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HomeMy WebLinkAboutAS-795_9412_CA_MRP_20230301ATCASSOCIATESOFNORTHCAROLINA,P.C.GROUNDWATERMONITORINGREPORTFORMERBEAL’S76(BEAL’S76HEATINGOILTANK)633NORTHMAINSTREET,HENDERSONVILLE,HENDERSONCOUNTY,NORTHCAROLINAATCProjectNo.SLC0941201Preparedfor:NorthCarolinaDepartmentofEnvironmentalQualityDivisionofWasteManagement-UndergroundStorageTankSection1646MailServiceCenterRaleigh,NorthCarolina27699-1646Preparedby:ATCAssociatesofNorthCarolina,P.C.7606WhitehallExecutiveCenterDrive,Suite800Charlotte,NorthCarolina28273Telephone704-529-3200\/C P A I\1f9/Email:William.Quarles@oneatlas.comAshleighThfcsrshProjectManagerDirectLine:704-972-4087Email:ashleiqh.thrash@oneatlas.comAlQuaries,P.G.SeniorProjectManagerDirectLine:704-972-4089March1,2023 7606 Whitehall Executive Center Drive, Suite 800 Charlotte, NC 28273 Tel: 704-529-3200 www.atcgroupservices.com March 1, 2023 Ms. Kristie Oseguera North Carolina Department of Environmental Quality Division of Waste Management – Underground Storage Tank Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Subject: Groundwater Monitoring Report Former Beal’s 76 (Beal’s 76 Heating Oil Tank) 633 North Main Street Hendersonville, Henderson County, North Carolina 28792 NCDEQ Incident No. 9412 (9994) ATC Project No.: SLC0941201 Dear Ms. Oseguera: ATC Associates of North Carolina, P.C. (ATC) submits the enclosed Groundwater Monitoring Report for the Former Beal’s 76 Site. The report presents investigative procedures, field activities, and laboratory analytical results for a groundwater sampling event conducted in November 2022. The report has been completed based on a November 1, 2022, Task Authorization (TA-01) authorized by the Trust Fund Branch of the Underground Storage Tank Section, Division of Waste Management, North Carolina Department of Environmental Quality. The work was performed as part of the State Lead Contract #N122019A between the NCDEQ and ATC. If you have any questions, please contact Al Quarles at (704) 972-4089. Sincerely, ATC Associates of North Carolina, P.C. Ashleigh Thrash Al Quarles, P.G. Project Manager Senior Project Manager Direct Line: 704-972-4087 Direct Line: 704-972-4089 Email: ashleigh.thrash@oneatlas.com Email: William.Quarles@oneatlas.com Attachments: 1. Groundwater Monitoring Report Former Beal’s 76 (Beal’s 76 Heating Oil Tank) March 1, 2023 Page i ATC Project No. SLC1255101 NCDEQ State Lead Program Table of Contents 1.0 SITE IDENTIFICATION .......................................................................................................................... 1 2.0 EXECUTIVE SUMMARY ........................................................................................................................ 2 3.0 SITE DESCRIPTION .............................................................................................................................. 3 3.1 SITE CHARACTERIZATION ............................................................................................................................. 3 3.2 SITE BACKGROUND..................................................................................................................................... 3 3.3 SITE AND REGIONAL GEOLOGY ...................................................................................................................... 4 3.4 SITE AND REGIONAL HYDROGEOLOGY ............................................................................................................. 5 4.0 GROUNDWATER CHARACTERIZATION ........................................................................................... 5 4.1 GROUNDWATER LEVELS............................................................................................................................... 5 4.2 GROUNDWATER QUALITY ............................................................................................................................ 5 5.0 RECEPTOR SURVEY ............................................................................................................................ 6 6.0 CONCLUSIONS AND RECOMMENDATIONS .................................................................................... 6 7.0 LIMITATIONS.......................................................................................................................................... 7 TABLES: Table 1 – Well Construction and Groundwater Elevation Data Table 2 – Field Parameters Table 3 – Groundwater Analytical Results Table 4 – Conceptual Site Model FIGURES: Figure 1 – Topographic Map Figure 2 – Site Map Figure 3 – Groundwater Elevation Contour Map Figure 4 – Groundwater Quality Map APPENDICES: Appendix A – Signed Access Agreements Appendix B – Field Notes and Photographic Log Appendix C – Additional Historical Analytical Results (November 1992 – March 1996) Appendix D – Laboratory Analytical Results Appendix E – Water Supply Well Information (Returned Surveys) ATCFormerBeal’s76(Beal’s76HeatingOilTank)March1,2023Page1of6ASSOCIATESOFNORTHCAROLINA.P.C.1.0SITEIDENTIFICATION1.SiteIdentificationDateofReport:FacilityI.D.:SiteRisk:IntermediateSiteRank:I185D/L60EFormerBeal’s76(Beal's76HeatingOilTank)March1,2023USTNumber:AS-795/AS-87100-0-0000013033USTIncidentNumber(ifknown):9412/9994LandUseCategory:CommericalSiteName:SiteStreetAddress:633NorthMainStreetCitv/Town:HendersonvilleDescriptionofGeographicalDataPoint:FormerGasolineUSTBasinLocationMethod:GoogleEarthZipCode:28792County:HendersonLatitude(decimaldegrees):35.319396°Longitude(decimaldegrees):82.461114°2.InformationaboutContactsAssociatedwiththeLeakingUSTSystemUSTOwner:(Former)Clifford(deceased)andDeloresShipmanAddress:739NorthMainStreet,Hendersonville,NC28792USTOperator:UnknownAddress:n/aPropertyOwner:ShipmanRentalsLLCAddress:739NorthMainStreet,Hendersonville.NC28792PropertyOccupant:UMIJapaneseRestaurantAddress:633NorthMainStreet.Hendersonville,NC28792Consultant/Contractor:ATCAssociatesofNorthCarolina,P.C.Address:7606WhitehallExecutiveCenterDr.,Suite800,Charlotte.NCAnalyticalLaboratory:PaceAnalyticalService.LLCAddress:9800KincevAve,Ste100,Huntersville.NC28078Tel.:828-693-4904Tel.:n/aTel.:828-693-4904Tel.:828-698-8048Tel.:(919)871-0999StateCertificationNo.12Tel:704-875-90923.InformationaboutReleaseDateDiscovered:EstimatedQuantityofRelease:UnknownCauseofRelease:UnknownSourceofRelease(Dispenser/Piping/UST):USTsystemSizesandcontentsofUSTsystem(s)fromwhichthereleaseoccurred:three4.000-qallongasolineUSTs(Incident9412)andone500-qallonheatingoilUST(Incident9994)November5,1992CriteriaUsedtoClassifyRisk:LNAPLandGCLexceedances(wellsMW-4andMW-9)4.InformationabouttheMonitoringReportDate(s)ofGroundwaterMonitoring/SoilSamplingEvent(s):November30,20225.CertificationI,AlQuarles,aLicensedGeologistforATCAssociatesofNorthCarolina.P.C.,docertifythattheinformationcontainedinthisreportiscorrectandaccuratetothebestofmyknowledge.ATCAssociatesofNorthCarolina,P.C.islicensedtopracticeengineeringandgeologyinNorthCarolina.ThecertificationnumberofthecompanyorcorporationforengineeringisC-1598.ThecertificationnumberofthecompanyorcorporationforgeologyisC-294.ATCProjectNo.SLC0941201NCDEQStateLeadProgram Former Beal’s 76 (Beal’s 76 Heating Oil Tank) March 1, 2023 Page 2 of 6 ATC Project No. SLC0941201 NCDEQ State Lead Program 2.0 EXECUTIVE SUMMARY On behalf of the Trust Fund Branch of the UST Section, ATC has completed a Groundwater Monitoring Report documenting the November 30, 2022, monitoring activities for the Former Beal’s 76 (Beal’s 76 Heating Oil Tank) site, located at 633 North Main Street in Hendersonville, North Carolina. The report has been completed based on a November 1, 2022, Task Authorization (TA-01) authorized by the Trust Fund Branch of the Underground Storage Tank (UST) Section, Division of Waste Management, North Carolina Department of Environmental Quality (NCDEQ). The work was performed as part of the State Lead Contract #N122019A between the NCDEQ and ATC. The approved scope of services included the following: 1) a file review; 2) pursue access agreements with the owners of off-site properties with monitoring wells; 3) measure liquid levels and sample monitoring wells with no Light Non-Aqueous Phase Liquid (LNAPL); 4) conduct a vehicular reconnaissance to identify potential receptors within 1,000 feet of the source areas and submit water supply well questionnaires to owners of properties within 500 feet of the source areas. The findings from the recent and historical assessment activities indicate the following:  No surface water bodies or water supply wells were located within 1,000 feet of the source area;  Monitoring well MW-4 contained measurable LNAPL (0.45 feet) and was not sampled;  Groundwater samples were collected from monitoring wells MW-1, MW-2, and MW-10D. Petroleum volatile organic compounds (VOCs) were reported in samples MW-1 and MW-2 at concentrations in excess of the 15A NCAC 02L .0202 groundwater quality standards (2L Standards). Vinyl chloride was reported in sample MW-10D in excess of the 2L Standard. None of the reported concentrations exceeded the Gross Contamination Levels (GCLs);  Monitoring wells MW-3, MW-5, MW-6, and MW-7 were not located;  Monitoring wells MW-8D and MW-9 could not be opened;  Monitoring well MW-15 was located under a parked vehicle, and the owner of the vehicle could not be located; and,  Groundwater elevations indicate that groundwater flow is generally to the south, and previous data indicate that groundwater flow is to the southeast towards Mud Creek. Wells MW-2, MW-4, and MW-9 previously contained LNAPL. VOC concentrations in well MW-1 have increased slightly compared to the March 1996 results. VOC concentrations in MW-2 have decreased since the March 1996 results. The VOC concentrations in MW-1 and MW-2 do not exceed 5% of the GCLs. The November 2022 results compared to the March 1996 results for wells MW-1 and MW-2 suggest that the plume is stable. The risk classification of the incident remains Intermediate based on the presence of LNAPL in MW-4, the prior presence of LNAPL in MW-9, and the prior exceedances of the GCLs when these wells were sampled in the past. Prior corrective action apparently included air sparging in well MW-8D and vapor extraction and groundwater pump and treat using well MW-9. ATC recommends the following: 1) Uncover wells MW-8D and MW-9 for sampling and possible use as remediation wells. 2) Locate and uncover the piping from wells MW-8D and MW-9 and evaluate the condition of the piping possible use for air sparging (MW-8D) and either vapor extraction only or total fluid extraction (MW-9). Evaluate possible replacement of sparge line if the existing air line is not in a condition to allow sparging. The current building may be over the area of the former treatment system. 3) Conduct an mobile multi-phase extraction event with air sparging (MMPE/AS) using wells MW-9 and MW-8D from the remote piping location, or conduct an 8-hour Aggressive Fluid Recovery (AFVR) event with AS using wells MW-4 and MW-9 as extraction wells and MW-8D as a sparge well (may require to be conducted during times the restaurant is closed). 4) Conduct subsequent monitoring of wells MW-4 and MW-9 to evaluate the removal of LNAPL and reduction of VOC concentrations compared to the GCLs. Former Beal’s 76 (Beal’s 76 Heating Oil Tank) March 1, 2023 Page 3 of 6 ATC Project No. SLC0941201 NCDEQ State Lead Program 3.0 SITE DESCRIPTION 3.1 SITE CHARACTERIZATION The Former Beal’s 76 (Beal’s 76 Heating Oil tank) site is located at 633 North Main Street in Hendersonville, North Carolina. Currently, the site is operated as the Umi Japanese Restaurant. The property is bound on the north by West Seventh Street; to the east by North Main Street, on the south by commercial properties, and on the West by the Reformation Presbyterian Church. The source areas for the incident include three 4,000-gallon gasoline USTs located near the east-central portion of the Site and one 500-gallon heating oil UST located north of the Site building. The three 4,000- gallon gasoline USTs were removed in 1990. The 500-gallon heating oil UST and a 500-gallon waste oil UST were removed in December 1992. No release was identified for the waste oil UST. Municipal water is available to the site and surrounding properties. A receptor survey conducted prior to sampling did not identify any water supply wells or surface water bodies within 1,000 feet of the site. A site topographic map is included as Figure 1 and a site map depicting monitoring well locations and other pertinent site features is included as Figure 2. 3.2 SITE BACKGROUND Three 4,000-gallon gasoline USTs were removed in 1990. A closure report could not be located in NCDEQ files. A 500-gallon waste oil UST and a 500-gallon heating oil UST were removed in December 1992. On July 21, 1992, a Pollution Incident/UST Leak Reporting Form (release report) was submitted for the site documenting petroleum chemicals in the subsurface that were found during an investigation at a neighboring site located across West Seventh Street to the northeast (Triangle Stop #200, Incident #6886). During this investigation, a monitoring well (MW-15) was installed in the North Carolina Department of Transportation (DOT) Right of Way (ROW) essentially on the Former Beal’s 76 site. Sampling results from well MW-15 indicated petroleum VOCs above the 2L Standards at that time. On November 5, 1992, Blue Ridge Environmental Services, Inc. (Blue Ridge), submitted a Preliminary Assessment Report (PAR) documenting subsurface investigation and monitoring well installation at the Site. During this investigation, four soil borings were advanced in the area of the former UST excavation to a depth of 12 feet below ground surface (ft-bgs) and two monitoring wells were installed to a depth of 30 ft- bgs (MW-1 and MW-2) between October 15 and October 20, 1992. Blue Ridge documented minor Photoionization Detector (PID) readings in the soil samples. However, groundwater samples collected from wells MW-1 and MW-2 contained VOCs above the 2L Standards. MW-1 contained total xylenes (430 μg/L) and naphthalene (94 μg/L) and MW-2 contained benzene (5,695 μg/L), toluene (15,270 μg/L), ethylbenzene (2,595 μg/L), total xylenes (16,140 μg/L), methyl-tert-butyl ether or MTBE (1,074 μg/L), and naphthalene (146 μg/L). On May 13, 1993, Blue Ridge submitted a Comprehensive Site Assessment (CSA) Report documenting the closure of the two remaining USTs at the Site and collection of data relating to initial abatement and assessment for the Site. During the CSA, the 550-gallon waste oil UST and the 550-gallon heating oil UST were closed by removal and Blue Ridge provided oversight of the closure. Blue Ridge documented that the USTs appeared to be in fair condition with only minor rust and no obvious holes. The soil excavated during this removal was returned to the excavation pit due to the lack of significant organic vapor readings or apparent evidence of hydrocarbon contamination. Soil samples collected during the excavation were submitted for Total Petroleum Hydrocarbon (TPH) analysis and the results were below established action levels. However, laboratory analytical results for soil samples collected from the areas of the former dispenser islands, former heating oil tank, and from monitoring well MW-5 installed across North Main Street at the former Lunsford Exxon contained VOCs in excess of established action levels. During October 1992 through January 1993, monitoring wells MW-1 through MW-6 were installed as part of the CSA. Groundwater samples were collected from all of the newly installed monitoring wells on February 5, 1993 Former Beal’s 76 (Beal’s 76 Heating Oil Tank) March 1, 2023 Page 4 of 6 ATC Project No. SLC0941201 NCDEQ State Lead Program and submitted for analysis of VOCs by EPA Method 602 and for PAHs by EPA Method 610. Sample results indicated that monitoring wells MW-2, MW-4, and MW-5 contained VOCs at concentrations exceeding the 2L Standards at that time. On July 31, 1995, Handex of the Carolinas, Inc. (Handex) submitted a Corrective Action Plan (CAP). An evaluation of remediation alternatives was discussed in the report and the recommended remedial action at the site was determined to be vacuum-enhanced pump-and-treat in conjunction with air sparging. The CAP also documented monitoring well installation and groundwater sampling conducted by Handex in May and June of 1995. On May 2, 1995, monitoring well MW-9 was installed as part of a vacuum-enhanced pump test and for future use as a possible recovery well. On May 16, 1995 and June 22, 1995, respectively, Handex installed monitoring wells MW-8D and MW-10D to evaluate the vertical extent of VOCs at the Site. Monitoring well MW-8D was also installed to be used as a future air sparge well. A report documenting system startup was not located in NCDEQ files. Between April 1995 and April 1996, Quarterly Monitoring Reports (QMRs) were submitted by Handex documenting groundwater sampling and analysis of groundwater samples collected from site monitoring wells and quarterly corrective action conducted at the Site. The QMRs documented historical LNAPL detections in monitoring wells MW-2, MW-4, and MW-9 and 2L exceedances in monitoring wells MW-1, MW-2, MW-4, MW-5, MW-8D, MW-9, and MW-15. In the April 28, 1995 QMR, Handex documented the installation of an LNAPL absorbent sock in MW-4. The most recent quarterly monitoring report available to ATC was dated April 26, 1996. The July 1995 Corrective Action Plan recommended air sparging in well MW-8D and vapor extraction and groundwater pump and treat using well MW-9. In a letter dated February 1, 1996, Handex indicated that installation of a corrective action system (air sparging and vapor extraction) began in late 1995. There are no other reports available to ATC regarding the operation and monitoring associated with corrective action. In a December 27, 2006 letter from the North Carolina Department of Environment and Natural Resources (NCDENR, now NCDEQ) to the Responsible Party (Mr. Shipman), the NCDENR states “The site is currently ranked LOW risk, and further remediation is not currently required.” The letter also indicated that the equipment belongs to the Responsible Party. The equipment was apparently removed from the site sometime after that letter was issued. In the absence of reports documenting the progress of corrective actions and associated monitoring, ATC cannot comment on the progress of remediation during the corrective actions. On September 16, 2022, the NCDEQ established a new Risk, Rank, and Abatement score of I185D. On September 29, 2022, the Asheville Regional office of the NCDEQ recommended the incident to the State Lead Cleanup program. The incident was subsequently accepted into the State Lead Cleanup program. The Site Access Agreement with the property owner (Shipman Rentals, LLC, Delores Shipman) was signed on September 28, 2022. 3.3 SITE AND REGIONAL GEOLOGY According to the 1985 USGS Geologic Map of North Carolina, the site is located within the Blue Ridge physiographic province near the Brevard Zone, which is in an area of faulting and a narrow zone of low relief. The most prominent formation in this area is the Henderson Gneiss which is described as medium to coarse grained biotite gneiss. Otherwise, the area is characterized by a mixture of igneous, metamorphic, and sedimentary rocks from the Proterozoic and Cambrian age. Boring logs from previous assessment activities generally identify the soils as grey to brown clay, silt, and mixtures of silt, clay, and sand with fragments of micas, feldspars, granites, and quartz. Bedrock was not documented in any of the borings completed on site to date, including the deep boring for MW-8D terminated at a depth of 50 ft-bgs. Former Beal’s 76 (Beal’s 76 Heating Oil Tank) March 1, 2023 Page 5 of 6 ATC Project No. SLC0941201 NCDEQ State Lead Program 3.4 SITE AND REGIONAL HYDROGEOLOGY The hydrogeology of the site is influenced by the Blue Ridge physiographic Province. The site is in a narrow zone of low relief. The drainage in the area is primarily to the northwest to the Tennessee River via the French Broad River. Groundwater flow through weathered bedrock (saprolite), that overlies competent bedrock, is primarily influenced by topography. Surficial aquifers in the area are unconfined. Hydrogeology within the bedrock aquifers in the area are influenced and characterized by secondary fracturing, joints, and cleavage planes within the formations. The groundwater table is in the saprolite, which is comprised of fine clay, silt, and mixtures of silt, clay, and sand with fragments of micas, feldspars, granites, and quartz. The water table at the site historically occurs approximately 17 to 20 ft-bgs. Historical groundwater measurements recorded at the site indicate the local groundwater flow is to the southeast toward Mud Creek. A Corrective Action Plan (CAP) submitted for the Site on July 28, 1995, identified the hydraulic gradient of 0.014 ft/ft across the site. The CAP also estimated a porosity of 20% for sandy soils. No additional aquifer information was available. 4.0 GROUNDWATER CHARACTERIZATION ATC personnel conducted a groundwater sampling event on November 30, 2022. Prior to the sampling event, ATC obtained a signed access agreement from the owners of properties where monitoring wells MW-6 and MW-7 were formerly located. Copies of the signed agreements are included in Appendix A. 4.1 GROUNDWATER LEVELS Groundwater level measurements were collected from monitoring wells MW-1, MW-2, MW-4, and MW-10D on November 30, 2022. Monitoring wells MW-3, MW-5, MW-6, and MW-7 were not located, even with the use of a metal detector, and wells MW-8D, and MW-9 could not be opened. MW-15 was located under a parked car and the owner could not be located. Monitoring well construction details and current and historical groundwater elevation data are summarized in Table 1. Depth to groundwater measurements ranged from 10.29 ft-bgs in MW-10D to 21.02 ft-bgs in MW-1. A groundwater elevation contour map generated using the November 30, 2022 groundwater elevation data is included as Figure 3. The groundwater elevation contours are also based on previously reported groundwater elevation contours, since the three monitoring wells with groundwater elevation data are not widely spaced for triangulation. This figure indicates that the direction of groundwater flow at the site is generally to the southeast. Field notes and the photographic log from the November 30, 2022, site visit are included in Appendix B. 4.2 GROUNDWATER QUALITY On November 30, 2022, ATC collected groundwater samples from monitoring wells MW-1, MW-2, and MW- 10D. Monitoring well MW-4 contained measurable LNAPL (0.45’). Field parameters obtained following purging of the monitoring wells are included in Table 2. Samples were collected in laboratory-approved containers, packed in ice and delivered under chain-of-custody protocol to Pace Analytical in Huntersville, North Carolina for analyses. All groundwater samples were analyzed for VOCs by EPA Method 6200B including MTBE, isopropyl ether (IPE), and 1,2-dibromoethane (ethylene dibromide or EDB). Petroleum volatile organic compounds (VOCs) were reported in samples MW-1 and MW-2 at concentrations in excess of the 15A NCAC 02L .0202 groundwater quality standards (2L Standards). Vinyl chloride, a non-petroleum VOC, was reported in sample MW-10D in excess of the 2L Standard. None of the reported concentrations exceeded the Gross Contamination Levels (GCLs). VOC concentrations in well MW-1 have increased slightly compared to the March 1996 results. VOC concentrations in MW-2 have decreased since the March 1996 results. The VOC concentrations in MW-1 and MW-2 do not exceed 5% of the GCLs. The November 2022 results compared to the March 1996 results for wells MW-1 and MW-2 suggest that the plume is stable. Former Beal’s 76 (Beal’s 76 Heating Oil Tank) March 1, 2023 Page 6 of 6 ATC Project No. SLC0941201 NCDEQ State Lead Program Current groundwater analytical data are summarized in Table 3. Additional historical results (November 1992 – March 1996) are included in Appendix C. The laboratory analytical report and chain-of-custody forms are included in Appendix D. A map showing chemicals of concern for the site that exceed the 2L Standards is included as Figure 4. As part of ATC’s quality assurance and quality control (QA and QC) measures, a data review of the laboratory report was conducted. During the review, it was concluded that samples were received by the laboratory in acceptable condition and properly preserved. The samples were analyzed within the correct holding times, and the chain of custody was properly completed by all parties. Toluene was detected in the Field Blank at an estimated concentration of 0.38 μg/L. The laboratory QA/QC report shows Method Blanks (MB), Matrix Spikes (MS) and Matrix Spike Duplicates (MSD), and laboratory control samples (LCS) were analyzed for each analytical method. MB, LCS, and MS/MSD data results were also provided for each analytical method. Toluene was not recovered outside of QC limits in any of the laboratory QA/QC samples. Refer to the laboratory report in Appendix D for details regarding QA/QC results for the laboratory samples and any noted exceptions. Overall, ATC concludes that the laboratory results are usable and any exceptions do not significantly impact the conclusions presented in this report. 5.0 RECEPTOR SURVEY ATC submitted water supply well questionnaires to 48 owners of properties located within 500 feet of the Site and conducted a vehicular reconnaissance within 1,000 feet of the Site to identify potential receptors (surface water bodies and water supply wells). No water supply wells or surface water bodies were identified within 1,000 feet of the Site during the vehicular reconnaissance. The nearest surface water body indicated by the Henderson County GIS website is more than 1,200 feet north-northwest of the Site. No water supply wells were identified from the returned questionnaires associated with twelve properties, including one from the Skyland Condos property manager for all of the condominiums managed by Skyland Condos. Copies of the returned questionnaires are included in Appendix E. 6.0 CONCLUSIONS AND RECOMMENDATIONS On behalf of the Trust Fund Branch of the UST Section, ATC has completed a Groundwater Monitoring Report documenting the November 30, 2022 monitoring activities for the Former Beal’s 76 Site, located at 633 North Main Street in Hendersonville, North Carolina. The findings from the recent and historical assessment activities indicate the following:  No surface water bodies or water supply wells were located within 1,000 feet of the source area;  Monitoring well MW-4 contained measurable LNAPL (0.45 feet) and was not sampled;  Groundwater samples were collected from monitoring wells MW-1, MW-2, and MW-10D. Petroleum volatile organic compounds (VOCs) were reported in samples MW-1 and MW-2 at concentrations in excess of the 15A NCAC 02L .0202 groundwater quality standards (2L Standards). Vinyl chloride was reported in sample MW-10D in excess of the 2L Standard. None of the reported concentrations exceeded the Gross Contamination Levels (GCLs);  Monitoring wells MW-3, MW-5, MW-6, and MW-7 were not located;  Monitoring wells MW-8D and MW-9 could not be opened;  Monitoring well MW-15 was located under a parked vehicle, and the owner of the vehicle could not be located; and,  Groundwater elevations indicate that groundwater flow is generally to the south, and previous data indicate that groundwater flow is to the southeast towards Mud Creek. Table 4 presents the Conceptual Site Model for the site based on the recent and historical assessment activities and corrective actions. Wells MW-2, MW-4, and MW-9 previously contained LNAPL. VOC concentrations in well MW-1 have increased slightly compared to the March 1996 results. VOC concentrations in MW-2 have decreased since the March 1996 results. The VOC concentrations in MW-1 and MW-2 do not exceed 5% of the GCLs. The November 2022 results compared to the March 1996 results for wells MW-1 and MW-2 suggest that the plume is stable. The risk classification of the incident remains Former Beal’s 76 (Beal’s 76 Heating Oil Tank) March 1, 2023 Page 7 of 6 ATC Project No. SLC0941201 NCDEQ State Lead Program Intermediate based on the presence of LNAPL in MW-4, the prior presence of LNAPL in MW-9, and the prior exceedances of the GCLs when these wells were sampled in the past. Prior corrective action apparently included air sparging in well MW-8D and vapor extraction and groundwater pump and treat using well MW-9 (see Section 3.2). Without the remediation progress reports that may exist between 1996 and 2006, the success of the prior corrective actions cannot be ascertained. However, based on the recent LNAPL in well MW-4, the prior corrective actions may have had limited success in site remediation. ATC recommends the following: 1) Uncover wells MW-8D and MW-9 for sampling and possible use as remediation wells. 2) Locate and uncover the piping from wells MW-8D and MW-9 and evaluate the condition of the piping possible use for air sparging (MW-8D) and either vapor extraction only or total fluid extraction (MW-9). Evaluate possible replacement of sparge line if the existing air line is not in a condition to allow sparging. The current building may be over the area of the former treatment system. 3) Conduct an MMPE/AS event using wells MW-9 and MW-8D from the remote piping location, or conduct an 8-hour AFVR event with AS using wells MW-4 and MW-9 as extraction wells and MW- 8D as a sparge well (may require to be conducted during times the restaurant is closed). 4) Conduct subsequent monitoring of wells MW-4 and MW-9 to evaluate the removal of LNAPL and reduction of VOC concentrations compared to the GCLs. 7.0 LIMITATIONS This report has been prepared for the exclusive use of the NCDEQ. The opinions included herein are based on information obtained during the study, on our experience in accordance with currently accepted hydrogeologic and engineering practices, and relevant regulatory guidelines at this time and location. Other than this, no warranty is implied or intended. Former Beal’s 76 ATC Project No. SLC0941201 NCDEQ State Lead Program TABLES MW-1 10/15/1992 11/30/2022 2 30 10-30 99.89 ----21.02 78.87 MW-2 10/20/1992 11/30/2022 2 30 10-30 99.40 19.59 0.01 19.60 79.81 MW-3 01/20/1993 CNL 2 30 15-30 100.41 ----CNL CNL MW-4 01/20/1993 11/30/2022 2 30 15-30 99.61 19.46 0.45 19.91 80.09 MW-5 01/22/1993 CNL 2 30 15-30 98.96 ----CNL CNL MW-6 01/29/1993 CNL 2 25 10-25 100.40 ----CNL CNL MW-7 Unknown CNL Unknown Unknown Unknown 100.08 ----CNL CNL MW-8D 05/16/1995 CNO 2 50 45-50 99.42 ----CNO CNO MW-9 05/02/1995 CNO 4 30 10-30 99.31 ----CNO CNO MW-10D Unknown 11/30/2022 Unknown Unknown Unknown 99.53 ----10.29 89.24 MW-15*Unknown CNL Unknown Unknown Unknown 100.76 ----CNL CNL Notes: -- = Not Detected TOC = Top-of-casing CNL = Could Not Locate CNO = Could Not Open ft-bgs = Feet below ground surface ft-toc = feet below top of casing Groundwater Elevation = TOC Elevation - (Depth to Groundwater - (LNAPL Thickness x 0.8581)) * = MW-15 installed for the assessment of UST Incident # 6886 (Triangle Stop #200) located northeast of the Former Beal's 76 site. TABLE 1 WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA Former Beal's 76 633 N. Main Street Hendersonville, North Carolina 28792 NCDEQ Incident #09412/09994 Well ID Screen Interval (ft-bgs) Date Installed Well Casing Diameter (inches) Groundwater Elevation (feet) TOC Elevation (feet) Depth to Groundwater (ft-toc) Date Measured Well Depth (ft-bgs) Depth to LNAPL (ft-toc) LNAPL Thickness (feet) Page 1 of 1 FIELD PARAMETERS Former Beal's 76 633 N. Main Street Hendersonville, North Carolina 28792 NCDEQ Incident #09412/09994 MW-1 11/30/22 21.13 0.726 0.9 659 Faulty Reading MW-2 11/30/22 21.64 6.1 0.6 73.4 Faulty Reading MW-10D 11/30/22 18.7 6.255 0.7 -130 Faulty Reading Notes: °C = degrees Celsius mS/cm = milliSiemens per centimeter mg/L = milligrams per liter ORP = oxidation-reduction potential mV= millivolts su = standard units TABLE 2 pH (su)Well ID Sample Date Temperature (°C) Conductivity (mS/cm) Dissolved Oxygen (mg/L) ORP (mV) Page 1 of 1 Well ID Date Collected BenzeneTolueneEthylbenzeneXylene (Total)NaphthaleneVinyl chloriden-PropylbenzeneIsopropylbenzene(Cumene)1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneChlorobenzene1 600 600 500 6 0.03 70 70 400 400 50 5,000 260,000 80,000 50,000 6,000 30 26,100 30,500 24,100 28,500 50,000 MW-1 11/30/2022 28.1 371 517 2,030 230 <1.9 77.0 40.1 191 833 <1.4 MW-2 11/30/2022 8.0 427 153 869 114 <1.9 73.4 26.6 170 607 <1.4 MW-4 11/30/2022 MW-10D 11/30/2022 0.83 0.69 <0.30 0.47J <0.64 0.64J <0.34 <0.33 0.65 0.84 0.33J Notes: 1) 15A NCAC 02L 0202 Groundwater Quality Standards (2L Standards). 2) NCDEQ Division of Waste Management (DWM) Gross Contamination Levels (GCLs). Only constituents detected above the reporting limit are shown Concentrations are reported in micrograms per liter (µg/L) Concentrations in bold exceed the 2L Standard Concentrations in bold and underlined exceed the GCL J = estimated concentration below the laboratory reporting limit 2L Standard (1) GCL (2) Not Sampled: LNAPL (0.45') TABLE 3 GROUNDWATER ANALYTICAL RESULTS Former Beal's 76 633 N. Main Street Hendersonville, North Carolina 28792 NCDEQ Incident #09412/09994 Page 1 of 1 Site Name: Former Beal's 76 Date:1/27/2023 Property Owner:Shipman Rentals, LLC Last Field Event Date:11/30/2022 NCDEQ UST Incident No.:9412/9994 Release Discovery Date:11/5/1992 Facility ID No.:00-0-0000013033 Source of Release:Dispenser/Piping Risk Classification:Intermediate Estimated Volume of Release:Unknown Risk Rank:185D Site Address:633 North Main Street Gasoline (leaded)Y Site City, ST ZIP:Hendersonville, NC 28792 Gasoline (unleaded) Site County:Henderson Gasoline (ethanol blend) NCDEQ Regional Office:Asheville Diesel Active UST Facility (Y/N/U):No Kerosene USTs Present (Y/N/U):No Heating Oil (#2)Y (MW-3, Low Risk now?) Heating Oil (>#2) Motor Oil Major Soil Type:Silty Clay Hydraulic Oil Surface Cover over impacted soil:Asphalt Used Oil Utilities within plume (Y/N/U):N >S-W MSCCs (Y/N/U):U (no risk-based rule data) >Residential MSCCs (Y/N/U):U >Comm/Ind MSCCs (Y/N/U):U Site (Current):Commercial (restaurant) Site (Future):Commercial North Adjacent:Commercial (Bank) Litho-Tectonic Zone Blue Ridge East Adjacent:Commercial (lawyer office/retail) Geologic Formation Henderson Gneiss South Adjacent:Commercial (Bank) Rock Type gneiss West Adjacent:Institutional (Church) Depth to Bedrock (ft bgs)>50 ft Municipal Water (Y/N/U):Y Active Potable Wells <1000 ft (#/U):N Depth to water (ft-bgs)19-21 Active Potable Wells <500 ft (#/U):N Gradient (ft/ft):0.021 Impacted Wells (Y/N/U):NA Direction (N E S W combo):SE Any wells <250 ft (Y/N/U):N Hydraulic Conductivity (ft/day):Unknown Total Porosity (%):20% (estimated)<500 ft (Y/N):N Effective Porosity (%):Unknown Type of Surface Water:NA Flow Rate (ft/year):Unknown Name of Nearest Stream:NA COCs >2L (Y/N/U):Y Stream Classification:NA COCs >2L Extent Defined (Y/N):N Impacted Surface Water (Y/N/U):NA COCs >GCLs (Y/N/U):Y COCs >GCLs (Wells):MW-4, MW-9 COCs >GCLs Extent Defined (Y/N):Y >LEL in Structures:Unknown (not likely) COCs >2B Standards by 10X (Y/N/U):NA Vapors in Buildings:Unknown (not likely) LNAPL (Y/N/U):Y Slab-on-grade or Crawlspace:Slab-on-grade LNAPL (Max Thickness ft):0.45 Dissolved VOCs <5 ft of Structures:No LNAPL (Wells):MW-4 LNAPL <15 ft of Structures:No LNAPL Extent Defined (Y/N):Y Basement <30 ft of Dissolved COCs:NA LNAPL (<5 ft beneath buildings/U):N Utilities within plume (Y/N/U):N Alternative Water Source:NA NORP:When LNAPL & GCLs addressed Site Remediation:Y Soil Excavation: AFVR: MMPE:Y (with AS) SVE/AS: Other: TABLE 4. CONCEPTUAL SITE MODEL Possible Path(s) to Closure Site Information Release Information Petroleum Type Released Comments: Receptor Information Water Supply Vapor Additional Support Documentation Available / Data Gaps: No risk-based soil analytical results. Approach (general discussion):Remove LNAPL and reduce VOCs <GCLs (MW-4 and possibly MW-9) Soil Information Geologic Information Groundwater Information Surface Water Land Use / Zoning Prior AS and SVE and P&T possibly between 1996 and 2006. Apparently low conductivity soils, little migration of VOCs since 1996 (26 years). Page 1 of 1 Former Beal’s 76 ATC Project No. SLC0941201 NCDEQ State Lead Program FIGURES 1. IMAGE SOURCE - GOOGLE EARTH, USGS EARTH POINT TOPO MAP APPLICATION MW-5 MW-3MW-6MW-15MW-4MW-10DMW-2MW-8DMW-9WEST SEVENTH STREETNORTH MAIN STREETFORMER500-GALHEATING OILUSTFORMERUST BASINFORMERDISPENSERAREAMW-1FORMER500-GALWASTE OILUSTMW-7= TYPE II MONITORING WELL= TYPE III MONITORING WELL1. IMAGE SOURCE - GOOGLE EARTH, OCTOBER, 2021 2. LOCATIONS OF NOTED FEATURES ARE APPROXIMATE MW-5 MW-3MW-6MW-15MW-4MW-10DMW-2MW-8DMW-9WEST SEVENTH STREETNORTH MAIN STREETFORMER500-GALHEATING OILUSTFORMERUST BASINFORMERDISPENSERAREAMW-1FORMER500-GALWASTE OILUSTMW-7= TYPE III MONITORING WELL= TYPE II MONITORING WELL1. IMAGE SOURCE - GOOGLE EARTH, OCTOBER, 2021 2. LOCATIONS OF NOTED FEATURES ARE APPROXIMATE NM77.05 NM83.26 80.0982.31 NM82.96 79.8182.00 84.083.082.0 8 1 . 0 8 0 . 0= GROUNDWATER ELEVATION IN FEET82.87= GROUNDWATER ELEVATION IN FEET = GROUNDWATER ELEVATION CONTOUR = GROUNDWATER FLOW DIRECTION 82.87(DASHED WHERE INFERRED) BASED ON GROUNDWATER ELEVATIONS MEASURED 11/30/2022 BASED ON GROUNDWATER ELEVATIONS MEASURED 03/12/1996NM82.26 NM85.19 NM81.53 89.2482.03 79.0 78.078.8781.15 NM80.08 MW-5 MW-3MW-6MW-15MW-4MW-10DMW-2MW-8DMW-9WEST SEVENTH STREETNORTH MAIN STREETFORMER500-GALHEATING OILUSTFORMERUST BASINFORMERDISPENSERAREAMW-1FORMER500-GALWASTE OILUSTMW-7= TYPE III MONITORING WELL= TYPE II MONITORING WELL1. IMAGE SOURCE - GOOGLE EARTH, OCTOBER, 2021 2. LOCATIONS OF NOTED FEATURES ARE APPROXIMATE 3. ONLY EXCEEDANCES ARE SHOWN 4. GROUNDWATER SAMPLES TAKEN 11/30/2022 5. LNAPL = LIGHT NON-AQUEOUS PHASE LIQUID Former Beal’s 76 ATC Project No. SLC0941201 NCDEQ State Lead Program APPENDIX A SIGNED ACCESS AGREEMENTS Former Beal’s 76 ATC Project No. SLC0941201 NCDEQ State Lead Program APPENDIX B FIELD NOTES AND PHOTOGRAPHIC LOG ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #2: MW-1 Location reference Photo #1: MW-1 ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #4: MW-2 Location reference Photo #3: MW-2 ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #6: MW-2 product Photo #5: MW-2 new well cap ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #8: MW-3 (Possible Placement under container) Photo #7: MW-3 (Possible Placement) ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #10: MW-4 Location Reference Photo #9: MW-4 ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #12: MW-6 (Possible Location, looking East; Could not Locate) Photo #11: MW-5 (Possible Location, looking East; Could not Locate) ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #14: MW-8D Photo #13: MW-7 (Possible Location, looking SouthEast; Could not Locate) ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #16: MW-9 (Location Reference) Photo #15: MW-9 ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #18: MW-10D (Location Reference) Photo #17: MW-10D ATC Associates of North Carolina, P.C. 2725 E. Millbrook Road, Suite 121 Raleigh, NC 27604 (919) 871-0999 PHOTOGRAPHS ATC PROJECT NO: SLC0941201 REVIEWED BY: AQ SCALE: NTS DATE: 11/30/2022 Former Beal’s 76 633 N. Main St Hendersonville, NC 27020 Photo #20: MW-15 (Location Reference; Could Not Access due to Vehicle) Photo #19: MW-10D (Replaced well cap) Former Beal’s 76 ATC Project No. SLC0941201 NCDEQ State Lead Program APPENDIX C ADDITIONAL HISTORICAL ANALYTICAL RESULTS (NOVEMBER 1992 – MARCH 1996) Former Beal’s 76 ATC Project No. SLC0941201 NCDEQ State Lead Program APPENDIX D LABORATORY ANALYTICAL RESULTS #=CL# December 05, 2022 LIMS USE: FR - AL QUARLES LIMS OBJECT ID: 92639014 92639014 Project: Pace Project No.: RE: Al Quarles ATC Group Services LLC 7606 Whitehall Executive Cente Suite 800 Charlotte, NC 28273 SLC0941201-FORMER BEALS 76 Dear Al Quarles: Enclosed are the analytical results for sample(s) received by the laboratory on November 30, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Taylor M Cannon taylor.cannon@pacelabs.com Project Manager (704)875-9092 Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 27 #=CP# CERTIFICATIONS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 27 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Lab ID Sample ID Matrix Date Collected Date Received 92639014001 MW-1 Water 11/30/22 11:50 11/30/22 15:30 92639014002 MW-2 Water 11/30/22 12:30 11/30/22 15:30 92639014003 MW-10D Water 11/30/22 12:00 11/30/22 15:30 92639014004 FB Water 11/30/22 12:00 11/30/22 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 27 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92639014001 MW-1 SM 6200B 70 PASI-CSAS 92639014002 MW-2 SM 6200B 70 PASI-CSAS 92639014003 MW-10D SM 6200B 70 PASI-CSAS 92639014004 FB SM 6200B 70 PASI-CCL PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:MW-1 Lab ID:92639014001 Collected:11/30/22 11:50 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol <182 ug/L 12/02/22 20:09 75-85-45001825 tert-Amylmethyl ether <46.2 ug/L 12/02/22 20:09 994-05-850.0 46.2 5 Benzene 28.1 ug/L 12/02/22 20:09 71-43-22.5 1.7 5 Bromobenzene <1.4 ug/L 12/02/22 20:09 108-86-12.5 1.4 5 Bromochloromethane <2.3 ug/L 12/02/22 20:09 74-97-52.5 2.3 5 Bromodichloromethane <1.5 ug/L 12/02/22 20:09 75-27-42.5 1.5 5 Bromoform <1.7 ug/L 12/02/22 20:09 75-25-22.5 1.7 5 Bromomethane <8.3 ug/L 12/02/22 20:09 74-83-925.0 8.3 5 tert-Butyl Alcohol <134 ug/L 12/02/22 20:09 75-65-02501345 n-Butylbenzene <2.4 ug/L 12/02/22 20:09 104-51-82.5 2.4 5 sec-Butylbenzene <2.0 ug/L 12/02/22 20:09 135-98-82.5 2.0 5 tert-Butylbenzene <1.6 ug/L 12/02/22 20:09 98-06-62.5 1.6 5 tert-Butyl Formate <147 ug/L 12/02/22 20:09 762-75-42501475 Carbon tetrachloride <1.7 ug/L 12/02/22 20:09 56-23-52.5 1.7 5 Chlorobenzene <1.4 ug/L 12/02/22 20:09 108-90-72.5 1.4 5 Chloroethane <3.2 ug/L 12/02/22 20:09 75-00-35.0 3.2 5 Chloroform <2.2 ug/L 12/02/22 20:09 67-66-32.5 2.2 5 Chloromethane <2.7 ug/L 12/02/22 20:09 74-87-35.0 2.7 5 2-Chlorotoluene <1.6 ug/L 12/02/22 20:09 95-49-82.5 1.6 5 4-Chlorotoluene <1.6 ug/L 12/02/22 20:09 106-43-42.5 1.6 5 1,2-Dibromo-3-chloropropane <1.7 ug/L 12/02/22 20:09 96-12-85.0 1.7 5 Dibromochloromethane <1.8 ug/L 12/02/22 20:09 124-48-12.5 1.8 5 1,2-Dibromoethane (EDB)<1.4 ug/L 12/02/22 20:09 106-93-42.5 1.4 5 Dibromomethane <2.0 ug/L 12/02/22 20:09 74-95-32.5 2.0 5 1,2-Dichlorobenzene <1.7 ug/L 12/02/22 20:09 95-50-12.5 1.7 5 1,3-Dichlorobenzene <1.7 ug/L 12/02/22 20:09 541-73-12.5 1.7 5 1,4-Dichlorobenzene <1.7 ug/L 12/02/22 20:09 106-46-72.5 1.7 5 Dichlorodifluoromethane <1.7 ug/L 12/02/22 20:09 75-71-82.5 1.7 5 1,1-Dichloroethane <1.8 ug/L 12/02/22 20:09 75-34-32.5 1.8 5 1,2-Dichloroethane <1.6 ug/L 12/02/22 20:09 107-06-22.5 1.6 5 1,1-Dichloroethene <1.7 ug/L 12/02/22 20:09 75-35-42.5 1.7 5 cis-1,2-Dichloroethene <1.9 ug/L 12/02/22 20:09 156-59-22.5 1.9 5 trans-1,2-Dichloroethene <2.0 ug/L 12/02/22 20:09 156-60-52.5 2.0 5 1,2-Dichloropropane <1.8 ug/L 12/02/22 20:09 78-87-52.5 1.8 5 1,3-Dichloropropane <1.4 ug/L 12/02/22 20:09 142-28-92.5 1.4 5 2,2-Dichloropropane <1.9 ug/L 12/02/22 20:09 594-20-72.5 1.9 5 1,1-Dichloropropene <2.1 ug/L 12/02/22 20:09 563-58-62.5 2.1 5 cis-1,3-Dichloropropene <1.8 ug/L 12/02/22 20:09 10061-01-52.5 1.8 5 trans-1,3-Dichloropropene <1.8 ug/L 12/02/22 20:09 10061-02-62.5 1.8 5 Diisopropyl ether <1.5 ug/L 12/02/22 20:09 108-20-32.5 1.5 5 Ethanol <361 ug/L 12/02/22 20:09 64-17-510003615 Ethylbenzene 517 ug/L 12/02/22 20:09 100-41-42.5 1.5 5 Ethyl-tert-butyl ether <16.2 ug/L 12/02/22 20:09 637-92-350.0 16.2 5 Hexachloro-1,3-butadiene <7.6 ug/L 12/02/22 20:09 87-68-310.0 7.6 5 Isopropylbenzene (Cumene)40.1 ug/L 12/02/22 20:09 98-82-82.5 1.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:MW-1 Lab ID:92639014001 Collected:11/30/22 11:50 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <9.8 ug/L 12/02/22 20:09 75-09-210.0 9.8 5 Methyl-tert-butyl ether <2.1 ug/L 12/02/22 20:09 1634-04-42.5 2.1 5 Naphthalene 230 ug/L 12/02/22 20:09 91-20-310.0 3.2 5 n-Propylbenzene 77.0 ug/L 12/02/22 20:09 103-65-12.5 1.7 5 Styrene <1.5 ug/L 12/02/22 20:09 100-42-52.5 1.5 5 1,1,1,2-Tetrachloroethane <1.6 ug/L 12/02/22 20:09 630-20-62.5 1.6 5 1,1,2,2-Tetrachloroethane <1.1 ug/L 12/02/22 20:09 79-34-52.5 1.1 5 Tetrachloroethene <1.5 ug/L 12/02/22 20:09 127-18-42.5 1.5 5 Toluene 371 ug/L 12/02/22 20:09 108-88-32.5 1.2 5 1,2,3-Trichlorobenzene <4.0 ug/L 12/02/22 20:09 87-61-610.0 4.0 5 1,2,4-Trichlorobenzene <3.2 ug/L 12/02/22 20:09 120-82-110.0 3.2 5 1,1,1-Trichloroethane <1.7 ug/L 12/02/22 20:09 71-55-62.5 1.7 5 1,1,2-Trichloroethane <1.6 ug/L 12/02/22 20:09 79-00-52.5 1.6 5 Trichloroethene <1.9 ug/L 12/02/22 20:09 79-01-62.5 1.9 5 Trichlorofluoromethane <1.5 ug/L 12/02/22 20:09 75-69-45.0 1.5 5 1,2,3-Trichloropropane <1.3 ug/L 12/02/22 20:09 96-18-42.5 1.3 5 1,2,4-Trimethylbenzene 833 ug/L 12/02/22 20:09 95-63-62.5 2.5 5 1,3,5-Trimethylbenzene 191 ug/L 12/02/22 20:09 108-67-82.5 1.7 5 Vinyl chloride <1.9 ug/L 12/02/22 20:09 75-01-45.0 1.9 5 Xylene (Total)2030 ug/L 12/02/22 20:09 1330-20-75.0 1.7 5 m&p-Xylene 1620 ug/L 12/02/22 20:09 179601-23-15.0 3.5 5 o-Xylene 413 ug/L 12/02/22 20:09 95-47-62.5 1.7 5 Surrogates 1,2-Dichloroethane-d4 (S)93 %12/02/22 20:09 17060-07-070-130 5 4-Bromofluorobenzene (S)99 %12/02/22 20:09 460-00-470-130 5 Toluene-d8 (S)107 %12/02/22 20:09 2037-26-570-130 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:MW-2 Lab ID:92639014002 Collected:11/30/22 12:30 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol <182 ug/L 12/02/22 20:27 75-85-45001825 tert-Amylmethyl ether <46.2 ug/L 12/02/22 20:27 994-05-850.0 46.2 5 Benzene 8.0 ug/L 12/02/22 20:27 71-43-22.5 1.7 5 Bromobenzene <1.4 ug/L 12/02/22 20:27 108-86-12.5 1.4 5 Bromochloromethane <2.3 ug/L 12/02/22 20:27 74-97-52.5 2.3 5 Bromodichloromethane <1.5 ug/L 12/02/22 20:27 75-27-42.5 1.5 5 Bromoform <1.7 ug/L 12/02/22 20:27 75-25-22.5 1.7 5 Bromomethane <8.3 ug/L 12/02/22 20:27 74-83-925.0 8.3 5 tert-Butyl Alcohol <134 ug/L 12/02/22 20:27 75-65-02501345 n-Butylbenzene <2.4 ug/L 12/02/22 20:27 104-51-82.5 2.4 5 sec-Butylbenzene <2.0 ug/L 12/02/22 20:27 135-98-82.5 2.0 5 tert-Butylbenzene <1.6 ug/L 12/02/22 20:27 98-06-62.5 1.6 5 tert-Butyl Formate <147 ug/L 12/02/22 20:27 762-75-42501475 Carbon tetrachloride <1.7 ug/L 12/02/22 20:27 56-23-52.5 1.7 5 Chlorobenzene <1.4 ug/L 12/02/22 20:27 108-90-72.5 1.4 5 Chloroethane <3.2 ug/L 12/02/22 20:27 75-00-35.0 3.2 5 Chloroform <2.2 ug/L 12/02/22 20:27 67-66-32.5 2.2 5 Chloromethane <2.7 ug/L 12/02/22 20:27 74-87-35.0 2.7 5 2-Chlorotoluene <1.6 ug/L 12/02/22 20:27 95-49-82.5 1.6 5 4-Chlorotoluene <1.6 ug/L 12/02/22 20:27 106-43-42.5 1.6 5 1,2-Dibromo-3-chloropropane <1.7 ug/L 12/02/22 20:27 96-12-85.0 1.7 5 Dibromochloromethane <1.8 ug/L 12/02/22 20:27 124-48-12.5 1.8 5 1,2-Dibromoethane (EDB)<1.4 ug/L 12/02/22 20:27 106-93-42.5 1.4 5 Dibromomethane <2.0 ug/L 12/02/22 20:27 74-95-32.5 2.0 5 1,2-Dichlorobenzene <1.7 ug/L 12/02/22 20:27 95-50-12.5 1.7 5 1,3-Dichlorobenzene <1.7 ug/L 12/02/22 20:27 541-73-12.5 1.7 5 1,4-Dichlorobenzene <1.7 ug/L 12/02/22 20:27 106-46-72.5 1.7 5 Dichlorodifluoromethane <1.7 ug/L 12/02/22 20:27 75-71-82.5 1.7 5 1,1-Dichloroethane <1.8 ug/L 12/02/22 20:27 75-34-32.5 1.8 5 1,2-Dichloroethane <1.6 ug/L 12/02/22 20:27 107-06-22.5 1.6 5 1,1-Dichloroethene <1.7 ug/L 12/02/22 20:27 75-35-42.5 1.7 5 cis-1,2-Dichloroethene <1.9 ug/L 12/02/22 20:27 156-59-22.5 1.9 5 trans-1,2-Dichloroethene <2.0 ug/L 12/02/22 20:27 156-60-52.5 2.0 5 1,2-Dichloropropane <1.8 ug/L 12/02/22 20:27 78-87-52.5 1.8 5 1,3-Dichloropropane <1.4 ug/L 12/02/22 20:27 142-28-92.5 1.4 5 2,2-Dichloropropane <1.9 ug/L 12/02/22 20:27 594-20-72.5 1.9 5 1,1-Dichloropropene <2.1 ug/L 12/02/22 20:27 563-58-62.5 2.1 5 cis-1,3-Dichloropropene <1.8 ug/L 12/02/22 20:27 10061-01-52.5 1.8 5 trans-1,3-Dichloropropene <1.8 ug/L 12/02/22 20:27 10061-02-62.5 1.8 5 Diisopropyl ether <1.5 ug/L 12/02/22 20:27 108-20-32.5 1.5 5 Ethanol <361 ug/L 12/02/22 20:27 64-17-510003615 Ethylbenzene 153 ug/L 12/02/22 20:27 100-41-42.5 1.5 5 Ethyl-tert-butyl ether <16.2 ug/L 12/02/22 20:27 637-92-350.0 16.2 5 Hexachloro-1,3-butadiene <7.6 ug/L 12/02/22 20:27 87-68-310.0 7.6 5 Isopropylbenzene (Cumene)26.6 ug/L 12/02/22 20:27 98-82-82.5 1.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:MW-2 Lab ID:92639014002 Collected:11/30/22 12:30 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <9.8 ug/L 12/02/22 20:27 75-09-210.0 9.8 5 Methyl-tert-butyl ether <2.1 ug/L 12/02/22 20:27 1634-04-42.5 2.1 5 Naphthalene 114 ug/L 12/02/22 20:27 91-20-310.0 3.2 5 n-Propylbenzene 73.4 ug/L 12/02/22 20:27 103-65-12.5 1.7 5 Styrene <1.5 ug/L 12/02/22 20:27 100-42-52.5 1.5 5 1,1,1,2-Tetrachloroethane <1.6 ug/L 12/02/22 20:27 630-20-62.5 1.6 5 1,1,2,2-Tetrachloroethane <1.1 ug/L 12/02/22 20:27 79-34-52.5 1.1 5 Tetrachloroethene <1.5 ug/L 12/02/22 20:27 127-18-42.5 1.5 5 Toluene 427 ug/L 12/02/22 20:27 108-88-32.5 1.2 5 1,2,3-Trichlorobenzene <4.0 ug/L 12/02/22 20:27 87-61-610.0 4.0 5 1,2,4-Trichlorobenzene <3.2 ug/L 12/02/22 20:27 120-82-110.0 3.2 5 1,1,1-Trichloroethane <1.7 ug/L 12/02/22 20:27 71-55-62.5 1.7 5 1,1,2-Trichloroethane <1.6 ug/L 12/02/22 20:27 79-00-52.5 1.6 5 Trichloroethene <1.9 ug/L 12/02/22 20:27 79-01-62.5 1.9 5 Trichlorofluoromethane <1.5 ug/L 12/02/22 20:27 75-69-45.0 1.5 5 1,2,3-Trichloropropane <1.3 ug/L 12/02/22 20:27 96-18-42.5 1.3 5 1,2,4-Trimethylbenzene 607 ug/L 12/02/22 20:27 95-63-62.5 2.5 5 1,3,5-Trimethylbenzene 170 ug/L 12/02/22 20:27 108-67-82.5 1.7 5 Vinyl chloride <1.9 ug/L 12/02/22 20:27 75-01-45.0 1.9 5 Xylene (Total)869 ug/L 12/02/22 20:27 1330-20-75.0 1.7 5 m&p-Xylene 648 ug/L 12/02/22 20:27 179601-23-15.0 3.5 5 o-Xylene 221 ug/L 12/02/22 20:27 95-47-62.5 1.7 5 Surrogates 1,2-Dichloroethane-d4 (S)91 %12/02/22 20:27 17060-07-070-130 5 4-Bromofluorobenzene (S)99 %12/02/22 20:27 460-00-470-130 5 Toluene-d8 (S)106 %12/02/22 20:27 2037-26-570-130 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:MW-10D Lab ID:92639014003 Collected:11/30/22 12:00 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol <36.4 ug/L 12/02/22 17:26 75-85-410036.4 1 tert-Amylmethyl ether <9.2 ug/L 12/02/22 17:26 994-05-810.0 9.2 1 Benzene 0.83 ug/L 12/02/22 17:26 71-43-20.50 0.34 1 Bromobenzene <0.29 ug/L 12/02/22 17:26 108-86-10.50 0.29 1 Bromochloromethane <0.47 ug/L 12/02/22 17:26 74-97-50.50 0.47 1 Bromodichloromethane <0.31 ug/L 12/02/22 17:26 75-27-40.50 0.31 1 Bromoform <0.34 ug/L 12/02/22 17:26 75-25-20.50 0.34 1 Bromomethane <1.7 ug/L 12/02/22 17:26 74-83-95.0 1.7 1 tert-Butyl Alcohol <26.8 ug/L 12/02/22 17:26 75-65-050.0 26.8 1 n-Butylbenzene <0.49 ug/L 12/02/22 17:26 104-51-80.50 0.49 1 sec-Butylbenzene <0.40 ug/L 12/02/22 17:26 135-98-80.50 0.40 1 tert-Butylbenzene <0.32 ug/L 12/02/22 17:26 98-06-60.50 0.32 1 tert-Butyl Formate <29.4 ug/L 12/02/22 17:26 762-75-450.0 29.4 1 Carbon tetrachloride <0.33 ug/L 12/02/22 17:26 56-23-50.50 0.33 1 Chlorobenzene 0.33J ug/L 12/02/22 17:26 108-90-70.50 0.28 1 Chloroethane <0.65 ug/L 12/02/22 17:26 75-00-31.0 0.65 1 Chloroform <0.43 ug/L 12/02/22 17:26 67-66-30.50 0.43 1 Chloromethane <0.54 ug/L 12/02/22 17:26 74-87-31.0 0.54 1 2-Chlorotoluene <0.32 ug/L 12/02/22 17:26 95-49-80.50 0.32 1 4-Chlorotoluene <0.32 ug/L 12/02/22 17:26 106-43-40.50 0.32 1 1,2-Dibromo-3-chloropropane <0.34 ug/L 12/02/22 17:26 96-12-81.0 0.34 1 Dibromochloromethane <0.36 ug/L 12/02/22 17:26 124-48-10.50 0.36 1 1,2-Dibromoethane (EDB)<0.27 ug/L 12/02/22 17:26 106-93-40.50 0.27 1 Dibromomethane <0.39 ug/L 12/02/22 17:26 74-95-30.50 0.39 1 1,2-Dichlorobenzene <0.34 ug/L 12/02/22 17:26 95-50-10.50 0.34 1 1,3-Dichlorobenzene <0.34 ug/L 12/02/22 17:26 541-73-10.50 0.34 1 1,4-Dichlorobenzene <0.33 ug/L 12/02/22 17:26 106-46-70.50 0.33 1 Dichlorodifluoromethane <0.35 ug/L 12/02/22 17:26 75-71-80.50 0.35 1 1,1-Dichloroethane <0.37 ug/L 12/02/22 17:26 75-34-30.50 0.37 1 1,2-Dichloroethane <0.32 ug/L 12/02/22 17:26 107-06-20.50 0.32 1 1,1-Dichloroethene <0.35 ug/L 12/02/22 17:26 75-35-40.50 0.35 1 cis-1,2-Dichloroethene <0.38 ug/L 12/02/22 17:26 156-59-20.50 0.38 1 trans-1,2-Dichloroethene <0.40 ug/L 12/02/22 17:26 156-60-50.50 0.40 1 1,2-Dichloropropane <0.36 ug/L 12/02/22 17:26 78-87-50.50 0.36 1 1,3-Dichloropropane <0.28 ug/L 12/02/22 17:26 142-28-90.50 0.28 1 2,2-Dichloropropane <0.39 ug/L 12/02/22 17:26 594-20-70.50 0.39 1 1,1-Dichloropropene <0.43 ug/L 12/02/22 17:26 563-58-60.50 0.43 1 cis-1,3-Dichloropropene <0.36 ug/L 12/02/22 17:26 10061-01-50.50 0.36 1 trans-1,3-Dichloropropene <0.36 ug/L 12/02/22 17:26 10061-02-60.50 0.36 1 Diisopropyl ether <0.31 ug/L 12/02/22 17:26 108-20-30.50 0.31 1 Ethanol <72.2 ug/L 12/02/22 17:26 64-17-520072.2 1 Ethylbenzene <0.30 ug/L 12/02/22 17:26 100-41-40.50 0.30 1 Ethyl-tert-butyl ether <3.2 ug/L 12/02/22 17:26 637-92-310.0 3.2 1 Hexachloro-1,3-butadiene <1.5 ug/L 12/02/22 17:26 87-68-32.0 1.5 1 Isopropylbenzene (Cumene)<0.33 ug/L 12/02/22 17:26 98-82-80.50 0.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:MW-10D Lab ID:92639014003 Collected:11/30/22 12:00 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <2.0 ug/L 12/02/22 17:26 75-09-22.0 2.0 1 Methyl-tert-butyl ether <0.42 ug/L 12/02/22 17:26 1634-04-40.50 0.42 1 Naphthalene <0.64 ug/L 12/02/22 17:26 91-20-32.0 0.64 1 n-Propylbenzene <0.34 ug/L 12/02/22 17:26 103-65-10.50 0.34 1 Styrene <0.29 ug/L 12/02/22 17:26 100-42-50.50 0.29 1 1,1,1,2-Tetrachloroethane <0.31 ug/L 12/02/22 17:26 630-20-60.50 0.31 1 1,1,2,2-Tetrachloroethane <0.22 ug/L 12/02/22 17:26 79-34-50.50 0.22 1 Tetrachloroethene <0.29 ug/L 12/02/22 17:26 127-18-40.50 0.29 1 Toluene 0.69 ug/L 12/02/22 17:26 108-88-30.50 0.24 1 1,2,3-Trichlorobenzene <0.81 ug/L 12/02/22 17:26 87-61-62.0 0.81 1 1,2,4-Trichlorobenzene <0.64 ug/L 12/02/22 17:26 120-82-12.0 0.64 1 1,1,1-Trichloroethane <0.33 ug/L 12/02/22 17:26 71-55-60.50 0.33 1 1,1,2-Trichloroethane <0.32 ug/L 12/02/22 17:26 79-00-50.50 0.32 1 Trichloroethene <0.38 ug/L 12/02/22 17:26 79-01-60.50 0.38 1 Trichlorofluoromethane <0.30 ug/L 12/02/22 17:26 75-69-41.0 0.30 1 1,2,3-Trichloropropane <0.26 ug/L 12/02/22 17:26 96-18-40.50 0.26 1 1,2,4-Trimethylbenzene 0.84 ug/L 12/02/22 17:26 95-63-60.50 0.50 1 1,3,5-Trimethylbenzene 0.65 ug/L 12/02/22 17:26 108-67-80.50 0.33 1 Vinyl chloride 0.64J ug/L 12/02/22 17:26 75-01-41.0 0.39 1 Xylene (Total)0.47J ug/L 12/02/22 17:26 1330-20-71.0 0.34 1 m&p-Xylene <0.71 ug/L 12/02/22 17:26 179601-23-11.0 0.71 1 o-Xylene 0.47J ug/L 12/02/22 17:26 95-47-60.50 0.34 1 Surrogates 1,2-Dichloroethane-d4 (S)94 %12/02/22 17:26 17060-07-070-130 1 4-Bromofluorobenzene (S)103 %12/02/22 17:26 460-00-470-130 1 Toluene-d8 (S)108 %12/02/22 17:26 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:FB Lab ID:92639014004 Collected:11/30/22 12:00 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV tert-Amyl Alcohol <36.4 ug/L 12/01/22 18:50 75-85-410036.4 1 tert-Amylmethyl ether <9.2 ug/L 12/01/22 18:50 994-05-810.0 9.2 1 Benzene <0.34 ug/L 12/01/22 18:50 71-43-20.50 0.34 1 Bromobenzene <0.29 ug/L 12/01/22 18:50 108-86-10.50 0.29 1 Bromochloromethane <0.47 ug/L 12/01/22 18:50 74-97-50.50 0.47 1 Bromodichloromethane <0.31 ug/L 12/01/22 18:50 75-27-40.50 0.31 1 Bromoform <0.34 ug/L 12/01/22 18:50 75-25-20.50 0.34 1 Bromomethane <1.7 ug/L 12/01/22 18:50 74-83-95.0 1.7 1 tert-Butyl Alcohol <26.8 ug/L 12/01/22 18:50 75-65-050.0 26.8 1 n-Butylbenzene <0.49 ug/L 12/01/22 18:50 104-51-80.50 0.49 1 sec-Butylbenzene <0.40 ug/L 12/01/22 18:50 135-98-80.50 0.40 1 tert-Butylbenzene <0.32 ug/L 12/01/22 18:50 98-06-60.50 0.32 1 tert-Butyl Formate <29.4 ug/L 12/01/22 18:50 762-75-450.0 29.4 1 Carbon tetrachloride <0.33 ug/L 12/01/22 18:50 56-23-50.50 0.33 1 Chlorobenzene <0.28 ug/L 12/01/22 18:50 108-90-70.50 0.28 1 Chloroethane <0.65 ug/L 12/01/22 18:50 75-00-31.0 0.65 1 Chloroform <0.43 ug/L 12/01/22 18:50 67-66-30.50 0.43 1 Chloromethane <0.54 ug/L 12/01/22 18:50 74-87-31.0 0.54 1 2-Chlorotoluene <0.32 ug/L 12/01/22 18:50 95-49-80.50 0.32 1 4-Chlorotoluene <0.32 ug/L 12/01/22 18:50 106-43-40.50 0.32 1 1,2-Dibromo-3-chloropropane <0.34 ug/L 12/01/22 18:50 96-12-81.0 0.34 1 Dibromochloromethane <0.36 ug/L 12/01/22 18:50 124-48-10.50 0.36 1 1,2-Dibromoethane (EDB)<0.27 ug/L 12/01/22 18:50 106-93-40.50 0.27 1 Dibromomethane <0.39 ug/L 12/01/22 18:50 74-95-30.50 0.39 1 1,2-Dichlorobenzene <0.34 ug/L 12/01/22 18:50 95-50-10.50 0.34 1 1,3-Dichlorobenzene <0.34 ug/L 12/01/22 18:50 541-73-10.50 0.34 1 1,4-Dichlorobenzene <0.33 ug/L 12/01/22 18:50 106-46-70.50 0.33 1 Dichlorodifluoromethane <0.35 ug/L 12/01/22 18:50 75-71-80.50 0.35 1 1,1-Dichloroethane <0.37 ug/L 12/01/22 18:50 75-34-30.50 0.37 1 1,2-Dichloroethane <0.32 ug/L 12/01/22 18:50 107-06-20.50 0.32 1 1,1-Dichloroethene <0.35 ug/L 12/01/22 18:50 75-35-40.50 0.35 1 cis-1,2-Dichloroethene <0.38 ug/L 12/01/22 18:50 156-59-20.50 0.38 1 trans-1,2-Dichloroethene <0.40 ug/L 12/01/22 18:50 156-60-50.50 0.40 1 1,2-Dichloropropane <0.36 ug/L 12/01/22 18:50 78-87-50.50 0.36 1 1,3-Dichloropropane <0.28 ug/L 12/01/22 18:50 142-28-90.50 0.28 1 2,2-Dichloropropane <0.39 ug/L 12/01/22 18:50 594-20-70.50 0.39 1 1,1-Dichloropropene <0.43 ug/L 12/01/22 18:50 563-58-60.50 0.43 1 cis-1,3-Dichloropropene <0.36 ug/L 12/01/22 18:50 10061-01-50.50 0.36 1 trans-1,3-Dichloropropene <0.36 ug/L 12/01/22 18:50 10061-02-60.50 0.36 1 Diisopropyl ether <0.31 ug/L 12/01/22 18:50 108-20-30.50 0.31 1 Ethanol <72.2 ug/L 12/01/22 18:50 64-17-520072.2 1 Ethylbenzene <0.30 ug/L 12/01/22 18:50 100-41-40.50 0.30 1 Ethyl-tert-butyl ether <3.2 ug/L 12/01/22 18:50 637-92-310.0 3.2 1 Hexachloro-1,3-butadiene <1.5 ug/L 12/01/22 18:50 87-68-32.0 1.5 1 Isopropylbenzene (Cumene)<0.33 ug/L 12/01/22 18:50 98-82-80.50 0.33 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 27 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Sample:FB Lab ID:92639014004 Collected:11/30/22 12:00 Received:11/30/22 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL Analytical Method: SM 6200B Pace Analytical Services - Charlotte 6200B MSV Methylene Chloride <2.0 ug/L 12/01/22 18:50 75-09-22.0 2.0 1 Methyl-tert-butyl ether <0.42 ug/L 12/01/22 18:50 1634-04-40.50 0.42 1 Naphthalene <0.64 ug/L 12/01/22 18:50 91-20-32.0 0.64 1 n-Propylbenzene <0.34 ug/L 12/01/22 18:50 103-65-10.50 0.34 1 Styrene <0.29 ug/L 12/01/22 18:50 100-42-50.50 0.29 1 1,1,1,2-Tetrachloroethane <0.31 ug/L 12/01/22 18:50 630-20-60.50 0.31 1 1,1,2,2-Tetrachloroethane <0.22 ug/L 12/01/22 18:50 79-34-50.50 0.22 1 Tetrachloroethene <0.29 ug/L 12/01/22 18:50 127-18-40.50 0.29 1 Toluene 0.38J ug/L 12/01/22 18:50 108-88-30.50 0.24 1 1,2,3-Trichlorobenzene <0.81 ug/L 12/01/22 18:50 87-61-62.0 0.81 1 1,2,4-Trichlorobenzene <0.64 ug/L 12/01/22 18:50 120-82-12.0 0.64 1 1,1,1-Trichloroethane <0.33 ug/L 12/01/22 18:50 71-55-60.50 0.33 1 1,1,2-Trichloroethane <0.32 ug/L 12/01/22 18:50 79-00-50.50 0.32 1 Trichloroethene <0.38 ug/L 12/01/22 18:50 79-01-60.50 0.38 1 Trichlorofluoromethane <0.30 ug/L 12/01/22 18:50 75-69-41.0 0.30 1 1,2,3-Trichloropropane <0.26 ug/L 12/01/22 18:50 96-18-40.50 0.26 1 1,2,4-Trimethylbenzene <0.50 ug/L 12/01/22 18:50 95-63-60.50 0.50 1 1,3,5-Trimethylbenzene <0.33 ug/L 12/01/22 18:50 108-67-80.50 0.33 1 Vinyl chloride <0.39 ug/L 12/01/22 18:50 75-01-41.0 0.39 1 Xylene (Total)<0.34 ug/L 12/01/22 18:50 1330-20-71.0 0.34 1 m&p-Xylene <0.71 ug/L 12/01/22 18:50 179601-23-11.0 0.71 1 o-Xylene <0.34 ug/L 12/01/22 18:50 95-47-60.50 0.34 1 Surrogates 1,2-Dichloroethane-d4 (S)84 %12/01/22 18:50 17060-07-0 C070-130 1 4-Bromofluorobenzene (S)95 %12/01/22 18:50 460-00-470-130 1 Toluene-d8 (S)100 %12/01/22 18:50 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 740169 SM 6200B SM 6200B 6200B MSV Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92639014004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3851045 Associated Lab Samples:92639014004 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 12/01/22 18:140.31 1,1,1-Trichloroethane ug/L <0.33 0.50 12/01/22 18:140.33 1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 12/01/22 18:140.22 1,1,2-Trichloroethane ug/L <0.32 0.50 12/01/22 18:140.32 1,1-Dichloroethane ug/L <0.37 0.50 12/01/22 18:140.37 1,1-Dichloroethene ug/L <0.35 0.50 12/01/22 18:140.35 1,1-Dichloropropene ug/L <0.43 0.50 12/01/22 18:140.43 1,2,3-Trichlorobenzene ug/L <0.81 2.0 12/01/22 18:140.81 1,2,3-Trichloropropane ug/L <0.26 0.50 12/01/22 18:140.26 1,2,4-Trichlorobenzene ug/L <0.64 2.0 12/01/22 18:140.64 1,2,4-Trimethylbenzene ug/L <0.50 0.50 12/01/22 18:140.50 1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 12/01/22 18:140.34 1,2-Dibromoethane (EDB)ug/L <0.27 0.50 12/01/22 18:140.27 1,2-Dichlorobenzene ug/L <0.34 0.50 12/01/22 18:140.34 1,2-Dichloroethane ug/L <0.32 0.50 12/01/22 18:140.32 1,2-Dichloropropane ug/L <0.36 0.50 12/01/22 18:140.36 1,3,5-Trimethylbenzene ug/L <0.33 0.50 12/01/22 18:140.33 1,3-Dichlorobenzene ug/L <0.34 0.50 12/01/22 18:140.34 1,3-Dichloropropane ug/L <0.28 0.50 12/01/22 18:140.28 1,4-Dichlorobenzene ug/L <0.33 0.50 12/01/22 18:140.33 2,2-Dichloropropane ug/L <0.39 0.50 12/01/22 18:140.39 2-Chlorotoluene ug/L <0.32 0.50 12/01/22 18:140.32 4-Chlorotoluene ug/L <0.32 0.50 12/01/22 18:140.32 Benzene ug/L <0.34 0.50 12/01/22 18:140.34 Bromobenzene ug/L <0.29 0.50 12/01/22 18:140.29 Bromochloromethane ug/L <0.47 0.50 12/01/22 18:140.47 Bromodichloromethane ug/L <0.31 0.50 12/01/22 18:140.31 Bromoform ug/L <0.34 0.50 12/01/22 18:140.34 Bromomethane ug/L <1.7 5.0 12/01/22 18:141.7 Carbon tetrachloride ug/L <0.33 0.50 12/01/22 18:140.33 Chlorobenzene ug/L <0.28 0.50 12/01/22 18:140.28 Chloroethane ug/L <0.65 1.0 12/01/22 18:140.65 Chloroform ug/L <0.43 0.50 12/01/22 18:140.43 Chloromethane ug/L <0.54 1.0 12/01/22 18:140.54 cis-1,2-Dichloroethene ug/L <0.38 0.50 12/01/22 18:140.38 cis-1,3-Dichloropropene ug/L <0.36 0.50 12/01/22 18:140.36 Dibromochloromethane ug/L <0.36 0.50 12/01/22 18:140.36 Dibromomethane ug/L <0.39 0.50 12/01/22 18:140.39 Dichlorodifluoromethane ug/L <0.35 0.50 12/01/22 18:140.35 Diisopropyl ether ug/L <0.31 0.50 12/01/22 18:140.31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3851045 Associated Lab Samples:92639014004 Matrix:Water AnalyzedMDL Ethanol ug/L <72.2 200 12/01/22 18:1472.2 Ethyl-tert-butyl ether ug/L <3.2 10.0 12/01/22 18:143.2 Ethylbenzene ug/L <0.30 0.50 12/01/22 18:140.30 Hexachloro-1,3-butadiene ug/L <1.5 2.0 12/01/22 18:141.5 Isopropylbenzene (Cumene)ug/L <0.33 0.50 12/01/22 18:140.33 m&p-Xylene ug/L <0.71 1.0 12/01/22 18:140.71 Methyl-tert-butyl ether ug/L <0.42 0.50 12/01/22 18:140.42 Methylene Chloride ug/L <2.0 2.0 12/01/22 18:142.0 n-Butylbenzene ug/L <0.49 0.50 12/01/22 18:140.49 n-Propylbenzene ug/L <0.34 0.50 12/01/22 18:140.34 Naphthalene ug/L <0.64 2.0 12/01/22 18:140.64 o-Xylene ug/L <0.34 0.50 12/01/22 18:140.34 sec-Butylbenzene ug/L <0.40 0.50 12/01/22 18:140.40 Styrene ug/L <0.29 0.50 12/01/22 18:140.29 tert-Amyl Alcohol ug/L <36.4 100 12/01/22 18:1436.4 tert-Amylmethyl ether ug/L <9.2 10.0 12/01/22 18:149.2 tert-Butyl Alcohol ug/L <26.8 50.0 12/01/22 18:1426.8 tert-Butyl Formate ug/L <29.4 50.0 12/01/22 18:1429.4 tert-Butylbenzene ug/L <0.32 0.50 12/01/22 18:140.32 Tetrachloroethene ug/L <0.29 0.50 12/01/22 18:140.29 Toluene ug/L <0.24 0.50 12/01/22 18:140.24 trans-1,2-Dichloroethene ug/L <0.40 0.50 12/01/22 18:140.40 trans-1,3-Dichloropropene ug/L <0.36 0.50 12/01/22 18:140.36 Trichloroethene ug/L <0.38 0.50 12/01/22 18:140.38 Trichlorofluoromethane ug/L <0.30 1.0 12/01/22 18:140.30 Vinyl chloride ug/L <0.39 1.0 12/01/22 18:140.39 Xylene (Total)ug/L <0.34 1.0 12/01/22 18:140.34 1,2-Dichloroethane-d4 (S)%83 70-130 12/01/22 18:14 4-Bromofluorobenzene (S)%96 70-130 12/01/22 18:14 Toluene-d8 (S)%98 70-130 12/01/22 18:14 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3851046LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.550 101 60-140 1,1,1-Trichloroethane ug/L 46.550 93 60-140 1,1,2,2-Tetrachloroethane ug/L 48.650 97 60-140 1,1,2-Trichloroethane ug/L 51.150 102 60-140 1,1-Dichloroethane ug/L 45.550 91 60-140 1,1-Dichloroethene ug/L 49.850 100 60-140 1,1-Dichloropropene ug/L 50.650 101 60-140 1,2,3-Trichlorobenzene ug/L 54.450 109 60-140 1,2,3-Trichloropropane ug/L 45.850 92 60-140 1,2,4-Trichlorobenzene ug/L 53.050 106 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3851046LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trimethylbenzene ug/L 47.750 95 60-140 1,2-Dibromo-3-chloropropane ug/L 52.850 106 60-140 1,2-Dibromoethane (EDB)ug/L 52.350 105 60-140 1,2-Dichlorobenzene ug/L 50.750 101 60-140 1,2-Dichloroethane ug/L 42.750 85 60-140 1,2-Dichloropropane ug/L 50.250 100 60-140 1,3,5-Trimethylbenzene ug/L 47.250 94 60-140 1,3-Dichlorobenzene ug/L 49.850 100 60-140 1,3-Dichloropropane ug/L 48.950 98 60-140 1,4-Dichlorobenzene ug/L 48.550 97 60-140 2,2-Dichloropropane ug/L 43.450 87 60-140 2-Chlorotoluene ug/L 46.550 93 60-140 4-Chlorotoluene ug/L 45.950 92 60-140 Benzene ug/L 48.550 97 60-140 Bromobenzene ug/L 51.150 102 60-140 Bromochloromethane ug/L 55.050 110 60-140 Bromodichloromethane ug/L 46.950 94 60-140 Bromoform ug/L 51.150 102 60-140 Bromomethane ug/L 43.750 87 60-140 Carbon tetrachloride ug/L 44.550 89 60-140 Chlorobenzene ug/L 50.550 101 60-140 Chloroethane ug/L 45.850 92 60-140 Chloroform ug/L 44.950 90 60-140 Chloromethane ug/L 54.950 110 60-140 cis-1,2-Dichloroethene ug/L 44.950 90 60-140 cis-1,3-Dichloropropene ug/L 49.150 98 60-140 Dibromochloromethane ug/L 50.350 101 60-140 Dibromomethane ug/L 57.950 116 60-140 Dichlorodifluoromethane ug/L 53.550 107 60-140 Diisopropyl ether ug/L 45.950 92 60-140 Ethanol ug/L 18002000 90 60-140 Ethyl-tert-butyl ether ug/L 81.0100 81 60-140 Ethylbenzene ug/L 47.250 94 60-140 Hexachloro-1,3-butadiene ug/L 49.750 99 60-140 Isopropylbenzene (Cumene)ug/L 47.150 94 60-140 m&p-Xylene ug/L 94.7100 95 60-140 Methyl-tert-butyl ether ug/L 49.450 99 60-140 Methylene Chloride ug/L 68.050 136 60-140 n-Butylbenzene ug/L 45.750 91 60-140 n-Propylbenzene ug/L 45.450 91 60-140 Naphthalene ug/L 57.150 114 60-140 o-Xylene ug/L 49.250 98 60-140 sec-Butylbenzene ug/L 45.450 91 60-140 Styrene ug/L 49.650 99 60-140 tert-Amyl Alcohol ug/L 8841000 88 60-140 tert-Amylmethyl ether ug/L 86.0100 86 60-140 tert-Butyl Alcohol ug/L 657500 131 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3851046LABORATORY CONTROL SAMPLE: LCSSpike tert-Butyl Formate ug/L 318400 80 60-140 tert-Butylbenzene ug/L 40.750 81 60-140 Tetrachloroethene ug/L 52.350 105 60-140 Toluene ug/L 47.650 95 60-140 trans-1,2-Dichloroethene ug/L 48.150 96 60-140 trans-1,3-Dichloropropene ug/L 47.550 95 60-140 Trichloroethene ug/L 53.950 108 60-140 Trichlorofluoromethane ug/L 41.250 82 60-140 Vinyl chloride ug/L 53.250 106 60-140 Xylene (Total)ug/L 144150 96 60-140 1,2-Dichloroethane-d4 (S)%85 70-130 4-Bromofluorobenzene (S)%95 70-130 Toluene-d8 (S)%97 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 3851047MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92638618003 3851048 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 20 118 60-140115 3 3020ND23.7 23.1 1,1,1-Trichloroethane ug/L 20 111 60-140113 2 3020ND22.2 22.7 1,1,2,2-Tetrachloroethane ug/L 20 112 60-140112 0 3020ND22.4 22.4 1,1,2-Trichloroethane ug/L 20 119 60-140121 1 3020ND23.8 24.1 1,1-Dichloroethane ug/L 20 110 60-140109 1 3020ND22.0 21.8 1,1-Dichloroethene ug/L 20 123 60-140121 1 3020ND24.6 24.3 1,1-Dichloropropene ug/L 20 122 60-140123 1 3020ND24.5 24.6 1,2,3-Trichlorobenzene ug/L 20 118 60-140128 8 3020ND23.6 25.6 1,2,3-Trichloropropane ug/L 20 105 60-140106 1 3020ND21.0 21.3 1,2,4-Trichlorobenzene ug/L 20 118 60-140121 3 3020ND23.6 24.2 1,2,4-Trimethylbenzene ug/L 20 114 60-140114 0 3020ND22.9 22.8 1,2-Dibromo-3- chloropropane ug/L 20 111 60-140115 4 3020ND22.1 23.1 1,2-Dibromoethane (EDB)ug/L 20 120 60-140119 1 3020ND24.1 23.7 1,2-Dichlorobenzene ug/L 20 119 60-140119 0 3020ND23.8 23.8 1,2-Dichloroethane ug/L 20 101 60-140100 1 3020ND20.3 20.1 1,2-Dichloropropane ug/L 20 119 60-140120 1 3020ND23.7 23.9 1,3,5-Trimethylbenzene ug/L 20 113 60-140113 1 3020ND22.7 22.5 1,3-Dichlorobenzene ug/L 20 119 60-140120 1 3020ND23.8 24.0 1,3-Dichloropropane ug/L 20 113 60-140114 0 3020ND22.7 22.8 1,4-Dichlorobenzene ug/L 20 115 60-140114 1 3020ND23.0 22.8 2,2-Dichloropropane ug/L 20 108 60-140108 0 3020ND21.6 21.5 2-Chlorotoluene ug/L 20 112 60-140113 0 3020ND22.5 22.5 4-Chlorotoluene ug/L 20 110 60-140110 0 3020ND21.9 21.9 Benzene ug/L 20 118 60-140118 0 3020ND23.5 23.6 Bromobenzene ug/L 20 121 60-140122 1 3020ND24.2 24.5 Bromochloromethane ug/L 20 127 60-140127 1 3020ND25.3 25.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3851047MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92638618003 3851048 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Bromodichloromethane ug/L 20 109 60-140108 0 3020ND21.7 21.7 Bromoform ug/L 20 111 60-140110 1 3020ND22.2 22.0 Bromomethane ug/L 20 85 60-14097 14 3020ND17.0 19.5 Carbon tetrachloride ug/L 20 110 60-140109 0 3020ND21.9 21.9 Chlorobenzene ug/L 20 121 60-140120 1 3020ND24.3 24.0 Chloroethane ug/L 20 137 60-140133 3 3020ND27.5 26.7 Chloroform ug/L 20 103 60-140107 3 3020ND20.6 21.3 Chloromethane ug/L 20 124 60-140129 3 3020ND24.9 25.7 cis-1,2-Dichloroethene ug/L 20 108 60-140108 0 3020ND21.5 21.5 cis-1,3-Dichloropropene ug/L 20 110 60-140111 0 3020ND22.0 22.1 Dibromochloromethane ug/L 20 113 60-140112 2 3020ND22.7 22.3 Dibromomethane ug/L 20 134 60-140134 0 3020ND26.8 26.9 Dichlorodifluoromethane ug/L 20 136 60-140135 1 3020ND27.3 27.0 Diisopropyl ether ug/L 20 101 60-140103 1 3020ND20.2 20.5 Ethanol ug/L 800 107 60-140113 6 30800ND856906 Ethyl-tert-butyl ether ug/L 40 85 60-14086 1 3040ND34.0 34.4 Ethylbenzene ug/L 20 114 60-140114 1 3020ND22.9 22.7 Hexachloro-1,3-butadiene ug/L 20 120 60-140122 1 3020ND24.1 24.3 Isopropylbenzene (Cumene)ug/L 20 114 60-140113 1 3020ND22.8 22.5 m&p-Xylene ug/L 40 116 60-140114 2 3040ND46.6 45.7 Methyl-tert-butyl ether ug/L 20 104 60-140105 1 3020ND20.9 21.0 Methylene Chloride ug/L 20 90 60-14088 2 3020ND18.0 17.6 n-Butylbenzene ug/L 20 109 60-140109 0 3020ND21.7 21.8 n-Propylbenzene ug/L 20 111 60-140110 1 3020ND22.3 22.0 Naphthalene ug/L 20 119 60-140132 10 3020ND23.8 26.3 o-Xylene ug/L 20 119 60-140117 2 3020ND23.8 23.3 sec-Butylbenzene ug/L 20 112 60-140111 1 3020ND22.4 22.3 Styrene ug/L 20 115 60-140113 1 3020ND23.0 22.7 tert-Amyl Alcohol ug/L 400 92 60-14098 7 30400ND366391 tert-Amylmethyl ether ug/L 40 93 60-14093 0 3040ND37.2 37.2 tert-Butyl Alcohol ug/L M120014960-140152 2 30200ND298305 tert-Butyl Formate ug/L M11605460-14045 18 30160ND87.1 72.8 tert-Butylbenzene ug/L 20 99 60-14099 1 3020ND19.9 19.7 Tetrachloroethene ug/L 20 129 60-140127 2 3020ND25.8 25.4 Toluene ug/L 20 116 60-140115 0 3020ND23.2 23.1 trans-1,2-Dichloroethene ug/L 20 115 60-140115 0 3020ND23.0 23.0 trans-1,3-Dichloropropene ug/L 20 107 60-140108 1 3020ND21.4 21.5 Trichloroethene ug/L 20 129 60-140131 1 3020ND25.9 26.1 Trichlorofluoromethane ug/L 20 113 60-140111 2 3020ND22.5 22.1 Vinyl chloride ug/L 20 127 60-140130 2 3020ND25.4 26.0 Xylene (Total)ug/L 60 117 60-140115 2 3060ND70.4 69.0 1,2-Dichloroethane-d4 (S)%83 70-13082 4-Bromofluorobenzene (S)%95 70-13095 Toluene-d8 (S)%97 70-13097 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 740838 SM 6200B SM 6200B 6200B MSV Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92639014001, 92639014002, 92639014003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3854143 Associated Lab Samples:92639014001, 92639014002, 92639014003 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L <0.31 0.50 12/02/22 13:130.31 1,1,1-Trichloroethane ug/L <0.33 0.50 12/02/22 13:130.33 1,1,2,2-Tetrachloroethane ug/L <0.22 0.50 12/02/22 13:130.22 1,1,2-Trichloroethane ug/L <0.32 0.50 12/02/22 13:130.32 1,1-Dichloroethane ug/L <0.37 0.50 12/02/22 13:130.37 1,1-Dichloroethene ug/L <0.35 0.50 12/02/22 13:130.35 1,1-Dichloropropene ug/L <0.43 0.50 12/02/22 13:130.43 1,2,3-Trichlorobenzene ug/L <0.81 2.0 12/02/22 13:130.81 1,2,3-Trichloropropane ug/L <0.26 0.50 12/02/22 13:130.26 1,2,4-Trichlorobenzene ug/L <0.64 2.0 12/02/22 13:130.64 1,2,4-Trimethylbenzene ug/L <0.50 0.50 12/02/22 13:130.50 1,2-Dibromo-3-chloropropane ug/L <0.34 1.0 12/02/22 13:130.34 1,2-Dibromoethane (EDB)ug/L <0.27 0.50 12/02/22 13:130.27 1,2-Dichlorobenzene ug/L <0.34 0.50 12/02/22 13:130.34 1,2-Dichloroethane ug/L <0.32 0.50 12/02/22 13:130.32 1,2-Dichloropropane ug/L <0.36 0.50 12/02/22 13:130.36 1,3,5-Trimethylbenzene ug/L <0.33 0.50 12/02/22 13:130.33 1,3-Dichlorobenzene ug/L <0.34 0.50 12/02/22 13:130.34 1,3-Dichloropropane ug/L <0.28 0.50 12/02/22 13:130.28 1,4-Dichlorobenzene ug/L <0.33 0.50 12/02/22 13:130.33 2,2-Dichloropropane ug/L <0.39 0.50 12/02/22 13:130.39 2-Chlorotoluene ug/L <0.32 0.50 12/02/22 13:130.32 4-Chlorotoluene ug/L <0.32 0.50 12/02/22 13:130.32 Benzene ug/L <0.34 0.50 12/02/22 13:130.34 Bromobenzene ug/L <0.29 0.50 12/02/22 13:130.29 Bromochloromethane ug/L <0.47 0.50 12/02/22 13:130.47 Bromodichloromethane ug/L <0.31 0.50 12/02/22 13:130.31 Bromoform ug/L <0.34 0.50 12/02/22 13:130.34 Bromomethane ug/L <1.7 5.0 12/02/22 13:131.7 Carbon tetrachloride ug/L <0.33 0.50 12/02/22 13:130.33 Chlorobenzene ug/L <0.28 0.50 12/02/22 13:130.28 Chloroethane ug/L <0.65 1.0 12/02/22 13:130.65 Chloroform ug/L <0.43 0.50 12/02/22 13:130.43 Chloromethane ug/L <0.54 1.0 12/02/22 13:130.54 cis-1,2-Dichloroethene ug/L <0.38 0.50 12/02/22 13:130.38 cis-1,3-Dichloropropene ug/L <0.36 0.50 12/02/22 13:130.36 Dibromochloromethane ug/L <0.36 0.50 12/02/22 13:130.36 Dibromomethane ug/L <0.39 0.50 12/02/22 13:130.39 Dichlorodifluoromethane ug/L <0.35 0.50 12/02/22 13:130.35 Diisopropyl ether ug/L <0.31 0.50 12/02/22 13:130.31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3854143 Associated Lab Samples:92639014001, 92639014002, 92639014003 Matrix:Water AnalyzedMDL Ethanol ug/L <72.2 200 12/02/22 13:1372.2 Ethyl-tert-butyl ether ug/L <3.2 10.0 12/02/22 13:133.2 Ethylbenzene ug/L <0.30 0.50 12/02/22 13:130.30 Hexachloro-1,3-butadiene ug/L <1.5 2.0 12/02/22 13:131.5 Isopropylbenzene (Cumene)ug/L <0.33 0.50 12/02/22 13:130.33 m&p-Xylene ug/L <0.71 1.0 12/02/22 13:130.71 Methyl-tert-butyl ether ug/L <0.42 0.50 12/02/22 13:130.42 Methylene Chloride ug/L <2.0 2.0 12/02/22 13:132.0 n-Butylbenzene ug/L <0.49 0.50 12/02/22 13:130.49 n-Propylbenzene ug/L <0.34 0.50 12/02/22 13:130.34 Naphthalene ug/L <0.64 2.0 12/02/22 13:130.64 o-Xylene ug/L <0.34 0.50 12/02/22 13:130.34 sec-Butylbenzene ug/L <0.40 0.50 12/02/22 13:130.40 Styrene ug/L <0.29 0.50 12/02/22 13:130.29 tert-Amyl Alcohol ug/L <36.4 100 12/02/22 13:1336.4 tert-Amylmethyl ether ug/L <9.2 10.0 12/02/22 13:139.2 tert-Butyl Alcohol ug/L <26.8 50.0 12/02/22 13:1326.8 tert-Butyl Formate ug/L <29.4 50.0 12/02/22 13:1329.4 tert-Butylbenzene ug/L <0.32 0.50 12/02/22 13:130.32 Tetrachloroethene ug/L <0.29 0.50 12/02/22 13:130.29 Toluene ug/L <0.24 0.50 12/02/22 13:130.24 trans-1,2-Dichloroethene ug/L <0.40 0.50 12/02/22 13:130.40 trans-1,3-Dichloropropene ug/L <0.36 0.50 12/02/22 13:130.36 Trichloroethene ug/L <0.38 0.50 12/02/22 13:130.38 Trichlorofluoromethane ug/L <0.30 1.0 12/02/22 13:130.30 Vinyl chloride ug/L <0.39 1.0 12/02/22 13:130.39 Xylene (Total)ug/L <0.34 1.0 12/02/22 13:130.34 1,2-Dichloroethane-d4 (S)%92 70-130 12/02/22 13:13 4-Bromofluorobenzene (S)%101 70-130 12/02/22 13:13 Toluene-d8 (S)%106 70-130 12/02/22 13:13 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3854144LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 58.850 118 60-140 1,1,1-Trichloroethane ug/L 59.050 118 60-140 1,1,2,2-Tetrachloroethane ug/L 60.350 121 60-140 1,1,2-Trichloroethane ug/L 56.550 113 60-140 1,1-Dichloroethane ug/L 56.250 112 60-140 1,1-Dichloroethene ug/L 55.250 110 60-140 1,1-Dichloropropene ug/L 53.650 107 60-140 1,2,3-Trichlorobenzene ug/L 59.150 118 60-140 1,2,3-Trichloropropane ug/L 57.050 114 60-140 1,2,4-Trichlorobenzene ug/L 57.250 114 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3854144LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trimethylbenzene ug/L 54.850 110 60-140 1,2-Dibromo-3-chloropropane ug/L 60.450 121 60-140 1,2-Dibromoethane (EDB)ug/L 53.650 107 60-140 1,2-Dichlorobenzene ug/L 54.050 108 60-140 1,2-Dichloroethane ug/L 60.950 122 60-140 1,2-Dichloropropane ug/L 57.550 115 60-140 1,3,5-Trimethylbenzene ug/L 54.350 109 60-140 1,3-Dichlorobenzene ug/L 54.950 110 60-140 1,3-Dichloropropane ug/L 59.250 118 60-140 1,4-Dichlorobenzene ug/L 53.950 108 60-140 2,2-Dichloropropane ug/L 60.450 121 60-140 2-Chlorotoluene ug/L 53.950 108 60-140 4-Chlorotoluene ug/L 55.050 110 60-140 Benzene ug/L 53.850 108 60-140 Bromobenzene ug/L 54.050 108 60-140 Bromochloromethane ug/L 63.250 126 60-140 Bromodichloromethane ug/L 54.450 109 60-140 Bromoform ug/L 61.450 123 60-140 Bromomethane ug/L 59.650 119 60-140 Carbon tetrachloride ug/L 52.750 105 60-140 Chlorobenzene ug/L 54.650 109 60-140 Chloroethane ug/L 59.850 120 60-140 Chloroform ug/L 58.750 117 60-140 Chloromethane ug/L 65.650 131 60-140 cis-1,2-Dichloroethene ug/L 59.150 118 60-140 cis-1,3-Dichloropropene ug/L 64.450 129 60-140 Dibromochloromethane ug/L 61.050 122 60-140 Dibromomethane ug/L 54.450 109 60-140 Dichlorodifluoromethane ug/L 51.550 103 60-140 Diisopropyl ether ug/L 54.750 109 60-140 Ethanol ug/L 26102000 131 60-140 Ethyl-tert-butyl ether ug/L 127100 127 60-140 Ethylbenzene ug/L 54.450 109 60-140 Hexachloro-1,3-butadiene ug/L 51.250 102 60-140 Isopropylbenzene (Cumene)ug/L 52.050 104 60-140 m&p-Xylene ug/L 106100 106 60-140 Methyl-tert-butyl ether ug/L 52.750 105 60-140 Methylene Chloride ug/L 54.750 109 60-140 n-Butylbenzene ug/L 55.650 111 60-140 n-Propylbenzene ug/L 52.850 106 60-140 Naphthalene ug/L 61.950 124 60-140 o-Xylene ug/L 54.250 108 60-140 sec-Butylbenzene ug/L 52.250 104 60-140 Styrene ug/L 57.350 115 60-140 tert-Amyl Alcohol ug/L 10901000 109 60-140 tert-Amylmethyl ether ug/L 119100 119 60-140 tert-Butyl Alcohol ug/L 523500 105 60-140 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3854144LABORATORY CONTROL SAMPLE: LCSSpike tert-Butyl Formate ug/L 435400 109 60-140 tert-Butylbenzene ug/L 44.750 89 60-140 Tetrachloroethene ug/L 51.550 103 60-140 Toluene ug/L 51.050 102 60-140 trans-1,2-Dichloroethene ug/L 57.450 115 60-140 trans-1,3-Dichloropropene ug/L 55.450 111 60-140 Trichloroethene ug/L 60.350 121 60-140 Trichlorofluoromethane ug/L 49.350 99 60-140 Vinyl chloride ug/L 66.450 133 60-140 Xylene (Total)ug/L 160150 107 60-140 1,2-Dichloroethane-d4 (S)%105 70-130 4-Bromofluorobenzene (S)%100 70-130 Toluene-d8 (S)%97 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 3854145MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92638864006 3854146 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 400 103 60-140110 7 30400ND412442 1,1,1-Trichloroethane ug/L 400 114 60-140127 11 30400ND458509 1,1,2,2-Tetrachloroethane ug/L 400 114 60-140128 11 30400ND457512 1,1,2-Trichloroethane ug/L 400 111 60-140118 6 30400ND445473 1,1-Dichloroethane ug/L 400 120 60-140130 9 30400ND478521 1,1-Dichloroethene ug/L 400 122 60-140129 5 30400ND490514 1,1-Dichloropropene ug/L 400 115 60-140124 8 30400ND458496 1,2,3-Trichlorobenzene ug/L 400 100 60-140111 11 30400ND398446 1,2,3-Trichloropropane ug/L 400 111 60-140123 10 30400ND442490 1,2,4-Trichlorobenzene ug/L 400 97 60-140108 11 30400ND389432 1,2,4-Trimethylbenzene ug/L 400 85 60-140133 9 30400178021202310 1,2-Dibromo-3- chloropropane ug/L 400 99 60-140114 14 30400ND398456 1,2-Dibromoethane (EDB)ug/L 400 99 60-140107 7 30400ND397426 1,2-Dichlorobenzene ug/L 400 101 60-140109 8 30400ND403436 1,2-Dichloroethane ug/L 400 116 60-140125 7 30400ND465500 1,2-Dichloropropane ug/L 400 115 60-140126 9 30400ND461503 1,3,5-Trimethylbenzene ug/L 400 107 60-140122 6 304005199491010 1,3-Dichlorobenzene ug/L 400 103 60-140109 6 30400ND412437 1,3-Dichloropropane ug/L 400 109 60-140123 12 30400ND435493 1,4-Dichlorobenzene ug/L 400 101 60-140107 6 30400ND402428 2,2-Dichloropropane ug/L 400 111 60-140122 10 30400ND443488 2-Chlorotoluene ug/L 400 108 60-140114 6 30400ND432458 4-Chlorotoluene ug/L 400 101 60-140110 8 30400ND405440 Benzene ug/L 400 113 60-140119 5 30400ND453477 Bromobenzene ug/L 400 103 60-140106 3 30400ND411424 Bromochloromethane ug/L 400 122 60-140137 11 30400ND490548 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 27 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 3854145MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92638864006 3854146 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Bromodichloromethane ug/L 400 105 60-140111 5 30400ND420444 Bromoform ug/L 400 103 60-140113 10 30400ND410454 Bromomethane ug/L 400 91 60-140112 21 30400ND362447 Carbon tetrachloride ug/L 400 109 60-140118 7 30400ND437471 Chlorobenzene ug/L 400 106 60-140111 4 30400ND425444 Chloroethane ug/L M140013460-140145 8 30400ND536580 Chloroform ug/L 400 114 60-140120 5 30400ND458481 Chloromethane ug/L M140012160-140149 21 30400ND483596 cis-1,2-Dichloroethene ug/L 400 122 60-140132 8 30400ND489527 cis-1,3-Dichloropropene ug/L 400 122 60-140128 5 30400ND490513 Dibromochloromethane ug/L 400 104 60-140118 13 30400ND416472 Dibromomethane ug/L 400 107 60-140111 4 30400ND430446 Dichlorodifluoromethane ug/L 400 93 60-140109 16 30400ND373437 Diisopropyl ether ug/L 400 111 60-140120 8 30400ND444481 Ethanol ug/L 16000 121 60-140132 9 3016000ND1930021200 Ethyl-tert-butyl ether ug/L 800 116 60-140123 6 30800ND929986 Ethylbenzene ug/L 400 109 60-140117 5 3040096.1 533 562 Hexachloro-1,3-butadiene ug/L 400 91 60-14099 9 30400ND363397 Isopropylbenzene (Cumene)ug/L 400 100 60-140111 9 3040036.6 436 480 m&p-Xylene ug/L 800 103 60-140117 9 3080036211901300 Methyl-tert-butyl ether ug/L 400 99 60-140109 9 30400ND398436 Methylene Chloride ug/L 400 116 60-140127 9 30400ND465507 n-Butylbenzene ug/L 400 125 60-140130 4 30400ND501520 n-Propylbenzene ug/L 400 103 60-140108 4 3040051.4 463 483 Naphthalene ug/L 400 98 60-140117 14 30400101495571 o-Xylene ug/L 400 105 60-140118 11 304006.9J 427 477 sec-Butylbenzene ug/L 400 104 60-140111 6 30400ND416442 Styrene ug/L 400 109 60-140120 10 30400ND435480 tert-Amyl Alcohol ug/L 8000 100 60-140110 10 308000ND79608780 tert-Amylmethyl ether ug/L 800 109 60-140117 7 30800ND875936 tert-Butyl Alcohol ug/L 4000 91 60-140104 14 304000ND36404170 tert-Butyl Formate ug/L 3200 101 60-140112 11 303200ND32303590 tert-Butylbenzene ug/L 400 85 60-14093 9 30400ND338370 Tetrachloroethene ug/L 400 99 60-140110 10 30400ND398441 Toluene ug/L 400 103 60-140115 10 304009.3J 423 469 trans-1,2-Dichloroethene ug/L 400 121 60-140129 6 30400ND483515 trans-1,3-Dichloropropene ug/L 400 101 60-140114 12 30400ND403455 Trichloroethene ug/L 400 118 60-140129 9 30400ND471515 Trichlorofluoromethane ug/L 400 111 60-140118 6 30400ND442470 Vinyl chloride ug/L M140012760-140149 16 30400ND509597 Xylene (Total)ug/L 1200 104 60-140117 10 30120036916201780 1,2-Dichloroethane-d4 (S)%102 70-130100 4-Bromofluorobenzene (S)%100 70-130104 Toluene-d8 (S)%104 70-130103 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 27 #=QL# QUALIFIERS Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS Result confirmed by second analysis.C0 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 27 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92639014 SLC0941201-FORMER BEALS 76 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92639014001 740838MW-1 SM 6200B 92639014002 740838MW-2 SM 6200B 92639014003 740838MW-10D SM 6200B 92639014004 740169FBSM 6200B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 12/05/2022 04:52 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 27 Page 25 of 27 Page 26 of 27 Page 27 of 27 Former Beal’s 76 ATC Project No. SLC0941201 NCDEQ State Lead Program APPENDIX E WATER SUPPLY WELL INFORMATION (RETURNED SURVEYS)