FA-3242_29421_CA_MRP_20200609

GROUNDWATER MONITORING REPORT

JOHNSON’S GAS & GROCERY
8853 CLINTON ROAD, STEDMAN, CUMBERLAND COUNTY, NC 28391
GROUNDWATER INCIDENT #: 29421
FACILITY ID #: 0-034292

JUNE 9, 2020

UST OWNER/OPERATOR:
LEVIE JOHNSON
8853 CLINTON ROAD, STEDMAN, NC 28391
PHONE NUMBER: [phone]

PROPERTY OWNER:
SAME AS UST OWNER

CONSULTANT:
HENRY NEMARGUT ENGINEERING SERVICES
2211 CHESTNUT STREET, WILMINGTON, NC 28405
PHONE NUMBER: [phone]

RELEASE INFORMATION:
DATE DISCOVERED: 9/18/2006
ESTIMATED QUANTITY OF RELEASE: UNKNOWN
CAUSE OF RELEASE: UNKNOWN
SOURCE OF RELEASE: UST SYSTEM
SIZE AND CONTENTS: (1) 6,500 & (1) 4,500 GALLON GASOLINE
LATITUDE: N 35o 0.184'; LONGITUDE: W 78o 39.409’

The Monitoring Report for this site has been prepared by Henry Nemargut Engineering Services. All
engineering work performed on this project was conducted under my direct supervision:

Henry Nemargut, P.E.
Henry Nemargut Engineering Services
North Carolina License #17669

June 9, 2020

Levie Johnson
8853 Clinton Road
Stedman, NC 28391

Reference: Groundwater Monitoring Report
Johnson’s Gas & Grocery
8853 Clinton Road
Stedman, Cumberland County, North Carolina 28391
Incident #29421; Facility ID #0-034292

Dear Mr. Johnson:

Please find enclosed a report summarizing groundwater monitoring and analyses for the above
referenced facility. Additional activities included a receptor survey update. All activities were
conducted in accordance with the NCDEQ guidelines and the requirements of 15A NCAC 2L
.0115.

If you have questions regarding this report, please contact our office.

Sincerely,

Henry Nemargut, P.E.
Henry Nemargut Engineering Services

TABLE OF CONTENTS

Section Page

1.0 Introduction and Background
1.1 Introduction 1
1.2 Scope of Services 1

2.0 Field Activities 2
2.1 Groundwater Flow Direction and Gradient 2
2.2 Monitor Well Sampling and Analysis 2
2.3 Supply Well Sampling and Analysis 3
2.4 Receptor Well Survey Update 3

3.0 Conclusions and Recommendations
3.1 General Summary 5
3.2 Recommendations 5
3.3 Limitations 6

LIST OF FIGURES

Figure 1: Project Location
Figure 2: Site Layout and Monitor Well Locations
Figure 3: Potentiometric Surface Map (5/3/13)
Figure 4: Total 6200B Concentration Map
Figure 5: Receptor Well Map

LIST OF TABLES

Table 1: Monitoring Well Information and Groundwater Elevations
Table 2: Summary of Groundwater Laboratory Analytical Results
Table 3: Supply Well Information

APPENDICES

Appendix A: Groundwater Laboratory Analytical Results

Page - 1
GROUNDWATER MONITORING REPORT
JOHNSON’S GAS & GROCERY
8853 Clinton Road
STEDMAN, NORTH CAROLINA 28391

1.0 Introduction and Background

1.1 Introduction

Levie Johnson owned a tank system at the facility referred to as Johnson’s Gas & Grocery located at
8853 Clinton Road in Stedman, NC. Figure 1 illustrates the location of the release site on the U.S.G.S.
Stedman Topographic Quadrangle. Figure 2 illustrates the layout of the monitor wells currently in place
at the site. All USTs and the former store building were removed by the NCDOT during a recent
highway expansion.

A correction action plan prepared for this site dated April 15, 2010 was approved by the NCDEQ
Fayetteville Regional Office. The approved CAP specified groundwater remediation via air
sparging/SVE to protect nearby receptors. The system was shut down in 2013 as directed by the NC-
DOT.

1.2 Scope of Services

This Groundwater monitoring report contains documentation concerning the following activities which
have been conducted at this facility:

o A monitoring well sampling event conducted on July 11, 2020, consisting of sampling of 2
monitoring wells on and off-site.

o Supply well sampling of the Levie Johnson rental property conducted on July 11, 2019.

o Laboratory analyses of groundwater samples conducted by Pace Analytical, Inc.

o A receptor survey update in the vicinity of the release source at this facility.

2.0 Field Activities

2.1 Ground Water Flow Direction and Gradient

In order to estimate the groundwater flow direction in the vicinity of the petroleum release, elevations of
the monitor well casings were measured using surveying equipment. Static water levels were obtained
from each of the wells and the data was used to compute a potentiometric surface map which is included
as Figure 3.

Page - 2
Groundwater data and monitoring well information, which are summarized in Table 1, were obtained to
estimate the hydraulic gradient at the project site; unfortunately, a potentiometric map could not be
generated since not enough wells were located due to the recent DOT highway expansion.

2.2 Monitor Well Sampling and Analyses

On May 2-3, 2013, twenty-seven monitor and recovery wells were sampled for analyses utilizing EPA
Methods 6200B plus MTBE, IPE, & EDB. Before sampling, the monitor wells were purged by
removing a minimum of three well volumes to ensure that the samples were representative of the actual
groundwater conditions. The monitor wells were developed using disposable plastic balers suspended
with unused nylon string. Following development of the groundwater monitoring wells, samples were
obtained from the disposable balers.

All samples were placed in laboratory supplied glassware, labeled with sample location, analysis to be
performed, time, date and sampler's name. The sample jars were then immediately placed in a cooler,
chilled with ice to approximately 4oC in preparation of transportation to an analytical laboratory
utilizing EPA approved chain-of-custody procedures.

Laboratory analytical results indicate the presence of 5 compounds above laboratory detection limits;
however, no compounds were identified above the current listed 2L Standards in the monitor well
network at this site. Total 6200B compounds were detected at a maximum level of 15.43 ug/l in MW-6.
Table 2 summarizes the laboratory analytical results, and Appendix A contains a copy of the laboratory
analytical report and chain of custody records. Figure 4 contains a 6200B concentration map.

2.3 Supply Well Sampling and Analyses

On May 3, 2013, the supply wells at the Levie Johnson rental property at 8854 Clinton Road was
sampled for analyses utilizing EPA Methods 6200B plus MTBE, IPE, & EDB. Before sampling, the
supply wells were purged by pumping from the well for approximately 10 minutes to ensure that the
samples were representative of the actual groundwater conditions. After pumping, the flowrate was
reduced for collection of samples. Samples were obtained from spigots closest to the supply wells.

All samples were placed in laboratory supplied glassware, labeled with sample location, analysis to be
performed, time, date and sampler's name. The sample jars were then immediately placed in a cooler,
chilled with ice to approximately 4oC in preparation of transportation to an analytical laboratory
utilizing EPA approved chain-of-custody procedures.

Laboratory analytical results failed to indicate the presence of any 6200B compounds above 2L
Standards in the sample from the Levie Johnson supply well (SW-2). Chloromethane was noted at a
level of 1.1 ug/l in the well located at 8854 Clinton road (SW-2); below its 2L Standard of 3 ug/l. Table
2 summarizes the laboratory analytical results, and Appendix A contains a copy of the laboratory
analytical report and chain of custody records.

Page - 3
2.4 Receptor Survey Update

In July, 2019, a local well survey was conducted in the vicinity of the release site by interviewing
nearby residents and business owners. The results of this survey indicate that 1 commercial facility and
13 private residences within 1,000’ of the release source have in-service water supply wells used for
consumptive purposes. One out of service irrigation well (IW-1) exists at a distance of 170’ from the
dispenser island release source owned by Levie Johnson (formerly a supply well). The new house on
the Johnson property is connected to municipal water supply. Table 3 contains information including
ownership and distance from the release source for the water supply wells identified during this well
survey update. Figure 5 depicts the locations of the supply wells identified on a Cumberland County
Tax Map.

3.0 Conclusions and Recommendations

3.1 General Summary

A groundwater monitoring sampling event has been conducted at the Johnson’s Gas & Grocery facility
located at 8853 Clinton Road in Stedman, NC. From a review of all information gathered during this
project, Henry Nemargut Engineering Services makes the following conclusions:

o (2) groundwater monitoring and (1) supply well near this release site were sampled to monitor
contaminant levels following NC-DOT highway expansion at this site.

o 5 petroleum compounds were detected in monitoring wells above laboratory detection limits but
below 2L Standards in monitoring well MW-6. No GCL violations were noted at the site.

o No compounds were detected in the Levie Johnson rental property supply well SW-2 above 2L
Standards. Chloromethane was noted at a level of 1.1 ug/l in this well located at 8854 Clinton
road (SW-2); below its 2L Standard of 3 ug/l.

o In July, 2019, a local well survey was conducted in the vicinity of the release site by
interviewing nearby residents and business owners. The results of this survey indicate that 1
commercial facility and 13 private residences within 1,000’ of the release source have in-service
water supply wells used for consumptive purposes.

3.2 Recommendations

From a review of all information gathered during this remediation project, Henry Nemargut Engineering
Services makes the following recommendations for corrective action:

A copy of this monitoring report has been forwarded to:

Page - 4
Mr. James Brown
NCDEQ-FRO UST Section
Systel Building, Suite 714
Fayetteville, NC 28301

3.3 Limitations

This report has been prepared for the exclusive use of Levie Johnson for the specific application to the
referenced site located in Cumberland County, North Carolina. The assessment was conducted based on
the scope of work and level of effort desired by the client. Our findings have been developed in
accordance with generally accepted standards in the practice of Groundwater Monitoring in the State of
North Carolina, available information and our professional judgment. No other warranty is expressed or
implied.

The data presented in this report are indicative of conditions that existed at the precise locations sampled
and at the time the samples were collected. Additionally, the data obtained from the samples would be
interpreted as meaningful with respect to the parameters indicated in the laboratory reports. No
additional information can be logically inferred from this data.

FIGURES

TABLES
TABLE 1Monitoring Well Information and Groundwater ElevationsJohnson's Gas & Grocery, 8853 Clinton Road, Stedman, NC 28391Well Number Top of Casing Elevation Top of Screen Elevation Bottom of Screen Elevation Depth to Water Groundwater ElevationMW-6 99.88 94.88 84.88 10.39 89.49MW-12 100.26 95.26 85.26 11.84 88.42MW-13 101.10 91.10 81.10 Not Found #VALUE!MW-14 101.03 91.03 81.03 Not Found #VALUE!MW-15 102.07 92.07 82.07 Not Found #VALUE!MW-16 102.85 92.85 82.85 Not Found #VALUE!MW-18 102.23 92.23 82.23 Not Found #VALUE!All measurements taken in feet and based on an arbitrary benchmark of 100.00 feet at MW-1 Groundwater levels measured on 05/3/2013
TABLE 2Summary of Groundwater Laboratory Analytical ResultsJohnson's Gas & Grocery8853 Clinton Road, Stedman, North Carolina 28391CONSTITUENT MW-6 MW-12 SW-2 GCL 2L StandardDate7/11/2019 7/11/2019 7/11/2019Benzene BDL BDL BDL 5,000 1Toluene BDL BDL BDL 257,500 600Ethylbenzene BDL BDL BDL 84,500 600Xylenes (Total) 1 BDL BDL 87,500 500BTEX(Total) 1 0 0 NSE NSENaphthalene 5 BDL BDL 15,500 6Isopropylbenzene 0.66 BDL BDL 25,000 70p-Isopropyltoluene BDL BDL BDL NSE NSEn-Propylbenzene 0.57 BDL BDL 30,000 70Acetone BDL BDL BDL 700,000 7001,2-Dichloroethane BDL BDL BDL 70,000 701,2,4-Trimethylbenzene 9.2 BDL BDL 28,500 4001,3,5-Trimethylbenzene BDL BDL BDL 25,000 400Isopropyl Ether (IPE) BDL BDL BDL 70,000 70MTBE BDL BDL BDL 200,000 20Chloromethane BDL BDL 1.1 3,000 3n-Butylbenzene BDL BDL BDL 6,900 70tert-Butylbenzene BDL BDL BDL 15,000 70Methyl Isobutyl Ketone BDL BDL BDL NSE NSEMethyl Butyl Ketone BDL BDL BDL NSE NSEMethyl Ethyl Ketone BDL BDL BDL 4,000 4000000TOTAL 6200B15.4301.1All results reported in micrograms per liter (ug/l); only detected compounds are listed.2L Standard = NCAC listed 2L Standard for groundwater.BDL = Below Detection LimitsN/A = Not AnalyzedNSE = No Standard Established
WellIdentification IW-1 SW-2 SW-3 SW-4 SW-5Owner Name Levie & Helen Johnson Levie & Helen Johnson City of Fayetteville Michael & Carla Barrett Gregory NunneryProperty 8847 Clinton Rd 8842 Clinton Rd 8956 Clinton Rd 9010 Clinton Rd 144 John Nunnery RdAddress Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391Owner Address 8853 Clinton Rd 8853 Clinton Rd 433 Hay St 9010 Clinton Rd 144 John Nunnery RdSteadman, NC 28391 Steadman, NC 28391 Fayetteville, NC 28301 Steadman, NC 28391 Steadman, NC 28391Occupant Levie & Helen Johnson Rental City of Fayetteville Michael & Carla Barrett Gregory NunneryMAPID # 1405-26-5446 1405-25-4991 1405-16-9146 1405-35-4601 1405-36-4297Use Out of Service Irrigation Potable Potable Potable PotableDistance 168' 475' 585' 995' 720'City Water? YES YES YES YES YESDepth of Well Unknown Unknown Unknown Unknown UnknownWell Diameter Unknown Unknown Unknown Unknown UnknownWell Yield Unknown Unknown Unknown Unknown UnknownDepth to Pump Unknown Unknown Unknown Unknown UnknownDepth of Casing Unknown Unknown Unknown Unknown UnknownStatic Water Unknown Unknown Unknown Unknown UnknownRosemart 88853 CLINTON RD, STEADMAN NCTABLE 3SUPPLY WELL INFORMATION1,500' RADIUSJOHNSON'S GAS AND GROCERY
WellIdentification SW-6 SW-7 SW-8 SW-9 SW-10Owner Name Jewell Stanley Roy Hall Karen Briza Dale Autry Randy StampsProperty Address 153 John Nunnery Rd 160 John Nunnery Rd 200 John Nunnery Rd 207 John Nunnery Rd 221 John Nunnery RdSteadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391Owner Address 1009 Open Field Dr PO Box 105 200 John Nunnery Rd 207 John Nunnery Rd 221 John Nunnery RdGarner, NC 27529 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391Occupant Jewell Stanley Roy Hall Karen Briza Dale Autry Randy StampsMAPID # 1405-36-1346 1405-36-4318 1405-36-4506 1405-36-1509 1405-36-0775Use Potable Potable Potable Potable PotableDistance 500' 830' 880' 640' 760'City Water? YES YES YES YES YESDepth of Well Unknown Unknown Unknown Unknown UnknownWell Diameter Unknown Unknown Unknown Unknown UnknownWell Yield Unknown Unknown Unknown Unknown UnknownDepth to Pump Unknown Unknown Unknown Unknown UnknownDepth of Casing Unknown Unknown Unknown Unknown UnknownStatic Water Unknown Unknown Unknown Unknown UnknownRosemart 8TABLE 3 (continued)SUPPLY WELL INFORMATION - 1,500' RADIUS8853 CLINTON RD, STEADMAN NC
WellIdentification SW-11 SW-12 SW-13 SW-14 SW-15Owner Name Randy Stamps Virginia Mavropoulos Jerry & Tammy Taylor Georgia Johnson Virginia MavropoulosProperty Address 241 John Nunnery Rd 253 John Nunnery Rd 8869 Clinton Rd 156 Red Rose Dr 8813 Clinton RdSteadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391Owner Address 221 John Nunnery Rd 253 John Nunnery Rd 512 John Nunnery Rd 8705 Clinton Rd 253 John Nunnery RdSteadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391 Steadman, NC 28391Occupant Randy Stamps Virginia Mavropoulos Jerry & Tammy Taylor Georgia Johnson Virginia MavropoulosMAPID # 1405-36-0940 1405-37-0024 1405-26-7686 1405-26-4885 1405-26-3561Use Potable Potable Potable Potable PotableDistance 790' 920' 700' 740' 570'City Water? YES YES YES YES YESDepth of Well Unknown Unknown Unknown Unknown UnknownWell Diameter Unknown Unknown Unknown Unknown UnknownWell Yield Unknown Unknown Unknown Unknown UnknownDepth to Pump Unknown Unknown Unknown Unknown UnknownDepth of Casing Unknown Unknown Unknown Unknown UnknownStatic Water Unknown Unknown Unknown Unknown UnknownRosemart 8TABLE 3 (continued)SUPPLY WELL INFORMATION - 1,500' RADIUS8853 CLINTON RD, STEADMAN NC

APPENDIX A

LABORATORY ANALYTICAL RESULTS
#=CL#
July 19, 2019
LIMS USE: FR - HENRY NEMARGUT
LIMS OBJECT ID: 92436549
92436549
Project:
Pace Project No.:
RE:
Henry Nemargut
Henry Nemargut Engineering
2211 Chestnut Street
Wilmington, NC 28405
Johnsons Grocery
Dear Henry Nemargut:
Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Ezell
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92436549
Johnsons Grocery
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92436549
Johnsons Grocery
Lab ID Sample ID Matrix Date Collected Date Received
92436549001 MW 6 Water 07/11/19 12:00 07/12/19 09:38
92436549002 MW 12 Water 07/11/19 13:35 07/12/19 09:38
92436549003 SW 2 Water 07/11/19 14:00 07/12/19 09:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92436549
Johnsons Grocery
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92436549001 MW 6 SM 6200B 63 PASI-CGAW
92436549002 MW 12 SM 6200B 63 PASI-CGAW
92436549003 SW 2 SM 6200B 63 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 29
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92436549
Johnsons Grocery
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92436549001 MW 6
Isopropylbenzene (Cumene) 0.66 ug/L 07/19/19 14:010.50SM 6200B
Naphthalene 5.0 ug/L 07/19/19 14:012.0SM 6200B
n-Propylbenzene 0.57 ug/L 07/19/19 14:010.50SM 6200B
1,2,4-Trimethylbenzene 9.2 ug/L 07/19/19 14:010.50SM 6200B
m&p-Xylene 1.0 ug/L 07/19/19 14:011.0SM 6200B
92436549003 SW 2
Chloromethane 1.1 ug/L 07/18/19 21:161.0SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92436549
Johnsons Grocery
Sample: MW 6 Lab ID: 92436549001 Collected: 07/11/19 12:00 Received: 07/12/19 09:38 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 07/19/19 14:01 71-43-20.50 1
Bromobenzene ND ug/L 07/19/19 14:01 108-86-10.50 1
Bromochloromethane ND ug/L 07/19/19 14:01 74-97-50.50 1
Bromodichloromethane ND ug/L 07/19/19 14:01 75-27-40.50 1
Bromoform ND ug/L 07/19/19 14:01 75-25-20.50 1
Bromomethane ND ug/L 07/19/19 14:01 74-83-95.0 1
n-Butylbenzene ND ug/L 07/19/19 14:01 104-51-80.50 1
sec-Butylbenzene ND ug/L 07/19/19 14:01 135-98-80.50 1
tert-Butylbenzene ND ug/L 07/19/19 14:01 98-06-60.50 1
Carbon tetrachloride ND ug/L 07/19/19 14:01 56-23-50.50 1
Chlorobenzene ND ug/L 07/19/19 14:01 108-90-70.50 1
Chloroethane ND ug/L 07/19/19 14:01 75-00-31.0 1
Chloroform ND ug/L 07/19/19 14:01 67-66-35.0 1
Chloromethane ND ug/L 07/19/19 14:01 74-87-31.0 1
2-Chlorotoluene ND ug/L 07/19/19 14:01 95-49-80.50 1
4-Chlorotoluene ND ug/L 07/19/19 14:01 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 07/19/19 14:01 96-12-81.0 1
Dibromochloromethane ND ug/L 07/19/19 14:01 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 07/19/19 14:01 106-93-40.50 1
Dibromomethane ND ug/L 07/19/19 14:01 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 07/19/19 14:01 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 07/19/19 14:01 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 07/19/19 14:01 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 07/19/19 14:01 75-71-80.50 1
1,1-Dichloroethane ND ug/L 07/19/19 14:01 75-34-30.50 1
1,2-Dichloroethane ND ug/L 07/19/19 14:01 107-06-20.50 1
1,1-Dichloroethene ND ug/L 07/19/19 14:01 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 07/19/19 14:01 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 07/19/19 14:01 156-60-50.50 1
1,2-Dichloropropane ND ug/L 07/19/19 14:01 78-87-50.50 1
1,3-Dichloropropane ND ug/L 07/19/19 14:01 142-28-90.50 1
2,2-Dichloropropane ND ug/L 07/19/19 14:01 594-20-70.50 1
1,1-Dichloropropene ND ug/L 07/19/19 14:01 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 07/19/19 14:01 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 07/19/19 14:01 10061-02-60.50 1
Diisopropyl ether ND ug/L 07/19/19 14:01 108-20-30.50 1
Ethylbenzene ND ug/L 07/19/19 14:01 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 07/19/19 14:01 87-68-32.0 1
Isopropylbenzene (Cumene)0.66 ug/L 07/19/19 14:01 98-82-80.50 1
Methylene Chloride ND ug/L 07/19/19 14:01 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 07/19/19 14:01 1634-04-40.50 1
Naphthalene 5.0 ug/L 07/19/19 14:01 91-20-32.0 1
n-Propylbenzene 0.57 ug/L 07/19/19 14:01 103-65-10.50 1
Styrene ND ug/L 07/19/19 14:01 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 07/19/19 14:01 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 07/19/19 14:01 79-34-50.50 1
Tetrachloroethene ND ug/L 07/19/19 14:01 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92436549
Johnsons Grocery
Sample: MW 6 Lab ID: 92436549001 Collected: 07/11/19 12:00 Received: 07/12/19 09:38 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 07/19/19 14:01 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 07/19/19 14:01 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 07/19/19 14:01 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 07/19/19 14:01 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 07/19/19 14:01 79-00-50.50 1
Trichloroethene ND ug/L 07/19/19 14:01 79-01-60.50 1
Trichlorofluoromethane ND ug/L 07/19/19 14:01 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 07/19/19 14:01 96-18-40.50 1
1,2,4-Trimethylbenzene 9.2 ug/L 07/19/19 14:01 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 07/19/19 14:01 108-67-80.50 1
Vinyl chloride ND ug/L 07/19/19 14:01 75-01-41.0 1
m&p-Xylene 1.0 ug/L 07/19/19 14:01 179601-23-11.0 1
o-Xylene ND ug/L 07/19/19 14:01 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 92 % 07/19/19 14:01 17060-07-070-130 1
4-Bromofluorobenzene (S) 104 % 07/19/19 14:01 460-00-470-130 1
Toluene-d8 (S) 107 % 07/19/19 14:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92436549
Johnsons Grocery
Sample: MW 12 Lab ID: 92436549002 Collected: 07/11/19 13:35 Received: 07/12/19 09:38 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 07/18/19 20:58 71-43-20.50 1
Bromobenzene ND ug/L 07/18/19 20:58 108-86-10.50 1
Bromochloromethane ND ug/L 07/18/19 20:58 74-97-50.50 1
Bromodichloromethane ND ug/L 07/18/19 20:58 75-27-40.50 1
Bromoform ND ug/L 07/18/19 20:58 75-25-20.50 1
Bromomethane ND ug/L 07/18/19 20:58 74-83-95.0 1
n-Butylbenzene ND ug/L 07/18/19 20:58 104-51-80.50 1
sec-Butylbenzene ND ug/L 07/18/19 20:58 135-98-80.50 1
tert-Butylbenzene ND ug/L 07/18/19 20:58 98-06-60.50 1
Carbon tetrachloride ND ug/L 07/18/19 20:58 56-23-50.50 1
Chlorobenzene ND ug/L 07/18/19 20:58 108-90-70.50 1
Chloroethane ND ug/L 07/18/19 20:58 75-00-31.0 1
Chloroform ND ug/L 07/18/19 20:58 67-66-35.0 1
Chloromethane ND ug/L 07/18/19 20:58 74-87-31.0 1
2-Chlorotoluene ND ug/L 07/18/19 20:58 95-49-80.50 1
4-Chlorotoluene ND ug/L 07/18/19 20:58 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 07/18/19 20:58 96-12-81.0 1
Dibromochloromethane ND ug/L 07/18/19 20:58 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 07/18/19 20:58 106-93-40.50 1
Dibromomethane ND ug/L 07/18/19 20:58 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 07/18/19 20:58 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 07/18/19 20:58 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 07/18/19 20:58 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 07/18/19 20:58 75-71-80.50 1
1,1-Dichloroethane ND ug/L 07/18/19 20:58 75-34-30.50 1
1,2-Dichloroethane ND ug/L 07/18/19 20:58 107-06-20.50 1
1,1-Dichloroethene ND ug/L 07/18/19 20:58 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 07/18/19 20:58 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 07/18/19 20:58 156-60-50.50 1
1,2-Dichloropropane ND ug/L 07/18/19 20:58 78-87-50.50 1
1,3-Dichloropropane ND ug/L 07/18/19 20:58 142-28-90.50 1
2,2-Dichloropropane ND ug/L 07/18/19 20:58 594-20-70.50 1
1,1-Dichloropropene ND ug/L 07/18/19 20:58 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 07/18/19 20:58 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 07/18/19 20:58 10061-02-60.50 1
Diisopropyl ether ND ug/L 07/18/19 20:58 108-20-30.50 1
Ethylbenzene ND ug/L 07/18/19 20:58 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 07/18/19 20:58 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 07/18/19 20:58 98-82-80.50 1
Methylene Chloride ND ug/L 07/18/19 20:58 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 07/18/19 20:58 1634-04-40.50 1
Naphthalene ND ug/L 07/18/19 20:58 91-20-32.0 1
n-Propylbenzene ND ug/L 07/18/19 20:58 103-65-10.50 1
Styrene ND ug/L 07/18/19 20:58 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 07/18/19 20:58 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 07/18/19 20:58 79-34-50.50 1
Tetrachloroethene ND ug/L 07/18/19 20:58 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
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Page 8 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92436549
Johnsons Grocery
Sample: MW 12 Lab ID: 92436549002 Collected: 07/11/19 13:35 Received: 07/12/19 09:38 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 07/18/19 20:58 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 07/18/19 20:58 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 07/18/19 20:58 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 07/18/19 20:58 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 07/18/19 20:58 79-00-50.50 1
Trichloroethene ND ug/L 07/18/19 20:58 79-01-60.50 1
Trichlorofluoromethane ND ug/L 07/18/19 20:58 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 07/18/19 20:58 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 07/18/19 20:58 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 07/18/19 20:58 108-67-80.50 1
Vinyl chloride ND ug/L 07/18/19 20:58 75-01-41.0 1
m&p-Xylene ND ug/L 07/18/19 20:58 179601-23-11.0 1
o-Xylene ND ug/L 07/18/19 20:58 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 92 % 07/18/19 20:58 17060-07-070-130 1
4-Bromofluorobenzene (S) 103 % 07/18/19 20:58 460-00-470-130 1
Toluene-d8 (S) 106 % 07/18/19 20:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
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Huntersville, NC 28078
[phone]
Page 9 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92436549
Johnsons Grocery
Sample: SW 2 Lab ID: 92436549003 Collected: 07/11/19 14:00 Received: 07/12/19 09:38 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Benzene ND ug/L 07/18/19 21:16 71-43-20.50 1
Bromobenzene ND ug/L 07/18/19 21:16 108-86-10.50 1
Bromochloromethane ND ug/L 07/18/19 21:16 74-97-50.50 1
Bromodichloromethane ND ug/L 07/18/19 21:16 75-27-40.50 1
Bromoform ND ug/L 07/18/19 21:16 75-25-20.50 1
Bromomethane ND ug/L 07/18/19 21:16 74-83-95.0 1
n-Butylbenzene ND ug/L 07/18/19 21:16 104-51-80.50 1
sec-Butylbenzene ND ug/L 07/18/19 21:16 135-98-80.50 1
tert-Butylbenzene ND ug/L 07/18/19 21:16 98-06-60.50 1
Carbon tetrachloride ND ug/L 07/18/19 21:16 56-23-50.50 1
Chlorobenzene ND ug/L 07/18/19 21:16 108-90-70.50 1
Chloroethane ND ug/L 07/18/19 21:16 75-00-31.0 1
Chloroform ND ug/L 07/18/19 21:16 67-66-35.0 1
Chloromethane 1.1 ug/L 07/18/19 21:16 74-87-31.0 1
2-Chlorotoluene ND ug/L 07/18/19 21:16 95-49-80.50 1
4-Chlorotoluene ND ug/L 07/18/19 21:16 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 07/18/19 21:16 96-12-81.0 1
Dibromochloromethane ND ug/L 07/18/19 21:16 124-48-10.50 1
1,2-Dibromoethane (EDB) ND ug/L 07/18/19 21:16 106-93-40.50 1
Dibromomethane ND ug/L 07/18/19 21:16 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 07/18/19 21:16 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 07/18/19 21:16 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 07/18/19 21:16 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 07/18/19 21:16 75-71-80.50 1
1,1-Dichloroethane ND ug/L 07/18/19 21:16 75-34-30.50 1
1,2-Dichloroethane ND ug/L 07/18/19 21:16 107-06-20.50 1
1,1-Dichloroethene ND ug/L 07/18/19 21:16 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 07/18/19 21:16 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 07/18/19 21:16 156-60-50.50 1
1,2-Dichloropropane ND ug/L 07/18/19 21:16 78-87-50.50 1
1,3-Dichloropropane ND ug/L 07/18/19 21:16 142-28-90.50 1
2,2-Dichloropropane ND ug/L 07/18/19 21:16 594-20-70.50 1
1,1-Dichloropropene ND ug/L 07/18/19 21:16 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 07/18/19 21:16 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 07/18/19 21:16 10061-02-60.50 1
Diisopropyl ether ND ug/L 07/18/19 21:16 108-20-30.50 1
Ethylbenzene ND ug/L 07/18/19 21:16 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 07/18/19 21:16 87-68-32.0 1
Isopropylbenzene (Cumene) ND ug/L 07/18/19 21:16 98-82-80.50 1
Methylene Chloride ND ug/L 07/18/19 21:16 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 07/18/19 21:16 1634-04-40.50 1
Naphthalene ND ug/L 07/18/19 21:16 91-20-32.0 1
n-Propylbenzene ND ug/L 07/18/19 21:16 103-65-10.50 1
Styrene ND ug/L 07/18/19 21:16 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 07/18/19 21:16 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 07/18/19 21:16 79-34-50.50 1
Tetrachloroethene ND ug/L 07/18/19 21:16 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
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Huntersville, NC 28078
[phone]
Page 10 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92436549
Johnsons Grocery
Sample: SW 2 Lab ID: 92436549003 Collected: 07/11/19 14:00 Received: 07/12/19 09:38 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 6200B6200B MSV
Toluene ND ug/L 07/18/19 21:16 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 07/18/19 21:16 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 07/18/19 21:16 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 07/18/19 21:16 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 07/18/19 21:16 79-00-50.50 1
Trichloroethene ND ug/L 07/18/19 21:16 79-01-60.50 1
Trichlorofluoromethane ND ug/L 07/18/19 21:16 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 07/18/19 21:16 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 07/18/19 21:16 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 07/18/19 21:16 108-67-80.50 1
Vinyl chloride ND ug/L 07/18/19 21:16 75-01-41.0 1
m&p-Xylene ND ug/L 07/18/19 21:16 179601-23-11.0 1
o-Xylene ND ug/L 07/18/19 21:16 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S) 98 % 07/18/19 21:16 17060-07-070-130 1
4-Bromofluorobenzene (S) 104 % 07/18/19 21:16 460-00-470-130 1
Toluene-d8 (S) 104 % 07/18/19 21:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
487239
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92436549002, 92436549003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2630590
Associated Lab Samples:92436549002, 92436549003
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 07/18/19 18:31
1,1,1-Trichloroethane ug/L ND 0.50 07/18/19 18:31
1,1,2,2-Tetrachloroethane ug/L ND 0.50 07/18/19 18:31
1,1,2-Trichloroethane ug/L ND 0.50 07/18/19 18:31
1,1-Dichloroethane ug/L ND 0.50 07/18/19 18:31
1,1-Dichloroethene ug/L ND 0.50 07/18/19 18:31
1,1-Dichloropropene ug/L ND 0.50 07/18/19 18:31
1,2,3-Trichlorobenzene ug/L ND 2.0 07/18/19 18:31
1,2,3-Trichloropropane ug/L ND 0.50 07/18/19 18:31
1,2,4-Trichlorobenzene ug/L ND 2.0 07/18/19 18:31
1,2,4-Trimethylbenzene ug/L ND 0.50 07/18/19 18:31
1,2-Dibromo-3-chloropropane ug/L ND 1.0 07/18/19 18:31
1,2-Dibromoethane (EDB) ug/L ND 0.50 07/18/19 18:31
1,2-Dichlorobenzene ug/L ND 0.50 07/18/19 18:31
1,2-Dichloroethane ug/L ND 0.50 07/18/19 18:31
1,2-Dichloropropane ug/L ND 0.50 07/18/19 18:31
1,3,5-Trimethylbenzene ug/L ND 0.50 07/18/19 18:31
1,3-Dichlorobenzene ug/L ND 0.50 07/18/19 18:31
1,3-Dichloropropane ug/L ND 0.50 07/18/19 18:31
1,4-Dichlorobenzene ug/L ND 0.50 07/18/19 18:31
2,2-Dichloropropane ug/L ND 0.50 07/18/19 18:31
2-Chlorotoluene ug/L ND 0.50 07/18/19 18:31
4-Chlorotoluene ug/L ND 0.50 07/18/19 18:31
Benzene ug/L ND 0.50 07/18/19 18:31
Bromobenzene ug/L ND 0.50 07/18/19 18:31
Bromochloromethane ug/L ND 0.50 07/18/19 18:31
Bromodichloromethane ug/L ND 0.50 07/18/19 18:31
Bromoform ug/L ND 0.50 07/18/19 18:31
Bromomethane ug/L ND 5.0 07/18/19 18:31
Carbon tetrachloride ug/L ND 0.50 07/18/19 18:31
Chlorobenzene ug/L ND 0.50 07/18/19 18:31
Chloroethane ug/L ND 1.0 07/18/19 18:31
Chloroform ug/L ND 5.0 07/18/19 18:31
Chloromethane ug/L ND 1.0 07/18/19 18:31
cis-1,2-Dichloroethene ug/L ND 0.50 07/18/19 18:31
cis-1,3-Dichloropropene ug/L ND 0.50 07/18/19 18:31
Dibromochloromethane ug/L ND 0.50 07/18/19 18:31
Dibromomethane ug/L ND 0.50 07/18/19 18:31
Dichlorodifluoromethane ug/L ND 0.50 07/18/19 18:31
Diisopropyl ether ug/L ND 0.50 07/18/19 18:31
Ethylbenzene ug/L ND 0.50 07/18/19 18:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2630590
Associated Lab Samples:92436549002, 92436549003
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 07/18/19 18:31
Isopropylbenzene (Cumene) ug/L ND 0.50 07/18/19 18:31
m&p-Xylene ug/L ND 1.0 07/18/19 18:31
Methyl-tert-butyl ether ug/L ND 0.50 07/18/19 18:31
Methylene Chloride ug/L ND 2.0 07/18/19 18:31
n-Butylbenzene ug/L ND 0.50 07/18/19 18:31
n-Propylbenzene ug/L ND 0.50 07/18/19 18:31
Naphthalene ug/L ND 2.0 07/18/19 18:31
o-Xylene ug/L ND 0.50 07/18/19 18:31
sec-Butylbenzene ug/L ND 0.50 07/18/19 18:31
Styrene ug/L ND 0.50 07/18/19 18:31
tert-Butylbenzene ug/L ND 0.50 07/18/19 18:31
Tetrachloroethene ug/L ND 0.50 07/18/19 18:31
Toluene ug/L ND 0.50 07/18/19 18:31
trans-1,2-Dichloroethene ug/L ND 0.50 07/18/19 18:31
trans-1,3-Dichloropropene ug/L ND 0.50 07/18/19 18:31
Trichloroethene ug/L ND 0.50 07/18/19 18:31
Trichlorofluoromethane ug/L ND 1.0 07/18/19 18:31
Vinyl chloride ug/L ND 1.0 07/18/19 18:31
1,2-Dichloroethane-d4 (S) % 94 70-130 07/18/19 18:31
4-Bromofluorobenzene (S) % 105 70-130 07/18/19 18:31
Toluene-d8 (S) % 106 70-130 07/18/19 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2630591LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 56.750 113 60-140
1,1,1-Trichloroethane ug/L 58.150 116 60-140
1,1,2,2-Tetrachloroethane ug/L 54.350 109 60-140
1,1,2-Trichloroethane ug/L 56.450 113 60-140
1,1-Dichloroethane ug/L 51.750 103 60-140
1,1-Dichloroethene ug/L 56.650 113 60-140
1,1-Dichloropropene ug/L 54.150 108 60-140
1,2,3-Trichlorobenzene ug/L 56.050 112 60-140
1,2,3-Trichloropropane ug/L 61.050 122 60-140
1,2,4-Trichlorobenzene ug/L 55.350 111 60-140
1,2,4-Trimethylbenzene ug/L 53.350 107 60-140
1,2-Dibromo-3-chloropropane ug/L 60.850 122 60-140
1,2-Dibromoethane (EDB) ug/L 53.650 107 60-140
1,2-Dichlorobenzene ug/L 52.950 106 60-140
1,2-Dichloroethane ug/L 50.850 102 60-140
1,2-Dichloropropane ug/L 57.050 114 60-140
1,3,5-Trimethylbenzene ug/L 54.050 108 60-140
1,3-Dichlorobenzene ug/L 53.150 106 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2630591LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 59.050 118 60-140
1,4-Dichlorobenzene ug/L 48.550 97 60-140
2,2-Dichloropropane ug/L 63.350 127 60-140
2-Chlorotoluene ug/L 51.850 104 60-140
4-Chlorotoluene ug/L 52.050 104 60-140
Benzene ug/L 55.250 110 60-140
Bromobenzene ug/L 51.650 103 60-140
Bromochloromethane ug/L 51.250 102 60-140
Bromodichloromethane ug/L 56.250 112 60-140
Bromoform ug/L 56.750 113 60-140
Bromomethane ug/L 61.650 123 60-140
Carbon tetrachloride ug/L 55.450 111 60-140
Chlorobenzene ug/L 50.950 102 60-140
Chloroethane ug/L 48.050 96 60-140
Chloroform ug/L 51.850 104 60-140
Chloromethane ug/L 51.850 104 60-140
cis-1,2-Dichloroethene ug/L 54.750 109 60-140
cis-1,3-Dichloropropene ug/L 61.450 123 60-140
Dibromochloromethane ug/L 60.350 121 60-140
Dibromomethane ug/L 49.850 100 60-140
Dichlorodifluoromethane ug/L 49.350 99 60-140
Diisopropyl ether ug/L 54.050 108 60-140
Ethylbenzene ug/L 52.350 105 60-140
Hexachloro-1,3-butadiene ug/L 60.750 121 60-140
Isopropylbenzene (Cumene) ug/L 56.850 114 60-140
m&p-Xylene ug/L 108100 108 60-140
Methyl-tert-butyl ether ug/L 52.750 105 60-140
Methylene Chloride ug/L 52.650 105 60-140
n-Butylbenzene ug/L 57.450 115 60-140
n-Propylbenzene ug/L 54.050 108 60-140
Naphthalene ug/L 59.850 120 60-140
o-Xylene ug/L 55.750 111 60-140
sec-Butylbenzene ug/L 55.950 112 60-140
Styrene ug/L 54.550 109 60-140
tert-Butylbenzene ug/L 44.150 88 60-140
Tetrachloroethene ug/L 56.650 113 60-140
Toluene ug/L 49.250 98 60-140
trans-1,2-Dichloroethene ug/L 53.650 107 60-140
trans-1,3-Dichloropropene ug/L 60.850 122 60-140
Trichloroethene ug/L 55.550 111 60-140
Trichlorofluoromethane ug/L 50.650 101 60-140
Vinyl chloride ug/L 50.550 101 60-140
1,2-Dichloroethane-d4 (S) % 105 70-130
4-Bromofluorobenzene (S) % 104 70-130
Toluene-d8 (S) % 97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2630592MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92436669006
2630593
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 107 60-140111 4 3020ND 21.3 22.3
1,1,1-Trichloroethane ug/L 20 119 60-140119 0 3020ND 23.8 23.9
1,1,2,2-Tetrachloroethane ug/L 20 108 60-140112 3 3020ND 21.7 22.4
1,1,2-Trichloroethane ug/L 20 114 60-140112 2 3020ND 22.9 22.4
1,1-Dichloroethane ug/L 20 115 60-140115 0 3020ND 23.0 23.0
1,1-Dichloroethene ug/L 20 129 60-140126 2 3020ND 25.8 25.2
1,1-Dichloropropene ug/L 20 108 60-140114 5 3020ND 21.7 22.9
1,2,3-Trichlorobenzene ug/L 20 116 60-140112 3 3020ND 23.3 22.5
1,2,3-Trichloropropane ug/L R120 88 60-140122 33 3020ND 17.6 24.5
1,2,4-Trichlorobenzene ug/L 20 115 60-140114 1 3020ND 22.9 22.8
1,2,4-Trimethylbenzene ug/L 20 113 60-140114 1 3020ND 22.5 22.7
1,2-Dibromo-3-
chloropropane ug/L 20 117 60-140123 5 3020ND 23.3 24.5
1,2-Dibromoethane (EDB) ug/L 20 104 60-140107 3 3020ND 20.8 21.4
1,2-Dichlorobenzene ug/L 20 111 60-140114 3 3020ND 22.2 22.8
1,2-Dichloroethane ug/L 20 106 60-140109 3 3020ND 21.1 21.7
1,2-Dichloropropane ug/L 20 118 60-140122 3 3020ND 23.7 24.3
1,3,5-Trimethylbenzene ug/L 20 115 60-140119 3 3020ND 23.1 23.8
1,3-Dichlorobenzene ug/L 20 113 60-140112 0 3020ND 22.5 22.5
1,3-Dichloropropane ug/L 20 110 60-140117 6 3020ND 22.0 23.3
1,4-Dichlorobenzene ug/L 20 107 60-140105 2 3020ND 21.5 21.1
2,2-Dichloropropane ug/L 20 135 60-140140 4 3020ND 27.1 28.1
2-Chlorotoluene ug/L 20 113 60-140111 2 3020ND 22.6 22.2
4-Chlorotoluene ug/L 20 114 60-140116 2 3020ND 22.7 23.1
Benzene ug/L 20 117 60-140120 2 3020ND 23.4 24.0
Bromobenzene ug/L 20 112 60-140111 1 3020ND 22.4 22.2
Bromochloromethane ug/L 20 116 60-140116 0 3020ND 23.2 23.3
Bromodichloromethane ug/L 20 119 60-140122 3 3020ND 23.8 24.4
Bromoform ug/L 20 109 60-140110 1 3020ND 21.8 22.1
Bromomethane ug/L M120 160 60-140165 3 3020ND 32.0 33.1
Carbon tetrachloride ug/L 20 124 60-140127 3 3020ND 24.7 25.4
Chlorobenzene ug/L 20 106 60-140112 5 3020ND 21.2 22.4
Chloroethane ug/L 20 114 60-140108 5 3020ND 22.7 21.7
Chloroform ug/L 20 113 60-140112 1 3020ND 22.7 22.5
Chloromethane ug/L 20 114 60-140106 7 3020ND 22.7 21.3
cis-1,2-Dichloroethene ug/L 20 120 60-140120 0 3020ND 24.0 23.9
cis-1,3-Dichloropropene ug/L 20 127 60-140126 1 3020ND 25.5 25.2
Dibromochloromethane ug/L 20 112 60-140115 3 3020ND 22.3 23.0
Dibromomethane ug/L 20 109 60-140115 6 3020ND 21.7 23.0
Dichlorodifluoromethane ug/L 20 106 60-140106 0 3020ND 21.3 21.2
Diisopropyl ether ug/L 20 107 60-140107 0 3020ND 21.4 21.4
Ethylbenzene ug/L 20 111 60-140115 3 3020ND 22.3 23.0
Hexachloro-1,3-butadiene ug/L 20 136 60-140125 8 3020ND 27.1 25.0
Isopropylbenzene
(Cumene)
ug/L 20 118 60-140123 5 3020ND 23.5 24.6
m&p-Xylene ug/L 40 116 60-140119 3 3040ND 46.3 47.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2630592MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92436669006
2630593
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 98 60-140103 5 3020ND 19.6 20.5
Methylene Chloride ug/L 20 110 60-140116 5 3020ND 22.0 23.1
n-Butylbenzene ug/L 20 124 60-140121 2 3020ND 24.8 24.2
n-Propylbenzene ug/L 20 120 60-140119 1 3020ND 24.1 23.8
Naphthalene ug/L 20 124 60-140121 2 3020ND 24.7 24.1
o-Xylene ug/L 20 114 60-140125 9 3020ND 22.8 25.0
sec-Butylbenzene ug/L 20 121 60-140124 2 3020ND 24.3 24.7
Styrene ug/L 20 109 60-140116 6 3020ND 21.9 23.2
tert-Butylbenzene ug/L 20 95 60-14099 3 3020ND 19.1 19.7
Tetrachloroethene ug/L 20 115 60-140114 1 3020ND 23.1 22.8
Toluene ug/L 20 112 60-140113 1 3020ND 22.4 22.6
trans-1,2-Dichloroethene ug/L 20 118 60-140118 0 3020ND 23.6 23.7
trans-1,3-Dichloropropene ug/L 20 125 60-140129 3 3020ND 25.0 25.7
Trichloroethene ug/L 20 114 60-140118 4 3020ND 22.8 23.7
Trichlorofluoromethane ug/L 20 114 60-140114 0 3020ND 22.8 22.7
Vinyl chloride ug/L 20 115 60-140110 4 3020ND 23.0 22.1
1,2-Dichloroethane-d4 (S) % 101 70-130102
4-Bromofluorobenzene (S) % 99 70-130101
Toluene-d8 (S) % 100 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
487327
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples: 92436549001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2630969
Associated Lab Samples:92436549001
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 07/19/19 10:58
1,1,1-Trichloroethane ug/L ND 0.50 07/19/19 10:58
1,1,2,2-Tetrachloroethane ug/L ND 0.50 07/19/19 10:58
1,1,2-Trichloroethane ug/L ND 0.50 07/19/19 10:58
1,1-Dichloroethane ug/L ND 0.50 07/19/19 10:58
1,1-Dichloroethene ug/L ND 0.50 07/19/19 10:58
1,1-Dichloropropene ug/L ND 0.50 07/19/19 10:58
1,2,3-Trichlorobenzene ug/L ND 2.0 07/19/19 10:58
1,2,3-Trichloropropane ug/L ND 0.50 07/19/19 10:58
1,2,4-Trichlorobenzene ug/L ND 2.0 07/19/19 10:58
1,2,4-Trimethylbenzene ug/L ND 0.50 07/19/19 10:58
1,2-Dibromo-3-chloropropane ug/L ND 1.0 07/19/19 10:58
1,2-Dibromoethane (EDB) ug/L ND 0.50 07/19/19 10:58
1,2-Dichlorobenzene ug/L ND 0.50 07/19/19 10:58
1,2-Dichloroethane ug/L ND 0.50 07/19/19 10:58
1,2-Dichloropropane ug/L ND 0.50 07/19/19 10:58
1,3,5-Trimethylbenzene ug/L ND 0.50 07/19/19 10:58
1,3-Dichlorobenzene ug/L ND 0.50 07/19/19 10:58
1,3-Dichloropropane ug/L ND 0.50 07/19/19 10:58
1,4-Dichlorobenzene ug/L ND 0.50 07/19/19 10:58
2,2-Dichloropropane ug/L ND 0.50 07/19/19 10:58
2-Chlorotoluene ug/L ND 0.50 07/19/19 10:58
4-Chlorotoluene ug/L ND 0.50 07/19/19 10:58
Benzene ug/L ND 0.50 07/19/19 10:58
Bromobenzene ug/L ND 0.50 07/19/19 10:58
Bromochloromethane ug/L ND 0.50 07/19/19 10:58
Bromodichloromethane ug/L ND 0.50 07/19/19 10:58
Bromoform ug/L ND 0.50 07/19/19 10:58
Bromomethane ug/L ND 5.0 07/19/19 10:58
Carbon tetrachloride ug/L ND 0.50 07/19/19 10:58
Chlorobenzene ug/L ND 0.50 07/19/19 10:58
Chloroethane ug/L ND 1.0 07/19/19 10:58
Chloroform ug/L ND 5.0 07/19/19 10:58
Chloromethane ug/L ND 1.0 07/19/19 10:58
cis-1,2-Dichloroethene ug/L ND 0.50 07/19/19 10:58
cis-1,3-Dichloropropene ug/L ND 0.50 07/19/19 10:58
Dibromochloromethane ug/L ND 0.50 07/19/19 10:58
Dibromomethane ug/L ND 0.50 07/19/19 10:58
Dichlorodifluoromethane ug/L ND 0.50 07/19/19 10:58
Diisopropyl ether ug/L ND 0.50 07/19/19 10:58
Ethylbenzene ug/L ND 0.50 07/19/19 10:58
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2630969
Associated Lab Samples:92436549001
Matrix: Water
Analyzed
Hexachloro-1,3-butadiene ug/L ND 2.0 07/19/19 10:58
Isopropylbenzene (Cumene) ug/L ND 0.50 07/19/19 10:58
m&p-Xylene ug/L ND 1.0 07/19/19 10:58
Methyl-tert-butyl ether ug/L ND 0.50 07/19/19 10:58
Methylene Chloride ug/L ND 2.0 07/19/19 10:58
n-Butylbenzene ug/L ND 0.50 07/19/19 10:58
n-Propylbenzene ug/L ND 0.50 07/19/19 10:58
Naphthalene ug/L ND 2.0 07/19/19 10:58
o-Xylene ug/L ND 0.50 07/19/19 10:58
sec-Butylbenzene ug/L ND 0.50 07/19/19 10:58
Styrene ug/L ND 0.50 07/19/19 10:58
tert-Butylbenzene ug/L ND 0.50 07/19/19 10:58
Tetrachloroethene ug/L ND 0.50 07/19/19 10:58
Toluene ug/L ND 0.50 07/19/19 10:58
trans-1,2-Dichloroethene ug/L ND 0.50 07/19/19 10:58
trans-1,3-Dichloropropene ug/L ND 0.50 07/19/19 10:58
Trichloroethene ug/L ND 0.50 07/19/19 10:58
Trichlorofluoromethane ug/L ND 1.0 07/19/19 10:58
Vinyl chloride ug/L ND 1.0 07/19/19 10:58
1,2-Dichloroethane-d4 (S) % 94 70-130 07/19/19 10:58
4-Bromofluorobenzene (S) % 107 70-130 07/19/19 10:58
Toluene-d8 (S) % 106 70-130 07/19/19 10:58
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2632028
Associated Lab Samples:92436549001
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 07/19/19 02:26
1,1,1-Trichloroethane ug/L ND 0.50 07/19/19 02:26
1,1,2,2-Tetrachloroethane ug/L ND 0.50 07/19/19 02:26
1,1,2-Trichloroethane ug/L ND 0.50 07/19/19 02:26
1,1-Dichloroethane ug/L ND 0.50 07/19/19 02:26
1,1-Dichloroethene ug/L ND 0.50 07/19/19 02:26
1,1-Dichloropropene ug/L ND 0.50 07/19/19 02:26
1,2,3-Trichlorobenzene ug/L ND 2.0 07/19/19 02:26
1,2,3-Trichloropropane ug/L ND 0.50 07/19/19 02:26
1,2,4-Trichlorobenzene ug/L ND 2.0 07/19/19 02:26
1,2,4-Trimethylbenzene ug/L ND 0.50 07/19/19 02:26
1,2-Dibromo-3-chloropropane ug/L ND 1.0 07/19/19 02:26
1,2-Dibromoethane (EDB) ug/L ND 0.50 07/19/19 02:26
1,2-Dichlorobenzene ug/L ND 0.50 07/19/19 02:26
1,2-Dichloroethane ug/L ND 0.50 07/19/19 02:26
1,2-Dichloropropane ug/L ND 0.50 07/19/19 02:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2632028
Associated Lab Samples:92436549001
Matrix: Water
Analyzed
1,3,5-Trimethylbenzene ug/L ND 0.50 07/19/19 02:26
1,3-Dichlorobenzene ug/L ND 0.50 07/19/19 02:26
1,3-Dichloropropane ug/L ND 0.50 07/19/19 02:26
1,4-Dichlorobenzene ug/L ND 0.50 07/19/19 02:26
2,2-Dichloropropane ug/L ND 0.50 07/19/19 02:26
2-Chlorotoluene ug/L ND 0.50 07/19/19 02:26
4-Chlorotoluene ug/L ND 0.50 07/19/19 02:26
Benzene ug/L ND 0.50 07/19/19 02:26
Bromobenzene ug/L ND 0.50 07/19/19 02:26
Bromochloromethane ug/L ND 0.50 07/19/19 02:26
Bromodichloromethane ug/L ND 0.50 07/19/19 02:26
Bromoform ug/L ND 0.50 07/19/19 02:26
Bromomethane ug/L ND 5.0 07/19/19 02:26
Carbon tetrachloride ug/L ND 0.50 07/19/19 02:26
Chlorobenzene ug/L ND 0.50 07/19/19 02:26
Chloroethane ug/L ND 1.0 07/19/19 02:26
Chloroform ug/L ND 5.0 07/19/19 02:26
Chloromethane ug/L ND 1.0 07/19/19 02:26
cis-1,2-Dichloroethene ug/L ND 0.50 07/19/19 02:26
cis-1,3-Dichloropropene ug/L ND 0.50 07/19/19 02:26
Dibromochloromethane ug/L ND 0.50 07/19/19 02:26
Dibromomethane ug/L ND 0.50 07/19/19 02:26
Dichlorodifluoromethane ug/L ND 0.50 07/19/19 02:26
Diisopropyl ether ug/L ND 0.50 07/19/19 02:26
Ethylbenzene ug/L ND 0.50 07/19/19 02:26
Hexachloro-1,3-butadiene ug/L ND 2.0 07/19/19 02:26
Isopropylbenzene (Cumene) ug/L ND 0.50 07/19/19 02:26
m&p-Xylene ug/L ND 1.0 07/19/19 02:26
Methyl-tert-butyl ether ug/L ND 0.50 07/19/19 02:26
Methylene Chloride ug/L ND 2.0 07/19/19 02:26
n-Butylbenzene ug/L ND 0.50 07/19/19 02:26
n-Propylbenzene ug/L ND 0.50 07/19/19 02:26
Naphthalene ug/L ND 2.0 07/19/19 02:26
o-Xylene ug/L ND 0.50 07/19/19 02:26
sec-Butylbenzene ug/L ND 0.50 07/19/19 02:26
Styrene ug/L ND 0.50 07/19/19 02:26
tert-Butylbenzene ug/L ND 0.50 07/19/19 02:26
Tetrachloroethene ug/L ND 0.50 07/19/19 02:26
Toluene ug/L ND 0.50 07/19/19 02:26
trans-1,2-Dichloroethene ug/L ND 0.50 07/19/19 02:26
trans-1,3-Dichloropropene ug/L ND 0.50 07/19/19 02:26
Trichloroethene ug/L ND 0.50 07/19/19 02:26
Trichlorofluoromethane ug/L ND 1.0 07/19/19 02:26
Vinyl chloride ug/L ND 1.0 07/19/19 02:26
1,2-Dichloroethane-d4 (S) % 91 70-130 07/19/19 02:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2632028
Associated Lab Samples:92436549001
Matrix: Water
Analyzed
4-Bromofluorobenzene (S) % 100 70-130 07/19/19 02:26
Toluene-d8 (S) % 100 70-130 07/19/19 02:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2630970LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 52.350 105 60-140
1,1,1-Trichloroethane ug/L 52.050 104 60-140
1,1,2,2-Tetrachloroethane ug/L 50.050 100 60-140
1,1,2-Trichloroethane ug/L 52.150 104 60-140
1,1-Dichloroethane ug/L 47.750 95 60-140
1,1-Dichloroethene ug/L 50.050 100 60-140
1,1-Dichloropropene ug/L 49.250 98 60-140
1,2,3-Trichlorobenzene ug/L 51.250 102 60-140
1,2,3-Trichloropropane ug/L 56.650 113 60-140
1,2,4-Trichlorobenzene ug/L 51.350 103 60-140
1,2,4-Trimethylbenzene ug/L 50.150 100 60-140
1,2-Dibromo-3-chloropropane ug/L 53.750 107 60-140
1,2-Dibromoethane (EDB) ug/L 52.050 104 60-140
1,2-Dichlorobenzene ug/L 48.850 98 60-140
1,2-Dichloroethane ug/L 45.350 91 60-140
1,2-Dichloropropane ug/L 52.750 105 60-140
1,3,5-Trimethylbenzene ug/L 51.550 103 60-140
1,3-Dichlorobenzene ug/L 48.250 96 60-140
1,3-Dichloropropane ug/L 55.650 111 60-140
1,4-Dichlorobenzene ug/L 46.350 93 60-140
2,2-Dichloropropane ug/L 58.850 118 60-140
2-Chlorotoluene ug/L 48.350 97 60-140
4-Chlorotoluene ug/L 49.750 99 60-140
Benzene ug/L 51.050 102 60-140
Bromobenzene ug/L 49.250 98 60-140
Bromochloromethane ug/L 49.050 98 60-140
Bromodichloromethane ug/L 52.450 105 60-140
Bromoform ug/L 54.750 109 60-140
Bromomethane ug/L 58.550 117 60-140
Carbon tetrachloride ug/L 51.150 102 60-140
Chlorobenzene ug/L 48.550 97 60-140
Chloroethane ug/L 44.650 89 60-140
Chloroform ug/L 48.250 96 60-140
Chloromethane ug/L 46.450 93 60-140
cis-1,2-Dichloroethene ug/L 50.950 102 60-140
cis-1,3-Dichloropropene ug/L 58.050 116 60-140
Dibromochloromethane ug/L 55.450 111 60-140
Dibromomethane ug/L 47.350 95 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2630970LABORATORY CONTROL SAMPLE:
LCSSpike
Dichlorodifluoromethane ug/L 47.750 95 60-140
Diisopropyl ether ug/L 50.150 100 60-140
Ethylbenzene ug/L 49.550 99 60-140
Hexachloro-1,3-butadiene ug/L 58.350 117 60-140
Isopropylbenzene (Cumene) ug/L 52.650 105 60-140
m&p-Xylene ug/L 100100 100 60-140
Methyl-tert-butyl ether ug/L 46.650 93 60-140
Methylene Chloride ug/L 48.650 97 60-140
n-Butylbenzene ug/L 53.750 107 60-140
n-Propylbenzene ug/L 51.350 103 60-140
Naphthalene ug/L 53.550 107 60-140
o-Xylene ug/L 53.250 106 60-140
sec-Butylbenzene ug/L 52.850 106 60-140
Styrene ug/L 50.250 100 60-140
tert-Butylbenzene ug/L 42.250 84 60-140
Tetrachloroethene ug/L 51.850 104 60-140
Toluene ug/L 46.650 93 60-140
trans-1,2-Dichloroethene ug/L 49.350 99 60-140
trans-1,3-Dichloropropene ug/L 57.050 114 60-140
Trichloroethene ug/L 51.550 103 60-140
Trichlorofluoromethane ug/L 45.650 91 60-140
Vinyl chloride ug/L 46.750 93 60-140
1,2-Dichloroethane-d4 (S) % 99 70-130
4-Bromofluorobenzene (S) % 101 70-130
Toluene-d8 (S) % 97 70-130
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2632029LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.350 99 60-140
1,1,1-Trichloroethane ug/L 48.750 97 60-140
1,1,2,2-Tetrachloroethane ug/L 47.850 96 60-140
1,1,2-Trichloroethane ug/L 51.150 102 60-140
1,1-Dichloroethane ug/L 48.550 97 60-140
1,1-Dichloroethene ug/L 47.950 96 60-140
1,1-Dichloropropene ug/L 47.450 95 60-140
1,2,3-Trichlorobenzene ug/L 38.550 77 60-140
1,2,3-Trichloropropane ug/L 49.050 98 60-140
1,2,4-Trichlorobenzene ug/L 43.050 86 60-140
1,2,4-Trimethylbenzene ug/L 43.950 88 60-140
1,2-Dibromo-3-chloropropane ug/L 44.050 88 60-140
1,2-Dibromoethane (EDB) ug/L 48.350 97 60-140
1,2-Dichlorobenzene ug/L 43.550 87 60-140
1,2-Dichloroethane ug/L 50.850 102 60-140
1,2-Dichloropropane ug/L 51.050 102 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2632029LABORATORY CONTROL SAMPLE:
LCSSpike
1,3,5-Trimethylbenzene ug/L 43.450 87 60-140
1,3-Dichlorobenzene ug/L 43.250 86 60-140
1,3-Dichloropropane ug/L 51.250 102 60-140
1,4-Dichlorobenzene ug/L 43.150 86 60-140
2,2-Dichloropropane ug/L 42.750 85 60-140
2-Chlorotoluene ug/L 43.050 86 60-140
4-Chlorotoluene ug/L 43.850 88 60-140
Benzene ug/L 50.550 101 60-140
Bromobenzene ug/L 45.350 91 60-140
Bromochloromethane ug/L 48.550 97 60-140
Bromodichloromethane ug/L 51.650 103 60-140
Bromoform ug/L 47.950 96 60-140
Bromomethane ug/L 50.950 102 60-140
Carbon tetrachloride ug/L 47.150 94 60-140
Chlorobenzene ug/L 46.950 94 60-140
Chloroethane ug/L 41.350 83 60-140
Chloroform ug/L 51.150 102 60-140
Chloromethane ug/L 43.150 86 60-140
cis-1,2-Dichloroethene ug/L 47.950 96 60-140
cis-1,3-Dichloropropene ug/L 52.250 104 60-140
Dibromochloromethane ug/L 47.250 94 60-140
Dibromomethane ug/L 52.450 105 60-140
Dichlorodifluoromethane ug/L 42.750 85 60-140
Diisopropyl ether ug/L 48.450 97 60-140
Ethylbenzene ug/L 48.350 97 60-140
Hexachloro-1,3-butadiene ug/L 45.950 92 60-140
Isopropylbenzene (Cumene) ug/L 48.050 96 60-140
m&p-Xylene ug/L 94.9100 95 60-140
Methyl-tert-butyl ether ug/L 49.150 98 60-140
Methylene Chloride ug/L 50.650 101 60-140
n-Butylbenzene ug/L 47.550 95 60-140
n-Propylbenzene ug/L 45.050 90 60-140
Naphthalene ug/L 41.450 83 60-140
o-Xylene ug/L 48.750 97 60-140
sec-Butylbenzene ug/L 45.250 90 60-140
Styrene ug/L 47.250 94 60-140
tert-Butylbenzene ug/L 38.850 78 60-140
Tetrachloroethene ug/L 47.550 95 60-140
Toluene ug/L 51.050 102 60-140
trans-1,2-Dichloroethene ug/L 48.850 98 60-140
trans-1,3-Dichloropropene ug/L 48.950 98 60-140
Trichloroethene ug/L 50.850 102 60-140
Trichlorofluoromethane ug/L 44.050 88 60-140
Vinyl chloride ug/L 50.650 101 60-140
1,2-Dichloroethane-d4 (S) % 92 70-130
4-Bromofluorobenzene (S) % 105 70-130
Toluene-d8 (S) % 97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2630971MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92436280011
2630972
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 400 104 60-140106 2 30400ND 418 424
1,1,1-Trichloroethane ug/L 400 108 60-140104 4 30400ND 434 416
1,1,2,2-Tetrachloroethane ug/L 400 103 60-140107 3 30400ND 414 428
1,1,2-Trichloroethane ug/L 400 109 60-140107 2 30400ND 435 429
1,1-Dichloroethane ug/L 400 110 60-140109 1 30400ND 438 435
1,1-Dichloroethene ug/L 400 111 60-140111 0 30400ND 444 444
1,1-Dichloropropene ug/L 400 109 60-140106 3 30400ND 437 423
1,2,3-Trichlorobenzene ug/L 400 103 60-140102 1 30400ND 412 408
1,2,3-Trichloropropane ug/L 400 107 60-140109 1 30400ND 428 434
1,2,4-Trichlorobenzene ug/L 400 103 60-140100 3 30400ND 410 398
1,2,4-Trimethylbenzene ug/L 400 84 60-14087 2 30400264 600 612
1,2-Dibromo-3-
chloropropane ug/L 400 96 60-140100 4 30400ND 383 398
1,2-Dibromoethane (EDB) ug/L 400 102 60-140106 3 30400ND 410 423
1,2-Dichlorobenzene ug/L 400 96 60-14094 2 30400ND 384 378
1,2-Dichloroethane ug/L 400 103 60-140108 5 30400ND 411 431
1,2-Dichloropropane ug/L 400 116 60-140114 2 30400ND 463 454
1,3,5-Trimethylbenzene ug/L 400 124 60-140124 0 30400ND 497 497
1,3-Dichlorobenzene ug/L 400 94 60-14093 1 30400ND 377 373
1,3-Dichloropropane ug/L 400 115 60-140110 5 30400ND 460 439
1,4-Dichlorobenzene ug/L 400 94 60-14095 1 30400ND 377 382
2,2-Dichloropropane ug/L 400 109 60-140109 0 30400ND 436 435
2-Chlorotoluene ug/L 400 98 60-14099 1 30400ND 392 395
4-Chlorotoluene ug/L 400 98 60-14098 0 30400ND 392 391
Benzene ug/L 400 121 60-140136 4 30400852 1340 1400
Bromobenzene ug/L 400 101 60-14098 2 30400ND 403 394
Bromochloromethane ug/L 400 106 60-140105 1 30400ND 423 420
Bromodichloromethane ug/L 400 107 60-140109 2 30400ND 427 437
Bromoform ug/L 400 95 60-14097 2 30400ND 380 389
Bromomethane ug/L 400 100 60-14097 2 30400ND 398 390
Carbon tetrachloride ug/L 400 105 60-140103 2 30400ND 421 411
Chlorobenzene ug/L 400 103 60-140103 0 30400ND 411 413
Chloroethane ug/L 400 108 60-140105 3 30400ND 432 420
Chloroform ug/L 400 115 60-140112 3 30400ND 462 448
Chloromethane ug/L 400 81 60-14083 2 3040016.8 340 348
cis-1,2-Dichloroethene ug/L 400 108 60-140107 1 30400ND 432 427
cis-1,3-Dichloropropene ug/L 400 115 60-140115 0 30400ND 458 460
Dibromochloromethane ug/L 400 98 60-14099 1 30400ND 394 396
Dibromomethane ug/L 400 113 60-140112 0 30400ND 450 449
Dichlorodifluoromethane ug/L 400 96 60-14095 1 30400ND 382 378
Diisopropyl ether ug/L 400 107 60-140105 2 30400ND 429 420
Ethylbenzene ug/L 400 106 60-140127 5 304001100 1530 1610
Hexachloro-1,3-butadiene ug/L 400 107 60-140103 3 30400ND 428 414
Isopropylbenzene
(Cumene)
ug/L 400 105 60-140104 1 3040040.1 459 457
m&p-Xylene ug/L 800 91 60-140105 4 308001780 2510 2620
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92436549
Johnsons Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2630971MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92436280011
2630972
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 400 106 60-140107 0 30400ND 426 427
Methylene Chloride ug/L 400 111 60-140109 1 30400ND 443 437
n-Butylbenzene ug/L 400 111 60-140109 2 30400ND 445 437
n-Propylbenzene ug/L 400 118 60-140117 1 30400ND 473 467
Naphthalene ug/L 400 91 60-140101 6 30400315 678 721
o-Xylene ug/L 400 96 60-140106 4 30400586 972 1010
sec-Butylbenzene ug/L 400 103 60-140100 3 30400ND 410 400
Styrene ug/L 400 105 60-140104 1 30400ND 421 417
tert-Butylbenzene ug/L 400 87 60-14085 3 30400ND 348 339
Tetrachloroethene ug/L 400 110 60-140106 4 30400ND 441 423
Toluene ug/L M1400 97 60-140153 7 304002530 2910 3140
trans-1,2-Dichloroethene ug/L 400 111 60-140110 1 30400ND 444 438
trans-1,3-Dichloropropene ug/L 400 102 60-140105 4 30400ND 407 422
Trichloroethene ug/L 400 112 60-140113 1 30400ND 447 451
Trichlorofluoromethane ug/L 400 104 60-140102 1 30400ND 414 408
Vinyl chloride ug/L 400 110 60-140113 3 30400ND 439 450
1,2-Dichloroethane-d4 (S) % 91 70-13090
4-Bromofluorobenzene (S) % 103 70-130104
Toluene-d8 (S) % 100 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 29
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92436549
Johnsons Grocery
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 29
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92436549
Johnsons Grocery
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92436549001 487327MW 6 SM 6200B
92436549002 487239MW 12 SM 6200B
92436549003 487239SW 2 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/19/2019 10:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 29
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