WS-4653_15063_CA_MRP_20140313

TABLES
Ashley Enterprises 2425 US Highway 21
2117 US HWY 21 S. Hamptonville, NC 27020
Hamptonville, NC 27020
WSW2 Sandra Gail 2032 Petty Rd.
Gail 2508 US HWY 21 Hamptonville, NC 77020
Hamptonville, NC 27020
WSW3 Delma Church (deceased)1704 Hamptonville Rd.
Church 1704 Hamptonville Rd. Hamptonville, NC 27020
Hamptonville, NC 27020
WSW4 Derek A Shore 2424 US Highway 21
Shore 2424 US HWY 21 Hamptonville, NC 27020
Hamptonville, NC 27020
WSW5 Wesley Wall 1708, 1712 Hamptonville Rd.
Wall PO Box 206 Hamptonville, NC 27029
Sullivan Island, SC 29482
WSW6 John H. Gardner (deceased)1717 Hamptonville Rd.
Gardner 1717 Hamptonville Rd. Hamptonville, NC 27020
Hamptonville NC 27020
WSW7 Terry Windsor 2405 US Highway 21
Windsor 4139 Old US HWY 21 Hamptonville, NC 27020
Hamptonville NC 27020
Jerry Wall 1737 Hamptonville Rd.
PO Box 509 Hamptonville, NC 27020
Hamptonville, NC 27020
Willis Scowls 2401 US Highway 21
2401 US HWY 21 Hamptonville, NC 27020
Hamptonville NC 27020
Olen King 2345 US Highway 21
2345 US HWY 21 Hamptonville, NC 27020
Hamptonville, NC 27020
Charles Moorefield 2337 US Highway 21
2337 US HWY 21 Hamptonville, NC 27020
Hamptonville, NC 27020
Minnie Chappell 1515 Dooley Rd.
1308 Ruck Sholes Rd. Hamptonville, NC 27020
Hamptonville, NC 27020
Undo S. Wall 2352 US Highway 21
2352 US HWY 21 Hamptonville, NC 27020
Hamptonville, NC 27020
Minnie Chappell 1515 Dooley Rd.
1308 Buck Sholes Rd. Hamptonville, NC 27020
Hamptonville, NC 27020
Ralph Talley 2328 US Highway 21
7328 US HWY 21 Hamptonville, NC 27020
Hamptonville, NC 27020
Walter Durham 2325 US Highway 21
2329 US HWY 21 Hamptonville, NC 27020
Hamptonville, NC 27020
Glenn Wall 1744 Hamptonville Rd.
1744 Hamptonville Rd Hamptonville NC 27020
Hamptonville, NC 27020
Bobby D. Church 2516 US Highway 21
2516 US HWY 21 Hamptonville, NC 27020
Hamptonville, NC 27020
sole source unknown unknown unknown unknown 103
INCIDENT # 15063
sole source unknown unknown unknown unknown 345
sole source unknown Drilled unknown unknown 642
Well AddressWell Owner/AddressWell ID No
Distance from Source
Area of Release (feet)
sole source unknown unknown unknown unknown 397
sole source unknown unknown unknown unknown 820
sole source unknown unknown unknown 468 450
sole source unknown unknown unknown unknown 303
925
WSW9
sole source unknown unknown unknown unknown 655
WSW8
sole source unknown unknown unknown unknown
695
WSW11
solo source unknown unknown unknown unknown 943
WSW10
note source unknown unknown unknown unknown
1,040
WSW13
sole source unknown unknown unknown unknown 1,463
WSW12
sole source unknown unknown unknown unknown
unknown unknown
1,117
WSW15
sole source unknown unknown unknown unknown 1,317
WSW14
sole source unknown unknown unknown unknown
692
Notes:
1. "BGS" =feet below ground surface.
2. Information obtained from Terraquest Water Supply Well Information table (June 2012), telephone and field Interviews (February 2014) and Yadkin County GIS; revised information shown in itlaics.
3. Well ID numbers are displayed on Figure 2.
WSW1
on site
WSW18
sole source unknown unknown unknown unknown
1,291
WSW17
sole source unknown unknown unknown unknown 1,044
WSW16
sole source unknown unknown
Screen Interval
(feet BGS)
Casing Depth
(feet BGS)Type of Well
Well Depth
(feet BGS)Well Use
TABLE 1
WATER SUPPLY WELL INFORMATION
WILLIAMS GROCERY
S&ME PROJECT NO. 4305-14-066
Well ID
Top of
Casing
Elevation*
(ft.)
Depth to Water
from Top
of Casing (ft.)
February 25, 2014
Groundwater
Elevation*
(ft.)
MW-1 23 to 33 498.82 22.28 476.54
MW-2 20 to 30 499.27 22.47 476.80
MW-3 23 to 33 499.47 22.78 476.69
MW-4 24 to 34 499.45 22.77 476.68
MW-5 24 to 34 498.34 22.54 475.80
MW-6 24 to 34 495.39 19.24 476.15
RW-1 499.38 22.75 476.63
Top of Casing Elevations provided from previous consultant reports.
Screen
Interval
(x to y ft.
BGS)
Note: MW-7, MW-8, MW-9 and MW-10 were reported as "could not locate" in previous
monitoring reports.
unknown
Table 2
Monitor Well Construction and Groundwater Level Data
Williams Grocery
Incident #15063
S&ME Project No. 4305-14-066
Method
Monitor
Well
Number
Date
Sampled Benzene1,2-Dibromo-ethane(EDB)1,2-Dichloro-ethaneDiisoporpyletherEthylbenzeneIsopropyl-benzeneMethl-tert-butyletherNaphthalenen-PropylbenzeneStyreneToluene1,2,4-Trimethyl-benzene1,3,5-Trimethyl-benzeneXylenes(total)MW-1 2/25/2014 24,800 1,440 2,860 744 2,890 144 66,200 1,090 438 103 32,900 3,880 1,110 19,280
MW-2 2/25/2014 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
MW-3 2/25/2014 17,500 1,030 607 149 3,570 192 598 1,340 624 176 37,500 4,980 1,400 23,020
MW-4 2/25/2014 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
MW-5 2/25/2014 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
MW-6 2/25/2014 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
RW-1 2/25/2014 30,200 998 1,620 590 3,350 118 7,980 1,040 343 202 47,100 2,900 653 19,160
1 0.02 0.4 70 600 70 20 6 70 70 600 400 400 500
5000 50 400 70,000 84,500 25,000 20,000 6,000 30,000 70,000 260,000 28,500 25,000 85,500
Dissolved concentrations reported in micrograms per liter (ug/L)
NCAC 2L = NCAC 2L Groundwater Quality Standards for Class GA groundwater
GCL = Gross Contaminant Level
Bold concentrations exceed the NCAC 2L groundwater standards for Class GA groundwater
Shaded concentrations exceed the GCL
Only detected analytes are shown
6200B
TABLE 3
MONITOR WELL SAMPLING RESULTS
WILLIAMS GROCERY
INCIDENT # 15063
S&ME PROJECT NO. 4305-14-066
NCAC 2L (ug/L)
GCL (ug/L)
Well ID Date
BenzeneTolueneXylenes(Total)Methyltert-butyletherNaphthaleneDiisopropyletherChloromethane1,2-DichloroethaneIsopropylbenzene1,2,4-Trimethylbenzene1,3.5-TrimethylbenzeneWSW-1 6/14/2010 63 0.95 13.84J 28 2.6 0.69 0.97 1.3 <0.034 <0.038 0.80
9/13/2010 55 0.79 16 24 3.4 0.63 <0.032 1 0.67 1.2 1.1
2/25/2014 <0.50 <0.50 <1.0 <0.50 <2.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50
WSW-2 2/25/2014 <0.50 <0.50 <1.0 <0.5 <2.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50
WSW-3 2/25/2014 <0.50 <0.50 <1.0 <0.50 <2.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50
WSW-4 2/25/2014 <0.50 <0.50 <1.0 <0.50 <2.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50
WSW-5 2/25/2014 <0.50 <0.50 <1.0 <0.50 <2.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50
WSW-6 2/25/2014 <0.50 <0.50 <1.0 <0.50 <2.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50
WSW-7 11/30/2009 <0.040 <0.060 <0.19 <0.11 <0.23 <0.080 NA 0.63 <0.10 <0.14 <0.080
12/6/2011 <0.054 <0.057 <0.17 <0.056 <0.094 <0.042 <0.032 0.52 <0.034 <0.038 <0.038
6/13/2012 <0.054 <0.057 <0.17 <0.056 <0.094 <0.042 <0.032 0.52 <0.034 <0.038 <0.038
2/25/2014 <0.50 <0.50 <1.0 <0.50 <2.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50
2L Standard 1 600 500 20 6 70 3 0.4 70 400 400
Notes:
Concentrations are reported in micrograms per liter (mg/L) or parts per billion (ppb)
Only contaminants detected above the method detection limits in water supply wells during previous monitoring events are shown
(Historical analytical results for the water supply wells shown and wells WSW-8 through WSW-11 and WSW-18 are included in Appendix II.)
Concentrations shown in bold exceed the corresponding North Carolina groundwater quality standard (2L Standard)
NA - not analyzed or data not available
J-Estimated concentration
S&ME Project No. 4305-14-066
Table 4
SUMMARY OF WATER SUPPLY WELL ANALYTICAL RESULTS
Williams Grocery
Incident No. 15063
FIGURES
0GRAPHIC SCALE600300600SCALE: 1" = 600'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwgTOPOGRAPHIC MAPWILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0661MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 150631,500 'SITE/2&$7,21ƒ
1ƒ
:(Google Earth)SOURCE: BROOKS CROSSROADS, NC USGS TOPOGRAPHIC MAP, 7.5-MINUTE SERIES, DATED 2013 (www.usgs.gov)SCALE: 1" = 600'
0GRAPHIC SCALE500250500SCALE: 1" = 500'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwgWATER SUPPLY WELLLOCATION MAPWILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0662MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 150631,
0
0
0

'
50
0

'US Hwy 21Hamptonville RdLEGEND- WATER SUPPLY WELL1,500 'Petty
RdWSW1WSW3(Church)WSW5(Wall)WSW6(Gardner)WSW8WSW17WSW18WSW2(Gail)WSW4(Shore)WSW7(Windsor)WSW9WSW10WSW11WSW16WSW15WSW12WSW14WSW13Reference: "SITE VICINITY MAP, FORMER WILLIAMS GROCERY", by Terraquest Environmental Consultants,Figure 2, dated 1/20/10 and 2010 aerial photograph obtained from www.nconemap.com. Parcel data obtained from Yadkin County GIS website
MW2MW1MW4MW3MW50GRAPHIC SCALE10050100SCALE: 1" = 100'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwgSITE PLANWILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0663MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 15063Reference: "SITE LAYOUT MAP, FORMER WILLIAMS GROCERY", by Terraquest Environmental Consultants,Figure 3, dated 6/28/12, and 2010 aerial photograph obtained from www.nconemap.comFORMERWILLIAMSGROCERYLEGEND- MONITORING WELL LOCATION- WATER SUPPLY WELL LOCATION- FORMER UST LOCATIONNOTE: LOCATIONS SHOWN ARE APPROXIMATEHOUSEMW6WSW1WSW5(WALL)WSW3(CHURCH)RW1HOUSEHOUSEAPTFORMERSHELLSTATION &MOBILE HOMEAPTPROPERTY
BOUND
AR
Y
0GRAPHIC SCALE502550SCALE: 1" = 50'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwgGROUNDWATER OCCURANCE AND FLOW DIRECTION (FEB. 25, 2014)WILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0664MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 15063LEGEND- MONITORING WELL LOCATION- WATER SUPPLY WELL LOCATION- FORMER UST LOCATION- RELATIVE GROUNDWATER ELEVATION MEASURED IN MONITORING WELL IN FEET- PROJECTED GROUNDWATER ELEVATION CONTOUR LINE- ESTIMATED GROUNDWATER FLOW DIRECTIONMW5FORMERWILLIAMSGROCERYHOUSEMW6WSW1WSW3(CHURCH)HOUSEHOUSEAPTAPTMW2MW1MW4MW3RW1Reference: "SITE LAYOUT MAP, FORMER WILLIAMS GROCERY", by Terraquest Environmental Consultants,Figure 3, dated 6/28/12, and 2010 aerial photograph obtained from www.nconemap.comFORMERSHELLSTATION &MOBILE HOMEPROPERTY
BOUNDARYWSW5(WALL)
0GRAPHIC SCALE502550SCALE: 1" = 50'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwgBENZENE CONCENTRATION CONTOUR MAP (FEB. 25, 2014)WILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0665MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 15063LEGEND- MONITORING WELL LOCATION- WATER SUPPLY WELL LOCATION- BENZENE CONCENTRATION IN ug/L- BENZENE ISOCONCENTRATION CONTOUR- 2L STANDARD- GROSS CONTAMINANT LEVEL- MICROGRAMS PER LITERMW2MW1MW4MW3MW5FORMERWILLIAMSGROCERYHOUSEMW6WSW1WSW3(CHURCH)RW1HOUSEHOUSEAPTAPTReference: "SITE LAYOUT MAP, FORMER WILLIAMS GROCERY", by Terraquest Environmental Consultants,Figure 3, dated 6/28/12, and 2010 aerial photograph obtained from www.nconemap.comFORMERSHELLSTATION &MOBILE HOME1 ug/L5,000 ug/Lug/LPROP
ERTY
BOUNDARYWSW5(WALL)
0GRAPHIC SCALE502550SCALE: 1" = 50'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwgETHYLENE DIBROMIDE CONCENTRATION CONTOUR MAP (FEB. 25, 2014)WILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0666MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 15063LEGEND- MONITORING WELL LOCATION- WATER SUPPLY WELL LOCATION- ETHYLENE DIBROMIDE CONCENTRATION IN ug/L- ETHYLENE DIBROMIDEISOCONCENTRATION CONTOUR- 2L STANDARD- GROSS CONTAMINANT LEVEL- MICROGRAMS PER LITERMW2MW1MW4MW3MW5FORMERWILLIAMSGROCERYHOUSEMW6WSW1WSW3(CHURCH)RW1HOUSEHOUSEAPTAPTReference: "SITE LAYOUT MAP, FORMER WILLIAMS GROCERY", by Terraquest Environmental Consultants,Figure 3, dated 6/28/12, and 2010 aerial photograph obtained from www.nconemap.comFORMERSHELLSTATION &MOBILE HOME0.02 ug/L50 ug/Lug/LPROP
ERTY
BOUNDARYWSW5(WALL)
0GRAPHIC SCALE502550SCALE: 1" = 50'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwg1,2-DICHLOROETHANE CONCENTRATION CONTOUR MAP (FEB. 25, 2014)WILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0667MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 15063LEGEND- MONITORING WELL LOCATION- WATER SUPPLY WELL LOCATION- 1,2-DICHLOROETHANE CONCENTRATION IN ug/L- 1,2-DICHLOROETHANE ISOCONCENTRATION CONTOUR- 2L STANDARD- GROSS CONTAMINANT LEVEL- MICROGRAMS PER LITERMW2MW1MW4MW3MW5FORMERWILLIAMSGROCERYHOUSEMW6WSW1WSW3(CHURCH)RW1HOUSEHOUSEAPTAPTReference: "SITE LAYOUT MAP, FORMER WILLIAMS GROCERY", by Terraquest Environmental Consultants,Figure 3, dated 6/28/12, and 2010 aerial photograph obtained from www.nconemap.comFORMERSHELLSTATION &MOBILE HOME0.4 ug/L400 ug/Lug/LPROP
ERTY
BOUNDARYWSW5(WALL)
0GRAPHIC SCALE502550SCALE: 1" = 50'PROJECT NO.DATE:FIGURE NO.SCALE:WWW.SMEINC.COM3718 OLD BATTLEGROUND ROADGREENSBORO, NC 27410PH. 336-288-7180FAX. [phone]DRAWN BY:CHECKED BY:DRAWING PATH:Q:\4305\2014\14-051 - WILLIAMS GROCERY\Williams Grocery Site-rev.dwgMTBE CONCENTRATION CONTOUR MAP (FEB. 25, 2014)WILLIAMS GROCERY2425 U.S. HIGHWAY 214305-14-0668MARCH 2014AS SHOWNRDMALBHAMPTONVILLE, YADKIN COUNTY, NORTH CAROLINAINCIDENT No. 15063LEGEND- MONITORING WELL LOCATION- WATER SUPPLY WELL LOCATION- MTBE CONCENTRATION IN ug/L- MTBE ISOCONCENTRATION CONTOUR- 2L STANDARD- GROSS CONTAMINANT LEVEL- MICROGRAMS PER LITER- METHYL TERT-BUTYL ETHERMW2MW1MW4MW3MW5FORMERWILLIAMSGROCERYHOUSEMW6WSW1WSW3(CHURCH)RW1HOUSEHOUSEAPTAPTReference: "SITE LAYOUT MAP, FORMER WILLIAMS GROCERY", by Terraquest Environmental Consultants,Figure 3, dated 6/28/12, and 2010 aerial photograph obtained from www.nconemap.comFORMERSHELLSTATION &MOBILE HOME20 ug/L20,000 ug/Lug/LPROP
ERTY
BOUNDARYWSW5(WALL)MTBE
APPENDIX I
PHOTOGRAPHS
Incident #15063
Williams Grocery – Hamptonville, Yadkin County, NC
S&ME Project #4305-14-051
Taken by: G. Simcox Date Taken: 2/25/14
1 View of the subject site from the south near water supply well
WSW-1.2 View of the area downgradient of the subject site property from
the west near water supply well WSW-1.
3 View from of the former UST basin area from the south.4 View of subject property to the south from monitor well MW-6.
APPENDIX II
HISTORICAL MONITORING WELL AND WATER SUPPLY WELL
ANALYTICAL DATA TABLES
APPENDIX III
LABORATORY REPORT AND CHAIN-OF-CUSTODY FORMAND GROUNDWATER SAMLING FIELD DATA FORMS
#=CL#
March 05, 2014
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 92191204
92191204
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR - UST Section
1637 Mail Service Center
Raleigh, NC 276991637
WILLIAMS GROCERY TF15063
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on February 26, 2014.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 35
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 35
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92191204001 MW-1 SM 6200B 63 PASI-CCAH
92191204002 MW-2 SM 6200B 63 PASI-CCAH
92191204003 MW-3 SM 6200B 63 PASI-CCAH
92191204004 MW-4 SM 6200B 63 PASI-CCAH
92191204005 MW-5 SM 6200B 63 PASI-CCAH
92191204006 MW-6 SM 6200B 63 PASI-CCAH
92191204007 RW-1 SM 6200B 63 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 35
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92191204001 MW-1
Benzene 24800 ug/L 03/03/14 06:26250SM 6200B
1,2-Dibromoethane (EDB)1440 ug/L 02/28/14 18:5825.0SM 6200B
1,2-Dichloroethane 2860 ug/L 02/28/14 18:5825.0SM 6200B
Diisopropyl ether 744 ug/L 02/28/14 18:5825.0SM 6200B
Ethylbenzene 2890 ug/L 02/28/14 18:5825.0SM 6200B
Isopropylbenzene (Cumene)144 ug/L 02/28/14 18:5825.0SM 6200B
Methyl-tert-butyl ether 66200 ug/L 03/03/14 06:26250SM 6200B
Naphthalene 1090 ug/L 02/28/14 18:58100SM 6200B
n-Propylbenzene 438 ug/L 02/28/14 18:5825.0SM 6200B
Styrene 103 ug/L 02/28/14 18:5825.0SM 6200B
Toluene 32900 ug/L 03/03/14 06:26250SM 6200B
1,2,4-Trimethylbenzene 3880 ug/L 02/28/14 18:5825.0SM 6200B
1,3,5-Trimethylbenzene 1110 ug/L 02/28/14 18:5825.0SM 6200B
m&p-Xylene 13200 ug/L 02/28/14 18:5850.0SM 6200B
o-Xylene 6080 ug/L 02/28/14 18:5825.0SM 6200B
92191204003 MW-3
Benzene 17500 ug/L 02/28/14 18:4150.0SM 6200B
1,2-Dibromoethane (EDB)1030 ug/L 02/28/14 18:4150.0SM 6200B
1,2-Dichloroethane 607 ug/L 02/28/14 18:4150.0SM 6200B
Diisopropyl ether 149 ug/L 02/28/14 18:4150.0SM 6200B
Ethylbenzene 3570 ug/L 02/28/14 18:4150.0SM 6200B
Isopropylbenzene (Cumene)192 ug/L 02/28/14 18:4150.0SM 6200B
Methyl-tert-butyl ether 598 ug/L 02/28/14 18:4150.0SM 6200B
Naphthalene 1340 ug/L 02/28/14 18:41200SM 6200B
n-Propylbenzene 624 ug/L 02/28/14 18:4150.0SM 6200B
Styrene 176 ug/L 02/28/14 18:4150.0SM 6200B
Toluene 37500 ug/L 03/03/14 06:09250SM 6200B
1,2,4-Trimethylbenzene 4980 ug/L 02/28/14 18:4150.0SM 6200B
1,3,5-Trimethylbenzene 1400 ug/L 02/28/14 18:4150.0SM 6200B
m&p-Xylene 15700 ug/L 02/28/14 18:41100SM 6200B
o-Xylene 7320 ug/L 02/28/14 18:4150.0SM 6200B
92191204007 RW-1
Benzene 30200 ug/L 03/03/14 06:42250SM 6200B
1,2-Dibromoethane (EDB)998 ug/L 02/28/14 19:1450.0SM 6200B
1,2-Dichloroethane 1620 ug/L 02/28/14 19:1450.0SM 6200B
Diisopropyl ether 590 ug/L 02/28/14 19:1450.0SM 6200B
Ethylbenzene 3350 ug/L 02/28/14 19:1450.0SM 6200B
Isopropylbenzene (Cumene)118 ug/L 02/28/14 19:1450.0SM 6200B
Methyl-tert-butyl ether 7980 ug/L 02/28/14 19:1450.0SM 6200B
Naphthalene 1040 ug/L 02/28/14 19:14200SM 6200B
n-Propylbenzene 343 ug/L 02/28/14 19:1450.0SM 6200B
Styrene 202 ug/L 02/28/14 19:1450.0SM 6200B
Toluene 47100 ug/L 03/03/14 06:42250SM 6200B
1,2,4-Trimethylbenzene 2900 ug/L 02/28/14 19:1450.0SM 6200B
1,3,5-Trimethylbenzene 653 ug/L 02/28/14 19:1450.0SM 6200B
m&p-Xylene 12900 ug/L 02/28/14 19:14100SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 4 of 35
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92191204007 RW-1
o-Xylene 6260 ug/L 02/28/14 19:1450.0SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 35
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Method:
Client:S&ME_FTF_GSB
SM 6200B
Date:March 05, 2014
Description:6200B MSV
General Information:
7 samples were analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
QC Batch: MSV/25917
L3: Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
• LCS (Lab ID: 1147020)
• 1,2-Dibromo-3-chloropropane
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/25917
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92190759001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MSD (Lab ID: 1149552)
• Hexachloro-1,3-butadiene
• cis-1,3-Dichloropropene
• trans-1,3-Dichloropropene
QC Batch: MSV/25980
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92191377015
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MSD (Lab ID: 1150151)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 35
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Method:
Client:S&ME_FTF_GSB
SM 6200B
Date:March 05, 2014
Description:6200B MSV
QC Batch: MSV/25980
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92191377015
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• cis-1,3-Dichloropropene
• trans-1,3-Dichloropropene
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-1 Lab ID:92191204001 Collected:02/25/14 11:45 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 24800 ug/L 03/03/14 06:26 71-43-2250500
Bromobenzene <25.0 ug/L 02/28/14 18:58 108-86-125.0 50
Bromochloromethane <25.0 ug/L 02/28/14 18:58 74-97-525.0 50
Bromodichloromethane <25.0 ug/L 02/28/14 18:58 75-27-425.0 50
Bromoform <25.0 ug/L 02/28/14 18:58 75-25-225.0 50
Bromomethane <250 ug/L 02/28/14 18:58 74-83-925050
n-Butylbenzene <25.0 ug/L 02/28/14 18:58 104-51-825.0 50
sec-Butylbenzene <25.0 ug/L 02/28/14 18:58 135-98-825.0 50
tert-Butylbenzene <25.0 ug/L 02/28/14 18:58 98-06-625.0 50
Carbon tetrachloride <25.0 ug/L 02/28/14 18:58 56-23-525.0 50
Chlorobenzene <25.0 ug/L 02/28/14 18:58 108-90-725.0 50
Chloroethane <50.0 ug/L 02/28/14 18:58 75-00-350.0 50
Chloroform <25.0 ug/L 02/28/14 18:58 67-66-325.0 50
Chloromethane <50.0 ug/L 02/28/14 18:58 74-87-350.0 50
2-Chlorotoluene <25.0 ug/L 02/28/14 18:58 95-49-825.0 50
4-Chlorotoluene <25.0 ug/L 02/28/14 18:58 106-43-425.0 50
1,2-Dibromo-3-chloropropane <50.0 ug/L 02/28/14 18:58 96-12-850.0 50
Dibromochloromethane <25.0 ug/L 02/28/14 18:58 124-48-125.0 50
1,2-Dibromoethane (EDB)1440 ug/L 02/28/14 18:58 106-93-425.0 50
Dibromomethane <25.0 ug/L 02/28/14 18:58 74-95-325.0 50
1,2-Dichlorobenzene <25.0 ug/L 02/28/14 18:58 95-50-125.0 50
1,3-Dichlorobenzene <25.0 ug/L 02/28/14 18:58 541-73-125.0 50
1,4-Dichlorobenzene <25.0 ug/L 02/28/14 18:58 106-46-725.0 50
Dichlorodifluoromethane <25.0 ug/L 02/28/14 18:58 75-71-825.0 50
1,1-Dichloroethane <25.0 ug/L 02/28/14 18:58 75-34-325.0 50
1,2-Dichloroethane 2860 ug/L 02/28/14 18:58 107-06-225.0 50
1,1-Dichloroethene <25.0 ug/L 02/28/14 18:58 75-35-425.0 50
cis-1,2-Dichloroethene <25.0 ug/L 02/28/14 18:58 156-59-225.0 50
trans-1,2-Dichloroethene <25.0 ug/L 02/28/14 18:58 156-60-525.0 50
1,2-Dichloropropane <25.0 ug/L 02/28/14 18:58 78-87-525.0 50
1,3-Dichloropropane <25.0 ug/L 02/28/14 18:58 142-28-925.0 50
2,2-Dichloropropane <25.0 ug/L 02/28/14 18:58 594-20-725.0 50
1,1-Dichloropropene <25.0 ug/L 02/28/14 18:58 563-58-625.0 50
cis-1,3-Dichloropropene <25.0 ug/L 02/28/14 18:58 10061-01-525.0 50
trans-1,3-Dichloropropene <25.0 ug/L 02/28/14 18:58 10061-02-625.0 50
Diisopropyl ether 744 ug/L 02/28/14 18:58 108-20-325.0 50
Ethylbenzene 2890 ug/L 02/28/14 18:58 100-41-425.0 50
Hexachloro-1,3-butadiene <100 ug/L 02/28/14 18:58 87-68-310050
Isopropylbenzene (Cumene)144 ug/L 02/28/14 18:58 98-82-825.0 50
Methylene Chloride ND ug/L 02/28/14 18:58 75-09-215050
Methyl-tert-butyl ether 66200 ug/L 03/03/14 06:26 1634-04-4250500
Naphthalene 1090 ug/L 02/28/14 18:58 91-20-310050
n-Propylbenzene 438 ug/L 02/28/14 18:58 103-65-125.0 50
Styrene 103 ug/L 02/28/14 18:58 100-42-525.0 50
1,1,1,2-Tetrachloroethane <25.0 ug/L 02/28/14 18:58 630-20-625.0 50
1,1,2,2-Tetrachloroethane <25.0 ug/L 02/28/14 18:58 79-34-525.0 50
Tetrachloroethene <25.0 ug/L 02/28/14 18:58 127-18-425.0 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-1 Lab ID:92191204001 Collected:02/25/14 11:45 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene 32900 ug/L 03/03/14 06:26 108-88-3250500
1,2,3-Trichlorobenzene <100 ug/L 02/28/14 18:58 87-61-610050
1,2,4-Trichlorobenzene <100 ug/L 02/28/14 18:58 120-82-110050
1,1,1-Trichloroethane <25.0 ug/L 02/28/14 18:58 71-55-625.0 50
1,1,2-Trichloroethane <25.0 ug/L 02/28/14 18:58 79-00-525.0 50
Trichloroethene <25.0 ug/L 02/28/14 18:58 79-01-625.0 50
Trichlorofluoromethane <50.0 ug/L 02/28/14 18:58 75-69-450.0 50
1,2,3-Trichloropropane <25.0 ug/L 02/28/14 18:58 96-18-425.0 50
1,2,4-Trimethylbenzene 3880 ug/L 02/28/14 18:58 95-63-625.0 50
1,3,5-Trimethylbenzene 1110 ug/L 02/28/14 18:58 108-67-825.0 50
Vinyl chloride <50.0 ug/L 02/28/14 18:58 75-01-450.0 50
m&p-Xylene 13200 ug/L 02/28/14 18:58 179601-23-150.0 50
o-Xylene 6080 ug/L 02/28/14 18:58 95-47-625.0 50
Surrogates
1,2-Dichloroethane-d4 (S)100 %02/28/14 18:58 17060-07-070-130 50
4-Bromofluorobenzene (S)99 %02/28/14 18:58 460-00-470-130 50
Toluene-d8 (S)101 %02/28/14 18:58 2037-26-570-130 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Huntersville, NC 28078
[phone]
Page 9 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-2 Lab ID:92191204002 Collected:02/25/14 12:45 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 02/28/14 19:47 71-43-20.50 1
Bromobenzene <0.50 ug/L 02/28/14 19:47 108-86-10.50 1
Bromochloromethane <0.50 ug/L 02/28/14 19:47 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 02/28/14 19:47 75-27-40.50 1
Bromoform <0.50 ug/L 02/28/14 19:47 75-25-20.50 1
Bromomethane <5.0 ug/L 02/28/14 19:47 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 02/28/14 19:47 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 02/28/14 19:47 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 02/28/14 19:47 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 02/28/14 19:47 56-23-50.50 1
Chlorobenzene <0.50 ug/L 02/28/14 19:47 108-90-70.50 1
Chloroethane <1.0 ug/L 02/28/14 19:47 75-00-31.0 1
Chloroform <0.50 ug/L 02/28/14 19:47 67-66-30.50 1
Chloromethane <1.0 ug/L 02/28/14 19:47 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 02/28/14 19:47 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 02/28/14 19:47 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 02/28/14 19:47 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 02/28/14 19:47 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 02/28/14 19:47 106-93-40.50 1
Dibromomethane <0.50 ug/L 02/28/14 19:47 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 02/28/14 19:47 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 02/28/14 19:47 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 02/28/14 19:47 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 02/28/14 19:47 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 02/28/14 19:47 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 02/28/14 19:47 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 02/28/14 19:47 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 02/28/14 19:47 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 02/28/14 19:47 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 02/28/14 19:47 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 02/28/14 19:47 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 02/28/14 19:47 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 02/28/14 19:47 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 02/28/14 19:47 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 02/28/14 19:47 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 02/28/14 19:47 108-20-30.50 1
Ethylbenzene <0.50 ug/L 02/28/14 19:47 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 02/28/14 19:47 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 02/28/14 19:47 98-82-80.50 1
Methylene Chloride <2.0 ug/L 02/28/14 19:47 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 02/28/14 19:47 1634-04-40.50 1
Naphthalene <2.0 ug/L 02/28/14 19:47 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 02/28/14 19:47 103-65-10.50 1
Styrene <0.50 ug/L 02/28/14 19:47 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 02/28/14 19:47 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 02/28/14 19:47 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 02/28/14 19:47 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 10 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-2 Lab ID:92191204002 Collected:02/25/14 12:45 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 02/28/14 19:47 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 02/28/14 19:47 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 02/28/14 19:47 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 02/28/14 19:47 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 02/28/14 19:47 79-00-50.50 1
Trichloroethene <0.50 ug/L 02/28/14 19:47 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 02/28/14 19:47 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 02/28/14 19:47 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 02/28/14 19:47 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 02/28/14 19:47 108-67-80.50 1
Vinyl chloride <1.0 ug/L 02/28/14 19:47 75-01-41.0 1
m&p-Xylene <1.0 ug/L 02/28/14 19:47 179601-23-11.0 1
o-Xylene <0.50 ug/L 02/28/14 19:47 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)104 %02/28/14 19:47 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %02/28/14 19:47 460-00-470-130 1
Toluene-d8 (S)101 %02/28/14 19:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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Page 11 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-3 Lab ID:92191204003 Collected:02/25/14 12:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 17500 ug/L 02/28/14 18:41 71-43-250.0 100
Bromobenzene <50.0 ug/L 02/28/14 18:41 108-86-150.0 100
Bromochloromethane <50.0 ug/L 02/28/14 18:41 74-97-550.0 100
Bromodichloromethane <50.0 ug/L 02/28/14 18:41 75-27-450.0 100
Bromoform <50.0 ug/L 02/28/14 18:41 75-25-250.0 100
Bromomethane <500 ug/L 02/28/14 18:41 74-83-9500100
n-Butylbenzene <50.0 ug/L 02/28/14 18:41 104-51-850.0 100
sec-Butylbenzene <50.0 ug/L 02/28/14 18:41 135-98-850.0 100
tert-Butylbenzene <50.0 ug/L 02/28/14 18:41 98-06-650.0 100
Carbon tetrachloride <50.0 ug/L 02/28/14 18:41 56-23-550.0 100
Chlorobenzene <50.0 ug/L 02/28/14 18:41 108-90-750.0 100
Chloroethane <100 ug/L 02/28/14 18:41 75-00-3100100
Chloroform <50.0 ug/L 02/28/14 18:41 67-66-350.0 100
Chloromethane <100 ug/L 02/28/14 18:41 74-87-3100100
2-Chlorotoluene <50.0 ug/L 02/28/14 18:41 95-49-850.0 100
4-Chlorotoluene <50.0 ug/L 02/28/14 18:41 106-43-450.0 100
1,2-Dibromo-3-chloropropane <100 ug/L 02/28/14 18:41 96-12-8100100
Dibromochloromethane <50.0 ug/L 02/28/14 18:41 124-48-150.0 100
1,2-Dibromoethane (EDB)1030 ug/L 02/28/14 18:41 106-93-450.0 100
Dibromomethane <50.0 ug/L 02/28/14 18:41 74-95-350.0 100
1,2-Dichlorobenzene <50.0 ug/L 02/28/14 18:41 95-50-150.0 100
1,3-Dichlorobenzene <50.0 ug/L 02/28/14 18:41 541-73-150.0 100
1,4-Dichlorobenzene <50.0 ug/L 02/28/14 18:41 106-46-750.0 100
Dichlorodifluoromethane <50.0 ug/L 02/28/14 18:41 75-71-850.0 100
1,1-Dichloroethane <50.0 ug/L 02/28/14 18:41 75-34-350.0 100
1,2-Dichloroethane 607 ug/L 02/28/14 18:41 107-06-250.0 100
1,1-Dichloroethene <50.0 ug/L 02/28/14 18:41 75-35-450.0 100
cis-1,2-Dichloroethene <50.0 ug/L 02/28/14 18:41 156-59-250.0 100
trans-1,2-Dichloroethene <50.0 ug/L 02/28/14 18:41 156-60-550.0 100
1,2-Dichloropropane <50.0 ug/L 02/28/14 18:41 78-87-550.0 100
1,3-Dichloropropane <50.0 ug/L 02/28/14 18:41 142-28-950.0 100
2,2-Dichloropropane <50.0 ug/L 02/28/14 18:41 594-20-750.0 100
1,1-Dichloropropene <50.0 ug/L 02/28/14 18:41 563-58-650.0 100
cis-1,3-Dichloropropene <50.0 ug/L 02/28/14 18:41 10061-01-550.0 100
trans-1,3-Dichloropropene <50.0 ug/L 02/28/14 18:41 10061-02-650.0 100
Diisopropyl ether 149 ug/L 02/28/14 18:41 108-20-350.0 100
Ethylbenzene 3570 ug/L 02/28/14 18:41 100-41-450.0 100
Hexachloro-1,3-butadiene <200 ug/L 02/28/14 18:41 87-68-3200100
Isopropylbenzene (Cumene)192 ug/L 02/28/14 18:41 98-82-850.0 100
Methylene Chloride <200 ug/L 02/28/14 18:41 75-09-2200100
Methyl-tert-butyl ether 598 ug/L 02/28/14 18:41 1634-04-450.0 100
Naphthalene 1340 ug/L 02/28/14 18:41 91-20-3200100
n-Propylbenzene 624 ug/L 02/28/14 18:41 103-65-150.0 100
Styrene 176 ug/L 02/28/14 18:41 100-42-550.0 100
1,1,1,2-Tetrachloroethane <50.0 ug/L 02/28/14 18:41 630-20-650.0 100
1,1,2,2-Tetrachloroethane <50.0 ug/L 02/28/14 18:41 79-34-550.0 100
Tetrachloroethene <50.0 ug/L 02/28/14 18:41 127-18-450.0 100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-3 Lab ID:92191204003 Collected:02/25/14 12:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene 37500 ug/L 03/03/14 06:09 108-88-3250500
1,2,3-Trichlorobenzene <200 ug/L 02/28/14 18:41 87-61-6200100
1,2,4-Trichlorobenzene <200 ug/L 02/28/14 18:41 120-82-1200100
1,1,1-Trichloroethane <50.0 ug/L 02/28/14 18:41 71-55-650.0 100
1,1,2-Trichloroethane <50.0 ug/L 02/28/14 18:41 79-00-550.0 100
Trichloroethene <50.0 ug/L 02/28/14 18:41 79-01-650.0 100
Trichlorofluoromethane <100 ug/L 02/28/14 18:41 75-69-4100100
1,2,3-Trichloropropane <50.0 ug/L 02/28/14 18:41 96-18-450.0 100
1,2,4-Trimethylbenzene 4980 ug/L 02/28/14 18:41 95-63-650.0 100
1,3,5-Trimethylbenzene 1400 ug/L 02/28/14 18:41 108-67-850.0 100
Vinyl chloride <100 ug/L 02/28/14 18:41 75-01-4100100
m&p-Xylene 15700 ug/L 02/28/14 18:41 179601-23-1100100
o-Xylene 7320 ug/L 02/28/14 18:41 95-47-650.0 100
Surrogates
1,2-Dichloroethane-d4 (S)102 %02/28/14 18:41 17060-07-070-130 100
4-Bromofluorobenzene (S)100 %02/28/14 18:41 460-00-470-130 100
Toluene-d8 (S)102 %02/28/14 18:41 2037-26-570-130 100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-4 Lab ID:92191204004 Collected:02/25/14 13:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 03/04/14 19:59 71-43-20.50 1
Bromobenzene <0.50 ug/L 03/04/14 19:59 108-86-10.50 1
Bromochloromethane <0.50 ug/L 03/04/14 19:59 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 03/04/14 19:59 75-27-40.50 1
Bromoform <0.50 ug/L 03/04/14 19:59 75-25-20.50 1
Bromomethane <5.0 ug/L 03/04/14 19:59 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 03/04/14 19:59 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 03/04/14 19:59 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 03/04/14 19:59 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 03/04/14 19:59 56-23-50.50 1
Chlorobenzene <0.50 ug/L 03/04/14 19:59 108-90-70.50 1
Chloroethane <1.0 ug/L 03/04/14 19:59 75-00-31.0 1
Chloroform <0.50 ug/L 03/04/14 19:59 67-66-30.50 1
Chloromethane <1.0 ug/L 03/04/14 19:59 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 03/04/14 19:59 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 03/04/14 19:59 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 03/04/14 19:59 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 03/04/14 19:59 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 03/04/14 19:59 106-93-40.50 1
Dibromomethane <0.50 ug/L 03/04/14 19:59 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 03/04/14 19:59 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 03/04/14 19:59 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 03/04/14 19:59 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 03/04/14 19:59 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 03/04/14 19:59 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 03/04/14 19:59 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 03/04/14 19:59 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 03/04/14 19:59 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 03/04/14 19:59 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 03/04/14 19:59 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 03/04/14 19:59 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 03/04/14 19:59 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 03/04/14 19:59 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 03/04/14 19:59 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 03/04/14 19:59 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 03/04/14 19:59 108-20-30.50 1
Ethylbenzene <0.50 ug/L 03/04/14 19:59 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 03/04/14 19:59 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 03/04/14 19:59 98-82-80.50 1
Methylene Chloride <2.0 ug/L 03/04/14 19:59 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 03/04/14 19:59 1634-04-40.50 1
Naphthalene <2.0 ug/L 03/04/14 19:59 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 03/04/14 19:59 103-65-10.50 1
Styrene <0.50 ug/L 03/04/14 19:59 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 03/04/14 19:59 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 03/04/14 19:59 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 03/04/14 19:59 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-4 Lab ID:92191204004 Collected:02/25/14 13:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 03/04/14 19:59 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 03/04/14 19:59 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 03/04/14 19:59 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 03/04/14 19:59 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 03/04/14 19:59 79-00-50.50 1
Trichloroethene <0.50 ug/L 03/04/14 19:59 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 03/04/14 19:59 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 03/04/14 19:59 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 03/04/14 19:59 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 03/04/14 19:59 108-67-80.50 1
Vinyl chloride <1.0 ug/L 03/04/14 19:59 75-01-41.0 1
m&p-Xylene <1.0 ug/L 03/04/14 19:59 179601-23-11.0 1
o-Xylene <0.50 ug/L 03/04/14 19:59 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)103 %03/04/14 19:59 17060-07-070-130 1
4-Bromofluorobenzene (S)95 %03/04/14 19:59 460-00-470-130 1
Toluene-d8 (S)100 %03/04/14 19:59 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-5 Lab ID:92191204005 Collected:02/25/14 13:45 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 02/28/14 18:25 71-43-20.50 1
Bromobenzene <0.50 ug/L 02/28/14 18:25 108-86-10.50 1
Bromochloromethane <0.50 ug/L 02/28/14 18:25 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 02/28/14 18:25 75-27-40.50 1
Bromoform <0.50 ug/L 02/28/14 18:25 75-25-20.50 1
Bromomethane <5.0 ug/L 02/28/14 18:25 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 02/28/14 18:25 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 02/28/14 18:25 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 02/28/14 18:25 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 02/28/14 18:25 56-23-50.50 1
Chlorobenzene <0.50 ug/L 02/28/14 18:25 108-90-70.50 1
Chloroethane <1.0 ug/L 02/28/14 18:25 75-00-31.0 1
Chloroform <0.50 ug/L 02/28/14 18:25 67-66-30.50 1
Chloromethane <1.0 ug/L 02/28/14 18:25 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 02/28/14 18:25 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 02/28/14 18:25 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 02/28/14 18:25 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 02/28/14 18:25 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 02/28/14 18:25 106-93-40.50 1
Dibromomethane <0.50 ug/L 02/28/14 18:25 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 02/28/14 18:25 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 02/28/14 18:25 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 02/28/14 18:25 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 02/28/14 18:25 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 02/28/14 18:25 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 02/28/14 18:25 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 02/28/14 18:25 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 02/28/14 18:25 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 02/28/14 18:25 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 02/28/14 18:25 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 02/28/14 18:25 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 02/28/14 18:25 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 02/28/14 18:25 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 02/28/14 18:25 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 02/28/14 18:25 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 02/28/14 18:25 108-20-30.50 1
Ethylbenzene <0.50 ug/L 02/28/14 18:25 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 02/28/14 18:25 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 02/28/14 18:25 98-82-80.50 1
Methylene Chloride <2.0 ug/L 02/28/14 18:25 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 02/28/14 18:25 1634-04-40.50 1
Naphthalene <2.0 ug/L 02/28/14 18:25 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 02/28/14 18:25 103-65-10.50 1
Styrene <0.50 ug/L 02/28/14 18:25 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 02/28/14 18:25 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 02/28/14 18:25 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 02/28/14 18:25 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-5 Lab ID:92191204005 Collected:02/25/14 13:45 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 02/28/14 18:25 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 02/28/14 18:25 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 02/28/14 18:25 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 02/28/14 18:25 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 02/28/14 18:25 79-00-50.50 1
Trichloroethene <0.50 ug/L 02/28/14 18:25 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 02/28/14 18:25 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 02/28/14 18:25 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 02/28/14 18:25 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 02/28/14 18:25 108-67-80.50 1
Vinyl chloride <1.0 ug/L 02/28/14 18:25 75-01-41.0 1
m&p-Xylene <1.0 ug/L 02/28/14 18:25 179601-23-11.0 1
o-Xylene <0.50 ug/L 02/28/14 18:25 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)104 %02/28/14 18:25 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %02/28/14 18:25 460-00-470-130 1
Toluene-d8 (S)101 %02/28/14 18:25 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-6 Lab ID:92191204006 Collected:02/25/14 14:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 02/28/14 17:51 71-43-20.50 1
Bromobenzene <0.50 ug/L 02/28/14 17:51 108-86-10.50 1
Bromochloromethane <0.50 ug/L 02/28/14 17:51 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 02/28/14 17:51 75-27-40.50 1
Bromoform <0.50 ug/L 02/28/14 17:51 75-25-20.50 1
Bromomethane <5.0 ug/L 02/28/14 17:51 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 02/28/14 17:51 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 02/28/14 17:51 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 02/28/14 17:51 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 02/28/14 17:51 56-23-50.50 1
Chlorobenzene <0.50 ug/L 02/28/14 17:51 108-90-70.50 1
Chloroethane <1.0 ug/L 02/28/14 17:51 75-00-31.0 1
Chloroform <0.50 ug/L 02/28/14 17:51 67-66-30.50 1
Chloromethane <1.0 ug/L 02/28/14 17:51 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 02/28/14 17:51 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 02/28/14 17:51 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 02/28/14 17:51 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 02/28/14 17:51 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 02/28/14 17:51 106-93-40.50 1
Dibromomethane <0.50 ug/L 02/28/14 17:51 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 02/28/14 17:51 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 02/28/14 17:51 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 02/28/14 17:51 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 02/28/14 17:51 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 02/28/14 17:51 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 02/28/14 17:51 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 02/28/14 17:51 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 02/28/14 17:51 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 02/28/14 17:51 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 02/28/14 17:51 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 02/28/14 17:51 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 02/28/14 17:51 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 02/28/14 17:51 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 02/28/14 17:51 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 02/28/14 17:51 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 02/28/14 17:51 108-20-30.50 1
Ethylbenzene <0.50 ug/L 02/28/14 17:51 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 02/28/14 17:51 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 02/28/14 17:51 98-82-80.50 1
Methylene Chloride <2.0 ug/L 02/28/14 17:51 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 02/28/14 17:51 1634-04-40.50 1
Naphthalene <2.0 ug/L 02/28/14 17:51 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 02/28/14 17:51 103-65-10.50 1
Styrene <0.50 ug/L 02/28/14 17:51 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 02/28/14 17:51 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 02/28/14 17:51 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 02/28/14 17:51 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:MW-6 Lab ID:92191204006 Collected:02/25/14 14:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 02/28/14 17:51 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 02/28/14 17:51 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 02/28/14 17:51 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 02/28/14 17:51 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 02/28/14 17:51 79-00-50.50 1
Trichloroethene <0.50 ug/L 02/28/14 17:51 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 02/28/14 17:51 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 02/28/14 17:51 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 02/28/14 17:51 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 02/28/14 17:51 108-67-80.50 1
Vinyl chloride <1.0 ug/L 02/28/14 17:51 75-01-41.0 1
m&p-Xylene <1.0 ug/L 02/28/14 17:51 179601-23-11.0 1
o-Xylene <0.50 ug/L 02/28/14 17:51 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)104 %02/28/14 17:51 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %02/28/14 17:51 460-00-470-130 1
Toluene-d8 (S)101 %02/28/14 17:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:RW-1 Lab ID:92191204007 Collected:02/25/14 11:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene 30200 ug/L 03/03/14 06:42 71-43-2250500
Bromobenzene <50.0 ug/L 02/28/14 19:14 108-86-150.0 100
Bromochloromethane <50.0 ug/L 02/28/14 19:14 74-97-550.0 100
Bromodichloromethane <50.0 ug/L 02/28/14 19:14 75-27-450.0 100
Bromoform <50.0 ug/L 02/28/14 19:14 75-25-250.0 100
Bromomethane <500 ug/L 02/28/14 19:14 74-83-9500100
n-Butylbenzene <50.0 ug/L 02/28/14 19:14 104-51-850.0 100
sec-Butylbenzene <50.0 ug/L 02/28/14 19:14 135-98-850.0 100
tert-Butylbenzene <50.0 ug/L 02/28/14 19:14 98-06-650.0 100
Carbon tetrachloride <50.0 ug/L 02/28/14 19:14 56-23-550.0 100
Chlorobenzene <50.0 ug/L 02/28/14 19:14 108-90-750.0 100
Chloroethane <100 ug/L 02/28/14 19:14 75-00-3100100
Chloroform <50.0 ug/L 02/28/14 19:14 67-66-350.0 100
Chloromethane <100 ug/L 02/28/14 19:14 74-87-3100100
2-Chlorotoluene <50.0 ug/L 02/28/14 19:14 95-49-850.0 100
4-Chlorotoluene <50.0 ug/L 02/28/14 19:14 106-43-450.0 100
1,2-Dibromo-3-chloropropane <100 ug/L 02/28/14 19:14 96-12-8100100
Dibromochloromethane <50.0 ug/L 02/28/14 19:14 124-48-150.0 100
1,2-Dibromoethane (EDB)998 ug/L 02/28/14 19:14 106-93-450.0 100
Dibromomethane <50.0 ug/L 02/28/14 19:14 74-95-350.0 100
1,2-Dichlorobenzene <50.0 ug/L 02/28/14 19:14 95-50-150.0 100
1,3-Dichlorobenzene <50.0 ug/L 02/28/14 19:14 541-73-150.0 100
1,4-Dichlorobenzene <50.0 ug/L 02/28/14 19:14 106-46-750.0 100
Dichlorodifluoromethane <50.0 ug/L 02/28/14 19:14 75-71-850.0 100
1,1-Dichloroethane <50.0 ug/L 02/28/14 19:14 75-34-350.0 100
1,2-Dichloroethane 1620 ug/L 02/28/14 19:14 107-06-250.0 100
1,1-Dichloroethene <50.0 ug/L 02/28/14 19:14 75-35-450.0 100
cis-1,2-Dichloroethene <50.0 ug/L 02/28/14 19:14 156-59-250.0 100
trans-1,2-Dichloroethene <50.0 ug/L 02/28/14 19:14 156-60-550.0 100
1,2-Dichloropropane <50.0 ug/L 02/28/14 19:14 78-87-550.0 100
1,3-Dichloropropane <50.0 ug/L 02/28/14 19:14 142-28-950.0 100
2,2-Dichloropropane <50.0 ug/L 02/28/14 19:14 594-20-750.0 100
1,1-Dichloropropene <50.0 ug/L 02/28/14 19:14 563-58-650.0 100
cis-1,3-Dichloropropene <50.0 ug/L 02/28/14 19:14 10061-01-550.0 100
trans-1,3-Dichloropropene <50.0 ug/L 02/28/14 19:14 10061-02-650.0 100
Diisopropyl ether 590 ug/L 02/28/14 19:14 108-20-350.0 100
Ethylbenzene 3350 ug/L 02/28/14 19:14 100-41-450.0 100
Hexachloro-1,3-butadiene <200 ug/L 02/28/14 19:14 87-68-3200100
Isopropylbenzene (Cumene)118 ug/L 02/28/14 19:14 98-82-850.0 100
Methylene Chloride <200 ug/L 02/28/14 19:14 75-09-2200100
Methyl-tert-butyl ether 7980 ug/L 02/28/14 19:14 1634-04-450.0 100
Naphthalene 1040 ug/L 02/28/14 19:14 91-20-3200100
n-Propylbenzene 343 ug/L 02/28/14 19:14 103-65-150.0 100
Styrene 202 ug/L 02/28/14 19:14 100-42-550.0 100
1,1,1,2-Tetrachloroethane <50.0 ug/L 02/28/14 19:14 630-20-650.0 100
1,1,2,2-Tetrachloroethane <50.0 ug/L 02/28/14 19:14 79-34-550.0 100
Tetrachloroethene <50.0 ug/L 02/28/14 19:14 127-18-450.0 100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Page 20 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Sample:RW-1 Lab ID:92191204007 Collected:02/25/14 11:15 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene 47100 ug/L 03/03/14 06:42 108-88-3250500
1,2,3-Trichlorobenzene <200 ug/L 02/28/14 19:14 87-61-6200100
1,2,4-Trichlorobenzene <200 ug/L 02/28/14 19:14 120-82-1200100
1,1,1-Trichloroethane <50.0 ug/L 02/28/14 19:14 71-55-650.0 100
1,1,2-Trichloroethane <50.0 ug/L 02/28/14 19:14 79-00-550.0 100
Trichloroethene <50.0 ug/L 02/28/14 19:14 79-01-650.0 100
Trichlorofluoromethane <100 ug/L 02/28/14 19:14 75-69-4100100
1,2,3-Trichloropropane <50.0 ug/L 02/28/14 19:14 96-18-450.0 100
1,2,4-Trimethylbenzene 2900 ug/L 02/28/14 19:14 95-63-650.0 100
1,3,5-Trimethylbenzene 653 ug/L 02/28/14 19:14 108-67-850.0 100
Vinyl chloride <100 ug/L 02/28/14 19:14 75-01-4100100
m&p-Xylene 12900 ug/L 02/28/14 19:14 179601-23-1100100
o-Xylene 6260 ug/L 02/28/14 19:14 95-47-650.0 100
Surrogates
1,2-Dichloroethane-d4 (S)101 %02/28/14 19:14 17060-07-070-130 100
4-Bromofluorobenzene (S)99 %02/28/14 19:14 460-00-470-130 100
Toluene-d8 (S)101 %02/28/14 19:14 2037-26-570-130 100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Page 21 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/25917
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92191204001, 92191204002, 92191204003, 92191204005, 92191204006, 92191204007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1147019
Associated Lab Samples:92191204001, 92191204002, 92191204003, 92191204005, 92191204006, 92191204007
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1,1-Trichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1,2,2-Tetrachloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1,2-Trichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1-Dichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1-Dichloroethene ug/L <0.50 0.50 02/28/14 14:18
1,1-Dichloropropene ug/L <0.50 0.50 02/28/14 14:18
1,2,3-Trichlorobenzene ug/L <2.0 2.0 02/28/14 14:18
1,2,3-Trichloropropane ug/L <0.50 0.50 02/28/14 14:18
1,2,4-Trichlorobenzene ug/L <2.0 2.0 02/28/14 14:18
1,2,4-Trimethylbenzene ug/L <0.50 0.50 02/28/14 14:18
1,2-Dibromo-3-chloropropane ug/L <1.0 1.0 02/28/14 14:18
1,2-Dibromoethane (EDB)ug/L <0.50 0.50 02/28/14 14:18
1,2-Dichlorobenzene ug/L <0.50 0.50 02/28/14 14:18
1,2-Dichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,2-Dichloropropane ug/L <0.50 0.50 02/28/14 14:18
1,3,5-Trimethylbenzene ug/L <0.50 0.50 02/28/14 14:18
1,3-Dichlorobenzene ug/L <0.50 0.50 02/28/14 14:18
1,3-Dichloropropane ug/L <0.50 0.50 02/28/14 14:18
1,4-Dichlorobenzene ug/L <0.50 0.50 02/28/14 14:18
2,2-Dichloropropane ug/L <0.50 0.50 02/28/14 14:18
2-Chlorotoluene ug/L <0.50 0.50 02/28/14 14:18
4-Chlorotoluene ug/L <0.50 0.50 02/28/14 14:18
Benzene ug/L <0.50 0.50 02/28/14 14:18
Bromobenzene ug/L <0.50 0.50 02/28/14 14:18
Bromochloromethane ug/L <0.50 0.50 02/28/14 14:18
Bromodichloromethane ug/L <0.50 0.50 02/28/14 14:18
Bromoform ug/L <0.50 0.50 02/28/14 14:18
Bromomethane ug/L <5.0 5.0 02/28/14 14:18
Carbon tetrachloride ug/L <0.50 0.50 02/28/14 14:18
Chlorobenzene ug/L <0.50 0.50 02/28/14 14:18
Chloroethane ug/L <1.0 1.0 02/28/14 14:18
Chloroform ug/L <0.50 0.50 02/28/14 14:18
Chloromethane ug/L <1.0 1.0 02/28/14 14:18
cis-1,2-Dichloroethene ug/L <0.50 0.50 02/28/14 14:18
cis-1,3-Dichloropropene ug/L <0.50 0.50 02/28/14 14:18
Dibromochloromethane ug/L <0.50 0.50 02/28/14 14:18
Dibromomethane ug/L <0.50 0.50 02/28/14 14:18
Dichlorodifluoromethane ug/L <0.50 0.50 02/28/14 14:18
Diisopropyl ether ug/L <0.50 0.50 02/28/14 14:18
Ethylbenzene ug/L <0.50 0.50 02/28/14 14:18
Hexachloro-1,3-butadiene ug/L <2.0 2.0 02/28/14 14:18
Isopropylbenzene (Cumene)ug/L <0.50 0.50 02/28/14 14:18
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Page 22 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1147019
Associated Lab Samples:92191204001, 92191204002, 92191204003, 92191204005, 92191204006, 92191204007
Matrix:Water
Analyzed
m&p-Xylene ug/L <1.0 1.0 02/28/14 14:18
Methyl-tert-butyl ether ug/L <0.50 0.50 02/28/14 14:18
Methylene Chloride ug/L <2.0 2.0 02/28/14 14:18
n-Butylbenzene ug/L <0.50 0.50 02/28/14 14:18
n-Propylbenzene ug/L <0.50 0.50 02/28/14 14:18
Naphthalene ug/L <2.0 2.0 02/28/14 14:18
o-Xylene ug/L <0.50 0.50 02/28/14 14:18
sec-Butylbenzene ug/L <0.50 0.50 02/28/14 14:18
Styrene ug/L <0.50 0.50 02/28/14 14:18
tert-Butylbenzene ug/L <0.50 0.50 02/28/14 14:18
Tetrachloroethene ug/L <0.50 0.50 02/28/14 14:18
Toluene ug/L <0.50 0.50 02/28/14 14:18
trans-1,2-Dichloroethene ug/L <0.50 0.50 02/28/14 14:18
trans-1,3-Dichloropropene ug/L <0.50 0.50 02/28/14 14:18
Trichloroethene ug/L <0.50 0.50 02/28/14 14:18
Trichlorofluoromethane ug/L <1.0 1.0 02/28/14 14:18
Vinyl chloride ug/L <1.0 1.0 02/28/14 14:18
1,2-Dichloroethane-d4 (S)%103 70-130 02/28/14 14:18
4-Bromofluorobenzene (S)%98 70-130 02/28/14 14:18
Toluene-d8 (S)%101 70-130 02/28/14 14:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1147020LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.450 103 60-140
1,1,1-Trichloroethane ug/L 58.150 116 60-140
1,1,2,2-Tetrachloroethane ug/L 56.550 113 60-140
1,1,2-Trichloroethane ug/L 57.250 114 60-140
1,1-Dichloroethane ug/L 54.450 109 60-140
1,1-Dichloroethene ug/L 50.450 101 60-140
1,1-Dichloropropene ug/L 56.750 113 60-140
1,2,3-Trichlorobenzene ug/L 58.450 117 60-140
1,2,3-Trichloropropane ug/L 55.750 111 60-140
1,2,4-Trichlorobenzene ug/L 57.150 114 60-140
1,2,4-Trimethylbenzene ug/L 56.750 113 60-140
1,2-Dibromo-3-chloropropane ug/L 78.3 CU,L35015760-140
1,2-Dibromoethane (EDB)ug/L 58.750 117 60-140
1,2-Dichlorobenzene ug/L 54.750 109 60-140
1,2-Dichloroethane ug/L 52.350 105 60-140
1,2-Dichloropropane ug/L 55.450 111 60-140
1,3,5-Trimethylbenzene ug/L 56.650 113 60-140
1,3-Dichlorobenzene ug/L 53.750 107 60-140
1,3-Dichloropropane ug/L 56.050 112 60-140
1,4-Dichlorobenzene ug/L 54.150 108 60-140
2,2-Dichloropropane ug/L 59.650 119 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Page 23 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1147020LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorotoluene ug/L 52.350 105 60-140
4-Chlorotoluene ug/L 55.650 111 60-140
Benzene ug/L 56.050 112 60-140
Bromobenzene ug/L 56.150 112 60-140
Bromochloromethane ug/L 53.150 106 60-140
Bromodichloromethane ug/L 50.950 102 60-140
Bromoform ug/L 49.050 98 60-140
Bromomethane ug/L 30.150 60 60-140
Carbon tetrachloride ug/L 49.450 99 60-140
Chlorobenzene ug/L 55.050 110 60-140
Chloroethane ug/L 37.050 74 60-140
Chloroform ug/L 54.550 109 60-140
Chloromethane ug/L 46.650 93 60-140
cis-1,2-Dichloroethene ug/L 53.150 106 60-140
cis-1,3-Dichloropropene ug/L 51.350 103 60-140
Dibromochloromethane ug/L 51.650 103 60-140
Dibromomethane ug/L 55.850 112 60-140
Dichlorodifluoromethane ug/L 44.450 89 60-140
Diisopropyl ether ug/L 55.950 112 60-140
Ethylbenzene ug/L 55.450 111 60-140
Hexachloro-1,3-butadiene ug/L 58.050 116 60-140
Isopropylbenzene (Cumene)ug/L 58.750 117 60-140
m&p-Xylene ug/L 115100 115 60-140
Methyl-tert-butyl ether ug/L 56.550 113 60-140
Methylene Chloride ug/L 55.050 110 60-140
n-Butylbenzene ug/L 57.650 115 60-140
n-Propylbenzene ug/L 57.450 115 60-140
Naphthalene ug/L 59.250 118 60-140
o-Xylene ug/L 57.150 114 60-140
sec-Butylbenzene ug/L 57.250 114 60-140
Styrene ug/L 52.850 106 60-140
tert-Butylbenzene ug/L 57.650 115 60-140
Tetrachloroethene ug/L 55.650 111 60-140
Toluene ug/L 52.950 106 60-140
trans-1,2-Dichloroethene ug/L 52.450 105 60-140
trans-1,3-Dichloropropene ug/L 51.450 103 60-140
Trichloroethene ug/L 55.050 110 60-140
Trichlorofluoromethane ug/L 45.150 90 60-140
Vinyl chloride ug/L 50.150 100 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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[phone]
Page 24 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1149551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92190759001
1149552
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 65 60-14064 120ND13.0 12.8
1,1,1-Trichloroethane ug/L 20 71 60-14069 220ND14.2 13.9
1,1,2,2-Tetrachloroethane ug/L 20 74 60-14072 320ND14.8 14.4
1,1,2-Trichloroethane ug/L 20 70 60-14069 220ND14.1 13.7
1,1-Dichloroethane ug/L 20 68 60-14067 220ND13.7 13.4
1,1-Dichloroethene ug/L 20 75 60-14072 320ND14.9 14.5
1,1-Dichloropropene ug/L 20 73 60-14072 220ND14.6 14.4
1,2,3-Trichlorobenzene ug/L 20 70 60-14065 720ND14.0 13.1
1,2,3-Trichloropropane ug/L 20 72 60-14070 320ND14.4 14.0
1,2,4-Trichlorobenzene ug/L 20 67 60-14063 720ND13.4 12.5
1,2,4-Trimethylbenzene ug/L 20 69 60-14065 620ND14.0 13.3
1,2-Dibromo-3-chloropropane ug/L 20 95 60-14087 820ND18.9 17.5
1,2-Dibromoethane (EDB)ug/L 20 75 60-14074 220ND15.0 14.7
1,2-Dichlorobenzene ug/L 20 71 60-14067 620ND14.2 13.4
1,2-Dichloroethane ug/L 20 68 60-14065 320ND13.5 13.1
1,2-Dichloropropane ug/L 20 68 60-14066 320ND13.5 13.1
1,3,5-Trimethylbenzene ug/L 20 68 60-14066 320ND14.0 13.5
1,3-Dichlorobenzene ug/L 20 69 60-14064 720ND13.8 12.8
1,3-Dichloropropane ug/L 20 75 60-14073 220ND14.9 14.6
1,4-Dichlorobenzene ug/L 20 70 60-14066 520ND14.0 13.3
2,2-Dichloropropane ug/L 20 62 60-14061 220ND12.4 12.2
2-Chlorotoluene ug/L 20 71 60-14066 720ND14.1 13.1
4-Chlorotoluene ug/L 20 73 60-14068 620ND14.6 13.7
Benzene ug/L 20 68 60-14067 220ND13.7 13.4
Bromobenzene ug/L 20 74 60-14070 620ND14.8 13.9
Bromochloromethane ug/L 20 73 60-14069 620ND14.5 13.7
Bromodichloromethane ug/L 20 68 60-14064 520ND13.5 12.8
Bromoform ug/L 20 65 60-14063 320ND12.9 12.5
Bromomethane ug/L 20 87 60-14078 1020ND17.3 15.7
Carbon tetrachloride ug/L 20 66 60-14064 220ND13.1 12.9
Chlorobenzene ug/L 20 71 60-14069 320ND14.1 13.7
Chloroethane ug/L 20 71 60-14068 520ND14.2 13.5
Chloroform ug/L 20 68 60-14065 420ND13.7 13.2
Chloromethane ug/L 20 74 60-14071 320ND14.7 14.2
cis-1,2-Dichloroethene ug/L 20 69 60-14065 620ND13.8 13.0
cis-1,3-Dichloropropene ug/L M0206060-14057 420ND12.0 11.5
Dibromochloromethane ug/L 20 65 60-14064 220ND13.1 12.9
Dibromomethane ug/L 20 66 60-14063 420ND13.1 12.7
Dichlorodifluoromethane ug/L 20 77 60-14073 520ND15.4 14.6
Diisopropyl ether ug/L 20 71 60-14069 420ND14.3 13.7
Ethylbenzene ug/L 20 69 60-14067 320ND13.8 13.5
Hexachloro-1,3-butadiene ug/L M0206060-14059 220ND12.1 11.8
Isopropylbenzene (Cumene)ug/L 20 70 60-14069 220ND14.0 13.7
m&p-Xylene ug/L 40 69 60-14067 340ND28.0 27.3
Methyl-tert-butyl ether ug/L 20 68 60-14066 420ND13.8 13.3
Methylene Chloride ug/L 20 72 60-14068 520ND14.3 13.7
n-Butylbenzene ug/L 20 65 60-14064 220ND13.0 12.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Page 25 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1149551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92190759001
1149552
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 73 60-14070 420ND14.5 14.0
Naphthalene ug/L 20 72 60-14067 620ND14.6 13.7
o-Xylene ug/L 20 69 60-14067 220ND14.0 13.7
sec-Butylbenzene ug/L 20 68 60-14066 320ND13.5 13.1
Styrene ug/L 20 73 60-14070 520ND14.6 13.9
tert-Butylbenzene ug/L 20 70 60-14067 420ND14.0 13.4
Tetrachloroethene ug/L 20 69 60-14069 020ND13.8 13.8
Toluene ug/L 20 66 60-14064 220ND13.2 12.9
trans-1,2-Dichloroethene ug/L 20 78 60-14081 420ND15.5 16.1
trans-1,3-Dichloropropene ug/L M0206060-14059 220ND12.0 11.7
Trichloroethene ug/L 20 64 60-14063 120ND12.8 12.6
Trichlorofluoromethane ug/L 20 74 60-14071 420ND14.7 14.2
Vinyl chloride ug/L 20 79 60-14077 420ND15.9 15.3
1,2-Dichloroethane-d4 (S)%104 70-130101
4-Bromofluorobenzene (S)%97 70-13097
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Page 26 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/25980
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92191204004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1150146
Associated Lab Samples:92191204004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.50 0.50 03/04/14 19:26
1,1,1-Trichloroethane ug/L <0.50 0.50 03/04/14 19:26
1,1,2,2-Tetrachloroethane ug/L <0.50 0.50 03/04/14 19:26
1,1,2-Trichloroethane ug/L <0.50 0.50 03/04/14 19:26
1,1-Dichloroethane ug/L <0.50 0.50 03/04/14 19:26
1,1-Dichloroethene ug/L <0.50 0.50 03/04/14 19:26
1,1-Dichloropropene ug/L <0.50 0.50 03/04/14 19:26
1,2,3-Trichlorobenzene ug/L <2.0 2.0 03/04/14 19:26
1,2,3-Trichloropropane ug/L <0.50 0.50 03/04/14 19:26
1,2,4-Trichlorobenzene ug/L <2.0 2.0 03/04/14 19:26
1,2,4-Trimethylbenzene ug/L <0.50 0.50 03/04/14 19:26
1,2-Dibromo-3-chloropropane ug/L <1.0 1.0 03/04/14 19:26
1,2-Dibromoethane (EDB)ug/L <0.50 0.50 03/04/14 19:26
1,2-Dichlorobenzene ug/L <0.50 0.50 03/04/14 19:26
1,2-Dichloroethane ug/L <0.50 0.50 03/04/14 19:26
1,2-Dichloropropane ug/L <0.50 0.50 03/04/14 19:26
1,3,5-Trimethylbenzene ug/L <0.50 0.50 03/04/14 19:26
1,3-Dichlorobenzene ug/L <0.50 0.50 03/04/14 19:26
1,3-Dichloropropane ug/L <0.50 0.50 03/04/14 19:26
1,4-Dichlorobenzene ug/L <0.50 0.50 03/04/14 19:26
2,2-Dichloropropane ug/L <0.50 0.50 03/04/14 19:26
2-Chlorotoluene ug/L <0.50 0.50 03/04/14 19:26
4-Chlorotoluene ug/L <0.50 0.50 03/04/14 19:26
Benzene ug/L <0.50 0.50 03/04/14 19:26
Bromobenzene ug/L <0.50 0.50 03/04/14 19:26
Bromochloromethane ug/L <0.50 0.50 03/04/14 19:26
Bromodichloromethane ug/L <0.50 0.50 03/04/14 19:26
Bromoform ug/L <0.50 0.50 03/04/14 19:26
Bromomethane ug/L <5.0 5.0 03/04/14 19:26
Carbon tetrachloride ug/L <0.50 0.50 03/04/14 19:26
Chlorobenzene ug/L <0.50 0.50 03/04/14 19:26
Chloroethane ug/L <1.0 1.0 03/04/14 19:26
Chloroform ug/L <0.50 0.50 03/04/14 19:26
Chloromethane ug/L <1.0 1.0 03/04/14 19:26
cis-1,2-Dichloroethene ug/L <0.50 0.50 03/04/14 19:26
cis-1,3-Dichloropropene ug/L <0.50 0.50 03/04/14 19:26
Dibromochloromethane ug/L <0.50 0.50 03/04/14 19:26
Dibromomethane ug/L <0.50 0.50 03/04/14 19:26
Dichlorodifluoromethane ug/L <0.50 0.50 03/04/14 19:26
Diisopropyl ether ug/L <0.50 0.50 03/04/14 19:26
Ethylbenzene ug/L <0.50 0.50 03/04/14 19:26
Hexachloro-1,3-butadiene ug/L <2.0 2.0 03/04/14 19:26
Isopropylbenzene (Cumene)ug/L <0.50 0.50 03/04/14 19:26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1150146
Associated Lab Samples:92191204004
Matrix:Water
Analyzed
m&p-Xylene ug/L <1.0 1.0 03/04/14 19:26
Methyl-tert-butyl ether ug/L <0.50 0.50 03/04/14 19:26
Methylene Chloride ug/L <2.0 2.0 03/04/14 19:26
n-Butylbenzene ug/L <0.50 0.50 03/04/14 19:26
n-Propylbenzene ug/L <0.50 0.50 03/04/14 19:26
Naphthalene ug/L <2.0 2.0 03/04/14 19:26
o-Xylene ug/L <0.50 0.50 03/04/14 19:26
sec-Butylbenzene ug/L <0.50 0.50 03/04/14 19:26
Styrene ug/L <0.50 0.50 03/04/14 19:26
tert-Butylbenzene ug/L <0.50 0.50 03/04/14 19:26
Tetrachloroethene ug/L <0.50 0.50 03/04/14 19:26
Toluene ug/L <0.50 0.50 03/04/14 19:26
trans-1,2-Dichloroethene ug/L <0.50 0.50 03/04/14 19:26
trans-1,3-Dichloropropene ug/L <0.50 0.50 03/04/14 19:26
Trichloroethene ug/L <0.50 0.50 03/04/14 19:26
Trichlorofluoromethane ug/L <1.0 1.0 03/04/14 19:26
Vinyl chloride ug/L <1.0 1.0 03/04/14 19:26
1,2-Dichloroethane-d4 (S)%103 70-130 03/04/14 19:26
4-Bromofluorobenzene (S)%95 70-130 03/04/14 19:26
Toluene-d8 (S)%100 70-130 03/04/14 19:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1150147LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 45.350 91 60-140
1,1,1-Trichloroethane ug/L 43.950 88 60-140
1,1,2,2-Tetrachloroethane ug/L 49.750 99 60-140
1,1,2-Trichloroethane ug/L 47.050 94 60-140
1,1-Dichloroethane ug/L 42.150 84 60-140
1,1-Dichloroethene ug/L 40.850 82 60-140
1,1-Dichloropropene ug/L 42.250 84 60-140
1,2,3-Trichlorobenzene ug/L 45.050 90 60-140
1,2,3-Trichloropropane ug/L 48.350 97 60-140
1,2,4-Trichlorobenzene ug/L 44.350 89 60-140
1,2,4-Trimethylbenzene ug/L 45.550 91 60-140
1,2-Dibromo-3-chloropropane ug/L 70.1 CU5014060-140
1,2-Dibromoethane (EDB)ug/L 51.250 102 60-140
1,2-Dichlorobenzene ug/L 45.850 92 60-140
1,2-Dichloroethane ug/L 42.150 84 60-140
1,2-Dichloropropane ug/L 44.450 89 60-140
1,3,5-Trimethylbenzene ug/L 45.250 90 60-140
1,3-Dichlorobenzene ug/L 44.150 88 60-140
1,3-Dichloropropane ug/L 49.250 98 60-140
1,4-Dichlorobenzene ug/L 45.850 92 60-140
2,2-Dichloropropane ug/L 49.050 98 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1150147LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorotoluene ug/L 43.050 86 60-140
4-Chlorotoluene ug/L 45.350 91 60-140
Benzene ug/L 43.950 88 60-140
Bromobenzene ug/L 47.950 96 60-140
Bromochloromethane ug/L 45.550 91 60-140
Bromodichloromethane ug/L 49.850 100 60-140
Bromoform ug/L 47.850 96 60-140
Bromomethane ug/L 54.150 108 60-140
Carbon tetrachloride ug/L 40.850 82 60-140
Chlorobenzene ug/L 45.250 90 60-140
Chloroethane ug/L 37.750 75 60-140
Chloroform ug/L 41.250 82 60-140
Chloromethane ug/L 40.750 81 60-140
cis-1,2-Dichloroethene ug/L 41.650 83 60-140
cis-1,3-Dichloropropene ug/L 43.050 86 60-140
Dibromochloromethane ug/L 47.750 95 60-140
Dibromomethane ug/L 44.850 90 60-140
Dichlorodifluoromethane ug/L 40.450 81 60-140
Diisopropyl ether ug/L 45.550 91 60-140
Ethylbenzene ug/L 43.450 87 60-140
Hexachloro-1,3-butadiene ug/L 39.750 79 60-140
Isopropylbenzene (Cumene)ug/L 44.750 89 60-140
m&p-Xylene ug/L 91.0100 91 60-140
Methyl-tert-butyl ether ug/L 44.950 90 60-140
Methylene Chloride ug/L 40.050 80 60-140
n-Butylbenzene ug/L 42.050 84 60-140
n-Propylbenzene ug/L 44.950 90 60-140
Naphthalene ug/L 47.750 95 60-140
o-Xylene ug/L 45.950 92 60-140
sec-Butylbenzene ug/L 42.350 85 60-140
Styrene ug/L 49.950 100 60-140
tert-Butylbenzene ug/L 43.150 86 60-140
Tetrachloroethene ug/L 42.550 85 60-140
Toluene ug/L 41.650 83 60-140
trans-1,2-Dichloroethene ug/L 40.650 81 60-140
trans-1,3-Dichloropropene ug/L 43.650 87 60-140
Trichloroethene ug/L 41.150 82 60-140
Trichlorofluoromethane ug/L 39.950 80 60-140
Vinyl chloride ug/L 42.750 85 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1150150MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92191377015
1150151
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 75 60-14064 1620ND15.1 12.8
1,1,1-Trichloroethane ug/L 20 82 60-14070 1620ND16.5 14.1
1,1,2,2-Tetrachloroethane ug/L 20 87 60-14073 1820ND17.3 14.5
1,1,2-Trichloroethane ug/L 20 84 60-14069 1920ND16.7 13.8
1,1-Dichloroethane ug/L 20 80 60-14068 1720ND16.0 13.6
1,1-Dichloroethene ug/L 20 86 60-14073 1620ND17.2 14.6
1,1-Dichloropropene ug/L 20 85 60-14072 1720ND17.0 14.3
1,2,3-Trichlorobenzene ug/L 20 77 60-14067 1420ND15.5 13.4
1,2,3-Trichloropropane ug/L 20 84 60-14070 1920ND16.9 13.9
1,2,4-Trichlorobenzene ug/L 20 75 60-14064 1520ND14.9 12.8
1,2,4-Trimethylbenzene ug/L 20 82 60-14070 1620ND16.4 14.0
1,2-Dibromo-3-chloropropane ug/L 20 104 60-14085 2020ND20.8 17.1
1,2-Dibromoethane (EDB)ug/L 20 87 60-14075 1620ND17.4 14.9
1,2-Dichlorobenzene ug/L 20 82 60-14069 1720ND16.5 13.9
1,2-Dichloroethane ug/L 20 78 60-14067 1620ND15.7 13.4
1,2-Dichloropropane ug/L 20 80 60-14068 1720ND16.1 13.6
1,3,5-Trimethylbenzene ug/L 20 82 60-14069 1720ND16.4 13.8
1,3-Dichlorobenzene ug/L 20 80 60-14067 1820ND16.0 13.4
1,3-Dichloropropane ug/L 20 89 60-14074 1820ND17.8 14.8
1,4-Dichlorobenzene ug/L 20 81 60-14069 1620ND16.2 13.7
2,2-Dichloropropane ug/L 20 70 60-14061 1320ND13.9 12.3
2-Chlorotoluene ug/L 20 79 60-14067 1720ND15.9 13.4
4-Chlorotoluene ug/L 20 84 60-14071 1720ND16.7 14.2
Benzene ug/L 20 81 60-14070 1520ND16.2 14.0
Bromobenzene ug/L 20 85 60-14072 1620ND16.9 14.3
Bromochloromethane ug/L 20 84 60-14070 1720ND16.7 14.1
Bromodichloromethane ug/L 20 78 60-14066 1720ND15.7 13.2
Bromoform ug/L 20 73 60-14063 1520ND14.7 12.7
Bromomethane ug/L 20 98 60-14090 820ND19.6 18.1
Carbon tetrachloride ug/L 20 73 60-14065 1120ND14.6 13.0
Chlorobenzene ug/L 20 84 60-14070 1820ND16.8 13.9
Chloroethane ug/L 20 84 60-14071 1720ND16.9 14.3
Chloroform ug/L 20 78 60-14068 1420ND15.5 13.5
Chloromethane ug/L 20 84 60-14073 1320ND16.7 14.7
cis-1,2-Dichloroethene ug/L 20 79 60-14067 1620ND15.9 13.5
cis-1,3-Dichloropropene ug/L M0206860-14059 1420ND13.5 11.8
Dibromochloromethane ug/L 20 76 60-14064 1720ND15.2 12.8
Dibromomethane ug/L 20 76 60-14066 1520ND15.2 13.1
Dichlorodifluoromethane ug/L 20 84 60-14074 1220ND16.7 14.8
Diisopropyl ether ug/L 20 82 60-14069 1620ND16.3 13.9
Ethylbenzene ug/L 20 82 60-14068 1820ND16.4 13.7
Hexachloro-1,3-butadiene ug/L 20 69 60-14060 1420ND13.7 12.0
Isopropylbenzene (Cumene)ug/L 20 84 60-14070 1820ND16.8 14.0
m&p-Xylene ug/L 40 84 60-14070 1840ND33.4 28.0
Methyl-tert-butyl ether ug/L 20 78 60-14065 1820ND15.6 13.1
Methylene Chloride ug/L 20 83 60-14068 1920ND16.9 14.0
n-Butylbenzene ug/L 20 76 60-14066 1420ND15.2 13.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1150150MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92191377015
1150151
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 86 60-14072 1820ND17.2 14.4
Naphthalene ug/L 20 83 60-14071 1620ND16.6 14.1
o-Xylene ug/L 20 83 60-14069 1920ND16.7 13.8
sec-Butylbenzene ug/L 20 81 60-14068 1820ND16.3 13.6
Styrene ug/L 20 86 60-14071 1820ND17.1 14.2
tert-Butylbenzene ug/L 20 83 60-14069 1820ND16.6 13.8
Tetrachloroethene ug/L 20 83 60-14070 1720ND16.7 14.1
Toluene ug/L 20 78 60-14066 1720ND15.5 13.1
trans-1,2-Dichloroethene ug/L 20 84 60-14071 1620ND16.7 14.3
trans-1,3-Dichloropropene ug/L M0206860-14059 1320ND13.5 11.8
Trichloroethene ug/L 20 76 60-14065 1620ND15.3 13.0
Trichlorofluoromethane ug/L 20 85 60-14072 1720ND17.1 14.3
Vinyl chloride ug/L 20 91 60-14077 1620ND18.1 15.4
1,2-Dichloroethane-d4 (S)%102 70-130102
4-Bromofluorobenzene (S)%97 70-13097
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 35
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.CU
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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Huntersville, NC 28078
[phone]
Page 32 of 35
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92191204
WILLIAMS GROCERY TF15063
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92191204001 MSV/25917MW-1 SM 6200B
92191204002 MSV/25917MW-2 SM 6200B
92191204003 MSV/25917MW-3 SM 6200B
92191204004 MSV/25980MW-4 SM 6200B
92191204005 MSV/25917MW-5 SM 6200B
92191204006 MSV/25917MW-6 SM 6200B
92191204007 MSV/25917RW-1 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:20 PM
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[phone]
Page 33 of 35
Page 34 of 35
Page 35 of 35
Location: Purge Date:
Project No.: Purge Time:
Source Well: Sample Date:
Sample Time:
Locked?: Yes:x No: Weather:
Sampled By: Air Temp:
feet
feet
feet
Purge Method
Sample Method Start Stop
Purge Rate ml/min
Control Settings On: sec. Start Stop
Off: sec.
Pressure: psi
2" well:
height:9.92 x .163 = 1.617
gallons X liters
Yes No x
*Stabilization Parameters
Time date Temp pHConductivity *ORP *D.O. *Turbidity DTW
Final Readings 1145 2/25/2014 17.40 5.10 140.80 2.00
*C u S
GROUNDWATER SAMPLING FIELD DATA
Williams Gcocery Tuesday, February 25, 2014
4305-14-051
MW-1 Tuesday, February 25, 2014
1145
Cloudy
Gary Simcox 45 *F
Water Level & Well Data
Depth to water from measuring point: 22.28
Depth to well bottom from measuring point: 32.20
Height of water column: 9.92
Measuring point: Top of Casing
Well Purging & Sample Collection
Bailer Purge Time
Bailer
Sample Collection Time
Was well purged dry
Field Analyses
Volume of water in well
Volume of water removed 4.9
Location: Purge Date:
Project No.: Purge Time:
Source Well: Sample Date:
Sample Time:
Locked?: Yes:x No: Weather:
Sampled By: Air Temp:
feet
feet
feet
Purge Method
Sample Method Start Stop
Purge Rate ml/min
Control Settings On: sec. Start Stop
Off: sec.
Pressure: psi
2" well:
height:10.73 x .163 = 1.749
gallons X liters
Yes No x
*Stabilization Parameters
Time date Temp pHConductivity *ORP *D.O. *Turbidity DTW
Final Readings 1245 2/25/2014 16.40 5.15 60.80 1.00
*C u S
Was well purged dry
Field Analyses
Volume of water in well
Volume of water removed 5.2
Well Purging & Sample Collection
Bailer Purge Time
Bailer
Sample Collection Time
Depth to well bottom from measuring point: 33.20
Height of water column: 10.73
Measuring point: Top of Casing
1245
Cloudy
Gary Simcox 45 *F
Water Level & Well Data
Depth to water from measuring point: 22.47
GROUNDWATER SAMPLING FIELD DATA
Williams Gcocery Tuesday, February 25, 2014
4305-14-051
MW-2 Tuesday, February 25, 2014
Location: Purge Date:
Project No.: Purge Time:
Source Well: Sample Date:
Sample Time:
Locked?: Yes:x No: Weather:
Sampled By: Air Temp:
feet
feet
feet
Purge Method
Sample Method Start Stop
Purge Rate ml/min
Control Settings On: sec. Start Stop
Off: sec.
Pressure: psi
2" well:
height:9.62 x .163 = 1.5681
gallons X liters
Yes No x
*Stabilization Parameters
Time date Temp pHConductivity *ORP *D.O. *Turbidity DTW
Final Readings 1215 2/25/2014 18.50 4.89 405.00 3.00
*C u S
Was well purged dry
Field Analyses
Volume of water in well
Volume of water removed 4.7
Well Purging & Sample Collection
Bailer Purge Time
Bailer
Sample Collection Time
Depth to well bottom from measuring point: 32.40
Height of water column: 9.62
Measuring point: Top of Casing
1215
Cloudy
Gary Simcox 45 *F
Water Level & Well Data
Depth to water from measuring point: 22.78
GROUNDWATER SAMPLING FIELD DATA
Williams Gcocery Tuesday, February 25, 2014
4305-14-051
MW-3 Tuesday, February 25, 2014
Location: Purge Date:
Project No.: Purge Time:
Source Well: Sample Date:
Sample Time:
Locked?: Yes:x No: Weather:
Sampled By: Air Temp:
feet
feet
feet
Purge Method
Sample Method Start Stop
Purge Rate ml/min
Control Settings On: sec. Start Stop
Off: sec.
Pressure: psi
2" well:
height:9.63 x .163 = 1.5697
gallons X liters
Yes No x
*Stabilization Parameters
Time date Temp pHConductivity *ORP *D.O. *Turbidity DTW
Final Readings 1315 2/25/2014 16.10 4.96 265.00 3.00
*C u S
Was well purged dry
Field Analyses
Volume of water in well
Volume of water removed 4.7
Well Purging & Sample Collection
Bailer Purge Time
Bailer
Sample Collection Time
Depth to well bottom from measuring point: 32.40
Height of water column: 9.63
Measuring point: Top of Casing
1315
Cloudy
Gary Simcox 45 *F
Water Level & Well Data
Depth to water from measuring point: 22.77
GROUNDWATER SAMPLING FIELD DATA
Williams Gcocery Tuesday, February 25, 2014
4305-14-051
MW-4 Tuesday, February 25, 2014
Location: Purge Date:
Project No.: Purge Time:
Source Well: Sample Date:
Sample Time:
Locked?: Yes:x No: Weather:
Sampled By: Air Temp:
feet
feet
feet
Purge Method
Sample Method Start Stop
Purge Rate ml/min
Control Settings On: sec. Start Stop
Off: sec.
Pressure: psi
2" well:
height:11.06 x .163 = 1.8028
gallons X liters
Yes No x
*Stabilization Parameters
Time date Temp pHConductivity *ORP *D.O. *Turbidity DTW
Final Readings 1345 2/25/2014 16.20 5.32 47.10 2.00
*C u S
Was well purged dry
Field Analyses
Volume of water in well
Volume of water removed 5.4
Well Purging & Sample Collection
Bailer Purge Time
Bailer
Sample Collection Time
Depth to well bottom from measuring point: 33.60
Height of water column: 11.06
Measuring point: Top of Casing
1345
Cloudy
Gary Simcox 45 *F
Water Level & Well Data
Depth to water from measuring point: 22.54
GROUNDWATER SAMPLING FIELD DATA
Williams Gcocery Tuesday, February 25, 2014
4305-14-051
MW-5 Tuesday, February 25, 2014
Location: Purge Date:
Project No.: Purge Time:
Source Well: Sample Date:
Sample Time:
Locked?: Yes:x No: Weather:
Sampled By: Air Temp:
feet
feet
feet
Purge Method
Sample Method Start Stop
Purge Rate ml/min
Control Settings On: sec. Start Stop
Off: sec.
Pressure: psi
2" well:
height:14.26 x .163 = 2.3244
gallons X liters
Yes No x
*Stabilization Parameters
Time date Temp pHConductivity *ORP *D.O. *Turbidity DTW
Final Readings 1415 2/25/2014 17.20 5.54 36.10 3.00
*C u S
Was well purged dry
Field Analyses
Volume of water in well
Volume of water removed 7.0
Well Purging & Sample Collection
Bailer Purge Time
Bailer
Sample Collection Time
Depth to well bottom from measuring point: 33.50
Height of water column: 14.26
Measuring point: Top of Casing
1415
Cloudy
Gary Simcox 45 *F
Water Level & Well Data
Depth to water from measuring point: 19.24
GROUNDWATER SAMPLING FIELD DATA
Williams Gcocery Tuesday, February 25, 2014
4305-14-051
MW-6 Tuesday, February 25, 2014
Location: Purge Date:
Project No.: Purge Time:
Source Well: Sample Date:
Sample Time:
Locked?: Yes:x No: Weather:
Sampled By: Air Temp:
feet
feet
feet
Purge Method
Sample Method Start Stop
Purge Rate ml/min
Control Settings On: sec. Start Stop
Off: sec.
Pressure: psi
4" well:
height:5.65 x .66 = 3.729
gallons X liters
Yes No x
*Stabilization Parameters
Time date Temp pHConductivity *ORP *D.O. *Turbidity DTW
Final Readings 1115 2/25/2014 17.60 5.22 319.00 1.00
*C u S
Was well purged dry
Field Analyses
Volume of water in well
Volume of water removed 11.2
Well Purging & Sample Collection
Bailer Purge Time
Bailer
Sample Collection Time
Depth to well bottom from measuring point: 28.40
Height of water column: 5.65
Measuring point: Top of Casing
1115
Cloudy
Gary Simcox 45 *F
Water Level & Well Data
Depth to water from measuring point: 22.75
GROUNDWATER SAMPLING FIELD DATA
Williams Gcocery Tuesday, February 25, 2014
4305-14-051
RW-1 Tuesday, February 25, 2014
#=CL#
March 05, 2014
LIMS USE: FR - LINDA BLALOCK
LIMS OBJECT ID: 92191212
92191212
Project:
Pace Project No.:
RE:
Ms. Linda Blalock
NCDENR - UST Section
1637 Mail Service Center
Raleigh, NC 276991637
WILLIAMS GROCERY 15063-01
Dear Ms. Blalock:
Enclosed are the analytical results for sample(s) received by the laboratory on February 26, 2014.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 34
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 34
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92191212001 WSW-1 SM 6200B 63 PASI-CCAH
92191212002 WSW-2 SM 6200B 63 PASI-CCAH
92191212003 WSW-3 SM 6200B 63 PASI-CCAH
92191212004 WSW-4 SM 6200B 63 PASI-CCAH
92191212005 WSW-5 SM 6200B 63 PASI-CCAH
92191212006 WSW-6 SM 6200B 63 PASI-CCAH
92191212007 WSW-7 SM 6200B 63 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 34
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92191212003 WSW-3
Methylene Chloride <2.0 ug/L 03/02/14 20:162.0SM 6200B
92191212007 WSW-7
1,1-Dichloroethane <0.50 ug/L 03/02/14 21:220.50SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 34
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Method:
Client:S&ME_FTF_GSB
SM 6200B
Date:March 05, 2014
Description:6200B MSV
General Information:
7 samples were analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
QC Batch: MSV/25917
L3: Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
• LCS (Lab ID: 1147020)
• 1,2-Dibromo-3-chloropropane
QC Batch: MSV/25918
L3: Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
• LCS (Lab ID: 1147063)
• 1,2-Dibromo-3-chloropropane
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MSV/25917
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92190759001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• MSD (Lab ID: 1149552)
• Hexachloro-1,3-butadiene
• cis-1,3-Dichloropropene
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 34
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Method:
Client:S&ME_FTF_GSB
SM 6200B
Date:March 05, 2014
Description:6200B MSV
QC Batch: MSV/25917
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92190759001
M0: Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
• trans-1,3-Dichloropropene
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-1 Lab ID:92191212001 Collected:02/25/14 15:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 02/28/14 18:08 71-43-20.50 1
Bromobenzene <0.50 ug/L 02/28/14 18:08 108-86-10.50 1
Bromochloromethane <0.50 ug/L 02/28/14 18:08 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 02/28/14 18:08 75-27-40.50 1
Bromoform <0.50 ug/L 02/28/14 18:08 75-25-20.50 1
Bromomethane <5.0 ug/L 02/28/14 18:08 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 02/28/14 18:08 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 02/28/14 18:08 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 02/28/14 18:08 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 02/28/14 18:08 56-23-50.50 1
Chlorobenzene <0.50 ug/L 02/28/14 18:08 108-90-70.50 1
Chloroethane <1.0 ug/L 02/28/14 18:08 75-00-31.0 1
Chloroform <0.50 ug/L 02/28/14 18:08 67-66-30.50 1
Chloromethane <1.0 ug/L 02/28/14 18:08 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 02/28/14 18:08 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 02/28/14 18:08 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 02/28/14 18:08 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 02/28/14 18:08 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 02/28/14 18:08 106-93-40.50 1
Dibromomethane <0.50 ug/L 02/28/14 18:08 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 02/28/14 18:08 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 02/28/14 18:08 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 02/28/14 18:08 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 02/28/14 18:08 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 02/28/14 18:08 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 02/28/14 18:08 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 02/28/14 18:08 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 02/28/14 18:08 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 02/28/14 18:08 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 02/28/14 18:08 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 02/28/14 18:08 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 02/28/14 18:08 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 02/28/14 18:08 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 02/28/14 18:08 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 02/28/14 18:08 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 02/28/14 18:08 108-20-30.50 1
Ethylbenzene <0.50 ug/L 02/28/14 18:08 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 02/28/14 18:08 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 02/28/14 18:08 98-82-80.50 1
Methylene Chloride <2.0 ug/L 02/28/14 18:08 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 02/28/14 18:08 1634-04-40.50 1
Naphthalene <2.0 ug/L 02/28/14 18:08 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 02/28/14 18:08 103-65-10.50 1
Styrene <0.50 ug/L 02/28/14 18:08 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 02/28/14 18:08 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 02/28/14 18:08 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 02/28/14 18:08 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-1 Lab ID:92191212001 Collected:02/25/14 15:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 02/28/14 18:08 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 02/28/14 18:08 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 02/28/14 18:08 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 02/28/14 18:08 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 02/28/14 18:08 79-00-50.50 1
Trichloroethene <0.50 ug/L 02/28/14 18:08 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 02/28/14 18:08 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 02/28/14 18:08 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 02/28/14 18:08 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 02/28/14 18:08 108-67-80.50 1
Vinyl chloride <1.0 ug/L 02/28/14 18:08 75-01-41.0 1
m&p-Xylene <1.0 ug/L 02/28/14 18:08 179601-23-11.0 1
o-Xylene <0.50 ug/L 02/28/14 18:08 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)104 %02/28/14 18:08 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %02/28/14 18:08 460-00-470-130 1
Toluene-d8 (S)100 %02/28/14 18:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-2 Lab ID:92191212002 Collected:02/25/14 18:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 03/02/14 19:59 71-43-20.50 1
Bromobenzene <0.50 ug/L 03/02/14 19:59 108-86-10.50 1
Bromochloromethane <0.50 ug/L 03/02/14 19:59 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 03/02/14 19:59 75-27-40.50 1
Bromoform <0.50 ug/L 03/02/14 19:59 75-25-20.50 1
Bromomethane <5.0 ug/L 03/02/14 19:59 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 03/02/14 19:59 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 03/02/14 19:59 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 03/02/14 19:59 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 03/02/14 19:59 56-23-50.50 1
Chlorobenzene <0.50 ug/L 03/02/14 19:59 108-90-70.50 1
Chloroethane <1.0 ug/L 03/02/14 19:59 75-00-31.0 1
Chloroform <0.50 ug/L 03/02/14 19:59 67-66-30.50 1
Chloromethane <1.0 ug/L 03/02/14 19:59 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 03/02/14 19:59 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 03/02/14 19:59 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 03/02/14 19:59 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 03/02/14 19:59 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 03/02/14 19:59 106-93-40.50 1
Dibromomethane <0.50 ug/L 03/02/14 19:59 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 03/02/14 19:59 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 03/02/14 19:59 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 03/02/14 19:59 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 03/02/14 19:59 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 03/02/14 19:59 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 03/02/14 19:59 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 03/02/14 19:59 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 03/02/14 19:59 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 03/02/14 19:59 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 03/02/14 19:59 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 03/02/14 19:59 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 03/02/14 19:59 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 03/02/14 19:59 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 03/02/14 19:59 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 03/02/14 19:59 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 03/02/14 19:59 108-20-30.50 1
Ethylbenzene <0.50 ug/L 03/02/14 19:59 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 03/02/14 19:59 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 03/02/14 19:59 98-82-80.50 1
Methylene Chloride <2.0 ug/L 03/02/14 19:59 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 03/02/14 19:59 1634-04-40.50 1
Naphthalene <2.0 ug/L 03/02/14 19:59 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 03/02/14 19:59 103-65-10.50 1
Styrene <0.50 ug/L 03/02/14 19:59 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 03/02/14 19:59 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 03/02/14 19:59 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 03/02/14 19:59 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
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Page 9 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-2 Lab ID:92191212002 Collected:02/25/14 18:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 03/02/14 19:59 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 03/02/14 19:59 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 03/02/14 19:59 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 03/02/14 19:59 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 03/02/14 19:59 79-00-50.50 1
Trichloroethene <0.50 ug/L 03/02/14 19:59 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 03/02/14 19:59 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 03/02/14 19:59 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 03/02/14 19:59 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 03/02/14 19:59 108-67-80.50 1
Vinyl chloride <1.0 ug/L 03/02/14 19:59 75-01-41.0 1
m&p-Xylene <1.0 ug/L 03/02/14 19:59 179601-23-11.0 1
o-Xylene <0.50 ug/L 03/02/14 19:59 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %03/02/14 19:59 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %03/02/14 19:59 460-00-470-130 1
Toluene-d8 (S)102 %03/02/14 19:59 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-3 Lab ID:92191212003 Collected:02/25/14 17:30 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 03/02/14 20:16 71-43-20.50 1
Bromobenzene <0.50 ug/L 03/02/14 20:16 108-86-10.50 1
Bromochloromethane <0.50 ug/L 03/02/14 20:16 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 03/02/14 20:16 75-27-40.50 1
Bromoform <0.50 ug/L 03/02/14 20:16 75-25-20.50 1
Bromomethane <5.0 ug/L 03/02/14 20:16 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 03/02/14 20:16 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 03/02/14 20:16 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 03/02/14 20:16 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 03/02/14 20:16 56-23-50.50 1
Chlorobenzene <0.50 ug/L 03/02/14 20:16 108-90-70.50 1
Chloroethane <1.0 ug/L 03/02/14 20:16 75-00-31.0 1
Chloroform <0.50 ug/L 03/02/14 20:16 67-66-30.50 1
Chloromethane <1.0 ug/L 03/02/14 20:16 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 03/02/14 20:16 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 03/02/14 20:16 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 03/02/14 20:16 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 03/02/14 20:16 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 03/02/14 20:16 106-93-40.50 1
Dibromomethane <0.50 ug/L 03/02/14 20:16 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 03/02/14 20:16 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 03/02/14 20:16 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 03/02/14 20:16 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 03/02/14 20:16 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 03/02/14 20:16 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 03/02/14 20:16 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 03/02/14 20:16 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 03/02/14 20:16 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 03/02/14 20:16 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 03/02/14 20:16 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 03/02/14 20:16 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 03/02/14 20:16 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 03/02/14 20:16 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 03/02/14 20:16 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 03/02/14 20:16 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 03/02/14 20:16 108-20-30.50 1
Ethylbenzene <0.50 ug/L 03/02/14 20:16 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 03/02/14 20:16 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 03/02/14 20:16 98-82-80.50 1
Methylene Chloride <2.0 ug/L 03/02/14 20:16 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 03/02/14 20:16 1634-04-40.50 1
Naphthalene <2.0 ug/L 03/02/14 20:16 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 03/02/14 20:16 103-65-10.50 1
Styrene <0.50 ug/L 03/02/14 20:16 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 03/02/14 20:16 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 03/02/14 20:16 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 03/02/14 20:16 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-3 Lab ID:92191212003 Collected:02/25/14 17:30 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 03/02/14 20:16 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 03/02/14 20:16 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 03/02/14 20:16 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 03/02/14 20:16 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 03/02/14 20:16 79-00-50.50 1
Trichloroethene <0.50 ug/L 03/02/14 20:16 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 03/02/14 20:16 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 03/02/14 20:16 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 03/02/14 20:16 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 03/02/14 20:16 108-67-80.50 1
Vinyl chloride <1.0 ug/L 03/02/14 20:16 75-01-41.0 1
m&p-Xylene <1.0 ug/L 03/02/14 20:16 179601-23-11.0 1
o-Xylene <0.50 ug/L 03/02/14 20:16 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)103 %03/02/14 20:16 17060-07-070-130 1
4-Bromofluorobenzene (S)100 %03/02/14 20:16 460-00-470-130 1
Toluene-d8 (S)102 %03/02/14 20:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-4 Lab ID:92191212004 Collected:02/25/14 15:30 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 03/02/14 20:32 71-43-20.50 1
Bromobenzene <0.50 ug/L 03/02/14 20:32 108-86-10.50 1
Bromochloromethane <0.50 ug/L 03/02/14 20:32 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 03/02/14 20:32 75-27-40.50 1
Bromoform <0.50 ug/L 03/02/14 20:32 75-25-20.50 1
Bromomethane <5.0 ug/L 03/02/14 20:32 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 03/02/14 20:32 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 03/02/14 20:32 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 03/02/14 20:32 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 03/02/14 20:32 56-23-50.50 1
Chlorobenzene <0.50 ug/L 03/02/14 20:32 108-90-70.50 1
Chloroethane <1.0 ug/L 03/02/14 20:32 75-00-31.0 1
Chloroform <0.50 ug/L 03/02/14 20:32 67-66-30.50 1
Chloromethane <1.0 ug/L 03/02/14 20:32 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 03/02/14 20:32 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 03/02/14 20:32 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 03/02/14 20:32 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 03/02/14 20:32 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 03/02/14 20:32 106-93-40.50 1
Dibromomethane <0.50 ug/L 03/02/14 20:32 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 03/02/14 20:32 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 03/02/14 20:32 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 03/02/14 20:32 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 03/02/14 20:32 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 03/02/14 20:32 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 03/02/14 20:32 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 03/02/14 20:32 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 03/02/14 20:32 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 03/02/14 20:32 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 03/02/14 20:32 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 03/02/14 20:32 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 03/02/14 20:32 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 03/02/14 20:32 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 03/02/14 20:32 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 03/02/14 20:32 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 03/02/14 20:32 108-20-30.50 1
Ethylbenzene <0.50 ug/L 03/02/14 20:32 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 03/02/14 20:32 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 03/02/14 20:32 98-82-80.50 1
Methylene Chloride <2.0 ug/L 03/02/14 20:32 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 03/02/14 20:32 1634-04-40.50 1
Naphthalene <2.0 ug/L 03/02/14 20:32 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 03/02/14 20:32 103-65-10.50 1
Styrene <0.50 ug/L 03/02/14 20:32 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 03/02/14 20:32 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 03/02/14 20:32 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 03/02/14 20:32 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-4 Lab ID:92191212004 Collected:02/25/14 15:30 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 03/02/14 20:32 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 03/02/14 20:32 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 03/02/14 20:32 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 03/02/14 20:32 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 03/02/14 20:32 79-00-50.50 1
Trichloroethene <0.50 ug/L 03/02/14 20:32 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 03/02/14 20:32 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 03/02/14 20:32 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 03/02/14 20:32 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 03/02/14 20:32 108-67-80.50 1
Vinyl chloride <1.0 ug/L 03/02/14 20:32 75-01-41.0 1
m&p-Xylene <1.0 ug/L 03/02/14 20:32 179601-23-11.0 1
o-Xylene <0.50 ug/L 03/02/14 20:32 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)103 %03/02/14 20:32 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %03/02/14 20:32 460-00-470-130 1
Toluene-d8 (S)101 %03/02/14 20:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-5 Lab ID:92191212005 Collected:02/25/14 16:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 03/02/14 20:49 71-43-20.50 1
Bromobenzene <0.50 ug/L 03/02/14 20:49 108-86-10.50 1
Bromochloromethane <0.50 ug/L 03/02/14 20:49 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 03/02/14 20:49 75-27-40.50 1
Bromoform <0.50 ug/L 03/02/14 20:49 75-25-20.50 1
Bromomethane <5.0 ug/L 03/02/14 20:49 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 03/02/14 20:49 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 03/02/14 20:49 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 03/02/14 20:49 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 03/02/14 20:49 56-23-50.50 1
Chlorobenzene <0.50 ug/L 03/02/14 20:49 108-90-70.50 1
Chloroethane <1.0 ug/L 03/02/14 20:49 75-00-31.0 1
Chloroform <0.50 ug/L 03/02/14 20:49 67-66-30.50 1
Chloromethane <1.0 ug/L 03/02/14 20:49 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 03/02/14 20:49 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 03/02/14 20:49 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 03/02/14 20:49 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 03/02/14 20:49 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 03/02/14 20:49 106-93-40.50 1
Dibromomethane <0.50 ug/L 03/02/14 20:49 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 03/02/14 20:49 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 03/02/14 20:49 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 03/02/14 20:49 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 03/02/14 20:49 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 03/02/14 20:49 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 03/02/14 20:49 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 03/02/14 20:49 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 03/02/14 20:49 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 03/02/14 20:49 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 03/02/14 20:49 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 03/02/14 20:49 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 03/02/14 20:49 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 03/02/14 20:49 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 03/02/14 20:49 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 03/02/14 20:49 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 03/02/14 20:49 108-20-30.50 1
Ethylbenzene <0.50 ug/L 03/02/14 20:49 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 03/02/14 20:49 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 03/02/14 20:49 98-82-80.50 1
Methylene Chloride <2.0 ug/L 03/02/14 20:49 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 03/02/14 20:49 1634-04-40.50 1
Naphthalene <2.0 ug/L 03/02/14 20:49 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 03/02/14 20:49 103-65-10.50 1
Styrene <0.50 ug/L 03/02/14 20:49 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 03/02/14 20:49 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 03/02/14 20:49 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 03/02/14 20:49 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-5 Lab ID:92191212005 Collected:02/25/14 16:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 03/02/14 20:49 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 03/02/14 20:49 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 03/02/14 20:49 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 03/02/14 20:49 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 03/02/14 20:49 79-00-50.50 1
Trichloroethene <0.50 ug/L 03/02/14 20:49 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 03/02/14 20:49 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 03/02/14 20:49 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 03/02/14 20:49 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 03/02/14 20:49 108-67-80.50 1
Vinyl chloride <1.0 ug/L 03/02/14 20:49 75-01-41.0 1
m&p-Xylene <1.0 ug/L 03/02/14 20:49 179601-23-11.0 1
o-Xylene <0.50 ug/L 03/02/14 20:49 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)102 %03/02/14 20:49 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %03/02/14 20:49 460-00-470-130 1
Toluene-d8 (S)101 %03/02/14 20:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-6 Lab ID:92191212006 Collected:02/25/14 17:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 03/02/14 21:05 71-43-20.50 1
Bromobenzene <0.50 ug/L 03/02/14 21:05 108-86-10.50 1
Bromochloromethane <0.50 ug/L 03/02/14 21:05 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 03/02/14 21:05 75-27-40.50 1
Bromoform <0.50 ug/L 03/02/14 21:05 75-25-20.50 1
Bromomethane <5.0 ug/L 03/02/14 21:05 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 03/02/14 21:05 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 03/02/14 21:05 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 03/02/14 21:05 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 03/02/14 21:05 56-23-50.50 1
Chlorobenzene <0.50 ug/L 03/02/14 21:05 108-90-70.50 1
Chloroethane <1.0 ug/L 03/02/14 21:05 75-00-31.0 1
Chloroform <0.50 ug/L 03/02/14 21:05 67-66-30.50 1
Chloromethane <1.0 ug/L 03/02/14 21:05 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 03/02/14 21:05 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 03/02/14 21:05 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 03/02/14 21:05 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 03/02/14 21:05 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 03/02/14 21:05 106-93-40.50 1
Dibromomethane <0.50 ug/L 03/02/14 21:05 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 03/02/14 21:05 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 03/02/14 21:05 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 03/02/14 21:05 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 03/02/14 21:05 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 03/02/14 21:05 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 03/02/14 21:05 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 03/02/14 21:05 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 03/02/14 21:05 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 03/02/14 21:05 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 03/02/14 21:05 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 03/02/14 21:05 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 03/02/14 21:05 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 03/02/14 21:05 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 03/02/14 21:05 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 03/02/14 21:05 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 03/02/14 21:05 108-20-30.50 1
Ethylbenzene <0.50 ug/L 03/02/14 21:05 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 03/02/14 21:05 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 03/02/14 21:05 98-82-80.50 1
Methylene Chloride <2.0 ug/L 03/02/14 21:05 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 03/02/14 21:05 1634-04-40.50 1
Naphthalene <2.0 ug/L 03/02/14 21:05 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 03/02/14 21:05 103-65-10.50 1
Styrene <0.50 ug/L 03/02/14 21:05 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 03/02/14 21:05 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 03/02/14 21:05 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 03/02/14 21:05 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
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Page 17 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-6 Lab ID:92191212006 Collected:02/25/14 17:00 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 03/02/14 21:05 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 03/02/14 21:05 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 03/02/14 21:05 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 03/02/14 21:05 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 03/02/14 21:05 79-00-50.50 1
Trichloroethene <0.50 ug/L 03/02/14 21:05 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 03/02/14 21:05 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 03/02/14 21:05 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 03/02/14 21:05 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 03/02/14 21:05 108-67-80.50 1
Vinyl chloride <1.0 ug/L 03/02/14 21:05 75-01-41.0 1
m&p-Xylene <1.0 ug/L 03/02/14 21:05 179601-23-11.0 1
o-Xylene <0.50 ug/L 03/02/14 21:05 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)104 %03/02/14 21:05 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %03/02/14 21:05 460-00-470-130 1
Toluene-d8 (S)101 %03/02/14 21:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 18 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-7 Lab ID:92191212007 Collected:02/25/14 16:30 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Benzene <0.50 ug/L 03/02/14 21:22 71-43-20.50 1
Bromobenzene <0.50 ug/L 03/02/14 21:22 108-86-10.50 1
Bromochloromethane <0.50 ug/L 03/02/14 21:22 74-97-50.50 1
Bromodichloromethane <0.50 ug/L 03/02/14 21:22 75-27-40.50 1
Bromoform <0.50 ug/L 03/02/14 21:22 75-25-20.50 1
Bromomethane <5.0 ug/L 03/02/14 21:22 74-83-95.0 1
n-Butylbenzene <0.50 ug/L 03/02/14 21:22 104-51-80.50 1
sec-Butylbenzene <0.50 ug/L 03/02/14 21:22 135-98-80.50 1
tert-Butylbenzene <0.50 ug/L 03/02/14 21:22 98-06-60.50 1
Carbon tetrachloride <0.50 ug/L 03/02/14 21:22 56-23-50.50 1
Chlorobenzene <0.50 ug/L 03/02/14 21:22 108-90-70.50 1
Chloroethane <1.0 ug/L 03/02/14 21:22 75-00-31.0 1
Chloroform <0.50 ug/L 03/02/14 21:22 67-66-30.50 1
Chloromethane <1.0 ug/L 03/02/14 21:22 74-87-31.0 1
2-Chlorotoluene <0.50 ug/L 03/02/14 21:22 95-49-80.50 1
4-Chlorotoluene <0.50 ug/L 03/02/14 21:22 106-43-40.50 1
1,2-Dibromo-3-chloropropane <1.0 ug/L 03/02/14 21:22 96-12-81.0 1
Dibromochloromethane <0.50 ug/L 03/02/14 21:22 124-48-10.50 1
1,2-Dibromoethane (EDB)<0.50 ug/L 03/02/14 21:22 106-93-40.50 1
Dibromomethane <0.50 ug/L 03/02/14 21:22 74-95-30.50 1
1,2-Dichlorobenzene <0.50 ug/L 03/02/14 21:22 95-50-10.50 1
1,3-Dichlorobenzene <0.50 ug/L 03/02/14 21:22 541-73-10.50 1
1,4-Dichlorobenzene <0.50 ug/L 03/02/14 21:22 106-46-70.50 1
Dichlorodifluoromethane <0.50 ug/L 03/02/14 21:22 75-71-80.50 1
1,1-Dichloroethane <0.50 ug/L 03/02/14 21:22 75-34-30.50 1
1,2-Dichloroethane <0.50 ug/L 03/02/14 21:22 107-06-20.50 1
1,1-Dichloroethene <0.50 ug/L 03/02/14 21:22 75-35-40.50 1
cis-1,2-Dichloroethene <0.50 ug/L 03/02/14 21:22 156-59-20.50 1
trans-1,2-Dichloroethene <0.50 ug/L 03/02/14 21:22 156-60-50.50 1
1,2-Dichloropropane <0.50 ug/L 03/02/14 21:22 78-87-50.50 1
1,3-Dichloropropane <0.50 ug/L 03/02/14 21:22 142-28-90.50 1
2,2-Dichloropropane <0.50 ug/L 03/02/14 21:22 594-20-70.50 1
1,1-Dichloropropene <0.50 ug/L 03/02/14 21:22 563-58-60.50 1
cis-1,3-Dichloropropene <0.50 ug/L 03/02/14 21:22 10061-01-50.50 1
trans-1,3-Dichloropropene <0.50 ug/L 03/02/14 21:22 10061-02-60.50 1
Diisopropyl ether <0.50 ug/L 03/02/14 21:22 108-20-30.50 1
Ethylbenzene <0.50 ug/L 03/02/14 21:22 100-41-40.50 1
Hexachloro-1,3-butadiene <2.0 ug/L 03/02/14 21:22 87-68-32.0 1
Isopropylbenzene (Cumene)<0.50 ug/L 03/02/14 21:22 98-82-80.50 1
Methylene Chloride <2.0 ug/L 03/02/14 21:22 75-09-22.0 1
Methyl-tert-butyl ether <0.50 ug/L 03/02/14 21:22 1634-04-40.50 1
Naphthalene <2.0 ug/L 03/02/14 21:22 91-20-32.0 1
n-Propylbenzene <0.50 ug/L 03/02/14 21:22 103-65-10.50 1
Styrene <0.50 ug/L 03/02/14 21:22 100-42-50.50 1
1,1,1,2-Tetrachloroethane <0.50 ug/L 03/02/14 21:22 630-20-60.50 1
1,1,2,2-Tetrachloroethane <0.50 ug/L 03/02/14 21:22 79-34-50.50 1
Tetrachloroethene <0.50 ug/L 03/02/14 21:22 127-18-40.50 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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Huntersville, NC 28078
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Page 19 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Sample:WSW-7 Lab ID:92191212007 Collected:02/25/14 16:30 Received:02/26/14 16:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
6200B MSV Analytical Method: SM 6200B
Toluene <0.50 ug/L 03/02/14 21:22 108-88-30.50 1
1,2,3-Trichlorobenzene <2.0 ug/L 03/02/14 21:22 87-61-62.0 1
1,2,4-Trichlorobenzene <2.0 ug/L 03/02/14 21:22 120-82-12.0 1
1,1,1-Trichloroethane <0.50 ug/L 03/02/14 21:22 71-55-60.50 1
1,1,2-Trichloroethane <0.50 ug/L 03/02/14 21:22 79-00-50.50 1
Trichloroethene <0.50 ug/L 03/02/14 21:22 79-01-60.50 1
Trichlorofluoromethane <1.0 ug/L 03/02/14 21:22 75-69-41.0 1
1,2,3-Trichloropropane <0.50 ug/L 03/02/14 21:22 96-18-40.50 1
1,2,4-Trimethylbenzene <0.50 ug/L 03/02/14 21:22 95-63-60.50 1
1,3,5-Trimethylbenzene <0.50 ug/L 03/02/14 21:22 108-67-80.50 1
Vinyl chloride <1.0 ug/L 03/02/14 21:22 75-01-41.0 1
m&p-Xylene <1.0 ug/L 03/02/14 21:22 179601-23-11.0 1
o-Xylene <0.50 ug/L 03/02/14 21:22 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)103 %03/02/14 21:22 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %03/02/14 21:22 460-00-470-130 1
Toluene-d8 (S)101 %03/02/14 21:22 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
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[phone]
Page 20 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/25917
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92191212001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1147019
Associated Lab Samples:92191212001
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1,1-Trichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1,2,2-Tetrachloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1,2-Trichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1-Dichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,1-Dichloroethene ug/L <0.50 0.50 02/28/14 14:18
1,1-Dichloropropene ug/L <0.50 0.50 02/28/14 14:18
1,2,3-Trichlorobenzene ug/L <2.0 2.0 02/28/14 14:18
1,2,3-Trichloropropane ug/L <0.50 0.50 02/28/14 14:18
1,2,4-Trichlorobenzene ug/L <2.0 2.0 02/28/14 14:18
1,2,4-Trimethylbenzene ug/L <0.50 0.50 02/28/14 14:18
1,2-Dibromo-3-chloropropane ug/L <1.0 1.0 02/28/14 14:18
1,2-Dibromoethane (EDB)ug/L <0.50 0.50 02/28/14 14:18
1,2-Dichlorobenzene ug/L <0.50 0.50 02/28/14 14:18
1,2-Dichloroethane ug/L <0.50 0.50 02/28/14 14:18
1,2-Dichloropropane ug/L <0.50 0.50 02/28/14 14:18
1,3,5-Trimethylbenzene ug/L <0.50 0.50 02/28/14 14:18
1,3-Dichlorobenzene ug/L <0.50 0.50 02/28/14 14:18
1,3-Dichloropropane ug/L <0.50 0.50 02/28/14 14:18
1,4-Dichlorobenzene ug/L <0.50 0.50 02/28/14 14:18
2,2-Dichloropropane ug/L <0.50 0.50 02/28/14 14:18
2-Chlorotoluene ug/L <0.50 0.50 02/28/14 14:18
4-Chlorotoluene ug/L <0.50 0.50 02/28/14 14:18
Benzene ug/L <0.50 0.50 02/28/14 14:18
Bromobenzene ug/L <0.50 0.50 02/28/14 14:18
Bromochloromethane ug/L <0.50 0.50 02/28/14 14:18
Bromodichloromethane ug/L <0.50 0.50 02/28/14 14:18
Bromoform ug/L <0.50 0.50 02/28/14 14:18
Bromomethane ug/L <5.0 5.0 02/28/14 14:18
Carbon tetrachloride ug/L <0.50 0.50 02/28/14 14:18
Chlorobenzene ug/L <0.50 0.50 02/28/14 14:18
Chloroethane ug/L <1.0 1.0 02/28/14 14:18
Chloroform ug/L <0.50 0.50 02/28/14 14:18
Chloromethane ug/L <1.0 1.0 02/28/14 14:18
cis-1,2-Dichloroethene ug/L <0.50 0.50 02/28/14 14:18
cis-1,3-Dichloropropene ug/L <0.50 0.50 02/28/14 14:18
Dibromochloromethane ug/L <0.50 0.50 02/28/14 14:18
Dibromomethane ug/L <0.50 0.50 02/28/14 14:18
Dichlorodifluoromethane ug/L <0.50 0.50 02/28/14 14:18
Diisopropyl ether ug/L <0.50 0.50 02/28/14 14:18
Ethylbenzene ug/L <0.50 0.50 02/28/14 14:18
Hexachloro-1,3-butadiene ug/L <2.0 2.0 02/28/14 14:18
Isopropylbenzene (Cumene)ug/L <0.50 0.50 02/28/14 14:18
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1147019
Associated Lab Samples:92191212001
Matrix:Water
Analyzed
m&p-Xylene ug/L <1.0 1.0 02/28/14 14:18
Methyl-tert-butyl ether ug/L <0.50 0.50 02/28/14 14:18
Methylene Chloride ug/L <2.0 2.0 02/28/14 14:18
n-Butylbenzene ug/L <0.50 0.50 02/28/14 14:18
n-Propylbenzene ug/L <0.50 0.50 02/28/14 14:18
Naphthalene ug/L <2.0 2.0 02/28/14 14:18
o-Xylene ug/L <0.50 0.50 02/28/14 14:18
sec-Butylbenzene ug/L <0.50 0.50 02/28/14 14:18
Styrene ug/L <0.50 0.50 02/28/14 14:18
tert-Butylbenzene ug/L <0.50 0.50 02/28/14 14:18
Tetrachloroethene ug/L <0.50 0.50 02/28/14 14:18
Toluene ug/L <0.50 0.50 02/28/14 14:18
trans-1,2-Dichloroethene ug/L <0.50 0.50 02/28/14 14:18
trans-1,3-Dichloropropene ug/L <0.50 0.50 02/28/14 14:18
Trichloroethene ug/L <0.50 0.50 02/28/14 14:18
Trichlorofluoromethane ug/L <1.0 1.0 02/28/14 14:18
Vinyl chloride ug/L <1.0 1.0 02/28/14 14:18
1,2-Dichloroethane-d4 (S)%103 70-130 02/28/14 14:18
4-Bromofluorobenzene (S)%98 70-130 02/28/14 14:18
Toluene-d8 (S)%101 70-130 02/28/14 14:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1147020LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 51.450 103 60-140
1,1,1-Trichloroethane ug/L 58.150 116 60-140
1,1,2,2-Tetrachloroethane ug/L 56.550 113 60-140
1,1,2-Trichloroethane ug/L 57.250 114 60-140
1,1-Dichloroethane ug/L 54.450 109 60-140
1,1-Dichloroethene ug/L 50.450 101 60-140
1,1-Dichloropropene ug/L 56.750 113 60-140
1,2,3-Trichlorobenzene ug/L 58.450 117 60-140
1,2,3-Trichloropropane ug/L 55.750 111 60-140
1,2,4-Trichlorobenzene ug/L 57.150 114 60-140
1,2,4-Trimethylbenzene ug/L 56.750 113 60-140
1,2-Dibromo-3-chloropropane ug/L 78.3 CU,L35015760-140
1,2-Dibromoethane (EDB)ug/L 58.750 117 60-140
1,2-Dichlorobenzene ug/L 54.750 109 60-140
1,2-Dichloroethane ug/L 52.350 105 60-140
1,2-Dichloropropane ug/L 55.450 111 60-140
1,3,5-Trimethylbenzene ug/L 56.650 113 60-140
1,3-Dichlorobenzene ug/L 53.750 107 60-140
1,3-Dichloropropane ug/L 56.050 112 60-140
1,4-Dichlorobenzene ug/L 54.150 108 60-140
2,2-Dichloropropane ug/L 59.650 119 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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Page 22 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1147020LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorotoluene ug/L 52.350 105 60-140
4-Chlorotoluene ug/L 55.650 111 60-140
Benzene ug/L 56.050 112 60-140
Bromobenzene ug/L 56.150 112 60-140
Bromochloromethane ug/L 53.150 106 60-140
Bromodichloromethane ug/L 50.950 102 60-140
Bromoform ug/L 49.050 98 60-140
Bromomethane ug/L 30.150 60 60-140
Carbon tetrachloride ug/L 49.450 99 60-140
Chlorobenzene ug/L 55.050 110 60-140
Chloroethane ug/L 37.050 74 60-140
Chloroform ug/L 54.550 109 60-140
Chloromethane ug/L 46.650 93 60-140
cis-1,2-Dichloroethene ug/L 53.150 106 60-140
cis-1,3-Dichloropropene ug/L 51.350 103 60-140
Dibromochloromethane ug/L 51.650 103 60-140
Dibromomethane ug/L 55.850 112 60-140
Dichlorodifluoromethane ug/L 44.450 89 60-140
Diisopropyl ether ug/L 55.950 112 60-140
Ethylbenzene ug/L 55.450 111 60-140
Hexachloro-1,3-butadiene ug/L 58.050 116 60-140
Isopropylbenzene (Cumene)ug/L 58.750 117 60-140
m&p-Xylene ug/L 115100 115 60-140
Methyl-tert-butyl ether ug/L 56.550 113 60-140
Methylene Chloride ug/L 55.050 110 60-140
n-Butylbenzene ug/L 57.650 115 60-140
n-Propylbenzene ug/L 57.450 115 60-140
Naphthalene ug/L 59.250 118 60-140
o-Xylene ug/L 57.150 114 60-140
sec-Butylbenzene ug/L 57.250 114 60-140
Styrene ug/L 52.850 106 60-140
tert-Butylbenzene ug/L 57.650 115 60-140
Tetrachloroethene ug/L 55.650 111 60-140
Toluene ug/L 52.950 106 60-140
trans-1,2-Dichloroethene ug/L 52.450 105 60-140
trans-1,3-Dichloropropene ug/L 51.450 103 60-140
Trichloroethene ug/L 55.050 110 60-140
Trichlorofluoromethane ug/L 45.150 90 60-140
Vinyl chloride ug/L 50.150 100 60-140
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 23 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1149551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92190759001
1149552
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 65 60-14064 120ND13.0 12.8
1,1,1-Trichloroethane ug/L 20 71 60-14069 220ND14.2 13.9
1,1,2,2-Tetrachloroethane ug/L 20 74 60-14072 320ND14.8 14.4
1,1,2-Trichloroethane ug/L 20 70 60-14069 220ND14.1 13.7
1,1-Dichloroethane ug/L 20 68 60-14067 220ND13.7 13.4
1,1-Dichloroethene ug/L 20 75 60-14072 320ND14.9 14.5
1,1-Dichloropropene ug/L 20 73 60-14072 220ND14.6 14.4
1,2,3-Trichlorobenzene ug/L 20 70 60-14065 720ND14.0 13.1
1,2,3-Trichloropropane ug/L 20 72 60-14070 320ND14.4 14.0
1,2,4-Trichlorobenzene ug/L 20 67 60-14063 720ND13.4 12.5
1,2,4-Trimethylbenzene ug/L 20 69 60-14065 620ND14.0 13.3
1,2-Dibromo-3-chloropropane ug/L 20 95 60-14087 820ND18.9 17.5
1,2-Dibromoethane (EDB)ug/L 20 75 60-14074 220ND15.0 14.7
1,2-Dichlorobenzene ug/L 20 71 60-14067 620ND14.2 13.4
1,2-Dichloroethane ug/L 20 68 60-14065 320ND13.5 13.1
1,2-Dichloropropane ug/L 20 68 60-14066 320ND13.5 13.1
1,3,5-Trimethylbenzene ug/L 20 68 60-14066 320ND14.0 13.5
1,3-Dichlorobenzene ug/L 20 69 60-14064 720ND13.8 12.8
1,3-Dichloropropane ug/L 20 75 60-14073 220ND14.9 14.6
1,4-Dichlorobenzene ug/L 20 70 60-14066 520ND14.0 13.3
2,2-Dichloropropane ug/L 20 62 60-14061 220ND12.4 12.2
2-Chlorotoluene ug/L 20 71 60-14066 720ND14.1 13.1
4-Chlorotoluene ug/L 20 73 60-14068 620ND14.6 13.7
Benzene ug/L 20 68 60-14067 220ND13.7 13.4
Bromobenzene ug/L 20 74 60-14070 620ND14.8 13.9
Bromochloromethane ug/L 20 73 60-14069 620ND14.5 13.7
Bromodichloromethane ug/L 20 68 60-14064 520ND13.5 12.8
Bromoform ug/L 20 65 60-14063 320ND12.9 12.5
Bromomethane ug/L 20 87 60-14078 1020ND17.3 15.7
Carbon tetrachloride ug/L 20 66 60-14064 220ND13.1 12.9
Chlorobenzene ug/L 20 71 60-14069 320ND14.1 13.7
Chloroethane ug/L 20 71 60-14068 520ND14.2 13.5
Chloroform ug/L 20 68 60-14065 420ND13.7 13.2
Chloromethane ug/L 20 74 60-14071 320ND14.7 14.2
cis-1,2-Dichloroethene ug/L 20 69 60-14065 620ND13.8 13.0
cis-1,3-Dichloropropene ug/L M0206060-14057 420ND12.0 11.5
Dibromochloromethane ug/L 20 65 60-14064 220ND13.1 12.9
Dibromomethane ug/L 20 66 60-14063 420ND13.1 12.7
Dichlorodifluoromethane ug/L 20 77 60-14073 520ND15.4 14.6
Diisopropyl ether ug/L 20 71 60-14069 420ND14.3 13.7
Ethylbenzene ug/L 20 69 60-14067 320ND13.8 13.5
Hexachloro-1,3-butadiene ug/L M0206060-14059 220ND12.1 11.8
Isopropylbenzene (Cumene)ug/L 20 70 60-14069 220ND14.0 13.7
m&p-Xylene ug/L 40 69 60-14067 340ND28.0 27.3
Methyl-tert-butyl ether ug/L 20 68 60-14066 420ND13.8 13.3
Methylene Chloride ug/L 20 72 60-14068 520ND14.3 13.7
n-Butylbenzene ug/L 20 65 60-14064 220ND13.0 12.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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Page 24 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1149551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92190759001
1149552
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Propylbenzene ug/L 20 73 60-14070 420ND14.5 14.0
Naphthalene ug/L 20 72 60-14067 620ND14.6 13.7
o-Xylene ug/L 20 69 60-14067 220ND14.0 13.7
sec-Butylbenzene ug/L 20 68 60-14066 320ND13.5 13.1
Styrene ug/L 20 73 60-14070 520ND14.6 13.9
tert-Butylbenzene ug/L 20 70 60-14067 420ND14.0 13.4
Tetrachloroethene ug/L 20 69 60-14069 020ND13.8 13.8
Toluene ug/L 20 66 60-14064 220ND13.2 12.9
trans-1,2-Dichloroethene ug/L 20 78 60-14081 420ND15.5 16.1
trans-1,3-Dichloropropene ug/L M0206060-14059 220ND12.0 11.7
Trichloroethene ug/L 20 64 60-14063 120ND12.8 12.6
Trichlorofluoromethane ug/L 20 74 60-14071 420ND14.7 14.2
Vinyl chloride ug/L 20 79 60-14077 420ND15.9 15.3
1,2-Dichloroethane-d4 (S)%104 70-130101
4-Bromofluorobenzene (S)%97 70-13097
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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Page 25 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/25918
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92191212002, 92191212003, 92191212004, 92191212005, 92191212006, 92191212007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1147062
Associated Lab Samples:92191212002, 92191212003, 92191212004, 92191212005, 92191212006, 92191212007
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L <0.50 0.50 03/02/14 19:43
1,1,1-Trichloroethane ug/L <0.50 0.50 03/02/14 19:43
1,1,2,2-Tetrachloroethane ug/L <0.50 0.50 03/02/14 19:43
1,1,2-Trichloroethane ug/L <0.50 0.50 03/02/14 19:43
1,1-Dichloroethane ug/L <0.50 0.50 03/02/14 19:43
1,1-Dichloroethene ug/L <0.50 0.50 03/02/14 19:43
1,1-Dichloropropene ug/L <0.50 0.50 03/02/14 19:43
1,2,3-Trichlorobenzene ug/L <2.0 2.0 03/02/14 19:43
1,2,3-Trichloropropane ug/L <0.50 0.50 03/02/14 19:43
1,2,4-Trichlorobenzene ug/L <2.0 2.0 03/02/14 19:43
1,2,4-Trimethylbenzene ug/L <0.50 0.50 03/02/14 19:43
1,2-Dibromo-3-chloropropane ug/L <1.0 1.0 03/02/14 19:43
1,2-Dibromoethane (EDB)ug/L <0.50 0.50 03/02/14 19:43
1,2-Dichlorobenzene ug/L <0.50 0.50 03/02/14 19:43
1,2-Dichloroethane ug/L <0.50 0.50 03/02/14 19:43
1,2-Dichloropropane ug/L <0.50 0.50 03/02/14 19:43
1,3,5-Trimethylbenzene ug/L <0.50 0.50 03/02/14 19:43
1,3-Dichlorobenzene ug/L <0.50 0.50 03/02/14 19:43
1,3-Dichloropropane ug/L <0.50 0.50 03/02/14 19:43
1,4-Dichlorobenzene ug/L <0.50 0.50 03/02/14 19:43
2,2-Dichloropropane ug/L <0.50 0.50 03/02/14 19:43
2-Chlorotoluene ug/L <0.50 0.50 03/02/14 19:43
4-Chlorotoluene ug/L <0.50 0.50 03/02/14 19:43
Benzene ug/L <0.50 0.50 03/02/14 19:43
Bromobenzene ug/L <0.50 0.50 03/02/14 19:43
Bromochloromethane ug/L <0.50 0.50 03/02/14 19:43
Bromodichloromethane ug/L <0.50 0.50 03/02/14 19:43
Bromoform ug/L <0.50 0.50 03/02/14 19:43
Bromomethane ug/L <5.0 5.0 03/02/14 19:43
Carbon tetrachloride ug/L <0.50 0.50 03/02/14 19:43
Chlorobenzene ug/L <0.50 0.50 03/02/14 19:43
Chloroethane ug/L <1.0 1.0 03/02/14 19:43
Chloroform ug/L <0.50 0.50 03/02/14 19:43
Chloromethane ug/L <1.0 1.0 03/02/14 19:43
cis-1,2-Dichloroethene ug/L <0.50 0.50 03/02/14 19:43
cis-1,3-Dichloropropene ug/L <0.50 0.50 03/02/14 19:43
Dibromochloromethane ug/L <0.50 0.50 03/02/14 19:43
Dibromomethane ug/L <0.50 0.50 03/02/14 19:43
Dichlorodifluoromethane ug/L <0.50 0.50 03/02/14 19:43
Diisopropyl ether ug/L <0.50 0.50 03/02/14 19:43
Ethylbenzene ug/L <0.50 0.50 03/02/14 19:43
Hexachloro-1,3-butadiene ug/L <2.0 2.0 03/02/14 19:43
Isopropylbenzene (Cumene)ug/L <0.50 0.50 03/02/14 19:43
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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Huntersville, NC 28078
[phone]
Page 26 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1147062
Associated Lab Samples:92191212002, 92191212003, 92191212004, 92191212005, 92191212006, 92191212007
Matrix:Water
Analyzed
m&p-Xylene ug/L <1.0 1.0 03/02/14 19:43
Methyl-tert-butyl ether ug/L <0.50 0.50 03/02/14 19:43
Methylene Chloride ug/L <2.0 2.0 03/02/14 19:43
n-Butylbenzene ug/L <0.50 0.50 03/02/14 19:43
n-Propylbenzene ug/L <0.50 0.50 03/02/14 19:43
Naphthalene ug/L <2.0 2.0 03/02/14 19:43
o-Xylene ug/L <0.50 0.50 03/02/14 19:43
sec-Butylbenzene ug/L <0.50 0.50 03/02/14 19:43
Styrene ug/L <0.50 0.50 03/02/14 19:43
tert-Butylbenzene ug/L <0.50 0.50 03/02/14 19:43
Tetrachloroethene ug/L <0.50 0.50 03/02/14 19:43
Toluene ug/L <0.50 0.50 03/02/14 19:43
trans-1,2-Dichloroethene ug/L <0.50 0.50 03/02/14 19:43
trans-1,3-Dichloropropene ug/L <0.50 0.50 03/02/14 19:43
Trichloroethene ug/L <0.50 0.50 03/02/14 19:43
Trichlorofluoromethane ug/L <1.0 1.0 03/02/14 19:43
Vinyl chloride ug/L <1.0 1.0 03/02/14 19:43
1,2-Dichloroethane-d4 (S)%102 70-130 03/02/14 19:43
4-Bromofluorobenzene (S)%99 70-130 03/02/14 19:43
Toluene-d8 (S)%101 70-130 03/02/14 19:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1147063LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.450 101 60-140
1,1,1-Trichloroethane ug/L 56.250 112 60-140
1,1,2,2-Tetrachloroethane ug/L 53.750 107 60-140
1,1,2-Trichloroethane ug/L 55.750 111 60-140
1,1-Dichloroethane ug/L 50.950 102 60-140
1,1-Dichloroethene ug/L 48.350 97 60-140
1,1-Dichloropropene ug/L 52.850 106 60-140
1,2,3-Trichlorobenzene ug/L 56.050 112 60-140
1,2,3-Trichloropropane ug/L 53.750 107 60-140
1,2,4-Trichlorobenzene ug/L 55.050 110 60-140
1,2,4-Trimethylbenzene ug/L 53.750 107 60-140
1,2-Dibromo-3-chloropropane ug/L 74.1 L35014860-140
1,2-Dibromoethane (EDB)ug/L 57.550 115 60-140
1,2-Dichlorobenzene ug/L 53.050 106 60-140
1,2-Dichloroethane ug/L 50.150 100 60-140
1,2-Dichloropropane ug/L 53.450 107 60-140
1,3,5-Trimethylbenzene ug/L 54.750 109 60-140
1,3-Dichlorobenzene ug/L 52.250 104 60-140
1,3-Dichloropropane ug/L 54.550 109 60-140
1,4-Dichlorobenzene ug/L 52.550 105 60-140
2,2-Dichloropropane ug/L 60.050 120 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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[phone]
Page 27 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1147063LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorotoluene ug/L 50.450 101 60-140
4-Chlorotoluene ug/L 53.150 106 60-140
Benzene ug/L 54.150 108 60-140
Bromobenzene ug/L 53.150 106 60-140
Bromochloromethane ug/L 49.750 99 60-140
Bromodichloromethane ug/L 58.050 116 60-140
Bromoform ug/L 47.650 95 60-140
Bromomethane ug/L 37.850 76 60-140
Carbon tetrachloride ug/L 49.350 99 60-140
Chlorobenzene ug/L 52.850 106 60-140
Chloroethane ug/L 32.650 65 60-140
Chloroform ug/L 51.250 102 60-140
Chloromethane ug/L 48.450 97 60-140
cis-1,2-Dichloroethene ug/L 50.650 101 60-140
cis-1,3-Dichloropropene ug/L 50.050 100 60-140
Dibromochloromethane ug/L 50.550 101 60-140
Dibromomethane ug/L 54.550 109 60-140
Dichlorodifluoromethane ug/L 50.250 100 60-140
Diisopropyl ether ug/L 52.950 106 60-140
Ethylbenzene ug/L 52.750 105 60-140
Hexachloro-1,3-butadiene ug/L 54.650 109 60-140
Isopropylbenzene (Cumene)ug/L 57.250 114 60-140
m&p-Xylene ug/L 110100 110 60-140
Methyl-tert-butyl ether ug/L 54.350 109 60-140
Methylene Chloride ug/L 44.550 89 60-140
n-Butylbenzene ug/L 54.950 110 60-140
n-Propylbenzene ug/L 55.050 110 60-140
Naphthalene ug/L 56.550 113 60-140
o-Xylene ug/L 55.150 110 60-140
sec-Butylbenzene ug/L 54.850 110 60-140
Styrene ug/L 58.950 118 60-140
tert-Butylbenzene ug/L 54.550 109 60-140
Tetrachloroethene ug/L 54.450 109 60-140
Toluene ug/L 51.950 104 60-140
trans-1,2-Dichloroethene ug/L 49.950 100 60-140
trans-1,3-Dichloropropene ug/L 50.250 100 60-140
Trichloroethene ug/L 52.150 104 60-140
Trichlorofluoromethane ug/L 43.450 87 60-140
Vinyl chloride ug/L 51.350 103 60-140
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1150192MATRIX SPIKE SAMPLE:
MSSpike
Result
92191212002
1,1,1,2-Tetrachloroethane ug/L 13.320 67 60-140<0.50
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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Huntersville, NC 28078
[phone]
Page 28 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1150192MATRIX SPIKE SAMPLE:
MSSpike
Result
92191212002
1,1,1-Trichloroethane ug/L 14.720 73 60-140<0.50
1,1,2,2-Tetrachloroethane ug/L 15.120 76 60-140<0.50
1,1,2-Trichloroethane ug/L 14.420 72 60-140<0.50
1,1-Dichloroethane ug/L 14.220 71 60-140<0.50
1,1-Dichloroethene ug/L 15.420 77 60-140<0.50
1,1-Dichloropropene ug/L 15.020 75 60-140<0.50
1,2,3-Trichlorobenzene ug/L 14.120 69 60-140<2.0
1,2,3-Trichloropropane ug/L 14.820 74 60-140<0.50
1,2,4-Trichlorobenzene ug/L 13.320 65 60-140<2.0
1,2,4-Trimethylbenzene ug/L 14.220 71 60-140<0.50
1,2-Dibromo-3-chloropropane ug/L 18.220 91 60-140<1.0
1,2-Dibromoethane (EDB)ug/L 15.520 77 60-140<0.50
1,2-Dichlorobenzene ug/L 14.220 71 60-140<0.50
1,2-Dichloroethane ug/L 13.720 68 60-140<0.50
1,2-Dichloropropane ug/L 13.820 69 60-140<0.50
1,3,5-Trimethylbenzene ug/L 14.120 71 60-140<0.50
1,3-Dichlorobenzene ug/L 13.820 69 60-140<0.50
1,3-Dichloropropane ug/L 15.520 78 60-140<0.50
1,4-Dichlorobenzene ug/L 13.920 69 60-140<0.50
2,2-Dichloropropane ug/L 12.920 65 60-140<0.50
2-Chlorotoluene ug/L 13.920 70 60-140<0.50
4-Chlorotoluene ug/L 14.720 74 60-140<0.50
Benzene ug/L 14.320 71 60-140<0.50
Bromobenzene ug/L 14.720 74 60-140<0.50
Bromochloromethane ug/L 14.720 73 60-140<0.50
Bromodichloromethane ug/L 13.620 68 60-140<0.50
Bromoform ug/L 12.920 64 60-140<0.50
Bromomethane ug/L 17.820 89 60-140<5.0
Carbon tetrachloride ug/L 13.420 67 60-140<0.50
Chlorobenzene ug/L 14.620 73 60-140<0.50
Chloroethane ug/L 14.720 73 60-140<1.0
Chloroform ug/L 14.020 70 60-140<0.50
Chloromethane ug/L 15.420 77 60-140<1.0
cis-1,2-Dichloroethene ug/L 14.020 70 60-140<0.50
cis-1,3-Dichloropropene ug/L 12.220 61 60-140<0.50
Dibromochloromethane ug/L 13.420 67 60-140<0.50
Dibromomethane ug/L 13.720 69 60-140<0.50
Dichlorodifluoromethane ug/L 15.320 76 60-140<0.50
Diisopropyl ether ug/L 14.220 71 60-140<0.50
Ethylbenzene ug/L 14.220 71 60-140<0.50
Hexachloro-1,3-butadiene ug/L 12.220 60 60-140<2.0
Isopropylbenzene (Cumene)ug/L 14.520 72 60-140<0.50
m&p-Xylene ug/L 29.140 73 60-140<1.0
Methyl-tert-butyl ether ug/L 13.720 68 60-140<0.50
Methylene Chloride ug/L 14.620 72 60-140<2.0
n-Butylbenzene ug/L 13.420 66 60-140<0.50
n-Propylbenzene ug/L 14.820 74 60-140<0.50
Naphthalene ug/L 14.820 73 60-140<2.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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[phone]
Page 29 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1150192MATRIX SPIKE SAMPLE:
MSSpike
Result
92191212002
o-Xylene ug/L 14.420 72 60-140<0.50
sec-Butylbenzene ug/L 14.120 70 60-140<0.50
Styrene ug/L 14.920 75 60-140<0.50
tert-Butylbenzene ug/L 14.120 71 60-140<0.50
Tetrachloroethene ug/L 14.620 73 60-140<0.50
Toluene ug/L 13.520 68 60-140<0.50
trans-1,2-Dichloroethene ug/L 16.320 81 60-140<0.50
trans-1,3-Dichloropropene ug/L 12.420 62 60-140<0.50
Trichloroethene ug/L 13.420 67 60-140<0.50
Trichlorofluoromethane ug/L 14.820 74 60-140<1.0
Vinyl chloride ug/L 16.320 82 60-140<1.0
1,2-Dichloroethane-d4 (S)%103 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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[phone]
Page 30 of 34
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.CU
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.L3
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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Page 31 of 34
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92191212
WILLIAMS GROCERY 15063-01
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92191212001 MSV/25917WSW-1 SM 6200B
92191212002 MSV/25918WSW-2 SM 6200B
92191212003 MSV/25918WSW-3 SM 6200B
92191212004 MSV/25918WSW-4 SM 6200B
92191212005 MSV/25918WSW-5 SM 6200B
92191212006 MSV/25918WSW-6 SM 6200B
92191212007 MSV/25918WSW-7 SM 6200B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/05/2014 05:22 PM
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[phone]
Page 32 of 34
Page 33 of 34
Page 34 of 34