WS-4653_15063_CA_MRP_20210601

Groundwater Monitoring Report

Williams Grocery

2425 US Highway 21
Hamptonville, Yadkin County, North Carolina
NCDEQ Incident #15063
ATC Project #SLC1506301

June 1, 2021

Groundwater Monitoring Report June 1, 2021
Williams Grocery, Hamptonville, Yadkin Co, NC, NCDEQ Incident #15063 ATC Project #SLC1506301

TABLE OF CONTENTS

1.0 SITE IDENTIFICATION ............................................................................... 1
2.0 EXECUTIVE SUMMARY ............................................................................. 2
3.0 SITE DESCRIPTION .................................................................................. 3
3.1 Site Characterization .................................................................... 3
3.2 Site Background ........................................................................... 3
3.3 Site and Regional Geology .......................................................... 5
3.4 Site and Regional Hydrogeology .................................................. 5
4.0 MOBILE MULTIPHASE EXTRACTION EVENT ......................................... 6
4.1 MMPE Event March 15 – 17, 2021 .............................................. 6
5.0 GROUNDWATER CHARACTERIZATION .................................................. 7
5.1 Water Supply Wells ...................................................................... 7
5.2 Groundwater Levels ..................................................................... 8
5.3 Groundwater Quality .................................................................... 8
6.0 CONCLUSIONS AND RECOMMENDATIONS ........................................... 9
TABLES
Table 1 Groundwater Elevation Data
Table 2 Water Supply Well Information
Table 3 Recent Water Supply Well Analytical Results
Table 4 Historical Water Supply Well Analytical Results
Table 5 Monitoring Well Construction Details
Table 6 Field Parameters
Table 7 Recent Groundwater Analytical Results
Table 8 Historical Groundwater Analytical Results

FIGURES
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Water Supply Well Location Map
Figure 4 Groundwater Elevation Contour Map
Figure 5 Contaminants of Concern

APPENDICES

Appendix A MMPE Subcontractor Report and Waste Disposal Manifest
Appendix B Field Notes
Appendix C Laboratory Report and Chain-of-Custody Documentation
Appendix D Health Risk Evaluation (WSW-6)

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2.0 EXECUTIVE SUMMARY
ATC Associates of North Carolina, P.C. (ATC) submits this Groundwater Monitoring Report
documenting a 96-hour MMPE event and associated monitoring well and water supply well
sampling in March and April 2021. The activities are associated with the Williams Grocery site,
located at 2425 US Highway 21, Hamptonville, Yadkin County, North Carolina. The work was
performed based on the February 25, 2021, Task Authorization (TA-01) by the Trust Fund
Branch of the Underground Storage Tank (UST) Section, Division of Waste Management, North
Carolina Department of Environmental Quality (NCDEQ). The work is being performed as part
of the State Lead Contract #N122019A between NCDEQ and ATC.

A release was discovered in February 1994, from the UST system during removal of a 2,000-
gallon gasoline UST and a 500-gallon kerosene UST. Three 550-gallon gasoline USTs were
filled in-place with concrete, and were later removed.

The approved scope of services included conducting a combined Mobile Multi-Phase Extraction
(MMPE) / Air Sparging (AS) event and the sampling of monitoring/remediation wells MW-1,
MW-3, MW-5, MW-12, RW-1, and AS-1, and water supply wells WSW-1, WSW-2, WSW-3,
WSW-4, WSW-5, WSW-6, and WSW-7, and the measurement of water levels in wells MW-2,
MW-4, and MW-6. All monitoring/remediation wells and water supply wells WSW-1, WSW-2,
WSW-6, and WSW-7 were sampled; however, water supply wells WSW-3, WSW-4, and WSW-
5 were not sampled due to absent owners.

The following summarizes the site conditions based on the recent and historical assessment
activities:

 There are no surface water bodies within 500 feet of the source area.
 Eleven active drinking water supply wells are located within 1,000 feet of the source
area, with one well (WSW-1) located within 250 feet of the source area. Municipal water
is not available to the site and surrounding area. Based on the groundwater flow
direction, ATC considers water supply wells WSW-1 and WSW-3 to be the most “at risk”
wells.
 During March 15 to 19, 2021, a 96-hour combined Mobile Multi-Phase Extraction
(MMPE) / Air Sparging (AS) event was conducted using MW-1, MW-3, and RW-1 as
extraction wells and well AS-1 as an AS well. Light non-aqueous phase liquid (LNAPL)
was not detected in the target wells prior to, immediately after or 20 minutes after the
MMPE event, although the initial water levels in wells MW-1 and MW-3 were above the
top of well screens. Approximately 9,580 gallons of total fluid and 288 pounds of volatile
organic compounds (VOCs) as vapor were removed during the MMPE event.
 Approximately 9,865 pounds of petroleum as vapor have been recovered over time at
this site.
 Water supply wells WSW-1, WSW-2, WSW-6, and WSW-7 were sampled on April 2,
2021. Water supply well WSW-6 contained VOCs at concentrations less than the 15A
NCAC 2L .0202 groundwater quality standards (2L Standards). No VOCs were detected
in WSW-1, WSW-2, or WSW-7.
 Health Risk Evaluation conducted by the NCDEQ for water supply well WSW-6 indicated
no restrictions of the use of the water at this time.
 Groundwater samples were obtained prior to the MMPE (March 15, 2021), during the
MMPE (March 17, 2021), and 2 weeks after the MMPE event (April 2, 2021).
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 LNAPL was detected in RW-1 at a thickness of 0.03 feet during the April 2, 2021 sampling
subsequent to the MMPE event. The concentrations of VOCs in monitoring wells MW-1
and MW-3 suggest residual LNAPL is present.
 Gross Contamination Levels (GCLs) were exceeded in wells MW-1, MW-3, and RW-1.
 Additional VOCs were detected in monitoring wells MW-1, MW-2, MW-3, MW-5, and AS-1
at concentrations exceeding the 2L Standards.
 No VOCs were detected in well MW-12.
 The depth to groundwater in the shallow wells ranged from 15.80 feet below top of casing
(ft-toc) in MW-6 to 19.38 in well RW-1. Groundwater flow is generally to the east-southeast,
with mounding at well MW-2.
 Due to seasonal rainfall well screens were submerged during this sampling event.

Based on recent and historical monitoring well sampling results, the horizontal extent of the
VOC plume is defined with the exception of the upgradient direction to the north and northwest.
The greatest concentrations of VOCs were detected in monitoring wells MW-1, MW-3, and RW-
1, with exceedances of the GCLs, and the concentrations appear to be relatively stable, with
several VOCs increasing in concentrations following the MMPE/AS event. The April 2, 2021
groundwater sampling results indicate that the combined MMPE/AS event was not effective in
reducing VOC concentrations; however, the event was successful in removing VOCs from the
subsurface.

ATC recommends a sampling event to include MW-1, MW-3, MW-5 and RW-1 in approximately
six months to evaluate the possible long term effectiveness of the MMPE/AS event, followed by
an evaluation of possible alternative remediation efforts.

3.0 SITE DESCRIPTION
3.1 Site Characterization
The NCDEQ retained ATC to provide environmental consulting services for Williams Grocery,
located at 2425 US Highway 21, Hamptonville, Yadkin County, North Carolina. Figure 1 depicts
the site location on a topographic map. The former Williams Grocery building was demolished
several years ago, and the residence located southeast of the former UST system was
demolished in early 2017. There are two apartments located on the property, to the southwest
of the former Williams Grocery building.

3.2 Site Background
The site formerly utilized a UST system consisting of one (1) 2,000-gallon gasoline UST, three
(3) 550-gallon gasoline USTs, and one (1) 550-gallon kerosene UST. The 2,000-gallon gasoline
UST and the 550-gallon kerosene UST were removed in February, 1994. The three 550-gallon
gasoline USTs were initially closed in place due to stability of nearby foundations. Closure
sampling was performed during tank closure activities. Total petroleum hydrocarbon (TPH)
concentrations ranged from 42 parts per million (ppm) to 22,115 ppm as gasoline range
organics (GRO) and from 2,982 ppm to 14,284 ppm as diesel range organics (DRO).

Groundwater monitoring wells MW-1 through MW-3 were installed and sampled in November,
1996. The locations of the monitoring wells are depicted on Figure 2. LNAPL was detected in
monitoring wells MW-1 and MW-3 during initial sampling. VOCs were detected in monitoring
well MW-2 at concentrations that exceeded the 2L Standards.

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The three USTs that were filled with concrete were removed in February 1997. During
excavation activities, 144 tons of petroleum impacted soils were removed. Vertical and
horizontal extent sampling detected concentrations ranging from 2,500 ppm to 13,000 ppm TPH
GRO.

Monitoring wells MW-4 through MW-11 were installed and sampled in April 1998. Initial
sampling indicated concentrations above the 2L Standards in monitoring wells MW-4, MW-5,
MW-8, and MW-9.

Monitoring well RW-1 was installed in June 2014 in the source area. Initial sampling of well RW-
1 showed concentrations of benzene, MTBE, and ethylene dibromide (EDB) above the 2L
Standards and GCLs. Eleven additional compounds were detected above the 2L Standards in
the well.

A Groundwater Monitoring Report completed by TerraQuest in June 2012, identified eleven
potable water supply wells within 1,000 feet of the site. According to prior reports, a Point-of-
Entry (POE) filtration system was installed on water supply well WSW-1.

Subsequent groundwater monitoring events have been performed at the site. Monitoring wells
MW-7 through MW-11 could not be located for multiple sampling events. The groundwater
monitoring event, performed in 2015, detected LNAPL in monitoring wells MW-3 and RW-1.
Concentrations of benzene, MTBE, and EDB were detected above the GCLs in monitoring well
MW-1. VOC concentrations exceeded the 2L Standards in monitoring well MW-2.

According to a Groundwater Monitoring Report completed by S&ME, approximately 18
aggressive fluid vapor recovery (AFVR) events were completed at the site from June 1997,
through November 1998. According to prior reports provided to ATC, approximately four MMPE
events were performed at the site from July 2001 through August 2004. An MMPE event was
also completed at the site as part of S&ME’s 2016 field activities from June 24, 2016, to June
24, 2016. According to data from the Groundwater Monitoring Report, the five MMPE events
generated 2,068 gallons of hydrocarbons as LNAPL and as vapors.

ATC conducted groundwater monitoring in November, 2017. VOC concentrations exceeded the
GCLs in wells MW-1 and MW-3. VOCs also exceed the 2L Standards in wells MW-1, MW-2,
MW-3, and RW-1.

From May 6, 2019 to May 10, 2019, a 96-hour MMPE was performed at the site using
monitoring wells MW-1, MW-3, and recovery well RW-1 as extraction wells, while sparging in
well AS-1. Prior to the MMPE event, groundwater samples were collected from wells MW-1,
MW-3, and recovery well RW-1 to serve as comparison for post-MMPE sampling. Based on the
calculations from the MMPE event, it appears that the MMPE was somewhat effective in mass
removal of petroleum hydrocarbons (approximately 270 pounds of VOCs removed). However, only
slight reductions in VOC concentrations were realized and VOC concentrations in the monitoring
well network continue to exceed GCLs. ATC recommended additional MMPE events with air
sparging to continue to remove mass from the monitoring well network.

ATC installed one Type II groundwater monitoring well, MW-12, to the southeast of MW-1 to
evaluate the horizontal extent of petroleum impact, on February 12, 2020. On February 12,
2020, ATC collected samples from water supply wells WSW-1, WSW-2, WSW-5, WSW-7, and
WSW-9. Water supply well WSW-7 contained toluene (9.3 µg/L) at a concentrations below the
2L Standard of 600 µg/L. No other compounds were detected in WSW-7. Based on the WSW-7
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results, the NCDEQ issued a Health Risk Evaluation stating “no restrictions on the use of this
water are recommended at this time.”

Groundwater samples were collected on February 13, 2020, from wells MW-1, MW-2, MW-3, MW-
4, MW-5 MW-6, MW-12 and recovery well RW-1. Monitoring well MW-1 multiple VOCs (benzene,
MTBE, EDB, 1,2-DCA, TAA, and TBA) above the GCLs. Monitoring well MW-3 contained benzene
and EDB above the GCLs. Additional VOCs were detected in monitoring wells MW-1, MW-2, MW-
3, and MW-5, and recovery well RW-1 at concentrations exceeding the 2L Standards. ATC
recommended performing a 96-hour combined MMPE/AS event using MW-1, MW-3 and RW-1 as
extraction wells with air-sparging using well AS-1.

3.3 Site and Regional Geology
According to the Geologic Map of North Carolina, produced by the State of North Carolina in
1985, the site lies in the Brushy Mountains of the Inner Piedmont Physiographic Province. The
rock type at the site has been identified as gneiss. The shallow subsurface in most areas of the
Piedmont contains residual soil overburden, including structure-free residuum, saprolite, and
partially weathered rock (PWR) that derive from in-place weathering of the crystalline bedrock.
In areas near creeks and rivers, alluvium derived from weathered residual soil is often present
and such material may be present near drainages at the property. Saprolite and PWR typically
contain some relict structures from the original rock material. Depth to rock ranges from ground
surface at occasional outcrops to depths greater than 100 feet in areas of easily weathered
rock.

3.4 Site and Regional Hydrogeology
The shallow aquifer occurrence varies in depth from ground surface at springs, creeks, and
rivers to as deep as 50 feet or more beneath upland surfaces in some parts of the Piedmont.
Water in the alluvium or unconsolidated residual material, including saprolite and PWR, usually
behaves as an unconfined, or water table, aquifer and will yield water with head elevation
equivalent to the first elevation where water was encountered. Permeability varies with lithology
and is typically relatively low in residual soils, with higher permeability in saprolite or PWR due
to relict rock texture and variable susceptibility to weathering exhibited by different minerals in
the rock. Groundwater flow in residual soils or alluvium is usually in rough concurrence with
local topographic conditions and is toward local drainage features.

The bedrock fractures or other planar features generally constitute the bedrock aquifer, with the
surrounding rock material being effectively impermeable. Along with fractures, contacts between
rock bodies probably constitute zones of significant groundwater occurrence in the bedrock. The
surrounding material and overlying residuum tend to make the bedrock aquifer a semi-confined
aquifer. That is, the overlying water and soil weight normally results in pressure that causes
water in a borehole which intersects a fracture or other feature to rise above the elevation of the
fracture or feature. Such features may not occur on predicable trends, at the same elevations,
or even be present or directly connected in separate boreholes. In areas adjacent to creeks the
bedrock groundwater generally discharges to the residuum or alluvium and then into the surface
water. In upland areas away from surface water drainages, the bedrock aquifer is generally
recharged by downward infiltration of residuum or alluvial aquifer water at locations where
fractures intersect the bedrock surface.

For sites in the Piedmont, the direction of groundwater flow in the shallow regolith aquifer is
generally from topographic higher elevations (recharge areas) toward topographic lower
elevations and non-perched surface water bodies (discharge areas). On April 2, 2021, the depth
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to groundwater in the shallow wells ranged from 15.80 feet below top of casing (ft-toc) in MW-6
to 19.38 in well RW-1. Groundwater flow is generally to the east-southeast, with mounding at
well MW-2.

4.0 MOBILE MULTIPHASE EXTRACTION EVENT
4.1 MMPE Event March 15 – 17, 2021
From March 15 to 19, 2021, Advanced Environmental Services, Inc. (Advanced) performed a
96-hour MMPE event. The event was completed using MW-1, MW-3 and RW-1 as extraction
wells, while sparging in AS-1 (pulsed 12 hours on and 12 hours off beginning on March 16).
ATC personnel provided onsite supervision for event set-up and break-down. Target extraction
wells were gauged for liquid levels prior to starting the MMPE event with an electronic oil-water
interface probe. No LNAPL was measured in the target wells prior to, immediately after or 20
minutes after the MMPE event. The depth to water and LNAPL are presented in Table 1.

During MMPE activities, a liquid ring vacuum pump unit is plumbed to the designated extraction
points, and a drop pipe is extended into the well through an airtight seal at the TOC and into the
water column. Throughout the MMPE process, a cone of depression forms around the
designated recovery points by drawing down the groundwater surface levels, thus causing
impacted water surrounding the recovery point to be extracted. Petroleum-impacted soil vapor
within the cone of depression and the overlying vadose zone is removed as part of the MMPE
extraction process.

The 96-hour MMPE event was initiated on March 15, 2021, and ended on March 19, 2021. The
effluent air stream was monitored for temperature, velocity, relative humidity, and organic vapor
concentrations on a daily basis. Calculated effluent airflow rates and the vapor concentration
readings from the vacuum truck indicated that approximately 288 pounds (47 equivalent
gallons) of petroleum hydrocarbons were recovered as vapor during the MMPE event. The
MMPE event removed approximately 9,580 gallons of total fluids.

A report provided by Advanced which includes monitoring data, emissions and recovery
calculations, and waste disposal manifests, is provided in Appendix A. ATC field notes from the
MMPE set-up and break-down supervision are presented in Appendix B.

The following summarizes the emissions reported in pounds from the previous 8-hour AFVR
and 96-hour MMPE events.

Event Date(s) Type VOC Emissions
pounds pounds/hr
6/12/97- 11/20/98
(18 events) AFVR 6,898 47.9
6/8/16 AFVR 51 50.5
7/24-28/01 MMPE 865 9.0
1/21-25/02 MMPE 50 0.5
6/20-24/16 MMPE 1,445 15.1
5/6-10/19 MMPE 269 2.8
3/15-19/21 MMPE 288 3.0
Total 9,865

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5.0 GROUNDWATER CHARACTERIZATION
5.1 Water Supply Wells
Eleven water supply wells have been previously identified within 1,000 feet from the site. Figure
3 depicts the location of the water supply wells on an aerial overlay. Table 2 summarizes water
supply well information. Based on the distances from the source area to the water supply wells
and the groundwater flow direction, the water supply wells within 500 feet (WSW-1, WSW-2,
WSW-3, WSW-5, and WSW-6) are considered the most “at-risk” wells.

On April 2, 2021, ATC collected samples from water supply wells located at 2425 US Highway 21
(site/WSW-1), 2508 US Highway 21 (WSW-2), 1717 Hamptonville Road (WSW-6), and 2405 US
Highway 21 (WSW-7).

The water supply wells located at 1704 Hamptonville Road (WSW-3) and 1708/1712 Hamptonville
Road (WSW-5) could not be sampled due to the occupant not being present.

Each water supply well sample was collected from outdoor spigots after purging for
approximately fifteen minutes. Field notes from the April 2, 2021 sampling event are presented
in Appendix B. The water samples were collected in laboratory-supplied, preserved containers;
entered into chain of custody control; placed on ice; and shipped to North Carolina accredited
Pace Analytical Services, LLC (Pace), in Huntersville, North Carolina, for laboratory analysis.
The samples were analyzed using Standard Method (SM) 6200B with ethanol and oxygenates,
and EPA Method 501.4 for EDB. A copy of the laboratory report is included in Appendix C.
Analytical results from supply well sampling indicate the following:

 Water supply well WSW-6 contained bromodichloromethane (1.0 µg/L), chloroform (5.4
µg/L), dibromocholoromethane (0.42J µg/L) and toluene (2.5 µg/L) at concentrations
below the 2L Standards for the respective compounds. No other VOCs were detected in
WSW-6; and
 No VOCs were detected in WSW-1, WSW-2, or WSW-7.

Due to the detection of VOCs in water supply well WSW-6, the NCDEQ conducted a Health
Risk Evaluation. The April 15, 2021 HRE stated that “None of the contaminants detected
exceeded the applicable water standards. Therefore, no restrictions of the use of the water are
recommended at this time.” The HRE is included in Appendix D.

Table 3 summarizes current water-supply well analytical results, and Table 4 summarizes
historical water supply well analytical results.

As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of the
laboratory reports was conducted. During the review, it was found that the samples were received
from the laboratory in acceptable condition and properly preserved. The samples were analyzed
within correct holding times and reported within the lab report, and the chain of custody was
properly completed by all parties. The laboratory QC report shows that an internal blank was
analyzed for each method that was used for the original samples. The laboratory fortified blank
(LFB) and laboratory control sample (LCS) data results were also provided for each analytical
method. VOCs were not detected in the field blank or trip blank. Refer to the laboratory reports
in Appendix C for details regarding QA results for the laboratory samples and any noted
exceptions. Overall, ATC concludes that the laboratory results are usable and any exceptions do
not significantly impact the conclusions presented in this report.

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5.2 Groundwater Levels
On March 15, 2021 and March 17, 2021, ATC measured the water levels in wells MW-1, MW-3,
and RW-3. ATC also measured the depth to water in the site monitoring/remediation wells on
April 2, 2021. LNAPL was not detected in the wells, except for 0.03 feet in well RW-1 on April 2,
2021. Figure 2 depicts a site map with the monitoring well locations. Monitoring well
construction details are included in Table 5. An oil/water interface probe was used to measure
the depth to groundwater from the top of well casing (TOC) in each well. Depth to groundwater
and water level elevation data are summarized in Table 1. Note that the groundwater levels
were above the top of well screens in the shallow monitoring wells. LNAPL (0.03 feet) was
detected in well RW-1 on April 2, 2021.

Based on depths to groundwater measured on April 2, 2021, the groundwater surface appears
to be mounded at the location of the former Williams Grocery building, with groundwater flow
primarily to the east and southeast. Due to unseasonal high rainfall during the fall and winter of
2020, groundwater levels in the monitoring wells were above the well screens during this sampling
event.

Figure 4 depicts a groundwater elevation contour map based on the April 2, 2021 data. Field
notes from the March 13, March 17, and April 2, 2021, groundwater monitoring event are
presented in Appendix B.

5.3 Groundwater Quality
ATC sampled wells MW-1, MW-3, and RW-1 on March 15, 2021 prior to the MMPE event, and
on March 17, 2021 after removing approximately 5,000 gallons of groundwater. On April 2,
2021, ATC sampled wells MW-1, MW-3, MW-5, MW-12, and AS-1.

During sampling activities, a three-volume well purge was implemented prior to groundwater
sample collection to ensure collection of representative groundwater samples. Field notes of the
sampling events are included in Appendix B. The groundwater samples were collected in
laboratory-supplied, preserved containers; entered into chain of custody control; placed on ice;
and shipped to Pace for analysis by SM 6200B including ethanol and oxygenates. A copy of the
laboratory report is included in Appendix C.

Groundwater field parameters including temperature, dissolved oxygen, conductivity, pH, and
oxidation reduction potential were measured during the monitoring event. Field parameter
readings for each well are presented in Table 6. Low dissolved oxygen levels [1.3 milligrams
per liter (mg/L) or less] in wells MW-1 and MW-3 are indicative of biological degradation of the
VOCs. Well MW-5 with low concentrations of VOCs, had the highest DO concentration of 7.5
mg/L. The other field parameters are not significantly different to make any conclusions.

Current and historical groundwater analytical results are summarized in Table 7 and Table 8,
respectively. The groundwater analytical results were compared to the 2L Standards and GCLs.
Groundwater analytical results indicated the following:

 The GCLs were exceeded in well MW-1 (benzene, EDB, 1,2-DCA, and tert-butyl alcohol
(TBA), and wells MW-3 and RW-1 (benzene and EDB), prior to the MMPE event.
 GCLs were exceeded in well RW-1 (benzene and EDB), at the approximate mid-point of
the MMPE event.
 GCLs were exceeded in well MW-1 (benzene, EDB, 1,2-DCA, and TBA), and well MW-3
(benzene and EDB), after the MMPE event.
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 Additional VOCs were detected in wells MW-1, MW-2, MW-3, MW-5, and AS-1 at
concentrations exceeding the 2L Standards.
 No VOCs were detected in well MW-12.

Figure 5 depicts VOC concentrations that exceeded the 2L Standards. Based on recent and
historical monitoring well sampling results, the horizontal extent of the VOC plume is defined
with the exception of the upgradient direction to the north and northwest. The greatest
concentrations of volatile organic compounds (VOCs) were detected in monitoring wells MW-1,
MW-3, and RW-1, with exceedances of the GCLs. The VOC concentrations appear to be
relatively stable, with several VOCs increasing in concentrations following the MMPE/AS event.
The April 2, 2021 sampling results indicate that the combined MMPE/AS event was not effective
in reducing VOC concentrations.

The QA and QC measures and conditions applicable to the water supply well monitoring, as
discussed in Section 5.1, also apply to the monitoring well sampling.

6.0 CONCLUSIONS AND RECOMMENDATIONS
On behalf of the Trust Fund Branch of the UST Section, ATC has completed a GMR
documenting the February 12 and 13, well installation and groundwater monitoring event for
Williams Grocery, located at 2425 US Highway 21, Hamptonville, Yadkin County, North
Carolina. The following summarizes the site conditions based on the recent and historical
assessment activities:

 There are no surface water bodies within 500 feet of the source area.
 Eleven active drinking water supply wells are located within 1,000 feet of the source
area, with one well (WSW-1) located within 250 feet of the source area. Municipal water
is not available to the site and surrounding area. Based on the groundwater flow
direction, ATC considers water supply wells WSW-1 and WSW-3 to be the most “at risk”
wells.
 During March 15 to 19, 2021, a 96-hour combined MMPE/AS event was conducted
using MW-1, MW-3, and RW-1 as extraction wells and well AS-1 as an AS well. LNAPL
was not detected in the target wells prior to, immediately after or 20 minutes after the
MMPE event, although the initial water levels in wells MW-1 and MW-3 were above the
top of well screens. Approximately 9,580 gallons of total fluid and 288 pounds of VOCs
as vapor were removed during the MMPE event.
 Approximately 9,865 pounds of petroleum as vapor have been recovered over time at
this site.
 Water supply wells WSW-1, WSW-2, WSW-6, and WSW-7 were sampled on April 2,
2021. Water supply well WSW-6 contained VOCs at concentrations less than the 2L
Standards. No VOCs were detected in WSW-1, WSW-2, or WSW-7.
 Health Risk Evaluation conducted by the NCDEQ for water supply well WSW-6 indicated
no restrictions of the use of the water at this time.
 Groundwater samples were obtained prior to the MMPE (March 15, 2021), during the
MMPE (March 17, 2021), and 2 weeks after the MMPE event (April 2, 2021).
 LNAPL was detected in RW-1 at a thickness of 0.03 feet during the April 2, 2021 sampling
subsequent to the MMPE event. The concentrations of VOCs in monitoring wells MW-1
and MW-3 suggest residual LNAPL is present.
 GCLs were exceeded in wells MW-1, MW-3, and RW-1.
 Additional VOCs were detected in monitoring wells MW-1, MW-2, MW-3, MW-5, and AS-1
at concentrations exceeding the 2L Standards.
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 No VOCs were detected in well MW-12.
 The depth to groundwater in the shallow wells ranged from 15.80 ft-toc in MW-6 to 19.38 in
well RW-1. Groundwater flow is generally to the east-southeast, with mounding at well MW-
2.
 Due to seasonal rainfall well screens were submerged during this sampling event.

Based on recent and historical monitoring well sampling results, the horizontal extent of the
VOC plume is defined with the exception of the upgradient direction to the north and northwest.
The greatest concentrations of VOCs were detected in monitoring wells MW-1, MW-3, and RW-
1, with exceedances of the GCLs, and the concentrations appear to be relatively stable, with
several VOCs increasing in concentrations following the MMPE/AS event. The April 2, 2021
groundwater sampling results indicate that the combined MMPE/AS event was not effective in
reducing VOC concentrations; however, the event was successful in removing VOCs from the
subsurface.

ATC recommends a sampling event to include MW-1, MW-3, MW-5 and RW-1 in approximately
six months to evaluate the possible long term effectiveness of the MMPE/AS event, followed by
an evaluation of possible alternative remediation efforts.

TABLES
Well ID Gauging Date
Well Screen
Interval
(ft-bgs)
Depth to
Groundwater
(ft-toc)
Depth to
LNAPL
(ft-toc)
LNAPL
Thickness
(ft)
TOC
Elevation
(ft)
Groundwater
Elevation
(ft)
9/10/2008 27.87 27.15 0.72 471.57
6/17/2009 NM NM --NM
11/9/2009 26.43 26.08 0.35 472.69
11/30/2009 26.02 ----472.80
6/14/2010 22.86 ----475.96
9/15/2011 25.80 ----473.02
6/13/2012 25.72 25.71 0.01 473.11
2/25/2014 22.28 ----476.54
10/3/2015 25.21 ----473.61
11/7/2017 24.25 ----474.57
5/6/2019 20.34 ----478.48
6/6/2019 20.43 ----478.39
2/12/2020 21.99 ----476.83
3/15/2021 18.80 ----480.02
3/19/2021 20.40 ----478.42
4/2/2021 18.75 ----480.07
9/10/2008 27.83 ----471.44
6/17/2009 27.01 ----472.26
11/30/2009 26.39 ----472.88
6/14/2010 23.04 ----476.23
9/15/2011 26.10 ----473.17
6/13/2012 26.11 ----473.16
2/25/2014 22.47 ----476.80
10/3/2015 25.61 ----473.66
11/7/2017 24.75 ----474.52
6/6/2019 20.65 ----478.62
2/12/2020 22.45 ----476.82
4/2/2021 18.80 ----480.47
9/10/2008 28.06 27.72 0.34 471.05
6/17/2009 27.15 ----472.32
11/30/2009 26.45 ----473.02
6/14/2010 23.37 ----476.10
9/15/2011 26.22 ----473.25
6/13/2012 26.26 26.25 0.01 472.57
2/25/2014 22.78 ----476.69
10/3/2015 25.84 ----473.63
11/7/2017 24.66 ----474.81
5/6/2019 20.92 ----478.55
6/6/2019 20.98 ----478.49
2/12/2020 22.62 ----476.85
3/15/2021 19.41 ----480.06
3/19/2021 20.40 ----479.07
4/2/2021 19.33 ----480.14
9/10/2008 27.87 ----471.58
6/17/2009 27.32 ----472.13
11/30/2009 26.66 ----472.79
6/14/2010 23.33 ----476.12
9/15/2011 26.41 ----473.04
6/13/2012 26.52 ----472.93
10/3/2015 25.90 ----473.55
11/7/2017 25.12 ----474.33
6/6/2019 20.95 ----478.50
2/12/2020 23.01 ----476.44
4/2/2021 19.23 ----480.22
23-33 498.82
MW-3 23-33 499.47
MW-2 20-30 499.27
MW-1
MW-4 24-34 499.45
NCDEQ INCIDENT #15063
TABLE 1
GROUNDWATER ELEVATION DATA
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
Page 1 of 2
Well ID Gauging Date
Well Screen
Interval
(ft-bgs)
Depth to
Groundwater
(ft-toc)
Depth to
LNAPL
(ft-toc)
LNAPL
Thickness
(ft)
TOC
Elevation
(ft)
Groundwater
Elevation
(ft)
NCDEQ INCIDENT #15063
TABLE 1
GROUNDWATER ELEVATION DATA
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
9/10/2008 24.43 ----473.91
6/17/2009 26.54 ----471.80
11/30/2009 26.03 ----472.31
6/14/2010 23.20 ----475.14
9/15/2011 26.06 ----472.28
6/13/2012 25.71 ----472.63
2/25/2014 22.54 ----475.80
10/3/2015 25.49 ----472.85
11/7/2017 24.22 ----474.12
6/6/2019 20.93 ----477.41
2/12/2020 22.13 ----476.21
4/2/2021 19.10 ----479.24
9/10/2008 NM ----NM
6/17/2009 23.20 ----472.19
11/30/2009 26.20 ----469.19
6/14/2010 NM ----NM
9/15/2011 NM ----NM
6/13/2012 22.40 ----472.99
2/25/2014 19.24 ----476.15
10/3/2015 22.15 ----473.24
11/7/2017 20.91 ----474.48
6/6/2019 17.87 ----477.52
2/12/2020 19.63 ----475.76
4/2/2021 15.30 ----480.09
9/10/2008 NM ----NM
6/17/2009 21.54 ----471.44
11/30/2009 21.10 ----471.88
6/14/2010 18.66 ----474.32
9/15/2011 NM ----NM
6/13/2012 NM ----NM
2/25/2014 NM ----NM
10/3/2015 NM ----NM
11/7/2017 NM ----NM
6/6/2019 NM ----NM
2/12/2020 NM
2/12/2020 21.01 ----475.84
4/2/2021 17.36 ----479.49
9/10/2008 27.64 27.26 0.38 472.07
6/17/2009 NM NM --NM
11/9/2009 26.64 26.58 0.06 472.79
11/30/2009 26.47 26.45 0.02 472.93
6/14/2010 23.39 ----475.99
9/15/2011 26.39 26.21 0.18 473.14
6/13/2012 26.23 26.20 0.03 473.18
2/25/2014 22.75 ----476.63
10/3/2015 25.72 ----473.66
11/7/2017 24.94 ----474.44
5/6/2019 20.90 ----478.48
6/6/2019 20.96 ----478.42
2/12/2020 22.97 ----476.41
3/15/2021 19.45 ----479.93
3/19/2021 21.10 ----478.28
4/2/2021 19.38 19.35 0.03 480.03
Notes:
ft = feet ft-toc = feet below top of casing
ft-bgs = feet below ground surface TOC = Top of Casing
Groundwater elevation calculated by [Top of Casing Elevation - Depth to Water] + [LNAPL Thickness*0.8581]
24-34 495.39
MW-12 20-35 496.85
Not Located
MW-8 22-32 492.98
RW-1 ?-45 499.38
MW-5 24-34 498.34
MW-6
Page 2 of 2
Well ID Well Owners / Well Users Property Address Mailing Address Well Use
(P/I/N)
Estimated
Distance/Direction from
Source Area (ft)
WSW-1 Derek Shore 2425 US Highway 21
Hamptonville, NC 27020
2424 US Highway 21
Hamptonville, NC 27020 P 105
WSW-2 Sandra Gail Long 2032 Petty Rd
Hamptonville, NC 27020
2508 US Highway 21
Hamptonville, NC 27020 P 440
WSW-3 Delma Church (deceased)1704 Hamptonville Road
Hamptonville, NC 27020
1704 Hamptonville Road
Hamptonville, NC 27020 P 345
WSW-4 Derek Shore 2424 US Highway 21
Hamptonville, NC 27020
2424 US Highway 21
Hamptonville, NC 27020 P 820
WSW-5 Wesley Wall 1708, 1712 Hamptonville Road
Hamptonville, NC 27029
PO Box 206
Sullivan Island, SC 29482 P 400
WSW-6 John H. Gardner (deceased)1717 Hamptonville Road
Hamptonville, NC 2720
1717 Hamptonville Road
Hamptonville, NC 27020 P 300
WSW-7 Terry Windsor 2405 US Highway 21
Hamptonville, NC 27020
4139 Old US Highway 21
Hamptonville, NC 27020 P 630
WSW-8 Jerry Wall 1737 Hamptonville Road
Hamptonville, NC 27020
PO Box 509
Hamptonville, NC 27020 P 925
WSW-9 Willis Scowls 2401 US Highway 21
Hamptonville, NC 27020
2401 US Highway 21
Hamptonville, NC 27020 P 740
WSW-10 Olen King 2345 US Highway 21
Hamptonville, NC 27020
2345 US Highway 21
Hamptonville, NC 27020 P 930
WSW-18 Bobby D. Church 2516 US Highway 21
Hamptonville, NC 27020
2516 US Highway 21
Hamptonville, NC 27020 P 690
Notes:
NA = Not available or unknown.
P / I / N = Potable water supply / Irrigation / Not in use
NCDEQ INCIDENT #15063
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
2425 US HIGHWAY 21
WILLIAMS GROCERY
WATER-SUPPLY WELL INFORMATION
TABLE 2
Well ID Sample Date
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthaleneBromodichloromethaneChloroformDibromochloromethane1 600 600 500 20 6 0.6 70 0.4
WSW-1 04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <0.31 <0.35 <0.36
WSW-2 04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <0.31 <0.35 <0.36
WSW-3 04/02/2021 Not Sampled - Property Owner Absent
WSW-5 04/02/2021 Not Sampled - Property Owner Absent
WSW-6 04/02/2021 <0.34 2.5 <0.30 <0.34 <0.42 <0.64 1.0 5.4 0.42J
WSW-7 04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <0.31 <0.35 <0.36
Notes:
"<" = Not Detected at or above the laboratory detection limit.
Concentrations are reported in micrograms per liter (µg/L)
2L Standard = 15A NCAC 02L .0202 Groundwater Quality Standard
NCDEQ INCIDENT #15063
2L Standard
TABLE 3
RECENT WATER SUPPLY WELL ANALYTICAL DATA
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-DichloroethaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneDibromochloromethane1 600 600 500 20 6 6,000 0.6 70 70 3 0.02 6 0.40 70 4,000 40 70 25 100 4,000 70 70 400 400 0.4
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 70,000 3,000 50 6,000 400 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 400
11/8/1996 ND ND ND ND ND NS ----NS ----ND --NS ND ----NS NS ----NS --NS NS NA
4/14/1998 ND ND ND ND ND NS ----NS ----ND --NS ND ----NS NS ----NS --NS NS NA
6/12/2003 ND ND ND ND <0.5 ND ----NS ----ND --ND NS ----ND ND ----ND --ND ND NA
3/8/2004 ND ND ND ND <1 ND ----NS ----ND --ND NS ----ND ND ----ND --ND ND NA
12/1/2005 ND ND ND ND ND ND ----ND ----<0.5 --<0.5 ND ----ND ND ----ND --ND ND NA
9/10/2008 <0.5 <0.5 <0.5 <1 NS <2 ----<0.5 ----<0.5 --<0.5 <0.5 ----<0.5 <0.5 ----<0.5 --<0.5 <0.5 NA
6/17/2009 <1 <5 <1 <3 NS <5 ----<1 ----<1 --<1 <1 ----<1 <1 ----<1 --<1 <1 NA
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 <0.080 <0.24 <0.050 --<0.11 <0.050 <0.070 <0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA
6/14/2010 63 0.95 <0.054 13.84 J 28 2.6 <1.5 <0.031 <0.059 <0.059 0.97 <0.041 <0.038 1.3 0.69 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 0.80 NA
9/13/2010 55 0.79 <0.054 16 24 3.4 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 1 0.63 <42 <0.11 0.67 <0.059 --<0.11 <0.059 <0.034 1.2 1.1 NA
9/15/2011
PRE POE <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/15/2011
POST POE <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011
PRE POE <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011
POST POE <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012
PRE POE <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012
POST POE <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/25/2014 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
11/7/2017 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 --<5.0 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <0.50 <0.50 NA
6/6/2019 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13 <65 <1.0 <0.13 <0.13 <1.3 <1.3 <0.13 <0.13 <0.13 <0.13 NA
2/12/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.35 <0.42 <0.011 <0.24 <0.26 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 NA
04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 NA <0.31 <0.49 <0.35 <0.65 <0.013 <0.37 <0.32 <0.31 <72.2 NA <0.33 NA NA NA <0.34 <0.29 <0.50 <0.33 <0.36
11/1/1997 ND ND ND ND ND ND ----ND ----ND --ND ND ----ND ND ----ND --ND ND NA
12/1/2005 ND ND ND ND ND ND ----ND ----<0.5 --<0.5 ND ----ND ND ----ND --ND ND NA
9/10/2008 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NA
6/17/2009 <1 <5 <1 <3 <1 <5 ----<1 ----<1 --<1 <1 ----<1 <1 ----<1 --<1 <1 NA
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 <0.080 <0.24 <0.050 --<0.11 <0.050 <0.070 <0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA
6/14/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/15/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/25/2014 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
10/19/2015 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
6/6/2019 <0.13 0.87 <0.13 <0.25 <0.13 <0.13 <2.0 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13 <65 <1.0 <0.13 <0.13 <1.3 <1.3 <0.13 <0.13 <0.13 <0.13 NA
2/12/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.35 <0.42 <0.011 <0.24 <0.26 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 NA
04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 NA <0.31 <0.49 <0.35 <0.65 <0.013 <0.37 <0.32 <0.31 <72.2 NA <0.33 NA NA NA <0.34 <0.29 <0.50 <0.33 <0.36
2L Standard
GCL Standard
WSW-2
TABLE 4
HISTORICAL WATER SUPPLY WELL ANALYTICAL RESULTS
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #15063
WSW-1
Page 1 of 3
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-DichloroethaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneDibromochloromethane1 600 600 500 20 6 6,000 0.6 70 70 3 0.02 6 0.40 70 4,000 40 70 25 100 4,000 70 70 400 400 0.4
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 70,000 3,000 50 6,000 400 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 400
2L Standard
GCL Standard
TABLE 4
HISTORICAL WATER SUPPLY WELL ANALYTICAL RESULTS
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #15063
4/14/1998 ND ND ND ND ND NS ----NS ----ND --NS ND ----NS NS ----NS --NS NS NA
6/12/2003 ND ND ND ND ND ND ----NS ----ND --ND NS ----ND ND ----ND --ND ND NA
3/8/2004 ND ND ND ND ND ND ----NS ----ND --ND NS ----ND ND ----ND --ND ND NA
12/1/2005 ND ND ND ND ND ND ----ND ----<0.5 --<0.5 ND ----ND ND ----ND --ND ND NA
9/10/2008 <0.5 <0.5 <0.5 <1 <0.5 <2 ----<0.5 ----<0.5 --<0.5 <0.5 ----<0.5 <0.5 ----<0.5 --<0.5 <0.5 NA
6/17/2009 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NA
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 <0.080 <0.24 <0.050 --<0.11 <0.050 <0.070 <0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA
6/14/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/15/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/25/2014 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
11/7/2017
6/6/2019
2/12/2020
04/02/2021
6/12/2003 ND ND ND ND ND ND ----NS ----ND --ND NS ----ND ND ----ND --ND ND NA
3/8/2004 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NA
12/1/2005 ND ND ND ND ND ND ----ND ----<0.5 --<0.5 ND ----ND ND ----ND --ND ND NA
9/10/2008 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NA
6/17/2009 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----4.3 J <0.059 <0.034 <0.038 <0.038 NA
9/15/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/25/2014 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
10/19/2015 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 1.2 <0.24 12 --<0.11 <0.050 <0.070 <0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA
2/12/2010 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <5 <0.50 <1.0 1 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <1.0 <0.50 NA
6/14/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/15/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/25/2014 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
10/19/2015 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
11/7/2017
6/6/2019 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13 <65 <1.0 <0.13 <0.13 <1.3 <1.3 <0.13 <0.13 <0.13 <0.13 NA
2/12/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.35 <0.42 <0.011 <0.24 <0.26 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 NA
04/02/2021
WSW-3
Not Sampled - Occupant Absence
Not Sampled - Occupant Absence
Not Sampled - Occupant Absence
Not Sampled - Occupant Absence
WSW-5
Not Sampled - Occupant Absence
WSW-4
Not Sampled - Occupant Absence
Page 2 of 3
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-DichloroethaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneDibromochloromethane1 600 600 500 20 6 6,000 0.6 70 70 3 0.02 6 0.40 70 4,000 40 70 25 100 4,000 70 70 400 400 0.4
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 70,000 3,000 50 6,000 400 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 400
2L Standard
GCL Standard
TABLE 4
HISTORICAL WATER SUPPLY WELL ANALYTICAL RESULTS
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #15063
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 1.2 <0.24 12 --<0.11 <0.050 <0.070 <0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA
6/14/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/15/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/25/2014 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
10/19/2015 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
11/7/2017 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 --<5.0 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <0.50 <0.50 NA
6/6/2019 <0.50 <0.50 <0.50 <1.5 <0.50 <0.50 <50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 --<5.0 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <0.50 <0.50 NA
2/12/2020
04/02/2021 <0.34 2.5 <0.30 <0.34 <0.42 <0.64 NA 1.0 <0.49 5.4 <0.65 <0.013 <0.37 <0.32 <0.31 <72.2 NA <0.33 NA NA NA <0.34 <0.29 <0.50 <0.33 0.42J
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 1.2 <0.24 12 --<0.11 0.63 <0.070 <0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA
2/12/2010 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <5 <0.50 <1.0 1 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <1.0 <0.50 NA
6/14/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 0.053 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/15/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
12/6/2011 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 0.52 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/13/2012 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 0.52 <0.054 <0.042 <42 <0.11 <0.034 <0.059 --<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/25/2014 <0.50 <0.50 <0.50 <1.0 <0.50 <2.0 --------<1.0 ----<0.50 <0.50 ----<0.50 ----------<0.50 <0.50 NA
11/7/2017
6/6/2019 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.13 <0.13 <0.13 <0.20 <0.13 0.31 J <0.13 <0.13 <65 <1.0 <0.13 <0.13 <1.3 <1.3 <0.13 <0.13 <0.13 <0.13 NA
2/12/2020 <0.24 9.3 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.35 <0.42 <0.011 <0.24 <0.26 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 NA
04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 NA <0.31 <0.49 <0.35 <0.65 <0.012 <0.37 <0.32 <0.31 <72.2 NA <0.33 NA NA NA <0.34 <0.29 <0.50 <0.33 <0.36
WSW-8 9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
6/6/2019 <0.13 <0.13 <0.13 <0.25 0.13 J <0.13 55.1 <0.13 <0.13 <0.13 0.33 J <0.13 0.28 J <0.13 <0.13 <65 <1.0 <0.13 <0.13 <1.3 17.1 <0.13 <0.13 <0.13 <0.13 NA
2/12/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.35 <0.42 <0.011 <0.24 <0.26 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 NA
9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
2/12/2020
4/2/2021
WSW-18 9/13/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.053 <0.032 <0.041 <0.038 <0.054 <0.042 <42 --<0.034 ----<0.83 <0.059 <0.034 <0.038 <0.038 NA
Notes:
"<" or ND = Not Detected at or above the laboratory detection or reporting limit
Concentrations are reported in micrograms per liter (µg/L)
Italicized values indicate levels above GCLs
J = Estimated value below method reporting limit
NA = Not Analyzed
GCL = Gross Contamination Level
Concentrations in bold print equal or exceed the 15A NCAC 2L .0202 Groundwater Qualtiy Standard (2L Standard).
WSW-9
WSW-7
WSW-6
Not Sampled - Occupant Absence
Not Sampled - No Running Water
Not Required
Not Sampled - Tenant Could Not Give Approval For Property Owner
WSW-10
Page 3 of 3

MW-1 November 1996 33 23-33 498.82
MW-2 November 1996 30 20-30 499.27
MW-3 November 1996 33 23-33 499.48
MW-4 April 1998 34 24-34 499.45
MW-5 April 1998 34 24-34 498.34
MW-6 April 1998 34 24-34 495.39
MW-8 April 1998 32 22-32 492.98
MW-12 February 2020 35 20-35 496.85
RW-1 June 2010 Unknown Unknown 499.38
Notes:
ft = feet
ft-bgs = feet below ground surface
TOC = Top of Casing
NCDEQ INCIDENT #15063
Well ID Date Installed Depth of Well
(ft-bgs)
Well Screen
Interval
(ft-bgs)
TOC
Elevation
(ft)
TABLE 5
MONITORING WELL CONSTRUCTION DETAILS
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
Well Date Temperature
(◦C)
Conductivity
(mS/cm)
pH
(su)
Oxidation-
Reduction
Potential
(mV)
Dissolved
Oxygen
(mg/L)
MW-1 4/2/2021 12.8 0.104 5.0 205 1.3
MW-2 4/2/2021 Not Required
MW-3 4/2/2021 13.7 0.184 4.7 218 1.1
MW-4 4/2/2021 Not Required
MW-5 4/2/2021 10.4 0.040 5.2 161 7.5
MW-6 4/2/2021 Not Required
MW-12 4/2/2021 12.1 0.104 6.2 153 4.0
AS-1 4/2/2021 12.2 0.092 5.8 162 3.2
RW-1 4/2/2021
Notes:
°C = Degrees Celsius
su = Standard Units
mV = millivolts
mS/cm = milliSiemens per centimeter
mg/L = milligrams per liter
Parameters Not Collected
NCDEQ INCIDENT #15063
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
TABLE 6
FIELD PARAMETERS
WILLIAMS GROCERY
2425 US HIGHWAY 21
Sample ID Constituent
of Concern
BenzeneTolueneEthylbenzeneXylene (Total)Methyl-tert-butyl etherNaphthalenen-Butylbenzenesec-ButylbenzeneChloroform1,2-Dibromoethane (EDB)1,2-DichloroethaneDiisopropyl ether2-HexanoneIsopropylbenzene (Cumene)Styrene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Butyl Alcohol1 600 600 500 20 6 70 70 70 0.02 0.4 70 40 70 70 400 400 40 10
5,000 260,000 80,000 50,000 20,000 6,000 69,00 8,500 70,000 50 400 70,000 40,000 25,000 70,000 28,500 24,100 40,000 10,000
03/15/2021 11,100 18,900 1,670 15,700 6,700 815 <98.0 <80.0 <70.6 858 1,130 200 853J <66.6 <58.4 2,670 773 17,000J 15,200
03/17/2021 2,860 4,010 290 6,040 5,050 327 <19.6 <16.0 <14.1 334 419 95.1 360 17.9J 1,380 1,380 465 15,300 24,700
04/02/2021 15,100 21,700 1,730 12,800 8,260 738 <61.2 <50.0 <44.1 809 1,060 291 NA 76.7 40.0J 2,200 658 12,600 16,000
03/15/2021 15,200 29,400 2,260 17,000 <106 816 <122 <100 <88.2 779 220 <77.0 527J 102J 79.0J 2,710 789 <9100 <6700
03/17/2021 2,840 6,020 442 5,880 51.1 520 <24.5 <20.0 <17.6 240 65.5 <15.4 228J 27.9 1,370 1,370 588 4,960J <1340
04/02/2021 15,300 28,400 2,220 15,000 <84.4 990 <98.0 <80.0 <70.6 673 195 <61.6 NA 106 75.4J 2,730 <66.4 <7280 <5360
03/15/2021 17,000 39,600 4,920 24,400 252 2,580 <98.0 <80.0 <70.6 515 337 103 <95.2 396 117 12,100 3,100 <7280 <5360
03/17/2021 15,400 41,400 3,800 21,400 717 1,210 <122 <100 <88.2 550 408 142 <119 188 4,870 4,870 1,330 <9100 <6700
MW-5 04/02/2021 4.5 12.6 2.1 17.9 <0.42 1.6J 0.76 <0.40 <0.35 <0.27 <0.32 <0.31 NA <0.33 <0.29 9.9 3.5 <36.4 <26.8
MW-12 04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 <0.49 <0.40 <0.35 <0.27 <0.32 <0.31 NA <0.33 <0.29 <0.50 <0.33 <36.4 <26.8
AS-1 04/02/2021 11.1 5.2 1.0 20.7 24.4 2.3 <0.49 <0.40 <0.35 0.74 24.9 10 NA <0.33 <0.29 1.2 <0.33 2,070 101
Notes:
Italicized values indicate levels above GCLs
J = Estimated value below method reporting limit
Concentrations in bold print exceed the 15A NCAC 02L .0202 Groundwater Quality Standard (2L Standard).
Concentrations in underlined print exceed the Gross Contamination Level (GCL)
MW-1
MW-3
RW-1
2L Standard
GCL
TABLE 7
RECENT GROUNDWATER ANALYTICAL RESULTS
WILLIAMS GROCERY
2425 US HIGHWAY 21
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
NCDEQ INCIDENT #15063
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-Dichloroethane1,2-DichloropropaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Butyl Alcoholtert-Amylmethyl ether1 600 600 500 20 6 6,000 0.6 70 70 70 3 0.02 6 0.40 0.60 70 4,000 40 70 25 100 4,000 70 70 400 400 40 10 128
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 8,500 70,000 3,000 50 6,000 400 600 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 40,000 10,000 12800
11/8/1996
4/14/1998
6/12/2003
3/8/2004
12/1/2005 23,009 33,000 3,200 152,000 25,000 2,700 ----<250 ------1,200 --5,100 --560 ----<250 <250 ----<250 --3,700 15,200 NA NA NA
9/10/2008
6/17/2009
11/30/2009 26,000 29,000 3,000 9,100 28,000 800 5,000 <3.2 25 --<2 --1,000 <2 <2 --590 9,700 190 110 4,000 110 2,700 300 67 2,500 110 NA NA NA
6/14/2010 30,000 35,000 2,900 16,400 54,000 1,100 10,000 <2 82 34 <2.1 <13 1,300 <1.5 2,900 --600 <1,700 580 160 --<1.9 7,400 420 72 1,400 1,100 NA NA NA
9/15/2011 35,000 38,000 2,700 19,500 75,000 660 14,000 <3.1 <5.9 <5.4 <13 <3.2 1,800 <3.8 4,300 --940 <4,200 450 190 96 250 9,800 320 170 2,100 550 NA NA NA
6/13/2012
2/25/2014 24,800 32,900 2,890 19,280 66,200 1,090 NA <25.0 <25.0 <25.0 <25.0 <50.0 1,440 <25.0 2,860 <25.0 744 NA NA 144 NA NA NA 438 103 3,880 1,110 NA NA NA
10/3/2015 23,400 30,700 2,550 14,090 35,900 <1,000 NA <250 <250 <250 <250 <500 1,350 <250 2,500 <250 549 NA NA <250 NA NA NA <250 <250 2,170 588 NA NA NA
11/7/2017 27,000 34,000 2,700 14,200 30,000 820 31,000 <200 <200 <200 <200 <800 1,500 <200 3,300 <200 540 NA 1,600 J 96 J <200 <2,000 15,000 260 210 2,100 540 NA NA NA
5/6/2019 19,800 32,700 3,130 20,000 19,400 894 24,500 <500 <500 <500 <500 <500 1,260 <500 1,970 <500 369 J NA <5,000 139 J <500 <2,500 8,940 424 J <500 3,610 1,120 NA NA NA
6/6/2019 19,600 31,100 2,790 18,800 16,700 695 15,300 <130 <130 <130 <130 <200 1,160 <130 1,830 <130 390 J <65,000 <1,000 141 J <130 <1,300 7,820 358 J <130 2,990 934 NA NA NA
2/13/2020 19,500 26,400 2,000 15,300 36,500 710 NA <37.0 <70.6 <49.2 <70.6 <83.0 1,130 <48.8 2280 <36.6 590 <19800 NA <47.6 NA NA NA 167 <51.2 2,260 558 59,600 286,000 NA
03/15/2021 11,100 18,900 1,670 15,700 6,700 815 NA <61.4 <98.0 <80.0 <70.6 NA 858 <73.4 1130 <71.0 200 <14400 853J <66.6 NA NA 2110 <68.0 <58.4 2,670 773 17000J 15,200 <532
03/17/2021 2,860 4,010 290 6,040 5,050 327 NA <12.3 <19.6 <16.0 <14.1 NA 334 <13.9 419 <14.2 95.1 <2890 360 17.9J NA NA NA <13.6 1,380 1,380 465 15,300 24,700 111J
04/02/2021 15,100 21,700 1,730 12,800 8,260 738 NA <38.4 <61.2 <50.0 <44.1 NA 809 <43.5 1060 <44.4 291 <9020 NA 76.7 NA NA NA <42.5 40.0J 2,200 658 12,600 16,000 <332
11/8/1996 1,200 3,100 400 1,580 ND NS ----NS ------11.3 --NS --170 ----NS NS ----NS --NS NS NA NA NA
4/14/1998 640 1,100 56 350 ND ND ----NS ------ND --NS --81 ----NS NS ----NS --NS NS NA NA NA
6/12/2003 ND 1.3 ND 12 ND ND ----NS ------ND -ND --ND ----ND NS ----ND --ND 5 NA NA NA
3/8/2004 1.4 2.6 ND 27.1 ND ND ----NS ------ND --ND --ND ----ND NS ----ND --ND 10 NA NA NA
12/1/2005 ND ND ND ND ND ND ----ND ------<0.50 --<0.5 --ND ----ND ND ----ND --ND ND NA NA NA
9/10/2008 142 494 92.7 386 <0.5 15.7 ----<0.5 ------1.7 --<5 --<0.5 ----3.4 <0.5 ----6.3 --44.1 24 NA NA NA
6/17/2009 41 120 16 79 <1 <5 ----<1 ------<1 --<1 --<1 ----<1 <1 ----1.4 --8.3 4.6 NA NA NA
11/30/2009 22 39 8 91 <0.11 1.6 <0.62 <0.080 <0.24 --<0.050 --<0.11 --<0.070 --<0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 0.52 <0.050 4.7 <0.080 NA NA NA
6/14/2010 <0.0054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --<0.034 <42 <0.11 <0.034 --<0.048 <0.83 <0.059 <0.034 <0.038 <0.038 NA NA NA
9/15/2011 10 110 20 214 <0.056 16 <1.5 <0.031 0.57 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --<0.042 <42 3.9 2.8 1.7 4 <0.83 4.4 <0.034 140 38 NA NA NA
6/13/2012 710 5,200 480 2,900 <0.056 130 49 J <0.031 22 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --<0.042 <42 3.9 23 12 4 <0.83 22 16 580 210 NA NA NA
2/24/2014 <0.50 <0.50 <0.50 <1.5 <0.50 <2.0 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.050 NA NA <0.50 NA NA NA <0.50 <0.50 <0.50 <0.50 NA NA NA
10/3/2015 51.7 233 2,550 188.6 <0.50 8 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 549 NA NA 1.5 NA NA NA 2.3 0.75 19.7 12.7 NA NA NA
11/7/2017 74 1,000 130 680 <25 39 <2,500 <25 <25 <25 <25 <100 <25 <25 <25 <25 <25 NA <250 <25 <25 <250 <250 <25 <25 86 34 NA NA NA
6/6/2019 <0.13 0.29 J 0.17 J 1.2 J <0.13 0.21 J <2.0 <0.13 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13 <0.13 <65 <1.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 1.1 0.39 J NA NA NA
2/13/2020 16.1 490 77.9 380 <2.2 18.1 NA <0.92 <1.8 <1.2 <1.8 <2.1 <1.2 <1.2 <1.3 <0.92 <1.7 <494 NA <1.2 NA NA NA <1.2 2.6 46.2 <1.1 <202 <88.0 NA
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
2425 US HIGHWAY 21
WILLIAMS GROCERY
MW-1
2L Standard
GCL Standard
Not Sampled - LNAPL
NCDEQ INCIDENT #15063
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
Not Sampled - LNAPL
Not Sampled - LNAPL
Not Sampled - LNAPL
Not Sampled - LNAPL
TABLE 8
Not Sampled - LNAPL
MW-2
Not Sampled - Could Not Locate
Page 1 of 5
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-Dichloroethane1,2-DichloropropaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Butyl Alcoholtert-Amylmethyl ether1 600 600 500 20 6 6,000 0.6 70 70 70 3 0.02 6 0.40 0.60 70 4,000 40 70 25 100 4,000 70 70 400 400 40 10 128
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 8,500 70,000 3,000 50 6,000 400 600 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 40,000 10,000 12800
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
2425 US HIGHWAY 21
WILLIAMS GROCERY
2L Standard
GCL Standard
NCDEQ INCIDENT #15063
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 8
11/8/1996
4/14/1998
6/12/2003
3/8/2004
12/1/2005 23,000 34,000 2,300 313,500 2,900 760 ----ND ------1,100 --1,200 --570 ----88 ND ----220 ND 2,100 460 NA NA NA
9/10/2008
6/17/2009 11,000 26,000 4,300 22,200 <100 610 ----210 ------470 --310 --<100 ----260 <100 ----990 <100 6,300 2,000 NA NA NA
11/30/2009 9,200 13,000 1,700 9,000 <4.4 570 <25 <3.2 33 --<2 ----------<3.2 <1,700 <7.6 90 <5.6 <5 350 250 <5.6 ----NA NA NA
6/14/2010 14,000 23,000 2,100 11,500 410 870 7,500 <1.2 31 <2.2 <2.1 <1.3 510 <1.5 410 --87 <1,700 790 110 --340 6,800 280 --2,200 620 NA NA NA
9/15/2011 31,000 44,000 2,900 15,200 590 890 10,000 <3.1 <5.9 <5.4 <5.3 <3.2 1,200 <3.8 1,100 --300 <4,200 1,200 210 95 420 6,200 370 95 2,700 670 NA NA NA
6/13/2012
2/25/2014 17,500 37,500 3,570 23,020 598 1,340 NA <50.0 <50.0 <50.0 <50.0 <100.0 1,030 <50.0 607 <50.0 149 <50.0 NA 192 NA NA NA 624 NA 4,980 1,400 NA NA NA
10/3/2015
11/7/2017 21,000 41,000 3,500 20,800 <500 1,300 5,500 J <500 <500 <500 <500 <500 1,200 <500 <500 <500 <500 NA <5,000 <500 <500 <5,000 2,700 J 420 J <500 3,500 980 NA NA NA
5/6/2019 18,300 32,300 2,350 15,800 <500 732 <10,000 <500 <500 <500 <500 <500 <500 <500 314 J <500 <500 NA <500 <500 <500 <2,500 <2,500 256 J <500 2,340 666 NA NA NA
6/6/2019 14,300 32,800 2,840 20,600 167 J 738 <2,000 <130 <130 <130 <130 <200 797 <130 298 J <130 <130 <65,000 <1,000 153 J <130 <1,300 <1,300 413 J <130 3,500 1,000 NA NA NA
2/13/2020 14,200 34,600 2,940 19,600 121J 1,030 NA <46.2 <88.2 <61.5 <88.2 <104 716 <61.0 201 <45.8 <83.5 <24700 NA <59.5 NA NA NA 361 88.9J 3,560 942 <10100 <4400 NA
03/15/2021 15,200 29400 2260 17000 <106 816 NA <76.8 <122 <100 <88.2 NA 779 <91.8 220 <88.8 <77.0 <18000 527J 102J NA NA <990 <85.0 79.0J 2710 789 <9100 <6700 <665
03/17/2021 2,840 6,020 442 5,880 51.1 520 NA <15.4 <24.5 <20.0 <17.6 NA 240 <17.4 65.5 <17.8 <15.4 <3610 228J 27.9 NA NA NA <17.0 1370 1370 588 4960J <1340 <133
04/02/2021 15,300 28,400 2,220 15,000 <84.4 990 NA <61.4 <98.0 <80.0 <70.6 NA 673 <69.6 195 <71.0 <61.6 <14400 NA 106 NA NA NA <68.0 75.4J 2730 <66.4 <7280 <5360 <532
4/14/1998 6 2 1 4 ND NS ----NS ------ND --NS --ND ----NS NS NS --NS --NS NS NA NA NA
6/12/2003 ND ND ND ND ND ND ----NS ------ND --ND --ND ----ND NS ND --NS --ND ND NA NA NA
3/8/2004 ND ND ND ND ND ND ----NS ------ND --ND --ND ----ND NS ND --NS --ND ND NA NA NA
12/1/2005 ND ND ND ND ND ND ----ND ------<0.5 --<0.5 --ND ----ND ND ND --ND --ND ND NA NA NA
9/10/2008 <0.5 0.58 <0.5 <1 <0.50 <2 ----<0.5 ------<0.5 --<0.5 --<0.5 ----<0.5 <0.5 <0.5 --<0.5 --<0.5 <0.5 NA NA NA
6/17/2009 <1 <5 <1 <3 <1 <5 ----<1 ------<1 --<1 --<1 ----<1 <1 <1 --<1 --<1 <1 NA NA NA
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 <0.080 <0.24 --<0.050 --<0.11 <0.050 <0.070 --<0.080 <42 --<0.10 <0.14 <0.090 <0.090 <0.14 <0.50 <0.14 <0.080 NA NA NA
6/14/2010 <0.054 <0.057 <0.054 <0.174 <0.056 <0.094 <1.5 <0.031 <0.059 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --<0.034 <42 <0.11 <0.034 --<0.059 <0.83 --<0.034 <0.038 <0.038 NA NA NA
9/15/2011 <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --<0.034 <42 <0.11 <0.034 --<0.059 <0.83 --<0.034 <0.038 <0.038 NA NA NA
6/13/2012 <0.054 <0.057 <0.054 <0.17 <0.056 <0.094 <1.5 <0.031 <0.059 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --<0.034 <42 <0.11 <0.034 --<0.059 <0.83 --<0.034 <0.038 <0.038 NA NA NA
2/24/2014 <0.50 <0.50 <0.50 <1.5 <0.50 <2.0 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA <0.50 NA <0.50 NA NA <0.50 <0.50 <0.50 NA NA NA
10/3/2015 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA <0.50 NA <0.50 NA NA <0.50 <0.50 <0.50 NA NA NA
11/7/2017 <0.50 <0.5 <0.50 <1.5 <0.50 <0.50 <50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 NA <5.0 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <0.50 <0.50 NA NA NA
6/6/2019 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <0.13 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13 <0.13 <65 <1.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NA NA NA
2/13/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.25 <0.35 <0.42 <0.23 <0.24 <0.26 <0.18 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 <40.5 <17.6 NA
Not Sampled - LNAPL
Not Sampled - LNAPL
MW-3
MW-4
Not Sampled - LNAPL
Not Sampled - LNAPL
Not Sampled - LNAPL
Not Sampled - LNAPL
Not Sampled - LNAPL
Page 2 of 5
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-Dichloroethane1,2-DichloropropaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Butyl Alcoholtert-Amylmethyl ether1 600 600 500 20 6 6,000 0.6 70 70 70 3 0.02 6 0.40 0.60 70 4,000 40 70 25 100 4,000 70 70 400 400 40 10 128
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 8,500 70,000 3,000 50 6,000 400 600 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 40,000 10,000 12800
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
2425 US HIGHWAY 21
WILLIAMS GROCERY
2L Standard
GCL Standard
NCDEQ INCIDENT #15063
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 8
4/14/1998 2,200 1,200 120 820 ND NS ----NS ------ND --NS --ND ----NS NS ----NS --NS NS NA NA NA
6/12/2003 3,200 700 190 1,220 ND ND ----NS ------ND --ND --ND ----ND NS ----NS --170 62 NA NA NA
3/8/2004 140 5 7.1 68 ND ND ----NS ------ND --ND --ND ----ND NS ----NS --9.4 2.7 NA NA NA
12/1/2005 200 2.6 5.4 98 3.5 5.1 ----ND ------<0.5 --<0.5 --4 ----0.7 ND ----ND --16 4.5 NA NA NA
9/10/2008 520 3.6 3 155.8 8.2 6.6 ----<5 ------<0.5 --<0.5 --5.1 ----1.1 <0.5 ----<0.5 --30 9.9 NA NA NA
6/17/2009 2,900 <500 110 1,140 <100 <500 ----<100 ------<1 --<1 --<100 ----<100 <100 ----<100 --220 <100 NA NA NA
11/30/2009 3,300 58 150 1,570 60 <9.2 <25 <3.2 <9.6 --<0.050 --<0.11 <0.050 <0.070 --22 <1,700 <7.6 <4 <5.6 <5 <36 <5.6 <2 290 54 NA NA NA
6/14/2010 42 <0.057 <0.057 8.2 3.4 1.7 <1.5 <0.031 <0.059 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --0.63 <42 <0.11 <0.034 --<0.048 <0.83 --<0.034 1.5 0.59 NA NA NA
9/15/2011 110 <0.057 1 19.3 1.8 2.1 <1.5 <0.031 <0.059 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --0.72 <42 <0.11 <0.034 <0.059 <0.043 <0.83 <0.059 <0.034 5.9 1.60 NA NA NA
6/13/2012 370 2 7.8 75 7.5 2.2 <1.5 <0.031 1.5 <0.054 <0.053 <0.032 <0.041 <0.038 <0.054 --2.2 <42 <0.11 <0.034 <0.059 <0.043 <0.83 <0.059 <0.034 15 5.9 NA NA NA
2/24/2014 <0.50 <0.50 <0.50 <1.5 <0.50 <2.0 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA <0.50 NA NA NA NA <0.50 <0.50 <0.50 NA NA NA
10/3/2015 0.56 <0.50 <0.50 <1.0 1.8 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 NA NA <0.50 NA NA NA NA <0.50 <0.50 <0.50 NA NA NA
11/7/2017 0.78 <0.5 <0.50 <1.5 <0.50 <0.50 <50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 NA <5.0 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <0.50 <0.50 NA NA NA
6/6/2019 <0.13 0.51 <0.13 <0.25 <0.13 0.16 J <2.0 <0.13 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13 <0.13 <65 <1.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 0.17 J <0.13 NA NA NA
2/13/2020 50.3 <0.23 <0.24 4.0 3.9 0.78J NA <0.18 <0.35 <0.25 <0.35 <0.42 <0.23 <0.24 15.1 <0.18 0.68 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 137 <17.6 NA
04/02/2021 4.5 12.6 2.1 17.9 <0.42 1.6J NA <0.31 0.76 <0.40 <0.35 NA <0.27 <0.35 <0.32 <0.36 <0.31 <72.2 NA <0.33 NA NA NA <0.34 <0.29 9.9 3.5 <36.4 <26.8 <2.7
4/14/1998 ND ND ND ND ND NS ----NS ------ND --NS --ND ----NS NS ----NS --NS NS NA NA NA
6/12/2003 ND ND ND ND ND ND ----NS ------ND --ND --ND ----ND NS ----ND --ND ND NA NA NA
3/8/2004 1.1 ND ND ND ND ND ----NS ------ND --ND --ND ----ND NS ----ND --ND ND NA NA NA
12/1/2005 ND ND ND ND ND ND ----ND ------<0.5 --<0.5 --ND ----ND ND ----ND --ND ND NA NA NA
9/10/2008 <0.5 <0.5 <0.5 <1 <0.5 <2 ----<0.5 ------<0.5 --<0.5 --<0.5 ----<0.5 <0.5 ----<0.5 --<0.5 <0.5 NA NA NA
6/17/2009 <1 <5 <1 <3 <1 <5 ----<1 ------<1 --<1 --<1 ----<1 <1 ----<1 --<1 <1 NA NA NA
11/30/2009 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 <0.080 <0.24 --<0.050 --<0.11 <0.050 <0.070 --<0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA NA NA
6/13/2012 <0.040 <0.060 <0.090 <0.19 <0.11 <0.23 <0.62 <0.080 <0.24 --<0.050 --<0.11 <0.050 <0.07 --<0.080 <42 <0.19 <0.10 <0.14 <0.13 <0.90 <0.090 <0.050 <0.14 <0.080 NA NA NA
2/24/2014 <0.50 <0.50 <0.50 <1.5 <0.50 ND NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 --<0.50 <0.50 NA NA <0.50 <0.50 NA NA <2.0 <0.50 <0.50 NA NA NA
10/3/2015 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 <0.50 <0.50 --<0.50 NA NA <0.50 NA NA NA <0.50 <0.50 <0.50 <0.50 NA NA NA
11/7/2017 <0.50 <0.5 <0.50 <1.5 <0.50 <0.50 <50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 NA <5.0 <0.50 <0.50 <5.0 <5.0 <0.50 <0.50 <0.50 <0.50 NA NA NA
6/6/2019 <0.13 0.23 J <0.13 <0.25 <0.13 <0.13 <2.0 <0.13 <0.13 <0.13 <0.13 <0.20 <0.13 <0.13 <0.13 <0.13 <0.13 <65 <1.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NA NA NA
2/13/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.25 <0.35 <0.42 <0.23 <0.24 <0.26 <0.18 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 <40.5 <17.6 NA
4/14/1998 ND ND ND ND ND ND ----NS ------ND --NS --ND ----NS NS --------NS NS NA NA NA
6/12/2003 ND ND ND ND ND ND ----NS ------ND --ND --ND ----ND ND ----ND --ND ND NA NA NA
3/8/2004 1.40 ND ND 9.6 ND ND ----NS ------ND --ND --ND ----ND ND ----ND --1.6 ND NA NA NA
12/1/2005
9/10/2008
6/17/2009
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
MW-7
MW-5
MW-6
Page 3 of 5
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-Dichloroethane1,2-DichloropropaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Butyl Alcoholtert-Amylmethyl ether1 600 600 500 20 6 6,000 0.6 70 70 70 3 0.02 6 0.40 0.60 70 4,000 40 70 25 100 4,000 70 70 400 400 40 10 128
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 8,500 70,000 3,000 50 6,000 400 600 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 40,000 10,000 12800
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
2425 US HIGHWAY 21
WILLIAMS GROCERY
2L Standard
GCL Standard
NCDEQ INCIDENT #15063
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 8
4/14/1998 240 2 ND 24 ND NS ----NS ------ND --NS --ND ----NS NS ----NS --NS NS NA NA NA
6/12/2003 2,300 ND ND 310 ND ND ----NS ------ND --ND --ND ----ND NS ----ND --ND ND NA NA NA
3/8/2004 1,200 ND ND 160 ND ND ----NS ------ND --140 --ND ----ND NS ----ND --ND ND NA NA NA
12/1/2005 1,600 1.9 ND ND 28 54 ----ND ------<0.5 --140 --14 ----6.6 ND ----ND --ND 4.8 NA NA NA
9/10/2008 1,130 1 <0.5 76 34 65.3 ----1.8 ------<0.5 --116 --10 ----8 3.2 ----<0.5 --<0.5 3.2 NA NA NA
6/17/2009 610 <5 <1 90 22 7.7 ----<1 ------<1 --66 --6.1 ----3.5 1.2 ----<1 --<1 1.4 NA NA NA
11/30/2009 890 0.6 <0.90 161.3 30 44 <6.2 <0.80 <2.4 --<0.50 --<1.1 <0.50 77 --8.8 <420 <1.9 <1 <1.4 <1.3 <9 <0.90 <0.50 <1.4 <0.80 NA NA NA
6/14/2010 970 <0.57 <0.54 101.1 30 30 <15 <0.31 <0.59 <0.54 <0.53 <0.32 <0.41 <0.38 80 --7.3 <420 <1.1 <0.34 --<0.48 <8.3 <0.59 <0.34 <0.38 <0.38 NA NA NA
6/13/2012
11/7/2017
4/14/1998 5 ND ND 4 ND NS ----NS ------ND --NS ND ----NS NS ----NS --NS NS NA NA NA
6/12/2003
3/8/2004
12/1/2005
9/10/2008
6/17/2009
4/14/1998 ND ND ND ND ND NS ----NS ------ND --NS --ND ----NS NS ----NS --NS NS NA NA NA
6/12/2003 3.8 ND ND ND 4.1 ND ----NS ------ND --ND --ND ----ND NS ----ND --ND ND NA NA NA
3/8/2004 ND ND ND ND ND ND ----ND ------ND --ND --ND ----ND ND ----ND --ND ND NA NA NA
12/1/2005 ND ND ND ND ND ND ----ND ------<0.5 --<0.5 --ND ----ND ND ----ND --ND ND NA NA NA
9/10/2008
6/17/2009
4/14/1998 ND ND ND ND ND NS ----NS ------0.07 --NS --ND ----NS NS ----NS --NS NS NA NA NA
6/12/2003
3/8/2004
12/1/2005
9/10/2008
6/17/2009
2/13/2020 <0.24 <0.23 <0.24 <0.50 <0.44 <0.66 NA <0.18 <0.35 <0.25 <0.35 <0.42 <0.23 <0.24 <0.26 <0.18 <0.33 <98.9 NA <0.24 NA NA NA <0.24 <0.26 <0.19 <0.23 <40.5 <17.6 NA
04/02/2021 <0.34 <0.48 <0.30 <0.34 <0.42 <0.64 NA <0.31 <0.49 <0.40 <0.35 <0.27 <0.35 <0.32 <0.36 <0.31 <72.2 NA <0.33 NA NA NA <0.34 <0.29 <0.50 <0.33 <36.4 <26.8 <2.7
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
MW-10
MW-11
MW-9
MW-8
Not Sampled - Could Not Locate
MW-12
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Not Sampled - Could Not Locate
Page 4 of 5
Well ID Sample
Date
BenzeneTolueneEthylbenzeneTotal XylenesMethyl Tertiary Butyl EtherNaphthaleneAcetoneBromodichloromethanen-Butylbenzenesec-ButylbenzeneChloroformChloromethane1,2-Dibromoethane1,1-Dichloroethane1,2-Dichloroethane1,2-DichloropropaneDiisopropyl EtherEthanol2-HexanoneIsopropylbenzenep-Isopropyltoluene4-Methyl-2-pentanone (MIBK)Methyl Ethyl Ketonen-PropylbenzeneStyrene1,2,4-Trimethylbenzene1,3,5-Trimethylbenzenetert-Amyl Alcoholtert-Butyl Alcoholtert-Amylmethyl ether1 600 600 500 20 6 6,000 0.6 70 70 70 3 0.02 6 0.40 0.60 70 4,000 40 70 25 100 4,000 70 70 400 400 40 10 128
5,000 260,000 84,500 85,500 20,000 6,000 6,000,000 NE 6,900 8,500 70,000 3,000 50 6,000 400 600 70,000 4,000,000 40,000 25,000 11,700 100,000 4,000,000 30,000 70,000 28,500 25,000 40,000 10,000 12800
HAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINA
2425 US HIGHWAY 21
WILLIAMS GROCERY
2L Standard
GCL Standard
NCDEQ INCIDENT #15063
HISTORICAL GROUNDWATER ANALYTICAL RESULTS
TABLE 8
6/14/2010 31,000 46,000 3,500 16,800 23,000 1,300 2,400 <1.2 110 42 <2.1 <1.3 860 <1.5 <1.5 --560 <1,700 --200 --<1.9 2,900 1,300 150 4,000 1,200 NA NA NA
6/13/2012
2/24/2014 30,200 47,100 3,350 12,900 7,980 1,040 NA <50.0 <50.0 <50.0 <50.0 <100.0 998 <50.0 <50.0 --590 NA NA 118 NA NA NA 1,040 202 2,900 653 NA NA NA
10/3/2015
11/7/2017 69 9.5 2.2 37.4 27 4.3 J <50 <0.50 0.24 J <0.50 <0.50 <2.0 0.73 <0.50 23 0.96 6.0 NA <5.0 0.16 J <0.50 <5.0 <5.0 0.24 J <0.50 23 1.7 NA NA NA
5/6/2019 27,800 69,100 4,170 22,000 855 841 <10,000 <500 <500 <500 <500 <500 747 <500 811 <500 295 J NA <5,000 148 J <500 <2,500 <2,500 441 J <500 3,580 1,050 NA NA NA
6/6/2019 26,300 48,800 3,860 21,500 1,010 758 <2,000 <130 <130 <130 <130 <200 695 <130 790 <130 347 J <65,000 <1,000 175 J <130 <1,300 <1,300 487 J <130 3,550 1,050 NA NA NA
2/13/2020 1,200 202 28.5 161 57.9 20.1 NA <1.8 <3.5 <2.5 <3.5 <4.2 <2.3 <2.4 74.9 <1.8 28.7 <989 NA <2.4 NA NA NA 2.5J <2.6 16.8 9.4 2210 <176 NA
03/15/2021 17,000 39,600 4,920 24,400 252 2,580 NA <61.4 <98.0 <80.0 <70.6 NA 515 <73.4 337 <71.0 103 <14400 <95.2 396 NA NA <792 <68.0 117 12100 3100 <7280 <5360 <532
03/17/2021 15,400 41,400 3,800 21,400 717 1,210 NA <76.8 <122 <100 <88.2 NA 550 <87.0 408 <88.8 142 <18000 <119 188 NA NA NA <85.0 4870 4870 1330 <9100 <6700 <665
4/2/2021
AS-1 04/02/2021 11.1 5.2 1.0 20.7 24.4 2.3 NA <0.31 <0.49 <0.40 <0.35 NA 0.74 <0.35 24.9 0.49J 10 <72.2 NA <0.33 NA NA NA <0.34 <0.29 1.2 <0.33 2070 101 8.0J
Notes:
"<" or ND = Not Detected at or above the laboratory detection or reporting limit
Concentrations are reported in micrograms per liter (µg/L)
Italicized values indicate levels above GCLs
J = Estimated value below method reporting limit
NA = Not Analyzed
GCL = Gross Contamination Level
Concentrations in bold print equal or exceed the 15A NCAC 2L .0202 Groundwater Qualtiy Standard (2L Standard).
RW-1
Not Sampled - LNAPL
Not Sampled - LNAPL
Not Sampled - LNAPL
Page 5 of 5

FIGURES
SITE
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
REFERENCE: USGS 7.5-MINUTE MAP, BROOKS CROSSROADS,
NORTH CAROLINA. DATED 2016
LATITUDE:ƒ1257+
LONGITUDE:ƒ:(67
MW-1
RW-1
MW-3
MW-2
MW-5
MW-6
FORMER USTs
FORMER USTs
RESIDENCE
FORMER
RESIDENCE
APARTMENTS
FORMER
WILLIAMS
GROCERY US H
IGHWAY

2
1
PETTY ROAD
HAM
P
T
O
N
VI
L
L
E
R
O
A
D
AS-1
MW-4
MW-12
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
ASSOCIATES OF NORTH CAROLINA, P.C.
C:\Users\robert.deppensmith\Desktop\CAD REFERENCES\ATC Logo_Full Color_CMYK.jpg
EXPLANATION
MONITORING WELL LOCATION
AIR SPARGE WELL LOCATION
500'1,000'
WSW-8 WSW-6
WSW-7
WSW-9
WSW-10
WSW-1
WSW-3WSW-5
WSW-2 WSW-4WSW-18
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
EXPLANATION
WATER SUPPLY WELL LOCATION
IMAGE SOURCE: NC GEOSPATIAL DATABASE (2018)
3
LB NF 02/28/2021 SLP1506303
MW-1
RW-1
MW-3
MW-2
MW-5
MW-6
FORMER USTs
FORMER USTs
RESIDENCE
FORMER
RESIDENCE
APARTMENTS
FORMER
WILLIAMS
GROCERY US
H
IGHW
A
Y

2
1
PETTY ROAD
HAM
P
T
O
N
VI
L
L
E
R
O
A
D
AS-1
MW-4
MW-12
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
ASSOCIATES OF NORTH CAROLINA, P.C.
C:\Users\robert.deppensmith\Desktop\CAD REFERENCES\ATC Logo_Full Color_CMYK.jpg
480.09
479.24
480.14
479.49
480.07
480.00
EXPLANATION
MONITORING WELL LOCATION
GROUNDWATER FLOW DIRECTION
GROUNDWATER CONTOUR LINE
GROUNDWATER ELEVATION (AT WELL)478.50
Notes:
1.Groundwater levels measured 04/02/20.
2.Dashed lines indicate areas of less certainty.
AIR SPARGE WELL LOCATION480.2480.0479.8479.6479.4480.4
480.47
480.22
MW-1
RW-1
MW-3
MW-2
MW-5
MW-6
RESIDENCE
FORMER
RESIDENCE
FORMER
WILLIAMS
GROCERY US
H
IGHW
A
Y

2
1
HAM
P
T
O
N
VI
L
L
E
R
O
A
D
AS-1
MW-4
MW-12
CAD FILE PREP. BYTYPE CODE REV. BY SCALE PROJECT NO.
TITLE
DATE
ASSOCIATES OF NORTH CAROLINA, P.C.
C:\Users\robert.deppensmith\Desktop\CAD REFERENCES\ATC Logo_Full Color_CMYK.jpg
EXPLANATION
MONITORING WELL LOCATION
Notes:
1.Groundwater samples collected on the date
noted
2.Italicized values exceed the Gross
Contamination Levels.
3.Concentrations exceeding the 2L Standards
are shown.
AIR SPARGE WELL LOCATION

APPENDIX A

MMPE SUBCONTRACTOR REPORT & WASTE DISPOSAL MANIFEST

ADVANCED
ENVIRONMENTAL SERVICES, INC.
“Your Environmental Solutions Partner”

MOBILE
MULTI-PHASE
EXTRACTION REPORT

Site Location:

Williams Grocery
2425 US Highway21
Hamptonville, North Carolina

Prepared for:

ATC Group Services
7606 Whiteville Executive Center Drive, Suite 800
Charlotte, North Carolina 28273
PM – Ms. Noelle France

April 7, 2021

TABLE OF CONTENTS

EVENT SUMMARY

MMPE FIELD LOG

MASS-REMOVAL CALCULATION

FIELD NOTES

DISPOSAL MANIFEST

MOBILE MULTI-PHASE EXTRACTION
EVENT SUMMARY

April 7, 2021

Location: Williams Grocery
2425 US Highway 21
Hamptonville, North Carolina

Client: ATC Group Services
7606 Whiteville Executive Center Drive, Suite 800
Charlotte, North Carolina 28273

Event Dates: March 15 - 19, 2021
Advanced Job # 03 – 2116

Advanced Personnel: Lee Heilig and Jonathan Kerr

MMPE System: MMPE system rated 21”hg at 130 CFM
4’ discharge stack - 2” diameter
6,000 - gallon tanker
Approximately 150’of 1.5” hose to 3 wells

Extraction Well: MW-1, MW-3 and RW-1
Air-Sparge: AS-1

Well Initial FP/WL(ft) Final FP/WL(ft) Stinger depth(ft) Run Time
MW-1 18.80 23.69 19 95.25 hours
MW-3 19.41 21.01 20 96.00 hours
RW-1 19.45 20.52 20 94.25 hours
AS-1 19.65 29.28 NA 36.00 hours

Description of Event:
The MMPE event ran from 11:45 March 15, through 11:45 March 19, 2021. The MMPE system
was active for 96.0 hours. During the event vacuum at the recovery pump ranged from 14.0 to
18.0 inches of mercury (hg) and stabilized at approximately 15.0 inches of mercury. Airflow
rates ranged from 2,500 to 3,100 feet per minute and stabilized at 3,100 feet per minute. Due to
excessive water recovery, flow was reduced 50 percent. System temperature ranged from 68.0 –
104.0 degrees (F) and humidity maintained 99.0 percent. Field gauged volatile organic
compounds (VOC’s) decreased from 30,000 parts per-million (PPM) to 14,000 PPM
throughout the event. Air Sparge operated 12 hours on 12 hours off for a total of 36.0 hours

Groundwater / Product Mix Recovered:
During the event, a total of 9,578 gallons of product/water mix were removed from the site and
properly disposed at a certified North Carolina disposal facility. Total fluids recovered, was
measured based on stick readings conducted during and following the event. Based on 96.0 hours
of operation and a total of 9,578 gallons recovered, the average groundwater recovery rate was
calculated to be approximately 99.77 gallons per hour.

Events Results:
Based on mass-removal calculations 287.51 pounds or 46.73 gallons of VOC’s were removed as
vapor. Using Dwyer Magnehelic gauges, vacuum influence (inches of water) was measured at
monitoring points MW-2 and MW-4. No measurable vacuum influence was observed at any
monitoring point. Draw-down was observed in MW-4 at 0.19 feet. Following the event, no
free product was identified in any well.

MMPE FIELD LOG:
CLIENT: ATC
JOB NAME: Williams Grocery
LOCATION: Hamptonville, NC
MMPE EVENT DATES: March 15 - 19, 2021
EXTRACTION POINTS: MW-1, MW-3, RW-1 and Air-Sparge AS-1
AES JOB NUMBER: 03 - 2116
DATE TIME FLOW (f/m) HUM.(%) TEMP. (F)VOC's(ppm)VAC. (hg")GALLONS STINGER/WL's EXTRACTION POINTS (hg")
MW-3 RW-1 MW-1
Stinger(ft)20 20 19
Start 11:45 Initial WL's 19.41 19.45 18.80
03/15/21 12:00 2,500 99.0 68 10,000 18.0 13.0 off-line off-line
13:25 3,000 99.0 87 30,000 15.0 9.0 8.0 9.0
14:40 3,000 99.0 89 30,000 15.0 9.0 4.0 9.0
15:50 3,000 99.0 97 28,000 15.0 516 gal.9.0 4.0 4.0
03/16/21 8:45 3,000 99.0 98 26,000 15.0 2,188 gal.4.0 4.0 4.0
10:45 3,000 99.0 94 28,000 15.0 4.0 4.0 4.0
12:45 3,000 99.0 96 26,000 15.0 4.0 4.0 4.0
15:00 3,000 99.0 97 26,000 15.0 4.0 4.0 4.0
03/17/21 9:00 3,000 99.0 94 22,000 15.0 3,984 gal.4.0 4.0 4.0
11:00 3,100 99.0 90 22,000 14.0 6.0 7.0 7.0
13:00 3,100 99.0 94 20,000 14.0 6.0 7.0 7.0
15:00 3,100 99.0 96 18,000 14.0 p/o 4,824 6.0 7.0 7.0
03/18/21 7:50 3,100 99.0 104 20,000 15.0 1,789 gal.6.0 7.0 7.0
9:30 3,100 99.0 100 18,000 15.0 6.0 7.0 7.0
11:00 3,100 99.0 98 16,000 15.0 6.0 7.0 7.0
13:00 3,100 99.0 102 18,000 15.0 6.0 7.0 7.0
03/19/21 8:45 3,100 99.0 88 16,000 15.0 4,289 gal.6.0 7.0 7.0
10:30 3,100 99.0 84 14,000 15.0 6.0 7.0 7.0
Final WL's 21.01 20.52 23.69
End 11:45 Total fluids: 9,578 gal.
Total free product:0.0
DATE TIME STINGER/WL's AIR-SPARGE POINTS VACUUM INFLUENCE (h2o") WELL GAUGING (ft)
AS-1 MW-2 MW-4 MW-2 MW-4
Start 11:45 Stinger(ft)n/a
Initial WL's 19.65 18.82 19.21
03/15/21 14:40 0.00 0.00
03/16/21 10:45 4.0
12:45 3.5 0.00 0.00 18.79 19.11
15:00 4.0
03/17/21 9:00 off-line
11:00 4.0
13:00 4.0
15:00 4.0 0.00 0.00 18.78 19.08
03/18/21 7:50 off-line
9:30 4.0
11:00 4.0 0.00 0.00 18.41 19.31
13:00 4.0
03/19/21 8:45 off-line 0.00 0.00 18.23 19.40
10:30 4.0
Final WL's 29.28
End 11:45
Page 1 of 1
MOBILE MULTI-PHASE EXTRACTION EVENT
SITE NAME: WILLIAMS GROCERY CLIENT: ATC ASSOCIATES
INCIDENT NUMBER:
AVERAGE DEPTH TO GROUNDWATER: 18 - 20 ft.
DESCRIBE SOIL IN THE SATURATED ZONE:
AVERAGE HYDRAULIC CONDUCTIVITY (if known):
EXTRACTION WELLS USED FOR MMPE: MW-3, RW-1 and MW-1 AIR-SPARGE AS-1
SPECIFICATIONS OF THE MMPE SYSTEM (cfm @ in Hg): 130 cfm @ 21.0"Hg
DRY STANDARD CUBIC FEET PER MINUTE (DSCFM) AIR FLOW CALCULATIONS (Qstd)
Date Hours Vacuum Velocity Pipe ID Temp Rel Humid Water Water Qstd
(inches of Hg)(ft/min)(in)(°F)(%)Vapor (Wt%)Vapor (Vol%)(flow)
3/15/21 24.00 16.00 2875.00 2 85 99.0 0.022 0.034 59
3/16/21 48.00 15.00 3000.00 2 96 99.0 0.035 0.053 59
3/17/21 72.00 14.00 3075.00 2 94 99.0 0.048 0.071 59
3/18/21 96.00 15.00 3100.00 2 96 99.0 0.048 0.071 60
3/19/21
NOTES
Qstd = Flow at DSCFM
Vacuum = The level of vacuum being applied should be recorded from the MMPE system (inches of Hg)
Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube)
Pipe ID = The inside diameter of the blower discharge piping (from the MMPE system)
Temperature = The temperature of the air stream exiting the blower discharge piping (dry bulb temp., in deg.°F)
Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping
Bwsw = water vapor % by weight, i.e., pounds of water per pound of dry air, derived from the Psychrometric chart (temp Vs relative humidity)
Bws = water vapor % by volume
EQUATIONS
Bws = (Bwsw/18 lb-mole H20)/[(1/28.84 lb-mole dry air) + (Bwsw/18 lb-mole H2O)]
Qstd = (1-Water Vapor) * velocity * (PI * (diameter/24)2) * (528°R/(Temp + 460))
EMISSION CALCULATIONS
Elapsed
Time Flow PPMmeasured PPMwet PPMdry K PPMconc Cc:m Cc PMRc PMRg PMR
(hour)(DSCFM)(ppm)(#C - gas)(mg/dsm3)(lb/dscf)(lb/hour)(lb/hour)(lb)
24 59 24500 24500 25364 1 25364 12655 0.00079008 2.78 3.22 77.29
48 59 26500 26500 27986 1 27986 13964 0.00087177 3.08 3.56 85.50
72 59 20500 20500 22077 1 22077 11015 0.00068769 2.45 2.84 68.04
96 60 17000 17000 18307 1 18307 9135 0.00057028 2.04 2.36 56.68
Total emissions in pounds 287.51
Total emissions as gallons (pounds / 6.152)46.73
NOTES
PPMmeasured = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping
PPMwet = "wet" concentration
PPMdry = "dry" concentration
K = Number of carbons in calibration gas: (Methane K = 1, or Propane K = 3, or Hexane K = 6)
PPMc= PPMv, Volumetric concentration of VOC emissions as carbon, dry basis at STP
Cc:m = mg/dsm3, mass concentration of VOC emissions as carbon
Mc = 12.01 mg/mg-mole, molecular weight of carbon
K3 = 24.07 dsm3/106 mg-mole, mass to volume conversion factor at STP
Cc = lb/dcsf, mass concentration of VOC emissions as carbon, dry basis at STP
PMRc = lb/hr, pollutant mass removal rate of VOC's as carbon
PMRg = lb/hr, pollutant mass removal rate of of VOC's as gasoline
PMR = lb, pollutant mass removal of VOC's as gasoline
EQUATIONS
PPMwet = PPMmeasured
PPMdry = (PPMwet)/(1-Bws)
PPMc = (PPMd)(K)
Cc:m = (PPMc)(Mc / K3)
Cc = (Cc:m)(62.43x10-9 lb-m3/mg-ft3)
PMRc = (Cc)(Qstd)(60 minute/hour)
PMRg = (PMRc)(Mg/Mcg)
PMR = (PMRg)(#hours)

APPENDIX B

FIELD NOTES

APPENDIX C

LABORATORY REPORT
AND
CHAIN-OF-CUSTODY DOCUMENTATION
#=CL#
March 22, 2021
LIMS USE: FR - NOELLE FRANCE
LIMS OBJECT ID: 92527693
92527693
Project:
Pace Project No.:
RE:
Noelle France
ATC Group Services LLC- South Charlotte
7606 Whitehall Exe Center Dr
Suite 800
Charlotte, NC 28273
WILLIAMS GROCERY
Dear Noelle France:
Enclosed are the analytical results for sample(s) received by the laboratory on March 15, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
[phone]
Enclosures
cc:Al Quarles, ATC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Lab ID Sample ID Matrix Date Collected Date Received
92527693001 MW-1 Water 03/15/21 12:12 03/15/21 17:25
92527693002 MW-3 Water 03/15/21 11:20 03/15/21 17:25
92527693003 RW-1 Water 03/15/21 12:45 03/15/21 17:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92527693001 MW-1 SM 6200B 72 PASI-CSAS
92527693002 MW-3 SM 6200B 72 PASI-CSAS
92527693003 RW-1 SM 6200B 72 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Sample:MW-1 Lab ID:92527693001 Collected:03/15/21 12:12 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 17000J ug/L 03/18/21 08:18 75-85-4200007280200
tert-Amylmethyl ether <532 ug/L 03/18/21 08:18 994-05-82000532200
Benzene 11100 ug/L 03/18/21 08:18 71-43-210069.0 200
Bromobenzene <58.0 ug/L 03/18/21 08:18 108-86-110058.0 200
Bromochloromethane <93.6 ug/L 03/18/21 08:18 74-97-510093.6 200
Bromodichloromethane <61.4 ug/L 03/18/21 08:18 75-27-410061.4 200
Bromoform <68.2 ug/L 03/18/21 08:18 75-25-210068.2 200
Bromomethane <332 ug/L 03/18/21 08:18 74-83-91000332200
2-Butanone (MEK)2110 ug/L 03/18/21 08:18 78-93-31000792200
tert-Butyl Alcohol 15200 ug/L 03/18/21 08:18 75-65-0100005360200
n-Butylbenzene <98.0 ug/L 03/18/21 08:18 104-51-810098.0 200
sec-Butylbenzene <80.0 ug/L 03/18/21 08:18 135-98-810080.0 200
tert-Butylbenzene <64.6 ug/L 03/18/21 08:18 98-06-610064.6 200
tert-Butyl Formate <5880 ug/L 03/18/21 08:18 762-75-4100005880200
Carbon tetrachloride <66.6 ug/L 03/18/21 08:18 56-23-510066.6 200
Chlorobenzene <56.8 ug/L 03/18/21 08:18 108-90-710056.8 200
Chloroethane <130 ug/L 03/18/21 08:18 75-00-3200130200
Chloroform <70.6 ug/L 03/18/21 08:18 67-66-310070.6 200
Chloromethane <108 ug/L 03/18/21 08:18 74-87-3200108200
2-Chlorotoluene <64.2 ug/L 03/18/21 08:18 95-49-810064.2 200
4-Chlorotoluene <64.8 ug/L 03/18/21 08:18 106-43-410064.8 200
1,2-Dibromo-3-chloropropane <68.0 ug/L 03/18/21 08:18 96-12-820068.0 200
Dibromochloromethane <71.8 ug/L 03/18/21 08:18 124-48-110071.8 200
1,2-Dibromoethane (EDB)858 ug/L 03/18/21 08:18 106-93-410054.4 200
Dibromomethane <78.8 ug/L 03/18/21 08:18 74-95-310078.8 200
1,2-Dichlorobenzene <67.8 ug/L 03/18/21 08:18 95-50-110067.8 200
1,3-Dichlorobenzene <68.0 ug/L 03/18/21 08:18 541-73-110068.0 200
1,4-Dichlorobenzene <66.6 ug/L 03/18/21 08:18 106-46-710066.6 200
Dichlorodifluoromethane <69.2 ug/L 03/18/21 08:18 75-71-810069.2 200
1,1-Dichloroethane <73.4 ug/L 03/18/21 08:18 75-34-310073.4 200
1,2-Dichloroethane 1130 ug/L 03/18/21 08:18 107-06-210064.4 200
1,1-Dichloroethene <69.6 ug/L 03/18/21 08:18 75-35-410069.6 200
cis-1,2-Dichloroethene <76.8 ug/L 03/18/21 08:18 156-59-210076.8 200
trans-1,2-Dichloroethene <79.2 ug/L 03/18/21 08:18 156-60-510079.2 200
1,2-Dichloropropane <71.0 ug/L 03/18/21 08:18 78-87-510071.0 200
1,3-Dichloropropane <56.8 ug/L 03/18/21 08:18 142-28-910056.8 200
2,2-Dichloropropane <77.6 ug/L 03/18/21 08:18 594-20-710077.6 200
1,1-Dichloropropene <85.4 ug/L 03/18/21 08:18 563-58-610085.4 200
cis-1,3-Dichloropropene <73.0 ug/L 03/18/21 08:18 10061-01-510073.0 200
trans-1,3-Dichloropropene <72.6 ug/L 03/18/21 08:18 10061-02-610072.6 200
Diisopropyl ether 200 ug/L 03/18/21 08:18 108-20-310061.6 200
Ethanol <14400 ug/L 03/18/21 08:18 64-17-54000014400200
Ethylbenzene 1670 ug/L 03/18/21 08:18 100-41-410060.8 200
Ethyl-tert-butyl ether <648 ug/L 03/18/21 08:18 637-92-32000648200
Hexachloro-1,3-butadiene <306 ug/L 03/18/21 08:18 87-68-3400306200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Sample:MW-1 Lab ID:92527693001 Collected:03/15/21 12:12 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
2-Hexanone 853J ug/L 03/18/21 08:18 591-78-6100095.2 200
Isopropylbenzene (Cumene)<66.6 ug/L 03/18/21 08:18 98-82-810066.6 200
Methylene Chloride <390 ug/L 03/18/21 08:18 75-09-2400390200
Methyl-tert-butyl ether 6700 ug/L 03/18/21 08:18 1634-04-410084.4 200
Naphthalene 815 ug/L 03/18/21 08:18 91-20-3400129200
n-Propylbenzene <68.0 ug/L 03/18/21 08:18 103-65-110068.0 200
Styrene <58.4 ug/L 03/18/21 08:18 100-42-510058.4 200
1,1,1,2-Tetrachloroethane <62.2 ug/L 03/18/21 08:18 630-20-610062.2 200
1,1,2,2-Tetrachloroethane <45.0 ug/L 03/18/21 08:18 79-34-510045.0 200
Tetrachloroethene <58.4 ug/L 03/18/21 08:18 127-18-410058.4 200
Toluene 18900 ug/L 03/18/21 08:18 108-88-310097.0 200
1,2,3-Trichlorobenzene <161 ug/L 03/18/21 08:18 87-61-6400161200
1,2,4-Trichlorobenzene <128 ug/L 03/18/21 08:18 120-82-1400128200
1,1,1-Trichloroethane <66.4 ug/L 03/18/21 08:18 71-55-610066.4 200
1,1,2-Trichloroethane <65.0 ug/L 03/18/21 08:18 79-00-510065.0 200
Trichloroethene <76.6 ug/L 03/18/21 08:18 79-01-610076.6 200
Trichlorofluoromethane <59.6 ug/L 03/18/21 08:18 75-69-420059.6 200
1,2,3-Trichloropropane <52.2 ug/L 03/18/21 08:18 96-18-410052.2 200
1,2,4-Trimethylbenzene 2670 ug/L 03/18/21 08:18 95-63-610099.0 200
1,3,5-Trimethylbenzene 773 ug/L 03/18/21 08:18 108-67-810066.4 200
Vinyl chloride <77.2 ug/L 03/18/21 08:18 75-01-420077.2 200
Xylene (Total)15700 ug/L 03/18/21 08:18 1330-20-720067.6 200
m&p-Xylene 10400 ug/L 03/18/21 08:18 179601-23-1200142200
o-Xylene 5240 ug/L 03/18/21 08:18 95-47-610067.6 200
Surrogates
1,2-Dichloroethane-d4 (S)99 %03/18/21 08:18 17060-07-070-130 200
4-Bromofluorobenzene (S)101 %03/18/21 08:18 460-00-470-130 200
Toluene-d8 (S)99 %03/18/21 08:18 2037-26-570-130 200
Sample:MW-3 Lab ID:92527693002 Collected:03/15/21 11:20 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <9100 ug/L 03/18/21 08:54 75-85-4250009100250
tert-Amylmethyl ether <665 ug/L 03/18/21 08:54 994-05-82500665250
Benzene 15200 ug/L 03/18/21 08:54 71-43-212586.2 250
Bromobenzene <72.5 ug/L 03/18/21 08:54 108-86-112572.5 250
Bromochloromethane <117 ug/L 03/18/21 08:54 74-97-5125117250
Bromodichloromethane <76.8 ug/L 03/18/21 08:54 75-27-412576.8 250
Bromoform <85.2 ug/L 03/18/21 08:54 75-25-212585.2 250
Bromomethane <415 ug/L 03/18/21 08:54 74-83-91250415250
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
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Huntersville, NC 28078
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Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Sample:MW-3 Lab ID:92527693002 Collected:03/15/21 11:20 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
2-Butanone (MEK)<990 ug/L 03/18/21 08:54 78-93-31250990250
tert-Butyl Alcohol <6700 ug/L 03/18/21 08:54 75-65-0125006700250
n-Butylbenzene <122 ug/L 03/18/21 08:54 104-51-8125122250
sec-Butylbenzene <100 ug/L 03/18/21 08:54 135-98-8125100250
tert-Butylbenzene <80.8 ug/L 03/18/21 08:54 98-06-612580.8 250
tert-Butyl Formate <7350 ug/L 03/18/21 08:54 762-75-4125007350250
Carbon tetrachloride <83.2 ug/L 03/18/21 08:54 56-23-512583.2 250
Chlorobenzene <71.0 ug/L 03/18/21 08:54 108-90-712571.0 250
Chloroethane <162 ug/L 03/18/21 08:54 75-00-3250162250
Chloroform <88.2 ug/L 03/18/21 08:54 67-66-312588.2 250
Chloromethane <135 ug/L 03/18/21 08:54 74-87-3250135250
2-Chlorotoluene <80.2 ug/L 03/18/21 08:54 95-49-812580.2 250
4-Chlorotoluene <81.0 ug/L 03/18/21 08:54 106-43-412581.0 250
1,2-Dibromo-3-chloropropane <85.0 ug/L 03/18/21 08:54 96-12-825085.0 250
Dibromochloromethane <89.8 ug/L 03/18/21 08:54 124-48-112589.8 250
1,2-Dibromoethane (EDB)779 ug/L 03/18/21 08:54 106-93-412568.0 250
Dibromomethane <98.5 ug/L 03/18/21 08:54 74-95-312598.5 250
1,2-Dichlorobenzene <84.8 ug/L 03/18/21 08:54 95-50-112584.8 250
1,3-Dichlorobenzene <85.0 ug/L 03/18/21 08:54 541-73-112585.0 250
1,4-Dichlorobenzene <83.2 ug/L 03/18/21 08:54 106-46-712583.2 250
Dichlorodifluoromethane <86.5 ug/L 03/18/21 08:54 75-71-812586.5 250
1,1-Dichloroethane <91.8 ug/L 03/18/21 08:54 75-34-312591.8 250
1,2-Dichloroethane 220 ug/L 03/18/21 08:54 107-06-212580.5 250
1,1-Dichloroethene <87.0 ug/L 03/18/21 08:54 75-35-412587.0 250
cis-1,2-Dichloroethene <96.0 ug/L 03/18/21 08:54 156-59-212596.0 250
trans-1,2-Dichloroethene <99.0 ug/L 03/18/21 08:54 156-60-512599.0 250
1,2-Dichloropropane <88.8 ug/L 03/18/21 08:54 78-87-512588.8 250
1,3-Dichloropropane <71.0 ug/L 03/18/21 08:54 142-28-912571.0 250
2,2-Dichloropropane <97.0 ug/L 03/18/21 08:54 594-20-712597.0 250
1,1-Dichloropropene <107 ug/L 03/18/21 08:54 563-58-6125107250
cis-1,3-Dichloropropene <91.2 ug/L 03/18/21 08:54 10061-01-512591.2 250
trans-1,3-Dichloropropene <90.8 ug/L 03/18/21 08:54 10061-02-612590.8 250
Diisopropyl ether <77.0 ug/L 03/18/21 08:54 108-20-312577.0 250
Ethanol <18000 ug/L 03/18/21 08:54 64-17-55000018000250
Ethylbenzene 2260 ug/L 03/18/21 08:54 100-41-412576.0 250
Ethyl-tert-butyl ether <810 ug/L 03/18/21 08:54 637-92-32500810250
Hexachloro-1,3-butadiene <382 ug/L 03/18/21 08:54 87-68-3500382250
2-Hexanone 527J ug/L 03/18/21 08:54 591-78-61250119250
Isopropylbenzene (Cumene)102J ug/L 03/18/21 08:54 98-82-812583.2 250
Methylene Chloride <488 ug/L 03/18/21 08:54 75-09-2500488250
Methyl-tert-butyl ether <106 ug/L 03/18/21 08:54 1634-04-4125106250
Naphthalene 816 ug/L 03/18/21 08:54 91-20-3500161250
n-Propylbenzene <85.0 ug/L 03/18/21 08:54 103-65-112585.0 250
Styrene 79.0J ug/L 03/18/21 08:54 100-42-512573.0 250
1,1,1,2-Tetrachloroethane <77.8 ug/L 03/18/21 08:54 630-20-612577.8 250
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Sample:MW-3 Lab ID:92527693002 Collected:03/15/21 11:20 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane <56.2 ug/L 03/18/21 08:54 79-34-512556.2 250
Tetrachloroethene <73.0 ug/L 03/18/21 08:54 127-18-412573.0 250
Toluene 29400 ug/L 03/18/21 08:54 108-88-3125121250
1,2,3-Trichlorobenzene <202 ug/L 03/18/21 08:54 87-61-6500202250
1,2,4-Trichlorobenzene <160 ug/L 03/18/21 08:54 120-82-1500160250
1,1,1-Trichloroethane <83.0 ug/L 03/18/21 08:54 71-55-612583.0 250
1,1,2-Trichloroethane <81.2 ug/L 03/18/21 08:54 79-00-512581.2 250
Trichloroethene <95.8 ug/L 03/18/21 08:54 79-01-612595.8 250
Trichlorofluoromethane <74.5 ug/L 03/18/21 08:54 75-69-425074.5 250
1,2,3-Trichloropropane <65.2 ug/L 03/18/21 08:54 96-18-412565.2 250
1,2,4-Trimethylbenzene 2710 ug/L 03/18/21 08:54 95-63-6125124250
1,3,5-Trimethylbenzene 789 ug/L 03/18/21 08:54 108-67-812583.0 250
Vinyl chloride <96.5 ug/L 03/18/21 08:54 75-01-425096.5 250
Xylene (Total)17000 ug/L 03/18/21 08:54 1330-20-725084.5 250
m&p-Xylene 11100 ug/L 03/18/21 08:54 179601-23-1250177250
o-Xylene 5900 ug/L 03/18/21 08:54 95-47-612584.5 250
Surrogates
1,2-Dichloroethane-d4 (S)100 %03/18/21 08:54 17060-07-070-130 250
4-Bromofluorobenzene (S)101 %03/18/21 08:54 460-00-470-130 250
Toluene-d8 (S)99 %03/18/21 08:54 2037-26-570-130 250
Sample:RW-1 Lab ID:92527693003 Collected:03/15/21 12:45 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7280 ug/L 03/19/21 05:39 75-85-4200007280200
tert-Amylmethyl ether <532 ug/L 03/19/21 05:39 994-05-82000532200
Benzene 17000 ug/L 03/19/21 05:39 71-43-210069.0 200
Bromobenzene <58.0 ug/L 03/19/21 05:39 108-86-110058.0 200
Bromochloromethane <93.6 ug/L 03/19/21 05:39 74-97-510093.6 200
Bromodichloromethane <61.4 ug/L 03/19/21 05:39 75-27-410061.4 200
Bromoform <68.2 ug/L 03/19/21 05:39 75-25-210068.2 200
Bromomethane <332 ug/L 03/19/21 05:39 74-83-91000332200
2-Butanone (MEK)<792 ug/L 03/19/21 05:39 78-93-31000792200
tert-Butyl Alcohol <5360 ug/L 03/19/21 05:39 75-65-0100005360200
n-Butylbenzene <98.0 ug/L 03/19/21 05:39 104-51-810098.0 200
sec-Butylbenzene <80.0 ug/L 03/19/21 05:39 135-98-810080.0 200
tert-Butylbenzene <64.6 ug/L 03/19/21 05:39 98-06-610064.6 200
tert-Butyl Formate <5880 ug/L 03/19/21 05:39 762-75-4100005880200
Carbon tetrachloride <66.6 ug/L 03/19/21 05:39 56-23-510066.6 200
Chlorobenzene <56.8 ug/L 03/19/21 05:39 108-90-710056.8 200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Sample:RW-1 Lab ID:92527693003 Collected:03/15/21 12:45 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Chloroethane <130 ug/L 03/19/21 05:39 75-00-3200130200
Chloroform <70.6 ug/L 03/19/21 05:39 67-66-310070.6 200
Chloromethane <108 ug/L 03/19/21 05:39 74-87-3200108200
2-Chlorotoluene <64.2 ug/L 03/19/21 05:39 95-49-810064.2 200
4-Chlorotoluene <64.8 ug/L 03/19/21 05:39 106-43-410064.8 200
1,2-Dibromo-3-chloropropane <68.0 ug/L 03/19/21 05:39 96-12-820068.0 200
Dibromochloromethane <71.8 ug/L 03/19/21 05:39 124-48-110071.8 200
1,2-Dibromoethane (EDB)515 ug/L 03/19/21 05:39 106-93-410054.4 200
Dibromomethane <78.8 ug/L 03/19/21 05:39 74-95-310078.8 200
1,2-Dichlorobenzene <67.8 ug/L 03/19/21 05:39 95-50-110067.8 200
1,3-Dichlorobenzene <68.0 ug/L 03/19/21 05:39 541-73-110068.0 200
1,4-Dichlorobenzene <66.6 ug/L 03/19/21 05:39 106-46-710066.6 200
Dichlorodifluoromethane <69.2 ug/L 03/19/21 05:39 75-71-810069.2 200
1,1-Dichloroethane <73.4 ug/L 03/19/21 05:39 75-34-310073.4 200
1,2-Dichloroethane 337 ug/L 03/19/21 05:39 107-06-210064.4 200
1,1-Dichloroethene <69.6 ug/L 03/19/21 05:39 75-35-410069.6 200
cis-1,2-Dichloroethene <76.8 ug/L 03/19/21 05:39 156-59-210076.8 200
trans-1,2-Dichloroethene <79.2 ug/L 03/19/21 05:39 156-60-510079.2 200
1,2-Dichloropropane <71.0 ug/L 03/19/21 05:39 78-87-510071.0 200
1,3-Dichloropropane <56.8 ug/L 03/19/21 05:39 142-28-910056.8 200
2,2-Dichloropropane <77.6 ug/L 03/19/21 05:39 594-20-710077.6 200
1,1-Dichloropropene <85.4 ug/L 03/19/21 05:39 563-58-610085.4 200
cis-1,3-Dichloropropene <73.0 ug/L 03/19/21 05:39 10061-01-510073.0 200
trans-1,3-Dichloropropene <72.6 ug/L 03/19/21 05:39 10061-02-610072.6 200
Diisopropyl ether 103 ug/L 03/19/21 05:39 108-20-310061.6 200
Ethanol <14400 ug/L 03/19/21 05:39 64-17-54000014400200
Ethylbenzene 4920 ug/L 03/19/21 05:39 100-41-410060.8 200
Ethyl-tert-butyl ether <648 ug/L 03/19/21 05:39 637-92-32000648200
Hexachloro-1,3-butadiene <306 ug/L 03/19/21 05:39 87-68-3400306200
2-Hexanone <95.2 ug/L 03/19/21 05:39 591-78-6100095.2 200
Isopropylbenzene (Cumene)396 ug/L 03/19/21 05:39 98-82-810066.6 200
Methylene Chloride <390 ug/L 03/19/21 05:39 75-09-2400390200
Methyl-tert-butyl ether 252 ug/L 03/19/21 05:39 1634-04-410084.4 200
Naphthalene 2580 ug/L 03/19/21 05:39 91-20-3400129200
n-Propylbenzene <68.0 ug/L 03/19/21 05:39 103-65-110068.0 200
Styrene 117 ug/L 03/19/21 05:39 100-42-510058.4 200
1,1,1,2-Tetrachloroethane <62.2 ug/L 03/19/21 05:39 630-20-610062.2 200
1,1,2,2-Tetrachloroethane <45.0 ug/L 03/19/21 05:39 79-34-510045.0 200
Tetrachloroethene <58.4 ug/L 03/19/21 05:39 127-18-410058.4 200
Toluene 39600 ug/L 03/19/21 05:39 108-88-310097.0 200
1,2,3-Trichlorobenzene <161 ug/L 03/19/21 05:39 87-61-6400161200
1,2,4-Trichlorobenzene <128 ug/L 03/19/21 05:39 120-82-1400128200
1,1,1-Trichloroethane <66.4 ug/L 03/19/21 05:39 71-55-610066.4 200
1,1,2-Trichloroethane <65.0 ug/L 03/19/21 05:39 79-00-510065.0 200
Trichloroethene <76.6 ug/L 03/19/21 05:39 79-01-610076.6 200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Sample:RW-1 Lab ID:92527693003 Collected:03/15/21 12:45 Received:03/15/21 17:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Trichlorofluoromethane <59.6 ug/L 03/19/21 05:39 75-69-420059.6 200
1,2,3-Trichloropropane <52.2 ug/L 03/19/21 05:39 96-18-410052.2 200
1,2,4-Trimethylbenzene 12100 ug/L 03/19/21 05:39 95-63-610099.0 200
1,3,5-Trimethylbenzene 3100 ug/L 03/19/21 05:39 108-67-810066.4 200
Vinyl chloride <77.2 ug/L 03/19/21 05:39 75-01-420077.2 200
Xylene (Total)24400 ug/L 03/19/21 05:39 1330-20-720067.6 200
m&p-Xylene 17000 ug/L 03/19/21 05:39 179601-23-1200142200
o-Xylene 7420 ug/L 03/19/21 05:39 95-47-610067.6 200
Surrogates
1,2-Dichloroethane-d4 (S)95 %03/19/21 05:39 17060-07-070-130 200
4-Bromofluorobenzene (S)96 %03/19/21 05:39 460-00-470-130 200
Toluene-d8 (S)99 %03/19/21 05:39 2037-26-570-130 200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
607343
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92527693001, 92527693002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3199716
Associated Lab Samples:92527693001, 92527693002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 03/18/21 02:380.31
1,1,1-Trichloroethane ug/L <0.33 0.50 03/18/21 02:380.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 03/18/21 02:380.22
1,1,2-Trichloroethane ug/L <0.32 0.50 03/18/21 02:380.32
1,1-Dichloroethane ug/L <0.37 0.50 03/18/21 02:380.37
1,1-Dichloroethene ug/L <0.35 0.50 03/18/21 02:380.35
1,1-Dichloropropene ug/L <0.43 0.50 03/18/21 02:380.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 03/18/21 02:380.81
1,2,3-Trichloropropane ug/L <0.26 0.50 03/18/21 02:380.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 03/18/21 02:380.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 03/18/21 02:380.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 03/18/21 02:380.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 03/18/21 02:380.27
1,2-Dichlorobenzene ug/L <0.34 0.50 03/18/21 02:380.34
1,2-Dichloroethane ug/L <0.32 0.50 03/18/21 02:380.32
1,2-Dichloropropane ug/L <0.36 0.50 03/18/21 02:380.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 03/18/21 02:380.33
1,3-Dichlorobenzene ug/L <0.34 0.50 03/18/21 02:380.34
1,3-Dichloropropane ug/L <0.28 0.50 03/18/21 02:380.28
1,4-Dichlorobenzene ug/L <0.33 0.50 03/18/21 02:380.33
2,2-Dichloropropane ug/L <0.39 0.50 03/18/21 02:380.39
2-Butanone (MEK)ug/L <4.0 5.0 03/18/21 02:384.0
2-Chlorotoluene ug/L <0.32 0.50 03/18/21 02:380.32
2-Hexanone ug/L <0.48 5.0 03/18/21 02:380.48
4-Chlorotoluene ug/L <0.32 0.50 03/18/21 02:380.32
Benzene ug/L <0.34 0.50 03/18/21 02:380.34
Bromobenzene ug/L <0.29 0.50 03/18/21 02:380.29
Bromochloromethane ug/L <0.47 0.50 03/18/21 02:380.47
Bromodichloromethane ug/L <0.31 0.50 03/18/21 02:380.31
Bromoform ug/L <0.34 0.50 03/18/21 02:380.34
Bromomethane ug/L <1.7 5.0 03/18/21 02:381.7
Carbon tetrachloride ug/L <0.33 0.50 03/18/21 02:380.33
Chlorobenzene ug/L <0.28 0.50 03/18/21 02:380.28
Chloroethane ug/L <0.65 1.0 03/18/21 02:380.65
Chloroform ug/L <0.35 0.50 03/18/21 02:380.35
Chloromethane ug/L <0.54 1.0 03/18/21 02:380.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 03/18/21 02:380.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 03/18/21 02:380.36
Dibromochloromethane ug/L <0.36 0.50 03/18/21 02:380.36
Dibromomethane ug/L <0.39 0.50 03/18/21 02:380.39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3199716
Associated Lab Samples:92527693001, 92527693002
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L <0.35 0.50 03/18/21 02:380.35
Diisopropyl ether ug/L <0.31 0.50 03/18/21 02:380.31
Ethanol ug/L <72.2 200 03/18/21 02:3872.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 03/18/21 02:383.2
Ethylbenzene ug/L <0.30 0.50 03/18/21 02:380.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 03/18/21 02:381.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 03/18/21 02:380.33
m&p-Xylene ug/L <0.71 1.0 03/18/21 02:380.71
Methyl-tert-butyl ether ug/L <0.42 0.50 03/18/21 02:380.42
Methylene Chloride ug/L <2.0 2.0 03/18/21 02:382.0
n-Butylbenzene ug/L <0.49 0.50 03/18/21 02:380.49
n-Propylbenzene ug/L <0.34 0.50 03/18/21 02:380.34
Naphthalene ug/L <0.64 2.0 03/18/21 02:380.64
o-Xylene ug/L <0.34 0.50 03/18/21 02:380.34
sec-Butylbenzene ug/L <0.40 0.50 03/18/21 02:380.40
Styrene ug/L <0.29 0.50 03/18/21 02:380.29
tert-Amyl Alcohol ug/L <36.4 100 03/18/21 02:3836.4
tert-Amylmethyl ether ug/L <2.7 10.0 03/18/21 02:382.7
tert-Butyl Alcohol ug/L <26.8 50.0 03/18/21 02:3826.8
tert-Butyl Formate ug/L <29.4 50.0 03/18/21 02:3829.4
tert-Butylbenzene ug/L <0.32 0.50 03/18/21 02:380.32
Tetrachloroethene ug/L <0.29 0.50 03/18/21 02:380.29
Toluene ug/L <0.48 0.50 03/18/21 02:380.48
trans-1,2-Dichloroethene ug/L <0.40 0.50 03/18/21 02:380.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 03/18/21 02:380.36
Trichloroethene ug/L <0.38 0.50 03/18/21 02:380.38
Trichlorofluoromethane ug/L <0.30 1.0 03/18/21 02:380.30
Vinyl chloride ug/L <0.39 1.0 03/18/21 02:380.39
Xylene (Total)ug/L <0.34 1.0 03/18/21 02:380.34
1,2-Dichloroethane-d4 (S)%99 70-130 03/18/21 02:38
4-Bromofluorobenzene (S)%101 70-130 03/18/21 02:38
Toluene-d8 (S)%100 70-130 03/18/21 02:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3199717LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 56.650 113 60-140
1,1,1-Trichloroethane ug/L 49.250 98 60-140
1,1,2,2-Tetrachloroethane ug/L 55.150 110 60-140
1,1,2-Trichloroethane ug/L 55.150 110 60-140
1,1-Dichloroethane ug/L 48.350 97 60-140
1,1-Dichloroethene ug/L 50.650 101 60-140
1,1-Dichloropropene ug/L 50.650 101 60-140
1,2,3-Trichlorobenzene ug/L 53.350 107 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3199717LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,3-Trichloropropane ug/L 54.250 108 60-140
1,2,4-Trichlorobenzene ug/L 53.850 108 60-140
1,2,4-Trimethylbenzene ug/L 52.650 105 60-140
1,2-Dibromo-3-chloropropane ug/L 55.350 111 60-140
1,2-Dibromoethane (EDB)ug/L 56.750 113 60-140
1,2-Dichlorobenzene ug/L 50.950 102 60-140
1,2-Dichloroethane ug/L 50.450 101 60-140
1,2-Dichloropropane ug/L 52.150 104 60-140
1,3,5-Trimethylbenzene ug/L 52.350 105 60-140
1,3-Dichlorobenzene ug/L 51.450 103 60-140
1,3-Dichloropropane ug/L 53.850 108 60-140
1,4-Dichlorobenzene ug/L 50.450 101 60-140
2,2-Dichloropropane ug/L 47.250 94 60-140
2-Butanone (MEK)ug/L 107100 107 60-140
2-Chlorotoluene ug/L 50.950 102 60-140
2-Hexanone ug/L 112100 112 60-140
4-Chlorotoluene ug/L 50.450 101 60-140
Benzene ug/L 50.550 101 60-140
Bromobenzene ug/L 49.150 98 60-140
Bromochloromethane ug/L 51.050 102 60-140
Bromodichloromethane ug/L 53.250 106 60-140
Bromoform ug/L 45.950 92 60-140
Bromomethane ug/L 46.850 94 60-140
Carbon tetrachloride ug/L 53.250 106 60-140
Chlorobenzene ug/L 52.350 105 60-140
Chloroethane ug/L 43.550 87 60-140
Chloroform ug/L 49.150 98 60-140
Chloromethane ug/L 39.650 79 60-140
cis-1,2-Dichloroethene ug/L 46.650 93 60-140
cis-1,3-Dichloropropene ug/L 55.950 112 60-140
Dibromochloromethane ug/L 56.250 112 60-140
Dibromomethane ug/L 55.650 111 60-140
Dichlorodifluoromethane ug/L 45.450 91 60-140
Diisopropyl ether ug/L 46.350 93 60-140
Ethanol ug/L 19402000 97 60-140
Ethyl-tert-butyl ether ug/L 95.7100 96 60-140
Ethylbenzene ug/L 51.950 104 60-140
Hexachloro-1,3-butadiene ug/L 52.150 104 60-140
Isopropylbenzene (Cumene)ug/L 53.350 107 60-140
m&p-Xylene ug/L 103100 103 60-140
Methyl-tert-butyl ether ug/L 50.850 102 60-140
Methylene Chloride ug/L 43.950 88 60-140
n-Butylbenzene ug/L 55.250 110 60-140
n-Propylbenzene ug/L 50.250 100 60-140
Naphthalene ug/L 53.750 107 60-140
o-Xylene ug/L 52.550 105 60-140
sec-Butylbenzene ug/L 51.650 103 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3199717LABORATORY CONTROL SAMPLE:
LCSSpike
Styrene ug/L 52.750 105 60-140
tert-Amyl Alcohol ug/L 11801000 118 60-140
tert-Amylmethyl ether ug/L 105100 105 60-140
tert-Butyl Alcohol ug/L 560500 112 60-140
tert-Butyl Formate ug/L 294400 73 60-140
tert-Butylbenzene ug/L 42.550 85 60-140
Tetrachloroethene ug/L 52.150 104 60-140
Toluene ug/L 51.650 103 60-140
trans-1,2-Dichloroethene ug/L 47.650 95 60-140
trans-1,3-Dichloropropene ug/L 54.250 108 60-140
Trichloroethene ug/L 52.350 105 60-140
Trichlorofluoromethane ug/L 45.250 90 60-140
Vinyl chloride ug/L 43.050 86 60-140
Xylene (Total)ug/L 156150 104 60-140
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3199718MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92527693002
3199719
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 5000 110 60-140109 1 305000<77.8 5520 5470
1,1,1-Trichloroethane ug/L 5000 108 60-140109 1 305000<83.0 5390 5470
1,1,2,2-Tetrachloroethane ug/L 5000 110 60-140108 2 305000<56.2 5520 5390
1,1,2-Trichloroethane ug/L 5000 109 60-140111 1 305000<81.2 5470 5540
1,1-Dichloroethane ug/L 5000 103 60-140105 1 305000<91.8 5160 5230
1,1-Dichloroethene ug/L 5000 110 60-140111 1 305000<87.0 5510 5560
1,1-Dichloropropene ug/L 5000 111 60-140114 2 305000<107 5550 5680
1,2,3-Trichlorobenzene ug/L 5000 104 60-140107 2 305000<202 5220 5330
1,2,3-Trichloropropane ug/L 5000 112 60-140106 5 305000<65.2 5600 5320
1,2,4-Trichlorobenzene ug/L 5000 105 60-140107 2 305000<160 5230 5340
1,2,4-Trimethylbenzene ug/L 5000 120 60-140114 4 305000271086908380
1,2-Dibromo-3-
chloropropane ug/L 5000 108 60-140109 0 305000<85.0 5410 5440
1,2-Dibromoethane (EDB)ug/L 5000 118 60-140113 3 30500077966606430
1,2-Dichlorobenzene ug/L 5000 111 60-140104 7 305000<84.8 5560 5180
1,2-Dichloroethane ug/L 5000 105 60-140109 3 30500022054805660
1,2-Dichloropropane ug/L 5000 108 60-140108 1 305000<88.8 5380 5420
1,3,5-Trimethylbenzene ug/L 5000 113 60-140111 2 30500078964606320
1,3-Dichlorobenzene ug/L 5000 110 60-140107 3 305000<85.0 5520 5370
1,3-Dichloropropane ug/L 5000 107 60-140107 0 305000<71.0 5330 5340
1,4-Dichlorobenzene ug/L 5000 106 60-140105 1 305000<83.2 5310 5270
2,2-Dichloropropane ug/L 5000 84 60-14085 1 305000<97.0 4190 4240
2-Butanone (MEK)ug/L 10000 107 60-140107 0 3010000<990 11200 11100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3199718MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92527693002
3199719
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Chlorotoluene ug/L 5000 110 60-140108 2 305000<80.2 5510 5420
2-Hexanone ug/L 10000 111 60-140108 2 3010000527J1160011400
4-Chlorotoluene ug/L 5000 109 60-140106 3 305000<81.0 5440 5280
Benzene ug/L 5000 107 60-140117 2 305000152002050021000
Bromobenzene ug/L 5000 106 60-140102 5 305000<72.5 5310 5080
Bromochloromethane ug/L 5000 114 60-140108 5 305000<117 5690 5390
Bromodichloromethane ug/L 5000 107 60-140107 0 305000<76.8 5360 5370
Bromoform ug/L 5000 94 60-14091 3 305000<85.2 4690 4560
Bromomethane ug/L 5000 92 60-14097 6 305000<415 4590 4860
Carbon tetrachloride ug/L 5000 114 60-140118 3 305000<83.2 5720 5890
Chlorobenzene ug/L 5000 108 60-140108 0 305000<71.0 5380 5390
Chloroethane ug/L 5000 102 60-140104 2 305000<162 5100 5200
Chloroform ug/L 5000 104 60-140108 4 305000<88.2 5200 5400
Chloromethane ug/L 5000 87 60-14089 1 305000<135 4360 4430
cis-1,2-Dichloroethene ug/L 5000 101 60-140103 2 305000<96.0 5070 5160
cis-1,3-Dichloropropene ug/L 5000 107 60-140108 2 305000<91.2 5330 5420
Dibromochloromethane ug/L 5000 106 60-140108 2 305000<89.8 5300 5410
Dibromomethane ug/L 5000 114 60-140112 2 305000<98.5 5700 5590
Dichlorodifluoromethane ug/L 5000 92 60-14092 0 305000<86.5 4600 4590
Diisopropyl ether ug/L 5000 98 60-14096 2 305000<77.0 4930 4850
Ethanol ug/L 200000 97 60-140105 8 30200000<18000 194000 209000
Ethyl-tert-butyl ether ug/L 10000 99 60-14098 1 3010000<810 9890 9820
Ethylbenzene ug/L 5000 111 60-140112 0 305000226078307860
Hexachloro-1,3-butadiene ug/L 5000 96 60-140105 8 305000<382 4810 5230
Isopropylbenzene
(Cumene)
ug/L 5000 111 60-140112 1 305000102J56505700
m&p-Xylene ug/L 10000 107 60-140105 1 3010000111002180021500
Methyl-tert-butyl ether ug/L 5000 103 60-140104 2 305000<106 5190 5270
Methylene Chloride ug/L 5000 94 60-14094 0 305000<488 4690 4680
n-Butylbenzene ug/L 5000 111 60-140112 1 305000<122 5540 5580
n-Propylbenzene ug/L 5000 115 60-140111 3 305000<85.0 5750 5550
Naphthalene ug/L 5000 108 60-140107 1 30500081662206180
o-Xylene ug/L 5000 112 60-140110 1 30500059001150011400
sec-Butylbenzene ug/L 5000 108 60-140111 3 305000<100 5420 5550
Styrene ug/L 5000 109 60-140109 0 30500079.0J 5540 5530
tert-Amyl Alcohol ug/L 100000 122 60-140121 1 30100000<9100 122000 121000
tert-Amylmethyl ether ug/L 10000 107 60-140106 1 3010000<665 10700 10600
tert-Butyl Alcohol ug/L 50000 110 60-140112 1 3050000<6700 55700 56400
tert-Butyl Formate ug/L 40000 76 60-14077 1 3040000<7350 30600 30900
tert-Butylbenzene ug/L 5000 90 60-14090 1 305000<80.8 4520 4480
Tetrachloroethene ug/L 5000 110 60-140105 5 305000<73.0 5520 5250
Toluene ug/L 5000 109 60-140115 1 305000294003490035200
trans-1,2-Dichloroethene ug/L 5000 105 60-140106 1 305000<99.0 5230 5310
trans-1,3-Dichloropropene ug/L 5000 104 60-140103 0 305000<90.8 5180 5160
Trichloroethene ug/L 5000 113 60-140113 0 305000<95.8 5650 5660
Trichlorofluoromethane ug/L 5000 101 60-140102 1 305000<74.5 5030 5100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3199718MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92527693002
3199719
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Vinyl chloride ug/L 5000 90 60-14091 1 305000<96.5 4510 4550
Xylene (Total)ug/L 15000 109 60-140106 1 3015000170003320032900
1,2-Dichloroethane-d4 (S)%94 70-13097
4-Bromofluorobenzene (S)%96 70-13099
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
607642
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92527693003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3201003
Associated Lab Samples:92527693003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 03/19/21 00:320.31
1,1,1-Trichloroethane ug/L <0.33 0.50 03/19/21 00:320.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 03/19/21 00:320.22
1,1,2-Trichloroethane ug/L <0.32 0.50 03/19/21 00:320.32
1,1-Dichloroethane ug/L <0.37 0.50 03/19/21 00:320.37
1,1-Dichloroethene ug/L <0.35 0.50 03/19/21 00:320.35
1,1-Dichloropropene ug/L <0.43 0.50 03/19/21 00:320.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 03/19/21 00:320.81
1,2,3-Trichloropropane ug/L <0.26 0.50 03/19/21 00:320.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 03/19/21 00:320.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 03/19/21 00:320.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 03/19/21 00:320.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 03/19/21 00:320.27
1,2-Dichlorobenzene ug/L <0.34 0.50 03/19/21 00:320.34
1,2-Dichloroethane ug/L <0.32 0.50 03/19/21 00:320.32
1,2-Dichloropropane ug/L <0.36 0.50 03/19/21 00:320.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 03/19/21 00:320.33
1,3-Dichlorobenzene ug/L <0.34 0.50 03/19/21 00:320.34
1,3-Dichloropropane ug/L <0.28 0.50 03/19/21 00:320.28
1,4-Dichlorobenzene ug/L <0.33 0.50 03/19/21 00:320.33
2,2-Dichloropropane ug/L <0.39 0.50 03/19/21 00:320.39
2-Butanone (MEK)ug/L <4.0 5.0 03/19/21 00:324.0
2-Chlorotoluene ug/L <0.32 0.50 03/19/21 00:320.32
2-Hexanone ug/L <0.48 5.0 03/19/21 00:320.48
4-Chlorotoluene ug/L <0.32 0.50 03/19/21 00:320.32
Benzene ug/L <0.34 0.50 03/19/21 00:320.34
Bromobenzene ug/L <0.29 0.50 03/19/21 00:320.29
Bromochloromethane ug/L <0.47 0.50 03/19/21 00:320.47
Bromodichloromethane ug/L <0.31 0.50 03/19/21 00:320.31
Bromoform ug/L <0.34 0.50 03/19/21 00:320.34
Bromomethane ug/L <1.7 5.0 03/19/21 00:321.7
Carbon tetrachloride ug/L <0.33 0.50 03/19/21 00:320.33
Chlorobenzene ug/L <0.28 0.50 03/19/21 00:320.28
Chloroethane ug/L <0.65 1.0 03/19/21 00:320.65
Chloroform ug/L <0.35 0.50 03/19/21 00:320.35
Chloromethane ug/L <0.54 1.0 03/19/21 00:320.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 03/19/21 00:320.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 03/19/21 00:320.36
Dibromochloromethane ug/L <0.36 0.50 03/19/21 00:320.36
Dibromomethane ug/L <0.39 0.50 03/19/21 00:320.39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3201003
Associated Lab Samples:92527693003
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L <0.35 0.50 03/19/21 00:320.35
Diisopropyl ether ug/L <0.31 0.50 03/19/21 00:320.31
Ethanol ug/L <72.2 200 03/19/21 00:3272.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 03/19/21 00:323.2
Ethylbenzene ug/L <0.30 0.50 03/19/21 00:320.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 03/19/21 00:321.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 03/19/21 00:320.33
m&p-Xylene ug/L <0.71 1.0 03/19/21 00:320.71
Methyl-tert-butyl ether ug/L <0.42 0.50 03/19/21 00:320.42
Methylene Chloride ug/L <2.0 2.0 03/19/21 00:322.0
n-Butylbenzene ug/L <0.49 0.50 03/19/21 00:320.49
n-Propylbenzene ug/L <0.34 0.50 03/19/21 00:320.34
Naphthalene ug/L <0.64 2.0 03/19/21 00:320.64
o-Xylene ug/L <0.34 0.50 03/19/21 00:320.34
sec-Butylbenzene ug/L <0.40 0.50 03/19/21 00:320.40
Styrene ug/L <0.29 0.50 03/19/21 00:320.29
tert-Amyl Alcohol ug/L <36.4 100 03/19/21 00:3236.4
tert-Amylmethyl ether ug/L <2.7 10.0 03/19/21 00:322.7
tert-Butyl Alcohol ug/L <26.8 50.0 03/19/21 00:3226.8
tert-Butyl Formate ug/L <29.4 50.0 03/19/21 00:3229.4
tert-Butylbenzene ug/L <0.32 0.50 03/19/21 00:320.32
Tetrachloroethene ug/L <0.29 0.50 03/19/21 00:320.29
Toluene ug/L <0.48 0.50 03/19/21 00:320.48
trans-1,2-Dichloroethene ug/L <0.40 0.50 03/19/21 00:320.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 03/19/21 00:320.36
Trichloroethene ug/L <0.38 0.50 03/19/21 00:320.38
Trichlorofluoromethane ug/L <0.30 1.0 03/19/21 00:320.30
Vinyl chloride ug/L <0.39 1.0 03/19/21 00:320.39
Xylene (Total)ug/L <0.34 1.0 03/19/21 00:320.34
1,2-Dichloroethane-d4 (S)%97 70-130 03/19/21 00:32
4-Bromofluorobenzene (S)%94 70-130 03/19/21 00:32
Toluene-d8 (S)%100 70-130 03/19/21 00:32
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3201004LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.550 97 60-140
1,1,1-Trichloroethane ug/L 44.250 88 60-140
1,1,2,2-Tetrachloroethane ug/L 46.950 94 60-140
1,1,2-Trichloroethane ug/L 47.150 94 60-140
1,1-Dichloroethane ug/L 44.350 89 60-140
1,1-Dichloroethene ug/L 46.450 93 60-140
1,1-Dichloropropene ug/L 45.350 91 60-140
1,2,3-Trichlorobenzene ug/L 49.050 98 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
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Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3201004LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,3-Trichloropropane ug/L 49.750 99 60-140
1,2,4-Trichlorobenzene ug/L 49.750 99 60-140
1,2,4-Trimethylbenzene ug/L 47.650 95 60-140
1,2-Dibromo-3-chloropropane ug/L 49.450 99 60-140
1,2-Dibromoethane (EDB)ug/L 48.250 96 60-140
1,2-Dichlorobenzene ug/L 49.550 99 60-140
1,2-Dichloroethane ug/L 41.350 83 60-140
1,2-Dichloropropane ug/L 43.550 87 60-140
1,3,5-Trimethylbenzene ug/L 46.450 93 60-140
1,3-Dichlorobenzene ug/L 50.250 100 60-140
1,3-Dichloropropane ug/L 47.150 94 60-140
1,4-Dichlorobenzene ug/L 50.450 101 60-140
2,2-Dichloropropane ug/L 45.650 91 60-140
2-Butanone (MEK)ug/L 84.1100 84 60-140
2-Chlorotoluene ug/L 46.950 94 60-140
2-Hexanone ug/L 90.5100 90 60-140
4-Chlorotoluene ug/L 45.950 92 60-140
Benzene ug/L 45.350 91 60-140
Bromobenzene ug/L 47.150 94 60-140
Bromochloromethane ug/L 47.650 95 60-140
Bromodichloromethane ug/L 43.350 87 60-140
Bromoform ug/L 48.050 96 60-140
Bromomethane ug/L 47.950 96 60-140
Carbon tetrachloride ug/L 48.850 98 60-140
Chlorobenzene ug/L 49.450 99 60-140
Chloroethane ug/L 43.350 87 60-140
Chloroform ug/L 43.250 86 60-140
Chloromethane ug/L 43.250 86 60-140
cis-1,2-Dichloroethene ug/L 43.150 86 60-140
cis-1,3-Dichloropropene ug/L 46.850 94 60-140
Dibromochloromethane ug/L 49.250 98 60-140
Dibromomethane ug/L 49.550 99 60-140
Dichlorodifluoromethane ug/L 49.250 98 60-140
Diisopropyl ether ug/L 40.850 82 60-140
Ethanol ug/L 17602000 88 60-140
Ethyl-tert-butyl ether ug/L 90.0100 90 60-140
Ethylbenzene ug/L 48.250 96 60-140
Hexachloro-1,3-butadiene ug/L 46.850 94 60-140
Isopropylbenzene (Cumene)ug/L 48.950 98 60-140
m&p-Xylene ug/L 97.1100 97 60-140
Methyl-tert-butyl ether ug/L 44.350 89 60-140
Methylene Chloride ug/L 44.650 89 60-140
n-Butylbenzene ug/L 47.950 96 60-140
n-Propylbenzene ug/L 46.350 93 60-140
Naphthalene ug/L 51.150 102 60-140
o-Xylene ug/L 48.450 97 60-140
sec-Butylbenzene ug/L 47.550 95 60-140
REPORT OF LABORATORY ANALYSIS
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Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3201004LABORATORY CONTROL SAMPLE:
LCSSpike
Styrene ug/L 49.150 98 60-140
tert-Amyl Alcohol ug/L 9601000 96 60-140
tert-Amylmethyl ether ug/L 94.2100 94 60-140
tert-Butyl Alcohol ug/L 438500 88 60-140
tert-Butyl Formate ug/L 376400 94 60-140
tert-Butylbenzene ug/L 39.850 80 60-140
Tetrachloroethene ug/L 49.350 99 60-140
Toluene ug/L 47.250 94 60-140
trans-1,2-Dichloroethene ug/L 45.050 90 60-140
trans-1,3-Dichloropropene ug/L 46.250 92 60-140
Trichloroethene ug/L 49.150 98 60-140
Trichlorofluoromethane ug/L 48.650 97 60-140
Vinyl chloride ug/L 44.350 89 60-140
Xylene (Total)ug/L 146150 97 60-140
1,2-Dichloroethane-d4 (S)%91 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3201005MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92527693003
3201006
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 4000 103 60-140104 1 304000<62.2 4130 4160
1,1,1-Trichloroethane ug/L 4000 99 60-14099 0 304000<66.4 3950 3960
1,1,2,2-Tetrachloroethane ug/L 4000 96 60-14098 2 304000<45.0 3850 3930
1,1,2-Trichloroethane ug/L 4000 100 60-140102 2 304000<65.0 4000 4070
1,1-Dichloroethane ug/L 4000 95 60-14098 3 304000<73.4 3810 3920
1,1-Dichloroethene ug/L 4000 104 60-140107 2 304000<69.6 4170 4260
1,1-Dichloropropene ug/L 4000 99 60-140100 2 304000<85.4 3940 4010
1,2,3-Trichlorobenzene ug/L 4000 106 60-140109 3 304000<161 4260 4370
1,2,3-Trichloropropane ug/L 4000 100 60-140105 5 304000<52.2 3980 4190
1,2,4-Trichlorobenzene ug/L 4000 106 60-140109 2 304000<128 4260 4350
1,2,4-Trimethylbenzene ug/L 4000 90 60-140100 3 304000121001570016100
1,2-Dibromo-3-
chloropropane ug/L 4000 99 60-140103 4 304000<68.0 3940 4100
1,2-Dibromoethane (EDB)ug/L 4000 101 60-140103 2 30400051545404650
1,2-Dichlorobenzene ug/L 4000 106 60-140108 3 304000<67.8 4220 4340
1,2-Dichloroethane ug/L 4000 87 60-14086 1 30400033738303790
1,2-Dichloropropane ug/L 4000 95 60-14096 2 304000<71.0 3780 3850
1,3,5-Trimethylbenzene ug/L 4000 97 60-140102 3 304000310069707190
1,3-Dichlorobenzene ug/L 4000 108 60-140110 2 304000<68.0 4300 4390
1,3-Dichloropropane ug/L 4000 98 60-14099 1 304000<56.8 3920 3950
1,4-Dichlorobenzene ug/L 4000 107 60-140109 1 304000<66.6 4290 4350
2,2-Dichloropropane ug/L 4000 71 60-14070 1 304000<77.6 2830 2800
2-Butanone (MEK)ug/L 8000 84 60-14087 4 308000<792 6720 6980
REPORT OF LABORATORY ANALYSIS
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Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3201005MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92527693003
3201006
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Chlorotoluene ug/L 4000 105 60-140112 7 304000<64.2 4190 4500
2-Hexanone ug/L 8000 90 60-14093 3 308000<95.2 7240 7460
4-Chlorotoluene ug/L 4000 99 60-140101 1 304000<64.8 3970 4020
Benzene ug/L 4000 88 60-14091 1 304000170002050020600
Bromobenzene ug/L 4000 102 60-140103 1 304000<58.0 4070 4130
Bromochloromethane ug/L 4000 102 60-140104 2 304000<93.6 4070 4150
Bromodichloromethane ug/L 4000 93 60-14094 1 304000<61.4 3730 3750
Bromoform ug/L 4000 98 60-14099 1 304000<68.2 3910 3960
Bromomethane ug/L 4000 105 60-140109 4 304000<332 4190 4360
Carbon tetrachloride ug/L 4000 109 60-140111 2 304000<66.6 4360 4440
Chlorobenzene ug/L 4000 107 60-140107 0 304000<56.8 4270 4260
Chloroethane ug/L 4000 122 60-140121 1 304000<130 4880 4830
Chloroform ug/L 4000 94 60-14097 4 304000<70.6 3740 3880
Chloromethane ug/L 4000 79 60-14083 4 304000<108 3180 3320
cis-1,2-Dichloroethene ug/L 4000 95 60-14095 0 304000<76.8 3780 3800
cis-1,3-Dichloropropene ug/L 4000 93 60-14094 1 304000<73.0 3730 3770
Dibromochloromethane ug/L 4000 102 60-140104 2 304000<71.8 4090 4150
Dibromomethane ug/L 4000 104 60-140106 2 304000<78.8 4160 4250
Dichlorodifluoromethane ug/L 4000 101 60-140101 1 304000<69.2 4060 4030
Diisopropyl ether ug/L 4000 86 60-14087 1 30400010335503590
Ethanol ug/L 160000 91 60-14093 2 30160000<14400 146000 148000
Ethyl-tert-butyl ether ug/L 8000 95 60-14097 2 308000<648 7620 7780
Ethylbenzene ug/L 4000 103 60-140105 1 304000492090409120
Hexachloro-1,3-butadiene ug/L 4000 100 60-140101 1 304000<306 4010 4040
Isopropylbenzene
(Cumene)
ug/L 4000 107 60-140108 0 30400039646904720
m&p-Xylene ug/L 8000 101 60-140106 2 308000170002500025500
Methyl-tert-butyl ether ug/L 4000 92 60-14094 2 30400025239104010
Methylene Chloride ug/L 4000 97 60-14098 0 304000<390 3900 3910
n-Butylbenzene ug/L 4000 122 60-140125 2 304000<98.0 4890 4980
n-Propylbenzene ug/L 4000 133 60-140135 2 304000<68.0 5300 5410
Naphthalene ug/L 4000 114 60-140123 5 304000258071507480
o-Xylene ug/L 4000 103 60-140105 1 30400074201150011600
sec-Butylbenzene ug/L 4000 108 60-140111 2 304000<80.0 4320 4420
Styrene ug/L 4000 106 60-140107 0 30400011743604380
tert-Amyl Alcohol ug/L 80000 102 60-140104 2 3080000<7280 81300 82800
tert-Amylmethyl ether ug/L 8000 101 60-140100 1 308000<532 8100 8040
tert-Butyl Alcohol ug/L 40000 89 60-14090 1 3040000<5360 35700 36000
tert-Butyl Formate ug/L 32000 96 60-14098 1 3032000<5880 30800 31200
tert-Butylbenzene ug/L 4000 88 60-14089 1 304000<64.6 3510 3540
Tetrachloroethene ug/L 4000 107 60-140107 0 304000<58.4 4280 4290
Toluene ug/L E40006360-14063 0 304000396004220042200
trans-1,2-Dichloroethene ug/L 4000 98 60-14098 1 304000<79.2 3940 3910
trans-1,3-Dichloropropene ug/L 4000 92 60-14092 1 304000<72.6 3670 3690
Trichloroethene ug/L 4000 109 60-140109 0 304000<76.6 4370 4360
Trichlorofluoromethane ug/L 4000 127 60-140127 0 304000<59.6 5080 5100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/22/2021 05:20 PM
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Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3201005MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92527693003
3201006
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Vinyl chloride ug/L 4000 93 60-14095 2 304000<77.2 3720 3800
Xylene (Total)ug/L 12000 101 60-140106 1 3012000244003660037100
1,2-Dichloroethane-d4 (S)%97 70-13096
4-Bromofluorobenzene (S)%98 70-13097
Toluene-d8 (S)%97 70-13097
REPORT OF LABORATORY ANALYSIS
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Page 22 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
REPORT OF LABORATORY ANALYSIS
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Page 23 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92527693
WILLIAMS GROCERY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92527693001 607343MW-1 SM 6200B
92527693002 607343MW-3 SM 6200B
92527693003 607642RW-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
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Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27
#=CL#
March 25, 2021
LIMS USE: FR - NOELLE FRANCE
LIMS OBJECT ID: 92528786
92528786
Project:
Pace Project No.:
RE:
Noelle France
ATC Group Services LLC- South Charlotte
7606 Whitehall Exe Center Dr
Suite 800
Charlotte, NC 28273
Williams Grocery
Dear Noelle France:
Enclosed are the analytical results for sample(s) received by the laboratory on March 19, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
[phone]
Enclosures
cc:Al Quarles, ATC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92528786
Williams Grocery
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92528786
Williams Grocery
Lab ID Sample ID Matrix Date Collected Date Received
92528786001 MW-1 Water 03/17/21 12:05 03/19/21 15:04
92528786002 MW-3 Water 03/17/21 12:10 03/19/21 15:04
92528786003 RW-1 Water 03/17/21 12:25 03/19/21 15:04
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92528786
Williams Grocery
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92528786001 MW-1 SM 6200B 72 PASI-CSAS
92528786002 MW-3 SM 6200B 72 PASI-CSAS
92528786003 RW-1 SM 6200B 72 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 4 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92528786
Williams Grocery
Sample:MW-1 Lab ID:92528786001 Collected:03/17/21 12:05 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 15300 ug/L 03/24/21 19:15 75-85-44000146040
tert-Amylmethyl ether 111J ug/L 03/24/21 19:15 994-05-840010640
Benzene 2860 ug/L 03/24/21 19:15 71-43-220.0 13.8 40
Bromobenzene <11.6 ug/L 03/24/21 19:15 108-86-120.0 11.6 40
Bromochloromethane <18.7 ug/L 03/24/21 19:15 74-97-520.0 18.7 40
Bromodichloromethane <12.3 ug/L 03/24/21 19:15 75-27-420.0 12.3 40
Bromoform <13.6 ug/L 03/24/21 19:15 75-25-220.0 13.6 40
Bromomethane <66.4 ug/L 03/24/21 19:15 74-83-920066.4 40
2-Butanone (MEK)1480 ug/L 03/24/21 19:15 78-93-320015840
tert-Butyl Alcohol 24700 ug/L 03/24/21 19:15 75-65-02000107040
n-Butylbenzene <19.6 ug/L 03/24/21 19:15 104-51-820.0 19.6 40
sec-Butylbenzene <16.0 ug/L 03/24/21 19:15 135-98-820.0 16.0 40
tert-Butylbenzene <12.9 ug/L 03/24/21 19:15 98-06-620.0 12.9 40
tert-Butyl Formate <1180 ug/L 03/24/21 19:15 762-75-42000118040
Carbon tetrachloride <13.3 ug/L 03/24/21 19:15 56-23-520.0 13.3 40
Chlorobenzene <11.4 ug/L 03/24/21 19:15 108-90-720.0 11.4 40
Chloroethane <26.0 ug/L 03/24/21 19:15 75-00-340.0 26.0 40
Chloroform <14.1 ug/L 03/24/21 19:15 67-66-320.0 14.1 40
Chloromethane <21.6 ug/L 03/24/21 19:15 74-87-340.0 21.6 40
2-Chlorotoluene <12.8 ug/L 03/24/21 19:15 95-49-820.0 12.8 40
4-Chlorotoluene <13.0 ug/L 03/24/21 19:15 106-43-420.0 13.0 40
1,2-Dibromo-3-chloropropane <13.6 ug/L 03/24/21 19:15 96-12-840.0 13.6 40
Dibromochloromethane <14.4 ug/L 03/24/21 19:15 124-48-120.0 14.4 40
1,2-Dibromoethane (EDB)334 ug/L 03/24/21 19:15 106-93-420.0 10.9 40
Dibromomethane <15.8 ug/L 03/24/21 19:15 74-95-320.0 15.8 40
1,2-Dichlorobenzene <13.6 ug/L 03/24/21 19:15 95-50-120.0 13.6 40
1,3-Dichlorobenzene <13.6 ug/L 03/24/21 19:15 541-73-120.0 13.6 40
1,4-Dichlorobenzene <13.3 ug/L 03/24/21 19:15 106-46-720.0 13.3 40
Dichlorodifluoromethane <13.8 ug/L 03/24/21 19:15 75-71-820.0 13.8 40
1,1-Dichloroethane <14.7 ug/L 03/24/21 19:15 75-34-320.0 14.7 40
1,2-Dichloroethane 419 ug/L 03/24/21 19:15 107-06-220.0 12.9 40
1,1-Dichloroethene <13.9 ug/L 03/24/21 19:15 75-35-420.0 13.9 40
cis-1,2-Dichloroethene <15.4 ug/L 03/24/21 19:15 156-59-220.0 15.4 40
trans-1,2-Dichloroethene <15.8 ug/L 03/24/21 19:15 156-60-520.0 15.8 40
1,2-Dichloropropane <14.2 ug/L 03/24/21 19:15 78-87-520.0 14.2 40
1,3-Dichloropropane <11.4 ug/L 03/24/21 19:15 142-28-920.0 11.4 40
2,2-Dichloropropane <15.5 ug/L 03/24/21 19:15 594-20-720.0 15.5 40
1,1-Dichloropropene <17.1 ug/L 03/24/21 19:15 563-58-620.0 17.1 40
cis-1,3-Dichloropropene <14.6 ug/L 03/24/21 19:15 10061-01-520.0 14.6 40
trans-1,3-Dichloropropene <14.5 ug/L 03/24/21 19:15 10061-02-620.0 14.5 40
Diisopropyl ether 95.1 ug/L 03/24/21 19:15 108-20-320.0 12.3 40
Ethanol <2890 ug/L 03/24/21 19:15 64-17-58000289040
Ethylbenzene 290 ug/L 03/24/21 19:15 100-41-420.0 12.2 40
Ethyl-tert-butyl ether <130 ug/L 03/24/21 19:15 637-92-340013040
Hexachloro-1,3-butadiene <61.2 ug/L 03/24/21 19:15 87-68-380.0 61.2 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92528786
Williams Grocery
Sample:MW-1 Lab ID:92528786001 Collected:03/17/21 12:05 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
2-Hexanone 360 ug/L 03/24/21 19:15 591-78-620019.0 40
Isopropylbenzene (Cumene)17.9J ug/L 03/24/21 19:15 98-82-820.0 13.3 40
Methylene Chloride <78.0 ug/L 03/24/21 19:15 75-09-280.0 78.0 40
Methyl-tert-butyl ether 5050 ug/L 03/24/21 19:15 1634-04-420.0 16.9 40
Naphthalene 327 ug/L 03/24/21 19:15 91-20-380.0 25.8 40
n-Propylbenzene <13.6 ug/L 03/24/21 19:15 103-65-120.0 13.6 40
Styrene <11.7 ug/L 03/24/21 19:15 100-42-520.0 11.7 40
1,1,1,2-Tetrachloroethane <12.4 ug/L 03/24/21 19:15 630-20-620.0 12.4 40
1,1,2,2-Tetrachloroethane <9.0 ug/L 03/24/21 19:15 79-34-520.0 9.0 40
Tetrachloroethene <11.7 ug/L 03/24/21 19:15 127-18-420.0 11.7 40
Toluene 4010 ug/L 03/24/21 19:15 108-88-320.0 19.4 40
1,2,3-Trichlorobenzene <32.2 ug/L 03/24/21 19:15 87-61-680.0 32.2 40
1,2,4-Trichlorobenzene <25.6 ug/L 03/24/21 19:15 120-82-180.0 25.6 40
1,1,1-Trichloroethane <13.3 ug/L 03/24/21 19:15 71-55-620.0 13.3 40
1,1,2-Trichloroethane <13.0 ug/L 03/24/21 19:15 79-00-520.0 13.0 40
Trichloroethene <15.3 ug/L 03/24/21 19:15 79-01-620.0 15.3 40
Trichlorofluoromethane <11.9 ug/L 03/24/21 19:15 75-69-440.0 11.9 40
1,2,3-Trichloropropane <10.4 ug/L 03/24/21 19:15 96-18-420.0 10.4 40
1,2,4-Trimethylbenzene 1380 ug/L 03/24/21 19:15 95-63-620.0 19.8 40
1,3,5-Trimethylbenzene 465 ug/L 03/24/21 19:15 108-67-820.0 13.3 40
Vinyl chloride <15.4 ug/L 03/24/21 19:15 75-01-440.0 15.4 40
Xylene (Total)6040 ug/L 03/24/21 19:15 1330-20-740.0 13.5 40
m&p-Xylene 3670 ug/L 03/24/21 19:15 179601-23-140.0 28.4 40
o-Xylene 2370 ug/L 03/24/21 19:15 95-47-620.0 13.5 40
Surrogates
1,2-Dichloroethane-d4 (S)97 %03/24/21 19:15 17060-07-070-130 40
4-Bromofluorobenzene (S)96 %03/24/21 19:15 460-00-470-130 40
Toluene-d8 (S)98 %03/24/21 19:15 2037-26-570-130 40
Sample:MW-3 Lab ID:92528786002 Collected:03/17/21 12:10 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 4960J ug/L 03/24/21 19:33 75-85-45000182050
tert-Amylmethyl ether <133 ug/L 03/24/21 19:33 994-05-850013350
Benzene 2840 ug/L 03/24/21 19:33 71-43-225.0 17.2 50
Bromobenzene <14.5 ug/L 03/24/21 19:33 108-86-125.0 14.5 50
Bromochloromethane <23.4 ug/L 03/24/21 19:33 74-97-525.0 23.4 50
Bromodichloromethane <15.4 ug/L 03/24/21 19:33 75-27-425.0 15.4 50
Bromoform <17.0 ug/L 03/24/21 19:33 75-25-225.0 17.0 50
Bromomethane <83.0 ug/L 03/24/21 19:33 74-83-925083.0 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92528786
Williams Grocery
Sample:MW-3 Lab ID:92528786002 Collected:03/17/21 12:10 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
2-Butanone (MEK)<198 ug/L 03/24/21 19:33 78-93-325019850
tert-Butyl Alcohol <1340 ug/L 03/24/21 19:33 75-65-02500134050
n-Butylbenzene <24.5 ug/L 03/24/21 19:33 104-51-825.0 24.5 50
sec-Butylbenzene <20.0 ug/L 03/24/21 19:33 135-98-825.0 20.0 50
tert-Butylbenzene <16.2 ug/L 03/24/21 19:33 98-06-625.0 16.2 50
tert-Butyl Formate <1470 ug/L 03/24/21 19:33 762-75-42500147050
Carbon tetrachloride <16.6 ug/L 03/24/21 19:33 56-23-525.0 16.6 50
Chlorobenzene <14.2 ug/L 03/24/21 19:33 108-90-725.0 14.2 50
Chloroethane <32.4 ug/L 03/24/21 19:33 75-00-350.0 32.4 50
Chloroform <17.6 ug/L 03/24/21 19:33 67-66-325.0 17.6 50
Chloromethane <27.0 ug/L 03/24/21 19:33 74-87-350.0 27.0 50
2-Chlorotoluene <16.0 ug/L 03/24/21 19:33 95-49-825.0 16.0 50
4-Chlorotoluene <16.2 ug/L 03/24/21 19:33 106-43-425.0 16.2 50
1,2-Dibromo-3-chloropropane <17.0 ug/L 03/24/21 19:33 96-12-850.0 17.0 50
Dibromochloromethane <18.0 ug/L 03/24/21 19:33 124-48-125.0 18.0 50
1,2-Dibromoethane (EDB)240 ug/L 03/24/21 19:33 106-93-425.0 13.6 50
Dibromomethane <19.7 ug/L 03/24/21 19:33 74-95-325.0 19.7 50
1,2-Dichlorobenzene <17.0 ug/L 03/24/21 19:33 95-50-125.0 17.0 50
1,3-Dichlorobenzene <17.0 ug/L 03/24/21 19:33 541-73-125.0 17.0 50
1,4-Dichlorobenzene <16.6 ug/L 03/24/21 19:33 106-46-725.0 16.6 50
Dichlorodifluoromethane <17.3 ug/L 03/24/21 19:33 75-71-825.0 17.3 50
1,1-Dichloroethane <18.4 ug/L 03/24/21 19:33 75-34-325.0 18.4 50
1,2-Dichloroethane 65.5 ug/L 03/24/21 19:33 107-06-225.0 16.1 50
1,1-Dichloroethene <17.4 ug/L 03/24/21 19:33 75-35-425.0 17.4 50
cis-1,2-Dichloroethene <19.2 ug/L 03/24/21 19:33 156-59-225.0 19.2 50
trans-1,2-Dichloroethene <19.8 ug/L 03/24/21 19:33 156-60-525.0 19.8 50
1,2-Dichloropropane <17.8 ug/L 03/24/21 19:33 78-87-525.0 17.8 50
1,3-Dichloropropane <14.2 ug/L 03/24/21 19:33 142-28-925.0 14.2 50
2,2-Dichloropropane <19.4 ug/L 03/24/21 19:33 594-20-725.0 19.4 50
1,1-Dichloropropene <21.4 ug/L 03/24/21 19:33 563-58-625.0 21.4 50
cis-1,3-Dichloropropene <18.2 ug/L 03/24/21 19:33 10061-01-525.0 18.2 50
trans-1,3-Dichloropropene <18.2 ug/L 03/24/21 19:33 10061-02-625.0 18.2 50
Diisopropyl ether <15.4 ug/L 03/24/21 19:33 108-20-325.0 15.4 50
Ethanol <3610 ug/L 03/24/21 19:33 64-17-510000361050
Ethylbenzene 442 ug/L 03/24/21 19:33 100-41-425.0 15.2 50
Ethyl-tert-butyl ether <162 ug/L 03/24/21 19:33 637-92-350016250
Hexachloro-1,3-butadiene <76.5 ug/L 03/24/21 19:33 87-68-310076.5 50
2-Hexanone 228J ug/L 03/24/21 19:33 591-78-625023.8 50
Isopropylbenzene (Cumene)27.9 ug/L 03/24/21 19:33 98-82-825.0 16.6 50
Methylene Chloride <97.5 ug/L 03/24/21 19:33 75-09-210097.5 50
Methyl-tert-butyl ether 51.1 ug/L 03/24/21 19:33 1634-04-425.0 21.1 50
Naphthalene 520 ug/L 03/24/21 19:33 91-20-310032.2 50
n-Propylbenzene <17.0 ug/L 03/24/21 19:33 103-65-125.0 17.0 50
Styrene <14.6 ug/L 03/24/21 19:33 100-42-525.0 14.6 50
1,1,1,2-Tetrachloroethane <15.6 ug/L 03/24/21 19:33 630-20-625.0 15.6 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92528786
Williams Grocery
Sample:MW-3 Lab ID:92528786002 Collected:03/17/21 12:10 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane <11.2 ug/L 03/24/21 19:33 79-34-525.0 11.2 50
Tetrachloroethene <14.6 ug/L 03/24/21 19:33 127-18-425.0 14.6 50
Toluene 6020 ug/L 03/24/21 19:33 108-88-325.0 24.2 50
1,2,3-Trichlorobenzene <40.3 ug/L 03/24/21 19:33 87-61-610040.3 50
1,2,4-Trichlorobenzene <32.0 ug/L 03/24/21 19:33 120-82-110032.0 50
1,1,1-Trichloroethane <16.6 ug/L 03/24/21 19:33 71-55-625.0 16.6 50
1,1,2-Trichloroethane <16.2 ug/L 03/24/21 19:33 79-00-525.0 16.2 50
Trichloroethene <19.2 ug/L 03/24/21 19:33 79-01-625.0 19.2 50
Trichlorofluoromethane <14.9 ug/L 03/24/21 19:33 75-69-450.0 14.9 50
1,2,3-Trichloropropane <13.0 ug/L 03/24/21 19:33 96-18-425.0 13.0 50
1,2,4-Trimethylbenzene 1370 ug/L 03/24/21 19:33 95-63-625.0 24.8 50
1,3,5-Trimethylbenzene 588 ug/L 03/24/21 19:33 108-67-825.0 16.6 50
Vinyl chloride <19.3 ug/L 03/24/21 19:33 75-01-450.0 19.3 50
Xylene (Total)5880 ug/L 03/24/21 19:33 1330-20-750.0 16.9 50
m&p-Xylene 2910 ug/L 03/24/21 19:33 179601-23-150.0 35.4 50
o-Xylene 2960 ug/L 03/24/21 19:33 95-47-625.0 16.9 50
Surrogates
1,2-Dichloroethane-d4 (S)93 %03/24/21 19:33 17060-07-070-130 50
4-Bromofluorobenzene (S)94 %03/24/21 19:33 460-00-470-130 50
Toluene-d8 (S)99 %03/24/21 19:33 2037-26-570-130 50
Sample:RW-1 Lab ID:92528786003 Collected:03/17/21 12:25 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <9100 ug/L 03/24/21 02:34 75-85-4250009100250
tert-Amylmethyl ether <665 ug/L 03/24/21 02:34 994-05-82500665250
Benzene 15400 ug/L 03/24/21 02:34 71-43-212586.2 250
Bromobenzene <72.5 ug/L 03/24/21 02:34 108-86-112572.5 250
Bromochloromethane <117 ug/L 03/24/21 02:34 74-97-5125117250
Bromodichloromethane <76.8 ug/L 03/24/21 02:34 75-27-412576.8 250
Bromoform <85.2 ug/L 03/24/21 02:34 75-25-212585.2 250
Bromomethane <415 ug/L 03/24/21 02:34 74-83-91250415250
2-Butanone (MEK)<990 ug/L 03/24/21 02:34 78-93-31250990250
tert-Butyl Alcohol <6700 ug/L 03/24/21 02:34 75-65-0125006700250
n-Butylbenzene <122 ug/L 03/24/21 02:34 104-51-8125122250
sec-Butylbenzene <100 ug/L 03/24/21 02:34 135-98-8125100250
tert-Butylbenzene <80.8 ug/L 03/24/21 02:34 98-06-612580.8 250
tert-Butyl Formate <7350 ug/L 03/24/21 02:34 762-75-4125007350250
Carbon tetrachloride <83.2 ug/L 03/24/21 02:34 56-23-512583.2 250
Chlorobenzene <71.0 ug/L 03/24/21 02:34 108-90-712571.0 250
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92528786
Williams Grocery
Sample:RW-1 Lab ID:92528786003 Collected:03/17/21 12:25 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Chloroethane <162 ug/L 03/24/21 02:34 75-00-3250162250
Chloroform <88.2 ug/L 03/24/21 02:34 67-66-312588.2 250
Chloromethane <135 ug/L 03/24/21 02:34 74-87-3250135250
2-Chlorotoluene <80.2 ug/L 03/24/21 02:34 95-49-812580.2 250
4-Chlorotoluene <81.0 ug/L 03/24/21 02:34 106-43-412581.0 250
1,2-Dibromo-3-chloropropane <85.0 ug/L 03/24/21 02:34 96-12-825085.0 250
Dibromochloromethane <89.8 ug/L 03/24/21 02:34 124-48-112589.8 250
1,2-Dibromoethane (EDB)550 ug/L 03/24/21 02:34 106-93-412568.0 250
Dibromomethane <98.5 ug/L 03/24/21 02:34 74-95-312598.5 250
1,2-Dichlorobenzene <84.8 ug/L 03/24/21 02:34 95-50-112584.8 250
1,3-Dichlorobenzene <85.0 ug/L 03/24/21 02:34 541-73-112585.0 250
1,4-Dichlorobenzene <83.2 ug/L 03/24/21 02:34 106-46-712583.2 250
Dichlorodifluoromethane <86.5 ug/L 03/24/21 02:34 75-71-812586.5 250
1,1-Dichloroethane <91.8 ug/L 03/24/21 02:34 75-34-312591.8 250
1,2-Dichloroethane 408 ug/L 03/24/21 02:34 107-06-212580.5 250
1,1-Dichloroethene <87.0 ug/L 03/24/21 02:34 75-35-412587.0 250
cis-1,2-Dichloroethene <96.0 ug/L 03/24/21 02:34 156-59-212596.0 250
trans-1,2-Dichloroethene <99.0 ug/L 03/24/21 02:34 156-60-512599.0 250
1,2-Dichloropropane <88.8 ug/L 03/24/21 02:34 78-87-512588.8 250
1,3-Dichloropropane <71.0 ug/L 03/24/21 02:34 142-28-912571.0 250
2,2-Dichloropropane <97.0 ug/L 03/24/21 02:34 594-20-712597.0 250
1,1-Dichloropropene <107 ug/L 03/24/21 02:34 563-58-6125107250
cis-1,3-Dichloropropene <91.2 ug/L 03/24/21 02:34 10061-01-512591.2 250
trans-1,3-Dichloropropene <90.8 ug/L 03/24/21 02:34 10061-02-612590.8 250
Diisopropyl ether 142 ug/L 03/24/21 02:34 108-20-312577.0 250
Ethanol <18000 ug/L 03/24/21 02:34 64-17-55000018000250
Ethylbenzene 3800 ug/L 03/24/21 02:34 100-41-412576.0 250
Ethyl-tert-butyl ether <810 ug/L 03/24/21 02:34 637-92-32500810250
Hexachloro-1,3-butadiene <382 ug/L 03/24/21 02:34 87-68-3500382250
2-Hexanone <119 ug/L 03/24/21 02:34 591-78-61250119250
Isopropylbenzene (Cumene)188 ug/L 03/24/21 02:34 98-82-812583.2 250
Methylene Chloride <488 ug/L 03/24/21 02:34 75-09-2500488250
Methyl-tert-butyl ether 717 ug/L 03/24/21 02:34 1634-04-4125106250
Naphthalene 1210 ug/L 03/24/21 02:34 91-20-3500161250
n-Propylbenzene <85.0 ug/L 03/24/21 02:34 103-65-112585.0 250
Styrene 134 ug/L 03/24/21 02:34 100-42-512573.0 250
1,1,1,2-Tetrachloroethane <77.8 ug/L 03/24/21 02:34 630-20-612577.8 250
1,1,2,2-Tetrachloroethane <56.2 ug/L 03/24/21 02:34 79-34-512556.2 250
Tetrachloroethene <73.0 ug/L 03/24/21 02:34 127-18-412573.0 250
Toluene 41400 ug/L 03/24/21 02:34 108-88-3125121250
1,2,3-Trichlorobenzene <202 ug/L 03/24/21 02:34 87-61-6500202250
1,2,4-Trichlorobenzene <160 ug/L 03/24/21 02:34 120-82-1500160250
1,1,1-Trichloroethane <83.0 ug/L 03/24/21 02:34 71-55-612583.0 250
1,1,2-Trichloroethane <81.2 ug/L 03/24/21 02:34 79-00-512581.2 250
Trichloroethene <95.8 ug/L 03/24/21 02:34 79-01-612595.8 250
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92528786
Williams Grocery
Sample:RW-1 Lab ID:92528786003 Collected:03/17/21 12:25 Received:03/19/21 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Trichlorofluoromethane <74.5 ug/L 03/24/21 02:34 75-69-425074.5 250
1,2,3-Trichloropropane <65.2 ug/L 03/24/21 02:34 96-18-412565.2 250
1,2,4-Trimethylbenzene 4870 ug/L 03/24/21 02:34 95-63-6125124250
1,3,5-Trimethylbenzene 1330 ug/L 03/24/21 02:34 108-67-812583.0 250
Vinyl chloride <96.5 ug/L 03/24/21 02:34 75-01-425096.5 250
Xylene (Total)21400 ug/L 03/24/21 02:34 1330-20-725084.5 250
m&p-Xylene 14600 ug/L 03/24/21 02:34 179601-23-1250177250
o-Xylene 6760 ug/L 03/24/21 02:34 95-47-612584.5 250
Surrogates
1,2-Dichloroethane-d4 (S)92 %03/24/21 02:34 17060-07-070-130 250
4-Bromofluorobenzene (S)93 %03/24/21 02:34 460-00-470-130 250
Toluene-d8 (S)98 %03/24/21 02:34 2037-26-570-130 250
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
608547
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92528786003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3205507
Associated Lab Samples:92528786003
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 03/23/21 21:270.31
1,1,1-Trichloroethane ug/L <0.33 0.50 03/23/21 21:270.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 03/23/21 21:270.22
1,1,2-Trichloroethane ug/L <0.32 0.50 03/23/21 21:270.32
1,1-Dichloroethane ug/L <0.37 0.50 03/23/21 21:270.37
1,1-Dichloroethene ug/L <0.35 0.50 03/23/21 21:270.35
1,1-Dichloropropene ug/L <0.43 0.50 03/23/21 21:270.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 03/23/21 21:270.81
1,2,3-Trichloropropane ug/L <0.26 0.50 03/23/21 21:270.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 03/23/21 21:270.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 03/23/21 21:270.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 03/23/21 21:270.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 03/23/21 21:270.27
1,2-Dichlorobenzene ug/L <0.34 0.50 03/23/21 21:270.34
1,2-Dichloroethane ug/L <0.32 0.50 03/23/21 21:270.32
1,2-Dichloropropane ug/L <0.36 0.50 03/23/21 21:270.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 03/23/21 21:270.33
1,3-Dichlorobenzene ug/L <0.34 0.50 03/23/21 21:270.34
1,3-Dichloropropane ug/L <0.28 0.50 03/23/21 21:270.28
1,4-Dichlorobenzene ug/L <0.33 0.50 03/23/21 21:270.33
2,2-Dichloropropane ug/L <0.39 0.50 03/23/21 21:270.39
2-Butanone (MEK)ug/L <4.0 5.0 03/23/21 21:274.0
2-Chlorotoluene ug/L <0.32 0.50 03/23/21 21:270.32
2-Hexanone ug/L <0.48 5.0 03/23/21 21:270.48
4-Chlorotoluene ug/L <0.32 0.50 03/23/21 21:270.32
Benzene ug/L <0.34 0.50 03/23/21 21:270.34
Bromobenzene ug/L <0.29 0.50 03/23/21 21:270.29
Bromochloromethane ug/L <0.47 0.50 03/23/21 21:270.47
Bromodichloromethane ug/L <0.31 0.50 03/23/21 21:270.31
Bromoform ug/L <0.34 0.50 03/23/21 21:270.34
Bromomethane ug/L <1.7 5.0 03/23/21 21:271.7
Carbon tetrachloride ug/L <0.33 0.50 03/23/21 21:270.33
Chlorobenzene ug/L <0.28 0.50 03/23/21 21:270.28
Chloroethane ug/L <0.65 1.0 03/23/21 21:270.65
Chloroform ug/L <0.35 0.50 03/23/21 21:270.35
Chloromethane ug/L <0.54 1.0 03/23/21 21:270.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 03/23/21 21:270.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 03/23/21 21:270.36
Dibromochloromethane ug/L <0.36 0.50 03/23/21 21:270.36
Dibromomethane ug/L <0.39 0.50 03/23/21 21:270.39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3205507
Associated Lab Samples:92528786003
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L <0.35 0.50 03/23/21 21:270.35
Diisopropyl ether ug/L <0.31 0.50 03/23/21 21:270.31
Ethanol ug/L <72.2 200 03/23/21 21:2772.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 03/23/21 21:273.2
Ethylbenzene ug/L <0.30 0.50 03/23/21 21:270.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 03/23/21 21:271.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 03/23/21 21:270.33
m&p-Xylene ug/L <0.71 1.0 03/23/21 21:270.71
Methyl-tert-butyl ether ug/L <0.42 0.50 03/23/21 21:270.42
Methylene Chloride ug/L <2.0 2.0 03/23/21 21:272.0
n-Butylbenzene ug/L <0.49 0.50 03/23/21 21:270.49
n-Propylbenzene ug/L <0.34 0.50 03/23/21 21:270.34
Naphthalene ug/L <0.64 2.0 03/23/21 21:270.64
o-Xylene ug/L <0.34 0.50 03/23/21 21:270.34
sec-Butylbenzene ug/L <0.40 0.50 03/23/21 21:270.40
Styrene ug/L <0.29 0.50 03/23/21 21:270.29
tert-Amyl Alcohol ug/L <36.4 100 03/23/21 21:2736.4
tert-Amylmethyl ether ug/L <2.7 10.0 03/23/21 21:272.7
tert-Butyl Alcohol ug/L <26.8 50.0 03/23/21 21:2726.8
tert-Butyl Formate ug/L <29.4 50.0 03/23/21 21:2729.4
tert-Butylbenzene ug/L <0.32 0.50 03/23/21 21:270.32
Tetrachloroethene ug/L <0.29 0.50 03/23/21 21:270.29
Toluene ug/L <0.48 0.50 03/23/21 21:270.48
trans-1,2-Dichloroethene ug/L <0.40 0.50 03/23/21 21:270.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 03/23/21 21:270.36
Trichloroethene ug/L <0.38 0.50 03/23/21 21:270.38
Trichlorofluoromethane ug/L <0.30 1.0 03/23/21 21:270.30
Vinyl chloride ug/L <0.39 1.0 03/23/21 21:270.39
Xylene (Total)ug/L <0.34 1.0 03/23/21 21:270.34
1,2-Dichloroethane-d4 (S)%91 70-130 03/23/21 21:27
4-Bromofluorobenzene (S)%92 70-130 03/23/21 21:27
Toluene-d8 (S)%99 70-130 03/23/21 21:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3205508LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.850 96 60-140
1,1,1-Trichloroethane ug/L 43.850 88 60-140
1,1,2,2-Tetrachloroethane ug/L 45.250 90 60-140
1,1,2-Trichloroethane ug/L 48.450 97 60-140
1,1-Dichloroethane ug/L 42.150 84 60-140
1,1-Dichloroethene ug/L 45.050 90 60-140
1,1-Dichloropropene ug/L 44.450 89 60-140
1,2,3-Trichlorobenzene ug/L 48.750 97 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3205508LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,3-Trichloropropane ug/L 46.950 94 60-140
1,2,4-Trichlorobenzene ug/L 49.650 99 60-140
1,2,4-Trimethylbenzene ug/L 45.450 91 60-140
1,2-Dibromo-3-chloropropane ug/L 45.750 91 60-140
1,2-Dibromoethane (EDB)ug/L 47.250 94 60-140
1,2-Dichlorobenzene ug/L 48.850 98 60-140
1,2-Dichloroethane ug/L 40.550 81 60-140
1,2-Dichloropropane ug/L 44.350 89 60-140
1,3,5-Trimethylbenzene ug/L 44.750 89 60-140
1,3-Dichlorobenzene ug/L 48.950 98 60-140
1,3-Dichloropropane ug/L 45.150 90 60-140
1,4-Dichlorobenzene ug/L 49.150 98 60-140
2,2-Dichloropropane ug/L 44.250 88 60-140
2-Butanone (MEK)ug/L 77.8100 78 60-140
2-Chlorotoluene ug/L 45.250 90 60-140
2-Hexanone ug/L 81.9100 82 60-140
4-Chlorotoluene ug/L 44.150 88 60-140
Benzene ug/L 46.050 92 60-140
Bromobenzene ug/L 45.750 91 60-140
Bromochloromethane ug/L 47.650 95 60-140
Bromodichloromethane ug/L 43.750 87 60-140
Bromoform ug/L 46.850 94 60-140
Bromomethane ug/L 51.050 102 60-140
Carbon tetrachloride ug/L 49.150 98 60-140
Chlorobenzene ug/L 48.750 97 60-140
Chloroethane ug/L 44.350 89 60-140
Chloroform ug/L 42.550 85 60-140
Chloromethane ug/L 38.450 77 60-140
cis-1,2-Dichloroethene ug/L 42.350 85 60-140
cis-1,3-Dichloropropene ug/L 46.950 94 60-140
Dibromochloromethane ug/L 48.350 97 60-140
Dibromomethane ug/L 50.250 100 60-140
Dichlorodifluoromethane ug/L 49.350 99 60-140
Diisopropyl ether ug/L 38.650 77 60-140
Ethanol ug/L 15702000 78 60-140
Ethyl-tert-butyl ether ug/L 87.9100 88 60-140
Ethylbenzene ug/L 46.950 94 60-140
Hexachloro-1,3-butadiene ug/L 45.350 91 60-140
Isopropylbenzene (Cumene)ug/L 48.450 97 60-140
m&p-Xylene ug/L 94.5100 95 60-140
Methyl-tert-butyl ether ug/L 42.450 85 60-140
Methylene Chloride ug/L 43.050 86 60-140
n-Butylbenzene ug/L 46.050 92 60-140
n-Propylbenzene ug/L 43.950 88 60-140
Naphthalene ug/L 48.950 98 60-140
o-Xylene ug/L 47.450 95 60-140
sec-Butylbenzene ug/L 45.650 91 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3205508LABORATORY CONTROL SAMPLE:
LCSSpike
Styrene ug/L 48.550 97 60-140
tert-Amyl Alcohol ug/L 9281000 93 60-140
tert-Amylmethyl ether ug/L 95.2100 95 60-140
tert-Butyl Alcohol ug/L 396500 79 60-140
tert-Butyl Formate ug/L 362400 90 60-140
tert-Butylbenzene ug/L 38.250 76 60-140
Tetrachloroethene ug/L 49.150 98 60-140
Toluene ug/L 48.350 97 60-140
trans-1,2-Dichloroethene ug/L 43.950 88 60-140
trans-1,3-Dichloropropene ug/L 46.450 93 60-140
Trichloroethene ug/L 50.950 102 60-140
Trichlorofluoromethane ug/L 50.150 100 60-140
Vinyl chloride ug/L 43.250 86 60-140
Xylene (Total)ug/L 142150 95 60-140
1,2-Dichloroethane-d4 (S)%88 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3205509MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92528786003
3205510
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 5000 99 60-14098 1 305000<77.8 4940 4910
1,1,1-Trichloroethane ug/L 5000 94 60-14095 2 305000<83.0 4690 4770
1,1,2,2-Tetrachloroethane ug/L 5000 91 60-14091 0 305000<56.2 4550 4530
1,1,2-Trichloroethane ug/L 5000 97 60-140100 2 305000<81.2 4870 4980
1,1-Dichloroethane ug/L 5000 89 60-14091 3 305000<91.8 4440 4560
1,1-Dichloroethene ug/L 5000 99 60-14099 0 305000<87.0 4930 4950
1,1-Dichloropropene ug/L 5000 93 60-14094 1 305000<107 4650 4700
1,2,3-Trichlorobenzene ug/L 5000 100 60-14098 2 305000<202 4990 4910
1,2,3-Trichloropropane ug/L 5000 94 60-14094 0 305000<65.2 4720 4700
1,2,4-Trichlorobenzene ug/L 5000 101 60-140100 1 305000<160 5050 5020
1,2,4-Trimethylbenzene ug/L 5000 104 60-140103 1 30500048701010010000
1,2-Dibromo-3-
chloropropane ug/L 5000 94 60-14092 2 305000<85.0 4710 4610
1,2-Dibromoethane (EDB)ug/L 5000 98 60-14097 1 30500055054605410
1,2-Dichlorobenzene ug/L 5000 103 60-140101 2 305000<84.8 5130 5030
1,2-Dichloroethane ug/L 5000 82 60-14084 2 30500040845204600
1,2-Dichloropropane ug/L 5000 92 60-14090 2 305000<88.8 4600 4500
1,3,5-Trimethylbenzene ug/L 5000 98 60-14097 1 305000133062106160
1,3-Dichlorobenzene ug/L 5000 104 60-140102 2 305000<85.0 5210 5090
1,3-Dichloropropane ug/L 5000 93 60-14093 0 305000<71.0 4630 4640
1,4-Dichlorobenzene ug/L 5000 104 60-140103 1 305000<83.2 5210 5140
2,2-Dichloropropane ug/L 5000 77 60-14078 0 305000<97.0 3870 3880
2-Butanone (MEK)ug/L 10000 76 60-14076 0 3010000<990 7590 7590
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3205509MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92528786003
3205510
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Chlorotoluene ug/L 5000 100 60-14098 2 305000<80.2 5000 4890
2-Hexanone ug/L 10000 86 60-14084 2 3010000<119 8560 8390
4-Chlorotoluene ug/L 5000 95 60-14093 2 305000<81.0 4750 4670
Benzene ug/L 5000 100 60-14097 1 305000154002040020300
Bromobenzene ug/L 5000 99 60-14097 2 305000<72.5 4940 4830
Bromochloromethane ug/L 5000 98 60-140100 1 305000<117 4920 4990
Bromodichloromethane ug/L 5000 89 60-14089 1 305000<76.8 4470 4440
Bromoform ug/L 5000 93 60-14092 1 305000<85.2 4650 4580
Bromomethane ug/L 5000 108 60-140120 11 305000<415 5390 6020
Carbon tetrachloride ug/L 5000 106 60-140110 4 305000<83.2 5300 5500
Chlorobenzene ug/L 5000 103 60-140102 1 305000<71.0 5150 5110
Chloroethane ug/L 5000 118 60-140121 3 305000<162 5880 6040
Chloroform ug/L 5000 89 60-14089 0 305000<88.2 4460 4460
Chloromethane ug/L 5000 84 60-14083 1 305000<135 4190 4160
cis-1,2-Dichloroethene ug/L 5000 88 60-14089 1 305000<96.0 4390 4440
cis-1,3-Dichloropropene ug/L 5000 90 60-14092 2 305000<91.2 4520 4610
Dibromochloromethane ug/L 5000 97 60-14098 1 305000<89.8 4830 4890
Dibromomethane ug/L 5000 102 60-140104 2 305000<98.5 5080 5180
Dichlorodifluoromethane ug/L 5000 105 60-140106 1 305000<86.5 5260 5290
Diisopropyl ether ug/L 5000 79 60-14081 2 30500014241004180
Ethanol ug/L 200000 98 60-14077 24 30200000<18000 196000 154000
Ethyl-tert-butyl ether ug/L 10000 89 60-14090 2 3010000<810 8880 9040
Ethylbenzene ug/L 5000 102 60-140102 0 305000380089208880
Hexachloro-1,3-butadiene ug/L 5000 99 60-14095 4 305000<382 4950 4760
Isopropylbenzene
(Cumene)
ug/L 5000 104 60-140103 1 30500018854005350
m&p-Xylene ug/L 10000 103 60-140103 0 3010000146002500024900
Methyl-tert-butyl ether ug/L 5000 86 60-14090 4 30500071750305210
Methylene Chloride ug/L 5000 93 60-14092 0 305000<488 4630 4600
n-Butylbenzene ug/L 5000 102 60-140102 1 305000<122 5120 5090
n-Propylbenzene ug/L 5000 108 60-140106 2 305000<85.0 5390 5280
Naphthalene ug/L 5000 107 60-140106 1 305000121065606510
o-Xylene ug/L 5000 104 60-140103 0 30500067601200011900
sec-Butylbenzene ug/L 5000 103 60-14099 4 305000<100 5150 4970
Styrene ug/L 5000 101 60-140100 1 30500013452005160
tert-Amyl Alcohol ug/L 100000 99 60-140100 1 30100000<9100 98600 99600
tert-Amylmethyl ether ug/L 10000 96 60-14098 2 3010000<665 9630 9840
tert-Butyl Alcohol ug/L 50000 84 60-14083 1 3050000<6700 42200 41600
tert-Butyl Formate ug/L 40000 88 60-14089 2 3040000<7350 35100 35700
tert-Butylbenzene ug/L 5000 86 60-14083 3 305000<80.8 4290 4150
Tetrachloroethene ug/L 5000 107 60-140102 5 305000<73.0 5350 5110
Toluene ug/L 5000 80 60-14091 1 305000414004540046000
trans-1,2-Dichloroethene ug/L 5000 92 60-14093 0 305000<99.0 4620 4630
trans-1,3-Dichloropropene ug/L 5000 89 60-14090 1 305000<90.8 4450 4500
Trichloroethene ug/L 5000 107 60-140109 2 305000<95.8 5330 5440
Trichlorofluoromethane ug/L 5000 123 60-140126 3 305000<74.5 6140 6320
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3205509MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92528786003
3205510
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Vinyl chloride ug/L 5000 93 60-14092 1 305000<96.5 4660 4610
Xylene (Total)ug/L 15000 104 60-140103 0 3015000214003690036800
1,2-Dichloroethane-d4 (S)%92 70-13094
4-Bromofluorobenzene (S)%97 70-13096
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
608833
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92528786001, 92528786002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3206735
Associated Lab Samples:92528786001, 92528786002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 03/24/21 10:500.31
1,1,1-Trichloroethane ug/L <0.33 0.50 03/24/21 10:500.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 03/24/21 10:500.22
1,1,2-Trichloroethane ug/L <0.32 0.50 03/24/21 10:500.32
1,1-Dichloroethane ug/L <0.37 0.50 03/24/21 10:500.37
1,1-Dichloroethene ug/L <0.35 0.50 03/24/21 10:500.35
1,1-Dichloropropene ug/L <0.43 0.50 03/24/21 10:500.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 03/24/21 10:500.81
1,2,3-Trichloropropane ug/L <0.26 0.50 03/24/21 10:500.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 03/24/21 10:500.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 03/24/21 10:500.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 03/24/21 10:500.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 03/24/21 10:500.27
1,2-Dichlorobenzene ug/L <0.34 0.50 03/24/21 10:500.34
1,2-Dichloroethane ug/L <0.32 0.50 03/24/21 10:500.32
1,2-Dichloropropane ug/L <0.36 0.50 03/24/21 10:500.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 03/24/21 10:500.33
1,3-Dichlorobenzene ug/L <0.34 0.50 03/24/21 10:500.34
1,3-Dichloropropane ug/L <0.28 0.50 03/24/21 10:500.28
1,4-Dichlorobenzene ug/L <0.33 0.50 03/24/21 10:500.33
2,2-Dichloropropane ug/L <0.39 0.50 03/24/21 10:500.39
2-Butanone (MEK)ug/L <4.0 5.0 03/24/21 10:504.0
2-Chlorotoluene ug/L <0.32 0.50 03/24/21 10:500.32
2-Hexanone ug/L <0.48 5.0 03/24/21 10:500.48
4-Chlorotoluene ug/L <0.32 0.50 03/24/21 10:500.32
Benzene ug/L <0.34 0.50 03/24/21 10:500.34
Bromobenzene ug/L <0.29 0.50 03/24/21 10:500.29
Bromochloromethane ug/L <0.47 0.50 03/24/21 10:500.47
Bromodichloromethane ug/L <0.31 0.50 03/24/21 10:500.31
Bromoform ug/L <0.34 0.50 03/24/21 10:500.34
Bromomethane ug/L <1.7 5.0 03/24/21 10:501.7
Carbon tetrachloride ug/L <0.33 0.50 03/24/21 10:500.33
Chlorobenzene ug/L <0.28 0.50 03/24/21 10:500.28
Chloroethane ug/L <0.65 1.0 03/24/21 10:500.65
Chloroform ug/L <0.35 0.50 03/24/21 10:500.35
Chloromethane ug/L <0.54 1.0 03/24/21 10:500.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 03/24/21 10:500.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 03/24/21 10:500.36
Dibromochloromethane ug/L <0.36 0.50 03/24/21 10:500.36
Dibromomethane ug/L <0.39 0.50 03/24/21 10:500.39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3206735
Associated Lab Samples:92528786001, 92528786002
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L <0.35 0.50 03/24/21 10:500.35
Diisopropyl ether ug/L <0.31 0.50 03/24/21 10:500.31
Ethanol ug/L <72.2 200 03/24/21 10:5072.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 03/24/21 10:503.2
Ethylbenzene ug/L <0.30 0.50 03/24/21 10:500.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 03/24/21 10:501.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 03/24/21 10:500.33
m&p-Xylene ug/L <0.71 1.0 03/24/21 10:500.71
Methyl-tert-butyl ether ug/L <0.42 0.50 03/24/21 10:500.42
Methylene Chloride ug/L <2.0 2.0 03/24/21 10:502.0
n-Butylbenzene ug/L <0.49 0.50 03/24/21 10:500.49
n-Propylbenzene ug/L <0.34 0.50 03/24/21 10:500.34
Naphthalene ug/L <0.64 2.0 03/24/21 10:500.64
o-Xylene ug/L <0.34 0.50 03/24/21 10:500.34
sec-Butylbenzene ug/L <0.40 0.50 03/24/21 10:500.40
Styrene ug/L <0.29 0.50 03/24/21 10:500.29
tert-Amyl Alcohol ug/L <36.4 100 03/24/21 10:5036.4
tert-Amylmethyl ether ug/L <2.7 10.0 03/24/21 10:502.7
tert-Butyl Alcohol ug/L <26.8 50.0 03/24/21 10:5026.8
tert-Butyl Formate ug/L <29.4 50.0 03/24/21 10:5029.4
tert-Butylbenzene ug/L <0.32 0.50 03/24/21 10:500.32
Tetrachloroethene ug/L <0.29 0.50 03/24/21 10:500.29
Toluene ug/L <0.48 0.50 03/24/21 10:500.48
trans-1,2-Dichloroethene ug/L <0.40 0.50 03/24/21 10:500.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 03/24/21 10:500.36
Trichloroethene ug/L <0.38 0.50 03/24/21 10:500.38
Trichlorofluoromethane ug/L <0.30 1.0 03/24/21 10:500.30
Vinyl chloride ug/L <0.39 1.0 03/24/21 10:500.39
Xylene (Total)ug/L <0.34 1.0 03/24/21 10:500.34
1,2-Dichloroethane-d4 (S)%93 70-130 03/24/21 10:50
4-Bromofluorobenzene (S)%93 70-130 03/24/21 10:50
Toluene-d8 (S)%99 70-130 03/24/21 10:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3206736LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.250 94 60-140
1,1,1-Trichloroethane ug/L 43.450 87 60-140
1,1,2,2-Tetrachloroethane ug/L 45.050 90 60-140
1,1,2-Trichloroethane ug/L 47.350 95 60-140
1,1-Dichloroethane ug/L 42.450 85 60-140
1,1-Dichloroethene ug/L 44.450 89 60-140
1,1-Dichloropropene ug/L 43.550 87 60-140
1,2,3-Trichlorobenzene ug/L 49.150 98 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3206736LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,3-Trichloropropane ug/L 47.950 96 60-140
1,2,4-Trichlorobenzene ug/L 49.450 99 60-140
1,2,4-Trimethylbenzene ug/L 45.150 90 60-140
1,2-Dibromo-3-chloropropane ug/L 48.050 96 60-140
1,2-Dibromoethane (EDB)ug/L 46.650 93 60-140
1,2-Dichlorobenzene ug/L 48.150 96 60-140
1,2-Dichloroethane ug/L 39.950 80 60-140
1,2-Dichloropropane ug/L 43.750 87 60-140
1,3,5-Trimethylbenzene ug/L 44.050 88 60-140
1,3-Dichlorobenzene ug/L 48.450 97 60-140
1,3-Dichloropropane ug/L 44.250 88 60-140
1,4-Dichlorobenzene ug/L 49.050 98 60-140
2,2-Dichloropropane ug/L 46.250 92 60-140
2-Butanone (MEK)ug/L 81.8100 82 60-140
2-Chlorotoluene ug/L 44.050 88 60-140
2-Hexanone ug/L 85.3100 85 60-140
4-Chlorotoluene ug/L 44.050 88 60-140
Benzene ug/L 44.950 90 60-140
Bromobenzene ug/L 45.450 91 60-140
Bromochloromethane ug/L 48.150 96 60-140
Bromodichloromethane ug/L 42.350 85 60-140
Bromoform ug/L 46.550 93 60-140
Bromomethane ug/L 47.350 95 60-140
Carbon tetrachloride ug/L 48.250 96 60-140
Chlorobenzene ug/L 47.950 96 60-140
Chloroethane ug/L 42.650 85 60-140
Chloroform ug/L 41.850 84 60-140
Chloromethane ug/L 40.850 82 60-140
cis-1,2-Dichloroethene ug/L 41.250 82 60-140
cis-1,3-Dichloropropene ug/L 46.250 92 60-140
Dibromochloromethane ug/L 47.650 95 60-140
Dibromomethane ug/L 48.850 98 60-140
Dichlorodifluoromethane ug/L 50.450 101 60-140
Diisopropyl ether ug/L 38.250 76 60-140
Ethanol ug/L 16902000 84 60-140
Ethyl-tert-butyl ether ug/L 86.1100 86 60-140
Ethylbenzene ug/L 46.450 93 60-140
Hexachloro-1,3-butadiene ug/L 46.750 93 60-140
Isopropylbenzene (Cumene)ug/L 48.050 96 60-140
m&p-Xylene ug/L 93.5100 93 60-140
Methyl-tert-butyl ether ug/L 42.650 85 60-140
Methylene Chloride ug/L 41.850 84 60-140
n-Butylbenzene ug/L 46.350 93 60-140
n-Propylbenzene ug/L 43.950 88 60-140
Naphthalene ug/L 49.650 99 60-140
o-Xylene ug/L 46.750 93 60-140
sec-Butylbenzene ug/L 45.850 92 60-140
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3206736LABORATORY CONTROL SAMPLE:
LCSSpike
Styrene ug/L 47.750 95 60-140
tert-Amyl Alcohol ug/L 9731000 97 60-140
tert-Amylmethyl ether ug/L 93.5100 94 60-140
tert-Butyl Alcohol ug/L 424500 85 60-140
tert-Butyl Formate ug/L 360400 90 60-140
tert-Butylbenzene ug/L 38.450 77 60-140
Tetrachloroethene ug/L 48.950 98 60-140
Toluene ug/L 47.150 94 60-140
trans-1,2-Dichloroethene ug/L 42.950 86 60-140
trans-1,3-Dichloropropene ug/L 45.550 91 60-140
Trichloroethene ug/L 50.250 100 60-140
Trichlorofluoromethane ug/L 47.650 95 60-140
Vinyl chloride ug/L 43.350 87 60-140
Xylene (Total)ug/L 140150 93 60-140
1,2-Dichloroethane-d4 (S)%90 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3206737MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92528948006
3206738
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 250 99 60-14099 0 30250ND248248
1,1,1-Trichloroethane ug/L 250 95 60-14094 1 30250ND237235
1,1,2,2-Tetrachloroethane ug/L 250 91 60-14090 0 30250ND226226
1,1,2-Trichloroethane ug/L 250 96 60-14098 3 30250ND240246
1,1-Dichloroethane ug/L 250 92 60-14090 2 30250ND230226
1,1-Dichloroethene ug/L 250 97 60-14096 1 30250ND243241
1,1-Dichloropropene ug/L 250 94 60-14093 1 30250ND234232
1,2,3-Trichlorobenzene ug/L 250 85 60-14092 8 30250ND212230
1,2,3-Trichloropropane ug/L 250 94 60-14091 3 30250ND234228
1,2,4-Trichlorobenzene ug/L 250 89 60-14094 5 30250ND222235
1,2,4-Trimethylbenzene ug/L 250 91 60-14092 1 30250ND233235
1,2-Dibromo-3-
chloropropane ug/L 250 90 60-14090 0 30250ND224224
1,2-Dibromoethane (EDB)ug/L 250 96 60-14095 1 30250ND241239
1,2-Dichlorobenzene ug/L 250 94 60-14098 4 30250ND235244
1,2-Dichloroethane ug/L 250 83 60-14083 0 30250ND211211
1,2-Dichloropropane ug/L 250 90 60-14094 4 30250ND224234
1,3,5-Trimethylbenzene ug/L 250 92 60-14094 2 30250ND235240
1,3-Dichlorobenzene ug/L 250 96 60-14099 3 30250ND240247
1,3-Dichloropropane ug/L 250 93 60-14092 1 30250ND232231
1,4-Dichlorobenzene ug/L 250 96 60-14098 3 30250ND239246
2,2-Dichloropropane ug/L 250 84 60-14082 3 30250ND211205
2-Butanone (MEK)ug/L 500 78 60-14076 2 30500ND388381
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3206737MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92528948006
3206738
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Chlorotoluene ug/L 250 90 60-14093 4 30250ND224233
2-Hexanone ug/L 500 82 60-14081 1 30500ND410404
4-Chlorotoluene ug/L 250 89 60-14089 1 30250ND222224
Benzene ug/L 250 93 60-140110 2 30250178020102060
Bromobenzene ug/L 250 94 60-14097 3 30250ND235242
Bromochloromethane ug/L 250 99 60-14098 2 30250ND248244
Bromodichloromethane ug/L 250 89 60-14091 1 30250ND224227
Bromoform ug/L 250 92 60-14091 1 30250ND231228
Bromomethane ug/L 250 94 60-14099 4 30250ND236247
Carbon tetrachloride ug/L 250 106 60-140107 0 30250ND266267
Chlorobenzene ug/L 250 103 60-140103 0 30250ND256258
Chloroethane ug/L 250 129 60-140126 2 30250ND322316
Chloroform ug/L 250 90 60-14090 1 30250ND226225
Chloromethane ug/L 250 76 60-14082 8 30250ND190205
cis-1,2-Dichloroethene ug/L 250 89 60-14088 1 30250ND222219
cis-1,3-Dichloropropene ug/L 250 92 60-14093 1 30250ND231233
Dibromochloromethane ug/L 250 98 60-14098 1 30250ND245244
Dibromomethane ug/L 250 105 60-140104 1 30250ND263259
Dichlorodifluoromethane ug/L 250 101 60-140101 0 30250ND252252
Diisopropyl ether ug/L 250 79 60-14078 1 302508.1 206 204
Ethanol ug/L 10000 70 60-14082 16 3010000ND69908200
Ethyl-tert-butyl ether ug/L 500 88 60-14088 1 30500ND441438
Ethylbenzene ug/L 250 100 60-140100 1 302509.6 259 260
Hexachloro-1,3-butadiene ug/L 250 92 60-14096 4 30250ND231241
Isopropylbenzene
(Cumene)
ug/L 250 103 60-140104 1 3025018.7 276 278
m&p-Xylene ug/L 500 99 60-140100 0 30500ND505507
Methyl-tert-butyl ether ug/L 250 86 60-14086 0 3025084.7 301 299
Methylene Chloride ug/L 250 89 60-14089 0 30250ND223222
n-Butylbenzene ug/L 250 90 60-14093 3 30250ND232239
n-Propylbenzene ug/L 250 92 60-14093 2 3025012.3 242 245
Naphthalene ug/L 250 77 60-14081 4 30250ND215225
o-Xylene ug/L 250 99 60-140100 1 30250ND250251
sec-Butylbenzene ug/L 250 97 60-140101 4 30250ND243252
Styrene ug/L 250 95 60-14096 0 30250ND238239
tert-Amyl Alcohol ug/L 5000 92 60-14093 0 305000ND57705790
tert-Amylmethyl ether ug/L 500 95 60-14096 1 30500ND475479
tert-Butyl Alcohol ug/L 2500 96 60-14095 1 302500ND25602540
tert-Butyl Formate ug/L P520005260-14050 4 302000ND10401010
tert-Butylbenzene ug/L 250 82 60-14084 3 30250ND205210
Tetrachloroethene ug/L 250 105 60-140103 2 30250ND262256
Toluene ug/L 250 103 60-140102 1 302508.7 266 264
trans-1,2-Dichloroethene ug/L 250 92 60-14091 1 30250ND230227
trans-1,3-Dichloropropene ug/L 250 90 60-14091 1 30250ND224227
Trichloroethene ug/L 250 109 60-140110 1 30250ND273275
Trichlorofluoromethane ug/L 250 128 60-140127 1 30250ND320317
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92528786
Williams Grocery
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3206737MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92528948006
3206738
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Vinyl chloride ug/L 250 89 60-14089 0 30250ND222223
Xylene (Total)ug/L 750 101 60-140101 0 30750ND755758
1,2-Dichloroethane-d4 (S)%93 70-13092
4-Bromofluorobenzene (S)%97 70-13096
Toluene-d8 (S)%97 70-13098
REPORT OF LABORATORY ANALYSIS
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Page 22 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92528786
Williams Grocery
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.P5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/25/2021 05:01 PM
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Page 23 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92528786
Williams Grocery
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92528786001 608833MW-1 SM 6200B
92528786002 608833MW-3 SM 6200B
92528786003 608547RW-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
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Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27
#=CL#
April 07, 2021
LIMS USE: FR - NOELLE FRANCE
LIMS OBJECT ID: 92531085
92531085
Project:
Pace Project No.:
RE:
Noelle France
ATC Group Services LLC- South Charlotte
7606 Whitehall Exe Center Dr
Suite 800
Charlotte, NC 28273
WILLIAMS GROCERY
Dear Noelle France:
Enclosed are the analytical results for sample(s) received by the laboratory on April 02, 2021. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
[phone]
Enclosures
cc:Al Quarles, ATC
REPORT OF LABORATORY ANALYSIS
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Page 1 of 47
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 2 of 47
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Lab ID Sample ID Matrix Date Collected Date Received
92531085001 MW-1 Water 04/02/21 12:00 04/02/21 17:34
92531085002 MW-3 Water 04/02/21 13:15 04/02/21 17:34
92531085003 MW-5 Water 04/02/21 14:15 04/02/21 17:34
92531085004 MW-12 Water 04/02/21 11:30 04/02/21 17:34
92531085005 AS-1 Water 04/02/21 12:30 04/02/21 17:34
92531085006 TRIP BLANK Water 04/02/21 00:00 04/02/21 17:34
92531085007 WSW-1 Water 04/02/21 14:30 04/02/21 17:34
92531085008 WSW-2 Water 04/02/21 15:50 04/02/21 17:34
92531085009 WSW-6 Water 04/02/21 15:10 04/02/21 17:34
92531085010 WSW-7 Water 04/02/21 15:40 04/02/21 17:34
92531085011 FB-1 Water 04/02/21 14:30 04/02/21 17:34
REPORT OF LABORATORY ANALYSIS
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Page 3 of 47
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92531085001 MW-1 SM 6200B 70 PASI-CSAS
92531085002 MW-3 SM 6200B 70 PASI-CSAS
92531085003 MW-5 SM 6200B 70 PASI-CSAS
92531085004 MW-12 SM 6200B 70 PASI-CSAS
92531085005 AS-1 SM 6200B 70 PASI-CSAS
92531085006 TRIP BLANK SM 6200B 70 PASI-CSAS
92531085007 WSW-1 EPA 504.1 2 PASI-CBAJ
SM 6200B 70 PASI-CSAS
92531085008 WSW-2 EPA 504.1 2 PASI-CBAJ
SM 6200B 70 PASI-CSAS
92531085009 WSW-6 EPA 504.1 2 PASI-CBAJ
SM 6200B 70 PASI-CSAS
92531085010 WSW-7 EPA 504.1 2 PASI-CBAJ
SM 6200B 70 PASI-CSAS
92531085011 FB-1 EPA 504.1 2 PASI-CBAJ
SM 6200B 70 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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Page 4 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-1 Lab ID:92531085001 Collected:04/02/21 12:00 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 12600 ug/L 04/06/21 17:02 75-85-4125004550125
tert-Amylmethyl ether <332 ug/L 04/06/21 17:02 994-05-81250332125
Benzene 15100 ug/L 04/06/21 17:02 71-43-262.5 43.1 125
Bromobenzene <36.2 ug/L 04/06/21 17:02 108-86-162.5 36.2 125
Bromochloromethane <58.5 ug/L 04/06/21 17:02 74-97-562.5 58.5 125
Bromodichloromethane <38.4 ug/L 04/06/21 17:02 75-27-462.5 38.4 125
Bromoform <42.6 ug/L 04/06/21 17:02 75-25-262.5 42.6 125
Bromomethane <208 ug/L 04/06/21 17:02 74-83-9625208125
tert-Butyl Alcohol 16000 ug/L 04/06/21 17:02 75-65-062503350125
n-Butylbenzene <61.2 ug/L 04/06/21 17:02 104-51-862.5 61.2 125
sec-Butylbenzene <50.0 ug/L 04/06/21 17:02 135-98-862.5 50.0 125
tert-Butylbenzene <40.4 ug/L 04/06/21 17:02 98-06-662.5 40.4 125
tert-Butyl Formate <3680 ug/L 04/06/21 17:02 762-75-462503680125
Carbon tetrachloride <41.6 ug/L 04/06/21 17:02 56-23-562.5 41.6 125
Chlorobenzene <35.5 ug/L 04/06/21 17:02 108-90-762.5 35.5 125
Chloroethane <81.1 ug/L 04/06/21 17:02 75-00-312581.1 125
Chloroform <44.1 ug/L 04/06/21 17:02 67-66-362.5 44.1 125
Chloromethane <67.5 ug/L 04/06/21 17:02 74-87-312567.5 125
2-Chlorotoluene <40.1 ug/L 04/06/21 17:02 95-49-862.5 40.1 125
4-Chlorotoluene <40.5 ug/L 04/06/21 17:02 106-43-462.5 40.5 125
1,2-Dibromo-3-chloropropane <42.5 ug/L 04/06/21 17:02 96-12-812542.5 125
Dibromochloromethane <44.9 ug/L 04/06/21 17:02 124-48-162.5 44.9 125
1,2-Dibromoethane (EDB)809 ug/L 04/06/21 17:02 106-93-462.5 34.0 125
Dibromomethane <49.2 ug/L 04/06/21 17:02 74-95-362.5 49.2 125
1,2-Dichlorobenzene <42.4 ug/L 04/06/21 17:02 95-50-162.5 42.4 125
1,3-Dichlorobenzene <42.5 ug/L 04/06/21 17:02 541-73-162.5 42.5 125
1,4-Dichlorobenzene <41.6 ug/L 04/06/21 17:02 106-46-762.5 41.6 125
Dichlorodifluoromethane <43.2 ug/L 04/06/21 17:02 75-71-862.5 43.2 125
1,1-Dichloroethane <45.9 ug/L 04/06/21 17:02 75-34-362.5 45.9 125
1,2-Dichloroethane 1060 ug/L 04/06/21 17:02 107-06-262.5 40.2 125
1,1-Dichloroethene <43.5 ug/L 04/06/21 17:02 75-35-462.5 43.5 125
cis-1,2-Dichloroethene <48.0 ug/L 04/06/21 17:02 156-59-262.5 48.0 125
trans-1,2-Dichloroethene <49.5 ug/L 04/06/21 17:02 156-60-562.5 49.5 125
1,2-Dichloropropane <44.4 ug/L 04/06/21 17:02 78-87-562.5 44.4 125
1,3-Dichloropropane <35.5 ug/L 04/06/21 17:02 142-28-962.5 35.5 125
2,2-Dichloropropane <48.5 ug/L 04/06/21 17:02 594-20-762.5 48.5 125
1,1-Dichloropropene <53.4 ug/L 04/06/21 17:02 563-58-662.5 53.4 125
cis-1,3-Dichloropropene <45.6 ug/L 04/06/21 17:02 10061-01-562.5 45.6 125
trans-1,3-Dichloropropene <45.4 ug/L 04/06/21 17:02 10061-02-662.5 45.4 125
Diisopropyl ether 291 ug/L 04/06/21 17:02 108-20-362.5 38.5 125
Ethanol <9020 ug/L 04/06/21 17:02 64-17-5250009020125
Ethylbenzene 1730 ug/L 04/06/21 17:02 100-41-462.5 38.0 125
Ethyl-tert-butyl ether <405 ug/L 04/06/21 17:02 637-92-31250405125
Hexachloro-1,3-butadiene <191 ug/L 04/06/21 17:02 87-68-3250191125
Isopropylbenzene (Cumene)76.7 ug/L 04/06/21 17:02 98-82-862.5 41.6 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-1 Lab ID:92531085001 Collected:04/02/21 12:00 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <244 ug/L 04/06/21 17:02 75-09-2250244125
Methyl-tert-butyl ether 8260 ug/L 04/06/21 17:02 1634-04-462.5 52.8 125
Naphthalene 738 ug/L 04/06/21 17:02 91-20-325080.6 125
n-Propylbenzene <42.5 ug/L 04/06/21 17:02 103-65-162.5 42.5 125
Styrene 40.0J ug/L 04/06/21 17:02 100-42-562.5 36.5 125
1,1,1,2-Tetrachloroethane <38.9 ug/L 04/06/21 17:02 630-20-662.5 38.9 125
1,1,2,2-Tetrachloroethane <28.1 ug/L 04/06/21 17:02 79-34-562.5 28.1 125
Tetrachloroethene <36.5 ug/L 04/06/21 17:02 127-18-462.5 36.5 125
Toluene 21700 ug/L 04/06/21 17:02 108-88-362.5 60.6 125
1,2,3-Trichlorobenzene <101 ug/L 04/06/21 17:02 87-61-6250101125
1,2,4-Trichlorobenzene <79.9 ug/L 04/06/21 17:02 120-82-125079.9 125
1,1,1-Trichloroethane <41.5 ug/L 04/06/21 17:02 71-55-662.5 41.5 125
1,1,2-Trichloroethane <40.6 ug/L 04/06/21 17:02 79-00-562.5 40.6 125
Trichloroethene <47.9 ug/L 04/06/21 17:02 79-01-662.5 47.9 125
Trichlorofluoromethane <37.2 ug/L 04/06/21 17:02 75-69-412537.2 125
1,2,3-Trichloropropane <32.6 ug/L 04/06/21 17:02 96-18-462.5 32.6 125
1,2,4-Trimethylbenzene 2200 ug/L 04/06/21 17:02 95-63-662.5 61.9 125
1,3,5-Trimethylbenzene 658 ug/L 04/06/21 17:02 108-67-862.5 41.5 125
Vinyl chloride <48.2 ug/L 04/06/21 17:02 75-01-412548.2 125
Xylene (Total)12800 ug/L 04/06/21 17:02 1330-20-712542.2 125
m&p-Xylene 8690 ug/L 04/06/21 17:02 179601-23-112588.6 125
o-Xylene 4080 ug/L 04/06/21 17:02 95-47-662.5 42.2 125
Surrogates
1,2-Dichloroethane-d4 (S)99 %04/06/21 17:02 17060-07-070-130 125
4-Bromofluorobenzene (S)98 %04/06/21 17:02 460-00-470-130 125
Toluene-d8 (S)102 %04/06/21 17:02 2037-26-570-130 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-3 Lab ID:92531085002 Collected:04/02/21 13:15 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <7280 ug/L 04/06/21 17:20 75-85-4200007280200
tert-Amylmethyl ether <532 ug/L 04/06/21 17:20 994-05-82000532200
Benzene 15300 ug/L 04/06/21 17:20 71-43-210069.0 200
Bromobenzene <58.0 ug/L 04/06/21 17:20 108-86-110058.0 200
Bromochloromethane <93.6 ug/L 04/06/21 17:20 74-97-510093.6 200
Bromodichloromethane <61.4 ug/L 04/06/21 17:20 75-27-410061.4 200
Bromoform <68.2 ug/L 04/06/21 17:20 75-25-210068.2 200
Bromomethane <332 ug/L 04/06/21 17:20 74-83-91000332200
tert-Butyl Alcohol <5360 ug/L 04/06/21 17:20 75-65-0100005360200
n-Butylbenzene <98.0 ug/L 04/06/21 17:20 104-51-810098.0 200
sec-Butylbenzene <80.0 ug/L 04/06/21 17:20 135-98-810080.0 200
tert-Butylbenzene <64.6 ug/L 04/06/21 17:20 98-06-610064.6 200
tert-Butyl Formate <5880 ug/L 04/06/21 17:20 762-75-4100005880200
Carbon tetrachloride <66.6 ug/L 04/06/21 17:20 56-23-510066.6 200
Chlorobenzene <56.8 ug/L 04/06/21 17:20 108-90-710056.8 200
Chloroethane <130 ug/L 04/06/21 17:20 75-00-3200130200
Chloroform <70.6 ug/L 04/06/21 17:20 67-66-310070.6 200
Chloromethane <108 ug/L 04/06/21 17:20 74-87-3200108200
2-Chlorotoluene <64.2 ug/L 04/06/21 17:20 95-49-810064.2 200
4-Chlorotoluene <64.8 ug/L 04/06/21 17:20 106-43-410064.8 200
1,2-Dibromo-3-chloropropane <68.0 ug/L 04/06/21 17:20 96-12-820068.0 200
Dibromochloromethane <71.8 ug/L 04/06/21 17:20 124-48-110071.8 200
1,2-Dibromoethane (EDB)673 ug/L 04/06/21 17:20 106-93-410054.4 200
Dibromomethane <78.8 ug/L 04/06/21 17:20 74-95-310078.8 200
1,2-Dichlorobenzene <67.8 ug/L 04/06/21 17:20 95-50-110067.8 200
1,3-Dichlorobenzene <68.0 ug/L 04/06/21 17:20 541-73-110068.0 200
1,4-Dichlorobenzene <66.6 ug/L 04/06/21 17:20 106-46-710066.6 200
Dichlorodifluoromethane <69.2 ug/L 04/06/21 17:20 75-71-810069.2 200
1,1-Dichloroethane <73.4 ug/L 04/06/21 17:20 75-34-310073.4 200
1,2-Dichloroethane 195 ug/L 04/06/21 17:20 107-06-210064.4 200
1,1-Dichloroethene <69.6 ug/L 04/06/21 17:20 75-35-410069.6 200
cis-1,2-Dichloroethene <76.8 ug/L 04/06/21 17:20 156-59-210076.8 200
trans-1,2-Dichloroethene <79.2 ug/L 04/06/21 17:20 156-60-510079.2 200
1,2-Dichloropropane <71.0 ug/L 04/06/21 17:20 78-87-510071.0 200
1,3-Dichloropropane <56.8 ug/L 04/06/21 17:20 142-28-910056.8 200
2,2-Dichloropropane <77.6 ug/L 04/06/21 17:20 594-20-710077.6 200
1,1-Dichloropropene <85.4 ug/L 04/06/21 17:20 563-58-610085.4 200
cis-1,3-Dichloropropene <73.0 ug/L 04/06/21 17:20 10061-01-510073.0 200
trans-1,3-Dichloropropene <72.6 ug/L 04/06/21 17:20 10061-02-610072.6 200
Diisopropyl ether <61.6 ug/L 04/06/21 17:20 108-20-310061.6 200
Ethanol <14400 ug/L 04/06/21 17:20 64-17-54000014400200
Ethylbenzene 2220 ug/L 04/06/21 17:20 100-41-410060.8 200
Ethyl-tert-butyl ether <648 ug/L 04/06/21 17:20 637-92-32000648200
Hexachloro-1,3-butadiene <306 ug/L 04/06/21 17:20 87-68-3400306200
Isopropylbenzene (Cumene)106 ug/L 04/06/21 17:20 98-82-810066.6 200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-3 Lab ID:92531085002 Collected:04/02/21 13:15 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <390 ug/L 04/06/21 17:20 75-09-2400390200
Methyl-tert-butyl ether <84.4 ug/L 04/06/21 17:20 1634-04-410084.4 200
Naphthalene 990 ug/L 04/06/21 17:20 91-20-3400129200
n-Propylbenzene <68.0 ug/L 04/06/21 17:20 103-65-110068.0 200
Styrene 75.4J ug/L 04/06/21 17:20 100-42-510058.4 200
1,1,1,2-Tetrachloroethane <62.2 ug/L 04/06/21 17:20 630-20-610062.2 200
1,1,2,2-Tetrachloroethane <45.0 ug/L 04/06/21 17:20 79-34-510045.0 200
Tetrachloroethene <58.4 ug/L 04/06/21 17:20 127-18-410058.4 200
Toluene 28400 ug/L 04/06/21 17:20 108-88-310097.0 200
1,2,3-Trichlorobenzene <161 ug/L 04/06/21 17:20 87-61-6400161200
1,2,4-Trichlorobenzene <128 ug/L 04/06/21 17:20 120-82-1400128200
1,1,1-Trichloroethane <66.4 ug/L 04/06/21 17:20 71-55-610066.4 200
1,1,2-Trichloroethane <65.0 ug/L 04/06/21 17:20 79-00-510065.0 200
Trichloroethene <76.6 ug/L 04/06/21 17:20 79-01-610076.6 200
Trichlorofluoromethane <59.6 ug/L 04/06/21 17:20 75-69-420059.6 200
1,2,3-Trichloropropane <52.2 ug/L 04/06/21 17:20 96-18-410052.2 200
1,2,4-Trimethylbenzene 2730 ug/L 04/06/21 17:20 95-63-610099.0 200
1,3,5-Trimethylbenzene <66.4 ug/L 04/06/21 17:20 108-67-810066.4 200
Vinyl chloride <77.2 ug/L 04/06/21 17:20 75-01-420077.2 200
Xylene (Total)15000 ug/L 04/06/21 17:20 1330-20-720067.6 200
m&p-Xylene 10100 ug/L 04/06/21 17:20 179601-23-1200142200
o-Xylene 4930 ug/L 04/06/21 17:20 95-47-610067.6 200
Surrogates
1,2-Dichloroethane-d4 (S)99 %04/06/21 17:20 17060-07-070-130 200
4-Bromofluorobenzene (S)98 %04/06/21 17:20 460-00-470-130 200
Toluene-d8 (S)100 %04/06/21 17:20 2037-26-570-130 200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-5 Lab ID:92531085003 Collected:04/02/21 14:15 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/06/21 04:14 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/06/21 04:14 994-05-810.0 2.7 1
Benzene 4.5 ug/L 04/06/21 04:14 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/06/21 04:14 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/06/21 04:14 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/06/21 04:14 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/06/21 04:14 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/06/21 04:14 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/06/21 04:14 75-65-050.0 26.8 1
n-Butylbenzene 0.76 ug/L 04/06/21 04:14 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/06/21 04:14 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/06/21 04:14 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/06/21 04:14 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/06/21 04:14 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/06/21 04:14 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/06/21 04:14 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/06/21 04:14 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/06/21 04:14 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/06/21 04:14 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/06/21 04:14 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/06/21 04:14 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/06/21 04:14 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/06/21 04:14 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/06/21 04:14 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/06/21 04:14 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/06/21 04:14 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/06/21 04:14 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/06/21 04:14 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/06/21 04:14 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/06/21 04:14 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/06/21 04:14 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/06/21 04:14 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/06/21 04:14 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/06/21 04:14 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/06/21 04:14 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/06/21 04:14 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/06/21 04:14 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/06/21 04:14 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/06/21 04:14 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 04/06/21 04:14 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/06/21 04:14 64-17-520072.2 1
Ethylbenzene 2.1 ug/L 04/06/21 04:14 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/06/21 04:14 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/06/21 04:14 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/06/21 04:14 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-5 Lab ID:92531085003 Collected:04/02/21 14:15 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 04/06/21 04:14 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/06/21 04:14 1634-04-40.50 0.42 1
Naphthalene 1.6J ug/L 04/06/21 04:14 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/06/21 04:14 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/06/21 04:14 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/06/21 04:14 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/06/21 04:14 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/06/21 04:14 127-18-40.50 0.29 1
Toluene 12.6 ug/L 04/06/21 04:14 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/06/21 04:14 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/06/21 04:14 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/06/21 04:14 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/06/21 04:14 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/06/21 04:14 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/06/21 04:14 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/06/21 04:14 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 9.9 ug/L 04/06/21 04:14 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 3.5 ug/L 04/06/21 04:14 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/06/21 04:14 75-01-41.0 0.39 1
Xylene (Total)17.9 ug/L 04/06/21 04:14 1330-20-71.0 0.34 1
m&p-Xylene 12.1 ug/L 04/06/21 04:14 179601-23-11.0 0.71 1
o-Xylene 5.8 ug/L 04/06/21 04:14 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %04/06/21 04:14 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/06/21 04:14 460-00-470-130 1
Toluene-d8 (S)101 %04/06/21 04:14 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-12 Lab ID:92531085004 Collected:04/02/21 11:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/06/21 03:56 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/06/21 03:56 994-05-810.0 2.7 1
Benzene <0.34 ug/L 04/06/21 03:56 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/06/21 03:56 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/06/21 03:56 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/06/21 03:56 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/06/21 03:56 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/06/21 03:56 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/06/21 03:56 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/06/21 03:56 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/06/21 03:56 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/06/21 03:56 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/06/21 03:56 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/06/21 03:56 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/06/21 03:56 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/06/21 03:56 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/06/21 03:56 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/06/21 03:56 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/06/21 03:56 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/06/21 03:56 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/06/21 03:56 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/06/21 03:56 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/06/21 03:56 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/06/21 03:56 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/06/21 03:56 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/06/21 03:56 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/06/21 03:56 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/06/21 03:56 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/06/21 03:56 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/06/21 03:56 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/06/21 03:56 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/06/21 03:56 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/06/21 03:56 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/06/21 03:56 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/06/21 03:56 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/06/21 03:56 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/06/21 03:56 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:56 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:56 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 04/06/21 03:56 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/06/21 03:56 64-17-520072.2 1
Ethylbenzene <0.30 ug/L 04/06/21 03:56 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/06/21 03:56 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/06/21 03:56 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/06/21 03:56 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:MW-12 Lab ID:92531085004 Collected:04/02/21 11:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 04/06/21 03:56 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/06/21 03:56 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 04/06/21 03:56 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/06/21 03:56 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/06/21 03:56 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/06/21 03:56 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/06/21 03:56 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/06/21 03:56 127-18-40.50 0.29 1
Toluene <0.48 ug/L 04/06/21 03:56 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/06/21 03:56 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/06/21 03:56 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/06/21 03:56 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/06/21 03:56 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/06/21 03:56 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/06/21 03:56 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/06/21 03:56 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 04/06/21 03:56 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/06/21 03:56 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/06/21 03:56 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 04/06/21 03:56 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 04/06/21 03:56 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 04/06/21 03:56 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %04/06/21 03:56 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %04/06/21 03:56 460-00-470-130 1
Toluene-d8 (S)107 %04/06/21 03:56 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:AS-1 Lab ID:92531085005 Collected:04/02/21 12:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol 2070 ug/L 04/06/21 22:08 75-85-410036.4 1
tert-Amylmethyl ether 8.0J ug/L 04/06/21 22:08 994-05-810.0 2.7 1
Benzene 11.1 ug/L 04/06/21 22:08 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/06/21 22:08 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/06/21 22:08 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/06/21 22:08 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/06/21 22:08 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/06/21 22:08 74-83-95.0 1.7 1
tert-Butyl Alcohol 101 ug/L 04/06/21 22:08 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/06/21 22:08 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/06/21 22:08 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/06/21 22:08 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/06/21 22:08 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/06/21 22:08 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/06/21 22:08 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/06/21 22:08 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/06/21 22:08 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/06/21 22:08 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/06/21 22:08 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/06/21 22:08 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/06/21 22:08 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/06/21 22:08 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)0.74 ug/L 04/06/21 22:08 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/06/21 22:08 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/06/21 22:08 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/06/21 22:08 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/06/21 22:08 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/06/21 22:08 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/06/21 22:08 75-34-30.50 0.37 1
1,2-Dichloroethane 24.9 ug/L 04/06/21 22:08 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/06/21 22:08 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/06/21 22:08 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/06/21 22:08 156-60-50.50 0.40 1
1,2-Dichloropropane 0.49J ug/L 04/06/21 22:08 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/06/21 22:08 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/06/21 22:08 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/06/21 22:08 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/06/21 22:08 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/06/21 22:08 10061-02-60.50 0.36 1
Diisopropyl ether 10 ug/L 04/06/21 22:08 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/06/21 22:08 64-17-520072.2 1
Ethylbenzene 1.0 ug/L 04/06/21 22:08 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/06/21 22:08 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/06/21 22:08 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/06/21 22:08 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:AS-1 Lab ID:92531085005 Collected:04/02/21 12:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 04/06/21 22:08 75-09-22.0 2.0 1
Methyl-tert-butyl ether 24.4 ug/L 04/06/21 22:08 1634-04-40.50 0.42 1
Naphthalene 2.3 ug/L 04/06/21 22:08 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/06/21 22:08 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/06/21 22:08 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/06/21 22:08 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/06/21 22:08 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/06/21 22:08 127-18-40.50 0.29 1
Toluene 5.2 ug/L 04/06/21 22:08 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/06/21 22:08 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/06/21 22:08 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/06/21 22:08 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/06/21 22:08 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/06/21 22:08 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/06/21 22:08 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/06/21 22:08 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 1.2 ug/L 04/06/21 22:08 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/06/21 22:08 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/06/21 22:08 75-01-41.0 0.39 1
Xylene (Total)20.7 ug/L 04/06/21 22:08 1330-20-71.0 0.34 1
m&p-Xylene 4.8 ug/L 04/06/21 22:08 179601-23-11.0 0.71 1
o-Xylene 15.9 ug/L 04/06/21 22:08 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %04/06/21 22:08 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %04/06/21 22:08 460-00-470-130 1
Toluene-d8 (S)102 %04/06/21 22:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:TRIP BLANK Lab ID:92531085006 Collected:04/02/21 00:00 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/05/21 22:49 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/05/21 22:49 994-05-810.0 2.7 1
Benzene <0.34 ug/L 04/05/21 22:49 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/05/21 22:49 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/05/21 22:49 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/05/21 22:49 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/05/21 22:49 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/05/21 22:49 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/05/21 22:49 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/05/21 22:49 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/05/21 22:49 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/05/21 22:49 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/05/21 22:49 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/05/21 22:49 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/05/21 22:49 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/05/21 22:49 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/05/21 22:49 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/05/21 22:49 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/05/21 22:49 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/05/21 22:49 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/05/21 22:49 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/05/21 22:49 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/05/21 22:49 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/05/21 22:49 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/05/21 22:49 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/05/21 22:49 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/05/21 22:49 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/05/21 22:49 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/05/21 22:49 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/05/21 22:49 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/05/21 22:49 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/05/21 22:49 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/05/21 22:49 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/05/21 22:49 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/05/21 22:49 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/05/21 22:49 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/05/21 22:49 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/05/21 22:49 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/05/21 22:49 10061-02-60.50 0.36 1
Diisopropyl ether <0.31 ug/L 04/05/21 22:49 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/05/21 22:49 64-17-520072.2 1
Ethylbenzene <0.30 ug/L 04/05/21 22:49 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/05/21 22:49 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/05/21 22:49 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/05/21 22:49 98-82-80.50 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:TRIP BLANK Lab ID:92531085006 Collected:04/02/21 00:00 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Methylene Chloride <2.0 ug/L 04/05/21 22:49 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/05/21 22:49 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 04/05/21 22:49 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/05/21 22:49 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/05/21 22:49 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/05/21 22:49 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/05/21 22:49 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/05/21 22:49 127-18-40.50 0.29 1
Toluene <0.48 ug/L 04/05/21 22:49 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/05/21 22:49 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/05/21 22:49 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/05/21 22:49 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/05/21 22:49 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/05/21 22:49 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/05/21 22:49 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/05/21 22:49 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 04/05/21 22:49 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/05/21 22:49 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/05/21 22:49 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 04/05/21 22:49 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 04/05/21 22:49 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 04/05/21 22:49 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %04/05/21 22:49 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/05/21 22:49 460-00-470-130 1
Toluene-d8 (S)101 %04/05/21 22:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-1 Lab ID:92531085007 Collected:04/02/21 14:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
Pace Analytical Services - Charlotte
504 GCS EDB and DBCP
1,2-Dibromoethane (EDB)<0.013 ug/L 04/06/21 20:14 106-93-404/06/21 09:430.020 0.013 1
Surrogates
1-Chloro-2-bromopropane (S)98 %04/06/21 20:14 301-79-5604/06/21 09:4370-130 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/06/21 22:26 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/06/21 22:26 994-05-810.0 2.7 1
Benzene <0.34 ug/L 04/06/21 22:26 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/06/21 22:26 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/06/21 22:26 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/06/21 22:26 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/06/21 22:26 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/06/21 22:26 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/06/21 22:26 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/06/21 22:26 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/06/21 22:26 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/06/21 22:26 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/06/21 22:26 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/06/21 22:26 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/06/21 22:26 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/06/21 22:26 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/06/21 22:26 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/06/21 22:26 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/06/21 22:26 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/06/21 22:26 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/06/21 22:26 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/06/21 22:26 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/06/21 22:26 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/06/21 22:26 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/06/21 22:26 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/06/21 22:26 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/06/21 22:26 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/06/21 22:26 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/06/21 22:26 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/06/21 22:26 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/06/21 22:26 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/06/21 22:26 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/06/21 22:26 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/06/21 22:26 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/06/21 22:26 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/06/21 22:26 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/06/21 22:26 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/06/21 22:26 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/06/21 22:26 10061-02-60.50 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-1 Lab ID:92531085007 Collected:04/02/21 14:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Diisopropyl ether <0.31 ug/L 04/06/21 22:26 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/06/21 22:26 64-17-520072.2 1
Ethylbenzene <0.30 ug/L 04/06/21 22:26 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/06/21 22:26 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/06/21 22:26 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/06/21 22:26 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 04/06/21 22:26 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/06/21 22:26 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 04/06/21 22:26 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/06/21 22:26 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/06/21 22:26 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/06/21 22:26 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/06/21 22:26 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/06/21 22:26 127-18-40.50 0.29 1
Toluene <0.48 ug/L 04/06/21 22:26 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/06/21 22:26 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/06/21 22:26 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/06/21 22:26 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/06/21 22:26 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/06/21 22:26 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/06/21 22:26 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/06/21 22:26 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 04/06/21 22:26 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/06/21 22:26 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/06/21 22:26 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 04/06/21 22:26 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 04/06/21 22:26 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 04/06/21 22:26 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %04/06/21 22:26 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %04/06/21 22:26 460-00-470-130 1
Toluene-d8 (S)102 %04/06/21 22:26 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-2 Lab ID:92531085008 Collected:04/02/21 15:50 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
Pace Analytical Services - Charlotte
504 GCS EDB and DBCP
1,2-Dibromoethane (EDB)<0.013 ug/L 04/06/21 20:29 106-93-404/06/21 09:430.020 0.013 1
Surrogates
1-Chloro-2-bromopropane (S)95 %04/06/21 20:29 301-79-5604/06/21 09:4370-130 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/06/21 03:02 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/06/21 03:02 994-05-810.0 2.7 1
Benzene <0.34 ug/L 04/06/21 03:02 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/06/21 03:02 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/06/21 03:02 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/06/21 03:02 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/06/21 03:02 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/06/21 03:02 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/06/21 03:02 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/06/21 03:02 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/06/21 03:02 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/06/21 03:02 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/06/21 03:02 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/06/21 03:02 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/06/21 03:02 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/06/21 03:02 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/06/21 03:02 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/06/21 03:02 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/06/21 03:02 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/06/21 03:02 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/06/21 03:02 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/06/21 03:02 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/06/21 03:02 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/06/21 03:02 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/06/21 03:02 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/06/21 03:02 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/06/21 03:02 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/06/21 03:02 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/06/21 03:02 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/06/21 03:02 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/06/21 03:02 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/06/21 03:02 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/06/21 03:02 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/06/21 03:02 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/06/21 03:02 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/06/21 03:02 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/06/21 03:02 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:02 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:02 10061-02-60.50 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-2 Lab ID:92531085008 Collected:04/02/21 15:50 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Diisopropyl ether <0.31 ug/L 04/06/21 03:02 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/06/21 03:02 64-17-520072.2 1
Ethylbenzene <0.30 ug/L 04/06/21 03:02 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/06/21 03:02 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/06/21 03:02 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/06/21 03:02 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 04/06/21 03:02 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/06/21 03:02 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 04/06/21 03:02 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/06/21 03:02 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/06/21 03:02 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/06/21 03:02 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/06/21 03:02 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/06/21 03:02 127-18-40.50 0.29 1
Toluene <0.48 ug/L 04/06/21 03:02 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/06/21 03:02 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/06/21 03:02 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/06/21 03:02 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/06/21 03:02 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/06/21 03:02 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/06/21 03:02 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/06/21 03:02 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 04/06/21 03:02 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/06/21 03:02 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/06/21 03:02 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 04/06/21 03:02 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 04/06/21 03:02 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 04/06/21 03:02 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %04/06/21 03:02 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/06/21 03:02 460-00-470-130 1
Toluene-d8 (S)102 %04/06/21 03:02 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-6 Lab ID:92531085009 Collected:04/02/21 15:10 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
Pace Analytical Services - Charlotte
504 GCS EDB and DBCP
1,2-Dibromoethane (EDB)<0.013 ug/L 04/06/21 20:44 106-93-404/06/21 09:430.020 0.013 1
Surrogates
1-Chloro-2-bromopropane (S)97 %04/06/21 20:44 301-79-5604/06/21 09:4370-130 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/06/21 03:20 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/06/21 03:20 994-05-810.0 2.7 1
Benzene <0.34 ug/L 04/06/21 03:20 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/06/21 03:20 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/06/21 03:20 74-97-50.50 0.47 1
Bromodichloromethane 1.0 ug/L 04/06/21 03:20 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/06/21 03:20 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/06/21 03:20 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/06/21 03:20 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/06/21 03:20 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/06/21 03:20 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/06/21 03:20 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/06/21 03:20 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/06/21 03:20 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/06/21 03:20 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/06/21 03:20 75-00-31.0 0.65 1
Chloroform 5.4 ug/L 04/06/21 03:20 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/06/21 03:20 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/06/21 03:20 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/06/21 03:20 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/06/21 03:20 96-12-81.0 0.34 1
Dibromochloromethane 0.42J ug/L 04/06/21 03:20 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/06/21 03:20 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/06/21 03:20 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/06/21 03:20 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/06/21 03:20 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/06/21 03:20 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/06/21 03:20 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/06/21 03:20 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/06/21 03:20 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/06/21 03:20 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/06/21 03:20 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/06/21 03:20 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/06/21 03:20 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/06/21 03:20 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/06/21 03:20 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/06/21 03:20 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:20 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:20 10061-02-60.50 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
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Page 21 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-6 Lab ID:92531085009 Collected:04/02/21 15:10 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Diisopropyl ether <0.31 ug/L 04/06/21 03:20 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/06/21 03:20 64-17-520072.2 1
Ethylbenzene <0.30 ug/L 04/06/21 03:20 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/06/21 03:20 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/06/21 03:20 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/06/21 03:20 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 04/06/21 03:20 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/06/21 03:20 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 04/06/21 03:20 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/06/21 03:20 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/06/21 03:20 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/06/21 03:20 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/06/21 03:20 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/06/21 03:20 127-18-40.50 0.29 1
Toluene 2.5 ug/L 04/06/21 03:20 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/06/21 03:20 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/06/21 03:20 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/06/21 03:20 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/06/21 03:20 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/06/21 03:20 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/06/21 03:20 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/06/21 03:20 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 04/06/21 03:20 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/06/21 03:20 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/06/21 03:20 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 04/06/21 03:20 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 04/06/21 03:20 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 04/06/21 03:20 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %04/06/21 03:20 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/06/21 03:20 460-00-470-130 1
Toluene-d8 (S)107 %04/06/21 03:20 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
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9800 Kincey Ave. Suite 100
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Page 22 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-7 Lab ID:92531085010 Collected:04/02/21 15:40 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
Pace Analytical Services - Charlotte
504 GCS EDB and DBCP
1,2-Dibromoethane (EDB)<0.012 ug/L 04/06/21 21:00 106-93-404/06/21 09:430.019 0.012 1
Surrogates
1-Chloro-2-bromopropane (S)101 %04/06/21 21:00 301-79-5604/06/21 09:4370-130 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/06/21 03:38 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/06/21 03:38 994-05-810.0 2.7 1
Benzene <0.34 ug/L 04/06/21 03:38 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/06/21 03:38 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/06/21 03:38 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/06/21 03:38 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/06/21 03:38 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/06/21 03:38 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/06/21 03:38 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/06/21 03:38 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/06/21 03:38 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/06/21 03:38 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/06/21 03:38 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/06/21 03:38 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/06/21 03:38 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/06/21 03:38 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/06/21 03:38 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/06/21 03:38 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/06/21 03:38 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/06/21 03:38 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/06/21 03:38 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/06/21 03:38 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/06/21 03:38 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/06/21 03:38 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/06/21 03:38 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/06/21 03:38 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/06/21 03:38 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/06/21 03:38 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/06/21 03:38 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/06/21 03:38 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/06/21 03:38 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/06/21 03:38 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/06/21 03:38 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/06/21 03:38 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/06/21 03:38 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/06/21 03:38 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/06/21 03:38 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:38 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/06/21 03:38 10061-02-60.50 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:WSW-7 Lab ID:92531085010 Collected:04/02/21 15:40 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Diisopropyl ether <0.31 ug/L 04/06/21 03:38 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/06/21 03:38 64-17-520072.2 1
Ethylbenzene <0.30 ug/L 04/06/21 03:38 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/06/21 03:38 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/06/21 03:38 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/06/21 03:38 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 04/06/21 03:38 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/06/21 03:38 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 04/06/21 03:38 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/06/21 03:38 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/06/21 03:38 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/06/21 03:38 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/06/21 03:38 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/06/21 03:38 127-18-40.50 0.29 1
Toluene <0.48 ug/L 04/06/21 03:38 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/06/21 03:38 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/06/21 03:38 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/06/21 03:38 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/06/21 03:38 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/06/21 03:38 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/06/21 03:38 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/06/21 03:38 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 04/06/21 03:38 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/06/21 03:38 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/06/21 03:38 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 04/06/21 03:38 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 04/06/21 03:38 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 04/06/21 03:38 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)101 %04/06/21 03:38 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/06/21 03:38 460-00-470-130 1
Toluene-d8 (S)101 %04/06/21 03:38 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:FB-1 Lab ID:92531085011 Collected:04/02/21 14:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1
Pace Analytical Services - Charlotte
504 GCS EDB and DBCP
1,2-Dibromoethane (EDB)<0.012 ug/L 04/06/21 21:15 106-93-404/06/21 09:430.019 0.012 1
Surrogates
1-Chloro-2-bromopropane (S)101 %04/06/21 21:15 301-79-5604/06/21 09:4370-130 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
tert-Amyl Alcohol <36.4 ug/L 04/05/21 23:07 75-85-410036.4 1
tert-Amylmethyl ether <2.7 ug/L 04/05/21 23:07 994-05-810.0 2.7 1
Benzene <0.34 ug/L 04/05/21 23:07 71-43-20.50 0.34 1
Bromobenzene <0.29 ug/L 04/05/21 23:07 108-86-10.50 0.29 1
Bromochloromethane <0.47 ug/L 04/05/21 23:07 74-97-50.50 0.47 1
Bromodichloromethane <0.31 ug/L 04/05/21 23:07 75-27-40.50 0.31 1
Bromoform <0.34 ug/L 04/05/21 23:07 75-25-20.50 0.34 1
Bromomethane <1.7 ug/L 04/05/21 23:07 74-83-95.0 1.7 1
tert-Butyl Alcohol <26.8 ug/L 04/05/21 23:07 75-65-050.0 26.8 1
n-Butylbenzene <0.49 ug/L 04/05/21 23:07 104-51-80.50 0.49 1
sec-Butylbenzene <0.40 ug/L 04/05/21 23:07 135-98-80.50 0.40 1
tert-Butylbenzene <0.32 ug/L 04/05/21 23:07 98-06-60.50 0.32 1
tert-Butyl Formate <29.4 ug/L 04/05/21 23:07 762-75-450.0 29.4 1
Carbon tetrachloride <0.33 ug/L 04/05/21 23:07 56-23-50.50 0.33 1
Chlorobenzene <0.28 ug/L 04/05/21 23:07 108-90-70.50 0.28 1
Chloroethane <0.65 ug/L 04/05/21 23:07 75-00-31.0 0.65 1
Chloroform <0.35 ug/L 04/05/21 23:07 67-66-30.50 0.35 1
Chloromethane <0.54 ug/L 04/05/21 23:07 74-87-31.0 0.54 1
2-Chlorotoluene <0.32 ug/L 04/05/21 23:07 95-49-80.50 0.32 1
4-Chlorotoluene <0.32 ug/L 04/05/21 23:07 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane <0.34 ug/L 04/05/21 23:07 96-12-81.0 0.34 1
Dibromochloromethane <0.36 ug/L 04/05/21 23:07 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)<0.27 ug/L 04/05/21 23:07 106-93-40.50 0.27 1
Dibromomethane <0.39 ug/L 04/05/21 23:07 74-95-30.50 0.39 1
1,2-Dichlorobenzene <0.34 ug/L 04/05/21 23:07 95-50-10.50 0.34 1
1,3-Dichlorobenzene <0.34 ug/L 04/05/21 23:07 541-73-10.50 0.34 1
1,4-Dichlorobenzene <0.33 ug/L 04/05/21 23:07 106-46-70.50 0.33 1
Dichlorodifluoromethane <0.35 ug/L 04/05/21 23:07 75-71-80.50 0.35 1
1,1-Dichloroethane <0.37 ug/L 04/05/21 23:07 75-34-30.50 0.37 1
1,2-Dichloroethane <0.32 ug/L 04/05/21 23:07 107-06-20.50 0.32 1
1,1-Dichloroethene <0.35 ug/L 04/05/21 23:07 75-35-40.50 0.35 1
cis-1,2-Dichloroethene <0.38 ug/L 04/05/21 23:07 156-59-20.50 0.38 1
trans-1,2-Dichloroethene <0.40 ug/L 04/05/21 23:07 156-60-50.50 0.40 1
1,2-Dichloropropane <0.36 ug/L 04/05/21 23:07 78-87-50.50 0.36 1
1,3-Dichloropropane <0.28 ug/L 04/05/21 23:07 142-28-90.50 0.28 1
2,2-Dichloropropane <0.39 ug/L 04/05/21 23:07 594-20-70.50 0.39 1
1,1-Dichloropropene <0.43 ug/L 04/05/21 23:07 563-58-60.50 0.43 1
cis-1,3-Dichloropropene <0.36 ug/L 04/05/21 23:07 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene <0.36 ug/L 04/05/21 23:07 10061-02-60.50 0.36 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Sample:FB-1 Lab ID:92531085011 Collected:04/02/21 14:30 Received:04/02/21 17:34 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Diisopropyl ether <0.31 ug/L 04/05/21 23:07 108-20-30.50 0.31 1
Ethanol <72.2 ug/L 04/05/21 23:07 64-17-520072.2 1
Ethylbenzene <0.30 ug/L 04/05/21 23:07 100-41-40.50 0.30 1
Ethyl-tert-butyl ether <3.2 ug/L 04/05/21 23:07 637-92-310.0 3.2 1
Hexachloro-1,3-butadiene <1.5 ug/L 04/05/21 23:07 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)<0.33 ug/L 04/05/21 23:07 98-82-80.50 0.33 1
Methylene Chloride <2.0 ug/L 04/05/21 23:07 75-09-22.0 2.0 1
Methyl-tert-butyl ether <0.42 ug/L 04/05/21 23:07 1634-04-40.50 0.42 1
Naphthalene <0.64 ug/L 04/05/21 23:07 91-20-32.0 0.64 1
n-Propylbenzene <0.34 ug/L 04/05/21 23:07 103-65-10.50 0.34 1
Styrene <0.29 ug/L 04/05/21 23:07 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane <0.31 ug/L 04/05/21 23:07 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane <0.22 ug/L 04/05/21 23:07 79-34-50.50 0.22 1
Tetrachloroethene <0.29 ug/L 04/05/21 23:07 127-18-40.50 0.29 1
Toluene <0.48 ug/L 04/05/21 23:07 108-88-30.50 0.48 1
1,2,3-Trichlorobenzene <0.81 ug/L 04/05/21 23:07 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene <0.64 ug/L 04/05/21 23:07 120-82-12.0 0.64 1
1,1,1-Trichloroethane <0.33 ug/L 04/05/21 23:07 71-55-60.50 0.33 1
1,1,2-Trichloroethane <0.32 ug/L 04/05/21 23:07 79-00-50.50 0.32 1
Trichloroethene <0.38 ug/L 04/05/21 23:07 79-01-60.50 0.38 1
Trichlorofluoromethane <0.30 ug/L 04/05/21 23:07 75-69-41.0 0.30 1
1,2,3-Trichloropropane <0.26 ug/L 04/05/21 23:07 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene <0.50 ug/L 04/05/21 23:07 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene <0.33 ug/L 04/05/21 23:07 108-67-80.50 0.33 1
Vinyl chloride <0.39 ug/L 04/05/21 23:07 75-01-41.0 0.39 1
Xylene (Total)<0.34 ug/L 04/05/21 23:07 1330-20-71.0 0.34 1
m&p-Xylene <0.71 ug/L 04/05/21 23:07 179601-23-11.0 0.71 1
o-Xylene <0.34 ug/L 04/05/21 23:07 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %04/05/21 23:07 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/05/21 23:07 460-00-470-130 1
Toluene-d8 (S)101 %04/05/21 23:07 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
611410
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92531085003, 92531085004, 92531085006, 92531085008, 92531085009, 92531085010, 92531085011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3218870
Associated Lab Samples:92531085003, 92531085004, 92531085006, 92531085008, 92531085009, 92531085010, 92531085011
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 04/05/21 22:310.31
1,1,1-Trichloroethane ug/L <0.33 0.50 04/05/21 22:310.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 04/05/21 22:310.22
1,1,2-Trichloroethane ug/L <0.32 0.50 04/05/21 22:310.32
1,1-Dichloroethane ug/L <0.37 0.50 04/05/21 22:310.37
1,1-Dichloroethene ug/L <0.35 0.50 04/05/21 22:310.35
1,1-Dichloropropene ug/L <0.43 0.50 04/05/21 22:310.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 04/05/21 22:310.81
1,2,3-Trichloropropane ug/L <0.26 0.50 04/05/21 22:310.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 04/05/21 22:310.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 04/05/21 22:310.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 04/05/21 22:310.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 04/05/21 22:310.27
1,2-Dichlorobenzene ug/L <0.34 0.50 04/05/21 22:310.34
1,2-Dichloroethane ug/L <0.32 0.50 04/05/21 22:310.32
1,2-Dichloropropane ug/L <0.36 0.50 04/05/21 22:310.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 04/05/21 22:310.33
1,3-Dichlorobenzene ug/L <0.34 0.50 04/05/21 22:310.34
1,3-Dichloropropane ug/L <0.28 0.50 04/05/21 22:310.28
1,4-Dichlorobenzene ug/L <0.33 0.50 04/05/21 22:310.33
2,2-Dichloropropane ug/L <0.39 0.50 04/05/21 22:310.39
2-Chlorotoluene ug/L <0.32 0.50 04/05/21 22:310.32
4-Chlorotoluene ug/L <0.32 0.50 04/05/21 22:310.32
Benzene ug/L <0.34 0.50 04/05/21 22:310.34
Bromobenzene ug/L <0.29 0.50 04/05/21 22:310.29
Bromochloromethane ug/L <0.47 0.50 04/05/21 22:310.47
Bromodichloromethane ug/L <0.31 0.50 04/05/21 22:310.31
Bromoform ug/L <0.34 0.50 04/05/21 22:310.34
Bromomethane ug/L <1.7 5.0 04/05/21 22:311.7
Carbon tetrachloride ug/L <0.33 0.50 04/05/21 22:310.33
Chlorobenzene ug/L <0.28 0.50 04/05/21 22:310.28
Chloroethane ug/L <0.65 1.0 04/05/21 22:310.65
Chloroform ug/L <0.35 0.50 04/05/21 22:310.35
Chloromethane ug/L <0.54 1.0 04/05/21 22:310.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 04/05/21 22:310.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 04/05/21 22:310.36
Dibromochloromethane ug/L <0.36 0.50 04/05/21 22:310.36
Dibromomethane ug/L <0.39 0.50 04/05/21 22:310.39
Dichlorodifluoromethane ug/L <0.35 0.50 04/05/21 22:310.35
Diisopropyl ether ug/L <0.31 0.50 04/05/21 22:310.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3218870
Associated Lab Samples:92531085003, 92531085004, 92531085006, 92531085008, 92531085009, 92531085010, 92531085011
Matrix:Water
AnalyzedMDL
Ethanol ug/L <72.2 200 04/05/21 22:3172.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 04/05/21 22:313.2
Ethylbenzene ug/L <0.30 0.50 04/05/21 22:310.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 04/05/21 22:311.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 04/05/21 22:310.33
m&p-Xylene ug/L <0.71 1.0 04/05/21 22:310.71
Methyl-tert-butyl ether ug/L <0.42 0.50 04/05/21 22:310.42
Methylene Chloride ug/L <2.0 2.0 04/05/21 22:312.0
n-Butylbenzene ug/L <0.49 0.50 04/05/21 22:310.49
n-Propylbenzene ug/L <0.34 0.50 04/05/21 22:310.34
Naphthalene ug/L <0.64 2.0 04/05/21 22:310.64
o-Xylene ug/L <0.34 0.50 04/05/21 22:310.34
sec-Butylbenzene ug/L <0.40 0.50 04/05/21 22:310.40
Styrene ug/L <0.29 0.50 04/05/21 22:310.29
tert-Amyl Alcohol ug/L <36.4 100 04/05/21 22:3136.4
tert-Amylmethyl ether ug/L <2.7 10.0 04/05/21 22:312.7
tert-Butyl Alcohol ug/L <26.8 50.0 04/05/21 22:3126.8
tert-Butyl Formate ug/L <29.4 50.0 04/05/21 22:3129.4
tert-Butylbenzene ug/L <0.32 0.50 04/05/21 22:310.32
Tetrachloroethene ug/L <0.29 0.50 04/05/21 22:310.29
Toluene ug/L <0.48 0.50 04/05/21 22:310.48
trans-1,2-Dichloroethene ug/L <0.40 0.50 04/05/21 22:310.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 04/05/21 22:310.36
Trichloroethene ug/L <0.38 0.50 04/05/21 22:310.38
Trichlorofluoromethane ug/L <0.30 1.0 04/05/21 22:310.30
Vinyl chloride ug/L <0.39 1.0 04/05/21 22:310.39
Xylene (Total)ug/L <0.34 1.0 04/05/21 22:310.34
1,2-Dichloroethane-d4 (S)%100 70-130 04/05/21 22:31
4-Bromofluorobenzene (S)%97 70-130 04/05/21 22:31
Toluene-d8 (S)%105 70-130 04/05/21 22:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3218871LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 55.950 112 60-140
1,1,1-Trichloroethane ug/L 55.150 110 60-140
1,1,2,2-Tetrachloroethane ug/L 56.150 112 60-140
1,1,2-Trichloroethane ug/L 57.050 114 60-140
1,1-Dichloroethane ug/L 55.450 111 60-140
1,1-Dichloroethene ug/L 57.050 114 60-140
1,1-Dichloropropene ug/L 54.350 109 60-140
1,2,3-Trichlorobenzene ug/L 52.250 104 60-140
1,2,3-Trichloropropane ug/L 54.350 109 60-140
1,2,4-Trichlorobenzene ug/L 51.550 103 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3218871LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 51.850 104 60-140
1,2-Dibromo-3-chloropropane ug/L 57.850 116 60-140
1,2-Dibromoethane (EDB)ug/L 54.950 110 60-140
1,2-Dichlorobenzene ug/L 51.450 103 60-140
1,2-Dichloroethane ug/L 50.150 100 60-140
1,2-Dichloropropane ug/L 57.350 115 60-140
1,3,5-Trimethylbenzene ug/L 52.650 105 60-140
1,3-Dichlorobenzene ug/L 52.850 106 60-140
1,3-Dichloropropane ug/L 54.850 110 60-140
1,4-Dichlorobenzene ug/L 53.450 107 60-140
2,2-Dichloropropane ug/L 55.850 112 60-140
2-Chlorotoluene ug/L 52.750 105 60-140
4-Chlorotoluene ug/L 51.250 102 60-140
Benzene ug/L 56.050 112 60-140
Bromobenzene ug/L 51.750 103 60-140
Bromochloromethane ug/L 56.650 113 60-140
Bromodichloromethane ug/L 56.950 114 60-140
Bromoform ug/L 58.550 117 60-140
Bromomethane ug/L 52.250 104 60-140
Carbon tetrachloride ug/L 57.450 115 60-140
Chlorobenzene ug/L 54.350 109 60-140
Chloroethane ug/L 44.450 89 60-140
Chloroform ug/L 48.850 98 60-140
Chloromethane ug/L 51.650 103 60-140
cis-1,2-Dichloroethene ug/L 55.650 111 60-140
cis-1,3-Dichloropropene ug/L 58.150 116 60-140
Dibromochloromethane ug/L 58.850 118 60-140
Dibromomethane ug/L 54.850 110 60-140
Dichlorodifluoromethane ug/L 46.550 93 60-140
Diisopropyl ether ug/L 51.450 103 60-140
Ethanol ug/L 20302000 101 60-140
Ethyl-tert-butyl ether ug/L 106100 106 60-140
Ethylbenzene ug/L 53.950 108 60-140
Hexachloro-1,3-butadiene ug/L 48.950 98 60-140
Isopropylbenzene (Cumene)ug/L 57.350 115 60-140
m&p-Xylene ug/L 110100 110 60-140
Methyl-tert-butyl ether ug/L 51.750 103 60-140
Methylene Chloride ug/L 52.350 105 60-140
n-Butylbenzene ug/L 51.250 102 60-140
n-Propylbenzene ug/L 50.950 102 60-140
Naphthalene ug/L 51.950 104 60-140
o-Xylene ug/L 54.850 110 60-140
sec-Butylbenzene ug/L 51.450 103 60-140
Styrene ug/L 57.650 115 60-140
tert-Amyl Alcohol ug/L 10401000 104 60-140
tert-Amylmethyl ether ug/L 106100 106 60-140
tert-Butyl Alcohol ug/L 488500 98 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3218871LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 441400 110 60-140
tert-Butylbenzene ug/L 44.350 89 60-140
Tetrachloroethene ug/L 54.450 109 60-140
Toluene ug/L 54.750 109 60-140
trans-1,2-Dichloroethene ug/L 55.950 112 60-140
trans-1,3-Dichloropropene ug/L 58.950 118 60-140
Trichloroethene ug/L 54.750 109 60-140
Trichlorofluoromethane ug/L 44.650 89 60-140
Vinyl chloride ug/L 51.650 103 60-140
Xylene (Total)ug/L 165150 110 60-140
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%103 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3218872MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92530999003
3218873
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 400 109 60-140113 3 30400ND435451
1,1,1-Trichloroethane ug/L 400 114 60-140115 0 30400ND457458
1,1,2,2-Tetrachloroethane ug/L 400 113 60-140114 1 30400ND451455
1,1,2-Trichloroethane ug/L 400 103 60-140109 6 30400ND412438
1,1-Dichloroethane ug/L 400 111 60-140114 2 30400ND446455
1,1-Dichloroethene ug/L 400 115 60-140121 5 30400ND460484
1,1-Dichloropropene ug/L 400 113 60-140114 1 30400ND451456
1,2,3-Trichlorobenzene ug/L 400 96 60-140109 13 30400ND382434
1,2,3-Trichloropropane ug/L 400 116 60-140118 2 30400ND463474
1,2,4-Trichlorobenzene ug/L 400 96 60-140108 11 30400ND385431
1,2,4-Trimethylbenzene ug/L E,M14002260-140186 16 30400370037904440
1,2-Dibromo-3-
chloropropane ug/L 400 111 60-140118 7 30400ND442473
1,2-Dibromoethane (EDB)ug/L 400 106 60-140110 3 30400ND425439
1,2-Dichlorobenzene ug/L 400 103 60-140109 6 30400ND412437
1,2-Dichloroethane ug/L 400 97 60-14099 2 30400ND389395
1,2-Dichloropropane ug/L 400 113 60-140114 1 30400ND452455
1,3,5-Trimethylbenzene ug/L M140036860-140429 15 30400ND14701720
1,3-Dichlorobenzene ug/L 400 100 60-140108 7 30400ND401432
1,3-Dichloropropane ug/L 400 107 60-140110 2 30400ND429439
1,4-Dichlorobenzene ug/L 400 102 60-140109 7 30400ND408436
2,2-Dichloropropane ug/L 400 94 60-14094 0 30400ND376376
2-Chlorotoluene ug/L M140012960-140143 10 30400ND516571
4-Chlorotoluene ug/L 400 93 60-14099 6 30400ND374397
Benzene ug/L 400 108 60-140111 3 30400ND434445
Bromobenzene ug/L 400 102 60-140107 5 30400ND409429
Bromochloromethane ug/L 400 108 60-140110 2 30400ND433441
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3218872MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92530999003
3218873
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 400 106 60-140114 7 30400ND424454
Bromoform ug/L 400 109 60-140110 2 30400ND434441
Bromomethane ug/L 400 95 60-140102 7 30400ND380408
Carbon tetrachloride ug/L 400 110 60-140119 8 30400ND442477
Chlorobenzene ug/L 400 106 60-140111 5 30400ND424444
Chloroethane ug/L 400 113 60-140114 1 30400ND451454
Chloroform ug/L 400 100 60-140104 4 30400ND400415
Chloromethane ug/L 400 96 60-140100 5 30400ND384402
cis-1,2-Dichloroethene ug/L 400 112 60-140114 1 30400ND449455
cis-1,3-Dichloropropene ug/L 400 106 60-140110 4 30400ND423441
Dibromochloromethane ug/L 400 110 60-140114 4 30400ND439457
Dibromomethane ug/L 400 104 60-140109 4 30400ND418434
Dichlorodifluoromethane ug/L 400 76 60-14079 4 30400ND304316
Diisopropyl ether ug/L 400 102 60-140105 3 30400ND407421
Ethanol ug/L 16000 99 60-140102 3 3016000ND1580016300
Ethyl-tert-butyl ether ug/L 800 104 60-140106 3 30800ND829851
Ethylbenzene ug/L M14008760-140155 11 30400199023402610
Hexachloro-1,3-butadiene ug/L 400 92 60-140105 13 30400ND368421
Isopropylbenzene
(Cumene)ug/L 400 107 60-140128 10 30400360790870
m&p-Xylene ug/L 800 101 60-140131 9 30800163024402680
Methyl-tert-butyl ether ug/L 400 102 60-140102 0 30400ND408409
Methylene Chloride ug/L 400 106 60-140107 1 30400ND424428
n-Butylbenzene ug/L M140015260-140158 4 30400ND606630
n-Propylbenzene ug/L M140032660-140382 16 30400ND13001530
Naphthalene ug/L 400 88 60-140130 15 3040074511001270
o-Xylene ug/L 400 106 60-140123 8 30400444868938
sec-Butylbenzene ug/L 400 114 60-140123 8 30400ND455492
Styrene ug/L 400 111 60-140117 5 3040050.1 492 518
tert-Amyl Alcohol ug/L 8000 100 60-14099 1 308000ND79907950
tert-Amylmethyl ether ug/L 800 100 60-140102 3 30800ND799819
tert-Butyl Alcohol ug/L 4000 106 60-140106 0 304000ND42504240
tert-Butyl Formate ug/L 3200 91 60-14090 2 303200ND29302880
tert-Butylbenzene ug/L 400 89 60-14094 5 30400ND355374
Tetrachloroethene ug/L 400 108 60-140111 3 30400ND431446
Toluene ug/L 400 109 60-140109 0 30400113547547
trans-1,2-Dichloroethene ug/L 400 111 60-140114 3 30400ND444458
trans-1,3-Dichloropropene ug/L 400 103 60-140107 4 30400ND412430
Trichloroethene ug/L 400 107 60-140111 4 30400ND428445
Trichlorofluoromethane ug/L 400 103 60-140105 3 30400ND410421
Vinyl chloride ug/L 400 95 60-140102 7 30400ND379407
Xylene (Total)ug/L 1200 103 60-140129 9 301200207033003620
1,2-Dichloroethane-d4 (S)%104 70-130101
4-Bromofluorobenzene (S)%104 70-130103
Toluene-d8 (S)%98 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
611675
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92531085001, 92531085002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3219796
Associated Lab Samples:92531085001, 92531085002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 04/06/21 10:430.31
1,1,1-Trichloroethane ug/L <0.33 0.50 04/06/21 10:430.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 04/06/21 10:430.22
1,1,2-Trichloroethane ug/L <0.32 0.50 04/06/21 10:430.32
1,1-Dichloroethane ug/L <0.37 0.50 04/06/21 10:430.37
1,1-Dichloroethene ug/L <0.35 0.50 04/06/21 10:430.35
1,1-Dichloropropene ug/L <0.43 0.50 04/06/21 10:430.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 04/06/21 10:430.81
1,2,3-Trichloropropane ug/L <0.26 0.50 04/06/21 10:430.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 04/06/21 10:430.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 04/06/21 10:430.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 04/06/21 10:430.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 04/06/21 10:430.27
1,2-Dichlorobenzene ug/L <0.34 0.50 04/06/21 10:430.34
1,2-Dichloroethane ug/L <0.32 0.50 04/06/21 10:430.32
1,2-Dichloropropane ug/L <0.36 0.50 04/06/21 10:430.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 04/06/21 10:430.33
1,3-Dichlorobenzene ug/L <0.34 0.50 04/06/21 10:430.34
1,3-Dichloropropane ug/L <0.28 0.50 04/06/21 10:430.28
1,4-Dichlorobenzene ug/L <0.33 0.50 04/06/21 10:430.33
2,2-Dichloropropane ug/L <0.39 0.50 04/06/21 10:430.39
2-Chlorotoluene ug/L <0.32 0.50 04/06/21 10:430.32
4-Chlorotoluene ug/L <0.32 0.50 04/06/21 10:430.32
Benzene ug/L <0.34 0.50 04/06/21 10:430.34
Bromobenzene ug/L <0.29 0.50 04/06/21 10:430.29
Bromochloromethane ug/L <0.47 0.50 04/06/21 10:430.47
Bromodichloromethane ug/L <0.31 0.50 04/06/21 10:430.31
Bromoform ug/L <0.34 0.50 04/06/21 10:430.34
Bromomethane ug/L <1.7 5.0 04/06/21 10:431.7
Carbon tetrachloride ug/L <0.33 0.50 04/06/21 10:430.33
Chlorobenzene ug/L <0.28 0.50 04/06/21 10:430.28
Chloroethane ug/L <0.65 1.0 04/06/21 10:430.65
Chloroform ug/L <0.35 0.50 04/06/21 10:430.35
Chloromethane ug/L <0.54 1.0 04/06/21 10:430.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 04/06/21 10:430.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 04/06/21 10:430.36
Dibromochloromethane ug/L <0.36 0.50 04/06/21 10:430.36
Dibromomethane ug/L <0.39 0.50 04/06/21 10:430.39
Dichlorodifluoromethane ug/L <0.35 0.50 04/06/21 10:430.35
Diisopropyl ether ug/L <0.31 0.50 04/06/21 10:430.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3219796
Associated Lab Samples:92531085001, 92531085002
Matrix:Water
AnalyzedMDL
Ethanol ug/L <72.2 200 04/06/21 10:4372.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 04/06/21 10:433.2
Ethylbenzene ug/L <0.30 0.50 04/06/21 10:430.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 04/06/21 10:431.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 04/06/21 10:430.33
m&p-Xylene ug/L <0.71 1.0 04/06/21 10:430.71
Methyl-tert-butyl ether ug/L <0.42 0.50 04/06/21 10:430.42
Methylene Chloride ug/L <2.0 2.0 04/06/21 10:432.0
n-Butylbenzene ug/L <0.49 0.50 04/06/21 10:430.49
n-Propylbenzene ug/L <0.34 0.50 04/06/21 10:430.34
Naphthalene ug/L <0.64 2.0 04/06/21 10:430.64
o-Xylene ug/L <0.34 0.50 04/06/21 10:430.34
sec-Butylbenzene ug/L <0.40 0.50 04/06/21 10:430.40
Styrene ug/L <0.29 0.50 04/06/21 10:430.29
tert-Amyl Alcohol ug/L <36.4 100 04/06/21 10:4336.4
tert-Amylmethyl ether ug/L <2.7 10.0 04/06/21 10:432.7
tert-Butyl Alcohol ug/L <26.8 50.0 04/06/21 10:4326.8
tert-Butyl Formate ug/L <29.4 50.0 04/06/21 10:4329.4
tert-Butylbenzene ug/L <0.32 0.50 04/06/21 10:430.32
Tetrachloroethene ug/L <0.29 0.50 04/06/21 10:430.29
Toluene ug/L <0.48 0.50 04/06/21 10:430.48
trans-1,2-Dichloroethene ug/L <0.40 0.50 04/06/21 10:430.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 04/06/21 10:430.36
Trichloroethene ug/L <0.38 0.50 04/06/21 10:430.38
Trichlorofluoromethane ug/L <0.30 1.0 04/06/21 10:430.30
Vinyl chloride ug/L <0.39 1.0 04/06/21 10:430.39
Xylene (Total)ug/L <0.34 1.0 04/06/21 10:430.34
1,2-Dichloroethane-d4 (S)%99 70-130 04/06/21 10:43
4-Bromofluorobenzene (S)%98 70-130 04/06/21 10:43
Toluene-d8 (S)%104 70-130 04/06/21 10:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3219797LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.650 103 60-140
1,1,1-Trichloroethane ug/L 50.950 102 60-140
1,1,2,2-Tetrachloroethane ug/L 51.050 102 60-140
1,1,2-Trichloroethane ug/L 50.750 101 60-140
1,1-Dichloroethane ug/L 51.250 102 60-140
1,1-Dichloroethene ug/L 53.950 108 60-140
1,1-Dichloropropene ug/L 51.150 102 60-140
1,2,3-Trichlorobenzene ug/L 50.450 101 60-140
1,2,3-Trichloropropane ug/L 49.450 99 60-140
1,2,4-Trichlorobenzene ug/L 50.150 100 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3219797LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 50.850 102 60-140
1,2-Dibromo-3-chloropropane ug/L 51.750 103 60-140
1,2-Dibromoethane (EDB)ug/L 49.750 99 60-140
1,2-Dichlorobenzene ug/L 48.650 97 60-140
1,2-Dichloroethane ug/L 44.450 89 60-140
1,2-Dichloropropane ug/L 52.250 104 60-140
1,3,5-Trimethylbenzene ug/L 50.950 102 60-140
1,3-Dichlorobenzene ug/L 50.350 101 60-140
1,3-Dichloropropane ug/L 50.250 100 60-140
1,4-Dichlorobenzene ug/L 50.750 101 60-140
2,2-Dichloropropane ug/L 53.250 106 60-140
2-Chlorotoluene ug/L 50.650 101 60-140
4-Chlorotoluene ug/L 48.650 97 60-140
Benzene ug/L 50.950 102 60-140
Bromobenzene ug/L 48.950 98 60-140
Bromochloromethane ug/L 51.250 102 60-140
Bromodichloromethane ug/L 52.550 105 60-140
Bromoform ug/L 53.450 107 60-140
Bromomethane ug/L 47.350 95 60-140
Carbon tetrachloride ug/L 53.050 106 60-140
Chlorobenzene ug/L 50.850 102 60-140
Chloroethane ug/L 41.750 83 60-140
Chloroform ug/L 44.750 89 60-140
Chloromethane ug/L 48.950 98 60-140
cis-1,2-Dichloroethene ug/L 51.350 103 60-140
cis-1,3-Dichloropropene ug/L 53.950 108 60-140
Dibromochloromethane ug/L 53.550 107 60-140
Dibromomethane ug/L 50.550 101 60-140
Dichlorodifluoromethane ug/L 47.250 94 60-140
Diisopropyl ether ug/L 46.550 93 60-140
Ethanol ug/L 18402000 92 60-140
Ethyl-tert-butyl ether ug/L 96.0100 96 60-140
Ethylbenzene ug/L 50.850 102 60-140
Hexachloro-1,3-butadiene ug/L 51.150 102 60-140
Isopropylbenzene (Cumene)ug/L 54.250 108 60-140
m&p-Xylene ug/L 104100 104 60-140
Methyl-tert-butyl ether ug/L 46.350 93 60-140
Methylene Chloride ug/L 46.850 94 60-140
n-Butylbenzene ug/L 51.850 104 60-140
n-Propylbenzene ug/L 49.450 99 60-140
Naphthalene ug/L 49.450 99 60-140
o-Xylene ug/L 50.850 102 60-140
sec-Butylbenzene ug/L 50.150 100 60-140
Styrene ug/L 53.750 107 60-140
tert-Amyl Alcohol ug/L 9141000 91 60-140
tert-Amylmethyl ether ug/L 96.4100 96 60-140
tert-Butyl Alcohol ug/L 437500 87 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3219797LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 399400 100 60-140
tert-Butylbenzene ug/L 42.950 86 60-140
Tetrachloroethene ug/L 51.850 104 60-140
Toluene ug/L 50.350 101 60-140
trans-1,2-Dichloroethene ug/L 51.950 104 60-140
trans-1,3-Dichloropropene ug/L 53.550 107 60-140
Trichloroethene ug/L 50.550 101 60-140
Trichlorofluoromethane ug/L 43.250 86 60-140
Vinyl chloride ug/L 50.350 101 60-140
Xylene (Total)ug/L 155150 103 60-140
1,2-Dichloroethane-d4 (S)%93 70-130
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3219798MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92531085002
3219799
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 4000 109 60-140110 1 304000<62.2 4350 4390
1,1,1-Trichloroethane ug/L 4000 110 60-140117 6 304000<66.4 4410 4670
1,1,2,2-Tetrachloroethane ug/L 4000 106 60-140105 1 304000<45.0 4230 4190
1,1,2-Trichloroethane ug/L 4000 109 60-140112 3 304000<65.0 4360 4490
1,1-Dichloroethane ug/L 4000 109 60-140112 3 304000<73.4 4380 4490
1,1-Dichloroethene ug/L 4000 119 60-140119 0 304000<69.6 4750 4760
1,1-Dichloropropene ug/L 4000 112 60-140115 3 304000<85.4 4480 4600
1,2,3-Trichlorobenzene ug/L 4000 98 60-140106 7 304000<161 3920 4220
1,2,3-Trichloropropane ug/L 4000 104 60-140101 2 304000<52.2 4150 4050
1,2,4-Trichlorobenzene ug/L 4000 98 60-140104 7 304000<128 3900 4180
1,2,4-Trimethylbenzene ug/L 4000 108 60-140110 1 304000273070407140
1,2-Dibromo-3-
chloropropane ug/L 4000 100 60-140108 8 304000<68.0 3990 4320
1,2-Dibromoethane (EDB)ug/L 4000 110 60-140109 1 30400067350805020
1,2-Dichlorobenzene ug/L 4000 103 60-140103 0 304000<67.8 4140 4120
1,2-Dichloroethane ug/L 4000 96 60-14098 2 30400019540304110
1,2-Dichloropropane ug/L 4000 113 60-140112 1 304000<71.0 4510 4470
1,3,5-Trimethylbenzene ug/L 4000 127 60-140131 3 304000<66.4 5090 5240
1,3-Dichlorobenzene ug/L 4000 105 60-140108 3 304000<68.0 4200 4330
1,3-Dichloropropane ug/L 4000 109 60-140108 1 304000<56.8 4350 4310
1,4-Dichlorobenzene ug/L 4000 107 60-140108 1 304000<66.6 4280 4340
2,2-Dichloropropane ug/L 4000 103 60-140103 0 304000<77.6 4110 4130
2-Chlorotoluene ug/L 4000 113 60-140113 0 304000<64.2 4520 4500
4-Chlorotoluene ug/L 4000 104 60-140107 3 304000<64.8 4170 4290
Benzene ug/L 4000 116 60-140100 3 304000153001990019300
Bromobenzene ug/L 4000 106 60-140109 3 304000<58.0 4250 4360
Bromochloromethane ug/L 4000 108 60-140110 2 304000<93.6 4310 4390
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3219798MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92531085002
3219799
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 4000 111 60-140111 0 304000<61.4 4430 4430
Bromoform ug/L 4000 110 60-140106 3 304000<68.2 4380 4250
Bromomethane ug/L 4000 122 60-140117 4 304000<332 4860 4690
Carbon tetrachloride ug/L 4000 116 60-140117 1 304000<66.6 4630 4670
Chlorobenzene ug/L 4000 111 60-140110 1 304000<56.8 4430 4380
Chloroethane ug/L 4000 124 60-140120 3 304000<130 4970 4800
Chloroform ug/L 4000 95 60-14097 1 304000<70.6 3810 3860
Chloromethane ug/L 4000 99 60-140102 3 304000<108 3970 4100
cis-1,2-Dichloroethene ug/L 4000 110 60-140114 3 304000<76.8 4420 4570
cis-1,3-Dichloropropene ug/L 4000 110 60-140110 0 304000<73.0 4410 4400
Dibromochloromethane ug/L 4000 115 60-140113 1 304000<71.8 4580 4530
Dibromomethane ug/L 4000 108 60-140106 2 304000<78.8 4300 4230
Dichlorodifluoromethane ug/L 4000 89 60-14092 3 304000<69.2 3560 3680
Diisopropyl ether ug/L 4000 98 60-140102 4 304000<61.6 3970 4110
Ethanol ug/L 160000 91 60-14098 7 30160000<14400 146000 156000
Ethyl-tert-butyl ether ug/L 8000 101 60-140104 3 308000<648 8080 8340
Ethylbenzene ug/L 4000 109 60-140109 0 304000222066006590
Hexachloro-1,3-butadiene ug/L 4000 101 60-140105 4 304000<306 4040 4180
Isopropylbenzene
(Cumene)ug/L 4000 115 60-140115 1 30400010646904720
m&p-Xylene ug/L 8000 113 60-140110 1 308000101001910018800
Methyl-tert-butyl ether ug/L 4000 97 60-140100 3 304000<84.4 3920 4060
Methylene Chloride ug/L 4000 104 60-140105 1 304000<390 4150 4190
n-Butylbenzene ug/L 4000 105 60-140104 1 304000<98.0 4210 4170
n-Propylbenzene ug/L 4000 114 60-140116 2 304000<68.0 4550 4640
Naphthalene ug/L 4000 91 60-140101 8 30400099046505050
o-Xylene ug/L 4000 123 60-140109 6 304000493098709280
sec-Butylbenzene ug/L 4000 109 60-140111 2 304000<80.0 4350 4450
Styrene ug/L 4000 118 60-140113 4 30400075.4J 4790 4600
tert-Amyl Alcohol ug/L 80000 102 60-140109 6 3080000<7280 81800 86900
tert-Amylmethyl ether ug/L 8000 99 60-140101 2 308000<532 7880 8060
tert-Butyl Alcohol ug/L 40000 95 60-140103 8 3040000<5360 38000 41400
tert-Butyl Formate ug/L 32000 98 60-140103 5 3032000<5880 31400 33000
tert-Butylbenzene ug/L 4000 93 60-14095 3 304000<64.6 3700 3820
Tetrachloroethene ug/L 4000 109 60-140111 2 304000<58.4 4370 4440
Toluene ug/L 4000 109 60-140121 1 304000284003270033200
trans-1,2-Dichloroethene ug/L 4000 112 60-140115 3 304000<79.2 4470 4610
trans-1,3-Dichloropropene ug/L 4000 109 60-140115 5 304000<72.6 4360 4590
Trichloroethene ug/L 4000 112 60-140110 2 304000<76.6 4490 4410
Trichlorofluoromethane ug/L 4000 113 60-140112 0 304000<59.6 4500 4490
Vinyl chloride ug/L 4000 103 60-140104 2 304000<77.2 4110 4170
Xylene (Total)ug/L 12000 117 60-140109 3 3012000150002900028100
1,2-Dichloroethane-d4 (S)%98 70-130102
4-Bromofluorobenzene (S)%102 70-130101
Toluene-d8 (S)%100 70-130105
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
611676
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92531085005, 92531085007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3219802
Associated Lab Samples:92531085005, 92531085007
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 04/06/21 20:380.31
1,1,1-Trichloroethane ug/L <0.33 0.50 04/06/21 20:380.33
1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 04/06/21 20:380.22
1,1,2-Trichloroethane ug/L <0.32 0.50 04/06/21 20:380.32
1,1-Dichloroethane ug/L <0.37 0.50 04/06/21 20:380.37
1,1-Dichloroethene ug/L <0.35 0.50 04/06/21 20:380.35
1,1-Dichloropropene ug/L <0.43 0.50 04/06/21 20:380.43
1,2,3-Trichlorobenzene ug/L <0.81 2.0 04/06/21 20:380.81
1,2,3-Trichloropropane ug/L <0.26 0.50 04/06/21 20:380.26
1,2,4-Trichlorobenzene ug/L <0.64 2.0 04/06/21 20:380.64
1,2,4-Trimethylbenzene ug/L <0.50 0.50 04/06/21 20:380.50
1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 04/06/21 20:380.34
1,2-Dibromoethane (EDB)ug/L <0.27 0.50 04/06/21 20:380.27
1,2-Dichlorobenzene ug/L <0.34 0.50 04/06/21 20:380.34
1,2-Dichloroethane ug/L <0.32 0.50 04/06/21 20:380.32
1,2-Dichloropropane ug/L <0.36 0.50 04/06/21 20:380.36
1,3,5-Trimethylbenzene ug/L <0.33 0.50 04/06/21 20:380.33
1,3-Dichlorobenzene ug/L <0.34 0.50 04/06/21 20:380.34
1,3-Dichloropropane ug/L <0.28 0.50 04/06/21 20:380.28
1,4-Dichlorobenzene ug/L <0.33 0.50 04/06/21 20:380.33
2,2-Dichloropropane ug/L <0.39 0.50 04/06/21 20:380.39
2-Chlorotoluene ug/L <0.32 0.50 04/06/21 20:380.32
4-Chlorotoluene ug/L <0.32 0.50 04/06/21 20:380.32
Benzene ug/L <0.34 0.50 04/06/21 20:380.34
Bromobenzene ug/L <0.29 0.50 04/06/21 20:380.29
Bromochloromethane ug/L <0.47 0.50 04/06/21 20:380.47
Bromodichloromethane ug/L <0.31 0.50 04/06/21 20:380.31
Bromoform ug/L <0.34 0.50 04/06/21 20:380.34
Bromomethane ug/L <1.7 5.0 04/06/21 20:381.7
Carbon tetrachloride ug/L <0.33 0.50 04/06/21 20:380.33
Chlorobenzene ug/L <0.28 0.50 04/06/21 20:380.28
Chloroethane ug/L <0.65 1.0 04/06/21 20:380.65
Chloroform ug/L <0.35 0.50 04/06/21 20:380.35
Chloromethane ug/L <0.54 1.0 04/06/21 20:380.54
cis-1,2-Dichloroethene ug/L <0.38 0.50 04/06/21 20:380.38
cis-1,3-Dichloropropene ug/L <0.36 0.50 04/06/21 20:380.36
Dibromochloromethane ug/L <0.36 0.50 04/06/21 20:380.36
Dibromomethane ug/L <0.39 0.50 04/06/21 20:380.39
Dichlorodifluoromethane ug/L <0.35 0.50 04/06/21 20:380.35
Diisopropyl ether ug/L <0.31 0.50 04/06/21 20:380.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3219802
Associated Lab Samples:92531085005, 92531085007
Matrix:Water
AnalyzedMDL
Ethanol ug/L <72.2 200 04/06/21 20:3872.2
Ethyl-tert-butyl ether ug/L <3.2 10.0 04/06/21 20:383.2
Ethylbenzene ug/L <0.30 0.50 04/06/21 20:380.30
Hexachloro-1,3-butadiene ug/L <1.5 2.0 04/06/21 20:381.5
Isopropylbenzene (Cumene)ug/L <0.33 0.50 04/06/21 20:380.33
m&p-Xylene ug/L <0.71 1.0 04/06/21 20:380.71
Methyl-tert-butyl ether ug/L <0.42 0.50 04/06/21 20:380.42
Methylene Chloride ug/L <2.0 2.0 04/06/21 20:382.0
n-Butylbenzene ug/L <0.49 0.50 04/06/21 20:380.49
n-Propylbenzene ug/L <0.34 0.50 04/06/21 20:380.34
Naphthalene ug/L <0.64 2.0 04/06/21 20:380.64
o-Xylene ug/L <0.34 0.50 04/06/21 20:380.34
sec-Butylbenzene ug/L <0.40 0.50 04/06/21 20:380.40
Styrene ug/L <0.29 0.50 04/06/21 20:380.29
tert-Amyl Alcohol ug/L <36.4 100 04/06/21 20:3836.4
tert-Amylmethyl ether ug/L <2.7 10.0 04/06/21 20:382.7
tert-Butyl Alcohol ug/L <26.8 50.0 04/06/21 20:3826.8
tert-Butyl Formate ug/L <29.4 50.0 04/06/21 20:3829.4
tert-Butylbenzene ug/L <0.32 0.50 04/06/21 20:380.32
Tetrachloroethene ug/L <0.29 0.50 04/06/21 20:380.29
Toluene ug/L <0.48 0.50 04/06/21 20:380.48
trans-1,2-Dichloroethene ug/L <0.40 0.50 04/06/21 20:380.40
trans-1,3-Dichloropropene ug/L <0.36 0.50 04/06/21 20:380.36
Trichloroethene ug/L <0.38 0.50 04/06/21 20:380.38
Trichlorofluoromethane ug/L <0.30 1.0 04/06/21 20:380.30
Vinyl chloride ug/L <0.39 1.0 04/06/21 20:380.39
Xylene (Total)ug/L <0.34 1.0 04/06/21 20:380.34
1,2-Dichloroethane-d4 (S)%96 70-130 04/06/21 20:38
4-Bromofluorobenzene (S)%97 70-130 04/06/21 20:38
Toluene-d8 (S)%107 70-130 04/06/21 20:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3219803LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.950 98 60-140
1,1,1-Trichloroethane ug/L 48.550 97 60-140
1,1,2,2-Tetrachloroethane ug/L 49.150 98 60-140
1,1,2-Trichloroethane ug/L 48.650 97 60-140
1,1-Dichloroethane ug/L 49.250 98 60-140
1,1-Dichloroethene ug/L 51.250 102 60-140
1,1-Dichloropropene ug/L 47.450 95 60-140
1,2,3-Trichlorobenzene ug/L 47.450 95 60-140
1,2,3-Trichloropropane ug/L 47.850 96 60-140
1,2,4-Trichlorobenzene ug/L 46.450 93 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3219803LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/L 46.950 94 60-140
1,2-Dibromo-3-chloropropane ug/L 49.950 100 60-140
1,2-Dibromoethane (EDB)ug/L 48.250 96 60-140
1,2-Dichlorobenzene ug/L 47.350 95 60-140
1,2-Dichloroethane ug/L 43.050 86 60-140
1,2-Dichloropropane ug/L 49.550 99 60-140
1,3,5-Trimethylbenzene ug/L 48.050 96 60-140
1,3-Dichlorobenzene ug/L 47.950 96 60-140
1,3-Dichloropropane ug/L 48.650 97 60-140
1,4-Dichlorobenzene ug/L 48.450 97 60-140
2,2-Dichloropropane ug/L 44.850 90 60-140
2-Chlorotoluene ug/L 48.150 96 60-140
4-Chlorotoluene ug/L 46.650 93 60-140
Benzene ug/L 49.050 98 60-140
Bromobenzene ug/L 47.150 94 60-140
Bromochloromethane ug/L 49.550 99 60-140
Bromodichloromethane ug/L 49.550 99 60-140
Bromoform ug/L 51.350 103 60-140
Bromomethane ug/L 48.350 97 60-140
Carbon tetrachloride ug/L 48.650 97 60-140
Chlorobenzene ug/L 47.950 96 60-140
Chloroethane ug/L 41.550 83 60-140
Chloroform ug/L 43.050 86 60-140
Chloromethane ug/L 47.150 94 60-140
cis-1,2-Dichloroethene ug/L 48.950 98 60-140
cis-1,3-Dichloropropene ug/L 48.450 97 60-140
Dibromochloromethane ug/L 52.350 105 60-140
Dibromomethane ug/L 47.550 95 60-140
Dichlorodifluoromethane ug/L 43.350 87 60-140
Diisopropyl ether ug/L 44.550 89 60-140
Ethanol ug/L 17902000 89 60-140
Ethyl-tert-butyl ether ug/L 93.4100 93 60-140
Ethylbenzene ug/L 47.450 95 60-140
Hexachloro-1,3-butadiene ug/L 44.550 89 60-140
Isopropylbenzene (Cumene)ug/L 50.450 101 60-140
m&p-Xylene ug/L 97.3100 97 60-140
Methyl-tert-butyl ether ug/L 44.850 90 60-140
Methylene Chloride ug/L 45.250 90 60-140
n-Butylbenzene ug/L 46.250 92 60-140
n-Propylbenzene ug/L 46.750 93 60-140
Naphthalene ug/L 48.050 96 60-140
o-Xylene ug/L 47.950 96 60-140
sec-Butylbenzene ug/L 47.150 94 60-140
Styrene ug/L 50.450 101 60-140
tert-Amyl Alcohol ug/L 8861000 89 60-140
tert-Amylmethyl ether ug/L 90.8100 91 60-140
tert-Butyl Alcohol ug/L 437500 87 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
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Page 39 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3219803LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butyl Formate ug/L 379400 95 60-140
tert-Butylbenzene ug/L 40.650 81 60-140
Tetrachloroethene ug/L 47.250 94 60-140
Toluene ug/L 47.450 95 60-140
trans-1,2-Dichloroethene ug/L 49.350 99 60-140
trans-1,3-Dichloropropene ug/L 49.350 99 60-140
Trichloroethene ug/L 47.850 96 60-140
Trichlorofluoromethane ug/L 41.850 84 60-140
Vinyl chloride ug/L 47.550 95 60-140
Xylene (Total)ug/L 145150 97 60-140
1,2-Dichloroethane-d4 (S)%91 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3219804MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92531231003
3219805
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 96 60-140106 10 3020ND19.2 21.1
1,1,1-Trichloroethane ug/L 20 99 60-140107 7 3020ND19.9 21.4
1,1,2,2-Tetrachloroethane ug/L 20 96 60-140105 9 3020ND19.2 21.1
1,1,2-Trichloroethane ug/L 20 93 60-140104 11 3020ND18.6 20.8
1,1-Dichloroethane ug/L 20 101 60-140105 4 3020ND20.2 21.1
1,1-Dichloroethene ug/L 20 107 60-140112 4 3020ND21.5 22.3
1,1-Dichloropropene ug/L 20 101 60-140106 5 3020ND20.2 21.2
1,2,3-Trichlorobenzene ug/L 20 105 60-140109 4 3020ND21.1 21.8
1,2,3-Trichloropropane ug/L 20 92 60-140101 10 3020ND18.3 20.3
1,2,4-Trichlorobenzene ug/L 20 104 60-140107 3 3020ND20.8 21.5
1,2,4-Trimethylbenzene ug/L 20 99 60-140108 9 3020ND19.7 21.7
1,2-Dibromo-3-
chloropropane ug/L 20 104 60-140116 11 3020ND20.8 23.3
1,2-Dibromoethane (EDB)ug/L 20 96 60-140104 8 3020ND19.1 20.8
1,2-Dichlorobenzene ug/L 20 93 60-140103 11 3020ND18.5 20.6
1,2-Dichloroethane ug/L 20 86 60-14093 8 3020ND17.3 18.6
1,2-Dichloropropane ug/L 20 98 60-140107 9 3020ND19.5 21.4
1,3,5-Trimethylbenzene ug/L 20 100 60-140110 10 3020ND19.9 22.0
1,3-Dichlorobenzene ug/L 20 94 60-140104 10 3020ND18.8 20.7
1,3-Dichloropropane ug/L 20 96 60-140106 9 3020ND19.3 21.1
1,4-Dichlorobenzene ug/L 20 95 60-140105 10 3020ND19.0 21.1
2,2-Dichloropropane ug/L 20 106 60-140111 5 3020ND21.1 22.2
2-Chlorotoluene ug/L 20 97 60-140109 11 3020ND19.5 21.8
4-Chlorotoluene ug/L 20 94 60-140103 9 3020ND18.8 20.5
Benzene ug/L 20 95 60-140105 10 3020ND19.1 21.0
Bromobenzene ug/L 20 95 60-140106 10 3020ND19.1 21.2
Bromochloromethane ug/L 20 96 60-140103 6 3020ND19.3 20.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3219804MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92531231003
3219805
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromodichloromethane ug/L 20 96 60-140107 10 3020ND19.3 21.4
Bromoform ug/L 20 97 60-140104 7 3020ND19.4 20.9
Bromomethane ug/L 20 102 60-140108 6 3020ND20.4 21.7
Carbon tetrachloride ug/L 20 101 60-140109 8 3020ND20.1 21.9
Chlorobenzene ug/L 20 96 60-140105 9 3020ND19.3 21.0
Chloroethane ug/L 20 102 60-140106 4 3020ND20.3 21.2
Chloroform ug/L 20 87 60-14092 6 3020ND17.3 18.4
Chloromethane ug/L 20 96 60-14097 1 3020ND19.2 19.5
cis-1,2-Dichloroethene ug/L 20 101 60-140108 7 3020ND20.1 21.6
cis-1,3-Dichloropropene ug/L 20 98 60-140108 9 3020ND19.7 21.5
Dibromochloromethane ug/L 20 99 60-140110 10 3020ND19.9 22.0
Dibromomethane ug/L 20 94 60-140101 7 3020ND18.8 20.3
Dichlorodifluoromethane ug/L 20 68 60-14070 2 3020ND13.6 13.9
Diisopropyl ether ug/L 20 89 60-14096 8 3020ND17.8 19.3
Ethanol ug/L 800 93 60-14098 5 30800ND748787
Ethyl-tert-butyl ether ug/L 40 93 60-14099 7 3040ND37.1 39.7
Ethylbenzene ug/L 20 97 60-140105 8 3020ND19.4 20.9
Hexachloro-1,3-butadiene ug/L 20 112 60-140117 4 3020ND22.5 23.3
Isopropylbenzene
(Cumene)ug/L 20 102 60-140110 7 3020ND20.5 22.1
m&p-Xylene ug/L 40 98 60-140107 9 3040ND39.3 42.9
Methyl-tert-butyl ether ug/L 20 89 60-14095 6 3020ND17.9 19.0
Methylene Chloride ug/L 20 94 60-140100 6 3020ND18.8 20.0
n-Butylbenzene ug/L 20 102 60-140111 8 3020ND20.4 22.1
n-Propylbenzene ug/L 20 98 60-140108 10 3020ND19.7 21.7
Naphthalene ug/L 20 101 60-140107 6 3020ND20.1 21.4
o-Xylene ug/L 20 96 60-140103 7 3020ND19.2 20.7
sec-Butylbenzene ug/L 20 100 60-140110 10 3020ND20.0 22.0
Styrene ug/L 20 95 60-140105 10 3020ND19.0 21.1
tert-Amyl Alcohol ug/L 400 87 60-14097 11 30400ND349389
tert-Amylmethyl ether ug/L 40 88 60-14097 9 3040ND35.2 38.7
tert-Butyl Alcohol ug/L 200 115 60-140130 12 30200ND230259
tert-Butyl Formate ug/L P51603260-14024 30160ND50.5 38.3J
tert-Butylbenzene ug/L 20 86 60-14095 11 3020ND17.1 19.1
Tetrachloroethene ug/L 20 101 60-140106 5 3020ND20.2 21.2
Toluene ug/L 20 93 60-140110 16 30201.6 20.1 23.6
trans-1,2-Dichloroethene ug/L 20 103 60-140109 6 3020ND20.5 21.9
trans-1,3-Dichloropropene ug/L 20 98 60-140109 10 3020ND19.6 21.8
Trichloroethene ug/L 20 95 60-140104 9 3020ND19.1 20.9
Trichlorofluoromethane ug/L 20 92 60-14098 7 3020ND18.3 19.7
Vinyl chloride ug/L 20 91 60-14095 4 3020ND18.2 19.0
Xylene (Total)ug/L 60 97 60-140106 8 3060ND58.5 63.6
1,2-Dichloroethane-d4 (S)%102 70-130101
4-Bromofluorobenzene (S)%101 70-130100
Toluene-d8 (S)%99 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
611652
EPA 504.1
EPA 504.1
GCS 504 EDB DBCP
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92531085007, 92531085008, 92531085009, 92531085010, 92531085011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3219737
Associated Lab Samples:92531085007, 92531085008, 92531085009, 92531085010, 92531085011
Matrix:Water
AnalyzedMDL
1,2-Dibromoethane (EDB)ug/L <0.013 0.020 04/06/21 16:230.013
1-Chloro-2-bromopropane (S)%91 70-130 04/06/21 16:23
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3219738LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3219739
1,2-Dibromoethane (EDB)ug/L 0.250.25 101 70-1301070.27 8 20
1-Chloro-2-bromopropane (S)%97 70-130100
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3219741MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92531055002
3219742
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dibromoethane (EDB)ug/L 0.25 104 65-135108 3 200.25ND 0.26 0.27
1-Chloro-2-bromopropane
(S)
%95 70-13098
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92531055001
3219740SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L <0.013 20ND
1-Chloro-2-bromopropane (S)%9792
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 47
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.P5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 47
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92531085
WILLIAMS GROCERY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92531085007 611652 611816WSW-1 EPA 504.1 EPA 504.1
92531085008 611652 611816WSW-2 EPA 504.1 EPA 504.1
92531085009 611652 611816WSW-6 EPA 504.1 EPA 504.1
92531085010 611652 611816WSW-7 EPA 504.1 EPA 504.1
92531085011 611652 611816FB-1 EPA 504.1 EPA 504.1
92531085001 611675MW-1 SM 6200B
92531085002 611675MW-3 SM 6200B
92531085003 611410MW-5 SM 6200B
92531085004 611410MW-12 SM 6200B
92531085005 611676AS-1 SM 6200B
92531085006 611410TRIP BLANK SM 6200B
92531085007 611676WSW-1 SM 6200B
92531085008 611410WSW-2 SM 6200B
92531085009 611410WSW-6 SM 6200B
92531085010 611410WSW-7 SM 6200B
92531085011 611410FB-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2021 01:54 PM
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Huntersville, NC 28078
[phone]
Page 44 of 47
Page 45 of 47
Page 46 of 47
Page 47 of 47

APPENDIX D

HEALTH RISK EVALUATION (WSW-6)

April 15, 2021 TO: Herb Berger
NC UST Section
RE: Health Risk Evaluation Incident # 15063 Randy Simmerson Well Sampling Results
1717 Hamptonville Road
Yadkinville, NC During this sampling event, four contaminants were detected in the well water. The standards used to determine if the water is suitable for drinking and cooking are the United States Environmental Protection
Agency’s Maximum Contaminant Levels (MCLs) or, if no MCLs exist, North Carolina Groundwater Standards
(2L). If any contaminant concentrations exceed applicable standards for using the water for drinking and cooking, those contaminant concentrations are further analyzed to determine if the water is suitable for other
household uses, such as showering, bathing, washing dishes, flushing toilets, and hand washing. The chart
below compares the detected contaminant concentrations with the applicable standards: Sample ID Contaminant Concentration (µg/L) MCL (µg/L) 2L (µg/L)
92531085009 Bromodichloromethane 1.0 80*
Chloroform 5.4 80*
Dibromochloromethane 0.42 80*
Toluene 2.5 1,000
µg/L – Stands for micrograms of contaminant per liter of water and is roughly equivalent to parts per billion.
* As total trihalomethanes. RECOMMENDATION: None of the contaminants detected exceeded the applicable water standards.
Therefore, no restrictions on the use of this water are recommended at this time.

David Lilley, Environmental Toxicologist
Division of Waste Management, NCDEQ