FA-1286_24238_CA_MRP_20230523

2401 Brentwood Road, Suite 107
Raleigh, NC 27604
P [phone]
F [phone]
Terracon.com
May 23, 2023
Mr. Mark Petermann
North Carolina Department Environmental Quality
Division of Waste Management
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
Email:[e-mail]
Re: Quarterly Injection Performance Monitoring Report
Blalock Fina
3574 NC Highway 55
Angier, Harnett County, North Carolina
NCDEQ Incident Number: 24238
UST Number: FA-1286
Terracon Project No. 70149672B
Dear Mr. Petermann:
Terracon Consultants, Inc. is pleased to submit this Quarterly Injection Performance Monitoring
Report for the above-referenced property. This report has been prepared in general accordance
with North Carolina Department Environmental Quality, Underground Storage Tank (UST)
Section Assessment Guidelines and Corrective Action Guidelines for Petroleum and Hazardous
Substance UST Releases / Petroleum Non-UST Releases,dated January 19, 2021, and Task
Authorization No. 06 approved on March 13, 2023.
If you have any questions regarding this report or the assessment activities, please contact us
at 919-873-2211.
Sincerely,
Terracon Consultants, Inc.
Ethan C. Dinwiddie, PG Les J. Abbott, Jr.
Senior Staff Geologist Field Scientist
Donald R. Malone, PE, RSM Justin F. Fabriziani, RSM
Senior Engineering Consultant Office Manager
QUARTERLY INJECTION PERFORMANCE
MONITORING REPORT
Blalock Fina (Incident #24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
May 23, 2023
Terracon Project No. 70149672B
Prepared for:
North Carolina Department Environmental Quality
Division of Waste Management
Raleigh, North Carolina
Prepared by:
Terracon Consultants, Inc.
Raleigh, North Carolina
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Table of Contents
A.SITE INFORMATION .................................................................................................... 1
B.EXECUTIVE SUMMARY ............................................................................................... 2
C.SITE HISTORY AND CHARACTERIZATION ................................................... 4
C.1 Site Setting ........................................................................................................................................ 4
C.2 Release Summary .......................................................................................................................... 4
C.3 Previous Investigations .............................................................................................................. 5
C.4 Water Supply Wells ....................................................................................................................... 6
D.ASSESSMENT INFORMATION ................................................................................ 6
D.1 Free Product Evaluation .............................................................................................................. 6
D.2 Groundwater Sampling Activities........................................................................................... 6
D.3 Field Groundwater Measurements and Sulfate Analytical Results ........................ 7
D.4 Groundwater Analytical Results ............................................................................................. 8
D.5 Soil Gas Sample Point Construction ...................................................................................... 9
D.6 Soil Gas Analytical Results ...................................................................................................... 10
E.CONCLUSIONS AND RECOMMENDATIONS ................................................. 10
F.REFERENCES ................................................................................................................... 13
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TABLE OF CONTENTS (CONT.)
FIGURES
Figure 1: Site Location Map
Figure 2: Site Plan
Figure 3: Water Supply Well Location Map
Figure 4: Groundwater Elevation Map (March 2023)
Figure 5: Groundwater Analytical Results (March 2023)
Figure 6: Benzene Isoconcentration Map (March 2023)
Figure 7: Naphthalene Isoconcentration Map (March 2023)
Figure 8: Toluene Isoconcentration Map (March 2023)
Figure 9: 1,2,4-Trimethylbenzene Isoconcentration Map (March 2023)
Figure 10: Total Xylenes Isoconcentration Map (March 2023)
Figure 11: Soil Gas Sample Location Map
TABLES
Table 1: Conceptual Site Model
Table 2: Water Supply Well Information
Table 3: Monitoring Well Construction Information and Historical Groundwater Elevations
Table 4: Field Groundwater Quality Measurements and Injectant Indicator Analytical Results
Table 5: Summary of Groundwater Analytical Results
Table 6: Summary of Soil Gas Analytical Results
APPENDICES
Appendix A: Photographs and Field Notes
Appendix B: Laboratory Analytical Results and Chain-of-Custody Forms
Appendix C: Soil Gas Risk Calculator Results
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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QUARTERLY INJECTION PERFORMANCE MONITORING
REPORT
A.SITE INFORMATION
Date of Report:May 23, 2023
NCDEQ Incident No:24238
UST No.FA-1286
Facility ID:Unknown/Not Applicable
Site Name:Blalock Fina
Site Location:3574 NC Highway 55
Angier, North Carolina 27501
Latitude:N 35.460095
Longitude:W 78.694913
UST Owner/Operator:N/A - NCDEQ
Current Property Owner:Ms. Zena Howell
3574 NC Highway 55
Angier, NC 24238
[phone]
Current Property
Occupant: Currently vacant, residential use proposed
Consultant:Terracon Consultants, Inc. (Contact: Justin L. Fabriziani)
2401 Brentwood Road, Suite 107
Raleigh, North Carolina 27604
919-873-2211
Laboratory:Pace Analytical Services, LLC (NCDEQ No. 329)
106 Vantage Point Drive
West Columbia, South Carolina 29712
[phone]
Release Information:Release Discovery Date: February 2001
Estimated Quantity: Unknown
Cause of Release: Underground Storage Tank System
Currently Active Tanks: None
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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I, Donald R. Malone, a Licensed Engineer for Terracon Consultants, Inc. (Terracon), do certify
that the information contained in this report is correct and accurate to the best of my
knowledge.
Donald R. Malone, P.E.
North Carolina Professional Engineering License No. 20195
Terracon is licensed to practice geology and engineering in North Carolina. The certification
numbers of the corporation are C-367 and F-0869, respectively.
B.EXECUTIVE SUMMARY
The Blalock Fina site, located at 3574 NC Highway 55 in Angier, North Carolina (site), is 0.69
acres (Figure 1). The property is vacant and consists of cleared land. The site formerly
contained a gasoline station and convenience store, which began operation in 1957. The gas
station was reportedly closed in 1989 and the underground storage tanks (USTs) were
reportedly pumped dry and filled with a sand/cement/water slurry. A release from the former
on-site UST system was discovered in February 2001, when laboratory analyses of soil samples
collected following the removal of the USTs revealed the presence of petroleum contaminants.
Subsequent environmental investigations at the site are summarized in the following sections.
The North Carolina Department of Environmental Quality (NCDEQ) filed a Notice of Residual
Petroleum (NRP) for soil and groundwater on December 9, 2016 prior to the sale of the
property between the property owner at the time, Mr. Donald Blalock, and the purchaser, Mr.
Scott Leonard. The NRP was filed with the Harnett County deed in Book 3462, Page 818-820.
As requested by NCDEQ, Terracon mobilized to the site on March 30 and 31, 2023 to:
n gauge depths to groundwater in monitoring wells;
n measure the potential presence of free product in the wells;
n collect field parameters to assess the effectiveness of the remedial activities
performed in August 2021 that included the injection of RemRx™ Controlled Release
Polymer (CRP) Persulfate and instantaneous release persulfate into multiple borings
(Terracon, 2021);
n collect samples from fifteen monitoring wells (MW-1, MW-3 through MW-12, RW-1,
RW-2, VEW-1, and VEW-2) for analysis of volatile organic compounds (VOCs) and
sulfate; and
n Install two soil gas sample points (SG-01 and SG-02) at 5 feet below land surface
(bls) and collect soil gas samples for analysis of VOCs.
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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Based on information obtained during the groundwater and soil gas monitoring activities,
Terracon provides the following findings and conclusions:
n Shallow groundwater depths in March 2023 ranged from 4.55 to 9.00 feet below top of casing
(bTOC). The apparent direction of surficial groundwater flow was to the southwest.
n Free product thicknesses were not detected in the monitoring wells. Free product has not been
detected since May 2012 (in MW-5).
n Benzene; ethylbenzene; isopropylbenzene; naphthalene; n-propylbenzene; toluene;
1,2,3-trichloropropane; 1,3,5-trimethylbenzene; 1,2,4-trimethylbenzene; and/or total xylenes
were detected at concentrations above the 15A North Carolina Administrative Code (NCAC) 2L
Groundwater Quality Standards (2L Standards) in wells MW-1, MW-3, MW-5, MW-6, MW-11,
RW-1, RW-2, and VEW-1.
n Petroleum constituents were not detected above the North Carolina Gross Contaminant Levels
(GCLs) during this sampling event. Benzene has historically been detected above the GCL in
MW-3 in January 2012 and in MW-5 in January 2018.
n VOCs were detected above the laboratory reporting limits, but below the 2L Standards in
MW-7, MW-8 and VEW-2.
n VOCs were not detected above the laboratory reporting limits in MW-4, MW-9, MW-10, and
MW-12.
n Based on the analytical results of injectant indicators (i.e., sulfate, specific conductivity, and
oxidation-reduction potential [ORP]), local spreading of RemRx™’s CRP Persulfate was
indicated by higher average specific conductivity and ORP compared to the baseline sampling
event and higher sulfate concentrations in monitoring wells located nearer and immediately
downgradient of the injectant borings. A reduction in sulfate and conductivity values in the
monitoring wells compared to previous sampling events may be due to dissipation of the
instantaneous release persulfate. Additional monitoring events will aid in interpreting field
measurement and analytical trends.
n Groundwater samples from monitoring wells MW-3, MW-5, RW-1, and RW-2 in close proximity
to the RemRx™ injection locations in August 2021 have exhibited limited concentration
reductions. However, only three monitoring events (November 2022, February 2022, and
September 2022) have occurred since the August 2021 injections; therefore, additional time
may be needed for the RemRx™ injections to present larger concentration changes.
Groundwater impacts extended off the site to the southwest. The groundwater contaminant
plume appeared to be relatively stable and was generally delineated horizontally with the
exception of the southeastern extent. The contaminant plume was not vertically delineated.
n Seven potable water supply wells have historically been identified within 1,000 feet of the
source area. These wells are located to the north, east, and south of the site and are
topographically cross- to up-gradient in relation to the plume. Active potable wells have not
been identified within 500 feet of the source area. Based on Terracon's receptor survey in
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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October 2019, municipal water was available to the site and properties located within 1,000
feet of the source area.
n VOCs were detected above the laboratory reporting limits, but below NCDEQ Residential and
Non-Residential Sub Slab and Exterior Soil Gas Screening Levels (SGSL) in SG-01 and SG-02.
Terracon entered the maximum detected concentrations of the soil gas samples into the
NCDEQ Risk Calculator (January 2023 version) to evaluate human health risk from vapor
intrusion into the on-site residence. Based on the risk calculator results, the detected
concentrations of VOCs do not present an unacceptable risk to the residence. Based on the
results, additional evaluation of the PVI pathway is not warranted at this time. Further
evaluation should be considered if the following occurs:
o Extension of the residential building over a larger footprint on the site;
o Connection of additional utilities to the on-site dwelling that may act as preferential
pathways for soil vapor intrusion;
o Petroleum concentrations in the on-site monitoring wells increase; or
o Future releases occur on or adjacent to the site.
C.SITE HISTORY AND CHARACTERIZATION
The purpose of this report is to present the findings of assessment activities performed in March
2023 at the Blalock Fina site located at 3574 NC Highway 55 in Angier, Harnett County, North
Carolina. This Quarterly Injection Performance Monitoring Report was prepared for the site in
response to a request by Mr. Mark Petermann with the NCDEQ DWM, State Lead Program. The
Quarterly Injection Performance Monitoring Report was prepared in general accordance with the
15A NCAC 2L .0115 regulations and the NCDEQ UST Section Assessment Guidelines and
Corrective Action Guidelines for Petroleum and Hazardous Substance UST Releases / Petroleum
Non-UST Releases,dated January 19, 2021, under the supervision of Mr. Donald R. Malone, a
North Carolina registered professional engineer (North Carolina Professional Engineering License
No. 20195).
C.1 Site Setting
The Blalock Fina site is comprised of 0.69 acres and consists of vacant, predominantly cleared
land. The surrounding properties consist of residential properties to the west, south, and east
with agricultural land to the north. The site and surrounding properties are depicted on
Figures 2 and 3.
C.2 Release Summary
A petroleum release was discovered in February 2001, when laboratory analysis of soil samples
collected following the removal of the former on-site USTs revealed the presence of petroleum
contaminants (Armstrong Geological & Engineering Services, P.C., 2001). The site operated as
a gasoline station and convenience store beginning in 1957. The site operated two 1,000-
gallon gasoline USTs with a third 550-gallon gasoline UST added to the site in 1958.
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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Approximately 1,224 tons of contaminated soil was excavated during the UST removal activities
in February 2001. A chronological summary of UST removal and subsequent assessment
activities at the site is discussed in the following subsection of this report.
C.3 Previous Investigations
Investigation activities conducted between 2002 and the present included installation of twelve
monitoring wells, two recovery wells, two vapor extraction wells, water supply well sampling,
and a mobile multi-phase extraction (MMPE) event in 2004. An injection event was conducted in
July 2011 that utilized chemical oxidation and oxygen-releasing compounds. The injectate
consisted of a solution of 18% persulfate and 2% PermOx Plus into two separate areas at the
site including the former source area on the north side of NC Highway 55 and a down-gradient
area south of NC Highway 55. During the injection, vacuum extraction was applied to extraction
wells and monitoring wells to remove contaminant mass, prevent groundwater mounding, and
provide hydraulic control (Force Environmental Service Company, LLC, 2011).
NCDEQ filed an NRP for soil and groundwater on December 9, 2016 prior to the sale of the
property between the property owner at the time, Mr. Donald Blalock, and the purchaser, Mr.
Scott Leonard. The NRP is filed with the deed in Book 3462, Page 818-820.
From 2014 to the present, Terracon has conducted groundwater and soil investigations at the
site to monitor the concentrations and extents of petroleum contamination. Due to the lack of
plume delineation to the southeast of MW-3, Terracon installed monitoring well MW-12 in
October 2019 (Terracon, 2019). In July and August 2021, Terracon completed a baseline
groundwater sampling event of the monitoring well network prior to a persulfate injection at the
site. Between August 23 and 25, 2021, Terracon completed the application of approximately
1,800 pounds of RemRx™ CRP Persulfate and 900 pounds of instantaneous release persulfate in
18 soil borings up to 18 feet below land surface to chemically enhance degradation of
petroleum contaminants in groundwater (Figure 3) (Terracon, 2021). RemRx™ CRP Persulfate
was utilized to establish in-situ chemical oxidation of the petroleum hydrocarbons by providing
a sustained delivery of oxidizing persulfate ions (S2O82–) and sulfate radicals (SO4• –). RemRx™
developed the sustained-release process to reduce the potential for contaminant rebounding.
Persulfate and the resulting sulfate radical anions degrade fuel-related constituents using
reduction/oxidation chemistry and do not rely on the presence of naturally occurring or
supplemental microbial bacteria.
Between November 2021 and March 2023, Terracon completed four post-injection groundwater
monitoring events after application of the RemRx™ CRP Persulfate. Local spreading of the CRP
Persulfate was indicated by higher average specific conductivity and ORP compared to the
baseline sampling event and higher sulfate and persulfate concentrations in some of the
monitoring wells located nearer and immediately downgradient of the injectant borings. Overall
reductions of conductivity, ORP, and sulfate concentrations in later post-injection monitoring
events indicated an apparent dissipation of the instantaneous release persulfate (Terracon,
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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2022a; 2022b; 2022c, and 2022d). The results of the injection and other investigation activities
were used to generate a conceptual site model of the current site conditions (Table 1).
C.4 Water Supply Wells
Terracon performed a receptor survey in October 2019 and identified thirteen water supply
wells within 1,000 feet of the source area. At that time, seven of the thirteen wells appeared to
be within 1,000 feet of the source area and serve as active, potable water sources. These wells
were generally situated topographically cross- to up-gradient of the plume. The most proximate
potable water supply well was WSW-5, located approximately 625 feet east of and cross-
gradient to the source area. Downgradient water supply wells were either inactive or
non-potable. Municipal water was available to the site and surrounding properties located
within 1,000 feet of the source area. Results of the water-supply well inventory are in Table 2
and well locations are on Figure 3.
D.ASSESSMENT INFORMATION
Terracon mobilized to the site on March 30 and 31, 2023 to:
n gauge depths to groundwater in monitoring wells;
n measure the potential presence of free product in the wells;
n collect field parameters to assess the effectiveness of the remedial activities
performed in August 2021 that included the injection of RemRx™ CRP Persulfate and
instantaneous release persulfate into multiple borings (Terracon, 2021);
n collect samples from fifteen monitoring wells (MW-1, MW-3 through MW-12, RW-1,
RW-2, VEW-1, and VEW-2) for analysis of VOCs and sulfate; and
n Install two soil gas sample points 4.5 to 5 feet bls and collect soil gas samples for
analysis of VOCs.
D.1 Free Product Evaluation
Free product was not detected in the monitoring wells during this assessment. Free product has
not been detected since May 2012 (in MW-5).
D.2 Groundwater Sampling Activities
Prior to sample collection, Terracon gauged the depth to groundwater in the monitoring wells.
Current and historical groundwater elevation measurements are in Table 3. Shallow
groundwater depths in March 2023 ranged from 4.55 to 9.00 feet bTOC. The apparent direction
of surficial groundwater flow direction was to the southwest based on the calculated
groundwater elevations. Groundwater elevations from the March 2023 gauging event are in
Figure 4. The manway for MW-1 was observed to be located below the existing land grade
and Terracon recommends raising the manway for continued integrity of the well. Copies of
field notes and a photographic log are in Appendix A.
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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Prior to sampling, the wells were purged with a peristaltic pump using low flow sampling
techniques (i.e., <200 milliliters per minute) prior to sampling. Field parameters consisting of
pH, temperature, ORP, dissolved oxygen, and specific conductivity were measured at each of
the well locations. After stabilization of pH and specific conductivity, a groundwater sample was
collected directly into laboratory-supplied containers at low-flow sampling rates.
The groundwater samples were placed in laboratory-supplied glassware, labeled, and stored in
an ice-packed cooler. The samples, along with chain-of-custody documentation, were delivered
to Pace Analytical Services, LLC, in Huntersville, North Carolina for analysis of VOCs by United
States Environmental Protection Agency (USEPA) Method 6200B, including methyl tert-butyl
ether, EDB, and di-isopropyl ether, and sulfate by USEPA Method 9056A.
D.3 Field Groundwater Measurements and Sulfate Analytical Results
The groundwater field parameters measured in the monitoring wells from this event and
comparisons to baseline average measurements (Table 4) are summarized below:
n pH field measurements in the monitoring wells ranged from 4.53 to 6.39 standard units
(s.u.) and were on average 1.21 s.u. lower than the baseline sampling event. This is
not remarkable because of the strong buffering capacity of typical aquifer-matrix soils.
n Specific conductivity measurements in the monitoring wells ranged from 34 to 800
microsiemens per centimeter (μS/cm). Specific conductivity is a surrogate for the
quantity of ions present in water; and thus, provides an indicator for the presence of
sulfate, persulfate, and perhaps other naturally occurring ions that might have been
released from aquifer matrix due to the remedial injections. The average conductivity
measurements in March 2023 were approximately 30 μS/cm higher than the baseline
sampling event and the quarterly monitoring event in September 2022. MW-4, which
is very near to remedial injections had significantly higher specific conductivity values
as compared to the baseline event; however, most of the other wells had similar
conductivity values as compared to the baseline event.
n Dissolved oxygen measurements in the monitoring wells ranged from 0.07 to 9.06
milligrams per liter (mg/L) and were on average approximately 0.3 mg/L lower than
the baseline sampling event. Oxygen concentrations vary from event to event, mainly
due to infiltration and recharge from rain events, and these small concentration
changes likely are not directly related to the remedial injections.
n ORP measurements in the monitoring wells ranged from -150.7 to 283.2 millivolts
(mV). ORP is a measure of the activity or strength of a water system to transfer
electrons either by oxidizing processes (increasing and/or positive ORP values) or
reducing processes (lower or negative ORP values). The ORP measurements in March
2023 were on average 145 mV higher than the baseline sampling event and
approximately 62 mV lower than the quarterly monitoring event in September 2022.
This indicates that the RemRx™ CRP Persulfate injected into the surficial aquifer initially
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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increased the oxidation potential of groundwater, especially in wells near to the
injection areas; however, the oxidation potential appears to be decreasing over time as
the mass of CRP decreases.
Dissolved sulfate can be present naturally in groundwater. Terracon did not collect initial
background sulfate concentrations prior to the remedial injections; however, the average sulfate
concentration was 5 mg/L in the “background” monitoring wells upgradient or fairly distant from
the injection borings (MW-7, MW-9, MW-10, and MW-12). Therefore, we consider 5 mg/L as a
reasonable background concentration for sulfate at the site.
The RemRx™ CRP Persulfate releases sulfate during the reaction and/or decay the S2O82– and SO4•
– ions. Likewise, some of the microorganisms in groundwater can utilize sulfate as an alternative
electron acceptor to drive anaerobic bio-oxidation of the petroleum hydrocarbons via the sulfate
reduction pathway. The average sulfate concentrations ranged from 233 mg/L in November 2021
to 62 mg/L in March 2023 in “non-background wells” immediately adjacent to and downgradient of
the RemRx™ CRP Persulfate injection borings (i.e., MW-1 through MW-6, MW-8, RW-1, RW-2,
VEW-1, and VEW-2). Therefore, average sulfate concentrations in these monitoring wells
decreased by approximately 170 mg/L from November 2021 to March 2023, likely due to decay of
the instantaneous release persulfate and the CRP. The sulfate concentrations in downgradient
monitor wells RW-2 and VEW-1 were less than the background sulfate concentration for the site;
however, sulfate concentrations in downgradient monitor wells VEW-2, MW-6, MW-8, and MW-11
remained elevated above background.
D.4 Groundwater Analytical Results
Based on the laboratory analytical report, benzene; ethylbenzene; isopropylbenzene;
naphthalene; n-propylbenzene; toluene; 1,2,3-trichloropropane; 1,3,5-trimethylbenzene;
1,2,4-trimethylbenzene; and/or total xylenes were detected at concentrations above the 2L
Standards in wells MW-1, MW-3, MW-5, MW-6, MW-11, RW-1, RW-2, and VEW-1. Petroleum
constituents were not detected above the GCLs during this sampling event. Benzene has
historically been detected above the GCL in MW-3 in January 2012 and in MW-5 in January 2018.
VOCs were detected above the laboratory reporting limits, but below the 2L Standards in MW-7,
MW-8, and VEW-2. VOCs were not detected above the laboratory reporting limits in MW-4, MW-9,
MW-10, and MW-12.
Groundwater analytical results are in Figure 5 and Table 5. A copy of the laboratory analytical
report is in Appendix B.Isoconcentration maps for the five leading petroleum contaminants
(benzene; naphthalene; toluene; 1,2,4-trimethylbenzene; and total xylenes) are on Figures 6,
7,8, 9, and 10, respectively. These maps show the contaminant plumes generally originating
from the south-central portion of the site in the source area and migrating to the west-
southwest underneath NC Highway 55 and onto the adjacent southwestern property.
Terracon evaluated the trends in petroleum constituents in monitoring wells immediately
adjacent to and downgradient of the remediation area (MW-3, MW-4, MW-5, MW-6, MW-8,
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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VEW-1, and VEW-2). Apparent reductions in constituent concentrations are not yet apparent.
Therefore, future monitoring events will be required to assess the success of the selected
remedial strategy.
The groundwater contaminant plume appears to be relatively stable and is generally delineated
horizontally with the exception of the southeastern extent. The extent of groundwater impact is
not vertically delineated. Active potable wells are not located within 500 feet of the source
area.
D.5 Soil Gas Sample Point Construction
The soil vapor points were constructed in general accordance with the practices outlined in the
NCDEQ DWM Vapor Intrusion Guidance (March 2018), the ITRC Vapor Intrusion Pathway: A
Practical Guideline (January 2007), and the ITRC Petroleum Vapor Intrusion: Fundamentals of
Screening, Investigation, and Management (October 2014).
The temporary soil vapor points were constructed in a borehole advanced to 5 feet bls via a
handheld Hilti hammer drill utilizing decontaminated 1.25-inch steel rods and a disposable steel
drive point. The temporary soil vapor points were constructed as follows:
n Installation of a 6-inch stainless steel soil gas implant from 4.5 to 5 feet bls;
n Installation of 0.25-inch outside diameter Teflon® lined tubing to the ground surface;
n Placement of sand in the borehole annulus to approximately one foot above the bottom
of the borehole, followed by hydrated bentonite to the ground surface.
After installation, the Teflon® lined tubing was capped and the soil vapor points were allowed to
equilibrate for at least two hours before sampling. Prior to sampling, a 0.25-inch outside
diameter Teflon® lined tube and Swagelok® fittings were used to connect the monitoring point
assembly to a laboratory-supplied, batch-certified 1.0-liter Summa® canister. A helium tracer
test was conducted prior to collecting the samples. The tracer test serves as a quality
assurance/quality control (QA/QC) method to verify the integrity of the soil vapor point seal in
addition to the connection of the sampling manifold and the soil vapor point. An MGD-2002
helium detector capable of measuring helium concentrations down to 25 parts per million (ppm)
was used to verify the presence and concentration of helium in the sample point and/or within
the sampling manifold.
The protocol for using a tracer gas is to enclose the sampling point and the sampling manifold
with a shroud. The helium tracer gas is released into the shroud until the atmosphere inside the
shroud is approximately 10 to 20 percent helium. Approximately three purge volumes (one
purge volume being equal to the volume within the borehole) were evacuated through Teflon®-
lined tubing that passes through the shroud using a hand pump. Purge samples were screened
for helium to assess for leaks in the well seal and/or sampling manifold after removal of each
well volume. The annulus is considered to be sufficiently sealed when helium concentrations
detected within the sampling points were less than ten percent of the helium concentration in
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
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the shroud. The shroud was enriched with greater than 10 percent helium. Helium was not
detected within the sample points at concentrations greater than the field instrument detection
limit (25 ppm [i.e., 0.0025 percent]). Purged soil gas was also screened with a miniRAE 3000
photoionization detector to assess for VOCs. The shroud helium concentration and the helium
concentration in the purged soil vapor was documented after each volume purged.
After completion of the helium tracer test, the valve of the purge device was closed, and the
sample canister valve was opened to collect soil vapor for laboratory analysis. The samples
were collected in a laboratory supplied, batch-certified 1.0-liter Summa® canister connected to
sample tubing using Swagelok® fittings at the soil vapor point. The sample canisters were filled
using a dedicated flow controller set to a sample rate of less than or equal to 200 ml/min and
the sample collection duration was 5 minutes. An in-line vacuum gauge was installed to the
sample controller to verify initial vacuum levels within the canister and as an indicator that the
target final pressure had been reached (i.e. sampling is complete). The sample canister valve
was closed when the gauge measured -6 inches in Hg vacuum. After completion of the sampling
activities, the soil vapor point was abandoned by removing the tubing. The location of the soil
gas points (SG-01 and SG-02) is depicted in Figure 11. Photographs and field notes are in
Appendix A.
The soil vapor samples were shipped via FedEx to Pace Analytical National Center for Testing
and Innovation in Mount Juliet, Tennessee under standard chain-of-custody procedures and
analyzed for VOCs via USEPA Method TO-15.
D.6 Soil Gas Analytical Results
Soil gas analytical results were compared with the NCDEQ Residential and Non-Residential
SGSLs. Multiple VOCs were detected above their laboratory reporting limits, but below their
respective Residential and Non-Residential SGSLs. Terracon entered the maximum detected
concentrations from the soil gas samples into the NCDEQ Risk Calculator (January 2023
version) to evaluate human health risk from vapor intrusion into the on-site residence. Based
on the risk calculator results, the cumulative carcinogenic risk and non-carcinogenic hazard
index were below NCDEQ risk thresholds (1E-04 and 1.0, respectively) for residential and non-
residential soil gas to indoor air scenarios. Therefore, the detected concentrations of VOCs do
not present an unacceptable risk to the residence.
Soil gas analytical results are in Table 6. A copy of the laboratory analytical report is in
Appendix B.A copy of the risk calculator results are in Appendix C.
E.CONCLUSIONS AND RECOMMENDATIONS
Terracon provides the following findings and conclusions based on the information obtained
during this and prior groundwater monitoring events:
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
Explore with us 11
n Shallow groundwater depths in March 2023 ranged from 4.55 to 9.00 feet bTOC. The
apparent direction of surficial groundwater flow was to the southwest.
n Free product thicknesses were not detected in the monitoring wells. Free product has not been
detected since May 2012 (in MW-5).
n Benzene; ethylbenzene; isopropylbenzene; naphthalene; n-propylbenzene; toluene;
1,2,3-trichloropropane; 1,3,5-trimethylbenzene; 1,2,4-trimethylbenzene; and/or total xylenes
were detected at concentrations above the 2L Standards in wells MW-1, MW-3, MW-5, MW-6,
MW-11, RW-1, RW-2, and VEW-1.
n Petroleum constituents were not detected above the GCLs during this sampling event.
Benzene has historically been detected above the GCL in MW-3 in January 2012 and in MW-5
in January 2018.
n VOCs were detected above the laboratory reporting limits, but below the 2L Standards in
MW-7, MW-8 and VEW-2.
n VOCs were not detected above the laboratory reporting limits in MW-4, MW-9, MW-10, and
MW-12.
n Based on the analytical results of injectant indicators (i.e., sulfate, specific conductivity, and
ORP), local spreading of RemRx™’s CRP Persulfate was indicated by higher average specific
conductivity and ORP compared to the baseline sampling event and higher sulfate
concentrations in monitoring wells located nearer and immediately downgradient of the
injectant borings. A reduction in sulfate and conductivity values in the monitoring wells
compared to previous sampling events may be due to dissipation of the instantaneous release
persulfate. Additional monitoring events will aid in interpreting field measurement and
analytical trends.
n Groundwater samples from monitoring wells MW-3, MW-5, RW-1, and RW-2 in close proximity
to the RemRx™ injection locations in August 2021 have exhibited limited concentration
reductions. However, only three monitoring events (November 2022, February 2022, and
September 2022) have occurred since the August 2021 injections; therefore, and additional
time may be needed for the RemRx™ injections to present larger concentration changes.
Groundwater impacts extended off the site to the southwest. The groundwater contaminant
plume appeared to be relatively stable and was generally delineated horizontally with the
exception of the southeastern extent. The contaminant plume was not vertically delineated.
n Seven potable water supply wells have historically been identified within 1,000 feet of the
source area. These wells are located to the north, east, and south of the site and are
topographically cross- to up-gradient in relation to the plume. Active potable wells have not
been identified within 500 feet of the source area. Based on Terracon's receptor survey in
October 2019, municipal water was available to the site and properties located within 1,000
feet of the source area.
n VOCs were detected above the laboratory reporting limits, but below NCDEQ Residential and
Non-Residential SGSLs in SG-01 and SG-02. Terracon entered the maximum detected
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
Explore with us 12
concentrations of the soil gas samples into the NCDEQ Risk Calculator (January 2023 version)
to evaluate human health risk from vapor intrusion into the on-site residence. Based on the
risk calculator results, the detected concentrations of VOCs do not present an unacceptable
risk to the residence. Based on the results, additional evaluation of the PVI pathway is not
warranted at this time. Further evaluation should be considered if the following occurs:
o Extension of the residential building that creates a larger footprint on the site;
o Connection of additional utilities to the on-site dwelling that may act as preferential
pathways for soil vapor intrusion;
o Petroleum concentrations in the on-site monitoring wells increase; or
o Future releases occur on or adjacent to the site.
Based on the data presented in this Quarterly Injection Performance Monitoring Report,
Terracon recommends the following activities be completed at the site.
n Conduct quarterly measurements of groundwater field parameters (e.g., pH, conductivity, and
ORP) to evaluate the distribution and release of the CRP Persulfate. In addition, semi-annual
groundwater monitoring events should be conducted to evaluate the effectiveness of the CRP
Persulfate in remediating petroleum contaminants in groundwater at the site. Groundwater
samples from the semi-annual monitoring events should be analyzed for VOCs and sulfate to
evaluate the distribution and release of the CRP Persulfate. The next quarterly event should be
conducted in June 2022 and the next semi-annual event should be conducted in September
2023. The future events would be performed by other NCDEQ contractors.
n Raise the manway for MW-1 to the existing land grade to ensure continued integrity of the
well.
n After collection and assessment of this additional data, NCDEQ should consider whether to:
o perform additional monitoring without further active remediation,
o perform an additional RemRx™ injection event, and/or
o perform an air sparging pilot test to evaluate the potential use of physical removal
methods (i.e., the low pH conditions at the site could cause in-situ bioremediation
approaches to have limited successes).
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
Explore with us 13
F.REFERENCES
Armstrong Geological & Engineering Services, P.C., 2001. Soil Assessment Report, Blalock’s
Fina, NC Highway 55 (Route 2) Angier, North Carolina. May 31.
Force Environmental Service Company, LLC, 2011. Blalock’s Fina, 3574 Hwy 55, Angier, NC
Incident #24238. October 9.
Interstate Technology Regulatory Council (ITRC), 2007. Interstate Technology Regulatory
Council Vapor Intrusion Pathway: A Practical Guidance. January.
ITRC, 2014. Petroleum Vapor Intrusion, Fundamentals of Screening, Investigation, and
Management. October.
North Carolina Department of Environmental Quality – Division of Waste Management (NCDEQ
DWM), 2018. NCDEQ Division of Waste Management Vapor Intrusion Guidance. March
2018.
Progress Environmental, Inc., 2013. Subsequent Remediation Monitoring Report, Former
Blalock’s Fina, 3574 NC Highway 55, Angier, Harnett County, North Carolina. March.
Schnabel Engineering, 2010. Revised Conceptual Corrective Action Plan, Blalock’s Fina,
NCDNER Incident #TF-24238, Angier, North Carolina. December.
Terracon Consultants, Inc. (Terracon), 2014. Federal/State Lead Monitoring Report, Blalock
Fina, 3574 NC Highway 55, Angier, Harnett County, North Carolina. December.
Terracon, 2015a. Federal/State Lead Monitoring Report, Blalock Fina, 3574 NC Highway 55,
Angier, Harnett County, North Carolina. April.
Terracon, 2015b. New Technology Cleanup Report, Blalock Fina, 3574 NC Highway 55, Angier,
Harnett County, North Carolina. July.
Terracon, 2016. Subsequent Monitoring Report, Blalock Fina, 3574 NC Highway 55, Angier,
Harnett County, North Carolina. April 28.
Terracon, 2017a. Design Basis Memorandum, Blalock Fina, 3574 NC Highway 55, Angier,
Harnett County, North Carolina. February 20.
Terracon, 2017b. Subsequent Monitoring Report, Blalock Fina, 3574 NC Highway 55, Angier,
Harnett County, North Carolina. August 7.
Terracon, 2018. Subsequent Monitoring Report, Blalock Fina, 3574 NC Highway 55, Angier,
Harnett County, North Carolina. August 11.
Terracon, 2019. Subsequent Monitoring Report, Blalock Fina, 3574 NC Highway 55, Angier,
Harnett County, North Carolina. April 18.
Terracon, 2020. Subsequent Monitoring Report, Blalock Fina, 3574 NC Highway 55, Angier,
Harnett County, North Carolina. June 4.
Terracon, 2021. Annual Monitoring Report, Blalock Fina, 3574 NC Highway 55, Angier, Harnett
County, North Carolina. September 24.
Blalock Fina
Angier, North Carolina
Terracon Project No. 70149672B
Incident No. 24238
May 23, 2023
Explore with us 14
Terracon, 2022a. Injection Performance Monitoring Letter Report, Blalock Fina, 3574 NC
Highway 55, Angier, Harnett County, North Carolina. January 7.
Terracon, 2022b. Quarterly Injection Performance Monitoring Report, Blalock Fina, 3574 NC
Highway 55, Angier, Harnett County, North Carolina. April 15.
Terracon, 2022c. Quarterly Injection Performance Monitoring Letter Report, Blalock Fina, 3574
NC Highway 55, Angier, Harnett County, North Carolina. July 22.
Terracon, 2022d. Quarterly Injection Performance Monitoring Report, Blalock Fina, 3574 NC
Highway 55, Angier, Harnett County, North Carolina. October 25.
Withers and Ravenel (W&R), 2002. Assessment Letter/Report, Blalock’s Fina, Highway 55
(Route 2), Angier, Harnett County, North Carolina. July.
W&R, 2004. Additional Assessment /MMPE Report, Blalock’s Fina, Highway 55 (Route 2),
Angier, Harnett County, North Carolina. May.

FIGURES
Copyright:© 2013 National Geographic Society, i-cubed
Site
USGS TOPOGRAPHIC MAP
ANGIER, VA QUADRANGLE (2013)
0 2,000 4,000 6,000 8,000 10,0001,000 Feet
CONTOUR INTERVAL 10 FEET
File Path:
Date:
PM:
Drawn By:
Checked By:
Approved By:
Project No.
Scale:
70149672BECD
AIM
ECD
JLF 2401 Brentwood Drive, Suite 107 Raleigh, NC 27604
Phone: [phone] Fax: [phone]March 2023
Topographic Vicinity Map (March 2023)
³
Blalock Fina
(Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
Figure
1
1:24,000
@A
@A@A@A
@A
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@A
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@A@A
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@A
@A
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@?
&*
&*&*&*&*&*&*&*
&*&*&*&*&*&*
&*&*&*&*
NC OneMap, NC Center for Geographic Information and Analysis, NC 911
Board
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxSite Map FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
2 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
@A Monitoring Well
@?Vapor Extraction Well
&*Application Borings (August 2021)
Approximate On-Site Residence
Excavation Extent
Former Building
Site Boundary
Harnett County Parcel Boundary
Data Sources:Well Locations - TerraconSite Boundary - Harnett County GIS
Imagery - ESRI WMS³
^_
Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
MW-10
MW-1
MW-4
RW-1 MW-3
MW-7
VEW-1
VEW-2
MW-9
MW-11
MW-6
MW-8
Barry
Gregory
Residence
Beckwith
Residence
Grass
NC

H
i
g
h
w
a
y

5
5
MW-12
MW-5
RW-2
ED
ED
ED
ED
ED
EDED
ED
ED
ED
ED
ED
ED
ED
ED
ED
NC OneMap, NC Center for Geographic Information and Analysis, NC 911
Board
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxWater Supply Well Location Map FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
3 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
ED Water Supply Well (Active/Potable)
ED Water Supply Well (Active/Non-potable)
ED Water Supply Well (Inactive)
ED Water Supply Well (Unknown Use)
Surface Water
Site Boundary
Parcel Boundary
Data Sources:
Well Locations - Terracon
Site Boundary - Harnett County GIS
Imagery - ESRI WMS³
^_Blalock Fina
(Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 400 800200 Feet
1,000 ft
WSW-2
WSW-1
WSW-3
WSW-5
WSW-7
WSW-12
WSW-13
WSW-11
WSW-14
WSW-16
WSW-15
WSW-6
WSW-10
WSW-4
WSW-8
WSW-9
500 ft
1,500 ft
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NC OneMap, NC Center for Geographic Information and Analysis, NC 911
Board
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxGroundwater Elevation Map
(March 2023)FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
4 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
@?Vapor Extraction Well
@A Monitoring Well
Approximate On-Site Residence
Excavation Extent
Former Building
Site Boundary
Parcel Boundary
Notes:Arbitrary datum set at 100 ft on MW-1Data Sources:
Well Locations - Terracon
Site Boundary - Harnett County GIS
Imagery - ESRI WMS³
^_
Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
MW-10
95.14
MW-1
93.26
MW-4
92.47
RW-1
92.40
MW-3
92.36RW-2
92.19
MW-7
90.81
VEW-1
88.75
VEW-2
88.41MW-9
85.60
MW-11
84.24
MW-6
88.25
MW-8
86.47
Barry
Gregory
Residence
Beckwith
Residence
Grass
Grass
Woods
Woods
NC

H
i
g
h
w
a
y

5
5
9
4
.
0
0
90.00
88.00
Estimated Groundwater FlowDirection
Groundwater Elevation (ft)95.09
MW-12
93.46
92.
0
0
MW-5
91.59
86.00
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@? N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxGroundwater Analytical Results
(March 2023)FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
5 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
@?Vapor Extraction Well
@A Monitoring Well
Approximate On-Site Residence
Excavation Extent
Former Building
Site Boundary
Harnett Parcel Boundary
Data Sources:
Well Locations - Terracon
Site Boundary - Harnett County GIS
Imagery - ESRI WMS³
^_Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 50 10025 Feet
Notes:Concentrations are in micrograms per liter (µg/L).Concentrations in bold exceed NCDEQ 2L Standards.BRL: below laboratory reporting limit"J": Estimated result below laboratory reporting limit andabove method detection limit.
Barry
Gregory
Residence
Beckwith
Residence
Grass
Grass
Woods
Woods
NC

H
i
g
h
w
a
y

5
5
MW-4
BRL
VEW-1
Benzene - 139
Ethylbenzene - 899
Isopropylbenzene - 55.3
Methylene Chloride - 139
Naphthalene - 406
n-Propylbenzene - 152
Toluene - 891
1,3,5-Trimethylbenzene - 324
1,2,4-Trimethylbenzene - 1,220Total Xylenes - 1,979
MW-9
BRL
MW-6
Benzene - 1,100
Ethylbenzene - 253
Isopropylbenzene - 8.6
Methylene Chloride - 157
Naphthalene - 79.0
n-Propylbenzene - 21.7
Toluene - 787
1,3,5-Trimethylbenzene - 12.1
1,2,4-Trimethylbenzene - 50.8
Total Xylenes - 181.6
MW-11
Benzene - 30.5
Ethylbenzene - 8.9
Isopropylbenzene - 3.2
Naphthalene - 9
n-Propylbenzene - 1.8
Toluene - 0.82
VEW-2BRL
MW-8
Isopropylbenzene - 0.64
Naphthalene - 1.2 J
RW-2
Benzene - 170
Ethylbenzene - 558
Isopropylbenzene - 21.6
Methylene Chloride - 236
Naphthalene - 187
n-Propylbenzene - 51.4
Toluene - 2,470
1,3,5-Trimethylbenzene - 138
1,2,4-Trimethylbenzene - 523
Total Xylenes - 2,910
MW-12
BRL
MW-3Benzene - 468Ethylbenzene - 2,610
Isopropylbenzene - 87.9
Naphthalene - 728
n-Propylbenzene - 241
Styrene - 43.5
Toluene - 9,040
1,3,5-Trimethylbenzene - 620
1,2,4-Trimethylbenzene - 2,170
Total Xylenes - 11,060
RW-1
Benzene - 3.4
sec-Butylbenzene - 1.8
Ethylbenzene - 1.9
Isopropylbenzene - 0.47 J
Naphthalene - 2.0 J
n-Propylbenzene - 1.86
Toluene - 4.8
1,3,5-Trimethylbenzene - 0.53
1,2,4-Trimethylbenzene - 1.9
Total Xylenes - 9.2
MW-10
BRL
MW-1Benzene - 20.1Ethylbenzene - 251Isopropylbenzene - 19.6Methylene Chloride - 29.5Naphthalene - 103
n-Propylbenzene - 51.4
Toluene - 223
1,3,5-Trimethylbenzene - 63.2
1,2,4-Trimethylbenzene - 243
Total Xylenes - 518
MW-5
Benzene - 0.93
Ethylbenzene - 45.9
Isopropylbenzene - 2.9
Naphthalene - 11.8
n-Propylbenzene - 7.8
Toluene - 32.2
1,2,3-Trichloropropane - 0.51
1,3,5-Trimethylbenzene - 20.4
1,2,4-Trimethylbenzene - 28.8
Total Xylenes - 50.2
MW-7Ethylbenzene - 0.85Naphthalene - 1.1 J1,3,5-Trimethylbenzene - 3.21,2,4-Trimethylbenzene - 5.8Total Xylenes - 6.7
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170
MW-3
468
RW-1
3.4
MW-5
0.93
MW-1
20.1
MW-9
<0.50
MW-11
30.5 MW-8
<0.50
MW-6
1,100
MW-7
<0.50 MW-4
<0.50
MW-12
<0.50
MW-10
<0.50
VEW-1
139
VEW-2
<0.50
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxBenzene Isoconcentration Map
(March 2023)FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
6 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
Benzene Isoconcentration Contour (inferred)
Approximate On-Site Residence
Former Building
Site Boundary
Harnett County Parcel Boundary
@A Monitoring Well
@?Vapor Extraction Well
Data Sources:
Site Boundary - Harnett County GISImagery - NC Onemap
³
^_
Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
Notes:
"<": indicates less than laboratory reporting limitConcentrations are in micrograms per liter (µg/L)NCDEQ 2L standard for benzene is 1 µg/L.Concentrations in bold exceeed 2L Standard.*: RW-1 not used for contouring purposes.
Barry
Gregory
Residence
Beckwith
Residence
Grass
Grass
Cleared Land
Woods
NC

H
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5
5100 µg/L1.0 µg/L
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MW-6
79 RW-2
187
MW-3
728
MW-1
103
MW-9
<2.0
MW-11
9.0
MW-4
<2.0
MW-5
11.8
MW-12
<2.0
MW-10
<2.0
MW-8
1.2 J
MW-7
1.1 J
RW-1
2.0 J
VEW-1
406
VEW-2
<0.50
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxNaphthalene Isoconcentration Map
(March 2023)FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
7 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
Naphthalene Isoconcentration Contour (Inferred)
@?Vapor Extraction Well
@A Monitoring Well
Approximate On-Site Residence
Site Boundary
Former Building
Harnett County Parcel Boundary
Data Sources:
Site Boundary - Harnett County GISImagery - NC Onemap
³
^_
Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
Notes:
"<": indicates less than laboratory reporting limitConcentrations are in micrograms per liter (µg/L)NCDEQ 2L standard for naphthalene is 6 µg/L.Concentrations in bold exceeed 2L Standard.*: RW-1 not used for contouring purposes.
Barry
Gregory
Residence
Beckwith
Residence
Grass
Grass
Cleared Land
Woods
NC

H
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h
w
a
y

5
5
60 µg/L
6 µg/L
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MW-6
787
RW-1
4.8
MW-1
223
MW-5
32.2
MW-9
<0.50
MW-11
0.82 MW-8
<0.50
MW-7
<0.50
MW-4
<0.50
RW-2
2,470
MW-3
9,040
MW-12
<0.50
MW-10
<0.50
VEW-1
891
VEW-2
<0.50
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxToluene Isoconcentration Map
(March 2023)FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
8 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
Toluene Isoconcentration Contour (inferred)@?Vapor Extraction Well
@A Monitoring Well
Approximate On-Site Residence
Site Boundary
Former Building
Harnett County Parcel Boundary
Data Sources:
Site Boundary - Harnett County GISImagery - NC Onemap
³
^_
Blalock Fina (Incident # 24238)3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
Notes:
"<": indicates less than laboratory reporting limitConcentrations are in micrograms per liter (µg/L)NCDEQ 2L standard for toluene is 600 µg/L.Concentrations in bold exceeed 2L Standard.*: RW-1 not used for contouring purposes.
Barry
Gregory
Residence
Beckwith
Residence
Grass
Grass
Cleared Land
Woods
NC

H
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5
5
600 µg/L
@A
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@?
MW-7
5.8
RW-2
523
RW-1
1.9
MW-1
243
MW-6
50.8
MW-5
28.8
MW-9
<0.50
MW-8
<0.50
MW-4
<0.50
MW-3
2,170
MW-12
<0.50
MW-10
<0.50
MW-11
<0.50
VEW-1
1,220
VEW-2
<0.50
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprx1,2,4-Trimethylbenzene Isoconcentration Map
(March 2023)
FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
9 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
1,2,4-Trimethylbenzene IsoconcentrationContour (Inferred)
Approximate On-Site Residence
Site Boundary
Former Building
Harnett County Parcel Boundary
@A Monitoring Well
@?Vapor Extraction Well
Data Sources:
Site Boundary - Harnett County GIS
Imagery - NC Onemap
³
^_
Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
Notes:
"<": indicates less than laboratory reporting limitConcentrations are in micrograms per liter (µg/L)NCDEQ 2L standard for 1,2,4-trimethybenzene is 400 µg/L.Concentrations in bold exceeed 2L Standard.*: RW-1 not used for contouring purposes.
Barry
Gregory
Residence
Beckwith
Residence
Grass
Grass
Cleared Land
Woods
NC

H
i
g
h
w
a
y

5
5
400 µg/L
@A
@A@A@A
@A
@A
@A
@A
@A@A
@A
@A
@A
@?
@?
MW-7
6.7
RW-1
9.2
MW-1
518
MW-9
<1.0
MW-8
<1.0
MW-4
<1.0
MW-5
50.2
MW-12
<1.0
MW-10
<1.0
MW-11
<1.0
MW-6
181.6 RW-2
2,910
MW-3
11,060
VEW-1
1,979
VEW-2
<0.50
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxTotal Xylenes Isoconcentration Map
(March 2023)FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
10 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
Total Xylenes Isoconcentration Contour
(inferred)
@A Monitoring Well
@?Vapor Extraction Well
Approximate On-Site Residence
Site Boundary
Former Building
Harnett County Parcel Boundary
Data Sources:Site Boundary - Harnett County GIS
Imagery - NC Onemap
³
^_
Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
Notes:
"<": indicates less than laboratory reporting limitConcentrations are in micrograms per liter (µg/L)NCDEQ 2L standard for xylenes is 500 µg/L.Concentrations in bold exceeed 2L Standard.*: RW-1 not used for contouring purposes.
Barry
Gregory
Residence
Beckwith
Residence
Grass
Grass
Cleared Land
Woods
NC

H
i
g
h
w
a
y

5
5
500 µg/L
#V
#VSG-01
SG-02
NC OneMap, NC Center for Geographic Information and Analysis, NC 911
Board
N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxSoil Gas Sample Location Map FigureProject No.
Reviewed By:
Date:
Drawn By:
70149672B
AIM
JLF
March 2023
2401 Brentwood Rd.Raleigh, NC 27604
PH. [phone] terracon.com
11 N:\GIS\2014\70149672B - Blalock Fina\70149672B - ArcPro\70149672B - ArcPro\70149672B - ArcPro.aprxLegend
#V Soil Gas Points (March 2023)
Approximate On-Site Residence
Excavation Extent
Former Building
Site Boundary
Harnett County Parcel Boundary
Data Sources:Well Locations - TerraconSite Boundary - Harnett County GIS
Imagery - ESRI WMS³
^_Blalock Fina (Incident # 24238)
3574 NC Highway 55
Angier, Harnett County, North Carolina
0 40 8020 Feet
Barry
Gregory
Residence
Beckwith
Residence
Grass
NC

H
i
g
h
w
a
y

5
5

TABLES
Two 1,000-gallon gas USTs and one 550-gallon gas UST (removed 2001)
Information not available
Information not available
NA
Coastal Plain
Residual Impacts
Extent
Contaminants of Concern
Concentrations
Soil Type Sand
Residual Impacts Yes
Extent Vicinity of UST excavation
Contaminants of Concern Gasoline compounds
Concentrations Above soil-to-groundwater MSCCs but below residential MSCCs
Soil Type Primarily sand to clayey sands
Source to GW?Yes
NAPL Present? Residual or Mobile?Free product not detected in monitoring wells since 2012
Depth to Groundwater Approximately 2 to 10 feet below land surface
Hydraulic Conductivity Site specific not evaluated, ~10-3 to 101 feet per day based on soil type
Delineated? If so, extent?Not delineated to east
Extend Off-Site?Extends off-site to southwest under NC Highway 55
Contaminants of Concern BTEX and other gasoline compounds
Concentrations Greater than 10x 2L Standard in several monitoring wells but below GCLs since 2018
Trends Generally stable
Horizontal Gradient Approximately 0.04-0.07 ft/ft
Vertical Gradient Unknown
Depth to Groundwater
Delineated? If so, extent?
Extends Off-Site?
Hydraulic Conductivity
Contaminants of Concern
Concentrations
Trends
Horizontal Gradient
Approximately 150 feet southwest (an unnamed pond)
VOC compounds not detected in sample from pond (2018)
Below laboratory reporting limits
NA
Lateral Distance from Impacts to Building ~110 feet southwest to off-site residence (site not developed)
Depth to GW Approximately 2 to 10 feet below land surface
Precluding Factors Present? Specify.Historical 1,2-DCA and EDB detections (lead scavenger)
GW Concentrations > VISLs?Yes
Exterior Soil Gas Concentrations >VISLs?No
Sub-Slab Concentrations > VISLs?Not Sampled
Indoor Air Concentrations > VISLs?Not Sampled
Is the VI Pathway Complete?No
1,224 tons of impacted soil excavated during UST removal in 2001,subsequent soil sampling
indicates residual soil impacts in vadose zone below residential MSCCs
1) MMPE event in 2004
2) Injection of oxidation and oxygen releasing compound in 2011. Post-injection
concentrations generally lower, but several well exhibit increased concentrations and/or
mobilization of NAPL.
3) Application of controlled release polymer persulfate and instantaneous release persulfate in
18 on-site borings (August 2021)
Number within 250 feet None identified
Number within 250-500 feet 1 non-potable (WSW-6) and 1 inactive (WSW-10)
Number within 500-1,000 feet 11 (2 inactive, 2 non-potable, 7 potable)
Not Evaluated
Future structures (site not developed), structures <100 ft from impacts
Vacant; residence being constructed by owner
Concentrations below Residential MSCCs - close without soil use restriction
NAPL and/or >GCLs GCL exceedance in MW-5 (2018)
Water Supply Wells Use restricted on-site through NRP
Topographically down-gradient pond - detections not reported January 2018
Does not appear to be a concern based on exterior soil gas data collected on March 31, 2023.
Notes:
MSCC: NCDEQ maximum soil contaminant concentrations UST: underground storage tank
2L Standard: 15A NCAC 2L groundwater quality standards NA: not applicable
GCL: NCDEQ gross contamination levels GW: groundwater
VISL: NCDEQ vapor intrusion screening levels BTEX: benzene, toluene, ethylbenzene, xylenes
NAPL: non-aqueous phase liquid MMPE: mobile multiphase extraction
VI: Vapor Intrusion UST: underground storage tank
MSCC: NCDEQ maximum soil contaminant concentrations NA: not applicable
2L Standard: 15A NCAC 2L groundwater quality standards GW: groundwater
GCL: NCDEQ gross contamination levels VOC: volatile organic compound
VISL: NCDEQ vapor intrusion screening levels BTEX: benzene, toluene, ethylbenzene, xylenes
NAPL: non-aqueous phase liquid DCA: dichloroethane
NCDEQ UST Guidance: NCDEQ UST Section Guidelines for Assessment VI: Vapor Intrusion
and Corrective Action for UST Releases
Table 1
Conceptual Site Model
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Project Number: 70149672B
Not Sampled
SubsurfaceSurface Water
Vapor Intrusion
Vapor Intrusion (Modeling/Screening or Empirical)
Current/Proposed Property Use
Soil (Type, When, Successful?)SurficialNot Sampled
BedrockGroundwater or Surficial Source?
Groundwater (Type, When, Successful?)Soil VaporScreeningAssessmentOther
SoilPhysiographic Province
SurficialGroundwaterSource
Areas
UST(s)
Dispensers
Piping
SurfaceWaterDistance from Source
Contaminants of Concern
Concentrations
RemediationReceptorsWSWsSurface Water (Modeling/Screening or Empirical)Closure PathwaySoil
GW
Table 2
Water Supply Well Information
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Project Number: 70149672B
WSW-1 Alfred and Linda Champion
Family Trust
88 Colby Lane
Angier, NC 27501
88 Colby Lane
Angier, NC 27501 780 feet / north Active / Potable 0692-03-7390.000
WSW-2 Arnold and Dawn Champion 126 Colby Lane
Angier, NC 27501
3878 NC 55 West
Angier, NC 27501 945 feet / north Active / Potable 0692-03-3402.000
WSW-3 Randy Wayne Yost 3605 Old Stage Road
Angier, NC 27501
3605 Old Stage Road
Angier, NC 27501 835 feet / northeast Active / Potable 0692-12-6945.000
WSW-4 William Patrick Smith II 62 Dark Forest Drive
Chapel Hill, NC 27516
3515 Old Stage Road North
Angier, NC 27501 1,000 feet / east Unknown 0692-12-8531.000
WSW-5 Randy K. and Linda C. McGee 3478 NC Highway 55 West
Angier, NC 27501
3478 NC Highway 55 West
Angier, NC 27501 625 feet / east Active / Potable 0692-12-3457.000
WSW-6 Harold L. and Ann S. Moore 3522 NC Highway 55 West
Angier, NC 27501
3498 NC Highway 55 West
Angier, NC 27501 410 feet / east Active / Non-potable 0692-12-1398.000
WSW-7 Cesareo Garcia Sanchez &
Juan Cordova Eugenia
3489 Old Stage Road North
Angier, NC 27501
3489 Old Stage Road North
Angier, NC 27501 840 feet / southeast Active / Potable 0692-12-6139.000
WSW-8 Christopher W. Taylor PO Box 2690
Lillington, NC 27546
3386 NC Highway 55 West
Angier, NC 27501 950 feet / southeast Unknown; property connected to municipal water 0692-12-6081.000
WSW-9 John Burnett P.O. Box 322
Holly Springs, NC 27540
3393 Old Stage Road North
Angier, NC 27501 1,100 feet / southeast Active / Non-potable 0692-11-7993.000
WSW-10 Christopher Thomas Moss 3535 NC Highway 55 West
Angier, NC 27501
3535 NC Highway 55 West
Angier, NC 27501 275 feet / south Inactive 0692-02-9241.000
WSW-11 Andrew M. Roach 2104 Bull Run Drive
Apex, NC 27539
136 Old Stage Court
Coats, NC 27521 1,050 feet / south Active / Potable 0692-11-1653.000
WSW-12 Nicholes L. and Jennice R. West 2729 Old Stage Court
Coats, NC 27521
145 Old Stage Court
Coats, NC 27521 780 feet / south Active / Potable 0692-01-9706.000
WSW-13 Roger Hutchinson & Natividad
Hutchinson
137 Old Stage Court
Coats, NC 27521
137 Old Stage Court
Coats, NC 27521 870 feet / south Active / Potable 0692-01-8696.000
WSW-14 Jerry J. Lambert 303 N. Lincoln St
Benson, NC 27504
123 Old Stage Court
Coats, NC 27521 1,040 feet / south Active / Potable 0692-01-9505.000
WSW-15 James Douglas Johnson, Jr.46 Creature Meadow Lane
Angier, NC 27501
46 Creature Meadow Lane
Angier, NC 27501 510 feet / southwest Active / Non-potable 0692-02-2306.000
WSW-16 Thomas N. Taylor 309 Head Street
Paris, TN 38242
3713 NC Highway 55 West
Angier, NC 27501 790 feet / northwest Active / Non-potable 0692-03-0008.000
WSW-17 Lyndon L. and Sherri Sargent 201 Pointer Creek Drive
Angier, NC 27501
201 Pointer Creek Drive
Angier, NC 27501 1,260 feet / west Active / Potable 0682-92-9336.000
WSW-18 Margaret Bennett and Lewis Lowe 172 Doug Johnson Lane
Angier, NC 27501
172 Doug Johnson Lane
Angier, NC 27501 1,370 feet / north Active / Potable 0692-03-6829.000
WSW-19 Eduado Julio Ruiz c/o Lucio Ruiz 222 Doug Johnson Lane
Angier, NC 27501
222 Doug Johnson Lane
Angier, NC 27501 1,380 feet / north Active / Potable 0692-03-8922.000
WSW-20 Wallace Roy Walden PO Box 831
Angier, NC 27501
150 Doug Johnson Lane
Angier, NC 27501 1,360 feet / north Active / Potable 0692-03-4895.000
WSW-21 Lynn P. Walden PO Box 831
Angier, NC 27501
124 Doug Johnson Lane
Angier, NC 27501 1,370 feet / north Active / Potable 0692-03-3777.000
WSW-22 Joyce P. Carter 3446 Old Stage Road North
Angier, NC 27501
3421 Old Stage Road North
Angier, NC 27501 1,130 feet / southeast Active / Non-potable 0692-12-8126.000
WSW-23 Dominic D. Cannavaro and
Helen B. Stewart
1510 Ridge Road
Raleigh, NC 27607
207 Colby Lane
Angier, NC 27501 1,200 feet / north Active / Potable 0692-03-6740.000
WSW-24 Dominic D. Cannavaro and
Helen B. Stewart
1510 Ridge Road
Raleigh, NC 27607
235 Colby Lane
Angier, NC 27501 1,220 feet / north Active / Potable 0692-03-8655.000
WSW-25 Dominic D. Cannavaro and
Helen B. Stewart
1510 Ridge Road
Raleigh, NC 27607
263 Colby Lane
Angier, NC 27501 1,240 feet / north Active / Potable 0692-13-0618.000
WSW-26 Paul Ray Santanio 240 Doug Johnson Lane
Angier 27501
240 Doug Johnson Lane
Angier 27501 1,410 feet / north Active / Potable 0692-03-9984.000
WSW-27 Anna Maria Smith PO Box 1404
Angier, NC 27501
3271 Old Stage Road North
Coats, NC 27521 1,380 feet / southeast Active / Potable 0692-11-4421.000
WSW-28 Robert E. and April R. Wronski 3304 Old Stage Road North
Coats, NC 27521
3304 Old Stage Road North
Coats, NC 27521 1,480 feet / southeast Active / Potable 0692-11-8442.000
WSW-29 Michelle Turner 3243 Old Stage Road North
Coats, NC 27521
3243 Old Stage Road North
Coats, NC 27521 1,480 feet / southeast Active / Potable 0692-11-3380.000
WSW-30 Joseph Roberts PO Box 422
Coats, NC 27521
3305 Old Stage Road North
Coats, NC 27521 1,280 feet / southest Active / Potable 0692-11-4771.000
WSW-31 Paul William Suksi 63 Old Stage Court
Coats, NC 27521
63 Old Stage Court
Coats, NC 27521 1,350 feet / south Active / Non-potable 0692-11-0145.000
WSW-32 Dana L. Green 75 Old Stage CourtCoats, NC 27521 75 Old Stage CourtCoats, NC 27521 1,250 feet / south Active / Non-potable 0692-01-9261.000
WSW-33 Elsie Kay Capps 78 Old Stage Court
Coats, NC 27521
78 Old Stage Court
Coats, NC 27521 1,290 feet / south Active / Non-potable 0692-11-1365.000
WSW-34 Daniel and Debora Lopez 89 Old Stage Court
Coats, NC 27512
89 Old Stage Court
Coats, NC 27512 1,230 feet / south Active / Potable 0692-01-9322.000
WSW-35 Linwood and Ina Marie Jones 105 Old Stage Court
Coats, NC 27521
105 Old Stage Court
Coats, NC 27521 1,050 feet / south Active / Potable 0692-01-9414.000
WSW-36 Brnell and Dennis McNeill 106 Old Stage Court
Coats, NC 27521
106 Old Stage Court
Coats, NC 27521 1,130 feet / south Active / Non-potable 0692-11-1449.000
WSW-37 Bobby Lee Stone 3270 Old Stage Road NorthCoats, NC 27521 3270 Old Stage Road NorthCoats, NC 27521 1,480 feet / southeast Active / Potable 0692-11-7255.000
WSW-38 Rosalio L. and Heather M. Calderon 3288 Old Stage Road North
Coats, NC 27521
3288 Old Stage Road North
Coats, NC 27521 1,470 feet / southeast Active / Potable 0692-11-7392.000
Well Status/Use Parcel IDWell No.Property Owner Mailing Address Property Address Distance/Direction from
source area
Page 1 of 1
Table 3
Monitoring Well Construction Information and Historical Groundwater Elevations
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Project Number: 70149672B
Well ID Date Water Level
Measured
Well Casing Depth
(ft. BGS)
Screened Interval
(x to y ft. BGS)Bottom of Well4
(ft. BGS)
Top of Casing
Elevation (ft.)
Depth to Water
from Top of
Casing (ft.)
Free Product
Thickness (ft.)
Groundwater
Elevation (ft.)Comments
11/05/14 6.87 --93.1302/11/15 4.59 --95.41
02/10/16 3.20 --96.80
06/28/17 7.11 --92.8901/16/18 9.67 --90.33
03/04/19 2.91 --97.09
10/18/19 8.99 --91.0105/04/20 6.08 --93.92
08/04/21 6.20 --93.8011/10/21 9.20 --90.8002/09/22 7.73 --92.27
05/25/22 6.69 --93.3109/07/22 8.98 --91.0203/30/23 6.74 --93.26
11/05/14 5.95 --92.61
02/11/15 4.04 --94.5202/10/16 3.13 --95.43
06/28/17 5.99 --92.5701/16/18 8.49 --90.0703/04/19 3.06 --95.50
10/18/19 7.57 --90.9905/04/20 5.53 --93.0307/14/21 7.30 --91.26
11/10/21 8.30 --90.2602/09/22 7.07 --91.49
05/25/22 6.18 --92.38
09/07/22 8.23 --90.3303/30/23 6.20 --92.36
11/05/14 7.50 --92.09
02/11/15 5.16 --94.4302/10/16 3.89 --95.7006/29/17 7.31 --92.28
01/15/18 10.26 --89.3303/04/19 3.15 --96.44
10/18/19 9.02 --90.57
05/04/20 6.85 --92.7408/04/21 6.65 --92.94
11/10/21 10.00 --89.59
02/09/22 8.55 --91.0405/25/22 6.93 --92.66
09/07/22 9.72 --89.87
03/30/23 7.12 --92.4711/05/14 7.20 --90.50
02/11/15 5.04 --92.66
02/10/16 4.27 --93.4306/29/17 6.44 --91.26
01/15/18 9.08 --88.62
03/04/19 4.12 --93.5810/18/19 7.85 --89.85
05/04/20 6.19 --91.5107/14/21 6.00 --91.7011/10/21 9.00 --88.70
02/09/22 7.34 --90.3605/25/22 5.98 --91.72
09/07/22 8.64 --89.06
03/30/23 6.11 --91.59
11/05/14 5.58 --87.6102/11/15 4.83 --88.36
02/10/16 4.02 --89.1706/28/17 5.12 --88.0701/15/16 6.21 --86.98
03/04/19 3.82 --89.3710/23/19 5.76 --87.43
05/04/20 4.90 --88.29
07/14/21 5.93 --87.2611/11/21 6.55 --86.64
02/09/22 5.27 --87.92
05/25/22 4.67 --88.5209/07/22 6.25 --86.94
03/31/23 4.94 --88.25
11/05/14 7.12 --90.4402/11/15 5.34 --92.22
02/10/16 4.77 --92.79
06/29/17 6.69 --90.8701/15/18 9.21 --88.35
03/04/19 4.16 --93.40
10/18/19 7.69 --89.8705/04/20 6.33 --91.23
07/14/21 6.75 --90.8111/10/21 9.10 --88.4602/09/22 7.80 --89.76
05/25/22 5.41 --92.1509/07/22 8.75 --88.8103/30/23 6.75 --90.81
11/05/14 7.65 --86.12
02/11/15 7.26 --86.5102/10/16 4.76 --89.01
06/28/17 7.53 --86.2401/15/18 8.03 --85.7403/04/19 4.91 --88.86
10/23/19 7.59 --86.1805/04/20 7.33 --86.4407/14/21 7.25 --86.52
11/11/21 8.90 --84.8702/09/22 7.30 --86.47
05/25/22 6.95 --86.82
09/07/22 8.69 --85.0803/31/23 7.30 --86.47
Notes:
1. "-" indicates measureable amounts of free product were not detected2. Bottom of well measurements are approximate and based off of field measurements; exact well construction data is unknown3. BGS = below ground surface
4. Elevation is based on arbitrary datum set at 100.00 feet on the top-of-casing of MW-1.
2.5-12.5 13.0 97.70
MW-7 4.0 4-11 11.0 97.56
100.00 2-inchType II
98.56 2-inchType II
99.59 2-inchType II
MW-1 8.0 8-18.5 18.0
MW-3 8.0 8-18 18.0
93.77 2-inchType II
MW-4 8.5 8.5-18 18.0
2-inchType II
2-inch
Type II
MW-6 5.0 5-10 11.0 93.19 2-inch
Type II
MW-5 2.5
MW-8 4.0 4-12 13.0
Page 1 of 2
Table 3
Monitoring Well Construction Information and Historical Groundwater Elevations
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Project Number: 70149672B
Well ID Date Water LevelMeasured Well Casing Depth(ft. BGS)Screened Interval(x to y ft. BGS)Bottom of Well4
(ft. BGS)
Top of CasingElevation (ft.)
Depth to Waterfrom Top of
Casing (ft.)
Free ProductThickness (ft.)GroundwaterElevation (ft.)Comments
11/05/14 3.61 --86.54
02/11/15 3.27 --86.8802/10/16 2.70 --87.4506/28/17 3.36 --86.79
01/15/18 3.98 --86.1703/04/19 2.56 --87.59
10/23/19 3.25 --86.90
05/04/20 3.20 --86.9507/14/21 3.10 --87.05
11/10/21 4.30 --85.8502/09/22 3.33 --86.8205/25/22 2.84 --87.31
09/07/22 4.50 --85.65
03/31/23 4.55 --85.6003/04/19 3.54 --100.60
10/18/19 11.67 --92.47
08/04/21 9.02 --95.1211/10/21 12.3 --91.84
02/09/22 9.05 --95.0905/26/22 8.73 --95.4109/08/22 11.93 --92.21
03/30/23 9.00 --95.14
11/05/14 5.01 --83.7802/11/15 4.35 --84.44
02/10/16 3.46 --85.33
06/28/17 Not Found ----01/15/18 4.97 --83.82
03/04/19 3.64 --85.1510/23/19 4.61 --84.1805/04/20 4.33 --84.46
07/14/21 4.23 --84.5611/10/21 5.35 --83.4402/09/22 4.05 --84.74
05/25/22 4.22 --84.5709/07/22 4.92 --83.87
03/31/23 4.55 --84.24
10/23/19 8.09 --90.2505/04/20 4.13 --94.2107/14/21 4.95 --93.39
11/11/21 7.35 --90.9902/09/22 5.94 --92.4005/25/22 4.72 --93.62
09/07/22 7.11 --91.2303/30/23 4.88 --93.4611/05/14 5.69 --92.71
02/11/15 3.66 --94.7402/10/16 2.85 --95.5506/28/17 5.83 --92.57
01/16/18 8.41 --89.9903/04/19 2.70 --95.7010/18/19 7.44 --90.96
05/04/20 5.31 --93.0907/14/21 6.01 --92.39
11/10/21 8.30 --90.10
02/09/22 6.89 --91.5105/25/22 6.04 --92.36
09/07/22 8.15 --90.25
03/30/23 6.00 --92.4011/05/14 5.46 --92.4302/11/15 3.57 --94.32
02/10/16 2.75 --95.1406/28/17 5.41 --92.48
01/16/18 7.83 --90.06
03/04/19 2.71 --95.1810/18/19 6.95 --90.94
05/04/20 4.99 --92.90
07/14/21 5.75 --92.1411/10/21 7.80 --90.09
02/09/22 6.49 --91.4005/25/22 5.60 --92.2909/07/22 7.61 --90.28
03/30/23 5.70 --92.19
11/05/14 9.08 --88.1002/11/15 8.21 --88.97
02/10/16 7.38 --89.80
06/28/17 8.61 --88.5701/15/18 9.89 --87.29
03/04/19 7.36 --89.8210/23/19 9.04 --88.1405/04/20 8.40 --88.78
07/14/21 8.57 --88.6111/11/21 10.30 --86.88
02/09/22 8.82 --88.36
05/25/22 8.31 --88.8709/07/22 10.00 --87.18
03/31/23 8.43 --88.75
11/05/14 9.64 --87.7702/11/15 8.81 --88.6002/10/16 8.13 --89.28
06/28/17 9.17 --88.2401/15/18 10.38 --87.03
03/04/19 7.92 --89.49
10/23/19 9.29 --88.1205/04/20 8.88 --88.53
07/14/21 9.98 --87.43
11/10/21 10.60 --86.8102/09/22 9.39 --88.02
05/25/22 8.64 --88.7709/07/22 10.33 --87.0803/31/23 9.00 --88.41
Notes:
1. "-" indicates measureable amounts of free product were not detected2. Bottom of well measurements are approximate and based off of field measurements; exact well construction data is unknown
3. BGS = below ground surface
4. Elevation is based on arbitrary datum set at 100.00 feet on the top-of-casing of MW-1.
97.18 2-inch
Type II
VEW-2 8.0 8-18 18.0 97.41 2-inchType II
VEW-1 Unknown Unknown 18.0
98.40 2-inch
Type II
RW-2 5.0 5-10 10.0 97.89 2-inch
Type II
RW-1 5.0 5-10 10.0
2-inch
Type II
MW-12 4.0 4-14 14.0 98.34 2-inchType II
88.79
90.15 2-inchType II
MW-10 5.0 5-15 15.0 104.14 2-inch
Type II
2.0MW-9 2-7 7.0
MW-11 2.0 2-12 13.0
Page 2 of 2
Well ID Date Temperature
(°C)pH Conductivity
(μS/cm)
DO
(mg/L)
ORP
(mV)
Sulfate
(mg/L)
Total Iron
(mg/L)
Persulfate
(mg/L)
08/04/21 19.92 9.57 120 0.57 -103.1 ------
11/10/21 21.02 6.04 145 0.17 18.0 ------
02/09/22 17.83 5.98 225 0.53 -20.4 15.1 ----
05/25/22 18.37 5.94 148 1.69 -7.3 ------
09/08/22 22.21 6.54 121 6.25 9.4 18 ----
03/30/23 16.9 6.23 166 2.65 -127.9 24.1 ----
07/14/21 23.46 6.52 353 3.00 -281.3 ------
11/10/21 22.59 6.53 433 0.20 -36.5 56 0.33 ND
02/09/22 15.64 6.20 346 0.38 -37.9 37 ----
05/25/22 19.19 6.28 399 1.49 -51.1 ------
09/07/22 23.34 6.69 225 3.84 -41.1 17 ----
03/30/23 16.2 6.41 350 0.07 -150.7 39.4 ----
08/04/21 24.32 7.92 209 7.56 -34.4 ------
11/10/21 21.45 4.59 480 0.68 360.3 450 ND 256.52
02/09/22 16.00 4.78 1,263 1.95 253.1 440 ----
05/25/22 18.88 4.60 516 2.74 242.3 ------
09/07/22 22.93 5.09 588 NA 283.3 250 ----
03/30/23 16.9 4.58 800 2.39 257.9 261 ----
07/14/21 23.99 5.67 90 3.21 -274.5 ------
11/10/21 23.25 5.50 682 0.15 -77.5 900 102.48 176.91
02/09/22 13.85 4.95 300 3.31 213.9 127 ----
05/25/22 20.78 5.76 207 2.37 -0.2 ------
09/08/22 25.83 5.09 76 2.31 217.8 23 ----
03/30/23 16.1 4.60 91 3.95 207.2 29.7 ----
07/14/21 24.11 6.29 64 1.91 137.4 ------
11/11/21 20.97 6.20 362 0.31 -63.1 135 9.68 34.7
02/10/22 14.25 5.27 94 1.71 163.0 30.7 ----
05/25/22 19.33 5.12 45 5.21 142.9 ------
09/08/22 23.61 5.89 38 NA 73.7 7.5 ----
03/31/23 15.2 5.87 147 0.84 -63.2 26.9 ----
07/14/21 22.53 4.74 58 4.62 -240.6 ------
11/10/21 22.33 4.97 46 2.30 136.0 ------
02/09/22 13.71 4.99 45 3.06 203.9 6.9 ----
05/25/22 21.02 4.62 35 6.38 187.6 ------
09/08/22 24.31 4.63 36 7.01 260.0 6.5 ----
03/30/23 15.5 4.81 43 2.26 195.4 8.3 ----
07/14/21 21.78 7.04 218 0.76 131.0 ------
11/11/21 19.46 5.34 182 4.93 160.8 65 0.92 1.33
02/10/22 15.11 5.53 184 2.56 151.2 55.7 ----
05/25/22 17.85 5.41 144 2.36 100.8 ------
09/08/22 22.37 5.41 162 NA 223.5 62 ----
03/31/23 15.0 5.01 155 2.26 207.9 51.3 ----
07/14/21 22.30 6.08 42 1.87 139.3 ------
11/11/21 19.29 4.99 33 1.97 198.8 ------
02/10/22 13.54 5.06 39 4.90 163.8 4.54 ----
05/25/22 19.52 4.74 45 4.74 198.1 ------
09/08/22 22.93 4.91 49 NA 171.7 9.9 ----
03/31/23 15.3 4.92 41 0.15 117.5 5.7 ----
08/04/21 22.05 8.45 25 4.95 -52.6 ------
11/10/21 21.25 5.43 39 0.71 163.7 6 8.4 16.77
02/09/22 16.64 5.90 89 6.13 135.4 3.93 ----
05/26/22 19.79 4.84 33 4.42 158.7 ------
09/08/22 22.83 5.01 31 5.04 229.3 3.3 ----
03/30/23 17.7 4.95 38 9.06 135.2 5.0 ----
07/14/21 21.55 6.61 105 2.12 135.2 ------
11/11/21 20.55 5.95 326 0.29 10.1 ------
02/10/22 16.05 5.75 120 3.61 147.8 23.6 ----
05/25/22 17.99 5.46 136 1.64 135.9 ------
09/08/22 23.38 5.83 149 NA 107.6 35 ----
03/31/23 14.8 5.82 188 1.28 49.6 39.5 ----
07/14/21 23.60 4.54 48 7.29 -182.9 ------
11/10/21 22.70 4.70 39 4.82 267.7 ------
02/09/22 15.12 5.16 32 7.58 168.5 3.78 ----
05/25/22 19.44 4.47 29 7.78 202.8 ------
09/07/22 25.66 4.20 34 7.13 287.3 3.3 ----
03/31/23 16.0 4.53 34 7.10 283.2 3.6 ----
Notes:
°C - degrees Celsius. μS/cm - microSiemens per centimeter.
mV - millivolts.DO - dissolved oxygen.
mg/L - milligrams per liter.ND - Non-detect
ORP - oxidation-reduction potential.-- : Not analyzed
November 11, 2021 sulfate, total iron, and persulfate concentrations analyzed via colorimetric/spectrophotometric methods.
Sulfate concentrations for other events analyzed via USEPA Method 9056A.
NA: Data not included due to erroneous readings from malfunctioning probe.
MW-3
MW-1
MW-12
MW-11
MW-10
MW-9
Table 4
Field Groundwater Quality Measurements and Injectant Indicator Analytical Results
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Project Number: 70149672B
MW-8
MW-7
MW-6
MW-5
MW-4
Page 1 of 2
Well ID Date Temperature
(°C)pH Conductivity
(μS/cm)
DO
(mg/L)
ORP
(mV)
Sulfate
(mg/L)
Total Iron
(mg/L)
Persulfate
(mg/L)
Table 4
Field Groundwater Quality Measurements and Injectant Indicator Analytical Results
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Project Number: 70149672B
07/14/21 22.58 6.20 537 2.86 -265.3 ------
11/10/21 23.26 6.18 305 0.56 -31.6 10 8.25 10.99
02/09/22 14.67 6.17 878 0.46 -11.7 260 ----
05/25/22 19.09 6.05 1085 1.73 -29.8 ------
09/07/22 27.73 6.22 1031 3.54 -34.4 380 ----
03/30/23 16.1 6.13 602 0.17 -70.9 163 ----
07/14/21 24.45 5.97 114 2.80 -281.2 ------
11/10/21 22.27 5.94 149 0.12 -47.4 ------
02/09/22 13.86 5.73 140 0.69 49.1 28.2 ----
05/25/22 21.07 6.01 313 4.70 -45.5 ------
09/07/22 26.40 6.02 99 1.26 -57.8 4.6 ----
03/30/23 16.1 6.05 169 1.14 -141.3 8.2 ----
07/14/21 22.81 7.39 587 0.59 -86.2 ------
11/11/21 21.89 6.50 415 0.52 -59.1 1 0.222 3.29
02/10/22 15.27 6.43 460 0.81 25.1 1.44 ----
05/25/22 19.55 6.21 330 0.40 -64.4 ------
09/08/22 23.63 6.67 51 NA 4.1 4.1 ----
03/31/23 16.2 6.39 240 0.70 -96.1 0.68 J ----
07/14/21 22.41 6.22 109 2.26 127.0 ------
11/11/21 22.44 5.24 86 1.48 161.2 26 ND ND
02/10/22 17.39 5.02 120 3.21 169.0 29 ----
05/25/22 19.89 4.97 120 2.80 164.1 ------
09/08/22 24.17 4.84 57 NA 258.6 15 ----
03/31/23 16.6 4.73 130 8.09 259.5 19.6 ----
22.79 6.61 178.60 3.09 -75.48 ------
21.65 5.61 248.13 1.28 77.43 183.22 18.61 71.50
15.26 5.53 289.00 2.73 118.25 71.13 ----
19.45 5.37 239.00 3.36 88.99 ------
24.09 5.54 183.13 4.55 132.87 55.95 ----
16.04 5.40 212.93 2.81 70.89 45.73 ----
Notes:
°C - degrees Celsius. μS/cm - microSiemens per centimeter.
mV - millivolts.DO - dissolved oxygen.
mg/L - milligrams per liter.ND - Non-detect
ORP - oxidation-reduction potential.-- : Not analyzed
J - estimated value below laboratory reporting limit and above method detection limit.
November 11, 2021 sulfate, total iron, and persulfate concentrations analyzed via colorimetric/spectrophotometric methods.
Sulfate concentrations for other events analyzed via USEPA Method 9056A.
NA: Data not included due to erroneous readings from malfunctioning probe.
Averages from March
2023
Averages from
September 2022
Averages from
November 2021
Averages from
February 2022
Averages from May
2022
VEW-2
VEW-1
Averages from July
and August 2021
RW-2
RW-1
Page 2 of 2
Table 5
Summary of Groundwater Analytical Results
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Pro Ject Number: 70149672B
Well/Sample
I.D.Date Collected (mm/dd/yy)tert-butylbenzene1,2,3-Trichloropropane6,000 1 4,000 70 70 70 3,000 70 3 0.02 0.4 0.4 70 600 70 25 20 400 6 70 70 0.2 600 0.005 400 400 500
600,000 5,000 4,000,000 5,900 8,800 14,750 NE 70,000 3,000 50 400 400 70,000 80,000 30,500 11,700 20,000 400,000 6,000 26,100 70,000 200 260,000 NE 24,100 28,500 50,000NE1.6 NE NE NE NE 1,800 0.81 52 0.18 2.2 NE 1,400 3.5 180 NE 450 760 4.6 490 1,900 3.2 3,800 4.5 35 50 77
01/10/12 --53.9 --ND ND --------ND ------208 34.0 ND ND --184 94 ND --571 --115 85.9 569
05/17/12 --9.6 --ND ND --------ND ------124 7.41 ND ND --107 20.8 ND --147 --41.5 172 33603/07/13 --375 --ND ND --------ND ------571 55.6 ND ND --313 104 6.8 --2,070 --561 1,570 4,820
11/05/14 --5.7 --3.0 3.0 --------<0.50 <0.50 <0.50 <0.50 91.9 13.9 --<0.50 --96.1 28.4 <0.50 <0.50 32 --1.1 1 22
02/12/15 --71 --<2.5 3.0 --------<1.2 <1.2 <1.2 <1.2 288 29.7 --<1.2 --174 68.6 1.2 J <1.2 149 --51.8 242 600
06/28/17 --<0.50 --<0.50 <0.50 ----<0.50 --<0.50 <0.50 <0.50 <0.50 0.65 <0.50 <0.50 <0.50 --<0.50 0.46 J <0.50 <0.50 0.82 --<0.50 <0.50 <0.50
01/16/18 --0.98 --3.6 2.2 --0.42 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 84 9.2 0.88 <0.50 --53 15 <0.50 <0.50 79 --7.9 32 146
03/04/19 --13 --7.9 3.6 --<2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 220 14 <2.5 <2.5 --88 41 <2.5 <2.5 140 --11 66 187
10/18/19 --1.3 --3 2.4 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 72 7.9 0.77 <0.50 --42 9.1 <0.50 <0.50 25 --7.9 33 127
05/04/20 --65 --30 <2.5 --<2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 520 29 5.1 <2.5 --150 100 <2.5 <2.5 310 --89 250 500
08/04/21 --10 H --33 H 8.1 H --<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 470 28 H 6.0 H <5.0 --180 H 100 <5.0 <5.0 500 --150 H 500 H 1,090 H
02/09/22 --3.69 --2.9 4.04 0.199 J <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 122 13.3 1.72 <1.0 --111 21.5 <1.0 <1.0 42.5 --21.1 76.7 200.7
09/08/22 <10 15 <10 11 3.7 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 180 18 2.1 <0.50 <0.50 100 43 <0.50 <0.50 71 --39 150 280
03/30/23 --20.1 --<1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 251 19.6 --<1.0 29.5 103 51.4 <1.0 <1.0 223 <1.0 63.2 243 518
01/10/12 -5,950 -ND ND ----ND ---8,860 966 ND ND -4,500 3,900 ND -37,100 --8,470 25,300 49,700
05/17/12 -264 -15.2 ND ----ND ---375 23.9 ND ND -182 81.4 ND -4,160 --126 557 1,964
03/07/13 -1,670 -<50 <50 ----ND ---1,430 82.3 ND ND -805 225 33.4 -8,540 --810 2,980 13,050
02/12/15 -2,000 -<25 <25 ----<25 <25 <25 <25 2,370 84.5 -<25 -864 252 53.1 <25 17,800 --588 2,430 12,360
02/10/16 -1,800 -<100 <100 ----<100 <100 260 <100 1,900 74 J <100 <100 -690 240 <100 <100 15,000 --560 2,100 9,900
06/28/17 -1,800 -<100 <100 --<100 -<100 <100 <100 <100 2,700 93 J <100 <100 -810 280 <100 <100 20,000 --570 2,300 13,200
01/16/18 -1,200 -<25 <25 -<25 <25 <25 <25 <25 <25 <25 2,700 95 <25 <25 -740 340 150 <25 21,000 --700 2,600 12,400
03/04/19 -890 -<100 <100 -<100 <100 <100 <100 <100 <100 <100 2,400 83 J <100 <100 -650 260 <100 <100 16,000 --590 2,200 11,600
10/18/19 -820 -<100 <100 -<100 <100 <100 <100 <100 <100 <100 2,900 99 J <100 <100 -850 310 <100 <100 19,000 --680 2,500 12,300
05/04/20 -560 -<100 <100 -<100 <100 <100 <100 <100 <100 <100 2,600 85 J <100 <100 -630 280 <100 <100 19,000 --560 2,100 11,700
07/14/21 -260 -<50 <50 -<50 <50 <50 <50 <50 <50 <50 2,200 74 <50 <50 -580 220 <50 <50 11,000 --460 1,700 9,900
02/09/22 -476 -20.9 J 13.7 J <50 <250 <250 <125 <50 <50 <25 <50 2,690 82.9 6.11 J <50 -718 239 <50 <50 9,860 --532 2,010 11,030
09/07/22 <500 500 <500 62 <25 <25 <25 <25 <25 <25 <25 <25 <25 2,400 79 <25 <25 <25 770 230 <25 <25 6,900 --480 1,700 8,600
03/30/23 --468 --<25 <25 <25 <50 <25 <50 <25 <25 <25 <25 2,610 87.9 --<25 <100 728 241 43.5 <25 9,040 <25.0 620 2,170 11,060
03/07/13 --ND --ND ND --------ND ------ND ND ND ND --ND ND ND -0.32 J --ND 0.34 J 0.77 J
11/05/14 --<0.50 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 --<2.0 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
02/12/15 --<0.50 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 --<2.0 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
02/10/16 --<0.50 --0.41 J 0.2 J --------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 0.18 J <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
06/29/17 --<0.50 --<0.50 <0.50 ----<0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
01/15/18 --<0.50 --<0.50 <0.50 --<0.50 <0.50 0.79 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/04/19 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
05/04/20 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
08/04/21 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/09/22 --<1.0 --0.333 J 0.181 J <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 2.07 0.403 J <1.0 <1.0 --1.90 J 0.645 J <1.0 <1.0 1.42 --<1.0 <1.0 0.557 J
09/07/22 <10 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.5003/30/23 --<0.50 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <2.0 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
01/10/12 --2,850 --ND ND --------23.5 ------812 67.5 ND 9.9 --434 ND ND --7,990 --338 1,230 4,870
11/05/14 --829 --<25 <25 --------<25 <25 <25 <25 649 32.1 --<25 --289 106 <25 <25 4,820 --236 851 3,48002/12/15 --953 --<25 <25 --------<25 <25 <25 <25 1,060 49.3 --<25 --317 154 <25 <25 6,420 --279 1,090 5,350
02/10/16 --1,200 --<100 <100 --------<100 <100 <100 <100 1,200 57 J <100 <100 --340 170 <100 <100 9,000 --320 1,200 5,500
06/29/17 --5,300 --<10 11 --<10 <10 --<10 <10 <10 <10 1,700 63 <10 <10 --460 210 67 <10 12,000 --390 1,200 5,400
03/04/19 --600 --<50 <50 --<50 <50 <50 <50 <50 <50 <50 1,200 63 <50 <50 --350 200 <50 <50 3,900 --270 650 2,600
10/18/19 --640 --34 <25 --<25 <25 <25 <25 <25 <25 <25 1,100 41 <25 <25 --270 150 <25 <25 3,000 --150 270 1,050
05/04/20 --790 --<50 <50 --<50 <50 <50 <50 <50 <50 <50 1,400 57 <50 <50 --330 200 <50 <50 7,600 --290 810 2,580
07/14/21 --89 --<5.0 4.3 J --<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 290 19 <5.0 <5.0 --100 67 <5.0 <5.0 820 --120 230 410
02/09/22 --194 --2.85 1.98 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 158 8.12 1.02 <1.0 --50.9 23.7 <1.0 <1.0 231 --43.4 89 280.1
09/08/22 <50 34 <50 7.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 270 11 <2.5 <2.5 <2.5 87 30 2.4 J <2.5 350 --67 98 129
03/30/23 --0.93 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 45.9 2.9 --<0.50 <2.0 11.8 7.8 <0.50 <0.50 32.2 0.51 20.4 28.8 50.2
Notes:
Results in micrograms per liter (µg/L).NE - Not Established
Petroleum compounds detected in one or more samples are shown. J - estimated value below laboratory reporting limit and above method detection limit.
Gray shading denotes concentrations above 15A NCAC 2L groundwater standard (2L standard).H - Sample analyzed outside of holding time.
Yellow shading denotes concentrations above Gross Contamination Levels (GCLs).ND - Not detected
GW-VISL: NCDEQ DWM Groundwater Vapor Intrusion Screen Level, January 2023.'-' Indicates not analyzed or detected
Gross Contamination Level (GCL) (ug/L)
Residential GW-VISL (ug/L)
MW-1
MW-3
MW-4
MW-5
2L Standard (ug/L)Chloroformtrans-1,3-Dichloropropene1,2-Dibromoethane (EDB)1,2-DichloroethaneAnalytical Method VOCs via Method 6200B including MTBE, IPE, and EDB
Contaminant of Concern→Benzenen-Butylbenzenesec-ButylbenzeneChloromethanep-IsopropyltolueneMethyl tert-Butyl Ether(MTBE)Naphthalenen-PropylbenzeneChloroethaneXylenes, TotalStyrene1,1,2,2-Tetrachloroethane1,3,5-Trimethylbenzene2-Butanone (MEK) AcetoneMethylene ChlorideToluene1,2,4-TrimethylbenzeneDiisopropyl Ether (IPE)EthylbenzeneIsopropylbenzenePage 1 of 4
Table 5
Summary of Groundwater Analytical Results
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Pro Ject Number: 70149672B
Well/Sample
I.D.Date Collected (mm/dd/yy)tert-butylbenzene1,2,3-Trichloropropane6,000 1 4,000 70 70 70 3,000 70 3 0.02 0.4 0.4 70 600 70 25 20 400 6 70 70 0.2 600 0.005 400 400 500
600,000 5,000 4,000,000 5,900 8,800 14,750 NE 70,000 3,000 50 400 400 70,000 80,000 30,500 11,700 20,000 400,000 6,000 26,100 70,000 200 260,000 NE 24,100 28,500 50,000NE1.6 NE NE NE NE 1,800 0.81 52 0.18 2.2 NE 1,400 3.5 180 NE 450 760 4.6 490 1,900 3.2 3,800 4.5 35 50 77
Gross Contamination Level (GCL) (ug/L)
Residential GW-VISL (ug/L)
2L Standard (ug/L)Chloroformtrans-1,3-Dichloropropene1,2-Dibromoethane (EDB)1,2-DichloroethaneAnalytical Method VOCs via Method 6200B including MTBE, IPE, and EDB
Contaminant of Concern→Benzenen-Butylbenzenesec-ButylbenzeneChloromethanep-IsopropyltolueneMethyl tert-Butyl Ether(MTBE)Naphthalenen-PropylbenzeneChloroethaneXylenes, TotalStyrene1,1,2,2-Tetrachloroethane1,3,5-Trimethylbenzene2-Butanone (MEK) AcetoneMethylene ChlorideToluene1,2,4-TrimethylbenzeneDiisopropyl Ether (IPE)EthylbenzeneIsopropylbenzene01/10/12
05/17/12 --4,400 --ND ND --------ND ------2,210 116 ND ND --930 ND ND -11,800 --709 2,850 11,980
03/07/13 --2,820 --ND ND --------ND ------2,180 125 ND ND --848 ND 32.6 J -10,500 --814 3,040 13,160
02/11/15 --658 --<5.0 <5.0 --------2.8 J <5.0 <5.0 <5.0 163 6.0 --<5.0 --33.4 16.7 <5.0 <5.0 1,670 --30.1 120 792
02/10/16 --47 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 6.2 <0.50 <0.50 <0.50 --0.83 0.43 J <0.50 <0.50 67 --1.2 3.4 27.2
06/28/17 --820 --<5.0 <5.0 ----<5.0 --<5.0 <5.0 <5.0 <5.0 220 7.0 <5.0 <5.0 --49 19 <5.0 <5.0 730 --39 140 570
01/15/18 --380 --<2.5 <2.5 --<2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 79 2.8 <2.5 <2.5 --22 6.6 <2.5 <2.5 110 --20 63 181
03/04/19 --220 --<0.50 0.49 J --<0.50 <0.50 <0.50 <0.50 5.2 <0.50 <0.50 130 4.3 <0.50 <0.50 --33 13 <0.50 <0.50 280 --18 46 220
10/23/19 --65 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 22 0.65 <0.50 <0.50 --3.5 1.6 <0.50 <0.50 19 --1.3 3.3 17.7
05/04/20 --74 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 16 <0.50 <0.50 <0.50 --1.3 0.72 <0.50 <0.50 80 --1.2 4.2 29
07/14/21 --5.0 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 5.6 <0.50 <0.50 <0.50 --1.0 0.50 <0.50 <0.50 8.5 --0.63 2.0 9.9
02/10/22 --21.3 --<1.0 <1.0 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 5.3 0.142 J <1.0 <1.0 --<5.0 0.306 J <1.0 <1.0 7.03 --0.398 J 0.688 J 1.944 J
09/08/22 <10 24 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 7.4 0.57 <0.50 <0.50 <0.50 4.1 1.3 <0.50 <0.50 2.9 --<0.50 1.1 2.09
03/31/23 --1,100 --<5.0 <5.0 <5.0 <10 <5.0 <10 <5.0 <5.0 <5.0 <5.0 253 8.6 --<5.0 157 79.0 21.7 <5.0 <5.0 787 <5.0 12.1 50.8 181.6
01/10/12
05/17/12 --0.54 -ND ND ----ND ---5.7 0.87 ND ND -7.5 3.4 ND -10.3 --9.4 33.1 40
03/07/13 --ND -ND ND ----ND ---ND ND ND ND -ND ND ND -ND --ND 0.41 J ND11/06/14 --<0.50 -<0.50 <0.50 ----<0.50 <0.50 <0.50 <0.50 1.5 1.0 -<0.50 -1.0 J 1.5 <0.50 <0.50 0.46 J --7.5 20.9 <0.50
02/11/15 --<0.50 -<0.50 <0.50 ----<0.50 <0.50 <0.50 <0.50 7.0 2.7 -<0.50 -3.3 6.2 <0.50 <0.50 1.9 --22.5 58.9 32.0
02/10/16 --<0.50 -<0.50 0.53 ----<0.50 <0.50 <0.50 <0.50 4.6 2 <0.50 <0.50 -1.3 4.4 <0.50 <0.50 1.7 --16 35 21.906/27/17 --<0.50 -2.7 0.83 --0.50 -<0.50 <0.50 <0.50 <0.50 13 3.9 <0.50 <0.50 -5.3 11 <0.50 <0.50 1.5 --29 84 20.1
01/15/18 --<0.50 -1.5 0.42 J -<0.50 <0.50 0.41 J <0.50 <0.50 <0.50 <0.50 13 3.2 <0.50 <0.50 -8.2 8.9 <0.50 <0.50 3.3 --14 80 24.1
03/04/19 --<0.50 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -0.65 0.46 J <0.50 <0.50 <0.50 --1.6 3.8 0.71
10/18/19 --<0.50 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.59 <0.50 <0.50 <0.50 -<0.50 0.68 <0.50 <0.50 <0.50 --2.3 5 1.8
05/04/20 --<0.50 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.9 <0.50 <0.50 <0.50 -0.59 0.89 <0.50 <0.50 0.57 --2.6 5.7 9.6
07/14/21 --<0.50 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 2.5 0.80 <0.50 <0.50 -1.8 3.0 <0.50 <0.50 <0.50 --8.4 20 11.5
02/09/22 --0.271 J -0.856 J 0.538 J <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 15.9 3.04 0.278 J <1.0 -10.5 9.7 <1.0 <1.0 2.53 --20.6 62.8 67.7
09/08/22 <10 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.64 <0.50 <0.50 <0.50 <0.50 0.65 1.0 <0.50 <0.50 <0.50 --2.7 5.6 2.5
03/30/23 --<0.50 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 0.85 0.50 --<0.50 <2.0 1.1 J <0.50 <0.50 <0.50 <0.50 <0.50 3.2 5.8 6.7
01/10/12 -ND -ND ND ----ND ---ND ND ND ND -ND ND ND -ND --ND ND ND
05/17/12 -ND -ND ND ----ND ---ND ND ND ND -ND ND ND -ND --ND ND ND
03/07/13 -ND -ND ND ----ND ---ND ND ND ND -ND ND ND -ND --ND ND ND
11/07/14 -<0.50 -<0.50 <0.50 ----<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -<0.50 -<2.0 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
02/11/15 -<0.50 -<0.50 <0.50 ----<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -<0.50 -<2.0 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
02/10/16 -<0.50 -<0.50 <0.50 ----<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
06/28/17 -<0.50 -<0.50 <0.50 --<0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
01/15/18 -0.43 J -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.53 <0.50 <0.50 -4.9 <0.50 <0.50 <0.50 <0.50 --4.6 3.8 6.0
03/04/19 -<0.50 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
10/23/19 -<0.50 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -4.9 <0.50 <0.50 <0.50 <0.50 --3.1 <0.50 <0.50
05/04/20 -0.69 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.47 J <0.50 <0.50 -6.1 <0.50 <0.50 <0.50 <0.50 --3.4 <0.50 <0.50
07/14/21 -<0.50 -<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 -0.85 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/10/22 -<1.0 -<1.0 <1.0 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 <1.0 <1.0 <1.0 <1.0 -<5.0 <1.0 <1.0 <1.0 <1.0 --<1.0 <1.0 <2.00
09/08/22 <10 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/30/23 --<0.50 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 0.64 --<0.50 <2.0 1.2 J <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
01/10/12 --ND --ND ND --------ND ------ND ND ND ND --ND ND ND --ND --ND ND ND
05/17/12 --ND --ND ND --------ND ------ND ND ND ND --ND ND ND --ND --ND ND ND
03/07/13 --ND --ND ND --------ND ------ND ND ND ND --ND ND ND --ND --ND ND ND11/07/14 --<0.50 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 --<2.0 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
02/11/15 --<0.50 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 --<2.0 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
02/10/16 --<0.50 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.5006/28/17 --<0.50 --<0.50 <0.50 ----<0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/04/19 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
10/23/19 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
05/04/20 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
07/14/21 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/10/22 --<1.0 --<1.0 <1.0 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 <1.0 <1.0 <1.0 <1.0 --<5.0 <1.0 <1.0 <1.0 <1.0 --<1.0 <1.0 <2.00
09/08/22 <10 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/31/23 --<0.50 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <2.0 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
Notes:
Results in micrograms per liter (µg/L).NE - Not Established
Petroleum compounds detected in one or more samples are shown. J - estimated value below laboratory reporting limit and above method detection limit.
Gray shading denotes concentrations above 15A NCAC 2L groundwater standard (2L standard).H - Sample analyzed outside of holding time.
Yellow shading denotes concentrations above Gross Contamination Levels (GCLs).ND - Not detected
GW-VISL: NCDEQ DWM Groundwater Vapor Intrusion Screen Level, January 2023.'-' Indicates not analyzed or detected
MW-6
Sample not collected due to free product in well
Sample not collected due to well being dry
MW-7
MW-8
MW-9
Page 2 of 4
Table 5
Summary of Groundwater Analytical Results
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Pro Ject Number: 70149672B
Well/Sample
I.D.Date Collected (mm/dd/yy)tert-butylbenzene1,2,3-Trichloropropane6,000 1 4,000 70 70 70 3,000 70 3 0.02 0.4 0.4 70 600 70 25 20 400 6 70 70 0.2 600 0.005 400 400 500
600,000 5,000 4,000,000 5,900 8,800 14,750 NE 70,000 3,000 50 400 400 70,000 80,000 30,500 11,700 20,000 400,000 6,000 26,100 70,000 200 260,000 NE 24,100 28,500 50,000NE1.6 NE NE NE NE 1,800 0.81 52 0.18 2.2 NE 1,400 3.5 180 NE 450 760 4.6 490 1,900 3.2 3,800 4.5 35 50 77
Gross Contamination Level (GCL) (ug/L)
Residential GW-VISL (ug/L)
2L Standard (ug/L)Chloroformtrans-1,3-Dichloropropene1,2-Dibromoethane (EDB)1,2-DichloroethaneAnalytical Method VOCs via Method 6200B including MTBE, IPE, and EDB
Contaminant of Concern→Benzenen-Butylbenzenesec-ButylbenzeneChloromethanep-IsopropyltolueneMethyl tert-Butyl Ether(MTBE)Naphthalenen-PropylbenzeneChloroethaneXylenes, TotalStyrene1,1,2,2-Tetrachloroethane1,3,5-Trimethylbenzene2-Butanone (MEK) AcetoneMethylene ChlorideToluene1,2,4-TrimethylbenzeneDiisopropyl Ether (IPE)EthylbenzeneIsopropylbenzene01/10/12 --ND --ND ND --------ND ------ND ND ND ND --ND ND ND --ND --ND ND ND
05/17/12 --ND --ND ND --------ND ------ND ND ND ND --ND ND ND --ND --ND ND ND
03/07/13 --ND --ND ND --------ND ------ND ND ND ND --ND ND ND --0.31 J --ND 0.32 J 0.54 J
11/07/14
03/04/19 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
10/18/19 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 0.56 --<0.50 <0.50 <0.50
05/04/20
08/04/21 --<0.50 --<0.50 <0.50 -<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/10/22 --<1.0 --<1.0 <1.0 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 <1.0 <1.0 0.143 J <1.0 --1.48 J <1.0 <1.0 <1.0 <1.0 --0.162 J 0.493 J <2.00
09/08/22 <10 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/30/23 --<0.50 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <2.0 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
01/10/12 --12.9 --5.7 ND --------ND ------ND 6.8 ND 2.1 --35.1 19.4 ND --2.2 --7.9 16.7 10.7
05/17/12 --58.2 --0.82 0.62 --------ND ------ND 2.5 ND 2.6 --2.8 6.4 ND --1.7 --2.3 ND 5.603/07/13 --1.5 --0.64 0.33 J --------ND ------ND 0.79 ND ND --3.4 2.0 ND --ND --ND 0.48 J ND
11/07/14 --7.5 --0.28 J 0.30 J --------<0.50 <0.50 <0.50 <0.50 7.9 1.6 --3.6 --8.6 2.7 <0.50 <0.50 <0.50 --<0.50 <0.50 <1.0
02/11/15 --0.62 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 1.5 0.26 J --<0.50 --<2.0 0.35 J <0.50 <0.50 <0.50 --<0.50 <0.50 <1.002/10/16 --<0.50 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
06/29/17
01/15/18 --11 --<0.50 1.1 --<0.50 <0.50 0.71 <0.50 <0.50 <0.50 <0.50 15 5.2 0.76 <0.50 --7.2 4.0 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
10/23/19 --4.0 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.94 <0.50 <0.50 <0.50 --0.45 J <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
05/04/20 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
07/14/21 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/10/22 --<1.0 --<1.0 <1.0 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 <1.0 <1.0 <1.0 <1.0 --<5.0 <1.0 <1.0 <1.0 <1.0 --<1.0 <1.0 <2.00
09/08/22 <10 19 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 2.1 0.87 <0.50 1.4 <0.50 2.6 0.51 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/31/23 --30.5 --<0.50 0.96 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 8.9 3.2 --<0.50 <2.0 9.0 1.8 <0.50 <0.50 0.82 <0.50 <0.50 <0.50 <1.0
10/23/19 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
05/04/20 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
07/14/21 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/09/22 --<1.0 --<1.0 <1.0 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 <1.0 <1.0 <1.0 <1.0 --<5.0 <1.0 <1.0 <1.0 <1.0 --<1.0 <1.0 <2.00
09/07/22 <10 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/30/23 --<0.50 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <2.0 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
01/10/12
05/17/12 --89.8 --ND ND --------ND ------201 10.6 ND ND --150 24.2 ND --222 --168 374 885
03/07/13 --466 --ND ND --------ND ------771 48.3 ND ND --401 91.8 8.8 J --2,820 --629 1,900 5,950
11/05/14 --2.7 --<0.50 0.80 --------<0.50 <0.50 <0.50 <0.50 0.67 0.6 --<0.50 --6.7 <0.50 <0.50 <0.50 0.45 J --19 <0.50 0.27 J
02/12/15 --46.1 --<0.50 0.90 --------<0.50 <0.50 <0.50 <0.50 0.71 0.66 --<0.50 --<2.0 0.62 <0.50 <0.50 3.3 --8.3 <0.50 <1.0
02/10/16 --34 --<0.50 1.1 --------<0.50 <0.50 <0.50 <0.50 0.89 1 1.5 <0.50 --12 0.55 <0.50 <0.50 0.46 J --<0.50 <0.50 <0.50
06/28/17 --1.6 --1.3 1.1 ----<0.50 --<0.50 <0.50 <0.50 <0.50 0.67 0.44 J <0.50 <0.50 --1.4 <0.50 <0.50 <0.50 1.5 --<0.50 <0.50 0.62
01/16/18 --4.0 --<0.50 1.3 --0.68 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 34 2.7 <0.50 <0.50 --16 3.3 <0.50 <0.50 1.1 --0.75 2.4 10.4
03/04/19 --230 --<2.5 <2.5 --<2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 59 5.8 <2.5 <2.5 --6.8 <2.5 <2.5 <2.5 2.8 --<2.5 <2.5 3.0
10/18/19 --25 --<0.50 0.53 --<0.50 <0.50 <0.50 <0.50 0.74 <0.50 <0.50 7.1 1.9 <0.50 <0.50 --9.4 1.4 <0.50 <0.50 0.65 --1.5 5.3 6.1
05/04/20 --34 --<0.50 2.4 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.4 1.4 <0.50 <0.50 --24 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 0.41 J
07/14/21 --13 --<0.50 2.7 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.94 <0.50 <0.50 --9.4 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/09/22 --7.77 --<1.0 2.23 0.286 J <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 12.3 1.92 <1.0 <1.0 --16.2 1.86 <1.0 <1.0 0.280 J --0.566 J 2.96 4.07 J
09/07/22 <10 3.8 <10 <0.50 2.8 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.54 0.63 <0.50 <0.50 <0.50 2.9 <0.50 <0.50 <0.50 0.64 --<0.50 <0.50 <0.50
03/30/23 --3.4 --<0.50 1.8 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 1.9 0.47 J --<0.50 <2.0 2.0 J <0.50 <0.50 <0.50 4.8 <0.50 0.53 1.9 9.2
Notes:
Results in micrograms per liter (µg/L).NE - Not Established
Petroleum compounds detected in one or more samples are shown. J - estimated value below laboratory reporting limit and above method detection limit.
Gray shading denotes concentrations above 15A NCAC 2L groundwater standard (2L standard).H - Sample analyzed outside of holding time.
Yellow shading denotes concentrations above Gross Contamination Levels (GCLs).ND - Not detected
GW-VISL: NCDEQ DWM Groundwater Vapor Intrusion Screen Level, January 2023.'-' Indicates not analyzed or detected
Sample not collected due to well being dry
Well not found
Well not sampled since March 2013; well was assumed to be destroyed
Well not sampled
RW-1
MW-10
MW-11
MW-12
Page 3 of 4
Table 5
Summary of Groundwater Analytical Results
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Pro Ject Number: 70149672B
Well/Sample
I.D.Date Collected (mm/dd/yy)tert-butylbenzene1,2,3-Trichloropropane6,000 1 4,000 70 70 70 3,000 70 3 0.02 0.4 0.4 70 600 70 25 20 400 6 70 70 0.2 600 0.005 400 400 500
600,000 5,000 4,000,000 5,900 8,800 14,750 NE 70,000 3,000 50 400 400 70,000 80,000 30,500 11,700 20,000 400,000 6,000 26,100 70,000 200 260,000 NE 24,100 28,500 50,000NE1.6 NE NE NE NE 1,800 0.81 52 0.18 2.2 NE 1,400 3.5 180 NE 450 760 4.6 490 1,900 3.2 3,800 4.5 35 50 77
Gross Contamination Level (GCL) (ug/L)
Residential GW-VISL (ug/L)
2L Standard (ug/L)Chloroformtrans-1,3-Dichloropropene1,2-Dibromoethane (EDB)1,2-DichloroethaneAnalytical Method VOCs via Method 6200B including MTBE, IPE, and EDB
Contaminant of Concern→Benzenen-Butylbenzenesec-ButylbenzeneChloromethanep-IsopropyltolueneMethyl tert-Butyl Ether(MTBE)Naphthalenen-PropylbenzeneChloroethaneXylenes, TotalStyrene1,1,2,2-Tetrachloroethane1,3,5-Trimethylbenzene2-Butanone (MEK) AcetoneMethylene ChlorideToluene1,2,4-TrimethylbenzeneDiisopropyl Ether (IPE)EthylbenzeneIsopropylbenzene01/10/12
05/17/12 --458 --ND ND --------ND ------848 64.8 ND ND --675 170 ND --5,860 --617 2,450 8,910
03/07/13 --416 --ND ND --------ND ------1,330 99.7 ND ND --884 261 ND --7,910 --1,020 3,520 12,650
11/05/14 --423 --<25 <25 --------<25 <25 <25 <25 704 31.9 --<25 --403 99.1 14.2 J <25 4,550 --272 758 3,260
02/12/15 --768 --<25 <25 --------<25 <25 <25 <25 1,510 66.6 --<25 --510 198 32.5 <25 8,990 --468 1,410 7,160
02/10/16 --530 --<50 <50 --------<50 <50 <50 <50 1,800 73 <50 <50 --520 220 <50 <50 9,500 --510 1,600 8,500
06/28/17 --450 --<50 <50 ----<50 --<50 <50 <50 <50 1,500 58 <50 <50 --520 160 <50 <50 7,500 --380 1,500 8,800
01/16/18 --220 --<2.5 5.1 --<2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 990 41 <2.5 <2.5 --320 120 60 <2.5 4,300 --300 1,100 5,600
03/04/19 --390 --<50 <50 --<50 <50 <50 <50 <50 <50 <50 2400 84 <50 <50 --660 250 <50 <50 7,900 --500 1,900 9,600
10/18/19 --210 --<25 <25 --<25 <25 <25 <25 <25 <25 <25 680 31 <25 <25 --230 94 <25 <25 4,400 --240 890 3,600
05/04/20 --660 --<100 <100 --<100 <100 <100 <100 <100 <100 <100 2,400 82 J <100 <100 --630 240 <100 <100 11,000 --530 2,000 12,600
07/14/21 --350 --<25 <25 --<25 <25 <25 <25 <25 <25 <25 470 <25 <25 <25 --170 52 <25 <25 3,800 --140 500 2,900
02/09/22 --51.4 --1.67 0.914 J <1.0 <5.0 <5.0 <2.50 0.191 J <1.0 --<1.0 179 7.24 0.554 J <1.0 --59.2 19.5 <1.0 <1.0 1,440 --31.6 118 833
09/07/22 <500 150 <500 <25 <25 <25 <25 <25 <25 <25 <25 <25 <25 1,100 53 <25 <25 <25 350 150 <25 <25 6,900 --330 1,200 5,300
03/30/23 --170 --<10 <10 <10 <20 <10 <20 <10 <10 <10 <10 558 21.6 --<10 236 187 51.4 <10 <10 2,470 <10.0 138 523 2,910
01/10/12 --1,210 --ND ND --------1.6 ------733 36.6 ND 2.4 --198 94.9 ND -3,450 --195 715 3,720
05/17/12 --1,260 --15.6 ND --------2.1 ------1,180 48.9 ND 2.7 --337 134 ND -4,670 --133 961 5,27003/07/13 --1,120 --ND 35.0 --------ND ------908 53.2 ND ND --438 138 14.3 -2,110 --359 857 2,877
11/06/14 --2,670 --<12.5 <12.5 --------<12.5 <12.5 <12.5 <12.5 1,170 46.1 --<12.5 --519 152 <12.5 <12.5 512 --307 348 177
02/11/15 --2,830 --<10 <10 --------<10 <10 <10 <10 1,440 62.1 --<10 --555 173 22.3 <10 3,330 --392 975 1,74602/10/16 --2,700 --<50 <50 --------<50 <50 <50 <50 1,800 64 <50 <50 --520 190 <50 <50 4,200 --390 800 2,200
06/28/17 --1,300 --41 <25 ----<25 --<25 <25 <25 <25 1,700 75 <25 <25 --630 220 <25 <25 3,700 --460 1,300 2,090
01/15/18 --2,000 --<10 12 --<10 <10 <10 <10 <10 <10 <10 2,300 86 <10 <10 --670 290 77 <10 10,000 --540 1,800 7,400
03/04/19 --1,300 --<50 <50 --<50 <50 <50 <50 <50 <50 <50 2,500 88 <50 <50 --700 270 <50 <50 6,100 --450 1,500 5,400
10/23/19 --1,200 --<50 <50 --<50 <50 <50 <50 <50 <50 <50 1,900 74 <50 <50 --690 230 <50 <50 4,100 --370 1,300 3,390
05/04/20 --1,200 --<50 <50 --<50 <50 <50 <50 <50 <50 <50 2,200 81 <50 <50 --560 250 <50 <50 5,700 --430 1,500 5,000
07/14/21 --470 --22 7.6 --<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 1,400 61 4.5 J <5.0 --510 190 <5.0 <5.0 1,000 --130 520 1,090
02/10/22 --322 --17.3 10.3 <10.0 <50.0 <50.0 <25.0 <10.0 <10.0 --<10.0 1,900 87.3 4.98 J <10.0 --699 245 <10.0 <10.0 2,110 --376 1,420 3,102
09/08/22 27 4.1 5.5 J 1.9 0.57 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 49 3.2 0.52 <0.50 <0.50 33 10 <0.50 <0.50 13 --9.5 40 49
03/31/23 --139 --<6.2 <6.2 <6.2 <12.5 <6.2 <12.5 <6.2 <6.2 <6.2 <6.2 899 55.3 --<6.2 139 406 152 <6.2 <6.2 891 <6.2 324 1,220 1,979
01/10/12 --7.4 --ND ND --------ND ------229 17.4 ND ND --106 38.6 1.9 --5.6 --127 179 82.3
05/17/12 --37.5 --ND ND --------ND ------99 10.4 ND ND --142 26.6 ND --6.3 --64.9 106 42.5
03/07/13 --14.9 --ND ND --------ND ------30.7 3.3 ND ND --116 7.4 0.72 --7.5 --16.3 5.7 20.9
11/06/14 --40.7 --<1.2 2.6 --------<1.2 <1.2 <1.2 <1.2 208 16.8 --<1.2 --179 42 <1.2 <1.2 105 --86.4 132 455
02/11/15 --26.2 --<0.50 <0.50 --------<0.50 <0.50 <0.50 <0.50 73.7 8.4 --<0.50 --97.8 14.8 <0.50 <0.50 10.9 --46.6 16.3 58.7
02/10/16 --28 --<0.50 0.75 --------<0.50 <0.50 <0.50 <0.50 36 3.8 0.51 <0.50 --30 6.7 <0.50 0.49 J 1.1 --17 1.6 7.1
06/28/17 --14 --1.0 0.49 J ----<0.50 --<0.50 <0.50 <0.50 <0.50 32 2.6 <0.50 <0.50 --17 5.1 <0.50 <0.50 <0.50 --0.55 6.7 1.98
01/15/18 --14 --<0.50 0.5 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 14 2.5 <0.50 <0.50 --16 3.0 <0.50 <0.50 <0.50 --11 <0.50 <0.50
03/04/19 --40 --<0.50 1.2 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 14 5.6 0.67 <0.50 --36 2.9 <0.50 <0.50 1.0 --34 <0.50 <0.50
10/23/19 --16 --1.4 1.3 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 21 5.5 0.74 <0.50 --24 7.6 <0.50 <0.50 <0.50 --22 1.1 0.68
05/04/20 --3.4 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.93 <0.50 <0.50 <0.50 --1.9 <0.50 <0.50 <0.50 <0.50 --0.48 J <0.50 <0.50
07/14/21 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.77 <0.50 <0.50 <0.50 --0.83 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
02/10/22 --0.179 J --<1.0 <1.0 <1.0 <5.0 <5.0 <2.50 <1.0 <1.0 --<1.0 <1.0 <1.0 <1.0 <1.0 --<5.0 <1.0 <1.0 <1.0 <1.0 --<1.0 <1.0 <2.00
09/08/22 <10 <0.50 <10 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.1 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
03/31/23 --<0.50 --<0.50 <0.50 <0.50 <1.0 <0.50 <1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <2.0 <2.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <1.0
Pond 01/16/18 --<0.50 --<0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50 <0.50 <0.50 --<0.50 <0.50 <0.50
Notes:
Results in micrograms per liter (µg/L).NE - Not Established
Petroleum compounds detected in one or more samples are shown. J - estimated value below laboratory reporting limit and above method detection limit.
Gray shading denotes concentrations above 15A NCAC 2L groundwater standard (2L standard).H - Sample analyzed outside of holding time.
Yellow shading denotes concentrations above Gross Contamination Levels (GCLs).ND - Not detected
GW-VISL: NCDEQ DWM Groundwater Vapor Intrusion Screen Level, January 2023.'-' Indicates not analyzed or detected
Sample not collected due to well being dry
RW-2
VEW-1
VEW-2
Page 4 of 4
Sample ID:SG-01 SG-02
Sample Date:03/31/23 03/31/23
Acetone <2.97 47.1 NE NE
Chloromethane <0.413 4.65 630 7,900
Cyclohexane <0.689 1.60 42,000 530,000
Ethanol <2.36 388 NE NE
Ethylbenzene 4.47 5.38 37 490
Trichlorofluoromethane <1.12 1.43 NE NE
Dichlorodifluoromethane <0.989 1.70 700 8,800
Heptane 11.0 4.38 280 35,000
n-Hexane <2.22 3.38 4,900 61,000
Methylene Chloride <0.694 3.34 3,400 53,000
Methyl Butyl Ketone <5.11 8.83 210 2,600
2-Butanone (MEK)<3.69 15.2 35,000 440,000
2-Propanol <3.07 11.4 1,400 18,000
Tetrachloroethene 37.3 35.4 280 3,500
Toluene 30.9 28.5 35,000 440,000
1,2,4-Trimethylbenzene 3.38 4.15 420 5,300
1,3,5-Trimethylbenzene 1.15 1.14 420 5,300
2,2,4-Trimethylpentane <0.934 3.97 NE NE
m&p-Xylene 14.5 16.0 700 8,800
o-Xylene 5.46 5.25 700 8,800
Notes:
Concentrations are reported in micrograms per cubic meter (μg/m3)
Values in BOLD were detected above the method detection limit
NCDEQ - North Carolina Department of Environmental Quality
VI-SGSL - Vapor Intrusion Sub Slab and Exterior Soil Gas Screening Level (January 2023)
Res - residential; Non-Res - commercial/industrial
Shaded detections exceed their applicable screening level
< : not detected above laboratory reporting limits
NE: not established
Volatile Organic Compounds (TO-15) - (µg/m3)
Table 6
Summary of Soil Gas Analytical Results
Blalock Fina (Incident #24238)
3574 NC Highway 55, Angier, North Carolina
Terracon Project Number: 70149672B
NCDEQ
VI-SGSL
(Res)
NCDEQ
VI-SGSL
(Non-Res)

APPENDIX A
PHOTOGRAPHS AND FIELD NOTES

Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 1 – MW-1
Photo 2 – MW-1
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 3 – MW-3
Photo 4 – MW-3
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 5 – MW-4
Photo 6 – MW-5
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 7 – MW-5
Photo 8 – MW-6
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 9 – MW-6
Photo 10 – MW-8
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 11 – MW-8
Photo 12 – MW-9
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 13 – MW-9
Photo 14 – MW-10
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 15 – MW-10
Photo 16 – MW-11
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 17 – MW-11
Photo 18 – MW-12
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 19 – MW-12
Photo 20 – RW-1
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 21 – RW-1
Photo 22 – RW-2
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 23 – RW-2
Photo 23 – VEW-1
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 24 – VEW-2
Photo 25 – VEW-2
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 26 – SG-1 helium tracer test
Photo 27 – SG-1 helium tracer test
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 28 – SG-1 sampling
Photo 29 – SG-1 post sample
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 30 – SG-2 helium tracer test
Photo 31 – SG-2 helium tracer test
Blalock Fina | Angier, NC
Photos Dated 3/30/2023 & 3/31/2023
Terracon Project No. 70149672B
Photo 32 – SG-2 sampling
Photo 33 – SG-2 post sample
WATER/PRODUCT LEVEL MEASUREMENT LOG
PROJECT NAME Page______ of ______
PROJECT NO.
DATE
EQUIPMENT USED
FIELD PERSONNEL
Well ID Depth to
Product
Product
Thickness Total Depth CommentsDepth to
Water
2401 Brentwood Rd Suite 107 * Raleigh, NC, 27604 * Phone [phone] * Fax [phone]

I 1BlalockFina701496721331302023
Les Abbott
screenMWI6.74 18 818MW36.20 18 8 18
This Iii 18 8.518132.512.5Mw64.94 Ii 4MW76.75MW87.30 73 4 1124
MW9 4,55 7 2 7MW109.0 15 515MW114.55 I 2 1214414inro
RW II go Stos10
YETI 8,8 81818zip18
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Btitiatoria MW I317023
Angier NC LTA
sunny 601 7430
81823
I
ga
O
14051420 0.75 1711 6.23 1,84 167 130.414251,0 16.9 8.25 2.56 166 128.5
1430 1,25 16.9 6123 2,65 166 127.9
Latif Art 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

BIT'atorizis Mw 3713023
Angier NC LTA
sunny 603 1415
313,8123
18 O
1.9gal
r
13501405 0175 76,2 6.41 0110 338 144
14451 464 47819 388 1 97
Lalouf Abt 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

BIT'atorizi MW 4330123AngierNCCJA
sunny 605 1325
330 23
Hit 070.88
0.45
15001515 017516.8 4.61 286 770 297.51016.8 4.592.56 790 255.613451.25 16.9 4.58 2.39 808 257.9
Latifah 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

BlatnikFina MW'S70149672133130123
Angier NC LJA
sunny 605 1545
3130 23
1818
o
0.48gal
15201535 0,75 16,2 4,62 5.60 089 219.2
15481 181 88 53 899 38
Lulong Allt 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Bitintorizis MW 63131123AngierNCCTA
Sunny 605 1235
313123TO4.94 O
5 9
12101225 0.751513 5.82 1,83 128 2616
1235 I s 1315848184 147 57.263.2
Lili J Allott 3131123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Einsteins MW 733023
Angier NC LTA
sunny 601 1600
3 30 23
115 10
0.69gal
15351550 0.75 15.4 4.812.89 044 198.615551,0 15.0 4,802144 044 197.316001.25 15.5 243442.26 043 195.4
Lalo JAH 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Einstein Mw 83131123
Angier NC 25A7220
Iii30 0
sit0.93gal
11501210 0.79 14,7 4.99 1,13 151 190.5
1215 1,0 15.0 5.00 2.04 157 196.512201,25 15.0 5.01 2.76 155 207.9
Let Jatt 3131123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

I i'atoning MW 93131123
Angier NC CJA
sunny 601 1300
3 31123
o
0.40gal
is
Lalonfatht 3 11 23
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Bitiatorizis MW 103130123AngierNCLTA
sunny 60s 1450
13,5123
0.98
11235 0.75 15.8 4.89 8.75 035 99.0
1448 11 16.5 4.938.53 042 112.3
1450 1.50 77.74.95 9.06 038 135.2
Lake Jatt 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Bititorizis MW 113731123
Angier NC CJA
sunny 604 1325
tie134.55 O
T.is1.38gal
1300 87.213150.75 14.9 5.84 1.64 55.81325its44885217818849.6
Lusting Abt 3131123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Etiigorin MW 12
3123043LTAAngierNC1705sunny605
3,4 12
4.88 OI1213.2gal
12401255 0.75 16.1 4547.41 035 251.61300110764,53753 034 274.813051.25 16,0 4.537,10 034 283.2
LeliaJAlbt 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

ÉÉÉÉÉB RV I313027
Angier NC CJA
sunny 605 1405
3 30 2351010 O
0.65gal
739013550.75 15.9 8.120.20 601 65.71,0 16.1 6.17 0.21 601 69.114851,25 16.1 6.13 0.17 602 70.9
Lalo Jat 3130123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

Bititorizis RW 2
3130 23LTAAgain'ny Yoo 7340
7 70 23
Polio o
0.70 gal
13151730 0.75 15.8 8.071.46 168 139.0
1335 1.0 16.1 1.05 1128 168 1371713401.25 96 8.05 4114 169 1413
VOL 8260 4298hL 3 HIsulfate300
Ifat 3130 23
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

EITHER VEW 13131723
Angier NC CJA
sunny 605 1350
3131 2581818 o
1325
138 816288578 9 it's a'to
1,25 1612 6.390.70 240 96.1
Latin J Allt 3131123
Groundwater Sampling Log
Site Name:Well ID:
Project Number:Sample Date:
Site Location:Sampler Initials:
Weather:Sample Time:
GAUGING DATA
Gauging Date:Well Diameter
Screen Interval (ft bls):6"
Total Depth (ft bTOC):4"
Depth to water (ft bTOC):2"
1"
Water column length (ft):¾"
Well Volume:
Sample Method Purge Device QA/QC Samples QA/QC Sample ID
Peristaltic Grundfos Dedicated Duplicate
Bladder Monsoon Disposable MS/MSD
Bailer PDB Decontaminated Equipment Blank
FIELD PARAMETERS
LABORATORY ANALYSIS
Date:

DO
(mg/L)
Cond.
(µmhos/cm)
Turbidity
(NTU)
ORP
(mV)
Flow
(ml/min)

Preservative

Method

Analytical Parameter

No. Bottles

Hold Time

Time Purge Vol.
(gal )
Temp
(°C)
pH
(SU)
L/ft
5.56
2.47
Gal/ft
1.47
0.653
0.618
0.154
0.163
0.041
0.023 0.087
Water Depth
(ft bTOC)

Bottle Size/Type

Signature:
Notes:

Stick-up length (ft ags):

BEEFIER NEW 2
3 31 23
Angier NC LTA
sunny 605 1420
3 31 12.15
8 18
18.8 O
T.tt
1355
I16,6 41728105 70 24916
Julie Jalut 33123
Sample ID:
Project :
Site Location:
Field Personnel:2401 Brentwood Road Suite 107
Date:Raleigh, NC 27604
Weather:919.873.2211
Canister Size:
Sample Rate:<200 mL/min Canister No.:
Analysis:TO-15 Flow Controller No.:
HELIUM TRACER TEST
Purge #1 Purge #2 Purge #3
Start Shroud He %:
Purge Start Time:
Volume Purged (mL):
End Shroud He %:
He in Soil Gas (ppm):
PID Ambient Air (ppb):
PID SV Point (ppb):
Note: 1% = 10,000 ppm
SAMPLE COLLECTION VOLUME CALCULATION
Time Vacuum (in Hg)
Start:
Stop:
Assumed porosity: sand pack= 0.4, dry bentonite=0.5
Soil Vapor Tracer Test & Sampling

56 1Blalock FingEgerNC
3131123
pinny Got
009057009678
15.01027 ios's isis60060099.9 13.7 15.128Go
1561 3116 4823
1040 30
1041 25
1042 19
1043 15
1044 10
1045 f
Sample ID:
Project :
Site Location:
Field Personnel:2401 Brentwood Road Suite 107
Date:Raleigh, NC 27604
Weather:919.873.2211
Canister Size:
Sample Rate:<200 mL/min Canister No.:
Analysis:TO-15 Flow Controller No.:
HELIUM TRACER TEST
Purge #1 Purge #2 Purge #3
Start Shroud He %:
Purge Start Time:
Volume Purged (mL):
End Shroud He %:
He in Soil Gas (ppm):
PID Ambient Air (ppb):
PID SV Point (ppb):
Note: 1% = 10,000 ppm
SAMPLE COLLECTION VOLUME CALCULATION
Time Vacuum (in Hg)
Start:
Stop:
Assumed porosity: sand pack= 0.4, dry bentonite=0.5
Soil Vapor Tracer Test & Sampling
SG 2
Blalock Fina
Eystein33123
Tinny 605
021878
009616
11554 16.4 15.81107111060060014916.2 15.3838302
1445 1317 1444
11201121
3025112220
1123 1411249
1125 S

2401 Brentwood Road, Suite
107 Raleigh, NC 27604
(919)-873-2211
FIELD ACTIVITY LOG
Date:
Project Name: Project Number:
Personnel: Equipment:

Current Site Name: Site Contact:

Time Description of Services Performed

Signature Page____ of_____

Blalock FinahesAbbott 78 9 7213
845 Les Abbott arrive on site
objective Groundwater sample MW 1MW3MW4MW5MW6MW7MW8 MW9MWIOMWilMW12RWW1RW2Installtwosoilgetpointsandsample900LocatingWellsandopeningcaps905MelissaByrumonsitetoutilitylocate1030Melissaoffsite
Having troublefinding MW1 Gangingothers1040Leavingsiteforicewater1145MWIlocated
Gauging all wells on NorthsideSeelogsforsampledata1530EthanDinwiddieonsite for SGpoint istall1720Allgtfpligiteonice
Lahey Allt i 2

2401 Brentwood Road, Suite
107 Raleigh, NC 27604
(919)-873-2211
FIELD ACTIVITY LOG
Date:
Project Name: Project Number:
Personnel: Equipment:

Current Site Name: Site Contact:

Time Description of Services Performed

Signature Page____ of_____
70 487213E'shititfina
900 Les Abbott arrive on site
910 Opening wells on south side of Hwy Ss940wellsopen945FinishingSGinstall1030SGpointssetupSalHetracertestSeenogsforalltime's1130SGsamplescomplete11301500GWsamplingsouthsideIsonspatteddidiceatingsite
Luton Jatt 22

APPENDIX B
LABORATORY ANALYTICAL RESULTS AND
CHAIN-OF-CUSTODY FORMS

#=CL#
April 11, 2023
LIMS USE: FR - ETHAN DINWIDDIE
LIMS OBJECT ID: 92660072
92660072
Project:
Pace Project No.:
RE:
Ethan Dinwiddie
Terracon
2401 Brentwood Road
Suite 107
Raleigh, NC 27604
70149672B BLALOCK FINA
Dear Ethan Dinwiddie:
Enclosed are the analytical results for sample(s) received by the laboratory on April 01, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 67
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 67
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Lab ID Sample ID Matrix Date Collected Date Received
92660072001 MW-1 Water 03/30/23 14:30 04/01/23 12:52
92660072002 MW-3 Water 03/30/23 14:15 04/01/23 12:52
92660072003 MW-4 Water 03/30/23 13:25 04/01/23 12:52
92660072004 MW-5 Water 03/30/23 15:45 04/01/23 12:52
92660072005 MW-6 Water 03/31/23 12:35 04/01/23 12:52
92660072006 MW-7 Water 03/30/23 16:00 04/01/23 12:52
92660072007 MW-8 Water 03/31/23 12:20 04/01/23 12:52
92660072008 MW-9 Water 03/31/23 13:00 04/01/23 12:52
92660072009 MW-10 Water 03/30/23 14:50 04/01/23 12:52
92660072010 MW-11 Water 03/31/23 13:25 04/01/23 12:52
92660072011 MW-12 Water 03/30/23 13:05 04/01/23 12:52
92660072012 RW-1 Water 03/30/23 14:05 04/01/23 12:52
92660072013 RW-2 Water 03/30/23 13:40 04/01/23 12:52
92660072014 VEW-1 Water 03/31/23 13:50 04/01/23 12:52
92660072015 VEW-2 Water 03/31/23 14:20 04/01/23 12:52
92660072016 FIELD BLANK Water 03/30/23 00:00 04/01/23 12:52
92660072017 TRIP BLANK Water 03/30/23 00:00 04/01/23 12:52
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 67
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92660072001 MW-1 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072002 MW-3 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072003 MW-4 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072004 MW-5 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072005 MW-6 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072006 MW-7 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072007 MW-8 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072008 MW-9 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072009 MW-10 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072010 MW-11 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072011 MW-12 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072012 RW-1 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072013 RW-2 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072014 VEW-1 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072015 VEW-2 SM 6200B 63 PASI-CLMB
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
92660072016 FIELD BLANK SM 6200B 63 PASI-CLMB
92660072017 TRIP BLANK SM 6200B 63 PASI-CLMB
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-1 Lab ID:92660072001 Collected:03/30/23 14:30 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 20.1 ug/L 04/10/23 19:00 71-43-21.0 0.69 2
Bromobenzene ND ug/L 04/10/23 19:00 108-86-11.0 0.58 2
Bromochloromethane ND ug/L 04/10/23 19:00 74-97-51.0 0.94 2
Bromodichloromethane ND ug/L 04/10/23 19:00 75-27-41.0 0.61 2
Bromoform ND ug/L 04/10/23 19:00 75-25-21.0 0.68 2
Bromomethane ND ug/L 04/10/23 19:00 74-83-910.0 3.3 2
n-Butylbenzene ND ug/L 04/10/23 19:00 104-51-81.0 0.98 2
sec-Butylbenzene ND ug/L 04/10/23 19:00 135-98-81.0 0.80 2
tert-Butylbenzene ND ug/L 04/10/23 19:00 98-06-61.0 0.65 2
Carbon tetrachloride ND ug/L 04/10/23 19:00 56-23-51.0 0.67 2
Chlorobenzene ND ug/L 04/10/23 19:00 108-90-71.0 0.57 2
Chloroethane ND ug/L 04/10/23 19:00 75-00-32.0 1.3 2
Chloroform ND ug/L 04/10/23 19:00 67-66-31.0 0.86 2
Chloromethane ND ug/L 04/10/23 19:00 74-87-32.0 1.1 2
2-Chlorotoluene ND ug/L 04/10/23 19:00 95-49-81.0 0.64 2
4-Chlorotoluene ND ug/L 04/10/23 19:00 106-43-41.0 0.65 2
1,2-Dibromo-3-chloropropane ND ug/L 04/10/23 19:00 96-12-82.0 0.68 2
Dibromochloromethane ND ug/L 04/10/23 19:00 124-48-11.0 0.72 2
1,2-Dibromoethane (EDB)ND ug/L 04/10/23 19:00 106-93-41.0 0.54 2
Dibromomethane ND ug/L 04/10/23 19:00 74-95-31.0 0.79 2
1,2-Dichlorobenzene ND ug/L 04/10/23 19:00 95-50-11.0 0.68 2
1,3-Dichlorobenzene ND ug/L 04/10/23 19:00 541-73-11.0 0.68 2
1,4-Dichlorobenzene ND ug/L 04/10/23 19:00 106-46-71.0 0.67 2
Dichlorodifluoromethane ND ug/L 04/10/23 19:00 75-71-8 L11.0 0.69 2
1,1-Dichloroethane ND ug/L 04/10/23 19:00 75-34-31.0 0.73 2
1,2-Dichloroethane ND ug/L 04/10/23 19:00 107-06-21.0 0.64 2
1,1-Dichloroethene ND ug/L 04/10/23 19:00 75-35-41.0 0.70 2
cis-1,2-Dichloroethene ND ug/L 04/10/23 19:00 156-59-21.0 0.77 2
trans-1,2-Dichloroethene ND ug/L 04/10/23 19:00 156-60-51.0 0.79 2
1,2-Dichloropropane ND ug/L 04/10/23 19:00 78-87-51.0 0.71 2
1,3-Dichloropropane ND ug/L 04/10/23 19:00 142-28-91.0 0.57 2
2,2-Dichloropropane ND ug/L 04/10/23 19:00 594-20-71.0 0.78 2
1,1-Dichloropropene ND ug/L 04/10/23 19:00 563-58-61.0 0.85 2
cis-1,3-Dichloropropene ND ug/L 04/10/23 19:00 10061-01-51.0 0.73 2
trans-1,3-Dichloropropene ND ug/L 04/10/23 19:00 10061-02-61.0 0.73 2
Diisopropyl ether ND ug/L 04/10/23 19:00 108-20-31.0 0.62 2
Ethylbenzene 251 ug/L 04/10/23 19:00 100-41-41.0 0.61 2
Hexachloro-1,3-butadiene ND ug/L 04/10/23 19:00 87-68-34.0 3.1 2
Isopropylbenzene (Cumene)19.6 ug/L 04/10/23 19:00 98-82-81.0 0.67 2
Methylene Chloride 29.5 ug/L 04/10/23 19:00 75-09-2 C94.0 3.9 2
Methyl-tert-butyl ether ND ug/L 04/10/23 19:00 1634-04-41.0 0.84 2
Naphthalene 103 ug/L 04/10/23 19:00 91-20-34.0 1.3 2
n-Propylbenzene 51.4 ug/L 04/10/23 19:00 103-65-11.0 0.68 2
Styrene ND ug/L 04/10/23 19:00 100-42-51.0 0.58 2
1,1,1,2-Tetrachloroethane ND ug/L 04/10/23 19:00 630-20-61.0 0.62 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-1 Lab ID:92660072001 Collected:03/30/23 14:30 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/10/23 19:00 79-34-51.0 0.45 2
Tetrachloroethene ND ug/L 04/10/23 19:00 127-18-41.0 0.58 2
Toluene 223 ug/L 04/10/23 19:00 108-88-31.0 0.48 2
1,2,3-Trichlorobenzene ND ug/L 04/10/23 19:00 87-61-64.0 1.6 2
1,2,4-Trichlorobenzene ND ug/L 04/10/23 19:00 120-82-14.0 1.3 2
1,1,1-Trichloroethane ND ug/L 04/10/23 19:00 71-55-61.0 0.66 2
1,1,2-Trichloroethane ND ug/L 04/10/23 19:00 79-00-51.0 0.65 2
Trichloroethene ND ug/L 04/10/23 19:00 79-01-61.0 0.77 2
Trichlorofluoromethane ND ug/L 04/10/23 19:00 75-69-42.0 0.60 2
1,2,3-Trichloropropane ND ug/L 04/10/23 19:00 96-18-41.0 0.52 2
1,2,4-Trimethylbenzene 243 ug/L 04/10/23 19:00 95-63-61.0 0.99 2
1,3,5-Trimethylbenzene 63.2 ug/L 04/10/23 19:00 108-67-81.0 0.66 2
Vinyl chloride ND ug/L 04/10/23 19:00 75-01-42.0 0.77 2
m&p-Xylene 374 ug/L 04/10/23 19:00 179601-23-12.0 1.4 2
o-Xylene 144 ug/L 04/10/23 19:00 95-47-61.0 0.68 2
Surrogates
1,2-Dichloroethane-d4 (S)93 %04/10/23 19:00 17060-07-070-130 2
4-Bromofluorobenzene (S)97 %04/10/23 19:00 460-00-470-130 2
Toluene-d8 (S)99 %04/10/23 19:00 2037-26-570-130 2
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 24.1 mg/L 04/05/23 21:04 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-3 Lab ID:92660072002 Collected:03/30/23 14:15 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 468 ug/L 04/08/23 05:50 71-43-225.0 17.2 50
Bromobenzene ND ug/L 04/08/23 05:50 108-86-125.0 14.5 50
Bromochloromethane ND ug/L 04/08/23 05:50 74-97-525.0 23.4 50
Bromodichloromethane ND ug/L 04/08/23 05:50 75-27-425.0 15.4 50
Bromoform ND ug/L 04/08/23 05:50 75-25-225.0 17.0 50
Bromomethane ND ug/L 04/08/23 05:50 74-83-925083.0 50
n-Butylbenzene ND ug/L 04/08/23 05:50 104-51-825.0 24.5 50
sec-Butylbenzene ND ug/L 04/08/23 05:50 135-98-825.0 20.0 50
tert-Butylbenzene ND ug/L 04/08/23 05:50 98-06-625.0 16.2 50
Carbon tetrachloride ND ug/L 04/08/23 05:50 56-23-525.0 16.6 50
Chlorobenzene ND ug/L 04/08/23 05:50 108-90-725.0 14.2 50
Chloroethane ND ug/L 04/08/23 05:50 75-00-350.0 32.4 50
Chloroform ND ug/L 04/08/23 05:50 67-66-325.0 21.5 50
Chloromethane ND ug/L 04/08/23 05:50 74-87-350.0 27.0 50
2-Chlorotoluene ND ug/L 04/08/23 05:50 95-49-825.0 16.0 50
4-Chlorotoluene ND ug/L 04/08/23 05:50 106-43-425.0 16.2 50
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 05:50 96-12-850.0 17.0 50
Dibromochloromethane ND ug/L 04/08/23 05:50 124-48-125.0 18.0 50
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 05:50 106-93-425.0 13.6 50
Dibromomethane ND ug/L 04/08/23 05:50 74-95-325.0 19.7 50
1,2-Dichlorobenzene ND ug/L 04/08/23 05:50 95-50-125.0 17.0 50
1,3-Dichlorobenzene ND ug/L 04/08/23 05:50 541-73-125.0 17.0 50
1,4-Dichlorobenzene ND ug/L 04/08/23 05:50 106-46-725.0 16.6 50
Dichlorodifluoromethane ND ug/L 04/08/23 05:50 75-71-8 L125.0 17.3 50
1,1-Dichloroethane ND ug/L 04/08/23 05:50 75-34-325.0 18.4 50
1,2-Dichloroethane ND ug/L 04/08/23 05:50 107-06-225.0 16.1 50
1,1-Dichloroethene ND ug/L 04/08/23 05:50 75-35-425.0 17.4 50
cis-1,2-Dichloroethene ND ug/L 04/08/23 05:50 156-59-225.0 19.2 50
trans-1,2-Dichloroethene ND ug/L 04/08/23 05:50 156-60-525.0 19.8 50
1,2-Dichloropropane ND ug/L 04/08/23 05:50 78-87-525.0 17.8 50
1,3-Dichloropropane ND ug/L 04/08/23 05:50 142-28-925.0 14.2 50
2,2-Dichloropropane ND ug/L 04/08/23 05:50 594-20-725.0 19.4 50
1,1-Dichloropropene ND ug/L 04/08/23 05:50 563-58-625.0 21.4 50
cis-1,3-Dichloropropene ND ug/L 04/08/23 05:50 10061-01-525.0 18.2 50
trans-1,3-Dichloropropene ND ug/L 04/08/23 05:50 10061-02-625.0 18.2 50
Diisopropyl ether ND ug/L 04/08/23 05:50 108-20-325.0 15.4 50
Ethylbenzene 2610 ug/L 04/08/23 05:50 100-41-425.0 15.2 50
Hexachloro-1,3-butadiene ND ug/L 04/08/23 05:50 87-68-310076.5 50
Isopropylbenzene (Cumene)87.9 ug/L 04/08/23 05:50 98-82-825.0 16.6 50
Methylene Chloride ND ug/L 04/08/23 05:50 75-09-210097.5 50
Methyl-tert-butyl ether ND ug/L 04/08/23 05:50 1634-04-425.0 21.1 50
Naphthalene 728 ug/L 04/08/23 05:50 91-20-310032.2 50
n-Propylbenzene 241 ug/L 04/08/23 05:50 103-65-125.0 17.0 50
Styrene 43.5 ug/L 04/08/23 05:50 100-42-525.0 14.6 50
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 05:50 630-20-625.0 15.6 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-3 Lab ID:92660072002 Collected:03/30/23 14:15 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 05:50 79-34-525.0 11.2 50
Tetrachloroethene ND ug/L 04/08/23 05:50 127-18-425.0 14.6 50
Toluene 9040 ug/L 04/08/23 05:50 108-88-325.0 12.0 50
1,2,3-Trichlorobenzene ND ug/L 04/08/23 05:50 87-61-610040.3 50
1,2,4-Trichlorobenzene ND ug/L 04/08/23 05:50 120-82-110032.0 50
1,1,1-Trichloroethane ND ug/L 04/08/23 05:50 71-55-625.0 16.6 50
1,1,2-Trichloroethane ND ug/L 04/08/23 05:50 79-00-525.0 16.2 50
Trichloroethene ND ug/L 04/08/23 05:50 79-01-625.0 19.2 50
Trichlorofluoromethane ND ug/L 04/08/23 05:50 75-69-450.0 14.9 50
1,2,3-Trichloropropane ND ug/L 04/08/23 05:50 96-18-425.0 13.0 50
1,2,4-Trimethylbenzene 2170 ug/L 04/08/23 05:50 95-63-625.0 24.8 50
1,3,5-Trimethylbenzene 620 ug/L 04/08/23 05:50 108-67-825.0 16.6 50
Vinyl chloride ND ug/L 04/08/23 05:50 75-01-450.0 19.3 50
m&p-Xylene 8290 ug/L 04/08/23 05:50 179601-23-150.0 35.4 50
o-Xylene 2770 ug/L 04/08/23 05:50 95-47-625.0 16.9 50
Surrogates
1,2-Dichloroethane-d4 (S)89 %04/08/23 05:50 17060-07-070-130 50
4-Bromofluorobenzene (S)97 %04/08/23 05:50 460-00-470-130 50
Toluene-d8 (S)100 %04/08/23 05:50 2037-26-570-130 50
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 39.4 mg/L 04/05/23 21:20 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-4 Lab ID:92660072003 Collected:03/30/23 13:25 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/08/23 00:46 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/08/23 00:46 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/08/23 00:46 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/08/23 00:46 75-27-40.50 0.31 1
Bromoform ND ug/L 04/08/23 00:46 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/08/23 00:46 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/08/23 00:46 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/08/23 00:46 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/08/23 00:46 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/08/23 00:46 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/08/23 00:46 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/08/23 00:46 75-00-31.0 0.65 1
Chloroform ND ug/L 04/08/23 00:46 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/08/23 00:46 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/08/23 00:46 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/08/23 00:46 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 00:46 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/08/23 00:46 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 00:46 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/08/23 00:46 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/08/23 00:46 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/08/23 00:46 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/08/23 00:46 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/08/23 00:46 75-71-8 L10.50 0.35 1
1,1-Dichloroethane ND ug/L 04/08/23 00:46 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/08/23 00:46 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/08/23 00:46 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/08/23 00:46 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/08/23 00:46 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/08/23 00:46 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/08/23 00:46 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/08/23 00:46 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/08/23 00:46 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/08/23 00:46 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/08/23 00:46 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/08/23 00:46 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/08/23 00:46 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/08/23 00:46 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 04/08/23 00:46 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/08/23 00:46 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/08/23 00:46 1634-04-40.50 0.42 1
Naphthalene ND ug/L 04/08/23 00:46 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/08/23 00:46 103-65-10.50 0.34 1
Styrene ND ug/L 04/08/23 00:46 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 00:46 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-4 Lab ID:92660072003 Collected:03/30/23 13:25 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 00:46 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/08/23 00:46 127-18-40.50 0.29 1
Toluene ND ug/L 04/08/23 00:46 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/08/23 00:46 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/08/23 00:46 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/08/23 00:46 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/08/23 00:46 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/08/23 00:46 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/08/23 00:46 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/08/23 00:46 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/08/23 00:46 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/08/23 00:46 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/08/23 00:46 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/08/23 00:46 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/08/23 00:46 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)95 %04/08/23 00:46 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/08/23 00:46 460-00-470-130 1
Toluene-d8 (S)98 %04/08/23 00:46 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 261 mg/L 04/06/23 04:55 14808-79-86.0 3.0 6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-5 Lab ID:92660072004 Collected:03/30/23 15:45 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 0.93 ug/L 04/11/23 03:02 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/11/23 03:02 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/11/23 03:02 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/11/23 03:02 75-27-40.50 0.31 1
Bromoform ND ug/L 04/11/23 03:02 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/11/23 03:02 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/11/23 03:02 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/11/23 03:02 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/11/23 03:02 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/11/23 03:02 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/11/23 03:02 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/11/23 03:02 75-00-31.0 0.65 1
Chloroform ND ug/L 04/11/23 03:02 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/11/23 03:02 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/11/23 03:02 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/11/23 03:02 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/11/23 03:02 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/11/23 03:02 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/11/23 03:02 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/11/23 03:02 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/11/23 03:02 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/11/23 03:02 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/11/23 03:02 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/11/23 03:02 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 04/11/23 03:02 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/11/23 03:02 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/11/23 03:02 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/11/23 03:02 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/11/23 03:02 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/11/23 03:02 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/11/23 03:02 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/11/23 03:02 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/11/23 03:02 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/11/23 03:02 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/11/23 03:02 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/11/23 03:02 108-20-30.50 0.31 1
Ethylbenzene 45.9 ug/L 04/11/23 03:02 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/11/23 03:02 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)2.9 ug/L 04/11/23 03:02 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/11/23 03:02 75-09-2 L12.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/11/23 03:02 1634-04-40.50 0.42 1
Naphthalene 11.8 ug/L 04/11/23 03:02 91-20-32.0 0.64 1
n-Propylbenzene 7.8 ug/L 04/11/23 03:02 103-65-10.50 0.34 1
Styrene ND ug/L 04/11/23 03:02 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/11/23 03:02 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-5 Lab ID:92660072004 Collected:03/30/23 15:45 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/11/23 03:02 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/11/23 03:02 127-18-40.50 0.29 1
Toluene 32.2 ug/L 04/11/23 03:02 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/11/23 03:02 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/11/23 03:02 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/11/23 03:02 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/11/23 03:02 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/11/23 03:02 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/11/23 03:02 75-69-41.0 0.30 1
1,2,3-Trichloropropane 0.51 ug/L 04/11/23 03:02 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 28.8 ug/L 04/11/23 03:02 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 20.4 ug/L 04/11/23 03:02 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/11/23 03:02 75-01-41.0 0.39 1
m&p-Xylene 41.2 ug/L 04/11/23 03:02 179601-23-11.0 0.71 1
o-Xylene 9.0 ug/L 04/11/23 03:02 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)95 %04/11/23 03:02 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/11/23 03:02 460-00-470-130 1
Toluene-d8 (S)98 %04/11/23 03:02 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 29.7 mg/L 04/05/23 21:53 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-6 Lab ID:92660072005 Collected:03/31/23 12:35 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 1100 ug/L 04/10/23 18:42 71-43-2 M15.0 3.4 10
Bromobenzene ND ug/L 04/10/23 18:42 108-86-1 M15.0 2.9 10
Bromochloromethane ND ug/L 04/10/23 18:42 74-97-5 M15.0 4.7 10
Bromodichloromethane ND ug/L 04/10/23 18:42 75-27-4 M15.0 3.1 10
Bromoform ND ug/L 04/10/23 18:42 75-25-2 M15.0 3.4 10
Bromomethane ND ug/L 04/10/23 18:42 74-83-9 M150.0 16.6 10
n-Butylbenzene ND ug/L 04/10/23 18:42 104-51-8 M15.0 4.9 10
sec-Butylbenzene ND ug/L 04/10/23 18:42 135-98-8 M15.0 4.0 10
tert-Butylbenzene ND ug/L 04/10/23 18:42 98-06-6 M15.0 3.2 10
Carbon tetrachloride ND ug/L 04/10/23 18:42 56-23-5 M15.0 3.3 10
Chlorobenzene ND ug/L 04/10/23 18:42 108-90-7 M15.0 2.8 10
Chloroethane ND ug/L 04/10/23 18:42 75-00-3 M110.0 6.5 10
Chloroform ND ug/L 04/10/23 18:42 67-66-3 M15.0 4.3 10
Chloromethane ND ug/L 04/10/23 18:42 74-87-3 M110.0 5.4 10
2-Chlorotoluene ND ug/L 04/10/23 18:42 95-49-8 M15.0 3.2 10
4-Chlorotoluene ND ug/L 04/10/23 18:42 106-43-4 M15.0 3.2 10
1,2-Dibromo-3-chloropropane ND ug/L 04/10/23 18:42 96-12-8 M110.0 3.4 10
Dibromochloromethane ND ug/L 04/10/23 18:42 124-48-1 M15.0 3.6 10
1,2-Dibromoethane (EDB)ND ug/L 04/10/23 18:42 106-93-4 M15.0 2.7 10
Dibromomethane ND ug/L 04/10/23 18:42 74-95-3 M15.0 3.9 10
1,2-Dichlorobenzene ND ug/L 04/10/23 18:42 95-50-1 M15.0 3.4 10
1,3-Dichlorobenzene ND ug/L 04/10/23 18:42 541-73-1 M15.0 3.4 10
1,4-Dichlorobenzene ND ug/L 04/10/23 18:42 106-46-7 M15.0 3.3 10
Dichlorodifluoromethane ND ug/L 04/10/23 18:42 75-71-8 L1,M05.0 3.5 10
1,1-Dichloroethane ND ug/L 04/10/23 18:42 75-34-3 M15.0 3.7 10
1,2-Dichloroethane ND ug/L 04/10/23 18:42 107-06-2 M15.0 3.2 10
1,1-Dichloroethene ND ug/L 04/10/23 18:42 75-35-4 M15.0 3.5 10
cis-1,2-Dichloroethene ND ug/L 04/10/23 18:42 156-59-2 M15.0 3.8 10
trans-1,2-Dichloroethene ND ug/L 04/10/23 18:42 156-60-5 M15.0 4.0 10
1,2-Dichloropropane ND ug/L 04/10/23 18:42 78-87-5 M15.0 3.6 10
1,3-Dichloropropane ND ug/L 04/10/23 18:42 142-28-9 M15.0 2.8 10
2,2-Dichloropropane ND ug/L 04/10/23 18:42 594-20-7 M15.0 3.9 10
1,1-Dichloropropene ND ug/L 04/10/23 18:42 563-58-6 M15.0 4.3 10
cis-1,3-Dichloropropene ND ug/L 04/10/23 18:42 10061-01-5 M15.0 3.6 10
trans-1,3-Dichloropropene ND ug/L 04/10/23 18:42 10061-02-6 M15.0 3.6 10
Diisopropyl ether ND ug/L 04/10/23 18:42 108-20-3 M15.0 3.1 10
Ethylbenzene 253 ug/L 04/10/23 18:42 100-41-4 M15.0 3.0 10
Hexachloro-1,3-butadiene ND ug/L 04/10/23 18:42 87-68-3 M120.0 15.3 10
Isopropylbenzene (Cumene)8.6 ug/L 04/10/23 18:42 98-82-8 M15.0 3.3 10
Methylene Chloride 157 ug/L 04/10/23 18:42 75-09-2 C9,M120.0 19.5 10
Methyl-tert-butyl ether ND ug/L 04/10/23 18:42 1634-04-4 M15.0 4.2 10
Naphthalene 79.0 ug/L 04/10/23 18:42 91-20-3 M120.0 6.4 10
n-Propylbenzene 21.7 ug/L 04/10/23 18:42 103-65-1 M15.0 3.4 10
Styrene ND ug/L 04/10/23 18:42 100-42-5 M15.0 2.9 10
1,1,1,2-Tetrachloroethane ND ug/L 04/10/23 18:42 630-20-6 M15.0 3.1 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-6 Lab ID:92660072005 Collected:03/31/23 12:35 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/10/23 18:42 79-34-5 M15.0 2.2 10
Tetrachloroethene ND ug/L 04/10/23 18:42 127-18-4 M15.0 2.9 10
Toluene 787 ug/L 04/10/23 18:42 108-88-3 M15.0 2.4 10
1,2,3-Trichlorobenzene ND ug/L 04/10/23 18:42 87-61-6 M120.0 8.1 10
1,2,4-Trichlorobenzene ND ug/L 04/10/23 18:42 120-82-1 M120.0 6.4 10
1,1,1-Trichloroethane ND ug/L 04/10/23 18:42 71-55-6 M15.0 3.3 10
1,1,2-Trichloroethane ND ug/L 04/10/23 18:42 79-00-5 M15.0 3.2 10
Trichloroethene ND ug/L 04/10/23 18:42 79-01-6 M15.0 3.8 10
Trichlorofluoromethane ND ug/L 04/10/23 18:42 75-69-4 M110.0 3.0 10
1,2,3-Trichloropropane ND ug/L 04/10/23 18:42 96-18-4 M15.0 2.6 10
1,2,4-Trimethylbenzene 50.8 ug/L 04/10/23 18:42 95-63-6 M15.0 5.0 10
1,3,5-Trimethylbenzene 12.1 ug/L 04/10/23 18:42 108-67-8 M15.0 3.3 10
Vinyl chloride ND ug/L 04/10/23 18:42 75-01-4 M110.0 3.9 10
m&p-Xylene 145 ug/L 04/10/23 18:42 179601-23-1 M110.0 7.1 10
o-Xylene 36.6 ug/L 04/10/23 18:42 95-47-6 M15.0 3.4 10
Surrogates
1,2-Dichloroethane-d4 (S)94 %04/10/23 18:42 17060-07-070-130 10
4-Bromofluorobenzene (S)99 %04/10/23 18:42 460-00-470-130 10
Toluene-d8 (S)97 %04/10/23 18:42 2037-26-570-130 10
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 26.9 mg/L 04/05/23 23:54 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-7 Lab ID:92660072006 Collected:03/30/23 16:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/11/23 02:08 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/11/23 02:08 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/11/23 02:08 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/11/23 02:08 75-27-40.50 0.31 1
Bromoform ND ug/L 04/11/23 02:08 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/11/23 02:08 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/11/23 02:08 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/11/23 02:08 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/11/23 02:08 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/11/23 02:08 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/11/23 02:08 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/11/23 02:08 75-00-31.0 0.65 1
Chloroform ND ug/L 04/11/23 02:08 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/11/23 02:08 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/11/23 02:08 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/11/23 02:08 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/11/23 02:08 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/11/23 02:08 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/11/23 02:08 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/11/23 02:08 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/11/23 02:08 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/11/23 02:08 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/11/23 02:08 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/11/23 02:08 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 04/11/23 02:08 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/11/23 02:08 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/11/23 02:08 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/11/23 02:08 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/11/23 02:08 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/11/23 02:08 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/11/23 02:08 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/11/23 02:08 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/11/23 02:08 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/11/23 02:08 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/11/23 02:08 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/11/23 02:08 108-20-30.50 0.31 1
Ethylbenzene 0.85 ug/L 04/11/23 02:08 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/11/23 02:08 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)0.50 ug/L 04/11/23 02:08 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/11/23 02:08 75-09-2 L12.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/11/23 02:08 1634-04-40.50 0.42 1
Naphthalene 1.1J ug/L 04/11/23 02:08 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/11/23 02:08 103-65-10.50 0.34 1
Styrene ND ug/L 04/11/23 02:08 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/11/23 02:08 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-7 Lab ID:92660072006 Collected:03/30/23 16:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/11/23 02:08 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/11/23 02:08 127-18-40.50 0.29 1
Toluene ND ug/L 04/11/23 02:08 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/11/23 02:08 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/11/23 02:08 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/11/23 02:08 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/11/23 02:08 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/11/23 02:08 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/11/23 02:08 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/11/23 02:08 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 5.8 ug/L 04/11/23 02:08 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 3.2 ug/L 04/11/23 02:08 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/11/23 02:08 75-01-41.0 0.39 1
m&p-Xylene 5.0 ug/L 04/11/23 02:08 179601-23-11.0 0.71 1
o-Xylene 1.7 ug/L 04/11/23 02:08 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)95 %04/11/23 02:08 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %04/11/23 02:08 460-00-470-130 1
Toluene-d8 (S)100 %04/11/23 02:08 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 8.3 mg/L 04/06/23 00:10 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-8 Lab ID:92660072007 Collected:03/31/23 12:20 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/08/23 01:40 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/08/23 01:40 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/08/23 01:40 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/08/23 01:40 75-27-40.50 0.31 1
Bromoform ND ug/L 04/08/23 01:40 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/08/23 01:40 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/08/23 01:40 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/08/23 01:40 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/08/23 01:40 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/08/23 01:40 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/08/23 01:40 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/08/23 01:40 75-00-31.0 0.65 1
Chloroform ND ug/L 04/08/23 01:40 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/08/23 01:40 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/08/23 01:40 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/08/23 01:40 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 01:40 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/08/23 01:40 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 01:40 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/08/23 01:40 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/08/23 01:40 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/08/23 01:40 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/08/23 01:40 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/08/23 01:40 75-71-8 L10.50 0.35 1
1,1-Dichloroethane ND ug/L 04/08/23 01:40 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/08/23 01:40 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/08/23 01:40 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/08/23 01:40 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/08/23 01:40 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/08/23 01:40 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/08/23 01:40 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/08/23 01:40 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/08/23 01:40 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/08/23 01:40 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/08/23 01:40 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/08/23 01:40 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/08/23 01:40 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/08/23 01:40 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)0.64 ug/L 04/08/23 01:40 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/08/23 01:40 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/08/23 01:40 1634-04-40.50 0.42 1
Naphthalene 1.2J ug/L 04/08/23 01:40 91-20-3 C82.0 0.64 1
n-Propylbenzene ND ug/L 04/08/23 01:40 103-65-10.50 0.34 1
Styrene ND ug/L 04/08/23 01:40 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 01:40 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-8 Lab ID:92660072007 Collected:03/31/23 12:20 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 01:40 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/08/23 01:40 127-18-40.50 0.29 1
Toluene ND ug/L 04/08/23 01:40 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/08/23 01:40 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/08/23 01:40 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/08/23 01:40 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/08/23 01:40 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/08/23 01:40 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/08/23 01:40 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/08/23 01:40 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/08/23 01:40 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/08/23 01:40 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/08/23 01:40 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/08/23 01:40 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/08/23 01:40 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %04/08/23 01:40 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/08/23 01:40 460-00-470-130 1
Toluene-d8 (S)99 %04/08/23 01:40 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 51.3 mg/L 04/06/23 00:28 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-9 Lab ID:92660072008 Collected:03/31/23 13:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/08/23 01:58 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/08/23 01:58 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/08/23 01:58 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/08/23 01:58 75-27-40.50 0.31 1
Bromoform ND ug/L 04/08/23 01:58 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/08/23 01:58 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/08/23 01:58 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/08/23 01:58 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/08/23 01:58 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/08/23 01:58 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/08/23 01:58 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/08/23 01:58 75-00-31.0 0.65 1
Chloroform ND ug/L 04/08/23 01:58 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/08/23 01:58 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/08/23 01:58 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/08/23 01:58 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 01:58 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/08/23 01:58 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 01:58 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/08/23 01:58 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/08/23 01:58 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/08/23 01:58 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/08/23 01:58 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/08/23 01:58 75-71-8 L10.50 0.35 1
1,1-Dichloroethane ND ug/L 04/08/23 01:58 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/08/23 01:58 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/08/23 01:58 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/08/23 01:58 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/08/23 01:58 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/08/23 01:58 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/08/23 01:58 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/08/23 01:58 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/08/23 01:58 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/08/23 01:58 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/08/23 01:58 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/08/23 01:58 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/08/23 01:58 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/08/23 01:58 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 04/08/23 01:58 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/08/23 01:58 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/08/23 01:58 1634-04-40.50 0.42 1
Naphthalene ND ug/L 04/08/23 01:58 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/08/23 01:58 103-65-10.50 0.34 1
Styrene ND ug/L 04/08/23 01:58 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 01:58 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-9 Lab ID:92660072008 Collected:03/31/23 13:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 01:58 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/08/23 01:58 127-18-40.50 0.29 1
Toluene ND ug/L 04/08/23 01:58 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/08/23 01:58 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/08/23 01:58 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/08/23 01:58 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/08/23 01:58 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/08/23 01:58 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/08/23 01:58 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/08/23 01:58 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/08/23 01:58 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/08/23 01:58 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/08/23 01:58 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/08/23 01:58 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/08/23 01:58 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)92 %04/08/23 01:58 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/08/23 01:58 460-00-470-130 1
Toluene-d8 (S)99 %04/08/23 01:58 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 5.7 mg/L 04/06/23 00:45 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-10 Lab ID:92660072009 Collected:03/30/23 14:50 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/08/23 02:16 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/08/23 02:16 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/08/23 02:16 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/08/23 02:16 75-27-40.50 0.31 1
Bromoform ND ug/L 04/08/23 02:16 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/08/23 02:16 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/08/23 02:16 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/08/23 02:16 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/08/23 02:16 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/08/23 02:16 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/08/23 02:16 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/08/23 02:16 75-00-31.0 0.65 1
Chloroform ND ug/L 04/08/23 02:16 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/08/23 02:16 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/08/23 02:16 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/08/23 02:16 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 02:16 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/08/23 02:16 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 02:16 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/08/23 02:16 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/08/23 02:16 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/08/23 02:16 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/08/23 02:16 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/08/23 02:16 75-71-8 L10.50 0.35 1
1,1-Dichloroethane ND ug/L 04/08/23 02:16 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/08/23 02:16 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/08/23 02:16 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/08/23 02:16 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/08/23 02:16 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/08/23 02:16 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/08/23 02:16 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/08/23 02:16 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/08/23 02:16 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/08/23 02:16 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/08/23 02:16 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/08/23 02:16 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/08/23 02:16 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/08/23 02:16 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 04/08/23 02:16 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/08/23 02:16 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/08/23 02:16 1634-04-40.50 0.42 1
Naphthalene ND ug/L 04/08/23 02:16 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/08/23 02:16 103-65-10.50 0.34 1
Styrene ND ug/L 04/08/23 02:16 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 02:16 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-10 Lab ID:92660072009 Collected:03/30/23 14:50 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 02:16 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/08/23 02:16 127-18-40.50 0.29 1
Toluene ND ug/L 04/08/23 02:16 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/08/23 02:16 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/08/23 02:16 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/08/23 02:16 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/08/23 02:16 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/08/23 02:16 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/08/23 02:16 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/08/23 02:16 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/08/23 02:16 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/08/23 02:16 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/08/23 02:16 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/08/23 02:16 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/08/23 02:16 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)96 %04/08/23 02:16 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %04/08/23 02:16 460-00-470-130 1
Toluene-d8 (S)100 %04/08/23 02:16 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 5.0 mg/L 04/06/23 01:01 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-11 Lab ID:92660072010 Collected:03/31/23 13:25 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 30.5 ug/L 04/08/23 02:34 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/08/23 02:34 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/08/23 02:34 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/08/23 02:34 75-27-40.50 0.31 1
Bromoform ND ug/L 04/08/23 02:34 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/08/23 02:34 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/08/23 02:34 104-51-80.50 0.49 1
sec-Butylbenzene 0.96 ug/L 04/08/23 02:34 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/08/23 02:34 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/08/23 02:34 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/08/23 02:34 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/08/23 02:34 75-00-31.0 0.65 1
Chloroform ND ug/L 04/08/23 02:34 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/08/23 02:34 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/08/23 02:34 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/08/23 02:34 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 02:34 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/08/23 02:34 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 02:34 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/08/23 02:34 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/08/23 02:34 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/08/23 02:34 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/08/23 02:34 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/08/23 02:34 75-71-8 L10.50 0.35 1
1,1-Dichloroethane ND ug/L 04/08/23 02:34 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/08/23 02:34 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/08/23 02:34 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/08/23 02:34 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/08/23 02:34 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/08/23 02:34 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/08/23 02:34 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/08/23 02:34 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/08/23 02:34 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/08/23 02:34 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/08/23 02:34 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/08/23 02:34 108-20-30.50 0.31 1
Ethylbenzene 8.9 ug/L 04/08/23 02:34 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/08/23 02:34 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)3.2 ug/L 04/08/23 02:34 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/08/23 02:34 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/08/23 02:34 1634-04-40.50 0.42 1
Naphthalene 9.0 ug/L 04/08/23 02:34 91-20-32.0 0.64 1
n-Propylbenzene 1.8 ug/L 04/08/23 02:34 103-65-10.50 0.34 1
Styrene ND ug/L 04/08/23 02:34 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 02:34 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-11 Lab ID:92660072010 Collected:03/31/23 13:25 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 02:34 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/08/23 02:34 127-18-40.50 0.29 1
Toluene 0.82 ug/L 04/08/23 02:34 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/08/23 02:34 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/08/23 02:34 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/08/23 02:34 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/08/23 02:34 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/08/23 02:34 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/08/23 02:34 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/08/23 02:34 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/08/23 02:34 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/08/23 02:34 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/08/23 02:34 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/08/23 02:34 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/08/23 02:34 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %04/08/23 02:34 17060-07-070-130 1
4-Bromofluorobenzene (S)95 %04/08/23 02:34 460-00-470-130 1
Toluene-d8 (S)98 %04/08/23 02:34 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 39.5 mg/L 04/06/23 01:17 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-12 Lab ID:92660072011 Collected:03/30/23 13:05 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/08/23 02:52 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/08/23 02:52 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/08/23 02:52 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/08/23 02:52 75-27-40.50 0.31 1
Bromoform ND ug/L 04/08/23 02:52 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/08/23 02:52 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/08/23 02:52 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/08/23 02:52 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/08/23 02:52 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/08/23 02:52 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/08/23 02:52 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/08/23 02:52 75-00-31.0 0.65 1
Chloroform ND ug/L 04/08/23 02:52 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/08/23 02:52 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/08/23 02:52 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/08/23 02:52 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 02:52 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/08/23 02:52 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 02:52 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/08/23 02:52 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/08/23 02:52 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/08/23 02:52 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/08/23 02:52 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/08/23 02:52 75-71-8 L10.50 0.35 1
1,1-Dichloroethane ND ug/L 04/08/23 02:52 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/08/23 02:52 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/08/23 02:52 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/08/23 02:52 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/08/23 02:52 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/08/23 02:52 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/08/23 02:52 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/08/23 02:52 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/08/23 02:52 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/08/23 02:52 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/08/23 02:52 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/08/23 02:52 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/08/23 02:52 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/08/23 02:52 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 04/08/23 02:52 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/08/23 02:52 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/08/23 02:52 1634-04-40.50 0.42 1
Naphthalene ND ug/L 04/08/23 02:52 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/08/23 02:52 103-65-10.50 0.34 1
Styrene ND ug/L 04/08/23 02:52 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 02:52 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:MW-12 Lab ID:92660072011 Collected:03/30/23 13:05 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 02:52 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/08/23 02:52 127-18-40.50 0.29 1
Toluene ND ug/L 04/08/23 02:52 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/08/23 02:52 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/08/23 02:52 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/08/23 02:52 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/08/23 02:52 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/08/23 02:52 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/08/23 02:52 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/08/23 02:52 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/08/23 02:52 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/08/23 02:52 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/08/23 02:52 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/08/23 02:52 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/08/23 02:52 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)93 %04/08/23 02:52 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/08/23 02:52 460-00-470-130 1
Toluene-d8 (S)101 %04/08/23 02:52 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 3.6 mg/L 04/06/23 01:34 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:RW-1 Lab ID:92660072012 Collected:03/30/23 14:05 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 3.4 ug/L 04/08/23 03:09 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/08/23 03:09 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/08/23 03:09 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/08/23 03:09 75-27-40.50 0.31 1
Bromoform ND ug/L 04/08/23 03:09 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/08/23 03:09 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/08/23 03:09 104-51-80.50 0.49 1
sec-Butylbenzene 1.8 ug/L 04/08/23 03:09 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/08/23 03:09 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/08/23 03:09 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/08/23 03:09 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/08/23 03:09 75-00-31.0 0.65 1
Chloroform ND ug/L 04/08/23 03:09 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/08/23 03:09 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/08/23 03:09 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/08/23 03:09 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/08/23 03:09 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/08/23 03:09 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/08/23 03:09 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/08/23 03:09 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/08/23 03:09 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/08/23 03:09 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/08/23 03:09 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/08/23 03:09 75-71-8 L10.50 0.35 1
1,1-Dichloroethane ND ug/L 04/08/23 03:09 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/08/23 03:09 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/08/23 03:09 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/08/23 03:09 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/08/23 03:09 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/08/23 03:09 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/08/23 03:09 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/08/23 03:09 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/08/23 03:09 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/08/23 03:09 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/08/23 03:09 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/08/23 03:09 108-20-30.50 0.31 1
Ethylbenzene 1.9 ug/L 04/08/23 03:09 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/08/23 03:09 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)0.47J ug/L 04/08/23 03:09 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/08/23 03:09 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/08/23 03:09 1634-04-40.50 0.42 1
Naphthalene 2.0J ug/L 04/08/23 03:09 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/08/23 03:09 103-65-10.50 0.34 1
Styrene ND ug/L 04/08/23 03:09 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/08/23 03:09 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:RW-1 Lab ID:92660072012 Collected:03/30/23 14:05 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/08/23 03:09 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/08/23 03:09 127-18-40.50 0.29 1
Toluene 4.8 ug/L 04/08/23 03:09 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/08/23 03:09 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/08/23 03:09 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/08/23 03:09 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/08/23 03:09 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/08/23 03:09 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/08/23 03:09 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/08/23 03:09 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 1.9 ug/L 04/08/23 03:09 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 0.53 ug/L 04/08/23 03:09 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/08/23 03:09 75-01-41.0 0.39 1
m&p-Xylene 6.1 ug/L 04/08/23 03:09 179601-23-11.0 0.71 1
o-Xylene 3.1 ug/L 04/08/23 03:09 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %04/08/23 03:09 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %04/08/23 03:09 460-00-470-130 1
Toluene-d8 (S)100 %04/08/23 03:09 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 163 mg/L 04/06/23 05:12 14808-79-83.0 1.5 3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:RW-2 Lab ID:92660072013 Collected:03/30/23 13:40 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 170 ug/L 04/10/23 18:24 71-43-210.0 6.9 20
Bromobenzene ND ug/L 04/10/23 18:24 108-86-110.0 5.8 20
Bromochloromethane ND ug/L 04/10/23 18:24 74-97-510.0 9.4 20
Bromodichloromethane ND ug/L 04/10/23 18:24 75-27-410.0 6.1 20
Bromoform ND ug/L 04/10/23 18:24 75-25-210.0 6.8 20
Bromomethane ND ug/L 04/10/23 18:24 74-83-910033.2 20
n-Butylbenzene ND ug/L 04/10/23 18:24 104-51-810.0 9.8 20
sec-Butylbenzene ND ug/L 04/10/23 18:24 135-98-810.0 8.0 20
tert-Butylbenzene ND ug/L 04/10/23 18:24 98-06-610.0 6.5 20
Carbon tetrachloride ND ug/L 04/10/23 18:24 56-23-510.0 6.7 20
Chlorobenzene ND ug/L 04/10/23 18:24 108-90-710.0 5.7 20
Chloroethane ND ug/L 04/10/23 18:24 75-00-320.0 13.0 20
Chloroform ND ug/L 04/10/23 18:24 67-66-310.0 8.6 20
Chloromethane ND ug/L 04/10/23 18:24 74-87-320.0 10.8 20
2-Chlorotoluene ND ug/L 04/10/23 18:24 95-49-810.0 6.4 20
4-Chlorotoluene ND ug/L 04/10/23 18:24 106-43-410.0 6.5 20
1,2-Dibromo-3-chloropropane ND ug/L 04/10/23 18:24 96-12-820.0 6.8 20
Dibromochloromethane ND ug/L 04/10/23 18:24 124-48-110.0 7.2 20
1,2-Dibromoethane (EDB)ND ug/L 04/10/23 18:24 106-93-410.0 5.4 20
Dibromomethane ND ug/L 04/10/23 18:24 74-95-310.0 7.9 20
1,2-Dichlorobenzene ND ug/L 04/10/23 18:24 95-50-110.0 6.8 20
1,3-Dichlorobenzene ND ug/L 04/10/23 18:24 541-73-110.0 6.8 20
1,4-Dichlorobenzene ND ug/L 04/10/23 18:24 106-46-710.0 6.7 20
Dichlorodifluoromethane ND ug/L 04/10/23 18:24 75-71-8 L110.0 6.9 20
1,1-Dichloroethane ND ug/L 04/10/23 18:24 75-34-310.0 7.3 20
1,2-Dichloroethane ND ug/L 04/10/23 18:24 107-06-210.0 6.4 20
1,1-Dichloroethene ND ug/L 04/10/23 18:24 75-35-410.0 7.0 20
cis-1,2-Dichloroethene ND ug/L 04/10/23 18:24 156-59-210.0 7.7 20
trans-1,2-Dichloroethene ND ug/L 04/10/23 18:24 156-60-510.0 7.9 20
1,2-Dichloropropane ND ug/L 04/10/23 18:24 78-87-510.0 7.1 20
1,3-Dichloropropane ND ug/L 04/10/23 18:24 142-28-910.0 5.7 20
2,2-Dichloropropane ND ug/L 04/10/23 18:24 594-20-710.0 7.8 20
1,1-Dichloropropene ND ug/L 04/10/23 18:24 563-58-610.0 8.5 20
cis-1,3-Dichloropropene ND ug/L 04/10/23 18:24 10061-01-510.0 7.3 20
trans-1,3-Dichloropropene ND ug/L 04/10/23 18:24 10061-02-610.0 7.3 20
Diisopropyl ether ND ug/L 04/10/23 18:24 108-20-310.0 6.2 20
Ethylbenzene 558 ug/L 04/10/23 18:24 100-41-410.0 6.1 20
Hexachloro-1,3-butadiene ND ug/L 04/10/23 18:24 87-68-340.0 30.6 20
Isopropylbenzene (Cumene)21.6 ug/L 04/10/23 18:24 98-82-810.0 6.7 20
Methylene Chloride 236 ug/L 04/10/23 18:24 75-09-2 C940.0 39.0 20
Methyl-tert-butyl ether ND ug/L 04/10/23 18:24 1634-04-410.0 8.4 20
Naphthalene 187 ug/L 04/10/23 18:24 91-20-340.0 12.9 20
n-Propylbenzene 51.4 ug/L 04/10/23 18:24 103-65-110.0 6.8 20
Styrene ND ug/L 04/10/23 18:24 100-42-510.0 5.8 20
1,1,1,2-Tetrachloroethane ND ug/L 04/10/23 18:24 630-20-610.0 6.2 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:RW-2 Lab ID:92660072013 Collected:03/30/23 13:40 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/10/23 18:24 79-34-510.0 4.5 20
Tetrachloroethene ND ug/L 04/10/23 18:24 127-18-410.0 5.8 20
Toluene 2470 ug/L 04/10/23 18:24 108-88-310.0 4.8 20
1,2,3-Trichlorobenzene ND ug/L 04/10/23 18:24 87-61-640.0 16.1 20
1,2,4-Trichlorobenzene ND ug/L 04/10/23 18:24 120-82-140.0 12.8 20
1,1,1-Trichloroethane ND ug/L 04/10/23 18:24 71-55-610.0 6.6 20
1,1,2-Trichloroethane ND ug/L 04/10/23 18:24 79-00-510.0 6.5 20
Trichloroethene ND ug/L 04/10/23 18:24 79-01-610.0 7.7 20
Trichlorofluoromethane ND ug/L 04/10/23 18:24 75-69-420.0 6.0 20
1,2,3-Trichloropropane ND ug/L 04/10/23 18:24 96-18-410.0 5.2 20
1,2,4-Trimethylbenzene 523 ug/L 04/10/23 18:24 95-63-610.0 9.9 20
1,3,5-Trimethylbenzene 138 ug/L 04/10/23 18:24 108-67-810.0 6.6 20
Vinyl chloride ND ug/L 04/10/23 18:24 75-01-420.0 7.7 20
m&p-Xylene 1880 ug/L 04/10/23 18:24 179601-23-120.0 14.2 20
o-Xylene 1030 ug/L 04/10/23 18:24 95-47-610.0 6.8 20
Surrogates
1,2-Dichloroethane-d4 (S)92 %04/10/23 18:24 17060-07-070-130 20
4-Bromofluorobenzene (S)100 %04/10/23 18:24 460-00-470-130 20
Toluene-d8 (S)99 %04/10/23 18:24 2037-26-570-130 20
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 8.2 mg/L 04/06/23 03:18 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:VEW-1 Lab ID:92660072014 Collected:03/31/23 13:50 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 139 ug/L 04/10/23 19:18 71-43-26.2 4.3 12.5
Bromobenzene ND ug/L 04/10/23 19:18 108-86-16.2 3.6 12.5
Bromochloromethane ND ug/L 04/10/23 19:18 74-97-56.2 5.8 12.5
Bromodichloromethane ND ug/L 04/10/23 19:18 75-27-46.2 3.8 12.5
Bromoform ND ug/L 04/10/23 19:18 75-25-26.2 4.3 12.5
Bromomethane ND ug/L 04/10/23 19:18 74-83-962.5 20.8 12.5
n-Butylbenzene ND ug/L 04/10/23 19:18 104-51-86.2 6.1 12.5
sec-Butylbenzene ND ug/L 04/10/23 19:18 135-98-86.2 5.0 12.5
tert-Butylbenzene ND ug/L 04/10/23 19:18 98-06-66.2 4.0 12.5
Carbon tetrachloride ND ug/L 04/10/23 19:18 56-23-56.2 4.2 12.5
Chlorobenzene ND ug/L 04/10/23 19:18 108-90-76.2 3.6 12.5
Chloroethane ND ug/L 04/10/23 19:18 75-00-312.5 8.1 12.5
Chloroform ND ug/L 04/10/23 19:18 67-66-36.2 5.4 12.5
Chloromethane ND ug/L 04/10/23 19:18 74-87-312.5 6.8 12.5
2-Chlorotoluene ND ug/L 04/10/23 19:18 95-49-86.2 4.0 12.5
4-Chlorotoluene ND ug/L 04/10/23 19:18 106-43-46.2 4.0 12.5
1,2-Dibromo-3-chloropropane ND ug/L 04/10/23 19:18 96-12-812.5 4.2 12.5
Dibromochloromethane ND ug/L 04/10/23 19:18 124-48-16.2 4.5 12.5
1,2-Dibromoethane (EDB)ND ug/L 04/10/23 19:18 106-93-46.2 3.4 12.5
Dibromomethane ND ug/L 04/10/23 19:18 74-95-36.2 4.9 12.5
1,2-Dichlorobenzene ND ug/L 04/10/23 19:18 95-50-16.2 4.2 12.5
1,3-Dichlorobenzene ND ug/L 04/10/23 19:18 541-73-16.2 4.2 12.5
1,4-Dichlorobenzene ND ug/L 04/10/23 19:18 106-46-76.2 4.2 12.5
Dichlorodifluoromethane ND ug/L 04/10/23 19:18 75-71-8 L16.2 4.3 12.5
1,1-Dichloroethane ND ug/L 04/10/23 19:18 75-34-36.2 4.6 12.5
1,2-Dichloroethane ND ug/L 04/10/23 19:18 107-06-26.2 4.0 12.5
1,1-Dichloroethene ND ug/L 04/10/23 19:18 75-35-46.2 4.4 12.5
cis-1,2-Dichloroethene ND ug/L 04/10/23 19:18 156-59-26.2 4.8 12.5
trans-1,2-Dichloroethene ND ug/L 04/10/23 19:18 156-60-56.2 5.0 12.5
1,2-Dichloropropane ND ug/L 04/10/23 19:18 78-87-56.2 4.4 12.5
1,3-Dichloropropane ND ug/L 04/10/23 19:18 142-28-96.2 3.6 12.5
2,2-Dichloropropane ND ug/L 04/10/23 19:18 594-20-76.2 4.8 12.5
1,1-Dichloropropene ND ug/L 04/10/23 19:18 563-58-66.2 5.3 12.5
cis-1,3-Dichloropropene ND ug/L 04/10/23 19:18 10061-01-56.2 4.6 12.5
trans-1,3-Dichloropropene ND ug/L 04/10/23 19:18 10061-02-66.2 4.5 12.5
Diisopropyl ether ND ug/L 04/10/23 19:18 108-20-36.2 3.8 12.5
Ethylbenzene 899 ug/L 04/10/23 19:18 100-41-46.2 3.8 12.5
Hexachloro-1,3-butadiene ND ug/L 04/10/23 19:18 87-68-325.0 19.1 12.5
Isopropylbenzene (Cumene)55.3 ug/L 04/10/23 19:18 98-82-86.2 4.2 12.5
Methylene Chloride 139 ug/L 04/10/23 19:18 75-09-2 C925.0 24.4 12.5
Methyl-tert-butyl ether ND ug/L 04/10/23 19:18 1634-04-46.2 5.3 12.5
Naphthalene 406 ug/L 04/10/23 19:18 91-20-325.0 8.1 12.5
n-Propylbenzene 152 ug/L 04/10/23 19:18 103-65-16.2 4.2 12.5
Styrene ND ug/L 04/10/23 19:18 100-42-56.2 3.6 12.5
1,1,1,2-Tetrachloroethane ND ug/L 04/10/23 19:18 630-20-66.2 3.9 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:VEW-1 Lab ID:92660072014 Collected:03/31/23 13:50 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/10/23 19:18 79-34-56.2 2.8 12.5
Tetrachloroethene ND ug/L 04/10/23 19:18 127-18-46.2 3.6 12.5
Toluene 891 ug/L 04/10/23 19:18 108-88-36.2 3.0 12.5
1,2,3-Trichlorobenzene ND ug/L 04/10/23 19:18 87-61-625.0 10.1 12.5
1,2,4-Trichlorobenzene ND ug/L 04/10/23 19:18 120-82-125.0 8.0 12.5
1,1,1-Trichloroethane ND ug/L 04/10/23 19:18 71-55-66.2 4.2 12.5
1,1,2-Trichloroethane ND ug/L 04/10/23 19:18 79-00-56.2 4.1 12.5
Trichloroethene ND ug/L 04/10/23 19:18 79-01-66.2 4.8 12.5
Trichlorofluoromethane ND ug/L 04/10/23 19:18 75-69-412.5 3.7 12.5
1,2,3-Trichloropropane ND ug/L 04/10/23 19:18 96-18-46.2 3.3 12.5
1,2,4-Trimethylbenzene 1220 ug/L 04/10/23 19:18 95-63-66.2 6.2 12.5
1,3,5-Trimethylbenzene 324 ug/L 04/10/23 19:18 108-67-86.2 4.2 12.5
Vinyl chloride ND ug/L 04/10/23 19:18 75-01-412.5 4.8 12.5
m&p-Xylene 1450 ug/L 04/10/23 19:18 179601-23-112.5 8.9 12.5
o-Xylene 529 ug/L 04/10/23 19:18 95-47-66.2 4.2 12.5
Surrogates
1,2-Dichloroethane-d4 (S)92 %04/10/23 19:18 17060-07-070-130 12.5
4-Bromofluorobenzene (S)98 %04/10/23 19:18 460-00-470-130 12.5
Toluene-d8 (S)101 %04/10/23 19:18 2037-26-570-130 12.5
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 0.68J mg/L 04/05/23 02:20 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:VEW-2 Lab ID:92660072015 Collected:03/31/23 14:20 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/11/23 03:20 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/11/23 03:20 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/11/23 03:20 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/11/23 03:20 75-27-40.50 0.31 1
Bromoform ND ug/L 04/11/23 03:20 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/11/23 03:20 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/11/23 03:20 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/11/23 03:20 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/11/23 03:20 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/11/23 03:20 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/11/23 03:20 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/11/23 03:20 75-00-31.0 0.65 1
Chloroform ND ug/L 04/11/23 03:20 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/11/23 03:20 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/11/23 03:20 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/11/23 03:20 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/11/23 03:20 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/11/23 03:20 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/11/23 03:20 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/11/23 03:20 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/11/23 03:20 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/11/23 03:20 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/11/23 03:20 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/11/23 03:20 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 04/11/23 03:20 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/11/23 03:20 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/11/23 03:20 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/11/23 03:20 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/11/23 03:20 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/11/23 03:20 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/11/23 03:20 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/11/23 03:20 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/11/23 03:20 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/11/23 03:20 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/11/23 03:20 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/11/23 03:20 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/11/23 03:20 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/11/23 03:20 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 04/11/23 03:20 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/11/23 03:20 75-09-2 L12.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/11/23 03:20 1634-04-40.50 0.42 1
Naphthalene ND ug/L 04/11/23 03:20 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/11/23 03:20 103-65-10.50 0.34 1
Styrene ND ug/L 04/11/23 03:20 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/11/23 03:20 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:VEW-2 Lab ID:92660072015 Collected:03/31/23 14:20 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/11/23 03:20 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/11/23 03:20 127-18-40.50 0.29 1
Toluene ND ug/L 04/11/23 03:20 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/11/23 03:20 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/11/23 03:20 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/11/23 03:20 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/11/23 03:20 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/11/23 03:20 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/11/23 03:20 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/11/23 03:20 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/11/23 03:20 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/11/23 03:20 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/11/23 03:20 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/11/23 03:20 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/11/23 03:20 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %04/11/23 03:20 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %04/11/23 03:20 460-00-470-130 1
Toluene-d8 (S)101 %04/11/23 03:20 2037-26-570-130 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 19.6 mg/L 04/05/23 03:07 14808-79-81.0 0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:FIELD BLANK Lab ID:92660072016 Collected:03/30/23 00:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/07/23 15:15 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/07/23 15:15 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/07/23 15:15 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/07/23 15:15 75-27-40.50 0.31 1
Bromoform ND ug/L 04/07/23 15:15 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/07/23 15:15 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/07/23 15:15 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/07/23 15:15 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/07/23 15:15 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/07/23 15:15 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/07/23 15:15 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/07/23 15:15 75-00-31.0 0.65 1
Chloroform ND ug/L 04/07/23 15:15 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/07/23 15:15 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/07/23 15:15 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/07/23 15:15 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/07/23 15:15 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/07/23 15:15 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/07/23 15:15 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/07/23 15:15 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/07/23 15:15 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/07/23 15:15 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/07/23 15:15 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/07/23 15:15 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 04/07/23 15:15 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/07/23 15:15 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/07/23 15:15 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/07/23 15:15 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/07/23 15:15 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/07/23 15:15 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/07/23 15:15 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/07/23 15:15 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/07/23 15:15 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/07/23 15:15 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/07/23 15:15 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/07/23 15:15 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/07/23 15:15 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/07/23 15:15 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 04/07/23 15:15 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/07/23 15:15 75-09-2 L12.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/07/23 15:15 1634-04-40.50 0.42 1
Naphthalene ND ug/L 04/07/23 15:15 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/07/23 15:15 103-65-10.50 0.34 1
Styrene ND ug/L 04/07/23 15:15 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/07/23 15:15 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:FIELD BLANK Lab ID:92660072016 Collected:03/30/23 00:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/07/23 15:15 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/07/23 15:15 127-18-40.50 0.29 1
Toluene ND ug/L 04/07/23 15:15 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/07/23 15:15 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/07/23 15:15 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/07/23 15:15 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/07/23 15:15 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/07/23 15:15 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/07/23 15:15 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/07/23 15:15 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/07/23 15:15 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/07/23 15:15 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/07/23 15:15 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/07/23 15:15 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/07/23 15:15 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)93 %04/07/23 15:15 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %04/07/23 15:15 460-00-470-130 1
Toluene-d8 (S)100 %04/07/23 15:15 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:TRIP BLANK Lab ID:92660072017 Collected:03/30/23 00:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 04/07/23 15:33 71-43-20.50 0.34 1
Bromobenzene ND ug/L 04/07/23 15:33 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 04/07/23 15:33 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 04/07/23 15:33 75-27-40.50 0.31 1
Bromoform ND ug/L 04/07/23 15:33 75-25-20.50 0.34 1
Bromomethane ND ug/L 04/07/23 15:33 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 04/07/23 15:33 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 04/07/23 15:33 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 04/07/23 15:33 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 04/07/23 15:33 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 04/07/23 15:33 108-90-70.50 0.28 1
Chloroethane ND ug/L 04/07/23 15:33 75-00-31.0 0.65 1
Chloroform ND ug/L 04/07/23 15:33 67-66-30.50 0.43 1
Chloromethane ND ug/L 04/07/23 15:33 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 04/07/23 15:33 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 04/07/23 15:33 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 04/07/23 15:33 96-12-81.0 0.34 1
Dibromochloromethane ND ug/L 04/07/23 15:33 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 04/07/23 15:33 106-93-40.50 0.27 1
Dibromomethane ND ug/L 04/07/23 15:33 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 04/07/23 15:33 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 04/07/23 15:33 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 04/07/23 15:33 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 04/07/23 15:33 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 04/07/23 15:33 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 04/07/23 15:33 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 04/07/23 15:33 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 04/07/23 15:33 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 04/07/23 15:33 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 04/07/23 15:33 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 04/07/23 15:33 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 04/07/23 15:33 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 04/07/23 15:33 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 04/07/23 15:33 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 04/07/23 15:33 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 04/07/23 15:33 108-20-30.50 0.31 1
Ethylbenzene ND ug/L 04/07/23 15:33 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 04/07/23 15:33 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)ND ug/L 04/07/23 15:33 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 04/07/23 15:33 75-09-2 L12.0 2.0 1
Methyl-tert-butyl ether ND ug/L 04/07/23 15:33 1634-04-40.50 0.42 1
Naphthalene ND ug/L 04/07/23 15:33 91-20-32.0 0.64 1
n-Propylbenzene ND ug/L 04/07/23 15:33 103-65-10.50 0.34 1
Styrene ND ug/L 04/07/23 15:33 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 04/07/23 15:33 630-20-60.50 0.31 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Sample:TRIP BLANK Lab ID:92660072017 Collected:03/30/23 00:00 Received:04/01/23 12:52 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1,2,2-Tetrachloroethane ND ug/L 04/07/23 15:33 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 04/07/23 15:33 127-18-40.50 0.29 1
Toluene ND ug/L 04/07/23 15:33 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 04/07/23 15:33 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 04/07/23 15:33 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 04/07/23 15:33 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 04/07/23 15:33 79-00-50.50 0.32 1
Trichloroethene ND ug/L 04/07/23 15:33 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 04/07/23 15:33 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 04/07/23 15:33 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene ND ug/L 04/07/23 15:33 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene ND ug/L 04/07/23 15:33 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 04/07/23 15:33 75-01-41.0 0.39 1
m&p-Xylene ND ug/L 04/07/23 15:33 179601-23-11.0 0.71 1
o-Xylene ND ug/L 04/07/23 15:33 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)94 %04/07/23 15:33 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %04/07/23 15:33 460-00-470-130 1
Toluene-d8 (S)100 %04/07/23 15:33 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
766100
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92660072002, 92660072003, 92660072005, 92660072007, 92660072008, 92660072009, 92660072010,
92660072011, 92660072012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3977658
Associated Lab Samples:92660072002, 92660072003, 92660072005, 92660072007, 92660072008, 92660072009, 92660072010,
92660072011, 92660072012
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/08/23 00:100.31
1,1,1-Trichloroethane ug/L ND 0.50 04/08/23 00:100.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/08/23 00:100.22
1,1,2-Trichloroethane ug/L ND 0.50 04/08/23 00:100.32
1,1-Dichloroethane ug/L ND 0.50 04/08/23 00:100.37
1,1-Dichloroethene ug/L ND 0.50 04/08/23 00:100.35
1,1-Dichloropropene ug/L ND 0.50 04/08/23 00:100.43
1,2,3-Trichlorobenzene ug/L ND 2.0 04/08/23 00:100.81
1,2,3-Trichloropropane ug/L ND 0.50 04/08/23 00:100.26
1,2,4-Trichlorobenzene ug/L ND 2.0 04/08/23 00:100.64
1,2,4-Trimethylbenzene ug/L ND 0.50 04/08/23 00:100.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/08/23 00:100.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/08/23 00:100.27
1,2-Dichlorobenzene ug/L ND 0.50 04/08/23 00:100.34
1,2-Dichloroethane ug/L ND 0.50 04/08/23 00:100.32
1,2-Dichloropropane ug/L ND 0.50 04/08/23 00:100.36
1,3,5-Trimethylbenzene ug/L ND 0.50 04/08/23 00:100.33
1,3-Dichlorobenzene ug/L ND 0.50 04/08/23 00:100.34
1,3-Dichloropropane ug/L ND 0.50 04/08/23 00:100.28
1,4-Dichlorobenzene ug/L ND 0.50 04/08/23 00:100.33
2,2-Dichloropropane ug/L ND 0.50 04/08/23 00:100.39
2-Chlorotoluene ug/L ND 0.50 04/08/23 00:100.32
4-Chlorotoluene ug/L ND 0.50 04/08/23 00:100.32
Benzene ug/L ND 0.50 04/08/23 00:100.34
Bromobenzene ug/L ND 0.50 04/08/23 00:100.29
Bromochloromethane ug/L ND 0.50 04/08/23 00:100.47
Bromodichloromethane ug/L ND 0.50 04/08/23 00:100.31
Bromoform ug/L ND 0.50 04/08/23 00:100.34
Bromomethane ug/L ND 5.0 04/08/23 00:101.7
Carbon tetrachloride ug/L ND 0.50 04/08/23 00:100.33
Chlorobenzene ug/L ND 0.50 04/08/23 00:100.28
Chloroethane ug/L ND 1.0 04/08/23 00:100.65
Chloroform ug/L ND 0.50 04/08/23 00:100.43
Chloromethane ug/L ND 1.0 04/08/23 00:100.54
cis-1,2-Dichloroethene ug/L ND 0.50 04/08/23 00:100.38
cis-1,3-Dichloropropene ug/L ND 0.50 04/08/23 00:100.36
Dibromochloromethane ug/L ND 0.50 04/08/23 00:100.36
Dibromomethane ug/L ND 0.50 04/08/23 00:100.39
Dichlorodifluoromethane ug/L ND 0.50 04/08/23 00:100.35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3977658
Associated Lab Samples:92660072002, 92660072003, 92660072005, 92660072007, 92660072008, 92660072009, 92660072010,
92660072011, 92660072012
Matrix:Water
AnalyzedMDL
Diisopropyl ether ug/L ND 0.50 04/08/23 00:100.31
Ethylbenzene ug/L ND 0.50 04/08/23 00:100.30
Hexachloro-1,3-butadiene ug/L ND 2.0 04/08/23 00:101.5
Isopropylbenzene (Cumene)ug/L ND 0.50 04/08/23 00:100.33
m&p-Xylene ug/L ND 1.0 04/08/23 00:100.71
Methyl-tert-butyl ether ug/L ND 0.50 04/08/23 00:100.42
Methylene Chloride ug/L ND 2.0 04/08/23 00:102.0
n-Butylbenzene ug/L ND 0.50 04/08/23 00:100.49
n-Propylbenzene ug/L ND 0.50 04/08/23 00:100.34
Naphthalene ug/L ND 2.0 04/08/23 00:100.64
o-Xylene ug/L ND 0.50 04/08/23 00:100.34
sec-Butylbenzene ug/L ND 0.50 04/08/23 00:100.40
Styrene ug/L ND 0.50 04/08/23 00:100.29
tert-Butylbenzene ug/L ND 0.50 04/08/23 00:100.32
Tetrachloroethene ug/L ND 0.50 04/08/23 00:100.29
Toluene ug/L ND 0.50 04/08/23 00:100.24
trans-1,2-Dichloroethene ug/L ND 0.50 04/08/23 00:100.40
trans-1,3-Dichloropropene ug/L ND 0.50 04/08/23 00:100.36
Trichloroethene ug/L ND 0.50 04/08/23 00:100.38
Trichlorofluoromethane ug/L ND 1.0 04/08/23 00:100.30
Vinyl chloride ug/L ND 1.0 04/08/23 00:100.39
1,2-Dichloroethane-d4 (S)%92 70-130 04/08/23 00:10
4-Bromofluorobenzene (S)%99 70-130 04/08/23 00:10
Toluene-d8 (S)%101 70-130 04/08/23 00:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3977659LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.520 108 60-140
1,1,1-Trichloroethane ug/L 20.720 103 60-140
1,1,2,2-Tetrachloroethane ug/L 20.420 102 60-140
1,1,2-Trichloroethane ug/L 22.020 110 60-140
1,1-Dichloroethane ug/L 20.620 103 60-140
1,1-Dichloroethene ug/L 22.420 112 60-140
1,1-Dichloropropene ug/L 22.220 111 60-140
1,2,3-Trichlorobenzene ug/L 20.320 102 60-140
1,2,3-Trichloropropane ug/L 19.720 98 60-140
1,2,4-Trichlorobenzene ug/L 20.320 101 60-140
1,2,4-Trimethylbenzene ug/L 20.620 103 60-140
1,2-Dibromo-3-chloropropane ug/L 18.420 92 60-140
1,2-Dibromoethane (EDB)ug/L 20.920 104 60-140
1,2-Dichlorobenzene ug/L 20.720 104 60-140
1,2-Dichloroethane ug/L 21.120 105 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3977659LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 22.520 113 60-140
1,3,5-Trimethylbenzene ug/L 20.520 102 60-140
1,3-Dichlorobenzene ug/L 21.120 106 60-140
1,3-Dichloropropane ug/L 19.920 99 60-140
1,4-Dichlorobenzene ug/L 20.420 102 60-140
2,2-Dichloropropane ug/L 19.520 98 60-140
2-Chlorotoluene ug/L 20.120 100 60-140
4-Chlorotoluene ug/L 20.320 101 60-140
Benzene ug/L 21.520 107 60-140
Bromobenzene ug/L 20.120 100 60-140
Bromochloromethane ug/L 20.720 103 60-140
Bromodichloromethane ug/L 20.520 103 60-140
Bromoform ug/L 19.720 99 60-140
Bromomethane ug/L 16.220 81 60-140
Carbon tetrachloride ug/L 22.620 113 60-140
Chlorobenzene ug/L 21.220 106 60-140
Chloroethane ug/L 20.620 103 60-140
Chloroform ug/L 19.720 99 60-140
Chloromethane ug/L 24.620 123 60-140
cis-1,2-Dichloroethene ug/L 21.220 106 60-140
cis-1,3-Dichloropropene ug/L 20.520 102 60-140
Dibromochloromethane ug/L 20.520 103 60-140
Dibromomethane ug/L 22.220 111 60-140
Dichlorodifluoromethane ug/L 28.6 L12014360-140
Diisopropyl ether ug/L 20.220 101 60-140
Ethylbenzene ug/L 20.820 104 60-140
Hexachloro-1,3-butadiene ug/L 20.720 103 60-140
Isopropylbenzene (Cumene)ug/L 21.120 106 60-140
m&p-Xylene ug/L 41.240 103 60-140
Methyl-tert-butyl ether ug/L 18.320 91 60-140
Methylene Chloride ug/L 22.120 111 60-140
n-Butylbenzene ug/L 20.020 100 60-140
n-Propylbenzene ug/L 19.720 98 60-140
Naphthalene ug/L 19.820 99 60-140
o-Xylene ug/L 20.620 103 60-140
sec-Butylbenzene ug/L 20.120 101 60-140
Styrene ug/L 21.120 105 60-140
tert-Butylbenzene ug/L 17.020 85 60-140
Tetrachloroethene ug/L 21.820 109 60-140
Toluene ug/L 20.620 103 60-140
trans-1,2-Dichloroethene ug/L 21.920 110 60-140
trans-1,3-Dichloropropene ug/L 19.820 99 60-140
Trichloroethene ug/L 23.220 116 60-140
Trichlorofluoromethane ug/L 20.020 100 60-140
Vinyl chloride ug/L 18.620 93 60-140
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3977659LABORATORY CONTROL SAMPLE:
LCSSpike
Toluene-d8 (S)%97 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3977660MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660072005
3977661
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L M12018960-140192 1 3020ND37.9 38.4
1,1,1-Trichloroethane ug/L M12019060-140195 2 3020ND38.0 39.0
1,1,2,2-Tetrachloroethane ug/L M12020060-140203 1 3020ND40.1 40.5
1,1,2-Trichloroethane ug/L M12020260-140212 5 3020ND40.5 42.4
1,1-Dichloroethane ug/L M12020760-140198 4 3020ND41.4 39.6
1,1-Dichloroethene ug/L M12022360-140213 5 3020ND44.7 42.5
1,1-Dichloropropene ug/L M12019460-140210 8 3020ND38.8 42.0
1,2,3-Trichlorobenzene ug/L M12018960-140203 7 3020ND37.9 40.5
1,2,3-Trichloropropane ug/L M12019660-140196 0 3020ND39.1 39.3
1,2,4-Trichlorobenzene ug/L M12017860-140197 10 3020ND35.5 39.4
1,2,4-Trimethylbenzene ug/L M12018960-140214 5 302050.8 88.6 93.6
1,2-Dibromo-3-
chloropropane ug/L M12016560-140181 9 3020ND32.9 36.2
1,2-Dibromoethane (EDB)ug/L M12019760-140201 2 3020ND39.5 40.2
1,2-Dichlorobenzene ug/L M12020560-140209 2 3020ND40.9 41.8
1,2-Dichloroethane ug/L M12020660-140203 1 3020ND41.3 40.7
1,2-Dichloropropane ug/L M12021560-140210 2 3020ND43.0 42.1
1,3,5-Trimethylbenzene ug/L M12018860-140200 5 302012.1 49.6 52.0
1,3-Dichlorobenzene ug/L M12020460-140204 0 3020ND40.9 40.7
1,3-Dichloropropane ug/L M12018760-140194 4 3020ND37.4 38.8
1,4-Dichlorobenzene ug/L M12021160-140207 2 3020ND42.2 41.5
2,2-Dichloropropane ug/L M12019460-140189 2 3020ND38.7 37.9
2-Chlorotoluene ug/L M12021160-140197 7 3020ND42.3 39.3
4-Chlorotoluene ug/L M12018960-140201 6 3020ND37.8 40.2
Benzene ug/L M12058860-140543 1 3020110012201210
Bromobenzene ug/L M12019060-140197 3 3020ND38.1 39.3
Bromochloromethane ug/L M12020460-140207 2 3020ND40.7 41.4
Bromodichloromethane ug/L M12018760-140191 2 3020ND37.3 38.1
Bromoform ug/L M12017860-140180 1 3020ND35.5 35.9
Bromomethane ug/L M12014260-140151 3020ND28.5J 30.2J
Carbon tetrachloride ug/L M12020060-140205 3 3020ND40.0 41.1
Chlorobenzene ug/L M12020660-140208 1 3020ND41.3 41.7
Chloroethane ug/L M12020660-140197 5 3020ND41.2 39.3
Chloroform ug/L M12020060-140196 2 3020ND40.0 39.3
Chloromethane ug/L M12026560-140258 3 3020ND53.0 51.6
cis-1,2-Dichloroethene ug/L M12020260-140206 2 3020ND40.5 41.3
cis-1,3-Dichloropropene ug/L M12018160-140187 4 3020ND36.1 37.4
Dibromochloromethane ug/L M12018460-140190 3 3020ND36.9 38.0
Dibromomethane ug/L M12022060-140221 1 3020ND44.0 44.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3977660MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660072005
3977661
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Dichlorodifluoromethane ug/L M02028060-140260 7 3020ND56.0 52.0
Diisopropyl ether ug/L M12019560-140200 2 3020ND39.0 40.0
Ethylbenzene ug/L M12022060-140226 0 3020253297298
Hexachloro-1,3-butadiene ug/L M12020460-140213 4 3020ND40.8 42.6
Isopropylbenzene
(Cumene)
ug/L M12020360-140202 1 30208.6 49.3 49.0
m&p-Xylene ug/L M14023960-140237 0 3040145240240
Methyl-tert-butyl ether ug/L M12016960-140171 1 3020ND33.9 34.3
Methylene Chloride ug/L M120-177 60-140-214 6 3020157122114
n-Butylbenzene ug/L M12019060-140198 4 3020ND38.1 39.6
n-Propylbenzene ug/L M12018260-140192 3 302021.7 58.1 60.1
Naphthalene ug/L M1209960-140176 15 302079.0 98.8 114
o-Xylene ug/L M12020460-140206 1 302036.6 77.3 77.7
sec-Butylbenzene ug/L M12019460-140202 4 3020ND38.8 40.4
Styrene ug/L M12021760-140211 2 3020ND43.3 42.3
tert-Butylbenzene ug/L M12015360-140168 9 3020ND30.6 33.6
Tetrachloroethene ug/L M12021060-140210 0 3020ND42.0 41.9
Toluene ug/L M12080960-140783 1 3020787949944
trans-1,2-Dichloroethene ug/L M12020760-140202 3 3020ND41.4 40.3
trans-1,3-Dichloropropene ug/L M12017460-140178 2 3020ND34.9 35.7
Trichloroethene ug/L M12021460-140222 4 3020ND42.7 44.4
Trichlorofluoromethane ug/L M12019460-140190 2 3020ND38.8 38.1
Vinyl chloride ug/L M12018560-140177 5 3020ND37.0 35.3
1,2-Dichloroethane-d4 (S)%96 70-13096
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%99 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
766396
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92660072016, 92660072017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3979253
Associated Lab Samples:92660072016, 92660072017
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/07/23 13:290.31
1,1,1-Trichloroethane ug/L ND 0.50 04/07/23 13:290.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/07/23 13:290.22
1,1,2-Trichloroethane ug/L ND 0.50 04/07/23 13:290.32
1,1-Dichloroethane ug/L ND 0.50 04/07/23 13:290.37
1,1-Dichloroethene ug/L ND 0.50 04/07/23 13:290.35
1,1-Dichloropropene ug/L ND 0.50 04/07/23 13:290.43
1,2,3-Trichlorobenzene ug/L ND 2.0 04/07/23 13:290.81
1,2,3-Trichloropropane ug/L ND 0.50 04/07/23 13:290.26
1,2,4-Trichlorobenzene ug/L ND 2.0 04/07/23 13:290.64
1,2,4-Trimethylbenzene ug/L ND 0.50 04/07/23 13:290.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/07/23 13:290.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/07/23 13:290.27
1,2-Dichlorobenzene ug/L ND 0.50 04/07/23 13:290.34
1,2-Dichloroethane ug/L ND 0.50 04/07/23 13:290.32
1,2-Dichloropropane ug/L ND 0.50 04/07/23 13:290.36
1,3,5-Trimethylbenzene ug/L ND 0.50 04/07/23 13:290.33
1,3-Dichlorobenzene ug/L ND 0.50 04/07/23 13:290.34
1,3-Dichloropropane ug/L ND 0.50 04/07/23 13:290.28
1,4-Dichlorobenzene ug/L ND 0.50 04/07/23 13:290.33
2,2-Dichloropropane ug/L ND 0.50 04/07/23 13:290.39
2-Chlorotoluene ug/L ND 0.50 04/07/23 13:290.32
4-Chlorotoluene ug/L ND 0.50 04/07/23 13:290.32
Benzene ug/L ND 0.50 04/07/23 13:290.34
Bromobenzene ug/L ND 0.50 04/07/23 13:290.29
Bromochloromethane ug/L ND 0.50 04/07/23 13:290.47
Bromodichloromethane ug/L ND 0.50 04/07/23 13:290.31
Bromoform ug/L ND 0.50 04/07/23 13:290.34
Bromomethane ug/L ND 5.0 04/07/23 13:291.7
Carbon tetrachloride ug/L ND 0.50 04/07/23 13:290.33
Chlorobenzene ug/L ND 0.50 04/07/23 13:290.28
Chloroethane ug/L ND 1.0 04/07/23 13:290.65
Chloroform ug/L ND 0.50 04/07/23 13:290.43
Chloromethane ug/L ND 1.0 04/07/23 13:290.54
cis-1,2-Dichloroethene ug/L ND 0.50 04/07/23 13:290.38
cis-1,3-Dichloropropene ug/L ND 0.50 04/07/23 13:290.36
Dibromochloromethane ug/L ND 0.50 04/07/23 13:290.36
Dibromomethane ug/L ND 0.50 04/07/23 13:290.39
Dichlorodifluoromethane ug/L ND 0.50 04/07/23 13:290.35
Diisopropyl ether ug/L ND 0.50 04/07/23 13:290.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3979253
Associated Lab Samples:92660072016, 92660072017
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 04/07/23 13:290.30
Hexachloro-1,3-butadiene ug/L ND 2.0 04/07/23 13:291.5
Isopropylbenzene (Cumene)ug/L ND 0.50 04/07/23 13:290.33
m&p-Xylene ug/L ND 1.0 04/07/23 13:290.71
Methyl-tert-butyl ether ug/L ND 0.50 04/07/23 13:290.42
Methylene Chloride ug/L 2.3 2.0 C904/07/23 13:292.0
n-Butylbenzene ug/L ND 0.50 04/07/23 13:290.49
n-Propylbenzene ug/L ND 0.50 04/07/23 13:290.34
Naphthalene ug/L ND 2.0 04/07/23 13:290.64
o-Xylene ug/L ND 0.50 04/07/23 13:290.34
sec-Butylbenzene ug/L ND 0.50 04/07/23 13:290.40
Styrene ug/L ND 0.50 04/07/23 13:290.29
tert-Butylbenzene ug/L ND 0.50 04/07/23 13:290.32
Tetrachloroethene ug/L ND 0.50 04/07/23 13:290.29
Toluene ug/L ND 0.50 04/07/23 13:290.24
trans-1,2-Dichloroethene ug/L ND 0.50 04/07/23 13:290.40
trans-1,3-Dichloropropene ug/L ND 0.50 04/07/23 13:290.36
Trichloroethene ug/L ND 0.50 04/07/23 13:290.38
Trichlorofluoromethane ug/L ND 1.0 04/07/23 13:290.30
Vinyl chloride ug/L ND 1.0 04/07/23 13:290.39
1,2-Dichloroethane-d4 (S)%93 70-130 04/07/23 13:29
4-Bromofluorobenzene (S)%98 70-130 04/07/23 13:29
Toluene-d8 (S)%101 70-130 04/07/23 13:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3979254LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 23.320 116 60-140
1,1,1-Trichloroethane ug/L 22.220 111 60-140
1,1,2,2-Tetrachloroethane ug/L 21.420 107 60-140
1,1,2-Trichloroethane ug/L 22.320 111 60-140
1,1-Dichloroethane ug/L 21.820 109 60-140
1,1-Dichloroethene ug/L 23.220 116 60-140
1,1-Dichloropropene ug/L 23.620 118 60-140
1,2,3-Trichlorobenzene ug/L 21.920 109 60-140
1,2,3-Trichloropropane ug/L 20.920 104 60-140
1,2,4-Trichlorobenzene ug/L 22.120 110 60-140
1,2,4-Trimethylbenzene ug/L 22.920 114 60-140
1,2-Dibromo-3-chloropropane ug/L 18.620 93 60-140
1,2-Dibromoethane (EDB)ug/L 22.020 110 60-140
1,2-Dichlorobenzene ug/L 22.420 112 60-140
1,2-Dichloroethane ug/L 21.720 109 60-140
1,2-Dichloropropane ug/L 23.220 116 60-140
1,3,5-Trimethylbenzene ug/L 22.820 114 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3979254LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 22.820 114 60-140
1,3-Dichloropropane ug/L 21.120 106 60-140
1,4-Dichlorobenzene ug/L 22.120 111 60-140
2,2-Dichloropropane ug/L 21.520 108 60-140
2-Chlorotoluene ug/L 21.220 106 60-140
4-Chlorotoluene ug/L 22.320 112 60-140
Benzene ug/L 22.520 113 60-140
Bromobenzene ug/L 21.320 107 60-140
Bromochloromethane ug/L 21.720 109 60-140
Bromodichloromethane ug/L 21.620 108 60-140
Bromoform ug/L 21.220 106 60-140
Bromomethane ug/L 18.020 90 60-140
Carbon tetrachloride ug/L 23.520 118 60-140
Chlorobenzene ug/L 22.920 114 60-140
Chloroethane ug/L 21.520 107 60-140
Chloroform ug/L 21.320 106 60-140
Chloromethane ug/L 24.020 120 60-140
cis-1,2-Dichloroethene ug/L 22.220 111 60-140
cis-1,3-Dichloropropene ug/L 21.620 108 60-140
Dibromochloromethane ug/L 22.120 110 60-140
Dibromomethane ug/L 23.020 115 60-140
Dichlorodifluoromethane ug/L 26.920 135 60-140
Diisopropyl ether ug/L 21.820 109 60-140
Ethylbenzene ug/L 22.520 113 60-140
Hexachloro-1,3-butadiene ug/L 24.920 125 60-140
Isopropylbenzene (Cumene)ug/L 23.420 117 60-140
m&p-Xylene ug/L 44.740 112 60-140
Methyl-tert-butyl ether ug/L 19.220 96 60-140
Methylene Chloride ug/L 31.4 L12015760-140
n-Butylbenzene ug/L 23.420 117 60-140
n-Propylbenzene ug/L 21.920 109 60-140
Naphthalene ug/L 21.120 106 60-140
o-Xylene ug/L 22.320 112 60-140
sec-Butylbenzene ug/L 22.820 114 60-140
Styrene ug/L 22.920 115 60-140
tert-Butylbenzene ug/L 21.920 110 60-140
Tetrachloroethene ug/L 24.720 123 60-140
Toluene ug/L 21.520 108 60-140
trans-1,2-Dichloroethene ug/L 22.920 115 60-140
trans-1,3-Dichloropropene ug/L 20.720 103 60-140
Trichloroethene ug/L 24.220 121 60-140
Trichlorofluoromethane ug/L 21.220 106 60-140
Vinyl chloride ug/L 18.620 93 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%96 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3979255MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660465001
3979256
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L M12013060-140149 14 3020ND25.9 29.8
1,1,1-Trichloroethane ug/L M12013460-140155 14 3020ND26.9 31.0
1,1,2,2-Tetrachloroethane ug/L 20 116 60-140139 18 3020ND23.2 27.8
1,1,2-Trichloroethane ug/L M12012660-140149 17 3020ND25.2 29.8
1,1-Dichloroethane ug/L M12012660-140151 18 3020ND25.2 30.1
1,1-Dichloroethene ug/L M12014560-140174 18 3020ND29.0 34.7
1,1-Dichloropropene ug/L M12014060-140166 17 3020ND28.0 33.1
1,2,3-Trichlorobenzene ug/L 20 129 60-140140 8 3020ND25.8 28.1
1,2,3-Trichloropropane ug/L 20 112 60-140131 15 3020ND22.4 26.1
1,2,4-Trichlorobenzene ug/L 20 129 60-140140 9 3020ND25.7 28.1
1,2,4-Trimethylbenzene ug/L M12013060-140142 9 3020ND25.9 28.4
1,2-Dibromo-3-
chloropropane ug/L 20 105 60-140124 16 3020ND21.1 24.8
1,2-Dibromoethane (EDB)ug/L M12012560-140146 16 3020ND24.9 29.2
1,2-Dichlorobenzene ug/L 20 124 60-140138 11 3020ND24.7 27.6
1,2-Dichloroethane ug/L M12012860-140150 16 3020ND25.5 29.9
1,2-Dichloropropane ug/L M12013360-140153 14 3020ND26.6 30.6
1,3,5-Trimethylbenzene ug/L M12012960-140141 9 3020ND25.8 28.2
1,3-Dichlorobenzene ug/L M12012660-140143 13 3020ND25.3 28.7
1,3-Dichloropropane ug/L 20 116 60-140138 17 3020ND23.3 27.6
1,4-Dichlorobenzene ug/L 20 122 60-140138 12 3020ND24.4 27.5
2,2-Dichloropropane ug/L M12013460-140158 17 3020ND26.7 31.6
2-Chlorotoluene ug/L 20 122 60-140135 11 3020ND24.3 27.1
4-Chlorotoluene ug/L 20 121 60-140137 12 3020ND24.3 27.4
Benzene ug/L M12013060-140150 14 3020ND26.1 30.0
Bromobenzene ug/L 20 118 60-140134 12 3020ND23.6 26.8
Bromochloromethane ug/L M12012360-140147 18 3020ND24.6 29.4
Bromodichloromethane ug/L M12012660-140143 13 3020ND25.1 28.6
Bromoform ug/L 20 116 60-140139 18 3020ND23.2 27.9
Bromomethane ug/L 20 95 60-140120 23 3020ND19.1 24.1
Carbon tetrachloride ug/L M12014360-140164 14 3020ND28.6 32.8
Chlorobenzene ug/L M12012560-140143 13 3020ND25.1 28.6
Chloroethane ug/L M12012660-140150 17 3020ND25.2 30.0
Chloroform ug/L M12012460-140142 14 3020ND24.8 28.5
Chloromethane ug/L M12015060-140178 17 3020ND30.0 35.6
cis-1,2-Dichloroethene ug/L M12013060-140153 16 3020ND26.0 30.6
cis-1,3-Dichloropropene ug/L M12012460-140143 14 3020ND24.8 28.5
Dibromochloromethane ug/L M12012660-140145 14 3020ND25.3 29.1
Dibromomethane ug/L M12013460-140153 14 3020ND26.8 30.7
Dichlorodifluoromethane ug/L M12018860-140221 16 3020ND37.6 44.3
Diisopropyl ether ug/L M12013060-140150 14 3020ND26.1 30.0
Ethylbenzene ug/L M12012360-140141 14 3020ND24.5 28.2
Hexachloro-1,3-butadiene ug/L M12015060-140161 8 3020ND29.9 32.3
Isopropylbenzene(Cumene)ug/L M12013260-140150 13 3020ND26.3 29.9
m&p-Xylene ug/L 40 123 60-140140 12 3040ND49.3 55.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3979255MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660465001
3979256
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 114 60-140133 15 3020ND22.8 26.5
Methylene Chloride ug/L M02012460-140150 19 3020ND24.9 30.0
n-Butylbenzene ug/L M12013560-140148 9 3020ND27.0 29.5
n-Propylbenzene ug/L 20 124 60-140135 9 3020ND24.8 27.1
Naphthalene ug/L 20 122 60-140133 9 3020ND24.3 26.5
o-Xylene ug/L M12012560-140141 12 3020ND25.0 28.3
sec-Butylbenzene ug/L M12013460-140146 9 3020ND26.8 29.2
Styrene ug/L M12012260-140144 16 3020ND24.4 28.8
tert-Butylbenzene ug/L 20 109 60-140119 9 3020ND21.7 23.8
Tetrachloroethene ug/L M12013660-140152 11 3020ND27.3 30.5
Toluene ug/L 20 123 60-140139 12 3020ND24.6 27.8
trans-1,2-Dichloroethene ug/L M12013960-140166 18 3020ND27.8 33.1
trans-1,3-Dichloropropene ug/L M12012360-140141 14 3020ND24.6 28.2
Trichloroethene ug/L M12014160-140160 12 3020ND28.2 32.0
Trichlorofluoromethane ug/L M12013260-140155 16 3020ND26.5 31.1
Vinyl chloride ug/L M12012060-140141 16 3020ND24.1 28.2
1,2-Dichloroethane-d4 (S)%97 70-130101
4-Bromofluorobenzene (S)%100 70-130102
Toluene-d8 (S)%97 70-13095
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
766850
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92660072004, 92660072006, 92660072015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3982076
Associated Lab Samples:92660072004, 92660072006, 92660072015
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/10/23 22:160.31
1,1,1-Trichloroethane ug/L ND 0.50 04/10/23 22:160.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/10/23 22:160.22
1,1,2-Trichloroethane ug/L ND 0.50 04/10/23 22:160.32
1,1-Dichloroethane ug/L ND 0.50 04/10/23 22:160.37
1,1-Dichloroethene ug/L ND 0.50 04/10/23 22:160.35
1,1-Dichloropropene ug/L ND 0.50 04/10/23 22:160.43
1,2,3-Trichlorobenzene ug/L ND 2.0 04/10/23 22:160.81
1,2,3-Trichloropropane ug/L ND 0.50 04/10/23 22:160.26
1,2,4-Trichlorobenzene ug/L ND 2.0 04/10/23 22:160.64
1,2,4-Trimethylbenzene ug/L ND 0.50 04/10/23 22:160.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/10/23 22:160.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/10/23 22:160.27
1,2-Dichlorobenzene ug/L ND 0.50 04/10/23 22:160.34
1,2-Dichloroethane ug/L ND 0.50 04/10/23 22:160.32
1,2-Dichloropropane ug/L ND 0.50 04/10/23 22:160.36
1,3,5-Trimethylbenzene ug/L ND 0.50 04/10/23 22:160.33
1,3-Dichlorobenzene ug/L ND 0.50 04/10/23 22:160.34
1,3-Dichloropropane ug/L ND 0.50 04/10/23 22:160.28
1,4-Dichlorobenzene ug/L ND 0.50 04/10/23 22:160.33
2,2-Dichloropropane ug/L ND 0.50 04/10/23 22:160.39
2-Chlorotoluene ug/L ND 0.50 04/10/23 22:160.32
4-Chlorotoluene ug/L ND 0.50 04/10/23 22:160.32
Benzene ug/L ND 0.50 04/10/23 22:160.34
Bromobenzene ug/L ND 0.50 04/10/23 22:160.29
Bromochloromethane ug/L ND 0.50 04/10/23 22:160.47
Bromodichloromethane ug/L ND 0.50 04/10/23 22:160.31
Bromoform ug/L ND 0.50 04/10/23 22:160.34
Bromomethane ug/L ND 5.0 04/10/23 22:161.7
Carbon tetrachloride ug/L ND 0.50 04/10/23 22:160.33
Chlorobenzene ug/L ND 0.50 04/10/23 22:160.28
Chloroethane ug/L ND 1.0 04/10/23 22:160.65
Chloroform ug/L ND 0.50 04/10/23 22:160.43
Chloromethane ug/L ND 1.0 04/10/23 22:160.54
cis-1,2-Dichloroethene ug/L ND 0.50 04/10/23 22:160.38
cis-1,3-Dichloropropene ug/L ND 0.50 04/10/23 22:160.36
Dibromochloromethane ug/L ND 0.50 04/10/23 22:160.36
Dibromomethane ug/L ND 0.50 04/10/23 22:160.39
Dichlorodifluoromethane ug/L ND 0.50 04/10/23 22:160.35
Diisopropyl ether ug/L ND 0.50 04/10/23 22:160.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3982076
Associated Lab Samples:92660072004, 92660072006, 92660072015
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 04/10/23 22:160.30
Hexachloro-1,3-butadiene ug/L ND 2.0 04/10/23 22:161.5
Isopropylbenzene (Cumene)ug/L ND 0.50 04/10/23 22:160.33
m&p-Xylene ug/L ND 1.0 04/10/23 22:160.71
Methyl-tert-butyl ether ug/L ND 0.50 04/10/23 22:160.42
Methylene Chloride ug/L ND 2.0 04/10/23 22:162.0
n-Butylbenzene ug/L ND 0.50 04/10/23 22:160.49
n-Propylbenzene ug/L ND 0.50 04/10/23 22:160.34
Naphthalene ug/L ND 2.0 04/10/23 22:160.64
o-Xylene ug/L ND 0.50 04/10/23 22:160.34
sec-Butylbenzene ug/L ND 0.50 04/10/23 22:160.40
Styrene ug/L ND 0.50 04/10/23 22:160.29
tert-Butylbenzene ug/L ND 0.50 04/10/23 22:160.32
Tetrachloroethene ug/L ND 0.50 04/10/23 22:160.29
Toluene ug/L ND 0.50 04/10/23 22:160.24
trans-1,2-Dichloroethene ug/L ND 0.50 04/10/23 22:160.40
trans-1,3-Dichloropropene ug/L ND 0.50 04/10/23 22:160.36
Trichloroethene ug/L ND 0.50 04/10/23 22:160.38
Trichlorofluoromethane ug/L ND 1.0 04/10/23 22:160.30
Vinyl chloride ug/L ND 1.0 04/10/23 22:160.39
1,2-Dichloroethane-d4 (S)%91 70-130 04/10/23 22:16
4-Bromofluorobenzene (S)%99 70-130 04/10/23 22:16
Toluene-d8 (S)%101 70-130 04/10/23 22:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3982077LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 22.420 112 60-140
1,1,1-Trichloroethane ug/L 21.320 106 60-140
1,1,2,2-Tetrachloroethane ug/L 20.420 102 60-140
1,1,2-Trichloroethane ug/L 22.220 111 60-140
1,1-Dichloroethane ug/L 20.520 103 60-140
1,1-Dichloroethene ug/L 22.720 113 60-140
1,1-Dichloropropene ug/L 22.320 112 60-140
1,2,3-Trichlorobenzene ug/L 21.920 110 60-140
1,2,3-Trichloropropane ug/L 20.220 101 60-140
1,2,4-Trichlorobenzene ug/L 21.220 106 60-140
1,2,4-Trimethylbenzene ug/L 21.220 106 60-140
1,2-Dibromo-3-chloropropane ug/L 18.720 93 60-140
1,2-Dibromoethane (EDB)ug/L 21.520 108 60-140
1,2-Dichlorobenzene ug/L 21.020 105 60-140
1,2-Dichloroethane ug/L 21.320 106 60-140
1,2-Dichloropropane ug/L 22.220 111 60-140
1,3,5-Trimethylbenzene ug/L 21.220 106 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3982077LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 21.520 108 60-140
1,3-Dichloropropane ug/L 20.420 102 60-140
1,4-Dichlorobenzene ug/L 20.820 104 60-140
2,2-Dichloropropane ug/L 20.820 104 60-140
2-Chlorotoluene ug/L 20.320 102 60-140
4-Chlorotoluene ug/L 20.920 104 60-140
Benzene ug/L 21.620 108 60-140
Bromobenzene ug/L 20.520 102 60-140
Bromochloromethane ug/L 20.820 104 60-140
Bromodichloromethane ug/L 20.920 104 60-140
Bromoform ug/L 20.320 101 60-140
Bromomethane ug/L 16.520 83 60-140
Carbon tetrachloride ug/L 21.920 109 60-140
Chlorobenzene ug/L 21.420 107 60-140
Chloroethane ug/L 18.920 94 60-140
Chloroform ug/L 20.320 102 60-140
Chloromethane ug/L 23.620 118 60-140
cis-1,2-Dichloroethene ug/L 21.220 106 60-140
cis-1,3-Dichloropropene ug/L 21.120 106 60-140
Dibromochloromethane ug/L 21.820 109 60-140
Dibromomethane ug/L 22.420 112 60-140
Dichlorodifluoromethane ug/L 24.720 124 60-140
Diisopropyl ether ug/L 22.320 111 60-140
Ethylbenzene ug/L 20.820 104 60-140
Hexachloro-1,3-butadiene ug/L 22.120 111 60-140
Isopropylbenzene (Cumene)ug/L 21.720 109 60-140
m&p-Xylene ug/L 42.040 105 60-140
Methyl-tert-butyl ether ug/L 20.020 100 60-140
Methylene Chloride ug/L 39.5 L12019760-140
n-Butylbenzene ug/L 20.720 104 60-140
n-Propylbenzene ug/L 20.120 101 60-140
Naphthalene ug/L 21.320 107 60-140
o-Xylene ug/L 21.420 107 60-140
sec-Butylbenzene ug/L 20.820 104 60-140
Styrene ug/L 21.420 107 60-140
tert-Butylbenzene ug/L 17.220 86 60-140
Tetrachloroethene ug/L 22.220 111 60-140
Toluene ug/L 20.520 102 60-140
trans-1,2-Dichloroethene ug/L 22.520 112 60-140
trans-1,3-Dichloropropene ug/L 20.720 104 60-140
Trichloroethene ug/L 22.720 114 60-140
Trichlorofluoromethane ug/L 18.520 93 60-140
Vinyl chloride ug/L 17.920 89 60-140
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%95 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3982078MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660213007
3982079
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 112 60-140128 14 3020ND22.4 25.6
1,1,1-Trichloroethane ug/L 20 117 60-140131 11 3020ND23.3 26.1
1,1,2,2-Tetrachloroethane ug/L 20 101 60-140115 13 3020ND20.2 22.9
1,1,2-Trichloroethane ug/L 20 111 60-140123 10 3020ND22.2 24.6
1,1-Dichloroethane ug/L 20 112 60-140127 12 3020ND22.4 25.3
1,1-Dichloroethene ug/L M12013160-140146 11 3020ND26.2 29.3
1,1-Dichloropropene ug/L 20 122 60-140138 12 3020ND24.5 27.7
1,2,3-Trichlorobenzene ug/L 20 109 60-140117 7 3020ND21.9 23.4
1,2,3-Trichloropropane ug/L 20 96 60-140108 11 3020ND19.3 21.6
1,2,4-Trichlorobenzene ug/L 20 112 60-140119 7 3020ND22.3 23.9
1,2,4-Trimethylbenzene ug/L 20 112 60-140121 8 3020ND22.5 24.2
1,2-Dibromo-3-
chloropropane ug/L 20 92 60-14098 6 3020ND18.4 19.5
1,2-Dibromoethane (EDB)ug/L 20 106 60-140117 10 3020ND21.1 23.4
1,2-Dichlorobenzene ug/L 20 109 60-140118 8 3020ND21.8 23.6
1,2-Dichloroethane ug/L 20 108 60-140125 15 3020ND21.6 25.0
1,2-Dichloropropane ug/L 20 116 60-140132 13 3020ND23.3 26.4
1,3,5-Trimethylbenzene ug/L 20 113 60-140121 7 3020ND22.7 24.3
1,3-Dichlorobenzene ug/L 20 112 60-140123 10 3020ND22.4 24.7
1,3-Dichloropropane ug/L 20 100 60-140112 11 3020ND20.0 22.4
1,4-Dichlorobenzene ug/L 20 107 60-140118 10 3020ND21.4 23.6
2,2-Dichloropropane ug/L 20 114 60-140129 12 3020ND22.9 25.8
2-Chlorotoluene ug/L 20 105 60-140115 9 3020ND20.9 23.0
4-Chlorotoluene ug/L 20 109 60-140118 8 3020ND21.7 23.6
Benzene ug/L 20 117 60-140130 10 3020ND23.5 25.9
Bromobenzene ug/L 20 100 60-140114 13 3020ND20.1 22.7
Bromochloromethane ug/L 20 108 60-140125 14 3020ND21.6 24.9
Bromodichloromethane ug/L 20 110 60-140125 13 3020ND21.9 24.9
Bromoform ug/L 20 98 60-140116 16 3020ND19.6 23.1
Bromomethane ug/L 20 92 60-140115 23 3020ND18.3 23.1
Carbon tetrachloride ug/L M12012960-140142 10 3020ND25.7 28.3
Chlorobenzene ug/L 20 109 60-140121 11 3020ND21.7 24.3
Chloroethane ug/L 20 113 60-140128 12 3020ND22.6 25.5
Chloroform ug/L 20 105 60-140120 14 3020ND20.9 24.1
Chloromethane ug/L M12013660-140155 12 3020ND27.3 30.9
cis-1,2-Dichloroethene ug/L 20 115 60-140129 12 3020ND22.9 25.8
cis-1,3-Dichloropropene ug/L 20 104 60-140117 11 3020ND20.9 23.4
Dibromochloromethane ug/L 20 104 60-140122 17 3020ND20.7 24.5
Dibromomethane ug/L 20 115 60-140132 14 3020ND23.0 26.5
Dichlorodifluoromethane ug/L M12016160-140181 12 3020ND32.2 36.2
Diisopropyl ether ug/L 20 110 60-140124 11 3020ND22.1 24.7
Ethylbenzene ug/L 20 109 60-140121 10 3020ND21.8 24.2
Hexachloro-1,3-butadiene ug/L 20 133 60-140133 0 3020ND26.6 26.7
Isopropylbenzene(Cumene)ug/L 20 118 60-140128 8 3020ND23.6 25.7
m&p-Xylene ug/L 40 110 60-140122 10 3040ND43.9 48.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3982078MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660213007
3982079
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 95 60-140108 13 3020ND19.0 21.7
Methylene Chloride ug/L 20 112 60-140129 15 3020ND22.3 25.9
n-Butylbenzene ug/L 20 119 60-140125 5 3020ND23.8 25.0
n-Propylbenzene ug/L 20 110 60-140117 6 3020ND22.0 23.3
Naphthalene ug/L 20 101 60-140108 7 3020ND20.2 21.7
o-Xylene ug/L 20 109 60-140122 11 3020ND21.8 24.5
sec-Butylbenzene ug/L 20 118 60-140123 4 3020ND23.6 24.6
Styrene ug/L 20 109 60-140122 12 3020ND21.7 24.5
tert-Butylbenzene ug/L 20 95 60-140100 5 3020ND18.9 20.0
Tetrachloroethene ug/L 20 119 60-140130 9 3020ND23.7 25.9
Toluene ug/L 20 110 60-140124 12 3020ND22.0 24.7
trans-1,2-Dichloroethene ug/L 20 123 60-140137 11 3020ND24.7 27.5
trans-1,3-Dichloropropene ug/L 20 103 60-140121 16 3020ND20.5 24.2
Trichloroethene ug/L 20 123 60-140138 11 3020ND24.6 27.5
Trichlorofluoromethane ug/L 20 117 60-140131 11 3020ND23.4 26.2
Vinyl chloride ug/L 20 106 60-140120 12 3020ND21.1 23.9
1,2-Dichloroethane-d4 (S)%96 70-13096
4-Bromofluorobenzene (S)%100 70-130101
Toluene-d8 (S)%97 70-13097
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
767056
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92660072001, 92660072013, 92660072014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3982718
Associated Lab Samples:92660072001, 92660072013, 92660072014
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 04/10/23 09:470.31
1,1,1-Trichloroethane ug/L ND 0.50 04/10/23 09:470.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 04/10/23 09:470.22
1,1,2-Trichloroethane ug/L ND 0.50 04/10/23 09:470.32
1,1-Dichloroethane ug/L ND 0.50 04/10/23 09:470.37
1,1-Dichloroethene ug/L ND 0.50 04/10/23 09:470.35
1,1-Dichloropropene ug/L ND 0.50 04/10/23 09:470.43
1,2,3-Trichlorobenzene ug/L ND 2.0 04/10/23 09:470.81
1,2,3-Trichloropropane ug/L ND 0.50 04/10/23 09:470.26
1,2,4-Trichlorobenzene ug/L ND 2.0 04/10/23 09:470.64
1,2,4-Trimethylbenzene ug/L ND 0.50 04/10/23 09:470.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 04/10/23 09:470.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 04/10/23 09:470.27
1,2-Dichlorobenzene ug/L ND 0.50 04/10/23 09:470.34
1,2-Dichloroethane ug/L ND 0.50 04/10/23 09:470.32
1,2-Dichloropropane ug/L ND 0.50 04/10/23 09:470.36
1,3,5-Trimethylbenzene ug/L ND 0.50 04/10/23 09:470.33
1,3-Dichlorobenzene ug/L ND 0.50 04/10/23 09:470.34
1,3-Dichloropropane ug/L ND 0.50 04/10/23 09:470.28
1,4-Dichlorobenzene ug/L ND 0.50 04/10/23 09:470.33
2,2-Dichloropropane ug/L ND 0.50 04/10/23 09:470.39
2-Chlorotoluene ug/L ND 0.50 04/10/23 09:470.32
4-Chlorotoluene ug/L ND 0.50 04/10/23 09:470.32
Benzene ug/L ND 0.50 04/10/23 09:470.34
Bromobenzene ug/L ND 0.50 04/10/23 09:470.29
Bromochloromethane ug/L ND 0.50 04/10/23 09:470.47
Bromodichloromethane ug/L ND 0.50 04/10/23 09:470.31
Bromoform ug/L ND 0.50 04/10/23 09:470.34
Bromomethane ug/L ND 5.0 04/10/23 09:471.7
Carbon tetrachloride ug/L ND 0.50 04/10/23 09:470.33
Chlorobenzene ug/L ND 0.50 04/10/23 09:470.28
Chloroethane ug/L ND 1.0 04/10/23 09:470.65
Chloroform ug/L ND 0.50 04/10/23 09:470.43
Chloromethane ug/L ND 1.0 04/10/23 09:470.54
cis-1,2-Dichloroethene ug/L ND 0.50 04/10/23 09:470.38
cis-1,3-Dichloropropene ug/L ND 0.50 04/10/23 09:470.36
Dibromochloromethane ug/L ND 0.50 04/10/23 09:470.36
Dibromomethane ug/L ND 0.50 04/10/23 09:470.39
Dichlorodifluoromethane ug/L ND 0.50 04/10/23 09:470.35
Diisopropyl ether ug/L ND 0.50 04/10/23 09:470.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3982718
Associated Lab Samples:92660072001, 92660072013, 92660072014
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 04/10/23 09:470.30
Hexachloro-1,3-butadiene ug/L ND 2.0 04/10/23 09:471.5
Isopropylbenzene (Cumene)ug/L ND 0.50 04/10/23 09:470.33
m&p-Xylene ug/L ND 1.0 04/10/23 09:470.71
Methyl-tert-butyl ether ug/L ND 0.50 04/10/23 09:470.42
Methylene Chloride ug/L ND 2.0 04/10/23 09:472.0
n-Butylbenzene ug/L ND 0.50 04/10/23 09:470.49
n-Propylbenzene ug/L ND 0.50 04/10/23 09:470.34
Naphthalene ug/L ND 2.0 04/10/23 09:470.64
o-Xylene ug/L ND 0.50 04/10/23 09:470.34
sec-Butylbenzene ug/L ND 0.50 04/10/23 09:470.40
Styrene ug/L ND 0.50 04/10/23 09:470.29
tert-Butylbenzene ug/L ND 0.50 04/10/23 09:470.32
Tetrachloroethene ug/L ND 0.50 04/10/23 09:470.29
Toluene ug/L ND 0.50 04/10/23 09:470.24
trans-1,2-Dichloroethene ug/L ND 0.50 04/10/23 09:470.40
trans-1,3-Dichloropropene ug/L ND 0.50 04/10/23 09:470.36
Trichloroethene ug/L ND 0.50 04/10/23 09:470.38
Trichlorofluoromethane ug/L ND 1.0 04/10/23 09:470.30
Vinyl chloride ug/L ND 1.0 04/10/23 09:470.39
1,2-Dichloroethane-d4 (S)%93 70-130 04/10/23 09:47
4-Bromofluorobenzene (S)%99 70-130 04/10/23 09:47
Toluene-d8 (S)%101 70-130 04/10/23 09:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3982719LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 22.720 113 60-140
1,1,1-Trichloroethane ug/L 21.420 107 60-140
1,1,2,2-Tetrachloroethane ug/L 20.220 101 60-140
1,1,2-Trichloroethane ug/L 21.620 108 60-140
1,1-Dichloroethane ug/L 20.620 103 60-140
1,1-Dichloroethene ug/L 23.220 116 60-140
1,1-Dichloropropene ug/L 22.120 110 60-140
1,2,3-Trichlorobenzene ug/L 21.220 106 60-140
1,2,3-Trichloropropane ug/L 19.420 97 60-140
1,2,4-Trichlorobenzene ug/L 21.020 105 60-140
1,2,4-Trimethylbenzene ug/L 21.420 107 60-140
1,2-Dibromo-3-chloropropane ug/L 18.620 93 60-140
1,2-Dibromoethane (EDB)ug/L 21.020 105 60-140
1,2-Dichlorobenzene ug/L 21.020 105 60-140
1,2-Dichloroethane ug/L 21.020 105 60-140
1,2-Dichloropropane ug/L 22.220 111 60-140
1,3,5-Trimethylbenzene ug/L 21.320 106 60-140
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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Page 55 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3982719LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 21.320 107 60-140
1,3-Dichloropropane ug/L 20.020 100 60-140
1,4-Dichlorobenzene ug/L 20.920 105 60-140
2,2-Dichloropropane ug/L 21.320 107 60-140
2-Chlorotoluene ug/L 20.320 101 60-140
4-Chlorotoluene ug/L 21.020 105 60-140
Benzene ug/L 21.520 107 60-140
Bromobenzene ug/L 20.120 101 60-140
Bromochloromethane ug/L 20.520 102 60-140
Bromodichloromethane ug/L 21.220 106 60-140
Bromoform ug/L 20.920 105 60-140
Bromomethane ug/L 15.020 75 60-140
Carbon tetrachloride ug/L 23.020 115 60-140
Chlorobenzene ug/L 21.520 107 60-140
Chloroethane ug/L 20.320 101 60-140
Chloroform ug/L 19.920 100 60-140
Chloromethane ug/L 23.920 119 60-140
cis-1,2-Dichloroethene ug/L 21.120 105 60-140
cis-1,3-Dichloropropene ug/L 21.420 107 60-140
Dibromochloromethane ug/L 21.120 106 60-140
Dibromomethane ug/L 22.220 111 60-140
Dichlorodifluoromethane ug/L 29.2 L12014660-140
Diisopropyl ether ug/L 21.520 108 60-140
Ethylbenzene ug/L 21.120 105 60-140
Hexachloro-1,3-butadiene ug/L 22.420 112 60-140
Isopropylbenzene (Cumene)ug/L 21.920 109 60-140
m&p-Xylene ug/L 42.240 105 60-140
Methyl-tert-butyl ether ug/L 18.820 94 60-140
Methylene Chloride ug/L 23.120 115 60-140
n-Butylbenzene ug/L 21.320 107 60-140
n-Propylbenzene ug/L 20.320 102 60-140
Naphthalene ug/L 20.520 103 60-140
o-Xylene ug/L 21.420 107 60-140
sec-Butylbenzene ug/L 21.120 105 60-140
Styrene ug/L 21.720 108 60-140
tert-Butylbenzene ug/L 17.520 87 60-140
Tetrachloroethene ug/L 23.320 117 60-140
Toluene ug/L 20.620 103 60-140
trans-1,2-Dichloroethene ug/L 22.220 111 60-140
trans-1,3-Dichloropropene ug/L 20.920 104 60-140
Trichloroethene ug/L 23.420 117 60-140
Trichlorofluoromethane ug/L 20.520 102 60-140
Vinyl chloride ug/L 18.420 92 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%96 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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Page 56 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3982720MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92659958005
3982721
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 108 60-140104 4 3020ND21.6 20.9
1,1,1-Trichloroethane ug/L 20 105 60-140100 5 3020ND21.1 20.0
1,1,2,2-Tetrachloroethane ug/L 20 110 60-140108 1 3020ND21.9 21.6
1,1,2-Trichloroethane ug/L 20 112 60-140106 5 3020ND22.3 21.2
1,1-Dichloroethane ug/L 20 109 60-140107 2 3020ND22.2 21.8
1,1-Dichloroethene ug/L 20 122 60-140121 1 3020ND24.5 24.1
1,1-Dichloropropene ug/L 20 105 60-140102 3 3020ND21.0 20.3
1,2,3-Trichlorobenzene ug/L M12014560-140118 21 3020ND28.9 23.5
1,2,3-Trichloropropane ug/L 20 118 60-140115 2 3020ND23.7 23.1
1,2,4-Trichlorobenzene ug/L 20 137 60-140116 16 3020ND27.3 23.2
1,2,4-Trimethylbenzene ug/L M120-351 60-140-352 0 3020383313313
1,2-Dibromo-3-
chloropropane ug/L 20 105 60-14092 13 3020ND21.0 18.4
1,2-Dibromoethane (EDB)ug/L 20 104 60-140107 3 3020ND20.8 21.5
1,2-Dichlorobenzene ug/L 20 111 60-140113 1 3020ND22.2 22.5
1,2-Dichloroethane ug/L 20 108 60-140109 1 3020ND21.6 21.9
1,2-Dichloropropane ug/L 20 111 60-140108 2 3020ND22.2 21.7
1,3,5-Trimethylbenzene ug/L M120-24 60-140-24 0 3020105100100
1,3-Dichlorobenzene ug/L 20 116 60-140108 7 3020ND23.2 21.6
1,3-Dichloropropane ug/L 20 96 60-14098 2 3020ND19.3 19.6
1,4-Dichlorobenzene ug/L 20 114 60-140110 4 3020ND22.8 22.0
2,2-Dichloropropane ug/L 20 108 60-140106 1 3020ND21.5 21.3
2-Chlorotoluene ug/L 20 98 60-14092 6 3020ND19.7 18.4
4-Chlorotoluene ug/L 20 98 60-140102 4 3020ND19.6 20.5
Benzene ug/L 20 93 60-14092 0 302014.3 32.8 32.7
Bromobenzene ug/L 20 105 60-140104 2 3020ND21.1 20.7
Bromochloromethane ug/L 20 108 60-140111 3 3020ND21.6 22.2
Bromodichloromethane ug/L 20 103 60-140104 1 3020ND20.7 20.9
Bromoform ug/L 20 97 60-14097 0 3020ND19.4 19.3
Bromomethane ug/L 20 86 60-14087 3020ND17.2J 17.4J
Carbon tetrachloride ug/L 20 113 60-140112 1 3020ND22.6 22.4
Chlorobenzene ug/L 20 109 60-140110 2 3020ND21.7 22.1
Chloroethane ug/L 20 107 60-140107 0 3020ND21.5 21.4
Chloroform ug/L 20 101 60-140103 2 3020ND20.1 20.5
Chloromethane ug/L M12014160-140139 2 3020ND28.2 27.7
cis-1,2-Dichloroethene ug/L 20 114 60-140113 1 3020ND22.8 22.6
cis-1,3-Dichloropropene ug/L 20 99 60-14095 5 3020ND19.9 19.0
Dibromochloromethane ug/L 20 102 60-14097 5 3020ND20.3 19.4
Dibromomethane ug/L 20 114 60-140116 2 3020ND22.8 23.2
Dichlorodifluoromethane ug/L M02015860-140155 2 3020ND31.5 31.1
Diisopropyl ether ug/L 20 110 60-140111 1 30204.0 26.1 26.2
Ethylbenzene ug/L M1203460-14029 1 302063.5 70.3 69.3
Hexachloro-1,3-butadiene ug/L M12015060-140131 14 3020ND30.0 26.2
Isopropylbenzene(Cumene)ug/L 20 89 60-14088 1 302024.3 42.0 41.8
m&p-Xylene ug/L 40 67 60-14066 0 304068.0 94.7 94.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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[phone]
Page 57 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3982720MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92659958005
3982721
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 105 60-140104 1 3020ND20.9 20.7
Methylene Chloride ug/L M12023260-140211 7 302010.9 57.3 53.1
n-Butylbenzene ug/L M12022960-140173 28 3020ND45.7 34.6
n-Propylbenzene ug/L M12032860-140317 3 3020ND65.6 63.4
Naphthalene ug/L 20 99 60-14077 11 302024.4 44.2 39.7
o-Xylene ug/L 20 112 60-140109 2 30208.1 30.5 29.9
sec-Butylbenzene ug/L M12015660-140144 8 3020ND31.2 28.8
Styrene ug/L 20 108 60-140104 4 3020ND21.6 20.8
tert-Butylbenzene ug/L 20 97 60-14090 8 3020ND19.3 17.9
Tetrachloroethene ug/L 20 111 60-140113 1 3020ND22.3 22.6
Toluene ug/L 20 104 60-140104 0 30201.6J 22.4 22.3
trans-1,2-Dichloroethene ug/L 20 114 60-140115 0 3020ND22.9 23.0
trans-1,3-Dichloropropene ug/L 20 98 60-140100 1 3020ND19.7 19.9
Trichloroethene ug/L 20 113 60-140109 3 3020ND22.6 21.8
Trichlorofluoromethane ug/L 20 107 60-140108 1 3020ND21.3 21.5
Vinyl chloride ug/L 20 99 60-14097 2 3020ND19.8 19.4
1,2-Dichloroethane-d4 (S)%100 70-13098
4-Bromofluorobenzene (S)%100 70-130102
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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Page 58 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
765718
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92660072001, 92660072002, 92660072003, 92660072004, 92660072005, 92660072006, 92660072007,
92660072008, 92660072009, 92660072010, 92660072011, 92660072012, 92660072013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3975683
Associated Lab Samples:92660072001, 92660072002, 92660072003, 92660072004, 92660072005, 92660072006, 92660072007,
92660072008, 92660072009, 92660072010, 92660072011, 92660072012, 92660072013
Matrix:Water
AnalyzedMDL
Sulfate mg/L ND 1.0 04/05/23 17:080.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3975684LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate mg/L 48.650 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3975685MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660045001
3975686
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate mg/L 50 92 90-11093 0 1050232278279
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3975687MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660072004
3975688
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate mg/L 50 97 90-110103 4 105029.7 78.1 81.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
765728
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92660072014, 92660072015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3975720
Associated Lab Samples:92660072014, 92660072015
Matrix:Water
AnalyzedMDL
Sulfate mg/L ND 1.0 04/05/23 01:480.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3975721LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate mg/L 50.050 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3975722MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660072014
3975723
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate mg/L 50 100 90-110100 1 10500.68J 50.6 50.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3975724MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92660024010
3975725
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate mg/L M15023590-110116 1 1050107001080010800
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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[phone]
Page 60 of 67
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Result may be biased high due to carryover from previously analyzed sample.C8
Common Laboratory Contaminant.C9
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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Huntersville, NC 28078
[phone]
Page 61 of 67
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92660072
70149672B BLALOCK FINA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92660072001 767056MW-1 SM 6200B
92660072002 766100MW-3 SM 6200B
92660072003 766100MW-4 SM 6200B
92660072004 766850MW-5 SM 6200B
92660072005 766100MW-6 SM 6200B
92660072006 766850MW-7 SM 6200B
92660072007 766100MW-8 SM 6200B
92660072008 766100MW-9 SM 6200B
92660072009 766100MW-10 SM 6200B
92660072010 766100MW-11 SM 6200B
92660072011 766100MW-12 SM 6200B
92660072012 766100RW-1 SM 6200B
92660072013 767056RW-2 SM 6200B
92660072014 767056VEW-1 SM 6200B
92660072015 766850VEW-2 SM 6200B
92660072016 766396FIELD BLANK SM 6200B
92660072017 766396TRIP BLANK SM 6200B
92660072001 765718MW-1 EPA 300.0 Rev 2.1 1993
92660072002 765718MW-3 EPA 300.0 Rev 2.1 1993
92660072003 765718MW-4 EPA 300.0 Rev 2.1 1993
92660072004 765718MW-5 EPA 300.0 Rev 2.1 1993
92660072005 765718MW-6 EPA 300.0 Rev 2.1 1993
92660072006 765718MW-7 EPA 300.0 Rev 2.1 1993
92660072007 765718MW-8 EPA 300.0 Rev 2.1 1993
92660072008 765718MW-9 EPA 300.0 Rev 2.1 1993
92660072009 765718MW-10 EPA 300.0 Rev 2.1 1993
92660072010 765718MW-11 EPA 300.0 Rev 2.1 1993
92660072011 765718MW-12 EPA 300.0 Rev 2.1 1993
92660072012 765718RW-1 EPA 300.0 Rev 2.1 1993
92660072013 765718RW-2 EPA 300.0 Rev 2.1 1993
92660072014 765728VEW-1 EPA 300.0 Rev 2.1 1993
92660072015 765728VEW-2 EPA 300.0 Rev 2.1 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/11/2023 01:33 PM
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[phone]
Page 62 of 67
Page 63 of 67
Page 64 of 67
Page 65 of 67
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Page 67 of 67
ANALYTICAL REPORT
April 14, 2023
Terracon - Raleigh, NC
Sample Delivery Group:L1600695
Samples Received:04/01/2023
Project Number:70149672B
Description:Blalock Fina
Report To:Annalee Farrell
2401 Brentwood Rd
Ste 107
Raleigh, NC 27604
Entire Report Reviewed By:
April 14, 2023
[Preliminary Report]
Heather J Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Terracon - Raleigh, NC 70149672B L1600695 04/14/23 15:45 1 of 18
April 14, 2023
Jason Romer
Project Manager
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Terracon - Raleigh, NC 70149672B L1600695 04/14/23 16:00 1 of 18
TABLE OF CONTENTS
Cp: Cover Page 1
Tc: Table of Contents 2
Ss: Sample Summary 3
Cn: Case Narrative 4
Sr: Sample Results 5
SG-1 L1600695-01 5
SG-2 L1600695-02 7
Qc: Quality Control Summary 9
Volatile Organic Compounds (MS) by Method TO-15 9
Gl: Glossary of Terms 16
Al: Accreditations & Locations 17
Sc: Sample Chain of Custody 18
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Terracon - Raleigh, NC 70149672B L1600695 04/14/23 16:00 2 of 18
SAMPLE SUMMARY
Collected by Collected date/time Received date/time
SG-1 L1600695-01 Air Les Abbott 03/31/23 10:45 04/01/23 09:00
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Volatile Organic Compounds (MS) by Method TO-15 WG2039147 1 04/10/23 19:09 04/10/23 19:09 DAH Mt. Juliet, TN
Collected by Collected date/time Received date/time
SG-2 L1600695-02 Air Les Abbott 03/31/23 11:25 04/01/23 09:00
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Volatile Organic Compounds (MS) by Method TO-15 WG2039147 1 04/10/23 19:37 04/10/23 19:37 DAH Mt. Juliet, TN
Volatile Organic Compounds (MS) by Method TO-15 WG2039650 1 04/11/23 17:16 04/11/23 17:16 DBB Mt. Juliet, TN
Volatile Organic Compounds (MS) by Method TO-15 WG2042008 10 04/14/23 13:10 04/14/23 13:10 MBF Mt. Juliet, TN
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Terracon - Raleigh, NC 70149672B L1600695 04/14/23 15:45 3 of 18
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Terracon - Raleigh, NC 70149672B L1600695 04/14/23 16:00 3 of 18
CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
[Preliminary Report]
Heather J Wagner
Project Manager
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Terracon - Raleigh, NC 70149672B L1600695 04/14/23 15:45 4 of 18
Jason Romer
Project Manager
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Terracon - Raleigh, NC 70149672B L1600695 04/14/23 16:00 4 of 18
SAMPLE RESULTS - 01
L1600695
SG-1
Collected date/time: 03/31/23 10:45
Volatile Organic Compounds (MS) by Method TO-15
CAS #Mol. Wt.RDL1 RDL2 Result Result Qualifier Dilution Batch
Analyte ppbv ug/m3 ppbv ug/m3
Acetone 67-64-1 58.10 1.25 2.97 ND ND 1 WG2039147
Allyl chloride 107-05-1 76.53 0.200 0.626 ND ND 1 WG2039147
Benzene 71-43-2 78.10 0.200 0.639 ND ND 1 WG2039147
Benzyl Chloride 100-44-7 127 0.200 1.04 ND ND 1 WG2039147
Bromodichloromethane 75-27-4 164 0.200 1.34 ND ND 1 WG2039147
Bromoform 75-25-2 253 0.600 6.21 ND ND 1 WG2039147
Bromomethane 74-83-9 94.90 0.200 0.776 ND ND 1 WG2039147
1,3-Butadiene 106-99-0 54.10 2.00 4.43 ND ND 1 WG2039147
Carbon disulfide 75-15-0 76.10 0.200 0.622 ND ND 1 WG2039147
Carbon tetrachloride 56-23-5 154 0.200 1.26 ND ND 1 WG2039147
Chlorobenzene 108-90-7 113 0.200 0.924 ND ND 1 WG2039147
Chloroethane 75-00-3 64.50 0.200 0.528 ND ND 1 WG2039147
Chloroform 67-66-3 119 0.200 0.973 ND ND 1 WG2039147
Chloromethane 74-87-3 50.50 0.200 0.413 ND ND 1 WG2039147
2-Chlorotoluene 95-49-8 126 0.200 1.03 ND ND 1 WG2039147
Cyclohexane 110-82-7 84.20 0.200 0.689 ND ND 1 WG2039147
Dibromochloromethane 124-48-1 208 0.200 1.70 ND ND 1 WG2039147
1,2-Dibromoethane 106-93-4 188 0.200 1.54 ND ND 1 WG2039147
1,2-Dichlorobenzene 95-50-1 147 0.200 1.20 ND ND 1 WG2039147
1,3-Dichlorobenzene 541-73-1 147 0.200 1.20 ND ND 1 WG2039147
1,4-Dichlorobenzene 106-46-7 147 0.200 1.20 ND ND 1 WG2039147
1,2-Dichloroethane 107-06-2 99 0.200 0.810 ND ND 1 WG2039147
1,1-Dichloroethane 75-34-3 98 0.200 0.802 ND ND 1 WG2039147
1,1-Dichloroethene 75-35-4 96.90 0.200 0.793 ND ND 1 WG2039147
cis-1,2-Dichloroethene 156-59-2 96.90 0.200 0.793 ND ND 1 WG2039147
trans-1,2-Dichloroethene 156-60-5 96.90 0.200 0.793 ND ND 1 WG2039147
1,2-Dichloropropane 78-87-5 113 0.200 0.924 ND ND 1 WG2039147
cis-1,3-Dichloropropene 10061-01-5 111 0.200 0.908 ND ND 1 WG2039147
trans-1,3-Dichloropropene 10061-02-6 111 0.200 0.908 ND ND 1 WG2039147
1,4-Dioxane 123-91-1 88.10 0.200 0.721 ND ND 1 WG2039147
Ethanol 64-17-5 46.10 1.25 2.36 ND ND 1 WG2039147
Ethylbenzene 100-41-4 106 0.200 0.867 1.03 4.47 1 WG2039147
4-Ethyltoluene 622-96-8 120 0.200 0.982 ND ND 1 WG2039147
Trichlorofluoromethane 75-69-4 137.40 0.200 1.12 ND ND 1 WG2039147
Dichlorodifluoromethane 75-71-8 120.92 0.200 0.989 ND ND 1 WG2039147
1,1,2-Trichlorotrifluoroethane 76-13-1 187.40 0.200 1.53 ND ND 1 WG2039147
1,2-Dichlorotetrafluoroethane 76-14-2 171 0.200 1.40 ND ND 1 WG2039147
Heptane 142-82-5 100 0.200 0.818 2.70 11.0 1 WG2039147
Hexachloro-1,3-butadiene 87-68-3 261 0.630 6.73 ND ND 1 WG2039147
n-Hexane 110-54-3 86.20 0.630 2.22 ND ND 1 WG2039147
Isopropylbenzene 98-82-8 120.20 0.200 0.983 ND ND 1 WG2039147
Methylene Chloride 75-09-2 84.90 0.200 0.694 ND ND 1 WG2039147
Methyl Butyl Ketone 591-78-6 100 1.25 5.11 ND ND 1 WG2039147
2-Butanone (MEK)78-93-3 72.10 1.25 3.69 ND ND 1 WG2039147
4-Methyl-2-pentanone (MIBK)108-10-1 100.10 1.25 5.12 ND ND 1 WG2039147
Methyl methacrylate 80-62-6 100.12 0.200 0.819 ND ND 1 WG2039147
MTBE 1634-04-4 88.10 0.200 0.721 ND ND 1 WG2039147
Naphthalene 91-20-3 128 0.630 3.30 ND ND 1 WG2039147
2-Propanol 67-63-0 60.10 1.25 3.07 ND ND 1 WG2039147
Propene 115-07-1 42.10 1.25 2.15 ND ND 1 WG2039147
Styrene 100-42-5 104 0.200 0.851 ND ND 1 WG2039147
1,1,2,2-Tetrachloroethane 79-34-5 168 0.200 1.37 ND ND 1 WG2039147
Tetrachloroethylene 127-18-4 166 0.200 1.36 5.49 37.3 1 WG2039147
Tetrahydrofuran 109-99-9 72.10 0.200 0.590 ND ND 1 WG2039147
Toluene 108-88-3 92.10 0.500 1.88 8.20 30.9 1 WG2039147
1,2,4-Trichlorobenzene 120-82-1 181 0.630 4.66 ND ND 1 WG2039147
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 01
L1600695
SG-1
Collected date/time: 03/31/23 10:45
Volatile Organic Compounds (MS) by Method TO-15
CAS #Mol. Wt.RDL1 RDL2 Result Result Qualifier Dilution Batch
Analyte ppbv ug/m3 ppbv ug/m3
1,1,1-Trichloroethane 71-55-6 133 0.200 1.09 ND ND 1 WG2039147
1,1,2-Trichloroethane 79-00-5 133 0.200 1.09 ND ND 1 WG2039147
Trichloroethylene 79-01-6 131 0.200 1.07 ND ND 1 WG2039147
1,2,4-Trimethylbenzene 95-63-6 120 0.200 0.982 0.689 3.38 1 WG2039147
1,3,5-Trimethylbenzene 108-67-8 120 0.200 0.982 0.234 1.15 1 WG2039147
2,2,4-Trimethylpentane 540-84-1 114.22 0.200 0.934 ND ND 1 WG2039147
Vinyl chloride 75-01-4 62.50 0.200 0.511 ND ND 1 WG2039147
Vinyl Bromide 593-60-2 106.95 0.200 0.875 ND ND 1 WG2039147
Vinyl acetate 108-05-4 86.10 0.200 0.704 ND ND J4 1 WG2039147
m&p-Xylene 1330-20-7 106 0.400 1.73 3.35 14.5 1 WG2039147
o-Xylene 95-47-6 106 0.200 0.867 1.26 5.46 1 WG2039147
(S) 1,4-Bromofluorobenzene 460-00-4 175 60.0-140 97.3 WG2039147
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 02
L1600695
SG-2
Collected date/time: 03/31/23 11:25
Volatile Organic Compounds (MS) by Method TO-15
CAS #Mol. Wt.RDL1 RDL2 Result Result Qualifier Dilution Batch
Analyte ppbv ug/m3 ppbv ug/m3
Acetone 67-64-1 58.10 1.25 2.97 19.8 47.1 1 WG2039650
Allyl chloride 107-05-1 76.53 0.200 0.626 ND ND 1 WG2039650
Benzene 71-43-2 78.10 0.200 0.639 ND ND 1 WG2039147
Benzyl Chloride 100-44-7 127 0.200 1.04 ND ND 1 WG2039147
Bromodichloromethane 75-27-4 164 0.200 1.34 ND ND 1 WG2039147
Bromoform 75-25-2 253 0.600 6.21 ND ND 1 WG2039147
Bromomethane 74-83-9 94.90 0.200 0.776 ND ND 1 WG2039650
1,3-Butadiene 106-99-0 54.10 2.00 4.43 ND ND 1 WG2039650
Carbon disulfide 75-15-0 76.10 0.200 0.622 ND ND 1 WG2039650
Carbon tetrachloride 56-23-5 154 0.200 1.26 ND ND 1 WG2039650
Chlorobenzene 108-90-7 113 0.200 0.924 ND ND 1 WG2039147
Chloroethane 75-00-3 64.50 0.200 0.528 ND ND 1 WG2039650
Chloroform 67-66-3 119 0.200 0.973 ND ND 1 WG2039650
Chloromethane 74-87-3 50.50 0.200 0.413 2.25 4.65 1 WG2039650
2-Chlorotoluene 95-49-8 126 0.200 1.03 ND ND 1 WG2039147
Cyclohexane 110-82-7 84.20 0.200 0.689 0.464 1.60 1 WG2039650
Dibromochloromethane 124-48-1 208 0.200 1.70 ND ND 1 WG2039147
1,2-Dibromoethane 106-93-4 188 0.200 1.54 ND ND 1 WG2039147
1,2-Dichlorobenzene 95-50-1 147 0.200 1.20 ND ND 1 WG2039147
1,3-Dichlorobenzene 541-73-1 147 0.200 1.20 ND ND 1 WG2039147
1,4-Dichlorobenzene 106-46-7 147 0.200 1.20 ND ND 1 WG2039147
1,2-Dichloroethane 107-06-2 99 0.200 0.810 ND ND 1 WG2039147
1,1-Dichloroethane 75-34-3 98 0.200 0.802 ND ND 1 WG2039650
1,1-Dichloroethene 75-35-4 96.90 0.200 0.793 ND ND 1 WG2039650
cis-1,2-Dichloroethene 156-59-2 96.90 0.200 0.793 ND ND 1 WG2039650
trans-1,2-Dichloroethene 156-60-5 96.90 0.200 0.793 ND ND 1 WG2039650
1,2-Dichloropropane 78-87-5 113 0.200 0.924 ND ND 1 WG2039147
cis-1,3-Dichloropropene 10061-01-5 111 0.200 0.908 ND ND 1 WG2039147
trans-1,3-Dichloropropene 10061-02-6 111 0.200 0.908 ND ND 1 WG2039147
1,4-Dioxane 123-91-1 88.10 0.200 0.721 ND ND 1 WG2039147
Ethanol 64-17-5 46.10 25.0 47.1 206 388 10 WG2042008
Ethylbenzene 100-41-4 106 0.200 0.867 1.24 5.38 1 WG2039147
4-Ethyltoluene 622-96-8 120 0.200 0.982 ND ND 1 WG2039147
Trichlorofluoromethane 75-69-4 137.40 0.200 1.12 0.255 1.43 1 WG2039650
Dichlorodifluoromethane 75-71-8 120.92 0.200 0.989 0.344 1.70 1 WG2039650
1,1,2-Trichlorotrifluoroethane 76-13-1 187.40 0.200 1.53 ND ND 1 WG2039650
1,2-Dichlorotetrafluoroethane 76-14-2 171 0.200 1.40 ND ND 1 WG2039650
Heptane 142-82-5 100 0.200 0.818 1.07 4.38 1 WG2039147
Hexachloro-1,3-butadiene 87-68-3 261 0.630 6.73 ND ND 1 WG2039147
n-Hexane 110-54-3 86.20 0.630 2.22 0.960 3.38 1 WG2039650
Isopropylbenzene 98-82-8 120.20 0.200 0.983 ND ND 1 WG2039147
Methylene Chloride 75-09-2 84.90 0.200 0.694 0.962 3.34 1 WG2039650
Methyl Butyl Ketone 591-78-6 100 1.25 5.11 2.16 8.83 1 WG2039147
2-Butanone (MEK)78-93-3 72.10 1.25 3.69 5.17 15.2 1 WG2039650
4-Methyl-2-pentanone (MIBK)108-10-1 100.10 1.25 5.12 ND ND 1 WG2039147
Methyl methacrylate 80-62-6 100.12 0.200 0.819 ND ND 1 WG2039147
MTBE 1634-04-4 88.10 0.200 0.721 ND ND 1 WG2039650
Naphthalene 91-20-3 128 0.630 3.30 ND ND 1 WG2039147
2-Propanol 67-63-0 60.10 1.25 3.07 4.62 11.4 1 WG2039650
Propene 115-07-1 42.10 1.25 2.15 ND ND 1 WG2039650
Styrene 100-42-5 104 0.200 0.851 ND ND 1 WG2039147
1,1,2,2-Tetrachloroethane 79-34-5 168 0.200 1.37 ND ND 1 WG2039147
Tetrachloroethylene 127-18-4 166 0.200 1.36 5.22 35.4 1 WG2039147
Tetrahydrofuran 109-99-9 72.10 0.200 0.590 ND ND 1 WG2039650
Toluene 108-88-3 92.10 0.500 1.88 7.57 28.5 1 WG2039147
1,2,4-Trichlorobenzene 120-82-1 181 0.630 4.66 ND ND 1 WG2039147
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 02
L1600695
SG-2
Collected date/time: 03/31/23 11:25
Volatile Organic Compounds (MS) by Method TO-15
CAS #Mol. Wt.RDL1 RDL2 Result Result Qualifier Dilution Batch
Analyte ppbv ug/m3 ppbv ug/m3
1,1,1-Trichloroethane 71-55-6 133 0.200 1.09 ND ND 1 WG2039650
1,1,2-Trichloroethane 79-00-5 133 0.200 1.09 ND ND 1 WG2039147
Trichloroethylene 79-01-6 131 0.200 1.07 ND ND 1 WG2039147
1,2,4-Trimethylbenzene 95-63-6 120 0.200 0.982 0.846 4.15 1 WG2039147
1,3,5-Trimethylbenzene 108-67-8 120 0.200 0.982 0.232 1.14 1 WG2039147
2,2,4-Trimethylpentane 540-84-1 114.22 0.200 0.934 0.849 3.97 1 WG2039650
Vinyl chloride 75-01-4 62.50 0.200 0.511 ND ND 1 WG2039650
Vinyl Bromide 593-60-2 106.95 0.200 0.875 ND ND 1 WG2039650
Vinyl acetate 108-05-4 86.10 0.200 0.704 ND ND 1 WG2039650
m&p-Xylene 1330-20-7 106 0.400 1.73 3.70 16.0 1 WG2039147
o-Xylene 95-47-6 106 0.200 0.867 1.21 5.25 1 WG2039147
(S) 1,4-Bromofluorobenzene 460-00-4 175 60.0-140 102 WG2039147
(S) 1,4-Bromofluorobenzene 460-00-4 175 60.0-140 103 WG2039650
(S) 1,4-Bromofluorobenzene 460-00-4 175 60.0-140 89.8 WG2042008
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2039147
Volatile Organic Compounds (MS) by Method TO-15 L1600695-01,02
Method Blank (MB)
(MB) R3911633-3 04/10/23 10:55
MB Result MB Qualifier MB MDL MB RDL
Analyte ppbv ppbv ppbv
Acetone U 0.584 1.25
Allyl Chloride U 0.114 0.200
Benzene U 0.0715 0.200
Benzyl Chloride U 0.0598 0.200
Bromodichloromethane U 0.0702 0.200
Bromoform U 0.0732 0.600
Bromomethane U 0.0982 0.200
1,3-Butadiene U 0.104 2.00
Carbon disulfide U 0.102 0.200
Carbon tetrachloride U 0.0732 0.200
Chlorobenzene U 0.0832 0.200
Chloroethane U 0.0996 0.200
Chloroform U 0.0717 0.200
Chloromethane U 0.103 0.200
2-Chlorotoluene U 0.0828 0.200
Cyclohexane U 0.0753 0.200
Dibromochloromethane U 0.0727 0.200
1,2-Dibromoethane U 0.0721 0.200
1,2-Dichlorobenzene U 0.128 0.200
1,3-Dichlorobenzene U 0.182 0.200
1,4-Dichlorobenzene U 0.0557 0.200
1,2-Dichloroethane U 0.0700 0.200
1,1-Dichloroethane U 0.0723 0.200
1,1-Dichloroethene U 0.0762 0.200
cis-1,2-Dichloroethene U 0.0784 0.200
trans-1,2-Dichloroethene U 0.0673 0.200
1,2-Dichloropropane U 0.0760 0.200
cis-1,3-Dichloropropene U 0.0689 0.200
trans-1,3-Dichloropropene U 0.0728 0.200
1,4-Dioxane U 0.0833 0.200
Ethanol U 0.265 1.25
Ethylbenzene U 0.0835 0.200
4-Ethyltoluene U 0.0783 0.200
Trichlorofluoromethane U 0.0819 0.200
Dichlorodifluoromethane U 0.137 0.200
1,1,2-Trichlorotrifluoroethane U 0.0793 0.200
1,2-Dichlorotetrafluoroethane U 0.0890 0.200
Heptane U 0.104 0.200
Hexachloro-1,3-butadiene U 0.105 0.630
n-Hexane U 0.206 0.630
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2039147
Volatile Organic Compounds (MS) by Method TO-15 L1600695-01,02
Method Blank (MB)
(MB) R3911633-3 04/10/23 10:55
MB Result MB Qualifier MB MDL MB RDL
Analyte ppbv ppbv ppbv
Isopropylbenzene U 0.0777 0.200
Methylene Chloride U 0.0979 0.200
Methyl Butyl Ketone U 0.133 1.25
2-Butanone (MEK)U 0.0814 1.25
4-Methyl-2-pentanone (MIBK)U 0.0765 1.25
Methyl Methacrylate U 0.0876 0.200
MTBE U 0.0647 0.200
Naphthalene U 0.350 0.630
2-Propanol U 0.264 1.25
Propene U 0.0932 1.25
Styrene U 0.0788 0.200
1,1,2,2-Tetrachloroethane U 0.0743 0.200
Tetrachloroethylene U 0.0814 0.200
Tetrahydrofuran U 0.0734 0.200
Toluene U 0.0870 0.500
1,2,4-Trichlorobenzene U 0.148 0.630
1,1,1-Trichloroethane U 0.0736 0.200
1,1,2-Trichloroethane U 0.0775 0.200
Trichloroethylene U 0.0680 0.200
1,2,4-Trimethylbenzene U 0.0764 0.200
1,3,5-Trimethylbenzene U 0.0779 0.200
2,2,4-Trimethylpentane U 0.133 0.200
Vinyl chloride U 0.0949 0.200
Vinyl Bromide U 0.0852 0.200
Vinyl acetate U 0.116 0.200
m&p-Xylene U 0.135 0.400
o-Xylene U 0.0828 0.200
(S) 1,4-Bromofluorobenzene 96.0 60.0-140
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3911633-1 04/10/23 08:39 • (LCSD) R3911633-2 04/10/23 09:07
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ppbv ppbv ppbv %%%%%
Acetone 3.75 3.22 3.23 85.9 86.1 70.0-130 0.310 25
Allyl Chloride 3.75 3.32 3.22 88.5 85.9 70.0-130 3.06 25
Benzene 3.75 3.41 3.40 90.9 90.7 70.0-130 0.294 25
Benzyl Chloride 3.75 3.58 3.62 95.5 96.5 70.0-152 1.11 25
Bromodichloromethane 3.75 3.52 3.48 93.9 92.8 70.0-130 1.14 25
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2039147
Volatile Organic Compounds (MS) by Method TO-15 L1600695-01,02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3911633-1 04/10/23 08:39 • (LCSD) R3911633-2 04/10/23 09:07
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ppbv ppbv ppbv %%%%%
Bromoform 3.75 3.56 3.50 94.9 93.3 70.0-130 1.70 25
Bromomethane 3.75 3.29 3.34 87.7 89.1 70.0-130 1.51 25
1,3-Butadiene 3.75 3.26 3.40 86.9 90.7 70.0-130 4.20 25
Carbon disulfide 3.75 3.28 3.27 87.5 87.2 70.0-130 0.305 25
Carbon tetrachloride 3.75 3.65 3.63 97.3 96.8 70.0-130 0.549 25
Chlorobenzene 3.75 3.39 3.45 90.4 92.0 70.0-130 1.75 25
Chloroethane 3.75 3.42 3.37 91.2 89.9 70.0-130 1.47 25
Chloroform 3.75 3.47 3.33 92.5 88.8 70.0-130 4.12 25
Chloromethane 3.75 3.29 3.29 87.7 87.7 70.0-130 0.000 25
2-Chlorotoluene 3.75 3.54 3.56 94.4 94.9 70.0-130 0.563 25
Cyclohexane 3.75 3.40 3.33 90.7 88.8 70.0-130 2.08 25
Dibromochloromethane 3.75 3.65 3.44 97.3 91.7 70.0-130 5.92 25
1,2-Dibromoethane 3.75 3.46 3.51 92.3 93.6 70.0-130 1.43 25
1,2-Dichlorobenzene 3.75 3.51 3.43 93.6 91.5 70.0-130 2.31 25
1,3-Dichlorobenzene 3.75 3.56 3.67 94.9 97.9 70.0-130 3.04 25
1,4-Dichlorobenzene 3.75 3.48 3.60 92.8 96.0 70.0-130 3.39 25
1,2-Dichloroethane 3.75 3.15 3.35 84.0 89.3 70.0-130 6.15 25
1,1-Dichloroethane 3.75 3.58 3.62 95.5 96.5 70.0-130 1.11 25
1,1-Dichloroethene 3.75 3.29 3.33 87.7 88.8 70.0-130 1.21 25
cis-1,2-Dichloroethene 3.75 3.34 3.29 89.1 87.7 70.0-130 1.51 25
trans-1,2-Dichloroethene 3.75 3.27 3.22 87.2 85.9 70.0-130 1.54 25
1,2-Dichloropropane 3.75 3.36 3.43 89.6 91.5 70.0-130 2.06 25
cis-1,3-Dichloropropene 3.75 3.43 3.40 91.5 90.7 70.0-130 0.878 25
trans-1,3-Dichloropropene 3.75 3.37 3.35 89.9 89.3 70.0-130 0.595 25
1,4-Dioxane 3.75 3.75 3.62 100 96.5 70.0-140 3.53 25
Ethanol 3.75 3.11 3.14 82.9 83.7 55.0-148 0.960 25
Ethylbenzene 3.75 3.47 3.62 92.5 96.5 70.0-130 4.23 25
4-Ethyltoluene 3.75 3.64 3.62 97.1 96.5 70.0-130 0.551 25
Trichlorofluoromethane 3.75 3.66 3.68 97.6 98.1 70.0-130 0.545 25
Dichlorodifluoromethane 3.75 3.38 3.43 90.1 91.5 64.0-139 1.47 25
1,1,2-Trichlorotrifluoroethane 3.75 3.23 3.31 86.1 88.3 70.0-130 2.45 25
1,2-Dichlorotetrafluoroethane 3.75 3.31 3.36 88.3 89.6 70.0-130 1.50 25
Heptane 3.75 2.99 3.13 79.7 83.5 70.0-130 4.58 25
Hexachloro-1,3-butadiene 3.75 3.15 3.34 84.0 89.1 70.0-151 5.86 25
n-Hexane 3.75 3.16 3.21 84.3 85.6 70.0-130 1.57 25
Isopropylbenzene 3.75 3.51 3.59 93.6 95.7 70.0-130 2.25 25
Methylene Chloride 3.75 3.06 3.21 81.6 85.6 70.0-130 4.78 25
Methyl Butyl Ketone 3.75 3.55 3.52 94.7 93.9 70.0-149 0.849 25
Methyl Ethyl Ketone 3.75 3.39 3.54 90.4 94.4 70.0-130 4.33 25
4-Methyl-2-pentanone (MIBK)3.75 3.21 3.22 85.6 85.9 70.0-139 0.311 25
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2039147
Volatile Organic Compounds (MS) by Method TO-15 L1600695-01,02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3911633-1 04/10/23 08:39 • (LCSD) R3911633-2 04/10/23 09:07
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ppbv ppbv ppbv %%%%%
Methyl Methacrylate 3.75 3.45 3.47 92.0 92.5 70.0-130 0.578 25
MTBE 3.75 3.51 3.48 93.6 92.8 70.0-130 0.858 25
Naphthalene 3.75 3.62 3.61 96.5 96.3 70.0-159 0.277 25
2-Propanol 3.75 3.35 3.30 89.3 88.0 70.0-139 1.50 25
Propene 3.75 3.11 3.19 82.9 85.1 64.0-144 2.54 25
Styrene 3.75 3.61 3.54 96.3 94.4 70.0-130 1.96 25
1,1,2,2-Tetrachloroethane 3.75 3.60 3.58 96.0 95.5 70.0-130 0.557 25
Tetrachloroethylene 3.75 3.35 3.34 89.3 89.1 70.0-130 0.299 25
Tetrahydrofuran 3.75 3.23 3.24 86.1 86.4 70.0-137 0.309 25
Toluene 3.75 3.37 3.32 89.9 88.5 70.0-130 1.49 25
1,2,4-Trichlorobenzene 3.75 3.45 3.46 92.0 92.3 70.0-160 0.289 25
1,1,1-Trichloroethane 3.75 3.46 3.43 92.3 91.5 70.0-130 0.871 25
1,1,2-Trichloroethane 3.75 3.61 3.39 96.3 90.4 70.0-130 6.29 25
Trichloroethylene 3.75 3.44 3.41 91.7 90.9 70.0-130 0.876 25
1,2,4-Trimethylbenzene 3.75 3.54 3.61 94.4 96.3 70.0-130 1.96 25
1,3,5-Trimethylbenzene 3.75 3.44 3.53 91.7 94.1 70.0-130 2.58 25
2,2,4-Trimethylpentane 3.75 3.24 3.25 86.4 86.7 70.0-130 0.308 25
Vinyl chloride 3.75 3.20 3.25 85.3 86.7 70.0-130 1.55 25
Vinyl Bromide 3.75 3.71 3.70 98.9 98.7 70.0-130 0.270 25
Vinyl acetate 3.75 2.87 2.47 76.5 65.9 70.0-130 J4 15.0 25
m&p-Xylene 7.50 7.02 7.12 93.6 94.9 70.0-130 1.41 25
o-Xylene 3.75 3.54 3.66 94.4 97.6 70.0-130 3.33 25
(S) 1,4-Bromofluorobenzene 100 101 60.0-140
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2039650
Volatile Organic Compounds (MS) by Method TO-15 L1600695-02
Method Blank (MB)
(MB) R3912124-3 04/11/23 11:16
MB Result MB Qualifier MB MDL MB RDL
Analyte ppbv ppbv ppbv
Acetone U 0.584 1.25
Allyl Chloride U 0.114 0.200
Bromomethane U 0.0982 0.200
1,3-Butadiene U 0.104 2.00
Carbon disulfide U 0.102 0.200
Carbon tetrachloride U 0.0732 0.200
Chloroethane U 0.0996 0.200
Chloroform U 0.0717 0.200
Chloromethane U 0.103 0.200
Cyclohexane U 0.0753 0.200
1,1-Dichloroethane U 0.0723 0.200
1,1-Dichloroethene U 0.0762 0.200
cis-1,2-Dichloroethene U 0.0784 0.200
trans-1,2-Dichloroethene U 0.0673 0.200
Trichlorofluoromethane U 0.0819 0.200
Dichlorodifluoromethane U 0.137 0.200
1,1,2-Trichlorotrifluoroethane U 0.0793 0.200
1,2-Dichlorotetrafluoroethane U 0.0890 0.200
n-Hexane U 0.206 0.630
Methylene Chloride U 0.0979 0.200
2-Butanone (MEK)U 0.0814 1.25
MTBE U 0.0647 0.200
2-Propanol U 0.264 1.25
Propene U 0.0932 1.25
Tetrahydrofuran U 0.0734 0.200
1,1,1-Trichloroethane U 0.0736 0.200
2,2,4-Trimethylpentane U 0.133 0.200
Vinyl chloride U 0.0949 0.200
Vinyl Bromide U 0.0852 0.200
Vinyl acetate U 0.116 0.200
(S) 1,4-Bromofluorobenzene 99.9 60.0-140
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3912124-1 04/11/23 09:59 • (LCSD) R3912124-2 04/11/23 10:38
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ppbv ppbv ppbv %%%%%
Acetone 3.75 4.16 4.05 111 108 70.0-130 2.68 25
Allyl Chloride 3.75 4.04 4.23 108 113 70.0-130 4.59 25
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2039650
Volatile Organic Compounds (MS) by Method TO-15 L1600695-02
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3912124-1 04/11/23 09:59 • (LCSD) R3912124-2 04/11/23 10:38
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ppbv ppbv ppbv %%%%%
Bromomethane 3.75 4.21 4.18 112 111 70.0-130 0.715 25
1,3-Butadiene 3.75 4.07 4.12 109 110 70.0-130 1.22 25
Carbon disulfide 3.75 3.63 3.63 96.8 96.8 70.0-130 0.000 25
Carbon tetrachloride 3.75 3.88 3.81 103 102 70.0-130 1.82 25
Chloroethane 3.75 4.15 4.17 111 111 70.0-130 0.481 25
Chloroform 3.75 4.05 3.98 108 106 70.0-130 1.74 25
Chloromethane 3.75 4.04 4.05 108 108 70.0-130 0.247 25
Cyclohexane 3.75 3.91 3.78 104 101 70.0-130 3.38 25
1,1-Dichloroethane 3.75 4.00 4.00 107 107 70.0-130 0.000 25
1,1-Dichloroethene 3.75 3.62 3.61 96.5 96.3 70.0-130 0.277 25
cis-1,2-Dichloroethene 3.75 4.02 3.98 107 106 70.0-130 1.00 25
trans-1,2-Dichloroethene 3.75 3.99 4.09 106 109 70.0-130 2.48 25
Trichlorofluoromethane 3.75 4.27 4.35 114 116 70.0-130 1.86 25
Dichlorodifluoromethane 3.75 2.91 2.76 77.6 73.6 64.0-139 5.29 25
1,1,2-Trichlorotrifluoroethane 3.75 4.33 4.18 115 111 70.0-130 3.53 25
1,2-Dichlorotetrafluoroethane 3.75 4.06 3.99 108 106 70.0-130 1.74 25
n-Hexane 3.75 4.04 4.08 108 109 70.0-130 0.985 25
Methylene Chloride 3.75 4.13 4.12 110 110 70.0-130 0.242 25
Methyl Ethyl Ketone 3.75 4.00 3.93 107 105 70.0-130 1.77 25
MTBE 3.75 3.96 3.99 106 106 70.0-130 0.755 25
2-Propanol 3.75 4.05 3.96 108 106 70.0-139 2.25 25
Propene 3.75 4.23 4.17 113 111 64.0-144 1.43 25
Tetrahydrofuran 3.75 4.06 4.04 108 108 70.0-137 0.494 25
1,1,1-Trichloroethane 3.75 3.87 3.86 103 103 70.0-130 0.259 25
2,2,4-Trimethylpentane 3.75 3.98 3.96 106 106 70.0-130 0.504 25
Vinyl chloride 3.75 4.29 4.23 114 113 70.0-130 1.41 25
Vinyl Bromide 3.75 4.08 4.09 109 109 70.0-130 0.245 25
Vinyl acetate 3.75 4.22 4.35 113 116 70.0-130 3.03 25
(S) 1,4-Bromofluorobenzene 97.3 98.1 60.0-140
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2042008
Volatile Organic Compounds (MS) by Method TO-15 L1600695-02
Method Blank (MB)
(MB) R3913319-3 04/14/23 09:06
MB Result MB Qualifier MB MDL MB RDL
Analyte ppbv ppbv ppbv
Ethanol 0.580 J 0.265 2.50
(S) 1,4-Bromofluorobenzene 88.6 60.0-140
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3913319-1 04/14/23 08:07 • (LCSD) R3913319-2 04/14/23 08:37
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ppbv ppbv ppbv %%%%%
Ethanol 3.75 4.09 4.04 109 108 55.0-148 1.23 25
(S) 1,4-Bromofluorobenzene 94.6 94.9 60.0-140
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec.Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Dilution
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Limits
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Qualifier
This column provides a letter and/or number designation that corresponds to additional information concerning the result
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
Result
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL”
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)Confidence level of 2 sigma.
Case Narrative (Cn)
A brief discussion about the included sample results, including a discussion of any non-conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
Summary (Qc)
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
Sample Chain of
Custody (Sc)
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
Sample Results (Sr)
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
J The identification of the analyte is acceptable; the reported value is an estimate.
J4 The associated batch QC was outside the established quality control range for accuracy.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN000032021-1
Arizona AZ0612 New Hampshire 2975
Arkansas 88-0469 New Jersey–NELAP TN002
California 2932 New Mexico ¹TN00003
Colorado TN00003 New York 11742
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina ¹DW21704
Georgia NELAP North Carolina ³41
Georgia ¹923 North Dakota R-140
Idaho TN00003 Ohio–VAP CL0069
Illinois 200008 Oklahoma 9915
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979
Kansas E-10277 Rhode Island LAO00356
Kentucky ¹ ⁶KY90010 South Carolina 84004002
Kentucky ²16 South Dakota n/a
Louisiana AI30792 Tennessee ¹ ⁴2006
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas ⁵LAB0152
Maryland 324 Utah TN000032021-11
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033
Minnesota 047-999-395 Washington C847
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA – ISO 17025 ⁵1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA–Crypto TN00003
ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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APPENDIX C
SOIL GAS RISK CALCULATOR RESULTS

Version Date:
Basis:
Site Name:
Site Address:
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
Reviewed By:
5/16/2023
Prepared By:Ethan Dinwiddie, PG
Justin Fabriziani, RSM
On-site Residence
North Carolina Department of Environmental Quality
Risk Calculator
Blalock Fina
3574 NC Hwy 55, Angier, NC
NCDEQ UST Section
UST Incident #24238
January 2023
November 2022 EPA RSL Table
North Carolina DEQ Risk Calculator
Complete Exposure Pathways
Version Date: January 2023
Basis: November 2022 EPA RSL Table
Site ID: UST Incident #24238
Exposure Unit ID: On-site Residence
Note: Risk output will only be calculated for complete exposure pathways.
Receptor Pathway
Check box if
pathway
complete
Soil
Groundwater Use
Soil
Groundwater Use
Construction Worker Soil
Soil
Surface Water
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Groundwater to Indoor Air
Soil Gas to Indoor Air
Indoor Air
Source Soil
Source Groundwater
Source Soil
Source Groundwater
Input Form 1A
VAPOR INTRUSION PATHWAYS
DIRECT CONTACT SOIL AND WATER PATHWAYS
Resident
Non-Residential Worker
Recreator/Trespasser
Resident
Non-Residential Worker
CONTAMINANT MIGRATION PATHWAYS
Groundwater
Surface Water
North Carolina DEQ Risk Calculator
Exposure Point Concentrations
Version Date: January 2023
Basis: November 2022 EPA RSL Table
Site ID: UST Incident #24238
Exposure Unit ID: On-site Residence
Description of Exposure Point Concentration Selection:
Exposure Point
Concentration
(ug/m3)
Notes:CAS Number Chemical MinimumConcentration(Qualifier)
MaximumConcentration(Qualifier)
Units Location ofMaximumConcentration
Detection
Frequency
Range ofDetectionLimits
ConcentrationUsed forScreening
Background
Value
ScreeningToxicity Value
(Screening
Level) (n/c)
PotentialARAR/TBCValue
PotentialARAR/TBCSource
COPC Flag
(Y/N)
Rationale forSelection orDeletion
47.1 67-64-1 Acetone ug/m3 SG-02
4.65 74-87-3 Chloromethane ug/m3 SG-02
1.6 110-82-7 Cyclohexane ug/m3 SG-02
1.7 75-71-8 Dichlorodifluoromethane ug/m3 SG-02
5.38 100-41-4 Ethylbenzene ug/m3 SG-02
11 142-82-5 Heptane, N-ug/m3 SG-01
3.38 110-54-3 Hexane, N-ug/m3 SG-02
8.83 591-78-6 Hexanone, 2-ug/m3 SG-02
11.4 67-63-0 Isopropanol ug/m3 SG-02
15.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 SG-02
3.34 75-09-2 Methylene Chloride ug/m3 SG-02
37.3 127-18-4 Tetrachloroethylene ug/m3 SG-01
30.9 108-88-3 Toluene ug/m3 SG-01
1.43 75-69-4 Trichlorofluoromethane ug/m3 SG-02
4.15 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 SG-02
1.15 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 SG-01
16 108-38-3 Xylene, m-ug/m3 SG-02
5.46 95-47-6 Xylene, o-ug/m3 SG-01
Input Form 2D
Soil Gas Exposure Point Concentration Table
Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.
If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations
North Carolina DEQ Risk Calculator
Risk for Individual Pathways Output Form 1A
Version Date: January 2023
Basis: November 2022 EPA RSL Table
Site ID: UST Incident #24238
Exposure Unit ID: On-site Residence
Receptor Pathway Carcinogenic
Risk Hazard Index Risk exceeded?
Soil NC NC NC
Groundwater Use*NC NC NC
Soil NC NC NC
Groundwater Use*NC NC NC
Construction Worker Soil NC NC NC
Soil NC NC NC
Surface Water*NC NC NC
Receptor Pathway Carcinogenic
Risk Hazard Index Risk exceeded?
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air 2.5E-07 4.9E-02 NO
Indoor Air NC NC NC
Groundwater to Indoor Air NC NC NC
Soil Gas to Indoor Air 1.9E-08 3.9E-03 NO
Indoor Air NC NC NC
Pathway Source
Source Soil NC
Source Groundwater NC
Source Soil NC
Source Groundwater NC
3. NM = Not modeled, user did not check this pathway as complete.
4. NC = Pathway not calculated, required contaminant migration parameters were not entered.
DIRECT CONTACT SOIL AND WATER CALCULATORS
Resident
Non-Residential Worker
Recreator/Trespasser
2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the
NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based
closure.
Surface Water Exceedence of 2B at Receptor?
Exceedence of 2B at Receptor?
VAPOR INTRUSION CALCULATORS
Resident
Non-Residential Worker
CONTAMINANT MIGRATION CALCULATORS
Target Receptor Concentrations Exceeded?
Groundwater Exceedence of 2L at Receptor?
Exceedence of 2L at Receptor?
1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead
concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations.
Notes:
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air
Version Date: January 2023
Basis: November 2022 EPA RSL Table
Site ID: UST Incident #24238
Exposure Unit ID: On-site Residence
CAS #Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 47.1 1.413 --
74-87-3 Chloromethane 4.65 0.1395 -1.9E+01 1.5E-03
110-82-7 Cyclohexane 1.6 0.048 -1.3E+03 7.7E-06
75-71-8 Dichlorodifluoromethane 1.7 0.051 -2.1E+01 4.9E-04
100-41-4 Ethylbenzene 5.38 0.1614 1.1E+00 2.1E+02 1.4E-07 1.5E-04
142-82-5 Heptane, N-11 0.33 -8.3E+01 7.9E-04
110-54-3 Hexane, N-3.38 0.1014 -1.5E+02 1.4E-04
591-78-6 Hexanone, 2-8.83 0.2649 -6.3E+00 8.5E-03
67-63-0 Isopropanol 11.4 0.342 -4.2E+01 1.6E-03
78-93-3 Methyl Ethyl Ketone (2-Butanone)15.2 0.456 -1.0E+03 8.7E-05
75-09-2 Methylene Chloride 3.34 0.1002 1.0E+02 1.3E+02 9.9E-10 1.6E-04
127-18-4 Tetrachloroethylene 37.3 1.119 1.1E+01 8.3E+00 1.0E-07 2.7E-02
108-88-3 Toluene 30.9 0.927 -1.0E+03 1.8E-04
75-69-4 Trichlorofluoromethane 1.43 0.0429 --
95-63-6 Trimethylbenzene, 1,2,4-4.15 0.1245 -1.3E+01 2.0E-03
108-67-8 Trimethylbenzene, 1,3,5-1.15 0.0345 -1.3E+01 5.5E-04
108-38-3 Xylene, m-16 0.48 -2.1E+01 4.6E-03
95-47-6 Xylene, o-5.46 0.1638 -2.1E+01 1.6E-03
Cumulative:2.5E-07 4.9E-02
All concentrations are in ug/m3
Output Form 3B
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air
Version Date: January 2023
Basis: November 2022 EPA RSL Table
Site ID: UST Incident #24238
Exposure Unit ID: On-site Residence
CAS #Chemical Name:
Soil Gas
Concentration
(ug/m3)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non-
Carcinogenic
Hazard
Quotient
67-64-1 Acetone 47.1 0.471 --
74-87-3 Chloromethane 4.65 0.0465 -7.9E+01 1.2E-04
110-82-7 Cyclohexane 1.6 0.016 -5.3E+03 6.1E-07
75-71-8 Dichlorodifluoromethane 1.7 0.017 -8.8E+01 3.9E-05
100-41-4 Ethylbenzene 5.38 0.0538 4.9E+00 8.8E+02 1.1E-08 1.2E-05
142-82-5 Heptane, N-11 0.11 -3.5E+02 6.3E-05
110-54-3 Hexane, N-3.38 0.0338 -6.1E+02 1.1E-05
591-78-6 Hexanone, 2-8.83 0.0883 -2.6E+01 6.7E-04
67-63-0 Isopropanol 11.4 0.114 -1.8E+02 1.3E-04
78-93-3 Methyl Ethyl Ketone (2-Butanone)15.2 0.152 -4.4E+03 6.9E-06
75-09-2 Methylene Chloride 3.34 0.0334 1.2E+03 5.3E+02 2.7E-11 1.3E-05
127-18-4 Tetrachloroethylene 37.3 0.373 4.7E+01 3.5E+01 7.9E-09 2.1E-03
108-88-3 Toluene 30.9 0.309 -4.4E+03 1.4E-05
75-69-4 Trichlorofluoromethane 1.43 0.0143 --
95-63-6 Trimethylbenzene, 1,2,4-4.15 0.0415 -5.3E+01 1.6E-04
108-67-8 Trimethylbenzene, 1,3,5-1.15 0.0115 -5.3E+01 4.4E-05
108-38-3 Xylene, m-16 0.16 -8.8E+01 3.7E-04
95-47-6 Xylene, o-5.46 0.0546 -8.8E+01 1.2E-04
Cumulative:1.9E-08 3.9E-03
All concentrations are in ug/m3
Output Form 3E
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
North Carolina DEQ Risk Calculator