WS-3209_9351_CA_LAB_20230417_Waypoint Lab Resport 691-692

 
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

4/17/2023
Withers & Ravenel David Vail
115 Mackenan Dr. BUILDING 117 Cary, NC, 27511
Ref: Analytical Testing
Lab Report Number: 23-094-0011 Client Project Description: Virgina's Gas Station
23-0307-6B
Dear David Vail:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/4/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 80
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-094-0011
Page 2 of 80
Report Number:
Sample Summary Table
Client Project Description:
23-094-0011
Virgina's Gas Station
23-0307-6B
Lab No Client Sample ID Matrix Date Collected Date Received
03/28/2023 10:45Aqueous 92833 MW-1 04/04/2023 12:06
03/28/2023 11:50Aqueous 92834 RW-1 04/04/2023 12:06
03/28/2023 11:00Aqueous 92835 MW-3 04/04/2023 12:06
03/28/2023 11:20Aqueous 92836 MW-4 04/04/2023 12:06
03/28/2023 11:35Aqueous 92837 MW-5 04/04/2023 12:06
03/28/2023 13:35Aqueous 92838 MW-6 04/04/2023 12:06
03/28/2023 13:02Aqueous 92839 MW-7 04/04/2023 12:06
03/28/2023 13:00Aqueous 92840 MW-8 04/04/2023 12:06
03/28/2023 12:45Aqueous 92841 MW-10 04/04/2023 12:06
03/28/2023Aqueous 92842 TB 04/04/2023 12:06
03/28/2023 10:35Aqueous 92843 FB 04/04/2023 12:06
03/28/2023 15:10Aqueous 92844 WSW-16 04/04/2023 12:06
Page 3 of 80
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-094-0011
Report Limit
Project:Virgina's Gas Station
V 92833MW-1
1830 04/11/2023 05:476200BEthylbenzeneµg/L 50.0
70.8 04/11/2023 05:476200BIsopropylbenzeneµg/L 50.0
661 04/11/2023 05:476200BNaphthaleneµg/L 100
152 04/11/2023 05:476200Bn-Propylbenzene µg/L 50.0
63.9 04/11/2023 05:476200BStyreneµg/L 50.0
2490 04/11/2023 05:476200BTolueneµg/L 50.0
1880 04/11/2023 05:476200B1,2,4-Trimethylbenzene µg/L 50.0
665 04/11/2023 05:476200B1,3,5-Trimethylbenzene µg/L 50.0
3720 04/11/2023 05:476200Bo-Xylene µg/L 50.0
8580 04/11/2023 05:476200Bm,p-Xylene µg/L 100
12300 04/11/2023 05:476200BXylene (Total)µg/L 50.0
V 92834RW-1
25000 04/12/2023 09:316200BBenzeneµg/L 500
10.1 04/11/2023 00:306200Bn-Butylbenzene µg/L 5.00
8.77 04/11/2023 00:306200Bsec-Butyl benzene µg/L 5.00
999 04/11/2023 00:306200BDi-Isopropyl Ether (DIPE)µg/L 5.00
305 04/11/2023 00:306200B1,2-Dibromoethane µg/L 5.00
121 04/11/2023 00:306200B1,2-Dichloroethane µg/L 5.00
1350 04/12/2023 09:316200BEthylbenzeneµg/L 500
40.8 04/11/2023 00:306200BIsopropylbenzeneµg/L 5.00
9.40 04/11/2023 00:306200B4-Isopropyl toluene µg/L 5.00
2130 04/12/2023 09:316200BMethyl tert-butyl ether (MTBE)µg/L 1000
592 04/11/2023 00:306200BNaphthaleneµg/L 10.0
86.0 04/11/2023 00:306200Bn-Propylbenzene µg/L 5.00
62.2 04/11/2023 00:306200BStyreneµg/L 5.00
25300 04/12/2023 09:316200BTolueneµg/L 500
2460 04/12/2023 09:316200B1,2,4-Trimethylbenzene µg/L 500
872 04/11/2023 00:306200B1,3,5-Trimethylbenzene µg/L 5.00
4430 04/12/2023 09:316200Bo-Xylene µg/L 500
8520 04/12/2023 09:316200Bm,p-Xylene µg/L 1000
13000 04/12/2023 09:316200BXylene (Total)µg/L 500
V 92835MW-3
19100 04/12/2023 09:556200BBenzeneµg/L 500
793 04/11/2023 06:126200BDi-Isopropyl Ether (DIPE)µg/L 50.0
348 04/11/2023 06:126200B1,2-Dibromoethane µg/L 50.0
570 04/11/2023 06:126200B1,2-Dichloroethane µg/L 50.0
Page 4 of 80
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-094-0011
Report Limit
Project:Virgina's Gas Station
V 92835MW-3
1850 04/11/2023 06:126200BEthylbenzeneµg/L 50.0
72.7 04/11/2023 06:126200BIsopropylbenzeneµg/L 50.0
2130 04/11/2023 06:126200BMethyl tert-butyl ether (MTBE)µg/L 100
850 04/11/2023 06:126200BNaphthaleneµg/L 100
171 04/11/2023 06:126200Bn-Propylbenzene µg/L 50.0
74.9 04/11/2023 06:126200BStyreneµg/L 50.0
28600 04/12/2023 09:556200BTolueneµg/L 500
2350 04/11/2023 06:126200B1,2,4-Trimethylbenzene µg/L 50.0
619 04/11/2023 06:126200B1,3,5-Trimethylbenzene µg/L 50.0
4370 04/11/2023 06:126200Bo-Xylene µg/L 50.0
9140 04/11/2023 06:126200Bm,p-Xylene µg/L 100
13500 04/11/2023 06:126200BXylene (Total)µg/L 50.0
V 92836MW-4
1230 04/11/2023 05:416200BBenzeneµg/L 50.0
81.5 04/11/2023 05:416200Bn-Butylbenzene µg/L 50.0
871 04/11/2023 05:416200BEthylbenzeneµg/L 50.0
113 04/11/2023 05:416200B2-Hexanone µg/L 100
58.0 04/11/2023 05:416200B4-Isopropyl toluene µg/L 50.0
719 04/11/2023 05:416200BNaphthaleneµg/L 100
91.4 04/11/2023 05:416200Bn-Propylbenzene µg/L 50.0
9190 04/11/2023 05:416200BTolueneµg/L 50.0
2990 04/11/2023 05:416200B1,2,4-Trimethylbenzene µg/L 50.0
911 04/11/2023 05:416200B1,3,5-Trimethylbenzene µg/L 50.0
3790 04/11/2023 05:416200Bo-Xylene µg/L 50.0
8070 04/11/2023 05:416200Bm,p-Xylene µg/L 100
11900 04/11/2023 05:416200BXylene (Total)µg/L 50.0
V 92838MW-6
37.1 04/11/2023 01:346200BBenzeneµg/L 0.500
8.37 04/11/2023 01:346200Bn-Butylbenzene µg/L 0.500
7.31 04/11/2023 01:346200Bsec-Butyl benzene µg/L 0.500
2.93 04/11/2023 01:346200Btert-Butyl benzene µg/L 2.00
1.04 04/11/2023 01:346200BDi-Isopropyl Ether (DIPE)µg/L 0.500
H88604/14/2023 01:506200BEthylbenzeneµg/L 50.0
39.7 04/11/2023 01:346200B2-Hexanone µg/L 1.00
59.2 04/11/2023 01:346200BIsopropylbenzeneµg/L 0.500
6.79 04/11/2023 01:346200B4-Isopropyl toluene µg/L 0.500
Page 5 of 80
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-094-0011
Report Limit
Project:Virgina's Gas Station
V 92838MW-6
1.84 04/11/2023 01:346200BMethyl tert-butyl ether (MTBE)µg/L 1.00
18.3 04/11/2023 01:346200B4-Methyl-2-Pentanone µg/L 1.00
H31904/14/2023 01:506200BNaphthaleneµg/L 100
H14604/14/2023 01:506200Bn-Propylbenzene µg/L 50.0
40.0 04/11/2023 01:346200BStyreneµg/L 0.500
H37604/14/2023 01:506200BTolueneµg/L 50.0
H139004/14/2023 01:506200B1,2,4-Trimethylbenzene µg/L 50.0
H39304/14/2023 01:506200B1,3,5-Trimethylbenzene µg/L 50.0
H130004/14/2023 01:506200Bo-Xylene µg/L 50.0
H401004/14/2023 01:506200Bm,p-Xylene µg/L 100
H531004/14/2023 01:506200BXylene (Total)µg/L 50.0
V 92839MW-7
H0.520 04/13/2023 04:016200BBenzeneµg/L 0.500
V 92841MW-10
1.67 04/11/2023 02:486200BTolueneµg/L 0.500
Page 6 of 80

Client: Withers & Ravenel CASE NARRATIVE
Project: Virgina's Gas Station Lab Report Number: 23-094-0011
Date: 4/14/2023
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,2,3-Trichlorobenzene QC Batch No: V32021/V31860
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Sample 92838 (MW-6) QC Batch No: V32021/V31864
Original sample was run within hold time. Dilution for sample ran out of hold time. Results of dilution verify original data.
Sample 92838 (MW-6)
Analyte: Toluene-d8 QC Batch No: V31865/V31864
Surrogate recovery(s) was flagged as outside QC limits due to high levels of target and/or non-target analytes. Batch QC samples (method blank and laboratory control samples) all showed surrogates within QC limits.
Sample 92839 (MW-7)
QC Batch No: V31970/V31969 Sample was run after a very hot sample originally within hold time, but exibited carryover. The sample was re-run
outside of hold time and saw the carryover was in fact due to the previous sample. Second run reported. Sample 92840 (MW-8) QC Batch No: V31970/V31969
Sample was run after a very hot sample originally within hold time, but exibited carryover. The sample was re-run outside of hold time and saw the carryover was in fact due to the previous sample. Second run reported.

Page 7 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-1
92833 Matrix:
3/28/2023 10:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1000 µg/L 1000Acetone 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Benzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Bromobenzene 100 04/11/23 05:47 6200BMSA
<100 µg/L 100Bromochloromethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Bromodichloromethane 100 04/11/23 05:47 6200BMSA
<500 µg/L 500Bromoform 100 04/11/23 05:47 6200BMSA
<100 µg/L 100Bromomethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0n-Butylbenzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0sec-Butyl benzene 100 04/11/23 05:47 6200BMSA
<200 µg/L 200tert-Butyl benzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Carbon Tetrachloride 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Chlorobenzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Chlorodibromomethane 100 04/11/23 05:47 6200BMSA
<100 µg/L 100Chloroethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Chloroform 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Chloromethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.02-Chlorotoluene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.04-Chlorotoluene 100 04/11/23 05:47 6200BMSA
<200 µg/L 2001,2-Dibromo-3-Chloropropane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,2-Dibromoethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Dibromomethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,2-Dichlorobenzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,3-Dichlorobenzene 100 04/11/23 05:47 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 8 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-1
92833 Matrix:
3/28/2023 10:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<50.0 µg/L 50.01,4-Dichlorobenzene 100 04/11/23 05:47 6200BMSA
<500 µg/L 500Dichlorodifluoromethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,2-Dichloroethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0cis-1,2-Dichloroethene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0trans-1,2-Dichloroethene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,2-Dichloropropane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,3-Dichloropropane 100 04/11/23 05:47 6200BMSA
<200 µg/L 2002,2-Dichloropropane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,1-Dichloropropene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0cis-1,3-Dichloropropene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0trans-1,3-Dichloropropene 100 04/11/23 05:47 6200BMSA
<20000 µg/L 20000Ethanol 100 04/11/23 05:47 6200BMSA
1830 µg/L 50.0Ethylbenzene 100 04/11/23 05:47 6200BMSA
<300 µg/L 300Hexachlorobutadiene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Di-Isopropyl Ether (DIPE)100 04/11/23 05:47 6200BMSA
70.8 µg/L 50.0Isopropylbenzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.04-Isopropyl toluene 100 04/11/23 05:47 6200BMSA
<100 µg/L 1002-Hexanone 100 04/11/23 05:47 6200BMSA
<500 µg/L 500Methyl Ethyl Ketone (MEK)100 04/11/23 05:47 6200BMSA
<200 µg/L 200Methylene Chloride 100 04/11/23 05:47 6200BMSA
<100 µg/L 100Methyl tert-butyl ether (MTBE)100 04/11/23 05:47 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 9 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-1
92833 Matrix:
3/28/2023 10:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 1004-Methyl-2-Pentanone 100 04/11/23 05:47 6200BMSA
661 µg/L 100Naphthalene 100 04/11/23 05:47 6200BMSA
152 µg/L 50.0n-Propylbenzene 100 04/11/23 05:47 6200BMSA
63.9 µg/L 50.0Styrene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Tetrachloroethene 100 04/11/23 05:47 6200BMSA
2490 µg/L 50.0Toluene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,2,3-Trichlorobenzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,2,4-Trichlorobenzene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,1,1-Trichloroethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,1,2-Trichloroethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Trichloroethene 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Trichlorofluoromethane 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.01,2,3-Trichloropropane 100 04/11/23 05:47 6200BMSA
1880 µg/L 50.01,2,4-Trimethylbenzene 100 04/11/23 05:47 6200BMSA
665 µg/L 50.01,3,5-Trimethylbenzene 100 04/11/23 05:47 6200BMSA
<500 µg/L 500Vinyl Acetate 100 04/11/23 05:47 6200BMSA
<50.0 µg/L 50.0Vinyl Chloride 100 04/11/23 05:47 6200BMSA
8580 µg/L 100m,p-Xylene 100 04/11/23 05:47 6200BMSA
3720 µg/L 50.0o-Xylene 100 04/11/23 05:47 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 10 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-1
92833 Matrix:
3/28/2023 10:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
12300 µg/L 50.0Xylene (Total)100 04/11/23 05:47 6200B
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%04/11/23 05:47100 MSA V31866
Surrogate: Dibromofluoromethane 102 Limits: 70-130%04/11/23 05:47100 MSA V31866
Surrogate: 1,2-Dichloroethane - d4 105 Limits: 70-130%04/11/23 05:47100 MSA V31866
Surrogate: Toluene-d8 99.2 Limits: 70-130%04/11/23 05:47100 MSA V31866
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 11 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:RW-1
92834 Matrix:
3/28/2023 11:50
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100Acetone 10 04/11/23 00:30 6200BMSA
25000 µg/L 500Benzene 1000 04/12/23 09:31 6200BTBL
<5.00 µg/L 5.00Bromobenzene 10 04/11/23 00:30 6200BMSA
<10.0 µg/L 10.0Bromochloromethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Bromodichloromethane 10 04/11/23 00:30 6200BMSA
<50.0 µg/L 50.0Bromoform 10 04/11/23 00:30 6200BMSA
<10.0 µg/L 10.0Bromomethane 10 04/11/23 00:30 6200BMSA
10.1 µg/L 5.00n-Butylbenzene 10 04/11/23 00:30 6200BMSA
8.77 µg/L 5.00sec-Butyl benzene 10 04/11/23 00:30 6200BMSA
<20.0 µg/L 20.0tert-Butyl benzene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Carbon Tetrachloride 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Chlorobenzene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Chlorodibromomethane 10 04/11/23 00:30 6200BMSA
<10.0 µg/L 10.0Chloroethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Chloroform 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Chloromethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.002-Chlorotoluene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.004-Chlorotoluene 10 04/11/23 00:30 6200BMSA
<20.0 µg/L 20.01,2-Dibromo-3-Chloropropane 10 04/11/23 00:30 6200BMSA
305 µg/L 5.001,2-Dibromoethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Dibromomethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,2-Dichlorobenzene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,3-Dichlorobenzene 10 04/11/23 00:30 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 12 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:RW-1
92834 Matrix:
3/28/2023 11:50
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<5.00 µg/L 5.001,4-Dichlorobenzene 10 04/11/23 00:30 6200BMSA
<50.0 µg/L 50.0Dichlorodifluoromethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,1-Dichloroethane 10 04/11/23 00:30 6200BMSA
121 µg/L 5.001,2-Dichloroethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,1-Dichloroethene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00cis-1,2-Dichloroethene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00trans-1,2-Dichloroethene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,2-Dichloropropane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,3-Dichloropropane 10 04/11/23 00:30 6200BMSA
<20.0 µg/L 20.02,2-Dichloropropane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,1-Dichloropropene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00cis-1,3-Dichloropropene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00trans-1,3-Dichloropropene 10 04/11/23 00:30 6200BMSA
<2000 µg/L 2000Ethanol 10 04/11/23 00:30 6200BMSA
1350 µg/L 500Ethylbenzene 1000 04/12/23 09:31 6200BTBL
<30.0 µg/L 30.0Hexachlorobutadiene 10 04/11/23 00:30 6200BMSA
999 µg/L 5.00Di-Isopropyl Ether (DIPE)10 04/11/23 00:30 6200BMSA
40.8 µg/L 5.00Isopropylbenzene 10 04/11/23 00:30 6200BMSA
9.40 µg/L 5.004-Isopropyl toluene 10 04/11/23 00:30 6200BMSA
<10.0 µg/L 10.02-Hexanone 10 04/11/23 00:30 6200BMSA
<50.0 µg/L 50.0Methyl Ethyl Ketone (MEK)10 04/11/23 00:30 6200BMSA
<20.0 µg/L 20.0Methylene Chloride 10 04/11/23 00:30 6200BMSA
2130 µg/L 1000Methyl tert-butyl ether (MTBE)1000 04/12/23 09:31 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 13 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:RW-1
92834 Matrix:
3/28/2023 11:50
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.04-Methyl-2-Pentanone 10 04/11/23 00:30 6200BMSA
592 µg/L 10.0Naphthalene 10 04/11/23 00:30 6200BMSA
86.0 µg/L 5.00n-Propylbenzene 10 04/11/23 00:30 6200BMSA
62.2 µg/L 5.00Styrene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,1,1,2-Tetrachloroethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,1,2,2-Tetrachloroethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Tetrachloroethene 10 04/11/23 00:30 6200BMSA
25300 µg/L 500Toluene 1000 04/12/23 09:31 6200BTBL
<5.00 µg/L 5.001,2,3-Trichlorobenzene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,2,4-Trichlorobenzene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,1,1-Trichloroethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,1,2-Trichloroethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Trichloroethene 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Trichlorofluoromethane 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.001,2,3-Trichloropropane 10 04/11/23 00:30 6200BMSA
2460 µg/L 5001,2,4-Trimethylbenzene 1000 04/12/23 09:31 6200BTBL
872 µg/L 5.001,3,5-Trimethylbenzene 10 04/11/23 00:30 6200BMSA
<50.0 µg/L 50.0Vinyl Acetate 10 04/11/23 00:30 6200BMSA
<5.00 µg/L 5.00Vinyl Chloride 10 04/11/23 00:30 6200BMSA
8520 µg/L 1000m,p-Xylene 1000 04/12/23 09:31 6200BTBL
4430 µg/L 500o-Xylene 1000 04/12/23 09:31 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 14 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:RW-1
92834 Matrix:
3/28/2023 11:50
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
13000 µg/L 500Xylene (Total)1000 04/12/23 09:31 6200B
Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%04/11/23 00:3010 MSA V31866
Surrogate: Dibromofluoromethane 97.8 Limits: 70-130%04/11/23 00:3010 MSA V31866
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%04/11/23 00:3010 MSA V31866
Surrogate: Toluene-d8 95.6 Limits: 70-130%04/11/23 00:3010 MSA V31866
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%04/12/23 09:311000 TBL V31920
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%04/12/23 09:311000 TBL V31920
Surrogate: 1,2-Dichloroethane - d4 97.2 Limits: 70-130%04/12/23 09:311000 TBL V31920
Surrogate: Toluene-d8 99.8 Limits: 70-130%04/12/23 09:311000 TBL V31920
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 15 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-3
92835 Matrix:
3/28/2023 11:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1000 µg/L 1000Acetone 100 04/11/23 06:12 6200BMSA
19100 µg/L 500Benzene 1000 04/12/23 09:55 6200BTBL
<50.0 µg/L 50.0Bromobenzene 100 04/11/23 06:12 6200BMSA
<100 µg/L 100Bromochloromethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Bromodichloromethane 100 04/11/23 06:12 6200BMSA
<500 µg/L 500Bromoform 100 04/11/23 06:12 6200BMSA
<100 µg/L 100Bromomethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0n-Butylbenzene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0sec-Butyl benzene 100 04/11/23 06:12 6200BMSA
<200 µg/L 200tert-Butyl benzene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Carbon Tetrachloride 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Chlorobenzene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Chlorodibromomethane 100 04/11/23 06:12 6200BMSA
<100 µg/L 100Chloroethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Chloroform 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Chloromethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.02-Chlorotoluene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.04-Chlorotoluene 100 04/11/23 06:12 6200BMSA
<200 µg/L 2001,2-Dibromo-3-Chloropropane 100 04/11/23 06:12 6200BMSA
348 µg/L 50.01,2-Dibromoethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Dibromomethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,2-Dichlorobenzene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,3-Dichlorobenzene 100 04/11/23 06:12 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 16 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-3
92835 Matrix:
3/28/2023 11:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<50.0 µg/L 50.01,4-Dichlorobenzene 100 04/11/23 06:12 6200BMSA
<500 µg/L 500Dichlorodifluoromethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethane 100 04/11/23 06:12 6200BMSA
570 µg/L 50.01,2-Dichloroethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0cis-1,2-Dichloroethene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0trans-1,2-Dichloroethene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,2-Dichloropropane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,3-Dichloropropane 100 04/11/23 06:12 6200BMSA
<200 µg/L 2002,2-Dichloropropane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,1-Dichloropropene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0cis-1,3-Dichloropropene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0trans-1,3-Dichloropropene 100 04/11/23 06:12 6200BMSA
<20000 µg/L 20000Ethanol 100 04/11/23 06:12 6200BMSA
1850 µg/L 50.0Ethylbenzene 100 04/11/23 06:12 6200BMSA
<300 µg/L 300Hexachlorobutadiene 100 04/11/23 06:12 6200BMSA
793 µg/L 50.0Di-Isopropyl Ether (DIPE)100 04/11/23 06:12 6200BMSA
72.7 µg/L 50.0Isopropylbenzene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.04-Isopropyl toluene 100 04/11/23 06:12 6200BMSA
<100 µg/L 1002-Hexanone 100 04/11/23 06:12 6200BMSA
<500 µg/L 500Methyl Ethyl Ketone (MEK)100 04/11/23 06:12 6200BMSA
<200 µg/L 200Methylene Chloride 100 04/11/23 06:12 6200BMSA
2130 µg/L 100Methyl tert-butyl ether (MTBE)100 04/11/23 06:12 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 17 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-3
92835 Matrix:
3/28/2023 11:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 1004-Methyl-2-Pentanone 100 04/11/23 06:12 6200BMSA
850 µg/L 100Naphthalene 100 04/11/23 06:12 6200BMSA
171 µg/L 50.0n-Propylbenzene 100 04/11/23 06:12 6200BMSA
74.9 µg/L 50.0Styrene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Tetrachloroethene 100 04/11/23 06:12 6200BMSA
28600 µg/L 500Toluene 1000 04/12/23 09:55 6200BTBL
<50.0 µg/L 50.01,2,3-Trichlorobenzene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,2,4-Trichlorobenzene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,1,1-Trichloroethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,1,2-Trichloroethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Trichloroethene 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Trichlorofluoromethane 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.01,2,3-Trichloropropane 100 04/11/23 06:12 6200BMSA
2350 µg/L 50.01,2,4-Trimethylbenzene 100 04/11/23 06:12 6200BMSA
619 µg/L 50.01,3,5-Trimethylbenzene 100 04/11/23 06:12 6200BMSA
<500 µg/L 500Vinyl Acetate 100 04/11/23 06:12 6200BMSA
<50.0 µg/L 50.0Vinyl Chloride 100 04/11/23 06:12 6200BMSA
9140 µg/L 100m,p-Xylene 100 04/11/23 06:12 6200BMSA
4370 µg/L 50.0o-Xylene 100 04/11/23 06:12 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 18 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-3
92835 Matrix:
3/28/2023 11:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
13500 µg/L 50.0Xylene (Total)100 04/11/23 06:12 6200B
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%04/11/23 06:12100 MSA V31866
Surrogate: Dibromofluoromethane 96.2 Limits: 70-130%04/11/23 06:12100 MSA V31866
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%04/11/23 06:12100 MSA V31866
Surrogate: Toluene-d8 97.0 Limits: 70-130%04/11/23 06:12100 MSA V31866
Surrogate: 4-Bromofluorobenzene 106 Limits: 70-130%04/12/23 09:551000 TBL V31920
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%04/12/23 09:551000 TBL V31920
Surrogate: 1,2-Dichloroethane - d4 96.0 Limits: 70-130%04/12/23 09:551000 TBL V31920
Surrogate: Toluene-d8 102 Limits: 70-130%04/12/23 09:551000 TBL V31920
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 19 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-4
92836 Matrix:
3/28/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1000 µg/L 1000Acetone 100 04/11/23 05:41 6200BMSA
1230 µg/L 50.0Benzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Bromobenzene 100 04/11/23 05:41 6200BMSA
<100 µg/L 100Bromochloromethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Bromodichloromethane 100 04/11/23 05:41 6200BMSA
<500 µg/L 500Bromoform 100 04/11/23 05:41 6200BMSA
<100 µg/L 100Bromomethane 100 04/11/23 05:41 6200BMSA
81.5 µg/L 50.0n-Butylbenzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0sec-Butyl benzene 100 04/11/23 05:41 6200BMSA
<200 µg/L 200tert-Butyl benzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Carbon Tetrachloride 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Chlorobenzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Chlorodibromomethane 100 04/11/23 05:41 6200BMSA
<100 µg/L 100Chloroethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Chloroform 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Chloromethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.02-Chlorotoluene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.04-Chlorotoluene 100 04/11/23 05:41 6200BMSA
<200 µg/L 2001,2-Dibromo-3-Chloropropane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,2-Dibromoethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Dibromomethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,2-Dichlorobenzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,3-Dichlorobenzene 100 04/11/23 05:41 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 20 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-4
92836 Matrix:
3/28/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<50.0 µg/L 50.01,4-Dichlorobenzene 100 04/11/23 05:41 6200BMSA
<500 µg/L 500Dichlorodifluoromethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,2-Dichloroethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,1-Dichloroethene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0cis-1,2-Dichloroethene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0trans-1,2-Dichloroethene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,2-Dichloropropane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,3-Dichloropropane 100 04/11/23 05:41 6200BMSA
<200 µg/L 2002,2-Dichloropropane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,1-Dichloropropene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0cis-1,3-Dichloropropene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0trans-1,3-Dichloropropene 100 04/11/23 05:41 6200BMSA
<20000 µg/L 20000Ethanol 100 04/11/23 05:41 6200BMSA
871 µg/L 50.0Ethylbenzene 100 04/11/23 05:41 6200BMSA
<300 µg/L 300Hexachlorobutadiene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Di-Isopropyl Ether (DIPE)100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Isopropylbenzene 100 04/11/23 05:41 6200BMSA
58.0 µg/L 50.04-Isopropyl toluene 100 04/11/23 05:41 6200BMSA
113 µg/L 1002-Hexanone 100 04/11/23 05:41 6200BMSA
<500 µg/L 500Methyl Ethyl Ketone (MEK)100 04/11/23 05:41 6200BMSA
<200 µg/L 200Methylene Chloride 100 04/11/23 05:41 6200BMSA
<100 µg/L 100Methyl tert-butyl ether (MTBE)100 04/11/23 05:41 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 21 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-4
92836 Matrix:
3/28/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 1004-Methyl-2-Pentanone 100 04/11/23 05:41 6200BMSA
719 µg/L 100Naphthalene 100 04/11/23 05:41 6200BMSA
91.4 µg/L 50.0n-Propylbenzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Styrene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Tetrachloroethene 100 04/11/23 05:41 6200BMSA
9190 µg/L 50.0Toluene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,2,3-Trichlorobenzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,2,4-Trichlorobenzene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,1,1-Trichloroethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,1,2-Trichloroethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Trichloroethene 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Trichlorofluoromethane 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.01,2,3-Trichloropropane 100 04/11/23 05:41 6200BMSA
2990 µg/L 50.01,2,4-Trimethylbenzene 100 04/11/23 05:41 6200BMSA
911 µg/L 50.01,3,5-Trimethylbenzene 100 04/11/23 05:41 6200BMSA
<500 µg/L 500Vinyl Acetate 100 04/11/23 05:41 6200BMSA
<50.0 µg/L 50.0Vinyl Chloride 100 04/11/23 05:41 6200BMSA
8070 µg/L 100m,p-Xylene 100 04/11/23 05:41 6200BMSA
3790 µg/L 50.0o-Xylene 100 04/11/23 05:41 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 22 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-4
92836 Matrix:
3/28/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
11900 µg/L 50.0Xylene (Total)100 04/11/23 05:41 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/11/23 05:41100 MSA V31865
Surrogate: Dibromofluoromethane 102 Limits: 70-130%04/11/23 05:41100 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%04/11/23 05:41100 MSA V31865
Surrogate: Toluene-d8 103 Limits: 70-130%04/11/23 05:41100 MSA V31865
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 23 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-5
92837 Matrix:
3/28/2023 11:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/11/23 01:09 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/11/23 01:09 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/11/23 01:09 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/11/23 01:09 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/11/23 01:09 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/11/23 01:09 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/11/23 01:09 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 24 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-5
92837 Matrix:
3/28/2023 11:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/11/23 01:09 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/11/23 01:09 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/11/23 01:09 6200BMSA
<200 µg/L 200Ethanol 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/11/23 01:09 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/11/23 01:09 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/11/23 01:09 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/11/23 01:09 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/11/23 01:09 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/11/23 01:09 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 25 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-5
92837 Matrix:
3/28/2023 11:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/11/23 01:09 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/11/23 01:09 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/11/23 01:09 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/11/23 01:09 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/11/23 01:09 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 26 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-5
92837 Matrix:
3/28/2023 11:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/11/23 01:09 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/11/23 01:091 MSA V31865
Surrogate: Dibromofluoromethane 101 Limits: 70-130%04/11/23 01:091 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%04/11/23 01:091 MSA V31865
Surrogate: Toluene-d8 104 Limits: 70-130%04/11/23 01:091 MSA V31865
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 27 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-6
92838 Matrix:
3/28/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1000 H µg/L 1000Acetone 100 04/14/23 01:50 6200BMSA
37.1 µg/L 0.500Benzene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/11/23 01:34 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/11/23 01:34 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/11/23 01:34 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/11/23 01:34 6200BMSA
8.37 µg/L 0.500n-Butylbenzene 1 04/11/23 01:34 6200BMSA
7.31 µg/L 0.500sec-Butyl benzene 1 04/11/23 01:34 6200BMSA
2.93 µg/L 2.00tert-Butyl benzene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/11/23 01:34 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/11/23 01:34 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/11/23 01:34 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 28 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-6
92838 Matrix:
3/28/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/11/23 01:34 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/11/23 01:34 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/11/23 01:34 6200BMSA
<200 µg/L 200Ethanol 1 04/11/23 01:34 6200BMSA
886 H µg/L 50.0Ethylbenzene 100 04/14/23 01:50 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/11/23 01:34 6200BMSA
1.04 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/11/23 01:34 6200BMSA
59.2 µg/L 0.500Isopropylbenzene 1 04/11/23 01:34 6200BMSA
6.79 µg/L 0.5004-Isopropyl toluene 1 04/11/23 01:34 6200BMSA
39.7 µg/L 1.002-Hexanone 1 04/11/23 01:34 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/11/23 01:34 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/11/23 01:34 6200BMSA
1.84 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/11/23 01:34 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 29 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-6
92838 Matrix:
3/28/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
18.3 µg/L 1.004-Methyl-2-Pentanone 1 04/11/23 01:34 6200BMSA
319 H µg/L 100Naphthalene 100 04/14/23 01:50 6200BMSA
146 H µg/L 50.0n-Propylbenzene 100 04/14/23 01:50 6200BMSA
40.0 µg/L 0.500Styrene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/11/23 01:34 6200B
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/11/23 01:34 6200BMSA
376 H µg/L 50.0Toluene 100 04/14/23 01:50 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/11/23 01:34 6200BMSA
1390 H µg/L 50.01,2,4-Trimethylbenzene 100 04/14/23 01:50 6200BMSA
393 H µg/L 50.01,3,5-Trimethylbenzene 100 04/14/23 01:50 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/11/23 01:34 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/11/23 01:34 6200BMSA
4010 H µg/L 100m,p-Xylene 100 04/14/23 01:50 6200BMSA
1300 H µg/L 50.0o-Xylene 100 04/14/23 01:50 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 30 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-6
92838 Matrix:
3/28/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
5310 H µg/L 50.0Xylene (Total)100 04/14/23 01:50 6200B
Surrogate: 4-Bromofluorobenzene 109 Limits: 70-130%04/11/23 01:341 MSA V31865
Surrogate: Dibromofluoromethane 114 Limits: 70-130%04/11/23 01:341 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 118 Limits: 70-130%04/11/23 01:341 MSA V31865
Surrogate: Toluene-d8 69.6 *Limits: 70-130%04/11/23 01:341 MSA V31865
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%04/14/23 01:50100 MSA V32021
Surrogate: Dibromofluoromethane 98.4 Limits: 70-130%04/14/23 01:50100 MSA V32021
Surrogate: 1,2-Dichloroethane - d4 99.8 Limits: 70-130%04/14/23 01:50100 MSA V32021
Surrogate: Toluene-d8 104 Limits: 70-130%04/14/23 01:50100 MSA V32021
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 31 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-7
92839 Matrix:
3/28/2023 13:02
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 H µg/L 10.0Acetone 1 04/13/23 04:01 6200BTBL
0.520 H µg/L 0.500Benzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Bromobenzene 1 04/13/23 04:01 6200BTBL
<1.00 H µg/L 1.00Bromochloromethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Bromodichloromethane 1 04/13/23 04:01 6200BTBL
<5.00 H
µg/L 5.00Bromoform 1 04/13/23 04:01 6200BTBL
<1.00 H µg/L 1.00Bromomethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500n-Butylbenzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500sec-Butyl benzene 1 04/13/23 04:01 6200BTBL
<2.00 H µg/L 2.00tert-Butyl benzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Carbon Tetrachloride 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Chlorobenzene 1 04/13/23 04:01 6200BTBL
<0.500 H
µg/L 0.500Chlorodibromomethane 1 04/13/23 04:01 6200BTBL
<1.00 H µg/L 1.00Chloroethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Chloroform 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Chloromethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5002-Chlorotoluene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5004-Chlorotoluene 1 04/13/23 04:01 6200BTBL
<2.00 H µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2-Dibromoethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Dibromomethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2-Dichlorobenzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,3-Dichlorobenzene 1 04/13/23 04:01 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 32 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-7
92839 Matrix:
3/28/2023 13:02
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 H µg/L 0.5001,4-Dichlorobenzene 1 04/13/23 04:01 6200BTBL
<5.00 H µg/L 5.00Dichlorodifluoromethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,1-Dichloroethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2-Dichloroethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,1-Dichloroethene 1 04/13/23 04:01 6200BTBL
<0.500 H
µg/L 0.500cis-1,2-Dichloroethene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500trans-1,2-Dichloroethene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2-Dichloropropane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,3-Dichloropropane 1 04/13/23 04:01 6200BTBL
<2.00 H µg/L 2.002,2-Dichloropropane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,1-Dichloropropene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500cis-1,3-Dichloropropene 1 04/13/23 04:01 6200BTBL
<0.500 H
µg/L 0.500trans-1,3-Dichloropropene 1 04/13/23 04:01 6200BTBL
<200 H µg/L 200Ethanol 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Ethylbenzene 1 04/13/23 04:01 6200BTBL
<3.00 H µg/L 3.00Hexachlorobutadiene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Isopropylbenzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5004-Isopropyl toluene 1 04/13/23 04:01 6200BTBL
<1.00 H µg/L 1.002-Hexanone 1 04/13/23 04:01 6200BTBL
<5.00 H µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/13/23 04:01 6200BTBL
<2.00 H µg/L 2.00Methylene Chloride 1 04/13/23 04:01 6200BTBL
<1.00 H µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/13/23 04:01 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 33 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-7
92839 Matrix:
3/28/2023 13:02
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 H µg/L 1.004-Methyl-2-Pentanone 1 04/13/23 04:01 6200BTBL
<1.00 H µg/L 1.00Naphthalene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500n-Propylbenzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Styrene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/13/23 04:01 6200BTBL
<0.500 H
µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Tetrachloroethene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Toluene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2,3-Trichlorobenzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2,4-Trichlorobenzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,1,1-Trichloroethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,1,2-Trichloroethane 1 04/13/23 04:01 6200BTBL
<0.500 H
µg/L 0.500Trichloroethene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Trichlorofluoromethane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2,3-Trichloropropane 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,2,4-Trimethylbenzene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.5001,3,5-Trimethylbenzene 1 04/13/23 04:01 6200BTBL
<5.00 H µg/L 5.00Vinyl Acetate 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500Vinyl Chloride 1 04/13/23 04:01 6200BTBL
<1.00 H µg/L 1.00m,p-Xylene 1 04/13/23 04:01 6200BTBL
<0.500 H µg/L 0.500o-Xylene 1 04/13/23 04:01 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 34 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-7
92839 Matrix:
3/28/2023 13:02
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 H µg/L 0.500Xylene (Total)1 04/13/23 04:01 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/11/23 01:581 MSA V31865
Surrogate: Dibromofluoromethane 104 Limits: 70-130%04/11/23 01:581 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 105 Limits: 70-130%04/11/23 01:581 MSA V31865
Surrogate: Toluene-d8 101 Limits: 70-130%04/11/23 01:581 MSA V31865
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/13/23 04:011 TBL V31970
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%04/13/23 04:011 TBL V31970
Surrogate: 1,2-Dichloroethane - d4 99.6 Limits: 70-130%04/13/23 04:011 TBL V31970
Surrogate: Toluene-d8 102 Limits: 70-130%04/13/23 04:011 TBL V31970
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 35 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-8
92840 Matrix:
3/28/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 H µg/L 10.0Acetone 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Benzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Bromobenzene 1 04/13/23 04:26 6200BTBL
<1.00 H µg/L 1.00Bromochloromethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Bromodichloromethane 1 04/13/23 04:26 6200BTBL
<5.00 H
µg/L 5.00Bromoform 1 04/13/23 04:26 6200BTBL
<1.00 H µg/L 1.00Bromomethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500n-Butylbenzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500sec-Butyl benzene 1 04/13/23 04:26 6200BTBL
<2.00 H µg/L 2.00tert-Butyl benzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Carbon Tetrachloride 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Chlorobenzene 1 04/13/23 04:26 6200BTBL
<0.500 H
µg/L 0.500Chlorodibromomethane 1 04/13/23 04:26 6200BTBL
<1.00 H µg/L 1.00Chloroethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Chloroform 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Chloromethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5002-Chlorotoluene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5004-Chlorotoluene 1 04/13/23 04:26 6200BTBL
<2.00 H µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2-Dibromoethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Dibromomethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2-Dichlorobenzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,3-Dichlorobenzene 1 04/13/23 04:26 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 36 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-8
92840 Matrix:
3/28/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 H µg/L 0.5001,4-Dichlorobenzene 1 04/13/23 04:26 6200BTBL
<5.00 H µg/L 5.00Dichlorodifluoromethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,1-Dichloroethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2-Dichloroethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,1-Dichloroethene 1 04/13/23 04:26 6200BTBL
<0.500 H
µg/L 0.500cis-1,2-Dichloroethene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500trans-1,2-Dichloroethene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2-Dichloropropane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,3-Dichloropropane 1 04/13/23 04:26 6200BTBL
<2.00 H µg/L 2.002,2-Dichloropropane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,1-Dichloropropene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500cis-1,3-Dichloropropene 1 04/13/23 04:26 6200BTBL
<0.500 H
µg/L 0.500trans-1,3-Dichloropropene 1 04/13/23 04:26 6200BTBL
<200 H µg/L 200Ethanol 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Ethylbenzene 1 04/13/23 04:26 6200BTBL
<3.00 H µg/L 3.00Hexachlorobutadiene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Isopropylbenzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5004-Isopropyl toluene 1 04/13/23 04:26 6200BTBL
<1.00 H µg/L 1.002-Hexanone 1 04/13/23 04:26 6200BTBL
<5.00 H µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/13/23 04:26 6200BTBL
<2.00 H µg/L 2.00Methylene Chloride 1 04/13/23 04:26 6200BTBL
<1.00 H µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/13/23 04:26 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 37 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-8
92840 Matrix:
3/28/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 H µg/L 1.004-Methyl-2-Pentanone 1 04/13/23 04:26 6200BTBL
<1.00 H µg/L 1.00Naphthalene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500n-Propylbenzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Styrene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/13/23 04:26 6200BTBL
<0.500 H
µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Tetrachloroethene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Toluene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2,3-Trichlorobenzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2,4-Trichlorobenzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,1,1-Trichloroethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,1,2-Trichloroethane 1 04/13/23 04:26 6200BTBL
<0.500 H
µg/L 0.500Trichloroethene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Trichlorofluoromethane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2,3-Trichloropropane 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,2,4-Trimethylbenzene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.5001,3,5-Trimethylbenzene 1 04/13/23 04:26 6200BTBL
<5.00 H µg/L 5.00Vinyl Acetate 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500Vinyl Chloride 1 04/13/23 04:26 6200BTBL
<1.00 H µg/L 1.00m,p-Xylene 1 04/13/23 04:26 6200BTBL
<0.500 H µg/L 0.500o-Xylene 1 04/13/23 04:26 6200BTBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 38 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-8
92840 Matrix:
3/28/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 H µg/L 0.500Xylene (Total)1 04/13/23 04:26 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/11/23 02:231 MSA V31865
Surrogate: Dibromofluoromethane 101 Limits: 70-130%04/11/23 02:231 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%04/11/23 02:231 MSA V31865
Surrogate: Toluene-d8 100 Limits: 70-130%04/11/23 02:231 MSA V31865
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/13/23 04:261 TBL V31970
Surrogate: Dibromofluoromethane 102 Limits: 70-130%04/13/23 04:261 TBL V31970
Surrogate: 1,2-Dichloroethane - d4 100 Limits: 70-130%04/13/23 04:261 TBL V31970
Surrogate: Toluene-d8 101 Limits: 70-130%04/13/23 04:261 TBL V31970
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 39 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-10
92841 Matrix:
3/28/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/11/23 02:48 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/11/23 02:48 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/11/23 02:48 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/11/23 02:48 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/11/23 02:48 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/11/23 02:48 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/11/23 02:48 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 40 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-10
92841 Matrix:
3/28/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/11/23 02:48 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/11/23 02:48 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/11/23 02:48 6200BMSA
<200 µg/L 200Ethanol 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/11/23 02:48 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/11/23 02:48 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/11/23 02:48 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/11/23 02:48 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/11/23 02:48 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/11/23 02:48 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 41 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-10
92841 Matrix:
3/28/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/11/23 02:48 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/11/23 02:48 6200BMSA
1.67 µg/L 0.500Toluene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/11/23 02:48 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/11/23 02:48 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/11/23 02:48 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/11/23 02:48 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 42 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:MW-10
92841 Matrix:
3/28/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/11/23 02:48 6200B
Surrogate: 4-Bromofluorobenzene 106 Limits: 70-130%04/11/23 02:481 MSA V31865
Surrogate: Dibromofluoromethane 102 Limits: 70-130%04/11/23 02:481 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 100 Limits: 70-130%04/11/23 02:481 MSA V31865
Surrogate: Toluene-d8 103 Limits: 70-130%04/11/23 02:481 MSA V31865
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 43 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:TB
92842 Matrix:
3/28/2023 0:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/10/23 21:51 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/10/23 21:51 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/10/23 21:51 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/10/23 21:51 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/10/23 21:51 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/10/23 21:51 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/10/23 21:51 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 44 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:TB
92842 Matrix:
3/28/2023 0:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/10/23 21:51 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/10/23 21:51 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/10/23 21:51 6200BMSA
<200 µg/L 200Ethanol 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/10/23 21:51 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/10/23 21:51 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/10/23 21:51 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/10/23 21:51 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/10/23 21:51 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/10/23 21:51 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 45 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:TB
92842 Matrix:
3/28/2023 0:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/10/23 21:51 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/10/23 21:51 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/10/23 21:51 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/10/23 21:51 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/10/23 21:51 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 46 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:TB
92842 Matrix:
3/28/2023 0:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/10/23 21:51 6200B
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%04/10/23 21:511 MSA V31865
Surrogate: Dibromofluoromethane 100 Limits: 70-130%04/10/23 21:511 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 99.8 Limits: 70-130%04/10/23 21:511 MSA V31865
Surrogate: Toluene-d8 103 Limits: 70-130%04/10/23 21:511 MSA V31865
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 47 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:FB
92843 Matrix:
3/28/2023 10:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/10/23 22:16 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/10/23 22:16 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/10/23 22:16 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/10/23 22:16 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/10/23 22:16 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/10/23 22:16 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/10/23 22:16 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 48 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:FB
92843 Matrix:
3/28/2023 10:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/10/23 22:16 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/10/23 22:16 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/10/23 22:16 6200BMSA
<200 µg/L 200Ethanol 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/10/23 22:16 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/10/23 22:16 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/10/23 22:16 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/10/23 22:16 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/10/23 22:16 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/10/23 22:16 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 49 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:FB
92843 Matrix:
3/28/2023 10:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/10/23 22:16 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/10/23 22:16 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/10/23 22:16 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/10/23 22:16 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/10/23 22:16 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 50 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:FB
92843 Matrix:
3/28/2023 10:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/10/23 22:16 6200B
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%04/10/23 22:161 MSA V31865
Surrogate: Dibromofluoromethane 100 Limits: 70-130%04/10/23 22:161 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 100 Limits: 70-130%04/10/23 22:161 MSA V31865
Surrogate: Toluene-d8 103 Limits: 70-130%04/10/23 22:161 MSA V31865
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 51 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:WSW-16
92844 Matrix:
3/28/2023 15:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/11/23 03:13 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/11/23 03:13 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/11/23 03:13 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/11/23 03:13 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/11/23 03:13 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/11/23 03:13 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/11/23 03:13 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 52 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:WSW-16
92844 Matrix:
3/28/2023 15:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/11/23 03:13 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/11/23 03:13 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/11/23 03:13 6200BMSA
<200 µg/L 200Ethanol 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/11/23 03:13 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/11/23 03:13 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/11/23 03:13 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/11/23 03:13 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/11/23 03:13 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/11/23 03:13 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 53 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:WSW-16
92844 Matrix:
3/28/2023 15:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/11/23 03:13 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/11/23 03:13 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/11/23 03:13 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/11/23 03:13 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/11/23 03:13 6200BMSA
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 54 of 80
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-094-0011
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
David Vail
Cary
23-0307-6B Received : 04/04/2023
Virgina's Gas Station
Report Date : 04/17/2023
Sample ID :
Lab No :
Sampled:WSW-16
92844 Matrix:
3/28/2023 15:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/11/23 03:13 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/11/23 03:131 MSA V31865
Surrogate: Dibromofluoromethane 102 Limits: 70-130%04/11/23 03:131 MSA V31865
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%04/11/23 03:131 MSA V31865
Surrogate: Toluene-d8 102 Limits: 70-130%04/11/23 03:131 MSA V31865
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Method Quantitation LimitMQLBeyond holding timeH
Page 55 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31866QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31860
Associated Lab Samples: 92833, 92834, 92835
LRB-V31860 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/10/23 22:2710.0< 10.0µg/LAcetone
04/10/23 22:270.500< 0.500µg/LBenzene
04/10/23 22:270.500< 0.500µg/LBromobenzene
04/10/23 22:271.00< 1.00µg/LBromochloromethane
04/10/23 22:270.500< 0.500µg/LBromodichloromethane
04/10/23 22:275.00< 5.00µg/LBromoform
04/10/23 22:271.00< 1.00µg/LBromomethane
04/10/23 22:270.500< 0.500µg/Ln-Butylbenzene
04/10/23 22:270.500< 0.500µg/Lsec-Butyl benzene
04/10/23 22:272.00< 2.00µg/Ltert-Butyl benzene
04/10/23 22:270.500< 0.500µg/LCarbon Tetrachloride
04/10/23 22:270.500< 0.500µg/LChlorobenzene
04/10/23 22:270.500< 0.500µg/LChlorodibromomethane
04/10/23 22:271.00< 1.00µg/LChloroethane
04/10/23 22:270.500< 0.500µg/LChloroform
04/10/23 22:270.500< 0.500µg/LChloromethane
04/10/23 22:270.500< 0.500µg/L2-Chlorotoluene
04/10/23 22:270.500< 0.500µg/L4-Chlorotoluene
04/10/23 22:272.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
04/10/23 22:270.500< 0.500µg/L1,2-Dibromoethane
04/10/23 22:270.500< 0.500µg/LDibromomethane
04/10/23 22:270.500< 0.500µg/L1,2-Dichlorobenzene
04/10/23 22:270.500< 0.500µg/L1,3-Dichlorobenzene
04/10/23 22:270.500< 0.500µg/L1,4-Dichlorobenzene
04/10/23 22:275.00< 5.00µg/LDichlorodifluoromethane
04/10/23 22:270.500< 0.500µg/L1,1-Dichloroethane
04/10/23 22:270.500< 0.500µg/L1,2-Dichloroethane
Page 1 of 22Date:04/17/2023 12:41 PM
Page 56 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31866QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31860
Associated Lab Samples: 92833, 92834, 92835
LRB-V31860 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/10/23 22:270.500< 0.500µg/L1,1-Dichloroethene
04/10/23 22:270.500< 0.500µg/Lcis-1,2-Dichloroethene
04/10/23 22:270.500< 0.500µg/Ltrans-1,2-Dichloroethene
04/10/23 22:270.500< 0.500µg/L1,2-Dichloropropane
04/10/23 22:270.500< 0.500µg/L1,3-Dichloropropane
04/10/23 22:272.00< 2.00µg/L2,2-Dichloropropane
04/10/23 22:270.500< 0.500µg/L1,1-Dichloropropene
04/10/23 22:270.500< 0.500µg/Lcis-1,3-Dichloropropene
04/10/23 22:270.500< 0.500µg/Ltrans-1,3-Dichloropropene
04/10/23 22:27200< 200µg/LEthanol
04/10/23 22:270.500< 0.500µg/LEthylbenzene
04/10/23 22:273.00< 3.00µg/LHexachlorobutadiene
04/10/23 22:270.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
04/10/23 22:270.500< 0.500µg/LIsopropylbenzene
04/10/23 22:270.500< 0.500µg/L4-Isopropyl toluene
04/10/23 22:271.00< 1.00µg/L2-Hexanone
04/10/23 22:275.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
04/10/23 22:272.00< 2.00µg/LMethylene Chloride
04/10/23 22:271.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
04/10/23 22:271.00< 1.00µg/L4-Methyl-2-Pentanone
04/10/23 22:271.00< 1.00µg/LNaphthalene
04/10/23 22:270.500< 0.500µg/Ln-Propylbenzene
04/10/23 22:270.500< 0.500µg/LStyrene
04/10/23 22:270.500< 0.500µg/L1,1,1,2-Tetrachloroethane
04/10/23 22:270.500< 0.500µg/L1,1,2,2-Tetrachloroethane
04/10/23 22:270.500< 0.500µg/LTetrachloroethene
04/10/23 22:270.500< 0.500µg/LToluene
Page 2 of 22Date:04/17/2023 12:41 PM
Page 57 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31866QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31860
Associated Lab Samples: 92833, 92834, 92835
LRB-V31860 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/10/23 22:270.500< 0.500µg/L1,2,3-Trichlorobenzene
04/10/23 22:270.500< 0.500µg/L1,2,4-Trichlorobenzene
04/10/23 22:270.500< 0.500µg/L1,1,1-Trichloroethane
04/10/23 22:270.500< 0.500µg/L1,1,2-Trichloroethane
04/10/23 22:270.500< 0.500µg/LTrichloroethene
04/10/23 22:270.500< 0.500µg/LTrichlorofluoromethane
04/10/23 22:270.500< 0.500µg/L1,2,3-Trichloropropane
04/10/23 22:270.500< 0.500µg/L1,2,4-Trimethylbenzene
04/10/23 22:270.500< 0.500µg/L1,3,5-Trimethylbenzene
04/10/23 22:275.00< 5.00µg/LVinyl Acetate
04/10/23 22:270.500< 0.500µg/LVinyl Chloride
04/10/23 22:271.00< 1.00µg/Lm,p-Xylene
04/10/23 22:270.500< 0.500µg/Lo-Xylene
04/10/23 22:274-Bromofluorobenzene (S)103 70-130
04/10/23 22:27Dibromofluoromethane (S)101 70-130
04/10/23 22:271,2-Dichloroethane - d4 (S)99.2 70-130
04/10/23 22:27Toluene-d8 (S)100 70-130
LCS-V31860 LCSD-V31860Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
30.6 76.571.228.540.0µg/LAcetone 40-160 7.1 20.0
20.5 10399.519.920.0µg/LBenzene 70-130 2.9 20.0
21.2 10610320.520.0µg/LBromobenzene 70-130 3.3 20.0
21.3 10710020.020.0µg/LBromochloromethane 70-130 6.2 20.0
20.2 10198.519.720.0µg/LBromodichloromethane 70-130 2.5 20.0
Page 3 of 22Date:04/17/2023 12:41 PM
Page 58 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31866QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31860
LCS-V31860 LCSD-V31860Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.0 10599.519.920.0µg/LBromoform 70-130 5.3 20.0
21.9 11010520.920.0µg/LBromomethane 60-140 4.6 20.0
21.1 10698.519.720.0µg/Ln-Butylbenzene 70-130 6.8 20.0
20.4 10296.019.220.0µg/Lsec-Butyl benzene 70-130 6.0 20.0
20.6 10396.019.220.0µg/Ltert-Butyl benzene 70-130 7.0 20.0
20.6 10397.019.420.0µg/LCarbon Tetrachloride 70-130 6.0 20.0
21.2 10610220.420.0µg/LChlorobenzene 70-130 3.8 20.0
21.0 10510120.120.0µg/LChlorodibromomethane 70-130 4.3 20.0
20.7 10498.519.720.0µg/LChloroethane 60-140 4.9 20.0
20.7 10410020.020.0µg/LChloroform 70-130 3.4 20.0
21.1 10698.019.620.0µg/LChloromethane 60-140 7.3 20.0
20.3 10298.519.720.0µg/L2-Chlorotoluene 70-130 3.0 20.0
20.5 10398.519.720.0µg/L4-Chlorotoluene 70-130 3.9 20.0
23.5 11810521.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 11.2 20.0
20.7 10497.019.420.0µg/L1,2-Dibromoethane 70-130 6.4 20.0
20.7 10496.519.320.0µg/LDibromomethane 70-130 7.0 20.0
21.1 10610220.420.0µg/L1,2-Dichlorobenzene 70-130 3.3 20.0
20.4 10210120.220.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0
20.6 10399.019.820.0µg/L1,4-Dichlorobenzene 70-130 3.9 20.0
19.0 95.089.017.820.0µg/LDichlorodifluoromethane 60-140 6.5 20.0
21.0 10510220.320.0µg/L1,1-Dichloroethane 70-130 3.3 20.0
19.8 99.096.019.220.0µg/L1,2-Dichloroethane 70-130 3.0 20.0
21.0 10510020.020.0µg/L1,1-Dichloroethene 70-130 4.8 20.0
20.3 10299.019.820.0µg/Lcis-1,2-Dichloroethene 70-130 2.4 20.0
20.4 10293.518.720.0µg/Ltrans-1,2-Dichloroethene 70-130 8.6 20.0
20.4 10298.519.720.0µg/L1,2-Dichloropropane 70-130 3.4 20.0
Page 4 of 22Date:04/17/2023 12:41 PM
Page 59 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31866QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31860
LCS-V31860 LCSD-V31860Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.6 10399.519.920.0µg/L1,3-Dichloropropane 70-130 3.4 20.0
21.6 10896.019.220.0µg/L2,2-Dichloropropane 70-130 11.7 20.0
21.9 11099.019.820.0µg/L1,1-Dichloropropene 70-130 10.0 20.0
20.3 10299.519.920.0µg/Lcis-1,3-Dichloropropene 70-130 1.9 20.0
20.9 10598.019.620.0µg/Ltrans-1,3-Dichloropropene 70-130 6.4 20.0
484 96.886.8434500µg/LEthanol 60-140 10.8 20.0
20.2 10197.019.420.0µg/LEthylbenzene 70-130 4.0 20.0
21.3 10797.019.420.0µg/LHexachlorobutadiene 70-130 9.3 20.0
20.0 10096.019.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 4.0 20.0
20.8 10499.519.920.0µg/LIsopropylbenzene 70-130 4.4 20.0
21.3 10710220.420.0µg/L4-Isopropyl toluene 70-130 4.3 20.0
21.0 10590.518.120.0µg/L2-Hexanone 60-140 14.8 20.0
17.8 89.078.515.720.0µg/LMethyl Ethyl Ketone (MEK)60-140 12.5 20.0
20.1 10196.519.320.0µg/LMethylene Chloride 70-130 4.0 20.0
20.7 10410020.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.4 20.0
20.2 10197.019.420.0µg/L4-Methyl-2-Pentanone 60-140 4.0 20.0
21.4 10710120.220.0µg/LNaphthalene 70-130 5.7 20.0
20.7 10497.519.520.0µg/Ln-Propylbenzene 70-130 5.9 20.0
20.4 10210120.120.0µg/LStyrene 70-130 1.4 20.0
20.7 10410220.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.4 20.0
20.7 10499.019.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.4 20.0
20.6 10397.019.420.0µg/LTetrachloroethene 70-130 6.0 20.0
20.4 10297.519.520.0µg/LToluene 70-130 4.5 20.0
22.7 11410821.520.0µg/L1,2,3-Trichlorobenzene 70-130 5.4 20.0
23.3 11710721.420.0µg/L1,2,4-Trichlorobenzene 70-130 8.5 20.0
21.1 10610220.320.0µg/L1,1,1-Trichloroethane 70-130 3.8 20.0
Page 5 of 22Date:04/17/2023 12:41 PM
Page 60 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31866QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31860
LCS-V31860 LCSD-V31860Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.5 97.596.019.220.0µg/L1,1,2-Trichloroethane 70-130 1.5 20.0
20.8 10497.019.420.0µg/LTrichloroethene 70-130 6.9 20.0
20.2 10194.518.920.0µg/LTrichlorofluoromethane 60-140 6.6 20.0
21.4 10790.518.120.0µg/L1,2,3-Trichloropropane 70-130 16.7 20.0
20.6 10399.019.820.0µg/L1,2,4-Trimethylbenzene 70-130 3.9 20.0
21.0 10510220.320.0µg/L1,3,5-Trimethylbenzene 70-130 3.3 20.0
20.5 10310220.320.0µg/LVinyl Acetate 60-140 0.9 20.0
20.6 10397.519.520.0µg/LVinyl Chloride 60-140 5.4 20.0
41.7 10499.239.740.0µg/Lm,p-Xylene 70-130 4.9 20.0
20.3 10298.019.620.0µg/Lo-Xylene 70-130 3.5 20.0
99.499.04-Bromofluorobenzene (S)70-130
10299.2Dibromofluoromethane (S)70-130
1021001,2-Dichloroethane - d4 (S)70-130
101101Toluene-d8 (S)70-130
Page 6 of 22Date:04/17/2023 12:41 PM
Page 61 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31865QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31864
Associated Lab Samples: 92836, 92837, 92838, 92841, 92842, 92843, 92844
LRB-V31864 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/10/23 21:2710.0< 10.0µg/LAcetone
04/10/23 21:270.500< 0.500µg/LBenzene
04/10/23 21:270.500< 0.500µg/LBromobenzene
04/10/23 21:271.00< 1.00µg/LBromochloromethane
04/10/23 21:270.500< 0.500µg/LBromodichloromethane
04/10/23 21:275.00< 5.00µg/LBromoform
04/10/23 21:271.00< 1.00µg/LBromomethane
04/10/23 21:270.500< 0.500µg/Ln-Butylbenzene
04/10/23 21:270.500< 0.500µg/Lsec-Butyl benzene
04/10/23 21:272.00< 2.00µg/Ltert-Butyl benzene
04/10/23 21:270.500< 0.500µg/LCarbon Tetrachloride
04/10/23 21:270.500< 0.500µg/LChlorobenzene
04/10/23 21:270.500< 0.500µg/LChlorodibromomethane
04/10/23 21:271.00< 1.00µg/LChloroethane
04/10/23 21:270.500< 0.500µg/LChloroform
04/10/23 21:270.500< 0.500µg/LChloromethane
04/10/23 21:270.500< 0.500µg/L2-Chlorotoluene
04/10/23 21:270.500< 0.500µg/L4-Chlorotoluene
04/10/23 21:272.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
04/10/23 21:270.500< 0.500µg/L1,2-Dibromoethane
04/10/23 21:270.500< 0.500µg/LDibromomethane
04/10/23 21:270.500< 0.500µg/L1,2-Dichlorobenzene
04/10/23 21:270.500< 0.500µg/L1,3-Dichlorobenzene
04/10/23 21:270.500< 0.500µg/L1,4-Dichlorobenzene
04/10/23 21:275.00< 5.00µg/LDichlorodifluoromethane
04/10/23 21:270.500< 0.500µg/L1,1-Dichloroethane
04/10/23 21:270.500< 0.500µg/L1,2-Dichloroethane
Page 7 of 22Date:04/17/2023 12:41 PM
Page 62 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31865QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31864
Associated Lab Samples: 92836, 92837, 92838, 92841, 92842, 92843, 92844
LRB-V31864 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/10/23 21:270.500< 0.500µg/L1,1-Dichloroethene
04/10/23 21:270.500< 0.500µg/Lcis-1,2-Dichloroethene
04/10/23 21:270.500< 0.500µg/Ltrans-1,2-Dichloroethene
04/10/23 21:270.500< 0.500µg/L1,2-Dichloropropane
04/10/23 21:270.500< 0.500µg/L1,3-Dichloropropane
04/10/23 21:272.00< 2.00µg/L2,2-Dichloropropane
04/10/23 21:270.500< 0.500µg/L1,1-Dichloropropene
04/10/23 21:270.500< 0.500µg/Lcis-1,3-Dichloropropene
04/10/23 21:270.500< 0.500µg/Ltrans-1,3-Dichloropropene
04/10/23 21:27200< 200µg/LEthanol
04/10/23 21:270.500< 0.500µg/LEthylbenzene
04/10/23 21:273.00< 3.00µg/LHexachlorobutadiene
04/10/23 21:270.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
04/10/23 21:270.500< 0.500µg/LIsopropylbenzene
04/10/23 21:270.500< 0.500µg/L4-Isopropyl toluene
04/10/23 21:271.00< 1.00µg/L2-Hexanone
04/10/23 21:275.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
04/10/23 21:272.00< 2.00µg/LMethylene Chloride
04/10/23 21:271.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
04/10/23 21:271.00< 1.00µg/L4-Methyl-2-Pentanone
04/10/23 21:271.00< 1.00µg/LNaphthalene
04/10/23 21:270.500< 0.500µg/Ln-Propylbenzene
04/10/23 21:270.500< 0.500µg/LStyrene
04/10/23 21:270.500< 0.500µg/L1,1,1,2-Tetrachloroethane
04/10/23 21:270.500< 0.500µg/L1,1,2,2-Tetrachloroethane
04/10/23 21:270.500< 0.500µg/LTetrachloroethene
04/10/23 21:270.500< 0.500µg/LToluene
Page 8 of 22Date:04/17/2023 12:41 PM
Page 63 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31865QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31864
Associated Lab Samples: 92836, 92837, 92838, 92841, 92842, 92843, 92844
LRB-V31864 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/10/23 21:270.500< 0.500µg/L1,2,3-Trichlorobenzene
04/10/23 21:270.500< 0.500µg/L1,2,4-Trichlorobenzene
04/10/23 21:270.500< 0.500µg/L1,1,1-Trichloroethane
04/10/23 21:270.500< 0.500µg/L1,1,2-Trichloroethane
04/10/23 21:270.500< 0.500µg/LTrichloroethene
04/10/23 21:270.500< 0.500µg/LTrichlorofluoromethane
04/10/23 21:270.500< 0.500µg/L1,2,3-Trichloropropane
04/10/23 21:270.500< 0.500µg/L1,2,4-Trimethylbenzene
04/10/23 21:270.500< 0.500µg/L1,3,5-Trimethylbenzene
04/10/23 21:275.00< 5.00µg/LVinyl Acetate
04/10/23 21:270.500< 0.500µg/LVinyl Chloride
04/10/23 21:271.00< 1.00µg/Lm,p-Xylene
04/10/23 21:270.500< 0.500µg/Lo-Xylene
04/10/23 21:274-Bromofluorobenzene (S)103 70-130
04/10/23 21:27Dibromofluoromethane (S)103 70-130
04/10/23 21:271,2-Dichloroethane - d4 (S)106 70-130
04/10/23 21:27Toluene-d8 (S)98.0 70-130
LCS-V31864 LCSD-V31864Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
37.4 93.510341.140.0µg/LAcetone 40-160 9.4 20.0
20.8 10410220.320.0µg/LBenzene 70-130 2.4 20.0
20.5 10310320.520.0µg/LBromobenzene 70-130 0.0 20.0
20.2 10196.019.220.0µg/LBromochloromethane 70-130 5.0 20.0
20.9 10510020.020.0µg/LBromodichloromethane 70-130 4.4 20.0
Page 9 of 22Date:04/17/2023 12:41 PM
Page 64 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31865QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31864
LCS-V31864 LCSD-V31864Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.4 97.096.519.320.0µg/LBromoform 70-130 0.5 20.0
21.8 10910921.720.0µg/LBromomethane 60-140 0.4 20.0
20.4 10210420.720.0µg/Ln-Butylbenzene 70-130 1.4 20.0
19.7 98.599.519.920.0µg/Lsec-Butyl benzene 70-130 1.0 20.0
19.7 98.510020.020.0µg/Ltert-Butyl benzene 70-130 1.5 20.0
20.5 10310120.220.0µg/LCarbon Tetrachloride 70-130 1.4 20.0
19.6 98.099.019.820.0µg/LChlorobenzene 70-130 1.0 20.0
20.3 10297.519.520.0µg/LChlorodibromomethane 70-130 4.0 20.0
21.1 10610320.620.0µg/LChloroethane 60-140 2.3 20.0
20.8 10410220.320.0µg/LChloroform 70-130 2.4 20.0
19.7 98.510120.220.0µg/LChloromethane 60-140 2.5 20.0
20.0 10010420.820.0µg/L2-Chlorotoluene 70-130 3.9 20.0
20.1 10110120.220.0µg/L4-Chlorotoluene 70-130 0.4 20.0
22.1 11198.519.720.0µg/L1,2-Dibromo-3-Chloropropane 70-130 11.4 20.0
20.6 10397.519.520.0µg/L1,2-Dibromoethane 70-130 5.4 20.0
21.1 10699.019.820.0µg/LDibromomethane 70-130 6.3 20.0
20.5 10310220.320.0µg/L1,2-Dichlorobenzene 70-130 0.9 20.0
20.4 10210120.220.0µg/L1,3-Dichlorobenzene 70-130 0.9 20.0
19.8 99.099.519.920.0µg/L1,4-Dichlorobenzene 70-130 0.5 20.0
20.0 10098.019.620.0µg/LDichlorodifluoromethane 60-140 2.0 20.0
20.7 10410320.620.0µg/L1,1-Dichloroethane 70-130 0.4 20.0
20.2 10196.519.320.0µg/L1,2-Dichloroethane 70-130 4.5 20.0
20.5 10310420.720.0µg/L1,1-Dichloroethene 70-130 0.9 20.0
20.4 10210120.220.0µg/Lcis-1,2-Dichloroethene 70-130 0.9 20.0
20.7 10499.519.920.0µg/Ltrans-1,2-Dichloroethene 70-130 3.9 20.0
20.9 10510120.120.0µg/L1,2-Dichloropropane 70-130 3.9 20.0
Page 10 of 22Date:04/17/2023 12:41 PM
Page 65 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31865QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31864
LCS-V31864 LCSD-V31864Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.5 10399.019.820.0µg/L1,3-Dichloropropane 70-130 3.4 20.0
19.5 97.598.519.720.0µg/L2,2-Dichloropropane 70-130 1.0 20.0
21.5 10810621.220.0µg/L1,1-Dichloropropene 70-130 1.4 20.0
21.1 10610020.020.0µg/Lcis-1,3-Dichloropropene 70-130 5.3 20.0
21.5 10810020.020.0µg/Ltrans-1,3-Dichloropropene 70-130 7.2 20.0
522 104101507500µg/LEthanol 60-140 2.9 20.0
19.6 98.096.019.220.0µg/LEthylbenzene 70-130 2.0 20.0
21.8 10910821.520.0µg/LHexachlorobutadiene 70-130 1.3 20.0
21.0 10510120.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.8 20.0
20.6 10310521.020.0µg/LIsopropylbenzene 70-130 1.9 20.0
20.3 10210420.720.0µg/L4-Isopropyl toluene 70-130 1.9 20.0
21.1 10696.019.220.0µg/L2-Hexanone 60-140 9.4 20.0
18.2 91.080.516.120.0µg/LMethyl Ethyl Ketone (MEK)60-140 12.2 20.0
20.4 10296.019.220.0µg/LMethylene Chloride 70-130 6.0 20.0
21.3 10710020.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.2 20.0
22.5 11310120.120.0µg/L4-Methyl-2-Pentanone 60-140 11.2 20.0
21.3 10799.519.920.0µg/LNaphthalene 70-130 6.7 20.0
19.9 99.510220.420.0µg/Ln-Propylbenzene 70-130 2.4 20.0
19.7 98.598.019.620.0µg/LStyrene 70-130 0.5 20.0
20.1 10110220.320.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0
21.5 10810120.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 6.2 20.0
20.8 10410320.620.0µg/LTetrachloroethene 70-130 0.9 20.0
20.4 10210020.020.0µg/LToluene 70-130 1.9 20.0
22.7 11411322.520.0µg/L1,2,3-Trichlorobenzene 70-130 0.8 20.0
22.6 11311021.920.0µg/L1,2,4-Trichlorobenzene 70-130 3.1 20.0
20.5 10310020.020.0µg/L1,1,1-Trichloroethane 70-130 2.4 20.0
Page 11 of 22Date:04/17/2023 12:41 PM
Page 66 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31865QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31864
LCS-V31864 LCSD-V31864Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.6 10899.519.920.0µg/L1,1,2-Trichloroethane 70-130 8.1 20.0
20.3 10299.519.920.0µg/LTrichloroethene 70-130 1.9 20.0
19.8 99.010020.020.0µg/LTrichlorofluoromethane 60-140 1.0 20.0
20.4 10210220.420.0µg/L1,2,3-Trichloropropane 70-130 0.0 20.0
20.1 10110220.320.0µg/L1,2,4-Trimethylbenzene 70-130 0.9 20.0
20.0 10010320.520.0µg/L1,3,5-Trimethylbenzene 70-130 2.4 20.0
19.1 95.591.018.220.0µg/LVinyl Acetate 60-140 4.8 20.0
20.6 10310120.220.0µg/LVinyl Chloride 60-140 1.9 20.0
40.3 10110341.140.0µg/Lm,p-Xylene 70-130 1.9 20.0
19.1 95.598.019.620.0µg/Lo-Xylene 70-130 2.5 20.0
1001004-Bromofluorobenzene (S)70-130
102101Dibromofluoromethane (S)70-130
1061011,2-Dichloroethane - d4 (S)70-130
102101Toluene-d8 (S)70-130
Page 12 of 22Date:04/17/2023 12:41 PM
Page 67 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31920QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31919
Associated Lab Samples: 92834, 92835
LRB-V31919 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/12/23 01:460.500< 0.500µg/LBenzene
04/12/23 01:460.500< 0.500µg/LEthylbenzene
04/12/23 01:461.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
04/12/23 01:460.500< 0.500µg/LToluene
04/12/23 01:460.500< 0.500µg/L1,2,4-Trimethylbenzene
04/12/23 01:461.00< 1.00µg/Lm,p-Xylene
04/12/23 01:460.500< 0.500µg/Lo-Xylene
04/12/23 01:464-Bromofluorobenzene (S)103 70-130
04/12/23 01:46Dibromofluoromethane (S)100 70-130
04/12/23 01:461,2-Dichloroethane - d4 (S)93.6 70-130
04/12/23 01:46Toluene-d8 (S)101 70-130
LCS-V31919 LCSD-V31919Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.6 10310220.420.0µg/LBenzene 70-130 0.9 20.0
20.1 10198.019.620.0µg/LEthylbenzene 70-130 2.5 20.0
20.6 10399.019.820.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.9 20.0
20.0 10010020.020.0µg/LToluene 70-130 0.0 20.0
20.6 10310220.320.0µg/L1,2,4-Trimethylbenzene 70-130 1.4 20.0
41.2 10310140.440.0µg/Lm,p-Xylene 70-130 1.9 20.0
20.1 10199.019.820.0µg/Lo-Xylene 70-130 1.5 20.0
10199.04-Bromofluorobenzene (S)70-130
97.8101Dibromofluoromethane (S)70-130
98.097.81,2-Dichloroethane - d4 (S)70-130
Page 13 of 22Date:04/17/2023 12:41 PM
Page 68 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31920QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31919
LCS-V31919 LCSD-V31919Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
100101Toluene-d8 (S)70-130
Page 14 of 22Date:04/17/2023 12:41 PM
Page 69 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31969
Associated Lab Samples: 92839, 92840
LRB-V31969 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/23 03:1210.0< 10.0µg/LAcetone
04/13/23 03:120.500< 0.500µg/LBenzene
04/13/23 03:120.500< 0.500µg/LBromobenzene
04/13/23 03:121.00< 1.00µg/LBromochloromethane
04/13/23 03:120.500< 0.500µg/LBromodichloromethane
04/13/23 03:125.00< 5.00µg/LBromoform
04/13/23 03:121.00< 1.00µg/LBromomethane
04/13/23 03:120.500< 0.500µg/Ln-Butylbenzene
04/13/23 03:120.500< 0.500µg/Lsec-Butyl benzene
04/13/23 03:122.00< 2.00µg/Ltert-Butyl benzene
04/13/23 03:120.500< 0.500µg/LCarbon Tetrachloride
04/13/23 03:120.500< 0.500µg/LChlorobenzene
04/13/23 03:120.500< 0.500µg/LChlorodibromomethane
04/13/23 03:121.00< 1.00µg/LChloroethane
04/13/23 03:120.500< 0.500µg/LChloroform
04/13/23 03:120.500< 0.500µg/LChloromethane
04/13/23 03:120.500< 0.500µg/L2-Chlorotoluene
04/13/23 03:120.500< 0.500µg/L4-Chlorotoluene
04/13/23 03:122.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
04/13/23 03:120.500< 0.500µg/L1,2-Dibromoethane
04/13/23 03:120.500< 0.500µg/LDibromomethane
04/13/23 03:120.500< 0.500µg/L1,2-Dichlorobenzene
04/13/23 03:120.500< 0.500µg/L1,3-Dichlorobenzene
04/13/23 03:120.500< 0.500µg/L1,4-Dichlorobenzene
04/13/23 03:125.00< 5.00µg/LDichlorodifluoromethane
04/13/23 03:120.500< 0.500µg/L1,1-Dichloroethane
04/13/23 03:120.500< 0.500µg/L1,2-Dichloroethane
Page 15 of 22Date:04/17/2023 12:41 PM
Page 70 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31969
Associated Lab Samples: 92839, 92840
LRB-V31969 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/23 03:120.500< 0.500µg/L1,1-Dichloroethene
04/13/23 03:120.500< 0.500µg/Lcis-1,2-Dichloroethene
04/13/23 03:120.500< 0.500µg/Ltrans-1,2-Dichloroethene
04/13/23 03:120.500< 0.500µg/L1,2-Dichloropropane
04/13/23 03:120.500< 0.500µg/L1,3-Dichloropropane
04/13/23 03:122.00< 2.00µg/L2,2-Dichloropropane
04/13/23 03:120.500< 0.500µg/L1,1-Dichloropropene
04/13/23 03:120.500< 0.500µg/Lcis-1,3-Dichloropropene
04/13/23 03:120.500< 0.500µg/Ltrans-1,3-Dichloropropene
04/13/23 03:12200< 200µg/LEthanol
04/13/23 03:120.500< 0.500µg/LEthylbenzene
04/13/23 03:123.00< 3.00µg/LHexachlorobutadiene
04/13/23 03:120.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
04/13/23 03:120.500< 0.500µg/LIsopropylbenzene
04/13/23 03:120.500< 0.500µg/L4-Isopropyl toluene
04/13/23 03:121.00< 1.00µg/L2-Hexanone
04/13/23 03:125.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
04/13/23 03:122.00< 2.00µg/LMethylene Chloride
04/13/23 03:121.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
04/13/23 03:121.00< 1.00µg/L4-Methyl-2-Pentanone
04/13/23 03:121.00< 1.00µg/LNaphthalene
04/13/23 03:120.500< 0.500µg/Ln-Propylbenzene
04/13/23 03:120.500< 0.500µg/LStyrene
04/13/23 03:120.500< 0.500µg/L1,1,1,2-Tetrachloroethane
04/13/23 03:120.500< 0.500µg/L1,1,2,2-Tetrachloroethane
04/13/23 03:120.500< 0.500µg/LTetrachloroethene
04/13/23 03:120.500< 0.500µg/LToluene
Page 16 of 22Date:04/17/2023 12:41 PM
Page 71 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31969
Associated Lab Samples: 92839, 92840
LRB-V31969 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/23 03:120.500< 0.500µg/L1,2,3-Trichlorobenzene
04/13/23 03:120.500< 0.500µg/L1,2,4-Trichlorobenzene
04/13/23 03:120.500< 0.500µg/L1,1,1-Trichloroethane
04/13/23 03:120.500< 0.500µg/L1,1,2-Trichloroethane
04/13/23 03:120.500< 0.500µg/LTrichloroethene
04/13/23 03:120.500< 0.500µg/LTrichlorofluoromethane
04/13/23 03:120.500< 0.500µg/L1,2,3-Trichloropropane
04/13/23 03:120.500< 0.500µg/L1,2,4-Trimethylbenzene
04/13/23 03:120.500< 0.500µg/L1,3,5-Trimethylbenzene
04/13/23 03:125.00< 5.00µg/LVinyl Acetate
04/13/23 03:120.500< 0.500µg/LVinyl Chloride
04/13/23 03:121.00< 1.00µg/Lm,p-Xylene
04/13/23 03:120.500< 0.500µg/Lo-Xylene
04/13/23 03:124-Bromofluorobenzene (S)103 70-130
04/13/23 03:12Dibromofluoromethane (S)102 70-130
04/13/23 03:121,2-Dichloroethane - d4 (S)104 70-130
04/13/23 03:12Toluene-d8 (S)101 70-130
LCS-V31969 LCSD-V31969Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
34.4 86.091.036.440.0µg/LAcetone 40-160 5.6 20.0
20.2 10193.518.720.0µg/LBenzene 70-130 7.7 20.0
20.2 10198.019.620.0µg/LBromobenzene 70-130 3.0 20.0
20.9 10599.519.920.0µg/LBromochloromethane 70-130 4.9 20.0
19.8 99.091.018.220.0µg/LBromodichloromethane 70-130 8.4 20.0
Page 17 of 22Date:04/17/2023 12:41 PM
Page 72 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31969
LCS-V31969 LCSD-V31969Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.6 10310420.720.0µg/LBromoform 70-130 0.4 20.0
21.3 10797.519.520.0µg/LBromomethane 60-140 8.8 20.0
19.1 95.591.518.320.0µg/Ln-Butylbenzene 70-130 4.2 20.0
18.8 94.087.517.520.0µg/Lsec-Butyl benzene 70-130 7.1 20.0
18.5 92.589.017.820.0µg/Ltert-Butyl benzene 70-130 3.8 20.0
18.9 94.589.017.820.0µg/LCarbon Tetrachloride 70-130 5.9 20.0
20.3 10295.019.020.0µg/LChlorobenzene 70-130 6.6 20.0
20.1 10197.019.420.0µg/LChlorodibromomethane 70-130 3.5 20.0
21.7 10910220.320.0µg/LChloroethane 60-140 6.6 20.0
19.7 98.594.518.920.0µg/LChloroform 70-130 4.1 20.0
19.6 98.095.019.020.0µg/LChloromethane 60-140 3.1 20.0
19.3 96.590.018.020.0µg/L2-Chlorotoluene 70-130 6.9 20.0
19.0 95.092.518.520.0µg/L4-Chlorotoluene 70-130 2.6 20.0
23.0 11512324.520.0µg/L1,2-Dibromo-3-Chloropropane 70-130 6.3 20.0
20.8 10410320.520.0µg/L1,2-Dibromoethane 70-130 1.4 20.0
20.9 10598.519.720.0µg/LDibromomethane 70-130 5.9 20.0
20.3 10296.519.320.0µg/L1,2-Dichlorobenzene 70-130 5.0 20.0
19.3 96.592.018.420.0µg/L1,3-Dichlorobenzene 70-130 4.7 20.0
19.1 95.592.518.520.0µg/L1,4-Dichlorobenzene 70-130 3.1 20.0
17.1 85.580.516.120.0µg/LDichlorodifluoromethane 60-140 6.0 20.0
20.2 10193.518.720.0µg/L1,1-Dichloroethane 70-130 7.7 20.0
19.8 99.094.518.920.0µg/L1,2-Dichloroethane 70-130 4.6 20.0
20.3 10292.518.520.0µg/L1,1-Dichloroethene 70-130 9.2 20.0
19.6 98.092.518.520.0µg/Lcis-1,2-Dichloroethene 70-130 5.7 20.0
19.4 97.091.518.320.0µg/Ltrans-1,2-Dichloroethene 70-130 5.8 20.0
19.9 99.594.518.920.0µg/L1,2-Dichloropropane 70-130 5.1 20.0
Page 18 of 22Date:04/17/2023 12:41 PM
Page 73 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31969
LCS-V31969 LCSD-V31969Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.2 10197.019.420.0µg/L1,3-Dichloropropane 70-130 4.0 20.0
17.7 88.582.516.520.0µg/L2,2-Dichloropropane 70-130 7.0 20.0
20.5 10399.019.820.0µg/L1,1-Dichloropropene 70-130 3.4 20.0
19.8 99.095.019.020.0µg/Lcis-1,3-Dichloropropene 70-130 4.1 20.0
19.7 98.594.518.920.0µg/Ltrans-1,3-Dichloropropene 70-130 4.1 20.0
610 122135677500µg/LEthanol 60-140 10.4 20.0
19.5 97.591.518.320.0µg/LEthylbenzene 70-130 6.3 20.0
19.5 97.588.017.620.0µg/LHexachlorobutadiene 70-130 10.2 20.0
19.6 98.094.518.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.6 20.0
19.5 97.590.518.120.0µg/LIsopropylbenzene 70-130 7.4 20.0
19.3 96.591.518.320.0µg/L4-Isopropyl toluene 70-130 5.3 20.0
22.1 11111823.620.0µg/L2-Hexanone 60-140 6.5 20.0
19.8 99.010621.120.0µg/LMethyl Ethyl Ketone (MEK)60-140 6.3 20.0
20.3 10296.519.320.0µg/LMethylene Chloride 70-130 5.0 20.0
20.8 10410420.820.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.0 20.0
22.3 11212023.920.0µg/L4-Methyl-2-Pentanone 60-140 6.9 20.0
21.6 10810921.720.0µg/LNaphthalene 70-130 0.4 20.0
18.8 94.088.517.720.0µg/Ln-Propylbenzene 70-130 6.0 20.0
19.8 99.089.517.920.0µg/LStyrene 70-130 10.0 20.0
20.3 10293.518.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 8.2 20.0
20.9 10510621.120.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.9 20.0
19.7 98.589.517.920.0µg/LTetrachloroethene 70-130 9.5 20.0
19.6 98.091.018.220.0µg/LToluene 70-130 7.4 20.0
21.8 10910721.420.0µg/L1,2,3-Trichlorobenzene 70-130 1.8 20.0
20.9 10510120.220.0µg/L1,2,4-Trichlorobenzene 70-130 3.4 20.0
20.0 10090.518.120.0µg/L1,1,1-Trichloroethane 70-130 9.9 20.0
Page 19 of 22Date:04/17/2023 12:41 PM
Page 74 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31970QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31969
LCS-V31969 LCSD-V31969Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.5 10398.019.620.0µg/L1,1,2-Trichloroethane 70-130 4.4 20.0
20.2 10192.518.520.0µg/LTrichloroethene 70-130 8.7 20.0
19.6 98.092.518.520.0µg/LTrichlorofluoromethane 60-140 5.7 20.0
19.5 97.510420.820.0µg/L1,2,3-Trichloropropane 70-130 6.4 20.0
19.3 96.591.518.320.0µg/L1,2,4-Trimethylbenzene 70-130 5.3 20.0
19.3 96.592.018.420.0µg/L1,3,5-Trimethylbenzene 70-130 4.7 20.0
18.6 93.094.518.920.0µg/LVinyl Acetate 60-140 1.6 20.0
19.4 97.090.018.020.0µg/LVinyl Chloride 60-140 7.4 20.0
39.2 98.093.037.240.0µg/Lm,p-Xylene 70-130 5.2 20.0
19.2 96.092.018.420.0µg/Lo-Xylene 70-130 4.2 20.0
99.099.64-Bromofluorobenzene (S)70-130
99.0100Dibromofluoromethane (S)70-130
1051041,2-Dichloroethane - d4 (S)70-130
101101Toluene-d8 (S)70-130
Page 20 of 22Date:04/17/2023 12:41 PM
Page 75 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32020
Associated Lab Samples: 92838
LRB-V32020 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/13/23 19:1310.0< 10.0µg/LAcetone
04/13/23 19:130.500< 0.500µg/LEthylbenzene
04/13/23 19:131.00< 1.00µg/LNaphthalene
04/13/23 19:130.500< 0.500µg/Ln-Propylbenzene
04/13/23 19:130.500< 0.500µg/LToluene
04/13/23 19:130.500< 0.500µg/L1,2,4-Trimethylbenzene
04/13/23 19:130.500< 0.500µg/L1,3,5-Trimethylbenzene
04/13/23 19:131.00< 1.00µg/Lm,p-Xylene
04/13/23 19:130.500< 0.500µg/Lo-Xylene
04/13/23 19:134-Bromofluorobenzene (S)102 70-130
04/13/23 19:13Dibromofluoromethane (S)98.6 70-130
04/13/23 19:131,2-Dichloroethane - d4 (S)101 70-130
04/13/23 19:13Toluene-d8 (S)105 70-130
LCS-V32020 LCSD-V32020Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
49.1 12311947.640.0µg/LAcetone 40-160 3.1 20.0
18.7 93.599.019.820.0µg/LEthylbenzene 70-130 5.7 20.0
19.5 97.511723.420.0µg/LNaphthalene 70-130 18.1 20.0
19.2 96.010721.320.0µg/Ln-Propylbenzene 70-130 10.3 20.0
20.0 10010621.220.0µg/LToluene 70-130 5.8 20.0
19.4 97.010420.820.0µg/L1,2,4-Trimethylbenzene 70-130 6.9 20.0
19.3 96.510621.120.0µg/L1,3,5-Trimethylbenzene 70-130 8.9 20.0
40.0 10010341.240.0µg/Lm,p-Xylene 70-130 2.9 20.0
19.3 96.598.519.720.0µg/Lo-Xylene 70-130 2.0 20.0
Page 21 of 22Date:04/17/2023 12:41 PM
Page 76 of 80
Quality Control Data
23-094-0011Report No:
Project Description:
Client ID:Withers & Ravenel
Virgina's Gas Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V32021QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V32020
LCS-V32020 LCSD-V32020Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1021034-Bromofluorobenzene (S)70-130
98.499.6Dibromofluoromethane (S)70-130
1021021,2-Dichloroethane - d4 (S)70-130
101101Toluene-d8 (S)70-130
Page 22 of 22Date:04/17/2023 12:41 PM
Page 77 of 80
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-094-0011
Withers & Ravenel
01221
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 0.8C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:04/04/2023 12:43:48
Special precautions or instructions included?
Comments:
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