WS-6406_24174_CA_RMR_20120524

ACTIVE REMEDIATION MONITORING REPORT

FORMER CARAWAY GROCERY
3419 OLD LEXINGTON ROAD
ASHEBORO, RANDOLPH COUNTY, NORTH CAROLINA
INCIDENT NO. 24174

Prepared For:

North Carolina Department of Environment and Natural Resources
UST Section
1637 Mail Service Center
Raleigh, North Carolina 27699-1637

Prepared By:

Progress Environmental, Inc.
P.O. Box 5884
Winston-Salem, North Carolina 27113

Progress Project 151178.003

May 24, 2012

TABLE OF CONTENTS

1. BACKGROUND INFORMATION ........................................................................................1
2. FIELD ACTIVITIES................................................................................................................4
3. LABORATORY RESULTS.....................................................................................................5
4. CONCLUSIONS.......................................................................................................................6
5. RECOMMENDATIONS..........................................................................................................7
6. QUALIFICATIONS OF REPORT.........................................................................................7

FIGURES
Figure 1 – Topographic Site Map
Figure 2 – Site Location Map
Figure 3 – Monitoring Well Location Map
Figure 4 – Benzene Isoconcentration Map
Figure 5 – Total BTEX Isoconcentration Map
Figure 6 – Groundwater Flow Direction Map
TABLE
Table 1 – Summary of Groundwater Anayltical Results
Table 2 – Monitoring Well Construction Information
Table 3A – MMPE Results
Table 3B – MMPE Results
APPENDIX
Groundwater Sampling Sheets
Laboratory Data Sheets and Chain-of-Custody Record

Former Caraway Grocery
Asheboro, Randolph County, North Carolina
Progress Project No. 151178.003
May 24, 2012

1
1. BACKGROUND INFORMATION

The site is the former Caraway Grocery located at 3419 Old Lexington Road in Asheboro, Randolph
County, North Carolina. The site is located in a rural area, sparsely developed with residential properties
along Old Lexington Road (Figures 1 and 2). Progress was provided with the following historical report
regarding the site:

• Comprehensive Site Assessment prepared by Pyramid Environmental and Engineering, P.C. and
dated November 11, 2010.

In 2002, Pyramid was contracted to complete a Phase II Limited Site Assessment at the subject property.
Pyramid reviewed available records at the Randolph County Tax Department and interviewed Ms.
Dorothy Dougan Fagge, former co-owner of the property, Mr. Phillip Poole, owner of Econo Oil
Company, and Larry Furr, owner of Mitchell Oil Company. Based on the information obtained from the
Randolph Tax Department, the existing building was constructed in approximately 1910 and was
historically operated as a country store. Ms. Dorothy Dougan Fagge and her sister, Mrs. Frances Dougan
Steere inherited the property from their parents.

According to Ms. Fagge, her uncle, Wade Dougan, operated the store between the 1920s and the 1940s
and installed two gasoline underground storage tanks (USTs), and possibly a kerosene UST. The two
gasoline USTs were found with a Geoprobe® and were located on the eastern and western sides of the
pump island. Ms. Fagge remembered an old, glass top kerosene pump near the current kerosene above
ground tank (AST) that was later installed; however, she did not remember a kerosene AST at the site
prior to the current AST. An old vent pipe was observed on the side of the building near the former
kerosene pump. The former kerosene pump was reportedly removed shortly after the death of Mr. Wade
Dougan. Mr. Wade Dougan operated the store until 1973, when he passed away. The petroleum sold by
Mr. Dougan was reportedly supplied by Herlocker Oil Company.

In the 1980s, Ms. Fagge agreed to rent the store to Mr. Carl Robbins. Mr. Robbins contracted Econo Oil
Company to install two additional 2,000-gallon gasoline USTs and one 550-gallon kerosene AST and a
kerosene pump. The store was called Caraway Grocery and operated under UST Facility ID number of 0-
018181. Econo Oil was the owner/operator of the USTs. In January 1993, Econo Oil Company sold the
two 2,000-gallon gasoline USTs to Mr. Randall Williams, who was listed in the NCDENR records as the
owner/operator of the USTs. Mr. Williams and Mr. Robbins continued to operate the store as a service
station. Mr. Robbins was supplied two shipments of petroleum by Mitchell Oil Company in 1993, after
which the store no longer sold petroleum. After Mr. Robbins’ ownership ended, the store was used for
video rental and no longer operated as a service station. According to Ms. Fagge, Mr. Robbins also
installed a car ramp to the west of the building and provided oil changes. According to Ms. Fagge, Mr.
Robbins utilized the pump island underneath the canopy for his gasoline pumps. The former gasoline
pumps were removed in the mid 1990s.

In 2002, Ms. Fagge lived approximately 350 feet southeast of the store in the house formerly owned by
her grandparents. According to Ms. Fagge, the water-supply well at the house became contaminated in
the 1950s or 1960s and was no longer potable. The water was reportedly tested at that time and
determined to contain gasoline related compounds. During Pyramid’s initial site visit, a water level
indicator was lowered into the water-supply well behind Ms. Fagge's house and did not encounter water
prior to the water level meter reaching the bottom of the well at a depth of 36 feet below land surface
(bls). There are no known underground sources of petroleum near the house, other than Caraway
Former Caraway Grocery
Asheboro, Randolph County, North Carolina
Progress Project No. 151178.003
May 24, 2012

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Grocery. The house was later connected to the water-supply well on the property directly southeast of the
house. The store does not currently have a water-supply well. Mr. Wade Dougan reportedly had a water
tank that collected rain runoff from the roof and supplied water to the spigot located beside the kerosene
AST.

On March 12, 2002, Pyramid drilled eleven borings (GP1 through GP11) at the subject site to assess soil
conditions and collect soil samples for laboratory analysis. The laboratory results for the soil samples
collected from GP1 and GP3 indicated total petroleum hydrocarbons (TPH) concentrations for gasoline
and diesel were below their respective detection limits of <1.0 mg/kg for gasoline and 10 mg/kg for
diesel. The results for the soil sample collected from GP4 indicated a TPH gasoline concentration of 190
mg/kg and a TPH diesel concentration of 1,800 mg/kg. The high diesel TPH concentration was
reportedly due to a kerosene release. The results for the soil sample collected from GP7 indicated a TPH
gasoline concentration of 1,100 mg/kg and a TPH diesel concentration of 580 mg/kg. The results for the
soil samples collected from GP8 and GP11 indicated TPH gasoline at concentrations ranging from 29
mg/kg to 330 mg/kg, and TPH diesel at concentrations ranging from 170 mg/kg to 280 mg/kg.

In October 2008, Terraine drilled two soil borings at the site that were converted to groundwater
monitoring wells (MW-1 & MW-2). The laboratory results of groundwater samples collected from the
monitoring wells indicated that some of the targeted petroleum compounds (benzene, toluene,
ethylbenzene, total xylenes, naphthalene, and n-propylbenzene) were detected at concentrations that
exceeded their respective North Carolina 2L Groundwater Quality Standards.

In March 2010, Pyramid supervised the closure of five (5) underground storage tanks, associated product
lines, and pump islands at the former Caraway Grocery site. The UST system included two 2,000-gallon
gasoline, one 275-gallon gasoline, one 625-gallon gasoline, and one 270-gallon kerosene tanks. Please
note, the two 2,000-gallon gasoline tanks were the only tanks that were registered with the North
Carolina Department of Environment and Natural Resources (NCDENR) UST Section. The three
additional unregistered USTs were likely installed in the 1920s and taken out of service prior to 1985.

The laboratory results of post-excavation soil samples collected from each excavation indicate the
presence of targeted compounds at concentrations that exceed their respective Soil-to-Groundwater
Maximum Soil Contaminant Concentrations (MSCCs). Two of the 20 post-excavation soil samples (T4E-
1 and T5E-3) contained concentrations of petroleum-related compounds that exceeded their respective
Residential MSCCs. Sample T4E-1 was collected from the Tank #4 excavation on the sidewall nearest
the existing canopy at a depth of 11 feet bls. T4E-1 contained concentrations of C5-C8 and C9-C12
aliphatics that exceed their respective residential MSCCs. Sample T5E-3 was collected from the Tank #5
excavation on the sidewall nearest the existing building. T5E-3 contained concentrations of C9-22
aromatics that exceed its residential MSCCs. In both cases, the soil samples were collected from
locations where the excavation was limited by the existing structure. The excavations at Tank #4 and #5
had been extended as close as possible to the building before the samples were collected. The manhole
covers for monitoring wells MW-1 and MW-2 were damaged during the UST and contaminated soil
removal activities performed in February 2010.

Based on the findings of the UST assessment work, the NCDENR required the completion of a
Comprehensive Site Assessment (CSA) for the site. Pyramid submitted a CSA dated November 11, 2010
to the NCDENR and based on the findings of the CSA recommended in-situ chemical remediation based
on the presence of the on-site structure and shallow depth to bedrock. On June 23-25, 2010 and then
again on August 12, 2010, Pyramid installed a total of fifteen two-inch diameter, Type-II groundwater
Former Caraway Grocery
Asheboro, Randolph County, North Carolina
Progress Project No. 151178.003
May 24, 2012

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monitoring wells (VE-1, MW-1A, MW-3 through MW-15) on the subject and neighboring property. The
wells were advanced to depths ranging from 30 feet to 35 feet bls. The one deep well (VE-1) has a total
depth of 74 feet. The soil borings advanced to install the monitoring wells were completed using a truck-
mounted air hammer drill rig. The monitoring wells were constructed using two-inch diameter, schedule-
40 PVC pipe. The lower 20 feet was constructed using 0.010-inch PVC slotted screen. The highest
concentrations of the petroleum-related compounds were detected in the vicinity of the former UST
excavation. None of the targeted petroleum-related compounds was detected above laboratory detection
limits in the groundwater sample collected from the up-gradient monitoring well (MW-6) or the
groundwater samples collected from the monitoring wells (MW-7, 10, 11, 13 and 15). This shows that
the horizontal extent of the groundwater contamination has been reasonably defined. The laboratory
results for this sampling event detected benzene concentrations ranging from below reporting limit
(BRL) to 3,520 µg/l in the groundwater sample collected from monitoring well MW-1A. No petroleum-
related compounds were detected in the water-supply well samples.

From June 20 through 23, 2011 Progress and Stewart’s Grading and Hauling (Stewart’s) were on-site to
excavate trenches for use as an infiltration gallery using PermeOx® Plus as previously proposed by
Pyramid Environmental and Engineering, P.C. Based on obvious odors in the soil excavated from the
trenches, Progress properly disposed of 321.24 tons impacted soil at the Cunningham Brick facility in
Lexington, North Carolina. Approximately 6,800 pounds of PermeOx® Plus was placed into the base of
the trenches and mixed using the track-mounted excavator. Approximately 3,000 gallons of potable water
was used to hydrate the PermeOx® Plus (Progress Project 151178.001, report dated July 12, 2011).

Progress previously completed an Active Remediation Monitoring Report (Progress Project 151178.002,
report dated October 4, 2011). Laboratory analysis of the groundwater samples collected from
monitoring wells MW-1A through MW-5, MW-8, MW-9, MW-12, and VE-1 detected targeted
compounds above their respective NC2LGWQS. Laboratory analysis of the groundwater samples
collected from monitoring wells MW-6, MW-7, MW-10, MW-11, and MW-13 through MW-15 did not
detect targeted compounds above their respective NC2LGWQS. Based on review of the laboratory data,
the groundwater concentrations have generally decreased near the source area and within the immediate
vicinity of the infiltration gallery. Specifically, Progress calculated the percentage change in the Total
BTEX concentrations detected in the groundwater samples collected most recently from the monitoring
wells. Groundwater samples collected from monitoring wells MW-1A (53%), MW-2 (85%), MW-3
(4%), MW-4 (65%), MW-5 (59%), MW-9 (99.68%), MW-14 (100%), and VE-1 (100%) have
demonstrated Total BTEX concentration reductions since a previous sampling event conducted in July
2010. Monitoring wells located outside of the immediate area of the infiltration gallery have exhibited
increases in targeted compounds since the 2010 sampling events. Specifically, groundwater samples
collected from monitoring wells MW-8 (42%) and MW-12 (124%) have demonstrated increases since the
2010 sampling events. Progress considers the fluctuations in the groundwater concentrations detected in
groundwater samples collected from the monitoring wells may be attributed to one or more of the
following: the excavation and removal of the UST systems (primary source); the excavation and off-site
disposal of identified soil contamination (secondary source), the use of PermeOx® Plus within the
infiltration gallery; the placement of approximately 3,000 gallons of water in the infiltration gallery to
hydrate and mobilize the Permeox Plus; and the natural migration of groundwater beneath the site.

Former Caraway Grocery
Asheboro, Randolph County, North Carolina
Progress Project No. 151178.003
May 24, 2012

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Site Geology and Hydrogeology

According to the Geologic Map of North Carolina, the subject site is located in the Carolina Slate Belt of
the Piedmont Physiographic Province of North Carolina. The site is located in an area underlain by rocks
composed of metasedimentary rocks. In the Piedmont Physiographic Province, groundwater generally
occurs under water-table conditions and is stored in the pore space between individual grains of residual
soil and in the fractures within the underlying parent rock. Due to the intense shearing associated with
the thrust faulting in the area, it can be expected that the fractures play a major role in the flow of
groundwater in the subsurface.

Recharge to the water table is primarily by precipitation infiltrating the upper soils and percolating
downward, under the influence of gravity, to the groundwater table. Typically, the water table is not a
level surface, but a subdued reflection of the land surface. However, the depth to the water table is not
constant, and depends on many factors, which include the amount of rainfall, the permeability of the soil,
and the amount of groundwater being pumped in the area.

Groundwater generally flows in directions sub-parallel to the ground surface slopes and under the
influence of gravity toward points of discharge such as creeks, swamps, drainage swales, or pumped
groundwater wells. Based on topographic inference, groundwater beneath the site most likely flows to
the south toward Back Creek (Figure 1).

2. FIELD ACTIVITIES

Mobile Multi-Phase Extraction (MMPE)

Progress completed an initial 96-hour MMPE event at the site. The MMPE event was completed from
April 2 through April 6, 2012. Impacted groundwater was extracted from monitoring wells MW-1, MW-
4, and MW-12 during this event. This event extracted approximately 5,690 gallons of impacted
groundwater and 162.129 pounds or 24.94 gallons of petroleum product as vapor.

Monitoring Well Sampling
Progress returned to the site on May 4, 2012 to sample the existing monitoring wells MW-1A through
MW-15, and VE-1. Prior to sampling, a static water level measurement was collected from the on-site
monitoring wells to determine the existing well volumes. The water meter was decontaminated prior to
use and in-between wells by washing in a solution of Alconox detergent and deionized water followed by
a rinse with deionized water. The monitoring wells were then purged by evacuating at least three well
volumes using a new disposable bailer dedicated to the well. To further demonstrate that the wells were
sufficiently purged, Progress continued to purge the wells until the following geochemical field
measurements had stabilized; temperature, and pH. Progress utilized an Oakton ph/CON 10 Series for pH
and conductivity calibrated using the manufacturers’ recommendations. Copies of the monitoring well
sampling sheets used during the field activities to document well volumes, geochemical testing and other
pertinent information are included in the Appendix.
Following purging, a groundwater sample was collected from the monitoring wells using disposable
bailers. Care was taken to minimize volatilization of the samples during the sampling process.
Immediately after collection, the groundwater samples were decanted into sample containers provided by
the laboratory. The groundwater samples were analyzed for volatile organic compounds (VOCs) by
Standard Method 6200B, for ethylene dibromide (EDB) using EPA Method 504.1, and for volatile
Former Caraway Grocery
Asheboro, Randolph County, North Carolina
Progress Project No. 151178.003
May 24, 2012

5
petroleum hydrocarbons using the Massachusetts Department of Environmental Protection (MADEP)
Method. The sample containers were labeled with the project name, sample location, and the date and
time the sample was collected. The samples were placed in a cooler containing ice to maintain the
samples at four degrees Celsius and was picked up by Pace Analytical Services (Pace) personnel and
picked up at the Progress Environmental, Inc. office and transported under chain-of-custody to their
facility in Huntersville, North Carolina for chemical analysis. Proper chain-of-custody (COC) procedures
were maintained throughout the sample collection and transportation process. A copy of the COC is
included in the Appendix.

The relative elevation of the top of each well casing (MW1A through MW-15, and VE-1) was measured
to the nearest 0.01 feet using a level and rod by Pyramid. The elevations were measured relative to an
arbitrary benchmark, which was assigned an elevation of 100 feet. The relative elevation of the top of
casing for each well and the measurement of the depth to groundwater surface from the top of the well
casing were used to determine the relative elevation of groundwater at each well location (Table 2). The
groundwater elevations collected on May 4, 2012 were used to prepare a groundwater contour map of the
site (Groundwater Flow Direction Map, Figure 6). Based on our interpretation of the groundwater flow
direction beneath the site, groundwater flows generally to the east-southeast beneath the site.

3. LABORATORY RESULTS

The results of the laboratory testing indicated the following:

• Laboratory analysis of the groundwater samples collected from monitoring wells MW-6, MW-7,
MW-8, MW-10, MW-11, MW-13, and MW-14 did not detect targeted compounds above their
respective NC2LGWQS.

• Laboratory analysis of the groundwater samples collected from monitoring well MW-1A
detected benzene, 1,2-dichloroethane, ethylbenzene, isopropylbenzene, naphthalene, n-
propylbenzene, MTBE, toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, total xylenes,
EDB, C5-C8 Aliphatics, C9-C12 Aliphatics, and C9-C10 Aromatics at concentrations exceeding
their respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well MW-2 detected
benzene and 1,2-dichloroethane concentrations exceeding their respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well MW-3 detected
benzene, 1,2-dichloroethane, C5-C8 Aliphatics, C9-C12 Aliphatics, and C9-C10 Aromatics at
concentrations exceeding their respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well MW-4 detected
benzene, 1,2-dichloroethane, ethylbenzene, isopropylbenzene, naphthalene, n-propylbenzene,
MTBE, toluene, 1,2,4-trimethylbenzene, total xylenes, EDB, C5-C8 Aliphatics, C9-C12
Aliphatics, and C9-C10 Aromatics at concentrations exceeding their respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well MW-5 detected
benzene, 1,2-dichloroethane, ethylbenzene, naphthalene, n-propylbenzene, toluene, 1,2,4-
trimethylbenzene, total xylenes, EDB, C5-C8 Aliphatics, C9-C12 Aliphatics, and C9-C10
Aromatics at concentrations exceeding their respective NC2LGWQS.
Former Caraway Grocery
Asheboro, Randolph County, North Carolina
Progress Project No. 151178.003
May 24, 2012

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• Laboratory analysis of the groundwater sample collected from monitoring well MW-9 detected
benzene and C5-C8 Aliphatics, at concentrations exceeding their respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well MW-12 detected
benzene, 1,2-dichloroethane, di-isopropyl ether, ethylbenzene, 2-hexanone, naphthalene, toluene,
total xylenes, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene EDB, C5-C8 Aliphatics, C9-C12
Aliphatics, and C9-C10 Aromatics at concentrations exceeding their respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well MW-15 detected
C5-C8 Aliphatics, C9-C12 Aliphatics, and C9-C10 Aromatics at concentrations exceeding their
respective NC2LGWQS.

• Laboratory analysis of the groundwater sample collected from monitoring well VE-1 detected
1,2-dichloroethane and MTBE at concentrations exceeding their respective NC2LGWQS.

A summary of the laboratory results is included in Table 1. Monitoring well construction information is
included as Table 2. A benzene isoconcentation map is included as Figure 4. A total BTEX
isoconcentration map is included as Figure 5. A groundwater flow direction map is included as Figure 6.
A copy of the groundwater monitoring well sampling data sheets, laboratory data sheets and chain-of-
custody records are included in the Appendix.

4. CONCLUSIONS

Based on the results of the assessment, Progress concludes the following:

• Progress completed a 96-hour MMPE event at the site. The MMPE event was completed from
April 2 through April 6, 2012. Impacted groundwater was extracted from monitoring wells MW-
1, MW-4, and MW-12 during this event. This event extracted approximately 5,690 gallons of
impacted groundwater and 162.129 pounds or 24.94 gallons of petroleum product as vapor.

• Laboratory analysis of the groundwater samples collected from monitoring wells MW-6, MW-7,
MW-8, MW-10, MW-11, MW-13, and MW-14 did not detect targeted compounds above their
respective NC2LGWQS.

• Laboratory analysis of the groundwater samples collected from monitoring wells MW-1A
through MW-5, MW-9, MW-12, MW-15, and VE-1 detected one or more petroleum-related
compounds at concentrations exceeding their respective NC2LGWQS.

• Based on review of the most recent laboratory data, Progress evaluated the effectiveness of the
remedial actions completed at the site. Groundwater samples collected from monitoring wells
MW-1A, MW-2, MW-3, MW-4, MW-12, and MW-15 have demonstrated Total BTEX
concentration increases since the implementing the remedial actions. Groundwater samples
collected from monitoring wells MW-5, MW-8, MW-9, MW-14, and VE-1 have demonstrated
Total BTEX concentration decreases since the implementing the remedial actions.

Former Caraway Grocery
Asheboro, Randolph County, North Carolina
Progress Project No. 151178.003
May 24, 2012

7
• It is Progress’ opinion that the increase in contaminant concentrations in groundwater samples
collected from monitoring wells outside the immediate source area indicate that the placement
and subsequent hydration of the Permeox Plus® has likely mobilized petroleum-related
contaminants adhered to the soil into the groundwater which have migrated with the natural flow
of groundwater beneath the site.

• Eleven active and one inactive water-supply wells were previously identified by others within
1,000 feet of the source area and municipal water is not available in the vicinity of the site.
Based on the presence of known water-supply wells in the vicinity of the site, the site has been
ranked as High Risk. In an effort to achieve regulatory closure for the site, it will be required
that the compounds detected in the groundwater be reduced to the below the NC2LGWQS or the
water-supply wells be properly closed. Municipal water is currently not available in the vicinity
of the site.

5. RECOMMENDATIONS

Because Progress has utilized the chemical in-situ remediation product PermeOx Plus®, Progress
recommends the following:

• Continuing to monitor the groundwater quarterly to document the long-term effect of the
remedial activities on the petroleum-related compounds detected in the groundwater; and

• Completing additional MMPE events at the site using monitoring wells located within the source
area as extraction wells, including monitoring wells MW-1A through MW-5 and MW-12.

6. QUALIFICATIONS OF REPORT

The activities and evaluative approaches used in this assessment are consistent with those normally
employed in hydrogeolgic projects of this type. Our evaluation of site conditions has been based on our
understanding of the site project information and the data obtained during our field activities.

FIGURES

Figure 1
Topographic Site Map

Former Caraway Grocery
3419 Old Lexington Road
Asheboro, North Carolina

Project: Fmr. Caraway Groc.
Client: NCDENR
Progress Job #: 151178.003
P.O. Box 5884
Winston-Salem, NC 27113
Telephone: [phone]
Fax: [phone]
www.progressenvironmental.com

USGS
7.5 Minute Series Topographic Map
Contour Interval: 10 feet
Scale: 1”=2000’
Farmer, N.C.
Date: 1994
Asheboro, N.C.
Date: 1994 Date: May 2012

SITE
Site
0'500'GRAPHIC SCALE500'1,000'1" = 500'ProgressENVIRONMENTAL, INC.JTB151178.003MAY 2012JTRSHOWNMAY 2012Figure 2.SKFP.O. Box 5884WINSTON-SALEM, NORTH CAROLINA 27113PHONE [phone] FAX [phone]FIGURE 2SITE LOCATION MAPFORMER CARAWAY GROCERY3419 OLD LEXINGTON ROADASHEBORO, NORTH CAROLINA%db("MAG-DATE")PROJECTSITE
MW-6MW-5MW-7MW-1AMW-3MW-4MW-2VE-1MW-11MW-10MW-14MW-12MW-8MW-9MW-15MW-60'40'GRAPHIC SCALE40'80'1" = 40'MW-13ProgressENVIRONMENTAL, INC.JTB151178.003MAY 2012JTRSHOWNMAY 2012Figure 3.SKFP.O. Box 5884WINSTON-SALEM, NORTH CAROLINA 27113PHONE [phone] FAX [phone]FIGURE 3MONITORING WELL LOCATION MAPFORMER CARAWAY GROCERY3419 OLD LEXINGTON ROADASHEBORO, NORTH CAROLINAPROJECT*SOURCE: PYRAMID ENVIRONMENTAL AND ENGINEERING, P.C. CSAAPPROXIMATE MONITORING WELL LOCATIONOl d L e x in g to n R o a d APPROXIMATE FORMER DISPENSER LOCATION%db("MAG-DATE")
MW-6MW-5MW-7MW-1AMW-3MW-4MW-2VE-1MW-11MW-10MW-14MW-12MW-8MW-9MW-15MW-40'40'GRAPHIC SCALE40'80'1" = 40'MW-13(3,040)(128)(ND)(2,090)(240)(ND)(ND)(429)(ND)(ND)(ND)(ND)(40.7)(ND)(ND)(2,780)3,000 ug/L1,500 ug/LBQL1 ug/L(4,590)ProgressENVIRONMENTAL, INC.JTB151178.003MAY 2012JTRSHOWNMAY 2012Figure 4.SKFP.O. Box 5884WINSTON-SALEM, NORTH CAROLINA 27113PHONE [phone] FAX [phone]FIGURE 4BENZENE ISOCONENTRATION MAPFORMER CARAWAY GROCERY3419 OLD LEXINGTON ROADASHEBORO, NORTH CAROLINAPROJECT*SOURCE: PYRAMID ENVIRONMENTAL AND ENGINEERING, P.C. CSAAPPROXIMATE MONITORING WELL LOCATION AND BENZENE CONCENTRATION IN UG/LOl d L e x in g to n R o a d APPROXIMATE FORMER DISPENSER LOCATION%db("MAG-DATE")*PLEASE NOTE: VE-1 OMITTED FROM BENZENE ISOPLETHSINDICATES NC2LGWQS EXCEEDANCE FOR BENZENE
MW-6MW-5MW-7MW-1AMW-3MW-4MW-2VE-1MW-11MW-10MW-14MW-12MW-8MW-9MW-15MW-40'40'GRAPHIC SCALE40'80'1" = 40'MW-13(13,470)(151.8)(ND)(7,330)(258.5)(ND)(ND)(1,546)(ND)(ND)(104.6)(ND)(50.2)(15,091)(ND)(ND)(6,693)5,000 ug/LBQL100 ug/LProgressENVIRONMENTAL, INC.JTB151178.003MAY 2012JTRSHOWNMAY 2012Figure 5.SKFP.O. Box 5884WINSTON-SALEM, NORTH CAROLINA 27113PHONE [phone] FAX [phone]FIGURE 5TOTAL BTEX ISOCONCENTRATION MAPFORMER CARAWAY GROCERY3419 OLD LEXINGTON ROADASHEBORO, NORTH CAROLINAPROJECT*SOURCE: PYRAMID ENVIRONMENTAL AND ENGINEERING, P.C. CSAAPPROXIMATE MONITORING WELL LOCATION AND BTEX CONCENTRATION IN UG/LOl d L e x in g to n R o a d APPROXIMATE FORMER DISPENSER LOCATION%db("MAG-DATE")*PLEASE NOTE: VE-1 OMITTED FROM BETEX ISOPLETHS
MW-6MW-5MW-7MW-1AMW-3MW-4MW-2VE-1MW-11MW-10MW-14MW-12MW-8MW-9MW-15MW-1A0'40'GRAPHIC SCALE40'80'1" = 40'MW-13(72.92)(72.95)(73.84)(75.37)(80.69)(79.69)(76.65)(79.56)(69.12)(76.58)(79.77)(73.09)(70.97)(72.28)(67.56)(72.92)76.0076.0072.0076.0072.0080.00ProgressENVIRONMENTAL, INC.JTB151178.003MAY 2012JTRNTSMAY 2012Figure 6.SKFP.O. Box 5884WINSTON-SALEM, NORTH CAROLINA 27113PHONE [phone] FAX [phone]FIGURE 6GROUNDWATER FLOW MAPFORMER CARAWAY GROCERY3419 OLD LEXINGTON ROADASHEBORO, NORTH CAROLINAPROJECT*SOURCE: PYRAMID ENVIRONMENTAL AND ENGINEERING, P.C. CSAAPPROXIMATE MONITORING WELL LOCATION AND GROUNDWATER ELEVATIONOl d L e x in g to n R o a d%db("MAG-DATE")*PLEASE NOTE: VE-1 and MW-2 OMITTED FROM THE GROUNDWATER FLOW CALCULATIONGROUNDWATER CONTOUR AND ELEVATION (CI = 4.0 FT.)CALCULATED GROUNDWATER FLOW DIRECTION

TABLES
504.1 3030cWell IDDate Collected (m/dd/yy)Depth to Water (Ft. Below TOC)6/30/2010 24.023,520ND ND ND ND ND47.5 35.3 1,160ND82.8 225ND164ND ND69.3 952 5.1 821 232 3,105 0.18 74 8,370 2,110 2,9409/9/2011 31.062,500 22.8 13.2ND ND ND21.9 61.0 572ND51.6 37.1ND112 15.0ND55.6 451ND39.2 47.5 555.7 0.05NA10,900 4,900 9602/8/2012 28.613,750 16.4ND ND ND ND18.7 63.9 727ND57.4 145ND120ND ND297 932ND332 145 1,525ND87.1 12,700 12,800 1,8905/4/2012 27.083,040ND ND ND ND ND85.4 55.8 1,540ND186 429ND519ND ND275 2,990ND2,870 972 5,900 4.1NA15,900 31,400 7,4406/30/2010 24.1786.2ND ND ND ND ND19.5 13.9 2ND ND ND ND ND ND ND18 6.3ND ND ND4.4ND NA NA NA NA9/9/2011 32.0914.7ND0.97ND ND ND19.9 9.9ND ND ND ND ND ND ND ND2.1ND ND ND ND ND ND NA140 78.5ND2/8/2012 28.4819.1ND0.72ND ND ND15.1 7.3ND ND1.4ND ND ND ND ND10.2 0.50ND ND ND ND ND11.0 104 60.0ND5/4/2012 27.03128 0.64 1.7ND ND ND16.1 8.3 7.6ND4.5 2.2ND2.2ND ND9.4 5.70ND2.8ND10.5ND NA378 179ND6/30/2010 22.3494.2ND ND ND ND ND1.6 2.7 54.7ND6.3ND ND11.5ND ND1 3.2ND ND14.7 12.71ND17.5 150 953.0 2409/9/2011 29.59146ND4.9 2.7ND ND4.1 7.2 9.4ND5.3ND ND5.9 3.1ND1.7 2.3ND3.6 1.9ND ND NA760 649 2542/8/2012 24.53275 5.5 9.5 2.7ND ND5.2 7.3 36.5ND11.9 5.1ND15.3ND ND3.7 6.6ND7.5 9.6 5.1ND9.4 1,100 1,190 3405/4/2012 23.55240 4.4 6.7 2.3ND ND10.7 6.3ND ND ND ND ND9.0ND ND3.8 9.0ND5.5ND9.5ND NA1,080 1,750 7286/30/2010 23.142,860ND ND ND ND ND35.4 46.6 998ND77.8 269ND176ND ND196 867ND706.0 224 2,483 0.067 179 7,900 17,000 2,5609/9/2011 31.302,050 18.3 9.4ND ND ND ND95.7 257ND26.8 33.5ND62.8 12.8ND434 84.6ND19.2 47.3 132.4ND NA7,410 4,710ND2/8/2012 27.252,780ND ND ND ND ND23.9 33.6 925ND71.9 139ND166ND ND98.1 1,170ND474 192 1,818ND139 13,400 17,300 2,6505/4/2012 25.172,090ND ND ND ND ND49.8ND765ND56.4 126ND138ND ND74.8 1,950ND658 213 2,525 5.0NA13,500 21,700 4,6706/30/2010 22.18975ND ND ND ND31.9 36.8 6.6 520ND42.9 88ND69.4ND ND ND1,970 2.6 346 118 2,359 17.2 11.3 5,010 11,600 1,0909/9/2011 27.83605 9.8 7.3ND ND ND16.9 3.7 341ND32.4 46.5ND53.7 8.8ND ND589ND150 44.7 855 0.75NA5,110 4,410 6692/8/2012 24.221,370 11.3ND ND ND ND41.6ND812ND62.8 127ND103ND ND ND3,260ND511 119 3,980 1.8 17.9 9,820 20,700 2,9905/4/2012 23.92429ND ND ND ND2.6 13.1 3.2 224ND25.4 53.4ND46.8ND ND ND257ND182 46.9 636 5.0NA2,850 7,160 1,3406/30/2010 20.16 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDND ND ND ND9/9/2011 27.14 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND ND ND2/8/2012 21.32 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND74.3ND ND ND5/4/2012 20.88 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND ND ND6/30/2010 15.28 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDND ND ND ND9/9/2011 23.420.95ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND2/8/2012 16.09 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND7.5ND ND ND5/4/2012 15.81 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND ND ND6/30/2010 16.59 ND ND ND ND ND ND ND ND1.9ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND9/9/2011 25.0617.0ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND2/8/2012 17.17 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND18.5ND ND ND5/4/2012 16.77 ND ND ND ND6.5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND80.2ND6/30/2010 16.8349.5 8.1ND ND ND ND0.83 0.5 97.3ND22 23.3ND42.8ND ND1.8 152ND177 63.2 523 0.21 41.1 352 3,110 5589/9/2011 25.162.6ND1.6ND ND ND ND ND ND ND1.7ND ND ND ND ND0.57ND ND ND ND ND ND NA106 85.5ND2/8/2012 20.15107 4.9 11.4ND ND ND ND ND13.8ND12.5ND ND9.9ND ND ND15.9ND8.2 3.0 31.3ND129 1,350 719 2035/4/2012 19.1040.7ND11.3ND ND ND ND ND3.7ND3.6ND ND2.4ND ND ND2.4ND ND ND3.4ND NA753 368 1356/30/2010 27.25 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND1.1ND ND ND ND ND ND ND ND ND ND9/9/2011 31.90 ND ND ND ND ND ND ND0.65ND ND ND ND ND ND ND ND2.4ND ND ND ND ND ND NA ND ND ND2/8/2012 28.63 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND1.3ND ND ND ND ND ND37.9ND ND ND5/4/2012 27.82 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND0.97ND ND ND ND ND ND NA ND ND ND6/30/2010 26.52 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND1.3ND ND ND ND ND ND ND ND ND ND9/9/2011 35.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND ND ND2/8/2012 33.29 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND105ND ND ND5/4/2012 32.04 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND75.4ND8/12/2010 23.9394.4ND ND ND ND ND49.5 89.1 310ND28.6 46.2 12.7 61ND ND347 525ND241 70.4ND2.3ND2,930 8,080ND9/9/2011 26.323,170 11.4 9.3ND ND0.93 130 98.6 63.7 8.8 42.7 41.5ND35.5 10.2 38.6 278 470ND49.2 31.9 561 1.6NA12,500 3,670ND2/8/2012 21.174,200ND ND ND ND ND159 78.0 264ND50.7 92.6ND63.7ND283 289 772ND229 145 1,989ND74.2 13,800 13,400 2,6805/4/2012 19.954,950ND ND ND ND28.6 257 72.7 891ND95.7 174ND182ND ND ND3,010ND1,510 620 6,240 32.8NA19,000 31,100 5,3208/12/2010 16.94 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDND ND ND ND9/9/2011 22.46 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND92.7ND2/8/2012 14.25 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDND ND ND ND5/4/2012 14.08 ND ND ND ND1.5ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA ND ND ND1 70 70 70 70 0.02 0.4 70 600 40 70 6 5 70 25* NS 20 600 0.005 400 400 500 0.02 15 400 700 2005,000 6,900 8,500 15,000 70,000 50 400 70,000 84,500 NS 257,500 15,500 4,600 30,000 NS NS 20,000 257,500 NS 28,500 2,500 87,500 50 15,000 NS NS NS1,2,3-TrichloropropaneMethylene ChlorideEDB2L Standard (µg/l)2-HexanoneChloroformMW-1AMW-2MW-3MW-4C9-C10 AromaticsEDBTotal XylenesC9-C12 AliphaticsC5-C8 AliphaticsLeadTable 1Summary of Groundwater Analytical Results Former Caraway GroceryVPHAnalytical MethodStandard Method 6200BActive Remediation Monitoring ReportNCDENR Incident No. 24174BenzeneEthylbenzeneContaminant of Concernn-Butylbenzenesec-Butylbenzene1,2-DichloroethaneDiisopropyl Ethertert-Butylbenzene1,3,5-Trimethylbenzenen-PropylbenzeneNaphthalenep-IsopropyltolueneTolueneMTBEIsopropylbenzene1,2,4-TrimethylbenzeneMIBKMW-5MW-6MW-7MW-8MW-9MW-10MW-11MW-12MW-13GCL (µg/l)
504.1 3030cWell IDDate Collected (m/dd/yy)Depth to Water (Ft. Below TOC)8/12/2010 22.21 ND ND ND ND ND ND ND ND17.5ND3ND ND7.9ND ND ND ND ND22.4 8.1 36ND ND ND204ND9/9/2011 27.85 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND ND ND2/8/2012 23.960.74ND0.80ND ND ND ND ND2.3ND2.0ND ND1.2ND ND ND ND ND ND ND ND ND40.0 126 76.4ND5/4/2012 22.70 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDNA ND ND ND8/12/2010 14.34 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NDND ND ND ND9/9/2011 18.43 ND3.8 1.7ND ND ND ND ND ND ND1.7ND ND2.1 2.9ND ND ND ND3.3ND ND ND NA222 192 67.42/8/2012 9.62 ND7.7ND ND ND ND ND ND9.8ND7.3ND ND19.3ND ND ND0.52ND70.5ND24.7ND105 333 843 2595/4/2012 9.96 ND13.8ND ND ND ND ND ND22.2ND11.02.2 ND28.6ND ND ND0.72ND139ND81.7ND NA714 1,450 6356/30/2010 29.5294.4ND ND ND ND ND1.8 11.3 2ND0.75ND ND ND ND ND39.6 6.2ND ND1.2 12 0.056 6 190ND ND9/9/2011 37.11 ND ND ND ND ND ND1.6 10.6ND ND ND ND ND ND ND ND47.2ND ND ND ND ND ND NA62.8ND ND2/8/2012 32.62 ND ND ND ND ND ND1.3 8.4ND ND ND ND ND ND ND ND41.5ND ND ND ND ND ND15.8 54.8ND ND5/4/2012 31.50 ND ND ND ND ND ND1.7 10.6ND ND ND ND ND ND ND ND48.7ND ND ND ND ND ND NA73.1ND ND1 70 70 70 70 0.02 0.4 70 600 40 70 6 5 70 25* NS 20 600 0.005 400 400 500 0.02 15 400 700 2005,000 6,900 8,500 15,000 70,000 50 400 70,000 84,500 NS 257,500 15,500 4,600 30,000 NS NS 20,000 257,500 NS 28,500 2,500 87,500 50 15,000 NS NS NS = Values are those that exceed the North Carolina 2L Groundwater Quality Standard = Values are those that exceed the Gross Contamination LevelsND = not detected above laboratory detection standardResults are reported in µg/lµg/L = micrograms per literGCL = gross contamination levelTOC = top of casingNS = No StandardNA = Not Analyzed* = Interim Standard effective April 1, 2011C9-C10 Aromatics1,2,3-TrichloropropaneMethylene ChlorideEDBLeadC5-C8 AliphaticsC9-C12 AliphaticsTolueneNaphthalene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotal Xylenesn-Propylbenzenep-IsopropyltolueneMIBKMTBEDiisopropyl EtherEthylbenzene2-HexanoneIsopropylbenzeneNCDENR Incident No. 24174Standard Method 6200BVPHContaminant of ConcernBenzenen-Butylbenzenesec-Butylbenzenetert-ButylbenzeneEDB1,2-DichloroethaneGCL (µg/l)2L Standard (µg/l)ChloroformMW-14MW-15VE-1Analytical MethodTable 1Summary of Groundwater Analytical Results Subsequent Active Remediation Monitoring ReportFormer Caraway Grocery
Well Screened Surveyed Total Depth to ElevationMonitoring Well Installation Diameter Interval Elevation Well Depth to Water to WaterID Date (inches) (feet) Top of Caing (feet TOC) (feet TOC) (feet TOC)(feet)5/4/20125/4/2012MW-1A 2008 2 15'-35' 100.00 35' 27.08 72.92MW-2 2008 2 35-50' 99.98 50' 27.03 72.95MW-3 June2010 2 17'-37' 98.92 37' 23.55 75.37MW-4 June2010 2 20'-40' 99.01 40' 25.17 73.84MW-5 June2010 2 14'-34' 100.57 34' 23.92 76.65MW-6 June2010 2 17-37' 100.57 37' 20.88 79.69MW-7 June2010 2 10'-30' 96.50 30' 15.81 80.69MW-8 June2010 2 10-30' 96.33 30' 16.77 79.56MW-9 June2010 2 10'-30' 92.19 30' 19.10 73.09MW-10 June2010 2 20'-40' 95.38 40' 27.82 67.56MW-11 June2010 2 18'-38' 101.16 38' 32.04 69.12MW-12 August 2010 2 10'-30' 90.92 30' 19.95 70.97MW-13 August 2010 2 10'-30' 93.85 30' 14.08 79.77MW-14 August 2010 2 13'-35' 94.98 35' 22.70 72.28MW-15 August 2010 2 10'-30' 86.54 30' 9.96 76.58VE-1 June 2010 2 69'-74' 99.91 74' 31.50 68.41Top of Casing measurements previously obtained by PyramidNCDENR Incident No. 24174Table 2Monitoring Well Construction InformationSubsequent Active Remediation Monitoring ReportFormer Caraway Grocery
DateExtraction PointsElapsed Time (Hours)(inches of Hg)Measured FlowVelocity(ft/min)Pipe ID(in)Temp(deg F)Temp (deg C)Rel. Humid(%)Water Vapor(Wt %)Water Vapor (Vol %)Qstd(flow)4/2/2012Start19.0 36.0 1791.401 2 106.9 41.6 83.4 0.04688 0.0699 33.84/3/20122417.6 38.0 1890.924 2 109.7 43.2 87.9 0.05459 0.0804 35.14/4/20124818.0 40.0 1990.446 2 106.6 41.4 91.8 0.05096 0.0755 37.44/5/20127217.5 44.0 2189.49 2 101.6 38.7 90.2 0.04231 0.0635 42.04/6/20129618.040.01990.44629736.194.20.037570.056838.8CalculationsQstdBwsBwswPerry’s Chemical Engineers’ Handbook)VATs Table 3AMW-1A, MW-4, MW-5, & MW-12MMPE ResultsNCDENR Incident No. 24174Subsequent Active Remediation Monitoring ReportFormer Caraway Grocery = stack temperature in degrees Rankin (Ro), Ro = Fo + 460 (use average value)= (60 sec/min) (1-Bws) (V) (A) (528 Ro / Ts)= (Bwsw/18 lb-mole H2O) / [(1/28.84 lb-mole dry air) + (Bwsw/18 lb-mole H2O)]= lb. of water per lb. of dry air (use high temperature psychrometric chart for air-water vapor mixtures in = velocity in ft/sec (obtain with hot wire anenometer or pitot tube (use average value)Coss-sectional area of discharge stack in square feet at sampling location
Elapsed Time(min)Flow(DSCFM)PPM Measured(ppm)K(#C-gas)PPMgCc:m(mg/dsm^3)Cc(lb/dscf)PMRc(lb/hr)PMRg (lb/hour)PMR(lb)1 33.8 4,698 4 18,792 9993 0.00062 1.267 1.466 35.1591440 35.1 5,000 4 20,000 10636 0.00066 1.400 1.620 38.8852880 37.4 4,807 4 19,228 10225 0.00064 1.432 1.657 39.7804320 42.0 5,000 4 20,000 10636 0.00066 1.675 1.938 46.5165760 38.8 5,000 4 20,000 10636 0.00066 1.546 1.789 1.7895820TOTAL EMISSIONS IN POUNDS162.129CalculationsPPMw= “wet” concentrationPPMd= “dry” concentrationPPMc = PPMv, volumetric concentration of VOC emissions as carbon, dry basis, at STP Cc:mCc= Cc:m (62.43 x 10-9 lb-m3/mg-ft3), lb/dscf, mass concentration of VOC emissions as carbon, dry basis, at STP PMRc= Cc (Qstd) (60 min/hr), lb/hr, pollutant mass removal rate of VOC’s as carbon PMRg= (PMRc) (Mg/Mcg), lb/hr, pollutant mass removal rate of VOC’s as gasoline K = number of carbons in calibration gas (methane K=1, propane K=3, hexane K=6)Mc = 12.01 mg/mg-mole, molecular wt. of carbon K3 = 24.07 dsm3/106 mg-mole, mass to volume conversion factor at STPCc = lb/dscf, mass concentration of VOC emissions as carbon, dry basis, at STPMg= 103 mg/mg-mole, molecular wt. of gasoline (value may vary depending on contaminant)Mcg = 89 mg/mg-mole, weight of carbon in gasoline moleculeAverage values for molecular weight of gasoline, weight of carbon in gasoline molecule, and the conversion of pounds of gasoline emissions to gallons of liquid gasoline are from Automotive Fuels Reference Book, by K. Owens and T. Coley, Second Edition, 1995, published by the Society of Automotive Engineers. Table 3B NOTE: To convert lbs. of gasoline emissions to gallons of liquid gasoline, divide by 6.25 lbs/gal.= PPMc (Mc/K3) NCDENR Incident No. 24174Subsequent Active Remedation Monitoring ReportMMPE Results Former Caraway Grocery

APPENDIX
May 19, 2012
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 92118063
92118063
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR - UST Section
1637 Mail Service Center
Raleigh, NC 276991637
24174 FMR. CARAWAY GROCERY
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on May 08, 2012. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Report re-issued on 5/19/12 to correct 6200B results for sample 004 (MW-4), which were reported from
the re-analysis of the sample.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001South Carolina Drinking Water Cert. #: 99006003Virginia Drinking Water Certification #: 00213
Connecticut Certification #: PH-0104Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84Louisiana DHH Drinking Water # LA 100031West Virginia Certification #: 357Virginia/VELAP Certification #: 460144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE SUMMARY
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Lab ID Sample ID Matrix Date Collected Date Received
92118063001 MW-1A Water 05/04/12 11:40 05/08/12 15:05
92118063002 MW-2 Water 05/04/12 10:25 05/08/12 15:05
92118063003 MW-3 Water 05/04/12 11:50 05/08/12 15:05
92118063004 MW-4 Water 05/04/12 11:35 05/08/12 15:05
92118063005 MW-5 Water 05/04/12 09:45 05/08/12 15:05
92118063006 MW-6 Water 05/04/12 09:15 05/08/12 15:05
92118063007 MW-7 Water 05/04/12 09:55 05/08/12 15:05
92118063008 MW-8 Water 05/04/12 10:20 05/08/12 15:05
92118063009 MW-9 Water 05/04/12 10:45 05/08/12 15:05
92118063010 MW-10 Water 05/04/12 10:10 05/08/12 15:05
92118063011 MW-11 Water 05/04/12 08:45 05/08/12 15:05
92118063012 MW-12 Water 05/04/12 11:15 05/08/12 15:05
92118063013 MW-13 Water 05/04/12 11:05 05/08/12 15:05
92118063014 MW-14 Water 05/04/12 11:00 05/08/12 15:05
92118063015 MW-15 Water 05/04/12 09:10 05/08/12 15:05
92118063016 VE-1 Water 05/04/12 11:20 05/08/12 15:05
92118063017 TRIP BLANK Water 05/04/12 00:00 05/08/12 15:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92118063001 MW-1A EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063002 MW-2 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063003 MW-3 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063004 MW-4 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063005 MW-5 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063006 MW-6 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063007 MW-7 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063008 MW-8 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063009 MW-9 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063010 MW-10 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063011 MW-11 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063012 MW-12 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063013 MW-13 EPA 504.1 2 PASI-CMEJ
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063014 MW-14 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063015 MW-15 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063016 VE-1 EPA 504.1 2 PASI-CMEJ
MADEP VPH 5 PASI-CAW
SM 6200B 64 PASI-CTLS
92118063017 TRIP BLANK SM 6200B 64 PASI-CTLS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92118063001 MW-1A
1,2-Dibromoethane (EDB)4.1 ug/L 05/10/12 18:020.10EPA 504.1
Aliphatic (C05-C08)15900 ug/L 05/11/12 23:47 N21250MADEP VPH
Aliphatic (C09-C12)31400 ug/L 05/11/12 23:47 N2,NC1250MADEP VPH
Aromatic (C09-C10)7440 ug/L 05/11/12 23:47 N21250MADEP VPH
Benzene 3040 ug/L 05/11/12 18:5112.5SM 6200B
1,2-Dichloroethane 85.4 ug/L 05/11/12 18:5112.5SM 6200B
Diisopropyl ether 55.8 ug/L 05/11/12 18:5112.5SM 6200B
Ethylbenzene 1540 ug/L 05/11/12 18:5112.5SM 6200B
Isopropylbenzene (Cumene)186 ug/L 05/11/12 18:5112.5SM 6200B
Methyl-tert-butyl ether 275 ug/L 05/11/12 18:5112.5SM 6200B
Naphthalene 429 ug/L 05/11/12 18:5150.0SM 6200B
n-Propylbenzene 519 ug/L 05/11/12 18:5112.5SM 6200B
Toluene 2990 ug/L 05/11/12 18:5112.5SM 6200B
1,2,4-Trimethylbenzene 2870 ug/L 05/11/12 18:5112.5SM 6200B
1,3,5-Trimethylbenzene 972 ug/L 05/11/12 18:5112.5SM 6200B
m&p-Xylene 4210 ug/L 05/11/12 18:5125.0SM 6200B
o-Xylene 1690 ug/L 05/11/12 18:5112.5SM 6200B
92118063002 MW-2
Aliphatic (C05-C08)378 ug/L 05/15/12 20:01 N250.0MADEP VPH
Aliphatic (C09-C12)179 ug/L 05/15/12 20:01 N250.0MADEP VPH
Benzene 128 ug/L 05/11/12 19:080.50SM 6200B
n-Butylbenzene 0.64 ug/L 05/11/12 19:080.50SM 6200B
sec-Butylbenzene 1.7 ug/L 05/11/12 19:080.50SM 6200B
1,2-Dichloroethane 16.1 ug/L 05/11/12 19:080.50SM 6200B
Diisopropyl ether 8.3 ug/L 05/11/12 19:080.50SM 6200B
Ethylbenzene 7.6 ug/L 05/11/12 19:080.50SM 6200B
Isopropylbenzene (Cumene)4.5 ug/L 05/11/12 19:080.50SM 6200B
Methyl-tert-butyl ether 9.4 ug/L 05/11/12 19:080.50SM 6200B
Naphthalene 2.2 ug/L 05/11/12 19:082.0SM 6200B
n-Propylbenzene 2.2 ug/L 05/11/12 19:080.50SM 6200B
Toluene 5.7 ug/L 05/11/12 19:080.50SM 6200B
1,2,4-Trimethylbenzene 2.8 ug/L 05/11/12 19:080.50SM 6200B
m&p-Xylene 6.4 ug/L 05/11/12 19:081.0SM 6200B
o-Xylene 4.1 ug/L 05/11/12 19:080.50SM 6200B
92118063003 MW-3
Aliphatic (C05-C08)1080 ug/L 05/15/12 20:26 N2,NC50.0MADEP VPH
Aliphatic (C09-C12)1740 ug/L 05/15/12 20:26 N2,NC50.0MADEP VPH
Aromatic (C09-C10)728 ug/L 05/15/12 20:26 N2,NC50.0MADEP VPH
Benzene 240 ug/L 05/11/12 19:241.2SM 6200B
n-Butylbenzene 4.4 ug/L 05/11/12 19:241.2SM 6200B
sec-Butylbenzene 6.7 ug/L 05/11/12 19:241.2SM 6200B
tert-Butylbenzene 2.3 ug/L 05/11/12 19:241.2SM 6200B
1,2-Dichloroethane 10.7 ug/L 05/11/12 19:241.2SM 6200B
Diisopropyl ether 6.3 ug/L 05/11/12 19:241.2SM 6200B
Ethylbenzene 30.5 ug/L 05/11/12 19:241.2SM 6200B
Isopropylbenzene (Cumene)6.5 ug/L 05/11/12 19:241.2SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92118063003 MW-3
Methyl-tert-butyl ether 3.8 ug/L 05/11/12 19:241.2SM 6200B
n-Propylbenzene 9.0 ug/L 05/11/12 19:241.2SM 6200B
Toluene 9.0 ug/L 05/11/12 19:241.2SM 6200B
1,2,4-Trimethylbenzene 5.5 ug/L 05/11/12 19:241.2SM 6200B
m&p-Xylene 7.1 ug/L 05/11/12 19:242.5SM 6200B
o-Xylene 2.4 ug/L 05/11/12 19:241.2SM 6200B
92118063004 MW-4
1,2-Dibromoethane (EDB)5.0 ug/L 05/12/12 06:220.20EPA 504.1
Aliphatic (C05-C08)13500 ug/L 05/11/12 23:21 N2,NC500MADEP VPH
Aliphatic (C09-C12)21700 ug/L 05/11/12 23:21 N2,NC500MADEP VPH
Aromatic (C09-C10)4670 ug/L 05/11/12 23:21 N2,NC500MADEP VPH
Benzene 2090 ug/L 05/18/12 13:5510.0SM 6200B
1,2-Dichloroethane 49.8 ug/L 05/18/12 13:5510.0SM 6200B
Ethylbenzene 765 ug/L 05/18/12 13:5510.0SM 6200B
Isopropylbenzene (Cumene)56.4 ug/L 05/18/12 13:5510.0SM 6200B
Methyl-tert-butyl ether 74.8 ug/L 05/18/12 13:5510.0SM 6200B
Naphthalene 126 ug/L 05/18/12 13:5540.0SM 6200B
n-Propylbenzene 138 ug/L 05/18/12 13:5510.0SM 6200B
Toluene 1950 ug/L 05/18/12 13:5510.0SM 6200B
1,2,4-Trimethylbenzene 658 ug/L 05/18/12 13:5510.0SM 6200B
1,3,5-Trimethylbenzene 213 ug/L 05/18/12 13:5510.0SM 6200B
m&p-Xylene 1840 ug/L 05/18/12 13:5520.0SM 6200B
o-Xylene 685 ug/L 05/18/12 13:5510.0SM 6200B
92118063005 MW-5
1,2-Dibromoethane (EDB)5.0 ug/L 05/10/12 18:430.20EPA 504.1
Aliphatic (C05-C08)2850 ug/L 05/15/12 23:22 N2500MADEP VPH
Aliphatic (C09-C12)7160 ug/L 05/15/12 23:22 N2500MADEP VPH
Aromatic (C09-C10)1340 ug/L 05/15/12 23:22 N2500MADEP VPH
Benzene 429 ug/L 05/16/12 18:102.0SM 6200B
1,2-Dibromoethane (EDB)2.6 ug/L 05/16/12 18:102.0SM 6200B
1,2-Dichloroethane 13.1 ug/L 05/16/12 18:102.0SM 6200B
Diisopropyl ether 3.2 ug/L 05/16/12 18:102.0SM 6200B
Ethylbenzene 224 ug/L 05/16/12 18:102.0SM 6200B
Isopropylbenzene (Cumene)25.4 ug/L 05/16/12 18:102.0SM 6200B
Naphthalene 53.4 ug/L 05/16/12 18:108.0SM 6200B
n-Propylbenzene 46.8 ug/L 05/16/12 18:102.0SM 6200B
Toluene 257 ug/L 05/16/12 18:102.0SM 6200B
1,2,4-Trimethylbenzene 182 ug/L 05/16/12 18:102.0SM 6200B
1,3,5-Trimethylbenzene 46.9 ug/L 05/16/12 18:102.0SM 6200B
m&p-Xylene 441 ug/L 05/16/12 18:104.0SM 6200B
o-Xylene 195 ug/L 05/16/12 18:102.0SM 6200B
92118063008 MW-8
Aliphatic (C09-C12)80.2 ug/L 05/11/12 17:29 N250.0MADEP VPH
Chloroform 6.5 ug/L 05/11/12 20:480.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92118063009 MW-9
Aliphatic (C05-C08)753 ug/L 05/11/12 17:54 N250.0MADEP VPH
Aliphatic (C09-C12)368 ug/L 05/11/12 17:54 N250.0MADEP VPH
Aromatic (C09-C10)135 ug/L 05/11/12 17:54 N250.0MADEP VPH
Benzene 40.7 ug/L 05/11/12 21:040.50SM 6200B
sec-Butylbenzene 11.3 ug/L 05/11/12 21:040.50SM 6200B
Ethylbenzene 3.7 ug/L 05/11/12 21:040.50SM 6200B
Isopropylbenzene (Cumene)3.6 ug/L 05/11/12 21:040.50SM 6200B
n-Propylbenzene 2.4 ug/L 05/11/12 21:040.50SM 6200B
Toluene 2.4 ug/L 05/11/12 21:040.50SM 6200B
m&p-Xylene 1.9 ug/L 05/11/12 21:041.0SM 6200B
o-Xylene 1.5 ug/L 05/11/12 21:040.50SM 6200B
92118063010 MW-10
Methyl-tert-butyl ether 0.97 ug/L 05/11/12 21:210.50SM 6200B
92118063011 MW-11
Aliphatic (C09-C12)75.4 ug/L 05/11/12 18:45 N250.0MADEP VPH
92118063012 MW-12
1,2-Dibromoethane (EDB)32.8 ug/L 05/10/12 19:030.96EPA 504.1
Aliphatic (C05-C08)19000 ug/L 05/12/12 00:12 N21250MADEP VPH
Aliphatic (C09-C12)31100 ug/L 05/12/12 00:12 N2,NC1250MADEP VPH
Aromatic (C09-C10)5320 ug/L 05/12/12 00:12 N21250MADEP VPH
Benzene 4950 ug/L 05/11/12 21:5512.5SM 6200B
1,2-Dibromoethane (EDB)28.6 ug/L 05/11/12 21:5512.5SM 6200B
1,2-Dichloroethane 257 ug/L 05/11/12 21:5512.5SM 6200B
Diisopropyl ether 72.7 ug/L 05/11/12 21:5512.5SM 6200B
Ethylbenzene 891 ug/L 05/11/12 21:5512.5SM 6200B
Isopropylbenzene (Cumene)95.7 ug/L 05/11/12 21:5512.5SM 6200B
Methyl-tert-butyl ether 236 ug/L 05/11/12 21:5512.5SM 6200B
Naphthalene 174 ug/L 05/11/12 21:5550.0SM 6200B
n-Propylbenzene 182 ug/L 05/11/12 21:5512.5SM 6200B
Toluene 3010 ug/L 05/11/12 21:5512.5SM 6200B
1,2,4-Trimethylbenzene 1510 ug/L 05/11/12 21:5512.5SM 6200B
1,3,5-Trimethylbenzene 620 ug/L 05/11/12 21:5512.5SM 6200B
m&p-Xylene 3930 ug/L 05/11/12 21:5525.0SM 6200B
o-Xylene 2310 ug/L 05/11/12 21:5512.5SM 6200B
92118063013 MW-13
Chloroform 1.5 ug/L 05/11/12 22:110.50SM 6200B
92118063015 MW-15
Aliphatic (C05-C08)714 ug/L 05/11/12 20:00 N250.0MADEP VPH
Aliphatic (C09-C12)1450 ug/L 05/11/12 20:00 N2,NC50.0MADEP VPH
Aromatic (C09-C10)635 ug/L 05/11/12 20:00 N2,NC50.0MADEP VPH
n-Butylbenzene 13.8 ug/L 05/11/12 22:450.50SM 6200B
Ethylbenzene 22.2 ug/L 05/11/12 22:450.50SM 6200B
Isopropylbenzene (Cumene)11.0 ug/L 05/11/12 22:450.50SM 6200B
Naphthalene 2.2 ug/L 05/11/12 22:452.0SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
HITS ONLY
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92118063015 MW-15
n-Propylbenzene 28.6 ug/L 05/11/12 22:450.50SM 6200B
Toluene 0.72 ug/L 05/11/12 22:450.50SM 6200B
1,2,4-Trimethylbenzene 139 ug/L 05/11/12 22:450.50SM 6200B
m&p-Xylene 58.5 ug/L 05/11/12 22:451.0SM 6200B
o-Xylene 23.2 ug/L 05/11/12 22:450.50SM 6200B
92118063016 VE-1
Aliphatic (C05-C08)73.1 ug/L 05/15/12 22:32 N250.0MADEP VPH
1,2-Dichloroethane 1.7 ug/L 05/11/12 23:010.50SM 6200B
Diisopropyl ether 10.6 ug/L 05/11/12 23:010.50SM 6200B
Methyl-tert-butyl ether 48.7 ug/L 05/11/12 23:010.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-1A Lab ID:92118063001 Collected:05/04/12 11:40 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)4.1 ug/L 5 05/10/12 18:02 106-93-405/09/12 15:070.10 0.10
Surrogates
1-Chloro-2-bromopropane (S)0 %5 05/10/12 18:02 301-79-56 S405/09/12 15:0770-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)15900 ug/L 25 05/11/12 23:47 N212501250
Aliphatic (C09-C12)31400 ug/L 25 05/11/12 23:47 N2,NC12501250
Aromatic (C09-C10)7440 ug/L 25 05/11/12 23:47 N212501250
Surrogates
2,5-Dibromotoluene (PID)(S)90 %25 05/11/12 23:4770-130
2,5-Dibromotoluene (FID)(S)106 %25 05/11/12 23:4770-130
6200B MSV Analytical Method: SM 6200B
Benzene 3040 ug/L 25 05/11/12 18:51 71-43-212.5 12.5
Bromobenzene ND ug/L 25 05/11/12 18:51 108-86-112.5 12.5
Bromochloromethane ND ug/L 25 05/11/12 18:51 74-97-512.5 12.5
Bromodichloromethane ND ug/L 25 05/11/12 18:51 75-27-412.5 12.5
Bromoform ND ug/L 25 05/11/12 18:51 75-25-212.5 12.5
Bromomethane ND ug/L 25 05/11/12 18:51 74-83-912525.0
n-Butylbenzene ND ug/L 25 05/11/12 18:51 104-51-812.5 12.5
sec-Butylbenzene ND ug/L 25 05/11/12 18:51 135-98-812.5 12.5
tert-Butylbenzene ND ug/L 25 05/11/12 18:51 98-06-612.5 12.5
Carbon tetrachloride ND ug/L 25 05/11/12 18:51 56-23-512.5 12.5
Chlorobenzene ND ug/L 25 05/11/12 18:51 108-90-712.5 12.5
Chloroethane ND ug/L 25 05/11/12 18:51 75-00-325.0 25.0
Chloroform ND ug/L 25 05/11/12 18:51 67-66-312.5 12.5
Chloromethane ND ug/L 25 05/11/12 18:51 74-87-325.0 25.0
2-Chlorotoluene ND ug/L 25 05/11/12 18:51 95-49-812.5 12.5
4-Chlorotoluene ND ug/L 25 05/11/12 18:51 106-43-412.5 12.5
1,2-Dibromo-3-chloropropane ND ug/L 25 05/11/12 18:51 96-12-825.0 25.0
Dibromochloromethane ND ug/L 25 05/11/12 18:51 124-48-112.5 12.5
1,2-Dibromoethane (EDB)ND ug/L 25 05/11/12 18:51 106-93-412.5 12.5
Dibromomethane ND ug/L 25 05/11/12 18:51 74-95-312.5 12.5
1,2-Dichlorobenzene ND ug/L 25 05/11/12 18:51 95-50-112.5 12.5
1,3-Dichlorobenzene ND ug/L 25 05/11/12 18:51 541-73-112.5 12.5
1,4-Dichlorobenzene ND ug/L 25 05/11/12 18:51 106-46-712.5 12.5
Dichlorodifluoromethane ND ug/L 25 05/11/12 18:51 75-71-812.5 12.5
1,1-Dichloroethane ND ug/L 25 05/11/12 18:51 75-34-312.5 12.5
1,2-Dichloroethane 85.4 ug/L 25 05/11/12 18:51 107-06-212.5 12.5
1,1-Dichloroethene ND ug/L 25 05/11/12 18:51 75-35-412.5 12.5
cis-1,2-Dichloroethene ND ug/L 25 05/11/12 18:51 156-59-212.5 12.5
trans-1,2-Dichloroethene ND ug/L 25 05/11/12 18:51 156-60-512.5 12.5
1,2-Dichloropropane ND ug/L 25 05/11/12 18:51 78-87-512.5 12.5
1,3-Dichloropropane ND ug/L 25 05/11/12 18:51 142-28-912.5 12.5
2,2-Dichloropropane ND ug/L 25 05/11/12 18:51 594-20-712.5 12.5
1,1-Dichloropropene ND ug/L 25 05/11/12 18:51 563-58-612.5 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 10 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-1A Lab ID:92118063001 Collected:05/04/12 11:40 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 25 05/11/12 18:51 10061-01-512.5 12.5
trans-1,3-Dichloropropene ND ug/L 25 05/11/12 18:51 10061-02-612.5 12.5
Diisopropyl ether 55.8 ug/L 25 05/11/12 18:51 108-20-312.5 12.5
Ethylbenzene 1540 ug/L 25 05/11/12 18:51 100-41-412.5 12.5
Hexachloro-1,3-butadiene ND ug/L 25 05/11/12 18:51 87-68-350.0 50.0
Isopropylbenzene (Cumene)186 ug/L 25 05/11/12 18:51 98-82-812.5 12.5
Methylene Chloride ND ug/L 25 05/11/12 18:51 75-09-250.0 50.0
Methyl-tert-butyl ether 275 ug/L 25 05/11/12 18:51 1634-04-412.5 12.5
Naphthalene 429 ug/L 25 05/11/12 18:51 91-20-350.0 50.0
n-Propylbenzene 519 ug/L 25 05/11/12 18:51 103-65-112.5 12.5
Styrene ND ug/L 25 05/11/12 18:51 100-42-512.5 12.5
1,1,1,2-Tetrachloroethane ND ug/L 25 05/11/12 18:51 630-20-612.5 12.5
1,1,2,2-Tetrachloroethane ND ug/L 25 05/11/12 18:51 79-34-512.5 12.5
Tetrachloroethene ND ug/L 25 05/11/12 18:51 127-18-412.5 12.5
Toluene 2990 ug/L 25 05/11/12 18:51 108-88-312.5 12.5
1,2,3-Trichlorobenzene ND ug/L 25 05/11/12 18:51 87-61-650.0 50.0
1,2,4-Trichlorobenzene ND ug/L 25 05/11/12 18:51 120-82-150.0 50.0
1,1,1-Trichloroethane ND ug/L 25 05/11/12 18:51 71-55-612.5 12.5
1,1,2-Trichloroethane ND ug/L 25 05/11/12 18:51 79-00-512.5 12.5
Trichloroethene ND ug/L 25 05/11/12 18:51 79-01-612.5 12.5
Trichlorofluoromethane ND ug/L 25 05/11/12 18:51 75-69-425.0 25.0
1,2,3-Trichloropropane ND ug/L 25 05/11/12 18:51 96-18-412.5 12.5
1,2,4-Trimethylbenzene 2870 ug/L 25 05/11/12 18:51 95-63-612.5 12.5
1,3,5-Trimethylbenzene 972 ug/L 25 05/11/12 18:51 108-67-812.5 12.5
Vinyl chloride ND ug/L 25 05/11/12 18:51 75-01-425.0 25.0
m&p-Xylene 4210 ug/L 25 05/11/12 18:51 179601-23-125.0 25.0
o-Xylene 1690 ug/L 25 05/11/12 18:51 95-47-612.5 12.5
Surrogates
1,2-Dichloroethane-d4 (S)103 %25 05/11/12 18:51 17060-07-070-130
Dibromofluoromethane (S)102 %25 05/11/12 18:51 1868-53-770-130
4-Bromofluorobenzene (S)96 %25 05/11/12 18:51 460-00-470-130
Toluene-d8 (S)99 %25 05/11/12 18:51 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 11 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-2 Lab ID:92118063002 Collected:05/04/12 10:25 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/09/12 20:57 106-93-405/09/12 15:070.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)98 %1 05/09/12 20:57 301-79-5605/09/12 15:0770-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)378 ug/L 1 05/15/12 20:01 N250.0 50.0
Aliphatic (C09-C12)179 ug/L 1 05/15/12 20:01 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/15/12 20:01 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)82 %1 05/15/12 20:0170-130
2,5-Dibromotoluene (FID)(S)97 %1 05/15/12 20:0170-130
6200B MSV Analytical Method: SM 6200B
Benzene 128 ug/L 1 05/11/12 19:08 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 19:08 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 19:08 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 19:08 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 19:08 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 19:08 74-83-95.0 1.0
n-Butylbenzene 0.64 ug/L 1 05/11/12 19:08 104-51-80.50 0.50
sec-Butylbenzene 1.7 ug/L 1 05/11/12 19:08 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 19:08 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 19:08 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 19:08 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 19:08 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 19:08 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 19:08 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 19:08 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 19:08 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 19:08 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 19:08 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 19:08 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 19:08 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 19:08 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 19:08 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 19:08 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 19:08 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 19:08 75-34-30.50 0.50
1,2-Dichloroethane 16.1 ug/L 1 05/11/12 19:08 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 19:08 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 19:08 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 19:08 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 19:08 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 19:08 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 19:08 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 19:08 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 12 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-2 Lab ID:92118063002 Collected:05/04/12 10:25 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 19:08 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 19:08 10061-02-60.50 0.50
Diisopropyl ether 8.3 ug/L 1 05/11/12 19:08 108-20-30.50 0.50
Ethylbenzene 7.6 ug/L 1 05/11/12 19:08 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 19:08 87-68-32.0 2.0
Isopropylbenzene (Cumene)4.5 ug/L 1 05/11/12 19:08 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 19:08 75-09-22.0 2.0
Methyl-tert-butyl ether 9.4 ug/L 1 05/11/12 19:08 1634-04-40.50 0.50
Naphthalene 2.2 ug/L 1 05/11/12 19:08 91-20-32.0 2.0
n-Propylbenzene 2.2 ug/L 1 05/11/12 19:08 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 19:08 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 19:08 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 19:08 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 19:08 127-18-40.50 0.50
Toluene 5.7 ug/L 1 05/11/12 19:08 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 19:08 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 19:08 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 19:08 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 19:08 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 19:08 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 19:08 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 19:08 96-18-40.50 0.50
1,2,4-Trimethylbenzene 2.8 ug/L 1 05/11/12 19:08 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 19:08 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 19:08 75-01-41.0 1.0
m&p-Xylene 6.4 ug/L 1 05/11/12 19:08 179601-23-11.0 1.0
o-Xylene 4.1 ug/L 1 05/11/12 19:08 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)103 %1 05/11/12 19:08 17060-07-070-130
Dibromofluoromethane (S)99 %1 05/11/12 19:08 1868-53-770-130
4-Bromofluorobenzene (S)97 %1 05/11/12 19:08 460-00-470-130
Toluene-d8 (S)101 %1 05/11/12 19:08 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 13 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-3 Lab ID:92118063003 Collected:05/04/12 11:50 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/09/12 21:17 106-93-405/09/12 15:080.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)102 %1 05/09/12 21:17 301-79-5605/09/12 15:0870-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)1080 ug/L 1 05/15/12 20:26 N2,NC50.0 50.0
Aliphatic (C09-C12)1740 ug/L 1 05/15/12 20:26 N2,NC50.0 50.0
Aromatic (C09-C10)728 ug/L 1 05/15/12 20:26 N2,NC50.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)105 %1 05/15/12 20:2670-130
2,5-Dibromotoluene (FID)(S)142 %1 05/15/12 20:26 S570-130
6200B MSV Analytical Method: SM 6200B
Benzene 240 ug/L 2.5 05/11/12 19:24 71-43-21.2 1.2
Bromobenzene ND ug/L 2.5 05/11/12 19:24 108-86-11.2 1.2
Bromochloromethane ND ug/L 2.5 05/11/12 19:24 74-97-51.2 1.2
Bromodichloromethane ND ug/L 2.5 05/11/12 19:24 75-27-41.2 1.2
Bromoform ND ug/L 2.5 05/11/12 19:24 75-25-21.2 1.2
Bromomethane ND ug/L 2.5 05/11/12 19:24 74-83-912.5 2.5
n-Butylbenzene 4.4 ug/L 2.5 05/11/12 19:24 104-51-81.2 1.2
sec-Butylbenzene 6.7 ug/L 2.5 05/11/12 19:24 135-98-81.2 1.2
tert-Butylbenzene 2.3 ug/L 2.5 05/11/12 19:24 98-06-61.2 1.2
Carbon tetrachloride ND ug/L 2.5 05/11/12 19:24 56-23-51.2 1.2
Chlorobenzene ND ug/L 2.5 05/11/12 19:24 108-90-71.2 1.2
Chloroethane ND ug/L 2.5 05/11/12 19:24 75-00-32.5 2.5
Chloroform ND ug/L 2.5 05/11/12 19:24 67-66-31.2 1.2
Chloromethane ND ug/L 2.5 05/11/12 19:24 74-87-32.5 2.5
2-Chlorotoluene ND ug/L 2.5 05/11/12 19:24 95-49-81.2 1.2
4-Chlorotoluene ND ug/L 2.5 05/11/12 19:24 106-43-41.2 1.2
1,2-Dibromo-3-chloropropane ND ug/L 2.5 05/11/12 19:24 96-12-82.5 2.5
Dibromochloromethane ND ug/L 2.5 05/11/12 19:24 124-48-11.2 1.2
1,2-Dibromoethane (EDB)ND ug/L 2.5 05/11/12 19:24 106-93-41.2 1.2
Dibromomethane ND ug/L 2.5 05/11/12 19:24 74-95-31.2 1.2
1,2-Dichlorobenzene ND ug/L 2.5 05/11/12 19:24 95-50-11.2 1.2
1,3-Dichlorobenzene ND ug/L 2.5 05/11/12 19:24 541-73-11.2 1.2
1,4-Dichlorobenzene ND ug/L 2.5 05/11/12 19:24 106-46-71.2 1.2
Dichlorodifluoromethane ND ug/L 2.5 05/11/12 19:24 75-71-81.2 1.2
1,1-Dichloroethane ND ug/L 2.5 05/11/12 19:24 75-34-31.2 1.2
1,2-Dichloroethane 10.7 ug/L 2.5 05/11/12 19:24 107-06-21.2 1.2
1,1-Dichloroethene ND ug/L 2.5 05/11/12 19:24 75-35-41.2 1.2
cis-1,2-Dichloroethene ND ug/L 2.5 05/11/12 19:24 156-59-21.2 1.2
trans-1,2-Dichloroethene ND ug/L 2.5 05/11/12 19:24 156-60-51.2 1.2
1,2-Dichloropropane ND ug/L 2.5 05/11/12 19:24 78-87-51.2 1.2
1,3-Dichloropropane ND ug/L 2.5 05/11/12 19:24 142-28-91.2 1.2
2,2-Dichloropropane ND ug/L 2.5 05/11/12 19:24 594-20-71.2 1.2
1,1-Dichloropropene ND ug/L 2.5 05/11/12 19:24 563-58-61.2 1.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 14 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-3 Lab ID:92118063003 Collected:05/04/12 11:50 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 2.5 05/11/12 19:24 10061-01-51.2 1.2
trans-1,3-Dichloropropene ND ug/L 2.5 05/11/12 19:24 10061-02-61.2 1.2
Diisopropyl ether 6.3 ug/L 2.5 05/11/12 19:24 108-20-31.2 1.2
Ethylbenzene 30.5 ug/L 2.5 05/11/12 19:24 100-41-41.2 1.2
Hexachloro-1,3-butadiene ND ug/L 2.5 05/11/12 19:24 87-68-35.0 5.0
Isopropylbenzene (Cumene)6.5 ug/L 2.5 05/11/12 19:24 98-82-81.2 1.2
Methylene Chloride ND ug/L 2.5 05/11/12 19:24 75-09-25.0 5.0
Methyl-tert-butyl ether 3.8 ug/L 2.5 05/11/12 19:24 1634-04-41.2 1.2
Naphthalene ND ug/L 2.5 05/11/12 19:24 91-20-35.0 5.0
n-Propylbenzene 9.0 ug/L 2.5 05/11/12 19:24 103-65-11.2 1.2
Styrene ND ug/L 2.5 05/11/12 19:24 100-42-51.2 1.2
1,1,1,2-Tetrachloroethane ND ug/L 2.5 05/11/12 19:24 630-20-61.2 1.2
1,1,2,2-Tetrachloroethane ND ug/L 2.5 05/11/12 19:24 79-34-51.2 1.2
Tetrachloroethene ND ug/L 2.5 05/11/12 19:24 127-18-41.2 1.2
Toluene 9.0 ug/L 2.5 05/11/12 19:24 108-88-31.2 1.2
1,2,3-Trichlorobenzene ND ug/L 2.5 05/11/12 19:24 87-61-65.0 5.0
1,2,4-Trichlorobenzene ND ug/L 2.5 05/11/12 19:24 120-82-15.0 5.0
1,1,1-Trichloroethane ND ug/L 2.5 05/11/12 19:24 71-55-61.2 1.2
1,1,2-Trichloroethane ND ug/L 2.5 05/11/12 19:24 79-00-51.2 1.2
Trichloroethene ND ug/L 2.5 05/11/12 19:24 79-01-61.2 1.2
Trichlorofluoromethane ND ug/L 2.5 05/11/12 19:24 75-69-42.5 2.5
1,2,3-Trichloropropane ND ug/L 2.5 05/11/12 19:24 96-18-41.2 1.2
1,2,4-Trimethylbenzene 5.5 ug/L 2.5 05/11/12 19:24 95-63-61.2 1.2
1,3,5-Trimethylbenzene ND ug/L 2.5 05/11/12 19:24 108-67-81.2 1.2
Vinyl chloride ND ug/L 2.5 05/11/12 19:24 75-01-42.5 2.5
m&p-Xylene 7.1 ug/L 2.5 05/11/12 19:24 179601-23-12.5 2.5
o-Xylene 2.4 ug/L 2.5 05/11/12 19:24 95-47-61.2 1.2
Surrogates
1,2-Dichloroethane-d4 (S)105 %2.5 05/11/12 19:24 17060-07-070-130
Dibromofluoromethane (S)100 %2.5 05/11/12 19:24 1868-53-770-130
4-Bromofluorobenzene (S)96 %2.5 05/11/12 19:24 460-00-470-130
Toluene-d8 (S)101 %2.5 05/11/12 19:24 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 15 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-4 Lab ID:92118063004 Collected:05/04/12 11:35 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)5.0 ug/L 10 05/12/12 06:22 106-93-405/09/12 15:080.20 0.20
Surrogates
1-Chloro-2-bromopropane (S)0 %10 05/12/12 06:22 301-79-56 S405/09/12 15:0870-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)13500 ug/L 10 05/11/12 23:21 N2,NC500500
Aliphatic (C09-C12)21700 ug/L 10 05/11/12 23:21 N2,NC500500
Aromatic (C09-C10)4670 ug/L 10 05/11/12 23:21 N2,NC500500
Surrogates
2,5-Dibromotoluene (PID)(S)95 %10 05/11/12 23:2170-130
2,5-Dibromotoluene (FID)(S)109 %10 05/11/12 23:2170-130
6200B MSV Analytical Method: SM 6200B
Benzene 2090 ug/L 20 05/18/12 13:55 71-43-210.0 10.0
Bromobenzene ND ug/L 20 05/18/12 13:55 108-86-110.0 10.0
Bromochloromethane ND ug/L 20 05/18/12 13:55 74-97-510.0 10.0
Bromodichloromethane ND ug/L 20 05/18/12 13:55 75-27-410.0 10.0
Bromoform ND ug/L 20 05/18/12 13:55 75-25-210.0 10.0
Bromomethane ND ug/L 20 05/18/12 13:55 74-83-910020.0
n-Butylbenzene ND ug/L 20 05/18/12 13:55 104-51-810.0 10.0
sec-Butylbenzene ND ug/L 20 05/18/12 13:55 135-98-810.0 10.0
tert-Butylbenzene ND ug/L 20 05/18/12 13:55 98-06-610.0 10.0
Carbon tetrachloride ND ug/L 20 05/18/12 13:55 56-23-510.0 10.0
Chlorobenzene ND ug/L 20 05/18/12 13:55 108-90-710.0 10.0
Chloroethane ND ug/L 20 05/18/12 13:55 75-00-320.0 20.0
Chloroform ND ug/L 20 05/18/12 13:55 67-66-310.0 10.0
Chloromethane ND ug/L 20 05/18/12 13:55 74-87-320.0 20.0
2-Chlorotoluene ND ug/L 20 05/18/12 13:55 95-49-810.0 10.0
4-Chlorotoluene ND ug/L 20 05/18/12 13:55 106-43-410.0 10.0
1,2-Dibromo-3-chloropropane ND ug/L 20 05/18/12 13:55 96-12-820.0 20.0
Dibromochloromethane ND ug/L 20 05/18/12 13:55 124-48-110.0 10.0
1,2-Dibromoethane (EDB)ND ug/L 20 05/18/12 13:55 106-93-410.0 10.0
Dibromomethane ND ug/L 20 05/18/12 13:55 74-95-310.0 10.0
1,2-Dichlorobenzene ND ug/L 20 05/18/12 13:55 95-50-110.0 10.0
1,3-Dichlorobenzene ND ug/L 20 05/18/12 13:55 541-73-110.0 10.0
1,4-Dichlorobenzene ND ug/L 20 05/18/12 13:55 106-46-710.0 10.0
Dichlorodifluoromethane ND ug/L 20 05/18/12 13:55 75-71-810.0 10.0
1,1-Dichloroethane ND ug/L 20 05/18/12 13:55 75-34-310.0 10.0
1,2-Dichloroethane 49.8 ug/L 20 05/18/12 13:55 107-06-210.0 10.0
1,1-Dichloroethene ND ug/L 20 05/18/12 13:55 75-35-410.0 10.0
cis-1,2-Dichloroethene ND ug/L 20 05/18/12 13:55 156-59-210.0 10.0
trans-1,2-Dichloroethene ND ug/L 20 05/18/12 13:55 156-60-510.0 10.0
1,2-Dichloropropane ND ug/L 20 05/18/12 13:55 78-87-510.0 10.0
1,3-Dichloropropane ND ug/L 20 05/18/12 13:55 142-28-910.0 10.0
2,2-Dichloropropane ND ug/L 20 05/18/12 13:55 594-20-710.0 10.0
1,1-Dichloropropene ND ug/L 20 05/18/12 13:55 563-58-610.0 10.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 16 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-4 Lab ID:92118063004 Collected:05/04/12 11:35 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 20 05/18/12 13:55 10061-01-510.0 10.0
trans-1,3-Dichloropropene ND ug/L 20 05/18/12 13:55 10061-02-610.0 10.0
Diisopropyl ether ND ug/L 20 05/18/12 13:55 108-20-310.0 10.0
Ethylbenzene 765 ug/L 20 05/18/12 13:55 100-41-410.0 10.0
Hexachloro-1,3-butadiene ND ug/L 20 05/18/12 13:55 87-68-340.0 40.0
Isopropylbenzene (Cumene)56.4 ug/L 20 05/18/12 13:55 98-82-810.0 10.0
Methylene Chloride ND ug/L 20 05/18/12 13:55 75-09-240.0 40.0
Methyl-tert-butyl ether 74.8 ug/L 20 05/18/12 13:55 1634-04-410.0 10.0
Naphthalene 126 ug/L 20 05/18/12 13:55 91-20-340.0 40.0
n-Propylbenzene 138 ug/L 20 05/18/12 13:55 103-65-110.0 10.0
Styrene ND ug/L 20 05/18/12 13:55 100-42-510.0 10.0
1,1,1,2-Tetrachloroethane ND ug/L 20 05/18/12 13:55 630-20-610.0 10.0
1,1,2,2-Tetrachloroethane ND ug/L 20 05/18/12 13:55 79-34-510.0 10.0
Tetrachloroethene ND ug/L 20 05/18/12 13:55 127-18-410.0 10.0
Toluene 1950 ug/L 20 05/18/12 13:55 108-88-310.0 10.0
1,2,3-Trichlorobenzene ND ug/L 20 05/18/12 13:55 87-61-640.0 40.0
1,2,4-Trichlorobenzene ND ug/L 20 05/18/12 13:55 120-82-140.0 40.0
1,1,1-Trichloroethane ND ug/L 20 05/18/12 13:55 71-55-610.0 10.0
1,1,2-Trichloroethane ND ug/L 20 05/18/12 13:55 79-00-510.0 10.0
Trichloroethene ND ug/L 20 05/18/12 13:55 79-01-610.0 10.0
Trichlorofluoromethane ND ug/L 20 05/18/12 13:55 75-69-420.0 20.0
1,2,3-Trichloropropane ND ug/L 20 05/18/12 13:55 96-18-410.0 10.0
1,2,4-Trimethylbenzene 658 ug/L 20 05/18/12 13:55 95-63-610.0 10.0
1,3,5-Trimethylbenzene 213 ug/L 20 05/18/12 13:55 108-67-810.0 10.0
Vinyl chloride ND ug/L 20 05/18/12 13:55 75-01-420.0 20.0
m&p-Xylene 1840 ug/L 20 05/18/12 13:55 179601-23-120.0 20.0
o-Xylene 685 ug/L 20 05/18/12 13:55 95-47-610.0 10.0
Surrogates
1,2-Dichloroethane-d4 (S)101 %20 05/18/12 13:55 17060-07-070-130
Dibromofluoromethane (S)99 %20 05/18/12 13:55 1868-53-770-130
4-Bromofluorobenzene (S)99 %20 05/18/12 13:55 460-00-470-130
Toluene-d8 (S)100 %20 05/18/12 13:55 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 17 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-5 Lab ID:92118063005 Collected:05/04/12 09:45 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)5.0 ug/L 10 05/10/12 18:43 106-93-405/09/12 15:090.20 0.20
Surrogates
1-Chloro-2-bromopropane (S)0 %10 05/10/12 18:43 301-79-56 S405/09/12 15:0970-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)2850 ug/L 10 05/15/12 23:22 N2500500
Aliphatic (C09-C12)7160 ug/L 10 05/15/12 23:22 N2500500
Aromatic (C09-C10)1340 ug/L 10 05/15/12 23:22 N2500500
Surrogates
2,5-Dibromotoluene (PID)(S)91 %10 05/15/12 23:2270-130
2,5-Dibromotoluene (FID)(S)112 %10 05/15/12 23:2270-130
6200B MSV Analytical Method: SM 6200B
Benzene 429 ug/L 4 05/16/12 18:10 71-43-22.0 2.0
Bromobenzene ND ug/L 4 05/16/12 18:10 108-86-12.0 2.0
Bromochloromethane ND ug/L 4 05/16/12 18:10 74-97-52.0 2.0
Bromodichloromethane ND ug/L 4 05/16/12 18:10 75-27-42.0 2.0
Bromoform ND ug/L 4 05/16/12 18:10 75-25-22.0 2.0
Bromomethane ND ug/L 4 05/16/12 18:10 74-83-920.0 4.0
n-Butylbenzene ND ug/L 4 05/16/12 18:10 104-51-82.0 2.0
sec-Butylbenzene ND ug/L 4 05/16/12 18:10 135-98-82.0 2.0
tert-Butylbenzene ND ug/L 4 05/16/12 18:10 98-06-62.0 2.0
Carbon tetrachloride ND ug/L 4 05/16/12 18:10 56-23-52.0 2.0
Chlorobenzene ND ug/L 4 05/16/12 18:10 108-90-72.0 2.0
Chloroethane ND ug/L 4 05/16/12 18:10 75-00-34.0 4.0
Chloroform ND ug/L 4 05/16/12 18:10 67-66-32.0 2.0
Chloromethane ND ug/L 4 05/16/12 18:10 74-87-34.0 4.0
2-Chlorotoluene ND ug/L 4 05/16/12 18:10 95-49-82.0 2.0
4-Chlorotoluene ND ug/L 4 05/16/12 18:10 106-43-42.0 2.0
1,2-Dibromo-3-chloropropane ND ug/L 4 05/16/12 18:10 96-12-84.0 4.0
Dibromochloromethane ND ug/L 4 05/16/12 18:10 124-48-12.0 2.0
1,2-Dibromoethane (EDB)2.6 ug/L 4 05/16/12 18:10 106-93-42.0 2.0
Dibromomethane ND ug/L 4 05/16/12 18:10 74-95-32.0 2.0
1,2-Dichlorobenzene ND ug/L 4 05/16/12 18:10 95-50-12.0 2.0
1,3-Dichlorobenzene ND ug/L 4 05/16/12 18:10 541-73-12.0 2.0
1,4-Dichlorobenzene ND ug/L 4 05/16/12 18:10 106-46-72.0 2.0
Dichlorodifluoromethane ND ug/L 4 05/16/12 18:10 75-71-82.0 2.0
1,1-Dichloroethane ND ug/L 4 05/16/12 18:10 75-34-32.0 2.0
1,2-Dichloroethane 13.1 ug/L 4 05/16/12 18:10 107-06-22.0 2.0
1,1-Dichloroethene ND ug/L 4 05/16/12 18:10 75-35-42.0 2.0
cis-1,2-Dichloroethene ND ug/L 4 05/16/12 18:10 156-59-22.0 2.0
trans-1,2-Dichloroethene ND ug/L 4 05/16/12 18:10 156-60-52.0 2.0
1,2-Dichloropropane ND ug/L 4 05/16/12 18:10 78-87-52.0 2.0
1,3-Dichloropropane ND ug/L 4 05/16/12 18:10 142-28-92.0 2.0
2,2-Dichloropropane ND ug/L 4 05/16/12 18:10 594-20-72.0 2.0
1,1-Dichloropropene ND ug/L 4 05/16/12 18:10 563-58-62.0 2.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 18 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-5 Lab ID:92118063005 Collected:05/04/12 09:45 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 4 05/16/12 18:10 10061-01-52.0 2.0
trans-1,3-Dichloropropene ND ug/L 4 05/16/12 18:10 10061-02-62.0 2.0
Diisopropyl ether 3.2 ug/L 4 05/16/12 18:10 108-20-32.0 2.0
Ethylbenzene 224 ug/L 4 05/16/12 18:10 100-41-42.0 2.0
Hexachloro-1,3-butadiene ND ug/L 4 05/16/12 18:10 87-68-38.0 8.0
Isopropylbenzene (Cumene)25.4 ug/L 4 05/16/12 18:10 98-82-82.0 2.0
Methylene Chloride ND ug/L 4 05/16/12 18:10 75-09-28.0 8.0
Methyl-tert-butyl ether ND ug/L 4 05/16/12 18:10 1634-04-42.0 2.0
Naphthalene 53.4 ug/L 4 05/16/12 18:10 91-20-38.0 8.0
n-Propylbenzene 46.8 ug/L 4 05/16/12 18:10 103-65-12.0 2.0
Styrene ND ug/L 4 05/16/12 18:10 100-42-52.0 2.0
1,1,1,2-Tetrachloroethane ND ug/L 4 05/16/12 18:10 630-20-62.0 2.0
1,1,2,2-Tetrachloroethane ND ug/L 4 05/16/12 18:10 79-34-52.0 2.0
Tetrachloroethene ND ug/L 4 05/16/12 18:10 127-18-42.0 2.0
Toluene 257 ug/L 4 05/16/12 18:10 108-88-32.0 2.0
1,2,3-Trichlorobenzene ND ug/L 4 05/16/12 18:10 87-61-68.0 8.0
1,2,4-Trichlorobenzene ND ug/L 4 05/16/12 18:10 120-82-18.0 8.0
1,1,1-Trichloroethane ND ug/L 4 05/16/12 18:10 71-55-62.0 2.0
1,1,2-Trichloroethane ND ug/L 4 05/16/12 18:10 79-00-52.0 2.0
Trichloroethene ND ug/L 4 05/16/12 18:10 79-01-62.0 2.0
Trichlorofluoromethane ND ug/L 4 05/16/12 18:10 75-69-44.0 4.0
1,2,3-Trichloropropane ND ug/L 4 05/16/12 18:10 96-18-42.0 2.0
1,2,4-Trimethylbenzene 182 ug/L 4 05/16/12 18:10 95-63-62.0 2.0
1,3,5-Trimethylbenzene 46.9 ug/L 4 05/16/12 18:10 108-67-82.0 2.0
Vinyl chloride ND ug/L 4 05/16/12 18:10 75-01-44.0 4.0
m&p-Xylene 441 ug/L 4 05/16/12 18:10 179601-23-14.0 4.0
o-Xylene 195 ug/L 4 05/16/12 18:10 95-47-62.0 2.0
Surrogates
1,2-Dichloroethane-d4 (S)100 %4 05/16/12 18:10 17060-07-070-130
Dibromofluoromethane (S)100 %4 05/16/12 18:10 1868-53-770-130
4-Bromofluorobenzene (S)97 %4 05/16/12 18:10 460-00-470-130
Toluene-d8 (S)99 %4 05/16/12 18:10 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 19 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-6 Lab ID:92118063006 Collected:05/04/12 09:15 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 23:57 106-93-405/10/12 14:410.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)93 %1 05/11/12 23:57 301-79-5605/10/12 14:4170-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 05/17/12 12:54 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 05/17/12 12:54 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/17/12 12:54 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)87 %1 05/17/12 12:5470-130
2,5-Dibromotoluene (FID)(S)102 %1 05/17/12 12:5470-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 20:14 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 20:14 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 20:14 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 20:14 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 20:14 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 20:14 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 20:14 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 20:14 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 20:14 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 20:14 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 20:14 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 20:14 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 20:14 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 20:14 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 20:14 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 20:14 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 20:14 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 20:14 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 20:14 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 20:14 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 20:14 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 20:14 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 20:14 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 20:14 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 20:14 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 20:14 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 20:14 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 20:14 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 20:14 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 20:14 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 20:14 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 20:14 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 20:14 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 20 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-6 Lab ID:92118063006 Collected:05/04/12 09:15 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 20:14 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 20:14 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 20:14 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 20:14 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 20:14 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 20:14 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 20:14 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 20:14 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 20:14 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 20:14 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 20:14 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 20:14 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 20:14 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 20:14 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 20:14 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 20:14 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 20:14 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 20:14 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 20:14 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 20:14 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 20:14 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 20:14 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 20:14 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 20:14 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 20:14 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 20:14 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 20:14 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)102 %1 05/11/12 20:14 17060-07-070-130
Dibromofluoromethane (S)100 %1 05/11/12 20:14 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 05/11/12 20:14 460-00-470-130
Toluene-d8 (S)101 %1 05/11/12 20:14 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 21 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-7 Lab ID:92118063007 Collected:05/04/12 09:55 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/09/12 22:39 106-93-405/09/12 15:090.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)93 %1 05/09/12 22:39 301-79-5605/09/12 15:0970-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 05/15/12 21:16 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 05/15/12 21:16 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/15/12 21:16 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)78 %1 05/15/12 21:1670-130
2,5-Dibromotoluene (FID)(S)100 %1 05/15/12 21:1670-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 20:31 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 20:31 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 20:31 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 20:31 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 20:31 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 20:31 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 20:31 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 20:31 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 20:31 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 20:31 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 20:31 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 20:31 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 20:31 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 20:31 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 20:31 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 20:31 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 20:31 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 20:31 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 20:31 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 20:31 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 20:31 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 20:31 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 20:31 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 20:31 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 20:31 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 20:31 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 20:31 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 20:31 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 20:31 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 20:31 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 20:31 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 20:31 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 20:31 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 22 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-7 Lab ID:92118063007 Collected:05/04/12 09:55 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 20:31 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 20:31 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 20:31 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 20:31 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 20:31 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 20:31 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 20:31 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 20:31 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 20:31 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 20:31 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 20:31 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 20:31 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 20:31 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 20:31 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 20:31 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 20:31 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 20:31 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 20:31 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 20:31 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 20:31 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 20:31 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 20:31 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 20:31 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 20:31 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 20:31 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 20:31 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 20:31 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)105 %1 05/11/12 20:31 17060-07-070-130
Dibromofluoromethane (S)100 %1 05/11/12 20:31 1868-53-770-130
4-Bromofluorobenzene (S)95 %1 05/11/12 20:31 460-00-470-130
Toluene-d8 (S)101 %1 05/11/12 20:31 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 23 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-8 Lab ID:92118063008 Collected:05/04/12 10:20 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/09/12 22:59 106-93-405/09/12 15:090.019 0.019
Surrogates
1-Chloro-2-bromopropane (S)76 %1 05/09/12 22:59 301-79-5605/09/12 15:0970-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 05/11/12 17:29 N250.0 50.0
Aliphatic (C09-C12)80.2 ug/L 1 05/11/12 17:29 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/11/12 17:29 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)86 %1 05/11/12 17:2970-130
2,5-Dibromotoluene (FID)(S)98 %1 05/11/12 17:2970-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 20:48 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 20:48 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 20:48 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 20:48 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 20:48 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 20:48 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 20:48 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 20:48 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 20:48 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 20:48 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 20:48 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 20:48 75-00-31.0 1.0
Chloroform 6.5 ug/L 1 05/11/12 20:48 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 20:48 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 20:48 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 20:48 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 20:48 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 20:48 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 20:48 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 20:48 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 20:48 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 20:48 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 20:48 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 20:48 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 20:48 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 20:48 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 20:48 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 20:48 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 20:48 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 20:48 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 20:48 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 20:48 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 20:48 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 24 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-8 Lab ID:92118063008 Collected:05/04/12 10:20 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 20:48 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 20:48 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 20:48 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 20:48 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 20:48 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 20:48 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 20:48 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 20:48 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 20:48 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 20:48 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 20:48 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 20:48 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 20:48 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 20:48 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 20:48 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 20:48 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 20:48 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 20:48 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 20:48 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 20:48 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 20:48 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 20:48 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 20:48 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 20:48 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 20:48 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 20:48 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 20:48 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)104 %1 05/11/12 20:48 17060-07-070-130
Dibromofluoromethane (S)100 %1 05/11/12 20:48 1868-53-770-130
4-Bromofluorobenzene (S)95 %1 05/11/12 20:48 460-00-470-130
Toluene-d8 (S)100 %1 05/11/12 20:48 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 25 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-9 Lab ID:92118063009 Collected:05/04/12 10:45 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/09/12 23:19 106-93-405/09/12 15:090.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)92 %1 05/09/12 23:19 301-79-5605/09/12 15:0970-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)753 ug/L 1 05/11/12 17:54 N250.0 50.0
Aliphatic (C09-C12)368 ug/L 1 05/11/12 17:54 N250.0 50.0
Aromatic (C09-C10)135 ug/L 1 05/11/12 17:54 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)89 %1 05/11/12 17:5470-130
2,5-Dibromotoluene (FID)(S)99 %1 05/11/12 17:5470-130
6200B MSV Analytical Method: SM 6200B
Benzene 40.7 ug/L 1 05/11/12 21:04 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 21:04 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 21:04 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 21:04 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 21:04 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 21:04 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 21:04 104-51-80.50 0.50
sec-Butylbenzene 11.3 ug/L 1 05/11/12 21:04 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 21:04 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 21:04 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 21:04 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 21:04 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 21:04 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 21:04 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 21:04 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 21:04 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 21:04 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 21:04 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 21:04 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 21:04 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 21:04 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 21:04 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 21:04 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 21:04 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 21:04 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 21:04 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 21:04 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 21:04 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 21:04 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 21:04 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 21:04 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 21:04 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 21:04 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 26 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-9 Lab ID:92118063009 Collected:05/04/12 10:45 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 21:04 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 21:04 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 21:04 108-20-30.50 0.50
Ethylbenzene 3.7 ug/L 1 05/11/12 21:04 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 21:04 87-68-32.0 2.0
Isopropylbenzene (Cumene)3.6 ug/L 1 05/11/12 21:04 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 21:04 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 21:04 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 21:04 91-20-32.0 2.0
n-Propylbenzene 2.4 ug/L 1 05/11/12 21:04 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 21:04 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 21:04 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 21:04 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 21:04 127-18-40.50 0.50
Toluene 2.4 ug/L 1 05/11/12 21:04 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 21:04 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 21:04 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 21:04 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 21:04 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 21:04 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 21:04 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 21:04 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 21:04 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 21:04 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 21:04 75-01-41.0 1.0
m&p-Xylene 1.9 ug/L 1 05/11/12 21:04 179601-23-11.0 1.0
o-Xylene 1.5 ug/L 1 05/11/12 21:04 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)102 %1 05/11/12 21:04 17060-07-070-130
Dibromofluoromethane (S)99 %1 05/11/12 21:04 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 05/11/12 21:04 460-00-470-130
Toluene-d8 (S)99 %1 05/11/12 21:04 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 27 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-10 Lab ID:92118063010 Collected:05/04/12 10:10 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/09/12 23:40 106-93-405/09/12 15:090.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)97 %1 05/09/12 23:40 301-79-5605/09/12 15:0970-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 05/11/12 18:19 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 05/11/12 18:19 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/11/12 18:19 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)85 %1 05/11/12 18:1970-130
2,5-Dibromotoluene (FID)(S)94 %1 05/11/12 18:1970-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 21:21 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 21:21 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 21:21 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 21:21 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 21:21 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 21:21 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 21:21 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 21:21 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 21:21 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 21:21 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 21:21 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 21:21 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 21:21 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 21:21 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 21:21 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 21:21 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 21:21 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 21:21 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 21:21 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 21:21 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 21:21 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 21:21 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 21:21 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 21:21 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 21:21 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 21:21 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 21:21 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 21:21 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 21:21 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 21:21 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 21:21 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 21:21 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 21:21 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 28 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-10 Lab ID:92118063010 Collected:05/04/12 10:10 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 21:21 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 21:21 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 21:21 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 21:21 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 21:21 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 21:21 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 21:21 75-09-22.0 2.0
Methyl-tert-butyl ether 0.97 ug/L 1 05/11/12 21:21 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 21:21 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 21:21 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 21:21 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 21:21 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 21:21 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 21:21 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 21:21 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 21:21 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 21:21 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 21:21 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 21:21 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 21:21 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 21:21 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 21:21 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 21:21 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 21:21 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 21:21 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 21:21 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 21:21 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)104 %1 05/11/12 21:21 17060-07-070-130
Dibromofluoromethane (S)98 %1 05/11/12 21:21 1868-53-770-130
4-Bromofluorobenzene (S)95 %1 05/11/12 21:21 460-00-470-130
Toluene-d8 (S)101 %1 05/11/12 21:21 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 29 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-11 Lab ID:92118063011 Collected:05/04/12 08:45 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/10/12 00:00 106-93-405/09/12 15:100.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)89 %1 05/10/12 00:00 301-79-5605/09/12 15:1070-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 05/11/12 18:45 N250.0 50.0
Aliphatic (C09-C12)75.4 ug/L 1 05/11/12 18:45 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/11/12 18:45 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)73 %1 05/11/12 18:4570-130
2,5-Dibromotoluene (FID)(S)94 %1 05/11/12 18:4570-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 21:38 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 21:38 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 21:38 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 21:38 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 21:38 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 21:38 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 21:38 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 21:38 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 21:38 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 21:38 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 21:38 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 21:38 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 21:38 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 21:38 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 21:38 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 21:38 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 21:38 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 21:38 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 21:38 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 21:38 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 21:38 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 21:38 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 21:38 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 21:38 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 21:38 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 21:38 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 21:38 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 21:38 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 21:38 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 21:38 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 21:38 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 21:38 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 21:38 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 30 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-11 Lab ID:92118063011 Collected:05/04/12 08:45 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 21:38 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 21:38 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 21:38 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 21:38 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 21:38 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 21:38 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 21:38 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 21:38 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 21:38 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 21:38 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 21:38 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 21:38 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 21:38 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 21:38 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 21:38 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 21:38 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 21:38 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 21:38 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 21:38 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 21:38 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 21:38 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 21:38 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 21:38 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 21:38 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 21:38 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 21:38 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 21:38 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)104 %1 05/11/12 21:38 17060-07-070-130
Dibromofluoromethane (S)99 %1 05/11/12 21:38 1868-53-770-130
4-Bromofluorobenzene (S)95 %1 05/11/12 21:38 460-00-470-130
Toluene-d8 (S)100 %1 05/11/12 21:38 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 31 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-12 Lab ID:92118063012 Collected:05/04/12 11:15 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)32.8 ug/L 50 05/10/12 19:03 106-93-405/09/12 15:100.96 0.96
Surrogates
1-Chloro-2-bromopropane (S)0 %50 05/10/12 19:03 301-79-56 S405/09/12 15:1070-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)19000 ug/L 25 05/12/12 00:12 N212501250
Aliphatic (C09-C12)31100 ug/L 25 05/12/12 00:12 N2,NC12501250
Aromatic (C09-C10)5320 ug/L 25 05/12/12 00:12 N212501250
Surrogates
2,5-Dibromotoluene (PID)(S)86 %25 05/12/12 00:1270-130
2,5-Dibromotoluene (FID)(S)99 %25 05/12/12 00:1270-130
6200B MSV Analytical Method: SM 6200B
Benzene 4950 ug/L 25 05/11/12 21:55 71-43-212.5 12.5
Bromobenzene ND ug/L 25 05/11/12 21:55 108-86-112.5 12.5
Bromochloromethane ND ug/L 25 05/11/12 21:55 74-97-512.5 12.5
Bromodichloromethane ND ug/L 25 05/11/12 21:55 75-27-412.5 12.5
Bromoform ND ug/L 25 05/11/12 21:55 75-25-212.5 12.5
Bromomethane ND ug/L 25 05/11/12 21:55 74-83-912525.0
n-Butylbenzene ND ug/L 25 05/11/12 21:55 104-51-812.5 12.5
sec-Butylbenzene ND ug/L 25 05/11/12 21:55 135-98-812.5 12.5
tert-Butylbenzene ND ug/L 25 05/11/12 21:55 98-06-612.5 12.5
Carbon tetrachloride ND ug/L 25 05/11/12 21:55 56-23-512.5 12.5
Chlorobenzene ND ug/L 25 05/11/12 21:55 108-90-712.5 12.5
Chloroethane ND ug/L 25 05/11/12 21:55 75-00-325.0 25.0
Chloroform ND ug/L 25 05/11/12 21:55 67-66-312.5 12.5
Chloromethane ND ug/L 25 05/11/12 21:55 74-87-325.0 25.0
2-Chlorotoluene ND ug/L 25 05/11/12 21:55 95-49-812.5 12.5
4-Chlorotoluene ND ug/L 25 05/11/12 21:55 106-43-412.5 12.5
1,2-Dibromo-3-chloropropane ND ug/L 25 05/11/12 21:55 96-12-825.0 25.0
Dibromochloromethane ND ug/L 25 05/11/12 21:55 124-48-112.5 12.5
1,2-Dibromoethane (EDB)28.6 ug/L 25 05/11/12 21:55 106-93-412.5 12.5
Dibromomethane ND ug/L 25 05/11/12 21:55 74-95-312.5 12.5
1,2-Dichlorobenzene ND ug/L 25 05/11/12 21:55 95-50-112.5 12.5
1,3-Dichlorobenzene ND ug/L 25 05/11/12 21:55 541-73-112.5 12.5
1,4-Dichlorobenzene ND ug/L 25 05/11/12 21:55 106-46-712.5 12.5
Dichlorodifluoromethane ND ug/L 25 05/11/12 21:55 75-71-812.5 12.5
1,1-Dichloroethane ND ug/L 25 05/11/12 21:55 75-34-312.5 12.5
1,2-Dichloroethane 257 ug/L 25 05/11/12 21:55 107-06-212.5 12.5
1,1-Dichloroethene ND ug/L 25 05/11/12 21:55 75-35-412.5 12.5
cis-1,2-Dichloroethene ND ug/L 25 05/11/12 21:55 156-59-212.5 12.5
trans-1,2-Dichloroethene ND ug/L 25 05/11/12 21:55 156-60-512.5 12.5
1,2-Dichloropropane ND ug/L 25 05/11/12 21:55 78-87-512.5 12.5
1,3-Dichloropropane ND ug/L 25 05/11/12 21:55 142-28-912.5 12.5
2,2-Dichloropropane ND ug/L 25 05/11/12 21:55 594-20-712.5 12.5
1,1-Dichloropropene ND ug/L 25 05/11/12 21:55 563-58-612.5 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 32 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-12 Lab ID:92118063012 Collected:05/04/12 11:15 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 25 05/11/12 21:55 10061-01-512.5 12.5
trans-1,3-Dichloropropene ND ug/L 25 05/11/12 21:55 10061-02-612.5 12.5
Diisopropyl ether 72.7 ug/L 25 05/11/12 21:55 108-20-312.5 12.5
Ethylbenzene 891 ug/L 25 05/11/12 21:55 100-41-412.5 12.5
Hexachloro-1,3-butadiene ND ug/L 25 05/11/12 21:55 87-68-350.0 50.0
Isopropylbenzene (Cumene)95.7 ug/L 25 05/11/12 21:55 98-82-812.5 12.5
Methylene Chloride ND ug/L 25 05/11/12 21:55 75-09-250.0 50.0
Methyl-tert-butyl ether 236 ug/L 25 05/11/12 21:55 1634-04-412.5 12.5
Naphthalene 174 ug/L 25 05/11/12 21:55 91-20-350.0 50.0
n-Propylbenzene 182 ug/L 25 05/11/12 21:55 103-65-112.5 12.5
Styrene ND ug/L 25 05/11/12 21:55 100-42-512.5 12.5
1,1,1,2-Tetrachloroethane ND ug/L 25 05/11/12 21:55 630-20-612.5 12.5
1,1,2,2-Tetrachloroethane ND ug/L 25 05/11/12 21:55 79-34-512.5 12.5
Tetrachloroethene ND ug/L 25 05/11/12 21:55 127-18-412.5 12.5
Toluene 3010 ug/L 25 05/11/12 21:55 108-88-312.5 12.5
1,2,3-Trichlorobenzene ND ug/L 25 05/11/12 21:55 87-61-650.0 50.0
1,2,4-Trichlorobenzene ND ug/L 25 05/11/12 21:55 120-82-150.0 50.0
1,1,1-Trichloroethane ND ug/L 25 05/11/12 21:55 71-55-612.5 12.5
1,1,2-Trichloroethane ND ug/L 25 05/11/12 21:55 79-00-512.5 12.5
Trichloroethene ND ug/L 25 05/11/12 21:55 79-01-612.5 12.5
Trichlorofluoromethane ND ug/L 25 05/11/12 21:55 75-69-425.0 25.0
1,2,3-Trichloropropane ND ug/L 25 05/11/12 21:55 96-18-412.5 12.5
1,2,4-Trimethylbenzene 1510 ug/L 25 05/11/12 21:55 95-63-612.5 12.5
1,3,5-Trimethylbenzene 620 ug/L 25 05/11/12 21:55 108-67-812.5 12.5
Vinyl chloride ND ug/L 25 05/11/12 21:55 75-01-425.0 25.0
m&p-Xylene 3930 ug/L 25 05/11/12 21:55 179601-23-125.0 25.0
o-Xylene 2310 ug/L 25 05/11/12 21:55 95-47-612.5 12.5
Surrogates
1,2-Dichloroethane-d4 (S)101 %25 05/11/12 21:55 17060-07-070-130
Dibromofluoromethane (S)96 %25 05/11/12 21:55 1868-53-770-130
4-Bromofluorobenzene (S)95 %25 05/11/12 21:55 460-00-470-130
Toluene-d8 (S)100 %25 05/11/12 21:55 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 33 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-13 Lab ID:92118063013 Collected:05/04/12 11:05 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/10/12 00:41 106-93-405/09/12 15:100.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)97 %1 05/10/12 00:41 301-79-5605/09/12 15:1070-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 05/15/12 21:41 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 05/15/12 21:41 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/15/12 21:41 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)77 %1 05/15/12 21:4170-130
2,5-Dibromotoluene (FID)(S)92 %1 05/15/12 21:4170-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 22:11 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 22:11 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 22:11 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 22:11 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 22:11 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 22:11 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 22:11 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 22:11 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 22:11 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 22:11 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 22:11 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 22:11 75-00-31.0 1.0
Chloroform 1.5 ug/L 1 05/11/12 22:11 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 22:11 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 22:11 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 22:11 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 22:11 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 22:11 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 22:11 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 22:11 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 22:11 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 22:11 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 22:11 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 22:11 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 22:11 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 22:11 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 22:11 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 22:11 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 22:11 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 22:11 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 22:11 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 22:11 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 22:11 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 34 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-13 Lab ID:92118063013 Collected:05/04/12 11:05 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 22:11 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 22:11 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 22:11 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 22:11 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 22:11 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 22:11 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 22:11 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 22:11 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 22:11 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 22:11 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 22:11 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 22:11 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 22:11 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 22:11 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 22:11 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 22:11 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 22:11 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 22:11 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 22:11 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 22:11 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 22:11 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 22:11 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 22:11 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 22:11 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 22:11 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 22:11 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 22:11 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)102 %1 05/11/12 22:11 17060-07-070-130
Dibromofluoromethane (S)97 %1 05/11/12 22:11 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 05/11/12 22:11 460-00-470-130
Toluene-d8 (S)101 %1 05/11/12 22:11 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 35 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-14 Lab ID:92118063014 Collected:05/04/12 11:00 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/10/12 01:01 106-93-405/09/12 15:100.019 0.019
Surrogates
1-Chloro-2-bromopropane (S)91 %1 05/10/12 01:01 301-79-5605/09/12 15:1070-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)ND ug/L 1 05/15/12 22:07 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 05/15/12 22:07 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/15/12 22:07 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)68 %1 05/15/12 22:07 S270-130
2,5-Dibromotoluene (FID)(S)78 %1 05/15/12 22:0770-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 22:28 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 22:28 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 22:28 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 22:28 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 22:28 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 22:28 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 22:28 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 22:28 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 22:28 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 22:28 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 22:28 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 22:28 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 22:28 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 22:28 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 22:28 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 22:28 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 22:28 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 22:28 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 22:28 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 22:28 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 22:28 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 22:28 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 22:28 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 22:28 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 22:28 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 22:28 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 22:28 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 22:28 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 22:28 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 22:28 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 22:28 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 22:28 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 22:28 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 36 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-14 Lab ID:92118063014 Collected:05/04/12 11:00 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 22:28 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 22:28 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 22:28 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 22:28 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 22:28 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 22:28 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 22:28 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 22:28 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 22:28 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 22:28 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 22:28 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 22:28 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 22:28 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 22:28 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 22:28 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 22:28 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 22:28 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 22:28 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 22:28 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 22:28 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 22:28 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 22:28 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 22:28 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 22:28 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 22:28 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 22:28 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 22:28 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)102 %1 05/11/12 22:28 17060-07-070-130
Dibromofluoromethane (S)98 %1 05/11/12 22:28 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 05/11/12 22:28 460-00-470-130
Toluene-d8 (S)101 %1 05/11/12 22:28 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 37 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-15 Lab ID:92118063015 Collected:05/04/12 09:10 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/10/12 01:22 106-93-405/09/12 15:100.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)91 %1 05/10/12 01:22 301-79-5605/09/12 15:1070-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)714 ug/L 1 05/11/12 20:00 N250.0 50.0
Aliphatic (C09-C12)1450 ug/L 1 05/11/12 20:00 N2,NC50.0 50.0
Aromatic (C09-C10)635 ug/L 1 05/11/12 20:00 N2,NC50.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)78 %1 05/11/12 20:0070-130
2,5-Dibromotoluene (FID)(S)83 %1 05/11/12 20:0070-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 22:45 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 22:45 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 22:45 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 22:45 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 22:45 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 22:45 74-83-95.0 1.0
n-Butylbenzene 13.8 ug/L 1 05/11/12 22:45 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 22:45 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 22:45 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 22:45 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 22:45 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 22:45 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 22:45 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 22:45 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 22:45 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 22:45 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 22:45 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 22:45 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 22:45 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 22:45 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 22:45 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 22:45 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 22:45 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 22:45 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 22:45 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 22:45 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 22:45 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 22:45 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 22:45 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 22:45 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 22:45 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 22:45 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 22:45 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 38 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:MW-15 Lab ID:92118063015 Collected:05/04/12 09:10 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 22:45 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 22:45 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 22:45 108-20-30.50 0.50
Ethylbenzene 22.2 ug/L 1 05/11/12 22:45 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 22:45 87-68-32.0 2.0
Isopropylbenzene (Cumene)11.0 ug/L 1 05/11/12 22:45 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 22:45 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 22:45 1634-04-40.50 0.50
Naphthalene 2.2 ug/L 1 05/11/12 22:45 91-20-32.0 2.0
n-Propylbenzene 28.6 ug/L 1 05/11/12 22:45 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 22:45 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 22:45 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 22:45 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 22:45 127-18-40.50 0.50
Toluene 0.72 ug/L 1 05/11/12 22:45 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 22:45 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 22:45 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 22:45 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 22:45 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 22:45 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 22:45 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 22:45 96-18-40.50 0.50
1,2,4-Trimethylbenzene 139 ug/L 1 05/11/12 22:45 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 22:45 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 22:45 75-01-41.0 1.0
m&p-Xylene 58.5 ug/L 1 05/11/12 22:45 179601-23-11.0 1.0
o-Xylene 23.2 ug/L 1 05/11/12 22:45 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)101 %1 05/11/12 22:45 17060-07-070-130
Dibromofluoromethane (S)97 %1 05/11/12 22:45 1868-53-770-130
4-Bromofluorobenzene (S)95 %1 05/11/12 22:45 460-00-470-130
Toluene-d8 (S)100 %1 05/11/12 22:45 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 39 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:VE-1 Lab ID:92118063016 Collected:05/04/12 11:20 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
504 GCS EDB and DBCP Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
1,2-Dibromoethane (EDB)ND ug/L 1 05/10/12 02:23 106-93-405/09/12 15:100.020 0.020
Surrogates
1-Chloro-2-bromopropane (S)96 %1 05/10/12 02:23 301-79-5605/09/12 15:1070-130
VPH NC Water Analytical Method: MADEP VPH
Aliphatic (C05-C08)73.1 ug/L 1 05/15/12 22:32 N250.0 50.0
Aliphatic (C09-C12)ND ug/L 1 05/15/12 22:32 N250.0 50.0
Aromatic (C09-C10)ND ug/L 1 05/15/12 22:32 N250.0 50.0
Surrogates
2,5-Dibromotoluene (PID)(S)82 %1 05/15/12 22:3270-130
2,5-Dibromotoluene (FID)(S)95 %1 05/15/12 22:3270-130
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 23:01 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 23:01 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 23:01 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 23:01 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 23:01 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 23:01 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 23:01 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 23:01 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 23:01 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 23:01 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 23:01 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 23:01 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 23:01 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 23:01 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 23:01 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 23:01 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 23:01 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 23:01 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 23:01 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 23:01 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 23:01 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 23:01 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 23:01 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 23:01 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 23:01 75-34-30.50 0.50
1,2-Dichloroethane 1.7 ug/L 1 05/11/12 23:01 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 23:01 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 23:01 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 23:01 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 23:01 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 23:01 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 23:01 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 23:01 563-58-60.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 40 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:VE-1 Lab ID:92118063016 Collected:05/04/12 11:20 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 23:01 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 23:01 10061-02-60.50 0.50
Diisopropyl ether 10.6 ug/L 1 05/11/12 23:01 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 23:01 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 23:01 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 23:01 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 23:01 75-09-22.0 2.0
Methyl-tert-butyl ether 48.7 ug/L 1 05/11/12 23:01 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 23:01 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 23:01 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 23:01 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 23:01 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 23:01 79-34-50.50 0.50
Tetrachloroethene ND ug/L 1 05/11/12 23:01 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 23:01 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 23:01 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 23:01 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 23:01 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 23:01 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 23:01 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 23:01 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 23:01 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 23:01 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 23:01 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 23:01 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 23:01 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 23:01 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)102 %1 05/11/12 23:01 17060-07-070-130
Dibromofluoromethane (S)97 %1 05/11/12 23:01 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 05/11/12 23:01 460-00-470-130
Toluene-d8 (S)101 %1 05/11/12 23:01 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 41 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:TRIP BLANK Lab ID:92118063017 Collected:05/04/12 00:00 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/11/12 23:18 71-43-20.50 0.50
Bromobenzene ND ug/L 1 05/11/12 23:18 108-86-10.50 0.50
Bromochloromethane ND ug/L 1 05/11/12 23:18 74-97-50.50 0.50
Bromodichloromethane ND ug/L 1 05/11/12 23:18 75-27-40.50 0.50
Bromoform ND ug/L 1 05/11/12 23:18 75-25-20.50 0.50
Bromomethane ND ug/L 1 05/11/12 23:18 74-83-95.0 1.0
n-Butylbenzene ND ug/L 1 05/11/12 23:18 104-51-80.50 0.50
sec-Butylbenzene ND ug/L 1 05/11/12 23:18 135-98-80.50 0.50
tert-Butylbenzene ND ug/L 1 05/11/12 23:18 98-06-60.50 0.50
Carbon tetrachloride ND ug/L 1 05/11/12 23:18 56-23-50.50 0.50
Chlorobenzene ND ug/L 1 05/11/12 23:18 108-90-70.50 0.50
Chloroethane ND ug/L 1 05/11/12 23:18 75-00-31.0 1.0
Chloroform ND ug/L 1 05/11/12 23:18 67-66-30.50 0.50
Chloromethane ND ug/L 1 05/11/12 23:18 74-87-31.0 1.0
2-Chlorotoluene ND ug/L 1 05/11/12 23:18 95-49-80.50 0.50
4-Chlorotoluene ND ug/L 1 05/11/12 23:18 106-43-40.50 0.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/11/12 23:18 96-12-81.0 1.0
Dibromochloromethane ND ug/L 1 05/11/12 23:18 124-48-10.50 0.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/11/12 23:18 106-93-40.50 0.50
Dibromomethane ND ug/L 1 05/11/12 23:18 74-95-30.50 0.50
1,2-Dichlorobenzene ND ug/L 1 05/11/12 23:18 95-50-10.50 0.50
1,3-Dichlorobenzene ND ug/L 1 05/11/12 23:18 541-73-10.50 0.50
1,4-Dichlorobenzene ND ug/L 1 05/11/12 23:18 106-46-70.50 0.50
Dichlorodifluoromethane ND ug/L 1 05/11/12 23:18 75-71-80.50 0.50
1,1-Dichloroethane ND ug/L 1 05/11/12 23:18 75-34-30.50 0.50
1,2-Dichloroethane ND ug/L 1 05/11/12 23:18 107-06-20.50 0.50
1,1-Dichloroethene ND ug/L 1 05/11/12 23:18 75-35-40.50 0.50
cis-1,2-Dichloroethene ND ug/L 1 05/11/12 23:18 156-59-20.50 0.50
trans-1,2-Dichloroethene ND ug/L 1 05/11/12 23:18 156-60-50.50 0.50
1,2-Dichloropropane ND ug/L 1 05/11/12 23:18 78-87-50.50 0.50
1,3-Dichloropropane ND ug/L 1 05/11/12 23:18 142-28-90.50 0.50
2,2-Dichloropropane ND ug/L 1 05/11/12 23:18 594-20-70.50 0.50
1,1-Dichloropropene ND ug/L 1 05/11/12 23:18 563-58-60.50 0.50
cis-1,3-Dichloropropene ND ug/L 1 05/11/12 23:18 10061-01-50.50 0.50
trans-1,3-Dichloropropene ND ug/L 1 05/11/12 23:18 10061-02-60.50 0.50
Diisopropyl ether ND ug/L 1 05/11/12 23:18 108-20-30.50 0.50
Ethylbenzene ND ug/L 1 05/11/12 23:18 100-41-40.50 0.50
Hexachloro-1,3-butadiene ND ug/L 1 05/11/12 23:18 87-68-32.0 2.0
Isopropylbenzene (Cumene)ND ug/L 1 05/11/12 23:18 98-82-80.50 0.50
Methylene Chloride ND ug/L 1 05/11/12 23:18 75-09-22.0 2.0
Methyl-tert-butyl ether ND ug/L 1 05/11/12 23:18 1634-04-40.50 0.50
Naphthalene ND ug/L 1 05/11/12 23:18 91-20-32.0 2.0
n-Propylbenzene ND ug/L 1 05/11/12 23:18 103-65-10.50 0.50
Styrene ND ug/L 1 05/11/12 23:18 100-42-50.50 0.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/11/12 23:18 630-20-60.50 0.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/11/12 23:18 79-34-50.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 42 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Sample:TRIP BLANK Lab ID:92118063017 Collected:05/04/12 00:00 Received:05/08/12 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
6200B MSV Analytical Method: SM 6200B
Tetrachloroethene ND ug/L 1 05/11/12 23:18 127-18-40.50 0.50
Toluene ND ug/L 1 05/11/12 23:18 108-88-30.50 0.50
1,2,3-Trichlorobenzene ND ug/L 1 05/11/12 23:18 87-61-62.0 2.0
1,2,4-Trichlorobenzene ND ug/L 1 05/11/12 23:18 120-82-12.0 2.0
1,1,1-Trichloroethane ND ug/L 1 05/11/12 23:18 71-55-60.50 0.50
1,1,2-Trichloroethane ND ug/L 1 05/11/12 23:18 79-00-50.50 0.50
Trichloroethene ND ug/L 1 05/11/12 23:18 79-01-60.50 0.50
Trichlorofluoromethane ND ug/L 1 05/11/12 23:18 75-69-41.0 1.0
1,2,3-Trichloropropane ND ug/L 1 05/11/12 23:18 96-18-40.50 0.50
1,2,4-Trimethylbenzene ND ug/L 1 05/11/12 23:18 95-63-60.50 0.50
1,3,5-Trimethylbenzene ND ug/L 1 05/11/12 23:18 108-67-80.50 0.50
Vinyl chloride ND ug/L 1 05/11/12 23:18 75-01-41.0 1.0
m&p-Xylene ND ug/L 1 05/11/12 23:18 179601-23-11.0 1.0
o-Xylene ND ug/L 1 05/11/12 23:18 95-47-60.50 0.50
Surrogates
1,2-Dichloroethane-d4 (S)103 %1 05/11/12 23:18 17060-07-070-130
Dibromofluoromethane (S)96 %1 05/11/12 23:18 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 05/11/12 23:18 460-00-470-130
Toluene-d8 (S)102 %1 05/11/12 23:18 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 43 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/5961
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92118063001, 92118063004, 92118063008, 92118063009, 92118063010, 92118063011, 92118063012,
92118063015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:762897
Associated Lab Samples:92118063001, 92118063004, 92118063008, 92118063009, 92118063010, 92118063011, 92118063012,
92118063015
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N205/11/12 15:28
Aliphatic (C09-C12)ug/L ND 50.0 N205/11/12 15:28
Aromatic (C09-C10)ug/L ND 50.0 N205/11/12 15:28
2,5-Dibromotoluene (FID)(S)%97 70-130 05/11/12 15:28
2,5-Dibromotoluene (PID)(S)%88 70-130 05/11/12 15:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
762898LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
762899
Aliphatic (C05-C08)ug/L 302 N230010170-13098293 3 25
Aliphatic (C09-C12)ug/L 336 N230011230-130111333 1 25
Aromatic (C09-C10)ug/L 97.9 N21009870-1309595.5 2 25
2,5-Dibromotoluene (FID)(S)%98 70-13096
2,5-Dibromotoluene (PID)(S)%89 70-13090
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 44 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/5973
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92118063002, 92118063003, 92118063005, 92118063007, 92118063013, 92118063014, 92118063016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:764183
Associated Lab Samples:92118063002, 92118063003, 92118063005, 92118063007, 92118063013, 92118063014, 92118063016
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N205/15/12 19:36
Aliphatic (C09-C12)ug/L ND 50.0 N205/15/12 19:36
Aromatic (C09-C10)ug/L ND 50.0 N205/15/12 19:36
2,5-Dibromotoluene (FID)(S)%96 70-130 05/15/12 19:36
2,5-Dibromotoluene (PID)(S)%83 70-130 05/15/12 19:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
764184LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
764185
Aliphatic (C05-C08)ug/L 307 N230010270-13099296 4 25
Aliphatic (C09-C12)ug/L 331 N230011030-130108324 2 25
Aromatic (C09-C10)ug/L 92.3 N21009270-1309090.1 2 25
2,5-Dibromotoluene (FID)(S)%98 70-130101
2,5-Dibromotoluene (PID)(S)%89 70-13088
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 45 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/5978
MADEP VPH
MADEP VPH
VPH NC Water
Associated Lab Samples:92118063006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:765267
Associated Lab Samples:92118063006
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 50.0 N205/17/12 12:29
Aliphatic (C09-C12)ug/L ND 50.0 N205/17/12 12:29
Aromatic (C09-C10)ug/L ND 50.0 N205/17/12 12:29
2,5-Dibromotoluene (FID)(S)%101 70-130 05/17/12 12:29
2,5-Dibromotoluene (PID)(S)%87 70-130 05/17/12 12:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
765268LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
765269
Aliphatic (C05-C08)ug/L 309 N230010370-130100301 3 25
Aliphatic (C09-C12)ug/L 321 N230010730-130109326 2 25
Aromatic (C09-C10)ug/L 92.7 N21009370-1309291.7 1 25
2,5-Dibromotoluene (FID)(S)%101 70-130106
2,5-Dibromotoluene (PID)(S)%91 70-13092
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 46 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/19096
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92118063001, 92118063002, 92118063003, 92118063006, 92118063007, 92118063008, 92118063009,
92118063010, 92118063011, 92118063012, 92118063013, 92118063014, 92118063015, 92118063016,
92118063017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:763046
Associated Lab Samples:92118063001, 92118063002, 92118063003, 92118063006, 92118063007, 92118063008, 92118063009,
92118063010, 92118063011, 92118063012, 92118063013, 92118063014, 92118063015, 92118063016,
92118063017
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 05/11/12 17:44
1,1,1-Trichloroethane ug/L ND 0.50 05/11/12 17:44
1,1,2,2-Tetrachloroethane ug/L ND 0.50 05/11/12 17:44
1,1,2-Trichloroethane ug/L ND 0.50 05/11/12 17:44
1,1-Dichloroethane ug/L ND 0.50 05/11/12 17:44
1,1-Dichloroethene ug/L ND 0.50 05/11/12 17:44
1,1-Dichloropropene ug/L ND 0.50 05/11/12 17:44
1,2,3-Trichlorobenzene ug/L ND 2.0 05/11/12 17:44
1,2,3-Trichloropropane ug/L ND 0.50 05/11/12 17:44
1,2,4-Trichlorobenzene ug/L ND 2.0 05/11/12 17:44
1,2,4-Trimethylbenzene ug/L ND 0.50 05/11/12 17:44
1,2-Dibromo-3-chloropropane ug/L ND 1.0 05/11/12 17:44
1,2-Dibromoethane (EDB)ug/L ND 0.50 05/11/12 17:44
1,2-Dichlorobenzene ug/L ND 0.50 05/11/12 17:44
1,2-Dichloroethane ug/L ND 0.50 05/11/12 17:44
1,2-Dichloropropane ug/L ND 0.50 05/11/12 17:44
1,3,5-Trimethylbenzene ug/L ND 0.50 05/11/12 17:44
1,3-Dichlorobenzene ug/L ND 0.50 05/11/12 17:44
1,3-Dichloropropane ug/L ND 0.50 05/11/12 17:44
1,4-Dichlorobenzene ug/L ND 0.50 05/11/12 17:44
2,2-Dichloropropane ug/L ND 0.50 05/11/12 17:44
2-Chlorotoluene ug/L ND 0.50 05/11/12 17:44
4-Chlorotoluene ug/L ND 0.50 05/11/12 17:44
Benzene ug/L ND 0.50 05/11/12 17:44
Bromobenzene ug/L ND 0.50 05/11/12 17:44
Bromochloromethane ug/L ND 0.50 05/11/12 17:44
Bromodichloromethane ug/L ND 0.50 05/11/12 17:44
Bromoform ug/L ND 0.50 05/11/12 17:44
Bromomethane ug/L ND 5.0 05/11/12 17:44
Carbon tetrachloride ug/L ND 0.50 05/11/12 17:44
Chlorobenzene ug/L ND 0.50 05/11/12 17:44
Chloroethane ug/L ND 1.0 05/11/12 17:44
Chloroform ug/L ND 0.50 05/11/12 17:44
Chloromethane ug/L ND 1.0 05/11/12 17:44
cis-1,2-Dichloroethene ug/L ND 0.50 05/11/12 17:44
cis-1,3-Dichloropropene ug/L ND 0.50 05/11/12 17:44
Dibromochloromethane ug/L ND 0.50 05/11/12 17:44
Dibromomethane ug/L ND 0.50 05/11/12 17:44
Dichlorodifluoromethane ug/L ND 0.50 05/11/12 17:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 47 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:763046
Associated Lab Samples:92118063001, 92118063002, 92118063003, 92118063006, 92118063007, 92118063008, 92118063009,
92118063010, 92118063011, 92118063012, 92118063013, 92118063014, 92118063015, 92118063016,
92118063017
Matrix:Water
Analyzed
Diisopropyl ether ug/L ND 0.50 05/11/12 17:44
Ethylbenzene ug/L ND 0.50 05/11/12 17:44
Hexachloro-1,3-butadiene ug/L ND 2.0 05/11/12 17:44
Isopropylbenzene (Cumene)ug/L ND 0.50 05/11/12 17:44
m&p-Xylene ug/L ND 1.0 05/11/12 17:44
Methyl-tert-butyl ether ug/L ND 0.50 05/11/12 17:44
Methylene Chloride ug/L ND 2.0 05/11/12 17:44
n-Butylbenzene ug/L ND 0.50 05/11/12 17:44
n-Propylbenzene ug/L ND 0.50 05/11/12 17:44
Naphthalene ug/L ND 2.0 05/11/12 17:44
o-Xylene ug/L ND 0.50 05/11/12 17:44
sec-Butylbenzene ug/L ND 0.50 05/11/12 17:44
Styrene ug/L ND 0.50 05/11/12 17:44
tert-Butylbenzene ug/L ND 0.50 05/11/12 17:44
Tetrachloroethene ug/L ND 0.50 05/11/12 17:44
Toluene ug/L ND 0.50 05/11/12 17:44
trans-1,2-Dichloroethene ug/L ND 0.50 05/11/12 17:44
trans-1,3-Dichloropropene ug/L ND 0.50 05/11/12 17:44
Trichloroethene ug/L ND 0.50 05/11/12 17:44
Trichlorofluoromethane ug/L ND 1.0 05/11/12 17:44
Vinyl chloride ug/L ND 1.0 05/11/12 17:44
1,2-Dichloroethane-d4 (S)%104 70-130 05/11/12 17:44
4-Bromofluorobenzene (S)%96 70-130 05/11/12 17:44
Dibromofluoromethane (S)%101 70-130 05/11/12 17:44
Toluene-d8 (S)%101 70-130 05/11/12 17:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
763047LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.550 101 60-140
1,1,1-Trichloroethane ug/L 46.350 93 60-140
1,1,2,2-Tetrachloroethane ug/L 49.450 99 60-140
1,1,2-Trichloroethane ug/L 52.950 106 60-140
1,1-Dichloroethane ug/L 44.150 88 60-140
1,1-Dichloroethene ug/L 48.950 98 60-140
1,1-Dichloropropene ug/L 47.850 96 60-140
1,2,3-Trichlorobenzene ug/L 50.350 101 60-140
1,2,3-Trichloropropane ug/L 49.250 98 60-140
1,2,4-Trichlorobenzene ug/L 50.450 101 60-140
1,2,4-Trimethylbenzene ug/L 49.950 100 60-140
1,2-Dibromo-3-chloropropane ug/L 52.650 105 60-140
1,2-Dibromoethane (EDB)ug/L 51.350 103 60-140
1,2-Dichlorobenzene ug/L 50.250 100 60-140
1,2-Dichloroethane ug/L 49.650 99 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 48 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
763047LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 49.250 98 60-140
1,3,5-Trimethylbenzene ug/L 49.850 100 60-140
1,3-Dichlorobenzene ug/L 50.250 100 60-140
1,3-Dichloropropane ug/L 50.750 101 60-140
1,4-Dichlorobenzene ug/L 50.450 101 60-140
2,2-Dichloropropane ug/L 45.850 92 60-140
2-Chlorotoluene ug/L 49.650 99 60-140
4-Chlorotoluene ug/L 51.750 103 60-140
Benzene ug/L 49.750 99 60-140
Bromobenzene ug/L 49.950 100 60-140
Bromochloromethane ug/L 52.450 105 60-140
Bromodichloromethane ug/L 49.050 98 60-140
Bromoform ug/L 55.250 110 60-140
Bromomethane ug/L 43.950 88 60-140
Carbon tetrachloride ug/L 51.150 102 60-140
Chlorobenzene ug/L 49.450 99 60-140
Chloroethane ug/L 42.050 84 60-140
Chloroform ug/L 50.950 102 60-140
Chloromethane ug/L 45.350 91 60-140
cis-1,2-Dichloroethene ug/L 50.250 100 60-140
cis-1,3-Dichloropropene ug/L 50.850 102 60-140
Dibromochloromethane ug/L 53.250 106 60-140
Dibromomethane ug/L 50.650 101 60-140
Dichlorodifluoromethane ug/L 38.050 76 60-140
Diisopropyl ether ug/L 50.650 101 60-140
Ethylbenzene ug/L 49.850 100 60-140
Hexachloro-1,3-butadiene ug/L 50.050 100 60-140
Isopropylbenzene (Cumene)ug/L 44.750 89 60-140
m&p-Xylene ug/L 97.5100 97 60-140
Methyl-tert-butyl ether ug/L 52.350 105 60-140
Methylene Chloride ug/L 55.250 110 60-140
n-Butylbenzene ug/L 51.350 103 60-140
n-Propylbenzene ug/L 48.150 96 60-140
Naphthalene ug/L 50.650 101 60-140
o-Xylene ug/L 47.450 95 60-140
sec-Butylbenzene ug/L 50.450 101 60-140
Styrene ug/L 51.950 104 60-140
tert-Butylbenzene ug/L 48.050 96 60-140
Tetrachloroethene ug/L 47.850 96 60-140
Toluene ug/L 45.150 90 60-140
trans-1,2-Dichloroethene ug/L 48.550 97 60-140
trans-1,3-Dichloropropene ug/L 51.950 104 60-140
Trichloroethene ug/L 49.750 99 60-140
Trichlorofluoromethane ug/L 46.850 94 60-140
Vinyl chloride ug/L 46.750 93 60-140
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%99 70-130
Dibromofluoromethane (S)%104 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 49 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
763047LABORATORY CONTROL SAMPLE:
LCSSpike
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
763048MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92118063007
763049
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 70 60-14075 7 3020ND13.9 14.9
1,1,1-Trichloroethane ug/L 20 70 60-14074 6 3020ND14.0 14.8
1,1,2,2-Tetrachloroethane ug/L 20 70 60-14077 10 3020ND14.0 15.5
1,1,2-Trichloroethane ug/L 20 80 60-14085 7 3020ND16.0 17.0
1,1-Dichloroethane ug/L 20 71 60-14075 5 3020ND14.2 14.9
1,1-Dichloroethene ug/L 20 79 60-14084 6 3020ND15.8 16.8
1,1-Dichloropropene ug/L 20 76 60-14081 6 3020ND15.2 16.2
1,2,3-Trichlorobenzene ug/L 20 72 60-14077 6 3020ND14.5 15.4
1,2,3-Trichloropropane ug/L 20 70 60-14077 10 3020ND13.9 15.4
1,2,4-Trichlorobenzene ug/L 20 73 60-14079 7 3020ND14.7 15.8
1,2,4-Trimethylbenzene ug/L 20 80 60-14084 5 3020ND16.1 16.8
1,2-Dibromo-3-chloropropane ug/L 20 64 60-14073 13 3020ND12.9 14.7
1,2-Dibromoethane (EDB)ug/L 20 74 60-14080 8 3020ND14.9 16.1
1,2-Dichlorobenzene ug/L 20 77 60-14081 5 3020ND15.4 16.1
1,2-Dichloroethane ug/L 20 75 60-14081 8 3020ND14.9 16.1
1,2-Dichloropropane ug/L 20 80 60-14084 5 3020ND15.9 16.8
1,3,5-Trimethylbenzene ug/L 20 80 60-14085 6 3020ND15.9 16.9
1,3-Dichlorobenzene ug/L 20 77 60-14082 6 3020ND15.3 16.3
1,3-Dichloropropane ug/L 20 78 60-14084 7 3020ND15.6 16.8
1,4-Dichlorobenzene ug/L 20 79 60-14084 6 3020ND15.8 16.7
2,2-Dichloropropane ug/L 20 66 60-14068 4 3020ND13.1 13.6
2-Chlorotoluene ug/L 20 80 60-14085 5 3020ND16.1 17.0
4-Chlorotoluene ug/L 20 84 60-14089 6 3020ND16.8 17.8
Benzene ug/L 20 81 60-14085 5 3020ND16.1 16.9
Bromobenzene ug/L 20 79 60-14083 5 3020ND15.8 16.6
Bromochloromethane ug/L 20 79 60-14083 5 3020ND15.8 16.6
Bromodichloromethane ug/L 20 69 60-14074 6 3020ND13.9 14.8
Bromoform ug/L M0205360-14057 8 3020ND10.6 11.5
Bromomethane ug/L M0204960-14058 18 3020ND9.7 11.7
Carbon tetrachloride ug/L 20 71 60-14077 7 3020ND14.2 15.3
Chlorobenzene ug/L 20 78 60-14083 6 3020ND15.6 16.6
Chloroethane ug/L 20 76 60-14079 4 3020ND15.3 15.9
Chloroform ug/L 20 78 60-14081 5 3020ND15.5 16.3
Chloromethane ug/L 20 72 60-14076 6 3020ND14.3 15.3
cis-1,2-Dichloroethene ug/L 20 79 60-14084 6 3020ND15.8 16.8
cis-1,3-Dichloropropene ug/L 20 73 60-14077 6 3020ND14.5 15.4
Dibromochloromethane ug/L 20 64 60-14068 7 3020ND12.8 13.6
Dibromomethane ug/L 20 74 60-14079 6 3020ND14.8 15.8
Dichlorodifluoromethane ug/L 20 60 60-14062 4 3020ND12.0 12.4
Diisopropyl ether ug/L 20 78 60-14084 7 3020ND15.6 16.7
Ethylbenzene ug/L 20 80 60-14084 6 3020ND15.9 16.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 50 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
763048MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92118063007
763049
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Hexachloro-1,3-butadiene ug/L 20 70 60-14075 7 3020ND14.0 14.9
Isopropylbenzene (Cumene)ug/L 20 70 60-14074 5 3020ND14.1 14.8
m&p-Xylene ug/L 40 79 60-14083 5 3040ND31.5 33.2
Methyl-tert-butyl ether ug/L 20 75 60-14081 7 3020ND15.0 16.1
Methylene Chloride ug/L 20 82 60-14088 8 3020ND16.3 17.7
n-Butylbenzene ug/L 20 83 60-14088 6 3020ND16.5 17.6
n-Propylbenzene ug/L 20 80 60-14083 4 3020ND16.0 16.6
Naphthalene ug/L 20 72 60-14079 9 3020ND14.4 15.8
o-Xylene ug/L 20 74 60-14078 6 3020ND14.7 15.6
sec-Butylbenzene ug/L 20 81 60-14086 6 3020ND16.3 17.3
Styrene ug/L 20 79 60-14084 5 3020ND15.9 16.8
tert-Butylbenzene ug/L 20 77 60-14081 5 3020ND15.4 16.1
Tetrachloroethene ug/L 20 75 60-14081 8 3020ND15.0 16.2
Toluene ug/L 20 73 60-14076 4 3020ND14.6 15.2
trans-1,2-Dichloroethene ug/L 20 76 60-14082 7 3020ND15.3 16.3
trans-1,3-Dichloropropene ug/L 20 71 60-14076 6 3020ND14.2 15.2
Trichloroethene ug/L 20 79 60-14082 4 3020ND15.7 16.4
Trichlorofluoromethane ug/L 20 74 60-14077 4 3020ND14.7 15.3
Vinyl chloride ug/L 20 76 60-14082 8 3020ND15.1 16.5
1,2-Dichloroethane-d4 (S)%98 70-13098
4-Bromofluorobenzene (S)%94 70-13095
Dibromofluoromethane (S)%98 70-13099
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 51 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/19107
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92118063005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:763583
Associated Lab Samples:92118063005
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 05/16/12 15:48
1,1,1-Trichloroethane ug/L ND 0.50 05/16/12 15:48
1,1,2,2-Tetrachloroethane ug/L ND 0.50 05/16/12 15:48
1,1,2-Trichloroethane ug/L ND 0.50 05/16/12 15:48
1,1-Dichloroethane ug/L ND 0.50 05/16/12 15:48
1,1-Dichloroethene ug/L ND 0.50 05/16/12 15:48
1,1-Dichloropropene ug/L ND 0.50 05/16/12 15:48
1,2,3-Trichlorobenzene ug/L ND 2.0 05/16/12 15:48
1,2,3-Trichloropropane ug/L ND 0.50 05/16/12 15:48
1,2,4-Trichlorobenzene ug/L ND 2.0 05/16/12 15:48
1,2,4-Trimethylbenzene ug/L ND 0.50 05/16/12 15:48
1,2-Dibromo-3-chloropropane ug/L ND 1.0 05/16/12 15:48
1,2-Dibromoethane (EDB)ug/L ND 0.50 05/16/12 15:48
1,2-Dichlorobenzene ug/L ND 0.50 05/16/12 15:48
1,2-Dichloroethane ug/L ND 0.50 05/16/12 15:48
1,2-Dichloropropane ug/L ND 0.50 05/16/12 15:48
1,3,5-Trimethylbenzene ug/L ND 0.50 05/16/12 15:48
1,3-Dichlorobenzene ug/L ND 0.50 05/16/12 15:48
1,3-Dichloropropane ug/L ND 0.50 05/16/12 15:48
1,4-Dichlorobenzene ug/L ND 0.50 05/16/12 15:48
2,2-Dichloropropane ug/L ND 0.50 05/16/12 15:48
2-Chlorotoluene ug/L ND 0.50 05/16/12 15:48
4-Chlorotoluene ug/L ND 0.50 05/16/12 15:48
Benzene ug/L ND 0.50 05/16/12 15:48
Bromobenzene ug/L ND 0.50 05/16/12 15:48
Bromochloromethane ug/L ND 0.50 05/16/12 15:48
Bromodichloromethane ug/L ND 0.50 05/16/12 15:48
Bromoform ug/L ND 0.50 05/16/12 15:48
Bromomethane ug/L ND 5.0 05/16/12 15:48
Carbon tetrachloride ug/L ND 0.50 05/16/12 15:48
Chlorobenzene ug/L ND 0.50 05/16/12 15:48
Chloroethane ug/L ND 1.0 05/16/12 15:48
Chloroform ug/L ND 0.50 05/16/12 15:48
Chloromethane ug/L ND 1.0 05/16/12 15:48
cis-1,2-Dichloroethene ug/L ND 0.50 05/16/12 15:48
cis-1,3-Dichloropropene ug/L ND 0.50 05/16/12 15:48
Dibromochloromethane ug/L ND 0.50 05/16/12 15:48
Dibromomethane ug/L ND 0.50 05/16/12 15:48
Dichlorodifluoromethane ug/L ND 0.50 05/16/12 15:48
Diisopropyl ether ug/L ND 0.50 05/16/12 15:48
Ethylbenzene ug/L ND 0.50 05/16/12 15:48
Hexachloro-1,3-butadiene ug/L ND 2.0 05/16/12 15:48
Isopropylbenzene (Cumene)ug/L ND 0.50 05/16/12 15:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 52 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:763583
Associated Lab Samples:92118063005
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 05/16/12 15:48
Methyl-tert-butyl ether ug/L ND 0.50 05/16/12 15:48
Methylene Chloride ug/L ND 2.0 05/16/12 15:48
n-Butylbenzene ug/L ND 0.50 05/16/12 15:48
n-Propylbenzene ug/L ND 0.50 05/16/12 15:48
Naphthalene ug/L ND 2.0 05/16/12 15:48
o-Xylene ug/L ND 0.50 05/16/12 15:48
sec-Butylbenzene ug/L ND 0.50 05/16/12 15:48
Styrene ug/L ND 0.50 05/16/12 15:48
tert-Butylbenzene ug/L ND 0.50 05/16/12 15:48
Tetrachloroethene ug/L ND 0.50 05/16/12 15:48
Toluene ug/L ND 0.50 05/16/12 15:48
trans-1,2-Dichloroethene ug/L ND 0.50 05/16/12 15:48
trans-1,3-Dichloropropene ug/L ND 0.50 05/16/12 15:48
Trichloroethene ug/L ND 0.50 05/16/12 15:48
Trichlorofluoromethane ug/L ND 1.0 05/16/12 15:48
Vinyl chloride ug/L ND 1.0 05/16/12 15:48
1,2-Dichloroethane-d4 (S)%101 70-130 05/16/12 15:48
4-Bromofluorobenzene (S)%98 70-130 05/16/12 15:48
Dibromofluoromethane (S)%98 70-130 05/16/12 15:48
Toluene-d8 (S)%99 70-130 05/16/12 15:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
763584LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 43.350 87 60-140
1,1,1-Trichloroethane ug/L 37.950 76 60-140
1,1,2,2-Tetrachloroethane ug/L 37.650 75 60-140
1,1,2-Trichloroethane ug/L 41.750 83 60-140
1,1-Dichloroethane ug/L 36.050 72 60-140
1,1-Dichloroethene ug/L 39.550 79 60-140
1,1-Dichloropropene ug/L 39.250 78 60-140
1,2,3-Trichlorobenzene ug/L 40.650 81 60-140
1,2,3-Trichloropropane ug/L 37.450 75 60-140
1,2,4-Trichlorobenzene ug/L 42.050 84 60-140
1,2,4-Trimethylbenzene ug/L 42.450 85 60-140
1,2-Dibromo-3-chloropropane ug/L 38.950 78 60-140
1,2-Dibromoethane (EDB)ug/L 41.550 83 60-140
1,2-Dichlorobenzene ug/L 40.650 81 60-140
1,2-Dichloroethane ug/L 39.350 79 60-140
1,2-Dichloropropane ug/L 40.150 80 60-140
1,3,5-Trimethylbenzene ug/L 41.450 83 60-140
1,3-Dichlorobenzene ug/L 40.750 81 60-140
1,3-Dichloropropane ug/L 40.450 81 60-140
1,4-Dichlorobenzene ug/L 38.950 78 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 53 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
763584LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 38.150 76 60-140
2-Chlorotoluene ug/L 41.350 83 60-140
4-Chlorotoluene ug/L 41.750 83 60-140
Benzene ug/L 40.750 81 60-140
Bromobenzene ug/L 40.450 81 60-140
Bromochloromethane ug/L 42.450 85 60-140
Bromodichloromethane ug/L 41.550 83 60-140
Bromoform ug/L 46.250 92 60-140
Bromomethane ug/L 48.850 98 60-140
Carbon tetrachloride ug/L 42.950 86 60-140
Chlorobenzene ug/L 39.850 80 60-140
Chloroethane ug/L 41.150 82 60-140
Chloroform ug/L 41.050 82 60-140
Chloromethane ug/L 42.150 84 60-140
cis-1,2-Dichloroethene ug/L 40.250 80 60-140
cis-1,3-Dichloropropene ug/L 43.250 86 60-140
Dibromochloromethane ug/L 44.850 90 60-140
Dibromomethane ug/L 40.650 81 60-140
Dichlorodifluoromethane ug/L 36.050 72 60-140
Diisopropyl ether ug/L 43.450 87 60-140
Ethylbenzene ug/L 40.250 80 60-140
Hexachloro-1,3-butadiene ug/L 41.250 82 60-140
Isopropylbenzene (Cumene)ug/L 37.550 75 60-140
m&p-Xylene ug/L 81.6100 82 60-140
Methyl-tert-butyl ether ug/L 43.450 87 60-140
Methylene Chloride ug/L 47.950 96 60-140
n-Butylbenzene ug/L 42.450 85 60-140
n-Propylbenzene ug/L 40.150 80 60-140
Naphthalene ug/L 40.850 82 60-140
o-Xylene ug/L 39.550 79 60-140
sec-Butylbenzene ug/L 40.450 81 60-140
Styrene ug/L 43.050 86 60-140
tert-Butylbenzene ug/L 40.050 80 60-140
Tetrachloroethene ug/L 39.550 79 60-140
Toluene ug/L 39.150 78 60-140
trans-1,2-Dichloroethene ug/L 39.050 78 60-140
trans-1,3-Dichloropropene ug/L 43.950 88 60-140
Trichloroethene ug/L 40.350 81 60-140
Trichlorofluoromethane ug/L 44.650 89 60-140
Vinyl chloride ug/L 43.950 88 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Dibromofluoromethane (S)%102 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 54 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
765098MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92118321007
765099
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 92 60-14089 2 3020ND18.3 17.9
1,1,1-Trichloroethane ug/L 20 85 60-14083 1 3020ND16.9 16.7
1,1,2,2-Tetrachloroethane ug/L 20 82 60-14079 4 3020ND16.5 15.9
1,1,2-Trichloroethane ug/L 20 94 60-14090 4 3020ND18.7 18.0
1,1-Dichloroethane ug/L 20 83 60-14081 2 3020ND16.6 16.2
1,1-Dichloroethene ug/L 20 91 60-14089 2 3020ND18.2 17.9
1,1-Dichloropropene ug/L 20 90 60-14086 4 3020ND17.9 17.1
1,2,3-Trichlorobenzene ug/L 20 86 60-14083 4 3020ND17.3 16.6
1,2,3-Trichloropropane ug/L 20 85 60-14080 6 3020ND17.0 16.0
1,2,4-Trichlorobenzene ug/L 20 88 60-14085 4 3020ND17.7 17.0
1,2,4-Trimethylbenzene ug/L 20 96 60-14093 3 3020ND19.1 18.6
1,2-Dibromo-3-chloropropane ug/L 20 77 60-14074 4 3020ND15.5 14.9
1,2-Dibromoethane (EDB)ug/L 20 91 60-14087 4 3020ND18.1 17.4
1,2-Dichlorobenzene ug/L 20 89 60-14086 4 3020ND17.8 17.1
1,2-Dichloroethane ug/L 20 90 60-14087 4 3020ND18.0 17.3
1,2-Dichloropropane ug/L 20 91 60-14089 3 3020ND18.3 17.8
1,3,5-Trimethylbenzene ug/L 20 94 60-14091 3 3020ND18.8 18.2
1,3-Dichlorobenzene ug/L 20 90 60-14087 4 3020ND18.0 17.4
1,3-Dichloropropane ug/L 20 91 60-14089 2 3020ND18.1 17.7
1,4-Dichlorobenzene ug/L 20 89 60-14085 4 3020ND17.8 17.0
2,2-Dichloropropane ug/L 20 79 60-14077 2 3020ND15.8 15.5
2-Chlorotoluene ug/L 20 93 60-14090 3 3020ND18.7 18.1
4-Chlorotoluene ug/L 20 96 60-14092 4 3020ND19.1 18.3
Benzene ug/L 20 95 60-14091 3 3020ND18.9 18.3
Bromobenzene ug/L 20 88 60-14087 2 3020ND17.7 17.3
Bromochloromethane ug/L 20 93 60-14092 1 3020ND18.5 18.3
Bromodichloromethane ug/L 20 87 60-14086 2 3020ND17.5 17.2
Bromoform ug/L 20 75 60-14075 0 3020ND15.0 14.9
Bromomethane ug/L 20 121 60-140121 1 3020ND24.3 24.1
Carbon tetrachloride ug/L 20 91 60-14090 1 3020ND18.3 18.1
Chlorobenzene ug/L 20 91 60-14090 2 3020ND18.2 17.9
Chloroethane ug/L 20 92 60-14088 4 3020ND18.5 17.7
Chloroform ug/L 20 92 60-14090 2 3020ND18.4 18.0
Chloromethane ug/L 20 91 60-14091 0 3020ND18.2 18.3
cis-1,2-Dichloroethene ug/L 20 91 60-14090 2 3020ND18.3 18.0
cis-1,3-Dichloropropene ug/L 20 88 60-14086 2 3020ND17.5 17.2
Dibromochloromethane ug/L 20 86 60-14085 1 3020ND17.2 17.1
Dibromomethane ug/L 20 91 60-14086 5 3020ND18.1 17.3
Dichlorodifluoromethane ug/L 20 81 60-14078 3 3020ND16.1 15.6
Diisopropyl ether ug/L 20 97 60-14094 3 3020ND19.3 18.7
Ethylbenzene ug/L 20 93 60-14091 2 3020ND18.6 18.2
Hexachloro-1,3-butadiene ug/L 20 87 60-14087 0 3020ND17.4 17.3
Isopropylbenzene (Cumene)ug/L 20 84 60-14082 3 3020ND16.8 16.3
m&p-Xylene ug/L 40 94 60-14091 3 3040ND37.7 36.6
Methyl-tert-butyl ether ug/L 20 95 60-14092 4 3020ND19.0 18.3
Methylene Chloride ug/L 20 103 60-140101 2 3020ND20.6 20.2
n-Butylbenzene ug/L 20 95 60-14091 4 3020ND19.0 18.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 55 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
765098MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92118321007
765099
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 92 60-14089 3 3020ND18.3 17.8
Naphthalene ug/L 20 86 60-14082 5 3020ND17.2 16.3
o-Xylene ug/L 20 88 60-14086 2 3020ND17.6 17.3
sec-Butylbenzene ug/L 20 93 60-14091 3 3020ND18.6 18.1
Styrene ug/L 20 95 60-14093 2 3020ND18.9 18.6
tert-Butylbenzene ug/L 20 92 60-14088 5 3020ND18.4 17.6
Tetrachloroethene ug/L 20 89 60-14086 4 3020ND17.8 17.2
Toluene ug/L 20 90 60-14087 3 3020ND18.0 17.4
trans-1,2-Dichloroethene ug/L 20 89 60-14087 3 3020ND17.9 17.4
trans-1,3-Dichloropropene ug/L 20 87 60-14088 1 3020ND17.5 17.6
Trichloroethene ug/L 20 93 60-14090 3 3020ND18.6 18.0
Trichlorofluoromethane ug/L 20 103 60-14099 4 3020ND20.6 19.9
Vinyl chloride ug/L 20 100 60-14098 2 3020ND20.0 19.6
1,2-Dichloroethane-d4 (S)%99 70-13098
4-Bromofluorobenzene (S)%98 70-130100
Dibromofluoromethane (S)%100 70-130100
Toluene-d8 (S)%100 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 56 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/19169
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92118063004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:766342
Associated Lab Samples:92118063004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 05/18/12 13:38
1,1,1-Trichloroethane ug/L ND 0.50 05/18/12 13:38
1,1,2,2-Tetrachloroethane ug/L ND 0.50 05/18/12 13:38
1,1,2-Trichloroethane ug/L ND 0.50 05/18/12 13:38
1,1-Dichloroethane ug/L ND 0.50 05/18/12 13:38
1,1-Dichloroethene ug/L ND 0.50 05/18/12 13:38
1,1-Dichloropropene ug/L ND 0.50 05/18/12 13:38
1,2,3-Trichlorobenzene ug/L ND 2.0 05/18/12 13:38
1,2,3-Trichloropropane ug/L ND 0.50 05/18/12 13:38
1,2,4-Trichlorobenzene ug/L ND 2.0 05/18/12 13:38
1,2,4-Trimethylbenzene ug/L ND 0.50 05/18/12 13:38
1,2-Dibromo-3-chloropropane ug/L ND 1.0 05/18/12 13:38
1,2-Dibromoethane (EDB)ug/L ND 0.50 05/18/12 13:38
1,2-Dichlorobenzene ug/L ND 0.50 05/18/12 13:38
1,2-Dichloroethane ug/L ND 0.50 05/18/12 13:38
1,2-Dichloropropane ug/L ND 0.50 05/18/12 13:38
1,3,5-Trimethylbenzene ug/L ND 0.50 05/18/12 13:38
1,3-Dichlorobenzene ug/L ND 0.50 05/18/12 13:38
1,3-Dichloropropane ug/L ND 0.50 05/18/12 13:38
1,4-Dichlorobenzene ug/L ND 0.50 05/18/12 13:38
2,2-Dichloropropane ug/L ND 0.50 05/18/12 13:38
2-Chlorotoluene ug/L ND 0.50 05/18/12 13:38
4-Chlorotoluene ug/L ND 0.50 05/18/12 13:38
Benzene ug/L ND 0.50 05/18/12 13:38
Bromobenzene ug/L ND 0.50 05/18/12 13:38
Bromochloromethane ug/L ND 0.50 05/18/12 13:38
Bromodichloromethane ug/L ND 0.50 05/18/12 13:38
Bromoform ug/L ND 0.50 05/18/12 13:38
Bromomethane ug/L ND 5.0 05/18/12 13:38
Carbon tetrachloride ug/L ND 0.50 05/18/12 13:38
Chlorobenzene ug/L ND 0.50 05/18/12 13:38
Chloroethane ug/L ND 1.0 05/18/12 13:38
Chloroform ug/L ND 0.50 05/18/12 13:38
Chloromethane ug/L ND 1.0 05/18/12 13:38
cis-1,2-Dichloroethene ug/L ND 0.50 05/18/12 13:38
cis-1,3-Dichloropropene ug/L ND 0.50 05/18/12 13:38
Dibromochloromethane ug/L ND 0.50 05/18/12 13:38
Dibromomethane ug/L ND 0.50 05/18/12 13:38
Dichlorodifluoromethane ug/L ND 0.50 05/18/12 13:38
Diisopropyl ether ug/L ND 0.50 05/18/12 13:38
Ethylbenzene ug/L ND 0.50 05/18/12 13:38
Hexachloro-1,3-butadiene ug/L ND 2.0 05/18/12 13:38
Isopropylbenzene (Cumene)ug/L ND 0.50 05/18/12 13:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 57 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:766342
Associated Lab Samples:92118063004
Matrix:Water
Analyzed
m&p-Xylene ug/L ND 1.0 05/18/12 13:38
Methyl-tert-butyl ether ug/L ND 0.50 05/18/12 13:38
Methylene Chloride ug/L ND 2.0 05/18/12 13:38
n-Butylbenzene ug/L ND 0.50 05/18/12 13:38
n-Propylbenzene ug/L ND 0.50 05/18/12 13:38
Naphthalene ug/L ND 2.0 05/18/12 13:38
o-Xylene ug/L ND 0.50 05/18/12 13:38
sec-Butylbenzene ug/L ND 0.50 05/18/12 13:38
Styrene ug/L ND 0.50 05/18/12 13:38
tert-Butylbenzene ug/L ND 0.50 05/18/12 13:38
Tetrachloroethene ug/L ND 0.50 05/18/12 13:38
Toluene ug/L ND 0.50 05/18/12 13:38
trans-1,2-Dichloroethene ug/L ND 0.50 05/18/12 13:38
trans-1,3-Dichloropropene ug/L ND 0.50 05/18/12 13:38
Trichloroethene ug/L ND 0.50 05/18/12 13:38
Trichlorofluoromethane ug/L ND 1.0 05/18/12 13:38
Vinyl chloride ug/L ND 1.0 05/18/12 13:38
1,2-Dichloroethane-d4 (S)%111 70-130 05/18/12 13:38
4-Bromofluorobenzene (S)%104 70-130 05/18/12 13:38
Dibromofluoromethane (S)%102 70-130 05/18/12 13:38
Toluene-d8 (S)%99 70-130 05/18/12 13:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
766343LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 42.950 86 60-140
1,1,1-Trichloroethane ug/L 36.450 73 60-140
1,1,2,2-Tetrachloroethane ug/L 37.850 76 60-140
1,1,2-Trichloroethane ug/L 42.150 84 60-140
1,1-Dichloroethane ug/L 33.350 67 60-140
1,1-Dichloroethene ug/L 36.350 73 60-140
1,1-Dichloropropene ug/L 37.250 74 60-140
1,2,3-Trichlorobenzene ug/L 40.650 81 60-140
1,2,3-Trichloropropane ug/L 38.750 77 60-140
1,2,4-Trichlorobenzene ug/L 40.950 82 60-140
1,2,4-Trimethylbenzene ug/L 41.150 82 60-140
1,2-Dibromo-3-chloropropane ug/L 38.950 78 60-140
1,2-Dibromoethane (EDB)ug/L 41.950 84 60-140
1,2-Dichlorobenzene ug/L 40.050 80 60-140
1,2-Dichloroethane ug/L 37.750 75 60-140
1,2-Dichloropropane ug/L 39.450 79 60-140
1,3,5-Trimethylbenzene ug/L 40.650 81 60-140
1,3-Dichlorobenzene ug/L 40.150 80 60-140
1,3-Dichloropropane ug/L 40.350 81 60-140
1,4-Dichlorobenzene ug/L 39.050 78 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 58 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
766343LABORATORY CONTROL SAMPLE:
LCSSpike
2,2-Dichloropropane ug/L 29.950 60 60-140
2-Chlorotoluene ug/L 39.950 80 60-140
4-Chlorotoluene ug/L 40.850 82 60-140
Benzene ug/L 39.850 80 60-140
Bromobenzene ug/L 38.750 77 60-140
Bromochloromethane ug/L 41.850 84 60-140
Bromodichloromethane ug/L 40.450 81 60-140
Bromoform ug/L 41.650 83 60-140
Bromomethane ug/L 42.550 85 60-140
Carbon tetrachloride ug/L 41.850 84 60-140
Chlorobenzene ug/L 39.550 79 60-140
Chloroethane ug/L 33.850 68 60-140
Chloroform ug/L 39.350 79 60-140
Chloromethane ug/L 37.350 75 60-140
cis-1,2-Dichloroethene ug/L 38.550 77 60-140
cis-1,3-Dichloropropene ug/L 40.750 81 60-140
Dibromochloromethane ug/L 43.050 86 60-140
Dibromomethane ug/L 41.650 83 60-140
Dichlorodifluoromethane ug/L 29.0 L0505860-140
Diisopropyl ether ug/L 39.650 79 60-140
Ethylbenzene ug/L 39.750 79 60-140
Hexachloro-1,3-butadiene ug/L 39.850 80 60-140
Isopropylbenzene (Cumene)ug/L 36.150 72 60-140
m&p-Xylene ug/L 79.2100 79 60-140
Methyl-tert-butyl ether ug/L 41.150 82 60-140
Methylene Chloride ug/L 43.550 87 60-140
n-Butylbenzene ug/L 40.550 81 60-140
n-Propylbenzene ug/L 38.650 77 60-140
Naphthalene ug/L 41.350 83 60-140
o-Xylene ug/L 38.650 77 60-140
sec-Butylbenzene ug/L 39.250 78 60-140
Styrene ug/L 42.250 84 60-140
tert-Butylbenzene ug/L 39.450 79 60-140
Tetrachloroethene ug/L 38.750 77 60-140
Toluene ug/L 38.550 77 60-140
trans-1,2-Dichloroethene ug/L 36.050 72 60-140
trans-1,3-Dichloropropene ug/L 42.650 85 60-140
Trichloroethene ug/L 40.550 81 60-140
Trichlorofluoromethane ug/L 40.250 80 60-140
Vinyl chloride ug/L 38.250 76 60-140
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%101 70-130
Dibromofluoromethane (S)%99 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 59 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/17430
EPA 504.1
EPA 504.1
GCS 504 EDB DBCP
Associated Lab Samples:92118063001, 92118063002, 92118063003, 92118063004, 92118063005, 92118063007, 92118063008,
92118063009, 92118063010, 92118063011, 92118063012, 92118063013, 92118063014, 92118063015,
92118063016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:761249
Associated Lab Samples:92118063001, 92118063002, 92118063003, 92118063004, 92118063005, 92118063007, 92118063008,
92118063009, 92118063010, 92118063011, 92118063012, 92118063013, 92118063014, 92118063015,
92118063016
Matrix:Water
Analyzed
1,2-Dibromoethane (EDB)ug/L ND 0.020 05/09/12 18:34
1-Chloro-2-bromopropane (S)%103 70-130 05/09/12 18:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
761250LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
761251
1,2-Dibromoethane (EDB)ug/L 0.27.29 96 70-130960.27 0 20
1-Chloro-2-bromopropane (S)%98 70-13099
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
761252MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92118063015
761253
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dibromoethane (EDB)ug/L .28 88 65-13586 2 20.28ND 0.25 0.24
1-Chloro-2-bromopropane (S)%94 70-13093
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92118063016
761254SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 20ND
1-Chloro-2-bromopropane (S)%99 496
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 60 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/17448
EPA 504.1
EPA 504.1
GCS 504 EDB DBCP
Associated Lab Samples:92118063006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:762130
Associated Lab Samples:92118063006
Matrix:Water
Analyzed
1,2-Dibromoethane (EDB)ug/L ND 0.020 05/11/12 22:56
1-Chloro-2-bromopropane (S)%102 70-130 05/11/12 22:56
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
762131LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
762132
1,2-Dibromoethane (EDB)ug/L 0.27.28 94 70-130980.28 4 20
1-Chloro-2-bromopropane (S)%102 70-130100
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
762133MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92118212007
762134
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dibromoethane (EDB)ug/L .28 88 65-13588 0 20.28ND 0.25 0.25
1-Chloro-2-bromopropane (S)%99 70-13099
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92118212008
762135SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 20ND
1-Chloro-2-bromopropane (S)%98 4100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 61 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
The lab does not hold TNI accreditation for this parameter.N2
Results acceptable because non-target analyte peak heights do not exceed the maximum calibrated upper range of the
system per Section 9.5.8 of the MADEP VPH method.NC
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample
re-analysis).S2
Surrogate recovery not evaluated against control limits due to sample dilution.S4
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 62 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92118063001 OEXT/17430 GCSV/11964MW-1A EPA 504.1 EPA 504.1
92118063002 OEXT/17430 GCSV/11964MW-2 EPA 504.1 EPA 504.1
92118063003 OEXT/17430 GCSV/11964MW-3 EPA 504.1 EPA 504.1
92118063004 OEXT/17430 GCSV/11964MW-4 EPA 504.1 EPA 504.1
92118063005 OEXT/17430 GCSV/11964MW-5 EPA 504.1 EPA 504.1
92118063006 OEXT/17448 GCSV/11971MW-6 EPA 504.1 EPA 504.1
92118063007 OEXT/17430 GCSV/11964MW-7 EPA 504.1 EPA 504.1
92118063008 OEXT/17430 GCSV/11964MW-8 EPA 504.1 EPA 504.1
92118063009 OEXT/17430 GCSV/11964MW-9 EPA 504.1 EPA 504.1
92118063010 OEXT/17430 GCSV/11964MW-10 EPA 504.1 EPA 504.1
92118063011 OEXT/17430 GCSV/11964MW-11 EPA 504.1 EPA 504.1
92118063012 OEXT/17430 GCSV/11964MW-12 EPA 504.1 EPA 504.1
92118063013 OEXT/17430 GCSV/11964MW-13 EPA 504.1 EPA 504.1
92118063014 OEXT/17430 GCSV/11964MW-14 EPA 504.1 EPA 504.1
92118063015 OEXT/17430 GCSV/11964MW-15 EPA 504.1 EPA 504.1
92118063016 OEXT/17430 GCSV/11964VE-1 EPA 504.1 EPA 504.1
92118063001 GCV/5961MW-1A MADEP VPH
92118063002 GCV/5973MW-2 MADEP VPH
92118063003 GCV/5973MW-3 MADEP VPH
92118063004 GCV/5961MW-4 MADEP VPH
92118063005 GCV/5973MW-5 MADEP VPH
92118063006 GCV/5978MW-6 MADEP VPH
92118063007 GCV/5973MW-7 MADEP VPH
92118063008 GCV/5961MW-8 MADEP VPH
92118063009 GCV/5961MW-9 MADEP VPH
92118063010 GCV/5961MW-10 MADEP VPH
92118063011 GCV/5961MW-11 MADEP VPH
92118063012 GCV/5961MW-12 MADEP VPH
92118063013 GCV/5973MW-13 MADEP VPH
92118063014 GCV/5973MW-14 MADEP VPH
92118063015 GCV/5961MW-15 MADEP VPH
92118063016 GCV/5973VE-1 MADEP VPH
92118063001 MSV/19096MW-1A SM 6200B
92118063002 MSV/19096MW-2 SM 6200B
92118063003 MSV/19096MW-3 SM 6200B
92118063004 MSV/19169MW-4 SM 6200B
92118063005 MSV/19107MW-5 SM 6200B
92118063006 MSV/19096MW-6 SM 6200B
92118063007 MSV/19096MW-7 SM 6200B
92118063008 MSV/19096MW-8 SM 6200B
92118063009 MSV/19096MW-9 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 63 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92118063
24174 FMR. CARAWAY GROCERY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92118063010 MSV/19096MW-10 SM 6200B
92118063011 MSV/19096MW-11 SM 6200B
92118063012 MSV/19096MW-12 SM 6200B
92118063013 MSV/19096MW-13 SM 6200B
92118063014 MSV/19096MW-14 SM 6200B
92118063015 MSV/19096MW-15 SM 6200B
92118063016 MSV/19096VE-1 SM 6200B
92118063017 MSV/19096TRIP BLANK SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/19/2012 12:58 PM Page 64 of 64
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]