FA-29108_48295_CA_LSA_20230315

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
March 15, 2023

Mr. Mike Haseltine
NCDEQ-UST Section
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405

Re: Phase II Limited Site Assessment Report
Mercy Grocery
1487 US Highway 15-501
Carthage, Moore County
North Carolina
Facility ID Number: 00-0-0000002143
Incident Number: 48295
GRI Project Number: 5947

Dear Mr. Haseltine,

Please find enclosed, the referenced report for the abovementioned site.
If you have any questions, please contact Scott Driscoll at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Yonas Badi; Mercy, LLC, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Phase II Limited Site Assessment Report
Mercy Grocery
1487 US Highway 15-501
Carthage, Moore County
North Carolina
Facility ID Number: 00-0-00000002143
Incident Number: 48295
GRI Project Number: 5947

Prepared for:

Mr. Yonas Badi
Mercy, LLC.
1487 US Highway 15-501,
Carthage, North Carolina 28326

March 8, 2023

Scott Driscoll
Project Manager
Colton Coolbaugh
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
i
EXECUTIVE SUMMARY
The Mercy Grocery site is located at 1487 US Highway 15-501 in Carthage, Moore County, North Carolina.
The property operates as a petroleum retail facility and convenience store. The site is covered by asphalt,
concrete, gravel and grass. There are two 8,000-gallon gasoline, one 2,000-gallon gasoline and one 1,000-
gallon diesel USTs currently in use at the site with three gasoline and one diesel dispensers. The
surrounding properties are zoned rural agricultural (RA), industrial (I) and business (B-1).

On October 19, 2021, NCDEQ conducted a compliance inspection at the site. Results of the inspection
noted numerous deficiencies, and a NOV was issued October 21, 2021. The NOV noted that records
provided to NCDEQ from 2019 summarizing tightness tests performed on the regular and premium spill
bucket(s) indicated a failing result. Based on this information, NCDEQ requested that a Site Check be
performed. On February 1, 2022, soil sampling conducted as part of the site check reported TPH soil
concentrations that exceeded RALs. The site check results identified a release at the site and a LSA was
required.

A receptor survey was conducted on October 6, 2022. Six water supply wells were identified within a
1,500-foot radius of the site. No water supply wells were identified within 250 feet of the site. Water
supply wells WSW-1, WSW-3, and WSW 5 were determined to be non-potable. The closest active water
supply well (WSW-4) is located 535 feet northwest of the site. Public water is available to the subject site
and to all surrounding through to Town of Carthage; PWS ID: NC0363025.

On October 6, 2022, GRI installed a Type II ground water monitoring well (MW-1) adjacent to the tank
basin at the site. A ground water sample was collected from MW-1 and was submitted to an NC certified
laboratory for analyses of VOCs, SVOCs, Lead and EPH/VPH. Ground water sampling revealed targeted
petroleum constituents above the MACs.

On January 26, 2023, four additional monitoring wells (GMW-2 through GMW-5) were installed at the
site. Groundwater samples collected from GMW-2 though GMW-5 revealed concentrations of individual
BTEX constituents, naphthalene, TAA, TBA, bromodichloromethane, Dibromochloromethane, EDB,
Isopropylbenzene, n-propylbenzene, styrene, 1,2,4-trimethylbenzene, and/or 1,3,5-trimethylbenzene
exceeding the MACs in GMW-2, GMW-4, and GMW-5. No reported contaminant concentrations in the
ground water samples collected exceeded the GCLs. Measurable amounts of free product have not been
detected at the site.

Risk based soil samples collected at a depth of four feet from the borehole drilled to install GMW-2
revealed concentrations of benzo(a)anthracene, benzo(b)fluoranthene and ideno(1,2,3-c,d)pyrene
exceeding the soil to water MCCs, and concentrations of benzo(a)pyrene and dibenzo(a,h)anthracene
exceeding the residential SCLs.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
ii
Based on this information, the site risk should be classified as high and additional monitoring wells should
be installed downgradient of GMW-2 and GMW-5 across US Highway 15-501 to delineate the extent of
the ground water contamination plume.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
iii

SITE INFORMATION
1. Site Identification
 Mercy Grocery (Facility ID 00-0-00000002143)
 Incident Number 48295 – Undetermined
 Location of Source Area: 1487 US Highway 15-501
Carthage, NC 27410
Moore County (Figures 1 and 2A)
35.362144°N, 79.320503°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System
UST Owner - Table 1 & 2
Tony Poindexter.
2902 Cornwell Drive
Sanford, NC 27332
unknown
unknown

UST Operator – Table 1 & 2
Mr. Yonas Badi
1487 US Highway 15-501
Carthage, NC 28327
[e-mail]
703-956-0354
Property Owner
Mercy LLC
1487 US Highway 15-501
Carthage, NC 28327
[e-mail]
703-956-0354

Property Occupant
Mercy Grocery
1487 US Highway 15-501
Carthage, NC 28327
Unknown
910-947-3463
Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical
449 Springbrook Road
Charlotte, NC 28217
State Certification No. 37735/402
704-529-6364
3. Information about Release
 Release of petroleum from operation of UST(s) currently in use at the site.
 An unknown amount of product was released from the leaking UST System via non-passing UST spill
buckets.
 Two 8,000-gallon gasoline, one 2,000-gallon gasoline and one 1,000-gallon kerosene USTs are currently
in use at the site.

Certification:

I, Samuel L. McKay, III, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice geology and engineering in North Carolina. The
certification numbers of the corporation are C-127 and C-2727, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
iv

ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
TABLE OF CONTENTS

EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1. RISK CHARACTERIZATION .....................................................................................................1
2. RECEPTOR INFORMATION .....................................................................................................3
3. SITE GEOLOGY AND HYDROGEOLOGY ...................................................................................4
4. SITE INVESTIGATION .............................................................................................................5
5. CONCLUSIONS AND RECOMMENDATIONS ............................................................................7
6. LIMITATIONS ........................................................................................................................8

FIGURES
Figure 1: Site Location Map
Figure 2: Site Vicinity Map
Figure 3: Site Map
Figure 4: Ground Water Flow Map
Figure 5: Soil Quality Map
Figure 6: Ground Water Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Receptor Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Soil Sample Analytical Results
Table 7: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: Moore County Property Cards
Appendix B: Well Construction Record and Subsurface Log
Appendix C: NCDEQ Correspondence
Appendix D: Laboratory Analytical Reports – Soil and Ground Water Samples

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
1
1. RISK CHARACTERIZATION
Limited Site Assessment Risk Classification and Land Use Form
Part I – Groundwater/Surface Water/Vapor Impacts
High Risk
1. Has the release contaminated any water supply well including any well used for non-drinking
purposes? UNKNOWN

2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the
release? YES

3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial cooling
water, filling swimming pools) located within 250 feet of the source area of the release?
NO

4. Does ground water within 500 feet of the source area of the release have the potential for future
use (there is no other source of water supply other than the groundwater)? NO

Public water is available to the site and surrounding properties and is provided by the Town of
Carthage.

5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a
confined space or pose any other serious threat to public health, public safety or the
environment?
NO

6. Are there any other factors that would cause the release to pose an imminent danger to public
health, public safety, or the environment? NO
If YES, explain:

Intermediate Risk
7. Is a surface water body located within 500 feet of the source area of the release? NO

If YES, does the maximum groundwater contaminant concentration exceed the surface water
quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10? N/A

8. Is the source area of the release located within an approved or planned wellhead protection area
as defined in 42 USC 300h-7(e)? NO

9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled
“Geology of North Carolina” published by the Department in 1985? YES

10. If YES, is the source area of the release located in an area in which there is recharge to an
unconfined or semi-confined deeper aquifer that is being used or may be used as a source of
drinking water? NO
If YES, describe.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
2
11. Do the levels of ground water contamination for any contaminant exceed the gross contamination
levels established by the Department? NO

No contaminant concentrations reported in the ground water samples collected exceeded the
GCLs.

Part II - Land Use
Property Containing Source Area of Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)? NO
Explain:
The subject property is an active convenience store and petroleum retail facility.

2. Does the property contain a school, daycare center, hospital, playground, park, recreation area,
church, nursing home, or other place of public assembly? NO
Explain:

The subject property is an active convenience store and petroleum retail facility.

3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.) or
industrial (e.g., manufacturing, utilities, industrial research and development,
chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial or industrial
enterprise, or is the land undeveloped? YES
Explain:

The subject property is an active convenience store and petroleum retail facility.

4. Do children visit the property? YES
Explain:

The site is currently a convenience store; children would likely visit the property.

5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security
personnel or both)? NO
Explain:
The property is easily accessible to pedestrian and vehicular traffic.
6. Do pavement, buildings, or other structures cap the contaminated soil? YES
Explain:
The site is currently covered with asphalt and concrete.

If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil
will remain capped in the foreseeable future?
The site is expected to remain in operation as an active convenience store and petroleum retail

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
3
facility in the near future.
7. What is the zoning status of the property?
According to the Moore County Official Zoning Map, the site is zoned B-1 (Business).
8. Is the use of the property likely to change in the next 20 years? NO
Explain:

The subject property is currently an active convenience store and petroleum retail facility and will
likely continue to operate as a convenience store.
Property Surrounding Source Area of Release
The questions below pertain to the area within 1,500 feet of the source area of the release (excludes
property containing source area of the release):

9. What is the distance from the source area of the release to the nearest primary or secondary
residence (permanent or temporary)?

The closest primary residence is located at 1467 US-15-501 and is approximately 100 feet east of
the UST basin.

10. What is the distance from the source area of the release to the nearest school, daycare center,
hospital, playground, park, recreation area, church, nursing home or other place of public
assembly?
Mother Nature Academy, LLC is located at 148 Hill Lane, approximately 3,100 feet south of the
source area at the site.

11. What is the zoning status of properties in the surrounding area?

According to the Moore County Official Zoning Map, the site is zoned for Business use B-1, and
surrounding properties are zoned Rural agricultural (RA) and Industrial (I).

12. Briefly characterize the use and activities of the land in the surrounding area.

The area surrounding the site is used for a mixture of commercial, residential and agricultural
activities.

2. RECEPTOR INFORMATION
1. Water Supply Wells:
A receptor survey was conducted on October 6, 2022. Six water supply wells were identified
within a 1,500-foot radius of the site. Water supply wells WSW-1, WSW-3, and WSW 5 were
determined to be non-potable. No water supply wells were identified within 250 feet of the site.
The closest active water supply well (WSW-4) is located 535 feet northwest of the site. A Site
Location Map is provided as Figure 1 and a Site Vicinity Map showing property boundaries and
surrounding water well locations for the site and surrounding properties has been included as

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
4
Figure 2. Receptor information, keyed to Figure 2 is presented in Table 3.
2. Public Water Supplies:
Are public water supplies available within 1,500 feet of the source area of the release? YES
If yes, where is the location of the nearest public water lines and the source(s) of the public water
supply. Explain:
Municipal water is available to the site and the surrounding properties. Water lines run along the
public streets in the area. Public water is supplied by the Town of Carthage water system PWS ID:
NC0363025.

3. Surface Water:
Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) within 1,500 feet of the
source area of the release. This information must be shown on the USGS topographic map.
No surface water bodies were identified within 500 feet. Ponds are located approximately 900
feet to the northwest, 900 feet to the northeast, 1,000 feet to the southwest, and 1,500 feet
southwest of the site.

4. Wellhead Protection Areas:
Identify all planned or approved wellhead protection areas in the vicinity of the source area. This
information must be shown on the USGS topographic map. Wellhead protection areas are
defined in 42 USC 300h-7(e).
On October 31, 2022, GRI personnel accessed the NCDEQ SWAP Program’s website to identify
wellhead protection areas in the vicinity of the subject site. The site is not located within a
wellhead protection area.

5. Deep Aquifers in the Coastal Plain Physiographic Region:
The site is located in the Coastal Plain Physiographic Region.

6. Subsurface Structures:
No structures with basements were observed in the vicinity of the source area.

7. Property Owners and Occupants:
The names and addresses of the owners of water supply wells and properties adjacent to the site
are presented in Tables 3 and 4 respectively. Property boundaries are shown on Figure 2.
Property cards for the adjacent property owners are attached as Appendix A.

3. SITE GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is located in the undivided surficial
deposits area of the Coastal Plain Physiographic Province. The region is generally described as Cretaceous
age sedimentary deposits overlain by deposits of unconsolidated sediments. The soil samples collected
during well installation activities consisted of a red, brown, and tan clays and silts with fine to coarse
grained sand. A Site Map is included as Figure 3. Well construction and gauging information is presented

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
5
in Table 5. Copies of the well construction record and subsurface log have been included as Appendix B.

On February 16, 2023 depth to ground water was measured from all of the monitoring wells at the site.
Depths to ground water ranged from 3.27 to 4.71 feet below TOC. The ground water elevations ranged
from 95.19 feet to 96.82 feet. Ground water flow was generally to the northwest with a horizontal
gradient of approximately 0.01 feet per foot. A ground water flow map is included as Figure 4. A summary
of the current gauging data is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Groundwater
Elevation
(ft.)
MW-1 15 - 45 45 100 4.22 95.78
GMW-2 5 - 15 15 100.10 4.39 95.71
GMW-3 5 - 15 15 100.32 4.71 95.61
GMW-4 5 - 15 15 100.09 3.27 96.82
GMW-5 5 - 15 15 99.42 4.23 95.19

4. SITE INVESTIGATION
On October 19, 2021, NCDEQ conducted a compliance inspection at the site. Results of the inspection
noted numerous deficiencies, and a NOV was issued October 21, 2021. The NOV noted that records
provided to NCDEQ from 2019 summarizing tightness tests performed on the regular and premium spill
bucket(s) indicated a failing result. Based on this information, NCDEQ requested that a Site Check be
performed. On February 1, 2022, three soil borings were advanced below the spill buckets associated
with premium and two regular USTs to depths of approximately 3 BGS and soil samples were collected
from the borings (PUL-1 RUL-1, and RUL2). TPH concentrations that exceeded the soil RALs were reported
during the February 2022 site check activities.

On October 6, 2022, GRI installed a Type II ground water monitoring well (MW-1) adjacent to the tank
basin at the site. A ground water sample was collected from MW-1 and was submitted to an NC certified
laboratory for analyses of VOCs using EPA Method 6200B + oxygenates, 625 plus 10tics, lead using EPA
Method 6010B, EDB using EPA Method 504.1, and EPH/VPH using the MADEP Method. Ground water
sampling revealed targeted petroleum constituents above the MACs. During the installation of MW-1,
five soil samples (MW-1 (10), MW-1 (20), MW-1 (30), MW-1 (40), and MW-1 (45)) were collected from
the borehole at various depths and were submitted for laboratory analyses of VOCs using EPA Method
8260, EPA Method 8270, MADEP EPH and/or MADEP VPH.

A receptor survey was conducted on October 6, 2022. Six water supply wells were identified within a
1,500-foot radius of the site. Water supply wells WSW-1, WSW-3, and WSW 5 were determined to be
non-potable. No water supply wells were identified within 250 feet of the site. The closest active water
supply well (WSW-4) is located 535 feet northwest of the site.

On January 26, 2023, four additional Type II monitoring wells (GMW-2 though GMW-5) were installed at

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
6
the site. A ground water sample was collected from GMW-2 and was submitted to an NC certified
laboratory for analyses of VOCs using EPA Method 6200B + oxygenates, 625 plus 10tics, lead using EPA
Method 6010B, EDB using EPA Method 504.1, and EPH/VPH using the MADEP Method. Ground water
samples were collected from GMW-3, GMW-4, and GMW-5 and submitted for analyses of VOCs using EPA
Method 6200B + oxygenates, lead using EPA Method 6010B, EDB using EPA Method 504.1, and VPH using
the MADEP Method

During the installation of GMW-2, GMW-3, GMW-4 and GMW-5, a soil sample was collected from each
well bore at a depth of four feet. The soil samples were submitted for analysis of TPH-GRO and TPH-DRO
using UVF technology. The soil sample from GMW-2 (GMW-2-4’) was submitted for additional analysis of
VOCs using EPA Method 8260, EPA Method 8270, MADEP EPH and/or MADEP VPH to gather worst case
risk-based soil results.

Copies of NCDEQ pertinent correspondence are included in Appendix C.

1. Soil Sampling:
Concentrations of benzo(a)anthracene, benzo(b)fluoranthene, ideno(1,2,3-c,d)pyrene and C11-C22
aromatics exceeded the soil to water MCCs and concentrations of benzo(a)pyrene and
dibenzo(a,h)anthracene exceeded the residential SCLs in GMW-2-4’. Outside of the original soil
sampling conducted during site check activities, concentrations of TPH GRO and DRO were not
detected in excess of the RALs in the well boreholes during the LSA. A Soil Quality Map has been
included as Figure 5. A summary of the full soil sample analytical results collected from the Site Check
and LSA investigations is presented in Table 6. A copy of the laboratory reports for the soil samples
collected in October 2022 and January 2023 have been included in Appendix D. An abbreviated
summary of the current soil sampling data collected during the LSA activities is shown below:

Sample ID Sample Depth (ft-BGS) TPH - GRO THH - DRO Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Soil to Water MCC
(mg/kg) 50 100 0.0072 5.4 8 6 0.085 0.2
Residential SCLs (mg/kg) NE NE 12 1,250 60.3 3,120 156 5.5
MW-1-10’ 10 NR NR 0.0007 J <0.0008 <0.0007 <0.0006 <0.0007 0.001 J
MW-1-45’ 45 NR NR <0.0007 <0.0008 <0.0007 <0.0006 0.0009 J <0.001
GMW-2-4’ 4 <10 29.2 <0.0006 <0.0007 <0.0006 <0.0005 <0.0007 <0.001
GMW-3-4’ 4 <10 3.2 NR NR NR NR NR NR
GMW-4-4’ 4 <10 <2 NR NR NR NR NR NR
GMW-5-4’ 4 <10 18.4 NR NR NR NR NR NR

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Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
7

2. Ground Water Sampling:
Concentrations of individual BTEX constituents, naphthalene, TAA, TBA, bromodichloromethane,
Dibromochloromethane, EDB, Isopropylbenzene, n-propylbenzene, styrene, 1,2,4-trmethylbenzene,
1,3,5-trimethylbenzene, C5-C8 aliphatics, C9-C12 aliphatics, and/or C9-C10 aromatics exceeded the
MACs in MW-1, GMW-2, GMW-4 and GMW-5. Measurable amounts of free product were not
detected in any of the gauged and sampled wells. No reported concentrations of targeted petroleum
constituents exceeded the GCLs. A Ground Water Quality Map has been included as Figure 6. A
summary of the ground water analytical data has been included in Table 7. A copy of the laboratory
reports for the ground water samples collected in October 2022 and January 2023 have been included
in Appendix D. An abbreviated summary of the current ground water sampling data is shown below:

Contaminant of
Concern
 Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MAC (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 84,500 85,500 20,000 6,000
MW-1 10.7 0.259 J 1.48 0.891 J 18.2 25.5
GMW-2 67.2 3.68 13.7 24.7 14.9 11.1
GMW-3 <0.180 <0.220 <0.170 0.766 J <0.140 <0.470
GMW-4 0.659 2.73 1.91 8.62 <0.140 <0.470
GMW-5 4,880 8,300 1,880 10,200 1.77 504

3. Quality Control:
All soil and ground water samples were immediately placed in laboratory-supplied containers after
collection, which were then placed in iced coolers. A new disposable bailer was used to sample the
monitoring well and new nitrile gloves were worn during soil and ground water sampling. Samples
were logged using proper chain-of-custody procedures. The samples were transported to a North
Carolina certified laboratory for analysis. A laboratory supplied trip blank was included in the sample
cooler. No detectable concentrations of requested method constituents were reported in the trip
blank.

5. CONCLUSIONS AND RECOMMENDATIONS
 The site is an active convenience store and petroleum retail facility. Land use in the area consists
of business, industrial and agricultural properties.
 A receptor survey was conducted on October 6, 2022. Six water supply wells were identified
within a 1,500-foot radius of the site. Water supply wells WSW-1, WSW-3, and WSW 5 were
determined to be non-potable. No water supply wells were identified within 250 feet of the site.
The closest active water supply well (WSW-4) is located 535 feet northwest of the site. Public
water is available to the subject site and to all surrounding properties.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Limited Site Assessment Report
Prepared on: March 8, 2023 Mercy Grocery
Project Manager: Scott Driscoll GRI Project No. 5947
8
 On October 6, 2022, GRI installed a Type II ground water monitoring well (MW-1) adjacent to the
tank basin at the site. A ground water sample was collected from MW-1 and was submitted to an
NC certified laboratory for analyses of VOCs, SVOCs, Lead and EPH/VPH. Ground water sampling
revealed targeted petroleum constituents above the MACs.
 On January 26, 2023, four additional monitoring wells (GMW-2 through GMW-5) were installed
at the site. Groundwater samples collected from GMW-2 though GMW-5 revealed concentrations
of individual BTEX constituents, naphthalene, TAA, TBA, bromodichloromethane,
Dibromochloromethane, EDB, Isopropylbenzene, n-propylbenzene, styrene, 1,2,4-
trmethylbenzene, and/or 1,3,5-trimethylbenzene exceeding the MACs in GMW-2, GMW-4 and
GMW-5. No reported contaminant concentrations in the ground water samples collected
exceeded the GCLs. Measurable amounts of free product have not been detected at the site.
 Risk based soil samples collected at a depth of four feet from the borehole drilled to install GMW-
2 revealed concentrations of benzo(a)anthracene, benzo(b)fluoranthene and ideno(1,2,3-
c,d)pyrene exceeding the soil to water MCCs, and concentrations of benzo(a)pyrene and
dibenzo(a,h)anthracene exceeding the residential SCLs.
 Based on this information, the site risk should be classified as high and additional monitoring wells
should be installed downgradient of GMW-2 and GMW-5 across US Highway 15-501 to delineate
the extent of the ground water contamination plume.

6. LIMITATIONS
This report has been prepared for the exclusive use of Mercy, LLC. for specific application to the
referenced site in Moore County, North Carolina. The assessment was conducted based on the scope of
work and level of effort specified by NCDEQ and with resources adequate only for that scope of work. Our
findings have been developed in accordance with generally accepted standards of geology and
hydrogeology practices in the State of North Carolina, available information and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site Location Mercy Grocery1487 US Highway 15-501Carthage, North CarolinaMoore CountyIncident No. 48295GRI Project No. 5947500 M2000 FTDate: 10/06/2022Location: 35.362144° N -79.320503° W Dad
"J
"J "J
"J
"J
"J
SITE
950800563219
950800374358
950800571830
950800364196
950800477305
950800474233
950800465864
950800453775
9
5
0
8
0
0
5
7
1
2
6
1
95
080
04
74
055
950800570168
WSW-6
WSW-5
WSW-4
WSW-3WSW-2
WSW-1 US 15-501 HWYBRYANT RDHONEY RD
DENNY LNPLAIN VIEW RD
KELLY RD
CLEGG LN³
FIGURE 2: SITE VICINITY MAPMERCY GROCERY1487 US HIGHWAY 15-501CARTHAGE, MOORE COUNTYNORTH CAROLINAINCIDENT NO. 48295GRI NO. 5947
PREPARED BY:GEOLOGICAL RESOURCES, INC.OCTOBER 5, 2022
0 300150Feet1 inch = 300 feet
1,500-FOOT RADIUS
250-FOOT RADIUS
1,000-FOOT RADIUS
500-FOOT RADIUS
LEGEND
"J Water Supply Well
streets
Rivers/Streams
lakes&rivers
Well Owners and Adjacent Properties
parcels

TABLES
UST ID Number 1-4 Facility ID Number
Owner or Operator?
Owner /Operator
UST ID Number 1 & 2 Facility ID Number
Owner or Operator?
Owner
UST ID Number 3 & 4 Facility ID Number
Owner or Operator?
Owner
Address Telephone Number
2902 Cornwell Drive, Sanford, North Carolina 27332 Unknown
2902 Cornwell Drive, Sanford, North Carolina 27332 Unknown
00-0-0000002143
Name of Owner or Operator Dates of Ownership / Operation
Tony Poindexter 11/01/1972 - 05/31/2018
Address Telephone Number
MERCY LLC 05/31/2018 - Current
Address Telephone Number
1487 US Highway 15-501, Carthage, North Carolina 28327
00-0-0000002143
Name of Owner or Operator Dates of Ownership / Operation
Tony Poindexter 01/01/1984 - 05/31/2018
TABLE 1
UST OWNER/OPERATOR INFORMATION
MERCY GROCERY (INCIDENT NO. 48295)
00-0-0000002143
Name of Owner or Operator Dates of Ownership / Operation
Page 1 of 1
Date: 02/10/22
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline 8,000 1/1/1984 Single Wall Steel 8' x 21' 4"Single Wall FRP Current Yes
2 Gasoline 8,000 1/1/1984 Single Wall Steel 8' x 21' 4"Single Wall FRP Current Yes
3 Gasoline 2,000 11/1/1972 Single Wall Steel 64" x 12'Single Wall FRP Current No
4 Diesel 1,000 11/1/1972 Single Wall Steel 48" x 10'Single Wall FRP Current No
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
TABLE 2
UST SYSTEM INFORMATION
MERCY GROCERY (INCIDENT NO. 48295)
Facility ID #: 00-0-0000002143
UST
ID
No.
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Page 1 of 1
Facility ID # : 0-0002143
Well ID.Parcel ID No.Well Owner Mailing Address Well Address Well Status
(Active/In-Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
WSW-1 9508-0046-6838 Mercy, LLC 1487 US Highway 15 501
Carthage, NC 28327
1467 US Highway 15 501
Carthage, NC 28327 Unknown Non-Potable Yes Yes ~925' NW
WSW-2 9508-0057-0168 Terrence R Erford 605 Bryant Road
Carthage, NC 28327
1421 US Highway 15 501
Carthage, NC 28327 Active Potable Yes No ~635' NW
WSW-3 9508-0057-3127 Anthony C. Troxler Post Office Box 398
Carthage, NC 28327
1403 US Highway 15 501
Carthage, NC 28327 Unknown Non-Potable Yes Yes ~750' NW
WSW-4 9508-0047-7305 Timothy and Tammy Bryant 109 Sullivan Drive
Carthage, NC 28327
1440 US Highway 15 501
Carthage, NC 28327 Active Potable Yes No ~535' NW
WSW-5 9508-0047-2438 Linda Stover Post Office Box 843
Vass, NC 28394
165 Plain View Road
Carthage, NC 28327 Inactive (2)Non-Potable Yes Yes ~540' NW
WSW-6 9508-0045-1882 Isabelle Frye c/o Elizabeth Frye 148 Honey Road
Carthage, NC 28327
148 Honey Road
Carthage, NC 28327 Active Potable Yes No ~1,175' N
Notes:
• Known receptors are shown on Figure 3.
• n/a: not applicable.
Unknown
TABLE 3
RECEPTOR INFORMATION
MERCY GROCERY (INCIDENT NO. 48295)
Date: 10/26/2022
Well Construction Details
(Depth, Screened Interval, Type of Well,
ect.)
Unknown
Unknown
Unknown
Unknown
Unknown
Page 1 of 1
Date: 10/26/2022 Facility ID #: 0-0002143
PIN Number Property Owner Name Property Owner Address
9508-0046-5800 (site)Mercy, LLC 1487 US Highway 15 501
Carthage, NC 28327
9508-0046-6838 Mercy, LLC 1487 US Highway 15 501
Carthage, NC 28327
9508-0056-3219 Terry and Belinda Bryant 111 Bryant Road
Carthage, NC 28327-9639
9508-0037-4358 Robert and Kimbra Reagan 1508 US Highway 15 501
Carthage, NC 28327
9508-0047-4055 Gary Lankford Life Estate 1476 US Highway 15 501
Carthage, NC 28327
Note:
• Properties are keyed to Figure 2.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
MERCY GROCERY (INCIDENT NO. 48295)
Page 1 of 1
Date: 02/17/2023 Facility ID #: 0-0002143
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Free Product
Thickness
(ft.)
Groundwater
Elevation
(ft.)
Comments
10/06/22 35.05 ---64.95
02/02/23 4.85 ---95.15
02/16/23 4.22 ---95.78
01/26/23 NS 5.60 ---NM
02/02/23 NS 4.98 ---NM
02/16/23 100.10 4.39 ---95.71
01/26/23 NS 5.98 ---NM
02/02/23 NS 5.34 ---NM
02/16/23 100.32 4.71 ---95.61
01/26/23 NS 4.19 ---NM
02/02/23 NS 3.71 ---NM
02/16/23 100.09 3.27 ---96.82
01/26/23 NS 8.46 ---NM
02/02/23 NS 4.42 ---NM
02/16/23 99.42 4.23 ---95.19
Notes:
• ft BGS : feet below ground surface.
• NM: Not measured.
• NS: Not surveyed.
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
MERCY GROCERY (INCIDENT NO. 48295)
155 - 155
155 - 155
155 - 155
155 - 155
100.004515 - 4515
01/26/23
01/26/23
01/26/23
01/26/23
10/06/22
GMW-5
GMW-4
GMW-3
GMW-2
MW-1
Page 1 of 1
Date: 02/26/2023 Facility ID #: 0-0002143
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)TPH - GROTPH - DROBenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl-ether (MTBE)NaphthaleneBenzo(a)anthraceneBenzo(b)fluorantheneBenzo(a)pyreneDibenzo(a,h)anthraceneIdeno(1,2,3-c,d)pyreneC5-C8 AliphaticsC9-C12 Aliphatics C9-C10 AromaticsC9-C18 AliphaticsC19-C36 Aliphatics C11-C22 Aromatics50 100 NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE
NE NE 0.0056 4.3 4.9 4.6 0.085 0.2 0.17 0.6 0.058 0.19 1.9 68 540 31 68 540 31
NE NE 18 1,200 1,560 3,129 156 5.5 6.6 6.6 0.66 0.66 6.63 939 1,500 469 939 1,500 469
PUL1 - 3'02/01/22 3 44 40 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
RUL1 - 3'02/01/22 3 713 364 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
RUL2 - 3'02/01/22 3 135 81 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
MW-1-10'10/06/22 10 NR NR 0.0007 J <0.0008 <0.0007 <0.0006 <0.0007 0.001 J <0.159 <0.167 <0.168 <0.263 <0.205 <1.40 <5.22 <0.714 <10.5 <14.0 <16.2
MW-1-20'10/06/22 20 NR NR NR NR NR NR NR NR NR NR NR NR NR <1220 <4560 <624 NR NR NR
MW-1-30'10/06/22 30 NR NR NR NR NR NR NR NR NR NR NR NR NR <1220 <4560 <624 NR NR NR
MW-1-40'10/06/22 40 NR NR NR NR NR NR NR NR NR NR NR NR NR <1220 <4560 <624 NR NR NR
MW-1-45'10/06/22 45 NR NR <0.0007 <0.0008 <0.0007 <0.0006 0.0009 J <0.001 <0.1778 <0.187 <0.189 <0.296 <0.230 <1.57 <5.87 <0.803 <11.9 <15.7 <18.3
GMW-2-4'01/26/23 4 <10 29.2 <0.0006 <0.0007 <0.0006 <0.0005 <0.0007 <0.001 2.57 5.85 3.82 0.737 3.70 <1.29 <4.82 <0.660 <9.71 <12.9 <15.0
GMW-3-4'01/26/23 4 <10 3.2 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
GMW-4-4'01/26/23 4 <10 <2 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
GMW-5-4'01/26/23 4 <10 18.4 NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• ft-BGS: feet below ground surface.
• RAL: Regulatory Action Level.
• MCCs: Maximum Contaminant Concentrations (soils).
• SCLs: Soil Cleanup Levels.
• < : Less than the method detection limit specified in the laboratory report
• Results reported in bold face type indicate the soil to water MCCs are being exceeded.
• Results reported in italics indicate the residential MCss are being exceeded.
• NE: Not Established
• NR: Not Requested.
Residential SCLs (mg/kg)
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Analytical Method MADEP VPH EPHEPA Method 8260B
TABLE 6
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
MERCY GROCERY (INCIDENT NO. 48295)
MADEP VPHTPH by UVF
Page 1 of 1
Date: 02/20/2023
LEAD
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 15,000 NE NE NE
MW-1 10/06/22 10.7 0.259 J 1.48 0.891 J 18.2 25.5 242 138 35 63.7 J 124 J 65
GMW-2 01/26/23 67.2 3.68 13.7 24.7 14.9 11.1 462 206 NR 120 191 111
GMW-3 01/26/23 <0.180 <0.220 <0.170 0.766 J <0.140 <0.470 <1.90 2.55 J NR <11.5 <25.8 <4.02
GMW-4 01/26/23 0.659 2.73 1.91 8.62 <0.140 <0.470 <1.90 NR NR <11.5 59.2 J 11.0 J
GMW-5 01/26/23 4,880 8,300 1,880 10,200 1.77 504 2,060 35.2 NR 7320 11400 6490
10/06/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR NR NR NR NR NR
01/26/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Consentrations of Bromodichloromethane, Dibromochloromethane, EDB, Isopropylbenzene, n-Propylbenzene,
Styrene, 1,2,4-Trimethylbenzene, and/or 1,3,5-Trimethylbenzene exceeded MACs in GMW-2, GMW-4, and GMW-5.
• Results reported in bold face type indicate the concentration exceeded the MAC.
• Results reported in italics indicate the concentration exceeded the GCL.
• J: Estimated value.
• NE: Not established.
• NR: Not reported.
Trip Blank EthylbenzeneTotal XylenesAnalytical Method

GCL (μg/l)
EPA 6200B
• Refer to laboratory report for other detectable concentrations which did not exceed the MAC.tert-Butyl alcohol(TBA)MAC (μg/l)Methyl-tert-butyl ether(MTBE)Naphthalenetert-Amyl alcohol(TAA)Contaminant of Concern
BenzeneTolueneTABLE 7
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
MERCY GROCERY (INCIDENT NO. 48295)
Facility ID #: 0-0002143
C9-C12 AliphaticsC9-C10 AromaticsLeadC5-C8 AliphaticsMADEP VPH
Page 1 of 1

APPENDICES

APPENDIX A
Moore County Property Cards

APPENDIX B
Well Construction Record and Boring Log
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548 A
Geological Resources, Inc.
N/A
4
10/06/22 MW-1
Mercy Grocery 0-0000002143
1487 US Highway 15-501, Carthage, NC
Moore 9508-0046-5800
35.361981 79.320383
4
4
1
45
35.05
6
6" Solid Flight auger
0 15 2"sch 40 PVC
15 45 2"0.010 sch 40 PVC
0 10 grout pour
10 13 bentonite pour
13 45 #2 sand pour
0 0.4 Asphalt
0.4 1 Brown silt
1 6 Tan fine sand
6 8 Tan fine sand
8 13 Brown sandy silt
13 23 Brown silty clay
23 31 Gray clay
31' -33' Tan clay; 33' - 39' Red clay; 39' - 45' Gray/red clay
10/26/2022
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548 A
Geological Resources, Inc.
N/A
4
01/26/2023 GMW-2
Mercy Grocery 0-0000002143
1487 US Highway 15-501, Carthage, NC
Moore 9508-0046-5800
35.361981 79.320383
4
4
1
15
5.60
6
6 Solid Stem auger
0 5 2"sch 40 PVC
5 15 2"0.010 sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 15 #2 sand pour
0 0.5 Asphalt
0.5 7 Light brown fine sand
7 12 Dark brown silty sand
12 15 Light brown sandy clay
01/27/2023
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548 A
Geological Resources, Inc.
N/A
4
01/26/2023 GMW-3
Mercy Grocery 0-0000002143
1487 US Highway 15-501, Carthage, NC
Moore 9508-0046-5800
35.361981 79.320383
4
4
1
15
5.98
6
6 Solid Stem auger
0 5 2"sch 40 PVC
5 15 2"0.010 sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 15 #2 sand pour
0 0.5 Topsoil
0.5 6 Tan fine sand
6 9 Red sandy silt
9 12 Light brown/red silt
12 15 Light brown/red course sandy silt
01/27/2023
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548 A
Geological Resources, Inc.
N/A
4
01/26/2023 GMW-4
Mercy Grocery 0-0000002143
1487 US Highway 15-501, Carthage, NC
Moore 9508-0046-5800
35.361981 79.320383
4
4
1
15
4.19
6
6 Solid Stem auger
0 5 2"sch 40 PVC
5 15 2"0.010 sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 15 #2 sand pour
0 0.5 Topsoil
0.5 7 Tan fine sand
7 12 Red silty sand
12 15 Red sandy clay
01/27/2023
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548 A
Geological Resources, Inc.
N/A
4
01/26/2023 GMW-5
Mercy Grocery 0-0000002143
1487 US Highway 15-501, Carthage, NC
Moore 9508-0046-5800
35.361981 79.320383
4
4
1
15
8.46
6
6 Solid Stem auger
0 5 2"sch 40 PVC
5 15 2"0.010 sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 15 #2 sand pour
0 0.5 Asphalt
0.5 6 Light brown fine sand
6 11 Red silty sand
11 15 Light brown sandy clay
01/27/2023

APPENDIX C
NCDEQ Correspondence

APPENDIX D
Laboratory Report – Soil and Ground Water Samples

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

10/21/2022
Geological Resources, Inc. Scott Driscoll
113 W. Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-280-0004 Client Project Description: Meley Grocery
GRI #5947
Dear Scott Driscoll:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 10/7/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 84
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-280-0004
Page 2 of 84
Report Number:
Sample Summary Table
Client Project Description:
22-280-0004
Meley Grocery
GRI #5947
Lab No Client Sample ID Matrix Date Collected Date Received
10/06/2022 09:27Solids 90146 MW-1 (10')10/07/2022 10:00
10/06/2022 09:40Solids 90147 MW-1 (20')10/07/2022 10:00
10/06/2022 09:54Solids 90148 MW-1 (30')10/07/2022 10:00
10/06/2022 10:09Solids 90149 MW-1 (40')10/07/2022 10:00
10/06/2022 10:22Solids 90150 MW-1 (45')10/07/2022 10:00
10/06/2022 13:02Aqueous 90151 MW-1 10/07/2022 10:00
10/06/2022 08:44Aqueous 90152 Trip Blank 10/07/2022 10:00
Page 3 of 84
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-280-0004
Report Limit
Project:Meley Grocery
V 90146MW-1 (10')
0.107 10/10/2022 16:318260DAcetonemg/Kg - dry 0.002
J0.0007 10/10/2022 16:318260DBenzenemg/Kg - dry 0.0007
J0.001 10/10/2022 16:318260DCarbon Disulfide mg/Kg - dry 0.0007
J0.011 10/10/2022 16:318260DMethyl Ethyl Ketone (MEK)mg/Kg - dry 0.0007
J0.001 10/10/2022 16:318260DNaphthalenemg/Kg - dry 0.001
12.7 10/13/2022 10:00SW-DRYWT Moisture %
V 90150MW-1 (45')
J0.009 10/10/2022 16:588260DAcetonemg/Kg - dry 0.003
J0.0009 10/10/2022 16:588260DMethyl tert-butyl ether (MTBE)mg/Kg - dry 0.0008
22.3 10/13/2022 10:00SW-DRYWT Moisture %
V 90151MW-1
0.035 10/13/2022 18:376010DLeadmg/L 0.012
20.0 10/14/2022 00:346200BAcetoneµg/L 1.80
10.7 10/14/2022 00:346200BBenzeneµg/L 0.180
J0.210 10/14/2022 00:346200Bn-Butylbenzene µg/L 0.180
J0.240 10/14/2022 00:346200Bsec-Butyl benzene µg/L 0.200
6.29 10/14/2022 00:346200BDi-Isopropyl Ether (DIPE)µg/L 0.500
1.48 10/14/2022 00:346200BEthylbenzeneµg/L 0.170
0.762 10/14/2022 00:346200BIsopropylbenzeneµg/L 0.180
J1.31 10/14/2022 00:346200BMethyl Ethyl Ketone (MEK)µg/L 0.710
18.2 10/14/2022 00:346200BMethyl tert-butyl ether (MTBE)µg/L 0.140
25.5 10/14/2022 00:346200BNaphthaleneµg/L 0.470
J0.292 10/14/2022 00:346200Bn-Propylbenzene µg/L 0.190
138 10/14/2022 00:346200Btert-Butyl Alcohol (TBA)µg/L 1.60
242 10/14/2022 17:166200Btert-Amyl Alcohol (TAA)µg/L 19.0
J0.870 10/14/2022 00:346200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
J0.259 10/14/2022 00:346200BTolueneµg/L 0.220
1.12 10/14/2022 00:346200B1,2,4-Trimethylbenzene µg/L 0.190
J0.891 10/14/2022 00:346200Bm,p-Xylene µg/L 0.420
J0.891 10/14/2022 00:346200BXylene (Total)µg/L 0.210
18.8 10/11/2022 16:26625.1 Naphthalene µg/L 8.27
J63.7 10/10/2022 14:22CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J12410/10/2022 14:22CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
65.0 10/10/2022 14:22CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
J89.2 10/11/2022 16:26CALCULATIONAromatic C11-C22 (Adjusted)µg/L 65.9
J10810/13/2022 13:21MADEP-EPH Aromatic C11-C22 µg/L 65.9
Page 4 of 84
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-280-0004
Report Limit
Project:Meley Grocery
V 90151MW-1
74.7 10/10/2022 14:22MADEP-VPH Aliphatic C5-C8 µg/L 11.5
191 10/10/2022 14:22MADEP-VPH Aliphatic C9-C12 µg/L 25.8
65.0 10/10/2022 14:22MADEP-VPH Aromatic C9-C10 µg/L 4.02
Page 5 of 84

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Meley Grocery Lab Report Number: 22-280-0004
Date: 10/21/2022
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 2-Butanone QC Batch No: V25214/V25131
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Ethanol QC Batch No: V25214/V25131
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: tert-Butyl alcohol QC Batch No: V25214/V25131
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: tert-Amyl alcohol QC Batch No: V25214/V25213
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Metals Analysis Method 6010D Sample 90151 (MW-1)
QC Batch No: V25100/V24927 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly. Volatile Organic Compounds - GC/MS Method 8260D Analyte: Acrolein QC Batch No: V24921/V24920
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable. Semivolatile Organic Compounds - GC/MS Method 8270E Sample 90095
Analyte: Benzoic Acid QC Batch No: V25262/V25072
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Sample 90095 Analyte: Hexachlorocyclopentadiene QC Batch No: V25262/V25072 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 6 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
12.7 %Moisture 1 10/13/22 10:00 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
0.107 mg/Kg - dry 0.002 0.022Acetone 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.022Acrolein 1 10/10/22 16:31 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.022Acrylonitrile 1 10/10/22 16:31 V24921TBL
0.0007 J mg/Kg - dry 0.0007 0.005Benzene 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 10/10/22 16:31 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 10/10/22 16:31 V24921TBL
<0.002 mg/Kg - dry 0.002 0.011
Bromomethane 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005n-Butylbenzene 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 10/10/22 16:31 V24921TBL
0.001 J mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 10/10/22 16:31 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.005Chlorobenzene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005
Chlorodibromomethane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.011Chloroethane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 10/10/22 16:31 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 10/10/22 16:31 V24921TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 10/10/22 16:31 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 10/10/22 16:31 V24921TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 10/10/22 16:31 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 10/10/22 16:31 V24921TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,2-Dichlorobenzene 1 10/10/22 16:31 V24921TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 10/10/22 16:31 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 10/10/22 16:31 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005
1,2-Dichloroethane 1 10/10/22 16:31 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 10/10/22 16:31 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 10/10/22 16:31 V24921TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 10/10/22 16:31 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.005
1,1-Dichloropropene 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 10/10/22 16:31 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 10/10/22 16:31 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.005Ethylbenzene 1 10/10/22 16:31 V24921TBL
<0.0010 mg/Kg - dry 0.0010 0.057Ethyl Tertiary Butyl Ether (ETBE)1 10/10/22 16:31 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 10/10/22 16:31 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.011n-Hexane 1 10/10/22 16:31 V24921TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
<0.0007 mg/Kg - dry 0.0007 0.0222-Hexanone 1 10/10/22 16:31 V24921TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 10/10/22 16:31 V24921TBL
0.011 J mg/Kg - dry 0.0007 0.022Methyl Ethyl Ketone (MEK)1 10/10/22 16:31 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 10/10/22 16:31 V24921TBL
<0.017 mg/Kg - dry 0.017 0.0224-Methyl-2-Pentanone 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.011Methylene Chloride 1 10/10/22 16:31 V24921TBL
0.001 J mg/Kg - dry 0.001 0.011Naphthalene 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005
n-Propylbenzene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 10/10/22 16:31 V24921TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005Tetrachloroethene 1 10/10/22 16:31 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.005Toluene 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 10/10/22 16:31 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.011
1,2,4-Trichlorobenzene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 10/10/22 16:31 V24921TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.005Trichloroethene 1 10/10/22 16:31 V24921TBL
<0.002 mg/Kg - dry 0.002 0.011Trichlorofluoromethane 1 10/10/22 16:31 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,2,4-Trimethylbenzene 1 10/10/22 16:31 V24921TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 10/10/22 16:31 V24921TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 10/10/22 16:31 V24921TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Chloride 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005o-Xylene 1 10/10/22 16:31 V24921TBL
<0.001 mg/Kg - dry 0.001 0.011m,p-Xylene 1 10/10/22 16:31 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.005Xylene (Total)1 10/10/22 16:31 V24921KCC
Surrogate: 4-Bromofluorobenzene 99.8 Limits: 70-130%10/10/22 16:311 TBL V24921
Surrogate: Dibromofluoromethane 104 Limits: 84-123%10/10/22 16:311 TBL V24921
Surrogate: Toluene-d8 96.6 Limits: 76-129%10/10/22 16:311 TBL V24921
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.132 mg/Kg - dry 0.132 0.756Acenaphthene 1 10/17/22 22:56 V25262JMV
<0.120 mg/Kg - dry 0.120 0.756Acenaphthylene 1 10/17/22 22:56 V25262JMV
<0.174 mg/Kg - dry 0.174 0.756Aniline 1 10/17/22 22:56 V25262JMV
<0.163 mg/Kg - dry 0.163 0.756Anthracene 1 10/17/22 22:56 V25262JMV
<0.159 mg/Kg - dry 0.159 0.756Benzo(a)anthracene 1 10/17/22 22:56 V25262JMV
<0.168 mg/Kg - dry 0.168 0.756
Benzo(a)pyrene 1 10/17/22 22:56 V25262JMV
<0.167 mg/Kg - dry 0.167 0.756Benzo(b)fluoranthene 1 10/17/22 22:56 V25262JMV
<0.155 mg/Kg - dry 0.155 0.756Benzo(g,h,i)perylene 1 10/17/22 22:56 V25262JMV
<0.156 mg/Kg - dry 0.156 0.756Benzo(k)fluoranthene 1 10/17/22 22:56 V25262JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.664 mg/Kg - dry 0.664 2.29Benzoic Acid 1 10/17/22 22:56 V25262JMV
<0.120 mg/Kg - dry 0.120 0.756Benzyl alcohol 1 10/17/22 22:56 V25262JMV
<0.135 mg/Kg - dry 0.135 0.756Bis(2-Chloroethoxy)methane 1 10/17/22 22:56 V25262JMV
<0.122 mg/Kg - dry 0.122 0.756Bis(2-Chloroethyl)ether 1 10/17/22 22:56 V25262JMV
<0.155 mg/Kg - dry 0.155 0.378Bis(2-Chloroisopropyl)ether 1 10/17/22 22:56 V25262JMV
<0.137 mg/Kg - dry 0.137 0.756Bis(2-ethylhexyl)phthalate 1 10/17/22 22:56 V25262JMV
<0.124 mg/Kg - dry 0.124 0.7564-Bromophenyl phenyl ether 1 10/17/22 22:56 V25262JMV
<0.129 mg/Kg - dry 0.129 0.378Butyl benzyl phthalate 1 10/17/22 22:56 V25262JMV
<0.105 mg/Kg - dry 0.105 0.756
4-Chloro-3-methylphenol 1 10/17/22 22:56 V25262JMV
<0.128 mg/Kg - dry 0.128 0.3784-Chloroaniline 1 10/17/22 22:56 V25262JMV
<0.132 mg/Kg - dry 0.132 0.7562-Chloronaphthalene 1 10/17/22 22:56 V25262JMV
<0.112 mg/Kg - dry 0.112 0.7562-Chlorophenol 1 10/17/22 22:56 V25262JMV
<0.144 mg/Kg - dry 0.144 1.154-Chlorophenyl phenyl ether 1 10/17/22 22:56 V25262JMV
<0.162 mg/Kg - dry 0.162 0.756Chrysene 1 10/17/22 22:56 V25262JMV
<0.263 mg/Kg - dry 0.263 0.756Dibenz(a,h)anthracene 1 10/17/22 22:56 V25262JMV
<0.136 mg/Kg - dry 0.136 0.756
Dibenzofuran 1 10/17/22 22:56 V25262JMV
<0.108 mg/Kg - dry 0.108 0.7561,2-Dichlorobenzene 1 10/17/22 22:56 V25262JMV
<0.111 mg/Kg - dry 0.111 0.7561,3-Dichlorobenzene 1 10/17/22 22:56 V25262JMV
<0.111 mg/Kg - dry 0.111 0.3781,4-Dichlorobenzene 1 10/17/22 22:56 V25262JMV
<0.168 mg/Kg - dry 0.168 0.7563,3'-Dichlorobenzidine 1 10/17/22 22:56 V25262JMV
<0.109 mg/Kg - dry 0.109 0.7562,4-Dichlorophenol 1 10/17/22 22:56 V25262JMV
<0.206 mg/Kg - dry 0.206 0.756Diethyl phthalate 1 10/17/22 22:56 V25262JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.199 mg/Kg - dry 0.199 0.756Dimethyl phthalate 1 10/17/22 22:56 V25262JMV
<0.123 mg/Kg - dry 0.123 0.3782,4-Dimethylphenol 1 10/17/22 22:56 V25262JMV
<0.122 mg/Kg - dry 0.122 0.756Di-n-butyl phthalate 1 10/17/22 22:56 V25262JMV
<0.274 mg/Kg - dry 0.274 1.724,6-Dinitro-2-methylphenol 1 10/17/22 22:56 V25262JMV
<0.595 mg/Kg - dry 0.595 1.722,4-Dinitrophenol 1 10/17/22 22:56 V25262JMV
<0.110 mg/Kg - dry 0.110 0.7562,4-Dinitrotoluene 1 10/17/22 22:56 V25262JMV
<0.123 mg/Kg - dry 0.123 0.7562,6-Dinitrotoluene 1 10/17/22 22:56 V25262JMV
<0.163 mg/Kg - dry 0.163 0.378Di-n-Octyl Phthalate 1 10/17/22 22:56 V25262JMV
<0.140 mg/Kg - dry 0.140 0.756
Fluoranthene 1 10/17/22 22:56 V25262JMV
<0.146 mg/Kg - dry 0.146 0.756Fluorene 1 10/17/22 22:56 V25262JMV
<0.121 mg/Kg - dry 0.121 0.756Hexachlorobenzene 1 10/17/22 22:56 V25262JMV
<0.111 mg/Kg - dry 0.111 0.756Hexachlorobutadiene 1 10/17/22 22:56 V25262JMV
<0.179 mg/Kg - dry 0.179 0.756Hexachlorocyclopentadiene 1 10/17/22 22:56 V25262JMV
<0.090 mg/Kg - dry 0.090 0.756Hexachloroethane 1 10/17/22 22:56 V25262JMV
<0.205 mg/Kg - dry 0.205 0.756Indeno(1,2,3-cd)pyrene 1 10/17/22 22:56 V25262JMV
<0.218 mg/Kg - dry 0.218 0.756
Isophorone 1 10/17/22 22:56 V25262JMV
<0.121 mg/Kg - dry 0.121 0.7561-Methylnaphthalene 1 10/17/22 22:56 V25262JMV
<0.114 mg/Kg - dry 0.114 0.7562-Methylnaphthalene 1 10/17/22 22:56 V25262JMV
<0.111 mg/Kg - dry 0.111 0.7562-Methylphenol 1 10/17/22 22:56 V25262JMV
<0.097 mg/Kg - dry 0.097 0.7563&4 Methylphenol 1 10/17/22 22:56 V25262JMV
<0.164 mg/Kg - dry 0.164 0.756Naphthalene 1 10/17/22 22:56 V25262JMV
<0.110 mg/Kg - dry 0.110 0.7562-Nitroaniline 1 10/17/22 22:56 V25262JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.137 mg/Kg - dry 0.137 0.7563-Nitroaniline 1 10/17/22 22:56 V25262JMV
<0.106 mg/Kg - dry 0.106 0.3784-Nitroaniline 1 10/17/22 22:56 V25262JMV
<0.132 mg/Kg - dry 0.132 0.378Nitrobenzene 1 10/17/22 22:56 V25262JMV
<0.101 mg/Kg - dry 0.101 0.7562-Nitrophenol 1 10/17/22 22:56 V25262JMV
<0.134 mg/Kg - dry 0.134 0.7564-Nitrophenol 1 10/17/22 22:56 V25262JMV
<0.301 mg/Kg - dry 0.301 0.756N-Nitrosodimethylamine 1 10/17/22 22:56 V25262JMV
<0.207 mg/Kg - dry 0.207 0.756N-Nitrosodiphenylamine 1 10/17/22 22:56 V25262JMV
<0.135 mg/Kg - dry 0.135 0.756N-Nitroso-di-n-propylamine 1 10/17/22 22:56 V25262JMV
<0.397 mg/Kg - dry 0.397 1.15
Pentachlorophenol 1 10/17/22 22:56 V25262JMV
<0.238 mg/Kg - dry 0.238 0.756Phenanthrene 1 10/17/22 22:56 V25262JMV
<0.128 mg/Kg - dry 0.128 0.756Phenol 1 10/17/22 22:56 V25262JMV
<0.153 mg/Kg - dry 0.153 0.756Pyrene 1 10/17/22 22:56 V25262JMV
<0.090 mg/Kg - dry 0.090 0.378Pyridine 1 10/17/22 22:56 V25262JMV
<0.122 mg/Kg - dry 0.122 0.7561,2,4-Trichlorobenzene 1 10/17/22 22:56 V25262JMV
<0.110 mg/Kg - dry 0.110 0.7562,4,5-Trichlorophenol 1 10/17/22 22:56 V25262JMV
<0.110 mg/Kg - dry 0.110 0.756
2,4,6-Trichlorophenol 1 10/17/22 22:56 V25262JMV
8270ESurrogate: Phenol-d5 93.4 Limits: 34-121%10/17/22 22:561 JMV
Surrogate: 2-Fluorobiphenyl 99.4 Limits: 44-115%10/17/22 22:561 JMV V25262
Surrogate: 2-Fluorophenol 95.2 Limits: 35-115%10/17/22 22:561 JMV V25262
Surrogate: Nitrobenzene-d5 85.6 Limits: 37-122%10/17/22 22:561 JMV V25262
Surrogate: 4-Terphenyl-d14 104 Limits: 54-127%10/17/22 22:561 JMV V25262
Surrogate: 2,4,6-Tribromophenol 111 Limits: 39-132%10/17/22 22:561 JMV V25262
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.40 mg/Kg - dry 1.40 9.16Aliphatic C5-C8 (Adjusted)100 10/10/22 17:08
<5.22 mg/Kg - dry 5.22 9.16Aliphatics C9-C12 (Adjusted)1 10/10/22 16:31
<0.714 mg/Kg - dry 0.714 9.16Aromatic C9-C10 (Adjusted)100 10/10/22 17:08
<16.2 mg/Kg - dry 16.2 57.0Aromatic C11-C22 (Adjusted)1 10/13/22 18:49
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V25038 10/12/22 10:55
<10.5 mg/Kg - dry 10.5 57.0Aliphatic C9-C18 1 10/13/22 18:49 V25109JLK
<14.0 mg/Kg - dry 14.0 57.0Aliphatic C19-C36 1 10/13/22 18:49 V25109JLK
<16.2 mg/Kg - dry 16.2 57.0Aromatic C11-C22 1 10/13/22 18:49 V25109JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 117 Limits: 40-140%10/13/22 18:491
MADEP-EPHSurrogate: Chlorooctadecane 80.4 Limits: 40-140%10/13/22 18:491 JLK
MADEP-EPHSurrogate: OTP Surrogate 87.4 Limits: 40-140%10/13/22 18:491 JLK
Surrogate: 2-Fluorobiphenyl 114 Limits: 40-140%10/13/22 18:491 JLK V25109
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24915 10/10/22 08:00
<1.40 mg/Kg - dry 1.40 9.16Aliphatic C5-C8 100 10/10/22 17:08 V24916TBL
<5.22 mg/Kg - dry 5.22 9.16Aliphatic C9-C12 100 10/10/22 17:08 V24916TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (10')
90146 Matrix:
10/6/2022 9:27
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24915 10/10/22 08:00
<0.714 mg/Kg - dry 0.714 9.16Aromatic C9-C10 100 10/10/22 17:08 V24916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)77.2 Limits: 70-130%10/10/22 17:08100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.7 Limits: 70-130%10/10/22 17:08100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (20')
90147 Matrix:
10/6/2022 9:40
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24915 10/10/22 08:00
<1220 µg/Kg 1220 8000Aliphatic C5-C8 100 10/10/22 17:32 V24916TBL
<4560 µg/Kg 4560 8000Aliphatic C9-C12 100 10/10/22 17:32 V24916TBL
<624 µg/Kg 624 8000Aromatic C9-C10 100 10/10/22 17:32 V24916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)86.5 Limits: 70-130%10/10/22 17:32100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)93.4 Limits: 70-130%10/10/22 17:32100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (30')
90148 Matrix:
10/6/2022 9:54
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24915 10/10/22 08:00
<1220 µg/Kg 1220 8000Aliphatic C5-C8 100 10/10/22 17:56 V24916TBL
<4560 µg/Kg 4560 8000Aliphatic C9-C12 100 10/10/22 17:56 V24916TBL
<624 µg/Kg 624 8000Aromatic C9-C10 100 10/10/22 17:56 V24916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)102 Limits: 70-130%10/10/22 17:56100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)109 Limits: 70-130%10/10/22 17:56100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (40')
90149 Matrix:
10/6/2022 10:09
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24915 10/10/22 08:00
<1220 µg/Kg 1220 8000Aliphatic C5-C8 100 10/10/22 18:20 V24916TBL
<4560 µg/Kg 4560 8000Aliphatic C9-C12 100 10/10/22 18:20 V24916TBL
<624 µg/Kg 624 8000Aromatic C9-C10 100 10/10/22 18:20 V24916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)77.3 Limits: 70-130%10/10/22 18:20100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)84.3 Limits: 70-130%10/10/22 18:20100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
22.3 %Moisture 1 10/13/22 10:00 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
0.009 J mg/Kg - dry 0.003 0.025Acetone 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.025Acrolein 1 10/10/22 16:58 V24921TBL
<0.0010 mg/Kg - dry 0.0010 0.025Acrylonitrile 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.006Benzene 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.006Bromobenzene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006Bromochloromethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006Bromodichloromethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006Bromoform 1 10/10/22 16:58 V24921TBL
<0.002 mg/Kg - dry 0.002 0.012
Bromomethane 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.006n-Butylbenzene 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.006sec-Butyl benzene 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.006tert-Butyl benzene 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.006Carbon Disulfide 1 10/10/22 16:58 V24921TBL
<0.002 mg/Kg - dry 0.002 0.006Carbon Tetrachloride 1 10/10/22 16:58 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.006Chlorobenzene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006
Chlorodibromomethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.012Chloroethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006Chloroform 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.012Chloromethane 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.0062-Chlorotoluene 1 10/10/22 16:58 V24921TBL
<0.0005 mg/Kg - dry 0.0005 0.0064-Chlorotoluene 1 10/10/22 16:58 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.006Di-Isopropyl Ether (DIPE)1 10/10/22 16:58 V24921TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
<0.0006 mg/Kg - dry 0.0006 0.0121,2-Dibromo-3-Chloropropane 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,2-Dibromoethane 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.006Dibromomethane 1 10/10/22 16:58 V24921TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,2-Dichlorobenzene 1 10/10/22 16:58 V24921TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,3-Dichlorobenzene 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.0061,4-Dichlorobenzene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.012Dichlorodifluoromethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloroethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006
1,2-Dichloroethane 1 10/10/22 16:58 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,1-Dichloroethene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006cis-1,2-Dichloroethene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,2-Dichloroethene 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2-Dichloropropane 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3-Dichloropropane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0062,2-Dichloropropane 1 10/10/22 16:58 V24921TBL
<0.0010 mg/Kg - dry 0.0010 0.006
1,1-Dichloropropene 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.006cis-1,3-Dichloropropene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,3-Dichloropropene 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.006Ethylbenzene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.064Ethyl Tertiary Butyl Ether (ETBE)1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.012Hexachlorobutadiene 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.012n-Hexane 1 10/10/22 16:58 V24921TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
<0.0008 mg/Kg - dry 0.0008 0.0252-Hexanone 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.006Isopropylbenzene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0064-Isopropyl toluene 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.025Methyl Ethyl Ketone (MEK)1 10/10/22 16:58 V24921TBL
0.0009 J mg/Kg - dry 0.0008 0.006Methyl tert-butyl ether (MTBE)1 10/10/22 16:58 V24921TBL
<0.019 mg/Kg - dry 0.019 0.0254-Methyl-2-Pentanone 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.012Methylene Chloride 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.012Naphthalene 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.006
n-Propylbenzene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006Styrene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1,2-Tetrachloroethane 1 10/10/22 16:58 V24921TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,1,2,2-Tetrachloroethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006Tetrachloroethene 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.006Toluene 1 10/10/22 16:58 V24921TBL
<0.0007 mg/Kg - dry 0.0007 0.0121,2,3-Trichlorobenzene 1 10/10/22 16:58 V24921TBL
<0.0008 mg/Kg - dry 0.0008 0.012
1,2,4-Trichlorobenzene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1-Trichloroethane 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,1,2-Trichloroethane 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.006Trichloroethene 1 10/10/22 16:58 V24921TBL
<0.002 mg/Kg - dry 0.002 0.012Trichlorofluoromethane 1 10/10/22 16:58 V24921TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,2,3-Trichloropropane 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,2,4-Trimethylbenzene 1 10/10/22 16:58 V24921TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V24920 10/10/22 08:00
<0.0007 mg/Kg - dry 0.0007 0.0061,3,5-Trimethylbenzene 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Acetate 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Chloride 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.006o-Xylene 1 10/10/22 16:58 V24921TBL
<0.001 mg/Kg - dry 0.001 0.012m,p-Xylene 1 10/10/22 16:58 V24921TBL
<0.0006 mg/Kg - dry 0.0006 0.006Xylene (Total)1 10/10/22 16:58 V24921
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%10/10/22 16:581 TBL V24921
Surrogate: Dibromofluoromethane 100 Limits: 84-123%10/10/22 16:581 TBL V24921
Surrogate: Toluene-d8 95.3 Limits: 76-129%10/10/22 16:581 TBL V24921
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.149 mg/Kg - dry 0.149 0.850Acenaphthene 1 10/17/22 23:19 V25262JMV
<0.135 mg/Kg - dry 0.135 0.850Acenaphthylene 1 10/17/22 23:19 V25262JMV
<0.195 mg/Kg - dry 0.195 0.850Aniline 1 10/17/22 23:19 V25262JMV
<0.184 mg/Kg - dry 0.184 0.850Anthracene 1 10/17/22 23:19 V25262JMV
<0.178 mg/Kg - dry 0.178 0.850Benzo(a)anthracene 1 10/17/22 23:19 V25262JMV
<0.189 mg/Kg - dry 0.189 0.850
Benzo(a)pyrene 1 10/17/22 23:19 V25262JMV
<0.187 mg/Kg - dry 0.187 0.850Benzo(b)fluoranthene 1 10/17/22 23:19 V25262JMV
<0.175 mg/Kg - dry 0.175 0.850Benzo(g,h,i)perylene 1 10/17/22 23:19 V25262JMV
<0.176 mg/Kg - dry 0.176 0.850Benzo(k)fluoranthene 1 10/17/22 23:19 V25262JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.746 mg/Kg - dry 0.746 2.57Benzoic Acid 1 10/17/22 23:19 V25262JMV
<0.135 mg/Kg - dry 0.135 0.850Benzyl alcohol 1 10/17/22 23:19 V25262JMV
<0.151 mg/Kg - dry 0.151 0.850Bis(2-Chloroethoxy)methane 1 10/17/22 23:19 V25262JMV
<0.137 mg/Kg - dry 0.137 0.850Bis(2-Chloroethyl)ether 1 10/17/22 23:19 V25262JMV
<0.175 mg/Kg - dry 0.175 0.424Bis(2-Chloroisopropyl)ether 1 10/17/22 23:19 V25262JMV
<0.154 mg/Kg - dry 0.154 0.850Bis(2-ethylhexyl)phthalate 1 10/17/22 23:19 V25262JMV
<0.140 mg/Kg - dry 0.140 0.8504-Bromophenyl phenyl ether 1 10/17/22 23:19 V25262JMV
<0.145 mg/Kg - dry 0.145 0.424Butyl benzyl phthalate 1 10/17/22 23:19 V25262JMV
<0.119 mg/Kg - dry 0.119 0.850
4-Chloro-3-methylphenol 1 10/17/22 23:19 V25262JMV
<0.144 mg/Kg - dry 0.144 0.4244-Chloroaniline 1 10/17/22 23:19 V25262JMV
<0.149 mg/Kg - dry 0.149 0.8502-Chloronaphthalene 1 10/17/22 23:19 V25262JMV
<0.126 mg/Kg - dry 0.126 0.8502-Chlorophenol 1 10/17/22 23:19 V25262JMV
<0.162 mg/Kg - dry 0.162 1.294-Chlorophenyl phenyl ether 1 10/17/22 23:19 V25262JMV
<0.182 mg/Kg - dry 0.182 0.850Chrysene 1 10/17/22 23:19 V25262JMV
<0.296 mg/Kg - dry 0.296 0.850Dibenz(a,h)anthracene 1 10/17/22 23:19 V25262JMV
<0.153 mg/Kg - dry 0.153 0.850
Dibenzofuran 1 10/17/22 23:19 V25262JMV
<0.121 mg/Kg - dry 0.121 0.8501,2-Dichlorobenzene 1 10/17/22 23:19 V25262JMV
<0.125 mg/Kg - dry 0.125 0.8501,3-Dichlorobenzene 1 10/17/22 23:19 V25262JMV
<0.125 mg/Kg - dry 0.125 0.4241,4-Dichlorobenzene 1 10/17/22 23:19 V25262JMV
<0.189 mg/Kg - dry 0.189 0.8503,3'-Dichlorobenzidine 1 10/17/22 23:19 V25262JMV
<0.123 mg/Kg - dry 0.123 0.8502,4-Dichlorophenol 1 10/17/22 23:19 V25262JMV
<0.231 mg/Kg - dry 0.231 0.850Diethyl phthalate 1 10/17/22 23:19 V25262JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.223 mg/Kg - dry 0.223 0.850Dimethyl phthalate 1 10/17/22 23:19 V25262JMV
<0.138 mg/Kg - dry 0.138 0.4242,4-Dimethylphenol 1 10/17/22 23:19 V25262JMV
<0.137 mg/Kg - dry 0.137 0.850Di-n-butyl phthalate 1 10/17/22 23:19 V25262JMV
<0.308 mg/Kg - dry 0.308 1.934,6-Dinitro-2-methylphenol 1 10/17/22 23:19 V25262JMV
<0.669 mg/Kg - dry 0.669 1.932,4-Dinitrophenol 1 10/17/22 23:19 V25262JMV
<0.124 mg/Kg - dry 0.124 0.8502,4-Dinitrotoluene 1 10/17/22 23:19 V25262JMV
<0.138 mg/Kg - dry 0.138 0.8502,6-Dinitrotoluene 1 10/17/22 23:19 V25262JMV
<0.184 mg/Kg - dry 0.184 0.424Di-n-Octyl Phthalate 1 10/17/22 23:19 V25262JMV
<0.158 mg/Kg - dry 0.158 0.850
Fluoranthene 1 10/17/22 23:19 V25262JMV
<0.164 mg/Kg - dry 0.164 0.850Fluorene 1 10/17/22 23:19 V25262JMV
<0.136 mg/Kg - dry 0.136 0.850Hexachlorobenzene 1 10/17/22 23:19 V25262JMV
<0.125 mg/Kg - dry 0.125 0.850Hexachlorobutadiene 1 10/17/22 23:19 V25262JMV
<0.202 mg/Kg - dry 0.202 0.850Hexachlorocyclopentadiene 1 10/17/22 23:19 V25262JMV
<0.102 mg/Kg - dry 0.102 0.850Hexachloroethane 1 10/17/22 23:19 V25262JMV
<0.230 mg/Kg - dry 0.230 0.850Indeno(1,2,3-cd)pyrene 1 10/17/22 23:19 V25262JMV
<0.245 mg/Kg - dry 0.245 0.850
Isophorone 1 10/17/22 23:19 V25262JMV
<0.136 mg/Kg - dry 0.136 0.8501-Methylnaphthalene 1 10/17/22 23:19 V25262JMV
<0.128 mg/Kg - dry 0.128 0.8502-Methylnaphthalene 1 10/17/22 23:19 V25262JMV
<0.124 mg/Kg - dry 0.124 0.8502-Methylphenol 1 10/17/22 23:19 V25262JMV
<0.109 mg/Kg - dry 0.109 0.8503&4 Methylphenol 1 10/17/22 23:19 V25262JMV
<0.185 mg/Kg - dry 0.185 0.850Naphthalene 1 10/17/22 23:19 V25262JMV
<0.124 mg/Kg - dry 0.124 0.8502-Nitroaniline 1 10/17/22 23:19 V25262JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V25072 10/13/22 10:30
<0.154 mg/Kg - dry 0.154 0.8503-Nitroaniline 1 10/17/22 23:19 V25262JMV
<0.120 mg/Kg - dry 0.120 0.4244-Nitroaniline 1 10/17/22 23:19 V25262JMV
<0.149 mg/Kg - dry 0.149 0.424Nitrobenzene 1 10/17/22 23:19 V25262JMV
<0.114 mg/Kg - dry 0.114 0.8502-Nitrophenol 1 10/17/22 23:19 V25262JMV
<0.150 mg/Kg - dry 0.150 0.8504-Nitrophenol 1 10/17/22 23:19 V25262JMV
<0.338 mg/Kg - dry 0.338 0.850N-Nitrosodimethylamine 1 10/17/22 23:19 V25262JMV
<0.232 mg/Kg - dry 0.232 0.850N-Nitrosodiphenylamine 1 10/17/22 23:19 V25262JMV
<0.151 mg/Kg - dry 0.151 0.850N-Nitroso-di-n-propylamine 1 10/17/22 23:19 V25262JMV
<0.446 mg/Kg - dry 0.446 1.29
Pentachlorophenol 1 10/17/22 23:19 V25262JMV
<0.267 mg/Kg - dry 0.267 0.850Phenanthrene 1 10/17/22 23:19 V25262JMV
<0.144 mg/Kg - dry 0.144 0.850Phenol 1 10/17/22 23:19 V25262JMV
<0.172 mg/Kg - dry 0.172 0.850Pyrene 1 10/17/22 23:19 V25262JMV
<0.101 mg/Kg - dry 0.101 0.424Pyridine 1 10/17/22 23:19 V25262JMV
<0.137 mg/Kg - dry 0.137 0.8501,2,4-Trichlorobenzene 1 10/17/22 23:19 V25262JMV
<0.123 mg/Kg - dry 0.123 0.8502,4,5-Trichlorophenol 1 10/17/22 23:19 V25262JMV
<0.124 mg/Kg - dry 0.124 0.850
2,4,6-Trichlorophenol 1 10/17/22 23:19 V25262JMV
8270ESurrogate: Phenol-d5 91.6 Limits: 34-121%10/17/22 23:191 JMV
Surrogate: 2-Fluorobiphenyl 94.6 Limits: 44-115%10/17/22 23:191 JMV V25262
Surrogate: 2-Fluorophenol 96.7 Limits: 35-115%10/17/22 23:191 JMV V25262
Surrogate: Nitrobenzene-d5 83.2 Limits: 37-122%10/17/22 23:191 JMV V25262
Surrogate: 4-Terphenyl-d14 101 Limits: 54-127%10/17/22 23:191 JMV V25262
Surrogate: 2,4,6-Tribromophenol 103 Limits: 39-132%10/17/22 23:191 JMV V25262
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.57 mg/Kg - dry 1.57 10.3Aliphatic C5-C8 (Adjusted)1 10/10/22 16:58
<5.87 mg/Kg - dry 5.87 10.3Aliphatics C9-C12 (Adjusted)1 10/10/22 16:58
<0.803 mg/Kg - dry 0.803 10.3Aromatic C9-C10 (Adjusted)100 10/10/22 18:43
<18.3 mg/Kg - dry 18.3 64.5Aromatic C11-C22 (Adjusted)1 10/13/22 19:25
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V25038 10/12/22 10:55
<11.9 mg/Kg - dry 11.9 64.5Aliphatic C9-C18 1 10/13/22 19:25 V25109JLK
<15.7 mg/Kg - dry 15.7 64.5Aliphatic C19-C36 1 10/13/22 19:25 V25109JLK
<18.3 mg/Kg - dry 18.3 64.5Aromatic C11-C22 1 10/13/22 19:25 V25109JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 109 Limits: 40-140%10/13/22 19:251 JLK
MADEP-EPHSurrogate: Chlorooctadecane 81.0 Limits: 40-140%10/13/22 19:251 JLK
MADEP-EPHSurrogate: OTP Surrogate 87.0 Limits: 40-140%10/13/22 19:251 JLK
Surrogate: 2-Fluorobiphenyl 107 Limits: 40-140%10/13/22 19:251 JLK V25109
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24915 10/10/22 08:00
<1.57 mg/Kg - dry 1.57 10.3Aliphatic C5-C8 100 10/10/22 18:43 V24916TBL
<5.87 mg/Kg - dry 5.87 10.3Aliphatic C9-C12 100 10/10/22 18:43 V24916TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1 (45')
90150 Matrix:
10/6/2022 10:22
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24915 10/10/22 08:00
<0.803 mg/Kg - dry 0.803 10.3Aromatic C9-C10 100 10/10/22 18:43 V24916TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)77.6 Limits: 70-130%10/10/22 18:43100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)87.4 Limits: 70-130%10/10/22 18:43100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 10/14/22 00:34 6200BMSA
0.035 mg/L 0.012 0.030Lead 5 10/13/22 18:37 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00 V25213 10/14/22 09:00
20.0 µg/L 1.80 10.0Acetone 1 10/14/22 00:34 V25132MSA
10.7 µg/L 0.180 0.500Benzene 1 10/14/22 00:34 V25132MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/14/22 00:34 V25132MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/14/22 00:34 V25132MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/14/22 00:34 V25132MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/14/22 00:34 V25132MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/14/22 00:34 V25132MSA
0.210 J µg/L 0.180 0.500n-Butylbenzene 1 10/14/22 00:34 V25132MSA
0.240 J
µg/L 0.200 0.500
sec-Butyl benzene 1 10/14/22 00:34 V25132MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/14/22 00:34 V25132MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/14/22 00:34 V25132MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/14/22 00:34 V25132MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/14/22 00:34 V25132MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/14/22 00:34 V25132MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/14/22 00:34 V25132MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/14/22 00:34 V25132MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/14/22 00:34 V25132MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/14/22 00:34 V25132MSA
6.29 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/14/22 00:34 V25132MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/14/22 00:34 V25132MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/14/22 00:34 V25132MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/14/22 00:34 V25132MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00 V25213 10/14/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/14/22 00:34 V25132MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/14/22 00:34 V25132MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/14/22 00:34 V25132MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/14/22 00:34 V25132MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/14/22 00:34 V25132MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/14/22 00:34 V25132MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/14/22 00:34 V25132MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 10/14/22 00:34 V25132MSA
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 10/14/22 00:34 V25132MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/14/22 00:34 V25132MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/14/22 00:34 V25132MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/14/22 00:34 V25132MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/14/22 00:34 V25132MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/14/22 00:34 V25132MSA
<42.0 µg/L 42.0 200Ethanol 1 10/14/22 00:34 V25132MSA
1.48 µg/L 0.170 0.500
Ethylbenzene 1 10/14/22 00:34 V25132MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/14/22 00:34 V25132MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/14/22 00:34 V25132MSA
0.762 µg/L 0.180 0.500Isopropylbenzene 1 10/14/22 00:34 V25132MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/14/22 00:34 V25132MSA
1.31 J µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/14/22 00:34 V25132MSA
18.2 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/14/22 00:34 V25132MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00 V25213 10/14/22 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/14/22 00:34 V25132MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/14/22 00:34 V25132MSA
25.5 µg/L 0.470 1.00Naphthalene 1 10/14/22 00:34 V25132MSA
0.292 J µg/L 0.190 0.500n-Propylbenzene 1 10/14/22 00:34 V25132MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/14/22 00:34 V25132MSA
138 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 10/14/22 00:34 V25132MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 10/14/22 00:34 V25132MSA
242 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 10/14/22 17:16 V25214MSA
0.870 J
µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 10/14/22 00:34 V25132MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/14/22 00:34 V25132MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/14/22 00:34 V25132MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 10/14/22 00:34 V25132MSA
0.259 J µg/L 0.220 0.500Toluene 1 10/14/22 00:34 V25132MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/14/22 00:34 V25132MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/14/22 00:34 V25132MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/14/22 00:34 V25132MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/14/22 00:34 V25132MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/14/22 00:34 V25132MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 10/14/22 00:34 V25132MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/14/22 00:34 V25132MSA
1.12 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/14/22 00:34 V25132MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/14/22 00:34 V25132MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00 V25213 10/14/22 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/14/22 00:34 V25132MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/14/22 00:34 V25132MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/14/22 00:34 V25132MSA
0.891 J µg/L 0.420 1.00m,p-Xylene 1 10/14/22 00:34 V25132MSA
0.891 J µg/L 0.210 0.500Xylene (Total)1 10/14/22 00:34 V25132KCC
Surrogate: 4-Bromofluorobenzene 98.4 Limits: 70-130%10/14/22 00:341 MSA V25132
Surrogate: Dibromofluoromethane 96.8 Limits: 70-130%10/14/22 00:341 MSA V25132
Surrogate: 1,2-Dichloroethane - d4 98.4 Limits: 70-130%10/14/22 00:341 MSA V25132
Surrogate: Toluene-d8 102 Limits: 70-130%10/14/22 00:341 MSA V25132
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%10/14/22 17:1610 MSA V25214
Surrogate: Dibromofluoromethane 107 Limits: 70-130%10/14/22 17:1610 MSA V25214
Surrogate: 1,2-Dichloroethane - d4 98.2 Limits: 70-130%10/14/22 17:1610 MSA V25214
Surrogate: Toluene-d8 98.8 Limits: 70-130%10/14/22 17:1610 MSA V25214
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V24887 10/10/22 09:28
<7.48 µg/L 7.48 10.5
Acenaphthene 1 10/11/22 16:26 V25225JMV
<7.25 µg/L 7.25 20.9Acenaphthylene 1 10/11/22 16:26 V25225JMV
<6.90 µg/L 6.90 10.5Anthracene 1 10/11/22 16:26 V25225JMV
<5.33 µg/L 5.33 10.5Benzidine 1 10/11/22 16:26 V25225JMV
<6.98 µg/L 6.98 10.5Benzo(a)anthracene 1 10/11/22 16:26 V25225JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V24887 10/10/22 09:28
<4.90 µg/L 4.90 10.5Benzo(a)pyrene 1 10/11/22 16:26 V25225JMV
<4.75 µg/L 4.75 10.5Benzo(b)fluoranthene 1 10/11/22 16:26 V25225JMV
<4.45 µg/L 4.45 10.5Benzo(g,h,i)perylene 1 10/11/22 16:26 V25225JMV
<5.10 µg/L 5.10 10.5Benzo(k)fluoranthene 1 10/11/22 16:26 V25225JMV
<12.1 µg/L 12.1 52.4Benzoic Acid 1 10/11/22 16:26 V25225JMV
<9.03 µg/L 9.03 10.5Benzyl alcohol 1 10/11/22 16:26 V25225JMV
<5.95 µg/L 5.95 10.5Bis(2-Chloroethoxy)methane 1 10/11/22 16:26 V25225JMV
<7.67 µg/L 7.67 10.5Bis(2-Chloroethyl)ether 1 10/11/22 16:26 V25225JMV
<6.92 µg/L 6.92 10.5
Bis(2-Chloroisopropyl)ether 1 10/11/22 16:26 V25225JMV
<9.24 µg/L 9.24 10.5Bis(2-ethylhexyl)phthalate 1 10/11/22 16:26 V25225JMV
<6.54 µg/L 6.54 20.94-Bromophenyl phenyl ether 1 10/11/22 16:26 V25225JMV
<4.76 µg/L 4.76 10.5Butyl benzyl phthalate 1 10/11/22 16:26 V25225JMV
<5.49 µg/L 5.49 10.54-Chloro-3-methylphenol 1 10/11/22 16:26 V25225JMV
<7.71 µg/L 7.71 20.92-Chloronaphthalene 1 10/11/22 16:26 V25225JMV
<6.91 µg/L 6.91 10.52-Chlorophenol 1 10/11/22 16:26 V25225JMV
<7.30 µg/L 7.30 20.9
4-Chlorophenyl phenyl ether 1 10/11/22 16:26 V25225JMV
<5.65 µg/L 5.65 10.5Chrysene 1 10/11/22 16:26 V25225JMV
<6.28 µg/L 6.28 20.9Dibenz(a,h)anthracene 1 10/11/22 16:26 V25225JMV
<5.31 µg/L 5.31 20.9Dibenzofuran 1 10/11/22 16:26 V25225JMV
<6.21 µg/L 6.21 10.51,2-Dichlorobenzene 1 10/11/22 16:26 V25225JMV
<6.12 µg/L 6.12 10.51,3-Dichlorobenzene 1 10/11/22 16:26 V25225JMV
<6.21 µg/L 6.21 10.51,4-Dichlorobenzene 1 10/11/22 16:26 V25225JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V24887 10/10/22 09:28
<6.93 µg/L 6.93 10.53,3'-Dichlorobenzidine 1 10/11/22 16:26 V25225JMV
<5.82 µg/L 5.82 10.52,4-Dichlorophenol 1 10/11/22 16:26 V25225JMV
<9.77 µg/L 9.77 20.9Diethyl phthalate 1 10/11/22 16:26 V25225JMV
<8.21 µg/L 8.21 10.5Dimethyl phthalate 1 10/11/22 16:26 V25225JMV
<11.4 µg/L 11.4 20.92,4-Dimethylphenol 1 10/11/22 16:26 V25225JMV
<7.72 µg/L 7.72 10.5Di-n-butyl phthalate 1 10/11/22 16:26 V25225JMV
<10.4 µg/L 10.4 31.44,6-Dinitro-2-methylphenol 1 10/11/22 16:26 V25225JMV
<11.1 µg/L 11.1 31.42,4-Dinitrophenol 1 10/11/22 16:26 V25225JMV
<5.46 µg/L 5.46 10.5
2,4-Dinitrotoluene 1 10/11/22 16:26 V25225JMV
<6.17 µg/L 6.17 20.92,6-Dinitrotoluene 1 10/11/22 16:26 V25225JMV
<5.26 µg/L 5.26 10.5Di-n-Octyl Phthalate 1 10/11/22 16:26 V25225JMV
<6.33 µg/L 6.33 10.5Fluoranthene 1 10/11/22 16:26 V25225JMV
<7.63 µg/L 7.63 10.5Fluorene 1 10/11/22 16:26 V25225JMV
<6.01 µg/L 6.01 20.9Hexachlorobenzene 1 10/11/22 16:26 V25225JMV
<6.14 µg/L 6.14 20.9Hexachlorobutadiene 1 10/11/22 16:26 V25225JMV
<6.17 µg/L 6.17 20.9
Hexachlorocyclopentadiene 1 10/11/22 16:26 V25225JMV
<5.48 µg/L 5.48 10.5Hexachloroethane 1 10/11/22 16:26 V25225JMV
<6.51 µg/L 6.51 10.5Indeno(1,2,3-cd)pyrene 1 10/11/22 16:26 V25225JMV
<7.05 µg/L 7.05 10.5Isophorone 1 10/11/22 16:26 V25225JMV
18.8 µg/L 8.27 10.5Naphthalene 1 10/11/22 16:26 V25225JMV
<8.27 µg/L 8.27 10.5Nitrobenzene 1 10/11/22 16:26 V25225JMV
<5.76 µg/L 5.76 10.52-Nitrophenol 1 10/11/22 16:26 V25225JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V24887 10/10/22 09:28
<2.95 µg/L 2.95 10.54-Nitrophenol 1 10/11/22 16:26 V25225JMV
<11.4 µg/L 11.4 20.9N-Nitrosodiphenylamine 1 10/11/22 16:26 V25225JMV
<8.46 µg/L 8.46 20.9N-Nitroso-di-n-propylamine 1 10/11/22 16:26 V25225JMV
<10.2 µg/L 10.2 52.4Pentachlorophenol 1 10/11/22 16:26 V25225JMV
<6.66 µg/L 6.66 10.5Phenanthrene 1 10/11/22 16:26 V25225JMV
<3.00 µg/L 3.00 10.5Phenol 1 10/11/22 16:26 V25225JMV
<5.69 µg/L 5.69 10.5Pyrene 1 10/11/22 16:26 V25225JMV
<6.56 µg/L 6.56 10.51,2,4-Trichlorobenzene 1 10/11/22 16:26 V25225JMV
<6.57 µg/L 6.57 20.9
2,4,6-Trichlorophenol 1 10/11/22 16:26 V25225JMV
625.1Surrogate: Phenol-d5 31.5 Limits: 10-63%10/11/22 16:261 JMV
Surrogate: 2-Fluorobiphenyl 77.9 Limits: 49-118%10/11/22 16:261 JMV V25225
Surrogate: 2-Fluorophenol 48.1 Limits: 22-84%10/11/22 16:261 JMV V25225
Surrogate: Nitrobenzene-d5 59.9 Limits: 43-123%10/11/22 16:261 JMV V25225
Surrogate: 4-Terphenyl-d14 82.8 Limits: 49-151%10/11/22 16:261 JMV V25225
Surrogate: 2,4,6-Tribromophenol 108 Limits: 31-144%10/11/22 16:261 JMV V25225
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V24877 10/10/22 09:00
<0.00347 µg/L 0.00347 0.0210
1,2-Dibromoethane 1 10/10/22 12:07 V24889JLK
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
63.7 J µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 10/10/22 14:22
124 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 10/10/22 14:22
65.0 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 10/10/22 14:22
89.2 J µg/L 65.9 269Aromatic C11-C22 (Adjusted)1 10/11/22 16:26
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V24998 10/12/22 08:30
<30.3 µg/L 30.3 376Aliphatic C9-C18 1 10/13/22 13:21 V25086JLK
<133 µg/L 133 538Aliphatic C19-C36 1 10/13/22 13:21 V25086JLK
108 J µg/L 65.9 269Aromatic C11-C22 1 10/13/22 13:21 V25086JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 123 Limits: 40-140%10/13/22 13:211 JLK
MADEP-EPHSurrogate: Chlorooctadecane 74.4 Limits: 40-140%10/13/22 13:211 JLK
MADEP-EPHSurrogate: OTP Surrogate 94.9 Limits: 40-140%10/13/22 13:211 JLK
Surrogate: 2-Fluorobiphenyl 119 Limits: 40-140%10/13/22 13:211 JLK V25086
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24911 10/10/22 08:00
74.7 µg/L 11.5 50.0Aliphatic C5-C8 1 10/10/22 14:22 V24912TBL
191 µg/L 25.8 50.0Aliphatic C9-C12 1 10/10/22 14:22 V24912TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:MW-1
90151 Matrix:
10/6/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V24911 10/10/22 08:00
65.0 µg/L 4.02 50.0Aromatic C9-C10 1 10/10/22 14:22 V24912TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)90.4 Limits: 70-130%10/10/22 14:221 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.6 Limits: 70-130%10/10/22 14:221 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:Trip Blank
90152 Matrix:
10/6/2022 8:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00
<1.80 µg/L 1.80 10.0Acetone 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.500Benzene 1 10/13/22 22:46 V25132MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 10/13/22 22:46 V25132MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 10/13/22 22:46 V25132MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 10/13/22 22:46 V25132MSA
<1.50 µg/L 1.50 5.00Bromoform 1 10/13/22 22:46 V25132MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 10/13/22 22:46 V25132MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 10/13/22 22:46 V25132MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 10/13/22 22:46 V25132MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 10/13/22 22:46 V25132MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 10/13/22 22:46 V25132MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 10/13/22 22:46 V25132MSA
<0.220 µg/L 0.220 0.500Chloroform 1 10/13/22 22:46 V25132MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 10/13/22 22:46 V25132MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 10/13/22 22:46 V25132MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 10/13/22 22:46 V25132MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 10/13/22 22:46 V25132MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 10/13/22 22:46 V25132MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 10/13/22 22:46 V25132MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 10/13/22 22:46 V25132MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:Trip Blank
90152 Matrix:
10/6/2022 8:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 10/13/22 22:46 V25132MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 10/13/22 22:46 V25132MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 10/13/22 22:46 V25132MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 10/13/22 22:46 V25132MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 10/13/22 22:46 V25132MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 10/13/22 22:46 V25132MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 10/13/22 22:46 V25132MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 10/13/22 22:46 V25132MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 10/13/22 22:46 V25132MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 10/13/22 22:46 V25132MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 10/13/22 22:46 V25132MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 10/13/22 22:46 V25132MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 10/13/22 22:46 V25132MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 10/13/22 22:46 V25132MSA
<42.0 µg/L 42.0 200
Ethanol 1 10/13/22 22:46 V25132MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 10/13/22 22:46 V25132MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 10/13/22 22:46 V25132MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 10/13/22 22:46 V25132MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 10/13/22 22:46 V25132MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 10/13/22 22:46 V25132MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:Trip Blank
90152 Matrix:
10/6/2022 8:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 10/13/22 22:46 V25132MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 10/13/22 22:46 V25132MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 10/13/22 22:46 V25132MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 10/13/22 22:46 V25132MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 10/13/22 22:46 V25132MSA
<0.220 µg/L 0.220 0.500Styrene 1 10/13/22 22:46 V25132MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 10/13/22 22:46 V25132MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 10/13/22 22:46 V25132MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 10/13/22 22:46 V25132MSA
<0.220 µg/L 0.220 0.500Toluene 1 10/13/22 22:46 V25132MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 10/13/22 22:46 V25132MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 10/13/22 22:46 V25132MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 10/13/22 22:46 V25132MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 10/13/22 22:46 V25132MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 10/13/22 22:46 V25132MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 10/13/22 22:46 V25132MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 10/13/22 22:46 V25132MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 10/13/22 22:46 V25132MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 10/13/22 22:46 V25132MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 10/13/22 22:46 V25132MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 84
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-280-0004
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 10/07/2022
Meley Grocery
Report Date : 10/21/2022
Sample ID :
Lab No :
Sampled:Trip Blank
90152 Matrix:
10/6/2022 8:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V25131 10/13/22 14:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 10/13/22 22:46 V25132MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 10/13/22 22:46 V25132
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%10/13/22 22:461 MSA V25132
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%10/13/22 22:461 MSA V25132
Surrogate: 1,2-Dichloroethane - d4 99.4 Limits: 70-130%10/13/22 22:461 MSA V25132
Surrogate: Toluene-d8 100 Limits: 70-130%10/13/22 22:461 MSA V25132
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 84
Sample ID Report Lab NoLRB22‐280‐0004 LRB‐V24887
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
NO TICS REPORTED 0 ug/L 1 625.1 10/11/2022 14:13 JMV V25225
Sample ID Report Lab NoMW‐1 22‐280‐0004 V90151
Paramater Result Units
Dilution 
Factor Method Analysis Date/Time Analyst Batch ID
Indane 28.9 ug/L 1 625.1 10/11/2022 16:26 JMV V25225
Phenyl Butene 11.3 ug/L 1 625.1 10/11/2022 16:26 JMV V25225
Page 44 of 84
Tentatively Identified Compound (LSC) summary
Data Path : S:\SMS\SMS-F\Data\101122\
Data File : F-101122-13.D
Acq On : 11 Oct 2022 14:13
Operator : JVOGEL
Sample : LRB-V24887
Misc :
ALS Vial : 12 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F082522_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
|--Internal Standard---|
TIC Top Hit name RT EstConc Units Response |# RT Resp Conc|
----------------------------------------------------------------------------
F082522_FL.M Thu Oct 20 14:27:19 2022 Page: 8
NO TICS REPORTED
Page 45 of 84
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\101122\
Data File : F-101122-19.D
Acq On : 11 Oct 2022 16:26
Operator : JVOGEL
Sample : V 90151-V24887
Misc :
ALS Vial : 18 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F082522_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 4 Indane Concentration Rank 1
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
3.726 28.96 ppb 456136 1,4-Dichlorobenzene-d4 3.579
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 Indane 118 C9H10 000496-11-7 91
2 Indane 118 C9H10 000496-11-7 87
3 Benzene, 1-ethenyl-4-methyl- 118 C9H10 000622-97-9 72
4 Benzene, 2-propenyl- 118 C9H10 000300-57-2 72
5 Benzene, 2-propenyl- 118 C9H10 000300-57-2 72
10 20 30 40 50 60 70 80 90 100 110 120 130
0
5000
m/z-->
Abundance Scan 313 (3.726 min): F-101122-19.D\data.ms (-302) (-)
117.1
91.1
39.0 63.051.0 103.077.0 128.8
10 20 30 40 50 60 70 80 90 100 110 120 130
0
5000
m/z-->
Abundance #111258: Indane
117.0
91.058.039.0 103.077.027.0
10 20 30 40 50 60 70 80 90 100 110 120 130
0
5000
m/z-->
Abundance #111257: Indane
117.0
91.063.039.0 51.0 103.077.027.015.0
10 20 30 40 50 60 70 80 90 100 110 120 130
0
5000
m/z-->
Abundance #111253: Benzene, 1-ethenyl-4-methyl-
117.0
91.0
39.0 63.051.0 103.077.027.015.0
3.40 3.60 3.80 4.00
m/z 117.10 100.00%
3.40 3.60 3.80 4.00
m/z 118.10 58.22%
3.40 3.60 3.80 4.00
m/z 115.00 32.51%
3.40 3.60 3.80 4.00
m/z 91.10 15.30%
3.40 3.60 3.80 4.00
m/z 116.10 8.13%
F082522_FL.M Thu Oct 20 14:29:06 2022 Page: 8Page 46 of 84
Library Search Compound Report
Data Path : S:\SMS\SMS-F\Data\101122\
Data File : F-101122-19.D
Acq On : 11 Oct 2022 16:26
Operator : JVOGEL
Sample : V 90151-V24887
Misc :
ALS Vial : 18 Sample Multiplier: 1
Quant Method : S:\SMS\SMS-F\Method\F082522_FL.M
Quant Title : 8270 / 625 INITIAL CALIBRATION
TIC Library : S:\Misc\NIST129K.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 7 1-Phenyl-1-butene Concentration Rank 3
R.T. EstConc Area Relative to ISTD R.T.
---------------------------------------------------------------------
4.414 11.30 ppb 355615 Naphthalene-d8 4.649
Hit# of 5 Tentative ID MW MolForm CAS# Qual
---------------------------------------------------------------------
1 1-Phenyl-1-butene 132 C10H12 000824-90-8 92
2 Benzene, 1-methyl-2-(2-propenyl)- 132 C10H12 001587-04-8 70
3 Indan, 1-methyl- 132 C10H12 000767-58-8 70
4 Benzene, 2-ethenyl-1,3-dimethyl-... 132 C10H12 002039-90-9 70
5 1H-Indene, 2,3-dihydro-2-methyl- 132 C10H12 000824-63-5 62
10 20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance Scan 430 (4.414 min): F-101122-19.D\data.ms (-426) (-)
117.1
132.1
91.0
77.051.0 65.039.0 103.1
10 20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance #112738: 1-Phenyl-1-butene
117.0
132.0
91.0
77.051.0 65.039.0 104.027.0
10 20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance #112748: Benzene, 1-methyl-2-(2-propenyl)-
117.0
132.0
91.0
105.065.0 77.039.0 51.027.0
10 20 30 40 50 60 70 80 90 100 110 120 130 140
0
5000
m/z-->
Abundance #112745: Indan, 1-methyl-
117.0
132.0
91.051.0 63.0 77.0 102.0
4.00 4.20 4.40 4.60 4.80
m/z 117.05 100.00%
4.00 4.20 4.40 4.60 4.80
m/z 119.10 47.29%
4.00 4.20 4.40 4.60 4.80
m/z 132.05 37.03%
4.00 4.20 4.40 4.60 4.80
m/z 115.10 31.52%
4.00 4.20 4.40 4.60 4.80
m/z 134.05 20.08%
F082522_FL.M Thu Oct 20 14:29:09 2022 Page: 11Page 47 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Metals Analysis
6010D
V24992,V25100QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V24927
Associated Lab Samples: 90151
LRB-V24927 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
10/11/22 16:350.0060.002<0.002mg/LLead
LCS-V24927Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1050.1050.100mg/LLead 80-120
V 90151-MS-V24927 V 90151-MSD-V24927Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.144 1090.1440.1000.1000.035mg/LLead 109 75-125 0.0 20.0
V 90151-PDS-V24927Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
10/13/22 18:591041.31mg/LLead
Page 1 of 35Date:10/21/2022 03:44 PM
Page 48 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V25132QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V25131
Associated Lab Samples: 90151, 90152
LRB-V25131 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/13/22 22:1910.01.80<1.80µg/LAcetone
10/13/22 22:190.5000.180<0.180µg/LBenzene
10/13/22 22:190.5000.210<0.210µg/LBromobenzene
10/13/22 22:191.000.420<0.420µg/LBromochloromethane
10/13/22 22:190.5000.160<0.160µg/LBromodichloromethane
10/13/22 22:195.001.50<1.50µg/LBromoform
10/13/22 22:191.000.280<0.280µg/LBromomethane
10/13/22 22:190.5000.180<0.180µg/Ln-Butylbenzene
10/13/22 22:190.5000.200<0.200µg/Lsec-Butyl benzene
10/13/22 22:192.000.920<0.920µg/Ltert-Butyl benzene
10/13/22 22:190.5000.180<0.180µg/LCarbon Tetrachloride
10/13/22 22:190.5000.190<0.190µg/LChlorobenzene
10/13/22 22:190.5000.190<0.190µg/LChlorodibromomethane
10/13/22 22:191.000.430<0.430µg/LChloroethane
10/13/22 22:190.5000.220<0.220µg/LChloroform
10/13/22 22:190.5000.220<0.220µg/LChloromethane
10/13/22 22:190.5000.200<0.200µg/L2-Chlorotoluene
10/13/22 22:190.5000.200<0.200µg/L4-Chlorotoluene
10/13/22 22:190.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
10/13/22 22:192.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
10/13/22 22:190.5000.200<0.200µg/L1,2-Dibromoethane
10/13/22 22:190.5000.230<0.230µg/LDibromomethane
10/13/22 22:190.5000.220<0.220µg/L1,2-Dichlorobenzene
10/13/22 22:190.5000.190<0.190µg/L1,3-Dichlorobenzene
10/13/22 22:190.5000.210<0.210µg/L1,4-Dichlorobenzene
10/13/22 22:195.001.20<1.20µg/LDichlorodifluoromethane
10/13/22 22:190.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 35Date:10/21/2022 03:44 PM
Page 49 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V25132QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V25131
Associated Lab Samples: 90151, 90152
LRB-V25131 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/13/22 22:190.5000.150<0.150µg/L1,2-Dichloroethane
10/13/22 22:190.5000.150<0.150µg/L1,1-Dichloroethene
10/13/22 22:190.5000.200<0.200µg/Lcis-1,2-Dichloroethene
10/13/22 22:190.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
10/13/22 22:190.5000.190<0.190µg/L1,2-Dichloropropane
10/13/22 22:190.5000.130<0.130µg/L1,3-Dichloropropane
10/13/22 22:192.000.210<0.210µg/L2,2-Dichloropropane
10/13/22 22:190.5000.200<0.200µg/L1,1-Dichloropropene
10/13/22 22:190.5000.210<0.210µg/Lcis-1,3-Dichloropropene
10/13/22 22:190.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
10/13/22 22:1920042.0<42.0µg/LEthanol
10/13/22 22:190.5000.170<0.170µg/LEthylbenzene
10/13/22 22:193.000.350<0.350µg/LHexachlorobutadiene
10/13/22 22:191.000.380<0.380µg/L2-Hexanone
10/13/22 22:190.5000.180<0.180µg/LIsopropylbenzene
10/13/22 22:190.5000.089<0.089µg/L4-Isopropyl toluene
10/13/22 22:195.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
10/13/22 22:191.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
10/13/22 22:191.000.078<0.078µg/L4-Methyl-2-Pentanone
10/13/22 22:192.000.330<0.330µg/LMethylene Chloride
10/13/22 22:191.000.470<0.470µg/LNaphthalene
10/13/22 22:190.5000.190<0.190µg/Ln-Propylbenzene
10/13/22 22:190.5000.220<0.220µg/LStyrene
10/13/22 22:1910.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
10/13/22 22:1910.00.350<0.350µg/Ltert-Butyl formate (TBF)
10/13/22 22:1910.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
10/13/22 22:190.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 3 of 35Date:10/21/2022 03:44 PM
Page 50 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V25132QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V25131
Associated Lab Samples: 90151, 90152
LRB-V25131 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/13/22 22:190.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
10/13/22 22:190.5000.220<0.220µg/LTetrachloroethene
10/13/22 22:190.5000.220<0.220µg/LToluene
10/13/22 22:190.5000.380<0.380µg/L1,2,3-Trichlorobenzene
10/13/22 22:190.5000.310<0.310µg/L1,2,4-Trichlorobenzene
10/13/22 22:190.5000.160<0.160µg/L1,1,1-Trichloroethane
10/13/22 22:190.5000.096<0.096µg/L1,1,2-Trichloroethane
10/13/22 22:190.5000.180<0.180µg/LTrichloroethene
10/13/22 22:190.5000.180<0.180µg/LTrichlorofluoromethane
10/13/22 22:190.5000.270<0.270µg/L1,2,3-Trichloropropane
10/13/22 22:190.5000.190<0.190µg/L1,2,4-Trimethylbenzene
10/13/22 22:190.5000.180<0.180µg/L1,3,5-Trimethylbenzene
10/13/22 22:195.001.00<1.00µg/LVinyl Acetate
10/13/22 22:190.5000.170<0.170µg/LVinyl Chloride
10/13/22 22:190.5000.210<0.210µg/Lo-Xylene
10/13/22 22:191.000.420<0.420µg/Lm,p-Xylene
10/13/22 22:1910.01.00<1.00µg/L3,3-Dimethyl-1-butanol
10/13/22 22:194-Bromofluorobenzene (S)98.0 70-130
10/13/22 22:19Dibromofluoromethane (S)97.0 70-130
10/13/22 22:191,2-Dichloroethane - d4 (S)98.4 70-130
10/13/22 22:19Toluene-d8 (S)99.6 70-130
LCS-V25131 LCSD-V25131Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
39.3 98.293.737.540.0µg/LAcetone 40-160 4.6 20.0
Page 4 of 35Date:10/21/2022 03:44 PM
Page 51 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V25132QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V25131
LCS-V25131 LCSD-V25131Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.6 93.095.519.120.0µg/LBenzene 70-130 2.6 20.0
18.2 91.094.018.820.0µg/LBromobenzene 70-130 3.2 20.0
20.5 10310220.420.0µg/LBromochloromethane 70-130 0.4 20.0
17.5 87.589.017.820.0µg/LBromodichloromethane 70-130 1.6 20.0
21.6 10810821.520.0µg/LBromoform 70-130 0.4 20.0
19.4 97.010320.620.0µg/LBromomethane 60-140 6.0 20.0
18.5 92.595.519.120.0µg/Ln-Butylbenzene 70-130 3.1 20.0
18.2 91.094.018.820.0µg/Lsec-Butyl benzene 70-130 3.2 20.0
18.0 90.095.519.120.0µg/Ltert-Butyl benzene 70-130 5.9 20.0
18.6 93.090.018.020.0µg/LCarbon Tetrachloride 70-130 3.2 20.0
18.7 93.596.519.320.0µg/LChlorobenzene 70-130 3.1 20.0
19.1 95.592.018.420.0µg/LChlorodibromomethane 70-130 3.7 20.0
18.7 93.597.519.520.0µg/LChloroethane 60-140 4.1 20.0
18.6 93.094.518.920.0µg/LChloroform 70-130 1.6 20.0
20.0 10010420.820.0µg/LChloromethane 60-140 3.9 20.0
18.2 91.094.018.820.0µg/L2-Chlorotoluene 70-130 3.2 20.0
18.2 91.095.019.020.0µg/L4-Chlorotoluene 70-130 4.3 20.0
18.6 93.095.019.020.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.1 20.0
19.7 98.511222.420.0µg/L1,2-Dibromo-3-Chloropropane 70-130 12.8 20.0
19.0 95.091.018.220.0µg/L1,2-Dibromoethane 70-130 4.3 20.0
19.6 98.094.518.920.0µg/LDibromomethane 70-130 3.6 20.0
19.1 95.598.519.720.0µg/L1,2-Dichlorobenzene 70-130 3.0 20.0
19.0 95.098.019.620.0µg/L1,3-Dichlorobenzene 70-130 3.1 20.0
19.0 95.097.519.520.0µg/L1,4-Dichlorobenzene 70-130 2.5 20.0
21.3 10710821.620.0µg/LDichlorodifluoromethane 60-140 1.3 20.0
18.4 92.094.018.820.0µg/L1,1-Dichloroethane 70-130 2.1 20.0
Page 5 of 35Date:10/21/2022 03:44 PM
Page 52 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V25132QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V25131
LCS-V25131 LCSD-V25131Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.5 87.588.517.720.0µg/L1,2-Dichloroethane 70-130 1.1 20.0
18.5 92.593.018.620.0µg/L1,1-Dichloroethene 70-130 0.5 20.0
18.5 92.594.018.820.0µg/Lcis-1,2-Dichloroethene 70-130 1.6 20.0
18.5 92.595.019.020.0µg/Ltrans-1,2-Dichloroethene 70-130 2.6 20.0
19.3 96.595.019.020.0µg/L1,2-Dichloropropane 70-130 1.5 20.0
18.4 92.092.518.520.0µg/L1,3-Dichloropropane 70-130 0.5 20.0
17.5 87.593.518.720.0µg/L2,2-Dichloropropane 70-130 6.6 20.0
19.4 97.099.019.820.0µg/L1,1-Dichloropropene 70-130 2.0 20.0
18.7 93.592.518.520.0µg/Lcis-1,3-Dichloropropene 70-130 1.0 20.0
18.7 93.592.518.520.0µg/Ltrans-1,3-Dichloropropene 70-130 1.0 20.0
416 83.281.4407500µg/LEthanol 60-140 2.1 20.0
18.0 90.092.018.420.0µg/LEthylbenzene 70-130 2.1 20.0
18.8 94.010220.320.0µg/LHexachlorobutadiene 70-130 7.6 20.0
18.8 94.092.518.520.0µg/L2-Hexanone 60-140 1.6 20.0
18.1 90.595.519.120.0µg/LIsopropylbenzene 70-130 5.3 20.0
19.1 95.598.519.720.0µg/L4-Isopropyl toluene 70-130 3.0 20.0
20.3 10210020.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 1.4 20.0
18.5 92.591.018.220.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.6 20.0
19.4 97.095.019.020.0µg/L4-Methyl-2-Pentanone 60-140 2.0 20.0
18.0 90.091.518.320.0µg/LMethylene Chloride 70-130 1.6 20.0
19.8 99.099.519.920.0µg/LNaphthalene 70-130 0.5 20.0
17.8 89.093.518.720.0µg/Ln-Propylbenzene 70-130 4.9 20.0
19.3 96.595.519.120.0µg/LStyrene 70-130 1.0 20.0
38.7 96.792.236.940.0µg/Ltert-Butyl Alcohol (TBA)40-140 4.7 20.0
38.5 96.297.539.040.0µg/Ltert-Butyl formate (TBF)40-140 1.2 20.0
38.2 95.596.738.740.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.3 20.0
Page 6 of 35Date:10/21/2022 03:44 PM
Page 53 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V25132QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V25131
LCS-V25131 LCSD-V25131Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.2 96.098.019.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.0 20.0
19.8 99.098.019.620.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.0 20.0
18.1 90.593.518.720.0µg/LTetrachloroethene 70-130 3.2 20.0
18.6 93.095.019.020.0µg/LToluene 70-130 2.1 20.0
19.9 99.510320.520.0µg/L1,2,3-Trichlorobenzene 70-130 2.9 20.0
19.8 99.010020.020.0µg/L1,2,4-Trichlorobenzene 70-130 1.0 20.0
17.6 88.092.518.520.0µg/L1,1,1-Trichloroethane 70-130 4.9 20.0
18.7 93.599.019.820.0µg/L1,1,2-Trichloroethane 70-130 5.7 20.0
18.9 94.592.518.520.0µg/LTrichloroethene 70-130 2.1 20.0
18.1 90.596.019.220.0µg/LTrichlorofluoromethane 60-140 5.8 20.0
18.4 92.094.018.820.0µg/L1,2,3-Trichloropropane 70-130 2.1 20.0
18.5 92.597.519.520.0µg/L1,2,4-Trimethylbenzene 70-130 5.2 20.0
18.5 92.595.019.020.0µg/L1,3,5-Trimethylbenzene 70-130 2.6 20.0
15.8 79.088.017.620.0µg/LVinyl Acetate 60-140 10.7 20.0
20.4 10210420.720.0µg/LVinyl Chloride 60-140 1.4 20.0
18.7 93.592.018.420.0µg/Lo-Xylene 70-130 1.6 20.0
37.6 94.098.239.340.0µg/Lm,p-Xylene 70-130 4.4 20.0
21.1 10610320.520.0µg/L3,3-Dimethyl-1-butanol 70-130 2.8 20.0
98.01014-Bromofluorobenzene (S)70-130
101101Dibromofluoromethane (S)70-130
10099.41,2-Dichloroethane - d4 (S)70-130
99.498.8Toluene-d8 (S)70-130
Page 7 of 35Date:10/21/2022 03:44 PM
Page 54 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V25214QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V25213
Associated Lab Samples: 90151
LRB-V25213 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/14/22 12:1310.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
10/14/22 12:134-Bromofluorobenzene (S)101 70-130
10/14/22 12:13Dibromofluoromethane (S)103 70-130
10/14/22 12:131,2-Dichloroethane - d4 (S)96.6 70-130
10/14/22 12:13Toluene-d8 (S)99.8 70-130
LCS-V25213 LCSD-V25213Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
14.4 72.011021.920.0µg/Ltert-Amyl Alcohol (TAA)40-140 41.3*20.0
99.21004-Bromofluorobenzene (S)70-130
115120Dibromofluoromethane (S)70-130
1011041,2-Dichloroethane - d4 (S)70-130
99.299.8Toluene-d8 (S)70-130
Page 8 of 35* QC Fail Date:10/21/2022 03:44 PM
Page 55 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V25225QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V24887
Associated Lab Samples: 90151
LRB-V24887 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/11/22 14:1310.07.12<7.12µg/LAcenaphthene
10/11/22 14:1320.06.94<6.94µg/LAcenaphthylene
10/11/22 14:1310.06.57<6.57µg/LAnthracene
10/11/22 14:1310.05.08<5.08µg/LBenzidine
10/11/22 14:1310.06.65<6.65µg/LBenzo(a)anthracene
10/11/22 14:1310.04.67<4.67µg/LBenzo(a)pyrene
10/11/22 14:1310.04.52<4.52µg/LBenzo(b)fluoranthene
10/11/22 14:1310.04.24<4.24µg/LBenzo(g,h,i)perylene
10/11/22 14:1310.04.86<4.86µg/LBenzo(k)fluoranthene
10/11/22 14:1350.011.5<11.5µg/LBenzoic Acid
10/11/22 14:1310.08.60<8.60µg/LBenzyl alcohol
10/11/22 14:1310.05.67<5.67µg/LBis(2-Chloroethoxy)methane
10/11/22 14:1310.07.30<7.30µg/LBis(2-Chloroethyl)ether
10/11/22 14:1310.06.59<6.59µg/LBis(2-Chloroisopropyl)ether
10/11/22 14:1310.08.80<8.80µg/LBis(2-ethylhexyl)phthalate
10/11/22 14:1320.06.26<6.26µg/L4-Bromophenyl phenyl ether
10/11/22 14:1310.04.53<4.53µg/LButyl benzyl phthalate
10/11/22 14:1310.05.23<5.23µg/L4-Chloro-3-methylphenol
10/11/22 14:1320.07.38<7.38µg/L2-Chloronaphthalene
10/11/22 14:1310.06.58<6.58µg/L2-Chlorophenol
10/11/22 14:1320.06.99<6.99µg/L4-Chlorophenyl phenyl ether
10/11/22 14:1310.05.38<5.38µg/LChrysene
10/11/22 14:1320.06.01<6.01µg/LDibenz(a,h)anthracene
10/11/22 14:1320.05.08<5.08µg/LDibenzofuran
10/11/22 14:1310.05.91<5.91µg/L1,2-Dichlorobenzene
10/11/22 14:1310.05.83<5.83µg/L1,3-Dichlorobenzene
10/11/22 14:1310.05.91<5.91µg/L1,4-Dichlorobenzene
Page 9 of 35Date:10/21/2022 03:44 PM
Page 56 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V25225QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V24887
Associated Lab Samples: 90151
LRB-V24887 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/11/22 14:1310.06.60<6.60µg/L3,3'-Dichlorobenzidine
10/11/22 14:1310.05.54<5.54µg/L2,4-Dichlorophenol
10/11/22 14:1320.09.35<9.35µg/LDiethyl phthalate
10/11/22 14:1310.07.82<7.82µg/LDimethyl phthalate
10/11/22 14:1320.010.9<10.9µg/L2,4-Dimethylphenol
10/11/22 14:1310.07.35<7.35µg/LDi-n-butyl phthalate
10/11/22 14:1330.09.92<9.92µg/L4,6-Dinitro-2-methylphenol
10/11/22 14:1330.010.6<10.6µg/L2,4-Dinitrophenol
10/11/22 14:1310.05.20<5.20µg/L2,4-Dinitrotoluene
10/11/22 14:1320.05.90<5.90µg/L2,6-Dinitrotoluene
10/11/22 14:1310.05.01<5.01µg/LDi-n-Octyl Phthalate
10/11/22 14:1310.06.03<6.03µg/LFluoranthene
10/11/22 14:1310.07.27<7.27µg/LFluorene
10/11/22 14:1320.05.75<5.75µg/LHexachlorobenzene
10/11/22 14:1320.05.88<5.88µg/LHexachlorobutadiene
10/11/22 14:1320.05.90<5.90µg/LHexachlorocyclopentadiene
10/11/22 14:1310.05.22<5.22µg/LHexachloroethane
10/11/22 14:1310.06.20<6.20µg/LIndeno(1,2,3-cd)pyrene
10/11/22 14:1310.06.71<6.71µg/LIsophorone
10/11/22 14:1310.07.88<7.88µg/LNaphthalene
10/11/22 14:1310.07.88<7.88µg/LNitrobenzene
10/11/22 14:1310.05.49<5.49µg/L2-Nitrophenol
10/11/22 14:1310.02.81<2.81µg/L4-Nitrophenol
10/11/22 14:1320.010.9<10.9µg/LN-Nitrosodiphenylamine
10/11/22 14:1320.08.10<8.10µg/LN-Nitroso-di-n-propylamine
10/11/22 14:1350.09.73<9.73µg/LPentachlorophenol
10/11/22 14:1310.06.34<6.34µg/LPhenanthrene
Page 10 of 35Date:10/21/2022 03:44 PM
Page 57 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V25225QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V24887
Associated Lab Samples: 90151
LRB-V24887 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/11/22 14:1310.02.86<2.86µg/LPhenol
10/11/22 14:1310.05.42<5.42µg/LPyrene
10/11/22 14:1310.06.25<6.25µg/L1,2,4-Trichlorobenzene
10/11/22 14:1320.06.29<6.29µg/L2,4,6-Trichlorophenol
10/11/22 14:132-Fluorobiphenyl (S)61.0 49-118
10/11/22 14:132-Fluorophenol (S)34.6 22-84
10/11/22 14:13Nitrobenzene-d5 (S)46.4 43-123
10/11/22 14:134-Terphenyl-d14 (S)73.8 49-151
10/11/22 14:132,4,6-Tribromophenol (S)86.2 31-144
10/11/22 14:13Phenol-d5 (S)22.4 10-63
LCS-V24887 LCSD-V24887Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.6 63.259.229.650.0µg/LAcenaphthene 47-145 6.5 20.0
33.4 66.862.831.450.0µg/LAcenaphthylene 33-145 6.1 20.0
34.8 69.668.234.150.0µg/LAnthracene 27-133 2.0 20.0
23.7 47.440.820.450.0µg/LBenzidine 15-150 14.9 20.0
34.9 69.865.432.750.0µg/LBenzo(a)anthracene 33-143 6.5 20.0
40.6 81.276.038.050.0µg/LBenzo(a)pyrene 17-163 6.6 20.0
35.6 71.266.833.450.0µg/LBenzo(b)fluoranthene 24-159 6.3 20.0
34.6 69.265.432.750.0µg/LBenzo(g,h,i)perylene 10-219 5.6 20.0
34.6 69.265.032.550.0µg/LBenzo(k)fluoranthene 11-162 6.2 20.0
11.6 23.226.413.250.0µg/LBenzoic Acid 10-125 12.9 20.0
33.0 66.058.829.450.0µg/LBenzyl alcohol 16-107 11.5 20.0
27.5 55.052.826.450.0µg/LBis(2-Chloroethoxy)methane 33-184 4.0 20.0
Page 11 of 35Date:10/21/2022 03:44 PM
Page 58 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V25225QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V24887
LCS-V24887 LCSD-V24887Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.8 47.643.421.750.0µg/LBis(2-Chloroethyl)ether 12-158 9.2 20.0
24.4 48.844.022.050.0µg/LBis(2-Chloroisopropyl)ether 36-166 10.3 20.0
33.9 67.864.232.150.0µg/LBis(2-ethylhexyl)phthalate 10-158 5.4 20.0
41.0 82.076.638.350.0µg/L4-Bromophenyl phenyl ether 53-127 6.8 20.0
28.5 57.054.027.050.0µg/LButyl benzyl phthalate 10-152 5.4 20.0
31.4 62.861.430.750.0µg/L4-Chloro-3-methylphenol 22-147 2.2 20.0
33.1 66.261.630.850.0µg/L2-Chloronaphthalene 60-118 7.1 20.0
31.5 63.057.828.950.0µg/L2-Chlorophenol 23-134 8.6 20.0
37.5 75.070.435.250.0µg/L4-Chlorophenyl phenyl ether 25-158 6.3 20.0
36.1 72.268.834.450.0µg/LChrysene 17-168 4.8 20.0
37.1 74.272.236.150.0µg/LDibenz(a,h)anthracene 10-227 2.7 20.0
35.0 70.064.632.350.0µg/LDibenzofuran 39-114 8.0 20.0
30.6 61.255.027.550.0µg/L1,2-Dichlorobenzene 32-129 10.6 20.0
29.7 59.454.027.050.0µg/L1,3-Dichlorobenzene 20-124 9.5 20.0
28.6 57.251.625.850.0µg/L1,4-Dichlorobenzene 20-124 10.2 20.0
32.6 65.261.430.750.0µg/L3,3'-Dichlorobenzidine 10-262 6.0 20.0
32.7 65.464.232.150.0µg/L2,4-Dichlorophenol 39-135 1.8 20.0
36.4 72.869.434.750.0µg/LDiethyl phthalate 10-114 4.7 20.0
36.8 73.668.834.450.0µg/LDimethyl phthalate 10-112 6.7 20.0
31.9 63.859.829.950.0µg/L2,4-Dimethylphenol 32-119 6.4 20.0
37.7 75.472.636.350.0µg/LDi-n-butyl phthalate 10-118 3.7 20.0
34.1 68.263.431.750.0µg/L4,6-Dinitro-2-methylphenol 10-181 7.2 20.0
33.8 67.664.632.350.0µg/L2,4-Dinitrophenol 10-191 4.5 20.0
41.0 82.075.237.650.0µg/L2,4-Dinitrotoluene 39-139 8.6 20.0
39.6 79.272.236.150.0µg/L2,6-Dinitrotoluene 50-158 9.2 20.0
33.8 67.664.232.150.0µg/LDi-n-Octyl Phthalate 10-146 5.1 20.0
Page 12 of 35Date:10/21/2022 03:44 PM
Page 59 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V25225QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V24887
LCS-V24887 LCSD-V24887Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
36.7 73.471.235.650.0µg/LFluoranthene 26-137 3.0 20.0
34.6 69.265.632.850.0µg/LFluorene 59-121 5.3 20.0
42.9 85.879.639.850.0µg/LHexachlorobenzene 10-152 7.4 20.0
32.6 65.262.031.050.0µg/LHexachlorobutadiene 24-116 5.0 20.0
27.5 55.051.225.650.0µg/LHexachlorocyclopentadiene 32-117 7.1 20.0
24.9 49.846.623.350.0µg/LHexachloroethane 40-113 6.6 20.0
35.5 71.067.433.750.0µg/LIndeno(1,2,3-cd)pyrene 10-171 5.2 20.0
22.8 45.643.021.550.0µg/LIsophorone 21-196 5.8 20.0
26.6 53.250.825.450.0µg/LNaphthalene 21-133 4.6 20.0
24.5 49.044.822.450.0µg/LNitrobenzene 35-180 8.9 20.0
29.8 59.656.028.050.0µg/L2-Nitrophenol 29-182 6.2 20.0
15.0 30.028.214.150.0µg/L4-Nitrophenol 10-132 6.1 20.0
41.3 82.680.240.150.0µg/LN-Nitrosodiphenylamine 69-152 2.9 20.0
28.5 57.050.425.250.0µg/LN-Nitroso-di-n-propylamine 10-230 12.2 20.0
43.5 87.082.041.050.0µg/LPentachlorophenol 14-176 5.9 20.0
34.5 69.067.633.850.0µg/LPhenanthrene 54-120 2.0 20.0
15.8 31.627.813.950.0µg/LPhenol 10-112 12.7 20.0
34.2 68.465.632.850.0µg/LPyrene 52-115 4.1 20.0
29.1 58.255.227.650.0µg/L1,2,4-Trichlorobenzene 44-142 5.2 20.0
35.3 70.664.432.250.0µg/L2,4,6-Trichlorophenol 37-144 9.1 20.0
64.661.42-Fluorobiphenyl (S)49-118
37.534.82-Fluorophenol (S)22-84
45.444.0Nitrobenzene-d5 (S)43-123
73.471.44-Terphenyl-d14 (S)49-151
93.590.12,4,6-Tribromophenol (S)31-144
Page 13 of 35Date:10/21/2022 03:44 PM
Page 60 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V25225QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V24887
LCS-V24887 LCSD-V24887Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.921.8Phenol-d5 (S)10-63
Page 14 of 35Date:10/21/2022 03:44 PM
Page 61 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V24921QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V24920
Associated Lab Samples: 90146, 90150
LRB-V24920 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/10/22 13:200.0200.002<0.002mg/KgAcetone
10/10/22 13:200.0200.001<0.001mg/KgAcrolein
10/10/22 13:200.0200.0008<0.0008mg/KgAcrylonitrile
10/10/22 13:200.0050.0006<0.0006mg/KgBenzene
10/10/22 13:200.0050.0005<0.0005mg/KgBromobenzene
10/10/22 13:200.0050.0008<0.0008mg/KgBromochloromethane
10/10/22 13:200.0050.001<0.001mg/KgBromodichloromethane
10/10/22 13:200.0050.001<0.001mg/KgBromoform
10/10/22 13:200.0100.001<0.001mg/KgBromomethane
10/10/22 13:200.0050.0005<0.0005mg/Kgn-Butylbenzene
10/10/22 13:200.0050.0006<0.0006mg/Kgsec-Butyl benzene
10/10/22 13:200.0050.0005<0.0005mg/Kgtert-Butyl benzene
10/10/22 13:200.0050.0006<0.0006mg/KgCarbon Disulfide
10/10/22 13:200.0050.001<0.001mg/KgCarbon Tetrachloride
10/10/22 13:200.0050.0007<0.0007mg/KgChlorobenzene
10/10/22 13:200.0050.0009<0.0009mg/KgChlorodibromomethane
10/10/22 13:200.0100.0009<0.0009mg/KgChloroethane
10/10/22 13:200.0050.001<0.001mg/KgChloroform
10/10/22 13:200.0100.0006<0.0006mg/KgChloromethane
10/10/22 13:200.0050.0005<0.0005mg/Kg2-Chlorotoluene
10/10/22 13:200.0050.0004<0.0004mg/Kg4-Chlorotoluene
10/10/22 13:200.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
10/10/22 13:200.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
10/10/22 13:200.0050.0006<0.0006mg/Kg1,2-Dibromoethane
10/10/22 13:200.0050.0006<0.0006mg/KgDibromomethane
10/10/22 13:200.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
10/10/22 13:200.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 15 of 35Date:10/21/2022 03:44 PM
Page 62 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V24921QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V24920
Associated Lab Samples: 90146, 90150
LRB-V24920 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/10/22 13:200.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
10/10/22 13:200.0100.001<0.001mg/KgDichlorodifluoromethane
10/10/22 13:200.0050.0008<0.0008mg/Kg1,1-Dichloroethane
10/10/22 13:200.0050.001<0.001mg/Kg1,2-Dichloroethane
10/10/22 13:200.0050.0007<0.0007mg/Kg1,1-Dichloroethene
10/10/22 13:200.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
10/10/22 13:200.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
10/10/22 13:200.0050.0004<0.0004mg/Kg1,2-Dichloropropane
10/10/22 13:200.0050.0006<0.0006mg/Kg1,3-Dichloropropane
10/10/22 13:200.0050.001<0.001mg/Kg2,2-Dichloropropane
10/10/22 13:200.0050.0008<0.0008mg/Kg1,1-Dichloropropene
10/10/22 13:200.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
10/10/22 13:200.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
10/10/22 13:200.0050.0006<0.0006mg/KgEthylbenzene
10/10/22 13:200.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
10/10/22 13:200.0100.0008<0.0008mg/KgHexachlorobutadiene
10/10/22 13:200.0100.0007<0.0007mg/Kgn-Hexane
10/10/22 13:200.0200.0006<0.0006mg/Kg2-Hexanone
10/10/22 13:200.0050.0005<0.0005mg/KgIsopropylbenzene
10/10/22 13:200.0050.001<0.001mg/Kg4-Isopropyl toluene
10/10/22 13:200.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
10/10/22 13:200.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
10/10/22 13:200.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
10/10/22 13:200.0100.001<0.001mg/KgMethylene Chloride
10/10/22 13:200.0100.0010<0.0010mg/KgNaphthalene
10/10/22 13:200.0050.0005<0.0005mg/Kgn-Propylbenzene
10/10/22 13:200.0050.001<0.001mg/KgStyrene
Page 16 of 35Date:10/21/2022 03:44 PM
Page 63 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V24921QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V24920
Associated Lab Samples: 90146, 90150
LRB-V24920 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/10/22 13:200.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
10/10/22 13:200.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
10/10/22 13:200.0050.0009<0.0009mg/KgTetrachloroethene
10/10/22 13:200.0050.0007<0.0007mg/KgToluene
10/10/22 13:200.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
10/10/22 13:200.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
10/10/22 13:200.0050.001<0.001mg/Kg1,1,1-Trichloroethane
10/10/22 13:200.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
10/10/22 13:200.0050.0009<0.0009mg/KgTrichloroethene
10/10/22 13:200.0100.002<0.002mg/KgTrichlorofluoromethane
10/10/22 13:200.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
10/10/22 13:200.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
10/10/22 13:200.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
10/10/22 13:200.0100.0005<0.0005mg/KgVinyl Acetate
10/10/22 13:200.0100.0005<0.0005mg/KgVinyl Chloride
10/10/22 13:200.0050.0005<0.0005mg/Kgo-Xylene
10/10/22 13:200.0100.001<0.001mg/Kgm,p-Xylene
10/10/22 13:204-Bromofluorobenzene (S)101 70-130
10/10/22 13:20Dibromofluoromethane (S)97.6 84-123
10/10/22 13:20Toluene-d8 (S)97.0 76-129
LCS-V24920Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
131*0.1310.100mg/KgAcrolein 70-130
Page 17 of 35* QC Fail Date:10/21/2022 03:44 PM
Page 64 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V24921QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V24920
LCS-V24920 LCSD-V24920Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.091 91.287.80.0870.100mg/KgAcetone 29-198 3.7 20
0.128 1281170.1170.100mg/KgAcrylonitrile 65-134 8.9 20
0.048 97.897.60.0480.050mg/KgBenzene 74-127 0.2 20
0.044 88.689.00.0440.050mg/KgBromobenzene 73-125 0.4 20
0.054 1091050.0520.050mg/KgBromochloromethane 72-134 3.7 20
0.045 91.089.80.0440.050mg/KgBromodichloromethane 75-122 1.3 20
0.048 96.098.00.0490.050mg/KgBromoform 66-135 2.0 20
0.056 1131020.0510.050mg/KgBromomethane 20-180 10.4 20
0.042 85.487.20.0430.050mg/Kgn-Butylbenzene 65-135 2.0 20
0.043 87.089.80.0440.050mg/Kgsec-Butyl benzene 66-131 3.1 20
0.041 82.886.40.0430.050mg/Kgtert-Butyl benzene 67-132 4.2 20
0.046 93.697.40.0480.050mg/KgCarbon Disulfide 61-129 3.9 20
0.039 79.481.40.0400.050mg/KgCarbon Tetrachloride 64-143 2.4 20
0.046 92.692.20.0460.050mg/KgChlorobenzene 74-118 0.4 20
0.047 95.897.00.0480.050mg/KgChlorodibromomethane 73-122 1.2 20
0.044 89.889.00.0440.050mg/KgChloroethane 33-149 0.8 20
0.045 91.890.60.0450.050mg/KgChloroform 73-127 1.3 20
0.040 81.884.80.0420.050mg/KgChloromethane 45-143 3.6 20
0.042 85.287.00.0430.050mg/Kg2-Chlorotoluene 67-124 2.0 20
0.042 85.287.20.0430.050mg/Kg4-Chlorotoluene 71-126 2.3 20
0.047 95.491.00.0450.050mg/KgDi-Isopropyl Ether (DIPE)59-159 4.7 20
0.053 1071040.0520.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 2.6 20
0.053 1081050.0520.050mg/Kg1,2-Dibromoethane 70-132 2.0 20
0.053 1061040.0510.050mg/KgDibromomethane 74-133 2.6 20
0.045 91.690.80.0450.050mg/Kg1,2-Dichlorobenzene 72-123 0.8 20
0.044 88.891.20.0450.050mg/Kg1,3-Dichlorobenzene 71-120 2.6 20
Page 18 of 35Date:10/21/2022 03:44 PM
Page 65 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V24921QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V24920
LCS-V24920 LCSD-V24920Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.044 88.488.80.0440.050mg/Kg1,4-Dichlorobenzene 71-123 0.4 20
0.030 61.063.00.0310.050mg/KgDichlorodifluoromethane 26-146 3.2 20
0.046 93.292.20.0460.050mg/Kg1,1-Dichloroethane 74-127 1.0 20
0.043 87.281.20.0400.050mg/Kg1,2-Dichloroethane 68-128 7.1 20
0.043 86.089.60.0440.050mg/Kg1,1-Dichloroethene 67-149 4.1 20
0.046 93.093.40.0460.050mg/Kgcis-1,2-Dichloroethene 76-134 0.4 20
0.046 92.090.00.0450.050mg/Kgtrans-1,2-Dichloroethene 73-132 2.1 20
0.051 1021040.0520.050mg/Kg1,2-Dichloropropane 73-130 1.5 20
0.050 10197.80.0480.050mg/Kg1,3-Dichloropropane 75-124 3.0 20
0.041 83.884.20.0420.050mg/Kg2,2-Dichloropropane 50-142 0.4 20
0.044 88.493.20.0460.050mg/Kg1,1-Dichloropropene 71-130 5.2 20
0.051 1021000.0500.050mg/Kgcis-1,3-Dichloropropene 71-125 1.9 20
0.049 99.696.80.0480.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.8 20
0.044 88.288.80.0440.050mg/KgEthylbenzene 74-128 0.6 20
0.096 96.694.10.0940.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 2.6 20
0.041 83.484.40.0420.050mg/KgHexachlorobutadiene 64-125 1.1 20
0.051 1031050.0520.050mg/Kgn-Hexane 70-130 1.3 20
0.056 1131110.0550.050mg/Kg2-Hexanone 61-157 2.1 20
0.043 86.287.80.0430.050mg/KgIsopropylbenzene 68-126 1.8 20
0.042 85.688.20.0440.050mg/Kg4-Isopropyl toluene 68-129 2.9 20
0.048 97.897.20.0480.050mg/KgMethyl Ethyl Ketone (MEK)63-149 0.6 20
0.050 10097.40.0480.050mg/KgMethyl tert-butyl ether (MTBE)70-130 2.6 20
0.054 1091040.0520.050mg/Kg4-Methyl-2-Pentanone 57-162 4.4 20
0.042 85.081.80.0400.050mg/KgMethylene Chloride 74-129 3.8 20
0.049 98.694.20.0470.050mg/KgNaphthalene 57-157 4.5 20
0.042 85.089.40.0440.050mg/Kgn-Propylbenzene 67-130 5.0 20
Page 19 of 35Date:10/21/2022 03:44 PM
Page 66 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V24921QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V24920
LCS-V24920 LCSD-V24920Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.047 95.696.00.0480.050mg/KgStyrene 77-121 0.4 20
0.045 90.493.40.0460.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 3.2 20
0.054 1081070.0530.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 1.4 20
0.044 89.690.60.0450.050mg/KgTetrachloroethene 68-130 1.1 20
0.047 95.495.20.0470.050mg/KgToluene 71-129 0.2 20
0.047 94.892.40.0460.050mg/Kg1,2,3-Trichlorobenzene 68-130 2.5 20
0.044 89.091.20.0450.050mg/Kg1,2,4-Trichlorobenzene 66-125 2.4 20
0.041 82.282.00.0410.050mg/Kg1,1,1-Trichloroethane 67-131 0.2 20
0.054 1081040.0510.050mg/Kg1,1,2-Trichloroethane 70-133 4.5 20
0.046 92.295.20.0470.050mg/KgTrichloroethene 75-133 3.2 20
0.036 72.075.80.0370.050mg/KgTrichlorofluoromethane 44-146 5.1 20
0.047 94.491.00.0450.050mg/Kg1,2,3-Trichloropropane 60-137 3.6 20
0.042 84.687.20.0430.050mg/Kg1,2,4-Trimethylbenzene 69-129 3.0 20
0.042 84.888.00.0440.050mg/Kg1,3,5-Trimethylbenzene 69-128 3.7 20
0.061 1231120.0550.050mg/KgVinyl Acetate 60-140 10.0 20
0.039 78.682.20.0410.050mg/KgVinyl Chloride 48-147 4.4 20
0.044 89.289.60.0440.050mg/Kgo-Xylene 74-126 0.4 20
0.088 88.690.20.0900.100mg/Kgm,p-Xylene 75-124 1.7 20
97.099.04-Bromofluorobenzene (S)70-130
10397.2Dibromofluoromethane (S)84-123
10097.6Toluene-d8 (S)76-129
Page 20 of 35Date:10/21/2022 03:44 PM
Page 67 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
Associated Lab Samples: 90146, 90150
LRB-V25072 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/17/22 13:100.6600.116<0.116mg/KgAcenaphthene
10/17/22 13:100.6600.105<0.105mg/KgAcenaphthylene
10/17/22 13:100.6600.152<0.152mg/KgAniline
10/17/22 13:100.6600.143<0.143mg/KgAnthracene
10/17/22 13:100.6600.139<0.139mg/KgBenzo(a)anthracene
10/17/22 13:100.6600.147<0.147mg/KgBenzo(a)pyrene
10/17/22 13:100.6600.146<0.146mg/KgBenzo(b)fluoranthene
10/17/22 13:100.6600.136<0.136mg/KgBenzo(g,h,i)perylene
10/17/22 13:100.6600.137<0.137mg/KgBenzo(k)fluoranthene
10/17/22 13:102.000.580<0.580mg/KgBenzoic Acid
10/17/22 13:100.6600.105<0.105mg/KgBenzyl alcohol
10/17/22 13:100.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane
10/17/22 13:100.6600.107<0.107mg/KgBis(2-Chloroethyl)ether
10/17/22 13:100.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether
10/17/22 13:100.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate
10/17/22 13:100.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether
10/17/22 13:100.3300.113<0.113mg/KgButyl benzyl phthalate
10/17/22 13:100.6600.092<0.092mg/Kg4-Chloro-3-methylphenol
10/17/22 13:100.3300.112<0.112mg/Kg4-Chloroaniline
10/17/22 13:100.6600.116<0.116mg/Kg2-Chloronaphthalene
10/17/22 13:100.6600.098<0.098mg/Kg2-Chlorophenol
10/17/22 13:101.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether
10/17/22 13:100.6600.142<0.142mg/KgChrysene
10/17/22 13:100.6600.230<0.230mg/KgDibenz(a,h)anthracene
10/17/22 13:100.6600.119<0.119mg/KgDibenzofuran
10/17/22 13:100.6600.094<0.094mg/Kg1,2-Dichlorobenzene
10/17/22 13:100.6600.097<0.097mg/Kg1,3-Dichlorobenzene
Page 21 of 35Date:10/21/2022 03:44 PM
Page 68 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
Associated Lab Samples: 90146, 90150
LRB-V25072 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/17/22 13:100.3300.097<0.097mg/Kg1,4-Dichlorobenzene
10/17/22 13:100.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine
10/17/22 13:100.6600.095<0.095mg/Kg2,4-Dichlorophenol
10/17/22 13:100.6600.180<0.180mg/KgDiethyl phthalate
10/17/22 13:100.6600.174<0.174mg/KgDimethyl phthalate
10/17/22 13:100.3300.108<0.108mg/Kg2,4-Dimethylphenol
10/17/22 13:100.6600.107<0.107mg/KgDi-n-butyl phthalate
10/17/22 13:101.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
10/17/22 13:101.500.520<0.520mg/Kg2,4-Dinitrophenol
10/17/22 13:100.6600.096<0.096mg/Kg2,4-Dinitrotoluene
10/17/22 13:100.6600.108<0.108mg/Kg2,6-Dinitrotoluene
10/17/22 13:100.3300.143<0.143mg/KgDi-n-Octyl Phthalate
10/17/22 13:100.6600.123<0.123mg/KgFluoranthene
10/17/22 13:100.6600.128<0.128mg/KgFluorene
10/17/22 13:100.6600.106<0.106mg/KgHexachlorobenzene
10/17/22 13:100.6600.097<0.097mg/KgHexachlorobutadiene
10/17/22 13:100.6600.157<0.157mg/KgHexachlorocyclopentadiene
10/17/22 13:100.6600.079<0.079mg/KgHexachloroethane
10/17/22 13:100.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
10/17/22 13:100.6600.191<0.191mg/KgIsophorone
10/17/22 13:100.6600.106<0.106mg/Kg1-Methylnaphthalene
10/17/22 13:100.6600.100<0.100mg/Kg2-Methylnaphthalene
10/17/22 13:100.6600.097<0.097mg/Kg2-Methylphenol
10/17/22 13:100.6600.084<0.084mg/Kg3&4 Methylphenol
10/17/22 13:100.6600.144<0.144mg/KgNaphthalene
10/17/22 13:100.6600.096<0.096mg/Kg2-Nitroaniline
10/17/22 13:100.6600.120<0.120mg/Kg3-Nitroaniline
Page 22 of 35Date:10/21/2022 03:44 PM
Page 69 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
Associated Lab Samples: 90146, 90150
LRB-V25072 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/17/22 13:100.3300.093<0.093mg/Kg4-Nitroaniline
10/17/22 13:100.3300.116<0.116mg/KgNitrobenzene
10/17/22 13:100.6600.088<0.088mg/Kg2-Nitrophenol
10/17/22 13:100.6600.117<0.117mg/Kg4-Nitrophenol
10/17/22 13:100.6600.263<0.263mg/KgN-Nitrosodimethylamine
10/17/22 13:100.6600.181<0.181mg/KgN-Nitrosodiphenylamine
10/17/22 13:100.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine
10/17/22 13:101.000.347<0.347mg/KgPentachlorophenol
10/17/22 13:100.6600.208<0.208mg/KgPhenanthrene
10/17/22 13:100.6600.112<0.112mg/KgPhenol
10/17/22 13:100.6600.134<0.134mg/KgPyrene
10/17/22 13:100.3300.079<0.079mg/KgPyridine
10/17/22 13:100.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene
10/17/22 13:100.6600.096<0.096mg/Kg2,4,5-Trichlorophenol
10/17/22 13:100.6600.096<0.096mg/Kg2,4,6-Trichlorophenol
10/17/22 13:102-Fluorobiphenyl (S)94.0 44-115
10/17/22 13:102-Fluorophenol (S)98.4 35-115
10/17/22 13:10Nitrobenzene-d5 (S)88.6 37-122
10/17/22 13:104-Terphenyl-d14 (S)102 54-127
10/17/22 13:102,4,6-Tribromophenol (S)108 39-132
10/17/22 13:10Phenol-d5 (S)92.7 34-121
LCS-V25072Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
98.21.641.67mg/KgAcenaphthene 40-123
98.21.641.67mg/KgAcenaphthylene 32-132
Page 23 of 35Date:10/21/2022 03:44 PM
Page 70 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
LCS-V25072Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1853.091.67mg/KgAniline 12-197
1011.691.67mg/KgAnthracene 47-123
1011.681.67mg/KgBenzo(a)anthracene 49-126
1272.121.67mg/KgBenzo(a)pyrene 45-129
1101.831.67mg/KgBenzo(b)fluoranthene 45-132
1141.901.67mg/KgBenzo(g,h,i)perylene 43-134
1081.811.67mg/KgBenzo(k)fluoranthene 47-132
73.01.221.67mg/KgBenzoic Acid 10-83
98.21.641.67mg/KgBenzyl alcohol 29-122
83.81.401.67mg/KgBis(2-Chloroethoxy)methane 36-121
77.81.301.67mg/KgBis(2-Chloroethyl)ether 31-120
83.21.391.67mg/KgBis(2-Chloroisopropyl)ether 33-131
1141.911.67mg/KgBis(2-ethylhexyl)phthalate 51-133
1031.721.67mg/Kg4-Bromophenyl phenyl ether 46-124
1141.911.67mg/KgButyl benzyl phthalate 48-132
91.61.531.67mg/Kg4-Chloro-3-methylphenol 45-122
88.01.471.67mg/Kg4-Chloroaniline 17-106
97.01.621.67mg/Kg2-Chloronaphthalene 41-114
91.01.521.67mg/Kg2-Chlorophenol 34-121
98.81.651.67mg/Kg4-Chlorophenyl phenyl ether 45-121
1051.751.67mg/KgChrysene 50-124
92.21.541.67mg/KgDibenz(a,h)anthracene 45-134
96.41.611.67mg/KgDibenzofuran 44-120
80.21.341.67mg/Kg1,2-Dichlorobenzene 33-117
79.61.331.67mg/Kg1,3-Dichlorobenzene 30-115
77.21.291.67mg/Kg1,4-Dichlorobenzene 31-115
82.61.381.67mg/Kg3,3'-Dichlorobenzidine 22-121
Page 24 of 35Date:10/21/2022 03:44 PM
Page 71 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
LCS-V25072Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
85.01.421.67mg/Kg2,4-Dichlorophenol 40-122
1081.801.67mg/KgDiethyl phthalate 50-124
1021.711.67mg/KgDimethyl phthalate 48-124
90.41.511.67mg/Kg2,4-Dimethylphenol 30-127
1111.851.67mg/KgDi-n-butyl phthalate 51-128
1051.751.67mg/Kg4,6-Dinitro-2-methylphenol 29-132
1202.011.67mg/Kg2,4-Dinitrophenol 27-129
1141.911.67mg/Kg2,4-Dinitrotoluene 48-126
1111.861.67mg/Kg2,6-Dinitrotoluene 46-124
1202.011.67mg/KgDi-n-Octyl Phthalate 45-140
1041.731.67mg/KgFluoranthene 50-127
1021.701.67mg/KgFluorene 43-125
1031.721.67mg/KgHexachlorobenzene 45-122
75.41.261.67mg/KgHexachlorobutadiene 32-123
82.61.381.67mg/KgHexachlorocyclopentadiene 32-117
74.81.251.67mg/KgHexachloroethane 28-117
1061.771.67mg/KgIndeno(1,2,3-cd)pyrene 45-133
81.41.361.67mg/KgIsophorone 30-122
84.41.411.67mg/Kg1-Methylnaphthalene 40-119
80.21.341.67mg/Kg2-Methylnaphthalene 38-122
94.61.581.67mg/Kg2-Methylphenol 32-122
84.41.411.67mg/Kg3&4 Methylphenol 34-119
76.61.281.67mg/KgNaphthalene 35-123
1021.711.67mg/Kg2-Nitroaniline 44-127
1041.731.67mg/Kg3-Nitroaniline 33-119
1081.811.67mg/Kg4-Nitroaniline 63-147
78.41.311.67mg/KgNitrobenzene 34-122
Page 25 of 35Date:10/21/2022 03:44 PM
Page 72 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
LCS-V25072Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
82.01.371.67mg/Kg2-Nitrophenol 36-123
1071.781.67mg/Kg4-Nitrophenol 30-132
51.90.8681.67mg/KgN-Nitrosodimethylamine 10-146
1222.031.67mg/KgN-Nitrosodiphenylamine 38-127
86.81.451.67mg/KgN-Nitroso-di-n-propylamine 36-120
1202.001.67mg/KgPentachlorophenol 25-133
98.81.651.67mg/KgPhenanthrene 50-121
91.61.531.67mg/KgPhenol 34-121
1021.711.67mg/KgPyrene 47-127
47.40.7931.67mg/KgPyridine 10-80
75.41.261.67mg/Kg1,2,4-Trichlorobenzene 34-118
97.01.621.67mg/Kg2,4,5-Trichlorophenol 41-124
1001.671.67mg/Kg2,4,6-Trichlorophenol 39-126
94.62-Fluorobiphenyl (S)44-115
91.52-Fluorophenol (S)35-115
74.2Nitrobenzene-d5 (S)37-122
1064-Terphenyl-d14 (S)54-127
1132,4,6-Tribromophenol (S)39-132
90.3Phenol-d5 (S)34-121
V 90095-MS-V25072 V 90095-MSD-V25072Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.61 96.41.551.671.67<0.116mg/KgAcenaphthene 92.8 40-123 3.7 20
1.61 96.41.551.671.67<0.105mg/KgAcenaphthylene 92.8 32-132 3.7 20
2.88 1722.491.671.67<0.152mg/KgAniline 149 12-197 14.5 20
Page 26 of 35Date:10/21/2022 03:44 PM
Page 73 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
V 90095-MS-V25072 V 90095-MSD-V25072Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.67 1001.681.671.67<0.143mg/KgAnthracene 101 47-123 0.5 20
1.65 98.81.641.671.67<0.139mg/KgBenzo(a)anthracene 98.2 49-126 0.6 20
2.02 1211.981.671.67<0.147mg/KgBenzo(a)pyrene 119 45-129 2.0 20
1.81 1081.781.671.67<0.146mg/KgBenzo(b)fluoranthene 107 45-132 1.6 20
1.82 1091.731.671.67<0.136mg/KgBenzo(g,h,i)perylene 104 43-134 5.0 20
1.74 1041.661.671.67<0.137mg/KgBenzo(k)fluoranthene 99.4 47-132 4.7 20
0.754 45.11.091.671.67<0.580mg/KgBenzoic Acid 65.2 10-83 36.4*20
1.60 95.81.541.671.67<0.105mg/KgBenzyl alcohol 92.2 29-122 3.8 20
1.34 80.21.291.671.67<0.118mg/KgBis(2-Chloroethoxy)methane 77.2 36-121 3.8 20
1.07 64.01.241.671.67<0.107mg/KgBis(2-Chloroethyl)ether 74.2 31-120 14.7 20
1.25 74.81.211.671.67<0.136mg/KgBis(2-Chloroisopropyl)ether 72.4 33-131 3.2 20
1.90 1141.861.671.67<0.120mg/KgBis(2-ethylhexyl)phthalate 111 51-133 2.1 20
1.72 1031.701.671.67<0.109mg/Kg4-Bromophenyl phenyl ether 102 46-124 1.1 20
1.81 1081.741.671.67<0.113mg/KgButyl benzyl phthalate 104 48-132 3.9 20
1.45 86.81.411.671.67<0.092mg/Kg4-Chloro-3-methylphenol 84.4 45-122 2.7 20
1.44 86.21.341.671.67<0.112mg/Kg4-Chloroaniline 80.2 17-106 7.1 20
1.55 92.81.461.671.67<0.116mg/Kg2-Chloronaphthalene 87.4 41-114 5.9 20
1.40 83.81.401.671.67<0.098mg/Kg2-Chlorophenol 83.8 34-121 0.0 20
1.63 97.61.601.671.67<0.126mg/Kg4-Chlorophenyl phenyl ether 95.8 45-121 1.8 20
1.73 1041.681.671.67<0.142mg/KgChrysene 101 50-124 2.9 20
1.56 93.41.501.671.67<0.230mg/KgDibenz(a,h)anthracene 89.8 45-134 3.9 20
1.60 95.81.561.671.67<0.119mg/KgDibenzofuran 93.4 44-120 2.5 20
1.19 71.21.231.671.67<0.094mg/Kg1,2-Dichlorobenzene 73.6 33-117 3.3 20
1.13 67.61.201.671.67<0.097mg/Kg1,3-Dichlorobenzene 71.8 30-115 6.0 20
1.13 67.61.181.671.67<0.097mg/Kg1,4-Dichlorobenzene 70.6 31-115 4.3 20
1.54 92.21.491.671.67<0.147mg/Kg3,3'-Dichlorobenzidine 89.2 22-121 3.3 20
Page 27 of 35* QC Fail Date:10/21/2022 03:44 PM
Page 74 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
V 90095-MS-V25072 V 90095-MSD-V25072Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.41 84.41.341.671.67<0.095mg/Kg2,4-Dichlorophenol 80.2 40-122 5.0 20
1.76 1051.741.671.67<0.180mg/KgDiethyl phthalate 104 50-124 1.1 20
1.68 1011.651.671.67<0.174mg/KgDimethyl phthalate 98.8 48-124 1.8 30
1.49 89.21.411.671.67<0.108mg/Kg2,4-Dimethylphenol 84.4 30-127 5.5 20
1.91 1141.921.671.67<0.107mg/KgDi-n-butyl phthalate 115 51-128 0.5 20
1.64 98.21.611.671.67<0.240mg/Kg4,6-Dinitro-2-methylphenol 96.4 29-132 1.8 20
1.57 94.01.681.671.67<0.520mg/Kg2,4-Dinitrophenol 101 27-129 6.7 20
1.84 1101.841.671.67<0.096mg/Kg2,4-Dinitrotoluene 110 48-126 0.0 20
1.88 1131.841.671.67<0.108mg/Kg2,6-Dinitrotoluene 110 46-124 2.1 20
1.93 1161.851.671.67<0.143mg/KgDi-n-Octyl Phthalate 111 45-140 4.2 20
1.72 1031.711.671.67<0.123mg/KgFluoranthene 102 50-127 0.5 20
1.66 99.41.601.671.67<0.128mg/KgFluorene 95.8 43-125 3.6 20
1.73 1041.761.671.67<0.106mg/KgHexachlorobenzene 105 45-122 1.7 20
1.19 71.21.131.671.67<0.097mg/KgHexachlorobutadiene 67.6 32-123 5.1 20
1.29 77.21.001.671.67<0.157mg/KgHexachlorocyclopentadiene 59.8 32-117 25.3*20
1.09 65.21.121.671.67<0.079mg/KgHexachloroethane 67.0 28-117 2.7 20
1.74 1041.711.671.67<0.179mg/KgIndeno(1,2,3-cd)pyrene 102 45-133 1.7 20
1.32 79.01.231.671.67<0.191mg/KgIsophorone 73.6 30-122 7.0 20
1.34 80.21.281.671.67<0.106mg/Kg1-Methylnaphthalene 76.6 40-119 4.5 20
1.28 76.61.221.671.67<0.100mg/Kg2-Methylnaphthalene 73.0 38-122 4.8 20
1.49 89.21.451.671.67<0.097mg/Kg2-Methylphenol 86.8 32-122 2.7 20
1.35 80.81.321.671.67<0.084mg/Kg3&4 Methylphenol 79.0 34-119 2.2 20
1.23 73.61.171.671.67<0.144mg/KgNaphthalene 70.0 35-123 5.0 20
1.68 1011.611.671.67<0.096mg/Kg2-Nitroaniline 96.4 44-127 4.2 20
1.64 98.21.651.671.67<0.120mg/Kg3-Nitroaniline 98.8 33-119 0.6 20
1.76 1051.721.671.67<0.093mg/Kg4-Nitroaniline 103 63-147 2.2 20
Page 28 of 35* QC Fail Date:10/21/2022 03:44 PM
Page 75 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V25262QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V25072
V 90095-MS-V25072 V 90095-MSD-V25072Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.24 74.21.171.671.67<0.116mg/KgNitrobenzene 70.0 34-122 5.8 20
1.30 77.81.251.671.67<0.088mg/Kg2-Nitrophenol 74.8 32-123 3.9 20
1.69 1011.651.671.67<0.117mg/Kg4-Nitrophenol 98.8 30-132 2.3 20
0.971 58.10.9041.671.67<0.263mg/KgN-Nitrosodimethylamine 54.1 10-146 7.1 30
1.99 1191.981.671.67<0.181mg/KgN-Nitrosodiphenylamine 119 38-127 0.5 20
1.38 82.61.371.671.67<0.118mg/KgN-Nitroso-di-n-propylamine 82.0 36-120 0.7 20
1.92 1151.931.671.67<0.347mg/KgPentachlorophenol 116 25-133 0.5 20
1.67 1001.651.671.67<0.208mg/KgPhenanthrene 98.8 50-121 1.2 20
1.44 86.21.401.671.67<0.112mg/KgPhenol 83.8 34-121 2.8 20
1.70 1021.661.671.67<0.134mg/KgPyrene 99.4 47-127 2.3 20
0.697 41.70.6841.671.67<0.079mg/KgPyridine 40.9 10-80 1.8 20
1.20 71.81.161.671.67<0.107mg/Kg1,2,4-Trichlorobenzene 69.4 34-118 3.3 20
1.62 97.01.561.671.67<0.096mg/Kg2,4,5-Trichlorophenol 93.4 41-124 3.7 20
1.63 97.61.581.671.67<0.096mg/Kg2,4,6-Trichlorophenol 94.6 39-126 3.1 20
92.82-Fluorobiphenyl (S)86.2 44-115
86.12-Fluorophenol (S)84.0 35-115
70.6Nitrobenzene-d5 (S)65.8 37-122
1044-Terphenyl-d14 (S)101 54-127
1122,4,6-Tribromophenol (S)111 39-132
85.5Phenol-d5 (S)81.9 34-121
Page 29 of 35Date:10/21/2022 03:44 PM
Page 76 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V24889QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V24877
Associated Lab Samples: 90151
LRB-V24877 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
10/10/22 10:230.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V24877 LCSD-V24877Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.231 92.488.80.2220.250µg/L1,2-Dibromoethane 70-130 3.9 20.0
Page 30 of 35Date:10/21/2022 03:44 PM
Page 77 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V25086QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V24998
Associated Lab Samples: 90151
LRB-V24998 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/13/22 11:3335028.2<28.2µg/LAliphatic C9-C18
10/13/22 11:33500124<124µg/LAliphatic C19-C36
10/13/22 11:3325061.2<61.2µg/LAromatic C11-C22
10/13/22 11:332-Fluorobiphenyl (S)102 40-140
10/13/22 11:332-Bromonaphthalene (S)100 40-140
10/13/22 11:33Chlorooctadecane (S)86.5 40-140
10/13/22 11:33OTP Surrogate (S)80.5 40-140
LCS-V24998 LCSD-V24998Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
370 61.662.5375600µg/LAliphatic C9-C18 40-140 1.3 50.0
606 75.780.6645800µg/LAliphatic C19-C36 40-140 6.2 50.0
1710 10185.214501700µg/LAromatic C11-C22 40-140 16.4 50.0
10697.52-Fluorobiphenyl (S)40-140
1091012-Bromonaphthalene (S)40-140
80.585.5Chlorooctadecane (S)40-140
85.079.5OTP Surrogate (S)40-140
Page 31 of 35Date:10/21/2022 03:44 PM
Page 78 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V25109QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V25038
Associated Lab Samples: 90146, 90150
LRB-V25038 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/13/22 17:0050.09.20<9.20mg/KgAliphatic C9-C18
10/13/22 17:0050.012.2<12.2mg/KgAliphatic C19-C36
10/13/22 17:0050.014.2<14.2mg/KgAromatic C11-C22
10/13/22 17:002-Fluorobiphenyl (S)107 40-140
10/13/22 17:002-Bromonaphthalene (S)109 40-140
10/13/22 17:00Chlorooctadecane (S)84.5 40-140
10/13/22 17:00OTP Surrogate (S)89.5 40-140
LCS-V25038 LCSD-V25038Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
40.2 67.069.841.960.0mg/KgAliphatic C9-C18 40-140 4.1 50
74.3 92.892.173.780.0mg/KgAliphatic C19-C36 40-140 0.8 50
169 99.498.2167170mg/KgAromatic C11-C22 40-140 1.1 50
11299.02-Fluorobiphenyl (S)40-140
1131032-Bromonaphthalene (S)40-140
95.597.5Chlorooctadecane (S)40-140
91.088.5OTP Surrogate (S)40-140
Page 32 of 35Date:10/21/2022 03:44 PM
Page 79 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V24912QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V24911
Associated Lab Samples: 90151
LRB-V24911 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/10/22 13:5850.011.5<11.5µg/LAliphatic C5-C8
10/10/22 13:5850.025.8<25.8µg/LAliphatic C9-C12
10/10/22 13:5850.04.02<4.02µg/LAromatic C9-C10
10/10/22 13:582,5-Dibromotoluene (FID) (S)89.3 70-130
10/10/22 13:582,5-Dibromotoluene (PID) (S)88.9 70-130
LCS-V24911 LCSD-V24911Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
339 113112337300µg/LAliphatic C5-C8 70-130 0.5 50.0
355 118118353300µg/LAliphatic C9-C12 70-130 0.5 50.0
112 112117117100µg/LAromatic C9-C10 70-130 4.3 50.0
80.389.32,5-Dibromotoluene (FID) (S)70-130
75.680.82,5-Dibromotoluene (PID) (S)70-130
Page 33 of 35Date:10/21/2022 03:44 PM
Page 80 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V24916QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V24915
Associated Lab Samples: 90146, 90147, 90148, 90149, 90150
LRB-V24915 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
10/10/22 16:448.001.22<1.22mg/KgAliphatic C5-C8
10/10/22 16:448.004.56<4.56mg/KgAliphatic C9-C12
10/10/22 16:448.000.624<0.624mg/KgAromatic C9-C10
10/10/22 16:442,5-Dibromotoluene (FID) (S)107 70-130
10/10/22 16:442,5-Dibromotoluene (PID) (S)97.1 70-130
LCS-V24915 LCSD-V24915Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
39.4 12312339.432.0mg/KgAliphatic C5-C8 70-130 0.0 50
38.1 11912138.832.0mg/KgAliphatic C9-C12 70-130 1.8 50
12.3 11510811.610.7mg/KgAromatic C9-C10 70-130 5.8 50
94.391.42,5-Dibromotoluene (FID) (S)70-130
98.192.02,5-Dibromotoluene (PID) (S)70-130
Page 34 of 35Date:10/21/2022 03:44 PM
Page 81 of 84
Quality Control Data
22-280-0004Report No:
Project Description:
Client ID:Geological Resources, Inc.
Meley Grocery
Dry Weight Determination
SW-DRYWT
V25055QC Analytical Batch:
Analysis Method:
Analysis Description:
V 90098-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 10/13/22 10:006.324.422.9%Moisture
V 90146-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 10/13/22 10:000.712.612.7%Moisture
Page 35 of 35Date:10/21/2022 03:44 PM
Page 82 of 84
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-280-0004
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 2.2C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:10/07/2022 11:22:49
Special precautions or instructions included?
Comments:
Page 83 of 84
Page 84 of 84

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

2/9/2023
Geological Resources, Inc. Scott Driscoll
113 W. Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 23-030-0002 Client Project Description: Merry Grocery
GRI #5947
Dear Scott Driscoll:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 1/27/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 109
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-030-0002
Page 2 of 109
Report Number:
Sample Summary Table
Client Project Description:
23-030-0002
Merry Grocery
GRI #5947
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
01/26/2023 11:10Aqueous 98594 GMW-2 01/27/2023 16:52
01/26/2023 11:10Aqueous 98594 GMW-2 01/27/2023 16:52 6010D Eurofins -
01/26/2023Aqueous 98595 GMW-3 01/27/2023 16:52
01/26/2023Aqueous 98595 GMW-3 01/27/2023 16:52 6010D Eurofins -
01/26/2023Aqueous 98596 GMW-4 01/27/2023 16:52
01/26/2023Aqueous 98596 GMW-4 01/27/2023 16:52 6010D Eurofins -
01/26/2023Aqueous 98597 GMW-5 01/27/2023 16:52
01/26/2023Aqueous 98597 GMW-5 01/27/2023 16:52 6010D Eurofins -
01/26/2023 08:00Aqueous 98598 TB 01/27/2023 16:52
01/26/2023 08:55Solids 98599 GM2-2-SS-4'01/27/2023 16:52
Eurofins - Savannah: Eurofins Environmental Testing Southeast, Savannah, Savannah, GA
Page 3 of 109
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-030-0002
Report Limit
Project:Merry Grocery
V 98594GMW-2
12.2 02/01/2023 06:336200BAcetoneµg/L 1.80
67.2 02/01/2023 06:336200BBenzeneµg/L 0.180
0.643 02/01/2023 06:336200Bn-Butylbenzene µg/L 0.180
2.69 02/01/2023 06:336200BChlorodibromomethaneµg/L 0.190
30.9 02/01/2023 06:336200BDi-Isopropyl Ether (DIPE)µg/L 0.500
13.7 02/01/2023 06:336200BEthylbenzeneµg/L 0.170
2.55 02/01/2023 06:336200BIsopropylbenzeneµg/L 0.180
14.9 02/01/2023 06:336200BMethyl tert-butyl ether (MTBE)µg/L 0.140
11.1 02/01/2023 06:336200BNaphthaleneµg/L 0.470
3.17 02/01/2023 06:336200Bn-Propylbenzene µg/L 0.190
206 02/02/2023 20:136200Btert-Butyl Alcohol (TBA)µg/L 16.0
462 02/02/2023 20:136200Btert-Amyl Alcohol (TAA)µg/L 19.0
J3.05 02/01/2023 06:336200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
3.68 02/01/2023 06:336200BTolueneµg/L 0.220
22.4 02/01/2023 06:336200B1,2,4-Trimethylbenzene µg/L 0.190
0.540 02/01/2023 06:336200B1,3,5-Trimethylbenzene µg/L 0.180
1.57 02/01/2023 06:336200Bo-Xylene µg/L 0.210
23.1 02/01/2023 06:336200Bm,p-Xylene µg/L 0.420
24.7 02/01/2023 06:336200BXylene (Total)µg/L 0.210
4.99 02/02/2023 13:42625.1 Naphthalene µg/L 0.771
120 01/31/2023 13:23CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
135 01/31/2023 13:23CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
111 01/31/2023 13:23CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
191 01/31/2023 13:23MADEP-VPH Aliphatic C5-C8 µg/L 11.5
284 01/31/2023 13:23MADEP-VPH Aliphatic C9-C12 µg/L 25.8
111 01/31/2023 13:23MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 98595GMW-3
14.5 02/02/2023 15:196200BAcetoneµg/L 1.80
J2.55 02/02/2023 15:196200Btert-Butyl Alcohol (TBA)µg/L 1.60
J0.255 02/02/2023 15:196200Bo-Xylene µg/L 0.210
J0.511 02/02/2023 15:196200Bm,p-Xylene µg/L 0.420
J0.766 02/02/2023 15:196200BXylene (Total)µg/L 0.210
V 98596GMW-4
0.659 02/02/2023 15:446200BBenzeneµg/L 0.180
2.30 02/02/2023 15:446200BBromodichloromethaneµg/L 0.160
0.815 02/02/2023 15:446200Bn-Butylbenzene µg/L 0.180
Page 4 of 109
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-030-0002
Report Limit
Project:Merry Grocery
V 98596GMW-4
1.51 02/02/2023 15:446200BChlorodibromomethaneµg/L 0.190
1.86 02/02/2023 15:446200BChloroformµg/L 0.220
1.91 02/02/2023 15:446200BEthylbenzeneµg/L 0.170
J0.777 02/02/2023 15:446200B2-Hexanone µg/L 0.380
J0.239 02/02/2023 15:446200BIsopropylbenzeneµg/L 0.180
J0.363 02/02/2023 15:446200B4-Methyl-2-Pentanone µg/L 0.078
0.957 02/02/2023 15:446200Bn-Propylbenzene µg/L 0.190
J3.89 02/02/2023 15:446200Btert-Butyl Alcohol (TBA)µg/L 1.60
2.73 02/02/2023 15:446200BTolueneµg/L 0.220
5.63 02/02/2023 15:446200B1,2,4-Trimethylbenzene µg/L 0.190
1.76 02/02/2023 15:446200B1,3,5-Trimethylbenzene µg/L 0.180
2.23 02/02/2023 15:446200Bo-Xylene µg/L 0.210
6.39 02/02/2023 15:446200Bm,p-Xylene µg/L 0.420
8.62 02/02/2023 15:446200BXylene (Total)µg/L 0.210
J59.2 01/31/2023 14:11CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J11.0 01/31/2023 14:11CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
80.7 01/31/2023 14:11MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J11.0 01/31/2023 14:11MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 98597GMW-5
4880 02/03/2023 18:576200BBenzeneµg/L 18.0
34.8 02/02/2023 19:006200Bn-Butylbenzene µg/L 0.180
16.9 02/02/2023 19:006200Bsec-Butyl benzene µg/L 0.200
J1.16 02/02/2023 19:006200Btert-Butyl benzene µg/L 0.920
15.9 02/02/2023 19:006200BDi-Isopropyl Ether (DIPE)µg/L 0.500
J0.215 02/02/2023 19:006200B1,4-Dichlorobenzene µg/L 0.210
1880 02/03/2023 18:576200BEthylbenzeneµg/L 17.0
6.99 02/02/2023 19:006200B2-Hexanone µg/L 0.380
75.1 02/02/2023 19:006200BIsopropylbenzeneµg/L 0.180
10.2 02/02/2023 19:006200B4-Isopropyl toluene µg/L 0.089
1.77 02/02/2023 19:006200BMethyl tert-butyl ether (MTBE)µg/L 0.140
6.33 02/02/2023 19:006200B4-Methyl-2-Pentanone µg/L 0.078
504 02/03/2023 18:576200BNaphthaleneµg/L 47.0
293 02/03/2023 18:576200Bn-Propylbenzene µg/L 19.0
73.8 02/02/2023 19:006200BStyreneµg/L 0.220
35.2 02/02/2023 19:006200Btert-Butyl Alcohol (TBA)µg/L 1.60
2060 02/03/2023 18:576200Btert-Amyl Alcohol (TAA)µg/L 190
Page 5 of 109
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-030-0002
Report Limit
Project:Merry Grocery
V 98597GMW-5
14.7 02/02/2023 19:006200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
8300 02/03/2023 18:576200BTolueneµg/L 22.0
2200 02/03/2023 18:576200B1,2,4-Trimethylbenzene µg/L 19.0
589 02/03/2023 18:576200B1,3,5-Trimethylbenzene µg/L 18.0
3100 02/03/2023 18:576200Bo-Xylene µg/L 21.0
7080 02/03/2023 18:576200Bm,p-Xylene µg/L 42.0
10200 02/03/2023 18:576200BXylene (Total)µg/L 21.0
7320 02/01/2023 10:06CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 1150
11400 02/01/2023 10:06CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 2580
6490 02/01/2023 10:06CALCULATIONAromatic C9-C10 (Adjusted)µg/L 402
4.14 02/02/2023 09:23EPA-504.1 1,2-Dibromoethane µg/L 0.0168
20500 02/01/2023 10:06MADEP-VPH Aliphatic C5-C8 µg/L 1150
29900 02/01/2023 10:06MADEP-VPH Aliphatic C9-C12 µg/L 2580
6490 02/01/2023 10:06MADEP-VPH Aromatic C9-C10 µg/L 402
V 98599GM2-2-SS-4'
J0.019 01/30/2023 19:168260DAcetonemg/Kg - dry 0.002
J0.198 02/06/2023 18:408270EAnthracenemg/Kg - dry 0.151
2.57 02/06/2023 18:408270EBenzo(a)anthracene mg/Kg - dry 0.147
3.82 02/06/2023 18:408270EBenzo(a)pyrene mg/Kg - dry 0.155
5.85 02/06/2023 18:408270EBenzo(b)fluoranthene mg/Kg - dry 0.154
3.37 02/06/2023 18:408270EBenzo(g,h,i)perylene mg/Kg - dry 0.143
2.02 02/06/2023 18:408270EBenzo(k)fluoranthene mg/Kg - dry 0.144
3.65 02/06/2023 18:408270EChrysenemg/Kg - dry 0.150
0.737 02/06/2023 18:408270EDibenz(a,h)anthracene mg/Kg - dry 0.243
5.49 02/06/2023 18:408270EFluoranthenemg/Kg - dry 0.130
3.70 02/06/2023 18:408270EIndeno(1,2,3-cd)pyrene mg/Kg - dry 0.189
2.04 02/06/2023 18:408270EPhenanthrenemg/Kg - dry 0.220
5.02 02/06/2023 18:408270EPyrenemg/Kg - dry 0.141
J43.4 02/07/2023 13:10MADEP-EPH Aromatic C11-C22 mg/Kg - dry 15.0
5.46 02/01/2023 16:54SW-DRYWT Moisture %
Page 6 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 02/01/23 06:33 6200BMSA
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: Dibromofluoromethane 96.2 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: Toluene-d8 97.4 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%02/02/23 20:1310 MSA V29470
Surrogate: Dibromofluoromethane 99.2 Limits: 70-130%02/02/23 20:1310 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 94.0 Limits: 70-130%02/02/23 20:1310 MSA V29470
Surrogate: Toluene-d8 99.8 Limits: 70-130%02/02/23 20:1310 MSA V29470
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29383 01/31/23 14:00 V29469 02/02/23 09:00
12.2 µg/L 1.80 10.0Acetone 1 02/01/23 06:33 V29384MSA
67.2 µg/L 0.180 0.500Benzene 1 02/01/23 06:33 V29384MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 02/01/23 06:33 V29384MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 02/01/23 06:33 V29384MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 02/01/23 06:33 V29384MSA
<1.50 µg/L 1.50 5.00Bromoform 1 02/01/23 06:33 V29384MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 02/01/23 06:33 V29384MSA
0.643 µg/L 0.180 0.500n-Butylbenzene 1 02/01/23 06:33 V29384MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 02/01/23 06:33 V29384MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 02/01/23 06:33 V29384MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/01/23 06:33 V29384MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 02/01/23 06:33 V29384MSA
2.69 µg/L 0.190 0.500Chlorodibromomethane 1 02/01/23 06:33 V29384MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 02/01/23 06:33 V29384MSA
<0.220 µg/L 0.220 0.500Chloroform 1 02/01/23 06:33 V29384MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 02/01/23 06:33 V29384MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/01/23 06:33 V29384MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/01/23 06:33 V29384MSA
30.9 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/01/23 06:33 V29384MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/01/23 06:33 V29384MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 02/01/23 06:33 V29384MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/01/23 06:33 V29384MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29383 01/31/23 14:00 V29469 02/02/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/01/23 06:33 V29384MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/01/23 06:33 V29384MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/01/23 06:33 V29384MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/01/23 06:33 V29384MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/01/23 06:33 V29384MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/01/23 06:33 V29384MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/01/23 06:33 V29384MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 02/01/23 06:33 V29384MSA
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 02/01/23 06:33 V29384MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/01/23 06:33 V29384MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/01/23 06:33 V29384MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/01/23 06:33 V29384MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/01/23 06:33 V29384MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/01/23 06:33 V29384MSA
<42.0 µg/L 42.0 200Ethanol 1 02/01/23 06:33 V29384MSA
13.7 µg/L 0.170 0.500
Ethylbenzene 1 02/01/23 06:33 V29384MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/01/23 06:33 V29384MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 02/01/23 06:33 V29384MSA
2.55 µg/L 0.180 0.500Isopropylbenzene 1 02/01/23 06:33 V29384MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 02/01/23 06:33 V29384MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/01/23 06:33 V29384MSA
14.9 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/01/23 06:33 V29384MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29383 01/31/23 14:00 V29469 02/02/23 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/01/23 06:33 V29384MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 02/01/23 06:33 V29384MSA
11.1 µg/L 0.470 1.00Naphthalene 1 02/01/23 06:33 V29384MSA
3.17 µg/L 0.190 0.500n-Propylbenzene 1 02/01/23 06:33 V29384MSA
<0.220 µg/L 0.220 0.500Styrene 1 02/01/23 06:33 V29384MSA
206 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 02/02/23 20:13 V29470MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 02/01/23 06:33 V29384MSA
462 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 02/02/23 20:13 V29470MSA
3.05 J
µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 02/01/23 06:33 V29384MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/01/23 06:33 V29384MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/01/23 06:33 V29384MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 02/01/23 06:33 V29384MSA
3.68 µg/L 0.220 0.500Toluene 1 02/01/23 06:33 V29384MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/01/23 06:33 V29384MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/01/23 06:33 V29384MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/01/23 06:33 V29384MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/01/23 06:33 V29384MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 02/01/23 06:33 V29384MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 02/01/23 06:33 V29384MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/01/23 06:33 V29384MSA
22.4 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 02/01/23 06:33 V29384MSA
0.540 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 02/01/23 06:33 V29384MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29383 01/31/23 14:00 V29469 02/02/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/01/23 06:33 V29384MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/01/23 06:33 V29384MSA
1.57 µg/L 0.210 0.500o-Xylene 1 02/01/23 06:33 V29384MSA
23.1 µg/L 0.420 1.00m,p-Xylene 1 02/01/23 06:33 V29384MSA
24.7 µg/L 0.210 0.500Xylene (Total)1 02/01/23 06:33 V29384KCC
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: Dibromofluoromethane 96.2 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: Toluene-d8 97.4 Limits: 70-130%02/01/23 06:331 MSA V29384
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%02/02/23 20:1310 MSA V29470
Surrogate: Dibromofluoromethane 99.2 Limits: 70-130%02/02/23 20:1310 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 94.0 Limits: 70-130%02/02/23 20:1310 MSA V29470
Surrogate: Toluene-d8 99.8 Limits: 70-130%02/02/23 20:1310 MSA V29470
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V29366 02/01/23 09:06
<0.320 µg/L 0.320 2.12
Acenaphthene 1 02/02/23 13:42 V29518JMV
<0.314 µg/L 0.314 2.12Acenaphthylene 1 02/02/23 13:42 V29518JMV
<0.886 µg/L 0.886 2.12Anthracene 1 02/02/23 13:42 V29518JMV
<1.40 µg/L 1.40 10.6Benzidine 1 02/02/23 13:42 V29518JMV
<0.675 µg/L 0.675 2.12Benzo(a)anthracene 1 02/02/23 13:42 V29518JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V29366 02/01/23 09:06
<1.08 µg/L 1.08 2.12Benzo(a)pyrene 1 02/02/23 13:42 V29518JMV
<2.63 µg/L 2.63 5.29Benzo(b)fluoranthene 1 02/02/23 13:42 V29518JMV
<1.07 µg/L 1.07 5.29Benzo(g,h,i)perylene 1 02/02/23 13:42 V29518JMV
<2.11 µg/L 2.11 5.29Benzo(k)fluoranthene 1 02/02/23 13:42 V29518JMV
<1.17 µg/L 1.17 10.6Benzoic Acid 1 02/02/23 13:42 V29518JMV
<0.723 µg/L 0.723 5.29Benzyl alcohol 1 02/02/23 13:42 V29518JMV
<0.495 µg/L 0.495 5.29Bis(2-Chloroethoxy)methane 1 02/02/23 13:42 V29518JMV
<1.10 µg/L 1.10 5.29Bis(2-Chloroethyl)ether 1 02/02/23 13:42 V29518JMV
<1.14 µg/L 1.14 5.29
Bis(2-Chloroisopropyl)ether 1 02/02/23 13:42 V29518JMV
<3.67 µg/L 3.67 10.6Bis(2-ethylhexyl)phthalate 1 02/02/23 13:42 V29518JMV
<1.17 µg/L 1.17 5.294-Bromophenyl phenyl ether 1 02/02/23 13:42 V29518JMV
<1.94 µg/L 1.94 5.29Butyl benzyl phthalate 1 02/02/23 13:42 V29518JMV
<1.25 µg/L 1.25 5.294-Chloro-3-methylphenol 1 02/02/23 13:42 V29518JMV
<7.82 µg/L 7.82 21.22-Chloronaphthalene 1 02/02/23 13:42 V29518JMV
<0.994 µg/L 0.994 10.62-Chlorophenol 1 02/02/23 13:42 V29518JMV
<1.81 µg/L 1.81 5.29
4-Chlorophenyl phenyl ether 1 02/02/23 13:42 V29518JMV
<0.429 µg/L 0.429 2.12Chrysene 1 02/02/23 13:42 V29518JMV
<0.460 µg/L 0.460 2.12Dibenz(a,h)anthracene 1 02/02/23 13:42 V29518JMV
<0.905 µg/L 0.905 5.29Dibenzofuran 1 02/02/23 13:42 V29518JMV
<2.12 µg/L 2.12 5.291,2-Dichlorobenzene 1 02/02/23 13:42 V29518JMV
<2.12 µg/L 2.12 5.291,3-Dichlorobenzene 1 02/02/23 13:42 V29518JMV
<2.17 µg/L 2.17 5.291,4-Dichlorobenzene 1 02/02/23 13:42 V29518JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V29366 02/01/23 09:06
<2.00 µg/L 2.00 5.293,3'-Dichlorobenzidine 1 02/02/23 13:42 V29518JMV
<1.55 µg/L 1.55 10.62,4-Dichlorophenol 1 02/02/23 13:42 V29518JMV
<0.788 µg/L 0.788 5.29Diethyl phthalate 1 02/02/23 13:42 V29518JMV
<0.993 µg/L 0.993 5.29Dimethyl phthalate 1 02/02/23 13:42 V29518JMV
<1.66 µg/L 1.66 21.22,4-Dimethylphenol 1 02/02/23 13:42 V29518JMV
<2.18 µg/L 2.18 5.29Di-n-butyl phthalate 1 02/02/23 13:42 V29518JMV
<2.19 µg/L 2.19 10.64,6-Dinitro-2-methylphenol 1 02/02/23 13:42 V29518JMV
<2.04 µg/L 2.04 10.62,4-Dinitrophenol 1 02/02/23 13:42 V29518JMV
<1.17 µg/L 1.17 5.29
2,4-Dinitrotoluene 1 02/02/23 13:42 V29518JMV
<0.855 µg/L 0.855 5.292,6-Dinitrotoluene 1 02/02/23 13:42 V29518JMV
<1.75 µg/L 1.75 5.29Di-n-Octyl Phthalate 1 02/02/23 13:42 V29518JMV
<0.265 µg/L 0.265 2.12Fluoranthene 1 02/02/23 13:42 V29518JMV
<0.855 µg/L 0.855 2.12Fluorene 1 02/02/23 13:42 V29518JMV
<1.04 µg/L 1.04 5.29Hexachlorobenzene 1 02/02/23 13:42 V29518JMV
<2.89 µg/L 2.89 5.29Hexachlorobutadiene 1 02/02/23 13:42 V29518JMV
<2.17 µg/L 2.17 5.29
Hexachlorocyclopentadiene 1 02/02/23 13:42 V29518JMV
<1.86 µg/L 1.86 5.29Hexachloroethane 1 02/02/23 13:42 V29518JMV
<0.505 µg/L 0.505 2.12Indeno(1,2,3-cd)pyrene 1 02/02/23 13:42 V29518JMV
<0.469 µg/L 0.469 5.29Isophorone 1 02/02/23 13:42 V29518JMV
4.99 µg/L 0.771 2.12Naphthalene 1 02/02/23 13:42 V29518JMV
<0.957 µg/L 0.957 5.29Nitrobenzene 1 02/02/23 13:42 V29518JMV
<0.521 µg/L 0.521 5.292-Nitrophenol 1 02/02/23 13:42 V29518JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
625.1 (Prep)
625.1 Prep Batch(es):V29366 02/01/23 09:06
<1.30 µg/L 1.30 10.64-Nitrophenol 1 02/02/23 13:42 V29518JMV
<1.16 µg/L 1.16 5.29N-Nitrosodiphenylamine 1 02/02/23 13:42 V29518JMV
<0.678 µg/L 0.678 5.29N-Nitroso-di-n-propylamine 1 02/02/23 13:42 V29518JMV
<1.51 µg/L 1.51 5.29Pentachlorophenol 1 02/02/23 13:42 V29518JMV
<0.453 µg/L 0.453 2.12Phenanthrene 1 02/02/23 13:42 V29518JMV
<0.688 µg/L 0.688 5.29Phenol 1 02/02/23 13:42 V29518JMV
<0.460 µg/L 0.460 2.12Pyrene 1 02/02/23 13:42 V29518JMV
<2.34 µg/L 2.34 5.291,2,4-Trichlorobenzene 1 02/02/23 13:42 V29518JMV
<1.40 µg/L 1.40 5.29
2,4,6-Trichlorophenol 1 02/02/23 13:42 V29518JMV
625.1Surrogate: Phenol-d5 24.9 Limits: 10-63%02/02/23 13:421 JMV
Surrogate: 2-Fluorobiphenyl 74.1 Limits: 49-118%02/02/23 13:421 JMV V29518
Surrogate: 2-Fluorophenol 35.9 Limits: 22-84%02/02/23 13:421 JMV V29518
Surrogate: Nitrobenzene-d5 77.1 Limits: 43-123%02/02/23 13:421 JMV V29518
Surrogate: 4-Terphenyl-d14 92.2 Limits: 49-151%02/02/23 13:421 JMV V29518
Surrogate: 2,4,6-Tribromophenol 85.8 Limits: 31-144%02/02/23 13:421 JMV V29518
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V29336 02/01/23 10:23
<0.00340 µg/L 0.00340 0.0206
1,2-Dibromoethane 1 02/01/23 18:34 V29367AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
120 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/31/23 13:23
135 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 01/31/23 13:23
111 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 01/31/23 13:23
<63.4 µg/L 63.4 259Aromatic C11-C22 (Adjusted)1 02/03/23 17:24
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V29399 02/02/23 08:41
<29.2 µg/L 29.2 363Aliphatic C9-C18 1 02/03/23 17:24 V29483AMP
<128 µg/L 128 518Aliphatic C19-C36 1 02/03/23 17:24 V29483AMP
<63.4 µg/L 63.4 259Aromatic C11-C22 1 02/03/23 17:24 V29483AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 103 Limits: 40-140%02/03/23 17:241 AMP
MADEP-EPHSurrogate: Chlorooctadecane 69.1 Limits: 40-140%02/03/23 17:241 AMP
MADEP-EPHSurrogate: OTP Surrogate 76.3 Limits: 40-140%02/03/23 17:241 AMP
Surrogate: 2-Fluorobiphenyl 106 Limits: 40-140%02/03/23 17:241 AMP V29483
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
191 µg/L 11.5 50.0Aliphatic C5-C8 1 01/31/23 13:23 V29322TBL
284 µg/L 25.8 50.0Aliphatic C9-C12 1 01/31/23 13:23 V29322TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-2
98594 Matrix:
1/26/2023 11:10
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
111 µg/L 4.02 50.0Aromatic C9-C10 1 01/31/23 13:23 V29322TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)94.0 Limits: 70-130%01/31/23 13:231 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)88.8 Limits: 70-130%01/31/23 13:231 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-3
98595 Matrix:
1/26/2023 0:00
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 02/02/23 15:19 6200BMSA
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%02/02/23 15:191 MSA V29470
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%02/02/23 15:191 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 90.2 Limits: 70-130%02/02/23 15:191 MSA V29470
Surrogate: Toluene-d8 99.2 Limits: 70-130%02/02/23 15:191 MSA V29470
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-3
98595 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
14.5 µg/L 1.80 10.0Acetone 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.500Benzene 1 02/02/23 15:19 V29470MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 02/02/23 15:19 V29470MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 02/02/23 15:19 V29470MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 02/02/23 15:19 V29470MSA
<1.50 µg/L 1.50 5.00Bromoform 1 02/02/23 15:19 V29470MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 02/02/23 15:19 V29470MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 02/02/23 15:19 V29470MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/02/23 15:19 V29470MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 02/02/23 15:19 V29470MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 02/02/23 15:19 V29470MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 02/02/23 15:19 V29470MSA
<0.220 µg/L 0.220 0.500Chloroform 1 02/02/23 15:19 V29470MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 02/02/23 15:19 V29470MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/02/23 15:19 V29470MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/02/23 15:19 V29470MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/02/23 15:19 V29470MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/02/23 15:19 V29470MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 02/02/23 15:19 V29470MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/02/23 15:19 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-3
98595 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/02/23 15:19 V29470MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/02/23 15:19 V29470MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/02/23 15:19 V29470MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/02/23 15:19 V29470MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/02/23 15:19 V29470MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/02/23 15:19 V29470MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 02/02/23 15:19 V29470MSA
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 02/02/23 15:19 V29470MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/02/23 15:19 V29470MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/02/23 15:19 V29470MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/02/23 15:19 V29470MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/02/23 15:19 V29470MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/02/23 15:19 V29470MSA
<42.0 µg/L 42.0 200Ethanol 1 02/02/23 15:19 V29470MSA
<0.170 µg/L 0.170 0.500
Ethylbenzene 1 02/02/23 15:19 V29470MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/02/23 15:19 V29470MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 02/02/23 15:19 V29470MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 02/02/23 15:19 V29470MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/02/23 15:19 V29470MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/02/23 15:19 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-3
98595 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/02/23 15:19 V29470MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 02/02/23 15:19 V29470MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 02/02/23 15:19 V29470MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 02/02/23 15:19 V29470MSA
<0.220 µg/L 0.220 0.500Styrene 1 02/02/23 15:19 V29470MSA
2.55 J µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 02/02/23 15:19 V29470MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 02/02/23 15:19 V29470MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 02/02/23 15:19 V29470MSA
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 02/02/23 15:19 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/02/23 15:19 V29470MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/02/23 15:19 V29470MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 02/02/23 15:19 V29470MSA
<0.220 µg/L 0.220 0.500Toluene 1 02/02/23 15:19 V29470MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/02/23 15:19 V29470MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/02/23 15:19 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/02/23 15:19 V29470MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 02/02/23 15:19 V29470MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/02/23 15:19 V29470MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 02/02/23 15:19 V29470MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 02/02/23 15:19 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-3
98595 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/02/23 15:19 V29470MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/02/23 15:19 V29470MSA
0.255 J µg/L 0.210 0.500o-Xylene 1 02/02/23 15:19 V29470MSA
0.511 J µg/L 0.420 1.00m,p-Xylene 1 02/02/23 15:19 V29470MSA
0.766 J µg/L 0.210 0.500Xylene (Total)1 02/02/23 15:19 V29470KCC
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%02/02/23 15:191 MSA V29470
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%02/02/23 15:191 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 90.2 Limits: 70-130%02/02/23 15:191 MSA V29470
Surrogate: Toluene-d8 99.2 Limits: 70-130%02/02/23 15:191 MSA V29470
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V29336 02/01/23 10:23
<0.00360 µg/L 0.00360 0.0218
1,2-Dibromoethane 1 02/01/23 18:53 V29367AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-3
98595 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/31/23 13:47
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 01/31/23 13:47
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 01/31/23 13:47
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 01/31/23 13:47 V29322TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 01/31/23 13:47 V29322TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 01/31/23 13:47 V29322TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)99.7 Limits: 70-130%01/31/23 13:471 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)94.4 Limits: 70-130%01/31/23 13:471 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-4
98596 Matrix:
1/26/2023 0:00
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 02/02/23 15:44 6200BMSA
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%02/02/23 15:441 MSA V29470
Surrogate: Dibromofluoromethane 98.0 Limits: 70-130%02/02/23 15:441 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%02/02/23 15:441 MSA V29470
Surrogate: Toluene-d8 101 Limits: 70-130%02/02/23 15:441 MSA V29470
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-4
98596 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 02/02/23 15:44 V29470MSA
0.659 µg/L 0.180 0.500Benzene 1 02/02/23 15:44 V29470MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 02/02/23 15:44 V29470MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 02/02/23 15:44 V29470MSA
2.30 µg/L 0.160 0.500Bromodichloromethane 1 02/02/23 15:44 V29470MSA
<1.50 µg/L 1.50 5.00Bromoform 1 02/02/23 15:44 V29470MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 02/02/23 15:44 V29470MSA
0.815 µg/L 0.180 0.500n-Butylbenzene 1 02/02/23 15:44 V29470MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 02/02/23 15:44 V29470MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 02/02/23 15:44 V29470MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/02/23 15:44 V29470MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 02/02/23 15:44 V29470MSA
1.51 µg/L 0.190 0.500Chlorodibromomethane 1 02/02/23 15:44 V29470MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 02/02/23 15:44 V29470MSA
1.86 µg/L 0.220 0.500Chloroform 1 02/02/23 15:44 V29470MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 02/02/23 15:44 V29470MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/02/23 15:44 V29470MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/02/23 15:44 V29470MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/02/23 15:44 V29470MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/02/23 15:44 V29470MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 02/02/23 15:44 V29470MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/02/23 15:44 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-4
98596 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/02/23 15:44 V29470MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/02/23 15:44 V29470MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/02/23 15:44 V29470MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/02/23 15:44 V29470MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/02/23 15:44 V29470MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/02/23 15:44 V29470MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/02/23 15:44 V29470MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 02/02/23 15:44 V29470MSA
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 02/02/23 15:44 V29470MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/02/23 15:44 V29470MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/02/23 15:44 V29470MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/02/23 15:44 V29470MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/02/23 15:44 V29470MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/02/23 15:44 V29470MSA
<42.0 µg/L 42.0 200Ethanol 1 02/02/23 15:44 V29470MSA
1.91 µg/L 0.170 0.500
Ethylbenzene 1 02/02/23 15:44 V29470MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/02/23 15:44 V29470MSA
0.777 J µg/L 0.380 1.002-Hexanone 1 02/02/23 15:44 V29470MSA
0.239 J µg/L 0.180 0.500Isopropylbenzene 1 02/02/23 15:44 V29470MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 02/02/23 15:44 V29470MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/02/23 15:44 V29470MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/02/23 15:44 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-4
98596 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
0.363 J µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/02/23 15:44 V29470MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 02/02/23 15:44 V29470MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 02/02/23 15:44 V29470MSA
0.957 µg/L 0.190 0.500n-Propylbenzene 1 02/02/23 15:44 V29470MSA
<0.220 µg/L 0.220 0.500Styrene 1 02/02/23 15:44 V29470MSA
3.89 J µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 02/02/23 15:44 V29470MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 02/02/23 15:44 V29470MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 02/02/23 15:44 V29470MSA
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 02/02/23 15:44 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/02/23 15:44 V29470MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/02/23 15:44 V29470MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 02/02/23 15:44 V29470MSA
2.73 µg/L 0.220 0.500Toluene 1 02/02/23 15:44 V29470MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/02/23 15:44 V29470MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/02/23 15:44 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/02/23 15:44 V29470MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/02/23 15:44 V29470MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 02/02/23 15:44 V29470MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 02/02/23 15:44 V29470MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/02/23 15:44 V29470MSA
5.63 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 02/02/23 15:44 V29470MSA
1.76 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 02/02/23 15:44 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-4
98596 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/02/23 15:44 V29470MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/02/23 15:44 V29470MSA
2.23 µg/L 0.210 0.500o-Xylene 1 02/02/23 15:44 V29470MSA
6.39 µg/L 0.420 1.00m,p-Xylene 1 02/02/23 15:44 V29470MSA
8.62 µg/L 0.210 0.500Xylene (Total)1 02/02/23 15:44 V29470KCC
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%02/02/23 15:441 MSA V29470
Surrogate: Dibromofluoromethane 98.0 Limits: 70-130%02/02/23 15:441 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 91.0 Limits: 70-130%02/02/23 15:441 MSA V29470
Surrogate: Toluene-d8 101 Limits: 70-130%02/02/23 15:441 MSA V29470
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V29336 02/01/23 10:23
<0.00340 µg/L 0.00340 0.0206
1,2-Dibromoethane 1 02/01/23 19:13 V29367AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-4
98596 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 01/31/23 14:11
59.2 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 01/31/23 14:11
11.0 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 01/31/23 14:11
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 01/31/23 14:11 V29322TBL
80.7 µg/L 25.8 50.0Aliphatic C9-C12 1 01/31/23 14:11 V29322TBL
11.0 J µg/L 4.02 50.0Aromatic C9-C10 1 01/31/23 14:11 V29322TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)91.2 Limits: 70-130%01/31/23 14:111 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)86.6 Limits: 70-130%01/31/23 14:111 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-5
98597 Matrix:
1/26/2023 0:00
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 02/02/23 19:00 6200BMSA
Surrogate: 4-Bromofluorobenzene 91.4 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: Dibromofluoromethane 94.2 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 107 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: Toluene-d8 98.8 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/03/23 18:57100 MSA V29529
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%02/03/23 18:57100 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%02/03/23 18:57100 MSA V29529
Surrogate: Toluene-d8 99.2 Limits: 70-130%02/03/23 18:57100 MSA V29529
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-5
98597 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00 V29528 02/03/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 02/02/23 19:00 V29470MSA
4880 µg/L 18.0 50.0Benzene 100 02/03/23 18:57 V29529MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 02/02/23 19:00 V29470MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 02/02/23 19:00 V29470MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 02/02/23 19:00 V29470MSA
<1.50 µg/L 1.50 5.00Bromoform 1 02/02/23 19:00 V29470MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 02/02/23 19:00 V29470MSA
34.8 µg/L 0.180 0.500n-Butylbenzene 1 02/02/23 19:00 V29470MSA
16.9 µg/L 0.200 0.500
sec-Butyl benzene 1 02/02/23 19:00 V29470MSA
1.16 J µg/L 0.920 2.00tert-Butyl benzene 1 02/02/23 19:00 V29470MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/02/23 19:00 V29470MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 02/02/23 19:00 V29470MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 02/02/23 19:00 V29470MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 02/02/23 19:00 V29470MSA
<0.220 µg/L 0.220 0.500Chloroform 1 02/02/23 19:00 V29470MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 02/02/23 19:00 V29470MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/02/23 19:00 V29470MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/02/23 19:00 V29470MSA
15.9 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/02/23 19:00 V29470MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/02/23 19:00 V29470MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 02/02/23 19:00 V29470MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/02/23 19:00 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-5
98597 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00 V29528 02/03/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/02/23 19:00 V29470MSA
0.215 J µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/02/23 19:00 V29470MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/02/23 19:00 V29470MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/02/23 19:00 V29470MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/02/23 19:00 V29470MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/02/23 19:00 V29470MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/02/23 19:00 V29470MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 02/02/23 19:00 V29470MSA
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 02/02/23 19:00 V29470MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/02/23 19:00 V29470MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/02/23 19:00 V29470MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/02/23 19:00 V29470MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/02/23 19:00 V29470MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/02/23 19:00 V29470MSA
<42.0 µg/L 42.0 200Ethanol 1 02/02/23 19:00 V29470MSA
1880 µg/L 17.0 50.0
Ethylbenzene 100 02/03/23 18:57 V29529MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/02/23 19:00 V29470MSA
6.99 µg/L 0.380 1.002-Hexanone 1 02/02/23 19:00 V29470MSA
75.1 µg/L 0.180 0.500Isopropylbenzene 1 02/02/23 19:00 V29470MSA
10.2 µg/L 0.089 0.5004-Isopropyl toluene 1 02/02/23 19:00 V29470MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/02/23 19:00 V29470MSA
1.77 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/02/23 19:00 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-5
98597 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00 V29528 02/03/23 09:00
6.33 µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/02/23 19:00 V29470MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 02/02/23 19:00 V29470MSA
504 µg/L 47.0 100Naphthalene 100 02/03/23 18:57 V29529MSA
293 µg/L 19.0 50.0n-Propylbenzene 100 02/03/23 18:57 V29529MSA
73.8 µg/L 0.220 0.500Styrene 1 02/02/23 19:00 V29470MSA
35.2 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 02/02/23 19:00 V29470MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 02/02/23 19:00 V29470MSA
2060 µg/L 190 1000tert-Amyl Alcohol (TAA)100 02/03/23 18:57 V29529MSA
14.7 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 02/02/23 19:00 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/02/23 19:00 V29470MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/02/23 19:00 V29470MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 02/02/23 19:00 V29470MSA
8300 µg/L 22.0 50.0Toluene 100 02/03/23 18:57 V29529MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/02/23 19:00 V29470MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/02/23 19:00 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/02/23 19:00 V29470MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/02/23 19:00 V29470MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 02/02/23 19:00 V29470MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 02/02/23 19:00 V29470MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/02/23 19:00 V29470MSA
2200 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 02/03/23 18:57 V29529MSA
589 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 02/03/23 18:57 V29529MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-5
98597 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00 V29528 02/03/23 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/02/23 19:00 V29470MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/02/23 19:00 V29470MSA
3100 µg/L 21.0 50.0o-Xylene 100 02/03/23 18:57 V29529MSA
7080 µg/L 42.0 100m,p-Xylene 100 02/03/23 18:57 V29529MSA
10200 µg/L 21.0 50.0Xylene (Total)100 02/03/23 18:57 V29529
Surrogate: 4-Bromofluorobenzene 91.4 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: Dibromofluoromethane 94.2 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 107 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: Toluene-d8 98.8 Limits: 70-130%02/02/23 19:001 MSA V29470
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%02/03/23 18:57100 MSA V29529
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%02/03/23 18:57100 MSA V29529
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%02/03/23 18:57100 MSA V29529
Surrogate: Toluene-d8 99.2 Limits: 70-130%02/03/23 18:57100 MSA V29529
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V29336 02/01/23 10:23
4.14 µg/L 0.0168 0.102
1,2-Dibromoethane 5 02/02/23 09:23 V29367AMP
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GMW-5
98597 Matrix:
1/26/2023 0:00
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
7320 µg/L 1150 5000Aliphatic C5-C8 (Adjusted)100 02/01/23 10:06
11400 µg/L 2580 5000Aliphatics C9-C12 (Adjusted)100 02/01/23 10:06
6490 µg/L 402 5000Aromatic C9-C10 (Adjusted)100 02/01/23 10:06
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29321 01/31/23 08:00
20500 µg/L 1150 5000Aliphatic C5-C8 100 02/01/23 10:06 V29322TBL
29900 µg/L 2580 5000Aliphatic C9-C12 100 02/01/23 10:06 V29322TBL
6490 µg/L 402 5000Aromatic C9-C10 100 02/01/23 10:06 V29322TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)88.6 Limits: 70-130%02/01/23 10:06100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)82.2 Limits: 70-130%02/01/23 10:06100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:TB
98598 Matrix:
1/26/2023 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.500Benzene 1 02/02/23 14:55 V29470MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 02/02/23 14:55 V29470MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 02/02/23 14:55 V29470MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 02/02/23 14:55 V29470MSA
<1.50 µg/L 1.50 5.00Bromoform 1 02/02/23 14:55 V29470MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 02/02/23 14:55 V29470MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 02/02/23 14:55 V29470MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/02/23 14:55 V29470MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 02/02/23 14:55 V29470MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 02/02/23 14:55 V29470MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 02/02/23 14:55 V29470MSA
<0.220 µg/L 0.220 0.500Chloroform 1 02/02/23 14:55 V29470MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 02/02/23 14:55 V29470MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/02/23 14:55 V29470MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/02/23 14:55 V29470MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/02/23 14:55 V29470MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/02/23 14:55 V29470MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 02/02/23 14:55 V29470MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 02/02/23 14:55 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:TB
98598 Matrix:
1/26/2023 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/02/23 14:55 V29470MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/02/23 14:55 V29470MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/02/23 14:55 V29470MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/02/23 14:55 V29470MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/02/23 14:55 V29470MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/02/23 14:55 V29470MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/02/23 14:55 V29470MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 02/02/23 14:55 V29470MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 02/02/23 14:55 V29470MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/02/23 14:55 V29470MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/02/23 14:55 V29470MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/02/23 14:55 V29470MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/02/23 14:55 V29470MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/02/23 14:55 V29470MSA
<42.0 µg/L 42.0 200
Ethanol 1 02/02/23 14:55 V29470MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 02/02/23 14:55 V29470MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/02/23 14:55 V29470MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 02/02/23 14:55 V29470MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 02/02/23 14:55 V29470MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/02/23 14:55 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:TB
98598 Matrix:
1/26/2023 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/02/23 14:55 V29470MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/02/23 14:55 V29470MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 02/02/23 14:55 V29470MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 02/02/23 14:55 V29470MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 02/02/23 14:55 V29470MSA
<0.220 µg/L 0.220 0.500Styrene 1 02/02/23 14:55 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/02/23 14:55 V29470MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/02/23 14:55 V29470MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 02/02/23 14:55 V29470MSA
<0.220 µg/L 0.220 0.500Toluene 1 02/02/23 14:55 V29470MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/02/23 14:55 V29470MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/02/23 14:55 V29470MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/02/23 14:55 V29470MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 02/02/23 14:55 V29470MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/02/23 14:55 V29470MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 02/02/23 14:55 V29470MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 02/02/23 14:55 V29470MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/02/23 14:55 V29470MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/02/23 14:55 V29470MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 02/02/23 14:55 V29470MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:TB
98598 Matrix:
1/26/2023 8:00
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29469 02/02/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 02/02/23 14:55 V29470MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 02/02/23 14:55 V29470
Surrogate: 4-Bromofluorobenzene 97.6 Limits: 70-130%02/02/23 14:551 MSA V29470
Surrogate: Dibromofluoromethane 100 Limits: 70-130%02/02/23 14:551 MSA V29470
Surrogate: 1,2-Dichloroethane - d4 95.2 Limits: 70-130%02/02/23 14:551 MSA V29470
Surrogate: Toluene-d8 100 Limits: 70-130%02/02/23 14:551 MSA V29470
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
5.46 %Moisture 1 02/01/23 16:54 SW-DRYWTAMB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V29300 01/30/23 08:00
0.019 J mg/Kg - dry 0.002 0.021Acetone 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.021Acrolein 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.021Acrylonitrile 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.005Benzene 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.005Bromobenzene 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.005Bromochloromethane 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.010
Bromomethane 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.005n-Butylbenzene 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.005tert-Butyl benzene 1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.005Chlorobenzene 1 01/30/23 19:16 V29301TBL
<0.0009 mg/Kg - dry 0.0009 0.005
Chlorodibromomethane 1 01/30/23 19:16 V29301TBL
<0.0009 mg/Kg - dry 0.0009 0.010Chloroethane 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.010Chloromethane 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.0052-Chlorotoluene 1 01/30/23 19:16 V29301TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 01/30/23 19:16 V29301TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V29300 01/30/23 08:00
<0.0005 mg/Kg - dry 0.0005 0.0101,2-Dibromo-3-Chloropropane 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,2-Dibromoethane 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 01/30/23 19:16 V29301TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,2-Dichlorobenzene 1 01/30/23 19:16 V29301TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,4-Dichlorobenzene 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.010Dichlorodifluoromethane 1 01/30/23 19:16 V29301TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.005
1,2-Dichloroethane 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.005cis-1,2-Dichloroethene 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.005
1,1-Dichloropropene 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.005trans-1,3-Dichloropropene 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.005Ethylbenzene 1 01/30/23 19:16 V29301TBL
<0.0009 mg/Kg - dry 0.0009 0.052Ethyl Tertiary Butyl Ether (ETBE)1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.010Hexachlorobutadiene 1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.010n-Hexane 1 01/30/23 19:16 V29301TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V29300 01/30/23 08:00
<0.0007 mg/Kg - dry 0.0007 0.0212-Hexanone 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.021Methyl Ethyl Ketone (MEK)1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 01/30/23 19:16 V29301TBL
<0.015 mg/Kg - dry 0.015 0.0214-Methyl-2-Pentanone 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.010Methylene Chloride 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.010Naphthalene 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.005
n-Propylbenzene 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 01/30/23 19:16 V29301TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,1,2,2-Tetrachloroethane 1 01/30/23 19:16 V29301TBL
<0.0010 mg/Kg - dry 0.0010 0.005Tetrachloroethene 1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.005Toluene 1 01/30/23 19:16 V29301TBL
<0.0006 mg/Kg - dry 0.0006 0.0101,2,3-Trichlorobenzene 1 01/30/23 19:16 V29301TBL
<0.0007 mg/Kg - dry 0.0007 0.010
1,2,4-Trichlorobenzene 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 01/30/23 19:16 V29301TBL
<0.0010 mg/Kg - dry 0.0010 0.005Trichloroethene 1 01/30/23 19:16 V29301TBL
<0.002 mg/Kg - dry 0.002 0.010Trichlorofluoromethane 1 01/30/23 19:16 V29301TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2,4-Trimethylbenzene 1 01/30/23 19:16 V29301TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V29300 01/30/23 08:00
<0.0006 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.010Vinyl Acetate 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.010Vinyl Chloride 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.005o-Xylene 1 01/30/23 19:16 V29301TBL
<0.001 mg/Kg - dry 0.001 0.010m,p-Xylene 1 01/30/23 19:16 V29301TBL
<0.0005 mg/Kg - dry 0.0005 0.005Xylene (Total)1 01/30/23 19:16 V29301
Surrogate: 4-Bromofluorobenzene 97.5 Limits: 70-130%01/30/23 19:161 TBL V29301
Surrogate: Dibromofluoromethane 110 Limits: 84-123%01/30/23 19:161 TBL V29301
Surrogate: Toluene-d8 96.2 Limits: 76-129%01/30/23 19:161 TBL V29301
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V29475 02/03/23 11:00
<0.122 mg/Kg - dry 0.122 0.698Acenaphthene 1 02/06/23 18:40 V29532JMV
<0.111 mg/Kg - dry 0.111 0.698Acenaphthylene 1 02/06/23 18:40 V29532JMV
<0.160 mg/Kg - dry 0.160 0.698Aniline 1 02/06/23 18:40 V29532JMV
0.198 J mg/Kg - dry 0.151 0.698Anthracene 1 02/06/23 18:40 V29532JMV
2.57 mg/Kg - dry 0.147 0.698Benzo(a)anthracene 1 02/06/23 18:40 V29532JMV
3.82 mg/Kg - dry 0.155 0.698
Benzo(a)pyrene 1 02/06/23 18:40 V29532JMV
5.85 mg/Kg - dry 0.154 0.698Benzo(b)fluoranthene 1 02/06/23 18:40 V29532JMV
3.37 mg/Kg - dry 0.143 0.698Benzo(g,h,i)perylene 1 02/06/23 18:40 V29532JMV
2.02 mg/Kg - dry 0.144 0.698Benzo(k)fluoranthene 1 02/06/23 18:40 V29532JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V29475 02/03/23 11:00
<0.613 mg/Kg - dry 0.613 2.12Benzoic Acid 1 02/06/23 18:40 V29532JMV
<0.111 mg/Kg - dry 0.111 0.698Benzyl alcohol 1 02/06/23 18:40 V29532JMV
<0.124 mg/Kg - dry 0.124 0.698Bis(2-Chloroethoxy)methane 1 02/06/23 18:40 V29532JMV
<0.113 mg/Kg - dry 0.113 0.698Bis(2-Chloroethyl)ether 1 02/06/23 18:40 V29532JMV
<0.143 mg/Kg - dry 0.143 0.349Bis(2-Chloroisopropyl)ether 1 02/06/23 18:40 V29532JMV
<0.126 mg/Kg - dry 0.126 0.698Bis(2-ethylhexyl)phthalate 1 02/06/23 18:40 V29532JMV
<0.115 mg/Kg - dry 0.115 0.6984-Bromophenyl phenyl ether 1 02/06/23 18:40 V29532JMV
<0.119 mg/Kg - dry 0.119 0.349Butyl benzyl phthalate 1 02/06/23 18:40 V29532JMV
<0.097 mg/Kg - dry 0.097 0.698
4-Chloro-3-methylphenol 1 02/06/23 18:40 V29532JMV
<0.118 mg/Kg - dry 0.118 0.3494-Chloroaniline 1 02/06/23 18:40 V29532JMV
<0.122 mg/Kg - dry 0.122 0.6982-Chloronaphthalene 1 02/06/23 18:40 V29532JMV
<0.103 mg/Kg - dry 0.103 0.6982-Chlorophenol 1 02/06/23 18:40 V29532JMV
<0.133 mg/Kg - dry 0.133 1.064-Chlorophenyl phenyl ether 1 02/06/23 18:40 V29532JMV
3.65 mg/Kg - dry 0.150 0.698Chrysene 1 02/06/23 18:40 V29532JMV
0.737 mg/Kg - dry 0.243 0.698Dibenz(a,h)anthracene 1 02/06/23 18:40 V29532JMV
<0.125 mg/Kg - dry 0.125 0.698
Dibenzofuran 1 02/06/23 18:40 V29532JMV
<0.099 mg/Kg - dry 0.099 0.6981,2-Dichlorobenzene 1 02/06/23 18:40 V29532JMV
<0.102 mg/Kg - dry 0.102 0.6981,3-Dichlorobenzene 1 02/06/23 18:40 V29532JMV
<0.103 mg/Kg - dry 0.103 0.3491,4-Dichlorobenzene 1 02/06/23 18:40 V29532JMV
<0.155 mg/Kg - dry 0.155 0.6983,3'-Dichlorobenzidine 1 02/06/23 18:40 V29532JMV
<0.101 mg/Kg - dry 0.101 0.6982,4-Dichlorophenol 1 02/06/23 18:40 V29532JMV
<0.190 mg/Kg - dry 0.190 0.698Diethyl phthalate 1 02/06/23 18:40 V29532JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 44 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V29475 02/03/23 11:00
<0.184 mg/Kg - dry 0.184 0.698Dimethyl phthalate 1 02/06/23 18:40 V29532JMV
<0.114 mg/Kg - dry 0.114 0.3492,4-Dimethylphenol 1 02/06/23 18:40 V29532JMV
<0.113 mg/Kg - dry 0.113 0.698Di-n-butyl phthalate 1 02/06/23 18:40 V29532JMV
<0.253 mg/Kg - dry 0.253 1.594,6-Dinitro-2-methylphenol 1 02/06/23 18:40 V29532JMV
<0.550 mg/Kg - dry 0.550 1.592,4-Dinitrophenol 1 02/06/23 18:40 V29532JMV
<0.102 mg/Kg - dry 0.102 0.6982,4-Dinitrotoluene 1 02/06/23 18:40 V29532JMV
<0.114 mg/Kg - dry 0.114 0.6982,6-Dinitrotoluene 1 02/06/23 18:40 V29532JMV
<0.151 mg/Kg - dry 0.151 0.349Di-n-Octyl Phthalate 1 02/06/23 18:40 V29532JMV
5.49 mg/Kg - dry 0.130 0.698
Fluoranthene 1 02/06/23 18:40 V29532JMV
<0.135 mg/Kg - dry 0.135 0.698Fluorene 1 02/06/23 18:40 V29532JMV
<0.112 mg/Kg - dry 0.112 0.698Hexachlorobenzene 1 02/06/23 18:40 V29532JMV
<0.103 mg/Kg - dry 0.103 0.698Hexachlorobutadiene 1 02/06/23 18:40 V29532JMV
<0.166 mg/Kg - dry 0.166 0.698Hexachlorocyclopentadiene 1 02/06/23 18:40 V29532JMV
<0.083 mg/Kg - dry 0.083 0.698Hexachloroethane 1 02/06/23 18:40 V29532JMV
3.70 mg/Kg - dry 0.189 0.698Indeno(1,2,3-cd)pyrene 1 02/06/23 18:40 V29532JMV
<0.202 mg/Kg - dry 0.202 0.698
Isophorone 1 02/06/23 18:40 V29532JMV
<0.112 mg/Kg - dry 0.112 0.6981-Methylnaphthalene 1 02/06/23 18:40 V29532JMV
<0.105 mg/Kg - dry 0.105 0.6982-Methylnaphthalene 1 02/06/23 18:40 V29532JMV
<0.102 mg/Kg - dry 0.102 0.6982-Methylphenol 1 02/06/23 18:40 V29532JMV
<0.089 mg/Kg - dry 0.089 0.6983&4 Methylphenol 1 02/06/23 18:40 V29532JMV
<0.152 mg/Kg - dry 0.152 0.698Naphthalene 1 02/06/23 18:40 V29532JMV
<0.102 mg/Kg - dry 0.102 0.6982-Nitroaniline 1 02/06/23 18:40 V29532JMV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 45 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V29475 02/03/23 11:00
<0.126 mg/Kg - dry 0.126 0.6983-Nitroaniline 1 02/06/23 18:40 V29532JMV
<0.098 mg/Kg - dry 0.098 0.3494-Nitroaniline 1 02/06/23 18:40 V29532JMV
<0.122 mg/Kg - dry 0.122 0.349Nitrobenzene 1 02/06/23 18:40 V29532JMV
<0.093 mg/Kg - dry 0.093 0.6982-Nitrophenol 1 02/06/23 18:40 V29532JMV
<0.123 mg/Kg - dry 0.123 0.6984-Nitrophenol 1 02/06/23 18:40 V29532JMV
<0.278 mg/Kg - dry 0.278 0.698N-Nitrosodimethylamine 1 02/06/23 18:40 V29532JMV
<0.191 mg/Kg - dry 0.191 0.698N-Nitrosodiphenylamine 1 02/06/23 18:40 V29532JMV
<0.124 mg/Kg - dry 0.124 0.698N-Nitroso-di-n-propylamine 1 02/06/23 18:40 V29532JMV
<0.367 mg/Kg - dry 0.367 1.06
Pentachlorophenol 1 02/06/23 18:40 V29532JMV
2.04 mg/Kg - dry 0.220 0.698Phenanthrene 1 02/06/23 18:40 V29532JMV
<0.118 mg/Kg - dry 0.118 0.698Phenol 1 02/06/23 18:40 V29532JMV
5.02 mg/Kg - dry 0.141 0.698Pyrene 1 02/06/23 18:40 V29532JMV
<0.083 mg/Kg - dry 0.083 0.349Pyridine 1 02/06/23 18:40 V29532JMV
<0.113 mg/Kg - dry 0.113 0.6981,2,4-Trichlorobenzene 1 02/06/23 18:40 V29532JMV
<0.101 mg/Kg - dry 0.101 0.6982,4,5-Trichlorophenol 1 02/06/23 18:40 V29532JMV
<0.102 mg/Kg - dry 0.102 0.698
2,4,6-Trichlorophenol 1 02/06/23 18:40 V29532JMV
8270ESurrogate: Phenol-d5 66.8 Limits: 34-121%02/06/23 18:401 JMV
Surrogate: 2-Fluorobiphenyl 85.6 Limits: 44-115%02/06/23 18:401 JMV V29532
Surrogate: 2-Fluorophenol 70.7 Limits: 35-115%02/06/23 18:401 JMV V29532
Surrogate: Nitrobenzene-d5 74.9 Limits: 37-122%02/06/23 18:401 JMV V29532
Surrogate: 4-Terphenyl-d14 97.6 Limits: 54-127%02/06/23 18:401 JMV V29532
Surrogate: 2,4,6-Tribromophenol 78.7 Limits: 39-132%02/06/23 18:401 JMV V29532
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 46 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.29 mg/Kg - dry 1.29 8.46Aliphatic C5-C8 (Adjusted)1 01/30/23 19:16
<4.82 mg/Kg - dry 4.82 8.46Aliphatics C9-C12 (Adjusted)1 01/30/23 19:16
<0.660 mg/Kg - dry 0.660 8.46Aromatic C9-C10 (Adjusted)100 01/31/23 10:36
<15.0 mg/Kg - dry 15.0 52.8Aromatic C11-C22 (Adjusted)1 02/06/23 18:40
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V29431 02/02/23 12:00
<9.71 mg/Kg - dry 9.71 52.8Aliphatic C9-C18 1 02/07/23 13:10 V29557AMP
<12.9 mg/Kg - dry 12.9 52.8Aliphatic C19-C36 1 02/07/23 13:10 V29557AMP
43.4 J mg/Kg - dry 15.0 52.8Aromatic C11-C22 1 02/07/23 13:10 V29557AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 103 Limits: 40-140%02/07/23 13:101 AMP
MADEP-EPHSurrogate: Chlorooctadecane 107 Limits: 40-140%02/07/23 13:101 AMP
MADEP-EPHSurrogate: OTP Surrogate 92.0 Limits: 40-140%02/07/23 13:101 AMP
Surrogate: 2-Fluorobiphenyl 106 Limits: 40-140%02/07/23 13:101 AMP V29557
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29304 01/31/23 08:00
<1.29 mg/Kg - dry 1.29 8.46Aliphatic C5-C8 100 01/31/23 10:36 V29305TBL
<4.82 mg/Kg - dry 4.82 8.46Aliphatic C9-C12 100 01/31/23 10:36 V29305TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 47 of 109
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-030-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #5947 Received : 01/27/2023
Merry Grocery
Report Date : 02/09/2023
Sample ID :
Lab No :
Sampled:GM2-2-SS-4'
98599 Matrix:
1/26/2023 8:55
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V29304 01/31/23 08:00
<0.660 mg/Kg - dry 0.660 8.46Aromatic C9-C10 100 01/31/23 10:36 V29305TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)82.2 Limits: 70-130%01/31/23 10:36100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)78.1 Limits: 70-130%01/31/23 10:36100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 48 of 109
Sample ID Report Lab No
LRB 23-030-0002 LRB-V29366
Paramater Result Units
Dilution
Factor Method Analysis Date/Time Analyst Batch ID
No TICS Reported 0 ug/L 1 625.1 2/1/2023 15:19 JMV V29518
Sample ID Report Lab No
GMW-2 23-030-0002 V 98594
Paramater Result Units
Dilution
Factor Method Analysis Date/Time Analyst Batch ID
Trimethyl benzene 12 ug/L 1 625.1 1/23/2023 17:14 JMV V29518
Indane 34.2 ug/L 1 625.1 1/23/2023 17:14 JMV V29518
Diethyl Benzene 22.6 ug/L 1 625.1 1/23/2023 17:14 JMV V29518
Dimethyl Etehnyl Benzene 15.2 ug/L 1 625.1 1/23/2023 17:14 JMV V29518
Hexadecanoic Acid 20.1 ug/L 1 625.1 1/23/2023 17:14 JMV V29518
Docosene 11.3 ug/L 1 625.1 1/23/2023 17:14 JMV V29518
Page 49 of 109
ANALYTICAL REPORT
PREPARED FOR
Attn: PM Group NC
Waypoint Analytical, Inc.
449 Springbrook Road
Charlotte, North Carolina 28217
Generated 2/6/2023 9:03:24 PM
JOB DESCRIPTION
23-030-0002
JOB NUMBER
680-229969-1
See page two for job notes and contact information.
Savannah GA 31404
5102 LaRoche Avenue
Eurofins Savannah
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Eurofins Savannah
Eurofins Savannah is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report may not be
reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the person who
signed this report.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
2/6/2023 9:03:24 PM
Authorized for release by
John Andros, Project Manager I
[e-mail]
[phone]
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Definitions/Glossary
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Savannah
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Sample Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229969-1
Project/Site: 23-030-0002
Lab Sample ID Client Sample ID Matrix Collected Received
680-229969-1 GMW-2 / 98594 Water 01/26/23 11:10 02/03/23 13:30
680-229969-2 GMW-3 / 98595 Water 01/26/23 00:00 02/03/23 13:30
680-229969-3 GMW-4 / 98596 Water 01/26/23 00:00 02/03/23 13:30
680-229969-4 GMW-5 / 98597 Water 01/26/23 00:00 02/03/23 13:30
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Page 53 of 109
Case Narrative
Client: Waypoint Analytical, Inc.Job ID: 680-229969-1
Project/Site: 23-030-0002
Job ID: 680-229969-1
Laboratory: Eurofins Savannah
Narrative
Job Narrative
680-229969-1
Receipt
The samples were received on 2/3/2023 1:30 PM. Unless otherwise noted below, the samples arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 5.4°C
Metals
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
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Client Sample Results
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Lab Sample ID: 680-229969-1Client Sample ID: GMW-2 / 98594
Matrix: WaterDate Collected: 01/26/23 11:10
Date Received: 02/03/23 13:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
14.3 10.0 ug/L 02/06/23 07:22 02/06/23 14:02 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Lab Sample ID: 680-229969-2Client Sample ID: GMW-3 / 98595
Matrix: WaterDate Collected: 01/26/23 00:00
Date Received: 02/03/23 13:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
497 10.0 ug/L 02/06/23 07:22 02/06/23 14:05 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Lab Sample ID: 680-229969-3Client Sample ID: GMW-4 / 98596
Matrix: WaterDate Collected: 01/26/23 00:00
Date Received: 02/03/23 13:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
19.3 10.0 ug/L 02/06/23 07:22 02/06/23 14:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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Client Sample Results
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Lab Sample ID: 680-229969-4Client Sample ID: GMW-5 / 98597
Matrix: WaterDate Collected: 01/26/23 00:00
Date Received: 02/03/23 13:30
Method: SW846 6010D - Metals (ICP) - Total Recoverable
RL MDL
31.0 10.0 ug/L 02/06/23 07:22 02/06/23 14:12 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lead
Eurofins Savannah
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QC Sample Results
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 680-762018/1-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 762171 Prep Batch: 762018
RL MDL
Lead ND 10.0 ug/L 02/06/23 07:22 02/06/23 13:41 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-762018/2-A
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 762171 Prep Batch: 762018
Lead 505 493.7 ug/L 98 80-120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec
Limits
Client Sample ID: Matrix SpikeLab Sample ID: 680-229917-A-1-B MS
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 762171 Prep Batch: 762018
Lead ND 505 495.7 ug/L 98 75-125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 680-229917-A-1-C MSD
Matrix: Water Prep Type: Total Recoverable
Analysis Batch: 762171 Prep Batch: 762018
Lead ND 505 482.8 ug/L 96 75-125 3 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
Eurofins Savannah
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QC Association Summary
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Metals
Prep Batch: 762018
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A680-229969-1 GMW-2 / 98594 Total Recoverable
Water 3005A680-229969-2 GMW-3 / 98595 Total Recoverable
Water 3005A680-229969-3 GMW-4 / 98596 Total Recoverable
Water 3005A680-229969-4 GMW-5 / 98597 Total Recoverable
Water 3005AMB 680-762018/1-A Method Blank Total Recoverable
Water 3005ALCS 680-762018/2-A Lab Control Sample Total Recoverable
Water 3005A680-229917-A-1-B MS Matrix Spike Total Recoverable
Water 3005A680-229917-A-1-C MSD Matrix Spike Duplicate Total Recoverable
Analysis Batch: 762171
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 762018680-229969-1 GMW-2 / 98594 Total Recoverable
Water 6010D 762018680-229969-2 GMW-3 / 98595 Total Recoverable
Water 6010D 762018680-229969-3 GMW-4 / 98596 Total Recoverable
Water 6010D 762018680-229969-4 GMW-5 / 98597 Total Recoverable
Water 6010D 762018MB 680-762018/1-A Method Blank Total Recoverable
Water 6010D 762018LCS 680-762018/2-A Lab Control Sample Total Recoverable
Water 6010D 762018680-229917-A-1-B MS Matrix Spike Total Recoverable
Water 6010D 762018680-229917-A-1-C MSD Matrix Spike Duplicate Total Recoverable
Eurofins Savannah
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Lab Chronicle
Client: Waypoint Analytical, Inc.Job ID: 680-229969-1
Project/Site: 23-030-0002
Client Sample ID: GMW-2 / 98594 Lab Sample ID: 680-229969-1
Matrix: WaterDate Collected: 01/26/23 11:10
Date Received: 02/03/23 13:30
Prep 3005A RR02/06/23 07:22 EET SAV762018
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 25 mL 25 mL
Analysis 6010D 1 762171 02/06/23 14:02 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: GMW-3 / 98595 Lab Sample ID: 680-229969-2
Matrix: WaterDate Collected: 01/26/23 00:00
Date Received: 02/03/23 13:30
Prep 3005A RR02/06/23 07:22 EET SAV762018
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 25 mL 25 mL
Analysis 6010D 1 762171 02/06/23 14:05 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: GMW-4 / 98596 Lab Sample ID: 680-229969-3
Matrix: WaterDate Collected: 01/26/23 00:00
Date Received: 02/03/23 13:30
Prep 3005A RR02/06/23 07:22 EET SAV762018
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 25 mL 25 mL
Analysis 6010D 1 762171 02/06/23 14:15 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Client Sample ID: GMW-5 / 98597 Lab Sample ID: 680-229969-4
Matrix: WaterDate Collected: 01/26/23 00:00
Date Received: 02/03/23 13:30
Prep 3005A RR02/06/23 07:22 EET SAV762018
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total Recoverable 25 mL 25 mL
Analysis 6010D 1 762171 02/06/23 14:12 BCB EET SAVTotal Recoverable
ICPHInstrument ID:
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
Page 12 of 16 2/6/2023
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Accreditation/Certification Summary
Client: Waypoint Analytical, Inc.Job ID: 680-229969-1
Project/Site: 23-030-0002
Laboratory: Eurofins Savannah
The accreditations/certifications listed below are applicable to this report.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW) State 269 12-31-23
South Carolina State 98001 06-30-23
Eurofins Savannah
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Method Summary
Job ID: 680-229969-1Client: Waypoint Analytical, Inc.
Project/Site: 23-030-0002
Method Method Description LaboratoryProtocol
SW8466010D Metals (ICP)EET SAV
SW8463005A Preparation, Total Recoverable or Dissolved Metals EET SAV
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET SAV = Eurofins Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL [phone]
Eurofins Savannah
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Page 15 of 16 2/6/2023
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Login Sample Receipt Checklist
Client: Waypoint Analytical, Inc.Job Number: 680-229969-1
Login Number: 229969
Question Answer Comment
Creator: Sims, Robert D
List Source: Eurofins Savannah
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Savannah
Page 16 of 16 2/6/2023
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Page 65 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29384QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29383
Associated Lab Samples: 98594
LRB-V29383 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/01/23 01:1510.01.80<1.80µg/LAcetone
02/01/23 01:150.5000.180<0.180µg/LBenzene
02/01/23 01:150.5000.210<0.210µg/LBromobenzene
02/01/23 01:151.000.420<0.420µg/LBromochloromethane
02/01/23 01:150.5000.160<0.160µg/LBromodichloromethane
02/01/23 01:155.001.50<1.50µg/LBromoform
02/01/23 01:151.000.280<0.280µg/LBromomethane
02/01/23 01:150.5000.180<0.180µg/Ln-Butylbenzene
02/01/23 01:150.5000.200<0.200µg/Lsec-Butyl benzene
02/01/23 01:152.000.920<0.920µg/Ltert-Butyl benzene
02/01/23 01:150.5000.180<0.180µg/LCarbon Tetrachloride
02/01/23 01:150.5000.190<0.190µg/LChlorobenzene
02/01/23 01:150.5000.190<0.190µg/LChlorodibromomethane
02/01/23 01:151.000.430<0.430µg/LChloroethane
02/01/23 01:150.5000.220<0.220µg/LChloroform
02/01/23 01:150.5000.220<0.220µg/LChloromethane
02/01/23 01:150.5000.200<0.200µg/L2-Chlorotoluene
02/01/23 01:150.5000.200<0.200µg/L4-Chlorotoluene
02/01/23 01:150.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
02/01/23 01:152.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
02/01/23 01:150.5000.230<0.230µg/LDibromomethane
02/01/23 01:150.5000.220<0.220µg/L1,2-Dichlorobenzene
02/01/23 01:150.5000.190<0.190µg/L1,3-Dichlorobenzene
02/01/23 01:150.5000.210<0.210µg/L1,4-Dichlorobenzene
02/01/23 01:155.001.20<1.20µg/LDichlorodifluoromethane
02/01/23 01:150.5000.240<0.240µg/L1,1-Dichloroethane
02/01/23 01:150.5000.150<0.150µg/L1,2-Dichloroethane
Page 1 of 41Date:02/09/2023 02:32 PM
Page 66 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29384QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29383
Associated Lab Samples: 98594
LRB-V29383 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/01/23 01:150.5000.150<0.150µg/L1,1-Dichloroethene
02/01/23 01:150.5000.200<0.200µg/Lcis-1,2-Dichloroethene
02/01/23 01:150.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
02/01/23 01:150.5000.190<0.190µg/L1,2-Dichloropropane
02/01/23 01:150.5000.130<0.130µg/L1,3-Dichloropropane
02/01/23 01:152.000.210<0.210µg/L2,2-Dichloropropane
02/01/23 01:150.5000.200<0.200µg/L1,1-Dichloropropene
02/01/23 01:150.5000.210<0.210µg/Lcis-1,3-Dichloropropene
02/01/23 01:150.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
02/01/23 01:1520042.0<42.0µg/LEthanol
02/01/23 01:150.5000.170<0.170µg/LEthylbenzene
02/01/23 01:153.000.350<0.350µg/LHexachlorobutadiene
02/01/23 01:151.000.380<0.380µg/L2-Hexanone
02/01/23 01:150.5000.180<0.180µg/LIsopropylbenzene
02/01/23 01:150.5000.089<0.089µg/L4-Isopropyl toluene
02/01/23 01:155.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
02/01/23 01:151.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
02/01/23 01:151.000.078<0.078µg/L4-Methyl-2-Pentanone
02/01/23 01:152.000.330<0.330µg/LMethylene Chloride
02/01/23 01:151.000.470<0.470µg/LNaphthalene
02/01/23 01:150.5000.190<0.190µg/Ln-Propylbenzene
02/01/23 01:150.5000.220<0.220µg/LStyrene
02/01/23 01:1510.00.350<0.350µg/Ltert-Butyl formate (TBF)
02/01/23 01:1510.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
02/01/23 01:150.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
02/01/23 01:150.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
02/01/23 01:150.5000.220<0.220µg/LTetrachloroethene
Page 2 of 41Date:02/09/2023 02:32 PM
Page 67 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29384QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29383
Associated Lab Samples: 98594
LRB-V29383 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/01/23 01:150.5000.220<0.220µg/LToluene
02/01/23 01:150.5000.380<0.380µg/L1,2,3-Trichlorobenzene
02/01/23 01:150.5000.310<0.310µg/L1,2,4-Trichlorobenzene
02/01/23 01:150.5000.160<0.160µg/L1,1,1-Trichloroethane
02/01/23 01:150.5000.096<0.096µg/L1,1,2-Trichloroethane
02/01/23 01:150.5000.180<0.180µg/LTrichloroethene
02/01/23 01:150.5000.180<0.180µg/LTrichlorofluoromethane
02/01/23 01:150.5000.270<0.270µg/L1,2,3-Trichloropropane
02/01/23 01:150.5000.190<0.190µg/L1,2,4-Trimethylbenzene
02/01/23 01:150.5000.180<0.180µg/L1,3,5-Trimethylbenzene
02/01/23 01:155.001.00<1.00µg/LVinyl Acetate
02/01/23 01:150.5000.170<0.170µg/LVinyl Chloride
02/01/23 01:150.5000.210<0.210µg/Lo-Xylene
02/01/23 01:151.000.420<0.420µg/Lm,p-Xylene
02/01/23 01:1510.01.00<1.00µg/L3,3-Dimethyl-1-butanol
02/01/23 01:154-Bromofluorobenzene (S)96.4 70-130
02/01/23 01:15Dibromofluoromethane (S)90.0 70-130
02/01/23 01:151,2-Dichloroethane - d4 (S)84.0 70-130
02/01/23 01:15Toluene-d8 (S)103 70-130
LCS-V29383 LCSD-V29383Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
43.6 10913855.340.0µg/LAcetone 40-160 23.6*20.0
18.8 94.010220.320.0µg/LBenzene 70-130 7.6 20.0
17.8 89.090.518.120.0µg/LBromobenzene 70-130 1.6 20.0
Page 3 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 68 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29384QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29383
LCS-V29383 LCSD-V29383Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.8 94.010621.120.0µg/LBromochloromethane 70-130 11.5 20.0
18.8 94.010621.120.0µg/LBromodichloromethane 70-130 11.5 20.0
20.9 10510921.720.0µg/LBromoform 70-130 3.7 20.0
15.9 79.582.016.420.0µg/LBromomethane 60-140 3.0 20.0
19.0 95.094.018.820.0µg/Ln-Butylbenzene 70-130 1.0 20.0
19.3 96.596.019.220.0µg/Lsec-Butyl benzene 70-130 0.5 20.0
19.3 96.595.019.020.0µg/Ltert-Butyl benzene 70-130 1.5 20.0
20.4 10211222.320.0µg/LCarbon Tetrachloride 70-130 8.8 20.0
19.8 99.010120.120.0µg/LChlorobenzene 70-130 1.5 20.0
21.1 10610420.820.0µg/LChlorodibromomethane 70-130 1.4 20.0
20.1 10111022.020.0µg/LChloroethane 60-140 9.0 20.0
19.4 97.010420.720.0µg/LChloroform 70-130 6.4 20.0
18.3 91.510220.320.0µg/LChloromethane 60-140 10.3 20.0
18.6 93.094.518.920.0µg/L2-Chlorotoluene 70-130 1.6 20.0
19.5 97.594.018.820.0µg/L4-Chlorotoluene 70-130 3.6 20.0
20.3 10211021.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 7.5 20.0
19.5 97.510821.520.0µg/L1,2-Dibromo-3-Chloropropane 70-130 9.7 20.0
18.1 90.595.519.120.0µg/LDibromomethane 70-130 5.3 20.0
20.4 10299.019.820.0µg/L1,2-Dichlorobenzene 70-130 2.9 20.0
19.8 99.010220.320.0µg/L1,3-Dichlorobenzene 70-130 2.4 20.0
19.9 99.599.519.920.0µg/L1,4-Dichlorobenzene 70-130 0.0 20.0
21.5 10897.519.520.0µg/LDichlorodifluoromethane 60-140 9.7 20.0
19.7 98.510521.020.0µg/L1,1-Dichloroethane 70-130 6.3 20.0
17.8 89.096.519.320.0µg/L1,2-Dichloroethane 70-130 8.0 20.0
18.8 94.099.519.920.0µg/L1,1-Dichloroethene 70-130 5.6 20.0
19.5 97.599.019.820.0µg/Lcis-1,2-Dichloroethene 70-130 1.5 20.0
Page 4 of 41Date:02/09/2023 02:32 PM
Page 69 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29384QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29383
LCS-V29383 LCSD-V29383Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.5 92.510120.120.0µg/Ltrans-1,2-Dichloroethene 70-130 8.2 20.0
19.0 95.010420.720.0µg/L1,2-Dichloropropane 70-130 8.5 20.0
18.2 91.099.519.920.0µg/L1,3-Dichloropropane 70-130 8.9 20.0
17.5 87.595.019.020.0µg/L2,2-Dichloropropane 70-130 8.2 20.0
20.1 10111122.120.0µg/L1,1-Dichloropropene 70-130 9.4 20.0
20.0 10010420.720.0µg/Lcis-1,3-Dichloropropene 70-130 3.4 20.0
18.8 94.010220.320.0µg/Ltrans-1,3-Dichloropropene 70-130 7.6 20.0
543 109118592500µg/LEthanol 60-140 8.6 20.0
19.1 95.596.019.220.0µg/LEthylbenzene 70-130 0.5 20.0
21.4 10710721.320.0µg/LHexachlorobutadiene 70-130 0.4 20.0
16.7 83.598.519.720.0µg/L2-Hexanone 60-140 16.4 20.0
19.8 99.095.519.120.0µg/LIsopropylbenzene 70-130 3.5 20.0
20.0 10097.519.520.0µg/L4-Isopropyl toluene 70-130 2.5 20.0
18.2 91.012023.920.0µg/LMethyl Ethyl Ketone (MEK)60-140 27.0*20.0
18.1 90.510320.520.0µg/LMethyl tert-butyl ether (MTBE)70-130 12.4 20.0
15.8 79.010020.020.0µg/L4-Methyl-2-Pentanone 60-140 23.4*20.0
17.7 88.595.519.120.0µg/LMethylene Chloride 70-130 7.6 20.0
17.7 88.594.518.920.0µg/LNaphthalene 70-130 6.5 20.0
19.3 96.594.518.920.0µg/Ln-Propylbenzene 70-130 2.0 20.0
20.2 10110120.220.0µg/LStyrene 70-130 0.0 20.0
33.2 83.087.034.840.0µg/Ltert-Butyl formate (TBF)40-140 4.7 20.0
38.4 96.010140.440.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 5.0 20.0
20.1 10199.519.920.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.0 20.0
18.0 90.098.019.620.0µg/L1,1,2,2-Tetrachloroethane 70-130 8.5 20.0
20.4 10210220.420.0µg/LTetrachloroethene 70-130 0.0 20.0
19.0 95.010120.120.0µg/LToluene 70-130 5.6 20.0
Page 5 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 70 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29384QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29383
LCS-V29383 LCSD-V29383Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.1 10110220.420.0µg/L1,2,3-Trichlorobenzene 70-130 1.4 20.0
19.5 97.510220.420.0µg/L1,2,4-Trichlorobenzene 70-130 4.5 20.0
19.1 95.510320.520.0µg/L1,1,1-Trichloroethane 70-130 7.0 20.0
18.8 94.010721.320.0µg/L1,1,2-Trichloroethane 70-130 12.4 20.0
19.8 99.010220.420.0µg/LTrichloroethene 70-130 2.9 20.0
19.8 99.010721.320.0µg/LTrichlorofluoromethane 60-140 7.2 20.0
16.7 83.590.518.120.0µg/L1,2,3-Trichloropropane 70-130 8.0 20.0
19.0 95.095.519.120.0µg/L1,2,4-Trimethylbenzene 70-130 0.5 20.0
19.8 99.097.019.420.0µg/L1,3,5-Trimethylbenzene 70-130 2.0 20.0
18.6 93.010120.120.0µg/LVinyl Acetate 60-140 7.7 20.0
20.2 10111222.320.0µg/LVinyl Chloride 60-140 9.8 20.0
18.9 94.596.019.220.0µg/Lo-Xylene 70-130 1.5 20.0
39.7 99.210140.340.0µg/Lm,p-Xylene 70-130 1.5 20.0
16.8 84.010621.120.0µg/L3,3-Dimethyl-1-butanol 70-130 22.6*20.0
98.294.84-Bromofluorobenzene (S)70-130
99.0106Dibromofluoromethane (S)70-130
92.097.41,2-Dichloroethane - d4 (S)70-130
101102Toluene-d8 (S)70-130
Page 6 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 71 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29470QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29469
Associated Lab Samples: 98594, 98595, 98596, 98597, 98598
LRB-V29469 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/02/23 14:3110.01.80<1.80µg/LAcetone
02/02/23 14:310.5000.180<0.180µg/LBenzene
02/02/23 14:310.5000.210<0.210µg/LBromobenzene
02/02/23 14:311.000.420<0.420µg/LBromochloromethane
02/02/23 14:310.5000.160<0.160µg/LBromodichloromethane
02/02/23 14:315.001.50<1.50µg/LBromoform
02/02/23 14:311.000.280<0.280µg/LBromomethane
02/02/23 14:310.5000.180<0.180µg/Ln-Butylbenzene
02/02/23 14:310.5000.200<0.200µg/Lsec-Butyl benzene
02/02/23 14:312.000.920<0.920µg/Ltert-Butyl benzene
02/02/23 14:310.5000.180<0.180µg/LCarbon Tetrachloride
02/02/23 14:310.5000.190<0.190µg/LChlorobenzene
02/02/23 14:310.5000.190<0.190µg/LChlorodibromomethane
02/02/23 14:311.000.430<0.430µg/LChloroethane
02/02/23 14:310.5000.220<0.220µg/LChloroform
02/02/23 14:310.5000.220<0.220µg/LChloromethane
02/02/23 14:310.5000.200<0.200µg/L2-Chlorotoluene
02/02/23 14:310.5000.200<0.200µg/L4-Chlorotoluene
02/02/23 14:310.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
02/02/23 14:312.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
02/02/23 14:310.5000.200<0.200µg/L1,2-Dibromoethane
02/02/23 14:310.5000.230<0.230µg/LDibromomethane
02/02/23 14:310.5000.220<0.220µg/L1,2-Dichlorobenzene
02/02/23 14:310.5000.190<0.190µg/L1,3-Dichlorobenzene
02/02/23 14:310.5000.210<0.210µg/L1,4-Dichlorobenzene
02/02/23 14:315.001.20<1.20µg/LDichlorodifluoromethane
02/02/23 14:310.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 41Date:02/09/2023 02:32 PM
Page 72 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29470QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29469
Associated Lab Samples: 98594, 98595, 98596, 98597, 98598
LRB-V29469 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/02/23 14:310.5000.150<0.150µg/L1,2-Dichloroethane
02/02/23 14:310.5000.150<0.150µg/L1,1-Dichloroethene
02/02/23 14:310.5000.200<0.200µg/Lcis-1,2-Dichloroethene
02/02/23 14:310.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
02/02/23 14:310.5000.190<0.190µg/L1,2-Dichloropropane
02/02/23 14:310.5000.130<0.130µg/L1,3-Dichloropropane
02/02/23 14:312.000.210<0.210µg/L2,2-Dichloropropane
02/02/23 14:310.5000.200<0.200µg/L1,1-Dichloropropene
02/02/23 14:310.5000.210<0.210µg/Lcis-1,3-Dichloropropene
02/02/23 14:310.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
02/02/23 14:3120042.0<42.0µg/LEthanol
02/02/23 14:310.5000.170<0.170µg/LEthylbenzene
02/02/23 14:313.000.350<0.350µg/LHexachlorobutadiene
02/02/23 14:311.000.380<0.380µg/L2-Hexanone
02/02/23 14:310.5000.180<0.180µg/LIsopropylbenzene
02/02/23 14:310.5000.089<0.089µg/L4-Isopropyl toluene
02/02/23 14:315.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
02/02/23 14:311.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
02/02/23 14:311.000.078<0.078µg/L4-Methyl-2-Pentanone
02/02/23 14:312.000.330<0.330µg/LMethylene Chloride
02/02/23 14:311.000.470<0.470µg/LNaphthalene
02/02/23 14:310.5000.190<0.190µg/Ln-Propylbenzene
02/02/23 14:310.5000.220<0.220µg/LStyrene
02/02/23 14:3110.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
02/02/23 14:3110.00.350<0.350µg/Ltert-Butyl formate (TBF)
02/02/23 14:3110.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
02/02/23 14:3110.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 8 of 41Date:02/09/2023 02:32 PM
Page 73 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29470QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29469
Associated Lab Samples: 98594, 98595, 98596, 98597, 98598
LRB-V29469 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/02/23 14:310.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
02/02/23 14:310.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
02/02/23 14:310.5000.220<0.220µg/LTetrachloroethene
02/02/23 14:310.5000.220<0.220µg/LToluene
02/02/23 14:310.5000.380<0.380µg/L1,2,3-Trichlorobenzene
02/02/23 14:310.5000.310<0.310µg/L1,2,4-Trichlorobenzene
02/02/23 14:310.5000.160<0.160µg/L1,1,1-Trichloroethane
02/02/23 14:310.5000.096<0.096µg/L1,1,2-Trichloroethane
02/02/23 14:310.5000.180<0.180µg/LTrichloroethene
02/02/23 14:310.5000.180<0.180µg/LTrichlorofluoromethane
02/02/23 14:310.5000.270<0.270µg/L1,2,3-Trichloropropane
02/02/23 14:310.5000.190<0.190µg/L1,2,4-Trimethylbenzene
02/02/23 14:310.5000.180<0.180µg/L1,3,5-Trimethylbenzene
02/02/23 14:315.001.00<1.00µg/LVinyl Acetate
02/02/23 14:310.5000.170<0.170µg/LVinyl Chloride
02/02/23 14:310.5000.210<0.210µg/Lo-Xylene
02/02/23 14:311.000.420<0.420µg/Lm,p-Xylene
02/02/23 14:3110.01.00<1.00µg/L3,3-Dimethyl-1-butanol
02/02/23 14:314-Bromofluorobenzene (S)97.2 70-130
02/02/23 14:31Dibromofluoromethane (S)96.4 70-130
02/02/23 14:311,2-Dichloroethane - d4 (S)93.6 70-130
02/02/23 14:31Toluene-d8 (S)100 70-130
Page 9 of 41Date:02/09/2023 02:32 PM
Page 74 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29470QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29469
LCS-V29469 LCSD-V29469Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
49.6 12416063.940.0µg/LAcetone 40-160 25.1*20.0
19.0 95.099.019.820.0µg/LBenzene 70-130 4.1 20.0
18.0 90.095.019.020.0µg/LBromobenzene 70-130 5.4 20.0
19.8 99.010420.720.0µg/LBromochloromethane 70-130 4.4 20.0
19.8 99.010520.920.0µg/LBromodichloromethane 70-130 5.4 20.0
22.2 11112925.720.0µg/LBromoform 70-130 14.6 20.0
17.1 85.591.518.320.0µg/LBromomethane 60-140 6.7 20.0
19.1 95.596.019.220.0µg/Ln-Butylbenzene 70-130 0.5 20.0
19.2 96.099.019.820.0µg/Lsec-Butyl benzene 70-130 3.0 20.0
19.3 96.597.019.420.0µg/Ltert-Butyl benzene 70-130 0.5 20.0
20.8 10411021.920.0µg/LCarbon Tetrachloride 70-130 5.1 20.0
19.9 99.510320.520.0µg/LChlorobenzene 70-130 2.9 20.0
19.9 99.511222.420.0µg/LChlorodibromomethane 70-130 11.8 20.0
20.1 10110420.720.0µg/LChloroethane 60-140 2.9 20.0
19.5 97.510520.920.0µg/LChloroform 70-130 6.9 20.0
18.1 90.596.019.220.0µg/LChloromethane 60-140 5.8 20.0
19.0 95.097.519.520.0µg/L2-Chlorotoluene 70-130 2.5 20.0
19.5 97.510020.020.0µg/L4-Chlorotoluene 70-130 2.5 20.0
19.8 99.010621.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 6.8 20.0
21.0 10512825.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 19.7 20.0
19.3 96.510821.520.0µg/L1,2-Dibromoethane 70-130 10.7 20.0
17.7 88.510320.620.0µg/LDibromomethane 70-130 15.1 20.0
20.3 10210521.020.0µg/L1,2-Dichlorobenzene 70-130 3.3 20.0
19.7 98.510420.720.0µg/L1,3-Dichlorobenzene 70-130 4.9 20.0
20.0 10010821.620.0µg/L1,4-Dichlorobenzene 70-130 7.6 20.0
21.3 10711222.420.0µg/LDichlorodifluoromethane 60-140 5.0 20.0
Page 10 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 75 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29470QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29469
LCS-V29469 LCSD-V29469Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.9 99.510420.720.0µg/L1,1-Dichloroethane 70-130 3.9 20.0
18.6 93.099.019.820.0µg/L1,2-Dichloroethane 70-130 6.2 20.0
19.2 96.010320.520.0µg/L1,1-Dichloroethene 70-130 6.5 20.0
19.3 96.510220.320.0µg/Lcis-1,2-Dichloroethene 70-130 5.0 20.0
18.5 92.594.518.920.0µg/Ltrans-1,2-Dichloroethene 70-130 2.1 20.0
19.3 96.599.519.920.0µg/L1,2-Dichloropropane 70-130 3.0 20.0
18.8 94.010320.620.0µg/L1,3-Dichloropropane 70-130 9.1 20.0
19.3 96.510220.320.0µg/L2,2-Dichloropropane 70-130 5.0 20.0
21.0 10511122.120.0µg/L1,1-Dichloropropene 70-130 5.1 20.0
19.4 97.010621.120.0µg/Lcis-1,3-Dichloropropene 70-130 8.3 20.0
18.8 94.010220.420.0µg/Ltrans-1,3-Dichloropropene 70-130 8.1 20.0
607 121131653500µg/LEthanol 60-140 7.3 20.0
19.1 95.510120.120.0µg/LEthylbenzene 70-130 5.1 20.0
22.0 11011322.520.0µg/LHexachlorobutadiene 70-130 2.2 20.0
18.4 92.011122.220.0µg/L2-Hexanone 60-140 18.7 20.0
19.2 96.099.519.920.0µg/LIsopropylbenzene 70-130 3.5 20.0
19.8 99.010220.420.0µg/L4-Isopropyl toluene 70-130 2.9 20.0
19.6 98.012825.520.0µg/LMethyl Ethyl Ketone (MEK)60-140 26.1*20.0
18.7 93.599.519.920.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.2 20.0
17.2 86.010120.220.0µg/L4-Methyl-2-Pentanone 60-140 16.0 20.0
17.5 87.594.518.920.0µg/LMethylene Chloride 70-130 7.6 20.0
18.6 93.010721.320.0µg/LNaphthalene 70-130 13.5 20.0
18.9 94.599.019.820.0µg/Ln-Propylbenzene 70-130 4.6 20.0
19.8 99.010420.820.0µg/LStyrene 70-130 4.9 20.0
32.2 80.510541.940.0µg/Ltert-Butyl Alcohol (TBA)40-140 26.1*20.0
39.7 99.210843.240.0µg/Ltert-Butyl formate (TBF)40-140 8.4 20.0
Page 11 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 76 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29470QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29469
LCS-V29469 LCSD-V29469Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.7 88.512524.920.0µg/Ltert-Amyl Alcohol (TAA)40-140 33.8*20.0
39.0 97.510642.540.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 8.5 20.0
20.7 10410621.120.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.9 20.0
19.8 99.011322.520.0µg/L1,1,2,2-Tetrachloroethane 70-130 12.7 20.0
20.4 10210721.320.0µg/LTetrachloroethene 70-130 4.3 20.0
18.6 93.099.519.920.0µg/LToluene 70-130 6.7 20.0
21.0 10511122.220.0µg/L1,2,3-Trichlorobenzene 70-130 5.5 20.0
19.9 99.511022.020.0µg/L1,2,4-Trichlorobenzene 70-130 10.0 20.0
20.0 10010220.320.0µg/L1,1,1-Trichloroethane 70-130 1.4 20.0
19.0 95.010320.520.0µg/L1,1,2-Trichloroethane 70-130 7.5 20.0
19.5 97.510420.720.0µg/LTrichloroethene 70-130 5.9 20.0
19.9 99.510220.420.0µg/LTrichlorofluoromethane 60-140 2.4 20.0
17.9 89.510220.420.0µg/L1,2,3-Trichloropropane 70-130 13.0 20.0
19.0 95.010020.020.0µg/L1,2,4-Trimethylbenzene 70-130 5.1 20.0
19.5 97.598.519.720.0µg/L1,3,5-Trimethylbenzene 70-130 1.0 20.0
23.4 11713226.420.0µg/LVinyl Acetate 60-140 12.0 20.0
19.6 98.010220.420.0µg/LVinyl Chloride 60-140 4.0 20.0
19.3 96.597.519.520.0µg/Lo-Xylene 70-130 1.0 20.0
38.4 96.010240.640.0µg/Lm,p-Xylene 70-130 5.5 20.0
18.4 92.011823.520.0µg/L3,3-Dimethyl-1-butanol 70-130 24.3*20.0
99.097.04-Bromofluorobenzene (S)70-130
101100Dibromofluoromethane (S)70-130
92.698.01,2-Dichloroethane - d4 (S)70-130
99.2101Toluene-d8 (S)70-130
Page 12 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 77 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29529QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29528
Associated Lab Samples: 98597
LRB-V29528 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 13:580.5000.180<0.180µg/LBenzene
02/03/23 13:580.5000.170<0.170µg/LEthylbenzene
02/03/23 13:581.000.470<0.470µg/LNaphthalene
02/03/23 13:580.5000.190<0.190µg/Ln-Propylbenzene
02/03/23 13:5810.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
02/03/23 13:580.5000.220<0.220µg/LToluene
02/03/23 13:580.5000.190<0.190µg/L1,2,4-Trimethylbenzene
02/03/23 13:580.5000.180<0.180µg/L1,3,5-Trimethylbenzene
02/03/23 13:580.5000.210<0.210µg/Lo-Xylene
02/03/23 13:581.000.420<0.420µg/Lm,p-Xylene
02/03/23 13:584-Bromofluorobenzene (S)100 70-130
02/03/23 13:58Dibromofluoromethane (S)97.6 70-130
02/03/23 13:581,2-Dichloroethane - d4 (S)98.2 70-130
02/03/23 13:58Toluene-d8 (S)100 70-130
LCS-V29528 LCSD-V29528Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.9 99.510120.220.0µg/LBenzene 70-130 1.4 20.0
19.8 99.010320.620.0µg/LEthylbenzene 70-130 3.9 20.0
17.2 86.085.517.120.0µg/LNaphthalene 70-130 0.5 20.0
20.8 10410721.420.0µg/Ln-Propylbenzene 70-130 2.8 20.0
21.1 10612524.920.0µg/Ltert-Amyl Alcohol (TAA)40-140 16.5 20.0
20.2 10110120.120.0µg/LToluene 70-130 0.4 20.0
21.3 10710921.720.0µg/L1,2,4-Trimethylbenzene 70-130 1.8 20.0
21.7 10911222.320.0µg/L1,3,5-Trimethylbenzene 70-130 2.7 20.0
Page 13 of 41Date:02/09/2023 02:32 PM
Page 78 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29529QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29528
LCS-V29528 LCSD-V29528Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.1 10610721.320.0µg/Lo-Xylene 70-130 0.9 20.0
42.3 10611043.840.0µg/Lm,p-Xylene 70-130 3.4 20.0
10098.64-Bromofluorobenzene (S)70-130
98.696.8Dibromofluoromethane (S)70-130
99.099.01,2-Dichloroethane - d4 (S)70-130
100101Toluene-d8 (S)70-130
Page 14 of 41Date:02/09/2023 02:32 PM
Page 79 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29518QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29366
Associated Lab Samples: 98594
LRB-V29366 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/01/23 15:192.000.302<0.302µg/LAcenaphthene
02/01/23 15:192.000.297<0.297µg/LAcenaphthylene
02/01/23 15:192.000.836<0.836µg/LAnthracene
02/01/23 15:1910.01.32<1.32µg/LBenzidine
02/01/23 15:192.000.637<0.637µg/LBenzo(a)anthracene
02/01/23 15:192.001.02<1.02µg/LBenzo(a)pyrene
02/01/23 15:195.002.49<2.49µg/LBenzo(b)fluoranthene
02/01/23 15:195.001.01<1.01µg/LBenzo(g,h,i)perylene
02/01/23 15:195.001.99<1.99µg/LBenzo(k)fluoranthene
02/01/23 15:1910.01.10<1.10µg/LBenzoic Acid
02/01/23 15:195.000.684<0.684µg/LBenzyl alcohol
02/01/23 15:195.000.468<0.468µg/LBis(2-Chloroethoxy)methane
02/01/23 15:195.001.04<1.04µg/LBis(2-Chloroethyl)ether
02/01/23 15:195.001.08<1.08µg/LBis(2-Chloroisopropyl)ether
02/01/23 15:1910.03.46<3.46µg/LBis(2-ethylhexyl)phthalate
02/01/23 15:195.001.11<1.11µg/L4-Bromophenyl phenyl ether
02/01/23 15:195.001.83<1.83µg/LButyl benzyl phthalate
02/01/23 15:195.001.18<1.18µg/L4-Chloro-3-methylphenol
02/01/23 15:1920.07.38<7.38µg/L2-Chloronaphthalene
02/01/23 15:1910.00.938<0.938µg/L2-Chlorophenol
02/01/23 15:195.001.71<1.71µg/L4-Chlorophenyl phenyl ether
02/01/23 15:192.000.405<0.405µg/LChrysene
02/01/23 15:192.000.434<0.434µg/LDibenz(a,h)anthracene
02/01/23 15:195.000.856<0.856µg/LDibenzofuran
02/01/23 15:195.002.00<2.00µg/L1,2-Dichlorobenzene
02/01/23 15:195.002.00<2.00µg/L1,3-Dichlorobenzene
02/01/23 15:195.002.05<2.05µg/L1,4-Dichlorobenzene
Page 15 of 41Date:02/09/2023 02:32 PM
Page 80 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29518QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29366
Associated Lab Samples: 98594
LRB-V29366 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/01/23 15:195.001.89<1.89µg/L3,3'-Dichlorobenzidine
02/01/23 15:1910.01.46<1.46µg/L2,4-Dichlorophenol
02/01/23 15:195.000.745<0.745µg/LDiethyl phthalate
02/01/23 15:195.000.939<0.939µg/LDimethyl phthalate
02/01/23 15:1920.01.57<1.57µg/L2,4-Dimethylphenol
02/01/23 15:195.002.06<2.06µg/LDi-n-butyl phthalate
02/01/23 15:1910.02.07<2.07µg/L4,6-Dinitro-2-methylphenol
02/01/23 15:1910.01.92<1.92µg/L2,4-Dinitrophenol
02/01/23 15:195.001.11<1.11µg/L2,4-Dinitrotoluene
02/01/23 15:195.000.809<0.809µg/L2,6-Dinitrotoluene
02/01/23 15:195.001.65<1.65µg/LDi-n-Octyl Phthalate
02/01/23 15:192.000.250<0.250µg/LFluoranthene
02/01/23 15:192.000.807<0.807µg/LFluorene
02/01/23 15:195.000.979<0.979µg/LHexachlorobenzene
02/01/23 15:195.002.73<2.73µg/LHexachlorobutadiene
02/01/23 15:195.002.05<2.05µg/LHexachlorocyclopentadiene
02/01/23 15:195.001.76<1.76µg/LHexachloroethane
02/01/23 15:192.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene
02/01/23 15:195.000.444<0.444µg/LIsophorone
02/01/23 15:192.000.728<0.728µg/LNaphthalene
02/01/23 15:195.000.905<0.905µg/LNitrobenzene
02/01/23 15:195.000.493<0.493µg/L2-Nitrophenol
02/01/23 15:1910.01.23<1.23µg/L4-Nitrophenol
02/01/23 15:195.001.10<1.10µg/LN-Nitrosodiphenylamine
02/01/23 15:195.000.641<0.641µg/LN-Nitroso-di-n-propylamine
02/01/23 15:195.001.43<1.43µg/LPentachlorophenol
02/01/23 15:192.000.428<0.428µg/LPhenanthrene
Page 16 of 41Date:02/09/2023 02:32 PM
Page 81 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29518QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29366
Associated Lab Samples: 98594
LRB-V29366 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/01/23 15:195.000.651<0.651µg/LPhenol
02/01/23 15:192.000.434<0.434µg/LPyrene
02/01/23 15:195.002.21<2.21µg/L1,2,4-Trichlorobenzene
02/01/23 15:195.001.32<1.32µg/L2,4,6-Trichlorophenol
02/01/23 15:192-Fluorobiphenyl (S)76.6 49-118
02/01/23 15:192-Fluorophenol (S)42.9 22-84
02/01/23 15:19Nitrobenzene-d5 (S)78.0 43-123
02/01/23 15:194-Terphenyl-d14 (S)101 49-151
02/01/23 15:192,4,6-Tribromophenol (S)68.1 31-144
02/01/23 15:19Phenol-d5 (S)29.3 10-63
LCS-V29366 LCSD-V29366Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
38.2 76.471.435.750.0µg/LAcenaphthene 47-145 6.7 20.0
40.9 81.875.037.550.0µg/LAcenaphthylene 33-145 8.6 20.0
44.5 89.082.641.350.0µg/LAnthracene 27-133 7.4 20.0
31.2 62.442.421.250.0µg/LBenzidine 15-150 38.1*20.0
43.3 86.682.841.450.0µg/LBenzo(a)anthracene 33-143 4.4 20.0
47.5 95.088.444.250.0µg/LBenzo(a)pyrene 17-163 7.1 20.0
44.3 88.683.241.650.0µg/LBenzo(b)fluoranthene 24-159 6.2 20.0
40.7 81.477.238.650.0µg/LBenzo(g,h,i)perylene 10-219 5.2 20.0
44.6 89.284.042.050.0µg/LBenzo(k)fluoranthene 11-162 6.0 20.0
23.2 46.440.220.150.0µg/LBenzoic Acid 10-125 14.3 20.0
33.8 67.662.031.050.0µg/LBenzyl alcohol 16-107 8.6 20.0
38.3 76.668.834.450.0µg/LBis(2-Chloroethoxy)methane 33-184 10.7 20.0
Page 17 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 82 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29518QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29366
LCS-V29366 LCSD-V29366Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.3 62.658.829.450.0µg/LBis(2-Chloroethyl)ether 12-158 6.2 20.0
33.6 67.260.430.250.0µg/LBis(2-Chloroisopropyl)ether 36-166 10.6 20.0
50.4 10194.447.250.0µg/LBis(2-ethylhexyl)phthalate 10-158 6.5 20.0
41.4 82.878.639.350.0µg/L4-Bromophenyl phenyl ether 53-127 5.2 20.0
50.6 10195.047.550.0µg/LButyl benzyl phthalate 10-152 6.3 20.0
42.2 84.476.038.050.0µg/L4-Chloro-3-methylphenol 22-147 10.4 20.0
37.8 75.668.834.450.0µg/L2-Chloronaphthalene 60-118 9.4 20.0
31.9 63.857.428.750.0µg/L2-Chlorophenol 23-134 10.5 20.0
41.0 82.075.637.850.0µg/L4-Chlorophenyl phenyl ether 25-158 8.1 20.0
43.0 86.081.040.550.0µg/LChrysene 17-168 5.9 20.0
44.6 89.280.840.450.0µg/LDibenz(a,h)anthracene 10-227 9.8 20.0
40.6 81.274.037.050.0µg/LDibenzofuran 39-114 9.2 20.0
26.4 52.850.425.250.0µg/L1,2-Dichlorobenzene 32-129 4.6 20.0
25.4 50.848.624.350.0µg/L1,3-Dichlorobenzene 20-124 4.4 20.0
26.1 52.248.424.250.0µg/L1,4-Dichlorobenzene 20-124 7.5 20.0
43.4 86.881.840.950.0µg/L3,3'-Dichlorobenzidine 10-262 5.9 20.0
39.4 78.869.034.550.0µg/L2,4-Dichlorophenol 39-135 13.2 20.0
44.3 88.681.640.850.0µg/LDiethyl phthalate 10-114 8.2 20.0
43.0 86.081.440.750.0µg/LDimethyl phthalate 10-112 5.4 20.0
52.6 10593.446.750.0µg/L2,4-Dimethylphenol 32-119 11.8 20.0
50.4 10193.246.650.0µg/LDi-n-butyl phthalate 10-118 7.8 20.0
48.5 97.079.839.950.0µg/L4,6-Dinitro-2-methylphenol 10-181 19.4 20.0
52.5 10584.242.150.0µg/L2,4-Dinitrophenol 10-191 21.9*20.0
44.9 89.878.239.150.0µg/L2,4-Dinitrotoluene 39-139 13.8 20.0
42.5 85.070.435.250.0µg/L2,6-Dinitrotoluene 50-158 18.7 20.0
53.3 10798.649.350.0µg/LDi-n-Octyl Phthalate 10-146 7.7 20.0
Page 18 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 83 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29518QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29366
LCS-V29366 LCSD-V29366Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
40.8 81.676.438.250.0µg/LFluoranthene 26-137 6.5 20.0
41.3 82.675.637.850.0µg/LFluorene 59-121 8.8 20.0
40.3 80.676.238.150.0µg/LHexachlorobenzene 10-152 5.6 20.0
29.4 58.854.027.050.0µg/LHexachlorobutadiene 24-116 8.5 20.0
22.3 44.639.819.950.0µg/LHexachlorocyclopentadiene 32-117 11.3 20.0
24.4 48.847.223.650.0µg/LHexachloroethane 40-113 3.3 20.0
41.3 82.676.238.150.0µg/LIndeno(1,2,3-cd)pyrene 10-171 8.0 20.0
25.1 50.245.022.550.0µg/LIsophorone 21-196 10.9 20.0
31.9 63.859.229.650.0µg/LNaphthalene 21-133 7.4 20.0
36.3 72.663.231.650.0µg/LNitrobenzene 35-180 13.8 20.0
39.7 79.465.832.950.0µg/L2-Nitrophenol 29-182 18.7 20.0
17.4 34.830.015.050.0µg/L4-Nitrophenol 10-132 14.8 20.0
50.6 10197.848.950.0µg/LN-Nitrosodiphenylamine 69-152 3.4 20.0
37.1 74.267.433.750.0µg/LN-Nitroso-di-n-propylamine 10-230 9.6 20.0
51.8 10496.048.050.0µg/LPentachlorophenol 14-176 7.6 20.0
43.0 86.080.640.350.0µg/LPhenanthrene 54-120 6.4 20.0
14.1 28.225.812.950.0µg/LPhenol 10-112 8.8 20.0
44.0 88.083.041.550.0µg/LPyrene 52-115 5.8 20.0
29.0 58.053.626.850.0µg/L1,2,4-Trichlorobenzene 44-142 7.8 20.0
41.3 82.674.237.150.0µg/L2,4,6-Trichlorophenol 37-144 10.7 20.0
72.072.22-Fluorobiphenyl (S)49-118
35.233.92-Fluorophenol (S)22-84
73.866.4Nitrobenzene-d5 (S)43-123
89.091.04-Terphenyl-d14 (S)49-151
78.374.32,4,6-Tribromophenol (S)31-144
Page 19 of 41Date:02/09/2023 02:32 PM
Page 84 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
625.1 - Base/Neutrals and Acids by GC/MS
625.1
V29518QC Analytical Batch(es):
Analysis Method:
Analysis Description:
625.1 (Prep)
QC Prep:V29366
LCS-V29366 LCSD-V29366Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
25.324.1Phenol-d5 (S)10-63
Page 20 of 41Date:02/09/2023 02:32 PM
Page 85 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V29301QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V29300
Associated Lab Samples: 98599
LRB-V29300 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/30/23 10:310.0200.002<0.002mg/KgAcetone
01/30/23 10:310.0200.001<0.001mg/KgAcrolein
01/30/23 10:310.0200.0008<0.0008mg/KgAcrylonitrile
01/30/23 10:310.0050.0006<0.0006mg/KgBenzene
01/30/23 10:310.0050.0005<0.0005mg/KgBromobenzene
01/30/23 10:310.0050.0008<0.0008mg/KgBromochloromethane
01/30/23 10:310.0050.001<0.001mg/KgBromodichloromethane
01/30/23 10:310.0050.001<0.001mg/KgBromoform
01/30/23 10:310.0100.001<0.001mg/KgBromomethane
01/30/23 10:310.0050.0005<0.0005mg/Kgn-Butylbenzene
01/30/23 10:310.0050.0006<0.0006mg/Kgsec-Butyl benzene
01/30/23 10:310.0050.0005<0.0005mg/Kgtert-Butyl benzene
01/30/23 10:310.0050.0006<0.0006mg/KgCarbon Disulfide
01/30/23 10:310.0050.001<0.001mg/KgCarbon Tetrachloride
01/30/23 10:310.0050.0007<0.0007mg/KgChlorobenzene
01/30/23 10:310.0050.0009<0.0009mg/KgChlorodibromomethane
01/30/23 10:310.0100.0009<0.0009mg/KgChloroethane
01/30/23 10:310.0050.001<0.001mg/KgChloroform
01/30/23 10:310.0100.0006<0.0006mg/KgChloromethane
01/30/23 10:310.0050.0005<0.0005mg/Kg2-Chlorotoluene
01/30/23 10:310.0050.0004<0.0004mg/Kg4-Chlorotoluene
01/30/23 10:310.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
01/30/23 10:310.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
01/30/23 10:310.0050.0006<0.0006mg/Kg1,2-Dibromoethane
01/30/23 10:310.0050.0006<0.0006mg/KgDibromomethane
01/30/23 10:310.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
01/30/23 10:310.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 21 of 41Date:02/09/2023 02:32 PM
Page 86 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V29301QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V29300
Associated Lab Samples: 98599
LRB-V29300 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/30/23 10:310.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
01/30/23 10:310.0100.001<0.001mg/KgDichlorodifluoromethane
01/30/23 10:310.0050.0008<0.0008mg/Kg1,1-Dichloroethane
01/30/23 10:310.0050.001<0.001mg/Kg1,2-Dichloroethane
01/30/23 10:310.0050.0007<0.0007mg/Kg1,1-Dichloroethene
01/30/23 10:310.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
01/30/23 10:310.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
01/30/23 10:310.0050.0004<0.0004mg/Kg1,2-Dichloropropane
01/30/23 10:310.0050.0006<0.0006mg/Kg1,3-Dichloropropane
01/30/23 10:310.0050.001<0.001mg/Kg2,2-Dichloropropane
01/30/23 10:310.0050.0008<0.0008mg/Kg1,1-Dichloropropene
01/30/23 10:310.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
01/30/23 10:310.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
01/30/23 10:310.0050.0006<0.0006mg/KgEthylbenzene
01/30/23 10:310.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
01/30/23 10:310.0100.0008<0.0008mg/KgHexachlorobutadiene
01/30/23 10:310.0100.0007<0.0007mg/Kgn-Hexane
01/30/23 10:310.0200.0006<0.0006mg/Kg2-Hexanone
01/30/23 10:310.0050.0005<0.0005mg/KgIsopropylbenzene
01/30/23 10:310.0050.001<0.001mg/Kg4-Isopropyl toluene
01/30/23 10:310.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
01/30/23 10:310.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
01/30/23 10:310.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
01/30/23 10:310.0100.001<0.001mg/KgMethylene Chloride
01/30/23 10:310.0100.0010<0.0010mg/KgNaphthalene
01/30/23 10:310.0050.0005<0.0005mg/Kgn-Propylbenzene
01/30/23 10:310.0050.001<0.001mg/KgStyrene
Page 22 of 41Date:02/09/2023 02:32 PM
Page 87 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V29301QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V29300
Associated Lab Samples: 98599
LRB-V29300 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/30/23 10:310.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
01/30/23 10:310.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
01/30/23 10:310.0050.0009<0.0009mg/KgTetrachloroethene
01/30/23 10:310.0050.0007<0.0007mg/KgToluene
01/30/23 10:310.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
01/30/23 10:310.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
01/30/23 10:310.0050.001<0.001mg/Kg1,1,1-Trichloroethane
01/30/23 10:310.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
01/30/23 10:310.0050.0009<0.0009mg/KgTrichloroethene
01/30/23 10:310.0100.002<0.002mg/KgTrichlorofluoromethane
01/30/23 10:310.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
01/30/23 10:310.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
01/30/23 10:310.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
01/30/23 10:310.0100.0005<0.0005mg/KgVinyl Acetate
01/30/23 10:310.0100.0005<0.0005mg/KgVinyl Chloride
01/30/23 10:310.0050.0005<0.0005mg/Kgo-Xylene
01/30/23 10:310.0100.001<0.001mg/Kgm,p-Xylene
01/30/23 10:314-Bromofluorobenzene (S)101 70-130
01/30/23 10:31Dibromofluoromethane (S)104 84-123
01/30/23 10:31Toluene-d8 (S)101 76-129
LCS-V29300 LCSD-V29300Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.110 1101030.1030.100mg/KgAcetone 29-198 6.5 20
0.072 72.782.40.0820.100mg/KgAcrolein 70-130 12.5 20
Page 23 of 41Date:02/09/2023 02:32 PM
Page 88 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V29301QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V29300
LCS-V29300 LCSD-V29300Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.097 97.01120.1120.100mg/KgAcrylonitrile 65-134 14.3 20
0.051 1021050.0520.050mg/KgBenzene 74-127 3.0 20
0.048 97.697.40.0480.050mg/KgBromobenzene 73-125 0.2 20
0.050 1021100.0540.050mg/KgBromochloromethane 72-134 7.5 20
0.050 1021090.0540.050mg/KgBromodichloromethane 75-122 7.1 20
0.047 94.61040.0520.050mg/KgBromoform 66-135 9.6 20
0.036 73.872.20.0360.050mg/KgBromomethane 20-180 2.1 20
0.048 97.21020.0510.050mg/Kgn-Butylbenzene 65-135 5.2 20
0.046 92.696.80.0480.050mg/Kgsec-Butyl benzene 66-131 4.4 20
0.046 92.295.40.0470.050mg/Kgtert-Butyl benzene 67-132 3.4 20
0.047 95.698.20.0490.050mg/KgCarbon Disulfide 61-129 2.6 20
0.045 90.21090.0540.050mg/KgCarbon Tetrachloride 64-143 18.8 20
0.047 95.099.60.0490.050mg/KgChlorobenzene 74-118 4.7 20
0.049 98.21010.0500.050mg/KgChlorodibromomethane 73-122 3.2 20
0.042 84.693.80.0460.050mg/KgChloroethane 33-149 10.3 20
0.050 10199.80.0490.050mg/KgChloroform 73-127 0.7 20
0.037 74.682.40.0410.050mg/KgChloromethane 45-143 9.9 20
0.046 92.896.20.0480.050mg/Kg2-Chlorotoluene 67-124 3.5 20
0.046 92.896.20.0480.050mg/Kg4-Chlorotoluene 71-126 3.5 20
0.047 95.498.00.0490.050mg/KgDi-Isopropyl Ether (DIPE)59-159 2.6 20
0.048 96.61140.0560.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 16.1 20
0.048 97.81030.0510.050mg/Kg1,2-Dibromoethane 70-132 5.5 20
0.049 99.61040.0520.050mg/KgDibromomethane 74-133 4.7 20
0.048 96.097.60.0480.050mg/Kg1,2-Dichlorobenzene 72-123 1.6 20
0.046 92.894.60.0470.050mg/Kg1,3-Dichlorobenzene 71-120 1.9 20
0.046 92.095.80.0470.050mg/Kg1,4-Dichlorobenzene 71-123 4.0 20
Page 24 of 41Date:02/09/2023 02:32 PM
Page 89 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V29301QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V29300
LCS-V29300 LCSD-V29300Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.035 71.679.40.0390.050mg/KgDichlorodifluoromethane 26-146 10.3 20
0.047 95.61010.0500.050mg/Kg1,1-Dichloroethane 74-127 5.2 20
0.049 99.41010.0500.050mg/Kg1,2-Dichloroethane 68-128 1.9 20
0.046 92.61000.0500.050mg/Kg1,1-Dichloroethene 67-149 7.8 20
0.048 97.81020.0510.050mg/Kgcis-1,2-Dichloroethene 76-134 4.4 20
0.048 97.61020.0510.050mg/Kgtrans-1,2-Dichloroethene 73-132 4.6 20
0.050 1001030.0510.050mg/Kg1,2-Dichloropropane 73-130 2.9 20
0.050 1011030.0510.050mg/Kg1,3-Dichloropropane 75-124 2.5 20
0.049 98.21030.0510.050mg/Kg2,2-Dichloropropane 50-142 4.3 20
0.047 95.81060.0520.050mg/Kg1,1-Dichloropropene 71-130 9.7 20
0.051 1031110.0550.050mg/Kgcis-1,3-Dichloropropene 71-125 7.5 20
0.055 1111150.0570.050mg/Kgtrans-1,3-Dichloropropene 68-123 3.1 20
0.044 89.294.60.0470.050mg/KgEthylbenzene 74-128 5.8 20
0.100 1001020.1020.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 1.9 20
0.043 87.892.00.0460.050mg/KgHexachlorobutadiene 64-125 4.6 20
0.046 93.01090.0540.050mg/Kgn-Hexane 70-130 15.8 20
0.041 83.689.00.0440.050mg/Kg2-Hexanone 61-157 6.2 20
0.046 93.094.00.0470.050mg/KgIsopropylbenzene 68-126 1.0 20
0.047 94.897.60.0480.050mg/Kg4-Isopropyl toluene 68-129 2.9 20
0.042 84.287.00.0430.050mg/KgMethyl Ethyl Ketone (MEK)63-149 3.2 20
0.050 1011050.0520.050mg/KgMethyl tert-butyl ether (MTBE)70-130 3.8 20
0.050 1001110.0550.050mg/Kg4-Methyl-2-Pentanone 57-162 10.2 20
0.045 90.093.20.0460.050mg/KgMethylene Chloride 74-129 3.4 20
0.047 95.41000.0500.050mg/KgNaphthalene 57-157 4.7 20
0.046 92.895.40.0470.050mg/Kgn-Propylbenzene 67-130 2.7 20
0.049 99.61020.0510.050mg/KgStyrene 77-121 2.5 20
Page 25 of 41Date:02/09/2023 02:32 PM
Page 90 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V29301QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V29300
LCS-V29300 LCSD-V29300Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.047 94.097.60.0480.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 3.7 20
0.047 95.41010.0500.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 6.0 20
0.046 93.01010.0500.050mg/KgTetrachloroethene 68-130 8.0 20
0.049 98.21010.0500.050mg/KgToluene 71-129 2.4 20
0.045 91.493.00.0460.050mg/Kg1,2,3-Trichlorobenzene 68-130 1.7 20
0.047 95.699.80.0490.050mg/Kg1,2,4-Trichlorobenzene 66-125 4.2 20
0.049 98.21030.0510.050mg/Kg1,1,1-Trichloroethane 67-131 4.9 20
0.048 96.01030.0510.050mg/Kg1,1,2-Trichloroethane 70-133 7.2 20
0.047 95.01020.0510.050mg/KgTrichloroethene 75-133 7.3 20
0.044 89.895.40.0470.050mg/KgTrichlorofluoromethane 44-146 6.0 20
0.051 10397.00.0480.050mg/Kg1,2,3-Trichloropropane 60-137 6.0 20
0.048 96.496.20.0480.050mg/Kg1,2,4-Trimethylbenzene 69-129 0.2 20
0.046 93.095.40.0470.050mg/Kg1,3,5-Trimethylbenzene 69-128 2.5 20
0.038 76.077.20.0380.050mg/KgVinyl Acetate 60-140 1.5 20
0.041 82.084.40.0420.050mg/KgVinyl Chloride 48-147 2.8 20
0.046 92.695.80.0470.050mg/Kgo-Xylene 74-126 3.3 20
0.091 91.597.20.0970.100mg/Kgm,p-Xylene 75-124 6.0 20
97.099.04-Bromofluorobenzene (S)70-130
108107Dibromofluoromethane (S)84-123
97.897.6Toluene-d8 (S)76-129
Page 26 of 41Date:02/09/2023 02:32 PM
Page 91 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
Associated Lab Samples: 98599
LRB-V29475 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/06/23 09:510.6600.116<0.116mg/KgAcenaphthene
02/06/23 09:510.6600.105<0.105mg/KgAcenaphthylene
02/06/23 09:510.6600.152<0.152mg/KgAniline
02/06/23 09:510.6600.143<0.143mg/KgAnthracene
02/06/23 09:510.6600.139<0.139mg/KgBenzo(a)anthracene
02/06/23 09:510.6600.147<0.147mg/KgBenzo(a)pyrene
02/06/23 09:510.6600.146<0.146mg/KgBenzo(b)fluoranthene
02/06/23 09:510.6600.136<0.136mg/KgBenzo(g,h,i)perylene
02/06/23 09:510.6600.137<0.137mg/KgBenzo(k)fluoranthene
02/06/23 09:512.000.580<0.580mg/KgBenzoic Acid
02/06/23 09:510.6600.105<0.105mg/KgBenzyl alcohol
02/06/23 09:510.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane
02/06/23 09:510.6600.107<0.107mg/KgBis(2-Chloroethyl)ether
02/06/23 09:510.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether
02/06/23 09:510.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate
02/06/23 09:510.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether
02/06/23 09:510.3300.113<0.113mg/KgButyl benzyl phthalate
02/06/23 09:510.6600.092<0.092mg/Kg4-Chloro-3-methylphenol
02/06/23 09:510.3300.112<0.112mg/Kg4-Chloroaniline
02/06/23 09:510.6600.116<0.116mg/Kg2-Chloronaphthalene
02/06/23 09:510.6600.098<0.098mg/Kg2-Chlorophenol
02/06/23 09:511.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether
02/06/23 09:510.6600.142<0.142mg/KgChrysene
02/06/23 09:510.6600.230<0.230mg/KgDibenz(a,h)anthracene
02/06/23 09:510.6600.119<0.119mg/KgDibenzofuran
02/06/23 09:510.6600.094<0.094mg/Kg1,2-Dichlorobenzene
02/06/23 09:510.6600.097<0.097mg/Kg1,3-Dichlorobenzene
Page 27 of 41Date:02/09/2023 02:32 PM
Page 92 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
Associated Lab Samples: 98599
LRB-V29475 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/06/23 09:510.3300.097<0.097mg/Kg1,4-Dichlorobenzene
02/06/23 09:510.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine
02/06/23 09:510.6600.095<0.095mg/Kg2,4-Dichlorophenol
02/06/23 09:510.6600.180<0.180mg/KgDiethyl phthalate
02/06/23 09:510.6600.174<0.174mg/KgDimethyl phthalate
02/06/23 09:510.3300.108<0.108mg/Kg2,4-Dimethylphenol
02/06/23 09:510.6600.107<0.107mg/KgDi-n-butyl phthalate
02/06/23 09:511.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
02/06/23 09:511.500.520<0.520mg/Kg2,4-Dinitrophenol
02/06/23 09:510.6600.096<0.096mg/Kg2,4-Dinitrotoluene
02/06/23 09:510.6600.108<0.108mg/Kg2,6-Dinitrotoluene
02/06/23 09:510.3300.143<0.143mg/KgDi-n-Octyl Phthalate
02/06/23 09:510.6600.123<0.123mg/KgFluoranthene
02/06/23 09:510.6600.128<0.128mg/KgFluorene
02/06/23 09:510.6600.106<0.106mg/KgHexachlorobenzene
02/06/23 09:510.6600.097<0.097mg/KgHexachlorobutadiene
02/06/23 09:510.6600.157<0.157mg/KgHexachlorocyclopentadiene
02/06/23 09:510.6600.079<0.079mg/KgHexachloroethane
02/06/23 09:510.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
02/06/23 09:510.6600.191<0.191mg/KgIsophorone
02/06/23 09:510.6600.106<0.106mg/Kg1-Methylnaphthalene
02/06/23 09:510.6600.100<0.100mg/Kg2-Methylnaphthalene
02/06/23 09:510.6600.097<0.097mg/Kg2-Methylphenol
02/06/23 09:510.6600.084<0.084mg/Kg3&4 Methylphenol
02/06/23 09:510.6600.144<0.144mg/KgNaphthalene
02/06/23 09:510.6600.096<0.096mg/Kg2-Nitroaniline
02/06/23 09:510.6600.120<0.120mg/Kg3-Nitroaniline
Page 28 of 41Date:02/09/2023 02:32 PM
Page 93 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
Associated Lab Samples: 98599
LRB-V29475 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/06/23 09:510.3300.093<0.093mg/Kg4-Nitroaniline
02/06/23 09:510.3300.116<0.116mg/KgNitrobenzene
02/06/23 09:510.6600.088<0.088mg/Kg2-Nitrophenol
02/06/23 09:510.6600.117<0.117mg/Kg4-Nitrophenol
02/06/23 09:510.6600.263<0.263mg/KgN-Nitrosodimethylamine
02/06/23 09:510.6600.181<0.181mg/KgN-Nitrosodiphenylamine
02/06/23 09:510.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine
02/06/23 09:511.000.347<0.347mg/KgPentachlorophenol
02/06/23 09:510.6600.208<0.208mg/KgPhenanthrene
02/06/23 09:510.6600.112<0.112mg/KgPhenol
02/06/23 09:510.6600.134<0.134mg/KgPyrene
02/06/23 09:510.3300.079<0.079mg/KgPyridine
02/06/23 09:510.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene
02/06/23 09:510.6600.096<0.096mg/Kg2,4,5-Trichlorophenol
02/06/23 09:510.6600.096<0.096mg/Kg2,4,6-Trichlorophenol
02/06/23 09:512-Fluorobiphenyl (S)86.8 44-115
02/06/23 09:512-Fluorophenol (S)72.3 35-115
02/06/23 09:51Nitrobenzene-d5 (S)77.8 37-122
02/06/23 09:514-Terphenyl-d14 (S)98.8 54-127
02/06/23 09:512,4,6-Tribromophenol (S)77.4 39-132
02/06/23 09:51Phenol-d5 (S)69.9 34-121
LCS-V29475Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
85.61.431.67mg/KgAcenaphthene 40-123
86.81.451.67mg/KgAcenaphthylene 32-132
Page 29 of 41Date:02/09/2023 02:32 PM
Page 94 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
LCS-V29475Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1191.991.67mg/KgAniline 12-197
92.21.541.67mg/KgAnthracene 47-123
92.81.551.67mg/KgBenzo(a)anthracene 49-126
1021.711.67mg/KgBenzo(a)pyrene 45-129
97.01.621.67mg/KgBenzo(b)fluoranthene 45-132
93.41.561.67mg/KgBenzo(g,h,i)perylene 43-134
93.41.561.67mg/KgBenzo(k)fluoranthene 47-132
49.10.8201.67mg/KgBenzoic Acid 10-83
86.81.451.67mg/KgBenzyl alcohol 29-122
77.81.301.67mg/KgBis(2-Chloroethoxy)methane 36-121
76.61.281.67mg/KgBis(2-Chloroethyl)ether 31-120
80.21.341.67mg/KgBis(2-Chloroisopropyl)ether 33-131
1001.671.67mg/KgBis(2-ethylhexyl)phthalate 51-133
92.81.551.67mg/Kg4-Bromophenyl phenyl ether 46-124
97.61.631.67mg/KgButyl benzyl phthalate 48-132
80.21.341.67mg/Kg4-Chloro-3-methylphenol 45-122
66.41.111.67mg/Kg4-Chloroaniline 17-106
86.21.441.67mg/Kg2-Chloronaphthalene 41-114
83.21.391.67mg/Kg2-Chlorophenol 34-121
92.21.541.67mg/Kg4-Chlorophenyl phenyl ether 45-121
91.61.531.67mg/KgChrysene 50-124
95.81.601.67mg/KgDibenz(a,h)anthracene 45-134
86.81.451.67mg/KgDibenzofuran 44-120
77.21.291.67mg/Kg1,2-Dichlorobenzene 33-117
76.01.271.67mg/Kg1,3-Dichlorobenzene 30-115
77.21.291.67mg/Kg1,4-Dichlorobenzene 31-115
73.61.231.67mg/Kg3,3'-Dichlorobenzidine 22-121
Page 30 of 41Date:02/09/2023 02:32 PM
Page 95 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
LCS-V29475Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
82.01.371.67mg/Kg2,4-Dichlorophenol 40-122
92.81.551.67mg/KgDiethyl phthalate 50-124
92.81.551.67mg/KgDimethyl phthalate 48-124
1011.691.67mg/Kg2,4-Dimethylphenol 30-127
1011.691.67mg/KgDi-n-butyl phthalate 51-128
91.61.531.67mg/Kg4,6-Dinitro-2-methylphenol 29-132
95.21.591.67mg/Kg2,4-Dinitrophenol 27-129
92.81.551.67mg/Kg2,4-Dinitrotoluene 48-126
91.01.521.67mg/Kg2,6-Dinitrotoluene 46-124
1021.711.67mg/KgDi-n-Octyl Phthalate 45-140
88.01.471.67mg/KgFluoranthene 50-127
89.21.491.67mg/KgFluorene 43-125
92.81.551.67mg/KgHexachlorobenzene 45-122
76.01.271.67mg/KgHexachlorobutadiene 32-123
67.01.121.67mg/KgHexachlorocyclopentadiene 32-117
73.01.221.67mg/KgHexachloroethane 28-117
97.01.621.67mg/KgIndeno(1,2,3-cd)pyrene 45-133
47.60.7961.67mg/KgIsophorone 30-122
72.41.211.67mg/Kg1-Methylnaphthalene 40-119
73.01.221.67mg/Kg2-Methylnaphthalene 38-122
86.21.441.67mg/Kg2-Methylphenol 32-122
76.01.271.67mg/Kg3&4 Methylphenol 34-119
71.21.191.67mg/KgNaphthalene 35-123
94.01.571.67mg/Kg2-Nitroaniline 44-127
80.81.351.67mg/Kg3-Nitroaniline 33-119
93.41.561.67mg/Kg4-Nitroaniline 63-147
68.81.151.67mg/KgNitrobenzene 34-122
Page 31 of 41Date:02/09/2023 02:32 PM
Page 96 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
LCS-V29475Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
74.21.241.67mg/Kg2-Nitrophenol 36-123
1081.801.67mg/Kg4-Nitrophenol 30-132
60.41.011.67mg/KgN-Nitrosodimethylamine 10-146
1091.821.67mg/KgN-Nitrosodiphenylamine 38-127
82.01.371.67mg/KgN-Nitroso-di-n-propylamine 36-120
1081.801.67mg/KgPentachlorophenol 25-133
91.01.521.67mg/KgPhenanthrene 50-121
81.41.361.67mg/KgPhenol 34-121
92.21.541.67mg/KgPyrene 47-127
46.00.7691.67mg/KgPyridine 10-80
72.41.211.67mg/Kg1,2,4-Trichlorobenzene 34-118
92.21.541.67mg/Kg2,4,5-Trichlorophenol 41-124
86.81.451.67mg/Kg2,4,6-Trichlorophenol 39-126
89.22-Fluorobiphenyl (S)44-115
75.92-Fluorophenol (S)35-115
71.8Nitrobenzene-d5 (S)37-122
97.04-Terphenyl-d14 (S)54-127
83.42,4,6-Tribromophenol (S)39-132
71.7Phenol-d5 (S)34-121
V 98599-MS-V29475 V 98599-MSD-V29475Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.53 91.61.621.671.67<0.116mg/KgAcenaphthene 97.0 40-123 5.7 20
1.64 98.21.711.671.67<0.105mg/KgAcenaphthylene 102 32-132 4.1 20
1.48 88.61.411.671.67<0.152mg/KgAniline 84.4 12-197 4.8 20
Page 32 of 41Date:02/09/2023 02:32 PM
Page 97 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
V 98599-MS-V29475 V 98599-MSD-V29475Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.75 93.51.891.671.670.188mg/KgAnthracene 102 47-123 7.6 20
2.40 -1.7*3.501.671.672.43mg/KgBenzo(a)anthracene 64.0 49-126 37.2*20
2.86 -43*4.401.671.673.61mg/KgBenzo(a)pyrene 47.3 45-129 42.4*20
3.43 -110*5.581.671.675.53mg/KgBenzo(b)fluoranthene 2.9*45-132 47.7*20
2.61 -33*4.031.671.673.19mg/KgBenzo(g,h,i)perylene 50.2 43-134 42.7*20
2.07 9.5*3.031.671.671.91mg/KgBenzo(k)fluoranthene 67.0 47-132 37.6*20
1.39 83.2*1.521.671.67<0.580mg/KgBenzoic Acid 91.0*10-83 8.9 20
1.52 91.01.601.671.67<0.105mg/KgBenzyl alcohol 95.8 29-122 5.1 20
1.35 80.81.391.671.67<0.118mg/KgBis(2-Chloroethoxy)methane 83.2 36-121 2.9 20
1.25 74.81.361.671.67<0.107mg/KgBis(2-Chloroethyl)ether 81.4 31-120 8.4 20
1.36 81.41.441.671.67<0.136mg/KgBis(2-Chloroisopropyl)ether 86.2 33-131 5.7 20
1.92 1151.991.671.67<0.120mg/KgBis(2-ethylhexyl)phthalate 119 51-133 3.5 20
1.68 1011.791.671.67<0.109mg/Kg4-Bromophenyl phenyl ether 107 46-124 6.3 20
1.80 1081.831.671.67<0.113mg/KgButyl benzyl phthalate 110 48-132 1.6 20
1.36 81.41.471.671.67<0.092mg/Kg4-Chloro-3-methylphenol 88.0 45-122 7.7 20
0.965 57.70.9541.671.67<0.112mg/Kg4-Chloroaniline 57.1 17-106 1.1 20
1.56 93.41.621.671.67<0.116mg/Kg2-Chloronaphthalene 97.0 41-114 3.7 20
1.47 88.01.531.671.67<0.098mg/Kg2-Chlorophenol 91.6 34-121 4.0 20
1.62 97.01.701.671.67<0.126mg/Kg4-Chlorophenyl phenyl ether 102 45-121 4.8 20
2.68 -46*4.001.671.673.45mg/KgChrysene 32.9*50-124 39.5*20
1.80 66.02.251.671.670.697mg/KgDibenz(a,h)anthracene 92.9 45-134 22.2*20
1.54 92.21.611.671.67<0.119mg/KgDibenzofuran 96.4 44-120 4.4 20
1.32 79.01.381.671.67<0.094mg/Kg1,2-Dichlorobenzene 82.6 33-117 4.4 20
1.28 76.61.331.671.67<0.097mg/Kg1,3-Dichlorobenzene 79.6 30-115 3.8 20
1.29 77.21.361.671.67<0.097mg/Kg1,4-Dichlorobenzene 81.4 31-115 5.2 20
0.787 47.10.6491.671.67<0.147mg/Kg3,3'-Dichlorobenzidine 38.8 22-121 19.2 20
Page 33 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 98 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
V 98599-MS-V29475 V 98599-MSD-V29475Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.42 85.01.491.671.67<0.095mg/Kg2,4-Dichlorophenol 89.2 40-122 4.8 20
1.64 98.21.681.671.67<0.180mg/KgDiethyl phthalate 101 50-124 2.4 20
1.62 97.01.721.671.67<0.174mg/KgDimethyl phthalate 103 48-124 5.9 30
1.82 1091.931.671.67<0.108mg/Kg2,4-Dimethylphenol 116 30-127 5.8 20
1.77 1061.871.671.67<0.107mg/KgDi-n-butyl phthalate 112 51-128 5.4 20
1.18 70.61.211.671.67<0.240mg/Kg4,6-Dinitro-2-methylphenol 72.4 29-132 2.5 20
1.16 69.41.161.671.67<0.520mg/Kg2,4-Dinitrophenol 69.4 27-129 0.0 20
1.58 94.61.621.671.67<0.096mg/Kg2,4-Dinitrotoluene 97.0 48-126 2.5 20
1.56 93.41.691.671.67<0.108mg/Kg2,6-Dinitrotoluene 101 46-124 8.0 20
1.81 1081.881.671.67<0.143mg/KgDi-n-Octyl Phthalate 113 45-140 3.7 20
3.05 -110*5.081.671.675.19mg/KgFluoranthene -6.5*50-127 49.9*20
1.60 95.81.701.671.67<0.128mg/KgFluorene 102 43-125 6.0 20
1.67 1001.721.671.67<0.106mg/KgHexachlorobenzene 103 45-122 2.9 20
1.32 79.01.391.671.67<0.097mg/KgHexachlorobutadiene 83.2 32-123 5.1 20
0.695 41.60.6011.671.67<0.157mg/KgHexachlorocyclopentadiene 35.9 32-117 14.5 20
1.25 74.81.271.671.67<0.079mg/KgHexachloroethane 76.0 28-117 1.5 20
2.74 -44*4.261.671.673.50mg/KgIndeno(1,2,3-cd)pyrene 45.5 45-133 43.4*20
0.797 47.70.8301.671.67<0.191mg/KgIsophorone 49.7 30-122 4.0 20
1.26 75.41.341.671.67<0.106mg/Kg1-Methylnaphthalene 80.2 40-119 6.1 20
1.24 74.21.301.671.67<0.100mg/Kg2-Methylnaphthalene 77.8 38-122 4.7 20
1.53 91.61.591.671.67<0.097mg/Kg2-Methylphenol 95.2 32-122 3.8 20
1.32 79.01.391.671.67<0.084mg/Kg3&4 Methylphenol 83.2 34-119 5.1 20
1.24 74.21.291.671.67<0.144mg/KgNaphthalene 77.2 35-123 3.9 20
1.65 98.81.711.671.67<0.096mg/Kg2-Nitroaniline 102 44-127 3.5 20
1.36 81.41.421.671.67<0.120mg/Kg3-Nitroaniline 85.0 33-119 4.3 20
1.59 95.21.631.671.67<0.093mg/Kg4-Nitroaniline 97.6 63-147 2.4 20
Page 34 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 99 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V29532QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V29475
V 98599-MS-V29475 V 98599-MSD-V29475Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.21 72.41.251.671.67<0.116mg/KgNitrobenzene 74.8 34-122 3.2 20
1.30 77.81.341.671.67<0.088mg/Kg2-Nitrophenol 80.2 32-123 3.0 20
1.82 1091.861.671.67<0.117mg/Kg4-Nitrophenol 111 30-132 2.1 20
1.05 62.81.061.671.67<0.263mg/KgN-Nitrosodimethylamine 63.4 10-146 0.9 30
1.98 1192.071.671.67<0.181mg/KgN-Nitrosodiphenylamine 124 38-127 4.4 20
1.40 83.81.441.671.67<0.118mg/KgN-Nitroso-di-n-propylamine 86.2 36-120 2.8 20
2.01 1202.111.671.67<0.347mg/KgPentachlorophenol 126 25-133 4.8 20
2.04 6.5*2.831.671.671.93mg/KgPhenanthrene 53.8 50-121 32.4*20
1.39 83.21.451.671.67<0.112mg/KgPhenol 86.8 34-121 4.2 20
3.07 -100*4.911.671.674.75mg/KgPyrene 9.5*47-127 46.1*20
0.879 52.60.9011.671.67<0.079mg/KgPyridine 53.9 10-80 2.4 20
1.28 76.61.321.671.67<0.107mg/Kg1,2,4-Trichlorobenzene 79.0 34-118 3.0 20
1.68 1011.781.671.67<0.096mg/Kg2,4,5-Trichlorophenol 107 41-124 5.7 20
1.60 95.81.661.671.67<0.096mg/Kg2,4,6-Trichlorophenol 99.4 39-126 3.6 20
94.62-Fluorobiphenyl (S)96.4 44-115
78.62-Fluorophenol (S)80.1 35-115
73.0Nitrobenzene-d5 (S)73.6 37-122
1064-Terphenyl-d14 (S)109 54-127
87.92,4,6-Tribromophenol (S)90.9 39-132
73.5Phenol-d5 (S)75.0 34-121
Page 35 of 41* QC Fail Date:02/09/2023 02:32 PM
Page 100 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V29367QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V29336
Associated Lab Samples: 98594, 98595, 98596, 98597
LRB-V29336 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
02/01/23 12:010.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V29336 LCSD-V29336Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.300 1201200.3000.250µg/L1,2-Dibromoethane 70-130 0.0 20.0
V 98373-DUP-V29336Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 02/01/23 14:190.0<0.0207< 0.0207µg/L1,2-Dibromoethane
V 98372-MS-V29336Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.267 1040.256< 0.00338µg/L1,2-Dibromoethane 70-130
Page 36 of 41Date:02/09/2023 02:32 PM
Page 101 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V29483QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V29399
Associated Lab Samples: 98594
LRB-V29399 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/03/23 14:5935028.2<28.2µg/LAliphatic C9-C18
02/03/23 14:59500124<124µg/LAliphatic C19-C36
02/03/23 14:5925061.2<61.2µg/LAromatic C11-C22
02/03/23 14:592-Fluorobiphenyl (S)102 40-140
02/03/23 14:592-Bromonaphthalene (S)102 40-140
02/03/23 14:59Chlorooctadecane (S)85.5 40-140
02/03/23 14:59OTP Surrogate (S)81.5 40-140
LCS-V29399 LCSD-V29399Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
367 61.167.0402600µg/LAliphatic C9-C18 40-140 9.1 50.0
653 81.689.7718800µg/LAliphatic C19-C36 40-140 9.4 50.0
1490 87.696.416401700µg/LAromatic C11-C22 40-140 9.5 50.0
1021042-Fluorobiphenyl (S)40-140
1001032-Bromonaphthalene (S)40-140
87.093.5Chlorooctadecane (S)40-140
74.082.5OTP Surrogate (S)40-140
Page 37 of 41Date:02/09/2023 02:32 PM
Page 102 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V29557QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V29431
Associated Lab Samples: 98599
LRB-V29431 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/07/23 10:4550.09.20<9.20mg/KgAliphatic C9-C18
02/07/23 10:4550.012.2<12.2mg/KgAliphatic C19-C36
02/07/23 10:4550.014.2<14.2mg/KgAromatic C11-C22
02/07/23 10:452-Fluorobiphenyl (S)94.7 40-140
02/07/23 10:452-Bromonaphthalene (S)92.7 40-140
02/07/23 10:45Chlorooctadecane (S)90.5 40-140
02/07/23 10:45OTP Surrogate (S)81.0 40-140
LCS-V29431 LCSD-V29431Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
49.2 82.076.545.960.0mg/KgAliphatic C9-C18 40-140 6.9 50
82.7 10396.377.180.0mg/KgAliphatic C19-C36 40-140 7.0 50
192 11398.8168170mg/KgAromatic C11-C22 40-140 13.3 50
1081062-Fluorobiphenyl (S)40-140
1081062-Bromonaphthalene (S)40-140
113102Chlorooctadecane (S)40-140
91.086.5OTP Surrogate (S)40-140
Page 38 of 41Date:02/09/2023 02:32 PM
Page 103 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V29305QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V29304
Associated Lab Samples: 98599
LRB-V29304 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/31/23 10:128.001.22<1.22mg/KgAliphatic C5-C8
01/31/23 10:128.004.56<4.56mg/KgAliphatic C9-C12
01/31/23 10:128.000.624<0.624mg/KgAromatic C9-C10
01/31/23 10:122,5-Dibromotoluene (FID) (S)89.0 70-130
01/31/23 10:122,5-Dibromotoluene (PID) (S)86.8 70-130
LCS-V29304 LCSD-V29304Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
33.6 10510232.732.0mg/KgAliphatic C5-C8 70-130 2.7 50
38.3 12011837.632.0mg/KgAliphatic C9-C12 70-130 1.8 50
11.1 10410210.910.7mg/KgAromatic C9-C10 70-130 1.8 50
84.679.92,5-Dibromotoluene (FID) (S)70-130
82.977.02,5-Dibromotoluene (PID) (S)70-130
Page 39 of 41Date:02/09/2023 02:32 PM
Page 104 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V29322QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V29321
Associated Lab Samples: 98594, 98595, 98596, 98597
LRB-V29321 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
01/31/23 12:5950.011.5<11.5µg/LAliphatic C5-C8
01/31/23 12:5950.025.8<25.8µg/LAliphatic C9-C12
01/31/23 12:5950.04.02<4.02µg/LAromatic C9-C10
01/31/23 12:592,5-Dibromotoluene (FID) (S)97.3 70-130
01/31/23 12:592,5-Dibromotoluene (PID) (S)91.9 70-130
LCS-V29321 LCSD-V29321Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
324 108103309300µg/LAliphatic C5-C8 70-130 4.7 50.0
363 121123369300µg/LAliphatic C9-C12 70-130 1.6 50.0
108 108106106100µg/LAromatic C9-C10 70-130 1.8 50.0
87.278.92,5-Dibromotoluene (FID) (S)70-130
78.077.32,5-Dibromotoluene (PID) (S)70-130
Page 40 of 41Date:02/09/2023 02:32 PM
Page 105 of 109
Quality Control Data
23-030-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Merry Grocery
Dry Weight Determination
SW-DRYWT
V29377QC Analytical Batch:
Analysis Method:
Analysis Description:
V 98688-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 02/01/23 16:543.633.332.1%Moisture
V 98689-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 02/01/23 16:543.318.017.4%Moisture
Page 41 of 41Date:02/09/2023 02:32 PM
Page 106 of 109
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-030-0002
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 0.9C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:01/30/2023 11:52:06
Special precautions or instructions included?
Comments:
Page 107 of 109
Page 108 of 109
Page 109 of 109

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
UVF Trilogy Analytical Report

Samples Collected: January 26, 2023
Samples Analyzed: January 27, 2023
Site Name: Mercy Grocery
Site Address: 1487 US Highway 15-501, Carthage, NC 28327
GRI Project Number: 5947

January 27, 2023

Xavier T. Farmer, GIT
Operator

Technical Procedures
Calibration
The UFV Trilogy has standard calibrations stored for the following analysis:
 GRO
 DRO
 Total PAH
 Target PAH
 Heavy PAH
Prior to use, calibration standards are used to perform a 5-point verification on the factory stored
calibrations for GRO and DRO. The calibration standards used are as follows:
GRO
 0.5 ppm
 1 ppm
 3 ppm
 5 ppm
 10 ppm
DRO
 0.1 ppm
 0.5 ppm
 1 ppm
 3 ppm
 5 ppm
Operation
Sample Extraction
 5mg of soil are weighed into a clean extraction jar
 Methanol is added to the extraction jar to create a 2x or 4x dilution
o 2x Dilution: 10 mL of methanol
o 4x Dilution: 20 mL of methanol
 The extraction jar is shaken for several minutes to thoroughly mix the soil with solvent
(methanol)
 The mixture is allowed to settle for several minutes
 A clean syringe is used to draw liquid from the extraction jar
 A clean filter is attached to the end of the syringe and the liquid dispensed through the filter
into a clean test tube
 This liquid is referred to as the extraction
Dilution Preparation
 An adjustable micropipette is used to precisely measure out the amount of extract needed for
the dilution
 The measured out amount of the extract is added to a clean test tube and methanol is added
dilute the extract. Examples of dilutions are shown below:

Extract Amount
500 μL
200 μL
100 μL
50 μL
25 μL

Add Solvent to the
5 mL line
5 mL line
5 mL line
5 mL line
5 mL line
2x Extract
Dilution Factor
20x
50x
100x
200x
400x
4x Extract
Dilution Factor
40x
100x
200x
400x
800x

Technical Procedures
Sample Analyzation
 The dilution is shaken to thoroughly mix, then poured into a clean glass cuvette
 The desired module is inserted into the UVF Trilogy and the corresponding factory calibration is
selected
 “Measure Fluorescence” is pressed on the touchscreen and the reading is recorded
 The reading should be between the concentrations of the calibration standards (GRO: 0.5-10
ppm; DRO 0.1-5 ppm)
o Reading below the calibration standard range are recorded as below the detection limit
 Detection Limit = (lower range of calibration standards range) x dilution factor
(i.e. a GRO sample with a 100x dilution factor has a detection limit of 50 ppm)
o Readings above the calibration standard range should be further diluted and reanalyzed
o Negative readings are an indication of quenching (see below)
 The reading is multiplied by the dilution factor to calculate the final concentration
 Check suspected contaminated samples for quenching by running additional dilutions
o According to the siteLAB Quick Reference Guide:
“Quenching” can occur when the detector is swamped by too many hydrocarbons or
organic interferences, producing low or negative concentrations. Test the sample at
multiple dilutions to confirm results are linear and accurate.”
QA/QC
Method Blank
 A method blank of methanol will be analyzed following calibration and following the last sample
analyzed each day
Duplicates
 One duplicate will be analyzed for every 20 samples
 The duplicate will be prepared from the extract of the sample and diluted to the same factor as
the sample analyzed
Project Name:Date Collected:
Project Number:Date Analysed:
Project Manager:Operator:
Sample ID Matrix Dilution
Factor x
GRO
Output
(ppm)
=GRO Value
(mg/Kg)
Dilution
Factor x
DRO
Output
(ppm)
=DRO Value
(mg/Kg)
GMW-2-4'Soil 20 <0.5 <10 20 1.46 29.2
GMW-3-4'Soil 20 <0.5 <10 20 0.16 3.2
GMW-4-4'Soil 20 <0.5 <10 20 <0.1 <2
GMW-5-4'Soil 20 1.09 21.8 20 0.92 18.4
UVF Analytical Report
siteLAB UVF Trilogy
1/27/2023
1/26/2023
Xavier T. Farmer
Mercy Grocery
5947
Scott Driscoll
Report Date:
1/27/2023
Page:
1 of 1
Page:
1 of 1
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