WS-28977_48970_CA_LTRRPT_20230426

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

April 27, 2023

Mr. Jordan Lerew
NCDEQ-UST Section
Greensboro Regional Office
400 W Market Street, Suite 300
Greensboro, NC 27401

Re: Monitoring Well Installation and
Ground Water Sampling Activities
R.H. Barringer Distribution
1620 Fairfax Road
Greensboro, Guilford County,
North Carolina
Incident Number: 30776
GRI Project No: 5925

Dear Mr. Lerew,

Please find enclosed the referenced report for the abovementioned site.
If you have any questions, please contact Sam McKay at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Chris Wilson; Petroleum Equipment and Service, Inc.; file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
April 26, 2023

Mr. Chris Wilson
President
Petroleum Equipment and Service, Inc.
4125 Sinclair Street
Denver, North Carolina 28307

Re: Monitoring Well Installation and
Ground Water Sampling Activities
R.H. Barringer Distributing
1620 Fairfax Road
Greensboro, North Carolina
Guilford County
Incident Number: 30776
GRI Project Number: 5925

Dear Mr. Wilson,

GRI presents the results of the monitoring well installation and ground water sampling activities at the
R.H. Barringer site in Greensboro, North Carolina. The activities were conducted in accordance with the
November 11, 2022, proposal to the NCDEQ.

On April 4, 2023, GRI installed monitoring well MW-2 to a total depth of approximately 20 feet BGS with
a 15-foot screened interval. No free product was observed at the time of installation. A ground water
sample was collected from the newly installed monitoring well and submitted for analyses of VOCs by
EPA Method 6200B, Lead by method 6010D, and EPH and VPH by the MADEP method. The depth to
water in monitoring well MW-2 was 3.74 feet prior to sampling. A Site Location Map and Site Map have
been included as Figure 1 and Figure 2 respectively. A copy of the boring log and well construction
record have been included as Appendix A.

Please see the attached laboratory report for the results of the April 2023 ground water sampling. A
concentration of MTBE was detected in the sample from MW-2 but did not exceed the MAC. All other
requested chemical constituents were reported below the method detection limits. A summary of the
groundwater analytical results is included as Table 1. A copy of the laboratory report is included as
Appendix B.

No further action is warranted for this incident and a NFA letter should be issued.

GRI Project Number: 5925
R.H. Barringer Distributing
Incident Number: 30776

3502 Hayes Road • Monroe, North Carolina 28110
Phone [phone] • [phone] • Fax [phone]

Please contact me at 704-845-4010 or [e-mail] with any questions or
comments.

Sincerely,

Samuel L. McKay III, P.G.
Project Manager

Cc
Jordon Lerew: Guilford County Environmental Health
James Brown : North Carolina Department of Environmental Quality – Winston Salem

FIGURES

SITE LOCATIONFigure 1 Site LocationR.H. Barringer Distributing1620 Fairfax RoadGreensboro, North CarolinaGuilford CountyIncident No. PendingGRI Project No. 5925500 M2000 FTDate: 08/16/2022Location: 36.047395° N -79.872288° W Dad

TABLES

EPA
504.1
SW846
6010D
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 1 30 0.02 15 400 700 200 700 10,000 200
5,000 260,000 80,000 50,000 20,000 6,000 1,000 12,000 50 15,000 NE NE NE NE NE NE
MW-1 05/24/22 2.00 0.469 0.239 J 1.03 J 0.664 J <0.470 NR NR <0.00343 38 <11.5 <25.8 <4.02 47.7 J <124 <61.2
Trip Blank 05/24/22 <0.180 <0.220 <0.170 <0.21 <0.140 <0.470 NR NR NR NR NR NR NR NR NR NR
MW-1 07/06/22 NR NR NR NR NR NR <1.01 <6.92 NR NR NR NR NR NR NR NR
MW-2 04/04/23 <0.180 <0.220 <0.170 <0.210 1.07 <0.470 NR NR NR 0.003 J <11.5 <25.8 <4.02 <28.2 <124 <61.2
Trip Blank 04/04/23 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR NR NR NR NR NR NR NR NR NR
Notes:
• NR: Not Requested.
TABLE 1
SUMMARY OF SAMPLE ANALYTICAL RESULTS
R.H. BARRINGER DISTRIBUTING (INCIDENT NO. 30776)Naphthalene1,2-Dibromoethane(EDB)Date: 04/25/2023
Analytical Method
Contaminant of Concern BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)SM 6200B MADEP EPH C9-C18 AliphaticsC19-C36 AliphaticsUnadjustedC11-C22 Aromatics• J: Estimated value.
• For other compounds reported which did not exceed the MACs, refer to the laboratory reports.
• Results reported in µg/l (micrograms per liter)
• MAC: Maximum Allowable Concenration as specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Standard not established.
• < : Less than the method detection limit specified in the laboratory report.
• Concentrations in bold face type indicate the MACs were below the reported concentrations; concentrations in italics GCLs were below the reported concentrations.
GCL (µg/l)
MADEP VPH REV 2.1
LeadUnadjustedC5-C8 AliphaticsUnadjustedC9-C12 AliphaticsUnadjustedC9-C10 AromaticsFacility ID #: 00-0-0000034383
EPA 625.1
1-Methylnaphthalene2-Methylnaphthalene2L Standard (µg/l)

APPENDICES

APPENDIX A
Well Construction Record and Boring Log

Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Depth:
Diameter:Completion Details:
PID Lab
From To (ppm)Sample Description Color Moisture Odor
Depth (ft)Lithology
SITE INFORMATION
DRILLING INFORMATION
BORING INFORMATION
R.H. Barringer Distributing
5925
4/4/23
Xavier T. Farmer
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-2
6"
20
Well installed at completion
0 0.5 Topsoil
0.5 12 Medium to coarse Sand Golden-brown Moist None
12 20 Fine to medium Silty Sand Medium brown Moist None

Photo 1: Preclearing Photo 2: Completion
Site Name:Date:
Project Number:Log Completed By:
Company:Drill Type:
Driller:License Number:
Boring ID:Top of Casing:
Diameter:Depth to Water:
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
From (ft)To (ft)From (ft)To (ft)Diameter (in)
Sand
Bentonite
Grout
Screen
Casing
SITE INFORMATION
DRILLING INFORMATION
WELL CONSTRUCTION INFORMATION
DIAGRAM - MONITORING WELL
Sand
Bentonite
Grout Screen
Inner Casing
Outer Casing
R.H. Barringer Distributing
5925
4/4/23
Xavier T. Farmer
Geological Resources, Inc.
Matt Steele
Solid Stem Auger
4548-A
MW-2
6"3.74
3 20
1 3
0 1
0 0 0
0 5 2
5 20 2
1
3
20
5
20
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Matt Steele
4548-A
Geological Resources, Inc.
2022-05-06-MW1-RW
4/4/23 MW-2
R.H. Barringer Distributing 00-0-0000034383
1620 Fairfax Rd., Greensboro
Guilford 7843177545
36.04796522 79.87240706
1
20
3.74
6"
Solid Stem Auger
3.74 12 Medium to Coarse Sand
12 20 Silty Sand
0 0 0
0 5 2 Sch 40 PVC
5 20 2 0.010 Sch 40 PVC
0 1 grout pour
1 3 bentonite pour
3 20 #2 Sand Pour
0 0.5 Topsoil
0.5 12 Medium to coarse Sand
12 20 Fine to medium Silty Sand
4/4/23
4
4
4
_______________
3/13/2023
X
R.H. Barringer
1620 Fairfax Road Greensboro, NC 27407
N/A
1
R.H. Barrringer Distributing Company Inc.
1620 Fairfax Road
Greensboro NC 27407
UST closure, high groundwater table
UST
No, But there is one existing monitoring well
Petroleum
25 feet
no
Samuel Bowers
3220-A
3502 Hayes Road
Monroe, NC 28110
704-845-4010
2022-05-06-MW1-RW
2022-05-06-MW1-RW
60
R.H. Barringer Distributing MW-2
1620 Fairfax Rd., Greensboro
36.04796522
79.87240706
X
20 2
3.74
0 5
5 20
0 1 Grout /Cement
1 3 Bentonite
3 20
Locking cap and Manhole
4/4/23
4/4/23
0 0.5 Topsoil
0.5 12 Medium to Coarse SAND
12 20 Fine to Medium Silty SAND
Golden brown
Medium brown
4/4/23

APPENDIX B
Laboratory Report-Ground Water Sample

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

4/17/2023
Geological Resources, Inc. Sam McKay
3502 Hayes Road Monroe, NC, 28110
Ref: Analytical Testing
Lab Report Number: 23-094-0020 Client Project Description: RH Barringer
GRI #5925
Dear Sam McKay:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/4/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 26
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-094-0020
Page 2 of 26
Report Number:
Sample Summary Table
Client Project Description:
23-094-0020
RH Barringer
GRI #5925
Lab No Client Sample ID Matrix Date Collected Date Received
04/04/2023 12:08Aqueous 92910 MW-2 04/04/2023
04/04/2023 08:30Aqueous 92911 Trip Blank 04/04/2023
Page 3 of 26
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-094-0020
Report Limit
Project:RH Barringer
V 92910MW-2
J0.003 04/10/2023 14:056010DLeadmg/L 0.002
0.769 04/13/2023 21:046200BDi-Isopropyl Ether (DIPE)µg/L 0.500
1.07 04/13/2023 21:046200BMethyl tert-butyl ether (MTBE)µg/L 0.140
J1.86 04/13/2023 21:046200Btert-Butyl Alcohol (TBA)µg/L 1.60
Page 4 of 26

Client: Geological Resources, Inc. CASE NARRATIVE
Project: RH Barringer Lab Report Number: 23-094-0020
Date: 4/17/2023
Massachusetts EPH Method MADEP-EPH QC Batch No: V32013 Aliphatic range C9-C18 is failing low in LCS/LCSD.
Analyte: 2-Bromonaphthalene
QC Batch No: V32013/V31953 Fractionation surrogate 2-Bromonaphthalene failed due to concentrated standard. The other fractionation
surrogate 2-Fluorobiphenyl is performing as expected. This proves the fractionation process is working.
Sample 92910 (MW-2) Analyte: Aliphatic C9-C18
QC Batch No: V32013/V31953 QC for this batch is failing, there is no more volume for this sample to be reprepped.
Volatile Organic Compounds - GC/MS Method 6200B Analyte: tert-Amyl alcohol QC Batch No: V32046/V32045
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 5 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-2
92910 Matrix:
4/4/2023 12:08
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 04/13/23 21:04 6200BMSA
0.003 J mg/L 0.002 0.006Lead 1 04/10/23 14:05 6010DJKC
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 6 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-2
92910 Matrix:
4/4/2023 12:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.500Benzene 1 04/13/23 21:04 V32046MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 04/13/23 21:04 V32046MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 04/13/23 21:04 V32046MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 04/13/23 21:04 V32046MSA
<1.50 µg/L 1.50 5.00Bromoform 1 04/13/23 21:04 V32046MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 04/13/23 21:04 V32046MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 04/13/23 21:04 V32046MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 04/13/23 21:04 V32046MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 04/13/23 21:04 V32046MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 04/13/23 21:04 V32046MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 04/13/23 21:04 V32046MSA
<0.220 µg/L 0.220 0.500Chloroform 1 04/13/23 21:04 V32046MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 04/13/23 21:04 V32046MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 04/13/23 21:04 V32046MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 04/13/23 21:04 V32046MSA
0.769 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 04/13/23 21:04 V32046MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 04/13/23 21:04 V32046MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 04/13/23 21:04 V32046MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 04/13/23 21:04 V32046MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 04/13/23 21:04 V32046MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 7 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-2
92910 Matrix:
4/4/2023 12:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 04/13/23 21:04 V32046MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 04/13/23 21:04 V32046MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 04/13/23 21:04 V32046MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 04/13/23 21:04 V32046MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 04/13/23 21:04 V32046MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 04/13/23 21:04 V32046MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 04/13/23 21:04 V32046MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 04/13/23 21:04 V32046MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 04/13/23 21:04 V32046MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 04/13/23 21:04 V32046MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 04/13/23 21:04 V32046MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 04/13/23 21:04 V32046MSA
<42.0 µg/L 42.0 200Ethanol 1 04/13/23 21:04 V32046MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 04/13/23 21:04 V32046MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 04/13/23 21:04 V32046MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 04/13/23 21:04 V32046MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 04/13/23 21:04 V32046MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 04/13/23 21:04 V32046MSA
1.07 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 04/13/23 21:04 V32046MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 04/13/23 21:04 V32046MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 04/13/23 21:04 V32046MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 8 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-2
92910 Matrix:
4/4/2023 12:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<0.470 µg/L 0.470 1.00Naphthalene 1 04/13/23 21:04 V32046MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 04/13/23 21:04 V32046MSA
<0.220 µg/L 0.220 0.500Styrene 1 04/13/23 21:04 V32046MSA
1.86 J µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 04/13/23 21:04 V32046MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 04/13/23 21:04 V32046MSA
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 04/13/23 21:04 V32046MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 04/13/23 21:04 V32046MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 04/13/23 21:04 V32046MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 04/13/23 21:04 V32046MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 04/13/23 21:04 V32046MSA
<0.220 µg/L 0.220 0.500Toluene 1 04/13/23 21:04 V32046MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 04/13/23 21:04 V32046MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 04/13/23 21:04 V32046MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 04/13/23 21:04 V32046MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 04/13/23 21:04 V32046MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 04/13/23 21:04 V32046MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 04/13/23 21:04 V32046MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 04/13/23 21:04 V32046MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 04/13/23 21:04 V32046MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 04/13/23 21:04 V32046MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 04/13/23 21:04 V32046MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 9 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-2
92910 Matrix:
4/4/2023 12:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 04/13/23 21:04 V32046MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 04/13/23 21:04 V32046
Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%04/13/23 21:041 MSA V32046
Surrogate: Dibromofluoromethane 95.8 Limits: 70-130%04/13/23 21:041 MSA V32046
Surrogate: 1,2-Dichloroethane - d4 91.6 Limits: 70-130%04/13/23 21:041 MSA V32046
Surrogate: Toluene-d8 94.2 Limits: 70-130%04/13/23 21:041 MSA V32046
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 10 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-2
92910 Matrix:
4/4/2023 12:08
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V31953 04/13/23 10:02
<28.2 µg/L 28.2 350Aliphatic C9-C18 1 04/14/23 11:24 V32013AMP
<124 µg/L 124 500Aliphatic C19-C36 1 04/14/23 11:24 V32013AMP
<61.2 µg/L 61.2 250Aromatic C11-C22 1 04/14/23 11:24 V32013AMP
MADEP-EPHSurrogate: 2-Bromonaphthalene 188 *Limits: 40-140%04/14/23 11:241 AMP
MADEP-EPHSurrogate: Chlorooctadecane 43.3 Limits: 40-140%04/14/23 11:241 AMP
MADEP-EPHSurrogate: OTP Surrogate 85.9 Limits: 40-140%04/14/23 11:241 AMP
Surrogate: 2-Fluorobiphenyl 111 Limits: 40-140%04/14/23 11:241 AMP V32013
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V31663 04/05/23 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 04/05/23 15:16 V31664TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 04/05/23 15:16 V31664TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 04/05/23 15:16 V31664TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)82.2 Limits: 70-130%04/05/23 15:161 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)95.0 Limits: 70-130%04/05/23 15:161 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 11 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:Trip Blank
92911 Matrix:
4/4/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<1.80 µg/L 1.80 10.0Acetone 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.500Benzene 1 04/13/23 20:37 V32046MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 04/13/23 20:37 V32046MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 04/13/23 20:37 V32046MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 04/13/23 20:37 V32046MSA
<1.50 µg/L 1.50 5.00Bromoform 1 04/13/23 20:37 V32046MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 04/13/23 20:37 V32046MSA
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 04/13/23 20:37 V32046MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 04/13/23 20:37 V32046MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 04/13/23 20:37 V32046MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 04/13/23 20:37 V32046MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 04/13/23 20:37 V32046MSA
<0.220 µg/L 0.220 0.500Chloroform 1 04/13/23 20:37 V32046MSA
<0.220 µg/L 0.220 0.500Chloromethane 1 04/13/23 20:37 V32046MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 04/13/23 20:37 V32046MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 04/13/23 20:37 V32046MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 04/13/23 20:37 V32046MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 04/13/23 20:37 V32046MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 04/13/23 20:37 V32046MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 04/13/23 20:37 V32046MSA
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 04/13/23 20:37 V32046MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 12 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:Trip Blank
92911 Matrix:
4/4/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 04/13/23 20:37 V32046MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 04/13/23 20:37 V32046MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 04/13/23 20:37 V32046MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 04/13/23 20:37 V32046MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 04/13/23 20:37 V32046MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 04/13/23 20:37 V32046MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 04/13/23 20:37 V32046MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 04/13/23 20:37 V32046MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 04/13/23 20:37 V32046MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 04/13/23 20:37 V32046MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 04/13/23 20:37 V32046MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 04/13/23 20:37 V32046MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 04/13/23 20:37 V32046MSA
<42.0 µg/L 42.0 200Ethanol 1 04/13/23 20:37 V32046MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 04/13/23 20:37 V32046MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 04/13/23 20:37 V32046MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 04/13/23 20:37 V32046MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 04/13/23 20:37 V32046MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 04/13/23 20:37 V32046MSA
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 04/13/23 20:37 V32046MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 04/13/23 20:37 V32046MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 13 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:Trip Blank
92911 Matrix:
4/4/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<0.330 µg/L 0.330 2.00Methylene Chloride 1 04/13/23 20:37 V32046MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 04/13/23 20:37 V32046MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 04/13/23 20:37 V32046MSA
<0.220 µg/L 0.220 0.500Styrene 1 04/13/23 20:37 V32046MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 04/13/23 20:37 V32046MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 04/13/23 20:37 V32046MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 04/13/23 20:37 V32046MSA
<0.220 µg/L 0.220 0.500Toluene 1 04/13/23 20:37 V32046MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 04/13/23 20:37 V32046MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 04/13/23 20:37 V32046MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 04/13/23 20:37 V32046MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 04/13/23 20:37 V32046MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 04/13/23 20:37 V32046MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 04/13/23 20:37 V32046MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 04/13/23 20:37 V32046MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 04/13/23 20:37 V32046MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 04/13/23 20:37 V32046MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 04/13/23 20:37 V32046MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 04/13/23 20:37 V32046MSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 14 of 26
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
23-094-0020
00087
Geological Resources, Inc.
3502 Hayes Road
Sam McKay
Monroe
Danyale Love
Project Manager
GRI #5925 Received : 04/04/2023
RH Barringer
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:Trip Blank
92911 Matrix:
4/4/2023 8:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V32045 04/13/23 09:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 04/13/23 20:37 V32046
Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%04/13/23 20:371 MSA V32046
Surrogate: Dibromofluoromethane 97.4 Limits: 70-130%04/13/23 20:371 MSA V32046
Surrogate: 1,2-Dichloroethane - d4 91.4 Limits: 70-130%04/13/23 20:371 MSA V32046
Surrogate: Toluene-d8 95.4 Limits: 70-130%04/13/23 20:371 MSA V32046
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLEstimated valueJ
Page 15 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Metals Analysis
6010D
V31773QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V31681
Associated Lab Samples: 92910
LRB-V31681 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
04/07/23 12:480.0060.002<0.002mg/LLead
LCS-V31681Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1020.1020.100mg/LLead 80-120
V 92499-MS-V31681 V 92499-MSD-V31681Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.104 1040.1030.1000.100< 0.002mg/LLead 103 75-125 0.9 20.0
V 92499-PDS-V31681Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
04/07/23 13:421050.261mg/LLead
Page 1 of 9Date:04/17/2023 06:09 PM
Page 16 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32045
Associated Lab Samples: 92910, 92911
LRB-V32045 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/23 19:4310.01.80<1.80µg/LAcetone
04/13/23 19:430.5000.180<0.180µg/LBenzene
04/13/23 19:430.5000.210<0.210µg/LBromobenzene
04/13/23 19:431.000.420<0.420µg/LBromochloromethane
04/13/23 19:430.5000.160<0.160µg/LBromodichloromethane
04/13/23 19:435.001.50<1.50µg/LBromoform
04/13/23 19:431.000.280<0.280µg/LBromomethane
04/13/23 19:430.5000.180<0.180µg/Ln-Butylbenzene
04/13/23 19:430.5000.200<0.200µg/Lsec-Butyl benzene
04/13/23 19:432.000.920<0.920µg/Ltert-Butyl benzene
04/13/23 19:430.5000.180<0.180µg/LCarbon Tetrachloride
04/13/23 19:430.5000.190<0.190µg/LChlorobenzene
04/13/23 19:430.5000.190<0.190µg/LChlorodibromomethane
04/13/23 19:431.000.430<0.430µg/LChloroethane
04/13/23 19:430.5000.220<0.220µg/LChloroform
04/13/23 19:430.5000.220<0.220µg/LChloromethane
04/13/23 19:430.5000.200<0.200µg/L2-Chlorotoluene
04/13/23 19:430.5000.200<0.200µg/L4-Chlorotoluene
04/13/23 19:430.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
04/13/23 19:432.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
04/13/23 19:430.5000.200<0.200µg/L1,2-Dibromoethane
04/13/23 19:430.5000.230<0.230µg/LDibromomethane
04/13/23 19:430.5000.220<0.220µg/L1,2-Dichlorobenzene
04/13/23 19:430.5000.190<0.190µg/L1,3-Dichlorobenzene
04/13/23 19:430.5000.210<0.210µg/L1,4-Dichlorobenzene
04/13/23 19:435.001.20<1.20µg/LDichlorodifluoromethane
04/13/23 19:430.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 9Date:04/17/2023 06:09 PM
Page 17 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32045
Associated Lab Samples: 92910, 92911
LRB-V32045 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/23 19:430.5000.150<0.150µg/L1,2-Dichloroethane
04/13/23 19:430.5000.150<0.150µg/L1,1-Dichloroethene
04/13/23 19:430.5000.200<0.200µg/Lcis-1,2-Dichloroethene
04/13/23 19:430.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
04/13/23 19:430.5000.190<0.190µg/L1,2-Dichloropropane
04/13/23 19:430.5000.130<0.130µg/L1,3-Dichloropropane
04/13/23 19:432.000.210<0.210µg/L2,2-Dichloropropane
04/13/23 19:430.5000.200<0.200µg/L1,1-Dichloropropene
04/13/23 19:430.5000.210<0.210µg/Lcis-1,3-Dichloropropene
04/13/23 19:430.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
04/13/23 19:4320042.0<42.0µg/LEthanol
04/13/23 19:430.5000.170<0.170µg/LEthylbenzene
04/13/23 19:433.000.350<0.350µg/LHexachlorobutadiene
04/13/23 19:431.000.380<0.380µg/L2-Hexanone
04/13/23 19:430.5000.180<0.180µg/LIsopropylbenzene
04/13/23 19:430.5000.089<0.089µg/L4-Isopropyl toluene
04/13/23 19:435.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
04/13/23 19:431.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
04/13/23 19:431.000.078<0.078µg/L4-Methyl-2-Pentanone
04/13/23 19:432.000.330<0.330µg/LMethylene Chloride
04/13/23 19:431.000.470<0.470µg/LNaphthalene
04/13/23 19:430.5000.190<0.190µg/Ln-Propylbenzene
04/13/23 19:430.5000.220<0.220µg/LStyrene
04/13/23 19:4310.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
04/13/23 19:4310.00.350<0.350µg/Ltert-Butyl formate (TBF)
04/13/23 19:4310.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
04/13/23 19:4310.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 3 of 9Date:04/17/2023 06:09 PM
Page 18 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32045
Associated Lab Samples: 92910, 92911
LRB-V32045 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/23 19:430.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
04/13/23 19:430.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
04/13/23 19:430.5000.220<0.220µg/LTetrachloroethene
04/13/23 19:430.5000.220<0.220µg/LToluene
04/13/23 19:430.5000.380<0.380µg/L1,2,3-Trichlorobenzene
04/13/23 19:430.5000.310<0.310µg/L1,2,4-Trichlorobenzene
04/13/23 19:430.5000.160<0.160µg/L1,1,1-Trichloroethane
04/13/23 19:430.5000.096<0.096µg/L1,1,2-Trichloroethane
04/13/23 19:430.5000.180<0.180µg/LTrichloroethene
04/13/23 19:430.5000.180<0.180µg/LTrichlorofluoromethane
04/13/23 19:430.5000.270<0.270µg/L1,2,3-Trichloropropane
04/13/23 19:430.5000.190<0.190µg/L1,2,4-Trimethylbenzene
04/13/23 19:430.5000.180<0.180µg/L1,3,5-Trimethylbenzene
04/13/23 19:435.001.00<1.00µg/LVinyl Acetate
04/13/23 19:430.5000.170<0.170µg/LVinyl Chloride
04/13/23 19:430.5000.210<0.210µg/Lo-Xylene
04/13/23 19:431.000.420<0.420µg/Lm,p-Xylene
04/13/23 19:4310.01.00<1.00µg/L3,3-Dimethyl-1-butanol
04/13/23 19:434-Bromofluorobenzene (S)109 70-130
04/13/23 19:43Dibromofluoromethane (S)96.2 70-130
04/13/23 19:431,2-Dichloroethane - d4 (S)92.0 70-130
04/13/23 19:43Toluene-d8 (S)93.8 70-130
Page 4 of 9Date:04/17/2023 06:09 PM
Page 19 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32045
LCS-V32045 LCSD-V32045Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
46.0 11512550.140.0µg/LAcetone 40-160 8.5 20.0
21.8 10911422.720.0µg/LBenzene 70-130 4.0 20.0
21.6 10811021.920.0µg/LBromobenzene 70-130 1.3 20.0
22.8 11411322.520.0µg/LBromochloromethane 70-130 1.3 20.0
20.0 10010120.220.0µg/LBromodichloromethane 70-130 0.9 20.0
19.0 95.090.018.020.0µg/LBromoform 70-130 5.4 20.0
17.9 89.596.519.320.0µg/LBromomethane 60-140 7.5 20.0
20.4 10210821.620.0µg/Ln-Butylbenzene 70-130 5.7 20.0
20.2 10110520.920.0µg/Lsec-Butyl benzene 70-130 3.4 20.0
19.8 99.010320.620.0µg/Ltert-Butyl benzene 70-130 3.9 20.0
16.7 83.590.018.020.0µg/LCarbon Tetrachloride 70-130 7.4 20.0
21.0 10511022.020.0µg/LChlorobenzene 70-130 4.6 20.0
18.5 92.593.018.620.0µg/LChlorodibromomethane 70-130 0.5 20.0
18.6 93.099.019.820.0µg/LChloroethane 60-140 6.2 20.0
20.5 10311022.020.0µg/LChloroform 70-130 7.0 20.0
19.5 97.510420.720.0µg/LChloromethane 60-140 5.9 20.0
21.1 10611021.920.0µg/L2-Chlorotoluene 70-130 3.7 20.0
21.9 11010821.520.0µg/L4-Chlorotoluene 70-130 1.8 20.0
23.5 11811923.820.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.2 20.0
19.6 98.088.017.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 10.7 20.0
21.7 10910120.120.0µg/L1,2-Dibromoethane 70-130 7.6 20.0
22.7 11411723.320.0µg/LDibromomethane 70-130 2.6 20.0
21.2 10610621.220.0µg/L1,2-Dichlorobenzene 70-130 0.0 20.0
20.9 10510621.120.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0
21.3 10710921.720.0µg/L1,4-Dichlorobenzene 70-130 1.8 20.0
15.6 78.080.016.020.0µg/LDichlorodifluoromethane 60-140 2.5 20.0
Page 5 of 9Date:04/17/2023 06:09 PM
Page 20 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32045
LCS-V32045 LCSD-V32045Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.9 10511122.120.0µg/L1,1-Dichloroethane 70-130 5.5 20.0
20.0 10010120.220.0µg/L1,2-Dichloroethane 70-130 0.9 20.0
19.3 96.594.518.920.0µg/L1,1-Dichloroethene 70-130 2.0 20.0
21.8 10911623.120.0µg/Lcis-1,2-Dichloroethene 70-130 5.7 20.0
20.5 10310721.420.0µg/Ltrans-1,2-Dichloroethene 70-130 4.2 20.0
21.9 11011522.920.0µg/L1,2-Dichloropropane 70-130 4.4 20.0
23.1 11611422.720.0µg/L1,3-Dichloropropane 70-130 1.7 20.0
19.1 95.510220.420.0µg/L2,2-Dichloropropane 70-130 6.5 20.0
20.1 10110621.220.0µg/L1,1-Dichloropropene 70-130 5.3 20.0
21.9 11011022.020.0µg/Lcis-1,3-Dichloropropene 70-130 0.4 20.0
21.5 10811022.020.0µg/Ltrans-1,3-Dichloropropene 70-130 2.2 20.0
531 10691.8459500µg/LEthanol 60-140 14.5 20.0
19.8 99.010420.820.0µg/LEthylbenzene 70-130 4.9 20.0
17.8 89.095.019.020.0µg/LHexachlorobutadiene 70-130 6.5 20.0
20.8 10411022.020.0µg/L2-Hexanone 60-140 5.6 20.0
20.3 10210821.520.0µg/LIsopropylbenzene 70-130 5.7 20.0
20.0 10010420.720.0µg/L4-Isopropyl toluene 70-130 3.4 20.0
22.3 11211022.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 1.3 20.0
22.2 11111022.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.9 20.0
25.4 12712324.520.0µg/L4-Methyl-2-Pentanone 60-140 3.6 20.0
21.5 10811322.620.0µg/LMethylene Chloride 70-130 4.9 20.0
20.1 10197.519.520.0µg/LNaphthalene 70-130 3.0 20.0
21.2 10610921.820.0µg/Ln-Propylbenzene 70-130 2.7 20.0
21.8 10911322.620.0µg/LStyrene 70-130 3.6 20.0
39.9 99.790.236.140.0µg/Ltert-Butyl Alcohol (TBA)40-140 10.0 20.0
45.5 11411545.840.0µg/Ltert-Butyl formate (TBF)40-140 0.6 20.0
Page 6 of 9Date:04/17/2023 06:09 PM
Page 21 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32046QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32045
LCS-V32045 LCSD-V32045Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
17.4 87.059.511.920.0µg/Ltert-Amyl Alcohol (TAA)40-140 37.5*20.0
46.2 11611545.940.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.6 20.0
19.8 99.099.519.920.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.5 20.0
23.0 11511021.920.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.8 20.0
18.9 94.599.019.820.0µg/LTetrachloroethene 70-130 4.6 20.0
22.0 11011623.220.0µg/LToluene 70-130 5.3 20.0
18.8 94.010120.120.0µg/L1,2,3-Trichlorobenzene 70-130 6.6 20.0
17.7 88.587.017.420.0µg/L1,2,4-Trichlorobenzene 70-130 1.7 20.0
19.2 96.010120.120.0µg/L1,1,1-Trichloroethane 70-130 4.5 20.0
23.5 11811723.320.0µg/L1,1,2-Trichloroethane 70-130 0.8 20.0
20.6 10310921.720.0µg/LTrichloroethene 70-130 5.2 20.0
15.7 78.583.516.720.0µg/LTrichlorofluoromethane 60-140 6.1 20.0
20.3 10210320.520.0µg/L1,2,3-Trichloropropane 70-130 0.9 20.0
20.6 10310721.420.0µg/L1,2,4-Trimethylbenzene 70-130 3.8 20.0
21.1 10610721.320.0µg/L1,3,5-Trimethylbenzene 70-130 0.9 20.0
22.5 11312124.120.0µg/LVinyl Acetate 60-140 6.8 20.0
17.7 88.595.519.120.0µg/LVinyl Chloride 60-140 7.6 20.0
20.8 10410721.420.0µg/Lo-Xylene 70-130 2.8 20.0
42.4 10611244.840.0µg/Lm,p-Xylene 70-130 5.5 20.0
16.8 84.071.514.320.0µg/L3,3-Dimethyl-1-butanol 70-130 16.0 20.0
1071054-Bromofluorobenzene (S)70-130
96.296.0Dibromofluoromethane (S)70-130
92.694.01,2-Dichloroethane - d4 (S)70-130
96.496.0Toluene-d8 (S)70-130
Page 7 of 9* QC Fail Date:04/17/2023 06:09 PM
Page 22 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V32013QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V31953
Associated Lab Samples: 92910
LRB-V31953 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/14/23 09:3535028.2<28.2µg/LAliphatic C9-C18
04/14/23 09:35500124<124µg/LAliphatic C19-C36
04/14/23 09:3525061.2<61.2µg/LAromatic C11-C22
04/14/23 09:352-Fluorobiphenyl (S)95.2 40-140
04/14/23 09:352-Bromonaphthalene (S)157 40-140
04/14/23 09:35Chlorooctadecane (S)68.3 40-140
04/14/23 09:35OTP Surrogate (S)64.3 40-140
LCS-V31953 LCSD-V31953Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
224 37.3*39.8*239600µg/LAliphatic C9-C18 40-140 6.4 50.0
410 51.261.6493800µg/LAliphatic C19-C36 40-140 18.3 50.0
1050 61.775.812901700µg/LAromatic C11-C22 40-140 20.5 50.0
96.21032-Fluorobiphenyl (S)40-140
163*175*2-Bromonaphthalene (S)40-140
48.762.5Chlorooctadecane (S)40-140
57.874.2OTP Surrogate (S)40-140
Page 8 of 9* QC Fail Date:04/17/2023 06:09 PM
Page 23 of 26
Quality Control Data
23-094-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RH Barringer
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V31664QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V31663
Associated Lab Samples: 92910
LRB-V31663 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/05/23 09:4550.011.5<11.5µg/LAliphatic C5-C8
04/05/23 09:4550.025.8<25.8µg/LAliphatic C9-C12
04/05/23 09:4550.04.02<4.02µg/LAromatic C9-C10
04/05/23 09:452,5-Dibromotoluene (FID) (S)81.0 70-130
04/05/23 09:452,5-Dibromotoluene (PID) (S)94.3 70-130
LCS-V31663 LCSD-V31663Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
292 97.395.3286300µg/LAliphatic C5-C8 70-130 2.0 50.0
363 121123370300µg/LAliphatic C9-C12 70-130 1.9 50.0
118 118102102100µg/LAromatic C9-C10 70-130 14.5 50.0
90.496.92,5-Dibromotoluene (FID) (S)70-130
99.51062,5-Dibromotoluene (PID) (S)70-130
Page 9 of 9Date:04/17/2023 06:09 PM
Page 24 of 26
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-094-0020
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 1.8C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:04/04/2023 15:59:22
Special precautions or instructions included?
Comments:
Page 25 of 26
Page 26 of 26