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HomeMy WebLinkAboutWS-9716_44919_CA_MRP_20230227 Groundwater Monitoring Report Crossroads Center-C 134 Arnold Road Lexington, Davidson County, North Carolina 27295 NCDEQ Incident #44919 ATC Project # SLC4491902 Submittal Date: February 27, 2023 Prepared for: North Carolina Department of Environmental Quality Division of Waste Management – Underground Storage Tank Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Prepared By: ATC Associates of North Carolina, P.C. 7606 Whitehall Executive Center Drive, Suite 800 Charlotte, North Carolina 28273 p: (704) 529-3200 / f: (704) 529-3272 7606 Whitehall Executive Center Drive Suite 800 Charlotte, NC 28273 Tel: 704-529-3200 Fax: 704-529-3272 www.atcgroupservices.com N.C. Engineering License No. C-1598 February 27, 2023 Mr. Scott Ryals, P.E. North Carolina Department of Environmental Quality Division of Waste Management - Underground Storage Tank Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Re: Groundwater Monitoring Report Crossroads Center-C 134 Arnold Road Lexington, Davidson County, North Carolina 27295 NCDEQ Incident #44919 ATC Project #SLC4491902 Task Authorization: TA-02 Dear Mr. Ryals: ATC Associates of North Carolina, P.C., under contract to the North Carolina Department of Environmental Quality, submits the enclosed Groundwater Monitoring Report for Crossroads Center-C. The report presents investigative procedures, field activities, and laboratory analytical results for the January 9, 2023, monitoring well installation and the January 13, 2023, groundwater monitoring event conducted at the site. If you have any questions or require additional information, please contact our office at (704) 529-3200. Sincerely, ATC Associates of North Carolina, P.C. Kyle Harris Al Quarles, P.G. Staff Scientist Senior Project Manager Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 TABLE OF CONTENTS 1.0 SITE IDENTIFICATION .......................................................................... 1 2.0 EXECUTIVE SUMMARY ........................................................................ 2 3.0 SITE DESCRIPTION .............................................................................. 3 3.1 Site Characterization.................................................................... 3 3.2 Site Background .......................................................................... 3 3.3 Site and Regional Geology .......................................................... 4 3.4 Site and Regional Hydrogeology ................................................. 5 4.0 GROUNDWATER CHARACTERIZATION............................................. 5 4.1 Access Agreements and Well Permits ......................................... 5 4.2 Monitoring Well Installation .......................................................... 6 4.3 Groundwater Levels ..................................................................... 6 4.4 Groundwater Quality .................................................................... 7 5.0 CONCLUSIONS AND RECOMMENDATIONS ...................................... 8 FIGURES Figure 1 Site Vicinity Map Figure 2 Site Map Figure 3 Receptor Survey Map Figure 4 Groundwater Elevation Map Figure 5 Groundwater Analytical Map TABLES Table 1 Well Construction and Groundwater Elevation Data Table 2 Field Parameters Table 3 Recent Groundwater Analytical Results Table 4 Historical Groundwater Analytical Results Table 5 Conceptual Site Model APPENDICES Appendix A Access Agreements, Well Permit Applications, and Well Permits Appendix B Well Construction Records and Soil Boring Logs Appendix C Field Notes and Photographs Appendix D Laboratory Report GroundwaterMonitoringReportCrossroadsCenter-C,Lexington,NC(IncidentNo44919)February27,2023ATCProject#SLC44919021.0SITEIDENTIFICATION1.SiteIdentificationDateofReport:February27,2023FacilityI.D.:00-0-0000029082USTIncidentNumber(ifknown):44919SiteRisk:IntermediateSiteRank:135DLandUseCategory:CommercialSiteName:CrossroadsCenter-CSiteStreetAddress:134ArnoldRoadCity/Town:LexingtonDescriptionofGeographicalDataPoint:Centerofon-sitecanopyLocationMethod:GoogleEarthLatitude(decimaldegrees):35.867193°Longitude(decimaldegrees):-80.250738°ZipCode:27295County:Davidson2.InformationaboutContactsAssociatedwiththeLeakingUSTSystemUSTOwner:24/7/365,IncAddress:1545LewisvilleClemmonsRoadUSTOperator:24/7/365,IncAddress:1545LewisvilleClemmonsRoadPropertyOwner:24/7/365,Inc,Address:1545LewisvilleClemmonsRoad,Clemmons,NC27012PropertyOccupant:VacantAddress:NotAvailableConsultant/Contractor:ATCAssociatesofNorthCarolina,P.C.Address:7606WhitehallExecCtrDr,Ste800,Charlotte,NC28273Tel.:704-529-3200AnalyticalLaboratory:PaceAnalyticalServices,LLCAddress:9800KincevAve.,Suite100,Huntersville,NC28078Tel:704-529-6364Tel.:(336)816-6133Tel.:(336)816-6133Tel.:(336)816-6133Tel:NotAvailableStateCertificationNo.123.InformationaboutReleaseDateDiscovered:09/21/2017EstimatedQuantityofRelease:UnknownCauseofRelease:UnknownSourceofRelease(Dispenser/Piping/UST):GasolineandDieselUSTsSizesandcontentsofUSTsystem(s)fromwhichthereleaseoccurred:One3,000-qallondiesel,two6,000-qallongasolineUSTs,andone5,000-qallongasolineUST.CriteriaUsedtoClassifyRisk:GroundwatercontaminantshavebeenfoundaboveGCLs4.InformationabouttheMonitoringReportDate(s)ofMonitoringWellInstallation:January9,2023Date(s)ofGroundwaterMonitoringEvents(s):January13,20235.CertificationI,AlQuarles,aLicensedGeologistforATCAssociatesofNorthCarolina,P.C.,docertifythattheinformationcontainedinthisreportiscorrectandaccuratetothebestofmyknowledge.ATCAssociatesofNorthCarolina,P.C.islicensedtopracticeengineeringandgeologyinNorthCarolina.ThecertificationnumberofthecompanyorcorporationisC-1598forengineeringandC-274forgeology.1 Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 2 2.0 EXECUTIVE SUMMARY ATC Associates of North Carolina, P.C. (ATC) has completed a Groundwater Monitoring Report (GMR), documenting the monitoring well installation on January 9, 2023, and the groundwater monitoring event on January 13, 2023, at the Crossroads Center-C site. The report has been completed based on a September 12, 2022, Task Authorization (TA-02) by the Trust Fund Branch of the UST Section, Division of Waste Management, North Carolina Department of Environmental Quality (NCDEQ). The work was performed as part of the State Lead Contract #N122019A between the NCDEQ and ATC. In accordance with TA-02, two monitoring wells were installed (MW-12 and MW-13) after obtaining access agreements with the two property owners and well permits from the NCDEQ. A groundwater monitoring event was conducted at the site by ATC with the sampling of monitoring wells MW-1, MW-3, MW-10, MW-12, and MW-13. Groundwater samples were analyzed for volatile organic compounds (VOCs). Concentrations were compared to the Gross Contamination Levels (GCLs) and the North Carolina 15A NCAC 2L .0202 groundwater quality standards (2L Standards). The purpose of the new wells MW-12 and MW-13 was to evaluate the extent of the GCL exceedance to the west and south of monitoring wells MW-3. The findings from the recent and historical activities indicate the following:  There are no water supply wells within 1,000 feet of the source area or surface water bodies within 500 feet of the source area;  Municipal water is provided to the area;  Light non-aqueous phase liquid (LNAPL) was not detected in the monitoring wells;  Benzene (6,590 micrograms per liter or µg/L) was detected in well MW-10 above the GCL of 5,000 µg/L;  VOCs exceeded the 2L Standards in MW-1, MW-3, MW-10, MW-12, and MW-13; and  The monitoring wells are 1-inch diameter wells, excluding MW-10, MW-12, and MW-13 that are 2-inch diameter wells; and  The depth to groundwater ranged from 6.69 feet below top of casing (ft-toc) in MW-13 to 10.59 ft-toc in MW-2, and groundwater flow is indicated to be to the south-southwest. Benzene in wells MW-3 and MW-10 and naphthalene in well MW-10 exceeded the GCLs in October 2021. Benzene in well MW-10 was the only VOC exceeding the GCL in January 2023, and the concentration increased by approximately 11% since October 2021. Benzene in MW-3 decreased by approximately 50% since October 2021. Naphthalene in MW-10 also decreased by approximately 95%, however, the concentration was similar to that reported in February of 2018 and in April and June of 2019. Excluding the benzene in MW-10, concentrations of VOCs decreased in wells MW-1, MW-3, and MW-10. The extent of the GCLs is defined with the additional wells MW-12 and MW-13. The January 2023 VOC concentrations in the downgradient well MW-13 were approximately 3% or less of those in MW-3, excluding tert-amyl alcohol that was approximately 11%. The January 13, 2023 groundwater levels were approximately 3.3 feet higher than the October 8, 2021 groundwater levels, with groundwater levels above the screen in wells MW-1, MW-3, and MW-4. Historically, concentrations of benzene in well MW-10 have increased with rising groundwater levels and decrease with falling groundwater levels, suggesting a possible zone of contaminated soil near the seasonal high groundwater levels. Note that the recent increase in benzene concentration in MW-10 appears to be less than prior increases suggesting natural degradation is occurring. Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 3 Based on the findings, ATC recommends the following:  Conduct a combined Mobile Multi-Phase Extraction (MMPE) and Ozone Injection (OI) event, using wells MW-1, MW-3, and MW-10 as extraction wells and VEW-1 as the injection well. This would require an NOI to be submitted to the NCDEQ, Division of Water Resources (DWR), Underground Injection Control (UIC) Program for the injection event; and,  Conduct groundwater sampling following the MMPE/OI event to evaluate possible reduction in VOC concentrations. 3.0 SITE DESCRIPTION 3.1 Site Characterization ATC, under contract to the NCDEQ, provided environmental consulting services at the Crossroads Center-C site, which is located at 134 Arnold Road, in Lexington, Davidson County, North Carolina. Figure 1 depicts the site on a topographic map. The site is currently a vacant building at the northwest intersection of Arnold Road and Old U.S. Highway 52. A railroad line is located along the eastern site boundary (Figure 2). The topography slopes to the southwest, with elevations of approximately 824 feet in the northeast area of the site to approximately 820 feet in the southwestern area of the site. A generally north-south trending topographic ridge is located east of the railroad line. No water supply wells have been identified within 1,000 feet of the source area. The nearest surface water body is approximately 650 feet to the southwest (Figure 3), according to the Davidson County GIS website. 3.2 Site Background The site’s UST system formerly consisted of five tanks, two 6,000-gallon gasoline tanks, one 5,000-gallon gasoline tank, one 3,000-gallon diesel tank, and one 2,000-gallon kerosene tank. The tanks were reportedly in use through 2012. In April 1994, a 2,000-gallon kerosene UST and associated piping for the UST were removed by Geo-Environmental Consultants with no evidence of release at the time. NCDEQ issued a closure letter for the tank in July 1995. A Phase II Environmental Site Assessment dated July 2002 performed by Environmental Consulting Services, LTD (ECS) documented a petroleum release at the site based on contamination present in both the soils and groundwater (Incident #24552). The source of the release was suspected to be from the two 6,000-gallon gasoline USTs. Assessment activities included: the installation of well MW-1 in July 2002 and wells MW-2 through MW-4 and VEW-1 in August 2002; and soil sampling collected during well installation. Soil contamination was found to be above soil-to-groundwater MSCCs and groundwater contaminants above NCDEQ 2L Standards. The incident (#24552) was closed in September 2002 with a Notice of Residual Petroleum (NORP) with a groundwater restriction for water supply wells and a soil restriction for soil excavation, but no residential land use restriction. At the time the NORP was issued a site check of the UST system had not been completed. Between May 2003 and December 2021, LR&S Inc. operated the UST system, until the UST permit to operate expired on December 31, 2012. LR&S Inc. was dissolved by the Secretary of State on September 28, 2015. Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 4 The current owner purchased the property on January 11, 2017. In September 2017 Progress Environmental Group, Inc. (Progress) removed the remaining four USTs and one AST remaining at the site. Soil contamination was found to be above NCDEQ Action Levels during the removal process and a hole was observed in one of the 6,000-gallon gasoline USTs. Total Petroleum Hydrocarbons-Diesel Range Organics (TPH-DRO) and TPH- Gasoline Range Organics (TPH-GRO) were found to be above their respective NCDEQ Action Levels in various soil samples from the tank pit. No additional soils were removed from the site during the tank removal. Incident #44919 was assigned to the reported release. In 2018, Progress conducted a Limited Site Assessment that included the installation and sampling of two additional monitoring wells, MW-10 and MW-11, and soil sampling. Soil contamination was revealed above the NCDEQs Soil-to-Groundwater and Residential MSCCs and groundwater contamination was revealed above the GCLs for benzene. One water-supply well was identified within 500 feet of the site. A follow-up groundwater monitoring event by Progress that year found an increase in previously identified constituent concentrations. No other remediation activities were taken at this time. In August 2019, Progress conducted a groundwater sampling event on wells MW-1 through MW-4, MW-10, MW-11, and VEW-1. No LNAPL was detected during the sampling event and benzene was detected above the GCL of 5,000 micrograms per liter (µg/L). Progress reported that the contaminant plume appeared to be migrating to the southwest. They also reported that the rise in the water column between 2018 and 2019 appeared to mobilize soil contaminants causing the sudden spike in contaminant levels in the groundwater. In May 2021 NCDEQs Corrective Action Branch performed a site inspection and found that wells MW-3, MW-4, and MW-10 were in good condition, wells MW-1 and VEW-1 were uncovered but may be usable, well MW-2 could not be located, and well MW-11 was reportedly destroyed. The site was accepted to the State Lead program in May 2021. On October 8, 2021, ATC conducted a groundwater monitoring event including wells MW-1 through MW-4, MW-10, and VEW-1 with analysis for VOCs. Benzene was detected at concentrations higher than the GCL in wells MW-3 and MW-10, and naphthalene was detected in well MW-10 above the GCL. Several VOCs exceeded the 2L Standards in wells MW-1, MW-3, MW-4, MW-10, and VEW-1. 3.3 Site and Regional Geology The Geologic Map of North Carolina produced by the North Carolina Geologic Survey (1985) indicates that the property is located within the Charlotte Belt of the Piedmont Physiographic Province. Rocks of the Piedmont are crystalline igneous and metamorphic rocks that were formed during Appalachian mountain building events during the Paleozoic Era, several hundred million years ago. The metamorphic rock type beneath the site is metagabbro, metadiorite, and mafic plutonic-volcanic complexes. The shallow subsurface in most areas of the Piedmont contains residual soil overburden, including structure-free residuum, saprolite, and partially weathered rock (PWR), that derive from in-place weathering of the crystalline bedrock. Occasional areas containing recent deposits of alluvium in the uppermost subsurface are found near streams and rivers. Saprolite and PWR typically contain some relict structures from the original rock material. Depth to rock ranges from ground surface at occasional outcrops to depths of up to 100 feet in Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 5 areas of easily weathered rock. Bedrock was not encountered at a depth of 45 feet below ground surface (ft-bgs) based on the boring for monitoring well VEW-1. 3.4 Site and Regional Hydrogeology The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and rivers to as deep as 50 feet or more beneath upland surfaces in some parts of the Piedmont. Groundwater in the alluvium or unconsolidated residual material, including saprolite and PWR, usually behaves as an unconfined, or water table, aquifer and will yield water with head elevation equivalent to the first elevation where water was encountered. Permeability varies with lithology and is typically relatively low in residual soils, with higher permeability in saprolite or PWR due to relict rock texture and variable susceptibility to weathering exhibited by different minerals in the rock. Groundwater flow in residual soils or alluvium is usually in rough concurrence with local topographic conditions and is toward local drainage features. The bedrock fractures or other planar features generally constitute the bedrock aquifer, with the surrounding rock material being effectively impermeable. Along with fractures, contacts between rock bodies probably constitute zones of significant groundwater occurrence in the bedrock. The surrounding material and overlying residuum tend to make the bedrock aquifer a semi-confined aquifer. That is, the overlying water and soil weight normally results in pressure that causes water in a borehole which intersects a fracture or other feature to rise above the elevation of the fracture or feature. Such features may not occur on predicable trends, at the same elevations, or even be present or directly connected in separate boreholes. In areas adjacent to creeks the bedrock groundwater generally discharges to the residuum or alluvium and then into the surface water. In upland areas away from surface water drainages, the bedrock aquifer is generally recharged by downward infiltration of residuum or alluvial aquifer water at locations where fractures intersect the bedrock surface. When gradient conditions are discussed, upgradient properties are in locations which could, based on topographic or groundwater elevation analysis, have shallow groundwater migration from them toward the site. Crossgradient sites are nearby properties with equivalent elevation to the site, which would be unlikely to have groundwater migration from them parallel to the site, and downgradient sites are nearby properties, which likely receive groundwater migration from beneath the site. Based on topography and historical groundwater level data, groundwater flow is to the south-southwest. The available historical depth to groundwater data indicate that the depth to groundwater has generally ranged from approximately 6 to 15 ft-bgs. 4.0 GROUNDWATER CHARACTERIZATION 4.1 Access Agreements and Well Permits On October 4, 2022, ATC submitted access agreements to the property owners of the two parcels where the new monitoring wells (MW-12 and MW-13) were proposed. The access agreement for well MW-12 was signed on October 15, 2022, by Mr. Michael S. Lane for the 158 Arnold Road property. The access agreement for well MW-13 took several attempts and phone conversations with the property owner, who had two different addresses. The agreement was signed on November 8, 2022 by Martha Fritts Martin and received on November 15, 2022. Copies of the access agreements are included in Appendix A. Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 6 On December 2, 2022, ATC submitted well permit applications to the NCDEQ, Division of Water Resources. A well permit for well was issued on December 12, 2022. Copies of the well permit applications and well permits are included in Appendix A. 4.2 Monitoring Well Installation On January 9, 2023, ATC supervised the installation of shallow groundwater monitoring wells MW-12 and MW-13, which are located to the west and south of MW-3, respectively. The wells were installed to evaluate the extent of the GCL exceedances in well MW-3. Prior to conducting any subsurface work, North Carolina 811 was notified to mark out any buried public utilities at the site. A private utility locator from Ground Penetrating Radar Systems, LLC (GPRS) was onsite to identify private utilities in the work area. No utilities were encountered within 10 feet of the work area. The monitoring wells were installed by Geologic Exploration (Geologic), a North Carolina- registered well driller. The monitoring wells were installed using hollow stem augers. Soil samples characterized for lithology and were screened at approximate 5-foot intervals with a photoionization detector (PID) for relative VOC levels. The soil from the MW-12 and MW-13 borings consisted of red-brown silty clayey silt and was relatively consistent with depth. Elevated PID readings (416 and 401 parts per million or ppm) were observed in soil samples from 10 to 20 ft-bgs (below the groundwater surface) from the MW-12 boring. Elevated PID readings were not observed in the soil samples from 0 to 10 ft-bgs from the MW-12 boring or in any of the soil samples from the MW-13 boring. Monitoring wells MW-12 and MW-13 were installed to a depth of 20 feet below ground surface (ft-bgs) including a 15-foot length, 0.010-inch slotted, 2-inch diameter PVC well screen extending from 5 to 20 ft-bgs and solid PVC riser casing to near ground surface. A sand pack filter was installed in the annular space between the well screen and the borehole from the base of the boring to one foot above the top of the well screen, followed by one foot of bentonite seal on top of the sand pack. A grout slurry was placed from the top of the bentonite seal to ground surface to seal the borehole around the solid PVC well pipe riser. Soil cuttings generated from the drilling of the monitoring wells were spread on site. The well was completed with a 2-foot by 2-foot concrete pad and manhole. The top of casing (TOC) elevation for the wells was measured during the groundwater monitoring event on January 13, 2023. TOC elevations were surveyed relative to an arbitrary elevation of 100 feet and existing monitoring well MW-3. The monitoring well record and soil boring log for monitoring wells MW-12 and MW-13 are including in Appendix B. Field notes of the well installation are presented in Appendix C. 4.3 Groundwater Levels On January 13, 2023, a groundwater monitoring event was conducted for monitoring wells MW- 1, MW-2, MW-3, MW-4, MW-10, MW-12, and MW-13. Wells MW-2 and MW-4 were only gauged for depths to water and total well depths. Monitoring well MW-11 could not be located and is presumed to have been destroyed. Figure 2 depicts the well locations on a site map. Well construction and groundwater level data are summarized in Table 1. The calculated groundwater elevations vary across the monitoring well network that do not allow representation of a smooth groundwater surface. Based on the October 8, 2021 data, groundwater flow is to Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 7 the south-southwest with a hydraulic gradient of 0.025 feet/foot. The January 13, 2023 groundwater elevations are presented on Figure 4. The January 13, 2023 groundwater levels were approximately 3.3 feet higher than the October 8, 2021 groundwater levels, with groundwater levels above the screen in wells MW-1, MW-3, and MW-4. Field notes and photographs from the January 13, 2023, groundwater monitoring event are presented in Appendix C. 4.4 Groundwater Quality On January 13, 2023, ATC collected groundwater samples from monitoring wells MW-1, MW-3, MW-10, MW-12, and MW-13. During sample activities, a three-volume well purge was implemented prior to groundwater sample collection to ensure a representative groundwater sample. Field parameters are presented in Table 2. The water samples were collected in laboratory-supplied, preserved containers; entered into chain of custody control; placed on ice; and shipped to North Carolina accredited Pace Analytical Services, Inc. in Huntersville, North Carolina. The groundwater samples were analyzed by Standard Method 6200B, including ethylene dibromide (EDB) and oxygenates. The laboratory analytical report and chain-of- custody documentation is included in Appendix D. The recent groundwater analytical results are summarized in Table 3. The historical groundwater analytical results are summarized in Table 4. A groundwater quality map of the recent results with exceedances of the 2L Standards is presented as Figure 5. The groundwater analytical results were compared to the 2L Standards and GCLs. The updated Conceptual Site Model is presented as Table 5. Groundwater analytical results indicated the following:  Benzene was detected above the GCL of 5,000 µg/L in MW-10 (6,590 µg/L); and  VOCs exceeded the 2L Standards in wells MW-1, MW-3, MW-10, MW-12, and MW-13. Benzene in wells MW-3 and MW-10 and naphthalene in well MW-10 exceeded the GCLs in October 2021. Benzene in well MW-10 was the only VOC exceeding the GCL in January 2023, and the concentration increased by approximately 11% since October 2021. Benzene in MW-3 decreased by approximately 50% since October 2021. Naphthalene in MW-10 also decreased by approximately 95%, however, the concentration was similar to that reported in February of 2018 and in April and June of 2019. Excluding the benzene in MW-10, concentrations of VOCs decreased in wells MW-1, MW-3, and MW-10. The extent of the GCLs is defined with the additional wells MW-12 and MW-13. The January 2023 VOC concentrations in the downgradient well MW-13 were approximately 3% or less of those in MW-3, excluding tert-amyl alcohol that was approximately 11%. Historically, concentrations of benzene in well MW-10 have increased with rising groundwater levels and decrease with falling groundwater levels, suggesting a possible zone of contaminated soil near the seasonal high groundwater levels. Note that the recent increase in benzene concentration in MW-10 appears to be less than prior increases suggesting natural degradation is occurring. As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of the laboratory report was conducted. During the review, it was found that the samples were received from the laboratory in acceptable condition and properly preserved. The samples were analyzed within correct holding times and reported within the lab report, and the chain of custody was properly completed by all parties. ATC collected one field blank during groundwater Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 8 monitoring activities with no detections. The laboratory QC report shows that laboratory reagent blanks (LRBs) and laboratory control samples/laboratory control sample duplicates (LCSs/LCSDs) were analyzed for each method that was used for the original samples. The LRB indicated no detections and the LCS/LCSD results were within acceptable laboratory control limits. Refer to the laboratory report in Appendix C for details regarding QA results for the laboratory samples and any noted exceptions. 5.0 CONCLUSIONS AND RECOMMENDATIONS On behalf of the Trust Fund Branch of the NCDEQ UST Section, ATC has completed assessment activities for the Crossroads Center-C UST site (incident no 44919), located at 134 Arnold road, Lexington, Davidson County, North Carolina. The findings from the recent and historical activities indicate the following:  There are no water supply wells within 1,000 feet of the source area or surface water bodies within 500 feet of the source area;  Municipal water is provided to the area;  LNAPL was not detected in the monitoring wells;  Benzene (6,590 micrograms per liter or µg/L) was detected in well MW-10 above the GCL of 5,000 µg/L;  VOCs exceeded the 2L Standards in MW-1, MW-3, MW-10, MW-12, and MW-13; and  The monitoring wells are 1-inch diameter wells, excluding MW-10, MW-12, and MW-13 that are 2-inch diameter wells; and  The depth to groundwater ranged from 6.69 ft-toc in MW-13 to 10.59 ft-toc in MW-2, and groundwater flow is indicated to be to the south-southwest. Benzene in wells MW-3 and MW-10 and naphthalene in well MW-10 exceeded the GCLs in October 2021. Benzene in well MW-10 was the only VOC exceeding the GCL in January 2023, and the concentration increased by approximately 11% since October 2021. Benzene in MW-3 decreased by approximately 50% since October 2021. Naphthalene in MW-10 also decreased by approximately 95%, however, the concentration was similar to that reported in February of 2018 and in April and June of 2019. Excluding the benzene in MW-10, concentrations of VOCs decreased in wells MW-1, MW-3, and MW-10. The extent of the GCLs is defined with the additional wells MW-12 and MW-13. The January 2023 VOC concentrations in the downgradient well MW-13 were approximately 3% or less of those in MW-3, excluding tert-amyl alcohol that was approximately 11%. The January 13, 2023 groundwater levels were approximately 3.3 feet higher than the October 8, 2021 groundwater levels, with groundwater levels above the screen in wells MW-1, MW-3, and MW-4. Historically, concentrations of benzene in well MW-10 have increased with rising groundwater levels and decrease with falling groundwater levels, suggesting a possible zone of contaminated soil near the seasonal high groundwater levels. Note that the recent increase in benzene concentration in MW-10 appears to be less than prior increases suggesting natural degradation is occurring. Based on the findings, ATC recommends the following:  Conduct a combined Mobile Multi-Phase Extraction (MMPE) and Ozone Injection (OI) event, using wells MW-1, MW-3, and MW-10 as extraction wells and VEW-1 as the Groundwater Monitoring Report February 27, 2023 Crossroads Center-C, Lexington, NC (Incident No 44919) ATC Project # SLC4491902 9 injection well. This would require an NOI to be submitted to the NCDEQ, DWR, UIC Program for the injection event; and,  Conduct groundwater sampling following the MMPE/OI event to evaluate possible reduction in VOC concentrations. FIGURES SITE VICINITY MAP 1"= 2,000' 1 Project Number: Date:Scale: Drawing File: Figure: App'd By: Drn. By: Ckd. By: N H:\2021\OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\CROSSROADS CENTER\SLC4491901-VIC.DWG, FIG111/17/2021 SEE LOWER LEFT CROSSROADS CENTER-C 134 ARNOLD ROAD LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA SLC4491901 DH AQ AQ ARNOLD ROAD SITEVEW-1MW-10MW-1MW-2MW-4MW-3SCALE: 1" = 20'2005101520NLEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEMW-1MONITORING WELLWell IdentificationMW-12MW-13MW-11DESTROYED MONITORING WELLWell IdentificationFigure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\CROSSROADS CENTER\SLC4491902-SITE.DWG, FIG2 SITE MAP02/15/2023SEE LOWER LEFTCROSSROADS CENTER-C 134 ARNOLD ROAD LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA SLC4491901AS SHOWNMS AQ2NOTES: 1.Features shown are not an authoritative location, nor are they presentedto a stated accuracy. COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET 500 FT.RADIUS1,000 FT.RADIUSLEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINESTREAMS/WETLANDS50SCALE: 1" = 200'2000100150200NFigure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2021\OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\CROSSROADS CENTER\SLC4491901-RECEPTOR.DWG, FIG3 RECEPTOR SURVEY MAP11/23/2021SEE LOWER LEFTCROSSROADS CENTER-C 134 ARNOLD ROAD LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA SLC4491901AS SHOWNDH AQ3NOTES: 1.Features shown are not an authoritative location, nor are they presented to a stated accuracy. COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET ARNOLD ROAD SITEVEW-1MW-10MW-1MW-11MW-2MW-4MW-3SCALE: 1" = 20'2005101520NMW-12MW-1389.61NM89.3290.1289.9789.4489.7090.03LEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEMW-289.32MONITORING WELLWell IdentificationRelative Groundwater Elevation (ft)GROUNDWATER FLOW DIRECTIONMW-11DESTROYED MONITORING WELLWell IdentificationFigure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\CROSSROADS CENTER\SLC4491902-POT.DWG, FIG4 GROUNDWATER ELEVATION MAP02/15/2023SEE LOWER LEFTCROSSROADS CENTER-C 134 ARNOLD ROAD LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA SLC4491901AS SHOWNMS AQ4NOTES: 1.Features shown are not an authoritative location, nor are they presentedto a stated accuracy.2.Groundwater samples collected on 01/13/23.3.Only constituents exceeding the NCDEQ 2L Standards are shown.4.DUE TO VARIABILITY OF GROUNDWATER ELEVATIONS,CONTOURS ARE NOT PRESENTED. THE GROUNDWATER FLOW ARROW IS BASED ON OCTOBER 8, 2021 DATA COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET ARNOLD ROAD SITEVEW-1MW-10MW-1MW-2NSMW-4MW-3SCALE: 1" = 20'2005101520NLEGEND:SITE PROPERTY LINENOTE: ALL LOCATIONS ARE APPROXIMATEPARCEL LINEMW-1MONITORING WELLWell IdentificationMW-12MW-13MW-11MW-11DESTROYED MONITORING WELLWell Identification Figure:Drawing File: Project Number: Ckd. By: Drn. By: App'd By: Ckd. Date:Scale:Date:H:\2023\1 OTHER OFFICES\NORTH CAROLINA\NCDEQ-STATE LEAD\CROSSROADS CENTER\SLC4491902-GW.DWG, FIG5 GROUNDWATER ANALYTICAL MAP02/15/2023SEE LOWER LEFTCROSSROADS CENTER-C 134 ARNOLD ROAD LEXINGTON, DAVIDSON COUNTY, NORTH CAROLINA SLC4491901AS SHOWNMS AQ5NOTES: 1.Features shown are not an authoritative location, nor are they presentedto a stated accuracy.2.Groundwater samples collected on 01/13/23.3.Only constituents exceeding the NCDEQ 2L Standards are shown.4.Concentrations underlined values exceed the GCL.5.µg/L = micrograms per liter. 6.J = estimated value between the laboratory reporting and method detection limits. COORDINATE SYSTEM: NAD 1983 NORTH CAROLINA STATE PLANE FIPS 3200, US SURVEY FEET TABLES TABLE 1 WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA Crossroads Center-C 134 Arnold Road Lexington, Davidson County, North Carolina 27295 NCDEQ Incident #44919 06/27/2019 6.17 ----93.83 10/08/2021 13.33 ----86.67 01/13/2023 9.88 ----90.12 06/27/2019 -------- 10/08/2021 13.82 ----86.80 01/13/2023 10.59 ----90.03 06/27/2019 5.13 ----93.26 10/08/2021 12.31 ----86.08 01/13/2023 8.95 ----89.44 06/27/2019 5.74 ----93.36 10/08/2021 12.78 ----86.32 01/13/2023 9.13 ----89.97 02/01/2018 13.75 ----85.95 05/07/2018 9.22 ----90.48 04/10/2019 8.25 ----91.45 06/27/2019 5.89 ----93.81 10/08/2021 13.00 ----86.70 01/13/2023 10.38 ----89.32 06/27/2019 -------- 02/01/2018 14.90 ------ 01/13/2023 MW-12 1/9/2023 2 20.00 5 - 20 98.62 01/13/2023 9.01 ----89.61 MW-13 1/9/2023 2 20.00 5 - 20 96.39 01/13/2023 6.69 ----89.70 06/27/2019 6.20 ----93.64 10/08/2021 13.29 ----86.55 Notes: TOC = Top-of-casing -- = Not Measured NA = Not Available LNAPL = light non-aqueous phase liquid If Free Procuct is present in a well, groundwater elevation should be calculated by: [Top of Casing Elevation - Depth to Water] + [Free Product Thickness x 0.8581] 99.84 Well ID Date Installed 1 Groundwater Elevation (feet) TOC Elevation (feet) Depth to Groundwater (feet below TOC) Date Measured Well Depth (feet below TOC) LNAPL Thickness (feet) Screen Interval (feet below TOC) Depth to LNAPL (feet below TOC) VEW-1 8/7/2002 8/6/2002 10 - 2544.231 MW-11 1/31/2018 Unknown Unknown 1/31/2018 Well Diameter (Inches) 1 1 10 - 25 -- MW-1 MW-2 MW-3 MW-4 MW-10 7/15/2002 8/7/2002 8/6/2002 99.7 1 2 24.55 24.74 24.67 25.12 24.69 Well Destroyed 10 - 25 10 - 25 10 - 25 10 - 25 10 - 25 100.00 100.62 98.39 99.10 Page 1 of 1 TABLE 2 FIELD PARAMETERS Crossroads Center-C 134 Arnold Road Lexington, Davidson County, North Carolina 27295 NCDEQ Incident #44919 MW-1 01/13/23 17.09 0.25 2.3 -82 6.1 MW-3 01/13/23 19.63 0.33 1.0 -46 5.9 MW-10 01/13/23 18.20 0.62 6.2 -120 6.1 MW-12 01/13/23 20.10 0.13 7.2 91 5.6 MW-13 01/13/23 18.99 0.09 7.1 154 5.1 Notes: °C = degrees Celsius mS/cm = milliSiemens per centimeter mg/L = milligrams per liter ORP = oxidation-reduction potential mV= millivolts su = standard units Temperature (°C) Conductivity (mS/cm) Dissolved Oxygen (mg/L) ORP (mV) pH (su)Well ID Sample Date Page 1 of 1 TABLE 3 RECENT GROUNDWATER ANALYTICAL RESULTS Crossroads Center-C 134 Arnold Road Lexington, Davidson County, North Carolina 27295 NCDEQ Incident #44919 Well ID Date Collected BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalenen-Butylbenzenesec-ButylbenzeneChloroformDiisopropyl etherIsopropylbenzenen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneEthanoltert-Amyl Alcohol1 600 600 500 20 6 70 70 70 70 70 70 70 400 400 4,000 40 5,000 260,000 80,000 50,000 20,000 6,000 5,900 8,800 70,000 70,000 30,500 26,100 70,000 28,500 24,100 4,000,000 40,000 MW-1 01/13/23 763 1,400 1,640 4,860 <8.4 354 14.9 <8.0 <8.6 <6.2 52.6 114 6.6J 894 216 <1,440 798J MW-3 01/13/23 2,720 43.3 514 11.1J <10.6 139 <12.2 <10.0 <10.8 46.9 32.6 55.7 <7.3 <12.4 <8.3 <1,800 2,810 MW-10 01/13/23 6,590 14,900 2,010 7,560 <52.8 414 <61.2 <50.0 <53.8 40.6J 74.3 175 <36.5 1,190 278 <9,020 <4,550 MW-12 01/13/23 77 0.89 6.5 18.8 <0.42 125 17.6 10.1 2.3 <0.31 49.8 25 <0.29 106 9.4 <72.2 170 MW-13 01/13/23 4.9 0.46J <0.30 <0.34 0.72 1.1J <0.49 1.4 <0.43 0.33J 1.0 <0.34 <0.29 <0.50 <0.33 166J 312 Notes: 1) 15A NCAC 02L 0202 Groundwater Quality Standards (2L Standards). 2) NCDEQ Division of Waste Management (DWM) Gross Contamination Levels (GCLs). Only constituents detected above the reporting limit are shown Concentrations are reported in micrograms per liter (µg/L) Concentrations in bold exceed the 2L Standard Concentrations in bold and underlined exceed the GCL VOCs = volatile organic compounds VPH = volatile petroleum hydrocarbons MADEP = Massachusetts Department of Environmental Protection J = estimated concentration below the laboratory reporting limit NE = Not Established ND = Not Detected NA = Not Analyzed Grayed values and "<" indicate the compound was below the laboratory reporting limit Analytical Method 2L Standard (1) GCL Standard (2) Standard Method 6200B Page 1 of 1 TABLE 4 HISTORICAL GROUNDWATER ANALYTICAL RESULTS Crossroads Center-C 134 Arnold Road Lexington, Davidson County, North Carolina 27295 NCDEQ Incident #44919 Well ID Date Collected BenzeneTolueneEthylbenzeneTotal XylenesMethyl tert-butyl ether (MTBE)NaphthaleneBromomethanen-Butylbenzenesec-Butyl benzeneChloroformIsopropyl Ether2-HexanoneIsopropylbenzene4-Isopropyl toluene4-Methyl-2-Pentanonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneEthanolter-Amyl AlcoholC5-C8 AliphaticsC9-C18 AliphaticsC9-C22 AromaticsC19-C36 Aliphatics1 600 600 500 20 6 10 70 70 70 70 40 70 25 100 70 70 400 400 4000 40 400 700 200 10,000 5,000 260,000 80,000 50,000 20,000 6,000 100,000 5,900 8,800 70,000 70,000 40,000 30,500 11,700 100,000 26,100 70,000 28,500 24,100 4,000,000 40,000 NE NE NE NE 06/27/19 1,310 2,570 2,220 4,700 ND 691 NA NA NA NA ND NA 155 NA NA 364 NA 2,030 622 NR NR NA NA NA NA 10/08/21 1,440 3,710 2,020 6,370 <0.140 4,480 <0.280 8.85 7.73 <0.220 0.698 1.95 68.6 4.05 4.16 275 7 2,130 503 NR NR NA NA NA NA 01/13/23 763 1,400 1,640 4,860 <8.4 354 <33.2 14.9 <8.0 <8.6 <6.2 NA 52.6 NA NA 114 6.6J 894 216 <1440 798J NA NA NA NA 07/04/19 ND ND ND ND ND ND NA NA NA NA ND NA ND NA NA ND NA ND ND NR NR NA NA NA NA 10/08/21 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.280 <0.180 <0.200 <0.220 <0.500 <0.380 <0.180 <0.089 <0.078 <0.190 <0.220 <0.190 <0.180 NR NR NA NA NA NA 06/27/19 10,800 147 1,770 141 130 288 NA NA NA NA 252 NA 86 NA NA 198 NA 151 ND NR NR NA NA NA NA 10/08/21 5,310 63.5 1,810 41.2 <0.140 4,660 <0.280 12.5 9.57 <0.220 43.5 <0.380 68.6 4.92 <0.078 95.1 2.14 13.4 37.1 NR NR NA NA NA NA 01/13/23 2,720 43.3 514 11.1J <10.6 139 <41.5 <12.2 <10.0 <10.8 46.9 NA 32.6 NA NA 55.7 <7.3 <12.4 <8.3 <1800 2,810 NA NA NA NA 06/27/19 104.0 ND 53.5 489 ND 318 NA NA NA NA NA NA 110 NA NA 246 NA 1,860 906 NR NR NA NA NA NA 10/08/21 37 4.28 2.82 22.2 <0.140 36.4 <0.280 4.64 4.53 <0.220 <0.500 <0.380 18.3 1.13 <0.078 16 <0.220 152 57.8 NR NR NA NA NA NA 02/01/18 5,870 7,000 1,130 5,020 ND 418 NA NA NA NA ND NA ND NA NA 198 NA 1,280 340 NR NR 4,040 4,540 1,290 NA 05/07/18 13,600 18,300 1,850 7,870 ND 293 NA NA NA NA 165 NA ND NA NA 170 NA 1,210 300 NR NR NA NA NA NA 04/10/19 17,000 21,600 2,370 9,220 ND 448 NA NA NA NA 130 NA ND NA NA 200 NA 1,470 314 NR NR NA NA NA NA 06/27/19 20,000 26,200 2,330 8,240 ND 415 NA NA NA NA 96 NA ND NA NA 240 NA 1,280 339 NR NR NA NA NA NA 10/08/21 5,950 16,600 4,160 13,200 <14.0 8,030 33.1J 60.7 44.9J <22.0 <50.0 <38.0 184 20J 48.6J 511 <22.0 3,380 814 NR NR NA NA NA NA 01/13/23 6,590 14,900 2,010 7,560 <52.8 414 <208 <61.2 <50.0 <53.8 40.6J NA 74.3 NA NA 175 <36.5 1,190 278 <9020 <4550 NA NA NA NA MW-11 02/01/18 ND 21.2 121 628 ND 28.8 NA NA NA NA ND NA ND NA NA ND NA ND ND NR NR ND 4,610 2,421 125 MW-12 01/13/23 77 0.9 7 19 <0.42 125 <1.7 17.6 10.1 2.3 <0.31 NA 50 NA NA 25 <0.29 106 9 <72.2 170 NA NA NA NA MW-13 01/13/23 4.9 0.46J <0.30 <0.34 0.72 1.1J <1.7 <0.49 1.4 <0.43 0.33J NA 1 NA NA <0.34 <0.29 <0.50 <0.33 166J 312 NA NA NA NA 06/27/19 ND ND ND ND ND ND NA NA NA NA ND NA ND NA NA ND NA ND ND NR NR NA NA NA NA 10/08/21 38.1 <0.220 <0.170 0.285J 0.294J <0.470 <0.280 <0.180 <0.200 1.65 1.18 <0.380 0.475J <0.089 <0.078 <0.190 <0.220 <0.190 <0.180 NR NR NA NA NA NA Notes: 1) 15A NCAC 02L 0202 Groundwater Quality Standard (2L Standard).VPH = volatile petroleum hydrocarbons NR = Not Reported 2) NCDEQ Division of Waste Management (DWM) Gross Contamination Level (GCL).MADEP = Massachusetts Department of Environmental Protection Only constituents detected above the reporting limit are shown J = estimated concentration below the laboratory reporting limit Concentrations are reported in micrograms per liter (µg/L)NE = Not Established Concentrations in bold exceed the 2L Standard ND = Not Detected Concentrations in bold and underlined exceed the GCL NA = Not Analyzed VOCs = volatile organic compounds Grayed values and "<" indicate the compound was below the laboratory reporting limit 2L Standard (1) GCL (2) Analytical Method MADEP Method VPH/EPH MW-10 VEW-1 Standard Method 6200B MW-1 MW-2 MW-3 MW-4 Page 1 of 1 TABLE 5 CONCEPTUAL SITE MODEL Crossroads Center-C 134 Arnold Road Lexington, Davidson County, North Carolina 27295 NCDEQ Incident #44919 Site Name:Crossroads Center-C Release Discovery Date:9/21/2017 NCDEQ UST Incident No.:44919 Source of Release:UST System Facility ID No.:00-0-0000029082 Estimated Volume of Release:Unknown Risk Classification:Intermediate Risk Rank:I135D Gasoline (leaded)x Site Address:134 Arnold Road Gasoline (unleaded) Site City, ST ZIP:Lexington, 27295 Gasoline (ethanol blend) Site County:Davidson Diesel x NCDEQ Regional Office:Winston-Salem Kerosene x Active UST Facility:No Heating Oil (#2) USTs Present:No (1 USTs removed 1994, remaining 4 removed 2017)Heating Oil (>#2) Motor Oil Soil Information Hydraulic Oil Major Soil Type:Cecil Sandy Loam Used Oil Surface Cover over impacted soil:Pavement, gravel and soil Utilities within plume (Y/N/U):U >S-W MSCCs (Y/N/U):Y Land Use >Residential MSCCs (Y/N/U):Y Site:Vacant commercial >Comm/Ind MSCCs (Y/N/U):N North Adjacent:Agricultural East Adjacent:Commercial (The Gun Store) Geologic Information South Adjacent:Agricultural Litho-Tectonic Zone Charlotte Belt West Adjacent:Commerical (Place of Praise) Geologic Formation Charlotte Belt Rock Type Metagabbro, metadiorite and mafic plutonic-volcanic complexes Depth (ft bgs)>25 Municipal Water (Y/N/U):Y Active Potable Wells <1000 ft (#/U):N Groundwater Information Active Potable Wells <500 ft (#/U):N Depth to water (ft-bgs)6-15 Impacted Wells (Y/N/U):N Gradient (ft/ft):0.025 Any wells <250 ft (Y/N/U):N Direction (N E S W combo):SSW Hydraulic Conductivity (ft/day):Unknown Total Porosity (%):Unknown <500 ft (Y/N):N Effective Porosity (%):Unknown Type of Surface Water: Flow Rate (ft/year):Unknown Name of Nearest Stream: COCs >2L (Y/N/U):Y Stream Classification: COCs >2L Extent Defined (Y/N):N COCs >GCLs (Y/N/U):Y COCs >GCLs (Wells):MW-10 (historically MW-3 also)>LEL in Structures:U COCs >GCLs Extent Defined (Y/N):Y Vapors in Buildings:U COCs >2B Standards by 10X (Y/N/U):NA Dissolved VOCs <5 ft of Structures:N LNAPL (Y/N/U):N LNAPL <15 ft of Structures:N LNAPL (Max Thickness ft):NA Basement <30 ft of Dissolved COCs:N LNAPL (Wells):NA LNAPL Extent Defined (Y/N):NA LNAPL (<5 ft beneath buildings/U):NA Utilities within plume (Y/N/U):Unknown Approach (general discussion): Evaluate natural attenuation with possible remedial actions to reduce levels to be less than the GCLs. Alternative Water Source Site and surrounding sites supplied by Davidson Public Water. NORP Previously filed Site Remediation Possible, MMPE/AS/Air Injection Soil Excavation Possible, following soil assessment. AFVR MMPE Possible, combined with air injection SVE/AS Other Vapor Comments: Updated 2/13/2023. MW-3 and MW-10 most heavily impacted, concentrations increase with higher water table. Possible actions to closure: 1) monitored natural attenuation; 2) excavation of soil following soil assessment; or 3) In-situ remediation by MMPE/Air Injection in the vadoze zone. Possible Path(s) to Closure Site Information Release Information Petroleum Type Released Receptor Information Water Supply Surface Water Bodies APPENDIX A ACCESS AGREEMENTS, WELL PERMIT APPLICATIONS, AND WELL PERMITS Right of Entry Agreement October 4, 2022 Davidson County PIN 6727-04-92-3937 158 Arnold Road Lexington, NC 27295 1 Scott Ryals, P.E. Environmental Engineer DWM UST Section 1646 Mail Service Center Raleigh, NC 27699-1646 RE: Right of Entry Agreement Crossroads Center-C, Incident No. 44919 134 Arnold Road Lexington, NC 27295 Dear Mr. Ryals, I am/We are the owner(s) of a parcel of property, located at or near the incident in question, and hereby permit the Department of Environment Quality (Department) or its contractor to enter upon said property for the purpose of conducting an assessment and/or remediation of the groundwater and/or soils under the authority of G.S. 143-215.94G. I am/We are granting permission with the understanding that: 1. The investigation shall be conducted by the UST Section of the Department’s Division of Waste Management or its contractor. 2. The costs of the investigation and/or remediation of the site and access shall be borne by the Department or its contractor in accordance with the acceptance of the site into the State-Lead Program. The Department or its contractor shall protect and prevent damage to the property and surrounding lands. Any damages will be restored by the Department or its contractor to as close to the pre-work condition as practicably possible. 3. Unless otherwise agreed, the Department or its contractor shall have access to the site by the shortest feasible route to the nearest public road. The Department or its contractor will notify the land owners 48 hours prior to entry and may enter upon the land at reasonable times and have full right of access during the period of the investigation. 4. Any claims which may arise against the Department or its contractor shall be governed by Article 31 of Chapter 143 of the North Carolina General Statutes, Tort Claims Against State Departments and Agencies, and as otherwise provided by law. 5. The activities to be carried out by the Department or its contractor are for the primary benefit of the Department and of the State of North Carolina. Any benefits accruing to the owner are incidental. The Department or its contractor is not and shall not be construed to be an agent, employee, or contractor of the landowner. RightofEntryAgreementDavidsonCountyPIN6727-04-92-3937158ArnoldRoadLexington,NC27295October4,2022Theinformationderivedfromtheinvestigationshallbemadeavailabletotheowneruponrequestandisapublicrecord,inaccordancewithG.S.132-1.I/Weagreenottointerferewith,removeoranywaysdamagetheDepartment’swell(s)oritscontractor’swell(s)andequipmentduringtheinvestigation.Sincerely,HvXLSignatureType/PrintNameofOwnerorAgent33<T-Y07-Pfd(PhoneNumberJ-JJ2iCfj.4-tu,nft.fpfi*EmailAddress/?<?,/3iYX/fitMailingAddressUvZLcoM-/0.C1737#City/State/ZipCode/A/{13.-Date2 FOR OFFICE USE ONLY PERMIT NO. ISSUED DATE NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY - DIVISION OF WATER RESOURCES APPLICATION FOR PERMIT TO CONSTRUCT A MONITORING OR RECOVERY WELL SYSTEM PLEASE TYPE OR PRINT CLEARLY In accordance with the provisions of Article 7, Chapter 87, General Statutes of North Carolina and regulations pursuant thereto, application is hereby made for a permit to construct monitoring or recovery wells. 1. Date: 2. County: 12/02/2022 Davidson 3. What type of well are you applying for? (monitoring or recovery): Monitoring 4. Applicant: NCDEQ, DWM, UST Section (Scott Ryals) Telephone: 919-707-8168 Applicant’s Mailing Address: 1646 Mail Service Center, Raleigh, NC2766-1646 Applicant’s Email Address (if available): scott.ryals@ncdenr.gov 5. Contact Person (if different than Applicant): Al Quarles Telephone: 704-529-3200 Contact Person’s Mailing Address: 7606 Whitehall Executive Center Drive, Suite 200, Charlotte, NC 28273 Contact Person’s Email Address (if available): william.quarles@oneatlas.com 6. Property Owner (if different than Applicant): Mr. Michael S Lane Telephone: 336-407-8406 Property Owner’s Mailing Address: PO Box 2106, Welcome, NC 27374 Property Owner’s Email Address (if available): mlane16@triad.rr.com 7. Property Physical Address (Including PIN Number) 158 Arnold Rd PIN 1132100000039 City Lexington County Davidson Zip Code 27295 8. Reason for Well(s): Groundwater assessment (ex: non-discharge permit requirements, suspected contamination, assessment, groundwater contamination, remediation, etc.) 9. Type of facility or site for which the well(s) is(are) needed: UST (ex: non-discharge facility, waste disposal site, landfill, UST, etc.) 10. Are there any current water quality permits or incidents associated with this facility or site? If so, list permit and/or incident no(s). UST Incident #44919; Crossroads Center-C, 134 Arnold Rd, Lexington, NC 27295 11. Type of contaminants being monitored or recovered: Volatile Organic Compounds (ex: organics, nutrients, heavy metals, etc.) 12. Are there any existing wells associated with the proposed well(s)? If yes, how many? 7 Existing Monitoring or Recovery Well Construction Permit No(s).: All on UST site property 13. Distance from proposed well(s) to nearest known waste or pollution source (in feet): approximately 50 feet 14. Are there any water supply wells located less than 500 feet from the proposed well(s)? no If yes, give distance(s): n/a 15. Well Contractor: TBD Certification No.: Well Contractor Address: PROPOSED WELL CONSTRUCTION INFORMATION 1. As required by 15A NCAC 02C .0105(f)(7), attach a well construction diagram of each well showing the following: a. Borehole and well diameter e. Type of casing material and thickness b. Estimated well depth f. Grout horizons c. Screen intervals g. Well head completion details d. Sand/gravel pack intervals Continued on Reverse FOR OFFICE USE ONLY PERMIT NO. ISSUED DATE NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY - DIVISION OF WATER RESOURCES APPLICATION FOR PERMIT TO CONSTRUCT A MONITORING OR RECOVERY WELL SYSTEM PLEASE TYPE OR PRINT CLEARLY In accordance with the provisions of Article 7, Chapter 87, General Statutes of North Carolina and regulations pursuant thereto, application is hereby made for a permit to construct monitoring or recovery wells. 1. Date: 2. County: 12/02/2022 Davidson 3. What type of well are you applying for? (monitoring or recovery): Monitoring 4. Applicant: NCDEQ, DWM, UST Section (Scott Ryals) Telephone: 919-707-8168 Applicant’s Mailing Address: 1646 Mail Service Center, Raleigh, NC2766-1646 Applicant’s Email Address (if available): scott.ryals@ncdenr.gov 5. Contact Person (if different than Applicant): Al Quarles Telephone: 704-529-3200 Contact Person’s Mailing Address: 7606 Whitehall Executive Center Drive, Suite 200, Charlotte, NC 28273 Contact Person’s Email Address (if available): william.quarles@oneatlas.com 6. Property Owner (if different than Applicant): Ms. Martha Fritts Martin Telephone: 336-248-8661 Property Owner’s Mailing Address: 1648 Arrington Dr., Lexington, NC 27295 Property Owner’s Email Address (if available): marthamartin@lexcominc.net 7. Property Physical Address (Including PIN Number) 2509 Arrington Dr. PIN 1132200000014 City Lexington County Davidson Zip Code 27295 8. Reason for Well(s): Groundwater assessment (ex: non-discharge permit requirements, suspected contamination, assessment, groundwater contamination, remediation, etc.) 9. Type of facility or site for which the well(s) is(are) needed: UST (ex: non-discharge facility, waste disposal site, landfill, UST, etc.) 10. Are there any current water quality permits or incidents associated with this facility or site? If so, list permit and/or incident no(s). UST Incident #44919; Crossroads Center-C, 134 Arnold Rd, Lexington, NC 27295 11. Type of contaminants being monitored or recovered: Volatile Organic Compounds (ex: organics, nutrients, heavy metals, etc.) 12. Are there any existing wells associated with the proposed well(s)? If yes, how many? 7 Existing Monitoring or Recovery Well Construction Permit No(s).: All on UST site property 13. Distance from proposed well(s) to nearest known waste or pollution source (in feet): approximately 100 feet 14. Are there any water supply wells located less than 500 feet from the proposed well(s)? no If yes, give distance(s): n/a 15. Well Contractor: TBD Certification No.: Well Contractor Address: PROPOSED WELL CONSTRUCTION INFORMATION 1. As required by 15A NCAC 02C .0105(f)(7), attach a well construction diagram of each well showing the following: a. Borehole and well diameter e. Type of casing material and thickness b. Estimated well depth f. Grout horizons c. Screen intervals g. Well head completion details d. Sand/gravel pack intervals Continued on Reverse North Carolina Department of Environmental Quality | Division of Water Resources Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Winston-Salem, North Carolina 27105 336.776.9800 December 12, 2022 Mr. Scott Ryals NCDEQ – DWM UST Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 SUBJECT: MONITORING WELL CONSTRUCTION PERMIT NO. WM0401417 COUNTY: Davidson FILE NAME: Crossroads Center-C Dear Mr. Ryals: In accordance with your application received on December 2, 2022, we are forwarding herewith: 1. Monitoring Well Construction Permit No. WM0401417 for the construction of one (1) monitoring well at 2509 Arrington Drive in Lexington in Davidson County. Henceforth, correspondence and data relating to this well shall be designated as specified in the subject heading above. This Permit will be effective from the date of issuance and shall be subject to the conditions and limitations as specified therein. If you have any questions regarding this permit, please contact me or Jim Gonsiewski at (336) 776-9800. Sincerely, Lon T. Snider Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDEQ - WSRO cc: Martha Fritts Martin (Electronic Copy) Al Quarles – ATC Associates of North Carolina, P.C. (Electronic Copy) North Carolina Department of Environmental Quality | Division of Water Resources Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Raleigh, North Carolina 27105 336.776.9800 NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES – WATER QUALITY REGIONAL OPERATIONS SECTION PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and other applicable Laws, Rules and Regulations. PERMISSION IS HEREBY GRANTED TO NCDEQ – DWM UST Section FOR THE CONSTRUCTION OF A MONITOR WELL SYSTEM consisting of one (1) monitoring well owned by the NCDEQ – DWM UST Section. The well will be located at 2509 Arrington Drive in Lexington, North Carolina, in Davidson County. This Permit is issued in accordance with the application received on December 2, 2022 in conformity with specifications and supporting data, all of which are filed with the Department of Environmental Quality and are considered integral parts of this Permit. This Permit is for well construction only, and does not waive any provision or requirement of any other applicable law or regulation. Construction of any well under this Permit shall be in strict compliance with the North Carolina Well Construction Regulations and Standards (15A NCAC 02C .0100), and other State and Local Laws and regulations pertaining to well construction. If any requirements or limitations specified in this Permit are unacceptable, you have a right to an adjudicatory hearing upon written request within 30 days of receipt of this Permit. The request must be in the form of a written petition conforming to Chapter 150B of the North Carolina General Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding. This Permit will be effective for one year from the date of its issuance and shall be subject to other specified conditions, limitations, or exceptions as follows: North Carolina Department of Environmental Quality | Division of Water Resources Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Raleigh, North Carolina 27105 336.776.9800 1. Issuance of this Permit does not obligate reimbursement from State trust funds, if these wells are being installed as part of an investigation for contamination from an underground storage tank or dry cleaner incident. 2. Issuance of this Permit does not supersede any other agreement, permit, or requirement issued by another agency. 3. The well(s) shall be located and constructed as shown on the attachments submitted as part of the Permit application. 4. Each well shall have a Well Contractor Identification Plate in accordance with 15A NCAC 02C .0108(o). 5. Well construction records (GW-1) for each well shall be submitted to the Division of Water Resources’ Information Processing Unit within 30 days of the well completion. 6. When the well is discontinued or abandoned, it shall be abandoned in accordance with 15A NCAC 02C .0113 and a well abandonment record (GW-30) shall be submitted to the Division of Water Resources’ Information Processing Unit within 30 days of the well abandonment. 7. The County Health Department may require a county monitoring well construction permit. Please contact the health department for their requirements. Permit issued the 12th day of December, 2022 FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION _______________________________________________ Lon T. Snider, Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDEQ - WSRO By Authority of the Environmental Management Commission Permit No. # WM0401417 North Carolina Department of Environmental Quality | Division of Water Resources Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Winston-Salem, North Carolina 27105 336.776.9800 December 12, 2022 Mr. Scott Ryals NCDEQ – DWM UST Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 SUBJECT: MONITORING WELL CONSTRUCTION PERMIT NO. WM0401418 COUNTY: Davidson FILE NAME: Crossroads Center-C Dear Mr. Ryals: In accordance with your application received on December 2, 2022, we are forwarding herewith: 1. Monitoring Well Construction Permit No. WM0401418 for the construction of one (1) monitoring well at 158 Arnold Road in Lexington in Davidson County. Henceforth, correspondence and data relating to this well shall be designated as specified in the subject heading above. This Permit will be effective from the date of issuance and shall be subject to the conditions and limitations as specified therein. If you have any questions regarding this permit, please contact me or Jim Gonsiewski at (336) 776-9800. Sincerely, Lon T. Snider Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDEQ - WSRO cc: Michael S. Lane (Electronic Copy) Al Quarles – ATC Associates of North Carolina, P.C. (Electronic Copy) North Carolina Department of Environmental Quality | Division of Water Resources Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Raleigh, North Carolina 27105 336.776.9800 NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES – WATER QUALITY REGIONAL OPERATIONS SECTION PERMIT FOR THE CONSTRUCTION OF A MONITORING WELL In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes, and other applicable Laws, Rules and Regulations. PERMISSION IS HEREBY GRANTED TO NCDEQ – DWM UST Section FOR THE CONSTRUCTION OF A MONITOR WELL SYSTEM consisting of one (1) monitoring well owned by the NCDEQ – DWM UST Section. The well will be located at 158 Arnold Road in Lexington, North Carolina, in Davidson County. This Permit is issued in accordance with the application received on December 2, 2022 in conformity with specifications and supporting data, all of which are filed with the Department of Environmental Quality and are considered integral parts of this Permit. This Permit is for well construction only, and does not waive any provision or requirement of any other applicable law or regulation. Construction of any well under this Permit shall be in strict compliance with the North Carolina Well Construction Regulations and Standards (15A NCAC 02C .0100), and other State and Local Laws and regulations pertaining to well construction. If any requirements or limitations specified in this Permit are unacceptable, you have a right to an adjudicatory hearing upon written request within 30 days of receipt of this Permit. The request must be in the form of a written petition conforming to Chapter 150B of the North Carolina General Statutes and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina 27699-6714. Unless such a demand is made, this Permit is final and binding. This Permit will be effective for one year from the date of its issuance and shall be subject to other specified conditions, limitations, or exceptions as follows: North Carolina Department of Environmental Quality | Division of Water Resources Winston-Salem Regional Office | 450 W. Hanes Mill Rd, Suite 300 | Raleigh, North Carolina 27105 336.776.9800 1. Issuance of this Permit does not obligate reimbursement from State trust funds, if these wells are being installed as part of an investigation for contamination from an underground storage tank or dry cleaner incident. 2. Issuance of this Permit does not supersede any other agreement, permit, or requirement issued by another agency. 3. The well(s) shall be located and constructed as shown on the attachments submitted as part of the Permit application. 4. Each well shall have a Well Contractor Identification Plate in accordance with 15A NCAC 02C .0108(o). 5. Well construction records (GW-1) for each well shall be submitted to the Division of Water Resources’ Information Processing Unit within 30 days of the well completion. 6. When the well is discontinued or abandoned, it shall be abandoned in accordance with 15A NCAC 02C .0113 and a well abandonment record (GW-30) shall be submitted to the Division of Water Resources’ Information Processing Unit within 30 days of the well abandonment. 7. The County Health Department may require a county monitoring well construction permit. Please contact the health department for their requirements. Permit issued the 12th day of December, 2022 FOR THE NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION _______________________________________________ Lon T. Snider, Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDEQ - WSRO By Authority of the Environmental Management Commission Permit No. # WM0401418 APPENDIX B WELL CONSTRUCTION RECORDS AND BORING LOGS WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018 1.Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2.Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3.Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single) □Industrial/Commercial □Residential Water Supply (shared) □Irrigation □Wells > 100,000 GPDNon-Water Supply Well: □Monitoring □Recovery Injection Well: □Aquifer Recharge □Groundwater Remediation □Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage □Experimental Technology □Subsidence Control □Geothermal (Closed Loop)□Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6.Is(are) the well(s): □Permanent or □Temporary 7.Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wellsdrilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10.Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method:(i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft. ft. ft. ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. 16. INNER CASING OR TUBING (geothermal closed-loop)FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. ft. ft. in. 17. SCREENFROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft. ft. in. ft. ft. in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft. ft. ft. ft. ft. ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft. ft. ft. ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. 21. REMARKS 22.Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23.Site diagram or additional well details:You may use the back of this page to provide additional well construction info (add 'See Over' in Remarks Box). You may also attach additional pages if necessary. 24.SUBMITTAL INSTRUCTIONS Submit this GW-1 within 30 days of well completion per the following: 24a. For All Wells: Original form to Division of Water Resources (DWR), Information Processing Unit, 1617 MSC, Raleigh, NC 27699-1617 24b. For Injection Wells: Copy to DWR, Underground Injection Control (IUC) Program, 1636 MSC, Raleigh, NC 27699-1636 24c. For Water Supply and Open-Loop Geothermal Return Wells: Copy to the county environmental health department of the county where installed 24d. For Water Wells producing over 100,000 GPD: Copy to DWR, CCPCUA Permit Program, 1611 MSC, Raleigh, NC 27699-1611 DAVID HALL A - 4459 GEOLOGIC EXPLORATION 0.0 5.0 SCH 40 5.0 20.0 .010 l 0.0 PORTLAND BENTONITE 4.0 20-40 0.0 ASPHALT 01/09/23 MW-12 0.5 GRAVEL 1.0 SILTY CLAY CROSSROADS CENTER - C 134 ARNOLD ROAD LEXINGTON 27295 DAVIDSON BENTONITE SEAL ~ 3.0 - 4.0 FEET 35° 52' 02.48" 80° 15' 02.58"01/10/23 l 20.0 12.0 8.0 AUGER PVC SCH 40 PVC 2.0 2.0 3.0 20.0 0.5 1.0 20.0 FINE SILICA SAND SLURRY 02-13-2023 C:\Users\william.quarles\Documents\Work Files\NCDEQ State-Lead temp\CrossRoads\MW-12.borClient: NCDEQ State Lead Program ATC Project No. SLC4491902 Lexington, North Carolina 134 Arnold Road Crossroad Center - C ppm = parts per million ft bgs = Feet Below Ground Surface. MONITORING WELL: MW-12 (Page 1 of 1) Date(s) Drilled : 01/09/2023 Drilling Contractor : Geologic Exploration Drilling Method : Hollow Stem Auger Boring Diameter : Diameter = 8" Logged By : Kyle Harris Depth in Feet (BGS)0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 USCSGRAPHICDESCRIPTION PID (ppm) 0 0.2 416 401 Elev.: 98.62 Well: MW-12 Grout Bentonite Filter Sand Cover Inner Casing Well Screen Asphalt GW ML ML ML Asphalt Gravel Red/brown clayey SILT, dry Red/brown clayey SILT, moist Red/brown clayey SILT, wet END OF BORING WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018 1.Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2.Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3.Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single) □Industrial/Commercial □Residential Water Supply (shared) □Irrigation □Wells > 100,000 GPDNon-Water Supply Well: □Monitoring □Recovery Injection Well: □Aquifer Recharge □Groundwater Remediation □Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage □Experimental Technology □Subsidence Control □Geothermal (Closed Loop)□Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6.Is(are) the well(s): □Permanent or □Temporary 7.Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wellsdrilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10.Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method:(i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft. ft. ft. ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. 16. INNER CASING OR TUBING (geothermal closed-loop)FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. ft. ft. in. 17. SCREENFROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft. ft. in. ft. ft. in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft. ft. ft. ft. ft. ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft. ft. ft. ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. ft. 21. REMARKS 22.Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23.Site diagram or additional well details:You may use the back of this page to provide additional well construction info (add 'See Over' in Remarks Box). You may also attach additional pages if necessary. 24.SUBMITTAL INSTRUCTIONS Submit this GW-1 within 30 days of well completion per the following: 24a. For All Wells: Original form to Division of Water Resources (DWR), Information Processing Unit, 1617 MSC, Raleigh, NC 27699-1617 24b. For Injection Wells: Copy to DWR, Underground Injection Control (IUC) Program, 1636 MSC, Raleigh, NC 27699-1636 24c. For Water Supply and Open-Loop Geothermal Return Wells: Copy to the county environmental health department of the county where installed 24d. For Water Wells producing over 100,000 GPD: Copy to DWR, CCPCUA Permit Program, 1611 MSC, Raleigh, NC 27699-1611 DAVID HALL A - 4459 GEOLOGIC EXPLORATION 0.0 5.0 SCH 40 5.0 20.0 .010 l 0.0 PORTLAND BENTONITE 4.0 20-40 0.0 SILTY CLAY 01/09/23 MW-13 CROSSROADS CENTER - C 134 ARNOLD ROAD LEXINGTON 27295 DAVIDSON BENTONITE SEAL ~ 3.0 - 4.0 FEET 35° 52' 02.48" 80° 15' 02.58"01/10/23 l 20.0 12.0 8.0 AUGER PVC SCH 40 PVC 2.0 2.0 3.0 20.0 20.0 FINE SILICA SAND SLURRY 02-13-2023 C:\Users\william.quarles\Documents\Work Files\NCDEQ State-Lead temp\CrossRoads\MW-13.borClient: NCDEQ State Lead Program ATC Project No. SLC4491902 Lexington, North Carolina 134 Arnold Road Crossroad Center - C ppm = parts per million ft bgs = Feet Below Ground Surface. MONITORING WELL: MW-13 (Page 1 of 1) Date(s) Drilled : 01/09/2023 Drilling Contractor : Geologic Exploration Drilling Method : Hollow Stem Auger Boring Diameter : Diameter = 8" Logged By : Kyle Harris Depth in Feet (BGS)0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 USCSGRAPHICDESCRIPTION PID (ppm) 0 0 0 0 Elev.: 96.39 Well: MW-13 Grout Bentonite Filter Sand Cover Inner Casing Well Screen ML ML ML Red/brown clayey SILT, dry Red/brown clayey SILT, moist Red/brown clayey SILT, wet End of Boring APPENDIX C FIELD LOGS AND PHOTOGRAPHS ATC Associates of North Carolina, P.C. 7606 Whitehall Exec Ctr Dr, Ste 800 Charlotte, NC 28273 (704) 529-3200 PHOTOGRAPHS ATC PROJECT NO: SLC4491902 REVIEWED BY: AQ SCALE: NTS DATE: 2/2023 Crossroads Center-C 134 Arnold Road Lexington, Davidson County, NC 27295 NCDEQ UST Incident # 44919 Photo # 2: Monitoring well MW-12 during drilling (1/9/2023) Photo # 1: Monitoring well MW-12 prior to drilling (1/9/2023) ATC Associates of North Carolina, P.C. 7606 Whitehall Exec Ctr Dr, Ste 800 Charlotte, NC 28273 (704) 529-3200 PHOTOGRAPHS ATC PROJECT NO: SLC4491902 REVIEWED BY: AQ SCALE: NTS DATE: 2/2023 Crossroads Center-C 134 Arnold Road Lexington, Davidson County, NC 27295 NCDEQ UST Incident # 44919 Photo # 4: Monitoring well MW-12 completion (1/9/2023) Photo # 3: Monitoring well MW-12 completion (1/9/2023) ATC Associates of North Carolina, P.C. 7606 Whitehall Exec Ctr Dr, Ste 800 Charlotte, NC 28273 (704) 529-3200 PHOTOGRAPHS ATC PROJECT NO: SLC4491902 REVIEWED BY: AQ SCALE: NTS DATE: 2/2023 Crossroads Center-C 134 Arnold Road Lexington, Davidson County, NC 27295 NCDEQ UST Incident # 44919 Photo # 6: Monitoring well MW-13 after completion (1/9/2023) Photo # 5: Monitoring well MW-13 during drilling (1/9/2023) ATC Associates of North Carolina, P.C. 7606 Whitehall Exec Ctr Dr, Ste 800 Charlotte, NC 28273 (704) 529-3200 PHOTOGRAPHS ATC PROJECT NO: SLC4491902 REVIEWED BY: AQ SCALE: NTS DATE: 2/2023 Crossroads Center-C 134 Arnold Road Lexington, Davidson County, NC 27295 NCDEQ UST Incident # 44919 Photo # 5: Monitoring well MW-13 after completion (1/9/2023) APPENDIX D LABORATORY REPORT January 23, 2023 LIMS USE: FR - AL QUARLES LIMS OBJECT ID: 92646869 92646869 Project: Pace Project No.: RE: Al Quarles ATC Group Services LLC 7606 Whitehall Executive Cente Suite 800 Charlotte, NC 28273 SLC4491902 CROSSROADS CENTER-C Dear Al Quarles: Enclosed are the analytical results for sample(s) received by the laboratory on January 13, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor M Cannon taylor.cannon@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 36 raceAnalytical www.pacelabs.com CERTIFICATIONS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 36 raceAnalytical www.pacelabs.com SAMPLE SUMMARY Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Lab ID Sample ID Matrix Date Collected Date Received 92646869001 MW-1 Water 01/13/23 10:40 01/13/23 15:55 92646869002 MW-3 Water 01/13/23 11:40 01/13/23 15:55 92646869003 MW-10 Water 01/13/23 12:00 01/13/23 15:55 92646869004 MW-12 Water 01/13/23 13:00 01/13/23 15:55 92646869005 MW-13 Water 01/13/23 13:10 01/13/23 15:55 92646869006 FB-1 Water 01/13/23 13:15 01/13/23 15:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 36 raceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92646869001 MW-1 SM 6200B 70 PASI-CCL 92646869002 MW-3 SM 6200B 70 PASI-CCL 92646869003 MW-10 SM 6200B 70 PASI-CCL 92646869004 MW-12 SM 6200B 70 PASI-CCL 92646869005 MW-13 SM 6200B 70 PASI-CCL 92646869006 FB-1 SM 6200B 70 PASI-CSAS PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-1 Lab ID:92646869001 Collected:01/13/23 10:40 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol 798J ug/L 01/20/23 21:31 75-85-4200072820 tert-Amylmethyl ether <185 ug/L 01/20/23 21:31 994-05-820018520 Benzene 763 ug/L 01/20/23 21:31 71-43-210.0 6.9 20 Bromobenzene <5.8 ug/L 01/20/23 21:31 108-86-110.0 5.8 20 Bromochloromethane <9.4 ug/L 01/20/23 21:31 74-97-510.0 9.4 20 Bromodichloromethane <6.1 ug/L 01/20/23 21:31 75-27-410.0 6.1 20 Bromoform <6.8 ug/L 01/20/23 21:31 75-25-210.0 6.8 20 Bromomethane <33.2 ug/L 01/20/23 21:31 74-83-910033.2 20 tert-Butyl Alcohol <536 ug/L 01/20/23 21:31 75-65-0100053620 n-Butylbenzene 14.9 ug/L 01/20/23 21:31 104-51-810.0 9.8 20 sec-Butylbenzene <8.0 ug/L 01/20/23 21:31 135-98-810.0 8.0 20 tert-Butylbenzene <6.5 ug/L 01/20/23 21:31 98-06-610.0 6.5 20 tert-Butyl Formate <588 ug/L 01/20/23 21:31 762-75-4100058820 Carbon tetrachloride <6.7 ug/L 01/20/23 21:31 56-23-510.0 6.7 20 Chlorobenzene <5.7 ug/L 01/20/23 21:31 108-90-710.0 5.7 20 Chloroethane <13.0 ug/L 01/20/23 21:31 75-00-320.0 13.0 20 Chloroform <8.6 ug/L 01/20/23 21:31 67-66-310.0 8.6 20 Chloromethane <10.8 ug/L 01/20/23 21:31 74-87-320.0 10.8 20 2-Chlorotoluene <6.4 ug/L 01/20/23 21:31 95-49-810.0 6.4 20 4-Chlorotoluene <6.5 ug/L 01/20/23 21:31 106-43-410.0 6.5 20 1,2-Dibromo-3-chloropropane <6.8 ug/L 01/20/23 21:31 96-12-820.0 6.8 20 Dibromochloromethane <7.2 ug/L 01/20/23 21:31 124-48-110.0 7.2 20 1,2-Dibromoethane (EDB)<5.4 ug/L 01/20/23 21:31 106-93-410.0 5.4 20 Dibromomethane <7.9 ug/L 01/20/23 21:31 74-95-310.0 7.9 20 1,2-Dichlorobenzene <6.8 ug/L 01/20/23 21:31 95-50-110.0 6.8 20 1,3-Dichlorobenzene <6.8 ug/L 01/20/23 21:31 541-73-110.0 6.8 20 1,4-Dichlorobenzene <6.7 ug/L 01/20/23 21:31 106-46-710.0 6.7 20 Dichlorodifluoromethane <6.9 ug/L 01/20/23 21:31 75-71-810.0 6.9 20 1,1-Dichloroethane <7.3 ug/L 01/20/23 21:31 75-34-310.0 7.3 20 1,2-Dichloroethane <6.4 ug/L 01/20/23 21:31 107-06-210.0 6.4 20 1,1-Dichloroethene <7.0 ug/L 01/20/23 21:31 75-35-410.0 7.0 20 cis-1,2-Dichloroethene <7.7 ug/L 01/20/23 21:31 156-59-210.0 7.7 20 trans-1,2-Dichloroethene <7.9 ug/L 01/20/23 21:31 156-60-510.0 7.9 20 1,2-Dichloropropane <7.1 ug/L 01/20/23 21:31 78-87-510.0 7.1 20 1,3-Dichloropropane <5.7 ug/L 01/20/23 21:31 142-28-910.0 5.7 20 2,2-Dichloropropane <7.8 ug/L 01/20/23 21:31 594-20-710.0 7.8 20 1,1-Dichloropropene <8.5 ug/L 01/20/23 21:31 563-58-610.0 8.5 20 cis-1,3-Dichloropropene <7.3 ug/L 01/20/23 21:31 10061-01-510.0 7.3 20 trans-1,3-Dichloropropene <7.3 ug/L 01/20/23 21:31 10061-02-610.0 7.3 20 Diisopropyl ether <6.2 ug/L 01/20/23 21:31 108-20-310.0 6.2 20 Ethanol <1440 ug/L 01/20/23 21:31 64-17-54000144020 Ethylbenzene 1640 ug/L 01/20/23 21:31 100-41-410.0 6.1 20 Ethyl-tert-butyl ether <64.8 ug/L 01/20/23 21:31 637-92-320064.8 20 Hexachloro-1,3-butadiene <30.6 ug/L 01/20/23 21:31 87-68-340.0 30.6 20 Isopropylbenzene (Cumene)52.6 ug/L 01/20/23 21:31 98-82-810.0 6.7 20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-1 Lab ID:92646869001 Collected:01/13/23 10:40 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <39.0 ug/L 01/20/23 21:31 75-09-240.0 39.0 20 Methyl-tert-butyl ether <8.4 ug/L 01/20/23 21:31 1634-04-410.0 8.4 20 Naphthalene 354 ug/L 01/20/23 21:31 91-20-340.0 12.9 20 n-Propylbenzene 114 ug/L 01/20/23 21:31 103-65-110.0 6.8 20 Styrene 6.6J ug/L 01/20/23 21:31 100-42-510.0 5.8 20 1,1,1,2-Tetrachloroethane <6.2 ug/L 01/20/23 21:31 630-20-610.0 6.2 20 1,1,2,2-Tetrachloroethane <4.5 ug/L 01/20/23 21:31 79-34-510.0 4.5 20 Tetrachloroethene <5.8 ug/L 01/20/23 21:31 127-18-410.0 5.8 20 Toluene 1400 ug/L 01/20/23 21:31 108-88-310.0 4.8 20 1,2,3-Trichlorobenzene <16.1 ug/L 01/20/23 21:31 87-61-640.0 16.1 20 1,2,4-Trichlorobenzene <12.8 ug/L 01/20/23 21:31 120-82-140.0 12.8 20 1,1,1-Trichloroethane <6.6 ug/L 01/20/23 21:31 71-55-610.0 6.6 20 1,1,2-Trichloroethane <6.5 ug/L 01/20/23 21:31 79-00-510.0 6.5 20 Trichloroethene <7.7 ug/L 01/20/23 21:31 79-01-610.0 7.7 20 Trichlorofluoromethane <6.0 ug/L 01/20/23 21:31 75-69-420.0 6.0 20 1,2,3-Trichloropropane <5.2 ug/L 01/20/23 21:31 96-18-410.0 5.2 20 1,2,4-Trimethylbenzene 894 ug/L 01/20/23 21:31 95-63-610.0 9.9 20 1,3,5-Trimethylbenzene 216 ug/L 01/20/23 21:31 108-67-810.0 6.6 20 Vinyl chloride <7.7 ug/L 01/20/23 21:31 75-01-420.0 7.7 20 Xylene (Total)4860 ug/L 01/20/23 21:31 1330-20-720.0 6.8 20 m&p-Xylene 4380 ug/L 01/20/23 21:31 179601-23-120.0 14.2 20 o-Xylene 477 ug/L 01/20/23 21:31 95-47-610.0 6.8 20 Surrogates 1,2-Dichloroethane-d4 (S)105 %01/20/23 21:31 17060-07-070-130 20 4-Bromofluorobenzene (S)97 %01/20/23 21:31 460-00-470-130 20 Toluene-d8 (S)99 %01/20/23 21:31 2037-26-570-130 20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-3 Lab ID:92646869002 Collected:01/13/23 11:40 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol 2810 ug/L 01/20/23 22:08 75-85-4250091025 tert-Amylmethyl ether <231 ug/L 01/20/23 22:08 994-05-825023125 Benzene 2720 ug/L 01/20/23 22:08 71-43-212.5 8.6 25 Bromobenzene <7.2 ug/L 01/20/23 22:08 108-86-112.5 7.2 25 Bromochloromethane <11.7 ug/L 01/20/23 22:08 74-97-512.5 11.7 25 Bromodichloromethane <7.7 ug/L 01/20/23 22:08 75-27-412.5 7.7 25 Bromoform <8.5 ug/L 01/20/23 22:08 75-25-212.5 8.5 25 Bromomethane <41.5 ug/L 01/20/23 22:08 74-83-912541.5 25 tert-Butyl Alcohol <670 ug/L 01/20/23 22:08 75-65-0125067025 n-Butylbenzene <12.2 ug/L 01/20/23 22:08 104-51-812.5 12.2 25 sec-Butylbenzene <10.0 ug/L 01/20/23 22:08 135-98-812.5 10.0 25 tert-Butylbenzene <8.1 ug/L 01/20/23 22:08 98-06-612.5 8.1 25 tert-Butyl Formate <735 ug/L 01/20/23 22:08 762-75-4125073525 Carbon tetrachloride <8.3 ug/L 01/20/23 22:08 56-23-512.5 8.3 25 Chlorobenzene <7.1 ug/L 01/20/23 22:08 108-90-712.5 7.1 25 Chloroethane <16.2 ug/L 01/20/23 22:08 75-00-325.0 16.2 25 Chloroform <10.8 ug/L 01/20/23 22:08 67-66-312.5 10.8 25 Chloromethane <13.5 ug/L 01/20/23 22:08 74-87-325.0 13.5 25 2-Chlorotoluene <8.0 ug/L 01/20/23 22:08 95-49-812.5 8.0 25 4-Chlorotoluene <8.1 ug/L 01/20/23 22:08 106-43-412.5 8.1 25 1,2-Dibromo-3-chloropropane <8.5 ug/L 01/20/23 22:08 96-12-825.0 8.5 25 Dibromochloromethane <9.0 ug/L 01/20/23 22:08 124-48-112.5 9.0 25 1,2-Dibromoethane (EDB)<6.8 ug/L 01/20/23 22:08 106-93-412.5 6.8 25 Dibromomethane <9.8 ug/L 01/20/23 22:08 74-95-312.5 9.8 25 1,2-Dichlorobenzene <8.5 ug/L 01/20/23 22:08 95-50-112.5 8.5 25 1,3-Dichlorobenzene <8.5 ug/L 01/20/23 22:08 541-73-112.5 8.5 25 1,4-Dichlorobenzene <8.3 ug/L 01/20/23 22:08 106-46-712.5 8.3 25 Dichlorodifluoromethane <8.6 ug/L 01/20/23 22:08 75-71-812.5 8.6 25 1,1-Dichloroethane <9.2 ug/L 01/20/23 22:08 75-34-312.5 9.2 25 1,2-Dichloroethane <8.0 ug/L 01/20/23 22:08 107-06-212.5 8.0 25 1,1-Dichloroethene <8.7 ug/L 01/20/23 22:08 75-35-412.5 8.7 25 cis-1,2-Dichloroethene <9.6 ug/L 01/20/23 22:08 156-59-212.5 9.6 25 trans-1,2-Dichloroethene <9.9 ug/L 01/20/23 22:08 156-60-512.5 9.9 25 1,2-Dichloropropane <8.9 ug/L 01/20/23 22:08 78-87-512.5 8.9 25 1,3-Dichloropropane <7.1 ug/L 01/20/23 22:08 142-28-912.5 7.1 25 2,2-Dichloropropane <9.7 ug/L 01/20/23 22:08 594-20-712.5 9.7 25 1,1-Dichloropropene <10.7 ug/L 01/20/23 22:08 563-58-612.5 10.7 25 cis-1,3-Dichloropropene <9.1 ug/L 01/20/23 22:08 10061-01-512.5 9.1 25 trans-1,3-Dichloropropene <9.1 ug/L 01/20/23 22:08 10061-02-612.5 9.1 25 Diisopropyl ether 46.9 ug/L 01/20/23 22:08 108-20-312.5 7.7 25 Ethanol <1800 ug/L 01/20/23 22:08 64-17-55000180025 Ethylbenzene 514 ug/L 01/20/23 22:08 100-41-412.5 7.6 25 Ethyl-tert-butyl ether <81.0 ug/L 01/20/23 22:08 637-92-325081.0 25 Hexachloro-1,3-butadiene <38.2 ug/L 01/20/23 22:08 87-68-350.0 38.2 25 Isopropylbenzene (Cumene)32.6 ug/L 01/20/23 22:08 98-82-812.5 8.3 25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-3 Lab ID:92646869002 Collected:01/13/23 11:40 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <48.8 ug/L 01/20/23 22:08 75-09-250.0 48.8 25 Methyl-tert-butyl ether <10.6 ug/L 01/20/23 22:08 1634-04-412.5 10.6 25 Naphthalene 139 ug/L 01/20/23 22:08 91-20-350.0 16.1 25 n-Propylbenzene 55.7 ug/L 01/20/23 22:08 103-65-112.5 8.5 25 Styrene <7.3 ug/L 01/20/23 22:08 100-42-512.5 7.3 25 1,1,1,2-Tetrachloroethane <7.8 ug/L 01/20/23 22:08 630-20-612.5 7.8 25 1,1,2,2-Tetrachloroethane <5.6 ug/L 01/20/23 22:08 79-34-512.5 5.6 25 Tetrachloroethene <7.3 ug/L 01/20/23 22:08 127-18-412.5 7.3 25 Toluene 43.3 ug/L 01/20/23 22:08 108-88-312.5 6.0 25 1,2,3-Trichlorobenzene <20.2 ug/L 01/20/23 22:08 87-61-650.0 20.2 25 1,2,4-Trichlorobenzene <16.0 ug/L 01/20/23 22:08 120-82-150.0 16.0 25 1,1,1-Trichloroethane <8.3 ug/L 01/20/23 22:08 71-55-612.5 8.3 25 1,1,2-Trichloroethane <8.1 ug/L 01/20/23 22:08 79-00-512.5 8.1 25 Trichloroethene <9.6 ug/L 01/20/23 22:08 79-01-612.5 9.6 25 Trichlorofluoromethane <7.4 ug/L 01/20/23 22:08 75-69-425.0 7.4 25 1,2,3-Trichloropropane <6.5 ug/L 01/20/23 22:08 96-18-412.5 6.5 25 1,2,4-Trimethylbenzene <12.4 ug/L 01/20/23 22:08 95-63-612.5 12.4 25 1,3,5-Trimethylbenzene <8.3 ug/L 01/20/23 22:08 108-67-812.5 8.3 25 Vinyl chloride <9.6 ug/L 01/20/23 22:08 75-01-425.0 9.6 25 Xylene (Total)11.1J ug/L 01/20/23 22:08 1330-20-725.0 8.4 25 m&p-Xylene <17.7 ug/L 01/20/23 22:08 179601-23-125.0 17.7 25 o-Xylene 11.1J ug/L 01/20/23 22:08 95-47-612.5 8.4 25 Surrogates 1,2-Dichloroethane-d4 (S)108 %01/20/23 22:08 17060-07-070-130 25 4-Bromofluorobenzene (S)96 %01/20/23 22:08 460-00-470-130 25 Toluene-d8 (S)99 %01/20/23 22:08 2037-26-570-130 25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-10 Lab ID:92646869003 Collected:01/13/23 12:00 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol <4550 ug/L 01/20/23 22:44 75-85-4125004550125 tert-Amylmethyl ether <1160 ug/L 01/20/23 22:44 994-05-812501160125 Benzene 6590 ug/L 01/20/23 22:44 71-43-262.5 43.1 125 Bromobenzene <36.2 ug/L 01/20/23 22:44 108-86-162.5 36.2 125 Bromochloromethane <58.5 ug/L 01/20/23 22:44 74-97-562.5 58.5 125 Bromodichloromethane <38.4 ug/L 01/20/23 22:44 75-27-462.5 38.4 125 Bromoform <42.6 ug/L 01/20/23 22:44 75-25-262.5 42.6 125 Bromomethane <208 ug/L 01/20/23 22:44 74-83-9625208125 tert-Butyl Alcohol <3350 ug/L 01/20/23 22:44 75-65-062503350125 n-Butylbenzene <61.2 ug/L 01/20/23 22:44 104-51-862.5 61.2 125 sec-Butylbenzene <50.0 ug/L 01/20/23 22:44 135-98-862.5 50.0 125 tert-Butylbenzene <40.4 ug/L 01/20/23 22:44 98-06-662.5 40.4 125 tert-Butyl Formate <3680 ug/L 01/20/23 22:44 762-75-462503680125 Carbon tetrachloride <41.6 ug/L 01/20/23 22:44 56-23-562.5 41.6 125 Chlorobenzene <35.5 ug/L 01/20/23 22:44 108-90-762.5 35.5 125 Chloroethane <81.1 ug/L 01/20/23 22:44 75-00-312581.1 125 Chloroform <53.8 ug/L 01/20/23 22:44 67-66-362.5 53.8 125 Chloromethane <67.5 ug/L 01/20/23 22:44 74-87-312567.5 125 2-Chlorotoluene <40.1 ug/L 01/20/23 22:44 95-49-862.5 40.1 125 4-Chlorotoluene <40.5 ug/L 01/20/23 22:44 106-43-462.5 40.5 125 1,2-Dibromo-3-chloropropane <42.5 ug/L 01/20/23 22:44 96-12-812542.5 125 Dibromochloromethane <44.9 ug/L 01/20/23 22:44 124-48-162.5 44.9 125 1,2-Dibromoethane (EDB)<34.0 ug/L 01/20/23 22:44 106-93-462.5 34.0 125 Dibromomethane <49.2 ug/L 01/20/23 22:44 74-95-362.5 49.2 125 1,2-Dichlorobenzene <42.4 ug/L 01/20/23 22:44 95-50-162.5 42.4 125 1,3-Dichlorobenzene <42.5 ug/L 01/20/23 22:44 541-73-162.5 42.5 125 1,4-Dichlorobenzene <41.6 ug/L 01/20/23 22:44 106-46-762.5 41.6 125 Dichlorodifluoromethane <43.2 ug/L 01/20/23 22:44 75-71-862.5 43.2 125 1,1-Dichloroethane <45.9 ug/L 01/20/23 22:44 75-34-362.5 45.9 125 1,2-Dichloroethane <40.2 ug/L 01/20/23 22:44 107-06-262.5 40.2 125 1,1-Dichloroethene <43.5 ug/L 01/20/23 22:44 75-35-462.5 43.5 125 cis-1,2-Dichloroethene <48.0 ug/L 01/20/23 22:44 156-59-262.5 48.0 125 trans-1,2-Dichloroethene <49.5 ug/L 01/20/23 22:44 156-60-562.5 49.5 125 1,2-Dichloropropane <44.4 ug/L 01/20/23 22:44 78-87-562.5 44.4 125 1,3-Dichloropropane <35.5 ug/L 01/20/23 22:44 142-28-962.5 35.5 125 2,2-Dichloropropane <48.5 ug/L 01/20/23 22:44 594-20-762.5 48.5 125 1,1-Dichloropropene <53.4 ug/L 01/20/23 22:44 563-58-662.5 53.4 125 cis-1,3-Dichloropropene <45.6 ug/L 01/20/23 22:44 10061-01-562.5 45.6 125 trans-1,3-Dichloropropene <45.4 ug/L 01/20/23 22:44 10061-02-662.5 45.4 125 Diisopropyl ether 40.6J ug/L 01/20/23 22:44 108-20-362.5 38.5 125 Ethanol <9020 ug/L 01/20/23 22:44 64-17-5250009020125 Ethylbenzene 2010 ug/L 01/20/23 22:44 100-41-462.5 38.0 125 Ethyl-tert-butyl ether <405 ug/L 01/20/23 22:44 637-92-31250405125 Hexachloro-1,3-butadiene <191 ug/L 01/20/23 22:44 87-68-3250191125 Isopropylbenzene (Cumene)74.3 ug/L 01/20/23 22:44 98-82-862.5 41.6 125 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-10 Lab ID:92646869003 Collected:01/13/23 12:00 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <244 ug/L 01/20/23 22:44 75-09-2250244125 Methyl-tert-butyl ether <52.8 ug/L 01/20/23 22:44 1634-04-462.5 52.8 125 Naphthalene 414 ug/L 01/20/23 22:44 91-20-325080.6 125 n-Propylbenzene 175 ug/L 01/20/23 22:44 103-65-162.5 42.5 125 Styrene <36.5 ug/L 01/20/23 22:44 100-42-562.5 36.5 125 1,1,1,2-Tetrachloroethane <38.9 ug/L 01/20/23 22:44 630-20-662.5 38.9 125 1,1,2,2-Tetrachloroethane <28.1 ug/L 01/20/23 22:44 79-34-562.5 28.1 125 Tetrachloroethene <36.5 ug/L 01/20/23 22:44 127-18-462.5 36.5 125 Toluene 14900 ug/L 01/20/23 22:44 108-88-362.5 29.9 125 1,2,3-Trichlorobenzene <101 ug/L 01/20/23 22:44 87-61-6250101125 1,2,4-Trichlorobenzene <79.9 ug/L 01/20/23 22:44 120-82-125079.9 125 1,1,1-Trichloroethane <41.5 ug/L 01/20/23 22:44 71-55-662.5 41.5 125 1,1,2-Trichloroethane <40.6 ug/L 01/20/23 22:44 79-00-562.5 40.6 125 Trichloroethene <47.9 ug/L 01/20/23 22:44 79-01-662.5 47.9 125 Trichlorofluoromethane <37.2 ug/L 01/20/23 22:44 75-69-412537.2 125 1,2,3-Trichloropropane <32.6 ug/L 01/20/23 22:44 96-18-462.5 32.6 125 1,2,4-Trimethylbenzene 1190 ug/L 01/20/23 22:44 95-63-662.5 61.9 125 1,3,5-Trimethylbenzene 278 ug/L 01/20/23 22:44 108-67-862.5 41.5 125 Vinyl chloride <48.2 ug/L 01/20/23 22:44 75-01-412548.2 125 Xylene (Total)7560 ug/L 01/20/23 22:44 1330-20-712542.2 125 m&p-Xylene 5620 ug/L 01/20/23 22:44 179601-23-112588.6 125 o-Xylene 1940 ug/L 01/20/23 22:44 95-47-662.5 42.2 125 Surrogates 1,2-Dichloroethane-d4 (S)108 %01/20/23 22:44 17060-07-070-130 125 4-Bromofluorobenzene (S)97 %01/20/23 22:44 460-00-470-130 125 Toluene-d8 (S)100 %01/20/23 22:44 2037-26-570-130 125 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-12 Lab ID:92646869004 Collected:01/13/23 13:00 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol 170 ug/L 01/20/23 20:55 75-85-410036.4 1 tert-Amylmethyl ether <9.2 ug/L 01/20/23 20:55 994-05-810.0 9.2 1 Benzene 77.0 ug/L 01/20/23 20:55 71-43-20.50 0.34 1 Bromobenzene <0.29 ug/L 01/20/23 20:55 108-86-10.50 0.29 1 Bromochloromethane <0.47 ug/L 01/20/23 20:55 74-97-50.50 0.47 1 Bromodichloromethane <0.31 ug/L 01/20/23 20:55 75-27-40.50 0.31 1 Bromoform <0.34 ug/L 01/20/23 20:55 75-25-20.50 0.34 1 Bromomethane <1.7 ug/L 01/20/23 20:55 74-83-95.0 1.7 1 tert-Butyl Alcohol <26.8 ug/L 01/20/23 20:55 75-65-050.0 26.8 1 n-Butylbenzene 17.6 ug/L 01/20/23 20:55 104-51-80.50 0.49 1 sec-Butylbenzene 10.1 ug/L 01/20/23 20:55 135-98-80.50 0.40 1 tert-Butylbenzene <0.32 ug/L 01/20/23 20:55 98-06-60.50 0.32 1 tert-Butyl Formate <29.4 ug/L 01/20/23 20:55 762-75-450.0 29.4 1 Carbon tetrachloride <0.33 ug/L 01/20/23 20:55 56-23-50.50 0.33 1 Chlorobenzene <0.28 ug/L 01/20/23 20:55 108-90-70.50 0.28 1 Chloroethane <0.65 ug/L 01/20/23 20:55 75-00-31.0 0.65 1 Chloroform 2.3 ug/L 01/20/23 20:55 67-66-30.50 0.43 1 Chloromethane <0.54 ug/L 01/20/23 20:55 74-87-31.0 0.54 1 2-Chlorotoluene <0.32 ug/L 01/20/23 20:55 95-49-80.50 0.32 1 4-Chlorotoluene <0.32 ug/L 01/20/23 20:55 106-43-40.50 0.32 1 1,2-Dibromo-3-chloropropane <0.34 ug/L 01/20/23 20:55 96-12-81.0 0.34 1 Dibromochloromethane <0.36 ug/L 01/20/23 20:55 124-48-10.50 0.36 1 1,2-Dibromoethane (EDB)<0.27 ug/L 01/20/23 20:55 106-93-40.50 0.27 1 Dibromomethane <0.39 ug/L 01/20/23 20:55 74-95-30.50 0.39 1 1,2-Dichlorobenzene <0.34 ug/L 01/20/23 20:55 95-50-10.50 0.34 1 1,3-Dichlorobenzene <0.34 ug/L 01/20/23 20:55 541-73-10.50 0.34 1 1,4-Dichlorobenzene <0.33 ug/L 01/20/23 20:55 106-46-70.50 0.33 1 Dichlorodifluoromethane <0.35 ug/L 01/20/23 20:55 75-71-80.50 0.35 1 1,1-Dichloroethane <0.37 ug/L 01/20/23 20:55 75-34-30.50 0.37 1 1,2-Dichloroethane <0.32 ug/L 01/20/23 20:55 107-06-20.50 0.32 1 1,1-Dichloroethene <0.35 ug/L 01/20/23 20:55 75-35-40.50 0.35 1 cis-1,2-Dichloroethene <0.38 ug/L 01/20/23 20:55 156-59-20.50 0.38 1 trans-1,2-Dichloroethene <0.40 ug/L 01/20/23 20:55 156-60-50.50 0.40 1 1,2-Dichloropropane <0.36 ug/L 01/20/23 20:55 78-87-50.50 0.36 1 1,3-Dichloropropane <0.28 ug/L 01/20/23 20:55 142-28-90.50 0.28 1 2,2-Dichloropropane <0.39 ug/L 01/20/23 20:55 594-20-70.50 0.39 1 1,1-Dichloropropene <0.43 ug/L 01/20/23 20:55 563-58-60.50 0.43 1 cis-1,3-Dichloropropene <0.36 ug/L 01/20/23 20:55 10061-01-50.50 0.36 1 trans-1,3-Dichloropropene <0.36 ug/L 01/20/23 20:55 10061-02-60.50 0.36 1 Diisopropyl ether <0.31 ug/L 01/20/23 20:55 108-20-30.50 0.31 1 Ethanol <72.2 ug/L 01/20/23 20:55 64-17-520072.2 1 Ethylbenzene 6.5 ug/L 01/20/23 20:55 100-41-40.50 0.30 1 Ethyl-tert-butyl ether <3.2 ug/L 01/20/23 20:55 637-92-310.0 3.2 1 Hexachloro-1,3-butadiene <1.5 ug/L 01/20/23 20:55 87-68-32.0 1.5 1 Isopropylbenzene (Cumene)49.8 ug/L 01/20/23 20:55 98-82-80.50 0.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-12 Lab ID:92646869004 Collected:01/13/23 13:00 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <2.0 ug/L 01/20/23 20:55 75-09-22.0 2.0 1 Methyl-tert-butyl ether <0.42 ug/L 01/20/23 20:55 1634-04-40.50 0.42 1 Naphthalene 125 ug/L 01/20/23 20:55 91-20-32.0 0.64 1 n-Propylbenzene 25.0 ug/L 01/20/23 20:55 103-65-10.50 0.34 1 Styrene <0.29 ug/L 01/20/23 20:55 100-42-50.50 0.29 1 1,1,1,2-Tetrachloroethane <0.31 ug/L 01/20/23 20:55 630-20-60.50 0.31 1 1,1,2,2-Tetrachloroethane <0.22 ug/L 01/20/23 20:55 79-34-50.50 0.22 1 Tetrachloroethene <0.29 ug/L 01/20/23 20:55 127-18-40.50 0.29 1 Toluene 0.89 ug/L 01/20/23 20:55 108-88-30.50 0.24 1 1,2,3-Trichlorobenzene <0.81 ug/L 01/20/23 20:55 87-61-62.0 0.81 1 1,2,4-Trichlorobenzene <0.64 ug/L 01/20/23 20:55 120-82-12.0 0.64 1 1,1,1-Trichloroethane <0.33 ug/L 01/20/23 20:55 71-55-60.50 0.33 1 1,1,2-Trichloroethane <0.32 ug/L 01/20/23 20:55 79-00-50.50 0.32 1 Trichloroethene <0.38 ug/L 01/20/23 20:55 79-01-60.50 0.38 1 Trichlorofluoromethane <0.30 ug/L 01/20/23 20:55 75-69-41.0 0.30 1 1,2,3-Trichloropropane <0.26 ug/L 01/20/23 20:55 96-18-40.50 0.26 1 1,2,4-Trimethylbenzene 106 ug/L 01/20/23 20:55 95-63-60.50 0.50 1 1,3,5-Trimethylbenzene 9.4 ug/L 01/20/23 20:55 108-67-80.50 0.33 1 Vinyl chloride <0.39 ug/L 01/20/23 20:55 75-01-41.0 0.39 1 Xylene (Total)18.8 ug/L 01/20/23 20:55 1330-20-71.0 0.34 1 m&p-Xylene 6.6 ug/L 01/20/23 20:55 179601-23-11.0 0.71 1 o-Xylene 12.2 ug/L 01/20/23 20:55 95-47-60.50 0.34 1 Surrogates 1,2-Dichloroethane-d4 (S)106 %01/20/23 20:55 17060-07-070-130 1 4-Bromofluorobenzene (S)100 %01/20/23 20:55 460-00-470-130 1 Toluene-d8 (S)96 %01/20/23 20:55 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-13 Lab ID:92646869005 Collected:01/13/23 13:10 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol 312 ug/L 01/23/23 14:16 75-85-410036.4 1 tert-Amylmethyl ether <9.2 ug/L 01/23/23 14:16 994-05-810.0 9.2 1 Benzene 4.9 ug/L 01/23/23 14:16 71-43-20.50 0.34 1 Bromobenzene <0.29 ug/L 01/23/23 14:16 108-86-10.50 0.29 1 Bromochloromethane <0.47 ug/L 01/23/23 14:16 74-97-50.50 0.47 1 Bromodichloromethane <0.31 ug/L 01/23/23 14:16 75-27-40.50 0.31 1 Bromoform <0.34 ug/L 01/23/23 14:16 75-25-20.50 0.34 1 Bromomethane <1.7 ug/L 01/23/23 14:16 74-83-95.0 1.7 1 tert-Butyl Alcohol <26.8 ug/L 01/23/23 14:16 75-65-050.0 26.8 1 n-Butylbenzene <0.49 ug/L 01/23/23 14:16 104-51-80.50 0.49 1 sec-Butylbenzene 1.4 ug/L 01/23/23 14:16 135-98-80.50 0.40 1 tert-Butylbenzene <0.32 ug/L 01/23/23 14:16 98-06-60.50 0.32 1 tert-Butyl Formate <29.4 ug/L 01/23/23 14:16 762-75-450.0 29.4 1 Carbon tetrachloride <0.33 ug/L 01/23/23 14:16 56-23-50.50 0.33 1 Chlorobenzene <0.28 ug/L 01/23/23 14:16 108-90-70.50 0.28 1 Chloroethane <0.65 ug/L 01/23/23 14:16 75-00-31.0 0.65 1 Chloroform <0.43 ug/L 01/23/23 14:16 67-66-30.50 0.43 1 Chloromethane <0.54 ug/L 01/23/23 14:16 74-87-31.0 0.54 1 2-Chlorotoluene <0.32 ug/L 01/23/23 14:16 95-49-80.50 0.32 1 4-Chlorotoluene <0.32 ug/L 01/23/23 14:16 106-43-40.50 0.32 1 1,2-Dibromo-3-chloropropane <0.34 ug/L 01/23/23 14:16 96-12-81.0 0.34 1 Dibromochloromethane <0.36 ug/L 01/23/23 14:16 124-48-10.50 0.36 1 1,2-Dibromoethane (EDB)<0.27 ug/L 01/23/23 14:16 106-93-40.50 0.27 1 Dibromomethane <0.39 ug/L 01/23/23 14:16 74-95-30.50 0.39 1 1,2-Dichlorobenzene <0.34 ug/L 01/23/23 14:16 95-50-10.50 0.34 1 1,3-Dichlorobenzene <0.34 ug/L 01/23/23 14:16 541-73-10.50 0.34 1 1,4-Dichlorobenzene <0.33 ug/L 01/23/23 14:16 106-46-70.50 0.33 1 Dichlorodifluoromethane <0.35 ug/L 01/23/23 14:16 75-71-80.50 0.35 1 1,1-Dichloroethane <0.37 ug/L 01/23/23 14:16 75-34-30.50 0.37 1 1,2-Dichloroethane <0.32 ug/L 01/23/23 14:16 107-06-20.50 0.32 1 1,1-Dichloroethene <0.35 ug/L 01/23/23 14:16 75-35-40.50 0.35 1 cis-1,2-Dichloroethene <0.38 ug/L 01/23/23 14:16 156-59-20.50 0.38 1 trans-1,2-Dichloroethene <0.40 ug/L 01/23/23 14:16 156-60-50.50 0.40 1 1,2-Dichloropropane <0.36 ug/L 01/23/23 14:16 78-87-50.50 0.36 1 1,3-Dichloropropane <0.28 ug/L 01/23/23 14:16 142-28-90.50 0.28 1 2,2-Dichloropropane <0.39 ug/L 01/23/23 14:16 594-20-70.50 0.39 1 1,1-Dichloropropene <0.43 ug/L 01/23/23 14:16 563-58-60.50 0.43 1 cis-1,3-Dichloropropene <0.36 ug/L 01/23/23 14:16 10061-01-50.50 0.36 1 trans-1,3-Dichloropropene <0.36 ug/L 01/23/23 14:16 10061-02-60.50 0.36 1 Diisopropyl ether 0.33J ug/L 01/23/23 14:16 108-20-30.50 0.31 1 Ethanol 166J ug/L 01/23/23 14:16 64-17-520072.2 1 Ethylbenzene <0.30 ug/L 01/23/23 14:16 100-41-40.50 0.30 1 Ethyl-tert-butyl ether <3.2 ug/L 01/23/23 14:16 637-92-310.0 3.2 1 Hexachloro-1,3-butadiene <1.5 ug/L 01/23/23 14:16 87-68-32.0 1.5 1 Isopropylbenzene (Cumene)1.0 ug/L 01/23/23 14:16 98-82-80.50 0.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:MW-13 Lab ID:92646869005 Collected:01/13/23 13:10 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <2.0 ug/L 01/23/23 14:16 75-09-22.0 2.0 1 Methyl-tert-butyl ether 0.72 ug/L 01/23/23 14:16 1634-04-40.50 0.42 1 Naphthalene 1.1J ug/L 01/23/23 14:16 91-20-32.0 0.64 1 n-Propylbenzene <0.34 ug/L 01/23/23 14:16 103-65-10.50 0.34 1 Styrene <0.29 ug/L 01/23/23 14:16 100-42-50.50 0.29 1 1,1,1,2-Tetrachloroethane <0.31 ug/L 01/23/23 14:16 630-20-60.50 0.31 1 1,1,2,2-Tetrachloroethane <0.22 ug/L 01/23/23 14:16 79-34-50.50 0.22 1 Tetrachloroethene <0.29 ug/L 01/23/23 14:16 127-18-40.50 0.29 1 Toluene 0.46J ug/L 01/23/23 14:16 108-88-30.50 0.24 1 1,2,3-Trichlorobenzene <0.81 ug/L 01/23/23 14:16 87-61-62.0 0.81 1 1,2,4-Trichlorobenzene <0.64 ug/L 01/23/23 14:16 120-82-12.0 0.64 1 1,1,1-Trichloroethane <0.33 ug/L 01/23/23 14:16 71-55-60.50 0.33 1 1,1,2-Trichloroethane <0.32 ug/L 01/23/23 14:16 79-00-50.50 0.32 1 Trichloroethene <0.38 ug/L 01/23/23 14:16 79-01-60.50 0.38 1 Trichlorofluoromethane <0.30 ug/L 01/23/23 14:16 75-69-41.0 0.30 1 1,2,3-Trichloropropane <0.26 ug/L 01/23/23 14:16 96-18-40.50 0.26 1 1,2,4-Trimethylbenzene <0.50 ug/L 01/23/23 14:16 95-63-60.50 0.50 1 1,3,5-Trimethylbenzene <0.33 ug/L 01/23/23 14:16 108-67-80.50 0.33 1 Vinyl chloride <0.39 ug/L 01/23/23 14:16 75-01-41.0 0.39 1 Xylene (Total)<0.34 ug/L 01/23/23 14:16 1330-20-71.0 0.34 1 m&p-Xylene <0.71 ug/L 01/23/23 14:16 179601-23-11.0 0.71 1 o-Xylene <0.34 ug/L 01/23/23 14:16 95-47-60.50 0.34 1 Surrogates 1,2-Dichloroethane-d4 (S)115 %01/23/23 14:16 17060-07-070-130 1 4-Bromofluorobenzene (S)100 %01/23/23 14:16 460-00-470-130 1 Toluene-d8 (S)101 %01/23/23 14:16 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:FB-1 Lab ID:92646869006 Collected:01/13/23 13:15 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol <36.4 ug/L 01/17/23 14:53 75-85-410036.4 1 tert-Amylmethyl ether <9.2 ug/L 01/17/23 14:53 994-05-810.0 9.2 1 Benzene <0.34 ug/L 01/17/23 14:53 71-43-20.50 0.34 1 Bromobenzene <0.29 ug/L 01/17/23 14:53 108-86-10.50 0.29 1 Bromochloromethane <0.47 ug/L 01/17/23 14:53 74-97-50.50 0.47 1 Bromodichloromethane <0.31 ug/L 01/17/23 14:53 75-27-40.50 0.31 1 Bromoform <0.34 ug/L 01/17/23 14:53 75-25-20.50 0.34 1 Bromomethane <1.7 ug/L 01/17/23 14:53 74-83-95.0 1.7 1 tert-Butyl Alcohol <26.8 ug/L 01/17/23 14:53 75-65-050.0 26.8 1 n-Butylbenzene <0.49 ug/L 01/17/23 14:53 104-51-80.50 0.49 1 sec-Butylbenzene <0.40 ug/L 01/17/23 14:53 135-98-80.50 0.40 1 tert-Butylbenzene <0.32 ug/L 01/17/23 14:53 98-06-60.50 0.32 1 tert-Butyl Formate <29.4 ug/L 01/17/23 14:53 762-75-450.0 29.4 1 Carbon tetrachloride <0.33 ug/L 01/17/23 14:53 56-23-50.50 0.33 1 Chlorobenzene <0.28 ug/L 01/17/23 14:53 108-90-70.50 0.28 1 Chloroethane <0.65 ug/L 01/17/23 14:53 75-00-31.0 0.65 1 Chloroform <0.43 ug/L 01/17/23 14:53 67-66-30.50 0.43 1 Chloromethane <0.54 ug/L 01/17/23 14:53 74-87-31.0 0.54 1 2-Chlorotoluene <0.32 ug/L 01/17/23 14:53 95-49-80.50 0.32 1 4-Chlorotoluene <0.32 ug/L 01/17/23 14:53 106-43-40.50 0.32 1 1,2-Dibromo-3-chloropropane <0.34 ug/L 01/17/23 14:53 96-12-81.0 0.34 1 Dibromochloromethane <0.36 ug/L 01/17/23 14:53 124-48-10.50 0.36 1 1,2-Dibromoethane (EDB)<0.27 ug/L 01/17/23 14:53 106-93-40.50 0.27 1 Dibromomethane <0.39 ug/L 01/17/23 14:53 74-95-30.50 0.39 1 1,2-Dichlorobenzene <0.34 ug/L 01/17/23 14:53 95-50-10.50 0.34 1 1,3-Dichlorobenzene <0.34 ug/L 01/17/23 14:53 541-73-10.50 0.34 1 1,4-Dichlorobenzene <0.33 ug/L 01/17/23 14:53 106-46-70.50 0.33 1 Dichlorodifluoromethane <0.35 ug/L 01/17/23 14:53 75-71-80.50 0.35 1 1,1-Dichloroethane <0.37 ug/L 01/17/23 14:53 75-34-30.50 0.37 1 1,2-Dichloroethane <0.32 ug/L 01/17/23 14:53 107-06-20.50 0.32 1 1,1-Dichloroethene <0.35 ug/L 01/17/23 14:53 75-35-40.50 0.35 1 cis-1,2-Dichloroethene <0.38 ug/L 01/17/23 14:53 156-59-20.50 0.38 1 trans-1,2-Dichloroethene <0.40 ug/L 01/17/23 14:53 156-60-50.50 0.40 1 1,2-Dichloropropane <0.36 ug/L 01/17/23 14:53 78-87-50.50 0.36 1 1,3-Dichloropropane <0.28 ug/L 01/17/23 14:53 142-28-90.50 0.28 1 2,2-Dichloropropane <0.39 ug/L 01/17/23 14:53 594-20-70.50 0.39 1 1,1-Dichloropropene <0.43 ug/L 01/17/23 14:53 563-58-60.50 0.43 1 cis-1,3-Dichloropropene <0.36 ug/L 01/17/23 14:53 10061-01-50.50 0.36 1 trans-1,3-Dichloropropene <0.36 ug/L 01/17/23 14:53 10061-02-60.50 0.36 1 Diisopropyl ether <0.31 ug/L 01/17/23 14:53 108-20-30.50 0.31 1 Ethanol <72.2 ug/L 01/17/23 14:53 64-17-520072.2 1 Ethylbenzene <0.30 ug/L 01/17/23 14:53 100-41-40.50 0.30 1 Ethyl-tert-butyl ether <3.2 ug/L 01/17/23 14:53 637-92-310.0 3.2 1 Hexachloro-1,3-butadiene <1.5 ug/L 01/17/23 14:53 87-68-32.0 1.5 1 Isopropylbenzene (Cumene)<0.33 ug/L 01/17/23 14:53 98-82-80.50 0.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 36 raceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Sample:FB-1 Lab ID:92646869006 Collected:01/13/23 13:15 Received:01/13/23 15:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <2.0 ug/L 01/17/23 14:53 75-09-22.0 2.0 1 Methyl-tert-butyl ether <0.42 ug/L 01/17/23 14:53 1634-04-40.50 0.42 1 Naphthalene <0.64 ug/L 01/17/23 14:53 91-20-32.0 0.64 1 n-Propylbenzene <0.34 ug/L 01/17/23 14:53 103-65-10.50 0.34 1 Styrene <0.29 ug/L 01/17/23 14:53 100-42-50.50 0.29 1 1,1,1,2-Tetrachloroethane <0.31 ug/L 01/17/23 14:53 630-20-60.50 0.31 1 1,1,2,2-Tetrachloroethane <0.22 ug/L 01/17/23 14:53 79-34-50.50 0.22 1 Tetrachloroethene <0.29 ug/L 01/17/23 14:53 127-18-40.50 0.29 1 Toluene <0.24 ug/L 01/17/23 14:53 108-88-30.50 0.24 1 1,2,3-Trichlorobenzene <0.81 ug/L 01/17/23 14:53 87-61-62.0 0.81 1 1,2,4-Trichlorobenzene <0.64 ug/L 01/17/23 14:53 120-82-12.0 0.64 1 1,1,1-Trichloroethane <0.33 ug/L 01/17/23 14:53 71-55-60.50 0.33 1 1,1,2-Trichloroethane <0.32 ug/L 01/17/23 14:53 79-00-50.50 0.32 1 Trichloroethene <0.38 ug/L 01/17/23 14:53 79-01-60.50 0.38 1 Trichlorofluoromethane <0.30 ug/L 01/17/23 14:53 75-69-41.0 0.30 1 1,2,3-Trichloropropane <0.26 ug/L 01/17/23 14:53 96-18-40.50 0.26 1 1,2,4-Trimethylbenzene <0.50 ug/L 01/17/23 14:53 95-63-60.50 0.50 1 1,3,5-Trimethylbenzene <0.33 ug/L 01/17/23 14:53 108-67-80.50 0.33 1 Vinyl chloride <0.39 ug/L 01/17/23 14:53 75-01-41.0 0.39 1 Xylene (Total)<0.34 ug/L 01/17/23 14:53 1330-20-71.0 0.34 1 m&p-Xylene <0.71 ug/L 01/17/23 14:53 179601-23-11.0 0.71 1 o-Xylene <0.34 ug/L 01/17/23 14:53 95-47-60.50 0.34 1 Surrogates 1,2-Dichloroethane-d4 (S)99 %01/17/23 14:53 17060-07-070-130 1 4-Bromofluorobenzene (S)100 %01/17/23 14:53 460-00-470-130 1 Toluene-d8 (S)108 %01/17/23 14:53 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 749777 SM 6200B SM 6200B 6200B MSV Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92646869006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3897382 Associated Lab Samples:92646869006 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 01/17/23 12:290.31 1,1,1-Trichloroethane ug/L <0.33 0.50 01/17/23 12:290.33 1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 01/17/23 12:290.22 1,1,2-Trichloroethane ug/L <0.32 0.50 01/17/23 12:290.32 1,1-Dichloroethane ug/L <0.37 0.50 01/17/23 12:290.37 1,1-Dichloroethene ug/L <0.35 0.50 01/17/23 12:290.35 1,1-Dichloropropene ug/L <0.43 0.50 01/17/23 12:290.43 1,2,3-Trichlorobenzene ug/L <0.81 2.0 01/17/23 12:290.81 1,2,3-Trichloropropane ug/L <0.26 0.50 01/17/23 12:290.26 1,2,4-Trichlorobenzene ug/L <0.64 2.0 01/17/23 12:290.64 1,2,4-Trimethylbenzene ug/L <0.50 0.50 01/17/23 12:290.50 1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 01/17/23 12:290.34 1,2-Dibromoethane (EDB)ug/L <0.27 0.50 01/17/23 12:290.27 1,2-Dichlorobenzene ug/L <0.34 0.50 01/17/23 12:290.34 1,2-Dichloroethane ug/L <0.32 0.50 01/17/23 12:290.32 1,2-Dichloropropane ug/L <0.36 0.50 01/17/23 12:290.36 1,3,5-Trimethylbenzene ug/L <0.33 0.50 01/17/23 12:290.33 1,3-Dichlorobenzene ug/L <0.34 0.50 01/17/23 12:290.34 1,3-Dichloropropane ug/L <0.28 0.50 01/17/23 12:290.28 1,4-Dichlorobenzene ug/L <0.33 0.50 01/17/23 12:290.33 2,2-Dichloropropane ug/L <0.39 0.50 01/17/23 12:290.39 2-Chlorotoluene ug/L <0.32 0.50 01/17/23 12:290.32 4-Chlorotoluene ug/L <0.32 0.50 01/17/23 12:290.32 Benzene ug/L <0.34 0.50 01/17/23 12:290.34 Bromobenzene ug/L <0.29 0.50 01/17/23 12:290.29 Bromochloromethane ug/L <0.47 0.50 01/17/23 12:290.47 Bromodichloromethane ug/L <0.31 0.50 01/17/23 12:290.31 Bromoform ug/L <0.34 0.50 01/17/23 12:290.34 Bromomethane ug/L <1.7 5.0 01/17/23 12:291.7 Carbon tetrachloride ug/L <0.33 0.50 01/17/23 12:290.33 Chlorobenzene ug/L <0.28 0.50 01/17/23 12:290.28 Chloroethane ug/L <0.65 1.0 01/17/23 12:290.65 Chloroform ug/L <0.43 0.50 01/17/23 12:290.43 Chloromethane ug/L <0.54 1.0 01/17/23 12:290.54 cis-1,2-Dichloroethene ug/L <0.38 0.50 01/17/23 12:290.38 cis-1,3-Dichloropropene ug/L <0.36 0.50 01/17/23 12:290.36 Dibromochloromethane ug/L <0.36 0.50 01/17/23 12:290.36 Dibromomethane ug/L <0.39 0.50 01/17/23 12:290.39 Dichlorodifluoromethane ug/L <0.35 0.50 01/17/23 12:290.35 Diisopropyl ether ug/L <0.31 0.50 01/17/23 12:290.31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3897382 Associated Lab Samples:92646869006 Matrix:Water AnalyzedMDL Ethanol ug/L <72.2 200 01/17/23 12:2972.2 Ethyl-tert-butyl ether ug/L <3.2 10.0 01/17/23 12:293.2 Ethylbenzene ug/L <0.30 0.50 01/17/23 12:290.30 Hexachloro-1,3-butadiene ug/L <1.5 2.0 01/17/23 12:291.5 Isopropylbenzene (Cumene)ug/L <0.33 0.50 01/17/23 12:290.33 m&p-Xylene ug/L <0.71 1.0 01/17/23 12:290.71 Methyl-tert-butyl ether ug/L <0.42 0.50 01/17/23 12:290.42 Methylene Chloride ug/L <2.0 2.0 01/17/23 12:292.0 n-Butylbenzene ug/L <0.49 0.50 01/17/23 12:290.49 n-Propylbenzene ug/L <0.34 0.50 01/17/23 12:290.34 Naphthalene ug/L <0.64 2.0 01/17/23 12:290.64 o-Xylene ug/L <0.34 0.50 01/17/23 12:290.34 sec-Butylbenzene ug/L <0.40 0.50 01/17/23 12:290.40 Styrene ug/L <0.29 0.50 01/17/23 12:290.29 tert-Amyl Alcohol ug/L <36.4 100 01/17/23 12:2936.4 tert-Amylmethyl ether ug/L <9.2 10.0 01/17/23 12:299.2 tert-Butyl Alcohol ug/L <26.8 50.0 01/17/23 12:2926.8 tert-Butyl Formate ug/L <29.4 50.0 01/17/23 12:2929.4 tert-Butylbenzene ug/L <0.32 0.50 01/17/23 12:290.32 Tetrachloroethene ug/L <0.29 0.50 01/17/23 12:290.29 Toluene ug/L <0.24 0.50 01/17/23 12:290.24 trans-1,2-Dichloroethene ug/L <0.40 0.50 01/17/23 12:290.40 trans-1,3-Dichloropropene ug/L <0.36 0.50 01/17/23 12:290.36 Trichloroethene ug/L <0.38 0.50 01/17/23 12:290.38 Trichlorofluoromethane ug/L <0.30 1.0 01/17/23 12:290.30 Vinyl chloride ug/L <0.39 1.0 01/17/23 12:290.39 Xylene (Total)ug/L <0.34 1.0 01/17/23 12:290.34 1,2-Dichloroethane-d4 (S)%101 70-130 01/17/23 12:29 4-Bromofluorobenzene (S)%99 70-130 01/17/23 12:29 Toluene-d8 (S)%108 70-130 01/17/23 12:29 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3897383LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 20.520 102 60-140 1,1,1-Trichloroethane ug/L 23.920 119 60-140 1,1,2,2-Tetrachloroethane ug/L 22.020 110 60-140 1,1,2-Trichloroethane ug/L 21.520 108 60-140 1,1-Dichloroethane ug/L 23.620 118 60-140 1,1-Dichloroethene ug/L 25.520 127 60-140 1,1-Dichloropropene ug/L 22.820 114 60-140 1,2,3-Trichlorobenzene ug/L 23.320 117 60-140 1,2,3-Trichloropropane ug/L 20.620 103 60-140 1,2,4-Trichlorobenzene ug/L 22.420 112 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3897383LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trimethylbenzene ug/L 23.120 115 60-140 1,2-Dibromo-3-chloropropane ug/L 22.620 113 60-140 1,2-Dibromoethane (EDB)ug/L 22.720 114 60-140 1,2-Dichlorobenzene ug/L 20.020 100 60-140 1,2-Dichloroethane ug/L 23.420 117 60-140 1,2-Dichloropropane ug/L 24.320 122 60-140 1,3,5-Trimethylbenzene ug/L 23.620 118 60-140 1,3-Dichlorobenzene ug/L 20.920 105 60-140 1,3-Dichloropropane ug/L 23.020 115 60-140 1,4-Dichlorobenzene ug/L 20.420 102 60-140 2,2-Dichloropropane ug/L 24.520 122 60-140 2-Chlorotoluene ug/L 21.020 105 60-140 4-Chlorotoluene ug/L 22.920 115 60-140 Benzene ug/L 22.120 110 60-140 Bromobenzene ug/L 21.920 110 60-140 Bromochloromethane ug/L 22.420 112 60-140 Bromodichloromethane ug/L 24.320 121 60-140 Bromoform ug/L 21.520 108 60-140 Bromomethane ug/L 20.720 104 60-140 Carbon tetrachloride ug/L 25.620 128 60-140 Chlorobenzene ug/L 22.320 111 60-140 Chloroethane ug/L 25.720 129 60-140 Chloroform ug/L 24.220 121 60-140 Chloromethane ug/L 25.120 126 60-140 cis-1,2-Dichloroethene ug/L 23.520 118 60-140 cis-1,3-Dichloropropene ug/L 23.920 120 60-140 Dibromochloromethane ug/L 22.820 114 60-140 Dibromomethane ug/L 23.020 115 60-140 Dichlorodifluoromethane ug/L 25.020 125 60-140 Diisopropyl ether ug/L 22.820 114 60-140 Ethanol ug/L 932800 116 60-140 Ethyl-tert-butyl ether ug/L 41.940 105 60-140 Ethylbenzene ug/L 22.120 111 60-140 Hexachloro-1,3-butadiene ug/L 23.720 119 60-140 Isopropylbenzene (Cumene)ug/L 21.920 110 60-140 m&p-Xylene ug/L 45.940 115 60-140 Methyl-tert-butyl ether ug/L 22.520 113 60-140 Methylene Chloride ug/L 23.820 119 60-140 n-Butylbenzene ug/L 25.320 126 60-140 n-Propylbenzene ug/L 23.120 116 60-140 Naphthalene ug/L 26.620 133 60-140 o-Xylene ug/L 23.020 115 60-140 sec-Butylbenzene ug/L 23.920 120 60-140 Styrene ug/L 23.420 117 60-140 tert-Amyl Alcohol ug/L 434400 108 60-140 tert-Amylmethyl ether ug/L 43.040 108 60-140 tert-Butyl Alcohol ug/L 206200 103 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3897383LABORATORY CONTROL SAMPLE: LCSSpike tert-Butyl Formate ug/L 173160 108 60-140 tert-Butylbenzene ug/L 20.020 100 60-140 Tetrachloroethene ug/L 21.220 106 60-140 Toluene ug/L 22.420 112 60-140 trans-1,2-Dichloroethene ug/L 23.720 119 60-140 trans-1,3-Dichloropropene ug/L 23.320 116 60-140 Trichloroethene ug/L 24.820 124 60-140 Trichlorofluoromethane ug/L 22.020 110 60-140 Vinyl chloride ug/L 24.620 123 60-140 Xylene (Total)ug/L 68.960 115 60-140 1,2-Dichloroethane-d4 (S)%104 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 3897384MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92646897001 3897385 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 85 60-140100 16 3020<0.31 17.0 20.1 1,1,1-Trichloroethane ug/L 20 111 60-140124 10 3020<0.33 22.3 24.7 1,1,2,2-Tetrachloroethane ug/L 20 93 60-140106 14 3020<0.22 18.5 21.3 1,1,2-Trichloroethane ug/L 20 101 60-140108 7 3020<0.32 20.2 21.6 1,1-Dichloroethane ug/L 20 109 60-140119 9 3020<0.37 21.8 23.8 1,1-Dichloroethene ug/L 20 118 60-140132 11 3020<0.35 23.6 26.4 1,1-Dichloropropene ug/L 20 104 60-140116 11 3020<0.43 20.9 23.3 1,2,3-Trichlorobenzene ug/L 20 86 60-14099 14 3020<0.81 17.2 19.9 1,2,3-Trichloropropane ug/L 20 86 60-140104 18 3020<0.26 17.3 20.8 1,2,4-Trichlorobenzene ug/L 20 88 60-14098 11 3020<0.64 17.6 19.6 1,2,4-Trimethylbenzene ug/L 20 98 60-140116 16 3020<0.50 19.7 23.2 1,2-Dibromo-3- chloropropane ug/L 20 94 60-140108 14 3020<0.34 18.8 21.5 1,2-Dibromoethane (EDB)ug/L 20 97 60-140111 14 3020<0.27 19.4 22.2 1,2-Dichlorobenzene ug/L 20 85 60-14099 16 3020<0.34 16.9 19.9 1,2-Dichloroethane ug/L 20 105 60-140121 14 3020<0.32 21.1 24.2 1,2-Dichloropropane ug/L 20 108 60-140120 10 3020<0.36 21.6 23.9 1,3,5-Trimethylbenzene ug/L 20 104 60-140119 13 3020<0.33 20.9 23.9 1,3-Dichlorobenzene ug/L 20 86 60-140102 17 3020<0.34 17.2 20.4 1,3-Dichloropropane ug/L 20 98 60-140113 15 3020<0.28 19.5 22.6 1,4-Dichlorobenzene ug/L 20 84 60-14096 14 3020<0.33 16.8 19.3 2,2-Dichloropropane ug/L 20 112 60-140120 6 3020<0.39 22.5 24.0 2-Chlorotoluene ug/L 20 94 60-140109 15 3020<0.32 18.8 21.8 4-Chlorotoluene ug/L 20 98 60-140110 12 3020<0.32 19.5 21.9 Benzene ug/L 20 101 60-140113 11 3020<0.34 20.2 22.6 Bromobenzene ug/L 20 93 60-140107 13 3020<0.29 18.7 21.3 Bromochloromethane ug/L 20 99 60-140115 15 3020<0.47 19.8 23.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3897384MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92646897001 3897385 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Bromodichloromethane ug/L 20 110 60-140115 5 3020<0.31 21.9 23.0 Bromoform ug/L 20 90 60-140102 13 3020<0.34 18.0 20.4 Bromomethane ug/L 20 65 60-14089 30 3020<1.7 13.1 17.7 Carbon tetrachloride ug/L 20 118 60-140128 8 3020<0.33 23.6 25.5 Chlorobenzene ug/L 20 96 60-140113 16 3020<0.28 19.2 22.6 Chloroethane ug/L 20 121 60-140134 10 3020<0.65 24.2 26.8 Chloroform ug/L 20 108 60-140121 12 3020<0.43 21.6 24.2 Chloromethane ug/L 20 118 60-140131 11 3020<0.54 23.5 26.1 cis-1,2-Dichloroethene ug/L 20 107 60-140120 11 3020<0.38 21.4 23.9 cis-1,3-Dichloropropene ug/L 20 105 60-140115 9 3020<0.36 21.0 23.0 Dibromochloromethane ug/L 20 94 60-140116 20 3020<0.36 18.9 23.1 Dibromomethane ug/L 20 97 60-140105 8 3020<0.39 19.5 21.1 Dichlorodifluoromethane ug/L 20 106 60-140118 11 3020<0.35 21.2 23.6 Diisopropyl ether ug/L 20 101 60-140115 13 3020<0.31 20.2 22.9 Ethanol ug/L 800 101 60-140117 15 30800<72.2 807 939 Ethyl-tert-butyl ether ug/L 40 90 60-140101 12 3040<3.2 36.0 40.4 Ethylbenzene ug/L 20 97 60-140112 14 3020<0.30 19.5 22.4 Hexachloro-1,3-butadiene ug/L 20 89 60-140115 25 3020<1.5 17.8 22.9 Isopropylbenzene (Cumene)ug/L 20 95 60-140114 18 3020<0.33 19.1 22.7 m&p-Xylene ug/L 40 96 60-140113 16 3040<0.71 38.4 45.1 Methyl-tert-butyl ether ug/L 20 93 60-140102 9 3020<0.42 18.5 20.4 Methylene Chloride ug/L 20 106 60-140119 12 3020<2.0 21.2 23.9 n-Butylbenzene ug/L 20 106 60-140124 16 3020<0.49 21.2 24.8 n-Propylbenzene ug/L 20 101 60-140114 12 3020<0.34 20.2 22.7 Naphthalene ug/L 20 92 60-140113 21 3020<0.64 18.3 22.6 o-Xylene ug/L 20 94 60-140116 21 3020<0.34 18.9 23.2 sec-Butylbenzene ug/L 20 102 60-140121 17 3020<0.40 20.5 24.2 Styrene ug/L 20 93 60-140110 17 3020<0.29 18.6 22.1 tert-Amyl Alcohol ug/L 400 91 60-14099 9 30400<36.4 363 398 tert-Amylmethyl ether ug/L 40 93 60-140101 8 3040<9.2 37.2 40.3 tert-Butyl Alcohol ug/L M120012960-140141 9 30200<26.8 259 282 tert-Butyl Formate ug/L P5160660-1405 30160<29.4 <29.4 <29.4 tert-Butylbenzene ug/L 20 88 60-140101 14 3020<0.32 17.6 20.2 Tetrachloroethene ug/L 20 91 60-140106 15 3020<0.29 18.3 21.2 Toluene ug/L 20 103 60-140112 8 3020<0.24 20.6 22.3 trans-1,2-Dichloroethene ug/L 20 111 60-140124 11 3020<0.40 22.1 24.8 trans-1,3-Dichloropropene ug/L 20 100 60-140112 12 3020<0.36 20.0 22.4 Trichloroethene ug/L 20 111 60-140116 4 3020<0.38 22.1 23.1 Trichlorofluoromethane ug/L 20 109 60-140119 9 3020<0.30 21.8 23.7 Vinyl chloride ug/L 20 116 60-140125 8 3020<0.39 23.1 25.1 Xylene (Total)ug/L 60 96 60-140114 18 3060<0.34 57.3 68.4 1,2-Dichloroethane-d4 (S)%112 70-130107 4-Bromofluorobenzene (S)%99 70-130100 Toluene-d8 (S)%102 70-13096 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 750552 SM 6200B SM 6200B 6200B MSV Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92646869001, 92646869002, 92646869003, 92646869004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3901051 Associated Lab Samples:92646869001, 92646869002, 92646869003, 92646869004 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 01/20/23 14:510.31 1,1,1-Trichloroethane ug/L <0.33 0.50 01/20/23 14:510.33 1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 01/20/23 14:510.22 1,1,2-Trichloroethane ug/L <0.32 0.50 01/20/23 14:510.32 1,1-Dichloroethane ug/L <0.37 0.50 01/20/23 14:510.37 1,1-Dichloroethene ug/L <0.35 0.50 01/20/23 14:510.35 1,1-Dichloropropene ug/L <0.43 0.50 01/20/23 14:510.43 1,2,3-Trichlorobenzene ug/L <0.81 2.0 01/20/23 14:510.81 1,2,3-Trichloropropane ug/L <0.26 0.50 01/20/23 14:510.26 1,2,4-Trichlorobenzene ug/L <0.64 2.0 01/20/23 14:510.64 1,2,4-Trimethylbenzene ug/L <0.50 0.50 01/20/23 14:510.50 1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 01/20/23 14:510.34 1,2-Dibromoethane (EDB)ug/L <0.27 0.50 01/20/23 14:510.27 1,2-Dichlorobenzene ug/L <0.34 0.50 01/20/23 14:510.34 1,2-Dichloroethane ug/L <0.32 0.50 01/20/23 14:510.32 1,2-Dichloropropane ug/L <0.36 0.50 01/20/23 14:510.36 1,3,5-Trimethylbenzene ug/L <0.33 0.50 01/20/23 14:510.33 1,3-Dichlorobenzene ug/L <0.34 0.50 01/20/23 14:510.34 1,3-Dichloropropane ug/L <0.28 0.50 01/20/23 14:510.28 1,4-Dichlorobenzene ug/L <0.33 0.50 01/20/23 14:510.33 2,2-Dichloropropane ug/L <0.39 0.50 01/20/23 14:510.39 2-Chlorotoluene ug/L <0.32 0.50 01/20/23 14:510.32 4-Chlorotoluene ug/L <0.32 0.50 01/20/23 14:510.32 Benzene ug/L <0.34 0.50 01/20/23 14:510.34 Bromobenzene ug/L <0.29 0.50 01/20/23 14:510.29 Bromochloromethane ug/L <0.47 0.50 01/20/23 14:510.47 Bromodichloromethane ug/L <0.31 0.50 01/20/23 14:510.31 Bromoform ug/L <0.34 0.50 01/20/23 14:510.34 Bromomethane ug/L <1.7 5.0 01/20/23 14:511.7 Carbon tetrachloride ug/L <0.33 0.50 01/20/23 14:510.33 Chlorobenzene ug/L <0.28 0.50 01/20/23 14:510.28 Chloroethane ug/L <0.65 1.0 01/20/23 14:510.65 Chloroform ug/L <0.43 0.50 01/20/23 14:510.43 Chloromethane ug/L <0.54 1.0 01/20/23 14:510.54 cis-1,2-Dichloroethene ug/L <0.38 0.50 01/20/23 14:510.38 cis-1,3-Dichloropropene ug/L <0.36 0.50 01/20/23 14:510.36 Dibromochloromethane ug/L <0.36 0.50 01/20/23 14:510.36 Dibromomethane ug/L <0.39 0.50 01/20/23 14:510.39 Dichlorodifluoromethane ug/L <0.35 0.50 01/20/23 14:510.35 Diisopropyl ether ug/L <0.31 0.50 01/20/23 14:510.31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3901051 Associated Lab Samples:92646869001, 92646869002, 92646869003, 92646869004 Matrix:Water AnalyzedMDL Ethanol ug/L <72.2 200 01/20/23 14:5172.2 Ethyl-tert-butyl ether ug/L <3.2 10.0 01/20/23 14:513.2 Ethylbenzene ug/L <0.30 0.50 01/20/23 14:510.30 Hexachloro-1,3-butadiene ug/L <1.5 2.0 01/20/23 14:511.5 Isopropylbenzene (Cumene)ug/L <0.33 0.50 01/20/23 14:510.33 m&p-Xylene ug/L <0.71 1.0 01/20/23 14:510.71 Methyl-tert-butyl ether ug/L <0.42 0.50 01/20/23 14:510.42 Methylene Chloride ug/L <2.0 2.0 01/20/23 14:512.0 n-Butylbenzene ug/L <0.49 0.50 01/20/23 14:510.49 n-Propylbenzene ug/L <0.34 0.50 01/20/23 14:510.34 Naphthalene ug/L <0.64 2.0 01/20/23 14:510.64 o-Xylene ug/L <0.34 0.50 01/20/23 14:510.34 sec-Butylbenzene ug/L <0.40 0.50 01/20/23 14:510.40 Styrene ug/L <0.29 0.50 01/20/23 14:510.29 tert-Amyl Alcohol ug/L <36.4 100 01/20/23 14:5136.4 tert-Amylmethyl ether ug/L <9.2 10.0 01/20/23 14:519.2 tert-Butyl Alcohol ug/L <26.8 50.0 01/20/23 14:5126.8 tert-Butyl Formate ug/L <29.4 50.0 01/20/23 14:5129.4 tert-Butylbenzene ug/L <0.32 0.50 01/20/23 14:510.32 Tetrachloroethene ug/L <0.29 0.50 01/20/23 14:510.29 Toluene ug/L <0.24 0.50 01/20/23 14:510.24 trans-1,2-Dichloroethene ug/L <0.40 0.50 01/20/23 14:510.40 trans-1,3-Dichloropropene ug/L <0.36 0.50 01/20/23 14:510.36 Trichloroethene ug/L <0.38 0.50 01/20/23 14:510.38 Trichlorofluoromethane ug/L <0.30 1.0 01/20/23 14:510.30 Vinyl chloride ug/L <0.39 1.0 01/20/23 14:510.39 Xylene (Total)ug/L <0.34 1.0 01/20/23 14:510.34 1,2-Dichloroethane-d4 (S)%106 70-130 01/20/23 14:51 4-Bromofluorobenzene (S)%97 70-130 01/20/23 14:51 Toluene-d8 (S)%103 70-130 01/20/23 14:51 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3901052LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 21.220 106 60-140 1,1,1-Trichloroethane ug/L 23.120 115 60-140 1,1,2,2-Tetrachloroethane ug/L 20.820 104 60-140 1,1,2-Trichloroethane ug/L 21.920 109 60-140 1,1-Dichloroethane ug/L 23.120 115 60-140 1,1-Dichloroethene ug/L 25.320 127 60-140 1,1-Dichloropropene ug/L 24.820 124 60-140 1,2,3-Trichlorobenzene ug/L 23.720 118 60-140 1,2,3-Trichloropropane ug/L 21.020 105 60-140 1,2,4-Trichlorobenzene ug/L 23.020 115 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3901052LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trimethylbenzene ug/L 22.720 113 60-140 1,2-Dibromo-3-chloropropane ug/L 20.820 104 60-140 1,2-Dibromoethane (EDB)ug/L 22.720 113 60-140 1,2-Dichlorobenzene ug/L 21.820 109 60-140 1,2-Dichloroethane ug/L 22.720 114 60-140 1,2-Dichloropropane ug/L 22.820 114 60-140 1,3,5-Trimethylbenzene ug/L 22.720 113 60-140 1,3-Dichlorobenzene ug/L 22.120 110 60-140 1,3-Dichloropropane ug/L 22.320 112 60-140 1,4-Dichlorobenzene ug/L 21.120 105 60-140 2,2-Dichloropropane ug/L 23.320 116 60-140 2-Chlorotoluene ug/L 21.620 108 60-140 4-Chlorotoluene ug/L 22.520 112 60-140 Benzene ug/L 20.120 101 60-140 Bromobenzene ug/L 21.320 107 60-140 Bromochloromethane ug/L 22.420 112 60-140 Bromodichloromethane ug/L 21.620 108 60-140 Bromoform ug/L 20.720 103 60-140 Bromomethane ug/L 17.320 87 60-140 Carbon tetrachloride ug/L 22.220 111 60-140 Chlorobenzene ug/L 22.220 111 60-140 Chloroethane ug/L 26.120 131 60-140 Chloroform ug/L 22.120 110 60-140 Chloromethane ug/L 25.420 127 60-140 cis-1,2-Dichloroethene ug/L 22.920 115 60-140 cis-1,3-Dichloropropene ug/L 22.420 112 60-140 Dibromochloromethane ug/L 21.620 108 60-140 Dibromomethane ug/L 21.520 108 60-140 Dichlorodifluoromethane ug/L 23.520 117 60-140 Diisopropyl ether ug/L 22.920 114 60-140 Ethanol ug/L 879800 110 60-140 Ethyl-tert-butyl ether ug/L 43.740 109 60-140 Ethylbenzene ug/L 22.020 110 60-140 Hexachloro-1,3-butadiene ug/L 23.020 115 60-140 Isopropylbenzene (Cumene)ug/L 21.420 107 60-140 m&p-Xylene ug/L 43.940 110 60-140 Methyl-tert-butyl ether ug/L 21.620 108 60-140 Methylene Chloride ug/L 22.720 114 60-140 n-Butylbenzene ug/L 23.620 118 60-140 n-Propylbenzene ug/L 21.920 110 60-140 Naphthalene ug/L 24.620 123 60-140 o-Xylene ug/L 21.820 109 60-140 sec-Butylbenzene ug/L 22.920 114 60-140 Styrene ug/L 22.620 113 60-140 tert-Amyl Alcohol ug/L 404400 101 60-140 tert-Amylmethyl ether ug/L 43.540 109 60-140 tert-Butyl Alcohol ug/L 205200 103 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3901052LABORATORY CONTROL SAMPLE: LCSSpike tert-Butyl Formate ug/L 177160 110 60-140 tert-Butylbenzene ug/L 18.320 91 60-140 Tetrachloroethene ug/L 22.020 110 60-140 Toluene ug/L 21.220 106 60-140 trans-1,2-Dichloroethene ug/L 23.820 119 60-140 trans-1,3-Dichloropropene ug/L 22.520 112 60-140 Trichloroethene ug/L 23.320 117 60-140 Trichlorofluoromethane ug/L 20.820 104 60-140 Vinyl chloride ug/L 23.720 118 60-140 Xylene (Total)ug/L 65.760 110 60-140 1,2-Dichloroethane-d4 (S)%105 70-130 4-Bromofluorobenzene (S)%99 70-130 Toluene-d8 (S)%98 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 3901053MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92647170003 3901054 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 128 60-140121 6 3020ND25.7 24.1 1,1,1-Trichloroethane ug/L M12015060-140142 5 3020ND30.0 28.4 1,1,2,2-Tetrachloroethane ug/L 20 129 60-140124 3 3020ND25.8 24.9 1,1,2-Trichloroethane ug/L 20 133 60-140127 5 3020ND26.6 25.4 1,1-Dichloroethane ug/L M12014860-140141 5 3020ND29.5 28.1 1,1-Dichloroethene ug/L M12016160-140153 6 3020ND32.3 30.6 1,1-Dichloropropene ug/L M12016360-140154 5 3020ND32.6 30.9 1,2,3-Trichlorobenzene ug/L 20 129 60-140139 8 3020ND25.8 27.9 1,2,3-Trichloropropane ug/L 20 130 60-140126 3 3020ND26.0 25.2 1,2,4-Trichlorobenzene ug/L 20 132 60-140131 1 3020ND26.3 26.2 1,2,4-Trimethylbenzene ug/L 20 139 60-140138 1 3020ND27.8 27.6 1,2-Dibromo-3- chloropropane ug/L 20 113 60-140116 2 3020ND22.7 23.1 1,2-Dibromoethane (EDB)ug/L 20 136 60-140132 3 3020ND27.2 26.3 1,2-Dichlorobenzene ug/L 20 133 60-140133 1 3020ND26.7 26.5 1,2-Dichloroethane ug/L M12014660-140138 6 3020ND29.2 27.6 1,2-Dichloropropane ug/L M12014560-140135 7 3020ND29.0 27.1 1,3,5-Trimethylbenzene ug/L 20 138 60-140137 1 3020ND27.6 27.4 1,3-Dichlorobenzene ug/L 20 133 60-140133 0 3020ND26.7 26.6 1,3-Dichloropropane ug/L 20 137 60-140130 5 3020ND27.5 26.1 1,4-Dichlorobenzene ug/L 20 126 60-140124 1 3020ND25.2 24.9 2,2-Dichloropropane ug/L M12015260-140142 6 3020ND30.4 28.5 2-Chlorotoluene ug/L 20 135 60-140134 1 3020ND27.0 26.8 4-Chlorotoluene ug/L 20 135 60-140137 1 3020ND27.1 27.4 Benzene ug/L 20 126 60-140119 6 3020ND25.2 23.8 Bromobenzene ug/L 20 128 60-140128 0 3020ND25.6 25.6 Bromochloromethane ug/L 20 140 60-140134 5 3020ND28.0 26.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3901053MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92647170003 3901054 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Bromodichloromethane ug/L 20 126 60-140120 5 3020ND25.3 24.0 Bromoform ug/L 20 111 60-140106 4 3020ND22.2 21.2 Bromomethane ug/L 20 112 60-140104 8 3020ND22.5 20.8 Carbon tetrachloride ug/L 20 133 60-140123 8 3020ND26.6 24.5 Chlorobenzene ug/L 20 136 60-140129 5 3020ND27.1 25.9 Chloroethane ug/L M12016560-140156 5 3020ND32.9 31.2 Chloroform ug/L M12014560-140136 7 3020ND29.3 27.4 Chloromethane ug/L 20 138 60-140133 4 3020ND27.6 26.6 cis-1,2-Dichloroethene ug/L M12014760-140142 4 3020ND29.5 28.3 cis-1,3-Dichloropropene ug/L 20 131 60-140123 6 3020ND26.3 24.7 Dibromochloromethane ug/L 20 120 60-140116 4 3020ND24.1 23.2 Dibromomethane ug/L 20 128 60-140121 6 3020ND25.7 24.2 Dichlorodifluoromethane ug/L 20 114 60-140107 6 3020ND22.7 21.4 Diisopropyl ether ug/L M12014860-140144 3 3020ND29.7 28.8 Ethanol ug/L M180014460-140136 5 30800ND11501090 Ethyl-tert-butyl ether ug/L M14014260-140138 3 3040ND57.0 55.2 Ethylbenzene ug/L 20 138 60-140132 4 3020ND27.7 26.5 Hexachloro-1,3-butadiene ug/L 20 131 60-140131 0 3020ND26.3 26.2 Isopropylbenzene (Cumene)ug/L 20 138 60-140133 4 3020ND27.6 26.5 m&p-Xylene ug/L M14014160-140135 4 3040ND56.2 54.0 Methyl-tert-butyl ether ug/L 20 140 60-140135 4 3020ND28.0 26.9 Methylene Chloride ug/L M12014260-140136 5 3020ND28.5 27.1 n-Butylbenzene ug/L M12014660-140145 1 3020ND29.2 29.0 n-Propylbenzene ug/L 20 138 60-140135 2 3020ND27.5 27.0 Naphthalene ug/L 20 136 60-140140 3 3020ND27.2 28.1 o-Xylene ug/L 20 139 60-140133 4 3020ND27.8 26.7 sec-Butylbenzene ug/L 20 140 60-140139 1 3020ND28.1 27.7 Styrene ug/L M12014260-140135 5 3020ND28.4 27.0 tert-Amyl Alcohol ug/L 400 129 60-140125 4 30400ND517498 tert-Amylmethyl ether ug/L 40 137 60-140131 4 3040ND54.7 52.5 tert-Butyl Alcohol ug/L M120018160-140187 3 30200ND362375 tert-Butyl Formate ug/L M1,R11605160-14037 33 30160ND81.2 58.5 tert-Butylbenzene ug/L 20 112 60-140112 0 3020ND22.4 22.4 Tetrachloroethene ug/L 20 134 60-140128 4 3020ND26.7 25.7 Toluene ug/L 20 132 60-140126 5 3020ND26.5 25.2 trans-1,2-Dichloroethene ug/L M12015760-140150 5 3020ND31.4 29.9 trans-1,3-Dichloropropene ug/L 20 131 60-140124 6 3020ND26.2 24.7 Trichloroethene ug/L M12014560-140136 7 3020ND29.0 27.1 Trichlorofluoromethane ug/L 20 129 60-140121 6 3020ND25.9 24.3 Vinyl chloride ug/L 20 134 60-140128 5 3020ND26.9 25.6 Xylene (Total)ug/L MS6014060-140134 4 3060ND84.0 80.7 1,2-Dichloroethane-d4 (S)%108 70-130107 4-Bromofluorobenzene (S)%103 70-130101 Toluene-d8 (S)%99 70-13099 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 751122 SM 6200B SM 6200B 6200B MSV Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92646869005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3903642 Associated Lab Samples:92646869005 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 01/23/23 13:580.31 1,1,1-Trichloroethane ug/L <0.33 0.50 01/23/23 13:580.33 1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 01/23/23 13:580.22 1,1,2-Trichloroethane ug/L <0.32 0.50 01/23/23 13:580.32 1,1-Dichloroethane ug/L <0.37 0.50 01/23/23 13:580.37 1,1-Dichloroethene ug/L <0.35 0.50 01/23/23 13:580.35 1,1-Dichloropropene ug/L <0.43 0.50 01/23/23 13:580.43 1,2,3-Trichlorobenzene ug/L <0.81 2.0 01/23/23 13:580.81 1,2,3-Trichloropropane ug/L <0.26 0.50 01/23/23 13:580.26 1,2,4-Trichlorobenzene ug/L <0.64 2.0 01/23/23 13:580.64 1,2,4-Trimethylbenzene ug/L <0.50 0.50 01/23/23 13:580.50 1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 01/23/23 13:580.34 1,2-Dibromoethane (EDB)ug/L <0.27 0.50 01/23/23 13:580.27 1,2-Dichlorobenzene ug/L <0.34 0.50 01/23/23 13:580.34 1,2-Dichloroethane ug/L <0.32 0.50 01/23/23 13:580.32 1,2-Dichloropropane ug/L <0.36 0.50 01/23/23 13:580.36 1,3,5-Trimethylbenzene ug/L <0.33 0.50 01/23/23 13:580.33 1,3-Dichlorobenzene ug/L <0.34 0.50 01/23/23 13:580.34 1,3-Dichloropropane ug/L <0.28 0.50 01/23/23 13:580.28 1,4-Dichlorobenzene ug/L <0.33 0.50 01/23/23 13:580.33 2,2-Dichloropropane ug/L <0.39 0.50 01/23/23 13:580.39 2-Chlorotoluene ug/L <0.32 0.50 01/23/23 13:580.32 4-Chlorotoluene ug/L <0.32 0.50 01/23/23 13:580.32 Benzene ug/L <0.34 0.50 01/23/23 13:580.34 Bromobenzene ug/L <0.29 0.50 01/23/23 13:580.29 Bromochloromethane ug/L <0.47 0.50 01/23/23 13:580.47 Bromodichloromethane ug/L <0.31 0.50 01/23/23 13:580.31 Bromoform ug/L <0.34 0.50 01/23/23 13:580.34 Bromomethane ug/L <1.7 5.0 01/23/23 13:581.7 Carbon tetrachloride ug/L <0.33 0.50 01/23/23 13:580.33 Chlorobenzene ug/L <0.28 0.50 01/23/23 13:580.28 Chloroethane ug/L <0.65 1.0 01/23/23 13:580.65 Chloroform ug/L <0.43 0.50 01/23/23 13:580.43 Chloromethane ug/L <0.54 1.0 01/23/23 13:580.54 cis-1,2-Dichloroethene ug/L <0.38 0.50 01/23/23 13:580.38 cis-1,3-Dichloropropene ug/L <0.36 0.50 01/23/23 13:580.36 Dibromochloromethane ug/L <0.36 0.50 01/23/23 13:580.36 Dibromomethane ug/L <0.39 0.50 01/23/23 13:580.39 Dichlorodifluoromethane ug/L <0.35 0.50 01/23/23 13:580.35 Diisopropyl ether ug/L <0.31 0.50 01/23/23 13:580.31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3903642 Associated Lab Samples:92646869005 Matrix:Water AnalyzedMDL Ethanol ug/L <72.2 200 01/23/23 13:5872.2 Ethyl-tert-butyl ether ug/L <3.2 10.0 01/23/23 13:583.2 Ethylbenzene ug/L <0.30 0.50 01/23/23 13:580.30 Hexachloro-1,3-butadiene ug/L <1.5 2.0 01/23/23 13:581.5 Isopropylbenzene (Cumene)ug/L <0.33 0.50 01/23/23 13:580.33 m&p-Xylene ug/L <0.71 1.0 01/23/23 13:580.71 Methyl-tert-butyl ether ug/L <0.42 0.50 01/23/23 13:580.42 Methylene Chloride ug/L <2.0 2.0 01/23/23 13:582.0 n-Butylbenzene ug/L <0.49 0.50 01/23/23 13:580.49 n-Propylbenzene ug/L <0.34 0.50 01/23/23 13:580.34 Naphthalene ug/L <0.64 2.0 01/23/23 13:580.64 o-Xylene ug/L <0.34 0.50 01/23/23 13:580.34 sec-Butylbenzene ug/L <0.40 0.50 01/23/23 13:580.40 Styrene ug/L <0.29 0.50 01/23/23 13:580.29 tert-Amyl Alcohol ug/L <36.4 100 01/23/23 13:5836.4 tert-Amylmethyl ether ug/L <9.2 10.0 01/23/23 13:589.2 tert-Butyl Alcohol ug/L <26.8 50.0 01/23/23 13:5826.8 tert-Butyl Formate ug/L <29.4 50.0 01/23/23 13:5829.4 tert-Butylbenzene ug/L <0.32 0.50 01/23/23 13:580.32 Tetrachloroethene ug/L <0.29 0.50 01/23/23 13:580.29 Toluene ug/L <0.24 0.50 01/23/23 13:580.24 trans-1,2-Dichloroethene ug/L <0.40 0.50 01/23/23 13:580.40 trans-1,3-Dichloropropene ug/L <0.36 0.50 01/23/23 13:580.36 Trichloroethene ug/L <0.38 0.50 01/23/23 13:580.38 Trichlorofluoromethane ug/L <0.30 1.0 01/23/23 13:580.30 Vinyl chloride ug/L <0.39 1.0 01/23/23 13:580.39 Xylene (Total)ug/L <0.34 1.0 01/23/23 13:580.34 1,2-Dichloroethane-d4 (S)%107 70-130 01/23/23 13:58 4-Bromofluorobenzene (S)%99 70-130 01/23/23 13:58 Toluene-d8 (S)%102 70-130 01/23/23 13:58 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3903643LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 21.820 109 60-140 1,1,1-Trichloroethane ug/L 23.820 119 60-140 1,1,2,2-Tetrachloroethane ug/L 22.920 114 60-140 1,1,2-Trichloroethane ug/L 23.420 117 60-140 1,1-Dichloroethane ug/L 22.920 115 60-140 1,1-Dichloroethene ug/L 24.320 122 60-140 1,1-Dichloropropene ug/L 25.720 128 60-140 1,2,3-Trichlorobenzene ug/L 25.920 129 60-140 1,2,3-Trichloropropane ug/L 23.420 117 60-140 1,2,4-Trichlorobenzene ug/L 24.220 121 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3903643LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trimethylbenzene ug/L 24.620 123 60-140 1,2-Dibromo-3-chloropropane ug/L 22.520 112 60-140 1,2-Dibromoethane (EDB)ug/L 23.820 119 60-140 1,2-Dichlorobenzene ug/L 23.720 119 60-140 1,2-Dichloroethane ug/L 24.320 121 60-140 1,2-Dichloropropane ug/L 23.920 119 60-140 1,3,5-Trimethylbenzene ug/L 24.520 122 60-140 1,3-Dichlorobenzene ug/L 23.920 120 60-140 1,3-Dichloropropane ug/L 23.420 117 60-140 1,4-Dichlorobenzene ug/L 22.520 113 60-140 2,2-Dichloropropane ug/L 23.420 117 60-140 2-Chlorotoluene ug/L 23.320 117 60-140 4-Chlorotoluene ug/L 24.120 120 60-140 Benzene ug/L 20.420 102 60-140 Bromobenzene ug/L 22.920 115 60-140 Bromochloromethane ug/L 22.920 115 60-140 Bromodichloromethane ug/L 22.320 111 60-140 Bromoform ug/L 20.620 103 60-140 Bromomethane ug/L 19.120 96 60-140 Carbon tetrachloride ug/L 21.420 107 60-140 Chlorobenzene ug/L 22.620 113 60-140 Chloroethane ug/L 24.320 122 60-140 Chloroform ug/L 23.120 116 60-140 Chloromethane ug/L 22.920 115 60-140 cis-1,2-Dichloroethene ug/L 23.320 116 60-140 cis-1,3-Dichloropropene ug/L 23.020 115 60-140 Dibromochloromethane ug/L 21.720 109 60-140 Dibromomethane ug/L 22.420 112 60-140 Dichlorodifluoromethane ug/L 22.420 112 60-140 Diisopropyl ether ug/L 24.120 120 60-140 Ethanol ug/L 975800 122 60-140 Ethyl-tert-butyl ether ug/L 46.840 117 60-140 Ethylbenzene ug/L 22.920 115 60-140 Hexachloro-1,3-butadiene ug/L 24.620 123 60-140 Isopropylbenzene (Cumene)ug/L 23.320 117 60-140 m&p-Xylene ug/L 47.140 118 60-140 Methyl-tert-butyl ether ug/L 23.020 115 60-140 Methylene Chloride ug/L 22.420 112 60-140 n-Butylbenzene ug/L 25.720 129 60-140 n-Propylbenzene ug/L 23.820 119 60-140 Naphthalene ug/L 27.520 138 60-140 o-Xylene ug/L 23.620 118 60-140 sec-Butylbenzene ug/L 24.520 122 60-140 Styrene ug/L 24.120 121 60-140 tert-Amyl Alcohol ug/L 467400 117 60-140 tert-Amylmethyl ether ug/L 47.240 118 60-140 tert-Butyl Alcohol ug/L 246200 123 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3903643LABORATORY CONTROL SAMPLE: LCSSpike tert-Butyl Formate ug/L 181160 113 60-140 tert-Butylbenzene ug/L 19.720 99 60-140 Tetrachloroethene ug/L 22.120 111 60-140 Toluene ug/L 22.220 111 60-140 trans-1,2-Dichloroethene ug/L 24.220 121 60-140 trans-1,3-Dichloropropene ug/L 23.420 117 60-140 Trichloroethene ug/L 23.820 119 60-140 Trichlorofluoromethane ug/L 19.820 99 60-140 Vinyl chloride ug/L 21.320 106 60-140 Xylene (Total)ug/L 70.660 118 60-140 1,2-Dichloroethane-d4 (S)%107 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 3903644MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92647273004 3903645 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 114 60-140125 9 3020ND22.9 25.0 1,1,1-Trichloroethane ug/L M12013660-140147 8 3020ND27.3 29.4 1,1,2,2-Tetrachloroethane ug/L 20 116 60-140129 11 3020ND23.1 25.9 1,1,2-Trichloroethane ug/L 20 122 60-140133 9 3020ND24.4 26.5 1,1-Dichloroethane ug/L M12013560-140145 7 3020ND27.1 29.1 1,1-Dichloroethene ug/L M12014660-140158 8 3020ND29.2 31.5 1,1-Dichloropropene ug/L M12015060-140161 7 3020ND30.1 32.3 1,2,3-Trichlorobenzene ug/L 20 112 60-140128 14 3020ND22.3 25.6 1,2,3-Trichloropropane ug/L 20 117 60-140131 11 3020ND23.4 26.1 1,2,4-Trichlorobenzene ug/L 20 113 60-140128 12 3020ND22.7 25.5 1,2,4-Trimethylbenzene ug/L 20 127 60-140134 6 3020ND25.4 26.9 1,2-Dibromo-3- chloropropane ug/L 20 101 60-140112 10 3020ND20.3 22.3 1,2-Dibromoethane (EDB)ug/L 20 122 60-140135 10 3020ND24.4 27.1 1,2-Dichlorobenzene ug/L 20 120 60-140129 7 3020ND24.1 25.8 1,2-Dichloroethane ug/L M12013760-140144 5 3020ND27.4 28.9 1,2-Dichloropropane ug/L M12013060-140142 9 3020ND26.0 28.3 1,3,5-Trimethylbenzene ug/L 20 127 60-140134 5 3020ND25.4 26.8 1,3-Dichlorobenzene ug/L 20 122 60-140129 6 3020ND24.4 25.8 1,3-Dichloropropane ug/L 20 123 60-140134 8 3020ND24.7 26.8 1,4-Dichlorobenzene ug/L 20 115 60-140122 6 3020ND23.0 24.4 2,2-Dichloropropane ug/L M12013860-140149 8 3020ND27.6 29.9 2-Chlorotoluene ug/L 20 124 60-140132 6 3020ND24.9 26.3 4-Chlorotoluene ug/L 20 126 60-140133 5 3020ND25.3 26.6 Benzene ug/L 20 114 60-140124 8 3020ND22.8 24.7 Bromobenzene ug/L 20 119 60-140126 6 3020ND23.8 25.2 Bromochloromethane ug/L M12013260-140141 7 3020ND26.3 28.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3903644MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92647273004 3903645 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Bromodichloromethane ug/L 20 115 60-140126 9 3020ND23.0 25.1 Bromoform ug/L 20 101 60-140109 8 3020ND20.1 21.8 Bromomethane ug/L 20 98 60-140110 12 3020ND19.6 22.1 Carbon tetrachloride ug/L 20 117 60-140126 8 3020ND23.3 25.2 Chlorobenzene ug/L 20 122 60-140132 8 3020ND24.4 26.4 Chloroethane ug/L M12015160-140162 7 3020ND30.1 32.4 Chloroform ug/L 20 131 60-140139 6 3020ND26.2 27.9 Chloromethane ug/L 20 121 60-140135 11 3020ND24.2 27.0 cis-1,2-Dichloroethene ug/L M12013760-140145 6 3020ND27.5 29.0 cis-1,3-Dichloropropene ug/L 20 119 60-140130 8 3020ND23.8 25.9 Dibromochloromethane ug/L 20 110 60-140120 9 3020ND22.0 24.0 Dibromomethane ug/L 20 116 60-140128 10 3020ND23.2 25.6 Dichlorodifluoromethane ug/L 20 106 60-140112 5 3020ND21.1 22.3 Diisopropyl ether ug/L M12013460-140147 9 3020ND26.8 29.3 Ethanol ug/L M180013060-140151 14 30800ND10401210 Ethyl-tert-butyl ether ug/L M14013060-140142 8 3040ND52.1 56.7 Ethylbenzene ug/L 20 122 60-140136 10 3020ND24.4 27.1 Hexachloro-1,3-butadiene ug/L 20 112 60-140125 11 3020ND22.4 25.0 Isopropylbenzene (Cumene)ug/L 20 123 60-140134 9 3020ND24.5 26.7 m&p-Xylene ug/L 40 125 60-140135 7 3040ND50.2 54.1 Methyl-tert-butyl ether ug/L 20 129 60-140140 8 3020ND25.8 28.0 Methylene Chloride ug/L M12013460-140141 5 3020ND26.7 28.2 n-Butylbenzene ug/L M12013060-140142 9 3020ND26.0 28.4 n-Propylbenzene ug/L 20 126 60-140134 6 3020ND25.3 26.8 Naphthalene ug/L 20 115 60-140134 15 3020ND23.0 26.8 o-Xylene ug/L 20 125 60-140134 8 3020ND24.9 26.9 sec-Butylbenzene ug/L 20 127 60-140136 7 3020ND25.5 27.2 Styrene ug/L 20 127 60-140139 9 3020ND25.4 27.7 tert-Amyl Alcohol ug/L 400 117 60-140130 10 30400ND467518 tert-Amylmethyl ether ug/L 40 123 60-140135 9 3040ND49.3 54.0 tert-Butyl Alcohol ug/L M120014060-140175 22 30200ND281350 tert-Butyl Formate ug/L 160 81 60-14062 26 30160ND129100 tert-Butylbenzene ug/L 20 103 60-140109 6 3020ND20.6 21.8 Tetrachloroethene ug/L 20 120 60-140129 7 3020ND24.1 25.8 Toluene ug/L 20 118 60-140128 8 3020ND23.7 25.6 trans-1,2-Dichloroethene ug/L M12014260-140153 8 3020ND28.5 30.7 trans-1,3-Dichloropropene ug/L 20 118 60-140130 10 3020ND23.7 26.1 Trichloroethene ug/L 20 130 60-140140 7 3020ND26.0 28.0 Trichlorofluoromethane ug/L 20 119 60-140128 7 3020ND23.9 25.5 Vinyl chloride ug/L 20 118 60-140132 11 3020ND23.6 26.4 Xylene (Total)ug/L 60 125 60-140135 7 3060ND75.1 81.0 1,2-Dichloroethane-d4 (S)%112 70-130110 4-Bromofluorobenzene (S)%100 70-130101 Toluene-d8 (S)%98 70-13098 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 36 raceAnalytical www.pacelabs.com QUALIFIERS Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result.MS The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be achieved in sample matrix spikes.P5 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 36 raceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92646869 SLC4491902 CROSSROADS CENTER-C Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92646869001 750552MW-1 SM 6200B 92646869002 750552MW-3 SM 6200B 92646869003 750552MW-10 SM 6200B 92646869004 750552MW-12 SM 6200B 92646869005 751122MW-13 SM 6200B 92646869006 749777FB-1 SM 6200B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/23/2023 04:53 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 36 raceAnalytical www.pacelabs.com Page 34 of 36 UU#_Title:ENV-FRM-HUN1-0083 v01_Sample Condition Upon Receipt Effective Date:05/12/202205/12/2022 Laboratory receiving samples: Asheville Q EdenQ Greenwood Q Huntersville Client Name: |l/Ai>noyct/illp||Raleigh^MerUO#:92646869SampleCondition Upon Receipt A )c (kroner /.c piMO -[jiarl,kAFedExIDUPSQuSPS0Client Project #:HimimilCourier:I ICommercial Other:Pace Custody Seal Present?DYes 3]No Seals Intact?I |Yes AfhCWP.FDate/InitialsPersonExaminingContents:, [Bubble Wrap Bubble Bags ONone OtherPackingMaterial:Biological Tissue Frozen? Yes DNO 0N/A/Thermometer:Ed ii 0Wet DBlueIRGunID: NoneTypeofIce:Correction Factor: Add/Subtract (°C)Cooler Temp:Temp should be above freezing to 6°C Samples out of temp criteria.Samples on ice,coolingprocesshasbegun9.s7 /Cooler Temp Corrected (°C); USDA Regulated Soil (Q]N/A,water sample)Did samples originatein a quarantine zone withinthe United States:CA,NY,or SCcheckmaps)?OYes ONo Did samplesoriginate froma foreignsource (internationally,including Hawaii and Puerto Rico)?OYes QNO Comments/Discrepancy: Yes DNQ DN/AChainofCustodyPresent?1. [g(Yes DNQ DN/ASamplesArrivedwithinHoldTime?2. Yes ETNO.DN/AShortHoldTimeAnalysis(<72 hr.)?3. Yes BNo N/ARushTurnAroundTimeRequested?4. Yes DNQ DN/ASufficientVolume?5. QY NO ON/A Yes ONo QN/A Correct Containers Used?-PaceContainers Used?6.Yes Yes DNO DN/AContainersIntact?7. Yes PNo QN/ADissolvedanalysis:Samples Field Filtered?8.EjVes ONo DN/ASampleLabelsMatchCOC?9. -Includes Date/Time/ID/Analysis Matrix: H]NO N/AYesHeadspaceinVOAVials(>5-6mm)?10. Yes DNO QN/ATripBlankPresent?11. N/AYesPNoTripBlankCustodySealsPresent? Field Data Required?OYes ONoCOMMENTS/SAMPLE DISCREPANCY Lot ID of split containers:CLIENT NOTIFICATION/RESOLUTION Date/Time:Person contacted: M T.3\Project Manager SCURF Review:Date: Project Manager SRF Review:Date: Qualtrax ID:69614 Page 1 of 2 Page 35 of 36 UU#_Title:ENV-FRM-HUN1-0083 v01_Sample Condition Upon Receipt I i\:«'"MI Effective Date:05/12/202205/12/2022 ®;92646869 Due Date: *Check mark top half of box if pH and/or dechlorination is verified andwithintheacceptancerangeforpreservationsamples.Exceptions:VOA,Coliform,TOC,Oiland Grease,DRO/8015(water)DOC,LLHg **Bottom half of box is to list number of bottles ***Check aj]unpreserved Nitrates for chlorine Project fl CLIENT::01/23/2392-flTC L *ocn u0»<D A 2 D 2<—L a>I<<<<u <<o<u «7»in QJ 2 JQ X>2 ro i<2 2 2 TO2roa.ro 1222UININ2fN > IN <C X)-O rH cnINVao2J1I X)XJ 23Va>QJ X3XJ<V Sc QJ QJ AQJ VXJ 2<X <<QJ QJQJ2X£2 INQJX <XJX £X a <O2roQJ QJ a.2 QJa.v ro 2 in QJ ro 2 QJ QJ Ol CL Viin in QJ QJinmmminQJ QJ .{22INQJXuQJ m m 2QJQJQJmroO<in yX u QJQJQJCJ<2 CL >O CL IN CL QJ O Xo 3oin<a CL O toCL tnc CL t/J KD X X ca.2 a.cQJin2INrJCccOCLtoUroINororo B23 c>3c22toX333XINC2XJaa.x 33NINXtoUa.a.i_xQJ3 C 2ro.y IN y y u roroB0JuQJ y y QJ-C QJ 3 QJXX*3 z XX)i3 u X)QJ 3 QJ XJQJX)tn tn QJ ‘X n •c cXm m3E X) x><EXJ<<EE <XJ <ro2IS12 cro /2 in J2 QJO QJ EEEOooQJ<E oo < ro <G CL CL <CL CL CL E CL CL CL a>>CO CO <><<>CO a.<_ JEOJ inE EEEEEEEEEEroEEEEQJQlE EE QJ X)EEQJO.tr .tf oaoo.ti oto AS oLO o>CO m £i in oooin§ .i o oo IN in o cn oLOofNinININ infNcn«—i rorHIN77 <—i CN IN rH rH IN INinHIN 7rH IN rH rH IN33ii32to I>3 >X X 3 3 3J—i 3 2 *T H333in *CD CZ in CL h-E rH cn cn cn cnrHrorocncn a cn ro fN rH ro sT rocoIN(J L9 L9 L3ID(D e> QJ CL L9 CL CL CL CL CL CL CL aCLCL CO$a o o o<<<«<>CD CO CD CD CD CD >CO m <>oCDinto1r 2 V 3 H\f4 \5 t *t6 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Oate preservation adjustedSampleIDTypeofPreservative Time preservation adjusted pH upon receipt Amountof Preservative added Lot tf Note:Whenever there is a discrepancy a feeling NorthCarolina compliance samples,a copy of this form willbe sent tothe North Carolina DENR CertificationOffice (i.e.Out of hold,incorrect preservative,out of temp,incorrect containers. Qualtrax ID:69614 Page 2 of 2 Page 36 of 36rface CHAIN-OF-CUSTODY /Analytical Request DocumentTheChain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately.Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at https://info.pacelabs.com/hubfs/pas-standard-terms.pdf.SectionC*ItionAluiredClientInformation:SectionBRequiredProject Information:Invoice Information:Page :Of1 1ReportTo:AI Quarles Attention:ipany:ATCGroupServices.LLC-Charlotte Copy To:Company Name:ress:7606WhitehallExec.CenterDr Address:e800.Charlotte.NC28273 Regulatory Agency lil:=>aceQuote:S+OiH.L#Cl ($Purchase Order #:al.quaries@atcgscom |Fax:Project Name.3aceProjectManager:ne:(704)529-3200 SLC4491902 Crossroads Center-C taylor,cannon@pacelabs com.State /Location uestedDueDate:Project #:PaceProfile #:3848-3 NC RequestedAnalysisFiltered (Y/N) 2a.r-Preservatives >-COLLECTED2O IT3uMATRIXDrinkingWatorDWWaterWasteWaterWWProductSoiVSoiid CODE 2noO8WToED«LUI<Zcep>>o </)SAMPLE ID oSLO)w10 IIO ooSIARTEND—Oil OL (/>atH-cc .£Wipe WP <OneCharacterperbox.(A-Z,0-9/,-) SampleIdsmustbe unique UJ tfi oARAirCLUJLUZQ)2 zQQ.<OtherTissue OT (/)O >111 O8C\| TS >1(O4:(J oz0)O COUJOra*c*T>m CM 3IDCLuo';2 raOXDC c !SCOo£u oo<u.C/5§CO —8 m£o z<o a Oc3 0)DATE--TtME DATE-44ME-s D OXXXzz >trT7TSI$/23vAu-'-flo (\o 40iWJ 40II 0012i'\o 12 oo 0o23 t 5 ooMv*-\1 Oo^4 I ocf>I 3 \05yr6'i X 00£M sKI3 y5I 7 8 3 0 1 2 ADDITIONALCOMMENTS RELINQUISHED BY /AFFILIATION DATE TIME ACCEPTED BY/AFFILIATION DATE TIME SAMPLE CONDITIONS iWfa /ATC l.Wi v v-11-78 8^fSr*'/V-r s aSAMPLERNAMEANDSIGNATURErac cQJOOPRINTNameofSAMPLER:C/5O in>.Eoj^ 0)>0.CL _ S§|05 C.i/l5/2 3 o z<U ^ab2 oocSIGNATUREofSAMPLER:DATE Signed:LU-