AS-1188_12487_CA_MRP_20230523

WithersRavenel
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115 MacKenan Drive | Cary, NC 27511
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F-1479
ASHEVILLE | CARY | CHARLOTTE | GREENSBORO | LUMBERTON | PITTSBORO | RALEIGH | SOUTHERN PINES | WILMINGTON

MONITORING REPORT

(Former) Whitaker’s Service Station
NCDEQ Incident #12487
UST # AS-1188
4900 Ellenboro Road
Mooresboro, Cleveland County, North Carolina
WithersRavenel Project No. 23-0307-EY

Prepared for:
State of North Carolina Department of Environmental Quality Division of Waste Management Underground Storage Tank Section Federal & State Lead Program 1646 Mail Service Center Raleigh, North Carolina 27699-1646
Prepared by:
WithersRavenel
115 MacKenan Drive
Cary, North Carolina 27511
North Carolina Firm License No. F-1479
May 23, 2023

WithersRavenel
Our People. Your Success.
115 MacKenan Drive | Cary, NC 27511
t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F-1479
ASHEVILLE | CARY | CHARLOTTE | GREENSBORO | LUMBERTON | PITTSBORO | RALEIGH | SOUTHERN PINES | WILMINGTON

May 23, 2023

State of North Carolina Department of Environmental Quality Federal & State Lead Program Division of Waste Management-Underground Storage Tank Section 1646 Mail Service Center
Raleigh, North Carolina 27699-1646 Attn: Ms. Sharon Ghiold Re: Monitoring Report (Former) Whitaker’s Service Station 4900 Ellenboro Road Mooresboro, Cleveland County, North Carolina Groundwater Incident Number: 12487 UST Number: AS-1188 WR Project Number: 23-0307-EY
Ms. Ghiold:
WithersRavenel, Inc. (WR) has completed this Monitoring Report to document the groundwater sampling activities completed at the site in association with our proposal, numbered Task Authorization (TA)-01, for the above referenced site, approved by the Federal & State Lead
Program on March 17, 2023. The enclosed report summarizes results of the recently completed
monitoring activities. WR appreciates the opportunity to be of service to the Federal & State Lead Program. Should you have any questions regarding the attached, please contact us at [phone].
Cordially, WithersRavenel

Flora D’Souza, CHMM Elizabeth A. Allyn, P.G.
Environmental Project Scientist II Environmental Project Geologist II
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Former Whitaker’s Service Station – NCDEQ Incident #12487 WR Project # 23-0307-EY Monitoring Report May 2023 i
TABLE OF CONTENTS

SECTION A. SITE INFORMATION ..................................................................................................................... 1
SECTION B. EXECUTIVE SUMMARY ................................................................................................................ 3
SECTION C. SITE HISTORY AND CHARACTERIZATION ............................................................................ 5
SECTION D. GROUNDWATER SAMPLING – MARCH 2023 ..................................................................... 9
SECTION E. CONCLUSIONS AND RECOMMENDATIONS ..................................................................... 10

FIGURES
Figure 1 General Location Map
Figure 2 Site Map
Figure 3 Groundwater Elevation Map – March 2023
Figure 4 Groundwater Analytical Results Map – March 2023
Figure 5 Receptor Map

TABLES
Table B-1 Site History: UST/AST System & Other Release Information
Table B-4 Summary of Groundwater Analytical Results
Table B-5A Public & Private Water Supply Well Information
Table B-7 Monitoring Well Construction Information and Liquid Level Data

APPENDICES
Appendix A Laboratory Analytical Report and Chain-of-Custody
Appendix B Field Notes and Photographic Record
Appendix C General Standard Operating Procedures

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Former Whitaker’s Service Station – NCDEQ Incident #12487 WR Project # 23-0307-EY Monitoring Report May 2023 1
SECTION A. SITE INFORMATION
1. Site Identification
Date of Report: May 23, 2023
Facility I.D.: 00-0-0000033009
Incident No.: 12487
UST No.: AS-1188
Site Risk: High
Site Rank: H355D
Land Use Category: Residential
Site Name: (Former) Whitaker’s Service Station
Site Location: 4900 Ellenboro Road
Nearest City/Town: Mooresboro
County: Cleveland
Description of Geographical Data Point: Center of Site
Location Method: Google Earth
Latitude: 35.304369° N
Longitude: -81.718544° W
2. Contact Information
Responsible Party: James Whitaker Whitakers Service Station (Dissolved)

Property Owner: Brenda Jean McGaha
Address: 118 Gene McGaha Lane, Mooresboro, NC 28114
Phone: Unknown

Consultant/Contractor: WithersRavenel
Address: 115 MacKenan Drive, Cary, NC 27511
Phone: [phone]

Analytical Laboratory: Waypoint Analytical, Inc.
State Certification Number: ENV402
Address: 449 Springbrook Rd., Charlotte, NC 28217
Phone: [phone]

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Former Whitaker’s Service Station – NCDEQ Incident #12487 WR Project # 23-0307-EY Monitoring Report May 2023 3
SECTION B. EXECUTIVE SUMMARY
1. Summary of Activities Associated with Current TA
WithersRavenel, Inc. (WR) conducted a groundwater sampling event at the former Whitaker’s Service Station site in Mooresboro, Cleveland County, North Carolina in association with task authorization (TA) TA-01 under North Carolina Department of Environmental Quality (NCDEQ) Contract #N70522-C. The scope of work for this project included the gauging, purging, and
sampling of existing monitoring wells MW-1, MW-2, and MW-3, and water supply well SW-E Blanton. A field blank was also analyzed as a part of this TA. 2. Soil, Groundwater and LNAPL Assessment Information

Soils No soil samples were collected by WR in association with this task authorization. Laboratory results for soil samples obtained at the time of underground storage tank (UST) closures in June 1994 showed gasoline range organic (GRO) and/or diesel range organic (DRO) total petroleum hydrocarbon (TPH) in several samples at concentrations exceeding the regulatory limits in place at
the time of closures. TPH GRO was detected at 2,562 milligrams per kilogram (mg/kg) at approximately two to three feet beneath the former 1,000-gallon gasoline UST of basin #3 which contained one 1,000-gallon gasoline UST and one 2,000-gallon gasoline UST. Data for soil samples collected in association with completion of a Limited Site Assessment (LSA) at the location showed several compounds at concentrations exceeding Soil to Groundwater Maximum Soil Contaminant
Concentrations (MSCCs) in soil samples collected from soil borings for monitoring wells MW-1 and MW-2. No petroleum constituents were detected above Soil to Groundwater MSCCS in soil samples collected from monitoring well MW-3.
Groundwater
WR collected groundwater samples from site monitoring wells MW-1, MW-2, and MW-3 and water supply well SW-E. Blanton on March 24, 2023. The groundwater samples were submitted for laboratory analysis of VOCs by SM6200B. A field blank was also submitted for analysis of VOCs by SM6200B.
• Laboratory analytical results indicated that benzene and naphthalene exceeded the 15A NCAC 2L Groundwater Quality Standards (2L Standards) in monitoring well MW-2.
• Laboratory analytical results indicated that monitoring well MW-1 contained acetone above the method detection limits but below the 2L Standards.
• MTBE was reported at a concentration below the 2L Standard in water supply well SW-E.
Blanton.
• Analytical data for monitoring well MW-3 and the field blank did not report any compounds
above the method detection limits.

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Light Non-Aqueous Phase Liquid (LNAPL) LNAPL was not identified during the March 24, 2023 sampling event. LNAPL was previously observed in monitoring well MW-2 in October 2010 and July 2011.
3. Receptor Information According to historical information, there are five active water supply wells within 1,000-feet of the subject property. Four of the supply wells are located between 320 and 435 feet from the source area and one well is located approximately 980 feet from the source area. Surface water
bodies were not identified within 500 feet of the source area. Potable water is supplied to the local area by the Cleveland County Water Department.
4. Remediation Activities
Based on WR’s review of historical files available for the site, the following remedial activities have been completed at the location:
• 2009 – Bio-Soks were installed in MW-1, MW-2, and MW-3. Based on currently available information, no additional remedial actions have been performed at the site.

5. Recommendations Based on the results of assessment and monitoring activities conducted at the site in association with this TA, WR recommends the following:

• Semi-annual monitoring of onsite monitoring wells and SW-E. Blanton.
• Attempt to install a new water supply well between 250’ to 500’ from the existing SW-E. Blanton well.
• Collect one soil sample at 15’ below ground surface (bgs) near MW-1 to determine if C9-C22 Aromatics remain above Residential MSCCs.
• Install shallower monitoring wells near MW-2 and MW-3 where the water table is within the
well screen.
• If funding is available, conduct a Remedial Design Characterization (RDC) to further characterize the extent of contamination in the subsurface to design an appropriate remedial
strategy.

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Former Whitaker’s Service Station – NCDEQ Incident #12487 WR Project # 23-0307-EY Monitoring Report May 2023 5
SECTION C. SITE HISTORY AND CHARACTERIZATION WR has completed a groundwater sampling event for the referenced site in association with TA-01 at the facility. The following information summarizes the site history and characterization.
1. UST Information The site is located at 4900 Ellenboro Road in Mooresboro, Cleveland County, NC (Figure 1). The site is currently vacant but formerly operated as a convenience store with commercial fuel sales.
The initial release was reported in June 1994 and associated with leaking gasoline and kerosene USTs. According to historical reports, three 1,000-gallon gasoline USTs, one 2,000-gallon gasoline UST, and one 550-gallon kerosene UST were present on the subject property. The five USTs were reportedly removed on June 28, 1994. Soil samples obtained from the site in association with UST closure indicated impacts by total petroleum hydrocarbons (TPH) at levels exceeding NC action
levels in the area of the former petroleum USTs. 2. Description of Release/General Assessment History The following summary of the assessment history is based on WR’s review of historical files for
the subject incident:
• June 1994 – Southeastern Geological Services removed three 1,000-gallon gasoline USTs, one
2,000-gallon gasoline UST, and one 550-gallon kerosene UST. A gasoline release was reported
from the 550-gallon kerosene UST and two 1,000-gallon gasoline USTs. TPH was detected at concentrations over the applicable standards at the time under three USTs with concentrations ranging from 27 mg/kg along product piping to 2,562 mg/kg under Tank #5 (1,000-gallon UST to the east of the subject building).

• January 26, 1996 – S&ME, Inc. (S&ME) submitted a Private Water Well Sampling & Well Survey Report documenting the sampling of three water supply wells (James Whitaker well, Eloise Blanton well, and David Blanton well). Several petroleum constituents were detected
below 2L Standards in the James Whitaker well. Two constituents, 1,2-dichloroethane (1,2-
DCA) and methyl tert-butyl ether (MTBE), were detected in the Eloise Blanton well. 1,2-DCA was detected above the 2L Standards and MTBE was below the 2L Standards established at that time.
• May 27, 1999 – S&ME submitted a Private Water Well Sampling Report documenting the sampling of three water supply wells (Eloise Blanton well, Hall well, and David Blanton well). Isopropyl ether (IPE) and MTBE were detected below the established 2L Standards. Petroleum constituents were not detected above the laboratory detection limits in the Hall well or David Blanton well.

• June 6, 2000 - S&ME submitted a Residential Water Well Sampling Report documenting the sampling of two water supply wells (James Whitaker well and Eloise Blanton well). 1,2-DCA
was detected above the 2L Standards and MTBE was detected below the established 2L
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Standards in the Eloise Blanton well. Petroleum constituents were not detected above the laboratory detection limits in the James Whitaker well.
• September 18, 2002 – S&ME submitted a Residential Water Well Sampling Report documenting the sampling of two water supply wells (Eloise Blanton well and David Blanton well). 1,2-DCA was detected above the 2L Standards and MTBE was detected below the established 2L Standards in the Eloise Blanton well. Petroleum constituents were not detected
above the laboratory detection limits in the David Blanton well.

• October 2003 and June 2005 – Lab data was submitted for sampling of Eloise Blanton well and Hall well in October 2003 and Eloise Blanton well, David Blanton well, and Hall well in
June 2005. 1,2-DCA was detected above 2L Standards in the Eloise Blanton well during the
2003 and 2005 sampling events.
• June 2006 – Hart & Hickman (H&H) submitted a Phase I Limited Site Assessment (LSA) report. The report documented soil sampling and the installation of three monitoring wells (MW-1
through MW-3) at the site. Soil analytical results indicated that total C9-C22 aromatics, naphthalene, 1,2,4-trimethylbenzene, xylenes, and 2-methylnaphthalene exceeded their respective soil to ground water maximum soil contaminant concentrations (MSCCs) in samples collected from the borings for monitoring wells MW-1 and MW-2. In addition, n-butylbenzene and 1,3,5-trimethylbenzene exceeded the soil-to-groundwater MSCCs in the soil sample
collected from MW-1, and C5-C8 aliphatics and ethylbenzene exceeded the soil-to-ground water MSCCs in the soil sample collected from MW-2. Total C9-C22 aromatics in MW-1 also exceeded the residential MSCC. Several petroleum constituents were detected above the 2L Standards in monitoring wells MW-1 and MW-2. Petroleum constituents were not detected above the laboratory detection limits in monitoring well MW-3. The receptor survey
conducted identified four active water supply wells and one non-potable water supply well within 1,000-feet of the source area. Municipal water is available to all properties within 1,500 feet of the site.
• July 29, 2008 – Hart & Hickman (H&H) submitted a Groundwater Monitoring Report. The report documented the sampling of the three monitoring wells and four water supply wells (Hall, Eloise Blanton, David Blanton, and Sorrow). 1,2-DCA was detected above the 2L Standard in the Eloise Blanton well. Several petroleum constituents were detected above the
2L Standards in monitoring well MW-2. Several petroleum constituents were detected above
the laboratory detection limits in monitoring well MW-1. Petroleum constituents were not detected above the laboratory detection limits in monitoring well MW-3.
• July 10, 2009 – S&ME submitted a Pre-CAP Monitoring Report. The report documented the
sampling of the three monitoring wells and two water supply wells (E. Blanton and Sorrow). 1,2-DCA and MTBE were detected above the 2L Standards in the Eloise Blanton well. Naphthalene was detected above the 2L Standard in monitoring well MW-1. Several petroleum constituents were detected above the 2L Standards in monitoring well MW-2. No
petroleum constituents were detected above the 2L Standards in monitoring well MW-3.
S&ME installed a Bio-Sokᵀᴹ in MW-1, MW-2, and MW-3 following sampling.
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• December 1, 2010 – S&ME submitted a Groundwater Monitoring Report. The report documented the sampling of the three monitoring wells and four water supply wells (Hall,
Eloise Blanton, David Blanton, and Sorrow). 1,2-DCA and MTBE were detected above the 2L
Standards in the Eloise Blanton well. Monitoring well MW-2 was not sampled due to the presence of 0.75 feet of LNAPL. Several petroleum constituents were detected above the laboratory detection limits, but below the 2L Standards in monitoring well MW-1. Petroleum constituents were not detected above the laboratory detection limits in monitoring well MW-
3.

• August 22, 2011 – S&ME submitted a Water Supply Well Sampling/Free Product Level Check report. The report documented the presence of 0.02 feet of LNAPL in monitoring well MW-2.
Four water supply wells (Hall, Eloise Blanton, David Blanton, and Sorrow) were sampled. 1,2-
DCA and MTBE were detected above 2L Standards in the Eloise Blanton well.
• February 2, 2018 – S&ME submitted a Report of Limited Groundwater Assessment. Monitoring wells MW-1 and MW-2 and water supply well SW-E. Blanton were sampled.
Benzene and naphthalene were detected above 2L Standards in monitoring well MW-2 and 1,2-DCA was above 2L Standards in water supply well SW-E. Blanton.
• November 2, 2018 – S&ME submitted a Report of Limited Groundwater Assessment.
Monitoring wells MW-1 and MW-2 and water supply well SW-E. Blanton were sampled. Benzene and naphthalene were detected above 2L Standards in monitoring well MW-2 and 1,2-DCA was above 2L Standards in water supply well SW-E. Blanton.
• July 10, 2019 – S&ME submitted a Report of Limited Groundwater Assessment. Monitoring wells MW-1 and MW-2 and water supply well SW-E. Blanton were sampled. Benzene and naphthalene were detected above 2L Standards in monitoring well MW-2. Acetone, 1,2-DCA, MTBE, and isopropyl ether were detected below 2L Standards in water supply well SW-E. Blanton.

• August 25, 2020 – S&ME submitted a Report of Limited Groundwater Assessment. Monitoring wells MW-1 and MW-2 and water supply well SW-E. Blanton were sampled. Benzene and
naphthalene were detected above 2L Standards in monitoring well MW-2. Acetone and MTBE
were detected below 2L Standards in water supply well SW-E. Blanton.
• August 12, 2021 – WR sampled monitoring wells MW-1 and MW-2. Water supply well SW-E.
Blanton was not sampled because WR personnel was not able to obtain authorization for
sampling the well. Benzene and naphthalene were reported at concentrations exceeding their 2L Standards. Several other constituents were detected in monitoring well MW-2 below the 2L Standards. No petroleum constituents were detected above the laboratory detection limits in monitoring well MW-1.

• July 25, 2022 – WR sampled monitoring wells MW-1 and MW-2 and water supply well SW-E. Blanton. Benzene, isopropylbenzene, 4-isopropyltoluene, naphthalene, n-propylbenzene, and 1,2,4-trimethylbenzene were each reported in the sample at concentrations exceeding their 2L Standards in monitoring well MW-2. Standards. Several other constituents were detected
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in monitoring well MW-2 below the 2L Standards. Acetone was detected above the laboratory detection limits in monitoring well MW-1. MTBE was detected below the 2L Standard in water supply well SW-E. Blanton.
3. Brief Description of Site Characteristics The property is located in a rural, residential / agricultural area of Mooresboro, Cleveland County, North Carolina (Figure 2). The property is currently vacant, and the USTs and dispensers have been removed.
4. Information on Receptors/Potential Receptors According to historical information, there are five active water supply wells within 1,000-feet of the subject property.
Potable water is supplied to the local area by the Cleveland County Water Department. The estimated locations of these water supply wells are shown on Figure 5. Information regarding the water supply sources is provided on Table B-5A.
5. Regional and Site Geology and Hydrology According to the 1985 USGS Geologic Map of the State of North Carolina, the subject property is located within the Inner Piedmont, Chauga Belt, Smith River Allochthon, and Sauratown Mountain
Belt. The site bedrock is intrusive rocks consisting of garnet, staurolite, kyanite, or sillimanite occur locally; lenses and layers of quartz schist, micaceous quartzite, calc-silicate rock, biotite gneiss, amphibolite, and phyllite. The soils encountered in this area are the residual product of in-place chemical weathering of rock presently underlying the site and/or historic depositional events. According to the USDA Soil Survey Map, the soils at the site consists of the Pacolet-Bethlehem
complex (PbB2). The PbB2 is found on 2 to 8 percent slopes and consists of sandy clay loams that originated from weathered granite and gneiss and/or schist.
Surficial unconfined groundwater movement within the overlying soils is controlled largely by
topographic gradients. However, as the groundwater percolates downward, it becomes influenced
by the subsurface geologic conditions. Therefore, the direction of groundwater movement in the
deeper aquifers may not be consistent with the reflecting topography. Recharge occurs primarily
by infiltration along higher elevations and typically discharges into streams or other surface water
bodies as the water flows from higher topographic elevations to lower topographic elevations.
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Former Whitaker’s Service Station – NCDEQ Incident #12487 WR Project # 23-0307-EY Monitoring Report May 2023 9
SECTION D. GROUNDWATER SAMPLING – MARCH 2023 On March 24, 2023, WR personnel mobilized to the subject property to perform groundwater sampling activities at the facility in association with TA-01 under NCDEQ Contract # N70522-C.
The scope of work for this project included the gauging, purging, and sampling of existing monitoring wells MW-1, MW-2, and MW-3. WR was also tasked with collecting a water supply well sample from SW-E. Blanton. The groundwater samples collected under TA-01 were submitted for laboratory analysis of VOCs by SM6200B.
The following paragraphs describe the sampling activities and associated laboratory analytical results. Groundwater Sampling Activities Prior to the purging and sampling of the site monitoring wells on March 24, 2023, WR personnel opened and gauged those wells targeted for purging and sampling with an electronic water level
indicator to determine the depth to groundwater at each well location. The depth to groundwater measurements in the monitoring wells ranged from 10.40 feet (ft) below the top of casing (ft-BTOC) in monitoring well MW-3 to 11.68 ft-BTOC in monitoring well MW-1. The depth to water in each of the wells was above the screened interval. Based on data
obtained during this sampling event, groundwater elevations were the same in all three monitoring wells. Historically, groundwater flow was toward the south to southeast. A groundwater hydraulic gradient map based on the March 24, 2023, measurements are shown on Figure 3. Groundwater elevation data are included in Table B-7.
Following gauging, monitoring wells were purged and sampled with separate, disposable polyethylene bailers for each well. Samples from the wells were decanted into pre-preserved laboratory provided sample containers. Samples collected from site monitoring wells were submitted via courier under chain-of-custody procedures to Waypoint Analytical, Inc. (Waypoint) in Charlotte, NC for testing by SM6200B.
Laboratory Results Analytical results for the groundwater samples collected on March 2023, indicated that monitoring well MW-2 contains 2L Standards exceedances of benzene and naphthalene.
Laboratory analytical results indicated that monitoring well MW-1 contains acetone above the method detection limits but below the 2L Standards. Laboratory analytical results indicated that water supply well SW-E. Blanton contains MTBE above the method detection limits but below the 2L Standards. There is no established USEPA MCL for
MTBE at this time. Analytical data for monitoring well MW-3 and the field blank did not report any compounds above the method detection limits.

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Former Whitaker’s Service Station – NCDEQ Incident #12487 WR Project # 23-0307-EY Monitoring Report May 2023 10
The following table compares Total VOCs results from MW-2 during the June 2022 event to MW-2 data collected in March 2023.
Well ID Total VOCs June 2022 (µg/L)
Total VOCs March 2023 (µg/L)
Percent Reduction / Increase (-/+ %)
MW-2 8,544.6 535.3 -93.74%
Total VOC concentrations have reduced significantly since June 2022. Analytical results are summarized in Table B-4 and illustrated on Figure 4. Copies of the laboratory
analytical report and chain-of-custody are included in Appendix A. A photographic record and field
notes are included in Appendix B. Standard Operating Procedures are included in Appendix C.
SECTION E. CONCLUSIONS AND RECOMMENDATIONS
This report documents the results of field activities conducted at the site for TA-01 which included the purging and sampling of monitoring wells MW-1, MW-2, MW-3, SW-E. Blanton, and a field blank. Conclusions based on observations, analytical data and research relating to the release at
the site combined with historical information include the following:

• The sites USTs and dispensers were removed in June 1994.
• Municipal water is available to the site and surrounding area through the Cleveland County
Water System.
• Four active water supply wells are located within 1,000-feet of the subject property.
• Benzene and naphthalene were reported at concentrations that exceeded the 2L Standards in
monitoring well MW-2.
• Acetone was reported at a concentration below the 2L Standard in monitoring well MW-1.
• MTBE was reported at a concentration below the 2L Standard in water supply well SW-E.
Blanton.
• No compounds were reported above the method detection limit in monitoring well MW-3 or the field blank.

Based on the results of assessment and monitoring activities conducted at the site in association with this TA, WR recommends the following:
• Semi-annual monitoring of onsite monitoring wells and SW-E. Blanton.
• Attempt to install a new water supply well between 250’ to 500’ from the existing SW-E. Blanton well.
• Collect one soil sample at 15’ below ground surface (bgs) near MW-1 to determine if C9-C22
Aromatics remain above Residential MSCCs.
• Install shallower monitoring wells near MW-2 and MW-3 where the water table is within the well screen.

FIGURES

MM
FD
DRAWN BY:
04/17/23 23-0307-EY
1
SUBJECT SITE
±1.6 ACRES
SCALE:FIGURE NO.:
PROJECT NO.:DATE:APPROVED BY:
FORMER WHITAKER'S SERVICE STATION - TF 12487
4900 ELLENBORO ROAD
MOORESBORO, CLEVELAND COUNTY, NC
GENERAL LOCATION MAP
1"=500 '
GRAPHIC SCALE
1 inch = 500 ft.
0 500250 1000
WithersRavenel
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115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 | license #: F-1479
www.withersravenel.com
MW-1
MW-2
MW-3
ELLENBORO ROA
D
FORMER UST LOCATIONS 1"=20 'GRAPHIC SCALE
1 inch = 20 ft.
0 2010 40
LEGEND
TYPE II MONITORING WELL LOCATION
NOTES:
1.) 2013 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.MMFDDRAWN BY:04/17/2323-0307-EY2SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:FORMER WHITAKER'S SERVICE STATION - TF 124874900 ELLENBORO ROADMOORESBORO, CLEVELAND COUNTY, NCSITE MAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.com
MW-1
MW-2
MW-3
ELLENBORO ROA
D
FORMER UST LOCATIONS
(88.32)
(88.32)
(88.32)1"=20 'GRAPHIC SCALE
1 inch = 20 ft.
0 2010 40
LEGEND
TYPE II MONITORING WELL LOCATION
GROUNDWATER ELEVATION (FT)
NOTES:
1.) 2019 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.MMFDDRAWN BY:04/18/2323-0307-EY3SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:FORMER WHITAKERS SERVICESTATION - TF 124874900 ELLENBORO ROADMOORESBORO, CLEVELAND COUNTY, NCGROUNDWATERELEVATION MAP -MARCH 2023WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.com(88.32)
MW-1
MW-2
MW-3
ELLENBORO ROAD
FORMER UST LOCATIONS
(88.32)
(88.32)
(88.32)1"=20 'GRAPHIC SCALE
1 inch = 20 ft.
0 2010 40
LEGEND
TYPE II MONITORING WELL LOCATION
NOTES:
1.) 2019 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.MMFDDRAWN BY:04/17/2323-0307-EY4SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:FORMER WHITAKERS SERVICESTATION - TF 124874900 ELLENBORO ROADMOORESBORO, CLEVELAND COUNTY, NCGROUNDWATERANALYTICAL RESULTSMAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.com
SW-E BLANTON
SW-D BLANTONSW-HALL
SW-SORROW
SW-PARKER 1"=200 'GRAPHIC SCALE
1 inch = 200 ft.
0 200100 400
LEGEND
WATER SUPPLY WELL LOCATION
NOTES:
1.) 2019 AERIAL OBTAINED FROM THE LOCAL COUNTY GIS DEPARTMENT.MMFDDRAWN BY:04/18/2323-0307-EY5SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:FORMER WHITAKERS SERVICESTATION - TF 124874900 ELLENBORO ROADMOORESBORO, CLEVELAND COUNTY, NCRECEPTOR MAPWithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.com

TABLES

UST IDNumberCurrent/LastContentsPreviousContentsCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofUSTWas release associated with UST System? (Y/N)1Kerosene Not Listed 550 Single‐Wall Steel 4' x 6' Single‐Wall Steel 01/01/72Closed(Removed 6/28/1994)Y2Gasoline Not Listed 1,000 Single‐Wall Steel 4' x 12' Single‐Wall Steel 01/01/72Closed(Removed 6/28/1994)N3Gasoline Not Listed 1,000 Single‐Wall Steel 4' x 12' Single‐Wall Steel 01/01/72Closed(Removed 6/28/1994)Y4Gasoline Not Listed 2,000 Single‐Wall Steel 64" x 12' Single‐Wall Steel 01/01/72Closed(Removed 6/28/1994)N5Gasoline Not Listed 1,000 Single‐Wall Steel 4' x 12' Single‐Wall Steel 01/01/72Closed(Removed 6/28/1994)YIncidentMaterial DateIncident # 12487 Petroleum UnknownNotes:1)UST Information from Tank Closure Report, Southeastern Geological Services, July 11, 1994.2)No ASTs have been noted on the property.Description of ReleaseRelease confirmed through laboratory analysis of soil samples showing TPH as GRO and/or DRO at levels exceeding Reportable Concentrations.  Table B‐1Site History:  UST System & Other Release InformationFormer Whitaker's Service Station Facility ID # 00‐0‐00000330094900 Ellenboro RoadMooresboro, Cleveland County NCIncident # 12487Page 1 of 1
Calculated
AcetoneBenzenesec‐Butylbenzene1,2‐DichloroethaneEthylbenzeneIsopropylbenzene4‐IsopropyltolueneMethyl tert‐butyl etherNaphthalenen‐PropylbenzeneToluene1,2,4‐Trimethylbenzene1,3,5‐TrimethylbenzeneTotal Xylenes67 64 1 71 43 2 135 98 8 107 06 2 100 41 4 98 82 8 99 87 6 1634 04 91 20 3 103 651 108 88 3 95 63 6 108 67 8 NA6/22/2006 NL <10 NL <10 61.6 14 NL <10 346 18.2 NL 376 115 420
5/9/2008 NL <0.500 NL NL 3.4 3.2 NL <0.500 100 3.2 NL 40 1.9 35.6
6/11/2009 NL <0.500 NL <0.500 2.2 1.8 NL <0.500 122 2.6 <0.500 69 3.4 26.3
1/29/2010 <5.00 <0.500 NL <0.500 <0.500 <0.500 <0.500 <0.500 4.9 <0.500 <0.500 3.7 0.51 1.43
10/27/2010 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 12 <0.500 <0.500 5.20.552.4
12/27/2017 <50 <0.500 0.18 <0.500 <0.500 <2.00 <2.00 <0.500 3.7 <0.500 <0.500 0.22 <2.00 <1.00
10/8/2018 <50 0.21 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <0.500 <0.500
6/18/2019 9 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500
7/24/2020 <50 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00
7/8/2021 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
6/28/2022 12.6 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500
3/24/2023 13.4 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
6/22/2006 NL 123 NL NL 47.8 18 NL 113 518 20.4 NL 235 84 129
5/9/2008 NL 210 NL NL 97 52 NL 55 2,000 93 NL 1,100 470 231
6/11/2009 NL 557 NL 2.8 58.8 12.4 NL 23.4 751 25.4 31.3 259 102 95.4
1/29/2010 <5.0 1,000 11 <0.500 120 22 16 26 880 33 48 310 120 232
10/27/2010
7/8/2011
12/27/2017 <250 360 2.6 <2.50 22 3.4 6.4 <2.50 320 4.8 3.3 81 20 19.85
10/8/2018 <500 320 3.2 <5.00 16 3.7 7.9 <5.00 150 5.5 <5.00 67 13 22
6/18/2019 <200 140 1.4 <4.00 220 10 0.84 <2.00 82 20 1.7 84 2 19.2
7/24/2020 <100 170 6.1 <1.00 210 14 5.8 <1.00 220 23 2.5 90 7.3 33
7/8/2021 <100 86.9 5.51 <5.00 417 28.7 <5.00 <10.0 237 50.7 <5.00 86.3 10.6 77.3
6/28/2022 <100 1,750 40.9 <5.00 24.6 207 36.3 <10.0 4,740 313 19.1 938 61.7 414
3/24/2023 <100 85 <5.00 <5.00 280 17.6 <5.00 <10.0 75.5 22.0 7.70 19.3 <5.00 28.7
6/22/2006 NL <0.500 NL NL 2.29 <0.500 NL <0.500 2.6 0.70 NL 5.78 1.91 8.19
5/9/2008 NL <0.500 NL NL <0.500 <0.500 NL <0.500 <2.00 <0.500 NL <0.500 <0.500 <1.5
6/11/2009 NL <0.500 <0.500 <0.500 <0.500 <0.500 NL <0.500 3.0 <0.500 <0.500 0.85 <0.500 <1.5
1/29/2010 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 <0.500 <0.500 <1.5
10/27/2010 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <1.5
3/24/2023 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
6/22/2006 NL NL NL 1.2 NL NL NL 14 NL NL NL NL NL NL
5/9/2008 NL <0.500 <0.500 1.7 <0.500 <0.500 <0.500 21 <2.00 <0.500 <0.500 <0.500 <0.500 <1.00
6/11/2009 NL <0.500 <0.500 1.8 <0.500 <0.500 <0.500 26.8 <2.00 <0.500 <0.500 <0.500 <0.500 <1.00
1/29/2010 <5.00 <0.500 <0.500 1.2 <0.500 <0.500 <0.500 7.7 <2.00 <0.500 <0.500 <0.500 <0.500 <1.5
10/27/2010 <10.0 <0.500 <0.500 1.5 <0.500 <0.500 <0.500 26 <1.00 <0.500 <0.500 <0.500 <0.500 <1.5
7/8/2011 NL <0.500 <0.500 1.2 <0.500 <0.500 <0.500 22 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500
12/27/2017 <50 <0.500 <0.500 0.64 <0.500 <2.00 <2.00 13 <0.500 <0.500 <0.500 <1.00 <2.00 <1.00
10/8/2018 <50 <0.500 <0.500 0.43 <0.500 <0.500 <0.500 11 <2.00 <0.500 <0.500 <0.500 <0.500 <0.500
6/18/2019 5.7 <0.500 <0.500 <1.00 <0.500 <0.500 <0.500 8.2 <5.00 <0.500 <0.500 <0.500 <0.500 <1.5
7/24/2020 4.8 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 9.5 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00
7/7/2022 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 15.1 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
3/24/2023 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 10.4 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
7/8/2021 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
6/28/2022 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
3/24/2023 <10.0 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500
6000 1 70 0.4 600 70 25 20 6 70 600 400 400 500
6,000,000 5,000 8,800 400 80,000 30,500 11,700 20,000 6,000 26,100 260,000 28,500 24,100 50,000
Notes:
1)
2)
3)
4)
NL
Result
Result
Result
NC 2L Standard 
GCLs for Groundwater
DateCollected
MW‐2
MW‐3
SW‐E Blanton
LNAPL ‐ Not Sampled
Field Blank
MW‐1
All results provided in ug/L (micrograms per liter) or parts per billion
NC 2L Standard ‐ Water Quality Standards for Class GA Groundwater, defined by NCAC Title 15A, Subchapter 02L, Section .0202 (Comprehensive Tables for Corrective Action 
Guidelines, September 2022).
GCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for Groundwater (Comprehensive Tables for Corrective Action Guidelines, September 2022). Only 
those compounds detected in one or more samples are shown hereon. 
= Not Listed
= Result Exceeds Laboratory Detection Limits
= Result Exceeds 2L Standard
= Result Exceeds GCL Value
TABLE B‐4SUMMARY OF GROUNDWATER ANALYTICAL RESULTSFormer Whitaker's Service Station4900 Ellenboro Road
Mooresboro, Cleveland County NCIncident # 12487
Analytical Method SM6200B ‐ Volatile Organic Compounds
SampleID
LNAPL ‐ Not Sampled
Well ID Well Owners / Well Users Property AddressMailing AddressWell Use (P/I/N)Estimated Distance/Direction from Source Area (ft)D. BlantonDavid Blanton4856 Ellenboro Road, Mooresboro, NC 281144856 Ellenboro Road, Mooresboro, NC 28114P400 NEE. BlantonDavid Blanton/Eloise Blanton4859 Ellenboro Road, Mooresboro, NC 281144856 Ellenboro Road, Mooresboro, NC 28114P320 NEHallWillie Hall4908 Ellenboro Road, Mooresboro, NC 281144908 Ellenboro Road, Mooresboro, NC 28114P350 WSorrowJoe Sorrow4860 Ellenboro Road, Mooresboro, NC 281144860 Ellenboro Road, Mooresboro, NC 28114P435 NWParkerEdgar Parker4918 Ellenboro Road, Mooresboro, NC 281144918 Ellenboro Road, Mooresboro, NC 28114NA980 WNotes:1)2)3)Table adapted from S&ME, Inc. "Groundwater Monitoring Report, Whitaker's Service Station, Table 6, Water Supply Well Information", December 1, 2010.NA = Not available or unknown.P / I / N = Potable water supply / Irrigation / Not in useTABLE B‐5AWATER SUPPLY WELL INFORMATION Former Whitaker's Service Station 4900 Ellenboro RoadMooresboro, Cleveland County NC Incident # 12487
6/11/2009 18.33 ‐‐81.67
1/29/2010 13.51 ‐‐86.49
10/27/2010 17.67 ‐‐82.33
12/27/2017 20.25 ‐‐79.75
6/18/2019 8.90 ‐‐91.10
7/24/2020 2.03 ‐‐97.97
7/8/2021 10.24 ‐‐89.76
6/28/2022 13.95 ‐‐86.05
3/24/2023 11.68 ‐‐88.32
6/11/2009 17.65 ‐‐81.47
1/29/2010 12.82 ‐‐86.30
10/27/2010 17.16 0.75 82.60
7/8/2011 17.24 0.02 81.90
12/27/2017 19.50 ‐‐79.62
6/18/2019 8.24 ‐‐90.88
7/24/2020 7.90 ‐‐91.22
7/8/2021 11.18 ‐‐87.94
6/28/2022 13.00 ‐‐86.12
3/24/2023 10.80 88.32
6/11/2009 17.00 ‐‐81.72
1/29/2010 10.19 ‐‐88.53
10/27/2010 16.97 ‐‐81.75
3/24/2023 10.40 ‐‐88.32
Notes:
Groundwater elevation calculated by: (Top‐of‐Casing ‐ Depth‐to‐Water) + (LNAPL thickness x 0.8581)
15‐256/21/2006MW‐3
Top‐of Casing (TOC) elevations for MW‐1 through MW‐3 based on survey completed by S&ME, Inc. (June 2009). 
Benchmark for elevation survey established at top of casing of monitoring well MW‐1. Assumed benchmark 
elevation established as 100.00 ft.
LNAPL = Light Non‐Aqueous Phase Liquid
MW‐1 6/21/2003 15‐25 100.00
MW‐2 6/21/2006 15‐25 99.12
Screened 
Interval        
(feet)
TABLE B‐7
MONITORING WELL CONSTRUCTION INFORMATION
Former Whitaker's Service Station
4900 Ellenboro RoadMooresboro, Cleveland County NC
Incident # 12487
‐‐ = Not measured
Top‐of‐Casing 
Elevation      
(feet)
Date Water 
Level 
Measured
Depth‐to‐Water 
from 
Top‐of‐Casing
(feet)
LNAPL 
Thickness
(feet)
Groundwater
Elevation     
(feet)
Well ID Date Installed  
98.72

APPENDIX A
LABORATORY ANALYTICAL REPORT & CHAIN OF CUSTODY

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

4/7/2023
Withers & Ravenel Matt James
115 Mackenan Dr. BUILDING 117 Cary, NC, 27511
Ref: Analytical Testing
Lab Report Number: 23-088-0003 Client Project Description: Whitakers Service Station
23-0307-Ey
Dear Matt James:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/29/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Angela D Overcash Senior Project Manager
Page 1 of 32
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2023402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/23-088-0003
Page 2 of 32
Report Number:
Sample Summary Table
Client Project Description:
23-088-0003
Whitakers Service Station
23-0307-Ey
Lab No Client Sample ID Matrix Date Collected Date Received
03/24/2023 12:30Aqueous 92444 MW-1 03/29/2023 10:10
03/24/2023 12:45Aqueous 92445 MW-2 03/29/2023 10:10
03/24/2023 13:00Aqueous 92446 MW-3 03/29/2023 10:10
03/24/2023 13:20Aqueous 92447 SW-E Blanton 03/29/2023 10:10
03/24/2023 13:25Aqueous 92448 FB 03/29/2023 10:10
Page 3 of 32
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
23-088-0003
Report Limit
Project:Whitakers Service Station
V 92444MW-1
13.4 04/05/2023 05:226200BAcetoneµg/L 10.0
V 92445MW-2
84.5 04/05/2023 08:146200BBenzeneµg/L 5.00
280 04/05/2023 08:146200BEthylbenzeneµg/L 5.00
17.6 04/05/2023 08:146200BIsopropylbenzeneµg/L 5.00
75.5 04/05/2023 08:146200BNaphthaleneµg/L 10.0
22.0 04/05/2023 08:146200Bn-Propylbenzene µg/L 5.00
7.70 04/05/2023 08:146200BTolueneµg/L 5.00
19.3 04/05/2023 08:146200B1,2,4-Trimethylbenzene µg/L 5.00
6.57 04/05/2023 08:146200Bo-Xylene µg/L 5.00
22.1 04/05/2023 08:146200Bm,p-Xylene µg/L 10.0
28.7 04/05/2023 08:146200BXylene (Total)µg/L 5.00
V 92447SW-E Blanton
10.4 04/05/2023 06:116200BMethyl tert-butyl ether (MTBE)µg/L 1.00
Page 4 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
92444 Matrix:
3/24/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
13.4 µg/L 10.0Acetone 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/05/23 05:22 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/05/23 05:22 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/05/23 05:22 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/05/23 05:22 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/05/23 05:22 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/05/23 05:22 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/05/23 05:22 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 5 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
92444 Matrix:
3/24/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/05/23 05:22 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/05/23 05:22 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/05/23 05:22 6200BMSA
<200 µg/L 200Ethanol 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/05/23 05:22 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/05/23 05:22 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/05/23 05:22 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/05/23 05:22 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/05/23 05:22 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/05/23 05:22 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 6 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
92444 Matrix:
3/24/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/05/23 05:22 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/05/23 05:22 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/05/23 05:22 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/05/23 05:22 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/05/23 05:22 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 7 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-1
92444 Matrix:
3/24/2023 12:30
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/05/23 05:22 6200B
Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%04/05/23 05:221 MSA V31662
Surrogate: Dibromofluoromethane 99.4 Limits: 70-130%04/05/23 05:221 MSA V31662
Surrogate: 1,2-Dichloroethane - d4 98.0 Limits: 70-130%04/05/23 05:221 MSA V31662
Surrogate: Toluene-d8 99.8 Limits: 70-130%04/05/23 05:221 MSA V31662
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 8 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
92445 Matrix:
3/24/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<100 µg/L 100Acetone 10 04/05/23 08:14 6200BMSA
84.5 µg/L 5.00Benzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Bromobenzene 10 04/05/23 08:14 6200BMSA
<10.0 µg/L 10.0Bromochloromethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Bromodichloromethane 10 04/05/23 08:14 6200BMSA
<50.0 µg/L 50.0Bromoform 10 04/05/23 08:14 6200BMSA
<10.0 µg/L 10.0Bromomethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00n-Butylbenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00sec-Butyl benzene 10 04/05/23 08:14 6200BMSA
<20.0 µg/L 20.0tert-Butyl benzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Carbon Tetrachloride 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Chlorobenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Chlorodibromomethane 10 04/05/23 08:14 6200BMSA
<10.0 µg/L 10.0Chloroethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Chloroform 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Chloromethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.002-Chlorotoluene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.004-Chlorotoluene 10 04/05/23 08:14 6200BMSA
<20.0 µg/L 20.01,2-Dibromo-3-Chloropropane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,2-Dibromoethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Dibromomethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,2-Dichlorobenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,3-Dichlorobenzene 10 04/05/23 08:14 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 9 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
92445 Matrix:
3/24/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<5.00 µg/L 5.001,4-Dichlorobenzene 10 04/05/23 08:14 6200BMSA
<50.0 µg/L 50.0Dichlorodifluoromethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,1-Dichloroethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,2-Dichloroethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,1-Dichloroethene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00cis-1,2-Dichloroethene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00trans-1,2-Dichloroethene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,2-Dichloropropane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,3-Dichloropropane 10 04/05/23 08:14 6200BMSA
<20.0 µg/L 20.02,2-Dichloropropane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,1-Dichloropropene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00cis-1,3-Dichloropropene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00trans-1,3-Dichloropropene 10 04/05/23 08:14 6200BMSA
<2000 µg/L 2000Ethanol 10 04/05/23 08:14 6200BMSA
280 µg/L 5.00Ethylbenzene 10 04/05/23 08:14 6200BMSA
<30.0 µg/L 30.0Hexachlorobutadiene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Di-Isopropyl Ether (DIPE)10 04/05/23 08:14 6200BMSA
17.6 µg/L 5.00Isopropylbenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.004-Isopropyl toluene 10 04/05/23 08:14 6200BMSA
<10.0 µg/L 10.02-Hexanone 10 04/05/23 08:14 6200BMSA
<50.0 µg/L 50.0Methyl Ethyl Ketone (MEK)10 04/05/23 08:14 6200BMSA
<20.0 µg/L 20.0Methylene Chloride 10 04/05/23 08:14 6200BMSA
<10.0 µg/L 10.0Methyl tert-butyl ether (MTBE)10 04/05/23 08:14 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 10 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
92445 Matrix:
3/24/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.04-Methyl-2-Pentanone 10 04/05/23 08:14 6200BMSA
75.5 µg/L 10.0Naphthalene 10 04/05/23 08:14 6200BMSA
22.0 µg/L 5.00n-Propylbenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Styrene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,1,1,2-Tetrachloroethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,1,2,2-Tetrachloroethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Tetrachloroethene 10 04/05/23 08:14 6200BMSA
7.70 µg/L 5.00Toluene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,2,3-Trichlorobenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,2,4-Trichlorobenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,1,1-Trichloroethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,1,2-Trichloroethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Trichloroethene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Trichlorofluoromethane 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,2,3-Trichloropropane 10 04/05/23 08:14 6200BMSA
19.3 µg/L 5.001,2,4-Trimethylbenzene 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.001,3,5-Trimethylbenzene 10 04/05/23 08:14 6200BMSA
<50.0 µg/L 50.0Vinyl Acetate 10 04/05/23 08:14 6200BMSA
<5.00 µg/L 5.00Vinyl Chloride 10 04/05/23 08:14 6200BMSA
22.1 µg/L 10.0m,p-Xylene 10 04/05/23 08:14 6200BMSA
6.57 µg/L 5.00o-Xylene 10 04/05/23 08:14 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 11 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-2
92445 Matrix:
3/24/2023 12:45
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
28.7 µg/L 5.00Xylene (Total)10 04/05/23 08:14 6200B
Surrogate: 4-Bromofluorobenzene 107 Limits: 70-130%04/05/23 08:1410 MSA V31662
Surrogate: Dibromofluoromethane 102 Limits: 70-130%04/05/23 08:1410 MSA V31662
Surrogate: 1,2-Dichloroethane - d4 102 Limits: 70-130%04/05/23 08:1410 MSA V31662
Surrogate: Toluene-d8 104 Limits: 70-130%04/05/23 08:1410 MSA V31662
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 12 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
92446 Matrix:
3/24/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/05/23 05:46 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/05/23 05:46 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/05/23 05:46 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/05/23 05:46 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/05/23 05:46 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/05/23 05:46 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/05/23 05:46 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 13 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
92446 Matrix:
3/24/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/05/23 05:46 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/05/23 05:46 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/05/23 05:46 6200BMSA
<200 µg/L 200Ethanol 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/05/23 05:46 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/05/23 05:46 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/05/23 05:46 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/05/23 05:46 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/05/23 05:46 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/05/23 05:46 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 14 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
92446 Matrix:
3/24/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/05/23 05:46 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/05/23 05:46 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/05/23 05:46 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/05/23 05:46 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/05/23 05:46 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 15 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:MW-3
92446 Matrix:
3/24/2023 13:00
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/05/23 05:46 6200B
Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%04/05/23 05:461 MSA V31662
Surrogate: Dibromofluoromethane 100 Limits: 70-130%04/05/23 05:461 MSA V31662
Surrogate: 1,2-Dichloroethane - d4 98.8 Limits: 70-130%04/05/23 05:461 MSA V31662
Surrogate: Toluene-d8 102 Limits: 70-130%04/05/23 05:461 MSA V31662
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 16 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:SW-E Blanton
92447 Matrix:
3/24/2023 13:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/05/23 06:11 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/05/23 06:11 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/05/23 06:11 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/05/23 06:11 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/05/23 06:11 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/05/23 06:11 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/05/23 06:11 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 17 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:SW-E Blanton
92447 Matrix:
3/24/2023 13:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/05/23 06:11 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/05/23 06:11 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/05/23 06:11 6200BMSA
<200 µg/L 200Ethanol 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/05/23 06:11 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/05/23 06:11 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/05/23 06:11 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/05/23 06:11 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/05/23 06:11 6200BMSA
10.4 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/05/23 06:11 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 18 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:SW-E Blanton
92447 Matrix:
3/24/2023 13:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/05/23 06:11 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/05/23 06:11 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/05/23 06:11 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/05/23 06:11 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/05/23 06:11 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 19 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:SW-E Blanton
92447 Matrix:
3/24/2023 13:20
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/05/23 06:11 6200B
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%04/05/23 06:111 MSA V31662
Surrogate: Dibromofluoromethane 101 Limits: 70-130%04/05/23 06:111 MSA V31662
Surrogate: 1,2-Dichloroethane - d4 96.4 Limits: 70-130%04/05/23 06:111 MSA V31662
Surrogate: Toluene-d8 100 Limits: 70-130%04/05/23 06:111 MSA V31662
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 20 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:FB
92448 Matrix:
3/24/2023 13:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0Acetone 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Benzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Bromobenzene 1 04/05/23 02:29 6200BMSA
<1.00 µg/L 1.00Bromochloromethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Bromodichloromethane 1 04/05/23 02:29 6200BMSA
<5.00 µg/L 5.00Bromoform 1 04/05/23 02:29 6200BMSA
<1.00 µg/L 1.00Bromomethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500n-Butylbenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500sec-Butyl benzene 1 04/05/23 02:29 6200BMSA
<2.00 µg/L 2.00tert-Butyl benzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Carbon Tetrachloride 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Chlorobenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Chlorodibromomethane 1 04/05/23 02:29 6200BMSA
<1.00 µg/L 1.00Chloroethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Chloroform 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Chloromethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5002-Chlorotoluene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5004-Chlorotoluene 1 04/05/23 02:29 6200BMSA
<2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2-Dibromoethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Dibromomethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/05/23 02:29 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 21 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:FB
92448 Matrix:
3/24/2023 13:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/05/23 02:29 6200BMSA
<5.00 µg/L 5.00Dichlorodifluoromethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2-Dichloroethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,1-Dichloroethene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2-Dichloropropane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,3-Dichloropropane 1 04/05/23 02:29 6200BMSA
<2.00 µg/L 2.002,2-Dichloropropane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,1-Dichloropropene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/05/23 02:29 6200BMSA
<200 µg/L 200Ethanol 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Ethylbenzene 1 04/05/23 02:29 6200BMSA
<3.00 µg/L 3.00Hexachlorobutadiene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Isopropylbenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5004-Isopropyl toluene 1 04/05/23 02:29 6200BMSA
<1.00 µg/L 1.002-Hexanone 1 04/05/23 02:29 6200BMSA
<5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/05/23 02:29 6200BMSA
<2.00 µg/L 2.00Methylene Chloride 1 04/05/23 02:29 6200BMSA
<1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/05/23 02:29 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 22 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:FB
92448 Matrix:
3/24/2023 13:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/05/23 02:29 6200BMSA
<1.00 µg/L 1.00Naphthalene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500n-Propylbenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Styrene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Tetrachloroethene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Toluene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Trichloroethene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Trichlorofluoromethane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/05/23 02:29 6200BMSA
<5.00 µg/L 5.00Vinyl Acetate 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500Vinyl Chloride 1 04/05/23 02:29 6200BMSA
<1.00 µg/L 1.00m,p-Xylene 1 04/05/23 02:29 6200BMSA
<0.500 µg/L 0.500o-Xylene 1 04/05/23 02:29 6200BMSA
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 23 of 32
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 27511
23-088-0003
01221
Withers & Ravenel
115 Mackenan Dr. BUILDING 117
Matt James
Cary
23-0307-Ey Received : 03/29/2023
Whitakers Service Station
Report Date : 04/07/2023
Sample ID :
Lab No :
Sampled:FB
92448 Matrix:
3/24/2023 13:25
Aqueous
Test Results Units MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500Xylene (Total)1 04/05/23 02:29 6200B
Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%04/05/23 02:291 MSA V31662
Surrogate: Dibromofluoromethane 100 Limits: 70-130%04/05/23 02:291 MSA V31662
Surrogate: 1,2-Dichloroethane - d4 97.8 Limits: 70-130%04/05/23 02:291 MSA V31662
Surrogate: Toluene-d8 104 Limits: 70-130%04/05/23 02:291 MSA V31662
Qualifiers/
Definitions
Method Quantitation LimitMQLDilution FactorDF
Page 24 of 32
Quality Control Data
23-088-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Whitakers Service Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31662QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31661
Associated Lab Samples: 92444, 92445, 92446, 92447, 92448
LRB-V31661 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/05/23 01:4010.0< 10.0µg/LAcetone
04/05/23 01:400.500< 0.500µg/LBenzene
04/05/23 01:400.500< 0.500µg/LBromobenzene
04/05/23 01:401.00< 1.00µg/LBromochloromethane
04/05/23 01:400.500< 0.500µg/LBromodichloromethane
04/05/23 01:405.00< 5.00µg/LBromoform
04/05/23 01:401.00< 1.00µg/LBromomethane
04/05/23 01:400.500< 0.500µg/Ln-Butylbenzene
04/05/23 01:400.500< 0.500µg/Lsec-Butyl benzene
04/05/23 01:402.00< 2.00µg/Ltert-Butyl benzene
04/05/23 01:400.500< 0.500µg/LCarbon Tetrachloride
04/05/23 01:400.500< 0.500µg/LChlorobenzene
04/05/23 01:400.500< 0.500µg/LChlorodibromomethane
04/05/23 01:401.00< 1.00µg/LChloroethane
04/05/23 01:400.500< 0.500µg/LChloroform
04/05/23 01:400.500< 0.500µg/LChloromethane
04/05/23 01:400.500< 0.500µg/L2-Chlorotoluene
04/05/23 01:400.500< 0.500µg/L4-Chlorotoluene
04/05/23 01:402.00< 2.00µg/L1,2-Dibromo-3-Chloropropane
04/05/23 01:400.500< 0.500µg/L1,2-Dibromoethane
04/05/23 01:400.500< 0.500µg/LDibromomethane
04/05/23 01:400.500< 0.500µg/L1,2-Dichlorobenzene
04/05/23 01:400.500< 0.500µg/L1,3-Dichlorobenzene
04/05/23 01:400.500< 0.500µg/L1,4-Dichlorobenzene
04/05/23 01:405.00< 5.00µg/LDichlorodifluoromethane
04/05/23 01:400.500< 0.500µg/L1,1-Dichloroethane
04/05/23 01:400.500< 0.500µg/L1,2-Dichloroethane
Page 1 of 6Date:04/07/2023 09:02 AM
Page 25 of 32
Quality Control Data
23-088-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Whitakers Service Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31662QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31661
Associated Lab Samples: 92444, 92445, 92446, 92447, 92448
LRB-V31661 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/05/23 01:400.500< 0.500µg/L1,1-Dichloroethene
04/05/23 01:400.500< 0.500µg/Lcis-1,2-Dichloroethene
04/05/23 01:400.500< 0.500µg/Ltrans-1,2-Dichloroethene
04/05/23 01:400.500< 0.500µg/L1,2-Dichloropropane
04/05/23 01:400.500< 0.500µg/L1,3-Dichloropropane
04/05/23 01:402.00< 2.00µg/L2,2-Dichloropropane
04/05/23 01:400.500< 0.500µg/L1,1-Dichloropropene
04/05/23 01:400.500< 0.500µg/Lcis-1,3-Dichloropropene
04/05/23 01:400.500< 0.500µg/Ltrans-1,3-Dichloropropene
04/05/23 01:40200< 200µg/LEthanol
04/05/23 01:400.500< 0.500µg/LEthylbenzene
04/05/23 01:403.00< 3.00µg/LHexachlorobutadiene
04/05/23 01:400.500< 0.500µg/LDi-Isopropyl Ether (DIPE)
04/05/23 01:400.500< 0.500µg/LIsopropylbenzene
04/05/23 01:400.500< 0.500µg/L4-Isopropyl toluene
04/05/23 01:401.00< 1.00µg/L2-Hexanone
04/05/23 01:405.00< 5.00µg/LMethyl Ethyl Ketone (MEK)
04/05/23 01:402.00< 2.00µg/LMethylene Chloride
04/05/23 01:401.00< 1.00µg/LMethyl tert-butyl ether (MTBE)
04/05/23 01:401.00< 1.00µg/L4-Methyl-2-Pentanone
04/05/23 01:401.00< 1.00µg/LNaphthalene
04/05/23 01:400.500< 0.500µg/Ln-Propylbenzene
04/05/23 01:400.500< 0.500µg/LStyrene
04/05/23 01:400.500< 0.500µg/L1,1,1,2-Tetrachloroethane
04/05/23 01:400.500< 0.500µg/L1,1,2,2-Tetrachloroethane
04/05/23 01:400.500< 0.500µg/LTetrachloroethene
04/05/23 01:400.500< 0.500µg/LToluene
Page 2 of 6Date:04/07/2023 09:02 AM
Page 26 of 32
Quality Control Data
23-088-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Whitakers Service Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31662QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31661
Associated Lab Samples: 92444, 92445, 92446, 92447, 92448
LRB-V31661 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/05/23 01:400.500< 0.500µg/L1,2,3-Trichlorobenzene
04/05/23 01:400.500< 0.500µg/L1,2,4-Trichlorobenzene
04/05/23 01:400.500< 0.500µg/L1,1,1-Trichloroethane
04/05/23 01:400.500< 0.500µg/L1,1,2-Trichloroethane
04/05/23 01:400.500< 0.500µg/LTrichloroethene
04/05/23 01:400.500< 0.500µg/LTrichlorofluoromethane
04/05/23 01:400.500< 0.500µg/L1,2,3-Trichloropropane
04/05/23 01:400.500< 0.500µg/L1,2,4-Trimethylbenzene
04/05/23 01:400.500< 0.500µg/L1,3,5-Trimethylbenzene
04/05/23 01:405.00< 5.00µg/LVinyl Acetate
04/05/23 01:400.500< 0.500µg/LVinyl Chloride
04/05/23 01:401.00< 1.00µg/Lm,p-Xylene
04/05/23 01:400.500< 0.500µg/Lo-Xylene
04/05/23 01:404-Bromofluorobenzene (S)99.6 70-130
04/05/23 01:40Dibromofluoromethane (S)99.6 70-130
04/05/23 01:401,2-Dichloroethane - d4 (S)97.6 70-130
04/05/23 01:40Toluene-d8 (S)101 70-130
LCS-V31661 LCSD-V31661Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
33.7 84.286.734.740.0µg/LAcetone 40-160 2.9 20.0
22.5 11310721.420.0µg/LBenzene 70-130 5.0 20.0
23.6 11811422.720.0µg/LBromobenzene 70-130 3.8 20.0
22.3 11210921.720.0µg/LBromochloromethane 70-130 2.7 20.0
22.6 11311022.020.0µg/LBromodichloromethane 70-130 2.6 20.0
Page 3 of 6Date:04/07/2023 09:02 AM
Page 27 of 32
Quality Control Data
23-088-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Whitakers Service Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31662QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31661
LCS-V31661 LCSD-V31661Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.7 10911222.320.0µg/LBromoform 70-130 2.7 20.0
23.8 11910721.320.0µg/LBromomethane 60-140 11.0 20.0
23.2 11610921.720.0µg/Ln-Butylbenzene 70-130 6.6 20.0
22.6 11310520.920.0µg/Lsec-Butyl benzene 70-130 7.8 20.0
22.4 11210320.520.0µg/Ltert-Butyl benzene 70-130 8.8 20.0
23.5 11810921.720.0µg/LCarbon Tetrachloride 70-130 7.9 20.0
22.3 11210621.220.0µg/LChlorobenzene 70-130 5.0 20.0
22.7 11411322.520.0µg/LChlorodibromomethane 70-130 0.8 20.0
21.7 10910220.420.0µg/LChloroethane 60-140 6.1 20.0
22.8 11410821.520.0µg/LChloroform 70-130 5.8 20.0
21.7 10910020.020.0µg/LChloromethane 60-140 8.1 20.0
23.0 11510921.820.0µg/L2-Chlorotoluene 70-130 5.3 20.0
22.4 11210921.820.0µg/L4-Chlorotoluene 70-130 2.7 20.0
22.0 11011823.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 7.0 20.0
23.0 11511623.120.0µg/L1,2-Dibromoethane 70-130 0.4 20.0
21.8 10910821.520.0µg/LDibromomethane 70-130 1.3 20.0
23.0 11511222.320.0µg/L1,2-Dichlorobenzene 70-130 3.0 20.0
22.6 11310921.720.0µg/L1,3-Dichlorobenzene 70-130 4.0 20.0
22.1 11110921.720.0µg/L1,4-Dichlorobenzene 70-130 1.8 20.0
22.7 11411022.020.0µg/LDichlorodifluoromethane 60-140 3.1 20.0
22.9 11510921.720.0µg/L1,1-Dichloroethane 70-130 5.3 20.0
22.3 11210921.820.0µg/L1,2-Dichloroethane 70-130 2.2 20.0
23.6 11811122.220.0µg/L1,1-Dichloroethene 70-130 6.1 20.0
22.6 11310821.520.0µg/Lcis-1,2-Dichloroethene 70-130 4.9 20.0
22.7 11410721.320.0µg/Ltrans-1,2-Dichloroethene 70-130 6.3 20.0
23.1 11611022.020.0µg/L1,2-Dichloropropane 70-130 4.8 20.0
Page 4 of 6Date:04/07/2023 09:02 AM
Page 28 of 32
Quality Control Data
23-088-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Whitakers Service Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31662QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31661
LCS-V31661 LCSD-V31661Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.4 11211022.020.0µg/L1,3-Dichloropropane 70-130 1.8 20.0
19.7 98.594.018.820.0µg/L2,2-Dichloropropane 70-130 4.6 20.0
24.2 12111422.720.0µg/L1,1-Dichloropropene 70-130 6.3 20.0
22.3 11210921.720.0µg/Lcis-1,3-Dichloropropene 70-130 2.7 20.0
22.6 11311122.220.0µg/Ltrans-1,3-Dichloropropene 70-130 1.7 20.0
559 112108539500µg/LEthanol 60-140 3.6 20.0
21.9 11010420.820.0µg/LEthylbenzene 70-130 5.1 20.0
22.5 11310320.520.0µg/LHexachlorobutadiene 70-130 9.3 20.0
23.2 11611422.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.1 20.0
23.3 11710921.720.0µg/LIsopropylbenzene 70-130 7.1 20.0
23.1 11610921.720.0µg/L4-Isopropyl toluene 70-130 6.2 20.0
21.2 10611422.720.0µg/L2-Hexanone 60-140 6.8 20.0
18.0 90.091.518.320.0µg/LMethyl Ethyl Ketone (MEK)60-140 1.6 20.0
21.9 11010521.020.0µg/LMethylene Chloride 70-130 4.1 20.0
23.0 11511522.920.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.4 20.0
22.8 11412124.220.0µg/L4-Methyl-2-Pentanone 60-140 5.9 20.0
22.1 11111422.720.0µg/LNaphthalene 70-130 2.6 20.0
22.5 11310721.420.0µg/Ln-Propylbenzene 70-130 5.0 20.0
23.0 11510921.720.0µg/LStyrene 70-130 5.8 20.0
22.9 11511322.620.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.3 20.0
21.1 10611122.120.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.6 20.0
21.8 10910320.620.0µg/LTetrachloroethene 70-130 5.6 20.0
22.6 11310821.620.0µg/LToluene 70-130 4.5 20.0
25.0 12512224.420.0µg/L1,2,3-Trichlorobenzene 70-130 2.4 20.0
24.2 12112124.220.0µg/L1,2,4-Trichlorobenzene 70-130 0.0 20.0
22.8 11410621.120.0µg/L1,1,1-Trichloroethane 70-130 7.7 20.0
Page 5 of 6Date:04/07/2023 09:02 AM
Page 29 of 32
Quality Control Data
23-088-0003Report No:
Project Description:
Client ID:Withers & Ravenel
Whitakers Service Station
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V31662QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V31661
LCS-V31661 LCSD-V31661Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
23.3 11711623.120.0µg/L1,1,2-Trichloroethane 70-130 0.8 20.0
23.4 11711222.320.0µg/LTrichloroethene 70-130 4.8 20.0
23.3 11711021.920.0µg/LTrichlorofluoromethane 60-140 6.1 20.0
21.5 10810320.620.0µg/L1,2,3-Trichloropropane 70-130 4.2 20.0
23.2 11611022.020.0µg/L1,2,4-Trimethylbenzene 70-130 5.3 20.0
22.7 11410621.220.0µg/L1,3,5-Trimethylbenzene 70-130 6.8 20.0
16.3 81.596.019.220.0µg/LVinyl Acetate 60-140 16.3 20.0
23.9 12011222.320.0µg/LVinyl Chloride 60-140 6.9 20.0
45.8 11510742.740.0µg/Lm,p-Xylene 70-130 7.0 20.0
22.5 11310821.520.0µg/Lo-Xylene 70-130 4.5 20.0
1021034-Bromofluorobenzene (S)70-130
102102Dibromofluoromethane (S)70-130
1041051,2-Dichloroethane - d4 (S)70-130
102101Toluene-d8 (S)70-130
Page 6 of 6Date:04/07/2023 09:02 AM
Page 30 of 32
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:23-088-0003
Withers & Ravenel
01221
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 0.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:03/29/2023 10:55:51
Special precautions or instructions included?
Comments:
Page 31 of 32
Page 32 of 32

APPENDIX B
FIELD NOTES & PHOTOGRAPHIC RECORD

PHOTO 1 View of site facing northwest

PHOTO 2 View of MW-1 facing southeast

PHOTO 3 View of MW-2 facing north
PHOTO 4 View of MW-3 facing southeast

PHOTO 5 View of SW-E. Blanton sampling location

APPENDIX C GENERAL STANDARD OPERATING PROCEDURES

Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
Our People. Your Success.
Soil Sampling, Soil Boring and Monitor Well Installation, Well Development Soil borings are installed utilizing a stainless-steel hand auger, direct-push hydraulic drill or auger rotary
drill using either a macro core™ sampler, hollow stem augers, or air rotary roller cone bit. Soil borings are
typically sampled at discrete intervals from the bucket of a clean stainless steel hand auger, direct push stainless steel sampler with acetate sleeve, or a split barrel sampler. When appropriate, soil samples may be collected from drill cuttings associated with the boring or well installation. Monitor wells are constructed within select soil borings of one, two, or four-inch inside diameter PVC
casing and machine slotted screen in accordance with NCAC Title 15A, Subchapter 02C (Well Construction Standards, Criteria and Standards Applicable to Water Supply and Certain Other Wells). Clean-washed “#2 Torpedo Sand” is typically utilized to fill the boring annulus surrounding the well screen, extending to a minimum of 1-foot above the well screen. A minimum 1-foot thick bentonite clay seal is emplaced above the sand pack and hydrated. Neat cement grout is placed in the remaining annulus
space from the upper portion of the bentonite seal to within 1-foot of surface grade. In coastal plain areas where shallow groundwater is encountered, a variance to construction standards may be employed to ensure the upper portion of the well screen intersects the upper aquifer surface. Wellheads may be completed with either concrete-set flush mounted traffic-bearing steel skirted manholes with bolt down covers or steel above-ground “stick-up” well protectors set in a concrete pad. The monitoring wells are
secured with locking caps. Temporary wells or piezometers may be completed with the PVC riser cut at or above grade, and are abandoned within 24-hours of their installation. Wells may be developed using a bailer, electric submersible pump, pneumatic pump, or peristaltic pump, dependent upon site conditions. When wells are developed by the driller, they may be developed with
any of the methods outlined above, in addition to air or water injection. Soil boring logs and well construction details are typically prepared for presentation in a report appendix. Borings completed in bedrock may be drilled using air rotary, coring, or sonic drilling methods. Groundwater Depth to Water Measurements

Groundwater level measurements are typically obtained using an electronic water level indicator which registers a tone and/or illuminated light when the probe contacts groundwater. Depth to groundwater measurements are obtained by lowering the probe attached to a cable usually marked in 0.01 foot intervals into the well until the probe of the meter intersects the water surface. The measurement from
the top of the riser pipe or top of casing (TOC) to the water level is recorded to the nearest 0.01 foot. The
electronic water level indicator probe and exposed probe cable is decontaminated between measurement locations.

Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
Our People. Your Success.
Free Product Level Measurements Light Non-Aqueous Phase Liquid (LNAPL) or “free product” present on the water table is measured using
an electronic oil/water interface probe. The interface probe has both an audible and illuminating light
that indicate when a liquid level is encountered. The oil/water interface probe registers a solid tone and solidly lit light when LNAPL petroleum product is encountered and a beeping tone flashing light when groundwater is encountered. Depth to LNAPL measurements are obtained by lowering the probe attached to a cable marked in 0.01 foot intervals into the well until the probe of the meter intersects the product or groundwater. The measurements from the top of the riser pipe or TOC to the liquid level are
recorded to the nearest 0.01 foot. The thickness of LNAPL is calculated by subtracting the depth to LNAPL measurement from the depth to groundwater measurement. The electronic interface probe is decontaminated between measurement locations. Soil Sampling and Field Screening
Soil sampling is performed in general accordance with ASTM: 1586-84 where applicable. Sampling procedures are followed to protect the chemical integrity of the soil samples and minimize the potential for cross contamination between sample locations, including discarding of the exterior of the sample which contacts the auger bucket, acetate sleeve, or split barrel sampler, the use of stainless steel sampling
equipment, and the thorough decontamination of sampling apparatus prior to use and between sample locations. Soil samples retained as a part of excavation or other intrusive “digging” activities may be collected from the bucket of excavation equipment or using a hand shovel, if appropriate. Care to collect soil samples
from excavation equipment includes retrieving native soil from material that has not made contact with the excavating equipment. Samples are collected in sealable bags or by directly filling sample containers as described above. Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample
integrity and minimize the potential for cross contamination or field personnel exposure to contaminants.
Sampling equipment such as hand auger extensions and buckets, direct push samplers, split spoons or shovels, are decontaminated prior to their use in the collection of samples. Samples are placed within laboratory grade sample containers provided by the laboratory to which the
samples are submitted, labeled, sealed, and placed in an ice filled cooler. An aliquot of the sample is
typically placed in a clean sealable bag and allowed to reach ambient air temperature for future screening of volatile vapor content with a photoionization detector (PID), flame-ionization detector (FID) or other portable screening device.
Screening of samples with a PID, FID or other field screening device is performed in accordance with
device manufacturer specifications for screening, following calibration of the instrument based on manufacturer recommended procedures.

Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
Our People. Your Success.
Groundwater Sampling Groundwater samples are generally collected using one of three standard methods – through the use of a
dedicated, disposable bailer, a peristaltic pump or submersible electric pump.
When sampling with a bailer, a minimum of three well volumes of groundwater are extracted from the well as a means of purging, unless the well is purged to a “dry” state prior to the removal of three volumes of water. Prior to collection of the groundwater sample with the bailer, the water level is allowed to recover to within 80% of the original level measured prior to purging.
When sampling with a peristaltic or submersible electric pump, polyethylene (PE) tubing (or equivalent) is emplaced into the screened section of the monitoring well, and the pump is used to extract water through the tubing. When using the either of these methods, general water quality measurements including but not limited to pH, temperature, dissolved oxygen (DO), oxygen reductive potential (ORP), specific
conductivity and turbidity may be used as methods for determining when an adequate purge of the well has been conducted. When water quality parameters are measured, the resulting data are included in well purge forms or field notes specific to each site and sampling point. Following the purging of three well volumes of groundwater (in the case of the bailed well) or stability of
monitored measurements (in the case of the peristaltic or submersible electric pump), the groundwater sample(s) are introduced directly into sample containers provided by the laboratory to which samples are ultimately submitted for analysis. Any samples requiring chemical preservation are contained in pre-preserved container(s) provided by the laboratory.
Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample integrity and minimize the potential for cross contamination of samples or field personnel exposure to contaminants. Water Supply Well Sampling

Sampling of water supply wells is accomplished through the collection of a representative sample from an in-line water tap or other point accessible for sampling. Where possible, the sample is collected from a point prior to any filtration or point of entry (POE) system which might be installed on a well. In some cases, samples will be collected from both pre and post-POE locations. Prior to the collection of samples
through an in-place sampling point, the tap or sampling port is cleaned with an Alconox® and deionized
water solution, rinsed with deionized water, and again with an isopropyl alcohol (IPA) rinse. In the case of active supply wells (e.g., a well with a useable well pump with an active power supply), the well pump is energized and allowed to run for a minimum of ten (10) minutes time, after which a sample is
contained in laboratory grade sample containers as described in the previous section. Water quality
parameters may be (but are not necessarily) measured in association with the well purging. Supply wells without active power supplies are not generally sampled, as the well seal cannot be compromised by individuals not certified as a well contractor. However, in the case of a well with no
power supply or pump installed, samples could be obtained through the use of a bailer, peristaltic pump or
electric submersible pump.
Generalized Standard Operating Procedures (Not All Inclusive)

WithersRavenel
Our People. Your Success.
Decontamination Procedures Decontamination procedures employed in the performance of field activities will vary dependent upon
the method(s) of sampling performed at any site, but will generally include the following:
• Remove excess soil/sludge from any sampling equipment as needed, • Wash and scrub the equipment with a phosphate-free detergent such as Alconox® or Liquinox® in a contaminant-free tap water solution. Use a brush to remove particulate matter and surface films as necessary,
• Rinse thoroughly with tap water, • Rinse thoroughly with analyte-free water (deionized water),
 Rinse thoroughly with isopropyl alcohol, • Allow the equipment to air dry,
• Prevent inadvertent contamination during storage and transport (accomplished through storage of equipment in foil or plastic bags/sheeting). In the case of disposable bailers and tubing utilized for the purging and sampling of wells, these items may be decontaminated prior to their disposal. In general, no decontamination of these items is necessary
prior to their use in sampling.
WithersRavenel
Our People. Your Success.
Former Whitaker’s Service Station – NCDEQ Incident #12487 WR Project # 23-0307-EY Monitoring Report May 2023 11
• If funding is available, conduct a Remedial Design Characterization (RDC) to further characterize the extent of contamination in the subsurface to design an appropriate remedial
strategy.