WS-6406_24174_CA_IAR_20100408

TABLE OF CONTENTS

I. GENERAL INFORMATION............................................................................................................1
A. OWNERSHIP OF UNDERGROUND STORAGE TANK(S) (USTS)............................................................. 1
B. FACILITY INFORMATION:.................................................................................................................... 1
C. CONTACTS:.......................................................................................................................................... 1
D. INTRODUCTION AND UST INFORMATION:.......................................................................................... 1
E. SITE HISTORY:..................................................................................................................................... 2
F. SITE CHARACTERISTICS:..................................................................................................................... 4
II. CLOSURE PROCEDURES............................................................................................................... 4
A. PREPARATIONS FOR CLOSURE:........................................................................................................... 4
B. EXCAVATION:...................................................................................................................................... 5
III. SITE INVESTIGATION................................................................................................................... 6
A. SOIL SAMPLING PROCEDURES, FIELD SCREENING, AND OBSERVATIONS:........................................ 6
B. GROUNDWATER /SURFACE WATER SAMPLING AND BEDROCK:........................................................ 8
C. QUALITY CONTROL MEASURES:........................................................................................................ 8
D. INVESTIGATION RESULTS:.................................................................................................................. 9
IV. CONCLUSIONS AND RECOMMENDATIONS........................................................................... 9
V. SIGNATURE OF PROFESSIONAL ENGINEER OR LICENSED GEOLOGIST................... 10

FIGURES
1) Topographic Map
2) Site Detail with Tank Closure Samples
3) Post-Excavation Samples

TABLES
1) UST Details (pg. 2)
2) Summary of Field Screening and TPH Laboratory Results
3) Lab Results of Post Excavation Samples for Tank #1 & #2 (2,000-gal. gasoline
USTs)
4) Lab Results of Post-Excavation Samples for Tank #3 (275-gal. gasoline UST)
5) Lab Results of Post-Excavation Samples for Tank #4 (625-gal. gasoline UST)
6) Lab Results of Post-Excavation Samples for Tank #5 (270-gal. kerosene UST)

APPENDICES

A. Non-Hazardous Liquid Manifest
B. Site Investigation Report for Permanent Closure – Form UST-2
C. Certificate of Disposal, Non-Hazardous Manifests & Weight Tickets for Soil
D. Certificate of Tank Disposal
E. Site Photographs
F. Standard Field Procedures
G. Laboratory Reports

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 1
Pyramid Project #2009-311 04/06/10

I. General Information
A. Ownership of Underground Storage Tank(s) (USTs)

USTs Owner: Property Owner:
Don & Judy Johnson Don & Judy Johnson
3337 Old Lexington Rd. 3337 Old Lexington Rd.
Asheboro, NC 27205 Asheboro, NC 27205

B. Facility Information:

1. Facility Name: Former Caraway Grocery (aka Dougan’s Store)
2. Facility ID #: 0-018181
3. NCDENR Groundwater Incident #: 24174
4. Facility Address: 3419 Old Lexington Rd., Asheboro, NC (see Figure 1)

C. Contacts:

1. Primary Contact Person: 2. Closure Contractor:
Mr. Don Johnson. EVO Corp.
3337 Old Lexington Rd. 1703 Vargrave St.
Asheboro, NC 27205 Winston-Salem, NC 27107
336-625-1669 336-725-5844

3. Primary Consultant: 4. Laboratory:
Pyramid Environmental and Pace Analytical Services
Engineering, P.C. (Pyramid) 9800 Kincey Ave., Suite 100
P.O. Box 16265 Huntersville, NC 28078
Greensboro, NC 27416-0265 NC Certification #12
336-335-3174 704-875-9092

D. Introduction and UST Information:

As authorized by the NCDENR Federal Trust Fund (FTF) Branch, Pyramid Environmental and
Engineering, P.C. (Pyramid) supervised the closure of five (5) underground storage tanks with
the associated product lines the former Caraway Grocery in Asheboro, North Carolina. The
location of the site is shown on Figure 1. The UST system included two 2,000-gallon gasoline,
one 275-gallon gasoline, one 625-gallon gasoline and one 270-gallon kerosene tanks. The two
2,000-gallon gasoline tanks were the only tanks that were registered with the DENR UST
Section. The three additional unregistered USTs were installed in the 1920s and taken out of
service before 1985. In addition to the five USTs, Pyramid authorized the removal and proper
disposal of one 500-gallon kerosene AST that was located directly above the 270-gallon
kerosene UST. Approximately 10-15 percent of this AST was below ground. The former
locations of the tanks are shown on Figure 2. The facility previously operated as a retail
petroleum fueling station and convenience store. At the time of the tank removal activities, the

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 2
Pyramid Project #2009-311 04/06/10

site was inactive. The work was performed from February 24 – March 1, 2010. The details of
the tanks removed are included in Table 1.

Table 1: UST Details

Tank
No.
Installation
Dates
Size in
Gallons
Tank
Dimensions
Last
Contents
Previous
Contents
UST Release
Detected
Date
Permanently
Closed
1 4/30/85 2,000 64” dia. x
12’ long
Gasoline Gasoline Yes 2/25/10
2 4/30/85 2,000 64” dia. x
12’ long
Gasoline Gasoline Yes 2/25/10
3 Unknown
(1920s?)
275 38” dia. x
4.75’ long
Gasoline Gasoline Yes 2/25/10
4 Unknown
(1920s?)
625 41” dia. x
7.83’ long
Gasoline Gasoline Yes 2/25/10
5 Unknown
(1920s?)
270 42” dia. x
3.75’ long
Kerosene Kerosene Yes 2/25/10

This 20-Day/Initial Abatement Action Report (IAAR) was prepared to satisfy the release
response requirements of 15A NCAC 2N .0702, .0703 and .07050 and 15A NCAC 2L
.0404(1).

E. Site History:

In 2002, Pyramid was contracted to perform a Phase II Assessment at the subject property.
Pyramid reviewed available records at the Randolph County tax department and interviewed
Mrs. Dorothy Dougan Fagge, co-owner of the property, Mr. Phillip Poole, owner of Econo Oil
Company, and Larry Furr, owner of Mitchell Oil Company. Based on the information obtained,
the existing building was constructed in 1910 and was used as a country store. The owners
(Mrs. Dorothy Dougan Fagge and her sister, Mrs. Frances Dougan Steere) at that time inherited
the property from their parents, the Dougan’s.

According to Mrs. Fagge, her uncle, Wade Dougan, began operating the store between the
1920s and the 1940s and installed two gasoline USTs, and possibly a kerosene UST. The two
gasoline USTs were found with the Geoprobe and are located on the east and west sides of the
pump island. Mrs. Fagge remembers an old, glass top kerosene pump near the current kerosene
AST that was later installed; however, she did not remember a kerosene AST at the site prior to
the current AST. An old vent pipe was observed on the side of the building near the former
kerosene pump. The former kerosene pump was removed shortly after the death of Mr. Wade
Dougan. Mr. Wade Dougan, currently deceased, operated the store until 1973 when he passed
away. The petroleum sold by Mr. Dougan was supplied by Herlocker Oil Company.

In the 1980s, Mrs. Fagge agreed to rent the store to Mr. Carl Robbins. Mr. Robbins contracted
Econo Oil Company to install two additional 2,000-gallon gasoline USTs and one 550-gallon
kerosene aboveground storage tank (AST) and a kerosene pump. The store was called Caraway

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 3
Pyramid Project #2009-311 04/06/10

Grocery and operated under UST Facility ID number of 0-018181. Econo Oil was the financial
owner/operator of the USTs. In January 1993, Econo Oil Company sold the two 2,000-gallon
gasoline USTs to Mr. Randall Williams, who was listed in the North Carolina Department of
Environment and Natural Resources (DENR) records as the financial owner/operator of the
USTs. Mr. Williams and Mr. Robbins continued to operate the store as a service station. Mr.
Robbins was supplied two shipments of petroleum by Mitchell Oil Company in 1993, after
which the store no longer sold petroleum. After Mr. Robbins ownership ended, the store was
used for video rental and did not operate as a service station. The two 2,000-gallon gasoline
tanks installed by Econo Oil Company were observed to be still in the ground. According to
Mrs. Fagge, Mr. Robbins also installed a car ramp to the west of the building and provided oil
changes. The 500-gallon kerosene AST is located east of the building with the kerosene pump
underneath the canopy. According to Mrs. Fagge, Mr. Robbins utilized the pump island
underneath the canopy for his gasoline pumps. The former gasoline pumps were removed in the
mid 1990s when the site was a video rental store.

In 2002, Mrs. Fagge lived approximately 350 feet southeast of the store in the house formerly
owned by her grandparents. According to Mrs. Fagge, the water supply well at the house
became contaminated in the 1950s or 1960s and was no longer potable. The water was tested
at that time and determined to contain gasoline. During Pyramid’s initial site visit, a water level
indicator was lowered into the supply well behind Mrs. Fagge's house and did not encounter
water prior to the well bottom at 36 feet below land surface (BLS). There are no known
underground sources of petroleum near the house other than the store. The house was later
connected to the water supply well on the property directly southeast of her house. Mrs. Fagge
previously owned the adjacent property, which she inherited from her parents. The store does
not have a water supply well. Mr. Wade Dougan had a water tank that collected rain runoff
from the roof and supplied water to the spigot located beside the kerosene AST.

On March 12, 2002, Pyramid performed eleven borings (GP1 through GP11) at the subject site
to assess soil conditions and collect soil samples for laboratory analyses. The laboratory results
for the soil samples collected from GP1 and GP3 indicated TPH concentrations for gasoline
and diesel were below their respective detection limits of <1.0 mg/kg for gasoline and 10
mg/kg for diesel. The results for the soil sample collected from GP4 indicated a TPH gasoline
concentration of 190 mg/kg and a TPH diesel concentration of 1,800 mg/kg. The high diesel
TPH is due to a kerosene release. The results for the soil sample collected from GP7 indicated
a TPH gasoline concentration of 1,100 mg/kg and a TPH diesel concentration of 580 mg/kg.
The results for the soil samples collected from GP8 and GP11 indicated TPH gasoline
concentrations ranging from 29 mg/kg to 330 mg/kg, and TPH diesel concentrations ranging
from 170 mg/kg to 280 mg/kg.

In October 2008, Terraine installed two soil borings at the site that were converted to
groundwater monitoring wells (MW-1 & MW-2). The laboratory results of groundwater
samples collected from the wells in 2008 indicated that some of the targeted petroleum
compounds (BTEX plus naphthalene and n-propylbenzene) were detected at concentrations
that exceeded their respective NCAC 2L groundwater standards.

The manhole covers for monitoring wells MW-1 and MW-2 were damaged during the UST and
contaminated soil removal activities performed in February 2010. Pyramid believes that these

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 4
Pyramid Project #2009-311 04/06/10

wells can be repaired and re-sampled to assess the current groundwater contaminant
concentrations.

F. Site Characteristics:

1. Facility active or inactive: Inactive

As stated above, at the time of the tank removal the site was inactive. The current property
owner (Don Johnson) was asked if the building could be demolished prior to removing the
USTs to provide better access for the removal of contaminated soil; however, he did not allow
the demolition because of the historical significance of the structure. Mr. Johnson is currently
in the process of trying to add the site to list of historic buildings in Randolph County.

2. Surrounding property use:

The surrounding area includes a mixture of residential and undeveloped land use.

3. Site geology/hydrogeology:

Pyramid’s review of the 1985 Geologic Map of North Carolina yielded information concerning
local geology and hydrogeology. Based on this review, the site is located in the Carolina Slate
Belt of North Carolina. The surface geology consists of regional soils created by the weathering
of underlying bedrock. This belt consists of heated and deformed volcanic and sedimentary
rocks. It was the site of a series of oceanic volcanic islands about 550-650 million years ago.
This belt is known for its numerous abandoned gold mines and prospects. According to the
1985 Geologic Map of North Carolina, the underlying bedrock in the area is described as meta-
mudstone and meta-argillite, map symbol CZmd.

In general, both surface and groundwater flow directions are controlled by topographic
contours of land forms in the Piedmont with flow occurring perpendicular to the contours from
high to low elevations. The surface water from the site flows to southeast and is directed by
surface topography to Back Creek which is located approximately 2,200 feet from the subject
property.

II. Closure Procedures
A. Preparations for Closure:

In preparation for the removal and closure of the USTs, the following work was performed:

1) The UST removal contractor (EVO) contacted NC-One-Call to at least 48 hours prior to
beginning the work to have all subsurface utilities marked at the site.

2) On February 24, 2010 the residual fuel and/or water in each tank were removed prior to
removing the tanks by HMHTTC in High Point, NC. The 2,000-gallon gasoline USTs
contained only a few inches of product each. Tank #3 and #4 contained approximately

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 5
Pyramid Project #2009-311 04/06/10

10 inches of water each and tank #5 contained 31 inches of water. A total of 357 gallons
of residual fuel and water was removed from the tanks and transported to HOH
Corporation in Winston-Salem, NC for treatment and disposal. A copy of the non-
hazardous liquid manifest is included in Appendix A.

3) EVO used a dry ice to purge the tanks of flammable vapors. Mr. Wendall Whatley, a
Fire Inspector representing the Randolph County Inspections Department was on-site to
verify that the Lower Explosive Limit (LEL) readings were <10% before authorizing
removal of the tanks. Once residual liquids and vapors were removed, the LEL was
checked and each UST had a reading below 10%.

B. Excavation:

1. On February 25-26 and March 1, 2010, Pyramid supervised the removal of the
USTs listed in Table 1 (pg. 2), the excavation of petroleum contaminated soil,
backfilling and compaction of the excavation and surface restoration at the subject
property. The locations of the USTs are shown on Figure 2.

2. Contamination was detected in the backfill in and around the UST basins. During
the excavation procedures, Pyramid screened soil samples using an Organic Vapor
Analyzer (OVA) to determine the approximate extent of soil contamination. The
field screening results indicated high levels of petroleum contamination at all five
tank locations (see Table 2).

3. The completed Site Investigation Report for UST Closure Form (UST-2) is included
as Appendix B. The UST-2 Form describes site conditions and activities completed
during the UST closure.

4. Petroleum contaminated soils removed from the site were transported to EVO
Corporation in Winston-Salem, NC for treatment and disposal. Based on certified
weight tickets, 248.48 tons of petroleum-contaminated soil was removed from the
site. Copies of the Non-Hazardous Material Manifests with certified weight tickets
are included in Appendix C.

5. After removal, the USTs were inspected for any visible holes. The tanks showed
some evidence of corrosion, but no visible holes were detected, with the exception
of tank #9 which was in poor condition. After removal and inspection, the USTs and
500-gallon AST were loaded and transported by EVO to OmniSource Southeast in
Winston-Salem, North Carolina for proper disposal. OmniSource cleans and cuts up
the tanks for metal recycling. A copy of the Tank Disposal Manifest is included in
Appendix D.

6. Photographs of the UST removals and contaminated soil excavation are included in
Appendix E.

7. The excavation was backfilled with soil from a local supplier and compacted using a
1 ton vibratory mechanical roller and the track excavator.

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 6
Pyramid Project #2009-311 04/06/10

8. The surface replacement included 6-8 inches of ABC stone over the entire
excavation which was also compacted with the vibratory roller. The site restoration
also included two areas that were seeded and cover with straw.

III. Site Investigation

A. Soil Sampling Procedures, Field Screening, and Observations:

As part of the limited site assessment required under 40 CFR 280.72 and 15A NCAC 2N .0803,
Pyramid collected soil samples from directly under the USTs, dispensers, product piping, and
at the limits of the contaminated soil excavation. The initial UST closure soil samples are
shown on Figure 2. The post-excavation soil sample locations are shown on Figure 3.

To prevent cross-contamination from the sampling procedures, clean disposable nitrile gloves
were worn by the sampling technician during these activities and were changed between
samples. All soil samples collected from the UST basin, product lines, and pump islands were
collected using the track excavator and obtained from the center of the bucket. The standard
field procedures used by Pyramid are included in Appendix F. The soil samples were packed
in a cooler on ice and maintained at 4°C during shipment to Pace Analytical Services in
Huntersville, NC.

Initial UST Closure Samples

As required, soil samples were collected directly beneath the USTs after removal to confirm if
a petroleum release had occurred. The initial UST soil samples were analyzed by the laboratory
for TPH using EPA Method 5030/8015, for gasoline range organics (GRO). The soil sample
collected underneath the kerosene UST was also analyzed using EPA Method and 3550/8015
for diesel range organics (DRO). Due to an equipment malfunction at the Pace laboratory, the
GRO analyses were subcontracted to ENCO in Cary, NC to ensure that the samples would be
analyzed within the required 14-day hold time. The field screening and TPH results of the
initial UST closure soil samples are presented in Table 2. As shown in Table 2, all of the initial
UST closure samples contained TPH concentrations that exceed the initial action level of 10
mg/kg. Copies of the laboratory reports for the initial UST closure soil samples are included in
Appendix G.

Product Line / Pump Island Samples

The product lines for the two 2,000-gallon gasoline USTs cut across the site to the front of the
pump island. The 2,000-gallon tank product lines and the soil underneath them was removed
as part of the Tank #1, #2 and #3 excavations, with exception of one area where soil was not
removed. No soil was removed and no samples were collected from the narrow area between
the two excavations performed for Tank #1, #2 & #3.

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 7
Pyramid Project #2009-311 04/06/10

Only a small amount of soil was excavated in front of the pump island due to the low roof of
the canopy, an existing underground communication utility and shallow rock. Two soil samples
were collected (PL1-3 & PL2-3), one in front of each of the former dispenser locations. The
soil at PL2 did not exhibit any petroleum odor and the sample was collected at 3 feet below
ground surface and analyzed for GRO. As indicated on page 2 of Table 2, the GRO for PL2-3
was 2.9 mg/kg. The soil at PL1 contained noticeable odor and was loaded for transportation
and off-site disposal. The sample collected at 3 feet below ground surface at PL1 exhibited a
slight petroleum odor; therefore, the sample was analyzed using the risk-based methods (VPH
& 8260). The laboratory results of the risk-based analyses for PL1-3 are included in Table 3.
As indicated in Table 3, none of the targeted compounds were detected at concentrations that
exceed the soil to groundwater or residential MSCCs.

Contaminated Soil Excavation and Post-Excavation Sampling

Contaminated soil excavation was performed at each tank location. Soils were screened using
an OVA to guide the direction of the excavation. Existing overhead power lines, one power
pole, an underground communication utility, the existing building, and shallow rock restricted
the extent of the excavations. The existing structure and utilities are shown on Figures 2 and 3.
The final dimensions of the excavation for the two 2,000-gallon gasoline USTs measured
approximately 15 feet wide, 17 feet long and 12-14 feet deep. The depth of the excavation was
limited by the presence of shallow rock. The final dimensions for the Tank #3 excavation
measured 8-10 feet wide, 13 feet long and 13-14 feet deep. This excavation was limited by the
existing canopy an underground utility and shallow rock. The final dimensions for the Tank #4
excavation measured 8 feet wide, 13 feet long and 12-13 feet deep. The final dimensions for the
Tank #5 excavation measured 6 feet wide, 13 feet long and 5-7 feet deep. This excavation was
limited by the existing building, an existing power pole, and shallow rock. The extents of each
excavation are shown on Figure 3.

As directed by the DENR, five (5) post-excavation soil samples were collected from each tank
excavation for a total of 20 soil samples for risk-based analysis. The locations of the post
excavation samples are shown on Figure 3. The post-excavation soil samples collected from
the three gasoline tank excavations were analyzed for volatile using EPA Method 8260 and for
VPH using the MADEP method.

The post-excavation soil samples collected from the kerosene tank excavation were analyzed
for volatile and semi-volatile organic compounds using EPA Methods 8260 and 8270 and for
VPH/EPH using the MADEP methods. The laboratory results of the post-excavation soil
samples are presented in Table 3, 4, 5 and 6. Table 3 includes the results of the post-
excavation soil samples collected from the two 2,000-gallon gasoline tank (Tank #1 & #2)
excavation. Table 4 includes the results of the post-excavation soil samples collected from the
Tank #3 excavation. Table 5 includes the results of the post-excavation soil samples collected
from the Tank #4 excavation and Table 6 includes the results of the post-excavation soil
samples collected from the Tank #5 excavation.. A copy of the laboratory report for the post-
excavation soil samples is included in Appendix G.

The laboratory results of post excavation soil samples collected from each excavation indicate
that some of the targeted compounds were detected at concentrations that exceed the soil to

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 8
Pyramid Project #2009-311 04/06/10

groundwater MSCCs. The following samples contained concentrations of the targeted
compounds that exceed the soil to groundwater MSCCs (2KTE-3, 2KTE-5, TE3-3, TE3-4,
T3E-5, T4E-1, T5E-3 and T5E-5). As indicated on Figure 3, seven of the eight samples listed
above were collected from locations where excavation was limited by existing structures,
utilities, or shallow rock.

Only two of the 20 post excavation soil samples (T4E-1 and T5E-3) contained concentrations
that exceed the residential MSCCs. Sample T4E-1 was collected from the Tank #4 excavation
on the sidewall nearest the existing canopy at a depth of 11 feet below land surface. T4E-1
contained concentrations of C5-C8 and C9-C12 aliphatics that exceed the residential MSCCs.
Sample T5E-3 was collected from the Tank #5 excavation on the sidewall nearest the existing
building. T5E-3 contained concentrations of C9-22 aromatics that exceed the residential
MSCCs. In both cases, the soil samples were collected from locations where excavation was
limited by the existing structure. The excavations at Tank #4 and #5 had been extended as close
as possible to the building before the samples were collected.

B. Groundwater /Surface Water Sampling and Bedrock:

No Groundwater or surface water samples were collected as part of the 20-Day/IAA Report. As
previously indicated, bedrock was encountered in each excavation and it limited the depth that
soils could be removed. The excavations at Tanks #1, #2, #3 and #4 terminated at 12-14 feet
below land surface and the excavation at Tank #5 terminated at 7 feet due to the presence of
shallow rock. The groundwater assessment work performed in 2008 indicated that the depth to
groundwater in MW-1 and MW-2 was approximately 29 feet from land surface. During the
tank removal and soil excavation operations, both groundwater monitoring wells (MW-1 &
MW-2) were damaged. Pyramid believes that these wells can be located and repaired for
future sampling and analysis.

C. Quality Control Measures:

New, sterile nitrile gloves were worn while obtaining the samples. Soil samples were collected
using a track excavator. The soil samples were placed into clean laboratory prepared containers
and sealed with airtight Teflon lids. The sampling jars were placed in a cooler and maintained
at approximately 4° Celsius immediately after collection. The soil samples were delivered to a
North Carolina certified laboratory for analysis. The date and time the samples were collected
and submitted to the laboratory can be found on the chain of custody forms in Appendix G.
No field or equipment blank samples were collected for quality control measures. Due to an
equipment malfunction at the Pace laboratory, the GRO analyses were subcontracted to ENCO
in Cary, NC to ensure that the samples would be analyzed within the required 14-day hold
time.

One trip blank was included with the sample shipment and was analyzed for volatile organic
compounds using EPA Method 8260. The laboratory results of the trip blank indicate that none
of the targeted compounds were detected above the laboratory detections limits.

Caraway Grocery – 3419 Old Lexington Road, Asheboro, NC – 20-Day/UST Closure 9
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The Pace report indicates that the surrogate recovery was either not evaluated, was outside the
control limits or exceeded the laboratory control limits for some samples due to matrix
interferences. In addition, matrix spike and/or matrix spike duplicate recovery was outside the
control limits for some samples. Detailed explanations of the QA/QC qualifiers are included on
pages 6-16 of the Pace report in Appendix G.

D. Investigation Results:

The laboratory results of the soil samples are summarized in Tables 2, 3, 4, 5 and 6. Copies of
the laboratory reports and chain-of-custody forms are included in Appendix G.

IV. Conclusions and Recommendations

On February 24 through March 1, 2010, Pyramid supervised the closure of five (5)
underground storage tanks with the associated product lines and pump islands at the former
Caraway Grocery at 3419 Old Lexington Road in Asheboro, North Carolina. The UST system
included two 2,000-gallon gasoline, one 275-gallon gasoline, one 625-gallon gasoline and one
270-gallon kerosene tanks. The two 2,000-gallon gasoline tanks were the only tanks that were
registered with the DENR UST Section. The three additional unregistered USTs were installed
in the 1920s and taken out of service before 1985. This report completes the closure assessment
necessary to comply with the 20-Day and Initial Abatement Action reporting requirements.

Based on the locations of the tanks, four separate excavations were necessary to complete the
UST and contaminated soil removal. Petroleum contaminated soils removed from the site were
transported to EVO Corporation in Winston-Salem, NC for treatment and disposal. Based on
certified weight tickets, 248.48 tons of petroleum-contaminated soil was removed from the site.

The laboratory results of post excavation soil samples collected from each excavation indicate
that some of the targeted compounds were detected at concentrations that exceed the soil to
groundwater MSCCs. Only two of the 20 post excavation soil samples (T4E-1 and T5E-3)
contained concentrations that exceed the residential MSCCs. Sample T4E-1 was collected from
the Tank #4 excavation on the sidewall nearest the existing canopy at a depth of 11 feet below
land surface. T4E-1 contained concentrations of C5-C8 and C9-C12 aliphatics that exceed the
residential MSCCs. Sample T5E-3 was collected from the Tank #5 excavation on the sidewall
nearest the existing building. T5E-3 contained concentrations of C9-22 aromatics that exceed
the residential MSCCs. In both cases, the soil samples were collected from locations where
excavation was limited by the existing structure. The excavations at Tank #4 and #5 had been
extended as close as possible to the building before the samples were collected.

During the planning phase of the work, the current property owner was asked if the building
could be demolished prior to removing the USTs to provide better access for the removal of
contaminated soil; however, he did not allow the demolition because of the historical
significance of the structure. If the property owner had agreed to demolish the existing
structure, it is likely that all contaminated soil with concentrations that exceed the residential
MSCCs could have been removed. Given the site conditions, limited work space and shallow
rock, most of the contaminated soils were removed from the source areas which should reduce

TABLES
Sample Date Sample Depth FID/OVM EPA Method EPA Method
Number Collected Location (feet) (ppm) 5030-GRO (mg/kg) 3550-DRO (mg/kg)
T1-SE 2/25/2010 Tank 1 - south end 6-7 420 NA NA
T1-NE 2/25/2010 Tank 1 - north end 6-7 >1000 NA NA
T2-NE 2/25/2010 Tank 2 - near north end 7-Jun >1000 NA NA
*T1A-8 2/25/2010 Tank 1 - near south end 8 120 38 NA
*T1B-8 2/25/2010 Tank 1 - north end 8 >1000 370 NA
*T2A-8 2/25/2010 Tank 2 - south end 8 14 23 NA
*T2B-8 2/25/2010 Tank 2 - north end 8 >1000 6500 NA
*T3-6 2/25/2010 Tank 3 - bottom/center 6 >1000 7100 NA
*T4A-6 2/25/2010 Tank 4 - south end 6 >1000 7700 NA
*T4B-6 2/25/2010 Tank 4 - north end 6 >1000 14000 NA
*T5-4 2/25/2010 Tank 5 - bottom/center 4 10 25 1220
2KTPBC 2/25/2010 2K tank pit - bottom/center 12-13 >1000 NA NA
*2KTE-3 2/25/2010 2K tank pit - east sidewall 11 >1000 NA NA
*2KTE-2 2/25/2010 2K tank pit - north sidewall 11 300 NA NA
*2KTE-4 2/25/2010 2K tank pit - south sidewall 10 10 NA NA
*2KTE-5 2/25/2010 2K tank pit - bottom/center 13-14 >1000 NA NA
*2KTE-1 2/25/2010 2K tank pit - west sidewall 10-11 430 NA NA
T3E-5 2/26/2010 Tank 3 - bottom/center 9-10 >1000 NA ND
*T3E-2 2/26/2010 Tank 3 - south sidewall 9-10 <1 NA ND
*T3E-1 2/26/2010 Tank 3 - east sidewall 12 50 NA NA
*T3E-4 2/26/2010 Tamk 3 - north sidewall 12 >1000 NA NA
*T3E-5 2/26/2010 Tank 3 - bottom/center 13-14 >1000 NA NA
*T3E-3 2/26/2010 Tank 3 - west sidwall 13 >1000 NA NA
319 Old Lexington Road, Asheboro, NC
Pyramid Project #2009-311
INITIAL UST CLOSURE SAMPLES
EXCAVATION SCREENING SAMPLES & POST-EXCAVATION SAMPLES
TABLE 2
Summary of Field Screening and TPH Laboratory Results
Former Caraway Grocery - UST System Closure Samples
Page 1 of 2
Sample Date Sample Depth FID/OVM EPA Method EPA Method
Number Collected Location (feet) (ppm) 5030-GRO (mg/kg) 3550-DRO (mg/kg)
319 Old Lexington Road, Asheboro, NC
Pyramid Project #2009-311
TABLE 2
Summary of Field Screening and TPH Laboratory Results
Former Caraway Grocery - UST System Closure Samples
T4E-2 2/26/2010 Tank 4 - south sidewall 8 130 NA NA
*T4E-3 2/26/2010 Tank 4 - west sidewall 8 <1 NA NA
*T4E-4 2/26/2010 Tank 4 - north sidewall 8 >1000 NA NA
T4E-5 2/26/2010 Tank 4 - bottom/center 9 500 NA NA
*T4E-5 2/26/2010 Tank 4 - bottom/center 12-13 150 NA NA
*T4E-2 2/26/2010 Tank 4 - south sidewall 10 5 NA NA
*T4E-1 2/26/2010 Tank 4 - east sidewall 11 >1000 NA NA
*T5E-1 2/26/2010 Tank 5 - east sidewall 6 6 NA NA
*T5E-2 2/26/2010 Tank 5 - south sidewall 5 <1 NA NA
*T5E-3 2/26/2010 Tank 5 - west sidewall 6 150 NA NA
*T5E-4 2/26/2010 Tank 5 - north sidewall 6 <1 NA NA
*T5E-5 2/26/2010 Tank 5 - bottom/center 7 200 NA NA
*PL1-3 2/26/2010 Product line at south dispenser 3 5 NA NA
*PL2-3 2/26/2010 Product line at north dispenser 3 <1 2.9 NA
10 10
ND = Not Detected Samples with no GRO or DRO data were collected for
Bold values exceed the NCDENR Initial Cleanup Level screening purposes only or were analyzed for risk-based
NA = Not Analyzed for this parameter methods only. The lab results of the risk-based analses
* indicates that the sample was collected for lab analysis are shown on Tables 3, 4, 5 & 6
Reference Figure 3 for sample locations
PRODUCT LINE / PUMP ISLAND SAMPLES
NCDENR Initial Cleanup Level (mg/kg)
Page 2 of 2
Analytical AnalyticalSoil toParameter Method 2KTE-1 2KTE-2 2KTE-3 2KTE-4 2KTE-5 PL1-3 Groundwater ResidentialSample Date: 2/15/2010 2/15/2010 2/15/2010 2/15/2010 2/15/2010 2/15/2010MSCC MSCCSample Depth (feet): 10-11 11 11 10 12-13 3 (mg/kg) (mg/kg)C5-C8 AliphaticsVPH BDL BDL 16.7 BDL 22.3 BDL 68 939C9-C12 AliphaticsVPH BDL BDL 96.5 BDL 37.5 BDLC9-C18 AliphaticsEPH NA NA NA NA NA NA 540 1500Sum of VPH & EPHBDL BDL 96.5 BDL 37.5 BDLC19-C36 AliphaticsEPH NA NA NA NA NA NA CI 31000C9-C10 AromaticsVPH BDL BDL34.7BDL 11.4 BDLC11-C22 AromaticsEPH NA NA NA NA NA NA 31 469Sum of VPH & EPHBDL BDL34.7BDL 11.4 BDLAcetone8260 BDL 0.164 BDL BDL BDL BDL 24 14000Benzene8260 BDL BDL BDL BDL BDL BDL 0.0056 18n-Butylbenzene8260 BDL BDL 2.37 BDL 1.16 BDL 4.3 626sec-Butylbenzene8260 BDL BDL BDL BDL BDL BDL 3.3 626tert-Butylbenzene8260 BDL BDL BDL BDL BDL BDL 3.4 6264-isopropyltoluene8260 BDL BDL 0.985 BDL BDL BDL NS NSEthylbenzene8260 BDL BDL 0.509 BDL 1.62 BDL 4.9 1560IPE8260 BDL BDL BDL 0.0053 BDL BDL 0.37 156Isopropylbenzene8260 BDL BDL 0.664 BDL 0.668 BDL 1.7 1564Methyl ethyl ketone (MEK)8260 BDL BDL BDL BDL BDL BDL 16 9385Naphthalene8260 BDL 0.01167.040.01352.2BDL 0.16 313n-Propylbenzene8260 BDL BDL 1.31 BDL BDL BDL 1.7 626Styrene8260 BDL BDL BDL BDL 0.469 BDL 1.5 3128Toluene8260 BDL BDL BDL 0.0175 1.78 BDL 4.3 12001,2,4-Trimethylbenzene8260 BDL 0.0167130.01568.710.0091 8.5 7821,3,5-Trimethylbenzene8260 BDL 0.0049 3.91 BDL 2.78 BDL 8.3 782Total Xylenes8260 BDL 0.0193 3.51 0.03188.20.0193 4.6 3129MTBE8260 BDL BDL BDL BDL BDL BDL 0.091 350All Other 8260 Parameters8260 BDL BDL BDL BDL BDL BDL N/A N/AMSCC=Maximum Soil Contaminant Concentration BDL = Below Det. Limits NA=Not Analyzed for this parametermg/kg = parts per million (ppm). CI=Considered ImmobileBOLD and shaded values exceed Soil to GW or Residential MSCC's N/A=Not Applicable J = Estimated ValueReference Figure 3 for sample locationsSample NumberPyramid Job #2009-311TABLE 3Laboratory Results of Post Excavation Samples - Tank #1 & #2 (2,000-gallon Gasoline USTs)Caraway Grocery - FTF No. 241743419 Old Lexington Road, Asheboro, NCNS = No Standard
Analytical AnalyticalSoil toParameter Method T3E - 1 T3E-2 T3E-3 T3E-4 T3E-5 Groundwater ResidentialSample Date: 2/26/2010 2/26/2010 2/26/2010 2/26/2010 2/26/2010MSCC MSCCSample Depth (feet): 10 10 13 12 13-14 (mg/kg) (mg/kg)C5-C8 AliphaticsVPH BDL BDL85BDL 53.4 68 939C9-C12 AliphaticsVPH BDL BDL 245 BDL 140C9-C18 AliphaticsEPH NA NA NA NA NA 540 1500Sum of VPH & EPHBDL BDL 245 BDL 140C19-C36 AliphaticsEPH NA NA NA NA NA CI 31000C9-C10 AromaticsVPH BDL BDL63.4BDL36C11-C22 AromaticsEPH NA NA NA NA NA 31 469Sum of VPH & EPHBDL BDL63.4BDL36Acetone8260 BDL BDL BDL 0.112 BDL 24 14000Benzene8260 BDL BDL BDL0.0106BDL 0.0056 18n-Butylbenzene8260 BDL BDL 3.11 0.0759 2.06 4.3 626sec-Butylbenzene8260 BDL BDL 1.29 0.0232 0.587 3.3 626tert-Butylbenzene8260 BDL BDL BDL BDL BDL 3.4 6264-isopropyltoluene8260 BDL BDL 2.25 0.0405 1.3 NS NSEthylbenzene8260 BDL BDL6.150.267 1.86 4.9 1560IPE8260 BDL BDL BDL BDL BDL 0.37 156Isopropylbenzene8260 BDL BDL 2.34 0.0434 1.04 1.7 1564Methyl ethyl ketone (MEK)8260 BDL BDL BDL BDL BDL 16 9385Naphthalene8260 BDL BDL4.77BDL2.410.16 313n-Propylbenzene8260 BDL BDL6.22BDL2.881.7 626Styrene8260 BDL BDL BDL BDL BDL 1.5 3128Toluene8260 BDL BDL11.7BDL 2.13 4.3 12001,2,4-Trimethylbenzene8260 0.0079 BDL27.70.91213.78.5 7821,3,5-Trimethylbenzene8260 BDL BDL8.950.241 4.51 8.3 782Total Xylenes8260 BDL BDL28.61.24 3.28 4.6 3129MTBE8260 BDL BDL BDL BDL BDL 0.091 350All Other 8260 Parameters8260 BDL BDL BDL BDL BDL N/A N/AMSCC=Maximum Soil Contaminant Concentration BDL = Below Detection Limits NA=Not Analyzed for this parameterReference Figure 3 for sample locationsmg/kg = parts per million (ppm). CI=Considered ImmobileBOLD and shaded values exceed Soil to GW or Residential MSCC's N/A=Not Applicable J = Estimated ValueSample NumberTABLE 4Laboratory Results of Post Excavation Samples - Tank #3 (275-gallon Gasoline UST)Caraway Grocery - FTF No. 241743419 Old Lexington Road, Asheboro, NCPyramid Job #2009-311NS = No Standard
Analytical AnalyticalSoil toParameter Method T4E - 1 T4E-2 T4E-3 T4E-4 T4E-5 Groundwater ResidentialSample Date: 2/26/2010 2/26/2010 2/26/2010 2/26/2010 2/26/2010MSCC MSCCSample Depth (feet): 11 10 8 8 12-13 (mg/kg) (mg/kg)C5-C8 AliphaticsVPH94615.9 BDL 24.2 BDL 68 939C9-C12 AliphaticsVPH159051.3 BDL 129 BDLC9-C18 AliphaticsEPH NA NA NA NA NA 540 1500Sum of VPH & EPH159051.3 BDL 129 BDLC19-C36 AliphaticsEPH NA NA NA NA NA CI 31000C9-C10 AromaticsVPH35910.4 BDL 27 BDLC11-C22 AromaticsEPH NA NA NA NA NA 31 469Sum of VPH & EPH35910.4 BDL 27 BDLAcetone8260 BDL BDL BDL BDL 0.127 24 14000Benzene82600.912BDL BDL BDL BDL 0.0056 18n-Butylbenzene826014.2BDL BDL 0.0226 BDL 4.3 626sec-Butylbenzene82606.21BDL BDL 0.0112 BDL 3.3 626tert-Butylbenzene8260 1.41 BDL BDL BDL BDL 3.4 6264-isopropyltoluene8260 18.4 BDL BDL 0.0291 BDL NS NSEthylbenzene82607.03BDL BDL 0.0048 BDL 4.9 1560IPE8260 BDL BDL BDL BDL BDL 0.37 156Isopropylbenzene826010.7BDL BDL 0.013 BDL 1.7 1564Methyl ethyl ketone (MEK)8260 BDL BDL BDL BDL BDL 16 9385Naphthalene826038.9BDL BDL 0.12 BDL 0.16 313n-Propylbenzene826019.5BDL BDL 0.0128 BDL 1.7 626Styrene8260 BDL BDL BDL BDL BDL 1.5 3128Toluene826012.8BDL BDL 0.0055 BDL 4.3 12001,2,4-Trimethylbenzene8260145BDL BDL 0.223 BDL 8.5 7821,3,5-Trimethylbenzene826072.3BDL BDL 0.0906 BDL 8.3 782Total Xylenes8260187BDL BDL 0.173 BDL 4.6 3129MTBE8260 BDL BDL BDL BDL BDL 0.091 350All Other 8260 Parameters8260 BDL BDL BDL BDL BDL N/A N/AMSCC=Maximum Soil Contaminant Concentration BDL = Below Detection Limits NA=Not Analyzed for this parameterReference Figure 3 for sample locationsmg/kg = parts per million (ppm). CI=Considered ImmobileBOLD and shaded values exceed Soil to GW or Residential MSCC's N/A=Not Applicable J = Estimated ValueSample NumberTABLE 5Laboratory Results of Post Excavation Samples - Tank #4 (625-gallon Gasoline UST)Caraway Grocery - FTF No. 241743419 Old Lexington Road, Asheboro, NCPyramid Job #2009-311NS = No Standard
Analytical AnalyticalSoil toParameter MethodT5E-1 T5E-2 T5E-3 T5E-4 T5E-5Groundwater ResidentialSample Date:2/26/2010 2/26/2010 2/26/2010 2/26/2010 2/26/2010MSCC MSCCSample Depth (feet):65667(mg/kg) (mg/kg)C5-C8 Aliphatics VPH BDL BDL BDL BDL BDL 68 939C9-C12 Aliphatics VPH BDL BDL 207 22.6 141C9-C18 Aliphatics EPH 122 NA NA NA648540 1500Sum of VPH & EPH 122 BDL 207 22.6789C19-C36 Aliphatics EPH NA 31.4 1440 NA NA CI 31000C9-C10 Aromatics VPH BDL BDL60BDL35.1C11-C22 Aromatics EPH 19.9 NA407NA18231 469Sum of VPH & EPH 19.9 BDL467BDL217.1Acetone 8260 BDL BDL BDL BDL BDL 24 14000Benzene 8260 BDL BDL BDL BDL BDL 0.0056 18n-Butylbenzene 8260 BDL BDL 2.03 BDL 0.55 4.3 626sec-Butylbenzene 8260 BDL BDL 0.568 BDL 0.624 3.3 626tert-Butylbenzene 8260 BDL BDL BDL BDL BDL 3.4 6264-isopropyltoluene 8260 BDL BDL 1.21 BDL 0.505 NS NSEthylbenzene 8260 BDL BDL BDL BDL BDL 4.9 1560IPE 8260 BDL BDL BDL BDL BDL 0.37 156Isopropylbenzene 8260 BDL BDL 0.314 BDL BDL 1.7 1564Methyl ethyl ketone (MEK) 8260 BDL BDL BDL BDL BDL 16 9385Naphthalene 8260 BDL BDL4.9BDL0.4630.16 313n-Propylbenzene 8260 BDL BDL 0.387 BDL BDL 1.7 626Toluene 8260 BDL BDL BDL BDL BDL 4.3 12001,2,4-Trimethylbenzene 8260 BDL BDL 1.17 BDL BDL 8.5 7821,3,5-Trimethylbenzene 8260 BDL BDL 2.09 BDL BDL 8.3 782Total Xylenes 8260 BDL BDL BDL BDL BDL 4.6 3129MTBE 8260 BDL BDL BDL BDL BDL 0.091 350All Other 8260 Parameters8260 BDL BDL BDL BDL BDL N/A N/ASample NumberTABLE 6Laboratory Results of Post Excavation Samples - Tank #5 (270-gallon Kerosene UST)Caraway Grocery - FTF No. 241743419 Old Lexington Road, Asheboro, NCPyramid Job #2009-311Page 1 of 2
Analytical AnalyticalSoil toParameter MethodT5E-1 T5E-2 T5E-3 T5E-4 T5E-5Groundwater ResidentialSample Date:2/26/2010 2/26/2010 2/26/2010 2/26/2010 2/26/2010MSCC MSCCSample Depth (feet):65667(mg/kg) (mg/kg)Sample NumberTABLE 6Laboratory Results of Post Excavation Samples - Tank #5 (270-gallon Kerosene UST)Caraway Grocery - FTF No. 241743419 Old Lexington Road, Asheboro, NCPyramid Job #2009-311Anthracene 8270 BDL BDL BDL BDL BDL 940 46002,4-Dichlorophenol 8270 BDL BDL BDL BDL BDL NS NS2,4-Dimethylphenol 8270 BDL BDL BDL BDL BDL 0.64 3122,3-dinitrotoluene 8270 BDL BDL BDL BDL BDL NS NS2-methylphenol 8270 BDL BDL BDL BDL BDL NS NS2-nitrophenol 8270 BDL BDL BDL BDL BDL NS NS3&4-methylphenol 8270 BDL BDL BDL BDL BDL NS NS4-nitrophenol 8270 BDL BDL BDL BDL BDL NS NSBenzioc Acid 8270 BDL BDL BDL BDL BDL 120 62571bis(2-chloroethoxy)methane 8270 BDL BDL BDL BDL BDL NS NSbis(2-chloroethyl)ether 8270 BDL BDL BDL BDL BDL 0.00016 0.581-Methylnaphthalene 8270 BDL BDL BDL BDL 2.48 NS NS2-Methylnaphthalene 8270 BDL BDL8.64BDL 0.775 3.6 63Benzo(b)fluoroanthene 8270 BDL BDL BDL BDL BDL 1.2 0.88Diethyl Phthalate 8270 BDL BDL BDL BDL BDL NS NSDimethyl phthalate 8270 BDL BDL BDL BDL BDL NS NSHexachloroethane 8270 BDL BDL BDL BDL BDL NS NSNaphthalene 8270 BDL BDL BDL BDL BDL 0.16 313Nitrobenzene 8270 BDL BDL BDL BDL BDL NS NSN-nitrosodi-n-Propylamine 8270 BDL BDL BDL BDL BDL NS NSN-Nitrosodiphenylamine 8270 BDL BDL BDL BDL BDL NS NSPhenanthrene 8270 BDL BDL BDL BDL BDL 56 469Phenol 8270 BDL BDL BDL BDL BDL 0.17 4693Pyrene 8270 BDL BDL BDL BDL BDL 270 469All Other 8270 Parameters8270 BDL BDL BDL BDL BDL N/A N/AMSCC=Maximum Soil Contaminant Concentration BDL = Below Detection Limits NA=Not Analyzed for this parameterReference Figure 3 for sample locationsmg/kg = parts per million (ppm). CI=Considered ImmobileBOLD and shaded values exceed Soil to GW or Residential MSCC's N/A=Not Applicable J = Estimated ValueNS = No StandardPage 2 of 2

APPENDIX A

Non-Hazardous Liquid Manifest

APPENDIX B

Site Investigation Report for Permanent Closure - UST-2 Form

APPENDIX C

Certificate of Disposal, Non-Hazardous Manifests
and Certified Weight Tickets for Soil

APPENDIX D

Certificate of Tank Disposal

APPENDIX E

Site Photographs

APPENDIX F

Standard Field Procedures
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Standard Field Procedures : Revision 10 Page 1 of 7
Pyramid Environmental & Engineering, P.C. 01-31-2010

Standard Field Procedures
Pyramid Environmental & Engineering, P.C.

1.0 Equipment Decontamination:
Equipment decontamination is essential to assure representative environmental samples are collected and to
eliminate the potential for cross contamination between sample points. Pyramid strives to clean all field
equipment prior to leaving the office; however, field decontamination is still required on most projects.
The procedures for decontamination of water level probes, hand augers, sampling probes and trowels, and
other field equipment are listed below.

1.1 EPA Region IV Decontamination Procedures:
Drilling and soil sampling equipment is decontaminated prior to use using a pressure washer or steam
cleaner. Reusable sampling equipment, hand augers, sampling probes and trowels, split spoon samplers,
water sampling equipment are decontaminated using the general procedure described below.

1. Wash with non-phosphate detergent and water, brush to remove particulate matter.
2. Rinse with tap water.
3. Rinse with 10 percent nitric acid solution (only if sampling for metals)
4. Rinse with deionized water.
5. Rinse with pesticide-grade isopropyl alcohol.
6. Rinse with deionized water.
7. Air-dry as long as possible.

The level of decontamination used is appropriate to the analytical parameters selected and the material
being used for sampling. For example, if metals analyses are required, then the 10 % nitric acid solution is
used for decontamination of stainless steel equipment. Pyramid obtains laboratory grade deionized water in
gallon jugs from the analytical laboratory for use in decontamination. Equipment that is not used
immediately after decontamination is wrapped in aluminum foil prior to storage.

2.0 Soil Boring Installation & Sampling:

Soil borings are used by Pyramid to characterize the subsurface at many sites. The borings provide
information concerning soil types and density, depth to refusal, depth to bedrock, organic vapors that may
be present, and can be used to obtain samples for laboratory analysis. Pyramid conducts borings in many
different ways, using hand augers, Direct Push equipment (Geoprobe), sample probes, split-spoon samplers
(ASTM D 1586-84), auger drilling, air drilling, and Virbo-Core. The following procedures are used by
Pyramid Environmental when performing soil borings:

1. Soil boring locations are chosen, and the utility locating service is called to mark all utilities. If
private utilities at the site need to be located in addition to the public utility locating service, then
these utilities are located and marked by a private utility locator service.
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Pyramid Environmental & Engineering, P.C. 01-31-2010

2. Down hole drilling equipment is cleaned prior to use and between borings using pressure washing.
Additional decontamination procedures are used for quality assurance for sampling tools such as
split spoons or Direct-Push Points.
3. Soil borings are advanced using direct-push, drilling rigs, hand augers, or other appropriate means.
4. Soil samples are normally collected at a minimum of 5-foot intervals. Each sample is divided into
two parts. Soil samples for laboratory analyses are jarred from the initial sample volume. The
remaining soil is stored in a sealed container for headspace analysis with an organic vapor
analyzer (OVA). After screening the soil with the field instruments, each soil sample is described
by the field geologist and a geologic description is recorded in the field notes.
5. Soil samples selected for laboratory analysis are placed in properly prepared, laboratory supplied
containers and immediately packed in a cooler on ice. Sample custody is maintained using
standard chain-of-custody procedures through delivery to the analytical laboratory.
6. Soil borings, which are not completed as monitor wells are grouted using a Portland cement,
bentonite, or backfilled with soil cuttings.
7. Soils are typically described in the field by the project geologist or soil scientist and are classified
according to the Unified Soil Classification System (ASTM D 2488-84).

2.1 Headspace Screening:
Soil samples are routinely screened for volatile organic compounds (VOCs) which may be an indication of
organic or petroleum hydrocarbon contamination. The typical screening procedure includes immediately
transferring the soil from the sampling devices to a sealed container (sealed plastic bag). The soil container
is filled approximately halfway with soil and sealed. This creates headspace above the soil in which VOCs
may accumulate. The container is allowed to stand for 5 to 15 minutes for the VOCs to equilibrate in the
headspace of the container. The headspace of the container is then screened using a calibrated organic
vapor analyzer (PID or FID). The screening is conducted by cracking the seal only enough to allow
insertion of the probe into the headspace so as not to dilute the sample. In most cases where the
contaminant of concern includes volatile organics, the soil samples showing the highest OVA readings from
each boring are selected for laboratory analysis.

2.2 Soil Sample Collection for Laboratory Analysis:
After the soil sampling depth has been reached, soil samples are collected using a variety of sampling
devices. The soil sample methods include sampling from split-spoons, stainless steel hand augers, stainless
steel sampling scoops, and directly from the center of the excavator bucket. The sample technician uses
appropriate disposable sampling gloves, which are changed between samples to avoid cross-contamination
of samples. Each sampling device is decontaminated prior to use. Only laboratory provided containers are
used for sample collection. Samples are collected in accordance with the preservation methods required by
the requested analytical method. Samples are handled as little as possible and preserved in the field as
specified for the analytical method. The samples are stored and transported to the laboratory in an
insulated cooler chilled to approximately 4 degrees C. The samples are labeled with a minimum of the
following information: project name or number, sampler name, date collected, sample number, and analysis
requested. Sample custody is maintained using standard chain-of-custody procedures through delivery to
the analytical laboratory. Notes of the sampling events are recorded in bound field notebooks.
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Standard Field Procedures : Revision 10 Page 3 of 7
Pyramid Environmental & Engineering, P.C. 01-31-2010

3.0 Direct Push Sampling Procedures
Direct Push sampling techniques has been used at many sites to collect soil and groundwater samples
rapidly and inexpensively. Track mounted direct push rigs can access hard to reach areas and allow
borings and small diameter monitoring wells to be installed. Pyramid has used this technology to the
benefit of our clients at many sites.

For soil sampling, typically, the direct push steel drive tube is decontaminated using a water pressure, and a
new plastic liner is inserted in the steel drive tube to collect the sample. If necessary, the stainless-steel
sampling tube is decontaminated using Region IV decontamination procedures. The soil samples are
collected in new polyethylene liner tubes within the steel drive tube. The soil sample is then extracted from
the polyethylene liner and preserved as required for the appropriate laboratory analysis.

The steel tubing and screen are driven to depth and the screened section is opened to allow groundwater to
enter the tubing. The water samples are withdrawn using new polyethylene tubing with either a
decontaminated stainless-steel check ball, or peristaltic pump. The groundwater sample is placed directly
into the appropriate laboratory containers and sealed immediately. To prevent cross contamination of
samples, new disposable tubing is used for each groundwater sample point. Disposable nitrile gloves are
worn by field personnel during sampling, and gloves are changed between samples. Groundwater sampling
procedures are detailed more in section 5.0., and are changed as appropriate for each analytical method.

4.0 Monitoring Well Installation
Monitoring wells are installed in many subsurface environments; sedimentary, Piedmont saprolite, and
mountain terrains to list a few. Formations encountered include unconsolidated and consolidated
sediments, saprolitic formations, weathered bedrock, and bedrock. Groundwater monitoring wells provide
a stable sampling point at discrete intervals within the confined or unconfined aquifers. Monitoring wells
are installed for a number of reasons, and are typically installed as 1-inch, 2-inch, 4-inch, or 6-inch
diameter wells. Construction may be of PVC or other appropriate materials. The following procedures are
used by Pyramid when performing borings and monitoring well installations :

1. If required, monitoring well permits are obtained from the State, County, or City agency.
2. Boring and monitoring well locations are chosen, and utilities are marked by the public utility
locating company. In some cases the drill locations are also checked using a private utility locator.
3. In selecting a drill site, care id given to avoid overhead power lines, and subsurface utilities
whenever possible.
4. Down hole drilling equipment is washed prior to use and between borings.
5. Borings are advanced using direct-push, drilling rigs, hand augers, or other appropriate means.
Monitor well drilling usually includes using hand auger, solid-stem augers, hollow-stem augers,
air rotary drilling, or air hammer drilling.
6. Soil samples are normally collected at a minimum of 5-foot intervals. Each sample is divided into
two parts. Soil samples for laboratory analyses are jarred from the initial sample volume. The
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Standard Field Procedures : Revision 10 Page 4 of 7
Pyramid Environmental & Engineering, P.C. 01-31-2010

remaining soil is stored in a sealed container for headspace analysis with an organic vapor
analyzer (OVA). After screening the soil with the field instruments, each soil sample is described
by the field geologist and a geologic description is recorded in the field notes.
7. Type II monitoring wells are usually installed using 2-inch diameter schedule 40 PVC riser and 2-
inch, 0.010-inch slotted well screen. The screened interval varies with the purpose, and well
details are presented with the boring logs.
8. Type III wells are usually installed as double cased wells to monitor the deeper portions of the
aquifer. The first casing is usually a 6-inch diameter casing drilled to bedrock or an appropriate
depth within the saprolite. The 6-inch diameter casing is then set and grouted in the borehole.
After the cement grout has set for 24-hours, the borehole is completed to the desired depth using
air rotary drilling or an air hammer. The Type III monitor well is usually constructed of 2-inch
diameter sch 40 PVC casing and 2-inch diameter 0.010-inch slotted well screen.
9. In most applications, a sand filter pack of #2 well sand (or appropriate well sand) is typically
installed to a level of 2 feet above the top of the screen in each well. A minimum 2-foot thick
bentonite seal is usually placed on top of the filter pack and hydrated with deionized or distilled
water. The remaining annular space of a typical well is backfilled to grade with a Portland
cement/bentonite grout. In monitoring wells where the water table is close to surface, the amount
of sand above the screen and bentonite will be reduced to allow for a minimum of 2 –3 feet of
cement grout.
10. At the surface, each well is usually secured with a locking cap and a steel well protector set in a 2
by 2 foot concrete pad. In some cases, stick-up well protectors are used to secure the well and
allow the well to more easily be located in wooded or open areas.
11. Each monitoring well is developed by surging, pumping, or bailing to obtain clear water samples.
All water removed during development was managed according to State specific standards.

5.0 Water Sampling Procedures
Pyramid relies on water sampling as a primary method for assessment of subsurface conditions. Water
sampling typically includes sampling groundwater from monitoring wells, supply wells, surface water
bodies, waste pits, sumps, etc…. The following provides typical sampling procedures for the major sample
types.

5.1 Monitoring Wells

1. Prior to sampling each monitor well, depth to product/groundwater and total well depth are
measured using a properly decontaminated electric interface probe. This information is recorded
in the field record and the volume of the water in the well casing is calculated.
2. To purge stagnant water from each monitor well, five well casing volumes of water are removed
from each well, or until the field parameters pH, Conductivity, D.O., and Temperature have
stabilized. If the water in the monitoring well is removed until the well is dry, then the well is
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Pyramid Environmental & Engineering, P.C. 01-31-2010

sampled thereafter. Water removed from wells during purging is managed according to the DENR
Guidelines.
3. Depending on project requirements, temperature, pH, specific conductance, dissolved oxygen, and
other parameters may be measured prior to sampling.
4. Groundwater samples are typically collected using a new disposable polyethylene bailer and a new
length of nylon cord. To prevent cross contamination of samples between wells, a new disposable
bailer is used for each well. A new pair of disposable gloves is worn by field personnel during
purging and sampling, and is changed between wells.
5. In the case of small diameter monitoring wells or direct-push water samples, water samples may
be collected using a peristaltic pump and new polyethylene tubing. Another method is to use a
segment of new polyethylene tubing and a stainless-steel check ball to create a “Tube Bailer”.
6. Groundwater samples selected for laboratory analysis are placed in properly prepared, laboratory
supplied containers and immediately packed in a cooler on ice. Samples are maintained under
strict control using standard chain-of-custody procedures through laboratory analysis.

5.2 Water Supply Well Sampling Procedures

1. Prior to sampling each water supply well, the well owner is contacted to provide access to the
well. The well owner is interviewed to find the faucet closest to the well for sampling. If there are
no faucets located on the well, then an outside faucet is used. If there are no outside faucets
available, then an inside tap is used. The information regarding the location of the faucet is
recorded in the field book.
2. The owner is interviewed to see if there is a chlorination system on the well, or if the well has
been recently chlorinated. Recent chlorination could affect the laboratory detection limits. In most
cases, the samples are preserved using sodium thiasulfate or ascorbic acid to remove the
interactions of chlorine, which may be present in the samples.
3. To purge stagnant water from the water supply well system, the faucet is allowed to run on full
stream for a minimum of 15 minutes. The aerator is removed from the tap if one is present. Water
removed from wells during purging is managed according to State Standards.
4. Supply well samples are collected using appropriate laboratory prepared containers for each
analysis. The analytical methods selected will vary with the contaminant of interest.
5. To prevent cross contamination of samples between wells, disposable latex gloves are worn by
field personnel during purging and sampling and are changed between wells.
6. It is possible that samples may be required at several places within the water supply system. The
samples will be collected accordingly and labeled to show the source and location sampled.
7. Supply well samples selected for laboratory analysis are placed in properly prepared, laboratory
supplied containers and immediately packed in a cooler on wet ice, and chilled to approximately 4
degrees Celsius. Samples are maintained under strict control using standard chain-of-custody
procedures through laboratory analysis.

______________________________________________________________________________________
Standard Field Procedures : Revision 10 Page 6 of 7
Pyramid Environmental & Engineering, P.C. 01-31-2010

5.3 Surface Water Sampling

Surface water samples are obtained using several techniques including use of sample bailers, scoops, from
boats, bridges, or actually wading into a stream. Caution should always be used when sampling surface
water to insure that the water collected is representative of the conditions. Since stream or open water
sampling is transient, careful documentation of the conditions is required. In many studies, additional
samples from upstream and downstream of the desired sample point are required. Surface water sampling
must be planned to reflect the desired conditions during sampling. The general procedures are similar to
the supply well sampling procedures detailed above.

1. Prepare the appropriate laboratory prepared containers for each analysis. The analytical methods
selected will vary with the contaminant of interest.
2. To prevent cross contamination of samples between samples, disposable latex gloves are worn by
field personnel during purging and sampling and are changed between samples.
3. It is possible that samples may be required at several places along the stream to check for
influences of up-stream facilities. The samples will be collected accordingly and labeled to show
the source and location sampled.
4. Sample will always be collected upstream of the area disturbed by the sampler.
5. Surface water samples selected for laboratory analysis are placed in properly prepared, laboratory
supplied containers and immediately packed in a cooler on ice. Samples are maintained under
strict control using standard chain-of-custody procedures through laboratory analysis.
______________________________________________________________________________________
Standard Field Procedures : Revision 10 Page 7 of 7
Pyramid Environmental & Engineering, P.C. 01-31-2010

6.0 Quality Assurance / Quality Control
The decontamination procedures listed above have been implemented on many sites with excellent results.
The procedures are often verified by an appropriate use of the following environmental sample “Blanks”.

Trip Blanks are used to verify that the sample containers are not impacted during shipping, and verify that
the source of the glassware is not the source of contamination. The Trip Blanks are preserved de-ionized
water, collected in the laboratory, and shipped with the sample containers to the site. The trip blank
remains in the cooler and is shipped back to the laboratory with the environmental samples. The Trip
Blank is usually analyzed for volatile organics, which correspond to the target analyses.

Field Blanks are quality assurance samples which are collected in the field to represent the conditions
present at the time the samples are collected. For water samples, the laboratory containers are opened and
filled in the field using de-ionized (or distilled) water from a known source. The samples then travel to the
laboratory with the other samples for analysis.

Equipment Blanks are used to verify whether the decontamination procedures used were effective in
removing the contaminants from the sampling device. If a non-disposable sampling device is used (such as
a sampling treir, scoop, hand auger, Teflon bailer, etc…, then the decontamination of the sampling device
is usually verified using an equipment blank. The equipment blank is collected using de-ionized (or
distilled) water from a known source. The equipment is cleaned, and allowed to dry, the water is poured
over or through the equipment, and collected in the appropriate sample containers. The equipment blank
samples are preserved with the other environmental samples, and shipped for analyses for the target
parameters.

Duplicate Samples are used to verify the sampling procedures and laboratory analysis variability. The
duplicate samples may be collected from waste streams, soil, or groundwater. These samples are collected
and sent to the laboratory as a blind sample to have maximum effectiveness. Samples are generally
analyzed for the same analytical methods as the actual environmental sample for direct comparison.

APPENDIX G

Laboratory Reports

102-A Woodwinds Industrial Court
Cary NC, 27511
919.467.3090 919.467.3515Phone:FAX:www.encolabs.com
Environmental Conservation Laboratories, Inc.
ENCO Workorder: C002460
Huntersville, NC 28078
Dear Kevin Godwin,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Monday, March 8, 2010.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative. This report shall not be reproduced except in full, without
the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me.
Sincerely,
Enclosure(s)
Project Number: 9264404, Project Name/Desc: CARAWAY GROC. 2009311
Attn: Kevin Godwin
Pace Analytical (PA007)
9800 Kincey Ave. Suite 100
Bill Scott
Project Manager
Thursday, March 11, 2010
RE: Laboratory Results for
The total number of pages in this report, including this page is 16.
www.encolabs.com
PROJECT NARRATIVE
Client: Pace Analytical (PA007)
Project: CARAWAY GROC. 2009311
ENCO Project ID: C002460
Overview
All samples submitted were analyzed by Environmental Conservation Laboratories, Inc. in accordance with the
methods referenced in the laboratory report. Any particular difficulties encountered during sample handling and
processing will be discussed in the Remarks section below.
Remarks
Analysis: EPA 8015C
Affected Samples: T2B-8'[C002460-04], T3-6'[C002460-05], T4A-6'[C002460-06], T4B-6'[C002460-07]
Nonconformance: The sample extract was diluted by a factor of 5 or greater, which, according to ENCO policies
and procedures, is considered to result in possibly inaccurate and misleading results for the surrogates.
Therefore, the recovery of surrogates in this situation is not reported.
-------------------------------------------------------------------------------------------------------------------------------------------
Analysis: EPA 8015C
Affected Samples: T5-4'[C002460-08]
Nonconformance: One or more surrogate compounds added to the sample to monitor sample preparation
efficiency were out of control with high bias. Technical review of the chromatographic data indicates that this
was caused by matrix interferences that could not be resolved from the surrogate peak.
-------------------------------------------------------------------------------------------------------------------------------------------
Bill Scott
Project Manager
Page 2 of 16
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SAMPLE SUMMARY/LABORATORY CHRONICLE
T1A-8'C002460-01 Sampled:02/25/10 10:45 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/9/2010 19:29
T1B-8'C002460-02 Sampled:02/25/10 10:50 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/10/2010 11:57
T2A-8'C002460-03 Sampled:02/25/10 10:55 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/9/2010 20:31
T2B-8'C002460-04 Sampled:02/25/10 11:00 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/10/2010 15:03
T3-6'C002460-05 Sampled:02/25/10 15:45 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/10/2010 15:34
T4A-6'C002460-06 Sampled:02/25/10 17:15 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/10/2010 16:05
T4B-6'C002460-07 Sampled:02/25/10 17:20 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/10/2010 16:35
T5-4'C002460-08 Sampled:02/25/10 15:50 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/11/10 03/09/10 12:44 3/9/2010 23:06
PL2-3'C002460-09 Sampled:02/26/10 15:55 Received:03/08/10 14:45Client ID:Lab ID:
Prep Date/Time(s)Hold Date/Time(s)Parameter Analysis Date/Time(s)
EPA 8015C 03/12/10 03/09/10 12:44 3/9/2010 23:37
Page 3 of 16
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SAMPLE DETECTION SUMMARY
Lab ID:Client ID:T1A-8'C002460-01
Analyte MethodUnitsPQLResultsFlag NotesMDL
38 4.6 mg/kg dry EPA 8015C GRO (C6-C10)1.5
Lab ID:Client ID:T1B-8'C002460-02
Analyte MethodUnitsPQLResultsFlag NotesMDL
370 9.9 mg/kg dry EPA 8015CD GRO (C6-C10)3.2
Lab ID:Client ID:T2A-8'C002460-03
Analyte MethodUnitsPQLResultsFlag NotesMDL
23 4.9 mg/kg dry EPA 8015C GRO (C6-C10)1.6
Lab ID:Client ID:T2B-8'C002460-04
Analyte MethodUnitsPQLResultsFlag NotesMDL
6500 260 mg/kg dry EPA 8015CD GRO (C6-C10)86
Lab ID:Client ID:T3-6'C002460-05
Analyte MethodUnitsPQLResultsFlag NotesMDL
7100 250 mg/kg dry EPA 8015CD GRO (C6-C10)82
Lab ID:Client ID:T4A-6'C002460-06
Analyte MethodUnitsPQLResultsFlag NotesMDL
7700 250 mg/kg dry EPA 8015CD GRO (C6-C10)81
Lab ID:Client ID:T4B-6'C002460-07
Analyte MethodUnitsPQLResultsFlag NotesMDL
14000 240 mg/kg dry EPA 8015CD GRO (C6-C10)78
Lab ID:Client ID:T5-4'C002460-08
Analyte MethodUnitsPQLResultsFlag NotesMDL
25 4.7 mg/kg dry EPA 8015C GRO (C6-C10)1.5
Lab ID:Client ID:PL2-3'C002460-09
Analyte MethodUnitsPQLResultsFlag NotesMDL
2.9 6.0 mg/kg dry EPA 8015CJ GRO (C6-C10)2.0
Page 4 of 16
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ANALYTICAL RESULTS
T1A-8'Description:Lab Sample ID:C002460-01 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 10:45 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 86.60
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/09/10 19:29GRO (C6-C10) [ECL-0069] ^1 1.5 bpk0C090154.638
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168150 %bpkEPA 8015C 03/09/10 19:290C09015138.42 1
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 5 of 16
www.encolabs.com
T1B-8'Description:Lab Sample ID:C002460-02 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 10:50 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 82.30
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/10/10 11:57GRO (C6-C10) [ECL-0069] ^2 3.2 bpk0C090159.9370D
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168135 %bpkEPA 8015C 03/10/10 11:570C09015128.96 2
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 6 of 16
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T2A-8'Description:Lab Sample ID:C002460-03 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 10:55 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 79.40
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/09/10 20:31GRO (C6-C10) [ECL-0069] ^1 1.6 bpk0C090154.923
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168131 %bpkEPA 8015C 03/09/10 20:310C09015128.83 1
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 7 of 16
www.encolabs.com
T2B-8'Description:Lab Sample ID:C002460-04 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 11:00 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 79.00
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/10/10 15:03GRO (C6-C10) [ECL-0069] ^50 86 bpk0C090152606500D
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168 %bpkEPA 8015C 03/10/10 15:030C090150.0 9.52 QS-0450
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 8 of 16
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T3-6'Description:Lab Sample ID:C002460-05 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 15:45 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 82.00
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/10/10 15:34GRO (C6-C10) [ECL-0069] ^50 82 bpk0C090152507100D
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168 %bpkEPA 8015C 03/10/10 15:340C090150.0 9.14 QS-0450
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 9 of 16
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T4A-6'Description:Lab Sample ID:C002460-06 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 17:15 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 80.80
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/10/10 16:05GRO (C6-C10) [ECL-0069] ^50 81 bpk0C090152507700D
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168 %bpkEPA 8015C 03/10/10 16:050C090150.0 9.01 QS-0450
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 10 of 16
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T4B-6'Description:Lab Sample ID:C002460-07 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 17:20 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 84.80
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/10/10 16:35GRO (C6-C10) [ECL-0069] ^50 78 bpk0C0901524014000D
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168 %bpkEPA 8015C 03/10/10 16:350C090150.0 8.67 QS-0450
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 11 of 16
www.encolabs.com
T5-4'Description:Lab Sample ID:C002460-08 03/08/10 14:45Received:
Matrix:Soil Sampled:02/25/10 15:50 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 82.60
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/09/10 23:06GRO (C6-C10) [ECL-0069] ^1 1.5 bpk0C090154.725
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168266 %bpkEPA 8015C 03/09/10 23:060C09015238.54 QS-061
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 12 of 16
www.encolabs.com
PL2-3'Description:Lab Sample ID:C002460-09 03/08/10 14:45Received:
Matrix:Soil Sampled:02/26/10 15:55 Work Order:C002460
CARAWAY GROC. 2009311Project:Sampled By:Client % Solids: 77.30
Gasoline Range Organics by GC
^ - ENCO Cary certified analyte [NC 591]
Analyte [CAS Number]DFUnitsResults MDL Method Analyzed ByBatchMRLFlag Notes
mg/kg dry EPA 8015C 03/09/10 23:37GRO (C6-C10) [ECL-0069] ^1 2.0 bpk0C090156.02.9 J
Surrogates Results Spike Lvl % Rec Batch Method Analyzed By% Rec Limits NotesDF
2,5-Dibromotoluene 59-168119 %bpkEPA 8015C 03/09/10 23:370C090151311.0 1
This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 13 of 16
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QUALITY CONTROL
Gasoline Range Organics by GC - Quality Control
Batch 0C09015 - EPA 5035
Prepared: 03/09/2010 12:44 Analyzed: 03/09/2010 13:49Blank (0C09015-BLK1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet4.91.6 U GRO (C6-C10)
mg/kg wet 8.87 59-168Surrogate: 2,5-Dibromotoluene 1069.4
Prepared: 03/09/2010 12:44 Analyzed: 03/09/2010 14:20LCS (0C09015-BS1)
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet5.5 50.0 51-1159145 GRO (C6-C10)
mg/kg wet 10.0 59-168Surrogate: 2,5-Dibromotoluene 12212
Prepared: 03/09/2010 12:44 Analyzed: 03/09/2010 14:51Matrix Spike (0C09015-MS1)
Source: C002321-07
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet5.5 50.0 45-1621041.8 U52 GRO (C6-C10)
mg/kg wet 10.0 59-168Surrogate: 2,5-Dibromotoluene 12412
Prepared: 03/09/2010 12:44 Analyzed: 03/09/2010 15:22Matrix Spike Dup (0C09015-MSD1)
Source: C002321-07
RPD%RECSourceSpike
MRL Analyte Notes LimitRPDLimits%RECResultLevelUnitsResultFlag
mg/kg wet5.5 50.0 2445-162104 0.11.8 U52 GRO (C6-C10)
mg/kg wet 10.0 59-168Surrogate: 2,5-Dibromotoluene 11812
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FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
J The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
ND The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
Surrogate recovery not calculated. Surrogate diluted out of the calibration range.QS-04
Surrogate recovery exceeded acceptance criteria due to coelution. Matrix effect confirmed.QS-06
Page 15 of 16
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Page 16 of 16
March 15, 2010
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 9264404
9264404
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR-UST Section
1637 Mail Service Center
Raleigh, NC 27699
CARAWAY GROC. 2009311
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on March 02, 2010. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Charlotte Certification IDsKentucky UST Certification #: 84Florida/NELAP Certification #: E87627
New Jersey Certification #: NC012North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12Pennsylvania Certification #: 68-00784
South Carolina Certification #: 990060001
South Carolina Drinking Water Cert. #: 990060003Tennessee Certification #: 04010
Virginia Certification #: 00213West Virginia Certification #: 3579800 Kincey Ave. - Ste 100 Huntersville, NC 28078Connecticut Certification #: PH-0104Louisiana/LELAP Certification #: 04034
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9264404001 T1A-8'ASTM D2974-87 1 PASI-CKDF
9264404002 T1B-8'ASTM D2974-87 1 PASI-CKDF
9264404003 T2A-8'ASTM D2974-87 1 PASI-CKDF
9264404004 T2B-8'ASTM D2974-87 1 PASI-CKDF
9264404005 T3-6'ASTM D2974-87 1 PASI-CKDF
9264404006 T4A-6'ASTM D2974-87 1 PASI-CKDF
9264404007 T4B-6'ASTM D2974-87 1 PASI-CKDF
9264404008 T5-4'EPA 8015 Modified 2 PASI-CRES
ASTM D2974-87 1 PASI-CKDF
9264404009 PL1-3'MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404010 PL2-3'ASTM D2974-87 1 PASI-CKDF
9264404011 2KTE-4 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404012 2KTE-5 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404013 2KTE-1 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404014 2KTE-2 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404015 2KTE-3 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404016 T3E-1 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404017 T3E-2 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404018 T3E-3 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
9264404019 T3E-4 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404020 T3E-5 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404021 T4E-1 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404022 T4E-2 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404023 T4E-3 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404024 T4E-4 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404025 T4E-5 MADEP VPH 5 PASI-CDHW
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404026 T5E-1 MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 74 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404027 T5E-2 MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 74 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404028 T5E-3 MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 74 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404029 T5E-4 MADEP EPH 7 PASI-CRES
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
MADEP VPH 5 PASI-CDHW
EPA 8270 74 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404030 T5E-5 MADEP EPH 7 PASI-CRES
MADEP VPH 5 PASI-CDHW
EPA 8270 74 PASI-CPPM
EPA 8260 71 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
9264404031 TRIP BLANK EPA 8260 71 PASI-CDLK
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
EPA 8015 Modified
Date:March 15, 2010
Description:8015 GCS THC-Diesel
General Information:
1 sample was analyzed for EPA 8015 Modified. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3546 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: OEXT/9439
S4: Surrogate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 411956)
• n-Pentacosane (S)
• MSD (Lab ID: 411957)
• n-Pentacosane (S)
• T5-4' (Lab ID: 9264404008)
• n-Pentacosane (S)
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
MADEP EPH
Date:March 15, 2010
Description:MADEP EPH NC Soil
General Information:
5 samples were analyzed for MADEP EPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with MADEP EPH with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: OEXT/9448
S4: Surrogate recovery not evaluated against control limits due to sample dilution.
• T5E-3 (Lab ID: 9264404028)
• 2-Bromonaphthalene (S)
• 2-Fluorobiphenyl (S)
• Nonatriacontane (S)
• o-Terphenyl (S)
• T5E-5 (Lab ID: 9264404030)
• Nonatriacontane (S)
S5: Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).
• T5E-5 (Lab ID: 9264404030)
• 2-Bromonaphthalene (S)
• 2-Fluorobiphenyl (S)
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
MADEP EPH
Date:March 15, 2010
Description:MADEP EPH NC Soil
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
MADEP VPH
Date:March 15, 2010
Description:VPH NC Soil
General Information:
21 samples were analyzed for MADEP VPH. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with MADEP VPH with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: GCV/3891
S5: Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).
• 2KTE-3 (Lab ID: 9264404015)
• 2,5-Dibromotoluene (FID)(S)
QC Batch: GCV/3897
S3: Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples. Resultsunaffected by high bias.
• T3E-4 (Lab ID: 9264404019)
• 2,5-Dibromotoluene (FID)(S)
• T5E-4 (Lab ID: 9264404029)
• 2,5-Dibromotoluene (PID)(S)
S5: Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).
• T3E-5 (Lab ID: 9264404020)
• 2,5-Dibromotoluene (FID)(S)
• T4E-1 (Lab ID: 9264404021)
• 2,5-Dibromotoluene (FID)(S)
• T4E-2 (Lab ID: 9264404022)
• 2,5-Dibromotoluene (FID)(S)
• T5E-3 (Lab ID: 9264404028)
• 2,5-Dibromotoluene (FID)(S)
• T5E-4 (Lab ID: 9264404029)
• 2,5-Dibromotoluene (FID)(S)
• T5E-5 (Lab ID: 9264404030)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
MADEP VPH
Date:March 15, 2010
Description:VPH NC Soil
QC Batch: GCV/3897
S5: Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).
• 2,5-Dibromotoluene (FID)(S)
• 2,5-Dibromotoluene (PID)(S)
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
EPA 8270
Date:March 15, 2010
Description:8270 MSSV Microwave
General Information:
5 samples were analyzed for EPA 8270. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3546 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: OEXT/9440
S4: Surrogate recovery not evaluated against control limits due to sample dilution.
• T5E-1 (Lab ID: 9264404026)
• Nitrobenzene-d5 (S)
• T5E-3 (Lab ID: 9264404028)
• Nitrobenzene-d5 (S)
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: OEXT/9440
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9264642008
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MS (Lab ID: 412002)
• 1,2,4-Trichlorobenzene
• 1,2-Dichlorobenzene
• 1,3-Dichlorobenzene
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
EPA 8270
Date:March 15, 2010
Description:8270 MSSV Microwave
QC Batch: OEXT/9440
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9264642008
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• 1,4-Dichlorobenzene
• 1-Methylnaphthalene
• 2,4,5-Trichlorophenol
• 2,4,6-Trichlorophenol
• 2,4-Dimethylphenol
• 2,4-Dinitrophenol
• 2,4-Dinitrotoluene
• 2-Chloronaphthalene
• 2-Chlorophenol
• 2-Methylnaphthalene
• 2-Methylphenol(o-Cresol)
• 2-Nitroaniline
• 2-Nitrophenol
• 3&4-Methylphenol(m&p Cresol)
• 3-Nitroaniline
• 4-Bromophenylphenyl ether
• 4-Chloroaniline
• 4-Chlorophenylphenyl ether
• 4-Nitroaniline
• 4-Nitrophenol
• Acenaphthene
• Acenaphthylene
• Aniline
• Benzo(a)pyrene
• Benzo(b)fluoranthene
• Benzo(g,h,i)perylene
• Benzoic Acid
• Benzyl alcohol
• Di-n-butylphthalate
• Dibenz(a,h)anthracene
• Dibenzofuran
• Diethylphthalate
• Dimethylphthalate
• Fluoranthene
• Fluorene
• Hexachloro-1,3-butadiene
• Hexachlorocyclopentadiene
• Hexachloroethane
• Indeno(1,2,3-cd)pyrene
• N-Nitrosodimethylamine
• N-Nitrosodiphenylamine
• Naphthalene
• Nitrobenzene
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
EPA 8270
Date:March 15, 2010
Description:8270 MSSV Microwave
QC Batch: OEXT/9440
A matrix spike and matrix spike duplicate (MS/MSD) were performed on the following sample(s): 9264642008
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• Pentachlorophenol
• Phenanthrene
• Phenol
• bis(2-Chloroethoxy)methane
• bis(2-Chloroethyl) ether
• bis(2-Chloroisopropyl) ether
• bis(2-Ethylhexyl)phthalate
• MSD (Lab ID: 412003)
• 2,4,5-Trichlorophenol
• 2,4,6-Trichlorophenol
• 2,4-Dinitrophenol
• 2-Nitroaniline
• 3-Nitroaniline
• 4-Bromophenylphenyl ether
• 4-Chloroaniline
• 4-Chlorophenylphenyl ether
• 4-Nitroaniline
• 4-Nitrophenol
• Acenaphthene
• Aniline
• Benzo(a)pyrene
• Benzo(b)fluoranthene
• Benzo(g,h,i)perylene
• Benzoic Acid
• Di-n-butylphthalate
• Di-n-octylphthalate
• Dibenz(a,h)anthracene
• Dibenzofuran
• Diethylphthalate
• Dimethylphthalate
• Hexachlorocyclopentadiene
• Indeno(1,2,3-cd)pyrene
• N-Nitrosodimethylamine
• N-Nitrosodiphenylamine
• Pentachlorophenol
• Phenanthrene
• bis(2-Chloroisopropyl) ether
• bis(2-Ethylhexyl)phthalate
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
EPA 8270
Date:March 15, 2010
Description:8270 MSSV Microwave
Additional Comments:
Analyte Comments:
QC Batch: OEXT/9440
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• T5E-1 (Lab ID: 9264404026)
• Phenol
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
EPA 8260
Date:March 15, 2010
Description:8260/5035A Volatile Organics
General Information:
22 samples were analyzed for EPA 8260. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: MSV/10160
S2: Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample re-analysis).
• T4E-1 (Lab ID: 9264404021)
• Toluene-d8 (S)
Method Blank:
All analytes were below the report limit in the method blank with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
QC Batch: MSV/10159
L0: Analyte recovery in the laboratory control sample (LCS) was outside QC limits.
• LCS (Lab ID: 410163)
• 1,2,4-Trichlorobenzene
• Vinyl acetate
• n-Butylbenzene
QC Batch: MSV/10160
L0: Analyte recovery in the laboratory control sample (LCS) was outside QC limits.
• LCS (Lab ID: 410169)
• 1,2,4-Trichlorobenzene
• Vinyl acetate
• n-Butylbenzene
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PROJECT NARRATIVE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Method:
Client:Pyramid_FTF
EPA 8260
Date:March 15, 2010
Description:8260/5035A Volatile Organics
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: MSV/10159
C9: Common Laboratory Contaminant.
• T4E-5 (Lab ID: 9264404025)
• Acetone
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• T5E-5 (Lab ID: 9264404030)
• Dichlorodifluoromethane
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• T4E-4 (Lab ID: 9264404024)
• 1,2,4-Trimethylbenzene
QC Batch: MSV/10160
1g: Non homogenous sample.
• T3E-4 (Lab ID: 9264404019)
• Dichlorodifluoromethane
C9: Common Laboratory Contaminant.
• 2KTE-2 (Lab ID: 9264404014)
• Acetone
• T3E-4 (Lab ID: 9264404019)
• Acetone
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• T3E-4 (Lab ID: 9264404019)
• 1,2,4-Trimethylbenzene
• 1,3,5-Trimethylbenzene
• Ethylbenzene
• m&p-Xylene
• Naphthalene
• n-Propylbenzene
• o-Xylene
• Toluene
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T1A-8'Lab ID:9264404001 Collected:02/25/10 10:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 13.4 %1 03/03/10 14:000.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 17 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T1B-8'Lab ID:9264404002 Collected:02/25/10 10:50 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 17.7 %1 03/03/10 14:000.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 18 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T2A-8'Lab ID:9264404003 Collected:02/25/10 10:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 20.6 %1 03/03/10 14:000.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 19 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T2B-8'Lab ID:9264404004 Collected:02/25/10 11:00 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 21.0 %1 03/03/10 14:010.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 20 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3-6'Lab ID:9264404005 Collected:02/25/10 15:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 18.0 %1 03/03/10 14:010.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 21 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4A-6'Lab ID:9264404006 Collected:02/25/10 17:15 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 19.2 %1 03/03/10 14:010.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 22 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4B-6'Lab ID:9264404007 Collected:02/25/10 17:20 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 15.2 %1 03/03/10 14:010.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 23 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5-4'Lab ID:9264404008 Collected:02/25/10 15:50 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8015 GCS THC-Diesel Analytical Method: EPA 8015 Modified Preparation Method: EPA 3546
Diesel Components 1220 mg/kg 5 03/11/10 11:14 68334-30-503/08/10 09:0030.3
n-Pentacosane (S)0 %5 03/11/10 11:14 629-99-2 S403/08/10 09:0050-135
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 17.4 %1 03/03/10 14:020.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 24 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:PL1-3'Lab ID:9264404009 Collected:02/26/10 15:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 17:0303/12/10 15:199.8
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 17:0303/12/10 15:199.8
Aromatic (C09-C10)ND mg/kg 1 03/13/10 17:0303/12/10 15:199.8
2,5-Dibromotoluene (PID)(S)103 %1 03/13/10 17:0303/12/10 15:1970-130
2,5-Dibromotoluene (FID)(S)109 %1 03/13/10 17:0303/12/10 15:1970-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/04/10 20:24 67-64-1103
Benzene ND ug/kg 1 03/04/10 20:24 71-43-25.1
Bromobenzene ND ug/kg 1 03/04/10 20:24 108-86-15.1
Bromochloromethane ND ug/kg 1 03/04/10 20:24 74-97-55.1
Bromodichloromethane ND ug/kg 1 03/04/10 20:24 75-27-45.1
Bromoform ND ug/kg 1 03/04/10 20:24 75-25-25.1
Bromomethane ND ug/kg 1 03/04/10 20:24 74-83-910.3
2-Butanone (MEK)ND ug/kg 1 03/04/10 20:24 78-93-3103
n-Butylbenzene ND ug/kg 1 03/04/10 20:24 104-51-85.1
sec-Butylbenzene ND ug/kg 1 03/04/10 20:24 135-98-85.1
tert-Butylbenzene ND ug/kg 1 03/04/10 20:24 98-06-65.1
Carbon tetrachloride ND ug/kg 1 03/04/10 20:24 56-23-55.1
Chlorobenzene ND ug/kg 1 03/04/10 20:24 108-90-75.1
Chloroethane ND ug/kg 1 03/04/10 20:24 75-00-310.3
Chloroform ND ug/kg 1 03/04/10 20:24 67-66-35.1
Chloromethane ND ug/kg 1 03/04/10 20:24 74-87-310.3
2-Chlorotoluene ND ug/kg 1 03/04/10 20:24 95-49-85.1
4-Chlorotoluene ND ug/kg 1 03/04/10 20:24 106-43-45.1
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/04/10 20:24 96-12-85.1
Dibromochloromethane ND ug/kg 1 03/04/10 20:24 124-48-15.1
1,2-Dibromoethane (EDB)ND ug/kg 1 03/04/10 20:24 106-93-45.1
Dibromomethane ND ug/kg 1 03/04/10 20:24 74-95-35.1
1,2-Dichlorobenzene ND ug/kg 1 03/04/10 20:24 95-50-15.1
1,3-Dichlorobenzene ND ug/kg 1 03/04/10 20:24 541-73-15.1
1,4-Dichlorobenzene ND ug/kg 1 03/04/10 20:24 106-46-75.1
Dichlorodifluoromethane ND ug/kg 1 03/04/10 20:24 75-71-810.3
1,1-Dichloroethane ND ug/kg 1 03/04/10 20:24 75-34-35.1
1,2-Dichloroethane ND ug/kg 1 03/04/10 20:24 107-06-25.1
1,1-Dichloroethene ND ug/kg 1 03/04/10 20:24 75-35-45.1
cis-1,2-Dichloroethene ND ug/kg 1 03/04/10 20:24 156-59-25.1
trans-1,2-Dichloroethene ND ug/kg 1 03/04/10 20:24 156-60-55.1
1,2-Dichloropropane ND ug/kg 1 03/04/10 20:24 78-87-55.1
1,3-Dichloropropane ND ug/kg 1 03/04/10 20:24 142-28-95.1
2,2-Dichloropropane ND ug/kg 1 03/04/10 20:24 594-20-75.1
1,1-Dichloropropene ND ug/kg 1 03/04/10 20:24 563-58-65.1
cis-1,3-Dichloropropene ND ug/kg 1 03/04/10 20:24 10061-01-55.1
trans-1,3-Dichloropropene ND ug/kg 1 03/04/10 20:24 10061-02-65.1
Diisopropyl ether ND ug/kg 1 03/04/10 20:24 108-20-35.1
Ethylbenzene ND ug/kg 1 03/04/10 20:24 100-41-45.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 25 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:PL1-3'Lab ID:9264404009 Collected:02/26/10 15:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/04/10 20:24 87-68-35.1
2-Hexanone ND ug/kg 1 03/04/10 20:24 591-78-651.3
Isopropylbenzene (Cumene)ND ug/kg 1 03/04/10 20:24 98-82-85.1
p-Isopropyltoluene ND ug/kg 1 03/04/10 20:24 99-87-65.1
Methylene Chloride ND ug/kg 1 03/04/10 20:24 75-09-220.5
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/04/10 20:24 108-10-151.3
Methyl-tert-butyl ether ND ug/kg 1 03/04/10 20:24 1634-04-45.1
Naphthalene ND ug/kg 1 03/04/10 20:24 91-20-35.1
n-Propylbenzene ND ug/kg 1 03/04/10 20:24 103-65-15.1
Styrene ND ug/kg 1 03/04/10 20:24 100-42-55.1
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/04/10 20:24 630-20-65.1
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/04/10 20:24 79-34-55.1
Tetrachloroethene ND ug/kg 1 03/04/10 20:24 127-18-45.1
Toluene ND ug/kg 1 03/04/10 20:24 108-88-35.1
1,2,3-Trichlorobenzene ND ug/kg 1 03/04/10 20:24 87-61-65.1
1,2,4-Trichlorobenzene ND ug/kg 1 03/04/10 20:24 120-82-15.1
1,1,1-Trichloroethane ND ug/kg 1 03/04/10 20:24 71-55-65.1
1,1,2-Trichloroethane ND ug/kg 1 03/04/10 20:24 79-00-55.1
Trichloroethene ND ug/kg 1 03/04/10 20:24 79-01-65.1
Trichlorofluoromethane ND ug/kg 1 03/04/10 20:24 75-69-45.1
1,2,3-Trichloropropane ND ug/kg 1 03/04/10 20:24 96-18-45.1
1,2,4-Trimethylbenzene 9.1 ug/kg 1 03/04/10 20:24 95-63-65.1
1,3,5-Trimethylbenzene ND ug/kg 1 03/04/10 20:24 108-67-85.1
Vinyl acetate ND ug/kg 1 03/04/10 20:24 108-05-451.3
Vinyl chloride ND ug/kg 1 03/04/10 20:24 75-01-410.3
Xylene (Total)19.3 ug/kg 1 03/04/10 20:24 1330-20-710.3
m&p-Xylene 11.7 ug/kg 1 03/04/10 20:24 1330-20-710.3
o-Xylene 7.6 ug/kg 1 03/04/10 20:24 95-47-65.1
Dibromofluoromethane (S)96 %1 03/04/10 20:24 1868-53-779-116
Toluene-d8 (S)102 %1 03/04/10 20:24 2037-26-588-110
4-Bromofluorobenzene (S)100 %1 03/04/10 20:24 460-00-474-115
1,2-Dichloroethane-d4 (S)111 %1 03/04/10 20:24 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 23.0 %1 03/03/10 14:030.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 26 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:PL2-3'Lab ID:9264404010 Collected:02/26/10 15:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 22.7 %1 03/03/10 14:040.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 27 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-4 Lab ID:9264404011 Collected:02/25/10 13:20 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 17:2803/12/10 15:198.5
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 17:2803/12/10 15:198.5
Aromatic (C09-C10)ND mg/kg 1 03/13/10 17:2803/12/10 15:198.5
2,5-Dibromotoluene (PID)(S)113 %1 03/13/10 17:2803/12/10 15:1970-130
2,5-Dibromotoluene (FID)(S)118 %1 03/13/10 17:2803/12/10 15:1970-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/04/10 20:43 67-64-187.2
Benzene ND ug/kg 1 03/04/10 20:43 71-43-24.4
Bromobenzene ND ug/kg 1 03/04/10 20:43 108-86-14.4
Bromochloromethane ND ug/kg 1 03/04/10 20:43 74-97-54.4
Bromodichloromethane ND ug/kg 1 03/04/10 20:43 75-27-44.4
Bromoform ND ug/kg 1 03/04/10 20:43 75-25-24.4
Bromomethane ND ug/kg 1 03/04/10 20:43 74-83-98.7
2-Butanone (MEK)ND ug/kg 1 03/04/10 20:43 78-93-387.2
n-Butylbenzene ND ug/kg 1 03/04/10 20:43 104-51-84.4
sec-Butylbenzene ND ug/kg 1 03/04/10 20:43 135-98-84.4
tert-Butylbenzene ND ug/kg 1 03/04/10 20:43 98-06-64.4
Carbon tetrachloride ND ug/kg 1 03/04/10 20:43 56-23-54.4
Chlorobenzene ND ug/kg 1 03/04/10 20:43 108-90-74.4
Chloroethane ND ug/kg 1 03/04/10 20:43 75-00-38.7
Chloroform ND ug/kg 1 03/04/10 20:43 67-66-34.4
Chloromethane ND ug/kg 1 03/04/10 20:43 74-87-38.7
2-Chlorotoluene ND ug/kg 1 03/04/10 20:43 95-49-84.4
4-Chlorotoluene ND ug/kg 1 03/04/10 20:43 106-43-44.4
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/04/10 20:43 96-12-84.4
Dibromochloromethane ND ug/kg 1 03/04/10 20:43 124-48-14.4
1,2-Dibromoethane (EDB)ND ug/kg 1 03/04/10 20:43 106-93-44.4
Dibromomethane ND ug/kg 1 03/04/10 20:43 74-95-34.4
1,2-Dichlorobenzene ND ug/kg 1 03/04/10 20:43 95-50-14.4
1,3-Dichlorobenzene ND ug/kg 1 03/04/10 20:43 541-73-14.4
1,4-Dichlorobenzene ND ug/kg 1 03/04/10 20:43 106-46-74.4
Dichlorodifluoromethane ND ug/kg 1 03/04/10 20:43 75-71-88.7
1,1-Dichloroethane ND ug/kg 1 03/04/10 20:43 75-34-34.4
1,2-Dichloroethane ND ug/kg 1 03/04/10 20:43 107-06-24.4
1,1-Dichloroethene ND ug/kg 1 03/04/10 20:43 75-35-44.4
cis-1,2-Dichloroethene ND ug/kg 1 03/04/10 20:43 156-59-24.4
trans-1,2-Dichloroethene ND ug/kg 1 03/04/10 20:43 156-60-54.4
1,2-Dichloropropane ND ug/kg 1 03/04/10 20:43 78-87-54.4
1,3-Dichloropropane ND ug/kg 1 03/04/10 20:43 142-28-94.4
2,2-Dichloropropane ND ug/kg 1 03/04/10 20:43 594-20-74.4
1,1-Dichloropropene ND ug/kg 1 03/04/10 20:43 563-58-64.4
cis-1,3-Dichloropropene ND ug/kg 1 03/04/10 20:43 10061-01-54.4
trans-1,3-Dichloropropene ND ug/kg 1 03/04/10 20:43 10061-02-64.4
Diisopropyl ether ND ug/kg 1 03/04/10 20:43 108-20-34.4
Ethylbenzene 5.3 ug/kg 1 03/04/10 20:43 100-41-44.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 28 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-4 Lab ID:9264404011 Collected:02/25/10 13:20 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/04/10 20:43 87-68-34.4
2-Hexanone ND ug/kg 1 03/04/10 20:43 591-78-643.6
Isopropylbenzene (Cumene)ND ug/kg 1 03/04/10 20:43 98-82-84.4
p-Isopropyltoluene ND ug/kg 1 03/04/10 20:43 99-87-64.4
Methylene Chloride ND ug/kg 1 03/04/10 20:43 75-09-217.4
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/04/10 20:43 108-10-143.6
Methyl-tert-butyl ether ND ug/kg 1 03/04/10 20:43 1634-04-44.4
Naphthalene 13.5 ug/kg 1 03/04/10 20:43 91-20-34.4
n-Propylbenzene ND ug/kg 1 03/04/10 20:43 103-65-14.4
Styrene ND ug/kg 1 03/04/10 20:43 100-42-54.4
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/04/10 20:43 630-20-64.4
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/04/10 20:43 79-34-54.4
Tetrachloroethene ND ug/kg 1 03/04/10 20:43 127-18-44.4
Toluene 17.5 ug/kg 1 03/04/10 20:43 108-88-34.4
1,2,3-Trichlorobenzene ND ug/kg 1 03/04/10 20:43 87-61-64.4
1,2,4-Trichlorobenzene ND ug/kg 1 03/04/10 20:43 120-82-14.4
1,1,1-Trichloroethane ND ug/kg 1 03/04/10 20:43 71-55-64.4
1,1,2-Trichloroethane ND ug/kg 1 03/04/10 20:43 79-00-54.4
Trichloroethene ND ug/kg 1 03/04/10 20:43 79-01-64.4
Trichlorofluoromethane ND ug/kg 1 03/04/10 20:43 75-69-44.4
1,2,3-Trichloropropane ND ug/kg 1 03/04/10 20:43 96-18-44.4
1,2,4-Trimethylbenzene 15.6 ug/kg 1 03/04/10 20:43 95-63-64.4
1,3,5-Trimethylbenzene ND ug/kg 1 03/04/10 20:43 108-67-84.4
Vinyl acetate ND ug/kg 1 03/04/10 20:43 108-05-443.6
Vinyl chloride ND ug/kg 1 03/04/10 20:43 75-01-48.7
Xylene (Total)31.8 ug/kg 1 03/04/10 20:43 1330-20-78.7
m&p-Xylene 19.5 ug/kg 1 03/04/10 20:43 1330-20-78.7
o-Xylene 12.3 ug/kg 1 03/04/10 20:43 95-47-64.4
Dibromofluoromethane (S)95 %1 03/04/10 20:43 1868-53-779-116
Toluene-d8 (S)100 %1 03/04/10 20:43 2037-26-588-110
4-Bromofluorobenzene (S)101 %1 03/04/10 20:43 460-00-474-115
1,2-Dichloroethane-d4 (S)104 %1 03/04/10 20:43 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 14.8 %1 03/03/10 14:040.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 29 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-5 Lab ID:9264404012 Collected:02/25/10 14:30 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)22.3 mg/kg 1 03/13/10 17:5303/12/10 15:198.7
Aliphatic (C09-C12)37.5 mg/kg 1 03/13/10 17:5303/12/10 15:198.7
Aromatic (C09-C10)11.4 mg/kg 1 03/13/10 17:5303/12/10 15:198.7
2,5-Dibromotoluene (PID)(S)114 %1 03/13/10 17:5303/12/10 15:1970-130
2,5-Dibromotoluene (FID)(S)128 %1 03/13/10 17:5303/12/10 15:1970-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 100 03/04/10 00:00 67-64-18910
Benzene ND ug/kg 100 03/04/10 00:00 71-43-2445
Bromobenzene ND ug/kg 100 03/04/10 00:00 108-86-1445
Bromochloromethane ND ug/kg 100 03/04/10 00:00 74-97-5445
Bromodichloromethane ND ug/kg 100 03/04/10 00:00 75-27-4445
Bromoform ND ug/kg 100 03/04/10 00:00 75-25-2445
Bromomethane ND ug/kg 100 03/04/10 00:00 74-83-9891
2-Butanone (MEK)ND ug/kg 100 03/04/10 00:00 78-93-38910
n-Butylbenzene 1160 ug/kg 100 03/04/10 00:00 104-51-8445
sec-Butylbenzene ND ug/kg 100 03/04/10 00:00 135-98-8445
tert-Butylbenzene ND ug/kg 100 03/04/10 00:00 98-06-6445
Carbon tetrachloride ND ug/kg 100 03/04/10 00:00 56-23-5445
Chlorobenzene ND ug/kg 100 03/04/10 00:00 108-90-7445
Chloroethane ND ug/kg 100 03/04/10 00:00 75-00-3891
Chloroform ND ug/kg 100 03/04/10 00:00 67-66-3445
Chloromethane ND ug/kg 100 03/04/10 00:00 74-87-3891
2-Chlorotoluene ND ug/kg 100 03/04/10 00:00 95-49-8445
4-Chlorotoluene ND ug/kg 100 03/04/10 00:00 106-43-4445
1,2-Dibromo-3-chloropropane ND ug/kg 100 03/04/10 00:00 96-12-8445
Dibromochloromethane ND ug/kg 100 03/04/10 00:00 124-48-1445
1,2-Dibromoethane (EDB)ND ug/kg 100 03/04/10 00:00 106-93-4445
Dibromomethane ND ug/kg 100 03/04/10 00:00 74-95-3445
1,2-Dichlorobenzene ND ug/kg 100 03/04/10 00:00 95-50-1445
1,3-Dichlorobenzene ND ug/kg 100 03/04/10 00:00 541-73-1445
1,4-Dichlorobenzene ND ug/kg 100 03/04/10 00:00 106-46-7445
Dichlorodifluoromethane ND ug/kg 100 03/04/10 00:00 75-71-8891
1,1-Dichloroethane ND ug/kg 100 03/04/10 00:00 75-34-3445
1,2-Dichloroethane ND ug/kg 100 03/04/10 00:00 107-06-2445
1,1-Dichloroethene ND ug/kg 100 03/04/10 00:00 75-35-4445
cis-1,2-Dichloroethene ND ug/kg 100 03/04/10 00:00 156-59-2445
trans-1,2-Dichloroethene ND ug/kg 100 03/04/10 00:00 156-60-5445
1,2-Dichloropropane ND ug/kg 100 03/04/10 00:00 78-87-5445
1,3-Dichloropropane ND ug/kg 100 03/04/10 00:00 142-28-9445
2,2-Dichloropropane ND ug/kg 100 03/04/10 00:00 594-20-7445
1,1-Dichloropropene ND ug/kg 100 03/04/10 00:00 563-58-6445
cis-1,3-Dichloropropene ND ug/kg 100 03/04/10 00:00 10061-01-5445
trans-1,3-Dichloropropene ND ug/kg 100 03/04/10 00:00 10061-02-6445
Diisopropyl ether ND ug/kg 100 03/04/10 00:00 108-20-3445
Ethylbenzene 1620 ug/kg 100 03/04/10 00:00 100-41-4445
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 30 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-5 Lab ID:9264404012 Collected:02/25/10 14:30 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 100 03/04/10 00:00 87-68-3445
2-Hexanone ND ug/kg 100 03/04/10 00:00 591-78-64450
Isopropylbenzene (Cumene)668 ug/kg 100 03/04/10 00:00 98-82-8445
p-Isopropyltoluene 703 ug/kg 100 03/04/10 00:00 99-87-6445
Methylene Chloride ND ug/kg 100 03/04/10 00:00 75-09-21780
4-Methyl-2-pentanone (MIBK)ND ug/kg 100 03/04/10 00:00 108-10-14450
Methyl-tert-butyl ether ND ug/kg 100 03/04/10 00:00 1634-04-4445
Naphthalene 2200 ug/kg 100 03/04/10 00:00 91-20-3445
n-Propylbenzene 1540 ug/kg 100 03/04/10 00:00 103-65-1445
Styrene 469 ug/kg 100 03/04/10 00:00 100-42-5445
1,1,1,2-Tetrachloroethane ND ug/kg 100 03/04/10 00:00 630-20-6445
1,1,2,2-Tetrachloroethane ND ug/kg 100 03/04/10 00:00 79-34-5445
Tetrachloroethene ND ug/kg 100 03/04/10 00:00 127-18-4445
Toluene 1780 ug/kg 100 03/04/10 00:00 108-88-3445
1,2,3-Trichlorobenzene ND ug/kg 100 03/04/10 00:00 87-61-6445
1,2,4-Trichlorobenzene ND ug/kg 100 03/04/10 00:00 120-82-1445
1,1,1-Trichloroethane ND ug/kg 100 03/04/10 00:00 71-55-6445
1,1,2-Trichloroethane ND ug/kg 100 03/04/10 00:00 79-00-5445
Trichloroethene ND ug/kg 100 03/04/10 00:00 79-01-6445
Trichlorofluoromethane ND ug/kg 100 03/04/10 00:00 75-69-4445
1,2,3-Trichloropropane ND ug/kg 100 03/04/10 00:00 96-18-4445
1,2,4-Trimethylbenzene 8710 ug/kg 100 03/04/10 00:00 95-63-6445
1,3,5-Trimethylbenzene 2780 ug/kg 100 03/04/10 00:00 108-67-8445
Vinyl acetate ND ug/kg 100 03/04/10 00:00 108-05-44450
Vinyl chloride ND ug/kg 100 03/04/10 00:00 75-01-4891
Xylene (Total)8200 ug/kg 100 03/04/10 00:00 1330-20-7891
m&p-Xylene 5770 ug/kg 100 03/04/10 00:00 1330-20-7891
o-Xylene 2430 ug/kg 100 03/04/10 00:00 95-47-6445
Dibromofluoromethane (S)93 %100 03/04/10 00:00 1868-53-779-116
Toluene-d8 (S)102 %100 03/04/10 00:00 2037-26-588-110
4-Bromofluorobenzene (S)99 %100 03/04/10 00:00 460-00-474-115
1,2-Dichloroethane-d4 (S)101 %100 03/04/10 00:00 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 12.3 %1 03/03/10 14:050.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 31 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-1 Lab ID:9264404013 Collected:02/25/10 14:15 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 18:1703/12/10 15:198.9
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 18:1703/12/10 15:198.9
Aromatic (C09-C10)ND mg/kg 1 03/13/10 18:1703/12/10 15:198.9
2,5-Dibromotoluene (PID)(S)99 %1 03/13/10 18:1703/12/10 15:1970-130
2,5-Dibromotoluene (FID)(S)110 %1 03/13/10 18:1703/12/10 15:1970-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/04/10 18:16 67-64-188.9
Benzene ND ug/kg 1 03/04/10 18:16 71-43-24.4
Bromobenzene ND ug/kg 1 03/04/10 18:16 108-86-14.4
Bromochloromethane ND ug/kg 1 03/04/10 18:16 74-97-54.4
Bromodichloromethane ND ug/kg 1 03/04/10 18:16 75-27-44.4
Bromoform ND ug/kg 1 03/04/10 18:16 75-25-24.4
Bromomethane ND ug/kg 1 03/04/10 18:16 74-83-98.9
2-Butanone (MEK)ND ug/kg 1 03/04/10 18:16 78-93-388.9
n-Butylbenzene ND ug/kg 1 03/04/10 18:16 104-51-84.4
sec-Butylbenzene ND ug/kg 1 03/04/10 18:16 135-98-84.4
tert-Butylbenzene ND ug/kg 1 03/04/10 18:16 98-06-64.4
Carbon tetrachloride ND ug/kg 1 03/04/10 18:16 56-23-54.4
Chlorobenzene ND ug/kg 1 03/04/10 18:16 108-90-74.4
Chloroethane ND ug/kg 1 03/04/10 18:16 75-00-38.9
Chloroform ND ug/kg 1 03/04/10 18:16 67-66-34.4
Chloromethane ND ug/kg 1 03/04/10 18:16 74-87-38.9
2-Chlorotoluene ND ug/kg 1 03/04/10 18:16 95-49-84.4
4-Chlorotoluene ND ug/kg 1 03/04/10 18:16 106-43-44.4
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/04/10 18:16 96-12-84.4
Dibromochloromethane ND ug/kg 1 03/04/10 18:16 124-48-14.4
1,2-Dibromoethane (EDB)ND ug/kg 1 03/04/10 18:16 106-93-44.4
Dibromomethane ND ug/kg 1 03/04/10 18:16 74-95-34.4
1,2-Dichlorobenzene ND ug/kg 1 03/04/10 18:16 95-50-14.4
1,3-Dichlorobenzene ND ug/kg 1 03/04/10 18:16 541-73-14.4
1,4-Dichlorobenzene ND ug/kg 1 03/04/10 18:16 106-46-74.4
Dichlorodifluoromethane ND ug/kg 1 03/04/10 18:16 75-71-88.9
1,1-Dichloroethane ND ug/kg 1 03/04/10 18:16 75-34-34.4
1,2-Dichloroethane ND ug/kg 1 03/04/10 18:16 107-06-24.4
1,1-Dichloroethene ND ug/kg 1 03/04/10 18:16 75-35-44.4
cis-1,2-Dichloroethene ND ug/kg 1 03/04/10 18:16 156-59-24.4
trans-1,2-Dichloroethene ND ug/kg 1 03/04/10 18:16 156-60-54.4
1,2-Dichloropropane ND ug/kg 1 03/04/10 18:16 78-87-54.4
1,3-Dichloropropane ND ug/kg 1 03/04/10 18:16 142-28-94.4
2,2-Dichloropropane ND ug/kg 1 03/04/10 18:16 594-20-74.4
1,1-Dichloropropene ND ug/kg 1 03/04/10 18:16 563-58-64.4
cis-1,3-Dichloropropene ND ug/kg 1 03/04/10 18:16 10061-01-54.4
trans-1,3-Dichloropropene ND ug/kg 1 03/04/10 18:16 10061-02-64.4
Diisopropyl ether ND ug/kg 1 03/04/10 18:16 108-20-34.4
Ethylbenzene ND ug/kg 1 03/04/10 18:16 100-41-44.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 32 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-1 Lab ID:9264404013 Collected:02/25/10 14:15 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/04/10 18:16 87-68-34.4
2-Hexanone ND ug/kg 1 03/04/10 18:16 591-78-644.4
Isopropylbenzene (Cumene)ND ug/kg 1 03/04/10 18:16 98-82-84.4
p-Isopropyltoluene ND ug/kg 1 03/04/10 18:16 99-87-64.4
Methylene Chloride ND ug/kg 1 03/04/10 18:16 75-09-217.8
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/04/10 18:16 108-10-144.4
Methyl-tert-butyl ether ND ug/kg 1 03/04/10 18:16 1634-04-44.4
Naphthalene 5.2 ug/kg 1 03/04/10 18:16 91-20-34.4
n-Propylbenzene ND ug/kg 1 03/04/10 18:16 103-65-14.4
Styrene ND ug/kg 1 03/04/10 18:16 100-42-54.4
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/04/10 18:16 630-20-64.4
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/04/10 18:16 79-34-54.4
Tetrachloroethene ND ug/kg 1 03/04/10 18:16 127-18-44.4
Toluene ND ug/kg 1 03/04/10 18:16 108-88-34.4
1,2,3-Trichlorobenzene ND ug/kg 1 03/04/10 18:16 87-61-64.4
1,2,4-Trichlorobenzene ND ug/kg 1 03/04/10 18:16 120-82-14.4
1,1,1-Trichloroethane ND ug/kg 1 03/04/10 18:16 71-55-64.4
1,1,2-Trichloroethane ND ug/kg 1 03/04/10 18:16 79-00-54.4
Trichloroethene ND ug/kg 1 03/04/10 18:16 79-01-64.4
Trichlorofluoromethane ND ug/kg 1 03/04/10 18:16 75-69-44.4
1,2,3-Trichloropropane ND ug/kg 1 03/04/10 18:16 96-18-44.4
1,2,4-Trimethylbenzene ND ug/kg 1 03/04/10 18:16 95-63-64.4
1,3,5-Trimethylbenzene ND ug/kg 1 03/04/10 18:16 108-67-84.4
Vinyl acetate ND ug/kg 1 03/04/10 18:16 108-05-444.4
Vinyl chloride ND ug/kg 1 03/04/10 18:16 75-01-48.9
Xylene (Total)ND ug/kg 1 03/04/10 18:16 1330-20-78.9
m&p-Xylene ND ug/kg 1 03/04/10 18:16 1330-20-78.9
o-Xylene ND ug/kg 1 03/04/10 18:16 95-47-64.4
Dibromofluoromethane (S)94 %1 03/04/10 18:16 1868-53-779-116
Toluene-d8 (S)102 %1 03/04/10 18:16 2037-26-588-110
4-Bromofluorobenzene (S)101 %1 03/04/10 18:16 460-00-474-115
1,2-Dichloroethane-d4 (S)107 %1 03/04/10 18:16 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 16.1 %1 03/03/10 14:050.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 33 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-2 Lab ID:9264404014 Collected:02/25/10 13:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 18:4203/12/10 15:198.8
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 18:4203/12/10 15:198.8
Aromatic (C09-C10)ND mg/kg 1 03/13/10 18:4203/12/10 15:198.8
2,5-Dibromotoluene (PID)(S)103 %1 03/13/10 18:4203/12/10 15:1970-130
2,5-Dibromotoluene (FID)(S)108 %1 03/13/10 18:4203/12/10 15:1970-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone 164 ug/kg 1 03/08/10 13:21 67-64-1 C990.9
Benzene ND ug/kg 1 03/08/10 13:21 71-43-24.5
Bromobenzene ND ug/kg 1 03/08/10 13:21 108-86-14.5
Bromochloromethane ND ug/kg 1 03/08/10 13:21 74-97-54.5
Bromodichloromethane ND ug/kg 1 03/08/10 13:21 75-27-44.5
Bromoform ND ug/kg 1 03/08/10 13:21 75-25-24.5
Bromomethane ND ug/kg 1 03/08/10 13:21 74-83-99.1
2-Butanone (MEK)ND ug/kg 1 03/08/10 13:21 78-93-390.9
n-Butylbenzene ND ug/kg 1 03/08/10 13:21 104-51-84.5
sec-Butylbenzene ND ug/kg 1 03/08/10 13:21 135-98-84.5
tert-Butylbenzene ND ug/kg 1 03/08/10 13:21 98-06-64.5
Carbon tetrachloride ND ug/kg 1 03/08/10 13:21 56-23-54.5
Chlorobenzene ND ug/kg 1 03/08/10 13:21 108-90-74.5
Chloroethane ND ug/kg 1 03/08/10 13:21 75-00-39.1
Chloroform ND ug/kg 1 03/08/10 13:21 67-66-34.5
Chloromethane ND ug/kg 1 03/08/10 13:21 74-87-39.1
2-Chlorotoluene ND ug/kg 1 03/08/10 13:21 95-49-84.5
4-Chlorotoluene ND ug/kg 1 03/08/10 13:21 106-43-44.5
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/08/10 13:21 96-12-84.5
Dibromochloromethane ND ug/kg 1 03/08/10 13:21 124-48-14.5
1,2-Dibromoethane (EDB)ND ug/kg 1 03/08/10 13:21 106-93-44.5
Dibromomethane ND ug/kg 1 03/08/10 13:21 74-95-34.5
1,2-Dichlorobenzene ND ug/kg 1 03/08/10 13:21 95-50-14.5
1,3-Dichlorobenzene ND ug/kg 1 03/08/10 13:21 541-73-14.5
1,4-Dichlorobenzene ND ug/kg 1 03/08/10 13:21 106-46-74.5
Dichlorodifluoromethane ND ug/kg 1 03/08/10 13:21 75-71-89.1
1,1-Dichloroethane ND ug/kg 1 03/08/10 13:21 75-34-34.5
1,2-Dichloroethane ND ug/kg 1 03/08/10 13:21 107-06-24.5
1,1-Dichloroethene ND ug/kg 1 03/08/10 13:21 75-35-44.5
cis-1,2-Dichloroethene ND ug/kg 1 03/08/10 13:21 156-59-24.5
trans-1,2-Dichloroethene ND ug/kg 1 03/08/10 13:21 156-60-54.5
1,2-Dichloropropane ND ug/kg 1 03/08/10 13:21 78-87-54.5
1,3-Dichloropropane ND ug/kg 1 03/08/10 13:21 142-28-94.5
2,2-Dichloropropane ND ug/kg 1 03/08/10 13:21 594-20-74.5
1,1-Dichloropropene ND ug/kg 1 03/08/10 13:21 563-58-64.5
cis-1,3-Dichloropropene ND ug/kg 1 03/08/10 13:21 10061-01-54.5
trans-1,3-Dichloropropene ND ug/kg 1 03/08/10 13:21 10061-02-64.5
Diisopropyl ether ND ug/kg 1 03/08/10 13:21 108-20-34.5
Ethylbenzene ND ug/kg 1 03/08/10 13:21 100-41-44.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 34 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-2 Lab ID:9264404014 Collected:02/25/10 13:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/08/10 13:21 87-68-34.5
2-Hexanone ND ug/kg 1 03/08/10 13:21 591-78-645.4
Isopropylbenzene (Cumene)ND ug/kg 1 03/08/10 13:21 98-82-84.5
p-Isopropyltoluene ND ug/kg 1 03/08/10 13:21 99-87-64.5
Methylene Chloride ND ug/kg 1 03/08/10 13:21 75-09-218.2
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/08/10 13:21 108-10-145.4
Methyl-tert-butyl ether ND ug/kg 1 03/08/10 13:21 1634-04-44.5
Naphthalene 11.6 ug/kg 1 03/08/10 13:21 91-20-34.5
n-Propylbenzene ND ug/kg 1 03/08/10 13:21 103-65-14.5
Styrene ND ug/kg 1 03/08/10 13:21 100-42-54.5
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/08/10 13:21 630-20-64.5
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/08/10 13:21 79-34-54.5
Tetrachloroethene ND ug/kg 1 03/08/10 13:21 127-18-44.5
Toluene ND ug/kg 1 03/08/10 13:21 108-88-34.5
1,2,3-Trichlorobenzene ND ug/kg 1 03/08/10 13:21 87-61-64.5
1,2,4-Trichlorobenzene ND ug/kg 1 03/08/10 13:21 120-82-14.5
1,1,1-Trichloroethane ND ug/kg 1 03/08/10 13:21 71-55-64.5
1,1,2-Trichloroethane ND ug/kg 1 03/08/10 13:21 79-00-54.5
Trichloroethene ND ug/kg 1 03/08/10 13:21 79-01-64.5
Trichlorofluoromethane ND ug/kg 1 03/08/10 13:21 75-69-44.5
1,2,3-Trichloropropane ND ug/kg 1 03/08/10 13:21 96-18-44.5
1,2,4-Trimethylbenzene 16.7 ug/kg 1 03/08/10 13:21 95-63-64.5
1,3,5-Trimethylbenzene 4.9 ug/kg 1 03/08/10 13:21 108-67-84.5
Vinyl acetate ND ug/kg 1 03/08/10 13:21 108-05-445.4
Vinyl chloride ND ug/kg 1 03/08/10 13:21 75-01-49.1
Xylene (Total)19.3 ug/kg 1 03/08/10 13:21 1330-20-79.1
m&p-Xylene 11.3 ug/kg 1 03/08/10 13:21 1330-20-79.1
o-Xylene 8.0 ug/kg 1 03/08/10 13:21 95-47-64.5
Dibromofluoromethane (S)100 %1 03/08/10 13:21 1868-53-779-116
Toluene-d8 (S)102 %1 03/08/10 13:21 2037-26-588-110
4-Bromofluorobenzene (S)96 %1 03/08/10 13:21 460-00-474-115
1,2-Dichloroethane-d4 (S)109 %1 03/08/10 13:21 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 12.0 %1 03/03/10 14:050.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 35 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-3 Lab ID:9264404015 Collected:02/25/10 13:05 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)16.7 mg/kg 1 03/13/10 19:0703/12/10 15:199.1
Aliphatic (C09-C12)96.5 mg/kg 1 03/13/10 19:0703/12/10 15:199.1
Aromatic (C09-C10)34.7 mg/kg 1 03/13/10 19:0703/12/10 15:199.1
2,5-Dibromotoluene (PID)(S)116 %1 03/13/10 19:0703/12/10 15:1970-130
2,5-Dibromotoluene (FID)(S)133 %1 03/13/10 19:07 S503/12/10 15:1970-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 100 03/04/10 19:11 67-64-19250
Benzene ND ug/kg 100 03/04/10 19:11 71-43-2463
Bromobenzene ND ug/kg 100 03/04/10 19:11 108-86-1463
Bromochloromethane ND ug/kg 100 03/04/10 19:11 74-97-5463
Bromodichloromethane ND ug/kg 100 03/04/10 19:11 75-27-4463
Bromoform ND ug/kg 100 03/04/10 19:11 75-25-2463
Bromomethane ND ug/kg 100 03/04/10 19:11 74-83-9925
2-Butanone (MEK)ND ug/kg 100 03/04/10 19:11 78-93-39250
n-Butylbenzene 2370 ug/kg 100 03/04/10 19:11 104-51-8463
sec-Butylbenzene ND ug/kg 100 03/04/10 19:11 135-98-8463
tert-Butylbenzene ND ug/kg 100 03/04/10 19:11 98-06-6463
Carbon tetrachloride ND ug/kg 100 03/04/10 19:11 56-23-5463
Chlorobenzene ND ug/kg 100 03/04/10 19:11 108-90-7463
Chloroethane ND ug/kg 100 03/04/10 19:11 75-00-3925
Chloroform ND ug/kg 100 03/04/10 19:11 67-66-3463
Chloromethane ND ug/kg 100 03/04/10 19:11 74-87-3925
2-Chlorotoluene ND ug/kg 100 03/04/10 19:11 95-49-8463
4-Chlorotoluene ND ug/kg 100 03/04/10 19:11 106-43-4463
1,2-Dibromo-3-chloropropane ND ug/kg 100 03/04/10 19:11 96-12-8463
Dibromochloromethane ND ug/kg 100 03/04/10 19:11 124-48-1463
1,2-Dibromoethane (EDB)ND ug/kg 100 03/04/10 19:11 106-93-4463
Dibromomethane ND ug/kg 100 03/04/10 19:11 74-95-3463
1,2-Dichlorobenzene ND ug/kg 100 03/04/10 19:11 95-50-1463
1,3-Dichlorobenzene ND ug/kg 100 03/04/10 19:11 541-73-1463
1,4-Dichlorobenzene ND ug/kg 100 03/04/10 19:11 106-46-7463
Dichlorodifluoromethane ND ug/kg 100 03/04/10 19:11 75-71-8925
1,1-Dichloroethane ND ug/kg 100 03/04/10 19:11 75-34-3463
1,2-Dichloroethane ND ug/kg 100 03/04/10 19:11 107-06-2463
1,1-Dichloroethene ND ug/kg 100 03/04/10 19:11 75-35-4463
cis-1,2-Dichloroethene ND ug/kg 100 03/04/10 19:11 156-59-2463
trans-1,2-Dichloroethene ND ug/kg 100 03/04/10 19:11 156-60-5463
1,2-Dichloropropane ND ug/kg 100 03/04/10 19:11 78-87-5463
1,3-Dichloropropane ND ug/kg 100 03/04/10 19:11 142-28-9463
2,2-Dichloropropane ND ug/kg 100 03/04/10 19:11 594-20-7463
1,1-Dichloropropene ND ug/kg 100 03/04/10 19:11 563-58-6463
cis-1,3-Dichloropropene ND ug/kg 100 03/04/10 19:11 10061-01-5463
trans-1,3-Dichloropropene ND ug/kg 100 03/04/10 19:11 10061-02-6463
Diisopropyl ether ND ug/kg 100 03/04/10 19:11 108-20-3463
Ethylbenzene 509 ug/kg 100 03/04/10 19:11 100-41-4463
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 36 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:2KTE-3 Lab ID:9264404015 Collected:02/25/10 13:05 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 100 03/04/10 19:11 87-68-3463
2-Hexanone ND ug/kg 100 03/04/10 19:11 591-78-64630
Isopropylbenzene (Cumene)664 ug/kg 100 03/04/10 19:11 98-82-8463
p-Isopropyltoluene 985 ug/kg 100 03/04/10 19:11 99-87-6463
Methylene Chloride ND ug/kg 100 03/04/10 19:11 75-09-21850
4-Methyl-2-pentanone (MIBK)ND ug/kg 100 03/04/10 19:11 108-10-14630
Methyl-tert-butyl ether ND ug/kg 100 03/04/10 19:11 1634-04-4463
Naphthalene 7040 ug/kg 100 03/04/10 19:11 91-20-3463
n-Propylbenzene 1310 ug/kg 100 03/04/10 19:11 103-65-1463
Styrene ND ug/kg 100 03/04/10 19:11 100-42-5463
1,1,1,2-Tetrachloroethane ND ug/kg 100 03/04/10 19:11 630-20-6463
1,1,2,2-Tetrachloroethane ND ug/kg 100 03/04/10 19:11 79-34-5463
Tetrachloroethene ND ug/kg 100 03/04/10 19:11 127-18-4463
Toluene ND ug/kg 100 03/04/10 19:11 108-88-3463
1,2,3-Trichlorobenzene ND ug/kg 100 03/04/10 19:11 87-61-6463
1,2,4-Trichlorobenzene ND ug/kg 100 03/04/10 19:11 120-82-1463
1,1,1-Trichloroethane ND ug/kg 100 03/04/10 19:11 71-55-6463
1,1,2-Trichloroethane ND ug/kg 100 03/04/10 19:11 79-00-5463
Trichloroethene ND ug/kg 100 03/04/10 19:11 79-01-6463
Trichlorofluoromethane ND ug/kg 100 03/04/10 19:11 75-69-4463
1,2,3-Trichloropropane ND ug/kg 100 03/04/10 19:11 96-18-4463
1,2,4-Trimethylbenzene 13000 ug/kg 100 03/04/10 19:11 95-63-6463
1,3,5-Trimethylbenzene 3910 ug/kg 100 03/04/10 19:11 108-67-8463
Vinyl acetate ND ug/kg 100 03/04/10 19:11 108-05-44630
Vinyl chloride ND ug/kg 100 03/04/10 19:11 75-01-4925
Xylene (Total)3510 ug/kg 100 03/04/10 19:11 1330-20-7925
m&p-Xylene 2010 ug/kg 100 03/04/10 19:11 1330-20-7925
o-Xylene 1490 ug/kg 100 03/04/10 19:11 95-47-6463
Dibromofluoromethane (S)94 %100 03/04/10 19:11 1868-53-779-116
Toluene-d8 (S)101 %100 03/04/10 19:11 2037-26-588-110
4-Bromofluorobenzene (S)102 %100 03/04/10 19:11 460-00-474-115
1,2-Dichloroethane-d4 (S)100 %100 03/04/10 19:11 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 17.0 %1 03/03/10 14:050.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 37 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-1 Lab ID:9264404016 Collected:02/26/10 10:30 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 19:3203/12/10 15:198.3
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 19:3203/12/10 15:198.3
Aromatic (C09-C10)ND mg/kg 1 03/13/10 19:3203/12/10 15:198.3
2,5-Dibromotoluene (PID)(S)113 %1 03/13/10 19:3203/12/10 15:1970-130
2,5-Dibromotoluene (FID)(S)129 %1 03/13/10 19:3203/12/10 15:1970-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/04/10 17:39 67-64-182.9
Benzene ND ug/kg 1 03/04/10 17:39 71-43-24.1
Bromobenzene ND ug/kg 1 03/04/10 17:39 108-86-14.1
Bromochloromethane ND ug/kg 1 03/04/10 17:39 74-97-54.1
Bromodichloromethane ND ug/kg 1 03/04/10 17:39 75-27-44.1
Bromoform ND ug/kg 1 03/04/10 17:39 75-25-24.1
Bromomethane ND ug/kg 1 03/04/10 17:39 74-83-98.3
2-Butanone (MEK)ND ug/kg 1 03/04/10 17:39 78-93-382.9
n-Butylbenzene ND ug/kg 1 03/04/10 17:39 104-51-84.1
sec-Butylbenzene ND ug/kg 1 03/04/10 17:39 135-98-84.1
tert-Butylbenzene ND ug/kg 1 03/04/10 17:39 98-06-64.1
Carbon tetrachloride ND ug/kg 1 03/04/10 17:39 56-23-54.1
Chlorobenzene ND ug/kg 1 03/04/10 17:39 108-90-74.1
Chloroethane ND ug/kg 1 03/04/10 17:39 75-00-38.3
Chloroform ND ug/kg 1 03/04/10 17:39 67-66-34.1
Chloromethane ND ug/kg 1 03/04/10 17:39 74-87-38.3
2-Chlorotoluene ND ug/kg 1 03/04/10 17:39 95-49-84.1
4-Chlorotoluene ND ug/kg 1 03/04/10 17:39 106-43-44.1
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/04/10 17:39 96-12-84.1
Dibromochloromethane ND ug/kg 1 03/04/10 17:39 124-48-14.1
1,2-Dibromoethane (EDB)ND ug/kg 1 03/04/10 17:39 106-93-44.1
Dibromomethane ND ug/kg 1 03/04/10 17:39 74-95-34.1
1,2-Dichlorobenzene ND ug/kg 1 03/04/10 17:39 95-50-14.1
1,3-Dichlorobenzene ND ug/kg 1 03/04/10 17:39 541-73-14.1
1,4-Dichlorobenzene ND ug/kg 1 03/04/10 17:39 106-46-74.1
Dichlorodifluoromethane ND ug/kg 1 03/04/10 17:39 75-71-88.3
1,1-Dichloroethane ND ug/kg 1 03/04/10 17:39 75-34-34.1
1,2-Dichloroethane ND ug/kg 1 03/04/10 17:39 107-06-24.1
1,1-Dichloroethene ND ug/kg 1 03/04/10 17:39 75-35-44.1
cis-1,2-Dichloroethene ND ug/kg 1 03/04/10 17:39 156-59-24.1
trans-1,2-Dichloroethene ND ug/kg 1 03/04/10 17:39 156-60-54.1
1,2-Dichloropropane ND ug/kg 1 03/04/10 17:39 78-87-54.1
1,3-Dichloropropane ND ug/kg 1 03/04/10 17:39 142-28-94.1
2,2-Dichloropropane ND ug/kg 1 03/04/10 17:39 594-20-74.1
1,1-Dichloropropene ND ug/kg 1 03/04/10 17:39 563-58-64.1
cis-1,3-Dichloropropene ND ug/kg 1 03/04/10 17:39 10061-01-54.1
trans-1,3-Dichloropropene ND ug/kg 1 03/04/10 17:39 10061-02-64.1
Diisopropyl ether ND ug/kg 1 03/04/10 17:39 108-20-34.1
Ethylbenzene ND ug/kg 1 03/04/10 17:39 100-41-44.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 38 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-1 Lab ID:9264404016 Collected:02/26/10 10:30 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/04/10 17:39 87-68-34.1
2-Hexanone ND ug/kg 1 03/04/10 17:39 591-78-641.4
Isopropylbenzene (Cumene)ND ug/kg 1 03/04/10 17:39 98-82-84.1
p-Isopropyltoluene ND ug/kg 1 03/04/10 17:39 99-87-64.1
Methylene Chloride ND ug/kg 1 03/04/10 17:39 75-09-216.6
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/04/10 17:39 108-10-141.4
Methyl-tert-butyl ether ND ug/kg 1 03/04/10 17:39 1634-04-44.1
Naphthalene ND ug/kg 1 03/04/10 17:39 91-20-34.1
n-Propylbenzene ND ug/kg 1 03/04/10 17:39 103-65-14.1
Styrene ND ug/kg 1 03/04/10 17:39 100-42-54.1
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/04/10 17:39 630-20-64.1
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/04/10 17:39 79-34-54.1
Tetrachloroethene ND ug/kg 1 03/04/10 17:39 127-18-44.1
Toluene ND ug/kg 1 03/04/10 17:39 108-88-34.1
1,2,3-Trichlorobenzene ND ug/kg 1 03/04/10 17:39 87-61-64.1
1,2,4-Trichlorobenzene ND ug/kg 1 03/04/10 17:39 120-82-14.1
1,1,1-Trichloroethane ND ug/kg 1 03/04/10 17:39 71-55-64.1
1,1,2-Trichloroethane ND ug/kg 1 03/04/10 17:39 79-00-54.1
Trichloroethene ND ug/kg 1 03/04/10 17:39 79-01-64.1
Trichlorofluoromethane ND ug/kg 1 03/04/10 17:39 75-69-44.1
1,2,3-Trichloropropane ND ug/kg 1 03/04/10 17:39 96-18-44.1
1,2,4-Trimethylbenzene 7.9 ug/kg 1 03/04/10 17:39 95-63-64.1
1,3,5-Trimethylbenzene ND ug/kg 1 03/04/10 17:39 108-67-84.1
Vinyl acetate ND ug/kg 1 03/04/10 17:39 108-05-441.4
Vinyl chloride ND ug/kg 1 03/04/10 17:39 75-01-48.3
Xylene (Total)ND ug/kg 1 03/04/10 17:39 1330-20-78.3
m&p-Xylene ND ug/kg 1 03/04/10 17:39 1330-20-78.3
o-Xylene ND ug/kg 1 03/04/10 17:39 95-47-64.1
Dibromofluoromethane (S)96 %1 03/04/10 17:39 1868-53-779-116
Toluene-d8 (S)101 %1 03/04/10 17:39 2037-26-588-110
4-Bromofluorobenzene (S)102 %1 03/04/10 17:39 460-00-474-115
1,2-Dichloroethane-d4 (S)113 %1 03/04/10 17:39 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 16.7 %1 03/03/10 14:060.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 39 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-2 Lab ID:9264404017 Collected:02/26/10 09:20 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 19:5703/15/10 09:5110
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 19:5703/15/10 09:5110
Aromatic (C09-C10)ND mg/kg 1 03/13/10 19:5703/15/10 09:5110
2,5-Dibromotoluene (PID)(S)110 %1 03/13/10 19:5703/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)115 %1 03/13/10 19:5703/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 18:49 67-64-1100
Benzene ND ug/kg 1 03/03/10 18:49 71-43-25.0
Bromobenzene ND ug/kg 1 03/03/10 18:49 108-86-15.0
Bromochloromethane ND ug/kg 1 03/03/10 18:49 74-97-55.0
Bromodichloromethane ND ug/kg 1 03/03/10 18:49 75-27-45.0
Bromoform ND ug/kg 1 03/03/10 18:49 75-25-25.0
Bromomethane ND ug/kg 1 03/03/10 18:49 74-83-910.0
2-Butanone (MEK)ND ug/kg 1 03/03/10 18:49 78-93-3100
n-Butylbenzene ND ug/kg 1 03/03/10 18:49 104-51-85.0
sec-Butylbenzene ND ug/kg 1 03/03/10 18:49 135-98-85.0
tert-Butylbenzene ND ug/kg 1 03/03/10 18:49 98-06-65.0
Carbon tetrachloride ND ug/kg 1 03/03/10 18:49 56-23-55.0
Chlorobenzene ND ug/kg 1 03/03/10 18:49 108-90-75.0
Chloroethane ND ug/kg 1 03/03/10 18:49 75-00-310.0
Chloroform ND ug/kg 1 03/03/10 18:49 67-66-35.0
Chloromethane ND ug/kg 1 03/03/10 18:49 74-87-310.0
2-Chlorotoluene ND ug/kg 1 03/03/10 18:49 95-49-85.0
4-Chlorotoluene ND ug/kg 1 03/03/10 18:49 106-43-45.0
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 18:49 96-12-85.0
Dibromochloromethane ND ug/kg 1 03/03/10 18:49 124-48-15.0
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 18:49 106-93-45.0
Dibromomethane ND ug/kg 1 03/03/10 18:49 74-95-35.0
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 18:49 95-50-15.0
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 18:49 541-73-15.0
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 18:49 106-46-75.0
Dichlorodifluoromethane ND ug/kg 1 03/03/10 18:49 75-71-810.0
1,1-Dichloroethane ND ug/kg 1 03/03/10 18:49 75-34-35.0
1,2-Dichloroethane ND ug/kg 1 03/03/10 18:49 107-06-25.0
1,1-Dichloroethene ND ug/kg 1 03/03/10 18:49 75-35-45.0
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 18:49 156-59-25.0
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 18:49 156-60-55.0
1,2-Dichloropropane ND ug/kg 1 03/03/10 18:49 78-87-55.0
1,3-Dichloropropane ND ug/kg 1 03/03/10 18:49 142-28-95.0
2,2-Dichloropropane ND ug/kg 1 03/03/10 18:49 594-20-75.0
1,1-Dichloropropene ND ug/kg 1 03/03/10 18:49 563-58-65.0
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 18:49 10061-01-55.0
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 18:49 10061-02-65.0
Diisopropyl ether ND ug/kg 1 03/03/10 18:49 108-20-35.0
Ethylbenzene ND ug/kg 1 03/03/10 18:49 100-41-45.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 40 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-2 Lab ID:9264404017 Collected:02/26/10 09:20 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 18:49 87-68-35.0
2-Hexanone ND ug/kg 1 03/03/10 18:49 591-78-650.2
Isopropylbenzene (Cumene)ND ug/kg 1 03/03/10 18:49 98-82-85.0
p-Isopropyltoluene ND ug/kg 1 03/03/10 18:49 99-87-65.0
Methylene Chloride ND ug/kg 1 03/03/10 18:49 75-09-220.1
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 18:49 108-10-150.2
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 18:49 1634-04-45.0
Naphthalene ND ug/kg 1 03/03/10 18:49 91-20-35.0
n-Propylbenzene ND ug/kg 1 03/03/10 18:49 103-65-15.0
Styrene ND ug/kg 1 03/03/10 18:49 100-42-55.0
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 18:49 630-20-65.0
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 18:49 79-34-55.0
Tetrachloroethene ND ug/kg 1 03/03/10 18:49 127-18-45.0
Toluene ND ug/kg 1 03/03/10 18:49 108-88-35.0
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 18:49 87-61-65.0
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 18:49 120-82-15.0
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 18:49 71-55-65.0
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 18:49 79-00-55.0
Trichloroethene ND ug/kg 1 03/03/10 18:49 79-01-65.0
Trichlorofluoromethane ND ug/kg 1 03/03/10 18:49 75-69-45.0
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 18:49 96-18-45.0
1,2,4-Trimethylbenzene ND ug/kg 1 03/03/10 18:49 95-63-65.0
1,3,5-Trimethylbenzene ND ug/kg 1 03/03/10 18:49 108-67-85.0
Vinyl acetate ND ug/kg 1 03/03/10 18:49 108-05-450.2
Vinyl chloride ND ug/kg 1 03/03/10 18:49 75-01-410.0
Xylene (Total)ND ug/kg 1 03/03/10 18:49 1330-20-710.0
m&p-Xylene ND ug/kg 1 03/03/10 18:49 1330-20-710.0
o-Xylene ND ug/kg 1 03/03/10 18:49 95-47-65.0
Dibromofluoromethane (S)101 %1 03/03/10 18:49 1868-53-779-116
Toluene-d8 (S)102 %1 03/03/10 18:49 2037-26-588-110
4-Bromofluorobenzene (S)102 %1 03/03/10 18:49 460-00-474-115
1,2-Dichloroethane-d4 (S)103 %1 03/03/10 18:49 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 15.6 %1 03/03/10 14:060.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 41 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-3 Lab ID:9264404018 Collected:02/26/10 10:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)85.0 mg/kg 1 03/13/10 20:2103/15/10 09:5113.9
Aliphatic (C09-C12)245 mg/kg 1 03/13/10 20:2103/15/10 09:5113.9
Aromatic (C09-C10)63.4 mg/kg 1 03/13/10 20:2103/15/10 09:5113.9
2,5-Dibromotoluene (PID)(S)110 %1 03/13/10 20:2103/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)125 %1 03/13/10 20:2103/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 250 03/04/10 01:31 67-64-122200
Benzene ND ug/kg 250 03/04/10 01:31 71-43-21110
Bromobenzene ND ug/kg 250 03/04/10 01:31 108-86-11110
Bromochloromethane ND ug/kg 250 03/04/10 01:31 74-97-51110
Bromodichloromethane ND ug/kg 250 03/04/10 01:31 75-27-41110
Bromoform ND ug/kg 250 03/04/10 01:31 75-25-21110
Bromomethane ND ug/kg 250 03/04/10 01:31 74-83-92220
2-Butanone (MEK)ND ug/kg 250 03/04/10 01:31 78-93-322200
n-Butylbenzene 3110 ug/kg 250 03/04/10 01:31 104-51-81110
sec-Butylbenzene 1290 ug/kg 250 03/04/10 01:31 135-98-81110
tert-Butylbenzene ND ug/kg 250 03/04/10 01:31 98-06-61110
Carbon tetrachloride ND ug/kg 250 03/04/10 01:31 56-23-51110
Chlorobenzene ND ug/kg 250 03/04/10 01:31 108-90-71110
Chloroethane ND ug/kg 250 03/04/10 01:31 75-00-32220
Chloroform ND ug/kg 250 03/04/10 01:31 67-66-31110
Chloromethane ND ug/kg 250 03/04/10 01:31 74-87-32220
2-Chlorotoluene ND ug/kg 250 03/04/10 01:31 95-49-81110
4-Chlorotoluene ND ug/kg 250 03/04/10 01:31 106-43-41110
1,2-Dibromo-3-chloropropane ND ug/kg 250 03/04/10 01:31 96-12-81110
Dibromochloromethane ND ug/kg 250 03/04/10 01:31 124-48-11110
1,2-Dibromoethane (EDB)ND ug/kg 250 03/04/10 01:31 106-93-41110
Dibromomethane ND ug/kg 250 03/04/10 01:31 74-95-31110
1,2-Dichlorobenzene ND ug/kg 250 03/04/10 01:31 95-50-11110
1,3-Dichlorobenzene ND ug/kg 250 03/04/10 01:31 541-73-11110
1,4-Dichlorobenzene ND ug/kg 250 03/04/10 01:31 106-46-71110
Dichlorodifluoromethane ND ug/kg 250 03/04/10 01:31 75-71-82220
1,1-Dichloroethane ND ug/kg 250 03/04/10 01:31 75-34-31110
1,2-Dichloroethane ND ug/kg 250 03/04/10 01:31 107-06-21110
1,1-Dichloroethene ND ug/kg 250 03/04/10 01:31 75-35-41110
cis-1,2-Dichloroethene ND ug/kg 250 03/04/10 01:31 156-59-21110
trans-1,2-Dichloroethene ND ug/kg 250 03/04/10 01:31 156-60-51110
1,2-Dichloropropane ND ug/kg 250 03/04/10 01:31 78-87-51110
1,3-Dichloropropane ND ug/kg 250 03/04/10 01:31 142-28-91110
2,2-Dichloropropane ND ug/kg 250 03/04/10 01:31 594-20-71110
1,1-Dichloropropene ND ug/kg 250 03/04/10 01:31 563-58-61110
cis-1,3-Dichloropropene ND ug/kg 250 03/04/10 01:31 10061-01-51110
trans-1,3-Dichloropropene ND ug/kg 250 03/04/10 01:31 10061-02-61110
Diisopropyl ether ND ug/kg 250 03/04/10 01:31 108-20-31110
Ethylbenzene 6150 ug/kg 250 03/04/10 01:31 100-41-41110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 42 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-3 Lab ID:9264404018 Collected:02/26/10 10:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 250 03/04/10 01:31 87-68-31110
2-Hexanone ND ug/kg 250 03/04/10 01:31 591-78-611100
Isopropylbenzene (Cumene)2340 ug/kg 250 03/04/10 01:31 98-82-81110
p-Isopropyltoluene 2250 ug/kg 250 03/04/10 01:31 99-87-61110
Methylene Chloride ND ug/kg 250 03/04/10 01:31 75-09-24440
4-Methyl-2-pentanone (MIBK)ND ug/kg 250 03/04/10 01:31 108-10-111100
Methyl-tert-butyl ether ND ug/kg 250 03/04/10 01:31 1634-04-41110
Naphthalene 4770 ug/kg 250 03/04/10 01:31 91-20-31110
n-Propylbenzene 6220 ug/kg 250 03/04/10 01:31 103-65-11110
Styrene ND ug/kg 250 03/04/10 01:31 100-42-51110
1,1,1,2-Tetrachloroethane ND ug/kg 250 03/04/10 01:31 630-20-61110
1,1,2,2-Tetrachloroethane ND ug/kg 250 03/04/10 01:31 79-34-51110
Tetrachloroethene ND ug/kg 250 03/04/10 01:31 127-18-41110
Toluene 11700 ug/kg 250 03/04/10 01:31 108-88-31110
1,2,3-Trichlorobenzene ND ug/kg 250 03/04/10 01:31 87-61-61110
1,2,4-Trichlorobenzene ND ug/kg 250 03/04/10 01:31 120-82-11110
1,1,1-Trichloroethane ND ug/kg 250 03/04/10 01:31 71-55-61110
1,1,2-Trichloroethane ND ug/kg 250 03/04/10 01:31 79-00-51110
Trichloroethene ND ug/kg 250 03/04/10 01:31 79-01-61110
Trichlorofluoromethane ND ug/kg 250 03/04/10 01:31 75-69-41110
1,2,3-Trichloropropane ND ug/kg 250 03/04/10 01:31 96-18-41110
1,2,4-Trimethylbenzene 27700 ug/kg 250 03/04/10 01:31 95-63-61110
1,3,5-Trimethylbenzene 8950 ug/kg 250 03/04/10 01:31 108-67-81110
Vinyl acetate ND ug/kg 250 03/04/10 01:31 108-05-411100
Vinyl chloride ND ug/kg 250 03/04/10 01:31 75-01-42220
Xylene (Total)28600 ug/kg 250 03/04/10 01:31 1330-20-72220
m&p-Xylene 18800 ug/kg 250 03/04/10 01:31 1330-20-72220
o-Xylene 9840 ug/kg 250 03/04/10 01:31 95-47-61110
Dibromofluoromethane (S)90 %250 03/04/10 01:31 1868-53-779-116
Toluene-d8 (S)101 %250 03/04/10 01:31 2037-26-588-110
4-Bromofluorobenzene (S)100 %250 03/04/10 01:31 460-00-474-115
1,2-Dichloroethane-d4 (S)101 %250 03/04/10 01:31 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 15.5 %1 03/03/10 14:060.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 43 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-4 Lab ID:9264404019 Collected:02/26/10 10:35 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 20:4603/15/10 09:519.6
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 20:4603/15/10 09:519.6
Aromatic (C09-C10)ND mg/kg 1 03/13/10 20:4603/15/10 09:519.6
2,5-Dibromotoluene (PID)(S)124 %1 03/13/10 20:4603/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)139 %1 03/13/10 20:46 S303/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone 112 ug/kg 1 03/04/10 18:34 67-64-1 C980.8
Benzene 10.6 ug/kg 1 03/04/10 18:34 71-43-24.0
Bromobenzene ND ug/kg 1 03/04/10 18:34 108-86-14.0
Bromochloromethane ND ug/kg 1 03/04/10 18:34 74-97-54.0
Bromodichloromethane ND ug/kg 1 03/04/10 18:34 75-27-44.0
Bromoform ND ug/kg 1 03/04/10 18:34 75-25-24.0
Bromomethane ND ug/kg 1 03/04/10 18:34 74-83-98.1
2-Butanone (MEK)ND ug/kg 1 03/04/10 18:34 78-93-380.8
n-Butylbenzene 75.9 ug/kg 1 03/04/10 18:34 104-51-84.0
sec-Butylbenzene 23.2 ug/kg 1 03/04/10 18:34 135-98-84.0
tert-Butylbenzene ND ug/kg 1 03/04/10 18:34 98-06-64.0
Carbon tetrachloride ND ug/kg 1 03/04/10 18:34 56-23-54.0
Chlorobenzene ND ug/kg 1 03/04/10 18:34 108-90-74.0
Chloroethane ND ug/kg 1 03/04/10 18:34 75-00-38.1
Chloroform ND ug/kg 1 03/04/10 18:34 67-66-34.0
Chloromethane ND ug/kg 1 03/04/10 18:34 74-87-38.1
2-Chlorotoluene ND ug/kg 1 03/04/10 18:34 95-49-84.0
4-Chlorotoluene ND ug/kg 1 03/04/10 18:34 106-43-44.0
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/04/10 18:34 96-12-84.0
Dibromochloromethane ND ug/kg 1 03/04/10 18:34 124-48-14.0
1,2-Dibromoethane (EDB)ND ug/kg 1 03/04/10 18:34 106-93-44.0
Dibromomethane ND ug/kg 1 03/04/10 18:34 74-95-34.0
1,2-Dichlorobenzene ND ug/kg 1 03/04/10 18:34 95-50-14.0
1,3-Dichlorobenzene ND ug/kg 1 03/04/10 18:34 541-73-14.0
1,4-Dichlorobenzene ND ug/kg 1 03/04/10 18:34 106-46-74.0
Dichlorodifluoromethane ND ug/kg 1 03/04/10 18:34 75-71-8 1g8.1
1,1-Dichloroethane ND ug/kg 1 03/04/10 18:34 75-34-34.0
1,2-Dichloroethane ND ug/kg 1 03/04/10 18:34 107-06-24.0
1,1-Dichloroethene ND ug/kg 1 03/04/10 18:34 75-35-44.0
cis-1,2-Dichloroethene ND ug/kg 1 03/04/10 18:34 156-59-24.0
trans-1,2-Dichloroethene ND ug/kg 1 03/04/10 18:34 156-60-54.0
1,2-Dichloropropane ND ug/kg 1 03/04/10 18:34 78-87-54.0
1,3-Dichloropropane ND ug/kg 1 03/04/10 18:34 142-28-94.0
2,2-Dichloropropane ND ug/kg 1 03/04/10 18:34 594-20-74.0
1,1-Dichloropropene ND ug/kg 1 03/04/10 18:34 563-58-64.0
cis-1,3-Dichloropropene ND ug/kg 1 03/04/10 18:34 10061-01-54.0
trans-1,3-Dichloropropene ND ug/kg 1 03/04/10 18:34 10061-02-64.0
Diisopropyl ether ND ug/kg 1 03/04/10 18:34 108-20-34.0
Ethylbenzene 267 ug/kg 1 03/04/10 18:34 100-41-4 E4.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 44 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-4 Lab ID:9264404019 Collected:02/26/10 10:35 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/04/10 18:34 87-68-34.0
2-Hexanone ND ug/kg 1 03/04/10 18:34 591-78-640.4
Isopropylbenzene (Cumene)43.4 ug/kg 1 03/04/10 18:34 98-82-84.0
p-Isopropyltoluene 40.5 ug/kg 1 03/04/10 18:34 99-87-64.0
Methylene Chloride ND ug/kg 1 03/04/10 18:34 75-09-216.2
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/04/10 18:34 108-10-140.4
Methyl-tert-butyl ether ND ug/kg 1 03/04/10 18:34 1634-04-44.0
Naphthalene 177 ug/kg 1 03/04/10 18:34 91-20-3 E4.0
n-Propylbenzene 171 ug/kg 1 03/04/10 18:34 103-65-1 E4.0
Styrene ND ug/kg 1 03/04/10 18:34 100-42-54.0
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/04/10 18:34 630-20-64.0
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/04/10 18:34 79-34-54.0
Tetrachloroethene ND ug/kg 1 03/04/10 18:34 127-18-44.0
Toluene 327 ug/kg 1 03/04/10 18:34 108-88-3 E4.0
1,2,3-Trichlorobenzene ND ug/kg 1 03/04/10 18:34 87-61-64.0
1,2,4-Trichlorobenzene ND ug/kg 1 03/04/10 18:34 120-82-14.0
1,1,1-Trichloroethane ND ug/kg 1 03/04/10 18:34 71-55-64.0
1,1,2-Trichloroethane ND ug/kg 1 03/04/10 18:34 79-00-54.0
Trichloroethene ND ug/kg 1 03/04/10 18:34 79-01-64.0
Trichlorofluoromethane ND ug/kg 1 03/04/10 18:34 75-69-44.0
1,2,3-Trichloropropane ND ug/kg 1 03/04/10 18:34 96-18-44.0
1,2,4-Trimethylbenzene 912 ug/kg 1 03/04/10 18:34 95-63-6 E4.0
1,3,5-Trimethylbenzene 241 ug/kg 1 03/04/10 18:34 108-67-8 E4.0
Vinyl acetate ND ug/kg 1 03/04/10 18:34 108-05-440.4
Vinyl chloride ND ug/kg 1 03/04/10 18:34 75-01-48.1
Xylene (Total)1240 ug/kg 1 03/04/10 18:34 1330-20-78.1
m&p-Xylene 855 ug/kg 1 03/04/10 18:34 1330-20-7 E8.1
o-Xylene 388 ug/kg 1 03/04/10 18:34 95-47-6 E4.0
Dibromofluoromethane (S)103 %1 03/04/10 18:34 1868-53-779-116
Toluene-d8 (S)100 %1 03/04/10 18:34 2037-26-588-110
4-Bromofluorobenzene (S)103 %1 03/04/10 18:34 460-00-474-115
1,2-Dichloroethane-d4 (S)109 %1 03/04/10 18:34 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 14.6 %1 03/03/10 14:060.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 45 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-5 Lab ID:9264404020 Collected:02/26/10 10:40 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)53.4 mg/kg 1 03/13/10 21:1103/15/10 09:5110.6
Aliphatic (C09-C12)140 mg/kg 1 03/13/10 21:1103/15/10 09:5110.6
Aromatic (C09-C10)36.0 mg/kg 1 03/13/10 21:1103/15/10 09:5110.6
2,5-Dibromotoluene (PID)(S)119 %1 03/13/10 21:1103/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)135 %1 03/13/10 21:11 S503/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 100 03/04/10 00:55 67-64-19080
Benzene ND ug/kg 100 03/04/10 00:55 71-43-2454
Bromobenzene ND ug/kg 100 03/04/10 00:55 108-86-1454
Bromochloromethane ND ug/kg 100 03/04/10 00:55 74-97-5454
Bromodichloromethane ND ug/kg 100 03/04/10 00:55 75-27-4454
Bromoform ND ug/kg 100 03/04/10 00:55 75-25-2454
Bromomethane ND ug/kg 100 03/04/10 00:55 74-83-9908
2-Butanone (MEK)ND ug/kg 100 03/04/10 00:55 78-93-39080
n-Butylbenzene 2060 ug/kg 100 03/04/10 00:55 104-51-8454
sec-Butylbenzene 587 ug/kg 100 03/04/10 00:55 135-98-8454
tert-Butylbenzene ND ug/kg 100 03/04/10 00:55 98-06-6454
Carbon tetrachloride ND ug/kg 100 03/04/10 00:55 56-23-5454
Chlorobenzene ND ug/kg 100 03/04/10 00:55 108-90-7454
Chloroethane ND ug/kg 100 03/04/10 00:55 75-00-3908
Chloroform ND ug/kg 100 03/04/10 00:55 67-66-3454
Chloromethane ND ug/kg 100 03/04/10 00:55 74-87-3908
2-Chlorotoluene ND ug/kg 100 03/04/10 00:55 95-49-8454
4-Chlorotoluene ND ug/kg 100 03/04/10 00:55 106-43-4454
1,2-Dibromo-3-chloropropane ND ug/kg 100 03/04/10 00:55 96-12-8454
Dibromochloromethane ND ug/kg 100 03/04/10 00:55 124-48-1454
1,2-Dibromoethane (EDB)ND ug/kg 100 03/04/10 00:55 106-93-4454
Dibromomethane ND ug/kg 100 03/04/10 00:55 74-95-3454
1,2-Dichlorobenzene ND ug/kg 100 03/04/10 00:55 95-50-1454
1,3-Dichlorobenzene ND ug/kg 100 03/04/10 00:55 541-73-1454
1,4-Dichlorobenzene ND ug/kg 100 03/04/10 00:55 106-46-7454
Dichlorodifluoromethane ND ug/kg 100 03/04/10 00:55 75-71-8908
1,1-Dichloroethane ND ug/kg 100 03/04/10 00:55 75-34-3454
1,2-Dichloroethane ND ug/kg 100 03/04/10 00:55 107-06-2454
1,1-Dichloroethene ND ug/kg 100 03/04/10 00:55 75-35-4454
cis-1,2-Dichloroethene ND ug/kg 100 03/04/10 00:55 156-59-2454
trans-1,2-Dichloroethene ND ug/kg 100 03/04/10 00:55 156-60-5454
1,2-Dichloropropane ND ug/kg 100 03/04/10 00:55 78-87-5454
1,3-Dichloropropane ND ug/kg 100 03/04/10 00:55 142-28-9454
2,2-Dichloropropane ND ug/kg 100 03/04/10 00:55 594-20-7454
1,1-Dichloropropene ND ug/kg 100 03/04/10 00:55 563-58-6454
cis-1,3-Dichloropropene ND ug/kg 100 03/04/10 00:55 10061-01-5454
trans-1,3-Dichloropropene ND ug/kg 100 03/04/10 00:55 10061-02-6454
Diisopropyl ether ND ug/kg 100 03/04/10 00:55 108-20-3454
Ethylbenzene 1860 ug/kg 100 03/04/10 00:55 100-41-4454
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 46 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T3E-5 Lab ID:9264404020 Collected:02/26/10 10:40 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 100 03/04/10 00:55 87-68-3454
2-Hexanone ND ug/kg 100 03/04/10 00:55 591-78-64540
Isopropylbenzene (Cumene)1040 ug/kg 100 03/04/10 00:55 98-82-8454
p-Isopropyltoluene 1300 ug/kg 100 03/04/10 00:55 99-87-6454
Methylene Chloride ND ug/kg 100 03/04/10 00:55 75-09-21820
4-Methyl-2-pentanone (MIBK)ND ug/kg 100 03/04/10 00:55 108-10-14540
Methyl-tert-butyl ether ND ug/kg 100 03/04/10 00:55 1634-04-4454
Naphthalene 2410 ug/kg 100 03/04/10 00:55 91-20-3454
n-Propylbenzene 2880 ug/kg 100 03/04/10 00:55 103-65-1454
Styrene ND ug/kg 100 03/04/10 00:55 100-42-5454
1,1,1,2-Tetrachloroethane ND ug/kg 100 03/04/10 00:55 630-20-6454
1,1,2,2-Tetrachloroethane ND ug/kg 100 03/04/10 00:55 79-34-5454
Tetrachloroethene ND ug/kg 100 03/04/10 00:55 127-18-4454
Toluene 2130 ug/kg 100 03/04/10 00:55 108-88-3454
1,2,3-Trichlorobenzene ND ug/kg 100 03/04/10 00:55 87-61-6454
1,2,4-Trichlorobenzene ND ug/kg 100 03/04/10 00:55 120-82-1454
1,1,1-Trichloroethane ND ug/kg 100 03/04/10 00:55 71-55-6454
1,1,2-Trichloroethane ND ug/kg 100 03/04/10 00:55 79-00-5454
Trichloroethene ND ug/kg 100 03/04/10 00:55 79-01-6454
Trichlorofluoromethane ND ug/kg 100 03/04/10 00:55 75-69-4454
1,2,3-Trichloropropane ND ug/kg 100 03/04/10 00:55 96-18-4454
1,2,4-Trimethylbenzene 13700 ug/kg 100 03/04/10 00:55 95-63-6454
1,3,5-Trimethylbenzene 4510 ug/kg 100 03/04/10 00:55 108-67-8454
Vinyl acetate ND ug/kg 100 03/04/10 00:55 108-05-44540
Vinyl chloride ND ug/kg 100 03/04/10 00:55 75-01-4908
Xylene (Total)8910 ug/kg 100 03/04/10 00:55 1330-20-7908
m&p-Xylene 5630 ug/kg 100 03/04/10 00:55 1330-20-7908
o-Xylene 3280 ug/kg 100 03/04/10 00:55 95-47-6454
Dibromofluoromethane (S)90 %100 03/04/10 00:55 1868-53-779-116
Toluene-d8 (S)100 %100 03/04/10 00:55 2037-26-588-110
4-Bromofluorobenzene (S)101 %100 03/04/10 00:55 460-00-474-115
1,2-Dichloroethane-d4 (S)99 %100 03/04/10 00:55 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 13.6 %1 03/03/10 14:070.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 47 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-1 Lab ID:9264404021 Collected:02/26/10 13:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)946 mg/kg 1 03/13/10 21:3503/15/10 09:5114.3
Aliphatic (C09-C12)1590 mg/kg 1 03/13/10 21:3503/15/10 09:5114.3
Aromatic (C09-C10)359 mg/kg 1 03/13/10 21:3503/15/10 09:5114.3
2,5-Dibromotoluene (PID)(S)102 %1 03/13/10 21:3503/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)131 %1 03/13/10 21:35 S503/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 100 03/04/10 01:13 67-64-110400
Benzene 912 ug/kg 100 03/04/10 01:13 71-43-2521
Bromobenzene ND ug/kg 100 03/04/10 01:13 108-86-1521
Bromochloromethane ND ug/kg 100 03/04/10 01:13 74-97-5521
Bromodichloromethane ND ug/kg 100 03/04/10 01:13 75-27-4521
Bromoform ND ug/kg 100 03/04/10 01:13 75-25-2521
Bromomethane ND ug/kg 100 03/04/10 01:13 74-83-91040
2-Butanone (MEK)ND ug/kg 100 03/04/10 01:13 78-93-310400
n-Butylbenzene 14200 ug/kg 100 03/04/10 01:13 104-51-8521
sec-Butylbenzene 6210 ug/kg 100 03/04/10 01:13 135-98-8521
tert-Butylbenzene 1410 ug/kg 100 03/04/10 01:13 98-06-6521
Carbon tetrachloride ND ug/kg 100 03/04/10 01:13 56-23-5521
Chlorobenzene ND ug/kg 100 03/04/10 01:13 108-90-7521
Chloroethane ND ug/kg 100 03/04/10 01:13 75-00-31040
Chloroform ND ug/kg 100 03/04/10 01:13 67-66-3521
Chloromethane ND ug/kg 100 03/04/10 01:13 74-87-31040
2-Chlorotoluene ND ug/kg 100 03/04/10 01:13 95-49-8521
4-Chlorotoluene ND ug/kg 100 03/04/10 01:13 106-43-4521
1,2-Dibromo-3-chloropropane ND ug/kg 100 03/04/10 01:13 96-12-8521
Dibromochloromethane ND ug/kg 100 03/04/10 01:13 124-48-1521
1,2-Dibromoethane (EDB)ND ug/kg 100 03/04/10 01:13 106-93-4521
Dibromomethane ND ug/kg 100 03/04/10 01:13 74-95-3521
1,2-Dichlorobenzene ND ug/kg 100 03/04/10 01:13 95-50-1521
1,3-Dichlorobenzene ND ug/kg 100 03/04/10 01:13 541-73-1521
1,4-Dichlorobenzene ND ug/kg 100 03/04/10 01:13 106-46-7521
Dichlorodifluoromethane ND ug/kg 100 03/04/10 01:13 75-71-81040
1,1-Dichloroethane ND ug/kg 100 03/04/10 01:13 75-34-3521
1,2-Dichloroethane ND ug/kg 100 03/04/10 01:13 107-06-2521
1,1-Dichloroethene ND ug/kg 100 03/04/10 01:13 75-35-4521
cis-1,2-Dichloroethene ND ug/kg 100 03/04/10 01:13 156-59-2521
trans-1,2-Dichloroethene ND ug/kg 100 03/04/10 01:13 156-60-5521
1,2-Dichloropropane ND ug/kg 100 03/04/10 01:13 78-87-5521
1,3-Dichloropropane ND ug/kg 100 03/04/10 01:13 142-28-9521
2,2-Dichloropropane ND ug/kg 100 03/04/10 01:13 594-20-7521
1,1-Dichloropropene ND ug/kg 100 03/04/10 01:13 563-58-6521
cis-1,3-Dichloropropene ND ug/kg 100 03/04/10 01:13 10061-01-5521
trans-1,3-Dichloropropene ND ug/kg 100 03/04/10 01:13 10061-02-6521
Diisopropyl ether ND ug/kg 100 03/04/10 01:13 108-20-3521
Ethylbenzene 7030 ug/kg 100 03/04/10 01:13 100-41-4521
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 48 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-1 Lab ID:9264404021 Collected:02/26/10 13:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 100 03/04/10 01:13 87-68-3521
2-Hexanone ND ug/kg 100 03/04/10 01:13 591-78-65210
Isopropylbenzene (Cumene)10700 ug/kg 100 03/04/10 01:13 98-82-8521
p-Isopropyltoluene 18400 ug/kg 100 03/04/10 01:13 99-87-6521
Methylene Chloride ND ug/kg 100 03/04/10 01:13 75-09-22080
4-Methyl-2-pentanone (MIBK)ND ug/kg 100 03/04/10 01:13 108-10-15210
Methyl-tert-butyl ether ND ug/kg 100 03/04/10 01:13 1634-04-4521
Naphthalene 38900 ug/kg 1250 03/04/10 19:29 91-20-38670
n-Propylbenzene 19500 ug/kg 100 03/04/10 01:13 103-65-1521
Styrene ND ug/kg 100 03/04/10 01:13 100-42-5521
1,1,1,2-Tetrachloroethane ND ug/kg 100 03/04/10 01:13 630-20-6521
1,1,2,2-Tetrachloroethane ND ug/kg 100 03/04/10 01:13 79-34-5521
Tetrachloroethene ND ug/kg 100 03/04/10 01:13 127-18-4521
Toluene 12800 ug/kg 100 03/04/10 01:13 108-88-3521
1,2,3-Trichlorobenzene ND ug/kg 100 03/04/10 01:13 87-61-6521
1,2,4-Trichlorobenzene ND ug/kg 100 03/04/10 01:13 120-82-1521
1,1,1-Trichloroethane ND ug/kg 100 03/04/10 01:13 71-55-6521
1,1,2-Trichloroethane ND ug/kg 100 03/04/10 01:13 79-00-5521
Trichloroethene ND ug/kg 100 03/04/10 01:13 79-01-6521
Trichlorofluoromethane ND ug/kg 100 03/04/10 01:13 75-69-4521
1,2,3-Trichloropropane ND ug/kg 100 03/04/10 01:13 96-18-4521
1,2,4-Trimethylbenzene 145000 ug/kg 1250 03/04/10 19:29 95-63-68670
1,3,5-Trimethylbenzene 72300 ug/kg 1250 03/04/10 19:29 108-67-88670
Vinyl acetate ND ug/kg 100 03/04/10 01:13 108-05-45210
Vinyl chloride ND ug/kg 100 03/04/10 01:13 75-01-41040
Xylene (Total)187000 ug/kg 1250 03/04/10 19:29 1330-20-717300
m&p-Xylene 105000 ug/kg 1250 03/04/10 19:29 1330-20-717300
o-Xylene 82200 ug/kg 1250 03/04/10 19:29 95-47-68670
Dibromofluoromethane (S)93 %100 03/04/10 01:13 1868-53-779-116
Toluene-d8 (S)117 %100 03/04/10 01:13 2037-26-5 S288-110
4-Bromofluorobenzene (S)88 %100 03/04/10 01:13 460-00-474-115
1,2-Dichloroethane-d4 (S)110 %100 03/04/10 01:13 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 27.9 %1 03/03/10 14:070.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 49 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-2 Lab ID:9264404022 Collected:02/26/10 13:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)15.9 mg/kg 1 03/13/10 22:0003/15/10 09:519.6
Aliphatic (C09-C12)51.3 mg/kg 1 03/13/10 22:0003/15/10 09:519.6
Aromatic (C09-C10)10.4 mg/kg 1 03/13/10 22:0003/15/10 09:519.6
2,5-Dibromotoluene (PID)(S)117 %1 03/13/10 22:0003/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)135 %1 03/13/10 22:00 S503/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 19:07 67-64-179.4
Benzene ND ug/kg 1 03/03/10 19:07 71-43-24.0
Bromobenzene ND ug/kg 1 03/03/10 19:07 108-86-14.0
Bromochloromethane ND ug/kg 1 03/03/10 19:07 74-97-54.0
Bromodichloromethane ND ug/kg 1 03/03/10 19:07 75-27-44.0
Bromoform ND ug/kg 1 03/03/10 19:07 75-25-24.0
Bromomethane ND ug/kg 1 03/03/10 19:07 74-83-97.9
2-Butanone (MEK)ND ug/kg 1 03/03/10 19:07 78-93-379.4
n-Butylbenzene ND ug/kg 1 03/03/10 19:07 104-51-84.0
sec-Butylbenzene ND ug/kg 1 03/03/10 19:07 135-98-84.0
tert-Butylbenzene ND ug/kg 1 03/03/10 19:07 98-06-64.0
Carbon tetrachloride ND ug/kg 1 03/03/10 19:07 56-23-54.0
Chlorobenzene ND ug/kg 1 03/03/10 19:07 108-90-74.0
Chloroethane ND ug/kg 1 03/03/10 19:07 75-00-37.9
Chloroform ND ug/kg 1 03/03/10 19:07 67-66-34.0
Chloromethane ND ug/kg 1 03/03/10 19:07 74-87-37.9
2-Chlorotoluene ND ug/kg 1 03/03/10 19:07 95-49-84.0
4-Chlorotoluene ND ug/kg 1 03/03/10 19:07 106-43-44.0
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 19:07 96-12-84.0
Dibromochloromethane ND ug/kg 1 03/03/10 19:07 124-48-14.0
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 19:07 106-93-44.0
Dibromomethane ND ug/kg 1 03/03/10 19:07 74-95-34.0
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 19:07 95-50-14.0
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 19:07 541-73-14.0
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 19:07 106-46-74.0
Dichlorodifluoromethane ND ug/kg 1 03/03/10 19:07 75-71-87.9
1,1-Dichloroethane ND ug/kg 1 03/03/10 19:07 75-34-34.0
1,2-Dichloroethane ND ug/kg 1 03/03/10 19:07 107-06-24.0
1,1-Dichloroethene ND ug/kg 1 03/03/10 19:07 75-35-44.0
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 19:07 156-59-24.0
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 19:07 156-60-54.0
1,2-Dichloropropane ND ug/kg 1 03/03/10 19:07 78-87-54.0
1,3-Dichloropropane ND ug/kg 1 03/03/10 19:07 142-28-94.0
2,2-Dichloropropane ND ug/kg 1 03/03/10 19:07 594-20-74.0
1,1-Dichloropropene ND ug/kg 1 03/03/10 19:07 563-58-64.0
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 19:07 10061-01-54.0
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 19:07 10061-02-64.0
Diisopropyl ether ND ug/kg 1 03/03/10 19:07 108-20-34.0
Ethylbenzene ND ug/kg 1 03/03/10 19:07 100-41-44.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 50 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-2 Lab ID:9264404022 Collected:02/26/10 13:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 19:07 87-68-34.0
2-Hexanone ND ug/kg 1 03/03/10 19:07 591-78-639.7
Isopropylbenzene (Cumene)ND ug/kg 1 03/03/10 19:07 98-82-84.0
p-Isopropyltoluene ND ug/kg 1 03/03/10 19:07 99-87-64.0
Methylene Chloride ND ug/kg 1 03/03/10 19:07 75-09-215.9
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 19:07 108-10-139.7
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 19:07 1634-04-44.0
Naphthalene ND ug/kg 1 03/03/10 19:07 91-20-34.0
n-Propylbenzene ND ug/kg 1 03/03/10 19:07 103-65-14.0
Styrene ND ug/kg 1 03/03/10 19:07 100-42-54.0
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 19:07 630-20-64.0
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 19:07 79-34-54.0
Tetrachloroethene ND ug/kg 1 03/03/10 19:07 127-18-44.0
Toluene ND ug/kg 1 03/03/10 19:07 108-88-34.0
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 19:07 87-61-64.0
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 19:07 120-82-14.0
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 19:07 71-55-64.0
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 19:07 79-00-54.0
Trichloroethene ND ug/kg 1 03/03/10 19:07 79-01-64.0
Trichlorofluoromethane ND ug/kg 1 03/03/10 19:07 75-69-44.0
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 19:07 96-18-44.0
1,2,4-Trimethylbenzene ND ug/kg 1 03/03/10 19:07 95-63-64.0
1,3,5-Trimethylbenzene ND ug/kg 1 03/03/10 19:07 108-67-84.0
Vinyl acetate ND ug/kg 1 03/03/10 19:07 108-05-439.7
Vinyl chloride ND ug/kg 1 03/03/10 19:07 75-01-47.9
Xylene (Total)ND ug/kg 1 03/03/10 19:07 1330-20-77.9
m&p-Xylene ND ug/kg 1 03/03/10 19:07 1330-20-77.9
o-Xylene ND ug/kg 1 03/03/10 19:07 95-47-64.0
Dibromofluoromethane (S)104 %1 03/03/10 19:07 1868-53-779-116
Toluene-d8 (S)101 %1 03/03/10 19:07 2037-26-588-110
4-Bromofluorobenzene (S)101 %1 03/03/10 19:07 460-00-474-115
1,2-Dichloroethane-d4 (S)105 %1 03/03/10 19:07 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 10.6 %1 03/03/10 14:080.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 51 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-3 Lab ID:9264404023 Collected:02/26/10 12:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 22:2503/15/10 09:5124.8
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 22:2503/15/10 09:5124.8
Aromatic (C09-C10)ND mg/kg 1 03/13/10 22:2503/15/10 09:5124.8
2,5-Dibromotoluene (PID)(S)118 %1 03/13/10 22:2503/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)124 %1 03/13/10 22:2503/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 19:26 67-64-1183
Benzene ND ug/kg 1 03/03/10 19:26 71-43-29.2
Bromobenzene ND ug/kg 1 03/03/10 19:26 108-86-19.2
Bromochloromethane ND ug/kg 1 03/03/10 19:26 74-97-59.2
Bromodichloromethane ND ug/kg 1 03/03/10 19:26 75-27-49.2
Bromoform ND ug/kg 1 03/03/10 19:26 75-25-29.2
Bromomethane ND ug/kg 1 03/03/10 19:26 74-83-918.3
2-Butanone (MEK)ND ug/kg 1 03/03/10 19:26 78-93-3183
n-Butylbenzene ND ug/kg 1 03/03/10 19:26 104-51-89.2
sec-Butylbenzene ND ug/kg 1 03/03/10 19:26 135-98-89.2
tert-Butylbenzene ND ug/kg 1 03/03/10 19:26 98-06-69.2
Carbon tetrachloride ND ug/kg 1 03/03/10 19:26 56-23-59.2
Chlorobenzene ND ug/kg 1 03/03/10 19:26 108-90-79.2
Chloroethane ND ug/kg 1 03/03/10 19:26 75-00-318.3
Chloroform ND ug/kg 1 03/03/10 19:26 67-66-39.2
Chloromethane ND ug/kg 1 03/03/10 19:26 74-87-318.3
2-Chlorotoluene ND ug/kg 1 03/03/10 19:26 95-49-89.2
4-Chlorotoluene ND ug/kg 1 03/03/10 19:26 106-43-49.2
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 19:26 96-12-89.2
Dibromochloromethane ND ug/kg 1 03/03/10 19:26 124-48-19.2
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 19:26 106-93-49.2
Dibromomethane ND ug/kg 1 03/03/10 19:26 74-95-39.2
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 19:26 95-50-19.2
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 19:26 541-73-19.2
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 19:26 106-46-79.2
Dichlorodifluoromethane ND ug/kg 1 03/03/10 19:26 75-71-818.3
1,1-Dichloroethane ND ug/kg 1 03/03/10 19:26 75-34-39.2
1,2-Dichloroethane ND ug/kg 1 03/03/10 19:26 107-06-29.2
1,1-Dichloroethene ND ug/kg 1 03/03/10 19:26 75-35-49.2
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 19:26 156-59-29.2
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 19:26 156-60-59.2
1,2-Dichloropropane ND ug/kg 1 03/03/10 19:26 78-87-59.2
1,3-Dichloropropane ND ug/kg 1 03/03/10 19:26 142-28-99.2
2,2-Dichloropropane ND ug/kg 1 03/03/10 19:26 594-20-79.2
1,1-Dichloropropene ND ug/kg 1 03/03/10 19:26 563-58-69.2
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 19:26 10061-01-59.2
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 19:26 10061-02-69.2
Diisopropyl ether ND ug/kg 1 03/03/10 19:26 108-20-39.2
Ethylbenzene ND ug/kg 1 03/03/10 19:26 100-41-49.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 52 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-3 Lab ID:9264404023 Collected:02/26/10 12:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 19:26 87-68-39.2
2-Hexanone ND ug/kg 1 03/03/10 19:26 591-78-691.7
Isopropylbenzene (Cumene)ND ug/kg 1 03/03/10 19:26 98-82-89.2
p-Isopropyltoluene ND ug/kg 1 03/03/10 19:26 99-87-69.2
Methylene Chloride ND ug/kg 1 03/03/10 19:26 75-09-236.7
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 19:26 108-10-191.7
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 19:26 1634-04-49.2
Naphthalene ND ug/kg 1 03/03/10 19:26 91-20-39.2
n-Propylbenzene ND ug/kg 1 03/03/10 19:26 103-65-19.2
Styrene ND ug/kg 1 03/03/10 19:26 100-42-59.2
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 19:26 630-20-69.2
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 19:26 79-34-59.2
Tetrachloroethene ND ug/kg 1 03/03/10 19:26 127-18-49.2
Toluene ND ug/kg 1 03/03/10 19:26 108-88-39.2
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 19:26 87-61-69.2
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 19:26 120-82-19.2
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 19:26 71-55-69.2
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 19:26 79-00-59.2
Trichloroethene ND ug/kg 1 03/03/10 19:26 79-01-69.2
Trichlorofluoromethane ND ug/kg 1 03/03/10 19:26 75-69-49.2
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 19:26 96-18-49.2
1,2,4-Trimethylbenzene ND ug/kg 1 03/03/10 19:26 95-63-69.2
1,3,5-Trimethylbenzene ND ug/kg 1 03/03/10 19:26 108-67-89.2
Vinyl acetate ND ug/kg 1 03/03/10 19:26 108-05-491.7
Vinyl chloride ND ug/kg 1 03/03/10 19:26 75-01-418.3
Xylene (Total)ND ug/kg 1 03/03/10 19:26 1330-20-718.3
m&p-Xylene ND ug/kg 1 03/03/10 19:26 1330-20-718.3
o-Xylene ND ug/kg 1 03/03/10 19:26 95-47-69.2
Dibromofluoromethane (S)95 %1 03/03/10 19:26 1868-53-779-116
Toluene-d8 (S)100 %1 03/03/10 19:26 2037-26-588-110
4-Bromofluorobenzene (S)100 %1 03/03/10 19:26 460-00-474-115
1,2-Dichloroethane-d4 (S)107 %1 03/03/10 19:26 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 61.1 %1 03/03/10 14:080.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 53 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-4 Lab ID:9264404024 Collected:02/26/10 12:15 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)24.2 mg/kg 1 03/13/10 22:4903/15/10 09:5111.6
Aliphatic (C09-C12)129 mg/kg 1 03/13/10 22:4903/15/10 09:5111.6
Aromatic (C09-C10)27.0 mg/kg 1 03/13/10 22:4903/15/10 09:5111.6
2,5-Dibromotoluene (PID)(S)92 %1 03/13/10 22:4903/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)119 %1 03/13/10 22:4903/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 21:52 67-64-182.6
Benzene ND ug/kg 1 03/03/10 21:52 71-43-24.1
Bromobenzene ND ug/kg 1 03/03/10 21:52 108-86-14.1
Bromochloromethane ND ug/kg 1 03/03/10 21:52 74-97-54.1
Bromodichloromethane ND ug/kg 1 03/03/10 21:52 75-27-44.1
Bromoform ND ug/kg 1 03/03/10 21:52 75-25-24.1
Bromomethane ND ug/kg 1 03/03/10 21:52 74-83-98.3
2-Butanone (MEK)ND ug/kg 1 03/03/10 21:52 78-93-382.6
n-Butylbenzene 22.6 ug/kg 1 03/03/10 21:52 104-51-84.1
sec-Butylbenzene 11.2 ug/kg 1 03/03/10 21:52 135-98-84.1
tert-Butylbenzene ND ug/kg 1 03/03/10 21:52 98-06-64.1
Carbon tetrachloride ND ug/kg 1 03/03/10 21:52 56-23-54.1
Chlorobenzene ND ug/kg 1 03/03/10 21:52 108-90-74.1
Chloroethane ND ug/kg 1 03/03/10 21:52 75-00-38.3
Chloroform ND ug/kg 1 03/03/10 21:52 67-66-34.1
Chloromethane ND ug/kg 1 03/03/10 21:52 74-87-38.3
2-Chlorotoluene ND ug/kg 1 03/03/10 21:52 95-49-84.1
4-Chlorotoluene ND ug/kg 1 03/03/10 21:52 106-43-44.1
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 21:52 96-12-84.1
Dibromochloromethane ND ug/kg 1 03/03/10 21:52 124-48-14.1
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 21:52 106-93-44.1
Dibromomethane ND ug/kg 1 03/03/10 21:52 74-95-34.1
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 21:52 95-50-14.1
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 21:52 541-73-14.1
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 21:52 106-46-74.1
Dichlorodifluoromethane ND ug/kg 1 03/03/10 21:52 75-71-88.3
1,1-Dichloroethane ND ug/kg 1 03/03/10 21:52 75-34-34.1
1,2-Dichloroethane ND ug/kg 1 03/03/10 21:52 107-06-24.1
1,1-Dichloroethene ND ug/kg 1 03/03/10 21:52 75-35-44.1
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 21:52 156-59-24.1
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 21:52 156-60-54.1
1,2-Dichloropropane ND ug/kg 1 03/03/10 21:52 78-87-54.1
1,3-Dichloropropane ND ug/kg 1 03/03/10 21:52 142-28-94.1
2,2-Dichloropropane ND ug/kg 1 03/03/10 21:52 594-20-74.1
1,1-Dichloropropene ND ug/kg 1 03/03/10 21:52 563-58-64.1
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 21:52 10061-01-54.1
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 21:52 10061-02-64.1
Diisopropyl ether ND ug/kg 1 03/03/10 21:52 108-20-34.1
Ethylbenzene 4.8 ug/kg 1 03/03/10 21:52 100-41-44.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 54 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-4 Lab ID:9264404024 Collected:02/26/10 12:15 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 21:52 87-68-34.1
2-Hexanone ND ug/kg 1 03/03/10 21:52 591-78-641.3
Isopropylbenzene (Cumene)13.0 ug/kg 1 03/03/10 21:52 98-82-84.1
p-Isopropyltoluene 29.1 ug/kg 1 03/03/10 21:52 99-87-64.1
Methylene Chloride ND ug/kg 1 03/03/10 21:52 75-09-216.5
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 21:52 108-10-141.3
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 21:52 1634-04-44.1
Naphthalene 120 ug/kg 1 03/03/10 21:52 91-20-34.1
n-Propylbenzene 12.8 ug/kg 1 03/03/10 21:52 103-65-14.1
Styrene ND ug/kg 1 03/03/10 21:52 100-42-54.1
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 21:52 630-20-64.1
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 21:52 79-34-54.1
Tetrachloroethene ND ug/kg 1 03/03/10 21:52 127-18-44.1
Toluene 5.5 ug/kg 1 03/03/10 21:52 108-88-34.1
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 21:52 87-61-64.1
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 21:52 120-82-14.1
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 21:52 71-55-64.1
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 21:52 79-00-54.1
Trichloroethene ND ug/kg 1 03/03/10 21:52 79-01-64.1
Trichlorofluoromethane ND ug/kg 1 03/03/10 21:52 75-69-44.1
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 21:52 96-18-44.1
1,2,4-Trimethylbenzene 223 ug/kg 1 03/03/10 21:52 95-63-6 E4.1
1,3,5-Trimethylbenzene 90.6 ug/kg 1 03/03/10 21:52 108-67-84.1
Vinyl acetate ND ug/kg 1 03/03/10 21:52 108-05-441.3
Vinyl chloride ND ug/kg 1 03/03/10 21:52 75-01-48.3
Xylene (Total)173 ug/kg 1 03/03/10 21:52 1330-20-78.3
m&p-Xylene 73.6 ug/kg 1 03/03/10 21:52 1330-20-78.3
o-Xylene 99.0 ug/kg 1 03/03/10 21:52 95-47-64.1
Dibromofluoromethane (S)95 %1 03/03/10 21:52 1868-53-779-116
Toluene-d8 (S)104 %1 03/03/10 21:52 2037-26-588-110
4-Bromofluorobenzene (S)106 %1 03/03/10 21:52 460-00-474-115
1,2-Dichloroethane-d4 (S)108 %1 03/03/10 21:52 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 12.9 %1 03/03/10 14:080.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 55 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-5 Lab ID:9264404025 Collected:02/26/10 13:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 23:1403/15/10 09:5110.1
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 23:1403/15/10 09:5110.1
Aromatic (C09-C10)ND mg/kg 1 03/13/10 23:1403/15/10 09:5110.1
2,5-Dibromotoluene (PID)(S)113 %1 03/13/10 23:1403/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)119 %1 03/13/10 23:1403/15/10 09:5170-130
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone 127 ug/kg 1 03/04/10 20:06 67-64-1 C982.9
Benzene ND ug/kg 1 03/04/10 20:06 71-43-24.1
Bromobenzene ND ug/kg 1 03/04/10 20:06 108-86-14.1
Bromochloromethane ND ug/kg 1 03/04/10 20:06 74-97-54.1
Bromodichloromethane ND ug/kg 1 03/04/10 20:06 75-27-44.1
Bromoform ND ug/kg 1 03/04/10 20:06 75-25-24.1
Bromomethane ND ug/kg 1 03/04/10 20:06 74-83-98.3
2-Butanone (MEK)ND ug/kg 1 03/04/10 20:06 78-93-382.9
n-Butylbenzene ND ug/kg 1 03/04/10 20:06 104-51-84.1
sec-Butylbenzene ND ug/kg 1 03/04/10 20:06 135-98-84.1
tert-Butylbenzene ND ug/kg 1 03/04/10 20:06 98-06-64.1
Carbon tetrachloride ND ug/kg 1 03/04/10 20:06 56-23-54.1
Chlorobenzene ND ug/kg 1 03/04/10 20:06 108-90-74.1
Chloroethane ND ug/kg 1 03/04/10 20:06 75-00-38.3
Chloroform ND ug/kg 1 03/04/10 20:06 67-66-34.1
Chloromethane ND ug/kg 1 03/04/10 20:06 74-87-38.3
2-Chlorotoluene ND ug/kg 1 03/04/10 20:06 95-49-84.1
4-Chlorotoluene ND ug/kg 1 03/04/10 20:06 106-43-44.1
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/04/10 20:06 96-12-84.1
Dibromochloromethane ND ug/kg 1 03/04/10 20:06 124-48-14.1
1,2-Dibromoethane (EDB)ND ug/kg 1 03/04/10 20:06 106-93-44.1
Dibromomethane ND ug/kg 1 03/04/10 20:06 74-95-34.1
1,2-Dichlorobenzene ND ug/kg 1 03/04/10 20:06 95-50-14.1
1,3-Dichlorobenzene ND ug/kg 1 03/04/10 20:06 541-73-14.1
1,4-Dichlorobenzene ND ug/kg 1 03/04/10 20:06 106-46-74.1
Dichlorodifluoromethane ND ug/kg 1 03/04/10 20:06 75-71-88.3
1,1-Dichloroethane ND ug/kg 1 03/04/10 20:06 75-34-34.1
1,2-Dichloroethane ND ug/kg 1 03/04/10 20:06 107-06-24.1
1,1-Dichloroethene ND ug/kg 1 03/04/10 20:06 75-35-44.1
cis-1,2-Dichloroethene ND ug/kg 1 03/04/10 20:06 156-59-24.1
trans-1,2-Dichloroethene ND ug/kg 1 03/04/10 20:06 156-60-54.1
1,2-Dichloropropane ND ug/kg 1 03/04/10 20:06 78-87-54.1
1,3-Dichloropropane ND ug/kg 1 03/04/10 20:06 142-28-94.1
2,2-Dichloropropane ND ug/kg 1 03/04/10 20:06 594-20-74.1
1,1-Dichloropropene ND ug/kg 1 03/04/10 20:06 563-58-64.1
cis-1,3-Dichloropropene ND ug/kg 1 03/04/10 20:06 10061-01-54.1
trans-1,3-Dichloropropene ND ug/kg 1 03/04/10 20:06 10061-02-64.1
Diisopropyl ether ND ug/kg 1 03/04/10 20:06 108-20-34.1
Ethylbenzene ND ug/kg 1 03/04/10 20:06 100-41-44.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 56 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T4E-5 Lab ID:9264404025 Collected:02/26/10 13:45 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Hexachloro-1,3-butadiene ND ug/kg 1 03/04/10 20:06 87-68-34.1
2-Hexanone ND ug/kg 1 03/04/10 20:06 591-78-641.4
Isopropylbenzene (Cumene)ND ug/kg 1 03/04/10 20:06 98-82-84.1
p-Isopropyltoluene ND ug/kg 1 03/04/10 20:06 99-87-64.1
Methylene Chloride ND ug/kg 1 03/04/10 20:06 75-09-216.6
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/04/10 20:06 108-10-141.4
Methyl-tert-butyl ether ND ug/kg 1 03/04/10 20:06 1634-04-44.1
Naphthalene ND ug/kg 1 03/04/10 20:06 91-20-34.1
n-Propylbenzene ND ug/kg 1 03/04/10 20:06 103-65-14.1
Styrene ND ug/kg 1 03/04/10 20:06 100-42-54.1
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/04/10 20:06 630-20-64.1
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/04/10 20:06 79-34-54.1
Tetrachloroethene ND ug/kg 1 03/04/10 20:06 127-18-44.1
Toluene ND ug/kg 1 03/04/10 20:06 108-88-34.1
1,2,3-Trichlorobenzene ND ug/kg 1 03/04/10 20:06 87-61-64.1
1,2,4-Trichlorobenzene ND ug/kg 1 03/04/10 20:06 120-82-14.1
1,1,1-Trichloroethane ND ug/kg 1 03/04/10 20:06 71-55-64.1
1,1,2-Trichloroethane ND ug/kg 1 03/04/10 20:06 79-00-54.1
Trichloroethene ND ug/kg 1 03/04/10 20:06 79-01-64.1
Trichlorofluoromethane ND ug/kg 1 03/04/10 20:06 75-69-44.1
1,2,3-Trichloropropane ND ug/kg 1 03/04/10 20:06 96-18-44.1
1,2,4-Trimethylbenzene ND ug/kg 1 03/04/10 20:06 95-63-64.1
1,3,5-Trimethylbenzene ND ug/kg 1 03/04/10 20:06 108-67-84.1
Vinyl acetate ND ug/kg 1 03/04/10 20:06 108-05-441.4
Vinyl chloride ND ug/kg 1 03/04/10 20:06 75-01-48.3
Xylene (Total)ND ug/kg 1 03/04/10 20:06 1330-20-78.3
m&p-Xylene ND ug/kg 1 03/04/10 20:06 1330-20-78.3
o-Xylene ND ug/kg 1 03/04/10 20:06 95-47-64.1
Dibromofluoromethane (S)108 %1 03/04/10 20:06 1868-53-779-116
Toluene-d8 (S)101 %1 03/04/10 20:06 2037-26-588-110
4-Bromofluorobenzene (S)102 %1 03/04/10 20:06 460-00-474-115
1,2-Dichloroethane-d4 (S)113 %1 03/04/10 20:06 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 8.6 %1 03/03/10 14:030.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 57 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-1 Lab ID:9264404026 Collected:02/26/10 15:00 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)122 mg/kg 4 03/10/10 13:5303/09/10 10:1055.1
Aliphatic (C19-C36)ND mg/kg 4 03/10/10 13:5303/09/10 10:1055.1
Aromatic (C11-C22)19.9 mg/kg 1 03/10/10 10:4103/09/10 10:1013.8
Nonatriacontane (S)77 %4 03/10/10 13:53 7194-86-703/09/10 10:1040-140
o-Terphenyl (S)75 %1 03/10/10 10:41 84-15-103/09/10 10:1040-140
2-Fluorobiphenyl (S)99 %1 03/10/10 10:41 321-60-803/09/10 10:1040-140
2-Bromonaphthalene (S)132 %1 03/10/10 10:41 580-13-203/09/10 10:1040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/13/10 23:3903/15/10 09:5110.8
Aliphatic (C09-C12)ND mg/kg 1 03/13/10 23:3903/15/10 09:5110.8
Aromatic (C09-C10)ND mg/kg 1 03/13/10 23:3903/15/10 09:5110.8
2,5-Dibromotoluene (PID)(S)111 %1 03/13/10 23:3903/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)125 %1 03/13/10 23:3903/15/10 09:5170-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 20 03/12/10 22:29 83-32-903/08/10 11:009090
Acenaphthylene ND ug/kg 20 03/12/10 22:29 208-96-803/08/10 11:009090
Aniline ND ug/kg 20 03/12/10 22:29 62-53-303/08/10 11:009090
Anthracene ND ug/kg 20 03/12/10 22:29 120-12-703/08/10 11:009090
Benzo(a)anthracene ND ug/kg 20 03/12/10 22:29 56-55-303/08/10 11:009090
Benzo(a)pyrene ND ug/kg 20 03/12/10 22:29 50-32-803/08/10 11:009090
Benzo(b)fluoranthene ND ug/kg 20 03/12/10 22:29 205-99-203/08/10 11:009090
Benzo(g,h,i)perylene ND ug/kg 20 03/12/10 22:29 191-24-203/08/10 11:009090
Benzo(k)fluoranthene ND ug/kg 20 03/12/10 22:29 207-08-903/08/10 11:009090
Benzoic Acid ND ug/kg 20 03/12/10 22:29 65-85-003/08/10 11:0045500
Benzyl alcohol ND ug/kg 20 03/12/10 22:29 100-51-603/08/10 11:0018200
4-Bromophenylphenyl ether ND ug/kg 20 03/12/10 22:29 101-55-303/08/10 11:009090
Butylbenzylphthalate ND ug/kg 20 03/12/10 22:29 85-68-703/08/10 11:009090
4-Chloro-3-methylphenol ND ug/kg 20 03/12/10 22:29 59-50-703/08/10 11:0018200
4-Chloroaniline ND ug/kg 20 03/12/10 22:29 106-47-803/08/10 11:0045500
bis(2-Chloroethoxy)methane ND ug/kg 20 03/12/10 22:29 111-91-103/08/10 11:009090
bis(2-Chloroethyl) ether ND ug/kg 20 03/12/10 22:29 111-44-403/08/10 11:009090
bis(2-Chloroisopropyl) ether ND ug/kg 20 03/12/10 22:29 108-60-103/08/10 11:009090
2-Chloronaphthalene ND ug/kg 20 03/12/10 22:29 91-58-703/08/10 11:009090
2-Chlorophenol ND ug/kg 20 03/12/10 22:29 95-57-803/08/10 11:009090
4-Chlorophenylphenyl ether ND ug/kg 20 03/12/10 22:29 7005-72-303/08/10 11:009090
Chrysene ND ug/kg 20 03/12/10 22:29 218-01-903/08/10 11:009090
Dibenz(a,h)anthracene ND ug/kg 20 03/12/10 22:29 53-70-303/08/10 11:009090
Dibenzofuran ND ug/kg 20 03/12/10 22:29 132-64-903/08/10 11:009090
1,2-Dichlorobenzene ND ug/kg 20 03/12/10 22:29 95-50-103/08/10 11:009090
1,3-Dichlorobenzene ND ug/kg 20 03/12/10 22:29 541-73-103/08/10 11:009090
1,4-Dichlorobenzene ND ug/kg 20 03/12/10 22:29 106-46-703/08/10 11:009090
3,3'-Dichlorobenzidine ND ug/kg 20 03/12/10 22:29 91-94-103/08/10 11:0045500
2,4-Dichlorophenol ND ug/kg 20 03/12/10 22:29 120-83-203/08/10 11:009090
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 58 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-1 Lab ID:9264404026 Collected:02/26/10 15:00 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Diethylphthalate ND ug/kg 20 03/12/10 22:29 84-66-203/08/10 11:009090
2,4-Dimethylphenol ND ug/kg 20 03/12/10 22:29 105-67-903/08/10 11:009090
Dimethylphthalate ND ug/kg 20 03/12/10 22:29 131-11-303/08/10 11:009090
Di-n-butylphthalate ND ug/kg 20 03/12/10 22:29 84-74-203/08/10 11:009090
4,6-Dinitro-2-methylphenol ND ug/kg 20 03/12/10 22:29 534-52-103/08/10 11:0018200
2,4-Dinitrophenol ND ug/kg 20 03/12/10 22:29 51-28-503/08/10 11:0045500
2,4-Dinitrotoluene ND ug/kg 20 03/12/10 22:29 121-14-203/08/10 11:009090
2,6-Dinitrotoluene ND ug/kg 20 03/12/10 22:29 606-20-203/08/10 11:009090
Di-n-octylphthalate ND ug/kg 20 03/12/10 22:29 117-84-003/08/10 11:009090
bis(2-Ethylhexyl)phthalate ND ug/kg 20 03/12/10 22:29 117-81-703/08/10 11:009090
Fluoranthene ND ug/kg 20 03/12/10 22:29 206-44-003/08/10 11:009090
Fluorene ND ug/kg 20 03/12/10 22:29 86-73-703/08/10 11:009090
Hexachloro-1,3-butadiene ND ug/kg 20 03/12/10 22:29 87-68-303/08/10 11:009090
Hexachlorobenzene ND ug/kg 20 03/12/10 22:29 118-74-103/08/10 11:009090
Hexachlorocyclopentadiene ND ug/kg 20 03/12/10 22:29 77-47-403/08/10 11:009090
Hexachloroethane ND ug/kg 20 03/12/10 22:29 67-72-103/08/10 11:009090
Indeno(1,2,3-cd)pyrene ND ug/kg 20 03/12/10 22:29 193-39-503/08/10 11:009090
Isophorone ND ug/kg 20 03/12/10 22:29 78-59-103/08/10 11:009090
1-Methylnaphthalene ND ug/kg 20 03/12/10 22:29 90-12-003/08/10 11:009090
2-Methylnaphthalene ND ug/kg 20 03/12/10 22:29 91-57-603/08/10 11:009090
2-Methylphenol(o-Cresol)ND ug/kg 20 03/12/10 22:29 95-48-703/08/10 11:009090
3&4-Methylphenol(m&p Cresol)ND ug/kg 20 03/12/10 22:2903/08/10 11:009090
Naphthalene ND ug/kg 20 03/12/10 22:29 91-20-303/08/10 11:009090
2-Nitroaniline ND ug/kg 20 03/12/10 22:29 88-74-403/08/10 11:0045500
3-Nitroaniline ND ug/kg 20 03/12/10 22:29 99-09-203/08/10 11:0045500
4-Nitroaniline ND ug/kg 20 03/12/10 22:29 100-01-603/08/10 11:0018200
Nitrobenzene ND ug/kg 20 03/12/10 22:29 98-95-303/08/10 11:009090
2-Nitrophenol ND ug/kg 20 03/12/10 22:29 88-75-503/08/10 11:009090
4-Nitrophenol ND ug/kg 20 03/12/10 22:29 100-02-703/08/10 11:0045500
N-Nitrosodimethylamine ND ug/kg 20 03/12/10 22:29 62-75-903/08/10 11:009090
N-Nitroso-di-n-propylamine ND ug/kg 20 03/12/10 22:29 621-64-703/08/10 11:009090
N-Nitrosodiphenylamine ND ug/kg 20 03/12/10 22:29 86-30-603/08/10 11:009090
Pentachlorophenol ND ug/kg 20 03/12/10 22:29 87-86-503/08/10 11:0045500
Phenanthrene ND ug/kg 20 03/12/10 22:29 85-01-803/08/10 11:009090
Phenol ND ug/kg 20 03/12/10 22:29 108-95-2 D303/08/10 11:009090
Pyrene ND ug/kg 20 03/12/10 22:29 129-00-003/08/10 11:009090
1,2,4-Trichlorobenzene ND ug/kg 20 03/12/10 22:29 120-82-103/08/10 11:009090
2,4,5-Trichlorophenol ND ug/kg 20 03/12/10 22:29 95-95-403/08/10 11:009090
2,4,6-Trichlorophenol ND ug/kg 20 03/12/10 22:29 88-06-203/08/10 11:009090
Nitrobenzene-d5 (S)0 %20 03/12/10 22:29 4165-60-0 S403/08/10 11:0030-150
2-Fluorobiphenyl (S)0 %20 03/12/10 22:29 321-60-803/08/10 11:0046-120
Terphenyl-d14 (S)0 %20 03/12/10 22:29 1718-51-003/08/10 11:0038-108
Phenol-d6 (S)0 %20 03/12/10 22:29 13127-88-303/08/10 11:0035-120
2-Fluorophenol (S)0 %20 03/12/10 22:29 367-12-403/08/10 11:0024-120
2,4,6-Tribromophenol (S)0 %20 03/12/10 22:29 118-79-603/08/10 11:0044-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 59 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-1 Lab ID:9264404026 Collected:02/26/10 15:00 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 21:34 67-64-1108
Benzene ND ug/kg 1 03/03/10 21:34 71-43-25.4
Bromobenzene ND ug/kg 1 03/03/10 21:34 108-86-15.4
Bromochloromethane ND ug/kg 1 03/03/10 21:34 74-97-55.4
Bromodichloromethane ND ug/kg 1 03/03/10 21:34 75-27-45.4
Bromoform ND ug/kg 1 03/03/10 21:34 75-25-25.4
Bromomethane ND ug/kg 1 03/03/10 21:34 74-83-910.8
2-Butanone (MEK)ND ug/kg 1 03/03/10 21:34 78-93-3108
n-Butylbenzene ND ug/kg 1 03/03/10 21:34 104-51-85.4
sec-Butylbenzene ND ug/kg 1 03/03/10 21:34 135-98-85.4
tert-Butylbenzene ND ug/kg 1 03/03/10 21:34 98-06-65.4
Carbon tetrachloride ND ug/kg 1 03/03/10 21:34 56-23-55.4
Chlorobenzene ND ug/kg 1 03/03/10 21:34 108-90-75.4
Chloroethane ND ug/kg 1 03/03/10 21:34 75-00-310.8
Chloroform ND ug/kg 1 03/03/10 21:34 67-66-35.4
Chloromethane ND ug/kg 1 03/03/10 21:34 74-87-310.8
2-Chlorotoluene ND ug/kg 1 03/03/10 21:34 95-49-85.4
4-Chlorotoluene ND ug/kg 1 03/03/10 21:34 106-43-45.4
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 21:34 96-12-85.4
Dibromochloromethane ND ug/kg 1 03/03/10 21:34 124-48-15.4
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 21:34 106-93-45.4
Dibromomethane ND ug/kg 1 03/03/10 21:34 74-95-35.4
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 21:34 95-50-15.4
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 21:34 541-73-15.4
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 21:34 106-46-75.4
Dichlorodifluoromethane ND ug/kg 1 03/03/10 21:34 75-71-810.8
1,1-Dichloroethane ND ug/kg 1 03/03/10 21:34 75-34-35.4
1,2-Dichloroethane ND ug/kg 1 03/03/10 21:34 107-06-25.4
1,1-Dichloroethene ND ug/kg 1 03/03/10 21:34 75-35-45.4
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 21:34 156-59-25.4
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 21:34 156-60-55.4
1,2-Dichloropropane ND ug/kg 1 03/03/10 21:34 78-87-55.4
1,3-Dichloropropane ND ug/kg 1 03/03/10 21:34 142-28-95.4
2,2-Dichloropropane ND ug/kg 1 03/03/10 21:34 594-20-75.4
1,1-Dichloropropene ND ug/kg 1 03/03/10 21:34 563-58-65.4
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 21:34 10061-01-55.4
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 21:34 10061-02-65.4
Diisopropyl ether ND ug/kg 1 03/03/10 21:34 108-20-35.4
Ethylbenzene ND ug/kg 1 03/03/10 21:34 100-41-45.4
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 21:34 87-68-35.4
2-Hexanone ND ug/kg 1 03/03/10 21:34 591-78-653.9
Isopropylbenzene (Cumene)ND ug/kg 1 03/03/10 21:34 98-82-85.4
p-Isopropyltoluene ND ug/kg 1 03/03/10 21:34 99-87-65.4
Methylene Chloride ND ug/kg 1 03/03/10 21:34 75-09-221.6
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 21:34 108-10-153.9
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 21:34 1634-04-45.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 60 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-1 Lab ID:9264404026 Collected:02/26/10 15:00 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene ND ug/kg 1 03/03/10 21:34 91-20-35.4
n-Propylbenzene ND ug/kg 1 03/03/10 21:34 103-65-15.4
Styrene ND ug/kg 1 03/03/10 21:34 100-42-55.4
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 21:34 630-20-65.4
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 21:34 79-34-55.4
Tetrachloroethene ND ug/kg 1 03/03/10 21:34 127-18-45.4
Toluene ND ug/kg 1 03/03/10 21:34 108-88-35.4
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 21:34 87-61-65.4
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 21:34 120-82-15.4
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 21:34 71-55-65.4
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 21:34 79-00-55.4
Trichloroethene ND ug/kg 1 03/03/10 21:34 79-01-65.4
Trichlorofluoromethane ND ug/kg 1 03/03/10 21:34 75-69-45.4
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 21:34 96-18-45.4
1,2,4-Trimethylbenzene ND ug/kg 1 03/03/10 21:34 95-63-65.4
1,3,5-Trimethylbenzene ND ug/kg 1 03/03/10 21:34 108-67-85.4
Vinyl acetate ND ug/kg 1 03/03/10 21:34 108-05-453.9
Vinyl chloride ND ug/kg 1 03/03/10 21:34 75-01-410.8
Xylene (Total)ND ug/kg 1 03/03/10 21:34 1330-20-710.8
m&p-Xylene ND ug/kg 1 03/03/10 21:34 1330-20-710.8
o-Xylene ND ug/kg 1 03/03/10 21:34 95-47-65.4
Dibromofluoromethane (S)98 %1 03/03/10 21:34 1868-53-779-116
Toluene-d8 (S)101 %1 03/03/10 21:34 2037-26-588-110
4-Bromofluorobenzene (S)99 %1 03/03/10 21:34 460-00-474-115
1,2-Dichloroethane-d4 (S)106 %1 03/03/10 21:34 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 27.4 %1 03/03/10 14:040.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 61 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-2 Lab ID:9264404027 Collected:02/26/10 15:05 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 03/10/10 11:1503/09/10 10:1012.8
Aliphatic (C19-C36)31.4 mg/kg 1 03/10/10 11:1503/09/10 10:1012.8
Aromatic (C11-C22)ND mg/kg 1 03/10/10 11:1503/09/10 10:1012.8
Nonatriacontane (S)77 %1 03/10/10 11:15 7194-86-703/09/10 10:1040-140
o-Terphenyl (S)82 %1 03/10/10 11:15 84-15-103/09/10 10:1040-140
2-Fluorobiphenyl (S)51 %1 03/10/10 11:15 321-60-803/09/10 10:1040-140
2-Bromonaphthalene (S)76 %1 03/10/10 11:15 580-13-203/09/10 10:1040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/14/10 00:0403/15/10 09:519.5
Aliphatic (C09-C12)ND mg/kg 1 03/14/10 00:0403/15/10 09:519.5
Aromatic (C09-C10)ND mg/kg 1 03/14/10 00:0403/15/10 09:519.5
2,5-Dibromotoluene (PID)(S)106 %1 03/14/10 00:0403/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)115 %1 03/14/10 00:0403/15/10 09:5170-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 03/12/10 22:54 83-32-903/08/10 11:00423
Acenaphthylene ND ug/kg 1 03/12/10 22:54 208-96-803/08/10 11:00423
Aniline ND ug/kg 1 03/12/10 22:54 62-53-303/08/10 11:00423
Anthracene ND ug/kg 1 03/12/10 22:54 120-12-703/08/10 11:00423
Benzo(a)anthracene ND ug/kg 1 03/12/10 22:54 56-55-303/08/10 11:00423
Benzo(a)pyrene ND ug/kg 1 03/12/10 22:54 50-32-803/08/10 11:00423
Benzo(b)fluoranthene ND ug/kg 1 03/12/10 22:54 205-99-203/08/10 11:00423
Benzo(g,h,i)perylene ND ug/kg 1 03/12/10 22:54 191-24-203/08/10 11:00423
Benzo(k)fluoranthene ND ug/kg 1 03/12/10 22:54 207-08-903/08/10 11:00423
Benzoic Acid ND ug/kg 1 03/12/10 22:54 65-85-003/08/10 11:002120
Benzyl alcohol ND ug/kg 1 03/12/10 22:54 100-51-603/08/10 11:00847
4-Bromophenylphenyl ether ND ug/kg 1 03/12/10 22:54 101-55-303/08/10 11:00423
Butylbenzylphthalate ND ug/kg 1 03/12/10 22:54 85-68-703/08/10 11:00423
4-Chloro-3-methylphenol ND ug/kg 1 03/12/10 22:54 59-50-703/08/10 11:00847
4-Chloroaniline ND ug/kg 1 03/12/10 22:54 106-47-803/08/10 11:002120
bis(2-Chloroethoxy)methane ND ug/kg 1 03/12/10 22:54 111-91-103/08/10 11:00423
bis(2-Chloroethyl) ether ND ug/kg 1 03/12/10 22:54 111-44-403/08/10 11:00423
bis(2-Chloroisopropyl) ether ND ug/kg 1 03/12/10 22:54 108-60-103/08/10 11:00423
2-Chloronaphthalene ND ug/kg 1 03/12/10 22:54 91-58-703/08/10 11:00423
2-Chlorophenol ND ug/kg 1 03/12/10 22:54 95-57-803/08/10 11:00423
4-Chlorophenylphenyl ether ND ug/kg 1 03/12/10 22:54 7005-72-303/08/10 11:00423
Chrysene ND ug/kg 1 03/12/10 22:54 218-01-903/08/10 11:00423
Dibenz(a,h)anthracene ND ug/kg 1 03/12/10 22:54 53-70-303/08/10 11:00423
Dibenzofuran ND ug/kg 1 03/12/10 22:54 132-64-903/08/10 11:00423
1,2-Dichlorobenzene ND ug/kg 1 03/12/10 22:54 95-50-103/08/10 11:00423
1,3-Dichlorobenzene ND ug/kg 1 03/12/10 22:54 541-73-103/08/10 11:00423
1,4-Dichlorobenzene ND ug/kg 1 03/12/10 22:54 106-46-703/08/10 11:00423
3,3'-Dichlorobenzidine ND ug/kg 1 03/12/10 22:54 91-94-103/08/10 11:002120
2,4-Dichlorophenol ND ug/kg 1 03/12/10 22:54 120-83-203/08/10 11:00423
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 62 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-2 Lab ID:9264404027 Collected:02/26/10 15:05 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Diethylphthalate ND ug/kg 1 03/12/10 22:54 84-66-203/08/10 11:00423
2,4-Dimethylphenol ND ug/kg 1 03/12/10 22:54 105-67-903/08/10 11:00423
Dimethylphthalate ND ug/kg 1 03/12/10 22:54 131-11-303/08/10 11:00423
Di-n-butylphthalate ND ug/kg 1 03/12/10 22:54 84-74-203/08/10 11:00423
4,6-Dinitro-2-methylphenol ND ug/kg 1 03/12/10 22:54 534-52-103/08/10 11:00847
2,4-Dinitrophenol ND ug/kg 1 03/12/10 22:54 51-28-503/08/10 11:002120
2,4-Dinitrotoluene ND ug/kg 1 03/12/10 22:54 121-14-203/08/10 11:00423
2,6-Dinitrotoluene ND ug/kg 1 03/12/10 22:54 606-20-203/08/10 11:00423
Di-n-octylphthalate ND ug/kg 1 03/12/10 22:54 117-84-003/08/10 11:00423
bis(2-Ethylhexyl)phthalate ND ug/kg 1 03/12/10 22:54 117-81-703/08/10 11:00423
Fluoranthene ND ug/kg 1 03/12/10 22:54 206-44-003/08/10 11:00423
Fluorene ND ug/kg 1 03/12/10 22:54 86-73-703/08/10 11:00423
Hexachloro-1,3-butadiene ND ug/kg 1 03/12/10 22:54 87-68-303/08/10 11:00423
Hexachlorobenzene ND ug/kg 1 03/12/10 22:54 118-74-103/08/10 11:00423
Hexachlorocyclopentadiene ND ug/kg 1 03/12/10 22:54 77-47-403/08/10 11:00423
Hexachloroethane ND ug/kg 1 03/12/10 22:54 67-72-103/08/10 11:00423
Indeno(1,2,3-cd)pyrene ND ug/kg 1 03/12/10 22:54 193-39-503/08/10 11:00423
Isophorone ND ug/kg 1 03/12/10 22:54 78-59-103/08/10 11:00423
1-Methylnaphthalene ND ug/kg 1 03/12/10 22:54 90-12-003/08/10 11:00423
2-Methylnaphthalene ND ug/kg 1 03/12/10 22:54 91-57-603/08/10 11:00423
2-Methylphenol(o-Cresol)ND ug/kg 1 03/12/10 22:54 95-48-703/08/10 11:00423
3&4-Methylphenol(m&p Cresol)ND ug/kg 1 03/12/10 22:5403/08/10 11:00423
Naphthalene ND ug/kg 1 03/12/10 22:54 91-20-303/08/10 11:00423
2-Nitroaniline ND ug/kg 1 03/12/10 22:54 88-74-403/08/10 11:002120
3-Nitroaniline ND ug/kg 1 03/12/10 22:54 99-09-203/08/10 11:002120
4-Nitroaniline ND ug/kg 1 03/12/10 22:54 100-01-603/08/10 11:00847
Nitrobenzene ND ug/kg 1 03/12/10 22:54 98-95-303/08/10 11:00423
2-Nitrophenol ND ug/kg 1 03/12/10 22:54 88-75-503/08/10 11:00423
4-Nitrophenol ND ug/kg 1 03/12/10 22:54 100-02-703/08/10 11:002120
N-Nitrosodimethylamine ND ug/kg 1 03/12/10 22:54 62-75-903/08/10 11:00423
N-Nitroso-di-n-propylamine ND ug/kg 1 03/12/10 22:54 621-64-703/08/10 11:00423
N-Nitrosodiphenylamine ND ug/kg 1 03/12/10 22:54 86-30-603/08/10 11:00423
Pentachlorophenol ND ug/kg 1 03/12/10 22:54 87-86-503/08/10 11:002120
Phenanthrene ND ug/kg 1 03/12/10 22:54 85-01-803/08/10 11:00423
Phenol ND ug/kg 1 03/12/10 22:54 108-95-203/08/10 11:00423
Pyrene ND ug/kg 1 03/12/10 22:54 129-00-003/08/10 11:00423
1,2,4-Trichlorobenzene ND ug/kg 1 03/12/10 22:54 120-82-103/08/10 11:00423
2,4,5-Trichlorophenol ND ug/kg 1 03/12/10 22:54 95-95-403/08/10 11:00423
2,4,6-Trichlorophenol ND ug/kg 1 03/12/10 22:54 88-06-203/08/10 11:00423
Nitrobenzene-d5 (S)60 %1 03/12/10 22:54 4165-60-003/08/10 11:0030-150
2-Fluorobiphenyl (S)64 %1 03/12/10 22:54 321-60-803/08/10 11:0046-120
Terphenyl-d14 (S)72 %1 03/12/10 22:54 1718-51-003/08/10 11:0038-108
Phenol-d6 (S)42 %1 03/12/10 22:54 13127-88-303/08/10 11:0035-120
2-Fluorophenol (S)39 %1 03/12/10 22:54 367-12-403/08/10 11:0024-120
2,4,6-Tribromophenol (S)57 %1 03/12/10 22:54 118-79-603/08/10 11:0044-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 63 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-2 Lab ID:9264404027 Collected:02/26/10 15:05 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 19:44 67-64-195.0
Benzene ND ug/kg 1 03/03/10 19:44 71-43-24.8
Bromobenzene ND ug/kg 1 03/03/10 19:44 108-86-14.8
Bromochloromethane ND ug/kg 1 03/03/10 19:44 74-97-54.8
Bromodichloromethane ND ug/kg 1 03/03/10 19:44 75-27-44.8
Bromoform ND ug/kg 1 03/03/10 19:44 75-25-24.8
Bromomethane ND ug/kg 1 03/03/10 19:44 74-83-99.5
2-Butanone (MEK)ND ug/kg 1 03/03/10 19:44 78-93-395.0
n-Butylbenzene ND ug/kg 1 03/03/10 19:44 104-51-84.8
sec-Butylbenzene ND ug/kg 1 03/03/10 19:44 135-98-84.8
tert-Butylbenzene ND ug/kg 1 03/03/10 19:44 98-06-64.8
Carbon tetrachloride ND ug/kg 1 03/03/10 19:44 56-23-54.8
Chlorobenzene ND ug/kg 1 03/03/10 19:44 108-90-74.8
Chloroethane ND ug/kg 1 03/03/10 19:44 75-00-39.5
Chloroform ND ug/kg 1 03/03/10 19:44 67-66-34.8
Chloromethane ND ug/kg 1 03/03/10 19:44 74-87-39.5
2-Chlorotoluene ND ug/kg 1 03/03/10 19:44 95-49-84.8
4-Chlorotoluene ND ug/kg 1 03/03/10 19:44 106-43-44.8
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 19:44 96-12-84.8
Dibromochloromethane ND ug/kg 1 03/03/10 19:44 124-48-14.8
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 19:44 106-93-44.8
Dibromomethane ND ug/kg 1 03/03/10 19:44 74-95-34.8
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 19:44 95-50-14.8
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 19:44 541-73-14.8
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 19:44 106-46-74.8
Dichlorodifluoromethane ND ug/kg 1 03/03/10 19:44 75-71-89.5
1,1-Dichloroethane ND ug/kg 1 03/03/10 19:44 75-34-34.8
1,2-Dichloroethane ND ug/kg 1 03/03/10 19:44 107-06-24.8
1,1-Dichloroethene ND ug/kg 1 03/03/10 19:44 75-35-44.8
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 19:44 156-59-24.8
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 19:44 156-60-54.8
1,2-Dichloropropane ND ug/kg 1 03/03/10 19:44 78-87-54.8
1,3-Dichloropropane ND ug/kg 1 03/03/10 19:44 142-28-94.8
2,2-Dichloropropane ND ug/kg 1 03/03/10 19:44 594-20-74.8
1,1-Dichloropropene ND ug/kg 1 03/03/10 19:44 563-58-64.8
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 19:44 10061-01-54.8
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 19:44 10061-02-64.8
Diisopropyl ether ND ug/kg 1 03/03/10 19:44 108-20-34.8
Ethylbenzene ND ug/kg 1 03/03/10 19:44 100-41-44.8
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 19:44 87-68-34.8
2-Hexanone ND ug/kg 1 03/03/10 19:44 591-78-647.5
Isopropylbenzene (Cumene)ND ug/kg 1 03/03/10 19:44 98-82-84.8
p-Isopropyltoluene ND ug/kg 1 03/03/10 19:44 99-87-64.8
Methylene Chloride ND ug/kg 1 03/03/10 19:44 75-09-219.0
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 19:44 108-10-147.5
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 19:44 1634-04-44.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 64 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-2 Lab ID:9264404027 Collected:02/26/10 15:05 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene ND ug/kg 1 03/03/10 19:44 91-20-34.8
n-Propylbenzene ND ug/kg 1 03/03/10 19:44 103-65-14.8
Styrene ND ug/kg 1 03/03/10 19:44 100-42-54.8
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 19:44 630-20-64.8
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 19:44 79-34-54.8
Tetrachloroethene ND ug/kg 1 03/03/10 19:44 127-18-44.8
Toluene ND ug/kg 1 03/03/10 19:44 108-88-34.8
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 19:44 87-61-64.8
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 19:44 120-82-14.8
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 19:44 71-55-64.8
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 19:44 79-00-54.8
Trichloroethene ND ug/kg 1 03/03/10 19:44 79-01-64.8
Trichlorofluoromethane ND ug/kg 1 03/03/10 19:44 75-69-44.8
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 19:44 96-18-44.8
1,2,4-Trimethylbenzene ND ug/kg 1 03/03/10 19:44 95-63-64.8
1,3,5-Trimethylbenzene ND ug/kg 1 03/03/10 19:44 108-67-84.8
Vinyl acetate ND ug/kg 1 03/03/10 19:44 108-05-447.5
Vinyl chloride ND ug/kg 1 03/03/10 19:44 75-01-49.5
Xylene (Total)ND ug/kg 1 03/03/10 19:44 1330-20-79.5
m&p-Xylene ND ug/kg 1 03/03/10 19:44 1330-20-79.5
o-Xylene ND ug/kg 1 03/03/10 19:44 95-47-64.8
Dibromofluoromethane (S)93 %1 03/03/10 19:44 1868-53-779-116
Toluene-d8 (S)100 %1 03/03/10 19:44 2037-26-588-110
4-Bromofluorobenzene (S)99 %1 03/03/10 19:44 460-00-474-115
1,2-Dichloroethane-d4 (S)102 %1 03/03/10 19:44 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 22.1 %1 03/03/10 14:040.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 65 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-3 Lab ID:9264404028 Collected:02/26/10 14:50 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)1440 mg/kg 50 03/10/10 14:2703/09/10 10:10574
Aliphatic (C19-C36)ND mg/kg 50 03/10/10 14:2703/09/10 10:10574
Aromatic (C11-C22)407 mg/kg 5 03/10/10 14:2703/09/10 10:1057.4
Nonatriacontane (S)0 %50 03/10/10 14:27 7194-86-7 S403/09/10 10:1040-140
o-Terphenyl (S)0 %5 03/10/10 14:27 84-15-1 S403/09/10 10:1040-140
2-Fluorobiphenyl (S)0 %5 03/10/10 14:27 321-60-8 S403/09/10 10:1040-140
2-Bromonaphthalene (S)0 %5 03/10/10 14:27 580-13-2 S403/09/10 10:1040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/14/10 00:2803/15/10 09:518.3
Aliphatic (C09-C12)207 mg/kg 1 03/14/10 00:2803/15/10 09:518.3
Aromatic (C09-C10)60.0 mg/kg 1 03/14/10 00:2803/15/10 09:518.3
2,5-Dibromotoluene (PID)(S)128 %1 03/14/10 00:2803/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)292 %1 03/14/10 00:28 S503/15/10 09:5170-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 20 03/12/10 23:19 83-32-903/08/10 11:007570
Acenaphthylene ND ug/kg 20 03/12/10 23:19 208-96-803/08/10 11:007570
Aniline ND ug/kg 20 03/12/10 23:19 62-53-303/08/10 11:007570
Anthracene ND ug/kg 20 03/12/10 23:19 120-12-703/08/10 11:007570
Benzo(a)anthracene ND ug/kg 20 03/12/10 23:19 56-55-303/08/10 11:007570
Benzo(a)pyrene ND ug/kg 20 03/12/10 23:19 50-32-803/08/10 11:007570
Benzo(b)fluoranthene ND ug/kg 20 03/12/10 23:19 205-99-203/08/10 11:007570
Benzo(g,h,i)perylene ND ug/kg 20 03/12/10 23:19 191-24-203/08/10 11:007570
Benzo(k)fluoranthene ND ug/kg 20 03/12/10 23:19 207-08-903/08/10 11:007570
Benzoic Acid ND ug/kg 20 03/12/10 23:19 65-85-003/08/10 11:0037900
Benzyl alcohol ND ug/kg 20 03/12/10 23:19 100-51-603/08/10 11:0015100
4-Bromophenylphenyl ether ND ug/kg 20 03/12/10 23:19 101-55-303/08/10 11:007570
Butylbenzylphthalate ND ug/kg 20 03/12/10 23:19 85-68-703/08/10 11:007570
4-Chloro-3-methylphenol ND ug/kg 20 03/12/10 23:19 59-50-703/08/10 11:0015100
4-Chloroaniline ND ug/kg 20 03/12/10 23:19 106-47-803/08/10 11:0037900
bis(2-Chloroethoxy)methane ND ug/kg 20 03/12/10 23:19 111-91-103/08/10 11:007570
bis(2-Chloroethyl) ether ND ug/kg 20 03/12/10 23:19 111-44-403/08/10 11:007570
bis(2-Chloroisopropyl) ether ND ug/kg 20 03/12/10 23:19 108-60-103/08/10 11:007570
2-Chloronaphthalene ND ug/kg 20 03/12/10 23:19 91-58-703/08/10 11:007570
2-Chlorophenol ND ug/kg 20 03/12/10 23:19 95-57-803/08/10 11:007570
4-Chlorophenylphenyl ether ND ug/kg 20 03/12/10 23:19 7005-72-303/08/10 11:007570
Chrysene ND ug/kg 20 03/12/10 23:19 218-01-903/08/10 11:007570
Dibenz(a,h)anthracene ND ug/kg 20 03/12/10 23:19 53-70-303/08/10 11:007570
Dibenzofuran ND ug/kg 20 03/12/10 23:19 132-64-903/08/10 11:007570
1,2-Dichlorobenzene ND ug/kg 20 03/12/10 23:19 95-50-103/08/10 11:007570
1,3-Dichlorobenzene ND ug/kg 20 03/12/10 23:19 541-73-103/08/10 11:007570
1,4-Dichlorobenzene ND ug/kg 20 03/12/10 23:19 106-46-703/08/10 11:007570
3,3'-Dichlorobenzidine ND ug/kg 20 03/12/10 23:19 91-94-103/08/10 11:0037900
2,4-Dichlorophenol ND ug/kg 20 03/12/10 23:19 120-83-203/08/10 11:007570
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 66 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-3 Lab ID:9264404028 Collected:02/26/10 14:50 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Diethylphthalate ND ug/kg 20 03/12/10 23:19 84-66-203/08/10 11:007570
2,4-Dimethylphenol ND ug/kg 20 03/12/10 23:19 105-67-903/08/10 11:007570
Dimethylphthalate ND ug/kg 20 03/12/10 23:19 131-11-303/08/10 11:007570
Di-n-butylphthalate ND ug/kg 20 03/12/10 23:19 84-74-203/08/10 11:007570
4,6-Dinitro-2-methylphenol ND ug/kg 20 03/12/10 23:19 534-52-103/08/10 11:0015100
2,4-Dinitrophenol ND ug/kg 20 03/12/10 23:19 51-28-503/08/10 11:0037900
2,4-Dinitrotoluene ND ug/kg 20 03/12/10 23:19 121-14-203/08/10 11:007570
2,6-Dinitrotoluene ND ug/kg 20 03/12/10 23:19 606-20-203/08/10 11:007570
Di-n-octylphthalate ND ug/kg 20 03/12/10 23:19 117-84-003/08/10 11:007570
bis(2-Ethylhexyl)phthalate ND ug/kg 20 03/12/10 23:19 117-81-703/08/10 11:007570
Fluoranthene ND ug/kg 20 03/12/10 23:19 206-44-003/08/10 11:007570
Fluorene ND ug/kg 20 03/12/10 23:19 86-73-703/08/10 11:007570
Hexachloro-1,3-butadiene ND ug/kg 20 03/12/10 23:19 87-68-303/08/10 11:007570
Hexachlorobenzene ND ug/kg 20 03/12/10 23:19 118-74-103/08/10 11:007570
Hexachlorocyclopentadiene ND ug/kg 20 03/12/10 23:19 77-47-403/08/10 11:007570
Hexachloroethane ND ug/kg 20 03/12/10 23:19 67-72-103/08/10 11:007570
Indeno(1,2,3-cd)pyrene ND ug/kg 20 03/12/10 23:19 193-39-503/08/10 11:007570
Isophorone ND ug/kg 20 03/12/10 23:19 78-59-103/08/10 11:007570
1-Methylnaphthalene ND ug/kg 20 03/12/10 23:19 90-12-003/08/10 11:007570
2-Methylnaphthalene 8640 ug/kg 20 03/12/10 23:19 91-57-603/08/10 11:007570
2-Methylphenol(o-Cresol)ND ug/kg 20 03/12/10 23:19 95-48-703/08/10 11:007570
3&4-Methylphenol(m&p Cresol)ND ug/kg 20 03/12/10 23:1903/08/10 11:007570
Naphthalene ND ug/kg 20 03/12/10 23:19 91-20-303/08/10 11:007570
2-Nitroaniline ND ug/kg 20 03/12/10 23:19 88-74-403/08/10 11:0037900
3-Nitroaniline ND ug/kg 20 03/12/10 23:19 99-09-203/08/10 11:0037900
4-Nitroaniline ND ug/kg 20 03/12/10 23:19 100-01-603/08/10 11:0015100
Nitrobenzene ND ug/kg 20 03/12/10 23:19 98-95-303/08/10 11:007570
2-Nitrophenol ND ug/kg 20 03/12/10 23:19 88-75-503/08/10 11:007570
4-Nitrophenol ND ug/kg 20 03/12/10 23:19 100-02-703/08/10 11:0037900
N-Nitrosodimethylamine ND ug/kg 20 03/12/10 23:19 62-75-903/08/10 11:007570
N-Nitroso-di-n-propylamine ND ug/kg 20 03/12/10 23:19 621-64-703/08/10 11:007570
N-Nitrosodiphenylamine ND ug/kg 20 03/12/10 23:19 86-30-603/08/10 11:007570
Pentachlorophenol ND ug/kg 20 03/12/10 23:19 87-86-503/08/10 11:0037900
Phenanthrene ND ug/kg 20 03/12/10 23:19 85-01-803/08/10 11:007570
Phenol ND ug/kg 20 03/12/10 23:19 108-95-203/08/10 11:007570
Pyrene ND ug/kg 20 03/12/10 23:19 129-00-003/08/10 11:007570
1,2,4-Trichlorobenzene ND ug/kg 20 03/12/10 23:19 120-82-103/08/10 11:007570
2,4,5-Trichlorophenol ND ug/kg 20 03/12/10 23:19 95-95-403/08/10 11:007570
2,4,6-Trichlorophenol ND ug/kg 20 03/12/10 23:19 88-06-203/08/10 11:007570
Nitrobenzene-d5 (S)0 %20 03/12/10 23:19 4165-60-0 S403/08/10 11:0030-150
2-Fluorobiphenyl (S)0 %20 03/12/10 23:19 321-60-803/08/10 11:0046-120
Terphenyl-d14 (S)0 %20 03/12/10 23:19 1718-51-003/08/10 11:0038-108
Phenol-d6 (S)0 %20 03/12/10 23:19 13127-88-303/08/10 11:0035-120
2-Fluorophenol (S)0 %20 03/12/10 23:19 367-12-403/08/10 11:0024-120
2,4,6-Tribromophenol (S)0 %20 03/12/10 23:19 118-79-603/08/10 11:0044-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 67 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-3 Lab ID:9264404028 Collected:02/26/10 14:50 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 50 03/03/10 22:28 67-64-14260
Benzene ND ug/kg 50 03/03/10 22:28 71-43-2213
Bromobenzene ND ug/kg 50 03/03/10 22:28 108-86-1213
Bromochloromethane ND ug/kg 50 03/03/10 22:28 74-97-5213
Bromodichloromethane ND ug/kg 50 03/03/10 22:28 75-27-4213
Bromoform ND ug/kg 50 03/03/10 22:28 75-25-2213
Bromomethane ND ug/kg 50 03/03/10 22:28 74-83-9426
2-Butanone (MEK)ND ug/kg 50 03/03/10 22:28 78-93-34260
n-Butylbenzene 2030 ug/kg 50 03/03/10 22:28 104-51-8213
sec-Butylbenzene 568 ug/kg 50 03/03/10 22:28 135-98-8213
tert-Butylbenzene ND ug/kg 50 03/03/10 22:28 98-06-6213
Carbon tetrachloride ND ug/kg 50 03/03/10 22:28 56-23-5213
Chlorobenzene ND ug/kg 50 03/03/10 22:28 108-90-7213
Chloroethane ND ug/kg 50 03/03/10 22:28 75-00-3426
Chloroform ND ug/kg 50 03/03/10 22:28 67-66-3213
Chloromethane ND ug/kg 50 03/03/10 22:28 74-87-3426
2-Chlorotoluene ND ug/kg 50 03/03/10 22:28 95-49-8213
4-Chlorotoluene ND ug/kg 50 03/03/10 22:28 106-43-4213
1,2-Dibromo-3-chloropropane ND ug/kg 50 03/03/10 22:28 96-12-8213
Dibromochloromethane ND ug/kg 50 03/03/10 22:28 124-48-1213
1,2-Dibromoethane (EDB)ND ug/kg 50 03/03/10 22:28 106-93-4213
Dibromomethane ND ug/kg 50 03/03/10 22:28 74-95-3213
1,2-Dichlorobenzene ND ug/kg 50 03/03/10 22:28 95-50-1213
1,3-Dichlorobenzene ND ug/kg 50 03/03/10 22:28 541-73-1213
1,4-Dichlorobenzene ND ug/kg 50 03/03/10 22:28 106-46-7213
Dichlorodifluoromethane ND ug/kg 50 03/03/10 22:28 75-71-8426
1,1-Dichloroethane ND ug/kg 50 03/03/10 22:28 75-34-3213
1,2-Dichloroethane ND ug/kg 50 03/03/10 22:28 107-06-2213
1,1-Dichloroethene ND ug/kg 50 03/03/10 22:28 75-35-4213
cis-1,2-Dichloroethene ND ug/kg 50 03/03/10 22:28 156-59-2213
trans-1,2-Dichloroethene ND ug/kg 50 03/03/10 22:28 156-60-5213
1,2-Dichloropropane ND ug/kg 50 03/03/10 22:28 78-87-5213
1,3-Dichloropropane ND ug/kg 50 03/03/10 22:28 142-28-9213
2,2-Dichloropropane ND ug/kg 50 03/03/10 22:28 594-20-7213
1,1-Dichloropropene ND ug/kg 50 03/03/10 22:28 563-58-6213
cis-1,3-Dichloropropene ND ug/kg 50 03/03/10 22:28 10061-01-5213
trans-1,3-Dichloropropene ND ug/kg 50 03/03/10 22:28 10061-02-6213
Diisopropyl ether ND ug/kg 50 03/03/10 22:28 108-20-3213
Ethylbenzene ND ug/kg 50 03/03/10 22:28 100-41-4213
Hexachloro-1,3-butadiene ND ug/kg 50 03/03/10 22:28 87-68-3213
2-Hexanone ND ug/kg 50 03/03/10 22:28 591-78-62130
Isopropylbenzene (Cumene)314 ug/kg 50 03/03/10 22:28 98-82-8213
p-Isopropyltoluene 1210 ug/kg 50 03/03/10 22:28 99-87-6213
Methylene Chloride ND ug/kg 50 03/03/10 22:28 75-09-2852
4-Methyl-2-pentanone (MIBK)ND ug/kg 50 03/03/10 22:28 108-10-12130
Methyl-tert-butyl ether ND ug/kg 50 03/03/10 22:28 1634-04-4213
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 68 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-3 Lab ID:9264404028 Collected:02/26/10 14:50 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene 4900 ug/kg 50 03/03/10 22:28 91-20-3213
n-Propylbenzene 387 ug/kg 50 03/03/10 22:28 103-65-1213
Styrene ND ug/kg 50 03/03/10 22:28 100-42-5213
1,1,1,2-Tetrachloroethane ND ug/kg 50 03/03/10 22:28 630-20-6213
1,1,2,2-Tetrachloroethane ND ug/kg 50 03/03/10 22:28 79-34-5213
Tetrachloroethene ND ug/kg 50 03/03/10 22:28 127-18-4213
Toluene ND ug/kg 50 03/03/10 22:28 108-88-3213
1,2,3-Trichlorobenzene ND ug/kg 50 03/03/10 22:28 87-61-6213
1,2,4-Trichlorobenzene ND ug/kg 50 03/03/10 22:28 120-82-1213
1,1,1-Trichloroethane ND ug/kg 50 03/03/10 22:28 71-55-6213
1,1,2-Trichloroethane ND ug/kg 50 03/03/10 22:28 79-00-5213
Trichloroethene ND ug/kg 50 03/03/10 22:28 79-01-6213
Trichlorofluoromethane ND ug/kg 50 03/03/10 22:28 75-69-4213
1,2,3-Trichloropropane ND ug/kg 50 03/03/10 22:28 96-18-4213
1,2,4-Trimethylbenzene 1170 ug/kg 50 03/03/10 22:28 95-63-6213
1,3,5-Trimethylbenzene 2090 ug/kg 50 03/03/10 22:28 108-67-8213
Vinyl acetate ND ug/kg 50 03/03/10 22:28 108-05-42130
Vinyl chloride ND ug/kg 50 03/03/10 22:28 75-01-4426
Xylene (Total)ND ug/kg 50 03/03/10 22:28 1330-20-7426
m&p-Xylene ND ug/kg 50 03/03/10 22:28 1330-20-7426
o-Xylene ND ug/kg 50 03/03/10 22:28 95-47-6213
Dibromofluoromethane (S)91 %50 03/03/10 22:28 1868-53-779-116
Toluene-d8 (S)101 %50 03/03/10 22:28 2037-26-588-110
4-Bromofluorobenzene (S)100 %50 03/03/10 22:28 460-00-474-115
1,2-Dichloroethane-d4 (S)102 %50 03/03/10 22:28 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 12.8 %1 03/03/10 14:040.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 69 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-4 Lab ID:9264404029 Collected:02/26/10 14:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)ND mg/kg 1 03/10/10 12:2303/09/10 10:1013.0
Aliphatic (C19-C36)ND mg/kg 1 03/10/10 12:2303/09/10 10:1013.0
Aromatic (C11-C22)ND mg/kg 1 03/10/10 12:2303/09/10 10:1013.0
Nonatriacontane (S)80 %1 03/10/10 12:23 7194-86-703/09/10 10:1040-140
o-Terphenyl (S)85 %1 03/10/10 12:23 84-15-103/09/10 10:1040-140
2-Fluorobiphenyl (S)93 %1 03/10/10 12:23 321-60-803/09/10 10:1040-140
2-Bromonaphthalene (S)93 %1 03/10/10 12:23 580-13-203/09/10 10:1040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/14/10 00:5303/15/10 09:5110.4
Aliphatic (C09-C12)22.6 mg/kg 1 03/14/10 00:5303/15/10 09:5110.4
Aromatic (C09-C10)ND mg/kg 1 03/14/10 00:5303/15/10 09:5110.4
2,5-Dibromotoluene (PID)(S)133 %1 03/14/10 00:53 S303/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)214 %1 03/14/10 00:53 S503/15/10 09:5170-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 03/12/10 23:44 83-32-903/08/10 11:00430
Acenaphthylene ND ug/kg 1 03/12/10 23:44 208-96-803/08/10 11:00430
Aniline ND ug/kg 1 03/12/10 23:44 62-53-303/08/10 11:00430
Anthracene ND ug/kg 1 03/12/10 23:44 120-12-703/08/10 11:00430
Benzo(a)anthracene ND ug/kg 1 03/12/10 23:44 56-55-303/08/10 11:00430
Benzo(a)pyrene ND ug/kg 1 03/12/10 23:44 50-32-803/08/10 11:00430
Benzo(b)fluoranthene ND ug/kg 1 03/12/10 23:44 205-99-203/08/10 11:00430
Benzo(g,h,i)perylene ND ug/kg 1 03/12/10 23:44 191-24-203/08/10 11:00430
Benzo(k)fluoranthene ND ug/kg 1 03/12/10 23:44 207-08-903/08/10 11:00430
Benzoic Acid ND ug/kg 1 03/12/10 23:44 65-85-003/08/10 11:002150
Benzyl alcohol ND ug/kg 1 03/12/10 23:44 100-51-603/08/10 11:00861
4-Bromophenylphenyl ether ND ug/kg 1 03/12/10 23:44 101-55-303/08/10 11:00430
Butylbenzylphthalate ND ug/kg 1 03/12/10 23:44 85-68-703/08/10 11:00430
4-Chloro-3-methylphenol ND ug/kg 1 03/12/10 23:44 59-50-703/08/10 11:00861
4-Chloroaniline ND ug/kg 1 03/12/10 23:44 106-47-803/08/10 11:002150
bis(2-Chloroethoxy)methane ND ug/kg 1 03/12/10 23:44 111-91-103/08/10 11:00430
bis(2-Chloroethyl) ether ND ug/kg 1 03/12/10 23:44 111-44-403/08/10 11:00430
bis(2-Chloroisopropyl) ether ND ug/kg 1 03/12/10 23:44 108-60-103/08/10 11:00430
2-Chloronaphthalene ND ug/kg 1 03/12/10 23:44 91-58-703/08/10 11:00430
2-Chlorophenol ND ug/kg 1 03/12/10 23:44 95-57-803/08/10 11:00430
4-Chlorophenylphenyl ether ND ug/kg 1 03/12/10 23:44 7005-72-303/08/10 11:00430
Chrysene ND ug/kg 1 03/12/10 23:44 218-01-903/08/10 11:00430
Dibenz(a,h)anthracene ND ug/kg 1 03/12/10 23:44 53-70-303/08/10 11:00430
Dibenzofuran ND ug/kg 1 03/12/10 23:44 132-64-903/08/10 11:00430
1,2-Dichlorobenzene ND ug/kg 1 03/12/10 23:44 95-50-103/08/10 11:00430
1,3-Dichlorobenzene ND ug/kg 1 03/12/10 23:44 541-73-103/08/10 11:00430
1,4-Dichlorobenzene ND ug/kg 1 03/12/10 23:44 106-46-703/08/10 11:00430
3,3'-Dichlorobenzidine ND ug/kg 1 03/12/10 23:44 91-94-103/08/10 11:002150
2,4-Dichlorophenol ND ug/kg 1 03/12/10 23:44 120-83-203/08/10 11:00430
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 70 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-4 Lab ID:9264404029 Collected:02/26/10 14:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Diethylphthalate ND ug/kg 1 03/12/10 23:44 84-66-203/08/10 11:00430
2,4-Dimethylphenol ND ug/kg 1 03/12/10 23:44 105-67-903/08/10 11:00430
Dimethylphthalate ND ug/kg 1 03/12/10 23:44 131-11-303/08/10 11:00430
Di-n-butylphthalate ND ug/kg 1 03/12/10 23:44 84-74-203/08/10 11:00430
4,6-Dinitro-2-methylphenol ND ug/kg 1 03/12/10 23:44 534-52-103/08/10 11:00861
2,4-Dinitrophenol ND ug/kg 1 03/12/10 23:44 51-28-503/08/10 11:002150
2,4-Dinitrotoluene ND ug/kg 1 03/12/10 23:44 121-14-203/08/10 11:00430
2,6-Dinitrotoluene ND ug/kg 1 03/12/10 23:44 606-20-203/08/10 11:00430
Di-n-octylphthalate ND ug/kg 1 03/12/10 23:44 117-84-003/08/10 11:00430
bis(2-Ethylhexyl)phthalate ND ug/kg 1 03/12/10 23:44 117-81-703/08/10 11:00430
Fluoranthene ND ug/kg 1 03/12/10 23:44 206-44-003/08/10 11:00430
Fluorene ND ug/kg 1 03/12/10 23:44 86-73-703/08/10 11:00430
Hexachloro-1,3-butadiene ND ug/kg 1 03/12/10 23:44 87-68-303/08/10 11:00430
Hexachlorobenzene ND ug/kg 1 03/12/10 23:44 118-74-103/08/10 11:00430
Hexachlorocyclopentadiene ND ug/kg 1 03/12/10 23:44 77-47-403/08/10 11:00430
Hexachloroethane ND ug/kg 1 03/12/10 23:44 67-72-103/08/10 11:00430
Indeno(1,2,3-cd)pyrene ND ug/kg 1 03/12/10 23:44 193-39-503/08/10 11:00430
Isophorone ND ug/kg 1 03/12/10 23:44 78-59-103/08/10 11:00430
1-Methylnaphthalene ND ug/kg 1 03/12/10 23:44 90-12-003/08/10 11:00430
2-Methylnaphthalene ND ug/kg 1 03/12/10 23:44 91-57-603/08/10 11:00430
2-Methylphenol(o-Cresol)ND ug/kg 1 03/12/10 23:44 95-48-703/08/10 11:00430
3&4-Methylphenol(m&p Cresol)ND ug/kg 1 03/12/10 23:4403/08/10 11:00430
Naphthalene ND ug/kg 1 03/12/10 23:44 91-20-303/08/10 11:00430
2-Nitroaniline ND ug/kg 1 03/12/10 23:44 88-74-403/08/10 11:002150
3-Nitroaniline ND ug/kg 1 03/12/10 23:44 99-09-203/08/10 11:002150
4-Nitroaniline ND ug/kg 1 03/12/10 23:44 100-01-603/08/10 11:00861
Nitrobenzene ND ug/kg 1 03/12/10 23:44 98-95-303/08/10 11:00430
2-Nitrophenol ND ug/kg 1 03/12/10 23:44 88-75-503/08/10 11:00430
4-Nitrophenol ND ug/kg 1 03/12/10 23:44 100-02-703/08/10 11:002150
N-Nitrosodimethylamine ND ug/kg 1 03/12/10 23:44 62-75-903/08/10 11:00430
N-Nitroso-di-n-propylamine ND ug/kg 1 03/12/10 23:44 621-64-703/08/10 11:00430
N-Nitrosodiphenylamine ND ug/kg 1 03/12/10 23:44 86-30-603/08/10 11:00430
Pentachlorophenol ND ug/kg 1 03/12/10 23:44 87-86-503/08/10 11:002150
Phenanthrene ND ug/kg 1 03/12/10 23:44 85-01-803/08/10 11:00430
Phenol ND ug/kg 1 03/12/10 23:44 108-95-203/08/10 11:00430
Pyrene ND ug/kg 1 03/12/10 23:44 129-00-003/08/10 11:00430
1,2,4-Trichlorobenzene ND ug/kg 1 03/12/10 23:44 120-82-103/08/10 11:00430
2,4,5-Trichlorophenol ND ug/kg 1 03/12/10 23:44 95-95-403/08/10 11:00430
2,4,6-Trichlorophenol ND ug/kg 1 03/12/10 23:44 88-06-203/08/10 11:00430
Nitrobenzene-d5 (S)69 %1 03/12/10 23:44 4165-60-003/08/10 11:0030-150
2-Fluorobiphenyl (S)61 %1 03/12/10 23:44 321-60-803/08/10 11:0046-120
Terphenyl-d14 (S)60 %1 03/12/10 23:44 1718-51-003/08/10 11:0038-108
Phenol-d6 (S)61 %1 03/12/10 23:44 13127-88-303/08/10 11:0035-120
2-Fluorophenol (S)63 %1 03/12/10 23:44 367-12-403/08/10 11:0024-120
2,4,6-Tribromophenol (S)71 %1 03/12/10 23:44 118-79-603/08/10 11:0044-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 71 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-4 Lab ID:9264404029 Collected:02/26/10 14:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 20:02 67-64-196.9
Benzene ND ug/kg 1 03/03/10 20:02 71-43-24.8
Bromobenzene ND ug/kg 1 03/03/10 20:02 108-86-14.8
Bromochloromethane ND ug/kg 1 03/03/10 20:02 74-97-54.8
Bromodichloromethane ND ug/kg 1 03/03/10 20:02 75-27-44.8
Bromoform ND ug/kg 1 03/03/10 20:02 75-25-24.8
Bromomethane ND ug/kg 1 03/03/10 20:02 74-83-99.7
2-Butanone (MEK)ND ug/kg 1 03/03/10 20:02 78-93-396.9
n-Butylbenzene ND ug/kg 1 03/03/10 20:02 104-51-84.8
sec-Butylbenzene ND ug/kg 1 03/03/10 20:02 135-98-84.8
tert-Butylbenzene ND ug/kg 1 03/03/10 20:02 98-06-64.8
Carbon tetrachloride ND ug/kg 1 03/03/10 20:02 56-23-54.8
Chlorobenzene ND ug/kg 1 03/03/10 20:02 108-90-74.8
Chloroethane ND ug/kg 1 03/03/10 20:02 75-00-39.7
Chloroform ND ug/kg 1 03/03/10 20:02 67-66-34.8
Chloromethane ND ug/kg 1 03/03/10 20:02 74-87-39.7
2-Chlorotoluene ND ug/kg 1 03/03/10 20:02 95-49-84.8
4-Chlorotoluene ND ug/kg 1 03/03/10 20:02 106-43-44.8
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 20:02 96-12-84.8
Dibromochloromethane ND ug/kg 1 03/03/10 20:02 124-48-14.8
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 20:02 106-93-44.8
Dibromomethane ND ug/kg 1 03/03/10 20:02 74-95-34.8
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 20:02 95-50-14.8
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 20:02 541-73-14.8
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 20:02 106-46-74.8
Dichlorodifluoromethane ND ug/kg 1 03/03/10 20:02 75-71-89.7
1,1-Dichloroethane ND ug/kg 1 03/03/10 20:02 75-34-34.8
1,2-Dichloroethane ND ug/kg 1 03/03/10 20:02 107-06-24.8
1,1-Dichloroethene ND ug/kg 1 03/03/10 20:02 75-35-44.8
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 20:02 156-59-24.8
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 20:02 156-60-54.8
1,2-Dichloropropane ND ug/kg 1 03/03/10 20:02 78-87-54.8
1,3-Dichloropropane ND ug/kg 1 03/03/10 20:02 142-28-94.8
2,2-Dichloropropane ND ug/kg 1 03/03/10 20:02 594-20-74.8
1,1-Dichloropropene ND ug/kg 1 03/03/10 20:02 563-58-64.8
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 20:02 10061-01-54.8
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 20:02 10061-02-64.8
Diisopropyl ether ND ug/kg 1 03/03/10 20:02 108-20-34.8
Ethylbenzene ND ug/kg 1 03/03/10 20:02 100-41-44.8
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 20:02 87-68-34.8
2-Hexanone ND ug/kg 1 03/03/10 20:02 591-78-648.5
Isopropylbenzene (Cumene)ND ug/kg 1 03/03/10 20:02 98-82-84.8
p-Isopropyltoluene ND ug/kg 1 03/03/10 20:02 99-87-64.8
Methylene Chloride ND ug/kg 1 03/03/10 20:02 75-09-219.4
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 20:02 108-10-148.5
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 20:02 1634-04-44.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 72 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-4 Lab ID:9264404029 Collected:02/26/10 14:55 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene ND ug/kg 1 03/03/10 20:02 91-20-34.8
n-Propylbenzene ND ug/kg 1 03/03/10 20:02 103-65-14.8
Styrene ND ug/kg 1 03/03/10 20:02 100-42-54.8
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 20:02 630-20-64.8
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 20:02 79-34-54.8
Tetrachloroethene ND ug/kg 1 03/03/10 20:02 127-18-44.8
Toluene ND ug/kg 1 03/03/10 20:02 108-88-34.8
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 20:02 87-61-64.8
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 20:02 120-82-14.8
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 20:02 71-55-64.8
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 20:02 79-00-54.8
Trichloroethene ND ug/kg 1 03/03/10 20:02 79-01-64.8
Trichlorofluoromethane ND ug/kg 1 03/03/10 20:02 75-69-44.8
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 20:02 96-18-44.8
1,2,4-Trimethylbenzene ND ug/kg 1 03/03/10 20:02 95-63-64.8
1,3,5-Trimethylbenzene ND ug/kg 1 03/03/10 20:02 108-67-84.8
Vinyl acetate ND ug/kg 1 03/03/10 20:02 108-05-448.5
Vinyl chloride ND ug/kg 1 03/03/10 20:02 75-01-49.7
Xylene (Total)ND ug/kg 1 03/03/10 20:02 1330-20-79.7
m&p-Xylene ND ug/kg 1 03/03/10 20:02 1330-20-79.7
o-Xylene ND ug/kg 1 03/03/10 20:02 95-47-64.8
Dibromofluoromethane (S)102 %1 03/03/10 20:02 1868-53-779-116
Toluene-d8 (S)101 %1 03/03/10 20:02 2037-26-588-110
4-Bromofluorobenzene (S)98 %1 03/03/10 20:02 460-00-474-115
1,2-Dichloroethane-d4 (S)103 %1 03/03/10 20:02 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 23.3 %1 03/03/10 14:110.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 73 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-5 Lab ID:9264404030 Collected:02/26/10 15:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
MADEP EPH NC Soil Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Aliphatic (C09-C18)648 mg/kg 20 03/10/10 15:0003/09/10 10:10223
Aliphatic (C19-C36)ND mg/kg 20 03/10/10 15:0003/09/10 10:10223
Aromatic (C11-C22)182 mg/kg 2 03/10/10 15:0003/09/10 10:1022.3
Nonatriacontane (S)0 %20 03/10/10 15:00 7194-86-7 S403/09/10 10:1040-140
o-Terphenyl (S)101 %2 03/10/10 15:00 84-15-103/09/10 10:1040-140
2-Fluorobiphenyl (S)224 %2 03/10/10 15:00 321-60-8 S503/09/10 10:1040-140
2-Bromonaphthalene (S)474 %2 03/10/10 15:00 580-13-2 S503/09/10 10:1040-140
VPH NC Soil Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Aliphatic (C05-C08)ND mg/kg 1 03/14/10 01:1803/15/10 09:5113.0
Aliphatic (C09-C12)141 mg/kg 1 03/14/10 01:1803/15/10 09:5113.0
Aromatic (C09-C10)35.1 mg/kg 1 03/14/10 01:1803/15/10 09:5113.0
2,5-Dibromotoluene (PID)(S)131 %1 03/14/10 01:18 S503/15/10 09:5170-130
2,5-Dibromotoluene (FID)(S)228 %1 03/14/10 01:18 S503/15/10 09:5170-130
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Acenaphthene ND ug/kg 1 03/13/10 00:09 83-32-903/08/10 11:00368
Acenaphthylene ND ug/kg 1 03/13/10 00:09 208-96-803/08/10 11:00368
Aniline ND ug/kg 1 03/13/10 00:09 62-53-303/08/10 11:00368
Anthracene ND ug/kg 1 03/13/10 00:09 120-12-703/08/10 11:00368
Benzo(a)anthracene ND ug/kg 1 03/13/10 00:09 56-55-303/08/10 11:00368
Benzo(a)pyrene ND ug/kg 1 03/13/10 00:09 50-32-803/08/10 11:00368
Benzo(b)fluoranthene ND ug/kg 1 03/13/10 00:09 205-99-203/08/10 11:00368
Benzo(g,h,i)perylene ND ug/kg 1 03/13/10 00:09 191-24-203/08/10 11:00368
Benzo(k)fluoranthene ND ug/kg 1 03/13/10 00:09 207-08-903/08/10 11:00368
Benzoic Acid ND ug/kg 1 03/13/10 00:09 65-85-003/08/10 11:001840
Benzyl alcohol ND ug/kg 1 03/13/10 00:09 100-51-603/08/10 11:00736
4-Bromophenylphenyl ether ND ug/kg 1 03/13/10 00:09 101-55-303/08/10 11:00368
Butylbenzylphthalate ND ug/kg 1 03/13/10 00:09 85-68-703/08/10 11:00368
4-Chloro-3-methylphenol ND ug/kg 1 03/13/10 00:09 59-50-703/08/10 11:00736
4-Chloroaniline ND ug/kg 1 03/13/10 00:09 106-47-803/08/10 11:001840
bis(2-Chloroethoxy)methane ND ug/kg 1 03/13/10 00:09 111-91-103/08/10 11:00368
bis(2-Chloroethyl) ether ND ug/kg 1 03/13/10 00:09 111-44-403/08/10 11:00368
bis(2-Chloroisopropyl) ether ND ug/kg 1 03/13/10 00:09 108-60-103/08/10 11:00368
2-Chloronaphthalene ND ug/kg 1 03/13/10 00:09 91-58-703/08/10 11:00368
2-Chlorophenol ND ug/kg 1 03/13/10 00:09 95-57-803/08/10 11:00368
4-Chlorophenylphenyl ether ND ug/kg 1 03/13/10 00:09 7005-72-303/08/10 11:00368
Chrysene ND ug/kg 1 03/13/10 00:09 218-01-903/08/10 11:00368
Dibenz(a,h)anthracene ND ug/kg 1 03/13/10 00:09 53-70-303/08/10 11:00368
Dibenzofuran ND ug/kg 1 03/13/10 00:09 132-64-903/08/10 11:00368
1,2-Dichlorobenzene ND ug/kg 1 03/13/10 00:09 95-50-103/08/10 11:00368
1,3-Dichlorobenzene ND ug/kg 1 03/13/10 00:09 541-73-103/08/10 11:00368
1,4-Dichlorobenzene ND ug/kg 1 03/13/10 00:09 106-46-703/08/10 11:00368
3,3'-Dichlorobenzidine ND ug/kg 1 03/13/10 00:09 91-94-103/08/10 11:001840
2,4-Dichlorophenol ND ug/kg 1 03/13/10 00:09 120-83-203/08/10 11:00368
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 74 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-5 Lab ID:9264404030 Collected:02/26/10 15:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8270 MSSV Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546
Diethylphthalate ND ug/kg 1 03/13/10 00:09 84-66-203/08/10 11:00368
2,4-Dimethylphenol ND ug/kg 1 03/13/10 00:09 105-67-903/08/10 11:00368
Dimethylphthalate ND ug/kg 1 03/13/10 00:09 131-11-303/08/10 11:00368
Di-n-butylphthalate ND ug/kg 1 03/13/10 00:09 84-74-203/08/10 11:00368
4,6-Dinitro-2-methylphenol ND ug/kg 1 03/13/10 00:09 534-52-103/08/10 11:00736
2,4-Dinitrophenol ND ug/kg 1 03/13/10 00:09 51-28-503/08/10 11:001840
2,4-Dinitrotoluene ND ug/kg 1 03/13/10 00:09 121-14-203/08/10 11:00368
2,6-Dinitrotoluene ND ug/kg 1 03/13/10 00:09 606-20-203/08/10 11:00368
Di-n-octylphthalate ND ug/kg 1 03/13/10 00:09 117-84-003/08/10 11:00368
bis(2-Ethylhexyl)phthalate ND ug/kg 1 03/13/10 00:09 117-81-703/08/10 11:00368
Fluoranthene ND ug/kg 1 03/13/10 00:09 206-44-003/08/10 11:00368
Fluorene ND ug/kg 1 03/13/10 00:09 86-73-703/08/10 11:00368
Hexachloro-1,3-butadiene ND ug/kg 1 03/13/10 00:09 87-68-303/08/10 11:00368
Hexachlorobenzene ND ug/kg 1 03/13/10 00:09 118-74-103/08/10 11:00368
Hexachlorocyclopentadiene ND ug/kg 1 03/13/10 00:09 77-47-403/08/10 11:00368
Hexachloroethane ND ug/kg 1 03/13/10 00:09 67-72-103/08/10 11:00368
Indeno(1,2,3-cd)pyrene ND ug/kg 1 03/13/10 00:09 193-39-503/08/10 11:00368
Isophorone ND ug/kg 1 03/13/10 00:09 78-59-103/08/10 11:00368
1-Methylnaphthalene 2480 ug/kg 1 03/13/10 00:09 90-12-003/08/10 11:00368
2-Methylnaphthalene 775 ug/kg 1 03/13/10 00:09 91-57-603/08/10 11:00368
2-Methylphenol(o-Cresol)ND ug/kg 1 03/13/10 00:09 95-48-703/08/10 11:00368
3&4-Methylphenol(m&p Cresol)ND ug/kg 1 03/13/10 00:0903/08/10 11:00368
Naphthalene ND ug/kg 1 03/13/10 00:09 91-20-303/08/10 11:00368
2-Nitroaniline ND ug/kg 1 03/13/10 00:09 88-74-403/08/10 11:001840
3-Nitroaniline ND ug/kg 1 03/13/10 00:09 99-09-203/08/10 11:001840
4-Nitroaniline ND ug/kg 1 03/13/10 00:09 100-01-603/08/10 11:00736
Nitrobenzene ND ug/kg 1 03/13/10 00:09 98-95-303/08/10 11:00368
2-Nitrophenol ND ug/kg 1 03/13/10 00:09 88-75-503/08/10 11:00368
4-Nitrophenol ND ug/kg 1 03/13/10 00:09 100-02-703/08/10 11:001840
N-Nitrosodimethylamine ND ug/kg 1 03/13/10 00:09 62-75-903/08/10 11:00368
N-Nitroso-di-n-propylamine ND ug/kg 1 03/13/10 00:09 621-64-703/08/10 11:00368
N-Nitrosodiphenylamine ND ug/kg 1 03/13/10 00:09 86-30-603/08/10 11:00368
Pentachlorophenol ND ug/kg 1 03/13/10 00:09 87-86-503/08/10 11:001840
Phenanthrene ND ug/kg 1 03/13/10 00:09 85-01-803/08/10 11:00368
Phenol ND ug/kg 1 03/13/10 00:09 108-95-203/08/10 11:00368
Pyrene ND ug/kg 1 03/13/10 00:09 129-00-003/08/10 11:00368
1,2,4-Trichlorobenzene ND ug/kg 1 03/13/10 00:09 120-82-103/08/10 11:00368
2,4,5-Trichlorophenol ND ug/kg 1 03/13/10 00:09 95-95-403/08/10 11:00368
2,4,6-Trichlorophenol ND ug/kg 1 03/13/10 00:09 88-06-203/08/10 11:00368
Nitrobenzene-d5 (S)87 %1 03/13/10 00:09 4165-60-003/08/10 11:0030-150
2-Fluorobiphenyl (S)57 %1 03/13/10 00:09 321-60-803/08/10 11:0046-120
Terphenyl-d14 (S)96 %1 03/13/10 00:09 1718-51-003/08/10 11:0038-108
Phenol-d6 (S)51 %1 03/13/10 00:09 13127-88-303/08/10 11:0035-120
2-Fluorophenol (S)50 %1 03/13/10 00:09 367-12-403/08/10 11:0024-120
2,4,6-Tribromophenol (S)90 %1 03/13/10 00:09 118-79-603/08/10 11:0044-136
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 75 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-5 Lab ID:9264404030 Collected:02/26/10 15:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 50 03/03/10 22:47 67-64-14340
Benzene ND ug/kg 50 03/03/10 22:47 71-43-2217
Bromobenzene ND ug/kg 50 03/03/10 22:47 108-86-1217
Bromochloromethane ND ug/kg 50 03/03/10 22:47 74-97-5217
Bromodichloromethane ND ug/kg 50 03/03/10 22:47 75-27-4217
Bromoform ND ug/kg 50 03/03/10 22:47 75-25-2217
Bromomethane ND ug/kg 50 03/03/10 22:47 74-83-9434
2-Butanone (MEK)ND ug/kg 50 03/03/10 22:47 78-93-34340
n-Butylbenzene 550 ug/kg 50 03/03/10 22:47 104-51-8217
sec-Butylbenzene 624 ug/kg 50 03/03/10 22:47 135-98-8217
tert-Butylbenzene ND ug/kg 50 03/03/10 22:47 98-06-6217
Carbon tetrachloride ND ug/kg 50 03/03/10 22:47 56-23-5217
Chlorobenzene ND ug/kg 50 03/03/10 22:47 108-90-7217
Chloroethane ND ug/kg 50 03/03/10 22:47 75-00-3434
Chloroform ND ug/kg 50 03/03/10 22:47 67-66-3217
Chloromethane ND ug/kg 50 03/03/10 22:47 74-87-3434
2-Chlorotoluene ND ug/kg 50 03/03/10 22:47 95-49-8217
4-Chlorotoluene ND ug/kg 50 03/03/10 22:47 106-43-4217
1,2-Dibromo-3-chloropropane ND ug/kg 50 03/03/10 22:47 96-12-8217
Dibromochloromethane ND ug/kg 50 03/03/10 22:47 124-48-1217
1,2-Dibromoethane (EDB)ND ug/kg 50 03/03/10 22:47 106-93-4217
Dibromomethane ND ug/kg 50 03/03/10 22:47 74-95-3217
1,2-Dichlorobenzene ND ug/kg 50 03/03/10 22:47 95-50-1217
1,3-Dichlorobenzene ND ug/kg 50 03/03/10 22:47 541-73-1217
1,4-Dichlorobenzene ND ug/kg 50 03/03/10 22:47 106-46-7217
Dichlorodifluoromethane ND ug/kg 50 03/03/10 22:47 75-71-8 D3434
1,1-Dichloroethane ND ug/kg 50 03/03/10 22:47 75-34-3217
1,2-Dichloroethane ND ug/kg 50 03/03/10 22:47 107-06-2217
1,1-Dichloroethene ND ug/kg 50 03/03/10 22:47 75-35-4217
cis-1,2-Dichloroethene ND ug/kg 50 03/03/10 22:47 156-59-2217
trans-1,2-Dichloroethene ND ug/kg 50 03/03/10 22:47 156-60-5217
1,2-Dichloropropane ND ug/kg 50 03/03/10 22:47 78-87-5217
1,3-Dichloropropane ND ug/kg 50 03/03/10 22:47 142-28-9217
2,2-Dichloropropane ND ug/kg 50 03/03/10 22:47 594-20-7217
1,1-Dichloropropene ND ug/kg 50 03/03/10 22:47 563-58-6217
cis-1,3-Dichloropropene ND ug/kg 50 03/03/10 22:47 10061-01-5217
trans-1,3-Dichloropropene ND ug/kg 50 03/03/10 22:47 10061-02-6217
Diisopropyl ether ND ug/kg 50 03/03/10 22:47 108-20-3217
Ethylbenzene ND ug/kg 50 03/03/10 22:47 100-41-4217
Hexachloro-1,3-butadiene ND ug/kg 50 03/03/10 22:47 87-68-3217
2-Hexanone ND ug/kg 50 03/03/10 22:47 591-78-62170
Isopropylbenzene (Cumene)ND ug/kg 50 03/03/10 22:47 98-82-8217
p-Isopropyltoluene 505 ug/kg 50 03/03/10 22:47 99-87-6217
Methylene Chloride ND ug/kg 50 03/03/10 22:47 75-09-2869
4-Methyl-2-pentanone (MIBK)ND ug/kg 50 03/03/10 22:47 108-10-12170
Methyl-tert-butyl ether ND ug/kg 50 03/03/10 22:47 1634-04-4217
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 76 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:T5E-5 Lab ID:9264404030 Collected:02/26/10 15:10 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "dry-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene 463 ug/kg 50 03/03/10 22:47 91-20-3217
n-Propylbenzene ND ug/kg 50 03/03/10 22:47 103-65-1217
Styrene ND ug/kg 50 03/03/10 22:47 100-42-5217
1,1,1,2-Tetrachloroethane ND ug/kg 50 03/03/10 22:47 630-20-6217
1,1,2,2-Tetrachloroethane ND ug/kg 50 03/03/10 22:47 79-34-5217
Tetrachloroethene ND ug/kg 50 03/03/10 22:47 127-18-4217
Toluene ND ug/kg 50 03/03/10 22:47 108-88-3217
1,2,3-Trichlorobenzene ND ug/kg 50 03/03/10 22:47 87-61-6217
1,2,4-Trichlorobenzene ND ug/kg 50 03/03/10 22:47 120-82-1217
1,1,1-Trichloroethane ND ug/kg 50 03/03/10 22:47 71-55-6217
1,1,2-Trichloroethane ND ug/kg 50 03/03/10 22:47 79-00-5217
Trichloroethene ND ug/kg 50 03/03/10 22:47 79-01-6217
Trichlorofluoromethane ND ug/kg 50 03/03/10 22:47 75-69-4217
1,2,3-Trichloropropane ND ug/kg 50 03/03/10 22:47 96-18-4217
1,2,4-Trimethylbenzene ND ug/kg 50 03/03/10 22:47 95-63-6217
1,3,5-Trimethylbenzene ND ug/kg 50 03/03/10 22:47 108-67-8217
Vinyl acetate ND ug/kg 50 03/03/10 22:47 108-05-42170
Vinyl chloride ND ug/kg 50 03/03/10 22:47 75-01-4434
Xylene (Total)ND ug/kg 50 03/03/10 22:47 1330-20-7434
m&p-Xylene ND ug/kg 50 03/03/10 22:47 1330-20-7434
o-Xylene ND ug/kg 50 03/03/10 22:47 95-47-6217
Dibromofluoromethane (S)91 %50 03/03/10 22:47 1868-53-779-116
Toluene-d8 (S)101 %50 03/03/10 22:47 2037-26-588-110
4-Bromofluorobenzene (S)101 %50 03/03/10 22:47 460-00-474-115
1,2-Dichloroethane-d4 (S)103 %50 03/03/10 22:47 17060-07-069-121
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 10.4 %1 03/03/10 14:110.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 77 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:TRIP BLANK Lab ID:9264404031 Collected:02/26/10 00:00 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "wet-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Acetone ND ug/kg 1 03/03/10 16:04 67-64-1100
Benzene ND ug/kg 1 03/03/10 16:04 71-43-25.0
Bromobenzene ND ug/kg 1 03/03/10 16:04 108-86-15.0
Bromochloromethane ND ug/kg 1 03/03/10 16:04 74-97-55.0
Bromodichloromethane ND ug/kg 1 03/03/10 16:04 75-27-45.0
Bromoform ND ug/kg 1 03/03/10 16:04 75-25-25.0
Bromomethane ND ug/kg 1 03/03/10 16:04 74-83-910.0
2-Butanone (MEK)ND ug/kg 1 03/03/10 16:04 78-93-3100
n-Butylbenzene ND ug/kg 1 03/03/10 16:04 104-51-85.0
sec-Butylbenzene ND ug/kg 1 03/03/10 16:04 135-98-85.0
tert-Butylbenzene ND ug/kg 1 03/03/10 16:04 98-06-65.0
Carbon tetrachloride ND ug/kg 1 03/03/10 16:04 56-23-55.0
Chlorobenzene ND ug/kg 1 03/03/10 16:04 108-90-75.0
Chloroethane ND ug/kg 1 03/03/10 16:04 75-00-310.0
Chloroform ND ug/kg 1 03/03/10 16:04 67-66-35.0
Chloromethane ND ug/kg 1 03/03/10 16:04 74-87-310.0
2-Chlorotoluene ND ug/kg 1 03/03/10 16:04 95-49-85.0
4-Chlorotoluene ND ug/kg 1 03/03/10 16:04 106-43-45.0
1,2-Dibromo-3-chloropropane ND ug/kg 1 03/03/10 16:04 96-12-85.0
Dibromochloromethane ND ug/kg 1 03/03/10 16:04 124-48-15.0
1,2-Dibromoethane (EDB)ND ug/kg 1 03/03/10 16:04 106-93-45.0
Dibromomethane ND ug/kg 1 03/03/10 16:04 74-95-35.0
1,2-Dichlorobenzene ND ug/kg 1 03/03/10 16:04 95-50-15.0
1,3-Dichlorobenzene ND ug/kg 1 03/03/10 16:04 541-73-15.0
1,4-Dichlorobenzene ND ug/kg 1 03/03/10 16:04 106-46-75.0
Dichlorodifluoromethane ND ug/kg 1 03/03/10 16:04 75-71-810.0
1,1-Dichloroethane ND ug/kg 1 03/03/10 16:04 75-34-35.0
1,2-Dichloroethane ND ug/kg 1 03/03/10 16:04 107-06-25.0
1,1-Dichloroethene ND ug/kg 1 03/03/10 16:04 75-35-45.0
cis-1,2-Dichloroethene ND ug/kg 1 03/03/10 16:04 156-59-25.0
trans-1,2-Dichloroethene ND ug/kg 1 03/03/10 16:04 156-60-55.0
1,2-Dichloropropane ND ug/kg 1 03/03/10 16:04 78-87-55.0
1,3-Dichloropropane ND ug/kg 1 03/03/10 16:04 142-28-95.0
2,2-Dichloropropane ND ug/kg 1 03/03/10 16:04 594-20-75.0
1,1-Dichloropropene ND ug/kg 1 03/03/10 16:04 563-58-65.0
cis-1,3-Dichloropropene ND ug/kg 1 03/03/10 16:04 10061-01-55.0
trans-1,3-Dichloropropene ND ug/kg 1 03/03/10 16:04 10061-02-65.0
Diisopropyl ether ND ug/kg 1 03/03/10 16:04 108-20-35.0
Ethylbenzene ND ug/kg 1 03/03/10 16:04 100-41-45.0
Hexachloro-1,3-butadiene ND ug/kg 1 03/03/10 16:04 87-68-35.0
2-Hexanone ND ug/kg 1 03/03/10 16:04 591-78-650.0
Isopropylbenzene (Cumene)ND ug/kg 1 03/03/10 16:04 98-82-85.0
p-Isopropyltoluene ND ug/kg 1 03/03/10 16:04 99-87-65.0
Methylene Chloride ND ug/kg 1 03/03/10 16:04 75-09-220.0
4-Methyl-2-pentanone (MIBK)ND ug/kg 1 03/03/10 16:04 108-10-150.0
Methyl-tert-butyl ether ND ug/kg 1 03/03/10 16:04 1634-04-45.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 78 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Sample:TRIP BLANK Lab ID:9264404031 Collected:02/26/10 00:00 Received:03/02/10 17:00 Matrix:Solid
Results reported on a "wet-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
8260/5035A Volatile Organics Analytical Method: EPA 8260
Naphthalene ND ug/kg 1 03/03/10 16:04 91-20-35.0
n-Propylbenzene ND ug/kg 1 03/03/10 16:04 103-65-15.0
Styrene ND ug/kg 1 03/03/10 16:04 100-42-55.0
1,1,1,2-Tetrachloroethane ND ug/kg 1 03/03/10 16:04 630-20-65.0
1,1,2,2-Tetrachloroethane ND ug/kg 1 03/03/10 16:04 79-34-55.0
Tetrachloroethene ND ug/kg 1 03/03/10 16:04 127-18-45.0
Toluene ND ug/kg 1 03/03/10 16:04 108-88-35.0
1,2,3-Trichlorobenzene ND ug/kg 1 03/03/10 16:04 87-61-65.0
1,2,4-Trichlorobenzene ND ug/kg 1 03/03/10 16:04 120-82-15.0
1,1,1-Trichloroethane ND ug/kg 1 03/03/10 16:04 71-55-65.0
1,1,2-Trichloroethane ND ug/kg 1 03/03/10 16:04 79-00-55.0
Trichloroethene ND ug/kg 1 03/03/10 16:04 79-01-65.0
Trichlorofluoromethane ND ug/kg 1 03/03/10 16:04 75-69-45.0
1,2,3-Trichloropropane ND ug/kg 1 03/03/10 16:04 96-18-45.0
1,2,4-Trimethylbenzene ND ug/kg 1 03/03/10 16:04 95-63-65.0
1,3,5-Trimethylbenzene ND ug/kg 1 03/03/10 16:04 108-67-85.0
Vinyl acetate ND ug/kg 1 03/03/10 16:04 108-05-450.0
Vinyl chloride ND ug/kg 1 03/03/10 16:04 75-01-410.0
Xylene (Total)ND ug/kg 1 03/03/10 16:04 1330-20-710.0
m&p-Xylene ND ug/kg 1 03/03/10 16:04 1330-20-710.0
o-Xylene ND ug/kg 1 03/03/10 16:04 95-47-65.0
Dibromofluoromethane (S)93 %1 03/03/10 16:04 1868-53-779-116
Toluene-d8 (S)101 %1 03/03/10 16:04 2037-26-588-110
4-Bromofluorobenzene (S)98 %1 03/03/10 16:04 460-00-474-115
1,2-Dichloroethane-d4 (S)103 %1 03/03/10 16:04 17060-07-069-121
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 79 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9439
EPA 3546
EPA 8015 Modified
8015 Solid GCSV
Associated Lab Samples:9264404008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:411953
Associated Lab Samples:9264404008
Matrix:Solid
Analyzed
Diesel Components mg/kg ND 5.0 03/10/10 13:05
n-Pentacosane (S)%78 50-135 03/10/10 13:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
411954LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
411955
Diesel Components mg/kg 141167 84 50-11474124 13
n-Pentacosane (S)%97 50-13590
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
411956MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9264239001
411957
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Diesel Components mg/kg P3,P6191-1609 50-107-3387 23191198001670013300
n-Pentacosane (S)%S4050-1350
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 80 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9448
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Associated Lab Samples:9264404026, 9264404027, 9264404028, 9264404029, 9264404030
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:412236
Associated Lab Samples:9264404026, 9264404027, 9264404028, 9264404029, 9264404030
Matrix:Solid
Analyzed
Aliphatic (C09-C18)mg/kg ND 10.0 03/09/10 16:50
Aliphatic (C19-C36)mg/kg ND 10.0 03/09/10 16:50
Aromatic (C11-C22)mg/kg ND 10.0 03/09/10 16:50
2-Bromonaphthalene (S)%96 40-140 03/09/10 16:50
2-Fluorobiphenyl (S)%95 40-140 03/09/10 16:50
Nonatriacontane (S)%89 40-140 03/09/10 16:50
o-Terphenyl (S)%98 40-140 03/09/10 16:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
412237LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
412238
Aliphatic (C09-C18)mg/kg ND10 83 40-14085ND 50
Aliphatic (C19-C36)mg/kg 11.613.3 87 40-1409112.1 5 50
Aromatic (C11-C22)mg/kg 27.328.3 96 40-1408223.2 16 50
2-Bromonaphthalene (S)%93 40-14090
2-Fluorobiphenyl (S)%91 40-14087
Nonatriacontane (S)%89 40-14090
o-Terphenyl (S)%92 40-14079
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 81 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3891
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples:9264404009, 9264404011, 9264404012, 9264404013, 9264404014, 9264404015, 9264404016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:414517
Associated Lab Samples:9264404009, 9264404011, 9264404012, 9264404013, 9264404014, 9264404015, 9264404016
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 10.0 03/13/10 01:06
Aliphatic (C09-C12)mg/kg ND 10.0 03/13/10 01:06
Aromatic (C09-C10)mg/kg ND 10.0 03/13/10 01:06
2,5-Dibromotoluene (FID)(S)%113 70-130 03/13/10 01:06
2,5-Dibromotoluene (PID)(S)%109 70-130 03/13/10 01:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
414518LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
414519
Aliphatic (C05-C08)mg/kg 14.215 94 70-1309514.2 0 25
Aliphatic (C09-C12)mg/kg 15.915 106 30-13010415.7 2 25
Aromatic (C09-C10)mg/kg ND5 97 70-13096ND 25
2,5-Dibromotoluene (FID)(S)%123 70-130115
2,5-Dibromotoluene (PID)(S)%109 70-130104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 82 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/3897
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples:9264404017, 9264404018, 9264404019, 9264404020, 9264404021, 9264404022, 9264404023, 9264404024,
9264404025, 9264404026, 9264404027, 9264404028, 9264404029
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:414897
Associated Lab Samples:9264404017, 9264404018, 9264404019, 9264404020, 9264404021, 9264404022, 9264404023, 9264404024,
9264404025, 9264404026, 9264404027, 9264404028, 9264404029, 9264404030
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 10.0 03/13/10 16:14
Aliphatic (C09-C12)mg/kg ND 10.0 03/13/10 16:14
Aromatic (C09-C10)mg/kg ND 10.0 03/13/10 16:14
2,5-Dibromotoluene (FID)(S)%129 70-130 03/13/10 16:14
2,5-Dibromotoluene (PID)(S)%128 70-130 03/13/10 16:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
414898LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
414899
Aliphatic (C05-C08)mg/kg 15.015 100 70-13010215.3 2 25
Aliphatic (C09-C12)mg/kg 17.615 118 30-13011817.7 0 25
Aromatic (C09-C10)mg/kg ND5 100 70-130100ND 25
2,5-Dibromotoluene (FID)(S)%120 70-130112
2,5-Dibromotoluene (PID)(S)%106 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 83 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/9440
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:9264404026, 9264404027, 9264404028, 9264404029, 9264404030
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:411999
Associated Lab Samples:9264404026, 9264404027, 9264404028, 9264404029, 9264404030
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg ND 330 03/12/10 21:15
1,2-Dichlorobenzene ug/kg ND 330 03/12/10 21:15
1,3-Dichlorobenzene ug/kg ND 330 03/12/10 21:15
1,4-Dichlorobenzene ug/kg ND 330 03/12/10 21:15
1-Methylnaphthalene ug/kg ND 330 03/12/10 21:15
2,4,5-Trichlorophenol ug/kg ND 330 03/12/10 21:15
2,4,6-Trichlorophenol ug/kg ND 330 03/12/10 21:15
2,4-Dichlorophenol ug/kg ND 330 03/12/10 21:15
2,4-Dimethylphenol ug/kg ND 330 03/12/10 21:15
2,4-Dinitrophenol ug/kg ND 1650 03/12/10 21:15
2,4-Dinitrotoluene ug/kg ND 330 03/12/10 21:15
2,6-Dinitrotoluene ug/kg ND 330 03/12/10 21:15
2-Chloronaphthalene ug/kg ND 330 03/12/10 21:15
2-Chlorophenol ug/kg ND 330 03/12/10 21:15
2-Methylnaphthalene ug/kg ND 330 03/12/10 21:15
2-Methylphenol(o-Cresol)ug/kg ND 330 03/12/10 21:15
2-Nitroaniline ug/kg ND 1650 03/12/10 21:15
2-Nitrophenol ug/kg ND 330 03/12/10 21:15
3&4-Methylphenol(m&p Cresol)ug/kg ND 330 03/12/10 21:15
3,3'-Dichlorobenzidine ug/kg ND 1650 03/12/10 21:15
3-Nitroaniline ug/kg ND 1650 03/12/10 21:15
4,6-Dinitro-2-methylphenol ug/kg ND 660 03/12/10 21:15
4-Bromophenylphenyl ether ug/kg ND 330 03/12/10 21:15
4-Chloro-3-methylphenol ug/kg ND 660 03/12/10 21:15
4-Chloroaniline ug/kg ND 1650 03/12/10 21:15
4-Chlorophenylphenyl ether ug/kg ND 330 03/12/10 21:15
4-Nitroaniline ug/kg ND 660 03/12/10 21:15
4-Nitrophenol ug/kg ND 1650 03/12/10 21:15
Acenaphthene ug/kg ND 330 03/12/10 21:15
Acenaphthylene ug/kg ND 330 03/12/10 21:15
Aniline ug/kg ND 330 03/12/10 21:15
Anthracene ug/kg ND 330 03/12/10 21:15
Benzo(a)anthracene ug/kg ND 330 03/12/10 21:15
Benzo(a)pyrene ug/kg ND 330 03/12/10 21:15
Benzo(b)fluoranthene ug/kg ND 330 03/12/10 21:15
Benzo(g,h,i)perylene ug/kg ND 330 03/12/10 21:15
Benzo(k)fluoranthene ug/kg ND 330 03/12/10 21:15
Benzoic Acid ug/kg ND 1650 03/12/10 21:15
Benzyl alcohol ug/kg ND 660 03/12/10 21:15
bis(2-Chloroethoxy)methane ug/kg ND 330 03/12/10 21:15
bis(2-Chloroethyl) ether ug/kg ND 330 03/12/10 21:15
bis(2-Chloroisopropyl) ether ug/kg ND 330 03/12/10 21:15
bis(2-Ethylhexyl)phthalate ug/kg ND 330 03/12/10 21:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 84 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:411999
Associated Lab Samples:9264404026, 9264404027, 9264404028, 9264404029, 9264404030
Matrix:Solid
Analyzed
Butylbenzylphthalate ug/kg ND 330 03/12/10 21:15
Chrysene ug/kg ND 330 03/12/10 21:15
Di-n-butylphthalate ug/kg ND 330 03/12/10 21:15
Di-n-octylphthalate ug/kg ND 330 03/12/10 21:15
Dibenz(a,h)anthracene ug/kg ND 330 03/12/10 21:15
Dibenzofuran ug/kg ND 330 03/12/10 21:15
Diethylphthalate ug/kg ND 330 03/12/10 21:15
Dimethylphthalate ug/kg ND 330 03/12/10 21:15
Fluoranthene ug/kg ND 330 03/12/10 21:15
Fluorene ug/kg ND 330 03/12/10 21:15
Hexachloro-1,3-butadiene ug/kg ND 330 03/12/10 21:15
Hexachlorobenzene ug/kg ND 330 03/12/10 21:15
Hexachlorocyclopentadiene ug/kg ND 330 03/12/10 21:15
Hexachloroethane ug/kg ND 330 03/12/10 21:15
Indeno(1,2,3-cd)pyrene ug/kg ND 330 03/12/10 21:15
Isophorone ug/kg ND 330 03/12/10 21:15
N-Nitroso-di-n-propylamine ug/kg ND 330 03/12/10 21:15
N-Nitrosodimethylamine ug/kg ND 330 03/12/10 21:15
N-Nitrosodiphenylamine ug/kg ND 330 03/12/10 21:15
Naphthalene ug/kg ND 330 03/12/10 21:15
Nitrobenzene ug/kg ND 330 03/12/10 21:15
Pentachlorophenol ug/kg ND 1650 03/12/10 21:15
Phenanthrene ug/kg ND 330 03/12/10 21:15
Phenol ug/kg ND 330 03/12/10 21:15
Pyrene ug/kg ND 330 03/12/10 21:15
2,4,6-Tribromophenol (S)%53 44-136 03/12/10 21:15
2-Fluorobiphenyl (S)%48 46-120 03/12/10 21:15
2-Fluorophenol (S)%47 24-120 03/12/10 21:15
Nitrobenzene-d5 (S)%49 30-150 03/12/10 21:15
Phenol-d6 (S)%47 35-120 03/12/10 21:15
Terphenyl-d14 (S)%70 38-108 03/12/10 21:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
412000LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
412001
1,2,4-Trichlorobenzene ug/kg 10501670 63 50-150761270 19 30
1,2-Dichlorobenzene ug/kg 9881670 59 50-150721190 19 30
1,3-Dichlorobenzene ug/kg 9531670 57 50-150691150 19 30
1,4-Dichlorobenzene ug/kg 9531670 57 50-150691150 19 30
1-Methylnaphthalene ug/kg 11401670 68 50-150771280 12 30
2,4,5-Trichlorophenol ug/kg 11801670 71 50-150751240 5 30
2,4,6-Trichlorophenol ug/kg 11701670 70 50-150761260 7 30
2,4-Dichlorophenol ug/kg 12501670 75 50-150871450 15 30
2,4-Dimethylphenol ug/kg 10701670 64 50-150741230 14 30
2,4-Dinitrophenol ug/kg 48808330 59 20-111615080 4 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 85 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
412000LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
412001
2,4-Dinitrotoluene ug/kg 12301670 74 50-150761270 3 30
2,6-Dinitrotoluene ug/kg 12501670 75 50-150771290 3 30
2-Chloronaphthalene ug/kg 11601670 70 50-150781290 11 30
2-Chlorophenol ug/kg 9881670 59 50-150721200 20 30
2-Methylnaphthalene ug/kg 11201670 67 50-150761260 12 30
2-Methylphenol(o-Cresol)ug/kg 10901670 65 50-150741230 12 30
2-Nitroaniline ug/kg 59308330 71 50-150756210 5 30
2-Nitrophenol ug/kg 10501670 63 50-150751250 18 30
3&4-Methylphenol(m&p Cresol)ug/kg 11601670 69 50-150761270 10 30
3,3'-Dichlorobenzidine ug/kg 62408330 75 50-150736110 2 30
3-Nitroaniline ug/kg 49108330 59 50-150564690 5 30
4,6-Dinitro-2-methylphenol ug/kg 24503330 74 15-136772550 4 30
4-Bromophenylphenyl ether ug/kg 11801670 71 50-150741230 4 30
4-Chloro-3-methylphenol ug/kg 25003330 75 50-150782620 5 30
4-Chloroaniline ug/kg 56508330 68 50-150715910 5 30
4-Chlorophenylphenyl ether ug/kg 11701670 70 50-150731220 4 30
4-Nitroaniline ug/kg 55308330 66 50-150665470 1 30
4-Nitrophenol ug/kg 58708330 70 33-105746140 4 30
Acenaphthene ug/kg 11501670 69 50-150731220 6 30
Acenaphthylene ug/kg 11901670 72 50-150761270 6 30
Aniline ug/kg 9041670 54 50-150611020 12 30
Anthracene ug/kg 12601670 76 50-150791320 5 30
Benzo(a)anthracene ug/kg 13601670 81 50-150851420 4 30
Benzo(a)pyrene ug/kg 11901670 71 50-150751250 5 30
Benzo(b)fluoranthene ug/kg 11501670 69 50-150741230 7 30
Benzo(g,h,i)perylene ug/kg 12101670 73 24-117781300 7 30
Benzo(k)fluoranthene ug/kg 12901670 77 50-150801330 3 30
Benzoic Acid ug/kg 40208330 48 15-104494120 2 30
Benzyl alcohol ug/kg 23003330 69 50-150752510 9 30
bis(2-Chloroethoxy)methane ug/kg 10601670 64 50-150741230 15 30
bis(2-Chloroethyl) ether ug/kg 11001670 66 50-150841400 24 30
bis(2-Chloroisopropyl) ether ug/kg 9241670 55 50-150661100 18 30
bis(2-Ethylhexyl)phthalate ug/kg 11701670 70 50-150711180 1 30
Butylbenzylphthalate ug/kg 11501670 69 50-150751260 9 30
Chrysene ug/kg 13401670 80 50-150851420 6 30
Di-n-butylphthalate ug/kg 11001670 66 50-150701170 6 30
Di-n-octylphthalate ug/kg 11301670 68 50-150741230 8 30
Dibenz(a,h)anthracene ug/kg 12001670 72 17-128771280 6 30
Dibenzofuran ug/kg 11901670 71 50-150741230 4 30
Diethylphthalate ug/kg 10901670 66 50-150691150 5 30
Dimethylphthalate ug/kg 11001670 66 50-150691150 4 30
Fluoranthene ug/kg 12601670 76 50-150801340 6 30
Fluorene ug/kg 12101670 73 50-150751260 4 30
Hexachloro-1,3-butadiene ug/kg 10101670 61 50-150761260 22 30
Hexachlorobenzene ug/kg 12701670 76 50-150821370 8 30
Hexachlorocyclopentadiene ug/kg 9791670 59 15-114691150 16 30
Hexachloroethane ug/kg 9621670 58 50-150691150 17 30
Indeno(1,2,3-cd)pyrene ug/kg 12201670 73 19-128771290 5 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 86 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
412000LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
412001
Isophorone ug/kg 13401670 81 50-150891480 10 30
N-Nitroso-di-n-propylamine ug/kg 12101670 72 50-150781300 8 30
N-Nitrosodimethylamine ug/kg 8851670 53 50-150661100 22 30
N-Nitrosodiphenylamine ug/kg 12301670 74 50-150771280 4 30
Naphthalene ug/kg 10201670 61 50-150731220 18 30
Nitrobenzene ug/kg 10301670 62 50-150751240 18 30
Pentachlorophenol ug/kg 53408330 64 15-130665510 3 30
Phenanthrene ug/kg 12401670 74 50-150781290 4 30
Phenol ug/kg 10801670 65 42-120781290 18 30
Pyrene ug/kg 13501670 81 50-150861440 7 30
2,4,6-Tribromophenol (S)%78 44-13683
2-Fluorobiphenyl (S)%68 46-12073
2-Fluorophenol (S)%58 24-12074
Nitrobenzene-d5 (S)%62 30-15074
Phenol-d6 (S)%65 35-12076
Terphenyl-d14 (S)%79 38-10885
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
412002MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9264642008
412003
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/kg M021904550-15052 162190ND9761140
1,2-Dichlorobenzene ug/kg M021904550-15052 132190ND9921130
1,3-Dichlorobenzene ug/kg M021904550-15051 122190ND9821100
1,4-Dichlorobenzene ug/kg M021904550-15051 132190ND9861120
1-Methylnaphthalene ug/kg M021904850-15053 112190ND10401160
2,4,5-Trichlorophenol ug/kg M021904850-15049 32190ND10401080
2,4,6-Trichlorophenol ug/kg M021904850-15049 22190ND10501070
2,4-Dichlorophenol ug/kg 2190 52 50-15059 132190ND11301290
2,4-Dimethylphenol ug/kg M021904750-15052 92190ND10301130
2,4-Dinitrophenol ug/kg M0109003950-15041 510900ND42704480
2,4-Dinitrotoluene ug/kg M021904950-15051 42190ND10701110
2,6-Dinitrotoluene ug/kg 2190 51 50-15052 32190ND11101140
2-Chloronaphthalene ug/kg M021904750-15050 72190ND10201100
2-Chlorophenol ug/kg M021904550-15052 152190ND9821140
2-Methylnaphthalene ug/kg M021904650-15052 112190ND10201140
2-Methylphenol(o-Cresol)ug/kg M021904650-15055 182190ND10001200
2-Nitroaniline ug/kg M0109004850-15049 310900ND52105350
2-Nitrophenol ug/kg M021904550-15052 142190ND9811130
3&4-Methylphenol(m&p
Cresol)ug/kg M021904850-15055 132190ND10601210
3,3'-Dichlorobenzidine ug/kg 10900 54 50-15054 110900ND58905850
3-Nitroaniline ug/kg M0109004350-15040 710900ND46904380
4,6-Dinitro-2-methylphenol ug/kg 4370 50 50-15050 14370ND21902200
4-Bromophenylphenyl ether ug/kg M021904650-15046 02190ND10101010
4-Chloro-3-methylphenol ug/kg 4370 50 50-15053 54370ND21902300
4-Chloroaniline ug/kg M0109004550-15048 710900ND49005270
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 87 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
412002MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9264642008
412003
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
4-Chlorophenylphenyl ether ug/kg M021904650-15047 32190ND9981020
4-Nitroaniline ug/kg M0109004250-15043 310900ND45404700
4-Nitrophenol ug/kg M0109004750-15049 310900ND51805360
Acenaphthene ug/kg M021904550-15047 52190ND9871030
Acenaphthylene ug/kg M021904850-15050 52190ND10401090
Aniline ug/kg M021901150-150132190ND244J284J
Anthracene ug/kg 2190 50 50-15050 02190ND11001100
Benzo(a)anthracene ug/kg 2190 54 50-15054 02190ND11801180
Benzo(a)pyrene ug/kg M021904750-15047 22190ND10401020
Benzo(b)fluoranthene ug/kg M021904750-15045 32190ND1020984
Benzo(g,h,i)perylene ug/kg M021904750-15049 22190ND10401060
Benzo(k)fluoranthene ug/kg 2190 51 50-15050 22190ND11101090
Benzoic Acid ug/kg M0109001450-1501710900ND1510J1900J
Benzyl alcohol ug/kg M043704750-15053 114370ND20702330
bis(2-Chloroethoxy)methane ug/kg M021904550-15051 122190ND9841110
bis(2-Chloroethyl) ether ug/kg M021904850-15056 162190ND10401220
bis(2-Chloroisopropyl) ether ug/kg M021904250-15048 132190ND9231060
bis(2-Ethylhexyl)phthalate ug/kg M021904550-15046 12190ND988997
Butylbenzylphthalate ug/kg 2190 50 50-15050 02190ND11001100
Chrysene ug/kg 2190 56 50-15055 22190ND12301210
Di-n-butylphthalate ug/kg M021904450-15044 12190ND962972
Di-n-octylphthalate ug/kg M021905050-15049 22190ND10901060
Dibenz(a,h)anthracene ug/kg M021904850-15048 02190ND10601060
Dibenzofuran ug/kg M021904650-15049 52190ND10101060
Diethylphthalate ug/kg M021904750-15048 32190ND10201050
Dimethylphthalate ug/kg M021904550-15046 22190ND9821000
Fluoranthene ug/kg M021904950-15050 02190ND10801080
Fluorene ug/kg M021904850-15050 32190ND10501090
Hexachloro-1,3-butadiene ug/kg M021904450-15051 142190ND9721110
Hexachlorobenzene ug/kg 2190 50 50-15050 02190ND11001100
Hexachlorocyclopentadiene ug/kg M021904350-15048 122190ND9321050
Hexachloroethane ug/kg M021904450-15051 152190ND9561110
Indeno(1,2,3-cd)pyrene ug/kg M021904850-15048 12190ND10401050
Isophorone ug/kg 2190 56 50-15060 72190ND12301320
N-Nitroso-di-n-propylamine ug/kg 2190 51 50-15056 102190ND11101220
N-Nitrosodimethylamine ug/kg M021903850-15044 142190ND838969
N-Nitrosodiphenylamine ug/kg M021904850-15048 02190ND10501050
Naphthalene ug/kg M021904450-15051 152190ND9621120
Nitrobenzene ug/kg M021904450-15050 122190ND9701100
Pentachlorophenol ug/kg M0109004650-15047 210900ND50205110
Phenanthrene ug/kg M021904850-15048 02190ND10601060
Phenol ug/kg M021904650-15053 152190ND10001160
Pyrene ug/kg 2190 58 50-15056 32190ND12701230
2,4,6-Tribromophenol (S)%53 44-13653
2-Fluorobiphenyl (S)%46 46-12049
2-Fluorophenol (S)%46 24-12052
Nitrobenzene-d5 (S)%45 30-15052
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 88 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
412002MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
9264642008
412003
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Phenol-d6 (S)%47 35-12053
Terphenyl-d14 (S)%57 38-10856
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 89 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/10159
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9264404009, 9264404011, 9264404023, 9264404024, 9264404025, 9264404026, 9264404027, 9264404028,
9264404029, 9264404030, 9264404031
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:410162
Associated Lab Samples:9264404009, 9264404011, 9264404023, 9264404024, 9264404025, 9264404026, 9264404027, 9264404028,
9264404029, 9264404030, 9264404031
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 03/03/10 15:46
1,1,1-Trichloroethane ug/kg ND 5.0 03/03/10 15:46
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 03/03/10 15:46
1,1,2-Trichloroethane ug/kg ND 5.0 03/03/10 15:46
1,1-Dichloroethane ug/kg ND 5.0 03/03/10 15:46
1,1-Dichloroethene ug/kg ND 5.0 03/03/10 15:46
1,1-Dichloropropene ug/kg ND 5.0 03/03/10 15:46
1,2,3-Trichlorobenzene ug/kg ND 5.0 03/03/10 15:46
1,2,3-Trichloropropane ug/kg ND 5.0 03/03/10 15:46
1,2,4-Trichlorobenzene ug/kg ND 5.0 03/03/10 15:46
1,2,4-Trimethylbenzene ug/kg ND 5.0 03/03/10 15:46
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 03/03/10 15:46
1,2-Dibromoethane (EDB)ug/kg ND 5.0 03/03/10 15:46
1,2-Dichlorobenzene ug/kg ND 5.0 03/03/10 15:46
1,2-Dichloroethane ug/kg ND 5.0 03/03/10 15:46
1,2-Dichloropropane ug/kg ND 5.0 03/03/10 15:46
1,3,5-Trimethylbenzene ug/kg ND 5.0 03/03/10 15:46
1,3-Dichlorobenzene ug/kg ND 5.0 03/03/10 15:46
1,3-Dichloropropane ug/kg ND 5.0 03/03/10 15:46
1,4-Dichlorobenzene ug/kg ND 5.0 03/03/10 15:46
2,2-Dichloropropane ug/kg ND 5.0 03/03/10 15:46
2-Butanone (MEK)ug/kg ND 100 03/03/10 15:46
2-Chlorotoluene ug/kg ND 5.0 03/03/10 15:46
2-Hexanone ug/kg ND 50.0 03/03/10 15:46
4-Chlorotoluene ug/kg ND 5.0 03/03/10 15:46
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 03/03/10 15:46
Acetone ug/kg ND 100 03/03/10 15:46
Benzene ug/kg ND 5.0 03/03/10 15:46
Bromobenzene ug/kg ND 5.0 03/03/10 15:46
Bromochloromethane ug/kg ND 5.0 03/03/10 15:46
Bromodichloromethane ug/kg ND 5.0 03/03/10 15:46
Bromoform ug/kg ND 5.0 03/03/10 15:46
Bromomethane ug/kg ND 10.0 03/03/10 15:46
Carbon tetrachloride ug/kg ND 5.0 03/03/10 15:46
Chlorobenzene ug/kg ND 5.0 03/03/10 15:46
Chloroethane ug/kg ND 10.0 03/03/10 15:46
Chloroform ug/kg ND 5.0 03/03/10 15:46
Chloromethane ug/kg ND 10.0 03/03/10 15:46
cis-1,2-Dichloroethene ug/kg ND 5.0 03/03/10 15:46
cis-1,3-Dichloropropene ug/kg ND 5.0 03/03/10 15:46
Dibromochloromethane ug/kg ND 5.0 03/03/10 15:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 90 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:410162
Associated Lab Samples:9264404009, 9264404011, 9264404023, 9264404024, 9264404025, 9264404026, 9264404027, 9264404028,
9264404029, 9264404030, 9264404031
Matrix:Solid
Analyzed
Dibromomethane ug/kg ND 5.0 03/03/10 15:46
Dichlorodifluoromethane ug/kg ND 10.0 03/03/10 15:46
Diisopropyl ether ug/kg ND 5.0 03/03/10 15:46
Ethylbenzene ug/kg ND 5.0 03/03/10 15:46
Hexachloro-1,3-butadiene ug/kg ND 5.0 03/03/10 15:46
Isopropylbenzene (Cumene)ug/kg ND 5.0 03/03/10 15:46
m&p-Xylene ug/kg ND 10.0 03/03/10 15:46
Methyl-tert-butyl ether ug/kg ND 5.0 03/03/10 15:46
Methylene Chloride ug/kg ND 20.0 03/03/10 15:46
n-Butylbenzene ug/kg ND 5.0 03/03/10 15:46
n-Propylbenzene ug/kg ND 5.0 03/03/10 15:46
Naphthalene ug/kg ND 5.0 03/03/10 15:46
o-Xylene ug/kg ND 5.0 03/03/10 15:46
p-Isopropyltoluene ug/kg ND 5.0 03/03/10 15:46
sec-Butylbenzene ug/kg ND 5.0 03/03/10 15:46
Styrene ug/kg ND 5.0 03/03/10 15:46
tert-Butylbenzene ug/kg ND 5.0 03/03/10 15:46
Tetrachloroethene ug/kg ND 5.0 03/03/10 15:46
Toluene ug/kg ND 5.0 03/03/10 15:46
trans-1,2-Dichloroethene ug/kg ND 5.0 03/03/10 15:46
trans-1,3-Dichloropropene ug/kg ND 5.0 03/03/10 15:46
Trichloroethene ug/kg ND 5.0 03/03/10 15:46
Trichlorofluoromethane ug/kg ND 5.0 03/03/10 15:46
Vinyl acetate ug/kg ND 50.0 03/03/10 15:46
Vinyl chloride ug/kg ND 10.0 03/03/10 15:46
Xylene (Total)ug/kg ND 10.0 03/03/10 15:46
1,2-Dichloroethane-d4 (S)%101 69-121 03/03/10 15:46
4-Bromofluorobenzene (S)%99 74-115 03/03/10 15:46
Dibromofluoromethane (S)%93 79-116 03/03/10 15:46
Toluene-d8 (S)%102 88-110 03/03/10 15:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
410163LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 53.550 107 75-137
1,1,1-Trichloroethane ug/kg 56.650 113 70-140
1,1,2,2-Tetrachloroethane ug/kg 49.150 98 74-133
1,1,2-Trichloroethane ug/kg 54.150 108 79-129
1,1-Dichloroethane ug/kg 58.350 117 72-139
1,1-Dichloroethene ug/kg 58.450 117 69-154
1,1-Dichloropropene ug/kg 54.250 108 74-138
1,2,3-Trichlorobenzene ug/kg 71.550 143 71-150
1,2,3-Trichloropropane ug/kg 51.250 102 74-135
1,2,4-Trichlorobenzene ug/kg 79.7 L05015968-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 91 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
410163LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 61.950 124 70-130
1,2-Dibromo-3-chloropropane ug/kg 48.050 96 65-146
1,2-Dibromoethane (EDB)ug/kg 52.150 104 77-136
1,2-Dichlorobenzene ug/kg 60.150 120 75-141
1,2-Dichloroethane ug/kg 55.850 112 74-134
1,2-Dichloropropane ug/kg 55.550 111 77-138
1,3,5-Trimethylbenzene ug/kg 60.650 121 65-128
1,3-Dichlorobenzene ug/kg 62.450 125 76-133
1,3-Dichloropropane ug/kg 51.850 104 79-132
1,4-Dichlorobenzene ug/kg 62.250 124 75-137
2,2-Dichloropropane ug/kg 66.250 132 73-137
2-Butanone (MEK)ug/kg 108100 108 61-138
2-Chlorotoluene ug/kg 58.250 116 73-138
2-Hexanone ug/kg 104100 104 58-159
4-Chlorotoluene ug/kg 64.650 129 75-136
4-Methyl-2-pentanone (MIBK)ug/kg 114100 114 74-139
Acetone ug/kg 109100 109 58-150
Benzene ug/kg 53.750 107 71-140
Bromobenzene ug/kg 58.350 117 72-144
Bromochloromethane ug/kg 47.050 94 78-133
Bromodichloromethane ug/kg 53.550 107 78-133
Bromoform ug/kg 48.850 98 74-132
Bromomethane ug/kg 64.750 129 63-184
Carbon tetrachloride ug/kg 66.850 134 73-143
Chlorobenzene ug/kg 56.750 113 77-137
Chloroethane ug/kg 57.150 114 68-146
Chloroform ug/kg 53.850 108 75-137
Chloromethane ug/kg 49.050 98 54-143
cis-1,2-Dichloroethene ug/kg 55.950 112 71-143
cis-1,3-Dichloropropene ug/kg 57.450 115 76-133
Dibromochloromethane ug/kg 53.250 106 77-131
Dibromomethane ug/kg 58.150 116 63-184
Dichlorodifluoromethane ug/kg 40.550 81 36-173
Diisopropyl ether ug/kg 58.450 117 68-144
Ethylbenzene ug/kg 57.350 115 69-141
Hexachloro-1,3-butadiene ug/kg 63.150 126 70-152
Isopropylbenzene (Cumene)ug/kg 56.850 114 77-143
m&p-Xylene ug/kg 118100 118 72-138
Methyl-tert-butyl ether ug/kg 26.350 53 2-138
Methylene Chloride ug/kg 52.350 105 69-136
n-Butylbenzene ug/kg 65.7 L05013165-128
n-Propylbenzene ug/kg 62.650 125 72-139
Naphthalene ug/kg 64.850 130 61-138
o-Xylene ug/kg 58.650 117 74-137
p-Isopropyltoluene ug/kg 59.350 119 66-128
sec-Butylbenzene ug/kg 60.650 121 72-140
Styrene ug/kg 53.150 106 76-137
tert-Butylbenzene ug/kg 59.950 120 68-141
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 92 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
410163LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/kg 60.150 120 72-136
Toluene ug/kg 55.150 110 69-139
trans-1,2-Dichloroethene ug/kg 57.850 116 72-144
trans-1,3-Dichloropropene ug/kg 58.950 118 73-135
Trichloroethene ug/kg 56.650 113 75-136
Trichlorofluoromethane ug/kg 50.350 101 69-144
Vinyl acetate ug/kg 1280 L0100128050-150
Vinyl chloride ug/kg 48.050 96 61-145
Xylene (Total)ug/kg 176150 118 73-138
1,2-Dichloroethane-d4 (S)%101 69-121
4-Bromofluorobenzene (S)%101 74-115
Dibromofluoromethane (S)%92 79-116
Toluene-d8 (S)%101 88-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
410431MATRIX SPIKE SAMPLE:
MSSpike
Result
9264404023
1,1-Dichloroethene ug/kg 12892.6 138 33-158ND
Benzene ug/kg 10792.6 116 46-143ND
Chlorobenzene ug/kg 11192.6 120 29-159ND
Toluene ug/kg 11292.6 121 38-145ND
Trichloroethene ug/kg 11392.6 123 70-130ND
1,2-Dichloroethane-d4 (S)%109 69-121
4-Bromofluorobenzene (S)%100 74-115
Dibromofluoromethane (S)%94 79-116
Toluene-d8 (S)%100 88-110
Parameter Units
Dup
Result QualifiersRPDResult
9264382004
410430SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg NDND
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 93 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
Dup
Result QualifiersRPDResult
9264382004
410430SAMPLE DUPLICATE:
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg NDND
1,3-Dichlorobenzene ug/kg NDND
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg 71.4JND
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg NDND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg NDND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg NDND
m&p-Xylene ug/kg NDND
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg NDND
n-Butylbenzene ug/kg NDND
n-Propylbenzene ug/kg NDND
Naphthalene ug/kg NDND
o-Xylene ug/kg NDND
p-Isopropyltoluene ug/kg NDND
sec-Butylbenzene ug/kg NDND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg NDND
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 94 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
Dup
Result QualifiersRPDResult
9264382004
410430SAMPLE DUPLICATE:
Trichlorofluoromethane ug/kg NDND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
Xylene (Total)ug/kg NDND
1,2-Dichloroethane-d4 (S)%108 33108
4-Bromofluorobenzene (S)%93 3394
Dibromofluoromethane (S)%97 3397
Toluene-d8 (S)%100 34102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 95 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/10160
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:9264404012, 9264404013, 9264404014, 9264404015, 9264404016, 9264404017, 9264404018, 9264404019,
9264404020, 9264404021, 9264404022
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:410168
Associated Lab Samples:9264404012, 9264404013, 9264404014, 9264404015, 9264404016, 9264404017, 9264404018, 9264404019,
9264404020, 9264404021, 9264404022
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 03/03/10 15:27
1,1,1-Trichloroethane ug/kg ND 5.0 03/03/10 15:27
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 03/03/10 15:27
1,1,2-Trichloroethane ug/kg ND 5.0 03/03/10 15:27
1,1-Dichloroethane ug/kg ND 5.0 03/03/10 15:27
1,1-Dichloroethene ug/kg ND 5.0 03/03/10 15:27
1,1-Dichloropropene ug/kg ND 5.0 03/03/10 15:27
1,2,3-Trichlorobenzene ug/kg ND 5.0 03/03/10 15:27
1,2,3-Trichloropropane ug/kg ND 5.0 03/03/10 15:27
1,2,4-Trichlorobenzene ug/kg ND 5.0 03/03/10 15:27
1,2,4-Trimethylbenzene ug/kg ND 5.0 03/03/10 15:27
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 03/03/10 15:27
1,2-Dibromoethane (EDB)ug/kg ND 5.0 03/03/10 15:27
1,2-Dichlorobenzene ug/kg ND 5.0 03/03/10 15:27
1,2-Dichloroethane ug/kg ND 5.0 03/03/10 15:27
1,2-Dichloropropane ug/kg ND 5.0 03/03/10 15:27
1,3,5-Trimethylbenzene ug/kg ND 5.0 03/03/10 15:27
1,3-Dichlorobenzene ug/kg ND 5.0 03/03/10 15:27
1,3-Dichloropropane ug/kg ND 5.0 03/03/10 15:27
1,4-Dichlorobenzene ug/kg ND 5.0 03/03/10 15:27
2,2-Dichloropropane ug/kg ND 5.0 03/03/10 15:27
2-Butanone (MEK)ug/kg ND 100 03/03/10 15:27
2-Chlorotoluene ug/kg ND 5.0 03/03/10 15:27
2-Hexanone ug/kg ND 50.0 03/03/10 15:27
4-Chlorotoluene ug/kg ND 5.0 03/03/10 15:27
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 03/03/10 15:27
Acetone ug/kg ND 100 03/03/10 15:27
Benzene ug/kg ND 5.0 03/03/10 15:27
Bromobenzene ug/kg ND 5.0 03/03/10 15:27
Bromochloromethane ug/kg ND 5.0 03/03/10 15:27
Bromodichloromethane ug/kg ND 5.0 03/03/10 15:27
Bromoform ug/kg ND 5.0 03/03/10 15:27
Bromomethane ug/kg ND 10.0 03/03/10 15:27
Carbon tetrachloride ug/kg ND 5.0 03/03/10 15:27
Chlorobenzene ug/kg ND 5.0 03/03/10 15:27
Chloroethane ug/kg ND 10.0 03/03/10 15:27
Chloroform ug/kg ND 5.0 03/03/10 15:27
Chloromethane ug/kg ND 10.0 03/03/10 15:27
cis-1,2-Dichloroethene ug/kg ND 5.0 03/03/10 15:27
cis-1,3-Dichloropropene ug/kg ND 5.0 03/03/10 15:27
Dibromochloromethane ug/kg ND 5.0 03/03/10 15:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 96 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:410168
Associated Lab Samples:9264404012, 9264404013, 9264404014, 9264404015, 9264404016, 9264404017, 9264404018, 9264404019,
9264404020, 9264404021, 9264404022
Matrix:Solid
Analyzed
Dibromomethane ug/kg ND 5.0 03/03/10 15:27
Dichlorodifluoromethane ug/kg ND 10.0 03/03/10 15:27
Diisopropyl ether ug/kg ND 5.0 03/03/10 15:27
Ethylbenzene ug/kg ND 5.0 03/03/10 15:27
Hexachloro-1,3-butadiene ug/kg ND 5.0 03/03/10 15:27
Isopropylbenzene (Cumene)ug/kg ND 5.0 03/03/10 15:27
m&p-Xylene ug/kg ND 10.0 03/03/10 15:27
Methyl-tert-butyl ether ug/kg ND 5.0 03/03/10 15:27
Methylene Chloride ug/kg ND 20.0 03/03/10 15:27
n-Butylbenzene ug/kg ND 5.0 03/03/10 15:27
n-Propylbenzene ug/kg ND 5.0 03/03/10 15:27
Naphthalene ug/kg ND 5.0 03/03/10 15:27
o-Xylene ug/kg ND 5.0 03/03/10 15:27
p-Isopropyltoluene ug/kg ND 5.0 03/03/10 15:27
sec-Butylbenzene ug/kg ND 5.0 03/03/10 15:27
Styrene ug/kg ND 5.0 03/03/10 15:27
tert-Butylbenzene ug/kg ND 5.0 03/03/10 15:27
Tetrachloroethene ug/kg ND 5.0 03/03/10 15:27
Toluene ug/kg ND 5.0 03/03/10 15:27
trans-1,2-Dichloroethene ug/kg ND 5.0 03/03/10 15:27
trans-1,3-Dichloropropene ug/kg ND 5.0 03/03/10 15:27
Trichloroethene ug/kg ND 5.0 03/03/10 15:27
Trichlorofluoromethane ug/kg ND 5.0 03/03/10 15:27
Vinyl acetate ug/kg ND 50.0 03/03/10 15:27
Vinyl chloride ug/kg ND 10.0 03/03/10 15:27
Xylene (Total)ug/kg ND 10.0 03/03/10 15:27
1,2-Dichloroethane-d4 (S)%102 69-121 03/03/10 15:27
4-Bromofluorobenzene (S)%99 74-115 03/03/10 15:27
Dibromofluoromethane (S)%92 79-116 03/03/10 15:27
Toluene-d8 (S)%101 88-110 03/03/10 15:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
410169LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 55.750 111 75-137
1,1,1-Trichloroethane ug/kg 57.850 116 70-140
1,1,2,2-Tetrachloroethane ug/kg 51.250 102 74-133
1,1,2-Trichloroethane ug/kg 55.750 111 79-129
1,1-Dichloroethane ug/kg 58.050 116 72-139
1,1-Dichloroethene ug/kg 59.850 120 69-154
1,1-Dichloropropene ug/kg 54.850 110 74-138
1,2,3-Trichlorobenzene ug/kg 74.650 149 71-150
1,2,3-Trichloropropane ug/kg 52.550 105 74-135
1,2,4-Trichlorobenzene ug/kg 84.3 L05016968-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 97 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
410169LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 64.250 128 70-130
1,2-Dibromo-3-chloropropane ug/kg 49.850 100 65-146
1,2-Dibromoethane (EDB)ug/kg 54.050 108 77-136
1,2-Dichlorobenzene ug/kg 61.950 124 75-141
1,2-Dichloroethane ug/kg 58.350 117 74-134
1,2-Dichloropropane ug/kg 56.350 113 77-138
1,3,5-Trimethylbenzene ug/kg 62.250 124 65-128
1,3-Dichlorobenzene ug/kg 64.950 130 76-133
1,3-Dichloropropane ug/kg 54.350 109 79-132
1,4-Dichlorobenzene ug/kg 65.050 130 75-137
2,2-Dichloropropane ug/kg 67.350 135 73-137
2-Butanone (MEK)ug/kg 105100 105 61-138
2-Chlorotoluene ug/kg 60.550 121 73-138
2-Hexanone ug/kg 106100 106 58-159
4-Chlorotoluene ug/kg 66.150 132 75-136
4-Methyl-2-pentanone (MIBK)ug/kg 117100 117 74-139
Acetone ug/kg 112100 112 58-150
Benzene ug/kg 54.250 108 71-140
Bromobenzene ug/kg 61.350 123 72-144
Bromochloromethane ug/kg 46.450 93 78-133
Bromodichloromethane ug/kg 53.850 108 78-133
Bromoform ug/kg 50.750 101 74-132
Bromomethane ug/kg 68.850 138 63-184
Carbon tetrachloride ug/kg 58.650 117 73-143
Chlorobenzene ug/kg 59.450 119 77-137
Chloroethane ug/kg 59.950 120 68-146
Chloroform ug/kg 53.950 108 75-137
Chloromethane ug/kg 51.550 103 54-143
cis-1,2-Dichloroethene ug/kg 58.150 116 71-143
cis-1,3-Dichloropropene ug/kg 58.650 117 76-133
Dibromochloromethane ug/kg 55.250 110 77-131
Dibromomethane ug/kg 58.450 117 63-184
Dichlorodifluoromethane ug/kg 42.450 85 36-173
Diisopropyl ether ug/kg 60.150 120 68-144
Ethylbenzene ug/kg 59.650 119 69-141
Hexachloro-1,3-butadiene ug/kg 65.550 131 70-152
Isopropylbenzene (Cumene)ug/kg 58.950 118 77-143
m&p-Xylene ug/kg 121100 121 72-138
Methyl-tert-butyl ether ug/kg 21.150 42 2-138
Methylene Chloride ug/kg 54.050 108 69-136
n-Butylbenzene ug/kg 67.9 L05013665-128
n-Propylbenzene ug/kg 64.950 130 72-139
Naphthalene ug/kg 66.350 133 61-138
o-Xylene ug/kg 61.550 123 74-137
p-Isopropyltoluene ug/kg 60.950 122 66-128
sec-Butylbenzene ug/kg 62.850 126 72-140
Styrene ug/kg 56.050 112 76-137
tert-Butylbenzene ug/kg 61.850 124 68-141
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 98 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
410169LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/kg 63.550 127 72-136
Toluene ug/kg 55.950 112 69-139
trans-1,2-Dichloroethene ug/kg 59.050 118 72-144
trans-1,3-Dichloropropene ug/kg 58.750 117 73-135
Trichloroethene ug/kg 57.750 115 75-136
Trichlorofluoromethane ug/kg 52.150 104 69-144
Vinyl acetate ug/kg 1410 L0100141350-150
Vinyl chloride ug/kg 49.950 100 61-145
Xylene (Total)ug/kg 183150 122 73-138
1,2-Dichloroethane-d4 (S)%97 69-121
4-Bromofluorobenzene (S)%102 74-115
Dibromofluoromethane (S)%92 79-116
Toluene-d8 (S)%100 88-110
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
410429MATRIX SPIKE SAMPLE:
MSSpike
Result
9264404022
1,1-Dichloroethene ug/kg 59.341.8 142 33-158ND
Benzene ug/kg 50.441.8 121 46-143ND
Chlorobenzene ug/kg 51.541.8 123 29-159ND
Toluene ug/kg 51.941.8 124 38-145ND
Trichloroethene ug/kg 51.841.8 124 70-130ND
1,2-Dichloroethane-d4 (S)%108 69-121
4-Bromofluorobenzene (S)%102 74-115
Dibromofluoromethane (S)%93 79-116
Toluene-d8 (S)%100 88-110
Parameter Units
Dup
Result QualifiersRPDResult
9264404017
410428SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg 3.3JND
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 99 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
Dup
Result QualifiersRPDResult
9264404017
410428SAMPLE DUPLICATE:
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg NDND
1,3-Dichlorobenzene ug/kg NDND
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg NDND
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg NDND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg NDND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg 3.6JND
m&p-Xylene ug/kg 4.3JND
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg NDND
n-Butylbenzene ug/kg NDND
n-Propylbenzene ug/kg NDND
Naphthalene ug/kg 3.1JND
o-Xylene ug/kg 3.1JND
p-Isopropyltoluene ug/kg NDND
sec-Butylbenzene ug/kg NDND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg 4.8ND
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 100 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Parameter Units
Dup
Result QualifiersRPDResult
9264404017
410428SAMPLE DUPLICATE:
Trichlorofluoromethane ug/kg 3.9JND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
Xylene (Total)ug/kg 7.3JND
1,2-Dichloroethane-d4 (S)%106 11103
4-Bromofluorobenzene (S)%99 17102
Dibromofluoromethane (S)%96 19101
Toluene-d8 (S)%101 15102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 101 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3048
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9264404001, 9264404002, 9264404003, 9264404004, 9264404005, 9264404006, 9264404007, 9264404008
Parameter Units
Dup
Result QualifiersRPDResult
9263769003
409703SAMPLE DUPLICATE:
Percent Moisture %16.0 116.1
Parameter Units
Dup
Result QualifiersRPDResult
9264404008
409704SAMPLE DUPLICATE:
Percent Moisture %18.2 417.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 102 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3049
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9264404009, 9264404010, 9264404011, 9264404012, 9264404013, 9264404014, 9264404015, 9264404016,
9264404017, 9264404018, 9264404019, 9264404020, 9264404021, 9264404022, 9264404023, 9264404024,
9264404025, 9264404026, 9264404027, 9264404028
Parameter Units
Dup
Result QualifiersRPDResult
9264404024
409706SAMPLE DUPLICATE:
Percent Moisture %11.6 1112.9
Parameter Units
Dup
Result QualifiersRPDResult
9264404009
409707SAMPLE DUPLICATE:
Percent Moisture %22.5 223.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 103 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3050
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:9264404029, 9264404030
Parameter Units
Dup
Result QualifiersRPDResult
9263905001
409713SAMPLE DUPLICATE:
Percent Moisture %47.9 550.3
Parameter Units
Dup
Result QualifiersRPDResult
9264403015
409714SAMPLE DUPLICATE:
Percent Moisture %21.1 320.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 104 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Non homogenous sample.1g
Common Laboratory Contaminant.C9
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Sample extract could not be concentrated to the routine final volume, resulting in elevated reporting limits.P3
Matrix spike recovery was outside laboratory control limits due to a parent sample concentration notably higher than the
spike level.P6
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample
re-analysis).S2
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples.
Results unaffected by high bias.S3
Surrogate recovery not evaluated against control limits due to sample dilution.S4
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 105 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9264404008 OEXT/9439 GCSV/7285T5-4'EPA 3546 EPA 8015 Modified
9264404026 OEXT/9448 GCSV/7286T5E-1 MADEP EPH MADEP EPH
9264404027 OEXT/9448 GCSV/7286T5E-2 MADEP EPH MADEP EPH
9264404028 OEXT/9448 GCSV/7286T5E-3 MADEP EPH MADEP EPH
9264404029 OEXT/9448 GCSV/7286T5E-4 MADEP EPH MADEP EPH
9264404030 OEXT/9448 GCSV/7286T5E-5 MADEP EPH MADEP EPH
9264404009 GCV/3891 GCV/3892PL1-3'MADEP VPH MADEP VPH
9264404011 GCV/3891 GCV/38922KTE-4 MADEP VPH MADEP VPH
9264404012 GCV/3891 GCV/38922KTE-5 MADEP VPH MADEP VPH
9264404013 GCV/3891 GCV/38922KTE-1 MADEP VPH MADEP VPH
9264404014 GCV/3891 GCV/38922KTE-2 MADEP VPH MADEP VPH
9264404015 GCV/3891 GCV/38922KTE-3 MADEP VPH MADEP VPH
9264404016 GCV/3891 GCV/3892T3E-1 MADEP VPH MADEP VPH
9264404017 GCV/3897 GCV/3898T3E-2 MADEP VPH MADEP VPH
9264404018 GCV/3897 GCV/3898T3E-3 MADEP VPH MADEP VPH
9264404019 GCV/3897 GCV/3898T3E-4 MADEP VPH MADEP VPH
9264404020 GCV/3897 GCV/3898T3E-5 MADEP VPH MADEP VPH
9264404021 GCV/3897 GCV/3898T4E-1 MADEP VPH MADEP VPH
9264404022 GCV/3897 GCV/3898T4E-2 MADEP VPH MADEP VPH
9264404023 GCV/3897 GCV/3898T4E-3 MADEP VPH MADEP VPH
9264404024 GCV/3897 GCV/3898T4E-4 MADEP VPH MADEP VPH
9264404025 GCV/3897 GCV/3898T4E-5 MADEP VPH MADEP VPH
9264404026 GCV/3897 GCV/3898T5E-1 MADEP VPH MADEP VPH
9264404027 GCV/3897 GCV/3898T5E-2 MADEP VPH MADEP VPH
9264404028 GCV/3897 GCV/3898T5E-3 MADEP VPH MADEP VPH
9264404029 GCV/3897 GCV/3898T5E-4 MADEP VPH MADEP VPH
9264404030 GCV/3897 GCV/3898T5E-5 MADEP VPH MADEP VPH
9264404026 OEXT/9440 MSSV/3396T5E-1 EPA 3546 EPA 8270
9264404027 OEXT/9440 MSSV/3396T5E-2 EPA 3546 EPA 8270
9264404028 OEXT/9440 MSSV/3396T5E-3 EPA 3546 EPA 8270
9264404029 OEXT/9440 MSSV/3396T5E-4 EPA 3546 EPA 8270
9264404030 OEXT/9440 MSSV/3396T5E-5 EPA 3546 EPA 8270
9264404009 MSV/10159PL1-3'EPA 8260
9264404011 MSV/101592KTE-4 EPA 8260
9264404012 MSV/101602KTE-5 EPA 8260
9264404013 MSV/101602KTE-1 EPA 8260
9264404014 MSV/101602KTE-2 EPA 8260
9264404015 MSV/101602KTE-3 EPA 8260
9264404016 MSV/10160T3E-1 EPA 8260
9264404017 MSV/10160T3E-2 EPA 8260
9264404018 MSV/10160T3E-3 EPA 8260
9264404019 MSV/10160T3E-4 EPA 8260
9264404020 MSV/10160T3E-5 EPA 8260
9264404021 MSV/10160T4E-1 EPA 8260
9264404022 MSV/10160T4E-2 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 106 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
9264404
CARAWAY GROC. 2009311
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
9264404023 MSV/10159T4E-3 EPA 8260
9264404024 MSV/10159T4E-4 EPA 8260
9264404025 MSV/10159T4E-5 EPA 8260
9264404026 MSV/10159T5E-1 EPA 8260
9264404027 MSV/10159T5E-2 EPA 8260
9264404028 MSV/10159T5E-3 EPA 8260
9264404029 MSV/10159T5E-4 EPA 8260
9264404030 MSV/10159T5E-5 EPA 8260
9264404031 MSV/10159TRIP BLANK EPA 8260
9264404001 PMST/3048T1A-8'ASTM D2974-87
9264404002 PMST/3048T1B-8'ASTM D2974-87
9264404003 PMST/3048T2A-8'ASTM D2974-87
9264404004 PMST/3048T2B-8'ASTM D2974-87
9264404005 PMST/3048T3-6'ASTM D2974-87
9264404006 PMST/3048T4A-6'ASTM D2974-87
9264404007 PMST/3048T4B-6'ASTM D2974-87
9264404008 PMST/3048T5-4'ASTM D2974-87
9264404009 PMST/3049PL1-3'ASTM D2974-87
9264404010 PMST/3049PL2-3'ASTM D2974-87
9264404011 PMST/30492KTE-4 ASTM D2974-87
9264404012 PMST/30492KTE-5 ASTM D2974-87
9264404013 PMST/30492KTE-1 ASTM D2974-87
9264404014 PMST/30492KTE-2 ASTM D2974-87
9264404015 PMST/30492KTE-3 ASTM D2974-87
9264404016 PMST/3049T3E-1 ASTM D2974-87
9264404017 PMST/3049T3E-2 ASTM D2974-87
9264404018 PMST/3049T3E-3 ASTM D2974-87
9264404019 PMST/3049T3E-4 ASTM D2974-87
9264404020 PMST/3049T3E-5 ASTM D2974-87
9264404021 PMST/3049T4E-1 ASTM D2974-87
9264404022 PMST/3049T4E-2 ASTM D2974-87
9264404023 PMST/3049T4E-3 ASTM D2974-87
9264404024 PMST/3049T4E-4 ASTM D2974-87
9264404025 PMST/3049T4E-5 ASTM D2974-87
9264404026 PMST/3049T5E-1 ASTM D2974-87
9264404027 PMST/3049T5E-2 ASTM D2974-87
9264404028 PMST/3049T5E-3 ASTM D2974-87
9264404029 PMST/3050T5E-4 ASTM D2974-87
9264404030 PMST/3050T5E-5 ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Date: 03/15/2010 05:37 PM Page 107 of 107
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]