WS-29296_48461_CA_WSW_20220527_Labs for wsw-Sands

#=CL#
May 27, 2022
LIMS USE: FR - LYNDAL BUTLER
LIMS OBJECT ID: 92606038
92606038
Project:
Pace Project No.:
RE:
Mr. Lyndal Butler
S&ME, Inc.
8646 West Market Street
Greensboro, NC 27409
4358-15-018 General Phase(625)
Dear Mr. Butler:
Enclosed are the analytical results for sample(s) received by the laboratory on May 24, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
[phone]
Enclosures
cc:Wayne Watterson, S&ME, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Lab ID Sample ID Matrix Date Collected Date Received
92606038001 6080 (625)Water 05/24/22 11:48 05/24/22 13:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92606038001 6080 (625)EPA 625.1 58 PASI-CPKS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 18
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92606038001 6080 (625)
Naphthalene 5.8 ug/L 05/26/22 17:364.2EPA 625.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 18
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Method:
Client:S&ME - Greensboro
EPA 625.1
Date:May 27, 2022
Description:625 RVE
General Information:
1 sample was analyzed for EPA 625.1 by Pace Analytical Services Charlotte. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end ofthis report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 625.1 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: 700590
S0: Surrogate recovery outside laboratory control limits.
• LCS (Lab ID: 3656992)
• Terphenyl-d14 (S)
• MS (Lab ID: 3656993)
• Terphenyl-d14 (S)
• MSD (Lab ID: 3656994)
• Terphenyl-d14 (S)
S3: Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
• BLANK (Lab ID: 3656991)
• Nitrobenzene-d5 (S)
• Terphenyl-d14 (S)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 18
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Method:
Client:S&ME - Greensboro
EPA 625.1
Date:May 27, 2022
Description:625 RVE
QC Batch: 700590
L1: Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples
may be biased high.
• LCS (Lab ID: 3656992)
• Di-n-butylphthalate
• Pyrene
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 700590
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35719272001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 3656993)
• Di-n-butylphthalate
• MSD (Lab ID: 3656994)
• Di-n-butylphthalate
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3656993)
• Di-n-octylphthalate
• Hexachloroethane
• MSD (Lab ID: 3656994)
• 2,4,6-Trichlorophenol
• Di-n-octylphthalate
• Pentachlorophenol
R1: RPD value was outside control limits.
• MSD (Lab ID: 3656994)
• 2,4-Dichlorophenol
• 2-Chlorophenol
• 2-Nitrophenol
• 4,6-Dinitro-2-methylphenol
• 4-Nitrophenol
• Hexachloroethane
• N-Nitrosodimethylamine
• Phenol
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Sample:6080 (625)Lab ID:92606038001 Collected:05/24/22 11:48 Received:05/24/22 13:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 05/26/22 17:36 83-32-905/26/22 06:284.2 1.7 1
Acenaphthylene ND ug/L 05/26/22 17:36 208-96-805/26/22 06:284.2 1.6 1
Anthracene ND ug/L 05/26/22 17:36 120-12-705/26/22 06:284.2 1.9 1
Benzo(a)anthracene ND ug/L 05/26/22 17:36 56-55-305/26/22 06:284.2 2.2 1
Benzo(a)pyrene ND ug/L 05/26/22 17:36 50-32-805/26/22 06:284.2 2.3 1
Benzo(b)fluoranthene ND ug/L 05/26/22 17:36 205-99-205/26/22 06:284.2 2.2 1
Benzo(g,h,i)perylene ND ug/L 05/26/22 17:36 191-24-205/26/22 06:284.2 2.4 1
Benzo(k)fluoranthene ND ug/L 05/26/22 17:36 207-08-905/26/22 06:284.2 2.3 1
4-Bromophenylphenyl ether ND ug/L 05/26/22 17:36 101-55-305/26/22 06:284.2 1.5 1
Butylbenzylphthalate ND ug/L 05/26/22 17:36 85-68-705/26/22 06:284.2 2.6 1
4-Chloro-3-methylphenol ND ug/L 05/26/22 17:36 59-50-705/26/22 06:284.2 2.8 1
bis(2-Chloroethoxy)methane ND ug/L 05/26/22 17:36 111-91-105/26/22 06:288.3 1.5 1
bis(2-Chloroethyl) ether ND ug/L 05/26/22 17:36 111-44-405/26/22 06:284.2 1.6 1
2-Chloronaphthalene ND ug/L 05/26/22 17:36 91-58-705/26/22 06:284.2 1.4 1
2-Chlorophenol ND ug/L 05/26/22 17:36 95-57-805/26/22 06:284.2 1.0 1
4-Chlorophenylphenyl ether ND ug/L 05/26/22 17:36 7005-72-305/26/22 06:284.2 1.7 1
Chrysene ND ug/L 05/26/22 17:36 218-01-905/26/22 06:284.2 2.3 1
Dibenz(a,h)anthracene ND ug/L 05/26/22 17:36 53-70-305/26/22 06:284.2 2.5 1
3,3'-Dichlorobenzidine ND ug/L 05/26/22 17:36 91-94-105/26/22 06:288.3 6.8 1
2,4-Dichlorophenol ND ug/L 05/26/22 17:36 120-83-205/26/22 06:284.2 1.2 1
Diethylphthalate ND ug/L 05/26/22 17:36 84-66-205/26/22 06:284.2 1.7 1
2,4-Dimethylphenol ND ug/L 05/26/22 17:36 105-67-905/26/22 06:288.3 1.4 1
Dimethylphthalate ND ug/L 05/26/22 17:36 131-11-305/26/22 06:284.2 1.8 1
Di-n-butylphthalate ND ug/L 05/26/22 17:36 84-74-2 L105/26/22 06:284.2 1.8 1
4,6-Dinitro-2-methylphenol ND ug/L 05/26/22 17:36 534-52-105/26/22 06:288.3 6.5 1
2,4-Dinitrophenol ND ug/L 05/26/22 17:36 51-28-505/26/22 06:2841.7 21.7 1
2,4-Dinitrotoluene ND ug/L 05/26/22 17:36 121-14-205/26/22 06:284.2 1.4 1
2,6-Dinitrotoluene ND ug/L 05/26/22 17:36 606-20-205/26/22 06:284.2 1.4 1
Di-n-octylphthalate ND ug/L 05/26/22 17:36 117-84-005/26/22 06:284.2 3.3 1
bis(2-Ethylhexyl)phthalate ND ug/L 05/26/22 17:36 117-81-705/26/22 06:284.2 3.1 1
Fluoranthene ND ug/L 05/26/22 17:36 206-44-005/26/22 06:284.2 1.8 1
Fluorene ND ug/L 05/26/22 17:36 86-73-705/26/22 06:284.2 1.7 1
Hexachloro-1,3-butadiene ND ug/L 05/26/22 17:36 87-68-305/26/22 06:284.2 1.5 1
Hexachlorobenzene ND ug/L 05/26/22 17:36 118-74-105/26/22 06:284.2 1.8 1
Hexachlorocyclopentadiene ND ug/L 05/26/22 17:36 77-47-405/26/22 06:288.3 1.3 1
Hexachloroethane ND ug/L 05/26/22 17:36 67-72-105/26/22 06:284.2 1.2 1
Indeno(1,2,3-cd)pyrene ND ug/L 05/26/22 17:36 193-39-505/26/22 06:284.2 2.4 1
Isophorone ND ug/L 05/26/22 17:36 78-59-105/26/22 06:288.3 1.4 1
Naphthalene 5.8 ug/L 05/26/22 17:36 91-20-305/26/22 06:284.2 1.7 1
Nitrobenzene ND ug/L 05/26/22 17:36 98-95-305/26/22 06:284.2 1.6 1
2-Nitrophenol ND ug/L 05/26/22 17:36 88-75-505/26/22 06:284.2 1.2 1
4-Nitrophenol ND ug/L 05/26/22 17:36 100-02-705/26/22 06:288.3 5.5 1
N-Nitrosodimethylamine ND ug/L 05/26/22 17:36 62-75-905/26/22 06:284.2 1.6 1
N-Nitroso-di-n-propylamine ND ug/L 05/26/22 17:36 621-64-705/26/22 06:284.2 1.1 1
N-Nitrosodiphenylamine ND ug/L 05/26/22 17:36 86-30-605/26/22 06:288.3 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Sample:6080 (625)Lab ID:92606038001 Collected:05/24/22 11:48 Received:05/24/22 13:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
2,2'-Oxybis(1-chloropropane)ND ug/L 05/26/22 17:36 108-60-105/26/22 06:284.2 0.96 1
Pentachlorophenol ND ug/L 05/26/22 17:36 87-86-505/26/22 06:288.3 3.1 1
Phenanthrene ND ug/L 05/26/22 17:36 85-01-805/26/22 06:284.2 1.7 1
Phenol ND ug/L 05/26/22 17:36 108-95-205/26/22 06:284.2 1.1 1
Pyrene ND ug/L 05/26/22 17:36 129-00-0 L105/26/22 06:284.2 1.8 1
1,2,4-Trichlorobenzene ND ug/L 05/26/22 17:36 120-82-105/26/22 06:284.2 1.4 1
2,4,6-Trichlorophenol ND ug/L 05/26/22 17:36 88-06-205/26/22 06:288.3 1.3 1
Surrogates
Nitrobenzene-d5 (S)65 %05/26/22 17:36 4165-60-005/26/22 06:2810-120 1
2-Fluorobiphenyl (S)57 %05/26/22 17:36 321-60-805/26/22 06:2815-120 1
Terphenyl-d14 (S)91 %05/26/22 17:36 1718-51-005/26/22 06:2811-131 1
Phenol-d6 (S)32 %05/26/22 17:36 13127-88-305/26/22 06:2810-120 1
2-Fluorophenol (S)45 %05/26/22 17:36 367-12-405/26/22 06:2810-120 1
2,4,6-Tribromophenol (S)77 %05/26/22 17:36 118-79-605/26/22 06:2810-137 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
700590
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92606038001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3656991
Associated Lab Samples:92606038001
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 5.0 05/26/22 11:041.7
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 05/26/22 11:041.2
2,4,6-Trichlorophenol ug/L ND 10.0 05/26/22 11:041.6
2,4-Dichlorophenol ug/L ND 5.0 05/26/22 11:041.4
2,4-Dimethylphenol ug/L ND 10.0 05/26/22 11:041.7
2,4-Dinitrophenol ug/L ND 50.0 05/26/22 11:0426.0
2,4-Dinitrotoluene ug/L ND 5.0 05/26/22 11:041.6
2,6-Dinitrotoluene ug/L ND 5.0 05/26/22 11:041.7
2-Chloronaphthalene ug/L ND 5.0 05/26/22 11:041.7
2-Chlorophenol ug/L ND 5.0 05/26/22 11:041.2
2-Nitrophenol ug/L ND 5.0 05/26/22 11:041.4
3,3'-Dichlorobenzidine ug/L ND 10.0 05/26/22 11:048.1
4,6-Dinitro-2-methylphenol ug/L ND 10.0 05/26/22 11:047.8
4-Bromophenylphenyl ether ug/L ND 5.0 05/26/22 11:041.8
4-Chloro-3-methylphenol ug/L ND 5.0 05/26/22 11:043.3
4-Chlorophenylphenyl ether ug/L ND 5.0 05/26/22 11:042.0
4-Nitrophenol ug/L ND 10.0 05/26/22 11:046.6
Acenaphthene ug/L ND 5.0 05/26/22 11:042.0
Acenaphthylene ug/L ND 5.0 05/26/22 11:042.0
Anthracene ug/L ND 5.0 05/26/22 11:042.3
Benzo(a)anthracene ug/L ND 5.0 05/26/22 11:042.7
Benzo(a)pyrene ug/L ND 5.0 05/26/22 11:042.8
Benzo(b)fluoranthene ug/L ND 5.0 05/26/22 11:042.6
Benzo(g,h,i)perylene ug/L ND 5.0 05/26/22 11:042.8
Benzo(k)fluoranthene ug/L ND 5.0 05/26/22 11:042.7
bis(2-Chloroethoxy)methane ug/L ND 10.0 05/26/22 11:041.8
bis(2-Chloroethyl) ether ug/L ND 5.0 05/26/22 11:041.9
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 05/26/22 11:043.7
Butylbenzylphthalate ug/L ND 5.0 05/26/22 11:043.1
Chrysene ug/L ND 5.0 05/26/22 11:042.8
Di-n-butylphthalate ug/L ND 5.0 05/26/22 11:042.2
Di-n-octylphthalate ug/L ND 5.0 05/26/22 11:043.9
Dibenz(a,h)anthracene ug/L ND 5.0 05/26/22 11:043.0
Diethylphthalate ug/L ND 5.0 05/26/22 11:042.0
Dimethylphthalate ug/L ND 5.0 05/26/22 11:042.1
Fluoranthene ug/L ND 5.0 05/26/22 11:042.2
Fluorene ug/L ND 5.0 05/26/22 11:042.1
Hexachloro-1,3-butadiene ug/L ND 5.0 05/26/22 11:041.8
Hexachlorobenzene ug/L ND 5.0 05/26/22 11:042.2
Hexachlorocyclopentadiene ug/L ND 10.0 05/26/22 11:041.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3656991
Associated Lab Samples:92606038001
Matrix:Water
AnalyzedMDL
Hexachloroethane ug/L ND 5.0 05/26/22 11:041.4
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 05/26/22 11:042.9
Isophorone ug/L ND 10.0 05/26/22 11:041.7
N-Nitroso-di-n-propylamine ug/L ND 5.0 05/26/22 11:041.3
N-Nitrosodimethylamine ug/L ND 5.0 05/26/22 11:041.9
N-Nitrosodiphenylamine ug/L ND 10.0 05/26/22 11:043.0
Naphthalene ug/L ND 5.0 05/26/22 11:042.1
Nitrobenzene ug/L ND 5.0 05/26/22 11:041.9
Pentachlorophenol ug/L ND 10.0 05/26/22 11:043.8
Phenanthrene ug/L ND 5.0 05/26/22 11:042.0
Phenol ug/L ND 5.0 05/26/22 11:041.4
Pyrene ug/L ND 5.0 05/26/22 11:042.2
2,4,6-Tribromophenol (S)%121 10-137 05/26/22 11:04
2-Fluorobiphenyl (S)%101 15-120 05/26/22 11:04
2-Fluorophenol (S)%77 10-120 05/26/22 11:04
Nitrobenzene-d5 (S)%147 10-120 S305/26/22 11:04
Phenol-d6 (S)%55 10-120 05/26/22 11:04
Terphenyl-d14 (S)%180 11-131 S305/26/22 11:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3656992LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 28.950 58 44-142
2,2'-Oxybis(1-chloropropane)ug/L 30.450 61 36-166
2,4,6-Trichlorophenol ug/L 43.350 87 37-144
2,4-Dichlorophenol ug/L 39.350 79 1-191
2,4-Dimethylphenol ug/L 39.550 79 32-119
2,4-Dinitrophenol ug/L 202250 81 1-181
2,4-Dinitrotoluene ug/L 58.350 117 39-139
2,6-Dinitrotoluene ug/L 51.750 103 50-158
2-Chloronaphthalene ug/L 34.550 69 60-118
2-Chlorophenol ug/L 35.350 71 23-134
2-Nitrophenol ug/L 42.950 86 29-182
3,3'-Dichlorobenzidine ug/L 121100 121 1-262
4,6-Dinitro-2-methylphenol ug/L 134100 134 1-181
4-Bromophenylphenyl ether ug/L 51.350 103 53-127
4-Chloro-3-methylphenol ug/L 81.1100 81 22-147
4-Chlorophenylphenyl ether ug/L 44.150 88 25-158
4-Nitrophenol ug/L 141250 57 1-132
Acenaphthene ug/L 38.950 78 47-145
Acenaphthylene ug/L 38.950 78 33-145
Anthracene ug/L 50.350 101 1-166
Benzo(a)anthracene ug/L 60.450 121 33-143
Benzo(a)pyrene ug/L 47.950 96 17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3656992LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 46.350 93 24-159
Benzo(g,h,i)perylene ug/L 45.150 90 1-219
Benzo(k)fluoranthene ug/L 46.050 92 11-162
bis(2-Chloroethoxy)methane ug/L 39.950 80 33-184
bis(2-Chloroethyl) ether ug/L 37.450 75 12-158
bis(2-Ethylhexyl)phthalate ug/L 61.050 122 8-158
Butylbenzylphthalate ug/L 60.050 120 1-152
Chrysene ug/L 58.550 117 17-168
Di-n-butylphthalate ug/L 61.1 L1501221-118
Di-n-octylphthalate ug/L 64.350 129 4-146
Dibenz(a,h)anthracene ug/L 46.750 93 1-227
Diethylphthalate ug/L 53.650 107 1-114
Dimethylphthalate ug/L 49.450 99 1-112
Fluoranthene ug/L 61.450 123 26-137
Fluorene ug/L 44.650 89 59-121
Hexachloro-1,3-butadiene ug/L 27.250 54 24-116
Hexachlorobenzene ug/L 49.550 99 1-152
Hexachlorocyclopentadiene ug/L 25.250 50 25-150
Hexachloroethane ug/L 23.450 47 40-113
Indeno(1,2,3-cd)pyrene ug/L 46.750 93 1-171
Isophorone ug/L 39.050 78 21-196
N-Nitroso-di-n-propylamine ug/L 37.650 75 1-230
N-Nitrosodimethylamine ug/L 33.250 66 25-150
N-Nitrosodiphenylamine ug/L 50.950 102 25-150
Naphthalene ug/L 31.250 62 21-133
Nitrobenzene ug/L 40.450 81 35-180
Pentachlorophenol ug/L 104100 104 14-176
Phenanthrene ug/L 54.550 109 54-120
Phenol ug/L 25.250 50 5-112
Pyrene ug/L 57.8 L15011652-115
2,4,6-Tribromophenol (S)%135 10-137
2-Fluorobiphenyl (S)%87 15-120
2-Fluorophenol (S)%66 10-120
Nitrobenzene-d5 (S)%95 10-120
Phenol-d6 (S)%51 10-120
Terphenyl-d14 (S)%S017211-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3656993MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35719272001
3656994
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 50 57 44-14258 3 30501.7U 28.5 29.2
2,2'-Oxybis(1-
chloropropane)ug/L 50 94 36-16675 23 30501.2U 46.9 37.4
2,4,6-Trichlorophenol ug/L M15010437-14418 30501.6U 51.8 9.1J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3656993MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35719272001
3656994
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4-Dichlorophenol ug/L R1501011-19147 73 30501.4U 50.3 23.4
2,4-Dimethylphenol ug/L 50 101 32-11981 23 30501.7U 50.7 40.3
2,4-Dinitrophenol ug/L 250 35 1-18116 3025026.0U 87.7 40.1J
2,4-Dinitrotoluene ug/L 50 116 39-139110 5 30501.6U 57.9 55.0
2,6-Dinitrotoluene ug/L 50 116 50-158102 13 30501.7U 57.9 50.9
2-Chloronaphthalene ug/L 50 91 60-11871 25 30501.7U 45.7 35.6
2-Chlorophenol ug/L R1509223-13447 64 30501.2U 45.8 23.5
2-Nitrophenol ug/L R15012029-18254 76 30501.4U 59.8 26.8
3,3'-Dichlorobenzidine ug/L 100 119 1-262116 2 301008.1U 119 116
4,6-Dinitro-2-methylphenol ug/L R1100721-18122 108 301007.8U 71.7 21.5
4-Bromophenylphenyl ether ug/L 50 98 53-12788 10 30501.8U 49.0 44.2
4-Chloro-3-methylphenol ug/L 100 109 22-14785 24 301003.3U 109 85.2
4-Chlorophenylphenyl ether ug/L 50 94 25-15879 17 30502.0U 47.0 39.6
4-Nitrophenol ug/L R1250561-1326 159 302506.6U 139 16.1
Acenaphthene ug/L 50 95 47-14577 21 30502.0U 47.3 38.5
Acenaphthylene ug/L 50 95 33-14578 20 30502.0U 47.4 38.8
Anthracene ug/L 50 95 1-16692 4 30502.3U 47.7 46.0
Benzo(a)anthracene ug/L 50 112 33-143109 2 30502.7U 55.8 54.6
Benzo(a)pyrene ug/L 50 124 17-163124 1 30502.8U 62.2 61.8
Benzo(b)fluoranthene ug/L 50 117 24-159117 0 30502.6U 58.6 58.5
Benzo(g,h,i)perylene ug/L 50 124 1-219127 2 30502.8U 62.2 63.4
Benzo(k)fluoranthene ug/L 50 121 11-162120 0 30502.7U 60.3 60.1
bis(2-
Chloroethoxy)methane ug/L 50 96 33-18476 23 30501.8U 48.2 38.2
bis(2-Chloroethyl) ether ug/L 50 96 12-15874 26 30501.9U 47.9 37.0
bis(2-Ethylhexyl)phthalate ug/L 50 136 8-158133 2 30503.7U 67.8 66.7
Butylbenzylphthalate ug/L 50 135 1-152137 1 30503.1U 67.5 68.3
Chrysene ug/L 50 108 17-168108 0 30502.8U 53.9 54.1
Di-n-butylphthalate ug/L M0501211-118122 1 30502.2U 60.3 61.1
Di-n-octylphthalate ug/L M1501544-146152 1 30503.9U 77.0 75.9
Dibenz(a,h)anthracene ug/L 50 126 1-227127 1 30503.0U 62.9 63.3
Diethylphthalate ug/L 50 103 1-11497 6 30502.0U 51.6 48.7
Dimethylphthalate ug/L 50 98 1-11287 13 30502.1U 49.1 43.3
Fluoranthene ug/L 50 111 26-137115 3 30502.2U 55.4 57.3
Fluorene ug/L 50 99 59-12184 16 30502.1U 49.3 42.0
Hexachloro-1,3-butadiene ug/L 50 39 24-11653 30 30501.8U 19.5 26.5
Hexachlorobenzene ug/L 50 96 1-15293 4 30502.2U 48.2 46.3
Hexachlorocyclopentadiene ug/L 50 65 25-15052 21 30501.6U 32.3 26.1
Hexachloroethane ug/L M1,R1503740-11355 40 30501.4U 18.3 27.4
Indeno(1,2,3-cd)pyrene ug/L 50 127 1-171127 0 30502.9U 63.6 63.5
Isophorone ug/L 50 97 21-19676 23 30501.7U 48.3 38.1
N-Nitroso-di-n-propylamine ug/L 50 99 1-23076 27 30501.3U 49.7 38.0
N-Nitrosodimethylamine ug/L R1509525-15068 33 30501.9U 47.4 33.8
N-Nitrosodiphenylamine ug/L 50 104 25-15097 7 30503.0U 52.0 48.4
Naphthalene ug/L 50 66 21-13363 6 30502.1U 33.2 31.3
Nitrobenzene ug/L 50 106 35-18085 22 30501.9U 53.1 42.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3656993MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35719272001
3656994
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Pentachlorophenol ug/L M11005314-1764 301003.8U 52.8 4.1J
Phenanthrene ug/L 50 102 54-12099 3 30502.0U 51.2 49.5
Phenol ug/L R150725-11244 49 30501.4U 36.1 21.8
Pyrene ug/L 50 104 52-115104 1 30502.2U 51.9 52.2
2,4,6-Tribromophenol (S)%123 10-13734
2-Fluorobiphenyl (S)%98 15-12079
2-Fluorophenol (S)%85 10-12026
Nitrobenzene-d5 (S)%117 10-12094
Phenol-d6 (S)%69 10-12040
Terphenyl-d14 (S)%S014811-131150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92606038
4358-15-018 General Phase(625)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92606038001 700590 7007386080 (625)EPA 625.1 EPA 625.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/27/2022 11:46 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 18
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