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HomeMy WebLinkAboutMO-2944_5469_CA_LTRRPT_20230228 CES Group Engineers, LLP IMPROVING. PROTECTING. RESTORING. 1 CHARLOTTE, NC COLUMBIA, SC www.ces-group.net February 28, 2023 Scott Ryals, PE Environmental Engineer North Carolina Department of Environmental Quality DWM UST Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 RE: Miscellaneous Letter Report for Groundwater Monitoring and Sampling City of Claremont Incident No.: 5469 UST ID No.: MO-2944 Facility ID No.: 00-0-0000007149 3301 E Main Street Claremont, Catawba County, North Carolina 28610 Dear Mr. Ryals: CES Group Engineers, LLP (CES), while under contract with the North Carolina Department of Environmental Quality (NCDEQ), Contract No.: N040722, executed on April 20, 2022, is submitting this Miscellaneous Letter Report for Groundwater Monitoring and Sampling to you for the aforementioned property electronically via email. A Site Location Map, depicting the location of the site in relation to nearby and surrounding features, is included as Figure 1. The performed work was authorized by NCDEQ Task Authorization (TA) #01, approved on February 1, 2023. The scope of services for TA #01 included the following:  Monitor and collect a groundwater sample from one monitoring well (MW-1) and collect one field blank for laboratory analysis of 6200B, including MTBE, IPE and EDB, 625 BNA, VPH and Lead; and  Prepare and submit one miscellaneous letter report summarizing groundwater monitoring, sampling and laboratory analytical findings. Based on concentrations of benzene, 2-methylnaphthalene, and VPH fractions in MW-1 previously reported above the 2L standard in March and April 2007, and with concentrations of lead reported in MW-1 slightly below the 2L standard in March and April 2007, the purpose of this groundwater monitoring and sampling event was to collect a groundwater sample from MW-1 to evaluate current concentration levels in comparison to the 2L standard. CES Group Engineers, LLP IMPROVING. PROTECTING. RESTORING. 2 As depicted on Figure 2, MW-1 is located immediately to the south of the onsite building (City of Claremont Police Department), and in the general area of the former 550-gallon gasoline and 1,000-gallon gasoline underground storage tanks (USTs), reportedly excavated and removed from the subsurface in December of 1989. Historical data summarizing soil and groundwater analytical results from sampling events conducted in 1990 and 2007, prepared by SPATCO Environmental, and SEI Environmental, Inc, respectively, are included in Appendix A. Groundwater Monitoring, Sampling and Laboratory Analysis On February 9, 2023, CES mobilized to the site to collect depth-to-groundwater (DTW) measurements and a groundwater sample from MW-1. The DTW measurement was recorded using a water level meter capable of detecting light non- aqueous phase liquid (LNAPL) to an accuracy of 0.01 feet. LNAPL was not detected in MW-1. The DTW measurement from MW-1 was recorded at a depth of 20.33-feet below grade. After collecting the depth to groundwater measurement, and after calculating the volume of water to be removed from MW-1, a dedicated 1.5-inch disposable bailer was used to purge approximately three to five well volumes from the monitoring well. Groundwater samples were then collected in laboratory provided vials and glassware via the dedicated 1.5-inch disposable bailer, stored on ice, and hand delivered under COC procedures on February 10, 2023 to Waypoint Analytical, LLC, of Charlotte, North Carolina, for laboratory analysis of the following:  6200B, including MTBE, IPE and EDB  625 BNA  VPH  Lead Groundwater laboratory analytical results from MW-1 reported petroleum-related constituent concentrations BELOW 2L (and GCL) standards on February 9, 2023. No petroleum hydrocarbon constituents were reported above method detection limits (MDLs) from the field blank. Tables B-4 and B-9 summarize groundwater analytical results and the depth to groundwater measurement, respectively. A field data groundwater monitoring sheet is included as Appendix B. The groundwater analytical report is included in Appendix C. Prior to the commencement of field monitoring and sampling activities, CES prepared and reviewed a site-specific Job Hazard Analysis (JHA) and Emergency Management and Health & Safety Plan (HASP), acknowledging that potential hazards exist onsite, which were properly recognized and evaluated by onsite personnel. A copy of the site-specific JHA and HASP are included in Appendix D. CES Group Engineers, LLP IMPROVING. PROTECTING. RESTORING. 3 Conclusions The findings of the February 9, 2023 groundwater sampling event are as follows:  One groundwater monitoring well (MW-1) and one field blank were monitored and sampled for analysis of 6200B, including MTBE, IPE and EDB, 625 BNA, VPH and Lead;  LNAPL or Free Product was not detected in MW-1;  Depth to groundwater was measured at 20.33-feet below grade in MW-1;  Apparent groundwater flow direction is unknown; and  Petroleum constituents in groundwater were reported BELOW 2L and GCL standards in MW-1. Recommendations Based upon groundwater concentration levels reported below the 2L and GCL standard from MW- 1 on February 9, 2023, and the previous Low-Risk classification, it is recommended that no further action (NFA) be issued for Incident 5469, and MW-1 be abandoned by a licensed North Carolina driller. Should you have any questions in regards to this submittal, please do not hesitate to contact me at (704) 325-5408 or ghans@ces-group.net. Regards, CES Group Engineers, LLP Greg Hans, PMP Environmental Division Manager E-Signature 2/28/2023 Charles D. Heleine, NC PE No. 27196 Senior Environmental Engineer Attachments: Figure 1: Site Location Map Figure 2: Site Plan Table B-4: Summary of Groundwater Analytical Results Table B-9: Current Groundwater Elevations Appendix A: Historical Data Appendix B: Field Data Monitoring Sheet Appendix C: Groundwater Laboratory Analytical Report Appendix D: Health & Safety Plan and JHA FIGURES DRAWN BY: BN CHECKED BY: GH PROJECT NUMBER: 8084.0223E DRAWING TITLE: SHEET NUMBER: SEAL:PROJECT DESCRIPTION:Site Location MapCES GROUP ENGINEERS, LLP NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net DATE: 02/23/2023 SCALE : NTS DRAWN BY: BN CHECKED BY: GH PROJECT NUMBER: 8084.0223E DRAWING TITLE: SHEET NUMBER: SEAL:PROJECT DESCRIPTION:Site PlanCES GROUP ENGINEERS, LLP NC FIRM LICENSE #F-1240 3525 WHITEHALL PARK DRIVESUITE 150CHARLOTTE, NC 28273T 704. 489.1500 www.ces-group.net DATE: 02/23/2023 SCALE : 1" = 20' TABLES Table B-4: Summary of Groundwater Analytical Results Revision Date: 02/22/2023 Incident Number and Name: Incident No. 5469; City of Claremont UST ID#: MO-2944 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 625 BNA 6010D VPH VPH VPH Sample ID Date Collected (m/dd/yy) Incident Phase MW-1*3/20 & 4/4/07 LSA 5 3 5.3 NA NA 30.4 BDL BDL 1.5 1 BDL 17.6 14.3 691 752 777 MW-1 2/9/23 GWR BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 4 66.8 BDL BDL 1 600 600 NA NA 500 20 70 6 70 0.02 30 15 400 700 200 5000 260000 80000 NA NA 50000 20000 70000 6000 70000 50 12000 15000 NA NA NA µg/l = Micrograms per Liter GCL = Gross Contamination Level BDL = Below Laboratory Detection Limit NA = Not Applicable J = Detected but below the Reporting Limit; therefore, result is an estimated concentration Concentrations in BOLD and Highlighted Yellow reported above 2L Standards Concentrations were reported below 2L and GCL Standards (February 9, 2023) Constituents not listed above were reported as BDLs MW-1* = Historical groundwater data collected by others Laboratory analysis performed by Waypoint Analytical, Inc of Charlotte, NC (NC Certification No. 402) Analytical Method (e.g., VOCs by EPA 6200B)  Contaminant of Concern (mg/kg)  2L Standard (ug/L) (Effective 4/1/2022) GCL (ug/L) (Table 2 - Revised 10/8/2020)EthylbenzeneBenzeneTolueneC9-C10 Aromaticso-XyleneMTBEm,p-XyleneXylene (Total)IPEC9-C12 AliphaticNaphthaleneChloroformEDBC5-C8 Aliphatic2-MethylnaphthaleneLead Table B-9: Groundwater Elevations and Free Product Thickness Revision Date: 2/10/2023 Incident No.: 5469; Incident Name: City of Claremont UST ID#: MO-2944 Well ID #Top of Casing Elevation (MSL) Screened Interval (top of screen, bottom of screen) Date Depth to Water* Uncorrected (feet) Free Product Thickness (feet) Depth to Water* Corrected for Free Product Thickness(feet) Groundwater Surface Elevation (MSL) MW-1 NA 25 to 35' 2/9/2023 20.33 0 20.33 NA APPENDIX A HISTORICAL DATA APPENDIX B FIELD DATA GROUNDWATER MONITORING SHEETS Appendix B: Groundwater Monitoring Field Data Completion Date: 2/9/2023 Incident Number and Name: Incident No. 5469; City of Claremont UST ID No. MO-2944 Well ID Sampling Date (m/dd/yy) Well Casing Diameter (in.) Screened Interval (x to y ft. BGS) Depth of Well (ft. BGS) Top of Casing Elevation * (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness (ft.) Groundwater Elevation* (ft.) Sample Analysis Number of Sample Containers Proposed Purged Volume (gal) Actual Purged Volume (gal) Purge Comments MNA Parameters MW-1 2/9/2023 2" 25 to 35' 35' N/A 20.33' ND N/A 6200B, incl MTBE + IPE + EDB, 625 BNA, VPH & Lead 9 7.5-gal 7.5-gal Purged appr. 7.5-gallons prior to sampling. Purged bailings observed to be clear to reddish/orange tint with minor sediment accumulation. No odor present, with no sheens present on bailings Not Collected City of Claremont, NCDEQ Incident No.: 5469, UST ID No.: MO-2944 *: Top-of-Casing elevations not obtained under current task order / work order APPENDIX C GROUNDWATER LABORATORY ANALYTICAL REPORT   Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   2/21/2023 CES Group Greg Hans 3525 Whitehall Park Dr. Suite 150 Charlotte, NC, 28273 Ref: Analytical Testing Lab Report Number: 23-041-0012 Client Project Description: City of Claremont Dear Greg Hans: Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/10/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 39 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date 02/28/202340750State ProgramAlabama 02/07/202388-0650State ProgramArkansas 06/30/20232904State ProgramCalifornia 06/30/2023E871157State Program - NELAPFlorida 02/18/2023C044State ProgramGeorgia 06/30/202304015State ProgramGeorgia 10/10/2023200078State Program - NELAPIllinois 06/30/202380215State ProgramKentucky 12/31/2023KY90047State ProgramKentucky 12/31/2023LA037State Program - NELAPLouisiana 06/30/202304015State Program - NELAPLouisiana 02/11/2023MSState ProgramMississippi 07/31/202347701State ProgramNorth Carolina 12/31/2023415State ProgramNorth Carolina 05/31/202368-03195State Program - NELAPPennsylvania 06/30/202384002State ProgramSouth Carolina 11/14/202502027State ProgramTennessee 09/30/2023T104704180State Program - NELAPTexas 06/30/202300106State ProgramVirginia 09/14/2023460181State Program - NELAPVirginia Page 1 of 1 00016/23-041-0012 Page 2 of 39 Report Number: Sample Summary Table Client Project Description: 23-041-0012 City of Claremont Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 02/09/2023 09:15Aqueous 99405 Field Blank 02/10/2023 11:10 02/09/2023 09:15Aqueous 99405 Field Blank 02/10/2023 11:10 6010D WP MTN - 02/09/2023 10:10Aqueous 99406 MW-1 02/10/2023 11:10 02/09/2023 10:10Aqueous 99406 MW-1 02/10/2023 11:10 6010D WP MTN - WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 3 of 39 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-041-0012 Report Limit Project:City of Claremont V 99406MW-1 J0.004 02/17/2023 21:386010DLeadmg/L 0.002 0.639 02/13/2023 15:346200Bn-Butylbenzene µg/L 0.180 66.8 02/13/2023 10:46MADEP-VPH Aliphatic C5-C8 µg/L 11.5 Page 4 of 39   Client: CES Group CASE NARRATIVE Project: City of Claremont Lab Report Number: 23-041-0012 Date: 2/21/2023 625.1 - Base/Neutrals and Acids by GC/MS Method 625.1 Analyte: Benzidine QC Batch No: V29896/V29776 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,2,3-Trichlorobenzene QC Batch No: V29758/V29757 Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Ethanol QC Batch No: V29758/V29757 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Page 5 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF <0.002 mg/L 0.002 0.006Lead 1 02/17/23 21:33 6010DBKN Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 6 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <1.80 µg/L 1.80 10.0Acetone 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.500Benzene 1 02/13/23 15:10 V29758MSA <0.210 µg/L 0.210 0.500Bromobenzene 1 02/13/23 15:10 V29758MSA <0.420 µg/L 0.420 1.00Bromochloromethane 1 02/13/23 15:10 V29758MSA <0.160 µg/L 0.160 0.500Bromodichloromethane 1 02/13/23 15:10 V29758MSA <1.50 µg/L 1.50 5.00Bromoform 1 02/13/23 15:10 V29758MSA <0.280 µg/L 0.280 1.00Bromomethane 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.500n-Butylbenzene 1 02/13/23 15:10 V29758MSA <0.200 µg/L 0.200 0.500 sec-Butyl benzene 1 02/13/23 15:10 V29758MSA <0.920 µg/L 0.920 2.00tert-Butyl benzene 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/13/23 15:10 V29758MSA <0.190 µg/L 0.190 0.500Chlorobenzene 1 02/13/23 15:10 V29758MSA <0.190 µg/L 0.190 0.500Chlorodibromomethane 1 02/13/23 15:10 V29758MSA <0.430 µg/L 0.430 1.00Chloroethane 1 02/13/23 15:10 V29758MSA <0.220 µg/L 0.220 0.500Chloroform 1 02/13/23 15:10 V29758MSA <0.220 µg/L 0.220 0.500 Chloromethane 1 02/13/23 15:10 V29758MSA <0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/13/23 15:10 V29758MSA <0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/13/23 15:10 V29758MSA <0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/13/23 15:10 V29758MSA <1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/13/23 15:10 V29758MSA <0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 02/13/23 15:10 V29758MSA <0.230 µg/L 0.230 0.500Dibromomethane 1 02/13/23 15:10 V29758MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 7 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/13/23 15:10 V29758MSA <0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/13/23 15:10 V29758MSA <0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/13/23 15:10 V29758MSA <1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/13/23 15:10 V29758MSA <0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/13/23 15:10 V29758MSA <0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/13/23 15:10 V29758MSA <0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/13/23 15:10 V29758MSA <0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.500 trans-1,2-Dichloroethene 1 02/13/23 15:10 V29758MSA <0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 02/13/23 15:10 V29758MSA <0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/13/23 15:10 V29758MSA <0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/13/23 15:10 V29758MSA <0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/13/23 15:10 V29758MSA <0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/13/23 15:10 V29758MSA <0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/13/23 15:10 V29758MSA <42.0 µg/L 42.0 200 Ethanol 1 02/13/23 15:10 V29758MSA <0.170 µg/L 0.170 0.500Ethylbenzene 1 02/13/23 15:10 V29758MSA <0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/13/23 15:10 V29758MSA <0.380 µg/L 0.380 1.002-Hexanone 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.500Isopropylbenzene 1 02/13/23 15:10 V29758MSA <0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 02/13/23 15:10 V29758MSA <0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/13/23 15:10 V29758MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 8 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/13/23 15:10 V29758MSA <0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/13/23 15:10 V29758MSA <0.330 µg/L 0.330 2.00Methylene Chloride 1 02/13/23 15:10 V29758MSA <0.470 µg/L 0.470 1.00Naphthalene 1 02/13/23 15:10 V29758MSA <0.190 µg/L 0.190 0.500n-Propylbenzene 1 02/13/23 15:10 V29758MSA <0.220 µg/L 0.220 0.500Styrene 1 02/13/23 15:10 V29758MSA <0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/13/23 15:10 V29758MSA <0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/13/23 15:10 V29758MSA <0.220 µg/L 0.220 0.500 Tetrachloroethene 1 02/13/23 15:10 V29758MSA <0.220 µg/L 0.220 0.500Toluene 1 02/13/23 15:10 V29758MSA <0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/13/23 15:10 V29758MSA <0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/13/23 15:10 V29758MSA <0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/13/23 15:10 V29758MSA <0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.500Trichloroethene 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.500 Trichlorofluoromethane 1 02/13/23 15:10 V29758MSA <0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/13/23 15:10 V29758MSA <0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 02/13/23 15:10 V29758MSA <0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 02/13/23 15:10 V29758MSA <1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/13/23 15:10 V29758MSA <0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/13/23 15:10 V29758MSA <0.210 µg/L 0.210 0.500o-Xylene 1 02/13/23 15:10 V29758MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 9 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <0.420 µg/L 0.420 1.00m,p-Xylene 1 02/13/23 15:10 V29758MSA <0.21 µg/L 0.210 0.500Xylene (Total)1 02/13/23 15:10 V29758 Surrogate: 4-Bromofluorobenzene 99.0 Limits: 70-130%02/13/23 15:101 MSA V29758 Surrogate: Dibromofluoromethane 94.6 Limits: 70-130%02/13/23 15:101 MSA V29758 Surrogate: 1,2-Dichloroethane - d4 95.8 Limits: 70-130%02/13/23 15:101 MSA V29758 Surrogate: Toluene-d8 101 Limits: 70-130%02/13/23 15:101 MSA V29758 Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <0.324 µg/L 0.324 2.15Acenaphthene 1 02/16/23 14:21 V29896JMV <0.319 µg/L 0.319 2.15Acenaphthylene 1 02/16/23 14:21 V29896JMV <0.898 µg/L 0.898 2.15Anthracene 1 02/16/23 14:21 V29896JMV <1.43 µg/L 1.43 10.8 Benzidine 1 02/16/23 14:21 V29896JMV <0.684 µg/L 0.684 2.15Benzo(a)anthracene 1 02/16/23 14:21 V29896JMV <1.10 µg/L 1.10 2.15Benzo(a)pyrene 1 02/16/23 14:21 V29896JMV <2.68 µg/L 2.68 5.38Benzo(b)fluoranthene 1 02/16/23 14:21 V29896JMV <1.09 µg/L 1.09 5.38Benzo(g,h,i)perylene 1 02/16/23 14:21 V29896JMV <2.14 µg/L 2.14 5.38Benzo(k)fluoranthene 1 02/16/23 14:21 V29896JMV <1.19 µg/L 1.19 10.8Benzoic Acid 1 02/16/23 14:21 V29896JMV <0.735 µg/L 0.735 5.38 Benzyl alcohol 1 02/16/23 14:21 V29896JMV <0.503 µg/L 0.503 5.38Bis(2-Chloroethoxy)methane 1 02/16/23 14:21 V29896JMV Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 10 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <1.12 µg/L 1.12 5.38Bis(2-Chloroethyl)ether 1 02/16/23 14:21 V29896JMV <1.16 µg/L 1.16 5.38Bis(2-Chloroisopropyl)ether 1 02/16/23 14:21 V29896JMV <3.74 µg/L 3.74 10.8Bis(2-ethylhexyl)phthalate 1 02/16/23 14:21 V29896JMV <1.19 µg/L 1.19 5.384-Bromophenyl phenyl ether 1 02/16/23 14:21 V29896JMV <1.97 µg/L 1.97 5.38Butyl benzyl phthalate 1 02/16/23 14:21 V29896JMV <1.27 µg/L 1.27 5.384-Chloro-3-methylphenol 1 02/16/23 14:21 V29896JMV <7.93 µg/L 7.93 21.52-Chloronaphthalene 1 02/16/23 14:21 V29896JMV <1.01 µg/L 1.01 10.82-Chlorophenol 1 02/16/23 14:21 V29896JMV <1.84 µg/L 1.84 5.38 4-Chlorophenyl phenyl ether 1 02/16/23 14:21 V29896JMV <0.435 µg/L 0.435 2.15Chrysene 1 02/16/23 14:21 V29896JMV <0.466 µg/L 0.466 2.15Dibenz(a,h)anthracene 1 02/16/23 14:21 V29896JMV <0.921 µg/L 0.921 5.38Dibenzofuran 1 02/16/23 14:21 V29896JMV <2.15 µg/L 2.15 5.381,2-Dichlorobenzene 1 02/16/23 14:21 V29896JMV <2.15 µg/L 2.15 5.381,3-Dichlorobenzene 1 02/16/23 14:21 V29896JMV <2.21 µg/L 2.21 5.381,4-Dichlorobenzene 1 02/16/23 14:21 V29896JMV <2.03 µg/L 2.03 5.38 3,3'-Dichlorobenzidine 1 02/16/23 14:21 V29896JMV <1.58 µg/L 1.58 10.82,4-Dichlorophenol 1 02/16/23 14:21 V29896JMV <0.801 µg/L 0.801 5.38Diethyl phthalate 1 02/16/23 14:21 V29896JMV <1.01 µg/L 1.01 5.38Dimethyl phthalate 1 02/16/23 14:21 V29896JMV <1.69 µg/L 1.69 21.52,4-Dimethylphenol 1 02/16/23 14:21 V29896JMV <2.22 µg/L 2.22 5.38Di-n-butyl phthalate 1 02/16/23 14:21 V29896JMV <2.24 µg/L 2.24 10.84,6-Dinitro-2-methylphenol 1 02/16/23 14:21 V29896JMV Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 11 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <2.07 µg/L 2.07 10.82,4-Dinitrophenol 1 02/16/23 14:21 V29896JMV <1.19 µg/L 1.19 5.382,4-Dinitrotoluene 1 02/16/23 14:21 V29896JMV <0.870 µg/L 0.870 5.382,6-Dinitrotoluene 1 02/16/23 14:21 V29896JMV <1.78 µg/L 1.78 5.38Di-n-Octyl Phthalate 1 02/16/23 14:21 V29896JMV <0.268 µg/L 0.268 2.15Fluoranthene 1 02/16/23 14:21 V29896JMV <0.867 µg/L 0.867 2.15Fluorene 1 02/16/23 14:21 V29896JMV <1.05 µg/L 1.05 5.38Hexachlorobenzene 1 02/16/23 14:21 V29896JMV <2.94 µg/L 2.94 5.38Hexachlorobutadiene 1 02/16/23 14:21 V29896JMV <2.21 µg/L 2.21 5.38 Hexachlorocyclopentadiene 1 02/16/23 14:21 V29896JMV <1.89 µg/L 1.89 5.38Hexachloroethane 1 02/16/23 14:21 V29896JMV <0.512 µg/L 0.512 2.15Indeno(1,2,3-cd)pyrene 1 02/16/23 14:21 V29896JMV <0.477 µg/L 0.477 5.38Isophorone 1 02/16/23 14:21 V29896JMV <1.23 µg/L 1.23 2.151-Methylnaphthalene 1 02/16/23 14:21 V29896JMV <0.715 µg/L 0.715 2.152-Methylnaphthalene 1 02/16/23 14:21 V29896JMV <0.782 µg/L 0.782 2.15Naphthalene 1 02/16/23 14:21 V29896JMV <0.973 µg/L 0.973 5.38 Nitrobenzene 1 02/16/23 14:21 V29896JMV <0.530 µg/L 0.530 5.382-Nitrophenol 1 02/16/23 14:21 V29896JMV <1.33 µg/L 1.33 10.84-Nitrophenol 1 02/16/23 14:21 V29896JMV <1.18 µg/L 1.18 5.38N-Nitrosodiphenylamine 1 02/16/23 14:21 V29896JMV <0.689 µg/L 0.689 5.38N-Nitroso-di-n-propylamine 1 02/16/23 14:21 V29896JMV <1.54 µg/L 1.54 5.38Pentachlorophenol 1 02/16/23 14:21 V29896JMV <0.460 µg/L 0.460 2.15Phenanthrene 1 02/16/23 14:21 V29896JMV Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 12 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <0.700 µg/L 0.700 5.38Phenol 1 02/16/23 14:21 V29896JMV <0.466 µg/L 0.466 2.15Pyrene 1 02/16/23 14:21 V29896JMV <2.38 µg/L 2.38 5.381,2,4-Trichlorobenzene 1 02/16/23 14:21 V29896JMV <1.42 µg/L 1.42 5.382,4,6-Trichlorophenol 1 02/16/23 14:21 V29896JMV 625.1Surrogate: Phenol-d5 25.0 Limits: 10-63%02/16/23 14:211 JMV Surrogate: 2-Fluorobiphenyl 71.9 Limits: 49-118%02/16/23 14:211 JMV V29896 Surrogate: 2-Fluorophenol 37.1 Limits: 22-84%02/16/23 14:211 JMV V29896 Surrogate: Nitrobenzene-d5 74.5 Limits: 43-123%02/16/23 14:211 JMV V29896 Surrogate: 4-Terphenyl-d14 96.7 Limits: 49-151%02/16/23 14:211 JMV V29896 Surrogate: 2,4,6-Tribromophenol 88.1 Limits: 31-144%02/16/23 14:211 JMV V29896 Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 13 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:Field Blank 99405 Matrix: 2/9/2023 9:15 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAVPH (Prep) MADEP-VPH Prep Batch(es):V29706 02/13/23 08:00 <11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 02/13/23 10:22 V29707TBL <25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 02/13/23 10:22 V29707TBL <4.02 µg/L 4.02 50.0Aromatic C9-C10 1 02/13/23 10:22 V29707TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)82.7 Limits: 70-130%02/13/23 10:221 TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)80.0 Limits: 70-130%02/13/23 10:221 TBL Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 14 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Test Results Units MDL MQL By Analytical Method Date / Time Analyzed DF 0.004 J mg/L 0.002 0.006Lead 1 02/17/23 21:38 6010DBKN Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 15 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <1.80 µg/L 1.80 10.0Acetone 1 02/13/23 15:34 V29758MSA <0.180 µg/L 0.180 0.500Benzene 1 02/13/23 15:34 V29758MSA <0.210 µg/L 0.210 0.500Bromobenzene 1 02/13/23 15:34 V29758MSA <0.420 µg/L 0.420 1.00Bromochloromethane 1 02/13/23 15:34 V29758MSA <0.160 µg/L 0.160 0.500Bromodichloromethane 1 02/13/23 15:34 V29758MSA <1.50 µg/L 1.50 5.00Bromoform 1 02/13/23 15:34 V29758MSA <0.280 µg/L 0.280 1.00Bromomethane 1 02/13/23 15:34 V29758MSA 0.639 µg/L 0.180 0.500n-Butylbenzene 1 02/13/23 15:34 V29758MSA <0.200 µg/L 0.200 0.500 sec-Butyl benzene 1 02/13/23 15:34 V29758MSA <0.920 µg/L 0.920 2.00tert-Butyl benzene 1 02/13/23 15:34 V29758MSA <0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 02/13/23 15:34 V29758MSA <0.190 µg/L 0.190 0.500Chlorobenzene 1 02/13/23 15:34 V29758MSA <0.190 µg/L 0.190 0.500Chlorodibromomethane 1 02/13/23 15:34 V29758MSA <0.430 µg/L 0.430 1.00Chloroethane 1 02/13/23 15:34 V29758MSA <0.220 µg/L 0.220 0.500Chloroform 1 02/13/23 15:34 V29758MSA <0.220 µg/L 0.220 0.500 Chloromethane 1 02/13/23 15:34 V29758MSA <0.200 µg/L 0.200 0.5002-Chlorotoluene 1 02/13/23 15:34 V29758MSA <0.200 µg/L 0.200 0.5004-Chlorotoluene 1 02/13/23 15:34 V29758MSA <0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 02/13/23 15:34 V29758MSA <1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 02/13/23 15:34 V29758MSA <0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 02/13/23 15:34 V29758MSA <0.230 µg/L 0.230 0.500Dibromomethane 1 02/13/23 15:34 V29758MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 16 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 02/13/23 15:34 V29758MSA <0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 02/13/23 15:34 V29758MSA <0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 02/13/23 15:34 V29758MSA <1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 02/13/23 15:34 V29758MSA <0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 02/13/23 15:34 V29758MSA <0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 02/13/23 15:34 V29758MSA <0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 02/13/23 15:34 V29758MSA <0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 02/13/23 15:34 V29758MSA <0.180 µg/L 0.180 0.500 trans-1,2-Dichloroethene 1 02/13/23 15:34 V29758MSA <0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 02/13/23 15:34 V29758MSA <0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 02/13/23 15:34 V29758MSA <0.210 µg/L 0.210 2.002,2-Dichloropropane 1 02/13/23 15:34 V29758MSA <0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 02/13/23 15:34 V29758MSA <0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 02/13/23 15:34 V29758MSA <0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 02/13/23 15:34 V29758MSA <42.0 µg/L 42.0 200 Ethanol 1 02/13/23 15:34 V29758MSA <0.170 µg/L 0.170 0.500Ethylbenzene 1 02/13/23 15:34 V29758MSA <0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 02/13/23 15:34 V29758MSA <0.380 µg/L 0.380 1.002-Hexanone 1 02/13/23 15:34 V29758MSA <0.180 µg/L 0.180 0.500Isopropylbenzene 1 02/13/23 15:34 V29758MSA <0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 02/13/23 15:34 V29758MSA <0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 02/13/23 15:34 V29758MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 17 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 02/13/23 15:34 V29758MSA <0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 02/13/23 15:34 V29758MSA <0.330 µg/L 0.330 2.00Methylene Chloride 1 02/13/23 15:34 V29758MSA <0.470 µg/L 0.470 1.00Naphthalene 1 02/13/23 15:34 V29758MSA <0.190 µg/L 0.190 0.500n-Propylbenzene 1 02/13/23 15:34 V29758MSA <0.220 µg/L 0.220 0.500Styrene 1 02/13/23 15:34 V29758MSA <0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 02/13/23 15:34 V29758MSA <0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 02/13/23 15:34 V29758MSA <0.220 µg/L 0.220 0.500 Tetrachloroethene 1 02/13/23 15:34 V29758MSA <0.220 µg/L 0.220 0.500Toluene 1 02/13/23 15:34 V29758MSA <0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 02/13/23 15:34 V29758MSA <0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 02/13/23 15:34 V29758MSA <0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 02/13/23 15:34 V29758MSA <0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 02/13/23 15:34 V29758MSA <0.180 µg/L 0.180 0.500Trichloroethene 1 02/13/23 15:34 V29758MSA <0.180 µg/L 0.180 0.500 Trichlorofluoromethane 1 02/13/23 15:34 V29758MSA <0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 02/13/23 15:34 V29758MSA <0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 02/13/23 15:34 V29758MSA <0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 02/13/23 15:34 V29758MSA <1.00 µg/L 1.00 5.00Vinyl Acetate 1 02/13/23 15:34 V29758MSA <0.170 µg/L 0.170 0.500Vinyl Chloride 1 02/13/23 15:34 V29758MSA <0.210 µg/L 0.210 0.500o-Xylene 1 02/13/23 15:34 V29758MSA Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 18 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 6200 PT 6200B Prep Batch(es):V29757 02/13/23 09:00 <0.420 µg/L 0.420 1.00m,p-Xylene 1 02/13/23 15:34 V29758MSA <0.21 µg/L 0.210 0.500Xylene (Total)1 02/13/23 15:34 V29758 Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%02/13/23 15:341 MSA V29758 Surrogate: Dibromofluoromethane 96.0 Limits: 70-130%02/13/23 15:341 MSA V29758 Surrogate: 1,2-Dichloroethane - d4 96.6 Limits: 70-130%02/13/23 15:341 MSA V29758 Surrogate: Toluene-d8 99.0 Limits: 70-130%02/13/23 15:341 MSA V29758 Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <0.306 µg/L 0.306 2.03Acenaphthene 1 02/16/23 14:44 V29896JMV <0.301 µg/L 0.301 2.03Acenaphthylene 1 02/16/23 14:44 V29896JMV <0.848 µg/L 0.848 2.03Anthracene 1 02/16/23 14:44 V29896JMV <1.35 µg/L 1.35 10.2 Benzidine 1 02/16/23 14:44 V29896JMV <0.646 µg/L 0.646 2.03Benzo(a)anthracene 1 02/16/23 14:44 V29896JMV <1.04 µg/L 1.04 2.03Benzo(a)pyrene 1 02/16/23 14:44 V29896JMV <2.53 µg/L 2.53 5.08Benzo(b)fluoranthene 1 02/16/23 14:44 V29896JMV <1.03 µg/L 1.03 5.08Benzo(g,h,i)perylene 1 02/16/23 14:44 V29896JMV <2.02 µg/L 2.02 5.08Benzo(k)fluoranthene 1 02/16/23 14:44 V29896JMV <1.12 µg/L 1.12 10.2Benzoic Acid 1 02/16/23 14:44 V29896JMV <0.694 µg/L 0.694 5.08 Benzyl alcohol 1 02/16/23 14:44 V29896JMV <0.475 µg/L 0.475 5.08Bis(2-Chloroethoxy)methane 1 02/16/23 14:44 V29896JMV Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 19 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <1.06 µg/L 1.06 5.08Bis(2-Chloroethyl)ether 1 02/16/23 14:44 V29896JMV <1.10 µg/L 1.10 5.08Bis(2-Chloroisopropyl)ether 1 02/16/23 14:44 V29896JMV <3.53 µg/L 3.53 10.2Bis(2-ethylhexyl)phthalate 1 02/16/23 14:44 V29896JMV <1.13 µg/L 1.13 5.084-Bromophenyl phenyl ether 1 02/16/23 14:44 V29896JMV <1.86 µg/L 1.86 5.08Butyl benzyl phthalate 1 02/16/23 14:44 V29896JMV <1.20 µg/L 1.20 5.084-Chloro-3-methylphenol 1 02/16/23 14:44 V29896JMV <7.49 µg/L 7.49 20.32-Chloronaphthalene 1 02/16/23 14:44 V29896JMV <0.956 µg/L 0.956 10.22-Chlorophenol 1 02/16/23 14:44 V29896JMV <1.74 µg/L 1.74 5.08 4-Chlorophenyl phenyl ether 1 02/16/23 14:44 V29896JMV <0.411 µg/L 0.411 2.03Chrysene 1 02/16/23 14:44 V29896JMV <0.440 µg/L 0.440 2.03Dibenz(a,h)anthracene 1 02/16/23 14:44 V29896JMV <0.869 µg/L 0.869 5.08Dibenzofuran 1 02/16/23 14:44 V29896JMV <2.03 µg/L 2.03 5.081,2-Dichlorobenzene 1 02/16/23 14:44 V29896JMV <2.03 µg/L 2.03 5.081,3-Dichlorobenzene 1 02/16/23 14:44 V29896JMV <2.08 µg/L 2.08 5.081,4-Dichlorobenzene 1 02/16/23 14:44 V29896JMV <1.92 µg/L 1.92 5.08 3,3'-Dichlorobenzidine 1 02/16/23 14:44 V29896JMV <1.49 µg/L 1.49 10.22,4-Dichlorophenol 1 02/16/23 14:44 V29896JMV <0.756 µg/L 0.756 5.08Diethyl phthalate 1 02/16/23 14:44 V29896JMV <0.954 µg/L 0.954 5.08Dimethyl phthalate 1 02/16/23 14:44 V29896JMV <1.59 µg/L 1.59 20.32,4-Dimethylphenol 1 02/16/23 14:44 V29896JMV <2.09 µg/L 2.09 5.08Di-n-butyl phthalate 1 02/16/23 14:44 V29896JMV <2.11 µg/L 2.11 10.24,6-Dinitro-2-methylphenol 1 02/16/23 14:44 V29896JMV Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 20 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <1.96 µg/L 1.96 10.22,4-Dinitrophenol 1 02/16/23 14:44 V29896JMV <1.13 µg/L 1.13 5.082,4-Dinitrotoluene 1 02/16/23 14:44 V29896JMV <0.821 µg/L 0.821 5.082,6-Dinitrotoluene 1 02/16/23 14:44 V29896JMV <1.68 µg/L 1.68 5.08Di-n-Octyl Phthalate 1 02/16/23 14:44 V29896JMV <0.253 µg/L 0.253 2.03Fluoranthene 1 02/16/23 14:44 V29896JMV <0.819 µg/L 0.819 2.03Fluorene 1 02/16/23 14:44 V29896JMV <0.994 µg/L 0.994 5.08Hexachlorobenzene 1 02/16/23 14:44 V29896JMV <2.77 µg/L 2.77 5.08Hexachlorobutadiene 1 02/16/23 14:44 V29896JMV <2.08 µg/L 2.08 5.08 Hexachlorocyclopentadiene 1 02/16/23 14:44 V29896JMV <1.79 µg/L 1.79 5.08Hexachloroethane 1 02/16/23 14:44 V29896JMV <0.484 µg/L 0.484 2.03Indeno(1,2,3-cd)pyrene 1 02/16/23 14:44 V29896JMV <0.451 µg/L 0.451 5.08Isophorone 1 02/16/23 14:44 V29896JMV <1.16 µg/L 1.16 2.031-Methylnaphthalene 1 02/16/23 14:44 V29896JMV <0.675 µg/L 0.675 2.032-Methylnaphthalene 1 02/16/23 14:44 V29896JMV <0.738 µg/L 0.738 2.03Naphthalene 1 02/16/23 14:44 V29896JMV <0.919 µg/L 0.919 5.08 Nitrobenzene 1 02/16/23 14:44 V29896JMV <0.500 µg/L 0.500 5.082-Nitrophenol 1 02/16/23 14:44 V29896JMV <1.25 µg/L 1.25 10.24-Nitrophenol 1 02/16/23 14:44 V29896JMV <1.12 µg/L 1.12 5.08N-Nitrosodiphenylamine 1 02/16/23 14:44 V29896JMV <0.651 µg/L 0.651 5.08N-Nitroso-di-n-propylamine 1 02/16/23 14:44 V29896JMV <1.45 µg/L 1.45 5.08Pentachlorophenol 1 02/16/23 14:44 V29896JMV <0.434 µg/L 0.434 2.03Phenanthrene 1 02/16/23 14:44 V29896JMV Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 21 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF 625.1 (Prep) 625.1 Prep Batch(es):V29776 02/15/23 09:03 <0.661 µg/L 0.661 5.08Phenol 1 02/16/23 14:44 V29896JMV <0.440 µg/L 0.440 2.03Pyrene 1 02/16/23 14:44 V29896JMV <2.25 µg/L 2.25 5.081,2,4-Trichlorobenzene 1 02/16/23 14:44 V29896JMV <1.34 µg/L 1.34 5.082,4,6-Trichlorophenol 1 02/16/23 14:44 V29896JMV 625.1Surrogate: Phenol-d5 22.5 Limits: 10-63%02/16/23 14:441 JMV Surrogate: 2-Fluorobiphenyl 72.2 Limits: 49-118%02/16/23 14:441 JMV V29896 Surrogate: 2-Fluorophenol 31.8 Limits: 22-84%02/16/23 14:441 JMV V29896 Surrogate: Nitrobenzene-d5 70.5 Limits: 43-123%02/16/23 14:441 JMV V29896 Surrogate: 4-Terphenyl-d14 83.3 Limits: 49-151%02/16/23 14:441 JMV V29896 Surrogate: 2,4,6-Tribromophenol 79.2 Limits: 31-144%02/16/23 14:441 JMV V29896 Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 22 of 39 , REPORT OF ANALYSISReport Number : Project Information : NC 28273 23-041-0012 00012 CES Group 3525 Whitehall Park Dr. Suite 150 Greg Hans Charlotte Received : 02/10/2023 City of Claremont Report Date : 02/21/2023 Sample ID : Lab No : Sampled:MW-1 99406 Matrix: 2/9/2023 10:10 Aqueous Analytical Method: Prep Method: Test Results Units MDL MQL By Analytical Batch Date / Time Analyzed DF MAVPH (Prep) MADEP-VPH Prep Batch(es):V29706 02/13/23 08:00 66.8 µg/L 11.5 50.0Aliphatic C5-C8 1 02/13/23 10:46 V29707TBL <25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 02/13/23 10:46 V29707TBL <4.02 µg/L 4.02 50.0Aromatic C9-C10 1 02/13/23 10:46 V29707TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)111 Limits: 70-130%02/13/23 10:461 TBL MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)105 Limits: 70-130%02/13/23 10:461 TBL Qualifiers/ Definitions Estimated valueJDilution FactorDF Method Quantitation LimitMQL Page 23 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Metals Analysis 6010D L664995QC Analytical Batch(es): Analysis Method: Analysis Description: 3005A QC Prep:L664176 Associated Lab Samples: 99405, 99406 LRB-L664176 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits 02/17/23 21:020.0060.002<0.002mg/LLead LCS-L664176Laboratory Control Sample Parameter LCS %RecLCS Result Spike Conc.Units % Rec Limits 1020.1020.100mg/LLead 80-120 V 99435-MS-L664176 V 99435-MSD-L664176Matrix Spike & Matrix Spike Duplicate MS Result Parameter Max RPD MS %Rec MSD Result MSD Spike Conc. MS Spike Conc.ResultUnits %Rec Limits MSD %Rec RPD 0.103 1010.1040.1000.1000.002mg/LLead 102 75-125 0.9 20 V 99435-PDS-L664176Post Digestion Spike Parameter Analyzed% Recovery PDS ResultUnits 02/17/23 22:141010.252mg/LLead Page 1 of 14Date:02/21/2023 03:56 PM Page 24 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V29758QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V29757 Associated Lab Samples: 99405, 99406 LRB-V29757 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/13/23 14:4710.01.80<1.80µg/LAcetone 02/13/23 14:470.5000.180<0.180µg/LBenzene 02/13/23 14:470.5000.210<0.210µg/LBromobenzene 02/13/23 14:471.000.420<0.420µg/LBromochloromethane 02/13/23 14:470.5000.160<0.160µg/LBromodichloromethane 02/13/23 14:475.001.50<1.50µg/LBromoform 02/13/23 14:471.000.280<0.280µg/LBromomethane 02/13/23 14:470.5000.180<0.180µg/Ln-Butylbenzene 02/13/23 14:470.5000.200<0.200µg/Lsec-Butyl benzene 02/13/23 14:472.000.920<0.920µg/Ltert-Butyl benzene 02/13/23 14:470.5000.180<0.180µg/LCarbon Tetrachloride 02/13/23 14:470.5000.190<0.190µg/LChlorobenzene 02/13/23 14:470.5000.190<0.190µg/LChlorodibromomethane 02/13/23 14:471.000.430<0.430µg/LChloroethane 02/13/23 14:470.5000.220<0.220µg/LChloroform 02/13/23 14:470.5000.220<0.220µg/LChloromethane 02/13/23 14:470.5000.200<0.200µg/L2-Chlorotoluene 02/13/23 14:470.5000.200<0.200µg/L4-Chlorotoluene 02/13/23 14:470.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE) 02/13/23 14:472.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane 02/13/23 14:470.5000.200<0.200µg/L1,2-Dibromoethane 02/13/23 14:470.5000.230<0.230µg/LDibromomethane 02/13/23 14:470.5000.220<0.220µg/L1,2-Dichlorobenzene 02/13/23 14:470.5000.190<0.190µg/L1,3-Dichlorobenzene 02/13/23 14:470.5000.210<0.210µg/L1,4-Dichlorobenzene 02/13/23 14:475.001.20<1.20µg/LDichlorodifluoromethane 02/13/23 14:470.5000.240<0.240µg/L1,1-Dichloroethane Page 2 of 14Date:02/21/2023 03:56 PM Page 25 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V29758QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V29757 Associated Lab Samples: 99405, 99406 LRB-V29757 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/13/23 14:470.5000.150<0.150µg/L1,2-Dichloroethane 02/13/23 14:470.5000.150<0.150µg/L1,1-Dichloroethene 02/13/23 14:470.5000.200<0.200µg/Lcis-1,2-Dichloroethene 02/13/23 14:470.5000.180<0.180µg/Ltrans-1,2-Dichloroethene 02/13/23 14:470.5000.190<0.190µg/L1,2-Dichloropropane 02/13/23 14:470.5000.130<0.130µg/L1,3-Dichloropropane 02/13/23 14:472.000.210<0.210µg/L2,2-Dichloropropane 02/13/23 14:470.5000.200<0.200µg/L1,1-Dichloropropene 02/13/23 14:470.5000.210<0.210µg/Lcis-1,3-Dichloropropene 02/13/23 14:470.5000.150<0.150µg/Ltrans-1,3-Dichloropropene 02/13/23 14:4720042.0<42.0µg/LEthanol 02/13/23 14:470.5000.170<0.170µg/LEthylbenzene 02/13/23 14:473.000.350<0.350µg/LHexachlorobutadiene 02/13/23 14:471.000.380<0.380µg/L2-Hexanone 02/13/23 14:470.5000.180<0.180µg/LIsopropylbenzene 02/13/23 14:470.5000.089<0.089µg/L4-Isopropyl toluene 02/13/23 14:475.000.710<0.710µg/LMethyl Ethyl Ketone (MEK) 02/13/23 14:471.000.140<0.140µg/LMethyl tert-butyl ether (MTBE) 02/13/23 14:471.000.078<0.078µg/L4-Methyl-2-Pentanone 02/13/23 14:472.000.330<0.330µg/LMethylene Chloride 02/13/23 14:471.000.470<0.470µg/LNaphthalene 02/13/23 14:470.5000.190<0.190µg/Ln-Propylbenzene 02/13/23 14:470.5000.220<0.220µg/LStyrene 02/13/23 14:470.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane 02/13/23 14:470.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane 02/13/23 14:470.5000.220<0.220µg/LTetrachloroethene 02/13/23 14:470.5000.220<0.220µg/LToluene Page 3 of 14Date:02/21/2023 03:56 PM Page 26 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V29758QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V29757 Associated Lab Samples: 99405, 99406 LRB-V29757 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/13/23 14:470.5000.380<0.380µg/L1,2,3-Trichlorobenzene 02/13/23 14:470.5000.310<0.310µg/L1,2,4-Trichlorobenzene 02/13/23 14:470.5000.160<0.160µg/L1,1,1-Trichloroethane 02/13/23 14:470.5000.096<0.096µg/L1,1,2-Trichloroethane 02/13/23 14:470.5000.180<0.180µg/LTrichloroethene 02/13/23 14:470.5000.180<0.180µg/LTrichlorofluoromethane 02/13/23 14:470.5000.270<0.270µg/L1,2,3-Trichloropropane 02/13/23 14:470.5000.190<0.190µg/L1,2,4-Trimethylbenzene 02/13/23 14:470.5000.180<0.180µg/L1,3,5-Trimethylbenzene 02/13/23 14:475.001.00<1.00µg/LVinyl Acetate 02/13/23 14:470.5000.170<0.170µg/LVinyl Chloride 02/13/23 14:470.5000.210<0.210µg/Lo-Xylene 02/13/23 14:471.000.420<0.420µg/Lm,p-Xylene 02/13/23 14:474-Bromofluorobenzene (S)101 70-130 02/13/23 14:47Dibromofluoromethane (S)95.8 70-130 02/13/23 14:471,2-Dichloroethane - d4 (S)99.4 70-130 02/13/23 14:47Toluene-d8 (S)99.6 70-130 LCS-V29757 LCSD-V29757Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 24.1 60.264.525.840.0µg/LAcetone 40-160 6.8 20.0 20.4 10210921.820.0µg/LBenzene 70-130 6.6 20.0 20.8 10410921.720.0µg/LBromobenzene 70-130 4.2 20.0 20.0 10010821.620.0µg/LBromochloromethane 70-130 7.6 20.0 19.9 99.510320.520.0µg/LBromodichloromethane 70-130 2.9 20.0 Page 4 of 14Date:02/21/2023 03:56 PM Page 27 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V29758QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V29757 LCS-V29757 LCSD-V29757Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 18.1 90.594.518.920.0µg/LBromoform 70-130 4.3 20.0 24.4 12212725.320.0µg/LBromomethane 60-140 3.6 20.0 21.2 10611422.720.0µg/Ln-Butylbenzene 70-130 6.8 20.0 20.7 10411021.920.0µg/Lsec-Butyl benzene 70-130 5.6 20.0 21.0 10511022.020.0µg/Ltert-Butyl benzene 70-130 4.6 20.0 20.7 10411122.120.0µg/LCarbon Tetrachloride 70-130 6.5 20.0 20.5 10310921.820.0µg/LChlorobenzene 70-130 6.1 20.0 21.3 10710721.320.0µg/LChlorodibromomethane 70-130 0.0 20.0 22.4 11211122.120.0µg/LChloroethane 60-140 1.3 20.0 19.7 98.510520.920.0µg/LChloroform 70-130 5.9 20.0 19.6 98.010921.720.0µg/LChloromethane 60-140 10.1 20.0 20.7 10410921.820.0µg/L2-Chlorotoluene 70-130 5.1 20.0 20.6 10310921.720.0µg/L4-Chlorotoluene 70-130 5.2 20.0 19.7 98.510721.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 7.8 20.0 21.2 10611322.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 6.3 20.0 21.3 10711022.020.0µg/L1,2-Dibromoethane 70-130 3.2 20.0 20.2 10110420.820.0µg/LDibromomethane 70-130 2.9 20.0 21.1 10611122.120.0µg/L1,2-Dichlorobenzene 70-130 4.6 20.0 21.1 10611222.420.0µg/L1,3-Dichlorobenzene 70-130 5.9 20.0 20.9 10511022.020.0µg/L1,4-Dichlorobenzene 70-130 5.1 20.0 18.8 94.099.019.820.0µg/LDichlorodifluoromethane 60-140 5.1 20.0 20.2 10110921.820.0µg/L1,1-Dichloroethane 70-130 7.6 20.0 19.7 98.510520.920.0µg/L1,2-Dichloroethane 70-130 5.9 20.0 20.8 10412224.320.0µg/L1,1-Dichloroethene 70-130 15.5 20.0 19.9 99.510821.520.0µg/Lcis-1,2-Dichloroethene 70-130 7.7 20.0 20.6 10311222.320.0µg/Ltrans-1,2-Dichloroethene 70-130 7.9 20.0 Page 5 of 14Date:02/21/2023 03:56 PM Page 28 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V29758QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V29757 LCS-V29757 LCSD-V29757Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 20.8 10410821.620.0µg/L1,2-Dichloropropane 70-130 3.7 20.0 21.6 10810721.320.0µg/L1,3-Dichloropropane 70-130 1.3 20.0 20.8 10411523.020.0µg/L2,2-Dichloropropane 70-130 10.0 20.0 22.0 11011823.520.0µg/L1,1-Dichloropropene 70-130 6.5 20.0 20.9 10510921.720.0µg/Lcis-1,3-Dichloropropene 70-130 3.7 20.0 21.3 10711021.920.0µg/Ltrans-1,3-Dichloropropene 70-130 2.7 20.0 470 94.0115575500µg/LEthanol 60-140 20.0*20.0 20.3 10210721.420.0µg/LEthylbenzene 70-130 5.2 20.0 22.9 11512024.020.0µg/LHexachlorobutadiene 70-130 4.6 20.0 17.7 88.589.517.920.0µg/L2-Hexanone 60-140 1.1 20.0 20.9 10511222.320.0µg/LIsopropylbenzene 70-130 6.4 20.0 21.6 10811422.820.0µg/L4-Isopropyl toluene 70-130 5.4 20.0 13.8 69.075.015.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 8.3 20.0 19.8 99.010621.220.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.8 20.0 19.8 99.010520.920.0µg/L4-Methyl-2-Pentanone 60-140 5.4 20.0 20.3 10210721.320.0µg/LMethylene Chloride 70-130 4.8 20.0 22.4 11211923.720.0µg/LNaphthalene 70-130 5.6 20.0 21.0 10511122.220.0µg/Ln-Propylbenzene 70-130 5.5 20.0 20.4 10210921.820.0µg/LStyrene 70-130 6.6 20.0 20.8 10410921.720.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.2 20.0 20.1 10110921.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 8.1 20.0 22.5 11311623.220.0µg/LTetrachloroethene 70-130 3.0 20.0 21.0 10511021.920.0µg/LToluene 70-130 4.1 20.0 24.6 123131*26.220.0µg/L1,2,3-Trichlorobenzene 70-130 6.2 20.0 23.0 11512525.020.0µg/L1,2,4-Trichlorobenzene 70-130 8.3 20.0 20.3 10211021.920.0µg/L1,1,1-Trichloroethane 70-130 7.5 20.0 Page 6 of 14* QC Fail Date:02/21/2023 03:56 PM Page 29 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V29758QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V29757 LCS-V29757 LCSD-V29757Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 20.3 10210721.320.0µg/L1,1,2-Trichloroethane 70-130 4.8 20.0 20.7 10411122.120.0µg/LTrichloroethene 70-130 6.5 20.0 21.0 10511122.120.0µg/LTrichlorofluoromethane 60-140 5.1 20.0 21.3 10711122.220.0µg/L1,2,3-Trichloropropane 70-130 4.1 20.0 20.7 10410921.720.0µg/L1,2,4-Trimethylbenzene 70-130 4.7 20.0 20.8 10411022.020.0µg/L1,3,5-Trimethylbenzene 70-130 5.6 20.0 26.8 13413426.720.0µg/LVinyl Acetate 60-140 0.3 20.0 21.1 10610921.820.0µg/LVinyl Chloride 60-140 3.2 20.0 19.5 97.510420.820.0µg/Lo-Xylene 70-130 6.4 20.0 41.2 10311044.140.0µg/Lm,p-Xylene 70-130 6.7 20.0 99.61004-Bromofluorobenzene (S)70-130 93.894.6Dibromofluoromethane (S)70-130 96.097.81,2-Dichloroethane - d4 (S)70-130 10698.8Toluene-d8 (S)70-130 Page 7 of 14Date:02/21/2023 03:56 PM Page 30 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V29896QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V29776 Associated Lab Samples: 99405, 99406 LRB-V29776 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/16/23 12:492.000.302<0.302µg/LAcenaphthene 02/16/23 12:492.000.297<0.297µg/LAcenaphthylene 02/16/23 12:492.000.836<0.836µg/LAnthracene 02/16/23 12:4910.01.32<1.32µg/LBenzidine 02/16/23 12:492.000.637<0.637µg/LBenzo(a)anthracene 02/16/23 12:492.001.02<1.02µg/LBenzo(a)pyrene 02/16/23 12:495.002.49<2.49µg/LBenzo(b)fluoranthene 02/16/23 12:495.001.01<1.01µg/LBenzo(g,h,i)perylene 02/16/23 12:495.001.99<1.99µg/LBenzo(k)fluoranthene 02/16/23 12:4910.01.10<1.10µg/LBenzoic Acid 02/16/23 12:495.000.684<0.684µg/LBenzyl alcohol 02/16/23 12:495.000.468<0.468µg/LBis(2-Chloroethoxy)methane 02/16/23 12:495.001.04<1.04µg/LBis(2-Chloroethyl)ether 02/16/23 12:495.001.08<1.08µg/LBis(2-Chloroisopropyl)ether 02/16/23 12:4910.03.46<3.46µg/LBis(2-ethylhexyl)phthalate 02/16/23 12:495.001.11<1.11µg/L4-Bromophenyl phenyl ether 02/16/23 12:495.001.83<1.83µg/LButyl benzyl phthalate 02/16/23 12:495.001.18<1.18µg/L4-Chloro-3-methylphenol 02/16/23 12:4920.07.38<7.38µg/L2-Chloronaphthalene 02/16/23 12:4910.00.938<0.938µg/L2-Chlorophenol 02/16/23 12:495.001.71<1.71µg/L4-Chlorophenyl phenyl ether 02/16/23 12:492.000.405<0.405µg/LChrysene 02/16/23 12:492.000.434<0.434µg/LDibenz(a,h)anthracene 02/16/23 12:495.000.856<0.856µg/LDibenzofuran 02/16/23 12:495.002.00<2.00µg/L1,2-Dichlorobenzene 02/16/23 12:495.002.00<2.00µg/L1,3-Dichlorobenzene 02/16/23 12:495.002.05<2.05µg/L1,4-Dichlorobenzene Page 8 of 14Date:02/21/2023 03:56 PM Page 31 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V29896QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V29776 Associated Lab Samples: 99405, 99406 LRB-V29776 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/16/23 12:495.001.89<1.89µg/L3,3'-Dichlorobenzidine 02/16/23 12:4910.01.46<1.46µg/L2,4-Dichlorophenol 02/16/23 12:495.000.745<0.745µg/LDiethyl phthalate 02/16/23 12:495.000.939<0.939µg/LDimethyl phthalate 02/16/23 12:4920.01.57<1.57µg/L2,4-Dimethylphenol 02/16/23 12:495.002.06<2.06µg/LDi-n-butyl phthalate 02/16/23 12:4910.02.07<2.07µg/L4,6-Dinitro-2-methylphenol 02/16/23 12:4910.01.92<1.92µg/L2,4-Dinitrophenol 02/16/23 12:495.001.11<1.11µg/L2,4-Dinitrotoluene 02/16/23 12:495.000.809<0.809µg/L2,6-Dinitrotoluene 02/16/23 12:495.001.65<1.65µg/LDi-n-Octyl Phthalate 02/16/23 12:492.000.250<0.250µg/LFluoranthene 02/16/23 12:492.000.807<0.807µg/LFluorene 02/16/23 12:495.000.979<0.979µg/LHexachlorobenzene 02/16/23 12:495.002.73<2.73µg/LHexachlorobutadiene 02/16/23 12:495.002.05<2.05µg/LHexachlorocyclopentadiene 02/16/23 12:495.001.76<1.76µg/LHexachloroethane 02/16/23 12:492.000.477<0.477µg/LIndeno(1,2,3-cd)pyrene 02/16/23 12:495.000.444<0.444µg/LIsophorone 02/16/23 12:492.001.14<1.14µg/L1-Methylnaphthalene 02/16/23 12:492.000.666<0.666µg/L2-Methylnaphthalene 02/16/23 12:492.000.728<0.728µg/LNaphthalene 02/16/23 12:495.000.905<0.905µg/LNitrobenzene 02/16/23 12:495.000.493<0.493µg/L2-Nitrophenol 02/16/23 12:4910.01.23<1.23µg/L4-Nitrophenol 02/16/23 12:495.001.10<1.10µg/LN-Nitrosodiphenylamine 02/16/23 12:495.000.641<0.641µg/LN-Nitroso-di-n-propylamine Page 9 of 14Date:02/21/2023 03:56 PM Page 32 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V29896QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V29776 Associated Lab Samples: 99405, 99406 LRB-V29776 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/16/23 12:495.001.43<1.43µg/LPentachlorophenol 02/16/23 12:492.000.428<0.428µg/LPhenanthrene 02/16/23 12:495.000.651<0.651µg/LPhenol 02/16/23 12:492.000.434<0.434µg/LPyrene 02/16/23 12:495.002.21<2.21µg/L1,2,4-Trichlorobenzene 02/16/23 12:495.001.32<1.32µg/L2,4,6-Trichlorophenol 02/16/23 12:492-Fluorobiphenyl (S)74.8 49-118 02/16/23 12:492-Fluorophenol (S)40.0 22-84 02/16/23 12:49Nitrobenzene-d5 (S)76.8 43-123 02/16/23 12:494-Terphenyl-d14 (S)103 49-151 02/16/23 12:492,4,6-Tribromophenol (S)85.9 31-144 02/16/23 12:49Phenol-d5 (S)27.6 10-63 LCS-V29776 LCSD-V29776Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 39.9 79.882.841.450.0µg/LAcenaphthene 47-145 3.6 20.0 40.6 81.284.042.050.0µg/LAcenaphthylene 33-145 3.3 20.0 46.3 92.697.248.650.0µg/LAnthracene 27-133 4.8 20.0 23.0 46.094.647.350.0µg/LBenzidine 15-150 69.1*20.0 44.5 89.093.446.750.0µg/LBenzo(a)anthracene 33-143 4.8 20.0 41.0 82.082.241.150.0µg/LBenzo(a)pyrene 17-163 0.2 20.0 40.0 80.079.839.950.0µg/LBenzo(b)fluoranthene 24-159 0.2 20.0 35.8 71.671.835.950.0µg/LBenzo(g,h,i)perylene 10-219 0.2 20.0 35.9 71.872.236.150.0µg/LBenzo(k)fluoranthene 11-162 0.5 20.0 20.1 40.241.420.750.0µg/LBenzoic Acid 10-125 2.9 20.0 Page 10 of 14* QC Fail Date:02/21/2023 03:56 PM Page 33 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V29896QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V29776 LCS-V29776 LCSD-V29776Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 34.2 68.467.233.650.0µg/LBenzyl alcohol 16-107 1.7 20.0 38.0 76.075.637.850.0µg/LBis(2-Chloroethoxy)methane 33-184 0.5 20.0 31.6 63.262.431.250.0µg/LBis(2-Chloroethyl)ether 12-158 1.2 20.0 30.7 61.459.829.950.0µg/LBis(2-Chloroisopropyl)ether 36-166 2.6 20.0 48.1 96.210150.550.0µg/LBis(2-ethylhexyl)phthalate 10-158 4.8 20.0 46.0 92.090.645.350.0µg/L4-Bromophenyl phenyl ether 53-127 1.5 20.0 44.7 89.495.647.850.0µg/LButyl benzyl phthalate 10-152 6.7 20.0 41.1 82.286.443.250.0µg/L4-Chloro-3-methylphenol 22-147 4.9 20.0 38.6 77.279.639.850.0µg/L2-Chloronaphthalene 60-118 3.0 20.0 31.4 62.862.031.050.0µg/L2-Chlorophenol 23-134 1.2 20.0 43.1 86.290.045.050.0µg/L4-Chlorophenyl phenyl ether 25-158 4.3 20.0 40.4 80.883.841.950.0µg/LChrysene 17-168 3.6 20.0 38.8 77.676.638.350.0µg/LDibenz(a,h)anthracene 10-227 1.2 20.0 41.7 83.486.843.450.0µg/LDibenzofuran 39-114 3.9 20.0 28.5 57.058.029.050.0µg/L1,2-Dichlorobenzene 32-129 1.7 20.0 27.9 55.856.428.250.0µg/L1,3-Dichlorobenzene 20-124 1.0 20.0 28.2 56.457.228.650.0µg/L1,4-Dichlorobenzene 20-124 1.4 20.0 45.9 91.894.447.250.0µg/L3,3'-Dichlorobenzidine 10-262 2.7 20.0 39.8 79.679.239.650.0µg/L2,4-Dichlorophenol 39-135 0.5 20.0 43.7 87.492.246.150.0µg/LDiethyl phthalate 10-114 5.3 20.0 43.5 87.089.044.550.0µg/LDimethyl phthalate 10-112 2.2 20.0 50.1 10098.449.250.0µg/L2,4-Dimethylphenol 32-119 1.8 20.0 51.0 10210854.150.0µg/LDi-n-butyl phthalate 10-118 5.8 20.0 54.5 10910552.450.0µg/L4,6-Dinitro-2-methylphenol 10-181 3.9 20.0 56.6 11310452.250.0µg/L2,4-Dinitrophenol 10-191 8.0 20.0 54.2 10810753.750.0µg/L2,4-Dinitrotoluene 39-139 0.9 20.0 Page 11 of 14Date:02/21/2023 03:56 PM Page 34 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V29896QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V29776 LCS-V29776 LCSD-V29776Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 44.0 88.087.443.750.0µg/L2,6-Dinitrotoluene 50-158 0.6 20.0 43.3 86.687.043.550.0µg/LDi-n-Octyl Phthalate 10-146 0.4 20.0 42.8 85.689.844.950.0µg/LFluoranthene 26-137 4.7 20.0 42.3 84.688.444.250.0µg/LFluorene 59-121 4.3 20.0 44.1 88.290.445.250.0µg/LHexachlorobenzene 10-152 2.4 20.0 33.5 67.066.033.050.0µg/LHexachlorobutadiene 24-116 1.5 20.0 36.3 72.672.236.150.0µg/LHexachlorocyclopentadiene 32-117 0.5 20.0 27.3 54.653.626.850.0µg/LHexachloroethane 40-113 1.8 20.0 37.9 75.875.037.550.0µg/LIndeno(1,2,3-cd)pyrene 10-171 1.0 20.0 33.5 67.067.633.850.0µg/LIsophorone 21-196 0.8 20.0 36.6 73.273.636.850.0µg/L1-Methylnaphthalene 40-135 0.5 20.0 36.4 72.872.636.350.0µg/L2-Methylnaphthalene 18-121 0.2 20.0 33.8 67.668.434.250.0µg/LNaphthalene 21-133 1.1 20.0 35.7 71.473.036.550.0µg/LNitrobenzene 35-180 2.2 20.0 43.0 86.082.241.150.0µg/L2-Nitrophenol 29-182 4.5 20.0 15.0 30.031.815.950.0µg/L4-Nitrophenol 10-132 5.8 20.0 54.2 10810954.750.0µg/LN-Nitrosodiphenylamine 69-152 0.9 20.0 37.8 75.672.436.250.0µg/LN-Nitroso-di-n-propylamine 10-230 4.3 20.0 52.9 10610452.250.0µg/LPentachlorophenol 14-176 1.3 20.0 44.6 89.291.845.950.0µg/LPhenanthrene 54-120 2.8 20.0 15.5 31.030.215.150.0µg/LPhenol 10-112 2.6 20.0 42.1 84.288.644.350.0µg/LPyrene 52-115 5.0 20.0 31.6 63.263.031.550.0µg/L1,2,4-Trichlorobenzene 44-142 0.3 20.0 42.8 85.686.243.150.0µg/L2,4,6-Trichlorophenol 37-144 0.6 20.0 74.678.82-Fluorobiphenyl (S)49-118 33.033.32-Fluorophenol (S)22-84 Page 12 of 14Date:02/21/2023 03:56 PM Page 35 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: 625.1 - Base/Neutrals and Acids by GC/MS 625.1 V29896QC Analytical Batch(es): Analysis Method: Analysis Description: 625.1 (Prep) QC Prep:V29776 LCS-V29776 LCSD-V29776Laboratory Control Sample & LCSD LCSD ResultParameter LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 76.478.6Nitrobenzene-d5 (S)43-123 88.896.04-Terphenyl-d14 (S)49-151 95.695.92,4,6-Tribromophenol (S)31-144 22.923.2Phenol-d5 (S)10-63 Page 13 of 14Date:02/21/2023 03:56 PM Page 36 of 39 Quality Control Data 23-041-0012Report No: Project Description: Client ID:CES Group City of Claremont QC Prep Batch Method: Massachusetts VPH MADEP-VPH V29707QC Analytical Batch(es): Analysis Method: Analysis Description: MAVPH (Prep) QC Prep:V29706 Associated Lab Samples: 99405, 99406 LRB-V29706 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLMDLBlank ResultUnits % Recovery % Rec Limits 02/13/23 09:5850.011.5<11.5µg/LAliphatic C5-C8 02/13/23 09:5850.025.8<25.8µg/LAliphatic C9-C12 02/13/23 09:5850.04.02<4.02µg/LAromatic C9-C10 02/13/23 09:582,5-Dibromotoluene (FID) (S)87.6 70-130 02/13/23 09:582,5-Dibromotoluene (PID) (S)81.7 70-130 LCS-V29706 LCSD-V29706Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 293 97.691.0273300µg/LAliphatic C5-C8 70-130 7.0 50.0 354 118118354300µg/LAliphatic C9-C12 70-130 0.0 50.0 114 114111111100µg/LAromatic C9-C10 70-130 2.6 50.0 92.086.12,5-Dibromotoluene (FID) (S)70-130 83.188.52,5-Dibromotoluene (PID) (S)70-130 Page 14 of 14Date:02/21/2023 03:56 PM Page 37 of 39 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-041-0012 CES Group 00012 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT15 4.6C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angelo Norvell Date & Time:02/10/2023 12:50:10 Special precautions or instructions included? Comments: Page 38 of 39 Page 39 of 39 APPENDIX D HEALTH & SAFTEY PLAN AND JOB HAZARD ANALYSIS 1 ENVIRONMENTAL MANAGEMENT AND HEALTH AND SAFETY PLAN NCDEQ Project MO-2944_5469 City of Claremont 3301 E Main Street Claremont, Catawba County, NC CES PROJECT NUMBER: 8084.0123E Prepared by: CES GROUP ENGINEERS, LLP 3525 Whitehall Park Drive, Suite 150 Charlotte, NC 28273 February 3, 2023 i TABLE OF CONTENTS Page 1.0 INTRODUCTION 1 1.1 PURPOSE/OBJECTIVE 2 1.2 RESPONSIBILITIES FOR HEALTH AND SAFETY 3 1.3 SUBCONTRACTOR’S RESPONSIBILITY 3 2.0 ASSIGNMENT OF RESPONSIBILITY 4 2.1 SITE SAFETY OFFICER 4 2.2 PROJECT MANAGER(S) 5 3.0 BACKGROUND AND HAZARD EVALUATION 7 3.1 PROJECT DESCRIPTION 7 3.2 HAZARD EVALUATION 7 3.3 SAFETY DATA SHEETS (SDS) 8 4.0 AIR MONITORING 9 4.1 MONITORING EQUIPMENT 9 4.2 TYPES AND FREQUENCY OF MONITORING 10 4.2.1 Breathing Zone Monitoring 10 4.2.2 Explosive Gas Source Monitoring 10 4.2.3 Work Area Monitoring 10 4.2.4 Dust Monitoring 10 4.3 ACTION LEVELS 11 5.0 PERSONAL PROTECTIVE EQUIPMENT AND PROCEDURES 11 5.1 RESPIRATORY PROTECTION 11 5.2 PROTECTIVE CLOTHING 12 5.3 LEVELS OF PROTECTION 13 5.3.1 Modified Level D 13 5.3.2 Level D Protection 13 5.3.3 Level C Protection 14 5.3.4 Level B Protection 14 6.0 SITE CONTROL 15 6.1 REGULATED AREAS 15 6.2 ACCESS/SITE SECURITY 16 6.3 POSTING/BARRICADES 16 ii Page 7.0 POLICIES 16 7.1 GENERAL WORK PRACTICES 16 7.2 HEAVY EQUIPMENT OPERATION 17 7.3 SANITATION 19 8.0 DECONTAMINATION 19 8.1 PERSONAL DECONTAMINATION 20 8.2 EQUIPMENT DECONTAMINATION 21 9.0 TRAINING 22 9.1 BASIC TRAINING 22 9.2 SITE-SPECIFIC TRAINING 22 10.0 HEALTH MONITORING 23 10.1 PHYSICAL EXAMINATION 23 10.2 HEAT STRESS 23 10.3 COLD STRESS 24 10.4 SELF MONITORING 26 11.0 SITE STANDARD OPERATING PROCEDURES 26 11.1 WORK PRACTICES 26 11.2 COMMUNICATION PROCEDURES 27 12.0 EMERGENCY PROCEDURES 28 12.1 GENERAL 28 12.2 RESPONSIBILITIES 29 12.3 EMERGENCY CONTACT LIST 30 12.4 PERSONNEL INJURY IN THE EXCLUSION ZONE 32 12.5 PERSONNEL INJURY IN THE SUPPORT ZONE 32 12.6 FIRE OR EXPLOSION 32 12.7 PERSONAL PROTECTIVE EQUIPMENT FAILURE 32 12.8 POLLUTANT DISCHARGES/SPILLS 32 APPENDIX A Safety Data Sheet (Benzene - Volatile Organic Compounds) APPENDIX B Emergency Phone Numbers / Contact List APPENDIX C Route to Hospital 1 ENVIRONMENTAL MANAGEMENT AND HEALTH AND SAFETY PLAN (EMP) NCDEQ Project MO-2944_5469 City of Claremont 3301 E Main Street Claremont, Catawba County, NC 1.0 INTRODUCTION This Environmental Management and Health and Safety Plan (EMP), additionally referred to as the ‘plan”, has been developed for CES Group Engineers, LLP (CES), for application to work completed at NCDEQ MO-2944_5469, City of Claremont, 3301 E Main Street, Claremont, Catawba County, North Carolina, under CES Project Number: 8084.0123E. For the purpose of this plan, the term “project” references “NCDEQ MO-2944_5469”. Additionally, this plan should also be utilized for any work completed at surrounding properties where contamination, or additional assessment activities, may be located. For the purpose of this plan, the term “subsurface investigation” will include, but is not limited to, geophysical investigations, drilling soil borings with conversion to temporary or permanent monitoring wells, excavation and removal of encountered underground storage tanks (USTs), and contaminated soils / groundwater, and additional assessment and remediation activities, which may include hand-augering of soil borings, installation of monitoring wells and/or remedial recovery wells, groundwater monitoring and sampling, and injections, and the abandonment of monitoring wells. The term “subsurface investigation” may also be referred to as “excavation” in this plan. The plan addresses health and safety procedures and information relevant to environmental services being provided by CES personnel, and/or subcontracted personnel. The health and safety portion of the plan provides procedures to minimize: (1) the potential for accidents from physical hazards, and (2) the potential for exposure to chemical contaminants during activities which disturb the subsurface materials in the event that contamination of soil or groundwater by special wastes is encountered. The Project Manager, assisted by the assigned Site Safety officer, will ensure that all on-site subcontractor personnel, and site visitors, comply with the specified health and safety requirements. At least one copy of this EMP will be maintained at the local office of CES, as well as one copy will be maintained onsite by CES, and/or subcontracted personnel. 2 As part of CES’ safety program, a site-specific Job Hazard Analysis (JHA) form will be used, in conjunction with this plan, which will also include the name, address, and telephone number of the nearest hospital in relation to the project address where work is being completed. CES personnel have been instructed to utilize 911 as the first call should an accident, or issue, be apparent that warrants an immediate emergency response action. This plan is intended for general use during subsurface investigation activities completed by CES personnel, or CES subconsultants/subcontractors, and as a general reference for workers to review and understand the potential environmental and health and safety conditions that may be present under normal subsurface investigation conditions. Additionally, this plan should also be utilized for any work completed at surrounding properties where subsurface investigation activities are, or may be required. Prior to initiating subsurface investigation activities, as those referenced above, CES personnel (Project Manager(s), Site Safety Officer, and/or Field Crews) will complete Job Hazard Analysis (JHA) and selected CES safety forms which detail job specifics, including the sequence of basic job steps, potential incidents or hazards, and recommended procedures to eliminate potential incidents or hazards. 1.1 PURPOSE / OBJECTIVE The protection of workers and environmental safety and health are major concerns during this project and cannot be understated. The objective of the EMP is to document procedures and precautions to be implemented during any geophysical investigations and installation of soil borings with conversion to permanent monitoring wells, and site assessments, including soil and groundwater monitoring and/or remediation activities, in order to provide for and promote safe working conditions at the site during field activities, specifically at locations where contamination of soil and groundwater has been documented and/or is expected to be encountered. The safety organization and procedures have been established based on a previous analysis of potential hazards at the site. Personal protection measures have been selected in response to these potential hazards. This EMP and HASP has also been developed based upon review of the requirements described in the U.S. Environmental Protection Agency (USEPA) Standard Operating Safety Guide and the U.S. Department of Labor OSHA standards 29 CFR Part 1910. Reasonable precautions will be taken by the contractor’s representative and its subcontractors to provide for and promote the safety and health of workers and the general public. Subcontractors will 3 be given copies and will be required to follow this EMP. 1.2 RESPONSIBILITIES FOR HEALTH AND SAFETY All site activities which have the potential to expose personnel to site contamination or a related injury are subject to this EMP. Personnel will be responsible for adherence to the safety procedures during the performance of the work. In no case may work be performed in a manner that conflicts with the intent of, or the inherent safety and environmental cautions expressed in, these procedures. Following due warning(s), personnel who violate safety procedures will be dismissed from the site, and may be terminated. In the event that contamination is encountered during regular construction operations, personnel will be exclusively employed in the affected area of the project site, who have been properly trained in health and safety regulations associated with handling hazardous materials or special wastes as specified in the training section (Section 9.0) of this EMP. The requirements provided herein may be modified as the work progresses to accommodate changing conditions, but a reduction or increase in the health and safety requirements will not be made without prior approval by the assigned Site Safety Officer (SSO). The prevention of adverse health effects and injuries to site workers is totally dependent on the contribution of all project participants. Open communication among workers, supervisors, and management concerning safety at the site is an essential element of this EMP. 1.3 SUBCONTRACTOR’S RESPONSIBILITY The Subcontractor is solely responsible for the health, safety, and protection of their own on- site personnel during the performance of the survey services work scope. The Subcontractor will perform the work specified in the contract documents in accordance with the HEALTH AND SAFETY REQUIREMENTS specified herein, and federal, OSHA, state, and local health and safety regulations. It will be the responsibility of the Subcontractor to be familiar with the required health and safety regulations in the performance of this work. The Subcontractor will designate a Site Safety officer to implement and monitor activities related to this EMP. Should any unforeseen or site-specific safety-related factor, hazard, or condition become evident during the performance of the work, the Subcontractor will take immediate and prudent action to establish and maintain safe working conditions and to safeguard site personnel, the public, and the environment. 4 2.0 ASSIGNMENT OF RESPONSIBILITY All site activities which have the potential to expose CES personnel to site contamination or related injury are subject to this EMP. As previously discussed, all site personnel are responsible for adherence to the safety procedures during performance of the work. Specific oversight responsibilities are assigned to various personnel as discussed in the paragraphs to follow. 2.1 SITE SAFETY OFFICER The SSO will be assigned to monitor the daily activities to assure that all health and safety procedures/policies are being followed by CES personnel. This includes communicating the specific requirements to all personnel, including subcontractors, implementing the EMP, conducting site inspections to monitor compliance with EMP as required, providing or coordinating training as required, coordinating the medical monitoring program, coordinating respirator fit tests as required, coordinating the acquisition, calibration and maintenance of air monitoring equipment, respirators and other safety equipment, directing on-site health and safety activities, and reporting safety related incidents or accidents to the Project Manager. The SSO for CES is: Greg Hans, PMP CES Group Engineers, LLP 3525 Whitehall Park Drive, Suite 150 Charlotte, NC 28273 704.325.5408 (direct) 617.828.9948 (mobile) It should be noted that the SSO may and will delegate responsibilities to a representative of CES, subconsultants and/or subcontractors working at the Site and offsite properties for any and all tasks associated with additional subsurface investigation activities. 2.2 PROJECT MANAGER(S) The project manager is ultimately responsible for ensuring that all project participants abide by the requirements set forth in this plan. Any and all changes in the scope of health and safety requirements or site characterization will be communicated from the Project Manager and/or Environmental Scientist/Engineer to the SSO. 5 Environmental Project Manager: Greg Hans, PMP CES Group Engineers, LLP 3525 Whitehall Park Drive, Suite 150 Charlotte, NC 28273 704.325.5408 (direct) 617.828.9948 (mobile) Environmental Engineer: Chuck Heleine, PE CES Group Engineers, LLP 3525 Whitehall Park Drive, Suite 150 Charlotte, NC 28273 704.308.7916 (mobile) 3.0 BACKGROUND AND HAZARD EVALUATION 3.1 PROJECT DESCRIPTION This project involves monitoring of potentially contaminated groundwater with petroleum related constituents, and may also include geophysical investigations or utility clearance, and the installation of soil borings with conversion to permanent monitoring wells via mechanical drilling techniques, and potential future assessment, monitoring and remediation of soil and groundwater contaminants potentially encountered by said or existing borings. Future activities at the site may include, but are not limited to excavation and removal of encountered underground storage tanks (USTs), and contaminated soils / groundwater, and additional assessment and remediation activities, which may include hand-augering of soil borings, installation of permanent monitoring wells and/or remedial recovery wells, groundwater monitoring, and injections, and abandonment of monitoring wells. During the completion of the aforementioned activities, heavy equipment and machinery, such as drilling rigs, excavators, back-hoes, dump trucks, etc may be utilized and present onsite. 3.2 HAZARD EVALUATION Constant attention will be given to physical hazards encountered during work day activities, particularly those activities associated near heavy equipment such as drilling, subsurface excavations, and/or earthmoving equipment. An evaluation of the potential hazards associated with site activities has been completed by reviewing the general construction 6 scope of work for each of the projects, to be performed by others. The following potential exposure pathways have been identified: · Dermal contact, inhalation and ingestion of contaminated soils and groundwater · Inhalation and ingestion of contaminated vapors and particles · Ingestion of waste solids (accidental/poor hygiene) · Dermal contact with waste solids Given that subsurface investigation activities may occur in close proximity to ongoing or future construction (ie, excavations) related activities that may disturb surficial and subsurface soils, pipes, etc and the physical properties of the contaminants that may be present at these locations, there is a potential respiratory hazard from contaminants such as petroleum related compounds, and therefore a contact hazard from petroleum related compounds. A respiratory hazard from dust and contaminated dust particles may also exist during nearby drilling, excavation and removal activities. It is recognized that site hazard evaluation is a dynamic and on-going process that changes on a daily basis during progression of the work. However, significant deviation from the prescribed site characterization will necessitate re-evaluation and possible EMP revision. Communication from the SSO will initiate the re-evaluation process by the Project Manager. 3.3 SAFETY DATA SHEETS (SDS) Consistent with 29 CFS 1910.1200, (Hazard Communication Standard) applicable Safety Data Sheets (or equivalent) will be kept on-site, in each vehicle, and with the Project Manager. All subcontractors must ensure that their employees are informed of their rights and responsibilities under the OSHA Hazard Communication Standard. Subcontractors will provide SDS sheets for items which they bring on the site, as applicable. Due to the presence of petroleum related constituents, a SDS for Benzene (prepared by Marathon Petroleum Company, dated 5/14/2015), as VOC concentrations may be encountered onsite, has been included as Appendix A. It should be noted that the attached SDS is representative of potential chemicals and materials that may be encountered in the field during subsurface investigation activities. Should these, or any other chemicals or hazardous materials, actually be encountered by CES employees while in the field, the hazards and exposures of these chemicals or hazardous materials will be re-evaluated. 7 4.0 AIR MONITORING The purpose of air monitoring during subsurface investigation activities is to identify and quantify airborne contaminants to determine the level of protection needed. Should air monitoring for airborne contaminants be necessary, air monitoring with direct reading instruments will be conducted during all intrusive activities. Four categories of air monitoring will be conducted as follows: · Breathing Zone Monitoring · Explosive Gas Source Monitoring · Work Area Monitoring · Dust Monitoring Equipment to be used in conducting air monitoring activities, along with a description of the type and frequency of monitoring and associated action levels are discussed in the paragraphs to follow. It should be noted that the contractors working in active construction zones, including but not limited to excavations, trenches, bore holes, etc should be responsible for proper air monitoring of these areas. However, should CES feel the need to perform additional air monitoring, the following procedures (as outlined in sections 4.0 through 6.0, and to an extent, sections 7.0 through 11.0) may be implemented. 4.1 MONITORING EQUIPMENT If CES employees are working in, or near, active construction zones where the potential exists for chemical hazards and exposures to be present, the breathing zones will be monitored using a MiniRAE portable VOC monitor. These instruments use a photoionization detector that is designed to measure trace quantities of VOCs with a parts-per-million (ppm) sensitivity range. It does not detect methane. The survey instrument will be calibrated using an appropriate standard according to manufacturer’s instructions. The VOC monitor will be calibrated prior to each use if the instrument is used infrequently, or daily when in constant use. If the MiniRAE portable VOC monitor detects elevated levels of VOC concentrations (> 50 ppmv), in ambient air at the site, a Gastech 02 /explosion/H2S meter will be used to measure oxygen concentrations, explosion potential, and hydrogen sulfide (H2S) concentration. The instrument will be calibrated with methane and H2S according to the manufacturer’s instructions. 8 Air monitoring equipment will be certified intrinsically safe and operated by personnel trained in the use of the specific equipment provided. 4.2 TYPES AND FREQUENCY OF MONITORING 4.2.1 Breathing Zone Monitoring The breathing zone of a representative employee suspected of greatest exposure for each job category engaged in work with potentially hazardous substances will be monitored as follows: · For excavation operations, monitor the breathing zone of the equipment operator and laborers with an OVM when the waste material is initially exposed. The results of the monitoring, the employee’s name, and the work activity will be recorded in the daily log 4.2.2 Explosive Gas Source Monitoring During all operations identified as having a fire/explosion hazard, a combustible gas meter set to measure the lower explosive level (LEL) will be used to continuously monitor the top of the trench or excavation. 4.2.3 Work Area Monitoring Each work area associated with hazardous waste spills and/or contamination will be monitored at least one time each day with an OVM to determine the concentration of contaminants being released into the general area. 4.2.4 Dust Monitoring Chemical exposure via inhalation will be mitigated through the evaluation of wind velocity, and common sense. Personal protective equipment will be utilized as necessary (based on specific action levels) to prevent chemical exposure in excess of the exposure limits. When possible, personnel should be situated upwind of work activity when working at the site. Excavated areas should be allowed to vent for one to two minutes prior to investigative activities to allow any vapors, dusts, or gases to dissipate. Liquids and solids should never be smelled to confirm the presence or absence of chemicals. 9 The SSO or CES representative will screen the site for dusty conditions to prevent inhalation of chemicals in particulate form (e.g. residue on soil grains). If dusty conditions are observed, all workers will wear appropriate respiratory protection designed for dusts. Extremely dusty conditions may require dust suppression via water mist or spray prior to returning to work. 4.3 ACTION LEVELS The action levels as prescribed by the National Institute for Occupational Safety and Health (NIOSH) will be used to initiate protective actions including, but not limited to, use of personal protective devices, shut down of specific work activities, and site evacuation. A current volume of the NIOSH Pocket Guide (electronic version) to Chemical hazards will, or may be utilized as an on-site referenced by the SSO. 5.0 PERSONAL PROTECTIVE EQUIPMENT AND PROCEDURES 5.1 RESPIRATORY PROTECTION During excavation or construction activities in an area where special wastes are expected or have been encountered, the use of respiratory protection equipment may be required. Respiratory protection is of primary importance as inhalation is one of the major routes of exposure to chemical toxicants. Respiratory protective devices include air purifying respirators, air-line respirators, and self-contained breathing apparatus. The following respiratory protection practices will be observed by all workers at the Site when conditions warrant respiratory protection: · The respiratory protection utilized on-site will be in accordance with OSHA, 29 CFR 1910.134 · Only properly cleaned, maintained, NIOSH/MSHA-approved, respirators will be used on-site (if required) · Selection of respirators, as well as any decisions regarding upgrading or downgrading of respiratory protection, will be made by the SSO 10 · Air-purifying cartridges will be replaced on a regular basis (at least once per day) as determined by the SSO · No employee will be assigned to tasks requiring the use of respirators if, based upon the most recent examination, a physician determines that the employee will be unable to function normally wearing a respirator or that the safety or health of the employee or other employees will be compromised by use of a respirator · Persons required to wear full-face respirators must not have beards or moustaches that interfere with proper respirator seal. All personnel wearing full-face respirators or personnel working in the exclusion zone will be required to be clean-shaven prior to each day’s shift. This will be strictly enforced by the SSO · All personnel required to use APRs must be properly fit tested prior to engaging in field activities in accordance with OSHA standards (29 CFR 1910.1025) 5.2 PROTECTIVE CLOTHING To protect workers against dermal contact with contaminants, the following apparel must be worn during site-specific work activities depending on the level of protection specified for those activities (Section 5.3 of this EMP): · Disposable Tyvek coveralls · PVC-coated or equivalent coveralls for splash protection · Nitrile gloves or equivalent · Inner gloves - latex or vinyl · Outer disposable boots · Hard hat · Chemical-resistant boots (Neoprene, PVC, or equivalent) · Hearing protection (as applicable) · Steel-toed safety shoes 11 · Goggles or safety glasses will be worn at all times in the work area · Sleeves taped to gloves and cuffs taped to boots · Face shield attachments for use with hard hats · Disposable, chemical-resistant outer boots Upgrading or downgrading selected protective equipment will be the decision of the SSO based on assessment of exposure potential during specific tasks. 5.3 LEVELS OF PROTECTION The levels of protection to be utilized at the site, and the activities to which they apply, are described in the following paragraphs. The SSO will select the appropriate level of PPE based on air monitoring results. 5.3.1 Modified Level D This is the minimum level of protective clothing to be worn at the site during subsurface investigation activities. All workers, supervisors, and visitors will be required to don the following clothing prior to entering the project site. Based on the anticipated activities to be performed at the site, it is anticipated that Modified Level D will provide adequate protection coverage. · Work clothes · Hard hat · Safety shoes · Visibility vest · Work gloves (only as necessary) 5.3.2 Level D Protection Level D protection includes chemical resistant gloves and will be used for site work whenever contact with contaminated equipment or materials is possible. The following clothing will be required for Level D: · Disposable, chemical-resistant outer boots · Coveralls (work uniform) · Hard hat · Eye protection (safety glasses, goggles, or face-shield)* · Safety shoes · Nitrile gloves* 12 * Optional, as determined by SSO Dust masks shall be used to reduce employee exposure to fugitive dust, an optional Level D device. The absence of dusty conditions at the site will be justification for the SSO to permit personnel to remove their masks. 5.3.3 Level C Protection Level C will be used for site work when the inhalation and dermal contact hazard is elevated. When conditions for Level C protection are appropriate, the following equipment will be required: · Tyvek coveralls/chemical-resistant protective coverall · Gloves (inner latex gloves and outer nitrile gloves) · Hard hat · Safety shoes · Full-face or half-face air purifying respirator with organic vapor cartridge (or other proper type cartridge for the intended use, as determined by the SSO) · Chemical-resistant outer boots · Tape gloves and boots to coveralls to prevent leakage · Hearing protection (as determined by SSO) 5.3.4 Level B Protection Level B will be used for site work when inhalation and dermal contact hazard are elevated to the point that a positive pressure, supplied air source is needed. · Saranex coveralls/chemical-resistant clothing · Gloves (inner latex gloves and outer nitrile gloves) · Hard hat · Self-contained breathing apparatus (SCBA), or Supplied Air- Line Respirator (SAR) · Chemical-resistant safety boots · Gloves and boots taped to prevent leakage 13 6.0 SITE CONTROL The purpose of site control is to minimize potential contamination of workers and to protect the surrounding area from hazards found at the site. If the project site is not secured by fencing or other suitable site control means and is not routinely patrolled by police or other independent security personnel; certain procedures must be followed to ensure suitable site control and limitation of access so that those persons who may be unaware of site conditions are not exposed to hazards. All excavations left open and unattended by site personnel will be appropriately barricaded and visibly posted with “No Trespassing” or other appropriate signage. All heavy machinery and equipment shall be locked or chained each evening upon completion of daily activities. All potentially contaminated media, such as soil, will be covered with plastic prior to leaving the site. 6.1 REGULATED AREAS As appropriate to the task conducted, the site vicinity will be divided into three zones to allow control of worker exposures. These zones are described as follows: · Exclusion Zone. This zone includes the actual area of contamination and localized work area where specific investigative and/or construction equipment is operating. This zone has the highest inhalation exposure potential, and/or presents a high probability of skin contact with cutaneous percutaneous - affecting chemicals. New exclusion zones may exist during certain site-specific activities. This will be defined by the SSO and access by individuals not necessary to operation will be limited. (Level D is minimum). · Contamination Reduction Zone. This zone includes the areas immediately surrounding the Exclusion Zone. All personnel and equipment leaving the Exclusion Zone shall be decontaminated in this zone. 14 Support Zone. This zone covers all areas outside of the Contamination Reduction Zone. Administrative activities are conducted in the Support zone, as well as equipment supply and first aid supply. It is essential that contamination be kept out of this zone. 6.2 ACCESS/SITE SECURITY Access to contaminated work areas (Exclusion and Contamination Reduction Zones) will be regulated and limited to authorized persons. Such persons include the Contractor’s employees, designated equipment operators, and designated union representatives, as applicable. The SSO will enforce access limitations during work hours. 6.3 POSTING/BARRICADES Warning signs will be posted and hung, as applicable, in readily visible locations in or near contaminated work areas. Barricades or barricade tape will be utilized to prevent access to various work areas as indicated above. 7.0 POLICIES 7.1 GENERAL WORK PRACTICES General work practices to be employed on-site are as follows: · At least one copy of this EMP will be available at the work site · No food or beverages will be present or consumed in the exclusion or contamination reduction zones. No tobacco products will be present or used, and cosmetics will not be applied in the exclusion or contamination reduction zones · No matches or lighters are permitted in the exclusion or contamination reduction zones · During operations within an area of contamination, all employees will be required to wash their hands and face before eating, drinking, smoking, or applying cosmetics 15 · Field personnel must observe each other for signs of exposure. Indications of adverse effects include, but are not limited to, the following: - Changes in complexion and skin discoloration - Changes in coordination - Changes in demeanor - Excessive salivation and pupillary response - Changes in speech pattern Field personnel will be cautioned to inform the SSO of non- visible effects of exposure such as the following: - Headaches - Dizziness - Nausea - Blurred vision - Cramps - Irritation of eyes, skin, or respiratory tract · 7.2 HEAVY EQUIPMENT OPERATION Extra attention should be paid to the following information regarding work around heavy equipment (cranes, excavators, front end/backhoe loaders, drilling rigs, etc.). · Use common sense · Follow OSHA requirements found in 29 CFR 1910 and 29 CFR 1926 · Wear hard hats, hearing protection, and safety glasses at all times (when not prohibited by the use of air purifying respirators). Wear other protective gear as specified in the Health and Safety Plan 16 · A closed cab or cage will be required for equipment used at the site · Pay attention at all times · Maintain visual contact at all times · Establish hand signal communication when verbal communication is difficult. Select one person per work group to be the one to give hand signals to equipment operators · Be aware of footing at all times · Be sure that all heavy equipment has a backup alarm · Be sure that only qualified people operate heavy equipment · Use chains, hoists, straps, and other equipment to safely move heavy materials · Use proper personal lifting techniques. (Use your legs, not your back) · Never walk directly in back of, or to the side of, heavy equipment without the operator’s knowledge · Never use a piece of equipment unless you are familiar with its operation. This applies to heavy as well as light equipment (for example, chain saws) · Make sure all precautions have been taken before moving pipe sections and other materials to be utilized during this project as they are extremely heavy. Let the equipment, not your body, do the moving 17 · Be sure that no underground or overhead power lines, sewer lines, gas lines, or telephone lines will present a hazard in the work area 7.3 SANITATION Onsite sanitation facilities (e.g., wash stations, etc.) may be provided for use by field personnel assigned to the work if work activities involve the direct handling of contaminated soils and groundwater. 8.0 DECONTAMINATION The process of removing or neutralizing contaminants that have accumulated on personnel and equipment is critical to personnel protection. Decontamination protects workers from hazardous substances that may contaminate and eventually permeate the protective clothing, respiratory equipment, tools, vehicles, and other equipment used on site. Decontamination protects site personnel in the following ways: minimizing the transfer of harmful materials into clean areas; preventing the mixing of incompatible chemicals; and protecting the community by preventing uncontrolled transportation of contaminants from the site. General – Each time an employee enters the Contamination Reduction Zone from the Exclusion Zone, he/she just make a thorough self-examination. Equipment must be removed without exposure to the wearer. Hands and face must be scrubbed before eating or use of tobacco or cosmetic products to avoid accidental ingestion of wastes. Footwear must be changed prior to leaving the Contamination Reduction Zone to avoid “tracking” of contaminants outside the area. Clothing – The Contractor will provide all required protective clothing. Protective clothes will be left in the change facility. No clothing (including boots) is to be worn or carried away from the site. Soiled clothing is to be disposed of as appropriate. Respirators – All required respirators will be provided and maintained by the Contractor and will be cleaned daily. Cleaning and maintenance will be performed in accordance with the appropriate OSHA standard (29 CFR 1910.134). 18 Packaging of Waste Items – All disposable clothing and other contaminated material will be placed in containers for storage on-site. Personnel will make a conscious effort to minimize the volume of contaminated materials. Legible and understandable precautionary labels will be affixed prominently to containers of contaminated scrap, waste, debris, and clothing. Containers will be disposed with other solids in an EPA-approved manner. 8.1 PERSONAL DECONTAMINATION Minimum measures to be undertaken for decontamination are outlined below. These measures are to be followed, as applicable, unless the SSO specifies that a higher level of decontamination is warranted, and accordingly, sets forth upgraded decontamination procedures. MINIMUM MEASURES FOR DECONTAMINATION STATION PROCEDURES 1. Equipment Drop 1. Deposit equipment used on site (tools, sampling devices and containers, monitoring instruments, radios, clipboards, etc.) on plastic drop cloths or in different containers with plastic liners. During hot weather operations, a cool down station may be set up within this area. 2. Outer Garment, Boots and Gloves Wash and Rinse 2. Scrub outer boots, outer gloves and fully encapsulating suit with decon solution or detergent and water. Rinse off using copious amounts of water. 3. Outer Boot and Glove Removal 3. Remove outer boots and gloves. Deposit in container with plastic liner. 4. Tank Change 4. If worker leaves Exclusion Zone to change air tanks, this is the last step in the decontamination procedure. Worker’s air tank is exchanged, new outer gloves and boot covers donned, joints taped, and worker returns to duty. 5. Boot, Gloves and Outer Garment Removal 5. Boots, fully-encapsulated suit, inner gloves removed and deposited in separate containers lined with plastic. 6. SCBA Removal 6. SCBA backpack and facepiece is removed (avoid touching face with fingers). SCBA deposited on plastic sheets. 7. Field Wash 7. Hands and face are thoroughly washed. Shower as soon as possible. 19 EQUIPMENT NEEDED TO PERFORM MINIMUM DECONTAMINATION MEASURES STATION EQUIPMENT 1 A. Various Size Containers B. Plastic Liners C. Plastic Drop Cloths 2 A. Container (20-30 Gallons) B. Decon. Solution or Detergent Water C. Rinse Water D. 2-3 Long-Handled, Soft Bristled Scrub Brushes 3 A. Container (20-30 Gallons) B. Plastic Liners C. Bench or Stools 4 A. Air Tanks or Masks and Cartridges, depending Upon Level. B. Tape C. Boot Covers D. Gloves 5 A. Containers (20-30 Gallons) B. Plastic Liners C. Bench or Stools 6 A. Plastic Sheets B. Basin or Bucket C. Soap and Towels D. Bench or Stools 8.2 EQUIPMENT DECONTAMINATION Any items taken into the Exclusion Zone will be assumed to be contaminated. In general, vehicles, equipment, and materials brought into the Exclusion Zone will remain in the Exclusion Zone until no longer necessary to the project. 20 All contaminated vehicles and equipment will be decontaminated before they are taken off- site. The Contractor will provide and maintain the following facilities for equipment decontamination: - equipment decontamination pad - contaminated water collection system - high-pressure water or steam cleaners - trisodium phosphate detergent - wire brushes and scrapers 9.0 TRAINING 9.1 BASIC TRAINING All employees who will perform work at the site must have completed environmental and safety training as approved and/or provided by CES, the Owner, the Contractor, or if required, by 3rd party General Contractor. 9.2 SITE-SPECIFIC TRAINING Employees assigned to the site may, as needed, be given site-specific training and field experience to include the following topics: - Acute and chronic effects of the toxic chemicals found at the site - Routes of potential exposure and field activities which could result in such exposure - Need for personal protection, types of protection, fit effectiveness and limitations - Medical surveillance program - Work zones established at the site - Prohibited activities in the Exclusion and Contamination Reduction Zones - Engineering controls and safe work practices associated with each employee’s work assignment, including dust control measures - Personal and equipment decontamination procedures - Emergency response procedures - Basic operational safety, emphasizing hazards expected on-site - Drum handling procedures - Spill control - Sampling procedures - Site communication procedures 21 - 10.0 HEALTH MONITORING 10.1 PHYSICAL EXAMINATION The Contractor may require all of its field workers to pass a pre-employment medical examination prior to working at the site. The examination shall include a complete medical and occupational history, and an evaluation from the attending physician as to whether the employee is qualified to work in areas where exposure to chemicals or physical stress is possible, and is physically able to use protective equipment, including respirators. 10.2 HEAT STRESS Subsurface investigation tasks, assignments, projects etc will, or may be conducted during all four season, winter, spring, summer and fall. Accordingly, warm temperatures during these time periods may put extra physical stress on the body. Long periods of exposure to heat may cause illness, particularly if the employee is not accustomed to working in hot areas. Also, heat builds up inside protective clothing, so there is a risk of heat stress even if outside temperatures are moderate. The signs, symptoms and treatment of heat stress are outlined below. All individuals participating in work in the Exclusion Zone and Contamination Reduction Zones should be monitored regularly for heat stress symptoms. Heat Cramps Symptoms: painful muscle spasms Cause: profuse sweating and drinking large amounts of water Treatment: provide liquids with electrolytes (sodium, potassium) like diluted Gatorade 22 Heat Exhaustion Symptoms: weakness, fatigue, dizziness; pale, cool, moist skin; heavy sweating; Headache; nausea; and fainting Cause: reduced blood volume resulting from dehydration from profuse sweating and insufficient replacement of water and salts Treatment: If worker is conscious, rest in cool place; replace water and electrolytes lost in sweat; if unconscious, get medical help immediately. DO NOT give liquids if person is unconscious Heat Stroke Symptoms: very dry, hot skin with red mottled or bluish appearance; confusion; Convulsions; unconsciousness; rapidly rising temperature Cause: body becomes overheated because the worker does not sweat. Can be fatal. Treatment: call for medical help immediately; move person to cool place; remove PPE; use wet towels or water and fan to cool while waiting for help. 10.4 COLD STRESS Subsurface investigation tasks, assignments, projects etc will, or may be conducted during all four season, winter, spring, summer and fall. Accordingly, cold temperatures during these time periods may put extra physical stress on the body. Long periods of exposure to cold may cause illness, particularly if the employee is not accustomed to working in cold areas. Cold stress occurs by driving down the body’s skin temperature and eventually the body temperature (core temperature). The signs, symptoms and treatment of cold stress are outlined below. All individuals participating in work in the Exclusion Zone and Contamination Reduction Zones should be monitored regularly for cold stress symptoms. 23 Hypothermia: Symptoms: shivering, reduced circulation, slow/weak pulse, slowed breathing, lack of coordination, irritability, confusion, sleepy behavior Cause: body heat is lost faster than it can be replaced and normal body temperature drops below 95 degrees F Treatment: move person to warm and dry area, remove wet clothes and replace with dry clothes, layer with blankets, give warm sweetened liquids, if unconscious, get medical help immediately. DO NOT give liquids if person is unconscious Frostbite Symptoms: reddened skin, with development of gray/white patches, numbness, firm or hard parts affected, blisters Cause: freezing of skin and underlying tissues typically affecting extremities, particularly the feet and hands Treatment: move person to warm and dry area, remove wet clothes and replace with dry clothes, layer with blankets, give warm sweetened liquids, if unconscious, get medical help immediately. DO NOT give liquids if person is unconscious. DO NOT rub affected area, DO NOT break blisters, DO NOT try to directly warm the frostbite areas without medical attention Trench Foot Symptoms: redness of skin, swelling, numbness, blisters Cause: prolonged exposure to wet and cold temperatures, constantly wet and cold feet, wet and cold feet lose heat 25x faster than dry feet Treatment: call for medical help immediately; remove the shoes, boots, wet socks, dry the feet 24 10.5 SELF MONITORING While at the site, CES employees and sub-contractors will be required to monitor their own health and that of their co-workers. Visual observations include: - behavioral changes - change in appetite - coordination losses - gum and lip discoloration - increased salivation - pupil dilation - sensation losses - skin rashes - slurred speech Any abnormalities or changes are to be reported to the physician and investigated immediately. Such aspects could be symptoms of toxic exposure and must not be allowed to persist without medical attention. In addition, all accidents and injuries, no matter how small, are to be reported to the SSO and investigated. 11.0 SITE STANDARD OPERATING PROCEDURES 11.1 WORK PRACTICES The need to exercise caution in the performance of specific work tasks is made more acute due to weather conditions, restricted mobility, and reduced peripheral vision caused by the protective gear itself, the need to maintain the integrity of the protective gear, and the increased difficulty in communicating caused by respirators. Work at the site will be conducted according to established procedures and guidelines for the safety and health of all involved. Among the most important of these principles for working at the site are: - In any unknown situation, always assume the worst conditions and plan accordingly - Establish and maintain communication 25 - Minimize contact with excavated or contaminated materials. Plan work work areas, decontamination areas, and procedures to accomplish this. Do not place equipment on drums or on the ground. Do not sit or stand on drums or other materials - Employ disposable items when possible to minimize risks during decontamination and possible cross-contamination during sampling/handling. This will require a common-sense approach to potential risks and costs - Smoking, eating, or drinking after entering the work zone and before decontamination will not be allowed. Oral ingestion of contaminants from your hands are a likely means of introduction of the toxic substances into the body - Avoid heat and other work stresses relating to wearing the protective gear. Work breaks and proper tracking are planned to prevent stress-related accidents or fatigue - Maintain monitoring systems. Conditions can change quickly if sub-surface areas of contamination are penetrated - Be observant of not only your own immediate surroundings but also that of others. It is a team effort to notice and warn of impending dangerous situations. Extra precautions are necessary when working near heavy equipment while utilizing personal protective gear, as vision, hearing, and communication may be restricted by the protective gear - Be aware that chemical contaminants may aggravate or worsen symptoms of other illnesses or intoxication. Avoid use of alcohol and working when ill 11.2 COMMUNICATION PROCEDURES Personnel in the Exclusion Zone shall remain within sight of other project personnel, and should work in conjunction with another individual. Since it is not anticipated that the project area will encompass a large area at any given time, radio communication will not be required. 26 The following standard hand signals will be used in the event that communication is required amongst workers in and/or between the Exclusion Zone and Contamination Reduction Zone. Hand gripping throat Out of air, cannot breathe Grip partner’s wrist, or both Leave area immediately Hands around partner’s waist Rotating hands above the head Need assistance Right hand thumb up OK, I’m all right, I understand Right hand thumb down No, negative 12.0 EMERGENCY PROCEDURES 12.1 GENERAL A comprehensive emergency response plan has been developed to handle all on-site emergencies. A list of site conditions which might require implementation of the plan includes but is not limited to: - Fire or explosion on-site - Serious employee injury - Accumulation of combustible gases or vapors at concentrations greater than background - Oxygen concentration below 19.5% - Unsafe working conditions, such as inclement weather or hazardous material releases - Major release of toxic materials for which appropriate PPE is not being worn by workers 27 12.2 RESPONSIBILITIES The emergency coordinator is the SSO (Greg Hans) or assigned CES representative working onsite; the alternate or back-up is the Environmental Engineer (Chuck Heleine). The emergency coordinator is responsible for: - Assessing the situation and determining whether an emergency exists which requires activating the plan - Directing all efforts in the area, including evacuating personnel and minimizing property loss - Ensuring that outside emergency services such as fire departments, police, ambulance, and hospitals are notified when necessary - Directing the shut-down of site operations when necessary - Notifying regulatory agencies as necessary 28 12.3 EMERGENCY CONTACT LIST Emergency Contact Phone Number Environmental PM: Greg Hans, PMP 617.828.9948 (M) CES Group Engineers, LLP 704.325.5408 (D) Other SSO (if assigned by by Env PM) Carolina Soil Investigations (Drillers) 704.539.5279 (assigned CSI field crew chief) Back-up PM Chuck Heleine 704.308.7916 (M) CES Group Engineers, LLP Police: North Carolina Highway Patrol 911 Claremont Police Department 828.466.7265 Hospital: Catawba Valley Medical Center 828.326.3000 3169 12th Avenue, SE Hickory, NC 28602 Fire: Claremont Fire Department 828.459.9296 Doctor: Catawba Valley Medical Center 828.326.3000 Ambulance 911 NCDENR (Mooresville Region) 704.663.1699 Directions to the nearest hospital: Catawba Valley Medical Center, 3169 12th Avenue, SE, Hickory, NC 28602 Refer to Appendix C. 29 12.4 PERSONNEL INJURY IN THE EXCLUSION ZONE When there is an injury in the Exclusion Zone, a continuous horn blast will be sounded as an emergency signal (as applicable). Upon the sounding of the emergency signal, all site personnel shall assemble in the personnel decontamination area. Rescue personnel will enter the Exclusion Zone (if required) to remove the injured person. The SSO, or CES representative, will evaluate the nature of the injury and call for an ambulance (if needed), and the affected person will be decontaminated to the extent possible prior to movement to the Support Zone. The appropriate first aid will be administered. No persons shall re-enter the Exclusion Zone until the cause of the injury or symptom is determined. 12.5 PERSONAL INJURY IN THE SUPPORT ZONE Upon notification of an injury in the Support Zone, the SSO, or CES representative, will assess the nature of the injury. If the injury or absence of the injured person does not affect the performance of site personnel, operations may continue while appropriate first aid and follow-up is initiated. If the injury increases the risk to others, the designated emergency signal (continuous horn blast) shall be sounded, and all site personnel shall move to the decontamination line for further instructions. Activities on-site will stop until the added risk is removed or minimized. 12.6 FIRE OR EXPLOSION Upon notification of a fire or explosion on-site, a continuous horn blast will be sounded, and all site personnel will assemble at the decontamination area. The fire department must be alerted and all personnel moved as soon as possible to a safe distance. 12.7 PERSONAL PROTECTIVE EQUIPMENT FAILURE If any site worker experiences a failure or alteration of protective equipment which may alter the protection factor, that person and his/her work partner must immediately leave the Exclusion Zone. Re-entry shall not be permitted until the equipment has been appropriately repaired or replaced. 12.8 POLLUTANT DISCHARGES/SPILLS In the event of an unauthorized discharge of pollutants or contaminants into the soil, sewers, or ambient air, the person first finding such an incident should immediately notify the Project Manager and/or the SSO. The Project Manager and/or SSO will immediately notify Greg Hans or Chuck Heleine and the Local Fire / Emergency Management agency (Catawba County Emergency Management at 828.465.8230). APPENDIX A SAFETY DATA SHEETS (BENZENE) SAFETY DATA SHEET SDS ID NO.:0156MAR019 Revision Date 05/14/2015 1. IDENTIFICATION Product Name:Marathon Petroleum Benzene Synonym:Benzene; Cyclohexatriene Product Code:0156MAR019 Chemical Family:Petroleum Hydrocarbon Recommended Use:Solvent. Chemical intermediate. Restrictions on Use:All others. SDS information:1-419-421-3070 Emergency Telephone:1-877-627-5463 2. HAZARD IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Specific target organ toxicity (repeated exposure)Category 1 Aspiration toxicity Category 1 Acute aquatic toxicity Category 2 Hazards Not Otherwise Classified (HNOC) Static accumulating flammable liquid Label elements EMERGENCY OVERVIEW Manufacturer, Importer, or Responsible Party Name and Address: MARATHON PETROLEUM COMPANY LP 539 South Main Street Findlay, OH 45840 Flammable liquids Category 2 Danger HIGHLY FLAMMABLE LIQUID AND VAPOR May accumulate electrostatic charge and ignite or explode SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 1 of 10 May be fatal if swallowed and enters airways Causes skin irritation _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools. Take precautionary measures against static discharge Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product Wash hands and any possibly exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid release to the environment Precautionary Statements - Response IF exposed or concerned: Get medical attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical attention IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower If skin irritation occurs: Get medical attention Wash contaminated clothing before reuse IF SWALLOWED: Immediately call a POISON CENTER or doctor Do NOT induce vomiting In case of fire: Use water spray, fog or regular foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Store locked up Precautionary Statements - Disposal Dispose of contents/container at an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Benzene is a six carbon aromatic petroleum hydrocarbon. Composition Information: Name CAS Number % Concentration Benzene 71-43-2 99-100 All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume. Causes serious eye irritation May cause genetic defects May cause cancer Causes damage to organs (blood, blood-forming organs, immune system) through prolonged or repeated exposure Toxic to aquatic life Appearance Clear Liquid Physical State Liquid Odor Sweet , Distinct SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 2 of 10 _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 4. FIRST AID MEASURES First Aid Measures General Advice:In case of accident or if you feel unwell, seek medical advice immediately (show directions for use or safety data sheet if possible). Inhalation:Remove to fresh air. If not breathing, institute rescue breathing. If breathing is difficult, ensure airway is clear, give oxygen and continue to monitor. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION. Skin Contact:Immediately wash exposed skin with plenty of soap and water while removing contaminated clothing and shoes. May be absorbed through the skin in harmful amounts. Get medical attention if irritation persists. Place contaminated clothing in closed container until cleaned or discarded. If clothing is to be laundered, inform the person performing the operation of contaminant's hazardous properties. Destroy contaminated, non-chemical resistant footwear. Eye Contact:Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Gently remove contacts while flushing. Get medical attention if irritation persists. Ingestion:Do not induce vomiting because of danger of aspirating liquid into lungs, causing serious damage and chemical pneumonitis. If spontaneous vomiting occurs, keep head below hips, or if patient is lying down, turn body and head to side to prevent aspiration and monitor for breathing difficulty. Never give anything by mouth to an unconscious person. Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION. Most important signs and symptoms, both short-term and delayed with overexposure Adverse Effects:Overexposure to vapors may cause eye, skin and respiratory irritation. Headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue. Prolonged and repeated contact may cause defatting and drying of the skin and may lead to irritation and/or dermatitis. Prolonged or repeated exposure may cause adverse effects on blood, blood-forming organs, and immune system. Indication of any immediate medical attention and special treatment needed Notes To Physician:INHALATION: This material (or a component) sensitizes the myocardium to the effects of sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in individuals exposed to this material. Administration of sympathomimetic drugs should be avoided. INGESTION: This material represents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media For small fires, Class B fire extinguishing media such as CO2, dry chemical, foam (AFFF/ATC) or water spray can be used. For large fires, water spray, fog or foam (AFFF/ATC) can be used. Firefighting should be attempted only by those who are adequately trained and equipped with proper protective equipment. Unsuitable extinguishing media Do not use straight water streams to avoid spreading fire. SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 3 of 10 Specific hazards arising from the chemical This product has been determined to be a highly flammable liquid per the OSHA Hazard Communication Standard and should be handled accordingly. Vapors may travel along the ground or be moved by ventilation and ignited by many sources such as pilot _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 lights, sparks, electric motors, static discharge, or other ignition sources at locations distant from material handling. Flashback can occur along vapor trail. For additional fire related information, see NFPA 30 or the Emergency Response Guidebook 130. Hazardous combustion products Smoke, carbon monoxide, and other products of incomplete combustion. Explosion data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge Yes. Special protective equipment and precautions for firefighters Firefighters should wear full protective clothing and positive-pressure self-contained breathing apparatus (SCBA) with a full face-piece, as appropriate. Avoid using straight water streams. Water may be ineffective in extinguishing low flash point fires, but can be used to cool exposed surfaces. Avoid excessive water spray application. Water spray and foam (AFFF/ATC) must be applied carefully to avoid frothing and from as far a distance as possible. Keep run-off water out of sewers and water sources. Additional firefighting tactics FIRES INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after the fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles: if this is impossible, withdraw from area and let fire burn. EVACUATION: Consider initial downwind evacuation for at least 1000 feet. If tank, rail car or tank truck is involved in a fire, ISOLATE for 5280 feet (1 mile) in all directions; also, consider initial evacuation of 5280 feet (1 mile) in all directions. 6. ACCIDENTAL RELEASE MEASURES Personal precautions:Keep public away. Isolate and evacuate area. Shut off source if safe to do so. Eliminate all ignition sources. Protective equipment:Use personal protection measures as recommended in Section 8. Emergency procedures:Advise authorities and National Response Center (800-424-8802) if the product has entered a water course or sewer. Notify local health and pollution control agencies, if appropriate. Environmental precautions:Avoid release to the environment. Avoid subsoil penetration. Methods and materials for containment: Contain liquid with sand or soil. Methods and materials for cleaning up: Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual liquids. Recover and return free product to proper containers. When recovering free liquids ensure all equipment is grounded and bonded. Use only non-sparking tools. 7. HANDLING AND STORAGE Safe Handling Precautions:NEVER SIPHON THIS PRODUCT BY MOUTH. Static accumulating flammable liquid. Use appropriate grounding and bonding practices. Bonding and grounding may be insufficient to eliminate the hazard from static electricity. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. Use only non-sparking tools. Do not cut, drill, grind or weld on empty containers since explosive residues may remain. Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Use only with adequate ventilation. Use personal protection measures as recommended in Section 8. Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap and water. Comply with all applicable EPA, OSHA, NFPA and consistent state and local requirements. NFPA Health 2 Flammability 3 Instability 0 Special Hazard - SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 4 of 10 _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 Hydrocarbons are basically non-conductors of electricity and can become electrostatically charged during mixing, filtering, pumping at high flow rates or loading and transfer operations. If this charge reaches a sufficiently high level, sparks can form that may ignite the vapors of flammable liquids. Sudden release of hot organic chemical vapors or mists from process equipment operating under elevated temperature and pressure, or sudden ingress of air into vacuum equipment may result in ignition of vapors or mists without the presence of obvious ignition sources. Nozzle spouts must be kept in contact with the containers or tank during the entire filling operation. Storage Conditions:Store in properly closed containers that are appropriately labeled and in a cool, well-ventilated area. Incompatible Materials Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Name ACGIH TLV OSHA PELS:OSHA - Vacated PELs NIOSH IDLH Benzene 71-43-2 0.5 ppm TWA 2.5 ppm STEL Skin - potential significant contribution to overallexposure by the cutaneous route TWA: 10 ppm (applies to industry segments exempt from the benzene standard)TWA: 1 ppm STEL: 5 ppm (see 29 CFR 1910.1028) 25 ppm Ceiling 1 ppm TWA 5 ppm STEL 500 ppm Notes:The manufacturer has voluntarily elected to provide exposure limits contained in OSHA's 1989 air contaminants standard in its SDSs, even though certain of those exposure limits were vacated in 1992. Engineering measures:Local or general exhaust required in an enclosed area or when there is inadequate ventilation. Use mechanical ventilation equipment that is explosion-proof. Personal protective equipment Eye protection:Use goggles or face-shield if the potential for splashing exists. Skin and body protection:For non-exposure jobs or where exposure is expected to be less than 15 minutes, neoprene gloves can be used to prevent skin contact. For all exposure jobs expected to be greater than 15 minutes, Viton® gloves should be used to prevent skin contact. Glove suitability is based on workplace conditions and usage. Contact the glove manufacturer for specific advice on glove selection and breakthrough times. Depending upon the conditions of use and specific work situations, additional protective equipment and/or clothing may be required to control exposures. Respiratory protection:Approved organic vapor chemical cartridge or supplied air respirators should be worn for exposures to any components exceeding the established exposure limits. Observe respirator assigned protection factors (APFs) criteria cited in federal OSHA 29 CFR 1910.134. Self-contained breathing apparatus should be used for fire fighting. Hygiene measures:Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Clear Liquid Color Colorless Odor Sweet , Distinct Odor Threshold 12 ppmv Property Values (Method) SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 5 of 10 _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 Melting Point / Freezing Point 5.5 °C / 42 °F Initial Boiling Point / Boiling Range 80 °C / 176 °F Flash Point -11 °C / 12 °F Evaporation Rate 5.1 (Butyl acetate = 1) Flammability (solid, gas)Not applicable. Flammability Limit in Air (%): Upper Flammability Limit:7.1 Lower Flammability Limit:1.4 Explosion limits:No data available. Vapor Pressure 3.21 psia @ 100°F Vapor Density 2.7 (Air = 1) Specific Gravity / Relative Density 0.883 Water Solubility No data available. Solubility in other solvents No data available. Partition Coefficient No data available. Decomposition temperature No data available. pH:Not applicable. Autoignition Temperature 562 °C / 1044 °F Kinematic Viscosity 0.593 cSt @ 100°F Dynamic Viscosity No data available. Explosive Properties No data available. VOC Content (%)No data available. Density No data available. Bulk Density Not applicable. 10. STABILITY AND REACTIVITY Chemical stability The material is stable at 70°F (21°C ), 760 mmHg pressure. Possibility of hazardous reactions None under normal processing. Hazardous polymerization Will not occur. Conditions to avoid Sources of heat or ignition. Incompatible Materials Strong oxidizing agents. Hazardous decomposition products None known under normal conditions of use. 11. TOXICOLOGICAL INFORMATION Potential short-term adverse effects from overexposures Inhalation Overexposure may cause respiratory tract irritation and central nervous system depression. Breathing high concentrations of this material, for example, in a confined space or by intentional abuse, can cause irregular heartbeats which can cause death. Eye contact Irritating to eyes. Skin contact Irritating to skin. May be absorbed through the skin in harmful amounts. Effects may become more serious with repeated or prolonged contact. Ingestion May be fatal if swallowed or vomited and enters airways. May cause irritation of the mouth, throat and gastrointestinal tract. May cause central nervous system depression or effects. Acute toxicological data Name Oral LD50 Dermal LD50 Inhalation LC50 Benzene > 2000 mg/kg (Rat)> 5000 mg/kg (Rabbit)> 20 mg/l (Rat) 4 h Reactivity The product is non-reactive under normal conditions. SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 6 of 10 _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 71-43-2 Delayed and immediate effects as well as chronic effects from short and long-term exposure BENZENE: Studies of workers exposed to benzene show clear evidence that overexposure can cause cancer and other diseases of the blood forming organs including Acute Myelogenous Leukemia (AML), and Aplastic Anemia (AA), an often fatal disease. Some studies suggest overexposure to benzene may also be associated with Myelodysplastic Syndrome (MDS). Findings from a case control study of workers exposed to benzene was reported during the 2009 Benzene Symposium in Munich included an increase in Acute Myeloid Leukemias and Non-Hodgkins Lymphoid Neoplasms (NHLN) of the subtype follicular lymphoma (FL) in some occupational categories. Some studies of workers exposed to benzene have shown an association with increased rates of chromosome aberrations in circulating lymphocytes. One study of women workers exposed to benzene suggested a weak association with irregular menstruation. However, other studies of workers exposed to benzene have not demonstrated clear evidence of an effect on fertility or reproductive outcome in humans. Benzene can cross the placenta and affect the developing fetus. Cases of AA have been reported in the offspring of persons severely overexposed to benzene. Studies in laboratory animals indicate that prolonged, repeated exposure to high levels of benzene vapor can cause bone marrow suppression and cancer in multiple organ systems. Studies in laboratory animals show evidence of adverse effects on male reproductive organs following high levels of exposure but no significant effects on reproduction have been observed. Embryotoxicity has been reported in studies of laboratory animals but effects were limited to reduced fetal weight and minor skeletal variations. Benzene has been classified as a proven human carcinogen by OSHA and a Group 1 (Carcinogenic to Humans) material by IARC. The current proposed IARC classification for benzene is summarized as follows: Sufficient evidence for Acute Myeloid Leukemia; limited evidence for Acute Lymphatic Leukemia, Chronic Lymphatic Leukemia, Non-Hodgkin Lymphoma, and Multiple Myeloma. Adverse effects related to the physical, chemical and toxicological characteristics Signs and Symptoms Overexposure to vapors may cause eye, skin and respiratory irritation. Inhalation of high vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting Repeated or prolonged skin contact may cause drying, reddening, itching and cracking. Sensitization Not expected to be a skin or respiratory sensitizer. Mutagenic effects May cause genetic defects. Carcinogenicity Cancer designations are listed in the table below Name ACGIH (Class) IARC (Class) NTP OSHA Benzene 71-43-2 Confirmed human carcinogen (A1) Carcinogenic to humans (1)Known to be human carcinogen Known carcinogen Reproductive toxicity None known. Specific Target Organ Toxicity (STOT) - single exposure Not classified. Specific Target Organ Toxicity (STOT) - repeated exposure Blood. Blood-forming organs. Immune system. Aspiration hazard May be fatal if swallowed or vomited and enters airways. 12. ECOLOGICAL INFORMATION Ecotoxicity This product should be considered toxic to aquatic organisms. Name Algae/aquatic plants Fish Toxicity to Crustacea SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 7 of 10 _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 Microorganisms Benzene 71-43-2 72-hr EC50 = 29 mg/l Algae 96-hr LC50 = 5.3 mg/l Rainbow trout (flow-through) -48-hr EC50 = 8.76-15.6 mg/l Daphnia magna (Static) Persistence and degradability Readily biodegradable in the environment. Bioaccumulation Not expected to bioaccumulate in aquatic organisms. Mobility in soil May partition into air, soil and water. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Description of Waste Residues This material may be a flammable liquid waste. Safe Handling of Wastes Handle in accordance with applicable local, state, and federal regulations. Use personal protection measures as required. Use appropriate grounding and bonding practices. Use only non-sparking tools. Do not expose to heat, open flames, strong oxidizers or other sources of ignition. No smoking. Disposal of Wastes / Methods of Disposal The user is responsible for determining if any discarded material is a hazardous waste (40 CFR 262.11). Dispose of in accordance with federal, state and local regulations. Methods of Contaminated Packaging DisposalEmpty containers should be completely drained and then discarded or recycled, if possible. Do not cut, drill, grind or weld on empty containers since explosive residues may be present. Dispose of in accordance with federal, state and local regulations. 14. TRANSPORT INFORMATION DOT (49 CFR 172.101): UN Proper Shipping Name:Benzene UN/Identification No:UN 1114 Class:3 Packing Group:II TDG (Canada): UN Proper Shipping Name:Benzene UN/Identification No:UN 1114 Transport Hazard Class(es):3 Packing Group:II 15. REGULATORY INFORMATION US Federal Regulatory Information: US TSCA Chemical Inventory Section 8(b):This product and/or its components are listed on the TSCA Chemical Inventory. EPA Superfund Amendment & Reauthorization Act (SARA): SARA Section 302:This product does not contain any component(s) included on EPA's Extremely Hazardous Substance (EHS) List. Name CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs Benzene NA SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 8 of 10 _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 SARA Section 304:This product may contain component(s) identified either as an EHS or a CERCLA Hazardous substance which in case of a spill or release may be subject to SARA reporting requirements: Name Hazardous Substances RQs Benzene 10 SARA Section 311/312:The following EPA hazard categories apply to this product: Acute Health Hazard Chronic Health Hazard Fire Hazard SARA Section 313:This product may contain component(s), which if in exceedance of the de minimus threshold, may be subject to the reporting requirements of SARA Title III Section 313 Toxic Release Reporting (Form R). Name CERCLA/SARA 313 Emission reporting: Benzene 0.1 % de minimis concentration State and Community Right-To-Know Regulations: The following component(s) of this material are identified on the regulatory lists below: Benzene Louisiana Right-To-Know:Not Listed California Proposition 65:Carcinogen, initial date 2/27/87 Developmental toxicity, initial date 12/26/97 Male reproductive toxicity, initial date 12/26/97 New Jersey Right-To-Know:SN 0197 Pennsylvania Right-To-Know:Environmental hazard; Special hazardous substance Massachusetts Right-To Know:Carcinogen; Extraordinarily hazardous Florida Substance List:Not Listed Rhode Island Right-To-Know:Toxic (skin); Flammable (skin); Carcinogen (skin) Michigan Critical Materials Register List:100 lb Annual usage threshold Massachusetts Extraordinarily Hazardous Substances:Carcinogen; Extraordinarily hazardous California - Regulated Carcinogens:Not Listed Pennsylvania RTK - Special Hazardous Substances: Present New Jersey - Special Hazardous Substances:Carcinogen; Flammable - third degree; Mutagen New Jersey - Environmental Hazardous Substances List: SN 0197 TPQ: 500 lb Illinois - Toxic Air Contaminants:Present New York - Reporting of Releases Part 597 - List of Hazardous Substances: 10 lb RQ (air); 1 lb RQ (land/water) Canada DSL/NDSL Inventory:This product and/or its components are listed either on the Domestic Substances List (DSL) or are exempt. Canadian Regulatory Information:This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by those regulations. Name Canada - WHMIS: Classifications of Substances: Canada - WHMIS: Ingredient Disclosure: Benzene B2,D2A,D2B 0.1% Note:Not applicable. SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 9 of 10 16. OTHER INFORMATION _____________________________________________________________________________________________ 0156MAR019 Marathon Petroleum Benzene Revision Date 05/14/2015 Prepared By Toxicology and Product Safety Revision Notes Revision Date 05/14/2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is intended as guidance for safe handling, use, processing, storage, transportation, accidental release, clean-up and disposal and is not considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SDS ID NO.: 0156MAR019 Product name: Marathon Petroleum Benzene Page 10 of 10 APPENDIX B EMERGENCY PHONE NUMBERS Emergency Contact Phone Number Environmental PM: Greg Hans, PMP 617.828.9948 (M) CES Group Engineers, LLP 704.325.5408 (D) Other SSO (if assigned by by Env PM) Carolina Soil Investigations (Drillers) 704.539.5279 (assigned CSI field crew chief) Back-up PM Chuck Heleine 704.308.7916 (M) CES Group Engineers, LLP Police: North Carolina Highway Patrol 911 Claremont Police Department 828.466.7265 Hospital: Catawba Valley Medical Center 828.326.3000 3169 12th Avenue, SE Hickory, NC 28602 Fire: Claremont Fire Department 828.459.9296 Doctor: Catawba Valley Medical Center 828.326.3000 Ambulance 911 NCDENR (Mooresville Region) 704.663.1699 Directions to the nearest hospital: Catawba Valley Medical Center, 3169 12th Avenue, SE, Hickory, NC 28602 Refer to Appendix C. APPENDIX C ROUTE TO HOSPITAL Starting at approximate address of 3301 E Main Street, Claremont, NC 28610 End at Catawba Valley Medical Center, 3169 12th Avenue, SE, Hickory, NC 28602