,barricadetape,
exclusionzones,etc.)
a.Workarea(s)identified:__Entiresite_________________________________________
b.Workareamarked_____Yes_____No
c.Workareabarricaded_____Yes_____No
d.Supportareaestablished:___n/a_____________________________________________
e.Entryandescaperoutesidentified:__n/a______________________________________
f.Rallypointidentified:_____Yes____NoLocation:____________________________
g.Emergencyshut-offforwateridentified_____Yes_____No
h.Emergencyfuelshut-offidentified_____Yes_____No
i.Sitemapattached:_____Yes_____No
**EmergencyResponseProcedures**
Action(i.e.shutoffallpowerequipment)Assembleatrallypoint
Call911formedicalorutilitiesemergencyDoNOTenterconfinedspaces
Discusswhattodoif…..cutproductline,waterline,cable/electricline

7.0JobActivitiesinWorkPlan:
USTRemovalXSoilSamplingManualFPRecovery
SoilExcavationSystemO&MOther(specify)
XPoweredDrillingMMPE/AFVR__________________
XHandAugeringXWatersampling__________________

8.0RequiredEducationand/orTraining:
XOSHA40hrXAnnual8hrRefresherOSHASiteSupervisor

9.0AirMonitoring:
If, in the opinion of the site supervisor, petroleum hydrocarbon vapor concentrationsare
excessive,siteactivitieswillceaseuntilpetroleumhydrocarbonvaporconcentrationsdiminishto
acceptablelevels.

10.0Equipment:
FID/PID_CombustiblegasindicatorXInterfaceProbe
O2meterXOtherWaterlevelMeter

11.0PersonnelProtectionEquipment:
XHardhatRubberbootsRespiratorXHearing
XSafetyglassesXWorkglovesSunscreenprotection
XSteeltoebootsXFirstaidkitRepellentXNitrile
TyveksuitXFireextinguisherXDustmaskgloves

12.0DecontaminationProcedures:(evaluateneedfordecon,describeprocedures)
Usenew,cleanglovestocollecteachsample

3
13.0EmergencyContacts:
a.LocalAssistance:
SitePhoneFireDepartment911
Police911Ambulance911
WaterDepartmentSanitarySewer
NaturalGasPowerCompany

NearestHospitalwithEmergencyRoom(directionsattached)
NameScotlandMemorialHospital
Address500LauchwoodDrive
Laurinburg,NC
Number910-291-7000

b.NationalorRegionalSourcesofAssistance:
1)GeologicalResources,Inc.[phone]
2)Chemtrec(24Hours)[phone]
3)BureauofExplosives(24Hours)[phone]
4)NationalResponseCenter,NRC(800)424-8802
(Oil/HazardousSubstances)
5)DOT,Off.OfHaz.Operations(800)467-4922

14.0Signatures:

Thisplanhasbeenreviewedbyallon-sitepersonnelandallprovisionsareclear(signatures
required).

ProjectManager:
SiteSupervisor:
Otherpersonnel:

4
15.0Amendments:

a.SiteSpecificHealthandSafetyPlansarebasedoninformationavailableatthetimeof
plan preparation. Unexpected conditions may arise. It is important that personal
protectivemeasuresbethoroughlyassessedpriortoandduringtheplannedactivities.
Unplannedactivitiesand/orchangesinthehazardstatusshouldinitiateareviewofthis
planandmayresultinmajorchangestoit.
b.Changesinthehazardstatusorunplannedactivitiesaretobesubmittedon“Amendment
totheSiteSpecificHealthandSafetyPlan”whichisincludedbellow.
c.AmendmentmustbeapprovedbytheProjectManagerpriortoimplementationofthe
amendment.

AMENDMENTTOTHESITESPECIFICHEALTHANDSAFETYPLAN

A.Changesinfieldactivitiesorhazards:

B.Proposedamendment:

C.Approval:

Proposedby:___________________________________date______________________

Approvedby:___________________________________date_____________________

Amendmentnumber:____________________________

Amendmenteffectivedate:_______________________

APPENDIX C
UVF Analytical Report

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
UVF Trilogy Analytical Report

Samples Collected: January 5, 2023
Samples Analyzed: January 6, 2023
Site Name: Breeden’s 66
Site Address: 22900 Aberdeen Highway, Laurinburg, NC
GRI Project Number: 5991

January 6, 2023

Kyle Perry
Operator

Technical Procedures
Calibration
The UFV Trilogy has standard calibrations stored for the following analysis:
· GRO
· DRO
· Total PAH
· Target PAH
· Heavy PAH
Prior to use, calibration standards are used to perform a 5-point verification on the factory stored
calibrations for GRO and DRO. The calibration standards used are as follows:
GRO
· 0.5 ppm
· 1 ppm
· 3 ppm
· 5 ppm
· 10 ppm
DRO
· 0.1 ppm
· 0.5 ppm
· 1 ppm
· 3 ppm
· 5 ppm
Operation
Sample Extraction
· 5mg of soil are weighed into a clean extraction jar
· Methanol is added to the extraction jar to create a 2x or 4x dilution
o 2x Dilution: 10 mL of methanol
o 4x Dilution: 20 mL of methanol
· The extraction jar is shaken for several minutes to thoroughly mix the soil with solvent
(methanol)
· The mixture is allowed to settle for several minutes
· A clean syringe is used to draw liquid from the extraction jar
· A clean filter is attached to the end of the syringe and the liquid dispensed through the filter
into a clean test tube
· This liquid is referred to as the extraction
Dilution Preparation
· An adjustable micropipette is used to precisely measure out the amount of extract needed for
the dilution
· The measured out amount of the extract is added to a clean test tube and methanol is added
dilute the extract. Examples of dilutions are shown below:

Extract Amount
500 μL
200 μL
100 μL
50 μL
25 μL

Add Solvent to the
5 mL line
5 mL line
5 mL line
5 mL line
5 mL line
2x Extract
Dilution Factor
20x
50x
100x
200x
400x
4x Extract
Dilution Factor
40x
100x
200x
400x
800x

Technical Procedures
Sample Analyzation
· The dilution is shaken to thoroughly mix, then poured into a clean glass cuvette
· The desired module is inserted into the UVF Trilogy and the corresponding factory calibration is
selected
· “Measure Fluorescence” is pressed on the touchscreen and the reading is recorded
· The reading should be between the concentrations of the calibration standards (GRO: 0.5-10
ppm; DRO 0.1-5 ppm)
o Reading below the calibration standard range are recorded as below the detection limit
§ Detection Limit = (lower range of calibration standards range) x dilution factor
(i.e. a GRO sample with a 100x dilution factor has a detection limit of 50 ppm)
o Readings above the calibration standard range should be further diluted and reanalyzed
o Negative readings are an indication of quenching (see below)
· The reading is multiplied by the dilution factor to calculate the final concentration
· Check suspected contaminated samples for quenching by running additional dilutions
o According to the siteLAB Quick Reference Guide:
“Quenching” can occur when the detector is swamped by too many hydrocarbons or
organic interferences, producing low or negative concentrations. Test the sample at
multiple dilutions to confirm results are linear and accurate.”
QA/QC
Method Blank
· A method blank of methanol will be analyzed following calibration and following the last sample
analyzed each day
Duplicates
· One duplicate will be analyzed for every 20 samples
· The duplicate will be prepared from the extract of the sample and diluted to the same factor as
the sample analyzed
Project Name:Date Collected:
Project Number:Date Analyzed:
Project Manager:Operator:
Sample ID Matrix
Dilution
Factor x
GRO
Output
(ppm)
=GRO Value
(mg/Kg)
Dilution
Factor x
DRO
Output
(ppm)
=DRO Value
(mg/Kg)
SB-2-16'Soil 20 0.58 11.6 20 0.27 5.4
SB-2-18'Soil 40 <0.5 <20 40 0.11 4.4
SB-2-20'Soil 40 <0.5 <20 40 0.11 4.4
SB-2-24'Soil 40 0.62 24.8 40 0.1 4.0
SB-3-8'Soil 40 0.54 21.6 40 0.11 4.4
SB-3-14'Soil 20 <0.5 <10 20 0.14 2.8
SB-3-16'Soil 20 1.21 24.2 20 0.24 4.8
SB-3-18'Soil 40 <0.5 <20 40 0.13 5.2
SB-3-22'Soil 100 6.41 641 100 2.59 259
SB-3-24'Soil 40 1.98 79.2 40 0.52 20.8
SB-4-22'Soil 40 <0.5 <20 40 0.1 4.0
SB-4-24'Soil 40 0.69 27.6 40 0.1 4.0
SB-5-18'Soil 20 0.58 11.6 20 0.1 2.0
SB-5-22'Soil 40 1.96 78.4 40 2.09 83.6
SB-5-24'Soil 20 0.51 10.2 20 0.16 3.2
DUP-A Soil 20 0.53 10.6 20 0.15 3.0
Soil <0 <0
Soil <0 <0
Soil <0 <0
UVF Analytical Report
siteLAB UVF Trilogy
1/6/2023
1/5/2023
Kyle Perry
Breeden's 66
5991
William Regenthal
Site:
Breeden's 66
Report Date:
1/6/2023
Page:
1 of 1

APPENDIX D
RTEs, Well Permits, Well Construction Records, and Subsurface Logs

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green St., Suite 714 | Fayetteville, North Carolina 28301-5043
910.433.3300

15 December 2022

Mr. William Regenthal c/o
Geological Resources, Inc.
3502 Hayes Rd.
Monroe, NC 28110

SUBJECT: Well Construction Permit No. WM0601230
3 Monitoring Wells
Laurinburg, Scotland Co., N.C.

Mr. Regenthal:
In accordance with the application prepared by you on 1 December 2022 and received in the
Fayetteville Regional Office on 2 December 2022; we are forwarding herewith Well Construction
Permit No. WM0601230 dated 15 December 2022 issued to Quality Oil & Gas at 203 W. Broad Ave.,
Rockingham, NC 28379 for the construction of three (3) monitoring wells located at 22900
Aberdeen Rd., Laurinburg, NC (Scotland Co. Pin No. 02-0314-01-034).

This Permit will be effective from the date of its issuance for one year and shall be subject to the
conditions and limitations as specified therein.

Please note that according to North Carolina Administrative Code, Title 15A, Subchapter 2C,
Section .0105 (g), "it is the responsibility of the well owner or his agent to see that a permit is secured
prior to the commencement of construction of any well for which a permit is required."

Issuance of this permit does not constitute approval of the subject wells for reimbursement from Trust
Funds.

If any parts, requirements, or limitations contained in this Permit are unacceptable to you, you have
the right to an adjudicatory hearing before a hearing officer upon written demand to the Director
within 30 days following receipt of this Permit, identifying the specific issues to be contended. Unless
such demand is made, this Permit shall be final and binding.

Sincerely,

Trent Allen, Regional Supervisor
Division of Water Resources – Water Quality Programs

Enclosure
cc: FRO Files

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green Street, Suite 714 | Fayetteville, North Carolina 28301-5043
910-433-3300

NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES – WATER QUALITY PROGRAMS PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL
In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and other
applicable Laws, Rules and Regulations.
PERMISSION IS HEREBY GRANTED TO

Quality Oil & Gas, Inc.

FOR THE CONSTRUCTION OF A MONITORING WELL SYSTEM owned by Quality Oil & Gas at 203 W.
Broad Ave., Rockingham, NC 28379 for the construction of the three (3) monitoring wells located at
22900 Aberdeen Rd., Laurinburg, NC (Scotland Co. Pin No. 02-0314-01-034). This Permit is issued
in accordance with the application received on 2 December 2022, in conformity with specifications
and supporting data, all of which are filed with the Department of Environmental Quality and are
considered integral parts of this Permit.
This Permit is for well construction only and does not waive any provision or requirement of any
other applicable law or regulation. Construction of any well under this Permit shall be in strict
compliance with the North Carolina Well Construction Regulations and Standards (15A NCAC
02C .0100), and other State and Local Laws and regulations pertaining to well construction.

If any requirements or limitations specified in this Permit are unacceptable, you have a right to an
adjudicatory hearing upon written request within 30 days of receipt of this Permit. The request must
be in the form of a written petition conforming to Chapter 150B of the North Carolina General
Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North
Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding. This Permit will be effective for one year from the date of its issuance and shall be subject to other
specified conditions, limitations, or exceptions as follows:

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green Street, Suite 714 | Fayetteville, North Carolina 28301-5043
910-433-3300

1. Issuance of this Permit does not obligate reimbursement from State trust
funds, if these wells are being installed as part of an investigation for
contamination from an underground storage tank or dry cleaner incident.
2. Issuance of this Permit does not supersede any other agreement, permit, or
requirement issued by another agency.
3. The well(s) shall be located and constructed as shown on the attachments
submitted as part of the Permit application.
4. Each well shall have a Well Contractor Identification Plate in
accordance with 15A NCAC 02C .0108(o).
5. Well construction records (GW-1) for each well shall be submitted to
the Division of Water Resources Information Processing Unit within 30 days
of the well completion.
6. When the well is discontinued or abandoned, it shall be abandoned in
accordance with 15A NCAC 02C .0113 and a well abandonment record (GW-
30) shall be submitted to the Division of Water Resources Information
Processing Unit within 30 days of the well abandonment.

Permit issued the 15th day of December 2022
FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

_______________________________________________
Trent Allen, Regional Supervisor
Division of Water Resources – Water Quality Programs
By Authority of the Environmental Management Commission
Permit No. # WM0601230

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green St., Suite 714 | Fayetteville, North Carolina 28301-5043
910.433.3300

15 December 2022

Mr. William Regenthal c/o
Geological Resources, Inc.
3502 Hayes Rd.
Monroe, NC 28110

SUBJECT: Well Construction Permit No. WM0601231
2 “Type 2” Monitoring Wells
Laurinburg, Scotland Co., N.C.

Mr. Regenthal:
In accordance with the application prepared by you on 1 December 2022 and received in the
Fayetteville Regional Office on 2 December 2022; we are forwarding herewith Well Construction
Permit No. WM0601231 dated 15 December 2022 issued to Quality Oil & Gas at 203 W. Broad Ave.,
Rockingham, NC 28379 for the construction of two (2) monitoring wells located at 22900 Aberdeen
Rd., Laurinburg, NC (Scotland Co. Pin No. 02-0316-01-001).

This Permit will be effective from the date of its issuance for one year and shall be subject to the
conditions and limitations as specified therein.

Please note that according to North Carolina Administrative Code, Title 15A, Subchapter 2C,
Section .0105 (g), "it is the responsibility of the well owner or his agent to see that a permit is secured
prior to the commencement of construction of any well for which a permit is required."

Issuance of this permit does not constitute approval of the subject wells for reimbursement from Trust
Funds.

If any parts, requirements, or limitations contained in this Permit are unacceptable to you, you have
the right to an adjudicatory hearing before a hearing officer upon written demand to the Director
within 30 days following receipt of this Permit, identifying the specific issues to be contended. Unless
such demand is made, this Permit shall be final and binding.

Sincerely,

Trent Allen, Regional Supervisor
Division of Water Resources – Water Quality Programs

Enclosure
cc: FRO Files

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green Street, Suite 714 | Fayetteville, North Carolina 28301-5043
910-433-3300

NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES – WATER QUALITY PROGRAMS PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL
In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and other
applicable Laws, Rules and Regulations.
PERMISSION IS HEREBY GRANTED TO

Quality Oil & Gas, Inc

FOR THE CONSTRUCTION OF A MONITORING WELL SYSTEM owned by Quality Oil & Gas at 203 W.
Broad Ave., Rockingham, NC 28379 for the construction of the two (2) monitoring wells located at
22900 Aberdeen Rd., Laurinburg, NC (Scotland Co. Pin No. 02-0316-01-001). This Permit is issued
in accordance with the application received on 2 December 2022, in conformity with specifications
and supporting data, all of which are filed with the Department of Environmental Quality and are
considered integral parts of this Permit.
This Permit is for well construction only and does not waive any provision or requirement of any
other applicable law or regulation. Construction of any well under this Permit shall be in strict
compliance with the North Carolina Well Construction Regulations and Standards (15A NCAC
02C .0100), and other State and Local Laws and regulations pertaining to well construction.

If any requirements or limitations specified in this Permit are unacceptable, you have a right to an
adjudicatory hearing upon written request within 30 days of receipt of this Permit. The request must
be in the form of a written petition conforming to Chapter 150B of the North Carolina General
Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North
Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding. This Permit will be effective for one year from the date of its issuance and shall be subject to other
specified conditions, limitations, or exceptions as follows:

North Carolina Department of Environmental Quality | Division of Water Resources
Fayetteville Regional Office | 225 Green Street, Suite 714 | Fayetteville, North Carolina 28301-5043
910-433-3300

1. Issuance of this Permit does not obligate reimbursement from State trust
funds, if these wells are being installed as part of an investigation for
contamination from an underground storage tank or dry cleaner incident.
2. Issuance of this Permit does not supersede any other agreement, permit, or
requirement issued by another agency.
3. The well(s) shall be located and constructed as shown on the attachments
submitted as part of the Permit application.
4. Each well shall have a Well Contractor Identification Plate in
accordance with 15A NCAC 02C .0108(o).
5. Well construction records (GW-1) for each well shall be submitted to
the Division of Water Resources Information Processing Unit within 30 days
of the well completion.
6. When the well is discontinued or abandoned, it shall be abandoned in
accordance with 15A NCAC 02C .0113 and a well abandonment record (GW-
30) shall be submitted to the Division of Water Resources Information
Processing Unit within 30 days of the well abandonment.

Permit issued the 15th day of December 2022
FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

_______________________________________________
Trent Allen, Regional Supervisor
Division of Water Resources – Water Quality Programs
By Authority of the Environmental Management Commission
Permit No. # WM0601231

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-5
6"
25
Well installed at completion
0 2 Silt Brown Dry None
2 9 Silty Clay Red Dry None
9 15 Fine Sand Tan Dry None
15 18 Silty Clay Brown Dry None
18 21 Sandy Silt Tan Moist None
21 25 Fine Sand Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-5
6"
99.13
18.90
9 25
7 9
0 7
0 0 0
0 10 2
10 25 2
7
9
25
10
25

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
1/3/23 MW-5
Breeden's 66 00-0-0000000347
22900 Aberdeen Rd, Laurinburg 28352
Scotland 02031401034
34.865101 79.455527
25
18.90
6"
Solid Stem Auger
0 0 0
0 10 2 Sch 40 PVC
10 25 2 0.010 Sch 40 PVC
0 7 grout pour
7 9 bentonite pour
9 25 #2 Sand Pour
0 2 Silt
2 9 Silty Clay
9 15 Fine Sand
15 18 Silty Clay
18 21 Sandy Silt
21 25 Fine Sand
1/3/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-6
6"
25
Well installed at completion
0 2 Silt Brown Dry None
2 10 Silty Clay Red Dry None
10 15 Silt Tan Dry None
15 19 Silty Clay Brown Dry None
19 21 Sandy Silt Tan Moist None
21 25 Fine Sand Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-6
6"
98.41
18.24
9 25
7 9
0 7
0 0 0
0 10 2
10 25 2
7
9
25
10
25

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
1/3/23 MW-6
Breeden's 66 00-0-0000000347
22900 Aberdeen Rd, Laurinburg 28352
Scotland 02031401034
34.865101 79.455527
25
18.24
6"
Solid Stem Auger
0 0 0
0 10 2 Sch 40 PVC
10 25 2 0.010 Sch 40 PVC
0 7 grout pour
7 9 bentonite pour
9 25 #2 Sand Pour
0 2 Silt
2 10 Silty Clay
10 15 Silt
15 19 Silty Clay
19 21 Sandy Silt
21 25 Fine Sand
1/3/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-7
6"
25
Well installed at completion
0 2 Silt Brown Dry None
2 9 Silty Clay Red Dry None
9 14 Silt Tan Dry None
14 18 Silty Clay Brown Dry None
18 21 Sandy Silt Tan Moist None
21 25 Fine Sand Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-7
6"
98.08
17.93
9 25
7 9
0 7
0 0 0
0 10 2
10 25 2
7
9
25
10
25

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
1/3/23 MW-7
Breeden's 66 00-0-0000000347
22900 Aberdeen Rd, Laurinburg 28352
Scotland 02031401034
34.865101 79.455527
25
17.93
6"
Solid Stem Auger
0 0 0
0 10 2 Sch 40 PVC
10 25 2 0.010 Sch 40 PVC
0 7 grout pour
7 9 bentonite pour
9 25 #2 Sand Pour
0 2 Silt
2 9 Silty Clay
9 14 Silt
14 18 Silty Clay
18 21 Sandy Silt
21 25 Fine Sand
1/3/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-8
6"
25
Well installed at completion
0 0.4 Asphalt
0.4 9 Silty Clay Red Dry None
9 14 Silt Tan Dry None
14 18 Silty Clay Brown Dry None
18 21 GS/TOC @20'Silty Clay Tan Moist None
21 25 Coarse Sandy Clay Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-8
6"
99.98
19.65
9 25
7 9
0 7
0 0 0
0 10 2
10 25 2
7
9
25
10
25

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
1/3/23 MW-8
Breeden's 66 00-0-0000000347
22900 Aberdeen Rd, Laurinburg 28352
Scotland 02031401034
34.865101 79.455527
25
19.65
6"
Solid Stem Auger
0 0 0
0 10 2 Sch 40 PVC
10 25 2 0.010 Sch 40 PVC
0 7 grout pour
7 9 bentonite pour
9 25 #2 Sand Pour
0 0.4 Asphalt
0.4 9 Silty Clay
9 14 Silt
14 18 Silty Clay
18 21 Silty Clay
21 25 Coarse Sandy Clay
1/3/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Hollow Step Auger
4548-A
TW-1
6.25"
55'
Well installed at completion
0 0.6 Asphalt
0.6 8 Silty Clay Red Dry None
8 12 Silt Tan Dry None
12 15 Fine Sand Tan Dry None
15 20 Silty Clay Brown Dry None
20 23 Sandy Silt Tan Moist None
23 31 Silty Clay Tan Wet None
31 37 Coarse Sand Tan Wet None
37 47 Clay Gray Moist None
47 55 Coarse Sand Gray Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
Sand Outer Casing
Bentonite
Grout
Inner Casing
Screen
Screen
Bentonite
Sand
DIAGRAM - TELESCOPING WELL
Grout
Outer
Casing
Inner Casing
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Matt Steele
Hollow Step Auger
4548-A
TW-1
6.25"
99.81
22.15
48 55
46 48
0 46
0 40 5
0 50 2
50 55 2
46
48
55
40
50
55

WELLCONSTRUCTIONRECORD
Thisformcanbeusedforsingleormultiplewells
FormGW-1 NorthCarolinaDepartmentofEnvironmentandNaturalResources–DivisionofWaterResources RevisedAugust2013
1.WellContractorInformation:

WellContractorName

NCWellContractorCertificationNumber

CompanyName

2.WellConstructionPermit#:
List all applicable well permits (i.e. County, State, Variance, Injection, etc.)

3.WellUse(checkwelluse):
WaterSupplyWell:
□Agricultural□Municipal/Public
□Geothermal(Heating/CoolingSupply)□ResidentialWaterSupply(single)
□Industrial/Commercial□ResidentialWaterSupply(shared)
□Irrigation
Non-WaterSupplyWell:
□Monitoring□Recovery
InjectionWell:
□AquiferRecharge□GroundwaterRemediation
□AquiferStorageandRecovery□SalinityBarrier
□AquiferTest□StormwaterDrainage
□ExperimentalTechnology□SubsidenceControl
□Geothermal(ClosedLoop)□Tracer
□Geothermal(Heating/CoolingReturn)□Other(explainunder#21Remarks)

4.DateWell(s)Completed:____________WellID#______________________

5a.WellLocation:

Facility/OwnerNameFacilityID#(ifapplicable)

PhysicalAddress,City,andZip

CountyParcelIdentificationNo.(PIN)

5b.LatitudeandLongitudeindegrees/minutes/secondsordecimaldegrees:
(ifwellfield,onelat/longissufficient)

N W

6.Is(are)thewell(s):□Permanentor□Temporary

7.Isthisarepairtoanexistingwell:□Yesor□No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8.Numberofwellsconstructed:
For multiple injection or non-water supply wells ONLY with the same construction, you can
submit one form.

9.Totalwelldepthbelowlandsurface: (ft.)
For multiple wells list all depths if different (example- 3@200’ and 2@100′)

10.Staticwaterlevelbelowtopofcasing:(ft.)
If water level is above casing, use “+”

11.Boreholediameter:(in.)

12.Wellconstructionmethod:
(i.e.auger,rotary,cable,directpush,etc.)

FORWATERSUPPLYWELLSONLY:
13a.Yield(gpm) Methodoftest:

13b.Disinfectiontype:Amount:

14.WATERZONES
FROMTODESCRIPTION
ft.ft.
ft.ft.
15.OUTERCASING(formulti-casedwells)ORLINER(ifapplicable)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
16.INNERCASINGORTUBING(geothermalclosed-loop)
FROMTODIAMETERTHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
17.SCREEN
FROMTODIAMETERSLOTSIZETHICKNESSMATERIAL
ft.ft.in.
ft.ft.in.
18.GROUT
FROMTOMATERIALEMPLACEMENTMETHOD&AMOUNT
ft.ft.
ft.ft.
ft.ft.
19.SAND/GRAVELPACK(ifapplicable)
FROMTOMATERIALEMPLACEMENTMETHOD
ft.ft.
ft.ft.
20.DRILLINGLOG(attachadditionalsheetsifnecessary)
FROMTODESCRIPTION(color,hardness,soil/rocktype,grainsize,etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21.REMARKS

22.Certification:

SignatureofCertifiedWellContractorDateBy signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Sitediagramoradditionalwelldetails:Youmayusethebackofthispagetoprovideadditionalwellsitedetailsorwell
constructiondetails.Youmayalsoattachadditionalpagesifnecessary.

SUBMITTALINSTUCTIONS

24a.ForAllWells:Submit this formwithin30daysof completionof well
constructiontothefollowing:
DivisionofWaterResources,InformationProcessingUnit,
1617MailServiceCenter,Raleigh,NC27699-1617
24b.ForInjectionWellsONLY:Inadditiontosendingtheformtotheaddressin
24aabove,alsosubmitacopyofthisformwithin30 daysofcompletionof well
constructiontothefollowing:

DivisionofWaterResources,UndergroundInjectionControlProgram,
1636MailServiceCenter,Raleigh,NC27699-1636
24c.ForWaterSupply&InjectionWells:
Also submitone copyof this form within30days ofcompletionof
wellconstructiontothecountyhealthdepartment ofthecountywhere
constructed.
ForInternalUseONLY:
Matt Steele
4548-A
Geological Resources, Inc.
1/3/23 TW-1
Breeden's 66 00-0-0000000347
22900 Aberdeen Rd, Laurinburg 28352
Scotland 02031401034
34.865101 79.455527
55
22.15
6.25"
Hollow Step Auger
0 40 5
0 50 2 Sch 40 PVC
50 55 2 0.010 Sch 40 PVC
0 46 grout pour
46 48 bentonite pour
48 55 #2 Sand Pour
0 0.6 Asphalt
0.6 8 Silty Clay
8 12 Silt
12 15 Fine Sand
15 20 Silty Clay
20 23 Sandy Silt
23 31 Silty Clay
31'-37' - Coarse sand; 37'-47' - clay; 47'-55' - coarse sand
1/3/23
_______________
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Sam Bowers
Direct Push
3220-A
SB-1
2.375"
25
Abandoned with native soil
0 0.4 Asphalt
0.4 10 Silty Clay Red Dry None
10 15 Silt Tan Dry None
15 19 Silty Clay Brown Dry None
19 22 Silty Clay Tan Moist None
22 25 Sandy Clay Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Sam Bowers
Direct Push
3220-A
SB-2
2.375"
25
Abandoned with native soil
0 0.4 Asphalt
0.4 10 Silty Clay Red Dry None
10 15 Silt Tan Dry None
15 19 Silty Clay Brown Dry None
19 22 Silty Clay Tan Moist None
22 25 Sandy Clay Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Sam Bowers
Direct Push
3220-A
SB-3
2.375"
25
Abandoned with native soil
0 0.4 Asphalt
0.4 10 Silty Clay Red Dry None
10 15 Silt Tan Dry None
15 19 Silty Clay Brown Dry None
19 22 Silty Clay Tan Moist None
22 25 Sandy Clay Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Sam Bowers
Direct Push
3220-A
SB-4
2.375"
25
Abandoned with native soil
0 0.4 Asphalt
0.4 9 Silty Clay Red Dry None
9 14 Silt Tan Dry None
14 18 Silty Clay Brown Dry None
18 21 Silty Clay Tan Moist None
21 25 Sandy Clay Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Sam Bowers
Direct Push
3220-A
SB-5
2.375"
25
Abandoned with native soil
0 2 Silt Brown Dry None
2 9 Silty Clay Red Dry None
9 15 Silt Tan Dry None
15 18 Silty Clay Brown Dry None
18 21 Sandy Clay Tan Moist None
21 25 Sandy Clay Tan Wet None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
Breeden's 66
5991
1/3/23
Jacob Brooks
Geological Resources, Inc.
Sam Bowers
Direct Push
3220-A
SB-6
2.375"
25
Abandoned with native soil
0 2 Silt Brown Dry None
2 10 Silty Clay Red Dry None
10 15 Silt Tan Dry None
15 19 Silty Clay Brown Dry None
19 21 Sandy Clay Tan Moist None
21 25 Sandy Clay Tan Wet None

Photo 1: Preclearing Photo 2: Completion

APPENDIX E
Laboratory Analytical Report

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

1/27/2023

GeologicalResources,Inc.
WilliamRegenthal
113WestFiretowerRoad,SuiteG
Winterville,NC,28590

Ref: AnalyticalTesting
LabReportNumber:23-011-0104
ClientProjectDescription:Breedens66
GRI#5991

DearWilliamRegenthal:

WaypointAnalytical,LLC(Charlotte)receivedsample(s)on1/11/2023fortheanalysespresentedinthe
followingreport.

Theabovereferencedprojecthasbeenanalyzedperyourinstructions.Theanalyseswereperformedin
accordancewiththeapplicableanalyticalmethod.

Theanalyticaldatahasbeenvalidatedusingstandardqualitycontrolmeasuresperformedasrequiredbythe
analyticalmethod.QualityAssurance,methodvalidations,instrumentationmaintenanceandcalibrationforall
parameterswereperformedinaccordancewithguidelinesestablishedbytheUSEPA(including40CFR136
MethodUpdateRuleMay2021)unlessotherwiseindicated.

Certainparameters(chlorine,pH,dissolvedoxygen,sulfite...)arerequiredtobeanalyzedwithin15minutesof
sampling.Usually,butnotalways,anyfieldparameteranalyzedatthelaboratoryisoutsideofthisholdingtime.
Refertosampleanalysistimeforconfirmationofholdingtimecompliance.

TheresultsareshownontheattachedReportofAnalysis(s).Resultsforsolidmatricesarereportedonanas-
receivedbasisunlessotherwiseindicated.Thisreportshallnotbereproducedexceptinfullandrelatesonlyto
thesamplesincludedinthisreport.

Pleasedonothesitatetocontactmeorclientservicesifyouhaveanyquestionsorneedadditionalinformation.

Sincerely,
DanyaleLove
ProjectManager
Page 1 of 164
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State Program Lab ID Expiration Date
02/28/202340750State ProgramAlabama
02/07/202388-0650State ProgramArkansas
06/30/20232904State ProgramCalifornia
06/30/2023E871157State Program - NELAPFlorida
02/18/2023C044State ProgramGeorgia
06/30/202304015State ProgramGeorgia
10/10/2023200078State Program - NELAPIllinois
06/30/202380215State ProgramKentucky
12/31/2023KY90047State ProgramKentucky
12/31/2023LA037State Program - NELAPLouisiana
06/30/202304015State Program - NELAPLouisiana
02/11/2023MSState ProgramMississippi
07/31/202347701State ProgramNorth Carolina
12/31/2023415State ProgramNorth Carolina
05/31/202368-03195State Program - NELAPPennsylvania
06/30/202384002State ProgramSouth Carolina
11/14/202502027State ProgramTennessee
09/30/2023T104704180State Program - NELAPTexas
06/30/202300106State ProgramVirginia
09/14/2023460181State Program - NELAPVirginia
Page 1 of 1 00016/23-011-0104
Page 2 of 164
Report Number:
Sample Summary Table
Client Project Description:
23-011-0104
Breedens 66
GRI # 5991
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
01/10/2023 13:34Aqueous 97303 MW-1 01/11/2023 15:04
01/10/2023 13:15Aqueous 97304 MW-2 01/11/2023 15:04
01/10/2023 13:22Aqueous 97305 MW-3 01/11/2023 15:04
01/10/2023 13:22Aqueous 97306 MW-4 01/11/2023 15:04
01/10/2023 14:10Aqueous 97307 MW-5 01/11/2023 15:04
01/10/2023 14:10Aqueous 97307 MW-5 01/11/2023 15:04 EPA-200.7 Eurofins -
01/10/2023 14:25Aqueous 97308 MW-6 01/11/2023 15:04
01/10/2023 14:25Aqueous 97308 MW-6 01/11/2023 15:04 EPA-200.7 Eurofins -
01/10/2023 14:18Aqueous 97309 MW-7 01/11/2023 15:04
01/10/2023 14:18Aqueous 97309 MW-7 01/11/2023 15:04 EPA-200.7 Eurofins -
01/10/2023 13:45Aqueous 97310 MW-8 01/11/2023 15:04
01/10/2023 13:45Aqueous 97310 MW-8 01/11/2023 15:04 EPA-200.7 Eurofins -
01/10/2023 14:00Aqueous 97311 TW-1 01/11/2023 15:04
01/10/2023 14:00Aqueous 97311 TW-1 01/11/2023 15:04 EPA-200.7 Eurofins -
01/10/2023Aqueous 97312 TB 01/11/2023 15:04
01/06/2023 10:12Solids 97313 TW-1-53'01/11/2023 15:04 WALK-BLACK WP MTN -
01/06/2023 10:12Solids 97313 TW-1-53'01/11/2023 15:04 Texture WP MTN -
01/06/2023 10:12Solids 97313 TW-1-53'01/11/2023 15:04 SIEVE TEST WP MTN -
01/06/2023 10:12Solids 97313 TW-1-53'01/11/2023 15:04 SIEVE WP MTN -
01/05/2023 10:47Solids 97314 MW-8-20'01/11/2023 15:04 WALK-BLACK WP MTN -
01/05/2023 10:47Solids 97314 MW-8-20'01/11/2023 15:04 Texture WP MTN -
01/05/2023 10:47Solids 97314 MW-8-20'01/11/2023 15:04 SIEVE TEST WP MTN -
01/05/2023 10:47Solids 97314 MW-8-20'01/11/2023 15:04 SIEVE WP MTN -
Eurofins - Savannah: Eurofins Environmental Testing Southeast, Savannah, Savannah, GA
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 164
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-011-0104
Report Limit
Project:Breedens 66
V 97303MW-1
550 01/22/2023 21:226200BBenzeneµg/L 18.0
9.97 01/19/2023 06:546200Bn-Butylbenzene µg/L 0.180
6.36 01/19/2023 06:546200Bsec-Butyl benzene µg/L 0.200
4.91 01/19/2023 06:546200BChloroformµg/L 0.220
6.27 01/19/2023 06:546200BDi-Isopropyl Ether (DIPE)µg/L 0.500
361 01/22/2023 21:226200BEthylbenzeneµg/L 17.0
22.2 01/19/2023 06:546200BIsopropylbenzeneµg/L 0.180
3.40 01/19/2023 06:546200B4-Isopropyl toluene µg/L 0.089
864 01/22/2023 21:226200BMethyl tert-butyl ether (MTBE)µg/L 14.0
40.5 01/19/2023 06:546200BNaphthaleneµg/L 0.470
40.6 01/19/2023 06:546200Bn-Propylbenzene µg/L 0.190
2.36 01/19/2023 06:546200BStyreneµg/L 0.220
187 01/19/2023 06:546200Btert-Butyl Alcohol (TBA)µg/L 1.60
1350 01/22/2023 21:226200Btert-Amyl Alcohol (TAA)µg/L 190
72.7 01/19/2023 06:546200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
362 01/22/2023 21:226200BTolueneµg/L 22.0
343 01/22/2023 21:226200B1,2,4-Trimethylbenzene µg/L 19.0
150 01/22/2023 21:226200B1,3,5-Trimethylbenzene µg/L 18.0
425 01/22/2023 21:226200Bo-Xylene µg/L 21.0
939 01/22/2023 21:226200Bm,p-Xylene µg/L 42.0
1360 01/22/2023 21:226200BXylene (Total)µg/L 21.0
V 97304MW-2
J0.239 01/22/2023 16:226200BBenzeneµg/L 0.180
J6.00 01/22/2023 16:226200Btert-Butyl Alcohol (TBA)µg/L 1.60
V 97305MW-3
168 01/22/2023 21:476200BBenzeneµg/L 18.0
81.8 01/19/2023 07:446200Bn-Butylbenzene µg/L 0.180
19.5 01/19/2023 07:446200Bsec-Butyl benzene µg/L 0.200
10.1 01/19/2023 07:446200BChloroformµg/L 0.220
522 01/22/2023 21:476200BEthylbenzeneµg/L 17.0
34.3 01/19/2023 07:446200BIsopropylbenzeneµg/L 0.180
6.97 01/19/2023 07:446200B4-Isopropyl toluene µg/L 0.089
43.3 01/19/2023 07:446200BMethyl tert-butyl ether (MTBE)µg/L 0.140
65.0 01/19/2023 07:446200BNaphthaleneµg/L 0.470
92.3 01/19/2023 07:446200Bn-Propylbenzene µg/L 0.190
7.13 01/19/2023 07:446200BStyreneµg/L 0.220
Page 4 of 164
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-011-0104
Report Limit
Project:Breedens 66
V 97305MW-3
18.6 01/19/2023 07:446200Btert-Butyl Alcohol (TBA)µg/L 1.60
76.1 01/19/2023 07:446200Btert-Amyl Alcohol (TAA)µg/L 1.90
J4.83 01/19/2023 07:446200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
1910 01/22/2023 21:476200BTolueneµg/L 22.0
810 01/22/2023 21:476200B1,2,4-Trimethylbenzene µg/L 19.0
251 01/22/2023 21:476200B1,3,5-Trimethylbenzene µg/L 18.0
812 01/22/2023 21:476200Bo-Xylene µg/L 21.0
2050 01/22/2023 21:476200Bm,p-Xylene µg/L 42.0
2860 01/22/2023 21:476200BXylene (Total)µg/L 21.0
V 97306MW-4
0.638 01/22/2023 19:176200BBenzeneµg/L 0.180
0.755 01/22/2023 19:176200BChloroformµg/L 0.220
1.65 01/22/2023 19:176200BDi-Isopropyl Ether (DIPE)µg/L 0.500
249 01/26/2023 10:466200BMethyl tert-butyl ether (MTBE)µg/L 1.40
15.6 01/22/2023 19:176200Btert-Butyl Alcohol (TBA)µg/L 1.60
68.8 01/22/2023 19:176200Btert-Amyl Alcohol (TAA)µg/L 1.90
J8.98 01/22/2023 19:176200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
V 97307MW-5
14.6 01/24/2023 06:266200BBenzeneµg/L 0.180
2.09 01/24/2023 06:266200Bn-Butylbenzene µg/L 0.180
0.901 01/24/2023 06:266200Bsec-Butyl benzene µg/L 0.200
68.3 01/24/2023 06:266200BEthylbenzeneµg/L 0.170
4.67 01/24/2023 06:266200BIsopropylbenzeneµg/L 0.180
1.98 01/24/2023 06:266200B4-Isopropyl toluene µg/L 0.089
15.6 01/24/2023 06:266200BMethyl tert-butyl ether (MTBE)µg/L 0.140
25.5 01/24/2023 06:266200BNaphthaleneµg/L 0.470
8.63 01/24/2023 06:266200Bn-Propylbenzene µg/L 0.190
J0.309 01/24/2023 06:266200BStyreneµg/L 0.220
88.6 01/24/2023 06:266200Btert-Butyl Alcohol (TBA)µg/L 1.60
98.2 01/24/2023 06:266200Btert-Amyl Alcohol (TAA)µg/L 1.90
J1.87 01/24/2023 06:266200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
62.8 01/24/2023 06:266200BTolueneµg/L 0.220
109 01/26/2023 11:586200B1,2,4-Trimethylbenzene µg/L 1.90
28.9 01/24/2023 06:266200B1,3,5-Trimethylbenzene µg/L 0.180
151 01/26/2023 11:586200Bo-Xylene µg/L 2.10
262 01/26/2023 11:586200Bm,p-Xylene µg/L 4.20
Page 5 of 164
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-011-0104
Report Limit
Project:Breedens 66
V 97307MW-5
413 01/26/2023 11:586200BXylene (Total)µg/L 2.10
J2.27 01/18/2023 20:43625.1 2,4-Dimethylphenol µg/L 1.70
2.63 01/18/2023 20:43625.1 1-Methylnaphthalene µg/L 1.23
5.05 01/18/2023 20:43625.1 2-Methylnaphthalene µg/L 0.719
16.9 01/18/2023 20:43625.1 Naphthalene µg/L 0.786
545 01/12/2023 13:03CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
644 01/13/2023 09:22CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 51.6
475 01/13/2023 09:22CALCULATIONAromatic C9-C10 (Adjusted)µg/L 8.04
See AttachedEPA-200.7 Lead mg/L
622 01/12/2023 13:03MADEP-VPH Aliphatic C5-C8 µg/L 11.5
1600 01/13/2023 09:22MADEP-VPH Aliphatic C9-C12 µg/L 51.6
475 01/13/2023 09:22MADEP-VPH Aromatic C9-C10 µg/L 8.04
V 97308MW-6
26.0 01/24/2023 06:516200BBenzeneµg/L 0.180
J0.319 01/24/2023 06:516200Bn-Butylbenzene µg/L 0.180
0.543 01/24/2023 06:516200Bsec-Butyl benzene µg/L 0.200
J53.1 01/24/2023 06:516200BEthanolµg/L 42.0
48.9 01/24/2023 06:516200BEthylbenzeneµg/L 0.170
3.90 01/24/2023 06:516200BIsopropylbenzeneµg/L 0.180
38.9 01/24/2023 06:516200BMethyl tert-butyl ether (MTBE)µg/L 0.140
13.5 01/24/2023 06:516200BNaphthaleneµg/L 0.470
4.60 01/24/2023 06:516200Bn-Propylbenzene µg/L 0.190
J0.370 01/24/2023 06:516200BStyreneµg/L 0.220
15.7 01/24/2023 06:516200Btert-Butyl Alcohol (TBA)µg/L 1.60
71.8 01/24/2023 06:516200Btert-Amyl Alcohol (TAA)µg/L 1.90
J4.22 01/24/2023 06:516200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
148 01/26/2023 12:226200BTolueneµg/L 2.20
44.7 01/24/2023 06:516200B1,2,4-Trimethylbenzene µg/L 0.190
9.10 01/24/2023 06:516200B1,3,5-Trimethylbenzene µg/L 0.180
86.9 01/24/2023 06:516200Bo-Xylene µg/L 0.210
119 01/24/2023 06:516200Bm,p-Xylene µg/L 0.420
206 01/24/2023 06:516200BXylene (Total)µg/L 0.210
J2.87 01/18/2023 21:28625.1 Benzoic Acid µg/L 1.21
J1.53 01/18/2023 21:28625.1 2-Methylnaphthalene µg/L 0.735
7.98 01/18/2023 21:28625.1 Naphthalene µg/L 0.804
266 01/12/2023 13:27CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
Page 6 of 164
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-011-0104
Report Limit
Project:Breedens 66
V 97308MW-6
189 01/12/2023 13:27CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
114 01/12/2023 13:27CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
See AttachedEPA-200.7 Lead mg/L
440 01/12/2023 13:27MADEP-VPH Aliphatic C5-C8 µg/L 11.5
558 01/12/2023 13:27MADEP-VPH Aliphatic C9-C12 µg/L 25.8
114 01/12/2023 13:27MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 97309MW-7
382 01/26/2023 15:586200BBenzeneµg/L 18.0
4.96 01/24/2023 07:166200Bn-Butylbenzene µg/L 0.180
3.30 01/24/2023 07:166200Bsec-Butyl benzene µg/L 0.200
3.03 01/24/2023 07:166200BDi-Isopropyl Ether (DIPE)µg/L 0.500
448 01/26/2023 15:586200BEthylbenzeneµg/L 17.0
19.1 01/24/2023 07:166200BIsopropylbenzeneµg/L 0.180
1.27 01/24/2023 07:166200B4-Isopropyl toluene µg/L 0.089
17.2 01/24/2023 07:166200BMethyl Ethyl Ketone (MEK)µg/L 0.710
440 01/26/2023 15:586200BMethyl tert-butyl ether (MTBE)µg/L 14.0
5.11 01/24/2023 07:166200B4-Methyl-2-Pentanone µg/L 0.078
157 01/26/2023 15:586200BNaphthaleneµg/L 47.0
37.4 01/24/2023 07:166200Bn-Propylbenzene µg/L 0.190
6.19 01/24/2023 07:166200BStyreneµg/L 0.220
139 01/24/2023 07:166200Btert-Butyl Alcohol (TBA)µg/L 1.60
J53201/26/2023 15:586200Btert-Amyl Alcohol (TAA)µg/L 190
56.8 01/24/2023 07:166200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
2130 01/26/2023 15:586200BTolueneµg/L 22.0
594 01/26/2023 15:586200B1,2,4-Trimethylbenzene µg/L 19.0
171 01/26/2023 15:586200B1,3,5-Trimethylbenzene µg/L 18.0
941 01/26/2023 15:586200Bo-Xylene µg/L 21.0
1680 01/26/2023 15:586200Bm,p-Xylene µg/L 42.0
2620 01/26/2023 15:586200BXylene (Total)µg/L 21.0
J5.76 01/18/2023 21:05625.1 2,4-Dimethylphenol µg/L 1.74
8.67 01/18/2023 21:05625.1 1-Methylnaphthalene µg/L 1.27
15.3 01/18/2023 21:05625.1 2-Methylnaphthalene µg/L 0.739
53.7 01/18/2023 21:05625.1 Naphthalene µg/L 0.808
1550 01/13/2023 09:46CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
1060 01/13/2023 09:46CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 258
1240 01/13/2023 09:46CALCULATIONAromatic C9-C10 (Adjusted)µg/L 40.2
Page 7 of 164
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-011-0104
Report Limit
Project:Breedens 66
V 97309MW-7
208 01/18/2023 21:05CALCULATIONAromatic C11-C22 (Adjusted)µg/L 61.2
See AttachedEPA-200.7 Lead mg/L
JQ0.0133 01/16/2023 13:54EPA-504.1 1,2-Dibromoethane µg/L 0.00338
J58.1 01/19/2023 18:24MADEP-EPH Aliphatic C9-C18 µg/L 28.2
262 01/19/2023 18:24MADEP-EPH Aromatic C11-C22 µg/L 61.2
4060 01/13/2023 09:46MADEP-VPH Aliphatic C5-C8 µg/L 115
5370 01/13/2023 09:46MADEP-VPH Aliphatic C9-C12 µg/L 258
1240 01/13/2023 09:46MADEP-VPH Aromatic C9-C10 µg/L 40.2
V 97310MW-8
2.28 01/23/2023 14:126200BBenzeneµg/L 0.180
4.83 01/23/2023 14:126200BEthylbenzeneµg/L 0.170
J0.364 01/23/2023 14:126200BIsopropylbenzeneµg/L 0.180
J0.228 01/23/2023 14:126200BMethyl tert-butyl ether (MTBE)µg/L 0.140
0.894 01/23/2023 14:126200Bn-Propylbenzene µg/L 0.190
J4.44 01/23/2023 14:126200Btert-Butyl Alcohol (TBA)µg/L 1.60
4.19 01/23/2023 14:126200BTolueneµg/L 0.220
5.61 01/23/2023 14:126200B1,2,4-Trimethylbenzene µg/L 0.190
2.30 01/23/2023 14:126200B1,3,5-Trimethylbenzene µg/L 0.180
6.30 01/23/2023 14:126200Bo-Xylene µg/L 0.210
14.4 01/23/2023 14:126200Bm,p-Xylene µg/L 0.420
20.7 01/23/2023 14:126200BXylene (Total)µg/L 0.210
J55.3 01/12/2023 14:15CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J13.6 01/12/2023 14:15CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
See AttachedEPA-200.7 Lead mg/L
94.4 01/12/2023 14:15MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J13.6 01/12/2023 14:15MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 97311TW-1
10.8 01/24/2023 03:066200BAcetoneµg/L 1.80
0.566 01/24/2023 03:066200BBenzeneµg/L 0.180
J0.473 01/24/2023 03:066200BEthylbenzeneµg/L 0.170
J0.972 01/24/2023 03:066200BMethyl tert-butyl ether (MTBE)µg/L 0.140
J5.47 01/24/2023 03:066200Btert-Butyl Alcohol (TBA)µg/L 1.60
J3.08 01/24/2023 03:066200Btert-Amyl Alcohol (TAA)µg/L 1.90
0.697 01/24/2023 03:066200BTolueneµg/L 0.220
0.918 01/24/2023 03:066200B1,2,4-Trimethylbenzene µg/L 0.190
J0.305 01/24/2023 03:066200B1,3,5-Trimethylbenzene µg/L 0.180
Page 8 of 164
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-011-0104
Report Limit
Project:Breedens 66
V 97311TW-1
0.690 01/24/2023 03:066200Bo-Xylene µg/L 0.210
1.34 01/24/2023 03:066200Bm,p-Xylene µg/L 0.420
2.03 01/24/2023 03:066200BXylene (Total)µg/L 0.210
See AttachedEPA-200.7 Lead mg/L
V 97312TB
J3.26 01/23/2023 13:486200BAcetoneµg/L 1.80
V 97313TW-1-53'
98.7 01/23/2023 11:00SIEVE% Passing 10 Mesh %0.1
68.3 01/23/2023 11:00SIEVE% Passing 40 Mesh %0.1
51.3 01/23/2023 11:00SIEVE% Passing 60 Mesh %0.1
33.3 01/23/2023 11:00SIEVE TEST % Passing 100 Mesh %0.1
87.6 01/23/2023 11:00SIEVE TEST % Passing 20 Mesh %0.1
25.7 01/23/2023 11:00SIEVE TEST % Passing 200 Mesh %0.1
100.0 01/23/2023 11:00SIEVE TEST % Passing 4 Mesh %0.1
10.0 01/20/2023 10:54Texture%Clay %0.1
89.0 01/20/2023 10:54Texture%Sand %0.1
1.0 01/20/2023 10:54Texture%Silt %0.1
Loamy Sand 01/20/2023 10:54TextureSoil Classification
0.07 01/20/2023 09:46WALK-BLACK Total Organic Carbon %0.05
V 97314MW-8-20'
85.3 01/23/2023 11:00SIEVE% Passing 10 Mesh %0.1
60.7 01/23/2023 11:00SIEVE% Passing 40 Mesh %0.1
51.4 01/23/2023 11:00SIEVE% Passing 60 Mesh %0.1
42.6 01/23/2023 11:00SIEVE TEST % Passing 100 Mesh %0.1
75.3 01/23/2023 11:00SIEVE TEST % Passing 20 Mesh %0.1
39.1 01/23/2023 11:00SIEVE TEST % Passing 200 Mesh %0.1
85.9 01/23/2023 11:00SIEVE TEST % Passing 4 Mesh %0.1
24.0 01/20/2023 10:54Texture%Clay %0.1
73.0 01/20/2023 10:54Texture%Sand %0.1
3.0 01/20/2023 10:54Texture%Silt %0.1
Sandy Clay Loam 01/20/2023 10:54TextureSoil Classification
0.21 01/20/2023 09:46WALK-BLACK Total Organic Carbon %0.05
Page 9 of 164

Client:GeologicalResources,Inc. CASENARRATIVE
Project:Breedens66
LabReportNumber:23-011-0104
Date:1/27/2023

625.1-Base/NeutralsandAcidsbyGC/MSMethod625.1
Sample97307(MW-5)
Analyte:2-Fluorobiphenyl
QCBatchNo:V29002/V28943
Surrogaterecovery(s)wasflaggedasoutsideQClimitsduetohighlevelsoftargetand/ornon-targetanalytes.
BatchQCsamples(methodblankandlaboratorycontrolsamples)allshowedsurrogateswithinQClimits.

Analyte:Benzidine
QCBatchNo:V29002/V28943
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Analyte:BenzoicAcid
QCBatchNo:V29002/V28943
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Sample97307(MW-5)
Analyte:Nitrobenzene-d5
QCBatchNo:V29002/V28943
Surrogaterecovery(s)wasflaggedasoutsideQClimitsduetohighlevelsoftargetand/ornon-targetanalytes.
BatchQCsamples(methodblankandlaboratorycontrolsamples)allshowedsurrogateswithinQClimits.

MassachusettsEPHMethodMADEP-EPH
Sample97308(MW-6)
Analyte:2-Bromonaphthalene
QCBatchNo:V29026/V28971
Surrogate(s)exhibitedahighbiasinthisprojectsamplewherenotargetanalytesweredetected.Thehigh
recovery(s)hadnoimpactonthedata.BatchQCsamples(methodblankandlaboratorycontrolsamples)all
showedsurrogateswithinQClimits.

Sample97309(MW-7)
Analyte:2-Bromonaphthalene
QCBatchNo:V29026/V28971
Fractionationsurrogatesaboveacceptedrange.Nomorevolumeforreextration.

Sample97308(MW-6)
Analyte:2-Fluorobiphenyl
QCBatchNo:V29026/V28971
Surrogate(s)exhibitedahighbiasinthisprojectsamplewherenotargetanalytesweredetected.Thehigh
recovery(s)hadnoimpactonthedata.BatchQCsamples(methodblankandlaboratorycontrolsamples)all
showedsurrogateswithinQClimits.

Sample97309(MW-7)
Analyte:2-Fluorobiphenyl
QCBatchNo:V29026/V28971
Fractionationsurrogatesaboveacceptedrange.Nomorevolumeforreextration.
Page 10 of 164

VolatileOrganicCompounds-GC/MSMethod6200B
Analyte:1,2-Dibromo-3-chloropropane
QCBatchNo:V29119/V29020
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Analyte:Naphthalene
QCBatchNo:V29119/V29020
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Analyte:Vinylacetate
QCBatchNo:V29096/V29020
RelativePercentDifference(RPD)fortheduplicateanalysiswasoutsideoftheallowableQClimits.

Page 11 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-1
97303 Matrix:
1/10/2023 13:34
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/19/23 06:54 6200BMSA
Surrogate: 4-Bromofluorobenzene 91.8 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: Dibromofluoromethane 93.4 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: Toluene-d8 102 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: 4-Bromofluorobenzene 96.6 Limits: 70-130%01/22/23 21:22100 MSA V29096
Surrogate: Dibromofluoromethane 94.8 Limits: 70-130%01/22/23 21:22100 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%01/22/23 21:22100 MSA V29096
Surrogate: Toluene-d8 102 Limits: 70-130%01/22/23 21:22100 MSA V29096
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 12 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-1
97303 Matrix:
1/10/2023 13:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/19/23 06:54 V29021MSA
550 µg/L 18.0 50.0
Benzene 100 01/22/23 21:22 V29096MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/19/23 06:54 V29021MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/19/23 06:54 V29021MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/19/23 06:54 V29021MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/19/23 06:54 V29021MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/19/23 06:54 V29021MSA
9.97 µg/L 0.180 0.500n-Butylbenzene 1 01/19/23 06:54 V29021MSA
6.36 µg/L 0.200 0.500sec-Butyl benzene 1 01/19/23 06:54 V29021MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/19/23 06:54 V29021MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/19/23 06:54 V29021MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/19/23 06:54 V29021MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/19/23 06:54 V29021MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/19/23 06:54 V29021MSA
4.91 µg/L 0.220 0.500Chloroform 1 01/19/23 06:54 V29021MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/19/23 06:54 V29021MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/19/23 06:54 V29021MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/19/23 06:54 V29021MSA
6.27 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/19/23 06:54 V29021MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/19/23 06:54 V29021MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/19/23 06:54 V29021MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/19/23 06:54 V29021MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 13 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-1
97303 Matrix:
1/10/2023 13:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/19/23 06:54 V29021MSA
<0.190 µg/L 0.190 0.500
1,3-Dichlorobenzene 1 01/19/23 06:54 V29021MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/19/23 06:54 V29021MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/19/23 06:54 V29021MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/19/23 06:54 V29021MSA
<0.150 µg/L 0.150 0.500
1,2-Dichloroethane 1 01/19/23 06:54 V29021MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/19/23 06:54 V29021MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/19/23 06:54 V29021MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/19/23 06:54 V29021MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/19/23 06:54 V29021MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/19/23 06:54 V29021MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/19/23 06:54 V29021MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/19/23 06:54 V29021MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/19/23 06:54 V29021MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/19/23 06:54 V29021MSA
<42.0 µg/L 42.0 200Ethanol 1 01/19/23 06:54 V29021MSA
361 µg/L 17.0 50.0Ethylbenzene 100 01/22/23 21:22 V29096MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/19/23 06:54 V29021MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/19/23 06:54 V29021MSA
22.2 µg/L 0.180 0.500
Isopropylbenzene 1 01/19/23 06:54 V29021MSA
3.40 µg/L 0.089 0.5004-Isopropyl toluene 1 01/19/23 06:54 V29021MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/19/23 06:54 V29021MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 14 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-1
97303 Matrix:
1/10/2023 13:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
864 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 01/22/23 21:22 V29096MSA
<0.078 µg/L 0.078 1.00
4-Methyl-2-Pentanone 1 01/19/23 06:54 V29021MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/19/23 06:54 V29021MSA
40.5 µg/L 0.470 1.00Naphthalene 1 01/19/23 06:54 V29021MSA
40.6 µg/L 0.190 0.500n-Propylbenzene 1 01/19/23 06:54 V29021MSA
2.36 µg/L 0.220 0.500
Styrene 1 01/19/23 06:54 V29021MSA
187 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 01/19/23 06:54 V29021MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/19/23 06:54 V29021MSA
1350 µg/L 190 1000tert-Amyl Alcohol (TAA)100 01/22/23 21:22 V29096MSA
72.7 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/19/23 06:54 V29021MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/19/23 06:54 V29021MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/19/23 06:54 V29021MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/19/23 06:54 V29021MSA
362 µg/L 22.0 50.0Toluene 100 01/22/23 21:22 V29096MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/19/23 06:54 V29021MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/19/23 06:54 V29021MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/19/23 06:54 V29021MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/19/23 06:54 V29021MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/19/23 06:54 V29021MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 01/19/23 06:54 V29021MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/19/23 06:54 V29021MSA
343 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 01/22/23 21:22 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 15 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-1
97303 Matrix:
1/10/2023 13:34
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
150 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 01/22/23 21:22 V29096MSA
<1.00 µg/L 1.00 5.00
Vinyl Acetate 1 01/19/23 06:54 V29021MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/19/23 06:54 V29021MSA
425 µg/L 21.0 50.0o-Xylene 100 01/22/23 21:22 V29096MSA
939 µg/L 42.0 100m,p-Xylene 100 01/22/23 21:22 V29096MSA
1360 µg/L 21.0 50.0
Xylene (Total)100 01/22/23 21:22 V29096
Surrogate: 4-Bromofluorobenzene 91.8 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: Dibromofluoromethane 93.4 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: 1,2-Dichloroethane - d4 95.0 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: Toluene-d8 102 Limits: 70-130%01/19/23 06:541 MSA V29021
Surrogate: 4-Bromofluorobenzene 96.6 Limits: 70-130%01/22/23 21:22100 MSA V29096
Surrogate: Dibromofluoromethane 94.8 Limits: 70-130%01/22/23 21:22100 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%01/22/23 21:22100 MSA V29096
Surrogate: Toluene-d8 102 Limits: 70-130%01/22/23 21:22100 MSA V29096
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 16 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-2
97304 Matrix:
1/10/2023 13:15
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/22/23 16:22 6200BMSA
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%01/22/23 16:221 MSA V29096
Surrogate: Dibromofluoromethane 92.2 Limits: 70-130%01/22/23 16:221 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%01/22/23 16:221 MSA V29096
Surrogate: Toluene-d8 97.8 Limits: 70-130%01/22/23 16:221 MSA V29096
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 17 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-2
97304 Matrix:
1/10/2023 13:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/22/23 16:22 V29096MSA
0.239 J
µg/L 0.180 0.500
Benzene 1 01/22/23 16:22 V29096MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/22/23 16:22 V29096MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/22/23 16:22 V29096MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/22/23 16:22 V29096MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/22/23 16:22 V29096MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/22/23 16:22 V29096MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/22/23 16:22 V29096MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/22/23 16:22 V29096MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/22/23 16:22 V29096MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/22/23 16:22 V29096MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/22/23 16:22 V29096MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/22/23 16:22 V29096MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/22/23 16:22 V29096MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/22/23 16:22 V29096MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/22/23 16:22 V29096MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/22/23 16:22 V29096MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/22/23 16:22 V29096MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/22/23 16:22 V29096MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/22/23 16:22 V29096MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/22/23 16:22 V29096MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/22/23 16:22 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 18 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-2
97304 Matrix:
1/10/2023 13:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/22/23 16:22 V29096MSA
<0.190 µg/L 0.190 0.500
1,3-Dichlorobenzene 1 01/22/23 16:22 V29096MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/22/23 16:22 V29096MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/22/23 16:22 V29096MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/22/23 16:22 V29096MSA
<0.150 µg/L 0.150 0.500
1,2-Dichloroethane 1 01/22/23 16:22 V29096MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/22/23 16:22 V29096MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/22/23 16:22 V29096MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/22/23 16:22 V29096MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/22/23 16:22 V29096MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/22/23 16:22 V29096MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/22/23 16:22 V29096MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/22/23 16:22 V29096MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/22/23 16:22 V29096MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/22/23 16:22 V29096MSA
<42.0 µg/L 42.0 200Ethanol 1 01/22/23 16:22 V29096MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/22/23 16:22 V29096MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/22/23 16:22 V29096MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/22/23 16:22 V29096MSA
<0.180 µg/L 0.180 0.500
Isopropylbenzene 1 01/22/23 16:22 V29096MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/22/23 16:22 V29096MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/22/23 16:22 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 19 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-2
97304 Matrix:
1/10/2023 13:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/22/23 16:22 V29096MSA
<0.078 µg/L 0.078 1.00
4-Methyl-2-Pentanone 1 01/22/23 16:22 V29096MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/22/23 16:22 V29096MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/22/23 16:22 V29096MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/22/23 16:22 V29096MSA
<0.220 µg/L 0.220 0.500
Styrene 1 01/22/23 16:22 V29096MSA
6.00 J µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 01/22/23 16:22 V29096MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/22/23 16:22 V29096MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/22/23 16:22 V29096MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/22/23 16:22 V29096MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/22/23 16:22 V29096MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/22/23 16:22 V29096MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/22/23 16:22 V29096MSA
<0.220 µg/L 0.220 0.500Toluene 1 01/22/23 16:22 V29096MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/22/23 16:22 V29096MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/22/23 16:22 V29096MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/22/23 16:22 V29096MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/22/23 16:22 V29096MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/22/23 16:22 V29096MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 01/22/23 16:22 V29096MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/22/23 16:22 V29096MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/22/23 16:22 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 20 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-2
97304 Matrix:
1/10/2023 13:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/22/23 16:22 V29096MSA
<1.00 µg/L 1.00 5.00
Vinyl Acetate 1 01/22/23 16:22 V29096MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/22/23 16:22 V29096MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/22/23 16:22 V29096MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/22/23 16:22 V29096MSA
<0.21 µg/L 0.210 0.500
Xylene (Total)1 01/22/23 16:22 V29096
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%01/22/23 16:221 MSA V29096
Surrogate: Dibromofluoromethane 92.2 Limits: 70-130%01/22/23 16:221 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%01/22/23 16:221 MSA V29096
Surrogate: Toluene-d8 97.8 Limits: 70-130%01/22/23 16:221 MSA V29096
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 21 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-3
97305 Matrix:
1/10/2023 13:22
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/19/23 07:44 6200BMSA
Surrogate: 4-Bromofluorobenzene 86.8 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: Dibromofluoromethane 94.6 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: 1,2-Dichloroethane - d4 96.2 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: Toluene-d8 105 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%01/22/23 21:47100 MSA V29096
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%01/22/23 21:47100 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 97.4 Limits: 70-130%01/22/23 21:47100 MSA V29096
Surrogate: Toluene-d8 95.4 Limits: 70-130%01/22/23 21:47100 MSA V29096
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 22 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-3
97305 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/19/23 07:44 V29021MSA
168 µg/L 18.0 50.0
Benzene 100 01/22/23 21:47 V29096MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/19/23 07:44 V29021MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/19/23 07:44 V29021MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/19/23 07:44 V29021MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/19/23 07:44 V29021MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/19/23 07:44 V29021MSA
81.8 µg/L 0.180 0.500n-Butylbenzene 1 01/19/23 07:44 V29021MSA
19.5 µg/L 0.200 0.500sec-Butyl benzene 1 01/19/23 07:44 V29021MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/19/23 07:44 V29021MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/19/23 07:44 V29021MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/19/23 07:44 V29021MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/19/23 07:44 V29021MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/19/23 07:44 V29021MSA
10.1 µg/L 0.220 0.500Chloroform 1 01/19/23 07:44 V29021MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/19/23 07:44 V29021MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/19/23 07:44 V29021MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/19/23 07:44 V29021MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/19/23 07:44 V29021MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/19/23 07:44 V29021MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/19/23 07:44 V29021MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/19/23 07:44 V29021MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 23 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-3
97305 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/19/23 07:44 V29021MSA
<0.190 µg/L 0.190 0.500
1,3-Dichlorobenzene 1 01/19/23 07:44 V29021MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/19/23 07:44 V29021MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/19/23 07:44 V29021MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/19/23 07:44 V29021MSA
<0.150 µg/L 0.150 0.500
1,2-Dichloroethane 1 01/19/23 07:44 V29021MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/19/23 07:44 V29021MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/19/23 07:44 V29021MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/19/23 07:44 V29021MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/19/23 07:44 V29021MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/19/23 07:44 V29021MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/19/23 07:44 V29021MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/19/23 07:44 V29021MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/19/23 07:44 V29021MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/19/23 07:44 V29021MSA
<42.0 µg/L 42.0 200Ethanol 1 01/19/23 07:44 V29021MSA
522 µg/L 17.0 50.0Ethylbenzene 100 01/22/23 21:47 V29096MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/19/23 07:44 V29021MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/19/23 07:44 V29021MSA
34.3 µg/L 0.180 0.500
Isopropylbenzene 1 01/19/23 07:44 V29021MSA
6.97 µg/L 0.089 0.5004-Isopropyl toluene 1 01/19/23 07:44 V29021MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/19/23 07:44 V29021MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 24 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-3
97305 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
43.3 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/19/23 07:44 V29021MSA
<0.078 µg/L 0.078 1.00
4-Methyl-2-Pentanone 1 01/19/23 07:44 V29021MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/19/23 07:44 V29021MSA
65.0 µg/L 0.470 1.00Naphthalene 1 01/19/23 07:44 V29021MSA
92.3 µg/L 0.190 0.500n-Propylbenzene 1 01/19/23 07:44 V29021MSA
7.13 µg/L 0.220 0.500
Styrene 1 01/19/23 07:44 V29021MSA
18.6 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 01/19/23 07:44 V29021MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/19/23 07:44 V29021MSA
76.1 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/19/23 07:44 V29021MSA
4.83 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/19/23 07:44 V29021MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/19/23 07:44 V29021MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/19/23 07:44 V29021MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/19/23 07:44 V29021MSA
1910 µg/L 22.0 50.0Toluene 100 01/22/23 21:47 V29096MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/19/23 07:44 V29021MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/19/23 07:44 V29021MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/19/23 07:44 V29021MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/19/23 07:44 V29021MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/19/23 07:44 V29021MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 01/19/23 07:44 V29021MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/19/23 07:44 V29021MSA
810 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 01/22/23 21:47 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 25 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-3
97305 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29020 01/18/23 14:00 V29095 01/22/23 09:00
251 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 01/22/23 21:47 V29096MSA
<1.00 µg/L 1.00 5.00
Vinyl Acetate 1 01/19/23 07:44 V29021MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/19/23 07:44 V29021MSA
812 µg/L 21.0 50.0o-Xylene 100 01/22/23 21:47 V29096MSA
2050 µg/L 42.0 100m,p-Xylene 100 01/22/23 21:47 V29096MSA
2860 µg/L 21.0 50.0
Xylene (Total)100 01/22/23 21:47 V29096
Surrogate: 4-Bromofluorobenzene 86.8 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: Dibromofluoromethane 94.6 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: 1,2-Dichloroethane - d4 96.2 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: Toluene-d8 105 Limits: 70-130%01/19/23 07:441 MSA V29021
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%01/22/23 21:47100 MSA V29096
Surrogate: Dibromofluoromethane 96.4 Limits: 70-130%01/22/23 21:47100 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 97.4 Limits: 70-130%01/22/23 21:47100 MSA V29096
Surrogate: Toluene-d8 95.4 Limits: 70-130%01/22/23 21:47100 MSA V29096
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 26 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-4
97306 Matrix:
1/10/2023 13:22
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/22/23 19:17 6200BMSA
Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 98.2 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: Toluene-d8 94.0 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: 4-Bromofluorobenzene 105 Limits: 70-130%01/26/23 10:4610 MSA V29244
Surrogate: Dibromofluoromethane 102 Limits: 70-130%01/26/23 10:4610 MSA V29244
Surrogate: 1,2-Dichloroethane - d4 99.6 Limits: 70-130%01/26/23 10:4610 MSA V29244
Surrogate: Toluene-d8 113 Limits: 70-130%01/26/23 10:4610 MSA V29244
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 27 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-4
97306 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00 V29243 01/26/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/22/23 19:17 V29096MSA
0.638 µg/L 0.180 0.500
Benzene 1 01/22/23 19:17 V29096MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/22/23 19:17 V29096MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/22/23 19:17 V29096MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/22/23 19:17 V29096MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/22/23 19:17 V29096MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/22/23 19:17 V29096MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/22/23 19:17 V29096MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/22/23 19:17 V29096MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/22/23 19:17 V29096MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/22/23 19:17 V29096MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/22/23 19:17 V29096MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/22/23 19:17 V29096MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/22/23 19:17 V29096MSA
0.755 µg/L 0.220 0.500Chloroform 1 01/22/23 19:17 V29096MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/22/23 19:17 V29096MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/22/23 19:17 V29096MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/22/23 19:17 V29096MSA
1.65 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/22/23 19:17 V29096MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/22/23 19:17 V29096MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/22/23 19:17 V29096MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/22/23 19:17 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 28 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-4
97306 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00 V29243 01/26/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/22/23 19:17 V29096MSA
<0.190 µg/L 0.190 0.500
1,3-Dichlorobenzene 1 01/22/23 19:17 V29096MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/22/23 19:17 V29096MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/22/23 19:17 V29096MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/22/23 19:17 V29096MSA
<0.150 µg/L 0.150 0.500
1,2-Dichloroethane 1 01/22/23 19:17 V29096MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/22/23 19:17 V29096MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/22/23 19:17 V29096MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/22/23 19:17 V29096MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/22/23 19:17 V29096MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/22/23 19:17 V29096MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/22/23 19:17 V29096MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/22/23 19:17 V29096MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/22/23 19:17 V29096MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/22/23 19:17 V29096MSA
<42.0 µg/L 42.0 200Ethanol 1 01/22/23 19:17 V29096MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/22/23 19:17 V29096MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/22/23 19:17 V29096MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/22/23 19:17 V29096MSA
<0.180 µg/L 0.180 0.500
Isopropylbenzene 1 01/22/23 19:17 V29096MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/22/23 19:17 V29096MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/22/23 19:17 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 29 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-4
97306 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00 V29243 01/26/23 09:00
249 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 01/26/23 10:46 V29244MSA
<0.078 µg/L 0.078 1.00
4-Methyl-2-Pentanone 1 01/22/23 19:17 V29096MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/22/23 19:17 V29096MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/22/23 19:17 V29096MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/22/23 19:17 V29096MSA
<0.220 µg/L 0.220 0.500
Styrene 1 01/22/23 19:17 V29096MSA
15.6 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 01/22/23 19:17 V29096MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/22/23 19:17 V29096MSA
68.8 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/22/23 19:17 V29096MSA
8.98 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/22/23 19:17 V29096MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/22/23 19:17 V29096MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/22/23 19:17 V29096MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/22/23 19:17 V29096MSA
<0.220 µg/L 0.220 0.500Toluene 1 01/22/23 19:17 V29096MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/22/23 19:17 V29096MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/22/23 19:17 V29096MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/22/23 19:17 V29096MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/22/23 19:17 V29096MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/22/23 19:17 V29096MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 01/22/23 19:17 V29096MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/22/23 19:17 V29096MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/22/23 19:17 V29096MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 30 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-4
97306 Matrix:
1/10/2023 13:22
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29095 01/22/23 09:00 V29243 01/26/23 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/22/23 19:17 V29096MSA
<1.00 µg/L 1.00 5.00
Vinyl Acetate 1 01/22/23 19:17 V29096MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/22/23 19:17 V29096MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/22/23 19:17 V29096MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/22/23 19:17 V29096MSA
<0.21 µg/L 0.210 0.500
Xylene (Total)1 01/22/23 19:17 V29096
Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: Dibromofluoromethane 99.0 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: 1,2-Dichloroethane - d4 98.2 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: Toluene-d8 94.0 Limits: 70-130%01/22/23 19:171 MSA V29096
Surrogate: 4-Bromofluorobenzene 105 Limits: 70-130%01/26/23 10:4610 MSA V29244
Surrogate: Dibromofluoromethane 102 Limits: 70-130%01/26/23 10:4610 MSA V29244
Surrogate: 1,2-Dichloroethane - d4 99.6 Limits: 70-130%01/26/23 10:4610 MSA V29244
Surrogate: Toluene-d8 113 Limits: 70-130%01/26/23 10:4610 MSA V29244
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 31 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/24/23 06:26 6200BMSA
See Attached mg/L 0.006Lead 1 EPA-200.7BKN
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 32 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/24/23 06:26 V29119MSA
14.6 µg/L 0.180 0.500
Benzene 1 01/24/23 06:26 V29119MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/24/23 06:26 V29119MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/24/23 06:26 V29119MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/24/23 06:26 V29119MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/24/23 06:26 V29119MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/24/23 06:26 V29119MSA
2.09 µg/L 0.180 0.500n-Butylbenzene 1 01/24/23 06:26 V29119MSA
0.901 µg/L 0.200 0.500sec-Butyl benzene 1 01/24/23 06:26 V29119MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/24/23 06:26 V29119MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/24/23 06:26 V29119MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/24/23 06:26 V29119MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/24/23 06:26 V29119MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/24/23 06:26 V29119MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/24/23 06:26 V29119MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/24/23 06:26 V29119MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/24/23 06:26 V29119MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/24/23 06:26 V29119MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/24/23 06:26 V29119MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/24/23 06:26 V29119MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/24/23 06:26 V29119MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/24/23 06:26 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 33 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/24/23 06:26 V29119MSA
<0.210 µg/L 0.210 0.500
1,4-Dichlorobenzene 1 01/24/23 06:26 V29119MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/24/23 06:26 V29119MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/24/23 06:26 V29119MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/24/23 06:26 V29119MSA
<0.150 µg/L 0.150 0.500
1,1-Dichloroethene 1 01/24/23 06:26 V29119MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/24/23 06:26 V29119MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/24/23 06:26 V29119MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/24/23 06:26 V29119MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/24/23 06:26 V29119MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/24/23 06:26 V29119MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/24/23 06:26 V29119MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/24/23 06:26 V29119MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/24/23 06:26 V29119MSA
<42.0 µg/L 42.0 200Ethanol 1 01/24/23 06:26 V29119MSA
68.3 µg/L 0.170 0.500Ethylbenzene 1 01/24/23 06:26 V29119MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/24/23 06:26 V29119MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/24/23 06:26 V29119MSA
4.67 µg/L 0.180 0.500Isopropylbenzene 1 01/24/23 06:26 V29119MSA
1.98 µg/L 0.089 0.500
4-Isopropyl toluene 1 01/24/23 06:26 V29119MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/24/23 06:26 V29119MSA
15.6 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/24/23 06:26 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 34 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/24/23 06:26 V29119MSA
<0.330 µg/L 0.330 2.00
Methylene Chloride 1 01/24/23 06:26 V29119MSA
25.5 µg/L 0.470 1.00Naphthalene 1 01/24/23 06:26 V29119MSA
8.63 µg/L 0.190 0.500n-Propylbenzene 1 01/24/23 06:26 V29119MSA
0.309 J µg/L 0.220 0.500Styrene 1 01/24/23 06:26 V29119MSA
88.6 µg/L 1.60 10.0
tert-Butyl Alcohol (TBA)1 01/24/23 06:26 V29119MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/24/23 06:26 V29119MSA
98.2 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/24/23 06:26 V29119MSA
1.87 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/24/23 06:26 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/24/23 06:26 V29119MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/24/23 06:26 V29119MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/24/23 06:26 V29119MSA
62.8 µg/L 0.220 0.500Toluene 1 01/24/23 06:26 V29119MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/24/23 06:26 V29119MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/24/23 06:26 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/24/23 06:26 V29119MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/24/23 06:26 V29119MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/24/23 06:26 V29119MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 01/24/23 06:26 V29119MSA
<0.270 µg/L 0.270 0.500
1,2,3-Trichloropropane 1 01/24/23 06:26 V29119MSA
109 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 01/26/23 11:58 V29244MSA
28.9 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/24/23 06:26 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 35 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/24/23 06:26 V29119MSA
<0.170 µg/L 0.170 0.500
Vinyl Chloride 1 01/24/23 06:26 V29119MSA
151 µg/L 2.10 5.00o-Xylene 10 01/26/23 11:58 V29244MSA
262 µg/L 4.20 10.0m,p-Xylene 10 01/26/23 11:58 V29244MSA
413 µg/L 2.10 5.00Xylene (Total)10 01/26/23 11:58 V29244
Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%01/24/23 06:261 MSA V29119
Surrogate: Dibromofluoromethane 88.0 Limits: 70-130%01/24/23 06:261 MSA V29119
Surrogate: 1,2-Dichloroethane - d4 93.4 Limits: 70-130%01/24/23 06:261 MSA V29119
Surrogate: Toluene-d8 99.2 Limits: 70-130%01/24/23 06:261 MSA V29119
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%01/26/23 11:5810 MSA V29244
Surrogate: Dibromofluoromethane 102 Limits: 70-130%01/26/23 11:5810 MSA V29244
Surrogate: 1,2-Dichloroethane - d4 104 Limits: 70-130%01/26/23 11:5810 MSA V29244
Surrogate: Toluene-d8 109 Limits: 70-130%01/26/23 11:5810 MSA V29244
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.326 µg/L 0.326 2.16
Acenaphthene 1 01/18/23 20:43 V29002JMV
<0.320 µg/L 0.320 2.16Acenaphthylene 1 01/18/23 20:43 V29002JMV
<0.902 µg/L 0.902 2.16Anthracene 1 01/18/23 20:43 V29002JMV
<1.43 µg/L 1.43 10.8Benzidine 1 01/18/23 20:43 V29002JMV
<0.687 µg/L 0.687 2.16
Benzo(a)anthracene 1 01/18/23 20:43 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 36 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.10 µg/L 1.10 2.16Benzo(a)pyrene 1 01/18/23 20:43 V29002JMV
<2.69 µg/L 2.69 5.41
Benzo(b)fluoranthene 1 01/18/23 20:43 V29002JMV
<1.09 µg/L 1.09 5.41Benzo(g,h,i)perylene 1 01/18/23 20:43 V29002JMV
<2.15 µg/L 2.15 5.41Benzo(k)fluoranthene 1 01/18/23 20:43 V29002JMV
<1.19 µg/L 1.19 10.8Benzoic Acid 1 01/18/23 20:43 V29002JMV
<0.740 µg/L 0.740 5.41
Benzyl alcohol 1 01/18/23 20:43 V29002JMV
<0.506 µg/L 0.506 5.41Bis(2-Chloroethoxy)methane 1 01/18/23 20:43 V29002JMV
<1.13 µg/L 1.13 5.41Bis(2-Chloroethyl)ether 1 01/18/23 20:43 V29002JMV
<1.17 µg/L 1.17 5.41Bis(2-Chloroisopropyl)ether 1 01/18/23 20:43 V29002JMV
<26.0 µg/L 26.0 54.1Bis(2-ethylhexyl)phthalate 1 01/18/23 20:43 V29002JMV
<1.20 µg/L 1.20 5.414-Bromophenyl phenyl ether 1 01/18/23 20:43 V29002JMV
<1.98 µg/L 1.98 5.41Butyl benzyl phthalate 1 01/18/23 20:43 V29002JMV
<1.28 µg/L 1.28 5.414-Chloro-3-methylphenol 1 01/18/23 20:43 V29002JMV
<7.97 µg/L 7.97 21.62-Chloronaphthalene 1 01/18/23 20:43 V29002JMV
<1.01 µg/L 1.01 10.82-Chlorophenol 1 01/18/23 20:43 V29002JMV
<1.85 µg/L 1.85 5.414-Chlorophenyl phenyl ether 1 01/18/23 20:43 V29002JMV
<0.437 µg/L 0.437 2.16Chrysene 1 01/18/23 20:43 V29002JMV
<0.468 µg/L 0.468 2.16Dibenz(a,h)anthracene 1 01/18/23 20:43 V29002JMV
<0.926 µg/L 0.926 5.41Dibenzofuran 1 01/18/23 20:43 V29002JMV
<2.16 µg/L 2.16 5.41
1,2-Dichlorobenzene 1 01/18/23 20:43 V29002JMV
<2.16 µg/L 2.16 5.411,3-Dichlorobenzene 1 01/18/23 20:43 V29002JMV
<2.22 µg/L 2.22 5.411,4-Dichlorobenzene 1 01/18/23 20:43 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 37 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<2.04 µg/L 2.04 5.413,3'-Dichlorobenzidine 1 01/18/23 20:43 V29002JMV
<1.58 µg/L 1.58 10.8
2,4-Dichlorophenol 1 01/18/23 20:43 V29002JMV
<0.806 µg/L 0.806 5.41Diethyl phthalate 1 01/18/23 20:43 V29002JMV
<1.02 µg/L 1.02 5.41Dimethyl phthalate 1 01/18/23 20:43 V29002JMV
2.27 J µg/L 1.70 21.62,4-Dimethylphenol 1 01/18/23 20:43 V29002JMV
<2.23 µg/L 2.23 5.41
Di-n-butyl phthalate 1 01/18/23 20:43 V29002JMV
<2.24 µg/L 2.24 10.84,6-Dinitro-2-methylphenol 1 01/18/23 20:43 V29002JMV
<2.07 µg/L 2.07 10.82,4-Dinitrophenol 1 01/18/23 20:43 V29002JMV
<1.20 µg/L 1.20 5.412,4-Dinitrotoluene 1 01/18/23 20:43 V29002JMV
<0.875 µg/L 0.875 5.412,6-Dinitrotoluene 1 01/18/23 20:43 V29002JMV
<1.79 µg/L 1.79 5.41Di-n-Octyl Phthalate 1 01/18/23 20:43 V29002JMV
<0.270 µg/L 0.270 2.16Fluoranthene 1 01/18/23 20:43 V29002JMV
<0.871 µg/L 0.871 2.16Fluorene 1 01/18/23 20:43 V29002JMV
<1.06 µg/L 1.06 5.41Hexachlorobenzene 1 01/18/23 20:43 V29002JMV
<2.95 µg/L 2.95 5.41Hexachlorobutadiene 1 01/18/23 20:43 V29002JMV
<2.22 µg/L 2.22 5.41Hexachlorocyclopentadiene 1 01/18/23 20:43 V29002JMV
<1.90 µg/L 1.90 5.41Hexachloroethane 1 01/18/23 20:43 V29002JMV
<0.515 µg/L 0.515 2.16Indeno(1,2,3-cd)pyrene 1 01/18/23 20:43 V29002JMV
<0.480 µg/L 0.480 5.41Isophorone 1 01/18/23 20:43 V29002JMV
2.63 µg/L 1.23 2.16
1-Methylnaphthalene 1 01/18/23 20:43 V29002JMV
5.05 µg/L 0.719 2.162-Methylnaphthalene 1 01/18/23 20:43 V29002JMV
16.9 µg/L 0.786 2.16Naphthalene 1 01/18/23 20:43 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 38 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.979 µg/L 0.979 5.41Nitrobenzene 1 01/18/23 20:43 V29002JMV
<0.533 µg/L 0.533 5.41
2-Nitrophenol 1 01/18/23 20:43 V29002JMV
<1.33 µg/L 1.33 10.84-Nitrophenol 1 01/18/23 20:43 V29002JMV
<1.19 µg/L 1.19 5.41N-Nitrosodiphenylamine 1 01/18/23 20:43 V29002JMV
<0.693 µg/L 0.693 5.41N-Nitroso-di-n-propylamine 1 01/18/23 20:43 V29002JMV
<1.55 µg/L 1.55 5.41
Pentachlorophenol 1 01/18/23 20:43 V29002JMV
<0.462 µg/L 0.462 2.16Phenanthrene 1 01/18/23 20:43 V29002JMV
<0.704 µg/L 0.704 5.41Phenol 1 01/18/23 20:43 V29002JMV
<0.468 µg/L 0.468 2.16Pyrene 1 01/18/23 20:43 V29002JMV
<2.39 µg/L 2.39 5.411,2,4-Trichlorobenzene 1 01/18/23 20:43 V29002JMV
<1.43 µg/L 1.43 5.412,4,6-Trichlorophenol 1 01/18/23 20:43 V29002JMV
625.1Surrogate: Phenol-d5 18.7 Limits: 10-63%01/18/23 20:431 JMV
Surrogate: 2-Fluorobiphenyl 42.7 *Limits: 49-118%01/18/23 20:431 JMV V29002
Surrogate: 2-Fluorophenol 25.0 Limits: 22-84%01/18/23 20:431 JMV V29002
Surrogate: Nitrobenzene-d5 35.1 *Limits: 43-123%01/18/23 20:431 JMV V29002
Surrogate: 4-Terphenyl-d14 54.3 Limits: 49-151%01/18/23 20:431 JMV V29002
Surrogate: 2,4,6-Tribromophenol 51.1 Limits: 31-144%01/18/23 20:431 JMV V29002
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V28888 01/16/23 09:30
<0.00337 µg/L 0.00337 0.02041,2-Dibromoethane 1 01/16/23 12:39 V28908AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 39 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-5
97307 Matrix:
1/10/2023 14:10
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
545 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/12/23 13:03
644 µg/L 51.6 100
Aliphatics C9-C12 (Adjusted)1 01/13/23 09:22
475 µg/L 8.04 100Aromatic C9-C10 (Adjusted)2 01/13/23 09:22
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
622 µg/L 11.5 50.0Aliphatic C5-C8 1 01/12/23 13:03 V28855TBL
1600 µg/L 51.6 100Aliphatic C9-C12 2 01/13/23 09:22 V28855TBL
475 µg/L 8.04 100Aromatic C9-C10 2 01/13/23 09:22 V28855TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)82.2 Limits: 70-130%01/12/23 13:031 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)77.6 Limits: 70-130%01/12/23 13:031 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)83.8 Limits: 70-130%01/13/23 09:222 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.2 Limits: 70-130%01/13/23 09:222 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 40 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/24/23 06:51 6200BMSA
See Attached mg/L 0.006Lead 1 EPA-200.7BKN
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 41 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/24/23 06:51 V29119MSA
26.0 µg/L 0.180 0.500
Benzene 1 01/24/23 06:51 V29119MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/24/23 06:51 V29119MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/24/23 06:51 V29119MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/24/23 06:51 V29119MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/24/23 06:51 V29119MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/24/23 06:51 V29119MSA
0.319 J µg/L 0.180 0.500n-Butylbenzene 1 01/24/23 06:51 V29119MSA
0.543 µg/L 0.200 0.500sec-Butyl benzene 1 01/24/23 06:51 V29119MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/24/23 06:51 V29119MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/24/23 06:51 V29119MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/24/23 06:51 V29119MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/24/23 06:51 V29119MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/24/23 06:51 V29119MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/24/23 06:51 V29119MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/24/23 06:51 V29119MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/24/23 06:51 V29119MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/24/23 06:51 V29119MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/24/23 06:51 V29119MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/24/23 06:51 V29119MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/24/23 06:51 V29119MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/24/23 06:51 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 42 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/24/23 06:51 V29119MSA
<0.210 µg/L 0.210 0.500
1,4-Dichlorobenzene 1 01/24/23 06:51 V29119MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/24/23 06:51 V29119MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/24/23 06:51 V29119MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/24/23 06:51 V29119MSA
<0.150 µg/L 0.150 0.500
1,1-Dichloroethene 1 01/24/23 06:51 V29119MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/24/23 06:51 V29119MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/24/23 06:51 V29119MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/24/23 06:51 V29119MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/24/23 06:51 V29119MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/24/23 06:51 V29119MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/24/23 06:51 V29119MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/24/23 06:51 V29119MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/24/23 06:51 V29119MSA
53.1 J µg/L 42.0 200Ethanol 1 01/24/23 06:51 V29119MSA
48.9 µg/L 0.170 0.500Ethylbenzene 1 01/24/23 06:51 V29119MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/24/23 06:51 V29119MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/24/23 06:51 V29119MSA
3.90 µg/L 0.180 0.500Isopropylbenzene 1 01/24/23 06:51 V29119MSA
<0.089 µg/L 0.089 0.500
4-Isopropyl toluene 1 01/24/23 06:51 V29119MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/24/23 06:51 V29119MSA
38.9 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/24/23 06:51 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 43 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/24/23 06:51 V29119MSA
<0.330 µg/L 0.330 2.00
Methylene Chloride 1 01/24/23 06:51 V29119MSA
13.5 µg/L 0.470 1.00Naphthalene 1 01/24/23 06:51 V29119MSA
4.60 µg/L 0.190 0.500n-Propylbenzene 1 01/24/23 06:51 V29119MSA
0.370 J µg/L 0.220 0.500Styrene 1 01/24/23 06:51 V29119MSA
15.7 µg/L 1.60 10.0
tert-Butyl Alcohol (TBA)1 01/24/23 06:51 V29119MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/24/23 06:51 V29119MSA
71.8 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/24/23 06:51 V29119MSA
4.22 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/24/23 06:51 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/24/23 06:51 V29119MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/24/23 06:51 V29119MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/24/23 06:51 V29119MSA
148 µg/L 2.20 5.00Toluene 10 01/26/23 12:22 V29244MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/24/23 06:51 V29119MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/24/23 06:51 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/24/23 06:51 V29119MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/24/23 06:51 V29119MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/24/23 06:51 V29119MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 01/24/23 06:51 V29119MSA
<0.270 µg/L 0.270 0.500
1,2,3-Trichloropropane 1 01/24/23 06:51 V29119MSA
44.7 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/24/23 06:51 V29119MSA
9.10 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/24/23 06:51 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 44 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/24/23 06:51 V29119MSA
<0.170 µg/L 0.170 0.500
Vinyl Chloride 1 01/24/23 06:51 V29119MSA
86.9 µg/L 0.210 0.500o-Xylene 1 01/24/23 06:51 V29119MSA
119 µg/L 0.420 1.00m,p-Xylene 1 01/24/23 06:51 V29119MSA
206 µg/L 0.210 0.500Xylene (Total)1 01/24/23 06:51 V29119KCC
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%01/24/23 06:511 MSA V29119
Surrogate: Dibromofluoromethane 92.6 Limits: 70-130%01/24/23 06:511 MSA V29119
Surrogate: 1,2-Dichloroethane - d4 93.6 Limits: 70-130%01/24/23 06:511 MSA V29119
Surrogate: Toluene-d8 101 Limits: 70-130%01/24/23 06:511 MSA V29119
Surrogate: 4-Bromofluorobenzene 106 Limits: 70-130%01/26/23 12:2210 MSA V29244
Surrogate: Dibromofluoromethane 101 Limits: 70-130%01/26/23 12:2210 MSA V29244
Surrogate: 1,2-Dichloroethane - d4 98.8 Limits: 70-130%01/26/23 12:2210 MSA V29244
Surrogate: Toluene-d8 109 Limits: 70-130%01/26/23 12:2210 MSA V29244
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.333 µg/L 0.333 2.21
Acenaphthene 1 01/18/23 21:28 V29002JMV
<0.328 µg/L 0.328 2.21Acenaphthylene 1 01/18/23 21:28 V29002JMV
<0.923 µg/L 0.923 2.21Anthracene 1 01/18/23 21:28 V29002JMV
<1.45 µg/L 1.45 11.0Benzidine 1 01/18/23 21:28 V29002JMV
<0.703 µg/L 0.703 2.21
Benzo(a)anthracene 1 01/18/23 21:28 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 45 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.13 µg/L 1.13 2.21Benzo(a)pyrene 1 01/18/23 21:28 V29002JMV
<2.75 µg/L 2.75 5.52
Benzo(b)fluoranthene 1 01/18/23 21:28 V29002JMV
<1.12 µg/L 1.12 5.52Benzo(g,h,i)perylene 1 01/18/23 21:28 V29002JMV
<2.20 µg/L 2.20 5.52Benzo(k)fluoranthene 1 01/18/23 21:28 V29002JMV
2.87 J µg/L 1.21 11.0Benzoic Acid 1 01/18/23 21:28 V29002JMV
<0.755 µg/L 0.755 5.52
Benzyl alcohol 1 01/18/23 21:28 V29002JMV
<0.516 µg/L 0.516 5.52Bis(2-Chloroethoxy)methane 1 01/18/23 21:28 V29002JMV
<1.15 µg/L 1.15 5.52Bis(2-Chloroethyl)ether 1 01/18/23 21:28 V29002JMV
<1.19 µg/L 1.19 5.52Bis(2-Chloroisopropyl)ether 1 01/18/23 21:28 V29002JMV
<26.5 µg/L 26.5 55.2Bis(2-ethylhexyl)phthalate 1 01/18/23 21:28 V29002JMV
<1.23 µg/L 1.23 5.524-Bromophenyl phenyl ether 1 01/18/23 21:28 V29002JMV
<2.02 µg/L 2.02 5.52Butyl benzyl phthalate 1 01/18/23 21:28 V29002JMV
<1.30 µg/L 1.30 5.524-Chloro-3-methylphenol 1 01/18/23 21:28 V29002JMV
<8.15 µg/L 8.15 22.12-Chloronaphthalene 1 01/18/23 21:28 V29002JMV
<1.03 µg/L 1.03 11.02-Chlorophenol 1 01/18/23 21:28 V29002JMV
<1.89 µg/L 1.89 5.524-Chlorophenyl phenyl ether 1 01/18/23 21:28 V29002JMV
<0.447 µg/L 0.447 2.21Chrysene 1 01/18/23 21:28 V29002JMV
<0.479 µg/L 0.479 2.21Dibenz(a,h)anthracene 1 01/18/23 21:28 V29002JMV
<0.945 µg/L 0.945 5.52Dibenzofuran 1 01/18/23 21:28 V29002JMV
<2.21 µg/L 2.21 5.52
1,2-Dichlorobenzene 1 01/18/23 21:28 V29002JMV
<2.21 µg/L 2.21 5.521,3-Dichlorobenzene 1 01/18/23 21:28 V29002JMV
<2.26 µg/L 2.26 5.521,4-Dichlorobenzene 1 01/18/23 21:28 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 46 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<2.09 µg/L 2.09 5.523,3'-Dichlorobenzidine 1 01/18/23 21:28 V29002JMV
<1.61 µg/L 1.61 11.0
2,4-Dichlorophenol 1 01/18/23 21:28 V29002JMV
<0.822 µg/L 0.822 5.52Diethyl phthalate 1 01/18/23 21:28 V29002JMV
<1.04 µg/L 1.04 5.52Dimethyl phthalate 1 01/18/23 21:28 V29002JMV
<1.73 µg/L 1.73 22.12,4-Dimethylphenol 1 01/18/23 21:28 V29002JMV
<2.27 µg/L 2.27 5.52
Di-n-butyl phthalate 1 01/18/23 21:28 V29002JMV
<2.28 µg/L 2.28 11.04,6-Dinitro-2-methylphenol 1 01/18/23 21:28 V29002JMV
<2.11 µg/L 2.11 11.02,4-Dinitrophenol 1 01/18/23 21:28 V29002JMV
<1.23 µg/L 1.23 5.522,4-Dinitrotoluene 1 01/18/23 21:28 V29002JMV
<0.893 µg/L 0.893 5.522,6-Dinitrotoluene 1 01/18/23 21:28 V29002JMV
<1.82 µg/L 1.82 5.52Di-n-Octyl Phthalate 1 01/18/23 21:28 V29002JMV
<0.276 µg/L 0.276 2.21Fluoranthene 1 01/18/23 21:28 V29002JMV
<0.891 µg/L 0.891 2.21Fluorene 1 01/18/23 21:28 V29002JMV
<1.08 µg/L 1.08 5.52Hexachlorobenzene 1 01/18/23 21:28 V29002JMV
<3.01 µg/L 3.01 5.52Hexachlorobutadiene 1 01/18/23 21:28 V29002JMV
<2.26 µg/L 2.26 5.52Hexachlorocyclopentadiene 1 01/18/23 21:28 V29002JMV
<1.94 µg/L 1.94 5.52Hexachloroethane 1 01/18/23 21:28 V29002JMV
<0.527 µg/L 0.527 2.21Indeno(1,2,3-cd)pyrene 1 01/18/23 21:28 V29002JMV
<0.490 µg/L 0.490 5.52Isophorone 1 01/18/23 21:28 V29002JMV
<1.26 µg/L 1.26 2.21
1-Methylnaphthalene 1 01/18/23 21:28 V29002JMV
1.53 J µg/L 0.735 2.212-Methylnaphthalene 1 01/18/23 21:28 V29002JMV
7.98 µg/L 0.804 2.21Naphthalene 1 01/18/23 21:28 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 47 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.999 µg/L 0.999 5.52Nitrobenzene 1 01/18/23 21:28 V29002JMV
<0.544 µg/L 0.544 5.52
2-Nitrophenol 1 01/18/23 21:28 V29002JMV
<1.35 µg/L 1.35 11.04-Nitrophenol 1 01/18/23 21:28 V29002JMV
<1.21 µg/L 1.21 5.52N-Nitrosodiphenylamine 1 01/18/23 21:28 V29002JMV
<0.707 µg/L 0.707 5.52N-Nitroso-di-n-propylamine 1 01/18/23 21:28 V29002JMV
<1.58 µg/L 1.58 5.52
Pentachlorophenol 1 01/18/23 21:28 V29002JMV
<0.472 µg/L 0.472 2.21Phenanthrene 1 01/18/23 21:28 V29002JMV
<0.718 µg/L 0.718 5.52Phenol 1 01/18/23 21:28 V29002JMV
<0.479 µg/L 0.479 2.21Pyrene 1 01/18/23 21:28 V29002JMV
<2.44 µg/L 2.44 5.521,2,4-Trichlorobenzene 1 01/18/23 21:28 V29002JMV
<1.46 µg/L 1.46 5.522,4,6-Trichlorophenol 1 01/18/23 21:28 V29002JMV
625.1Surrogate: Phenol-d5 28.4 Limits: 10-63%01/18/23 21:281 JMV
Surrogate: 2-Fluorobiphenyl 68.8 Limits: 49-118%01/18/23 21:281 JMV V29002
Surrogate: 2-Fluorophenol 41.3 Limits: 22-84%01/18/23 21:281 JMV V29002
Surrogate: Nitrobenzene-d5 60.0 Limits: 43-123%01/18/23 21:281 JMV V29002
Surrogate: 4-Terphenyl-d14 78.6 Limits: 49-151%01/18/23 21:281 JMV V29002
Surrogate: 2,4,6-Tribromophenol 75.5 Limits: 31-144%01/18/23 21:281 JMV V29002
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V28888 01/16/23 09:30
<0.00342 µg/L 0.00342 0.02071,2-Dibromoethane 1 01/16/23 13:16 V28908AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 48 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
266 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/12/23 13:27
189 µg/L 25.8 50.0
Aliphatics C9-C12 (Adjusted)1 01/12/23 13:27
114 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 01/12/23 13:27
<63.6 µg/L 63.6 260Aromatic C11-C22 (Adjusted)1 01/19/23 17:48
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V28971 01/18/23 10:00
<29.4 µg/L 29.4 365Aliphatic C9-C18 1 01/19/23 17:48 V29026AMP
<129 µg/L 129 521Aliphatic C19-C36 1 01/19/23 17:48 V29026AMP
<63.6 µg/L 63.6 260
Aromatic C11-C22 1 01/19/23 17:48 V29026AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 143 *Limits: 40-140%01/19/23 17:481 AMP
MADEP-EPHSurrogate: Chlorooctadecane 88.5 Limits: 40-140%01/19/23 17:481 AMP
MADEP-EPHSurrogate: OTP Surrogate 105 Limits: 40-140%01/19/23 17:481 AMP
Surrogate: 2-Fluorobiphenyl 141 *Limits: 40-140%01/19/23 17:481 AMP V29026
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
440 µg/L 11.5 50.0Aliphatic C5-C8 1 01/12/23 13:27 V28855TBL
558 µg/L 25.8 50.0Aliphatic C9-C12 1 01/12/23 13:27 V28855TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 49 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-6
97308 Matrix:
1/10/2023 14:25
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
114 µg/L 4.02 50.0Aromatic C9-C10 1 01/12/23 13:27 V28855TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)81.9 Limits: 70-130%01/12/23 13:271 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)75.6 Limits: 70-130%01/12/23 13:271 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 50 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/24/23 07:16 6200BMSA
See Attached mg/L 0.006Lead 1 EPA-200.7BKN
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 51 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/24/23 07:16 V29119MSA
382 µg/L 18.0 50.0
Benzene 100 01/26/23 15:58 V29244MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/24/23 07:16 V29119MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/24/23 07:16 V29119MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/24/23 07:16 V29119MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/24/23 07:16 V29119MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/24/23 07:16 V29119MSA
4.96 µg/L 0.180 0.500n-Butylbenzene 1 01/24/23 07:16 V29119MSA
3.30 µg/L 0.200 0.500sec-Butyl benzene 1 01/24/23 07:16 V29119MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/24/23 07:16 V29119MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/24/23 07:16 V29119MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/24/23 07:16 V29119MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/24/23 07:16 V29119MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/24/23 07:16 V29119MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/24/23 07:16 V29119MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/24/23 07:16 V29119MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/24/23 07:16 V29119MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/24/23 07:16 V29119MSA
3.03 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/24/23 07:16 V29119MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/24/23 07:16 V29119MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/24/23 07:16 V29119MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/24/23 07:16 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 52 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/24/23 07:16 V29119MSA
<0.210 µg/L 0.210 0.500
1,4-Dichlorobenzene 1 01/24/23 07:16 V29119MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/24/23 07:16 V29119MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/24/23 07:16 V29119MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/24/23 07:16 V29119MSA
<0.150 µg/L 0.150 0.500
1,1-Dichloroethene 1 01/24/23 07:16 V29119MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/24/23 07:16 V29119MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/24/23 07:16 V29119MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/24/23 07:16 V29119MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/24/23 07:16 V29119MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/24/23 07:16 V29119MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/24/23 07:16 V29119MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/24/23 07:16 V29119MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/24/23 07:16 V29119MSA
<42.0 µg/L 42.0 200Ethanol 1 01/24/23 07:16 V29119MSA
448 µg/L 17.0 50.0Ethylbenzene 100 01/26/23 15:58 V29244MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/24/23 07:16 V29119MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/24/23 07:16 V29119MSA
19.1 µg/L 0.180 0.500Isopropylbenzene 1 01/24/23 07:16 V29119MSA
1.27 µg/L 0.089 0.500
4-Isopropyl toluene 1 01/24/23 07:16 V29119MSA
17.2 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/24/23 07:16 V29119MSA
440 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 01/26/23 15:58 V29244MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 53 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
5.11 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/24/23 07:16 V29119MSA
<0.330 µg/L 0.330 2.00
Methylene Chloride 1 01/24/23 07:16 V29119MSA
157 µg/L 47.0 100Naphthalene 100 01/26/23 15:58 V29244MSA
37.4 µg/L 0.190 0.500n-Propylbenzene 1 01/24/23 07:16 V29119MSA
6.19 µg/L 0.220 0.500Styrene 1 01/24/23 07:16 V29119MSA
139 µg/L 1.60 10.0
tert-Butyl Alcohol (TBA)1 01/24/23 07:16 V29119MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/24/23 07:16 V29119MSA
532 J µg/L 190 1000tert-Amyl Alcohol (TAA)100 01/26/23 15:58 V29244MSA
56.8 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/24/23 07:16 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/24/23 07:16 V29119MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/24/23 07:16 V29119MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/24/23 07:16 V29119MSA
2130 µg/L 22.0 50.0Toluene 100 01/26/23 15:58 V29244MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/24/23 07:16 V29119MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/24/23 07:16 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/24/23 07:16 V29119MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/24/23 07:16 V29119MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/24/23 07:16 V29119MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 01/24/23 07:16 V29119MSA
<0.270 µg/L 0.270 0.500
1,2,3-Trichloropropane 1 01/24/23 07:16 V29119MSA
594 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 01/26/23 15:58 V29244MSA
171 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 01/26/23 15:58 V29244MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 54 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00 V29243 01/26/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/24/23 07:16 V29119MSA
<0.170 µg/L 0.170 0.500
Vinyl Chloride 1 01/24/23 07:16 V29119MSA
941 µg/L 21.0 50.0o-Xylene 100 01/26/23 15:58 V29244MSA
1680 µg/L 42.0 100m,p-Xylene 100 01/26/23 15:58 V29244MSA
2620 µg/L 21.0 50.0Xylene (Total)100 01/26/23 15:58 V29244
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%01/24/23 07:161 MSA V29119
Surrogate: Dibromofluoromethane 88.6 Limits: 70-130%01/24/23 07:161 MSA V29119
Surrogate: 1,2-Dichloroethane - d4 94.6 Limits: 70-130%01/24/23 07:161 MSA V29119
Surrogate: Toluene-d8 87.0 Limits: 70-130%01/24/23 07:161 MSA V29119
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%01/26/23 15:58100 MSA V29244
Surrogate: Dibromofluoromethane 101 Limits: 70-130%01/26/23 15:58100 MSA V29244
Surrogate: 1,2-Dichloroethane - d4 99.6 Limits: 70-130%01/26/23 15:58100 MSA V29244
Surrogate: Toluene-d8 109 Limits: 70-130%01/26/23 15:58100 MSA V29244
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.335 µg/L 0.335 2.22
Acenaphthene 1 01/18/23 21:05 V29002JMV
<0.329 µg/L 0.329 2.22Acenaphthylene 1 01/18/23 21:05 V29002JMV
<0.927 µg/L 0.927 2.22Anthracene 1 01/18/23 21:05 V29002JMV
<1.47 µg/L 1.47 11.1Benzidine 1 01/18/23 21:05 V29002JMV
<0.707 µg/L 0.707 2.22
Benzo(a)anthracene 1 01/18/23 21:05 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 55 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.13 µg/L 1.13 2.22Benzo(a)pyrene 1 01/18/23 21:05 V29002JMV
<2.77 µg/L 2.77 5.56
Benzo(b)fluoranthene 1 01/18/23 21:05 V29002JMV
<1.12 µg/L 1.12 5.56Benzo(g,h,i)perylene 1 01/18/23 21:05 V29002JMV
<2.21 µg/L 2.21 5.56Benzo(k)fluoranthene 1 01/18/23 21:05 V29002JMV
<1.22 µg/L 1.22 11.1Benzoic Acid 1 01/18/23 21:05 V29002JMV
<0.760 µg/L 0.760 5.56
Benzyl alcohol 1 01/18/23 21:05 V29002JMV
<0.520 µg/L 0.520 5.56Bis(2-Chloroethoxy)methane 1 01/18/23 21:05 V29002JMV
<1.16 µg/L 1.16 5.56Bis(2-Chloroethyl)ether 1 01/18/23 21:05 V29002JMV
<1.20 µg/L 1.20 5.56Bis(2-Chloroisopropyl)ether 1 01/18/23 21:05 V29002JMV
<26.7 µg/L 26.7 55.6Bis(2-ethylhexyl)phthalate 1 01/18/23 21:05 V29002JMV
<1.23 µg/L 1.23 5.564-Bromophenyl phenyl ether 1 01/18/23 21:05 V29002JMV
<2.03 µg/L 2.03 5.56Butyl benzyl phthalate 1 01/18/23 21:05 V29002JMV
<1.31 µg/L 1.31 5.564-Chloro-3-methylphenol 1 01/18/23 21:05 V29002JMV
<8.19 µg/L 8.19 22.22-Chloronaphthalene 1 01/18/23 21:05 V29002JMV
<1.04 µg/L 1.04 11.12-Chlorophenol 1 01/18/23 21:05 V29002JMV
<1.90 µg/L 1.90 5.564-Chlorophenyl phenyl ether 1 01/18/23 21:05 V29002JMV
<0.449 µg/L 0.449 2.22Chrysene 1 01/18/23 21:05 V29002JMV
<0.481 µg/L 0.481 2.22Dibenz(a,h)anthracene 1 01/18/23 21:05 V29002JMV
<0.951 µg/L 0.951 5.56Dibenzofuran 1 01/18/23 21:05 V29002JMV
<2.22 µg/L 2.22 5.56
1,2-Dichlorobenzene 1 01/18/23 21:05 V29002JMV
<2.22 µg/L 2.22 5.561,3-Dichlorobenzene 1 01/18/23 21:05 V29002JMV
<2.28 µg/L 2.28 5.561,4-Dichlorobenzene 1 01/18/23 21:05 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 56 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<2.10 µg/L 2.10 5.563,3'-Dichlorobenzidine 1 01/18/23 21:05 V29002JMV
<1.62 µg/L 1.62 11.1
2,4-Dichlorophenol 1 01/18/23 21:05 V29002JMV
<0.828 µg/L 0.828 5.56Diethyl phthalate 1 01/18/23 21:05 V29002JMV
<1.04 µg/L 1.04 5.56Dimethyl phthalate 1 01/18/23 21:05 V29002JMV
5.76 J µg/L 1.74 22.22,4-Dimethylphenol 1 01/18/23 21:05 V29002JMV
<2.29 µg/L 2.29 5.56
Di-n-butyl phthalate 1 01/18/23 21:05 V29002JMV
<2.30 µg/L 2.30 11.14,6-Dinitro-2-methylphenol 1 01/18/23 21:05 V29002JMV
<2.13 µg/L 2.13 11.12,4-Dinitrophenol 1 01/18/23 21:05 V29002JMV
<1.23 µg/L 1.23 5.562,4-Dinitrotoluene 1 01/18/23 21:05 V29002JMV
<0.899 µg/L 0.899 5.562,6-Dinitrotoluene 1 01/18/23 21:05 V29002JMV
<1.83 µg/L 1.83 5.56Di-n-Octyl Phthalate 1 01/18/23 21:05 V29002JMV
<0.277 µg/L 0.277 2.22Fluoranthene 1 01/18/23 21:05 V29002JMV
<0.895 µg/L 0.895 2.22Fluorene 1 01/18/23 21:05 V29002JMV
<1.09 µg/L 1.09 5.56Hexachlorobenzene 1 01/18/23 21:05 V29002JMV
<3.04 µg/L 3.04 5.56Hexachlorobutadiene 1 01/18/23 21:05 V29002JMV
<2.28 µg/L 2.28 5.56Hexachlorocyclopentadiene 1 01/18/23 21:05 V29002JMV
<1.96 µg/L 1.96 5.56Hexachloroethane 1 01/18/23 21:05 V29002JMV
<0.529 µg/L 0.529 2.22Indeno(1,2,3-cd)pyrene 1 01/18/23 21:05 V29002JMV
<0.493 µg/L 0.493 5.56Isophorone 1 01/18/23 21:05 V29002JMV
8.67 µg/L 1.27 2.22
1-Methylnaphthalene 1 01/18/23 21:05 V29002JMV
15.3 µg/L 0.739 2.222-Methylnaphthalene 1 01/18/23 21:05 V29002JMV
53.7 µg/L 0.808 2.22Naphthalene 1 01/18/23 21:05 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 57 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.01 µg/L 1.01 5.56Nitrobenzene 1 01/18/23 21:05 V29002JMV
<0.548 µg/L 0.548 5.56
2-Nitrophenol 1 01/18/23 21:05 V29002JMV
<1.37 µg/L 1.37 11.14-Nitrophenol 1 01/18/23 21:05 V29002JMV
<1.22 µg/L 1.22 5.56N-Nitrosodiphenylamine 1 01/18/23 21:05 V29002JMV
<0.712 µg/L 0.712 5.56N-Nitroso-di-n-propylamine 1 01/18/23 21:05 V29002JMV
<1.59 µg/L 1.59 5.56
Pentachlorophenol 1 01/18/23 21:05 V29002JMV
<0.475 µg/L 0.475 2.22Phenanthrene 1 01/18/23 21:05 V29002JMV
<0.723 µg/L 0.723 5.56Phenol 1 01/18/23 21:05 V29002JMV
<0.481 µg/L 0.481 2.22Pyrene 1 01/18/23 21:05 V29002JMV
<2.46 µg/L 2.46 5.561,2,4-Trichlorobenzene 1 01/18/23 21:05 V29002JMV
<1.47 µg/L 1.47 5.562,4,6-Trichlorophenol 1 01/18/23 21:05 V29002JMV
625.1Surrogate: Phenol-d5 28.8 Limits: 10-63%01/18/23 21:051 JMV
Surrogate: 2-Fluorobiphenyl 60.6 Limits: 49-118%01/18/23 21:051 JMV V29002
Surrogate: 2-Fluorophenol 40.5 Limits: 22-84%01/18/23 21:051 JMV V29002
Surrogate: Nitrobenzene-d5 54.0 Limits: 43-123%01/18/23 21:051 JMV V29002
Surrogate: 4-Terphenyl-d14 74.6 Limits: 49-151%01/18/23 21:051 JMV V29002
Surrogate: 2,4,6-Tribromophenol 67.5 Limits: 31-144%01/18/23 21:051 JMV V29002
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V28888 01/16/23 09:30
0.0133 JQ µg/L 0.00338 0.02051,2-Dibromoethane 1 01/16/23 13:54 V28908AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 58 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
1550 µg/L 115 500Aliphatic C5-C8 (Adjusted)10 01/13/23 09:46
1060 µg/L 258 500
Aliphatics C9-C12 (Adjusted)10 01/13/23 09:46
1240 µg/L 40.2 500Aromatic C9-C10 (Adjusted)10 01/13/23 09:46
208 µg/L 61.2 250Aromatic C11-C22 (Adjusted)1 01/18/23 21:05
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V28971 01/18/23 10:00
58.1 J µg/L 28.2 350Aliphatic C9-C18 1 01/19/23 18:24 V29026AMP
<124 µg/L 124 500Aliphatic C19-C36 1 01/19/23 18:24 V29026AMP
262 µg/L 61.2 250
Aromatic C11-C22 1 01/19/23 18:24 V29026AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 144 *Limits: 40-140%01/19/23 18:241 AMP
MADEP-EPHSurrogate: Chlorooctadecane 81.5 Limits: 40-140%01/19/23 18:241 AMP
MADEP-EPHSurrogate: OTP Surrogate 108 Limits: 40-140%01/19/23 18:241 AMP
Surrogate: 2-Fluorobiphenyl 149 *Limits: 40-140%01/19/23 18:241 AMP V29026
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
4060 µg/L 115 500Aliphatic C5-C8 10 01/13/23 09:46 V28855TBL
5370 µg/L 258 500Aliphatic C9-C12 10 01/13/23 09:46 V28855TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 59 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-7
97309 Matrix:
1/10/2023 14:18
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
1240 µg/L 40.2 500Aromatic C9-C10 10 01/13/23 09:46 V28855TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)81.9 Limits: 70-130%01/13/23 09:4610 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)77.1 Limits: 70-130%01/13/23 09:4610 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 60 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/23/23 14:12 6200BMSA
See Attached mg/L 0.006Lead 1 EPA-200.7BKN
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 61 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 01/23/23 14:12 V29117MSA
2.28 µg/L 0.180 0.500
Benzene 1 01/23/23 14:12 V29117MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/23/23 14:12 V29117MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/23/23 14:12 V29117MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/23/23 14:12 V29117MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/23/23 14:12 V29117MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/23/23 14:12 V29117MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/23/23 14:12 V29117MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/23/23 14:12 V29117MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/23/23 14:12 V29117MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/23/23 14:12 V29117MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/23/23 14:12 V29117MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/23/23 14:12 V29117MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/23/23 14:12 V29117MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/23/23 14:12 V29117MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/23/23 14:12 V29117MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/23/23 14:12 V29117MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/23/23 14:12 V29117MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/23/23 14:12 V29117MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/23/23 14:12 V29117MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/23/23 14:12 V29117MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/23/23 14:12 V29117MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 62 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/23/23 14:12 V29117MSA
<0.210 µg/L 0.210 0.500
1,4-Dichlorobenzene 1 01/23/23 14:12 V29117MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/23/23 14:12 V29117MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/23/23 14:12 V29117MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/23/23 14:12 V29117MSA
<0.150 µg/L 0.150 0.500
1,1-Dichloroethene 1 01/23/23 14:12 V29117MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/23/23 14:12 V29117MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/23/23 14:12 V29117MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/23/23 14:12 V29117MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/23/23 14:12 V29117MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/23/23 14:12 V29117MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/23/23 14:12 V29117MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/23/23 14:12 V29117MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/23/23 14:12 V29117MSA
<42.0 µg/L 42.0 200Ethanol 1 01/23/23 14:12 V29117MSA
4.83 µg/L 0.170 0.500Ethylbenzene 1 01/23/23 14:12 V29117MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/23/23 14:12 V29117MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/23/23 14:12 V29117MSA
0.364 J µg/L 0.180 0.500Isopropylbenzene 1 01/23/23 14:12 V29117MSA
<0.089 µg/L 0.089 0.500
4-Isopropyl toluene 1 01/23/23 14:12 V29117MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/23/23 14:12 V29117MSA
0.228 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/23/23 14:12 V29117MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 63 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/23/23 14:12 V29117MSA
<0.330 µg/L 0.330 2.00
Methylene Chloride 1 01/23/23 14:12 V29117MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/23/23 14:12 V29117MSA
0.894 µg/L 0.190 0.500n-Propylbenzene 1 01/23/23 14:12 V29117MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/23/23 14:12 V29117MSA
4.44 J
µg/L 1.60 10.0
tert-Butyl Alcohol (TBA)1 01/23/23 14:12 V29117MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/23/23 14:12 V29117MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/23/23 14:12 V29117MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/23/23 14:12 V29117MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/23/23 14:12 V29117MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/23/23 14:12 V29117MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/23/23 14:12 V29117MSA
4.19 µg/L 0.220 0.500Toluene 1 01/23/23 14:12 V29117MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/23/23 14:12 V29117MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/23/23 14:12 V29117MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/23/23 14:12 V29117MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/23/23 14:12 V29117MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/23/23 14:12 V29117MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 01/23/23 14:12 V29117MSA
<0.270 µg/L 0.270 0.500
1,2,3-Trichloropropane 1 01/23/23 14:12 V29117MSA
5.61 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/23/23 14:12 V29117MSA
2.30 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/23/23 14:12 V29117MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 64 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/23/23 14:12 V29117MSA
<0.170 µg/L 0.170 0.500
Vinyl Chloride 1 01/23/23 14:12 V29117MSA
6.30 µg/L 0.210 0.500o-Xylene 1 01/23/23 14:12 V29117MSA
14.4 µg/L 0.420 1.00m,p-Xylene 1 01/23/23 14:12 V29117MSA
20.7 µg/L 0.210 0.500Xylene (Total)1 01/23/23 14:12 V29117KCC
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%01/23/23 14:121 MSA V29117
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%01/23/23 14:121 MSA V29117
Surrogate: 1,2-Dichloroethane - d4 99.0 Limits: 70-130%01/23/23 14:121 MSA V29117
Surrogate: Toluene-d8 101 Limits: 70-130%01/23/23 14:121 MSA V29117
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.309 µg/L 0.309 2.05
Acenaphthene 1 01/18/23 19:35 V29002JMV
<0.304 µg/L 0.304 2.05Acenaphthylene 1 01/18/23 19:35 V29002JMV
<0.856 µg/L 0.856 2.05Anthracene 1 01/18/23 19:35 V29002JMV
<1.36 µg/L 1.36 10.3Benzidine 1 01/18/23 19:35 V29002JMV
<0.652 µg/L 0.652 2.05
Benzo(a)anthracene 1 01/18/23 19:35 V29002JMV
<1.05 µg/L 1.05 2.05Benzo(a)pyrene 1 01/18/23 19:35 V29002JMV
<2.55 µg/L 2.55 5.13Benzo(b)fluoranthene 1 01/18/23 19:35 V29002JMV
<1.04 µg/L 1.04 5.13Benzo(g,h,i)perylene 1 01/18/23 19:35 V29002JMV
<2.04 µg/L 2.04 5.13Benzo(k)fluoranthene 1 01/18/23 19:35 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 65 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.13 µg/L 1.13 10.3Benzoic Acid 1 01/18/23 19:35 V29002JMV
<0.701 µg/L 0.701 5.13
Benzyl alcohol 1 01/18/23 19:35 V29002JMV
<0.480 µg/L 0.480 5.13Bis(2-Chloroethoxy)methane 1 01/18/23 19:35 V29002JMV
<1.07 µg/L 1.07 5.13Bis(2-Chloroethyl)ether 1 01/18/23 19:35 V29002JMV
<1.11 µg/L 1.11 5.13Bis(2-Chloroisopropyl)ether 1 01/18/23 19:35 V29002JMV
<24.7 µg/L 24.7 51.3
Bis(2-ethylhexyl)phthalate 1 01/18/23 19:35 V29002JMV
<1.14 µg/L 1.14 5.134-Bromophenyl phenyl ether 1 01/18/23 19:35 V29002JMV
<1.88 µg/L 1.88 5.13Butyl benzyl phthalate 1 01/18/23 19:35 V29002JMV
<1.21 µg/L 1.21 5.134-Chloro-3-methylphenol 1 01/18/23 19:35 V29002JMV
<7.56 µg/L 7.56 20.52-Chloronaphthalene 1 01/18/23 19:35 V29002JMV
<0.966 µg/L 0.966 10.32-Chlorophenol 1 01/18/23 19:35 V29002JMV
<1.75 µg/L 1.75 5.134-Chlorophenyl phenyl ether 1 01/18/23 19:35 V29002JMV
<0.415 µg/L 0.415 2.05Chrysene 1 01/18/23 19:35 V29002JMV
<0.444 µg/L 0.444 2.05Dibenz(a,h)anthracene 1 01/18/23 19:35 V29002JMV
<0.878 µg/L 0.878 5.13Dibenzofuran 1 01/18/23 19:35 V29002JMV
<2.05 µg/L 2.05 5.131,2-Dichlorobenzene 1 01/18/23 19:35 V29002JMV
<2.05 µg/L 2.05 5.131,3-Dichlorobenzene 1 01/18/23 19:35 V29002JMV
<2.10 µg/L 2.10 5.131,4-Dichlorobenzene 1 01/18/23 19:35 V29002JMV
<1.94 µg/L 1.94 5.133,3'-Dichlorobenzidine 1 01/18/23 19:35 V29002JMV
<1.50 µg/L 1.50 10.3
2,4-Dichlorophenol 1 01/18/23 19:35 V29002JMV
<0.764 µg/L 0.764 5.13Diethyl phthalate 1 01/18/23 19:35 V29002JMV
<0.963 µg/L 0.963 5.13Dimethyl phthalate 1 01/18/23 19:35 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 66 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.61 µg/L 1.61 20.52,4-Dimethylphenol 1 01/18/23 19:35 V29002JMV
<2.11 µg/L 2.11 5.13
Di-n-butyl phthalate 1 01/18/23 19:35 V29002JMV
<2.13 µg/L 2.13 10.34,6-Dinitro-2-methylphenol 1 01/18/23 19:35 V29002JMV
<1.98 µg/L 1.98 10.32,4-Dinitrophenol 1 01/18/23 19:35 V29002JMV
<1.14 µg/L 1.14 5.132,4-Dinitrotoluene 1 01/18/23 19:35 V29002JMV
<0.830 µg/L 0.830 5.13
2,6-Dinitrotoluene 1 01/18/23 19:35 V29002JMV
<1.69 µg/L 1.69 5.13Di-n-Octyl Phthalate 1 01/18/23 19:35 V29002JMV
<0.256 µg/L 0.256 2.05Fluoranthene 1 01/18/23 19:35 V29002JMV
<0.827 µg/L 0.827 2.05Fluorene 1 01/18/23 19:35 V29002JMV
<1.00 µg/L 1.00 5.13Hexachlorobenzene 1 01/18/23 19:35 V29002JMV
<2.80 µg/L 2.80 5.13Hexachlorobutadiene 1 01/18/23 19:35 V29002JMV
<2.10 µg/L 2.10 5.13Hexachlorocyclopentadiene 1 01/18/23 19:35 V29002JMV
<1.81 µg/L 1.81 5.13Hexachloroethane 1 01/18/23 19:35 V29002JMV
<0.488 µg/L 0.488 2.05Indeno(1,2,3-cd)pyrene 1 01/18/23 19:35 V29002JMV
<0.455 µg/L 0.455 5.13Isophorone 1 01/18/23 19:35 V29002JMV
<1.17 µg/L 1.17 2.051-Methylnaphthalene 1 01/18/23 19:35 V29002JMV
<0.682 µg/L 0.682 2.052-Methylnaphthalene 1 01/18/23 19:35 V29002JMV
<0.746 µg/L 0.746 2.05Naphthalene 1 01/18/23 19:35 V29002JMV
<0.928 µg/L 0.928 5.13Nitrobenzene 1 01/18/23 19:35 V29002JMV
<0.505 µg/L 0.505 5.13
2-Nitrophenol 1 01/18/23 19:35 V29002JMV
<1.27 µg/L 1.27 10.34-Nitrophenol 1 01/18/23 19:35 V29002JMV
<1.13 µg/L 1.13 5.13N-Nitrosodiphenylamine 1 01/18/23 19:35 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 67 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.657 µg/L 0.657 5.13N-Nitroso-di-n-propylamine 1 01/18/23 19:35 V29002JMV
<1.47 µg/L 1.47 5.13
Pentachlorophenol 1 01/18/23 19:35 V29002JMV
<0.438 µg/L 0.438 2.05Phenanthrene 1 01/18/23 19:35 V29002JMV
<0.667 µg/L 0.667 5.13Phenol 1 01/18/23 19:35 V29002JMV
<0.444 µg/L 0.444 2.05Pyrene 1 01/18/23 19:35 V29002JMV
<2.27 µg/L 2.27 5.13
1,2,4-Trichlorobenzene 1 01/18/23 19:35 V29002JMV
<1.35 µg/L 1.35 5.132,4,6-Trichlorophenol 1 01/18/23 19:35 V29002JMV
625.1Surrogate: Phenol-d5 26.0 Limits: 10-63%01/18/23 19:351 JMV
Surrogate: 2-Fluorobiphenyl 67.1 Limits: 49-118%01/18/23 19:351 JMV V29002
Surrogate: 2-Fluorophenol 35.1 Limits: 22-84%01/18/23 19:351 JMV V29002
Surrogate: Nitrobenzene-d5 58.1 Limits: 43-123%01/18/23 19:351 JMV V29002
Surrogate: 4-Terphenyl-d14 77.8 Limits: 49-151%01/18/23 19:351 JMV V29002
Surrogate: 2,4,6-Tribromophenol 72.5 Limits: 31-144%01/18/23 19:351 JMV V29002
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V28888 01/16/23 09:30
<0.00333 µg/L 0.00333 0.02021,2-Dibromoethane 1 01/16/23 14:14 V28908AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 68 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8
97310 Matrix:
1/10/2023 13:45
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/12/23 14:15
55.3 J
µg/L 25.8 50.0
Aliphatics C9-C12 (Adjusted)1 01/12/23 14:15
13.6 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 01/12/23 14:15
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 01/12/23 14:15 V28855TBL
94.4 µg/L 25.8 50.0Aliphatic C9-C12 1 01/12/23 14:15 V28855TBL
13.6 J µg/L 4.02 50.0Aromatic C9-C10 1 01/12/23 14:15 V28855TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)81.9 Limits: 70-130%01/12/23 14:151 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)75.1 Limits: 70-130%01/12/23 14:151 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 69 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/24/23 03:06 6200BMSA
See Attached mg/L 0.006Lead 1 EPA-200.7BKN
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 70 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00
10.8 µg/L 1.80 10.0Acetone 1 01/24/23 03:06 V29119MSA
0.566 µg/L 0.180 0.500
Benzene 1 01/24/23 03:06 V29119MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/24/23 03:06 V29119MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/24/23 03:06 V29119MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/24/23 03:06 V29119MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/24/23 03:06 V29119MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/24/23 03:06 V29119MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/24/23 03:06 V29119MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/24/23 03:06 V29119MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/24/23 03:06 V29119MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/24/23 03:06 V29119MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/24/23 03:06 V29119MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/24/23 03:06 V29119MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/24/23 03:06 V29119MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/24/23 03:06 V29119MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/24/23 03:06 V29119MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/24/23 03:06 V29119MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/24/23 03:06 V29119MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/24/23 03:06 V29119MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/24/23 03:06 V29119MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/24/23 03:06 V29119MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/24/23 03:06 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 71 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 01/24/23 03:06 V29119MSA
<0.210 µg/L 0.210 0.500
1,4-Dichlorobenzene 1 01/24/23 03:06 V29119MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/24/23 03:06 V29119MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/24/23 03:06 V29119MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 01/24/23 03:06 V29119MSA
<0.150 µg/L 0.150 0.500
1,1-Dichloroethene 1 01/24/23 03:06 V29119MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/24/23 03:06 V29119MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/24/23 03:06 V29119MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/24/23 03:06 V29119MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/24/23 03:06 V29119MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/24/23 03:06 V29119MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/24/23 03:06 V29119MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/24/23 03:06 V29119MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/24/23 03:06 V29119MSA
<42.0 µg/L 42.0 200Ethanol 1 01/24/23 03:06 V29119MSA
0.473 J µg/L 0.170 0.500Ethylbenzene 1 01/24/23 03:06 V29119MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/24/23 03:06 V29119MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/24/23 03:06 V29119MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 01/24/23 03:06 V29119MSA
<0.089 µg/L 0.089 0.500
4-Isopropyl toluene 1 01/24/23 03:06 V29119MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/24/23 03:06 V29119MSA
0.972 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/24/23 03:06 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 72 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 01/24/23 03:06 V29119MSA
<0.330 µg/L 0.330 2.00
Methylene Chloride 1 01/24/23 03:06 V29119MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/24/23 03:06 V29119MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/24/23 03:06 V29119MSA
<0.220 µg/L 0.220 0.500Styrene 1 01/24/23 03:06 V29119MSA
5.47 J
µg/L 1.60 10.0
tert-Butyl Alcohol (TBA)1 01/24/23 03:06 V29119MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/24/23 03:06 V29119MSA
3.08 J µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/24/23 03:06 V29119MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/24/23 03:06 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/24/23 03:06 V29119MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/24/23 03:06 V29119MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/24/23 03:06 V29119MSA
0.697 µg/L 0.220 0.500Toluene 1 01/24/23 03:06 V29119MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/24/23 03:06 V29119MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/24/23 03:06 V29119MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/24/23 03:06 V29119MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/24/23 03:06 V29119MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/24/23 03:06 V29119MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 01/24/23 03:06 V29119MSA
<0.270 µg/L 0.270 0.500
1,2,3-Trichloropropane 1 01/24/23 03:06 V29119MSA
0.918 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/24/23 03:06 V29119MSA
0.305 J µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/24/23 03:06 V29119MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 73 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29118 01/23/23 14:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 01/24/23 03:06 V29119MSA
<0.170 µg/L 0.170 0.500
Vinyl Chloride 1 01/24/23 03:06 V29119MSA
0.690 µg/L 0.210 0.500o-Xylene 1 01/24/23 03:06 V29119MSA
1.34 µg/L 0.420 1.00m,p-Xylene 1 01/24/23 03:06 V29119MSA
2.03 µg/L 0.210 0.500Xylene (Total)1 01/24/23 03:06 V29119KCC
Surrogate: 4-Bromofluorobenzene 106 Limits: 70-130%01/24/23 03:061 MSA V29119
Surrogate: Dibromofluoromethane 93.6 Limits: 70-130%01/24/23 03:061 MSA V29119
Surrogate: 1,2-Dichloroethane - d4 98.8 Limits: 70-130%01/24/23 03:061 MSA V29119
Surrogate: Toluene-d8 97.8 Limits: 70-130%01/24/23 03:061 MSA V29119
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.333 µg/L 0.333 2.21
Acenaphthene 1 01/18/23 19:58 V29002JMV
<0.328 µg/L 0.328 2.21Acenaphthylene 1 01/18/23 19:58 V29002JMV
<0.923 µg/L 0.923 2.21Anthracene 1 01/18/23 19:58 V29002JMV
<1.45 µg/L 1.45 11.0Benzidine 1 01/18/23 19:58 V29002JMV
<0.703 µg/L 0.703 2.21
Benzo(a)anthracene 1 01/18/23 19:58 V29002JMV
<1.13 µg/L 1.13 2.21Benzo(a)pyrene 1 01/18/23 19:58 V29002JMV
<2.75 µg/L 2.75 5.52Benzo(b)fluoranthene 1 01/18/23 19:58 V29002JMV
<1.12 µg/L 1.12 5.52Benzo(g,h,i)perylene 1 01/18/23 19:58 V29002JMV
<2.20 µg/L 2.20 5.52Benzo(k)fluoranthene 1 01/18/23 19:58 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 74 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.21 µg/L 1.21 11.0Benzoic Acid 1 01/18/23 19:58 V29002JMV
<0.755 µg/L 0.755 5.52
Benzyl alcohol 1 01/18/23 19:58 V29002JMV
<0.516 µg/L 0.516 5.52Bis(2-Chloroethoxy)methane 1 01/18/23 19:58 V29002JMV
<1.15 µg/L 1.15 5.52Bis(2-Chloroethyl)ether 1 01/18/23 19:58 V29002JMV
<1.19 µg/L 1.19 5.52Bis(2-Chloroisopropyl)ether 1 01/18/23 19:58 V29002JMV
<26.5 µg/L 26.5 55.2
Bis(2-ethylhexyl)phthalate 1 01/18/23 19:58 V29002JMV
<1.23 µg/L 1.23 5.524-Bromophenyl phenyl ether 1 01/18/23 19:58 V29002JMV
<2.02 µg/L 2.02 5.52Butyl benzyl phthalate 1 01/18/23 19:58 V29002JMV
<1.30 µg/L 1.30 5.524-Chloro-3-methylphenol 1 01/18/23 19:58 V29002JMV
<8.15 µg/L 8.15 22.12-Chloronaphthalene 1 01/18/23 19:58 V29002JMV
<1.03 µg/L 1.03 11.02-Chlorophenol 1 01/18/23 19:58 V29002JMV
<1.89 µg/L 1.89 5.524-Chlorophenyl phenyl ether 1 01/18/23 19:58 V29002JMV
<0.447 µg/L 0.447 2.21Chrysene 1 01/18/23 19:58 V29002JMV
<0.479 µg/L 0.479 2.21Dibenz(a,h)anthracene 1 01/18/23 19:58 V29002JMV
<0.945 µg/L 0.945 5.52Dibenzofuran 1 01/18/23 19:58 V29002JMV
<2.21 µg/L 2.21 5.521,2-Dichlorobenzene 1 01/18/23 19:58 V29002JMV
<2.21 µg/L 2.21 5.521,3-Dichlorobenzene 1 01/18/23 19:58 V29002JMV
<2.26 µg/L 2.26 5.521,4-Dichlorobenzene 1 01/18/23 19:58 V29002JMV
<2.09 µg/L 2.09 5.523,3'-Dichlorobenzidine 1 01/18/23 19:58 V29002JMV
<1.61 µg/L 1.61 11.0
2,4-Dichlorophenol 1 01/18/23 19:58 V29002JMV
<0.822 µg/L 0.822 5.52Diethyl phthalate 1 01/18/23 19:58 V29002JMV
<1.04 µg/L 1.04 5.52Dimethyl phthalate 1 01/18/23 19:58 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 75 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<1.73 µg/L 1.73 22.12,4-Dimethylphenol 1 01/18/23 19:58 V29002JMV
<2.27 µg/L 2.27 5.52
Di-n-butyl phthalate 1 01/18/23 19:58 V29002JMV
<2.28 µg/L 2.28 11.04,6-Dinitro-2-methylphenol 1 01/18/23 19:58 V29002JMV
<2.11 µg/L 2.11 11.02,4-Dinitrophenol 1 01/18/23 19:58 V29002JMV
<1.23 µg/L 1.23 5.522,4-Dinitrotoluene 1 01/18/23 19:58 V29002JMV
<0.893 µg/L 0.893 5.52
2,6-Dinitrotoluene 1 01/18/23 19:58 V29002JMV
<1.82 µg/L 1.82 5.52Di-n-Octyl Phthalate 1 01/18/23 19:58 V29002JMV
<0.276 µg/L 0.276 2.21Fluoranthene 1 01/18/23 19:58 V29002JMV
<0.891 µg/L 0.891 2.21Fluorene 1 01/18/23 19:58 V29002JMV
<1.08 µg/L 1.08 5.52Hexachlorobenzene 1 01/18/23 19:58 V29002JMV
<3.01 µg/L 3.01 5.52Hexachlorobutadiene 1 01/18/23 19:58 V29002JMV
<2.26 µg/L 2.26 5.52Hexachlorocyclopentadiene 1 01/18/23 19:58 V29002JMV
<1.94 µg/L 1.94 5.52Hexachloroethane 1 01/18/23 19:58 V29002JMV
<0.527 µg/L 0.527 2.21Indeno(1,2,3-cd)pyrene 1 01/18/23 19:58 V29002JMV
<0.490 µg/L 0.490 5.52Isophorone 1 01/18/23 19:58 V29002JMV
<1.26 µg/L 1.26 2.211-Methylnaphthalene 1 01/18/23 19:58 V29002JMV
<0.735 µg/L 0.735 2.212-Methylnaphthalene 1 01/18/23 19:58 V29002JMV
<0.804 µg/L 0.804 2.21Naphthalene 1 01/18/23 19:58 V29002JMV
<0.999 µg/L 0.999 5.52Nitrobenzene 1 01/18/23 19:58 V29002JMV
<0.544 µg/L 0.544 5.52
2-Nitrophenol 1 01/18/23 19:58 V29002JMV
<1.35 µg/L 1.35 11.04-Nitrophenol 1 01/18/23 19:58 V29002JMV
<1.21 µg/L 1.21 5.52N-Nitrosodiphenylamine 1 01/18/23 19:58 V29002JMV
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 76 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V28943 01/17/23 08:54
<0.707 µg/L 0.707 5.52N-Nitroso-di-n-propylamine 1 01/18/23 19:58 V29002JMV
<1.58 µg/L 1.58 5.52
Pentachlorophenol 1 01/18/23 19:58 V29002JMV
<0.472 µg/L 0.472 2.21Phenanthrene 1 01/18/23 19:58 V29002JMV
<0.718 µg/L 0.718 5.52Phenol 1 01/18/23 19:58 V29002JMV
<0.479 µg/L 0.479 2.21Pyrene 1 01/18/23 19:58 V29002JMV
<2.44 µg/L 2.44 5.52
1,2,4-Trichlorobenzene 1 01/18/23 19:58 V29002JMV
<1.46 µg/L 1.46 5.522,4,6-Trichlorophenol 1 01/18/23 19:58 V29002JMV
625.1Surrogate: Phenol-d5 21.5 Limits: 10-63%01/18/23 19:581 JMV
Surrogate: 2-Fluorobiphenyl 50.9 Limits: 49-118%01/18/23 19:581 JMV V29002
Surrogate: 2-Fluorophenol 29.9 Limits: 22-84%01/18/23 19:581 JMV V29002
Surrogate: Nitrobenzene-d5 45.8 Limits: 43-123%01/18/23 19:581 JMV V29002
Surrogate: 4-Terphenyl-d14 62.9 Limits: 49-151%01/18/23 19:581 JMV V29002
Surrogate: 2,4,6-Tribromophenol 58.2 Limits: 31-144%01/18/23 19:581 JMV V29002
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V28888 01/16/23 09:30
<0.00343 µg/L 0.00343 0.02081,2-Dibromoethane 1 01/16/23 14:33 V28908AMP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 77 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/12/23 14:39
<25.8 µg/L 25.8 50.0
Aliphatics C9-C12 (Adjusted)1 01/12/23 14:39
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 01/12/23 14:39
<63.2 µg/L 63.2 258Aromatic C11-C22 (Adjusted)1 01/18/23 19:58
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V28971 01/18/23 10:00
<29.1 µg/L 29.1 361Aliphatic C9-C18 1 01/19/23 19:01 V29026AMP
<128 µg/L 128 515Aliphatic C19-C36 1 01/19/23 19:01 V29026AMP
<63.2 µg/L 63.2 258
Aromatic C11-C22 1 01/19/23 19:01 V29026AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 131 Limits: 40-140%01/19/23 19:011 AMP
MADEP-EPHSurrogate: Chlorooctadecane 87.4 Limits: 40-140%01/19/23 19:011 AMP
MADEP-EPHSurrogate: OTP Surrogate 94.7 Limits: 40-140%01/19/23 19:011 AMP
Surrogate: 2-Fluorobiphenyl 128 Limits: 40-140%01/19/23 19:011 AMP V29026
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 01/12/23 14:39 V28855TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 01/12/23 14:39 V28855TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 78 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1
97311 Matrix:
1/10/2023 14:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V28854 01/13/23 08:00
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 01/12/23 14:39 V28855TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)80.5 Limits: 70-130%01/12/23 14:391 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)77.4 Limits: 70-130%01/12/23 14:391 TBL
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 79 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TB
97312 Matrix:
1/10/2023 0:00
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 01/23/23 13:48 6200BMSA
Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%01/23/23 13:481 MSA V29117
Surrogate: Dibromofluoromethane 99.8 Limits: 70-130%01/23/23 13:481 MSA V29117
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%01/23/23 13:481 MSA V29117
Surrogate: Toluene-d8 93.4 Limits: 70-130%01/23/23 13:481 MSA V29117
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 80 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TB
97312 Matrix:
1/10/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
3.26 J µg/L 1.80 10.0Acetone 1 01/23/23 13:48 V29117MSA
<0.180 µg/L 0.180 0.500
Benzene 1 01/23/23 13:48 V29117MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 01/23/23 13:48 V29117MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 01/23/23 13:48 V29117MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 01/23/23 13:48 V29117MSA
<1.50 µg/L 1.50 5.00
Bromoform 1 01/23/23 13:48 V29117MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 01/23/23 13:48 V29117MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 01/23/23 13:48 V29117MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 01/23/23 13:48 V29117MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 01/23/23 13:48 V29117MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 01/23/23 13:48 V29117MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 01/23/23 13:48 V29117MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 01/23/23 13:48 V29117MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 01/23/23 13:48 V29117MSA
<0.220 µg/L 0.220 0.500Chloroform 1 01/23/23 13:48 V29117MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 01/23/23 13:48 V29117MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 01/23/23 13:48 V29117MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 01/23/23 13:48 V29117MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 01/23/23 13:48 V29117MSA
<1.10 µg/L 1.10 2.00
1,2-Dibromo-3-Chloropropane 1 01/23/23 13:48 V29117MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 01/23/23 13:48 V29117MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 01/23/23 13:48 V29117MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 81 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TB
97312 Matrix:
1/10/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 01/23/23 13:48 V29117MSA
<0.190 µg/L 0.190 0.500
1,3-Dichlorobenzene 1 01/23/23 13:48 V29117MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 01/23/23 13:48 V29117MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 01/23/23 13:48 V29117MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 01/23/23 13:48 V29117MSA
<0.150 µg/L 0.150 0.500
1,2-Dichloroethane 1 01/23/23 13:48 V29117MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 01/23/23 13:48 V29117MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 01/23/23 13:48 V29117MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 01/23/23 13:48 V29117MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 01/23/23 13:48 V29117MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 01/23/23 13:48 V29117MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 01/23/23 13:48 V29117MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 01/23/23 13:48 V29117MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 01/23/23 13:48 V29117MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 01/23/23 13:48 V29117MSA
<42.0 µg/L 42.0 200Ethanol 1 01/23/23 13:48 V29117MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 01/23/23 13:48 V29117MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 01/23/23 13:48 V29117MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 01/23/23 13:48 V29117MSA
<0.180 µg/L 0.180 0.500
Isopropylbenzene 1 01/23/23 13:48 V29117MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 01/23/23 13:48 V29117MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 01/23/23 13:48 V29117MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 82 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TB
97312 Matrix:
1/10/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 01/23/23 13:48 V29117MSA
<0.078 µg/L 0.078 1.00
4-Methyl-2-Pentanone 1 01/23/23 13:48 V29117MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 01/23/23 13:48 V29117MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 01/23/23 13:48 V29117MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 01/23/23 13:48 V29117MSA
<0.220 µg/L 0.220 0.500
Styrene 1 01/23/23 13:48 V29117MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 01/23/23 13:48 V29117MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 01/23/23 13:48 V29117MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 01/23/23 13:48 V29117MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 01/23/23 13:48 V29117MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 01/23/23 13:48 V29117MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 01/23/23 13:48 V29117MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 01/23/23 13:48 V29117MSA
<0.220 µg/L 0.220 0.500Toluene 1 01/23/23 13:48 V29117MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 01/23/23 13:48 V29117MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 01/23/23 13:48 V29117MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 01/23/23 13:48 V29117MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 01/23/23 13:48 V29117MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 01/23/23 13:48 V29117MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 01/23/23 13:48 V29117MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 01/23/23 13:48 V29117MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 01/23/23 13:48 V29117MSA
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 83 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TB
97312 Matrix:
1/10/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29115 01/23/23 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 01/23/23 13:48 V29117MSA
<1.00 µg/L 1.00 5.00
Vinyl Acetate 1 01/23/23 13:48 V29117MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 01/23/23 13:48 V29117MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 01/23/23 13:48 V29117MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 01/23/23 13:48 V29117MSA
<0.21 µg/L 0.210 0.500
Xylene (Total)1 01/23/23 13:48 V29117
Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%01/23/23 13:481 MSA V29117
Surrogate: Dibromofluoromethane 99.8 Limits: 70-130%01/23/23 13:481 MSA V29117
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%01/23/23 13:481 MSA V29117
Surrogate: Toluene-d8 93.4 Limits: 70-130%01/23/23 13:481 MSA V29117
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 84 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:TW-1-53'
97313 Matrix:
1/6/2023 10:12
Solids
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
10.0 %0.1%Clay 1 01/20/23 10:54 TextureEB
89.0 %0.1%Sand 1 01/20/23 10:54 TextureEB
1.0 %0.1%Silt 1 01/20/23 10:54 TextureEB
Loamy SandSoil Classification 1 01/20/23 10:54 TextureEB
0.07 %0.05Total Organic Carbon 1 01/20/23 09:46 WALK-BLACKAAB
100.0 %0.1% Passing 4 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
98.7 %0.1% Passing 10 Mesh 1 01/23/23 11:00 SIEVEVVP
87.6 %0.1% Passing 20 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
68.3 %0.1% Passing 40 Mesh 1 01/23/23 11:00 SIEVEVVP
51.3 %0.1% Passing 60 Mesh 1 01/23/23 11:00 SIEVEVVP
33.3 %0.1% Passing 100 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
25.7 %0.1% Passing 200 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 85 of 164
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-011-0104
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI # 5991 Received : 01/11/2023
Breedens 66
Report Date : 01/27/2023
Sample ID :
Lab No :
Sampled:MW-8-20'
97314 Matrix:
1/5/2023 10:47
Solids
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
24.0 %0.1%Clay 1 01/20/23 10:54 TextureEB
73.0 %0.1%Sand 1 01/20/23 10:54 TextureEB
3.0 %0.1%Silt 1 01/20/23 10:54 TextureEB
Sandy Clay LoamSoil Classification 1 01/20/23 10:54 TextureEB
0.21 %0.05Total Organic Carbon 1 01/20/23 09:46 WALK-BLACKAAB
85.9 %0.1% Passing 4 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
85.3 %0.1% Passing 10 Mesh 1 01/23/23 11:00 SIEVEVVP
75.3 %0.1% Passing 20 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
60.7 %0.1% Passing 40 Mesh 1 01/23/23 11:00 SIEVEVVP
51.4 %0.1% Passing 60 Mesh 1 01/23/23 11:00 SIEVEVVP
42.6 %0.1% Passing 100 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
39.1 %0.1% Passing 200 Mesh 1 01/23/23 11:00 SIEVE TESTVVP
Qualifiers/Definitions Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
RPD >40% dual column resultsQ
Page 86 of 164
SampleID Report LabNo
LRB 23‐011‐0104 LRB‐V28943
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
HexadecanoicAcid 11.5 ug/L 1 625.1 1/18/202316:31 JMV V29002
SampleID Report LabNo
MW‐5 23‐011‐0104 V97307
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Toluene25.7 ug/L 1 625.1 1/18/202320:43 JMV V29002
Xylene 78.5 ug/L 1 625.1 1/18/202320:43 JMV V29002
EthylMethylBenzene 17.1 ug/L 1 625.1 1/18/202320:43 JMV V29002
TrimethylBenzene 60.6 ug/L 1 625.1 1/18/202320:43 JMV V29002
ProenylBenzene 10.6 ug/L 1 625.1 1/18/202320:43 JMV V29002
SampleID Report LabNo
MW‐6 23‐011‐0104 V97308
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Toluene 48.5 ug/L 1 625.1 1/18/202321:28 JMV V29002
DimethylBenzene 48.1 ug/L 1 625.1 1/18/202321:28 JMV V29002
TrimethylBenzene 26.4 ug/L 1 625.1 1/18/202321:28 JMV V29002
Page 87 of 164
SampleID Report LabNo
MW‐7 23‐011‐0104 V97309
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
MethylPentanol 27.1 ug/L 1 625.1 1/18/202321:05 JMV V29002
Toluene 370 ug/L 1 625.1 1/18/202321:05 JMV V29002
MethylCyclopentanol 33.6 ug/L 1 625.1 1/18/202321:05 JMV V29002
DimethylCyclopentanol 24.8 ug/L 1 625.1 1/18/202321:05 JMV V29002
DimethylBenzene 265 ug/L 1 625.1 1/18/202321:05 JMV V29002
EthylMethylBenzene 47.2 ug/L 1 625.1 1/18/202321:05 JMV V29002
TrimethylBenzene 175 ug/L 1 625.1 1/18/202321:05 JMV V29002
DimethylphenylEthanone 24.8 ug/L 1 625.1 1/18/202321:05 JMV V29002
SampleID Report LabNo
MW‐8 23‐011‐0104 V97310
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
NOTICSREPORTED 0 ug/L 1 625.1 1/18/202319:35 JMV V29002
SampleID Report LabNo
TW‐1 23‐011‐0104 V97311
Paramater Result Units
Dilution
Factor Method AnalysisDate/Time Analyst BatchID
Cyclohexanamine 27.7 ug/L 1 625.1 1/18/202319:58 JMV V29002
TetradecanoicAcid 11.3 ug/L 1 625.1 1/18/202319:58 JMV V29002
Page 88 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-16.D
Acq On : 18 Jan 2023 16:31
Operator : JVOGEL
Sample : LRB-V28943
Misc :
ALS Vial : 15 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 2 n-Hexadecanoic acid Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
7.974 11.53 pp 316501 Phenanthrene-d10 7.510
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 99
2 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 96
3 n-Hexadecanoic acid $$ Hexadecan... 256 C16H32O2 000057-10-3 95
4 Tridecanoic acid 214 C13H26O2 000638-53-9 90
5 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 89
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance Scan 1053 (7.974 min): F011823-16.D\data.ms (-1050) (-)73.0
43.1
129.1
97.1 213.2 256.1171.1
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123965: n-Hexadecanoic acid
43.0 73.0
256.0
129.0
213.097.0 157.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123964: n-Hexadecanoic acid43.0 73.0
129.097.0 213.0 256.0171.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance#57109: n-Hexadecanoic acid $$ Hexadecanoic acid $$ n-Hexadecoic ac
43.0 73.0
129.0 256.097.0 213.0157.0 185.0
7.60 7.80 8.00 8.20 8.40
m/z 73.00 100.00%
7.60 7.80 8.00 8.20 8.40
m/z 60.00 84.00%
7.60 7.80 8.00 8.20 8.40
m/z 43.10 80.16%
7.60 7.80 8.00 8.20 8.40
m/z 41.05 66.04%
7.60 7.80 8.00 8.20 8.40
m/z 57.10 59.72%
F011823_FL.M Sun Jan 22 09:13:45 2023 Page: 6Page 89 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-27.D
Acq On : 18 Jan 2023 20:43
Operator : JVOGEL
Sample : V 97307-V28943
Misc :
ALS Vial : 26 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 1 Toluene Concentration Rank 5
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.116 25.67 pp 432754 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Toluene 92 C7H8 000108-88-3 91
2 Toluene 92 C7H8 000108-88-3 91
3 Toluene 92 C7H8 000108-88-3 91
4 1,3,5-Cycloheptatriene $$ Cycloh... 92 C7H8 000544-25-2 90
5 Toluene $$ Benzene, methyl $$ Me... 92 C7H8 000108-88-3 87
0 20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance Scan 56 (2.116 min): F011823-27.D\data.ms (-49) (-)91.1
65.039.0 206.9
0 20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109011: Toluene
91.0
39.0 65.0
1.0
0 20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109014: Toluene91.0
65.039.0
0 20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109012: Toluene
91.0
39.0 65.0
2.00 2.20 2.40
m/z 91.10 100.00%
2.00 2.20 2.40
m/z 92.10 59.68%
2.00 2.20 2.40
m/z 65.00 10.26%
2.00 2.20 2.40
m/z 39.00 8.66%
2.00 2.20 2.40
m/z 63.00 7.39%
F011823_FL.M Sun Jan 22 09:16:05 2023 Page: 5Page 90 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-27.D
Acq On : 18 Jan 2023 20:43
Operator : JVOGEL
Sample : V 97307-V28943
Misc :
ALS Vial : 26 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 2 p-Xylene Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.804 78.49 pp 1322970 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 p-Xylene 106 C8H10 000106-42-3 97
2 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
3 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
4 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
5 p-Xylene 106 C8H10 000106-42-3 97
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance Scan 173 (2.804 min): F011823-27.D\data.ms (-168) (-)91.1
106.1
77.151.039.0 65.0
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance #110022: p-Xylene
91.0
106.0
77.051.039.0 65.027.015.0
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance #110009: Benzene, 1,3-dimethyl-91.0
106.0
77.051.039.0 65.027.0
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance #110012: Benzene, 1,3-dimethyl-
91.0
106.0
39.0 77.051.0 65.027.0
2.40 2.60 2.80 3.00 3.20
m/z 91.10 100.00%
2.40 2.60 2.80 3.00 3.20
m/z 106.10 47.76%
2.40 2.60 2.80 3.00 3.20
m/z 105.10 20.68%
2.40 2.60 2.80 3.00 3.20
m/z 77.10 12.26%
2.40 2.60 2.80 3.00 3.20
m/z 51.00 9.61%
F011823_FL.M Sun Jan 22 09:16:06 2023 Page: 6Page 91 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-27.D
Acq On : 18 Jan 2023 20:43
Operator : JVOGEL
Sample : V 97307-V28943
Misc :
ALS Vial : 26 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 3 Benzene, 1-ethyl-2-methyl- Concentration Rank 7
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.338 17.06 pp 287561 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 94
2 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 94
3 Benzene, 1-ethyl-2-methyl- $$ To... 120 C9H12 000611-14-3 91
4 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 91
5 Benzene, 1,3,5-trimethyl- 120 C9H12 000108-67-8 90
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 264 (3.338 min): F011823-27.D\data.ms (-260) (-)105.1
120.1
91.177.039.0 51.0 63.0
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111386: Benzene, 1-ethyl-2-methyl-
105.0
120.0
77.0 91.044.0 65.0
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111384: Benzene, 1-ethyl-2-methyl-105.0
120.0
77.0 91.039.0 51.0 65.027.0
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance#4792: Benzene, 1-ethyl-2-methyl- $$ Toluene, o-ethyl- $$ o-Ethylmethyl
105.0
120.0
39.0 91.077.027.0 51.0 65.0
3.00 3.20 3.40 3.60
m/z 105.10 100.00%
3.00 3.20 3.40 3.60
m/z 120.10 31.33%
3.00 3.20 3.40 3.60
m/z 91.10 11.69%
3.00 3.20 3.40 3.60
m/z 77.00 11.66%
3.00 3.20 3.40 3.60
m/z 106.10 9.34%
F011823_FL.M Sun Jan 22 09:16:07 2023 Page: 7Page 92 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-27.D
Acq On : 18 Jan 2023 20:43
Operator : JVOGEL
Sample : V 97307-V28943
Misc :
ALS Vial : 26 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 4 Benzene, 1,2,3-trimethyl- Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.444 60.60 pp 1021450 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 95
2 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 94
3 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 94
4 Benzene, 1,3,5-trimethyl- 120 C9H12 000108-67-8 94
5 Benzene, 1,2,3-trimethyl- $$ Hem... 120 C9H12 000526-73-8 94
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 282 (3.444 min): F011823-27.D\data.ms (-277) (-)105.1
120.1
77.1 91.139.0 51.0 65.1
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111401: Benzene, 1,2,3-trimethyl-
105.0
120.0
77.0 91.039.0 51.027.0 65.015.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111405: Benzene, 1,2,4-trimethyl-105.0
120.0
77.0 91.051.039.0 65.027.015.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111403: Benzene, 1,2,4-trimethyl-
105.0
120.0
77.0 91.051.027.0 65.040.0
3.20 3.40 3.60 3.80
m/z 105.10 100.00%
3.20 3.40 3.60 3.80
m/z 120.10 47.53%
3.20 3.40 3.60 3.80
m/z 119.10 12.43%
3.20 3.40 3.60 3.80
m/z 77.10 11.79%
3.20 3.40 3.60 3.80
m/z 91.10 10.73%
F011823_FL.M Sun Jan 22 09:16:08 2023 Page: 8Page 93 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-27.D
Acq On : 18 Jan 2023 20:43
Operator : JVOGEL
Sample : V 97307-V28943
Misc :
ALS Vial : 26 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 5 Benzene, 2-propenyl- Concentration Rank 8
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.726 10.64 pp 179428 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 2-propenyl- 118 C9H10 000300-57-2 86
2 Indane 118 C9H10 000496-11-7 83
3 Indane 118 C9H10 000496-11-7 83
4 Tetracyclo[3.3.1.0(2,8).0(4,6)]-... 118 C9H10 000000-00-0 80
5 Benzene, 2-propenyl- 118 C9H10 000300-57-2 72
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 330 (3.726 min): F011823-27.D\data.ms (-326) (-)117.1
91.063.039.0 51.0 103.077.1
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111246: Benzene, 2-propenyl-
117.0
91.028.0 39.0 51.0 65.0 77.0 106.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111258: Indane 117.0
91.058.039.0 103.077.027.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111257: Indane
117.0
91.063.039.0 51.0 103.077.027.015.0
3.40 3.60 3.80 4.00
m/z 117.05 100.00%
3.40 3.60 3.80 4.00
m/z 118.10 58.18%
3.40 3.60 3.80 4.00
m/z 115.10 32.45%
3.40 3.60 3.80 4.00
m/z 91.00 15.35%
3.40 3.60 3.80 4.00
m/z 116.10 7.32%
F011823_FL.M Sun Jan 22 09:16:08 2023 Page: 9Page 94 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-29.D
Acq On : 18 Jan 2023 21:28
Operator : JVOGEL
Sample : V 97308-V28943
Misc :
ALS Vial : 28 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 1 Toluene Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.111 48.54 pp 822211 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Toluene 92 C7H8 000108-88-3 94
2 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 91
3 Toluene 92 C7H8 000108-88-3 91
4 Toluene 92 C7H8 000108-88-3 91
5 Toluene $$ Benzene, methyl $$ Me... 92 C7H8 000108-88-3 91
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance Scan 55 (2.111 min): F011823-29.D\data.ms (-50) (-)91.1
65.039.1 207.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109014: Toluene
91.0
65.039.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109024: 1,3,5-Cycloheptatriene91.0
39.0 65.0
15.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109012: Toluene
91.0
39.0 65.0
2.00 2.20 2.40
m/z 91.10 100.00%
2.00 2.20 2.40
m/z 92.10 57.89%
2.00 2.20 2.40
m/z 65.00 10.80%
2.00 2.20 2.40
m/z 39.10 8.95%
2.00 2.20 2.40
m/z 63.00 6.99%
F011823_FL.M Sun Jan 22 09:17:41 2023 Page: 5Page 95 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-29.D
Acq On : 18 Jan 2023 21:28
Operator : JVOGEL
Sample : V 97308-V28943
Misc :
ALS Vial : 28 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 2 Benzene, 1,3-dimethyl- Concentration Rank 3
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.804 48.10 pp 814782 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
2 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
3 p-Xylene 106 C8H10 000106-42-3 97
4 p-Xylene 106 C8H10 000106-42-3 95
5 Benzene, 1,2-dimethyl- $$ o-Dime... 106 C8H10 000095-47-6 95
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance Scan 173 (2.804 min): F011823-29.D\data.ms (-168) (-)91.0
51.0 74.0 111.9 207.1
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #110010: Benzene, 1,3-dimethyl-
91.0
51.027.0 74.0 108.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #110009: Benzene, 1,3-dimethyl-91.0
51.027.0 74.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #110021: p-Xylene
91.0
51.027.0 74.0
2.40 2.60 2.80 3.00 3.20
m/z 91.05 100.00%
2.40 2.60 2.80 3.00 3.20
m/z 106.10 51.09%
2.40 2.60 2.80 3.00 3.20
m/z 105.10 20.21%
2.40 2.60 2.80 3.00 3.20
m/z 77.00 12.71%
2.40 2.60 2.80 3.00 3.20
m/z 51.05 9.25%
F011823_FL.M Sun Jan 22 09:17:41 2023 Page: 6Page 96 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-29.D
Acq On : 18 Jan 2023 21:28
Operator : JVOGEL
Sample : V 97308-V28943
Misc :
ALS Vial : 28 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 3 Benzene, 1,2,3-trimethyl- Concentration Rank 6
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.438 26.45 pp 448051 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 97
2 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 95
3 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 95
4 Benzene, 1,3,5-trimethyl- $$ Mes... 120 C9H12 000108-67-8 94
5 Benzene, 1,3,5-trimethyl- 120 C9H12 000108-67-8 94
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 281 (3.438 min): F011823-29.D\data.ms (-277) (-)105.1
120.1
77.0 91.151.139.0 65.1
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111401: Benzene, 1,2,3-trimethyl-
105.0
120.0
77.0 91.039.0 51.027.0 65.015.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111403: Benzene, 1,2,4-trimethyl-105.0
120.0
77.0 91.051.027.0 65.040.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111405: Benzene, 1,2,4-trimethyl-
105.0
120.0
77.0 91.051.039.0 65.027.015.0
3.20 3.40 3.60 3.80
m/z 105.10 100.00%
3.20 3.40 3.60 3.80
m/z 120.10 47.83%
3.20 3.40 3.60 3.80
m/z 119.10 13.36%
3.20 3.40 3.60 3.80
m/z 77.00 11.46%
3.20 3.40 3.60 3.80
m/z 91.10 9.64%
F011823_FL.M Sun Jan 22 09:17:42 2023 Page: 7Page 97 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 1 2-Pentanol, 2-methyl- Concentration Rank 7
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
1.946 27.11 pp 501800 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 2-Pentanol, 2-methyl- 102 C6H14O 000590-36-3 83
2 2-Pentanol, 2-methyl- 102 C6H14O 000590-36-3 78
3 2-Pentanol, 2-methyl- 102 C6H14O 000590-36-3 74
4 2-Butanol, 2,3-dimethyl- 102 C6H14O 000594-60-5 72
5 2-Butanol, 2,3-dimethyl- 102 C6H14O 000594-60-5 72
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance Scan 27 (1.946 min): F011823-28.D\data.ms (-19) (-)59.0
87.143.0
207.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109760: 2-Pentanol, 2-methyl-
59.0
87.0
43.0
27.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109759: 2-Pentanol, 2-methyl-59.0
87.041.0
20 40 60 80 100 120 140 160 180 200
0
5000
m/z-->
Abundance #109761: 2-Pentanol, 2-methyl-
59.0
43.0 87.027.0
105.0
1.90 2.002.10 2.202.302.40
m/z 59.05 100.00%
1.90 2.002.10 2.202.302.40
m/z 87.10 30.21%
1.90 2.002.10 2.202.302.40
m/z 45.00 27.80%
1.90 2.002.10 2.202.302.40
m/z 43.00 23.95%
1.90 2.002.10 2.202.302.40
m/z 41.05 19.20%
F011823_FL.M Sun Jan 22 09:16:51 2023 Page: 5Page 98 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 3 Toluene Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.116 371.05 pp 6869170 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Toluene 92 C7H8 000108-88-3 94
2 Toluene 92 C7H8 000108-88-3 91
3 Toluene 92 C7H8 000108-88-3 91
4 Toluene 92 C7H8 000108-88-3 91
5 Toluene $$ Benzene, methyl $$ Me... 92 C7H8 000108-88-3 91
20 30 40 50 60 70 80 90 100
0
5000
m/z-->
Abundance Scan 56 (2.116 min): F011823-28.D\data.ms (-49) (-)91.0
65.039.0 51.0 77.0
20 30 40 50 60 70 80 90 100
0
5000
m/z-->
Abundance #109014: Toluene
91.0
65.039.0 51.027.0 77.0
20 30 40 50 60 70 80 90 100
0
5000
m/z-->
Abundance #109013: Toluene 91.0
39.0 65.051.027.0 77.0
20 30 40 50 60 70 80 90 100
0
5000
m/z-->
Abundance #109012: Toluene
91.0
39.0 65.051.027.0 77.0
2.00 2.20 2.40
m/z 91.05 100.00%
2.00 2.20 2.40
m/z 92.05 62.73%
2.00 2.20 2.40
m/z 64.95 11.27%
2.00 2.20 2.40
m/z 39.05 9.94%
2.00 2.20 2.40
m/z 63.00 8.51%
F011823_FL.M Sun Jan 22 09:16:53 2023 Page: 7Page 99 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 4 Cyclopentanol, 1-methyl- $$... Concentration Rank 6
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.222 33.63 pp 622559 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Cyclopentanol, 1-methyl- $$ 1-Hy... 100 C6H12O 001462-03-9 91
2 Cyclopentanol, 1-methyl- 100 C6H12O 001462-03-9 86
3 Cyclopentanol, 1-methyl- 100 C6H12O 001462-03-9 64
4 1-Methoxycyclohexane 114 C7H14O 000931-56-6 45
5 3-Hexanone, 2-methyl- 114 C7H14O 007379-12-6 43
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 74 (2.222 min): F011823-28.D\data.ms (-68) (-)71.0
43.0
58.0
85.0
100.0 114.1
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance#1825: Cyclopentanol, 1-methyl- $$ 1-Hydroxy-1-methylcyclopentane $$
71.0
43.0
58.0
85.027.0
15.0 100.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #109499: Cyclopentanol, 1-methyl-71.0
43.0
58.0
85.028.0
15.0 100.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #109498: Cyclopentanol, 1-methyl-
71.0
43.0
58.0
85.0
100.0
2.00 2.20 2.40 2.60
m/z 71.05 100.00%
2.00 2.20 2.40 2.60
m/z 43.05 56.74%
2.00 2.20 2.40 2.60
m/z 58.00 45.72%
2.00 2.20 2.40 2.60
m/z 57.10 20.00%
2.00 2.20 2.40 2.60
m/z 41.05 14.99%
F011823_FL.M Sun Jan 22 09:16:54 2023 Page: 8Page 100 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 5 1,3-Dimethyl cyclopentanol Concentration Rank 8
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.492 24.84 pp 459864 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 1,3-Dimethyl cyclopentanol 114 C7H14O 019550-46-0 80
2 2-Hexanone, 4-methyl- 114 C7H14O 000105-42-0 38
3 Thiazole 85 C3H3NS 000288-47-1 38
4 Cyclopentanol, 1-methyl- 100 C6H12O 001462-03-9 35
5 3-Methyl-1-hexen-3-ol $$ 1-Hexen... 114 C7H14O 055145-28-3 27
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 120 (2.492 min): F011823-28.D\data.ms (-112) (-)43.0 71.1
58.0 85.1
99.0
114.1
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #3861: 1,3-Dimethyl cyclopentanol
43.0 71.0
85.058.0
27.0
99.015.0 114.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #110835: 2-Hexanone, 4-methyl-43.0
58.0
85.027.0 71.0 114.015.0 99.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #108656: Thiazole
85.058.0
28.0
45.0
70.0
2.20 2.40 2.60 2.80
m/z 43.00 100.00%
2.20 2.40 2.60 2.80
m/z 71.10 97.91%
2.20 2.40 2.60 2.80
m/z 58.00 73.72%
2.20 2.40 2.60 2.80
m/z 85.10 71.23%
2.20 2.40 2.60 2.80
m/z 41.10 22.87%
F011823_FL.M Sun Jan 22 09:16:55 2023 Page: 9Page 101 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 6 Benzene, 1,3-dimethyl- Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
2.810 264.76 pp 4901470 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
2 p-Xylene 106 C8H10 000106-42-3 97
3 p-Xylene 106 C8H10 000106-42-3 97
4 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
5 Benzene, 1,3-dimethyl- 106 C8H10 000108-38-3 97
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance Scan 174 (2.810 min): F011823-28.D\data.ms (-168) (-)91.1
106.1
77.051.039.1 65.1
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance #110010: Benzene, 1,3-dimethyl-
91.0
106.0
77.051.039.0 65.027.015.0
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance #110021: p-Xylene 91.0
106.0
77.051.039.0 65.027.0
10 20 30 40 50 60 70 80 90 100 110
0
5000
m/z-->
Abundance #110025: p-Xylene
91.0
106.0
77.051.039.0 65.027.0
2.40 2.60 2.80 3.00 3.20
m/z 91.10 100.00%
2.40 2.60 2.80 3.00 3.20
m/z 106.05 50.24%
2.40 2.60 2.80 3.00 3.20
m/z 105.10 21.15%
2.40 2.60 2.80 3.00 3.20
m/z 77.05 12.63%
2.40 2.60 2.80 3.00 3.20
m/z 51.00 10.11%
F011823_FL.M Sun Jan 22 09:16:56 2023 Page: 10Page 102 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 7 Benzene, 1-ethyl-2-methyl- ... Concentration Rank 4
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.344 47.18 pp 873410 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1-ethyl-2-methyl- $$ To... 120 C9H12 000611-14-3 93
2 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 93
3 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 93
4 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 93
5 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 90
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 265 (3.344 min): F011823-28.D\data.ms (-259) (-)105.1
120.1
91.077.139.0 51.0 65.1
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance#4792: Benzene, 1-ethyl-2-methyl- $$ Toluene, o-ethyl- $$ o-Ethylmethyl
105.0
120.0
39.0 91.077.027.0 51.0 65.0
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111385: Benzene, 1-ethyl-2-methyl-105.0
120.0
91.077.039.0 51.0 65.027.0
20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111386: Benzene, 1-ethyl-2-methyl-
105.0
120.0
77.0 91.044.0 65.0
3.00 3.20 3.40 3.60
m/z 105.05 100.00%
3.00 3.20 3.40 3.60
m/z 120.05 31.97%
3.00 3.20 3.40 3.60
m/z 91.05 12.02%
3.00 3.20 3.40 3.60
m/z 77.10 11.81%
3.00 3.20 3.40 3.60
m/z 106.10 8.90%
F011823_FL.M Sun Jan 22 09:16:56 2023 Page: 11Page 103 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 8 Benzene, 1,2,3-trimethyl- Concentration Rank 3
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.444 174.79 pp 3235880 1,4-Dichlorobenzene-d4 3.585
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 95
2 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 94
3 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 94
4 Benzene, 1,2,3-trimethyl- $$ Hem... 120 C9H12 000526-73-8 94
5 Benzene, 1,3,5-trimethyl- 120 C9H12 000108-67-8 94
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance Scan 282 (3.444 min): F011823-28.D\data.ms (-277) (-)105.1
120.1
77.1 91.039.0 51.0 65.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111401: Benzene, 1,2,3-trimethyl-
105.0
120.0
77.0 91.039.0 51.027.0 65.015.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111403: Benzene, 1,2,4-trimethyl-105.0
120.0
77.0 91.051.027.0 65.040.0
10 20 30 40 50 60 70 80 90 100 110 120
0
5000
m/z-->
Abundance #111405: Benzene, 1,2,4-trimethyl-
105.0
120.0
77.0 91.051.039.0 65.027.015.0
3.20 3.40 3.60 3.80
m/z 105.10 100.00%
3.20 3.40 3.60 3.80
m/z 120.10 49.52%
3.20 3.40 3.60 3.80
m/z 119.10 13.73%
3.20 3.40 3.60 3.80
m/z 77.10 12.35%
3.20 3.40 3.60 3.80
m/z 91.05 10.50%
F011823_FL.M Sun Jan 22 09:16:57 2023 Page: 12Page 104 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-28.D
Acq On : 18 Jan 2023 21:05
Operator : JVOGEL
Sample : V 97309-V28943
Misc :
ALS Vial : 27 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 9 Ethanone, 1-(2,4-dimethylph... Concentration Rank 9
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
5.095 24.78 pp 630947 Naphthalene-d8 4.649
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Ethanone, 1-(2,4-dimethylphenyl)- 148 C10H12O 000089-74-7 97
2 Ethanone, 1-(2,5-dimethylphenyl)- 148 C10H12O 002142-73-6 95
3 Ethanone, 1-(2,4-dimethylphenyl)- 148 C10H12O 000089-74-7 95
4 Ethanone, 1-(3,4-dimethylphenyl)... 148 C10H12O 003637-01-2 94
5 1-(2,3-Dimethylphenyl)ethanone 148 C10H12O 002142-71-4 94
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance Scan 563 (5.095 min): F011823-28.D\data.ms (-559) (-)133.1
105.1
148.1
77.0
43.0 63.0 91.1 118.1
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance #114677: Ethanone, 1-(2,4-dimethylphenyl)-
133.0
105.0 148.0
77.043.0 63.0 91.027.0 119.0
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance #114647: Ethanone, 1-(2,5-dimethylphenyl)-133.0
105.0
77.0 148.0
43.0
63.0 91.0 119.0
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160
0
5000
m/z-->
Abundance #114678: Ethanone, 1-(2,4-dimethylphenyl)-
133.0
105.0
148.0
77.043.0 63.027.0 91.0 119.0
4.80 5.00 5.20 5.40
m/z 133.05 100.00%
4.80 5.00 5.20 5.40
m/z 105.10 63.13%
4.80 5.00 5.20 5.40
m/z 148.05 43.01%
4.80 5.00 5.20 5.40
m/z 77.05 19.59%
4.80 5.00 5.20 5.40
m/z 103.10 15.03%
F011823_FL.M Sun Jan 22 09:16:58 2023 Page: 13Page 105 of 164
Tentatively Identified Compound (LSC) summary
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-24.D
Acq On : 18 Jan 2023 19:35
Operator : JVOGEL
Sample : V 97310-V28943
Misc :
ALS Vial : 23 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
|--Internal Standard---|
TIC Top Hit name RT EstConc Units Response |# RT Resp Conc|
----------------------------------------------------------------------------
F011823_FL.M Sun Jan 22 09:14:41 2023 Page: 15Page 106 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-25.D
Acq On : 18 Jan 2023 19:58
Operator : JVOGEL
Sample : V 97311-V28943
Misc :
ALS Vial : 24 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 2 Cyclohexanamine, N-cyclohexyl- Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
5.912 27.71 pp 758245 Acenaphthene-d10 6.188
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Cyclohexanamine, N-cyclohexyl- 181 C12H23N 000101-83-7 96
2 Cyclohexanamine, N-cyclohexyl- 181 C12H23N 000101-83-7 93
3 Cyclohexanamine, N-cyclohexyl- $... 181 C12H23N 000101-83-7 93
4 Cyclohexanamine, N-cyclohexyl- 181 C12H23N 000101-83-7 91
5 Dimecamine $$ Bicyclo[2.2.1]hept... 181 C12H23N 003570-07-8 80
0 20 40 60 80 100 120 140 160 180
0
5000
m/z-->
Abundance Scan 702 (5.912 min): F011823-25.D\data.ms (-689) (-)138.1
56.1
181.282.0 100.139.0 122.2
0 20 40 60 80 100 120 140 160 180
0
5000
m/z-->
Abundance #118717: Cyclohexanamine, N-cyclohexyl-
138.0
56.0
181.0
82.0 100.030.0
0 20 40 60 80 100 120 140 160 180
0
5000
m/z-->
Abundance #118718: Cyclohexanamine, N-cyclohexyl-138.0
56.0
181.082.0 100.030.0 122.0
0 20 40 60 80 100 120 140 160 180
0
5000
m/z-->
Abundance#26503: Cyclohexanamine, N-cyclohexyl- $$ Dicyclohexylamine $$ Dode
138.0
56.0
181.082.028.0 100.0 122.04.0
5.60 5.80 6.00 6.20
m/z 138.05 100.00%
5.60 5.80 6.00 6.20
m/z 56.10 27.44%
5.60 5.80 6.00 6.20
m/z 181.20 12.66%
5.60 5.80 6.00 6.20
m/z 55.10 12.32%
5.60 5.80 6.00 6.20
m/z 41.00 11.58%
F011823_FL.M Sun Jan 22 09:15:19 2023 Page: 6Page 107 of 164
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\F011823\
Data File : F011823-25.D
Acq On : 18 Jan 2023 19:58
Operator : JVOGEL
Sample : V 97311-V28943
Misc :
ALS Vial : 24 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F011823_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 5 Tetradecanoic acid Concentration Rank 4
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
7.980 11.34 pp 328274 Phenanthrene-d10 7.504
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Tetradecanoic acid 228 C14H28O2 000544-63-8 97
2 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 96
3 n-Hexadecanoic acid 256 C16H32O2 000057-10-3 94
4 Tetradecanoic acid 228 C14H28O2 000544-63-8 68
5 Tridecanoic acid 214 C13H26O2 000638-53-9 64
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance Scan 1054 (7.980 min): F011823-25.D\data.ms (-1050) (-)73.0
43.0
129.1
256.197.1 213.2
171.1
151.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #122570: Tetradecanoic acid
73.0
43.0
129.0
185.097.0 228.0157.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123965: n-Hexadecanoic acid43.0 73.0
256.0
129.0
213.097.0 157.0 185.0
20 40 60 80 100 120 140 160 180 200 220 240 260
0
5000
m/z-->
Abundance #123964: n-Hexadecanoic acid
43.0 73.0
129.097.0 213.0 256.0171.0
7.60 7.80 8.00 8.20 8.40
m/z 73.00 100.00%
7.60 7.80 8.00 8.20 8.40
m/z 43.05 77.99%
7.60 7.80 8.00 8.20 8.40
m/z 59.95 75.71%
7.60 7.80 8.00 8.20 8.40
m/z 41.10 63.09%
7.60 7.80 8.00 8.20 8.40
m/z 55.10 61.17%
F011823_FL.M Sun Jan 22 09:15:22 2023 Page: 9Page 108 of 164
ANALYTICAL REPORT
PREPARED FOR
Attn: PM Group NC
Waypoint Analytical, Inc.
449 Springbrook Road
Charlotte, North Carolina 28217
Generated 1/20/2023 2:09:39 PM
JOB DESCRIPTION
23-011-0104
JOB NUMBER
680-229202-1
See page two for job notes and contact information.
Savannah GA 31404
5102 LaRoche Avenue
Eurofins Savannah
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Eurofins Savannah
Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report may not be
reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the person who
signed this report.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
1/20/2023 2:09:39 PM
Authorized for release by
John Andros, Project Manager I
[e-mail]
[phone]
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Definitions/Glossary
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Savannah
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Sample Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229202-1
Project/Site: 23-011-0104
Lab Sample ID Client Sample ID Matrix Collected Received
680-229202-1 MW-5 / 97307 Water 01/10/23 14:10 01/17/23 12:02
680-229202-2 MW-6 / 97308 Water 01/10/23 14:25 01/17/23 12:02
680-229202-3 MW-7 / 97309 Water 01/10/23 14:18 01/17/23 12:02
680-229202-4 MW-8 / 97310 Water 01/10/23 13:45 01/17/23 12:02
680-229202-5 TW-1 / 97311 Water 01/10/23 14:00 01/17/23 12:02
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Case Narrative
Client: Waypoint Analytical, Inc.Job ID: 680-229202-1
Project/Site: 23-011-0104
Job ID: 680-229202-1
Laboratory: Eurofins Savannah
Narrative
Job Narrative
680-229202-1
Receipt
The samples were received on 1/17/2023 12:02 PM. Unless otherwise noted below, the samples arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 16.3°C
Metals
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
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Client Sample Results
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Lab Sample ID: 680-229202-1Client Sample ID: MW-5 / 97307
Matrix: WaterDate Collected: 01/10/23 14:10
Date Received: 01/17/23 12:02
Method: 40CFR136A 200.7 Rev 4.4 - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 ug/L 01/18/23 06:15 01/19/23 13:27 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Lab Sample ID: 680-229202-2Client Sample ID: MW-6 / 97308
Matrix: WaterDate Collected: 01/10/23 14:25
Date Received: 01/17/23 12:02
Method: 40CFR136A 200.7 Rev 4.4 - Metals (ICP) - Total Recoverable
RL MDL
18.9 10.0 ug/L 01/18/23 06:15 01/19/23 13:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Lab Sample ID: 680-229202-3Client Sample ID: MW-7 / 97309
Matrix: WaterDate Collected: 01/10/23 14:18
Date Received: 01/17/23 12:02
Method: 40CFR136A 200.7 Rev 4.4 - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 ug/L 01/18/23 06:15 01/19/23 13:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Lab Sample ID: 680-229202-4Client Sample ID: MW-8 / 97310
Matrix: WaterDate Collected: 01/10/23 13:45
Date Received: 01/17/23 12:02
Method: 40CFR136A 200.7 Rev 4.4 - Metals (ICP) - Total Recoverable
RL MDL
34.8 10.0 ug/L 01/18/23 06:15 01/19/23 13:09 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Lab Sample ID: 680-229202-5Client Sample ID: TW-1 / 97311
Matrix: WaterDate Collected: 01/10/23 14:00
Date Received: 01/17/23 12:02
Method: 40CFR136A 200.7 Rev 4.4 - Metals (ICP) - Total Recoverable
RL MDL
ND 10.0 ug/L 01/18/23 06:15 01/19/23 13:18 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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QC Sample Results
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Method: 200.7 Rev 4.4 - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 680-759438/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 759797 Prep Batch: 759438
RL MDL
Lead ND 10.0 ug/L 01/18/23 06:15 01/19/23 13:03 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-759438/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 759797 Prep Batch: 759438
Lead 505 504.1 ug/L 100 85-115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec
Limits
Eurofins Savannah
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QC Association Summary
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Metals
Prep Batch: 759438
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200.7-1994 R4.4680-229202-1 MW-5 / 97307 Total Recoverable
Water 200.7-1994 R4.4680-229202-2 MW-6 / 97308 Total Recoverable
Water 200.7-1994 R4.4680-229202-3 MW-7 / 97309 Total Recoverable
Water 200.7-1994 R4.4680-229202-4 MW-8 / 97310 Total Recoverable
Water 200.7-1994 R4.4680-229202-5 TW-1 / 97311 Total Recoverable
Water 200.7-1994 R4.4MB 680-759438/1-A Method Blank Total Recoverable
Water 200.7-1994 R4.4LCS 680-759438/2-A Lab Control Sample Total Recoverable
Analysis Batch: 759797
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200.7 Rev 4.4 759438680-229202-1 MW-5 / 97307 Total Recoverable
Water 200.7 Rev 4.4 759438680-229202-2 MW-6 / 97308 Total Recoverable
Water 200.7 Rev 4.4 759438680-229202-3 MW-7 / 97309 Total Recoverable
Water 200.7 Rev 4.4 759438680-229202-4 MW-8 / 97310 Total Recoverable
Water 200.7 Rev 4.4 759438680-229202-5 TW-1 / 97311 Total Recoverable
Water 200.7 Rev 4.4 759438MB 680-759438/1-A Method Blank Total Recoverable
Water 200.7 Rev 4.4 759438LCS 680-759438/2-A Lab Control Sample Total Recoverable
Eurofins Savannah
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Lab Chronicle
Client: Waypoint Analytical, Inc.Job ID: 680-229202-1
Project/Site: 23-011-0104
Client Sample ID: MW-5 / 97307 Lab Sample ID: 680-229202-1
Matrix: WaterDate Collected: 01/10/23 14:10
Date Received: 01/17/23 12:02
Prep 200.7-1994 R4.4 RR01/18/23 06:15 EET SAV759438
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 759797 01/19/23 13:27 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: MW-6 / 97308 Lab Sample ID: 680-229202-2
Matrix: WaterDate Collected: 01/10/23 14:25
Date Received: 01/17/23 12:02
Prep 200.7-1994 R4.4 RR01/18/23 06:15 EET SAV759438
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 759797 01/19/23 13:24 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: MW-7 / 97309 Lab Sample ID: 680-229202-3
Matrix: WaterDate Collected: 01/10/23 14:18
Date Received: 01/17/23 12:02
Prep 200.7-1994 R4.4 RR01/18/23 06:15 EET SAV759438
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 759797 01/19/23 13:21 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: MW-8 / 97310 Lab Sample ID: 680-229202-4
Matrix: WaterDate Collected: 01/10/23 13:45
Date Received: 01/17/23 12:02
Prep 200.7-1994 R4.4 RR01/18/23 06:15 EET SAV759438
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 759797 01/19/23 13:09 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: TW-1 / 97311 Lab Sample ID: 680-229202-5
Matrix: WaterDate Collected: 01/10/23 14:00
Date Received: 01/17/23 12:02
Prep 200.7-1994 R4.4 RR01/18/23 06:15 EET SAV759438
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 759797 01/19/23 13:18 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
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Accreditation/Certification Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229202-1
Project/Site: 23-011-0104
Laboratory: Eurofins Savannah
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW) State 269 12-31-23
South Carolina State 98001 06-30-23
Eurofins Savannah
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Method Summary
Job ID: 680-229202-1Client: Waypoint Analytical, Inc.
Project/Site: 23-011-0104
Method Method Description LaboratoryProtocol
40CFR136A200.7 Rev 4.4 Metals (ICP)EET SAV
EPA200.7-1994 R4.4 Preparation, Total Recoverable Metals EET SAV
Protocol References:
40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater", 40CFR, Part 136, Appendix A, October 26, 1984 and
subsequent revisions.
EPA = US Environmental Protection Agency
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
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Login Sample Receipt Checklist
Client: Waypoint Analytical, Inc.Job Number: 680-229202-1
Login Number: 229202
Question Answer Comment
Creator: Sims, Robert D
List Source: Eurofins Savannah
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
FalseSamples were received on ice.Thermal preservation not required.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Savannah
Page 17 of 17 1/20/2023
1
2
3
4
5
6
7
8
9
10
11
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Page 125 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29020
Associated Lab Samples: 97303, 97305
LRB-V29020 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/19/23 03:5810.01.80<1.80µg/LAcetone
01/19/23 03:580.5000.210<0.210µg/LBromobenzene
01/19/23 03:581.000.420<0.420µg/LBromochloromethane
01/19/23 03:580.5000.160<0.160µg/LBromodichloromethane
01/19/23 03:585.001.50<1.50µg/LBromoform
01/19/23 03:581.000.280<0.280µg/LBromomethane
01/19/23 03:580.5000.180<0.180µg/Ln-Butylbenzene
01/19/23 03:580.5000.200<0.200µg/Lsec-Butyl benzene
01/19/23 03:582.000.920<0.920µg/Ltert-Butyl benzene
01/19/23 03:580.5000.180<0.180µg/LCarbon Tetrachloride
01/19/23 03:580.5000.190<0.190µg/LChlorobenzene
01/19/23 03:580.5000.190<0.190µg/LChlorodibromomethane
01/19/23 03:581.000.430<0.430µg/LChloroethane
01/19/23 03:580.5000.220<0.220µg/LChloroform
01/19/23 03:580.5000.220<0.220µg/LChloromethane
01/19/23 03:580.5000.200<0.200µg/L2-Chlorotoluene
01/19/23 03:580.5000.200<0.200µg/L4-Chlorotoluene
01/19/23 03:580.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
01/19/23 03:582.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
01/19/23 03:580.5000.200<0.200µg/L1,2-Dibromoethane
01/19/23 03:580.5000.230<0.230µg/LDibromomethane
01/19/23 03:580.5000.220<0.220µg/L1,2-Dichlorobenzene
01/19/23 03:580.5000.190<0.190µg/L1,3-Dichlorobenzene
01/19/23 03:580.5000.210<0.210µg/L1,4-Dichlorobenzene
01/19/23 03:585.001.20<1.20µg/LDichlorodifluoromethane
01/19/23 03:580.5000.240<0.240µg/L1,1-Dichloroethane
01/19/23 03:580.5000.150<0.150µg/L1,2-Dichloroethane
Page 1 of 36Date:01/27/2023 04:56 PM
Page 126 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29020
Associated Lab Samples: 97303, 97305
LRB-V29020 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/19/23 03:580.5000.150<0.150µg/L1,1-Dichloroethene
01/19/23 03:580.5000.200<0.200µg/Lcis-1,2-Dichloroethene
01/19/23 03:580.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
01/19/23 03:580.5000.190<0.190µg/L1,2-Dichloropropane
01/19/23 03:580.5000.130<0.130µg/L1,3-Dichloropropane
01/19/23 03:582.000.210<0.210µg/L2,2-Dichloropropane
01/19/23 03:580.5000.200<0.200µg/L1,1-Dichloropropene
01/19/23 03:580.5000.210<0.210µg/Lcis-1,3-Dichloropropene
01/19/23 03:580.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
01/19/23 03:5820042.0<42.0µg/LEthanol
01/19/23 03:583.000.350<0.350µg/LHexachlorobutadiene
01/19/23 03:581.000.380<0.380µg/L2-Hexanone
01/19/23 03:580.5000.180<0.180µg/LIsopropylbenzene
01/19/23 03:580.5000.089<0.089µg/L4-Isopropyl toluene
01/19/23 03:585.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
01/19/23 03:581.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
01/19/23 03:581.000.078<0.078µg/L4-Methyl-2-Pentanone
01/19/23 03:582.000.330<0.330µg/LMethylene Chloride
01/19/23 03:581.000.470<0.470µg/LNaphthalene
01/19/23 03:580.5000.190<0.190µg/Ln-Propylbenzene
01/19/23 03:580.5000.220<0.220µg/LStyrene
01/19/23 03:5810.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
01/19/23 03:5810.00.350<0.350µg/Ltert-Butyl formate (TBF)
01/19/23 03:5810.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
01/19/23 03:5810.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
01/19/23 03:580.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
01/19/23 03:580.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
Page 2 of 36Date:01/27/2023 04:56 PM
Page 127 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29020
Associated Lab Samples: 97303, 97305
LRB-V29020 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/19/23 03:580.5000.220<0.220µg/LTetrachloroethene
01/19/23 03:580.5000.380<0.380µg/L1,2,3-Trichlorobenzene
01/19/23 03:580.5000.310<0.310µg/L1,2,4-Trichlorobenzene
01/19/23 03:580.5000.160<0.160µg/L1,1,1-Trichloroethane
01/19/23 03:580.5000.096<0.096µg/L1,1,2-Trichloroethane
01/19/23 03:580.5000.180<0.180µg/LTrichloroethene
01/19/23 03:580.5000.180<0.180µg/LTrichlorofluoromethane
01/19/23 03:580.5000.270<0.270µg/L1,2,3-Trichloropropane
01/19/23 03:585.001.00<1.00µg/LVinyl Acetate
01/19/23 03:580.5000.170<0.170µg/LVinyl Chloride
01/19/23 03:5810.01.00<1.00µg/L3,3-Dimethyl-1-butanol
01/19/23 03:584-Bromofluorobenzene (S)123 70-130
01/19/23 03:58Dibromofluoromethane (S)93.0 70-130
01/19/23 03:581,2-Dichloroethane - d4 (S)97.0 70-130
01/19/23 03:58Toluene-d8 (S)95.4 70-130
LCS-V29020 LCSD-V29020Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
24.2 60.562.525.040.0µg/LAcetone 40-160 3.2 20.0
20.4 10210621.220.0µg/LBromobenzene 70-130 3.8 20.0
20.3 10210220.320.0µg/LBromochloromethane 70-130 0.0 20.0
19.6 98.099.019.820.0µg/LBromodichloromethane 70-130 1.0 20.0
18.1 90.598.519.720.0µg/LBromoform 70-130 8.4 20.0
17.8 89.087.017.420.0µg/LBromomethane 60-140 2.2 20.0
20.1 10110521.020.0µg/Ln-Butylbenzene 70-130 4.3 20.0
Page 3 of 36Date:01/27/2023 04:56 PM
Page 128 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29020
LCS-V29020 LCSD-V29020Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
19.8 99.010220.420.0µg/Lsec-Butyl benzene 70-130 2.9 20.0
19.7 98.510320.620.0µg/Ltert-Butyl benzene 70-130 4.4 20.0
18.8 94.096.019.220.0µg/LCarbon Tetrachloride 70-130 2.1 20.0
20.3 10210821.620.0µg/LChlorobenzene 70-130 6.2 20.0
18.3 91.591.018.220.0µg/LChlorodibromomethane 70-130 0.5 20.0
20.8 10410520.920.0µg/LChloroethane 60-140 0.4 20.0
20.1 10110320.520.0µg/LChloroform 70-130 1.9 20.0
18.9 94.597.019.420.0µg/LChloromethane 60-140 2.6 20.0
20.1 10110420.820.0µg/L2-Chlorotoluene 70-130 3.4 20.0
19.8 99.010520.920.0µg/L4-Chlorotoluene 70-130 5.4 20.0
19.2 96.010020.020.0µg/LDi-Isopropyl Ether (DIPE)70-130 4.0 20.0
18.6 93.085.517.120.0µg/L1,2-Dibromo-3-Chloropropane 70-130 8.4 20.0
19.4 97.010020.020.0µg/L1,2-Dibromoethane 70-130 3.0 20.0
19.7 98.594.518.920.0µg/LDibromomethane 70-130 4.1 20.0
19.7 98.510420.820.0µg/L1,2-Dichlorobenzene 70-130 5.4 20.0
19.5 97.510521.020.0µg/L1,3-Dichlorobenzene 70-130 7.4 20.0
19.4 97.010420.720.0µg/L1,4-Dichlorobenzene 70-130 6.4 20.0
21.8 10910621.220.0µg/LDichlorodifluoromethane 60-140 2.7 20.0
19.8 99.010420.720.0µg/L1,1-Dichloroethane 70-130 4.4 20.0
19.4 97.097.019.420.0µg/L1,2-Dichloroethane 70-130 0.0 20.0
19.5 97.510220.320.0µg/L1,1-Dichloroethene 70-130 4.0 20.0
19.5 97.510520.920.0µg/Lcis-1,2-Dichloroethene 70-130 6.9 20.0
20.8 10410721.320.0µg/Ltrans-1,2-Dichloroethene 70-130 2.3 20.0
20.1 10110320.620.0µg/L1,2-Dichloropropane 70-130 2.4 20.0
19.2 96.099.019.820.0µg/L1,3-Dichloropropane 70-130 3.0 20.0
17.9 89.589.017.820.0µg/L2,2-Dichloropropane 70-130 0.5 20.0
Page 4 of 36Date:01/27/2023 04:56 PM
Page 129 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29020
LCS-V29020 LCSD-V29020Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
20.6 10310220.420.0µg/L1,1-Dichloropropene 70-130 0.9 20.0
19.9 99.596.019.220.0µg/Lcis-1,3-Dichloropropene 70-130 3.5 20.0
19.7 98.595.019.020.0µg/Ltrans-1,3-Dichloropropene 70-130 3.6 20.0
388 77.677.4387500µg/LEthanol 60-140 0.2 20.0
20.5 10396.019.220.0µg/LHexachlorobutadiene 70-130 6.5 20.0
14.9 74.578.515.720.0µg/L2-Hexanone 60-140 5.2 20.0
21.1 10611022.020.0µg/LIsopropylbenzene 70-130 4.1 20.0
20.0 10010320.620.0µg/L4-Isopropyl toluene 70-130 2.9 20.0
15.7 78.570.014.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 11.4 20.0
18.6 93.094.518.920.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.6 20.0
15.6 78.078.515.720.0µg/L4-Methyl-2-Pentanone 60-140 0.6 20.0
20.1 10110220.320.0µg/LMethylene Chloride 70-130 0.9 20.0
19.8 99.010420.720.0µg/LNaphthalene 70-130 4.4 20.0
20.4 10210621.220.0µg/Ln-Propylbenzene 70-130 3.8 20.0
18.7 93.510621.120.0µg/LStyrene 70-130 12.0 20.0
27.6 69.071.528.640.0µg/Ltert-Butyl Alcohol (TBA)40-140 3.5 20.0
35.2 88.075.230.140.0µg/Ltert-Butyl formate (TBF)40-140 15.6 20.0
15.6 78.068.513.720.0µg/Ltert-Amyl Alcohol (TAA)40-140 12.9 20.0
38.8 97.095.738.340.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.2 20.0
21.3 10711122.220.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.1 20.0
18.2 91.093.018.620.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.1 20.0
21.3 10711222.420.0µg/LTetrachloroethene 70-130 5.0 20.0
23.3 11711122.120.0µg/L1,2,3-Trichlorobenzene 70-130 5.2 20.0
21.4 10710821.620.0µg/L1,2,4-Trichlorobenzene 70-130 0.9 20.0
20.2 10110120.220.0µg/L1,1,1-Trichloroethane 70-130 0.0 20.0
19.2 96.094.018.820.0µg/L1,1,2-Trichloroethane 70-130 2.1 20.0
Page 5 of 36Date:01/27/2023 04:56 PM
Page 130 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29020
LCS-V29020 LCSD-V29020Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
20.2 10110520.920.0µg/LTrichloroethene 70-130 3.4 20.0
20.0 10010020.020.0µg/LTrichlorofluoromethane 60-140 0.0 20.0
17.5 87.590.018.020.0µg/L1,2,3-Trichloropropane 70-130 2.8 20.0
15.8 79.070.514.120.0µg/LVinyl Acetate 60-140 11.3 20.0
20.7 10410621.120.0µg/LVinyl Chloride 60-140 1.9 20.0
17.1 85.580.016.020.0µg/L3,3-Dimethyl-1-butanol 70-130 6.6 20.0
98.61034-Bromofluorobenzene (S)70-130
98.096.2Dibromofluoromethane (S)70-130
97.296.21,2-Dichloroethane - d4 (S)70-130
101104Toluene-d8 (S)70-130
Page 6 of 36Date:01/27/2023 04:56 PM
Page 131 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29096QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29095
Associated Lab Samples: 97303, 97304, 97305, 97306
LRB-V29095 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/22/23 15:3210.01.80<1.80µg/LAcetone
01/22/23 15:320.5000.180<0.180µg/LBenzene
01/22/23 15:320.5000.210<0.210µg/LBromobenzene
01/22/23 15:321.000.420<0.420µg/LBromochloromethane
01/22/23 15:320.5000.160<0.160µg/LBromodichloromethane
01/22/23 15:325.001.50<1.50µg/LBromoform
01/22/23 15:321.000.280<0.280µg/LBromomethane
01/22/23 15:320.5000.180<0.180µg/Ln-Butylbenzene
01/22/23 15:320.5000.200<0.200µg/Lsec-Butyl benzene
01/22/23 15:322.000.920<0.920µg/Ltert-Butyl benzene
01/22/23 15:320.5000.180<0.180µg/LCarbon Tetrachloride
01/22/23 15:320.5000.190<0.190µg/LChlorobenzene
01/22/23 15:320.5000.190<0.190µg/LChlorodibromomethane
01/22/23 15:321.000.430<0.430µg/LChloroethane
01/22/23 15:320.5000.220<0.220µg/LChloroform
01/22/23 15:320.5000.220<0.220µg/LChloromethane
01/22/23 15:320.5000.200<0.200µg/L2-Chlorotoluene
01/22/23 15:320.5000.200<0.200µg/L4-Chlorotoluene
01/22/23 15:320.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
01/22/23 15:322.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
01/22/23 15:320.5000.200<0.200µg/L1,2-Dibromoethane
01/22/23 15:320.5000.230<0.230µg/LDibromomethane
01/22/23 15:320.5000.220<0.220µg/L1,2-Dichlorobenzene
01/22/23 15:320.5000.190<0.190µg/L1,3-Dichlorobenzene
01/22/23 15:320.5000.210<0.210µg/L1,4-Dichlorobenzene
01/22/23 15:325.001.20<1.20µg/LDichlorodifluoromethane
01/22/23 15:320.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 36Date:01/27/2023 04:56 PM
Page 132 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29096QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29095
Associated Lab Samples: 97303, 97304, 97305, 97306
LRB-V29095 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/22/23 15:320.5000.150<0.150µg/L1,2-Dichloroethane
01/22/23 15:320.5000.150<0.150µg/L1,1-Dichloroethene
01/22/23 15:320.5000.200<0.200µg/Lcis-1,2-Dichloroethene
01/22/23 15:320.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
01/22/23 15:320.5000.190<0.190µg/L1,2-Dichloropropane
01/22/23 15:320.5000.130<0.130µg/L1,3-Dichloropropane
01/22/23 15:322.000.210<0.210µg/L2,2-Dichloropropane
01/22/23 15:320.5000.200<0.200µg/L1,1-Dichloropropene
01/22/23 15:320.5000.210<0.210µg/Lcis-1,3-Dichloropropene
01/22/23 15:320.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
01/22/23 15:3220042.0<42.0µg/LEthanol
01/22/23 15:320.5000.170<0.170µg/LEthylbenzene
01/22/23 15:323.000.350<0.350µg/LHexachlorobutadiene
01/22/23 15:321.000.380<0.380µg/L2-Hexanone
01/22/23 15:320.5000.180<0.180µg/LIsopropylbenzene
01/22/23 15:320.5000.089<0.089µg/L4-Isopropyl toluene
01/22/23 15:325.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
01/22/23 15:321.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
01/22/23 15:321.000.078<0.078µg/L4-Methyl-2-Pentanone
01/22/23 15:322.000.330<0.330µg/LMethylene Chloride
01/22/23 15:321.000.470<0.470µg/LNaphthalene
01/22/23 15:320.5000.190<0.190µg/Ln-Propylbenzene
01/22/23 15:320.5000.220<0.220µg/LStyrene
01/22/23 15:3210.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
01/22/23 15:3210.00.350<0.350µg/Ltert-Butyl formate (TBF)
01/22/23 15:3210.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
01/22/23 15:3210.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 8 of 36Date:01/27/2023 04:56 PM
Page 133 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29096QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29095
Associated Lab Samples: 97303, 97304, 97305, 97306
LRB-V29095 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/22/23 15:320.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
01/22/23 15:320.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
01/22/23 15:320.5000.220<0.220µg/LTetrachloroethene
01/22/23 15:320.5000.220<0.220µg/LToluene
01/22/23 15:320.5000.380<0.380µg/L1,2,3-Trichlorobenzene
01/22/23 15:320.5000.310<0.310µg/L1,2,4-Trichlorobenzene
01/22/23 15:320.5000.160<0.160µg/L1,1,1-Trichloroethane
01/22/23 15:320.5000.096<0.096µg/L1,1,2-Trichloroethane
01/22/23 15:320.5000.180<0.180µg/LTrichloroethene
01/22/23 15:320.5000.180<0.180µg/LTrichlorofluoromethane
01/22/23 15:320.5000.270<0.270µg/L1,2,3-Trichloropropane
01/22/23 15:320.5000.190<0.190µg/L1,2,4-Trimethylbenzene
01/22/23 15:320.5000.180<0.180µg/L1,3,5-Trimethylbenzene
01/22/23 15:325.001.00<1.00µg/LVinyl Acetate
01/22/23 15:320.5000.170<0.170µg/LVinyl Chloride
01/22/23 15:320.5000.210<0.210µg/Lo-Xylene
01/22/23 15:321.000.420<0.420µg/Lm,p-Xylene
01/22/23 15:3210.01.00<1.00µg/L3,3-Dimethyl-1-butanol
01/22/23 15:324-Bromofluorobenzene (S)101 70-130
01/22/23 15:32Dibromofluoromethane (S)98.4 70-130
01/22/23 15:321,2-Dichloroethane - d4 (S)99.6 70-130
01/22/23 15:32Toluene-d8 (S)99.2 70-130
Page 9 of 36Date:01/27/2023 04:56 PM
Page 134 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29096QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29095
LCS-V29095 LCSD-V29095Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
36.0 90.089.735.940.0µg/LAcetone 40-160 0.2 20.0
19.7 98.599.519.920.0µg/LBenzene 70-130 1.0 20.0
19.4 97.096.519.320.0µg/LBromobenzene 70-130 0.5 20.0
16.3 81.582.016.420.0µg/LBromochloromethane 70-130 0.6 20.0
18.3 91.592.018.420.0µg/LBromodichloromethane 70-130 0.5 20.0
17.6 88.091.518.320.0µg/LBromoform 70-130 3.8 20.0
19.4 97.098.519.720.0µg/LBromomethane 60-140 1.5 20.0
18.0 90.095.019.020.0µg/Ln-Butylbenzene 70-130 5.4 20.0
19.5 97.598.519.720.0µg/Lsec-Butyl benzene 70-130 1.0 20.0
20.1 10110621.220.0µg/Ltert-Butyl benzene 70-130 5.3 20.0
18.2 91.095.519.120.0µg/LCarbon Tetrachloride 70-130 4.8 20.0
20.2 10110220.320.0µg/LChlorobenzene 70-130 0.4 20.0
19.7 98.596.519.320.0µg/LChlorodibromomethane 70-130 2.0 20.0
17.9 89.594.018.820.0µg/LChloroethane 60-140 4.9 20.0
18.3 91.597.519.520.0µg/LChloroform 70-130 6.3 20.0
16.3 81.584.016.820.0µg/LChloromethane 60-140 3.0 20.0
19.1 95.596.519.320.0µg/L2-Chlorotoluene 70-130 1.0 20.0
17.4 87.089.017.820.0µg/L4-Chlorotoluene 70-130 2.2 20.0
17.4 87.091.518.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 5.0 20.0
20.0 10098.019.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 2.0 20.0
18.9 94.590.018.020.0µg/L1,2-Dibromoethane 70-130 4.8 20.0
18.4 92.088.017.620.0µg/LDibromomethane 70-130 4.4 20.0
17.3 86.593.018.620.0µg/L1,2-Dichlorobenzene 70-130 7.2 20.0
18.4 92.090.518.120.0µg/L1,3-Dichlorobenzene 70-130 1.6 20.0
18.4 92.095.019.020.0µg/L1,4-Dichlorobenzene 70-130 3.2 20.0
16.5 82.589.017.820.0µg/LDichlorodifluoromethane 60-140 7.5 20.0
Page 10 of 36Date:01/27/2023 04:56 PM
Page 135 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29096QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29095
LCS-V29095 LCSD-V29095Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
15.5 77.592.518.520.0µg/L1,1-Dichloroethane 70-130 17.6 20.0
18.5 92.599.019.820.0µg/L1,2-Dichloroethane 70-130 6.7 20.0
21.0 10511122.220.0µg/L1,1-Dichloroethene 70-130 5.5 20.0
19.0 95.092.018.420.0µg/Lcis-1,2-Dichloroethene 70-130 3.2 20.0
19.2 96.010020.020.0µg/Ltrans-1,2-Dichloroethene 70-130 4.0 20.0
18.2 91.096.019.220.0µg/L1,2-Dichloropropane 70-130 5.3 20.0
18.5 92.592.018.420.0µg/L1,3-Dichloropropane 70-130 0.5 20.0
17.6 88.096.019.220.0µg/L2,2-Dichloropropane 70-130 8.6 20.0
19.8 99.010120.220.0µg/L1,1-Dichloropropene 70-130 2.0 20.0
18.9 94.597.019.420.0µg/Lcis-1,3-Dichloropropene 70-130 2.6 20.0
19.1 95.510821.520.0µg/Ltrans-1,3-Dichloropropene 70-130 11.8 20.0
448 89.690.6453500µg/LEthanol 60-140 1.1 20.0
19.9 99.599.019.820.0µg/LEthylbenzene 70-130 0.5 20.0
15.2 76.084.516.920.0µg/LHexachlorobutadiene 70-130 10.5 20.0
18.5 92.584.516.920.0µg/L2-Hexanone 60-140 9.0 20.0
18.3 91.510120.220.0µg/LIsopropylbenzene 70-130 9.8 20.0
20.0 10010521.020.0µg/L4-Isopropyl toluene 70-130 4.8 20.0
19.8 99.098.519.720.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.5 20.0
19.4 97.089.017.820.0µg/LMethyl tert-butyl ether (MTBE)70-130 8.6 20.0
20.4 10295.019.020.0µg/L4-Methyl-2-Pentanone 60-140 7.1 20.0
19.3 96.596.519.320.0µg/LMethylene Chloride 70-130 0.0 20.0
19.5 97.510120.120.0µg/LNaphthalene 70-130 3.0 20.0
17.8 89.086.517.320.0µg/Ln-Propylbenzene 70-130 2.8 20.0
19.5 97.510120.120.0µg/LStyrene 70-130 3.0 20.0
35.9 89.781.032.440.0µg/Ltert-Butyl Alcohol (TBA)40-140 10.2 20.0
42.0 10597.739.140.0µg/Ltert-Butyl formate (TBF)40-140 7.1 20.0
Page 11 of 36Date:01/27/2023 04:56 PM
Page 136 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29096QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29095
LCS-V29095 LCSD-V29095Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
26.2 13113326.620.0µg/Ltert-Amyl Alcohol (TAA)40-140 1.5 20.0
40.2 10110240.740.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.2 20.0
21.3 10711222.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 5.0 20.0
19.3 96.589.017.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 8.0 20.0
18.8 94.096.519.320.0µg/LTetrachloroethene 70-130 2.6 20.0
19.1 95.596.019.220.0µg/LToluene 70-130 0.5 20.0
20.2 10198.019.620.0µg/L1,2,3-Trichlorobenzene 70-130 3.0 20.0
17.3 86.597.519.520.0µg/L1,2,4-Trichlorobenzene 70-130 11.9 20.0
17.8 89.098.519.720.0µg/L1,1,1-Trichloroethane 70-130 10.1 20.0
18.4 92.097.519.520.0µg/L1,1,2-Trichloroethane 70-130 5.8 20.0
18.4 92.098.019.620.0µg/LTrichloroethene 70-130 6.3 20.0
16.5 82.592.518.520.0µg/LTrichlorofluoromethane 60-140 11.4 20.0
18.0 90.080.016.020.0µg/L1,2,3-Trichloropropane 70-130 11.7 20.0
19.0 95.099.019.820.0µg/L1,2,4-Trimethylbenzene 70-130 4.1 20.0
19.5 97.595.019.020.0µg/L1,3,5-Trimethylbenzene 70-130 2.5 20.0
21.2 10680.516.120.0µg/LVinyl Acetate 60-140 27.3*20.0
16.9 84.594.518.920.0µg/LVinyl Chloride 60-140 11.1 20.0
18.1 90.587.017.420.0µg/Lo-Xylene 70-130 3.9 20.0
39.5 98.795.738.340.0µg/Lm,p-Xylene 70-130 3.0 20.0
22.6 11394.018.820.0µg/L3,3-Dimethyl-1-butanol 70-130 18.3 20.0
1011064-Bromofluorobenzene (S)70-130
98.899.0Dibromofluoromethane (S)70-130
1051021,2-Dichloroethane - d4 (S)70-130
107101Toluene-d8 (S)70-130
Page 12 of 36* QC Fail Date:01/27/2023 04:56 PM
Page 137 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29115
Associated Lab Samples: 97310, 97312
LRB-V29115 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/23/23 13:2310.01.80<1.80µg/LAcetone
01/23/23 13:230.5000.180<0.180µg/LBenzene
01/23/23 13:230.5000.210<0.210µg/LBromobenzene
01/23/23 13:231.000.420<0.420µg/LBromochloromethane
01/23/23 13:230.5000.160<0.160µg/LBromodichloromethane
01/23/23 13:235.001.50<1.50µg/LBromoform
01/23/23 13:231.000.280<0.280µg/LBromomethane
01/23/23 13:230.5000.180<0.180µg/Ln-Butylbenzene
01/23/23 13:230.5000.200<0.200µg/Lsec-Butyl benzene
01/23/23 13:232.000.920<0.920µg/Ltert-Butyl benzene
01/23/23 13:230.5000.180<0.180µg/LCarbon Tetrachloride
01/23/23 13:230.5000.190<0.190µg/LChlorobenzene
01/23/23 13:230.5000.190<0.190µg/LChlorodibromomethane
01/23/23 13:231.000.430<0.430µg/LChloroethane
01/23/23 13:230.5000.220<0.220µg/LChloroform
01/23/23 13:230.5000.220<0.220µg/LChloromethane
01/23/23 13:230.5000.200<0.200µg/L2-Chlorotoluene
01/23/23 13:230.5000.200<0.200µg/L4-Chlorotoluene
01/23/23 13:230.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
01/23/23 13:232.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
01/23/23 13:230.5000.200<0.200µg/L1,2-Dibromoethane
01/23/23 13:230.5000.230<0.230µg/LDibromomethane
01/23/23 13:230.5000.220<0.220µg/L1,2-Dichlorobenzene
01/23/23 13:230.5000.190<0.190µg/L1,3-Dichlorobenzene
01/23/23 13:230.5000.210<0.210µg/L1,4-Dichlorobenzene
01/23/23 13:235.001.20<1.20µg/LDichlorodifluoromethane
01/23/23 13:230.5000.240<0.240µg/L1,1-Dichloroethane
Page 13 of 36Date:01/27/2023 04:56 PM
Page 138 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29115
Associated Lab Samples: 97310, 97312
LRB-V29115 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/23/23 13:230.5000.150<0.150µg/L1,2-Dichloroethane
01/23/23 13:230.5000.150<0.150µg/L1,1-Dichloroethene
01/23/23 13:230.5000.200<0.200µg/Lcis-1,2-Dichloroethene
01/23/23 13:230.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
01/23/23 13:230.5000.190<0.190µg/L1,2-Dichloropropane
01/23/23 13:230.5000.130<0.130µg/L1,3-Dichloropropane
01/23/23 13:232.000.210<0.210µg/L2,2-Dichloropropane
01/23/23 13:230.5000.200<0.200µg/L1,1-Dichloropropene
01/23/23 13:230.5000.210<0.210µg/Lcis-1,3-Dichloropropene
01/23/23 13:230.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
01/23/23 13:2320042.0<42.0µg/LEthanol
01/23/23 13:230.5000.170<0.170µg/LEthylbenzene
01/23/23 13:233.000.350<0.350µg/LHexachlorobutadiene
01/23/23 13:231.000.380<0.380µg/L2-Hexanone
01/23/23 13:230.5000.180<0.180µg/LIsopropylbenzene
01/23/23 13:230.5000.089<0.089µg/L4-Isopropyl toluene
01/23/23 13:235.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
01/23/23 13:231.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
01/23/23 13:231.000.078<0.078µg/L4-Methyl-2-Pentanone
01/23/23 13:232.000.330<0.330µg/LMethylene Chloride
01/23/23 13:231.000.470<0.470µg/LNaphthalene
01/23/23 13:230.5000.190<0.190µg/Ln-Propylbenzene
01/23/23 13:230.5000.220<0.220µg/LStyrene
01/23/23 13:2310.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
01/23/23 13:2310.00.350<0.350µg/Ltert-Butyl formate (TBF)
01/23/23 13:2310.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
01/23/23 13:2310.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 14 of 36Date:01/27/2023 04:56 PM
Page 139 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29115
Associated Lab Samples: 97310, 97312
LRB-V29115 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/23/23 13:230.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
01/23/23 13:230.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
01/23/23 13:230.5000.220<0.220µg/LTetrachloroethene
01/23/23 13:230.5000.220<0.220µg/LToluene
01/23/23 13:230.5000.380<0.380µg/L1,2,3-Trichlorobenzene
01/23/23 13:230.5000.310<0.310µg/L1,2,4-Trichlorobenzene
01/23/23 13:230.5000.160<0.160µg/L1,1,1-Trichloroethane
01/23/23 13:230.5000.096<0.096µg/L1,1,2-Trichloroethane
01/23/23 13:230.5000.180<0.180µg/LTrichloroethene
01/23/23 13:230.5000.180<0.180µg/LTrichlorofluoromethane
01/23/23 13:230.5000.270<0.270µg/L1,2,3-Trichloropropane
01/23/23 13:230.5000.190<0.190µg/L1,2,4-Trimethylbenzene
01/23/23 13:230.5000.180<0.180µg/L1,3,5-Trimethylbenzene
01/23/23 13:235.001.00<1.00µg/LVinyl Acetate
01/23/23 13:230.5000.170<0.170µg/LVinyl Chloride
01/23/23 13:230.5000.210<0.210µg/Lo-Xylene
01/23/23 13:231.000.420<0.420µg/Lm,p-Xylene
01/23/23 13:2310.01.00<1.00µg/L3,3-Dimethyl-1-butanol
01/23/23 13:234-Bromofluorobenzene (S)102 70-130
01/23/23 13:23Dibromofluoromethane (S)93.6 70-130
01/23/23 13:231,2-Dichloroethane - d4 (S)92.6 70-130
01/23/23 13:23Toluene-d8 (S)100 70-130
Page 15 of 36Date:01/27/2023 04:56 PM
Page 140 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29115
LCS-V29115 LCSD-V29115Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
37.6 94.090.736.340.0µg/LAcetone 40-160 3.5 20.0
19.4 97.098.019.620.0µg/LBenzene 70-130 1.0 20.0
19.0 95.010120.120.0µg/LBromobenzene 70-130 5.6 20.0
15.3 76.576.515.320.0µg/LBromochloromethane 70-130 0.0 20.0
17.2 86.086.017.220.0µg/LBromodichloromethane 70-130 0.0 20.0
19.7 98.591.518.320.0µg/LBromoform 70-130 7.3 20.0
19.7 98.510821.520.0µg/LBromomethane 60-140 8.7 20.0
18.3 91.590.018.020.0µg/Ln-Butylbenzene 70-130 1.6 20.0
20.4 10299.019.820.0µg/Lsec-Butyl benzene 70-130 2.9 20.0
21.3 10797.019.420.0µg/Ltert-Butyl benzene 70-130 9.3 20.0
18.9 94.595.519.120.0µg/LCarbon Tetrachloride 70-130 1.0 20.0
20.9 10510220.420.0µg/LChlorobenzene 70-130 2.4 20.0
21.0 10510520.920.0µg/LChlorodibromomethane 70-130 0.4 20.0
17.9 89.590.518.120.0µg/LChloroethane 60-140 1.1 20.0
18.0 90.094.518.920.0µg/LChloroform 70-130 4.8 20.0
15.7 78.585.017.020.0µg/LChloromethane 60-140 7.9 20.0
19.4 97.089.017.820.0µg/L2-Chlorotoluene 70-130 8.6 20.0
18.7 93.583.016.620.0µg/L4-Chlorotoluene 70-130 11.8 20.0
19.8 99.099.019.820.0µg/LDi-Isopropyl Ether (DIPE)70-130 0.0 20.0
17.5 87.595.519.120.0µg/L1,2-Dibromo-3-Chloropropane 70-130 8.7 20.0
18.5 92.584.516.920.0µg/L1,2-Dibromoethane 70-130 9.0 20.0
17.8 89.082.516.520.0µg/LDibromomethane 70-130 7.5 20.0
19.8 99.090.018.020.0µg/L1,2-Dichlorobenzene 70-130 9.5 20.0
18.2 91.098.019.620.0µg/L1,3-Dichlorobenzene 70-130 7.4 20.0
18.4 92.094.018.820.0µg/L1,4-Dichlorobenzene 70-130 2.1 20.0
14.8 74.076.515.320.0µg/LDichlorodifluoromethane 60-140 3.3 20.0
Page 16 of 36Date:01/27/2023 04:56 PM
Page 141 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29115
LCS-V29115 LCSD-V29115Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
16.4 82.086.517.320.0µg/L1,1-Dichloroethane 70-130 5.3 20.0
19.2 96.097.519.520.0µg/L1,2-Dichloroethane 70-130 1.5 20.0
19.6 98.010921.820.0µg/L1,1-Dichloroethene 70-130 10.6 20.0
18.6 93.094.518.920.0µg/Lcis-1,2-Dichloroethene 70-130 1.6 20.0
18.0 90.010320.620.0µg/Ltrans-1,2-Dichloroethene 70-130 13.4 20.0
18.6 93.097.019.420.0µg/L1,2-Dichloropropane 70-130 4.2 20.0
18.2 91.090.518.120.0µg/L1,3-Dichloropropane 70-130 0.5 20.0
17.9 89.593.518.720.0µg/L2,2-Dichloropropane 70-130 4.3 20.0
21.0 10510621.120.0µg/L1,1-Dichloropropene 70-130 0.4 20.0
18.5 92.510120.220.0µg/Lcis-1,3-Dichloropropene 70-130 8.7 20.0
18.3 91.510420.820.0µg/Ltrans-1,3-Dichloropropene 70-130 12.7 20.0
464 92.890.2451500µg/LEthanol 60-140 2.8 20.0
19.6 98.010320.620.0µg/LEthylbenzene 70-130 4.9 20.0
18.7 93.594.018.820.0µg/LHexachlorobutadiene 70-130 0.5 20.0
17.6 88.093.518.720.0µg/L2-Hexanone 60-140 6.0 20.0
19.5 97.598.519.720.0µg/LIsopropylbenzene 70-130 1.0 20.0
21.3 10710521.020.0µg/L4-Isopropyl toluene 70-130 1.4 20.0
19.5 97.592.018.420.0µg/LMethyl Ethyl Ketone (MEK)60-140 5.8 20.0
18.5 92.596.519.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 4.2 20.0
17.2 86.096.519.320.0µg/L4-Methyl-2-Pentanone 60-140 11.5 20.0
18.0 90.094.018.820.0µg/LMethylene Chloride 70-130 4.3 20.0
22.1 11110120.120.0µg/LNaphthalene 70-130 9.4 20.0
18.1 90.590.018.020.0µg/Ln-Propylbenzene 70-130 0.5 20.0
19.7 98.510220.420.0µg/LStyrene 70-130 3.4 20.0
36.0 90.090.536.240.0µg/Ltert-Butyl Alcohol (TBA)40-140 0.5 20.0
37.8 94.597.739.140.0µg/Ltert-Butyl formate (TBF)40-140 3.3 20.0
Page 17 of 36Date:01/27/2023 04:56 PM
Page 142 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29115
LCS-V29115 LCSD-V29115Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
26.4 13212124.120.0µg/Ltert-Amyl Alcohol (TAA)40-140 9.1 20.0
40.3 10110040.040.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.7 20.0
21.8 10910020.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 8.6 20.0
18.6 93.089.017.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.3 20.0
18.0 90.094.018.820.0µg/LTetrachloroethene 70-130 4.3 20.0
18.5 92.594.518.920.0µg/LToluene 70-130 2.1 20.0
23.4 11710120.120.0µg/L1,2,3-Trichlorobenzene 70-130 15.1 20.0
19.4 97.094.018.820.0µg/L1,2,4-Trichlorobenzene 70-130 3.1 20.0
18.2 91.094.518.920.0µg/L1,1,1-Trichloroethane 70-130 3.7 20.0
19.1 95.598.519.720.0µg/L1,1,2-Trichloroethane 70-130 3.0 20.0
18.3 91.592.018.420.0µg/LTrichloroethene 70-130 0.5 20.0
16.6 83.091.018.220.0µg/LTrichlorofluoromethane 60-140 9.1 20.0
19.1 95.586.517.320.0µg/L1,2,3-Trichloropropane 70-130 9.8 20.0
20.0 10097.519.520.0µg/L1,2,4-Trimethylbenzene 70-130 2.5 20.0
20.2 10188.517.720.0µg/L1,3,5-Trimethylbenzene 70-130 13.1 20.0
22.8 11410821.520.0µg/LVinyl Acetate 60-140 5.8 20.0
17.2 86.092.018.420.0µg/LVinyl Chloride 60-140 6.7 20.0
18.9 94.590.018.020.0µg/Lo-Xylene 70-130 4.8 20.0
36.9 92.295.038.040.0µg/Lm,p-Xylene 70-130 2.9 20.0
19.7 98.587.517.520.0µg/L3,3-Dimethyl-1-butanol 70-130 11.8 20.0
98.698.04-Bromofluorobenzene (S)70-130
97.096.0Dibromofluoromethane (S)70-130
96.897.61,2-Dichloroethane - d4 (S)70-130
98.499.4Toluene-d8 (S)70-130
Page 18 of 36Date:01/27/2023 04:56 PM
Page 143 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29119QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29118
Associated Lab Samples: 97307, 97308, 97309, 97311
LRB-V29118 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/24/23 01:0110.01.80<1.80µg/LAcetone
01/24/23 01:010.5000.180<0.180µg/LBenzene
01/24/23 01:010.5000.210<0.210µg/LBromobenzene
01/24/23 01:011.000.420<0.420µg/LBromochloromethane
01/24/23 01:010.5000.160<0.160µg/LBromodichloromethane
01/24/23 01:015.001.50<1.50µg/LBromoform
01/24/23 01:011.000.280<0.280µg/LBromomethane
01/24/23 01:010.5000.180<0.180µg/Ln-Butylbenzene
01/24/23 01:010.5000.200<0.200µg/Lsec-Butyl benzene
01/24/23 01:012.000.920<0.920µg/Ltert-Butyl benzene
01/24/23 01:010.5000.180<0.180µg/LCarbon Tetrachloride
01/24/23 01:010.5000.190<0.190µg/LChlorobenzene
01/24/23 01:010.5000.190<0.190µg/LChlorodibromomethane
01/24/23 01:011.000.430<0.430µg/LChloroethane
01/24/23 01:010.5000.220<0.220µg/LChloroform
01/24/23 01:010.5000.220<0.220µg/LChloromethane
01/24/23 01:010.5000.200<0.200µg/L2-Chlorotoluene
01/24/23 01:010.5000.200<0.200µg/L4-Chlorotoluene
01/24/23 01:010.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
01/24/23 01:012.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
01/24/23 01:010.5000.230<0.230µg/LDibromomethane
01/24/23 01:010.5000.220<0.220µg/L1,2-Dichlorobenzene
01/24/23 01:010.5000.190<0.190µg/L1,3-Dichlorobenzene
01/24/23 01:010.5000.210<0.210µg/L1,4-Dichlorobenzene
01/24/23 01:015.001.20<1.20µg/LDichlorodifluoromethane
01/24/23 01:010.5000.240<0.240µg/L1,1-Dichloroethane
01/24/23 01:010.5000.150<0.150µg/L1,2-Dichloroethane
Page 19 of 36Date:01/27/2023 04:56 PM
Page 144 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29119QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29118
Associated Lab Samples: 97307, 97308, 97309, 97311
LRB-V29118 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/24/23 01:010.5000.150<0.150µg/L1,1-Dichloroethene
01/24/23 01:010.5000.200<0.200µg/Lcis-1,2-Dichloroethene
01/24/23 01:010.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
01/24/23 01:010.5000.190<0.190µg/L1,2-Dichloropropane
01/24/23 01:010.5000.130<0.130µg/L1,3-Dichloropropane
01/24/23 01:012.000.210<0.210µg/L2,2-Dichloropropane
01/24/23 01:010.5000.200<0.200µg/L1,1-Dichloropropene
01/24/23 01:010.5000.210<0.210µg/Lcis-1,3-Dichloropropene
01/24/23 01:010.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
01/24/23 01:0120042.0<42.0µg/LEthanol
01/24/23 01:010.5000.170<0.170µg/LEthylbenzene
01/24/23 01:013.000.350<0.350µg/LHexachlorobutadiene
01/24/23 01:011.000.380<0.380µg/L2-Hexanone
01/24/23 01:010.5000.180<0.180µg/LIsopropylbenzene
01/24/23 01:010.5000.089<0.089µg/L4-Isopropyl toluene
01/24/23 01:015.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
01/24/23 01:011.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
01/24/23 01:011.000.078<0.078µg/L4-Methyl-2-Pentanone
01/24/23 01:012.000.330<0.330µg/LMethylene Chloride
01/24/23 01:011.000.470<0.470µg/LNaphthalene
01/24/23 01:010.5000.190<0.190µg/Ln-Propylbenzene
01/24/23 01:010.5000.220<0.220µg/LStyrene
01/24/23 01:0110.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
01/24/23 01:0110.00.350<0.350µg/Ltert-Butyl formate (TBF)
01/24/23 01:0110.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
01/24/23 01:0110.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
01/24/23 01:010.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 20 of 36Date:01/27/2023 04:56 PM
Page 145 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29119QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29118
Associated Lab Samples: 97307, 97308, 97309, 97311
LRB-V29118 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/24/23 01:010.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
01/24/23 01:010.5000.220<0.220µg/LTetrachloroethene
01/24/23 01:010.5000.220<0.220µg/LToluene
01/24/23 01:010.5000.380<0.380µg/L1,2,3-Trichlorobenzene
01/24/23 01:010.5000.310<0.310µg/L1,2,4-Trichlorobenzene
01/24/23 01:010.5000.160<0.160µg/L1,1,1-Trichloroethane
01/24/23 01:010.5000.096<0.096µg/L1,1,2-Trichloroethane
01/24/23 01:010.5000.180<0.180µg/LTrichloroethene
01/24/23 01:010.5000.180<0.180µg/LTrichlorofluoromethane
01/24/23 01:010.5000.270<0.270µg/L1,2,3-Trichloropropane
01/24/23 01:010.5000.190<0.190µg/L1,2,4-Trimethylbenzene
01/24/23 01:010.5000.180<0.180µg/L1,3,5-Trimethylbenzene
01/24/23 01:015.001.00<1.00µg/LVinyl Acetate
01/24/23 01:010.5000.170<0.170µg/LVinyl Chloride
01/24/23 01:010.5000.210<0.210µg/Lo-Xylene
01/24/23 01:011.000.420<0.420µg/Lm,p-Xylene
01/24/23 01:0110.01.00<1.00µg/L3,3-Dimethyl-1-butanol
01/24/23 01:014-Bromofluorobenzene (S)92.8 70-130
01/24/23 01:01Dibromofluoromethane (S)93.4 70-130
01/24/23 01:011,2-Dichloroethane - d4 (S)95.8 70-130
01/24/23 01:01Toluene-d8 (S)105 70-130
LCS-V29118 LCSD-V29118Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
32.9 82.283.733.540.0µg/LAcetone 40-160 1.8 20.0
Page 21 of 36Date:01/27/2023 04:56 PM
Page 146 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29119QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29118
LCS-V29118 LCSD-V29118Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
18.3 91.510320.620.0µg/LBenzene 70-130 11.8 20.0
19.5 97.598.019.620.0µg/LBromobenzene 70-130 0.5 20.0
16.1 80.581.016.220.0µg/LBromochloromethane 70-130 0.6 20.0
15.8 79.089.017.820.0µg/LBromodichloromethane 70-130 11.9 20.0
17.0 85.094.518.920.0µg/LBromoform 70-130 10.5 20.0
17.0 85.094.018.820.0µg/LBromomethane 60-140 10.0 20.0
19.2 96.097.019.420.0µg/Ln-Butylbenzene 70-130 1.0 20.0
20.7 10496.519.320.0µg/Lsec-Butyl benzene 70-130 7.0 20.0
22.0 11010220.420.0µg/Ltert-Butyl benzene 70-130 7.5 20.0
18.6 93.010621.220.0µg/LCarbon Tetrachloride 70-130 13.0 20.0
20.0 10010621.120.0µg/LChlorobenzene 70-130 5.3 20.0
18.9 94.597.019.420.0µg/LChlorodibromomethane 70-130 2.6 20.0
17.0 85.096.519.320.0µg/LChloroethane 60-140 12.6 20.0
18.0 90.097.019.420.0µg/LChloroform 70-130 7.4 20.0
16.9 84.595.019.020.0µg/LChloromethane 60-140 11.6 20.0
20.5 10397.519.520.0µg/L2-Chlorotoluene 70-130 5.0 20.0
18.6 93.087.517.520.0µg/L4-Chlorotoluene 70-130 6.0 20.0
19.7 98.510721.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 7.8 20.0
23.6 11887.517.520.0µg/L1,2-Dibromo-3-Chloropropane 70-130 29.6*20.0
16.3 81.591.518.320.0µg/LDibromomethane 70-130 11.5 20.0
19.1 95.594.018.820.0µg/L1,2-Dichlorobenzene 70-130 1.5 20.0
19.5 97.589.017.820.0µg/L1,3-Dichlorobenzene 70-130 9.1 20.0
18.7 93.592.018.420.0µg/L1,4-Dichlorobenzene 70-130 1.6 20.0
15.0 75.086.017.220.0µg/LDichlorodifluoromethane 60-140 13.6 20.0
16.8 84.092.518.520.0µg/L1,1-Dichloroethane 70-130 9.6 20.0
17.2 86.099.019.820.0µg/L1,2-Dichloroethane 70-130 14.0 20.0
Page 22 of 36* QC Fail Date:01/27/2023 04:56 PM
Page 147 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29119QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29118
LCS-V29118 LCSD-V29118Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
18.9 94.510220.420.0µg/L1,1-Dichloroethene 70-130 7.6 20.0
18.6 93.099.519.920.0µg/Lcis-1,2-Dichloroethene 70-130 6.7 20.0
17.0 85.010220.320.0µg/Ltrans-1,2-Dichloroethene 70-130 17.6 20.0
17.9 89.599.519.920.0µg/L1,2-Dichloropropane 70-130 10.5 20.0
18.0 90.089.517.920.0µg/L1,3-Dichloropropane 70-130 0.5 20.0
15.8 79.089.017.820.0µg/L2,2-Dichloropropane 70-130 11.9 20.0
18.0 90.010420.820.0µg/L1,1-Dichloropropene 70-130 14.4 20.0
18.7 93.510320.520.0µg/Lcis-1,3-Dichloropropene 70-130 9.1 20.0
18.7 93.510120.120.0µg/Ltrans-1,3-Dichloropropene 70-130 7.2 20.0
437 87.479.2396500µg/LEthanol 60-140 9.8 20.0
19.3 96.510320.520.0µg/LEthylbenzene 70-130 6.0 20.0
18.8 94.091.018.220.0µg/LHexachlorobutadiene 70-130 3.2 20.0
17.5 87.581.516.320.0µg/L2-Hexanone 60-140 7.1 20.0
19.9 99.593.518.720.0µg/LIsopropylbenzene 70-130 6.2 20.0
21.0 10510521.020.0µg/L4-Isopropyl toluene 70-130 0.0 20.0
19.4 97.091.018.220.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.3 20.0
17.6 88.093.018.620.0µg/LMethyl tert-butyl ether (MTBE)70-130 5.5 20.0
18.4 92.090.518.120.0µg/L4-Methyl-2-Pentanone 60-140 1.6 20.0
18.2 91.010120.120.0µg/LMethylene Chloride 70-130 9.9 20.0
23.9 12096.519.320.0µg/LNaphthalene 70-130 21.2*20.0
18.8 94.089.017.820.0µg/Ln-Propylbenzene 70-130 5.4 20.0
18.7 93.596.019.220.0µg/LStyrene 70-130 2.6 20.0
35.0 87.589.735.940.0µg/Ltert-Butyl Alcohol (TBA)40-140 2.5 20.0
36.3 90.789.235.740.0µg/Ltert-Butyl formate (TBF)40-140 1.6 20.0
20.6 10310220.320.0µg/Ltert-Amyl Alcohol (TAA)40-140 1.4 20.0
40.8 10297.238.940.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 4.7 20.0
Page 23 of 36* QC Fail Date:01/27/2023 04:56 PM
Page 148 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29119QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29118
LCS-V29118 LCSD-V29118Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
20.7 10498.519.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.9 20.0
18.7 93.586.017.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 8.3 20.0
19.7 98.592.018.420.0µg/LTetrachloroethene 70-130 6.8 20.0
18.2 91.096.519.320.0µg/LToluene 70-130 5.8 20.0
25.4 12710621.120.0µg/L1,2,3-Trichlorobenzene 70-130 18.4 20.0
20.9 10592.018.420.0µg/L1,2,4-Trichlorobenzene 70-130 12.7 20.0
16.9 84.510120.220.0µg/L1,1,1-Trichloroethane 70-130 17.7 20.0
18.9 94.596.519.320.0µg/L1,1,2-Trichloroethane 70-130 2.0 20.0
16.8 84.010120.220.0µg/LTrichloroethene 70-130 18.3 20.0
16.2 81.086.517.320.0µg/LTrichlorofluoromethane 60-140 6.5 20.0
20.3 10295.019.020.0µg/L1,2,3-Trichloropropane 70-130 6.6 20.0
21.1 10697.519.520.0µg/L1,2,4-Trimethylbenzene 70-130 7.8 20.0
21.1 10697.519.520.0µg/L1,3,5-Trimethylbenzene 70-130 7.8 20.0
18.4 92.080.516.120.0µg/LVinyl Acetate 60-140 13.3 20.0
15.9 79.594.518.920.0µg/LVinyl Chloride 60-140 17.2 20.0
17.2 86.094.018.820.0µg/Lo-Xylene 70-130 8.8 20.0
36.8 92.095.038.040.0µg/Lm,p-Xylene 70-130 3.2 20.0
19.3 96.591.018.220.0µg/L3,3-Dimethyl-1-butanol 70-130 5.8 20.0
1051004-Bromofluorobenzene (S)70-130
92.496.2Dibromofluoromethane (S)70-130
92.299.21,2-Dichloroethane - d4 (S)70-130
100103Toluene-d8 (S)70-130
Page 24 of 36Date:01/27/2023 04:56 PM
Page 149 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29244QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29243
Associated Lab Samples: 97306, 97307, 97308, 97309
LRB-V29243 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/26/23 08:230.5000.180<0.180µg/LBenzene
01/26/23 08:230.5000.170<0.170µg/LEthylbenzene
01/26/23 08:231.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
01/26/23 08:231.000.470<0.470µg/LNaphthalene
01/26/23 08:2310.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
01/26/23 08:230.5000.220<0.220µg/LToluene
01/26/23 08:230.5000.190<0.190µg/L1,2,4-Trimethylbenzene
01/26/23 08:230.5000.180<0.180µg/L1,3,5-Trimethylbenzene
01/26/23 08:230.5000.210<0.210µg/Lo-Xylene
01/26/23 08:231.000.420<0.420µg/Lm,p-Xylene
01/26/23 08:234-Bromofluorobenzene (S)104 70-130
01/26/23 08:23Dibromofluoromethane (S)101 70-130
01/26/23 08:231,2-Dichloroethane - d4 (S)98.4 70-130
01/26/23 08:23Toluene-d8 (S)111 70-130
LCS-V29243 LCSD-V29243Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
19.0 95.010120.220.0µg/LBenzene 70-130 6.1 20.0
19.7 98.510621.120.0µg/LEthylbenzene 70-130 6.8 20.0
19.2 96.095.519.120.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.5 20.0
24.1 12112825.620.0µg/LNaphthalene 70-130 6.0 20.0
20.6 10310821.620.0µg/Ltert-Amyl Alcohol (TAA)40-140 4.7 20.0
19.0 95.010220.420.0µg/LToluene 70-130 7.1 20.0
21.7 10911923.720.0µg/L1,2,4-Trimethylbenzene 70-130 8.8 20.0
21.6 10811923.820.0µg/L1,3,5-Trimethylbenzene 70-130 9.6 20.0
Page 25 of 36Date:01/27/2023 04:56 PM
Page 150 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29244QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29243
LCS-V29243 LCSD-V29243Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
19.9 99.510721.320.0µg/Lo-Xylene 70-130 6.7 20.0
41.9 10511244.940.0µg/Lm,p-Xylene 70-130 6.9 20.0
99.81024-Bromofluorobenzene (S)70-130
10299.8Dibromofluoromethane (S)70-130
10498.81,2-Dichloroethane - d4 (S)70-130
108108Toluene-d8 (S)70-130
Page 26 of 36Date:01/27/2023 04:56 PM
Page 151 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29002QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V28943
Associated Lab Samples: 97307, 97308, 97309, 97310, 97311
LRB-V28943 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/18/23 16:312.000.302<0.302µg/LAcenaphthene
01/18/23 16:312.000.297<0.297µg/LAcenaphthylene
01/18/23 16:312.000.836<0.836µg/LAnthracene
01/18/23 16:3110.01.32<1.32µg/LBenzidine
01/18/23 16:312.000.637<0.637µg/LBenzo(a)anthracene
01/18/23 16:312.001.02<1.02µg/LBenzo(a)pyrene
01/18/23 16:315.002.49<2.49µg/LBenzo(b)fluoranthene
01/18/23 16:315.001.01<1.01µg/LBenzo(g,h,i)perylene
01/18/23 16:315.001.99<1.99µg/LBenzo(k)fluoranthene
01/18/23 16:3110.01.10<1.10µg/LBenzoic Acid
01/18/23 16:315.000.684<0.684µg/LBenzyl alcohol
01/18/23 16:315.000.468<0.468µg/LBis(2-Chloroethoxy)methane
01/18/23 16:315.001.04<1.04µg/LBis(2-Chloroethyl)ether
01/18/23 16:315.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
01/18/23 16:3150.024.0<24.0µg/LBis(2-ethylhexyl)phthalate
01/18/23 16:315.001.11<1.11µg/L4-Bromophenyl phenyl ether
01/18/23 16:315.001.83<1.83µg/LButyl benzyl phthalate
01/18/23 16:315.001.18<1.18µg/L4-Chloro-3-methylphenol
01/18/23 16:3120.07.38<7.38µg/L2-Chloronaphthalene
01/18/23 16:3110.00.938<0.938µg/L2-Chlorophenol
01/18/23 16:315.001.71<1.71µg/L4-Chlorophenyl phenyl ether
01/18/23 16:312.000.405<0.405µg/LChrysene
01/18/23 16:312.000.434<0.434µg/LDibenz(a,h)anthracene
01/18/23 16:315.000.856<0.856µg/LDibenzofuran
01/18/23 16:315.002.00<2.00µg/L1,2-Dichlorobenzene
01/18/23 16:315.002.00<2.00µg/L1,3-Dichlorobenzene
01/18/23 16:315.002.05<2.05µg/L1,4-Dichlorobenzene
Page 27 of 36Date:01/27/2023 04:56 PM
Page 152 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29002QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V28943
Associated Lab Samples: 97307, 97308, 97309, 97310, 97311
LRB-V28943 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/18/23 16:315.001.89<1.89µg/L3,3'-Dichlorobenzidine
01/18/23 16:3110.01.46<1.46µg/L2,4-Dichlorophenol
01/18/23 16:315.000.745<0.745µg/LDiethyl phthalate
01/18/23 16:315.000.939<0.939µg/LDimethyl phthalate
01/18/23 16:3120.01.57<1.57µg/L2,4-Dimethylphenol
01/18/23 16:315.002.06<2.06µg/LDi-n-butyl phthalate
01/18/23 16:3110.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
01/18/23 16:3110.01.92<1.92µg/L2,4-Dinitrophenol
01/18/23 16:315.001.11<1.11µg/L2,4-Dinitrotoluene
01/18/23 16:315.000.809<0.809µg/L2,6-Dinitrotoluene
01/18/23 16:315.001.65<1.65µg/LDi-n-Octyl Phthalate
01/18/23 16:312.000.250<0.250µg/LFluoranthene
01/18/23 16:312.000.807<0.807µg/LFluorene
01/18/23 16:315.000.979<0.979µg/LHexachlorobenzene
01/18/23 16:315.002.73<2.73µg/LHexachlorobutadiene
01/18/23 16:315.002.05<2.05µg/LHexachlorocyclopentadiene
01/18/23 16:315.001.76<1.76µg/LHexachloroethane
01/18/23 16:312.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
01/18/23 16:315.000.444<0.444µg/LIsophorone
01/18/23 16:312.001.14<1.14µg/L1-Methylnaphthalene
01/18/23 16:312.000.666<0.666µg/L2-Methylnaphthalene
01/18/23 16:312.000.728<0.728µg/LNaphthalene
01/18/23 16:315.000.905<0.905µg/LNitrobenzene
01/18/23 16:315.000.493<0.493µg/L2-Nitrophenol
01/18/23 16:3110.01.23<1.23µg/L4-Nitrophenol
01/18/23 16:315.001.10<1.10µg/LN-Nitrosodiphenylamine
01/18/23 16:315.000.641<0.641µg/LN-Nitroso-di-n-propylamine
Page 28 of 36Date:01/27/2023 04:56 PM
Page 153 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29002QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V28943
Associated Lab Samples: 97307, 97308, 97309, 97310, 97311
LRB-V28943 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/18/23 16:315.001.43<1.43µg/LPentachlorophenol
01/18/23 16:312.000.428<0.428µg/LPhenanthrene
01/18/23 16:315.000.651<0.651µg/LPhenol
01/18/23 16:312.000.434<0.434µg/LPyrene
01/18/23 16:315.002.21<2.21µg/L1,2,4-Trichlorobenzene
01/18/23 16:315.001.32<1.32µg/L2,4,6-Trichlorophenol
01/18/23 16:312-Fluorobiphenyl (S)66.4 49-118
01/18/23 16:312-Fluorophenol (S)36.7 22-84
01/18/23 16:31Nitrobenzene-d5 (S)59.0 43-123
01/18/23 16:314-Terphenyl-d14 (S)78.0 49-151
01/18/23 16:312,4,6-Tribromophenol (S)72.0 31-144
01/18/23 16:31Phenol-d5 (S)26.1 10-63
LCS-V28943 LCSD-V28943Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
35.7 71.473.036.550.0µg/LAcenaphthene 47-145 2.2 20.0
35.4 70.871.235.650.0µg/LAcenaphthylene 33-145 0.5 20.0
40.8 81.680.640.350.0µg/LAnthracene 27-133 1.2 20.0
19.4 38.855.827.950.0µg/LBenzidine 15-150 35.9*20.0
40.7 81.478.839.450.0µg/LBenzo(a)anthracene 33-143 3.2 20.0
50.1 10097.648.850.0µg/LBenzo(a)pyrene 17-163 2.6 20.0
46.6 93.289.844.950.0µg/LBenzo(b)fluoranthene 24-159 3.7 20.0
43.0 86.083.641.850.0µg/LBenzo(g,h,i)perylene 10-219 2.8 20.0
45.0 90.087.843.950.0µg/LBenzo(k)fluoranthene 11-162 2.4 20.0
14.3 28.622.611.350.0µg/LBenzoic Acid 10-125 23.4*20.0
Page 29 of 36* QC Fail Date:01/27/2023 04:56 PM
Page 154 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29002QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V28943
LCS-V28943 LCSD-V28943Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
27.6 55.259.029.550.0µg/LBenzyl alcohol 16-107 6.6 20.0
28.2 56.459.629.850.0µg/LBis(2-Chloroethoxy)methane 33-184 5.5 20.0
23.4 46.851.225.650.0µg/LBis(2-Chloroethyl)ether 12-158 8.9 20.0
26.4 52.858.429.250.0µg/LBis(2-Chloroisopropyl)ether 36-166 10.0 20.0
42.1 84.282.641.350.0µg/LBis(2-ethylhexyl)phthalate 10-158 1.9 20.0
39.5 79.079.439.750.0µg/L4-Bromophenyl phenyl ether 53-127 0.5 20.0
42.6 85.282.241.150.0µg/LButyl benzyl phthalate 10-152 3.5 20.0
31.8 63.664.832.450.0µg/L4-Chloro-3-methylphenol 22-147 1.8 20.0
33.5 67.069.034.550.0µg/L2-Chloronaphthalene 60-118 2.9 20.0
24.2 48.452.626.350.0µg/L2-Chlorophenol 23-134 8.3 20.0
38.3 76.677.438.750.0µg/L4-Chlorophenyl phenyl ether 25-158 1.0 20.0
41.3 82.680.440.250.0µg/LChrysene 17-168 2.6 20.0
42.4 84.883.441.750.0µg/LDibenz(a,h)anthracene 10-227 1.6 20.0
35.9 71.873.036.550.0µg/LDibenzofuran 39-114 1.6 20.0
23.3 46.650.825.450.0µg/L1,2-Dichlorobenzene 32-129 8.6 20.0
22.7 45.450.625.350.0µg/L1,3-Dichlorobenzene 20-124 10.8 20.0
22.5 45.048.424.250.0µg/L1,4-Dichlorobenzene 20-124 7.2 20.0
32.7 65.467.033.550.0µg/L3,3'-Dichlorobenzidine 10-262 2.4 20.0
27.6 55.257.628.850.0µg/L2,4-Dichlorophenol 39-135 4.2 20.0
41.1 82.281.040.550.0µg/LDiethyl phthalate 10-114 1.4 20.0
39.3 78.678.839.450.0µg/LDimethyl phthalate 10-112 0.2 20.0
30.3 60.664.032.050.0µg/L2,4-Dimethylphenol 32-119 5.4 20.0
44.4 88.887.243.650.0µg/LDi-n-butyl phthalate 10-118 1.8 20.0
39.5 79.081.240.650.0µg/L4,6-Dinitro-2-methylphenol 10-181 2.7 20.0
44.0 88.086.243.150.0µg/L2,4-Dinitrophenol 10-191 2.0 20.0
42.2 84.483.041.550.0µg/L2,4-Dinitrotoluene 39-139 1.6 20.0
Page 30 of 36Date:01/27/2023 04:56 PM
Page 155 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29002QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V28943
LCS-V28943 LCSD-V28943Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
40.1 80.281.840.950.0µg/L2,6-Dinitrotoluene 50-158 1.9 20.0
45.2 90.490.045.050.0µg/LDi-n-Octyl Phthalate 10-146 0.4 20.0
41.4 82.881.440.750.0µg/LFluoranthene 26-137 1.7 20.0
38.4 76.878.439.250.0µg/LFluorene 59-121 2.0 20.0
40.2 80.478.839.450.0µg/LHexachlorobenzene 10-152 2.0 20.0
23.7 47.449.824.950.0µg/LHexachlorobutadiene 24-116 4.9 20.0
20.1 40.241.620.850.0µg/LHexachlorocyclopentadiene 32-117 3.4 20.0
21.5 43.048.224.150.0µg/LHexachloroethane 40-113 11.4 20.0
42.8 85.683.441.750.0µg/LIndeno(1,2,3-cd)pyrene 10-171 2.6 20.0
21.8 43.644.422.250.0µg/LIsophorone 21-196 1.8 20.0
28.4 56.859.429.750.0µg/L1-Methylnaphthalene 40-135 4.4 20.0
27.2 54.456.228.150.0µg/L2-Methylnaphthalene 18-121 3.2 20.0
25.0 50.053.226.650.0µg/LNaphthalene 21-133 6.2 20.0
25.8 51.654.227.150.0µg/LNitrobenzene 35-180 4.9 20.0
24.7 49.453.226.650.0µg/L2-Nitrophenol 29-182 7.4 20.0
17.8 35.635.817.950.0µg/L4-Nitrophenol 10-132 0.5 20.0
47.7 95.497.648.850.0µg/LN-Nitrosodiphenylamine 69-152 2.2 20.0
28.4 56.861.030.550.0µg/LN-Nitroso-di-n-propylamine 10-230 7.1 20.0
47.3 94.693.646.850.0µg/LPentachlorophenol 14-176 1.0 20.0
41.0 82.081.240.650.0µg/LPhenanthrene 54-120 0.9 20.0
11.3 22.624.612.350.0µg/LPhenol 10-112 8.4 20.0
41.5 83.080.840.450.0µg/LPyrene 52-115 2.6 20.0
23.6 47.251.425.750.0µg/L1,2,4-Trichlorobenzene 44-142 8.5 20.0
34.5 69.073.436.750.0µg/L2,4,6-Trichlorophenol 37-144 6.1 20.0
64.668.02-Fluorobiphenyl (S)49-118
29.034.12-Fluorophenol (S)22-84
Page 31 of 36Date:01/27/2023 04:56 PM
Page 156 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29002QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V28943
LCS-V28943 LCSD-V28943Laboratory Control Sample & LCSD
LCSDResultParameter LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
47.852.2Nitrobenzene-d5 (S)43-123
82.882.04-Terphenyl-d14 (S)49-151
76.476.92,4,6-Tribromophenol (S)31-144
21.423.6Phenol-d5 (S)10-63
Page 32 of 36Date:01/27/2023 04:56 PM
Page 157 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V28908QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V28888
Associated Lab Samples: 97307, 97308, 97309, 97310, 97311
LRB-V28888 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits
01/16/23 11:230.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V28888 LCSD-V28888Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
0.303 1211090.2730.250µg/L1,2-Dibromoethane 70-130 10.4 20.0
V 97308-DUP-V28888Duplicate
Max RPDParameter AnalyzedRPDDUP
Result
ResultUnits
20.0 01/16/23 13:351.9<0.0203< 0.0203µg/L1,2-Dibromoethane
V 97307-MS-V28888Matrix Spike
MS ResultParameter Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits %Rec
Limits
0.315 1210.261< 0.00345µg/L1,2-Dibromoethane 70-130
Page 33 of 36Date:01/27/2023 04:56 PM
Page 158 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V29026QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V28971
Associated Lab Samples: 97308, 97309, 97311
LRB-V28971 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/19/23 15:5935028.2<28.2µg/LAliphatic C9-C18
01/19/23 15:59500124<124µg/LAliphatic C19-C36
01/19/23 15:5925061.2<61.2µg/LAromatic C11-C22
01/19/23 15:592-Fluorobiphenyl (S)130 40-140
01/19/23 15:592-Bromonaphthalene (S)132 40-140
01/19/23 15:59Chlorooctadecane (S)92.0 40-140
01/19/23 15:59OTP Surrogate (S)104 40-140
LCS-V28971 LCSD-V28971Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
413 68.869.6418600µg/LAliphatic C9-C18 40-140 1.2 50.0
811 10196.2770800µg/LAliphatic C19-C36 40-140 5.1 50.0
2190 12911619801700µg/LAromatic C11-C22 40-140 10.0 50.0
1371272-Fluorobiphenyl (S)40-140
1391282-Bromonaphthalene (S)40-140
99.096.5Chlorooctadecane (S)40-140
113106OTP Surrogate (S)40-140
Page 34 of 36Date:01/27/2023 04:56 PM
Page 159 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V28855QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V28854
Associated Lab Samples: 97307, 97308, 97309, 97310, 97311
LRB-V28854 Matrix: AQULab Reagent Blank
Parameter AnalyzedMQLMDLBlankResultUnits %Recovery % Rec Limits
01/12/23 11:2750.011.5<11.5µg/LAliphatic C5-C8
01/12/23 11:2750.025.8<25.8µg/LAliphatic C9-C12
01/12/23 11:2750.04.02<4.02µg/LAromatic C9-C10
01/12/23 11:272,5-Dibromotoluene (FID) (S)79.1 70-130
01/12/23 11:272,5-Dibromotoluene (PID) (S)77.3 70-130
LCS-V28854 LCSD-V28854Laboratory Control Sample & LCSD
LCSDResultParameter Max
RPD
LCSD% RecLCS%RecLCSResultSpikeConc.Units % RecLimits RPD
306 10297.3292300µg/LAliphatic C5-C8 70-130 4.6 50.0
371 124122367300µg/LAliphatic C9-C12 70-130 1.0 50.0
110 110107107100µg/LAromatic C9-C10 70-130 2.7 50.0
80.678.32,5-Dibromotoluene (FID) (S)70-130
77.575.92,5-Dibromotoluene (PID) (S)70-130
Page 35 of 36Date:01/27/2023 04:56 PM
Page 160 of 164
Quality Control Data
23-011-0104Report No:
Project Description:
Client ID:Geological Resources, Inc.
Breedens 66
Total Organic Carbon - Walkley Black
WALK-BLACK
L659572QC Analytical Batch:
Analysis Method:
Analysis Description:
Associated Lab Samples: 97313, 97314
LRB Matrix: SOLLab Reagent Blank
Parameter AnalyzedMQLBlankResultUnits
01/20/23 09:460.05< 0.05%Total Organic Carbon
V 97314-DUPDuplicate
Max RPDParameter AnalyzedRPDDUPResultResultUnits
20.0 01/20/23 09:460.00.210.21%Total Organic Carbon
Page 36 of 36Date:01/27/2023 04:56 PM
Page 161 of 164
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-011-0104
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 1.5C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Not enough sample volume to analyze for EPH on samples MW-5 & MW-8.
Signature:Angela D Overcash Date & Time:01/11/2023 16:36:28
Special precautions or instructions included?
Comments:
Page 162 of 164
Page 163 of 164
Page 164 of 164

APPENDIX F
Slug Test Data
0. 0.4 0.8 1.2 1.6 2.
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\MW-1 Graph.aqt
Date: 02/01/23 Time: 13:33:06
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Breeden's 66
Project: 5991
Location: Laurinburg, NC
Test Well: MW-1
Test Date: 1/10/23
AQUIFER DATA
Saturated Thickness: 38.4 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (MW-1)
Initial Displacement: 1.75 ft Static Water Column Height: 5.7 ft
Total Well Penetration Depth: 5.7 ft Screen Length: 5.7 ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
Gravel Pack Porosity: 0.3
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 3.565E-5 ft/min y0 = 1.71 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 19.30 Test well
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 21.05 Test well
Total well depth (TWD) TWD 25.00 Test well
Top of Casing Elevation (TOC) TOC 100.00 Test well
Highest historical ground water elevation at site (HGWE) HGWE 83.21 All site wells
Deepest well depth elevation (DWDE) DWDE 44.81 Deepest well
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW)H(o) 1.75 1.75' = For a 3' , 1-1/2 " bailer in a 2" dia. Well
H: Static water column height H 5.70 TWD minus SDTW
Well # MW-1 Test well ID
7 b: Saturated thickness of aquifer b 38.40
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.1 Use 0.1
8 D: Casing length 0 Use 0.0 If water table intersects screen
L: Well screen length 5.70 Use H If H is less than L
9 R(c ): Inside radius of well casing R(c) 0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells
R(w): Well radius R(w) 0.2500 1/2 auger outside diameter in feet
R(sk): Well skin radius R(sk) 0.2500 1/2 auger outside diameter in feet
10 N(e): N(e): 0.3 Use 0.3
H(o): H(o) 1.75 Use H(o)
Breeden's 66
Laurinburg, NC
MW-1
1/10/2023
AQTESOLV DATA ENTRY FORM
(For wells screened ACROSS water table)
File: AQTESOLV Data Entry Form
Breeden's 66
Well MW-1
Test Date 01/10/23
Initial DTW
(ft) 19.30

Time Displacement
(min) (ft)
0 0
0.017 0.179
0.033 1.784
0.05 1.756
0.067 1.763
0.083 1.736
0.1 1.728
0.117 1.728
0.133 1.729
0.15 1.722
0.167 1.729
0.183 1.721
0.2 1.721
0.217 1.721
0.233 1.722
0.25 1.722
0.267 1.721
0.283 1.721
0.3 1.722
0.317 1.722
0.333 1.714
0.35 1.714
0.367 1.721
0.383 1.714
0.4 1.715
0.417 1.715
0.433 1.714
0.45 1.714
0.467 1.714
0.483 1.715
0.5 1.713
0.517 1.715
0.533 1.714
0.55 1.715
0.567 1.715
0.583 1.715
0.6 1.714
0.617 1.714
0.633 1.715
0.65 1.715
0.667 1.714
0.683 1.714
0.7 1.715
0.717 1.709
0.733 1.708
0.75 1.71
0.767 1.709
0.783 1.708
0.8 1.708
0.817 1.714
0.833 1.709
0.85 1.709
0.867 1.709
0.883 1.708
0.9 1.708
0.917 1.709
0.933 1.708
0.95 1.709
0.967 1.708
0.983 1.708
1 1.709
1.017 1.708
1.033 1.708
1.05 1.708
1.067 1.709
1.083 1.709
1.1 1.708
1.117 1.708
1.133 1.708
1.15 1.708
1.167 1.709
1.183 1.708
1.2 1.708
1.217 1.708
1.233 1.701
1.25 1.709
1.267 1.701
1.283 1.702
1.3 1.701
1.317 1.702
1.333 1.701
1.35 1.7
1.367 1.701
1.383 1.701
1.4 1.701
1.417 1.701
1.433 1.702
1.45 1.701
1.467 1.702
1.483 1.701
1.5 1.701
1.517 1.701
1.533 1.703
1.55 1.7
1.567 1.701
1.583 1.701
1.6 1.701
1.617 1.701
1.633 1.701
1.65 1.701
1.667 1.694
1.683 1.694
1.7 1.701
1.717 1.702
1.733 1.702
1.75 1.694
1.767 1.695
1.783 1.703
1.8 1.701
1.817 1.694
1.833 1.701
1.85 1.694
1.867 1.694
1.883 1.694
1.9 1.694
1.917 1.694
1.933 1.694
1.95 1.694
1.967 1.694
1.983 1.694
2 1.694
0. 4. 8. 12. 16. 20.
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\MW-8 Graph.aqt
Date: 02/01/23 Time: 13:33:39
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Breeden's 66
Project: 5991
Location: Laurinburg, NC
Test Well: MW-8
Test Date: 1/10/23
AQUIFER DATA
Saturated Thickness: 38.4 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (MW-8)
Initial Displacement: 1.75 ft Static Water Column Height: 5.44 ft
Total Well Penetration Depth: 5.44 ft Screen Length: 5.44 ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
Gravel Pack Porosity: 0.3
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.0005749 ft/min y0 = 0.9421 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 19.56 Test well
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 21.31 Test well
Total well depth (TWD) TWD 25.00 Test well
Top of Casing Elevation (TOC) TOC 99.98 Test well
Highest historical ground water elevation at site (HGWE) HGWE 83.21 All site wells
Deepest well depth elevation (DWDE) DWDE 44.81 Deepest well
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW)H(o) 1.75 1.75' = For a 3' , 1-1/2 " bailer in a 2" dia. Well
H: Static water column height H 5.44 TWD minus SDTW
Well # MW-8 Test well ID
7 b: Saturated thickness of aquifer b 38.40
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.1 Use 0.1
8 D: Casing length 0 Use 0.0 If water table intersects screen
L: Well screen length 5.44 Use H If H is less than L
9 R(c ): Inside radius of well casing R(c) 0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells
R(w): Well radius R(w) 0.2500 1/2 auger outside diameter in feet
R(sk): Well skin radius R(sk) 0.2500 1/2 auger outside diameter in feet
10 N(e): N(e): 0.3 Use 0.3
H(o): H(o) 1.75 Use H(o)
1/10/2023
AQTESOLV DATA ENTRY FORM
(For wells screened ACROSS water table)
Breeden's 66
Laurinburg, NC
MW-8
File: AQTESOLV Data Entry Form
Breeden's 66
Well MW-8
Test Date 01/10/23
Initial DTW
(ft) 19.56

Time Displacement
(min) (ft)
0 0
0.017 0.647
0.033 1.516
0.05 1.488
0.067 1.447
0.083 1.413
0.1 1.385
0.117 1.351
0.133 1.329
0.15 1.309
0.167 1.289
0.183 1.274
0.2 1.253
0.217 1.233
0.233 1.226
0.25 1.212
0.267 1.205
0.283 1.074
0.3 1.109
0.317 1.074
0.333 1.109
0.35 1.123
0.367 1.123
0.383 1.116
0.4 1.116
0.417 1.116
0.433 1.109
0.45 1.102
0.467 1.1
0.483 1.095
0.5 1.08
0.517 1.088
0.533 1.087
0.55 1.087
0.567 1.08
0.583 1.073
0.6 1.074
0.617 1.066
0.633 1.067
0.65 1.06
0.667 1.06
0.683 1.059
0.7 1.053
0.717 1.053
0.733 1.046
0.75 1.046
0.767 1.045
0.783 1.038
0.8 1.039
0.817 1.038
0.833 1.031
0.85 1.031
0.867 1.025
0.883 1.025
0.9 1.017
0.917 1.016
0.933 1.016
0.95 1.01
0.967 1.011
0.983 1.009
1 1.009
1.017 1.009
1.033 1.003
1.05 0.997
1.067 0.996
1.083 0.997
1.1 0.99
1.117 0.983
1.133 0.983
1.15 0.982
1.167 0.982
1.183 0.982
1.2 0.976
1.217 0.968
1.233 0.968
1.25 0.968
1.267 0.961
1.283 0.961
1.3 0.961
1.317 0.954
1.333 0.954
1.35 0.953
1.367 0.955
1.383 0.947
1.4 0.947
1.417 0.94
1.433 0.941
1.45 0.941
1.467 0.935
1.483 0.934
1.5 0.927
1.517 0.928
1.533 0.92
1.55 0.844
1.567 0.873
1.583 0.878
1.6 0.886
1.617 0.885
1.633 0.885
1.65 0.885
1.667 0.878
1.683 0.878
1.7 0.878
1.717 0.876
1.733 0.877
1.75 0.878
1.767 0.872
1.783 0.872
1.8 0.872
1.817 0.871
1.833 0.873
1.85 0.865
1.867 0.858
1.883 0.844
1.9 0.858
1.917 0.866
1.933 0.857
1.95 0.858
1.967 0.858
1.983 0.857
2 0.858
2.017 0.85
2.033 0.851
2.05 0.85
2.067 0.851
2.083 0.843
2.1 0.843
2.117 0.836
2.133 0.844
2.15 0.835
2.167 0.836
2.183 0.836
2.2 0.836
2.217 0.836
2.233 0.835
2.25 0.828
2.267 0.829
2.283 0.828
2.3 0.83
2.317 0.822
2.333 0.815
2.35 0.822
2.367 0.814
2.383 0.814
2.4 0.815
2.417 0.814
2.433 0.813
2.45 0.814
2.467 0.815
2.483 0.807
2.5 0.809
2.517 0.802
2.533 0.807
2.55 0.808
2.567 0.808
2.583 0.801
2.6 0.801
2.617 0.801
2.633 0.802
2.65 0.794
2.667 0.795
2.683 0.795
2.7 0.795
2.717 0.787
2.733 0.786
2.75 0.786
2.767 0.787
2.783 0.78
2.8 0.779
2.817 0.781
2.833 0.779
2.85 0.773
2.867 0.773
2.883 0.774
2.9 0.772
2.917 0.766
2.933 0.765
2.95 0.766
2.967 0.766
2.983 0.767
3 0.758
3.017 0.759
3.033 0.759
3.05 0.759
3.067 0.751
3.083 0.752
3.1 0.752
3.117 0.746
3.133 0.745
3.15 0.74
3.167 0.738
3.183 0.738
3.2 0.738
3.217 0.732
3.233 0.731
3.25 0.732
3.267 0.731
3.283 0.732
3.3 0.725
3.317 0.725
3.333 0.724
3.35 0.725
3.367 0.718
3.383 0.716
3.4 0.717
3.417 0.689
3.433 0.716
3.45 0.71
3.467 0.71
3.483 0.71
3.5 0.71
3.517 0.71
3.533 0.71
3.55 0.71
3.567 0.703
3.583 0.703
3.6 0.703
3.617 0.703
3.633 0.696
3.65 0.696
3.667 0.696
3.683 0.696
3.7 0.689
3.717 0.689
3.733 0.696
3.75 0.689
3.767 0.689
3.783 0.69
3.8 0.683
3.817 0.684
3.833 0.683
3.85 0.677
3.867 0.676
3.883 0.669
3.9 0.668
3.917 0.669
3.933 0.661
3.95 0.662
3.967 0.662
3.983 0.662
4 0.662
4.017 0.661
4.033 0.655
4.05 0.654
4.067 0.662
4.083 0.655
4.1 0.655
4.117 0.655
4.133 0.655
4.15 0.648
4.167 0.649
4.183 0.648
4.2 0.648
4.217 0.641
4.233 0.641
4.25 0.64
4.267 0.64
4.283 0.641
4.3 0.641
4.317 0.633
4.333 0.634
4.35 0.634
4.367 0.634
4.383 0.633
4.4 0.627
4.417 0.627
4.433 0.627
4.45 0.627
4.467 0.627
4.483 0.621
4.5 0.627
4.517 0.621
4.533 0.621
4.55 0.62
4.567 0.613
4.583 0.614
4.6 0.614
4.617 0.607
4.633 0.607
4.65 0.6
4.667 0.606
4.683 0.606
4.7 0.606
4.717 0.598
4.733 0.606
4.75 0.599
4.767 0.6
4.783 0.593
4.8 0.599
4.817 0.593
4.833 0.592
4.85 0.591
4.867 0.592
4.883 0.591
4.9 0.592
4.917 0.592
4.933 0.598
4.95 0.599
4.967 0.592
4.983 0.593
5 0.592
5.017 0.593
5.033 0.592
5.05 0.591
5.067 0.592
5.083 0.59
5.1 0.591
5.117 0.592
5.133 0.584
5.15 0.583
5.167 0.584
5.183 0.584
5.2 0.584
5.217 0.583
5.233 0.578
5.25 0.577
5.267 0.577
5.283 0.578
5.3 0.57
5.317 0.569
5.333 0.57
5.35 0.569
5.367 0.569
5.383 0.569
5.4 0.563
5.417 0.563
5.433 0.563
5.45 0.562
5.467 0.562
5.483 0.557
5.5 0.556
5.517 0.556
5.533 0.557
5.55 0.556
5.567 0.557
5.583 0.557
5.6 0.556
5.617 0.55
5.633 0.549
5.65 0.55
5.667 0.549
5.683 0.541
5.7 0.542
5.717 0.543
5.733 0.542
5.75 0.542
5.767 0.542
5.783 0.542
5.8 0.542
5.817 0.541
5.833 0.542
5.85 0.541
5.867 0.542
5.883 0.542
5.9 0.534
5.917 0.535
5.933 0.534
5.95 0.533
5.967 0.535
5.983 0.533
6 0.534
6.017 0.535
6.033 0.534
6.05 0.528
6.067 0.528
6.083 0.527
6.1 0.528
6.117 0.527
6.133 0.527
6.15 0.528
6.167 0.519
6.183 0.519
6.2 0.519
6.217 0.52
6.233 0.52
6.25 0.52
6.267 0.513
6.283 0.512
6.3 0.511
6.317 0.513
6.333 0.512
6.35 0.512
6.367 0.513
6.383 0.513
6.4 0.513
6.417 0.512
6.433 0.505
6.45 0.506
6.467 0.505
6.483 0.506
6.5 0.505
6.517 0.505
6.533 0.506
6.55 0.505
6.567 0.498
6.583 0.499
6.6 0.497
6.617 0.498
6.633 0.498
6.65 0.499
6.667 0.498
6.683 0.492
6.7 0.492
6.717 0.492
6.733 0.492
6.75 0.491
6.767 0.485
6.783 0.485
6.8 0.486
6.817 0.485
6.833 0.484
6.85 0.484
6.867 0.485
6.883 0.485
6.9 0.485
6.917 0.485
6.933 0.478
6.95 0.486
6.967 0.479
6.983 0.478
7 0.478
7.017 0.47
7.033 0.47
7.05 0.47
7.067 0.47
7.083 0.47
7.1 0.471
7.117 0.47
7.133 0.47
7.15 0.47
7.167 0.471
7.183 0.472
7.2 0.471
7.217 0.47
7.233 0.463
7.25 0.463
7.267 0.464
7.283 0.463
7.3 0.463
7.317 0.464
7.333 0.464
7.35 0.456
7.367 0.457
7.383 0.457
7.4 0.456
7.417 0.456
7.433 0.456
7.45 0.457
7.467 0.449
7.483 0.449
7.5 0.45
7.517 0.442
7.533 0.442
7.55 0.449
7.567 0.45
7.583 0.449
7.6 0.45
7.617 0.448
7.633 0.443
7.65 0.442
7.667 0.441
7.683 0.449
7.7 0.444
7.717 0.439
7.733 0.443
7.75 0.429
7.767 0.442
7.783 0.442
7.8 0.443
7.817 0.441
7.833 0.442
7.85 0.441
7.867 0.442
7.883 0.442
7.9 0.435
7.917 0.435
7.933 0.435
7.95 0.434
7.967 0.435
7.983 0.435
8 0.435
8.017 0.435
8.033 0.435
8.05 0.435
8.067 0.435
8.083 0.429
8.1 0.428
8.117 0.429
8.133 0.428
8.15 0.428
8.167 0.429
8.183 0.428
8.2 0.429
8.217 0.429
8.233 0.429
8.25 0.429
8.267 0.427
8.283 0.428
8.3 0.428
8.317 0.428
8.333 0.428
8.35 0.429
8.367 0.429
8.383 0.42
8.4 0.421
8.417 0.422
8.433 0.413
8.45 0.421
8.467 0.421
8.483 0.414
8.5 0.414
8.517 0.414
8.533 0.415
8.55 0.415
8.567 0.414
8.583 0.414
8.6 0.414
8.617 0.414
8.633 0.414
8.65 0.415
8.667 0.414
8.683 0.414
8.7 0.413
8.717 0.415
8.733 0.414
8.75 0.415
8.767 0.415
8.783 0.408
8.8 0.407
8.817 0.406
8.833 0.407
8.85 0.407
8.867 0.408
8.883 0.407
8.9 0.407
8.917 0.407
8.933 0.4
8.95 0.4
8.967 0.401
8.983 0.401
9 0.4
9.017 0.4
9.033 0.4
9.05 0.4
9.067 0.399
9.083 0.398
9.1 0.4
9.117 0.399
9.133 0.399
9.15 0.399
9.167 0.399
9.183 0.399
9.2 0.399
9.217 0.393
9.233 0.399
9.25 0.392
9.267 0.392
9.283 0.393
9.3 0.393
9.317 0.393
9.333 0.393
9.35 0.394
9.367 0.393
9.383 0.392
9.4 0.392
9.417 0.393
9.433 0.393
9.45 0.385
9.467 0.386
9.483 0.385
9.5 0.385
9.517 0.386
9.533 0.385
9.55 0.386
9.567 0.385
9.583 0.386
9.6 0.386
9.617 0.385
9.633 0.386
9.65 0.387
9.667 0.386
9.683 0.386
9.7 0.386
9.717 0.386
9.733 0.385
9.75 0.385
9.767 0.386
9.783 0.385
9.8 0.384
9.817 0.385
9.833 0.386
9.85 0.379
9.867 0.385
9.883 0.379
9.9 0.378
9.917 0.378
9.933 0.378
9.95 0.379
9.967 0.379
9.983 0.378
10 0.378
10.017 0.38
10.033 0.38
10.05 0.379
10.067 0.38
10.083 0.379
10.1 0.379
10.117 0.379
10.133 0.378
10.15 0.371
10.167 0.371
10.183 0.372
10.2 0.372
10.217 0.371
10.233 0.377
10.25 0.371
10.267 0.371
10.283 0.372
10.3 0.372
10.317 0.371
10.333 0.372
10.35 0.378
10.367 0.378
10.383 0.371
10.4 0.371
10.417 0.372
10.433 0.372
10.45 0.371
10.467 0.371
10.483 0.371
10.5 0.372
10.517 0.371
10.533 0.372
10.55 0.373
10.567 0.372
10.583 0.364
10.6 0.366
10.617 0.364
10.633 0.365
10.65 0.364
10.667 0.363
10.683 0.364
10.7 0.365
10.717 0.365
10.733 0.365
10.75 0.365
10.767 0.365
10.783 0.364
10.8 0.365
10.817 0.371
10.833 0.364
10.85 0.364
10.867 0.364
10.883 0.364
10.9 0.364
10.917 0.364
10.933 0.366
10.95 0.364
10.967 0.364
10.983 0.365
11 0.364
11.017 0.363
11.033 0.364
11.05 0.363
11.067 0.364
11.083 0.364
11.1 0.363
11.117 0.363
11.133 0.364
11.15 0.364
11.167 0.363
11.183 0.364
11.2 0.365
11.217 0.358
11.233 0.358
11.25 0.358
11.267 0.358
11.283 0.357
11.3 0.358
11.317 0.364
11.333 0.364
11.35 0.357
11.367 0.357
11.383 0.357
11.4 0.357
11.417 0.358
11.433 0.357
11.45 0.358
11.467 0.357
11.483 0.357
11.5 0.357
11.517 0.357
11.533 0.355
11.55 0.357
11.567 0.358
11.583 0.351
11.6 0.357
11.617 0.363
11.633 0.358
11.65 0.357
11.667 0.33
11.683 0.35
11.7 0.364
11.717 0.363
11.733 0.364
11.75 0.363
11.767 0.357
11.783 0.357
11.8 0.357
11.817 0.357
11.833 0.356
11.85 0.356
11.867 0.356
11.883 0.357
11.9 0.357
11.917 0.356
11.933 0.356
11.95 0.356
11.967 0.356
11.983 0.356
12 0.356

0. 2. 4. 6. 8. 10.
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\TW-1 Graph.aqt
Date: 02/01/23 Time: 13:34:12
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Breeden's 66
Project: 5991
Location: Laurinburg, NC
Test Well: TW-1
Test Date: 1/10/23
AQUIFER DATA
Saturated Thickness: 38.4 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (TW-1)
Initial Displacement: 1.75 ft Static Water Column Height: 32.9 ft
Total Well Penetration Depth: 32.9 ft Screen Length: 5. ft
Casing Radius: 0.085 ft Well Radius: 0.1667 ft
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.0007378 ft/min y0 = 1.68 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 22.10 Test well (ft)
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 23.85 Test well (ft)
Total well depth (TWD)TWD 55.00 Test well (ft)
Top of Casing Elevation (TOC)TOC 99.81 Test well (ft)
Highest ground water elevation at site (HGWE)HGWE 83.21 All site wells (ft)
Deepest well depth elevation (DWDE)DWDE 44.81 Deepest well (ft)
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW (ft))H(o)1.75 Use 1.75
H: Static water column height H 32.90 TWD minus SDTW (ft)
Well #TW-1 Test well ID
7 b: Saturated thickness of aquifer b 38.40
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.10 Use 0.1
8 D: Casing length D 27.90 TWD minus SDTW minus screen length (ft)
L: Well screen length L 5.00 Screen length (ft)
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells(ft)
R(w): Well radius R(w)0.1667 1/2 auger outside diameter (ft)
R(sk): Well skin radius R(sk)0.1667 1/2 auger outside diameter (ft)
1/10/2023
AQTESOLV DATA ENTRY FORM
(For wells screened BELOW water table)
Breeden's 66
Laurinburg, NC
TW-1
File: AQTESOLV Data Entry Form
Breeden's 66
Well TW-1
Test Date 01/10/23
Initial DTW
(ft) 22.10

Time Displacement
(min) (ft)
0 0
0.017 0.455
0.033 4.216
0.05 1.82
0.067 1.695
0.083 1.681
0.1 1.66
0.117 1.654
0.133 1.641
0.15 1.634
0.167 1.62
0.183 1.613
0.2 1.598
0.217 1.59
0.233 1.578
0.25 1.572
0.267 1.565
0.283 1.558
0.3 1.544
0.317 1.536
0.333 1.53
0.35 1.517
0.367 1.51
0.383 1.504
0.4 1.496
0.417 1.496
0.433 1.482
0.45 1.482
0.467 1.482
0.483 1.481
0.5 1.475
0.517 1.476
0.533 1.468
0.55 1.462
0.567 1.461
0.583 1.456
0.6 1.448
0.617 1.441
0.633 1.433
0.65 1.427
0.667 1.42
0.683 1.412
0.7 1.413
0.717 1.406
0.733 1.399
0.75 1.393
0.767 1.386
0.783 1.379
0.8 1.37
0.817 1.372
0.833 1.358
0.85 1.35
0.867 1.351
0.883 1.344
0.9 1.338
0.917 1.33
0.933 1.323
0.95 1.324
0.967 1.317
0.983 1.31
1 1.303
1.017 1.297
1.033 1.296
1.05 1.29
1.067 1.282
1.083 1.275
1.1 1.269
1.117 1.269
1.133 1.262
1.15 1.255
1.167 1.248
1.183 1.242
1.2 1.242
1.217 1.235
1.233 1.227
1.25 1.22
1.267 1.213
1.283 1.212
1.3 1.208
1.317 1.201
1.333 1.201
1.35 1.193
1.367 1.187
1.383 1.179
1.4 1.179
1.417 1.172
1.433 1.165
1.45 1.165
1.467 1.158
1.483 1.151
1.5 1.146
1.517 1.145
1.533 1.138
1.55 1.13
1.567 1.131
1.583 1.125
1.6 1.117
1.617 1.111
1.633 1.11
1.65 1.103
1.667 1.103
1.683 1.096
1.7 1.089
1.717 1.084
1.733 1.084
1.75 1.076
1.767 1.07
1.783 1.07
1.8 1.062
1.817 1.056
1.833 1.055
1.85 1.048
1.867 1.042
1.883 1.042
1.9 1.034
1.917 1.027
1.933 1.028
1.95 1.022
1.967 1.015
1.983 1.014
2 1.008
2.017 1.007
2.033 1
2.05 1.001
2.067 0.994
2.083 0.987
2.1 0.988
2.117 0.979
2.133 0.973
2.15 0.973
2.167 0.967
2.183 0.967
2.2 0.96
2.217 0.952
2.233 0.952
2.25 0.945
2.267 0.947
2.283 0.939
2.3 0.932
2.317 0.931
2.333 0.925
2.35 0.918
2.367 0.918
2.383 0.911
2.4 0.91
2.417 0.911
2.433 0.905
2.45 0.897
2.467 0.898
2.483 0.892
2.5 0.891
2.517 0.883
2.533 0.883
2.55 0.876
2.567 0.87
2.583 0.871
2.6 0.864
2.617 0.857
2.633 0.856
2.65 0.848
2.667 0.849
2.683 0.85
2.7 0.843
2.717 0.836
2.733 0.837
2.75 0.83
2.767 0.83
2.783 0.823
2.8 0.821
2.817 0.823
2.833 0.816
2.85 0.809
2.867 0.809
2.883 0.801
2.9 0.801
2.917 0.795
2.933 0.795
2.95 0.787
2.967 0.788
2.983 0.781
3 0.782
3.017 0.781
3.033 0.775
3.05 0.774
3.067 0.767
3.083 0.768
3.1 0.761
3.117 0.754
3.133 0.754
3.15 0.747
3.167 0.747
3.183 0.747
3.2 0.74
3.217 0.739
3.233 0.733
3.25 0.733
3.267 0.726
3.283 0.725
3.3 0.719
3.317 0.719
3.333 0.713
3.35 0.712
3.367 0.705
3.383 0.706
3.4 0.698
3.417 0.699
3.433 0.698
3.45 0.699
3.467 0.691
3.483 0.691
3.5 0.693
3.517 0.686
3.533 0.677
3.55 0.678
3.567 0.671
3.583 0.671
3.6 0.671
3.617 0.664
3.633 0.665
3.65 0.657
3.667 0.657
3.683 0.658
3.7 0.651
3.717 0.651
3.733 0.644
3.75 0.644
3.767 0.645
3.783 0.637
3.8 0.637
3.817 0.63
3.833 0.63
3.85 0.63
3.867 0.623
3.883 0.623
3.9 0.617
3.917 0.616
3.933 0.61
3.95 0.609
3.967 0.61
3.983 0.603
4 0.603
4.017 0.602
4.033 0.596
4.05 0.595
4.067 0.595
4.083 0.589
4.1 0.59
4.117 0.59
4.133 0.583
4.15 0.583
4.167 0.575
4.183 0.574
4.2 0.576
4.217 0.576
4.233 0.568
4.25 0.568
4.267 0.562
4.283 0.562
4.3 0.555
4.317 0.561
4.333 0.554
4.35 0.554
4.367 0.548
4.383 0.547
4.4 0.547
4.417 0.54
4.433 0.541
4.45 0.533
4.467 0.532
4.483 0.534
4.5 0.533
4.517 0.528
4.533 0.528
4.55 0.528
4.567 0.521
4.583 0.52
4.6 0.52
4.617 0.521
4.633 0.514
4.65 0.506
4.667 0.513
4.683 0.507
4.7 0.506
4.717 0.505
4.733 0.5
4.75 0.5
4.767 0.499
4.783 0.492
4.8 0.492
4.817 0.493
4.833 0.485
4.85 0.485
4.867 0.486
4.883 0.485
4.9 0.478
4.917 0.478
4.933 0.471
4.95 0.471
4.967 0.471
4.983 0.472
5 0.471
5.017 0.466
5.033 0.465
5.05 0.466
5.067 0.459
5.083 0.458
5.1 0.452
5.117 0.451
5.133 0.451
5.15 0.451
5.167 0.452
5.183 0.444
5.2 0.444
5.217 0.444
5.233 0.437
5.25 0.437
5.267 0.435
5.283 0.438
5.3 0.43
5.317 0.431
5.333 0.431
5.35 0.423
5.367 0.423
5.383 0.423
5.4 0.424
5.417 0.423
5.433 0.416
5.45 0.417
5.467 0.409
5.483 0.409
5.5 0.409
5.517 0.409
5.533 0.409
5.55 0.403
5.567 0.402
5.583 0.402
5.6 0.402
5.617 0.396
5.633 0.396
5.65 0.395
5.667 0.397
5.683 0.388
5.7 0.389
5.717 0.388
5.733 0.381
5.75 0.389
5.767 0.389
5.783 0.382
5.8 0.381
5.817 0.375
5.833 0.375
5.85 0.375
5.867 0.375
5.883 0.368
5.9 0.368
5.917 0.368
5.933 0.369
5.95 0.368
5.967 0.361
5.983 0.361
6 0.362
6.017 0.36
6.033 0.361
6.05 0.361
6.067 0.355
6.083 0.355
6.1 0.347
6.117 0.354
6.133 0.347
6.15 0.354
6.167 0.347
6.183 0.347
6.2 0.34
6.217 0.34
6.233 0.34
6.25 0.34
6.267 0.334
6.283 0.333
6.3 0.335
6.317 0.333
6.333 0.334
6.35 0.328
6.367 0.327
6.383 0.326
6.4 0.326
6.417 0.327
6.433 0.32
6.45 0.32
6.467 0.32
6.483 0.321
6.5 0.32
6.517 0.321
6.533 0.312
6.55 0.314
6.567 0.314
6.583 0.313
6.6 0.313
6.617 0.306
6.633 0.307
6.65 0.306
6.667 0.307
6.683 0.299
6.7 0.299
6.717 0.299
6.733 0.3
6.75 0.299
6.767 0.292
6.783 0.292
6.8 0.292
6.817 0.292
6.833 0.293
6.85 0.291
6.867 0.285
6.883 0.285
6.9 0.286
6.917 0.285
6.933 0.285
6.95 0.286
6.967 0.285
6.983 0.286
7 0.277
7.017 0.278
7.033 0.278
7.05 0.277
7.067 0.278
7.083 0.273
7.1 0.272
7.117 0.272
7.133 0.272
7.15 0.273
7.167 0.265
7.183 0.271
7.2 0.265
7.217 0.265
7.233 0.266
7.25 0.264
7.267 0.265
7.283 0.258
7.3 0.258
7.317 0.258
7.333 0.258
7.35 0.258
7.367 0.252
7.383 0.251
7.4 0.251
7.417 0.252
7.433 0.251
7.45 0.243
7.467 0.25
7.483 0.244
7.5 0.244
7.517 0.245
7.533 0.235
7.55 0.245
7.567 0.245
7.583 0.244
7.6 0.237
7.617 0.237
7.633 0.238
7.65 0.237
7.667 0.238
7.683 0.237
7.7 0.231
7.717 0.23
7.733 0.231
7.75 0.23
7.767 0.23
7.783 0.229
7.8 0.224
7.817 0.224
7.833 0.224
7.85 0.223
7.867 0.223
7.883 0.223
7.9 0.222
7.917 0.223
7.933 0.216
7.95 0.217
7.967 0.216
7.983 0.217
8 0.217
8.017 0.217
8.033 0.217
8.05 0.211
8.067 0.21
8.083 0.21
8.1 0.21
8.117 0.21
8.133 0.21
8.15 0.211
8.167 0.21
8.183 0.204
8.2 0.204
8.217 0.203
8.233 0.204
8.25 0.203
8.267 0.203
8.283 0.204
8.3 0.196
8.317 0.203
8.333 0.197
8.35 0.196
8.367 0.196
8.383 0.196
8.4 0.196
8.417 0.197
8.433 0.197
8.45 0.19
8.467 0.19
8.483 0.189
8.5 0.19
8.517 0.189
8.533 0.189
8.55 0.189
8.567 0.19
8.583 0.189
8.6 0.189
8.617 0.182
8.633 0.182
8.65 0.183
8.667 0.183
8.683 0.183
8.7 0.182
8.717 0.176
8.733 0.174
8.75 0.175
8.767 0.175
8.783 0.176
8.8 0.175
8.817 0.176
8.833 0.176
8.85 0.176
8.867 0.175
8.883 0.175
8.9 0.169
8.917 0.175
8.933 0.168
8.95 0.169
8.967 0.169
8.983 0.169
9 0.169
9.017 0.169
9.033 0.169
9.05 0.169
9.067 0.162
9.083 0.162
9.1 0.161
9.117 0.162
9.133 0.161
9.15 0.161
9.167 0.162
9.183 0.162
9.2 0.162
9.217 0.161
9.233 0.161
9.25 0.155
9.267 0.155
9.283 0.155
9.3 0.155
9.317 0.155
9.333 0.155
9.35 0.156
9.367 0.155
9.383 0.156
9.4 0.149
9.417 0.149
9.433 0.149
9.45 0.149
9.467 0.15
9.483 0.149
9.5 0.15
9.517 0.149
9.533 0.149
9.55 0.149
9.567 0.15
9.583 0.142
9.6 0.142
9.617 0.142
9.633 0.142
9.65 0.142
9.667 0.142
9.683 0.142
9.7 0.142
9.717 0.143
9.733 0.142
9.75 0.143
9.767 0.136
9.783 0.136
9.8 0.135
9.817 0.135
9.833 0.136
9.85 0.135
9.867 0.136
9.883 0.135
9.9 0.136
9.917 0.135
9.933 0.136
9.95 0.128
9.967 0.129
9.983 0.128
10 0.128

APPENDIX G
Public Notification

•
•
••
January 31, 2023

CERTIFIED MAIL

Mayor Jim T. Willis
Mayor of Laurinburg
P.O. Box 249
Laurinburg, NC 28353

RE: Comprehensive Site Assessment – Public Notice
Breeden’s 66
22900 Aberdeen Road
Laurinburg, North Carolina
Scotland County
Incident Number: 48332
GRI Project Number: 5991
Dear Mayor Willis:

In March 2022, a petroleum release was reported at the above referenced property. In conjunction with
North Carolina Department of Environmental Quality (NCDEQ), soil and ground water assessment
activities, including those Limited Site Assessment (LSA) and Comprehensive Site Assessment (CSA),
were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or comments.

Sincerely,
William Regenthal, P.G.
Project Manager

enclosure

•
•
••
January 31, 2023

CERTIFIED MAIL

Ms. Kristen Patterson
Health Director – Scotland County
P.O. Box 69
Laurinburg, NC 28352

RE: Comprehensive Site Assessment – Public Notice
Breeden’s 66
22900 Aberdeen Road
Laurinburg, North Carolina
Scotland County
Incident Number: 48332
GRI Project Number: 5991
Dear Ms. Patterson:

In March 2022, a petroleum release was reported at the above referenced property. In conjunction with
North Carolina Department of Environmental Quality (NCDEQ), soil and ground water assessment
activities, including those Limited Site Assessment (LSA) and Comprehensive Site Assessment (CSA),
were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or comments.

Sincerely,
William Regenthal, P.G.
Project Manager

enclosure

•
•
••
January 31, 2023

CERTIFIED MAIL

Mr. Charles D. Nichols, III
City Manager of Laurinburg
P.O. Box 69
Laurinburg, NC 28353

RE: Comprehensive Site Assessment – Public Notice
Breeden’s 66
22900 Aberdeen Road
Laurinburg, North Carolina
Scotland County
Incident Number: 48332
GRI Project Number: 5991
Dear Mr. Nichols:

In March 2022, a petroleum release was reported at the above referenced property. In conjunction with
North Carolina Department of Environmental Quality (NCDEQ), soil and ground water assessment
activities, including those Limited Site Assessment (LSA) and Comprehensive Site Assessment (CSA),
were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or comments.

Sincerely,
William Regenthal, P.G.
Project Manager

enclosure