WS-5420_18698_CA_LAB_20221027_Mise Property POE Monitoring Data

ANALYTICAL REPORT
Eurofins Pensacola
3355 McLemore Drive
Pensacola, FL 32514
Tel: [phone]
Laboratory Job ID: 400-228080-1
Laboratory Sample Delivery Group: NC0150 TF#9615
Client Project/Site: Wanda Mise
For:
North Carolina Dept of Env Quality
NCDEQ-DWM-UST SECTION
1646 Mail Service Center
Raleigh, North Carolina 27699
Attn: Linda Blalock
Authorized for release by:
11/11/2022 11:30:42 AM
Isabel Enfinger, Project Manager I
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI
requirements for accredited parameters, exceptions are noted in this report. This
report may not be reproduced except in full, and with written approval from the
laboratory. For questions please contact the Project Manager at the e-mail address or
telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic
signature is intended to be the legally binding equivalent of a traditionally handwritten
signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
The test results in this report relate only to the samples as received by the laboratory
and will meet all requirements of the methodology, with any exceptions noted. This
report shall not be reproduced except in full, without the express written approval of
the laboratory. All questions should be directed to the {0} Project Manager.
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Table of Contents
Client: North Carolina Dept of Env Quality
Project/Site: Wanda Mise
Laboratory Job ID: 400-228080-1
SDG: NC0150 TF#9615
Page 2 of 26 Eurofins Pensacola11/11/2022
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
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Case Narrative
Client: North Carolina Dept of Env Quality Job ID: 400-228080-1
Project/Site: Wanda Mise SDG: NC0150 TF#9615
Job ID: 400-228080-1
Laboratory: Eurofins Pensacola
Narrative
Job Narrative
400-228080-1
Comments
No additional comments.
Receipt
The samples were received on 10/31/2022 8:41 AM. Unless otherwise noted below, the samples arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 5.5º C.
GC/MS VOA
Method SM6200-B: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 400-599983 were outside control
limits. Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS)
recovery was within acceptance limits.
Method SM6200-B: The laboratory control sample (LCS) for analytical batch 400-599983 recovered outside control limits for the following
analytes: Bromomethane. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the
data have been reported.
Method SM6200-B: The continuing calibration verification (CCV) associated with batch 400-599983 recovered above the upper control limit
for Bromomethane. The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have been
reported
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
GC Semi VOA
Method 504.1: The closing continuing calibration verification (CCV) associated with batch 400-599349 recovered above the upper control
limit for Ethylene Dibromide. The samples associated with this CCV that were non-detects for the affected analytes have been reported.
Method 504.1: The closing continuing calibration verification (CCV) standard associated with batch 400-599349 recovered outside the
upper limits. The following samples contained the target analyte, Ethylene Dibromide, therefore, re-analysis was performed outside of
Holding Time. Both sets of data have been reported
D1 (400-228080-3)
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins PensacolaPage 3 of 26 11/11/2022
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Detection Summary
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Client Sample ID: D1 Lab Sample ID: 400-228080-1
Chloroform
RL
1.0 ug/L
MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type
Total/NA11.1 SM6200-B
Client Sample ID: D3 Lab Sample ID: 400-228080-2
No Detections.
Client Sample ID: D1 Lab Sample ID: 400-228080-3
Ethylene Dibromide
RL
0.021 ug/L
MDLAnalyteResultQualifier Unit Dil Fac D Method Prep Type
Total/NA10.35 504.1
Ethylene Dibromide - RA 0.021 ug/L Total/NA10.30 H 504.1
Client Sample ID: D3 Lab Sample ID: 400-228080-4
No Detections.
Eurofins Pensacola
This Detection Summary does not include radiochemical test results.
Page 4 of 26 11/11/2022
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Method Summary
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method Method Description LaboratoryProtocol
SMSM6200-B Volatile Organic Compounds EET PEN
EPA-DW504.1 EDB, DBCP and 1,2,3-TCP (GC)EET PEN
SW8465030BPurge and Trap EET PEN
EPA-DW504.1 Microextraction EET PEN
Protocol References:
EPA-DW = "Methods For The Determination Of Organic Compounds In Drinking Water", EPA/600/4-88/039, December 1988 And Its Supplements.
SM = "Standard Methods For The Examination Of Water And Wastewater"
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
Page 5 of 26 11/11/2022
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Sample Summary
Client: North Carolina Dept of Env Quality Job ID: 400-228080-1
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Lab Sample ID Client Sample ID Matrix Collected Received
400-228080-1 D1 Water 10/27/22 08:10 10/31/22 08:41
400-228080-2 D3 Water 10/27/22 08:15 10/31/22 08:41
400-228080-3 D1 Water 10/27/22 08:20 10/31/22 08:41
400-228080-4 D3 Water 10/27/22 08:25 10/31/22 08:41
Eurofins PensacolaPage 6 of 26 11/11/2022
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Client Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Lab Sample ID: 400-228080-1Client Sample ID: D1
Matrix: WaterDate Collected: 10/27/22 08:10
Date Received: 10/31/22 08:41
Method: SM6200-B - Volatile Organic Compounds
RL MDL
<1.0 1.0 ug/L 11/09/22 20:54 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
1.0 ug/L 11/09/22 20:54 1<1.01,1,2,2-Tetrachloroethane
1.0 ug/L 11/09/22 20:54 1<1.01,1,2-Trichloro-1,2,2-trifluoroethane
5.0 ug/L 11/09/22 20:54 1<5.01,1,2-Trichloroethane
1.0 ug/L 11/09/22 20:54 1<1.01,1-Dichloroethane
1.0 ug/L 11/09/22 20:54 1<1.01,1-Dichloroethene
1.0 ug/L 11/09/22 20:54 1<1.01,2,3-Trichlorobenzene
1.0 ug/L 11/09/22 20:54 1<1.01,2,4-Trichlorobenzene
1.0 ug/L 11/09/22 20:54 1<1.0 F11,2,4-Trimethylbenzene
5.0 ug/L 11/09/22 20:54 1<5.01,2-Dibromo-3-Chloropropane
1.0 ug/L 11/09/22 20:54 1<1.01,2-Dichlorobenzene
1.0 ug/L 11/09/22 20:54 1<1.01,2-Dichloroethane
1.0 ug/L 11/09/22 20:54 1<1.01,2-Dichloropropane
1.0 ug/L 11/09/22 20:54 1<1.0 F11,3,5-Trimethylbenzene
1.0 ug/L 11/09/22 20:54 1<1.0 F11,3-Dichlorobenzene
1.0 ug/L 11/09/22 20:54 1<1.0 F11,4-Dichlorobenzene
25 ug/L 11/09/22 20:54 1<252-Butanone (MEK)
25 ug/L 11/09/22 20:54 1<252-Hexanone
25 ug/L 11/09/22 20:54 1<254-Methyl-2-pentanone (MIBK)
25 ug/L 11/09/22 20:54 1<25Acetone
1.0 ug/L 11/09/22 20:54 1<1.0Benzene
5.0 ug/L 11/09/22 20:54 1<5.0Bromoform
1.0 ug/L 11/09/22 20:54 1<1.0 F1 *+Bromomethane
1.0 ug/L 11/09/22 20:54 1<1.0Carbon disulfide
1.0 ug/L 11/09/22 20:54 1<1.0Carbon tetrachloride
1.0 ug/L 11/09/22 20:54 1<1.0 F1Chlorobenzene
1.0 ug/L 11/09/22 20:54 1<1.0Chlorobromomethane
1.0 ug/L 11/09/22 20:54 1<1.0Chlorodibromomethane
1.0 ug/L 11/09/22 20:54 1<1.0Chloroethane
1.0 ug/L 11/09/22 20:54 11.1Chloroform
1.0 ug/L 11/09/22 20:54 1<1.0Chloromethane
1.0 ug/L 11/09/22 20:54 1<1.0cis-1,2-Dichloroethene
5.0 ug/L 11/09/22 20:54 1<5.0cis-1,3-Dichloropropene
5.0 ug/L 11/09/22 20:54 1<5.0Dibromomethane
1.0 ug/L 11/09/22 20:54 1<1.0Dichlorobromomethane
1.0 ug/L 11/09/22 20:54 1<1.0Dichlorodifluoromethane
1.0 ug/L 11/09/22 20:54 1<1.0 F1Ethylbenzene
1.0 ug/L 11/09/22 20:54 1<1.0Ethylene Dibromide
1.0 ug/L 11/09/22 20:54 1<1.0Methyl tert-butyl ether
5.0 ug/L 11/09/22 20:54 1<5.0Methylene Chloride
5.0 ug/L 11/09/22 20:54 1<5.0 F1m-Xylene & p-Xylene
5.0 ug/L 11/09/22 20:54 1<5.0Naphthalene
5.0 ug/L 11/09/22 20:54 1<5.0 F1o-Xylene
1.0 ug/L 11/09/22 20:54 1<1.0 F1Styrene
1.0 ug/L 11/09/22 20:54 1<1.0 F1Tetrachloroethene
1.0 ug/L 11/09/22 20:54 1<1.0 F1Toluene
1.0 ug/L 11/09/22 20:54 1<1.0Trichloroethene
1.0 ug/L 11/09/22 20:54 1<1.0Trichlorofluoromethane
1.0 ug/L 11/09/22 20:54 1<1.0Vinyl chloride
Eurofins Pensacola
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Client Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Lab Sample ID: 400-228080-1Client Sample ID: D1
Matrix: WaterDate Collected: 10/27/22 08:10
Date Received: 10/31/22 08:41
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
<10 F1 10 ug/L 11/09/22 20:54 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Xylenes, Total
1.0 ug/L 11/09/22 20:54 1<1.0Isopropyl ether
4-Bromofluorobenzene 93 72-119 11/09/22 20:54 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 105 11/09/22 20:54 175-126
Toluene-d8 (Surr)103 11/09/22 20:54 164-132
Eurofins Pensacola
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Client Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Lab Sample ID: 400-228080-2Client Sample ID: D3
Matrix: WaterDate Collected: 10/27/22 08:15
Date Received: 10/31/22 08:41
Method: SM6200-B - Volatile Organic Compounds
RL MDL
<1.0 1.0 ug/L 11/10/22 02:06 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1-Trichloroethane
1.0 ug/L 11/10/22 02:06 1<1.01,1,2,2-Tetrachloroethane
1.0 ug/L 11/10/22 02:06 1<1.01,1,2-Trichloro-1,2,2-trifluoroethane
5.0 ug/L 11/10/22 02:06 1<5.01,1,2-Trichloroethane
1.0 ug/L 11/10/22 02:06 1<1.01,1-Dichloroethane
1.0 ug/L 11/10/22 02:06 1<1.01,1-Dichloroethene
1.0 ug/L 11/10/22 02:06 1<1.01,2,3-Trichlorobenzene
1.0 ug/L 11/10/22 02:06 1<1.01,2,4-Trichlorobenzene
1.0 ug/L 11/10/22 02:06 1<1.01,2,4-Trimethylbenzene
5.0 ug/L 11/10/22 02:06 1<5.01,2-Dibromo-3-Chloropropane
1.0 ug/L 11/10/22 02:06 1<1.01,2-Dichlorobenzene
1.0 ug/L 11/10/22 02:06 1<1.01,2-Dichloroethane
1.0 ug/L 11/10/22 02:06 1<1.01,2-Dichloropropane
1.0 ug/L 11/10/22 02:06 1<1.01,3,5-Trimethylbenzene
1.0 ug/L 11/10/22 02:06 1<1.01,3-Dichlorobenzene
1.0 ug/L 11/10/22 02:06 1<1.01,4-Dichlorobenzene
25 ug/L 11/10/22 02:06 1<252-Butanone (MEK)
25 ug/L 11/10/22 02:06 1<252-Hexanone
25 ug/L 11/10/22 02:06 1<254-Methyl-2-pentanone (MIBK)
25 ug/L 11/10/22 02:06 1<25Acetone
1.0 ug/L 11/10/22 02:06 1<1.0Benzene
5.0 ug/L 11/10/22 02:06 1<5.0Bromoform
1.0 ug/L 11/10/22 02:06 1<1.0 *+Bromomethane
1.0 ug/L 11/10/22 02:06 1<1.0Carbon disulfide
1.0 ug/L 11/10/22 02:06 1<1.0Carbon tetrachloride
1.0 ug/L 11/10/22 02:06 1<1.0Chlorobenzene
1.0 ug/L 11/10/22 02:06 1<1.0Chlorobromomethane
1.0 ug/L 11/10/22 02:06 1<1.0Chlorodibromomethane
1.0 ug/L 11/10/22 02:06 1<1.0Chloroethane
1.0 ug/L 11/10/22 02:06 1<1.0Chloroform
1.0 ug/L 11/10/22 02:06 1<1.0Chloromethane
1.0 ug/L 11/10/22 02:06 1<1.0cis-1,2-Dichloroethene
5.0 ug/L 11/10/22 02:06 1<5.0cis-1,3-Dichloropropene
5.0 ug/L 11/10/22 02:06 1<5.0Dibromomethane
1.0 ug/L 11/10/22 02:06 1<1.0Dichlorobromomethane
1.0 ug/L 11/10/22 02:06 1<1.0Dichlorodifluoromethane
1.0 ug/L 11/10/22 02:06 1<1.0Ethylbenzene
1.0 ug/L 11/10/22 02:06 1<1.0Ethylene Dibromide
1.0 ug/L 11/10/22 02:06 1<1.0Methyl tert-butyl ether
5.0 ug/L 11/10/22 02:06 1<5.0Methylene Chloride
5.0 ug/L 11/10/22 02:06 1<5.0m-Xylene & p-Xylene
5.0 ug/L 11/10/22 02:06 1<5.0Naphthalene
5.0 ug/L 11/10/22 02:06 1<5.0o-Xylene
1.0 ug/L 11/10/22 02:06 1<1.0Styrene
1.0 ug/L 11/10/22 02:06 1<1.0Tetrachloroethene
1.0 ug/L 11/10/22 02:06 1<1.0Toluene
1.0 ug/L 11/10/22 02:06 1<1.0Trichloroethene
1.0 ug/L 11/10/22 02:06 1<1.0Trichlorofluoromethane
1.0 ug/L 11/10/22 02:06 1<1.0Vinyl chloride
Eurofins Pensacola
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Client Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Lab Sample ID: 400-228080-2Client Sample ID: D3
Matrix: WaterDate Collected: 10/27/22 08:15
Date Received: 10/31/22 08:41
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
<10 10 ug/L 11/10/22 02:06 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Xylenes, Total
1.0 ug/L 11/10/22 02:06 1<1.0Isopropyl ether
4-Bromofluorobenzene 90 72-119 11/10/22 02:06 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 104 11/10/22 02:06 175-126
Toluene-d8 (Surr)99 11/10/22 02:06 164-132
Eurofins Pensacola
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Client Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Lab Sample ID: 400-228080-3Client Sample ID: D1
Matrix: WaterDate Collected: 10/27/22 08:20
Date Received: 10/31/22 08:41
Method: EPA-DW 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
RL MDL
0.35 0.021 ug/L 11/04/22 14:48 11/04/22 20:27 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylene Dibromide
4-Bromofluorobenzene 83 56-150 11/04/22 14:48 11/04/22 20:27 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: EPA-DW 504.1 - EDB, DBCP and 1,2,3-TCP (GC) - RA
RL MDL
0.30 H 0.021 ug/L 11/04/22 14:48 11/09/22 09:19 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylene Dibromide
4-Bromofluorobenzene 76 56-150 11/04/22 14:48 11/09/22 09:19 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Eurofins Pensacola
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Client Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Lab Sample ID: 400-228080-4Client Sample ID: D3
Matrix: WaterDate Collected: 10/27/22 08:25
Date Received: 10/31/22 08:41
Method: EPA-DW 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
RL MDL
<0.021 0.021 ug/L 11/04/22 14:48 11/04/22 20:48 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Ethylene Dibromide
4-Bromofluorobenzene 89 56-150 11/04/22 14:48 11/04/22 20:48 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Eurofins Pensacola
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Surrogate Summary
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method: SM6200-B - Volatile Organic Compounds
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (72-119)(75-126)(64-132)
BFB DBFM TOL
93 105 103400-228080-1
Percent Surrogate Recovery (Acceptance Limits)
D1
91 103 100400-228080-1 MS D1
93 104 96400-228080-1 MSD D1
90 104 99400-228080-2 D3
94 101 99LCS 400-599983/1002 Lab Control Sample
94 103 102MB 400-599983/4 Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (56-150)
BFB2
83400-228080-3
Percent Surrogate Recovery (Acceptance Limits)
D1
76400-228080-3 - RA D1
89400-228080-4 D3
86LCS 400-599301/2-A Lab Control Sample
96LCSD 400-599301/3-A Lab Control Sample Dup
73MB 400-599301/1-A Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
Eurofins Pensacola
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Definitions/Glossary
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Qualifiers
GC/MS VOA
Qualifier Description
*+LCS and/or LCSD is outside acceptance limits, high biased.
Qualifier
F1 MS and/or MSD recovery exceeds control limits.
GC Semi VOA
Qualifier Description
H Sample was prepped or analyzed beyond the specified holding time
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins Pensacola
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QC Association Summary
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
GC/MS VOA
Analysis Batch: 599983
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM6200-B400-228080-1 D1 Total/NA
Water SM6200-B400-228080-2 D3 Total/NA
Water SM6200-BMB 400-599983/4 Method Blank Total/NA
Water SM6200-BLCS 400-599983/1002 Lab Control Sample Total/NA
Water SM6200-B400-228080-1 MS D1 Total/NA
Water SM6200-B400-228080-1 MSD D1 Total/NA
GC Semi VOA
Prep Batch: 599301
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 504.1400-228080-3 D1 Total/NA
Water 504.1400-228080-3 - RA D1 Total/NA
Water 504.1400-228080-4 D3 Total/NA
Water 504.1MB 400-599301/1-A Method Blank Total/NA
Water 504.1LCS 400-599301/2-A Lab Control Sample Total/NA
Water 504.1LCSD 400-599301/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 599349
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 504.1 599301400-228080-3 D1 Total/NA
Water 504.1 599301400-228080-4 D3 Total/NA
Water 504.1 599301MB 400-599301/1-A Method Blank Total/NA
Water 504.1 599301LCS 400-599301/2-A Lab Control Sample Total/NA
Water 504.1 599301LCSD 400-599301/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 599836
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 504.1 599301400-228080-3 - RA D1 Total/NA
Eurofins Pensacola
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QC Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method: SM6200-B - Volatile Organic Compounds
Client Sample ID: Method BlankLab Sample ID: MB 400-599983/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
RL MDL
1,1,1-Trichloroethane <1.0 1.0 ug/L 11/09/22 18:49 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<1.0 1.0 ug/L 11/09/22 18:49 11,1,2,2-Tetrachloroethane
<1.0 1.0 ug/L 11/09/22 18:49 11,1,2-Trichloro-1,2,2-trifluoroethane
<5.0 5.0 ug/L 11/09/22 18:49 11,1,2-Trichloroethane
<1.0 1.0 ug/L 11/09/22 18:49 11,1-Dichloroethane
<1.0 1.0 ug/L 11/09/22 18:49 11,1-Dichloroethene
<1.0 1.0 ug/L 11/09/22 18:49 11,2,3-Trichlorobenzene
<1.0 1.0 ug/L 11/09/22 18:49 11,2,4-Trichlorobenzene
<1.0 1.0 ug/L 11/09/22 18:49 11,2,4-Trimethylbenzene
<5.0 5.0 ug/L 11/09/22 18:49 11,2-Dibromo-3-Chloropropane
<1.0 1.0 ug/L 11/09/22 18:49 11,2-Dichlorobenzene
<1.0 1.0 ug/L 11/09/22 18:49 11,2-Dichloroethane
<1.0 1.0 ug/L 11/09/22 18:49 11,2-Dichloropropane
<1.0 1.0 ug/L 11/09/22 18:49 11,3,5-Trimethylbenzene
<1.0 1.0 ug/L 11/09/22 18:49 11,3-Dichlorobenzene
<1.0 1.0 ug/L 11/09/22 18:49 11,4-Dichlorobenzene
<25 25 ug/L 11/09/22 18:49 12-Butanone (MEK)
<25 25 ug/L 11/09/22 18:49 12-Hexanone
<25 25 ug/L 11/09/22 18:49 14-Methyl-2-pentanone (MIBK)
<25 25 ug/L 11/09/22 18:49 1Acetone
<1.0 1.0 ug/L 11/09/22 18:49 1Benzene
<5.0 5.0 ug/L 11/09/22 18:49 1Bromoform
<1.0 1.0 ug/L 11/09/22 18:49 1Bromomethane
<1.0 1.0 ug/L 11/09/22 18:49 1Carbon disulfide
<1.0 1.0 ug/L 11/09/22 18:49 1Carbon tetrachloride
<1.0 1.0 ug/L 11/09/22 18:49 1Chlorobenzene
<1.0 1.0 ug/L 11/09/22 18:49 1Chlorobromomethane
<1.0 1.0 ug/L 11/09/22 18:49 1Chlorodibromomethane
<1.0 1.0 ug/L 11/09/22 18:49 1Chloroethane
<1.0 1.0 ug/L 11/09/22 18:49 1Chloroform
<1.0 1.0 ug/L 11/09/22 18:49 1Chloromethane
<1.0 1.0 ug/L 11/09/22 18:49 1cis-1,2-Dichloroethene
<5.0 5.0 ug/L 11/09/22 18:49 1cis-1,3-Dichloropropene
<5.0 5.0 ug/L 11/09/22 18:49 1Dibromomethane
<1.0 1.0 ug/L 11/09/22 18:49 1Dichlorobromomethane
<1.0 1.0 ug/L 11/09/22 18:49 1Dichlorodifluoromethane
<1.0 1.0 ug/L 11/09/22 18:49 1Ethylbenzene
<1.0 1.0 ug/L 11/09/22 18:49 1Ethylene Dibromide
<1.0 1.0 ug/L 11/09/22 18:49 1Methyl tert-butyl ether
<5.0 5.0 ug/L 11/09/22 18:49 1Methylene Chloride
<5.0 5.0 ug/L 11/09/22 18:49 1m-Xylene & p-Xylene
<5.0 5.0 ug/L 11/09/22 18:49 1Naphthalene
<5.0 5.0 ug/L 11/09/22 18:49 1o-Xylene
<1.0 1.0 ug/L 11/09/22 18:49 1Styrene
<1.0 1.0 ug/L 11/09/22 18:49 1Tetrachloroethene
<1.0 1.0 ug/L 11/09/22 18:49 1Toluene
<1.0 1.0 ug/L 11/09/22 18:49 1Trichloroethene
<1.0 1.0 ug/L 11/09/22 18:49 1Trichlorofluoromethane
Eurofins Pensacola
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QC Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-599983/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
RL MDL
Vinyl chloride <1.0 1.0 ug/L 11/09/22 18:49 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
<10 10 ug/L 11/09/22 18:49 1Xylenes, Total
<1.0 1.0 ug/L 11/09/22 18:49 1Isopropyl ether
4-Bromofluorobenzene 94 72-119 11/09/22 18:49 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
103 11/09/22 18:49 1Dibromofluoromethane75-126
102 11/09/22 18:49 1Toluene-d8 (Surr)64-132
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-599983/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
1,1,1-Trichloroethane 50.0 47.9 ug/L 96 68-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,2,2-Tetrachloroethane 50.0 46.1 ug/L 92 70-131
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
50.0 43.2 ug/L 86 60-139
1,1,2-Trichloroethane 50.0 46.9 ug/L 94 70-130
1,1-Dichloroethane 50.0 49.3 ug/L 99 70-130
1,1-Dichloroethene 50.0 44.1 ug/L 88 63-134
1,2,3-Trichlorobenzene 50.0 47.0 ug/L 94 60-138
1,2,4-Trichlorobenzene 50.0 46.0 ug/L 92 60-140
1,2,4-Trimethylbenzene 50.0 49.8 ug/L 100 70-130
1,2-Dibromo-3-Chloropropane 50.0 43.4 ug/L 87 54-135
1,2-Dichlorobenzene 50.0 49.3 ug/L 99 67-130
1,2-Dichloroethane 50.0 48.5 ug/L 97 69-130
1,2-Dichloropropane 50.0 47.8 ug/L 96 70-130
1,3,5-Trimethylbenzene 50.0 49.3 ug/L 99 69-130
1,3-Dichlorobenzene 50.0 49.8 ug/L 100 70-130
1,4-Dichlorobenzene 50.0 50.6 ug/L 101 70-130
2-Butanone (MEK)200 185 ug/L 93 61-145
2-Hexanone 200 228 ug/L 114 65-137
4-Methyl-2-pentanone (MIBK)200 226 ug/L 113 69-138
Acetone 200 243 ug/L 122 43-160
Benzene 50.0 46.6 ug/L 93 70-130
Bromoform 50.0 44.2 ug/L 88 57-140
Bromomethane 50.0 81.1 *+ug/L 162 10-160
Carbon disulfide 50.0 44.2 ug/L 88 61-137
Carbon tetrachloride 50.0 48.1 ug/L 96 61-137
Chlorobenzene 50.0 47.8 ug/L 96 70-130
Chlorobromomethane 50.0 45.5 ug/L 91 70-130
Chlorodibromomethane 50.0 44.6 ug/L 89 67-135
Chloroethane 50.0 42.7 ug/L 85 55-141
Chloroform 50.0 47.1 ug/L 94 69-130
Chloromethane 50.0 68.1 ug/L 136 58-137
cis-1,2-Dichloroethene 50.0 48.4 ug/L 97 68-130
cis-1,3-Dichloropropene 50.0 44.4 ug/L 89 69-132
Dibromomethane 50.0 44.6 ug/L 89 70-130
Eurofins Pensacola
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QC Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-599983/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
Dichlorobromomethane 50.0 46.0 ug/L 92 67-133
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Dichlorodifluoromethane 50.0 48.4 ug/L 97 41-146
Ethylbenzene 50.0 48.7 ug/L 97 70-130
Ethylene Dibromide 50.0 44.5 ug/L 89 70-130
Methyl tert-butyl ether 50.0 41.6 ug/L 83 66-130
Methylene Chloride 50.0 46.6 ug/L 93 66-135
m-Xylene & p-Xylene 50.0 48.6 ug/L 97 70-130
Naphthalene 50.0 43.1 ug/L 86 47-149
o-Xylene 50.0 47.4 ug/L 95 70-130
Styrene 50.0 48.4 ug/L 97 70-130
Tetrachloroethene 50.0 47.0 ug/L 94 65-130
Toluene 50.0 48.2 ug/L 96 70-130
Trichloroethene 50.0 46.2 ug/L 92 70-130
Trichlorofluoromethane 50.0 54.8 ug/L 110 65-138
Vinyl chloride 50.0 59.3 ug/L 119 59-136
Xylenes, Total 100 95.9 ug/L 96 70-130
Isopropyl ether 25.0 27.9 ug/L 112 64-132
4-Bromofluorobenzene 72 -119
Surrogate
94
LCS LCS
Qualifier Limits%Recovery
101Dibromofluoromethane 75 -126
99Toluene-d8 (Surr)64 -132
Client Sample ID: D1Lab Sample ID: 400-228080-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
1,1,1-Trichloroethane <1.0 50.0 40.4 ug/L 81 57-142
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
1,1,2,2-Tetrachloroethane <1.0 50.0 44.7 ug/L 89 66-135
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
<1.0 50.0 38.9 ug/L 78 55-150
1,1,2-Trichloroethane <5.0 50.0 42.5 ug/L 85 66-131
1,1-Dichloroethane <1.0 50.0 44.6 ug/L 89 61-144
1,1-Dichloroethene <1.0 50.0 40.4 ug/L 81 54-147
1,2,3-Trichlorobenzene <1.0 50.0 25.1 ug/L 50 43-145
1,2,4-Trichlorobenzene <1.0 50.0 21.3 ug/L 43 39-148
1,2,4-Trimethylbenzene <1.0 F1 50.0 19.5 F1 ug/L 39 50-139
1,2-Dibromo-3-Chloropropane <5.0 50.0 38.9 ug/L 78 45-135
1,2-Dichlorobenzene <1.0 50.0 26.8 ug/L 54 52-137
1,2-Dichloroethane <1.0 50.0 47.1 ug/L 94 60-141
1,2-Dichloropropane <1.0 50.0 41.2 ug/L 82 66-137
1,3,5-Trimethylbenzene <1.0 F1 50.0 18.8 F1 ug/L 38 52-135
1,3-Dichlorobenzene <1.0 F1 50.0 24.0 F1 ug/L 48 54-135
1,4-Dichlorobenzene <1.0 F1 50.0 24.2 F1 ug/L 48 53-135
2-Butanone (MEK)<25 200 181 ug/L 91 55-150
2-Hexanone <25 200 230 ug/L 115 65-140
4-Methyl-2-pentanone (MIBK)<25 200 242 ug/L 121 63-146
Acetone <25 200 213 ug/L 107 43-150
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QC Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: D1Lab Sample ID: 400-228080-1 MS
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
Benzene <1.0 50.0 38.3 ug/L 77 56-142
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
Bromoform <5.0 50.0 36.8 ug/L 74 50-140
Bromomethane <1.0 F1 *+50.0 90.5 F1 ug/L 181 10-150
Carbon disulfide <1.0 50.0 36.7 ug/L 73 48-150
Carbon tetrachloride <1.0 50.0 38.8 ug/L 78 55-145
Chlorobenzene <1.0 F1 50.0 28.9 F1 ug/L 58 64-130
Chlorobromomethane <1.0 50.0 45.0 ug/L 90 64-140
Chlorodibromomethane <1.0 50.0 38.5 ug/L 77 56-143
Chloroethane <1.0 50.0 40.0 ug/L 80 50-150
Chloroform 1.1 50.0 43.4 ug/L 85 60-141
Chloromethane <1.0 50.0 59.9 ug/L 120 49-148
cis-1,2-Dichloroethene <1.0 50.0 41.5 ug/L 83 59-143
cis-1,3-Dichloropropene <5.0 50.0 34.0 ug/L 68 57-140
Dibromomethane <5.0 50.0 42.6 ug/L 85 63-138
Dichlorobromomethane <1.0 50.0 40.5 ug/L 81 59-143
Dichlorodifluoromethane <1.0 50.0 47.4 ug/L 95 16-150
Ethylbenzene <1.0 F1 50.0 23.4 F1 ug/L 47 58-131
Ethylene Dibromide <1.0 50.0 39.0 ug/L 77 64-132
Methyl tert-butyl ether <1.0 50.0 42.9 ug/L 86 59-137
Methylene Chloride <5.0 50.0 44.0 ug/L 88 60-146
m-Xylene & p-Xylene <5.0 F1 50.0 22.5 F1 ug/L 45 57-130
Naphthalene <5.0 50.0 29.6 ug/L 59 25-150
o-Xylene <5.0 F1 50.0 23.7 F1 ug/L 47 61-130
Styrene <1.0 F1 50.0 26.4 F1 ug/L 53 58-131
Tetrachloroethene <1.0 F1 50.0 24.7 F1 ug/L 49 52-133
Toluene <1.0 F1 50.0 30.8 F1 ug/L 62 65-130
Trichloroethene <1.0 50.0 32.0 ug/L 64 64-136
Trichlorofluoromethane <1.0 50.0 55.2 ug/L 110 54-150
Vinyl chloride <1.0 50.0 56.8 ug/L 114 46-150
Xylenes, Total <10 F1 100 46.2 F1 ug/L 46 59-130
Isopropyl ether <1.0 25.0 27.1 ug/L 109 60-144
4-Bromofluorobenzene 72 -119
Surrogate
91
MS MS
Qualifier Limits%Recovery
103Dibromofluoromethane 75 -126
100Toluene-d8 (Surr)64 -132
Client Sample ID: D1Lab Sample ID: 400-228080-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
1,1,1-Trichloroethane <1.0 50.0 41.7 ug/L 83 57-142 3 30
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
1,1,2,2-Tetrachloroethane <1.0 50.0 44.1 ug/L 88 66-135 1 30
1,1,2-Trichloro-1,2,2-trifluoroetha
ne
<1.0 50.0 40.0 ug/L 80 55-150 3 30
1,1,2-Trichloroethane <5.0 50.0 42.2 ug/L 84 66-131 1 30
1,1-Dichloroethane <1.0 50.0 44.4 ug/L 89 61-144 0 30
1,1-Dichloroethene <1.0 50.0 40.7 ug/L 81 54-147 1 30
Eurofins Pensacola
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QC Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: D1Lab Sample ID: 400-228080-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
1,2,3-Trichlorobenzene <1.0 50.0 28.2 ug/L 56 43-145 11 30
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
1,2,4-Trichlorobenzene <1.0 50.0 25.2 ug/L 50 39-148 17 30
1,2,4-Trimethylbenzene <1.0 F1 50.0 24.3 F1 ug/L 49 50-139 22 30
1,2-Dibromo-3-Chloropropane <5.0 50.0 41.0 ug/L 82 45-135 5 30
1,2-Dichlorobenzene <1.0 50.0 30.1 ug/L 60 52-137 12 30
1,2-Dichloroethane <1.0 50.0 46.4 ug/L 93 60-141 1 30
1,2-Dichloropropane <1.0 50.0 43.8 ug/L 88 66-137 6 30
1,3,5-Trimethylbenzene <1.0 F1 50.0 23.7 F1 ug/L 47 52-135 23 30
1,3-Dichlorobenzene <1.0 F1 50.0 26.8 ug/L 54 54-135 11 30
1,4-Dichlorobenzene <1.0 F1 50.0 27.2 ug/L 54 53-135 12 30
2-Butanone (MEK)<25 200 177 ug/L 88 55-150 2 30
2-Hexanone <25 200 216 ug/L 108 65-140 6 30
4-Methyl-2-pentanone (MIBK)<25 200 233 ug/L 117 63-146 4 30
Acetone <25 200 198 ug/L 99 43-150 7 30
Benzene <1.0 50.0 39.7 ug/L 79 56-142 4 30
Bromoform <5.0 50.0 37.9 ug/L 76 50-140 3 30
Bromomethane <1.0 F1 *+50.0 91.9 F1 ug/L 184 10-150 2 50
Carbon disulfide <1.0 50.0 37.0 ug/L 74 48-150 1 30
Carbon tetrachloride <1.0 50.0 40.9 ug/L 82 55-145 5 30
Chlorobenzene <1.0 F1 50.0 30.6 F1 ug/L 61 64-130 6 30
Chlorobromomethane <1.0 50.0 43.6 ug/L 87 64-140 3 30
Chlorodibromomethane <1.0 50.0 39.9 ug/L 80 56-143 4 30
Chloroethane <1.0 50.0 43.2 ug/L 86 50-150 8 30
Chloroform 1.1 50.0 44.2 ug/L 86 60-141 2 30
Chloromethane <1.0 50.0 69.0 ug/L 138 49-148 14 31
cis-1,2-Dichloroethene <1.0 50.0 43.3 ug/L 87 59-143 4 30
cis-1,3-Dichloropropene <5.0 50.0 35.5 ug/L 71 57-140 4 30
Dibromomethane <5.0 50.0 41.1 ug/L 82 63-138 4 30
Dichlorobromomethane <1.0 50.0 41.0 ug/L 82 59-143 1 30
Dichlorodifluoromethane <1.0 50.0 51.8 ug/L 104 16-150 9 31
Ethylbenzene <1.0 F1 50.0 27.4 F1 ug/L 55 58-131 16 30
Ethylene Dibromide <1.0 50.0 39.1 ug/L 77 64-132 0 30
Methyl tert-butyl ether <1.0 50.0 43.0 ug/L 86 59-137 0 30
Methylene Chloride <5.0 50.0 43.5 ug/L 87 60-146 1 32
m-Xylene & p-Xylene <5.0 F1 50.0 26.0 F1 ug/L 52 57-130 15 30
Naphthalene <5.0 50.0 34.0 ug/L 68 25-150 14 30
o-Xylene <5.0 F1 50.0 27.1 F1 ug/L 54 61-130 13 30
Styrene <1.0 F1 50.0 28.6 F1 ug/L 57 58-131 8 30
Tetrachloroethene <1.0 F1 50.0 27.9 ug/L 56 52-133 12 30
Toluene <1.0 F1 50.0 33.5 ug/L 67 65-130 8 30
Trichloroethene <1.0 50.0 35.3 ug/L 71 64-136 10 30
Trichlorofluoromethane <1.0 50.0 56.1 ug/L 112 54-150 2 30
Vinyl chloride <1.0 50.0 61.3 ug/L 123 46-150 8 30
Xylenes, Total <10 F1 100 53.1 F1 ug/L 53 59-130 14 30
Isopropyl ether <1.0 25.0 28.5 ug/L 114 60-144 5 30
4-Bromofluorobenzene 72 -119
Surrogate
93
MSD MSD
Qualifier Limits%Recovery
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QC Sample Results
Job ID: 400-228080-1Client: North Carolina Dept of Env Quality
SDG: NC0150 TF#9615Project/Site: Wanda Mise
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: D1Lab Sample ID: 400-228080-1 MSD
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599983
Dibromofluoromethane 75 -126
Surrogate
104
MSD MSD
Qualifier Limits%Recovery
96Toluene-d8 (Surr)64 -132
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
Client Sample ID: Method BlankLab Sample ID: MB 400-599301/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599349 Prep Batch: 599301
RL MDL
Ethylene Dibromide <0.020 0.020 ug/L 11/04/22 14:48 11/04/22 19:05 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
4-Bromofluorobenzene 73 56-150 11/04/22 19:05 1
MB MB
Surrogate
11/04/22 14:48
Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-599301/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599349 Prep Batch: 599301
Ethylene Dibromide 0.101 0.112 ug/L 111 70-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
4-Bromofluorobenzene 56 -150
Surrogate
86
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-599301/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 599349 Prep Batch: 599301
Ethylene Dibromide 0.101 0.118 ug/L 118 70-130 6 10
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
4-Bromofluorobenzene 56 -150
Surrogate
96
LCSD LCSD
Qualifier Limits%Recovery
Eurofins Pensacola
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Lab Chronicle
Client: North Carolina Dept of Env Quality Job ID: 400-228080-1
Project/Site: Wanda Mise SDG: NC0150 TF#9615
Client Sample ID: D1 Lab Sample ID: 400-228080-1
Matrix: WaterDate Collected: 10/27/22 08:10
Date Received: 10/31/22 08:41
Analysis SM6200-B AGW11/09/22 20:541 EET PEN599983
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: D3 Lab Sample ID: 400-228080-2
Matrix: WaterDate Collected: 10/27/22 08:15
Date Received: 10/31/22 08:41
Analysis SM6200-B AGW11/10/22 02:061 EET PEN599983
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: D1 Lab Sample ID: 400-228080-3
Matrix: WaterDate Collected: 10/27/22 08:20
Date Received: 10/31/22 08:41
Prep 504.1 JAW11/04/22 14:48 EET PEN599301
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 33.5 mL 35 mL
Analysis 504.1 1 599349 11/04/22 20:27 JAW EET PENTotal/NA
Prep 504.1 RA 599301 11/04/22 14:48 JAW EET PENTotal/NA 33.5 mL 35 mL
Analysis 504.1 RA 1 599836 11/09/22 09:19 DS EET PENTotal/NA
Client Sample ID: D3 Lab Sample ID: 400-228080-4
Matrix: WaterDate Collected: 10/27/22 08:25
Date Received: 10/31/22 08:41
Prep 504.1 JAW11/04/22 14:48 EET PEN599301
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 33.8 mL 35 mL
Analysis 504.1 1 599349 11/04/22 20:48 JAW EET PENTotal/NA
Client Sample ID: Method Blank Lab Sample ID: MB 400-599301/1-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 JAW11/04/22 14:48 EET PEN599301
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 599349 11/04/22 19:05 JAW EET PENTotal/NA
Client Sample ID: Method Blank Lab Sample ID: MB 400-599983/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW11/09/22 18:491 EET PEN599983
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Eurofins Pensacola
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Lab Chronicle
Client: North Carolina Dept of Env Quality Job ID: 400-228080-1
Project/Site: Wanda Mise SDG: NC0150 TF#9615
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-599301/2-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 JAW11/04/22 14:48 EET PEN599301
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 599349 11/04/22 19:25 JAW EET PENTotal/NA
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-599983/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW11/09/22 17:541 EET PEN599983
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-599301/3-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 JAW11/04/22 14:48 EET PEN599301
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 599349 11/04/22 19:46 JAW EET PENTotal/NA
Client Sample ID: D1 Lab Sample ID: 400-228080-1 MS
Matrix: WaterDate Collected: 10/27/22 08:10
Date Received: 10/31/22 08:41
Analysis SM6200-B AGW11/09/22 21:561 EET PEN599983
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: D1 Lab Sample ID: 400-228080-1 MSD
Matrix: WaterDate Collected: 10/27/22 08:10
Date Received: 10/31/22 08:41
Analysis SM6200-B AGW11/09/22 22:171 EET PEN599983
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
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Accreditation/Certification Summary
Client: North Carolina Dept of Env Quality Job ID: 400-228080-1
Project/Site: Wanda Mise SDG: NC0150 TF#9615
Laboratory: Eurofins Pensacola
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 314 12-31-22
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which
the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
SM6200-B Water 1,1,2-Trichloro-1,2,2-trifluoroethane
SM6200-B Water 2-Butanone (MEK)
SM6200-B Water 2-Hexanone
SM6200-B Water 4-Methyl-2-pentanone (MIBK)
SM6200-B Water Acetone
SM6200-B Water Carbon disulfide
Eurofins Pensacola
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Login Sample Receipt Checklist
Client: North Carolina Dept of Env Quality Job Number: 400-228080-1
SDG Number: NC0150 TF#9615
Login Number: 228080
Question Answer Comment
Creator: Roberts, Alexis J
List Source: Eurofins Pensacola
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
N/AThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.5.5°C IR8
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.No date on COC, logged in per container labels.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Pensacola
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