FA-114_5189_CA_MRP_20230509

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
May 9, 2023

Mr. Ken Currie
NCDEQ-UST Section
Fayetteville Regional Office
Systel Building
225 Green Street, Suite 714
Fayetteville, NC 28301-5043

Re: Ground Water Monitoring Report
April 2023
John’s Citgo Service, Inc.
1205 North Main Street
Red Springs, Robeson County
North Carolina
Facility ID Number: 0-00-0000021055
Incident Number: 5189
GRI Project Number: 5008

Dear Mr. Currie,

Please find attached the referenced report for the abovementioned site.
If you have any questions, please contact William Regenthal at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Johnny Robertson; John’s Texaco Service, Inc. file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Ground Water Monitoring Report
April 2023
John’s Citgo Service, Inc.
211 North Main Street
Red Springs, Robeson County
North Carolina
Facility ID Number: 0-00-0000021055
Incident Number: 5189
GRI Project Number: 5008

Prepared for:

Mr. Johnny Robertson
John’s Texaco Service, Inc.
211A North Main Street
Red Springs, NC 28377

May 9, 2023

William Regenthal, P.G.
Project Manager
Colton Coolbaugh, G.I.T.
Staff Scientist

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
i
SITE INFORMATION
1. Site Identification
 John’s Citgo Service, Inc. (Facility ID 0-00-0000021055)
 Incident Number 5189 – Intermediate Risk (I170D)
 Location of Source Area: 211 North Main Street
Red Springs, NC 28677
Robeson County
34.818453°N, 79.182021°W (Topographical Map)

2. Information about Contacts Associated with the Leaking UST System

UST Owner
John’s Texaco Service Inc.
211 North Main Street
Red Springs, NC 28377
[e-mail]
910-843-8574

UST Operator
John’s Texaco Service Inc.
211 North Main Street
Red Springs, NC 28377
[e-mail]
910-843-8574

Property Owner
John’s Texaco Service Inc.
211 North Main Street
Red Springs, NC 28377
[e-mail]
910-843-8574

Property Occupant
RS Motors
211 North Main Street
Red Springs, NC 28377
Email Unknown
910-843-8574

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-698-1253

Analytical Laboratory
SGS North America, Inc.
4405 Vineland Road, Suite C-15
Orlando, FL 32811
State Certification No. 573
407-425-6700
3. Information about Release
 A release was discovered on January 8, 2019, during UST removal activities. A past release (UST
Incident #5189) was reported for the site in August 1989.
 An unknown amount of product was released from the leaking UST System
 One 4,000-gallon gasoline, one 1,000-gallon diesel, two 8,000-gallon gasoline and two 10,000-
gallon gasoline USTs, associated dispensers and product piping were removed on January 7 and
8, 2019. Four 4,000-gallon gasoline USTs were removed from the site on December 21, 1988.
One 1,000-gallon kerosene and one 550-gallon oil USTs were removed from the site on August 6,
1996.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
ii
EXECUTIVE SUMMARY
John’s Citgo Service, Inc. is located at 211 North Main Street in Red Springs, Robeson County, North
Carolina. The site is currently occupied by a used automobile dealership. The adjoining properties are
commercial and residential. On January 7 and 8, 2019, one 1,000-gallon diesel, one 4,000-gallon gasoline,
two 10,000-gallon gasoline, and two 8,000-gallon gasoline USTs, associated dispensers, and product
piping were removed from the site. Four 4,000-gallon gasoline USTs were removed from the site on
December 21, 1988. One 1,000-gallon kerosene and one 550-gallon oil USTs were removed from the site
on August 6, 1996. A release was reported in August 1989 and UST Incident #5189 was assigned.

Based on the March 2019 receptor survey, three non-potable water supply wells were identified within a
1,500-foot radius of the site. No water supply wells were identified within a 250-foot radius of the source
area. Public water is available to the site and the surrounding properties. A small, spring-fed wetland has
been identified approximately 430 feet north of the source area.

On April 4, 2023, eight Type II monitoring wells (MW-2, MW-3, MW-5, GMW-1, GMW-3, GMW-4, GMW-
7 and GMW-8) were gauged, purged and sampled in accordance with NCDEQ guidelines. Concentrations
of individual BTEX constituents, MTBE, naphthalene, n-butylbenzene, p-isopropyltoluene, n-
propylbenzene, vinyl chloride, 1,2,4-trimethylbenzene and/or 1,3,5-trimethylbenzene that exceeded the
MACs were reported in the ground water samples collected from GMW-1, GMW-3, GMW-4, GMW-7,
GMW-8, MW-2 and MW-3. Concentrations of benzene and/or toluene that exceeded ten times the NCAC
2B Surface Water Standards were reported in the ground water samples collected from GMW-7, MW-2
and MW-3. All of the reported contaminant concentrations were less than the GCLs. Free product was
not observed.

The contaminant mass at the site has reduced 81% since May 2020.

Based on this information, a contaminant Fate & Transport Model should be completed and a change of
site risk classification can be considered pending the results.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
TABLE OF CONTENTS
SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION ...................................................................................................2
3.0 FREE PRODUCT REMOVAL ........................................................................................................4
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ..................................4
5.0 PROPOSED REMEDIAL ACTION .................................................................................................4
6.0 CONCLUSIONS .........................................................................................................................5
7.0 LIMITATIONS ...........................................................................................................................5
8.0 STATEMENTS AND CERTIFICATION ...........................................................................................5

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Site Vicinity Map
Figure 4: Water Table Surface Map
Figure 5: Ground Water Quality Map
Figure 6: Estimated Contaminant Mass Area Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Water Supply Well Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Ground Water Sample Analytical Results
Table 6A: Summary of Natural Attenuation Parameter Results

APPENDICES
Appendix A: State Correspondence
Appendix B: Laboratory Report – Ground Water Samples
Appendix C: Contaminant Mass Calculations

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the April 2023 ground water sampling event at the John’s Citgo Service, Inc.
site; located at 211 North Main Street in Red Springs, Robeson County, North Carolina (Figure 1). These
activities were conducted in accordance with GRI Proposal No. 22-837, which was submitted to NCDEQ
on February 15, 2023, and was approved as Task Authorization No. 5189-013 on February 16, 2023. State
correspondence has been included as Appendix A.

The site is currently owned by John’s Texaco Service, Inc. The former petroleum retail facility and
convenience store was also operated by John’s Texaco Service, Inc. The site is currently occupied by a
used automotive dealership. On January 7 and 8, 2019, one 1,000-gallon diesel, one 4,000-gallon gasoline,
two 10,000-gallon gasoline, and two 8,000-gallon gasoline USTs, associated dispensers and product piping
were removed from the site. Four 4,000-gallon gasoline USTs were removed from the site on December
21, 1988. One 1,000-gallon kerosene and one 550-gallon oil USTs were removed from the site on August
6, 1996. A release was reported in August 1989 and UST Incident #5189 was assigned. UST
owner/operator information and UST system information are included as Tables 1 and 2, respectively.
The Registered Tank Report is shown below:

During past assessment activities, fourteen Type II monitoring wells (MW-1 through MW-6 and GMW-1
through GMW-8) and one Type III monitoring well (TW-1) were installed at the site. MW-1 has since been

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
2
destroyed, and MW-6 has historically been a dry well. A Site Map showing the locations of the monitoring
wells and the structures on-site has been included as Figure 2.

A receptor survey was conducted on March 22, 2019. Three non-potable water supply wells were
identified within a 1,500-foot radius of the site. No water supply wells were identified within a 250-foot
radius of the source area. Public water is available to the site and the surrounding properties. Water
supply well information is presented in Table 3. Adjacent property owner information is presented in
Table 4.

A small, spring-fed wetland was identified approximately 430 feet north of the site. Based on the presence
of surface water bodies within 500 feet of the source area, the existence of free product and ground water
contaminant concentrations above ten times the NCAC 2B surface water standards, the site’s risk had
been classified as intermediate. A Site Vicinity Map showing the adjacent properties, water supply well
locations and the location of the surface water body has been included as Figure 3.

A CAP has not been developed for this incident.
2.0 PRESENTATION OF CURRENT SITE ASSESSMENT INFORMATION/ COMPARISON TO HISTORICAL
ASSESSMENT INFORMATION
On April 4, 2023, eight Type II monitoring wells (MW-2, MW-3, MW-5, GMW-1, GMW-3, GMW-4, GMW-
7 and GMW-8) were gauged, purged and sampled in accordance with NCDEQ guidelines. Depths to
ground water in the Type II monitoring wells ranged from 11.07 feet to 13.35 feet below the tops of well
casings. Ground water elevations in the Type II monitoring wells ranged from 84.75 feet to 87.79 feet.
Ground water flow was generally to the northeast with a horizontal hydraulic gradient of approximately
0.02 feet per foot. Well construction and gauging information is presented in Table 5. A Water Table
Surface Map based on the Type II monitoring wells is included as Figure 4. A summary of the current
ground water gauging data is shown below:
Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
GMW-1 6 - 16 16 100.00 12.21 --- 87.79
GMW-3 10 - 20 20 98.96 11.96 --- 87.00
GMW-4 10 – 20 20 97.89 11.52 --- 86.37
GMW-7 10 – 20 20 100.27 12.57 --- 87.70
GMW-8 10 – 20 20 97.68 11.07 --- 86.61
MW-2 Unknown 30 100.65 13.35 --- 87.30
MW-3 Unknown 20 100.23 12.44 --- 87.79
MW-5 Unknown 40 96.30 11.55 --- 84.75
Ground water samples collected from the monitoring wells were submitted for laboratory analyses of
VOCs using EPA Method 6200B and natural attenuation parameters (nitrate, sulfate, ferrous iron and
methane). Additionally, field parameters (dissolved oxygen, oxidation reduction potential, temperature,
pH and conductivity) were measured for all sampled wells.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
3
Concentrations of individual BTEX constituents, MTBE, naphthalene, n-butylbenzene, p-isopropyltoluene,
n-propylbenzene, vinyl chloride, 1,2,4-trimethylbenzene and/or 1,3,5-trimethylbenzene that exceeded
the MACs were reported in the ground water samples collected from GMW-1, GMW-3, GMW-4, GMW-7,
GMW-8, MW-2 and MW-3. Concentrations of benzene and/or toluene that exceeded ten times the NCAC
2B Surface Water Standards were reported in the ground water samples collected from GMW-7, MW-2
and MW-3. All of the reported contaminant concentrations were less than the GCLs. Free product was
not observed. A summary of the analytical results for ground water samples collected on April 4, 2023, is
presented in Table 6. A summary of natural attenuation parameter results is presented in Table 6A. A
Ground Water Quality Map based on the April 2023 data is included as Figure 5. A complete report of
laboratory analyses of the ground water samples collected from the monitoring wells during the April
2023 sampling event has been included as Appendix B. A summary of the current ground water analytical
data is shown below:

Contaminant of
Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MACs (µg/l) 1 600 600 500 20 6
GCL (µg/l) 5,000 260,000 84,500 85,500 20,000 6,000
10 x 2B SW (µg/l) 510 110 NE NE NE NE
GMW-1 2.3 17.9 3.6 37.3 0.67 4.2
GMW-3 2.9 17.4 13.9 73.8 <0.13 11.8
GMW-4 18.3 31.2 64.4 236 0.91 J 25.6
GMW-7 405 3,590 1,310 7,760 290 306
GMW-8 1.8 1.8 1.9 5.1 0.43 J 3.1
MW-2 215 2,940 1,180 6,730 <6.3 298
MW-3 749 10,200 2,510 13,500 176 639
MW-5 <0.13 1.7 0.86 4.7 <0.13 1.9
TB (Trip Blank) <0.13 11 <0.13 <0.25 639 <0.13

The baseline contaminant mass at the site was determined based on the total BTEX, MTBE, and
naphthalene concentrations from the May 2020 ground water sampling event as well as the maximum
historical water column height observed in each area. The contaminant plume consists of one area based
on the toluene concentrations during the May 2020 ground water sampling event. The contaminant mass
at the site had decreased by 81% between May 2020 and April 2023. Please note, MW-4, GMW-5 and
GMW-6 were not sampled during the April 2023 sampling event and the last known concentrations were
used for calculations. Contaminant mass calculations have been included as Appendix C. A map of the
contaminant mass area has been included as Figure 6. A chart depicting the overall contaminant mass
trend is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
4

The site is located in the Coastal Plain Physiographic Province of North Carolina. The water table has a
seasonal high depth to water of approximately nine to fifteen feet bgs.

Please note that since a CAP has not been completed for the site, contaminant milestones have not been
established.
3.0 FREE PRODUCT REMOVAL
During the April 2023 sampling event, no free product was observed. Free product has historically been
present in GMW-5 and MW-3. An AFVR event was conducted on MW-3 in October 2019 and GMW-5 in
January 2022. Free product has not been detected in MW-3 since 2020 and in GMW-5 since January 2022.
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
Since a CAP has not been developed for this incident, no natural attenuation monitoring plan is currently
in place at the site. No contaminant reduction milestones have been established for this incident.
5.0 PROPOSED REMEDIAL ACTION
Prior to the discovery of free product in GMW-5, the proposed remedial action for the incident was to
complete a Contaminant Fate & Transport Model in order to determine if contaminant constituents would
reach the spring-fed wetland area within 500 feet of the site. The Contaminant Fate & Transport Model

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: May 9, 2023 John’s Citgo Service, Inc.
Project Manager: William Regenthal, P.G. GRI Project No. 5008
5
could not be completed due to the presence of free product. Additionally, due to the drop in the ground
water level at the site since 2021, insufficient water volume has been present in wells at the site to allow
for proper analyses collection. Ground water was sufficient during the April 2023 sampling event and
natural attenuation parameters were able to be collected. A contaminant Fate & Transport Model can
now be completed, and the risk classification can be re-evaluated.
6.0 CONCLUSIONS
 On April 4, 2023, eight Type II monitoring wells MW-2, MW-3, MW-5, GMW-1, GMW-3, GMW-4,
GMW-7 and GMW-8) were gauged, purged and sampled in accordance with NCDEQ guidelines.
 Ground water flow was generally to the northeast with a horizontal hydraulic gradient of
approximately 0.02 feet per foot.
 Concentrations of individual BTEX constituents, MTBE, naphthalene, n-butylbenzene, p-
isopropyltoluene, n-propylbenzene, vinyl chloride, 1,2,4-trimethylbenzene and/or 1,3,5-
trimethylbenzene that exceeded the MACs were reported in the ground water samples collected
from GMW-1, GMW-3, GMW-4, GMW-7, GMW-8, MW-2 and MW-3. Concentrations of benzene
and/or toluene that exceeded ten times the NCAC 2B Surface Water Standards were reported in
the ground water samples collected from GMW-7, MW-2, and MW-3. All of the reported
contaminant concentrations were less than the GCLs. Free product was not observed.
 The contaminant mass at the site has decreased by 81% since May 2020.
 Based on this information, a contaminant Fate & Transport Model should be completed and a
change of site risk classification can be considered pending the results.
7.0 LIMITATIONS
This report has been prepared for the exclusive use of John’s Texaco Service, Inc. for specific application
to the referenced site in Robeson County, North Carolina. The assessment was conducted based on the
scope of work and level of effort desired by NCDEQ and with resources adequate only for that scope of
work. Our findings have been developed in accordance with generally accepted standards of
environmental practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.
8.0 STATEMENTS AND CERTIFICATION
1 Enter the date the monitoring report was due. n/a Will this report be submitted after the
established due date?
YES NO
2 Was any required information from the above template missing from this report? YES NO

FIGURES
Copyright (C) 2009 MyTopo
SCALE 1:24000
0 1000 2000 3000 4000 5000
FEET
Declination
MN 8.65° W
MN
Location: 034.8184530° N 079.1820210° WDate: 01/22/19
Scale: 1 inch = 2,000 ft.
Copyright (C) 2009 MyTopo
Figure 1
Site Location Map
John's Citgo Service Inc.
211 North Main Street, Red Springs, Robeson County,
NC
Incident No. 5189
GRI Project No. 5008
"J
"J
"J
SITE
934858577200
934858396000
934858694800
934859307300
934858293400934848453400 934858274300934858586600
934848078800 934858374400
934859522100
WSW-3
WSW-2
WSW-1
LITTLE RAFT SWAMP
THIRD AVE MAIN STVANCE STCOLLEGE STCHURCH STDFA
FO U R TH AVESHANNON RDROBERTS ST
MCMILLAN AVECROSS STJAMES ST
SECOND AVEBROWN ST
SARATOGA STPEACHTREE STWI
L
LI
AMS STFIRST AVE
HACKETT ST
MCNEILL DRCOPPEDGE STCHARLEVEAUX STJOHN C RAY STMCRAE STFIFTH AVE MT TABOR RDDFADFA
SECOND AVE
SECOND AVE
DFADFASECOND AVE
FIRST AVE
FIGURE 3: SITE VICINITY MAPJOHN'S CITGO SERVICE, INC.211 N. MAIN STREETRED SPRINGS, ROBESON COUNTYNORTH CAROLINAINCIDENT NO. 5189GRI PROJECT NO. 5008
PREPARED BY:GEOLOGICAL RESOURCES, INC.MARCH 15, 2019
0 300150
Feet1 inch = 300 feet
³
1,500-FOOT RADIUS
1,000-FOOT RADIUS
500-FOOT RADIUS 250-FOOT RADIUS
LEGEND
Zoning CB
"J Water Supply Well
Well Owners and Adjacent Properties
ncrivers
StreetCenterlinesSep28
hydromaj_poly
Robeson County NC Parcels_2018_06_22
ZONE R
ZONE CB
ZONE R

TABLES
UST ID Number 7 - 8 Facility ID Number
Owner or Operator?
Owner and Operator
UST ID Number 2 Facility ID Number
Owner or Operator?
Owner and Operator
UST ID Number 1, 5, 6 Facility ID Number
Owner or Operator?
Owner and Operator
UST ID Number 3, 4, 12, 13 Facility ID Number
Owner or Operator?
Owner and Operator
UST ID Number 9 Facility ID Number
Owner or Operator?
Owner and Operator
UST ID Number 10 Facility ID Number
Owner or Operator?
Owner and Operator
UST ID Number 11 Facility ID Number
Owner or Operator?
Owner and Operator
211 North Main Street, Red Springs, NC 28377 910-843-8574
0-021055
Name of Owner or Operator Dates of Ownership / Operation
John's Texaco Service, Inc. 10/09/1988 - 01/07/2019
Address Telephone Number
TABLE 1
UST OWNER/OPERATOR INFORMATION
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
0-021055
Name of Owner or Operator Dates of Ownership / Operation
John's Texaco Service, Inc. 10/14/1961 - 01/08/2019
Address Telephone Number
211 North Main Street, Red Springs, NC 28377 910-843-8574
211 North Main Street, Red Springs, NC 28377 910-843-8574
0-021055
0-021055
Name of Owner or Operator Dates of Ownership / Operation
John's Texaco Service, Inc. 12/21/1988 - 01/07/2019
Address
Address Telephone Number
211 North Main Street, Red Springs, NC 28377 910-843-8574
Telephone Number
0-021055
Name of Owner or Operator Dates of Ownership / Operation
John's Texaco Service, Inc. 12/21/1988 - 01/07/2019
Address Telephone Number
Name of Owner or Operator Dates of Ownership / Operation
John's Texaco Service, Inc. 12/21/1988 - 08/06/1996
Address Telephone Number
Name of Owner or Operator Dates of Ownership / Operation
211 North Main Street, Red Springs, NC 28377 910-843-8574
0-021055
John's Texaco Service, Inc. 09/28/1960 - 08/21/1997
Telephone Number
211 North Main Street, Red Springs, NC 28377 910-843-8574
211 North Main Street, Red Springs, NC 28377 910-843-8574
0-021055
Name of Owner or Operator Dates of Ownership / Operation
John's Texaco Service, Inc. 09/27/1967 - 08/06/1996
Address
Page 1 of 1
Date: 07/09/19
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline Gasoline 4,000 12/21/1988 Single Wall Steel 64" x 24' Single Wall FRP
Removed
(01/07/19) Yes
2 Diesel Diesel 1,000 10/09/1988
Single Wall
Steel/FRP 64" x 72"Single Wall
Steel
Removed
(01/07/19) Yes
5 Gasoline Gasoline 8,000 12/21/1988
Single Wall
Steel/FRP 8' x 21' 4" Single Wall FRP
Removed
(01/07/19) Yes
6 Gasoline Gasoline 8,000 12/21/1988
Single Wall
Steel/FRP 8' x 21' 4" Single Wall FRP
Removed
(01/07/19) Yes
7 Gasoline Gasoline 10,000 10/14/1961
Single Wall
Steel/FRP 8' x 26' 7" Single Wall FRP
Removed
(01/08/19) Yes
8 Gasoline Gasoline 10,000 10/14/1961
Single Wall
Steel/FRP 8' x 26' 7" Single Wall FRP
Removed
(01/08/19) Yes
9 Kerosene Kerosene 1,000 12/21/1988 Single Wall Steel 64" x 72"
Single Wall
Steel
Removed
(08/06/96) Yes
10 Gasoline Gasoline 10,000 09/28/1960 Single Wall Steel 8' x 26' 7"
Single Wall
Steel
Removed
(08/21/97) Yes
11 Oil Oil 550 09/27/1967 Single Wall Steel 46" x 74"
Single Wall
Steel
Removed
(08/06/96) Yes
12 Gasoline Gasoline 4,000 10/14/1967 Single Wall Steel 64" x 24' Unknown
Removed
(12/21/88) Yes
13 Gasoline Gasoline 4,000 10/14/1961 Single Wall Steel 64" x 24' Unknown
Removed
(12/21/88) Yes
TABLE 2
UST SYSTEM INFORMATION
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Facility ID #: 0-021055
Date
Installed
Construction
Details
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Page 1 of 1
Date: 03/28/19
Well # Tax Pin #Well
Owner Mailing Address Physical Well
Address
Well
Use Municipal
Water?
Well
Depth
(ft BGS)
Type
of
Well
(Drilled/
Bored)
Well
Casing
Depth
(ft. BGS)
Well
Screen
Interval
(x to y
ft. BGS)
Approximate
Distance
from
Contaminant
Plume Edge
(ft.)
WSW-1 934859522100 Town of Red Springs
217 S. Main Steet,
Red Springs, NC
28377
Main Street
Active
/Non-Potable Yes Unkown Unknown Unknown Unknown 328'
WSW-2

934848078800 Ronald W. and Angela H. Hall
112 Coppedge
Street. Red Springs,
NC 28377
112 Coppedge
Street. Red Springs,
NC 28377
Active
/Non-Potable Yes Unkown Unknown Unknown Unknown 1,300'
WSW-3 934848453400
Marvin O. Dice Jr & wife Lisa R.
Cooper
106 Church Street,
Red Springs, NC
28377
106 Church Street,
Red Springs, NC
28377
Active
/Non-Potable Yes Unkown Unknown Unknown Unknown 1,053'
• Water supply wells are keyed to Figure 2.
TABLE 3
WATER SUPPLY WELL INFORMATION
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Facility ID # : 0-021055
Note:
Page 1 of 1
Date: 07/09/19 Facility ID #: 0-021055
934858396000 (site) John's Texaco Service Inc. P.O. Box 466, Red Springs, NC 28377
934859307300 John J. McMillan 106 Huntington Ln., Red Springs, NC 28377
934858293400 Cheryl Locklear P.O. Box 1240, Pembroke, NC 28372
934858586600 Tamim Al Saedi and Sadig Al Saedi et al 210 North Main St., Red Springs, NC 28377
934858694800 Robertson John P III & wife Janet F. Robertson 211 North Main St., Red Springs, NC 28377
934858577200 Robert Lee Jr. & wife Jamie G. Vahoy 3892 Oxendine School Rd., Maxton, NC 28364
934858374400 Vance B. & wife Delores Neal 109 Parkview Ave., Fayettville, NC 28305
934858274300 John's Texaco Service Inc. 211 North Main St., Red Springs, NC 28377
Note:
• Properties are keyed to Figure 3.
TABLE 4
ADJACENT PROPERTY OWNER INFORMATION
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Tax Pin Number Property Owner Name Mailing Address
Page 1 of 1
Date: 04/28/2023
02/19/19 11.07 ---88.93
07/01/19 13.10 ---86.90
11/11/19 14.69 ---85.31
05/06/20 11.84 ---88.16
09/29/20 12.27 ---87.73
01/25/21 10.55 ---89.45
07/07/21 13.55 ---86.45
01/05/22 15.48 ---84.52
06/09/22 14.25 ---85.75
10/05/22 14.64 ---85.36
04/04/23 12.21 ---87.79
02/19/19 12.26 ---88.22
07/01/19 13.74 ---86.74
11/11/19 15.31 ---85.17
05/06/20 12.00 ---88.48
09/29/20 8.80 ---91.68
01/25/21 5.19 ---95.29
01/05/22 15.43 ---85.05
06/09/22 15.22 ---85.26
10/05/22 14.06 ---86.42
11/11/19 14.46 ---84.50
05/06/20 11.60 ---87.36
09/29/20 11.90 ---87.06
01/25/21 10.39 ---88.57
07/07/21 13.51 ---85.45
01/05/22 14.82 ---84.14
06/09/22 14.14 ---84.82
10/05/22 13.50 ---85.46
04/04/23 11.96 ---87.00
11/11/19 13.18 ---84.71
05/06/20 10.55 ---87.34
09/29/20 10.74 ---87.15
01/25/21 8.95 ---88.94
01/05/22 13.70 ---84.19
06/09/22 12.61 ----85.28
10/05/22 12.76 ----85.13
04/04/23 11.52 ---86.37
11/11/19 14.66 ---85.40
05/06/20 11.84 ---88.22
09/29/20 12.26 ---87.80
01/25/21 10.46 ---89.60
01/05/22 16.33 0.81 84.43
03/15/22 14.50 0.10 85.65
06/09/22 14.11 ---85.95
10/05/22 14.51 ---85.55
11/11/19 15.63 ---85.03
05/06/20 12.50 ---88.16
09/29/20 12.91 ---87.75
01/25/21 10.79 ---89.87
01/05/22 16.17 ---84.49
06/09/22 13.38 ---87.28
10/05/22 14.83 ---85.83
11/11/19 15.41 ---84.86
05/06/20 12.40 ---87.87
09/29/20 12.51 ---87.76
01/25/21 10.88 ---89.39
07/07/21 14.31 ---85.96
01/05/22 15.89 ---84.38
06/09/22 14.56 ---85.71
10/05/22 14.41 ---85.86
04/04/23 12.57 ---87.70
05/06/20 11.13 ---86.55
09/29/20 11.36 ---86.32
01/25/21 10.03 ---87.65
01/05/22 14.50 ---83.18
06/09/22 12.61 ---85.07
10/05/22 13.36 ---84.32
04/04/23 11.07 ---86.61
GMW-3
100.00166 - 16602/18/19GMW-1
98.962010 - 201011/05/19
6 6 - 16 16 100.48
GMW-7
97.892010 - 201011/05/19GMW-4
100.272010 - 201011/05/19
100.66
11/05/19 10 10 - 20
97.682010 - 201005/05/20GMW-8
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Well ID
Date Water
Level
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Comments
Top of
Casing
Elevation*
(ft.)
Facility ID #: 0-021055
Well
Installation
(mm/dd/yy)
Bottom
of Well
(ft. BGS)
Depth to
Water from
Top of Casing
(ft)
GMW-5
GMW-6
Ground
Water
Elevation
(ft.)
Free Product
Thickness**
(ft.)
GMW-2 02/18/19
20 100.06
11/05/19 10 10 - 20 20
Page 1 of 2
Date: 04/28/2023
TABLE 5
WELL CONSTRUCTION AND GAUGING INFORMATION
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Well ID
Date Water
Level
Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Comments
Top of
Casing
Elevation*
(ft.)
Facility ID #: 0-021055
Well
Installation
(mm/dd/yy)
Bottom
of Well
(ft. BGS)
Depth to
Water from
Top of Casing
(ft)
Ground
Water
Elevation
(ft.)
Free Product
Thickness**
(ft.)
07/01/19 14.71 ---85.94
11/11/19 15.91 ---84.74
05/05/20 13.04 ---87.61
09/29/20 13.32 ---87.33
01/25/21 11.69 ---88.96
07/07/21 15.10 ---85.55
01/05/22 16.45 ---84.20
06/09/22 15.57 ---85.08
10/05/22 14.99 ---85.66
04/04/23 13.35 ---87.30
07/01/19 14.18 0.23 86.25
10/16/19 15.01 0.55 85.22 Before AFVR
10/16/19 DRY DRY DRY After AFVR
11/11/19 15.42 ---84.81
05/05/20 12.28 0.02 87.97
09/29/20 12.59 ---87.64
01/25/21 10.87 ---89.36
07/07/21 14.40 ---85.83
01/05/22 15.82 ---84.41
06/09/22 14.98 ---85.25
10/05/22 14.38 ---85.85
04/04/23 12.44 ---87.79
07/01/19 13.23 ---85.66
11/11/19 15.33 ---83.56
05/05/20 11.47 ---87.42
09/29/20 11.11 ---87.78
01/25/21 10.20 ---88.69
01/05/22 14.80 ---84.09
06/09/22 14.34 ---84.55
10/05/22 13.33 ---85.56
07/01/19 12.09 ---84.21
11/11/19 13.00 ---83.30
05/05/20 11.05 ---85.25
09/29/20 11.18 ---85.12
01/25/21 10.17 ---86.13
01/05/22 13.38 ---82.92
06/09/22 13.15 ---83.15
10/05/22 12.29 ---84.01
04/04/23 11.55 ---84.75
07/01/19 NM NM NM Dry
11/11/19 NM NM NM Dry
01/05/22 9.31 ---NM
05/05/20 41.05 ---56.99
09/29/20 10.01 ---88.03
01/25/21 9.21 ---88.83
1/5/2022 14.31 ---83.73
6/9/2022 14.45 ---83.59
10/05/22 12.41 ---85.63
Notes:
• ** : If free product is present in a well, groundwater elevation calculated by: [Top of Casing Elevation - Depth to Water] +
[free product thickness x 0.8581].
MW-2 100.6530unknownunknownunknown
MW-3
96.3040unknownunknownunknown
37 98.89unknownunknown
100.2320unknownunknownunknown
• NM: Not Measured.
• ft BGS : feet below ground surface.
NM11unknownunknownunknownMW-6
TW-1 05/05/20 45 45 - 50 50 98.04
• *: Reference point for elevation measurements, assumed elevation 100.00 ft.
unknownMW-4
MW-5
Page 2 of 2
Date: 04/28/2023
EPA
Method
504.1
EPA
Method
625
SW846
6010D
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 40 0.02 30 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 26,100 28,500 24,100 40,000 50 12,000 15,000 NE NE NE NE NE NE
510 110 NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE
02/19/19 4,620 36,100 4,670 24,500 632 792 142 J 381 J 3,080 812 2,060 J 5.3 681 111 82,400 13,100 J 48,300 4,030 49.4 J 910 B
07/01/19 2,960 22,900 5,310 26,400 <63 939 255 922 6,630 1,900 NR NR NR NR NR NR NR NR NR NR
11/11/19 3,700 28,400 3,950 20,800 372 581 152 J 398 2,990 836 NR NR NR NR NR NR NR NR NR NR
05/06/20 1,920 15,600 2,500 15,100 169 J 361 80.3 J 269 2,460 669 NR NR NR NR NR NR NR NR NR NR
09/29/20 1,970 17,900 3,510 19,500 <63 1,270 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 1,840 13,800 2,340 13,400 <63 467 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
07/07/21 1,070 9,420 1,420 8,480 <25 392 45.4 J 119 1,650 427 NR NR NR NR NR NR NR NR NR NR
01/05/22 979 9,820 1,950 12,600 <31 533 92.3 J 255 2,890 800 NR NR NR NR NR NR NR NR NR NR
06/09/22 992 7,890 1,410 12,400 77.2 J 779 77.3 203 2,860 869 NR NR NR NR NR NR NR NR NR NR
10/05/22 1,560 11,200 E 1,590 12,000 108 584 68.9 196 2,480 750 NR NR NR NR NR NR NR NR NR NR
04/04/23 2.3 17.9 3.6 37.3 0.67 4.2 0.30 J 0.61 11.5 3.7 NR NR NR NR NR NR NR NR NR NR
02/19/19 6.8 J 74.9 236 1,130 <0.13 146 49.9 154 1,450 353 <40 <0.0093 NR 15.7 2,850 <700 5,020 NR NR NR
07/01/19 0.64 3.9 17.6 62.8 <0.13 35.4 7.8 30.3 213 43 NR NR NR NR NR NR NR NR NR NR
11/11/19 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
05/06/20 0.34 J 0.84 0.56 1.7 15.6 0.61 0.22 J 1.3 NS 1.3 NR NR NR NR NR NR NR NR NR NR
09/29/20 <0.13 <0.13 <0.13 <0.25 2.8 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 NS NS NS NS NS NS NS NS NS NS NR NR NR NR NR NR NR NR NR NR
06/09/22 <0.180 <0.220 1.07 0.537 J 1.55 <0.470 <0.180 0.411 J 1.55 0.235 J NR NR NR NR NR NR NR NR NR NR
10/05/22 1.69 1.90 28.1 17.7 16.4 11.2 7.81 29.0 96.9 39.5 NR NR NR NR NR NR NR NR NR NR
11/11/19 355 3,280 715 2,870 19.0 J 148 28.4 J 43.4 J 320 91.1 NR NR NR NR NR NR NR NR NR NR
05/06/20 137 1,160 284 995 <3.1 55.0 8.4 J 17.4 127 28.8 NR NR NR NR NR NR NR NR NR NR
09/29/20 51 599 114 440 <2.5 25.9 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 80.0 921 212 860 <3.1 50.5 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
07/07/21 113 1,110 248 841 <3.1 45.1 6.8 J 13.3 83.8 19.3 NR NR NR NR NR NR NR NR NR NR
01/05/22 329 3,190 756 3,440 <6.3 196 24.2 J 43 414 104 NR NR NR NR NR NR NR NR NR NR
06/09/22 47.9 323 79.6 357 <1.40 24.5 2.40 J 4.31 J 52.4 13.1 NR NR NR NR NR NR NR NR NR NR
10/05/22 316 1,680 291 1,240 17.2 74.8 13.0 26.2 163 45.3 NR NR NR NR NR NR NR NR NR NR
04/04/23 2.9 17.4 13.9 73.8 <0.13 11.8 1.7 6.1 41.2 12.5 NR NR NR NR NR NR NR NR NR NR
11/11/19 11.6 10.6 7.8 55.1 4.1 1.9 0.82 2.3 6.3 2.8 NR NR NR NR NR NR NR NR NR NR
05/06/20 36.8 33.9 59.0 145 2.9 19.2 5.7 17.1 49.4 17.2 NR NR NR NR NR NR NR NR NR NR
09/29/20 43.8 9 44.1 43.2 1.1 19.5 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 53.8 4.6 56 72.3 <0.25 35.4 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 <0.13 <0.13 0.13 J 0.35 J <0.13 0.91 <0.13 0.41 J 1.4 0.77 NR NR NR NR NR NR NR NR NR NR
06/09/22 4.45 4.11 3.86 6.89 <0.140 4.28 0.773 1.46 3.75 0.412 J NR NR NR NR NR NR NR NR NR NR
10/05/22 78.9 223 140 683 9.11 47.1 18.8 53.4 220 77.4 NR NR NR NR NR NR NR NR NR NR
04/04/23 18.3 31.2 64.4 236 0.91 J 25.6 7.2 19.8 117 23.3 NR NR NR NR NR NR NR NR NR NR
11/11/19 <13 900 774 4,070 <13 205 58.8 241 1,770 528 NR NR NR NR NR NR NR NR NR NR
05/06/20 <1.3 130 160 793 <1.3 66.3 21.7 123 659 249 NR NR NR NR NR NR NR NR NR NR
09/29/20 <1.3 129 137 637 <1.3 66.9 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 <0.63 131 118 573 <0.63 51.1 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
03/15/22 31.2 1,290 679 3,700 <0.63 218 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
06/09/22 <18.0 310 377 2,150 <14.0 212 60.1 264 2,270 690 NR NR NR NR NR NR NR NR NR NR
10/05/22 <1.80 403 589 3,273.1 E <1.40 421 102 468 3,161.7 E 1,305.6 E NR NR NR NR NR NR NR NR NR NR
GMW-5
GMW-4
GMW-3
GMW-2
Contaminant of Concern

MAC (µg/l)
10 x 2B SW (µg/l)
GCL (µg/l)
GMW-1 C11-C22 AromaticsC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsC19-C36 AliphaticsLeadSM 6200B and/or SM 602
BenzeneIsopropylbenzenen-PropylbenzeneTolueneEthylbenzeneXylenes2-MethylnaphthaleneMTBEtert-Amyl alcohol(TAA)Naphthalene1,3,5-TrimethylbenzeneEDB1,2,4-TrimethylbenzeneTABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Analytical Method MADEP Method VPH MADEP Method EPH
Facility ID #: 0-021055
Page 1 of 3
Date: 04/28/2023
EPA
Method
504.1
EPA
Method
625
SW846
6010D
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 40 0.02 30 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 26,100 28,500 24,100 40,000 50 12,000 15,000 NE NE NE NE NE NE
510 110 NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE
Contaminant of Concern

MAC (µg/l)
10 x 2B SW (µg/l)
GCL (µg/l)C11-C22 AromaticsC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsC19-C36 AliphaticsLeadSM 6200B and/or SM 602
BenzeneIsopropylbenzenen-PropylbenzeneTolueneEthylbenzeneXylenes2-MethylnaphthaleneMTBEtert-Amyl alcohol(TAA)Naphthalene1,3,5-TrimethylbenzeneEDB1,2,4-TrimethylbenzeneTABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Analytical Method MADEP Method VPH MADEP Method EPH
Facility ID #: 0-021055
11/11/19 268 2,450 1,120 5,200 <6.3 151 65.9 186 1,340 380 NR NR NR NR NR NR NR NR NR NR
05/06/20 51.9 494 245 1,490 <2.5 66.0 11.0 37.0 386 119 NR NR NR NR NR NR NR NR NR NR
09/29/20 35 328 125 744 <1.3 53.9 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 8.7 79.6 51 202 <0.25 12.8 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 298 600 430 806 <13 129 16 33.5 417 43 NR NR NR NR NR NR NR NR NR NR
06/09/22 0.492 J 12.3 25.9 164 <0.140 52.2 7.88 41.5 425 134 NR NR NR NR NR NR NR NR NR NR
10/05/22 17.3 67.1 74.8 404 <0.140 25.2 9.04 26.7 197 49.4 NR NR NR NR NR NR NR NR NR NR
11/11/19 991 11,600 2,670 13,900 408 488 110 J 316 2,370 649 NR NR NR NR NR NR NR NR NR NR
05/06/20 733 7,680 2,250 12,400 387 368 85.2 J 280 2,350 620 NR NR NR NR NR NR NR NR NR NR
09/29/20 631 6,140 2,120 11,700 379 393 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 347 4,080 1,870 10,100 <13 433 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
07/07/21 379 4,530 2,000 11,400 <25 1,490 97.8 J 410 4,760 1,110 NR NR NR NR NR NR NR NR NR NR
01/05/22 466 5,400 E 2,880 15,700 E <13 928 206 685 5,240 E 1,460 NR NR NR NR NR NR NR NR NR NR
06/09/22 363 3,100 1,680 9,210 156 559 100 279 2,490 615 NR NR NR NR NR NR NR NR NR NR
10/05/22 432 4,120 1,940 10,500 161 656 114 325 2,610 680 NR NR NR NR NR NR NR NR NR NR
04/04/23 405 3,590 1,310 7,760 290 306 54.3 143 1,570 403 NR NR NR NR NR NR NR NR NR NR
05/06/20 37.7 97.6 156 674 2.9 45.4 12.7 40.5 248 62.8 NR NR NR NR NR NR NR NR NR NR
09/29/20 6.2 0.62 18.4 37.2 <0.13 12.3 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 2.9 4.6 8.6 30.3 <0.13 3.9 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 33.1 1.2 39.6 43.5 2 40.9 5.3 9.3 54.0 E 5.4 NR NR NR NR NR NR NR NR NR NR
06/09/22 17.3 13.7 39.9 74.0 1.71 46.4 9.14 19.7 122 15.1 NR NR NR NR NR NR NR NR NR NR
10/05/22 17.0 15.4 27.4 84.9 <1.40 247 6.12 10.3 40.7 8.46 NR NR NR NR NR NR NR NR NR NR
04/04/23 1.8 1.8 1.9 5.1 0.43 J 3.1 0.52 0.81 2.8 0.64 NR NR NR NR NR NR NR NR NR NR
07/01/19 329 5,400 1,290 6,070 <25 262 42.5 J 109 978 259 NR NR NR NR NR NR NR NR NR NR
11/11/19 174 2,430 671 3,390 <6.3 180 30.2 70.1 626 168 NR NR NR NR NR NR NR NR NR NR
05/06/20 326 4,810 1,140 6,010 <13 226 36.7 J 98.5 1,000 257 NR NR NR NR NR NR NR NR NR NR
09/29/20 222 2,490 1,040 5,090 <6.3 264 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 216 3,010 880 4,800 <13 232 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
07/07/21 257 3,460 1,120 5,560 <13 238 38.1 J 105 978 239 NR NR NR NR NR NR NR NR NR NR
01/05/22 125 1,480 523 2,670 <3.1 166 23.4 56.4 535 136 NR NR NR NR NR NR NR NR NR NR
06/09/22 89.4 851 673 2,700 <1.40 266 58.9 152 994 301 NR NR NR NR NR NR NR NR NR NR
10/05/22 144 158.42 E 823 356.68 E <0.140 195 39.6 97.0 753 187 NR NR NR NR NR NR NR NR NR NR
04/04/23 215 2,940 1,180 6,730 <6.3 298 42.1 70.9 1,230 303 NR NR NR NR NR NR NR NR NR NR
07/01/19 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
11/11/19 1,120 11,800 3,080 17,800 318 918 124 J 343 3,390 936 NR NR NR NR NR NR NR NR NR NR
05/06/20 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
09/29/20 1,070 12,900 2,440 16,500 <63 5,160 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 514 9,070 2,280 13,400 <31 721 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
07/07/21 571 11,700 2,910 16,400 <130 2,830 <130 311 J 4,550 1,140 NR NR NR NR NR NR NR NR NR NR
01/05/22 85.4 2,930 928 7,900 <6.3 517 35.7 103 1,600 570 NR NR NR NR NR NR NR NR NR NR
06/09/22 488 8,110 2,250 15,500 95.0 J 1,380 88.4 172 4,750 1,830 NR NR NR NR NR NR NR NR NR NR
10/05/22 544 8,230 998 11,400 117 1,050 29.6 J 62.9 2,360 843 NR NR NR NR NR NR NR NR NR NR
04/04/23 749 10,200 2,510 13,500 176 639 55.2 113 1,760 438 NR NR NR NR NR NR NR NR NR NR
07/01/19 <0.13 <0.13 <0.13 <0.25 0.18 J <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
11/11/19 <0.13 0.40 J <0.13 0.34 J 0.16 J <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
05/06/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
09/29/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 <0.13 0.29 J <0.13 0.49 J <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 <0.13 <0.13 <0.13 <0.25 0.14 J <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
06/09/22 4.66 78.0 35.9 273 0.407 J 25.4 5.35 18.7 177 63.5 NR NR NR NR NR NR NR NR NR NR
10/05/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
GMW-6
MW-2
GMW-7
GMW-8
MW-4
MW-3
Page 2 of 3
Date: 04/28/2023
EPA
Method
504.1
EPA
Method
625
SW846
6010D
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 70 70 400 400 40 0.02 30 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 30,500 26,100 28,500 24,100 40,000 50 12,000 15,000 NE NE NE NE NE NE
510 110 NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE
Contaminant of Concern

MAC (µg/l)
10 x 2B SW (µg/l)
GCL (µg/l)C11-C22 AromaticsC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsC9-C18 AliphaticsC19-C36 AliphaticsLeadSM 6200B and/or SM 602
BenzeneIsopropylbenzenen-PropylbenzeneTolueneEthylbenzeneXylenes2-MethylnaphthaleneMTBEtert-Amyl alcohol(TAA)Naphthalene1,3,5-TrimethylbenzeneEDB1,2,4-TrimethylbenzeneTABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Analytical Method MADEP Method VPH MADEP Method EPH
Facility ID #: 0-021055
07/01/19 15.7 0.41 J 2 3.8 <0.13 1.9 0.7 <0.13 0.51 <0.13 NR NR NR NR NR NR NR NR NR NR
11/11/19 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
05/06/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
09/29/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 15 0.62 4.7 12.7 <0.13 3.4 0.91 0.40 J 1.2 0.27 J NR NR NR NR NR NR NR NR NR NR
06/09/22 6.40 186 72.3 534 <1.40 74.4 4.05 J 12.6 215 71.3 NR NR NR NR NR NR NR NR NR NR
10/05/22 0.777 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
04/04/23 <0.13 1.7 0.86 4.7 <0.13 1.9 <0.13 0.18 J 2.2 0.54 NR NR NR NR NR NR NR NR NR NR
05/06/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
09/29/20 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/25/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR NR NR NR NR
01/05/22 <0.13 <0.13 <0.13 <0.25 <0.13 0.24 J <0.13 <0.13 0.21 J <0.13 NR NR NR NR NR NR NR NR NR NR
06/09/22 0.561 9.49 1.93 17 <0.140 0.983 J <0.180 0.281 J 3.36 0.877 NR NR NR NR NR NR NR NR NR NR
10/05/22 <0.180 0.709 <0.170 0.789 J <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
01/05/22 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
06/09/22 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
10/05/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.180 <0.190 <0.190 <0.180 NR NR NR NR NR NR NR NR NR NR
04/04/23 <0.13 11 <0.13 <0.25 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• < : Less than the method detection limit specified in the laboratory report.
• MAC: Maximum Allowable Concentration specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• 10 x 2B Standards: Ten times the 2B North Carolina Surface Water Standards for Class C waters (Little Raft Swamp) specified in T15A NCAC 2B.0200 or EPA National Criteria due to a spring-fed wetland within a 500-foot radius of the
site.
• J: Estimated value.
• E: Value exceeds calibration range.
• NE: Not Established.
• NR: Not Requested.
• FP: Free Product.
• NA: Not Applicable.
• Concentrations of n-butylbenzene (168 µg/l in GMW-5), p-isopropyltoluene (51.0 µg/l in GMW-5) and vinyl chloride (0.289 J µg/l in TW-1) that exceeded the MACs were reported in the ground water sample collected on 10/05/22.
• Concentrations in bold face type exceeded the 2L standards.
• Concentrations in italics exceeded the gross contamination levels.
• Underlined concentrations exceeded the 2B surface water standards by a factor of 10.
• Refer to laboratory report for detected constituents that did not exceed the MACs, or for which no standard has been established.
TW-1
Trip Blank
MW-5
Page 3 of 3
Well No.Sampled Date
(mm/dd/yy)
DO
(mg/L)Temp (oC)pH ORP
(mv)
Methane
(μg/L)
Nitrate
(μg/L)
Sulfate
(μg/L)
Ferrous Iron
(μg/L)
GMW-1 04/04/23 1.61 19.77 6.11 18.10 67.20 4,600 3,700 <100
01/05/22 1.38 19.10 5.30 156.9 13.2 <100 <2,000 3,700
06/09/22 2.78 20.02 6.49 143.2 <2.51 <76.0 18,800 2,510
10/05/22 1.69 NS NS 50.4 25.8 <76 1,120 J 1,860
04/04/23 0.93 18.38 5.55 77.6 16.0 <100 36,600 22,800
01/05/22 NS NS NS NS 0.18 J 5,100 9,800 <100
06/09/22 2.36 21.64 5.87 139.2 <2.51 3,850 20,900 2,150
10/05/22 3.97 24.67 5.95 170.8 21.0 2,410 21,900 1,890
04/04/23 1.86 18.74 5.41 116.7 4.9 3,100 7,600 4,300
06/09/22 1.49 21.39 5.94 158.6 <2.51 <76.0 3,790 6,600
10/05/22 5.18 23.48 7.05 58.4 <2.51 <76 3,240 7,270
01/05/22 1.30 NS NS 130.3 16.2 <100 <2,000 120
06/09/22 2.47 21.71 5.47 177.2 <2.51 2,490 1,560 J <50.0
10/05/22 NS NS NS NS <2.51 <0.333 8.02 70.0 J
01/05/22 NS NS NS NS 148 <100 <2,000 4,800
06/09/22 1.83 21.05 5.50 171.9 76.8 <76.0 <650 10,700
10/05/22 NS NS NS NS 84.9 <76 793 J 2,800
04/04/23 0.96 19.35 5.30 113.4 87.5 <100 <2,000 5,700
01/05/22 NS NS NS NS 4.4 <100 <2,000 <100
06/09/22 1.02 21.43 5.26 166.4 <2.51 261 5,180 12,200
10/05/22 NS NS NS NS 19.8 <76 12,300 910
04/04/23 1.18 19.26 5.60 68.6 7.1 <100 24,100 13,700
01/05/22 2.46 NS NS 118.9 4.0 440 <2,000 5,200
06/09/22 1.31 21.26 5.85 170.2 <2.51 <76.0 <650 9,670
10/05/22 2.39 NS NS 21.3 <2.51 <76 1,640 J 2,840
04/04/23 1.20 19.85 5.81 48.1 10.3 <100 <2,000 10,400
TABLE 6A
SUMMARY OF NATURAL ATTENUATION PARAMETER RESULTS
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Date: 04/28/2023 Facility ID # : 0-021055
GMW-8
MW-2
GMW-6
GMW-3
GMW-4
GMW-5
GMW-7
Well No.Sampled Date
(mm/dd/yy)
DO
(mg/L)Temp (oC)pH ORP
(mv)
Methane
(μg/L)
Nitrate
(μg/L)
Sulfate
(μg/L)
Ferrous Iron
(μg/L)
TABLE 6A
SUMMARY OF NATURAL ATTENUATION PARAMETER RESULTS
JOHN'S CITGO SERVICE (INCIDENT NO. 5189)
Date: 04/28/2023 Facility ID # : 0-021055
01/05/22 2.18 NS NS 65.0 114 <100 2,300 3,700
06/09/22 0.89 21.86 5.78 178.2 133 <76.0 1,510 J 14,400
10/05/22 NS NS NS NS 339 <76 4,270 6,300
04/04/23 0.91 20.07 5.77 59.4 305 <100 <2,000 15,500
MW-4 01/05/22 NS NS NS NS NS NS NS NS
01/05/22 5.94 22.13 4.45 171.9 0.30 J 1,900 3,000 940
06/09/22 2.31 22.17 5.01 191.4 <2.51 2,760 3,800 <50.0
10/05/22 NS NS NS NS <2.51 2,630 7,960 480
04/04/23 1.46 20.21 5.54 128.2 <0.16 2,500 2,000 <100
Notes:
• NS: Not sampled; Low sample volume prohibited parameters being collected.
• NR: Not requested.
• FP: Free Product.
• Analyses for nitrate and sulfate by Method SW846/9056; analyses for methane by Method RSK 175; analyses for ferrous iron by EPA Method SM
3500 Fe-D. Field measurements of dissolved oxygen, temperature, pH and ORP were collected during sampling using a field meter.
• <: Less than the method detection limit specified in the laboratory report.
• J: Estimated concentration.
MW-5
MW-3

APPENDICES

APPENDIX A
State Correspondence

November 15, 2022

Mr. John P. Robertson, III
John’s Texaco Service, Inc. 211A North Main Street
Red Springs, NC 28377

Re: Notice of Regulatory Requirements 15A NCAC 2L .0407(d)
Risk-based Assessment and Corrective Action
for Petroleum Underground Storage Tanks
John’s Citgo Service
211 North Main Street Red Springs, Robeson County
Incident Number: 5189
Risk Classification: Intermediate Ranking: I-170-D

Dear Mr. Robertson:
The Monitoring Report dated October 27, 2022, has been reviewed and you are requested to proceed
with your consultant’s recommendations as stated in the report conclusions. The next sampling event should
be scheduled to occur during April 2023 using a reduced number of monitoring wells. Perhaps by that time the
static water levels will have increased sufficiently enough to schedule a Fate & Transport Model.

If you have questions regarding the information contained in this letter, please contact me at the
Fayetteville Regional Office address below or at [phone].

Sincerely,

Kenneth E. Currie, Hydrogeologist
Fayetteville Regional Office
UST Section, Division of Waste Management

c: Mr. William L. Regenthal, L.G., Geological Resources, Inc. (email copy)
FRO Digital Incident File #5189

5008 Received NOV 16 2022
5008 Received FEB 16 2023

APPENDIX B
Laboratory Report – Ground Water Samples
05/08/23
Technical Report for
GRI (Geological Resources Inc.)
John's Citgo Service; 211 N Main St, Red Springs, NC
5008
SGS Job Number: FC3950
Sampling Date: 04/04/23
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 05/08/23
Reissue #1
e-Hardcopy 2.0
Automated Report
77
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 77
FC3950
Florida ♦ 4405 Vineland Road ♦ Suite C-15 ♦ Orlando, FL 32811 ♦ tel: [phone] ♦ fax: [phone]
May 8, 2023 Mr. William Regenthal GRI 3502 Hayes Rd Monroe, NC 28110 RE: SGS North America Inc. - Orlando job FC3950 Reissue Dear Mr. Regenthal, The final report for job number FC3950 has been edited to reflect requested corrections. These edits have been incorporated into the revised report.
Sample ID has been revised.
SGS North America Inc. - Orlando apologies for any inconvenience this may have caused. Please feel free to contact us if we can be of further assistance.
Sincerely,

SGS North America Inc. - Orlando

2 of 77
FC3950
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................4
Section 2: Summary of Hits ....................................................................................................5
Section 3: Sample Results ........................................................................................................9
3.1: FC3950-1: TRIP BLANK .............................................................................................10
3.2: FC3950-2: GMW-1 .......................................................................................................12
3.3: FC3950-3: MW-2 ..........................................................................................................16
3.4: FC3950-4: MW-3 ..........................................................................................................21
3.5: FC3950-5: GMW-7 .......................................................................................................25
3.6: FC3950-6: GMW-3 .......................................................................................................29
3.7: FC3950-7: GMW-4 .......................................................................................................33
3.8: FC3950-8: MW-5 ..........................................................................................................37
3.9: FC3950-9: GMW-8 .......................................................................................................41
Section 4: Misc. Forms ............................................................................................................45
4.1: Chain of Custody ...........................................................................................................46
Section 5: MS Volatiles - QC Data Summaries .....................................................................49
5.1: Method Blank Summary ................................................................................................50
5.2: Blank Spike Summary ...................................................................................................56
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................62
Section 6: GC Volatiles - QC Data Summaries .....................................................................68
6.1: Method Blank Summary ................................................................................................69
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................70
6.3: Matrix Spike Summary ..................................................................................................71
6.4: Duplicate Summary .......................................................................................................72
Section 7: General Chemistry - QC Data Summaries ..........................................................73
7.1: Method Blank and Spike Results Summary ..................................................................74
7.2: Duplicate Results Summary ..........................................................................................75
7.3: Matrix Spike Results Summary .....................................................................................76
7.4: Matrix Spike Duplicate Results Summary ....................................................................77 12345673 of 77
FC3950
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FC3950
John's Citgo Service; 211 N Main St, Red Springs, NC
Project No: 5008
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FC3950-1 04/04/23 11:17 JB 04/05/23 AQ Trip Blank Water TRIP BLANK
FC3950-2 04/04/23 12:16 JB 04/05/23 AQ Ground Water GMW-1
FC3950-3 04/04/23 12:42 JB 04/05/23 AQ Ground Water MW-2
FC3950-4 04/04/23 13:05 JB 04/05/23 AQ Ground Water MW-3
FC3950-5 04/04/23 13:27 JB 04/05/23 AQ Ground Water GMW-7
FC3950-6 04/04/23 13:49 JB 04/05/23 AQ Ground Water GMW-3
FC3950-7 04/04/23 14:07 JB 04/05/23 AQ Ground Water GMW-4
FC3950-8 04/04/23 14:16 JB 04/05/23 AQ Ground Water MW-5
FC3950-9 04/04/23 14:43 JB 04/05/23 AQ Ground Water GMW-8
4 of 77
FC39501
Summary of Hits Page 1 of 4
Job Number:FC3950
Account:GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Collected:04/04/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC3950-1 TRIP BLANK
Toluene 11.0 0.50 0.13 ug/l SM 6200B
FC3950-2 GMW-1
Benzene 2.3 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 0.16 J 0.50 0.13 ug/l SM 6200B
Chloroform 1.8 0.50 0.13 ug/l SM 6200B
o-Chlorotoluene 0.46 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 3.6 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 0.30 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 0.67 0.50 0.13 ug/l SM 6200B
Naphthalene 4.2 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 0.61 0.50 0.13 ug/l SM 6200B
Toluene 17.9 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 11.5 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 3.7 0.50 0.13 ug/l SM 6200B
m,p-Xylene 23.2 1.0 0.13 ug/l SM 6200B
o-Xylene 14.1 0.50 0.13 ug/l SM 6200B
Xylene (total)37.3 1.5 0.25 ug/l SM 6200B
Methane 67.2 0.50 0.16 ug/l RSKSOP-147/175
Nitrogen, Nitrate 4.6 0.10 mg/l EPA 300/SW846 9056A
Sulfate 3.7 2.0 mg/l EPA 300/SW846 9056A
FC3950-3 MW-2
Benzene 215 25 6.3 ug/l SM 6200B
n-Butylbenzene 13.1 J 25 6.3 ug/l SM 6200B
sec-Butylbenzene 10.9 J 25 6.3 ug/l SM 6200B
Ethylbenzene 1180 25 6.3 ug/l SM 6200B
Isopropylbenzene 42.1 25 6.3 ug/l SM 6200B
p-Isopropyltoluene 10.8 J 25 6.3 ug/l SM 6200B
Naphthalene 298 25 6.3 ug/l SM 6200B
n-Propylbenzene 70.9 50 13 ug/l SM 6200B
Styrene 6.7 J 25 6.3 ug/l SM 6200B
Toluene 2940 50 13 ug/l SM 6200B
1,2,3-Trichlorobenzene a 9.2 J 25 6.3 ug/l SM 6200B
1,2,4-Trichlorobenzene a 8.5 J 25 6.3 ug/l SM 6200B
1,2,4-Trimethylbenzene 1230 25 6.3 ug/l SM 6200B
1,3,5-Trimethylbenzene 303 25 6.3 ug/l SM 6200B
m,p-Xylene 4910 50 6.3 ug/l SM 6200B
o-Xylene 1820 25 6.3 ug/l SM 6200B
Xylene (total)6730 75 13 ug/l SM 6200B
Methane 10.3 0.50 0.16 ug/l RSKSOP-147/175
5 of 77
FC39502
Summary of Hits Page 2 of 4
Job Number:FC3950
Account:GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Collected:04/04/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
Iron, Ferrous b 10.4 2.5 mg/l SM3500FE B-11
FC3950-4 MW-3
Benzene 749 50 13 ug/l SM 6200B
n-Butylbenzene 15.8 J 50 13 ug/l SM 6200B
sec-Butylbenzene 16.5 J 50 13 ug/l SM 6200B
Ethylbenzene 2510 50 13 ug/l SM 6200B
Isopropylbenzene 55.2 50 13 ug/l SM 6200B
p-Isopropyltoluene 14.5 J 50 13 ug/l SM 6200B
Methyl Tert Butyl Ether 176 50 13 ug/l SM 6200B
Naphthalene 639 50 13 ug/l SM 6200B
n-Propylbenzene 113 50 13 ug/l SM 6200B
Styrene 22.4 J 50 13 ug/l SM 6200B
Toluene 10200 130 31 ug/l SM 6200B
1,2,3-Trichlorobenzene 16.0 J 50 13 ug/l SM 6200B
1,2,4-Trichlorobenzene 15.4 J 50 13 ug/l SM 6200B
1,2,4-Trimethylbenzene 1760 50 13 ug/l SM 6200B
1,3,5-Trimethylbenzene 438 50 13 ug/l SM 6200B
m,p-Xylene 9790 100 13 ug/l SM 6200B
o-Xylene 3710 50 13 ug/l SM 6200B
Xylene (total)13500 150 25 ug/l SM 6200B
Methane 305 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous b 15.5 2.5 mg/l SM3500FE B-11
FC3950-5 GMW-7
Benzene 405 50 13 ug/l SM 6200B
n-Butylbenzene 15.3 J 50 13 ug/l SM 6200B
Ethylbenzene 1310 50 13 ug/l SM 6200B
Isopropylbenzene 54.3 50 13 ug/l SM 6200B
Methyl Tert Butyl Ether 290 50 13 ug/l SM 6200B
Naphthalene 306 50 13 ug/l SM 6200B
n-Propylbenzene 143 50 13 ug/l SM 6200B
Toluene 3590 50 13 ug/l SM 6200B
1,2,4-Trimethylbenzene 1570 50 13 ug/l SM 6200B
1,3,5-Trimethylbenzene 403 50 13 ug/l SM 6200B
m,p-Xylene 5670 100 13 ug/l SM 6200B
o-Xylene 2080 50 13 ug/l SM 6200B
Xylene (total)7760 150 25 ug/l SM 6200B
Methane 87.5 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous b 5.7 2.5 mg/l SM3500FE B-11
6 of 77
FC39502
Summary of Hits Page 3 of 4
Job Number:FC3950
Account:GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Collected:04/04/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC3950-6 GMW-3
Benzene 2.9 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 1.1 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 0.99 0.50 0.13 ug/l SM 6200B
o-Chlorotoluene 1.5 0.50 0.13 ug/l SM 6200B
Ethylbenzene 13.9 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 1.7 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.47 J 0.50 0.13 ug/l SM 6200B
Naphthalene 11.8 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 6.1 0.50 0.13 ug/l SM 6200B
Toluene 17.4 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 41.2 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 12.5 0.50 0.13 ug/l SM 6200B
m,p-Xylene 54.6 1.0 0.13 ug/l SM 6200B
o-Xylene 19.1 0.50 0.13 ug/l SM 6200B
Xylene (total)73.8 1.5 0.25 ug/l SM 6200B
Methane 16.0 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous b 22.8 2.5 mg/l SM3500FE B-11
Sulfate 36.6 2.0 mg/l EPA 300/SW846 9056A
FC3950-7 GMW-4
Benzene 18.3 2.5 0.63 ug/l SM 6200B
n-Butylbenzene 1.9 J 2.5 0.63 ug/l SM 6200B
sec-Butylbenzene 1.5 J 2.5 0.63 ug/l SM 6200B
Chloroform 3.1 2.5 0.63 ug/l SM 6200B
Ethylbenzene 64.4 2.5 0.63 ug/l SM 6200B
Isopropylbenzene 7.2 2.5 0.63 ug/l SM 6200B
Methyl Tert Butyl Ether 0.91 J 2.5 0.63 ug/l SM 6200B
Naphthalene 25.6 2.5 0.63 ug/l SM 6200B
n-Propylbenzene 19.8 2.5 0.63 ug/l SM 6200B
Toluene 31.2 2.5 0.63 ug/l SM 6200B
1,2,4-Trimethylbenzene 117 2.5 0.63 ug/l SM 6200B
1,3,5-Trimethylbenzene 23.3 2.5 0.63 ug/l SM 6200B
m,p-Xylene 153 5.0 0.63 ug/l SM 6200B
o-Xylene 83.6 2.5 0.63 ug/l SM 6200B
Xylene (total)236 7.5 1.3 ug/l SM 6200B
Methane 4.9 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous b 4.3 1.0 mg/l SM3500FE B-11
Nitrogen, Nitrate 3.1 0.10 mg/l EPA 300/SW846 9056A
Sulfate 7.6 2.0 mg/l EPA 300/SW846 9056A
7 of 77
FC39502
Summary of Hits Page 4 of 4
Job Number:FC3950
Account:GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Collected:04/04/23
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FC3950-8 MW-5
Ethylbenzene 0.86 0.50 0.13 ug/l SM 6200B
Naphthalene 1.9 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 0.18 J 0.50 0.13 ug/l SM 6200B
Toluene 1.7 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 2.2 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.54 0.50 0.13 ug/l SM 6200B
m,p-Xylene 3.4 1.0 0.13 ug/l SM 6200B
o-Xylene 1.3 0.50 0.13 ug/l SM 6200B
Xylene (total)4.7 1.5 0.25 ug/l SM 6200B
Nitrogen, Nitrate 2.5 0.10 mg/l EPA 300/SW846 9056A
Sulfate 2.0 2.0 mg/l EPA 300/SW846 9056A
FC3950-9 GMW-8
Benzene 1.8 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 0.14 J 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 0.15 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 1.9 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 0.52 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 0.43 J 0.50 0.13 ug/l SM 6200B
Naphthalene 3.1 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 0.81 0.50 0.13 ug/l SM 6200B
Toluene 1.8 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 2.8 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.64 0.50 0.13 ug/l SM 6200B
m,p-Xylene 3.6 1.0 0.13 ug/l SM 6200B
o-Xylene 1.5 0.50 0.13 ug/l SM 6200B
Xylene (total)5.1 1.5 0.25 ug/l SM 6200B
Methane 7.1 0.50 0.16 ug/l RSKSOP-147/175
Iron, Ferrous b 13.7 2.5 mg/l SM3500FE B-11
Sulfate 24.1 2.0 mg/l EPA 300/SW846 9056A
(a) Associated CCV outside of control limits high.
(b) Field analysis required. Received out of hold time and analyzed by request.
8 of 77
FC39502
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
9 of 77
FC39503
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FC3950-1 Date Sampled:04/04/23
Matrix:AQ - Trip Blank Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A577.D 1 04/07/23 15:04 TD n/a n/a V3A27
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene a ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 77
FC395033.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:TRIP BLANK
Lab Sample ID:FC3950-1 Date Sampled:04/04/23
Matrix:AQ - Trip Blank Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide b ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene a ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 11.0 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene a ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene a ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane a ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 77
FC395033.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:GMW-1
Lab Sample ID:FC3950-2 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A602.D 1 04/10/23 15:47 TD n/a n/a V3A28
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2.3 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 0.16 0.50 0.13 ug/l J
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform 1.8 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene 0.46 0.50 0.13 ug/l J
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 77
FC395033.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:GMW-1
Lab Sample ID:FC3950-2 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 3.6 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 0.30 0.50 0.13 ug/l J
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.67 0.50 0.13 ug/l
91-20-3 Naphthalene 4.2 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 0.61 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 17.9 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 11.5 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 3.7 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 23.2 1.0 0.13 ug/l
95-47-6 o-Xylene 14.1 0.50 0.13 ug/l
1330-20-7 Xylene (total)37.3 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 105%70-130%
17060-07-0 1,2-Dichloroethane-D4 106%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 77
FC395033.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FC3950-2 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81752.D 1 04/06/23 12:14 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 67.2 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 77
FC395033.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-1
Lab Sample ID:FC3950-2 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a <0.10 0.10 mg/l 1 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate 4.6 0.10 mg/l 1 04/05/23 15:33 GT EPA 300/SW846 9056A
Sulfate 3.7 2.0 mg/l 1 04/05/23 15:33 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
15 of 77
FC395033.2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:MW-2
Lab Sample ID:FC3950-3 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A581.D 50 04/07/23 16:38 TD n/a n/a V3A27
Run #2 3A617.D 100 04/11/23 12:26 TD n/a n/a V3A29
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 215 25 6.3 ug/l
108-86-1 Bromobenzene ND 25 6.3 ug/l
74-97-5 Bromochloromethane ND 25 6.3 ug/l
75-27-4 Bromodichloromethane ND 25 6.3 ug/l
75-25-2 Bromoform ND 25 6.3 ug/l
104-51-8 n-Butylbenzene 13.1 25 6.3 ug/l J
135-98-8 sec-Butylbenzene 10.9 25 6.3 ug/l J
98-06-6 tert-Butylbenzene ND 25 6.3 ug/l
56-23-5 Carbon Tetrachloride ND 25 6.3 ug/l
108-90-7 Chlorobenzene ND 25 6.3 ug/l
75-00-3 Chloroethane ND 25 10 ug/l
67-66-3 Chloroform ND 25 6.3 ug/l
95-49-8 o-Chlorotoluene ND 25 6.3 ug/l
106-43-4 p-Chlorotoluene a ND 25 6.3 ug/l
124-48-1 Dibromochloromethane ND 25 6.3 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 25 12 ug/l
106-93-4 1,2-Dibromoethane ND 25 6.3 ug/l
75-71-8 Dichlorodifluoromethane ND 25 10 ug/l
95-50-1 1,2-Dichlorobenzene ND 25 6.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 25 6.3 ug/l
106-46-7 1,4-Dichlorobenzene ND 25 6.3 ug/l
75-34-3 1,1-Dichloroethane ND 25 6.3 ug/l
107-06-2 1,2-Dichloroethane ND 25 6.3 ug/l
75-35-4 1,1-Dichloroethylene ND 25 6.3 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 25 6.3 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 25 6.3 ug/l
78-87-5 1,2-Dichloropropane ND 25 6.3 ug/l
142-28-9 1,3-Dichloropropane ND 25 6.3 ug/l
594-20-7 2,2-Dichloropropane ND 25 6.3 ug/l
563-58-6 1,1-Dichloropropene ND 25 6.3 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 25 6.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 25 6.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 77
FC395033.3
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:MW-2
Lab Sample ID:FC3950-3 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 25 6.3 ug/l
100-41-4 Ethylbenzene 1180 25 6.3 ug/l
87-68-3 Hexachlorobutadiene ND 25 6.3 ug/l
98-82-8 Isopropylbenzene 42.1 25 6.3 ug/l
99-87-6 p-Isopropyltoluene 10.8 25 6.3 ug/l J
74-83-9 Methyl Bromide b ND 25 10 ug/l
74-87-3 Methyl Chloride ND 25 10 ug/l
74-95-3 Methylene Bromide ND 25 6.3 ug/l
75-09-2 Methylene Chloride ND 100 50 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 25 6.3 ug/l
91-20-3 Naphthalene 298 25 6.3 ug/l
103-65-1 n-Propylbenzene 70.9 c 50 13 ug/l
100-42-5 Styrene 6.7 25 6.3 ug/l J
630-20-6 1,1,1,2-Tetrachloroethane ND 25 6.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 25 6.3 ug/l
127-18-4 Tetrachloroethylene ND 25 6.3 ug/l
108-88-3 Toluene 2940 c 50 13 ug/l
87-61-6 1,2,3-Trichlorobenzene d 9.2 25 6.3 ug/l J
120-82-1 1,2,4-Trichlorobenzene d 8.5 25 6.3 ug/l J
71-55-6 1,1,1-Trichloroethane ND 25 6.3 ug/l
79-00-5 1,1,2-Trichloroethane ND 25 6.3 ug/l
79-01-6 Trichloroethylene ND 25 6.3 ug/l
75-69-4 Trichlorofluoromethane ND 25 10 ug/l
96-18-4 1,2,3-Trichloropropane a ND 25 6.3 ug/l
95-63-6 1,2,4-Trimethylbenzene 1230 25 6.3 ug/l
108-67-8 1,3,5-Trimethylbenzene 303 25 6.3 ug/l
75-01-4 Vinyl Chloride ND 25 6.3 ug/l
m,p-Xylene 4910 50 6.3 ug/l
95-47-6 o-Xylene 1820 25 6.3 ug/l
1330-20-7 Xylene (total)6730 75 13 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%102%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%105%70-130%
2037-26-5 Toluene-D8 102%102%70-130%
460-00-4 4-Bromofluorobenzene 101%100%70-130%
(a) Associated CCV outside of control limits high, sample was ND.
(b) Associated BS recovery outside control limits high, sample is ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
17 of 77
FC395033.3
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:MW-2
Lab Sample ID:FC3950-3 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
(c) Result is from Run# 2
(d) Associated CCV outside of control limits high.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 77
FC395033.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-2
Lab Sample ID:FC3950-3 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81753.D 1 04/06/23 12:21 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 10.3 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 77
FC395033.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-2
Lab Sample ID:FC3950-3 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 10.4 2.5 mg/l 25 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate <0.10 0.10 mg/l 1 04/05/23 17:24 GT EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 04/05/23 17:24 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
20 of 77
FC395033.3
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-3
Lab Sample ID:FC3950-4 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A605.D 100 04/10/23 16:58 TD n/a n/a V3A28
Run #2 3A618.D 250 04/11/23 12:49 TD n/a n/a V3A29
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 749 50 13 ug/l
108-86-1 Bromobenzene ND 50 13 ug/l
74-97-5 Bromochloromethane ND 50 13 ug/l
75-27-4 Bromodichloromethane ND 50 13 ug/l
75-25-2 Bromoform ND 50 13 ug/l
104-51-8 n-Butylbenzene 15.8 50 13 ug/l J
135-98-8 sec-Butylbenzene 16.5 50 13 ug/l J
98-06-6 tert-Butylbenzene ND 50 13 ug/l
56-23-5 Carbon Tetrachloride ND 50 13 ug/l
108-90-7 Chlorobenzene ND 50 13 ug/l
75-00-3 Chloroethane ND 50 20 ug/l
67-66-3 Chloroform ND 50 13 ug/l
95-49-8 o-Chlorotoluene ND 50 13 ug/l
106-43-4 p-Chlorotoluene ND 50 13 ug/l
124-48-1 Dibromochloromethane ND 50 13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 25 ug/l
106-93-4 1,2-Dibromoethane ND 50 13 ug/l
75-71-8 Dichlorodifluoromethane ND 50 20 ug/l
95-50-1 1,2-Dichlorobenzene ND 50 13 ug/l
541-73-1 1,3-Dichlorobenzene ND 50 13 ug/l
106-46-7 1,4-Dichlorobenzene ND 50 13 ug/l
75-34-3 1,1-Dichloroethane ND 50 13 ug/l
107-06-2 1,2-Dichloroethane ND 50 13 ug/l
75-35-4 1,1-Dichloroethylene ND 50 13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 13 ug/l
78-87-5 1,2-Dichloropropane ND 50 13 ug/l
142-28-9 1,3-Dichloropropane ND 50 13 ug/l
594-20-7 2,2-Dichloropropane ND 50 13 ug/l
563-58-6 1,1-Dichloropropene ND 50 13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 77
FC395033.4
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-3
Lab Sample ID:FC3950-4 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 50 13 ug/l
100-41-4 Ethylbenzene 2510 50 13 ug/l
87-68-3 Hexachlorobutadiene ND 50 13 ug/l
98-82-8 Isopropylbenzene 55.2 50 13 ug/l
99-87-6 p-Isopropyltoluene 14.5 50 13 ug/l J
74-83-9 Methyl Bromide ND 50 20 ug/l
74-87-3 Methyl Chloride ND 50 20 ug/l
74-95-3 Methylene Bromide ND 50 13 ug/l
75-09-2 Methylene Chloride ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether 176 50 13 ug/l
91-20-3 Naphthalene 639 50 13 ug/l
103-65-1 n-Propylbenzene 113 50 13 ug/l
100-42-5 Styrene 22.4 50 13 ug/l J
630-20-6 1,1,1,2-Tetrachloroethane ND 50 13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 13 ug/l
127-18-4 Tetrachloroethylene ND 50 13 ug/l
108-88-3 Toluene 10200 a 130 31 ug/l
87-61-6 1,2,3-Trichlorobenzene 16.0 50 13 ug/l J
120-82-1 1,2,4-Trichlorobenzene 15.4 50 13 ug/l J
71-55-6 1,1,1-Trichloroethane ND 50 13 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 13 ug/l
79-01-6 Trichloroethylene ND 50 13 ug/l
75-69-4 Trichlorofluoromethane ND 50 20 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 13 ug/l
95-63-6 1,2,4-Trimethylbenzene 1760 50 13 ug/l
108-67-8 1,3,5-Trimethylbenzene 438 50 13 ug/l
75-01-4 Vinyl Chloride ND 50 13 ug/l
m,p-Xylene 9790 100 13 ug/l
95-47-6 o-Xylene 3710 50 13 ug/l
1330-20-7 Xylene (total)13500 150 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%102%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%105%70-130%
2037-26-5 Toluene-D8 101%101%70-130%
460-00-4 4-Bromofluorobenzene 101%101%70-130%
(a) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
22 of 77
FC395033.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-3
Lab Sample ID:FC3950-4 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81761.D 1 04/06/23 14:22 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 305 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 77
FC395033.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-3
Lab Sample ID:FC3950-4 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 15.5 2.5 mg/l 25 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate <0.10 0.10 mg/l 1 04/05/23 17:46 GT EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 04/05/23 17:46 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
24 of 77
FC395033.4
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:GMW-7
Lab Sample ID:FC3950-5 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A606.D 100 04/10/23 17:21 TD n/a n/a V3A28
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 405 50 13 ug/l
108-86-1 Bromobenzene ND 50 13 ug/l
74-97-5 Bromochloromethane ND 50 13 ug/l
75-27-4 Bromodichloromethane ND 50 13 ug/l
75-25-2 Bromoform ND 50 13 ug/l
104-51-8 n-Butylbenzene 15.3 50 13 ug/l J
135-98-8 sec-Butylbenzene ND 50 13 ug/l
98-06-6 tert-Butylbenzene ND 50 13 ug/l
56-23-5 Carbon Tetrachloride ND 50 13 ug/l
108-90-7 Chlorobenzene ND 50 13 ug/l
75-00-3 Chloroethane ND 50 20 ug/l
67-66-3 Chloroform ND 50 13 ug/l
95-49-8 o-Chlorotoluene ND 50 13 ug/l
106-43-4 p-Chlorotoluene ND 50 13 ug/l
124-48-1 Dibromochloromethane ND 50 13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 25 ug/l
106-93-4 1,2-Dibromoethane ND 50 13 ug/l
75-71-8 Dichlorodifluoromethane ND 50 20 ug/l
95-50-1 1,2-Dichlorobenzene ND 50 13 ug/l
541-73-1 1,3-Dichlorobenzene ND 50 13 ug/l
106-46-7 1,4-Dichlorobenzene ND 50 13 ug/l
75-34-3 1,1-Dichloroethane ND 50 13 ug/l
107-06-2 1,2-Dichloroethane ND 50 13 ug/l
75-35-4 1,1-Dichloroethylene ND 50 13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 13 ug/l
78-87-5 1,2-Dichloropropane ND 50 13 ug/l
142-28-9 1,3-Dichloropropane ND 50 13 ug/l
594-20-7 2,2-Dichloropropane ND 50 13 ug/l
563-58-6 1,1-Dichloropropene ND 50 13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 77
FC395033.5
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:GMW-7
Lab Sample ID:FC3950-5 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 50 13 ug/l
100-41-4 Ethylbenzene 1310 50 13 ug/l
87-68-3 Hexachlorobutadiene ND 50 13 ug/l
98-82-8 Isopropylbenzene 54.3 50 13 ug/l
99-87-6 p-Isopropyltoluene ND 50 13 ug/l
74-83-9 Methyl Bromide ND 50 20 ug/l
74-87-3 Methyl Chloride ND 50 20 ug/l
74-95-3 Methylene Bromide ND 50 13 ug/l
75-09-2 Methylene Chloride ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether 290 50 13 ug/l
91-20-3 Naphthalene 306 50 13 ug/l
103-65-1 n-Propylbenzene 143 50 13 ug/l
100-42-5 Styrene ND 50 13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 50 13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 13 ug/l
127-18-4 Tetrachloroethylene ND 50 13 ug/l
108-88-3 Toluene 3590 50 13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 50 13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 50 13 ug/l
71-55-6 1,1,1-Trichloroethane ND 50 13 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 13 ug/l
79-01-6 Trichloroethylene ND 50 13 ug/l
75-69-4 Trichlorofluoromethane ND 50 20 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 13 ug/l
95-63-6 1,2,4-Trimethylbenzene 1570 50 13 ug/l
108-67-8 1,3,5-Trimethylbenzene 403 50 13 ug/l
75-01-4 Vinyl Chloride ND 50 13 ug/l
m,p-Xylene 5670 100 13 ug/l
95-47-6 o-Xylene 2080 50 13 ug/l
1330-20-7 Xylene (total)7760 150 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
26 of 77
FC395033.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-7
Lab Sample ID:FC3950-5 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81762.D 1 04/06/23 14:30 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 87.5 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
27 of 77
FC395033.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-7
Lab Sample ID:FC3950-5 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 5.7 2.5 mg/l 25 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate <0.10 0.10 mg/l 1 04/05/23 18:08 GT EPA 300/SW846 9056A
Sulfate <2.0 2.0 mg/l 1 04/05/23 18:08 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
28 of 77
FC395033.5
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:GMW-3
Lab Sample ID:FC3950-6 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A621.D 1 04/11/23 14:00 TD n/a n/a V3A29
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2.9 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 1.1 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 0.99 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene 1.5 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
29 of 77
FC395033.6
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:GMW-3
Lab Sample ID:FC3950-6 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 13.9 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 1.7 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 0.47 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 11.8 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 6.1 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 17.4 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 41.2 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 12.5 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 54.6 1.0 0.13 ug/l
95-47-6 o-Xylene 19.1 0.50 0.13 ug/l
1330-20-7 Xylene (total)73.8 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 94%70-130%
17060-07-0 1,2-Dichloroethane-D4 97%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
30 of 77
FC395033.6
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-3
Lab Sample ID:FC3950-6 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81763.D 1 04/06/23 14:37 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 16.0 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
31 of 77
FC395033.6
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-3
Lab Sample ID:FC3950-6 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 22.8 2.5 mg/l 25 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate <0.10 0.10 mg/l 1 04/05/23 18:30 GT EPA 300/SW846 9056A
Sulfate 36.6 2.0 mg/l 1 04/05/23 18:30 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
32 of 77
FC395033.6
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:GMW-4
Lab Sample ID:FC3950-7 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A619.D 5 04/11/23 13:13 TD n/a n/a V3A29
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 18.3 2.5 0.63 ug/l
108-86-1 Bromobenzene ND 2.5 0.63 ug/l
74-97-5 Bromochloromethane ND 2.5 0.63 ug/l
75-27-4 Bromodichloromethane ND 2.5 0.63 ug/l
75-25-2 Bromoform ND 2.5 0.63 ug/l
104-51-8 n-Butylbenzene 1.9 2.5 0.63 ug/l J
135-98-8 sec-Butylbenzene 1.5 2.5 0.63 ug/l J
98-06-6 tert-Butylbenzene ND 2.5 0.63 ug/l
56-23-5 Carbon Tetrachloride ND 2.5 0.63 ug/l
108-90-7 Chlorobenzene ND 2.5 0.63 ug/l
75-00-3 Chloroethane ND 2.5 1.0 ug/l
67-66-3 Chloroform 3.1 2.5 0.63 ug/l
95-49-8 o-Chlorotoluene ND 2.5 0.63 ug/l
106-43-4 p-Chlorotoluene ND 2.5 0.63 ug/l
124-48-1 Dibromochloromethane ND 2.5 0.63 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.5 1.2 ug/l
106-93-4 1,2-Dibromoethane ND 2.5 0.63 ug/l
75-71-8 Dichlorodifluoromethane ND 2.5 1.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 2.5 0.63 ug/l
541-73-1 1,3-Dichlorobenzene ND 2.5 0.63 ug/l
106-46-7 1,4-Dichlorobenzene ND 2.5 0.63 ug/l
75-34-3 1,1-Dichloroethane ND 2.5 0.63 ug/l
107-06-2 1,2-Dichloroethane ND 2.5 0.63 ug/l
75-35-4 1,1-Dichloroethylene ND 2.5 0.63 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 2.5 0.63 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 2.5 0.63 ug/l
78-87-5 1,2-Dichloropropane ND 2.5 0.63 ug/l
142-28-9 1,3-Dichloropropane ND 2.5 0.63 ug/l
594-20-7 2,2-Dichloropropane ND 2.5 0.63 ug/l
563-58-6 1,1-Dichloropropene ND 2.5 0.63 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 2.5 0.63 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 2.5 0.63 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
33 of 77
FC395033.7
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:GMW-4
Lab Sample ID:FC3950-7 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 2.5 0.63 ug/l
100-41-4 Ethylbenzene 64.4 2.5 0.63 ug/l
87-68-3 Hexachlorobutadiene ND 2.5 0.63 ug/l
98-82-8 Isopropylbenzene 7.2 2.5 0.63 ug/l
99-87-6 p-Isopropyltoluene ND 2.5 0.63 ug/l
74-83-9 Methyl Bromide ND 2.5 1.0 ug/l
74-87-3 Methyl Chloride ND 2.5 1.0 ug/l
74-95-3 Methylene Bromide ND 2.5 0.63 ug/l
75-09-2 Methylene Chloride ND 10 5.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.91 2.5 0.63 ug/l J
91-20-3 Naphthalene 25.6 2.5 0.63 ug/l
103-65-1 n-Propylbenzene 19.8 2.5 0.63 ug/l
100-42-5 Styrene ND 2.5 0.63 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 2.5 0.63 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 2.5 0.63 ug/l
127-18-4 Tetrachloroethylene ND 2.5 0.63 ug/l
108-88-3 Toluene 31.2 2.5 0.63 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 2.5 0.63 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 2.5 0.63 ug/l
71-55-6 1,1,1-Trichloroethane ND 2.5 0.63 ug/l
79-00-5 1,1,2-Trichloroethane ND 2.5 0.63 ug/l
79-01-6 Trichloroethylene ND 2.5 0.63 ug/l
75-69-4 Trichlorofluoromethane ND 2.5 1.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.5 0.63 ug/l
95-63-6 1,2,4-Trimethylbenzene 117 2.5 0.63 ug/l
108-67-8 1,3,5-Trimethylbenzene 23.3 2.5 0.63 ug/l
75-01-4 Vinyl Chloride ND 2.5 0.63 ug/l
m,p-Xylene 153 5.0 0.63 ug/l
95-47-6 o-Xylene 83.6 2.5 0.63 ug/l
1330-20-7 Xylene (total)236 7.5 1.3 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 106%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
34 of 77
FC395033.7
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-4
Lab Sample ID:FC3950-7 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81764.D 1 04/06/23 14:50 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 4.9 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
35 of 77
FC395033.7
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-4
Lab Sample ID:FC3950-7 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 4.3 1.0 mg/l 10 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate 3.1 0.10 mg/l 1 04/05/23 18:52 GT EPA 300/SW846 9056A
Sulfate 7.6 2.0 mg/l 1 04/05/23 18:52 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
36 of 77
FC395033.7
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-5
Lab Sample ID:FC3950-8 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A627.D 1 04/11/23 16:22 TD n/a n/a V3A29
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
37 of 77
FC395033.8
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-5
Lab Sample ID:FC3950-8 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 0.86 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene 1.9 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 0.18 0.50 0.13 ug/l J
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1.7 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 2.2 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.54 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 3.4 1.0 0.13 ug/l
95-47-6 o-Xylene 1.3 0.50 0.13 ug/l
1330-20-7 Xylene (total)4.7 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 102%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
38 of 77
FC395033.8
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-5
Lab Sample ID:FC3950-8 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81765.D 1 04/06/23 14:57 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane ND 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
39 of 77
FC395033.8
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:MW-5
Lab Sample ID:FC3950-8 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a <0.10 0.10 mg/l 1 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate 2.5 0.10 mg/l 1 04/05/23 19:14 GT EPA 300/SW846 9056A
Sulfate 2.0 2.0 mg/l 1 04/05/23 19:14 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
40 of 77
FC395033.8
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:GMW-8
Lab Sample ID:FC3950-9 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 3A622.D 1 04/11/23 14:24 TD n/a n/a V3A29
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1.8 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 0.14 0.50 0.13 ug/l J
135-98-8 sec-Butylbenzene 0.15 0.50 0.13 ug/l J
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
41 of 77
FC395033.9
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:GMW-8
Lab Sample ID:FC3950-9 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:SM 6200B Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene 1.9 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 0.52 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.43 0.50 0.13 ug/l J
91-20-3 Naphthalene 3.1 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 0.81 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1.8 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene 2.8 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.64 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 3.6 1.0 0.13 ug/l
95-47-6 o-Xylene 1.5 0.50 0.13 ug/l
1330-20-7 Xylene (total)5.1 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
42 of 77
FC395033.9
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-8
Lab Sample ID:FC3950-9 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Method:RSKSOP-147/175 Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 LL81766.D 1 04/06/23 15:05 SS n/a n/a GLL2841
Run #2
Initial Volume Headspace Volume Volume Injected Temperature
Run #1 38.0 ml 5.0 ml 500 ul 21 Deg. C
Run #2
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane 7.1 0.50 0.16 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
43 of 77
FC395033.9
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:GMW-8
Lab Sample ID:FC3950-9 Date Sampled:04/04/23
Matrix:AQ - Ground Water Date Received:04/05/23
Percent Solids:n/a
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
General Chemistry
Analyte Result RL Units DF Analyzed By Method
Iron, Ferrous a 13.7 2.5 mg/l 25 04/07/23 10:30 ST SM3500FE B-11
Nitrogen, Nitrate <0.10 0.10 mg/l 1 04/05/23 19:36 GT EPA 300/SW846 9056A
Sulfate 24.1 2.0 mg/l 1 04/05/23 19:36 GT EPA 300/SW846 9056A
(a) Field analysis required. Received out of hold time and analyzed by request.
RL = Reporting Limit
44 of 77
FC395033.9
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
45 of 77
FC39504
FC3950: Chain of Custody
Page 1 of 3
46 of 77
FC395044.1
Job Number:FC3950 Client:GRI
Date / Time Received:4/5/2023 9:30:00 AM Delivery Method:FX
Project:JOHN'S CITGO SERVICE
Airbill #'s:570790508230
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (4.4);
Cooler 1: (4.3);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230320 pH 10-12 25BDH07 Other: (Specify)pH 1.0 - 12.0 222221
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.1; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:NATHANS Date:Date:4/5/2023 9:30:00 AM
FC3950: Chain of Custody
Page 2 of 3
47 of 77
FC395044.1
TAT (Days):7
Received Date:4/5/2023
Due Date:4/12/2023
Project Description:John's Citgo Service; 211 N Main St, Red Springs,
Account Name:GRI (Geological Resources Inc.)
Deliverable:COMMB
CSR:MM
Requested Date:5/8/2023
Job Change Order:FC3950
Sample #:FC3950-8
GMW-5
Change:
Per client request sample ID should be MW-5.Dept:
====================================================================================================================
====================================================================================================================
TAT:7
Above Changes Per:
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Date/Time:5/8/2023 12:37:08 PM
Page 1 of 1
William Regenthal
FC3950: Chain of Custody
Page 3 of 3
48 of 77
FC395044.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
49 of 77
FC39505
Method Blank Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A27-MB 3A566.D 1 04/07/23 TD n/a n/a V3A27
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-1, FC3950-3
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
50 of 77
FC395055.1.1
Method Blank Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A27-MB 3A566.D 1 04/07/23 TD n/a n/a V3A27
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-1, FC3950-3
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
51 of 77
FC395055.1.1
Method Blank Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A28-MB 3A590.D 1 04/10/23 TD n/a n/a V3A28
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-2, FC3950-4, FC3950-5
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
52 of 77
FC395055.1.2
Method Blank Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A28-MB 3A590.D 1 04/10/23 TD n/a n/a V3A28
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-2, FC3950-4, FC3950-5
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 106%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
53 of 77
FC395055.1.2
Method Blank Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A29-MB 3A615.D 1 04/11/23 TD n/a n/a V3A29
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-3, FC3950-4, FC3950-6, FC3950-7, FC3950-8, FC3950-9
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
54 of 77
FC395055.1.3
Method Blank Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A29-MB 3A615.D 1 04/11/23 TD n/a n/a V3A29
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-3, FC3950-4, FC3950-6, FC3950-7, FC3950-8, FC3950-9
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
55 of 77
FC395055.1.3
Blank Spike Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A27-BS 3A563.D 1 04/07/23 TD n/a n/a V3A27
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-1, FC3950-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.3 103 70-130
108-86-1 Bromobenzene 10 10.5 105 70-130
74-97-5 Bromochloromethane 10 10.0 100 70-130
75-27-4 Bromodichloromethane 10 10.6 106 70-130
75-25-2 Bromoform 10 11.0 110 70-130
104-51-8 n-Butylbenzene 10 10 100 70-130
135-98-8 sec-Butylbenzene 10 9.7 97 70-130
98-06-6 tert-Butylbenzene 10 9.7 97 70-130
56-23-5 Carbon Tetrachloride 10 10.2 102 70-130
108-90-7 Chlorobenzene 10 10.1 101 70-130
75-00-3 Chloroethane 10 12.1 121 60-140
67-66-3 Chloroform 10 10.2 102 70-130
95-49-8 o-Chlorotoluene 10 10.5 105 70-130
106-43-4 p-Chlorotoluene 10 10.4 104 70-130
124-48-1 Dibromochloromethane 10 9.4 94 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.5 85 70-130
106-93-4 1,2-Dibromoethane 10 9.1 91 70-130
75-71-8 Dichlorodifluoromethane 10 12.4 124 60-140
95-50-1 1,2-Dichlorobenzene 10 10.3 103 70-130
541-73-1 1,3-Dichlorobenzene 10 10.3 103 70-130
106-46-7 1,4-Dichlorobenzene 10 10 100 70-130
75-34-3 1,1-Dichloroethane 10 9.8 98 70-130
107-06-2 1,2-Dichloroethane 10 10 100 70-130
75-35-4 1,1-Dichloroethylene 10 10.2 102 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.9 99 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.2 102 70-130
78-87-5 1,2-Dichloropropane 10 10.6 106 70-130
142-28-9 1,3-Dichloropropane 10 10.6 106 70-130
594-20-7 2,2-Dichloropropane 10 11.1 111 70-130
563-58-6 1,1-Dichloropropene 10 10.9 109 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.8 98 70-130
10061-02-6 trans-1,3-Dichloropropene 10 8.7 87 70-130
108-20-3 Di-Isopropyl Ether 10 9.4 94 70-130
100-41-4 Ethylbenzene 10 10.3 103 70-130
87-68-3 Hexachlorobutadiene 10 11.2 112 70-130
98-82-8 Isopropylbenzene 10 9.6 96 70-130
* = Outside of Control Limits.
56 of 77
FC395055.2.1
Blank Spike Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A27-BS 3A563.D 1 04/07/23 TD n/a n/a V3A27
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-1, FC3950-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.5 95 70-130
74-83-9 Methyl Bromide 10 15.6 156*60-140
74-87-3 Methyl Chloride 10 11.3 113 60-140
74-95-3 Methylene Bromide 10 10.1 101 70-130
75-09-2 Methylene Chloride 10 8.7 87 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.6 106 70-130
91-20-3 Naphthalene 10 8.6 86 70-130
103-65-1 n-Propylbenzene 10 10.7 107 70-130
100-42-5 Styrene 10 9.0 90 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.2 92 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.0 90 70-130
127-18-4 Tetrachloroethylene 10 10.3 103 70-130
108-88-3 Toluene 10 10.2 102 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.5 105 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.7 107 70-130
71-55-6 1,1,1-Trichloroethane 10 10.5 105 70-130
79-00-5 1,1,2-Trichloroethane 10 10 100 70-130
79-01-6 Trichloroethylene 10 10.1 101 70-130
75-69-4 Trichlorofluoromethane 10 11.3 113 60-140
96-18-4 1,2,3-Trichloropropane 10 10.3 103 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.6 96 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.8 98 70-130
75-01-4 Vinyl Chloride 10 10.9 109 60-140
m,p-Xylene 20 21.5 108 70-130
95-47-6 o-Xylene 10 9.4 94 70-130
1330-20-7 Xylene (total)30 30.9 103 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
* = Outside of Control Limits.
57 of 77
FC395055.2.1
Blank Spike Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A28-BS 3A587.D 1 04/10/23 TD n/a n/a V3A28
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-2, FC3950-4, FC3950-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.3 103 70-130
108-86-1 Bromobenzene 10 10.5 105 70-130
74-97-5 Bromochloromethane 10 10 100 70-130
75-27-4 Bromodichloromethane 10 10.5 105 70-130
75-25-2 Bromoform 10 11.2 112 70-130
104-51-8 n-Butylbenzene 10 9.6 96 70-130
135-98-8 sec-Butylbenzene 10 9.5 95 70-130
98-06-6 tert-Butylbenzene 10 9.4 94 70-130
56-23-5 Carbon Tetrachloride 10 10 100 70-130
108-90-7 Chlorobenzene 10 10.1 101 70-130
75-00-3 Chloroethane 10 11.7 117 60-140
67-66-3 Chloroform 10 10.1 101 70-130
95-49-8 o-Chlorotoluene 10 10.3 103 70-130
106-43-4 p-Chlorotoluene 10 10.3 103 70-130
124-48-1 Dibromochloromethane 10 9.5 95 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.1 91 70-130
106-93-4 1,2-Dibromoethane 10 9.3 93 70-130
75-71-8 Dichlorodifluoromethane 10 13.0 130 60-140
95-50-1 1,2-Dichlorobenzene 10 10.2 102 70-130
541-73-1 1,3-Dichlorobenzene 10 10.2 102 70-130
106-46-7 1,4-Dichlorobenzene 10 9.9 99 70-130
75-34-3 1,1-Dichloroethane 10 9.6 96 70-130
107-06-2 1,2-Dichloroethane 10 10.0 100 70-130
75-35-4 1,1-Dichloroethylene 10 10 100 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.8 98 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10 100 70-130
78-87-5 1,2-Dichloropropane 10 10.6 106 70-130
142-28-9 1,3-Dichloropropane 10 10.9 109 70-130
594-20-7 2,2-Dichloropropane 10 10.9 109 70-130
563-58-6 1,1-Dichloropropene 10 10.7 107 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.7 97 70-130
10061-02-6 trans-1,3-Dichloropropene 10 8.8 88 70-130
108-20-3 Di-Isopropyl Ether 10 9.4 94 70-130
100-41-4 Ethylbenzene 10 10.0 100 70-130
87-68-3 Hexachlorobutadiene 10 10.9 109 70-130
98-82-8 Isopropylbenzene 10 9.3 93 70-130
* = Outside of Control Limits.
58 of 77
FC395055.2.2
Blank Spike Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A28-BS 3A587.D 1 04/10/23 TD n/a n/a V3A28
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-2, FC3950-4, FC3950-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.0 90 70-130
74-83-9 Methyl Bromide 10 11.7 117 60-140
74-87-3 Methyl Chloride 10 11.6 116 60-140
74-95-3 Methylene Bromide 10 10.3 103 70-130
75-09-2 Methylene Chloride 10 8.5 85 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.8 108 70-130
91-20-3 Naphthalene 10 9.0 90 70-130
103-65-1 n-Propylbenzene 10 10.3 103 70-130
100-42-5 Styrene 10 8.9 89 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.2 92 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.1 91 70-130
127-18-4 Tetrachloroethylene 10 10.2 102 70-130
108-88-3 Toluene 10 10 100 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.8 108 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.7 107 70-130
71-55-6 1,1,1-Trichloroethane 10 10.2 102 70-130
79-00-5 1,1,2-Trichloroethane 10 10.1 101 70-130
79-01-6 Trichloroethylene 10 10.0 100 70-130
75-69-4 Trichlorofluoromethane 10 11.8 118 60-140
96-18-4 1,2,3-Trichloropropane 10 10.5 105 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.5 95 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.5 95 70-130
75-01-4 Vinyl Chloride 10 11.6 116 60-140
m,p-Xylene 20 21.2 106 70-130
95-47-6 o-Xylene 10 9.3 93 70-130
1330-20-7 Xylene (total)30 30.5 102 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
* = Outside of Control Limits.
59 of 77
FC395055.2.2
Blank Spike Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A29-BS 3A612.D 1 04/11/23 TD n/a n/a V3A29
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-3, FC3950-4, FC3950-6, FC3950-7, FC3950-8, FC3950-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.9 109 70-130
108-86-1 Bromobenzene 10 10.7 107 70-130
74-97-5 Bromochloromethane 10 10.3 103 70-130
75-27-4 Bromodichloromethane 10 11.1 111 70-130
75-25-2 Bromoform 10 11.7 117 70-130
104-51-8 n-Butylbenzene 10 10.4 104 70-130
135-98-8 sec-Butylbenzene 10 10.2 102 70-130
98-06-6 tert-Butylbenzene 10 10.1 101 70-130
56-23-5 Carbon Tetrachloride 10 10.8 108 70-130
108-90-7 Chlorobenzene 10 10.6 106 70-130
75-00-3 Chloroethane 10 11.0 110 60-140
67-66-3 Chloroform 10 10.6 106 70-130
95-49-8 o-Chlorotoluene 10 10.9 109 70-130
106-43-4 p-Chlorotoluene 10 10.9 109 70-130
124-48-1 Dibromochloromethane 10 9.9 99 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.3 93 70-130
106-93-4 1,2-Dibromoethane 10 9.7 97 70-130
75-71-8 Dichlorodifluoromethane 10 13.5 135 60-140
95-50-1 1,2-Dichlorobenzene 10 10.7 107 70-130
541-73-1 1,3-Dichlorobenzene 10 10.7 107 70-130
106-46-7 1,4-Dichlorobenzene 10 10.4 104 70-130
75-34-3 1,1-Dichloroethane 10 10.2 102 70-130
107-06-2 1,2-Dichloroethane 10 10.4 104 70-130
75-35-4 1,1-Dichloroethylene 10 10.6 106 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.3 103 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.6 106 70-130
78-87-5 1,2-Dichloropropane 10 11.1 111 70-130
142-28-9 1,3-Dichloropropane 10 11.4 114 70-130
594-20-7 2,2-Dichloropropane 10 11.7 117 70-130
563-58-6 1,1-Dichloropropene 10 11.5 115 70-130
10061-01-5 cis-1,3-Dichloropropene 10 10.2 102 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.3 93 70-130
108-20-3 Di-Isopropyl Ether 10 9.9 99 70-130
100-41-4 Ethylbenzene 10 10.7 107 70-130
87-68-3 Hexachlorobutadiene 10 11.7 117 70-130
98-82-8 Isopropylbenzene 10 9.9 99 70-130
* = Outside of Control Limits.
60 of 77
FC395055.2.3
Blank Spike Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
V3A29-BS 3A612.D 1 04/11/23 TD n/a n/a V3A29
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-3, FC3950-4, FC3950-6, FC3950-7, FC3950-8, FC3950-9
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.8 98 70-130
74-83-9 Methyl Bromide 10 13.3 133 60-140
74-87-3 Methyl Chloride 10 11.7 117 60-140
74-95-3 Methylene Bromide 10 10.6 106 70-130
75-09-2 Methylene Chloride 10 9.1 91 70-130
1634-04-4 Methyl Tert Butyl Ether 10 11.3 113 70-130
91-20-3 Naphthalene 10 9.5 95 70-130
103-65-1 n-Propylbenzene 10 11.0 110 70-130
100-42-5 Styrene 10 9.3 93 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.8 98 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.5 95 70-130
127-18-4 Tetrachloroethylene 10 10.8 108 70-130
108-88-3 Toluene 10 10.5 105 70-130
87-61-6 1,2,3-Trichlorobenzene 10 11.1 111 70-130
120-82-1 1,2,4-Trichlorobenzene 10 11.4 114 70-130
71-55-6 1,1,1-Trichloroethane 10 10.9 109 70-130
79-00-5 1,1,2-Trichloroethane 10 10.6 106 70-130
79-01-6 Trichloroethylene 10 10.7 107 70-130
75-69-4 Trichlorofluoromethane 10 11.8 118 60-140
96-18-4 1,2,3-Trichloropropane 10 11.0 110 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.1 101 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.2 102 70-130
75-01-4 Vinyl Chloride 10 11.6 116 60-140
m,p-Xylene 20 22.3 112 70-130
95-47-6 o-Xylene 10 9.8 98 70-130
1330-20-7 Xylene (total)30 32.1 107 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
* = Outside of Control Limits.
61 of 77
FC395055.2.3
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3834-7MS 3A579.D 50 04/07/23 TD n/a n/a V3A27
FC3834-7MSD 3A580.D 50 04/07/23 TD n/a n/a V3A27
FC3834-7 3A568.D 50 04/07/23 TD n/a n/a V3A27
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-1, FC3950-3
FC3834-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 1070 500 1680 122 500 1670 120 1 70-130/20
108-86-1 Bromobenzene ND 500 523 105 500 528 106 1 70-130/20
74-97-5 Bromochloromethane ND 500 491 98 500 501 100 2 70-130/20
75-27-4 Bromodichloromethane ND 500 484 97 500 500 100 3 70-130/20
75-25-2 Bromoform ND 500 456 91 500 470 94 3 70-130/20
104-51-8 n-Butylbenzene ND 500 489 98 500 497 99 2 70-130/20
135-98-8 sec-Butylbenzene ND 500 486 97 500 493 99 1 70-130/20
98-06-6 tert-Butylbenzene ND 500 477 95 500 485 97 2 70-130/20
56-23-5 Carbon Tetrachloride ND 500 478 96 500 495 99 3 70-130/20
108-90-7 Chlorobenzene ND 500 506 101 500 511 102 1 70-130/20
75-00-3 Chloroethane ND 500 447 89 500 517 103 15 60-140/20
67-66-3 Chloroform ND 500 516 103 500 516 103 0 70-130/20
95-49-8 o-Chlorotoluene ND 500 525 105 500 527 105 0 70-130/20
106-43-4 p-Chlorotoluene ND 500 521 104 500 518 104 1 70-130/20
124-48-1 Dibromochloromethane ND 500 410 82 500 426 85 4 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 500 423 85 500 425 85 0 70-130/20
106-93-4 1,2-Dibromoethane ND 500 444 89 500 454 91 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 500 553 111 500 639 128 14 60-140/20
95-50-1 1,2-Dichlorobenzene ND 500 509 102 500 513 103 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 500 504 101 500 515 103 2 70-130/20
106-46-7 1,4-Dichlorobenzene ND 500 492 98 500 504 101 2 70-130/20
75-34-3 1,1-Dichloroethane ND 500 495 99 500 501 100 1 70-130/20
107-06-2 1,2-Dichloroethane ND 500 499 100 500 507 101 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 500 530 106 500 530 106 0 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 500 498 100 500 500 100 0 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 500 524 105 500 528 106 1 70-130/20
78-87-5 1,2-Dichloropropane ND 500 529 106 500 542 108 2 70-130/20
142-28-9 1,3-Dichloropropane ND 500 536 107 500 545 109 2 70-130/20
594-20-7 2,2-Dichloropropane ND 500 560 112 500 565 113 1 70-130/20
563-58-6 1,1-Dichloropropene ND 500 562 112 500 568 114 1 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 500 470 94 500 479 96 2 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 500 416 83 500 429 86 3 70-130/20
108-20-3 Di-Isopropyl Ether 15.8 J 500 489 95 500 495 96 1 70-130/20
100-41-4 Ethylbenzene 57.4 500 579 104 500 585 106 1 70-130/20
87-68-3 Hexachlorobutadiene ND 500 528 106 500 550 110 4 70-130/20
98-82-8 Isopropylbenzene ND 500 473 95 500 479 96 1 70-130/20
* = Outside of Control Limits.
62 of 77
FC395055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3834-7MS 3A579.D 50 04/07/23 TD n/a n/a V3A27
FC3834-7MSD 3A580.D 50 04/07/23 TD n/a n/a V3A27
FC3834-7 3A568.D 50 04/07/23 TD n/a n/a V3A27
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-1, FC3950-3
FC3834-7 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 500 461 92 500 467 93 1 70-130/20
74-83-9 Methyl Bromide ND 500 305 61 500 397 79 26*60-140/20
74-87-3 Methyl Chloride ND 500 472 94 500 541 108 14 60-140/20
74-95-3 Methylene Bromide ND 500 505 101 500 504 101 0 70-130/20
75-09-2 Methylene Chloride ND 500 460 92 500 460 92 0 70-130/20
1634-04-4 Methyl Tert Butyl Ether 488 500 1090 120 500 1080 118 1 70-130/20
91-20-3 Naphthalene 6.5 J 500 437 86 500 447 88 2 70-130/20
103-65-1 n-Propylbenzene 6.5 J 500 546 108 500 548 108 0 70-130/20
100-42-5 Styrene ND 500 439 88 500 443 89 1 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 500 431 86 500 440 88 2 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 500 450 90 500 450 90 0 70-130/20
127-18-4 Tetrachloroethylene ND 500 527 105 500 533 107 1 70-130/20
108-88-3 Toluene 98.9 500 616 103 500 619 104 0 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 500 508 102 500 526 105 3 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 500 515 103 500 533 107 3 70-130/20
71-55-6 1,1,1-Trichloroethane ND 500 527 105 500 529 106 0 70-130/20
79-00-5 1,1,2-Trichloroethane ND 500 502 100 500 506 101 1 70-130/20
79-01-6 Trichloroethylene ND 500 518 104 500 522 104 1 70-130/20
75-69-4 Trichlorofluoromethane ND 500 478 96 500 553 111 15 60-140/20
96-18-4 1,2,3-Trichloropropane ND 500 531 106 500 527 105 1 70-130/20
95-63-6 1,2,4-Trimethylbenzene 32.9 500 528 99 500 539 101 2 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 500 492 98 500 497 99 1 70-130/20
75-01-4 Vinyl Chloride ND 500 467 93 500 538 108 14 60-140/20
m,p-Xylene 98.8 1000 1190 109 1000 1200 110 1 70-130/20
95-47-6 o-Xylene 18.7 J 500 486 93 500 494 95 2 70-130/20
1330-20-7 Xylene (total)117 1500 1670 104 1500 1690 105 1 70-130/20
CAS No.Surrogate Recoveries MS MSD FC3834-7 Limits
1868-53-7 Dibromofluoromethane 99%99%99%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%102%104%70-130%
2037-26-5 Toluene-D8 100%100%102%70-130%
460-00-4 4-Bromofluorobenzene 101%100%100%70-130%
* = Outside of Control Limits.
63 of 77
FC395055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5003-6MS 3A603.D 50 04/10/23 TD n/a n/a V3A28
FC5003-6MSD 3A604.D 50 04/10/23 TD n/a n/a V3A28
FC5003-6 3A598.D 50 04/10/23 TD n/a n/a V3A28
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-2, FC3950-4, FC3950-5
FC5003-6 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 28.1 500 559 106 500 549 104 2 70-130/20
108-86-1 Bromobenzene ND 500 517 103 500 510 102 1 70-130/20
74-97-5 Bromochloromethane ND 500 491 98 500 485 97 1 70-130/20
75-27-4 Bromodichloromethane ND 500 502 100 500 496 99 1 70-130/20
75-25-2 Bromoform ND 500 493 99 500 505 101 2 70-130/20
104-51-8 n-Butylbenzene ND 500 492 98 500 501 100 2 70-130/20
135-98-8 sec-Butylbenzene 6.7 J 500 486 96 500 486 96 0 70-130/20
98-06-6 tert-Butylbenzene ND 500 473 95 500 472 94 0 70-130/20
56-23-5 Carbon Tetrachloride ND 500 490 98 500 494 99 1 70-130/20
108-90-7 Chlorobenzene ND 500 505 101 500 498 100 1 70-130/20
75-00-3 Chloroethane ND 500 455 91 500 453 91 0 60-140/20
67-66-3 Chloroform ND 500 515 103 500 505 101 2 70-130/20
95-49-8 o-Chlorotoluene ND 500 519 104 500 513 103 1 70-130/20
106-43-4 p-Chlorotoluene ND 500 513 103 500 516 103 1 70-130/20
124-48-1 Dibromochloromethane ND 500 431 86 500 434 87 1 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 500 436 87 500 462 92 6 70-130/20
106-93-4 1,2-Dibromoethane ND 500 453 91 500 463 93 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 500 546 109 500 591 118 8 60-140/20
95-50-1 1,2-Dichlorobenzene ND 500 505 101 500 503 101 0 70-130/20
541-73-1 1,3-Dichlorobenzene ND 500 504 101 500 496 99 2 70-130/20
106-46-7 1,4-Dichlorobenzene ND 500 493 99 500 489 98 1 70-130/20
75-34-3 1,1-Dichloroethane ND 500 498 100 500 487 97 2 70-130/20
107-06-2 1,2-Dichloroethane ND 500 507 101 500 494 99 3 70-130/20
75-35-4 1,1-Dichloroethylene ND 500 529 106 500 519 104 2 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 500 512 102 500 499 100 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 500 521 104 500 513 103 2 70-130/20
78-87-5 1,2-Dichloropropane ND 500 540 108 500 525 105 3 70-130/20
142-28-9 1,3-Dichloropropane ND 500 541 108 500 535 107 1 70-130/20
594-20-7 2,2-Dichloropropane ND 500 553 111 500 545 109 1 70-130/20
563-58-6 1,1-Dichloropropene ND 500 564 113 500 558 112 1 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 500 484 97 500 475 95 2 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 500 428 86 500 427 85 0 70-130/20
108-20-3 Di-Isopropyl Ether 23.6 J 500 493 94 500 501 95 2 70-130/20
100-41-4 Ethylbenzene 43.7 500 552 102 500 548 101 1 70-130/20
87-68-3 Hexachlorobutadiene ND 500 528 106 500 549 110 4 70-130/20
98-82-8 Isopropylbenzene 6.5 J 500 479 95 500 479 95 0 70-130/20
* = Outside of Control Limits.
64 of 77
FC395055.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC5003-6MS 3A603.D 50 04/10/23 TD n/a n/a V3A28
FC5003-6MSD 3A604.D 50 04/10/23 TD n/a n/a V3A28
FC5003-6 3A598.D 50 04/10/23 TD n/a n/a V3A28
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-2, FC3950-4, FC3950-5
FC5003-6 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 500 452 90 500 460 92 2 70-130/20
74-83-9 Methyl Bromide ND 500 503 101 500 546 109 8 60-140/20
74-87-3 Methyl Chloride ND 500 491 98 500 538 108 9 60-140/20
74-95-3 Methylene Bromide ND 500 497 99 500 505 101 2 70-130/20
75-09-2 Methylene Chloride ND 500 470 94 500 455 91 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether 2250 500 2810 112 500 2860 122 2 70-130/20
91-20-3 Naphthalene 158 500 627 94 500 654 99 4 70-130/20
103-65-1 n-Propylbenzene 10.8 J 500 537 105 500 534 105 1 70-130/20
100-42-5 Styrene ND 500 443 89 500 440 88 1 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 500 438 88 500 442 88 1 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 500 445 89 500 460 92 3 70-130/20
127-18-4 Tetrachloroethylene ND 500 522 104 500 520 104 0 70-130/20
108-88-3 Toluene ND 500 509 102 500 504 101 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 500 522 104 500 541 108 4 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 500 540 108 500 548 110 1 70-130/20
71-55-6 1,1,1-Trichloroethane ND 500 527 105 500 520 104 1 70-130/20
79-00-5 1,1,2-Trichloroethane ND 500 516 103 500 516 103 0 70-130/20
79-01-6 Trichloroethylene ND 500 527 105 500 518 104 2 70-130/20
75-69-4 Trichlorofluoromethane ND 500 490 98 500 520 104 6 60-140/20
96-18-4 1,2,3-Trichloropropane ND 500 505 101 500 533 107 5 70-130/20
95-63-6 1,2,4-Trimethylbenzene 14.6 J 500 488 95 500 485 94 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 500 484 97 500 487 97 1 70-130/20
75-01-4 Vinyl Chloride ND 500 472 94 500 516 103 9 60-140/20
m,p-Xylene ND 1000 1090 109 1000 1070 107 2 70-130/20
95-47-6 o-Xylene ND 500 470 94 500 464 93 1 70-130/20
1330-20-7 Xylene (total)ND 1500 1560 104 1500 1530 102 2 70-130/20
CAS No.Surrogate Recoveries MS MSD FC5003-6 Limits
1868-53-7 Dibromofluoromethane 100%99%106%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%102%108%70-130%
2037-26-5 Toluene-D8 100%100%101%70-130%
460-00-4 4-Bromofluorobenzene 101%100%100%70-130%
* = Outside of Control Limits.
65 of 77
FC395055.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3950-6MS 3A628.D 2 04/11/23 TD n/a n/a V3A29
FC3950-6MSD 3A629.D 2 04/11/23 TD n/a n/a V3A29
FC3950-6 3A621.D 1 04/11/23 TD n/a n/a V3A29
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-3, FC3950-4, FC3950-6, FC3950-7, FC3950-8, FC3950-9
FC3950-6 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 2.9 20 24.4 108 20 24.3 107 0 70-130/20
108-86-1 Bromobenzene ND 20 21.5 108 20 21.5 108 0 70-130/20
74-97-5 Bromochloromethane ND 20 19.1 96 20 19.5 98 2 70-130/20
75-27-4 Bromodichloromethane ND 20 20.5 103 20 20.7 104 1 70-130/20
75-25-2 Bromoform ND 20 19.6 98 20 19.9 100 2 70-130/20
104-51-8 n-Butylbenzene 1.1 20 21.8 104 20 22.3 106 2 70-130/20
135-98-8 sec-Butylbenzene 0.99 20 21.0 100 20 21.5 103 2 70-130/20
98-06-6 tert-Butylbenzene ND 20 19.9 100 20 20.4 102 2 70-130/20
56-23-5 Carbon Tetrachloride ND 20 19.7 99 20 20.1 101 2 70-130/20
108-90-7 Chlorobenzene ND 20 21.1 106 20 21.0 105 0 70-130/20
75-00-3 Chloroethane ND 20 19.3 97 20 20.1 101 4 60-140/20
67-66-3 Chloroform ND 20 20.5 103 20 20.5 103 0 70-130/20
95-49-8 o-Chlorotoluene 1.5 20 23.0 108 20 23.3 109 1 70-130/20
106-43-4 p-Chlorotoluene ND 20 21.6 108 20 21.7 109 0 70-130/20
124-48-1 Dibromochloromethane ND 20 17.3 87 20 17.5 88 1 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 20 17.8 89 20 19.1 96 7 70-130/20
106-93-4 1,2-Dibromoethane ND 20 18.8 94 20 19.0 95 1 70-130/20
75-71-8 Dichlorodifluoromethane ND 20 23.4 117 20 25.3 127 8 60-140/20
95-50-1 1,2-Dichlorobenzene ND 20 21.1 106 20 20.9 105 1 70-130/20
541-73-1 1,3-Dichlorobenzene ND 20 20.9 105 20 21.2 106 1 70-130/20
106-46-7 1,4-Dichlorobenzene ND 20 20.5 103 20 20.7 104 1 70-130/20
75-34-3 1,1-Dichloroethane ND 20 19.6 98 20 19.4 97 1 70-130/20
107-06-2 1,2-Dichloroethane ND 20 20.0 100 20 19.7 99 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 20 21.2 106 20 21.2 106 0 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 20 20.7 104 20 20.8 104 0 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 20 20.7 104 20 21.2 106 2 70-130/20
78-87-5 1,2-Dichloropropane ND 20 22.4 112 20 22.3 112 0 70-130/20
142-28-9 1,3-Dichloropropane ND 20 22.3 112 20 22.3 112 0 70-130/20
594-20-7 2,2-Dichloropropane ND 20 21.8 109 20 22.1 111 1 70-130/20
563-58-6 1,1-Dichloropropene ND 20 23.5 118 20 23.7 119 1 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 20 18.6 93 20 18.9 95 2 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 20 17.1 86 20 17.4 87 2 70-130/20
108-20-3 Di-Isopropyl Ether ND 20 20.1 101 20 20.1 101 0 70-130/20
100-41-4 Ethylbenzene 13.9 20 36.4 113 20 35.9 110 1 70-130/20
87-68-3 Hexachlorobutadiene ND 20 22.2 111 20 23.3 117 5 70-130/20
98-82-8 Isopropylbenzene 1.7 20 21.2 98 20 21.6 100 2 70-130/20
* = Outside of Control Limits.
66 of 77
FC395055.3.3
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3950-6MS 3A628.D 2 04/11/23 TD n/a n/a V3A29
FC3950-6MSD 3A629.D 2 04/11/23 TD n/a n/a V3A29
FC3950-6 3A621.D 1 04/11/23 TD n/a n/a V3A29
The QC reported here applies to the following samples:Method: SM 6200B
FC3950-3, FC3950-4, FC3950-6, FC3950-7, FC3950-8, FC3950-9
FC3950-6 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene 0.47 J 20 19.4 95 20 20.1 98 4 70-130/20
74-83-9 Methyl Bromide ND 20 14.1 71 20 15.0 75 6 60-140/20
74-87-3 Methyl Chloride ND 20 35.9 180*20 36.3 182*1 60-140/20
74-95-3 Methylene Bromide ND 20 20.2 101 20 20.3 102 0 70-130/20
75-09-2 Methylene Chloride ND 20 18.5 93 20 18.5 93 0 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 20 21.3 107 20 21.9 110 3 70-130/20
91-20-3 Naphthalene 11.8 20 32.2 102 20 32.5 104 1 70-130/20
103-65-1 n-Propylbenzene 6.1 20 27.5 107 20 27.9 109 1 70-130/20
100-42-5 Styrene ND 20 18.6 93 20 18.8 94 1 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 20 18.5 93 20 18.5 93 0 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 20 18.5 93 20 19.3 97 4 70-130/20
127-18-4 Tetrachloroethylene ND 20 21.8 109 20 21.9 110 0 70-130/20
108-88-3 Toluene 17.4 20 41.7 122 20 40.3 115 3 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 20 21.5 108 20 22.1 111 3 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 20 22.6 113 20 23.1 116 2 70-130/20
71-55-6 1,1,1-Trichloroethane ND 20 21.2 106 20 21.4 107 1 70-130/20
79-00-5 1,1,2-Trichloroethane ND 20 28.0 140*20 28.3 142*1 70-130/20
79-01-6 Trichloroethylene ND 20 21.9 110 20 21.7 109 1 70-130/20
75-69-4 Trichlorofluoromethane ND 20 20.5 103 20 21.9 110 7 60-140/20
96-18-4 1,2,3-Trichloropropane ND 20 21.6 108 20 22.2 111 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 41.2 20 59.9 94 20 59.3 91 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 12.5 20 32.1 98 20 32.2 99 0 70-130/20
75-01-4 Vinyl Chloride ND 20 20.4 102 20 21.6 108 6 60-140/20
m,p-Xylene 54.6 40 105 126 40 102 119 3 70-130/20
95-47-6 o-Xylene 19.1 20 42.0 115 20 40.4 107 4 70-130/20
1330-20-7 Xylene (total)73.8 60 147 122 60 142 114 3 70-130/20
CAS No.Surrogate Recoveries MS MSD FC3950-6 Limits
1868-53-7 Dibromofluoromethane 96%96%94%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%99%97%70-130%
2037-26-5 Toluene-D8 101%101%103%70-130%
460-00-4 4-Bromofluorobenzene 101%102%103%70-130%
* = Outside of Control Limits.
67 of 77
FC395055.3.3
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
68 of 77
FC39506
Method Blank Summary Page 1 of 1
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLL2841-MB LL81748.D 1 04/06/23 SS n/a n/a GLL2841
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
CAS No.Compound Result RL MDL Units Q
74-82-8 Methane ND 0.50 0.16 ug/l
69 of 77
FC395066.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GLL2841-BS LL81745.D 1 04/06/23 SS n/a n/a GLL2841
GLL2841-BSD LL81746.D 1 04/06/23 SS n/a n/a GLL2841
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
74-82-8 Methane 108 136 126 132 122 3 62-139/30
* = Outside of Control Limits.
70 of 77
FC395066.2.1
Matrix Spike Summary Page 1 of 1
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3950-3MS LL81768.D 1 04/06/23 SS n/a n/a GLL2841
FC3950-3 LL81753.D 1 04/06/23 SS n/a n/a GLL2841
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
FC3950-3 Spike MS MS
CAS No.Compound ug/l Q ug/l ug/l %Limits
74-82-8 Methane 10.3 108 141 121 62-139
* = Outside of Control Limits.
71 of 77
FC395066.3.1
Duplicate Summary Page 1 of 1
Job Number:FC3950
Account:GRINCC GRI (Geological Resources Inc.)
Project:John's Citgo Service; 211 N Main St, Red Springs, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FC3950-3DUP LL81767.D 1 04/06/23 SS n/a n/a GLL2841
FC3950-3 LL81753.D 1 04/06/23 SS n/a n/a GLL2841
The QC reported here applies to the following samples:Method: RSKSOP-147/175
FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
FC3950-3 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
74-82-8 Methane 10.3 10.8 5 30
* = Outside of Control Limits.
72 of 77
FC395066.4.1
SGS North America Inc.
General Chemistry
QC Data Summaries
Includes the following where applicable:
• Method Blank and Blank Spike Summaries
• Duplicate Summaries
• Matrix Spike Summaries
Orlando, FL
Section 7
73 of 77
FC39507
METHOD BLANK AND SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC3950
Account: GRINCC - GRI (Geological Resources Inc.)
Project: John's Citgo Service; 211 N Main St, Red Springs, NC
MB Spike BSP BSP QC
Analyte Batch ID RL Result Units Amount Result %Recov Limits
Bromide GP38620/GN93881 0.50 0.0 mg/l 10 10.9 109.0 90-110%
Chloride GP38620/GN93881 2.0 0.0 mg/l 50 49.4 98.8 90-110%
Fluoride GP38620/GN93881 0.20 0.0 mg/l 2.5 2.58 103.2 90-110%
Iron, Ferrous GN93891 0.10 0.0 mg/l 0.500 0.50 99.0 82-115%
Nitrogen, Nitrate GP38620/GN93881 0.10 0.0 mg/l 2.5 2.49 99.6 90-110%
Nitrogen, Nitrite GP38620/GN93881 0.10 0.0 mg/l 2.5 2.65 106.0 90-110%
Sulfate GP38620/GN93881 2.0 0.0 mg/l 50 48.5 97.0 90-110%
Associated Samples:
Batch GN93891: FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
Batch GP38620: FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
(*) Outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
74 of 77
FC395077.1
DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC3950
Account: GRINCC - GRI (Geological Resources Inc.)
Project: John's Citgo Service; 211 N Main St, Red Springs, NC
QC Original DUP QC
Analyte Batch ID Sample Units Result Result RPD Limits
Iron, Ferrous GN93891 FC3950-2 mg/l 0.030 0.030 0.0 0-31%
Associated Samples:
Batch GN93891: FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
(*) Outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
75 of 77
FC395077.2
MATRIX SPIKE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC3950
Account: GRINCC - GRI (Geological Resources Inc.)
Project: John's Citgo Service; 211 N Main St, Red Springs, NC
QC Original Spike MS QC
Analyte Batch ID Sample Units Result Amount Result %Rec Limits
Bromide GP38620/GN93881 FC3950-2 mg/l 0.29 10 10.1 98.1 90-110%
Chloride GP38620/GN93881 FC3950-2 mg/l 20.8 50 65.1 88.6N(a) 90-110%
Fluoride GP38620/GN93881 FC3950-2 mg/l 0.0 2.5 3.1 124.0N(a) 90-110%
Nitrogen, Nitrate GP38620/GN93881 FC3950-2 mg/l 4.6 2.5 6.2 64.0N(a) 90-110%
Nitrogen, Nitrite GP38620/GN93881 FC3950-2 mg/l 0.045 2.5 2.4 94.2 90-110%
Sulfate GP38620/GN93881 FC3950-2 mg/l 3.7 50 51.0 94.6 90-110%
Associated Samples:
Batch GP38620: FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
(a) Spike recovery indicates possible matrix interference.
__________________________________________________________________________________________________________________________
Page 1
76 of 77
FC395077.3
MATRIX SPIKE DUPLICATE RESULTS SUMMARY
GENERAL CHEMISTRY
Login Number: FC3950
Account: GRINCC - GRI (Geological Resources Inc.)
Project: John's Citgo Service; 211 N Main St, Red Springs, NC
QC Original Spike MSD QC
Analyte Batch ID Sample Units Result Amount Result RPD Limit
Bromide GP38620/GN93881 FC3950-2 mg/l 0.29 10 10.2 1.0 15%
Chloride GP38620/GN93881 FC3950-2 mg/l 20.8 50 65.1 0.0 15%
Fluoride GP38620/GN93881 FC3950-2 mg/l 0.0 2.5 3.1 0.0 15%
Nitrogen, Nitrate GP38620/GN93881 FC3950-2 mg/l 4.6 2.5 6.2 0.0 15%
Nitrogen, Nitrite GP38620/GN93881 FC3950-2 mg/l 0.045 2.5 2.4 0.0 15%
Sulfate GP38620/GN93881 FC3950-2 mg/l 3.7 50 51.5 1.0 15%
Associated Samples:
Batch GP38620: FC3950-2, FC3950-3, FC3950-4, FC3950-5, FC3950-6, FC3950-7, FC3950-8, FC3950-9
(*) Outside of QC limits
(N) Matrix Spike Rec. outside of QC limits
__________________________________________________________________________________________________________________________
Page 1
77 of 77
FC395077.4

APPENDIX C
Contaminant Mass Calculations
Area ID Well ID Area
(ft²)
Average Well
Depth
(ft.)
Average
Depth to
Water
(ft.)
Water Column
Height
(ft)
Volume
(ft³)
Volume
(L)
Effective
Porosity
Effective
Volume
(L)
MW-2
MW-3
GMW-1
GMW-3
GMW-5
GMW-6
GMW-7
Area Date Well Benzene
(μ/L)
Toluene
(μ/L)
Ethylbenzene
(μ/L)
Xylenes
(μ/L)
MTBE
(μ/L)
Naphthalene
(μ/L)
Total
(μ/L)
DTW
(ft.)
Average Water
Column Height
(ft.)
Total Average Mass
(g)Percent Red.To Date Red.
MW-2 326 4810.00 1140.00 6010.00 0.00 226 12512.00 13.04
MW-3 FP FP FP FP FP FP FP 12.28
GMW-1 1920.00 15600.00 2500.00 15100.00 169 J 361.00 35481.00 11.84
GMW-3 137 1160 284 995 0.00 55 2631.00 11.60
GMW-5 0.00 130 160 793 0.00 66.3 1149.30 11.84
GMW-6 51.9 494 245 1490 0.00 66 2346.90 12.50
GMW-7 733 7680.00 2250.00 12400.00 387 368 23818.00 12.40
Avg.527.98 4979.00 1096.50 6131.33 77.40 190.38 12989.70 12.21
MW-2 222.00 2490.00 1040.00 5090.00 0.00 264.00 9106.00 13.32
MW-3 1070.00 12900.00 2440.00 16500.00 0.00 5160.00 38070.00 12.59
GMW-1 1970.00 17900.00 3510.00 19500.00 0.00 1270.00 44150.00 12.27
GMW-3 51.00 599.00 114.00 440.00 0.00 25.90 1229.90 11.90
GMW-5 0.00 129.00 137.00 637.00 0.00 66.90 969.90 12.26
GMW-6 35.00 328.00 125.00 744.00 0.00 53.90 1285.90 12.91
GMW-7 631.00 6140.00 2120.00 11700.00 379.00 393.00 21363.00 12.51
Avg.568.43 5783.71 1355.14 7801.57 54.14 1033.39 16596.39 12.54
MW-2 216.00 3010.00 880.00 4800.00 0.00 232.00 9138.00 11.69
MW-3 514.00 9070.00 2280.00 13400.00 0.00 721.00 25985.00 10.87
GMW-1 1840.00 13800.00 2340.00 13400.00 0.00 467.00 31847.00 10.55
GMW-3 80.00 921.00 212.00 860.00 0.00 50.50 2123.50 10.39
GMW-5 0.00 131.00 118.00 573.00 0.00 51.10 873.10 10.46
GMW-6 8.70 79.60 51.00 202.00 0.00 12.80 354.10 10.79
GMW-7 347.00 4080.00 1870.00 10100.00 0.00 433.00 16830.00 10.88
Avg.429.39 4441.66 1107.29 6190.71 0.00 281.06 12450.10 10.80
1 18,230.4 20.86
APPENDIX C
CONTAMINANT MASS CALCULATIONS
JOHN'S CITGO SERVICE, INC. (INCIDENT NO. 5189)
Baseline Event
893,07212.21 8.65 157,692.96 4,465,360.01 0.20
-11.48%10.06
---
09/29/20 8.32 14261.21 -22.99%-22.99%
11594.99 ---05/06/20
01/25/21 12925.76 9.36%
Area 1
8.65
Page 1 of 3
Area ID Well ID Area
(ft²)
Average Well
Depth
(ft.)
Average
Depth to
Water
(ft.)
Water Column
Height
(ft)
Volume
(ft³)
Volume
(L)
Effective
Porosity
Effective
Volume
(L)
MW-2
MW-3
GMW-1
GMW-3
GMW-5
GMW-6
GMW-7
Area Date Well Benzene
(μ/L)
Toluene
(μ/L)
Ethylbenzene
(μ/L)
Xylenes
(μ/L)
MTBE
(μ/L)
Naphthalene
(μ/L)
Total
(μ/L)
DTW
(ft.)
Average Water
Column Height
(ft.)
Total Average Mass
(g)Percent Red.To Date Red.
1 18,230.4 20.86
APPENDIX C
CONTAMINANT MASS CALCULATIONS
JOHN'S CITGO SERVICE, INC. (INCIDENT NO. 5189)
Baseline Event
893,07212.21 8.65 157,692.96 4,465,360.01 0.20
MW-2 257 3460 1120 5560 0.00 238 10635.00 15.10
MW-3 571 11700 2910 16400 0.00 2830 34411.00 14.40
GMW-1 1070 9420 1420 8480 0.00 392 20782.00 13.55
GMW-3 113 1110 248 841 0.00 45.1 2357.10 13.51
GMW-5 0.00 131.00 118.00 573.00 0.00 51.10 873.10 10.46
GMW-6 8.70 79.60 51.00 202.00 0.00 12.80 354.10 10.79
GMW-7 379 4530 2000 11400 0.00 1490 19799.00 14.31
Avg.342.67 4347.23 1123.86 6208.00 0.00 722.71 12744.47 13.16
MW-2 125.00 1480.00 523.00 2670.00 0.00 166.00 4964.00 16.45
MW-3 85.40 2930.00 928.00 7900.00 0.00 517.00 12360.40 15.82
GMW-1 979.00 9820.00 1950.00 12600.00 0.00 533.00 25882.00 15.48
GMW-3 329.00 3190.00 756.00 3440.00 0.00 196.00 7911.00 14.82
GMW-5 0.00 131.00 118.00 573.00 0.00 51.10 873.10 16.33
GMW-6 298.00 600.00 430.00 806.00 0.00 129.00 2263.00 16.17
GMW-7 466.00 5400.00 2880.00 15700.00 0.00 928.00 25374.00 15.89
Avg.326.06 3364.43 1083.57 6241.29 0.00 360.01 11375.36 15.85
MW-4 4.66 78 35.9 273 0.41 25.4 417.37 14.34
MW-5 6.40 186 72.3 534 0.00 74.4 873.10 13.15
GMW-1 992 7890 1410 12400 77.20 779 23548.20 14.25
GMW-3 47.9 323 79.6 357 0.00 24.5 832.00 14.14
GMW-5 0.00 310 377 2150 0.00 212 3049.00 14.11
GMW-6 0.49 12.3 25.9 164 0.00 52.2 254.89 13.38
GMW-7 363 3100 1680 9210 156 559 15068.00 14.56
Avg.202.06 1699.90 525.81 3584.00 33.37 246.64 6291.79 13.99
07/07/21 7.70
Area 1
(Cont.)01/05/22
06/09/22 6.87
12.62%
49.27%41.94%5882.33
10131.71 21.62%
61.51%
5.01
4462.74 55.95%
Page 2 of 3
Area ID Well ID Area
(ft²)
Average Well
Depth
(ft.)
Average
Depth to
Water
(ft.)
Water Column
Height
(ft)
Volume
(ft³)
Volume
(L)
Effective
Porosity
Effective
Volume
(L)
MW-2
MW-3
GMW-1
GMW-3
GMW-5
GMW-6
GMW-7
Area Date Well Benzene
(μ/L)
Toluene
(μ/L)
Ethylbenzene
(μ/L)
Xylenes
(μ/L)
MTBE
(μ/L)
Naphthalene
(μ/L)
Total
(μ/L)
DTW
(ft.)
Average Water
Column Height
(ft.)
Total Average Mass
(g)Percent Red.To Date Red.
1 18,230.4 20.86
APPENDIX C
CONTAMINANT MASS CALCULATIONS
JOHN'S CITGO SERVICE, INC. (INCIDENT NO. 5189)
Baseline Event
893,07212.21 8.65 157,692.96 4,465,360.01 0.20
MW-4 0 0 0 0 0.00 0 0.00 13.33
MW-5 0.777 0 0 0 0.00 0 0.78 12.29
GMW-1 1560 11200 1590 12000 108.00 584 27042.00 14.64
GMW-3 316 1680 291 1240 17.20 74.8 3619.00 13.50
GMW-5 0.00 403 589 3273.1 0.00 421 4686.10 14.51
GMW-6 17.30 67.1 74.8 404 0.00 25.2 588.40 14.83
GMW-7 432 4120 1940 10500 161 656 17809.00 14.41
Avg.332.30 2495.73 640.69 3916.73 40.89 251.57 7677.90 13.93
MW-4 0 0 0 0 0.00 0 0.00 13.33
MW-5 0.000 1.7 0.86 4.7 0.00 1.9 9.16 11.55
GMW-1 2.3 17.9 3.6 37.3 0.67 4.2 65.97 12.21
GMW-3 2.9 17.4 13.9 73.8 0.00 11.8 119.80 11.96
GMW-5 0.00 403 589 3273.1 0.00 421 4686.10 14.51
GMW-6 17.30 67.1 74.8 404 0.00 25.2 588.40 14.83
GMW-7 405 3590 1310 7760 290 306 13661.00 12.57
Avg.61.07 585.30 284.59 1650.41 41.52 110.01 2732.92 12.99
Date
Average Water
Column Height
(ft.)
05/06/20 8.65
09/29/20 8.32
01/25/21 10.06
07/07/21 7.70
01/05/22 5.01
06/09/22 6.87
10/05/22 6.93
04/04/23 7.87
Notes:
• FP: Free Product
• Area of the contaminant plume is calculated from Figure 6
• Height of the water column is calculated by subtracting the average depth to water from the average well depth of the referenced monitoring wells
• Volume of the contaminant plume is calculated by multiplying the area of the plume by the average height of the water column during each sampling event
• Effective porosity is assumed based on the sub-surface soil profile obtained from well construction records and soil boring logs
• Total mass was calculated by multiplying the total contaminant concentrations for the sampling event with effective volume
• Contaminant mass cannot be calculated in wells containing FP; therefore, the total contaminant mass is based on the known concentrations in the area for each sampling event.
• When areas couldn’t be sampled, the last known concentrations were used in the calculations.
-23.1%53%
10,132 21.6%13%
Total Contaminant Mass
(g)
Percent Reduction Compared
to Previous Event Percent Reduction To Date
11,595 ------
5,882 41.9%49%
14,261 -23.0%-23%
Area 1
(Cont.)
04/04/23 7.87 2219.40 59.60%
2,219 59.6%81%
52.62%10/05/22 6.93 5493.46 6.61%
80.86%
4,463 24.1%62%
12,926 9.4%-11%
5,493
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