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HomeMy WebLinkAboutNCD991278953_20020508_National Starch & Chemical Corp._FRBCERCLA SPD_Phase II NDTS First Annual Event Results-OCRI I 1BBL I I I I I I I I I I I I I I I I BLASLAND, BOUCK & LEE, 1/\IC engineers & scien'(is/S 183 2188 Transmitted Via Federal Express May 8, 2002 Mr. Jon Bomholm Remedial Project Manager United States Environmental Protection Agency 61 Forsyth Street, S.W. Atlanta, GA 30303-3 I 04 Re: Phase II NOTS First Annual Sampling Event Results Cedar Springs Plant Site Salisbury, North Carolina BBL Project#: 050.07 Dear Mr. Bornholm: On behalf of National Starch & Chemical Company (NSCC), Blasland, Bouck & Lee, Inc. (BBL) is transmitting results of the first annual sampling event of the Phase II Natural Degradation Treatability Study (NOTS) for Operable Unit Four at the Cedar Springs Plant Site located in Salisbury, North Carolina. Figure I is the Site Location Map and Figure 2 presents the Site Map. The Phase II NOTS activities are described in the Phase II NOTS Work Plan for Operable Unit Four (OU4) (BBL, January 2000). The Work Plan was conditionally approved by the United States Environmental Protection Agency in a letter dated June 25, 200 I. This letter presents a description of the field activities and analytical results. As described in the Work Plan, a comprehensive review of the Phase II NOTS will be performed after five annual sampling events have been completed. Results from the first annual Phase II NOTS sampling event indicate: • Samples collected from selected locations where previous sampling indicated elevated concentrations of 1,2-dichloroethane (1,2-DCA), show decreased concentration with time; and • Samples collected from locations near the Northeast Tributary exhibited no soil impacts. Thus natural attenuation has been successful in reducing concentrations to the Record of Decision (ROD) performance standard or the initial estimate of impacted material is significantly greater than actual mass. The remainder of this letter report will describe the field activities, results and future activities. 8 South River Road• Cranbury, NJ 08512-9502 Tel (609) 860-0590 • Voice Mail (609) 860-8072 • Fax (609) 860-0491 • Offices Nalionwide I I I I I I I I I I I I I I I I I I I Field Activities Mr. Jon Bomholm May 8, 2002 Page 2 of5 Soil samples were collected from locations in OU4 during November 6 to 13, 2001. Five pairs of soil borings were performed in randomly selected blocks of the grid covering Area 2. The grid and locations of the soil samples are shown on Figure 3. At each location split spoon samples were collected using a geoprobe from the ground surface to either the water table or refusal of the sampling device. Photo- Ionization Detector (PIO) readings were collected from the length of the soil column and recorded in the project field book. A soil sample was collected for laboratory analysis from the 6-inch soil interval exhibiting the highest PID readings. For the paired samples, the intervals of sample collection were consistent in depth (no greater than two feet difference). Soil samples were analyzed for volatile organic compounds (VOes), nitrate, sulfate, iron, chloride ions, and total organic carbon. Table I presents the highest PIO reading from each 2-foot interval of the randomly selected soil boring location and the interval from which the soil sample was collected. Table 1 also presents the depth at which boring was terminated, either due to encountering the water table or refusal of the sampling device. Soil samples were collected from five locations in Area 2 previously sampled during the Remedial Investigation (RI). At each location, split spoon samples were collected using a geoprobe from the ground surface to either the water table or refusal of the sampling device. A soil sample was collected for laboratory analysis from the interval where the highest 1,2-dichloroethane ( 1,2-DeA) concentration was observed during the RI sampling. The soil boring was screened with a PID and if a soil interval exhibited a higher PID reading than the interval sampled during the RI a second soil sample was collected from the interval with the highest PID reading. The following table indicates the samples collected from the previously sampled locations . . \ i,' -'RISamplc Depth ;,• Adclitional,Sampk Deptli .Sit!"ple . · 'irt,bssY·c<.· : .. '·· -·-rrttiesl· . ---.-- SBA2-06 5.5 8 SBA2-08 19.5 4.5 SBA2-09 13.5 None SBA2-16 3.5 None SBA2-20 5.5 None A soil sample was not collected from the 19.5-foot interval at location SBA2-08. During sampling at this location, saturated conditions were encountered at 18 feet bgs, a sample was collected at the deepest dry interval (17.5 to 18 feet bgs) and submitted to the analytical laboratory. Soil samples were collected continuously every six inches from location SBA2-09 and SBA2-20 to evaluate the concentration of 1,2- DeA throughout the entire soil profile. Soil samples were collected from two locations in the Lagoon Area previously sampled during the RI. Similar to the sampling procedure for Area 2, split spoon samples were collected using a geoprobe from the ground surface to either the water table or refusal of the sampling device. A soil sample was collected for laboratory analysis from the interval where the highest 1,2-DeA concentration was observed during the RI sampling. An additional soil gas monitoring well (SGMW) was installed in a background location. SGMW-4 which was intended to be a background monitoring well exhibited concentrations of 1,2-DeA during previous sampling events. Soil samples were collected at the prospective location and depths for SGMW-9 and analyzed for voes to ensure that the location would provide data from an unimpacted area of the site. Table 2 presents the results from the soil sample. No voes were detected in either of the samples and 18322188 BLASLAND, BOUCK & LEE. INC. engineers & JC/enflsts I I I I I I I I I I I I I I I I I I I Mr. Jon Bornholm May 8, 2002 Page 3 of 5 Table 2 presents the results from the soil sample. No VOCs were detected in either of the samples and SGMW-9 was installed in the northeast comer of the fenced area of the· facility. SGMW-9 was constructed with a screened interval from 2 to 4 and from 6 to 8 feet below ground surface, consiste.nt in construction with the other SGMWs. Soil gas samples were collected from two intervals at each of the nine SGMWs at the site. Soil gas samples were collected using laboratory-supplied stainless steel summa canisters. The summa canisters filled passively at a rate of approximately 50 milliliters per minute. Results Table 3 presents results of soil samples collected from the Area 2 grid. Only VOCs which were detected in at least one sample are included in Table 3. Concentrations of 1,2-DCA and daughter products chloroethane, vinyl chloride, and chloride ions are presented on Figure 4. Concentrations of 1,2-DCA are less than the ROD performance standard of I 69 ug/kg at 19 of the 27 locations sampled. The soil samp_les collected in the vicinity of the Northeast Tributary had no detections of 1,2-DCA. Table 4 presents the results of the soil samples collected from the five previously sampled locations in Area 2. Historical 1,2-DCA analytical results are presented on Figure 5. At each previously sampled location, a soil sample was collected from the interval sampled during the RI, as well as the interval with the highest PIO reading, if this interval differed from the RI-sampled interval. The following table presents the reported 1,2-DCA concentrations from the· RI samples and the corresponding NOTS Phase II samples. 'RI NOTS Phase II 2001 '' Sample Depth 1,2-DCA' COncentri,tion Depth. -l,2:.ocA _Crincen'tration . . ,_ '(ft biis\ -/uo/ko\ /ft bgs) ' /ue/ko\ ' ' SB/\2-06 5.5 29,000 5 -5.5 6,300 SB/\2-08 19.5 1.300EJ 17.5-18 2. IO0 SIJA2-09 13.5 53.000D 13.5 -14 500 Slli\2-I 6 3.5 5401) 3.5 -4 6.8U Slli\2-20 5.5 1.600,000D 5.5 6 2.3) The concentration of 1,2-DCA in the NOTS Phase II samples is less that that of the RI samples with the exception of SBA2-08. Table 5 presents the results of the continuous soil samples collected from SBA2-09 and SBA2-20. At SBA2-09, the greatest 1,2-DCA concentrations are observed in the shallow soil and the greatest observed concentration of 1,2-DCA is shallower than the interval sampled during the RI. At SBA2-20, 1,2-DCA concentrations appear to increase with depth in the soil sample and the greatest observed concentration of 1,2-DCA is deeper than the interval sampled during the RJ. Results of the Area 2 soil sampling indicate: 18~22188 • Samples collected from locations near the Northeast Tributary exhibit no soil impacts. Comparison of these results to representations of soil quality in the RI indicates the area of impacted soil is less than the inferred area of impacted soil in the RI. Thus natural attenuation has been successful in reducing concentrations to the ROD performance standard or the initial BLASLAND. BOUCK & LEE. INC. engineers & sclenf/sts I I I I I I I I I I I I I I I I I I I Mr. Jon Bornholm May 8, 2002 Page 4 of5 • Collection of samples from selected locations where previous sampling indicated elevated concentrations of 1,2-OCA shows decreased concentration with time. Although the data indicate decreases in concentration, estimation of site specific degradation rates is premature because natural degradation processes typically are not linear. Future samples collected in the vicinity of these samples will provide data that will be used to estimate site-specific 1,2-OCA degradation rates. Table 6 presents the results of the soil samples collected from the two previously sampled locations in the Lagoon Area. Figure 6 presents the historical 1,2-OCA analytical results for samples from the Lagoon Area. The concentration of 1,2-OCA in soil boring SBLA-13 during the RI sampling was reported to be 16,000 ug/kg (I 1.5 feet bgs). The NOTS Phase II sample in soil boring SBLA-13 from the interval l l to 11.5 feet bgs has a 1,2-OCA concentration of 1,500 ug/kg. The concentration of 1,2-OCA in soil boring SBLA-14 during the Rl sampling was reported to be 290 ug/kg (3.5 ft bgs). The NOTS Phase II sample in soil boring SBLA-14 from the interval 3 to 3.5 ft bgs has a non-detect concentration of l,2-OCA at 7.6 ug/kg. Table 7 presents the results of the soil gas samples collected from the 9 SGMWs. Only VOCs which were detected in at least one sample are included in Table 7. Figures 7 and 8 present the historical 1,2- OCA concentrations from the SGMWs in the shallow and deep monitoring intervals, respectively. SGMW-9 and SGMW-4 have no detections of I ,2-OCA or its daughter products. Future Activities The second annual sampling event of the Phase II NOTS will occur in November 2002. The following Area 2 grid sampling locations will be resampled in 2002, SB-012B, SB-l24A, SB-124B, SB-146A, SB- 146B, SB-199A, SB-229A, SB-229B. Twelve Area 2 grid sampling locations will be eliminated as l,2- OCA was not detected at the location. Of the twelve locations to be eliminated, ten of the locations are paired samples from five grid blocks. In 2002, five grid blocks will be randomly selected and two samples will be collected from each grid block. Two additional grid blocks will be selected to replace the two additional samples to be eliminated. Four of the five resampled Area 2 locations have detections of 1,2-OCA. These four locations will be sampled in 2002. The fifth location, SBA2-l 6, will be eliminated from the sampling program. In the Lagoon Area, SBLA-13 has a detectable concentration of l,2-OCA and will be sampled in 2002. SBLA- 14 will be eliminated from the sampling program as 1,2-OCA was not detected in this sample. The following table lists the soil samples that will be collected during the November 2002 sampling event. SB-012B SB-124B SBA2-06 SIJLA-13 Sll-124A Sll-199A SIJA2-08 7 paired samples from SB-124B SB-229A SBA2-09 selected grid blocks SB-124A SB-229B SBA2-20 Soil gas samples will be collected from the 9 SGMWs. An interim data report will be prepared upon receipt of the results from the analytical laboratory. BLASLAND, BOUCK & LEE. INC. 18322188 &nglnaars a scientists I I I I I I I I I I I I I I I I I I I Mr. Jon Bornholm May 8, 2002 Page S ofS At the conclusion of the fifth year of sampling a final report will be prepared. The final report will contain: the data collected during the field activities; analysis of the field data with respect to an estimation of the mass of 1,2-DCA present and degradation rate of 1,2-DCA in the soils; and analysis of 1,2-DCA degradation pathways using the parameters collected during the field sampling. If you have any questions or comments please contact me at (925) 274-1100 or mpf@bbl-inc.com. Sincerely, BLASLAND, BOUCK & LEE, INC. -~-·-----c.~-----.. V Michael P. Fleischner, P.E. Manager, Engineering M PF /CJY /hr! Enclosures cc: Angela Doh!, National Starch & Chemical Company Richard Franklin, National Starch & Chemical Company Catherine J. Yewdall, Blasland, Bouck & Lee, Inc. 18322188 BLASLAND. BOUCK & LEE. INC. engineers & Jc/ant/sis I I I I I I I I I I I I I I I I I I I Location SB-012A SB-0128 SB-034A SB-0348 SB-036A SB-036B SB-124A SB-124B SB-146A SB-146B SB-158A SB-158B SB-173A SB-173B SB-194A SB-194B SB-199A SB-199B SB-229A SB-229B 0-2 0 0 0.0 0.0 0.0 3.2@ 1.5' 5.5@ I' 16.3@ ]' 4.5@ 2' 28@ 2' 0 2.2@ 2' 4.0 0 15.5@ 0.5' 20.5@ I' 2.8@ 0.5' 0 2.5@ I' 0 2 4 0 0 0.0 0.0 0.0 27.3@ 2.5' 17@ 2.5' 10.5@ 2.5' 1.9@ 4' 91@ 2.5' 0 2.0@ 4' 1.4 0 3.4@ 3' 4.6@ 3.5' 0 0 3.4@ 2' 0 4 6 6 8 8 10 0 0 0 0 0 0 0.0 14@ 8' 6.8@ 9' 0.0 Refusal at 5.5' Sample collected from 5 5.5' Saturated at 2' 10-12 0 0 1.9@ 10.5 Table I PID Readings and Sample Intervals National Starch & Chemical Company Cedar Springs Plant Site, Salisbury, NC Dcnth Interval 12-14 14 16 16 -18 0 2.4@ 15.5' 2.0@ 17' 1.0@ 13' 0 3.4@ 17.5' Refusal at 11.5' Sample collected from 7.5 -8' Sample collected from 1.5 2' I 14@ 4.5' Saturated at 4.5' Samo le collected from 4 4.5' 64 @4' 10@ 7.5' 25 @9' 52@ II' 15@ 12.5' 4@ 15' 8@ 18' 148@ 5' 40@ 7' 25@ 8.5 21 @ 11.5 7.4@ 13' 13.6@ 15' 56@ 17.5' 37@ 5' 25@ 6.5' 4.5@ 9.5' 14.3@11' 6.4@ 13.5' 1.2@ 14.5' 2.7@ 17.5' 9.6@ 5' 10@7' 4.8@ 9.5' 2.5@ 10.5' 2.5@ II' 25@ 15.5' 5@ 17' 0 3.6 3.5@ 8' 67@ II' 25 @ 12' 65@ 14' 60@ 17' 3.4@ 5' 0 5.3@ 10' 5.8@ 11' 83.5@ 13' 4.5@ 15' 19@ 18' 1.6@ 4.5' 4.5@ 8' 0 Saturated at 8.5' Samole collected from 7.5 -8' 3.4 @ 6' 0 Saturated at 7.5' Sample collected from 5.5 -6' Saturated at 3' Sample collected from 0 0.5' 0.7@ 5' NA Saturated at 6', recovery from 6 -8' highly weathered rock Samnle collected from 3.5 4' 3.4@ 5' 0 I 13@ 9.5' 400@ II' 0 2.0@ 15.5' 17@ 19' 2.9@ 5' 1.4@ 7' 0 1.2 @ 12' 17@]3.5' Refusal at 14' Page I of I 18-20 20-22 22-24 24-26 26-28 I 28 -30 I 32-34 1.4@ 18' Refusal at 20' Sample collected from 15.5 -16' I.I@ 19' Refusal at 20' Sample collected from 17.5-18' Saturated at I 8' Sample collected from 4 -4.5 Saturated at 18' Sample collected from 5 -5.5' 1.8@ 19' Saturated at 20' Sample collected from 5 -5.5' 48@ 18.5' Saturated at 20' -Refusal at 22' Sample collected from 2.5 -3' 1.0@ 20' Saturated at 18.5' Sample collected from 11 -11.5' Saturated at 16.5' Samole collected from 13 -13.5' 0 Refusal @ 20' Sample collected from 11 -11.5' Sample collected from I 3.5 -14' 0 0 0 0 13.9@ 0 0 0 0 0 0 Saturated at 25' 13.5' Samole collected from 13.5-14' 0 0 0 10.4@ 11' 3.4@ 13' 1.0@ 15.5' 3.1@ 17.5' 1.7@19' 0 0 0 Saturated at 24.5' Sample collected from 11 - I I .5' F:IPROJECTS\NSCaOU4\NDTS Interim Reportltablel .doc I I I I I I I I I I I I I I I I I I I soilresu1ts.xls Table 2 SGMW-9 Preliminary Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC Sample Number CIK140189017 CIKI40189018 Sample ID SGMW-9 SGMW-9 Sample Depth 4.5 - 5 7.5 - 8 Matrix SOIL SOIL Sample Date 11/13/2001 11/13/2001 SDG CIKl40189 CIKI40189 Volatile Or11anic Compounds (ur,fh) 1.1, I-Trichloroethane 5.4 U 5 U I, 1,2.2-Tetrachloroethanc 5.4 U 5 U I, l ,2-Trichloro-1,2,2-5.4 U SU trinuoroethanc I, I ,2-Trichloroethane 5.4 U 5 U I, 1-Dichlorocthanc 5.4 U 5 U I, 1-Dichloroethcne 5.4 U 5 U 1,2-Dibromo-3-chloropropane II U 9.9 U 1,2-Dibromocthanc 5.4 U 5 U 1,2-Dichloroethane 5.4 U 5 U 1.2-Dichloropropane 5.4 U 5 U 2-Butanone 21 U 20 U 2-Hexanone 21 U 20 U 4-Methyl-2-pcntanone 21 U 20 U Acetone 6.2 J 20 U Benzene 5.4 U 5 U Bromodichloromethane 5.4 U 5 U Bromoform 5.4 U 5 U Bromomethane II U 9.9 U Carbon tetrachloride 5.4 U ,· 5 U Chlorobenzene 5.4 U 5 U Chloroethane II U 9.9 U Chlorofonn 5.4 U SU Chloromethane II U 9.9 U cis-1,2-Dichloroethene 5.4 U 5 U cis-1,3-Dichloropropene 5.4 U 5 U Cyclohexanc 5.4 U 5 U Dibromochloromethane 5.4 U 5 U Dichlorodifluoromethane II U 9.9 U Ethyl benzene 5.4 U 5 U lsopropylbenzene 5.4 U 5 U Methyl acetate 5.4 U 5 U Methyl tert-butyl ether 5.4 U 5 U Methylcyclohexane 5.4 U 5 U Methylene chloride 5.4 U 5 U Styrene 5.4 U 5 U Tctrachlorocthene 5.4 U 5 U Toluene 5.4 U 5 U trans-1,2-Dichloroethene 5.4 U 5 U trans-1,3-Dichloropropene 5.4 U 5 U Trichloroethene 5.4 U 5 U Trichlorofluoromethane II U 9.9 U Vinyl chloride II U 9.9 U Xylenes (total) 16 U 15 U Semi-Volatile OrJ!.anic Comvo1mds (111!.lkJ!.) 1,2-Dichlorobenzene 5.4 U 5 U 1,3-Dichlorobenzene 5.4 U 5 U 1,4-Dich\orobcnzene 5.4 U 5 U 1,2,4-Trichlorobenzene 5.4 U 5 U U -analyte 1s not detected al the mdmtcd concentrat10n Page 1 of 1 --- Sample Number Sample.ID Sample Depth Matrix Sample Date SDG Volatile Organic Compounds 'ue/k,) l, l ,2-Trichloroethane l, 1-Dichloroethene 1,2-Dichloroethane I, 2-Dichloropropane 2-Butanone 2-Hexanone 4-Methyl-2-pentanone Acetone Benzene Chlorobenzene Chloroethane Chloroform cis-1,2-Dichloroethene Cyclohexane ' Ethylbenzcne Isopropylbenzene Methyl acetate Methylcyclohexane Methylene chloride Tetrach!oroethene Toluene Trichloroethene Vinyl chloride X ylenes (lOtal) Semi-Volatile Organic Comvound\' (uelkr!) 1,4-Dichlorobcnzene Inorganic Compound.\' (uglkg) · Chloride Iron Total Organic Carbon Nitrate ---·-·- CIK090138003 CIK090138004 SB-012A-01 SB-012B-0I 15.5 -16 17.5 -18 SOIL SOIL 11/8/2001 11/8/2001 CIK090138 CIK090138 4.2 U SU 4.2 U SU 4.2 U 54 4.2 U 1.6 J 17 U 20 U 17 U 20 U 17U 20 U 17 U 9.4 J 4.2 U 5 U 4.2 U 5 U 8.3 U to u 4.2 U 5 U 4.2 U 5U 4.2 U 5 U 4.2 U 5 U 4.2 U 5 U 4.2 U 5 U 4.2 U 5 U 4.2 U 5 U 4.2 U SU 4.2 U 1.5 J . 4.2 U 5U 8.3 U to u 12 U 15 U 4.2 U I 5 U 10.9 U 11.6 U 21,600 11,600 54.6 U 58.1 U 0.55 U 0.58 U Table 3 Area 2 Grid Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC CIK090138001 CIK090138007 SB-034A-01 SB-DUP0l-01 7.5 - 8 SOIL SOIL 11/8/2001 11/8/2001 CIK090138 CIK090138 5.7 U 5.3 U 5.7 U 5.3 U 5.7.U 2.6 J 5.7 U 5.3 U 23 U 21 U 23 U 21 U 23 U 21 U 38 43 5.7 U 5.3 U 5.7 U 5.3 U 11 U 11 U 5.7 U 5.3 U 5.7 U 5.3 U 5.7 U 5.3 U 5.7 U 5.3 U 5.7 U 5.3 U 5.7 U 5.3 U 5.7 U 5.3 U 5.7 U 5.3 U 5.7 U 5.3 U 2.5 J 2.6 J 5.7 U 5.3 U II U II U 17 U 16 U I 5.7 U I 5.3 U 13.5 U 12.3 U 38,200 38,200 67.3 U 61.4 U 0.67 U 0.61 U U -analyte 1s not detected at the md1cated concentration NA -analyte was not analyzed in the sample J -compound was detected at an estimated concentration below the reporting limit E -reported concentration exceeded the instrument calibration range SB-DUP0l-01 is a duplicate sample of SB-034A-01(7.5-8) CIK090138002 SB-034B-0I 5-5.5 SOIL 11/8/2001 CIK090138 4.3 U 4.3 U 4.3 U 4.3 U 17 U 17 U 17 U 17 U 4.3 U 4.3 U 8.5 U 4.3 U 4.3 U 4.3 U 4.3 U 4.3 U 4.3 U 4.3 U 4.3 U 4.3 U 2 J 4.3 U 8.5 U 13 U 1 4.3 U 11.5 U 85,900 57.4 U 0.57 U F:\PAOJECTS\NSCC\OU4\remevalres\soilresu!ts.xls Page 1 of 4 Cl K070187001 CIK070187002 SB-036A-01 SB-036B-0l LS - 2 4-4.5 SOIL SOIL 11/6/2001 11/6/2001 CIK070187 CIK070187 . 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 20 U 26 U 20 U 26 U 20 U 26 U 20 U 81 4.9 U 6.5 U 4.9 U 6.5 U . 9.8 U 13 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 4.9 U 6.5 U 9.8 U 13 U 15 U 20 U 1 4.9 U 6.5 U 15. l 12.4 U 60,500 20,500 4600 252 0.61 U 0.62 U ----- Sample Number Sample ID Sample Depth Matrix Sample Date SDG Volarile Organic Compound.,· U(!/k•I I, 1,2-Trichloroethane l, 1-Dichloroethene 1,2-Dichloroethane 1,2-Dichloropropane 2-Butanone 2-Hexanone 4-Meth yl-2-pentanone Acetone Benzene Chlorobenzene Chloroethane Chloroform cis-1,2-Dichlorocthene Cyclohexane Ethylbenzene lsopropy\bcnzene Me thy I acetate Methylcyclohexane Methylene chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Volatile Organic Comnound.\· fto•/ki,) 1,4-Dichlorobenzene I Inorganic Compounds (uglkg) Chloride Iron Tola! Organic Carbon Nitrate --------- CIKIJ0I 13002 CIK1301l3003 SB-l24A-01 SB-1248-01 4-4.5 5 -5.5 SOIL SOIL I 1/1212001 11/12/2001 CIK130113 CIK130l 13 5.3 U 5.3 U 5.3 U 5.3 U 1.2 J 1.6 J 5.3 U 5.3 u 2.7) 21 U 21 U 21 U 21 U 21 U 8.4 J 21 U 5.3 U 5.3 U 5.3 U 5.3 U II U II U 5.3 U 5.3 U 5.3 U 5.3 U 9.1 6.3 25 5.3 U 5.3 U 5.3 U 5.3 U 5.3 U 5.3 U 5.3 U 5.3 U 5.3 U 5.3 U 5.3 U 17 15 5.3 U 5.3 U 2.8 J 10 J 6.4 J 16 U 5.3 U 5.3 U 39.] 35.0 60,700 67,400 271 907 0.65 U 0.66 U Table 3 Area 2 Grid Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC Cl K!30113004 CI K 140204009 DUP-02-01 SB-146A-0I 5 -5.5 SOIL SOIL 11/12/2001 11/13/2001 CIKl30113 CIK140204 4.8 U 5.8 U 4.8 U 5.8 U 1.5 J 2.9 J 4.8 U 5.8 U 19 U 6.61 19 U 23 U 19 U 23 U 6 J 81 1.3 J 1.7 J 4.8 U 5.8 U 9.7 U . 12 U 4.8 U 5.8 U 1.3 J 6.1 18 7.5 2 J 22 4.8 U 5.8 U 4.8 U 5.8 U 4.8 U 1.6 J 4.8 U 5.8 U 4.8 U 5.8 U 27 140 4.8 U 5.8 U 24 18 2.1 J 33 I 4.8 U I 5.8 U 28.3 67.5 46,400 44,800 2120 1770 0.65 U 0.65 U U -analyte 1s not detected at the indicated concentrauon NA -analyte was not analyzed in the sample J -concentration indica1ed is an estimated concentration less than the reporting limit E -reported concentration exceeded the instrument calibration· range SB-DUP0l-01 is a duplicaie sample of SB-034A-01(7.5-8) Cl Kl30113001 SB-1468-01 2.5 - 3 SOlL 11/12/2001 CIK1301l3 6 U 5.3 J 31 2.4 J 24 U 24 U 24 U 41 24 6U 12 U 27 73 640 E 730 E 17 6 U 340 E 6U 3 J 2600 E 8.5 250 E 1700 E I 6U 57.5 120,000 11200 5.1 F:\PROJECTS\NSCC\OU4\remeva1res\soilresults.xls ------Page2of4 CIK130l 1300!R2 C!K080l37003 SB-146B-0I SB-l5SA-0I 2.5 - 3 II -11.5 SOIL· SOlL 11/12/2001 lln/2001 CIKl30113 CIK080l37 370 U 300 U 370 U 300 U 370 U 300 U 370 U 300 U 1,500 U 1,200 U 1,500 U 1,200 U 1,500 U 1,200 U 1,500 U 350 J 370 U 300 U 370 U 300 U 730 U 610 U 370 U 300 U 370 U 300 U . 370 U 300 U 1,600 180 J 370 U 140 J 370 U ·300 U 860 300U 350 J 370 370 U 300 U 12000 93 J 370 U 300 U 240 J 610 U 4100 300 J 370 U 300 U NA 13.8 U NA 44,900 NA 69.1 U NA 0.69 U ----- - -- - -- - -- Sample Number Sample ID Sample Depth Matrix Sample Date SDG Volatile Organic Compounds Uf!fkf!) I, 1,2-Trichloroethane l, 1-Dichloroethene 1.2-Dichloroethane 1,2-Dichloropropane 2-Butanone 2-Hexanone 4-Methyl-2-pentanone Acetone Benzene Chlorobenzene Chloroethane Chloroform cis-1,2-Dichloroethene Cyclohexane Ethyl benzene lsopropylbenzene Methyl acetate Methylcyclohexane Methylene chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Volatile Organic Comvounds (uf!!kf!J 1,4-Dichlorobenzene Inorganic Compounds (uglkg) Chloride lrnn Total Organic Carbon Nitrate CJK080!37004 CJK080!37005 SB-1588-01 SB-173A-01 13 -13.5 7.5 - 8 SOIL SOIL lln/2001 11n12001 CIK080l37 CIK080!37 220 U 4.6 U 220 U 4.6 U 220 U 4.6 U 220 U 4.6 U 870 U 18 U 870 U 18 U 870 U 18 U 490 J 25 220 U 4.6 U 220 U 4.6 U 430 U 9.2 U 220 U 4.6 U 220 U 4.6 U 220 U 4.6 U 220 U 4.6 U 95 J 4.6 U 220 U 4.6 U 520 4.6 U 290 4.6 U 220 U 4.6 U 83 J 1.2 J 220 U 4.6 U 430 U 9.2 U 650 U 14 U 220 U I 4.6 U l0.6 U 38.0 13,500 63,700 2590 5600 0.53 U 2.6 Table 3 Area 2 Grid Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC CJK080!37006 CI K070 I 87003 SB-1738-01 S8-J94A-01 5.5 - 6 0-0.5 SOIL SOIL 11n12001 I 1/6/2001 CIK080137 CIK070187 250 U 6.8 U 250 U 6.8 U 250 U 6.8 U 250 U 6.8 U 1,000 U 27 U 1,000 U 27 U 1,000 U 27 U 570 J 720 E 250 U 6.8 U 250 U 6.8 U 5IO U 14 U 250 U 6.8 U 250 U 6.8 U 250 U 6.8 U 250 U 6.8 U 250 U 6.8 U 250 U 6.8 U 250 U 6.8 U 350 6.8 U 250 U 6.8 U 67 J 6.8 U 250 U 6.8 U 510 U 14 U 760 U 20 U 250 U 6.8 U I 1.6 U 13.5 73,300 76,200 3950 22200 0.58 U 0.64 U U -analyte 1s not detected at the md1cated concentration NA -analyte was not analyzed in the sample J -concentration indicated is an estimated concentration less_ than the reporting limit E -reported concentration exceeded the instrument calibration range SB-DUP0l-01 is a duplicate sample of SB-034A-0I(?,5-8) F:\PROJECTS\NSCC\OU4\remevalres\soilresults.xls CJK070J87003R2 CI K070187004 SB-194A-01 SB-1948-01 0-0.5 0 -0.5 SOIL SOIL I 1/6/2001 11/6/2001 CIK070187 CIK070187 330 U 6.3 U 330 U 6.3 U 330 U 6.3 U 330U 6.3 U 1,300 U 25 U 1,300 U 25 U 1,300 U 25 U 540 J 16 J 330 U 6.3 U 330 U 6.3 U 660 U 13 U 330 U 6.3 U 330 U 6.3 U 330 U 6.3 U 330 U 6.3 U 330 U 6.3 U 330 U 6.3 U 330 U 6.3 U 420 6.3 U 330 U 6.3 U 84 J 2.1 J 330 U 6.3 U 660 U 13 U 990 U 19 U 330 U I 6.3 U NA 13.8 NA 84,200 NA 7330 NA 0.66 U - - -Page 3 of 4 CIK080137001 SB-J99A-01 I I - I J.5 SOIL I Jn/2001 CIK080137 260 U 260 U 240 J 260 U 1,000 U 1,000 U 1,000 U 480 J 260 U 260 U 520 U 260 U 260 U 260 U 260 U 260 U 260 U 260 U 530 260 U 130 J 260 U 520 U 780 U I 260 U 12.2 U 41,800 61.1 U 0.61 U -- - Sample Number Sample ID Sample Depth Matrix Sample Date SDG Volatile Organic: Compounds 111•/kv) I, 1,2-Trichloroethane I. l-Dichlorocthene 1,2-Dichloioethane 1,2-Dichloropropane 2-Butanone 2-Hexanone 4-Meth yl-2-pentanone Acetone Benzene Chlorobenzene Ch\oroethane Chloroform cis-l ,2-Dichloroethene Cyclohexane Ethylbenzene lsopropylbenzene Methyl acetate Methylcyclohexane Methylene chloride Tetrachlorocthene Toluene Trichloroethene Vinyl chloride Xylenes (total) Semi-Volatile Organic Compound.\· (uf!lk~ l 1,4-Dichlorobenzene I Inorganic Compound.\· (uglkg) Chloride Iron Total Organic Carbon Nitrate F:\PAOJECTS\NSCC\OU4\remevalres\soilresults.xls ----------- CIK080137002 SB-1998-01 13.5 -14 SOIL I ln/2001 CIK080137 4.8 U 4.8 U 4.8 U 4.8 U 19 U 19 U 19 U 19 U 4.8 U 4.8 U 9.5 U 4.8 U 4.8 U 4.8 U 4.8 U 4.8 U 4.8 U 4.8 U 4.8 U 4.8 U 4.8 U 4.8 U 9.5 U 14 U 4.8 U 11.0 U 13,700 54.9 U 0.55 U Table 3 Area 2 Grid Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC C!K070187006 CI K070187006R2 SB-229A-01 SB-229A-01 13.5 -14 _ 13.5-14 SOIL SOIL 11/6/2001 11/6/2001 CIK070187 CIK070187 6 U 290 U 6U 290 U 220 290 U 6 U 290 U 5 J 1,200 U 24 U 1,200 U 24 U 1,200 U 240 E 1,200 U 6U 290 U 6U 290 U 12 U 580 U 6U 290 U 6U 290 U 6U 290 U 6U 290 U 6U 290 U 6U 290 U 6U 290 U 6 U 330 U 6U 290 U 6U 290 U 6U 290 U 12 U 580 U 18 U 880 U I 6U I 290 U 13.4 U NA 68,100 NA 9980 NA 0.67 U NA U -analyte 1s not detected at the indicated concentration NA -analyte was not analyzed in the sample Cl K070187007 SB-2298-01 II -11.5 SOIL 11/6/2001 CIK070187 7.1 U 7.1 U 1.200E 7.1 U 28 U 28 U 28 U 28 U 7.1 U 5.2 J 4.2 J 7.1 U 7.1 U 7.1 U 7.1 U 7.1 U 7.1 U 7.1 U 7.1 U 1.7 J 1.6 J 7.1 U 4.1 J 21 U I 13 45.7 97,200 73.2 U 1.6 J -concentration in~icated is an estimated concentration less than the reporting limit E -reported concentration exceeded the instrument calibriuion range SB-DUP0l-01 is a duplicate sa,;nple of SB-034A-0l(7.5-8) C!K070187007R2 SB-2298-01 11-11.5 SOIL 11/6/2001 CIK070187 350 U 350 U 1,200 350 U 1,400 U 1,400 U 1,400 U 1,400 U 350 U 350 U 700 U 350 U 350 U 350 U 350 U 350 U 350 U 350 U . 590 350 U 91 J 350 U 700 U 1100 U 350 U NA NA NA NA ----Page 4 of 4 -·-- - - Sample Number Sample ID Sample Depth Matrix Sample Date SDG Volatile Organic Compounds (1w/kvl I, 1,2-Trichlorocthane I, 1-Dichloroethane 1,2-Dichloroethane 1,2-Dichloropropane 2-Butanone 2-Hexanone 4-Methyl~ 2-pentanone Acetone Benzene Chlorobenzene Chlorocthanc Chloroform cis-1,2-Dichloroethene Cyclohcxane Ethyl benzene lsopropylbenzene Methyl acetate Methylcyclohexane Methylc_ne chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Volarile Organic Comnounds (1ir1/ke) 1,4-Dichlorobenzene I Inorganic Compo1111ds (uglkg) Chloride Iron Total Organic Carbon Nitrate - - - --- - Table 4 Previously Sampled Area 2 Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC - - - CI Kl00104001 CIK100104001R2 CIK100104002 CIK140189001 CIK140189002R2 SBA2-06-0l SBA2-06-0l SBA2-06-0l SBA2-08-0l 5 -5.5 5 -5.5 7.5 - 8 4 -4.5 SOIL SOIL SOIL SOIL 11/9/2001 11/9/2001 11/9/2001 11/13/2001 CIKI00104 CIKI00I04 CIK100104 CIK140189 5U 260 U 300U 4.7 U. 5U 260 U 300 U 4.7 U 6,500 E 6,300 11,000 56 5U 260 U 300 U 4.7 U 20 U 1,000 U 1,200 U 1.9 J 20 U 1,000 U 1,200 U 19 U 20 U 1,000 U 1,200 U 19 U 5.5 J 1,000 U 1,200 U 11 J 5 U 260 U 300 U I.I J 5U 260 U 300 U 4.7 U 43 520 U 610 U 6.8 J 5U 260 U 300 U 4.7 U 5U 260 U 300 U 4.7 U 5 U 260 U 300 U 6.7 5 U 260 U 300 U I J 5 U 260 U 300 U 4.7 U 5U 260 U 300 U 4.7 U 5U 260 U 300 U 4.7 U 5U 330 370 4.7 U 5U 260 U 300 U 4.7 U 3.9 J 66 J 300 U 14 . L3 J 260 U 300 U 4.7 U 93 130 J 190 J 5.4 J 15 U 780 U 910 U 2.2 J 5 U I 260 U 300 U 4.7 U 87.5 162 16.3 18,800 50,700 41,100 65.1 U 65.4 U 1120 0.65 U 0.65 U 0.63 U U -analyte 1s not detected at the indicated concentration J -compound was detected at an estimated concentration below the reporting limit ~ -reported concentration exceeded the insti:ument calibration range SBA2-08-0l 17.5 -18 SOIL 11/13/2001 CIK140189 4.5 4.2 U 2,900 E 4.2 U 17U 17 U 17 U 36 4.2 4.2 U 39 4.2 U I J 4.2 U 4.2 U 4.2 U 4.2 U 4.2 U 4.2 U 4.2 U 4.2 U 1.5 J 6.2 J 12 U I 4.2 U I 58.2 10,300 56.3 U 0.56 U F:IPROJECTSINSCCIOU4\remevalres\soilresults.xls ----Page 1 of 2 CIK140189002 SBA2-08-0l 17.5 -18 SOIL 11/13/2001 CIKl40189 230 U 230 U 2,100 230 U 930 U 930 U 930 U 930 U 230 U 230 U 470.U 230 U 230 U 230 U 230 U 230 U 230 U 230 U 230 U 230 U 230 U 230 U 470 U 700 U 230 U --1111!1 - - - Sample Number Sample ID Sample Depth Matrix Sample Date SDG Volarile Organic Compounds {ll~/ke) I, 1,2-Trichloroethane I, 1-Dichlorocthane 1,2-Dichloroethane 1,2-Dichloropropane 2-Butanone 2-Hexanone 4-Methyl-2-pentanonc Acetone Benzene Chiorobenzene Chloroethane Chloroform cis-1,2-Dichloroel.hene Cyclohexane Ethylbenzene Isopropylbenzene Methyl acetate Methylcyclohexane Methylene chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Vola1ile Organic Comnounds f1w/kr,) l ,4-Dichlorobenzene Inorganic Compo1111ds (11glkg) Chloride Iron Total Organic ~arbon Nitrate F:\PROJECTS\NSCC\OU4\remevalres\soilresults.xls --- - -- Table 4 Previously Sampled Area 2 Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC - - - - CIK140!89004 C!K140189016 CIK070187005 CIK14020400! CIK140204001R2 SBA2-09-0I SBA2-09-01 SBA2-16-0I SBA2-20-01 1.5 -2 13.5 -14 3.5 -4 5 -5.5 SOIL SOIL SOIL SOIL 11/13/2001 11/13/2001. 11/6/2001 11/13/2001 C!Kl40189 CIK140189 CIK070187 CIKl40204 1,400 U 200 U 6.8 U 6.7 U 1,400 U 200 U 6.8 U 6.7 U 35,000 500 6.8 U 3.6 J 1,400 U 200 U 6.8 U 6.7 U 5,500 U 790 U 27U 8.9 J 5,500 U 790 U 27 U 27 U 5,500 U 790 U 27 U 27 U 5,500 U 790 U 68 63 1,400 U 200 U 6.8 U 6.4 J 1,400 U 200 U 6.8 U 6.7 U 2,700 U 390 U 14 U 13 U 1,400 U 200 U 6.8 U 6.7 U 1,400 U 200 U 6.8 U 6.7 U 1,400 U 200 U 6.8 U 110 1,400 U 200 U 6.8 U 72 1,400 U 200 U 6.8 U 1.6 J 1,400 U 200 U 6.8 U 6.7 U 1,400 U 200 U 6.8 U 31 1,400 U 200 U· 6.8 U 6.7 U 1,400 U 200 U 6.8 U 6.7 U 1,400 U 200 U 6.8 U 1300 E 1,400 U 200 U 6.8 U 6.7 U 3,600 390 U 14 U 13 U 4,100 U 590 U 21 U 270 1.400 U 200 U 6.8 U 6.7 U 14.1 U 47.9 81,600 87,000 2400 0.74 U U -analyte 1s not detected at the indicated concentration J -compound was detected at an estimated concentration below the reporting limit E -reported concentration excee~ed the instrument calibration range SBA2-20-01 5 -5.5 SOIL 11/13/2001 C!Kl40204 350 U 350 U 350 U 350 U 1,400 U 1,400 U 1,400 U 360 J 350 U 350 U 700 U 350 U 350 U 350 U 350 U 350 U 350 U 350 U 350 U 350 U 610 350 U 700 U 1,000 U I 350 U ---Page 2 of 2 --- Sample Number Sample lD Sample Depth Matrix Sample Date SDG PIO ReadinR Volatile Organic Compoundx 111•/kvJ I, 1,2-Trichloroethane I, 1-Oichloroethene 1,2-Dichloroethane 1.2-Dichloropropane 2-Butanone 2-Hexanone 4-Methyl-2-pentanone Acetone Benzene Chlorobenzene Chloroethane Chloroform cis-1,2-Dichloroethene Cyclohexane Ethylbenzene Isopropylbenzcne Methyl acetate Methylcyclohexane · Methylene chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Volatile Organic Comno~mds (uf!/kr.,) 1.4-Dichlorobenzene ----------- CIKl40!89003 CIKl40!89004 SBA2-09·01 SBA2-09-0I 0.5 · I 1.5 · 2 SOIL SOIL 11/13/200! 11/13/2001 C!Kl40189 C!K140!89 20@!.5ft 6,600U l.400U 6,600U 1.400 U 120,000 35,000 6,600 U 1,400 U 26,000 U 5,500 U 26,000 U 5,500 U 26.000 U 5,500 U 26,000 U 5,500 U 6,600 U 1,400 U 6,600 U 1,400 U 13,000 U 2,700 U 6,600 U 1,400 U 6.600 U 1,400 U 6,600U 1,400 U 6,600U 1,400 U 6.600 U 1,400 U 6,600U 1,400 U 6,600 U · 1,400 U 6,600 U 1,400 U 6.600U 1,400 U 6,600U 1,400 U 6.600 U 1,400 U 3,800 J 3,600 20.000 U 4,100 U 6,600U I 1,400 U Table 5 SBA2-09 and SBA2·20 Continuous Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC C!K!40189005 C!Kl40!89005R2 C!Kl40!89006 SBA2-09-0I SBA2-09-0! SBA2·09-0I 2.5 -3 2.5 · 3 3.5. 4 SOIL SOIL SOIL I 1/13/2001 11/13/2001 11/13/2001 C!Kl40!89 CIK!40!89 CIK140189 13.5@ 3.5 ft 5.4 U 300 U 4.6 U 2.3 J 300 U 1.9 J 450 E 300 U 83 5.4 U 300 U 4.6 U 20 J 1200 U 6.8 J 22 U 1200 U 18 U 9.5 J 1200 U 11 J 220 E 310 J 31 28 300 U 48 5.4 U 300 U 4.6 U II U 610 U 9.2 U 5.4 U 300 lJ 4.6 U 14 300 U 10 5.4 U 300 U 3.3 J 5.4 U 300 U 1.6 J 5.4 U 300 U 1.2 J 5.4 U 300 U 4.6 U 5.4 U 300 U 3.3 I 5.4 U 90 J 4.6 U I.I J 300 U 4.6 U 330 E 320 260 E 4.2 J 300 U 3.5 J 500 E 610 U 430 E 6.2 J 910 U 11 J 5.4 U I 300 U I 4.6 U Each 2 foot sphl spoon mterval was screened with the PID, the recorded readmg 1s the highest for the spht spoon U -analyte is not detected at the indicated concentration J -compound was detected at an estimated concentration below the reporting limit E -reported concentration exceeded the instrument calibration range CIKl40189006R2 SBA2-09-0! 3.5 · 4 SOIL 11/13/2001 CIKl40!89 220 U 220 U 220 lJ 220 U 880 U 880 U 880 U 880 U 220 U 220 U 440 U 220 U. 220 U 220 U 220 U 220 U 220 U 220 U 220 U 220 U 200 J 220 U 180 J 660 U 220 U F:\PROJECTS\NSCC\OU4\remevalres\soilresults.xls --·--Page 1 of 5 CIKl40189007 CIK!40!89007R2 SBA2-09-0! SBA2·09-0I 4.5 · 5 4.5 · 5 SOIL SOIL 11/13/200! I 1/13/2001 CIK!40189 C!K140!89 0 0 6.1 U 310 U 6:1 U 310 lJ 1,600 E 510 6.1 U 310 U 4.1 J !,300U 24 U 1,300 U 24 U 1,300 U 64 320 J 82 310 U 6.1 U 310 U 12 U 630 U 6.1 U 310 U 5.5 J 310 U 6.1 U 310 U 6.1 U 310 U 6.1 U 310 U 6.1 U 310 U 6.1 U 310 U 6.1 U 310 U 6.1 U 310 U 14 310 U 6.1 U 310 U 39 630 U 2.71 940 U I 6.1 U 310 U ---- - - - - - --- - ---- Sample Number Sample ID Sample Depth Matrix Sample Date SDG /'JD Readi11f! Volarile Organic Compound.~ (1wlh•) I ,l ,2-Trichloroethane I, 1-Dichloroethene 1,2-Dichloroethane 1,2-Dichloropropane 2-Butanone 2-HeXanone 4-Methy 1-2-pentanone Acetone Benzene Chlorobenzene Chloroethane Chloroform cis-1,2-Dichloroethene Cyclohexane E1hy !benzene lsopropylbenzcne Methyl acetate Mcthylcyclohexane Methylene chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Volatile Organic Comvounds (11f!lkJ!) 1,4-Dichlorobenzene CIKl40189008 Cl Kl40189009 SBA2-09-0l SBA2-09-0l 5.5 - 6 6.5 -7 SOIL SOIL 11/ I 3/200 I I 1/13/2001 C!Ki40189 CIKI40189 0 6.3 U 300 U 6.3 U 300 U 71 2,100 6.3 U 300 U 11 J 1.200 U 25 U 1.200 U 32 1,200 U 89 1.200 U 76 300 U 6.3 U 300 U 13 U 600 U 6.3 U 300 U 3.1 J 300 U 6.3 U 300 U 6.3 U 300 U 6.3 U 300 U 12 300 U 6.3 U 300 U 6.3 U .100 U 6.3 U JOO U 18 150 J 6.3 U 300 U 28 600 U 4) 900 U 6.3 U 300 U Table 5 SBA2-09 and SBA2-20 Continuous Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC CIKl40!89010R2 CIKl40189010 CIKl40!89011R2 SBA2-09-01 SBA2-09-0l SBA2-09-0l 7.5 - 8 7.5 - 8 8.5 - 9 SOIL SOIL SOIL I 1/13/2001 I 1/13/2001 11/13/2001 CIKI40189 CIK!40189 CIK140189 1.2 @ 7.5 ft 3.2@ 9 ft 270 U 5.6 U 4.3 U 270 U 5.6 U 4.3 U 420 870 E 480 E 270 U 5.6 U 4.3 U 1.100 U 52 17 1,100 U 22 U 17 U 1,100 U 100 20 590 J 650 E 200 270 U 48 24 270 U 5.6 U 4.3 U 530 U 3.8 J 8.6 U 270 U 5.6 U 4.3 U 270 U 5.6 U 4.3 U 270 U 5.6 U 4.3 U 270 U 5.6 U 4.3 U 270 U 5.6 U 4.3 U 270 U 9.7 17 270 U 5.6 U 4.3 U 270 U 5.6 U 4.3 U 270 U 5.6 U 4.3 U 270 U 27 1.7 J 270 U 5.6 U 4.3 U 530 U 10 J 1.6 J 800 lJ 2.7 J 13 U I 270 U I 5.6 U I 4.3 U I Each 2 foot split spoon interval was screened w11h the PID, the recorded readmg 1s the highest for lhe spht spoon U -analyte is not detected at the indicated concentration J -compound was detected at an estimated concentration below the reporting limit E -reported concentration exceeded the instrument calibration range F:\PROJECTS\NSCC\OU4\remevalres\soilresults.x!s CIKl4018901 l CIKl40!89012 SBA2-09-0l SBA2-09-01 8.5 - 9 9.5 -10 SOIL SOIL 11/13/200 I 11/13/2001. C!Ki40189 CIKI40189. 210 U 4.9 U 210 U 4.9 U 290 180 210 U 4.9 U 820 U 8.3 J 820 U 19 U 820 U 9.2 J 380 J 100 210 U 7.2 210 U 4.9 U 410 U 9.7 U 210 U 4.9 U 210 U 4.9 U 210 U 4.9 U 210 U 4.9 U 210 U 4.9 U 210 U 16 210 U 4.9 U 210 U 4.9 U 210 U 4.9 U 210 U 4.9 U 210 U 4.9 U 410 U 9.7 U 620 U 15 U 210 U I 4.9 U - - -Page 2 of 5 CIKl40!890!3R2 SBA2-09-0l 10.5 -11 SOIL 11/13/2001 CIK140!89 2.4@ I I ft 200 U 200 U 240 200 U 810 U 810 U 810 U 210 J 200 U 200 U 410 U 200 U 200 U 200 U 200 U 200 U 200 U 200 U 200 U 200 U 200 U 200 U 410 U 610 U 200 U - -- Sample Number Sample ID Sample Depth Matrix Sample Date SDG PID Readi11v \lolatile Organic Compounds (111'/k•1l I, 1,2-Trichloroethane I, 1-Dichloroethene 1,2-Dichloroethane 1,2-Dichloropropane 2-Butanone 2-Hexanone 4-Methyl-2-pentanone Acetone Benzene Chlorobenzene Chloroethane Chlorofonn · cis-1,2-Dichloroethene Cyclohexane Ethyl benzene Isopropylbenzene Methyl acetate Methylcyclohexane Methylene chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Volatile Organic Comnounds (u"o/ko) 1,4-Dichlorobenzene --- --- - --- CIKl40189013 CIKl40189014 SBA2-09-0I SBA2-09-0I 10.5-11 11.5-12 SOIL SOIL 11/13/2001 11/13/2001 CIKl40189 CIKI40189 3.9.U 4.4 U 3.9 U 4.4 U 490 E 140 3.9 u 4.4 U 16 U 17 U 16 U 17 U 3.6 J 17 U 12 J 4.6 J 3.5 J 4.4 U 3.9 U 4.4 U 7.8 U 8.7 U 3.9 U 4.4 U 3.9 U 4.4 U 3.9 U 4.4 U 3.9 U 4.4 U 3.9 U 4.4 U 3.9 U 4.4 U 3.9 U 4.4 U 3.9 U 4.4 U 3.9 U 4.4 U 0.86 J 4.4 U 3.9 U 4.4 U 7.8 U 8.7 U 12 U 13 U . 3.9 U I 4.4 U Table 5 SBA2·09 and SBA2-20 Continuous Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC CIKl40189015 CIKl40189016 CIKl40189019 SBA2-09-0l SBA2-09-0l SBA2-20-01 13. 13.5 13.5 · 14 2.5 - 3 SOIL SOIL SOIL I l/13/200 I 11/1312001 11/1312001 CIKI40189 CIKl40189 CIKI40189 3.0@ 13 fl 210 U 200 U 7 U 210 U 200 U 7U 670 500 7 U 210 U 200 U 7 U 830 U 790 U 3.8 J 830 U 790 U 1.9 J 830 U 790 U 28 U 210 J 790 U 67 210 U 200 U 3.5 J 210 U 200 U 7 U 420 U 390 U 7.6 J 210 U 200 U 7U 210 U 200 U 7U 210 U 200 U 18 210 U 200 U 40 210 U 200 U 7U 210 U 200 U 43 210 U 200 U 6.5 J 210 U 200 U 7 U 210 U ' 200 U 7 U 210 U 200 U 490 E 210 U 200 U 7 U 420 U 390 U 14 U 620 U 590 U 110 I 2IO U 200 U 7 U Each 2 foot spin spoon interval was screened with the PIO, the recorded reading ts the highest for the spht spoon U -analyte is not detected at the indicated concentration J -compound was detected at an estimated concentration below the reporting limit E -reported concentration exceeded the instrument calibration range CIKl40189019R2 SBA2-20-01 2.5 - 3 SOIL 11/13/2001 CIKI40189 360 U 360 U 810 360 U 1,400 U 1,400 U 1,400 U 470 J 360 U 360 U 720 U 360 U 360 U 360 U 360 U 360 U 360 U 360 U l00 J 360 U 590 360 U 2,100 1,100 U 360 U F:\PROJECTS\NSCC\OU4\remeva1res\soi1results.xls - - - - Page 3 of 5 CIKl40189020 CIKl40204001 SBA2-20-0l SBA2-20-0l 3.5 · 4 5-5.5 SOIL SOIL 11/131200 I 11/13/2001 CIKl40189 CIKl40204 4.9@ 3.5 ft 27.5@5ft 6U 6.7 U 6U 6.7 U 7.4 3.6 J 6U 6.7 U · 4.9 J 8.9 J 24 U 27 U 24 U 27 U 36 63 2.5 J 6.4 J 6U 6.7 U 12 U 13 U 6U 6.7 U 6U 6.7 U 14 110 34 72 6U 1.6 J 47 6.7 U 5.7 J 31 6U 6.7 U 6U 6.7 U 2IO 1300 E 6U 6.7 U 12 U 13 U 120 270 I 6U I 6.7 U -- - Sample Number Sample ID Sample Depth Matrix Sample Date SDG PIO Readi11v Volalile Organic Compound.f u ,fk,.1 I, 1,2-Trichloroethane I, 1-Dichloroethene 1,2-Dichloroethane 1,2-Dichloropropane 2-Butanone 2-Hexanone 4-Methyl-2-pemanone Acetone Benzene Chlorobenzene Chloroethane Chloroform cis'-1,2-Dichloroethene Cyclohexane Ethylbenzene lsopropylbenzene Methyl acetate Methylcyclohexane Methylene chloride Tetrachloroethene Toluene Trichlorocthene Vinyl chloride Xvlenes (IOtal) Semi-Volatile Organic Comnound.1· (ur>/k"> 1,4-Dichlorobenzene ---- -- ----- CI K 14020400 I R2 CI K 140204002 SBA2-20-0I SBA2-20-0I 5 -5.5 5.5 -6 SOIL SOIL 11/13/2001 I 1/13/2001 C1K140204 C1K140204 350 U 5.2 U 350 U 5.2 U 350 U 2.3 J 350 U 5.2 U 1,400 U 6.2 J 1,400 U 21 U 1,400 U 21 U 360 J 36 350 U 2.8 J 350 U 5.2 U 700 U 10 U 350 U ,5.2 U 350 U 5.2 U 350 U 22 350 U 17 350 U 5.2 U 350 U 14 350 U 6.6 350 U 5.2 U 350 U 5.2 U 610 520 E 350 U 5.2 U 700 U 10 U 1,000 U 62 350 U I 5.2 U Table 5 SBA2-09 and SBA2-20 Continuous Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC . CIKl40204002R2 C!K140204010 CIK140204010R2 SBA2-20-0I DUP-03-01 DUP-03-01 5.5 -6 SOIL SOIL SOIL 11/13/2001 11/13/2001 11/13/2001 CIKl40204 CIK140204 CIKl40204 270 U 5.2 U 260 U 270 U 5.2 U 260 U 270 U 4.3 J 260 U 270 U 5.2 U 260 U 1.100 U 5.5 J 1,000 U 1.100 U 21 U 1,000 U 1,100 U 21 U 1,000 U 280 J 28 1.000-U 270 U 1.7 J 260 U 270 U 5.2 U 260 U 540 U 10 U 510 U 270 U 5.2 U 260 U 270 U 5.2 U 260 U 270 U 15 260 U 270 U 14 260 U 270 U 5.2 U 260 U 270 U 16 260 U 270 U 4 J 260 U 270 U 5.2 U 260 U 270 U 5.2 U 260 U 220 J 360 E 180 J 270 U 5.2 U 260 U 540 U 10 U 510 U 820 U 55 770 U 1 270 U 5.2 U 260 U . Each 2 foot spht spoon mterval was screened with the PID, the recorded reading 1s the highest for the spht spoon U -analyte is no{ detected at the indicated concentration J -compound was detected at an estimated concentration below the reporting limit E -reported concentration exceeded the instrument calibration range CI K 140204003 SBA2-20-01 6.5 -7 SOIL 11/13/2001 ClK140204 25@7ft 200 U 200 U 470 200 U 790 U 790 U 790 U 790 U 200 U 200 U 390 U 200 U 200 U 200 U 78 J 200 U 200 U 200 U 200 U 200 U 3100 200 U 390 U 140 J 200 U F:\PROJECTS\NSCC\OU4\remevalres\soilresults.xls - -- - Page 4 of s CI K 140204004 CI K 140204005 SBA2-20-0I SBA2-20-0I 7.5 -8 8.5 -9 SOIL SOIL 11/13/2001 11/13/2001 ClKl40204 CIK140204 24.7 @ 9 ft 1,900 U 14,000 U 1,900 U 14,000 U 70,000 470,000 1,900 U 14,000 U 7.500 U 57.000 U 7,500 U 57,000 U 7,500 U 57.000 U 7,500 U 57.000 U 1,900 U 14,000 U 1,900 U 14,000 U 3,700 U 29.000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,900 U 14,000 U 1,600 J 14,000 U 1,900 U 14,000 U 3,700 U 29,000 U 5,600 U 43.000 U 1,900 U I 14,000 U ----- Sample Number Sample ID Sample Depth Matrix Sample Date SDG PJD Readinf! Volatile Orga11ic Compound.1· (111!/kr>J I, l ,2~Trichloroethane 1, 1-Dichloroethene 1,2-Dichloroethane 1.2-Dichloropropane 2-Butanone 2-Hexanone 4-Meth y 1-2-pentanone Acetone Benzene Chlorobenzene Chloroethane Chloroform cis-1,2-Dichloroethene Cyclohexane Ethylbenzcne Isopropylbenzene Methyl acetate Methylcyclohexane Methylene chloride Tetrachloroethene Toluene Trichloroethene Vinyl chloride Xvlenes (total) Semi-Voltllile Organic Conmound.1· (u,,/k0 ) 1,4-Dichlorobenzene - - Cl K140204006 SBA2-20-0I 9.5 -10 SOIL 11/13/2001 CIKl40204 6,300 U 6,300 U 140,000 6,300 U 25,000 U 25,000 U 25,000 U 25,000 U 6,300 U 6,300 U 13,000 U 6,300 U 6,300 U 6,300 U 6,300 U 6,300 U 6,300 U 6,300 U 6,300 U 6,300 U 6,300 U 6,300 U 13,000 U 19,000 U 6,300 U - -.. ---- Table 5 SBA2-09 and SBA2-20 Continuous Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC CI K 140204007 CI K 140204008 SBAZ-20-01 SBA2-20-0I 10.5 -11 I 1.5 -12 SOIL SOIL 11/13/2001 11/13/2001 CIKl40204 CIKl40204 6.8@ 11 ft 4,300 U 1,600 U 4.300 U 1,600 U 82,000 44,000 4,300 U 1,600 U 17,000 U 6,400V 17,000 U 6,400V 17,000 U 6,400V 17.000 U 6,400 U 4,300 U 1,600 U 4,300 U 1,600 U 8,700 U 3,200 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1,600 U 4,300 U 1.600 U 4,300 U 1,600 U 8,700 U 3,200 U 13.000 U 4,800 U I 4,300 U 1,600 U - Each 2 foot split spoon interval was screened with the PID, the recorded reading is the highest for the split spoon U -analyte is not detected at the indicated concentration J -compound was detected at an estimated concentration below the reporting limit E -reported concentration exceeded the instrument calibration range F:\PAOJECTS\NSCC\OU4\remevatres\sollresults.xls - - - - Page 5 of 5 -I I I I I I I I I I I I I I I I I I Table 6 Previously Sampled Lagoon Area Soil Boring Analytical Results National Starch and Chemical Company Cedar Springs Plant Site, Salisbury, NC . Sample Number C 1 K090 l 38006R2 C 1K090138006 C 1K090138005 Sample ID SBLA-13-01 SBLA-13-01 SBLA-14-01 Sample Depth 11-11.5 11 - I 1.5 3 -3.5 Matrix SOIL SOIL SOIL Sample Date 11/8/2001 11/8/2001 11/8/2001 SDG CIK090138 ClK090!38 ClK090138 Volatile Onwnic Comvounds (uPlke) 1, 1,2-Trichloroethane 280 U 5.5 U 7.6 U I, 1-Dichloroethane 280 U 5.5 U 7.6 U 1,2-Dichlorocthane 1500 2600 E 7.6 U 1,2-Dichloropropane 280 U 5.5 U 7.6 U 2-Butanone 1100 U 22 U 30 U 2-Hexanone 1100 U 22 U 30 U 4-Methyl-2-pentanone llO0U 22 U 30 U Acetone 360 J 22 U 14 J Benzene 280 U 5.5 U 7.6 U Chlorobenzene 280 U 5.5 U 7.6 U Chloroethane 570 U 11 U 85 Chloroform 280 U 5.5 U 7.6 U cis-1,2-Dichloroethene 280 U 5.5 U 7.6 U Cyclohcxane 280 U 5.5 U 1.9 J Ethylbenzene 280 U 5.5 U 7.6 U lsopropy I benzene 280 U 5.5 U 7.6 U Methyl acetate 280 U 5.5 U 7.6 U Methylcyclohexane 280 U 5.5 U 7.6 U Methylene chloride 510 5.5 U 7.6 U Tetrachloi-oethene 280 U 5.5 u· 7.6 U Toluene 280 U 1.4 J 11 Trichloroethene 280 U 5.5 U 7.6 U Vinyl chloride 570 U II U 120 Xylenes (total) 850 U 16 U 23 U Semi-Volatile Onumic Comnowuls (uRlkP) 1,4-Dichlorobenzene 280 U I 5.5 U I 7.6 U hwnwnic Comoow,ds (ue/ke) Iron NA 8,930 14,100 Total Organic Carbon NA 65.3 U 70.2 U Nitrate NA 0.65 U 0.7 U U -analyte 1s not detected at the indicated concentrat,on J -compound was detected at an estimated concentration below the reporting limit E -reported concentration exceeded the instrument calibration range _NA -analyte was not analyzed in the sample J F:\PROJECTS\NSCC\OU4\remevalres\soilresults.xls Page 1 of 1 --- - - Sample ID Laboratory ID Matrix Sample Depth Samele Date GCIMS Volatiles nnb Iv/vi Chloromethane Vinyl Chloride Bromomethane Chloroethane 1, 1-Dichloroethane 1, 1, 1-T richloroethane Benzene 1,2-Dichloroethane Trichloroethane 1 ,2-Dichloropropane 4-Methyl-2-pentanone (MIBK) Toluene T etrachloroethene 2-Hexanone 4-Ethyltoluene 1,4-Dichlorobenzene Hexachlorobutadiene Fixed Gases %fvlvJ Carbon Dioxide Oxygen Nitrogen Ethane Ethene Methane Carbon monoxide --- - - --- SGMW1 (2-4) M1260149-007 AIR 2-4 11/20/2001 2400 U 200000 1200 U 2400 U 1200 U 1200 U 1200 U 1200 U 1200 U 1200 U 6200 3600 1200 U 18000 U 29000 1200 U 2400 U 2.5 5.2 72 DIL 0.1100 2.0 7.8 0.0061 U Table 7 SGMW Analytical Results National Starch and Chemical Company Cedar Springs Site, Salisbury, NC SGMW1 (6-8) SGMW2(2-4) M1K260149-008 M 1 K260149-009 AIR AIR 6-8 2-4 11/20/2001 11/20/2001 14000 U 350000 U 170000 1900000 6900 U 180000 U 14000 U 350000 U 6900 U 180000 U 6900 U 180000 U 12000 180000 U 740000 15000000 6900 U 180000 U 6900 U 180000 U 34000 U 880000 U 6900 U 1200000 6900 U 180000 U 100000 U 2700000 U 34000 U 180000 U 6900 U 180000 U 14000 U 350000 U 3.7 5.3 0.34 U · 0.35 U . 1.7 U 7.4 2.0 1.2 1.0 26 89 53 0.0017 0.0018 U SGMW2 (6-8) M1K260149-010 AIR 6-8 11/20/2001 170000 U 510000 .. 84000 U 170000 U 84000 U 84000 U 84000 U 19000000 84000 U 84000 U 420000 U 580000 84000 U 1300000 U 84000 U 84000 U 170000 U 3.5 0.42 U 10 1.7 5.2 73 0.0021 U -- SGMW3 (2-4) M1K260149-011 AIR 2-4 11/20/2001 55000 U 1500000 28000 U 55000 U 28000 U 28000 U 28000 U 5900000 28000 U 28000 U 140000 U 1300000 28000 U 410000 U 28000 U 28000 U 55000 U 9.4 0.75 19 0.19 53 11 0.0028 U OIL -the concentration is estimated due to dilution or the presence of interfering analytes. U -analyte is not detected at the indicated concentration ----Page 1 of 3 SGMW3 (6-8) M1K260149-012 AIR 6-8 11/20/2001 1600000 U 2800000 780000 U 1600000 U 780000 U 780000 U 780000 U 100000000 780000 U 780000 U 3900000 U 13000000 780000 U 12000000 U 780000 U 780000 U 1600000 U 9.7 0.39 U 9.8 1.2 13 56 0.0020 U --- - - - Sample ID Laboratory 10 Matrix Sample Depth Samole Date GC/MS Volatiles "' b tvfv) Chloromethane Vinyl Chloride Bromomethane Chloroethane 1, 1-Dichloroethane 1, 1, 1 -Trichloroethane Benzene 1 ,2-Dichloroethane Trichloroethane 1,2-Dichloropropane 4-Methyl-2-pentanone (MIBK) Toluene Tetrachloroethene 2-Hexanone 4-Ethyltoluene 1,4-Dichlorobenzene Hexachlorobutadiene Fixed Gases %/v/vJ Carbon Dioxide Oxygen Nitrogen Ethane Ethane Methane Carbon monoxide -- - - --- SGMW4 (2-4) M 1 K260149-005 AIR 2-4 11/19/2001 4.0 U 2.0 U 2.0 U 4.0 U 2.0 U 2.0 U . 2.0 U 2.0 U 2.0 U 2.0 U 10 U 2.0 U 2.0 U 30 U 2.0 U 2.0 U 4.0 U 1 .2 22 76 0.00099 U 0.00099 U 0.00072 0.0020 U Table 7 SGMW Analytical Results National Starch and Chemical Company Cedar Springs Site, Salisbury, NC SGMW4 (6-8) SGMW5 (2-4) M1 K260149-006 M1K260149-003 AIR AIR 6-8 2-4 11/19/2001 11/19/2001 4.0 U 4.0 U 2.0 U 2.0 U 2.0 U 2.0 U 4.0 U 4.0 U 2.0 U 2.0 U 2.0 U 2.0 U 2.0 U 2.0 U 2.0 U 3.9 2.0 U 2.0 U 2.0 U 2.0 U 10 U · 10 U 2.0 U 2.0 U 2.0 U 2.0 U 30 U 30 U 2.0 U 2.0 U 2.0 U 2.0 U 4.0 U 4.0 U 3.7 0.010 U 18 0.20 U 77 1.0 U 0.00087 U 0.00050 U 0.00087 U 0.00050 U 0.00035 U 0.00020 U 0.0017 U 0.0010 U SGMW5 (6-8) M 1 K260149-004 AIR 6-8 11/19/2001 8800 U 1000000 4400 34000 4400 U 4400 U 4400 U 340000 4400 U 4400 U 22000 U 4400 U 4400 U 66000 U 4400 U 4400 U 8800 U 9.2 1.9 78 0.043 5.4 3.9 0.0033 U -- SGMW6 (2-4) M1K260149-001 AIR 2-4 11/19/2001 1700 U 200000 840 U 11000 840 U 840 U 840 U 200000 840 U 840 U 4200 U 840 U 840 U 13000 U 840 U 840 U 1700 U 2.6 18 76 0.0010 2.8 0.33 0.0017 U OIL -the concentration is estimated due to dilution or the presence of interfering analytes. U -analyte is not detected at the indicated concentration ---- Page 2 of 3 SGMW6 (6-8) M1K260149-002 AIR 6-8 11/19/2001 29000 U 1100000 14000 U 29000 U 14000 U 14000 U 14000 U 2300000 14000 U 14000 U 72000 U 14000 U 14000 U 220000 U 14000 U 14000 U 29000 U 15 1. 1 59 0.0,8 17 3.6 0.0029 U --- --· - Sample ID Laboratory ID Matrix Sample Depth Sample Date GC/MS Volatiles nnb lvlv) Chloromethane Vinyl Chloride Bromomethane Chloroethane 1, 1-Dichloroethane 1, 1, 1-Trichloroethane Benzene 1,2-Dichloroethane Trlchloroethene 1,2-Dichloropropane 4-Methyl-2-pentanone (MIBK) Toluene Tetrachloroethene 2-Hexanone 4-Ethyltoluene 1,4-Dichlorobenzene Hexachlorobutadiene Fixed Gases %/v/v} Carbon Dioxide Oxygen Nitrogen Ethane Ethene Methane Carbon monoxide -- - - --- SGMW7 (2-4) Table 7 SGMW Analytical Results National Starch and Chemical Company Cedar Springs Site, Salisbury, NC SGMW7 (6-8) SGMW8 (2-4) M1K260149-013 M1K260149-014 M1K260149-015 AIR AIR AIR 2-4 6-8 2-4 11/20/2001 11/20/2001 11/2012001 7.0 U 40000 U 15 U 3.5 U 56000 7.7 U 3.5 U 20000 U 7.7 U 7.0 U 40000 U 15 U 4.3 20000 U 7.7 U 4.2 20000 U 7.7 U 3.5 U 20000 U 7.7 U 19 1600000 15 35 20000 U 17 15 20000 U 9.0 18 U 99000 U 38 U 3.5 U 66000 7.7 U 620 20000 U 630 53 300000 U 110 3.5 U 20000 U 7.7 U 3.5 U 20000 U 7.7 U 130 40000 U 55 3.2 21 3.9 19 3.4 ', 19 76 67 76 0.00088 U 0.00098 U 0.00096 U 0.00088 U 6.5 0.00096 U 0.0017 0.068 0.00081 0.0018 U 0.0020 U 0.0019 U SGMW8 (6-8) M1K260149-016 AIR 6-8 11/20/2001 33000 U 57000 17000 U 33000 U 17000 U 17000 U 17000 U 1300000 17000 U 17000 U 84000 U 37000 17000 U 250000 U 17000 U 17000 U 33000 U 19 6.9 66 0.00084 U 5.6 0.054 -- SGMW9 (2-4) M2B120193-001 AIR 2-4 2/6/2002 4.0 U 2.0 U 2.0 U 4.0 U 2.0 U 2.0 U 2.0 U 2.0 U 2.0 U 2.0 U 10 U 2.0 U 2.0 U 30 U 2.0 U 4.8 4.0 U 0.039 22 81 0.0014 U 0.0014 U 0.00057 0.0028 U OIL -the concentration is estimated due to dilution or the presence of intertering analytes. U -analyte is not detected at the indicated concentration ---- Page 3 of 3 SGMW9 (6-8) M2B120193-002 AIR 6-8 2/612002 4.0 U 2.0 U 2.0 U 4.0 U 2.0 U 2.0 U 2.0 U 2.0 U 2.0 U 2.0 U 10 U 2.0 U 2.0 U 30 U 2.0 U 5.7 4.0 U 1.4 19 83 0.0012 U 0.0012 U 0.00048 U 0.0024 U I I I I I I I I SOURCES: ROWAN MILLS, CHINA GROVE, NORTH CAROLINA 7.5 MINUTE QUADRANGLE CONTOUR INTERVAL= 10 FEET QUADRANGLE LOCATION 05/06/02 CRA-54-TLF 05007001/05007805.cdr s•n· 98 MILS UTM GRID AND l98f MAGNETIC NORTH DECLINATION AT CENTER OF SHEET 2000' 0 2000' Approximate Scale: 1" = 2000' NATIONAL STARCH AND CHEMICAL COMPANY CEDAR SPRINGS ROAD PLANT SALISBURY, NORTH CAROLINA PHASE II NOTS INTERIM REPORT SITE LOCATION MAP I FIGURE BBL BlASlAN0, BOUCK & LEE, INC. 1 engineers & scientists I I I I I I I ~-~~g~~s=:: I I I I I I 0 X: 05007X02.Dwt; L: Of"f•Fl'Ef I P: PAGESE:T/PLT-Dl. 04/01/02 CRA-!>4---IY 05007001/05007804.0WG • P-2 I ( I / I \ I I I I \ \; I I. LEGEND o MONITORING WELL LOCATION ♦ EXTRACTION 'NELL LOCATION .a SOIL GAS MONITORING WELL A PROPOSED BACKGROUND SOIL GAS MONITORING WELL LOCATION I I SOURCES: -MAP ENTITLED •51rr MAP. PREPARED FOR NATIONAL STARCH \ AND CHEMICAL COMPANY BY INTERNATIONAL TECHNOLOGY CORPORATION, KNOXv'ILLE, TENN., DATED 5/18/93. MONITORING 'NELL SURVEY BY SCHULE['lBE.RGER SURVEYING COMPANY, SALISBURY, N.C., DATED 1/21/97 MONITORING 'NELL SUR\IE;Y BY TAYLOR 'NEISMAN & TAYlOR, RALEIGH N.C .• DATED .3/98 MAP ENTITLED .FlGURE J-1 LOCATION Rf SOIL PLOTS AND SOIL GAS MONITORING WELL!; IN AREA 2 PREPARED BY NATIONAL STARCH AND CHEMICAL COMPANY. SALISBURY, N.C. DA TE: UNKNOWN. MAP ENTITLED ·FIGURE J-2 LOCATION OF REPLICATION PLOTS AND SOIL GAS MONITORING °WELLS 1N 1HE LAGOON AREA · PREPARED BY NATIONAL STARCH ANO CHEMICAL COMPANY. SALISBURY, N.C. DATE: UNKNOWN. ""' ' SCALE IN FEET I I I I I I I I I I I I I I I I I I I 0 / ::, 0 / 4o 0 0 0 0 I I I \ / / ----- \ 0 O \ 0 0 \ 0 0 \ \ --/ / ( I \ < \ \ \ \ I I I I \ \ \ \ I \ \ \ \ \ I I I \ I I I \ \ \ I I I I \ I I I I I I I I I \ \ \ \ \ \ \ \ I I \ \ \ \ \ \ \ I I I I I I I I I I I I I I I I I I I I I I I I / / I I iQ 0 0 I \ \ I I I I I I I I I I I I I I I ( I I I LEGEND & SOIL BORING LOCATION (APPROXIMATE} • MONITORING WELL LOCATION ♦ EXTRACTION 'NELL LOCATION A SURFACE WATER/SEDIMENT SAMPLE LOCATION A SOIL BORING (UNMONUMENTED) G) MONITORING WEU ---ABANDONED TERRA-COTTA PROCESS SEWER LINES (UNDERGROUND) ---ABANDONED TERRA-COTTA STORM SEWER LINE SOURCES: -MAP ENTITLED ~SITE MAP• PREPARED FOR NATIONAL STARCH AND CHEMICAL COMPANY BY INTERNATIONAL TECHNOLOGY CORPORATION, KNOX\/ILLE, TENN., DATED 5/18/93. -MONITORING WELL SURVEY BY SCHULEt,IBE.RGER SURVE'l1NG COMPANY, SALISBURY, N.C., DATED 1/21/97 -MONITORING WELL SUR'v'E;Y BY TAYLOR WEISMAN & TAYLOR RALEIGH N.C., DA TED 3/98 ' -SURVEYED BY TAYLOR 'MSEMAN & TAYLOR. GRID LAYOUT/BORING LOCATION MAP, NATIONAL STARCH PLANT, ROWAN COUNTY, SALISBURY, NC, DATED 10/25/01 NATIONAL STARCH AND CHEMICAL COMPANY CEDAR SPRINGS PLANT SALSBURY, NORTH CAROLINA PHASE II NOTS INTERIM REPORT SOIL BORING LOCATIONS BBL FIGURE BV.SLAND, eotJCK & LEE, INC, eng/noen !!I 1clon11111 3 SG-MW-9 0/ SBA2-16 ~ ~fZ!!:! ____ ( 1,2-DCA I CHLORCETHANE ; CHLORIDE ! V!NYL CHLORIDE o 3.5-4.0 i 6.a u l 14 u \ 14.1 u ! 14 u // '-""'-'=-'-"'"-''--'-'-;;..a:....-,-----=-"--'---"----./-! SB-1"6A SGMW-9 i:)EPT~i _ 1 _ f,_2~~6CA"' :··cH_LORofTI-iANE _-:-cl➔LQf{iDE"T\fN'(L"CHLORiD( 5~-0-=-5~5-j 2.9 J f 12 U : 67.5 I 18 /0 /\ _DEPTI-l 1.2_:-DE4f-HLOROETHANE 1' CHLO~IDE-+-V,NYL CHLD~1DE 4.5-5.C 5A U i 11 U I ~ NA 1 11 U SB-146B DEP-T~l--T·1:-2~ocA· r-cnL-o"R"OE"THANE : cHL6RtDE i V,NYL "cHi.ORibE --2.5 ~:-f(fi 31 -: 12 u : 57.5 1 250 E DEPTH ---·-------· 13.5-14.0 SB-199A -DEP.iH_ ! 1,2-ocAT cHLOROETHANE-f CHL0131_0TT VINYL _P!j!::_qp:!_qf 11.0-11.5-40 520 U 7 12.2 U '----; 520 U X: POSTINGS. TXT L: OFF=REF SBA2-20 o_EPTH .. : .. ! 1,2-ocA I cHloRoETHANE_! CHLORIDE f VINYL CHLORIDE - 2.5-3.0 ! 7 U ! 7.6 J l NA .. __ ' 14 U S.5-4.0 i 7.4 1 12 U NA 1 12.~u-.. -_-_-_-_-.. _-: )~Q_~~-5 _ ! 3.6 J [13U-1 47.9 : 13 u--~---------·- _!;i.5-:§ . .Q_ ! 2 . .3 J i 10 tr __ .f fit' ___ . l 1 __ 0 u 6.5-7.0 -39-□ U j NA -,..r 3~o~o~u·_· __ __, 7.5•--ao J,100 u ! NA 3,100 u a.5---s.o .. 29,ooo u NA 29,ooo u g-:s=fQ.c 140,000 13,000 U , NA 13,000 U 10.s-11.0 s2.ooo s,100 u , NA ~,7oo u · -- 1f5-12.o 44,000 3 200 U -: NA 3,2CO U P: PAGESET/PLT-DL 01/30/03 CRA-54-IY,TLF 05007001/ 05007C10,DWG S8A2-11 4. SBP.2-1 0 A. 0 l-c'7.~5--8=.c=. -5 ~U~' -i 9.9 U I ! NA ! 9.9 U \ \SIBEAM SB-124A _Q_S£'_TH r 1,2-ocA i cHLoR0Er~_ANET CFL0~10;;: 4.0-4.5 ! 1.2 Ji 11 U I 39.1 i 2-lllm'l'IIIE[A!IDJIBL\L:mDO c,llmWN'IN>--am«tDWWWILd) SB-1248 OtP·--·--(2-DCA I CHLOROETHANE 1 CHLORIDE"""j V!NY\.. CHLORIDE s.o....:s.s 11,s J ·t-11 u __ .. ___ i 35 ! 10 J \ \ \ \ ..,,.o=EP~r~H~~:~,~,2~-cicA·-;=¢FLOR-oft·;~}i:~~2P.~DE 1 wJYL cit-o-R1-g_( 11.0-11.5 i 500 11 U 1 13.1 U i 11 U < ,'1-;:r~ ' ' SB-19~A DEPTHT 1,2-DcA 1 CHLOROE1HANE : CHLORlofG,mYL 01LOR!□E o-05's.s u \ 14 1..: ! 13.5 i 14 u I SB-1738 "DEPTfi~~OCA 1 CHLOFWETHP.NE"'. CHLORIDE ·1 VINYL CHLCR\DE 5.5-6.0 i 250 U ! 510 U 1 11.6 U ! 510 LI SBA2-0B DEPTH ____ J_ 1, 2-D_~f', _\_gHLOROETHANE_t-9il:.Qf:JQL__Y!tj_)'.h __ f_'.>i_b9_!i\Q_E;_ 4.()-f._~ j 56 ! §.8 -~ _ ... _ _ i 16:_3 __ .... ' __ 5_.4 ~ 17.5-1s~O-2,100 ·39---------·-rsa.2 ------: rE:·J ---------- SB-Q3.411 .DEPTH l 1,2-ocAT CHLOROETH,\NE i CHLORIDE ' VINYL CHLORIDE ·5:a-s~s ·n .3 u i s.s u · --·---711~s u : a.s u SB-OJ4A DEPTH f 1,2~DCA ! CHLOROETiiANE ('CHlORiDE l V!NYl CHLORIDE- 7,5-8.0 1 s-:-1-u-T11 u 11.3.5 u i 11 u SB-OJ6A :_(?_F;f'.IrL : r..~ ,2_:-Q¢_6 _ ~ ¢_H_~O_:~_q~td~-~-~. L CHt/~~!~F;-1-0_t_,iY1=-.f.8~9_RlD( 1.5-2.0 i 4.9 Li + 9.8 U j 15.1 l 9.8 U "i--==~~~~-~==se"'-0368 Q_EPTH ! 1,2-ocA~_CHLOROETHIK([tl:::.~Q31.9.~ _: VINYL c~_L_Q~Q~, 4.0-4.5 16.SU 113U )12.4U i t3U SB-0128 -~~f}fi=~].J,?=)~G~_~.fB_1:-cROETHANE ] CHLORIDE _[_ViN\-L~LO.RIDE- 17.5-18.0 i 54 ; 10 U ; 11.6 U ! 10 U I .. . . LEGEND .o. SOIL BORING LOCATION (APPROXIMATE) A SOIL BORING (UNMONUMENTED) ® MONITORING WELL u E J NA NOT DETECTED COMPOUND WAS OVER CALIBRATION RANGE COMPOUND DETECTED BELOW THE REPORTING LIMIT (THE VALUE GIVEN IS AN ESTIMATE) COMPOUND WAS NOT ANAL YlED ALL UNITS ARE IN UG/KG SOURCE: INDICATES DETECTED CONCENTRATION GREATER THAN THE ROD PERFORMANCE STANDARD OF 169UG/KG FOR 1,2-DICHLOROETHANE (1,2-DCA) -SURVEYED BY TAYLOR WISEMAN & TAYLOR. GRID LAYOUT/BORING LOCATION MAP, NATIONAL STARCH PLANT, ROWAN COUNTY, SALISBURY, NC, DATED 10/25/01 0 60' 120' I-----;;.;I I GRAPHIC SCALE NATIONAL STARCH AND CHEMICAL COMPANY CEDAR SPRINGS PLANT SALSBURY, NORTH CAROLINA PHASE II NOTS INTERIM REPORT ANALYTICAL SOIL SAMPLING RESULTS BBL BLASLAND, BOUCK & LEE, INC, enginee r s & scientists FIGURE 4 ------ ------ - ...._____ \ ' ', \ \ "" \ \ "" \ \ \ "" \ \ \ '\ SB-229,1, 4001 113.5 -14.0 ~ ~ SBA2-O7 "----_,,,,-, 1-c,,,,u"'A"'-RTE'-", ccR +'DC:,, E""P,::,TH:__,,~--' 1',!i' 2:;,..;; _,.,/ "' 4Q9'.2 18.0 -22.0 410 D /*_,,-l.-""40Jc>9'"c2~-/-"2'.'c0.~0,:c·:_· cc22'.c.C"-,a,7:..:,4"'-0 -"D / 4092 8 ,0 -10.0 1 110 U \ \ QUA.RTER 1Qi}3 SBA2-05 SBA2-11 DEPTH 1,2-DCA 4.0 6.0 3 J 1Q93 \ \ \ '"-. A 1083 6.0 ' 8.0 2 J SB\2-1 1"" SBA2-2O Q!J/!RTER I DE}JTH i,2-DCA 10;;13 : 4.0 -6.0 1.600,DOO D 1093 i 6.0 -10.0 290,000 D 4001 l 2.s -3.o 1 u 4001 ! 3.5 -4.0 7,,1 4001 Q01 l 5.5 -6.0 4{)01 ! 6.5 --7.0 -·4001 '' ·1 i. 5 ·-8~0 4Q01 i 8.5 -9.0 4Q01 ! 9,5 -10.0 4QOi i 10,5 -11.0 4001 i 1"1.5 -12.0 2.3 J 470 70,000 470,000 ,,,~ ,/ \ /// \ // \ < \ X: 05007X01.D\,G,05007X02.DWG,FIG5.i¾ L: OFF=REF ,\ \ P: PAGESET/PLT'.l.□L \ D5/02/02 CRA-54clY, TLF \ 05007001 / 05007C\1.DWG ./' \ \ SOIL PLOT 1 QUARTER DEPTH I 1,2-DCA 4Q96 r4-~~6 2. 1 00 __ 66,000 4Q96 6 ----e 11,000 -9s,ooo 1Q87 I 4 -G 9,700 -19,000 1097 6 -8 13,00 2QS7 2 -4 1,100 2Q97 4 -6 480 ZQ97 6 -5 250 3097 4 -6 :SQ97 6 -8 4Q97 2 --4 4097 4 -6 ,tQ97 6 -8 \ \ ' I \ fl / / ( 11 I I I \ SB-199A QUAR rER DEP fH 4007 ! 11 0 -11.5 SBA2-1O Ql.JAR T[R DEP TH 4Q96 2 -' 4 ()96 4 -c 4Q9(i 5 -6 lQ97 2 -' 1Q97 4 -6 1Q97 5 -A 2Q97 2 ., 4 2Q97 4 -· 6 2Q97 5 -8 3Q97 2 -4 3Q97 4 -,, I I I I \ I \ \ \ \ \ \ \ \ I I \ \ "- \ \ \ "" ...._____ S8-1998 QU.A.RTER DEPTH i 1,2-DCA 4001 I 13,5 -14.0 i 4.8 u ) I I I \ ---- "" '--- 1.2-DCA \ 220 U ) \ /// \$B::'..146A SB-46B ~ QUARTER j DEPT.'1 1,2-DCA '-. 4001 1 iLO -11.5 I .300 U \ \ I-Q-U~A~R~TE=R-,C":='c\;=,1"';=4 "-rc--=-c-ccc-l SOIL PLOT 3 \ -+'' \ \ \ \ \ SB-1948 ------QUAfnu-: ' DEPTH -.._ 4Q01 i C -0.5 SBA2-16 QUARTER DEPTH 4001 1-c-~=-,-,cSB=c-=1;,c, 48""A"--77-=cc-l ,,,,,, OU.t\R;"ER l DEPTI-i i 1,2--DCA. /" 4Q01 5.0 + 5.5 ! 2.9 J y \ SB A S8-146B QUAi~T~R DEPTH ! 1.2-DCA 4007 I SBAZ-08 Qf.JARTER i DEPTH 4\)92 ! D -2.0 4001 4bo1 f 2.0 -4.0 ! 18.0 --20. SB-124A QUAR~ER ' DEPTH I 1.2-DCA 4-001 I i 4.0 -4.5 : 1.2 J I SBA2-09I OUAR TE.k DEFlH 1,2-DCA QUARTER DEPTH 4Q96 0 -2 330,000 D 4096 2 -4 3,400,0 4096 4 -6 480 J - 4096 6 -8 110,000 -440, 1Q97 2 _, 4 350,000 D -4-2 i097 I 4 ' 6 140,000 D -480, 1097 6 -8 32,000 -260,0 2097 4 -6 2097 5 " 6 7,500 J 3097 4 ,_ 6 88,000 3Q97 4 -6 -36,000 2;,Q97 6 -8 4097 2 -4 4Q97 4 -5 409"/ 4 -6 4097 6 -8 TJ : : I ' j \ ! 4.0 ·-6.0 i 3.0 ·-10.C i 20 0 -22. i 5.0 -5.5 I 7.5 -8.0 , QUcRTER 4QS2 \ 2.0 -4.0 \ \ SB-O348 SGMW-9 I I I SG-MW-9 _ Q,UAR!,f;R _ DEF_TI-J ______ : ,2--DC.A. \ \ \ \ \ \ \ \ SB-194" <1-Q01 4Q01 QUARTER \ DEPTH 1,2-DCi\ 4Q01 f O -0.5 I 6.8 U \ SB-1738 CU.A.RTER 1 DEPTH 1,2-CCA i 5.5 --6.0 l 250 !J \ SB-173A QU.~RTER ; DEPTH 1 1,2-DCA '1-QO': ( 7.5 --8.0 1 4.5 U 7.5 -8.0 5 U \ \ \ \ \ \ \ I I I I I I \ \ SB-O36A \ \ \ \ I ' I I \ \ \ I \ \ I I \ \ \ \ \ \ \ \ \ \ \ \ ~ \ \ \ \ \ I \ QUAKTER DEPTH 1,2-DCA. SB-O36B \ \ \ \ SB-O34A DEPTH 1.2-DCA 7.5 -8.0 ;5.7U \ \ \ SB-012" l 1,2-DC,A. i 15.-5 -16.D 4,2 U I I l QU/1.ffTFR i DEPTH , 1,2--D~~ 4001 i 4.0 -4.5 i 5.5 U \ \ \ \ I \ \ I I ) _,/ ~r RCP /J-, 3~;;r:<.; ,,,-,,,;:,/ // /" / /_,,;:, / / / ~ I I I ) LEGEND • u D E J SO IL BOR ING LOCATION EXTRACTION WELL LOCATION SURFACE WATER/SEDIMENT SAMPLE LOCATION SOIL BORING (UNMONUMENTED) MONITORING WELL ABANDONED TERRA-COTTA PROCESS SEWER LINES (UNDERGROUND) ABANDONED TERRA-COTTA STORM SEWER LINE SOIL PLOT NOT DETECTED CONCENTRATION REPORTED FROM A SECONDARY DILUTION EXCEEDED CALIBRATION RANGE (DILUTED RUN CONCENTRATION IS UNAVAILABLE) ESTIMATED CONCEN TRATION IS LESS THAN THE DETECTION LIMIT l 660D■INDICATES DETECTED CONCENTRATION GREATER THAN THE ROD PERFORMANCE STANDARD OF 169 UG/KG FOR 1,2-DCA ALL UNITS ARE IN PPB. SOURCES: MAP ENTITLED "SITE MAP" PREPARED FOR NATIONAL STARCH AND CHEMICAL COMPANY BY INTERNATIONAL TECHNOLOGY CORPORATION, KNOXVILLE, TENN., DATED 5/18/93. MONITORING WELL SURVEY BY SCHULENBERGER SURVEYING COMPANY, SALISBURY, N.C., DATED 1 /21 /97 MONITORING WELL SURVEY BY TAYLOR WEISMAN & TAYLOR, RALEIGH N.C,, DATED 3/98 FINAL REMEDIAL INVESTIGATION REPORT FOR OPERABLE UNIT THREE. PREPARED BY IT CORPORATION . DATED JUNE 2, 1993, PHASE I NATURAL DEGRADATION TREATABILITY STUDY FOR OPERABLE UNIT 4, CEDAR SPRINGS ROAD PLANT, SALISBURY, NORTH CAROLINA. PREPARED BY ENVIROGEN, INC. DATED MARCH 26, 1998, NATIONAL STARCH AND CHEMICAL COMPANY CEDAR SPRINGS PLANT SALSBURY, NORTH CAROLINA PHASE II NOTS INTERIM REPORT HISTORICAL 1,2-DCA ANALYTICAL SOIL SAMPLING RESULTS PLANT AREA BBL BLASLAND, BOUCK & LEE, INC . engineers & scientists FIGURE 5 I I / / / / \ \ \ / X: 05007X01.DWG,05007X02.DWG L: OFF~REF P: PAGESET/PLT-DL 01 /30/03 CRA-54-IY, TLF 05007001 / 05007C14.DWG \ \ \ \' ' ,,\ \ \ \ \ \ \ (\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ / \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ > \ V \ / I I QUARTER 4Q92 4Q92 SBLA-22 SBLA-04 QUARTER DEPTH 1,2-DC.4 ,fQ92 4Q92 4092 SBLA-06 SBLA-06 * 1/ DEPTH 6.0 - 8.0 .. 11,?-DCA B.C i 51 :0.0 ! :52 SBLA-19 Ji.. QU/1,RTER DEPTH 1,2-DC . .'i.. Toii---·· t ·4~0-~ .o i s J // / _/ ~ SBLA-07 SBLA-23 QUARTER ' DEP TH l 1,2-DCA 1093 i 2.0 ·-4.0 l 6 u SBLA -24 SBLA-24 C!UARTF R I DEPTH ! i,2-DGA 1 Q93 I s.o --8.0 ! 3 J \ \ \ \ \ \ \ \ \ \ \ SBLA-2J SBLA/22 .A SBLA-20 SBLA-07 QUARTER 4092 4-Q92 \ \ \ \ \ \ \ \ \ \\ \ \ \\ \\ \ \ \ I I \ \ I I I SBLA-10 OU.ARTER DEP TH 4092 6.0 -8.0 4Q92 16.0 .-13.0 1,2-DCA 13 7 u \ \ \ \ \ SBLA -0 I I I I I \ l I I NS-49 SBLA-05 \ • /3BLA 05 - SBLl'.-15 A,,,---- SBLA-18 (\ QUARTER -----------· .:.Q92 \ \ ,;.Q92 ~/' 40 92 DEPTH -------------···---2.0 -4.0 4.C 5.0 6.0 -8.0 ! 1,2--DCA 230 /- 86 /9 I I J J \ \ SBLA-01 4 d-51 I \ \ I,----==-,.....,,,....--seLA-01 I QUARTER 4Q92 2.0 -4-.0 DEPTH I I I I QuARTER \ \ SBLA-0J DEPTH SBLAr-02 QUARTER DEPT}) 4Q92 4092 4092 1,2-DC,4 4C:32. 6. 0 -8. 0 13J J \ \ \ SBLA-03 \ \ \ \ \ QUARTER +Q92 SBLA-0._B 7 __ _, QU:'-.RER DEPTF i ,2-DCA tio92 , o -~ 2,0 I .::. ,1 4Q92 ! 4.0 .. 6.Q 9 U I SBLA-09 I I I I I I I I I \ I I I I I I I I I I I I I I I I ' 1,2--DCA , .2.0 -4.0 i 2 J \ I I I SBLA-08 / \ \ \ \ ' . \ \ 1 I I I I I I I I I I I I I I I I I I I I \ \ I \ \ / / I I I \ \ \ \ \ \ ,. \ \ SBLA -09 / / / \ \ \ \ \ \ \ \ / / / / _,,.,, / / / ------------/ / / 0 4-0' I I I I I I I I I I I I I I C I I I \ _j \ \ ,./ - \ \ \ \ \ \ 1,_ ---- aa· I GRAPHIC SCALE I , .. -·-_..,.,, / .. -----. .... ' ' I I LEGEND ,._ SOIL BORING LOCATION -$-EXTRACTION WELL LOCATION • SURFACE WATER/SEDIMENT SAMPLE LOCATION ~ SOIL BORING (UNMONUMENTED) @ MONITORING WELL -u D E J ABANDONED TERRA-COTTA PROCESS SEWER LINES (UNDERGROUND) ABANDONED TERRA-COTTA STORM SEWER LINE SOIL PLOT NOT DETECTED CONCENTRATION REPORTED FROM A SECONDARY DILUTION EXCEEDED CALIBRATION RANGE (DILUTED RUN CONCENTRATION IS UNAVAILABLE) ESTIMATED CONCENTRATION IS LESS THAN THE DETECTION LIMIT l660D■INDICA TES DETECTED CONCENTRATION GREATER THAN THE ROD PERFORMANCE STANDARD OF 169 UG/KG FOR 1,2-DCA ALL UNITS ARE IN PPB. SOURCES: MAP ENTITLED "SITE MAP" PREPARED FOR NATIONAL STARCH AND CHEMICAL COMPANY BY INTERNATIONAL TECHNOLOGY CORPORATION, KNOXVILLE, TENN., DA TED 5/18/93. -MONITORING WELL SURVEY BY SCHULENBERGER SURVEYING COMPANY, SALISBURY, N.C., DATED 1/21/97 -MONITORING WELL SURVEY BY TAYLOR WEISMAN & TAYLOR, RALEIGH N.C., DATED 3/98 -FINAL REMEDIAL INVESTIGATION REPORT FOR OPERABLE UNIT THREE. PREPARED BY IT CORPORATION. DATED JUNE 2, 1993. -PHASE I NATURAL DEGRADATION TREATABILITY STUDY FOR OPERABLE UNIT 4, CEDAR SPRINGS ROAD PLANT, SALISBURY, NORTH CAROLINA. PREPARED BY ENVIROGEN, INC. DATED MARCH 26, 1998. NATIONAL STARCH AND CHEMICAL COMPANY CEDAR SPRINGS PLANT SALSBURY, NORTH CAROLINA PHASE II NOTS INTERIM REPORT HISTORICAL 1,2-DCA ANALYTICAL SOIL SAMPLING RESULTS LAGOON AREA BBL FIGURE 6 BLASLAND, BOUCK & LEE, INC. engineers & scientists ~ ---------------- I I I \ \ \ I I I I I I I \ \ \ \ I I I I I \ I I I I I I I x-~NS~2 I I I I I I I I I I \ \ \ \ I I \ \ •: 05007'02.DWG L: OIT•REr,,,,V,PNTS P: PAG.:Sl:T/PLT-OL I 01/.}()/0J CRA-54-l'f,TU 05007001 /05007C12.Dwt; I \ \ \ \ \ I I I I I I I I I u) r------ r------ I I I I I I I \ \ \ I I I I I I I I I \ I I I I l-- \ / / \ / '--/ ,,-1/ 1/" ~ / LEGEND • MONITORING WELL LOCATION -$-EXTRACTION WELL LOCATION 1,.. SOIL GAS MONITORING WELL U NOT DETECTED D CONCENTRATION REPORTED FROM A SECONDARY DILUTION I SOURCES: ALL UNI TS ARE IN PPB. MAP ENTITLED MSITE MAPM PREPARED FOR NATIONAL STARCH AND CHEMICAL COMPANY BY INTERNATIONAL TECHNOLOGY CORPORATION, KNOXVILLE. TENN., DATED 5/18/93. MONITORING WELL SURVEY BY SCHULENBERGER SURVEYING COMPANY, SALISBURY, N.C., DATED 1/21/97 -MONITORING WELL SUR\IE;Y SY TAYLOR WEISMAN & TAYLOR, RALEIGH N.C., DATED 3/98 -MAP ENTITLED nFIGURE 3-1, LOCATION OF SOIL PLOTS ANO SOIL GAS MONITORING WELLS IN AREA 2" PREPARED BY NATIONAL STARCH ANO CHEMICAL COMPANY. SALISBURY, N.C. DATE: UNKNOWN. -MAP ENTITLED "FIGURE 3-2, LOCATION OF REPLICATION PLOTS AND SOIL GAS MONITORING WELLS IN THE LAGOON AREA". PREPARED BY NATIONAL STARCH AND CHEMICAL COMPANY. SALISBURY, N.C. DATE: UNKNOWN. -FINAL REMEDIAL INVESTIGATION REPORT FOR OPERABLE UNIT THREE. PREPARED BY IT CORPORATION. DATED JUNE 2, 1993. -PHASE I NATURAL DEGRADATION TREATABIUTY STUDY FOR OPERABLE UNIT 4, CEDAR SPRINGS ROAD PLANT. SALISBURY, NORTH CAROLINA. PREPARED BY ENVIROGEN, INC. DATED MARCH 26, 1998. NATIONAL STARCH AND CHEMICAL COMPANY CEDAR SPRINGS ROAD PLANT SALSBURY, NORTH CAROLINA PHASE II NDTS INTERIM REPORT HISTORICAL SOIL GAS MONITORING RESULTS DEPTH: 2-4 FEET BBL BlASLANO. BOUCK & LEE. INC. er,g,neer, t ,c;.,,,,,.1, FIGURE 7 --I I I I I I I I I I I I I I i \ \ I \ \ I ~07 I \ I I I I I I I I I I I I I I x-pr I NS--;2 I I / -- x: o5007X02 owe le Off•Rff P. PAC{S(lfPt.1-0l 01/lO/0J CRA-54-IY,Tlf 05007001 /0SD07Cl J.0WG I I \ \ I I I I I I I I I I I I I I I I I I I I I I I I I I I ( - I \ I I I I - \ \ \ / Lil \ / ['---\../ ['---✓ 1/ * SGt.lW-1 ) t.lONTH 1,2-DCA 0EC-96 31,000.000 D \ 0 JAN-97 3.700,000 0 FEB-97 3,100,000 D l.-1AR-97 5J ' s APR-97 2,000.000 D \ 0 -( t.lAY-97 3,700,000 0 JUN-97 460 D I JUL-97 ' u AUG-97 6,500.000 D \ I SEP-97 5,200.000 0 I OCT-97 2,500.000 D NOV-97 4,500.000 D > 0EC-97 2,800.000 NOV 01 740.000 I I I I / I / - - ( I I I I I I / / / _c-- LEGEND • MONITORING WELL LOCATION -$-EXTRACTION WHL LOCATION .._ SOIL GAS MONITORING WELL U NOT DETECTED O CONCENTRATION REPORTED FROM A SECONDARY DILUTION ALL UNITS ARE IN PPB SOURCES: -MAP ENTITLED ·s1TE MAP-PREPARED FOR NATIONAL STARCH ANO CHEMICAL COMPANY BY INTERNATIONAL TECHNOLOGY CORPORATION. KNOXVILLE. TENN .. DA TED 5/18/93. -MONITORING WELL SURVEY BY SCHULENBERGER SURVEYING COMPANY, SALISBURY, N.C .. DATED 1/21/97 -MONITORING WELL SURVEY BY TAYLOR WEISMAN & TAYLOR, RALEIGH N.C., DA TED 3/96 -MAP ENTITLED riFIGURE 3-1, LOCATION OF SOIL PLOTS ANO SOIL GAS MONITORING WELLS IN AREA 2" PREPARED BY NATIONAL STARCH AND CHEMICAL COMPANY. SALISBURY, N.C DATE: UNKNOWN. -MAP ENTITLED riFIGURE 3-2. LOCATION OF REPLICATION PLOTS ANO SOIL GAS MONITORING WELLS IN THE LAGOON AREAri. PREPARED BY NATIONAL STARCH AND CHEMICAL COMPANY. SALISBURY, N.C. DATE: UNKNOWN -FINAL REMEDIAL INVESTIGATION REPORT FOR OPERABLE UNIT THREE PREPARED BY IT CORPORATION. DATED JUNE 2. 1993 -PHASE I NATURAL DEGRADATION TREATABILITY STUDY FOR OPERABLE UNIT 4, CEDAR SPRINGS ROAD PLANT, SALISBURY, NORTH CAROLINA. PREPARED BY ENVIROGEN, INC. DATED MARCH 26, 1998. NATIONAL STARCH AND CHE~ICAL CO~PANY CEDAR SPRINGS ROAD PLANT SALSBURY, NORTH CAROLINA PHASE II NOTS INTERIM REPORT / 1-----cH=1=s=T=o=R~IC~A~L~S~0=1~L~G-CA~S~------1 MONITORING RESULTS DEPTH 6-8 FEET BBL BLASLAND BOUCK & lEE, INC lilng,na•r, I 1,;,an11t/1 f'IGURE 8