WS-6406_24174_CA_LAB_20100528

May 28, 2010
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9269887
9269887
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR-UST Section
1637 Mail Service Center
Raleigh, NC 27699
CARAWAY GROCERY
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on May 20, 2010. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Charlotte Certification IDsFlorida/NELAP Certification #: E87627Connecticut Certification #: PH-0104
Louisiana/LELAP Certification #: 04034New Jersey Certification #: NC012North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12
Pennsylvania Certification #: 68-00784
South Carolina Certification #: 99006001South Carolina Drinking Water Cert. #: 99006003
Tennessee Certification #: 04010Virginia Certification #: 00213West Virginia Certification #: 3579800 Kincey Ave. - Ste 100 Huntersville, NC 28078Kentucky UST Certification #: 84
Asheville Certification IDs
Connecticut Certification #: PH-0106Florida/NELAP Certification #: E87648Louisiana/LELAP Certification #: 03095
Massachusetts Certification #: M-NC030New Jersey Certification #: NC011
North Carolina Bioassay Certification #: 9North Carolina Drinking Water Certification #: 37712North Carolina Wastewater Certification #: 40
Pennsylvania Certification #: 68-03578South Carolina Bioassay Certification #: 9903002South Carolina Certification #: 9903001
Tennessee Certification #: 2980Virginia Certification #: 00072
2225 Riverside Dr. Asheville, NC 28804West Virginia Certification #: 356
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9269887001 BABER SW EPA 6010 1 PASI-AJMW
SM 6200B 65 PASI-CKJM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Method:
Client:Pyramid_FTF
EPA 6010
Date:May 28, 2010
Description:6010 MET ICP, 3030C
General Information:
1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with SM 3030C with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Method:
Client:Pyramid_FTF
SM 6200B
Date:May 28, 2010
Description:6200B MSV
General Information:
1 sample was analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/11013
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9269887001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 446894)
• 1,1,1-Trichloroethane
• 1,1-Dichloroethane
• 1,1-Dichloroethene
• 1,1-Dichloropropene
• 1,2-Dichloropropane
• 2,2-Dichloropropane
• Benzene
• Chloroethane
• Diisopropyl ether
• Ethanol
• Methylene Chloride
• Vinyl chloride
• cis-1,2-Dichloroethene
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Method:
Client:Pyramid_FTF
SM 6200B
Date:May 28, 2010
Description:6200B MSV
QC Batch: MSV/11013
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9269887001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• n-Propylbenzene
• trans-1,2-Dichloroethene
• MSD (Lab ID: 446895)
• 1,1,1-Trichloroethane
• 1,1-Dichloroethane
• 1,1-Dichloroethene
• 1,1-Dichloropropene
• 1,2-Dichloropropane
• 2,2-Dichloropropane
• 4-Chlorotoluene
• Benzene
• Bromobenzene
• Chloroethane
• Diisopropyl ether
• Ethanol
• Methylene Chloride
• Vinyl chloride
• cis-1,2-Dichloroethene
• n-Butylbenzene
• n-Propylbenzene
• trans-1,2-Dichloroethene
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Sample:BABER SW Lab ID:9269887001 Collected:05/19/10 09:25 Received:05/20/10 11:58 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6010 MET ICP, 3030C Analytical Method: EPA 6010 Preparation Method: SM 3030C
Lead ND ug/L 1 05/26/10 23:50 7439-92-105/22/10 09:555.0
6200B MSV Analytical Method: SM 6200B
Benzene ND ug/L 1 05/24/10 19:04 71-43-20.50
Bromobenzene ND ug/L 1 05/24/10 19:04 108-86-10.50
Bromochloromethane ND ug/L 1 05/24/10 19:04 74-97-50.50
Bromodichloromethane ND ug/L 1 05/24/10 19:04 75-27-40.50
Bromoform ND ug/L 1 05/24/10 19:04 75-25-20.50
Bromomethane ND ug/L 1 05/24/10 19:04 74-83-95.0
n-Butylbenzene ND ug/L 1 05/24/10 19:04 104-51-80.50
sec-Butylbenzene ND ug/L 1 05/24/10 19:04 135-98-80.50
tert-Butylbenzene ND ug/L 1 05/24/10 19:04 98-06-60.50
Carbon tetrachloride ND ug/L 1 05/24/10 19:04 56-23-50.50
Chlorobenzene ND ug/L 1 05/24/10 19:04 108-90-70.50
Chloroethane ND ug/L 1 05/24/10 19:04 75-00-31.0
Chloroform ND ug/L 1 05/24/10 19:04 67-66-30.50
Chloromethane ND ug/L 1 05/24/10 19:04 74-87-31.0
2-Chlorotoluene ND ug/L 1 05/24/10 19:04 95-49-80.50
4-Chlorotoluene ND ug/L 1 05/24/10 19:04 106-43-40.50
1,2-Dibromo-3-chloropropane ND ug/L 1 05/24/10 19:04 96-12-81.0
Dibromochloromethane ND ug/L 1 05/24/10 19:04 124-48-10.50
1,2-Dibromoethane (EDB)ND ug/L 1 05/24/10 19:04 106-93-40.50
Dibromomethane ND ug/L 1 05/24/10 19:04 74-95-30.50
1,2-Dichlorobenzene ND ug/L 1 05/24/10 19:04 95-50-10.50
1,3-Dichlorobenzene ND ug/L 1 05/24/10 19:04 541-73-10.50
1,4-Dichlorobenzene ND ug/L 1 05/24/10 19:04 106-46-70.50
Dichlorodifluoromethane ND ug/L 1 05/24/10 19:04 75-71-80.50
1,1-Dichloroethane ND ug/L 1 05/24/10 19:04 75-34-30.50
1,2-Dichloroethane ND ug/L 1 05/24/10 19:04 107-06-20.50
1,1-Dichloroethene ND ug/L 1 05/24/10 19:04 75-35-40.50
cis-1,2-Dichloroethene ND ug/L 1 05/24/10 19:04 156-59-20.50
trans-1,2-Dichloroethene ND ug/L 1 05/24/10 19:04 156-60-50.50
1,2-Dichloropropane ND ug/L 1 05/24/10 19:04 78-87-50.50
1,3-Dichloropropane ND ug/L 1 05/24/10 19:04 142-28-90.50
2,2-Dichloropropane ND ug/L 1 05/24/10 19:04 594-20-70.50
1,1-Dichloropropene ND ug/L 1 05/24/10 19:04 563-58-60.50
cis-1,3-Dichloropropene ND ug/L 1 05/24/10 19:04 10061-01-50.50
trans-1,3-Dichloropropene ND ug/L 1 05/24/10 19:04 10061-02-60.50
Diisopropyl ether ND ug/L 1 05/24/10 19:04 108-20-30.50
Ethanol ND ug/L 1 05/24/10 19:04 64-17-5200
Ethylbenzene ND ug/L 1 05/24/10 19:04 100-41-40.50
Hexachloro-1,3-butadiene ND ug/L 1 05/24/10 19:04 87-68-32.0
Isopropylbenzene (Cumene)ND ug/L 1 05/24/10 19:04 98-82-80.50
Methylene Chloride ND ug/L 1 05/24/10 19:04 75-09-22.0
Methyl-tert-butyl ether ND ug/L 1 05/24/10 19:04 1634-04-40.50
Naphthalene ND ug/L 1 05/24/10 19:04 91-20-32.0
n-Propylbenzene ND ug/L 1 05/24/10 19:04 103-65-10.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 7 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Sample:BABER SW Lab ID:9269887001 Collected:05/19/10 09:25 Received:05/20/10 11:58 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Styrene ND ug/L 1 05/24/10 19:04 100-42-50.50
1,1,1,2-Tetrachloroethane ND ug/L 1 05/24/10 19:04 630-20-60.50
1,1,2,2-Tetrachloroethane ND ug/L 1 05/24/10 19:04 79-34-50.50
Tetrachloroethene ND ug/L 1 05/24/10 19:04 127-18-40.50
Toluene ND ug/L 1 05/24/10 19:04 108-88-30.50
1,2,3-Trichlorobenzene ND ug/L 1 05/24/10 19:04 87-61-62.0
1,2,4-Trichlorobenzene ND ug/L 1 05/24/10 19:04 120-82-12.0
1,1,1-Trichloroethane ND ug/L 1 05/24/10 19:04 71-55-60.50
1,1,2-Trichloroethane ND ug/L 1 05/24/10 19:04 79-00-50.50
Trichloroethene ND ug/L 1 05/24/10 19:04 79-01-60.50
Trichlorofluoromethane ND ug/L 1 05/24/10 19:04 75-69-41.0
1,2,3-Trichloropropane ND ug/L 1 05/24/10 19:04 96-18-40.50
1,2,4-Trimethylbenzene ND ug/L 1 05/24/10 19:04 95-63-60.50
1,3,5-Trimethylbenzene ND ug/L 1 05/24/10 19:04 108-67-80.50
Vinyl chloride ND ug/L 1 05/24/10 19:04 75-01-41.0
m&p-Xylene ND ug/L 1 05/24/10 19:04 179601-23-11.0
o-Xylene ND ug/L 1 05/24/10 19:04 95-47-60.50
1,2-Dichloroethane-d4 (S)102 %1 05/24/10 19:04 17060-07-070-130
Dibromofluoromethane (S)102 %1 05/24/10 19:04 1868-53-770-130
4-Bromofluorobenzene (S)94 %1 05/24/10 19:04 460-00-470-130
Toluene-d8 (S)102 %1 05/24/10 19:04 2037-26-570-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 8 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/6376
SM 3030C
EPA 6010
6010 MET 3030C
Associated Lab Samples:9269887001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:445603
Associated Lab Samples:9269887001
Matrix:Water
Analyzed
Lead ug/L ND 5.0 05/26/10 23:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
445604LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 509500 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
445605MATRIX SPIKE SAMPLE:
MSSpike
Result
9269887001
Lead ug/L 506500 101 75-125ND
Parameter Units
Dup
Result QualifiersRPDResult
9269879006
445606SAMPLE DUPLICATE:
Lead ug/L NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 9 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/11013
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:9269887001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:446665
Associated Lab Samples:9269887001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 05/24/10 16:28
1,1,1-Trichloroethane ug/L ND 0.50 05/24/10 16:28
1,1,2,2-Tetrachloroethane ug/L ND 0.50 05/24/10 16:28
1,1,2-Trichloroethane ug/L ND 0.50 05/24/10 16:28
1,1-Dichloroethane ug/L ND 0.50 05/24/10 16:28
1,1-Dichloroethene ug/L ND 0.50 05/24/10 16:28
1,1-Dichloropropene ug/L ND 0.50 05/24/10 16:28
1,2,3-Trichlorobenzene ug/L ND 2.0 05/24/10 16:28
1,2,3-Trichloropropane ug/L ND 0.50 05/24/10 16:28
1,2,4-Trichlorobenzene ug/L ND 2.0 05/24/10 16:28
1,2,4-Trimethylbenzene ug/L ND 0.50 05/24/10 16:28
1,2-Dibromo-3-chloropropane ug/L ND 1.0 05/24/10 16:28
1,2-Dibromoethane (EDB)ug/L ND 0.50 05/24/10 16:28
1,2-Dichlorobenzene ug/L ND 0.50 05/24/10 16:28
1,2-Dichloroethane ug/L ND 0.50 05/24/10 16:28
1,2-Dichloropropane ug/L ND 0.50 05/24/10 16:28
1,3,5-Trimethylbenzene ug/L ND 0.50 05/24/10 16:28
1,3-Dichlorobenzene ug/L ND 0.50 05/24/10 16:28
1,3-Dichloropropane ug/L ND 0.50 05/24/10 16:28
1,4-Dichlorobenzene ug/L ND 0.50 05/24/10 16:28
2,2-Dichloropropane ug/L ND 0.50 05/24/10 16:28
2-Chlorotoluene ug/L ND 0.50 05/24/10 16:28
4-Chlorotoluene ug/L ND 0.50 05/24/10 16:28
Benzene ug/L ND 0.50 05/24/10 16:28
Bromobenzene ug/L ND 0.50 05/24/10 16:28
Bromochloromethane ug/L ND 0.50 05/24/10 16:28
Bromodichloromethane ug/L ND 0.50 05/24/10 16:28
Bromoform ug/L ND 0.50 05/24/10 16:28
Bromomethane ug/L ND 5.0 05/24/10 16:28
Carbon tetrachloride ug/L ND 0.50 05/24/10 16:28
Chlorobenzene ug/L ND 0.50 05/24/10 16:28
Chloroethane ug/L ND 1.0 05/24/10 16:28
Chloroform ug/L ND 0.50 05/24/10 16:28
Chloromethane ug/L ND 1.0 05/24/10 16:28
cis-1,2-Dichloroethene ug/L ND 0.50 05/24/10 16:28
cis-1,3-Dichloropropene ug/L ND 0.50 05/24/10 16:28
Dibromochloromethane ug/L ND 0.50 05/24/10 16:28
Dibromomethane ug/L ND 0.50 05/24/10 16:28
Dichlorodifluoromethane ug/L ND 0.50 05/24/10 16:28
Diisopropyl ether ug/L ND 0.50 05/24/10 16:28
Ethanol ug/L ND 200 05/24/10 16:28
Ethylbenzene ug/L ND 0.50 05/24/10 16:28
Hexachloro-1,3-butadiene ug/L ND 2.0 05/24/10 16:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 10 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:446665
Associated Lab Samples:9269887001
Matrix:Water
Analyzed
Isopropylbenzene (Cumene)ug/L ND 0.50 05/24/10 16:28
m&p-Xylene ug/L ND 1.0 05/24/10 16:28
Methyl-tert-butyl ether ug/L ND 0.50 05/24/10 16:28
Methylene Chloride ug/L ND 2.0 05/24/10 16:28
n-Butylbenzene ug/L ND 0.50 05/24/10 16:28
n-Propylbenzene ug/L ND 0.50 05/24/10 16:28
Naphthalene ug/L ND 2.0 05/24/10 16:28
o-Xylene ug/L ND 0.50 05/24/10 16:28
sec-Butylbenzene ug/L ND 0.50 05/24/10 16:28
Styrene ug/L ND 0.50 05/24/10 16:28
tert-Butylbenzene ug/L ND 0.50 05/24/10 16:28
Tetrachloroethene ug/L ND 0.50 05/24/10 16:28
Toluene ug/L ND 0.50 05/24/10 16:28
trans-1,2-Dichloroethene ug/L ND 0.50 05/24/10 16:28
trans-1,3-Dichloropropene ug/L ND 0.50 05/24/10 16:28
Trichloroethene ug/L ND 0.50 05/24/10 16:28
Trichlorofluoromethane ug/L ND 1.0 05/24/10 16:28
Vinyl chloride ug/L ND 1.0 05/24/10 16:28
1,2-Dichloroethane-d4 (S)%96 70-130 05/24/10 16:28
4-Bromofluorobenzene (S)%98 70-130 05/24/10 16:28
Dibromofluoromethane (S)%99 70-130 05/24/10 16:28
Toluene-d8 (S)%99 70-130 05/24/10 16:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
446666LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.750 97 60-140
1,1,1-Trichloroethane ug/L 52.850 106 60-140
1,1,2,2-Tetrachloroethane ug/L 45.550 91 60-140
1,1,2-Trichloroethane ug/L 48.850 98 60-140
1,1-Dichloroethane ug/L 54.550 109 60-140
1,1-Dichloroethene ug/L 55.150 110 60-140
1,1-Dichloropropene ug/L 49.950 100 60-140
1,2,3-Trichlorobenzene ug/L 49.450 99 60-140
1,2,3-Trichloropropane ug/L 47.050 94 60-140
1,2,4-Trichlorobenzene ug/L 50.750 101 60-140
1,2,4-Trimethylbenzene ug/L 50.850 102 60-140
1,2-Dibromo-3-chloropropane ug/L 46.850 94 60-140
1,2-Dibromoethane (EDB)ug/L 47.050 94 60-140
1,2-Dichlorobenzene ug/L 50.050 100 60-140
1,2-Dichloroethane ug/L 48.050 96 60-140
1,2-Dichloropropane ug/L 50.550 101 60-140
1,3,5-Trimethylbenzene ug/L 51.050 102 60-140
1,3-Dichlorobenzene ug/L 49.950 100 60-140
1,3-Dichloropropane ug/L 48.650 97 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 11 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
446666LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dichlorobenzene ug/L 49.450 99 60-140
2,2-Dichloropropane ug/L 54.350 109 60-140
2-Chlorotoluene ug/L 50.150 100 60-140
4-Chlorotoluene ug/L 51.850 104 60-140
Benzene ug/L 50.650 101 60-140
Bromobenzene ug/L 50.950 102 60-140
Bromochloromethane ug/L 50.350 101 60-140
Bromodichloromethane ug/L 46.550 93 60-140
Bromoform ug/L 48.350 97 60-140
Bromomethane ug/L 46.650 93 60-140
Carbon tetrachloride ug/L 52.650 105 60-140
Chlorobenzene ug/L 51.250 102 60-140
Chloroethane ug/L 45.350 91 60-140
Chloroform ug/L 47.850 96 60-140
Chloromethane ug/L 48.450 97 60-140
cis-1,2-Dichloroethene ug/L 53.750 107 60-140
cis-1,3-Dichloropropene ug/L 49.850 100 60-140
Dibromochloromethane ug/L 46.750 93 60-140
Dibromomethane ug/L 50.050 100 60-140
Dichlorodifluoromethane ug/L 48.550 97 60-140
Diisopropyl ether ug/L 46.750 93 60-140
Ethanol ug/L 17802000 89 60-140
Ethylbenzene ug/L 49.350 99 60-140
Hexachloro-1,3-butadiene ug/L 49.950 100 60-140
Isopropylbenzene (Cumene)ug/L 50.250 100 60-140
m&p-Xylene ug/L 100100 100 60-140
Methyl-tert-butyl ether ug/L 45.350 91 60-140
Methylene Chloride ug/L 52.050 104 60-140
n-Butylbenzene ug/L 49.950 100 60-140
n-Propylbenzene ug/L 52.050 104 60-140
Naphthalene ug/L 51.150 102 60-140
o-Xylene ug/L 49.050 98 60-140
sec-Butylbenzene ug/L 50.950 102 60-140
Styrene ug/L 51.550 103 60-140
tert-Butylbenzene ug/L 50.850 102 60-140
Tetrachloroethene ug/L 49.550 99 60-140
Toluene ug/L 48.650 97 60-140
trans-1,2-Dichloroethene ug/L 52.450 105 60-140
trans-1,3-Dichloropropene ug/L 49.750 99 60-140
Trichloroethene ug/L 50.250 100 60-140
Trichlorofluoromethane ug/L 46.850 94 60-140
Vinyl chloride ug/L 46.250 92 60-140
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%98 70-130
Dibromofluoromethane (S)%100 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 12 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
446894MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9269887001
446895
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 105 60-140108 320ND21.0 21.6
1,1,1-Trichloroethane ug/L M02014260-140142 020ND28.4 28.4
1,1,2,2-Tetrachloroethane ug/L 20 111 60-140120 820ND22.1 23.9
1,1,2-Trichloroethane ug/L 20 119 60-140129 720ND23.9 25.7
1,1-Dichloroethane ug/L M02016860-140165 220ND33.7 33.0
1,1-Dichloroethene ug/L M02016560-140163 220ND33.1 32.6
1,1-Dichloropropene ug/L M02014960-140147 120ND29.8 29.4
1,2,3-Trichlorobenzene ug/L 20 100 60-140111 1020ND20.1 22.2
1,2,3-Trichloropropane ug/L 20 100 60-140105 520ND20.0 21.1
1,2,4-Trichlorobenzene ug/L 20 105 60-140115 920ND20.9 23.0
1,2,4-Trimethylbenzene ug/L 20 130 60-140137 520ND26.1 27.5
1,2-Dibromo-3-chloropropane ug/L 20 107 60-140123 1420ND21.4 24.7
1,2-Dibromoethane (EDB)ug/L 20 106 60-140110 420ND21.2 22.0
1,2-Dichlorobenzene ug/L 20 116 60-140124 720ND23.2 24.8
1,2-Dichloroethane ug/L 20 129 60-140133 320ND25.8 26.6
1,2-Dichloropropane ug/L M02014760-140150 220ND29.3 30.0
1,3,5-Trimethylbenzene ug/L 20 132 60-140137 420ND26.4 27.5
1,3-Dichlorobenzene ug/L 20 117 60-140124 620ND23.4 24.8
1,3-Dichloropropane ug/L 20 121 60-140127 520ND24.2 25.4
1,4-Dichlorobenzene ug/L 20 117 60-140124 620ND23.3 24.9
2,2-Dichloropropane ug/L M02015660-140155 020ND31.1 31.0
2-Chlorotoluene ug/L 20 133 60-140138 420ND26.6 27.7
4-Chlorotoluene ug/L M02013760-140143 420ND27.4 28.5
Benzene ug/L M02014560-140146 120ND28.9 29.2
Bromobenzene ug/L M02013660-140144 520ND27.3 28.7
Bromochloromethane ug/L 20 131 60-140135 220ND26.3 26.9
Bromodichloromethane ug/L 20 117 60-140120 220ND23.5 23.9
Bromoform ug/L 20 90 60-14095 520ND18.0 19.0
Bromomethane ug/L 20 122 60-140131 820ND24.4 26.3
Carbon tetrachloride ug/L 20 128 60-140129 020ND25.7 25.7
Chlorobenzene ug/L 20 119 60-140122 220ND23.9 24.4
Chloroethane ug/L M02016160-140154 420ND32.6 31.2
Chloroform ug/L 20 135 60-140135 020ND26.9 27.0
Chloromethane ug/L 20 136 60-140132 320ND27.2 26.5
cis-1,2-Dichloroethene ug/L M02016060-140162 120ND32.1 32.4
cis-1,3-Dichloropropene ug/L 20 133 60-140135 220ND26.6 27.1
Dibromochloromethane ug/L 20 96 60-140100 420ND19.1 20.0
Dibromomethane ug/L 20 106 60-140112 620ND21.1 22.4
Dichlorodifluoromethane ug/L 20 138 60-140134 320ND27.7 26.8
Diisopropyl ether ug/L M02014660-140149 220ND29.3 29.7
Ethanol ug/L M080014360-140171 18800ND11401370
Ethylbenzene ug/L 20 123 60-140125 220ND24.5 24.9
Hexachloro-1,3-butadiene ug/L 20 100 60-140104 420ND19.9 20.8
Isopropylbenzene (Cumene)ug/L 20 121 60-140123 120ND24.3 24.6
m&p-Xylene ug/L 40 125 60-140126 140ND50.1 50.4
Methyl-tert-butyl ether ug/L 20 126 60-140132 520ND25.1 26.4
Methylene Chloride ug/L M02016260-140163 020ND32.5 32.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 13 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
446894MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9269887001
446895
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L M02013760-140142 420ND27.3 28.5
n-Propylbenzene ug/L M02014260-140147 320ND28.4 29.4
Naphthalene ug/L 20 112 60-140126 1220ND22.4 25.1
o-Xylene ug/L 20 123 60-140122 120ND24.5 24.4
sec-Butylbenzene ug/L 20 137 60-140139 220ND27.5 28.0
Styrene ug/L 20 122 60-140122 020ND24.5 24.5
tert-Butylbenzene ug/L 20 127 60-140134 520ND25.4 26.7
Tetrachloroethene ug/L 20 107 60-140108 120ND21.3 21.6
Toluene ug/L 20 130 60-140131 120ND25.9 26.3
trans-1,2-Dichloroethene ug/L M02016160-140160 120ND32.3 32.0
trans-1,3-Dichloropropene ug/L 20 125 60-140130 420ND24.9 26.1
Trichloroethene ug/L 20 119 60-140121 220ND23.8 24.3
Trichlorofluoromethane ug/L 20 129 60-140126 220ND25.8 25.3
Vinyl chloride ug/L M02015560-140153 120ND31.1 30.7
1,2-Dichloroethane-d4 (S)%109 70-130106
4-Bromofluorobenzene (S)%84 70-13084
Dibromofluoromethane (S)%106 70-130107
Toluene-d8 (S)%104 70-130104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 14 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 15 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9269887
CARAWAY GROCERY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9269887001 MPRP/6376 ICP/5886BABER SW SM 3030C EPA 6010
9269887001 MSV/11013BABER SW SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 05/28/2010 03:34 PM Page 16 of 16
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]