Loading...
HomeMy WebLinkAboutWS-2436_3298_CA_MRP_20230501  WithersRavenel Our People. Your Success.    115 MacKenan Drive | Cary, NC 27511  t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479  Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington        GROUNDWATER MONITORING REPORT    Forest Oaks Circle K  NCDEQ Incident #3298  UST # WS‐2436   5324 Liberty Road  Greensboro, Guilford County, North Carolina  WithersRavenel Project No. 23‐0307‐K                                            Prepared for:  State of North Carolina  Department of Environmental Quality  Division of Waste Management   Underground Storage Tank Section  Federal & State Lead Program  1646 Mail Service Center  Raleigh, North Carolina 27699‐1646    Prepared by: WithersRavenel 115 MacKenan Drive  Cary, North Carolina 27511  North Carolina Firm License No. F‐1479  May 1, 2023 .    WithersRavenel Our People. Your Success.        115 MacKenan Drive | Cary, NC 27511  t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479  Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington  May 1, 2023    State of North Carolina  Department of Environmental Quality  Federal & State Lead Program  Division of Waste Management‐Underground Storage Tank Section  1646 Mail Service Center  Raleigh, North Carolina 27699‐1646    Attn:  Ms. Sharon Ghiold    Re:  Groundwater Monitoring Report   Forest Oaks Circle K  5324 Liberty Road  Greensboro, Guilford County, North Carolina  Groundwater Incident Number: 3298  UST Number: WS‐2436  WR Project Number:  23‐0307‐K    Ms. Ghiold:  WithersRavenel, Inc. (WR) has completed this Groundwater Monitoring Report to document a  groundwater sampling event completed at the site in association with task authorization TA‐01,  for the above referenced site, approved by the Federal & State Lead Program on March 1, 2023  under North Carolina Department of Environmental Quality (NCDEQ) Contract # N70522‐C.     WR appreciates the opportunity to be of service to the Federal & State Lead Program. Should you  have any questions regarding the attached, please contact us at (919) 469‐3340.    Cordially,  WithersRavenel      Cory Nobles       Elizabeth A. Allyn, P.G.  Environmental Geologist II     Environmental Project Geologist II WithersRavenel Our People. Your Success.      Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report April 2023  i      TABLE OF CONTENTS     SECTION A. SITE INFORMATION ..................................................................................................................... 1  SECTION B. EXECUTIVE SUMMARY ................................................................................................................ 3  SECTION C. SITE HISTORY AND CHARACTERIZATION ............................................................................ 5  SECTION D. GROUNDWATER SAMPLING – MARCH 2023 ..................................................................... 9  SECTION E. CONCLUSIONS AND RECOMMENDATIONS ..................................................................... 10    FIGURES   Figure 1 General Location Map  Figure 2 Site Map  Figure 3 Potential Receptor Map  Figure 4 Hydraulic Gradient Map – March 7, 2023  Figure 5 Groundwater Analytical Results Map – March 7, 2023  Figure 6 Dissolved Benzene Isoconcentration Map – March 7, 2023     TABLES   Table B‐1 Site History: UST/AST System & Other Release Information  Table B‐4 Summary of Groundwater Analytical Results  Table B‐5A Public and Private Water Supply Well Information  Table B‐7 Monitoring Well Construction and Groundwater Elevation Information  Table B‐9 Current & Historical Groundwater Elevations and LNAPL Thickness     APPENDICES   Appendix A Field Notes and Photographic Record  Appendix B Laboratory Analytical Report  Appendix C General Standard Operating Procedures          WithersRavenel Our People. Your Success.      Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  1      SECTION A. SITE INFORMATION   1. Site Identification  Date of Report:  May 1, 2023  Facility I.D.: 00‐0‐0000010522  Incident No.: 3298  UST No.: WS‐2436  Site Risk: High  Site Rank: H192D  Land Use Category: Commercial  Site Name: Forest Oaks Circle K  Site Location: 5324 Liberty Road  Nearest City/Town: Greensboro  County: Guilford  Description of Geographical Data Point:  Center of Reported Source Area  Location Method:  Google Earth™  Latitude: 35°58'21.44"N  Longitude: 79°42'38.07"W  2. Contact Information  UST Operator: L.P. Vanstory (deceased)  Address: Not Applicable  Phone: Not Applicable     Property Owner: Sunrise Food & Gas LLC  Address: 507 West 3rd Street, Siler City, NC 27344  Phone: 919‐742‐6003     Property Occupant: Sam’s Food Stores  Address: 5324 Liberty Road, Greensboro, NC 27406  Phone: 336‐674‐8264     Consultant/Contractor: WithersRavenel, Inc.  Address:  115 MacKenan Drive, Cary, NC 27511  Phone:  919‐469‐3340     Analytical Laboratory: Waypoint Analytical, Inc.   State Certification Number: ENV402  Address: 449 Springbrook Rd., Charlotte, NC 28217  Phone: 704‐529‐6364     WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  3  SECTION B. EXECUTIVE SUMMARY    1. Summary of Activities Associated with Current TA    WithersRavenel, Inc. (WR) conducted a groundwater sampling event at the Forest Oaks Circle K  site located at 5324 Liberty Road in Greensboro, Guilford County, North Carolina in association  with task authorization TA‐01 under North Carolina Department of Environmental Quality  (NCDEQ) Contract #N70522‐C.     2. Soil, Groundwater and LNAPL Assessment Information     Soils  No soil samples were obtained in association with the monitoring activities conducted by WR  during the March 2023 event. In July 1992, soil samples documented the presence of volatile total  petroleum hydrocarbons at concentrations that exceeded the NCDEQ Action Levels. Soil sampling  conducted in July 1992, prior to the UST closure activities, indicated a maximum concentration of  total petroleum hydrocarbons (TPH) – gasoline range organics (GRO) of 2,380 mg/kg.  Soil samples  were not collected during the UST removal and over‐excavation activities.  Risk based soil samples  were collected from MW‐1 (B‐2) and B‐1.  Soils samples identified several petroleum compounds  above the Soil‐to‐Groundwater Maximum Soil Contaminant Concentrations (MSCCs). It should be  noted, the soil samples were collected from below the water table at depths ranging from 10 to  14 ft bgs.     Groundwater   WR collected samples from groundwater monitoring wells MW‐1 through MW‐5 and water  supply well WSW‐2 on March 7, 2023. The residence at water supply well WSW‐12 appeared to  be vacant and the spigot did not produce water. The groundwater samples were submitted for  laboratory analysis of volatile organic compounds (VOCs) by SM 6200B plus oxygenates.    Laboratory analysis of the groundwater samples collected from monitoring wells MW‐1, MW‐2,  and MW‐3 detected one or more petroleum compounds above the North Carolina 2L  Groundwater Quality Standards (2L Standards). No analytes were present above the Gross  Contamination Levels for Groundwater (GCLs).    No analytes were present in water supply well WSW‐2 above the laboratory detection limits.    Liquid Non‐Aqueous Phase Liquid  Light non‐aqueous phase liquid (LNAPL) has not historically been detected in the monitoring wells  associated with the site.  However, LNAPL was reported in the excavation at the time of the UST  closures.            WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  4  3.       Receptor Information    A receptor survey update was conducted as part of the 2013 groundwater monitoring activities  performed by Crawford Environmental Services, Inc. (CES).  According to the report associated  with the update, fourteen properties within 1,500 feet of the release area were identified as having  water supply wells. Municipal water is available to properties along Liberty Road.  According to the report, the closest surface water to the subject property is an intermittent creek  approximately 300 feet to the southeast of the subject property.      4. Remediation Activities    Based on WR’s review of historical files available for the site, the following remedial activities have  been completed at the site:   Remedial actions performed at the site to date include the removal of 8,000 gal and 6,000  gal UST systems in November 1993, followed by excavation of impacted soils totaling 238  tons during 1994.  Two additional USTs were discovered during the soil excavation activities,  both of which were removed on March 28, 1994.     In June 2012, S&ME conducted a MMPE event at the site utilizing MW‐1 and MW‐3. During  the MMPE event, 1,952 gallons of VOC‐impacted water was recovered and transported  offsite for disposal. Based on mass removal calculations, 962.24 pounds of VOCs (156.41  gallons) were removed as vapor during the event.     In February 2022, WR conducted a MMPE event at the site utilizing MW‐1 and MW‐3.  During the MMPE event, 2,668 gallons of VOC‐impacted water was recovered and  transported offsite for disposal. Based on mass removal calculations, 259.11 pounds of VOCs  (42.12 gallons) were removed as vapor during the event.      5. Recommendations  Based on the results of the activities conducted at the site in association with this TA, WR  recommends the following:   If sufficient funding is available, WR recommends conducting a Remedial Design  Characterization study.       WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  5  SECTION C. SITE HISTORY AND CHARACTERIZATION    The following information summarizes the site history and characterization.      1. UST Information  The locations of the former UST system, onsite improvements, and the present onsite monitoring  wells are depicted on Figure 2.  The former USTs were centrally located on the subject property  along the northeast property boundary.  According to the historical information on the incident,  two previously known USTs and two orphan USTs were closed by removal in 1993 and 1994,  respectively.   WR is not aware of any aboveground storage tank (ASTs) located on the subject  site.  Table B‐1 summarizes information regarding USTs that were formerly utilized on the  property and includes information about currently operational USTs on the site.      2.       Description of Release/General Assessment History  The following summary of the assessment history is based on WR’s review of historical files for  the subject incident:   Dissolved petroleum hydrocarbons were detected in an on‐site water supply well in 1986. This  well has reportedly been abandoned.   Analysis of soil samples collected from the site in July 1992 documented the presence of  volatile total petroleum hydrocarbons at concentrations that exceeded the State Action Levels.   In November 1993, DAACO Pump and Tank Contractors (DAACO) removed an 8,000‐gallon  and a 6,000‐gallon UST.   LNAPL was noted in the excavations after each UST was removed. No UST closure samples  were collected during the UST removal activities. The overburden and sideburden were placed  back into the UST excavation.   In 1994, DAACO returned to the site and removed approximately 238 tons of petroleum  contaminated soil, which they disposed of off‐site at a permitted facility.  o While excavating contaminated soil, two additional gasoline USTs were discovered ‐  one 1,000‐gallon and one 1,500‐gallon UST.  o The final excavation reportedly measured 60 ft by 25 ft by 6 ft deep.   In August of 2009, S&ME completed a Limited Site Assessment (LSA) for the incident during  which a groundwater monitoring well (MW‐1) was installed within the former UST pit and a  receptor survey was conducted.  o Risk based soil samples were collected from MW‐1 (B‐2) and B‐1.  Soils samples  identified several petroleum compounds in excess of the Soil‐to‐Groundwater MSCCs;  it should be noted, the soil samples were collected from below the water table at  depths ranging from 10 to 14 ft bgs.  o The receptor survey identified eight water supply wells within 1,000 feet of the source  area, two of which were within 500 feet of the source area.  WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  6  o Analytical results for the groundwater sample from MW‐1 indicated the presence of  one or more petroleum constituents at concentrations above 2L Standards and the  GCL.   January 2010 – A Groundwater Monitoring Report completed by S&ME documented the  installation of three additional monitoring wells (MW‐2, MW‐3, and MW‐4).   July 2012 – Analytical results for water samples collected in July 2012 from WSW‐2 identified  1,2 DCA at a concentration of 0.56 ug/L, which is above its 2L standard.  Analytical results  during the June 2013 sampling event also identified the presence of 1,2 DCA in the water  sample taken from WSW‐2, however, the concentration was below the reporting detection  limits and was estimated.  In addition, results from the October 2011, July 2012, and June  2013 sampling events identified the presence of di‐isopropyl ether at concentrations that were  below its 2L standard.  The water supply well is located at 5607 Hagan Stone Park Road and  is approximately 350 feet southeast of the release area.   May 2012 ‐ Off‐site monitoring well MW‐5 was installed.   June 2012 ‐ A MMPE event was conducted using MW‐1 and MW‐3 as extraction points.  During the MMPE event, 1,952 gallons of VOC‐impacted water was recovered and  transported offsite for disposal. Based on mass removal calculations, 962.24 pounds of VOCs  (156.41 gallons) were removed as vapor during the event.     July 2014 – WR conducted a monitoring event at the site which included the collection of  groundwater samples from wells MW‐1, MW‐2, MW‐3, MW‐4 and MW‐5, and supply wells  WSW‐1, WSW‐2, WSW‐4, WSW‐7, and WSW‐12.  Analytical data for groundwater samples  obtained from the monitoring wells on the site indicated a benzene concentration above the  GCL in MW‐1 and one or more targeted compounds concentrations above the 2L Standards  in MW‐1, MW‐2, and MW‐3.   Data for supply well samples did not indicate the presence of  targeted compounds by SM6200B, except for IPE, reported in WSW‐2 at a concentration of  1.1 µg/L, below the 2L Standard.     April 2015 – WR completed groundwater and supply well sampling activities at the site.   Analytical data for groundwater samples obtained from the monitoring wells on the site  indicated a benzene concentration above the GCL in MW‐1 and one or more targeted  compounds concentrations above the 2L Standards in MW‐1, MW‐2, and MW‐3.   Tert‐amyl  methyl ether (TAME) and tert‐amyl alcohol (TAA) were reported in the sample obtained from  MW‐2 at levels of 1.1 and 5,800 µg/L, respectively.  The level of TAA in the sample exceeded  the 2L Standard for the compound, while the level of TAME did not exceed its 2L Standard.   Analytical data for samples obtained from supply wells WSW‐2 and WSW‐11 did not show  the presence of targeted compounds at levels above the MDL for SM6200B.     May 2016 – WR performed groundwater and supply well sampling at the location. Analytical  data for groundwater samples obtained from the monitoring wells on the site indicated a  benzene concentration above the GCL in MW‐1 and one or more targeted compounds  concentrations above the 2L Standards in MW‐1, MW‐2, and MW‐3.  Lab results for samples  collected from supply wells WSW‐2, WSW‐11 and WSW‐12 showed IPE present in the sample  from WSW‐2 at a concentration of 1.02 µg/L, a level which falls beneath the 2L Standard for  the compound.    WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  7   January 2018 – WR completed an Underground Injection Control (UIC) Permit application to  allow for the injection of EnviroClean surfactant to enhance degradation of contaminants at  the location. The injection was not conducted.   May 2018 – WR performed a limited groundwater sampling event at the site, including the  sampling of wells MW‐1, MW‐3, and MW‐4.  Analytical data for groundwater samples  obtained from the monitoring wells on the site indicated a benzene concentration above the  GCL in MW‐1 and one or more targeted compounds concentrations above the 2L Standards  in MW‐1 and MW‐3.     August 2019 ‐ WR performed a groundwater sampling event at the site, including the sampling  of wells MW‐1, MW‐2, MW‐3 and MW‐4 and supply wells WSW‐2 and WSW‐12.  Analytical  data for groundwater samples obtained from the monitoring wells on the site indicated a  benzene concentration above the GCL in MW‐1 and one or more targeted compounds  concentrations above the 2L Standards in MW‐1, MW‐2, and MW‐3.  Acetone was reported  in the sample from WSW‐12 at a level below the NC 2L Standard.  No targeted chemicals were  reported above the laboratory MDL in the sample obtained from WSW‐2.   November 2020 ‐ WR performed a groundwater sampling event including the sampling of  MW‐1 through MW‐5 and water supply wells WSW‐2 and WSW‐12. Laboratory results  indicated benzene in the sample from MW‐1 at a level exceeding the GCL. One or more  targeted compounds were identified in excess of the 2L Standards in wells MW‐1, MW‐2 and  MW‐3. No targeted compounds were reported in the samples obtained from wells MW‐4 or  MW‐5 at concentrations above the laboratory MDL.  WSW‐2 contained IPE in excess of the  laboratory MDL, but below the 2L Standard. No compounds were detected in WSW‐12.   February / March 2022 – WR performed an MMPE event that removed 2,668 gallons of  impacted groundwater and 42.12 gallons of VOCs were removed as vapor. WR also performed  a groundwater sampling event for MW‐1 through MW‐5 as well as water supply wells WSW‐ 2 and WSW‐12. Laboratory results indicated that MW‐1, MW‐2, and MW‐3 contained  compounds at concentrations above the 2L Standard. MW‐3 contained benzene at a  concentration above the GCL. Di‐isopropyl ether was detected in WSW‐2 at a concentration  above the laboratory detection limits, but below the NC 2L Standard.    Ongoing – WR is attempting to connect the property located at 5607 Hagan Court,  Greensboro, NC to the City of Greensboro municipal water supply.     3.  Site Characteristics  The property is located at 5324 Liberty Road in Greensboro, Guilford County, North Carolina  (Figure 1) and operates as a convenient store with retail petroleum sales (Figure 2).  The Guilford  County Parcel ID No. for the property is 7880997601.  The surrounding area is moderately  developed with a mixture of commercial and residential properties.         WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  8  4.       Information on Receptors/Potential Receptors  A receptor survey update was conducted as part of the 2013 groundwater monitoring activities  performed by CES.  According to the report associated with the update, fourteen properties within  1,500 feet of the release area were identified as having water supply wells. Municipal water is  available to properties along Liberty Road.  The owners of water supply wells WSW‐2 and WSW‐ 12 have agreed to connect to municipal water. A water meter has been installed at the WSW‐12  location. However, it has not been connected to the municipal water line. The residence at WSW‐ 12 appears vacant. In March 2023, an annexation agreement was submitted to the City of  Greensboro for the property containing WSW‐2.   According to the report, the closest surface water to the subject property is an intermittent creek  approximately 300 feet to the southeast of the subject property.    5.       Regional and Site Geology and Hydrology  The Geologic Map of North Carolina depicts the site is located in the metamorphosed granitic  rocks of the intrusive rocks of the Carolina Slate Belt. The Geologic Map of North Carolina  indicates the site is underlain by megacrystic, well foliated, metamorphosed granitic rock which  locally contains hornblende and is comprised of the Chapel Hill, Chatham, Farrington, Meadow  Flats, Mt. Moriah, Parks Crossroads plutons, and Roxboro and Vance County suites.    According to the United States Department of Agricultural (USDA) Natural Resources  Conservation Service (NRCS) Web Soil Survey, the source area is underlain by Enon fine sandy  loam (2 to 6 percent slopes).  Enon fine sandy loam is well drained, found on summits of interfluves,  and the parent material is saprolite derived from diorite and/or gabbro and/or diabase and/or  gneiss. Boring log and excavation records from the site indicate that the general lithology of the  site soils consisted of micaceous silts and clayey silts.         WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  9  SECTION D. GROUNDWATER SAMPLING – MARCH 2023    WR mobilized to the site on March 7, 2023, to sample the five Type II groundwater monitoring  wells associated with the site and water supply wells WSW‐2 and WSW‐12. The locations of  monitoring wells MW‐1 through MW‐5 are shown on Figure 2. The locations of water supply wells  are shown on Figure 3.  Monitoring Well Sampling Activities  Prior to purging activities, groundwater levels were gauged with a decontaminated electronic  water level meter. Groundwater levels measured within the monitoring wells ranged from 3.03  feet below Top of Casing (TOC) in monitoring well MW‐5 to 7.25 feet below TOC in monitoring  well MW‐2. Groundwater elevations were utilized to generate a groundwater flow map at the site,  based on the March 2023 groundwater levels (Figure 4).  Groundwater elevation data indicated  that groundwater predominantly flows to the west and southeast across the site. The monitoring  well screens were submerged in monitoring wells MW‐1, MW‐3, MW‐4, and MW‐5. Groundwater  elevations and well construction information is summarized in Table B‐7. Historical groundwater  elevation data is summarized in Table B‐9.  After gauging, each monitoring well was purged a minimum of three volumes of groundwater using  dedicated bailers.  All groundwater samples were then placed directly into laboratory‐provided  containers, placed on ice, and under property chain‐of‐custody procedures, transported to  Waypoint Analytical, Inc. located in Charlotte, NC, to be analyzed for VOCs by SM6200B plus  oxygenates.  Water Supply Well Sampling Activities  WR mobilized to the site on March 7, 2023, for the purposes of sampling supply wells WSW‐2  and WSW‐12. The property where water supply well WSW‐12 is located was vacant at the time  of the groundwater sampling and there was no power to the well. Therefore, this well was not  sampled. For sampling, each of the wells was purged by opening their respective sampling points  allowing the well pump(s) to run continuously for a minimum of 10‐minutes. After sufficient  purging of the wells, each was sampled by decanting well water into pre‐preserved laboratory  provided sample containers.    Samples collected from WSW‐2 and a field blank were submitted to Waypoint for testing by SM  6200B plus oxygenates.     Laboratory Results  Laboratory analysis of the groundwater samples collected from monitoring wells MW‐1, MW‐2,  and MW‐3 detected one or more petroleum compounds above the 2L Standards. No analytes  were present above the GCLs.    No analytes were present in water supply well WSW‐2 above the laboratory detection limits.    A summary of the groundwater analytical results is presented in Table B‐4. Water supply well  sampling results are shown on Figure 3 and monitoring well sampling results are shown on Figure  5. A benzene isoconcentration map is included as Figure 6. A photographic record and the field  notes are included in Appendix A.  A copy of the laboratory analytical report and chain‐of‐custody  is included in Appendix B.  WR’s standard operating procedures are provided in Appendix C.  WithersRavenel Our People. Your Success.    Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23‐0307‐K  Groundwater Monitoring Report May 2023  10    SECTION E. CONCLUSIONS AND RECOMMENDATIONS    This report documents the results of field activities conducted at the site under TA‐01, which  included a groundwater sampling event. Conclusions based on observations, analytical data and  research relating to the release at the site combined with historical information include the  following:   Fourteen properties within 1,500 feet of the release area were identified as having water  supply wells. Municipal water is available to properties along Liberty Road.     The groundwater remedial goals are the 2L Standards based on the information obtained  during the 2013 receptor survey. Current groundwater concentrations exceed the 2L  Standards in monitoring wells MW‐1, MW‐2, and MW‐3.   The site is currently in use as a retail petroleum station and convenience store.  Based on the results of assessment and monitoring activities conducted at the site in association  with this TA, WR recommends the following:   If sufficient funding is available, WR recommends conducting a Remedial Design  Characterization study.     WithersRavenel Our People. Your Success. FIGURES EAA MJ DRAWN BY: 04/07/2023 23-0307-K 1 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: GENERAL LOCATION MAP WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=500 ' GRAPHIC SCALE 1 inch = 500 ft. 0 500250 1000 FOREST OAKS CIRCLE K INCIDENT # 3298 5324 LIBERTY ROAD GREENSBORO, GUILFORD COUNTY, NC SUBJECT SITE ±0.81 ACRE LIBERTY RDHAGAN STONE PARK RDMW-2MW-1MW-5MW-4MW-3EAA MJ DRAWN BY: 04/07/2023 23-0307-K 2 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: FOREST OAKS CIRCLE K INCIDENT # 3298 5324 LIBERTY ROAD GREENSBORO, GUILFORD COUNTY, NC SITE MAPWithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=40 'LEGENDTYPE II MONITORING WELL LOCATIONNOTES:1.2022 AERIAL OBTAINED FROM NC ONE MAP.GRAPHIC SCALE1 inch = 40 ft.0402080 1387119564131410122EAA MJ DRAWN BY: 04/07/2023 23-0307-K 3 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: FOREST OAKS CIRCLE K INCIDENT # 3298 5324 LIBERTY ROAD GREENSBORO, GUILFORD COUNTY, NC POTENTIAL RECEPTOR MAP WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=300 'LEGENDSUPPLY WELL LOCATION(SEE CORRESPONDING INFORMATION IN TABLE B-5)NOTES:1. 2022 AERIAL OBTAINED FROM NC ONE MAP.GRAPHIC SCALE1 inch = 300 ft.03001506004 LIBERTY RDHAGAN STONE PARK RDMW-2MW-1MW-5MW-4(91.37)(93.50)(92.58)(93.87)(93.05)9 3 . 5 93.0 93.5 9 3 . 0MW-39 2 . 5 9 2 . 0 9 1 . 5 EAA MJ DRAWN BY: 04/04/2022 23-0307-K 4 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: FOREST OAKS CIRCLE K INCIDENT # 3298 5324 LIBERTY ROAD GREENSBORO, GUILFORD COUNTY, NC HYDRAULIC GRADIENT MAP (ft) MARCH 7, 2023 WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=30 'LEGENDTYPE II MONITORING WELL LOCATIONGROUNDWATER ELEVATIONIMPLIED GROUNDWATER ELEVATIONINFERRED GROUNDWATER FLOWNOTES:1.2022 AERIAL OBTAINED FROM NC ONE MAP.GRAPHIC SCALE1 inch = 30 ft.0301560(93.05)93 LIBERTY RDHAGAN STONE PARK RDMW-2MW-1MW-5MW-4MW-3EAA MJ DRAWN BY: 04/07/2023 23-0307-K 5 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: FOREST OAKS CIRCLE K INCIDENT # 3298 5324 LIBERTY ROAD GREENSBORO, GUILFORD COUNTY, NC GROUNDWATER ANALYTICAL RESULTS MAP - MARCH 7, 2023 WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=40 'LEGENDTYPE II MONITORING WELL LOCATIONNOTES:1.2022 AERIAL OBTAINED FROM NC ONE MAP.GRAPHIC SCALE1 inch = 40 ft.0402080 LIBERTY RDHAGAN STONE PARK RDMW-2MW-1MW-5MW-4(3,230)(<0.500)(<0.500)(3,090)(<0.500 )1.01,0001.01,0001.0ESTIMATED EXTENT OFBENZENE AT LEVELSEXCEEDING GCLMW-3EAA MJ DRAWN BY: 04/04/22 23-0307-K 6 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: FOREST OAKS CIRCLE K INCIDENT # 3298 5324 LIBERTY ROAD GREENSBORO, GUILFORD COUNTY, NC DISSOLVED BENZENE ISOCONCENTRATION MAP (ug/L) MARCH 7, 2023 WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com 1"=30 'LEGENDTYPE II MONITORING WELL LOCATIONGROUNDWATER BENZENE CONCENTRATIONIMPLIED GROUNDWATER BENZENE CONCENTRATIONESTIMATED EXTENT OF BENZENE AT LEVELS EXCEEDING 2L STANDARDNOTES:1.2022 AERIAL OBTAINED FROM NC ONE MAP.GRAPHIC SCALE1 inch = 30 ft.0301560(3,090)1,000 WithersRavenel Our People. Your Success. TABLES UST IDNumberCurrent/LastContentsPreviousContentsCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length) (ft)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofUSTWas release associated with UST System? (Y/N)1 Gasoline N/A 8,000 Steel ~8.0 x 21.4 N/A 1979Permanently Closed by Removal (November 1993)Y2 Gasoline N/A 6,000 Steel ~8.0 x 16 N/A 1979Permanently Closed by Removal (November 1993)Y3 Gasoline N/A 1,500 Steel Unknown N/A UnknownPermanently Closed by Removal (March 1994)Y4 Gasoline N/A 1,000 Steel Unknown N/A UnknownPermanently Closed by Removal (March 1994)Y5 Gasoline N/A 10,000Single Wall SteelUnknownSingle Wall Fiberglass Reinforced Plastic Piping, Pressurized Delivery System3/1/1995 Currently Operational N6 Gasoline N/A 10,000Single Wall SteelUnknownSingle Wall Fiberglass Reinforced Plastic Piping, Pressurized Delivery System3/1/1995 Currently Operational N7 Gasoline N/A 10,000Single Wall SteelUnknownSingle Wall Fiberglass Reinforced Plastic Piping, Pressurized Delivery System3/1/1995 Currently Operational NAST IDNumberCurrent/LastContentsPreviousContentsCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length) (ft)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofASTWas release associated with AST System? (Y/N)N/A N/A N/A N/A N/A N/A N/A N/A N/A N/AIncidentNumberMaterialReleasedDateofRelease3298 Gasoline UnknownNotes:1)2)Greensboro, Guilford County, NCDescription of ReleaseTable B‐1Site History:  UST/AST System & Other Release InformationFOREST OAKS CIRCLE KUST release was detected through laboratory analysis of soil samples collected in August 1992.5324 Liberty RoadIncident Number: 3298Tank information for USTs 5, 6 and 7 from NCDEQ‐DWM's "NC UST Facility Operating Permits", and "tblALLTANKS" , both dated January 2015.  These USTs are operated under NCDEQ‐DWM UST Section Facility ID # 00‐2‐0000010522.WR is not aware of any ASTs associated with the subject site.Page 1 of 1 ACETONEBENZENEN-BUTYLBENZENESEC-BUTYLBENZENETERT-BUTYLBENZENECARBON TETRACHLORIDECHLOROMETHANE1,2-DICHLOROETHANEETHANOLETHYLBENZENEDI-ISOPROPYL ETHERISOPROPYLBENZENEP-ISOPROPYLTOLUENE2-BUTANONE (MEK)METHYL TERT-BUTYL ETHER4-METHYL-2-PENTANONE (MIBK)NAPHTHALENEN-PROPYLBENZENESTYRENETERT-AMYL ALCOHOLTERT-AMYL METHYL ETHERTERT-BUTYL ALCOHOLETHYL TERT-BUTYL ETHERTERT-BUTYL FORMATETOLUENE1,2,4-TRIMETHYLBENZENE1,3,5-TRIMETHYLBENZENETOTAL XYLENE67-64-1 71-43-2 104-51-8 135-98-8 98-06-6 56-23-5 74-87-3 107-06-2 64-17-5 100-41-4 108-20-3 98-82-8 99-87-6 78-93-3 1634-04-4 108-10-1 91-20-3 103-65-1 100-42-5 75-85-4 994-05-8 75-65-0 637-92-3 762-75-4 108-88-3 95-63-6 108-67-8 NA 7/13/2009 NR 12,000 ND ND ND NR NR 49.9 NR 3,050 4,180 68.8 NR NR 804 NR 798 188 169 NR NR NR NR NR 11,600 1,290 326 10540 6/28/2010 ND 15,000 56 ND ND NR NR 56 NR 2,400 2,300 72 NR 28 J 310 NR 910 230 140 NR NR NR NR NR 20,000 1,900 540 11000 8/16/2011 ND 14,000 ND ND ND NR NR 44 NR 3,200 2,200 99 NR ND 280 NR 940 180 120 NR NR NR NR NR 15,000 1,200 360 12000 6/25-29/2012 7/5/2012 NR 9,100 14 7 ND NR NR 16 NR 1,100 1,100 ND NR NR 140 NR 410 ND 20 NR NR NR NR NR 4,800 320 100 2500 6/19/2013 ND 5,210 ND ND ND NR NR 51.7 NR 1,510 920 38.3 NR NR 81.7 NR 601 103 90.7 NR NR NR NR NR 9,980 1,260 342 8970 7/22/2014 <12000 7,800 <250 <250 <250 <250 <620 <250 NA 2,000 1,000 <250 <250 <2500 <250 <2500 <1200 <250 <250 NA NA NA NA NA 8,800 710 <250 7900 4/29/2015 <25000 7,000 <500 <500 <500 <500 <1200 <500 <50000 2,300 770 <500 <500 <5000 <500 <5000 <2500 <500 <500 <25000 <500 <2500 <500 <10000 11,000 960 <500 8800 5/11/2016 <5000 8,470 <100 <100 <100 <100 <250 <100 <10000 2,200 1,110 <100 <100 <1000 <100 <1000 677 121 <100 <5000 <100 <500 <100 <2000 9,710 1,290 320 9860 5/14/2018 <1000 5,520 <20.0 <20.0 <20.0 <20.0 <50.0 <20.0 <2000 2,770 594 NR NR <200 44.4 <200 843 243 33 NR <20 125 <20 NR 9,820 1,730 483 11000 8/14/2019 <3.1 7,200 23 11 <0.88 <1.1 <0.79 18 <270 3,300 500 78 7.4 <2.4 35 <0.78 2500 220 38 <7.2 <100 300 <0.59 <2.5 10,000 2,600 520 15000 11/13/2020 <31 6,700 <7.6 <7.6 <8.8 <11 <7.9 <6.6 <2700 3,200 420 73 <8.9 <24 <100 <7.8 900 210 <50 <72 <1000 <1000 <5.9 <25 9,100 1,800 450 13000 2/14-18/2022 3/22/2022 <1000 3,990 <50.0 <50.0 <200 <50.0 <50.0 <50.0 <20000 2,860 308 120 <50.0 <500 <100 <100 609 255 <50.0 1090 <1000 <1000 <1000 <1000 3,760 1,250 402 6890 3/7/2023 <100 3,090 11 5.93 <20.0 <5.00 116 <5.00 <2000 2,510 227 59.7 5.25 <50.0 16.6 <10.0 752 153 10.8 <1000 <100 <100 <100 <100 1,400 701 200 4,680 7/13/2009 NR 1.5 ND 2 1.8 NR NR 0.81 NR ND 165 0.89 NR NR 2.1 NR ND ND ND NR NR NR NR NR ND ND ND ND 6/28/2010 ND 4 ND 4 2.8 NR NR 0.65 NR ND 140 1 NR ND 1.8 NR ND ND ND NR NR NR NR NR ND ND ND ND 8/16/2011 2.6 J 6.6 ND 2.6 2 NR NR 0.51 NR ND 160 2.2 NR ND 2.6 NR ND 1.1 ND NR NR NR NR NR ND ND ND ND 7/5/2012 5.4 J 3.7 ND 1.8 1.7 NR NR 0.65 NR ND 150 ND NR 3.2 J 2.8 NR ND NR ND NR NR NR NR NR ND ND ND ND 6/19/2013 ND 0.26 J ND 0.78 0.62 NR NR ND NR ND 12.8 0.26 J NR NR 0.27 J ND ND ND NR NR NR NR NR ND 0.28 J ND ND 7/22/2014 <50 4.6 <1 1.2 <1 <1 <2.5 <1 NA <1 130 <1 <1 <10 1.5 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 4/29/2015 <50 3 <1 2.1 1.7 <1 <2.5 <1 <100 <1 280 <1 <1 <10 6.8 <10 <5 <1 <1 5,800 1.1 <500 <1 <20 <5 <1 <1 <2 5/11/2016 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 108 <1 <1 <10 2.25 <10 <5 <1 <1 <1250 <1 156 <1 <500 <5 <1 <1 <2 8/14/2019 <0.31 16 <0.5 7.7 3.2 <0.11 <0.079 <0.066 <27 <0.5 120 1.2 <0.089 <0.24 1.8 <0.078 <0.19 0.56 <0.047 <0.72 <0.10 520 <0.059 <0.25 <0.044 <0.054 <0.076 <0.15 11/13/2020 <10 3.4 <0.076 2.8 1.8 <0.11 <0.079 <0.066 <27 <0.061 130 <0.5 <0.089 <0.24 3.3 <0.078 <1 <0.087 <0.047 <0.72 <10 470 <0.059 <0.25 <0.044 <0.054 <0.076 <0.15 3/22/2022 <10.0 2.09 <0.500 1.14 <2.00 <0.500 <0.500 <0.500 <200 <0.500 171 <0.500 <0.500 <5.00 6.85 <1.00 <1.00 <0.500 <0.500 5800 <10.0 525 <10.0 <10.0 0.618 <0.500 <0.500 <0.500 3/7/2023 <10.0 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <200 <0.500 47.7 <0.500 <0.500 <5.00 3 <1.00 <1.00 <0.500 <0.500 <1000 <10.0 64.5 <10.0 <10.0 <0.500 <0.500 <0.500 <0.500 7/13/2009 NR 14,400 ND ND ND NR NR ND NR 2,680 728 ND NR NR ND NR 1,160 247 ND NR NR NR NR NR 32,200 2,070 524 13,630 6/28/2010 ND 8,200 120 ND ND NR NR ND NR 3,500 220 110 NR ND ND NR 1,400 380 310 NR NR NR NR NR 23,000 3,000 780 17,000 8/16/2011 ND 11,000 ND ND ND NR NR ND NR 2,900 240 180 NR ND ND NR 1,300 300 150 NR NR NR NR NR 25,000 1,800 500 13,000 6/25-29/2012 7/5/2012 ND 10,000 430 68 ND NR NR ND NR 5,000 350 350 NR ND ND NR 4,100 1,300 1,100 NR NR NR NR NR 30,000 4,600 1,200 25,000 6/19/2013 ND 3,540 ND ND ND NR NR ND NR 2,290 89.9 96.5 NR NR ND NR 1,040 302 32.1 NR NR NR NR NR 5,440 2,380 576 8,520 7/22/2014 <12000 3,700 <250 <250 <250 <250 <620 <250 NA 1,700 <250 <250 <250 <2500 <250 <2500 <1200 <250 <250 NA NA NA NA NA 5,500 1,200 300 7,700 4/29/2015 <10000 3,400 <200 <200 <200 <200 <500 <200 <20000 2,000 <200 <200 <200 <2000 <200 <2000 <1000 <200 <200 <10000 <200 <1000 <200 <4000 5,100 1,200 300 7,300 5/11/2016 <12500 3,260 <250 <250 <250 <250 <625 <250 <25000 1,760 <250 <250 <250 <2500 <250 <2500 <1250 <250 <250 <12500 <250 <1250 <250 <5000 3,550 2,080 545 8,940 5/14/2018 <5000 3,270 <100 <100 <100 <100 <250 <100 <10000 1,870 <100 NR NR <1000 <100 <1000 808 227 <100 NR <100 <500 <100 NR 4,240 1,510 366 7,010 8/14/2019 <3.1 3,200 240 73 <0.88 <1.1 <0.79 <0.66 <270 2,600 42 270 53 <2.4 <0.42 <0.78 1,900 870 <0.47 <7.2 <1.0 <6.4 <0.59 <2.5 1,600 2,400 620 8,500 11/13/2020 <3.1 4,100 52 18 <0.88 <1.1 <0.79 <0.66 <270 2,400 68 85 13 <2.4 <10 <10 950 270 18 <7.2 <1.0 <6.4 <0.59 <2.5 3,100 2,000 260 7,200 2/14-18/2022 3/22/2022 <1000 5,310 431 144 <200 <50.0 <50.0 <50.0 <20000 6190 71.2 440 111 <500 <100 <100 1520 1700 277 <1000 <1000 <1000 <1000 <1000 14100 8600 2860 25800 3/7/2023 <1000 3,230 616 170 <200 <50.0 <50.0 <50.0 <20000 3,900 76.9 340 98.1 <500 <100 389 2,280 1,340 <50.0 <1000 <1000 <1000 <1000 <1000 3,750 7,170 2,270 13,200 6,000 1 70 70 70 NL 3 0.4 4,000 600 70 70 25 4,000 20 100 6 70 70 40 128 10 47 40 600 400 400 500 6,000,000 5,000 5,900 8,800 14,750 NL 3,000 400 4,000,000 80,000 70,000 30,500 11,700 4,000,000 20,000 100,000 6,000 26,100 70,000 40,000 128,000 10,000 47,000 40,000 260,000 28,500 24,100 50,000 Notes: 1)NL = Not Listed2)NA = Compound Not Analyzed for by Laboratory 3)NR = Compound Not Reported By Previous Consultants, or not included in analytical method suite4)ND = Compound Not Detected. 5)Result = Result Exceeds Laboratory Detection Limits Result = Result Exceeds 2L Standard Result = Result Exceeds GCL Value NC 2L Standard - North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L GCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for Groundwater All results provided in ug/L (micrograms per liter) or parts per billion SampleID DateCollected MMPE Event MMPE Event MW-3 Greensboro, Guilford County, NC Compounds analyzed by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included in the Appendix for a full list of constituents MW-1 SM6200B / EPA-8260 - Volatile Organic CompoundsAnalytical Method NC 2L Standard GCLs for Groundwater J = Compound detected above laboratory detection limite but below the laboratory reporting limit. MMPE Event MW-2 MMPE Event TABLE B-4SUMMARY OF GROUNDWATER ANALYTICAL RESULTS FOREST OAKS CIRCLE K Incident Number: 3298 5324 Liberty Road Page 1 of 2 ACETONEBENZENEN-BUTYLBENZENESEC-BUTYLBENZENETERT-BUTYLBENZENECARBON TETRACHLORIDECHLOROMETHANE1,2-DICHLOROETHANEETHANOLETHYLBENZENEDI-ISOPROPYL ETHERISOPROPYLBENZENEP-ISOPROPYLTOLUENE2-BUTANONE (MEK)METHYL TERT-BUTYL ETHER4-METHYL-2-PENTANONE (MIBK)NAPHTHALENEN-PROPYLBENZENESTYRENETERT-AMYL ALCOHOLTERT-AMYL METHYL ETHERTERT-BUTYL ALCOHOLETHYL TERT-BUTYL ETHERTERT-BUTYL FORMATETOLUENE1,2,4-TRIMETHYLBENZENE1,3,5-TRIMETHYLBENZENETOTAL XYLENE67-64-1 71-43-2 104-51-8 135-98-8 98-06-6 56-23-5 74-87-3 107-06-2 64-17-5 100-41-4 108-20-3 98-82-8 99-87-6 78-93-3 1634-04-4 108-10-1 91-20-3 103-65-1 100-42-5 75-85-4 994-05-8 75-65-0 637-92-3 762-75-4 108-88-3 95-63-6 108-67-8 NA SampleID DateCollected Greensboro, Guilford County, NC SM6200B / EPA-8260 - Volatile Organic CompoundsAnalytical Method TABLE B-4SUMMARY OF GROUNDWATER ANALYTICAL RESULTS FOREST OAKS CIRCLE K Incident Number: 3298 5324 Liberty Road 7/13/2009 NR ND ND ND ND NR NR ND NR ND ND ND NR NR ND NR ND ND ND NR NR NR NR NR ND ND ND ND 6/28/2010 NR ND ND ND ND NR NR ND NR ND ND ND NR ND ND NR ND ND ND NR NR NR NR NR ND ND ND ND 8/16/2011 NR ND ND ND ND NR NR ND NR ND ND ND NR ND ND NR ND ND ND NR NR NR NR NR ND ND ND ND 7/5/2012 NR ND ND ND ND NR NR ND NR ND ND ND NR ND ND NR ND NR ND NR NR NR NR NR ND ND ND ND 6/19/2013 NR ND ND ND ND NR NR ND NR 0.37 J ND ND NR ND ND NR 2.4 ND ND NR NR NR NR NR 0.41 J 2.4 0.9 1.97 7/22/2014 <50 <1 <1 <1 <1 <1 <2.5 <1 NA <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 4/29/2015 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 5/11/2016 5/14/2018 <50 <1 <1.00 <1.00 <1.00 <1.00 <2.50 <1.00 <100 <1 <10 NR NR 29.9 <1 <10.0 <5 <1 <1.00 NR <1 <5 <1 NR <1 <1.00 <1.00 <38/14/2019 <10 <0.048 <0.076 <0.076 <0.088 <0.11 <0.079 <0.066 <27 <0.061 <0.050 <0.054 <0.089 <0.24 <0.042 <0.078 <0.19 <0.087 <0.047 <0.72 <0.10 <0.64 <0.059 <0.25 <0.044 <0.054 <0.076 <0.15 11/13/2020 <0.31 <0.048 <0.076 <0.076 <0.088 <0.11 <0.079 <0.066 <27 <0.061 <0.050 <0.054 <0.089 <0.24 <0.042 <0.078 <0.19 <0.087 <0.047 <0.72 <0.10 <0.64 <0.059 <0.25 <0.044 <0.054 <0.076 <0.15 3/22/2022 <10.0 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <200 <0.500 <0.500 <0.500 <0.500 <5.00 <1.00 <1.00 <1.00 <0.500 <0.500 <10.0 <10.0 <10.0 <10.0 <10.0 <0.500 <0.500 <0.500 <0.500 3/7/2023 <10.0 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <200 <0.500 <0.500 <0.500 <0.500 <5.00 <1.00 <1.00 <1.00 <0.500 <0.500 <10.0 <10.0 <10.0 <10.0 <10.0 <0.500 <0.500 <0.500 <0.500 7/5/2012 ND ND ND ND ND NR NR ND NR ND ND ND NR ND ND NR ND NR ND NR NR NR NR NR ND ND ND ND 6/19/2013 ND ND 0.49 J ND ND NR NR ND NR 0.77 ND ND NR NR ND NR 1.9 J 0.49 J ND NR NR NR NR NR 0.55 4.2 1.3 3.8 7/22/2014 <50 <1 <1 <1 <1 <1 <2.5 <1 NA <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 4/29/2015 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 5/11/2016 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 8/14/2019 11/13/2020 <0.31 <0.048 <0.076 <0.076 <0.088 <0.11 <0.079 <0.066 <27 <0.061 <0.050 <0.054 <0.089 <0.24 <0.042 <0.078 <0.19 <0.087 <0.047 <0.72 <0.10 <0.64 <0.059 <0.25 <0.044 <0.054 <0.076 <0.15 3/22/2022 <10.0 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <200 <0.500 <0.500 <0.500 <0.500 <5.00 <1.00 <1.00 <1.00 <0.500 <0.500 <10.0 <10.0 <10.0 <10.0 <10.0 <0.500 <0.500 <0.500 <0.500 3/7/2023 <10.0 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <200 <0.500 <0.500 <0.500 <0.500 <5.00 <1.00 <1.00 <1.00 <0.500 <0.500 <10.0 <10.0 <10.0 <10.0 <10.0 <0.500 <0.500 <0.500 <0.500 WSW-1 7/22/2014 <50 <1 <1 <1 <1 <1 <2.5 <1 NA <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 7/22/2014 <50 <1 <1 <1 <1 <1 <2.5 <1 NA <1 1.1 <1 <1 <10 <1 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 4/29/2015 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 5/12/2016 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 1.02 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 8/14/2019 <10 <0.048 <0.076 <0.076 <0.088 <0.11 <0.079 <0.066 <27 <0.061 <0.050 <0.054 <0.089 <5 <0.042 <0.078 <0.19 <0.087 <0.047 <0.72 <0.10 <0.64 <0.059 <0.25 <0.044 <0.054 <0.076 <0.15 11/13/2020 <0.31 <0.048 <0.076 <0.076 NA <0.11 <0.079 <0.066 <27 <0.061 2.3 <0.054 <0.089 <0.24 <0.042 <0.078 <0.19 <0.087 <0.047 NA NA <0.64 NA NA <0.044 <0.054 <0.076 <0.15 3/22/2022 <10.0 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <200 <0.500 0.876 <0.500 <0.500 <5.00 <1.00 <1.00 <1.00 <0.500 <0.500 <10.0 <10.0 <10.0 <10.0 <10.0 <0.500 <0.500 <0.500 <0.500 3/7/2023 <10.0 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <200 <0.500 <0.500 <0.500 <0.500 <5.00 <1.00 <1.00 <1.00 <0.500 <0.500 <10.0 <10.0 <10.0 <10.0 <10.0 <0.500 <0.500 <0.500 <0.500 WSW-4 7/22/2014 <50 <1 <1 <1 <1 <1 <2.5 <1 NA <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 WSW-7 7/22/2014 <50 <1 <1 <1 <1 <1 <2.5 <1 NA <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 4/29/2015 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 5/11/2016 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 7/22/2014 <50 <1 <1 <1 <1 <1 <2.5 <1 NA <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 NA NA NA NA NA <5 <1 <1 <2 5/11/2016 <50 <1 <1 <1 <1 <1 <2.5 <1 <100 <1 <1 <1 <1 <10 <1 <10 <5 <1 <1 <50 <1 <5 <1 <20 <5 <1 <1 <2 8/14/2019 22 <0.048 <0.076 <0.076 <0.088 <0.11 <0.079 <0.066 <27 <0.061 <0.050 <0.054 <0.089 <0.24 <0.042 <0.078 <0.19 <0.087 <0.047 <0.72 <0.10 <0.64 <0.059 <0.25 <0.044 <0.054 <0.076 <0.15 11/13/2020 <0.31 <0.048 <0.076 <0.076 NA <0.11 <0.079 <0.066 <27 <0.061 <0.050 <0.054 <0.089 <0.24 <0.042 <0.078 <0.19 <0.087 <0.047 NA NA <0.64 NA NA <0.044 <0.054 <0.076 <0.15 3/22/2022 3/7/2023 6,000 1 70 70 70 NL 3 0.4 4,000 600 70 70 25 4,000 20 100 6 70 70 40 128 10 47 40 600 400 400 500 6,000,000 5,000 5,900 8,800 14,750 NL 3,000 400 4,000,000 80,000 70,000 30,500 11,700 4,000,000 20,000 100,000 6,000 26,100 70,000 40,000 128,000 10,000 47,000 40,000 260,000 28,500 24,100 50,000 Notes: 1)NL = Not Listed2)NA = Compound Not Analyzed for by Laboratory 3)NR = Compound Not Reported By Previous Consultants, or not included in analytical method suite4)ND = Compound Not Detected. 5)Result = Result Exceeds Laboratory Detection Limits Result = Result Exceeds 2L Standard Result = Result Exceeds GCL Value GCLs for Groundwater NOT SAMPLED - NO POWER TO WELL J = Compound detected above laboratory detection limite but below the laboratory reporting limit. NOT SAMPLED - NO POWER TO WELL GCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for Groundwater. All results provided in ug/L (micrograms per liter) or parts per billion. Compounds analyzed by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included in the Appendix for a full list of constituents. NOT SAMPLED NOT SAMPLED NC 2L Standard - North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L. MW-5 WSW-2 NC 2L Standard MW-4 WSW-12 WSW-11 Page 2 of 2 Easting NorthingWSW‐1 7880991864 5304 Liberty Rd Ruby F. Baker5304 Liberty RdGreensboro, NC 27406Potable(Active)Unknown Unknown 735 Up‐gradient 1789105.51 810035.78WSW‐2 7890091203 5607 Hagan Stone Park Rd Kim Simpson5607 Hagan Stone Park RdGreensboro, NC 27406Potable(Active)Unknown Unknown 335 Down‐gradient 1789956.58 809404.57WSW‐3 7880899807 5503‐A Chapparal DrFredrick W. & Ceyln P.Holt3906 Stonebrook FarmsGreensboro, NC 27406Potable(Active)Unknown Unknown 865 Up‐gradient 1788908.21 809919.35WSW‐4 7891002002 5401 Liberty RdCommunity in Christ Presbyterian Church5401 Liberty RdGreensboro, NC 27406Potable(Active)Unknown Unknown 710 Cross‐gradient 1790261.85 810114.81WSW‐5 7881908476 5409 Forest Oaks Dr Carolina Beasley5409 Forest Oaks DrGreensboro, NC 27406Non‐Potable Unknown Unknown 845 Cross‐gradient 1789815.41 810484.11WSW‐6 7881908578 5407 Forest Oaks DrWalter N. & Rhonda B.Mandrack5407 Forest Oaks DrGreensboro, NC 27406Potable(Active)Unknown Unknown 965 Cross‐gradient 1789813.00 810605.57WSW‐7 7890084808 5611 Hagan Stone Park Rd J. H. Thompson 5611 Hagan Stone Park RdPotable(Active)Unknown Unknown 805 Down‐gradient 1789988.80 808883.51WSW‐8 7890080425 5621 Hagan Stone Park Rd Lawrence Glenn Feir5621 Hagan Stone Park RdGreensboro, NC 27406Potable(Active)Unknown Unknown 1205 Down‐gradient 1789960.09 808463.53WSW‐9 7881906513 5408 Forest Oaks Dr Lornie May5408 Forest Oaks DrGreensboro, NC 27406Potable(Active)Unknown Unknown 925 Cross‐gradient 1789538.65 810551.46WSW‐10 7881908780 5405 Forest Oaks Dr Paul Johnson, Jr.5405 Forest Oaks DrGreensboro, NC 27406Potable(Active)Unknown Unknown 1080 Cross‐gradient 1789821.43 810721.02WSW‐11 7890093146 5410 Liberty Rd Timothy Simpson5410 Liberty RdGreensboro, NC 27406Potable(Active)Unknown Unknown 785 Down‐gradient 1790291.20 809100.56WSW‐12 7880993860 5306 Liberty RdBrotherhood Properties, LLC11 Edinburgh CtGreensboro, NC 27406Potable(Active)Unknown Unknown 400 Up‐gradient 1789336.65 809718.41WSW‐13 7880983611 5626 Hagan Ct Phillip & Donna Silvestri5626 Hagan CtGreensboro, NC 27406Potable(Active)Unknown Unknown 1030 Cross‐gradient 1789167.528 808780.0075WSW‐14 7880897712 5511 Chapparal Dr Ann Crutchfield5511 Chapparal DrGreensboro, NC 27406Potable(Active)Unknown Unknown 1050 Up‐gradient 1788677.07 809647.05       2.)  Information regarding the water supply well's use and location  obtained from Groundwater Monitoring Report Crawford Environmental Services, April 18, 2013.        3.)  WR has not performed a receptor survey in association with the subject property and thus the information provided above has not been verified. Well Screen Interval(feet)Notes:        1.)  Well location addresses and property owner address were obtained from the Guilford County GIS Department.  Property ownership data current as of September 10, 2019.Well IDWell Distance from Source Area(feet)Well Coordinates(NC State Plane NAD 83 Feet)ParcelNumberLocation Relative to Groundwater FlowProperty AddressIncident Number: 3298Well UseTABLE B‐5PUBLIC & PRIVATE WATER SUPPLY WELL INFORMATIONFOREST OAKS CIRCLE K5324 Liberty RoadGreensboro, Guilford County, NCProperty Owner Property Owner AddressWell Depth(feet)Page 1 of 1 Easting NorthingMW‐1 7/10/2009 2 22 7 7 ‐ 22 100.00 3/7/2023 6.13‐‐‐93.87 1789740.28 809691.81MW‐2 11/3/2009 2 17 7 7 ‐ 17 99.83 3/7/2023 7.25‐‐‐92.58 1789690.88 809722.76MW‐3 11/3/2009 2 17 7 7 ‐ 17 97.70 3/7/2023 4.20‐‐‐93.50 1789788.67 809601.04MW‐4 11/3/2009 2 14.5 4.5 4.5 ‐ 14.5 96.59 3/7/2023 3.54‐‐‐93.05 1789704.38 809568.03MW‐5 5/15/2012 2 16 6 6 ‐ 16 94.40 3/7/2023 3.03‐‐‐91.37 1789820.55 809582.821)2)3)Top‐of‐Casing Elevation      (feet)Well Casing Depth (feet)Well coordinates collected using a Trimble 2005 Series GeoXH GPS Unit.NM Denotes "Not Measured".Notes: Depth‐to‐Water from Top‐of‐Casing(feet)GroundwaterElevation      (feet)Top of Casing (TOC) elevations based on arbitrary 100 foot benchmark established at TOC for MW‐1 by S&ME, Inc., November 5, 2009.Free Product Thickness(feet)Well Casing Diameter(inches)Date InstalledTotal Depth     (feet)TABLE B‐75324 Liberty RoadMONITORING & REMEDIATION WELL CONSTRUCTION INFORMATIONDate Water Level MeasuredScreened Interval     (feet)Greensboro, Guilford County, NCWell IDWell Coordinates(NC State Plane NAD 83 Feet)FOREST OAKS CIRCLE KIncident Number: 3298Page 1 of 1 Well ID Screened Interval (feet) Top-of-Casing Elevation (feet) Date Water Level Measured Depth-to-LNAPL(feet) Depth-to-WaterUncorrected(feet) LNAPL Thickness(feet) Depth-to-WaterCorrected(feet) Groundwater SurfaceElevation (feet) 7/13/2009 ---7.15 ---7.15 92.85 11/5/2009 ---9.21 ---9.21 90.79 11/20/2009 ---7.97 ---7.97 92.03 6/28/2010 ---7.37 ---7.37 92.63 8/16/2011 ---9.16 ---9.16 90.84 7/5/2012 ---8.51 ---8.51 91.49 6/19/2013 ---6.19 ---6.19 93.81 7/22/2014 ---7.75 ---7.75 92.25 4/29/2015 ---6.60 ---6.60 93.40 5/11/2016 ---6.69 ---6.69 93.31 8/14/2019 ---7.23 ---7.23 92.77 11/13/2020 ---5.62 ---5.62 94.38 2/14/2022 (pre-MMPE)---8.05 ---8.05 91.95 2/18/2022 (post-MMPE)---4.70 ---4.70 95.30 3/22/2022 ---6.94 ---6.94 93.06 3/7/2023 ---6.13 ---6.13 93.87 11/5/2009 ---10.08 ---10.08 89.75 11/20/2009 ---8.97 ---8.97 90.86 6/28/2010 ---7.57 ---7.57 92.26 8/16/2011 ---10.28 ---10.28 89.55 7/5/2012 ---9.47 ---9.47 90.36 6/19/2013 ---6.99 ---6.99 92.84 7/22/2014 ---8.31 ---8.31 91.52 4/29/2015 ---7.74 ---7.74 92.09 5/11/2016 ---7.99 ---7.99 91.84 8/14/2019 ---7.22 ---7.22 92.61 11/13/2020 ---6.21 ---6.21 93.62 3/22/2022 ---8.27 ---8.27 91.56 3/7/2023 ---7.25 ---7.25 92.58 11/5/2009 ---7.71 ---7.71 89.99 11/20/2009 ---5.96 ---5.96 91.74 6/28/2010 ---6.06 ---6.06 91.64 8/16/2011 ---8.47 ---8.47 89.23 7/5/2012 ---8.15 ---8.15 89.55 6/19/2013 ---4.81 ---4.81 92.89 7/22/2014 ---7.80 ---7.80 89.90 4/29/2015 ---6.25 ---6.25 91.45 5/11/2016 ---5.39 ---5.39 92.31 8/14/2019 ---6.92 ---6.92 90.78 11/13/2020 ---3.23 ---3.23 94.47 2/14/2022 (pre-MMPE)---4.70 ---4.70 94.47 2/18/2022 (post-MMPE)---16.22 ---16.22 94.47 3/22/2022 ---6.81 ---6.81 90.89 3/7/2023 ---4.20 ---4.20 93.50 1)2)3) Incident Number: 3298 TABLE B-9CURRENT & HISTORICAL GROUNDWATER ELEVATIONS & FREE PRODUCT THICKNESSFOREST OAKS CIRCLE K 5324 Liberty RoadGreensboro, Guilford County, NC MW-2 MW-1 7 - 22 100.00 7 - 17 99.83 97.70MW-3 7 - 17 Notes: Top of Casing (TOC) elevations based on arbitrary 100 foot benchmark established at TOC for MW-1by S&ME, Inc., November 5, 2009.NM Denotes "Not Measured"WR Personnel were unable to locate MW-5 on August 14, 2019. Page 1 of 2 Well ID Screened Interval (feet) Top-of-Casing Elevation (feet) Date Water Level Measured Depth-to-LNAPL(feet) Depth-to-WaterUncorrected(feet) LNAPL Thickness(feet) Depth-to-WaterCorrected(feet) Groundwater SurfaceElevation (feet) Incident Number: 3298 TABLE B-9CURRENT & HISTORICAL GROUNDWATER ELEVATIONS & FREE PRODUCT THICKNESSFOREST OAKS CIRCLE K 5324 Liberty RoadGreensboro, Guilford County, NC 11/5/2009 ---4.84 ---4.84 91.75 11/20/2009 ---4.62 ---4.62 91.97 6/28/2010 ---5.34 ---5.34 91.25 8/16/2011 ---6.17 ---6.17 90.42 7/5/2012 ---6.34 ---6.34 90.25 6/19/2013 ---4.15 ---4.15 92.44 7/22/2014 ---5.82 ---5.82 90.77 4/29/2015 ---4.45 ---4.45 92.14 5/11/2016 ---4.11 ---4.11 92.48 8/14/2019 ---5.57 ---5.57 91.02 11/13/2020 ---3.19 ---3.19 93.40 3/22/2022 ---3.90 ---3.90 92.69 3/7/2023 ---3.54 ---3.54 93.05 7/5/2012 ---6.72 ---6.72 87.68 6/19/2013 ---6.83 ---6.83 87.57 7/22/2014 ---7.30 ---7.30 87.10 4/29/2015 ---3.65 ---3.65 90.75 5/11/2016 ---3.84 ---3.84 90.56 8/14/2019 ---NM ---NM NM 11/13/2020 ---3.31 ---3.31 91.09 3/22/2022 ---3.05 ---3.05 91.35 3/7/2023 ---3.03 ---3.03 91.37 1)2)3) Top of Casing (TOC) elevations based on arbitrary 100 foot benchmark established at TOC for MW-1by S&ME, Inc., November 5, 2009.NM Denotes "Not Measured"WR Personnel were unable to locate MW-5 on August 14, 2019. Notes: 4.5 - 14.5 96.59 94.40 MW-4 MW-5 6 - 16 Page 2 of 2 WithersRavenel Our People. Your Success. APPENDIX A FIELD NOTES & PHOTOGRAPHIC RECORD WithersRavenel Our People. Your Success. Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23-0307-K Groundwater Monitoring Report Photograph Date: March 7, 2023 PHOTO 1 Site facing west PHOTO 2 Location of MW-1 facing southwest WithersRavenel Our People. Your Success. Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23-0307-K Groundwater Monitoring Report Photograph Date: March 7, 2023 PHOTO 3 Location of MW-2 facing south PHOTO 4 Location of MW-3 facing west WithersRavenel Our People. Your Success. Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23-0307-K Groundwater Monitoring Report Photograph Date: March 7, 2023 PHOTO 5 Location of MW-4 facing northeast PHOTO 6 Location of MW-1 facing south (photo from March 2022) WithersRavenel Our People. Your Success. Forest Oaks Circle K – NCDEQ Inc. #3298 WR Project # 23-0307-K Groundwater Monitoring Report Photograph Date: March 7, 2023 PHOTO 7 Residence served by water supply well WSW-2 PHOTO 8 Residence served by water supply well WSW-12 WithersRavenel Our People. Your Success. APPENDIX B LABORATORY ANALYTICAL REPORT   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   3/20/2023 Withers & Ravenel Liz Allyn 115 Mackenan Dr. BUILDING 117 Cary, NC, 27511 Ref: Analytical Testing Lab Report Number: 23-069-0106 Client Project Description: Forest Oaks Circle K Dear Liz Allyn: Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/10/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 43 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/23-069-0106 Page 2 of 43 Report Number: Sample Summary Table Client Project Description: 23-069-0106 Forest Oaks Circle K Lab No Client Sample ID Matrix Date Collected Date Received 03/07/2023 14:25Aqueous 90875 MW-1 03/10/2023 12:30 03/07/2023 13:40Aqueous 90876 MW-2 03/10/2023 12:30 03/07/2023 11:45Aqueous 90877 MW-3 03/10/2023 12:30 03/07/2023 13:05Aqueous 90878 MW-4 03/10/2023 12:30 03/07/2023 12:25Aqueous 90879 MW-5 03/10/2023 12:30 03/07/2023 15:30Aqueous 90880 WSW-2 03/10/2023 12:30 03/07/2023 14:50Aqueous 90881 Field Blank 03/10/2023 12:30 Page 3 of 43 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-069-0106 Report Limit Project:Forest Oaks Circle K V 90875MW-1 3090 03/17/2023 23:176200BBenzeneµg/L 50.0 11.0 03/16/2023 21:136200Bn-Butylbenzene µg/L 5.00 5.93 03/16/2023 21:136200Bsec-Butyl benzene µg/L 5.00 116 03/16/2023 21:136200BChloromethaneµg/L 5.00 227 03/16/2023 21:136200BDi-Isopropyl Ether (DIPE)µg/L 5.00 2510 03/17/2023 23:176200BEthylbenzeneµg/L 50.0 59.7 03/16/2023 21:136200BIsopropylbenzeneµg/L 5.00 5.25 03/16/2023 21:136200B4-Isopropyl toluene µg/L 5.00 16.6 03/16/2023 21:136200BMethyl tert-butyl ether (MTBE)µg/L 10.0 752 03/16/2023 21:136200BNaphthaleneµg/L 10.0 153 03/16/2023 21:136200Bn-Propylbenzene µg/L 5.00 10.8 03/16/2023 21:136200BStyreneµg/L 5.00 1400 03/17/2023 23:176200BTolueneµg/L 50.0 701 03/16/2023 21:136200B1,2,4-Trimethylbenzene µg/L 5.00 200 03/16/2023 21:136200B1,3,5-Trimethylbenzene µg/L 5.00 709 03/16/2023 21:136200Bo-Xylene µg/L 5.00 3970 03/17/2023 23:176200Bm,p-Xylene µg/L 100 4680 03/16/2023 21:136200BXylene (Total)µg/L 5.00 V 90876MW-2 47.7 03/16/2023 17:136200BDi-Isopropyl Ether (DIPE)µg/L 0.500 3.00 03/16/2023 17:136200BMethyl tert-butyl ether (MTBE)µg/L 1.00 64.5 03/16/2023 17:136200Btert-Butyl Alcohol (TBA)µg/L 10.0 V 90877MW-3 3230 03/16/2023 22:016200BBenzeneµg/L 50.0 616 03/16/2023 22:016200Bn-Butylbenzene µg/L 50.0 170 03/16/2023 22:016200Bsec-Butyl benzene µg/L 50.0 76.9 03/16/2023 22:016200BDi-Isopropyl Ether (DIPE)µg/L 50.0 3900 03/16/2023 22:016200BEthylbenzeneµg/L 50.0 340 03/16/2023 22:016200BIsopropylbenzeneµg/L 50.0 98.1 03/16/2023 22:016200B4-Isopropyl toluene µg/L 50.0 389 03/16/2023 22:016200B4-Methyl-2-Pentanone µg/L 100 2280 03/16/2023 22:016200BNaphthaleneµg/L 100 1340 03/16/2023 22:016200Bn-Propylbenzene µg/L 50.0 3750 03/16/2023 22:016200BTolueneµg/L 50.0 7170 03/16/2023 22:016200B1,2,4-Trimethylbenzene µg/L 50.0 2270 03/16/2023 22:016200B1,3,5-Trimethylbenzene µg/L 50.0 Page 4 of 43 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-069-0106 Report Limit Project:Forest Oaks Circle K V 90877MW-3 2620 03/16/2023 22:016200Bo-Xylene µg/L 50.0 10600 03/16/2023 22:016200Bm,p-Xylene µg/L 100 13200 03/16/2023 22:016200BXylene (Total)µg/L 50.0 Page 5 of 43   Client: Withers & Ravenel CASE NARRATIVE Project: Forest Oaks Circle K Lab Report Number: 23-069-0106 Date: 3/20/2023 Volatile Organic Compounds - GC/MS Method 6200B Analyte: tert-Amyl Methyl Ether QC Batch No: V30957/V30955 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Page 6 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-1 90875 Matrix: 3/7/2023 14:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <100 µg/L 100Acetone 10 03/16/23 21:13 6200BENM 3090 µg/L 50.0Benzene 100 03/17/23 23:17 6200BMSA <5.00 µg/L 5.00Bromobenzene 10 03/16/23 21:13 6200BENM <10.0 µg/L 10.0Bromochloromethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Bromodichloromethane 10 03/16/23 21:13 6200BENM <50.0 µg/L 50.0Bromoform 10 03/16/23 21:13 6200BENM <10.0 µg/L 10.0Bromomethane 10 03/16/23 21:13 6200BENM 11.0 µg/L 5.00n-Butylbenzene 10 03/16/23 21:13 6200BENM 5.93 µg/L 5.00sec-Butyl benzene 10 03/16/23 21:13 6200BENM <20.0 µg/L 20.0tert-Butyl benzene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Carbon Tetrachloride 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Chlorobenzene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Chlorodibromomethane 10 03/16/23 21:13 6200BENM <10.0 µg/L 10.0Chloroethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Chloroform 10 03/16/23 21:13 6200BENM 116 µg/L 5.00Chloromethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.002-Chlorotoluene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.004-Chlorotoluene 10 03/16/23 21:13 6200BENM <20.0 µg/L 20.01,2-Dibromo-3-Chloropropane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,2-Dibromoethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Dibromomethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,2-Dichlorobenzene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,3-Dichlorobenzene 10 03/16/23 21:13 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 7 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-1 90875 Matrix: 3/7/2023 14:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <5.00 µg/L 5.001,4-Dichlorobenzene 10 03/16/23 21:13 6200BENM <50.0 µg/L 50.0Dichlorodifluoromethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,1-Dichloroethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,2-Dichloroethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,1-Dichloroethene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00cis-1,2-Dichloroethene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00trans-1,2-Dichloroethene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,2-Dichloropropane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,3-Dichloropropane 10 03/16/23 21:13 6200BENM <20.0 µg/L 20.02,2-Dichloropropane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,1-Dichloropropene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00cis-1,3-Dichloropropene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00trans-1,3-Dichloropropene 10 03/16/23 21:13 6200BENM <2000 µg/L 2000Ethanol 10 03/16/23 21:13 6200BENM 2510 µg/L 50.0Ethylbenzene 100 03/17/23 23:17 6200BMSA <30.0 µg/L 30.0Hexachlorobutadiene 10 03/16/23 21:13 6200BENM 227 µg/L 5.00Di-Isopropyl Ether (DIPE)10 03/16/23 21:13 6200BENM 59.7 µg/L 5.00Isopropylbenzene 10 03/16/23 21:13 6200BENM 5.25 µg/L 5.004-Isopropyl toluene 10 03/16/23 21:13 6200BENM <10.0 µg/L 10.02-Hexanone 10 03/16/23 21:13 6200BENM <50.0 µg/L 50.0Methyl Ethyl Ketone (MEK)10 03/16/23 21:13 6200BENM <20.0 µg/L 20.0Methylene Chloride 10 03/16/23 21:13 6200BENM 16.6 µg/L 10.0Methyl tert-butyl ether (MTBE)10 03/16/23 21:13 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 8 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-1 90875 Matrix: 3/7/2023 14:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <10.0 µg/L 10.04-Methyl-2-Pentanone 10 03/16/23 21:13 6200BENM 752 µg/L 10.0Naphthalene 10 03/16/23 21:13 6200BENM 153 µg/L 5.00n-Propylbenzene 10 03/16/23 21:13 6200BENM 10.8 µg/L 5.00Styrene 10 03/16/23 21:13 6200BENM <1000 µg/L 1000tert-Amyl Alcohol (TAA)100 03/17/23 23:17 6200BMSA <100 µg/L 100tert-Amyl Methyl Ether (TAME)10 03/16/23 21:13 6200BENM <100 µg/L 100tert-Butyl Alcohol (TBA)10 03/16/23 21:13 6200BENM <100 µg/L 100Ethyl Tertiary Butyl Ether (ETBE)10 03/16/23 21:13 6200BENM <100 µg/L 100tert-Butyl formate (TBF)10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,1,1,2-Tetrachloroethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,1,2,2-Tetrachloroethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Tetrachloroethene 10 03/16/23 21:13 6200BENM 1400 µg/L 50.0Toluene 100 03/17/23 23:17 6200BMSA <5.00 µg/L 5.001,2,3-Trichlorobenzene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,2,4-Trichlorobenzene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,1,1-Trichloroethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,1,2-Trichloroethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Trichloroethene 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.00Trichlorofluoromethane 10 03/16/23 21:13 6200BENM <5.00 µg/L 5.001,2,3-Trichloropropane 10 03/16/23 21:13 6200BENM 701 µg/L 5.001,2,4-Trimethylbenzene 10 03/16/23 21:13 6200BENM 200 µg/L 5.001,3,5-Trimethylbenzene 10 03/16/23 21:13 6200BENM <50.0 µg/L 50.0Vinyl Acetate 10 03/16/23 21:13 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 9 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-1 90875 Matrix: 3/7/2023 14:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <5.00 µg/L 5.00Vinyl Chloride 10 03/16/23 21:13 6200BENM 3970 µg/L 100m,p-Xylene 100 03/17/23 23:17 6200BMSA 709 µg/L 5.00o-Xylene 10 03/16/23 21:13 6200BENM 4680 µg/L 5.00Xylene (Total)10 03/16/23 21:13 6200B Surrogate: 4-Bromofluorobenzene 90.4 Limits: 70-130%03/16/23 21:1310 ENM V30957 Surrogate: Dibromofluoromethane 95.4 Limits: 70-130%03/16/23 21:1310 ENM V30957 Surrogate: 1,2-Dichloroethane - d4 92.8 Limits: 70-130%03/16/23 21:1310 ENM V30957 Surrogate: Toluene-d8 85.6 Limits: 70-130%03/16/23 21:1310 ENM V30957 Surrogate: 4-Bromofluorobenzene 95.4 Limits: 70-130%03/17/23 23:17100 MSA V30984 Surrogate: Dibromofluoromethane 86.6 Limits: 70-130%03/17/23 23:17100 MSA V30984 Surrogate: 1,2-Dichloroethane - d4 89.0 Limits: 70-130%03/17/23 23:17100 MSA V30984 Surrogate: Toluene-d8 98.4 Limits: 70-130%03/17/23 23:17100 MSA V30984 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 10 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-2 90876 Matrix: 3/7/2023 13:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <10.0 µg/L 10.0Acetone 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Benzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Bromobenzene 1 03/16/23 17:13 6200BENM <1.00 µg/L 1.00Bromochloromethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Bromodichloromethane 1 03/16/23 17:13 6200BENM <5.00 µg/L 5.00Bromoform 1 03/16/23 17:13 6200BENM <1.00 µg/L 1.00Bromomethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500n-Butylbenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500sec-Butyl benzene 1 03/16/23 17:13 6200BENM <2.00 µg/L 2.00tert-Butyl benzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Carbon Tetrachloride 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Chlorobenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Chlorodibromomethane 1 03/16/23 17:13 6200BENM <1.00 µg/L 1.00Chloroethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Chloroform 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Chloromethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5002-Chlorotoluene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5004-Chlorotoluene 1 03/16/23 17:13 6200BENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2-Dibromoethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Dibromomethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2-Dichlorobenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 03/16/23 17:13 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 11 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-2 90876 Matrix: 3/7/2023 13:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.5001,4-Dichlorobenzene 1 03/16/23 17:13 6200BENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,1-Dichloroethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2-Dichloroethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,1-Dichloroethene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2-Dichloropropane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,3-Dichloropropane 1 03/16/23 17:13 6200BENM <2.00 µg/L 2.002,2-Dichloropropane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,1-Dichloropropene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 03/16/23 17:13 6200BENM <200 µg/L 200Ethanol 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Ethylbenzene 1 03/16/23 17:13 6200BENM <3.00 µg/L 3.00Hexachlorobutadiene 1 03/16/23 17:13 6200BENM 47.7 µg/L 0.500Di-Isopropyl Ether (DIPE)1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Isopropylbenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5004-Isopropyl toluene 1 03/16/23 17:13 6200BENM <1.00 µg/L 1.002-Hexanone 1 03/16/23 17:13 6200BENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 03/16/23 17:13 6200BENM <2.00 µg/L 2.00Methylene Chloride 1 03/16/23 17:13 6200BENM 3.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 03/16/23 17:13 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 12 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-2 90876 Matrix: 3/7/2023 13:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1.00 µg/L 1.004-Methyl-2-Pentanone 1 03/16/23 17:13 6200BENM <1.00 µg/L 1.00Naphthalene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500n-Propylbenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Styrene 1 03/16/23 17:13 6200BENM <1000 µg/L 1000tert-Amyl Alcohol (TAA)100 03/17/23 23:45 6200BMSA <10.0 µg/L 10.0tert-Amyl Methyl Ether (TAME)1 03/16/23 17:13 6200BENM 64.5 µg/L 10.0tert-Butyl Alcohol (TBA)1 03/16/23 17:13 6200BENM <10.0 µg/L 10.0Ethyl Tertiary Butyl Ether (ETBE)1 03/16/23 17:13 6200BENM <10.0 µg/L 10.0tert-Butyl formate (TBF)1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Tetrachloroethene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Toluene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Trichloroethene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Trichlorofluoromethane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 03/16/23 17:13 6200BENM <5.00 µg/L 5.00Vinyl Acetate 1 03/16/23 17:13 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 13 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-2 90876 Matrix: 3/7/2023 13:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.500Vinyl Chloride 1 03/16/23 17:13 6200BENM <1.00 µg/L 1.00m,p-Xylene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500o-Xylene 1 03/16/23 17:13 6200BENM <0.500 µg/L 0.500Xylene (Total)1 03/16/23 17:13 6200B Surrogate: 4-Bromofluorobenzene 90.2 Limits: 70-130%03/16/23 17:131 ENM V30957 Surrogate: Dibromofluoromethane 93.0 Limits: 70-130%03/16/23 17:131 ENM V30957 Surrogate: 1,2-Dichloroethane - d4 82.6 Limits: 70-130%03/16/23 17:131 ENM V30957 Surrogate: Toluene-d8 88.6 Limits: 70-130%03/16/23 17:131 ENM V30957 Surrogate: 4-Bromofluorobenzene 95.2 Limits: 70-130%03/17/23 23:45100 MSA V30984 Surrogate: Dibromofluoromethane 87.4 Limits: 70-130%03/17/23 23:45100 MSA V30984 Surrogate: 1,2-Dichloroethane - d4 91.2 Limits: 70-130%03/17/23 23:45100 MSA V30984 Surrogate: Toluene-d8 97.8 Limits: 70-130%03/17/23 23:45100 MSA V30984 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 14 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-3 90877 Matrix: 3/7/2023 11:45 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1000 µg/L 1000Acetone 100 03/16/23 22:01 6200BENM 3230 µg/L 50.0Benzene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Bromobenzene 100 03/16/23 22:01 6200BENM <100 µg/L 100Bromochloromethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Bromodichloromethane 100 03/16/23 22:01 6200BENM <500 µg/L 500Bromoform 100 03/16/23 22:01 6200BENM <100 µg/L 100Bromomethane 100 03/16/23 22:01 6200BENM 616 µg/L 50.0n-Butylbenzene 100 03/16/23 22:01 6200BENM 170 µg/L 50.0sec-Butyl benzene 100 03/16/23 22:01 6200BENM <200 µg/L 200tert-Butyl benzene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Carbon Tetrachloride 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Chlorobenzene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Chlorodibromomethane 100 03/16/23 22:01 6200BENM <100 µg/L 100Chloroethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Chloroform 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Chloromethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.02-Chlorotoluene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.04-Chlorotoluene 100 03/16/23 22:01 6200BENM <200 µg/L 2001,2-Dibromo-3-Chloropropane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,2-Dibromoethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Dibromomethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,2-Dichlorobenzene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,3-Dichlorobenzene 100 03/16/23 22:01 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 15 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-3 90877 Matrix: 3/7/2023 11:45 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <50.0 µg/L 50.01,4-Dichlorobenzene 100 03/16/23 22:01 6200BENM <500 µg/L 500Dichlorodifluoromethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,1-Dichloroethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,2-Dichloroethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,1-Dichloroethene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0cis-1,2-Dichloroethene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0trans-1,2-Dichloroethene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,2-Dichloropropane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,3-Dichloropropane 100 03/16/23 22:01 6200BENM <200 µg/L 2002,2-Dichloropropane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,1-Dichloropropene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0cis-1,3-Dichloropropene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0trans-1,3-Dichloropropene 100 03/16/23 22:01 6200BENM <20000 µg/L 20000Ethanol 100 03/16/23 22:01 6200BENM 3900 µg/L 50.0Ethylbenzene 100 03/16/23 22:01 6200BENM <300 µg/L 300Hexachlorobutadiene 100 03/16/23 22:01 6200BENM 76.9 µg/L 50.0Di-Isopropyl Ether (DIPE)100 03/16/23 22:01 6200BENM 340 µg/L 50.0Isopropylbenzene 100 03/16/23 22:01 6200BENM 98.1 µg/L 50.04-Isopropyl toluene 100 03/16/23 22:01 6200BENM <100 µg/L 1002-Hexanone 100 03/16/23 22:01 6200BENM <500 µg/L 500Methyl Ethyl Ketone (MEK)100 03/16/23 22:01 6200BENM <200 µg/L 200Methylene Chloride 100 03/16/23 22:01 6200BENM <100 µg/L 100Methyl tert-butyl ether (MTBE)100 03/16/23 22:01 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 16 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-3 90877 Matrix: 3/7/2023 11:45 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF 389 µg/L 1004-Methyl-2-Pentanone 100 03/16/23 22:01 6200BENM 2280 µg/L 100Naphthalene 100 03/16/23 22:01 6200BENM 1340 µg/L 50.0n-Propylbenzene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Styrene 100 03/16/23 22:01 6200BENM <1000 µg/L 1000tert-Amyl Alcohol (TAA)100 03/16/23 22:01 6200BENM <1000 µg/L 1000tert-Amyl Methyl Ether (TAME)100 03/16/23 22:01 6200BENM <1000 µg/L 1000tert-Butyl Alcohol (TBA)100 03/16/23 22:01 6200BENM <1000 µg/L 1000Ethyl Tertiary Butyl Ether (ETBE)100 03/16/23 22:01 6200BENM <1000 µg/L 1000tert-Butyl formate (TBF)100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Tetrachloroethene 100 03/16/23 22:01 6200BENM 3750 µg/L 50.0Toluene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,2,3-Trichlorobenzene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,2,4-Trichlorobenzene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,1,1-Trichloroethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,1,2-Trichloroethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Trichloroethene 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.0Trichlorofluoromethane 100 03/16/23 22:01 6200BENM <50.0 µg/L 50.01,2,3-Trichloropropane 100 03/16/23 22:01 6200BENM 7170 µg/L 50.01,2,4-Trimethylbenzene 100 03/16/23 22:01 6200BENM 2270 µg/L 50.01,3,5-Trimethylbenzene 100 03/16/23 22:01 6200BENM <500 µg/L 500Vinyl Acetate 100 03/16/23 22:01 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 17 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-3 90877 Matrix: 3/7/2023 11:45 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <50.0 µg/L 50.0Vinyl Chloride 100 03/16/23 22:01 6200BENM 10600 µg/L 100m,p-Xylene 100 03/16/23 22:01 6200BENM 2620 µg/L 50.0o-Xylene 100 03/16/23 22:01 6200BENM 13200 µg/L 50.0Xylene (Total)100 03/16/23 22:01 6200B Surrogate: 4-Bromofluorobenzene 92.2 Limits: 70-130%03/16/23 22:01100 ENM V30957 Surrogate: Dibromofluoromethane 94.8 Limits: 70-130%03/16/23 22:01100 ENM V30957 Surrogate: 1,2-Dichloroethane - d4 87.8 Limits: 70-130%03/16/23 22:01100 ENM V30957 Surrogate: Toluene-d8 89.2 Limits: 70-130%03/16/23 22:01100 ENM V30957 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 18 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-4 90878 Matrix: 3/7/2023 13:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <10.0 µg/L 10.0Acetone 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Benzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Bromobenzene 1 03/16/23 17:37 6200BENM <1.00 µg/L 1.00Bromochloromethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Bromodichloromethane 1 03/16/23 17:37 6200BENM <5.00 µg/L 5.00Bromoform 1 03/16/23 17:37 6200BENM <1.00 µg/L 1.00Bromomethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500n-Butylbenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500sec-Butyl benzene 1 03/16/23 17:37 6200BENM <2.00 µg/L 2.00tert-Butyl benzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Carbon Tetrachloride 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Chlorobenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Chlorodibromomethane 1 03/16/23 17:37 6200BENM <1.00 µg/L 1.00Chloroethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Chloroform 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Chloromethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5002-Chlorotoluene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5004-Chlorotoluene 1 03/16/23 17:37 6200BENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2-Dibromoethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Dibromomethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2-Dichlorobenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 03/16/23 17:37 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 19 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-4 90878 Matrix: 3/7/2023 13:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.5001,4-Dichlorobenzene 1 03/16/23 17:37 6200BENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,1-Dichloroethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2-Dichloroethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,1-Dichloroethene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2-Dichloropropane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,3-Dichloropropane 1 03/16/23 17:37 6200BENM <2.00 µg/L 2.002,2-Dichloropropane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,1-Dichloropropene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 03/16/23 17:37 6200BENM <200 µg/L 200Ethanol 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Ethylbenzene 1 03/16/23 17:37 6200BENM <3.00 µg/L 3.00Hexachlorobutadiene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Isopropylbenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5004-Isopropyl toluene 1 03/16/23 17:37 6200BENM <1.00 µg/L 1.002-Hexanone 1 03/16/23 17:37 6200BENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 03/16/23 17:37 6200BENM <2.00 µg/L 2.00Methylene Chloride 1 03/16/23 17:37 6200BENM <1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 03/16/23 17:37 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 20 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-4 90878 Matrix: 3/7/2023 13:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1.00 µg/L 1.004-Methyl-2-Pentanone 1 03/16/23 17:37 6200BENM <1.00 µg/L 1.00Naphthalene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500n-Propylbenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Styrene 1 03/16/23 17:37 6200BENM <10.0 µg/L 10.0tert-Amyl Alcohol (TAA)1 03/16/23 17:37 6200BENM <10.0 µg/L 10.0tert-Amyl Methyl Ether (TAME)1 03/16/23 17:37 6200BENM <10.0 µg/L 10.0tert-Butyl Alcohol (TBA)1 03/16/23 17:37 6200BENM <10.0 µg/L 10.0Ethyl Tertiary Butyl Ether (ETBE)1 03/16/23 17:37 6200BENM <10.0 µg/L 10.0tert-Butyl formate (TBF)1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Tetrachloroethene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Toluene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Trichloroethene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Trichlorofluoromethane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 03/16/23 17:37 6200BENM <5.00 µg/L 5.00Vinyl Acetate 1 03/16/23 17:37 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 21 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-4 90878 Matrix: 3/7/2023 13:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.500Vinyl Chloride 1 03/16/23 17:37 6200BENM <1.00 µg/L 1.00m,p-Xylene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500o-Xylene 1 03/16/23 17:37 6200BENM <0.500 µg/L 0.500Xylene (Total)1 03/16/23 17:37 6200B Surrogate: 4-Bromofluorobenzene 87.2 Limits: 70-130%03/16/23 17:371 ENM V30957 Surrogate: Dibromofluoromethane 91.2 Limits: 70-130%03/16/23 17:371 ENM V30957 Surrogate: 1,2-Dichloroethane - d4 80.2 Limits: 70-130%03/16/23 17:371 ENM V30957 Surrogate: Toluene-d8 93.0 Limits: 70-130%03/16/23 17:371 ENM V30957 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 22 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-5 90879 Matrix: 3/7/2023 12:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <10.0 µg/L 10.0Acetone 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Benzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Bromobenzene 1 03/16/23 18:01 6200BENM <1.00 µg/L 1.00Bromochloromethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Bromodichloromethane 1 03/16/23 18:01 6200BENM <5.00 µg/L 5.00Bromoform 1 03/16/23 18:01 6200BENM <1.00 µg/L 1.00Bromomethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500n-Butylbenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500sec-Butyl benzene 1 03/16/23 18:01 6200BENM <2.00 µg/L 2.00tert-Butyl benzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Carbon Tetrachloride 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Chlorobenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Chlorodibromomethane 1 03/16/23 18:01 6200BENM <1.00 µg/L 1.00Chloroethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Chloroform 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Chloromethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5002-Chlorotoluene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5004-Chlorotoluene 1 03/16/23 18:01 6200BENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2-Dibromoethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Dibromomethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2-Dichlorobenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 03/16/23 18:01 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 23 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-5 90879 Matrix: 3/7/2023 12:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.5001,4-Dichlorobenzene 1 03/16/23 18:01 6200BENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,1-Dichloroethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2-Dichloroethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,1-Dichloroethene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2-Dichloropropane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,3-Dichloropropane 1 03/16/23 18:01 6200BENM <2.00 µg/L 2.002,2-Dichloropropane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,1-Dichloropropene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 03/16/23 18:01 6200BENM <200 µg/L 200Ethanol 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Ethylbenzene 1 03/16/23 18:01 6200BENM <3.00 µg/L 3.00Hexachlorobutadiene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Isopropylbenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5004-Isopropyl toluene 1 03/16/23 18:01 6200BENM <1.00 µg/L 1.002-Hexanone 1 03/16/23 18:01 6200BENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 03/16/23 18:01 6200BENM <2.00 µg/L 2.00Methylene Chloride 1 03/16/23 18:01 6200BENM <1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 03/16/23 18:01 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 24 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-5 90879 Matrix: 3/7/2023 12:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1.00 µg/L 1.004-Methyl-2-Pentanone 1 03/16/23 18:01 6200BENM <1.00 µg/L 1.00Naphthalene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500n-Propylbenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Styrene 1 03/16/23 18:01 6200BENM <10.0 µg/L 10.0tert-Amyl Alcohol (TAA)1 03/16/23 18:01 6200BENM <10.0 µg/L 10.0tert-Amyl Methyl Ether (TAME)1 03/16/23 18:01 6200BENM <10.0 µg/L 10.0tert-Butyl Alcohol (TBA)1 03/16/23 18:01 6200BENM <10.0 µg/L 10.0Ethyl Tertiary Butyl Ether (ETBE)1 03/16/23 18:01 6200BENM <10.0 µg/L 10.0tert-Butyl formate (TBF)1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Tetrachloroethene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Toluene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Trichloroethene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Trichlorofluoromethane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 03/16/23 18:01 6200BENM <5.00 µg/L 5.00Vinyl Acetate 1 03/16/23 18:01 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 25 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:MW-5 90879 Matrix: 3/7/2023 12:25 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.500Vinyl Chloride 1 03/16/23 18:01 6200BENM <1.00 µg/L 1.00m,p-Xylene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500o-Xylene 1 03/16/23 18:01 6200BENM <0.500 µg/L 0.500Xylene (Total)1 03/16/23 18:01 6200B Surrogate: 4-Bromofluorobenzene 88.6 Limits: 70-130%03/16/23 18:011 ENM V30957 Surrogate: Dibromofluoromethane 93.4 Limits: 70-130%03/16/23 18:011 ENM V30957 Surrogate: 1,2-Dichloroethane - d4 86.2 Limits: 70-130%03/16/23 18:011 ENM V30957 Surrogate: Toluene-d8 89.4 Limits: 70-130%03/16/23 18:011 ENM V30957 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 26 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:WSW-2 90880 Matrix: 3/7/2023 15:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <10.0 µg/L 10.0Acetone 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Benzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Bromobenzene 1 03/16/23 18:25 6200BENM <1.00 µg/L 1.00Bromochloromethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Bromodichloromethane 1 03/16/23 18:25 6200BENM <5.00 µg/L 5.00Bromoform 1 03/16/23 18:25 6200BENM <1.00 µg/L 1.00Bromomethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500n-Butylbenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500sec-Butyl benzene 1 03/16/23 18:25 6200BENM <2.00 µg/L 2.00tert-Butyl benzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Carbon Tetrachloride 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Chlorobenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Chlorodibromomethane 1 03/16/23 18:25 6200BENM <1.00 µg/L 1.00Chloroethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Chloroform 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Chloromethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5002-Chlorotoluene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5004-Chlorotoluene 1 03/16/23 18:25 6200BENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2-Dibromoethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Dibromomethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2-Dichlorobenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 03/16/23 18:25 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 27 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:WSW-2 90880 Matrix: 3/7/2023 15:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.5001,4-Dichlorobenzene 1 03/16/23 18:25 6200BENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,1-Dichloroethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2-Dichloroethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,1-Dichloroethene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2-Dichloropropane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,3-Dichloropropane 1 03/16/23 18:25 6200BENM <2.00 µg/L 2.002,2-Dichloropropane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,1-Dichloropropene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 03/16/23 18:25 6200BENM <200 µg/L 200Ethanol 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Ethylbenzene 1 03/16/23 18:25 6200BENM <3.00 µg/L 3.00Hexachlorobutadiene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Isopropylbenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5004-Isopropyl toluene 1 03/16/23 18:25 6200BENM <1.00 µg/L 1.002-Hexanone 1 03/16/23 18:25 6200BENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 03/16/23 18:25 6200BENM <2.00 µg/L 2.00Methylene Chloride 1 03/16/23 18:25 6200BENM <1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 03/16/23 18:25 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 28 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:WSW-2 90880 Matrix: 3/7/2023 15:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1.00 µg/L 1.004-Methyl-2-Pentanone 1 03/16/23 18:25 6200BENM <1.00 µg/L 1.00Naphthalene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500n-Propylbenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Styrene 1 03/16/23 18:25 6200BENM <10.0 µg/L 10.0tert-Amyl Alcohol (TAA)1 03/16/23 18:25 6200BENM <10.0 µg/L 10.0tert-Amyl Methyl Ether (TAME)1 03/16/23 18:25 6200BENM <10.0 µg/L 10.0tert-Butyl Alcohol (TBA)1 03/16/23 18:25 6200BENM <10.0 µg/L 10.0Ethyl Tertiary Butyl Ether (ETBE)1 03/16/23 18:25 6200BENM <10.0 µg/L 10.0tert-Butyl formate (TBF)1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Tetrachloroethene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Toluene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Trichloroethene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Trichlorofluoromethane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 03/16/23 18:25 6200BENM <5.00 µg/L 5.00Vinyl Acetate 1 03/16/23 18:25 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 29 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:WSW-2 90880 Matrix: 3/7/2023 15:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.500Vinyl Chloride 1 03/16/23 18:25 6200BENM <1.00 µg/L 1.00m,p-Xylene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500o-Xylene 1 03/16/23 18:25 6200BENM <0.500 µg/L 0.500Xylene (Total)1 03/16/23 18:25 6200B Surrogate: 4-Bromofluorobenzene 90.2 Limits: 70-130%03/16/23 18:251 ENM V30957 Surrogate: Dibromofluoromethane 92.2 Limits: 70-130%03/16/23 18:251 ENM V30957 Surrogate: 1,2-Dichloroethane - d4 80.2 Limits: 70-130%03/16/23 18:251 ENM V30957 Surrogate: Toluene-d8 91.2 Limits: 70-130%03/16/23 18:251 ENM V30957 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 30 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:Field Blank 90881 Matrix: 3/7/2023 14:50 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <10.0 µg/L 10.0Acetone 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Benzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Bromobenzene 1 03/16/23 14:25 6200BENM <1.00 µg/L 1.00Bromochloromethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Bromodichloromethane 1 03/16/23 14:25 6200BENM <5.00 µg/L 5.00Bromoform 1 03/16/23 14:25 6200BENM <1.00 µg/L 1.00Bromomethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500n-Butylbenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500sec-Butyl benzene 1 03/16/23 14:25 6200BENM <2.00 µg/L 2.00tert-Butyl benzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Carbon Tetrachloride 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Chlorobenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Chlorodibromomethane 1 03/16/23 14:25 6200BENM <1.00 µg/L 1.00Chloroethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Chloroform 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Chloromethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5002-Chlorotoluene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5004-Chlorotoluene 1 03/16/23 14:25 6200BENM <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2-Dibromoethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Dibromomethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2-Dichlorobenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,3-Dichlorobenzene 1 03/16/23 14:25 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 31 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:Field Blank 90881 Matrix: 3/7/2023 14:50 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.5001,4-Dichlorobenzene 1 03/16/23 14:25 6200BENM <5.00 µg/L 5.00Dichlorodifluoromethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,1-Dichloroethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2-Dichloroethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,1-Dichloroethene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2-Dichloropropane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,3-Dichloropropane 1 03/16/23 14:25 6200BENM <2.00 µg/L 2.002,2-Dichloropropane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,1-Dichloropropene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 03/16/23 14:25 6200BENM <200 µg/L 200Ethanol 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Ethylbenzene 1 03/16/23 14:25 6200BENM <3.00 µg/L 3.00Hexachlorobutadiene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Isopropylbenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5004-Isopropyl toluene 1 03/16/23 14:25 6200BENM <1.00 µg/L 1.002-Hexanone 1 03/16/23 14:25 6200BENM <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 03/16/23 14:25 6200BENM <2.00 µg/L 2.00Methylene Chloride 1 03/16/23 14:25 6200BENM <1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 03/16/23 14:25 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 32 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:Field Blank 90881 Matrix: 3/7/2023 14:50 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1.00 µg/L 1.004-Methyl-2-Pentanone 1 03/16/23 14:25 6200BENM <1.00 µg/L 1.00Naphthalene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500n-Propylbenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Styrene 1 03/16/23 14:25 6200BENM <10.0 µg/L 10.0tert-Amyl Alcohol (TAA)1 03/16/23 14:25 6200BENM <10.0 µg/L 10.0tert-Amyl Methyl Ether (TAME)1 03/16/23 14:25 6200BENM <10.0 µg/L 10.0tert-Butyl Alcohol (TBA)1 03/16/23 14:25 6200BENM <10.0 µg/L 10.0Ethyl Tertiary Butyl Ether (ETBE)1 03/16/23 14:25 6200BENM <10.0 µg/L 10.0tert-Butyl formate (TBF)1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Tetrachloroethene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Toluene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,1,1-Trichloroethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,1,2-Trichloroethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Trichloroethene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Trichlorofluoromethane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2,3-Trichloropropane 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 03/16/23 14:25 6200BENM <5.00 µg/L 5.00Vinyl Acetate 1 03/16/23 14:25 6200BENM Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 33 of 43 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-069-0106 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary Received : 03/10/2023 Forest Oaks Circle K Report Date : 03/20/2023 Sample ID : Lab No : Sampled:Field Blank 90881 Matrix: 3/7/2023 14:50 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.500Vinyl Chloride 1 03/16/23 14:25 6200BENM <1.00 µg/L 1.00m,p-Xylene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500o-Xylene 1 03/16/23 14:25 6200BENM <0.500 µg/L 0.500Xylene (Total)1 03/16/23 14:25 6200B Surrogate: 4-Bromofluorobenzene 89.4 Limits: 70-130%03/16/23 14:251 ENM V30957 Surrogate: Dibromofluoromethane 92.6 Limits: 70-130%03/16/23 14:251 ENM V30957 Surrogate: 1,2-Dichloroethane - d4 81.2 Limits: 70-130%03/16/23 14:251 ENM V30957 Surrogate: Toluene-d8 89.8 Limits: 70-130%03/16/23 14:251 ENM V30957 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 34 of 43 Quality Control Data 23-069-0106Report No: Project Description: Client ID:Withers & Ravenel Forest Oaks Circle K QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V30957QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V30955 Associated Lab Samples: 90875, 90876, 90877, 90878, 90879, 90880, 90881 LRB-V30955 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 03/16/23 13:3710.0< 10.0µg/LAcetone 03/16/23 13:370.500< 0.500µg/LBenzene 03/16/23 13:370.500< 0.500µg/LBromobenzene 03/16/23 13:371.00< 1.00µg/LBromochloromethane 03/16/23 13:370.500< 0.500µg/LBromodichloromethane 03/16/23 13:375.00< 5.00µg/LBromoform 03/16/23 13:371.00< 1.00µg/LBromomethane 03/16/23 13:370.500< 0.500µg/Ln-Butylbenzene 03/16/23 13:370.500< 0.500µg/Lsec-Butyl benzene 03/16/23 13:372.00< 2.00µg/Ltert-Butyl benzene 03/16/23 13:370.500< 0.500µg/LCarbon Tetrachloride 03/16/23 13:370.500< 0.500µg/LChlorobenzene 03/16/23 13:370.500< 0.500µg/LChlorodibromomethane 03/16/23 13:371.00< 1.00µg/LChloroethane 03/16/23 13:370.500< 0.500µg/LChloroform 03/16/23 13:370.500< 0.500µg/LChloromethane 03/16/23 13:370.500< 0.500µg/L2-Chlorotoluene 03/16/23 13:370.500< 0.500µg/L4-Chlorotoluene 03/16/23 13:372.00< 2.00µg/L1,2-Dibromo-3-Chloropropane 03/16/23 13:370.500< 0.500µg/L1,2-Dibromoethane 03/16/23 13:370.500< 0.500µg/LDibromomethane 03/16/23 13:370.500< 0.500µg/L1,2-Dichlorobenzene 03/16/23 13:370.500< 0.500µg/L1,3-Dichlorobenzene 03/16/23 13:370.500< 0.500µg/L1,4-Dichlorobenzene 03/16/23 13:375.00< 5.00µg/LDichlorodifluoromethane 03/16/23 13:370.500< 0.500µg/L1,1-Dichloroethane 03/16/23 13:370.500< 0.500µg/L1,2-Dichloroethane Page 1 of 7Date:03/20/2023 05:42 PM Page 35 of 43 Quality Control Data 23-069-0106Report No: Project Description: Client ID:Withers & Ravenel Forest Oaks Circle K QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V30957QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V30955 Associated Lab Samples: 90875, 90876, 90877, 90878, 90879, 90880, 90881 LRB-V30955 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 03/16/23 13:370.500< 0.500µg/L1,1-Dichloroethene 03/16/23 13:370.500< 0.500µg/Lcis-1,2-Dichloroethene 03/16/23 13:370.500< 0.500µg/Ltrans-1,2-Dichloroethene 03/16/23 13:370.500< 0.500µg/L1,2-Dichloropropane 03/16/23 13:370.500< 0.500µg/L1,3-Dichloropropane 03/16/23 13:372.00< 2.00µg/L2,2-Dichloropropane 03/16/23 13:370.500< 0.500µg/L1,1-Dichloropropene 03/16/23 13:370.500< 0.500µg/Lcis-1,3-Dichloropropene 03/16/23 13:370.500< 0.500µg/Ltrans-1,3-Dichloropropene 03/16/23 13:37200< 200µg/LEthanol 03/16/23 13:370.500< 0.500µg/LEthylbenzene 03/16/23 13:373.00< 3.00µg/LHexachlorobutadiene 03/16/23 13:370.500< 0.500µg/LDi-Isopropyl Ether (DIPE) 03/16/23 13:370.500< 0.500µg/LIsopropylbenzene 03/16/23 13:370.500< 0.500µg/L4-Isopropyl toluene 03/16/23 13:371.00< 1.00µg/L2-Hexanone 03/16/23 13:375.00< 5.00µg/LMethyl Ethyl Ketone (MEK) 03/16/23 13:372.00< 2.00µg/LMethylene Chloride 03/16/23 13:371.00< 1.00µg/LMethyl tert-butyl ether (MTBE) 03/16/23 13:371.00< 1.00µg/L4-Methyl-2-Pentanone 03/16/23 13:371.00< 1.00µg/LNaphthalene 03/16/23 13:370.500< 0.500µg/Ln-Propylbenzene 03/16/23 13:370.500< 0.500µg/LStyrene 03/16/23 13:3710.0< 10.0µg/Ltert-Amyl Alcohol (TAA) 03/16/23 13:3710.0< 10.0µg/Ltert-Amyl Methyl Ether (TAME) 03/16/23 13:3710.0< 10.0µg/Ltert-Butyl Alcohol (TBA) 03/16/23 13:3710.0< 10.0µg/LEthyl Tertiary Butyl Ether (ETBE) Page 2 of 7Date:03/20/2023 05:42 PM Page 36 of 43 Quality Control Data 23-069-0106Report No: Project Description: Client ID:Withers & Ravenel Forest Oaks Circle K QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V30957QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V30955 Associated Lab Samples: 90875, 90876, 90877, 90878, 90879, 90880, 90881 LRB-V30955 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 03/16/23 13:3710.0< 10.0µg/Ltert-Butyl formate (TBF) 03/16/23 13:370.500< 0.500µg/L1,1,1,2-Tetrachloroethane 03/16/23 13:370.500< 0.500µg/L1,1,2,2-Tetrachloroethane 03/16/23 13:370.500< 0.500µg/LTetrachloroethene 03/16/23 13:370.500< 0.500µg/LToluene 03/16/23 13:370.500< 0.500µg/L1,2,3-Trichlorobenzene 03/16/23 13:370.500< 0.500µg/L1,2,4-Trichlorobenzene 03/16/23 13:370.500< 0.500µg/L1,1,1-Trichloroethane 03/16/23 13:370.500< 0.500µg/L1,1,2-Trichloroethane 03/16/23 13:370.500< 0.500µg/LTrichloroethene 03/16/23 13:370.500< 0.500µg/LTrichlorofluoromethane 03/16/23 13:370.500< 0.500µg/L1,2,3-Trichloropropane 03/16/23 13:370.500< 0.500µg/L1,2,4-Trimethylbenzene 03/16/23 13:370.500< 0.500µg/L1,3,5-Trimethylbenzene 03/16/23 13:375.00< 5.00µg/LVinyl Acetate 03/16/23 13:370.500< 0.500µg/LVinyl Chloride 03/16/23 13:371.00< 1.00µg/Lm,p-Xylene 03/16/23 13:370.500< 0.500µg/Lo-Xylene 03/16/23 13:374-Bromofluorobenzene (S)89.4 70-130 03/16/23 13:37Dibromofluoromethane (S)93.8 70-130 03/16/23 13:371,2-Dichloroethane - d4 (S)84.0 70-130 03/16/23 13:37Toluene-d8 (S)91.2 70-130 Page 3 of 7Date:03/20/2023 05:42 PM Page 37 of 43 Quality Control Data 23-069-0106Report No: Project Description: Client ID:Withers & Ravenel Forest Oaks Circle K QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V30957QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V30955 LCS-V30955 LCSD-V30955Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 28.7 71.771.528.640.0µg/LAcetone 40-160 0.3 20.0 20.8 10410721.420.0µg/LBenzene 70-130 2.8 20.0 16.5 82.585.017.020.0µg/LBromobenzene 70-130 2.9 20.0 22.4 11211022.020.0µg/LBromochloromethane 70-130 1.8 20.0 19.8 99.099.519.920.0µg/LBromodichloromethane 70-130 0.5 20.0 19.7 98.596.019.220.0µg/LBromoform 70-130 2.5 20.0 24.7 12412825.520.0µg/LBromomethane 60-140 3.1 20.0 17.7 88.595.519.120.0µg/Ln-Butylbenzene 70-130 7.6 20.0 16.9 84.592.018.420.0µg/Lsec-Butyl benzene 70-130 8.4 20.0 16.1 80.588.517.720.0µg/Ltert-Butyl benzene 70-130 9.4 20.0 21.0 10511021.920.0µg/LCarbon Tetrachloride 70-130 4.1 20.0 19.1 95.510120.220.0µg/LChlorobenzene 70-130 5.5 20.0 19.0 95.093.018.620.0µg/LChlorodibromomethane 70-130 2.1 20.0 22.0 11012124.120.0µg/LChloroethane 60-140 9.1 20.0 20.0 10010320.520.0µg/LChloroform 70-130 2.4 20.0 17.2 86.091.018.220.0µg/LChloromethane 60-140 5.6 20.0 15.9 79.584.516.920.0µg/L2-Chlorotoluene 70-130 6.0 20.0 16.1 80.586.017.220.0µg/L4-Chlorotoluene 70-130 6.6 20.0 20.7 10486.517.320.0µg/L1,2-Dibromo-3-Chloropropane 70-130 17.8 20.0 19.9 99.595.019.020.0µg/L1,2-Dibromoethane 70-130 4.6 20.0 21.6 10810120.220.0µg/LDibromomethane 70-130 6.6 20.0 17.5 87.591.018.220.0µg/L1,2-Dichlorobenzene 70-130 3.9 20.0 17.4 87.093.018.620.0µg/L1,3-Dichlorobenzene 70-130 6.6 20.0 17.0 85.090.518.120.0µg/L1,4-Dichlorobenzene 70-130 6.2 20.0 16.4 82.085.017.020.0µg/LDichlorodifluoromethane 60-140 3.5 20.0 19.8 99.092.518.520.0µg/L1,1-Dichloroethane 70-130 6.7 20.0 Page 4 of 7Date:03/20/2023 05:42 PM Page 38 of 43 Quality Control Data 23-069-0106Report No: Project Description: Client ID:Withers & Ravenel Forest Oaks Circle K QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V30957QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V30955 LCS-V30955 LCSD-V30955Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 19.6 98.092.518.520.0µg/L1,2-Dichloroethane 70-130 5.7 20.0 21.2 10611322.620.0µg/L1,1-Dichloroethene 70-130 6.3 20.0 19.8 99.010120.220.0µg/Lcis-1,2-Dichloroethene 70-130 2.0 20.0 19.3 96.599.519.920.0µg/Ltrans-1,2-Dichloroethene 70-130 3.0 20.0 20.8 10410521.020.0µg/L1,2-Dichloropropane 70-130 0.9 20.0 19.0 95.094.018.820.0µg/L1,3-Dichloropropane 70-130 1.0 20.0 21.3 10711322.520.0µg/L2,2-Dichloropropane 70-130 5.4 20.0 21.4 10711222.320.0µg/L1,1-Dichloropropene 70-130 4.1 20.0 21.4 10710621.120.0µg/Lcis-1,3-Dichloropropene 70-130 1.4 20.0 22.5 11310721.320.0µg/Ltrans-1,3-Dichloropropene 70-130 5.4 20.0 646 129118591500µg/LEthanol 60-140 8.8 20.0 17.8 89.093.518.720.0µg/LEthylbenzene 70-130 4.9 20.0 16.8 84.093.518.720.0µg/LHexachlorobutadiene 70-130 10.7 20.0 20.3 10299.519.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.9 20.0 16.6 83.091.018.220.0µg/LIsopropylbenzene 70-130 9.1 20.0 17.5 87.594.018.820.0µg/L4-Isopropyl toluene 70-130 7.1 20.0 17.8 89.075.015.020.0µg/L2-Hexanone 60-140 17.0 20.0 17.4 87.077.015.420.0µg/LMethyl Ethyl Ketone (MEK)60-140 12.1 20.0 19.1 95.597.519.520.0µg/LMethylene Chloride 70-130 2.0 20.0 21.1 10697.019.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 8.3 20.0 22.5 11397.019.420.0µg/L4-Methyl-2-Pentanone 60-140 14.7 20.0 21.0 10591.018.220.0µg/LNaphthalene 70-130 14.2 20.0 16.2 81.089.517.920.0µg/Ln-Propylbenzene 70-130 9.9 20.0 19.1 95.510120.120.0µg/LStyrene 70-130 5.1 20.0 18.9 94.511222.420.0µg/Ltert-Amyl Alcohol (TAA)40-140 16.9 20.0 47.5 11996.238.540.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 20.9*20.0 Page 5 of 7* QC Fail Date:03/20/2023 05:42 PM Page 39 of 43 Quality Control Data 23-069-0106Report No: Project Description: Client ID:Withers & Ravenel Forest Oaks Circle K QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V30957QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V30955 LCS-V30955 LCSD-V30955Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 46.9 11798.739.540.0µg/Ltert-Butyl Alcohol (TBA)40-140 17.1 20.0 46.4 11611244.640.0µg/LEthyl Tertiary Butyl Ether (ETBE)70-130 3.9 20.0 47.9 12011345.140.0µg/Ltert-Butyl formate (TBF)40-140 6.0 20.0 18.6 93.095.519.120.0µg/L1,1,1,2-Tetrachloroethane 70-130 2.6 20.0 19.8 99.093.018.620.0µg/L1,1,2,2-Tetrachloroethane 70-130 6.2 20.0 19.4 97.010521.020.0µg/LTetrachloroethene 70-130 7.9 20.0 21.0 10510821.520.0µg/LToluene 70-130 2.3 20.0 20.2 10194.018.820.0µg/L1,2,3-Trichlorobenzene 70-130 7.1 20.0 19.4 97.097.019.420.0µg/L1,2,4-Trichlorobenzene 70-130 0.0 20.0 19.5 97.510220.420.0µg/L1,1,1-Trichloroethane 70-130 4.5 20.0 22.7 11410520.920.0µg/L1,1,2-Trichloroethane 70-130 8.2 20.0 20.8 10410621.220.0µg/LTrichloroethene 70-130 1.9 20.0 23.1 11612224.320.0µg/LTrichlorofluoromethane 60-140 5.0 20.0 19.0 95.085.017.020.0µg/L1,2,3-Trichloropropane 70-130 11.1 20.0 16.6 83.089.017.820.0µg/L1,2,4-Trimethylbenzene 70-130 6.9 20.0 16.5 82.591.018.220.0µg/L1,3,5-Trimethylbenzene 70-130 9.7 20.0 16.6 83.089.517.920.0µg/LVinyl Acetate 60-140 7.5 20.0 20.2 10110420.720.0µg/LVinyl Chloride 60-140 2.4 20.0 37.6 94.010040.140.0µg/Lm,p-Xylene 70-130 6.4 20.0 17.9 89.595.519.120.0µg/Lo-Xylene 70-130 6.4 20.0 90.890.44-Bromofluorobenzene (S)70-130 95.494.6Dibromofluoromethane (S)70-130 92.082.01,2-Dichloroethane - d4 (S)70-130 90.893.8Toluene-d8 (S)70-130 Page 6 of 7Date:03/20/2023 05:42 PM Page 40 of 43 Quality Control Data 23-069-0106Report No: Project Description: Client ID:Withers & Ravenel Forest Oaks Circle K QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V30984QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V30983 Associated Lab Samples: 90875, 90876 LRB-V30983 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 03/17/23 15:350.500< 0.500µg/LBenzene 03/17/23 15:350.500< 0.500µg/LEthylbenzene 03/17/23 15:3510.0< 10.0µg/Ltert-Amyl Alcohol (TAA) 03/17/23 15:350.500< 0.500µg/LToluene 03/17/23 15:351.00< 1.00µg/Lm,p-Xylene 03/17/23 15:354-Bromofluorobenzene (S)96.0 70-130 03/17/23 15:35Dibromofluoromethane (S)87.4 70-130 03/17/23 15:351,2-Dichloroethane - d4 (S)89.6 70-130 03/17/23 15:35Toluene-d8 (S)98.0 70-130 LCS-V30983 LCSD-V30983Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 16.7 83.586.517.320.0µg/LBenzene 70-130 3.5 20.0 16.2 81.084.516.920.0µg/LEthylbenzene 70-130 4.2 20.0 13.4 67.085.017.020.0µg/Ltert-Amyl Alcohol (TAA)40-140 23.6*20.0 15.8 79.081.016.220.0µg/LToluene 70-130 2.5 20.0 34.1 85.287.034.840.0µg/Lm,p-Xylene 70-130 2.0 20.0 98.298.24-Bromofluorobenzene (S)70-130 87.487.0Dibromofluoromethane (S)70-130 90.490.01,2-Dichloroethane - d4 (S)70-130 97.697.8Toluene-d8 (S)70-130 Page 7 of 7* QC Fail Date:03/20/2023 05:42 PM Page 41 of 43 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-069-0106 Withers & Ravenel 01221 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT15 2.5C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angela D Overcash Date & Time:03/10/2023 18:18:22 Special precautions or instructions included? Comments: Page 42 of 43 Page 43 of 43 WithersRavenel Our People. Your Success. APPENDIX C GENERAL STANDARD OPERATING PROCEDURES Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Soil Sampling, Soil Boring and Monitor Well Installation, Well Development Soil borings are installed utilizing a stainless-steel hand auger, direct-push hydraulic drill or auger rotary drill using either a macro core™ sampler, hollow stem augers, or air rotary roller cone bit. Soil borings are typically sampled at discrete intervals from the bucket of a clean stainless steel hand auger, direct push stainless steel sampler with acetate sleeve, or a split barrel sampler. When appropriate, soil samples may be collected from drill cuttings associated with the boring or well installation. Monitor wells are constructed within select soil borings of one, two, or four-inch inside diameter PVC casing and machine slotted screen in accordance with NCAC Title 15A, Subchapter 02C (Well Construction Standards, Criteria and Standards Applicable to Water Supply and Certain Other Wells). Clean-washed “#2 Torpedo Sand” is typically utilized to fill the boring annulus surrounding the well screen, extending to a minimum of 1-foot above the well screen. A minimum 1-foot thick bentonite clay seal is emplaced above the sand pack and hydrated. Neat cement grout is placed in the remaining annulus space from the upper portion of the bentonite seal to within 1-foot of surface grade. In coastal plain areas where shallow groundwater is encountered, a variance to construction standards may be employed to ensure the upper portion of the well screen intersects the upper aquifer surface. Wellheads may be completed with either concrete-set flush mounted traffic-bearing steel skirted manholes with bolt down covers or steel above-ground “stick-up” well protectors set in a concrete pad. The monitoring wells are secured with locking caps. Temporary wells or piezometers may be completed with the PVC riser cut at or above grade, and are abandoned within 24-hours of their installation. Wells may be developed using a bailer, electric submersible pump, pneumatic pump, or peristaltic pump, dependent upon site conditions. When wells are developed by the driller, they may be developed with any of the methods outlined above, in addition to air or water injection. Soil boring logs and well construction details are typically prepared for presentation in a report appendix. Borings completed in bedrock may be drilled using air rotary, coring, or sonic drilling methods. Groundwater Depth to Water Measurements Groundwater level measurements are typically obtained using an electronic water level indicator which registers a tone and/or illuminated light when the probe contacts groundwater. Depth to groundwater measurements are obtained by lowering the probe attached to a cable usually marked in 0.01 foot intervals into the well until the probe of the meter intersects the water surface. The measurement from the top of the riser pipe or top of casing (TOC) to the water level is recorded to the nearest 0.01 foot. The electronic water level indicator probe and exposed probe cable is decontaminated between measurement locations. Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Free Product Level Measurements Light Non-Aqueous Phase Liquid (LNAPL) or “free product” present on the water table is measured using an electronic oil/water interface probe. The interface probe has both an audible and illuminating light that indicate when a liquid level is encountered. The oil/water interface probe registers a solid tone and solidly lit light when LNAPL petroleum product is encountered and a beeping tone flashing light when groundwater is encountered. Depth to LNAPL measurements are obtained by lowering the probe attached to a cable marked in 0.01 foot intervals into the well until the probe of the meter intersects the product or groundwater. The measurements from the top of the riser pipe or TOC to the liquid level are recorded to the nearest 0.01 foot. The thickness of LNAPL is calculated by subtracting the depth to LNAPL measurement from the depth to groundwater measurement. The electronic interface probe is decontaminated between measurement locations. Soil Sampling and Field Screening Soil sampling is performed in general accordance with ASTM: 1586-84 where applicable. Sampling procedures are followed to protect the chemical integrity of the soil samples and minimize the potential for cross contamination between sample locations, including discarding of the exterior of the sample which contacts the auger bucket, acetate sleeve, or split barrel sampler, the use of stainless steel sampling equipment, and the thorough decontamination of sampling apparatus prior to use and between sample locations. Soil samples retained as a part of excavation or other intrusive “digging” activities may be collected from the bucket of excavation equipment or using a hand shovel, if appropriate. Care to collect soil samples from excavation equipment includes retrieving native soil from material that has not made contact with the excavating equipment. Samples are collected in sealable bags or by directly filling sample containers as described above. Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample integrity and minimize the potential for cross contamination or field personnel exposure to contaminants. Sampling equipment such as hand auger extensions and buckets, direct push samplers, split spoons or shovels, are decontaminated prior to their use in the collection of samples. Samples are placed within laboratory grade sample containers provided by the laboratory to which the samples are submitted, labeled, sealed, and placed in an ice filled cooler. An aliquot of the sample is typically placed in a clean sealable bag and allowed to reach ambient air temperature for future screening of volatile vapor content with a photoionization detector (PID), flame-ionization detector (FID) or other portable screening device. Screening of samples with a PID, FID or other field screening device is performed in accordance with device manufacturer specifications for screening, following calibration of the instrument based on manufacturer recommended procedures. Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Groundwater Sampling Groundwater samples are generally collected using one of three standard methods – through the use of a dedicated, disposable bailer, a peristaltic pump or submersible electric pump. When sampling with a bailer, a minimum of three well volumes of groundwater are extracted from the well as a means of purging, unless the well is purged to a “dry” state prior to the removal of three volumes of water. Prior to collection of the groundwater sample with the bailer, the water level is allowed to recover to within 80% of the original level measured prior to purging. When sampling with a peristaltic or submersible electric pump, polyethylene (PE) tubing (or equivalent) is emplaced into the screened section of the monitoring well, and the pump is used to extract water through the tubing. When using the either of these methods, general water quality measurements including but not limited to pH, temperature, dissolved oxygen (DO), oxygen reductive potential (ORP), specific conductivity and turbidity may be used as methods for determining when an adequate purge of the well has been conducted. When water quality parameters are measured, the resulting data are included in well purge forms or field notes specific to each site and sampling point. Following the purging of three well volumes of groundwater (in the case of the bailed well) or stability of monitored measurements (in the case of the peristaltic or submersible electric pump), the groundwater sample(s) are introduced directly into sample containers provided by the laboratory to which samples are ultimately submitted for analysis. Any samples requiring chemical preservation are contained in pre-preserved container(s) provided by the laboratory. Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample integrity and minimize the potential for cross contamination of samples or field personnel exposure to contaminants. Water Supply Well Sampling Sampling of water supply wells is accomplished through the collection of a representative sample from an in-line water tap or other point accessible for sampling. Where possible, the sample is collected from a point prior to any filtration or point of entry (POE) system which might be installed on a well. In some cases, samples will be collected from both pre and post-POE locations. Prior to the collection of samples through an in-place sampling point, the tap or sampling port is cleaned with an Alconox® and deionized water solution, rinsed with deionized water, and again with an isopropyl alcohol (IPA) rinse. In the case of active supply wells (e.g., a well with a useable well pump with an active power supply), the well pump is energized and allowed to run for a minimum of ten (10) minutes time, after which a sample is contained in laboratory grade sample containers as described in the previous section. Water quality parameters may be (but are not necessarily) measured in association with the well purging. Supply wells without active power supplies are not generally sampled, as the well seal cannot be compromised by individuals not certified as a well contractor. However, in the case of a well with no power supply or pump installed, samples could be obtained through the use of a bailer, peristaltic pump or electric submersible pump. Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Decontamination Procedures Decontamination procedures employed in the performance of field activities will vary dependent upon the method(s) of sampling performed at any site, but will generally include the following: • Remove excess soil/sludge from any sampling equipment as needed, • Wash and scrub the equipment with a phosphate-free detergent such as Alconox® or Liquinox® in a contaminant-free tap water solution. Use a brush to remove particulate matter and surface films as necessary, • Rinse thoroughly with tap water, • Rinse thoroughly with analyte-free water (deionized water),  Rinse thoroughly with isopropyl alcohol, • Allow the equipment to air dry, • Prevent inadvertent contamination during storage and transport (accomplished through storage of equipment in foil or plastic bags/sheeting). In the case of disposable bailers and tubing utilized for the purging and sampling of wells, these items may be decontaminated prior to their disposal. In general, no decontamination of these items is necessary prior to their use in sampling.