AS-1146_12047_CA_MRP_20230523

WithersRavenel
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115 MacKenan Drive | Cary, NC 27511
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F-1479
Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington

MONITORING REPORT

JR’s Country Store
NCDEQ Incident # 12047
UST # AS-1146
5492 Crabtree Road
Clyde, Haywood County, North Carolina
WithersRavenel Project No. 23-0307-CS

Prepared for:
State of North Carolina Department of Environmental Quality Division of Waste Management Underground Storage Tank Section Federal & State Lead Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646
Prepared by:
WithersRavenel
115 MacKenan Drive
Cary, North Carolina 27511
North Carolina Firm License No. F-1479
May 23, 2023
WithersRavenel
Our People. Your Success.
115 MacKenan Drive | Cary, NC 27511
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F-1479
Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington

May 23, 2023 State of North Carolina Department of Environmental Quality Federal & State Lead Program
Division of Waste Management-Underground Storage Tank Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646
Attn: Ms. Sharon Ghiold Re: Monitoring Report JR’s Country Store 5492 Crabtree Road
Clyde, Haywood County, North Carolina
Groundwater Incident Number: 12047 UST Number: AS-1146 WR Project Number: 23-0307-CS Ms. Ghiold:
WithersRavenel, Inc. (WR) has completed this Subsequent Monitoring Report to document assessment activities completed at the facility in association with our proposal, numbered Task Authorization (TA)-01 under contract #N70522-C, for the above referenced site, approved by the Federal & State Lead Program on March 17, 2023. The enclosed report summarizes results of the recently completed monitoring activities.
WR appreciates the opportunity to be of service to the Federal & State Lead Program. Should you have any questions regarding the attached, please contact us at [phone]. Cordially, WithersRavenel

Flora D’Souza, CHMM Elizabeth A. Allyn, PG
Environmental Project Scientist II Environmental Project Geologist II

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JR’s Country Store – NCDEQ Incident #12047 WR Project # 23-0307-CS Monitoring Report May 2023 i
TABLE OF CONTENTS

SECTION A. SITE INFORMATION ..................................................................................................................... 1
SECTION B. EXECUTIVE SUMMARY ................................................................................................................ 3
SECTION C. SITE HISTORY AND CHARACTERIZATION ............................................................................ 5
SECTION D. GROUNDWATER SAMPLING – MARCH 2023 ..................................................................... 8
SECTION E. CONCLUSIONS AND RECOMMENDATIONS ........................................................................ 9

FIGURES
Figure 1 General Location Map
Figure 2 Site Map
Figure 3 Groundwater Hydraulic Gradient Map (March 2023)
Figure 4 Groundwater Analytical Results Map (March 2023)
Figure 5 Receptor Map

TABLES
Table B-1 Site History: UST/AST System & Other Release Information
Table B-4 Summary of Groundwater Analytical Results
Table B-5A Public & Private Water Supply Well Information
Table B-7 Monitoring Well Construction and Liquid Level Data

APPENDICES
Appendix A Laboratory Analytical Report and Chain-of-Custody
Appendix B Field Notes & Photographic Record
Appendix C General Standard Operating Procedures

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SECTION A. SITE INFORMATION
1. Site Identification
Date of Report: May 23, 2023
Facility I.D.: 0-0-0000010628
Incident No.: 12047
UST No.: AS-1146
Site Risk: High
Site Rank: H0530D
Land Use Category: Commercial
Site Name: JR’s Country Store
Site Location: 5492 Crabtree Road
Nearest City/Town: Clyde
County: Haywood
Description of Geographical Data Point: Center of Site
Location Method: Google Earth
Latitude: 35.592535° N
Longitude: -82.937961° W
2. Contact Information
Responsible Party: Milton J. Messer and Marjorie M. Lowdermilk
Address: Route 1, Box 312B, Clyde, NC 28721
Phone: Unknown

Property Owner/Occupant: Roger Fricks
Address: 68 Best Lane, Clyde, NC 28721
Phone: [phone]

Consultant/Contractor: WithersRavenel
Address: 115 MacKenan Drive, Cary, NC 27511
Phone: [phone]

Analytical Laboratory: Waypoint Analytical, Inc.
State Certification Number: ENV402
Address: 449 Springbrook Rd., Charlotte, NC 28217
Phone: [phone]

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SECTION B. EXECUTIVE SUMMARY
1. Summary of Activities Associated with Current TA
WithersRavenel, Inc. (WR) completed a groundwater monitoring event at the JR’s Country Store located at 5492 Crabtree Road in Clyde, Haywood County, North Carolina in association with TA-
01 under North Caroline Department of Environmental Quality (NCDEQ) Contract # N70522-C. 2. Soil, Groundwater and LNAPL Assessment Information

Soils No soil samples were collected by WR in association with this task authorization. Laboratory analysis of the soil samples collected from beneath the underground storage tanks (USTs) and the pump island detected Total Petroleum Hydrocarbons – Gasoline Range Organics (TPH-GRO) concentrations ranging from 25.7 milligrams per kilogram (mg/kg) to 749 mg/kg. Approximately
147 tons of petroleum contaminated soil was excavated from beneath the USTs. Post-excavation sampling detected TPH-GRO concentrations ranging from 1.1 mg/kg to 536 mg/kg at the base of the excavation. WR is not aware of the presence of any risk-based soil data for the incident.
Groundwater WR collected groundwater samples from site monitoring wells MW-1, MW-2R, MW-5, MW-8, and MW-9 on June 29, 2022. WR was also granted permission to collect samples from water supply wells WSW-1B, WSW-2, and WSW-6. WR was unable to collect groundwater samples
from WSW-3 and WSW-7. The collected groundwater samples were submitted for laboratory analysis of volatile organic compounds (VOCs) by SM6200B. Laboratory analytical results revealed the following exceedances to the NCDEQ 15A NCAC 2L Groundwater Quality Standards (2L Standards):

• MW-1: Methyl tert-butyl ether (MTBE);
• MW-8: Di-Isopropyl Ether and MTBE.
No other compounds within the sampled monitoring wells were reported at concentrations that exceeded regulatory standards established by NCDEQ. The water supply well samples from wells WSW-2 and WSW-6 contained concentrations of one
or more of the following compounds: di-isopropyl ether, and/or MTBE at concentrations below the established 2L Standards. LNAPL
Measurable thickness of Light Non-Aqueous Phase Liquid (LNAPL) was not encountered in March
2023. WR is not aware of the historical presence of LNAPL in any of the site monitoring wells.
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3. Receptor Information Fourteen (14) water supply wells and one spring have been identified within 1,000 feet of the site. Five of these water supply wells are located within 500 feet of the site (WSW-1B, WSW-2, WSW-
3, WSW-6, and WSW-7). Municipal water is reportedly unavailable to the site or surrounding properties. Well head protection areas were not identified within 1,500-ft of the subject property. 4. Remediation Activities

Based on WR’s review of historical files available for the site, the following remedial activities have been completed at the location:
• Approximately 147 tons of petroleum contaminated soil was excavated from beneath the
USTs during closure activities in January / February 1994. The excavation was reportedly advanced to a depth of 18 feet below ground surface (BGS). Based on currently available information, WR is unaware of additional remedial actions that have
been performed at the site.
5. Recommendations Based on the results of assessment and monitoring activities conducted at the site in association
with this TA, WR recommends the following:

• Continued semi-annual monitoring of site monitoring wells and water supply wells within 500 feet of the area of release.
• If funding is available, conduct a targeted injection of BOS200 near and downgradient of MW-8.
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SECTION C. SITE HISTORY AND CHARACTERIZATION WR has completed a groundwater sampling event for the referenced site in association with TA-01 at the facility in March 2023. The following information summarizes the site history and
characterization. 1. UST Information The subject property is located at the 5492 Crabtree Road in Clyde, Haywood County, North
Carolina (Figures 1 and 2). According to the Haywood County GIS website, the subject property is owned by Mr. Roger Fricks. The site is currently occupied by F&F Trucking, a transport company. In January 1994, one 1,000-gallon gasoline UST and one 550-gallon gasoline UST were removed from the site. Available UST information is summarized on Table B-1. Laboratory analysis of the soil samples collected beneath the USTs and the pump island detected TPH-GRO concentrations
ranging from 25.7 mg/kg to 749 mg/kg. Approximately 147 tons of petroleum contaminated soil was excavated from beneath the USTs to a depth of 18 feet BGS. Post-excavation sampling detected TPH-GRO concentrations ranging from 1.1 mg/kg to 536 mg/kg at the floor of the excavation.
2. Description of Release/General Assessment History The following summary of the assessment history is based on WR’s review of historical files for the subject incident:
• January 1994 – July 1996 – The USTs and approximately 147 tons of petroleum impacted soils were removed from the site during January / February 1994. Subsequently, seven monitoring wells (MW-1 through MW-7) were installed on the subject property and
periodically monitored.
• November 1996 – A Comprehensive Site Assessment (CSA) was prepared.
• January 1997 through January 2021 – Groundwater sampling of site monitoring wells and some water supply wells occurred. Monitoring wells MW-6 and MW-7 have not been located
since 1996 and are presumed destroyed. At some point, on-site supply well WSW-1A was abandoned and replaced with WSW-1B.
• July 2013 – A receptor survey was completed by Crawford Environmental Services (CES).
Twenty-six (26) water supply wells and one spring were identified within 1,500 feet of the site.
Six of these water supply wells were located within 500 feet of the site (WSW-1B, WSW-2, WSW-3, WSW-6, WSW-7, and WSW-15).
• August 2015 – Monitoring well MW-8 was installed.
• January 2021 – Groundwater monitoring event identified 2L exceedances in MW-1, MW-5, and MW-8. Water supply well WSW-2 was also sampled and contained concentrations of di-isopropyl ether and MTBE at concentrations below 2L Standards.
• April 2022 – WR installed monitoring well MW-9 and replacement MW-2R at the site and
conducted a receptor survey update for the surrounding area. Groundwater sampling of select monitoring wells and water supply wells identified the MTBE, di-isopropyl ether, and/or naphthalene at concentrations exceeding 2L Standards in wells MW-1, MW-5, and MW-8.
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Water supply wells WSW-2, WSW-3, and WSW-6 contained benzene, di-isopropyl ether, and/or MTBE at concentrations exceeding method detection limits but below 2L Standards.
• June 2022 – Groundwater monitoring event identified 2L exceedances in MW-1, MW-5, and
MW-8. Water supply wells WSW-2 and WSW-6 were also sampled and contained concentrations of one or more of the following compounds: di-isopropyl ether and/or MTBE at concentrations below the established 2L Standards.
3. Brief Description of Site Characteristics
The subject property is located at the 5492 Crabtree Road in Clyde, Haywood County, North Carolina (Figures 1 and 2). According to the Haywood County GIS website, the subject property is owned by Mr. Roger Fricks. The site is currently occupied by F&F Trucking, a transport company.
The subject property is located in a rural, mostly residential area.
4. Information on Receptors/Potential Receptors According to the most recent receptor survey update conducted in January 2022, fourteen (14)
water supply wells and one spring were identified to be within 1,000 feet of the site. Five of these
water supply wells are located within 500 feet of the site (WSW-1B, WSW-2, WSW-3, WSW-6, and WSW-7). According to Mr. Richard Hodge with the Town of Canton, The Town of Canton’s water line terminates near exit 31 on interstate 40 and there are no municipal water lines between exit 31 and exit 24, the Crabtree Road exit. Well head protection areas were not identified within
1,500-ft of the subject property.
The estimated locations of these water supply wells are shown on Figure 5. Information regarding the water supply sources is provided on Table B-5A.
5. Regional and Site Geology and Hydrology
As determined from the USGS Topographic Map, Clyde, North Carolina Quadrangle dated 2019
(Figure 1), the site is located at an approximate elevation of 2,550 feet above mean sea level. An
unnamed tributary to Crabtree Creek, is located approximately 1,000 feet east and south of site.
Surface runoff on the site generally flows toward the southeast.

According to the Geologic Map of North Carolina, the site is located in the Blue Ridge Belt of the
Blue Ridge Physiographic Province. The site bedrock consists of interlayered biotite-garnet gneiss
and amphibolite. The soils encountered in this area are the residual product of in-place chemical
weathering of rock presently underlying the site and/or historic depositional events. According to
the USDA Soil Survey Map, the soils at the site consists of Hayesville clay loam (HaC2). HaC2 is
found on 8 to 15 percent slopes and consists of clay loams that originated from weathered gneiss
and amphibolite. During the installation of MW-2R and MW-9, soils consisted of varying amounts
of sand and silts to depths of approximately 45 feet BGS.

Surficial unconfined groundwater movement within the overlying soils is controlled largely by
topographic gradients. However, as the groundwater percolates downward, it becomes influenced
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by the subsurface geologic conditions. Therefore, the direction of groundwater movement in the
deeper aquifers may not be consistent with the surface topography. Recharge occurs primarily by
infiltration along higher elevations and typically discharges into streams or other surface water
bodies as the water flows from higher topographic elevations to lower topographic elevations.
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SECTION D. GROUNDWATER SAMPLING – MARCH 2023 On March 29, 2023, WR personnel performed groundwater sampling activities at the site. The scope of work for this project included the gauging, purging, and sampling of existing monitoring
wells MW-1, MW-2R, MW-5, MW-8, and MW-9. WR was also tasked with collecting water supply wells samples from WSW-1B, WSW-2, WSW-3, WSW-6, and WSW-7. In the performance of assessment activities at the site, WR was able to collect groundwater samples from MW-1, MW-2R, MW-3, MW-4, MW-5, MW-8, and MW-9. WR also was granted
signed permission to collect a sample from WSW-1B, WSW-2, and WSW-6. The following provides information as to why wells WSW-3 and WSW-7 were not sampled during the March 2023 event:
• WSW-3 – Vacant; building under construction; and
• WSW-7 – The homeowner was not home to grant permission. The following paragraphs describe the sampling activities and associated laboratory analytical
results. Groundwater Sampling Activities Prior to the purging and sampling of the site monitoring wells on March 29, 2023, WR personnel opened and gauged those wells targeted for purging and sampling with a decontaminated
electronic water level indicator to determine the depth to groundwater at each well location. In
the performance of these activities along with the purging process, LNAPL was not measured in any of the monitoring wells gauged. The depth to groundwater measurements in the monitoring wells ranged from 31.69 feet (ft) below the top of casing (ft-BTOC) in monitoring well MW-9 to 36.55 ft-BTOC in monitoring well
MW-8. Based on data obtained during this sampling event, groundwater flow appears to trend to the east-southeast. This groundwater flow appears generally consistent with past assertions. A groundwater hydraulic gradient map based on the March 2023 measurements are shown on Figure 3. Groundwater elevation data are included in Table B-7.
Following gauging, monitoring wells were purged and sampled with separate, disposable polyethylene bailers for each well. Samples from the wells along with a field blank (FB-1) were decanted into pre-preserved laboratory provided sample containers. Samples collected from site monitoring wells were submitted to Waypoint Analytical, Inc. (Waypoint) for testing by Standard Method (SM) 6200B plus oxygenates.
Laboratory Results Analytical results for the groundwater samples collected on March 29, 2023 revealed the following exceedances to the 2L Standard.

• MW-1: MTBE (26 µg/L); and
• MW-8: Di-Isopropyl Ether (190 µg/L) and MTBE (862 µg/L)

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Multiple petroleum constituents were reported in monitoring wells MW-1, MW-2R, and MW-5 at concentrations exceeding method detection limits (MDLs) but below 2L Standards. No other compounds within the sampled monitoring wells were reported at concentrations that exceeded regulatory standards established by NCDEQ.
The water supply well samples from well WSW-2 contained concentrations of di-isopropyl ether and MTBE and WSW-6 contained MTBE at concentrations below the established 2L Standards. The following table compares Total VOCs results from March 2023 to concentrations reported in
June 2022:
Well ID
Total VOCs
June 2022 (µg/L)
Total VOCs
March 2023 (µg/L)
Percent Change
MW-1 30.30 28.02 8% Decrease MW-5 31.76 19.0 40% Decrease
MW-8 1,339.65 1,052.0 21% Decrease

Total VOC concentrations in the on-site monitoring wells show general decreases since the June
2022 monitoring event. Results from water supply wells WSW-2 and WSW-6 show a decrease of 15% and 18%, respectively, when comparing total VOCs from March 2023 to results from June 2022.

Laboratory analytical results are shown on Figure 4 and included in Table B-4. Copies of the laboratory analytical report and chain-of-custody are included in Appendix A. Field notes and a photographic record are included as Appendix B. Standard Operating Procedures are included in Appendix C.

SECTION E. CONCLUSIONS AND RECOMMENDATIONS This report documents the results of groundwater sampling activities conducted at the site for TA-
01. Conclusions based on observations, analytical data and research relating to the release at the
site combined with historical information include the following:
• The site and all surrounding properties are provided potable water through private water
supply wells.
• No municipal water is supplied to the local area.
• WR is unaware of any risk-based soil samples from the former UST area.
• MTBE was reported at concentrations exceeding the 2L Standard in monitoring wells MW-1 and MW-8.
• Di-isopropyl ether was reported at a concentration exceeding 2L Standards in monitoring well
MW-8.
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JR’s Country Store – NCDEQ Incident #12047 WR Project # 23-0307-CS Monitoring Report May 2023 10
• The water supply well samples from WSW-2 and WSW-6 contained concentrations of di-isopropyl ether and/or MTBE at concentrations below established 2L Standards.
• No compounds were reported at concentrations that exceed their respective Gross Contamination Levels (GCLs).
• Total VOC changes over-time show significant reductions in wells MW-1, MW-5, and MW-8.
• Groundwater appears to be naturally attenuating at the site.
• Results from water supply wells WSW-2 and WSW-6 show a decrease of 15% and 18%, respectively, since June 2022.
• The concentrations in water supply well WSW-2 has remained approximately the same since January 2018 and MTBE in WSW-6 has remained at a similar concentration since it was first sampled by WR in January 2022.
• LNAPL was not observed in March 2023.
Based on the results of assessment and monitoring activities conducted at the site in association with this TA, WR recommends the following:
• Continued semi-annual monitoring of site monitoring wells and water supply wells within 500 feet of the area of release.
• If funding is available, conduct a targeted injection of BOS200 near and downgradient of MW-
8.

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FIGURES
MM
FD
DRAWN BY:
04/17/23 23-0307-CS
1
SUBJECT SITE
SCALE:FIGURE NO.:
PROJECT NO.:DATE:APPROVED BY:
JR'S COUNTRY STORE - TF #12047
5492 CRABTREE ROAD
CLYDE, HAYWOOD COUNTY, NC
GENERAL LOCATION MAP
1"=500 '
GRAPHIC SCALE
1 inch = 500 ft.
0 500250 1000
WithersRavenel
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115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479
www.withersravenel.com
SITECRABTREE RD
FORMERUST LOCATIONCRABTR
E
E

C
H
U
R
C
H

R
D
C
R
A
B
T
R
E
E

R
D
MW-3MW-2RMW-4MW-1MW-5MW-6(DESTROYED)MW-7(DESTROYED)WSW-1A(ABANDONED)WSW-1B(ACTIVE)WSW-2(ACTIVE)WSW-6(ACTIVE)WSW-7(ACTIVE)WSW-3(ACTIVE)MW-9MW-8MMFDDRAWN BY:04/17/2323-0307-CS2SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:JR'S COUNTRY STORETF #120475492 CRABTREE ROADCLYDE, HAYWOOD COUNTY, NCSITE MAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com1"=100 'GRAPHIC SCALE1 inch = 100 ft.010050200LEGENDTYPE II MONITORING WELL LOCATIONWATER SUPPLY WELLNOTES: 1.) AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.
SITECRABTREE RD
FORMERUST LOCATIONCRABTREE CHUR
C
H

R
D
CRABTREE RD
MW-3MW-2RMW-4MW-1MW-5MW-6(DESTROYED)MW-7(DESTROYED)WSW-1A(ABANDONED)WSW-2(ACTIVE)WSW-3(ACTIVE)MW-9MW-8(NM)(NM)(64.62)(65.97)65.0(65.57)64.063.0(62.21)(63.13)1"=60 'GRAPHIC SCALE1 inch = 60 ft.06030120LEGENDTYPE II MONITORING WELL LOCATIONWATER SUPPLY WELLGROUNDWATER ELEVATION (FEET)GROUNDWATER GRADIENT (FEET)GROUNDWATER CONTOURNOTES: 1.) AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.MMFDDRAWN BY:04/17/2323-0307-CS3SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:JR'S COUNTRY STORE5492 CRABTREE ROADCLYDE, HAYWOOD COUNTY, NCGROUNDWATER HYDRAULICGRADIENT MAP(MARCH 2023)WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com(64.29)65.0
SITECRABTREE RD
FORMERUST LOCATIONCRABTREE CHUR
C
H

R
D
CRABTREE RD
MW-3MW-2RMW-4MW-1MW-5MW-6(DESTROYED)MW-7(DESTROYED)WSW-1A(ABANDONED)WSW-2(ACTIVE)WSW-3(ACTIVE)MW-9MW-8(2.44)(26)(862)(14) MTBE 2LCONTOUR 20 ug/L(12.9)(NS)(NS)(NS)(<1.00)1"=60 'GRAPHIC SCALE1 inch = 60 ft.06030120LEGENDTYPE II MONITORING WELL LOCATIONWATER SUPPLY WELLMTBE CONCENTRATION (ug/L)NOTES: 1.) AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.MMFDDRAWN BY:04/17/2323-0307-CS4SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:JR'S COUNTRY STORETF #120475492 CRABTREE ROADCLYDE, HAYWOOD COUNTY, NCGROUNDWATER ANALYTICALRESULTS MAP(MARCH 2023)WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479 | www.withersravenel.com(64.29)
CRABTREE RDCRABTREE CHURCH RDCRABTREE RD500 FT
1000 FT
WSW-1A
(ABANDONED)
WSW-1B
(ACTIVE)
WSW-3
(ACTIVE)
WSW-2
(ACTIVE)
WSW-6
(ACTIVE)
WSW-7
(ACTIVE)
WSW-8
(ACTIVE)
WSW-15
(ACTIVE)
WSW-17
(ACTIVE)
WSW-24
(ACTIVE)
WSW-12
(ACTIVE)
WSW-14
(ACTIVE)
WSW-13
(ACTIVE)
WSW-22
(ACTIVE)
SURFACE WATER BODY
INTERMITTENT STREAM
WSW-21
(ACTIVE)
NO MUNICIPAL WATER SUPPLIED TO THE LOCAL AREA.
ALL DEVELOPED PROPERTIES EXPECTED TO UTILITIZE WELLS FOR POTABLE WATER.
CHURCH
PROPERTY MMFDDRAWN BY:04/17/2323-0307-CS5SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:JR'S COUNTRY STORETF #120475492 CRABTREE ROADCLYDE, HAYWOOD COUNTY, NCRECEPTOR MAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.com1"=200 'GRAPHIC SCALE
1 inch = 200 ft.
0 200100 400
LEGEND
WATER SUPPLY WELL LOCATION (ESTIMATED)
NOTES:
1.) AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.
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TABLES
UST IDNumberCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofUSTWas release associated with UST System? (Y/N)1 1,000 Steel Unknown Single Wall Steel UnknownPermanently Closed By Removal (January 1994)Y2 550 Steel Unknown Single Wall Steel UnknownPermanently Closed By Removal (January 1994)YAST IDNumberCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length) (ft)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofASTWas release associated with AST System? (Y/N)IncidentNumberMaterialReleasedDateofRelease12047 GasolineJanuary 1994Notes:1) UST Information obtained from NCDEQ tank and ownership publications.Table B-1Site History: UST/AST System & Other Release InformationJR's Country StoreLaboratory analysis of the soil samples collected from the bottom of the UST excavation and the pump island detected Total Petroleum Hydrocarbons – Gasoline Range Organics (TPH-GRO) ranging from 25.7 milligrams per kilogram (mg/kg) to 749 mg/kg. Approximately 147 tons of petroleum contaminated soil was excavated from beneath the USTs. Post excavation sampling detected TPH-GRO concentrations ranging from 1.1 mg/kg to 536 mg/kg at the base of the excavation.5492 Crabtree RoadClyde, Haywood County, North Carolina Description of ReleaseIncident # 12047Current/LastContentsGasolineCurrent/LastContentsGasolinePage 1 of 1
Calculated
Acetone Benzene 1,2-DichloroethaneEthylbenzene Isopropyl Ether 4-IsopropyltolueneMBK, Methyl Butyl Ketone (2-Hexanone) MEK (2-Butanone)Methylene Chloride Methyl-tert-Butyl Ether MIBK (4-Methyl-2-pentanone) Naphthalene n-PropylbenzeneToluene 1,2,4-Trimethylbenzene 1,3,5-TrimethylbenzeneTotal Xylenes67-64-1 71-43-2 107-06-2 100-41-4 108-20-3 99-87-6 591-78-6 78-93-3 75-09-2 1634-04-4 108-10-1 91-20-3 103-65-1 108-88-3 95-63-6 108-67-8 1330-20-7
01/01/94 NS 430 ND 755 507 NA NS NS NA 2,307 NS NS NS 349 NS NS 513
08/01/95 NS 396 ND 269 332 NA NS NS NA 88 NS NS NS 566 NS NS 662
11/01/95 NS 260 ND 463 418 NA NS NS NA 335 NS NS NS 410 NS NS 555
03/01/96 NS 1,150 ND 73.2 48.5 NA NS NS NA 482 NS NS NS 1,807 NS NS 2,030
06/01/96 NS 2,485 ND 849 230 NA NS NS NA ND NS NS NS 5,496 NS NS 6,036
08/01/96 NS 196 ND 67.2 569 NA NS NS NA 685 NS 84.9 NS 221 NS NS 371
01/01/05 NS 97 ND ND 1,100 NA NS NS NA 6,100 NS NS NS 32 NS NS ND
07/29/09 NS 7.5 ND ND 404 NA ND ND NA 147 ND ND ND ND ND ND ND
02/24/10 NS 15 ND ND 300 NA ND ND NA 150 ND ND ND ND ND ND ND
06/30/11 NS 36 ND 0.25J 260 NA ND ND NA 1,300 ND 1 ND 8.2 ND 0.31J 15.6
01/14/12 NS 3.3 ND 0.40J 230 NA ND ND NA 1,200 ND ND ND 1.7 0.45J 0.25J 4.8
03/21/13 NS 0.67 ND ND 247 NA ND ND NA 1,370 ND ND ND 0.56 ND ND 0.65
07/23/14 NS ND ND ND 330 NA ND ND NA 2,500 ND ND ND ND ND ND ND
08/07/15 NS <5.0 <5.0 <5.0 94.5 NA <5.0 <5.0 NA 753 <5.0 <20.0 <5.0 <5.0 <5.0 <5.0 <5.0
10/15/16 NS <2.5 <2.5 <2.5 89.5 NA <2.5 <2.5 NA 746 <2.5 <10.0 <2.5 <2.5 <2.5 <2.5 <2.5
01/23/18
11/29/18
01/06/21 <10 <0.50 <0.50 <0.50 5.7 <0.50 <1.0 <5.0 <2.0 45 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.5
01/22/22 <10.0 0.527 <0.500 <0.500 7.27 <0.500 <1.00 <5.00 <2.00 65.3 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 2.69
06/29/22 <10.0 <0.500 <0.500 <0.500 1.90 <0.500 <1.00 <5.00 <2.00 28.4 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/29/23 <10.0 <0.500 <0.500 <0.500 2.02 <0.500 <1.00 <5.00 <2.00 26.0 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/01/94 NS ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS 16.2
08/01/95 NS ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
03/01/96 NS ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
06/01/96 NS ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
08/01/96 NS ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
07/29/09
02/24/10
06/30/11
01/14/12
03/21/13
07/23/14 NS ND ND ND 2.3 NA ND ND NA ND ND 2.7 ND ND ND ND ND
08/07/15 NS <0.5 <0.5 <0.5 2.6 NA <0.5 <0.5 NA <0.5 <0.5 1.6 <0.5 <0.5 <0.5 <0.5 <0.5
10/15/16 NS <0.5 <0.5 <0.5 1.6 NA <0.5 <0.5 NA 3.4 <0.5 <2.0 <0.5 <0.5 <0.5 <0.5 <0.5
01/23/18
11/29/18
01/06/21 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0 <5.0 <2.0 1.6 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.5
01/22/22 <10.0 <0.500 <0.500 <0.500 1.43 <0.500 <1.00 <5.00 <2.00 4.36 <1.00 <1.00 <0.500 <0.500 0.956 <0.500 <0.500
06/29/22 <10.0 <0.500 <0.500 <0.500 0.669 <0.500 <1.00 <5.00 <2.00 2.15 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/29/23 <10.0 <0.500 <0.500 <0.500 0.754 <0.500 <1.00 <5.00 <2.00 2.44 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/01/94 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS 10.3
08/01/95 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
11/01/95 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
03/01/96 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
06/01/96 NA ND ND ND ND NA NS NS NA 0.7 NS NS NS ND NS NS ND
08/01/96 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
07/29/09
02/24/10 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
06/30/11 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
01/04/12 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
03/21/13 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
07/23/14 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
08/07/15
10/15/16
01/23/18
01/06/21
01/22/22 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 <1.00 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/01/94 NA ND ND 2.1 NS NA NS NS NA ND NS NS NS ND NS NS 3
08/01/95 NA ND ND ND NS NA NS NS NA ND NS NS NS ND NS NS ND
11/01/95 NA ND ND ND NS NA NS NS NA ND NS NS NS ND NS NS ND
03/01/96 NA ND ND ND NS NA NS NS NA ND NS NS NS ND NS NS ND
06/01/96 NA ND ND ND NS NA NS NS NA 0.8 NS NS NS ND NS NS ND
08/01/96 NA ND ND ND NS NA NS NS NA ND NS NS NS ND NS NS ND
07/29/09
02/24/10 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
06/30/11 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
01/04/12 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
03/21/13 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
07/23/14 NA ND ND ND ND NA ND ND NA ND ND ND ND ND ND ND ND
08/07/16
10/15/16
01/23/18
01/06/21
01/22/22 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 <1.00 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/01/94 NA 4,499 ND 751 2,748 NA NS NS NA 4,429 NS NS NS 5150 NS NS 8,210
08/01/95 NA 0.8 ND ND 6.2 NA NS NS NA ND NS NS NS MD NS NS ND
11/01/95 NA 44.2 ND ND 8.3 NA NS NS NA 1 NS NS NS ND NS NS ND
03/01/96 NA 92.5 ND ND 4.4 NA NS NS NA ND NS NS NS ND NS NS ND
06/01/96 NA 61 ND ND 4.2 NA NS NS NA 0.7 NS NS NS ND NS NS ND
08/01/96 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
07/29/09
02/24/10
06/30/11
01/04/12
03/21/13 NA ND ND ND 1.5 NA ND ND NA 0.42 J ND ND ND ND ND ND ND
07/23/14 NA ND ND ND 56 NA ND ND NA 160 ND ND ND ND ND ND ND
08/07/15
10/15/16
01/23/18
11/29/18
01/06/21 <10 <0.50 <0.50 <0.50 23 <0.50 <1.0 <5.0 <2.0 62 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.5
01/22/22 <10.0 <0.500 <0.500 <0.500 13.5 <0.500 <1.00 <5.00 <2.00 30.4 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
06/29/22 <10.0 <0.500 <0.500 <0.500 7.56 <0.500 <1.00 <5.00 <2.00 24.2 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/29/23 <10.0 <0.500 <0.500 <0.500 5.00 <0.500 <1.00 <5.00 <2.00 14.0 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
08/01/96 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
12/01/96 NA 1.2 ND ND 1.7 NA NS NS NA 1.1 NS NS NS ND NS NS ND
07/29/09
08/01/96 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
12/01/96 NA ND ND ND ND NA NS NS NA ND NS NS NS ND NS NS ND
07/29/09
MW-3
MW-4
MW-7
MW-6
NOT SAMPLED - WELL DRY
NOT SAMPLED - WELL DRY
NOT SAMPLED - WELL DRY
WELL DESTROYED
NOT SAMPLED
TABLE B-4
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
JR's Country Store
Incident # 12047
5492 Crabtree Road
Clyde, Haywood County, North Carolina
Sample
ID
Date
Collected
Analytical Method 6200B - Volatile Organic Compounds
NOT SAMPLED
WELL DESTROYED
NOT SAMPLED - WELL DRY
NOT SAMPLED - WELL DRY
MW-5
MW-1
NOT SAMPLED - WELL DRY
NOT SAMPLED - WELL DRY
NOT SAMPLED - WELL DRY
NOT SAMPLED - WELL DRY
NOT SAMPLED - WELL DRY
MW-2R
MW-2
WELL DESTROYED
Page 1 of 2
Calculated
Acetone Benzene 1,2-DichloroethaneEthylbenzene Isopropyl Ether 4-IsopropyltolueneMBK, Methyl Butyl Ketone (2-Hexanone) MEK (2-Butanone)Methylene Chloride Methyl-tert-Butyl Ether MIBK (4-Methyl-2-pentanone) Naphthalene n-PropylbenzeneToluene 1,2,4-Trimethylbenzene 1,3,5-TrimethylbenzeneTotal Xylenes67-64-1 71-43-2 107-06-2 100-41-4 108-20-3 99-87-6 591-78-6 78-93-3 75-09-2 1634-04-4 108-10-1 91-20-3 103-65-1 108-88-3 95-63-6 108-67-8 1330-20-7
TABLE B-4
SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
JR's Country Store
Incident # 12047
5492 Crabtree Road
Clyde, Haywood County, North Carolina
Sample
ID
Date
Collected
Analytical Method 6200B - Volatile Organic Compounds
08/10/15 NA 16.1 1.4 12.2 333 NA <0.5 ,0.5 NA 1,530 1.3 8 2.6 12.2 40.9 <0.5 181.4
10/15/16 NA 6.4 <6.2 <6.2 374 NA <6.2 <6.2 NA 1,820 <6.2 <25.0 <6.2 <6.2 18.2 9.8 46
01/23/18 NA 3.6 1.4 2.3 460 NA 7.7 40 NA 2,800 5.6 11 <0.5 <0.5 11 6.9 13
11/29/18 NA 9.7 <0.4 6 250 NA <0.5 24 J NA 1,700 <0.5 20 <0.5 <0.5 11 4.2 J 14 J
01/06/21 <100 <5.0 <5.0 <5.0 380 <5.0 <10 <50 <20 1,900 <10 34 <5.0 <5.0 <5.0 <5.0 <15
01/22/22 <10.0 <0.500 0.613 <0.500 239 <0.500 <1.00 <5.00 <2.00 985 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
06/29/22 <10.0 <0.500 0.645 <0.500 179 <0.500 <1.00 <5.00 <2.00 1,160 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/29/23 <100 <5.00 <5.00 <5.00 190 <5.00 <10.0 <50.0 <20.0 862 <10.0 <10.0 <5.00 <5.00 <5.00 <5.00 <5.00
01/22/22 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 <1.00 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
06/29/22 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 <1.00 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/29/23 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 <1.00 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
WSW-1B 03/29/23 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 <1.00 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
11/01/95 NS ND NA ND NA ND NA NS NA ND NA NS NA ND NA NA ND
01/19/05 NS NS NA NS NA 2.1 NA NS NA 1.3 NA NS NA NS NA NA NS
05/11/06 NS NS NA NS NA ND NA NS NA ND NA NS NA NS NA NA NS
07/29/09 ND ND NA ND NA 2 NA ND NA 2 NA ND NA ND NA NA ND
02/24/10 ND ND NA ND NA 2.8 NA ND NA 3.6 NA ND NA ND NA NA ND
06/30/11 ND ND NA ND NA 2.2 NA ND NA 3.1 NA ND NA ND NA NA ND
01/04/12 ND ND NA ND NA 1.4 NA ND NA 2.1 NA ND NA ND NA NA ND
03/21/13 ND ND NA ND NA 1.5 NA ND NA 2 NA ND NA ND NA NA ND
07/23/14 ND ND NA ND NA 1.1 NA ND NA 1.9 NA ND NA ND NA NA ND
08/10/15 <0.5 <0.5 NA <0.5 NA 1.3 NA <0.5 NA 2.7 NA <2.0 NA <0.5 NA NA <0.5
10/15/16 <0.5 <0.5 NA <0.5 NA 2.1 NA <0.5 NA 4.4 NA <2.0 NA <0.5 NA NA <0.5
01/23/18 <0.5 <0.5 NA <0.5 NA 3.3 NA <0.5 NA 11 NA <2.0 NA <0.5 NA NA <0.5
11/29/18 <0.5 <0.5 NA <0.5 NA 3.1 NA <0.5 NA 11 NA <2.0 NA <0.5 NA NA <0.5
01/06/21 <10 <0.50 <0.50 <0.50 3.3 <0.50 <1.0 <5.0 <2.0 15 <1.0 <1.0 <0.50 <0.50 <0.50 <0.50 <1.5
01/22/22 <10.0 <0.500 <0.500 <0.500 2.59 <0.500 <1.00 <5.00 <2.00 13.5 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
06/29/22 <10.0 <0.500 <0.500 <0.500 2.06 <0.500 <1.00 <5.00 <2.00 15.7 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/29/23 <10.0 <0.500 <0.500 <0.500 2.12 <0.500 <1.00 <5.00 <2.00 12.9 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
WSW-3 01/22/22 <10.0 0.724 <0.500 <0.500 2.51 <0.500 <1.00 <5.00 <2.00 14.6 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
01/22/22 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 2.49 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
06/29/22 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 3.45 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
03/29/23 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 <2.00 2.84 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
6000 1 0.4 600 70 25 40 4000 5 20 100 6 70 600 400 400 500
6,000,000 5,000 400 84,500 70,000 11,700 40,000 4,000,000 5,000 20,000 100,000 6,000 30,000 260,000 28,500 24,500 50000
Notes:
1)All results provided in ug/L (micrograms per liter) or parts per billion.
2)
3)
4)GCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for Groundwater.
NL = No Regulatory Limit Established
NA / ND = Compound Not Analyzed or Not Detected
Result = Result Exceeds Laboratory Detection Limits
Result = Result Exceeds 2L Standard
Result = Result Exceeds GCL Value
NC 2L Standard - North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L.
MW-8
WSW-6
Compounds analyzed for by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included in the Appendix for a full list of constituents.
GCLs for Groundwater
NC 2L Standard
WSW-2
MW-9
Page 2 of 2
5492 Crabtree RoadClyde NC 28721Notes: 1)WSW-8229 Bannock Drive Clyde, NC 28721Haywood Charles Garrison, Jr.220 Bannock DriveClyde, NC 288721PotableWSW-125221 Crabtree RoadClyde, NC 28721HaywoodWilliam & Pauline Davis5221 Crabtree RoadClyde, NC 28721Potable Unknown UnknownPotable Unknown Unknown 1,450-ft SSEWSW-11309 Bannock DriveClyde, NC 28721HaywoodRichard Thompson & Dianne Brown85 Hiaway TrailClyde, NC 28721Potable Unknown UnknownWSW-9250 Bannock DriveClyde, NC 288721HaywoodKara and Kyle Chandler250 Bannock DriveClyde, NC 288721Potable Unknown Unknown 1,450-ft SSWWSW-10240 Bannock DriveClyde, NC 288721HaywoodJerry & Nancy Ferguson, Jr.240 Bannock DriveClyde, NC 288721WSW-7152 Grace LaneClyde, NC 28721HaywoodMichael and Angela Ledford152 Grace Lane Clyde, NC 28721Potable Unknown Unknown 400-ft SW99 Susie Noland RoadClyde, NC 28721WSW-538 Goldey LaneClyde, NC 28721Haywood Curnal Payne19255 NC 209 HwyHot Springs, NC 28743WSW-6192 Grace LaneClyde, NC 28721HaywoodAngela Keener Ledford152 Grace LaneClyde, NC 28721Potable Unknown UnknownPotable Unknown Unknown 1,250-ft SWPatricia Noland5561 Crabtree RoadClyde, NC 28721WSW-327 Best LaneClyde, NC 28721HaywoodCrabtree Mountain LLCPO Box 277Clyde, NC 28721-0277PotableWSW-454 Goldey LaneClyde, NC 28721Haywood Robert J ThomasGregory Allen Davis124 Crabtree Church RoadClyde, NC 28721PotableNNE600-ft NEWSW-18Potable Unknown Unknown 700-ft SWPotable Unknown Unknown 1,000-ft NNWPotable Unknown UnknownUnknown 1,500-ftUnknownWSW-15124 Crabtree Church RoadClyde, NC 28721HaywoodWSW-25464 Crabtree RoadClyde, NC 28721HaywoodRichard Samuel Caldwell5464 Crabtree RoadClyde, NC 28721WSW-145358 Crabtree RoadClyde, NC 28721HaywoodRonald & Evelyn Bradshaw5358 Crabtree RoadClyde, NC 2872154 Goldey LaneClyde, NC 28721Potable UnknownUnknown Unknown 1,500-ftUnknown Unknown 1,150-ft ESEUnknown Unknown 1,500-ft NENESWUnknown 600-ftUnknown5492 Crabtree RoadClyde NC 2872168 Best LaneClyde, NC 28721122 Winners CircleClyde, NC 28721457 Winners CircleClyde, NC 2872168 Best LaneClyde, NC 28721122 Winners CircleClyde, NC 28721PO Box 277Clyde, NC 28721-0277257 Winners CircleClyde, NC 287215405 Crabtree RoadClyde, NC 287215795 Crabtree RoadClyde, NC 28721Unknown 1,000-ft NEWSW-135350 CrabtreeClyde, NC 28721HaywoodCharles & Nancy Garrison, Jr.229 Bannock DriveClyde, NC 28721Spring HaywoodCrabtree Mountain LLCWSW-20WSW-16244 Crabtree Church RdClyde, NC 28721Haywood Charles Hoglen1272 S Yow Mill RdToccoa, GA 30577-8838HaywoodCrabtreeIronduff Volunteer fire99 Susie Noland RoadClyde, NC 28721WSW-175561 Crabtree RoadClyde, NC 28721HaywoodActiveWSW-22 Haywood Lucy Creech Potable257 Winners CircleClyde, NC 28721PO Box 277Clyde, NC 28721-027727 Best LaneClyde, NC 28721WSW-25 Haywood Daniel Royer Potable5795 Crabtree RoadClyde, NC 28721SSEUnknownUnknown 490-ft SEUnknown 550-ft250-ft NE1,250-ftUnknownUnknown250-ftPotablePotableOn sitePotable Unknown 100-ft SWSWSW1,250-ft SSW950-ft SWUnknownPotable UnknownUnknown Unknown 900-ft SWUnknown Unknown 550-ft NEWSW-1A Haywood Roger William Fricks AbandonedWSW-24 HaywoodCrabtree United Methodist ChurchPotable5373 Crabtree Road Clyde, NC 28721WSW-21 HaywoodCrabtree Mountain LLCWSW-1B Haywood Roger William Fricks PotableHaywood Joseph James PotableNo municipal supplied to the area. All Developed properties utilize wells for potable water.Well UseWell Depth(feet)Well Screen Well Distance from Source AreaLocation Relative to UnknownUnknown Unknown 1,250-ft ENEUnknownUnknown Unknown On siteWell ID Property Address County Property Owner Property Owner AddressTABLE B-5APUBLIC & PRIVATE WATER SUPPLY WELL INFORMATIONJR's Country StoreIncident # 120475492 Crabtree RoadClyde, Haywood County, North Carolina Page 1 of 1
Well ID Date Installed
Top of Casing
Elevation
(ft)
Well Diameter
(in)
Well Casing
Depth
(ft-BGS)
Screen Interval
(ft-BGS)
Date of
Measurement
Depth to Product
(ft-BTOC)
Depth To Water
(ft-BTOC)
Product Thickness
(ft)
Groundwater
Elevation
(ft)
01/23/12 -- 40.95 -- 58.60
03/21/13 -- 40.36 -- NM
07/23/14 -- 33.80 -- 65.75
08/07/15 -- 37.33 -- 62.22
10/15/16 -- 38.29 -- 61.26
01/23/18 -- DRY -- DRY
01/29/18 -- DRY -- DRY
01/06/21 -- 29.86 -- 69.69
01/21/22 -- 31.30 -- 68.25
06/29/22 -- 31.60 -- 67.95
03/29/23 -- 33.58 -- 65.97
01/23/12 -- DRY -- DRY
03/21/13 -- 39.87 -- NM
07/23/14 -- 34.15 -- 64.74
08/07/15 -- 37.52 -- 61.37
10/15/16 -- 37.76 -- 61.13
01/23/18 -- DRY -- DRY
01/29/18 -- DRY -- DRY
01/06/21 -- 29.75 -- 69.14
01/21/22 -- 33.65 -- 65.49
06/29/22 -- 32.57 -- 66.57
03/29/23 -- 34.52 -- 64.62
01/23/12 -- 37.26 -- 58.95
03/21/13 -- 36.01 -- 60.20
07/23/14 -- 28.77 -- 67.44
08/07/15 -- Not Measured -- Not Measured
10/15/16 -- Not Measured -- Not Measured
01/23/18 -- Not Measured -- Not Measured
01/29/18 -- Not Measured -- Not Measured
01/06/21 -- 24.91 -- 71.30
01/21/22 -- 27.40 -- 68.81
01/23/12 -- 37.84 -- 59.34
03/21/13 -- 36.71 -- 60.47
07/23/14 -- 30.40 -- 66.78
08/07/15 -- Not Measured -- Not Measured
10/15/16 -- Not Measured -- Not Measured
01/23/18 -- Not Measured -- Not Measured
01/29/18 -- Not Measured -- Not Measured
01/06/21 -- 25.64 -- 71.54
01/21/22 -- 28.00 -- 69.18
01/23/12 -- DRY -- DRY
03/21/13 -- 38.44 -- 63.04
07/23/14 -- 36.50 -- 64.98
08/07/15 -- DRY -- DRY
10/15/16 -- DRY -- DRY
01/23/18 -- DRY -- DRY
01/29/18 -- DRY -- DRY
01/06/21 -- 31.50 -- 69.98
01/21/22 -- 32.70 -- 68.78
06/29/22 -- 33.95 -- 67.53
03/29/23 -- 35.91 -- 65.57
01/23/12 -- Not Located -- Not Located
03/21/13 -- Not Located -- Not Located
07/23/14 -- Not Located -- Not Located
08/07/15 -- Not Located -- Not Located
10/15/16 -- -- -- --
01/23/18 -- -- -- --
01/29/18 -- -- -- --
01/06/21 -- Not Located -- Not Located
01/06/21 -- Not Located -- Not Located
01/23/12 -- Not Located -- Not Located
03/21/13 -- Not Located -- Not Located
07/23/14 -- Not Located -- Not Surveyed
08/07/15 -- Not Located -- Not Located
10/15/16 -- Not Located -- Not Located
01/23/18 -- Not Located -- Not Located
01/29/18 -- Not Located -- Not Located
01/06/21 -- Not Located -- Not Located
01/06/21 -- Not Located -- Not Located
01/23/12 -- -- -- --
03/21/13 -- -- -- --
07/23/14 -- -- -- --
08/07/15 -- 40.06 -- 59.62
10/15/16 -- 40.18 -- 59.50
01/23/18 -- 46.46 -- 53.22
01/29/18 -- 43.95 -- 55.73
01/06/21 -- 32.54 -- 67.14
01/21/22 -- 34.45 -- 65.23
06/29/22 -- 34.30 -- 65.38
03/29/23 -- 36.55 -- 63.13
01/21/22 -- 30.35 -- 63.55
06/29/22 -- 29.61 -- 64.29
03/29/23 -- 31.69 -- 62.21
1)
2)
3)
4)
5)
Destroyed
BTOC - Below Top of Casing.
Notes:
Top of Casing (TOC) elevations & data provided prior to January 2021 by previous consultants.
MW-1 1994 99.55 2.00 45.00 Unknown
MW-2 1994 98.89 2.00 40.00 Unknown
Unknown
Unknown
MW-3 1994 96.21 2.00 40.00
MW-4 1994 97.18 2.00 40.00
2.00 40
Unknown
MW-6 1996 97.66 2.00 38 28-38
MW-5 1994 101.48 2.00 40.00
If free product present groundwater elevation calculated by [TOC-DTW]+[free product thickness x 0.8581].
NM = Not Measured.
BGS - Below Ground Surface.
TABLE B-7
MONITORING WELL CONSTRUCTION AND LIQUID LEVEL DATA
JR's Country Store
Clyde, Haywood County, North Carolina
5492 Crabtree Road
Incident # 12047
30-40
MW-8 2015 99.68 2.00 54
25-45
MW-9 Jan-22 93.90 2.00 45 25-45
MW-2R Jan-22 99.14 2.00 45.00
44-54
MW-7 1996 91.89
Page 1 of 1
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APPENDIX A LABORATORY ANALYTICAL REPORT & CHAIN OF CUSTODY

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

4/11/2023
Withers & Ravenel Flora D'Souza
115 Mackenan Dr. BUILDING 117 Cary, NC, 27511
Ref: Analytical Testing
Lab Report Number: 23-090-0010 Client Project Description: JR's Country Store
23-0307-CS
Dear Flora D'Souza:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/31/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 49
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-090-0010
Page 2 of 49
Report Number:
Sample Summary Table
Client Project Description:
23-090-0010
JR's Country Store
23-0307-CS
Lab No Client Sample ID Matrix Date Collected Date Received
03/29/2023 11:20Aqueous 92666 MW-1 03/31/2023 12:00
03/29/2023 11:55Aqueous 92667 MW-2R 03/31/2023 12:00
03/29/2023 12:30Aqueous 92668 MW-5 03/31/2023 12:00
03/29/2023 13:05Aqueous 92669 MW-8 03/31/2023 12:00
03/29/2023 13:35Aqueous 92670 MW-9 03/31/2023 12:00
03/29/2023 14:35Aqueous 92671 WSW-1B 03/31/2023 12:00
03/29/2023 14:10Aqueous 92672 WSW-2 03/31/2023 12:00
03/29/2023 15:25Aqueous 92673 WSW-6 03/31/2023 12:00
03/29/2023 13:45Aqueous 92674 Field Blank 03/31/2023 12:00
Page 3 of 49
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-090-0010
Report Limit
Project:JR's Country Store
V 92666MW-1
2.02 04/08/2023 05:166200BDi-Isopropyl Ether (DIPE)µg/L 0.500
26.0 04/08/2023 05:166200BMethyl tert-butyl ether (MTBE)µg/L 1.00
V 92667MW-2R
0.754 04/08/2023 05:406200BDi-Isopropyl Ether (DIPE)µg/L 0.500
2.44 04/08/2023 05:406200BMethyl tert-butyl ether (MTBE)µg/L 1.00
V 92668MW-5
5.00 04/08/2023 06:056200BDi-Isopropyl Ether (DIPE)µg/L 0.500
14.0 04/08/2023 06:056200BMethyl tert-butyl ether (MTBE)µg/L 1.00
V 92669MW-8
190 04/08/2023 09:216200BDi-Isopropyl Ether (DIPE)µg/L 5.00
862 04/08/2023 09:216200BMethyl tert-butyl ether (MTBE)µg/L 10.0
V 92672WSW-2
2.12 04/08/2023 07:186200BDi-Isopropyl Ether (DIPE)µg/L 0.500
12.9 04/08/2023 07:186200BMethyl tert-butyl ether (MTBE)µg/L 1.00
V 92673WSW-6
2.84 04/08/2023 07:436200BMethyl tert-butyl ether (MTBE)µg/L 1.00
Page 4 of 49

Client: Withers & Ravenel CASE NARRATIVE
Project: JR's Country Store Lab Report Number: 23-090-0010
Date: 4/10/2023
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,2,3-Trichlorobenzene QC Batch No: V31821/V31818
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 1,2,4-Trichlorobenzene QC Batch No: V31821/V31818
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 2-Hexanone QC Batch No: V31821/V31818
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 4-Methyl-2-pentanone QC Batch No: V31821/V31818
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits. Analyte: Acetone QC Batch No: V31821/V31818
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V31821/V31818
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: Ethanol QC Batch No: V31821/V31818
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable. Analyte: Ethanol QC Batch No: V31821/V31818
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 5 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-1
92666 Matrix:
3/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 05:16 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 05:16 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 05:16 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 05:16 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 05:16 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 05:16 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 05:16 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 6 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-1
92666 Matrix:
3/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 05:16 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 05:16 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 05:16 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 05:16 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 05:16 6200BMSA
2.02 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 05:16 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 05:16 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 05:16 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 05:16 6200BMSA
26.0 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 05:16 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 7 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-1
92666 Matrix:
3/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 05:16 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 05:16 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 05:16 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 05:16 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 05:16 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 8 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-1
92666 Matrix:
3/29/2023 11:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 05:16 6200B
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%04/08/23 05:161 MSA V31821
Surrogate: Dibromofluoromethane 101 Limits: 70-130%04/08/23 05:161 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%04/08/23 05:161 MSA V31821
Surrogate: Toluene-d8 102 Limits: 70-130%04/08/23 05:161 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 9 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-2R
92667 Matrix:
3/29/2023 11:55
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 05:40 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 05:40 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 05:40 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 05:40 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 05:40 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 05:40 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 05:40 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 10 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-2R
92667 Matrix:
3/29/2023 11:55
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 05:40 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 05:40 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 05:40 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 05:40 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 05:40 6200BMSA
0.754 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 05:40 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 05:40 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 05:40 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 05:40 6200BMSA
2.44 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 05:40 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 11 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-2R
92667 Matrix:
3/29/2023 11:55
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 05:40 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 05:40 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 05:40 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 05:40 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 05:40 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 12 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-2R
92667 Matrix:
3/29/2023 11:55
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 05:40 6200B
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%04/08/23 05:401 MSA V31821
Surrogate: Dibromofluoromethane 101 Limits: 70-130%04/08/23 05:401 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 103 Limits: 70-130%04/08/23 05:401 MSA V31821
Surrogate: Toluene-d8 101 Limits: 70-130%04/08/23 05:401 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 13 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-5
92668 Matrix:
3/29/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 06:05 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 06:05 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 06:05 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 06:05 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 06:05 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 06:05 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 06:05 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 14 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-5
92668 Matrix:
3/29/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 06:05 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 06:05 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 06:05 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 06:05 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 06:05 6200BMSA
5.00 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 06:05 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 06:05 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 06:05 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 06:05 6200BMSA
14.0 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 06:05 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 15 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-5
92668 Matrix:
3/29/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 06:05 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 06:05 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 06:05 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 06:05 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 06:05 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 16 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-5
92668 Matrix:
3/29/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 06:05 6200B
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%04/08/23 06:051 MSA V31821
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%04/08/23 06:051 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%04/08/23 06:051 MSA V31821
Surrogate: Toluene-d8 100 Limits: 70-130%04/08/23 06:051 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 17 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-8
92669 Matrix:
3/29/2023 13:05
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100Acetone 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Benzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Bromobenzene 10 04/08/23 09:21 6200BMSA
<10.0 µg/L 10.0Bromochloromethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Bromodichloromethane 10 04/08/23 09:21 6200BMSA
<50.0 µg/L 50.0Bromoform 10 04/08/23 09:21 6200BMSA
<10.0 µg/L 10.0Bromomethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00n-Butylbenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00sec-Butyl benzene 10 04/08/23 09:21 6200BMSA
<20.0 µg/L 20.0tert-Butyl benzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Carbon Tetrachloride 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Chlorobenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Chlorodibromomethane 10 04/08/23 09:21 6200BMSA
<10.0 µg/L 10.0Chloroethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Chloroform 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Chloromethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.002-Chlorotoluene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.004-Chlorotoluene 10 04/08/23 09:21 6200BMSA
<20.0 µg/L 20.01,2-Dibromo-3-Chloropropane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2-Dibromoethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Dibromomethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2-Dichlorobenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,3-Dichlorobenzene 10 04/08/23 09:21 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 18 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-8
92669 Matrix:
3/29/2023 13:05
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<5.00 µg/L 5.001,4-Dichlorobenzene 10 04/08/23 09:21 6200BMSA
<50.0 µg/L 50.0Dichlorodifluoromethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,1-Dichloroethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2-Dichloroethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,1-Dichloroethene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00cis-1,2-Dichloroethene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00trans-1,2-Dichloroethene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2-Dichloropropane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,3-Dichloropropane 10 04/08/23 09:21 6200BMSA
<20.0 µg/L 20.02,2-Dichloropropane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,1-Dichloropropene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00cis-1,3-Dichloropropene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00trans-1,3-Dichloropropene 10 04/08/23 09:21 6200BMSA
<2000 µg/L 2000Ethanol 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Ethylbenzene 10 04/08/23 09:21 6200BMSA
<30.0 µg/L 30.0Hexachlorobutadiene 10 04/08/23 09:21 6200BMSA
190 µg/L 5.00Di-Isopropyl Ether (DIPE)10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Isopropylbenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.004-Isopropyl toluene 10 04/08/23 09:21 6200BMSA
<10.0 µg/L 10.02-Hexanone 10 04/08/23 09:21 6200BMSA
<50.0 µg/L 50.0Methyl Ethyl Ketone (MEK)10 04/08/23 09:21 6200BMSA
<20.0 µg/L 20.0Methylene Chloride 10 04/08/23 09:21 6200BMSA
862 µg/L 10.0Methyl tert-butyl ether (MTBE)10 04/08/23 09:21 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 19 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-8
92669 Matrix:
3/29/2023 13:05
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.04-Methyl-2-Pentanone 10 04/08/23 09:21 6200BMSA
<10.0 µg/L 10.0Naphthalene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00n-Propylbenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Styrene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,1,1,2-Tetrachloroethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,1,2,2-Tetrachloroethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Tetrachloroethene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Toluene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2,3-Trichlorobenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2,4-Trichlorobenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,1,1-Trichloroethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,1,2-Trichloroethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Trichloroethene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Trichlorofluoromethane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2,3-Trichloropropane 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,2,4-Trimethylbenzene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.001,3,5-Trimethylbenzene 10 04/08/23 09:21 6200BMSA
<50.0 µg/L 50.0Vinyl Acetate 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00Vinyl Chloride 10 04/08/23 09:21 6200BMSA
<10.0 µg/L 10.0m,p-Xylene 10 04/08/23 09:21 6200BMSA
<5.00 µg/L 5.00o-Xylene 10 04/08/23 09:21 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 20 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-8
92669 Matrix:
3/29/2023 13:05
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<5.00 µg/L 5.00Xylene (Total)10 04/08/23 09:21 6200B
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%04/08/23 09:2110 MSA V31821
Surrogate: Dibromofluoromethane 100 Limits: 70-130%04/08/23 09:2110 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%04/08/23 09:2110 MSA V31821
Surrogate: Toluene-d8 100 Limits: 70-130%04/08/23 09:2110 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 21 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-9
92670 Matrix:
3/29/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 06:30 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 06:30 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 06:30 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 06:30 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 06:30 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 06:30 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 06:30 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 22 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-9
92670 Matrix:
3/29/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 06:30 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 06:30 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 06:30 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 06:30 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 06:30 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 06:30 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 06:30 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 06:30 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 06:30 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 23 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-9
92670 Matrix:
3/29/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 06:30 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 06:30 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 06:30 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 06:30 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 06:30 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 24 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:MW-9
92670 Matrix:
3/29/2023 13:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 06:30 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/08/23 06:301 MSA V31821
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%04/08/23 06:301 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 98.6 Limits: 70-130%04/08/23 06:301 MSA V31821
Surrogate: Toluene-d8 101 Limits: 70-130%04/08/23 06:301 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 25 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-1B
92671 Matrix:
3/29/2023 14:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 06:54 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 06:54 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 06:54 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 06:54 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 06:54 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 06:54 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 06:54 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 26 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-1B
92671 Matrix:
3/29/2023 14:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 06:54 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 06:54 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 06:54 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 06:54 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 06:54 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 06:54 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 06:54 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 06:54 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 06:54 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 27 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-1B
92671 Matrix:
3/29/2023 14:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 06:54 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 06:54 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 06:54 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 06:54 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 06:54 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 28 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-1B
92671 Matrix:
3/29/2023 14:35
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 06:54 6200B
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%04/08/23 06:541 MSA V31821
Surrogate: Dibromofluoromethane 101 Limits: 70-130%04/08/23 06:541 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%04/08/23 06:541 MSA V31821
Surrogate: Toluene-d8 99.4 Limits: 70-130%04/08/23 06:541 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 29 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-2
92672 Matrix:
3/29/2023 14:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 07:18 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 07:18 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 07:18 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 07:18 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 07:18 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 07:18 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 07:18 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 30 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-2
92672 Matrix:
3/29/2023 14:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 07:18 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 07:18 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 07:18 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 07:18 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 07:18 6200BMSA
2.12 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 07:18 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 07:18 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 07:18 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 07:18 6200BMSA
12.9 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 07:18 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 31 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-2
92672 Matrix:
3/29/2023 14:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 07:18 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 07:18 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 07:18 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 07:18 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 07:18 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 32 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-2
92672 Matrix:
3/29/2023 14:10
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 07:18 6200B
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%04/08/23 07:181 MSA V31821
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%04/08/23 07:181 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%04/08/23 07:181 MSA V31821
Surrogate: Toluene-d8 100 Limits: 70-130%04/08/23 07:181 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 33 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-6
92673 Matrix:
3/29/2023 15:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 07:43 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 07:43 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 07:43 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 07:43 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 07:43 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 07:43 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 07:43 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 34 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-6
92673 Matrix:
3/29/2023 15:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 07:43 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 07:43 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 07:43 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 07:43 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 07:43 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 07:43 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 07:43 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 07:43 6200BMSA
2.84 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 07:43 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 35 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-6
92673 Matrix:
3/29/2023 15:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 07:43 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 07:43 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 07:43 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 07:43 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 07:43 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 36 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:WSW-6
92673 Matrix:
3/29/2023 15:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 07:43 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/08/23 07:431 MSA V31821
Surrogate: Dibromofluoromethane 104 Limits: 70-130%04/08/23 07:431 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%04/08/23 07:431 MSA V31821
Surrogate: Toluene-d8 98.6 Limits: 70-130%04/08/23 07:431 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 37 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:Field Blank
92674 Matrix:
3/29/2023 13:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/08/23 08:07 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/08/23 08:07 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/08/23 08:07 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/08/23 08:07 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/08/23 08:07 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/08/23 08:07 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/08/23 08:07 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 38 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:Field Blank
92674 Matrix:
3/29/2023 13:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/08/23 08:07 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/08/23 08:07 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/08/23 08:07 6200BMSA
<200 µg/L 200Ethanol 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/08/23 08:07 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/08/23 08:07 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/08/23 08:07 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/08/23 08:07 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/08/23 08:07 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/08/23 08:07 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 39 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:Field Blank
92674 Matrix:
3/29/2023 13:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/08/23 08:07 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/08/23 08:07 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/08/23 08:07 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/08/23 08:07 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/08/23 08:07 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 40 of 49
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-090-0010
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Flora D'Souza
Cary
23-0307-CS Received : 03/31/2023
JR's Country Store
Report Date : 04/11/2023
Sample ID :
Lab No :
Sampled:Field Blank
92674 Matrix:
3/29/2023 13:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/08/23 08:07 6200B
Surrogate: 4-Bromofluorobenzene 104 Limits: 70-130%04/08/23 08:071 MSA V31821
Surrogate: Dibromofluoromethane 102 Limits: 70-130%04/08/23 08:071 MSA V31821
Surrogate: 1,2-Dichloroethane - d4 104 Limits: 70-130%04/08/23 08:071 MSA V31821
Surrogate: Toluene-d8 100 Limits: 70-130%04/08/23 08:071 MSA V31821
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 41 of 49
Quality Control Data
23-090-0010Report No:
Project Description:
Client ID:Withers & Ravenel
JR's Country Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31821QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31818
Associated Lab Samples: 92666, 92667, 92668, 92669, 92670, 92671, 92672, 92673, 92674
LRB-V31818 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/08/23 02:2510.0< 10.0µg/LAcetone
04/08/23 02:250.500< 0.500µg/LBenzene
04/08/23 02:250.500< 0.500µg/LBromobenzene
04/08/23 02:251.00< 1.00µg/LBromochloromethane
04/08/23 02:250.500< 0.500µg/LBromodichloromethane
04/08/23 02:255.00< 5.00µg/LBromoform
04/08/23 02:251.00< 1.00µg/LBromomethane
04/08/23 02:250.500< 0.500µg/Ln-Butylbenzene
04/08/23 02:250.500< 0.500µg/Lsec-Butyl benzene
04/08/23 02:252.00< 2.00µg/Ltert-Butyl benzene
04/08/23 02:250.500< 0.500µg/LCarbon Tetrachloride
04/08/23 02:250.500< 0.500µg/LChlorobenzene
04/08/23 02:250.500< 0.500µg/LChlorodibromomethane
04/08/23 02:251.00< 1.00µg/LChloroethane
04/08/23 02:250.500< 0.500µg/LChloroform
04/08/23 02:250.500< 0.500µg/LChloromethane
04/08/23 02:250.500< 0.500µg/L2-Chlorotoluene
04/08/23 02:250.500< 0.500µg/L4-Chlorotoluene
04/08/23 02:252.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
04/08/23 02:250.500< 0.500µg/L1,2-Dibromoethane
04/08/23 02:250.500< 0.500µg/LDibromomethane
04/08/23 02:250.500< 0.500µg/L1,2-Dichlorobenzene
04/08/23 02:250.500< 0.500µg/L1,3-Dichlorobenzene
04/08/23 02:250.500< 0.500µg/L1,4-Dichlorobenzene
04/08/23 02:255.00< 5.00µg/LDichlorodifluoromethane
04/08/23 02:250.500< 0.500µg/L1,1-Dichloroethane
04/08/23 02:250.500< 0.500µg/L1,2-Dichloroethane
Page 1 of 6Date:04/11/2023 10:26 AM
Page 42 of 49
Quality Control Data
23-090-0010Report No:
Project Description:
Client ID:Withers & Ravenel
JR's Country Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31821QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31818
Associated Lab Samples: 92666, 92667, 92668, 92669, 92670, 92671, 92672, 92673, 92674
LRB-V31818 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/08/23 02:250.500< 0.500µg/L1,1-Dichloroethene
04/08/23 02:250.500< 0.500µg/Lcis-1,2-Dichloroethene
04/08/23 02:250.500< 0.500µg/Ltrans-1,2-Dichloroethene
04/08/23 02:250.500< 0.500µg/L1,2-Dichloropropane
04/08/23 02:250.500< 0.500µg/L1,3-Dichloropropane
04/08/23 02:252.00< 2.00µg/L2,2-Dichloropropane
04/08/23 02:250.500< 0.500µg/L1,1-Dichloropropene
04/08/23 02:250.500< 0.500µg/Lcis-1,3-Dichloropropene
04/08/23 02:250.500< 0.500µg/Ltrans-1,3-Dichloropropene
04/08/23 02:25200< 200µg/LEthanol
04/08/23 02:250.500< 0.500µg/LEthylbenzene
04/08/23 02:253.00< 3.00µg/LHexachlorobutadiene
04/08/23 02:250.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
04/08/23 02:250.500< 0.500µg/LIsopropylbenzene
04/08/23 02:250.500< 0.500µg/L4-Isopropyl toluene
04/08/23 02:251.00< 1.00µg/L2-Hexanone
04/08/23 02:255.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
04/08/23 02:252.00< 2.00µg/LMethylene Chloride
04/08/23 02:251.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
04/08/23 02:251.00< 1.00µg/L4-Methyl-2-Pentanone
04/08/23 02:251.00< 1.00µg/LNaphthalene
04/08/23 02:250.500< 0.500µg/Ln-Propylbenzene
04/08/23 02:250.500< 0.500µg/LStyrene
04/08/23 02:250.500< 0.500µg/L1,1,1,2-Tetrachloroethane
04/08/23 02:250.500< 0.500µg/L1,1,2,2-Tetrachloroethane
04/08/23 02:250.500< 0.500µg/LTetrachloroethene
04/08/23 02:250.500< 0.500µg/LToluene
Page 2 of 6Date:04/11/2023 10:26 AM
Page 43 of 49
Quality Control Data
23-090-0010Report No:
Project Description:
Client ID:Withers & Ravenel
JR's Country Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31821QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31818
Associated Lab Samples: 92666, 92667, 92668, 92669, 92670, 92671, 92672, 92673, 92674
LRB-V31818 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/08/23 02:250.500< 0.500µg/L1,2,3-Trichlorobenzene
04/08/23 02:250.500< 0.500µg/L1,2,4-Trichlorobenzene
04/08/23 02:250.500< 0.500µg/L1,1,1-Trichloroethane
04/08/23 02:250.500< 0.500µg/L1,1,2-Trichloroethane
04/08/23 02:250.500< 0.500µg/LTrichloroethene
04/08/23 02:250.500< 0.500µg/LTrichlorofluoromethane
04/08/23 02:250.500< 0.500µg/L1,2,3-Trichloropropane
04/08/23 02:250.500< 0.500µg/L1,2,4-Trimethylbenzene
04/08/23 02:250.500< 0.500µg/L1,3,5-Trimethylbenzene
04/08/23 02:255.00< 5.00µg/LVinyl Acetate
04/08/23 02:250.500< 0.500µg/LVinyl Chloride
04/08/23 02:251.00< 1.00µg/Lm,p-Xylene
04/08/23 02:250.500< 0.500µg/Lo-Xylene
04/08/23 02:254-Bromofluorobenzene (S)104 70-130
04/08/23 02:25Dibromofluoromethane (S)102 70-130
04/08/23 02:251,2-Dichloroethane - d4 (S)101 70-130
04/08/23 02:25Toluene-d8 (S)99.6 70-130
LCS-V31818 LCSD-V31818Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
32.8 82.010240.840.0µg/LAcetone 40-160 21.7*20.0
19.8 99.010020.020.0µg/LBenzene 70-130 1.0 20.0
20.4 10210521.020.0µg/LBromobenzene 70-130 2.8 20.0
19.9 99.510420.820.0µg/LBromochloromethane 70-130 4.4 20.0
20.0 10010320.620.0µg/LBromodichloromethane 70-130 2.9 20.0
Page 3 of 6* QC Fail Date:04/11/2023 10:26 AM
Page 44 of 49
Quality Control Data
23-090-0010Report No:
Project Description:
Client ID:Withers & Ravenel
JR's Country Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31821QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31818
LCS-V31818 LCSD-V31818Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.1 11112324.620.0µg/LBromoform 70-130 10.7 20.0
21.4 10710320.620.0µg/LBromomethane 60-140 3.8 20.0
20.0 10010420.720.0µg/Ln-Butylbenzene 70-130 3.4 20.0
19.7 98.510220.320.0µg/Lsec-Butyl benzene 70-130 3.0 20.0
20.0 10010320.520.0µg/Ltert-Butyl benzene 70-130 2.4 20.0
20.2 10110420.820.0µg/LCarbon Tetrachloride 70-130 2.9 20.0
19.5 97.599.519.920.0µg/LChlorobenzene 70-130 2.0 20.0
21.5 10811422.820.0µg/LChlorodibromomethane 70-130 5.8 20.0
21.3 10711322.520.0µg/LChloroethane 60-140 5.4 20.0
20.1 10110220.320.0µg/LChloroform 70-130 0.9 20.0
20.5 10310821.520.0µg/LChloromethane 60-140 4.7 20.0
19.8 99.010120.220.0µg/L2-Chlorotoluene 70-130 2.0 20.0
20.4 10210420.820.0µg/L4-Chlorotoluene 70-130 1.9 20.0
25.5 128150*30.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 16.2 20.0
20.8 10411122.120.0µg/L1,2-Dibromoethane 70-130 6.0 20.0
20.6 10311322.520.0µg/LDibromomethane 70-130 8.8 20.0
20.5 10310721.320.0µg/L1,2-Dichlorobenzene 70-130 3.8 20.0
20.4 10210420.820.0µg/L1,3-Dichlorobenzene 70-130 1.9 20.0
19.5 97.510320.520.0µg/L1,4-Dichlorobenzene 70-130 5.0 20.0
22.3 11211923.720.0µg/LDichlorodifluoromethane 60-140 6.0 20.0
19.6 98.010120.120.0µg/L1,1-Dichloroethane 70-130 2.5 20.0
20.9 10510821.620.0µg/L1,2-Dichloroethane 70-130 3.2 20.0
19.0 95.098.519.720.0µg/L1,1-Dichloroethene 70-130 3.6 20.0
19.4 97.010120.120.0µg/Lcis-1,2-Dichloroethene 70-130 3.5 20.0
19.4 97.097.519.520.0µg/Ltrans-1,2-Dichloroethene 70-130 0.5 20.0
19.6 98.010120.220.0µg/L1,2-Dichloropropane 70-130 3.0 20.0
Page 4 of 6* QC Fail Date:04/11/2023 10:26 AM
Page 45 of 49
Quality Control Data
23-090-0010Report No:
Project Description:
Client ID:Withers & Ravenel
JR's Country Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31821QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31818
LCS-V31818 LCSD-V31818Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.7 98.510821.620.0µg/L1,3-Dichloropropane 70-130 9.2 20.0
17.8 89.093.518.720.0µg/L2,2-Dichloropropane 70-130 4.9 20.0
20.2 10110621.120.0µg/L1,1-Dichloropropene 70-130 4.3 20.0
19.7 98.598.019.620.0µg/Lcis-1,3-Dichloropropene 70-130 0.5 20.0
20.5 10310621.220.0µg/Ltrans-1,3-Dichloropropene 70-130 3.3 20.0
574 115145*725500µg/LEthanol 60-140 23.2*20.0
19.5 97.510120.120.0µg/LEthylbenzene 70-130 3.0 20.0
22.6 11311623.120.0µg/LHexachlorobutadiene 70-130 2.1 20.0
19.6 98.099.519.920.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.5 20.0
20.4 10210420.820.0µg/LIsopropylbenzene 70-130 1.9 20.0
20.0 10010320.520.0µg/L4-Isopropyl toluene 70-130 2.4 20.0
21.0 10514028.020.0µg/L2-Hexanone 60-140 28.5*20.0
20.8 10411522.920.0µg/LMethyl Ethyl Ketone (MEK)60-140 9.6 20.0
18.6 93.094.018.820.0µg/LMethylene Chloride 70-130 1.0 20.0
21.5 10811222.320.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.6 20.0
21.7 10913827.620.0µg/L4-Methyl-2-Pentanone 60-140 23.9*20.0
25.3 12712925.720.0µg/LNaphthalene 70-130 1.5 20.0
19.3 96.510120.120.0µg/Ln-Propylbenzene 70-130 4.0 20.0
20.2 10110120.220.0µg/LStyrene 70-130 0.0 20.0
20.5 10310721.420.0µg/L1,1,1,2-Tetrachloroethane 70-130 4.2 20.0
21.6 10812424.720.0µg/L1,1,2,2-Tetrachloroethane 70-130 13.3 20.0
19.9 99.510520.920.0µg/LTetrachloroethene 70-130 4.9 20.0
19.8 99.010320.620.0µg/LToluene 70-130 3.9 20.0
28.0 140*148*29.520.0µg/L1,2,3-Trichlorobenzene 70-130 5.2 20.0
26.1 131*134*26.720.0µg/L1,2,4-Trichlorobenzene 70-130 2.2 20.0
19.6 98.010120.120.0µg/L1,1,1-Trichloroethane 70-130 2.5 20.0
Page 5 of 6* QC Fail Date:04/11/2023 10:26 AM
Page 46 of 49
Quality Control Data
23-090-0010Report No:
Project Description:
Client ID:Withers & Ravenel
JR's Country Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31821QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31818
LCS-V31818 LCSD-V31818Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.9 11011522.920.0µg/L1,1,2-Trichloroethane 70-130 4.4 20.0
20.1 10110420.820.0µg/LTrichloroethene 70-130 3.4 20.0
21.7 10911623.220.0µg/LTrichlorofluoromethane 60-140 6.6 20.0
22.4 11212825.520.0µg/L1,2,3-Trichloropropane 70-130 12.9 20.0
20.3 10210520.920.0µg/L1,2,4-Trimethylbenzene 70-130 2.9 20.0
20.4 10210420.820.0µg/L1,3,5-Trimethylbenzene 70-130 1.9 20.0
21.1 10611422.820.0µg/LVinyl Acetate 60-140 7.7 20.0
22.0 11011422.820.0µg/LVinyl Chloride 60-140 3.5 20.0
40.5 10110642.240.0µg/Lm,p-Xylene 70-130 4.1 20.0
19.9 99.510220.320.0µg/Lo-Xylene 70-130 1.9 20.0
1021004-Bromofluorobenzene (S)70-130
101100Dibromofluoromethane (S)70-130
1061081,2-Dichloroethane - d4 (S)70-130
98.698.0Toluene-d8 (S)70-130
Page 6 of 6Date:04/11/2023 10:26 AM
Page 47 of 49
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-090-0010
Withers & Ravenel
01221
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 3.5C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:03/31/2023 12:22:06
Special precautions or instructions included?
Comments:
Page 48 of 49
Page 49 of 49
WithersRavenel
Our People. Your Success.

APPENDIX B FIELD NOTES & PHOTOGRAPHIC RECORD

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Our People. Your Success.

PHOTO 1 View of Site
PHOTO 2 View monitoring well MW-1 looking east
WithersRavenel
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PHOTO 3 View of monitoring well MW-2R looking east
PHOTO 4 View of monitoring well MW-5 looking south
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PHOTO 5 View of monitoring well MW-8 looking west
PHOTO 5 View of monitoring well MW-9 looking north
WithersRavenel
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APPENDIX C GENERAL STANDARD OPERATING PROCEDURES
Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
Our People. Your Success.
Soil Sampling, Soil Boring and Monitor Well Installation, Well Development Soil borings are installed utilizing a stainless-steel hand auger, direct-push hydraulic drill or auger rotary
drill using either a macro core™ sampler, hollow stem augers, or air rotary roller cone bit. Soil borings are
typically sampled at discrete intervals from the bucket of a clean stainless steel hand auger, direct push stainless steel sampler with acetate sleeve, or a split barrel sampler. When appropriate, soil samples may be collected from drill cuttings associated with the boring or well installation. Monitor wells are constructed within select soil borings of one, two, or four-inch inside diameter PVC
casing and machine slotted screen in accordance with NCAC Title 15A, Subchapter 02C (Well Construction Standards, Criteria and Standards Applicable to Water Supply and Certain Other Wells). Clean-washed “#2 Torpedo Sand” is typically utilized to fill the boring annulus surrounding the well screen, extending to a minimum of 1-foot above the well screen. A minimum 1-foot thick bentonite clay seal is emplaced above the sand pack and hydrated. Neat cement grout is placed in the remaining annulus
space from the upper portion of the bentonite seal to within 1-foot of surface grade. In coastal plain areas where shallow groundwater is encountered, a variance to construction standards may be employed to ensure the upper portion of the well screen intersects the upper aquifer surface. Wellheads may be completed with either concrete-set flush mounted traffic-bearing steel skirted manholes with bolt down covers or steel above-ground “stick-up” well protectors set in a concrete pad. The monitoring wells are
secured with locking caps. Temporary wells or piezometers may be completed with the PVC riser cut at or above grade, and are abandoned within 24-hours of their installation. Wells may be developed using a bailer, electric submersible pump, pneumatic pump, or peristaltic pump, dependent upon site conditions. When wells are developed by the driller, they may be developed with
any of the methods outlined above, in addition to air or water injection. Soil boring logs and well construction details are typically prepared for presentation in a report appendix. Borings completed in bedrock may be drilled using air rotary, coring, or sonic drilling methods. Groundwater Depth to Water Measurements

Groundwater level measurements are typically obtained using an electronic water level indicator which registers a tone and/or illuminated light when the probe contacts groundwater. Depth to groundwater measurements are obtained by lowering the probe attached to a cable usually marked in 0.01 foot intervals into the well until the probe of the meter intersects the water surface. The measurement from
the top of the riser pipe or top of casing (TOC) to the water level is recorded to the nearest 0.01 foot. The
electronic water level indicator probe and exposed probe cable is decontaminated between measurement locations.

Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
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Free Product Level Measurements Light Non-Aqueous Phase Liquid (LNAPL) or “free product” present on the water table is measured using
an electronic oil/water interface probe. The interface probe has both an audible and illuminating light
that indicate when a liquid level is encountered. The oil/water interface probe registers a solid tone and solidly lit light when LNAPL petroleum product is encountered and a beeping tone flashing light when groundwater is encountered. Depth to LNAPL measurements are obtained by lowering the probe attached to a cable marked in 0.01 foot intervals into the well until the probe of the meter intersects the product or groundwater. The measurements from the top of the riser pipe or TOC to the liquid level are
recorded to the nearest 0.01 foot. The thickness of LNAPL is calculated by subtracting the depth to LNAPL measurement from the depth to groundwater measurement. The electronic interface probe is decontaminated between measurement locations. Soil Sampling and Field Screening
Soil sampling is performed in general accordance with ASTM: 1586-84 where applicable. Sampling procedures are followed to protect the chemical integrity of the soil samples and minimize the potential for cross contamination between sample locations, including discarding of the exterior of the sample which contacts the auger bucket, acetate sleeve, or split barrel sampler, the use of stainless steel sampling
equipment, and the thorough decontamination of sampling apparatus prior to use and between sample locations. Soil samples retained as a part of excavation or other intrusive “digging” activities may be collected from the bucket of excavation equipment or using a hand shovel, if appropriate. Care to collect soil samples
from excavation equipment includes retrieving native soil from material that has not made contact with the excavating equipment. Samples are collected in sealable bags or by directly filling sample containers as described above. Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample
integrity and minimize the potential for cross contamination or field personnel exposure to contaminants.
Sampling equipment such as hand auger extensions and buckets, direct push samplers, split spoons or shovels, are decontaminated prior to their use in the collection of samples. Samples are placed within laboratory grade sample containers provided by the laboratory to which the
samples are submitted, labeled, sealed, and placed in an ice filled cooler. An aliquot of the sample is
typically placed in a clean sealable bag and allowed to reach ambient air temperature for future screening of volatile vapor content with a photoionization detector (PID), flame-ionization detector (FID) or other portable screening device.
Screening of samples with a PID, FID or other field screening device is performed in accordance with
device manufacturer specifications for screening, following calibration of the instrument based on manufacturer recommended procedures.

Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
Our People. Your Success.
Groundwater Sampling Groundwater samples are generally collected using one of three standard methods – through the use of a
dedicated, disposable bailer, a peristaltic pump or submersible electric pump.
When sampling with a bailer, a minimum of three well volumes of groundwater are extracted from the well as a means of purging, unless the well is purged to a “dry” state prior to the removal of three volumes of water. Prior to collection of the groundwater sample with the bailer, the water level is allowed to recover to within 80% of the original level measured prior to purging.
When sampling with a peristaltic or submersible electric pump, polyethylene (PE) tubing (or equivalent) is emplaced into the screened section of the monitoring well, and the pump is used to extract water through the tubing. When using the either of these methods, general water quality measurements including but not limited to pH, temperature, dissolved oxygen (DO), oxygen reductive potential (ORP), specific
conductivity and turbidity may be used as methods for determining when an adequate purge of the well has been conducted. When water quality parameters are measured, the resulting data are included in well purge forms or field notes specific to each site and sampling point. Following the purging of three well volumes of groundwater (in the case of the bailed well) or stability of
monitored measurements (in the case of the peristaltic or submersible electric pump), the groundwater sample(s) are introduced directly into sample containers provided by the laboratory to which samples are ultimately submitted for analysis. Any samples requiring chemical preservation are contained in pre-preserved container(s) provided by the laboratory.
Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample integrity and minimize the potential for cross contamination of samples or field personnel exposure to contaminants. Water Supply Well Sampling

Sampling of water supply wells is accomplished through the collection of a representative sample from an in-line water tap or other point accessible for sampling. Where possible, the sample is collected from a point prior to any filtration or point of entry (POE) system which might be installed on a well. In some cases, samples will be collected from both pre and post-POE locations. Prior to the collection of samples
through an in-place sampling point, the tap or sampling port is cleaned with an Alconox® and deionized
water solution, rinsed with deionized water, and again with an isopropyl alcohol (IPA) rinse. In the case of active supply wells (e.g., a well with a useable well pump with an active power supply), the well pump is energized and allowed to run for a minimum of ten (10) minutes time, after which a sample is
contained in laboratory grade sample containers as described in the previous section. Water quality
parameters may be (but are not necessarily) measured in association with the well purging. Supply wells without active power supplies are not generally sampled, as the well seal cannot be compromised by individuals not certified as a well contractor. However, in the case of a well with no
power supply or pump installed, samples could be obtained through the use of a bailer, peristaltic pump or
electric submersible pump.
Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
Our People. Your Success.
Decontamination Procedures Decontamination procedures employed in the performance of field activities will vary dependent upon
the method(s) of sampling performed at any site, but will generally include the following:
• Remove excess soil/sludge from any sampling equipment as needed, • Wash and scrub the equipment with a phosphate-free detergent such as Alconox® or Liquinox® in a contaminant-free tap water solution. Use a brush to remove particulate matter and surface films as necessary,
• Rinse thoroughly with tap water, • Rinse thoroughly with analyte-free water (deionized water),
 Rinse thoroughly with isopropyl alcohol, • Allow the equipment to air dry,
• Prevent inadvertent contamination during storage and transport (accomplished through storage of equipment in foil or plastic bags/sheeting). In the case of disposable bailers and tubing utilized for the purging and sampling of wells, these items may be decontaminated prior to their disposal. In general, no decontamination of these items is necessary
prior to their use in sampling.