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HomeMy WebLinkAboutNCD991278953_19970301_National Starch & Chemical Corp._FRBCERCLA RA_Groundwater Remediation System OU-3, Conceptual Design & Preliminary Design Report-OCRI I I I I •• I I I I I I I I I I I I I 'f)up SALISBURY PLANT 1~vl~ 'MAR 2 ~ i~91. GROUNDWATER REMEDIATION SYSTEM OPERABLE UNIT 3 CONCEPTUAL DESIGN AND PRELIMINARY DESIGN REPORT March 1997 Prepared by NATIONAL STARCII AND CHEMICAL COMPANY 10 Finderne Avenue Bridgewater, New Jersey 08807 National Starch and Chemical Company Salisbury, North Carolina I I I I I I I I I I I I I I I I I I I TABLE OF CONTENTS 1.0 INTRODUCTION ....................................................... 1 1.1 Purpose and Organization of Conceptual Design Report ................... 1 1.2 Site Location and Description ........................................ 1 1.3 RD/RA Work Plan and On-Site Meeting ................................ 6 1.4 Summary of Site Characteristics ...................................... 7 1.5 Conceptual Design Report Contents ................................... 7 2.0 GROUNDWATER EXTRACTION SYSTEM ............................... 11 2.1 Installation of Extraction Wells ...................................... 11 2.2 Step-Drawdown Pump Tests ........................................ 11 2.3 Packer Testing of Bedrock Wells .................................. 11 2.4 Surveying of Site and Wells ........................................ 15 2.5 Sampling of Groundwater from Saprolite and Bedrock Wells .............. 16 2.6 Pilot Testing of Diffused Air Stripping Treatment System ................. 16 3.0 REMEDIAL DESIGN .................................................. 25 3.1 Design Basis ..................................................... 25 3 .2 Existing Trench Area Pretreatment System Difficulties ................... 2 7 3.3 Proposed Pretreatment System for OU3 and Trench Area Groundwater ...... 27 3.4 Details of the Proposed Groundwater Pretreatment System ................ 28 4.0 PRELIMINARY DESIGN ............................................... 32 4.1 Preliminary Sizes and Preliminary Equipment List ....................... 32 4.2 Preliminary Design Drawings ....................................... 32 4.3 Air Permit Application ............................................. 32 I I I I I I I I I I I I I I I I I 1.0 · INTRODUCTION 1.1 Purpose and Organization of Conceptual Design Report This Conceptual Design and Preliminary Design Report is prepared to fulfill requirements of the United States Environmental Protection Agency's (USEPA's) Unilateral Administrative Order and the Statement of Work (SOW) for the Remedial Design/Remedial Action (RD/RA) of Operable Unit No. 3 (OU3) at the National Starch and Chemical Company's (NSCC's) Cedar Springs Road Plant site in Salisbury, North Carolina. It is prepared in accordance with the Final RD/RA Work Plan at OU3 approved by the USEPA on August 20, 1996 and presents the details of the Groundwater Extraction System, the Groundwater Pretreatment System, and the Preliminary Design of the Groundwater Pretreatment System. This Conceptual Design and Preliminary Design Report is comprised of four sections. Section one of this Conceptual Design and Preliminary Design Report presents and discusses Site Background Information. Site Background Information includes site location, site history, and a summary of site soils, sediments and groundwater characteristics. Section two presents and discusses the details of the Groundwater Extraction System at OU3. Section three presents and discusses the details of the Pretreatment System including the design basis for the various unit operations. Section four contains the Preliminary Design Drawings of the Groundwater Pretreatment System. 1.2 Site Location and Description The NSCC site, also referred to as the Cedar Springs Road Plant site, is located in Rowan County, North Carolina, approximately 5 miles south of the City of Salisbury. Salisbury is approximately 40 miles northeast of Charlotte, North Carolina along Interstate 85. Figure 1-1 illustrates the location of the site. Land use of the areas immediately adjacent to the site is a mixture of residential and industrial developments. An industrial park is located on the east and south sides of the site. Grants Creek forms the western boundary of the site. The Southmark Industrial Park is located along the southern property line. The Little Acres Mobile Home Subdivision adjoins the extreme southwestern corner of the site. A housing development, Kings Forest, is adjacent to the north side of the site. A second development, Stonybrook, lies across Airport Road on the northern side of the site. I C:',PROJECTS1SLSBRY·(HJJ',O\J3CNDES.SV I I I I I I I I I I I I I I I I I I I I The NSCC site is approximately 500 acres in size. OU3 at the NSCC site comprises of the following: 1. 2. Contaminated groundwater located in Area 2, the parking lot, and the wastewater treatment lagoons of the Plant; and Contaminated surface water/sediments in the Northeast Tributary. The Chemical Production Plant and the wastewater treatment lagoons are located in the southwestern portion of the property. The portion of the NSCC facility known as Area 2 is located in the northeast portion of the Plant Operations area. The wastewater treatment lagoons are located in the south and southwest portion of Plant Operations area. Figure 1-2 illustrates these facilities at the NSCC site. The Northeast Tributary crosses the NSCC property paralleling Cedar Springs Road and passes within 50 yards of the front of the Plant Operations Area. This tributary receives runoff from an industrial complex on the east side of Cedar Springs Road, from Cedar Springs Road itself, and from the Southmark Industrial Park located to the south. Areas on both sides of the stream contribute runoff throughout its reach. The watershed boundary is shown in Figure 1-3. From the Area 2 of the Production Plant, the stream flows for approximately 6,000 feet before joining with Grants Creek located to the north. Grants Creek flows approximately 12 miles beyond NSCC property where it joins with the Yadkin River approximately 2 miles downstream from the water supply intake for the City of Salisbury. The Northeast Tributary receives discharge from the W. A. Brown Plant through a National Pollutant Discharge Elimination System (NPDES) permit. W .A. Brown is an industrial facility located on the east side of Cedar Springs Road. The discharge point is a pipe located on the east bank of the Northeast Tributary, downstream of the NSCC Plant Operations area (Figure 1-2). Area 2 of the NSCC facility consists of the reactor room, the tank room, raw material bulk storage facilities, warehouse tanks, diked storage tanks, and roadway. The wastewater from Area 2 consists of water from washing/rinsing of reactors and line (piping, pumps, etc.) flushing. These cleaning operations occur between processing of different products. The waste stream discharge _includes reactor and feed line wash and rinse, which contains trace amounts of organic and inorganic compounds in a water solution. The wastewater from Area 2 is sent to the Plant's Wastewater Pre-Treatment System before being discharged to the City of Salisbury's Publicly Owned Treatment Works (POTW). The existing Wastewater Pre-Treatment System is composed of two Lagoons ( Lagoons No. I and No.2 ) for storing untreated wastewater ( Lagoon No. I is aerated ), a Primary Treatment C:1PROJECTSISLSBRY·OU310\J3CNDES.SV 2 I I I I I I I I I I I I I I I I I I I li,IILL BRIOC[ o-i'7,- 70 "o v,i,,,_ "' l__ ) "'"-._ { DAVIDSON COUNTY ---- HICH~ ROCK LAKE COUNTY N \ KANNAPLOIS CABARRUS COUNTY 7 I {N;ational Starch and Chemical Company Salisbury, North Carolina SCALE: 0 8 16 MILES Figure 1-1 Site Location Map r,-------------------------------------~7 I I I I I I -I I ii I I i I I I I I N. C. GRID NORTli (NAO 83) \ NPDES PERMITTED DISCHARGE POINT\ FOR W.A. BROWN \ • --~ ,,--... NORTHEAST TRIBUTARY X --·· 0 0::: ".+' .. ( ~ Q_ Q_ ◊ oo-.>. <( "" '-i,.G 'l-) ~ C~-~ -..._/ w ~ ( ""j z '-i,.G \ _J ~ -.,.o .\__,, ---✓ ~ >-f-- \!oo-.>. 0::: g ~ _) w Q_ L 0 0::: Q_ 0 100 200 JOO J {jjJ:,tlonal S/arch and Chemical Company 600 FUT SITE PLAN SALISBURY, NC PLANT ~.__ _________________________________________________ _j_ ______________ _L _ __:M:::AR'.'._'.:C:'..'._H_:_19:_:9'.'._7 __ _1_ _ _.':F.'_'-IG'.'.:UR:'.E:..___'._:1-~2~__J_J .-,-----------------------------~7 I I I I i I I I I i I I I I I I I ~ N AIRPORT ROAD + 500 0 500 p10iit•1■1■ i'41iil UH,■ IUf ii I ►-HH ii ■ ii I+*' ii lilll 1111 ♦4 I ii I ii I iii++ I 11111 I ii I j 250 750 + /ilptlonal Starch and Chemical Company SALISBURY, NC PLANT + + + + WATERSHED MAP MARCH 1997 FIGURE 1-3 _J I I I I I I I I I I I I D E I I System for solids removal, a Biological Reactor ( Lagoon No.3 ) for stabilizing soluble organics in the wastewater and an Effluent Lagoon ( Lagoon No.4 ) for storing secondary effluent prior to discharge into the City of Salisbury sewer system. The Plant's Wastewater Pre-Treatment System was upgraded to allow Pre-Treatment and discharge of combined groundwater from OUI and plant effluent. This system, known as the Combined Pre-Treatment System, is now treating both OUI groundwater (including the Plume Periphery groundwater and groundwater from the Extraction Wells in the Trench Area) and plant wastewater. The Combined Pre-Treatment System is designed to treat two OUI groundwater streams (Trench Area and Plume Periphery groundwater) in addition to the Plant's wastewater. Trench area groundwater is now treated in the Trench Area Pretreatment System to remove metals and organic compounds before being discharged to the existing Lagoon No. l where this flow is combined with the Plant's wastewater. Lagoon No. I provides equalization and pH adjustment to the wastewater. Wastewater from Lagoon No. I is pumped to the Primary Treatment System where solids are removed by chemical precipitation and settling in a Primary Clarifier. Overflow from the Primary Clarifier flows into Lagoon No.2 for equalization and is transferred to the Biological Reactor (Lagoon No.3) once a day. Following completion of treatment, the treated effluent is decanted and pumped to Lagoon No.4 for further storage and aeration before being discharged to the City's sewer for further treatment at the POTW. 1.3 RD/RA Work Plan and On-Site Meeting As required by the Unilateral Administrative Order, a Draft RD/RA Work Plan was I prepared and submitted to the USEPA during December 1995 to provide the framework for conducting the RD/RA of OU3 for remediation of groundwater contamination at this site. After several revisions of this Draft the Final RD/RA Work Plan was approved by USEPA during April 1996. During August, 1996 USEPA gave NSCC Notice to Proceed with the RD/RA Work Plan activities at this site. A site visit was conducted by the USEPA and the NCDEHNR on October 4, 1996. A kick-off meeting with the USEPA, the NCDEHNR, the Weil L\·illers and the Packer Testing Consultant was also held at the site on Friday, October 4, 1996 for initiating the OU3 RD/RA Work Plan activities. Following this Kick-off meeting field investigations for OU3 were initiated on October-?, 1996. Field investigations included taking of rock cores; installation of Extraction Wells; development and packer testing of Extraction Wells; step-drawdown tests of Extraction Wells; sampling of groundwater, surface water and sediment; field survey; preparation of summary reports of field investigations and Pilot Testing of Air Stripping. ' ' C:IPROJECTSISLSBRY,QU3'0U3CNDES.SV 6 I I I I I I I I I I I I 1.4 Summary of Site Characteristics The RI and FS Reports for the OU3 were completed during June, 1993. The overall nature and extent of comntamination associated with OU3 is based on analytical results of environmental samples collected from surface and subsurface soils, the groundwater, the surface water and sediment of the Northeast Tributary, and the physical/chemical and geological/hydrogeological characteristics of the area. VOCs, SVOCs, one pesticide, and several inorganic analytes were detected in the soils and groundwater at OU3. Two VOCs and several metals were detected in the surface water/sediment samples. Table 1-1 lists the contaminants detected in each environmental medium sampled during the conduct of the RI in 1993 as well as the contaminants detected in each environmental medium sampled during the field investigations and installation of Extraction Wells for the RD/RA of OU3 in 1996-97. The frequency and range of concentrations detected are also presented in this table. 1. 5 Conceptual Design Report Contents This Conceptual Design and Preliminary Design Report for OU3 consists of the following: 1. Results of additional field investigations conducted during the RD/RA of OU3 including (a) Drilling and Installation of Monitoring and Extraction Wells in the saprolite and bedrock aquifers, (b) Packer Testing of Bedrock Wells to delineate depths of vertical contamination of bedrock aquifer, (c) Step- Drawdown Tests of the Extraction Wells installed for OU3, (d) sampling of groundwater from the Monitoring and Extraction Wells located at OU3, (e) Pilot Testing of the Diffused Air Stripping Treatment System, (f) sampling of surface water and sediment in the Northeast Tributary, and (g) laboratory analysis of.groundwater, surface water and sediment samples: 2. Details of Remedial Design including (a) Design Basis; (b) Sizing of Pipes, Storage Tanks and Delivery Systems: (c) Conceptual Design of the ~ Groundwater Pretreatment System; and (g) Process Flow Schematics for the Groundwater Extraction and Pretreatment System; and 3. Preliminary Design Drawings of the Groundwater Extraction and Pretreatment System. I C:IPROJECTS'SLSBRYOU3'0UJC:-,JDES.SV 7 I I I I I I I I I I I I I I Table 1-1 Range and Frequency of Detection of Organic Contaminants and Inorganic Constituents Phase I and II OU3 RI and Field Investigation of OU3 RD/RA Comp~und Volatile Organic Compounds Acetone Bromodichloromethane 2-Butanone Carbon Disulfide Chloroethane Chloroform Dibromochloromethane 1,2-Dichloroethane 1, 1-Dichloroethene 1,2-Dichloroethene 1,2-Dichloropropane Ethyl benzene Methylene Chloride I Tetrachloroethene Toluene 1, 1,2-Trichloroethane Trichloroethene Total Xylenes Vinyl Chloride Groundwater from RI 9-4,200 (15) 4-8 (3) 3-35 (6) 7-8,900 (2) 1-660,000 (30) 1-14 (3) 1-200 (4) 5 9-36 (2) 1-160 (5) 107(4) 1-120(3) 1-5 (10) 2-90 (4) 1-120 (8) Groundwater from RD/RA 4-2000 J (9) 130-260,000 (I 0) 2-3000 1 (8) Concentrations for wa,ter samples are reported in micrgrams per liter (ug/1) or in parts per billion (ppb.) : Number appearing in parenthesis is the frequency of detection. The reported values fdr Groundwater RD/RA are only from the ten new extraction wells. I I I C:\PROJECTSISLSBRY'OU310U3C.NDES.SV 8 I I I I I I I I I I D D I I I I Table 1-1 (Continued) Range and Frequency of Detection of Organic Contaminants and Inorganic Constituents Phase I and II OU3 RI and Field Investigation of0U3 RD/RA Compound Groundwater from RI Semi-Volatile Organic Compounds Bis(2-chloroethyl) ether Bis(2-ethylhexyl)phthalate Di-n-butyl Phthalate 2-Methyl Phenol N-Nitrosodiphenyllamine Pesticide Delta-Hexachlorocyclohexane 13-32 (2) 8 2-17(3) 0.16 Groundwater from RD/RA 3-16 (7) 2 J (l) 2 J (1) NA Concentrations for water samples are reported in micrgrams per liter (ug/1) or in parts per billion (ppb.) Number appearing in parenthesis is the frequency of detection. The reported values for Groundwater RD/RA are only from the ten new extraction wells. ' C:IPROJECTSISLSBRY•OU310U3CNDES.SV 9 I I I I I I I I I I I I I I I I Table 1-1 (Continued) Range and Frequency of Detection of Organic Contaminants and Inorganic Constituents Phase I and II OU3 RI and Field Investigation of OU3 RD/RA Compound Inorganic Constituents Antimony Arsenic Barium Beryllium Chromium Cobalt Copper Cyanide Lead Manganese Nickel Thallium Vanadium Zinc Groundwater from RI Groundwater from RD/RA 2-30 (3) 2.4 28.2-737 (8) 1-2.5 (2) 12.9-59.6 (6) 47-66.4 (2) 12.4-23.7 (2) 12-16(2) 3.3-3.9 (2) 1.5-12,000,000 (14) 23.4-39.6 (3) 1-3 (2) 10.7-272 (II) 22-6,410,000 (4) 20-55.4 (10) 10.1-46.4 (6) 4.6-17.6 (9) tbd 59.60-3290 (10) 6.10-16.20 (9) 9.9-746 (10) Concer.trations for water samples are reported in micrgrams per liter (ug/1) or in parts per billion (ppb.) Number appearing in parenthesis is the frequency of detection. The reported values·for Groundwater RD/RA are only from the ten new extraction wells. I C:IPROJECTS\SLSBRY10U3'·0U3CNDES.SV 10 ! I I I I I I I I I I I I I I I I I I I 2.0 GROUNDWATER EXTRACTION SYSTEM 2.1 Installation of Extraction Wells The Groundwater Extraction System consists of five (5) Saprolite Extraction Wells (NS-45, NS-47, NS-49, NS-51, and NS-53) and five (5) Bedrock Extraction Wells (NS-46, NS-48, NS- 50, NS-52 and NS~54). Two of the five Saprolite Extraction Wells (NS-45 and NS-47) were drilled and installed in Area 2 of the Plant and the other three Saprolite Extraction Wells (NS-49, NS-51 and NS-53) were drilled and installed in the Lagoon Area. Two of the five Bedrock Extraction Wells (NS-46 and NS-48) were drilled and installed in Area 2 of the Plant and the other three Bedrock Extraction Wells (NS-50, NS-52 and NS-54) were drilled and installed in the Lagoon Area. Figure 2-1 illustrates the locations of these Saprolite and Bedrock Extraction Wells. Table 2-1 summarizes the pertinent well construcion data and other information for these Extraction Wells. Details of drilling and installation of these Extraction Wells were provided in the OU3 RD/RA Field Investigations Summary Report. 2.2 Step-Drawdown Pump Tests Following installation of the ten Extraction Wells. Step-Drawdown Tests were conducted in each of the Saprolite and Bedrock Extraction Wells to determine (a) Radii of lnflunce of each well at various pumping rates, (b) Specific Capacities of the Extraction Wells, (c) Maximum Allowable Pumping Rates (to assure sufficient depth of submergence of the pump at all times without causing excessive drawdown) from each well, and (d) Design Pumping Rates for each of the ten Extraction Wells to assure effective control and removal of the Groundwater Contaminant Plume. Details of the Step-Drawdown Tests and procedures used during the Field Investigations were provided in the OU3 RD/RA Field Investigations Summary ' Report. Table 2-2 summarizes the results of the Step-Drawdown Tests for the ten Extraction Wells. 2.3 Packer Testing of Bedrock Wells The bedrock extraction wells in Area 2 of the Plant and in the Lagoon area were drilled to depths ranging from 200.4 feet to 201.3 feet below the ground surface. Following drilling of the five bedrock £~traction Wells, Packer Tests were conducted in the borehole of each bedrock Extraction' Well. ' The primary objectives of the Packer Tests were to (a) determine the depth or depths of the bedrock aquifer from which contaminated groundwater is to be extracted. (b) the vertical I C: \ PR OJE CTSI SL SB R 'f\ OU3 '· QU3CND ES. S V 11 r~--------------------------------~7 I I I I I I I I I I I I I I I I I L N. C. GRID NORTH (NAO 83) _J • J ,...--._ X 0 O::'. . 0.... 0.... <{ ..__,, w z _j >-I- O::'. w 0.... 0 O::'. 0.... 0 100 200 JOO 600 FEET {iif;atlonal Starch and Chem;ca/ Company LOCATIONS OF OU3 EXTRACTION WELLS SALISBURY, NC PLANT t.tARCH 1997 FIGURE 2-1 _J I I Table 2-1 I Cedar Springs Road Plant Site, Salisbury, North Carolina Operable Unit 3 Extraction Well Construction Data I Well No. Installation Location Diameter Total Depth Screen Interval Casing Interval I Zone Inches ft. ft. ft. I NS-45 Saprolite Area 2 6.00 55.00 -12.7 to -52.7 +3.0 to -12.7 I NS-46 Bedrock Area 2 5.875 200.40 Open Borehole +2.75 to -11.7 No Screen I NS-47 Saprolite Area 2 6.00 50.00 -11.7 to -41.7 +2.75to-11.7 I NS-48 Bedrock Area 2 5.875 201.30 Open Borehole +2.33 to -49.3 No Screen I NS-49 Saprolite Lagoon 6.00 115.50 -44.5 to -113.6 +2.58 to -44.5 I NS-50 Bedrock Lagoon 5.875 200.40 Open Borehole +1.0 to-134.0 No Screen I NS-51 Saprolite Lagoon 6.00 117.60 -43.5 to -112.5 +2.41 to -43.5 I NS-52 Bedrock Lagoon 9.875 200.40 Open Borehole +2.25 to -126.0 No Screen I NS-53 Saprolite . Lagoon 6.00 117.00 -45.0 to -115.0 +2.75 to -45.0 I NS-54 Bedrock Lagoon 9.875 201.00 Open Borehole + 2.33 to -120.0 I No Screen I I C:\PROJECTSISLSARY'·OUJ'OU3CNDES.SV 13 I I I I I I I I I I I I I I I I I I I I Well No. NS-45 NS-46 NS-47 NS-48 NS-49 NS-50 NS-51 NS-52 NS-53 NS-54 Table 2-2 Cedar Springs Road Plant Site, Salisbury, North Carolina Operable Unit 3 Results of Step-Drawdown Tests of Extraction Wells Zone Max. Pumping Rate During Test, gpm Saprolite 2.0 Bed Rock 8.0 Saprolite 2.0 Bed Rock 11.0 Saprolite 40.0 Bed Rock 40.0 Saprolite 30.0 Bed Rock 30.0 Saprolite 40.0 Bed Rock 30.0 Drawdown Depth to at Maximum Pump Pumping, ft. Intake, ft. 44.00 54.45 168.78 188.00 12.36 40 55 95.36 187.00 35.96 107.12 153.17 186.12 97.55 107.22 165 .82 186.12 26.73 107.22 148.85 174.12 Specific Capacity, gpm/ft 0.045 0. 162 0.115 1.120 0.261 0.180 1.496 0.201 Allowable Pumping Rate, gpm 2.00 6.00 2.00 14.00 60.00 40.00 25.00 25.00 60.00 30.00 C:1PROJECTS\SLSBRYOU310U3CNDES.SV 14 Design Pumping Rate, gpm 2.00 6.00 2.00 14.00 15.00 5.00 10.00 5.00 20.00 5.00 I I I I I I I I I I I I I I I I I I I extent of the groundwater contamination in the bedrock aquifer, and (c) the permeability and transmissivity of the various water producing zones in the bedrock aquifer. Two inflatable rubber packers were used to isolate the selected test zone in the bedrock aquifer with a 3-inch submersible pump placed in between the two packers. All equipment used in the Packer Tests were steam cleaned prior to initiating work at each bedrock well. The rubber packers were lowered to the desired depths in the bore hole and then inflated with nitrogen gas supplied from a ground level pressurized tank. Once inflated, the inflated packers isolated the borehole into three separate zones. Pressures in each zone were monitored during the Packer Tests using pressure transducers and was recorded on a computer. Prior to initiating the Packer Tests a slug of water was introduced into the isolated section of the borehole to determine whether or not that section of the bedrock is fractured and the rate of exfiltration of the water slug into the bedrock. After the slug of water exfiltrated into the bedrock, the submersible pump was turned on to pump water from the bedrock section in between the packers while recording the pressure changes in the three zones. Normally, after pumping three volumes of water from within the isolated zone a sample of groundwater was collected for laboratory analysis. In some sections of the boreholes where the bedrock is less fractured, the exfiltration of the slug of water took considerable time. In these sections the recharge of water and recovery of pressure after completion of only one volume of pumping was extremely slow. In these instances, only one volume of water was extracted from the isolated zone before the groundwater sample was collected. In sections of the borehole where there was little or no ex filtration and infiltration, groundwater samples were not collected. However, in all cases groundwater samples were collected from the lowest section of the borehole to determine whether or not groundwater contamination reached this level of the bedrock. Samples fJf extracted groundwater was collected for analysis of VOCs, SVOCs, and TCL metals. After completion of the Packer Tests of the selected zone of the bore hole representing a portion of the bedrock aquifer, the rubber packers were deflated and the whole pack was then lowered to a different zone for another set of tests. This process was continued until the entire borehole is tested. In some of the zones, because of lack of inflow, Packer Testing could not be conducted. Results of the Packer Tests were presented and discussed in the OU3 RD/RA Field Investigations Swnmary Report. 2.4 Surveying of Site and Wells Following completion of the Extraction Wells. a field survey of all wells located in the Plant Area and in the Lagoon Area was conducted to develop a detailed site map of the existing facilities and wells. The survey was carried out to establish accurate horrizontal locations of C:\l'ROJECTS1SLSBRY10U310U3CNDES.SV 15 I I I I I I I I I I I I I I I I I I I wells and other facilities, and vertical elevations of the well rims and ground surface within the surveyed area. Elevations of the rims of all Extraction Wells were then used to determine the relative elevations of the water levels in all wells under different pumping rates in each well. Field survey of the area next to the existing Trench Area Treatment Building, where the new OU3 Groundwater Remediation Treatment System will be built, was also conducted to establish ground contours and elevations for the detailed design. A map of the field survey is included in the back pocket of this report. 2.5 Sampling of Groundwater from Saprolite and Bedrock Wells Sampling of groundwater from the ten (10) newly installed saprolite and bedrock wells was carried out during the conduct of the Packer Tests and after completion of the Step-Drawdown Tests. As required in the OU3 ROD, sampling of eight (8) existing saprolite wells (NS-13, NS-14, NS-33, NS-35, NS-37, NS-39, NS-42 and NS-43) and six (6) bedrock Monitoring Wells (NS-34, NS-36, NS-38, NS-40, NS-41, and NS-44) installed during the Remedial Investigations for OU3 was also conducted durin)! the sampling of the newly installed Extraction Wells. The initial sampling of these Extraction Wells and Monitoring Wells during Packer Testing was carried out to establish the existing contamination baseline. Figure 2-2 illustrate the locations of all saprolite Extraction and Monitoring Wells. Figure 2-3 Illustrates all bedrock Extraction and Monitoring Wells. Results of the groundwater sampling and analysis are presented and discussed in detail in the OU3 RD/RA Field Investigations Summary Report. 2.6 Pilot Testing of Diffused Air Stripping Treatment System Pilot Testing of the Diffused Air Stripping Treatment System was conducted after install ion of the Saprolite and Bedrock Extraction Wells. Contaminated groundwater from the Extraction Wells was first pumped into a 300 gallons Air Stripping Reactor. Figure 2-4 illustrates the schematic of the Air Stripping Treatment System used for removing the Volatile Organic Co111pounds from the contaminated groundwater. The Air Stripping Reactor was fitted at the bottom with a fine bubble diffuser system consisting of four Ceramic Disks. Air was supplied from the Plant-Air Supply to the bottom of the Ceramic Disks. The supplied air was discharged as bubbles through the pores of the Ceramic Disks. This created a system of very fine air bubbles. These fine air bubbles diffused through the contaminated water column in the Reactor. Samples of contaminatt;d groundwater were collected for laboratory analysis. After filling the Reactor with contaminated groundwater. air was supplied to the Reactor at a constant rate for twelve hours. Water samples were collected from the Reactor for laboratory analysis after operation of the Reactor for 3 hours, 6 hours, 9 hours aand 12 hours. Altogether, eight (A C:\PROJECTS1SLSBRY'OU3'0U3CNDES.S\' 16 I I I I I I I I I I I I I I I I I I I through H) separate Air Stripping tests were conducted. The rate of air flow into the Reactor during these tests was varied from 8 scfm (0.65 scfm/sq. ft.) to 20 scfm (1.63 scfm/sq. ft.) to determine the most effective aeration rate. Tables 2-3, 2-4, 2-5 and 2-6 present the results of Air Stripping tests B, C, D, E, F, G, and Hof the Diffused Air Stripping System and its effectiveness. Results from Test A are not available because the Analytical Laboratory lost the samples. As seen from the data in these tables, the efficiency of the Air Stripping System increased with increased air supply to the Reactor. Concentrations of all Volatile Organic Compounds were below their respective detection limits after 12 hours of aeration. At the air flow rate of 1.63 scfm/sq. ft.. the effectiveness of the Air Stripping System was better than 99 percent. The Pilot Testing of the Air Stripping Treatment System was conducted during the Winter month ( January ) when the water temperture was very low. This reduced the removal efficincy of the Air Stripping Treatment System as well as increased stripping time in the Reactor. In the Final Design of the prototype Air Stripping Treatment System a Thermal Oxidizer will be used to destruct the VOCs and SVOCs contained in the exhaust air from the Air Stripping Reactors. The Thermal Oxidizer will be operated at 1400 degrees Ferheneit to destroy the VOCs and SVOCs in the exhaust air fr')m the Reactors. The heat in the exhaust air from the Thermal Oxidizer will be recovered by using a Heat Exchanger. This recovered heat will be used to heat the contaminated groundwater in the Reactors. It is estimated that heating the contaminated groundwater by using recovered heat from the Thermal Oxidizer will significantly increase the efficiency of the Air Stripping and reduce both the air flow rate and the aeration time in the Reactor. With use of recovered heat from the Theremal Oxidizer six to nine hours of aeration should be sufficient to reduce the concentation of VOCs and SVOCs in the groundwater to below detection level. During start-up of the Groundwater Remediation Treatment System further tests will be conducted with recovered heat from the Thermal Oxidizer to confirm this and to determine the most effective air flow rate and duration of aeration. C:\PROJECTSISLSBRY·OUJ'OIJJCNOES.SV 17 ~i-----------------------------------,7 I I I I I I I I I I I I I I I I N. C. GRID NORTI-i (NAO BJ) NS-J7 0 \ • NS--43 0 NS-47 NS-JJ 0 ,,--... X 0 0::: Q_ Q_ <t: '-../ w z _J >-f- 0::: w Q_ 0 0::: Q_ 0 100 200 JOO 600 F'EET I LOCATIONS OF SAPROLITE EXTRACTION AND MONITORING WELLS [BMfonal Storch and Ch•mfoo/ Company ~'----------------------:----------::::.... ______________________ L ___ s_A_L_1s_s_u_R_Y_:,_N_:_c_PL:::_A ___ N_T~--_JL_~M~AR~c:'.'."...:'~•9~1 __ j_ _ __'.:Fr~cu~R~E~2-:__:2~_J_J r~-----------------------,---------------------,7 I I I I I I I I I I I I I I I I I N. C. GRID NORTli (NAO BJ) NS-J7 0 \ • NS-4J 0 NS-47 ---\ \ \ -. J NS-JJ 0 ,,--.., X 0 0::: o_ o_ <t: ..___, w z __J >--\-- 0::: w o_ 0 0::: o_ 0 100 200 JOO 600 FEET {R;_atlonal Starch and Chom;ca/ Company LOCATIONS OF BEDROCK EXTRACTION AND MONITORING WELLS ~L-------------------------------.:::_ ______________________ L ___ s_A_L_1s_s_u_R_Y.:_·_N_c_P.::_LA_N __ T ___ _L_~M~A~Rc::"~'~ss~1'--_l-~F~1G~uR!:!E:_22-:::3~-J_J -- - - - - - - - - --- --- - -11!!!!!1 ,--------------------------------~7 SUPPLIED GROUNDWATER BLOWER /H;atlonal Starch and Chemical Company SALISBURY, NC PLANT EXHAUST AIR DIFFUSED AERATION TANK FINE BUBBLE DIFFUSED AIR STRIPPING SYSTEM TREATED GROUNDWATER PUMP SCHEMA TIC OF PILOT AIR STRIPPING TREATMENT SYSTEM MARCH 1997 FIGURE 2-4 [_~ ___________________ __j_ ___ ___:.__ _ __1_~:::.::.:..::=--=---=-__J_J ------------------- Table 2-3 Results of Pilot Test Trials Band C Salisbury Plant Groundwater Remediation System -Operable Unit 3 Trial (flowrate) Trial B (8 scfm) Sample ID B-1 B-2 B-3 Sample Interval (hr.) 0 3 6 Parameter ( ug/1) Methylene Chloride 2000 JB 300 JB 30 D Acetone 10000 u 600 JB 50 1,2-dichloroethane 91000 D 11000 1400 Total Concentration(ug/1) 103000 11900 1480 Percent Removal 88.45 98.56 Notes: 2000 J = Reported value is an estimate 2000 B = The paramter was also detected in the method blank I 0000 U = The value is less than the detection limit. C:\l'ROJECTSISI.SBR Y\( )U3\()IJ3CNDES.SV JB JB Trail C (8 scfm) B-4 C-1 C-2 C-3 9 0 3 6 8 JB 6000 JB 900 JB 300 D D 10 JB 4000 JB 2000 JB 500 D D 220 D 210000 D 43000 10000 238 220000 45900 10800 99.77 79.14 95.09 21 C-4 9 JB 60 JB JB 280 B 3300 3640 98.35 ------------------- Table 2-4 Results of Pilot Test Trials D and E Salisbury Plant Groundwater Remediation System -Operable Unit 3 1 n?n1n41n.:o Trial (flowrate) Trial D (12 scfml Sample ID D-1 D-2 D-3 Sample Interval (hr.) 0 3 6 Parameter ( ug/1) Methylene Chloride 2000 JB 40 JB 2 Acetone 2500 u 20 JB 9 1,2-dichloroethane 36000 I 100 78 Total Concentration(ug/1) 40500 1160 89 Percent Removal 97.14 99.78 Notes: 2000 J = Reported value is an estimate 2000 B = The paramtcr was also detected in the method blank I 0000 U = The value is less than the detection limit. C:\PROJHTS\SI.SBR YI.( IUJ\OUJCNDES.S V Trail E /12 scfm) D-4 E-1 E-2 E-3 9 0 3 6 JB 2 JB 1000 JB 300 J 30 D JB 6 JB 1000 JB 200 JB 40 D 9 J 90000 ED 8800 790 17 92000 9300 860 99.96 89.89 99.07 22 E-4 9 J 3 J JB 8 JB 91 102 99.89 ---- - - - - - - - ---- - - -- Table 2-5 Results of Pilot Test Trials F and G Salisbury Plant Groundwater Remediation System -Operable Unit 3 n,n1n,1m.:o Trial (flowrate) Trial F (I 6 scfm) Sample ID F-1 F-2 r, . -., Sample Interval (hr.) 0 3 6 Parameter ( ug/1) Methylene Chloride 1400 J lJ Acetone u 48 DJ 17 B 1,2-dichloroethane 67000 2000 30 Total Concentration(ug/1) 68400 2048 47 Percent Removal 97.01 99.93 Notes: 2000 J = Reported value is an estimate 2000 B = The paramter was also detected in the method blank I 0000 U = The value is less than the detection limit. C:\l'ROJHTS\SLSBR Y\< >UJI( HJ3CNDES.SV Trail G (I 6 scfm) F-4 G-1 G-2 G-3 9 0 3 6 u 3 J 3100 J u B 27 B 2800 JB 63 DJ 10 B 2 120000 3400 51 32 125900 3463 61 99.95 97.25 99.95 23 G-4 9 lJ 3 J JB 10 JB , J .) 16 99.99 ------------------- Table 2-6 Results of Pilot Test Trials Hand I Salisbury Plant Groundwater Remediation System -Operable Unit 3 1 n?n1n,1n1,:o Trial (flowrate) Trial H 120 scfm) Sample ID H-1 H-2 H-3 Sample Interval (hr.) 0 ' 6 j Parameter ( ug/1) Methylene Chloride u u Acetone 970 JB u 84 DB 12 1,2-dichloroethane 61000 510 D 6 Total Concentration(ug/1) 61000 594 18 Percent Removal 99.03 99.97 Notes: 2000 J = Reported value is an estimate 2000 B = The paramter was also detected in the method blank I 0000 U = The value is less than the detection limit. C:\l'RI >JECTS\Sl.Sl!R YIOl JJIOUJCNDES.S V Trail I /20 scfm) H-4 1-1 1-2 1-3 9 0 3 6 u u u u B 13 B 1300 JB 83 B 76 J u 140000 1400 E 76 13 141300 1483 152 99.98 98.95 99.89 24 1-4 9 u u B 66 B u 66 99.95 I I I I I I I I I I I I I I I I I I I 3.0 REMEDIAL DESIGN 3. 1 Design Basis As mentioned in Section 2.0 of this Conceptual Design and Preliminary Design Report Groundwater will be extracted from five saprolite Extraction Wells (NS-45, NS-47, NS-49, NS-51, and NS-53) and five bedrock Extraction Wells (NS-46, NS-48, NS-50, NS-52 and NS-54). Four of these Extraction Wells ( NS-45, NS-46, NS-47, and NS-48) are located in Area 2 of the Plant and the remaining six Extraction Wells ( NS-49, NS-50, NS-51, NS-52, NS-53, and NS-54) are located in the Lagoon Area of the Plant. The design pumping rates for each of these Extraction Wells are as follows: ----------------------------------------------------------------------------·--- OU3 Extraction Wells Design Pumping Rate, gpm --------------------------------------------------------------------- NS-45 NS-46 NS-47 NS-48 NS-49 NS-50 NS-51 NS-52 NS-53 NS-54 2 6 2 14 15 5 10 5 20 5 -------------------------------------------- Total 84 ------------------------------------------ A total of about 120,000 gallons of contaminated groundwater will be pumped from these ten newly installed saprolite and bedrock Extraction Wells for OU3. At this rate of pumping the groundwater extraction system is expected to have an area vf i1~•Junce covering the contaminated groundwater plume. Based on the results of sampling and analysis of groundwater from these Extraction Wells conducted during the Packer Tests and Step-Drawdown Tests, the quality characterists of the groundwater have been established for use as the design criteria. These groundwater quality characteristics and estimated effluent characteristics from the Pretreatment System are presented in table 3-1. C:\PROJECTS1SLSBRY10U3'0U3CNDES.SV 25 I I I I I I I I I I I I I I I I I I Table 3-1 Cedar Springs Road Plant Site, Salisbury, North Carolina Operable Unit 3 · Influent and Effluent Characteristics for Pretreatment System Parameters Influent Concentrations, ppb Effluent Concentrations, ppb I. Volatile Organics Acetone 2,000 < 10 1,2-Dichloroethane 260,000 < 10 Methylene Chloride 3,000 < 10 Chloroethane* 40 < 10 Chloroform* 9,000 < 10 1, 1-Dichloroethene* 20 < 10 1,2-Dichloroethene* 200 < 10 Ethyl Benzene* 40 < 10 Tetrachloroethene* 120 < 10 Tolune* 120 < 10 Total Xylenes* 100 < 10 Vinyl Chloride* 120 < 10 II. Semi-Volatile Organics Bis(2-chloroethyl) ether 50 < 10 Di-n-Butyl Phthalate 20 < 10 III. Metals Chromium* 60 60 Copper 25 25 Lead* 3 3 Nickel* 40 40 .. Zinc 1,000 < 100 Manganese 3.500 < 100 * These VOCs and metals were detected in groundwater samples collected and analysed during the OU3 RI but were not detected in the groundwater samples collectecd during the Packer Tests and Step-Drawdown Tests. C:\PROJECTSISLSBRY'·OU310U3CNDES.SV 26 I I I I I I I I I I I I I I I I I I 3.2 Existing Trench Area Pretreatment System Difficulties The existing Trtench Area Pretreatment System designed by the IT Corporation has some defficiencies and causes operating problems for the operators. The Metals Removal System produces hazardous sludge and solids. Some of these sludge and solids accumulate in the Packed Tower used for stripping the VOCs. As a result the packing in the Packed Tower gets clogged and require periodic removal and cleaning. This operation involving removal, cleaning and recharging of the packing is hazardous to the operators. 3.3 Proposed Pretreatment System for OU3 and Trench Area Groundwater To eliminate the undesirable and hazardous operations at the existing Trench Area Pretreatment System, National Starch and Chemic;\! Company proposes to treat the contaminated groundwater from the Trench Area together with the contaminated groundwater from OU3. In this new Pretreatment System all contaminated groundwater will be treated by using a new Diffused Air Stripping System. The Trench Area groundwater, which is more contaminated than the groundwater in OU3, will be treated in a separate Diffused Air Stripping Tank to assure complete removal of all VOCs and SVOCs present in the Trench Area groundwater. The groundwater from the OU3 will be treated in three other Diffused Air Stripping Tanks. All of these Diffused Air Stripping Tanks will be located in a new Pretreatment Building to be located next to the existing Trench Area Pretreatment Building. The groundwater in the four Diffused Air Stripping Tanks will be heated using recovered heat to raise the temperature of the groundwater for more efficient and effective stripping of VOCs and SVOCs The exhaust air from each Diffused Air Stripping Tank will be collected and heated to about 1400 degrees Ferenheit in a Thermal Oxidizer to destroy the VOCs and SVOCs. The VOCs and SVOCs will be converted into harmless gases and compounds. The Thermal Oxidizer will operate on natural gas and will generate considerable amounts of heat to raise the temperature of the exhaust air from the Diffused Air Stripping Tanks. NSCC will use a Heat Exchanger to recover this available heat from the exhaust air. This recovered heat will be used to heat the groundwater in each Diffused Air Stripping Tank. After completion of the air stripping treatment the groundwater will be pumped to the existing Lagoon No. I in the Plant's Combined Pretreatment System. The existing Combined C:IPROJECTS',SLSBRY'OU310U3CNDES.SV 27 I I I I I I I I I I I I I I I I I I I Pretreatment System consists of a Primary Physical/Chemical Coagulation/Flocculation Treatment System followed by a Multi-Cycle Sequencing Batch Reactor (MC-SBR) Biological Treatment System. The Physical/Chemical Treatment Systemwas designed to remove metals and will remove the metals remaining in the groundwater from OU3 and the Trench Area after completion of the Diffused Air Stripping Treatment. The Biological Treatment will remove any remaining dissolved organic contaminants in the groundwater. 3.4 Details of the Proposed Groundwater Pretreatment System The proposed groundwater Pretreatment System for OU3 consists of the following elements: a. Storage of extracted groundwater from Extraction Wells NS-45, NS-46, and NS-47 in a new 2,000 gallons Storage Tank to be located in Area 2 of the Plant; b. Transfer of contaminated groundwater from the new 2,000 gallons Storage Tank in Area 2 of Plant to the existing 19,900 gallons Fiber Glass Storage Tank in the Trench Area Pretreatment System; c. Pumping of contaminated groundwater from Extraction Wells NS-48, NS-49, NS-50, NS-51, NS-52, NS-53, and NS-54 to the existing 19,900 gallons Fiber Glass Storage Tank in the Trench Area Pretreatment System; d. Pumping of contaminated groundwater from the existing Trench Area Sump in the Trench Area Pretreatment Building to the existing 11,300 gallons Sludge Storage Tank in the Trench Area Pretreatment Building; e. Transfer of contaminated groundwater from the existing 19,900 gallons Fiber Glass Storage Tank in the Trench Area Pretreatment System to three new 20, 000 gallons Diffused Air Stripping Tanks for removal of VOCs and SVOCs; f. Transfer of contaminated groundwater from the existing 11,300 gallons Sludge Storage Tank to a new 20,000 gallons Diffused Air Stripping Tank for removal of VOCs and SVOCs; g. Provide air supply to the Diffused Air Stripping Tanks from Aeration Blowers; h. Thermal destruction of VOCs and SVOCs contained in the exhaust air from the four new 20,000 gallons Diffused Air Stripping Tanks by using a Thermal Oxidizer; 1. Recovery of heat from the Thermal Oxidizer by using a Heat Exchanger; J. Use of recovered heat from the Thermal Oxidizer to heat the contaminated groundwater in the four 20,000 gallons Diffused Air Stripping Tanks to increase efficiency of Diffuseed Air Stripping and reduce detention time; k. Recirculation of contaminated groundwater from the Diffused Air Stripping Tanks through the Heat Exchanger to raise the temperature of the contaminated groundwater in the Tanks; and I. Transfer of groundwater (after completion of stripping) from the Diffused Air Stripping Tanks to existing Lagoon No. 1 for further treatment in the existing Combined Pretreatment System at the Salisbury Plant. C:\PROJECTS\SLSBRYIOU310U3CNDES.SV 28 I I I I I I I I I I I I I I I I I I I Figures 3-IA and 3-1B illustrate the Process Flow Diagram of the Proposed Groundwater Pretreatmemnt System for the contaminated groundwater from OU3 and the Trench Area. C:1PROJECTS',SLSBR Y·OU3'0U3C~DES.SV 29 .~. ,-----------------------------~7 I I I I I I I I I I I I I I I I I NS-47 2 CPM NS-46 6 CPM NS-45 1.8 CPM AREA 2 SURGE TANK 2,000 CAL. CONTAINMENT FROM TRENCH AA[A \lltllS NS-48 14 GPM NS-50 5 CPM EXISTING Pl.JMPS NS-51 10 CPM EXISTING TREND-I WATER SUMP NS-52 5 CPM NS-SJ 20 GPM ABO Ll.2. A1.AM. Se.0., P.l. NOltTM CMCl.MA P.[_ NO. OEV. OCSCR!PnON TRENCH WATER EQUALIZATION TANK (EXISTING SLUDGE TANK) 11,JOO GAL OUJ RAW WATER EOUALIZATION TANK (EXISTING HYOR<X.. YSIS TANK) 19,900 GAL / / TRENCH WATER TRANSFER PUMPS EXISTING CONTAINMENT RAW WATER TRANSFER PUMPS EXISTING CONTAINMENT DATE ~r,, SCAI..£: ~ {jj:,tfonal Starch and Chemical Company SALISBURY PLANT OPERABLE UNIT 3 GROUNDWATER REMEDIATION SYSTEM TO AERATION TANK NO. 4 TO AERATION TANKS 1, 2. J PROCESS FLOW DIAGRAM SHEET 1 MARCH 1997 FIGURE 3-lA _J r=---------------------------'---------- 1 I I I I I I I I I I I I I I I FROM TRENCH WATER EOUAUZATION TANK FROM OOJ EOUAUZATlON TANK l D-\ \----0 \-0 •ow A.ERA TlON BLOWERS •OV> MOVlJ AERATION TANK NO. 1 "''s---~------.~------// ~ rnSTINC LAGOON NO. 1 . ~ M0V21 D-\ MOV10 TREATtO WATER TRANsrER PUMPS -I l \----0 \----0 •OV2 MQV14 AERATION TANK NO. 2 l \----0 MOV22 R(OROJLA TION PU•PS D-\ l,IQV11 -I l \----0 \----0 MOVJ M0V15 AERATION TANK NO. 3 REOROJLA TlON LINE l \----0 MOV2J NA TIJRAL CAS \----0 OV>2 MOV4 T MOV16 - AERATION TANK " " TO ATMOSPHERE EXHAUST STACI( HEAT EXCHANGER NO. 4 " " J THERMAL 0XI0IZ£R ', \./ I REV. OESCRIPTlON . DA TE Dl!..i:o r<: fai:J. =~ l Nj:rtlonal Slorch and Cht1mical Company MOV24 " . I-< I-< BOOSTER FAN PROCESS FLOW DIAGRAM SHEET 2 -~ SALISBURY PLANT OPERABLE UNIT 3 ~-------------------------,---------------~'"-"_.!_~_·,_!._"'_.·_. !'_.,_·".;._· _ •. _,.~-~------~--~-"""--"--~~-G_R_o_u_N_D_W_A_T_E_R_R_E_M_E_D_IA_T_1o_N~_s_Y_S_T_E_M_~ ___ M_A_RC_H_l9_9_7 __ ~ ___ F_IG_U_R_E_3_-_1s_~ I I I I I I I I I I I I I I I I I I I 4.0 PRELIMINARY DESIGN 4.1 Preliminary Sizes and Preliminary Equipment List Based on the Design Concept presented in Sections 3.3 and 3.4 of this Conceptual Design and Preliminary Design Report NSCC has conducted Preliminary Design of the Groundwater Pretreatment System for OU3 and the Trench Area. Preliminary sizes and dimensions of the needed equipment for treatment of the contaminated groundwater from OU3 and the Trench Area have been established. Table 4-1 presents the Preliminary Equipment List and their sizes. As seen from the data presented in this table, the total dynamic heads (TDHs) of the pumps have not been determined yet because the layout of the force mains have not been finalized yet. Following approval of the Conceptual Design and Preliminary Design Report by the USEPA and the NCDEHNR, National Starch and Chemical Company will finalize these preliminary sizes and equipment list. All necessary revisions and modifications will be made to assure fulfilment of all regulatory requirements. 4.2 Preliminary Design Drawings Preliminary layouts of the proposed Pretreatment System for contaminated groundwater from OU3 and the Trench Area have been prepared to reflect the Conceptual Design presented and discussed in Section 3 of this Report. The Preliminary Design Drawings (Figures 4-1, 4-2 and 4-3) are included here as a part of the 30 percent design. 4.3 Air Permit Application The proposed Diffused Air Stripping System followed by Thermal Oxidation of the exhaust gases from the Stripping Tanks is expected to destroy all VOCs and SVOCs. The exhaust from the Thermal Oxidizer will contain some harmless non-hazardous gases such as CO,, 0 2, Cl, etc. National Starch and Chemical Company will apply for an air discharge permit from the NCDEHNR following approval of the Conceptual Design and Preliminary Design Report by the USEPA and the NCDEHNR. C:1PROJECTSISLSBRYOU310U3CNDES.SV I I I I I I I I I I I I I I I I I I I l. 2. 3. Table 4-1 Groundwater Remediation System -Operable Unit 3 Preliminary Equipment List Extraction Well Pumps Pump Capacity TQtl!I D):'.namic Head Well No. gp_m fl NS-45 2 To be determined NS-46 6 To be determined NS-47 2 To be determined NS-48 14 To be determined NS-49 15 To be determined NS-50 5 To be determined NS-51 10 To be determined NS-52 5 To be determined NS-53 20 To be determined NS-54 5 To be determined Area 2 Surge Tank (for Wells NS-45. NS-46 and NS-4 7) Number of Units Capacity Dimensions Material 2,000 gallons 7 ft. Diameter x 7'-6" High Polyethylene Area 2 Transfer Pumps A2TP1 & A2TP2 (Area 2 Surge Tank to Raw Water Equalization Tank) Number of Units Type Capacity 2 Centrifugal 100 GPM -TOH to be determined C:IPROJECTS\SLSBRYOU3'0U3CNDES.SV I I I I I I I I I I I I I I I I I I I 4. 5. 6. 7. 8. Table 4-1 (Continued) Groundwater Remediation System -Operable Unit 3 Preliminary Equipment List OU3 Raw Water Equalization Tank (existing Hydrolysis Tank T-1005) Number of Units Capacity Dimensions Material I 19,900 gallons I 3'-0" Dia. x 20'-0" High FRP Trench Water Equalization Tank (existing Sludge Holding Tank T-1007) Number of Units Capacity Dimensions Material 11,300 gallons 12'-6" Dia. x 12'-0" High Epoxy coated carbon steel Raw Water Transfer Pumps RWTPI and RWTP2 (Raw Water Equalization Basin to Aeration Tanks I, 2 and 3) Number of Units Type Capacity 2 Centrifugal 350 GPM -TOH to be determined Trench Water Transfer Pumps TRTPI and TRTP2 (Trench Water Equalization Basin to Aeration Tank 4) Number of Units Type Capacity Aeration Tanks I, 2, 3 and 4 Number of Units Capacity Dimensions Material 2 Centrifugal 350 GPM -TOH to be determined 4 20,000 gallons operating 28'-0" long x 12'-0" wide x IO' high 8' water depth Epoxy primed and painted carbon steel C:1 PROJECTS\SLSBR Y· OU3'0U3CNDES.SV 34 I I I I I I I I I I I I I I I I I I I 9. I 0. 12. 13. 14. Table 4-1 (Continued) Groundwater Remediation System -Operable Unit 3 Preliminary Equipment List Aeration Blowers ABLI, ABL2, ABL3 and ABL4 Number of Units Capacity Accessories 4 500 SCFM at 6 psi Inlet and Discharge Silencers, Inlet Filter Aeration System for four Aeration Tanks Type Number of discs Diameter of discs Fine bubble aeration using ceramic discs 184 per tank (23 x 8) 9" Treated Water Transfer Pumps TWTPI and TWTP2 (Aeration Tanks to Lagoon No. I) Number of Units Type Capacity 2 Centrifugal 350 GPM -TOH to be determined Recirculation Pumps RCP 1 and RCP2 (Aeration Tanks to Heat Exchanger) Number of Units Type Capacity Thermal Oxidizer Number of Units Accessories Heat Exchanger Number of Units Accessories 2 Centrifugal 350 GPM -TOH to be determined Booster Fan, Combustion Air Blower, PLC Control Corrosion Control Assembly C:\PROJECTSISLSBR'(l0lJ310U3CNDES.SV 35 I I I I I I I I I I I I I I I I I I I I 5. I 6. 17. I 8. ;, I 9. Table 4-1 (Continued) Groundwater Remediation System -Operable Unit 3 Preliminary Equipment List 6" Motorized Butterfly Valves MOY!, MOV2, MOV3, MOY4 (influent to Aeration Tanks I, 2, 3 and 4), MOV5, MOV6, MOV7, MOY8 (suction lines from Aeration Tanks I, 2, 3 and 4 to Treated Water Transfer Pumps/Recirculation Pumps) Number of Units Type Size Service 8 Butterfly 6" Water 6" Motorized Butterfly Valves MOV9, MOYI0, MOY! I, MOYl2 (Air supply lines to Aeration Tanks I, 2, 3 and 4) MOYl3, MOYI4, MOVl5 and MOY! 6 (Air exhaust lines from Aertion Tanks I, 2, 3 and 4) Number of Units Type Size Service 8 Butterfly 6" Air 6" Motorized Butterfly Valves MOY I 7, MOY 18, MOY 19, MOY20 (Recirculation Line suction from Aeration Tanks I, 2, 3 and 4), MOY2l, MOY22, MOV23 and MOY24 (Recirculation Line discharge to Aeration Tanks I, 2, 3 and 4). Number of Units Type Size Service 8 Butterfly Valve 6" Water Reactor Tank Level Sensors (one in each Aeration Tank) Number of Units Type Output Material 4 Pressure Transducer type 4-20 mA 17-4 PH stainless steel sensor 304 stainless steel housing Extraction Well Level Sensors Number of Units Type 10 Three electrodes (ground, high level and low level) C:1PROJECTSISLSBRY•OUJ'"OU3CNOES.SV 36 I I I I I I I I I I I I I I I I I I I 20. 21. 22. 23. 24. Table 4-1 (Continued) Groundwater Remediation System -Operable Unit 3 Preliminary Equipment List Number of controller relays 2 (high level and low level) per well Flow Meter FM 1 (Discharge to Lagoon No. I) Number of Units Type Size Indicator Outputs Range ElectroMagnetic Flowmeter 6" Flow in gpm and totalizer in gallons 4-20 mA 0 to 350 gpm Flow Meters for Extraction Wells Number of Units Type 10 Propeller type sensor, analog flow indicator Pressure Switches (Discharge from each Aeration Blower, suction to Thermal Oxidizer) Number of Units Type Operating Range Automatic Sampler Number of Units Type Unit Heaters Number of Units Type Size 5 Low Differential Pressure Switches Single Pole Double Throw 9 to 85" H,O for Blowers, TBD for Thermal Oxidizer Programmable Refrigerated Composite Sampler 4 Electric To be determined 25. Exhaust Fans Number of Units Size C :1 PR OJE CTS\SLSBR Y' OlJJIQtJ3CNDES. S V 2 To be determined 37 •~------~---------------------~7 I I I I I I I I I I I I I I I I I ~ N. C. GRID NORTH (NAO SJ) _J \ / / ------~ NS-47 I I NEW BUILDING---',-------... SEE FIGURE 4-3 I \ \ \ \ I I ,,--... X 0 0::: Q_ Q_ <t: ----✓ w z _J >-f--- 0::: w Q_ 0 0::: Q_ SEE FIGURE 4-2 ' ,, LEGEND: • - - - -• ABOVE GROUND PIPING FROM WELLS NS-45 SCALE: I- 0 100 200 EXTRACTION WELLS 300 600 FEET {H;atlonal Starch and Chem;ca/ Company GROUNDWATER REMEDIATION SYSTEM PRELIMINARY SITE LAYOUT SALISBURY, NC PLANT MARCH 1997 FIGURE 4-1 _J rr---------------:--:--------======--:---=--=-------------'--------~7 I -~~ - I /~ I I I I I I I I I I I I I I I \ NS-: X AREA 2 SURGE TANK--\--' -----NS-45 NEW TREATMENT BUILDING~.----~ SEE FIGURE 4-3 () N. C. GRID NORTH (NAO 83) LEGEND: -.. --ABOVE GROUND PIPING FROM WELLS NS-45 EXTRACTION WELLS {R;atlonal Starch and Chemical Company SCALE: 0 50 100 200 JOO FEET GROUNDWATER REMEDIATION SYSTEM PRELIMINARY SITE LAYOUT ~~---------------~~-------------------------_J ____ sA_L_1s_B_u_RY_._N_c_P_LA_N_T ___ L__'M~A:".'.RC:'.'._H__'..:19'._::97'._ _ _L_'F:.'.':IG'.':_UR~E:....'.4~-~2-_J_J r.----------------------------------------------i7 I I I I I I I I I I I I I I I I I L 11&31 RECIRCULATION PUMP NO. I 0 ' "' N AERATION TANK NO. 1 1Fe11 RECIRCULATION PUMP NO. 2 AERATION TANK NO. 2 AERATION TANK NO. J 11931 TREATED WATER TRANSFER PUMP NO. 1 AERATION TANK NO. 4 1R11 TREATED WATER TRANSFER PUMP NO. 2 TRENCH WA TtR EQUALIZATION TANK 1 ..... 11 TRENCH WATER u::._-=:.Jj ~ANSFER PUMP NO. 1 1~11 TRENCH WATER ucc.......;;;~ ~ANSfER PUMP NO. 2 >-----------------------11·-a·-------------------------1 COSTER FAN D HEAT EXCHANGER AERA TIQN Bl OWERS NO. 1 NO. 2 NO. J NO. 4 J.eU Li.2. ALAM. Sc.0., P.E. -TH CAIIO.JNA P.E. NO. R{V. DESCRIPTIClf( RAW WATER ANSfER PUMP NO. I 11H1 RAW WATER EOUAUZATION TANK r----t---------c----j SCAI..£: l/UI" • 1•-0• {jf;atfonal Sfarch and Ch•mfoaf Campany SALISBURY PLANT OPERABLE UNIT 3 GROUNDWATER REMEDIATION SYSTEM TREATMENT BUILDING PRELIMINARY EQUIPMENT LAYOUT MARCH 1997 FIGURE 4-3 _J i'= "' 0 z 9 "' c., Li z: BAR GRAPH ::i en SCALE: 1 • = 40' ~ rll71 Iii HI m!M¥f¥i4W fiii#iiiAA 871 G -~ 7-¥Pifi4§itiiiW 0 20 40 M 120 Ii!! SITE , 160 TOPOGRAPHIC SURVEY FOR: NATIONAL STARCH & CHEMICAL COMPANY I , I NOlE:. ELEVATIONS BASED ON N.G.V.D. OF 1929 t.10N. "10 JAS 1966 790" -ELEVATION: 789.-452' LOCKE TOWNSHIP - DEED BOOK BOOK OF t.1APS TAX t.1AP SCALE: 1 • ·= 40' ROWAM CO., N.C. PAGE .PAGE PARCEL DAlE: 1-20-97 AIRPORT ROAD ,,,111111,,,, ,,, ,, ,,, -<,\-\ CAflo ,,, •••o~ •••••••• (_IA.',,,. "' ••• ST •• . .,.. ,,,. ~ ~ ··<c,.o' '=~;.-. ..., \ = ,~ 0~ ~ : . . \ ~ :: i L-2667 i i :.:v!r-ct:a:: ~ (1 \-Y-i: .. -1..0/ /f f <:. 1;, ·-.~ SUR-lt·• .::,Q:' •• . ·:!-. ~o .·•········ ... ,<?;; ........ ',A l S l~~ ,, NOlE : THIS t.1AP IS NOT PREPARED FOR RECORDATION~••· H 11,, •••' SURVEY & MAP BY SHULENBURGER SURVEYING CO. 516 N. MAIN ST., SALISBURY, N.C. PHONE 637-9623 • •• j ' '' ,.. ·, j □ • 0 • "' 181 It RW NS-37 • NS-38 Ell NS-01A Ell EX-06 Ell EX-05 Ell EX-07 Ell EX-08 Ell EX-011 Ell EX-10 Ell NS-03 NOTE: ELEVATIONS BASED ON N.G.V.D. OF 19211 MON. •10 JAS 1966 790" -ELEVATION: 789.-152' LEGEND Existing Stone New Cone. Man • Existing Iron New Iron Point Nail Centerline Right-of-Way ------- Ell NS-24 Ell NS-12 Ell NS-45 NS-43 SP-1'-ia,,SP-2 'el......sP-3 ( NS-46 SP-6 NS-36 SP-;~ \ NS-35 NS-47 ' NS-44 B.C.-4 NS-40\ NS-39~ NS-54'--e Ell NS-48 B.C.-1 NS-501 _ ........ NS-49 fNS-51 NS-42li E&NS-13 NS-41 .......:_NS-52 Ell NS-53 SP-7 SP-8 Ell NS-14 ,': )\'r / ::u I □ SP-4 NS-34 ' NS-33 AIRPORT ROAD n' OJ C < z ~ i!: 25 z C ~ c..i z Point Northing Easting Point NS-01A NS-OJ NS-12 NS-13 NS-14 NS-24 NS-33 NS-34 NS-35 NS-36 NS-37 NS-38 NS-39 NS-40 NS-41 NS-42 NS-43 NS-44 NS-45 NS-46 NS-47 NS-48 NS-49 NS-50 NS-51 NS-52 NS-53 NS-54 Point EX-05 EX-06 EX-07 EX-08 EX-09 EX-10 B.C.-1 68777 3. 0806 1544356.4238 B.C.-2 687746.4449 1544300.4484 B.C.-3 687675. 7411 1544164.6780 B.C.-4 687658.2901 1544127.9325 Point Northing Easting SP-1 688038.5712 1543935.6977 SP-2 688030.1817 1543939.7733 SP-3 688020.8312 1543944.1124 SP-4 687994.0875 15-44665.7373 SP-5 688085.4662 1544172.8738 SP-6 688088.4189 1544191.5383 SP-7 687348.4545 15+.298.8776 SP-8 687343.0814 1544285.5106 (Top of Casing) Northing 689016.9080 687754.3168 687389.6391 687406.9616 687201 .3077 688457.9525 887269.0518 687282.8024 688123.6266 888136.6160 689191.1974 689179.4258 687404.1162 687408.3171 687376.6586 687385.9925 688212.5863 666200.4359 688229.2728 688086.4757 688082.5678 687871.3146 687465.0684 687467.6553 687393.2356 687348.0701 687307.9678 687364.1173 Northing 688308. 7427 688362.0564 688316.3405 688100. 7920 687932.6444 6877 34.11650 Eostlng Elevation 1541957.9848 787 02' 1543408.5162 77•UB' 154.1581. 7078 777.36' 15+1449. 7632 762.69' 15H453.2417 765.36' 1543548.9324 758.32' 1544769.7920 776.36' 154-4783.0360 776.27' 1544312.9883 746.11' 1544306.8070 745.59' 1543;169.3651 746.11' 1543372.5748 745.61' 1544177.8866 769.91' 1544,87.5495 769.34' 1544361.9094 766.03' 1544..359.9315 766.16' 1544547.1130 759.38' 1544552. 8889 759.30' 154-4107.5843 754.85' 154-1213.3177 768.99' 154-4217.4011 769.62' 1544305.3300 770.22' 1544326.4230 766.98' 154-4321.9131 766.08' 154-4395.4143 764.98' 154-4377. 7372 764.67' 1544135.1892 770.13' 1544" 82.8757 770.28' (Top of Cosing) Ea•ting 1542'320.1579 1542 379.1826 154 2999. 2846 1543043. 9496 1542857.9606 1542879.8511 Elevation 781.26' 788.28' 789.23' 789.19' 782.29' 775.92' BAR GRAPH • • • • • • • • • • 0 100 200 SCALE: 1 • = 200' 400 600 WELL LOCATION SURVEY FOR: 800 JVATIONAL STARCH cl: CHEMICAL CO. ·, SCALE: 1 • -200' DATE: 1-21-97 LOCKE TOWNSHIP, ROWAN COUNTY, NORTH CAROLINA TAX MAP 471 SURVEY AND MAP BY SHULENBURGER SURVEYING COMPANY MS N. MAIN ST., SALISBURY, N.C. PHONE: (704) 637-9623