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HomeMy WebLinkAboutAS-1789_20326_CA_MRP_20230510  WithersRavenel Our People. Your Success.    115 MacKenan Drive | Cary, NC 27511  t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479  Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington          GROUNDWATER MONITORING REPORT    Foothills Service Center  NCDEQ Incident #20326  UST # AS‐1789   312 East Union Street  Morganton, Burke County, North Carolina  WithersRavenel Project No. 23‐0307‐B                                            Prepared for:  State of North Carolina  Department of Environmental Quality  Division of Waste Management   Underground Storage Tank Section  Federal & State Lead Program  1646 Mail Service Center  Raleigh, North Carolina 27699‐1646    Prepared by: WithersRavenel 115 MacKenan Drive  Cary, North Carolina 27511  North Carolina Firm License No. F‐1479  May 10, 2023 .    WithersRavenel Our People. Your Success.        115 MacKenan Drive | Cary, NC 27511  t: 919.469.3340 | f: 919.467.6008 | www.withersravenel.com | License No. F‐1479  Asheville | Cary | Charlotte | Greensboro | Lumberton | Pittsboro | Raleigh | Southern Pines | Wilmington    May 10, 2023    State of North Carolina  Department of Environmental Quality  Federal & State Lead Program  Division of Waste Management‐Underground Storage Tank Section  1646 Mail Service Center  Raleigh, North Carolina 27699‐1646    Attn:  Ms. Sharon Ghiold    Re:  Groundwater Monitoring Report   Foothills Service Center  312 East Union Street  Morganton, Burke County, North Carolina  Groundwater Incident Number: 20326  UST Number: AS‐1789  WR Project Number:  23‐0307‐B    Ms. Ghiold:  WithersRavenel, Inc. (WR) has completed this Groundwater Monitoring Report to document a  limited groundwater sampling event including monitoring wells MW‐1, MW‐2, MW‐3, MW‐7, and  MW‐8 in association with task authorization TA‐02, for the above referenced site, approved by  the Trust Fund Branch on April 4, 2023.     WR appreciates the opportunity to be of service to the Federal & State Lead Program. Should you  have any questions regarding the attached, please contact us at (919) 469‐3340.    Cordially,  WithersRavenel              Cory Nobles      Elizabeth A. Allyn, P.G.  Environmental Geologist II    Environmental Project Geologist II WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  i      TABLE OF CONTENTS  SECTION A: SITE INFORMATION ..................................................................................................................... 1  SECTION B. EXECUTIVE SUMMARY ................................................................................................................ 3  SECTION C. SITE HISTORY AND CHARACTERIZATION ............................................................................ 5  SECTION D. GROUNDWATER SAMPLING – APRIL 2023 ......................................................................... 8  SECTION E. CONCLUSIONS AND RECOMMENDATIONS ........................................................................ 9    FIGURES   Figure 1 General Location Map  Figure 2 Site Map  Figure 3 Groundwater Elevation Contour Map  Figure 4 Groundwater Analytical Map  Figure 5 Benzene Isoconcentration Map     TABLES   Table B‐1 Site History: UST/AST System & Other Release Information  Table B‐4 Summary of Groundwater Analytical Results  Table B‐7 Monitoring Well Construction Information  Table B‐9 Current & Historical Groundwater Elevations & LNAPL Thicknesses     APPENDICES   Appendix A Remedial Well Construction Records  Appendix B Field Notes and Photographic Record  Appendix C Laboratory Analytical Report  Appendix D WR’s Standard Operating Procedures  WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  1    SECTION A: SITE INFORMATION 1. Site Identification  Date of Report:  May 10, 2023  Facility I.D.: 00‐0‐0000004714  Incident No.: 20326  UST No.: AS‐1789  Site Risk: Intermediate  Site Rank: I175D  Land Use Category: Central Business District (CBD)  Site Name: Foothills Service Center  Site Location: 312 East Union Street  Nearest City/Town: Morganton  County: Burke  Description of Geographical Data Point:  Center of UST Area 1  Location Method:  Google Earth™  Latitude: 35.747905°  Longitude: ‐81.685458°  2. Contact Information  UST Operator: Unknown  Address: Not Applicable  Phone: Not Applicable     Property Owner: Redevelopment Commission of the City of Morganton  Address: P.O. Box 3448, Morganton, NC 28680  Phone: 828‐438‐5270     Property Occupant: Undeveloped  Address: Not Applicable  Phone: Not Applicable     Consultant/Contractor: WithersRavenel, Inc.  Address:  115 MacKenan Drive, Cary, NC 27511  Phone:  919‐469‐3340     Analytical Laboratory: Waypoint Analytical, LLC   State Certification Number: ENV402  Address: 449 Springbrook Rd., Charlotte, NC 28217  Phone: 704‐529‐6364     WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  3     SECTION B. EXECUTIVE SUMMARY   1. Summary of Activities Associated with Current TA    WithersRavenel, Inc. (WR) sampled monitoring wells MW‐1, MW‐2, MW‐3, MW‐7, and MW‐8 at  the Foothills Service Center site located at 312 East Union Street in Morganton, Burke County,  North Carolina in association with task authorization TA‐02 under North Carolina Department of  Environmental Quality (NCDEQ) Contract #N70522‐C.     2. Soil, Groundwater and LNAPL Assessment Information     Soils  During the installation of monitoring well MW‐8 on February 2, 2023, WR collected a risk‐based  soil sample from the interval below the fill and above the water table identified as SB‐1 (20‐25).  This soil sample contained naphthalene above the Industrial/Commercial Maximum Soil  Contaminant Concentration (MSCC) and several compounds above the Soil‐to Groundwater and  Residential MSCCs. In addition, as part of a potential property transaction, S&ME advanced  fourteen soil samples throughout the site and on the adjacent property. The soil samples collected  in the vicinity of the former underground storage tank (UST) system exhibited concentrations  above the Soil‐to‐Groundwater and Residential MSCCs, but not the Industrial/Commercial  MSCCs. These soil samples were collected between 15 and 25 feet below ground surface.    Groundwater   WR collected samples from groundwater monitoring wells MW‐1 through MW‐3 and MW‐7 and  MW‐8 on April 17, 2023.  The groundwater samples were submitted for laboratory analysis of  volatile organic compounds (VOCs) by SM 6200B.    Laboratory analysis of the groundwater samples collected from MW‐1, MW‐7, and MW‐8  indicated benzene above the Gross Contamination Levels for Groundwater (GCLs) and MW‐1 and  MW‐7 had 1,2‐dibromoethane above the GCL. Monitoring well MW‐2 contained one or more  petroleum compounds above the North Carolina 2L Groundwater Quality Standards (2L  Standards). Monitoring well MW‐3 did not indicate compounds above the laboratory detection  limits.    Liquid Non‐Aqueous Phase Liquid  Light non‐aqueous phase liquid (LNAPL) was not detected during the April 17, 2023 sampling  event. LNAPL has historically been detected in monitoring well MW‐1.    3.       Receptor Information    The area within 1,500‐feet of the subject property is supplied potable water by the Town of  Morganton Municipal Water System.  WR is not aware of any surface water bodies within 500‐ feet of the subject property.  WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  4     4. Remediation Activities    Based on WR’s review of historical files available for the site, the following remedial activities have  been completed at the site:   Six 560‐gallon USTs, one 1,000‐gallon UST, one 1,200‐gallon UST, and one 2,000‐gallon UST  were removed from the subject property on March 23‐31, 2020. A total of 828.99 tons of  petroleum‐impacted soil were removed the property during the UST removal.     In January 2022, WR conducted a Mobile Multi‐Phase Extraction (MMPE) event at the site  utilizing MW‐1. During the MMPE event, eight gallons of LNAPL and 2,206 gallons of VOC‐ impacted water were recovered and transported offsite for disposal. Based on mass removal  calculations, 1,083.28 pounds of VOCs or 176.09 gallons of VOCs were removed as vapor  during the event.     WR conducted two air sparge enhanced MMPEs (AS/MMPEs) in March 2023, one the week  of March 6, 2023 and one the following week. In completion of the AS/MMPE events, a total  of 9,121‐gallons of contaminated water was recovered and based on mass removal  calculations, a total of 1,171.24‐pounds or 190.39‐gallons of volatile organic compounds  (VOCs) were removed as vapor.        5. Recommendations  Based on the results of the activities conducted at the site in association with this TA, WR  recommends the following:   Evaluating remedial options after the in situ Chemical Oxidation bench scale testing results  for the A.G. Jobe site (NCDEQ Incident #30075) are received.       WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  5     SECTION C. SITE HISTORY AND CHARACTERIZATION   The following information summarizes the site history and characterization.      1. UST Information  In September 2000, seven USTs (UST‐1 through UST‐6, and UST‐9) were emptied and closed in  place using foam.  In January 2020, WR conducted a ground‐penetrating radar (GPR) survey to  identify the locations of the closed‐in‐place USTs. In March 2020, WR completed the closure by  removal of the UST systems which included six 560‐gallon USTs, one 1,000‐gallon UST, one  1,200‐gallon UST, and one 2,000‐gallon UST.  Information regarding the USTs is summarized on  Table B‐1.    2.       Description of Release/General Assessment History  The following summary of the assessment history is based on WR’s review of historical files for  the subject incident:  February 1997 ‐ Phase II–Abandoned UST Study, LAW Engineering and Environmental Services,  Inc. (LAW)    LAW completed underground locating and confirmed the presence of five USTs, one UST was  present in one tank basin and the remaining four identified USTs were in an additional tank basin.   LAW collected soil samples around the two UST basins. Results indicated the presence of TPH‐ GRO exceeding the current NCDEQ Action Level in four of the seven soil samples collected.  The  groundwater samples collected from the soil borings indicated the presence of impacts above the  2L Standards in each of the six samples with the GCL for benzene exceeded in four of the six  groundwater samples.  LAW personnel did not identify water supply wells on the site or adjacent  properties and the area is served by municipal water.      September 2000 – UST Removal and Abandonment, Royster Oil Company, Inc. (Royster)    Royster abandoned‐in‐place seven USTs using foam and removed one 550‐gallon UST in the  triangle formed by the intersection of Lenoir Street and East Union Street.     February 2020 – Initial Groundwater Monitoring Report (WR)  WR performed a GPR survey and collected soil and groundwater samples. The GPR survey  identified five USTs at the site. Soil sampling indicated the petroleum release appears to be  concentrated near the former dispenser island and its adjacent tanks and that soil contamination  extends to the groundwater table at approximately 25 feet bgs. The groundwater plume appears  to be primarily concentrated near the dispenser island.     May 2020 – Initial Abatement Action Report (WR)  WR supervised the removal of nine USTs consisting of six 560‐gallon USTs, one 1,000‐gallon UST,  one 1,200‐gallon UST, and one 2,000‐gallon UST between March 23 and 31, 2020. Two additional  USTs were identified during the UST removal activities in the UST basin previously thought to  contain one UST. A total of 828.99 tons of petroleum‐impacted soils were removed from the site  WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  6     during the UST closure activities and transported off‐site for treatment and disposal.  Exceedances  of the Soil‐to‐Groundwater and Residential MSCCs were observed in the soil samples collected  from Excavation 1 and Excavation 4.  Excavation 1 encompassed the dispensers and USTs 1  through 4 and extended to approximately 18‐20 feet bgs and Excavation 4 included USTs 7, 8 and  9 and extended to approximately 7 feet bgs.     September 2020 – Subsequent Monitoring Report (WR)  WR installed and collected samples from monitoring wells MW‐1 through MW‐3 on July 14, 2020.   The groundwater sample collected from monitoring well MW‐1 indicated benzene and EDB above  the GCL. Multiple contaminants were identified above the 2L Standards in monitoring wells MW‐ 1 through MW‐3. LNAPL was not observed in the site monitoring wells.  The groundwater flow  direction was determined to be to the south, generally towards an unnamed tributary of Hunting  Creek approximately 920 feet to the southeast.      February 2021 – Annual Monitoring Report (WR)  WR collected samples from monitoring wells MW‐1 through MW‐3 on January 20, 2021.  The  groundwater sample collected from monitoring well MW‐1 indicated benzene and EDB remained  above the GCL. Multiple contaminants were identified above the 2L Standards in monitoring wells  MW‐1 through MW‐3. LNAPL was not observed in the site monitoring wells.      August 2021 – Corrective Action Feasibility Study (WR)  Based on the observed soil and groundwater concentrations, LNAPL was determined to likely be  present at the site. Therefore, WR recommended a surfactant‐enhanced injection and MMPE  event. Since EDB was not likely to be addressed by this approach, WR recommended treating the  remaining contaminant mass via a carbon‐based injection such as Trap & Treat BOS 200®,  PetrofixTM, or similar injectates.     March 2022 – Subsequent Monitoring Report (WR)  On January 24 through 28, 2022, WR supervised a MMPE event. Prior to the MMPE event, the  depth to LNAPL and groundwater measurements in MW‐1 were 27.60 feet below the top of  casing (ft‐BTOC) and 27.99 ft‐BTOC, respectively, for a LNAPL thickness of 0.39 feet. During the  radius of influence gauging conducted on January 28, 2022, as part of the MMPE event, LNAPL  was detected in monitoring well MW‐2 at a thickness of 0.07 feet. Approximately eight gallons of  LNAPL and 2,206 gallons of VOC‐impacted water were recovered and transported offsite for  disposal. Based on mass removal calculations, 1,083.28 pounds of VOCs or 176.09 gallons of  VOCs were removed as vapor during the event.    WR mobilized to the site on March 2, 2022 to sample three Type II groundwater monitoring wells.  Monitoring well MW‐1 contained LNAPL at a thickness of 0.41 feet and was not sampled.  Laboratory analysis of the groundwater samples collected from monitoring wells MW‐2 and MW‐ 3 identified one or more petroleum compounds above the 2L Standards, but not the GCLs.       WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  7     March 2023 – Groundwater Monitoring Report (WR)  WR supervised the installation of two monitoring wells, sampled the five monitoring wells at the  site, and installed one 4” remediation well and three 2” air sparge wells. During the installation of  monitoring well MW‐8 on February 2, 2023, WR collected a risk‐based soil sample from the  interval below the fill and above the water table identified as SB‐1 (20‐25). This soil sample  contained naphthalene above the Industrial/Commercial MSCC and several compounds above the  Soil‐to Groundwater and Residential MSCCs.   Laboratory analysis of the groundwater samples collected from MW‐7 indicated benzene and 1,2‐ dibromoethane above the GCLs and MW‐8 had benzene above its GCL. Monitoring wells MW‐2,  MW‐3, MW‐4, MW‐7, and MW‐8 detected one or more petroleum compounds above the 2L  Standards.   On February 27, 2023, WR personnel along with Geologic Exploration (GEX) mobilized to the site  to install one 4‐inch groundwater recovery well and three 2‐inch air sparge wells via hollow stem  auger. The 4‐inch diameter recovery well was installed to a depth of 40 feet with 15 feet of screen.  The 2‐inch diameter air sparge wells were installed to depths of 40 feet each with five feet of  screen. The well construction records from GEX are included in Appendix A as they were not  submitted by GEX prior to submittal of the Groundwater Monitoring Report dated March 30,  2023.    April 2023 – Letter Report – MMPE Events (WR)  WR mobilized to the subject site on March 6, 2023 and March 13, 2023, for the purposes of  performing two AS/MMPE events on select monitoring wells and recovery well RW‐1 and utilizing  air sparge wells AS‐1, AS‐2, and AS‐3 for air injection. Throughout the course of the AS/MMPE  events, effluent emissions ranged from 8,000 parts per million (ppm) to 100,000 ppm. In  completion of the AS/MMPE events, a total of 9,121‐gallons of contaminated water was  recovered and based on mass removal calculations, a total of 1,171.24‐pounds or 190.39‐gallons  of volatile organic compounds (VOCs) were removed as vapor.      3.  Site Characteristics  The site is located in an urban (commercial) area of Morganton, Burke County, NC (Figure 1),  addressed as 312 East Union Street.  This property is indexed by the Burke County GIS system as  Burke County Real Estate ID #31519, NC PIN 2703372877.  The property encompasses  approximately 0.27 acres of land and is utilized as a parking area for the City of Morganton.    The property is bounded along its eastern side by White Street, and to the north by East Union  Street.  The site is bordered to the south and west by undeveloped grass lots. Eight Type II  monitoring wells associated with assessment activities performed at the site are located at the site  as shown on Figure 2.    Natural gas, water and sanitary sewer services to the location are provided through buried lines.   Electrical service is provided overhead. Stormwater drainage is provided through man‐made  WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  8     conveyances (e.g., buried lines, drop inlets).  Surface runoff is channeled through these stormwater  conveyances.    4.       Information on Receptors/Potential Receptors  The area within 1,500‐feet of the subject property is supplied potable water by the Town of  Morganton Municipal Water System.  WR is not aware of surface water bodies within 500‐feet of  the subject property.  Evaluation of the Morganton, NC, Topographic Quadrangle (US Geological Survey, 7.5 Minute  Series, 2019) and 2‐ft elevation contours provided by the Burke County GIS Service indicate that  the subject property is at an approximate elevation of 1,172 feet above mean sea level (AMSL) at  the center of the subject property.  A scaled portion of the USGS Quadrangle is included as Figure  1.  Topography at the site slopes primarily to the southeast.         5.       Regional and Site Geology and Hydrology  The Geologic Map of North Carolina (Department of Natural Resources, Division of Land  Resources, North Carolina Geologic Survey, 1985) shows materials underlying the site to consist  of “migmatitic granitic gneiss” of Cambrian‐Ordovician age, within intrusive rocks of the Inner  Piedmont, Chauga Belt, Smith River Allochthon, and Sauratown Mountain Belts.  Base materials at  the site location are indexed as “foliated to massive, granitic to quartz dioritic; biotite gneiss and  amphibolite common.”  The site is adjacent to what is mapped as “biotite gneiss and schist” of Late  Proterozoic‐Cambrian age, with metamorphic rocks of the Inner Piedmont, Chauga Belt, Smith  River Allochthon, and Sauratown Mountain Belts. Base materials in this area are indexed as  “inequigranular, locally abundant potassic feldspar and garnet; interlayered and gradational with  calc‐silicate rock, sillimanite‐mica schist, and amphibolite and contains small masses of granitic  rock.”   According to the United States Department of Agricultural (USDA) Natural Resources  Conservation Service (NRCS) Web Soil Survey, the source area is underlain by urban land soils.  Urban land is defined as impervious layers over human‐transported material. Boring log and  excavation records from the site indicate that the general lithology of the site soils consists of  micaceous silts and clayey silts.    SECTION D. GROUNDWATER SAMPLING – APRIL 2023 WR mobilized to the site on April 17, 2023, to sample monitoring wells MW‐1 through MW‐3 and  MW‐7 and MW‐8. The locations of monitoring wells MW‐1 through MW‐8 are shown on Figure  2.  Prior to purging activities, groundwater levels were gauged with a decontaminated electronic oil‐ water interface meter. Groundwater levels measured within the monitoring wells ranged from  25.71 ft‐BTOC in monitoring well MW‐8 to 26.70 ft‐BTOC in monitoring well MW‐3. The  monitoring wells were screened across the water table. Groundwater elevations were utilized to  WithersRavenel Our People. Your Success.  Foothills Service Center – NCDEQ Inc. #20326 WR Project # 23‐0307‐B  Groundwater Monitoring Report May 2023  9     generate a groundwater flow map at the site, based on the April 2023 groundwater levels (Figure  3).  Groundwater elevation data indicated that groundwater flows to the southeast in the vicinity  of the source area.  Groundwater elevations and well construction information is summarized in  Table B‐7. Historical groundwater elevations and LNAPL thicknesses are included in Table B‐9.  After gauging, the monitoring wells were purged a minimum of three volumes of groundwater  using dedicated bailers.  Groundwater samples were then placed directly into laboratory‐provided  containers, placed on ice, and under property chain‐of‐custody procedures, transported to  Waypoint Analytical, Inc. located in Charlotte, NC, to be analyzed for VOCs by SM6200B.  Laboratory Results  Laboratory analysis of the groundwater samples collected from MW‐1, MW‐7, and MW‐8  indicated benzene above the GCLs and MW‐1 and MW‐7 had 1,2‐dibromoethane above the GCL.  Monitoring well MW‐2 contained one or more petroleum compounds above the 2L Standards.  Monitoring well MW‐3 did not indicate compounds above the laboratory detection limits.  A summary of the groundwater analytical results is presented in Table B‐4 and shown on Figure  4. A benzene isoconcentration map is included as Figure 5. A photographic record and the field  notes are included in Appendix B.  A copy of the laboratory analytical report and chain‐of‐custody  is included in Appendix C.  WR’s standard operating procedures are provided in Appendix D.    SECTION E. CONCLUSIONS AND RECOMMENDATIONS This report documents the results of field activities conducted at the site for TA‐02, which included  a limited groundwater sampling event which included monitoring wells MW‐1, MW‐2, MW‐3,  MW‐7, and MW‐8. Conclusions based on observations, analytical data and research relating to  the release at the site combined with historical information include the following:   The soil remedial goals for the site are the Industrial/Commercial MSCCs. A soil sample  collected in February 2023 contained naphthalene above the Industrial/Commercial MSCC.    The groundwater remedial goals are the GCLs. Laboratory analysis of the groundwater  samples collected from MW‐1, MW‐7, and MW‐8 indicated benzene above the GCLs and  MW‐1 and MW‐7 had 1,2‐dibromoethane above the GCL.    The site is currently utilized as a parking lot by the City of Morganton.   Contaminant concentrations in monitoring well MW‐2 did not exceed the GCLs.   Monitoring well MW‐3 did not exhibit concentrations exceeding the laboratory detection  limits.  Based on the results of assessment and monitoring activities conducted at the site in association  with this TA, WR recommends the following:   Evaluating remedial options after the in situ Chemical Oxidation bench scale testing results  for the A.G. Jobe site (NCDEQ Incident #30075) are received.      WithersRavenel Our People. Your Success.    FIGURES     P U M P I S L A N D EAST UNION STREET WHITE STREETEXCAVATION 3EXCAVATION 4EXCAVATION 1EXCAVATION 2MW-1MW-3MW-2MW-7MW-4(S&ME)MW-5(S&ME)MW-6(S&ME)AS-3AS-1AS-2RW-1MW-8DCV EAA DRAWN BY: 03/06/2023 23-0307-B 2 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY:SITE MAP WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 license #: F-1479 | www.withersravenel.com 1"=20 '201040FORMER FOOTHILLS SERVICE CENTER TF20326 312 EAST UNION STREET MORGANTON, BURKE COUNTY, NCLEGENDNOTES: 1.) 2018 AERIAL OBTAINED FROM NC ONEMAP.0GRAPHIC SCALE1 inch = 20 feet EAST UNION STREET WHITE STREETMW-1MW-3MW-2MW-7MW-4(S&ME)MW-5(S&ME)MW-6(S&ME)(73.68)(73.59)(73.12)73.50(73.08)(72.91)73.2573.00(NM)(NM)(NM)AS-3AS-1AS-2RW-1MW-8DCV EAA DRAWN BY: 05/02/2023 23-0307-B 3 SCALE:FIGURE NO.: PROJECT NO.:DATE:APPROVED BY: GROUNDWATER ELEVATION CONTOUR MAP (APRIL 17, 2023) WithersRavenel Engineers | Planners | Surveyors 115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340 license #: F-1479 | www.withersravenel.com 1"=20 'GRAPHIC SCALE1 inch = 20 ft.0201040 FOOTHILLS SERVICE CENTER TF-20326 312 EAST UNION STREET MORGANTON, BURKE COUNTY, NCLEGENDNOTES: 1.) AERIAL OBTAINED FROM NC ONEMAP. 2.) MONITORING WELLS MW-7 AND MW-8 WERE NOT USED FOR CONSTRUCTING GROUNDWATER ELEVATION CONTOURS.(73.08) PUMP ISLA ND EXCAVATION 3 EXCAVATION 4 EXCAVATION 1 EXCAVATION 2 MW-1 MW-3 MW-2 MW-7 MW-4 (S&ME) MW-5 (S&ME) AS-3 AS-1 AS-2 RW-1 MW-8 EAAEAADRAWN BY:05/03/202323-0307-B4SCALE:FIGURE NO.:PROJECT NO.:DATE:APPROVED BY:GROUNDWATER ANALYTICALRESULTS MAP(APRIL 17, 2023)WithersRavenelEngineers | Planners | Surveyors115 MacKenan Drive | Cary, NC 27511 | t: 919.469.3340license #: F-1479 | www.withersravenel.com1"=20 '2010 40 FOOTHILLS SERVICE CENTERTF20326312 EAST UNION STREETMORGANTON, BURKE COUNTY, NCLEGEND NOTES: 1.) 2018 AERIAL OBTAINED FROM NC ONE MAP. 0 GRAPHIC SCALE 1 inch = 20 feet WithersRavenel Our People. Your Success.      TABLES     UST IDNumberCurrent/LastContentsPreviousContentsCapacity(in gallons)ConstructionDetailsTankDimensions (diameter x length) (ft)Description ofAssociatedPiping & PumpsDate of TankInstallationStatus ofUSTWas release associated with UST System? (Y/N)1* Petroleum Unknown 560 Single Wall Steel 3.5 x 7.6 N/A Unknown Removed 03/2020 Yes2* Petroleum Unknown 560 Single Wall Steel 3.5 x 7.6 N/A Unknown Removed 03/2020 Yes3* Petroleum Unknown 1,000 Single Wall Steel 4 x 10 N/A Unknown Removed 03/2020 Yes4* Petroleum Unknown 1,200 Single Wall Steel 4 x 12 N/A Unknown Removed 03/2020 Yes5* Petroleum Unknown 2,000 Single Wall Steel 5 x 12 N/A Unknown Removed 03/2020 Yes6* Petroleum Unknown 560 Single Wall Steel 3.5 x 7.6 N/A Unknown Removed 03/2020 Yes7 Petroleum Unknown 560 Single Wall Steel 3.5 x 7.6 N/A Unknown Removed 03/2020 Yes8 Petroleum Unknown 560 Single Wall Steel 3.5 x 7.6 N/A Unknown Removed 03/2020 Yes9* Petroleum Unknown 560 Single Wall Steel 3.5 x 7.6 N/A Unknown Removed 03/2020 YesIncidentNumberMaterialReleasedDateofRelease20326 Petroleum UnknownNotes:1)2)3) N/A = Not Available.Morganton, Burke County, NCDescription of ReleaseA Phase II Abandoned UST Study was conducted on the property in February 1997. Soil and groundwater contamination were discovered during the study above state action levels. * USTs # 1, 2, 3, 4, 5, 6 and 9 had been closed‐in‐place (foam‐filled) in September 2000.USTs # 7 and 8 were identified on the property during tank closure activities conducted during March 2020.  Table B‐1Site History:  UST/AST System & Other Release InformationFoothills Service CenterIncident # 20326312 East Union StreetPage 1 of 1 Acetone Benzenen‐Butylbenzenesec‐Butylbenzene1,2‐Dibromoethane1,2‐DichloroethaneEthylbenzeneDi‐isopropyl ether (IPE)Isopropylbenzene (Cumene) 4‐Isopropyltoluene2‐HexanoneMethyl Tert‐Butyl EtherNaphthalenen‐PropylbenzeneToluene1,2,4‐Trimethylbenzene1,3,5‐TrimethylbenzeneTotal Xylenes67‐64‐171‐43‐2 104‐51‐8 135‐98‐8 106‐93‐4 107‐06‐2 100‐41‐4 108‐20‐398‐82‐899‐87‐6 591‐78‐61634‐04‐491‐20‐3 103‐65‐1 108‐88‐395‐63‐6 108‐67‐81330‐20‐707/14/20 NR21,00061<7.6180260 4,000 290 210<8.9200 8,200 1,300 650 42,000 4,500 1,200 20,00001/20/21<100019,000<50 <50150260 3,800 270 180<50160 6,400 1,000 560 40,000 4,000 1,000 21,0001/24‐28/202203/02/2201/31/2302/02/233/6‐10/20233/13‐17/202304/17/23<100019,50069.7<50.098.9124 3,020 156 168<50.0 <1001,930 1,350 545 37,400 4,580 1,110 17,40007/14/20 NR940<7.6 <7.6 <5.1 <6.62,900<5.0210<8.9 <6.5 <4.21,000 580 420 4,000 1,000 15,20001/20/21<1000520 56<50 <50 <502,600<50230<50 <100 <1001,000 630 280 4,600 1,200 15,00003/02/22<100168 95.7 47.3<5.00 <5.002,020<5.00218 22.9<10.0 <10.01,500 619 153 4,310 1,130 12,20001/31/23NR52.2NR NR NR <9.501,320<10.0 NR NR NR <11.0503NR135 2,660 754NR02/02/23<100062.5 96.8 54.1<50.0 <50.01,580<50.0193<50.0 <100 <100879 530 115 5,150 1,510 11,30004/17/23<100059.3 65.5<50.0 <50.0 <50.01,270<50.0145<50.0 <100 <100810 396 101 3,840 1,100 8,43007/14/20 NR43 0.63 0.52<0.051 <0.0666.9<0.0501.8 0.50<0.065 <0.0425.3 3.4 3.9 88 20 12001/20/21<1016<0.50 <0.50 <0.50 <0.501.8<0.500.58<0.50 <1.0 <1.01.9 0.86<0.5034 7.4 4003/02/22<10.086.4 0.576 0.506<0.500 <0.5003.74<0.5002.34<0.500 <1.00 <1.008.26 1.39 0.796 139 21 14501/31/23NR24.3NR NR NR <0.11900.721 J0.313 J NR NR NR 0.577 J <3.00 NR0.449 J12.7 2.88NR02/02/23<10.017.9<0.500 <0.500 <0.500 <0.5000.983<0.5000.669<0.500 <1.00 <1.002.87<0.500<0.50016.5 3.79 24.204/17/23<10.0 <0.500 <0.500 <0.500 <0.500 <0.500<0.500 <0.500 <0.500 <0.500 <1.00 <1.00<1.00 <0.500 <0.500 <0.500 <0.500 <0.5006000 1 70 70 0.02 0.4 600 70 70 25 40 20 6 70 600 400 400 5006,000,000 5,000 5,900 8,800 50 400 80,000 70,000 30,500 11,700 40,000 20,000 6,000 26,100 260,000 28,500 24,100 50,000Notes:1)2)3)4)5)ResultResultResultGCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for Groundwater.MW‐2MW‐3NC 2L Standard GCLs for GroundwaterMW‐1AS/MMPE EventAS/MMPE Event= Result Exceeds NC Gross Contaminant Level for Groundwater.All results provided in ug/L (micrograms per liter) or parts per billion.Compounds analyzed for by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included in the Appendix for a full list of constituents. NC 2L Standard ‐ North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L.NR = Not reported.= Result Exceeds Laboratory Detection Limits.= Result Exceeds NC 2L Standard for Groundwater.TABLE B‐4SUMMARY OF GROUNDWATER ANALYTICAL RESULTSFoothills Service CenterIncident # 20326312 East Union StreetMorganton, Burke County, NCAnalytical Method SM6200BSample IDDateCollected0.41 feet of Light Non‐Aqueous Phase Liquid0.05 feet of Light Non‐Aqueous Phase LiquidMMPE performed on MW‐10.09 feet of Light Non‐Aqueous Phase LiquidPage 1 of 2 Acetone Benzenen‐Butylbenzenesec‐Butylbenzene1,2‐Dibromoethane1,2‐DichloroethaneEthylbenzeneDi‐isopropyl ether (IPE)Isopropylbenzene (Cumene) 4‐Isopropyltoluene2‐HexanoneMethyl Tert‐Butyl EtherNaphthalenen‐PropylbenzeneToluene1,2,4‐Trimethylbenzene1,3,5‐TrimethylbenzeneTotal Xylenes67‐64‐171‐43‐2 104‐51‐8 135‐98‐8 106‐93‐4 107‐06‐2 100‐41‐4 108‐20‐398‐82‐899‐87‐6 591‐78‐61634‐04‐491‐20‐3 103‐65‐1 108‐88‐395‐63‐6 108‐67‐81330‐20‐7TABLE B‐4SUMMARY OF GROUNDWATER ANALYTICAL RESULTSFoothills Service CenterIncident # 20326312 East Union StreetMorganton, Burke County, NCAnalytical Method SM6200BSample IDDateCollected02/02/232,88017,300200 98.1242378 5,060 278 347<50.0316 15,600 1,430 1,080 39,200 7,070 1,880 28,9003/6‐10/20233/13‐17/202304/17/23<100023,700<50.0 <50.0117260 2,950 309 153<50.0149 15,800<100432 40,600 3,170 780 16,60002/02/23<100013,4001,080 431<50.0 <50.07,620 141 895 179<1003,370 2,750 3,210 40,800 10,900 5,350 33,5003/6‐10/20233/13‐17/202304/17/23<10009,190<50.0 <50.0 <50.065.4 2,940 60.7 181<50.0146 1,640 1,090 514 29,900 3,660 933 16,800MW‐4 (S&ME) 02/01/23NR49.2NR NR NR3.57<0.5001.61NR NR NR23.9<3.00 NR <0.41016.5 3.41 40.6MW‐5 (S&ME) 02/01/23NR <0.130 NR NR NR0.291  J<0.500 <0.200 NR NR NR <0.220 <3.00 NR <0.410 <0.820 <0.560 <1.60MW‐6 (S&ME) 02/01/23NR <0.130 NR NR NR <0.190 <0.500 <0.200 NR NRNR <0.220 <3.00 NR <0.410 <0.820 <0.560 <1.606000 1 70 70 0.02 0.4 600 70 70 25 40 20 6 70 600 400 400 5006,000,000 5,000 5,900 8,800 50 400 80,000 70,000 30,500 11,700 40,000 20,000 6,000 26,100 260,000 28,500 24,100 50,000Notes:1)2)3)4)5)6) Results for MW‐4 (S&ME), MW‐5 (S&ME), and MW‐6 (S&ME) were provided by S&ME in a table.ResultResultResultNR = Not reported.= Result Exceeds Laboratory Detection Limits.= Result Exceeds NC 2L Standard for Groundwater.= Result Exceeds NC Gross Contaminant Level for Groundwater.NC 2L Standard GCLs for GroundwaterAll results provided in ug/L (micrograms per liter) or parts per billion.Compounds analyzed for by laboratory but not listed were not detected above laboratory detection limits. See the laboratory report included in the Appendix for a full list of constituents. NC 2L Standard ‐ North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L.GCLs for Groundwater = NCDEQ UST Section Gross Contamination Levels for Groundwater.MW‐7MW‐8AS/MMPE EventAS/MMPE EventAS/MMPE EventAS/MMPE EventPage 2 of 2 Easting NorthingMW‐17/14/2020 2 30 15 15‐30 100.00 4/17/2023‐‐‐26.32‐‐‐73.68 1203268.02 737925.29MW‐27/14/2020 2 30 15 15‐30 99.52 4/17/2023‐‐‐25.93‐‐‐73.59 1203216.30 737879.64MW‐37/14/2020 2 30 15 15‐30 99.82 4/17/2023‐‐‐26.70‐‐‐73.12 1203275.25 737852.27MW‐41/30/20232 35.5 15 20.5-35.5NM4/17/2023‐‐‐NM‐‐‐NM‐‐‐ ‐‐‐MW‐51/30/20232 30.5 15 15.5-30.5NM4/17/2023‐‐‐NM‐‐‐NM‐‐‐ ‐‐‐MW‐61/30/20232 28.7 15 13.7-28.7NM4/17/2023‐‐‐NM‐‐‐NM‐‐‐ ‐‐‐MW‐72/2/2023 2 33 18 18‐33 99.50 4/17/2023‐‐‐26.59‐‐‐72.91‐‐‐ ‐‐‐MW‐82/2/2023 2 33 18 18‐33 98.79 4/17/2023‐‐‐25.71‐‐‐73.08‐‐‐ ‐‐‐RW‐12/27/2023 4 40 25 25‐40 NM 4/17/2023‐‐‐NM‐‐‐NM‐‐‐ ‐‐‐AS‐12/27/2023 2 40 35 35‐40 NM 4/17/2023‐‐‐NM‐‐‐NM‐‐‐ ‐‐‐AS‐22/27/2023 2 40 35 35‐40 NM 4/17/2023‐‐‐NM‐‐‐NM‐‐‐ ‐‐‐AS‐32/27/2023 2 40 35 35‐40 NM 4/17/2023‐‐‐NM‐‐‐NM‐‐‐ ‐‐‐Notes:TABLE B‐7312 East Union StreetMONITORING WELL CONSTRUCTION INFORMATIONWell Casing Diameter(inches)LNAPL Thickness(feet)Monitoring Well IDGroundwaterElevation        (feet)Foothills Service CenterIncident # 20326Depth‐to‐Water from Top‐of‐Casing(feet)Morganton, Burke County, NCTotal Depth     (feet)Top‐of‐Casing Elevation     (feet)Well Casing Depth (feet)Screened Interval     (feet)Depth‐to‐LNAPL from Top‐of‐Casing(feet)3) Groundwater elevation adjusted for LNAPL is [Top of Casing Elevation ‐ Depth to Water] + [LNAPL Thickness * 0.8581].1) Well Top of Casing (TOC) elevation based on arbitrary 100.00 ft benchmark established at TOC for MW‐1.4) NM = Not measured..2) LNAPL = Light Non‐Aqueous Phase Liquid.Well Coordinates(NC State Plane NAD 83 Feet)Date Water Level MeasuredDate Installed  Page 1 of 1 Easting Northing7/14/2020‐‐‐25.99‐‐‐74.011/20/2021‐‐‐24.96‐‐‐75.041/24/2022 (pre‐MMPE) 27.60 27.99 0.39 72.341/28/2022 (post‐MMPE)‐‐‐29.62‐‐‐70.383/2/2022 27.39 27.80 0.41 72.552/1/2023 26.96 27.05 0.09 73.032/2/2023 27.05 27.00 0.05 73.042/27/2023‐‐‐26.50‐‐‐73.503/6/2023  (pre‐MMPE) 26.50 26.51 0.01 73.503/10/2023  (post‐MMPE) 26.66 26.85 0.19 73.313/13/2023  (pre‐MMPE) 26.40 26.50 0.10 73.593/17/2023  (pre‐MMPE)‐‐‐28.80‐‐‐71.204/17/2023‐‐‐26.32‐‐‐73.687/14/2020‐‐‐25.82‐‐‐73.701/20/2021‐‐‐24.61‐‐‐74.911/24/2022‐‐‐27.41‐‐‐72.113/2/2022‐‐‐27.03‐‐‐72.492/1/2023 26.57 72.952/2/2023‐‐‐26.60‐‐‐72.922/27/2023‐‐‐26.10‐‐‐73.423/6/2023  (pre‐MMPE)‐‐‐26.10‐‐‐73.423/10/2023  (post‐MMPE)‐‐‐26.15‐‐‐73.373/13/2023  (pre‐MMPE)‐‐‐26.05‐‐‐73.473/17/2023  (pre‐MMPE)‐‐‐26.05‐‐‐73.474/17/2023‐‐‐25.93‐‐‐73.597/14/2020‐‐‐26.34‐‐‐73.481/20/2021‐‐‐25.34‐‐‐74.481/24/2022‐‐‐28.10‐‐‐71.723/2/2022‐‐‐27.82‐‐‐72.002/1/2023 27.33 72.492/2/2023‐‐‐27.35‐‐‐72.472/27/2023‐‐‐26.85‐‐‐72.973/6/2023  (pre‐MMPE)‐‐‐26.85‐‐‐72.973/10/2023  (post‐MMPE)‐‐‐26.86‐‐‐72.963/13/2023  (pre‐MMPE)‐‐‐26.75‐‐‐73.073/17/2023  (pre‐MMPE)‐‐‐26.80‐‐‐73.024/17/2023‐‐‐26.70‐‐‐73.121203275.25 737852.2799.521203216.30 737879.64MW‐37/14/2020 2 30 15 15‐30 99.82MW‐27/14/2020 2 30 15 15‐30Well Coordinates(NC State Plane NAD 83 Feet)MW‐17/14/2020 2 30 15 15‐30 100.001203268.02 737925.29Top‐of‐Casing Elevation     (feet)Date Water Level MeasuredDepth‐to‐LNAPL from Top‐of‐Casing(feet)Depth‐to‐Water from Top‐of‐Casing(feet)LNAPL Thickness(feet)GroundwaterElevation        (feet)Monitoring Well IDDate Installed  Well Casing Diameter(inches)Total Depth     (feet)Well Casing Depth (feet)Screened Interval      (feet)TABLE B‐9CURRENT & HISTORICAL GROUNDWATER ELEVATIONS & LNAPL THICKNESSESFoothills Service CenterIncident # 20326312 East Union StreetMorganton, Burke County, NCPage 1 of 2 Easting NorthingWell Coordinates(NC State Plane NAD 83 Feet)Top‐of‐Casing Elevation     (feet)Date Water Level MeasuredDepth‐to‐LNAPL from Top‐of‐Casing(feet)Depth‐to‐Water from Top‐of‐Casing(feet)LNAPL Thickness(feet)GroundwaterElevation        (feet)Monitoring Well IDDate Installed  Well Casing Diameter(inches)Total Depth     (feet)Well Casing Depth (feet)Screened Interval      (feet)TABLE B‐9CURRENT & HISTORICAL GROUNDWATER ELEVATIONS & LNAPL THICKNESSESFoothills Service CenterIncident # 20326312 East Union StreetMorganton, Burke County, NCMW‐41/30/20232 35.5 15 20.5-35.5NM2/1/2023‐‐‐26.10‐‐‐NM‐‐‐ ‐‐‐MW‐51/30/20232 30.5 15 15.5-30.5NM2/1/2023‐‐‐26.50‐‐‐NM‐‐‐ ‐‐‐MW‐61/30/20232 28.7 15 13.7-28.7NM2/1/2023‐‐‐26.00‐‐‐NM‐‐‐ ‐‐‐2/2/2023‐‐‐27.25‐‐‐72.252/27/2023‐‐‐26.75‐‐‐72.753/6/2023  (pre‐MMPE)‐‐‐26.75‐‐‐72.753/10/2023  (post‐MMPE)‐‐‐28.85‐‐‐70.653/13/2023  (pre‐MMPE)‐‐‐26.70‐‐‐72.803/17/2023  (pre‐MMPE)‐‐‐28.02‐‐‐71.484/17/2023‐‐‐26.59‐‐‐72.912/2/2023‐‐‐26.50‐‐‐72.292/27/2023‐‐‐25.85‐‐‐72.943/6/2023  (pre‐MMPE)‐‐‐25.90‐‐‐72.893/10/2023  (post‐MMPE)‐‐‐26.45‐‐‐72.343/13/2023  (pre‐MMPE)‐‐‐25.70‐‐‐73.093/17/2023  (pre‐MMPE)‐‐‐26.95‐‐‐71.844/17/2023‐‐‐25.71‐‐‐73.083/6/2023  (pre‐MMPE)‐‐‐26.55‐‐‐NM3/10/2023  (post‐MMPE)‐‐‐27.00‐‐‐NM3/13/2023  (pre‐MMPE) 26.40 26.50 0.10 NM3/17/2023  (pre‐MMPE) 28.01‐‐‐NMAS‐12/27/2023 2 40 35 35‐40 NM 3/6/2023‐‐‐26.76‐‐‐NM‐‐‐ ‐‐‐AS‐22/27/2023 2 40 35 35‐40 NM 3/6/2023‐‐‐26.50‐‐‐NM‐‐‐ ‐‐‐AS‐32/27/2023 2 40 35 35‐40 NM 3/6/2023‐‐‐26.00‐‐‐NM‐‐‐ ‐‐‐Notes:3) Groundwater elevation adjusted for LNAPL is [Top of Casing Elevation ‐ Depth to Water] + [LNAPL Thickness * 0.8581]4) NM = Not measured..Not Measured‐‐‐ ‐‐‐1) Well Top of Casing (TOC) elevation based on arbitrary 100.00 ft benchmark established at TOC for MW‐12) LNAPL = Light Non‐Aqueous Phase Liquid.RW‐12/27/2023 4 40 25 25‐40‐‐‐MW‐82/2/2023 2 33 18 18‐33 98.79‐‐‐ ‐‐‐MW‐72/2/2023 2 33 18 18‐33 99.50‐‐‐Page 2 of 2 WithersRavenel Our People. Your Success.      APPENDIX A    REMEDIAL WELL CONSTRUCTION RECORDS     WELL CONSTRUCTION RECORD (GW-1)For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: ƑAgricultural ƑMunicipal/Public ƑGeothermal (Heating/Cooling Supply)ƑResidential Water Supply (single) ƑIndustrial/Commercial ƑResidential Water Supply (shared) ƑIrrigation ƑWells > 100,000 GPD Non-Water Supply Well: ƑMonitoring ƑRecovery Injection Well: ƑAquifer Recharge ƑGroundwater Remediation ƑAquifer Storage and Recovery ƑSalinity Barrier ƑAquifer Test ƑStormwater Drainage ƑExperimental Technology ƑSubsidence Control ƑGeothermal (Closed Loop)ƑTracer ƑGeothermal (Heating/Cooling Return) ƑOther (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): ƑPermanent or ƑTemporary 7. Is this a repair to an existing well: ƑYes or ƑNo If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100ƍ) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. Site diagram or additional well details: You may use the back of this page to provide additional ZHOOFRQVWUXFWLRQLQIR DGG 6HH2YHU LQ5HPDUNV%R[ <RXPD\DOVRDWWDFKDGGLWLRQDOSDJHVLIQHFHVVDU\ SUBMITTAL INSTRUCTIONS Submit this GW-1 within 30 days of well completion per the following: 24a. For All Wells:Original form to Division of Water Resources (DWR), Information Processing Unit, 1617 MSC, Raleigh, NC 27699-1617 24b. For Injection Wells:Copy to DWR, Underground Injection Control (IUC) Program, 1636 MSC, Raleigh, NC 27699-1636 24c. For Water Supply and Open-Loop Geothermal Return Wells: Copy to the county environmental health department of the county where installed 24d. For Water Wells producing over 100,000 GPD: Copy to DWR, CCPCUAPermit Program, 1611 MSC, Raleigh, NC 27699-1611 JACOB MESSICK A - 4252 GEOLOGIC EXPLORATION 0.0 35.0 SCH 40 35.0 40.0 .010 ● 0.0 PORTLAND BENTONITE 33.0 20-40 0.0 BROWN/TAN SILTY CLAY 02/27/23 AS-1 15.0 TAN SILT 30.0 TAN SILTY SAND FOOTHILLS SERVICE CENTER 312 EAST UNION STREET MORGANTON 28655 BURKE BENTONITE SEAL ~ 30.0 - 33.0 FEET 35° 44' 52.16" 81° 41' 07.47"03/24/23 ● 40.0 33.0 8.0 AUGER PVC SCH 40 PVC 2.0 2.0 30.0 40.0 15.0 30.0 40.0 FINE SILICA SAND SLURRY WELL CONSTRUCTION RECORD (GW-1)For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: ƑAgricultural ƑMunicipal/Public ƑGeothermal (Heating/Cooling Supply)ƑResidential Water Supply (single) ƑIndustrial/Commercial ƑResidential Water Supply (shared) ƑIrrigation ƑWells > 100,000 GPD Non-Water Supply Well: ƑMonitoring ƑRecovery Injection Well: ƑAquifer Recharge ƑGroundwater Remediation ƑAquifer Storage and Recovery ƑSalinity Barrier ƑAquifer Test ƑStormwater Drainage ƑExperimental Technology ƑSubsidence Control ƑGeothermal (Closed Loop)ƑTracer ƑGeothermal (Heating/Cooling Return) ƑOther (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): ƑPermanent or ƑTemporary 7. Is this a repair to an existing well: ƑYes or ƑNo If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100ƍ) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. Site diagram or additional well details: You may use the back of this page to provide additional ZHOOFRQVWUXFWLRQLQIR DGG 6HH2YHU LQ5HPDUNV%R[ <RXPD\DOVRDWWDFKDGGLWLRQDOSDJHVLIQHFHVVDU\ SUBMITTAL INSTRUCTIONS Submit this GW-1 within 30 days of well completion per the following: 24a. For All Wells:Original form to Division of Water Resources (DWR), Information Processing Unit, 1617 MSC, Raleigh, NC 27699-1617 24b. For Injection Wells:Copy to DWR, Underground Injection Control (IUC) Program, 1636 MSC, Raleigh, NC 27699-1636 24c. For Water Supply and Open-Loop Geothermal Return Wells: Copy to the county environmental health department of the county where installed 24d. For Water Wells producing over 100,000 GPD: Copy to DWR, CCPCUAPermit Program, 1611 MSC, Raleigh, NC 27699-1611 JACOB MESSICK A - 4252 GEOLOGIC EXPLORATION 0.0 35.0 SCH 40 35.0 40.0 .010 ● 0.0 PORTLAND BENTONITE 33.0 20-40 0.0 BROWN/TAN SILTY CLAY 02/27/23 AS-2 15.0 TAN SILT 30.0 TAN SILTY SAND FOOTHILLS SERVICE CENTER 312 EAST UNION STREET MORGANTON 28655 BURKE BENTONITE SEAL ~ 30.0 - 33.0 FEET 35° 44' 52.16" 81° 41' 07.47"03/24/23 ● 40.0 33.0 8.0 AUGER PVC SCH 40 PVC 2.0 2.0 30.0 40.0 15.0 30.0 40.0 FINE SILICA SAND SLURRY WELL CONSTRUCTION RECORD (GW-1)For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: ƑAgricultural ƑMunicipal/Public ƑGeothermal (Heating/Cooling Supply)ƑResidential Water Supply (single) ƑIndustrial/Commercial ƑResidential Water Supply (shared) ƑIrrigation ƑWells > 100,000 GPD Non-Water Supply Well: ƑMonitoring ƑRecovery Injection Well: ƑAquifer Recharge ƑGroundwater Remediation ƑAquifer Storage and Recovery ƑSalinity Barrier ƑAquifer Test ƑStormwater Drainage ƑExperimental Technology ƑSubsidence Control ƑGeothermal (Closed Loop)ƑTracer ƑGeothermal (Heating/Cooling Return) ƑOther (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): ƑPermanent or ƑTemporary 7. Is this a repair to an existing well: ƑYes or ƑNo If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100ƍ) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. Site diagram or additional well details: You may use the back of this page to provide additional ZHOOFRQVWUXFWLRQLQIR DGG 6HH2YHU LQ5HPDUNV%R[ <RXPD\DOVRDWWDFKDGGLWLRQDOSDJHVLIQHFHVVDU\ SUBMITTAL INSTRUCTIONS Submit this GW-1 within 30 days of well completion per the following: 24a. For All Wells:Original form to Division of Water Resources (DWR), Information Processing Unit, 1617 MSC, Raleigh, NC 27699-1617 24b. For Injection Wells:Copy to DWR, Underground Injection Control (IUC) Program, 1636 MSC, Raleigh, NC 27699-1636 24c. For Water Supply and Open-Loop Geothermal Return Wells: Copy to the county environmental health department of the county where installed 24d. For Water Wells producing over 100,000 GPD: Copy to DWR, CCPCUAPermit Program, 1611 MSC, Raleigh, NC 27699-1611 JACOB MESSICK A - 4252 GEOLOGIC EXPLORATION 0.0 35.0 SCH 40 35.0 40.0 .010 ● 0.0 PORTLAND BENTONITE 33.0 20-40 0.0 BROWN/TAN SILTY CLAY 02/28/23 AS-3 15.0 TAN SILT 30.0 TAN SILTY SAND FOOTHILLS SERVICE CENTER 312 EAST UNION STREET MORGANTON 28655 BURKE BENTONITE SEAL ~ 30.0 - 33.0 FEET 35° 44' 52.16" 81° 41' 07.47"03/24/23 ● 40.0 33.0 8.0 AUGER PVC SCH 40 PVC 2.0 2.0 30.0 40.0 15.0 30.0 40.0 FINE SILICA SAND SLURRY WELL CONSTRUCTION RECORD (GW-1)For Internal Use Only: Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 6-6-2018 1. Well Contractor Information: Well Contractor Name NC Well Contractor Certification Number Company Name 2. Well Construction Permit #: List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.) 3. Well Use (check well use): Water Supply Well: ƑAgricultural ƑMunicipal/Public ƑGeothermal (Heating/Cooling Supply)ƑResidential Water Supply (single) ƑIndustrial/Commercial ƑResidential Water Supply (shared) ƑIrrigation ƑWells > 100,000 GPD Non-Water Supply Well: ƑMonitoring ƑRecovery Injection Well: ƑAquifer Recharge ƑGroundwater Remediation ƑAquifer Storage and Recovery ƑSalinity Barrier ƑAquifer Test ƑStormwater Drainage ƑExperimental Technology ƑSubsidence Control ƑGeothermal (Closed Loop)ƑTracer ƑGeothermal (Heating/Cooling Return) ƑOther (explain under #21 Remarks) 4. Date Well(s) Completed: Well ID# 5a. Well Location: Facility/Owner Name Facility ID# (if applicable) Physical Address, City, and Zip County Parcel Identification No. (PIN) 5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W 6. Is(are) the well(s): ƑPermanent or ƑTemporary 7. Is this a repair to an existing well: ƑYes or ƑNo If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells drilled: 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100ƍ) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount: 14. WATER ZONES FROM TO DESCRIPTION ft.ft. ft.ft. 15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. 16. INNER CASING OR TUBING (geothermal closed-loop) FROM TO DIAMETER THICKNESS MATERIAL ft.ft.in. ft.ft.in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ft.ft.in. ft.ft.in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT ft.ft. ft.ft. ft.ft. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD ft.ft. ft.ft. 20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.) ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. ft.ft. 21. REMARKS 22. Certification: Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. Site diagram or additional well details: You may use the back of this page to provide additional ZHOOFRQVWUXFWLRQLQIR DGG 6HH2YHU LQ5HPDUNV%R[ <RXPD\DOVRDWWDFKDGGLWLRQDOSDJHVLIQHFHVVDU\ SUBMITTAL INSTRUCTIONS Submit this GW-1 within 30 days of well completion per the following: 24a. For All Wells:Original form to Division of Water Resources (DWR), Information Processing Unit, 1617 MSC, Raleigh, NC 27699-1617 24b. For Injection Wells:Copy to DWR, Underground Injection Control (IUC) Program, 1636 MSC, Raleigh, NC 27699-1636 24c. For Water Supply and Open-Loop Geothermal Return Wells: Copy to the county environmental health department of the county where installed 24d. For Water Wells producing over 100,000 GPD: Copy to DWR, CCPCUAPermit Program, 1611 MSC, Raleigh, NC 27699-1611 JACOB MESSICK A - 4252 GEOLOGIC EXPLORATION 0.0 25.0 SCH 40 25.0 40.0 .010 ● 0.0 PORTLAND BENTONITE 23.0 20-40 0.0 BROWN/TAN SILTY CLAY 02/28/23 RW-1 15.0 TAN SILT 30.0 TAN SILTY SAND FOOTHILLS SERVICE CENTER 312 EAST UNION STREET MORGANTON 28655 BURKE BENTONITE SEAL ~ 20.0 - 23.0 FEET 35° 44' 52.16" 81° 41' 07.47"03/24/23 ● 40.0 33.0 8.0 AUGER PVC SCH 40 PVC 4.0 4.0 20.0 40.0 15.0 30.0 40.0 FINE SILICA SAND SLURRY WithersRavenel Our People. Your Success.      APPENDIX B    FIELD NOTES & PHOTOGRAPHIC RECORD     WithersRavenel Our People. Your Success.  Foothills Service Center WR Project # 23‐0307‐B  Photographic Record April 2023    Frame No. 1   Description: View of the site facing southwest.    Frame No. 2   Description: View of site looking west  WithersRavenel Our People. Your Success.  Foothills Service Center WR Project # 23‐0307‐B  Photographic Record April 2023    Frame No. 3   Description: View of site looking northwest.    Frame No. 4   Description: Looking south across site.  WithersRavenel Our People. Your Success.  Foothills Service Center WR Project # 23‐0307‐B  Photographic Record April 2023      Frame No.5   Description: View of MW‐1.    Frame No. 6   Description: View of MW‐2.  WithersRavenel Our People. Your Success.  Foothills Service Center WR Project # 23‐0307‐B  Photographic Record April 2023        Frame No. 7   Description: Location of MW‐3.    Frame No. 8   Description: Location of MW‐7. WithersRavenel Our People. Your Success.  Foothills Service Center WR Project # 23‐0307‐B  Photographic Record April 2023    Frame No. 9   Description: Location of MW‐8.    WithersRavenel Our People. Your Success.      APPENDIX C    LABORATORY ANALYTICAL REPORT       Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.   5/1/2023 Withers & Ravenel Liz Allyn 115 Mackenan Dr. BUILDING 117 Cary, NC, 27511 Ref: Analytical Testing Lab Report Number: 23-111-0102 Client Project Description: Foothills Service Center 23-0307-B Dear Liz Allyn: Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/21/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as- received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Angela D Overcash Senior Project Manager Page 1 of 35 Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date 07/31/202337735State ProgramNorth Carolina 12/31/2023402State ProgramNorth Carolina 07/31/202399012State ProgramSouth Carolina 12/31/202299012State ProgramSouth Carolina Page 1 of 1 00016/23-111-0102 Page 2 of 35 Report Number: Sample Summary Table Client Project Description: 23-111-0102 Foothills Service Center 23-0307-B Lab No Client Sample ID Matrix Date Collected Date Received 04/17/2023 13:20Aqueous 94564 MW-1 04/21/2023 12:15 04/17/2023 13:55Aqueous 94565 MW-2 04/21/2023 12:15 04/17/2023 14:30Aqueous 94566 MW-3 04/21/2023 12:15 04/17/2023 15:05Aqueous 94567 MW-7 04/21/2023 12:15 04/17/2023 15:40Aqueous 94568 MW-8 04/21/2023 12:15 Page 3 of 35 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-111-0102 Report Limit Project:Foothills Service Center V 94564MW-1 19500 04/28/2023 21:346200BBenzeneµg/L 500 69.7 04/27/2023 21:126200Bn-Butylbenzene µg/L 50.0 156 04/27/2023 21:126200BDi-Isopropyl Ether (DIPE)µg/L 50.0 98.9 04/27/2023 21:126200B1,2-Dibromoethane µg/L 50.0 124 04/27/2023 21:126200B1,2-Dichloroethane µg/L 50.0 3020 04/27/2023 21:126200BEthylbenzeneµg/L 50.0 168 04/27/2023 21:126200BIsopropylbenzeneµg/L 50.0 1930 04/27/2023 21:126200BMethyl tert-butyl ether (MTBE)µg/L 100 1350 04/27/2023 21:126200BNaphthaleneµg/L 100 545 04/27/2023 21:126200Bn-Propylbenzene µg/L 50.0 37400 04/28/2023 21:346200BTolueneµg/L 500 4580 04/27/2023 21:126200B1,2,4-Trimethylbenzene µg/L 50.0 1110 04/27/2023 21:126200B1,3,5-Trimethylbenzene µg/L 50.0 5960 04/27/2023 21:126200Bo-Xylene µg/L 50.0 11400 04/27/2023 21:126200Bm,p-Xylene µg/L 100 17400 04/27/2023 21:126200BXylene (Total)µg/L 50.0 V 94565MW-2 59.3 04/27/2023 21:366200BBenzeneµg/L 50.0 65.5 04/27/2023 21:366200Bn-Butylbenzene µg/L 50.0 1270 04/27/2023 21:366200BEthylbenzeneµg/L 50.0 145 04/27/2023 21:366200BIsopropylbenzeneµg/L 50.0 810 04/27/2023 21:366200BNaphthaleneµg/L 100 396 04/27/2023 21:366200Bn-Propylbenzene µg/L 50.0 101 04/27/2023 21:366200BTolueneµg/L 50.0 3840 04/27/2023 21:366200B1,2,4-Trimethylbenzene µg/L 50.0 1100 04/27/2023 21:366200B1,3,5-Trimethylbenzene µg/L 50.0 2140 04/27/2023 21:366200Bo-Xylene µg/L 50.0 6290 04/27/2023 21:366200Bm,p-Xylene µg/L 100 8430 04/27/2023 21:366200BXylene (Total)µg/L 50.0 V 94567MW-7 23700 04/28/2023 21:586200BBenzeneµg/L 500 309 04/27/2023 22:016200BDi-Isopropyl Ether (DIPE)µg/L 50.0 117 04/27/2023 22:016200B1,2-Dibromoethane µg/L 50.0 260 04/27/2023 22:016200B1,2-Dichloroethane µg/L 50.0 2950 04/27/2023 22:016200BEthylbenzeneµg/L 50.0 149 04/27/2023 22:016200B2-Hexanone µg/L 100 Page 4 of 35 Summary of Detected Analytes QualifiersAnalyzedUnitsResult Report Number: Client Sample ID Method Parameters Lab Sample ID 23-111-0102 Report Limit Project:Foothills Service Center V 94567MW-7 153 04/27/2023 22:016200BIsopropylbenzeneµg/L 50.0 15800 04/28/2023 21:586200BMethyl tert-butyl ether (MTBE)µg/L 1000 432 04/27/2023 22:016200Bn-Propylbenzene µg/L 50.0 40600 04/28/2023 21:586200BTolueneµg/L 500 3170 04/27/2023 22:016200B1,2,4-Trimethylbenzene µg/L 50.0 780 04/27/2023 22:016200B1,3,5-Trimethylbenzene µg/L 50.0 5550 04/27/2023 22:016200Bo-Xylene µg/L 50.0 11000 04/27/2023 22:016200Bm,p-Xylene µg/L 100 16600 04/27/2023 22:016200BXylene (Total)µg/L 50.0 V 94568MW-8 9190 04/27/2023 22:256200BBenzeneµg/L 50.0 60.7 04/27/2023 22:256200BDi-Isopropyl Ether (DIPE)µg/L 50.0 65.4 04/27/2023 22:256200B1,2-Dichloroethane µg/L 50.0 2940 04/27/2023 22:256200BEthylbenzeneµg/L 50.0 146 04/27/2023 22:256200B2-Hexanone µg/L 100 181 04/27/2023 22:256200BIsopropylbenzeneµg/L 50.0 1640 04/27/2023 22:256200BMethyl tert-butyl ether (MTBE)µg/L 100 1090 04/27/2023 22:256200BNaphthaleneµg/L 100 514 04/27/2023 22:256200Bn-Propylbenzene µg/L 50.0 29900 04/28/2023 22:236200BTolueneµg/L 500 3660 04/27/2023 22:256200B1,2,4-Trimethylbenzene µg/L 50.0 933 04/27/2023 22:256200B1,3,5-Trimethylbenzene µg/L 50.0 5740 04/27/2023 22:256200Bo-Xylene µg/L 50.0 11100 04/27/2023 22:256200Bm,p-Xylene µg/L 100 16800 04/27/2023 22:256200BXylene (Total)µg/L 50.0 Page 5 of 35   Client: Withers & Ravenel CASE NARRATIVE Project: Foothills Service Center Lab Report Number: 23-111-0102 Date: 5/1/2023 Volatile Organic Compounds - GC/MS Method 6200B Analyte: Methylene chloride QC Batch No: V32624/V32546 LCSD failed low for this compound. LCS and all other QC passed within method parameters. A standard at or below the RL was run and saw recovery. No hits in samples. No further action taken. Page 6 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-1 94564 Matrix: 4/17/2023 13:20 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1000 µg/L 1000Acetone 100 04/27/23 21:12 6200BMSA 19500 µg/L 500Benzene 1000 04/28/23 21:34 6200BMSA <50.0 µg/L 50.0Bromobenzene 100 04/27/23 21:12 6200BMSA <100 µg/L 100Bromochloromethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Bromodichloromethane 100 04/27/23 21:12 6200BMSA <500 µg/L 500Bromoform 100 04/27/23 21:12 6200BMSA <100 µg/L 100Bromomethane 100 04/27/23 21:12 6200BMSA 69.7 µg/L 50.0n-Butylbenzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0sec-Butyl benzene 100 04/27/23 21:12 6200BMSA <200 µg/L 200tert-Butyl benzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Carbon Tetrachloride 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Chlorobenzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Chlorodibromomethane 100 04/27/23 21:12 6200BMSA <100 µg/L 100Chloroethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Chloroform 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Chloromethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.02-Chlorotoluene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.04-Chlorotoluene 100 04/27/23 21:12 6200BMSA <200 µg/L 2001,2-Dibromo-3-Chloropropane 100 04/27/23 21:12 6200BMSA 98.9 µg/L 50.01,2-Dibromoethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Dibromomethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,2-Dichlorobenzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,3-Dichlorobenzene 100 04/27/23 21:12 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 7 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-1 94564 Matrix: 4/17/2023 13:20 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <50.0 µg/L 50.01,4-Dichlorobenzene 100 04/27/23 21:12 6200BMSA <500 µg/L 500Dichlorodifluoromethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,1-Dichloroethane 100 04/27/23 21:12 6200BMSA 124 µg/L 50.01,2-Dichloroethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,1-Dichloroethene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0cis-1,2-Dichloroethene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0trans-1,2-Dichloroethene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,2-Dichloropropane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,3-Dichloropropane 100 04/27/23 21:12 6200BMSA <200 µg/L 2002,2-Dichloropropane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,1-Dichloropropene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0cis-1,3-Dichloropropene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0trans-1,3-Dichloropropene 100 04/27/23 21:12 6200BMSA <20000 µg/L 20000Ethanol 100 04/27/23 21:12 6200BMSA 3020 µg/L 50.0Ethylbenzene 100 04/27/23 21:12 6200BMSA <300 µg/L 300Hexachlorobutadiene 100 04/27/23 21:12 6200BMSA 156 µg/L 50.0Di-Isopropyl Ether (DIPE)100 04/27/23 21:12 6200BMSA 168 µg/L 50.0Isopropylbenzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.04-Isopropyl toluene 100 04/27/23 21:12 6200BMSA <100 µg/L 1002-Hexanone 100 04/27/23 21:12 6200BMSA <500 µg/L 500Methyl Ethyl Ketone (MEK)100 04/27/23 21:12 6200BMSA <200 µg/L 200Methylene Chloride 100 04/27/23 21:12 6200BMSA 1930 µg/L 100Methyl tert-butyl ether (MTBE)100 04/27/23 21:12 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 8 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-1 94564 Matrix: 4/17/2023 13:20 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <100 µg/L 1004-Methyl-2-Pentanone 100 04/27/23 21:12 6200BMSA 1350 µg/L 100Naphthalene 100 04/27/23 21:12 6200BMSA 545 µg/L 50.0n-Propylbenzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Styrene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Tetrachloroethene 100 04/27/23 21:12 6200BMSA 37400 µg/L 500Toluene 1000 04/28/23 21:34 6200BMSA <50.0 µg/L 50.01,2,3-Trichlorobenzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,2,4-Trichlorobenzene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,1,1-Trichloroethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,1,2-Trichloroethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Trichloroethene 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Trichlorofluoromethane 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.01,2,3-Trichloropropane 100 04/27/23 21:12 6200BMSA 4580 µg/L 50.01,2,4-Trimethylbenzene 100 04/27/23 21:12 6200BMSA 1110 µg/L 50.01,3,5-Trimethylbenzene 100 04/27/23 21:12 6200BMSA <500 µg/L 500Vinyl Acetate 100 04/27/23 21:12 6200BMSA <50.0 µg/L 50.0Vinyl Chloride 100 04/27/23 21:12 6200BMSA 11400 µg/L 100m,p-Xylene 100 04/27/23 21:12 6200BMSA 5960 µg/L 50.0o-Xylene 100 04/27/23 21:12 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 9 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-1 94564 Matrix: 4/17/2023 13:20 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF 17400 µg/L 50.0Xylene (Total)100 04/27/23 21:12 6200B Surrogate: 4-Bromofluorobenzene 99.0 Limits: 70-130%04/27/23 21:12100 MSA V32548 Surrogate: Dibromofluoromethane 94.2 Limits: 70-130%04/27/23 21:12100 MSA V32548 Surrogate: 1,2-Dichloroethane - d4 93.0 Limits: 70-130%04/27/23 21:12100 MSA V32548 Surrogate: Toluene-d8 101 Limits: 70-130%04/27/23 21:12100 MSA V32548 Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%04/28/23 21:341000 MSA V32624 Surrogate: Dibromofluoromethane 91.0 Limits: 70-130%04/28/23 21:341000 MSA V32624 Surrogate: 1,2-Dichloroethane - d4 93.0 Limits: 70-130%04/28/23 21:341000 MSA V32624 Surrogate: Toluene-d8 101 Limits: 70-130%04/28/23 21:341000 MSA V32624 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 10 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-2 94565 Matrix: 4/17/2023 13:55 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1000 µg/L 1000Acetone 100 04/27/23 21:36 6200BMSA 59.3 µg/L 50.0Benzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Bromobenzene 100 04/27/23 21:36 6200BMSA <100 µg/L 100Bromochloromethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Bromodichloromethane 100 04/27/23 21:36 6200BMSA <500 µg/L 500Bromoform 100 04/27/23 21:36 6200BMSA <100 µg/L 100Bromomethane 100 04/27/23 21:36 6200BMSA 65.5 µg/L 50.0n-Butylbenzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0sec-Butyl benzene 100 04/27/23 21:36 6200BMSA <200 µg/L 200tert-Butyl benzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Carbon Tetrachloride 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Chlorobenzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Chlorodibromomethane 100 04/27/23 21:36 6200BMSA <100 µg/L 100Chloroethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Chloroform 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Chloromethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.02-Chlorotoluene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.04-Chlorotoluene 100 04/27/23 21:36 6200BMSA <200 µg/L 2001,2-Dibromo-3-Chloropropane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,2-Dibromoethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Dibromomethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,2-Dichlorobenzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,3-Dichlorobenzene 100 04/27/23 21:36 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 11 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-2 94565 Matrix: 4/17/2023 13:55 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <50.0 µg/L 50.01,4-Dichlorobenzene 100 04/27/23 21:36 6200BMSA <500 µg/L 500Dichlorodifluoromethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,1-Dichloroethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,2-Dichloroethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,1-Dichloroethene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0cis-1,2-Dichloroethene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0trans-1,2-Dichloroethene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,2-Dichloropropane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,3-Dichloropropane 100 04/27/23 21:36 6200BMSA <200 µg/L 2002,2-Dichloropropane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,1-Dichloropropene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0cis-1,3-Dichloropropene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0trans-1,3-Dichloropropene 100 04/27/23 21:36 6200BMSA <20000 µg/L 20000Ethanol 100 04/27/23 21:36 6200BMSA 1270 µg/L 50.0Ethylbenzene 100 04/27/23 21:36 6200BMSA <300 µg/L 300Hexachlorobutadiene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Di-Isopropyl Ether (DIPE)100 04/27/23 21:36 6200BMSA 145 µg/L 50.0Isopropylbenzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.04-Isopropyl toluene 100 04/27/23 21:36 6200BMSA <100 µg/L 1002-Hexanone 100 04/27/23 21:36 6200BMSA <500 µg/L 500Methyl Ethyl Ketone (MEK)100 04/27/23 21:36 6200BMSA <200 µg/L 200Methylene Chloride 100 04/27/23 21:36 6200BMSA <100 µg/L 100Methyl tert-butyl ether (MTBE)100 04/27/23 21:36 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 12 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-2 94565 Matrix: 4/17/2023 13:55 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <100 µg/L 1004-Methyl-2-Pentanone 100 04/27/23 21:36 6200BMSA 810 µg/L 100Naphthalene 100 04/27/23 21:36 6200BMSA 396 µg/L 50.0n-Propylbenzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Styrene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Tetrachloroethene 100 04/27/23 21:36 6200BMSA 101 µg/L 50.0Toluene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,2,3-Trichlorobenzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,2,4-Trichlorobenzene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,1,1-Trichloroethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,1,2-Trichloroethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Trichloroethene 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Trichlorofluoromethane 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.01,2,3-Trichloropropane 100 04/27/23 21:36 6200BMSA 3840 µg/L 50.01,2,4-Trimethylbenzene 100 04/27/23 21:36 6200BMSA 1100 µg/L 50.01,3,5-Trimethylbenzene 100 04/27/23 21:36 6200BMSA <500 µg/L 500Vinyl Acetate 100 04/27/23 21:36 6200BMSA <50.0 µg/L 50.0Vinyl Chloride 100 04/27/23 21:36 6200BMSA 6290 µg/L 100m,p-Xylene 100 04/27/23 21:36 6200BMSA 2140 µg/L 50.0o-Xylene 100 04/27/23 21:36 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 13 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-2 94565 Matrix: 4/17/2023 13:55 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF 8430 µg/L 50.0Xylene (Total)100 04/27/23 21:36 6200B Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%04/27/23 21:36100 MSA V32548 Surrogate: Dibromofluoromethane 94.8 Limits: 70-130%04/27/23 21:36100 MSA V32548 Surrogate: 1,2-Dichloroethane - d4 94.6 Limits: 70-130%04/27/23 21:36100 MSA V32548 Surrogate: Toluene-d8 101 Limits: 70-130%04/27/23 21:36100 MSA V32548 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 14 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-3 94566 Matrix: 4/17/2023 14:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <10.0 µg/L 10.0Acetone 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Benzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Bromobenzene 1 04/27/23 17:09 6200BMSA <1.00 µg/L 1.00Bromochloromethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Bromodichloromethane 1 04/27/23 17:09 6200BMSA <5.00 µg/L 5.00Bromoform 1 04/27/23 17:09 6200BMSA <1.00 µg/L 1.00Bromomethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500n-Butylbenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500sec-Butyl benzene 1 04/27/23 17:09 6200BMSA <2.00 µg/L 2.00tert-Butyl benzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Carbon Tetrachloride 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Chlorobenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Chlorodibromomethane 1 04/27/23 17:09 6200BMSA <1.00 µg/L 1.00Chloroethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Chloroform 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Chloromethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5002-Chlorotoluene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5004-Chlorotoluene 1 04/27/23 17:09 6200BMSA <2.00 µg/L 2.001,2-Dibromo-3-Chloropropane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2-Dibromoethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Dibromomethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2-Dichlorobenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,3-Dichlorobenzene 1 04/27/23 17:09 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 15 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-3 94566 Matrix: 4/17/2023 14:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.5001,4-Dichlorobenzene 1 04/27/23 17:09 6200BMSA <5.00 µg/L 5.00Dichlorodifluoromethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,1-Dichloroethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2-Dichloroethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,1-Dichloroethene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500cis-1,2-Dichloroethene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500trans-1,2-Dichloroethene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2-Dichloropropane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,3-Dichloropropane 1 04/27/23 17:09 6200BMSA <2.00 µg/L 2.002,2-Dichloropropane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,1-Dichloropropene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500cis-1,3-Dichloropropene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500trans-1,3-Dichloropropene 1 04/27/23 17:09 6200BMSA <200 µg/L 200Ethanol 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Ethylbenzene 1 04/27/23 17:09 6200BMSA <3.00 µg/L 3.00Hexachlorobutadiene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Di-Isopropyl Ether (DIPE)1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Isopropylbenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5004-Isopropyl toluene 1 04/27/23 17:09 6200BMSA <1.00 µg/L 1.002-Hexanone 1 04/27/23 17:09 6200BMSA <5.00 µg/L 5.00Methyl Ethyl Ketone (MEK)1 04/27/23 17:09 6200BMSA <2.00 µg/L 2.00Methylene Chloride 1 04/27/23 17:09 6200BMSA <1.00 µg/L 1.00Methyl tert-butyl ether (MTBE)1 04/27/23 17:09 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 16 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-3 94566 Matrix: 4/17/2023 14:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1.00 µg/L 1.004-Methyl-2-Pentanone 1 04/27/23 17:09 6200BMSA <1.00 µg/L 1.00Naphthalene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500n-Propylbenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Styrene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,1,1,2-Tetrachloroethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,1,2,2-Tetrachloroethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Tetrachloroethene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Toluene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2,3-Trichlorobenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2,4-Trichlorobenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,1,1-Trichloroethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,1,2-Trichloroethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Trichloroethene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Trichlorofluoromethane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2,3-Trichloropropane 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,2,4-Trimethylbenzene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.5001,3,5-Trimethylbenzene 1 04/27/23 17:09 6200BMSA <5.00 µg/L 5.00Vinyl Acetate 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500Vinyl Chloride 1 04/27/23 17:09 6200BMSA <1.00 µg/L 1.00m,p-Xylene 1 04/27/23 17:09 6200BMSA <0.500 µg/L 0.500o-Xylene 1 04/27/23 17:09 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 17 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-3 94566 Matrix: 4/17/2023 14:30 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <0.500 µg/L 0.500Xylene (Total)1 04/27/23 17:09 6200B Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%04/27/23 17:091 MSA V32548 Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%04/27/23 17:091 MSA V32548 Surrogate: 1,2-Dichloroethane - d4 99.4 Limits: 70-130%04/27/23 17:091 MSA V32548 Surrogate: Toluene-d8 100 Limits: 70-130%04/27/23 17:091 MSA V32548 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 18 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-7 94567 Matrix: 4/17/2023 15:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1000 µg/L 1000Acetone 100 04/27/23 22:01 6200BMSA 23700 µg/L 500Benzene 1000 04/28/23 21:58 6200BMSA <50.0 µg/L 50.0Bromobenzene 100 04/27/23 22:01 6200BMSA <100 µg/L 100Bromochloromethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Bromodichloromethane 100 04/27/23 22:01 6200BMSA <500 µg/L 500Bromoform 100 04/27/23 22:01 6200BMSA <100 µg/L 100Bromomethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0n-Butylbenzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0sec-Butyl benzene 100 04/27/23 22:01 6200BMSA <200 µg/L 200tert-Butyl benzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Carbon Tetrachloride 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Chlorobenzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Chlorodibromomethane 100 04/27/23 22:01 6200BMSA <100 µg/L 100Chloroethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Chloroform 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Chloromethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.02-Chlorotoluene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.04-Chlorotoluene 100 04/27/23 22:01 6200BMSA <200 µg/L 2001,2-Dibromo-3-Chloropropane 100 04/27/23 22:01 6200BMSA 117 µg/L 50.01,2-Dibromoethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Dibromomethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,2-Dichlorobenzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,3-Dichlorobenzene 100 04/27/23 22:01 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 19 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-7 94567 Matrix: 4/17/2023 15:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <50.0 µg/L 50.01,4-Dichlorobenzene 100 04/27/23 22:01 6200BMSA <500 µg/L 500Dichlorodifluoromethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,1-Dichloroethane 100 04/27/23 22:01 6200BMSA 260 µg/L 50.01,2-Dichloroethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,1-Dichloroethene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0cis-1,2-Dichloroethene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0trans-1,2-Dichloroethene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,2-Dichloropropane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,3-Dichloropropane 100 04/27/23 22:01 6200BMSA <200 µg/L 2002,2-Dichloropropane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,1-Dichloropropene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0cis-1,3-Dichloropropene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0trans-1,3-Dichloropropene 100 04/27/23 22:01 6200BMSA <20000 µg/L 20000Ethanol 100 04/27/23 22:01 6200BMSA 2950 µg/L 50.0Ethylbenzene 100 04/27/23 22:01 6200BMSA <300 µg/L 300Hexachlorobutadiene 100 04/27/23 22:01 6200BMSA 309 µg/L 50.0Di-Isopropyl Ether (DIPE)100 04/27/23 22:01 6200BMSA 153 µg/L 50.0Isopropylbenzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.04-Isopropyl toluene 100 04/27/23 22:01 6200BMSA 149 µg/L 1002-Hexanone 100 04/27/23 22:01 6200BMSA <500 µg/L 500Methyl Ethyl Ketone (MEK)100 04/27/23 22:01 6200BMSA <200 µg/L 200Methylene Chloride 100 04/27/23 22:01 6200BMSA 15800 µg/L 1000Methyl tert-butyl ether (MTBE)1000 04/28/23 21:58 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 20 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-7 94567 Matrix: 4/17/2023 15:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <100 µg/L 1004-Methyl-2-Pentanone 100 04/27/23 22:01 6200BMSA <100 µg/L 100Naphthalene 100 04/27/23 22:01 6200BMSA 432 µg/L 50.0n-Propylbenzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Styrene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Tetrachloroethene 100 04/27/23 22:01 6200BMSA 40600 µg/L 500Toluene 1000 04/28/23 21:58 6200BMSA <50.0 µg/L 50.01,2,3-Trichlorobenzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,2,4-Trichlorobenzene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,1,1-Trichloroethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,1,2-Trichloroethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Trichloroethene 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Trichlorofluoromethane 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.01,2,3-Trichloropropane 100 04/27/23 22:01 6200BMSA 3170 µg/L 50.01,2,4-Trimethylbenzene 100 04/27/23 22:01 6200BMSA 780 µg/L 50.01,3,5-Trimethylbenzene 100 04/27/23 22:01 6200BMSA <500 µg/L 500Vinyl Acetate 100 04/27/23 22:01 6200BMSA <50.0 µg/L 50.0Vinyl Chloride 100 04/27/23 22:01 6200BMSA 11000 µg/L 100m,p-Xylene 100 04/27/23 22:01 6200BMSA 5550 µg/L 50.0o-Xylene 100 04/27/23 22:01 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 21 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-7 94567 Matrix: 4/17/2023 15:05 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF 16600 µg/L 50.0Xylene (Total)100 04/27/23 22:01 6200B Surrogate: 4-Bromofluorobenzene 98.4 Limits: 70-130%04/27/23 22:01100 MSA V32548 Surrogate: Dibromofluoromethane 93.8 Limits: 70-130%04/27/23 22:01100 MSA V32548 Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%04/27/23 22:01100 MSA V32548 Surrogate: Toluene-d8 102 Limits: 70-130%04/27/23 22:01100 MSA V32548 Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%04/28/23 21:581000 MSA V32624 Surrogate: Dibromofluoromethane 91.4 Limits: 70-130%04/28/23 21:581000 MSA V32624 Surrogate: 1,2-Dichloroethane - d4 90.6 Limits: 70-130%04/28/23 21:581000 MSA V32624 Surrogate: Toluene-d8 101 Limits: 70-130%04/28/23 21:581000 MSA V32624 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 22 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-8 94568 Matrix: 4/17/2023 15:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <1000 µg/L 1000Acetone 100 04/27/23 22:25 6200BMSA 9190 µg/L 50.0Benzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Bromobenzene 100 04/27/23 22:25 6200BMSA <100 µg/L 100Bromochloromethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Bromodichloromethane 100 04/27/23 22:25 6200BMSA <500 µg/L 500Bromoform 100 04/27/23 22:25 6200BMSA <100 µg/L 100Bromomethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0n-Butylbenzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0sec-Butyl benzene 100 04/27/23 22:25 6200BMSA <200 µg/L 200tert-Butyl benzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Carbon Tetrachloride 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Chlorobenzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Chlorodibromomethane 100 04/27/23 22:25 6200BMSA <100 µg/L 100Chloroethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Chloroform 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Chloromethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.02-Chlorotoluene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.04-Chlorotoluene 100 04/27/23 22:25 6200BMSA <200 µg/L 2001,2-Dibromo-3-Chloropropane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,2-Dibromoethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Dibromomethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,2-Dichlorobenzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,3-Dichlorobenzene 100 04/27/23 22:25 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 23 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-8 94568 Matrix: 4/17/2023 15:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <50.0 µg/L 50.01,4-Dichlorobenzene 100 04/27/23 22:25 6200BMSA <500 µg/L 500Dichlorodifluoromethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,1-Dichloroethane 100 04/27/23 22:25 6200BMSA 65.4 µg/L 50.01,2-Dichloroethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,1-Dichloroethene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0cis-1,2-Dichloroethene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0trans-1,2-Dichloroethene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,2-Dichloropropane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,3-Dichloropropane 100 04/27/23 22:25 6200BMSA <200 µg/L 2002,2-Dichloropropane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,1-Dichloropropene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0cis-1,3-Dichloropropene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0trans-1,3-Dichloropropene 100 04/27/23 22:25 6200BMSA <20000 µg/L 20000Ethanol 100 04/27/23 22:25 6200BMSA 2940 µg/L 50.0Ethylbenzene 100 04/27/23 22:25 6200BMSA <300 µg/L 300Hexachlorobutadiene 100 04/27/23 22:25 6200BMSA 60.7 µg/L 50.0Di-Isopropyl Ether (DIPE)100 04/27/23 22:25 6200BMSA 181 µg/L 50.0Isopropylbenzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.04-Isopropyl toluene 100 04/27/23 22:25 6200BMSA 146 µg/L 1002-Hexanone 100 04/27/23 22:25 6200BMSA <500 µg/L 500Methyl Ethyl Ketone (MEK)100 04/27/23 22:25 6200BMSA <200 µg/L 200Methylene Chloride 100 04/27/23 22:25 6200BMSA 1640 µg/L 100Methyl tert-butyl ether (MTBE)100 04/27/23 22:25 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 24 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-8 94568 Matrix: 4/17/2023 15:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF <100 µg/L 1004-Methyl-2-Pentanone 100 04/27/23 22:25 6200BMSA 1090 µg/L 100Naphthalene 100 04/27/23 22:25 6200BMSA 514 µg/L 50.0n-Propylbenzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Styrene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,1,1,2-Tetrachloroethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,1,2,2-Tetrachloroethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Tetrachloroethene 100 04/27/23 22:25 6200BMSA 29900 µg/L 500Toluene 1000 04/28/23 22:23 6200BMSA <50.0 µg/L 50.01,2,3-Trichlorobenzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,2,4-Trichlorobenzene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,1,1-Trichloroethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,1,2-Trichloroethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Trichloroethene 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Trichlorofluoromethane 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.01,2,3-Trichloropropane 100 04/27/23 22:25 6200BMSA 3660 µg/L 50.01,2,4-Trimethylbenzene 100 04/27/23 22:25 6200BMSA 933 µg/L 50.01,3,5-Trimethylbenzene 100 04/27/23 22:25 6200BMSA <500 µg/L 500Vinyl Acetate 100 04/27/23 22:25 6200BMSA <50.0 µg/L 50.0Vinyl Chloride 100 04/27/23 22:25 6200BMSA 11100 µg/L 100m,p-Xylene 100 04/27/23 22:25 6200BMSA 5740 µg/L 50.0o-Xylene 100 04/27/23 22:25 6200BMSA Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 25 of 35 , REPORT OF ANALYSISReport Number : Project Information : NC 27511 23-111-0102 01221 Withers & Ravenel 115 Mackenan Dr. BUILDING 117 Liz Allyn Cary 23-0307-B Received : 04/21/2023 Foothills Service Center Report Date : 05/01/2023 Sample ID : Lab No : Sampled:MW-8 94568 Matrix: 4/17/2023 15:40 Aqueous Test Results Units MQL By Analytical Method Date / Time Analyzed DF 16800 µg/L 50.0Xylene (Total)100 04/27/23 22:25 6200B Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%04/27/23 22:25100 MSA V32548 Surrogate: Dibromofluoromethane 97.0 Limits: 70-130%04/27/23 22:25100 MSA V32548 Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%04/27/23 22:25100 MSA V32548 Surrogate: Toluene-d8 100 Limits: 70-130%04/27/23 22:25100 MSA V32548 Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%04/28/23 22:231000 MSA V32624 Surrogate: Dibromofluoromethane 93.2 Limits: 70-130%04/28/23 22:231000 MSA V32624 Surrogate: 1,2-Dichloroethane - d4 91.4 Limits: 70-130%04/28/23 22:231000 MSA V32624 Surrogate: Toluene-d8 101 Limits: 70-130%04/28/23 22:231000 MSA V32624 Qualifiers/ Definitions Method Quantitation LimitMQLDilution FactorDF Page 26 of 35 Quality Control Data 23-111-0102Report No: Project Description: Client ID:Withers & Ravenel Foothills Service Center QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V32548QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V32546 Associated Lab Samples: 94564, 94565, 94566, 94567, 94568 LRB-V32546 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 04/27/23 15:3210.0< 10.0µg/LAcetone 04/27/23 15:320.500< 0.500µg/LBenzene 04/27/23 15:320.500< 0.500µg/LBromobenzene 04/27/23 15:321.00< 1.00µg/LBromochloromethane 04/27/23 15:320.500< 0.500µg/LBromodichloromethane 04/27/23 15:325.00< 5.00µg/LBromoform 04/27/23 15:321.00< 1.00µg/LBromomethane 04/27/23 15:320.500< 0.500µg/Ln-Butylbenzene 04/27/23 15:320.500< 0.500µg/Lsec-Butyl benzene 04/27/23 15:322.00< 2.00µg/Ltert-Butyl benzene 04/27/23 15:320.500< 0.500µg/LCarbon Tetrachloride 04/27/23 15:320.500< 0.500µg/LChlorobenzene 04/27/23 15:320.500< 0.500µg/LChlorodibromomethane 04/27/23 15:321.00< 1.00µg/LChloroethane 04/27/23 15:320.500< 0.500µg/LChloroform 04/27/23 15:320.500< 0.500µg/LChloromethane 04/27/23 15:320.500< 0.500µg/L2-Chlorotoluene 04/27/23 15:320.500< 0.500µg/L4-Chlorotoluene 04/27/23 15:322.00< 2.00µg/L1,2-Dibromo-3-Chloropropane 04/27/23 15:320.500< 0.500µg/L1,2-Dibromoethane 04/27/23 15:320.500< 0.500µg/LDibromomethane 04/27/23 15:320.500< 0.500µg/L1,2-Dichlorobenzene 04/27/23 15:320.500< 0.500µg/L1,3-Dichlorobenzene 04/27/23 15:320.500< 0.500µg/L1,4-Dichlorobenzene 04/27/23 15:325.00< 5.00µg/LDichlorodifluoromethane 04/27/23 15:320.500< 0.500µg/L1,1-Dichloroethane 04/27/23 15:320.500< 0.500µg/L1,2-Dichloroethane Page 1 of 7Date:05/01/2023 04:27 PM Page 27 of 35 Quality Control Data 23-111-0102Report No: Project Description: Client ID:Withers & Ravenel Foothills Service Center QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V32548QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V32546 Associated Lab Samples: 94564, 94565, 94566, 94567, 94568 LRB-V32546 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 04/27/23 15:320.500< 0.500µg/L1,1-Dichloroethene 04/27/23 15:320.500< 0.500µg/Lcis-1,2-Dichloroethene 04/27/23 15:320.500< 0.500µg/Ltrans-1,2-Dichloroethene 04/27/23 15:320.500< 0.500µg/L1,2-Dichloropropane 04/27/23 15:320.500< 0.500µg/L1,3-Dichloropropane 04/27/23 15:322.00< 2.00µg/L2,2-Dichloropropane 04/27/23 15:320.500< 0.500µg/L1,1-Dichloropropene 04/27/23 15:320.500< 0.500µg/Lcis-1,3-Dichloropropene 04/27/23 15:320.500< 0.500µg/Ltrans-1,3-Dichloropropene 04/27/23 15:32200< 200µg/LEthanol 04/27/23 15:320.500< 0.500µg/LEthylbenzene 04/27/23 15:323.00< 3.00µg/LHexachlorobutadiene 04/27/23 15:320.500< 0.500µg/LDi-Isopropyl Ether (DIPE) 04/27/23 15:320.500< 0.500µg/LIsopropylbenzene 04/27/23 15:320.500< 0.500µg/L4-Isopropyl toluene 04/27/23 15:321.00< 1.00µg/L2-Hexanone 04/27/23 15:325.00< 5.00µg/LMethyl Ethyl Ketone (MEK) 04/27/23 15:322.00< 2.00µg/LMethylene Chloride 04/27/23 15:321.00< 1.00µg/LMethyl tert-butyl ether (MTBE) 04/27/23 15:321.00< 1.00µg/L4-Methyl-2-Pentanone 04/27/23 15:321.00< 1.00µg/LNaphthalene 04/27/23 15:320.500< 0.500µg/Ln-Propylbenzene 04/27/23 15:320.500< 0.500µg/LStyrene 04/27/23 15:320.500< 0.500µg/L1,1,1,2-Tetrachloroethane 04/27/23 15:320.500< 0.500µg/L1,1,2,2-Tetrachloroethane 04/27/23 15:320.500< 0.500µg/LTetrachloroethene 04/27/23 15:320.500< 0.500µg/LToluene Page 2 of 7Date:05/01/2023 04:27 PM Page 28 of 35 Quality Control Data 23-111-0102Report No: Project Description: Client ID:Withers & Ravenel Foothills Service Center QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V32548QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V32546 Associated Lab Samples: 94564, 94565, 94566, 94567, 94568 LRB-V32546 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 04/27/23 15:320.500< 0.500µg/L1,2,3-Trichlorobenzene 04/27/23 15:320.500< 0.500µg/L1,2,4-Trichlorobenzene 04/27/23 15:320.500< 0.500µg/L1,1,1-Trichloroethane 04/27/23 15:320.500< 0.500µg/L1,1,2-Trichloroethane 04/27/23 15:320.500< 0.500µg/LTrichloroethene 04/27/23 15:320.500< 0.500µg/LTrichlorofluoromethane 04/27/23 15:320.500< 0.500µg/L1,2,3-Trichloropropane 04/27/23 15:320.500< 0.500µg/L1,2,4-Trimethylbenzene 04/27/23 15:320.500< 0.500µg/L1,3,5-Trimethylbenzene 04/27/23 15:325.00< 5.00µg/LVinyl Acetate 04/27/23 15:320.500< 0.500µg/LVinyl Chloride 04/27/23 15:321.00< 1.00µg/Lm,p-Xylene 04/27/23 15:320.500< 0.500µg/Lo-Xylene 04/27/23 15:324-Bromofluorobenzene (S)98.2 70-130 04/27/23 15:32Dibromofluoromethane (S)97.2 70-130 04/27/23 15:321,2-Dichloroethane - d4 (S)96.4 70-130 04/27/23 15:32Toluene-d8 (S)102 70-130 LCS-V32546 LCSD-V32546Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 26.3 65.760.524.240.0µg/LAcetone 40-160 8.3 20.0 18.5 92.592.518.520.0µg/LBenzene 70-130 0.0 20.0 19.6 98.097.519.520.0µg/LBromobenzene 70-130 0.5 20.0 18.7 93.593.518.720.0µg/LBromochloromethane 70-130 0.0 20.0 18.3 91.594.518.920.0µg/LBromodichloromethane 70-130 3.2 20.0 Page 3 of 7Date:05/01/2023 04:27 PM Page 29 of 35 Quality Control Data 23-111-0102Report No: Project Description: Client ID:Withers & Ravenel Foothills Service Center QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V32548QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V32546 LCS-V32546 LCSD-V32546Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 19.7 98.595.519.120.0µg/LBromoform 70-130 3.0 20.0 18.1 90.593.018.620.0µg/LBromomethane 60-140 2.7 20.0 19.6 98.097.519.520.0µg/Ln-Butylbenzene 70-130 0.5 20.0 19.1 95.595.519.120.0µg/Lsec-Butyl benzene 70-130 0.0 20.0 19.0 95.094.518.920.0µg/Ltert-Butyl benzene 70-130 0.5 20.0 17.8 89.090.018.020.0µg/LCarbon Tetrachloride 70-130 1.1 20.0 18.6 93.094.018.820.0µg/LChlorobenzene 70-130 1.0 20.0 19.8 99.096.019.220.0µg/LChlorodibromomethane 70-130 3.0 20.0 22.3 11211022.020.0µg/LChloroethane 60-140 1.3 20.0 18.6 93.091.518.320.0µg/LChloroform 70-130 1.6 20.0 17.1 85.588.017.620.0µg/LChloromethane 60-140 2.8 20.0 19.5 97.594.518.920.0µg/L2-Chlorotoluene 70-130 3.1 20.0 19.5 97.596.519.320.0µg/L4-Chlorotoluene 70-130 1.0 20.0 21.7 10910220.320.0µg/L1,2-Dibromo-3-Chloropropane 70-130 6.6 20.0 19.3 96.594.518.920.0µg/L1,2-Dibromoethane 70-130 2.0 20.0 18.7 93.591.018.220.0µg/LDibromomethane 70-130 2.7 20.0 20.2 10198.019.620.0µg/L1,2-Dichlorobenzene 70-130 3.0 20.0 20.0 10099.519.920.0µg/L1,3-Dichlorobenzene 70-130 0.5 20.0 19.7 98.596.519.320.0µg/L1,4-Dichlorobenzene 70-130 2.0 20.0 18.5 92.591.518.320.0µg/LDichlorodifluoromethane 60-140 1.0 20.0 18.8 94.094.518.920.0µg/L1,1-Dichloroethane 70-130 0.5 20.0 18.8 94.090.018.020.0µg/L1,2-Dichloroethane 70-130 4.3 20.0 18.6 93.094.018.820.0µg/L1,1-Dichloroethene 70-130 1.0 20.0 18.7 93.594.518.920.0µg/Lcis-1,2-Dichloroethene 70-130 1.0 20.0 18.6 93.094.018.820.0µg/Ltrans-1,2-Dichloroethene 70-130 1.0 20.0 18.8 94.091.518.320.0µg/L1,2-Dichloropropane 70-130 2.6 20.0 Page 4 of 7Date:05/01/2023 04:27 PM Page 30 of 35 Quality Control Data 23-111-0102Report No: Project Description: Client ID:Withers & Ravenel Foothills Service Center QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V32548QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V32546 LCS-V32546 LCSD-V32546Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 18.7 93.593.018.620.0µg/L1,3-Dichloropropane 70-130 0.5 20.0 18.8 94.097.019.420.0µg/L2,2-Dichloropropane 70-130 3.1 20.0 19.1 95.595.519.120.0µg/L1,1-Dichloropropene 70-130 0.0 20.0 19.0 95.094.018.820.0µg/Lcis-1,3-Dichloropropene 70-130 1.0 20.0 18.7 93.592.518.520.0µg/Ltrans-1,3-Dichloropropene 70-130 1.0 20.0 459 91.886.4432500µg/LEthanol 60-140 6.0 20.0 18.7 93.592.518.520.0µg/LEthylbenzene 70-130 1.0 20.0 19.2 96.010020.020.0µg/LHexachlorobutadiene 70-130 4.0 20.0 18.6 93.091.518.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 1.6 20.0 19.9 99.597.519.520.0µg/LIsopropylbenzene 70-130 2.0 20.0 19.7 98.598.019.620.0µg/L4-Isopropyl toluene 70-130 0.5 20.0 17.5 87.580.516.120.0µg/L2-Hexanone 60-140 8.3 20.0 18.2 91.083.016.620.0µg/LMethyl Ethyl Ketone (MEK)60-140 9.1 20.0 16.8 84.083.516.720.0µg/LMethylene Chloride 70-130 0.5 20.0 19.5 97.594.018.820.0µg/LMethyl tert-butyl ether (MTBE)70-130 3.6 20.0 18.4 92.084.016.820.0µg/L4-Methyl-2-Pentanone 60-140 9.0 20.0 20.3 10296.019.220.0µg/LNaphthalene 70-130 5.5 20.0 19.3 96.596.019.220.0µg/Ln-Propylbenzene 70-130 0.5 20.0 19.5 97.596.519.320.0µg/LStyrene 70-130 1.0 20.0 19.7 98.597.519.520.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.0 20.0 19.5 97.596.019.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 1.5 20.0 19.5 97.597.019.420.0µg/LTetrachloroethene 70-130 0.5 20.0 18.7 93.592.018.420.0µg/LToluene 70-130 1.6 20.0 22.0 11010621.220.0µg/L1,2,3-Trichlorobenzene 70-130 3.7 20.0 21.1 10610320.520.0µg/L1,2,4-Trichlorobenzene 70-130 2.8 20.0 18.2 91.092.018.420.0µg/L1,1,1-Trichloroethane 70-130 1.0 20.0 Page 5 of 7Date:05/01/2023 04:27 PM Page 31 of 35 Quality Control Data 23-111-0102Report No: Project Description: Client ID:Withers & Ravenel Foothills Service Center QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V32548QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V32546 LCS-V32546 LCSD-V32546Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 19.0 95.093.018.620.0µg/L1,1,2-Trichloroethane 70-130 2.1 20.0 18.9 94.594.518.920.0µg/LTrichloroethene 70-130 0.0 20.0 19.3 96.596.519.320.0µg/LTrichlorofluoromethane 60-140 0.0 20.0 20.1 10193.518.720.0µg/L1,2,3-Trichloropropane 70-130 7.2 20.0 19.8 99.097.519.520.0µg/L1,2,4-Trimethylbenzene 70-130 1.5 20.0 19.6 98.097.519.520.0µg/L1,3,5-Trimethylbenzene 70-130 0.5 20.0 19.9 99.510020.020.0µg/LVinyl Acetate 60-140 0.5 20.0 18.9 94.596.019.220.0µg/LVinyl Chloride 60-140 1.5 20.0 39.0 97.598.239.340.0µg/Lm,p-Xylene 70-130 0.7 20.0 19.1 95.595.019.020.0µg/Lo-Xylene 70-130 0.5 20.0 10199.04-Bromofluorobenzene (S)70-130 97.299.2Dibromofluoromethane (S)70-130 10299.81,2-Dichloroethane - d4 (S)70-130 101101Toluene-d8 (S)70-130 Page 6 of 7Date:05/01/2023 04:27 PM Page 32 of 35 Quality Control Data 23-111-0102Report No: Project Description: Client ID:Withers & Ravenel Foothills Service Center QC Prep Batch Method: Volatile Organic Compounds - GC/MS 6200B V32624QC Analytical Batch(es): Analysis Method: Analysis Description: 6200 PT QC Prep:V32623 Associated Lab Samples: 94564, 94567, 94568 LRB-V32623 Matrix: AQULab Reagent Blank Parameter AnalyzedMQLBlank ResultUnits % Recovery % Rec Limits 04/28/23 14:170.500< 0.500µg/LBenzene 04/28/23 14:171.00< 1.00µg/LMethyl tert-butyl ether (MTBE) 04/28/23 14:170.500< 0.500µg/LToluene 04/28/23 14:174-Bromofluorobenzene (S)98.4 70-130 04/28/23 14:17Dibromofluoromethane (S)92.4 70-130 04/28/23 14:171,2-Dichloroethane - d4 (S)93.8 70-130 04/28/23 14:17Toluene-d8 (S)102 70-130 LCS-V32623 LCSD-V32623Laboratory Control Sample & LCSD LCSD ResultParameter Max RPD LCSD % Rec LCS %Rec LCS Result Spike Conc.Units % Rec Limits RPD 15.5 77.580.516.120.0µg/LBenzene 70-130 3.7 20.0 15.6 78.078.515.720.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.6 20.0 15.3 76.581.016.220.0µg/LToluene 70-130 5.7 20.0 97.898.04-Bromofluorobenzene (S)70-130 94.895.2Dibromofluoromethane (S)70-130 96.695.61,2-Dichloroethane - d4 (S)70-130 100101Toluene-d8 (S)70-130 Page 7 of 7Date:05/01/2023 04:27 PM Page 33 of 35 Fed Ex UPS US Postal Client Lab Courier Other : Shipment Receipt Form Customer Number: Customer Name: Report Number:23-111-0102 Withers & Ravenel 01221 Shipping Method Shipping container/cooler uncompromised? Thermometer ID:IRT-15 1.2 C Chain of Custody (COC) present?Yes No Yes No Not Present Yes No Not Present Yes No COC agrees with sample label(s)? Yes No COC properly completed Samples in proper containers? Sample containers intact? Sufficient sample volume for indicated test(s)? All samples received within holding time? Cooler temperature in compliance? Yes No Yes No Yes No Yes No Yes No Yes NoCooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes No Yes No N/A Yes No N/A Yes No N/ASoil VOA method 5035 – compliance criteria met Water - Sample containers properly preserved Water - VOA vials free of headspace Yes No N/A Trip Blanks received with VOAs Low concentration EnCore samplers (48 hr) High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d) High concentration container (48 hr) Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Number of coolers/boxes received Yes No 1 Signature:Angela D Overcash Date & Time:04/21/2023 14:38:40 Special precautions or instructions included? Comments: Page 34 of 35 Page 35 of 35 WithersRavenel Our People. Your Success.      APPENDIX D    WR’S STANDARD OPERATING PROCEDURES    Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Soil Sampling, Soil Boring and Monitor Well Installation, Well Development Soil borings are installed utilizing a stainless-steel hand auger, direct-push hydraulic drill or auger rotary drill using either a macro core™ sampler, hollow stem augers, or air rotary roller cone bit. Soil borings are typically sampled at discrete intervals from the bucket of a clean stainless steel hand auger, direct push stainless steel sampler with acetate sleeve, or a split barrel sampler. When appropriate, soil samples may be collected from drill cuttings associated with the boring or well installation. Monitor wells are constructed within select soil borings of one, two, or four-inch inside diameter PVC casing and machine slotted screen in accordance with NCAC Title 15A, Subchapter 02C (Well Construction Standards, Criteria and Standards Applicable to Water Supply and Certain Other Wells). Clean-washed “#2 Torpedo Sand” is typically utilized to fill the boring annulus surrounding the well screen, extending to a minimum of 1-foot above the well screen. A minimum 1-foot thick bentonite clay seal is emplaced above the sand pack and hydrated. Neat cement grout is placed in the remaining annulus space from the upper portion of the bentonite seal to within 1-foot of surface grade. In coastal plain areas where shallow groundwater is encountered, a variance to construction standards may be employed to ensure the upper portion of the well screen intersects the upper aquifer surface. Wellheads may be completed with either concrete-set flush mounted traffic-bearing steel skirted manholes with bolt down covers or steel above-ground “stick-up” well protectors set in a concrete pad. The monitoring wells are secured with locking caps. Temporary wells or piezometers may be completed with the PVC riser cut at or above grade, and are abandoned within 24-hours of their installation. Wells may be developed using a bailer, electric submersible pump, pneumatic pump, or peristaltic pump, dependent upon site conditions. When wells are developed by the driller, they may be developed with any of the methods outlined above, in addition to air or water injection. Soil boring logs and well construction details are typically prepared for presentation in a report appendix. Borings completed in bedrock may be drilled using air rotary, coring, or sonic drilling methods. Groundwater Depth to Water Measurements Groundwater level measurements are typically obtained using an electronic water level indicator which registers a tone and/or illuminated light when the probe contacts groundwater. Depth to groundwater measurements are obtained by lowering the probe attached to a cable usually marked in 0.01 foot intervals into the well until the probe of the meter intersects the water surface. The measurement from the top of the riser pipe or top of casing (TOC) to the water level is recorded to the nearest 0.01 foot. The electronic water level indicator probe and exposed probe cable is decontaminated between measurement locations. Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Free Product Level Measurements Light Non-Aqueous Phase Liquid (LNAPL) or “free product” present on the water table is measured using an electronic oil/water interface probe. The interface probe has both an audible and illuminating light that indicate when a liquid level is encountered. The oil/water interface probe registers a solid tone and solidly lit light when LNAPL petroleum product is encountered and a beeping tone flashing light when groundwater is encountered. Depth to LNAPL measurements are obtained by lowering the probe attached to a cable marked in 0.01 foot intervals into the well until the probe of the meter intersects the product or groundwater. The measurements from the top of the riser pipe or TOC to the liquid level are recorded to the nearest 0.01 foot. The thickness of LNAPL is calculated by subtracting the depth to LNAPL measurement from the depth to groundwater measurement. The electronic interface probe is decontaminated between measurement locations. Soil Sampling and Field Screening Soil sampling is performed in general accordance with ASTM: 1586-84 where applicable. Sampling procedures are followed to protect the chemical integrity of the soil samples and minimize the potential for cross contamination between sample locations, including discarding of the exterior of the sample which contacts the auger bucket, acetate sleeve, or split barrel sampler, the use of stainless steel sampling equipment, and the thorough decontamination of sampling apparatus prior to use and between sample locations. Soil samples retained as a part of excavation or other intrusive “digging” activities may be collected from the bucket of excavation equipment or using a hand shovel, if appropriate. Care to collect soil samples from excavation equipment includes retrieving native soil from material that has not made contact with the excavating equipment. Samples are collected in sealable bags or by directly filling sample containers as described above. Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample integrity and minimize the potential for cross contamination or field personnel exposure to contaminants. Sampling equipment such as hand auger extensions and buckets, direct push samplers, split spoons or shovels, are decontaminated prior to their use in the collection of samples. Samples are placed within laboratory grade sample containers provided by the laboratory to which the samples are submitted, labeled, sealed, and placed in an ice filled cooler. An aliquot of the sample is typically placed in a clean sealable bag and allowed to reach ambient air temperature for future screening of volatile vapor content with a photoionization detector (PID), flame-ionization detector (FID) or other portable screening device. Screening of samples with a PID, FID or other field screening device is performed in accordance with device manufacturer specifications for screening, following calibration of the instrument based on manufacturer recommended procedures. Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Groundwater Sampling Groundwater samples are generally collected using one of three standard methods – through the use of a dedicated, disposable bailer, a peristaltic pump or submersible electric pump. When sampling with a bailer, a minimum of three well volumes of groundwater are extracted from the well as a means of purging, unless the well is purged to a “dry” state prior to the removal of three volumes of water. Prior to collection of the groundwater sample with the bailer, the water level is allowed to recover to within 80% of the original level measured prior to purging. When sampling with a peristaltic or submersible electric pump, polyethylene (PE) tubing (or equivalent) is emplaced into the screened section of the monitoring well, and the pump is used to extract water through the tubing. When using the either of these methods, general water quality measurements including but not limited to pH, temperature, dissolved oxygen (DO), oxygen reductive potential (ORP), specific conductivity and turbidity may be used as methods for determining when an adequate purge of the well has been conducted. When water quality parameters are measured, the resulting data are included in well purge forms or field notes specific to each site and sampling point. Following the purging of three well volumes of groundwater (in the case of the bailed well) or stability of monitored measurements (in the case of the peristaltic or submersible electric pump), the groundwater sample(s) are introduced directly into sample containers provided by the laboratory to which samples are ultimately submitted for analysis. Any samples requiring chemical preservation are contained in pre-preserved container(s) provided by the laboratory. Sampling is performed using new, disposable nitrile gloves for each sample location to ensure sample integrity and minimize the potential for cross contamination of samples or field personnel exposure to contaminants. Water Supply Well Sampling Sampling of water supply wells is accomplished through the collection of a representative sample from an in-line water tap or other point accessible for sampling. Where possible, the sample is collected from a point prior to any filtration or point of entry (POE) system which might be installed on a well. In some cases, samples will be collected from both pre and post-POE locations. Prior to the collection of samples through an in-place sampling point, the tap or sampling port is cleaned with an Alconox® and deionized water solution, rinsed with deionized water, and again with an isopropyl alcohol (IPA) rinse. In the case of active supply wells (e.g., a well with a useable well pump with an active power supply), the well pump is energized and allowed to run for a minimum of ten (10) minutes time, after which a sample is contained in laboratory grade sample containers as described in the previous section. Water quality parameters may be (but are not necessarily) measured in association with the well purging. Supply wells without active power supplies are not generally sampled, as the well seal cannot be compromised by individuals not certified as a well contractor. However, in the case of a well with no power supply or pump installed, samples could be obtained through the use of a bailer, peristaltic pump or electric submersible pump. Generalized Standard Operating Procedures (Not All Inclusive) WithersRavenel Our People. Your Success. Decontamination Procedures Decontamination procedures employed in the performance of field activities will vary dependent upon the method(s) of sampling performed at any site, but will generally include the following: • Remove excess soil/sludge from any sampling equipment as needed, • Wash and scrub the equipment with a phosphate-free detergent such as Alconox® or Liquinox® in a contaminant-free tap water solution. Use a brush to remove particulate matter and surface films as necessary, • Rinse thoroughly with tap water, • Rinse thoroughly with analyte-free water (deionized water),  Rinse thoroughly with isopropyl alcohol, • Allow the equipment to air dry, • Prevent inadvertent contamination during storage and transport (accomplished through storage of equipment in foil or plastic bags/sheeting). In the case of disposable bailers and tubing utilized for the purging and sampling of wells, these items may be decontaminated prior to their disposal. In general, no decontamination of these items is necessary prior to their use in sampling.