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HomeMy WebLinkAboutWS-6406_24174_CA_MRP_20141027FEDERAL/STATE-LEAD MONITORING REPORT Former Caraway Grocery (Incident #24174) 3419 Old Lexington Road Asheboro, Randolph County, North Carolina October 27, 2014 Terracon Project No. 70149641 Prepared for: North Carolina Department of Environment and Natural Resources Division of Waste Management Raleigh, North Carolina Prepared by: Terracon Consultants, Inc. Raleigh, North Carolina Terracon Consultants, Inc. 2401 Brentwood Road, Suite 107 Raleigh, NC 27604 P 919-873-2211 F 919-873-9555 terracon.com October 27, 2014 Mr. Herb Berger North Carolina Department of Environment and Natural Resources Division of Waste Management 1637 Mail Service Center Raleigh, North Carolina 27699-1637 Email:herb.berger@ncdenr.gov Re: Federal/State-Lead Monitoring Report Former Caraway Grocery 3419 Old Lexington Road Asheboro, Randolph County, North Carolina UST Incident Number: 24174 Terracon Project No. 70149641 Dear Mr. Berger: Terracon Consultants, Inc. (Terracon) is pleased to submit this Federal/State-Lead Monitoring Report for the above referenced property. This report has been prepared in general accordance with North Carolina Department of Environment and Natural Resources (NCDENR), UST Section Guidelines for Assessment and Corrective Action for UST Releases,dated July 15, 2008, revised December 2013 and Task Authorization No. 01, approved on August 11, 2014. If you have any questions regarding this report or the assessment activities, please contact us at 919-873-2211. Sincerely, Terracon Consultants, Inc. Thomas A. Perdue, EI Michael T. Jordan, LG Environmental Scientist Senior Geologist Christopher L. Corbitt, LG Senior Project Manager Enclosures Table of Contents A.SITE INFORMATION ............................................................................................. 1 B.EXECUTIVE SUMMARY ....................................................................................... 2 C.SITE HISTORY AND CHARACTERIZATION ........................................................ 3 C.1 Site Setting ............................................................................................................................................ 4 C.2 Release Summary................................................................................................................................. 4 C.3 Previous Investigations ....................................................................................................................... 4 C.4 Water Supply Wells .............................................................................................................................. 6 C.5 Surface Water ....................................................................................................................................... 6 C.6 Land Use Information .......................................................................................................................... 6 D.ASSESSMENT INFORMATION ............................................................................ 7 D.1 Site Geology and Hydrogeology ........................................................................................................ 7 D.2 Sampling Activities ............................................................................................................................... 8 D.2.1 Free Product Evaluation ................................................................................................................... 8 D.2.2 Groundwater Sampling Activities ................................................................................................... 8 D.2.3 Analytical Results .............................................................................................................................. 9 E.CONCLUSIONS AND RECOMMENDATIONS ..................................................... 9 FIGURES Figure 1: Site Location Map Figure 2: Site Plan Figure 3: Groundwater Elevation Map (August 12, 2014) Figure 4: Groundwater Analytical Results Map (August 12, 2014) Figure 5: Benzene Isoconcentration Map (August 12, 2014) Figure 6: Benzene Concentrations versus Time TABLES Table 1: Water Supply Well Information Table 2: Summary of Groundwater Analytical Results Table 3: Monitoring Well Construction Information and Historical Groundwater Elevations Table 4: Summary of OSWER Vapor Intrusion Assessment APPENDIX Appendix A: Laboratory Analytical Results and Chain of Custody Forms Appendix B: Photographs Appendix C: Water Supply Well Map (Pyramid Environmental & Engineering, P.C. dated March 18, 2010) Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 1 DRAFT FEDERAL/STATE-LEAD MONITORING REPORT A. SITE INFORMATION Date of Report:October 27, 2014 NCDENR Incident No:27174 Facility ID:0-01818 Site Name:Former Caraway Grocery Site Location:3419 Old Lexington Road Asheboro, North Carolina 27205 Latitude:N 35.738292 Longitude:W 79.884234 UST Owner/Operator:NA/NCDENR State Lead Program Current Property Owner: Mr. Don Johnson 3337 Old Lexington Road Asheboro, North Carolina 27205 (336) 629-3334 Current Property Occupant: Vacant Consultant:Terracon Consultants, Inc. (Contact: Thomas A. Perdue, EI) 2401 Brentwood Road Raleigh, North Carolina 27604 (919) 873-2211 Laboratory:Shealy Environmental Services (NCDENR No. 329) 106 Vantage Point Drive West Columbia, South Carolina 29172 (803) 791-9700 Release Information:Release Discovery Date: 2002 Estimated Quantity: Unknown Cause of Release: Underground Storage Tank System Former USTs: one 270-gallon kerosene UST, one 275-gallon gasoline UST, one 625-gallon gasoline, two 2,000-gallon gasoline USTs Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 2 I, Christopher L. Corbitt, a Licensed Geologist for Terracon Consultants, Inc., do certify that the information contained in this report is correct and accurate to the best of my knowledge. Christopher L. Corbitt, L.G. NC License No. 1015 Terracon Consultants, Inc. is licensed to practice geology/engineering in North Carolina. The certification number of the corporation is F-0869. B. EXECUTIVE SUMMARY The Former Caraway Grocery site, located at 3419 Old Lexington Road, is situated on the northwest corner of a 13.76-acre parcel (Randolph County Parcel ID 7732742533) in Asheboro, North Carolina (Figure 1). The site contains cleared and wooded land with an approximately 625-square foot former gas station building with a former dispenser island canopy. The site previously operated the following underground storage tanks (USTs): One 270-gallon kerosene UST; One 275-gallon gasoline UST; One 625-gallon gasoline; and Two 2,000-gallon gasoline USTs. During a 2002 Limited Phase II Site Assessment, soil borings located near on-site UST systems exhibited odors, visual staining, and soil contamination above NCDENR action levels. Groundwater monitoring events began at the site in 2008 and the USTs were removed in 2010. A subsequent in- situ soil remediation event was conducted at the site in 2011 and a mobile, multi-phase extraction (MMPE) event was conducted at the site in 2012, which extracted a total of approximately 5,690 gallons of impacted groundwater and approximately 24.92 gallons of petroleum product as vapor from monitoring wells MW-1A, MW-4, and MW-12 over a 96-hour time period. According to the most recent groundwater monitoring event of 2013, GCL and 2L exceedences remain at the site. Eleven potable water supply wells were identified within 1,000 feet of the source area. Three of the eleven potable water supply wells were identified within 500 feet of the source area. According to prior reports, municipal water is not available to the area. At the direction of the NCDENR, Terracon mobilized to the site on August 12, 2014 to sample seven on-site monitoring wells (MW-1A, MW-3, MW-4, MW-5, MW-9, MW-12, and MW-14) and one water supply wells (SW-1) located near the site. During the most recent sampling event, shallow groundwater depths in the monitoring wells ranged Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 3 from approximately 13.20 to 30.64 feet below ground surface (bgs). Following well purging activities, groundwater samples were collected from monitoring wells MW-1A, MW-3, MW-4, MW-5, MW-9, MW-12, and MW-14, placed in laboratory provided containers and delivered to Shealy Environmental Services, Inc., in West Columbia, North Carolina for analysis of volatile organic compounds (VOCs) by EPA Method 6200B plus MTBE, EDB, and IPE. Due to the weight of the approximately three-foot diameter concrete cover on water supply well SW-1, Terracon was unable to remove the concrete cover safely; therefore a sample was not collected from water supply well SW-1. SW-1 was not connected a discharge point outside of the well house. Eleven petroleum constituents were reported in monitoring wells MW-1A, MW-3, MW-4, MW-5, MW- 9, and MW-12 above their respective 2L groundwater quality standards, including benzene which was reported above its gross contamination level (GCL) of 5,000 micrograms per liter (µg/L) in MW-4 (5,200 µg/L) and MW-12 (7,800 µg/L). Seven other petroleum constituents were reported in MW- 1A, MW-3, MW-4, MW-5, MW-9, MW-12, and MW-14 below their respective 2L groundwater quality standards. Based on information obtained during the completion of Federal/State-Lead monitoring activities, Terracon provides the following conclusions and findings. Benzene was detected in two on-site wells above its GCL. Eleven petroleum constituents were detected in on-site wells at levels that exceed their 2L groundwater quality standards. Benzene, ethylbenzene and naphthalene exceeded a target cancer risk (TCR) of 10-6 for the groundwater to indoor air pathway. The following compounds exceeded a total hazard quotient (THQ) of 1 from well MW-4: benzene, 1,2,4-trimethylbenzene and total xylenes. Based on the distance of monitoring well MW-4 to the on-site structure (approximately 30 feet) and depth to groundwater (24.23 feet bgs), there is a potential for vapor intrusion into the on-site structure, although the building is not a residence. Municipal water is not available at the site and the surrounding properties. Groundwater monitoring wells were screened across saprolite and bedrock without an outer casing which provided a hydraulic connection between shallow and deeper portions of the aquifer. The construction of these wells could potentially enhance vertical migration of contaminants. The remediation trenches may contribute to the migration of the contaminant plume. C. SITE HISTORY AND CHARACTERIZATION The purpose of this report is to evaluate the current status of the groundwater quality at the Former Caraway Grocery site. Terracon completed this report to summarize the findings of assessment activities performed on August 12, 2014 at the site located at 3419 Old Lexington Road in Asheboro, Randolph County, North Carolina (Figure 1). This Federal/State-Lead Monitoring report was Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 4 prepared for the site in response to a request by the Incident Manager, Mr. Herb Berger with the NCDENR Division of Waste Management, State Lead Program. The Federal/State-Lead Monitoring Report was prepared in general accordance with the 15A NCAC 2L .0115 regulations and the NCDENR Underground Storage Tank (UST) Section Guidelines for Assessment and Corrective Action for UST Releases, dated July 15, 2008, revised December 2013, under the supervision of Mr. Christopher L. Corbitt, a North Carolina registered licensed geologist (North Carolina License No. 1015). C.1 Site Setting The site is located on the northwest corner of a 13.76-acre parcel and contains cleared and wooded land with an approximately 625-square foot former gas station building with a former dispenser island canopy. The site is depicted in Figure 2. The adjacent property to the north consists of cleared and wooded land with the intersection of Old Lexington Road and Caraway Mountain Road. Areas immediately to the east include Old Lexington Road followed by cleared and wooded land with a vacant residential structure. The adjoining and nearby properties to the south include cleared and wooded land with two residential structures. The adjacent property to the west includes wooded land. C.2 Release Summary According to prior reports made available by NCDENR, the site operated as a fueling station from the 1920s to the 1980s and previously operated one 270-gallon kerosene UST, one 275-gallon gasoline UST, one 625-gallon gasoline, and two 2,000-gallon gasoline USTs as well as a 500-gallon kerosene AST. During a 2002 Limited Phase II Site Assessment, soil borings located near on-site UST systems exhibited odors, visual staining, and soil contamination above NCDENR action levels. A chronological summary of UST removal and subsequent assessment and remediation activities at the site is discussed in the following section of the report. C.3 Previous Investigations In 2002, Pyramid Environmental & Engineering, P.C. (Pyramid) conducted a Limited Phase II Site Assessment at the site to determine if the on-site UST system had impacted the site. Eleven soil borings were installed by direct-push technology (DPT) in the vicinity of the former UST systems, AST and dispensers. Refusal was encountered throughout the site between 3 and 15 feet below grade surface (bgs) and soil staining and petroleum odors were observed in six borings. Six soil samples were collected and submitted for laboratory analysis of total petroleum hydrocarbons (TPH) gasoline range organics (GRO) and diesel range organics (DRO). GRO and DRO action levels were exceeded in four samples collected indicating that a gasoline and kerosene release had occurred at the site. Terraine, Inc. conducted a Phase I Limited Site Assessment at the site in 2008 at the direction of NCDENR which included the installation of two groundwater monitoring wells, MW-1 and MW-2. A Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 5 groundwater sample was collected for laboratory analysis from each monitoring well. According to laboratory analysis, 13 constituents were reported above 2L groundwater quality standards from both samples. In March of 2010, the former USTs and associated dispensers and piping were removed from the ground. Pyramid conducted the UST removal oversight, which removed one 270-gallon kerosene UST, one 275-gallon gasoline UST, one 625-gallon gasoline UST, and two 2,000-gallon gasoline USTs and one 500-gallon kerosene AST. Approximately 248.48 tons of contaminated soil was removed from the site and disposed of at an off-site location. Confirmation soil samples and post- excavation soil samples from the UST systems indicated that contaminated soils, including benzene and naphthalene greater than 100 times the soil-to-groundwater maximum soil contamination concentrations (MSCCs), remained after UST excavations. Monitoring well MW-1 was destroyed during UST removal activities. Fifteen additional monitoring wells (MW-1A, and MW-3 through MW-15, and vapor extraction well VE-1) were installed at the site in 2010 as part of the Comprehensive Site Assessment (CSA) conducted by Pyramid. A groundwater sample was collected from each monitoring well and submitted for laboratory analysis. According to laboratory results, 2L groundwater quality standard exceedences were reported in numerous wells throughout the site; however, GCL exceedences were not reported. The CSA indicated that municipal water supply is not available to the site or site vicinity and identified 11 water supply wells within 1,000 feet of the site. Water supply well SW-1, located approximately 350 feet to the south of the site, was also sampled and did not exhibit detectable concentrations. In June of 2011, Progress Environmental, Inc. (Progress) conducted active remediation at the site. Two trenches were excavated and approximately 321.24 tons of contaminated soil was removed from the site. One trench was located in the vicinity of the former gasoline and kerosene USTs on the southern side of the structure and the down-gradient position of those USTs that measured approximately four to five feet wide by 115 feet long and varied between 9 and 15 feet deep. A second trench was located in the vicinity of the former gasoline UST and an oil changing location located on the northern side of the on-site structure which measured four to five feet wide by 20 feet long and approximately 15 feet deep. After excavation limits were reached for both trenches, approximately 6,800 total pounds of PermeOx® Plus for in-situ soil remediation at the site. The trenches were backfilled with imported material. After the in-situ soil remediation activities, Progress returned to the site on September 9, 2011 to sample the existing monitoring wells (MW-1A through MW-15 and VE-1). According to laboratory results, 2L exceedences still remained at the site in the groundwater samples collected. Generally lower concentrations were reported in the groundwater samples than in prior sampling events. Progress returned to the site again in February 2012 to sample the existing monitoring wells (MW-1A through MW-15 and VE-1) and to survey top of casings for monitoring wells. Based on groundwater elevations, groundwater was estimated to flow towards the east and northeast at the site. According Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 6 to laboratory results, 2L exceedences still remained at the site in the groundwater samples collected; however, wells located immediately outside the source area saw an increase of concentrations in petroleum constituents. A MMPE event was conducted by Progress as well as monitoring well sampling as summarized in an Active Remediation Monitoring Report dated May 24, 2012. An initial 96-hour MMPE event was completed at the site between April 2 and April 6, 2012, which extracted a total of approximately 5,690 gallons of impacted groundwater and approximately 24.92 gallons of petroleum product as vapor from monitoring wells MW-1A, MW-4, and MW-12. Progress returned to the site on May 4, 2012 to collect groundwater samples from the on-site monitoring wells (MW-1A through MW-15 and VE-1). Based on groundwater elevations, groundwater was estimated to flow towards the east and southeast at the site. According to laboratory analysis, six wells reported petroleum concentrations in exceedences of 2L groundwater quality standards. According to the most recent Groundwater Monitoring Report, conducted by Crawford Environmental Services dated August 8, 2013, the groundwater monitoring wells (MW-1A through MW-15 and VE- 1) were sampled. Eight monitoring wells exhibited 2L exceedences with benzene reported above its 5,000 μg/L GCL in MW-12 (8,560 μg/L) and 1,2-Dibromoethane (EDB) reported above its 50 μg/L GCL in MW-5 (79.1 μg /L) and MW-12 (134 μg /L). C.4 Water Supply Wells Eleven water supply wells were identified within 1,000 feet of the UST basin (source area). Municipal water is not available to properties located within 1,000 feet of the source area. Results of the water-supply well inventory from previous investigations by other consultants are presented in Table 1 and well locations are depicted in Appendix C. C.5 Surface Water According to the USGS Farmer, NC topographic map dated 1999, the site is situated on a topographic divide that generally parallels Old Lexington Road. Topography at the site slopes to the south/southwest. The site is located in the upper reaches of the drainage basin for Back Creek. The topographic map indicates that Back Creek Lake is located approximately 1,200 feet to the west of the site. Terracon observed an unnamed pond located approximately 850 feet to the south of the site during field events. Surface waters are depicted on Figure 1. C.6 Land Use Information Adjacent properties to the north consist of cleared and wooded land and the intersection of Old Lexington Road and Caraway Mountain Road. Areas immediately to the east include Old Lexington Road, cleared and wooded land and a vacant residential structure. The adjoining and nearby properties to the south include cleared and wooded land with two residential structures. The adjacent property to the west is wooded. Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 7 D. ASSESSMENT INFORMATION D.1 Site Geology and Hydrogeology The following resources were reviewed to evaluate site-specific geological and hydrogeological characteristics. Farmer Quadrangle, North Carolina, USGS 7.5-minute series topographic map, dated 1994 (Figure 1). Geologic Map of North Carolina, dated 1985. Soil Survey of Randolph County, North Carolina, US Department of Agriculture, Natural Resources Conservation Service, Web Soil Survey via the Internet,http://websoilsurvey.nrcs.usda.gov/app/. The site is located within the Carolina Slate Belt of the Piedmont Physiographic Province. The site is underlain by metavolcanic-epiclastic rocks, consisting of metamorphosed argillite, mudstone, volcanic sandstone, conglomerate, and volcanic rock. The Piedmont Physiographic Province generally consists of low to medium elevation, rounded hills and long rolling northeast to southwest trending ridges with incised creeks and river channels. In-place chemical and physical weathering of parent rocks typically form residual soils in the Piedmont region. Weathering is facilitated by the presence of fractures, joints, and less resistant minerals in the rock. In areas not altered by erosion, alluvial deposition or anthropogenic activities, the typical residual soil profile consists of clay-rich unconsolidated materials at the surface, transitioning to sandy silts and silty sands at depth. Typically, the boundary between soil and rock is not sharply defined. This transitional zone is termed “partially weathered rock.” Information obtained from the Web Soil Survey for Randolph County, depicts soils on the site as the Georgeville gravelly silty clay loam (GgB2). In the Piedmont, groundwater generally occurs in pore spaces within soils and in the structural features present in the underlying rock (i.e. joints, fractures, and faults). Recharge to the water table is primarily by precipitation infiltrating the surficial soils and percolating downward under the influence of gravity to the water table. Typically, the water table is not a level surface, but a subdued reflection of the land surface. The depth to the water table is not consistent and is dependent upon several factors that include the amount of rainfall, permeability of the soil, the extent of fracturing in the underlying rock, and the influences of groundwater pumping. Groundwater typically flows in directions parallel to the ground surface, and migrates to discharge points such as surface water features, the toes of slopes or natural springs. Fluctuations in the depth of the water table can be expected depending on variations in precipitation and surface water run-off. Normally, the highest levels of the water table occur in late winter and spring and the lowest levels occur in the late summer and fall. Terracon used prior top-of-well casing elevation information available in the 2013 Groundwater Monitoring Report and collected Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 8 depth to water measurements from the top of the well casings during the monitoring well sampling activities in an attempt to estimate the groundwater flow direction. Current depth to water measurements generally varied between 13.20 and 30.64 feet bgs at the site. Based on the groundwater elevation data, groundwater is expected to flow to the southeast from the site (Figure 3). Monitoring Well Construction Records from previous reports depict that the following Type II monitoring wells have screened intervals that intersect surfical groundwater in saprolite/partially weather rock and also extend at least five feet into competent bedrock without an outer casing: MW- 1A, MW-2, MW-3, MW-4, MW-6, MW-7, MW-8, MW-11, MW-12, MW-13, MW-14, and MW-15. These monitoring wells provide a hydraulic connection and vertical migration pathway of impacted groundwater between separate portions of the aquifer. D.2 Sampling Activities D.2.1 Free Product Evaluation Free product was not encountered in the wells during this assessment. D.2.2 Groundwater Sampling Activities Terracon mobilized to the site on August 12, 2014 to conduct groundwater sampling as requested by the NCDENR. Prior to sample collection, Terracon gauged the groundwater elevations in monitoring wells MW-1A, MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11, MW-12, MW-13, MW-14, MW-15, and VE-1. Groundwater samples were collected from monitoring wells MW-1A, MW-3, MW-4, MW-5, MW-9, MW-12, and MW-14. The approximate locations of the wells are shown on the Site Plan (Figure 2). Current and historical groundwater elevation measurements are provided in Table 3. Prior to sampling, the monitoring wells were purged with a peristaltic pump using low flow sampling techniques (i.e., <200 milliliters per minute) prior to sampling. The following parameters were measured: pH, temperature, oxidation reduction potential (ORP), dissolved oxygen (DO), and conductivity. After stabilization of field parameters (pH and conductivity), a groundwater sample was collected directly into laboratory supplied containers at low flow sampling rates. The groundwater samples were packed on ice and shipped via FedEx along with chain of custody documentation to Shealy Environmental Services, Inc. (Shealy) in West Columbia, South Carolina (North Carolina Field Services Certification #329) for analysis of VOCs by Standard Method 6200B including xylenes, MTBE, EDB and IPE. Terracon also attempted to sample one off-site water supply well (SW-1) to evaluate potential impacts to off-site receptors. Water supply well SW-1 was operable and connected to a foot pump located in the well house, but was not connected to a discharge point outside of the well house. At the time of the field work, water supply well SW-1 was covered with an approximate three-foot diameter concrete cover. Due to the weight of the concrete cover, Terracon was unable to remove the concrete cover safely; therefore, a sample was not collected from water supply well SW-1. According to Mr. Don Johnson, owner of the site, water supply well SW-1 is not in use. Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 9 D.2.3 Analytical Results According to laboratory analytical results, eleven petroleum constituents were reported in monitoring wells MW-1A, MW-3, MW-4, MW-5, MW-9, and MW-12 above their respective 2L groundwater quality standards, including benzene which was reported above its GCL of 5,000 µg/L in monitoring wells MW-4 (5,200 µg/L) and MW-12 (7,800 µg/L). Seven other petroleum constituents were reported in monitoring wells MW-1A, MW-3, MW-4, MW-5, MW-9, MW-12, and MW-14 below their respective 2L groundwater quality standards. The potential for vapor intrusion risk was evaluated using the EPA Office of Solid Waste and Emergency Response (OSWER) Vapor Intrusion Screening Level Calculator based on the groundwater data from monitoring well MW-4 located approximately 30 feet to the southeast of the on-site structure. Benzene, ethylbenzene and naphthalene exceeded a target cancer risk (TCR) of 10-6 for the groundwater to indoor air pathway. The following compounds exceeded a total hazard quotient (THQ) of 1: benzene, 1,2,4-trimethylbenzene and total xylenes. A benzene isoconcentration map is located in Figure 5 and a benzene concentration versus time map for monitoring wells MW-1A, MW-4, MW-5, and MW-12 is located in Figure 6. The groundwater analytical results from the monitoring wells and water supply wells are summarized in Table 2 and the vapor intrusion risk is summarized in Table 4. Copies of the laboratory analytical reports are provided in Appendix A. E. CONCLUSIONS AND RECOMMENDATIONS Based on information obtained during the completion of Federal/State Lead Monitoring activities, Terracon provides the following conclusions and findings. Benzene was detected in two on-site wells above its GCL. Eleven petroleum constituents were detected in on-site wells at levels that exceed their 2L groundwater quality standards. Benzene, ethylbenzene and naphthalene exceeded a target cancer risk (TCR) of 10-6 for the groundwater to indoor air pathway. The following compounds exceeded a total hazard quotient (THQ) of 1 from well MW-4: benzene, 1,2,4-trimethylbenzene and total xylenes. Based on the distance of monitoring well MW-4 to the on-site structure (approximately 30 feet) and depth to groundwater (24.23 feet bgs), there is a potential for vapor intrusion into the on-site structure, although the building is not a residence. Municipal water is not available at the site and the surrounding properties. Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 October 27, 2014 Responsive ■Resourceful ■Reliable 10 Groundwater monitoring wells were screened across saprolite and bedrock without an outer casing which provided a hydraulic connection between shallow and deeper portions of the aquifer. The construction of these wells could potentially enhance vertical migration of contaminants. The remediation trenches may contribute to the migration of the contaminant plume. Based on the data presented in this Federal/State-Lead Monitoring report, Terracon recommends the following activities be completed at the site. Further assessment for potential of vapor intrusion into the on-site structure if there is a change in use. Groundwater monitoring wells MW-1A, MW-2, MW-3, MW-7, MW-8, MW-11, MW-12, MW-13, and MW-15 should be abandoned due to screens providing a hydraulic connection and vertical migration pathway of impacted groundwater between separate portions of the aquifer. Monitoring wells MW-1A, MW-13, and MW-15 should be reinstalled to depths above the bedrock interface and sampled for VOCs. Monitoring well MW-12 should be replaced with a well pair. F. REFERENCES Limited Phase II Site Assessment, Pyramid Environmental & Engineering, P.C. dated April 10, 2002 Phase I Limited Site Assessment, Terraine, Inc. dated December 31, 2008 20-Day Report/Initial Abatement Action Report, Pyramid Environmental & Engineering, P.C. dated April 8, 2010 Comprehensive Site Assessment, Pyramid Environmental & Engineering, P.C. dated November 11, 2010 Active Remediation Monitoring Report, Progress Environmental, Inc. dated July 12, 2011 Active Remediation Monitoring Report, Progress Environmental, Inc. dated October 4, 2011 Active Remediation Monitoring Report, Progress Environmental, Inc. dated February 21, 2012 Active Remediation Monitoring Report, Progress Environmental, Inc. dated May 24, 2012 Groundwater Monitoring Report, Crawford Environmental Services dated August 8, 2013 FIGURES SITE Pond Copyright:© 2013 National Geographic Society, i-cubed N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig1_SiteLoc_082914_102.mxdSite Location Map FigureProject No. Reviewed By: Date: Drawn By: 70149641 JDF TAP September 2014 2401 Brentwood Rd.Raleigh, NC 27604 PH. (919) 873-2211 terracon.com ³ FORMER CARAWAY GROCERYINCIDENT NUMBER 241743419 OLD LEXINGTON ROADASHEBORO, NORTH CAROLINA 1^_ SITE COORDINATES: 79°12'47.982"W 34°43'15.202"N 0 2,500 5,0001,250 Feet 0 0.5 10.25 Miles 1:24,000 Data Source: USGS Farmer Quadrangle, 1994, 7.5-Minute Series @A@A @A @A @A @A @A @A @A @A @A @A @A @A @A @A VE-1 MW-9 MW-8 MW-7 MW-6 MW-5 MW-4 MW-3 MW-2 MW-15 MW-14 MW-13 MW-12 MW-11 MW-10 MW-1A Old Lexington Road FormerCaraway Grocery Mo bile H o me Canopy WoodedArea WoodedArea WoodedArea WoodedArea nm Canopy 12 3 4 5/6 N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig2_SitePlan_082914_102.mxdFigureProject No. Reviewed By: Date: Drawn By:JDF TAP September 2014 2401 Brentwood Rd.Raleigh, NC 27604 PH. (919) 873-2211 terracon.com 2 N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig2_SitePlan_082914_102.mxdData Sources:Well Locations - TerraconImagery - ESRI WMS³ FORMER CARAWAY GROCERYINCIDENT NUMBER 241743419 OLD LEXINGTON ROADASHEBORO, NC 70149641 ^_ Site Plan @A Monitoring Well Former UST/AST Location Former Dispenser Location Remediation Trenches 1 inch = 45 feet Tank #Type Content Size (gal.)Installed Removed1USTGasoline2,000 4/30/85 2/25/102USTGasoline2,000 4/30/85 2/25/103USTGasoline275Unknown (1920s?)2/25/104USTGasoline625Unknown (1920s?)2/25/105USTKerosene270Unknown (1920s?)2/25/106ASTKerosene500Unknown2/25/10 @A @A @A @A @A @A @A @A @A @A @A @A @A @A @A@A @A @A @A @A @A @A @A @A @A @A @A @A @A @A Old Lexington Road FormerCaraway Grocery Mo bile H o me Canopy WoodedArea WoodedArea WoodedArea WoodedArea MW-375.60 VE-169.27 MW-974.15 MW-879.41 MW-780.91 MW-679.76 MW-577.82 MW-474.78 MW-1573.34 MW-1474.02 MW-1378.62 MW-1271.64 MW-1171.96 MW-1067.03 MW-274.78 MW-1A74.94 80 nm 75 70 N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig3_GWElev_091514_102.mxdFigureProject No. Reviewed By: Date: Drawn By:JDF TAP September 2014 2401 Brentwood Rd.Raleigh, NC 27604 PH. (919) 873-2211 terracon.com 3 N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig3_GWElev_091514_102.mxdNote:ft msl = feet above mean sea levelContours dashed where inferred Data Sources:Well Locations - TerraconImagery - ESRI WMS³ FORMER CARAWAY GROCERYINCIDENT NUMBER 241743419 OLD LEXINGTON ROADASHEBORO, NC 70149641 ^_ Groundwater Elevation Map(8/12/2014) @A Monitoring Well Potentiometric Contour Est. Groundwater Flow Direction UST/AST Dispenser Remediation Trenches 73.34 Groundwater Elevation (ft msl)1 inch = 45 feet @A@A @A @A @A @A @A @A @A @A @A @A @A @A @A @A MW-14 MW-9Benzene: 21,2-DCA: 1.3 MW-3Benzene: 1601,2-DCA: 12Naphthalene: 23 MW-5Benzene: 810Ethylbenzene: 800Isopropylbenzene: 85Naphthalene: 130n-Propylbenzene: 140Toluene: 14001,2,4-Trimethylbenzene: 570Total Xylenes: 2960 MW-1ABenzene: 4300Ethylbenzene: 1800Isopropylbenzene: 120MTBE: 61Naphthalene: 180Toluene: 15001,2,4-Trimethylbenzene: 1100Total Xylenes: 4590 MW-12Benzene: 7800Ethylbenzene: 2900Isopropylbenzene: 160MTBE: 99Naphthalene: 330n-Propylbenzene: 360Toluene: 36001,3,5-Trimethylbenzene: 6401,2,4-Trimethylbenzene:2200Total Xylenes: 8700 MW-4Benzene: 5200Ethylbenzene: 1700Isopropylbenzene: 110MTBE: 320Naphthalene: 230n-Propylbenzene: 260Toluene: 25001,2,4-Trimethylbenzene: 1200Total Xylenes: 4700 MW-10 MW-15 MW-11 MW-13 MW-8 MW-7 MW-6 MW-2 VE-1 Canopy M o bile H o m e Source: Esri, DigitalGlobe, GeoEye, i-cubed, Earthstar Geographics,CNES/Airbus DS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP,swisstopo, and the GIS User Community N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig4_GWAnlytl_091514_102.mxdFigureProject No. Reviewed By: Date: Drawn By:JDF TAP September 2014 2401 Brentwood Rd.Raleigh, NC 27604 PH. (919) 873-2211 terracon.com 4 N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig4_GWAnlytl_091514_102.mxdNotes: - Monitoring wells MW-2, MW-6, MW-7, MW-8, MW-10, MW-11, MW-13, MW-15, and VE-1 were not sampled- All concentrations in micrograms per liter (…g/L)- Only compounds with 2L exceedances are shown on figure- Concentrations in bold indicate compounds reported above GCLs Data Sources:- Well Locations - Terracon- Imagery - ESRI WMS³ FORMER CARAWAY GROCERYINCIDENT NUMBER 241743419 OLD LEXINGTON ROADASHEBORO, NC 70149641 ^_ Groundwater Analytical Results Map(8/12/2014) @A Monitoring Well UST/AST Dispenser Remediation Trenches 1 inch = 45 feet @A@A @A @A @A @A @A @A @A @A @A @A @A @A @A @A VE-1 MW-8 MW-7 MW-6 MW-2 MW-15 MW-14 MW-13 MW-11 MW-10 MW-92 MW-5810 MW-3160 MW-45200MW-127800 MW-1A4300 Canopy M o bile H o m e 1 …g/L10 …g/L100 …g/L 1000 …g/LSource: Esri, DigitalGlobe, GeoEye, i-cubed, Earthstar Geographics,CNES/Airbus DS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP,swisstopo, and the GIS User Community N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig5_Benzene_092314_102.mxdFigureProject No. Reviewed By: Date: Drawn By:JDF TAP September 2014 2401 Brentwood Rd.Raleigh, NC 27604 PH. (919) 873-2211 terracon.com 5 N:\GIS\NCDENR_UST_Sites\70149641_CarawayGrcy_NC\T_project\mxd\70149641_Fig5_Benzene_092314_102.mxdNotes: - Monitoring wells MW-2, MW-6, MW-7, MW-8, MW-10, MW-11, MW-13, MW-15, and VE-1 were not sampled- All concentrations in micrograms per liter (…g/L)- Concentrations in bold indicate compounds reported above GCLs Data Sources:- Well Locations - Terracon- Imagery - ESRI WMS³ FORMER CARAWAY GROCERYINCIDENT NUMBER 241743419 OLD LEXINGTON ROADASHEBORO, NC 70149641 ^_ Benzene Isoconcentration Map(8/12/2014) @A Monitoring Well UST/AST Dispenser Remediation Trenches Benzene Isocontour 1 inch = 45 feet Figure:Date: September 2014 Project Number: 70149641 Benzene Concentrations versus Time FORMER CARAWAY GROCERY INCIDENT NUMBER 24174 3419 OLD LEXINGTON ROAD ASHEBORO, NORTH CAROLINABenzene Concentration (ʅg/L)0 1,000 2,000 3,000 4,000 5,000 6,000 7,000 8,000 9,000 1/1/20107/1/20101/1/20117/1/20111/1/20127/1/20121/1/20137/1/20131/1/20147/1/2014MW-1A MW-4 MW-5 MW-12 USTs/ASTremoved (March 2010)Trench and PermeOxInstallation (June 2011)6 2401 Brentwood Road, Suite 107 Raleigh, North Carolina 27612 Date Sampled1993USTs/AST last used (1993)MMPE Event (April 2012) TABLES TABLE 1 Water Supply Well Information Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 NCDENR Incident No. 24174 3337 Old Lexington Road Asheboro, NC 27205 626 Kennedy Farm Road Trinity, NC 27370 1255 Back Creek Road Asheboro, NC 27205 3437 Caraway Mountain Road Asheboro, NC 27205 3256 Old Lexington Road Asheboro, NC 27205 3334 Old Lexington Road Asheboro, NC 27205 3338 Old Lexington Road Asheboro, NC 27205 3354 Old Lexington Road Asheboro, NC 27205 3388 Old Lexington Road Asheboro, NC 27205 3437 Caraway Mountain Road Asheboro, NC 27205 7732850084 SW-14 Robert Glenn Baber, Jr.3437 Caraway Mountain Road SW-13 Robert Glenn Baber, Jr.3388 Old Lexington Road 7732756502 Parcel PIN Notes SW-1 Don Johnson & Judy Fagge 3359 Old Lexington Road 3419 Old Lexington Road Well No.Property Owner Mailing Address Property Address 7732642607 7732749558SW-12 Mark & Dawn Smith 3354 Old Lexington Road 7732842305 SW-11 Roger Herman Hill 3338 Old Lexington Road 7732842770 SW-10 Ruby Thompson Hill (LE)3334 Old Lexington Road 3328 Old Lexington Road 7732730454 Mobile home park, each trailer has a well SW-7 Clayton Stoneman 1255 Back Creek Road 7732737849 SW-2, 3, 4, 5, 6 Clayton Stoneman 2422 Smyrna Grove Drive 2391 Smyrna Grove Drive 7732739978 SW-9 Roger Herman Hill 4.61 acres off Old Lexington Road 7732846325 SW-8 Smyrna Grove Church & Trustees 1275 Back Creek Road TABLE 2 Summary of Groundwater Analytical Results Former Caraway GroceryAsheboro, North Carolina Terracon Project No. 70149641 NCDENR Incident No. 24174 3030C Well/SampleI.D. Depth to Water from Top of Casing (feet)Date Collected (mm/dd/yy)ChloroethaneMW-1 Not available 10/30/2008 1,120 33.6 13.9 0.670 NR NR ND ND 29.7 593 NR 63 7.54 130 NR NR 80.1 137 NR 262 NR 276 115 798 1,330B1 2,060 7,720 NR NR 38.5 Not available 6/30/2010 3,520 ND ND ND NR ND ND 47.5 35.3 1,160 ND 82.8 ND 69.3 ND ND 225 164 NR 952 ND 821 232 3,105 NA NA 8,370 2,110 2,940 74 Not available 9/9/2011 2,500 22.8 13.2 ND NR ND ND 21.9 61 572 ND 51.6 15 55.6 ND ND 37.1 112 NR 451 ND 39.2 47.5 555.7 NA NA 10.9 4,900 960 NR 20.61 2/8/2012 3,750 16.4 ND ND NR ND ND 18.7 63.9 727 ND 57.4 ND 297 ND ND 145 120 NR 932 ND 332 145 1,525 NA NA 12,700 12,800 1,890 87.1 27.08 5/4/2012 3,040 ND ND ND NR ND ND 85.4 55.8 1,540 ND 186 ND 275 ND ND 429 519 ND 2,990 ND 2,870 972 5,900 NA NA 15,900 31,400 7,440 NR 25.16 6/12/2013 4,110 19.1 ND ND NR ND 29.2 138 38.3 1,800 ND 108 ND 139 ND ND 309 241 73.1 6,530 ND 1,350 352 6,460 NA NA NR NR NR NR 25.06 8/12/2014 4,300 37 16J <1.9 <8.5 <8.5 <3.1 <1.2 30 1,800 NA 120 <0.89 61 <8.5 NA 180 <1.2 <0.75 1,500 NA 1,100 360 4,590 NA NA NA NA NA NA Not available 10/30/2008 122 1.24 0.630 ND NR NR ND 13.6 10.1 45.3 NR 4.16 ND 20.1 NR NR 6.52 8.17 NR 10.5 NR NR 7.32 61.3 ND ND ND NR NR NA Not available 6/30/2010 86.2 ND ND ND NR ND ND 19.5 13.9 2 ND ND ND 18 ND ND ND ND NR 6.3 ND ND ND 4.4 NA NA NR NR NR NR Not available 9/9/2011 14.7 ND 0.97 ND NR ND ND 19.9 9.9 ND ND ND ND 2.1 ND ND ND ND NR ND ND ND ND ND NA NA 140 78.5 ND NR 28.48 2/8/2012 19.1 ND 0.72 ND NR ND ND 15.1 7.3 ND ND 1.4 ND 10.2 ND ND ND ND NR 0.5 ND ND ND ND NA NA 104 60 ND 11 27.03 5/4/2012 128 0.64 1.7 ND NR ND ND 16.1 8.3 7.6 ND 4.5 ND 9.4 ND ND 2.2 2.2 ND 5.7 ND 2.8 ND 10.5 NA NA 378 179 ND NR 25.83 6/12/2013 88.7 ND 0.71 ND NR ND ND 10.9 8.6 6.4 ND 2.5 ND 15.8 ND ND 2.6 1.5 ND 11.1 ND 4.2 1.1 16.9 NA NA NR NR NR NR 25.20 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Not available 6/30/2010 94.2 ND ND ND NR ND ND 1.6 2.7 54.7 ND 6.3 ND 1 ND ND ND 11.5 NR 3.2 ND ND 14.7 12.71 NA NA 150 953 240 17.5 Not available 9/9/2011 146 ND 4.9 2.7 NR ND ND 4.1 7.2 9.4 ND 5.3 3.1 1.7 ND ND ND 5.9 NR 2.3 ND 3.6 1.9 ND NA NA 760 649 254 NR 24.53 2/8/2012 275 5.5 9.5 2.7 NR ND ND 5.2 7.3 36.5 ND 11.9 ND 3.7 ND ND 5.1 15.3 NR 6.6 ND 7.5 9.6 5.1 NA NA 110 1,190 340 9.4 23.55 5/4/2012 240 4.4 6.7 2.3 NR ND ND 10.7 7.3 ND ND ND ND 3.8 ND ND ND 9 ND 9 ND 5..5 ND 9.5 NA NA 1,080 1,750 728 NR 23.89 6/12/2013 355 27 31.8 6.1 NR ND ND 9.4 8.2 63.7 ND 18.3 ND ND ND ND ND 28.5 ND 8.9 ND 25.8 3.51 18.1 NA NA NR NR NR NR 23.32 8/12/2014 160 6.6 9.3 3.5 0.6 1.8 <0.061 12 10 30 NA 9.6 1.9 7.1 <0.17 NA 23 15 <0.015 4.2 NA <0.17 9.7 8.8 NA NA NA NA NA NA Not available 6/30/2010 2,860 ND ND ND NR ND ND 35.4 46.6 998 ND 77.8 ND 196 ND ND 269 176 ND 867 ND 706 224 2,483 NA NA 7,900 17,000 2,560 179 Not available 9/9/2011 2,050 18.3 9.4 ND NR ND ND ND 95.7 257 ND 26.8 12.8 434 ND ND 33.5 62.8 ND 84.6 ND 19.2 47.3 132.4 NA NA 7,410 4,710 ND NR 27.25 2/8/2012 2,780 ND ND ND NR ND ND 23.9 33.6 925 ND 71.9 ND 98.1 ND ND 139 166 ND 1,170 ND 474 192 1,818 NA NA 13,400 17,300 2,650 139 25.17 5/4/2012 2,090 ND ND ND NR ND ND 49.8 ND 765 ND 56.4 ND 74.8 ND ND 126 138 ND 1,950 ND 658 213 2,525 NA NA 13,500 21,700 4,670 NR 23.89 6/12/2013 3,830 17.5 ND ND NR ND 40.1 109.0 ND 1,540 ND 90 ND 65.6 ND ND 230 199 ND 7,570 ND 981 306 5,940 NA NA NR NR NR NR 24.23 8/12/2014 5,200 <0.84 16J <1.9 <8.5 <8.5 <3.1 <1.2 60 1,700 NA 110 <0.89 320 <8.5 NA 230 260 <0.75 2,500 NA 1,200 390 4,700 NA NA NA NA NA NA Not available 6/30/2010 975 ND ND ND NR ND 31.9 36.8 6.6 520 ND 42.9 ND ND ND ND 88 69.4 ND 1,970 2.6 346 118 2,359 NA NA 5,010 11,600 1,090 11.3 Not available 9/9/2011 605 9.8 7.3 ND NR ND ND 16.9 3.7 341 ND 32.4 8.8 ND ND ND 46.5 53.7 ND 589 ND 150 44.7 855 NA NA 5,110 4,410 669 NR 24.22 2/8/2012 1,370 11.3 ND ND NR ND ND 41.6 ND 812 ND 62.9 ND ND ND ND 127 103 ND 3,260 ND 511 119 3,980 NA NA 9,820 20,700 2,990 17.9 23.92 5/4/2012 429 ND ND ND NR ND 2.6 13.1 3.2 224 ND 25.4 ND ND ND ND 53.4 46.8 ND 257 ND 182 46.9 636 NA NA 2,850 7,160 1,340 NR 21.95 6/12/2013 3,420 ND ND ND NR ND 79.1 92.4 ND 3,280 ND 146 ND ND ND ND 355 271 ND 14,200 ND 2,110 475 15,840 NA NA NR NR NR NR 22.75 8/12/2014 810 <0.84 13J <1.9 <8.5 <8.5 <3.1 <1.2 <2.6 800 NA 85 <0.89 <0.95 <8.5 NA 130 140 <0.75 1,400 NA 160 570 2,960 NA NA NA NA NA NA Not available 6/30/2010 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND ND Not available 9/9/2011 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 21.32 2/8/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND 7.5 20.88 5/4/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 19.41 6/12/2013 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.73 ND 0.29J ND 1.36J NA NA NR NR NR NR 20.81 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Not available 6/30/2010 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND ND Not available 9/9/2011 0.95 ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 16.09 2/8/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND 18.5 15.81 5/4/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 13.54 6/12/2013 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.39J ND ND ND 0.86 NA NA NR NR NR NR 15.59 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 1 70 70 70 3,000 70 0.02 0.4 70 600 40 70 25 20 5 100 6 70 70 600 NE 400 400 500 700 200 400 700 200 15 5,000 6,900 8,500 15,000 NE 70,000 50 400 70,000 84,500 40,000 25,000 11,700 20,000 5,000 100,000 6,000 30,000 70,000 260,000 NE 28,500 25,000 85,500 NE NE NE NE NE 15,000 All results in µg/L. <- denotes less than sample reporting detection limit."-" denotes not analyzed. Grey shading denotes levels above the 2L standard. Yellow shading denotes levels above the Gross Contamination Levels (GCLs).ND denotes non-detectNE - Not establishedNR - Not reported NA - Not analyzedB1 - Analyte was detected in the associated method blank. Analyte concentration is greater than 10x the concentration found in the method blank. MW-3 MW-5 MW-1A LeadC9-C18 AliphaticsC9-C22 AromaticsChloroform1,2-Dibromoethane1,2-DichloroethaneDiisopropyl Ether2L Standard (ug/L) MADEP EPH/VPH EthylbenzeneMW-6 MW-7 Analytical Method 6200B n-Butylbenzene2-Hexanone Isopropylbenzenep-IsopropyltolueneMethyl tert butyl etherMethylene chloride4-Methyl-2-pentanonesec-Butylbenzenetert-ButylbenzneGCL (ug/L)C5-C8 AliphaticsC9-C12 AliphaticsC9-C10 Aromatics1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneXylenes (Total)Contaminant of Concern ĺ BenzeneStyreneToluene1,2,3-TrichloropropaneNaphthalenen-PropylbenzeneMW-4 MW-2 1 of 1 TABLE 2 Summary of Groundwater Analytical Results Former Caraway GroceryAsheboro, North Carolina Terracon Project No. 70149641 NCDENR Incident No. 24174 3030C Well/Sample I.D. Depth to Water from Top of Casing (feet) Date Collected (mm/dd/yy)ChloroethaneNot available 6/30/2010 ND ND ND ND NR ND ND ND ND 1.9 ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND 41.1 Not available 9/9/2011 17 ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 17.17 2/8/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND 129 16.77 5/4/2012 ND ND ND ND NR 6.5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND 80.2 ND NR 14.61 6/12/2013 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA NR NR NR NR 16.92 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Not available 6/30/2010 49.5 8.1 ND ND NR ND ND 0.83 0.5 97.3 ND 22 ND 1.8 ND ND 23.3 42.8 ND 152 ND 177 63.2 523 NA NA 352 3,110 558 ND Not available 9/9/2011 2.6 ND 1.6 ND NR ND ND ND ND ND ND 1.7 ND 0.57 ND ND ND ND ND ND ND ND ND ND NA NA 106 85.5 ND NR 20.15 2/8/2012 107 4.9 11.4 ND NR ND ND ND ND 13.8 ND 12.5 ND ND ND ND ND 9.9 ND 15.9 ND 3 3 31.3 NA NA 1,350 719 203 37.9 19.10 5/4/2012 40.7 ND 11.3 ND NR ND ND ND ND 3.7 ND 3.6 ND ND ND ND ND 2.4 ND 2.4 ND ND ND ND NA NA 753 368 135 NR 16.81 6/12/2013 52.8 0.76 2.9 ND NR ND ND 0.51 0.36J 10.9 ND 5 ND 0.53 ND ND ND 4.2 ND 9.3 ND 1.8 1.3 16.7 NA NA NR NR NR NR 18.04 8/12/2014 2 <0.017 1.4 <0.037 <0.17 <0.17 <0.061 1.3 0.59 0.31J NA 0.69 <0.018 1.4 <0.17 NA <0.17 <0.024 <0.015 0.18J NA <0.17 <0.17 <0.62 NA NA NA NA NA NA Not available 6/30/2010 ND ND ND ND NR ND ND ND ND ND ND ND ND 1.1 ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND ND Not available 9/9/2011 ND ND ND ND NR ND ND ND 0.65 ND ND ND ND 2.4 ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 28.63 2/8/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND 1.3 ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND 105 27.82 5/4/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND 0.97 ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 23.61 6/12/2013 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.56 ND ND ND 0.25J NA NA NR NR NR NR 28.35 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Not available 6/30/2010 ND ND ND ND NR ND ND ND ND ND ND ND ND 1.3 ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND ND Not available 9/9/2011 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 33.29 2/8/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND 74.2 32.04 5/4/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND 75.4 ND NR 31.86 6/12/2013 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.401 ND ND ND 0.25J NA NA NR NR NR NR 29.20 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Not available 6/30/2010 94.4 ND ND ND NR ND ND 49.5 89.1 310 ND 28.6 ND 347 12.7 ND 46.2 61 ND 525 ND 241 70.4 ND NA NA 2,930 8,080 ND ND Not available 9/9/2011 3,170 11.4 9.3 ND NR ND 0.93 130 98.6 63.7 8.8 42.7 10.2 278 ND 38.6 41.5 35.5 ND 470 ND 49.2 31.9 561 NA NA 12,500 3,670 ND NR 21.17 2/8/2012 4,200 ND ND ND NR ND ND 159 78 264 ND 50.7 ND 289 ND 283 92.6 63.7 ND 772 ND 229 145 1,989 NA NA 13,800 13,400 2,680 ND 19.95 5/4/2012 4,950 ND ND ND NR ND ND 257 72.7 891 ND 95.7 ND ND ND ND 174 182 ND 3,010 1,510 620 6,240 32.8 NA NA 19,000 31,100 5,320 NR 15.61 6/12/2013 8,560 ND ND ND NR ND 134 377 57.6 3,210 ND 158 ND 131 ND ND 376 384 ND 10,700 ND 2,580 661 12,890 NA NA NR NR NR NR 19.28 8/12/2014 7,800 <0.84 21J <1.9 <8.5 <8.5 <3.1 <1.2 46 2,900 NA 160 <0.89 99 <8.5 NA 330 360 <0.75 3,600 NA 640 2,200 8,700 NA NA NA NA NA NA Not available 6/30/2010 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND ND Not available 9/9/2011 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND 92.7 ND NR 14.25 2/8/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND ND 14.08 5/4/2012 ND ND ND ND NR 1.5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 12.10 6/12/2013 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.56 ND ND ND 0.86J NA NA NR NR NR NR 15.23 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Not available 6/30/2010 ND ND ND ND NR ND ND ND ND 17.5 ND 3 ND ND ND ND ND 7.9 ND ND ND 22.4 8.1 3.6 NA NA ND 204 ND ND Not available 9/9/2011 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 23.96 2/8/2012 0.74 ND 0.8 ND NR ND ND ND ND 2.3 ND 2 ND ND ND ND ND 1.2 ND ND ND ND ND ND NA NA 123 76.4 ND 40 22.70 5/4/2012 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR 20.97 6/12/2013 0.33J ND ND ND NR ND ND ND ND 2 ND 0.99 ND 0.86 ND ND ND 0.59 ND 0.62 ND 1.1 0.40J 4.1 NA NA NR NR NR NR 20.96 8/12/2014 0.27 <0.017 <0.01 <0.037 <0.17 <0.17 <0.061 <0.023 <0.052 <0.17 NA <0.029 <0.018 <0.019 <0.17 NA 0.21J <0.024 <0.015 0.53 NA <0.17 <0.17 <0.46 NA NA NA NA NA NA 1 70 70 70 3,000 70 0.02 0.4 70 600 40 70 25 20 5 100 6 70 70 600 NE 400 400 500 700 200 400 700 200 15 5,000 6,900 8,500 15,000 NE 70,000 50 400 70,000 84,500 40,000 25,000 11,700 20,000 5,000 100,000 6,000 30,000 70,000 260,000 NE 28,500 25,000 85,500 NE NE NE NE NE 15,000 All results in µg/L. <- denotes less than sample reporting detection limit."-" denotes not analyzed. Grey shading denotes levels above the 2L standard.Yellow shading denotes levels above the Gross Contamination Levels (GCLs).ND denotes non-detectNE - Not establishedNR - Not reportedNA - Not analyzedB1 - Analyte was detected in the associated method blank. Analyte concentration is greater than 10x the concentration found in the method blank.p-IsopropyltolueneAnalytical Method 6200B MADEP EPH/VPH Contaminant of Concern ĺ Benzenen-Butylbenzenesec-Butylbenzenetert-ButylbenzneChloroform1,2-DibromoethaneC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsLeadToluene1,2,3-Trichloropropane1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneXylenes (Total)C9-C18 Aliphatics2L Standard (ug/L) GCL (ug/L) MW-13 MW-14 C9-C22 AromaticsMethyl tert butyl etherMethylene chloride4-Methyl-2-pentanoneNaphthalenen-PropylbenzeneStyrene1,2-DichloroethaneDiisopropyl EtherEthylbenzene2-Hexanone IsopropylbenzeneMW-8 MW-9 MW-10 MW-11 MW-12 2 of 3 TABLE 2Summary of Groundwater Analytical Results Former Caraway GroceryAsheboro, North Carolina Terracon Project No. 70149641NCDENR Incident No. 24174 3030C Well/Sample I.D. Depth to Water from Top of Casing (feet) Date Collected (mm/dd/yy)ChloroethaneNot available 6/30/2010 ND ND ND ND NR ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NA NA ND ND ND NR Not available 9/9/2011 ND 3.8 1.7 ND NR ND ND ND ND ND ND 1.7 2.9 ND ND ND ND 2.1 ND ND ND 3.3 ND ND NA NA 222 192 67.4 NR 9.62 2/8/2012 ND 7.7 ND ND NR ND ND ND ND 9.8 ND 7.3 ND ND ND ND ND 19.3 ND 0.52 ND 70.5 ND 24.7 NA NA 333 843 259 105 9.96 5/4/2012 ND 13.8 ND ND NR ND ND ND ND 22.2 ND 11 ND ND ND ND 2.2 28.6 ND 0.72 ND 139 ND 81.7 NA NA 714 1,450 635 NR 6.00 6/12/2013 0.34J 8.2 ND ND NR ND ND ND ND 5.9 ND 6.7 ND ND ND ND 1.4J 19.1 ND 1.2 ND 66.1 ND 22.2 NA NA NR NR NR NR 13.20 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Not available 6/30/2010 94.4 ND ND ND NR ND ND 1.8 11.3 2 ND 0.75 ND 39.6 ND ND ND ND ND 6.2 ND 1.2 12 12 NA NA NR NR ND 6 Not available 9/9/2011 ND ND ND ND NR ND ND 1.6 10.6 ND ND ND ND 47.2 ND ND ND ND ND ND ND ND ND ND NA NA NR NR ND NR 32.62 2/8/2012 ND ND ND ND NR ND ND 1.3 8.4 ND ND ND ND 41.5 ND ND ND ND ND ND ND ND ND ND NA NA NR NR ND 15.8 31.50 5/4/2012 ND ND ND ND NR ND ND 1.7 10.6 ND ND ND ND 48.7 ND ND ND ND ND ND ND ND ND ND NA NA 73.1 ND ND NR 29.46 6/12/2013 0.36J ND ND ND NR ND ND 1.8 8.7 0.26J ND ND ND 33 ND ND ND ND ND 0.96 ND ND ND 1.07 NA NA NR NR NR NR 30.64 8/12/2014 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 1 70 70 70 3,000 70 0.02 0.4 70 600 40 70 25 20 5 100 6 70 70 600 NE 400 400 500 700 200 400 700 200 15 5,000 6,900 8,500 15,000 NE 70,000 50 400 70,000 84,500 40,000 25,000 11,700 20,000 5,000 100,000 6,000 30,000 70,000 260,000 NE 28,500 25,000 85,500 NE NE NE NE NE 15,000 All results in µg/L. <- denotes less than sample reporting detection limit."-" denotes not analyzed. Grey shading denotes levels above the 2L standard.Yellow shading denotes levels above the Gross Contamination Levels (GCLs).ND denotes non-detectNE - Not establishedNR - Not reportedNA - Not analyzedB1 - Analyte was detected in the associated method blank. Analyte concentration is greater than 10x the concentration found in the method blank.p-IsopropyltolueneAnalytical Method 6200B MADEP EPH/VPH Contaminant of Concern ĺ Benzenen-Butylbenzenesec-Butylbenzenetert-ButylbenzneChloroform1,2-DibromoethaneC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsLeadToluene1,2,3-Trichloropropane1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneXylenes (Total)C9-C18 AliphaticsMW-15 VE-1 2L Standard (ug/L) GCL (ug/L)C9-C22 AromaticsMethyl tert butyl etherMethylene chloride4-Methyl-2-pentanoneNaphthalenen-PropylbenzeneStyrene1,2-DichloroethaneDiisopropyl EtherEthylbenzene2-Hexanone Isopropylbenzene3 of 3 TABLE 3 Monitoring Well Construction Information and Historical Groundwater Elevations Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 NCDENR Incident No. 24174 Well Id Date Intalled Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation (ft.) Date Water Level Measured Depth to Water from Top of Casing (ft.) Free Product Thickness (ft.) Groundwater Elevation (ft.) Comments 6/30/2010 9/9/2011 2/8/2012 20.61 None 71.39 5/4/2012 27.08 None 72.92 6/12/2013 25.16 None 74.84 8/12/2014 25.06 None 74.94 6/30/2010 9/9/2011 2/8/2012 28.48 None 71.5 5/4/2012 27.03 None 72.95 6/12/2013 25.83 None 74.15 8/12/2014 25.20 None 74.78 6/30/2010 9/9/2011 2/8/2012 24.53 None 74.39 5/4/2012 23.55 None 75.37 6/12/2013 23.89 None 75.03 8/12/2014 23.32 None 75.60 6/30/2010 9/9/2011 2/8/2012 27.25 None 71.76 5/4/2012 25.17 None 73.84 6/12/2013 23.89 None 75.12 8/12/2014 24.23 None 74.78 6/30/2010 9/9/2011 2/8/2012 24.22 None 76.13 5/4/2012 23.92 None 76.65 6/12/2013 21.95 None 78.62 8/12/2014 22.75 None 77.82 6/30/2010 9/9/2011 2/8/2012 21.32 None 79.25 5/4/2012 20.88 None 79.69 6/12/2013 19.41 None 81.16 8/12/2014 20.81 None 79.76 ft = feet ft BGS = feet below grade surface 100.57 MW-1A 2008 2-inch Type II1515-35 35 100 MW-5 June 2010 14 14-34 34 99.01 2-inch Type II MW-2 2008 35 35-50 50 99.98 MW-4 June 2010 20 20-40 40 2-inch Type II MW-3 June 2010 17 17-37 37 98.92 2-inch Type II 2-inch Type II Not available Not available Not available Not available 2-inch Type IIMW-6 June 2010 17 17-37 37 100.57 Not available Not available Not available Not available Not available Not available Not available Not available Page 1 of 3 TABLE 3 Monitoring Well Construction Information and Historical Groundwater Elevations Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 NCDENR Incident No. 24174 Well Id Date Intalled Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation (ft.) Date Water Level Measured Depth to Water from Top of Casing (ft.) Free Product Thickness (ft.) Groundwater Elevation (ft.) Comments 6/30/2010 9/9/2011 2/8/2012 16.09 None 80.41 5/4/2012 15.81 None 80.69 6/12/2013 13.54 None 82.96 8/12/2014 15.59 None 80.91 6/30/2010 9/9/2011 2/8/2012 17.17 None 79.16 5/4/2012 16.77 None 79.56 6/12/2013 14.61 None 81.72 8/12/2014 16.92 None 79.41 6/30/2010 9/9/2011 2/8/2012 20.15 None 72.04 5/4/2012 19.10 None 73.09 6/12/2013 16.81 None 75.38 8/12/2014 18.04 None 74.15 6/30/2010 9/9/2011 2/8/2012 28.63 None 66.75 5/4/2012 27.82 None 67.56 6/12/2013 23.61 None 71.77 8/12/2014 28.35 None 67.03 6/30/2010 9/9/2011 2/8/2012 33.29 None 67.87 5/4/2012 32.04 None 69.12 6/12/2013 31.86 None 69.3 8/12/2014 29.20 None 71.96 6/30/2010 9/9/2011 2/8/2012 21.17 None 69.75 5/4/2012 19.95 None 70.97 6/12/2013 15.61 None 75.31 8/12/2014 19.28 None 71.64 ft = feet ft BGS = feet below grade surface Not available 2-inch Type II Not available MW-8 June 2010 10 10-30 30 96.33 Not available MW-7 June 2010 10 10-30 30 96.5 2-inch Type II Not available MW-9 June 2010 10 10-30 30 92.19 Not available 2-inch Type II Not available MW-10 June 2010 20 20-40 40 95.38 Not available 2-inch Type II Not available MW-11 June 2010 18 18-38 38 101.16 Not available 2-inch Type II 2-inch Type II Not available Not available MW-12 August 2010 10 10-30 30 90.92 Not available Page 2 of 3 TABLE 3 Monitoring Well Construction Information and Historical Groundwater Elevations Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 NCDENR Incident No. 24174 Well Id Date Intalled Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation (ft.) Date Water Level Measured Depth to Water from Top of Casing (ft.) Free Product Thickness (ft.) Groundwater Elevation (ft.) Comments 6/30/2010 9/9/2011 2/8/2012 14.25 None 79.6 5/4/2012 14.08 None 79.77 6/12/2013 12.10 None 81.75 8/12/2014 15.23 None 78.62 6/30/2010 9/9/2011 2/8/2012 23.96 None 71.02 5/4/2012 22.70 None 72.28 6/12/2013 20.97 None 74.01 8/12/2014 20.96 None 74.02 6/30/2010 9/9/2011 2/8/2012 9.62 None 76.92 5/4/2012 9.96 None 76.58 6/12/2013 6.00 None 80.54 8/12/2014 13.20 None 73.34 6/30/2010 9/9/2011 2/8/2012 32.62 None 67.29 5/4/2012 31.50 None 68.41 6/12/2013 29.46 None 70.45 8/12/2014 30.64 None 69.27 ft = feet ft BGS = feet below grade surface Not available 2-inch Type II Not available MW-14 August 2010 15 15-35 35 94.98 Not available MW-13 August 2010 10 10-30 30 93.85 2-inch Type II Not available MW-15 August 2010 10 10-30 30 86.54 Not available 2-inch Type II Not available VE-1 June 2010 Outer casing: 0-69 Inner casing: 0-52 69-74 74 99.91 Not available 2-inch Type III Not available Page 3 of 3 TABLE 4 Summary of OSWER Vapor Intrusion Assessment Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 NCDENR Incident No. 24174 x OSWER VAPOR INTRUSION ASSESSMENT x Groundwater Concentration to Indoor Air Concentration (GWC-IAC) Calculator Version 3.3.1, May 2014 RSLs x x Parameter Symbol Value InstructionsxExposure Scenario Scenario Commercial Select residential or commercial scenario from pull down listxTarget Risk for Carcinogens TCR 1.00E-06xTarget Hazard Quotient for Non-Carcinogens THQ 1 Average Groundwater Temperature (oC)Tgw 25 Enter average of the stabilized groundwater temperature to correct Henry's Law Constant for groundwater target concentrations x x Site Groundwater Concentration Calculated Indoor Air Concentration VI Carcinogenic Risk VI Hazard Inhalation Unit Risk Reference Concentration x Cgw Cia IUR RfC x CAS Chemical Name (ug/L)(ug/m3)(ug/m3)-1 (mg/m3)i x 71-43-2 Benzene 5.2E+03 1.18E+03 7.5E-04 9.0E+00 7.80E-06 I 3.00E-02 Ix 98-82-8 Cumene 1.1E+02 5.17E+01 No IUR 3.0E-02 4.00E-01 Ix 108-20-3 Diisopropyl Ether 6.0E+01 6.28E+00 No IUR 2.0E-03 7.00E-01 Px 100-41-4 Ethylbenzene 1.7E+03 5.48E+02 1.1E-04 1.3E-01 2.50E-06 CA 1.00E+00 Ix 1634-04-4 Methyl tert-Butyl Ether (MTBE)3.2E+02 7.68E+00 1.6E-07 5.8E-04 2.60E-07 CA 3.00E+00 I x 91-20-3 Naphthalene 2.3E+02 4.14E+00 1.1E-05 3.1E-01 3.40E-05 CA 3.00E-03 I x 108-88-3 Toluene 2.5E+03 6.79E+02 No IUR 3.1E-02 5.00E+00 I x 95-63-6 Trimethylbenzene, 1,2,4-3.9E+02 9.82E+01 No IUR 3.2E+00 7.00E-03 Px 1330-20-7 Xylenes 4.7E+03 9.95E+02 No IUR 2.3E+00 1.00E-01 I Notes: (1)Inhalation Pathway Exposure Parameters (RME):Units Exposure Scenario Symbol Value Symbol Value Symbol ValueAveraging time for carcinogens (yrs)ATc_R_GW 70 ATc_C_GW 70 ATc_GW 70Averaging time for non-carcinogens (yrs)ATnc_R_GW 26 ATnc_C_GW 25 Atnc_GW 25Exposure duration (yrs)ED_R_GW 26 ED_C_GW 25 ED_GW 25Exposure frequency (days/yr)EF_R_GW 350 EF_C_GW 250 EF_GW 250Exposure time (hr/day)ET_R_GW 24 ET_C_GW 8 ET_GW 8 (2)Generic Attenuation Factors: Source Medium of Vapors Symbol Value Symbol Value Symbol ValueGroundwater ( - )AFgw_R_GW 0.001 AFgw_C_GW 0.001 AFgw_GW 0.001Sub-Slab and Exterior Soil Gas ( - )AFss_R_GW 0.1 AFss_C_GW 0.1 AFss_GW 0.1 (3)FormulasCia, target = MIN( Cia,c; Cia,nc)Cia,c (ug/m3) = TCR x ATc x (365 days/yr) x (24 hrs/day) / (ED x EF x ET x IUR)Cia,nc (ug/m3) = THQ x ATnc x (365 days/yr) x (24 hrs/day) x RfC x (1000 ug/mg) / (ED x EF x ET) (4)Special Case Chemicals Trichloroethylene Symbol Value Symbol Value Symbol ValuemIURTCE_R_GW 1.00E-06 mIURTCE_C_GW 0.00E+00 mIURTCE_GW 0.00E+00IURTCE_R_GW 3.10E-06 IURTCE_C_GW 4.10E-06 IURTCE_GW 4.10E-06 Mutagenic Chemicals The exposure durations and age-dependent adjustment factors for mutagenic-mode-of-action are listed in the table below: 0 - 2 years 2 2 - 6 years 4 6 - 16 years 10 16 - 26 years 10 Mutagenic-mode-of-action (MMOA) adjustment factor This factor is used in the equations for mutagenic chemicals. Vinyl Chloride See the Navigation Guide equation for Cia,c for vinyl chloride. Notation: I = IRIS: EPA Integrated Risk Information System (IRIS). Available online at: http://www.epa.gov/iris/subst/index.htmlP = PPRTV. EPA Provisional Peer Reviewed Toxicity Values (PPRTVs). Available online at:http://hhpprtv.ornl.gov/pprtv.shtmlA = Agency for Toxic Substances and Disease Registry (ATSDR) Minimum Risk Levels (MRLs). Available online at:http://www.atsdr.cdc.gov/mrls/index.htmlCA = California Environmental Protection Agency/Office of Environmental Health Hazard Assessment assessments. Available online at:http://www.oehha.ca.gov/risk/ChemicalDB/index.aspH = HEAST. EPA Superfund Health Effects Assessment Summary Tables (HEAST) database. Available online at: http://epa-heast.ornl.gov/heast.shtmlS = See RSL User Guide, Section 5X = PPRTV AppendixMut = Chemical acts according to the mutagenic-mode-of-action, special exposure parameters apply (see footnote (4) above).VC = Special exposure equation for vinyl chloride applies (see Navigation Guide for equation).TCE = Special mutagenic and non-mutagenic IURs for trichloroethylene apply (see footnote (4) above).Yellow highlighting indicates site-specific parameters that may be edited by the user.Blue highlighting indicates exposure factors that are based on Risk Assessment Guidance for Superfund (RAGS) or EPA vapor intrusion guidance, which generally should not be changed. Pink highlighting indicates VI carcinogenic risk greater than the target risk for carcinogens (TCR) or VI Hazard greater than or equal to the target hazard quotient for non-carcinogens (THQ). Mutagenic Indicator CR HQ Note: This section applies to trichloroethylene and other mutagenic chemicals, but not to vinyl chloride. Age Cohort Exposure Duration Age-dependent adjustment factor 10 3 Enter target risk for carcinogens (for comparison to the calculated VI carcinogenic risk in column F) Enter target hazard quotient for non-carcinogens (for comparison to the calculated VI hazard in column G) 31 25 Selected (based on scenario) Selected (based on scenario) Selected (based on scenario) Residential Commercial Residential Commercial Residential Commercial RFC Source* IUR Source* VISL Calculator Version 3.3.1, May 2014 RSLs - Groundwater to Indoor Air Worksheet Page 1 of 1 APPENDIX A LABORATORY ANALYTICAL RESULTS AND CHAIN-OF-CUSTODY FORMS SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Terracon Consultants, Inc. 2401 Brentwood Road Suite 107 I Raleigh, NC 27604 Attention: Thomas Perdue PH14008Lot Number: 70149641Project Number: Caraway GroceryProject Name: 08/25/2014Date Completed: Nisreen Saikaly Project Manager *PH14008* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Terracon Consultants, Inc. Lot Number: PH14008 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Terracon Consultants, Inc. Lot Number: PH14008 Sample Number Sample ID Matrix Date Sampled Date Received 001 08/12/2014 1431MW-5 Aqueous 08/14/2014 002 08/12/2014 1534MW-1A Aqueous 08/14/2014 003 08/12/2014 1625MW-4 Aqueous 08/14/2014 004 08/12/2014 1723MW-3 Aqueous 08/14/2014 005 08/12/2014 2039MW-14 Aqueous 08/14/2014 006 08/12/2014 2137MW-9 Aqueous 08/14/2014 007 08/12/2014 2224MW-12 Aqueous 08/14/2014 (7 samples) Page: 3 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Terracon Consultants, Inc. Lot Number: PH14008 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-5 Aqueous Benzene SM 6200B-810 ug/L 6 001 MW-5 Aqueous sec-Butylbenzene SM 6200B-13 J ug/L 6 001 MW-5 Aqueous Ethylbenzene SM 6200B-800 ug/L 6 001 MW-5 Aqueous Isopropylbenzene (Cumene)SM 6200B-85 ug/L 6 001 MW-5 Aqueous Naphthalene SM 6200B-130 ug/L 6 001 MW-5 Aqueous n-Propylbenzene SM 6200B-140 ug/L 6 001 MW-5 Aqueous Toluene SM 6200B-1400 ug/L 7 001 MW-5 Aqueous 1,3,5-Trimethylbenzene (Mesitylene)SM 6200B-160 ug/L 7 001 MW-5 Aqueous 1,2,4-Trimethylbenzene SM 6200B-570 ug/L 7 001 MW-5 Aqueous m+p - Xylenes SM 6200B-2100 ug/L 7 001 MW-5 Aqueous o - Xylenes SM 6200B-860 ug/L 7 002 MW-1A Aqueous Benzene SM 6200B-4300 ug/L 8 002 MW-1A Aqueous n-Butylbenzene SM 6200B-37 ug/L 8 002 MW-1A Aqueous sec-Butylbenzene SM 6200B-16 J ug/L 8 002 MW-1A Aqueous Diisopropyl ether (IPE)SM 6200B-30 ug/L 8 002 MW-1A Aqueous Ethylbenzene SM 6200B-1800 ug/L 8 002 MW-1A Aqueous Isopropylbenzene (Cumene)SM 6200B-120 ug/L 8 002 MW-1A Aqueous Methyl tertiary butyl ether (MTBE)SM 6200B-61 ug/L 8 002 MW-1A Aqueous Naphthalene SM 6200B-180 ug/L 8 002 MW-1A Aqueous Toluene SM 6200B-1500 ug/L 9 002 MW-1A Aqueous 1,3,5-Trimethylbenzene (Mesitylene)SM 6200B-360 ug/L 9 002 MW-1A Aqueous 1,2,4-Trimethylbenzene SM 6200B-1100 ug/L 9 002 MW-1A Aqueous m+p - Xylenes SM 6200B-3700 ug/L 9 002 MW-1A Aqueous o - Xylenes SM 6200B-890 ug/L 9 003 MW-4 Aqueous Benzene SM 6200B-5200 ug/L 10 003 MW-4 Aqueous sec-Butylbenzene SM 6200B-16 J ug/L 10 003 MW-4 Aqueous Diisopropyl ether (IPE)SM 6200B-60 ug/L 10 003 MW-4 Aqueous Ethylbenzene SM 6200B-1700 ug/L 10 003 MW-4 Aqueous Isopropylbenzene (Cumene)SM 6200B-110 ug/L 10 003 MW-4 Aqueous Methyl tertiary butyl ether (MTBE)SM 6200B-320 ug/L 10 003 MW-4 Aqueous Naphthalene SM 6200B-230 ug/L 10 003 MW-4 Aqueous n-Propylbenzene SM 6200B-260 ug/L 10 003 MW-4 Aqueous Toluene SM 6200B-2500 ug/L 11 003 MW-4 Aqueous 1,3,5-Trimethylbenzene (Mesitylene)SM 6200B-390 ug/L 11 003 MW-4 Aqueous 1,2,4-Trimethylbenzene SM 6200B-1200 ug/L 11 003 MW-4 Aqueous m+p - Xylenes SM 6200B-3500 ug/L 11 003 MW-4 Aqueous o - Xylenes SM 6200B-1200 ug/L 11 004 MW-3 Aqueous Benzene SM 6200B-160 ug/L 12 004 MW-3 Aqueous n-Butylbenzene SM 6200B-6.6 ug/L 12 004 MW-3 Aqueous sec-Butylbenzene SM 6200B-9.3 ug/L 12 004 MW-3 Aqueous tert-Butylbenzene SM 6200B-3.5 ug/L 12 004 MW-3 Aqueous Chloroethane SM 6200B-0.58 ug/L 12 004 MW-3 Aqueous Chloroform SM 6200B-1.8 ug/L 12 004 MW-3 Aqueous 1,2-Dichloroethane SM 6200B-12 ug/L 12 004 MW-3 Aqueous Diisopropyl ether (IPE)SM 6200B-10 ug/L 12 Page: 4 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Executive Summary (Continued) Lot Number: PH14008 Sample Sample ID Matrix Parameter Method Result Q Units Page 004 MW-3 Aqueous Ethylbenzene SM 6200B-30 ug/L 12 004 MW-3 Aqueous Isopropylbenzene (Cumene)SM 6200B-9.6 ug/L 12 004 MW-3 Aqueous p-Isopropyltoluene (p-Cymene)SM 6200B-1.9 ug/L 12 004 MW-3 Aqueous Methyl tertiary butyl ether (MTBE)SM 6200B-7.1 ug/L 12 004 MW-3 Aqueous Naphthalene SM 6200B-23 ug/L 12 004 MW-3 Aqueous n-Propylbenzene SM 6200B-15 ug/L 12 004 MW-3 Aqueous Toluene SM 6200B-4.2 ug/L 13 004 MW-3 Aqueous 1,2,4-Trimethylbenzene SM 6200B-9.7 ug/L 13 004 MW-3 Aqueous m+p - Xylenes SM 6200B-6.9 ug/L 13 004 MW-3 Aqueous o - Xylenes SM 6200B-1.9 ug/L 13 005 MW-14 Aqueous Benzene SM 6200B-0.27 J ug/L 14 005 MW-14 Aqueous Naphthalene SM 6200B-0.21 J ug/L 14 005 MW-14 Aqueous Toluene SM 6200B-0.53 ug/L 15 005 MW-14 Aqueous m+p - Xylenes SM 6200B-0.29 J ug/L 15 006 MW-9 Aqueous Benzene SM 6200B-2.0 ug/L 16 006 MW-9 Aqueous sec-Butylbenzene SM 6200B-1.4 ug/L 16 006 MW-9 Aqueous 1,2-Dichloroethane SM 6200B-1.3 ug/L 16 006 MW-9 Aqueous Diisopropyl ether (IPE)SM 6200B-0.59 ug/L 16 006 MW-9 Aqueous Ethylbenzene SM 6200B-0.31 J ug/L 16 006 MW-9 Aqueous Isopropylbenzene (Cumene)SM 6200B-0.69 ug/L 16 006 MW-9 Aqueous Methyl tertiary butyl ether (MTBE)SM 6200B-1.4 ug/L 16 006 MW-9 Aqueous Toluene SM 6200B-0.18 J ug/L 17 006 MW-9 Aqueous m+p - Xylenes SM 6200B-0.45 J ug/L 17 007 MW-12 Aqueous Benzene SM 6200B-7800 ug/L 18 007 MW-12 Aqueous sec-Butylbenzene SM 6200B-21 J ug/L 18 007 MW-12 Aqueous Diisopropyl ether (IPE)SM 6200B-46 ug/L 18 007 MW-12 Aqueous Ethylbenzene SM 6200B-2900 ug/L 18 007 MW-12 Aqueous Isopropylbenzene (Cumene)SM 6200B-160 ug/L 18 007 MW-12 Aqueous Methyl tertiary butyl ether (MTBE)SM 6200B-99 ug/L 18 007 MW-12 Aqueous Naphthalene SM 6200B-330 ug/L 18 007 MW-12 Aqueous n-Propylbenzene SM 6200B-360 ug/L 18 007 MW-12 Aqueous Toluene SM 6200B-3600 ug/L 19 007 MW-12 Aqueous 1,3,5-Trimethylbenzene (Mesitylene)SM 6200B-640 ug/L 19 007 MW-12 Aqueous 1,2,4-Trimethylbenzene SM 6200B-2200 ug/L 19 007 MW-12 Aqueous m+p - Xylenes SM 6200B-6000 ug/L 19 007 MW-12 Aqueous o - Xylenes SM 6200B-2700 ug/L 19 (81 detections) Page: 5 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-5 PH14008-001 08/12/2014 1431 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 1921 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Benzene 71-43-2 SM 6200B-20 810 1ug/L1.425 Bromobenzene 108-86-1 SM 6200B-20 ND 1ug/L1.425 Bromochloromethane 74-97-5 SM 6200B-20 ND 1ug/L2.825 Bromodichloromethane 75-27-4 SM 6200B-20 ND 1ug/L8.525 Bromoform 75-25-2 SM 6200B-20 ND 1ug/L0.5125 Bromomethane (Methyl bromide)74-83-9 SM 6200B-20 ND 1ug/L1025 n-Butylbenzene 104-51-8 SM 6200B-20 ND 1ug/L0.8425 sec-Butylbenzene 135-98-8 SM 6200B-20 13 J 1ug/L0.5225 tert-Butylbenzene 98-06-6 SM 6200B-20 ND 1ug/L1.925 Carbon tetrachloride 56-23-5 SM 6200B-20 ND 1ug/L4.325 Chlorobenzene 108-90-7 SM 6200B-20 ND 1ug/L8.525 Chloroethane 75-00-3 SM 6200B-20 ND 1ug/L8.525 Chloroform 67-66-3 SM 6200B-20 ND 1ug/L8.525 Chloromethane (Methyl chloride)74-87-3 SM 6200B-20 ND 1ug/L8.725 2-Chlorotoluene 95-49-8 SM 6200B-20 ND 1ug/L3.025 4-Chlorotoluene 106-43-4 SM 6200B-20 ND 1ug/L0.9525 Dibromochloromethane 124-48-1 SM 6200B-20 ND 1ug/L8.525 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-20 ND 1ug/L3.125 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-20 ND 1ug/L4.725 1,2-Dichlorobenzene 95-50-1 SM 6200B-20 ND 1ug/L8.525 1,3-Dichlorobenzene 541-73-1 SM 6200B-20 ND 1ug/L8.525 1,4-Dichlorobenzene 106-46-7 SM 6200B-20 ND 1ug/L8.525 Dichlorodifluoromethane 75-71-8 SM 6200B-20 ND 1ug/L3.525 1,1-Dichloroethane 75-34-3 SM 6200B-20 ND 1ug/L2.725 1,2-Dichloroethane 107-06-2 SM 6200B-20 ND 1ug/L1.225 1,1-Dichloroethene 75-35-4 SM 6200B-20 ND 1ug/L4.725 cis-1,2-Dichloroethene 156-59-2 SM 6200B-20 ND 1ug/L4.425 trans-1,2-Dichloroethene 156-60-5 SM 6200B-20 ND 1ug/L4.025 1,2-Dichloropropane 78-87-5 SM 6200B-20 ND 1ug/L4.125 1,3-Dichloropropane 142-28-9 SM 6200B-20 ND 1ug/L0.9525 2,2-Dichloropropane 594-20-7 SM 6200B-20 ND 1ug/L3.025 1,1-Dichloropropene 563-58-6 SM 6200B-20 ND 1ug/L3.725 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-20 ND 1ug/L4.525 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-20 ND 1ug/L9.025 Diisopropyl ether (IPE)108-20-3 SM 6200B-20 ND 1ug/L2.625 Ethylbenzene 100-41-4 SM 6200B-20 800 1ug/L8.525 Hexachlorobutadiene 87-68-3 SM 6200B-20 ND 1ug/L8.525 Isopropylbenzene (Cumene)98-82-8 SM 6200B-20 85 1ug/L1.425 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-20 ND 1ug/L0.8925 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-20 ND 1ug/L0.9525 Methylene chloride 75-09-2 SM 6200B-20 ND 1ug/L8.525 Naphthalene 91-20-3 SM 6200B-20 130 1ug/L8.525 n-Propylbenzene 103-65-1 SM 6200B-20 140 1ug/L1.225 Styrene 100-42-5 SM 6200B-20 ND 1ug/L0.7525 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-5 PH14008-001 08/12/2014 1431 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 1921 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-20 ND 1ug/L2.925 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-20 ND 1ug/L0.6525 Tetrachloroethene 127-18-4 SM 6200B-20 ND 1ug/L0.7225 Toluene 108-88-3 SM 6200B-20 1400 1ug/L8.525 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-20 ND 1ug/L1525 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-20 ND 1ug/L8.525 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-20 ND 1ug/L8.525 1,1,1-Trichloroethane 71-55-6 SM 6200B-20 ND 1ug/L1.425 1,1,2-Trichloroethane 79-00-5 SM 6200B-20 ND 1ug/L1.625 Trichloroethene 79-01-6 SM 6200B-20 ND 1ug/L1.225 Trichlorofluoromethane 75-69-4 SM 6200B-20 ND 1ug/L2.525 1,2,3-Trichloropropane 96-18-4 SM 6200B-20 ND 1ug/L1725 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-20 160 1ug/L8.525 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-20 570 1ug/L8.525 Vinyl chloride 75-01-4 SM 6200B-20 ND 1ug/L3.325 m+p - Xylenes 179601-23-1 SM 6200B-20 2100 1ug/L8.525 o - Xylenes 95-47-6 SM 6200B-20 860 1ug/L8.525 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 101 70-130 Bromofluorobenzene 96 70-130 Toluene-d8 100 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-1A PH14008-002 08/12/2014 1534 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 1944 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Benzene 71-43-2 SM 6200B-20 4300 1ug/L1.425 Bromobenzene 108-86-1 SM 6200B-20 ND 1ug/L1.425 Bromochloromethane 74-97-5 SM 6200B-20 ND 1ug/L2.825 Bromodichloromethane 75-27-4 SM 6200B-20 ND 1ug/L8.525 Bromoform 75-25-2 SM 6200B-20 ND 1ug/L0.5125 Bromomethane (Methyl bromide)74-83-9 SM 6200B-20 ND 1ug/L1025 n-Butylbenzene 104-51-8 SM 6200B-20 37 1ug/L0.8425 sec-Butylbenzene 135-98-8 SM 6200B-20 16 J 1ug/L0.5225 tert-Butylbenzene 98-06-6 SM 6200B-20 ND 1ug/L1.925 Carbon tetrachloride 56-23-5 SM 6200B-20 ND 1ug/L4.325 Chlorobenzene 108-90-7 SM 6200B-20 ND 1ug/L8.525 Chloroethane 75-00-3 SM 6200B-20 ND 1ug/L8.525 Chloroform 67-66-3 SM 6200B-20 ND 1ug/L8.525 Chloromethane (Methyl chloride)74-87-3 SM 6200B-20 ND 1ug/L8.725 2-Chlorotoluene 95-49-8 SM 6200B-20 ND 1ug/L3.025 4-Chlorotoluene 106-43-4 SM 6200B-20 ND 1ug/L0.9525 Dibromochloromethane 124-48-1 SM 6200B-20 ND 1ug/L8.525 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-20 ND 1ug/L3.125 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-20 ND 1ug/L4.725 1,2-Dichlorobenzene 95-50-1 SM 6200B-20 ND 1ug/L8.525 1,3-Dichlorobenzene 541-73-1 SM 6200B-20 ND 1ug/L8.525 1,4-Dichlorobenzene 106-46-7 SM 6200B-20 ND 1ug/L8.525 Dichlorodifluoromethane 75-71-8 SM 6200B-20 ND 1ug/L3.525 1,1-Dichloroethane 75-34-3 SM 6200B-20 ND 1ug/L2.725 1,2-Dichloroethane 107-06-2 SM 6200B-20 ND 1ug/L1.225 1,1-Dichloroethene 75-35-4 SM 6200B-20 ND 1ug/L4.725 cis-1,2-Dichloroethene 156-59-2 SM 6200B-20 ND 1ug/L4.425 trans-1,2-Dichloroethene 156-60-5 SM 6200B-20 ND 1ug/L4.025 1,2-Dichloropropane 78-87-5 SM 6200B-20 ND 1ug/L4.125 1,3-Dichloropropane 142-28-9 SM 6200B-20 ND 1ug/L0.9525 2,2-Dichloropropane 594-20-7 SM 6200B-20 ND 1ug/L3.025 1,1-Dichloropropene 563-58-6 SM 6200B-20 ND 1ug/L3.725 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-20 ND 1ug/L4.525 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-20 ND 1ug/L9.025 Diisopropyl ether (IPE)108-20-3 SM 6200B-20 30 1ug/L2.625 Ethylbenzene 100-41-4 SM 6200B-20 1800 1ug/L8.525 Hexachlorobutadiene 87-68-3 SM 6200B-20 ND 1ug/L8.525 Isopropylbenzene (Cumene)98-82-8 SM 6200B-20 120 1ug/L1.425 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-20 ND 1ug/L0.8925 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-20 61 1ug/L0.9525 Methylene chloride 75-09-2 SM 6200B-20 ND 1ug/L8.525 Naphthalene 91-20-3 SM 6200B-20 180 1ug/L8.525 n-Propylbenzene 103-65-1 SM 6200B-20 ND 1ug/L1.225 Styrene 100-42-5 SM 6200B-20 ND 1ug/L0.7525 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-1A PH14008-002 08/12/2014 1534 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 1944 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-20 ND 1ug/L2.925 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-20 ND 1ug/L0.6525 Tetrachloroethene 127-18-4 SM 6200B-20 ND 1ug/L0.7225 Toluene 108-88-3 SM 6200B-20 1500 1ug/L8.525 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-20 ND 1ug/L1525 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-20 ND 1ug/L8.525 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-20 ND 1ug/L8.525 1,1,1-Trichloroethane 71-55-6 SM 6200B-20 ND 1ug/L1.425 1,1,2-Trichloroethane 79-00-5 SM 6200B-20 ND 1ug/L1.625 Trichloroethene 79-01-6 SM 6200B-20 ND 1ug/L1.225 Trichlorofluoromethane 75-69-4 SM 6200B-20 ND 1ug/L2.525 1,2,3-Trichloropropane 96-18-4 SM 6200B-20 ND 1ug/L1725 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-20 360 1ug/L8.525 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-20 1100 1ug/L8.525 Vinyl chloride 75-01-4 SM 6200B-20 ND 1ug/L3.325 m+p - Xylenes 179601-23-1 SM 6200B-20 3700 1ug/L8.525 o - Xylenes 95-47-6 SM 6200B-20 890 1ug/L8.525 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 97 70-130 Toluene-d8 102 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-4 PH14008-003 08/12/2014 1625 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 2008 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Benzene 71-43-2 SM 6200B-20 5200 1ug/L1.425 Bromobenzene 108-86-1 SM 6200B-20 ND 1ug/L1.425 Bromochloromethane 74-97-5 SM 6200B-20 ND 1ug/L2.825 Bromodichloromethane 75-27-4 SM 6200B-20 ND 1ug/L8.525 Bromoform 75-25-2 SM 6200B-20 ND 1ug/L0.5125 Bromomethane (Methyl bromide)74-83-9 SM 6200B-20 ND 1ug/L1025 n-Butylbenzene 104-51-8 SM 6200B-20 ND 1ug/L0.8425 sec-Butylbenzene 135-98-8 SM 6200B-20 16 J 1ug/L0.5225 tert-Butylbenzene 98-06-6 SM 6200B-20 ND 1ug/L1.925 Carbon tetrachloride 56-23-5 SM 6200B-20 ND 1ug/L4.325 Chlorobenzene 108-90-7 SM 6200B-20 ND 1ug/L8.525 Chloroethane 75-00-3 SM 6200B-20 ND 1ug/L8.525 Chloroform 67-66-3 SM 6200B-20 ND 1ug/L8.525 Chloromethane (Methyl chloride)74-87-3 SM 6200B-20 ND 1ug/L8.725 2-Chlorotoluene 95-49-8 SM 6200B-20 ND 1ug/L3.025 4-Chlorotoluene 106-43-4 SM 6200B-20 ND 1ug/L0.9525 Dibromochloromethane 124-48-1 SM 6200B-20 ND 1ug/L8.525 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-20 ND 1ug/L3.125 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-20 ND 1ug/L4.725 1,2-Dichlorobenzene 95-50-1 SM 6200B-20 ND 1ug/L8.525 1,3-Dichlorobenzene 541-73-1 SM 6200B-20 ND 1ug/L8.525 1,4-Dichlorobenzene 106-46-7 SM 6200B-20 ND 1ug/L8.525 Dichlorodifluoromethane 75-71-8 SM 6200B-20 ND 1ug/L3.525 1,1-Dichloroethane 75-34-3 SM 6200B-20 ND 1ug/L2.725 1,2-Dichloroethane 107-06-2 SM 6200B-20 ND 1ug/L1.225 1,1-Dichloroethene 75-35-4 SM 6200B-20 ND 1ug/L4.725 cis-1,2-Dichloroethene 156-59-2 SM 6200B-20 ND 1ug/L4.425 trans-1,2-Dichloroethene 156-60-5 SM 6200B-20 ND 1ug/L4.025 1,2-Dichloropropane 78-87-5 SM 6200B-20 ND 1ug/L4.125 1,3-Dichloropropane 142-28-9 SM 6200B-20 ND 1ug/L0.9525 2,2-Dichloropropane 594-20-7 SM 6200B-20 ND 1ug/L3.025 1,1-Dichloropropene 563-58-6 SM 6200B-20 ND 1ug/L3.725 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-20 ND 1ug/L4.525 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-20 ND 1ug/L9.025 Diisopropyl ether (IPE)108-20-3 SM 6200B-20 60 1ug/L2.625 Ethylbenzene 100-41-4 SM 6200B-20 1700 1ug/L8.525 Hexachlorobutadiene 87-68-3 SM 6200B-20 ND 1ug/L8.525 Isopropylbenzene (Cumene)98-82-8 SM 6200B-20 110 1ug/L1.425 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-20 ND 1ug/L0.8925 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-20 320 1ug/L0.9525 Methylene chloride 75-09-2 SM 6200B-20 ND 1ug/L8.525 Naphthalene 91-20-3 SM 6200B-20 230 1ug/L8.525 n-Propylbenzene 103-65-1 SM 6200B-20 260 1ug/L1.225 Styrene 100-42-5 SM 6200B-20 ND 1ug/L0.7525 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-4 PH14008-003 08/12/2014 1625 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 2008 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-20 ND 1ug/L2.925 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-20 ND 1ug/L0.6525 Tetrachloroethene 127-18-4 SM 6200B-20 ND 1ug/L0.7225 Toluene 108-88-3 SM 6200B-20 2500 1ug/L8.525 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-20 ND 1ug/L1525 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-20 ND 1ug/L8.525 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-20 ND 1ug/L8.525 1,1,1-Trichloroethane 71-55-6 SM 6200B-20 ND 1ug/L1.425 1,1,2-Trichloroethane 79-00-5 SM 6200B-20 ND 1ug/L1.625 Trichloroethene 79-01-6 SM 6200B-20 ND 1ug/L1.225 Trichlorofluoromethane 75-69-4 SM 6200B-20 ND 1ug/L2.525 1,2,3-Trichloropropane 96-18-4 SM 6200B-20 ND 1ug/L1725 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-20 390 1ug/L8.525 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-20 1200 1ug/L8.525 Vinyl chloride 75-01-4 SM 6200B-20 ND 1ug/L3.325 m+p - Xylenes 179601-23-1 SM 6200B-20 3500 1ug/L8.525 o - Xylenes 95-47-6 SM 6200B-20 1200 1ug/L8.525 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 96 70-130 Toluene-d8 102 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-3 PH14008-004 08/12/2014 1723 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 08/21/2014 1504 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Benzene 71-43-2 SM 6200B-20 160 1ug/L0.0270.50 Bromobenzene 108-86-1 SM 6200B-20 ND 1ug/L0.0270.50 Bromochloromethane 74-97-5 SM 6200B-20 ND 1ug/L0.0550.50 Bromodichloromethane 75-27-4 SM 6200B-20 ND 1ug/L0.170.50 Bromoform 75-25-2 SM 6200B-20 ND 1ug/L0.0100.50 Bromomethane (Methyl bromide)74-83-9 SM 6200B-20 ND 1ug/L0.200.50 n-Butylbenzene 104-51-8 SM 6200B-20 6.6 1ug/L0.0170.50 sec-Butylbenzene 135-98-8 SM 6200B-20 9.3 1ug/L0.0100.50 tert-Butylbenzene 98-06-6 SM 6200B-20 3.5 1ug/L0.0370.50 Carbon tetrachloride 56-23-5 SM 6200B-20 ND 1ug/L0.0850.50 Chlorobenzene 108-90-7 SM 6200B-20 ND 1ug/L0.170.50 Chloroethane 75-00-3 SM 6200B-20 0.58 1ug/L0.170.50 Chloroform 67-66-3 SM 6200B-20 1.8 1ug/L0.170.50 Chloromethane (Methyl chloride)74-87-3 SM 6200B-20 ND 1ug/L0.170.50 2-Chlorotoluene 95-49-8 SM 6200B-20 ND 1ug/L0.0590.50 4-Chlorotoluene 106-43-4 SM 6200B-20 ND 1ug/L0.0190.50 Dibromochloromethane 124-48-1 SM 6200B-20 ND 1ug/L0.170.50 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-20 ND 1ug/L0.0610.50 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-20 ND 1ug/L0.0940.50 1,2-Dichlorobenzene 95-50-1 SM 6200B-20 ND 1ug/L0.170.50 1,3-Dichlorobenzene 541-73-1 SM 6200B-20 ND 1ug/L0.170.50 1,4-Dichlorobenzene 106-46-7 SM 6200B-20 ND 1ug/L0.170.50 Dichlorodifluoromethane 75-71-8 SM 6200B-20 ND 1ug/L0.0710.50 1,1-Dichloroethane 75-34-3 SM 6200B-20 ND 1ug/L0.0540.50 1,2-Dichloroethane 107-06-2 SM 6200B-20 12 1ug/L0.0230.50 1,1-Dichloroethene 75-35-4 SM 6200B-20 ND 1ug/L0.0940.50 cis-1,2-Dichloroethene 156-59-2 SM 6200B-20 ND 1ug/L0.0870.50 trans-1,2-Dichloroethene 156-60-5 SM 6200B-20 ND 1ug/L0.0790.50 1,2-Dichloropropane 78-87-5 SM 6200B-20 ND 1ug/L0.0810.50 1,3-Dichloropropane 142-28-9 SM 6200B-20 ND 1ug/L0.0190.50 2,2-Dichloropropane 594-20-7 SM 6200B-20 ND 1ug/L0.0600.50 1,1-Dichloropropene 563-58-6 SM 6200B-20 ND 1ug/L0.0740.50 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-20 ND 1ug/L0.0900.50 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-20 ND 1ug/L0.180.50 Diisopropyl ether (IPE)108-20-3 SM 6200B-20 10 1ug/L0.0520.50 Ethylbenzene 100-41-4 SM 6200B-20 30 1ug/L0.170.50 Hexachlorobutadiene 87-68-3 SM 6200B-20 ND 1ug/L0.170.50 Isopropylbenzene (Cumene)98-82-8 SM 6200B-20 9.6 1ug/L0.0290.50 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-20 1.9 1ug/L0.0180.50 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-20 7.1 1ug/L0.0190.50 Methylene chloride 75-09-2 SM 6200B-20 ND 1ug/L0.170.50 Naphthalene 91-20-3 SM 6200B-20 23 1ug/L0.170.50 n-Propylbenzene 103-65-1 SM 6200B-20 15 1ug/L0.0240.50 Styrene 100-42-5 SM 6200B-20 ND 1ug/L0.0150.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-3 PH14008-004 08/12/2014 1723 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 08/21/2014 1504 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-20 ND 1ug/L0.0570.50 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-20 ND 1ug/L0.0130.50 Tetrachloroethene 127-18-4 SM 6200B-20 ND 1ug/L0.0140.50 Toluene 108-88-3 SM 6200B-20 4.2 1ug/L0.170.50 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-20 ND 1ug/L0.300.50 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-20 ND 1ug/L0.170.50 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-20 ND 1ug/L0.170.50 1,1,1-Trichloroethane 71-55-6 SM 6200B-20 ND 1ug/L0.0290.50 1,1,2-Trichloroethane 79-00-5 SM 6200B-20 ND 1ug/L0.0310.50 Trichloroethene 79-01-6 SM 6200B-20 ND 1ug/L0.0240.50 Trichlorofluoromethane 75-69-4 SM 6200B-20 ND 1ug/L0.0510.50 1,2,3-Trichloropropane 96-18-4 SM 6200B-20 ND 1ug/L0.330.50 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-20 ND 1ug/L0.170.50 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-20 9.7 1ug/L0.170.50 Vinyl chloride 75-01-4 SM 6200B-20 ND 1ug/L0.0650.50 m+p - Xylenes 179601-23-1 SM 6200B-20 6.9 1ug/L0.170.50 o - Xylenes 95-47-6 SM 6200B-20 1.9 1ug/L0.170.50 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 70-130 Bromofluorobenzene 100 70-130 Toluene-d8 102 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-14 PH14008-005 08/12/2014 2039 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 08/21/2014 1528 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Benzene 71-43-2 SM 6200B-20 0.27 J 1ug/L0.0270.50 Bromobenzene 108-86-1 SM 6200B-20 ND 1ug/L0.0270.50 Bromochloromethane 74-97-5 SM 6200B-20 ND 1ug/L0.0550.50 Bromodichloromethane 75-27-4 SM 6200B-20 ND 1ug/L0.170.50 Bromoform 75-25-2 SM 6200B-20 ND 1ug/L0.0100.50 Bromomethane (Methyl bromide)74-83-9 SM 6200B-20 ND 1ug/L0.200.50 n-Butylbenzene 104-51-8 SM 6200B-20 ND 1ug/L0.0170.50 sec-Butylbenzene 135-98-8 SM 6200B-20 ND 1ug/L0.0100.50 tert-Butylbenzene 98-06-6 SM 6200B-20 ND 1ug/L0.0370.50 Carbon tetrachloride 56-23-5 SM 6200B-20 ND 1ug/L0.0850.50 Chlorobenzene 108-90-7 SM 6200B-20 ND 1ug/L0.170.50 Chloroethane 75-00-3 SM 6200B-20 ND 1ug/L0.170.50 Chloroform 67-66-3 SM 6200B-20 ND 1ug/L0.170.50 Chloromethane (Methyl chloride)74-87-3 SM 6200B-20 ND 1ug/L0.170.50 2-Chlorotoluene 95-49-8 SM 6200B-20 ND 1ug/L0.0590.50 4-Chlorotoluene 106-43-4 SM 6200B-20 ND 1ug/L0.0190.50 Dibromochloromethane 124-48-1 SM 6200B-20 ND 1ug/L0.170.50 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-20 ND 1ug/L0.0610.50 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-20 ND 1ug/L0.0940.50 1,2-Dichlorobenzene 95-50-1 SM 6200B-20 ND 1ug/L0.170.50 1,3-Dichlorobenzene 541-73-1 SM 6200B-20 ND 1ug/L0.170.50 1,4-Dichlorobenzene 106-46-7 SM 6200B-20 ND 1ug/L0.170.50 Dichlorodifluoromethane 75-71-8 SM 6200B-20 ND 1ug/L0.0710.50 1,1-Dichloroethane 75-34-3 SM 6200B-20 ND 1ug/L0.0540.50 1,2-Dichloroethane 107-06-2 SM 6200B-20 ND 1ug/L0.0230.50 1,1-Dichloroethene 75-35-4 SM 6200B-20 ND 1ug/L0.0940.50 cis-1,2-Dichloroethene 156-59-2 SM 6200B-20 ND 1ug/L0.0870.50 trans-1,2-Dichloroethene 156-60-5 SM 6200B-20 ND 1ug/L0.0790.50 1,2-Dichloropropane 78-87-5 SM 6200B-20 ND 1ug/L0.0810.50 1,3-Dichloropropane 142-28-9 SM 6200B-20 ND 1ug/L0.0190.50 2,2-Dichloropropane 594-20-7 SM 6200B-20 ND 1ug/L0.0600.50 1,1-Dichloropropene 563-58-6 SM 6200B-20 ND 1ug/L0.0740.50 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-20 ND 1ug/L0.0900.50 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-20 ND 1ug/L0.180.50 Diisopropyl ether (IPE)108-20-3 SM 6200B-20 ND 1ug/L0.0520.50 Ethylbenzene 100-41-4 SM 6200B-20 ND 1ug/L0.170.50 Hexachlorobutadiene 87-68-3 SM 6200B-20 ND 1ug/L0.170.50 Isopropylbenzene (Cumene)98-82-8 SM 6200B-20 ND 1ug/L0.0290.50 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-20 ND 1ug/L0.0180.50 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-20 ND 1ug/L0.0190.50 Methylene chloride 75-09-2 SM 6200B-20 ND 1ug/L0.170.50 Naphthalene 91-20-3 SM 6200B-20 0.21 J 1ug/L0.170.50 n-Propylbenzene 103-65-1 SM 6200B-20 ND 1ug/L0.0240.50 Styrene 100-42-5 SM 6200B-20 ND 1ug/L0.0150.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-14 PH14008-005 08/12/2014 2039 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 08/21/2014 1528 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-20 ND 1ug/L0.0570.50 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-20 ND 1ug/L0.0130.50 Tetrachloroethene 127-18-4 SM 6200B-20 ND 1ug/L0.0140.50 Toluene 108-88-3 SM 6200B-20 0.53 1ug/L0.170.50 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-20 ND 1ug/L0.300.50 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-20 ND 1ug/L0.170.50 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-20 ND 1ug/L0.170.50 1,1,1-Trichloroethane 71-55-6 SM 6200B-20 ND 1ug/L0.0290.50 1,1,2-Trichloroethane 79-00-5 SM 6200B-20 ND 1ug/L0.0310.50 Trichloroethene 79-01-6 SM 6200B-20 ND 1ug/L0.0240.50 Trichlorofluoromethane 75-69-4 SM 6200B-20 ND 1ug/L0.0510.50 1,2,3-Trichloropropane 96-18-4 SM 6200B-20 ND 1ug/L0.330.50 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-20 ND 1ug/L0.170.50 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-20 ND 1ug/L0.170.50 Vinyl chloride 75-01-4 SM 6200B-20 ND 1ug/L0.0650.50 m+p - Xylenes 179601-23-1 SM 6200B-20 0.29 J 1ug/L0.170.50 o - Xylenes 95-47-6 SM 6200B-20 ND 1ug/L0.170.50 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 97 70-130 Toluene-d8 101 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-9 PH14008-006 08/12/2014 2137 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 08/21/2014 1554 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Benzene 71-43-2 SM 6200B-20 2.0 1ug/L0.0270.50 Bromobenzene 108-86-1 SM 6200B-20 ND 1ug/L0.0270.50 Bromochloromethane 74-97-5 SM 6200B-20 ND 1ug/L0.0550.50 Bromodichloromethane 75-27-4 SM 6200B-20 ND 1ug/L0.170.50 Bromoform 75-25-2 SM 6200B-20 ND 1ug/L0.0100.50 Bromomethane (Methyl bromide)74-83-9 SM 6200B-20 ND 1ug/L0.200.50 n-Butylbenzene 104-51-8 SM 6200B-20 ND 1ug/L0.0170.50 sec-Butylbenzene 135-98-8 SM 6200B-20 1.4 1ug/L0.0100.50 tert-Butylbenzene 98-06-6 SM 6200B-20 ND 1ug/L0.0370.50 Carbon tetrachloride 56-23-5 SM 6200B-20 ND 1ug/L0.0850.50 Chlorobenzene 108-90-7 SM 6200B-20 ND 1ug/L0.170.50 Chloroethane 75-00-3 SM 6200B-20 ND 1ug/L0.170.50 Chloroform 67-66-3 SM 6200B-20 ND 1ug/L0.170.50 Chloromethane (Methyl chloride)74-87-3 SM 6200B-20 ND 1ug/L0.170.50 2-Chlorotoluene 95-49-8 SM 6200B-20 ND 1ug/L0.0590.50 4-Chlorotoluene 106-43-4 SM 6200B-20 ND 1ug/L0.0190.50 Dibromochloromethane 124-48-1 SM 6200B-20 ND 1ug/L0.170.50 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-20 ND 1ug/L0.0610.50 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-20 ND 1ug/L0.0940.50 1,2-Dichlorobenzene 95-50-1 SM 6200B-20 ND 1ug/L0.170.50 1,3-Dichlorobenzene 541-73-1 SM 6200B-20 ND 1ug/L0.170.50 1,4-Dichlorobenzene 106-46-7 SM 6200B-20 ND 1ug/L0.170.50 Dichlorodifluoromethane 75-71-8 SM 6200B-20 ND 1ug/L0.0710.50 1,1-Dichloroethane 75-34-3 SM 6200B-20 ND 1ug/L0.0540.50 1,2-Dichloroethane 107-06-2 SM 6200B-20 1.3 1ug/L0.0230.50 1,1-Dichloroethene 75-35-4 SM 6200B-20 ND 1ug/L0.0940.50 cis-1,2-Dichloroethene 156-59-2 SM 6200B-20 ND 1ug/L0.0870.50 trans-1,2-Dichloroethene 156-60-5 SM 6200B-20 ND 1ug/L0.0790.50 1,2-Dichloropropane 78-87-5 SM 6200B-20 ND 1ug/L0.0810.50 1,3-Dichloropropane 142-28-9 SM 6200B-20 ND 1ug/L0.0190.50 2,2-Dichloropropane 594-20-7 SM 6200B-20 ND 1ug/L0.0600.50 1,1-Dichloropropene 563-58-6 SM 6200B-20 ND 1ug/L0.0740.50 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-20 ND 1ug/L0.0900.50 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-20 ND 1ug/L0.180.50 Diisopropyl ether (IPE)108-20-3 SM 6200B-20 0.59 1ug/L0.0520.50 Ethylbenzene 100-41-4 SM 6200B-20 0.31 J 1ug/L0.170.50 Hexachlorobutadiene 87-68-3 SM 6200B-20 ND 1ug/L0.170.50 Isopropylbenzene (Cumene)98-82-8 SM 6200B-20 0.69 1ug/L0.0290.50 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-20 ND 1ug/L0.0180.50 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-20 1.4 1ug/L0.0190.50 Methylene chloride 75-09-2 SM 6200B-20 ND 1ug/L0.170.50 Naphthalene 91-20-3 SM 6200B-20 ND 1ug/L0.170.50 n-Propylbenzene 103-65-1 SM 6200B-20 ND 1ug/L0.0240.50 Styrene 100-42-5 SM 6200B-20 ND 1ug/L0.0150.50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-9 PH14008-006 08/12/2014 2137 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 1 08/21/2014 1554 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-20 ND 1ug/L0.0570.50 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-20 ND 1ug/L0.0130.50 Tetrachloroethene 127-18-4 SM 6200B-20 ND 1ug/L0.0140.50 Toluene 108-88-3 SM 6200B-20 0.18 J 1ug/L0.170.50 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-20 ND 1ug/L0.300.50 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-20 ND 1ug/L0.170.50 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-20 ND 1ug/L0.170.50 1,1,1-Trichloroethane 71-55-6 SM 6200B-20 ND 1ug/L0.0290.50 1,1,2-Trichloroethane 79-00-5 SM 6200B-20 ND 1ug/L0.0310.50 Trichloroethene 79-01-6 SM 6200B-20 ND 1ug/L0.0240.50 Trichlorofluoromethane 75-69-4 SM 6200B-20 ND 1ug/L0.0510.50 1,2,3-Trichloropropane 96-18-4 SM 6200B-20 ND 1ug/L0.330.50 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-20 ND 1ug/L0.170.50 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-20 ND 1ug/L0.170.50 Vinyl chloride 75-01-4 SM 6200B-20 ND 1ug/L0.0650.50 m+p - Xylenes 179601-23-1 SM 6200B-20 0.45 J 1ug/L0.170.50 o - Xylenes 95-47-6 SM 6200B-20 ND 1ug/L0.170.50 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 97 70-130 Toluene-d8 101 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-12 PH14008-007 08/12/2014 2224 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 2030 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL Benzene 71-43-2 SM 6200B-20 7800 1ug/L1.425 Bromobenzene 108-86-1 SM 6200B-20 ND 1ug/L1.425 Bromochloromethane 74-97-5 SM 6200B-20 ND 1ug/L2.825 Bromodichloromethane 75-27-4 SM 6200B-20 ND 1ug/L8.525 Bromoform 75-25-2 SM 6200B-20 ND 1ug/L0.5125 Bromomethane (Methyl bromide)74-83-9 SM 6200B-20 ND 1ug/L1025 n-Butylbenzene 104-51-8 SM 6200B-20 ND 1ug/L0.8425 sec-Butylbenzene 135-98-8 SM 6200B-20 21 J 1ug/L0.5225 tert-Butylbenzene 98-06-6 SM 6200B-20 ND 1ug/L1.925 Carbon tetrachloride 56-23-5 SM 6200B-20 ND 1ug/L4.325 Chlorobenzene 108-90-7 SM 6200B-20 ND 1ug/L8.525 Chloroethane 75-00-3 SM 6200B-20 ND 1ug/L8.525 Chloroform 67-66-3 SM 6200B-20 ND 1ug/L8.525 Chloromethane (Methyl chloride)74-87-3 SM 6200B-20 ND 1ug/L8.725 2-Chlorotoluene 95-49-8 SM 6200B-20 ND 1ug/L3.025 4-Chlorotoluene 106-43-4 SM 6200B-20 ND 1ug/L0.9525 Dibromochloromethane 124-48-1 SM 6200B-20 ND 1ug/L8.525 1,2-Dibromoethane (EDB)106-93-4 SM 6200B-20 ND 1ug/L3.125 Dibromomethane (Methylene bromide)74-95-3 SM 6200B-20 ND 1ug/L4.725 1,2-Dichlorobenzene 95-50-1 SM 6200B-20 ND 1ug/L8.525 1,3-Dichlorobenzene 541-73-1 SM 6200B-20 ND 1ug/L8.525 1,4-Dichlorobenzene 106-46-7 SM 6200B-20 ND 1ug/L8.525 Dichlorodifluoromethane 75-71-8 SM 6200B-20 ND 1ug/L3.525 1,1-Dichloroethane 75-34-3 SM 6200B-20 ND 1ug/L2.725 1,2-Dichloroethane 107-06-2 SM 6200B-20 ND 1ug/L1.225 1,1-Dichloroethene 75-35-4 SM 6200B-20 ND 1ug/L4.725 cis-1,2-Dichloroethene 156-59-2 SM 6200B-20 ND 1ug/L4.425 trans-1,2-Dichloroethene 156-60-5 SM 6200B-20 ND 1ug/L4.025 1,2-Dichloropropane 78-87-5 SM 6200B-20 ND 1ug/L4.125 1,3-Dichloropropane 142-28-9 SM 6200B-20 ND 1ug/L0.9525 2,2-Dichloropropane 594-20-7 SM 6200B-20 ND 1ug/L3.025 1,1-Dichloropropene 563-58-6 SM 6200B-20 ND 1ug/L3.725 cis-1,3-Dichloropropene 10061-01-5 SM 6200B-20 ND 1ug/L4.525 trans-1,3-Dichloropropene 10061-02-6 SM 6200B-20 ND 1ug/L9.025 Diisopropyl ether (IPE)108-20-3 SM 6200B-20 46 1ug/L2.625 Ethylbenzene 100-41-4 SM 6200B-20 2900 1ug/L8.525 Hexachlorobutadiene 87-68-3 SM 6200B-20 ND 1ug/L8.525 Isopropylbenzene (Cumene)98-82-8 SM 6200B-20 160 1ug/L1.425 p-Isopropyltoluene (p-Cymene)99-87-6 SM 6200B-20 ND 1ug/L0.8925 Methyl tertiary butyl ether (MTBE)1634-04-4 SM 6200B-20 99 1ug/L0.9525 Methylene chloride 75-09-2 SM 6200B-20 ND 1ug/L8.525 Naphthalene 91-20-3 SM 6200B-20 330 1ug/L8.525 n-Propylbenzene 103-65-1 SM 6200B-20 360 1ug/L1.225 Styrene 100-42-5 SM 6200B-20 ND 1ug/L0.7525 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Terracon Consultants, Inc. MW-12 PH14008-007 08/12/2014 2224 08/14/2014 Aqueous Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 SM 6200B-SM 6200B-2011 50 08/21/2014 2030 EH1 54542 AnalyticalCAS Parameter Number Method Result Q PQL Units RunMDL 1,1,1,2-Tetrachloroethane 630-20-6 SM 6200B-20 ND 1ug/L2.925 1,1,2,2-Tetrachloroethane 79-34-5 SM 6200B-20 ND 1ug/L0.6525 Tetrachloroethene 127-18-4 SM 6200B-20 ND 1ug/L0.7225 Toluene 108-88-3 SM 6200B-20 3600 1ug/L8.525 1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 SM 6200B-20 ND 1ug/L1525 1,2,3-Trichlorobenzene 87-61-6 SM 6200B-20 ND 1ug/L8.525 1,2,4-Trichlorobenzene 120-82-1 SM 6200B-20 ND 1ug/L8.525 1,1,1-Trichloroethane 71-55-6 SM 6200B-20 ND 1ug/L1.425 1,1,2-Trichloroethane 79-00-5 SM 6200B-20 ND 1ug/L1.625 Trichloroethene 79-01-6 SM 6200B-20 ND 1ug/L1.225 Trichlorofluoromethane 75-69-4 SM 6200B-20 ND 1ug/L2.525 1,2,3-Trichloropropane 96-18-4 SM 6200B-20 ND 1ug/L1725 1,3,5-Trimethylbenzene (Mesitylene)108-67-8 SM 6200B-20 640 1ug/L8.525 1,2,4-Trimethylbenzene 95-63-6 SM 6200B-20 2200 1ug/L8.525 Vinyl chloride 75-01-4 SM 6200B-20 ND 1ug/L3.325 m+p - Xylenes 179601-23-1 SM 6200B-20 6000 1ug/L8.525 o - Xylenes 95-47-6 SM 6200B-20 2700 1ug/L8.525 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 102 70-130 Bromofluorobenzene 95 70-130 Toluene-d8 101 70-130 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary Page: 20 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:PQ54542-001 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil Benzene ND 08/21/2014 12420.50 0.027 ug/L1 Bromobenzene ND 08/21/2014 12420.50 0.027 ug/L1 Bromochloromethane ND 08/21/2014 12420.50 0.055 ug/L1 Bromodichloromethane ND 08/21/2014 12420.50 0.17 ug/L1 Bromoform ND 08/21/2014 12420.50 0.010 ug/L1 Bromomethane (Methyl bromide)ND 08/21/2014 12420.50 0.20 ug/L1 tert-Butylbenzene ND 08/21/2014 12420.50 0.037 ug/L1 sec-Butylbenzene ND 08/21/2014 12420.50 0.010 ug/L1 n-Butylbenzene ND 08/21/2014 12420.50 0.017 ug/L1 Carbon tetrachloride ND 08/21/2014 12420.50 0.085 ug/L1 Chlorobenzene ND 08/21/2014 12420.50 0.17 ug/L1 Chloroethane ND 08/21/2014 12420.50 0.17 ug/L1 Chloroform ND 08/21/2014 12420.50 0.17 ug/L1 Chloromethane (Methyl chloride)ND 08/21/2014 12420.50 0.17 ug/L1 4-Chlorotoluene ND 08/21/2014 12420.50 0.019 ug/L1 2-Chlorotoluene ND 08/21/2014 12420.50 0.059 ug/L1 Dibromochloromethane ND 08/21/2014 12420.50 0.17 ug/L1 1,2-Dibromoethane (EDB)ND 08/21/2014 12420.50 0.061 ug/L1 Dibromomethane (Methylene bromide)ND 08/21/2014 12420.50 0.094 ug/L1 1,4-Dichlorobenzene ND 08/21/2014 12420.50 0.17 ug/L1 1,3-Dichlorobenzene ND 08/21/2014 12420.50 0.17 ug/L1 1,2-Dichlorobenzene ND 08/21/2014 12420.50 0.17 ug/L1 Dichlorodifluoromethane ND 08/21/2014 12420.50 0.071 ug/L1 1,2-Dichloroethane ND 08/21/2014 12420.50 0.023 ug/L1 1,1-Dichloroethane ND 08/21/2014 12420.50 0.054 ug/L1 trans-1,2-Dichloroethene ND 08/21/2014 12420.50 0.079 ug/L1 cis-1,2-Dichloroethene ND 08/21/2014 12420.50 0.087 ug/L1 1,1-Dichloroethene ND 08/21/2014 12420.50 0.094 ug/L1 2,2-Dichloropropane ND 08/21/2014 12420.50 0.060 ug/L1 1,3-Dichloropropane ND 08/21/2014 12420.50 0.019 ug/L1 1,2-Dichloropropane ND 08/21/2014 12420.50 0.081 ug/L1 trans-1,3-Dichloropropene ND 08/21/2014 12420.50 0.18 ug/L1 cis-1,3-Dichloropropene ND 08/21/2014 12420.50 0.090 ug/L1 1,1-Dichloropropene ND 08/21/2014 12420.50 0.074 ug/L1 Diisopropyl ether (IPE)ND 08/21/2014 12420.50 0.052 ug/L1 Ethylbenzene ND 08/21/2014 12420.50 0.17 ug/L1 Hexachlorobutadiene ND 08/21/2014 12420.50 0.17 ug/L1 Isopropylbenzene (Cumene)ND 08/21/2014 12420.50 0.029 ug/L1 p-Isopropyltoluene (p-Cymene)ND 08/21/2014 12420.50 0.018 ug/L1 Methyl tertiary butyl ether (MTBE)ND 08/21/2014 12420.50 0.019 ug/L1 Methylene chloride ND 08/21/2014 12420.50 0.17 ug/L1 Naphthalene ND 08/21/2014 12420.50 0.17 ug/L1 n-Propylbenzene ND 08/21/2014 12420.50 0.024 ug/L1 Styrene ND 08/21/2014 12420.50 0.015 ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 21 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - MB Batch:Prep Method: Sample ID:PQ54542-001 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q PQL MDL Units Analysis DateDil 1,1,2,2-Tetrachloroethane ND 08/21/2014 12420.50 0.013 ug/L1 1,1,1,2-Tetrachloroethane ND 08/21/2014 12420.50 0.057 ug/L1 Tetrachloroethene ND 08/21/2014 12420.50 0.014 ug/L1 Toluene ND 08/21/2014 12420.50 0.17 ug/L1 1,1,2-Trichloro-1,2,2-Trifluoroethane ND 08/21/2014 12420.50 0.30 ug/L1 1,2,4-Trichlorobenzene ND 08/21/2014 12420.50 0.17 ug/L1 1,2,3-Trichlorobenzene ND 08/21/2014 12420.50 0.17 ug/L1 1,1,2-Trichloroethane ND 08/21/2014 12420.50 0.031 ug/L1 1,1,1-Trichloroethane ND 08/21/2014 12420.50 0.029 ug/L1 Trichloroethene ND 08/21/2014 12420.50 0.024 ug/L1 Trichlorofluoromethane ND 08/21/2014 12420.50 0.051 ug/L1 1,2,3-Trichloropropane ND 08/21/2014 12420.50 0.33 ug/L1 1,2,4-Trimethylbenzene ND 08/21/2014 12420.50 0.17 ug/L1 1,3,5-Trimethylbenzene (Mesitylene)ND 08/21/2014 12420.50 0.17 ug/L1 Vinyl chloride ND 08/21/2014 12420.50 0.065 ug/L1 o - Xylenes ND 08/21/2014 12420.50 0.17 ug/L1 m+p - Xylenes ND 08/21/2014 12420.50 0.17 ug/L1 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 102 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 22 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:PQ54542-002 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Benzene 49 08/21/2014 1108995070-1301 Bromobenzene 49 08/21/2014 1108995070-1301 Bromochloromethane 50 08/21/2014 11081015070-1301 Bromodichloromethane 51 08/21/2014 11081025070-1301 Bromoform 53 08/21/2014 11081065070-1301 Bromomethane (Methyl bromide)46 08/21/2014 1108925060-1401 tert-Butylbenzene 49 08/21/2014 1108985070-1301 sec-Butylbenzene 48 08/21/2014 1108975070-1301 n-Butylbenzene 50 08/21/2014 11081015070-1301 Carbon tetrachloride 52 08/21/2014 11081035070-1301 Chlorobenzene 49 08/21/2014 1108995070-1301 Chloroethane 48 08/21/2014 1108965042-1631 Chloroform 50 08/21/2014 1108995070-1301 Chloromethane (Methyl chloride)49 08/21/2014 1108975020-1581 4-Chlorotoluene 50 08/21/2014 1108995070-1301 2-Chlorotoluene 47 08/21/2014 1108955070-1301 Dibromochloromethane 52 08/21/2014 11081055070-1301 1,2-Dibromoethane (EDB)50 08/21/2014 11081005070-1301 Dibromomethane (Methylene bromide)49 08/21/2014 1108985070-1301 1,4-Dichlorobenzene 49 08/21/2014 1108985070-1301 1,3-Dichlorobenzene 49 08/21/2014 1108985070-1301 1,2-Dichlorobenzene 50 08/21/2014 1108995070-1301 Dichlorodifluoromethane 50 08/21/2014 1108995060-1401 1,2-Dichloroethane 49 08/21/2014 1108985070-1301 1,1-Dichloroethane 50 08/21/2014 11081005070-1301 trans-1,2-Dichloroethene 51 08/21/2014 11081015070-1301 cis-1,2-Dichloroethene 50 08/21/2014 1108995070-1301 1,1-Dichloroethene 52 08/21/2014 11081035070-1301 2,2-Dichloropropane 55 08/21/2014 11081105070-1301 1,3-Dichloropropane 49 08/21/2014 1108985070-1301 1,2-Dichloropropane 49 08/21/2014 1108995070-1301 trans-1,3-Dichloropropene 52 08/21/2014 11081045070-1301 cis-1,3-Dichloropropene 52 08/21/2014 11081055070-1301 1,1-Dichloropropene 49 08/21/2014 1108985070-1301 Diisopropyl ether (IPE)50 08/21/2014 11081005070-1301 Ethylbenzene 50 08/21/2014 1108995070-1301 Hexachlorobutadiene 52 08/21/2014 11081045070-1301 Isopropylbenzene (Cumene)48 08/21/2014 1108975070-1301 p-Isopropyltoluene (p-Cymene)50 08/21/2014 11081005070-1301 Methyl tertiary butyl ether (MTBE)49 08/21/2014 1108995070-1301 Methylene chloride 49 08/21/2014 1108985070-1301 Naphthalene 53 08/21/2014 11081055050-1401 n-Propylbenzene 48 08/21/2014 1108975070-1301 Styrene 52 08/21/2014 11081045070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 23 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - LCS Batch:Prep Method: Sample ID:PQ54542-002 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) 1,1,2,2-Tetrachloroethane 48 08/21/2014 1108965070-1301 1,1,1,2-Tetrachloroethane 51 08/21/2014 11081015070-1301 Tetrachloroethene 49 08/21/2014 1108985070-1301 Toluene 50 08/21/2014 1108995070-1301 1,1,2-Trichloro-1,2,2-Trifluoroethane 64 08/21/2014 11081295070-1301 1,2,4-Trichlorobenzene 52 08/21/2014 11081055070-1301 1,2,3-Trichlorobenzene 53 08/21/2014 11081055070-1301 1,1,2-Trichloroethane 49 08/21/2014 1108985070-1301 1,1,1-Trichloroethane 51 08/21/2014 11081025070-1301 Trichloroethene 50 08/21/2014 1108995070-1301 Trichlorofluoromethane 49 08/21/2014 1108985060-1401 1,2,3-Trichloropropane 48 08/21/2014 1108965070-1301 1,2,4-Trimethylbenzene 49 08/21/2014 1108995070-1301 1,3,5-Trimethylbenzene (Mesitylene)49 08/21/2014 1108995070-1301 Vinyl chloride 50 08/21/2014 1108995060-1401 o - Xylenes 50 08/21/2014 1108995070-1301 m+p - Xylenes 50 08/21/2014 11081005070-1301 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 102 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 24 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - LCSD Batch:Prep Method: Sample ID:PQ54542-003 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Benzene 49 08/21/2014 1131985070-1300.38 201 Bromobenzene 50 08/21/2014 1131995070-1300.58 201 Bromochloromethane 51 08/21/2014 11311015070-1300.14 201 Bromodichloromethane 52 08/21/2014 11311035070-1300.70 201 Bromoform 54 08/21/2014 11311085070-1301.8 201 Bromomethane (Methyl bromide)48 08/21/2014 1131965060-1404.1 201 tert-Butylbenzene 49 08/21/2014 1131995070-1300.72 201 sec-Butylbenzene 49 08/21/2014 1131995070-1302.0 201 n-Butylbenzene 51 08/21/2014 11311025070-1301.1 201 Carbon tetrachloride 51 08/21/2014 11311035070-1300.45 201 Chlorobenzene 50 08/21/2014 11311005070-1300.60 201 Chloroethane 49 08/21/2014 1131985042-1632.5 201 Chloroform 50 08/21/2014 1131995070-1300.028 201 Chloromethane (Methyl chloride)46 08/21/2014 1131935020-1584.4 201 4-Chlorotoluene 51 08/21/2014 11311025070-1302.7 201 2-Chlorotoluene 49 08/21/2014 1131975070-1302.8 201 Dibromochloromethane 53 08/21/2014 11311065070-1300.99 201 1,2-Dibromoethane (EDB)50 08/21/2014 11311015070-1301.4 201 Dibromomethane (Methylene bromide)49 08/21/2014 1131985070-1300.11 201 1,4-Dichlorobenzene 49 08/21/2014 1131995070-1300.97 201 1,3-Dichlorobenzene 49 08/21/2014 1131995070-1300.13 201 1,2-Dichlorobenzene 50 08/21/2014 11311005070-1300.88 201 Dichlorodifluoromethane 48 08/21/2014 1131965060-1403.2 201 1,2-Dichloroethane 49 08/21/2014 1131985070-1300.11 201 1,1-Dichloroethane 50 08/21/2014 11311005070-1300.42 201 trans-1,2-Dichloroethene 51 08/21/2014 11311015070-1300.24 201 cis-1,2-Dichloroethene 50 08/21/2014 11311005070-1300.62 201 1,1-Dichloroethene 52 08/21/2014 11311045070-1301.1 201 2,2-Dichloropropane 52 08/21/2014 11311055070-1304.9 201 1,3-Dichloropropane 49 08/21/2014 1131985070-1300.16 201 1,2-Dichloropropane 49 08/21/2014 1131985070-1300.31 201 trans-1,3-Dichloropropene 53 08/21/2014 11311055070-1301.4 201 cis-1,3-Dichloropropene 52 08/21/2014 11311055070-1300.038 201 1,1-Dichloropropene 50 08/21/2014 1131995070-1300.83 201 Diisopropyl ether (IPE)53 08/21/2014 11311065070-1305.3 201 Ethylbenzene 50 08/21/2014 11311015070-1301.8 201 Hexachlorobutadiene 51 08/21/2014 11311035070-1301.3 201 Isopropylbenzene (Cumene)50 08/21/2014 1131995070-1303.0 201 p-Isopropyltoluene (p-Cymene)51 08/21/2014 11311015070-1301.0 201 Methyl tertiary butyl ether (MTBE)52 08/21/2014 11311045070-1305.5 201 Methylene chloride 48 08/21/2014 1131975070-1301.6 201 Naphthalene 51 08/21/2014 11311035050-1402.2 201 n-Propylbenzene 49 08/21/2014 1131995070-1302.4 201 Styrene 52 08/21/2014 11311045070-1300.10 201 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 25 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - LCSD Batch:Prep Method: Sample ID:PQ54542-003 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) 1,1,2,2-Tetrachloroethane 49 08/21/2014 1131975070-1301.5 201 1,1,1,2-Tetrachloroethane 51 08/21/2014 11311035070-1301.2 201 Tetrachloroethene 50 08/21/2014 1131995070-1301.0 201 Toluene 50 08/21/2014 11311005070-1300.15 201 1,1,2-Trichloro-1,2,2-Trifluoroethane 59 08/21/2014 11311195070-1308.1 201 1,2,4-Trichlorobenzene 51 08/21/2014 11311025070-1302.6 201 1,2,3-Trichlorobenzene 50 08/21/2014 11311005070-1304.7 201 1,1,2-Trichloroethane 50 08/21/2014 11311005070-1301.3 201 1,1,1-Trichloroethane 50 08/21/2014 11311015070-1300.80 201 Trichloroethene 50 08/21/2014 11311005070-1300.49 201 Trichlorofluoromethane 50 08/21/2014 11311015060-1403.1 201 1,2,3-Trichloropropane 49 08/21/2014 1131985070-1302.8 201 1,2,4-Trimethylbenzene 49 08/21/2014 1131995070-1300.45 201 1,3,5-Trimethylbenzene (Mesitylene)50 08/21/2014 11311015070-1302.0 201 Vinyl chloride 48 08/21/2014 1131955060-1403.9 201 o - Xylenes 50 08/21/2014 11311015070-1301.7 201 m+p - Xylenes 50 08/21/2014 11311015070-1301.2 201 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 101 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 26 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - MS Batch:Prep Method: Sample ID:PH14008-007MS 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Benzene 10000 08/21/2014 2053E97250070-130780050 Bromobenzene 2500 08/21/2014 2053100250070-130ND50 Bromochloromethane 2300 08/21/2014 205393250070-130ND50 Bromodichloromethane 2500 08/21/2014 2053100250070-130ND50 Bromoform 2400 08/21/2014 205394250070-130ND50 Bromomethane (Methyl bromide)2500 08/21/2014 205398250060-140ND50 n-Butylbenzene 2700 08/21/2014 2053108250070-130ND50 sec-Butylbenzene 2600 08/21/2014 2053104250070-1302150 tert-Butylbenzene 2900 08/21/2014 2053116250070-130ND50 Carbon tetrachloride 2600 08/21/2014 2053104250070-130ND50 Chlorobenzene 2500 08/21/2014 2053101250070-130ND50 Chloroethane 2700 08/21/2014 2053109250042-163ND50 Chloroform 2500 08/21/2014 205399250070-130ND50 Chloromethane (Methyl chloride)2400 08/21/2014 205394250020-158ND50 2-Chlorotoluene 2800 08/21/2014 2053111250070-130ND50 4-Chlorotoluene 2600 08/21/2014 2053103250070-130ND50 Dibromochloromethane 2500 08/21/2014 2053100250070-130ND50 1,2-Dibromoethane (EDB)2400 08/21/2014 205396250070-130ND50 Dibromomethane (Methylene bromide)2300 08/21/2014 205393250070-130ND50 1,2-Dichlorobenzene 2500 08/21/2014 205399250070-130ND50 1,3-Dichlorobenzene 2500 08/21/2014 205399250070-130ND50 1,4-Dichlorobenzene 2500 08/21/2014 205399250070-130ND50 Dichlorodifluoromethane 2600 08/21/2014 2053103250060-140ND50 1,1-Dichloroethane 2600 08/21/2014 2053102250070-130ND50 1,2-Dichloroethane 2700 08/21/2014 2053107250070-130ND50 1,1-Dichloroethene 2800 08/21/2014 2053112250070-130ND50 cis-1,2-Dichloroethene 2500 08/21/2014 205399250070-130ND50 trans-1,2-Dichloroethene 2600 08/21/2014 2053103250070-130ND50 1,2-Dichloropropane 2500 08/21/2014 205399250070-130ND50 1,3-Dichloropropane 2400 08/21/2014 205396250070-130ND50 2,2-Dichloropropane 2100 08/21/2014 205385250070-130ND50 1,1-Dichloropropene 2600 08/21/2014 2053103250070-130ND50 cis-1,3-Dichloropropene 2400 08/21/2014 205397250070-130ND50 trans-1,3-Dichloropropene 2400 08/21/2014 205397250070-130ND50 Diisopropyl ether (IPE)2600 08/21/2014 2053101250070-1304650 Ethylbenzene 5600 08/21/2014 2053109250070-130290050 Hexachlorobutadiene 2700 08/21/2014 2053108250070-130ND50 Isopropylbenzene (Cumene)2700 08/21/2014 2053103250070-13016050 p-Isopropyltoluene (p-Cymene)2700 08/21/2014 2053107250070-130ND50 Methyl tertiary butyl ether (MTBE)2400 08/21/2014 205392250070-1309950 Methylene chloride 2500 08/21/2014 2053100250070-130ND50 Naphthalene 2900 08/21/2014 2053102250050-14033050 n-Propylbenzene 2900 08/21/2014 2053103250070-13036050 Styrene 2700 08/21/2014 2053107250070-130ND50 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 27 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - MS Batch:Prep Method: Sample ID:PH14008-007MS 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) 1,1,1,2-Tetrachloroethane 2500 08/21/2014 2053101250070-130ND50 1,1,2,2-Tetrachloroethane 2300 08/21/2014 205390250070-130ND50 Tetrachloroethene 2600 08/21/2014 2053104250070-130ND50 Toluene 6200 08/21/2014 2053101250070-130360050 1,1,2-Trichloro-1,2,2-Trifluoroethane 3100 08/21/2014 2053124250070-130ND50 1,2,3-Trichlorobenzene 2700 08/21/2014 2053107250070-130ND50 1,2,4-Trichlorobenzene 2700 08/21/2014 2053106250070-130ND50 1,1,1-Trichloroethane 2600 08/21/2014 2053103250070-130ND50 1,1,2-Trichloroethane 2400 08/21/2014 205396250070-130ND50 Trichloroethene 2600 08/21/2014 2053103250070-130ND50 Trichlorofluoromethane 2700 08/21/2014 2053107250060-140ND50 1,2,3-Trichloropropane 2200 08/21/2014 205388250070-130ND50 1,3,5-Trimethylbenzene (Mesitylene)3300 08/21/2014 2053106250070-13064050 1,2,4-Trimethylbenzene 4800 08/21/2014 2053103250070-130220050 Vinyl chloride 2600 08/21/2014 2053103250060-140ND50 m+p - Xylenes 8700 08/21/2014 2053110250070-130600050 o - Xylenes 5300 08/21/2014 2053104250070-130270050 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 93 70-130 Bromofluorobenzene 97 70-130 Toluene-d8 102 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 28 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - MSD Batch:Prep Method: Sample ID:PH14008-007MD 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) Benzene 10000 08/21/2014 2116E93250070-1301.1 20780050 Bromobenzene 2500 08/21/2014 211698250070-1301.7 20ND50 Bromochloromethane 2400 08/21/2014 211697250070-1304.5 20ND50 Bromodichloromethane 2500 08/21/2014 2116101250070-1300.89 20ND50 Bromoform 2400 08/21/2014 211695250070-1301.2 20ND50 Bromomethane (Methyl bromide)2400 08/21/2014 211696250060-1402.1 20ND50 n-Butylbenzene 2500 08/21/2014 2116102250070-1305.4 20ND50 sec-Butylbenzene 2500 08/21/2014 211698250070-1306.2 202150 tert-Butylbenzene 2800 08/21/2014 2116110250070-1305.2 20ND50 Carbon tetrachloride 2500 08/21/2014 2116101250070-1303.2 20ND50 Chlorobenzene 2500 08/21/2014 211699250070-1302.8 20ND50 Chloroethane 2700 08/21/2014 2116107250042-1631.6 20ND50 Chloroform 2500 08/21/2014 211698250070-1300.89 20ND50 Chloromethane (Methyl chloride)2300 08/21/2014 211691250020-1584.1 20ND50 2-Chlorotoluene 2700 08/21/2014 2116107250070-1303.7 20ND50 4-Chlorotoluene 2500 08/21/2014 211698250070-1304.2 20ND50 Dibromochloromethane 2500 08/21/2014 2116101250070-1300.39 20ND50 1,2-Dibromoethane (EDB)2400 08/21/2014 211697250070-1301.1 20ND50 Dibromomethane (Methylene bromide)2300 08/21/2014 211694250070-1300.55 20ND50 1,2-Dichlorobenzene 2400 08/21/2014 211697250070-1301.8 20ND50 1,3-Dichlorobenzene 2400 08/21/2014 211697250070-1302.3 20ND50 1,4-Dichlorobenzene 2400 08/21/2014 211695250070-1303.4 20ND50 Dichlorodifluoromethane 2400 08/21/2014 211697250060-1406.7 20ND50 1,1-Dichloroethane 2500 08/21/2014 2116100250070-1301.9 20ND50 1,2-Dichloroethane 2700 08/21/2014 2116109250070-1302.3 20ND50 1,1-Dichloroethene 2700 08/21/2014 2116110250070-1301.8 20ND50 cis-1,2-Dichloroethene 2500 08/21/2014 211698250070-1301.0 20ND50 trans-1,2-Dichloroethene 2500 08/21/2014 2116101250070-1301.8 20ND50 1,2-Dichloropropane 2400 08/21/2014 211698250070-1300.89 20ND50 1,3-Dichloropropane 2400 08/21/2014 211696250070-1300.18 20ND50 2,2-Dichloropropane 2100 08/21/2014 211682250070-1303.3 20ND50 1,1-Dichloropropene 2500 08/21/2014 211699250070-1303.8 20ND50 cis-1,3-Dichloropropene 2400 08/21/2014 211697250070-1300.36 20ND50 trans-1,3-Dichloropropene 2400 08/21/2014 211697250070-1300.18 20ND50 Diisopropyl ether (IPE)2500 08/21/2014 2116100250070-1301.1 204650 Ethylbenzene 5400 08/21/2014 2116102250070-1303.2 20290050 Hexachlorobutadiene 2600 08/21/2014 2116103250070-1304.4 20ND50 Isopropylbenzene (Cumene)2600 08/21/2014 211699250070-1304.4 2016050 p-Isopropyltoluene (p-Cymene)2500 08/21/2014 2116100250070-1306.1 20ND50 Methyl tertiary butyl ether (MTBE)2400 08/21/2014 211693250070-1301.5 209950 Methylene chloride 2500 08/21/2014 2116100250070-1300.18 20ND50 Naphthalene 2900 08/21/2014 2116104250050-1402.4 2033050 n-Propylbenzene 2800 08/21/2014 211697250070-1304.8 2036050 Styrene 2600 08/21/2014 2116105250070-1301.8 20ND50 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 29 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Volatile Organic Compounds by GC/MS - MSD Batch:Prep Method: Sample ID:PH14008-007MD 54542 SM 6200B-2011 Analytical Method:SM 6200B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(ug/L)(ug/L)(ug/L) 1,1,1,2-Tetrachloroethane 2500 08/21/2014 2116101250070-1300.45 20ND50 1,1,2,2-Tetrachloroethane 2300 08/21/2014 211691250070-1300.49 20ND50 Tetrachloroethene 2500 08/21/2014 2116100250070-1304.0 20ND50 Toluene 6100 08/21/2014 211698250070-1301.3 20360050 1,1,2-Trichloro-1,2,2-Trifluoroethane 3100 08/21/2014 2116125250070-1300.80 20ND50 1,2,3-Trichlorobenzene 2700 08/21/2014 2116108250070-1300.15 20ND50 1,2,4-Trichlorobenzene 2600 08/21/2014 2116104250070-1301.6 20ND50 1,1,1-Trichloroethane 2500 08/21/2014 2116102250070-1301.2 20ND50 1,1,2-Trichloroethane 2400 08/21/2014 211697250070-1300.97 20ND50 Trichloroethene 2500 08/21/2014 2116100250070-1302.7 20ND50 Trichlorofluoromethane 2500 08/21/2014 2116101250060-1405.5 20ND50 1,2,3-Trichloropropane 2200 08/21/2014 211690250070-1302.0 20ND50 1,3,5-Trimethylbenzene (Mesitylene)3100 08/21/2014 2116100250070-1304.9 2064050 1,2,4-Trimethylbenzene 4600 08/21/2014 211697250070-1303.3 20220050 Vinyl chloride 2500 08/21/2014 2116101250060-1402.5 20ND50 m+p - Xylenes 8500 08/21/2014 2116102250070-1302.1 20600050 o - Xylenes 5200 08/21/2014 211699250070-1302.6 20270050 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 95 70-130 Bromofluorobenzene 96 70-130 Toluene-d8 101 70-130 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ Page: 30 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 APPENDIX B PHOTOGRAPHS Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 Date photographs taken: August 12, 2014 Photo #1 View of the site Photo #2 View of the adjoining property to the north Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 Date photographs taken: August 12, 2014 Photo #3 View of the adjoining residential property to the east with monitoring well MW-11 Photo #4 Former location of the 2,000-gallon gasoline USTs, 275-gallon gasoline UST, 270- gallon kerosene UST, and 500-gallon kerosene AST MW-11 Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 Date photographs taken: August 12, 2014 Photo #5 View of the southern portion of the site and adjoining property to the south Photo #6 View of the adjoining property to the east Former Caraway Grocery Asheboro, North Carolina Terracon Project No. 70149641 Incident No. 24174 Date photographs taken: August 12, 2014 Photo #7 View of the adjoining property to the west APPENDIX C Water Supply Well Map (Pyramid Environmental & Engineering, P.C. dated March 18, 2010)