FA-28135_47395_CA_RPTS_20230314_REVISEDARA

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
March 14, 2023

Mr. Mike Haseltine
NCDEQ-UST Section
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405

Re: Additional Risk Assessment Report
August 2022
Moore’s Citgo
305 South Church Street
Kenly, Johnston County
North Carolina
Facility ID Number: 0-00-0000030088
Incident Number: 7709 / 47395
GRI Project Number: 5285

Dear Mr. Haseltine,

Please find enclosed, the referenced report for the abovementioned site.
If you have any questions, please contact Rae Brown at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Ahmad Dari, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Additional Risk Assessment Report
August 2022
Moore’s Citgo
305 South Church Street
Kenly, Johnston County
North Carolina
Facility ID Number: 0-00-0000030088
Incident Number: 7709 / 47395
GRI Project Number: 5285

Prepared for:

Mr. Ahmad Dari
106 Brockton Ridge Drive
Garner, North Carolina 27529

Revised
March 14, 2023

Rae Troiano Brown, P. G.
Project Manager
Sharon Lowther
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
i
EXECUTIVE SUMMARY
The Moore’s Citgo site is located at 305 South Church Street in Kenly, Johnston County, North Carolina.
The property operates as a petroleum retail facility and convenience store. A site check was conducted
in May 2020 follow a ground water sampling event conducted by the State Lead contractor that confirmed
the presence of a release. Three 6,000-gallon gasoline USTs are currently in use at the site. No water
supply wells were identified within a 1,500-foot radius of the site. Public water is available to the subject
site and to all surrounding properties. No surface water bodies were identified within a 500-foot radius
of the site.

On September 6, 2019, the NCDEQ received analytical data from a ground water sampling event
conducted by a State Lead contractor that indicated a release from the current UST system had occurred.
In 2020, a site check and Limited Site Assessment were completed.

On August 15 and 16, 2022, during Additional Risk Assessment activities, three Type II monitoring wells
and one Type III monitoring well were installed at the site. Nine soil samples were collected during
installation of the monitoring wells and submitted for TPH-GRO analysis. The concentrations of GRO
reported in soil samples MW-2 2’, MW-2 24’, MW-3 24’, MW-4 20’, MW-4 24’, TW-1 10’, and TW-1 20’
exceeded the RAL.

On August 16 and 25, 2022, four Type II monitoring wells and one telescoping well were gauged, purged
and/or sampled. Free product was present in MW-1, MW-3, and MW-4 during both sampling events.
Concentrations of benzene, MTBE, naphthalene, TAA, bromodichloromethane, TBA,
dibromochloromethane, C5-C8 aliphatics, and/or C9-C10 aromatics reported in the ground water samples
from MW-2 and TW-1 exceeded the MACs during one or both sampling events. All concentrations were
below GCL.

Rising head slug tests were conducted on MW-2 and TW-1 in August 2022. The hydraulic conductivity and
seepage velocity for Type II monitoring well were 2.175 x 10-5 feet per minute (3.132 x 10-2 feet per day)
and 3.13 x 10-3 feet per day (1.14 feet per year), respectively. The hydraulic conductivity and seepage
velocity in the Type III monitoring were 1.795 x 10-2 feet per minute (25.85 feet per day) and 2.58 feet per
day (943 feet per year), respectively.

Based on this information, the site should be remain intermediate risk due to the presence of free product
and a CSA should be conducted at the site. Free product removal activities should be conducted at the
site until free product is no longer present

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
ii
SITE INFORMATION
1. Site Identification
 Moore’s Citgo (Facility ID 0-00-0000030088)
 Incident Number 7709 / 47395 – Intermediate Risk (I235A)
 Location of Source Area: 305 South Church Street
Kenly, NC 28677
Johnston County
35.594436°N, 78.128942°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST Owner UST/AST Owner
Ahmad Dari Speedway, LLC
PO Box 182
Kenly, NC 27542
500 Speedway Drive
Enon, OH 45323
[e-mail] [e-mail]
252-452-1848 919-516-8069

UST Operator UST/AST Operator
Ahmad Dari Speedway, LLC
PO Box 182
Kenly, NC 27542
500 Speedway Drive
Enon, OH 45323
[e-mail] [e-mail]
252-452-1848 919-516-8069

Property Owner Property Owner
Ahmad Dari William’s Family Heirs, LLC
106 Brockton Ridge Drive
Garner, NC 27529
3602 US Highway 264 East
Greenville, NC 27858
[e-mail] Email Unknown
252-452-1848 Phone No. Unknown

Property Occupant
Moore’s Citgo
305 South Church Street
Kenly, NC 27542
[e-mail]
252-452-1848

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical, LLC
449 Springbrook Road
Charlotte, NC 28217
State Certification No. 402
704-529-6364
3. Information about Release
 Release was discovered on June 16, 2020.
 An unknown amount of product was released from the leaking UST System.
 Three 6,000-gallon gasoline USTs are in use at the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant
Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”

NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
TABLE OF CONTENTS
EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ............................................................................................................................ ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 MONITORING WELL INSTALLATION ..........................................................................................2
3.0 HYDROGEOLOGIC INVESTIGATION ...........................................................................................3
4.0 GROUND WATER QUALITY INFORMATION ...............................................................................4
5.0 FREE PRODUCT REMOVAL ........................................................................................................5
6.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................5
7.0 CONCLUSIONS .........................................................................................................................5
8.0 LIMITATIONS ...........................................................................................................................6
9.0 STATEMENTS AND CERTIFICATION ...........................................................................................6

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Site Vicinity Map
Figure 4: Soil Quality Map
Figure 5: Water Table Surface Map
Figure 6: Ground Water Quality Map
Figure 7: Cross-Section A-A’
Figure 8: Cross-Section B-B’

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Adjacent Property Owner Information
Table 4: Summary of Soil Sample Analytical Results
Table 5: Well Construction and Gauging Information
Table 6: Summary of Slug Test Analyses
Table 7: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: State Correspondence
Appendix B: Well Construction Records and Subsurface Logs
Appendix C: Slug Test Analysis
Appendix D: Laboratory Analytical Reports

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the August 2022 additional risk assessment activities at the Moore’s Citgo site;
located at 305 South Church Street in Kenly, Johnston County, North Carolina (Figure 1). The scope of
work was conducted in accordance with GRI Proposal No. 21-616. Two scopes of work were submitted
under GRI Proposal No. 21-616 which were submitted to the NCDEQ on October 7, 2021 and April 18,
2022, and were approved as Task Authorization Nos. 7709-47395-2 and 7709-47395-3 on October 5, 2021
and April 18, 2022, respectively. State correspondence has been included as Appendix A.

In 1992, a release (Incident No. 7709) was reported at the site. The responsible party filed for bankruptcy
and the company dissolved in 1993. The site was admitted to the State Lead program. Incident No. 7709
was administratively closed out on December 7, 2021, by the UST section after the release was
determined to be comingled with the current release (Incident No. 47395).

On September 6, 2019, the NCDEQ received analytical data from the State Lead contractor indicating a
release or discharge from the current UST system had occurred at the site. On May 13, 2020, GRI
conducted a site check that confirmed the presence of a release. This release was issued Incident No.
47395 and was determined to be comingled with Incident No. 7709.

The site is currently owned and operated by Mr. Ahmad Dari as a petroleum retail facility. Currently, three
6,000-gallon gasoline USTs are active at the site. UST owner/operator information and UST system
information are included as Tables 1 and 2, respectively. The Registered Tank Report is shown below:

The site is an active convenience store and petroleum retail facility. The surrounding area is a mixture of
residential and commercial properties. The site contains one building and is primarily capped with
concrete and asphalt. The overall topography at the site is relatively flat. No surface water bodies were

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
2
identified within a 500-foot radius of the site. One Type II monitoring well (MW-1) was installed at the
site during previous ground water assessment activities. A Site Map showing the locations of the
monitoring wells and the structures on-site has been included as Figure 2.

On September 30, 2020, a receptor survey was conducted. No water supply wells were identified within
a 1,500-foot radius of the site. Public water is available to the subject site and to all surrounding
properties. No surface water bodies were identified within a 500-foot radius of the site. Adjacent property
owner information is presented in Table 3. A Site Vicinity Map showing the adjacent properties has been
included as Figure 3.

2.0 MONITORING WELL INSTALLATION
On August 15 and 16, 2022, three Type II monitoring wells (MW-2, MW-3 and MW-4) and one Type III
monitoring well (TW-1) were installed. MW-2, MW-3 and MW-4 were each installed to a total depth of
25 feet with a screened interval of 20 feet. TW-1 was installed to a total depth of 46 feet with a screened
interval of 5 feet. Copies of the subsurface logs and Well Construction Records have been included in
Appendix B. Photos of MW-2, MW-3, MW-4 and TW-1 are shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
3

3.0 SOIL ASSESSMENT
On August 15 and 16, 2022, soil samples were collected every 2 feet during the installation of monitoring
wells MW-2, MW-3, MW-4, and TW-1 and screened using a PID. The soil samples with the highest PID
readings from the saturated and unsaturated zones of each well were submitted for laboratory analysis
of TPH-GRO. The concentrations exceeded the RAL in soil samples MW-2-2’, MW-2-24’, MW-3-24’, MW-
4-20’, MW-4-24’, TW-1-10’, and TW-1-20’. The soil sampling analytical results are presented in Table 4.
A Soil Quality Map with the results of the soil sampling in 2022 has been included as Figure 4.

4.0 HYDROGEOLOGIC INVESTIGATION
On August 16 and 25, 2022, four Type II monitoring wells (MW-1 through MW-4) and one telescoping well
(TW-1) were gauged, purged and/or sampled in accordance with the NCDEQ guidelines. Free product was
observed in monitoring wells MW-1, MW-3, and MW-4 during both sampling events.

The depths to ground water in the Type II monitoring wells (MW-1 through MW-4) measured on August
16, 2022 ranged from 6.46 to 7.22 feet below the tops of well casings. Ground water elevations at the
site, based on an assumed datum of 100 feet, ranged from 92.56 to 93.73 feet relative to a temporary
benchmark.

The depths to ground water in the Type II monitoring wells (MW-1 through MW-4) measured on August
25, 2022 ranged from 4.74 to 6.67 feet below the tops of well casings. Ground water elevations at the
site, based on an assumed datum of 100 feet, ranged from 93.37 to 94.64 feet relative to a temporary
benchmark. Based on this information, the ground water flow direction was generally toward the south.
The horizontal hydraulic gradient between MW-3 and MW-4 was approximately 0.02 feet per foot. The
vertical hydraulic gradient calculated for paired wells MW-1 and TW-1 was 0.009 feet per foot in the

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
4
downward direction. Well construction and gauging information is presented in Table 5. A Water Table
Surface Map based on the Type II monitoring wells is included as Figure 5. A summary of the August 25,
2022 ground water gauging data is shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of
Casing
(ft.)
Free Product
Thickness
(ft.)
Groundwater
Elevation
(ft.)
MW-1 3 - 23 27 100.34 6.06 0.30 94.54
MW-2 5 - 25 25 99.08 4.74 --- 94.34
MW-3 5 - 25 25 100.00 6.67 0.05 93.37
MW-4 5 - 25 25 100.82 6.27 0.10 94.64
TW-1 41 - 46 46 100.29 6.08 --- 94.21

Rising head slug tests were conducted in MW-2 and TW-1 on August 25, 2022. The hydraulic conductivity
in the Type II monitoring well (MW-2) calculated using the Bouwer and Rice method, was 2.175 x 10-5 feet
per minute (3.132 x 10-2 feet per day). The seepage velocity in MW-2, calculated using the equation V =
k(dh/dl)/ne, was 3.13 x 10-3 (1.14 feet per year). The hydraulic conductivity in the Type III monitoring well
calculated using the Bouwer and Rice method was 1.795 x 10-2 feet per minute (25.85 feet per day). The
seepage velocity calculated for the Type III monitoring well was 2.58 feet per day (943 feet per year). A
summary of the results of the slug test analyses is presented in Table 6. Calculations and raw data from
the slug tests have been included as Appendix C.
5.0 GROUND WATER QUALITY INFORMATION
Ground water samples collected from monitoring wells MW-2 and TW-1 during both August 2022
sampling events were submitted for laboratory analyses using EPA Method 6200B, EPA Method 6010, and
MADEP VPH. Ground water samples were not collected from MW-1, MW-3 and MW-4 during either
sampling event due to the presence of free product. The concentrations of benzene, MTBE, naphthalene,
TAA, bromodichloromethane, TBA, dibromochloroethane, C5-C8 aliphatics, and C9-C10 aromatics
reported in the ground water samples collected from MW-2 and/or TW-1 on August 16, 2022 exceeded
the MACs. The concentrations of benzene, MTBE, naphthalene, TAA, TBA, C5-C8 aliphatics, and C9-C10
aromatics reported in the ground water samples collected from MW-2 and/or TW-1 on August 25, 2022
exceeded the MACs. All the reported contaminant concentrations were below GCLs during both August
2022 sampling events. A summary of the analytical results for ground water samples collected in August
2022 is presented in Table 7. A Ground Water Quality Map based on the August 25, 2022 data is included
as Figure 6. Complete reports of laboratory analyses of the ground water samples collected from the
monitoring wells during the August 2022 sampling events have been included as Appendix D. Cross
sections A-A’ and B-B’ are included as Figures 7 and 8; the lines of cross section are included on Figure 2.
A summary of the August 25, 2022 ground water analytical data is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
5

Contaminant
of Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MAC (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 FP FP FP FP FP FP
MW-2 401 40.6 51.4 66.8 451 27.6
MW-3 FP FP FP FP FP FP
MW-4 FP FP FP FP FP FP
TW-1 1.13 1.62 0.941 5.52 0.876 J 0.656 J

All samples were collected in accordance with the NCDEQ guidelines. Clean, disposable bailers and nitrile
gloves were used for the collection of the ground water samples. The samples were collected in
laboratory supplied containers and shipped to the laboratory in a cooler following proper chain-of-custody
procedures.

The site is located in the Coastal Plain Physiographic Province of North Carolina. The surficial aquifer
overlies the Upper Tertiary and Upper Cape Fear aquifers and associated confining units. The water table
has a seasonal high depth to water of approximately five to seven feet BGS.
6.0 FREE PRODUCT REMOVAL
Free product was present in MW-1, MW-3 and MW-4 during both August 2022 sampling events. To date,
no free product recovery has been performed.

MMPE events should be scheduled to remove free product from MW-1, MW-3, and MW-4.
7.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
The site is currently in the assessment phase; therefore, no natural attenuation monitoring plan is
currently in place at the site.
8.0 CONCLUSIONS
 On August 15 and 16, 2022, three Type II monitoring wells and one Type III monitoring well were
installed. MW-2, MW-3 and MW-4 were installed to a total depth of 25 feet with a screened
interval of 20 feet. TW-1 was installed to a total depth of 46 feet with a screened interval of 5
feet.
 On August 16 and 25, 2022, four Type II monitoring wells and one telescoping well were gauged,
purged and/or sampled. Free product was present in MW-1, MW-3, and MW-4 during both
sampling events. Ground water flow was generally to the south with a horizontal gradient of
approximately 0.02 feet per foot. The vertical gradient between paired wells MW-1 and TW-1
was approximately 0.009 feet per foot in the downward direction.
 Concentrations of benzene, MTBE, naphthalene, TAA, bromodichloromethane, TBA,
dibromochloromethane, C5-C8 aliphatics, and/or C9-C10 aromatics reported in the ground water

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
6
samples from MW-2 and TW-1 exceeded the MACs during one or both sampling events. All
concentrations were below GCL.
 Based on this information, the site should remain intermediate risk due to the presence of free
product and a CSA should be conducted at the site. Free product removal activities should be
conducted at the site until free product is no longer present.

9.0 LIMITATIONS
This report has been prepared for the exclusive use of Mr. Ahmad Dari for the specific application to the
referenced site in Johnston County, North Carolina. The assessment was conducted based on the scope
of work and level of effort desired by the NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
10.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. n/a Will this report be submitted after the
established due date?
YES NO
2 Was any required information from the above template missing from this report? YES NO
IF the answer to question #1 or# 2 is “YES”, please provide additional information in this cell to explain
what was missing and why.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved
in the Corrective Action Plan not be met? (within a reasonable margin of error)
YES NO
IF the answer to question #3 is “NO”, skip to the certification under #8 below.
IF the answer to question #3 is “YES”, please generally describe in this cell the possible reason(s) and
outline proposed remedies. (This should be described in more detail in the report text above.)

N/A
4 Does any known or suspected source zone soil contamination or free product remain
outside of the assessed area that could be inhibiting natural attenuation?
YES NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a
potential new release from a separate onsite or offsite source?
YES NO

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Additional Risk Assessment Report
Prepared on: March 14, 2023 Moore’s Citgo
Project Manager: Rae Troiano Brown, P. G. GRI Project No. 5285
7
IF the answer to either question #4 or #5 is “YES”, generally describe in this cell any actions
recommended to further assess or clean up this known or suspected source. (This should be described
in more detail in the report text above.)

6 Certification:
I, Rae Troiano Brown, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice engineering and geology in North Carolina. The
certification number of the company or corporation is C-2727/C-127.

FIGURES
SITE LOCATION500 M2000 FTDate: 05/25/2020Location: 35.594436° N -78.128942° W Dad Figure 1 Site Location Moore’s Citgo305 South Church StreetKenly, Johnston County, NC Incident No. 7709/47395 GRI Project No. 5285
SITE
265720-82-6363
265720-82-9003
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26
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FIGURE 'S CITGO305 SOUTH CHURCH STREETKENLY, JOHNSTON COUNTYNORTH CAROLINA GRI NO. 5285
PREPARED BY:GEOLOGICAL RESOURC INC.SEPTE 202
1,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
³
0 300150Feet1 inch = 300 feet
LEGEND
Ditch
Street Centerlines
Hydrology
Adjacent Parcels
Johnston County NC parcels_2020
INCIDENT NO. 7709 / 47395
MBER 1 ES,
2
3: SITE VICINITY MAP MOORE

TABLES
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1-3 Facility ID Number
Owner or Operator?
Owner/Operator
0-00-0000030088
TABLE 1
UST OWNER/OPERATOR INFORMATION
MOORE'S CITGO (INCIDENT NO. 7709/47395)
106 Brockton Rdige Drive, Garner, NC 27529 252-452-1848
Name of Owner or Operator Dates of Ownership / Operation
Ahmad Dari 07/12/2006 - Current
Address Telephone Number
Address Telephone Number
Unknown Unknown
0-00-0000030088
Name of Owner or Operator Dates of Ownership / Operation
Billy Moore 07/07/1993 - 07/12/2006
Address Telephone Number
Unknown Unknown
0-00-0000030088
Name of Owner or Operator Dates of Ownership / Operation
Pope Oil Company 01/01/1978 - 07/07/1993
Page 1 of 1
Date: 05/21/20
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline NA 6,000 1/1/1978 Single Wall Steel 8' x 16' Single Wall FRP Current Yes
2 Gasoline NA 6,000 1/1/1978 Single Wall Steel 8' x 16' Single Wall FRP Current Yes
3 Gasoline NA 6,000 1/1/1978 Single Wall Steel 8' x 16' Single Wall FRP Current Yes
TABLE 2
UST SYSTEM INFORMATION
MOORE'S CITGO (INCIDENT NO. 7709/47395)
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Facility ID #: 0-00-0000030088
Page 1 of 1
Date: 08/29/22 Facility ID #: 0-00-0000030088
PIN Number Property Owner Name Property Owner Address
265720-82-8373 (site) Ahmad Dari
106 Brockton Ridge Drive
Garner, NC 27529
265720-82-7482 Robert Doyce Austin, Jr. and Shawna
Marie Austin
3001 Reedybrook Crossing, Apartment 3421
Apex, NC 27523
265716-82-9524 Robbie D. Brown and
Ryan D. Brown
316 S Maple Avenue
Kenly, NC 27542
265720-92-0401 Rafat Said Elbardawell and
Tawfiq Ibrahim Awad
2633 Tummel Lane
Fuquay Varina, NC 27526
265720-92-0292 Epark LLC P.O. Box 10907
Goldsboro NC, 27532
265720-82-9003 Daughtridge Enterprises Inc.P.O. Box 593
Rocky Mount, NC 27802
265720-82-6363 Shri Ganesha Inc.403 S Crurch Street
Kenly NC, 27542
Note:
• Properties are keyed to Figure 2.
TABLE 3
ADJACENT PROPERTY OWNER INFORMATION
MOORE'S CITGO (INCIDENT NO. 7709/47395)
Page 1 of 1
Date: 09/02/22 Facility ID #: 0-00-0000030088
5030/
8015D
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)Gasoline-Range TPHBenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl-ether (MTBE)Naphthalenen-ButylbenzeneIsopropylbenzenen-PropylbenzeneC5-C8 AliphaticsC9-C10 Aromatics50 NE NE NE NE NE NE NE NE NE NE NE
NE 0.0056 4.3 4.9 4.6 0.091 0.16 4.3 1.7 1.7 68 31
NE 18 1,200 1,560 3,129 350 313 626 1,564 626 939 469
SB-1-3' 05/13/2020 3 553 NR NR NR NR NR NR NR NR NR NR NR
SB-2-3' 05/13/2020 3 198 NR NR NR NR NR NR NR NR NR NR NR
SB-3-3' 05/13/2020 3 4.64 J NR NR NR NR NR NR NR NR NR NR NR
SB-4-3' 05/13/2020 3 388 NR NR NR NR NR NR NR NR NR NR NR
SB-5-3' 05/13/2020 3 14.9 NR NR NR NR NR NR NR NR NR NR NR
SB-6-3' 05/13/2020 3 458 NR NR NR NR NR NR NR NR NR NR NR
SB-7-3' 05/13/2020 3 6.07 NR NR NR NR NR NR NR NR NR NR NR
SB-8-3' 05/13/2020 3 45.9 NR NR NR NR NR NR NR NR NR NR NR
SB-9-3' 05/13/2020 3 194 NR NR NR NR NR NR NR NR NR NR NR
SB-10-3' 05/13/2020 3 107 NR NR NR NR NR NR NR NR NR NR NR
SB-11-3' 05/13/2020 3 12.7 NR NR NR NR NR NR NR NR NR NR NR
MW-1-3' 9/24/2020 3 NR 0.0877 J <0.60 3.25 1.72 <0.060 9.47 8.25 6.29 11.7 1,340 211 J
MW-2 2' 08/16/2022 2 50.7 NR NR NR NR NR NR NR NR NR NR NR
MW-2 24' 08/16/2022 24 1,920 NR NR NR NR NR NR NR NR NR NR NR
MW-3 18' 08/16/2022 18 38.5 NR NR NR NR NR NR NR NR NR NR NR
MW-3 24' 08/16/2022 24 289 NR NR NR NR NR NR NR NR NR NR NR
MW-4 20' 08/16/2022 20 58.2 NR NR NR NR NR NR NR NR NR NR NR
MW-4 24' 08/16/2022 24 649 NR NR NR NR NR NR NR NR NR NR NR
TW-1 10' 8/15/2022 10 737 NR NR NR NR NR NR NR NR NR NR NR
TABLE 4
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
MOORE'S CITGO (INCIDENT NO. 7709/47395)
EPA Method 8260B MADEP VPH
Residential SCLs (mg/kg)
Analytical Method 
RAL (mg/kg)
Soil to Water MCC (mg/kg)
Page 1 of 2
Date: 09/02/22 Facility ID #: 0-00-0000030088
5030/
8015D
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)Gasoline-Range TPHBenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl-ether (MTBE)Naphthalenen-ButylbenzeneIsopropylbenzenen-PropylbenzeneC5-C8 AliphaticsC9-C10 Aromatics50 NE NE NE NE NE NE NE NE NE NE NE
NE 0.0056 4.3 4.9 4.6 0.091 0.16 4.3 1.7 1.7 68 31
NE 18 1,200 1,560 3,129 350 313 626 1,564 626 939 469
TABLE 4
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
MOORE'S CITGO (INCIDENT NO. 7709/47395)
EPA Method 8260B MADEP VPH
Residential SCLs (mg/kg)
Analytical Method 
RAL (mg/kg)
Soil to Water MCC (mg/kg)
TW-1 20' 8/15/2022 20 384 NR NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• ft-BGS: feet below ground surface.
• RAL: Regulatory Action Level.
• MCCs: Maximum Contaminant Concentrations (soils).
• SCLs: Soil Cleanup Levels.
• NE: Not Established
• NR: Not Requested.
• J: Estimated Concentrations
• Concentrations in bold exceeded The RAL.
Page 2 of 2
Date: 09/02/22 Facility ID #: 0-00-0000030088
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Depth to Free
Product**
(ft.)
Free Product
Thickness **
(ft.)
Groundwater
Elevation
(ft.)
Comments
09/24/20 4.91 NM NM NM
08/16/22 6.82 6.57 0.25 93.73
08/25/22 6.06 5.76 0.30 94.54
08/16/22 6.52 --- --- 92.56
08/25/22 4.74 --- --- 94.34
08/16/22 6.46 6.45 0.01 93.55
08/25/22 6.67 6.62 0.05 93.37
08/16/22 7.22 7.17 0.05 93.64
08/25/22 6.27 6.17 0.10 94.64
08/16/22 7.69 --- --- 92.60
08/25/22 6.08 --- --- 94.21
Notes:
• ** : If free product is present in a well, ground water elevation calculated by: [Top of Casing Elevation - Depth to Water] + [free product thickness x 0.8581].
• ft BGS : feet below ground surface.
• NA: Not available.
• NM: Not measured.
25
25
25
46
99.08
100.00
100.82
100.29
5 5 - 25
5
5
41
5 - 25
5 - 25
41 - 46
MW-2
MW-3
MW-4
TW-1
08/16/22
08/16/22
08/16/22
08/15/22
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
MOORE'S CITGO (INCIDENT NO. 7709/47395)
MW-1 09/24/20 23 3 - 23 27 100.34
Page 1 of 1
Facility ID#: 0-00-0000030088
ft/min ft/day ft/day ft/year
MW-2 2.175E-05 3.132E-02 3.13E-03 1.14E+00
TW-1 1.795E-02 2.585E+01 2.58E+00 9.43E+02
Note:
Seepage velocities calculated using the equation v = k(dh/dl)/ne , where:
k = hydraulic conductivity
ne = effective porosity = 0.20
dh/dl = hydraulic gradient = 0.02 ft/ft
TABLE 6
SUMMARY OF SLUG TEST ANALYSES
MOORE'S CITGO (INCIDENT NO. 7709/47395)
Date : 09/12/22
Well Hydraulic Conductivity (k) Seepage Velocity (v)
Date: 09/08/22 Facility ID#: 0-00-0000030088
EPA 6010
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 0.6 10 0.4 70 70 400 400 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 NE 10,000 400 25,000 30,000 28,500 25,000 15,000 NE NE NE
09/24/20 877 2,900 2,450 3,580 111 549 546 J <13 <200 <13 175 354 1,370 302 21 6,550 791 J 3,750
08/16/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
08/25/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
08/16/22 571 133 91.1 94.2 449 12.5 986 <0.160 138 <0.190 38.5 53.2 25.7 8.16 0.003 J 1,880 185 421
08/25/22 401 40.6 51.4 66.8 451 27.6 904 <1.60 372 <1.90 23.5 30.4 10.1 6.33 0.021 1,240 159 341
08/16/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
08/25/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
08/16/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
08/25/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
08/16/22 5.5 15 14.1 49 0.713 J 4.16 12 3.03 5.86 J 1.15 2.61 5.07 10.5 4.7 0.02 186 123 J 36.6 J
08/25/22 1.13 1.62 0.941 5.52 0.876 J 0.656 J <1.90 <0.160 <1.60 <0.190 0.284 J 0.376 J 1.89 0.774 0.010 45.5 J <25.8 <4.02
08/16/22 <0.180 0.64 0.225 J 0.892 J <0.140 <0.470 NR <0.160 NR <0.190 <0.180 <0.190 <0.190 <0.180 NR NR NR NR
08/25/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR <0.160 NR <0.190 <0.180 <0.190 <0.190 <0.180 NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• 2B Standard: North Carolina surface water standards for Class C waters specified in T15A NCAC 2B.0200 or EPA Nathional Criteria.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type indicate the MAC was below the reported concentration.
• Underlined results indicate 10 times the 2B Standards were below the reported concentrations.
• Results in italics indicate the GCLs were below the reported concentrations.
• J: Estimated value.
• NE: Not established.
• S: Toxicity exceeds solubility, no visible sheen or free product in water or on sediment or shoreline per 15A NCAC 02B .0211 & .0220
• NR: Not reported.
TABLE 7
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
MOORE'S CITGO (INCIDENT NO. 7709/47395)
Analytical Method
EPA 6200B
Contaminant of Concern
BenzeneTolueneEthylbenzeneXylenesMTBEMADEP VPH
C9-C12 AliphaticsC9-C10 AromaticsGCL (μg/l)
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.tert-Amyl alcohol(TAA)MW-1
MW-2
TW-1
MW-4
MW-3 Dibromochloromethane(Chlorodibromomethane)Trip Blank C5-C8 AliphaticsMAC (μg/l)NaphthaleneIsopropylbenzenen-Propylbenzene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneLeadBromodichloromethanetert-Butyl alcohol(TBA)Page 1 of 1

APPENDICES

APPENDIX A
State Correspondence
Site Name City / County /Johnston Incident #7709/47395
Resp Pty Name / Contact Incident Mgr Region RAL
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #1
Consultant / Project Mgr /Rae Troiano Brown
Telephone / Fax Number /Task Authorization Number:2 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I235A RRA Date:9/10/2019
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached? [ ] Proof of payment attached directly to the front of each invoice?
Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode
RO IM AuthProposed
Rate/Price
(Consultant)RO Supv. AuthProposed Task
Subtotal
(Consultant)
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
3.101 90 / feet Y $12.50 Y $1,125.00 $1,125.00 /
3.101 60 / feet Y $18.00 Y $1,080.00 $1,080.00 /
3.113 90 / feet Y $50.00 Y $4,500.00 $4,500.00 /
3.115 60 / feet Y $75.00 Y $4,500.00 $4,500.00 /
3.351 4 / wells Y $80.00 Y $320.00 $320.00 /
3.398 2 / events Y $350.00 Y $700.00 $700.00 /
3.500 2 / nights Y $151.00 Y $302.00 $302.00 /
4.031 5 / wells Y $110.00 Y $550.00 $550.00 /
4.090 #240 5 / samples Y $88.00 Y $440.00 $440.00 /
4.090 #271 1 / sample Y $62.00 Y $62.00 $62.00 /
4.090 #280 4 / samples Y $42.00 Y $168.00 $168.00 /
4.090 #330 5 / samples Y $13.00 Y $65.00 $65.00 /
4.090 #341 5 / samples Y $52.00 Y $260.00 $260.00 /
4.090 #350 8 / samples Y $36.00 Y $288.00 $288.00 /
4.090 #590 3 / samples Y $35.00 Y $105.00 $105.00 /
4.090 #640 3 / samples Y $121.00 Y $363.00 $363.00 /
4.091 1 /shipment Y $60.00 Y $60.00 $60.00 /
4.091 1 /shipment Y $80.00 Y $80.00 $80.00 /
5.010 1 / event Y $1,300.00 Y $1,300.00 $1,300.00 /
6.032 1 / report Y $1,800.00 Y $1,800.00 $1,800.00 /
12.030 1 / night Y $151.00 Y $151.00 $151.00 /
12.050 2 / trips Y $250.00 Y $500.00 $500.00 /
/ /
/ /
/ /
/ /
/ /
Requested Preapproved Claimed3
TOTAL:$18,719.00 $18,719.00 TOTAL:
Total Standard Costs (Not Third Party)$18,719.00 $18,719.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty CostsProcess Tracking (Date)
TA Submittal: 10/5/21 by: (PM)(Reserved for RO)
RO Review: 10/7/21 by: (IM) Joint UST Preapproval Confirmed By:Date1 10/7/2021
RO Supv. Review: 10/7/21 by: (STF) RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee within a week of approval. The signed pre-approval must be submitted
in the submitted claim. Signature indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work
proceeding. Scope/cost negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the
UST Section and RP is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 8/1/2020
RTB
Proposed
Units / Type
(Consultant)
James Brown
TRUE
21-616 September 2021
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
100.00%
[e-mail]
Ahmad Dari
Geological Resources, Inc.
DIRECTED - CAB ONLY
Kenly
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Moore's Citgo
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be
attached to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If, following completion of this ePATA,
you discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order" in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12 months of the completion date of the FIRST completed task to remain within the Statute of Limitations. All ePATAs submitted within a claim are closed with
that claim, and may not be re-used in a separate submittal, even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
JWB
MHH
(Initials)
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORMDept of Environmental Quality - Division of Waste Management
10/12/21
Site Name City / County /Johnston Incident #7709-47395
Resp Pty Name / Contact Incident Mgr Region FAY
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #2
Consultant / Project Mgr /Rae Brown
Telephone / Fax Number /Task Authorization Number:3 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I235A RRA Date:9/10/2019
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode
RO IM AuthProposed
Rate/Price
(Consultant)RO Supv. AuthProposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
3.118 150 /feet Y $5.00 Y $750.00 $750.00 /
3.397 2 /Mobe Y $100.00 Y $200.00 $200.00 /
4.090 #240 5 /samples Y $6.00 Y $30.00 $30.00 /
4.090 #271 1 /sample Y $4.00 Y $4.00 $4.00 /
4.090 #280 4 /samples Y $3.00 Y $12.00 $12.00 /
4.090 #330 5 /samples Y $1.00 Y $5.00 $5.00 /
4.090 #341 5 /samples Y $4.00 Y $20.00 $20.00 /
4.090 #350 8 /samples Y $3.00 Y $24.00 $24.00 /
4.090 #590 3 /samples Y $3.00 Y $9.00 $9.00 /
4.090 #640 3 /samples Y $8.00 Y $24.00 $24.00 /
12.055 2 /trip Y $50.00 Y $100.00 $100.00 /
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
Requested Preapproved Claimed 3
TOTAL:$1,178.00 $1,178.00 TOTAL:
Total Standard Costs (Not Third Party)$1,178.00 $1,178.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:4/18/22 by:(PM)(Reserved for RO)
RO Review:4/18/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 4/18/2022
RO Supv. Review:4/18/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee within a week of approval. The signed pre-approval must be submitted
in the submitted claim. Signature indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work
proceeding. Scope/cost negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the
UST Section and RP is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
DIRECTED - CAB ONLY
Kenly
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
Moore's Citgo
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be attached to
elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If, following completion of this ePATA, you discover that
unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request designated as a "Change
Order"in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to the cover of the corresponding
claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been completed within 12 months of the
completion date of the FIRST completed task to remain within the Statute of Limitations. All ePATAs submitted within a claim are closed with that claim, and may not be re-used in a
separate submittal, even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed amount below may be affected by the
eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and necessary expenses per 15A NCAC 2P .0402 and
.0404.
JWB
MHH
(Initials)
RB
Proposed
Units / Type
(Consultant)
James Brown
Yes
21-616 Apr-22
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
100.00%
[e-mail]
Ahmad Dari
Geological Resources, Inc.
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality -Division of Waste Management

July 16, 2021

Dari Ahmad
P.O. Box 182
Kenly, NC 27542

Re: Notice of Regulatory Requirements
15A NCAC 2L .0407(c) [Intermediate Risk]
Risk-based Assessment and Corrective Action
For Petroleum Underground Storage Tanks

Moore’s Citgo
305 South Church Street
Kenly, Johnston County
Incident Number: 7709/47395
Risk Classification: Intermediate
Ranking: I235A
Dear Mr. Ahmad:

The Limited Site Assessment Report received on December 3, 2020, and subsequent Letter Report for
groundwater sampling received on May 12, 2021, has been reviewed by the UST Section, Division of Waste
Management, Fayetteville Regional Office. The review indicates groundwater contamination exceeds the
groundwater quality standards established in Title 15A NCAC 2L .0202 The risk posed by the discharge or
release at the subject site is classified by the Department of Environmental Quality as intermediate, as stipulated
under Title 15A NCAC 2L .0406. The land use at the site is classified as residential. Please note that Title 15A
NCAC 2L .0407(a) requires you to notify the Department of any changes that might affect the risk or land use
classifications that have been assigned.

Title 15A NCAC 2L .0407(c) [Intermediate Risk] requires you to comply with the assessment and
cleanup requirements of Title 15A NCAC 2N .0706 and Title15A NCAC 2L .0106(c) and 2L .0106(g). Failure
to comply in the manner and time specified may result in the assessment of civil penalties and/or the use
of other enforcement mechanisms.

Typically, a Comprehensive Site Assessment (CSA) Report prepared in accordance with these
requirements and the most recent version of the Guidelines for Assessment and Corrective Action for UST
Releases submitted to this office within 90 days of the date of this notice would satisfy this requirement.
Alternatively, an extension to this deadline may be obtained through the completion and submittal of a Risk
Assessment Report within 90 days of this notice. This report supplements the LSA through the assessment of
groundwater characteristics and the risk to nearby receptors. Specifically, the Risk Assessment Report should
include, at a minimum:

The installation of three horizontal extent monitoring wells and one vertical extent monitoring well. One
monitoring well shall be installed upgradient of the source of contamination and two monitoring wells shall be
installed downgradient of the source of contamination, as best as can be determined, and located such that
groundwater flow direction and hydraulic gradient may accurately be determined. The vertical extent monitoring
well shall be installed immediately downgradient of the source area of contamination, as best as can be
determined, with any drilling greater than a depth of 75 feet requiring authorization from the regional office
incident manager. Note, the vertical extent monitoring well must not connect aquifers.

• The analysis of representative soil samples collected during the construction of the monitoring wells. One soil
sample must be collected in the unsaturated zone and one in the smear/saturated zone from suspected worst-case
locations exhibiting visible contamination or elevated levels of volatile organic compounds based on field
screening techniques. Only the suspected most contaminated soil sample in each zone from each boring should be
submitted for laboratory analysis using the EPA 8015B TPH (or equivalent) appropriate for the fuel types
suspected in the release.
• The collection of groundwater samples from the new monitoring wells, analyzed by the appropriate method(s) for
the constituents relevant to the release.
• The collection of groundwater samples from any onsite water supply wells and any water supply wells located
adjacent to the site less than 250 feet from the source area of the release, analyzed by the appropriate method(s)
for the constituents relevant to the release. Sampling of more than 5 water supply wells will require approval of
the regional office incident manager.
• The survey of all monitoring wells and collection of potentiometric data for the completion of a potentiometric
surface / groundwater elevation and flow map.
• The completion of one aquifer slug test in a representative well to provide a calculation of hydraulic conductivity,
transmissivity, and linear groundwater velocity.
Because a release or discharge has been confirmed, a Licensed Geologist or a Professional Engineer,
certified by the State of North Carolina, is required to prepare and certify all reports submitted to the Department
in accordance with 15A NCAC 2L .0103(e) and 2L .0111(b).
Effective October 1, 2004, the Department of Environmental Quality requires that all work not
determined to be an emergency response or associated with risk assessment (i.e., the Limited Site Assessment
Report, per Title 15A NCAC 2L .0405) must be preapproved if State Trust Fund reimbursement is anticipated.
To comply with this requirement for a CSA, a completed Preapproval/Claim Authorization Form, encompassing
the required comprehensive assessment activities must be received in this office within 14 days of the date of
this letter.
However, as the Risk Assessment Report qualifies as an exempted scope of work, written preapproval is
not required to complete the activities described above, as documented under Task 2.610 in the 2017 Reasonable
Rate Document, Version 1/15/17. Upon completion of any eligible activities, you should submit your claim
promptly. Reimbursement funds are budgeted based on completed preapprovals, but delays in reimbursement
or even denial due to exceeding the statute of limitations on claiming eligible costs can result where claims are
not submitted immediately following work completion.
Please note that before you sell, transfer, or request a “No Further Action” determination for a property
that has not been remediated to below “unrestricted use” standards, you must file a Notice of Residual Petroleum
("Notice") with the Register of Deeds in the county where the property is located (NCGS 143B-279.9 and 143B-
279.11).
If you have any questions regarding trust fund eligibility or reimbursement from the Commercial Leaking
Petroleum Underground Storage Tank Cleanup Fund, please contact the UST Section Trust Fund Branch at (919)
707-8171. If you have any questions regarding the actions that must be taken or the rules mentioned in this letter,
please contact me at the address or telephone number listed below.

Sincerely,

James W. Brown
Hydrogeologist
Fayetteville Regional Office
UST Section, Division of Waste Management, NCDEQ

cc: Rae Brown – GRI (e-mail)

APPENDIX B
Well Construction Records and Subsurface Logs
WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only:
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018
1.Well Contractor Information:
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2.Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3.Well Use (check well use):
Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single) □Industrial/Commercial □Residential Water Supply (shared) □Irrigation □Wells > 100,000 GPDNon-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation □Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage □Experimental Technology □Subsidence Control □Geothermal (Closed Loop)□Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: Well ID#
5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient)
N W
6.Is(are) the well(s): □Permanent or □Temporary
7.Is this a repair to an existing well: □Yes or □No
If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wellsdrilled:
9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′)
10.Static water level below top of casing: (ft.) If water level is above casing, use “+”
11. Borehole diameter: (in.)
12. Well construction method:(i.e. auger, rotary, cable, direct push, etc.)
FOR WATER SUPPLY WELLS ONLY:
13a. Yield (gpm) Method of test:
13b. Disinfection type: Amount:
14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREENFROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS
22.Certification:
Signature of Certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23.Site diagram or additional well details:You may use the back of this page to provide additional well construction info (add 'See Over' in Remarks Box). You may also attach additional pages if necessary.
24.SUBMITTAL INSTRUCTIONS
Submit this GW-1 within 30 days of well completion per the following:
24a. For All Wells: Original form to Division of Water Resources (DWR), Information Processing Unit, 1617 MSC, Raleigh, NC 27699-1617
24b. For Injection Wells: Copy to DWR, Underground Injection Control (IUC) Program, 1636 MSC, Raleigh, NC 27699-1636
24c. For Water Supply and Open-Loop Geothermal Return Wells: Copy to the county environmental health department of the county where installed
24d. For Water Wells producing over 100,000 GPD: Copy to DWR, CCPCUA Permit Program, 1611 MSC, Raleigh, NC 27699-1611
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Moore's Citgo
Address 305 South Church Street, Kenly, NC 27542
Boring Number MW-2 Date Drilled
Sample Method Grab Drilling Method 6" Solid flight auger
Completion Details Well installed at completion to a total depth of 25 feet with a 15 foot screened interval
Driller Sam Bowers Log By J. Brooks
Lab Sample PIDDepthSampleInterval(ft)ppm LITHOLOGY
0 0' - 0.6' Concrete
0.6' - 3' Brown fine sandy silt; dry
2 MW-2-2'2 625
4 4 12

6 6 18
8 8 29
10 10 28

12 12 17
14 14 10

16 16 9

18 18 7
20 20 4

22 22 3

24 MW-2-24'24 71
26

28

30
32
34

36

38

40
14' - 25' Tan fine sandy clay; moist
08/16/22

5' - 8' Brown fine sand; moist

8' - 14' Brown fine sandy clay; moist

3' - 5' Gray fine sand; moist

Well set at 25 feet

Wet at 22 feet
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Moore's Citgo
Address 305 South Church Street, Kenly, NC 27542
Boring Number MW-3 Date Drilled
Sample Method Grab Drilling Method 6 "Solid flight auger
Completion Details Well installed at completion to a total depth of 25 feet with a 15 foot screened interval
Driller Sam Bowers Log By J. Brooks
Lab Sample PIDDepthSampleInterval(ft)ppm LITHOLOGY
0 0 - 0.6'; Concrete
0.6' - 3'; Brown fine sandy silt; dry
2 2 30
4 4 5

6 6 3
8 8 4
10 10 3

12 12 6
14 14 7

16 16 17

18 MW-3-18'18 42
20 20 23

22 22 4

24 MW-3-24'24 65
26

28

30
32
34

36

38

40
08/16/22
3' - 5'; Gray fine sand; moist

5' - 8'; Brown fine sand; moist

8' - 14'; Brown fine sandy clay; moist

14' - 25'; Tan fine sandy clay; moist

Wet at 22 feet

Well set at 25 feet
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Moore's Citgo
Address 305 South Church Street, Kenly, NC 27542
Boring Number MW-4 Date Drilled
Sample Method Grab Drilling Method Solid flight auger
Completion Details Well installed at completion to a total depth of 25 feet with a 15 foot screened interval
Driller Sam Bowers Log By J. Brooks
Lab Sample PIDDepthSampleInterval(ft)ppm LITHOLOGY
0 0 - 0.6'; Concrete
0.6' - 3'; Brown fine sandy silt; dry
2 2 55
4 4 14

6 6 43
8 8 22
10 10 30

12 12 6
14 14 9

16 16 63

18 18 281 18' - 25'; Tan fine silty clay; wet at 18 feet
20 MW-4-20'20 294

22 22 133

24 MW-4-24'24 20
26

28

30
32
34

36

38

40
12' - 18'; Tan fine sandy clay; moist
08/16/22
3' - 5'; Gray fine sand; moist

5' - 8'; Brown fine sand; moist

8' - 12'; Brown fine sandy clay; moist

Well set at 25 feet
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project Moore's Citgo
Address 305 South Church Street, Kenly, NC 27542
Boring Number TW-1 Date Drilled
Sample Method Grab Drilling Method 6.625"auger/4.5" Mud rotary
Completion Details
Driller Sam Bowers Log By J. Brooks
Lab Sample PIDDepthSampleInterval(ft)ppm LITHOLOGY
0
3
6
9
TW-1-10'
12
15

18
TW-1-20'
21
24

27
30
33

36
39
42

45
48
51

54
57
60

Well set at 46 feet

Well installed at completion to a depth of 46 feet with an outer casing of 30 feet and a screened interval of 5 feet
5 - 12' Gray fine sandy clay
17 - 25' Brown silt with coarse sand

12 - 17' Light brown clay with coarse sand

08/15-16/22
0 - 0.5' Concrete
0.5 - 3' Dark brown clay with sand
3 - 5' Black silt

25 - 30' Gray tight clay
30 - 46' Black/blue slate

APPENDIX C
Slug Test Analysis
0. 4. 8. 12. 16. 20.
0.01
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\MW-2.aqt
Date: 09/21/22 Time: 09:15:48
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Moore's Citgo
Project: 5285
Location: Kenly, NC
Test Well: MW-2
Test Date: 08/25/22
AQUIFER DATA
Saturated Thickness: 40.35 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (MW-2)
Initial Displacement: 1.75 ft Static Water Column Height: 20.25 ft
Total Well Penetration Depth: 20.25 ft Screen Length: 20. ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 2.175E-5 ft/min y0 = 0.5825 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 4.75 Test well (ft)
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 6.50 Test well (ft)
Total well depth (TWD)TWD 25.00 Test well (ft)
Top of Casing Elevation (TOC)TOC 99.08 Test well (ft)
Highest ground water elevation at site (HGWE)HGWE 94.64 All site wells (ft)
Deepest well depth elevation (DWDE)DWDE 54.29 Deepest well (ft)
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW (ft))H(o)1.75 Use 1.75
H: Static water column height H 20.25 TWD minus SDTW (ft)
Well #MW-2 Test well ID
7 b: Saturated thickness of aquifer b 40.35
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.10 Use 0.1
8 D: Casing length D 0.25 TWD minus SDTW minus screen length (ft)
L: Well screen length L 20.00 Screen length (ft)
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells(ft)
R(w): Well radius R(w)0.2500 1/2 auger outside diameter (ft)
R(sk): Well skin radius R(sk)0.2500 1/2 auger outside diameter (ft)
8/25/2022
AQTESOLV DATA ENTRY FORM
(For wells screened BELOW water table)
5285 Moore's Citgo
Kenly, NC
MW-2
File: 5285 AQTESOLV Data Entry.xlsx
Moore's Citgo
Well MW-2
Test Date 08/25/22
Initial DTW (ft) 4.75

Time Displacement
(min) (ft)
0.000 0.0000
0.017 -0.0010
0.033 0.0690
0.050 3.1980
0.067 1.2880
0.083 0.9150
0.100 1.1310
0.117 1.2900
0.133 1.2100
0.150 1.0620
0.167 0.9940
0.183 0.9650
0.200 0.9240
0.217 0.8850
0.233 0.8570
0.250 0.8360
0.267 0.8160
0.283 0.7970
0.300 0.7880
0.317 0.7670
0.333 0.7570
0.350 0.7570
0.367 0.7480
0.383 0.7390
0.400 0.7280
0.417 0.7180
0.433 0.7180
0.450 0.7080
0.467 0.7090
0.483 0.6990
0.500 0.6990
0.517 0.6880
0.533 0.6880
0.550 0.6890
0.567 0.6790
Time Displacement
(min) (ft)
0.583 0.6790
0.600 0.6780
0.617 0.6690
0.633 0.6690
0.650 0.6690
0.667 0.6680
0.683 0.6590
0.700 0.6600
0.717 0.6590
0.733 0.6590
0.750 0.6590
0.767 0.6590
0.783 0.6490
0.800 0.6500
0.817 0.6490
0.833 0.6490
0.850 0.6490
0.867 0.6490
0.883 0.6390
0.900 0.6390
0.917 0.6390
0.933 0.6390
0.950 0.6390
0.967 0.6290
0.983 0.6290
1.000 0.6300
1.017 0.6300
1.033 0.6290
1.050 0.6200
1.067 0.6190
1.083 0.6190
1.100 0.6180
1.117 0.6190
1.133 0.6190
1.150 0.6180
1.167 0.6190
1.183 0.6190
1.200 0.6190
1.217 0.6190
1.233 0.6090
1.250 0.6090
Time Displacement
(min) (ft)
1.267 0.6090
1.283 0.6090
1.300 0.6090
1.317 0.6080
1.333 0.6090
1.350 0.6080
1.367 0.6090
1.383 0.6090
1.400 0.6080
1.417 0.6080
1.433 0.6090
1.450 0.6000
1.467 0.6000
1.483 0.6000
1.500 0.5990
1.517 0.6000
1.533 0.5990
1.550 0.5990
1.567 0.5990
1.583 0.6000
1.600 0.5990
1.617 0.5900
1.633 0.5890
1.650 0.5880
1.667 0.5890
1.683 0.5890
1.700 0.5890
1.717 0.5880
1.733 0.5900
1.750 0.5890
1.767 0.5890
1.783 0.5890
1.800 0.5880
1.817 0.5890
1.833 0.5880
1.850 0.5890
1.867 0.5900
1.883 0.5790
1.900 0.5790
1.917 0.5790
1.933 0.5800
Time Displacement
(min) (ft)
1.950 0.5800
1.967 0.5800
1.983 0.5790
2.000 0.5800
2.017 0.5800
2.033 0.5810
2.050 0.5790
2.067 0.5800
2.083 0.5800
2.100 0.5800
2.117 0.5790
2.133 0.5790
2.150 0.5800
2.167 0.5690
2.183 0.5700
2.200 0.5700
2.217 0.5700
2.233 0.5700
2.250 0.5700
2.267 0.5700
2.283 0.5710
2.300 0.5700
2.317 0.5700
2.333 0.5700
2.350 0.5700
2.367 0.5700
2.383 0.5700
2.400 0.5690
2.417 0.5700
2.433 0.5600
2.450 0.5700
2.467 0.5600
2.483 0.5580
2.500 0.5600
2.517 0.5600
2.533 0.5610
2.550 0.5600
2.567 0.5600
2.583 0.5600
2.600 0.5610
2.617 0.5610
Time Displacement
(min) (ft)
2.633 0.5590
2.650 0.5600
2.667 0.5590
2.683 0.5600
2.700 0.5600
2.717 0.5590
2.733 0.5600
2.750 0.5600
2.767 0.5600
2.783 0.5600
2.800 0.5490
2.817 0.5500
2.833 0.5500
2.850 0.5490
2.867 0.5500
2.883 0.5490
2.900 0.5490
2.917 0.5500
2.933 0.5500
2.950 0.5500
2.967 0.5500
2.983 0.5500
3.000 0.5500
3.017 0.5490
3.033 0.5500
3.050 0.5500
3.067 0.5500
3.083 0.5500
3.100 0.5490
3.117 0.5500
3.133 0.5490
3.150 0.5390
3.167 0.5400
3.183 0.5400
3.200 0.5400
3.217 0.5400
3.233 0.5390
3.250 0.5390
3.267 0.5390
3.283 0.5390
3.300 0.5390
Time Displacement
(min) (ft)
3.317 0.5400
3.333 0.5390
3.350 0.5400
3.367 0.5390
3.383 0.5400
3.400 0.5400
3.417 0.5390
3.433 0.5390
3.450 0.5390
3.467 0.5390
3.483 0.5400
3.500 0.5400
3.517 0.5390
3.533 0.5400
3.550 0.5390
3.567 0.5390
3.583 0.5300
3.600 0.5300
3.617 0.5300
3.633 0.5290
3.650 0.5300
3.667 0.5300
3.683 0.5310
3.700 0.5290
3.717 0.5300
3.733 0.5310
3.750 0.5300
3.767 0.5310
3.783 0.5310
3.800 0.5310
3.817 0.5310
3.833 0.5300
3.850 0.5300
3.867 0.5310
3.883 0.5300
3.900 0.5310
3.917 0.5300
3.933 0.5300
3.950 0.5310
3.967 0.5310
3.983 0.5300
Time Displacement
(min) (ft)
4.000 0.5310
4.017 0.5310
4.033 0.5310
4.050 0.5300
4.067 0.5300
4.083 0.5300
4.100 0.5300
4.117 0.5300
4.133 0.5290
4.150 0.5290
4.167 0.5310
4.183 0.5300
4.200 0.5220
4.217 0.5300
4.233 0.5200
4.250 0.5200
4.267 0.5200
4.283 0.5200
4.300 0.5200
4.317 0.5200
4.333 0.5200
4.350 0.5200
4.367 0.5200
4.383 0.5200
4.400 0.5200
4.417 0.5210
4.433 0.5200
4.450 0.5200
4.467 0.5200
4.483 0.5200
4.500 0.5190
4.517 0.5210
4.533 0.5210
4.550 0.5200
4.567 0.5190
4.583 0.5200
4.600 0.5200
4.617 0.5200
4.633 0.5200
4.650 0.5200
4.667 0.5100
Time Displacement
(min) (ft)
4.683 0.5110
4.700 0.5110
4.717 0.5090
4.733 0.5100
4.750 0.5100
4.767 0.5110
4.783 0.5100
4.800 0.5100
4.817 0.5110
4.833 0.5100
4.850 0.5100
4.867 0.5100
4.883 0.5110
4.900 0.5100
4.917 0.5100
4.933 0.5090
4.950 0.5100
4.967 0.5100
4.983 0.5100
5.000 0.5100
5.017 0.5100
5.033 0.5110
5.050 0.5100
5.067 0.5090
5.083 0.5100
5.100 0.5100
5.117 0.5100
5.133 0.5100
5.150 0.5110
5.167 0.5000
5.183 0.5000
5.200 0.5010
5.217 0.5000
5.233 0.5000
5.250 0.4990
5.267 0.4990
5.283 0.5000
5.300 0.5000
5.317 0.5000
5.333 0.5000
5.350 0.5000
Time Displacement
(min) (ft)
5.367 0.4990
5.383 0.5000
5.400 0.5000
5.417 0.5000
5.433 0.5000
5.450 0.5010
5.467 0.5000
5.483 0.5000
5.500 0.4990
5.517 0.5000
5.533 0.5000
5.550 0.5000
5.567 0.4990
5.583 0.4990
5.600 0.5000
5.617 0.5000
5.633 0.5000
5.650 0.4890
5.667 0.5000
5.683 0.4890
5.700 0.5000
5.717 0.4900
5.733 0.4910
5.750 0.4900
5.767 0.4910
5.783 0.4890
5.800 0.4900
5.817 0.4900
5.833 0.4900
5.850 0.4900
5.867 0.4890
5.883 0.4900
5.900 0.4900
5.917 0.4900
5.933 0.4900
5.950 0.4900
5.967 0.4890
5.983 0.4900
6.000 0.4900
6.017 0.4890
6.033 0.4900
Time Displacement
(min) (ft)
6.050 0.4900
6.067 0.4910
6.083 0.4890
6.100 0.4900
6.117 0.4900
6.133 0.4890
6.150 0.4900
6.167 0.4900
6.183 0.4900
6.200 0.4800
6.217 0.4800
6.233 0.4900
6.250 0.4800
6.267 0.4800
6.283 0.4800
6.300 0.4900
6.317 0.4790
6.333 0.5290
6.350 0.4890
6.367 0.4790
6.383 0.4800
6.400 0.4900
6.417 0.5000
6.433 0.5080
6.450 0.4790
6.467 0.4800
6.483 0.4800
6.500 0.4900
6.517 0.4800
6.533 0.5000
6.550 0.5000
6.567 0.4600
6.583 0.4910
6.600 0.4900
6.617 0.4900
6.633 0.4800
6.650 0.4900
6.667 0.4800
6.683 0.4700
6.700 0.5000
6.717 0.4800
Time Displacement
(min) (ft)
6.733 0.4780
6.750 0.4800
6.767 0.4790
6.783 0.4800
6.800 0.4710
6.817 0.4710
6.833 0.4800
6.850 0.4790
6.867 0.4800
6.883 0.4800
6.900 0.4790
6.917 0.4710
6.933 0.4700
6.950 0.4700
6.967 0.4700
6.983 0.4700
7.000 0.4700
7.017 0.4710
7.033 0.4710
7.050 0.4700
7.067 0.4710
7.083 0.4710
7.100 0.4710
7.117 0.4700
7.133 0.4710
7.150 0.4700
7.167 0.4710
7.183 0.4710
7.200 0.4710
7.217 0.4710
7.233 0.4700
7.250 0.4700
7.267 0.4700
7.283 0.4700
7.300 0.4700
7.317 0.4700
7.333 0.4600
7.350 0.4600
7.367 0.4700
7.383 0.4610
7.400 0.4700
Time Displacement
(min) (ft)
7.417 0.4600
7.433 0.4600
7.450 0.4600
7.467 0.4600
7.483 0.4600
7.500 0.4600
7.517 0.4610
7.533 0.4600
7.550 0.4600
7.567 0.4600
7.583 0.4590
7.600 0.4590
7.617 0.4600
7.633 0.4610
7.650 0.4610
7.667 0.4580
7.683 0.4600
7.700 0.4610
7.717 0.4600
7.733 0.4600
7.750 0.4600
7.767 0.4600
7.783 0.4610
7.800 0.4610
7.817 0.4600
7.833 0.4600
7.850 0.4600
7.867 0.4600
7.883 0.4600
7.900 0.4600
7.917 0.4600
7.933 0.4610
7.950 0.4600
7.967 0.4610
7.983 0.4600
8.000 0.4510
8.017 0.4500
8.033 0.4520
8.050 0.4500
8.067 0.4500
8.083 0.4510
Time Displacement
(min) (ft)
8.100 0.4510
8.117 0.4500
8.133 0.4510
8.150 0.4500
8.167 0.4510
8.183 0.4500
8.200 0.4510
8.217 0.4510
8.233 0.4510
8.250 0.4510
8.267 0.4510
8.283 0.4490
8.300 0.4490
8.317 0.4510
8.333 0.4500
8.350 0.4500
8.367 0.4510
8.383 0.4510
8.400 0.4510
8.417 0.4500
8.433 0.4490
8.450 0.4500
8.467 0.4510
8.483 0.4510
8.500 0.4510
8.517 0.4520
8.533 0.4500
8.550 0.4510
8.567 0.4500
8.583 0.4400
8.600 0.4500
8.617 0.4410
8.633 0.4410
8.650 0.4410
8.667 0.4400
8.683 0.4410
8.700 0.4400
8.717 0.4400
8.733 0.4400
8.750 0.4400
8.767 0.4410
Time Displacement
(min) (ft)
8.783 0.4420
8.800 0.4410
8.817 0.4420
8.833 0.4410
8.850 0.4410
8.867 0.4410
8.883 0.4410
8.900 0.4410
8.917 0.4400
8.933 0.4410
8.950 0.4400
8.967 0.4400
8.983 0.4390
9.000 0.4400
9.017 0.4390
9.033 0.4410
9.050 0.4400
9.067 0.4400
9.083 0.4400
9.100 0.4410
9.117 0.4410
9.133 0.4400
9.150 0.4400
9.167 0.4400
9.183 0.4420
9.200 0.4400
9.217 0.4400
9.233 0.4410
9.250 0.4400
9.267 0.4410
9.283 0.4400
9.300 0.4300
9.317 0.4400
9.333 0.4300
9.350 0.4310
9.367 0.4300
9.383 0.4300
9.400 0.4300
9.417 0.4300
9.433 0.4290
9.450 0.4300
Time Displacement
(min) (ft)
9.467 0.4310
9.483 0.4310
9.500 0.4310
9.517 0.4300
9.533 0.4300
9.550 0.4320
9.567 0.4290
9.583 0.4300
9.600 0.4300
9.617 0.4310
9.633 0.4290
9.650 0.4310
9.667 0.4300
9.683 0.4300
9.700 0.4310
9.717 0.4300
9.733 0.4310
9.750 0.4300
9.767 0.4300
9.783 0.4300
9.800 0.4300
9.817 0.4300
9.833 0.4310
9.850 0.4300
9.867 0.4300
9.883 0.4300
9.900 0.4290
9.917 0.4300
9.933 0.4300
9.950 0.4300
9.967 0.4310
9.983 0.4200
10.000 0.4200
10.017 0.4210
10.033 0.4200
10.050 0.4200
10.067 0.4210
10.083 0.4210
10.100 0.4210
10.117 0.4210
10.133 0.4210
Time Displacement
(min) (ft)
10.150 0.4200
10.167 0.4200
10.183 0.4220
10.200 0.4210
10.217 0.4190
10.233 0.4210
10.250 0.4200
10.267 0.4210
10.283 0.4210
10.300 0.4210
10.317 0.4220
10.333 0.4200
10.350 0.4210
10.367 0.4210
10.383 0.4210
10.400 0.4200
10.417 0.4210
10.433 0.4210
10.450 0.4200
10.467 0.4210
10.483 0.4210
10.500 0.4200
10.517 0.4200
10.533 0.4200
10.550 0.4220
10.567 0.4210
10.583 0.4200
10.600 0.4200
10.617 0.4210
10.633 0.4210
10.650 0.4210
10.667 0.4210
10.683 0.4110
10.700 0.4110
10.717 0.4120
10.733 0.4120
10.750 0.4110
10.767 0.4120
10.783 0.4120
10.800 0.4120
10.817 0.4120
Time Displacement
(min) (ft)
10.833 0.4110
10.850 0.4120
10.867 0.4110
10.883 0.4120
10.900 0.4110
10.917 0.4110
10.933 0.4120
10.950 0.4120
10.967 0.4120
10.983 0.4120
11.000 0.4120
11.017 0.4110
11.033 0.4120
11.050 0.4120
11.067 0.4120
11.083 0.4130
11.100 0.4120
11.117 0.4120
11.133 0.4120
11.150 0.4110
11.167 0.4120
11.183 0.4130
11.200 0.4120
11.217 0.4120
11.233 0.4120
11.250 0.4110
11.267 0.4120
11.283 0.4110
11.300 0.4110
11.317 0.4120
11.333 0.4110
11.350 0.4120
11.367 0.4110
11.383 0.4120
11.400 0.4030
11.417 0.4110
11.433 0.4020
11.450 0.4020
11.467 0.4020
11.483 0.4010
11.500 0.4020
Time Displacement
(min) (ft)
11.517 0.4030
11.533 0.4010
11.550 0.4020
11.567 0.4020
11.583 0.4020
11.600 0.4010
11.617 0.4020
11.633 0.4000
11.650 0.4010
11.667 0.4010
11.683 0.4010
11.700 0.4020
11.717 0.4000
11.733 0.4020
11.750 0.4020
11.767 0.4010
11.783 0.4020
11.800 0.4020
11.817 0.4020
11.833 0.4010
11.850 0.4010
11.867 0.4020
11.883 0.4020
11.900 0.4010
11.917 0.4020
11.933 0.4020
11.950 0.4020
11.967 0.4020
11.983 0.4010
12.000 0.4020
12.017 0.4020
12.033 0.4020
12.050 0.4010
12.067 0.4020
12.083 0.4010
12.100 0.4010
12.117 0.4030
12.133 0.4000
12.150 0.4010
12.167 0.4010
12.183 0.4010
Time Displacement
(min) (ft)
12.200 0.3910
12.217 0.3920
12.233 0.4020
12.250 0.3910
12.267 0.3910
12.283 0.3920
12.300 0.3910
12.317 0.3910
12.333 0.3920
12.350 0.3910
12.367 0.3910
12.383 0.3920
12.400 0.3910
12.417 0.3920
12.433 0.3910
12.450 0.3920
12.467 0.3920
12.483 0.3920
12.500 0.3920
12.517 0.3910
12.533 0.3920
12.550 0.3910
12.567 0.3920
12.583 0.3910
12.600 0.3910
12.617 0.3920
12.633 0.3920
12.650 0.3920
12.667 0.3920
12.683 0.3910
12.700 0.3920
12.717 0.3900
12.733 0.3920
12.750 0.3920
12.767 0.3920
12.783 0.3910
12.800 0.3910
12.817 0.3910
12.833 0.3920
12.850 0.3910
12.867 0.3920
Time Displacement
(min) (ft)
12.883 0.3920
12.900 0.3920
12.917 0.3920
12.933 0.3920
12.950 0.3920
12.967 0.3910
12.983 0.3920
13.000 0.3920
13.017 0.3820
13.033 0.3920
13.050 0.3810
13.067 0.3910
13.083 0.3820
13.100 0.3910
13.117 0.3820
13.133 0.3820
13.150 0.3810
13.167 0.3820
13.183 0.3820
13.200 0.3830
13.217 0.3810
13.233 0.3810
13.250 0.3810
13.267 0.3820
13.283 0.3810
13.300 0.3810
13.317 0.3810
13.333 0.3810
13.350 0.3820
13.367 0.3810
13.383 0.3820
13.400 0.3810
13.417 0.3800
13.433 0.3810
13.450 0.3800
13.467 0.3810
13.483 0.3810
13.500 0.3820
13.517 0.3810
13.533 0.3810
13.550 0.3810
Time Displacement
(min) (ft)
13.567 0.3810
13.583 0.3800
13.600 0.3810
13.617 0.3810
13.633 0.3810
13.650 0.3810
13.667 0.3810
13.683 0.3810
13.700 0.3810
13.717 0.3820
13.733 0.3810
13.750 0.3810
13.767 0.3800
13.783 0.3810
13.800 0.3800
13.817 0.3810
13.833 0.3810
13.850 0.3810
13.867 0.3810
13.883 0.3810
13.900 0.3710
13.917 0.3710
13.933 0.3810
13.950 0.3810
13.967 0.3710
13.983 0.3710
14.000 0.3710
14.017 0.3700
14.033 0.3710
14.050 0.3700
14.067 0.3700
14.083 0.3710
14.100 0.3710
14.117 0.3710
14.133 0.3710
14.150 0.3700
14.167 0.3720
14.183 0.3710
14.200 0.3710
14.217 0.3710
14.233 0.3720
Time Displacement
(min) (ft)
14.250 0.3710
14.267 0.3710
14.283 0.3700
14.300 0.3710
14.317 0.3710
14.333 0.3710
14.350 0.3700
14.367 0.3710
14.383 0.3720
14.400 0.3710
14.417 0.3710
14.433 0.3710
14.450 0.3720
14.467 0.3710
14.483 0.3710
14.500 0.3700
14.517 0.3710
14.533 0.3720
14.550 0.3720
14.567 0.3710
14.583 0.3720
14.600 0.3700
14.617 0.3720
14.633 0.3710
14.650 0.3710
14.667 0.3710
14.683 0.3710
14.700 0.3610
14.717 0.3710
14.733 0.3710
14.750 0.3710
14.767 0.3610
14.783 0.3710
14.800 0.3600
14.817 0.3610
14.833 0.3610
14.850 0.3610
14.867 0.3620
14.883 0.3610
14.900 0.3610
14.917 0.3610
Time Displacement
(min) (ft)
14.933 0.3610
14.950 0.3600
14.967 0.3600
14.983 0.3600
15.000 0.3610
15.017 0.3610
15.033 0.3610
15.050 0.3610
15.067 0.3610
15.083 0.3610
15.100 0.3590
15.117 0.3610
15.133 0.3610
15.150 0.3610
15.167 0.3600
15.183 0.3610
15.200 0.3610
15.217 0.3610
15.233 0.3600
15.250 0.3610
15.267 0.3600
15.283 0.3600
15.300 0.3610
15.317 0.3610
15.333 0.3600
15.350 0.3610
15.367 0.3610
15.383 0.3610
15.400 0.3600
15.417 0.3610
15.433 0.3600
15.450 0.3610
15.467 0.3620
15.483 0.3600
15.500 0.3600
15.517 0.3600
15.533 0.3610
15.550 0.3610
15.567 0.3610
15.583 0.3610
15.600 0.3600
Time Displacement
(min) (ft)
15.617 0.3600
15.633 0.3620
15.650 0.3600
15.667 0.3600
15.683 0.3500
15.700 0.3600
15.717 0.3600
15.733 0.3600
15.750 0.3510
15.767 0.3610
15.783 0.3610
15.800 0.3500
15.817 0.3510
15.833 0.3510
15.850 0.3510
15.867 0.3500
15.883 0.3510
15.900 0.3500
15.917 0.3510
15.933 0.3500
15.950 0.3500
15.967 0.3510
15.983 0.3490
16.000 0.3510
16.017 0.3500
16.033 0.3490
16.050 0.3490
16.067 0.3510
16.083 0.3500
16.100 0.3500
16.117 0.3500
16.133 0.3500
16.150 0.3500
16.167 0.3500
16.183 0.3500
16.200 0.3510
16.217 0.3490
16.233 0.3500
16.250 0.3500
16.267 0.3510
16.283 0.3490
Time Displacement
(min) (ft)
16.300 0.3490
16.317 0.3500
16.333 0.3490
16.350 0.3500
16.367 0.3500
16.383 0.3500
16.400 0.3500
16.417 0.3500
16.433 0.3500
16.450 0.3490
16.467 0.3500
16.483 0.3500
16.500 0.3500
16.517 0.3500
16.533 0.3500
16.550 0.3500
16.567 0.3490
16.583 0.3490
16.600 0.3500
16.617 0.3500
16.633 0.3500
16.650 0.3500
16.667 0.3490
16.683 0.3500
16.700 0.3490
16.717 0.3500
16.733 0.3490
16.750 0.3500
16.767 0.3500
16.783 0.3410
16.800 0.3410
16.817 0.3400
16.833 0.3400
16.850 0.3400
16.867 0.3400
16.883 0.3400
16.900 0.3400
16.917 0.3400
16.933 0.3800
16.950 0.3490
16.967 0.3400
Time Displacement
(min) (ft)
16.983 0.3490
17.000 0.3410

0. 0.6 1.2 1.8 2.4 3.
0.001
0.01
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\TW-1.aqt
Date: 09/21/22 Time: 09:12:48
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: Moore's Citgo
Project: 5285
Location: Kenly, NC
Test Well: TW-1
Test Date: 08/25/22
AQUIFER DATA
Saturated Thickness: 40.35 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (TW-1)
Initial Displacement: 1.75 ft Static Water Column Height: 40.01 ft
Total Well Penetration Depth: 40.01 ft Screen Length: 5. ft
Casing Radius: 0.085 ft Well Radius: 0.1875 ft
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.01795 ft/min y0 = 2.16 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 5.99 Test well (ft)
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 7.74 Test well (ft)
Total well depth (TWD)TWD 46.00 Test well (ft)
Top of Casing Elevation (TOC)TOC 100.29 Test well (ft)
Highest ground water elevation at site (HGWE)HGWE 94.64 All site wells (ft)
Deepest well depth elevation (DWDE)DWDE 54.29 Deepest well (ft)
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW (ft))H(o)1.75 Use 1.75
H: Static water column height H 40.01 TWD minus SDTW (ft)
Well #TW-1 Test well ID
7 b: Saturated thickness of aquifer b 40.35
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.10 Use 0.1
8 D: Casing length D 35.01 TWD minus SDTW minus screen length (ft)
L: Well screen length L 5.00 Screen length (ft)
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells(ft)
R(w): Well radius R(w)0.1875 1/2 auger outside diameter (ft)
R(sk): Well skin radius R(sk)0.1875 1/2 auger outside diameter (ft)
8/25/2022
AQTESOLV DATA ENTRY FORM
(For wells screened BELOW water table)
5285 Moore's Citgo
Kenly, NC
TW-1
File: 5285 AQTESOLV Data Entry
Moore's Citgo
Well TW-1
Test Date 08/25/22
Initial DTW (ft) 5.99

Time Displacement
(min) (ft)
0 0
0.017 0.029
0.033 1.654
0.050 1.516
0.067 1.388
0.083 1.279
0.100 1.182
0.117 1.082
0.133 0.994
0.150 0.916
0.167 0.837
0.183 0.769
0.200 0.65
0.217 0.65
0.233 0.59
0.250 0.531
0.267 0.482
0.283 0.443
0.300 0.395
0.317 0.343
0.333 0.324
0.350 0.286
0.367 0.256
0.383 0.226
0.400 0.216
0.417 0.197
0.433 0.178
0.450 0.156
0.467 0.138
0.483 0.128
0.500 0.119
0.517 0.108
0.533 0.088
0.550 0.089
0.567 0.08
Time Displacement
(min) (ft)
0.583 0.069
0.600 0.07
0.617 0.06
0.633 0.06
0.650 0.049
0.667 0.05
0.683 0.049
0.700 0.04
0.717 0.04
0.733 0.039
0.750 0.039
0.767 0.029
0.783 0.03
0.800 0.03
0.817 0.03
0.833 0.03
0.850 0.03
0.867 0.02
0.883 0.021
0.900 0.02
0.917 0.021
0.933 0.02
0.950 0.019
0.967 0.021
0.983 0.021
1.000 0.021
1.017 0.021
1.033 0.021
1.050 0.022
1.067 0.021
1.083 0.022
1.100 0.021
1.117 0.021
1.133 0.022
1.150 0.021
1.167 0.021
1.183 0.011
1.200 0.021
1.217 0.021
1.233 0.02
1.250 0.02
Time Displacement
(min) (ft)
1.267 0.02
1.283 0.021
1.300 0.022
1.317 0.021
1.333 0.021
1.350 0.021
1.367 0.01
1.383 0.011
1.400 0.021
1.417 0.01
1.433 0.021
1.450 0.011
1.467 0.011
1.483 0.01
1.500 0.011
1.517 0.012
1.533 0.011
1.550 0.011
1.567 0.011
1.583 0.021
1.600 0.021
1.617 0.021
1.633 0.021
1.650 0.022
1.667 0.021
1.683 0.021
1.700 0.02
1.717 0.021
1.733 0.021
1.750 0.021
1.767 0.021
1.783 0.021
1.800 0.021
1.817 0.022
1.833 0.021
1.850 0.021
1.867 0.021
1.883 0.021
1.900 0.012
1.917 0.011
1.933 0.011
Time Displacement
(min) (ft)
1.950 0.011
1.967 0.011
1.983 0.012
2.000 0.011
2.017 0.001
2.033 0.001
2.050 0.001
2.067 -0.008
2.083 0
2.100 0.001
2.117 0.002
2.133 0.003
2.150 0.001
2.167 0.011
2.183 0.011
2.200 0.011
2.217 0.011
2.233 0.011
2.250 0.012
2.267 0.011
2.283 0.011
2.300 0.011
2.317 0.021
2.333 0.011
2.350 0.011
2.367 0.021
2.383 0.011
2.400 0.012
2.417 0.01
2.433 0.021
2.450 0.011
2.467 0.012
2.483 0.012
2.500 0.012

APPENDIX D
Laboratory Analytical Reports

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

9/8/2022
Geological Resources, Inc. Rae Brown
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-238-0011 Client Project Description: Moore's Citgo
GRI #5285
Dear Rae Brown:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/26/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 33
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-238-0011
Page 2 of 33
Report Number:
Sample Summary Table
Client Project Description:
22-238-0011
Moore's Citgo
GRI #5285
Lab No Client Sample ID Matrix Date Collected Date Received
08/25/2022 10:15Aqueous 98069 Trip Blank 08/26/2022 09:30
08/25/2022 11:57Aqueous 98070 MW-2 08/26/2022 09:30
08/25/2022 10:46Aqueous 98071 TW-1 08/26/2022 09:30
Page 3 of 33
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-238-0011
Report Limit
Project:Moore's Citgo
V 98070MW-2
0.021 09/07/2022 15:506010DLeadmg/L 0.002
125 09/06/2022 09:366200BAcetoneµg/L 18.0
401 09/06/2022 09:366200BBenzeneµg/L 1.80
3.88 09/06/2022 09:096200Bn-Butylbenzene µg/L 0.180
3.72 09/06/2022 09:096200Bsec-Butyl benzene µg/L 0.200
51.4 09/06/2022 09:096200BEthylbenzeneµg/L 0.170
23.5 09/06/2022 09:096200BIsopropylbenzeneµg/L 0.180
3.48 09/06/2022 09:096200B4-Isopropyl toluene µg/L 0.089
451 09/06/2022 09:366200BMethyl tert-butyl ether (MTBE)µg/L 1.40
27.6 09/06/2022 09:096200BNaphthaleneµg/L 0.470
30.4 09/06/2022 09:096200Bn-Propylbenzene µg/L 0.190
372 09/06/2022 09:366200Btert-Butyl Alcohol (TBA)µg/L 16.0
904 09/06/2022 09:366200Btert-Amyl Alcohol (TAA)µg/L 19.0
J7.10 09/06/2022 09:096200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
40.6 09/06/2022 09:096200BTolueneµg/L 0.220
10.1 09/06/2022 09:096200B1,2,4-Trimethylbenzene µg/L 0.190
6.33 09/06/2022 09:096200B1,3,5-Trimethylbenzene µg/L 0.180
5.53 09/06/2022 09:096200Bo-Xylene µg/L 0.210
61.3 09/06/2022 09:096200Bm,p-Xylene µg/L 0.420
66.8 09/06/2022 09:096200BXylene (Total)µg/L 0.210
1240 08/30/2022 09:15CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 23.0
159 08/29/2022 11:49CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
341 08/29/2022 11:49CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
1680 08/30/2022 09:15MADEP-VPH Aliphatic C5-C8 µg/L 23.0
618 08/29/2022 11:49MADEP-VPH Aliphatic C9-C12 µg/L 25.8
341 08/29/2022 11:49MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 98071TW-1
0.010 09/07/2022 15:546010DLeadmg/L 0.002
1.13 09/06/2022 08:516200BBenzeneµg/L 0.180
3.55 09/06/2022 08:516200BChloroformµg/L 0.220
0.941 09/06/2022 08:516200BEthylbenzeneµg/L 0.170
J0.284 09/06/2022 08:516200BIsopropylbenzeneµg/L 0.180
J0.876 09/06/2022 08:516200BMethyl tert-butyl ether (MTBE)µg/L 0.140
J0.656 09/06/2022 08:516200BNaphthaleneµg/L 0.470
J0.376 09/06/2022 08:516200Bn-Propylbenzene µg/L 0.190
1.62 09/06/2022 08:516200BTolueneµg/L 0.220
Page 4 of 33
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-238-0011
Report Limit
Project:Moore's Citgo
V 98071TW-1
1.89 09/06/2022 08:516200B1,2,4-Trimethylbenzene µg/L 0.190
0.774 09/06/2022 08:516200B1,3,5-Trimethylbenzene µg/L 0.180
0.954 09/06/2022 08:516200Bo-Xylene µg/L 0.210
4.57 09/06/2022 08:516200Bm,p-Xylene µg/L 0.420
5.52 09/06/2022 08:516200BXylene (Total)µg/L 0.210
J45.5 08/29/2022 11:25CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J48.2 08/29/2022 11:25MADEP-VPH Aliphatic C5-C8 µg/L 11.5
J30.3 08/29/2022 11:25MADEP-VPH Aliphatic C9-C12 µg/L 25.8
Page 5 of 33

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Moore's Citgo Lab Report Number: 22-238-0011
Date: 9/8/2022
Volatile Organic Compounds - GC/MS Method 6200B Analyte: tert-Amyl alcohol QC Batch No: V23560/V23556
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 6 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
98069 Matrix:
8/25/2022 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.500Benzene 1 09/06/22 03:44 V23560ENM
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/06/22 03:44 V23560ENM
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/06/22 03:44 V23560ENM
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/06/22 03:44 V23560ENM
<1.50 µg/L 1.50 5.00Bromoform 1 09/06/22 03:44 V23560ENM
<0.280 µg/L 0.280 1.00Bromomethane 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/06/22 03:44 V23560ENM
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 09/06/22 03:44 V23560ENM
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/06/22 03:44 V23560ENM
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/06/22 03:44 V23560ENM
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/06/22 03:44 V23560ENM
<0.430 µg/L 0.430 1.00Chloroethane 1 09/06/22 03:44 V23560ENM
<0.220 µg/L 0.220 0.500Chloroform 1 09/06/22 03:44 V23560ENM
<0.220 µg/L 0.220 0.500
Chloromethane 1 09/06/22 03:44 V23560ENM
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/06/22 03:44 V23560ENM
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/06/22 03:44 V23560ENM
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/06/22 03:44 V23560ENM
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/06/22 03:44 V23560ENM
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 09/06/22 03:44 V23560ENM
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/06/22 03:44 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
98069 Matrix:
8/25/2022 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/06/22 03:44 V23560ENM
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/06/22 03:44 V23560ENM
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/06/22 03:44 V23560ENM
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/06/22 03:44 V23560ENM
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/06/22 03:44 V23560ENM
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/06/22 03:44 V23560ENM
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/06/22 03:44 V23560ENM
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 09/06/22 03:44 V23560ENM
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 09/06/22 03:44 V23560ENM
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/06/22 03:44 V23560ENM
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/06/22 03:44 V23560ENM
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/06/22 03:44 V23560ENM
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/06/22 03:44 V23560ENM
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/06/22 03:44 V23560ENM
<42.0 µg/L 42.0 200
Ethanol 1 09/06/22 03:44 V23560ENM
<0.170 µg/L 0.170 0.500Ethylbenzene 1 09/06/22 03:44 V23560ENM
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/06/22 03:44 V23560ENM
<0.380 µg/L 0.380 1.002-Hexanone 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 09/06/22 03:44 V23560ENM
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/06/22 03:44 V23560ENM
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/06/22 03:44 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
98069 Matrix:
8/25/2022 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/06/22 03:44 V23560ENM
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/06/22 03:44 V23560ENM
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/06/22 03:44 V23560ENM
<0.470 µg/L 0.470 1.00Naphthalene 1 09/06/22 03:44 V23560ENM
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 09/06/22 03:44 V23560ENM
<0.220 µg/L 0.220 0.500Styrene 1 09/06/22 03:44 V23560ENM
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/06/22 03:44 V23560ENM
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/06/22 03:44 V23560ENM
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 09/06/22 03:44 V23560ENM
<0.220 µg/L 0.220 0.500Toluene 1 09/06/22 03:44 V23560ENM
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/06/22 03:44 V23560ENM
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/06/22 03:44 V23560ENM
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/06/22 03:44 V23560ENM
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 09/06/22 03:44 V23560ENM
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/06/22 03:44 V23560ENM
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/06/22 03:44 V23560ENM
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/06/22 03:44 V23560ENM
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/06/22 03:44 V23560ENM
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/06/22 03:44 V23560ENM
<0.210 µg/L 0.210 0.500o-Xylene 1 09/06/22 03:44 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
98069 Matrix:
8/25/2022 10:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 09/06/22 03:44 V23560ENM
<0.21 µg/L 0.210 0.500Xylene (Total)1 09/06/22 03:44 V23560
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%09/06/22 03:441 ENM V23560
Surrogate: Dibromofluoromethane 94.2 Limits: 70-130%09/06/22 03:441 ENM V23560
Surrogate: 1,2-Dichloroethane - d4 95.4 Limits: 70-130%09/06/22 03:441 ENM V23560
Surrogate: Toluene-d8 99.8 Limits: 70-130%09/06/22 03:441 ENM V23560
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:MW-2
98070 Matrix:
8/25/2022 11:57
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 09/06/22 09:36 6200BENM
0.021 mg/L 0.002 0.006Lead 1 09/07/22 15:50 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:MW-2
98070 Matrix:
8/25/2022 11:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
125 µg/L 18.0 100Acetone 10 09/06/22 09:36 V23560ENM
401 µg/L 1.80 5.00Benzene 10 09/06/22 09:36 V23560ENM
<2.10 µg/L 2.10 5.00Bromobenzene 10 09/06/22 09:36 V23560ENM
<4.20 µg/L 4.20 10.0Bromochloromethane 10 09/06/22 09:36 V23560ENM
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 09/06/22 09:36 V23560ENM
<15.0 µg/L 15.0 50.0Bromoform 10 09/06/22 09:36 V23560ENM
<2.80 µg/L 2.80 10.0Bromomethane 10 09/06/22 09:36 V23560ENM
3.88 µg/L 0.180 0.500n-Butylbenzene 1 09/06/22 09:09 V23560ENM
3.72 µg/L 0.200 0.500
sec-Butyl benzene 1 09/06/22 09:09 V23560ENM
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/06/22 09:09 V23560ENM
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 09/06/22 09:36 V23560ENM
<1.90 µg/L 1.90 5.00Chlorobenzene 10 09/06/22 09:36 V23560ENM
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 09/06/22 09:36 V23560ENM
<4.30 µg/L 4.30 10.0Chloroethane 10 09/06/22 09:36 V23560ENM
<2.20 µg/L 2.20 5.00Chloroform 10 09/06/22 09:36 V23560ENM
<2.20 µg/L 2.20 5.00
Chloromethane 10 09/06/22 09:36 V23560ENM
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 09/06/22 09:36 V23560ENM
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 09/06/22 09:36 V23560ENM
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 09/06/22 09:36 V23560ENM
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 09/06/22 09:36 V23560ENM
<2.30 µg/L 2.30 5.00Dibromomethane 10 09/06/22 09:36 V23560ENM
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 09/06/22 09:36 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:MW-2
98070 Matrix:
8/25/2022 11:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 09/06/22 09:36 V23560ENM
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 09/06/22 09:36 V23560ENM
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 09/06/22 09:36 V23560ENM
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 09/06/22 09:36 V23560ENM
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 09/06/22 09:36 V23560ENM
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 09/06/22 09:36 V23560ENM
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 09/06/22 09:36 V23560ENM
<1.80 µg/L 1.80 5.00trans-1,2-Dichloroethene 10 09/06/22 09:36 V23560ENM
<1.90 µg/L 1.90 5.00
1,2-Dichloropropane 10 09/06/22 09:36 V23560ENM
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 09/06/22 09:36 V23560ENM
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 09/06/22 09:36 V23560ENM
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 09/06/22 09:36 V23560ENM
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 09/06/22 09:36 V23560ENM
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 09/06/22 09:36 V23560ENM
<420 µg/L 420 2000Ethanol 10 09/06/22 09:36 V23560ENM
51.4 µg/L 0.170 0.500
Ethylbenzene 1 09/06/22 09:09 V23560ENM
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 09/06/22 09:36 V23560ENM
<3.80 µg/L 3.80 10.02-Hexanone 10 09/06/22 09:36 V23560ENM
23.5 µg/L 0.180 0.500Isopropylbenzene 1 09/06/22 09:09 V23560ENM
3.48 µg/L 0.089 0.5004-Isopropyl toluene 1 09/06/22 09:09 V23560ENM
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 09/06/22 09:36 V23560ENM
451 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 09/06/22 09:36 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:MW-2
98070 Matrix:
8/25/2022 11:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 09/06/22 09:36 V23560ENM
<3.30 µg/L 3.30 20.0Methylene Chloride 10 09/06/22 09:36 V23560ENM
27.6 µg/L 0.470 1.00Naphthalene 1 09/06/22 09:09 V23560ENM
30.4 µg/L 0.190 0.500n-Propylbenzene 1 09/06/22 09:09 V23560ENM
<2.20 µg/L 2.20 5.00Styrene 10 09/06/22 09:36 V23560ENM
372 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 09/06/22 09:36 V23560ENM
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 09/06/22 09:36 V23560ENM
904 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 09/06/22 09:36 V23560ENM
7.10 J
µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 09/06/22 09:09 V23560ENM
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 09/06/22 09:36 V23560ENM
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 09/06/22 09:36 V23560ENM
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 09/06/22 09:36 V23560ENM
40.6 µg/L 0.220 0.500Toluene 1 09/06/22 09:09 V23560ENM
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 09/06/22 09:36 V23560ENM
<3.10 µg/L 3.10 5.001,2,4-Trichlorobenzene 10 09/06/22 09:36 V23560ENM
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 09/06/22 09:36 V23560ENM
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 09/06/22 09:36 V23560ENM
<1.80 µg/L 1.80 5.00Trichloroethene 10 09/06/22 09:36 V23560ENM
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 09/06/22 09:36 V23560ENM
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 09/06/22 09:36 V23560ENM
10.1 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/06/22 09:09 V23560ENM
6.33 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/06/22 09:09 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:MW-2
98070 Matrix:
8/25/2022 11:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 09/06/22 09:36 V23560ENM
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 09/06/22 09:36 V23560ENM
5.53 µg/L 0.210 0.500o-Xylene 1 09/06/22 09:09 V23560ENM
61.3 µg/L 0.420 1.00m,p-Xylene 1 09/06/22 09:09 V23560ENM
66.8 µg/L 0.210 0.500Xylene (Total)1 09/06/22 09:09 V23560
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%09/06/22 09:091 ENM V23560
Surrogate: Dibromofluoromethane 93.8 Limits: 70-130%09/06/22 09:091 ENM V23560
Surrogate: 1,2-Dichloroethane - d4 96.2 Limits: 70-130%09/06/22 09:091 ENM V23560
Surrogate: Toluene-d8 101 Limits: 70-130%09/06/22 09:091 ENM V23560
Surrogate: 4-Bromofluorobenzene 99.8 Limits: 70-130%09/06/22 09:3610 ENM V23560
Surrogate: Dibromofluoromethane 95.6 Limits: 70-130%09/06/22 09:3610 ENM V23560
Surrogate: 1,2-Dichloroethane - d4 95.6 Limits: 70-130%09/06/22 09:3610 ENM V23560
Surrogate: Toluene-d8 100 Limits: 70-130%09/06/22 09:3610 ENM V23560
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V23312 08/30/22 14:00
<0.00337 µg/L 0.00337 0.0204
1,2-Dibromoethane 1 08/30/22 20:54 V23403JLK
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:MW-2
98070 Matrix:
8/25/2022 11:57
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
1240 µg/L 23.0 100Aliphatic C5-C8 (Adjusted)1 08/30/22 09:15
159 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 08/29/22 11:49
341 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 08/29/22 11:49
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V23243 08/29/22 08:00
1680 µg/L 23.0 100Aliphatic C5-C8 2 08/30/22 09:15 V23244TBL
618 µg/L 25.8 50.0Aliphatic C9-C12 1 08/29/22 11:49 V23244TBL
341 µg/L 4.02 50.0Aromatic C9-C10 1 08/29/22 11:49 V23244TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)77.6 Limits: 70-130%08/29/22 11:491 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)75.9 Limits: 70-130%08/29/22 11:491 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)84.0 Limits: 70-130%08/30/22 09:152 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)77.1 Limits: 70-130%08/30/22 09:152 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:TW-1
98071 Matrix:
8/25/2022 10:46
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 09/06/22 08:51 6200BENM
0.010 mg/L 0.002 0.006Lead 1 09/07/22 15:54 6010DEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:TW-1
98071 Matrix:
8/25/2022 10:46
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 09/06/22 08:51 V23560ENM
1.13 µg/L 0.180 0.500Benzene 1 09/06/22 08:51 V23560ENM
<0.210 µg/L 0.210 0.500Bromobenzene 1 09/06/22 08:51 V23560ENM
<0.420 µg/L 0.420 1.00Bromochloromethane 1 09/06/22 08:51 V23560ENM
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 09/06/22 08:51 V23560ENM
<1.50 µg/L 1.50 5.00Bromoform 1 09/06/22 08:51 V23560ENM
<0.280 µg/L 0.280 1.00Bromomethane 1 09/06/22 08:51 V23560ENM
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 09/06/22 08:51 V23560ENM
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 09/06/22 08:51 V23560ENM
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 09/06/22 08:51 V23560ENM
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 09/06/22 08:51 V23560ENM
<0.190 µg/L 0.190 0.500Chlorobenzene 1 09/06/22 08:51 V23560ENM
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 09/06/22 08:51 V23560ENM
<0.430 µg/L 0.430 1.00Chloroethane 1 09/06/22 08:51 V23560ENM
3.55 µg/L 0.220 0.500Chloroform 1 09/06/22 08:51 V23560ENM
<0.220 µg/L 0.220 0.500
Chloromethane 1 09/06/22 08:51 V23560ENM
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 09/06/22 08:51 V23560ENM
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 09/06/22 08:51 V23560ENM
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 09/06/22 08:51 V23560ENM
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 09/06/22 08:51 V23560ENM
<0.230 µg/L 0.230 0.500Dibromomethane 1 09/06/22 08:51 V23560ENM
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 09/06/22 08:51 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:TW-1
98071 Matrix:
8/25/2022 10:46
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 09/06/22 08:51 V23560ENM
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 09/06/22 08:51 V23560ENM
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 09/06/22 08:51 V23560ENM
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 09/06/22 08:51 V23560ENM
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 09/06/22 08:51 V23560ENM
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 09/06/22 08:51 V23560ENM
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 09/06/22 08:51 V23560ENM
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 09/06/22 08:51 V23560ENM
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 09/06/22 08:51 V23560ENM
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 09/06/22 08:51 V23560ENM
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 09/06/22 08:51 V23560ENM
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 09/06/22 08:51 V23560ENM
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 09/06/22 08:51 V23560ENM
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 09/06/22 08:51 V23560ENM
<42.0 µg/L 42.0 200Ethanol 1 09/06/22 08:51 V23560ENM
0.941 µg/L 0.170 0.500
Ethylbenzene 1 09/06/22 08:51 V23560ENM
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 09/06/22 08:51 V23560ENM
<0.380 µg/L 0.380 1.002-Hexanone 1 09/06/22 08:51 V23560ENM
0.284 J µg/L 0.180 0.500Isopropylbenzene 1 09/06/22 08:51 V23560ENM
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 09/06/22 08:51 V23560ENM
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 09/06/22 08:51 V23560ENM
0.876 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 09/06/22 08:51 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:TW-1
98071 Matrix:
8/25/2022 10:46
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 09/06/22 08:51 V23560ENM
<0.330 µg/L 0.330 2.00Methylene Chloride 1 09/06/22 08:51 V23560ENM
0.656 J µg/L 0.470 1.00Naphthalene 1 09/06/22 08:51 V23560ENM
0.376 J µg/L 0.190 0.500n-Propylbenzene 1 09/06/22 08:51 V23560ENM
<0.220 µg/L 0.220 0.500Styrene 1 09/06/22 08:51 V23560ENM
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 09/06/22 08:51 V23560ENM
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 09/06/22 08:51 V23560ENM
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 09/06/22 08:51 V23560ENM
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 09/06/22 08:51 V23560ENM
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 09/06/22 08:51 V23560ENM
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 09/06/22 08:51 V23560ENM
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 09/06/22 08:51 V23560ENM
1.62 µg/L 0.220 0.500Toluene 1 09/06/22 08:51 V23560ENM
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 09/06/22 08:51 V23560ENM
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 09/06/22 08:51 V23560ENM
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 09/06/22 08:51 V23560ENM
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 09/06/22 08:51 V23560ENM
<0.180 µg/L 0.180 0.500Trichloroethene 1 09/06/22 08:51 V23560ENM
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 09/06/22 08:51 V23560ENM
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 09/06/22 08:51 V23560ENM
1.89 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 09/06/22 08:51 V23560ENM
0.774 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 09/06/22 08:51 V23560ENM
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:TW-1
98071 Matrix:
8/25/2022 10:46
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23556 09/05/22 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 09/06/22 08:51 V23560ENM
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 09/06/22 08:51 V23560ENM
0.954 µg/L 0.210 0.500o-Xylene 1 09/06/22 08:51 V23560ENM
4.57 µg/L 0.420 1.00m,p-Xylene 1 09/06/22 08:51 V23560ENM
5.52 µg/L 0.210 0.500Xylene (Total)1 09/06/22 08:51 V23560
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%09/06/22 08:511 ENM V23560
Surrogate: Dibromofluoromethane 95.8 Limits: 70-130%09/06/22 08:511 ENM V23560
Surrogate: 1,2-Dichloroethane - d4 95.2 Limits: 70-130%09/06/22 08:511 ENM V23560
Surrogate: Toluene-d8 101 Limits: 70-130%09/06/22 08:511 ENM V23560
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V23312 08/30/22 14:00
<0.00340 µg/L 0.00340 0.0206
1,2-Dibromoethane 1 08/30/22 21:12 V23403JLK
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 33
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-238-0011
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/26/2022
Moore's Citgo
Report Date : 09/08/2022
Sample ID :
Lab No :
Sampled:TW-1
98071 Matrix:
8/25/2022 10:46
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
45.5 J µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 08/29/22 11:25
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 08/29/22 11:25
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 08/29/22 11:25
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V23243 08/29/22 08:00
48.2 J µg/L 11.5 50.0Aliphatic C5-C8 1 08/29/22 11:25 V23244TBL
30.3 J µg/L 25.8 50.0Aliphatic C9-C12 1 08/29/22 11:25 V23244TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 08/29/22 11:25 V23244TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)77.4 Limits: 70-130%08/29/22 11:251 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)76.7 Limits: 70-130%08/29/22 11:251 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Page 22 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Metals Analysis
6010D
V23566QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V23346
Associated Lab Samples: 98070, 98071
LRB-V23346 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
09/07/22 14:590.0060.002<0.002mg/LLead
LCS-V23346Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1050.1050.100mg/LLead 80-120
V 97971-MS-V23346 V 97971-MSD-V23346Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.105 1000.1070.1000.1000.005mg/LLead 102 75-125 1.8 20.0
V 97971-PDS-V23346Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
09/07/22 15:2799.00.249mg/LLead
Page 1 of 9Date:09/08/2022 12:42 PM
Page 23 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23560QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23556
Associated Lab Samples: 98069, 98070, 98071
LRB-V23556 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/06/22 02:4910.01.80<1.80µg/LAcetone
09/06/22 02:490.5000.180<0.180µg/LBenzene
09/06/22 02:490.5000.210<0.210µg/LBromobenzene
09/06/22 02:491.000.420<0.420µg/LBromochloromethane
09/06/22 02:490.5000.160<0.160µg/LBromodichloromethane
09/06/22 02:495.001.50<1.50µg/LBromoform
09/06/22 02:491.000.280<0.280µg/LBromomethane
09/06/22 02:490.5000.180<0.180µg/Ln-Butylbenzene
09/06/22 02:490.5000.200<0.200µg/Lsec-Butyl benzene
09/06/22 02:492.000.920<0.920µg/Ltert-Butyl benzene
09/06/22 02:490.5000.180<0.180µg/LCarbon Tetrachloride
09/06/22 02:490.5000.190<0.190µg/LChlorobenzene
09/06/22 02:490.5000.190<0.190µg/LChlorodibromomethane
09/06/22 02:491.000.430<0.430µg/LChloroethane
09/06/22 02:490.5000.220<0.220µg/LChloroform
09/06/22 02:490.5000.220<0.220µg/LChloromethane
09/06/22 02:490.5000.200<0.200µg/L2-Chlorotoluene
09/06/22 02:490.5000.200<0.200µg/L4-Chlorotoluene
09/06/22 02:490.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
09/06/22 02:492.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
09/06/22 02:490.5000.200<0.200µg/L1,2-Dibromoethane
09/06/22 02:490.5000.230<0.230µg/LDibromomethane
09/06/22 02:490.5000.220<0.220µg/L1,2-Dichlorobenzene
09/06/22 02:490.5000.190<0.190µg/L1,3-Dichlorobenzene
09/06/22 02:490.5000.210<0.210µg/L1,4-Dichlorobenzene
09/06/22 02:495.001.20<1.20µg/LDichlorodifluoromethane
09/06/22 02:490.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 9Date:09/08/2022 12:42 PM
Page 24 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23560QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23556
Associated Lab Samples: 98069, 98070, 98071
LRB-V23556 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/06/22 02:490.5000.150<0.150µg/L1,2-Dichloroethane
09/06/22 02:490.5000.150<0.150µg/L1,1-Dichloroethene
09/06/22 02:490.5000.200<0.200µg/Lcis-1,2-Dichloroethene
09/06/22 02:490.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
09/06/22 02:490.5000.190<0.190µg/L1,2-Dichloropropane
09/06/22 02:490.5000.130<0.130µg/L1,3-Dichloropropane
09/06/22 02:492.000.210<0.210µg/L2,2-Dichloropropane
09/06/22 02:490.5000.200<0.200µg/L1,1-Dichloropropene
09/06/22 02:490.5000.210<0.210µg/Lcis-1,3-Dichloropropene
09/06/22 02:490.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
09/06/22 02:4920042.0<42.0µg/LEthanol
09/06/22 02:490.5000.170<0.170µg/LEthylbenzene
09/06/22 02:493.000.350<0.350µg/LHexachlorobutadiene
09/06/22 02:491.000.380<0.380µg/L2-Hexanone
09/06/22 02:490.5000.180<0.180µg/LIsopropylbenzene
09/06/22 02:490.5000.089<0.089µg/L4-Isopropyl toluene
09/06/22 02:495.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
09/06/22 02:491.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
09/06/22 02:491.000.078<0.078µg/L4-Methyl-2-Pentanone
09/06/22 02:492.000.330<0.330µg/LMethylene Chloride
09/06/22 02:491.000.470<0.470µg/LNaphthalene
09/06/22 02:490.5000.190<0.190µg/Ln-Propylbenzene
09/06/22 02:490.5000.220<0.220µg/LStyrene
09/06/22 02:4910.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
09/06/22 02:4910.00.350<0.350µg/Ltert-Butyl formate (TBF)
09/06/22 02:4910.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
09/06/22 02:4910.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 3 of 9Date:09/08/2022 12:42 PM
Page 25 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23560QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23556
Associated Lab Samples: 98069, 98070, 98071
LRB-V23556 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
09/06/22 02:490.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
09/06/22 02:490.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
09/06/22 02:490.5000.220<0.220µg/LTetrachloroethene
09/06/22 02:490.5000.220<0.220µg/LToluene
09/06/22 02:490.5000.380<0.380µg/L1,2,3-Trichlorobenzene
09/06/22 02:490.5000.310<0.310µg/L1,2,4-Trichlorobenzene
09/06/22 02:490.5000.160<0.160µg/L1,1,1-Trichloroethane
09/06/22 02:490.5000.096<0.096µg/L1,1,2-Trichloroethane
09/06/22 02:490.5000.180<0.180µg/LTrichloroethene
09/06/22 02:490.5000.180<0.180µg/LTrichlorofluoromethane
09/06/22 02:490.5000.270<0.270µg/L1,2,3-Trichloropropane
09/06/22 02:490.5000.190<0.190µg/L1,2,4-Trimethylbenzene
09/06/22 02:490.5000.180<0.180µg/L1,3,5-Trimethylbenzene
09/06/22 02:495.001.00<1.00µg/LVinyl Acetate
09/06/22 02:490.5000.170<0.170µg/LVinyl Chloride
09/06/22 02:490.5000.210<0.210µg/Lo-Xylene
09/06/22 02:491.000.420<0.420µg/Lm,p-Xylene
09/06/22 02:4910.01.00<1.00µg/L3,3-Dimethyl-1-butanol
09/06/22 02:494-Bromofluorobenzene (S)99.6 70-130
09/06/22 02:49Dibromofluoromethane (S)96.6 70-130
09/06/22 02:491,2-Dichloroethane - d4 (S)96.4 70-130
09/06/22 02:49Toluene-d8 (S)100 70-130
Page 4 of 9Date:09/08/2022 12:42 PM
Page 26 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23560QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23556
LCS-V23556 LCSD-V23556Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
44.7 11211044.040.0µg/LAcetone 40-160 1.5 20.0
20.7 10410420.720.0µg/LBenzene 70-130 0.0 20.0
20.8 10410320.520.0µg/LBromobenzene 70-130 1.4 20.0
20.9 10511022.020.0µg/LBromochloromethane 70-130 5.1 20.0
21.2 10610621.220.0µg/LBromodichloromethane 70-130 0.0 20.0
24.2 12112024.020.0µg/LBromoform 70-130 0.8 20.0
19.4 97.093.518.720.0µg/LBromomethane 60-140 3.6 20.0
19.8 99.010120.120.0µg/Ln-Butylbenzene 70-130 1.5 20.0
20.7 10410721.320.0µg/Lsec-Butyl benzene 70-130 2.8 20.0
21.2 10610721.320.0µg/Ltert-Butyl benzene 70-130 0.4 20.0
20.5 10310120.120.0µg/LCarbon Tetrachloride 70-130 1.9 20.0
21.4 10710621.220.0µg/LChlorobenzene 70-130 0.9 20.0
23.6 11811723.320.0µg/LChlorodibromomethane 70-130 1.2 20.0
16.9 84.592.518.520.0µg/LChloroethane 60-140 9.0 20.0
19.8 99.010120.120.0µg/LChloroform 70-130 1.5 20.0
16.5 82.584.016.820.0µg/LChloromethane 60-140 1.8 20.0
20.5 10310320.620.0µg/L2-Chlorotoluene 70-130 0.4 20.0
20.9 10510420.720.0µg/L4-Chlorotoluene 70-130 0.9 20.0
21.0 10510320.620.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.9 20.0
20.9 10510921.720.0µg/L1,2-Dibromo-3-Chloropropane 70-130 3.7 20.0
21.0 10510821.620.0µg/L1,2-Dibromoethane 70-130 2.8 20.0
20.9 10510220.420.0µg/LDibromomethane 70-130 2.4 20.0
22.0 11011422.820.0µg/L1,2-Dichlorobenzene 70-130 3.5 20.0
21.9 11010921.820.0µg/L1,3-Dichlorobenzene 70-130 0.4 20.0
21.3 10711022.020.0µg/L1,4-Dichlorobenzene 70-130 3.2 20.0
13.2 66.071.014.220.0µg/LDichlorodifluoromethane 60-140 7.2 20.0
Page 5 of 9Date:09/08/2022 12:42 PM
Page 27 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23560QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23556
LCS-V23556 LCSD-V23556Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.7 98.598.519.720.0µg/L1,1-Dichloroethane 70-130 0.0 20.0
18.9 94.594.518.920.0µg/L1,2-Dichloroethane 70-130 0.0 20.0
20.0 10010020.020.0µg/L1,1-Dichloroethene 70-130 0.0 20.0
19.9 99.598.519.720.0µg/Lcis-1,2-Dichloroethene 70-130 1.0 20.0
19.6 98.099.019.820.0µg/Ltrans-1,2-Dichloroethene 70-130 1.0 20.0
20.9 10598.519.720.0µg/L1,2-Dichloropropane 70-130 5.9 20.0
22.9 11511422.820.0µg/L1,3-Dichloropropane 70-130 0.4 20.0
15.8 79.080.016.020.0µg/L2,2-Dichloropropane 70-130 1.2 20.0
20.0 10010220.420.0µg/L1,1-Dichloropropene 70-130 1.9 20.0
20.4 10210320.520.0µg/Lcis-1,3-Dichloropropene 70-130 0.4 20.0
20.4 10210320.520.0µg/Ltrans-1,3-Dichloropropene 70-130 0.4 20.0
532 10688.2441500µg/LEthanol 60-140 18.7 20.0
21.3 10710721.320.0µg/LEthylbenzene 70-130 0.0 20.0
20.4 10210721.320.0µg/LHexachlorobutadiene 70-130 4.3 20.0
20.3 10298.019.620.0µg/L2-Hexanone 60-140 3.5 20.0
21.0 10510721.320.0µg/LIsopropylbenzene 70-130 1.4 20.0
21.2 10610821.520.0µg/L4-Isopropyl toluene 70-130 1.4 20.0
21.2 10610521.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.9 20.0
21.5 10811022.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.2 20.0
19.7 98.599.019.820.0µg/L4-Methyl-2-Pentanone 60-140 0.5 20.0
20.1 10110120.220.0µg/LMethylene Chloride 70-130 0.4 20.0
18.4 92.093.018.620.0µg/LNaphthalene 70-130 1.0 20.0
20.9 10510621.120.0µg/Ln-Propylbenzene 70-130 0.9 20.0
22.0 11011122.120.0µg/LStyrene 70-130 0.4 20.0
47.7 11911746.940.0µg/Ltert-Butyl Alcohol (TBA)40-140 1.6 20.0
43.5 10910843.140.0µg/Ltert-Butyl formate (TBF)40-140 0.9 20.0
Page 6 of 9Date:09/08/2022 12:42 PM
Page 28 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23560QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23556
LCS-V23556 LCSD-V23556Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
16.5 82.511623.220.0µg/Ltert-Amyl Alcohol (TAA)40-140 33.7*20.0
44.6 11211144.440.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.4 20.0
22.8 11411322.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.8 20.0
22.8 11410621.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 7.2 20.0
21.4 10710821.520.0µg/LTetrachloroethene 70-130 0.4 20.0
20.6 10310220.420.0µg/LToluene 70-130 0.9 20.0
20.3 10210320.620.0µg/L1,2,3-Trichlorobenzene 70-130 1.4 20.0
20.4 10210320.620.0µg/L1,2,4-Trichlorobenzene 70-130 0.9 20.0
19.9 99.510120.220.0µg/L1,1,1-Trichloroethane 70-130 1.4 20.0
21.5 10810521.020.0µg/L1,1,2-Trichloroethane 70-130 2.3 20.0
20.0 10010220.420.0µg/LTrichloroethene 70-130 1.9 20.0
20.3 10210621.120.0µg/LTrichlorofluoromethane 60-140 3.8 20.0
23.6 11811523.020.0µg/L1,2,3-Trichloropropane 70-130 2.5 20.0
21.0 10510821.520.0µg/L1,2,4-Trimethylbenzene 70-130 2.3 20.0
21.4 10710821.520.0µg/L1,3,5-Trimethylbenzene 70-130 0.4 20.0
20.0 10098.019.620.0µg/LVinyl Acetate 60-140 2.0 20.0
16.8 84.087.017.420.0µg/LVinyl Chloride 60-140 3.5 20.0
21.3 10710721.320.0µg/Lo-Xylene 70-130 0.0 20.0
43.9 11011144.540.0µg/Lm,p-Xylene 70-130 1.3 20.0
23.8 11912725.420.0µg/L3,3-Dimethyl-1-butanol 70-130 6.5 20.0
99.698.84-Bromofluorobenzene (S)70-130
99.297.8Dibromofluoromethane (S)70-130
97.297.01,2-Dichloroethane - d4 (S)70-130
101101Toluene-d8 (S)70-130
Page 7 of 9* QC Fail Date:09/08/2022 12:42 PM
Page 29 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V23403QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V23312
Associated Lab Samples: 98070, 98071
LRB-V23312 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
08/30/22 15:360.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V23312 LCSD-V23312Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.245 98.097.60.2440.250µg/L1,2-Dibromoethane 70-130 0.4 20.0
V 97714-DUP-V23312Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 08/30/22 18:220.0<0.0206< 0.0206µg/L1,2-Dibromoethane
V 97713-MS-V23312Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.256 99.20.258< 0.00340µg/L1,2-Dibromoethane 70-130
Page 8 of 9Date:09/08/2022 12:42 PM
Page 30 of 33
Quality Control Data
22-238-0011Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V23244QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V23243
Associated Lab Samples: 98070, 98071
LRB-V23243 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/29/22 11:0150.011.5<11.5µg/LAliphatic C5-C8
08/29/22 11:0150.025.8<25.8µg/LAliphatic C9-C12
08/29/22 11:0150.04.02<4.02µg/LAromatic C9-C10
08/29/22 11:012,5-Dibromotoluene (FID) (S)77.8 70-130
08/29/22 11:012,5-Dibromotoluene (PID) (S)75.1 70-130
LCS-V23243 LCSD-V23243Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
281 93.691.0273300µg/LAliphatic C5-C8 70-130 2.8 50.0
294 98.096.6290300µg/LAliphatic C9-C12 70-130 1.3 50.0
104 10499.699.6100µg/LAromatic C9-C10 70-130 4.3 50.0
75.580.82,5-Dibromotoluene (FID) (S)70-130
77.584.92,5-Dibromotoluene (PID) (S)70-130
Page 9 of 9Date:09/08/2022 12:42 PM
Page 31 of 33
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-238-0011
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 2.8C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:08/26/2022 11:13:15
Special precautions or instructions included?
Comments:
Page 32 of 33
Page 33 of 33

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

9/1/2022
Geological Resources, Inc. Rae Brown
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-231-0060 Client Project Description: Moore's Citgo
GRI #5285
Dear Rae Brown:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 8/19/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 49
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State Program Lab ID Expiration Date
02/28/202340750State ProgramAlabama
02/07/202388-0650State ProgramArkansas
06/30/20232904State ProgramCalifornia
06/30/2023E871157State Program - NELAPFlorida
02/18/2023C044State ProgramGeorgia
06/30/202304015State ProgramGeorgia
10/10/2022200078State Program - NELAPIllinois
06/30/202380215State ProgramKentucky
12/31/2022KY90047State ProgramKentucky
12/31/2022LA037State Program - NELAPLouisiana
06/30/202304015State Program - NELAPLouisiana
02/11/2023MSState ProgramMississippi
12/31/2022415State ProgramNorth Carolina
05/31/202368-03195State Program - NELAPPennsylvania
06/30/202284002State ProgramSouth Carolina
02/11/202302027State ProgramTennessee
09/30/2022T104704180State Program - NELAPTexas
06/30/202300106State ProgramVirginia
09/14/2022460181State Program - NELAPVirginia
Page 1 of 1 00016/22-231-0060
Page 2 of 49
Report Number:
Sample Summary Table
Client Project Description:
22-231-0060
Moore's Citgo
GRI #5285
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
08/15/2022 15:32Solids 97628 TW-1 10'08/19/2022
08/15/2022 15:57Solids 97629 TW-1 20'08/19/2022
08/16/2022 08:33Solids 97630 MW-4 20'08/19/2022
08/16/2022 08:42Solids 97631 MW-4 24'08/19/2022
08/16/2022 08:42Solids 97631 MW-4 24'08/19/2022 WALK-BLACK WP MTN -
08/16/2022 08:42Solids 97631 MW-4 24'08/19/2022 Texture WP MTN -
08/16/2022 09:46Solids 97632 MW-3 18'08/19/2022
08/16/2022 09:54Solids 97633 MW-3 24'08/19/2022
08/16/2022 10:21Solids 97634 MW-2 2'08/19/2022
08/16/2022 11:05Solids 97635 MW-2 24'08/19/2022
08/16/2022 11:05Solids 97635 MW-2 24'08/19/2022 WALK-BLACK WP MTN -
08/16/2022 11:05Solids 97635 MW-2 24'08/19/2022 Texture WP MTN -
08/17/2022 09:19Solids 97636 TW-1 46'08/19/2022 WALK-BLACK WP MTN -
08/17/2022 09:19Solids 97636 TW-1 46'08/19/2022 Texture WP MTN -
08/16/2022 07:38Aqueous 97637 Trip Blank 08/19/2022
08/16/2022 15:04Aqueous 97638 MW-2 08/19/2022
08/17/2022 10:54Aqueous 97639 TW-1 08/19/2022
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 49
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-231-0060
Report Limit
Project:Moore's Citgo
V 97628TW-1 10'
737 08/24/2022 12:458015C GRO Gasoline Range Organics (C6-C10)mg/Kg 20.7
V 97629TW-1 20'
384 08/24/2022 13:138015C GRO Gasoline Range Organics (C6-C10)mg/Kg 20.7
V 97630MW-4 20'
58.2 08/24/2022 09:578015C GRO Gasoline Range Organics (C6-C10)mg/Kg 2.07
V 97631MW-4 24'
649 08/24/2022 12:178015C GRO Gasoline Range Organics (C6-C10)mg/Kg 20.7
12.0 08/29/2022 13:59Texture%Clay %0.1
29.0 08/29/2022 13:59Texture%Sand %
59.0 08/29/2022 13:59Texture%Silt %0.1
Silt Loam 08/29/2022 13:59TextureSoil Classification
0.20 08/29/2022 14:30WALK-BLACK Total Organic Carbon %0.05
V 97632MW-3 18'
38.5 08/24/2022 10:258015C GRO Gasoline Range Organics (C6-C10)mg/Kg 2.07
V 97633MW-3 24'
289 08/24/2022 11:498015C GRO Gasoline Range Organics (C6-C10)mg/Kg 20.7
V 97634MW-2 2'
50.7 08/24/2022 10:538015C GRO Gasoline Range Organics (C6-C10)mg/Kg 2.07
V 97635MW-2 24'
1920 08/24/2022 11:218015C GRO Gasoline Range Organics (C6-C10)mg/Kg 20.7
10.0 08/29/2022 13:59Texture%Clay %0.1
73.0 08/29/2022 13:59Texture%Sand %
17.0 08/29/2022 13:59Texture%Silt %0.1
Sandy Loam 08/29/2022 13:59TextureSoil Classification
0.42 08/29/2022 14:30WALK-BLACK Total Organic Carbon %0.05
V 97636TW-1 46'
6.0 08/29/2022 13:59Texture%Clay %0.1
83.0 08/29/2022 13:59Texture%Sand %
11.0 08/29/2022 13:59Texture%Silt %0.1
Loamy Sand 08/29/2022 13:59TextureSoil Classification
0.20 08/29/2022 14:30WALK-BLACK Total Organic Carbon %0.05
Page 4 of 49
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-231-0060
Report Limit
Project:Moore's Citgo
V 97637Trip Blank
J2.50 08/29/2022 22:556200BAcetoneµg/L 1.80
J0.225 08/29/2022 22:556200BEthylbenzeneµg/L 0.170
0.640 08/29/2022 22:556200BTolueneµg/L 0.220
J0.892 08/29/2022 22:556200Bm,p-Xylene µg/L 0.420
J0.892 08/29/2022 22:556200BXylene (Total)µg/L 0.210
V 97638MW-2
J0.003 08/24/2022 16:306010DLeadmg/L 0.002
19.9 08/29/2022 23:196200BAcetoneµg/L 1.80
571 08/30/2022 15:186200BBenzeneµg/L 1.80
12.4 08/29/2022 23:196200Bn-Butylbenzene µg/L 0.180
8.56 08/29/2022 23:196200Bsec-Butyl benzene µg/L 0.200
1.22 08/29/2022 23:196200BDi-Isopropyl Ether (DIPE)µg/L 0.500
91.1 08/30/2022 15:186200BEthylbenzeneµg/L 1.70
38.5 08/29/2022 23:196200BIsopropylbenzeneµg/L 0.180
4.74 08/29/2022 23:196200B4-Isopropyl toluene µg/L 0.089
449 08/30/2022 15:186200BMethyl tert-butyl ether (MTBE)µg/L 1.40
12.5 08/29/2022 23:196200BNaphthaleneµg/L 0.470
53.2 08/29/2022 23:196200Bn-Propylbenzene µg/L 0.190
138 08/29/2022 23:196200Btert-Butyl Alcohol (TBA)µg/L 1.60
986 08/30/2022 15:186200Btert-Amyl Alcohol (TAA)µg/L 19.0
J4.36 08/29/2022 23:196200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
133 08/30/2022 15:186200BTolueneµg/L 2.20
25.7 08/29/2022 23:196200B1,2,4-Trimethylbenzene µg/L 0.190
8.16 08/29/2022 23:196200B1,3,5-Trimethylbenzene µg/L 0.180
2.40 08/29/2022 23:196200Bo-Xylene µg/L 0.210
91.8 08/29/2022 23:196200Bm,p-Xylene µg/L 0.420
94.2 08/29/2022 23:196200BXylene (Total)µg/L 0.210
1180 08/24/2022 09:39CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
185 08/24/2022 08:15CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
421 08/24/2022 08:15CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
1880 08/24/2022 09:39MADEP-VPH Aliphatic C5-C8 µg/L 115
791 08/24/2022 08:15MADEP-VPH Aliphatic C9-C12 µg/L 25.8
421 08/24/2022 08:15MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 97639TW-1
0.020 08/24/2022 16:346010DLeadmg/L 0.002
11.5 08/29/2022 23:436200BAcetoneµg/L 1.80
Page 5 of 49
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-231-0060
Report Limit
Project:Moore's Citgo
V 97639TW-1
5.50 08/29/2022 23:436200BBenzeneµg/L 0.180
3.03 08/29/2022 23:436200BBromodichloromethaneµg/L 0.160
1.73 08/29/2022 23:436200Bn-Butylbenzene µg/L 0.180
0.574 08/29/2022 23:436200Bsec-Butyl benzene µg/L 0.200
1.15 08/29/2022 23:436200BChlorodibromomethaneµg/L 0.190
9.36 08/29/2022 23:436200BChloroformµg/L 0.220
14.1 08/29/2022 23:436200BEthylbenzeneµg/L 0.170
2.61 08/29/2022 23:436200BIsopropylbenzeneµg/L 0.180
J0.268 08/29/2022 23:436200B4-Isopropyl toluene µg/L 0.089
J2.26 08/29/2022 23:436200BMethyl Ethyl Ketone (MEK)µg/L 0.710
J0.713 08/29/2022 23:436200BMethyl tert-butyl ether (MTBE)µg/L 0.140
4.16 08/29/2022 23:436200BNaphthaleneµg/L 0.470
5.07 08/29/2022 23:436200Bn-Propylbenzene µg/L 0.190
J5.86 08/29/2022 23:436200Btert-Butyl Alcohol (TBA)µg/L 1.60
12.0 08/29/2022 23:436200Btert-Amyl Alcohol (TAA)µg/L 1.90
15.0 08/29/2022 23:436200BTolueneµg/L 0.220
10.5 08/29/2022 23:436200B1,2,4-Trimethylbenzene µg/L 0.190
4.70 08/29/2022 23:436200B1,3,5-Trimethylbenzene µg/L 0.180
7.56 08/29/2022 23:436200Bo-Xylene µg/L 0.210
41.4 08/29/2022 23:436200Bm,p-Xylene µg/L 0.420
49.0 08/29/2022 23:436200BXylene (Total)µg/L 0.210
186 08/24/2022 08:39CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J12308/24/2022 08:39CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J36.6 08/24/2022 08:39CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
206 08/24/2022 08:39MADEP-VPH Aliphatic C5-C8 µg/L 11.5
223 08/24/2022 08:39MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J36.6 08/24/2022 08:39MADEP-VPH Aromatic C9-C10 µg/L 4.02
Page 6 of 49

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Moore's Citgo Lab Report Number: 22-231-0060
Date: 9/1/2022
Total Petroleum Hydrocarbons - Volatile Method 8015C GRO Sample 97629 (TW-1 20') Analyte: a,a,a-Trifluorotoluene
QC Batch No: V23064/V23062 The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Surrogate of sample was affected by matrix of the sample. All QC surrogates pass within range. No further action taken.

Page 7 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1 10'
97628 Matrix:
8/15/2022 15:32
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
737 mg/Kg 20.7 50.0Gasoline Range Organics (C6-C10)500 08/24/22 12:45 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 134 Limits: 50-137%08/24/22 12:45500 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 8 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1 20'
97629 Matrix:
8/15/2022 15:57
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
384 mg/Kg 20.7 50.0Gasoline Range Organics (C6-C10)500 08/24/22 13:13 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 137 *Limits: 50-137%08/24/22 13:13500 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 9 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-4 20'
97630 Matrix:
8/16/2022 8:33
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
58.2 mg/Kg 2.07 5.00Gasoline Range Organics (C6-C10)50 08/24/22 09:57 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 134 Limits: 50-137%08/24/22 09:5750 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 10 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-4 24'
97631 Matrix:
8/16/2022 8:42
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
12.0 %0.1%Clay 1 08/29/22 13:59 TextureEB
0.20 %0.05Total Organic Carbon 1 08/29/22 14:30 WALK-BLACKTAW
29.0 %%Sand 1 08/29/22 13:59 TextureEB
59.0 %0.1%Silt 1 08/29/22 13:59 TextureEB
Silt LoamSoil Classification 1 08/29/22 13:59 TextureEB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 11 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-4 24'
97631 Matrix:
8/16/2022 8:42
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
649 mg/Kg 20.7 50.0Gasoline Range Organics (C6-C10)500 08/24/22 12:17 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 99.0 Limits: 50-137%08/24/22 12:17500 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 12 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-3 18'
97632 Matrix:
8/16/2022 9:46
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
38.5 mg/Kg 2.07 5.00Gasoline Range Organics (C6-C10)50 08/24/22 10:25 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 131 Limits: 50-137%08/24/22 10:2550 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 13 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-3 24'
97633 Matrix:
8/16/2022 9:54
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
289 mg/Kg 20.7 50.0Gasoline Range Organics (C6-C10)500 08/24/22 11:49 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 134 Limits: 50-137%08/24/22 11:49500 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 14 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2 2'
97634 Matrix:
8/16/2022 10:21
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
50.7 mg/Kg 2.07 5.00Gasoline Range Organics (C6-C10)50 08/24/22 10:53 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 137 Limits: 50-137%08/24/22 10:5350 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 15 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2 24'
97635 Matrix:
8/16/2022 11:05
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
10.0 %0.1%Clay 1 08/29/22 13:59 TextureEB
0.42 %0.05Total Organic Carbon 1 08/29/22 14:30 WALK-BLACKTAW
73.0 %%Sand 1 08/29/22 13:59 TextureEB
17.0 %0.1%Silt 1 08/29/22 13:59 TextureEB
Sandy LoamSoil Classification 1 08/29/22 13:59 TextureEB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 16 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2 24'
97635 Matrix:
8/16/2022 11:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8015C GRO Prep Batch(es):V23062 08/24/22 08:00
1920 mg/Kg 20.7 50.0Gasoline Range Organics (C6-C10)500 08/24/22 11:21 V23064TBL
8015C GROSurrogate: a,a,a-Trifluorotoluene 85.9 Limits: 50-137%08/24/22 11:21500 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 17 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1 46'
97636 Matrix:
8/17/2022 9:19
Solids
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
6.0 %0.1%Clay 1 08/29/22 13:59 TextureEB
83.0 %%Sand 1 08/29/22 13:59 TextureEB
11.0 %0.1%Silt 1 08/29/22 13:59 TextureEB
Loamy SandSoil Classification 1 08/29/22 13:59 TextureEB
0.20 %0.05Total Organic Carbon 1 08/29/22 14:30 WALK-BLACKTAW
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 18 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97637 Matrix:
8/16/2022 7:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
2.50 J µg/L 1.80 10.0Acetone 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.500Benzene 1 08/29/22 22:55 V23311JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/29/22 22:55 V23311JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/29/22 22:55 V23311JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/29/22 22:55 V23311JLB
<1.50 µg/L 1.50 5.00Bromoform 1 08/29/22 22:55 V23311JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 08/29/22 22:55 V23311JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 08/29/22 22:55 V23311JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/29/22 22:55 V23311JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/29/22 22:55 V23311JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/29/22 22:55 V23311JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 08/29/22 22:55 V23311JLB
<0.220 µg/L 0.220 0.500Chloroform 1 08/29/22 22:55 V23311JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 08/29/22 22:55 V23311JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/29/22 22:55 V23311JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/29/22 22:55 V23311JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/29/22 22:55 V23311JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/29/22 22:55 V23311JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 08/29/22 22:55 V23311JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/29/22 22:55 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 19 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97637 Matrix:
8/16/2022 7:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/29/22 22:55 V23311JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/29/22 22:55 V23311JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/29/22 22:55 V23311JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/29/22 22:55 V23311JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/29/22 22:55 V23311JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/29/22 22:55 V23311JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/29/22 22:55 V23311JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 08/29/22 22:55 V23311JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 08/29/22 22:55 V23311JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/29/22 22:55 V23311JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/29/22 22:55 V23311JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/29/22 22:55 V23311JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/29/22 22:55 V23311JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/29/22 22:55 V23311JLB
<42.0 µg/L 42.0 200
Ethanol 1 08/29/22 22:55 V23311JLB
0.225 J µg/L 0.170 0.500Ethylbenzene 1 08/29/22 22:55 V23311JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/29/22 22:55 V23311JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 08/29/22 22:55 V23311JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 08/29/22 22:55 V23311JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/29/22 22:55 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 20 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97637 Matrix:
8/16/2022 7:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/29/22 22:55 V23311JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/29/22 22:55 V23311JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/29/22 22:55 V23311JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 08/29/22 22:55 V23311JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 08/29/22 22:55 V23311JLB
<0.220 µg/L 0.220 0.500Styrene 1 08/29/22 22:55 V23311JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/29/22 22:55 V23311JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/29/22 22:55 V23311JLB
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 08/29/22 22:55 V23311JLB
0.640 µg/L 0.220 0.500Toluene 1 08/29/22 22:55 V23311JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/29/22 22:55 V23311JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/29/22 22:55 V23311JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/29/22 22:55 V23311JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 08/29/22 22:55 V23311JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/29/22 22:55 V23311JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/29/22 22:55 V23311JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/29/22 22:55 V23311JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/29/22 22:55 V23311JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/29/22 22:55 V23311JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 08/29/22 22:55 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 21 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97637 Matrix:
8/16/2022 7:38
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
0.892 J µg/L 0.420 1.00m,p-Xylene 1 08/29/22 22:55 V23311JLB
0.892 J µg/L 0.210 0.500Xylene (Total)1 08/29/22 22:55 V23311
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%08/29/22 22:551 JLB V23311
Surrogate: Dibromofluoromethane 101 Limits: 70-130%08/29/22 22:551 JLB V23311
Surrogate: 1,2-Dichloroethane - d4 109 Limits: 70-130%08/29/22 22:551 JLB V23311
Surrogate: Toluene-d8 108 Limits: 70-130%08/29/22 22:551 JLB V23311
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 22 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2
97638 Matrix:
8/16/2022 15:04
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/29/22 23:19 6200BJLB
0.003 J mg/L 0.002 0.006Lead 1 08/24/22 16:30 6010DMMR
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 23 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2
97638 Matrix:
8/16/2022 15:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00 V23323 08/30/22 09:00
19.9 µg/L 1.80 10.0Acetone 1 08/29/22 23:19 V23311JLB
571 µg/L 1.80 5.00Benzene 10 08/30/22 15:18 V23324JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/29/22 23:19 V23311JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/29/22 23:19 V23311JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 08/29/22 23:19 V23311JLB
<1.50 µg/L 1.50 5.00Bromoform 1 08/29/22 23:19 V23311JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 08/29/22 23:19 V23311JLB
12.4 µg/L 0.180 0.500n-Butylbenzene 1 08/29/22 23:19 V23311JLB
8.56 µg/L 0.200 0.500
sec-Butyl benzene 1 08/29/22 23:19 V23311JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/29/22 23:19 V23311JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/29/22 23:19 V23311JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/29/22 23:19 V23311JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 08/29/22 23:19 V23311JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 08/29/22 23:19 V23311JLB
<0.220 µg/L 0.220 0.500Chloroform 1 08/29/22 23:19 V23311JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 08/29/22 23:19 V23311JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/29/22 23:19 V23311JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/29/22 23:19 V23311JLB
1.22 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/29/22 23:19 V23311JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/29/22 23:19 V23311JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/29/22 23:19 V23311JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/29/22 23:19 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 24 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2
97638 Matrix:
8/16/2022 15:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00 V23323 08/30/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/29/22 23:19 V23311JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/29/22 23:19 V23311JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/29/22 23:19 V23311JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/29/22 23:19 V23311JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/29/22 23:19 V23311JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/29/22 23:19 V23311JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/29/22 23:19 V23311JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/29/22 23:19 V23311JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 08/29/22 23:19 V23311JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/29/22 23:19 V23311JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/29/22 23:19 V23311JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/29/22 23:19 V23311JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/29/22 23:19 V23311JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/29/22 23:19 V23311JLB
<42.0 µg/L 42.0 200Ethanol 1 08/29/22 23:19 V23311JLB
91.1 µg/L 1.70 5.00
Ethylbenzene 10 08/30/22 15:18 V23324JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/29/22 23:19 V23311JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 08/29/22 23:19 V23311JLB
38.5 µg/L 0.180 0.500Isopropylbenzene 1 08/29/22 23:19 V23311JLB
4.74 µg/L 0.089 0.5004-Isopropyl toluene 1 08/29/22 23:19 V23311JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/29/22 23:19 V23311JLB
449 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 08/30/22 15:18 V23324JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 25 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2
97638 Matrix:
8/16/2022 15:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00 V23323 08/30/22 09:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/29/22 23:19 V23311JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/29/22 23:19 V23311JLB
12.5 µg/L 0.470 1.00Naphthalene 1 08/29/22 23:19 V23311JLB
53.2 µg/L 0.190 0.500n-Propylbenzene 1 08/29/22 23:19 V23311JLB
<0.220 µg/L 0.220 0.500Styrene 1 08/29/22 23:19 V23311JLB
138 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/29/22 23:19 V23311JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/29/22 23:19 V23311JLB
986 µg/L 19.0 100tert-Amyl Alcohol (TAA)10 08/30/22 15:18 V23324JLB
4.36 J
µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 08/29/22 23:19 V23311JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/29/22 23:19 V23311JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/29/22 23:19 V23311JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/29/22 23:19 V23311JLB
133 µg/L 2.20 5.00Toluene 10 08/30/22 15:18 V23324JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/29/22 23:19 V23311JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/29/22 23:19 V23311JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/29/22 23:19 V23311JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/29/22 23:19 V23311JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/29/22 23:19 V23311JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/29/22 23:19 V23311JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/29/22 23:19 V23311JLB
25.7 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/29/22 23:19 V23311JLB
8.16 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/29/22 23:19 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 26 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2
97638 Matrix:
8/16/2022 15:04
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00 V23323 08/30/22 09:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/29/22 23:19 V23311JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/29/22 23:19 V23311JLB
2.40 µg/L 0.210 0.500o-Xylene 1 08/29/22 23:19 V23311JLB
91.8 µg/L 0.420 1.00m,p-Xylene 1 08/29/22 23:19 V23311JLB
94.2 µg/L 0.210 0.500Xylene (Total)1 08/29/22 23:19 V23311
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%08/29/22 23:191 JLB V23311
Surrogate: Dibromofluoromethane 97.6 Limits: 70-130%08/29/22 23:191 JLB V23311
Surrogate: 1,2-Dichloroethane - d4 105 Limits: 70-130%08/29/22 23:191 JLB V23311
Surrogate: Toluene-d8 111 Limits: 70-130%08/29/22 23:191 JLB V23311
Surrogate: 4-Bromofluorobenzene 99.0 Limits: 70-130%08/30/22 15:1810 JLB V23324
Surrogate: Dibromofluoromethane 96.0 Limits: 70-130%08/30/22 15:1810 JLB V23324
Surrogate: 1,2-Dichloroethane - d4 94.8 Limits: 70-130%08/30/22 15:1810 JLB V23324
Surrogate: Toluene-d8 97.6 Limits: 70-130%08/30/22 15:1810 JLB V23324
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V23312 08/30/22 14:00
<0.00345 µg/L 0.00345 0.0209
1,2-Dibromoethane 1 08/30/22 16:42 V23403JLK
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 27 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:MW-2
97638 Matrix:
8/16/2022 15:04
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
1180 µg/L 115 500Aliphatic C5-C8 (Adjusted)10 08/24/22 09:39
185 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 08/24/22 08:15
421 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 08/24/22 08:15
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V23058 08/23/22 08:00
1880 µg/L 115 500Aliphatic C5-C8 10 08/24/22 09:39 V23059TBL
791 µg/L 25.8 50.0Aliphatic C9-C12 1 08/24/22 08:15 V23059TBL
421 µg/L 4.02 50.0Aromatic C9-C10 1 08/24/22 08:15 V23059TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)77.7 Limits: 70-130%08/24/22 08:151 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)77.7 Limits: 70-130%08/24/22 08:151 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)85.0 Limits: 70-130%08/24/22 09:3910 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)80.2 Limits: 70-130%08/24/22 09:3910 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 28 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1
97639 Matrix:
8/17/2022 10:54
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 08/29/22 23:43 6200BJLB
0.020 mg/L 0.002 0.006Lead 1 08/24/22 16:34 6010DMMR
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 29 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1
97639 Matrix:
8/17/2022 10:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
11.5 µg/L 1.80 10.0Acetone 1 08/29/22 23:43 V23311JLB
5.50 µg/L 0.180 0.500Benzene 1 08/29/22 23:43 V23311JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 08/29/22 23:43 V23311JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 08/29/22 23:43 V23311JLB
3.03 µg/L 0.160 0.500Bromodichloromethane 1 08/29/22 23:43 V23311JLB
<1.50 µg/L 1.50 5.00Bromoform 1 08/29/22 23:43 V23311JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 08/29/22 23:43 V23311JLB
1.73 µg/L 0.180 0.500n-Butylbenzene 1 08/29/22 23:43 V23311JLB
0.574 µg/L 0.200 0.500
sec-Butyl benzene 1 08/29/22 23:43 V23311JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 08/29/22 23:43 V23311JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 08/29/22 23:43 V23311JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 08/29/22 23:43 V23311JLB
1.15 µg/L 0.190 0.500Chlorodibromomethane 1 08/29/22 23:43 V23311JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 08/29/22 23:43 V23311JLB
9.36 µg/L 0.220 0.500Chloroform 1 08/29/22 23:43 V23311JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 08/29/22 23:43 V23311JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 08/29/22 23:43 V23311JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 08/29/22 23:43 V23311JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 08/29/22 23:43 V23311JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 08/29/22 23:43 V23311JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 08/29/22 23:43 V23311JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 08/29/22 23:43 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 30 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1
97639 Matrix:
8/17/2022 10:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 08/29/22 23:43 V23311JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 08/29/22 23:43 V23311JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 08/29/22 23:43 V23311JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 08/29/22 23:43 V23311JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 08/29/22 23:43 V23311JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 08/29/22 23:43 V23311JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 08/29/22 23:43 V23311JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 08/29/22 23:43 V23311JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 08/29/22 23:43 V23311JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 08/29/22 23:43 V23311JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 08/29/22 23:43 V23311JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 08/29/22 23:43 V23311JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 08/29/22 23:43 V23311JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 08/29/22 23:43 V23311JLB
<42.0 µg/L 42.0 200Ethanol 1 08/29/22 23:43 V23311JLB
14.1 µg/L 0.170 0.500
Ethylbenzene 1 08/29/22 23:43 V23311JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 08/29/22 23:43 V23311JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 08/29/22 23:43 V23311JLB
2.61 µg/L 0.180 0.500Isopropylbenzene 1 08/29/22 23:43 V23311JLB
0.268 J µg/L 0.089 0.5004-Isopropyl toluene 1 08/29/22 23:43 V23311JLB
2.26 J µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 08/29/22 23:43 V23311JLB
0.713 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 08/29/22 23:43 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 31 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1
97639 Matrix:
8/17/2022 10:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 08/29/22 23:43 V23311JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 08/29/22 23:43 V23311JLB
4.16 µg/L 0.470 1.00Naphthalene 1 08/29/22 23:43 V23311JLB
5.07 µg/L 0.190 0.500n-Propylbenzene 1 08/29/22 23:43 V23311JLB
<0.220 µg/L 0.220 0.500Styrene 1 08/29/22 23:43 V23311JLB
5.86 J µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 08/29/22 23:43 V23311JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 08/29/22 23:43 V23311JLB
12.0 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 08/29/22 23:43 V23311JLB
<0.280 µg/L 0.280 10.0
tert-Amyl Methyl Ether (TAME)1 08/29/22 23:43 V23311JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 08/29/22 23:43 V23311JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 08/29/22 23:43 V23311JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 08/29/22 23:43 V23311JLB
15.0 µg/L 0.220 0.500Toluene 1 08/29/22 23:43 V23311JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 08/29/22 23:43 V23311JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 08/29/22 23:43 V23311JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 08/29/22 23:43 V23311JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 08/29/22 23:43 V23311JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 08/29/22 23:43 V23311JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 08/29/22 23:43 V23311JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 08/29/22 23:43 V23311JLB
10.5 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 08/29/22 23:43 V23311JLB
4.70 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 08/29/22 23:43 V23311JLB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 32 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1
97639 Matrix:
8/17/2022 10:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V23310 08/29/22 14:00
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 08/29/22 23:43 V23311JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 08/29/22 23:43 V23311JLB
7.56 µg/L 0.210 0.500o-Xylene 1 08/29/22 23:43 V23311JLB
41.4 µg/L 0.420 1.00m,p-Xylene 1 08/29/22 23:43 V23311JLB
49.0 µg/L 0.210 0.500Xylene (Total)1 08/29/22 23:43 V23311
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%08/29/22 23:431 JLB V23311
Surrogate: Dibromofluoromethane 98.4 Limits: 70-130%08/29/22 23:431 JLB V23311
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%08/29/22 23:431 JLB V23311
Surrogate: Toluene-d8 112 Limits: 70-130%08/29/22 23:431 JLB V23311
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 33 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-231-0060
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI #5285 Received : 08/19/2022
Moore's Citgo
Report Date : 09/01/2022
Sample ID :
Lab No :
Sampled:TW-1
97639 Matrix:
8/17/2022 10:54
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
186 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 08/24/22 08:39
123 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 08/24/22 08:39
36.6 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 08/24/22 08:39
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V23058 08/23/22 08:00
206 µg/L 11.5 50.0Aliphatic C5-C8 1 08/24/22 08:39 V23059TBL
223 µg/L 25.8 50.0Aliphatic C9-C12 1 08/24/22 08:39 V23059TBL
36.6 J µg/L 4.02 50.0Aromatic C9-C10 1 08/24/22 08:39 V23059TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)83.2 Limits: 70-130%08/24/22 08:391 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)87.0 Limits: 70-130%08/24/22 08:391 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Page 34 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Metals Analysis
6010D
V23117QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V23057
Associated Lab Samples: 97638, 97639
LRB-V23057 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
08/24/22 15:580.0060.002<0.002mg/LLead
LCS-V23057Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1090.1090.100mg/LLead 80-120
V 97683-MS-V23057 V 97683-MSD-V23057Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.109 1040.1100.1000.1000.005mg/LLead 105 75-125 0.9 20.0
V 97683-PDS-V23057Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
08/24/22 16:181000.252mg/LLead
Page 1 of 12Date:09/01/2022 03:38 PM
Page 35 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23311QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23310
Associated Lab Samples: 97637, 97638, 97639
LRB-V23310 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/29/22 19:4110.01.80<1.80µg/LAcetone
08/29/22 19:410.5000.180<0.180µg/LBenzene
08/29/22 19:410.5000.210<0.210µg/LBromobenzene
08/29/22 19:411.000.420<0.420µg/LBromochloromethane
08/29/22 19:410.5000.160<0.160µg/LBromodichloromethane
08/29/22 19:415.001.50<1.50µg/LBromoform
08/29/22 19:411.000.280<0.280µg/LBromomethane
08/29/22 19:410.5000.180<0.180µg/Ln-Butylbenzene
08/29/22 19:410.5000.200<0.200µg/Lsec-Butyl benzene
08/29/22 19:412.000.920<0.920µg/Ltert-Butyl benzene
08/29/22 19:410.5000.180<0.180µg/LCarbon Tetrachloride
08/29/22 19:410.5000.190<0.190µg/LChlorobenzene
08/29/22 19:410.5000.190<0.190µg/LChlorodibromomethane
08/29/22 19:411.000.430<0.430µg/LChloroethane
08/29/22 19:410.5000.220<0.220µg/LChloroform
08/29/22 19:410.5000.220<0.220µg/LChloromethane
08/29/22 19:410.5000.200<0.200µg/L2-Chlorotoluene
08/29/22 19:410.5000.200<0.200µg/L4-Chlorotoluene
08/29/22 19:410.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
08/29/22 19:412.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
08/29/22 19:410.5000.200<0.200µg/L1,2-Dibromoethane
08/29/22 19:410.5000.230<0.230µg/LDibromomethane
08/29/22 19:410.5000.220<0.220µg/L1,2-Dichlorobenzene
08/29/22 19:410.5000.190<0.190µg/L1,3-Dichlorobenzene
08/29/22 19:410.5000.210<0.210µg/L1,4-Dichlorobenzene
08/29/22 19:415.001.20<1.20µg/LDichlorodifluoromethane
08/29/22 19:410.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 12Date:09/01/2022 03:38 PM
Page 36 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23311QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23310
Associated Lab Samples: 97637, 97638, 97639
LRB-V23310 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/29/22 19:410.5000.150<0.150µg/L1,2-Dichloroethane
08/29/22 19:410.5000.150<0.150µg/L1,1-Dichloroethene
08/29/22 19:410.5000.200<0.200µg/Lcis-1,2-Dichloroethene
08/29/22 19:410.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
08/29/22 19:410.5000.190<0.190µg/L1,2-Dichloropropane
08/29/22 19:410.5000.130<0.130µg/L1,3-Dichloropropane
08/29/22 19:412.000.210<0.210µg/L2,2-Dichloropropane
08/29/22 19:410.5000.200<0.200µg/L1,1-Dichloropropene
08/29/22 19:410.5000.210<0.210µg/Lcis-1,3-Dichloropropene
08/29/22 19:410.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
08/29/22 19:4120042.0<42.0µg/LEthanol
08/29/22 19:410.5000.170<0.170µg/LEthylbenzene
08/29/22 19:413.000.350<0.350µg/LHexachlorobutadiene
08/29/22 19:411.000.380<0.380µg/L2-Hexanone
08/29/22 19:410.5000.180<0.180µg/LIsopropylbenzene
08/29/22 19:410.5000.089<0.089µg/L4-Isopropyl toluene
08/29/22 19:415.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
08/29/22 19:411.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
08/29/22 19:411.000.078<0.078µg/L4-Methyl-2-Pentanone
08/29/22 19:412.000.330<0.330µg/LMethylene Chloride
08/29/22 19:411.000.470<0.470µg/LNaphthalene
08/29/22 19:410.5000.190<0.190µg/Ln-Propylbenzene
08/29/22 19:410.5000.220<0.220µg/LStyrene
08/29/22 19:4110.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
08/29/22 19:4110.00.350<0.350µg/Ltert-Butyl formate (TBF)
08/29/22 19:4110.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
08/29/22 19:4110.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 3 of 12Date:09/01/2022 03:38 PM
Page 37 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23311QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23310
Associated Lab Samples: 97637, 97638, 97639
LRB-V23310 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/29/22 19:410.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
08/29/22 19:410.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
08/29/22 19:410.5000.220<0.220µg/LTetrachloroethene
08/29/22 19:410.5000.220<0.220µg/LToluene
08/29/22 19:410.5000.380<0.380µg/L1,2,3-Trichlorobenzene
08/29/22 19:410.5000.310<0.310µg/L1,2,4-Trichlorobenzene
08/29/22 19:410.5000.160<0.160µg/L1,1,1-Trichloroethane
08/29/22 19:410.5000.096<0.096µg/L1,1,2-Trichloroethane
08/29/22 19:410.5000.180<0.180µg/LTrichloroethene
08/29/22 19:410.5000.180<0.180µg/LTrichlorofluoromethane
08/29/22 19:410.5000.270<0.270µg/L1,2,3-Trichloropropane
08/29/22 19:410.5000.190<0.190µg/L1,2,4-Trimethylbenzene
08/29/22 19:410.5000.180<0.180µg/L1,3,5-Trimethylbenzene
08/29/22 19:415.001.00<1.00µg/LVinyl Acetate
08/29/22 19:410.5000.170<0.170µg/LVinyl Chloride
08/29/22 19:410.5000.210<0.210µg/Lo-Xylene
08/29/22 19:411.000.420<0.420µg/Lm,p-Xylene
08/29/22 19:4110.01.00<1.00µg/L3,3-Dimethyl-1-butanol
08/29/22 19:414-Bromofluorobenzene (S)102 70-130
08/29/22 19:41Dibromofluoromethane (S)102 70-130
08/29/22 19:411,2-Dichloroethane - d4 (S)104 70-130
08/29/22 19:41Toluene-d8 (S)105 70-130
Page 4 of 12Date:09/01/2022 03:38 PM
Page 38 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23311QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23310
LCS-V23310 LCSD-V23310Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
36.8 92.094.537.840.0µg/LAcetone 40-160 2.6 20.0
18.7 93.596.019.220.0µg/LBenzene 70-130 2.6 20.0
20.9 10510320.620.0µg/LBromobenzene 70-130 1.4 20.0
19.6 98.098.019.620.0µg/LBromochloromethane 70-130 0.0 20.0
19.1 95.598.019.620.0µg/LBromodichloromethane 70-130 2.5 20.0
20.0 10010521.020.0µg/LBromoform 70-130 4.8 20.0
21.4 10711122.220.0µg/LBromomethane 60-140 3.6 20.0
21.4 10710821.520.0µg/Ln-Butylbenzene 70-130 0.4 20.0
21.6 10810621.220.0µg/Lsec-Butyl benzene 70-130 1.8 20.0
20.8 10410420.820.0µg/Ltert-Butyl benzene 70-130 0.0 20.0
18.4 92.095.519.120.0µg/LCarbon Tetrachloride 70-130 3.7 20.0
19.7 98.510220.320.0µg/LChlorobenzene 70-130 3.0 20.0
21.1 10610420.820.0µg/LChlorodibromomethane 70-130 1.4 20.0
19.9 99.599.019.820.0µg/LChloroethane 60-140 0.5 20.0
19.0 95.099.019.820.0µg/LChloroform 70-130 4.1 20.0
17.0 85.085.517.120.0µg/LChloromethane 60-140 0.5 20.0
20.6 10310420.820.0µg/L2-Chlorotoluene 70-130 0.9 20.0
21.0 10510621.220.0µg/L4-Chlorotoluene 70-130 0.9 20.0
19.9 99.510220.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.9 20.0
19.2 96.097.019.420.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.0 20.0
20.6 10310520.920.0µg/L1,2-Dibromoethane 70-130 1.4 20.0
18.6 93.094.018.820.0µg/LDibromomethane 70-130 1.0 20.0
21.4 10710621.220.0µg/L1,2-Dichlorobenzene 70-130 0.9 20.0
20.6 10310621.120.0µg/L1,3-Dichlorobenzene 70-130 2.3 20.0
20.9 10510521.020.0µg/L1,4-Dichlorobenzene 70-130 0.4 20.0
18.0 90.092.018.420.0µg/LDichlorodifluoromethane 60-140 2.1 20.0
Page 5 of 12Date:09/01/2022 03:38 PM
Page 39 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23311QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23310
LCS-V23310 LCSD-V23310Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.9 94.597.019.420.0µg/L1,1-Dichloroethane 70-130 2.6 20.0
18.6 93.095.519.120.0µg/L1,2-Dichloroethane 70-130 2.6 20.0
18.6 93.098.519.720.0µg/L1,1-Dichloroethene 70-130 5.7 20.0
18.9 94.598.019.620.0µg/Lcis-1,2-Dichloroethene 70-130 3.6 20.0
18.9 94.598.519.720.0µg/Ltrans-1,2-Dichloroethene 70-130 4.1 20.0
19.0 95.097.519.520.0µg/L1,2-Dichloropropane 70-130 2.5 20.0
20.1 10110521.020.0µg/L1,3-Dichloropropane 70-130 4.3 20.0
18.6 93.097.519.520.0µg/L2,2-Dichloropropane 70-130 4.7 20.0
18.4 92.095.519.120.0µg/L1,1-Dichloropropene 70-130 3.7 20.0
19.0 95.097.519.520.0µg/Lcis-1,3-Dichloropropene 70-130 2.5 20.0
19.0 95.097.019.420.0µg/Ltrans-1,3-Dichloropropene 70-130 2.0 20.0
457 91.4100500500µg/LEthanol 60-140 8.9 20.0
19.8 99.010220.420.0µg/LEthylbenzene 70-130 2.9 20.0
20.6 10310120.120.0µg/LHexachlorobutadiene 70-130 2.4 20.0
19.7 98.510020.020.0µg/L2-Hexanone 60-140 1.5 20.0
21.4 10710420.820.0µg/LIsopropylbenzene 70-130 2.8 20.0
21.6 10810921.820.0µg/L4-Isopropyl toluene 70-130 0.9 20.0
20.2 10110120.220.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.0 20.0
19.3 96.599.019.820.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.5 20.0
18.8 94.098.019.620.0µg/L4-Methyl-2-Pentanone 60-140 4.1 20.0
19.2 96.095.019.020.0µg/LMethylene Chloride 70-130 1.0 20.0
21.6 10810921.720.0µg/LNaphthalene 70-130 0.4 20.0
21.2 10610721.320.0µg/Ln-Propylbenzene 70-130 0.4 20.0
21.0 10510721.420.0µg/LStyrene 70-130 1.8 20.0
25.6 64.074.529.840.0µg/Ltert-Butyl Alcohol (TBA)40-140 15.1 20.0
41.3 10310542.040.0µg/Ltert-Butyl formate (TBF)40-140 1.6 20.0
Page 6 of 12Date:09/01/2022 03:38 PM
Page 40 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23311QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23310
LCS-V23310 LCSD-V23310Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
18.9 94.592.518.520.0µg/Ltert-Amyl Alcohol (TAA)40-140 2.1 20.0
39.7 99.210140.240.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.2 20.0
19.8 99.010220.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.9 20.0
20.1 10110220.320.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.9 20.0
20.2 10110220.320.0µg/LTetrachloroethene 70-130 0.4 20.0
18.8 94.095.019.020.0µg/LToluene 70-130 1.0 20.0
23.1 11610921.820.0µg/L1,2,3-Trichlorobenzene 70-130 5.7 20.0
22.3 11211022.020.0µg/L1,2,4-Trichlorobenzene 70-130 1.3 20.0
18.4 92.096.519.320.0µg/L1,1,1-Trichloroethane 70-130 4.7 20.0
19.7 98.510020.020.0µg/L1,1,2-Trichloroethane 70-130 1.5 20.0
19.3 96.598.019.620.0µg/LTrichloroethene 70-130 1.5 20.0
18.7 93.597.519.520.0µg/LTrichlorofluoromethane 60-140 4.1 20.0
21.4 10710420.820.0µg/L1,2,3-Trichloropropane 70-130 2.8 20.0
21.2 10610721.420.0µg/L1,2,4-Trimethylbenzene 70-130 0.9 20.0
21.2 10610821.520.0µg/L1,3,5-Trimethylbenzene 70-130 1.4 20.0
18.8 94.010220.320.0µg/LVinyl Acetate 60-140 7.6 20.0
18.7 93.595.519.120.0µg/LVinyl Chloride 60-140 2.1 20.0
20.1 10110320.520.0µg/Lo-Xylene 70-130 1.9 20.0
42.9 10711043.940.0µg/Lm,p-Xylene 70-130 2.3 20.0
18.2 91.010520.920.0µg/L3,3-Dimethyl-1-butanol 70-130 13.8 20.0
10297.84-Bromofluorobenzene (S)70-130
97.498.0Dibromofluoromethane (S)70-130
1041011,2-Dichloroethane - d4 (S)70-130
104105Toluene-d8 (S)70-130
Page 7 of 12Date:09/01/2022 03:38 PM
Page 41 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V23324QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V23323
Associated Lab Samples: 97638
LRB-V23323 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/30/22 11:410.5000.180<0.180µg/LBenzene
08/30/22 11:410.5000.170<0.170µg/LEthylbenzene
08/30/22 11:411.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
08/30/22 11:4110.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
08/30/22 11:410.5000.220<0.220µg/LToluene
08/30/22 11:414-Bromofluorobenzene (S)98.0 70-130
08/30/22 11:41Dibromofluoromethane (S)97.4 70-130
08/30/22 11:411,2-Dichloroethane - d4 (S)95.4 70-130
08/30/22 11:41Toluene-d8 (S)97.4 70-130
LCS-V23323 LCSD-V23323Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.6 10310621.220.0µg/LBenzene 70-130 2.8 20.0
20.2 10110520.920.0µg/LEthylbenzene 70-130 3.4 20.0
21.2 10610921.720.0µg/LMethyl tert-butyl ether (MTBE)70-130 2.3 20.0
19.0 95.011021.920.0µg/Ltert-Amyl Alcohol (TAA)40-140 14.1 20.0
20.4 10210521.020.0µg/LToluene 70-130 2.8 20.0
98.496.64-Bromofluorobenzene (S)70-130
98.298.2Dibromofluoromethane (S)70-130
96.897.01,2-Dichloroethane - d4 (S)70-130
97.697.4Toluene-d8 (S)70-130
Page 8 of 12Date:09/01/2022 03:38 PM
Page 42 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Total Petroleum Hydrocarbons - Volatile
8015C GRO
V23064QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V23062
Associated Lab Samples: 97628, 97629, 97630, 97631, 97632, 97633, 97634, 97635
LRB-V23062 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/24/22 09:295.002.07<2.07mg/KgGasoline Range Organics (C6-C10)
08/24/22 09:29a,a,a-Trifluorotoluene (S)127 50-137
LCS-V23062 LCSD-V23062Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
47.8 95.696.248.150.0mg/KgGasoline Range Organics (C6-C10)41-138 0.6 20
114126a,a,a-Trifluorotoluene (S)50-137
Page 9 of 12Date:09/01/2022 03:38 PM
Page 43 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V23403QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V23312
Associated Lab Samples: 97638
LRB-V23312 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
08/30/22 15:360.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V23312 LCSD-V23312Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.245 98.097.60.2440.250µg/L1,2-Dibromoethane 70-130 0.4 20.0
V 97714-DUP-V23312Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 08/30/22 18:220.0<0.0206< 0.0206µg/L1,2-Dibromoethane
V 97713-MS-V23312Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.256 99.20.258< 0.00340µg/L1,2-Dibromoethane 70-130
Page 10 of 12Date:09/01/2022 03:38 PM
Page 44 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V23059QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V23058
Associated Lab Samples: 97638, 97639
LRB-V23058 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
08/23/22 17:3450.011.5<11.5µg/LAliphatic C5-C8
08/23/22 17:3450.025.8<25.8µg/LAliphatic C9-C12
08/23/22 17:3450.04.02<4.02µg/LAromatic C9-C10
08/23/22 17:342,5-Dibromotoluene (FID) (S)89.3 70-130
08/23/22 17:342,5-Dibromotoluene (PID) (S)97.5 70-130
LCS-V23058 LCSD-V23058Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
274 91.389.6269300µg/LAliphatic C5-C8 70-130 1.8 50.0
328 109108324300µg/LAliphatic C9-C12 70-130 1.2 50.0
105 105117117100µg/LAromatic C9-C10 70-130 10.8 50.0
87.389.82,5-Dibromotoluene (FID) (S)70-130
92.895.32,5-Dibromotoluene (PID) (S)70-130
Page 11 of 12Date:09/01/2022 03:38 PM
Page 45 of 49
Quality Control Data
22-231-0060Report No:
Project Description:
Client ID:Geological Resources, Inc.
Moore's Citgo
Total Organic Carbon - Walkley Black
WALK-BLACK
L634679QC Analytical Batch:
Analysis Method:
Analysis Description:
Associated Lab Samples: 97631, 97635, 97636
LRB Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
08/29/22 14:300.05< 0.05%Total Organic Carbon
V 97631-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 08/29/22 14:300.00.200.20%Total Organic Carbon
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Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-231-0060
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 2.9C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Danyale Love Date & Time:08/22/2022 17:07:21
Special precautions or instructions included?
Comments:
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