FA-28436_47690_CA_MRP_20230221

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
February 21, 2023

Mr. Mike Haseltine
North Carolina Department of Environmental Quality
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, North Carolina 28301

Re: Ground Water Monitoring Report
Food Plus 1
319 North Main Street
Bladenboro, Bladen County
Incident # 47690
Site Ranking: Intermediate 125 D
GRI # 5636

Dear Mr. Haseltine:

Geological Resources, Inc. (GRI) presents the results of the ground water sampling event at the Food Plus
1 site in Bladenboro, North Carolina. The activities were conducted in response to NCDEQ correspondence
dated June 15, 2022.

On February 8, 2023, monitoring well MW-1 was gauged, purged, and sampled per NCDEQ guidelines.
The depth to ground water was 1.94 feet below the top of well casing. Ground water samples were
submitted for analyses of VOCs and oxygenates by EPA Method 6200B. A Site Location Map and Site Map
have been included as Figures 1 and 2, respectively.

Please see the attached summary table for the results of the February 2023 ground water sampling.
Concentrations of benzene, MTBE, naphthalene, tert-Amyl alcohol, and di-isopropyl ether that exceeded
the Maximum Allowable Concentrations (MACs) as specified in T15A NCAC 2L.0202 were reported in the
ground water samples collected from MW-1. No reported contaminant concentrations exceeded the
Gross Contaminant Levels (GCLs). A copy of the laboratory report is attached.

In April 2022, an updated receptor survey was conducted. No water supply wells were identified within
1,500 feet of the site. Public water is available to the subject site and to all surrounding properties. No
surface water bodies were identified within 500 feet of the site.

According to the April 2022 receptor survey and the February 2023 laboratory results, the site risk should
be reduced. Subsequent to completing a Notice of Residual Petroleum and public notification, the
incident should be closed.

Food Plus 1
Ground Water Sampling
Page 2 of 2

3502 Hayes Road • Monroe, North Carolina 28110
Phone [phone] • [phone] • Fax [phone]

Please contact me at 704-698-1254 or [e-mail] with any questions or comments.

Sincerely,

Rae Troiano Brown, P.G.
Project Manager

cc: client; file

enclosures
SITE LOCATIONFigure 1 Site Location Food Plus 1319 North Main StreetBladenboro, North CarolinaBladen CountyIncident No. 47690GRI Project No. 5636500 M2000 FTDate: 06/09/2022Location: 34.541282° N -78.786262° W Dad
Date: 02/20/23
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 128 10 47 70 70 70 400
5,000 260,000 84,500 85,500 20,000 6,000 40,000 12,800 10,000 47,000 25,000 70,000 30,000 28,500
MW-1 04/06/22 5,250 E 79.4 1,470 2,453.9 407 811 1,490 36.3 J 2,010 345 62.8 291 148 1,700
MW-1 02/08/23 1,770 3.21 J 325 36.7 184 126 538 9.49 J 989 NR 18.3 146 35.1 335
Notes:
• Results reported in micrograms per liter (µg/l).
• < : Less than the method detection limit specified in the laboratory report.
• 2L Standard specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Not Established.
• Concentrations in bold face type exceeded the 2L standards.
• Concentrations in italics exceeded the gross contamination levels.
• E: Exceeds calibration range.
• J: Estimated value.
• Refer to laboratory report for detected constituents that did not exceed the MACs, or for which no standard has been established.
• NR: Not Requested.
TABLE 1
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
FOOD PLUS 1 (INCIDENT NO. 47690)
Facility ID No. 00-0-0000012918
Analytical Method 1,2,4-Trimethylbenzenen-PropylbenzeneEthyl tert-butyl ether (ETBE)GCL (µg/l)
2L Standard (µg/l)tert-Amyl alcohol(TAA)Contaminant of Concern Methyl-tert-butyl ether(MTBE)NaphthaleneBenzeneTolueneEthylbenzeneTotal XylenesEPA Method 6200B tert-Butyl alcohol(TBA)tert-Amyl methyl ether (TAME)Di-isopropyl etherIsopropylbenzenePage 1 of 1

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

2/14/2023
Geological Resources, Inc. Rae Brown
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 23-040-0005 Client Project Description: Food Plus 1
GRI #5636
Dear Rae Brown:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/9/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 17
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-040-0005
Page 2 of 17
Report Number:
Sample Summary Table
Client Project Description:
23-040-0005
Food Plus 1
GRI #5636
Lab No Client Sample ID Matrix Date Collected Date Received
02/08/2023 14:47Aqueous 99276 MW-1 02/09/2023 10:10
Page 3 of 17
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-040-0005
Report Limit
Project:Food Plus 1
V 99276MW-1
1770 02/09/2023 17:106200BBenzeneµg/L 18.0
J2.34 02/09/2023 16:436200Bn-Butylbenzene µg/L 1.80
146 02/09/2023 16:436200BDi-Isopropyl Ether (DIPE)µg/L 5.00
325 02/09/2023 16:436200BEthylbenzeneµg/L 1.70
18.3 02/09/2023 16:436200BIsopropylbenzeneµg/L 1.80
184 02/09/2023 16:436200BMethyl tert-butyl ether (MTBE)µg/L 1.40
126 02/09/2023 16:436200BNaphthaleneµg/L 4.70
35.1 02/09/2023 16:436200Bn-Propylbenzene µg/L 1.90
989 02/09/2023 16:436200Btert-Butyl Alcohol (TBA)µg/L 16.0
538 02/09/2023 16:436200Btert-Amyl Alcohol (TAA)µg/L 19.0
J9.49 02/09/2023 16:436200Btert-Amyl Methyl Ether (TAME)µg/L 2.80
J3.21 02/09/2023 16:436200BTolueneµg/L 2.20
335 02/09/2023 16:436200B1,2,4-Trimethylbenzene µg/L 1.90
85.6 02/09/2023 16:436200B1,3,5-Trimethylbenzene µg/L 1.80
14.1 02/09/2023 16:436200Bo-Xylene µg/L 2.10
22.6 02/09/2023 16:436200Bm,p-Xylene µg/L 4.20
36.7 02/09/2023 16:436200BXylene (Total)µg/L 2.10
Page 4 of 17
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-040-0005
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5636 Received : 02/09/2023
Food Plus 1
Report Date : 02/14/2023
Sample ID :
Lab No :
Sampled:MW-1
99276 Matrix:
2/8/2023 14:47
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 02/09/23 16:43 6200BMSA
Surrogate: 4-Bromofluorobenzene 98.8 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: Toluene-d8 98.6 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%02/09/23 17:10100 MSA V29658
Surrogate: Dibromofluoromethane 100 Limits: 70-130%02/09/23 17:10100 MSA V29658
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%02/09/23 17:10100 MSA V29658
Surrogate: Toluene-d8 100 Limits: 70-130%02/09/23 17:10100 MSA V29658
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 5 of 17
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-040-0005
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5636 Received : 02/09/2023
Food Plus 1
Report Date : 02/14/2023
Sample ID :
Lab No :
Sampled:MW-1
99276 Matrix:
2/8/2023 14:47
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29657 02/09/23 09:00
<18.0 µg/L 18.0 100Acetone 10 02/09/23 16:43 V29658MSA
1770 µg/L 18.0 50.0Benzene 100 02/09/23 17:10 V29658MSA
<2.10 µg/L 2.10 5.00Bromobenzene 10 02/09/23 16:43 V29658MSA
<4.20 µg/L 4.20 10.0Bromochloromethane 10 02/09/23 16:43 V29658MSA
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 02/09/23 16:43 V29658MSA
<15.0 µg/L 15.0 50.0Bromoform 10 02/09/23 16:43 V29658MSA
<2.80 µg/L 2.80 10.0Bromomethane 10 02/09/23 16:43 V29658MSA
2.34 J µg/L 1.80 5.00n-Butylbenzene 10 02/09/23 16:43 V29658MSA
<2.00 µg/L 2.00 5.00
sec-Butyl benzene 10 02/09/23 16:43 V29658MSA
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 02/09/23 16:43 V29658MSA
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 02/09/23 16:43 V29658MSA
<1.90 µg/L 1.90 5.00Chlorobenzene 10 02/09/23 16:43 V29658MSA
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 02/09/23 16:43 V29658MSA
<4.30 µg/L 4.30 10.0Chloroethane 10 02/09/23 16:43 V29658MSA
<2.20 µg/L 2.20 5.00Chloroform 10 02/09/23 16:43 V29658MSA
<2.20 µg/L 2.20 5.00
Chloromethane 10 02/09/23 16:43 V29658MSA
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 02/09/23 16:43 V29658MSA
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 02/09/23 16:43 V29658MSA
146 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 02/09/23 16:43 V29658MSA
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 02/09/23 16:43 V29658MSA
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 02/09/23 16:43 V29658MSA
<2.30 µg/L 2.30 5.00Dibromomethane 10 02/09/23 16:43 V29658MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 6 of 17
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-040-0005
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5636 Received : 02/09/2023
Food Plus 1
Report Date : 02/14/2023
Sample ID :
Lab No :
Sampled:MW-1
99276 Matrix:
2/8/2023 14:47
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29657 02/09/23 09:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 02/09/23 16:43 V29658MSA
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 02/09/23 16:43 V29658MSA
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 02/09/23 16:43 V29658MSA
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 02/09/23 16:43 V29658MSA
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 02/09/23 16:43 V29658MSA
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 02/09/23 16:43 V29658MSA
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 02/09/23 16:43 V29658MSA
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 02/09/23 16:43 V29658MSA
<1.80 µg/L 1.80 5.00
trans-1,2-Dichloroethene 10 02/09/23 16:43 V29658MSA
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 02/09/23 16:43 V29658MSA
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 02/09/23 16:43 V29658MSA
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 02/09/23 16:43 V29658MSA
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 02/09/23 16:43 V29658MSA
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 02/09/23 16:43 V29658MSA
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 02/09/23 16:43 V29658MSA
<420 µg/L 420 2000
Ethanol 10 02/09/23 16:43 V29658MSA
325 µg/L 1.70 5.00Ethylbenzene 10 02/09/23 16:43 V29658MSA
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 02/09/23 16:43 V29658MSA
<3.80 µg/L 3.80 10.02-Hexanone 10 02/09/23 16:43 V29658MSA
18.3 µg/L 1.80 5.00Isopropylbenzene 10 02/09/23 16:43 V29658MSA
<0.890 µg/L 0.890 5.004-Isopropyl toluene 10 02/09/23 16:43 V29658MSA
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 02/09/23 16:43 V29658MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 17
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-040-0005
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5636 Received : 02/09/2023
Food Plus 1
Report Date : 02/14/2023
Sample ID :
Lab No :
Sampled:MW-1
99276 Matrix:
2/8/2023 14:47
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29657 02/09/23 09:00
184 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 02/09/23 16:43 V29658MSA
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 02/09/23 16:43 V29658MSA
<3.30 µg/L 3.30 20.0Methylene Chloride 10 02/09/23 16:43 V29658MSA
126 µg/L 4.70 10.0Naphthalene 10 02/09/23 16:43 V29658MSA
35.1 µg/L 1.90 5.00n-Propylbenzene 10 02/09/23 16:43 V29658MSA
<2.20 µg/L 2.20 5.00Styrene 10 02/09/23 16:43 V29658MSA
989 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 02/09/23 16:43 V29658MSA
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 02/09/23 16:43 V29658MSA
538 µg/L 19.0 100
tert-Amyl Alcohol (TAA)10 02/09/23 16:43 V29658MSA
9.49 J µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 02/09/23 16:43 V29658MSA
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 02/09/23 16:43 V29658MSA
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 02/09/23 16:43 V29658MSA
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 02/09/23 16:43 V29658MSA
3.21 J µg/L 2.20 5.00Toluene 10 02/09/23 16:43 V29658MSA
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 02/09/23 16:43 V29658MSA
<3.10 µg/L 3.10 5.00
1,2,4-Trichlorobenzene 10 02/09/23 16:43 V29658MSA
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 02/09/23 16:43 V29658MSA
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 02/09/23 16:43 V29658MSA
<1.80 µg/L 1.80 5.00Trichloroethene 10 02/09/23 16:43 V29658MSA
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 02/09/23 16:43 V29658MSA
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 02/09/23 16:43 V29658MSA
335 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 02/09/23 16:43 V29658MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 17
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
23-040-0005
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5636 Received : 02/09/2023
Food Plus 1
Report Date : 02/14/2023
Sample ID :
Lab No :
Sampled:MW-1
99276 Matrix:
2/8/2023 14:47
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V29657 02/09/23 09:00
85.6 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 02/09/23 16:43 V29658MSA
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 02/09/23 16:43 V29658MSA
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 02/09/23 16:43 V29658MSA
14.1 µg/L 2.10 5.00o-Xylene 10 02/09/23 16:43 V29658MSA
22.6 µg/L 4.20 10.0m,p-Xylene 10 02/09/23 16:43 V29658MSA
36.7 µg/L 2.10 5.00Xylene (Total)10 02/09/23 16:43 V29658
Surrogate: 4-Bromofluorobenzene 98.8 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: Toluene-d8 98.6 Limits: 70-130%02/09/23 16:4310 MSA V29658
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%02/09/23 17:10100 MSA V29658
Surrogate: Dibromofluoromethane 100 Limits: 70-130%02/09/23 17:10100 MSA V29658
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%02/09/23 17:10100 MSA V29658
Surrogate: Toluene-d8 100 Limits: 70-130%02/09/23 17:10100 MSA V29658
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 17
Quality Control Data
23-040-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Food Plus 1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29658QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29657
Associated Lab Samples: 99276
LRB-V29657 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/09/23 14:2710.01.80<1.80µg/LAcetone
02/09/23 14:270.5000.180<0.180µg/LBenzene
02/09/23 14:270.5000.210<0.210µg/LBromobenzene
02/09/23 14:271.000.420<0.420µg/LBromochloromethane
02/09/23 14:270.5000.160<0.160µg/LBromodichloromethane
02/09/23 14:275.001.50<1.50µg/LBromoform
02/09/23 14:271.000.280<0.280µg/LBromomethane
02/09/23 14:270.5000.180<0.180µg/Ln-Butylbenzene
02/09/23 14:270.5000.200<0.200µg/Lsec-Butyl benzene
02/09/23 14:272.000.920<0.920µg/Ltert-Butyl benzene
02/09/23 14:270.5000.180<0.180µg/LCarbon Tetrachloride
02/09/23 14:270.5000.190<0.190µg/LChlorobenzene
02/09/23 14:270.5000.190<0.190µg/LChlorodibromomethane
02/09/23 14:271.000.430<0.430µg/LChloroethane
02/09/23 14:270.5000.220<0.220µg/LChloroform
02/09/23 14:270.5000.220<0.220µg/LChloromethane
02/09/23 14:270.5000.200<0.200µg/L2-Chlorotoluene
02/09/23 14:270.5000.200<0.200µg/L4-Chlorotoluene
02/09/23 14:270.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
02/09/23 14:272.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
02/09/23 14:270.5000.200<0.200µg/L1,2-Dibromoethane
02/09/23 14:270.5000.230<0.230µg/LDibromomethane
02/09/23 14:270.5000.220<0.220µg/L1,2-Dichlorobenzene
02/09/23 14:270.5000.190<0.190µg/L1,3-Dichlorobenzene
02/09/23 14:270.5000.210<0.210µg/L1,4-Dichlorobenzene
02/09/23 14:275.001.20<1.20µg/LDichlorodifluoromethane
02/09/23 14:270.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 6Date:02/14/2023 12:15 PM
Page 10 of 17
Quality Control Data
23-040-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Food Plus 1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29658QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29657
Associated Lab Samples: 99276
LRB-V29657 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/09/23 14:270.5000.150<0.150µg/L1,2-Dichloroethane
02/09/23 14:270.5000.150<0.150µg/L1,1-Dichloroethene
02/09/23 14:270.5000.200<0.200µg/Lcis-1,2-Dichloroethene
02/09/23 14:270.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
02/09/23 14:270.5000.190<0.190µg/L1,2-Dichloropropane
02/09/23 14:270.5000.130<0.130µg/L1,3-Dichloropropane
02/09/23 14:272.000.210<0.210µg/L2,2-Dichloropropane
02/09/23 14:270.5000.200<0.200µg/L1,1-Dichloropropene
02/09/23 14:270.5000.210<0.210µg/Lcis-1,3-Dichloropropene
02/09/23 14:270.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
02/09/23 14:2720042.0<42.0µg/LEthanol
02/09/23 14:270.5000.170<0.170µg/LEthylbenzene
02/09/23 14:273.000.350<0.350µg/LHexachlorobutadiene
02/09/23 14:271.000.380<0.380µg/L2-Hexanone
02/09/23 14:270.5000.180<0.180µg/LIsopropylbenzene
02/09/23 14:270.5000.089<0.089µg/L4-Isopropyl toluene
02/09/23 14:275.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
02/09/23 14:271.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
02/09/23 14:271.000.078<0.078µg/L4-Methyl-2-Pentanone
02/09/23 14:272.000.330<0.330µg/LMethylene Chloride
02/09/23 14:271.000.470<0.470µg/LNaphthalene
02/09/23 14:270.5000.190<0.190µg/Ln-Propylbenzene
02/09/23 14:270.5000.220<0.220µg/LStyrene
02/09/23 14:2710.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
02/09/23 14:2710.00.350<0.350µg/Ltert-Butyl formate (TBF)
02/09/23 14:2710.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
02/09/23 14:2710.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 2 of 6Date:02/14/2023 12:15 PM
Page 11 of 17
Quality Control Data
23-040-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Food Plus 1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29658QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29657
Associated Lab Samples: 99276
LRB-V29657 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
02/09/23 14:270.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
02/09/23 14:270.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
02/09/23 14:270.5000.220<0.220µg/LTetrachloroethene
02/09/23 14:270.5000.220<0.220µg/LToluene
02/09/23 14:270.5000.380<0.380µg/L1,2,3-Trichlorobenzene
02/09/23 14:270.5000.310<0.310µg/L1,2,4-Trichlorobenzene
02/09/23 14:270.5000.160<0.160µg/L1,1,1-Trichloroethane
02/09/23 14:270.5000.096<0.096µg/L1,1,2-Trichloroethane
02/09/23 14:270.5000.180<0.180µg/LTrichloroethene
02/09/23 14:270.5000.180<0.180µg/LTrichlorofluoromethane
02/09/23 14:270.5000.270<0.270µg/L1,2,3-Trichloropropane
02/09/23 14:270.5000.190<0.190µg/L1,2,4-Trimethylbenzene
02/09/23 14:270.5000.180<0.180µg/L1,3,5-Trimethylbenzene
02/09/23 14:275.001.00<1.00µg/LVinyl Acetate
02/09/23 14:270.5000.170<0.170µg/LVinyl Chloride
02/09/23 14:270.5000.210<0.210µg/Lo-Xylene
02/09/23 14:271.000.420<0.420µg/Lm,p-Xylene
02/09/23 14:2710.01.00<1.00µg/L3,3-Dimethyl-1-butanol
02/09/23 14:274-Bromofluorobenzene (S)101 70-130
02/09/23 14:27Dibromofluoromethane (S)101 70-130
02/09/23 14:271,2-Dichloroethane - d4 (S)99.2 70-130
02/09/23 14:27Toluene-d8 (S)99.6 70-130
Page 3 of 6Date:02/14/2023 12:15 PM
Page 12 of 17
Quality Control Data
23-040-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Food Plus 1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29658QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29657
LCS-V29657 LCSD-V29657Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
43.9 11010140.540.0µg/LAcetone 40-160 8.0 20.0
21.7 10910821.620.0µg/LBenzene 70-130 0.4 20.0
21.5 10811222.320.0µg/LBromobenzene 70-130 3.6 20.0
22.1 11111522.920.0µg/LBromochloromethane 70-130 3.5 20.0
24.1 12112324.520.0µg/LBromodichloromethane 70-130 1.6 20.0
23.9 12012024.020.0µg/LBromoform 70-130 0.4 20.0
26.8 13413927.720.0µg/LBromomethane 60-140 3.3 20.0
23.4 11711923.720.0µg/Ln-Butylbenzene 70-130 1.2 20.0
22.5 11311823.620.0µg/Lsec-Butyl benzene 70-130 4.7 20.0
21.8 10911522.920.0µg/Ltert-Butyl benzene 70-130 4.9 20.0
25.3 127134*26.820.0µg/LCarbon Tetrachloride 70-130 5.7 20.0
21.8 10910621.220.0µg/LChlorobenzene 70-130 2.7 20.0
23.0 11511322.620.0µg/LChlorodibromomethane 70-130 1.7 20.0
24.1 12112424.820.0µg/LChloroethane 60-140 2.8 20.0
21.2 10610621.120.0µg/LChloroform 70-130 0.4 20.0
19.9 99.510220.320.0µg/LChloromethane 60-140 1.9 20.0
20.2 10111823.520.0µg/L2-Chlorotoluene 70-130 15.1 20.0
21.7 10911122.220.0µg/L4-Chlorotoluene 70-130 2.2 20.0
21.7 10911222.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.7 20.0
21.3 10710521.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.4 20.0
21.9 11010721.320.0µg/L1,2-Dibromoethane 70-130 2.7 20.0
21.7 10910821.620.0µg/LDibromomethane 70-130 0.4 20.0
21.3 10711222.320.0µg/L1,2-Dichlorobenzene 70-130 4.5 20.0
21.8 10910821.620.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0
21.3 10711122.220.0µg/L1,4-Dichlorobenzene 70-130 4.1 20.0
22.3 11211422.820.0µg/LDichlorodifluoromethane 60-140 2.2 20.0
Page 4 of 6* QC Fail Date:02/14/2023 12:15 PM
Page 13 of 17
Quality Control Data
23-040-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Food Plus 1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29658QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29657
LCS-V29657 LCSD-V29657Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.1 11111122.220.0µg/L1,1-Dichloroethane 70-130 0.4 20.0
20.9 10510721.420.0µg/L1,2-Dichloroethane 70-130 2.3 20.0
23.1 11611222.420.0µg/L1,1-Dichloroethene 70-130 3.0 20.0
21.0 10510721.320.0µg/Lcis-1,2-Dichloroethene 70-130 1.4 20.0
22.3 11211623.120.0µg/Ltrans-1,2-Dichloroethene 70-130 3.5 20.0
22.0 11011122.220.0µg/L1,2-Dichloropropane 70-130 0.9 20.0
21.1 10610420.720.0µg/L1,3-Dichloropropane 70-130 1.9 20.0
21.9 11011322.620.0µg/L2,2-Dichloropropane 70-130 3.1 20.0
23.6 11811923.720.0µg/L1,1-Dichloropropene 70-130 0.4 20.0
22.8 11411222.420.0µg/Lcis-1,3-Dichloropropene 70-130 1.7 20.0
22.8 11411222.420.0µg/Ltrans-1,3-Dichloropropene 70-130 1.7 20.0
543 109118590500µg/LEthanol 60-140 8.2 20.0
20.7 10410621.120.0µg/LEthylbenzene 70-130 1.9 20.0
22.0 11011623.220.0µg/LHexachlorobutadiene 70-130 5.3 20.0
21.3 10710320.620.0µg/L2-Hexanone 60-140 3.3 20.0
22.4 11211422.720.0µg/LIsopropylbenzene 70-130 1.3 20.0
23.4 11711923.820.0µg/L4-Isopropyl toluene 70-130 1.6 20.0
19.0 95.094.018.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 1.0 20.0
21.2 10610821.520.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.4 20.0
21.9 11011021.920.0µg/L4-Methyl-2-Pentanone 60-140 0.0 20.0
21.4 10710521.020.0µg/LMethylene Chloride 70-130 1.8 20.0
17.0 85.083.016.620.0µg/LNaphthalene 70-130 2.3 20.0
22.1 11111122.120.0µg/Ln-Propylbenzene 70-130 0.0 20.0
22.9 11511523.020.0µg/LStyrene 70-130 0.4 20.0
40.5 10189.235.740.0µg/Ltert-Butyl Alcohol (TBA)40-140 12.5 20.0
32.6 81.584.533.840.0µg/Ltert-Butyl formate (TBF)40-140 3.6 20.0
Page 5 of 6Date:02/14/2023 12:15 PM
Page 14 of 17
Quality Control Data
23-040-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Food Plus 1
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V29658QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V29657
LCS-V29657 LCSD-V29657Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.4 11212725.420.0µg/Ltert-Amyl Alcohol (TAA)40-140 12.5 20.0
43.6 10910943.540.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.2 20.0
21.9 11010921.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0
22.1 11111022.020.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.4 20.0
20.6 10310621.220.0µg/LTetrachloroethene 70-130 2.8 20.0
21.6 10811122.120.0µg/LToluene 70-130 2.2 20.0
21.0 10510120.220.0µg/L1,2,3-Trichlorobenzene 70-130 3.8 20.0
21.7 10911322.520.0µg/L1,2,4-Trichlorobenzene 70-130 3.6 20.0
22.7 11411523.020.0µg/L1,1,1-Trichloroethane 70-130 1.3 20.0
21.5 10810721.420.0µg/L1,1,2-Trichloroethane 70-130 0.4 20.0
21.9 11010521.020.0µg/LTrichloroethene 70-130 4.1 20.0
23.5 11811823.620.0µg/LTrichlorofluoromethane 60-140 0.4 20.0
18.6 93.094.518.920.0µg/L1,2,3-Trichloropropane 70-130 1.6 20.0
21.6 10811322.620.0µg/L1,2,4-Trimethylbenzene 70-130 4.5 20.0
22.0 11011422.820.0µg/L1,3,5-Trimethylbenzene 70-130 3.5 20.0
26.1 13113627.220.0µg/LVinyl Acetate 60-140 4.1 20.0
25.5 12812424.720.0µg/LVinyl Chloride 60-140 3.1 20.0
21.4 10710921.720.0µg/Lo-Xylene 70-130 1.3 20.0
43.8 11011244.940.0µg/Lm,p-Xylene 70-130 2.4 20.0
25.6 12811422.720.0µg/L3,3-Dimethyl-1-butanol 70-130 12.0 20.0
99.21014-Bromofluorobenzene (S)70-130
10198.6Dibromofluoromethane (S)70-130
99.498.61,2-Dichloroethane - d4 (S)70-130
99.099.4Toluene-d8 (S)70-130
Page 6 of 6Date:02/14/2023 12:15 PM
Page 15 of 17
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-040-0005
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 3.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:02/09/2023 10:40:38
Special precautions or instructions included?
Comments:
Page 16 of 17
Page 17 of 17