NCD991278953_19930409_National Starch & Chemical Corp._FRBCERCLA LTRA_Quarterly Report - First Quarter 1993 OU-1-OCR

D
0
,<
1Kl:GtlVt.U
JUN 15 1993 rn INTERNATIONAL
TECHNOLOGY 0 CORPORATION SUPERFUND SEtTION
D
D
E
E
I
I
•
I
I
I
I
I
I
I
I
I
Quarterly Report
First Quarter 1993
Operable Unit One
National Starch and Chemical Company Site
Cedar Springs Road
Salisbury, North Carolina
Prepared by:
IT Corporation
312 Directors Drive
Knoxville, Tennessee
April 9, 1993
RESPONSIVE TO THE NEEDS OF ENVIRONMENTAL MANAGEMENT
I
I
I
I
I
I
I
I
I
n
D
D
I
I
I
rn INTERNATIONAL TECHNOLOGY
CORPORATION
Ms. Barbara Benoy
Remedial Project Manager
Environmental Protection Agency
345 Courtland Street, N. E.
Atlanta, Georgia 30365
April 9, 1993
IT Project No. 408668.19.10
Quarterly Report. First Quarter 1993. Operable Unit One
National Starch and Chemical Company Site
Salisbury, North Carolina
Dear Barbara:
Enclosed are five bound and one unbound copies of the quarterly report. If you have any
questions, please call me at [phone].
Sincerely,
IT CORPORATION
Michael N. Sturdevant, P. E.
Project Manager
Enclosures
cc: Hank Graulich, NSCC
Alex Samson, NSCC
Ray Parodowski, NSCC
Regional Office
312 Directors Drive• KnoXV1lle. Tennessee 37923 • 615-690-321 l
IT Corporat10n JS a who1/y owned subsidiary of International Technology Corporation
-.
I
I
-I
I
I
I
I
I
I
m
D
0
E
ti
I
I
I
I
Quarterly Report
-First Quarter 1993
Operable Unit One
National Starch and Chemical Company Site
Cedar Springs Road
KN/1004/WPJ004.QR,<>4-<>l-93/FI
Salisbury, North Carolina
Prepared by:
IT Corporation
312 Directors Drive
Knoxville, Tennessee
April 9, 1993
I
I
I
I
I
I ,,
I
I
D
D
n
E
I
I
I
I
Table of Contents ________________ _
Groundwater Monitoring Activities for the First Quarter . . . . . . . . . . . . . . . . . . . . . . . . . I
Activities Planned for Second Quarter I 993 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Appendix A -Certificates of Analysis
List of Tables. _________________ _
Table Title
1 Detectable Concentrations of ROD Contaminants and Selected Water Quality
Parameters in Groundwater, 1992 and First Quarter 1993, Operable Unit One
2 Detectable Concentrations of ROD Contaminants and Selected Water Quality
Parameters in Groundwater, 1992 and First Quarter 1993, Operable Unit One
3 Groundwater Cleanup Criteria, Operable Unit One
4 First Quarter 1993 Water Level Measurements, Operable Unit One
List of Figure..__ _________________ _
Figure Title
Site Map I
2 Water Level Contour Map for Bedrock Water Levels, February 16, 1993
KN/1004/WPI004.QR,,{)4-09-93/FI
I
I
I
I
I
D
m
I
I,
I
I
I
I
Groundwater Monitoring Activities for the First Quarter 1993
Groundwater samples from four downgradient groundwater monitoring wells (NS29, NS30,
NS3!, and NS32) and three of the four extraction wells (EX0I, EX03, and EX04) were
collected on February 17 and I 8, I 993. EX02 was not sampled because the pump was not
functioning. All samples were analyzed for Target Compound List (TCL), volatile and
semivolatile organic compounds (VOCs and SVOCs), and Target Analyte List (TAL) metals.
In addition, samples from the four downgradient monitoring wells were analyzed for total
dissolved solids (TDS) and chloride, and samples from the extraction wells were analyzed for
TDS, chloride, chemical oxygen demand (COD), and total Kjeldahl nitrogen (TKN). These
water quality parameters were analyzed to monitor influent loadings to the Plume Periphery
Pretreatment Systems (PPPS) and to project startup flow rates for the Combined Pretreatment
System (CPS). The TCL and TAL compounds were analyzed under U.S. Environmental
Protection Agency (EPA) Level IV Contract Laboratory Program (CLP) protocol.
Results from the chemical analysis are presented in Tables I and 2. The most recent results
from sampling and analysis during 1992 are provided for reference. The list of compounds
presented in Tables 1 and 2 represent the contaminants specified in the Operable Unit One
Record of Decision (ROD). The list of compounds from the ROD and associated cleanup
levels are provided in Table 3 for reference. Figure 1 is a site map showing the well
locations and Figure 2 is a groundwater contour map. The certificates of analysis are
provided in Appendix A.
The most predominant contaminants are VOCs. Extraction well EX02 contained the highest
levels of VOCs and SVOCs. For the downgradient wells, five VOCs, one SVOC, and one
metal exceeded cleanup levels (shaded values in Table 2). Acetone, 1,2-dichloroethane, 1,2-
dichloropropane, and bis(2-chloroethyl)ether appeared at elevated levels most frequently.
Water level measurements were taken (February 1993) from all four downgradient and several
other selected monitoring wells and all four extraction wells (including EX02). Results are
provided in Table 4.
On February 8, I 993, all extraction well pumps were shut off. Since then, one or more of the
pumps have been on or off to perform maintenance and construction activities on the PPPS
KN/I 004/WPI 004. QR,<>1-08-93/Fl 1
I
I
I
I
I
I
I
I
m
D
fl,
I)
I
I
I,
I
I
I
I
and CPS. The pump in extraction well EX02 stopped functioning during the quarterly
sampling activity. Subsequent investigation determined that the pump motor burned out.
pump motor was replaced and is expected to be back in service by April 12, 1993.
KN/I 004/WPI 004.QR,(14-08-93/FJ 2
The
I
I
I
I
I
I
I
I
m
m
fl
D
E
m
a
I
I
1·
I
Activities Planned for Second Quarter 1993
Groundwater monitoring will continue. The pump and related components from extraction
well EX02 are expected to be operational by April 12, 1993.
KN/I 004/WP I 004.QR,o4-08-93/Fl 3
I
I
I
I
I
I,
I
I
I
I
0
8
D
n
Table 1
Detectable Concentrations of ROD Contaminants and Selected
Water Quality Parameters in Groundwater
Well Number
Sample Date
Volatile Organics (ppbf
Acetone
Benzene
Bromodichloromethane
Chloroform
1,2-Dichloroethane
1, 1-Dichloroethylene
1,2-Dichloropropane
Ethyl benzene
Methylene chloride
Toluene
1, 1,2-Trichloroethane
Trichloroethylene
Vinyl chloride
Xylenes (total)
1992 and First Quarter 1993
Operable Unit One
National Starch and Chemical Company,
Salisbury, North Carolina
(Page 1 of 2)
EX01 EX01 EX02 EX02 EX03 EX03
19928 Feb. 1993b 1992 Feb. 1993 1992 Feb. 1993
NAd 75 NA NSe NA 1300 D
NS
NS
NS
1J' 20 380 D NS 10 23
NS
8 35 320 D NS 29 120
6 NS 1 J
5 2 BJ 8 NS 3J 2 BJ
8 13 120 NS 20 58
NS
NS
NS
NA 2J NA NS NA 10
Semlvolatlle Organics (ppb)
bis(2-Chloroethyl)ether 20 38 350 D NS 80 82
4-Nitrophenol NS
KN!1004/WP1004.T1/04·06•93IF1
EX04
1992
NA
6
20
1 J
2J
7
NA
16
EX04
Feb. 1993
1200 D
2J
4J
2J
5
28
2J
12
D
u
I
I
I
I
I
I
I
D
0
0
ti
Well Number EX01 EX01
Sample Date 19928 Feb. 1993b
Volatile Organics (ppbf
lnorganlcs (ppb)
Arsenic NA
Barium NA 682 B
Beryllium NA
Cadmium
Chromium 12.0
Manganese 96 222
Nickel
Selenium NA
Zinc 39 35.3
Water Quality (ppm)9
TDS 360 508
Chloride NA 82.0
COD NA 73.0
TKN NA 0.3
Table 1
(Page 2 of 2)
EX02 EX02
1992 Feb. 1993
NA NS
NA NS
NA NS
NS
NS
10,900 NS
NS
NA NS
10 NS
2000 NS
NA NS
NA NS
NA NS
EX03
1992
NA
NA
NA
2900
NA
18
830
NA
NA
NA
8 Reference Certificates of Analysis ITEK 52169, 52722, and 52224 for 1992 data.
bReference Certificate of Analysis ITEK 53448 for February 1993 data.
EX03
Feb. 1993
166 B
3950
112 B
884
210.0
239.0
1.8
J.'Pb -parts per billion
NA -not analyzed. All 1992 samples were analyzed for primary pollutants (U.S. EPA Methods
EX04 EX04
1992 Feb. 1993
NA
NA 37.3 B
NA
1800 4290
NA
11 13.0 B
580 1270
NA 130.0
NA 65.0
NA 1.7
624 and 625), which do not include acetone and xylenes. For organics, analysis included only cadmium, chromium,
manganese, nickel, and zinc. For water quality, analysis included only TDS.
8NS -not sampled. EX02 pump not functioning. 1Oualifiers: J -indicates an estimated value less than the detection limit.
B -analyte was found in the blank as well as the sample.
B (inorganics) -Value greater than instrument detection limit, but less than contract required quantitation
limit.
D -compound analyzed at a secondary dilution factor.
9ppm -parts per million
KN/10041WP1 004. T1/04-06-93/F1
I
D Table 2
I Detectable Concentrations of ROD Contaminants and Selected
Water Quality Parameters in Groundwater
1992 and First Quarter 1993
I Operable Unit One
National Starch and Chemical Company,
I
Salisbury, North Carolina
(Page 1 of 2)
I Well Number NS29 NS29 NS30 NS30 NS31 NS31 NS32 NS32
Sample Date 1992" Feb. 1993' 1992 Feb. 1993 1992 Feb. 1993 1992 Feb. 1993
I Volatlle Organics (ppb)'
Acetone 2700 BO 29 B 2900
I Benzene
Bromodichloromethane
I Chloroform
1,2-Dichloroethane
m 1, 1-Dichloroethylene
1,2-Dichloropropane
0 Ethyl benzene
Methylene chloride 2 BJ 3 BJ 3 BJ 3 BJ 2 BJ
Toluene 20 60 34 J 7 34 0 1, 1,2-Trichloroethane
Trichloroethylene
I Vinyl chloride
Xylenes (total) 4J 12 6
I
bis(2-Chloroethyl)ether
I 4-Nitrophenol
lnorganlcs (ppb)
I Arsenic
Barium 85.8 B 182 B 40.3 B 23.4 B 240 193 B 87.5 B 65.8 B
I Beryllium 1.2 B
Cadmium
I Chromium 32.6 11.1 18.4
I KN/1 004/WP 1 004. T2/04-08-93/F 1
I
I
D
u
I
I
I
0
fl
I
I
I
I
I
I
I
I
Well Number NS29 NS29
Sample Date 1992" Feb. 1993'
Volatlle Organics (ppb)'
Manganese 582 475
Nickel
Selenium
Zinc 164 10.3 B
Water Quality (ppm)'
TDS NA' 1020
Chloride NA 84
coo NA NA
TKN NA NA
Table 2
(Page 2 of 2)
NS30 NS30
1992 Feb. 1993
1820 839
87.6 8.2 B
NA 634
NA 22
NA NA
NA NA
NS31
1992
14.9 B
40.5
NA
NA
NA
NA
'Reference Cert~icate of Analysis ITEK 52176, 52177, and 53103 for 1992 data.
'Reference Cert~icate of Analysis ITEK 53438 for February 1993 data.
'ppb -parts per billion.
'ppm -parts per million.
NS31 NS32 NS32
Feb. 1993 1992 Feb. 1993
17.9 143 80.6
39.3 B
27.9 15.8 B 6.4 B
706 NA 207
15 NA 2.0
NA NA NA
NA NA NA
'NA -not analyzed. The 1992 samples were not analyzed tor water quality parameters. The 1993 analysis included only
TDS and chloride.
Qualifiers: J -indicates an estimated value less than the detection limit.
B -analyte was found in the blank as well as the sample.
B (inorganics) -Value greater than instrument detection limit, but less than contract required quantnation
limn.
D -compound analyzed at a secondary dilution factor.
KN/1 004-NJP 1 004. T2/04·08•93IF 1
I
I
g
I
B
D
u
m
m
I
I
I
I
I
I
I
I
Table 3
Groundwater Cleanup Criteria
Operable Unit One
National Starch and Chemical Company,
Salisbury, North carolina
I Compound I Cleanup Concentration (ppb)a
Volatlle Organics
Acetone 3,500
Benzene 5
Bromodichloromethane 5
Chloroform 5
1,2-dichloroethane 5
1, 1 •dichloroethylene 7
1 ,2-dichloropropane 6
Ethyl benzene 3,500
Methylene chloride 5
Toluene 2,000
1 , 1,2-trichloroethane 5
Trichloroethylene 5
Vinyl chloride 2
Xylenes 350
Semlvolatlle Organics
Bis(2-chloroethyl)ether 5
4-Nitrophenol 350
lnorganlcs
Arsenic 10
Barium 1,000
Beryllium 17.5
Cadmium 10
Chromium 50
Manganese 7,700
Nickel 350
Selenium 10
Zinc 7,350
"ppb = parts per billion.
I
Reference source: U.S. Environmental Protection Agency, Enforcement Record of Decision, Remedial
Alternative Selection for Operable Untt One, National Starch and Chemical Corporation Stte, prepared
for U.S. EPA Region IV, Atlanta, Georgia (9·30·88). p. 19.
KN/100<4/WP 1004 .T3/03-30-931DO
I
g
I
0
D
I
u
I
•
I
•
I
I
I
I
I
I
I
I
Well
EX01
EX02
EX03
EX04
NS05
NS06
NS21
NS22
NS23
NS26
NS27
NS28
NS29
NS30
NS31
NS32
P01
Stream Gage 1
Stream Gage 2
Table 4
First Quarter 1993 Water Level Measurements
Operable Unit One
National Starch and Chemical Company,
Salisbury, North Carolina
Reference
Point Depth to
Measurement Point of Elevation Water
Date Reference (ft MSL) (ft MSL)
2/16/93 Toe• 731.85 41.57
2/16/93 TOG 718.24 7.10
2/16/93 TOG 740.46 21.41
2/16/93 TOG 754.12 34.79
2/16/93 TOG 767.96 18.50
2/16/93 TOG 738.87 7.42
2/16/93 TOG 739.13 4.08
2/16/93 TOG 715.94 Dry
2/16/93 TOG 752.36 20.96
2/16/93 TOG 720.77 3.42
2/16/93 TOG 749.47 17.58
2/16/93 TOG 767.82 21.17
2/16/93 TOG 715.50 41.82
2/16/93 TOG 718.54 NA°
2/16/93 TOG 711.15 4.54
2/16/93 TOG 699.48 NA
2/16/93 TOG 708.09 2.33
2/16/93 Iron pin' 693.90 1.75
2/16/93 Iron pin 712.26 1.67
• TOG -Measurement taken from top of inner well casing.
• Measurement taken from top of iron pin next to stream.
c NA -Not applicable, well is artesian.
Water Level
Elevation
(ft MSL)
690.28
711.14
719.05
719.33
749.46
731.45
735.05
NA
731.40
717.35
731.89
746.65
673.68
NA
706.61
NA
705.76
710.59
692.90
' MSL -Mean sea level, National Starch and Chemical Company plant vertical datum
elevation 777.79 feet msl.
KN/1004/WP1004.TB4/04-08-93/F2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
\
z
I
I
I
\
I
I
N
'
\
\
I
/
/
'
/
/
'
\
/
/
\
\
\
\
I
\
+
/
I
I
I
/
I
I
PO 4
®
c:\it\ds\civil\natstar\fig!site.dg Apr. 7. 1993 13:20:59
\
\
\ E11STING ACCESS
,RiJJADS (TYP.)-~
I I I I
I I I I I
I I I I I
I I I I
I '
\
' ' \
\ \
I
I
NS28 ~
I
I
' \
I
I
\
\
\
\
300 0 300 600
r Iii"•· ,t'"""'l@uf ""'rn l#?ffii?li(iilikfiiliHliltn, I iii ii t.l*liti& itidiiii,
150 450
GRAPHIC SCALE: 1 '=300'
'
/
/
I
I
I
,NS10
I
I
I
I
\
\
I
I
I ,,
/ I
/
I I
I
I I
~/ I
I I y I
I
I
I
I I
I
I
I
I LEGEND
I
\
I \ ® \ EXISTING PIEZOMETER
l®>I EXISTING BEDROCK MONITORING
I
I
I
I l@I EXISTING BEDROCK EXTRACTION I
I
I
I
,/1@1
'r
I I
I
I
I / l@I EXISTING SAPROLITE
,' _ MONITORING WELL
(SHALLOW)
I
\ I
I
I
I
J
/ ,,
I
I
I
I
I
/::! ~
\ 0
I
I
I
S03
0
\ .. ~·=-
\
I
I
..
\
[]
I
THIS DRAWING AND ALL INFORMATION FIGURE 1 THEREON IS CONFIDENTIAL AND MUST
NOT BE MADE PUBLIC OR COPIED UNLESS SITE MAC>
DULY AUTHORIZED, SHALL NOT BE USED f"'lr
CHECKED:
APPROVED:
b---~----------------tDRAWING NO:
WELL
WELL
EXCEPT FOR THE PURPOSE FOR WHICH
IT WAS SUPPLIED, N'-JD IS SUBJECT TO
RETURN UPON DEM.AtJD. ALL RIGHTS OF
INVENTION OR DESIGN ARE RESERVED.
REVISION DESCRIPTION FIGURE 1
I
I
I
I
I
:I
I
I
I
I
I
I
I
I
I
I
I
I
\
I
I
\
' I \
I \
I
-------
I
I
' \
I
I
\
'
\
I
I
\
I
/
/
/
\
I
I
\
\
I
I
I
I
I
c:\it\ds\civil\natstar\fig2asit.dg Apr. B. 1993 09:22:18
I
I I I I I I I I I
I
\
\
\
\ \
' \
I
\
I
\ I
I
I
\
\
\
I
/
\
I
I
I
/
/
/
\
\NS09
I
I
I
I
I
I
I I
I I
I I
I
J
I
I
I
LEGEND
\ \ ® EXISTING PIEZOMETER
I : \@)\ EXISTING BEDROCK MONITORING WELL
I
I
I
1 ,' \@\ EXISTING BEDROCK EXTRACTION WELL
I I I
I I
I I
I I
I I I
/ l®>I EXISTING SAPROLITE (SHALLOW)
I I
r-.l~-I I I
/ MONITORING WELL
'.-749.15-WATER SURF ACE ELEVATION I
I ,0
I
\
I
\
I
I
[]
CMSL) AND CONTOUR
NOTES
1. WATER LEVEL FOR NS29
NOT USED IN CONSTRUCTION
OF CONTOURED GROUNDWATER
SURFACE.
-------
/ ..... -------_,,.. ,,,..,,.
I I
I I
I
~====~~====---
2. WATER LEVELS FOR NS30
AND NS32 WERE NOT
MEASURED DUE TO ARTESIAN
CONDITIONS.
I I
\
' --I '----;<--_) \
\ , /
' I \
150
300
''"'
,
/ , ,
/ I / ' / I
600
; •♦'*'* Hiilj
450
GRAPHIC SCALE: l '=300'
m INTERNATIONAL
TECHNOLOGY
CORPORATION
KNOXVILLE, TENNESSEE
THIS DRAWING AND ALL INFORMATION
THEREON IS CONFlDENTI.Al. ANO MUST
NOT BE M.ADE PUBLIC OR COPIED UNLESS
DULY AUTHORIZED, SHALL NOT BE USED
EXCEPT FOR THE PURPOSE FOR WHICH
JT WAS SUPPLIED, AND rs SUBJECT TO
RETURN UPON DEMAND. ALL RIGHTS OF
INVENTION OR DESIGN ARE RESERVED.
ST.ART DATE:
04/06/93
DRAWN:
NATIONAL ST ARCH
AND CHEMICAL COMP ANY
SALISBURY NC P.O. TERRY
FIGURE 2 CHECKED:
WATER LEVEL CONTOUR MAP
FOR BEDROCK WATER LEVELS
1=,.,,,,,.,,,.=.,,;F,,;E:;,B~R:,:..U=.AR:..:.,:Y_1:..:6ct...,;1:.::9:..:9:..:3::._ __ ---, DRAWING NO•
REVISION DESCRIPTION
APPROVED:
FIGURE 2
I
I
I
I
I
I
I
I
I
I Appendix A
I Certificates of Analysis
I
I
I
I
11
I
I
I KNn004/WP!004.QRm-3!-93/DO
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
@ INTERNATIONAL
TECHNOLOGY
CORPORATION
IT Corporation
312 Directors Drive
Knoxville, TN 37923
Attn: Mike Sturdevant
ANALYTICAL
SERVICES
CERTIFICATE OF ANALYSIS
September 14, 1992
Job Number: ITEK 52169 P.O. Number: 408668.09.60
This is the Certificate of Analysis for the following samples:
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
08/27/92
Five (5)
Water
On 08/27/92, five (5) water samples arrived at the ITAS-Knoxville, Tennessee, laboratory from IT
Corporation, Knoxville, Tennessee in support of the National Starch project. The list of analytical tests
performed, as well as date of receipt and analysis, can be found in the attached report.
II. Analytical Results/Methodology
The analytical results for this report are presented by analytical test. Each set of data will include sample
identification information and the analytical results. Please note that the data are not blank corrected.
The samples were analyzed for priority pollutant volatile organic compounds by gas chromatography/ mass
spectroscopy (GC/MS) based on EPA method 624.
The samples were analyzed for priority pollutant semivolatile organic compounds by gas
chromatography/mass spectroscopy (GC/MS) based on EPA method 625.
Reviewed and Approved:
~La ~ Curry ~
Laboratory Systems Manager
Amenr.an Council o! !ndeper.der-11 t....::::boratcr1es
!r.ternatior.al A.ssoc:atior. 01 En·nror.rr.er.tal T➔:.::r.;i-'.coorator1es
Arner:can _A.ssoc:at1cn. tor :...c::bcra:crr Ac::~eaica11on
rr Analytical Services. 5815 Midc1lebrook Pike. Knoxville. TN 37921
IT Corporation
September 14, 1992
Client Project ID: National Starch
m. Quality Control
Routine laboratory level I QC was followed.
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52169
The volatiles analyses were performed by purge and trap with a J&W DB-624 megabore column on a
Finnigan OW A GC/MS/DS. The volatiles analyses went well. Sample EX02082692B required a dilution
to report all analytes within the instrument's calibration range. The same sample had one surrogate outside
the acceptable recovery limits. The dilution surrogate recoveries were within limits.
The semivolatiles analyses were performed on a Finnigan 4500 GC/MS/DS. The semivolatiles analyses
generally went well. EPA method 625 does not have specified limits on surrogate recoveries; however,
based on EPA SOW OLM0l.8 limits, three samples had low acid-extractable surrogate recoveries. This
may indicate that early-eluting acid-extractable compounds did not extract adequately. The base neutral
surrogate recoveries were well within the limits, which indicated the base neutral target compounds did
extract well. Sample EX02082692C required a dilution to report bis(2-chloroethyl)ether within the
calib.ration range. There were no other problems seen in the final review of the data.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
VOLATILE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in /Lg/liter (ppb)
Sample Matrix: Water
Client Sample ID: Method Blank
lab Sample ID: EB083!
Comeound Concentration Comeound
acrolein 10 u l , 1-dichloroethene
acrylonitrile 10 u cis-1,2-dichloroethene
benzene 5 u trans-1,2-dichloroethene
bromodichJoromethane 5 u 1,2-dichloropropane
bromofonn 5 u cis-1,3-dichloropropene
bromomethane 10 u trans-1,3-dichloropropene
carbon tetrachloride 5 u ethyl benzene
chlorobcnzene 5 u methylene chloride
chloroethane 10 u l, 1,2,2-tetrachloroethane
2-chloroethylvinyl ether 10 u tetrachlorocthcne
chloroform 5 u toluene
chlorometbane 10 u 1, 1, !-trichloroethane
dibromochloromethane 5 u l, 1,2-trichloroethane
1, 1-dichloroethane 5 u trichloroctbene
1.2-dichloroethane 5 u trichlorofluoromethane
vinyl chloride
u
]
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Date of Analysis: 08/3 1/92
3
Concentration
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
10 u
VOA-PP.FRM :;;-;9'!
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
VOLATILE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EXO 10826928
Lab Sample ID: TT4533
ComQound
acrolein
acrylonitrile
benzene
bromodichloromethane
bromoform
bromomethane
carbon tetrachloride
chlorobenzene
chloroethane
2-chloroethylvinyl ether
chloroform
chloromethane
di bromochloromethane
I, 1-dichloroethane
1,2-dichloroethane
Results in i,g/liter (ppb)
Sample Matrix: Water
Concentration Compound
JO u l, 1-dichloroethene
JO u cis-1,2-dichloroethene
5 u trans-1,2-dichloroethene
5 u 1.2-dichloropropane
5 u cis-1,3-dichloropropene
JO u trans-1,3-dichloropropene
5 u ethyl benzene
s u methylene chloride
JO u l, 1,2,2-tetrachloroethane
JO u tetrachloroethene
s u toluene
JO u l, l, 1-trichloroethane
5 u l, 1,2-trichloroethane
5 u trichloroethcoe
1 trichlorofluoromethane
vinyl chloride
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Analysis: 08/31/92
4
Concentration
5 u
5 u
s u
8
s u
5 u
5 u
s
5 u
s u
8
s u
s u
s u
s u
10 u
VOA.•PP.FRM :.'7,-¥.:
I
I
I
I
I
I
I
I
I
I
g
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I'
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
VOLATILE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: EX02082692B
Lab Sample ID: TT4534
Comgound Concentration Com~ound
acrolein 10 u l, l -dichloroethene
acrylonitrile 10 u cis-l .2-dichloroethene
benzene 5 u trans-1,2-dichlorocthene
bromodichloromethane 5 u 1,2-dichloropropane
bromofonn 5 u cis-1,3-dichloropropene
bromomethane 10 u trans-1,3-dichloropropene
carbon tetrachloride 5 u ethyl benzene
chlorobenzene 5 u methylene chloride
chlorr"'thane 22 l, l ,2,2-tetrachloroethane
2-chloroethylvinyl ether 10 u tetrachloroethene
chloroform 5 u toluene
chloromethane 10 u 1, l, l -trichloroethane
dibromochloromethane 5 u 1, 1,2-trichloroethane
l, 1-dichloroethane 5 u trichloroethene
1.2-dichloroetbane 380 D trichlorofluoromethane
vinyl chloride
u
J
D
Compound was analyzed for but not detected. The number is tbe detection limit for the sample.
Indicates an estimated value less than the detection limit.
Compound analyzed at a secondary dilution factor.
Concentration
5 u
5 u
5 u
320 D
5 u
5 u
6
8
5 u
5 u
120
5 u
5 u
5 u
5 u
10 u
I Date of Analysis: 08/31/92
I
I
5
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52169
VOLATILE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EX03082692B
La.b Sample ID: TI4535
ComQound
acrolein
acrylooitrile
benzene
bromodichJoromethane
bromoform
bromomethane
carbon tetrachloride
chlorobenzene
ch.Joroethane
2-chloroethylvinyl ether
chloroform
chloromethane
dibromochloromethane
I, 1-dichloroethane
1,2-dichloroethane
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Compound
lO u 1, 1-dichloroethene
lO u cis-1,2-dichloroethene
5 u trans-1,2-dichloroethene
5 u 1,2-dichloropropane
5 u cis-1, 3-dichloropropene
10 u trans-1,3-dichloropropene
5 u ethyl benzene
5 u methylene chloride
7 1 I, 1,2,2-tetrachloroethane
lO u tetrachlorocthcne
5 u toluene
lO u I, I, I-trichloroethane
5 u I, 1,2-trichloroethane
5 u tricbloroethene
lO trichJorofluoromethane
vinyl chloride
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Analysis: 08/31/92
6
Concentration
5 u
5 u
5 u
29
5 u
5 u
1
3 1
5 u
5 u
20
5 u
5 u
5 u
5 u
lO u
VOA-PP.fRM .:.-'T.:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
VOLATILE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µglliter (ppb)
Sample Matrix: Water
Client Sample ID: EX04082692B
Lab Sample ID: TT4536
Com2ound Concentration Com2ound
acrolein IO u I, 1-dichloroetbene
acrylonitrile 10 u cis~ 1,2-dichloroethene
benzene J trans-I , 2-dichlorocthene
bromodichloromethane 5 u 1,2-dichloropropaoe
bromoform 5 u cis-l , 3-dichloropropene
bromomethane 10 u traos-1,3-dichloropropene
carbon tetrachloride 5 u ethyl benzene
chlorobenzene 5 u methylene chloride
chloroethanc 3 J l, l ,2,2-tetrachloroethaoe
2-chloroethylvinyl ether IO u tetrachloroethene
chloroform. 5 u toluene
chloromctbane 10 u I, 1, 1-trichloroetbaoe
dibromochloromctbane 5 u 1, 1,2-trichloroetbaoe
I, 1-dichloroetbaoe 5 u trichloroethene
1,2-dichloroetbaoe 6 trichlorofluorometbane
vinyl chloride
u
J
Compound was analyzed for but not detected. Toe number is the detection limit for the sample.
Indicates ao estimated value less than the detection limit.
Date of Analysis: 08131192
7
Concentration
5 u
5 u
5 u
20
5 u
5 u
J
2 J
5 t_;
5 u
7
5 L
5 l.'
s
5
10
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
VOLATILE ORGANIC PR1OR1TY POLLUTANT ANALYSIS
Results in /Lg/liter (ppb)
Sample Matrix: Water
Client Sample ID: ST082692B
Lab Sample ID: TT4537
Comeound Concentration Compound Concentration
acrolein 10 u 1.1-dichloroethene 5 u
acrylonitrile 10 u cis-1,2-dichloroethene 5 u
benzene 5 u trans-1,2-dichloroethene 5 u
bromodichloromethane 5 u 1,2-dichloropropane 70
bromoform 5 u cis-1,3-dichloropropene 5 u
bromomethane 10 u trans-1,3-dichloropropene 5 u
carbon tetrachloride 5 u ethyl benzene 5 u
chlorobcnzene 5 u methylene chloride 3 J
chloroethane 6 1 I, 1,2,2-tetrachloroethane 5 u
2-chloroethylvinyl ether 10 u tetrachloroethene 5 u
chloroform 5 u toluene 26
chlorometbane 10 u 1, I , I -trichloroethane 5 u
dibromochloromethane 5 u I, 1,2-trichloroetbane 5 u
I , 1-dichloroethane 5 u trichloroethene 5 u
1,2-dichloroethane 59 trichlorotluoromethane 5 u
vinyl chloride 10 u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Analysis: 08/31/92
8 VOA·PP.FRM :,";':,n
I
I
I
I
I
I
I
I
I
I
D
I
n
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
WATER SURROGATE PERCENT RECOVERY SUMMARY
Toluene-D8
Client SamQle ID (88-110%)•
EX0 l082692B 104
EX02082692B 105
EX02082692B DL IOI
EX03082692B 91
EX04082692B 95
ST082692B 94
Method Blank 88
•Values in parentheses represent required QC limits.
.. Values are outside of required QC limits.
DL -Dilution.
9
VOLATILE
BFB 1,2 Dichloroethane-D4
(86-115%)• (76-114%)•
103 96
102 159 ••
96 113
90 93
93 92
95 92
90 89
REC1.:,,.FRM
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EXO I082692C
Lab Sample ID: TT4538
Compound
acenaphthene
acenapbtbylene
anthracene
benzidine
benzo(a)antbracene
benzo(b )fluoranthene
benzo(k)fluoranthene
benzo(a)pyrene
benzo(g,h,i)perylene
butyibenzylphthalate
bis(2-chloroethoxy)methane
bi s(2-c hloroetby I )ether
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
IO u bis(2-chloroisopropyi)ether
IO u bis(2-etbylhexyl)pbthalate
10 u 4-bromopbenyl phenyl ether
so u 2-chloronapbthalene
IO u 4-chlorophenyl phenyl ether
10 u chrysene
IO u dibenz(a,h)antbracene
10 u di-n-butylphthalate
IO u 1,2-dichlorobenzene
2 J 1,3-dichlorobenzene
IO u I , 4-dichlorobenzene
20
u
J
Compound was analyzed for but not detected. Toe number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
IO
Concentration
10 u
10 u
10 u
IO u
IO u
IO u
IO u
IO u
10 u
IO u
IO u
BNE-PP.FRM :.-~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, I 992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52169
BASE/NEUTRAL EX1RACTABLE ORGANJC PRIORITY POLLUTANT ANALYSIS
( continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: EXO I082692C
Lab Sample ID: TT4538
Compound Concentration Compound Concentration
3 ,3' -diclilorobenzidine 20 u hexachloroctbane IO u
diethylphthalate IO u indeno( 1,2,3-cd)pyrene IO u
dimethyl phthalate 10 u isoph9rone IO u
2,4-dinitrotoluene IO u naphthalene IO u
2,6-dinitrotoluene IO u nitrobenzene IO u
di-n-octyl phthalate 10 u n-nitroso-di-n-propylamine IO u
1,2-diphenylhydrazine( 1) IO u n-nitrosodimethylamine 10 u
fluoranthene 10 u n-nitrosodiphenylamine(2) IO u
tluorene IO u phenantbrene IO u
hexachlorobenzcne IO u pyrene IO u
hexachlorobutadiene 10 u 1,2,4-triclilorobenzene 10 u
hexach.lorocyclopentadiene IO u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
(I) Screened for as azobenzene
(2) Detected as diphenylamine
Date of Extraction:
Date of Analysis:
08/27/92
08130192
11 8N'E-PP FRM :. -":'.
IT CoipOration
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
ACID EXTRACTABLE ORGANIC PRIORITY POLLC".°ANT ANALYSIS
Client Sample ID: EX0l082692C
Lab Sample ID: TI4538
Compound
4-chloro-3-methylphenol
2-chloropheool
2,4-dichlorophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Results in 11g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 2-oitrophenol
10 u 4-nitrophenol
10 u peotachlorophenol
10 u phenol
50 u 2,4,6-trichlorophenol
50 u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
12
Concentration
10 u
50 u
50 u
10 u
10 u
ACID-Pl' I •.\I . -~:
I
I
I
I
I
I
I
I
I
I
D
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EX02082692C
Lab Sample ID: TT4539
Compound
acenapbtheoe
acenaphthylene
anthracene
benzidine
benzo(a)anthracene
benzo(b)fluoranthene
benzo(k)fluoranthene
benzo(a)pyrene
benzo(g,h,i)perylene
butylbenzylphthalate
bis(2-chloroethoxy)methane
bis(2-chloroethy !)ether
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10. u bis(2-chloroisopropyl)ether
10 u bi s(2-eth y lhexy I )phthalate
10 u 4-bromophenyl phenyl ether
52 u 2-chloronaphthalene
10 u 4-chlorophenyl phenyl ether
10 u chrysene
10 u dibenz(a,h)anthracene
10 u di-n-butylphthalate
10 u 1,2-dichlorobenzene
4 J 1,3-dichlorobenzene
10 u 1,4-dicblorobenzene
310 D
u
J
D
Compound was analyzed for but not detected. The number is the detection limit for the sample.
lndicates an estimated value less than the detection limit.
Compound analyzed at a secondary dilution factor.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
13
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
BNE-PP.FR.\-1 :. '7'9'2
I
IT ANALYTICAL SERVICES IT Corporation
September 14, 1992 5815 MIDDLEBROOK PIKE I
KNOXVILLE. TN
Client Project ID: National Starch Job Number: ITEK 52169
Client Sample ID:
Lab Sample ID:
BASE/NEUTRAL EXlRACTABLE ORGANIC PRIORITY POLLUTA>"-IT ANALYSIS
( continued)
Results in µg/liter (ppb)
Sample Matrix: Water
EX02082692C
IT4539
Compound Concentration Compound Concentration
3,3' -dichlorobenzidine 21 u hexachloroethane
diethylphthalate 10 u indeno( 1,2,3-cd)pyrene
dimethyl phthalate 10 u isophorone
2,4-dinitrotoiuene 10 u naphthalene
2,6-dinitrotoluene 10 u nitrobenzene
di-n-octyl phthalate 10 u n-nitroso-di-n-propylamine
1,2-diphenylhydrazine(l) 10 u n-nitrosodimethylamine
tluoranthene 10 u n-nitrosodiphenylamine(2)
fluorene 10 u phenanthrene
hexachlorobenzene 10 u pyrene
hexachlorobutadiene 10 u 1,2,4-trichlorobenzene
hexachlorocyclopentadiene 10 u
u
J
(1)
(2)
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Screened for as azobenzene
Detected as diphenylamine
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
14
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
I
I
I
I
I
I
I
I
D
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
lT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EX02082692C
Lab Sample ID: IT4539
Compound
4-chloro-3-methylphenol
2-chlorophenol
2,4-dichlorophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 2-nitrophenol
10 u 4-nitrophenol
10 u. pentachlorophenol
10 u phenol
52 u 2,4,6-trichlorophenol
52 u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
15
Concentration
10 U
52 U
52 U
9 J
10 U
ACID-PP FR.M :..-.-,:
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
58 15 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EX03082692C
Lab Sample ID: TT4540
Compound
acenaphthene
acenaphthylene
anthracene
benzidine
benzo(a)anthracene
benzo(b )fluoranthene
benzo(k)fluoranthene
benzo(a)pyrene
benzo(g,h,i)perylene
butylbenzylphthalate
bis(2-chloroethoxy)methane
bis(2-chloroethyl)ether
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-chloroisopropyl)ether
10 u bis(2-ethylhexyl)phthalate
10 u 4-bromophenyl phenyl ether
50 u 2-chloronaphthalene
10 u 4-chlorophenyl phenyl ether
10 u cbrysene
10 u dibenz(a,h)anthracene
IO u di-n-butylphthalate
10 u 1,2-dichlorobenzene
3 J 1,3-dichlorobenzene
10 u 1,4-dichlorobenzene
84
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
lndicatcs an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
16
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
BNE-PP.FRM :.-,r.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Cotporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
( continued)
Client Sample ID: EX03082692C
Lab Sample ID: TT4540
Compound
3 ,3 '-dichlorobenzidine
diethylphthalate
dimethyl phthalate
2,4-dinitrntoluene
2,6-dinitrotoluene
di-n-octyl phthalate
1,2-diphenylhydrazine( I)
fluoranthene
tluorene
hexachlorobenzene
hexacb.1orobutadiene
hexachlorocyclopentadieoe
Results in µglliter (ppb)
Sample Matrix: Water
Concentration Compound
20 u hexachloroethanc
10 u indeno( 1,2,3-cd)pyrene
10 u isopborone
10 u naphthalene
10 u nitrobenzene
10 u n-nitroso-di-n-prnpylamine
10 u n-nitrosodimethylamine
10 u n-nitrnsodiphenylamine(2)
10 u phenanthrene
10 u pyrene
10 u 1,2,4-trichlorobenzene
10 u
Concentration
IO u
10 u
10 u
10 u
10 u
10 u
IO u
10 u
10 u
10 u
10 u
U Compound was analyi.ed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
( 1) Screened for as azobenzene
(2) Detected as diphenylamine
Date of Extraction:
Date of Analysis:
08127192
08130192
17
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
ACID EX1RACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EX03082692C
Lab Sample ID: TT4540
Compound
4-chloro-3-methylpbenol
2-<:hJoropbenol
2,4-dichJoropbenol
2,4-dimetbylpbenol
2.4-dinitropbenol
2-metbyl-4,6-dinitropbenol
Results in l'g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 2-nitropbenol
10 u 4-nitropbenol
10 u pentacbloropbenol
10 u phenol
50 u 2,4,6-tricbloropbenol
50 u
U Compound was analyud for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
18 c,·
Concentration
10 u
50 u
50 u
10 u
10 u
ACID-PP.fR1,.t :.t7:~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Coiporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: EX04082692C
Lab Sample ID: TI4541
Compound Concentration Compound Concentration
acenaphthene 10 u bis(2-chloroisopropyl)ether
acenaphthylene 10 u bis(2-ethy lhexy l)phthalate
anthracene 10 u 4-bromophenyl phenyl ether
"bcnzidine 50 u 2-chloronaphthalene
bcnzo(a)anthracene 10 u 4-chlorophenyl phenyl ether
benzo{b)fluoranthene 10 u chrysene
benzo(k)fluoranthene 10 u dibcnz(a,h)anthracene
benzo(a)pyrene 10 u di-n-butylphthalate
benzo(g,h,i)perylene 10 u 1,2-dichlorobenzene
butylbenzylphthalate 3 J 1,3-dichlorobenzene
bis(2-chloroethoxy)methane 10 u l , 4-dichlorobenzene
bis(2-chloroethyl)ether 16
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
lndicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
19 ,.
10 u
6 J
10 u
10 u
10 u
10 u
10 u
3 J
10 u
10 u
10 u
BNE-PP.FRM :;:~
IT Corporation
September 14, 1992
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
I
I
Client Project ID: National Starch Job Number: ITEK 52169 1
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EX04082692C
Lab Sample ID: TT454I
Compound
3,3 '-dichlorobenzidine
diethylphthalate
dimethyl phthalate
2,4-dinitrotoluene
2,6-dinitrotoluene
di-n-octyl phthalate
1,2-diphenylhydrazine( I)
fluoranthene
fluorene
hexachlorobenzcoe
hexachlorobutadiene
hexachlorocyclopentadiene
( continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
20 u hexachloroethane
IO u indeno( 1,2,3-cd)pyrene
IO u isophorone
IO u naphthalene
IO u nitrobenz.ene
IO u n-nitroso-di-n-propylamine
IO u n-nitrosodimethylamine
IO u n-nitrosodiphenylamine(2)
IO u phenanthrene
IO u pyrene
IO u 1,2,4-trichlorobenz.ene
IO u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
(I) Screened for as azobenz.ene
(2) Detected as dipbenylamine
Dale of Extraction:
Date of Analysis:
08/27/92
08/30/92
20
Concentration
IO u
10 u
10 u
IO u
IO u
IO u
IO u
IO u
IO u
IO u
10 u
BNE-PP.FRM
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
·I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: EX04082692C
ub Sample ID: IT4541
Compound
4-chloro-3-metbylphenol
2-chlorophenol
2,4-dichlorophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Results in µg/liter (ppb)
Sample Matrix: W,ter
Concentration Compound
IO u 2-nitrophenol
IO u 4-nitrophenol
10 u pentachlorophenol
IO u phenol
50 u 2,4,6-trichlorophenol
50 u
u
J
Compound was analyzod for but not detected. Toe number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
21
Concentration
10 u
50 u
50 u
IO u
IO u
ACID-PP FRM :-~
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTJCAL SERVJCES
5815 MIDDLEBROOK PIKE
KNOXVJLLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: ST082692C
Lab Sample ID: TT4542
Compound Concentration Compound
acenaphthene 10 u bis(2-chloroisopropyl)ether
acenaphthylene 10 u bis(2-ethylhexyl)phthalate
anthracene 10 u 4-bromophenyl phenyl ether
benzidine 50 u 2-chloronaphthalene
benzo(a)anthracene 10 u 4-chlorophenyl phenyl ether
benzo(b)fluoranthene 10 u chrysene
benzo(k)fluoranthene 10 u dibenz(a,h)anthracene
benzo(a)pyrene 10 u di-n-butylphthalate
benzo(g,h,i)perylene 10 u 1,2-dichlorobenu:ne
butylbenzylphthalate 10 u 1,3-dichlorobenu:ne
bis(2-chloroethoxy)methane 10 u I , 4-dichlorobenu:ne
bis(2-chloroethyl)ether 91
u
J
Compound was analyzed for but not detected. Toe number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
22
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
BNE•PP l ~M
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
( continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: ST082692C
Lab Sample ID: TI4542
Compound Concentration Compound Concentration
3 ,3 '-dichlorobenzidine 20 u hexachloroethane
diethylphthalate 10 u indeno( 1,2,3-cd)pyrene
dimethyl phthalate 10 u isophorone
2,4-dinitrotoluene lO u naphthalene
2 ,6--dinitrotoluene 10 u nitrobenzene
di-n-<>ctyl phthalate 10 u n-nitroso-di-n-propylamine
1.2-diphenylhydrazine( 1) lO u n-nitrosodimethylamine
fl uoranthene 10 u n-nitrosodiphenylamine(2)
fluorene lO u phenanthrene
hexachlorobenzene lO u pyrene
bexachlorobutadiene 10 u 1,2,4-trichlorobenzene
bexachlorocyclopentadiene 10 u
u
J
(I)
(2)
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Screened for as azobenzene
Detected as diphenylamine
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
23
lO u
lO u
lO u
10 u
lO u
lO u
lO u
10 u
10 u
lO u
lO u
0NE-PP FRM -;.'7,'r..
IT Corporation
September 14, 1992
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
I
I
Client Project ID: National Starch Job Number: ITEK 52169 1
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: ST082692C
Lab Sample ID: TT4542
Compound
4-cbloro-3-methylpheool
2-cblorophenol
2,4-dichlorophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
IO u 2-nitropheool
IO u 4-nitrophenol
10 u pentacblorophenol
10 u phenol
50 u 2,4,6-trichlorophenol
50 u
U . Compound was analyzed for but not detected. The number is the detection limit for the sample. J -Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
24
Concentration
IO u
50 u
50 u
3 J
IO u
ACID-PP.FRM :.-: ~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
i
I
I
I
I
I
' I
I
I'
I
I
I
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/iiter (ppb)
Sample Matrix: Water
Client Sample ID: Method Blank
Lab Sample ID: BLl417
Com12ound Concentration Compound
acenaphthene 10 u bis(2-cbloroisopropyl)ether
acenaphthylene 10 u bis( 2-ethy lbexy I )phthalate
anthracene 10 u 4-bromophenyl phenyl ether
benzidine 50 u 2-cbloronaphthalene
bei:.::i( a )antbracene 10 u 4-cblorophenyl phenyl ether
benzo(b)fluoranthene 10 u cbrysene
benzo(lc)fluoranthene IO u dibenz(a,h)antbracene
benzo(a)pyrene 10 u di-n-butylphthalate
benzo(g,h,i)perylene 10 u 1,2-dicblorobenzene
butylbenzylphthalate 10 u 1,3-dicblorobenzene
bis(2-cbloroethoxy)methane 10 u 1,4-dicblorobenzene
bis(2-cbloroethyl)ether 10 u
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
25
Concentration
10 u
10 u
IO u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
BNE•PP.FRM ::,";'.q,:
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
( continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample IO: Method Blank
u,b Sample ID: BLl417
Compound Concentration Compound
3, 3 '-dichlorobenzidine 20 u hexachloroethane
diethylphthalate 10 u indeno( 1,2 ,3-cd)pyrene
dimethyl phthalate 10 u isophorone
2,4-dinitrotoluene 10 u naphthalene
2,6-dinitrotoluene 10 u nitrobenzene
di-n-octyl phthalate 10 u n-nitroso-di-n-propylamine
1,2-diphenylhydrazine( 1) 10 u n-nitrosodimethylamine
fluoranthene 10 u n-nitrosodiphenylamine(2)
fluorcne 10 u phenanthrene
hexachlorobenz.ene 10 u pyrene
hexachlorobutadicnc 10 u 1,2,4-trichlorobenz.ene
hexachlorocyciopentadiene 10 u
u
J
(1)
(2)
Compound was analyl.Cd for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Screened for as azobenz.ene
Detected as diphenylamine
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
26
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
BHE-PP.FRM ::::,r.
I
I
I
I
'I
I
I
' I
I
I
I
I
I
I
I
I
I
I
1· ...
I
' I,
.I
I'
I
I
11
I
IT Corporation
September 14, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52169
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: Method Blank
Lab Sample ID: BLl417
ComRQund
4-<:hloro-3-methylphenol
2-cblorophenol
2,4-dichlorophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 2-nitrophenol
10 u 4-nitrophenol
10 u pentacblorophenol
10 u phenol
50 u 2,4,6-trichlorophenol
50 u
U Compound was analyl.Cd for but not detected. The number is the detection limit for the sample.
J Indicate., an e.,timaled value less than the detection limit.
Date of Extraction:
Date of Analysis:
08/27/92
08/30/92
27
Concentration
10 u
50 u
50 u
10 u
10 u
IT Corporation
September 14, 1992
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Client Project ID: National Starch Job Number: ITEK 52 l69
WATER SURROGATE PERCENT RECOVERY SUMMARY
SEMIVOLATILE
SI S2 S3 S4 S5 S6 S7 S8
Client Sample ID (NBZ) <FBP) crnD (ffi!,) (2FP) (TBP) (2CP) (DCB)
EX0 1082692C 79 81 89 33 51 95 69 71
EX02082692C 79 76 84 8 •• 21 73 45 72
EX02082692C DL 75 71 79 9 •• 19 •• 65 42 67
EX03082692C 83 82 84 9 •• 16 •• 50 38 76
EX04082692C 88 87 89 4 •• 39 51 59 81
ST082692C 90 83 78 17 29 62 51 81
Method Blank 84 83 89 33 50 90 69 74
OC LlMITS
Si (NBZ) = nitrobenzene-d5 (35-114%)
S2 (FBP) = 2-fluorobiphenyl (43-116%)
S3 (TPH) = terphenyl-<114 (33-141 %)
S4 (PHL) = phenol-d5 (10-110%)
S5 (2FP) = 2-fluorophenol (21-110%)
S6 (TBP) = 2,4,6-tribromophenol (10-123%)
S7 (2CP) = 2-chlorophenol-<14 (33-110%) (advisory)
S8 (DCB) = 1,2-<lichlorobenzene-<14 (16-110%) (advisory)
••Values outside of required QC limits.
28 'JI.E0.1C-l.FRM
I
I
I
I
·•
1
' 'I '/
I
·1
I
I
~ 1 •.• £RNATJONAL ANALYSIS RE: ... c.JEST AND
~ ~~~~i CHAIN OF CUSTODY RECORD*
Project Name/No. 1 /vA1ic#lj/ <;liiic/1 Samples Shipment Date 7 /]·}6 ?2
Sample Team Members 2 r/Je,J,let /, 0.1/o/hl,_,e/( Lab Destination 8 I, Tl/ 5 _m PL
Reference Document l\c. 3 1 2 8 1 6
Page 1 of __
Bill to 5 Juh ;f £jog 6/J / t'I/ iO
Profit Center No. 3 358 I Lab Contact 9 /{1111 /AI S /
Project Manager4 ffl,°ke :5iz.,,-.J.e,'n4;J-Project Contact/Phone ~2 QOf/.) 6 :39 07y/ Report to: 10 , 5$11_ . ;jlcJ~oS
Purchase Order No. 6 -----Carrier/Waybill No. 13 FA/ '{XI :b-37-S9/.J..
9 ,;i c) ·· · · p.i,o,.;e 7o'I-6 '39 -<" /Sf I
Required Report Date 11 -1 --• 11, ••... , ..
Sample 14 Sample 15 16 . 1, s I 1 19 Requested Testing 20 Condition an 21 Disposal 22
Date/Time Container amp e Pre-
Number Descrint:ion/Tvne Collected Tvne Volume sen,ative Proaram Receipt Record No.
.s· ro;126c;J.. c a flov.<Jw,d ('/1. CvmD
8·Jl,-<j;J
/1"' "'"' .y <>c /1/V p, f //.I'< (z, 70(_ t/.K.., ) a.. 1 fr-:z.7. ~,c_
1.,aS ~ )45$ IL €Pf/ 6)5 ,,,.,,,~.,_G A J" ,_,he+
' 1,-),/,-<jJ. ~"' le"-,.,0 ~>1/ ,
£i,o/C8)bq) C a>'.ouru J"'a / e ,i. ~G-. '{00 al.v> IL L/OC £ ffl 6.:.i.5 he,t./:,S
~ ~-26-'i L ·11,.,., s,e1t NV /t'JI'.
EXcJo8}b9l C 4Rou...J;. ,~Jell ~ l'IJ.5 -,J-,;.5 tL </ 0( 1:--p11 l:J.5 l,f,'14
f:')(o'\08 Ji:,f) C ~~bv-"JI.\J>d (~ G...
g-.z(-~L.
1'1<1</
rl t" J,R,L
Cl/.+5J IL 'I oc Eft1625 NO i""'1/4. ),,-,, ~
cY:0 l/ oS)t 1,). C aROJMi IV~ /r.t G. 5-16·'i 2.
1.S60
/1 h' be 'l.
o,ln-S5 IL s,, oc cftlb:i S /4,-V le,:, .,. /
l,r.r.P.5
£ ro9..J 6 9;;. 13 I: 4:/J,vj C,.;,#efl. {i, 8. ;i.6 ·'i 2.
/.50.S llo/1 .z '; i/On fl.(/_.
¥"C rr1ef-J,cJ /;-J </
/:Xvfl,<g:JG9J. J3 c;/2.(Vndu.,,Hez [.,.-fl•26 ·',{'..
I '/t.O [/{fl 1. v 'l{,l/1 I r/cf y( p'l.~fJo/ 62 c/
;::: loJot)69 LIJ ' cAv.J '<. ,1{,',( Cr ' %-20"~<.. t/[v'J ity,:;,,I /I ( ~ M,IJ~ 6.1. '( \, /
/il5 ,;roe
Special lnstructio~s: .23 [)Je~5e. Re+ vKrv' (,r;/e,1. Jo ))11 /,'0,111 I .Sf 11(£ Ii /'edrit .Sae.;("< IJ .SIJ/,',/v.e/ All .J<f/$/f
Possible Hazard Identification: 24 I Sample Dispo~I: 25 ' ~
,
Non-hazard ._J Flammable _J Skin Irritant _J Poison B _J Unknown~ Return to Client Disposal by Lab _J Archive !mos.)
Turnaround Time Required: 26 t::;' d I [!q Level: 27
Normal _J Rush ~ /l y I ' IL _J 111.;_J Project Soecific lspecifv]: I I
1. Relinquished by 28 JI 1 /tl'fate: "' 1. Received by 2~
f Date: ?;(27(°12.. ~ [S,gnature/Aff,hat.ionJ -rc;:,,, Fj,/dlev / \Time: \[S1gnature/Aff11iat.ionJ //.,A.,. V /'rftS.J' Time: 0"62D
2. Relinquished by / 'ti,,~ 1)2. Received by Date: ......
(Signature/ Aff,lmtion] Time: !Signature/ Aff1lintion) Time:
3. Relinquished by Date: 3. Received by Date:
[Signature/ Aff1liat1□f"' J Time: (Signature/ Aff1batinnJ Time:
Comments: 29
/7£,<: S'.2/67
. MCA 3115/9
l---------+---"7"""------lf-----------=f=,,,......_::::---1---+---+---------+----....:...---....:...--1-------1~
" C l---------+,,.c....------lf---------l-----l-==+--:::-+---------t----------1--------11
1------"--'--------...L.------i.---...L.--...L.--.,J._,-~------J..._------......I-----~
Special Instructions: 23 (>1~ 5e e fu1.,v fo&tl. 15
Possible Hazard Identification: 24
Non-hazard '_J Flammable _J Skin Irritant · _J Poison B _J Unknown
Turnaround Time.flequired: 26 cl
Normal _J Rush ti S A
QC Level: 27
1 . Relinquished by 28 _
{Signature/ Affiliation] / O/J')
2. Relinquished by
(Signature/ Affiliation)
3. Relinquished by
(Signature/ Affiliation]
Comments: 29
. Received by 28~
1gnature/ Affiliation) ~
2. Received by
!Signature/ Affiliation)
3. Received by
(Signature/ Affiliation]
Archive. (mos.)
Date: cg 2-7 '72-
Time: 0'?2D
Date:
Time:
Date:
Time:
,
~
/I ,, ,,
I .,
1·
j,
I ,,.
·1,
I,
1
I
[D INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
CERTIF1CATE OF ANALYSIS
IT Corporation November 16, 1992
312 Directors Drive
Knoxville, TN 37923
Attn: Sara Mokros
Job Number: ITEK 52722
This is the Certificate of Analysis for the following samples:
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
11/04/92
Ten (10)
Water
On 11/04/92, ten (10) water samples arrived at the ITAS-Knoxville, Tennessee, laboratory from IT
Corporation, Knoxville, Tennessee, in support of the National Starch project. The list of analytical tests
performed, as well as date of receipt and analysis, can be found in the attached report.
II. Analytical Results/Methodology
The analytical results for this report are presented by analytical test. Each set of data will include sample
identification information and the analytical results. Please note that the data are not blank corrected.
The samples were analyzed for the requested metals by graphite furnace atomic absorption spectroscopy
(GFAA) and inductively coupled argon plasma spectroscopy (ICP) baesd on EPA methods 249.2 and 6010.
The total dissolved solids (TDS) content of the samples was determined using EPA method 160.1.
The total suspended solids (TSS) content of the samples was determined using EPA method 160. 2.
Reviewed and Approved:
Alyce R. Moore
Laboratory Manager
Ameni:ar. C:J'Jncil ot Independent Lcbora1ones
lr:terriat!c;--;::il ,\.ssoc:at1on ot Erm:onmentcl l•::::::r.-;i-: ct-,or01011es
_:·..iner:ca:--. Assoc:at1on :or :...aborator·1 ;..c::0C1!at:::m
IT Analytical Services. 5815 Middlebrook Pike. Knoxville, TN 37921 661·1·69
IT Corporation
November 16, 1992
Client Project ID: National Starch
m. Quality Control
Routine laboratory level I QC was followed.
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52722
The samples were digested on 11/05/92 for ICP and GFAA. The GFAA analysis for nickel was performed
on 11/05/92; the remaining metals were analyzed by ICP on 11/10/92. All run QC was acceptable. No
problems were encountered.
The TDS content of the samples was determined gravimetrically by filtration and evaporation of the filtrate
to a constant weight at 180°C. No problems were encountered.
The TSS content of the samples was determined gravimetrically by filtration and measurement of the filter
residue weight after drying at 103-105°C. No problems were encountered.
2
r,e?-t r-<J
I
,I
I
,j
I
I
I
I
I
l1 ,,
' I
I
I
i
I .,
I
IT Corporation
November 16, 1992
Client Project ID: National Starch
Client Sample ID: Method Blank
Lab Sample ID: PBWI 1142/PBWI 1145
cadmium 0.005 u
chromium 0.01 u
copper 0.01 u
manganese 0.002 u
nickel 0.002 u
zinc 0.018
Digestion Date: I 1/05/92
METALS ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
EXOI 1103
W2170
0.005 u
0.01 u
0.01
0.096
0.002 u
0.039
Analysis Date: 11/10/92 (ICP), I 1/05/92 (GFAA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52722
EX021103 EX031103
W2172 W2172
0.005 u 0.005 u
0.01 u 0.01 u
0.01 u 0.01 u
10.9 2.9
0.002 u 0.002 u
0.010 0.018
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
3
IT Corporation
November 16, 1992
Client Project ID: National Starch
Client Sample ID: EX041103
Lab Sample ID: W2173
cadmium 0.005 u
chromium 0.01 u
copper 0.01 u
manganese 1.8
nickel 0.002 u
zinc 0.Dll
Digestion Date: 11/05/92
METALS ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
ST! 103A
W2174
0.005 u
0.01 u
O.DI u
2.6
0.013
0.074
Analysis Date: 11/10/92 (ICP), 11/05/92 (GFAA)
TFl103
W2175
0.005
0.01
0.01
2.6
0.002
0.044
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52722
CLE1103A
W2176
u 0.005 u
u 0.01 u
u 0.01 u
0.089
u 0.002 u
0.011
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
4
,;~7.\ ~q
I ,,
I
I
.1
I
I
I
\I
,J
I .,
I
,I
I
' I
I
I,
1.
'I
I
I
1.
IT Corporation
November 16, 1992
Client Project ID: National Starch
Client Sample ID:
Lab Sample ID:
chromium
nickel
zinc
Digestion Date: 11/05/92
METALS ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Llll03A L31103A
W2177 W2178
0.03 0.05
0.024 0.044
0.085 0.068
Analysis Date: I 1/10/92 (ICP). 11/05/92 (GFAA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVIUE, TN
Job Number: ITEK 52722
XXl 103
W2179
0.026
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
5
IT Corporation
November 16, 1992
Client Project ID: National Starch
Client SamQle ID
Method Blank
STI103B
L3! 103B
CLE1103B
LI i 103B
Date of Analysis: I 1/05/92
TOTAL DISSOLVED SOLIDS ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Lab SamQle ID
P4455
W2!66
W2167
W2!68
W2!69
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52722
Result
u
805
8,360
665
5,660
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
6
h~;:"-1 fi:'l
I
I
,I
,I
ii
I
I
-I
I
,I
,I
:1
,I
I
I
:1
11
I\ ,,
t
\I
fl, ,,
\I
I
I
'
I
\I
I
:1
I
I
1~
1 •
{I
IT Corporation
November 16, 1992
Client Project ID: National Starch
TOTAL SUSPENDED SOLIDS ANALYSIS
Date of Analysis: 11/05/92
Client Sample ID
Method Blank
CLEli03B
Lll 103B
Results in mg/liter (ppm)
Sample Matrix: Water
Lab Sample ID
P4454
W2168
W2169
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52722
Result
u
u
67
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
7
~ INTERNATIONAL ANALYSIS REQUEST AND Reference Document No. 3 6 1 8 7 6 ~ ~~~~i-, CHAIN OF CUSTODY RECORD* Page 1 of __
Project Name/No. 1 S-/lll?.I.,/,. Samples Shipment Date 7 / l-3-'12. Bill to:5 ;1/n4c-,uf{_(__s/4ec t{ ____ .............. i:
Sample Team Members~t_,t/c~ k=-V Lab Destination 8 / /l'r..5 -1'11 PL ---=v1,71=--i/c,J6(°/j"~-;:;9-:t,2_ .. ·-· ~'
Profit Center No. 3 / 'f, Lab Contact 9 l(.",n, L l'f ,'5 ~ ____ 8
Proiect Manager 4 /11,ke S/2rr...devl¾I Project Contact/Phone 12 7 6 '-1-637 -666 I Report to: 1~_,'.;>1¼4--1r1c;f,~0 _s _____ j
Purchase Order No. 6 ------Carrier/Waybill No. 13 '/f/7/.26/3 36 _}it,._,2.../:;
1
•/;;.f_/,:::,,,JD}-
772
--3 --[:
I I 6 9 2-(Qj ~,-" Required Report Date 11 --mD••··· -<1.s1~-J2 7z-------------~ .... ,n,■• .f.·■l1 ... i'· - --------··-------·---·---· ---- -• ..
Sample 14 Sample 15 Date/Time 16 Container 1 Sample11 Pre-19 Requested Testing 20 Condition on 21 Disposal 22
Number Description/Tune Collected ·Tvne Volume sen,ative Proaram Receipt Record No.
/l-3-92... Pl1sl-; C b tiJE-P/5 ' -1£:xoJ I/IJ3 f;.~,1,) Lvrie/l.... 566111I JIJJ°-3 7DL-~ i10& 6 • E'f.o) ;;o-, 11-J-'iL 5WM/ ;/JJQ:, 6/1l!?T11/5 "\ :·· --7 {//1.. ii,
0
E'I.D <.II IJ.. ') 1 1-3-~ L ,;-ooml I-IN /23 6111ETA0 .;;;:· '. ,-: ~ " l! J.o " D
EXol///D3 ,1-.3-9 <-_:yjDn1 I J-/NO-,, I If) Fr,4 Is // //.,
<: 1110..J 11 ,J-3;.)l....
//.2 iirori I !fNo; t ff} .F7 rf5 .. :· ~ ! ; ·•
ST1103 B 11-3-'/L. JL 1/ /) (., ;.DS :,:, ;'° . ...
//2 </ ; :'·: ct f' ' '.
u ,1-J-92. c;(ii),,i I tS/llE7;f/5
., ~,_ ;. -. m tF !/(}'<-I 11/0 /J;/D?, a
C C ·v 11-J-J}-,v
,SCXJt1 I o,J/v 0
'iv/In~ J-1 NOs , 'J 17'-f, z,, 2
t, t?'JE7ii/'> I 0 Special Instructions: 23 -Cd, Cr. Cu /!111 , M· 21'1 ';:z 1?1£;#5 -C:r. N:, 2,,-, bv..ffP 3 --
Possible Hazard Identification: 24 --, -Sample Disposal: 25 -. ' c ~ ,--Flammable ::i Skin Irritant iJ Poison B :.:i Unknown 'ii,_ Return to Client I:) Disposal by LalJ/.l Archive (mos.) ~ Non-hazard :_J u m TurnarotJnd Tim
1
~Required: 26 ~&.Lev~t21 0 ~ Normal :_J Rush J I.~ 1/ .. J 1110 Project Soecific (specie,): ·-.. .. ---~
1. Relinquished by ~ ,J, ;Ji/,, Date: /1-3· 9 Z.. 1 , Received by 2a ~/x Date: //-3-';J.:::. ~ C (S1gnature/Affiliation] /CyyJ .L _.,1 170-w n Time: I 1'1U, (Signature/ Affiliation) Time: I ~✓-v-:, ~
0 2. Relinquished by p-e} f:x I Date:_l f '<f { }1__ 2, Received by -~ Date: Ul'-fl ')L ~
~-
m
[Signature/Affi!iat.ion) Time: U"t,2.0 [Signature/ Affiliation) rn.-~K...Time: EJ<l2.0
3. Relinquished by Date: 3. Received by Date: (Signature/Affiliation) Time: [Signature/ Affiliation] Time:
Comments: 29 Avj "l ues I-; o 0 C\1 I/ 5Ai!.4 n1okllv5 6'i0-]2!/
-----, --·-.-
~ ---· ------ ---,_ -·-_, ··-·
rn INTERNATIONAL
TECHNOLOGY
CORPORATION
Project Name /Y!Jf/cw.4/ __ Sf'!tC ~-
ANALYSIS REQUEST AND
CHAIN OF CUSTODY RECORD [cont.)*
Project No. _ 1zo8f£f <? 2, f-2_
Reference Document No_30 36/._Jf 7 6
Page-2._of _2._
Samples Shipment Date_ //--_J--:_ f2
....------....... ------....... --~'""·~·· ~-··" Date/Time 16 Container11 Sample18 Pre-19 Requested Testing 20 Condition on 21 Disposal 22 ~ Sample14
Number
Sample 15
Descriptian/Tvne Collected Tvne Volume servative Proqram Receipt Record No. £.
c'LE f/C)J 4 e-~wrvd l,)4ktf.-1~7-!is"L o/r,J,·c C,m,,,,/ HNtJ3 c:fpE;~~ a' µ::_=::=-_:_:_:C=::--'-'--F--'-"""'-'-'--"'-=.:-'-'--'=-!--LLC'="-cc--+!=-'-'-'-'=-+-':ei.:L.!L:.-f-'--"-'-'::.L-l---'=::__:_---==::_-+-------+------~ru
CLE/!o-3 13 -''i>:;sc;z. , )L-v "c ;55d-TDS § l----'-----+--i-----1---+---'----f--i----l--'----l-----l--'--=-c:c___-<-:="--+-------+--------l3
LI /lo~ II i1,,tJ 2 sro,,,, I r-lN!J, _,!7JET4/s ' l -~-~~---------t-~---t---,f---+---+-~~--------+-------+--------1.,,
Lll/0313 11,-JiJ" Jl-Lj 0 c T5-5.fTD5 ~
'
I
I
-< rn
0 ~
-n
iii a:
n 0 " <
en rn i-----;----+----;-----+---t---+----+--t----1-t--+---+-----+----+-------+--------lrn □-ru n 1----;----+-----+----+---l---t---+-+---ir--l---+---l-----+----+-------+--------l,<-8,
0 1----+-----------+---J---t---t--+---,r-+--t---1-----+----+-------+--------l3
0 i---t-----t-----t----t----t--t---+-t--,f-t--+--+-----+---+-------+------~~
" rn n ru
5 i---;------t-----t----t---,c--t---t--t--+-,-t--,c--+-----+---+-------+------~~
I
I
g
0 0 u,
I
I ,,
I
I ,,
I
I ,,
1,
I
i
I'
I
I
[D INTERNATIONAL
TECHNOLOGY CORPORATION
IT Corporation
3 I 2 Directors Drive
Knoxville, TN 37923
Attn: Mike Sturdevant
ANALYTICAL
SERVICES
CERTIFICATE OF ANALYSIS
September 21, 1992
Job Number: ITEK 52224 P,O, Number: 408668,009,60
This is the Certificate of Analysis for the following samples:
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
09/02/92
Three (3)
Water
On 09/02/92, three (3) water samples arrived at the ITAS-Knoxville, Tennessee laboratory from IT
Corporation, Knoxville, Tennessee, in support of the National Starch project. The list of analytical tests
performed, as well as date of receipt and analysis, can be found in the attached report.
II. Analytical Results/Methodology
The analytical results for this report are presented by analytical test. Each set of data will include sample
identification information and the analytical results, Please note that the data are not blank corrected,
The samples were analyzed for priority pollutant semivolatile organic compounds by gas
chromatography/mass spectroscopy (GC/MS) based on EPA method 625.
Revie~~ and A_,,gproved: ~{~' <~/
Alyce , Moore
Laboratory Manager
Amen<::ar. C::,uncii 01 Independent Labora1or1es
ir.!err:~:io,.~1 A.ss8c:ct:on 01 E:,:1i;or.:1:er,1ci T~s::r,J :.c:.bora1or1es
:\..:rier:c:a:--, _: . .ssoc:at:or. '.or '....atorator·1 Ac.::ri_;d\:at:on
IT Analytical Services. 5815 Middlebrook Pike, Knoxville, TN 37921
I
IT Corporation
September 21, 1992
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE I
KNOXVILLE. TN ·
Client Project ID: National Starch Job Number: ITEK 52224 ,1
m. Quality Control
Routine laboratory level I QC was followed.
The semivolatiles analyses were performed by direct injection of sample extract on a Restek XTI-5 capillary column on a Finnigan 4500 GC/MS/DS. The sample analyses generally went well. Samples EX020901C and EX030901C exhibited low acid surrogate recoveries. Although sample EX020901C had more than one acid surrogate outside advisory limits, a request for reextraction was not made as this analysis was on an extraction from a source previously characterized with similar matrix interferences.
CLP internal standards and surrogate standards were employed for convenience and practicality. There
. were no problems seen in final data review.
2
I
I
,t
I
;1
I
·I
I
I
I
I
I
I
I
I
I ,,
I
I
I
1 ,,
I
I
I
I
I
I
IT Corporation
September 21, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52224
BASE/NEU1RAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: Method Blank
Lab Sample ID: BL1475
Comeound
accnaphthene
acenaphthylene
anlhracenc
benzidine
benzo(a)anthraccne
benzo(b)fluoranthene
benzo(k)fluoranthene
benzo(a)pyrcne
benzo(g,h,i)pcrylene
butylbenzylphthalate
bis(2<hlorocthoxy)methane
bis(2<hlorocthyl)ether
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Comoound
IO u bis(2<hloroisopropyl)ether
IO u bis(2-ethylhexyl)phthalate
IO u 4-bromophenyl phenyl ether
so u 2-<:hloronaphthalene
IO u 4..:hlorophenyl phenyl ether
10 u chrysene
IO u dibenz(a,h)anthracene
IO u di-n-butylphthalate
IO u 1,2-dichlorobenzene
10 u 1,3-dichlorobenzene
10 u I, 4-dichlorobenzene
IO u
U -Compound was analyzed for but not detected. Toe number is the detection limit for the sample.
Date of Extraction:
Date of Analysis:
09/03/92
09/09/92
3
Concentration
10 u
10 u
IO u
10 u
IO u
IO u
IO u
10 u
10 u
10 u
10 u
BNE-PP.FRM Y:!91.
IT Coq,oration
September 21, 1992
Client Project ID: National Starch
I
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE I
KNOXVILLE. TN .
Job Number: ITEK 52224 ,1
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS (continued)
Results in 1<g/liter (ppb)
Sample Matrix: Water
Client Sample ID: Method Blank
Lab Sample ID: BL147S
Compound Concentration Compound
3 ,3 '-dichlorobenzidine 20 u hexachlorocthane
diethylphthalate 10 u indeno( 1,2 ,3-cd)pyrene
dimethyl phthalate 10 u isophorone
2,4-dinitrotoluene 10 u naphthalene
2,6~initrotoluene 10 u nitrobenzene
di-n-octyl phthalate 10 u n-nitroso-di-n-propylamine
1,2-dipheny !hydrazine( 1) 10 u n-nitrosodimethylamine
lluoranthene 10 u n-nitrosodiphenylamine(2)
fluorene 10 u phenanthrene
hexachlorobenzene 10 u pyrene
hexachlorobutadiene 10 u 1,2,4-trichlorobenz.ene
hexachlorocyclopentadiene 10 u
u
(I)
(2)
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Screened for as ambem.ene
Detected as diphenylamine
Date of Extraction:
Date of Analysis:
09/03/92
09/09/92
4
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
I
I
:I
I
/I
I
I
I
I
I
I
I
I
I
Btffi.PP.FRM ,r.,., I
·--·I
I
I
'I
I
'I
I
I
1
I
I
I
I
I
I
I
I
I
l
I
IT Corporation
September 21, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 52224
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Client Sample ID: Method Blank
Lab Sample ID: 811475
Compound
4...:hloro-3-methylphenol
2-chlorophenol
2,4-dichlorophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Results in /Lg,1!iter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 2-nitrophenol
10 u 4-nitrophenol
10 u pentachlorophenol
10 u phenol
50 u 2,4,6-trichlorophenol
50 u
U -Compound was analyzed for but not detected. Toe number i, the detection limit for the sample.
Date of Extraction:
Date of Analysis:
09/03/92
09/09/92
5
Concentration
10 U
50 U
50 U
10 U
10 U
AC(l).PP.FRM '.:,'7'Q'?
I
IT Corporation
September 21, 1992
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE I
KNOXVILLE, TN .
Client Project ID: National Starch Job Number: ITEK 52224 1
Client Sample ID:
Lab Sample ID:
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/liter (ppb)
Sample Matrix: Water
EX02090!C
TT5056
Compound Concentration Compound Concentration
acenaphthene IO u bis(2~hloroisopropyl)ether
acenaphthylene IO u bis(2-ethylhexyl)phthalate
anthracene IO u 4-bromophenyl phenyl ether
benzidine 50 u 2~hloronaphthalene
benzo(a)anthracene IO u 4~hlorophenyl phenyl ether
benzo(b)fluoranthene 10 u chrysenc
benzo(k)fluoranthene IO u dibenz(a,h)anthracene
benzo(a)pyrene IO u di-n-butylphthalate
benzo(g,h,i)perylene IO u 1,2-<lichlorobenzene
butylbenzylphthalate 3 J 1,3-<lichlorobenzene
bis(2~hloroethoxy)methane IO u I , 4-<lichlorobenzene
bis(2~hloroethyl)ether 350 D
u
J
D
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Compound analyzed at a secondary dilution factor.
Date of Extraction:
Date of Analysis:
09/03/92
09/09/92
6
IO U
10 U
IO U
10 U
IO U
IO U
10 U
10 U
10 U
10 U
10 U
8H£.PP.FRM
I
' I
I
I
I
I
I
I
I
I
I
I
:I
I
/I cs~,
I
I
I
I
I
I
I
I
I
I
.I
I
I
I
I
I
I
I
I
I
IT Corporation
September 2 I, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52224
BASE/NEUTRAL EX1RACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID• EX02090!C
Lab Sample ID: IT5056
Compound Concentration Compound
3 ,3 '-dichlorobenzidine 20 u hexachloroethane
diethylphthalate 10 u indeno( 1,2,3-<:d)pyrene
dimethyl phthalate 10 u isophoronc
2, 4-dinitrotoluene 10 u naphthalene
2,6-dinitrotoluene 10 u nitrobenz.ene
di-n-octyl phthalate 10 u n·nitroso-di·n·propylamine
1,2-diphenylhydrazine(I) 10 u n-nitrosodimethylamine
fluoranthene 10 u n-nitrosodiphenylamine(2)
fluorenc 10 u phenanthrene
hexachlorobenzene 10 u pyrene
hexachlorobutadiene 10 u 1,2,4-trichlorobenune
hexachlorocyclopentadiene 10 u
U Compound was analyzed for but not detected. The number is the detection limit for the 9&111ple.
J Indicates an estimated value less than the detection limit.
D Compound analyzed at a secondary dilution factor.
(I) Screened for as azoben7.ene
(2) Detected as diphcnylamino
Date of Extraction:
Date of Analysis:
09/03/92
09/09/92
7
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
IT Corporation
September 21, 1992
Client Project ID: National Starch
I
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE I
KNOXVILLE, TN
Job Number: ITEK 522241
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/liter (ppb) I
Client Sample ID: EX020901C
Lab Sample ID: IT5056
Compound
4-<:hloro-3-methylphenol
2-<:hlorophenol
2,4-dichlorophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Sample Matrix: Water
Concentration Compound
IO .u 2-nitrophenol
IO u 4-nitrophenol
IO u pentachlorophenol
10 u phenol
50 u 2,4,6-trichlorophenol
50 u
U Compound was analyzed for but not detected. The number i• the detection limit for the sample.
J lndicale9 an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
09/03/92
09/09/92
8
I
I
Concentration I IO u
50 u
50 u ·• 9 J
IO u I
'I
I
I
I
I
I
I ,,
ACII}.PP.FRM "'1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 21, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52224
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample JD: EX030901C
Lab Sample ID: TI5057
Compound Concentration Compound
acenaphthene 10 u bis(2-<:hloroisopropyl)ether
acenaphthylene 10 u bis(2~thylhexyl)phthalate
anthracene 10 u 4-bromophenyl phenyl ether
· benzidine 50 u 2-<:hloronaphthalene
benzo(a)anthracene 10 u 4-<:hlorophenyl phenyl ether
benzo(b)fluoranthene 10 u chrysenc
benzo(k)fluoranthene LO u dibenz(a,h)anthracene
benzo(a)pyrene 10 u di-n-butylphthalate
benzo(g,h,i)perylene 10 u 1,2-<lichlorobenzene
butylbenzylphthalate LO u 1,3-<lichlorobenzene
bis(2-<:hloroethoxy)methane 10 u I, 4-<lichlorobenzene
bis(2-<:hloroethyl)ether 80
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
Date of Extraciion:
Date of Analysis:
09/03/<n
09/09/<n
9
Concentration
10 u
10 u
10 u
LO u
10 u
LO u
LO u
10 u
LO u
10 u
10 u
BHE-PP.FRM Ylf<I'!
IT Corporation
September 21, 1992
IT ANALYilCAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
I
I
Client Project ID: National Starch Job Number: ITEK 52224 ________________ .,
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS (continued)
Results in µg/!iter (ppb)
Sample Matrix: Water
Client Sample ID: EX030901C
Lab Sample ID: TI5057
Compound Concentration Compound
3 ,3 '-dichlorobenzidine 20 u hexachloroethane
diethylphthalate 10 u indeno( 1,2,3-<:d)pyrene
dimethyl phthalate 10 u isophorone
2,4-dinitrotoluene 10 u naphthalene
2,6-dinitrotoluene 10 u nitrobcnz.ene
di-n-octyl phthalate 10 u n-nitroso-di-n-propylamine
1,2-diphenylhydrazine( 1) 10 u n-nitrosodimethylamine
fluoranthene 10 u n-nitrosodiphcnylamine(2)
fluorene 10 u phcnanthrenc
hcxachlorobenz.cnc 10 u pyrenc
hcxachlorobutadienc 10 u 1,2,4-trichlorobenz.cnc
hcxachlorocyclopentadiene 10 u
U Compound was analyzed for but not detected. Tho number is tho detection limit for tho sample.
(I) Screened for as azobcnzenc
(2) Detected as diphcnylaminc
Date of Extraction:
Dato of Analysis:
09/fY3/92
09/09/92
10
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
BNE-PP.FRM
' -
I
0
I
I
·1
I
E
'"l
I
I
I
I
I
I
I
1
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 21, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52224
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in l'g/liter (ppb)
Client Sample ID: EX030901C
lab Sample ID: TI5057
Compound
4-<:hloro-3-methylphenol
2-<:hlorophenol
2, 4-dich!orophenol
2,4-dimethylphenol
2,4-dinitrophenol
2-methyl-4,6-dinitrophenol
Sample Matrix: Water
Concentration Compound
10 u 2-nitrophenol
10 u 4-nitrophenol
10 u pentach!orophenol
10 u phenol·
50 u 2,4,6-trichlorophenol
50 u
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
Date of Extraction:
Date of Analysis:
09/03/<n.
09/09/<n.
11
Concentration
10 U
50 U
50 U
10 U
10 U
ACID-PP.FllM :.n.'92
IT Corporation
September 21, 1992
Client Project ID: National Starch
I
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE I
KNOXVILLE, TN .
Job Number: ITEK 52224.
I
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS '
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: EX040901C
Lab Sample ID: IT5058
Com!!Qund Concentration Com!!Qund
acenaphthene 10 u bis(2-<:hloroisopropyl)ether
acenaphthylene 10 u bis(2-ethylhexyl)phthalate
anthracene 10 u 4-bromophenyl phenyl ether
benzidine 50 u 2-<:hloronaphthalene
benz.o( a)anthracene 10 u 4-<:hlorophenyl phenyl ether
benz.o(b )fluoranthene 10 u chrysene
benz.o(k)fluoranthene 10 u dibenz.(a,h)anthracene
benz.o(a)pyrene 10 u di-n-butylphthalate
benz.o(g,h,i)perylene 10 u 1,2-dichlorobenzene
butylbenzylphthalate 10 u 1,3-dichlorobenzene
bis(2-<:hloroethoxy)methane 10 u I, 4-dichlorobenzene
bis(2-<:hloroethyl)ether 16
U -Compound was analyr.cd for but not detected. The number is the detection limit for the sample.
Date of Extraction:
Date of Analysis:
09/00/9'2
09/09/9'2
12
Concentration
10 U
10 U
10 U
10 U
10 U
10 U
10 U
10 U
10 U
10 U
10 u
I
,I
I
I
I
I
I
I
I
I
I
I
I
I
BNE-PPFRM "'"'I
.. -I
I
I
I
I
I
I
I
1
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 21, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVIU.E. TN
Job Number: ITEK 52224
BASE/NEUTRAL EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: EX040901C
lab Sample ID: TI5058
Compound Concentration Compound Concentration
3 ,3 '-dichlorobenzidine .20 u hexachloroethane 10 u
diethylphthalate 10 u indeno(l ,2,3-cd)pyrene 10 u
dimethyl phthalate 10 u isophorone 10 u
2,4-dinitrotoluene 10 u naphthalene 10 u
2,6-dinitrotoluene 10 u nitrobenz.ene 10 u
di-n-«tyl phthalate 10 u n-nitroso-di-n-propylamine 10 u
1,2-diphenylhydrazine( 1) 10 u n-nitrosodimethylamine 10 u
fluoranthene 10 u n-nitrosodiphenylamine(2) 10 u
fluorene 10 u phenanthrene 10 u
hexach!orobenzene 10 u pyrene 10 u
hexachlorobutadiene 10 u 1,2,4-trichlorobenz.ene 10 u
hexachlorocyclopentadiene 10 u
U Compound was analyzed for but not detected. Toe number is the detection limit for the sample.
(I)
(2)
Screened for as azobenzene
Detected as diphenylamine
Date of Extraction: 09/C13l92
Date of Analysis: 09/09/92
13 BN'E-PP.fllM Y7'9'Z
IT Corporation
September 21, 1992
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
I
I
Client Project ID: National Starch Job Number: ITEK 522241
ACID EXTRACTABLE ORGANIC PRIORITY POLLUTANT ANALYSIS
Results in µg/liter (ppb)
Client Sample ID: EX04090!C ·
Lab Sample ID: 'IT5058
Compound
4-chloro-3-methylphenol
2-chlorophenol
2,4-<lichlorophenol
2,4-<limethylphenol
2,4-<linitrophenol
2-methyl-4,6-<linitrophenol
Sample Matrix: Water
Concentration Compound
10 u 2-nitrophenol
10 u 4-nitrophenol
10 u pentachlorophenol
10 u phenol
50 u 2,4,6-trichlorophenol
50 u
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
Date of Extraction:
Date of Analysis:
09/00/92
09/09/92
14
I
/I
I
Concentration I 10 u
50 u
50 u ·I
10 u
10 u I
I
I
I
I
I
I
I
I
ACID-PP.FRM "'~1
I
I
I
I
I
I
I
I
I ,,
I
I
I
I
I
I
I
I
I
i
IT Coiporation
September 21, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52224
WATER SURROGATE PERCENT RECOVERY SUMMARY
SI S2
Client Sam~le ID iliBZ) (ml
EX02090!C 90 78
EX020901C DL 89 79
EX030901C 88 89
EX040901C 87 90
Method Blank 93 92
SI (NBZ}
S2 (FBP)
SJ (TPH)
S4 (PHL)
S5 (2FP)
S6 (TBP)
S7 (2CP)
S8 (DCB)
•Values outside of required QC limits.
DL -Dilution.
=
= =
=
= = = =
SEMIVOLATILE
SJ S4
mID aw.)
76 0 •
74 10
89 II
90 19
94 35
nitrobcnzene-dS
2-fluorobiphenyl
tcrphenyl-<114
phcnol-dS
2-fluorophenol
2,4,6-tribromophenol
2-<:hlorophenol-<14
1,2-<iichlorobcnzcne-<14
15
S5 S6 S7 S8
(1ff) (TI!f) (£g) (DCB}
17 • 39 32 • 77
15 • 30 31 • 73
17 • 62 39 80
33 67 55 76
57 81 72 83
oc UMITS
(35-114%)
(43-116%)
(33-141 %)
(10-110%)
(21-110%)
(10-123%)
(33-110%) (advisory)
(16-110%) (advisory)
I.REC\X' · I . FRM
rn l •.. £RNATIONAL
TECHNOLOGY
CORPORATION
Project Name/No 1 J//M'o,.;1;/ Sft.J f'lc A
Sample Team ~embers 2 I. J.1eNJ'1
Profit Center No.~~g.5~~1--.----,--,
· Project Manager4 r?'l; ke. 5 f...,adf1111.J
Purchase Order No._6 ____ ~---
Required Report Date 11 Cj -'t · q 2_
ANALYSIS RE-..JEST AND
CHAIN OF CUSTODY RECORD*
Reference Document I\-. 3 1 2 8 1 7
Page 1 of __
Samples Shipment Date _7___':i -I -0 2___ Bill to s_ ~b tl:__Zj_QJ>_66 ec_l)2, 6-c)
Lab Destination 8 / 745 m fL_ }[; t:Cfv/t I 5ld1rc1i--·--;
Lab Contact g / ( /['I) L 1} I si e___ ' --------------i
Project Contact/Phone 12 7°'-/ i3 C; CY '(( Report to: 1~ .5 i)r? 4 !Ybk li't, S. ____________ 1
Carrier/Waybill No. 13 3L;z__QJ:J.,--,=-::c---.------_)-<No~v."/I< p"\/ __ ---::
ONE CONTAINER PER LINE --~--
Sample 14 Sample 15 Date/Time 16 Container 1' Sample 1 E p,.... 19 Requested Testing 20 Condition on 21 Disposal 22
Number Description/Tvce Collected Tv0e Volume servative
bY01,)()()/ C Uf?.uvl'/._, A /r,1 9-1-5 2. 41te,c.. ;;_ )L
I'll/I IC)3o tJ<h?5'5 IL
&Y:o3o9ol C
:--Y:o voc;o/ C ' V ( ,, \ V \ ,I ~ J
\ I
\ I
\/ / ;· I I I
X V 1/ I
I I
I \ /\ J\ I J / ,
Program
~voe. Mt I t"d t2.S
1
\/,/
\ /
\/ ,x
I \
Receipt Record No.
2 °L (01L -Ff~ 7 / 2.../.1,._ J
.---'. ' .. i ' ' .. ·,: 't:-,:,· . , .. •.
\ V .
,. . . .
• I}>'•:•, -.. . . :· " . '
. '
·.,; .· ,, -., . r (
< ' " < < I v \ V \ \ V , ... / \i <
Ii <
' f:. e 1-c:VI-I'-&; k,,, ----;/4 ~e11v4 f S T;,;;fc; ,;' cer/411 ~ £, < Special Instructions: 23 fJ (p,qse , " r , . /(j .,Ja S' f:.d ..-,f'-,(s _.,,,/( :
Possible Hazard ldentificat;i9n: 24 Sample Disposal: 25 • -... <
-·-· Non-hazard :::.J Flammable . .J Skin Irritant fJ Poison B i.J Unknown~ Return to Ciient)U Disposal by Lab J Archive ----· ·-··-... (mos.)
Turnaro_LJnd Time_Required: 2~)-J I ~Leve1;_27
111.,.:.i Normal .J Rush ...I 5 fW . 11. . ...J Project Soecific (specify): .. ------------. -----· ---·
1 . Relinquished by~ je; f, Date:_,-,'.,'3O 1. Received by 28 ~ d Date: ·-·-------(Signature/Affiliation) 7, ,A 1-t/'" f X-0 Time: q -/ -7 / !S1gnature/Aff11iation) -e _V Time: -----------
I ' 2. Relinquished by I Date: 2. Received by~ -:l,,/ //I Date:_'i/..7 ,/ '2 L_ Time: (Signature/ Affiliation) (S1gnature/Aff1hation) ~ r v ~ f',1rt--/C.. Time: (fi) I.S:.
3. Relinquished by Date: 3. Received by Date:
(Signature/ Affiliation) Time: (Signature/ Aff1bation I Time: -----------
Comments: 29
__,,. "'---I -IE J<. s-;:i.;,,~ --· ----·------· -- -- -·--
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
@ INTERNATIONAL TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
CERTIF1CATE OF ANALYSIS
RECEIVED
MAR 1 7 1993
IT Corporation March 16, 1993
312 Directors Drive
Knoxville, TN 37923
Attn: Mike Sturdevant
Job Number: ITEK 53448 P.O. Number: 408668.19.10
This is the Certificate of Analysis for the following samples:
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
02/19/93
Four (4)
Water -three (3), Trip Blank -one (1)
On 02/19/93, three (3) water samples and one (I) trip blank arrived at the ITAS-Knoxville, Tennessee,
laboratory from IT Corporation, Knoxville, Tennessee, in support of the National Starch project. The list
of analytical tests performed, as well as date of receipt and analysis, can be found in the attached report.
II. Analytical Results/Methodology
The analytical results for this report are presented by analytical test. E.ach set of data will include sample
identification information and the analytical results. Please note that the data are not blank corrected.
The samples were analyzed for Target Compound List (TCL) volatiles and semivolatiles by gas
chromatography/mass spectroscopy (GC/MS) in accordance with the EPA CLP 2/88 Statement of Work.
Reviewed and Approved:
Alyce . Moore
Laboratory Manager
Amencan Council ol Independent Laboratmies
Intemat1onal Associalion o! Environmental Testing Lcboratones
.ll...."Tiencan Assocmtion tor Laboratory Accreditallon
IT Analytical Services, 5815 Middlebrook Pike, Knoxville, TN 37921 68\.1-89
IT Cotp0ration
March 16, 1993
Client Project ID: National Starch
II. Analytical Results/Methodology (continued)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53448
The samples were analyzed for Target Analyte List (TAL) metals by cold vapor atomic absorption
spectroscopy (CV AA), graphite furnace atomic absorption spectroscopy (GFAA), and inductively coupled
plasma spectroscopy (ICP) in accordance with the EPA CLP Il.MOl Statement of Work.
Chemical oxygen demand (COD) was measured using the EPA approved HACH procedure, HACH Water
Analysis Handbook, HACH Chemical Company, 1980.
The samples were analyzed for chloride based on EPA method 325.3.
The samples were analyzed for total Kjeldahl nitrogen (TKN) based on EPA method 351.3.
The total dissolved solids (TDS) content of the samples was determined using EPA method 160.1.
m. Ouality Control
The volatiles analyses were performed by purge and trap with a J&W DB-624 megabore column on a
Finnigan GC/MS/DS. The samples analyses went well. Commonly detected target analytes included
acetone, chlorinated hydrocarbons, and some aromatic hydrocarbons. Ex:03-2/93 and Ex:04-2/93 required
dilution for acetone with good agreement between the original analyses and dilutions. Background levels of
methylene chloride were seen in the method blank, trip blank and some of the samples. There were no
problems seen in final data review.
The semivolatiles analyses were performed by direct injection of sample extract on a Restek XTI-5
capillary column on a Finnigan 4500 GC/MS/DS. The sample analyses went well. Two acid surrogate
recoveries were low and outside method limits in Ex:04-2/93. There was insufficient sample for
reextraction and so no determination could be made as to the cause of poor surrogate recoveries. Acid
extractable targets were reported for EX0I-2/93 and Ex:03-2/93, but none were seen in EX04-2/93.
However, it is possible that phenolic species were present in Ex:04-2/93 and not detected owing to the poor
acid surrogate recoveries in this sample. There were no other problems seen in final data review.
The samples were digested on 03/03/93 for ICP and 03/03/93 for GFAA. The samples for mercury
analysis were prepared just prior to analysis. The CV AA analysis for mercury was performed on
03/08/93; the GFAA analyses for arsenic, lead, selenium, and thallium were performed on 03/04-03/08/93;
the remaining metals were analyzed by ICP on 03/04/93. All run QC was acceptable. Slightly elevated
detection limits for EX03-2/93 and Ex:04-2/93 were due to matrix interferences. No other problems were
encountered.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
m. Quality Control (continued)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
The COD of the samples was measured using the reactor digestion method followed by titration with
ferrous ammonium sulfate. No problems were encountered.
The samples were analyzed for chloride using the mercuric nitrate titrimetric procedure with HACH
reagents. No problems were encountered.
The samples were prepared for TKN analysis by acid digestion/distillation using a micro-Kjeldahl system.
The distillate was analyzed by Nesslerization using HACH reagents. No problems were encountered.
The IDS content of the samples was determined gravimetrically by filtration and evaporation of the filtrate
to a constant weight at 180°C. No problems were encountered.
3
,,,,,:_. ,.,,
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX0l-2/93
Lab Sample ID: VV6362
Co1DD0!!!1d
chlol'OIDf"'.fb1ne
btwww Jhme
vinyl chloride
chlorocthane
methylene chloride
acetone
carbon disulfide
I, 1-dichlorocthene
I, 1-dichlorocthane
1,2-dichlorocthene (total)
chloroform
1,2-dichlorocthane
2-butanone
I, l, 1-trichlorocthane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in i<g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-dichloropropane
10 u cis-1,3-dichloropropene
10 u trichloroethenc
10 u dibromochloromethane
2 BJ I, I ,2-trichlorocthane
75 benz.ene
5 u trans-1,3-dichloropropene
5 u bromoform
5 u 4-methyl-2-pentanone
5 u 2-hexanonc
5 u tetrachlorocthene
20 1,1,2,2-tetrschlorocthane
10 u toluene
5 u chlorobenz.ene
5 u ethylbenz.ene
10 u styrene
5 u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53448
Concentrati!!l!
35
5 u
5 u
5 u
5 u
5 u
5 u
5 u
10 u
10 u
5 u
5 u
13
5 u
5 u
5 u
2 J
U Compound was analyud for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
B Analyte was found in the blank as well as the sample.
Date of Analysis: 02/24/93
Dilution Factor: 1.0
4
,,;,.: t ;,,,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
D
m
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX03-2/93
Lab Sample ID: VV6363
Coml!QUnd
chloromethane
bromomelhane
vinyl chloride
chloroetbane
methylene chloride
acetone
carbon disulfide
I , 1-dichloroethene
I , 1-dichloroethane
1,2-dichloroethene (total)
chloroform
1,2-dicbloroethane
2-butanone
I , I , I -trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in 1<g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-dichloropropane
10 u cis-1,3-dichloropropene
10 u tricbloroetbme
10 dibromochloromotbane
2 BJ I, 1,2-trichloroetbane
1,300 D benzene
3 1 tnns-1,3-dichloropropene
s u bromoform
s u 4-methyl-2-pentanone
s u 2•hexanone
s u tetrachloroethene
23 l, 1,2,2-tetncbloroethane
10 u toluene
s u chlorobenzene
s u ethylbenzene
10 u styrene
s u xylenes (total)
IT ANALYTICAL SERVICES
58 I 5 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
120
s u
s u
s u
s u
s u
s u
s u
10 u
10 u
s u
s u
58
s u
s u
s u
10
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
1 Indicates an estimated value less than the detection limit.
B Analyte was found in the blank as well as the sample.
D Compound analyzed at a secondary dilution factor.
Date of Analysis: 02/24/93
Dilution Factor: 1.0
s
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX04-2/93
Lab Sample ID: VV6364
Compound
chloromethane
bromomelhane
vinyl chloride
chloroethane
methylene chloride
acetone
carbon disulfide
1, 1-dichloroethene
1, 1-dichloroethane
1,2-dichloroethene (total)
chloroform
1,2-dichloroethane
2-butsnone
l, l, l ·trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in 14g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-dichloropropane
10 u cis-1,3-dichloropropene
28 trichloroethme
7 J dibromochlorometbaoe
s u 1, 1,2-trichloroethane
1,200 D ben'lffle
76 trans-1,3-dichloropropene
s u bromoform
s u 4-methyl-2-pentsnone
s u 2-hexanone
s u tctrachloroethenc
4 J 1, l ,2,2~oroethane
10 u toluene
s u chlorobenzene
s u elhylbenzene
10 u styrene
s u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
s u
s u
s u
s u
s u
2 J
s u
5 u
10 u
10 u
s u
s u
s
s u
2 J
s u
2 J
u
J
B
D
Compound was analy:r.ed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value lC88 than the detection limit.
Analyte was found in the blank as well as the sample.
Compound analy:r.ed at a secondary dilution factor.
Date of Analysis: 02/25/93
Dilution Factor: 1.0
6
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
a
0
D
0
0
0
I
ti
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: Trip Blank
Lab Sample ID: VV636S
Comoound
chloromethane
bromomethane
vinyl chloride
chloroethane
methylene chloride
acetone
can,on disulfide
l, 1-dichloroethene
I, 1-dichloroethane
1,2-dichloroethene (total)
chloroform
1,2-dichloroethane
2-butanone
I, I, I -trichloroethane
carbon tetnu:hloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in l'g/Iiter (ppb)
Sample Matrix: Water
Concentratiog Compound
10 u 1,2-dichloropropane
10 u ci1• 1,3--dichlo1opi0pene
10 u trichloroethme
10 u dibromochloromethane
4 BJ 1,1,2-trichloroethane
10 u benz.ene
s u tnma-1,3-dichlo,op,opene
s u bromoform
s u 4-methyl-2-pentanone
s u 2-hexanone
s u tetnu:hloroethene
s u I, 1,2,2-tctrachloroethane
10 u toluene
s u chlorobenz.ene
s u ethylbenz.ene
10 u styrene
s u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
s u
s u
s u
s u
s u
s u
s u
s u
10 u
10 u
s u
s u
s u
s u
s u
s u
s u
u
J
B
Compound was analy:r.ed for but not detected. 1he number is the detection limit for the aample.
lndicatea an estimated value lesa than the detection limit.
Analyte was found in the blank as well as the sample.
Date of Analysis: 02/25/93
Dilution Factor: 1.0
7
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: Method Blank 1
Lab Sample ID: VB0224
Compound
chloromethane
bromometbane
vinyl chloride
chloroethane
methylene chloride
acetone
carbon dieulfide
1, 1-<licbloroethene
1, 1-<lichloroethane
1,2-<lichloroethene (total)
chloroform
1,2-<licbloroethane
2-butanone
I, I, 1-tricbloroethane
carbon tetrachloride
vinyl acetate
bromodicbloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-<lichloropropane
10 u cis-1,3-<lichloropropme
10 u tricbloroediene
10 u dibromocbloromethane
2 J 1,1,2-tricbloroethane
10 u benzene
s u trarui-1,3-<licbloropropene
s u bromoform
s u 4-methyl-2-pentanone
s u 2-bexanone
s u tetracldoroethme
s u 1,1,2,2-tetracldoroethane
10 u toluene
s u chlorobenzene
s u ethylbenzene
10 u styrene
s u xylenee (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
s u
s u
s u
s u
s u
s u
s u
s u
10 u
10 u
s u
s u
s u
s u
s u
s u
s u
U Compound was analyl.ed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Analysis: 02/24/93
This method blank applies to the following samples: EX0l-2/93 and EX03-2/93.
8
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
VOLATILE ORGANIC TARGEf COMPOUND UST
Client Sample ID: Method Blank 2
Lab Sample ID: VB02242
Compound
chloromethane
bro mo methane
vinyl chloride
chloroethane
methylene chloride
acetone
carbon disulfide
l , 1-dichloroethene
I , 1-dichloroethane
1,2-dichloroethene (total)
chloroform
1,2-dichloroethane
2-butanone
I , I, I -trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
Results in 14g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-dichloropropane
10 u cis-1,3-dichloropropene
10 u trichloroethene
10 u dibromochloromethane
3 1 I, 1,2-trichloroethane
10 u benzene
5 u trans-1,3-dichloropropene
5 u bromoform
5 u 4-methyl-2-penlanone
5 u 2-hexanone
5 u lelrach!oroethene
5 u I, 1,2,2-tetrachloroethane
10 u toluene
5 u chlorobenzene
5 u ethylbenzene
10 u styrene
5 u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53448
Concentration
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
10 u
10 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Date of Analysis: 02/24/93
This method blank applies ti, the following samples: EX03-2/93 DL, EX04-2/93, EX04-2/93 DL and Trip Blank.
DL -Dilution.
9
IT Corporation
March 16, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
WATER SURROGATE PERCENT RECOVERY SUMMARY
•
DL
Toluene-OS
Client Sam11le ID (88-110%)*
EX0l-2/93 104
EX03-2/93 103
EX03-2/93 DL 104
EX04-2/93 107
EX04-2/93 DL 104
Trip Blank 100
Method Blank I 104
Method Blank 2 99
Values in parentheses represent required QC limits .
Dilution
VOLATILE
Bromofluorobenzene 1,2 Dichloroethane-04
(86-!15%)* (Z6-114%)*
105 79
102 84
IOI 99
105 94
!OS 93
97 94
107 90
100 93
10
,,H,;.' /<••
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX0l-2/93
Lab Sample ID: VV6366
Compound
phenol
bis(2-chloroethyl)ether
2-chlorophenol
1,3-<lichlorobenz.ene
1,4-<lichlorobenzene
benzyl alcohol
1, 2-<lichlorobenzene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hexachloroethane
nitrobenzene
isopborone
2-nitrophenol
2,4-dimethylphenol
benzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-chloroethoxy)methane
38 2,4-dichlorophenol
10 u 1,2,4-trichlorobenzene
10 u naphthalene
10 u 4-chloroaniline
10 u hexachlorobutadicne
10 u 4-chloro--3-methylphenol
10 u 2-methylnaphthalene
10 u hexachlorocyclopentadiene
4 J 2,4,6-trichlorophenol
10 u 2,4,5-trichlorophenol
10 u 2-chloronaphthalcne
10 u 2-nitroaniline
10 u dimethyl phthalate
10 u acenaphthylene
10 u 2,6-<linitrotoluene
so u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentratiog
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
so u
10 u
so u
10 u
10 u
10 u
u
J
Compound was analyi.ed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Extraction Date:
Analysis Date:
Dilution Factor:
02/22/93
03/02/93
1.0
11 \EiUVOA\Ta-FDI 4'1Wl
IT Corporation
March 16, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
SEMIVOLATILE TARGET COMPOUND UST (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: EX0l-2/93
Lab Sample ID: VV6366
Compound Concentration Compound Concentration
3-nitroaniline 50 u anthracene 10 u
acenaphthene 10 u di-n-butylphthalate 10 u
2,4-<linitrophenol 50 u fluoranthene 10 u
4-nitrophenol 50 u pyrene 10 u
dibenzofuran 10 u butylbenzylphthalate 10 u
2,4-dinitrotoluene 10 u 3 ,3' -dichlorobenzidine 20 u
diethylphthalate 10 u benm(a)anthracene 10 u
4-chlorophenyl-phenylether 10 u chrysene 10 u
fluorcne 10 u bis(2-<ethylhexyl)phthalate 2 J
4-nitroaniline 50 u di-n-octylphthalate 10 u
4,6-dinitro-2-methylphenol 50 u ben7.0(h )fluoranthene 10 u
n-nitrosodiphenylamine1 10 u benzo(k)fluoranthene 10 u
4-bromophenyl-phenylether 10 u benm(a)pyrene 10 u
hexachlorobenzene 10 u indeno( 1,2,3-cd)pyrene 10 u
pentachlorophenol 50 u dibenm(a,h)anthracene 10 u
phenanthrene 10 u benm(g,h,i)perylene 10 u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
Dilution Factor: 1.0
12 ISDIIYOA\TCLFIM 411:wl
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX03-2/93
Lab Sample ID: VV6367
Coml!Qund
phenol
bis(2-chloroethyl)ether
2-chlorophenol
1,3-dichlorobenzene
1,4-dichlorobenzene
benzyl alcohol
1,2-dichlorobenzene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hcxachloroethane
nitrobemene
isophorone
2-nitrophenol
2,4-dimethylphenol
benzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-chloroethoxy)methane
82 2,4-dichlorophenol
10 u 1,2,4-tricbl"""-zme
10 u naphthalene
10 u 4-chloroaniline
10 u hexachlorobutadiene
10 u 4-chloro-3-methylphenol
10 u 2-methylnaphthalene
10 u hexachlorocyclopentadiene
65 2,4,6-trichlorophenol
10 u 2,4,5-tricblorophenol
10 u 2-chloronaphthalene
10 u 2-nitroaniline
10 u dimethyl phthalate
10 u acenaphthylene
10 u 2,6-dinitrotoluene
52 u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentrati!!ll
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
52 u
10 u
52 u
10 u
10 u
10 u
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Extraction Date:
Analysis Date:
Dilution Factor:
02/22/93
03/02/93
1.0
13 \SBOVOA'fl'CLFDI 411"'2
IT Corporation
March 16, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
SEMIVOLATILE TARGET COMPOUND UST (continued)
Results in /lg/liter (ppb)
Sample Matrix: Water
Client Sample ID: EX03-2/93
Lab Sample ID: VV6367
Compound Concentration Compound
3-nitroaniline 52 u anthracene
acenaphthene 10 u di-n-butylphthalatc
2,~trophenol 52 u fluoranthme
4-nitrophenol 52 u pyrene
dibenzofuran 10 u butylbenzylphthalatc
2,4-dinitrotoluene 10 u 3 ,3 • -dichlorobenzidine
diethylphthalate 10 u benzo(a)anthracene
4-chlorophenyl-phenylether 10 u chrysene
fluorene 10 u bis(2-ethylhexyl)phthalatc
4-nitroaniline 52 u di-n-octylphthalatc
4,6-dinitro-2-methylphenol 52 u ben7.0(b )fluoranthene
n-nitrosodiphenylamine' 10 u benz.o(k)fluoranthenc
4-bromophenyl-phenylether 10 u benzo(a)pyrene
hexachlorobenzene 10 u indeno( 1,2,3-al)pyrene
pentachlorophenol 52 u dibenzo(a,h)anthracene
phenanthrene 10 u benm(g,h,i)perylene
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
Dilution Factor: 1.0
14
Concentration
10 u
10 u
10 u
10 u
10 u
21 u
10 u
10 u
3 J
10 u
10 u
10 u
10 u
10 u
10 u
10 u
\Sl3MIYOA\Ta..PDI 411S/9'l
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX04-2/93
Lab Sample ID: VV6368
Compound
phenol
bis(2-chloroethyl)ether
2-chlorophenol
l ,3-<lichloroben7.cne
1,4-dichlorobenzene
benzyl alcohol
1,2-<lichlorobenzene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hexachloroethane
nitrobenz.ene
isophorone
2-nitrophenol
2,4-dimethylphenol
bcnzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in l'g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-chloroethoxy)methane
12 2,4-dichlorophenol
10 u 1,2,4-trichlorobcnz.ene
10 u naphthalene
10 u 4-chloroaniline
10 u hexach!orobutadiene
10 u 4-ch!oro-3-methylphenol
10 u 2-methylnaphthalene
10 u hexachlorocyclopentadiene
10 u 2,4,6-trichlorophenol
10 u 2,4,S-trich!orophenol
10 u 2-chloronaphthalene
10 u 2-nitffl8nmne
10 u dimethyl phthalate
10 u acenaphthylene
10 u 2,6-<linitrotoluene
so u
IT ANALTTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
so u
10 u
so u
10 u
10 u
10 u
u
J
Compound was analy:r.od for but not detected. The number is the detection limit for the aample.
Indicates an estimated value less than the detection limit.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
Dilution Factor: 1.0
IS ~A\Ta..PDI Afllffl:
IT Corporation
March 16, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
SEMIVOLATILE TARGET COMPOUND USf (continued)
Results in l'g/liter (ppb)
Sample Matrix: Water
Client Sample ID: EX04-2/93
ub Sample ID: VV6368
Comoound Concentration Compound
3-nitroaniline so u anthraccnc
acenaphthene 10 u di-n-butylphthalate
2,4-dinitrophenol so u fluoranthene
4-nitrophenol so u pym,e
dibenzofuran 10 u butylbenzylphthalate
2,4-dinitrotoluene 10 u 3 ,3 '-dichlorobenzidine
diethylphthalate 10 u benm(a)anthraccnc
4-chlorophenyl-phenylether 10 u chrysene
fluorcne 10 u bis(2-ethylhexyl)phthalate
4-nitroaniline so u di-n-octylphthalate
4,6-dinitro-2-methylphenol so u benm(b )fluoranthene
n-nitrosodiphenylamine' 10 u benm(k)fluoranthene
4-bromophenyl-phenylether 10 u benzo(a)pyrene
hexachlorobenzene 10 u indeno{l,2,3-ro)pyrene
pentachlorophenol so u dibenm(a,h)anthracene
phenanthrene 10 u benzo(g,h,i)perylene
u
J
Compound was analyl.ed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Extraction Date:
Analysis Date:
Dilution Factor:
02/22/93
03/02/93
1.0
16
Concentration
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
\IIIMIYOATl'C...PDI 4f1Wl
"H,;.' ,...,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Coiporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: Method Blank
Lab Sample ID: Bl.3195
Compound
phenol
bis(2-ch!oroethyl)ether
2-chlorophenol
1,3-<lichlorobenzene
1,4-<lichlorobenzene
benzyl alcohol
1,2-<lich!orobenzene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamino
heuchloroethsne
nitrobenz.ene
isophorone
2-nitrophenol
2,4-<limethylphenol
benzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-chloroethoxy )methane
10 u 2,~chlorophenol
10 u 1,2,4-trichlorobenz.ene
10 u naphthalene
10 u 4-chloroaniJine
10 u heuch!orobutadiene
10 u 4-chloro-3-methylphenol
10 u 2-methylnaphthalene
10 u heuch!orocyclopentsdiene
10 u 2,4,6-trichlorophenol
10 u 2,4,5-trichlorophenol
10 u 2-ch!oronaphthalene
10 u 2-nitroaniline
10 u dimethyl phthalate
10 u acenaphthylene
10 u 2,6-<linitrotoluene
50 u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
50 u
10 u
50 u
10 u
10 u
10 u
u
J
Compound was analy7.IXI for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
17 \SDUYOA\TCLPIM 4/ll/92
IT Corporation
March 16, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53448
SEMIVOLATILE TARGET COMPOUND UST (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: Method Blank
Lab Sample ID: Bl.3195
Coml!Qund Concentration Compound
3-nitroaniline so u anthracene
acenaphthene 10 u di-n-butylpbth•l•te
2,4-<linitrophenol so u fluoranthene
4-nitrophenol so u pyrene
dibenmfuran 10 u butylbenzylphthalate
2,4-<linitrotoluene 10 u 3 ,3 '-dichlOJObenzidine
diethylphthalate 10 u benzo(a)anthracene
4-chlorophenyl-phenylether 10 u chryaene
fluorene 10 u bis(2-dhylhexyl)phthalate
4-nitroaniline so u di-n-octylphthalate
4,6-dinitro-2-methylphmol so u benzo(b )fluoranthme
n-nitrosodiphenylamine' 10 u benzo(k)fluoranthene
4-bromophenyl-phenylether 10 u benzo(a)pyrene
hexachlorobenzene 10 u indeno( 1,2,3-cd)pyrene
pentachlorophenol so u dibenzo(a,b)anthracene
phenanthrene 10 u benzo(g,h,i)perylene
u
J
Compound was analyud for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
18
Concentration
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
\.1111DYOA\Tt1JIIIII 4'JS,92
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
WATER SURROGATE PERCENT RECOVERY SUMMARY
Nitro-2-Fluoro-
Benz.enc-OS Biphenyl
Client Samele ID (35-114:!i}* (43-116%}*
EXOl-2/93 72 77
EX03-2/93 SI 60
EX04-2/93 78 75
Method Blank 73 73
*Values in parentheaes ,ep,eaenl ,-equired QC limits.
••values outside requiml QC limits.
SEMI-VOLATILE
2,4,6-
Terphenyl-2-Fluoro-Tribromo-
014 Phenol-OS Phenol Phenol
(33-141 %}* (10-94:!il* (21-100 l!i}* (10-123:!i}*
80 31 53 104
76 37 61 116
75 0 •• 6 •• 60
71 26 40 76
19 \SEMIVOA\TCLnM 411W2
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX0l-2/93
Lab Sample ID: VV6372
Compound
aluminum
antimony
arsenic
barium
beryllium
cadmium
METALS TARGET ANALYTE usr
Results in 1<g/litcr (ppb)
Sample Matrix: Water
Concentration Compound
40.0 u magnesium
30.0 u manganeoe
2.0 u mercury
68.2 B nickel
1.0 u potassium
s.o u selenium
calcium 125,000 silver
chromium 12.0 sodium
cobalt 20.0 u thallium
copper 13.1 B vanadium
iron 187 zinc
lead 2.0 u
Date of Digestion: 03/03/93
Date of Analysis: 03/04/93 (ICP), 03/04 -03/08/93 (GFAA), 03/08/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Conccntratiog
8,990
222
0.20 u
20.0 u
2,050 B
2.0 u
s.o u
12,SOO
2.0 u
10.0 u
35.3
U Compound was analy7.Cd for but not detected. The number is the detection limit for the sample.
B Value grestcr than instrument detection limit, but less than contract required quantitation limit.
20 \SEIOVOA\TC..JIDI 41lll92
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX03-2/93
Lab Sample ID: VV6373
Compound
aluminum
antimony
anenic
barium
beryllium
cadmium
METALS TARGET ANALYTE UST
Results in ,,glliter (ppb)
Sample Matrix: Water
Concentration Compound
40.0 u magnesium
30.0 u manganme
2.0 u mercury
166 B nickel
1.0 u potusium
s.o u selenium
calcium 217,000 silver
chromium 10.0 u sodium
cobalt S8.S thallium
copper 12.S B vanadium
iron 13,100 zinc
lead 2.0 u
Date of Digestion: 03/03/93
Date of Analysis: 03/04/93 (ICP), 03/04 -03/08/93 (GFAA), 03/08/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
37,700
3,950
0.20 u
20.0 u
2,300 B
4.0 u
s.o u
18,900
2.0 u
10.0 u
11.2 B
U Compound was analyt.ed for but not detected. The number is the detection limit for the aample.
B Value greater than instrument detection limit, but less than contract required quantitation limit.
21 ISEMIVOA.m::L.PIM 411319'2
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: EX04-2/93
Lab Sample ID: VV6374
Compound
aluminum
antimony
anenic
barium
beryllium
cadmium
METALS TARGET ANALYTE UST
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Compound
40.0 u magneeium
30.0 u ,man~
2.0 u mercury
37.3 B nickel
1.0 u potassium
5.0 u selenium
calcium 131,000 silver
chromium 10.0 u sodium
cobalt 20.0 u tballium
copper 10.0 u vanadium
iron 1,870 zinc
lead 2.0 u
Date of Digestion: 03/03/93
Date of Analysis: 03/04/93 (ICP), 03/04 -03/08/93 (GFAA), 03/08/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53448
Concentration
36,000
4,290
0.20 u
20.0 u
2,160 B
4.0 u
5.0 u
12,000
2.0 u
10.0 u
13.0 B
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
B Value greater than instrument detection limit, but less than contract required quantitation limit.
22 \SIMIYOA\TC...FDI 411!.91
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Sample ID: Method Blank
METALS TARGET ANALYTE UST
Results in µg/liter (ppb)
Sample Matrix: Water
Lab Sample ID: PBWC5482/PBWil788
Compound Concentration Compound
aluminum 40.000 u magnesium
antimony 30.000 u manganese
arsenic 40.000 u mercury
barium 2.000 u nickel
beryllium J.000 u potaasium
cadmium 5.000 u selenium
calcium 30.000 u silver
chromium 10.000 u sodium
cobalt 20.000 u thallium
copper. 10.000 u vanadium
iron 23.620 B zinc
lead 40.000 u
Date of Digestion: 03/03/93
Date of Analysis: 03/04/93 (ICP), 03/04 -03/08/93 (GFAA), 03/08/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Concentration
30.0000 u
2.000 u
0.200 u
20.000 u
1,000.000 u
60.000 u
5.000 u
200.000 u
40.000 u
10.000 u
6.850 B
U Compound was analyzed for but not detected. The number is the detection limit for the ssmple.
B -Value greater than instrument detection limit, but leas than contract required quantitation limit.
23 ISBll!VOA.n'a..FD( 4113192
IT Corporation
March 16, 1993
Client Project ID: National Starch
Client Project ID: Method Blank
lab Sample ID: PBWI1790
Compound
arsenic
lead
selenium
thallium
Date of Digestion: 03/03/93
Date of Analysis: 03/04 • 03/08/93 (GFAA)
MEfALS ANALYSIS
Results in 1<g/litcr (ppb)
Sample Matrix: Water
Result
2.000 U
2.000 U
2.000 U
2.000 U
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
U · Compound was analy,:ed for but not detected. 1be number is the detection limit for the sample.
24 \SEMIYOAna..FIM 411:wl
MJ_:t)1•>
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
, I
1,
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Analysis Date:
CHEMICAL OXYGEN DEMAND ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Clie~• Sample ID Lab Sample ID
Method Blank
EX0l-2/93
EX00-2/93
EX04-2/93
02/23/93
VV6375
VV6376
VV6377
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
•
73.0
239.0
65.0
u • Compound was analyud for but not detected. The number is the detect.ion limit for the asmple.
A method blank is not applicable for this analysis .
25 \SIMIVOA\TCLFRM 4113192:
IT Corporation
March 16, 1993
Client Project ID: National Starch
Analysis Date:
Client Sampl-. ID
Method Blank
EX0l-2/93
EX03-2/93
EX04-2/93
02/23/93
CHLORIDE ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Lah Samnl-. ID
P4781
VV6369
VV6370
VV6371
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Result
1.0
82.0
210.0
130.0
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
26 '313MJVOAYl'aJIDI 4'13Rl
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 16, 1993
Client Project ID: National Starch
Analysis Date:
TOTAL KJELDAHL NITROGEN ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Client Sample ID I.ab Sample ID
P4777
VV637S
VV6376
VV6377
Method Blank
EX0l-2/93
EX03-2/93
EX04-2/93
02/23/93
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Result
0.1 U
0.3
1.8
1.7
I U -Compound was analy:r.ed for but not detected. The number is lhe detection limit for lhe sample.
I
I
I
I
I
I
I
27 \Sl!MIYOA.'1'0-PUf 4/IWl
IT Corporation
March 16, 1993
Client Project ID: National Starch
Analysis Date:
Client Sample ID
Method Blank
EX0!-2/93
EX03-2/93
EX04-2/93
02/22/93
TOTAL DISSOLVED SOUDS ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Lab Sample ID
P4774
VV6369
VV6370
VV6371
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53448
Result
I U
508
884
1,270
U • Compound was analyud for but not detected. The number is the detection limit for the aample.
28 \SIMIYOA\TCLPD( 411!.19:Z
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-------------rn INTERNATIONAL ANALYSIS REQUEST AND
TECHNOLOGY CHAIN OF CUSTODY RECORD*
CORPORATION /,. / c..t t, #I? ilWd Sr,v,
Projtct Name/No 1 .L/08(:./g. 15" /C, Samples Shipment Date 7 J-I £-13
Sample Team Members 2 /. //cN cl IE y Lab Destination 8 I 771 S . t1'J PL
Lab Contact 9 S.:J:<>/t f-14~,<.5
$,·l~v#f Project Contact/Phone 120.o_<d ,fj'_7:_666/ _
Profit Center No. 3
Project Manager 4 /11,/(E
Purchase Order No. 6
Required Report Date 11 M-11:Jn A-(
Sample 14
Number
S ecial Instructions: 23
carrier/Waybill No.~3 ___ ~_
------Reference Document No. 3 2 2 8 U j
Page 1 of __
Bill to 5 ,,A/,1 /,0..v,1/. ST;4 re I;'
-)__.'t,# ?"C.---.j,:f'6(f. /</ /tJ
Possible Hazard Identification: 24
Non-hazard ! j Flammable .J Skin Irritant .J Poison B .J Unknown ~ Sample Disposal: 25
Return to Client ..i Disposat by Lab.la
Turnaround Time Required: 26
Nonmal Rushl,J
1 . Relinquished by 2s
(Signature/ AffiliBtion)
2. Relinquish
(Signature/Affiliation)
3. Relinquished
!Signature/ Affiliation)
Comments: 29
QC evel: 21
I. 11 . .J 111.'.J Pro·ect
1 . Received by 2
I Stgnature/ Affihation)
2. Received by
(Signature/ Alf1l1etionJ
3. Received by
(Signature/ AffihAtion)
Archive (mos)
Date:
Time:
Date:
Time:
Date:
Time:
00 INTERNATIONAL
TECHNOLOGY
CORPORATION . ,
ANALYSIS REQUEST AND
CHAIN OF CUSTODY RECORD*
Reference Document No. 3 2 2 8 7 !:l
Page 1 of
fl,? -/, 'o,,_, ,,, ( Sr ,t ,e c 4
Projtct Name/No. 1 r./086fJ'. /</_/0 Samples Shipment Date 7 2 -/,J"->3 Bill to 5 ,A/r,/,',,,y,? / s/,,,_,<, c ,{
Sample Team Members 2 ·--;;:-#E.Nd/o/ Lab Destination 8 / "?J15 #1/'L
Profit Center No. 3 Lab Contact 9 Sro# L,:s_ . -;:t;6 -# y-a?6t:J?k /o
Project Manager4 M']i/(c sk/4,/~,.,;:.Project Contact/Phone _12_(2°Y) 6--?_.,)-✓c'// 10 /,'" . n It Report to: __ _ ~e,_,, ~ r',,f c _
Purchase □rderNo.6 __ __ Carrier/WaybillNo._13____ ____________ _____ _7 ________ 7 ____ _
-~'1,.,_"'7-: _#(6~A'<"_.5 Required Report Date 11 ;v'c,.<,., _,, ( ONE CONTAINER PER LINE
Sample 14
Number
£-Yo/ C
Sample 15
Dncrlndnn/T"""
Date/Time 16 Conteiner11 Sample H Pre-19
Collected T""" Volume --
2-llf-4..5 C JOLO It,,
Exol h r /11<:C:
I
Special Instructions: 23 /1;1,, ,/ c'Jur5J.~,r..,_5 < 11 I I
Possible Hazard Identification: 24
Aaquaeted THting 20
-rem
r ..,.., ,.,--n,..,
.
Non-hazard ! J Flammable .J Skin Irritant .J Poison B .J Unknown Jr Sample Disposal: 25
Return to Client .i Disposal by Lab.kl Archive
Turnarq4Ad Time Required: 26
Normal lli Rushl..J I QC Level: 21 ,.·a ".J 111 . .,J Project Specific (sn..c;AA-"
(mos.)
1 . Relinquished by 28.._./ , / / /
(Signeture/Affilfstion) ...-/ ~ /(e~-vj Date:
Time:
1 . Received by 28 _ --;7 _ /
[Signeture/Afflltation) ~·~ Date: 2 -/~-Ki
Time:
2. Relinquish~ /VOi ~
(&gnatuce/Affil,eO<fnJ / -/1-.~ ~V! <;: /+~ \
3. Relinquished'by___
(Signeture/Affiltation} -------
Comments· 29 1 · 1 · u~e Jfl-rtf"· re
Date:
Time:
Date:
Time:
--- -- - - - -
2. Received by /,l, /l
[SignaUJre/Alf1l1nt1onJ AJ? A/ i
3. Received by
[Signature/ Affll1ntion)
.
, Date:_ ..:i. -/f' -?'"2...
Time: cv 9 CJO
Date:
Time:
- - - - -..-r: lllif,<../-tilllil -
-------------rn INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYSIS REQUEST AND -------Reference Document No. S 2 2 8 / 'j
-/ CHAIN OF CUSTODY RECORD*
)/,1--/ic ,,_,,1 / S74a l 4
Proje::t Name/No 1 '/cB/{g ,Jy_ /0 Samples Shipment Date 7 2-1,r-93
Sample Team Members 2 I, #c-/ld.&-'/ Lab Destination 8 /Tr+.S . tnt:C Sib -:/I f-{::l?~t:',51. /y /C
Profit Center No. 3 _ Lab Contact 9 --¼L,/r &JJZ!l-, .>
Project Manager 4~ti't'" si,~J~',fv_f-Project Contact/Phone .12 6.6 i!. {, 3 / t,({l Report to: 10 Kt7v1 A/ PJ'/_( K.
Page3 of ._3_
Bill to 5 ,.v,r/,~-vr1/ 575tcc I:'
Purchase Order No. 6 _ _ Carrier/Waybill No._13 ___ ____ _ _ _ _ ··,,;-,,,j,i,1-.. 7i1ohfa5
Required Report Date 11 ,¼,11 ~-?--/ -· - ----- --ONE CONTAINER PER LINE .. -.. --.,. -----·
Sample 14 Sample 15 Date/Time 16 Container 1 · ISa rnple i' Pre-19 Requested THtlng 20 Co.wfltlun on 21 Dis_., 22 .
Number Deecrhmnn/T..-Collected T-Volume servathnt ..,_,ram RecaNINo.
Exo/ 6--1/rnov..,../ lu 4--/e /4.
1-t.i-9J c,/,15/,'c } L, )/.s-,,, i"'D n /k' ;./ ,,2oc / rt(_ -, 110,/~~ /030 IV
6xoJ. F ' I I I r Gvo-,. l ~ ~ '"-'ji!:1i, Jt:zr
A--15-·q_3 7 ,i '~-'.:,. bi. JIA/,1) l,C)<('oj /~ 9 yr; I
s·1-a</ _, 2-1.t·'I _3 II/ if/ 11/ t1/ !:: ,I/ 1020 J ;
\ / \ \ \ ,,....,..._ I In. ,..,,
\/ V / / , / \ ~ • 1-.l 1 • '. a t ~ r• , J ~ _,· .. ·,r ,•· '
A /\ V I I /\ /\ • ..,. . ~
/\
/ ' \. I/ \__, I / \____,. \ \ / "'--
Special Instructions: 23 i},1,y /J,,e5 f, ~,.._,,; r _,,_II JI e v/,,v l'/Je,I<
Possible Hazard Identification: 2J ' Sample Disposal: 25
' ' ' ' i 0
. ' '
1 '
! ' ' '
I ' ' ' ' '
'
'
'
Non-hazard 1..J Flammable .J Skin Irritant .J Poison B ..J Unknown ')d" Return to Client ..i Disposal by Lab Jr' Archive ' (mos J ~
Turna~~d Time Required: 26 j ~Level:27 ' ' Nonna! , RushlJ I -11 . .J 111.•..J Project Soecific (soec;r..,. u ------... i 1. Relinquished by 2~ /~ __ ,j'g, Date: 2-/5-73 1 . Received by 28 7c/Y Date: .2. -/.Y.-c;;-3:
(Signature/Affitietion) C.."?J-7 Time: .. I Signature/ Afhhation) Time: :
2. Relinquished by f-J'OT c~ ' Date: 2. Received by u/. ' Date: .,;:; -,7 -f' J (Signature/ Affilietion I ,tn.1 "-'Gll/1 Cb Time: -(Signature/Affiliation) ---/7r.,::, Time: l? 5'<70 3. Relinquished by"'--.. _) Date: 3. Received by ' Date: f&gnature/ Affiltat.Jon) Time: !Signature/ Affiliation) Time: -
Comments: 29
!TEX. MCA )(15,'91
I
I
I
I
I
I
I
I
I,
I
I
I
I
I
I
I
I
I
I
[D INTERNATIONAL
TECHNOLOGY
CORPORATION
IT Corporation
3 1 2 Directors Drive
Knoxville. TN 37923
Ann: Mike Sturdevant
Job Number: ITEK 52176
ANALYTICAL
SERVICES
CERTIFICATE OF l\NALYSIS
This is the Certificate of Analysis for the following samples:
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
08/27/92
Three (3)
Water -two (2). Trip Blank -one (I)
September IO. 1992
P.O. Number: 408668.009.60
On 08/27/92, two (2) water samples and one (I) trip blank arrived at the ITAS-Knoxville, Tennessee.
laboratory from IT Corporation, Knoxville, Tennessee in support of the National Starch project. The list of
analytical tests performed, as well as date of receipt and analysis, can be found in the anached report.
II. Analvtical Results/Methodology
The analytical results for this report are presented by analytical test. Each set of data will include sample
identification information and the analytical results. Please note that the data are not blank corrected.
The samples were analyzed for Target Compound List (TCL) volatiles by gas chromatography/mass
spectroscopy (GC/MS) in accordance with the EPA CLP 2/88 Statement of Work.
Reviewed and Approved:
Alyce i. Moore
Laboratory Manager
IT Analytical Services. 5815 Middlebrook Pike. Knoxville. TN 37921
IT Coll)Oration
September 10, 1992
Client Project ID: National Starch
ill. Oualitv Control
[T ANALYT[CAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52176
The volatiles analyses were performed by purge and trap with a J&W DB-624 megabore column on a
Finnigan OW A GC/MS/DS. The sample analyses went weU. Sample NS-29 required a dilution for
acetone. The MS/MSD associated with sample NS-29 was analyzed at the more dilute level. The acetone
value in the original dilution appears to be elevated compared to the acetone values from the diluted
MS/MSD and sample. Based on this, the acetone values from the undiluted analysis and the diluted
MS/MSD are considered more representative of the actual acetone concentration in the sample. Two
recoveries were also higher in the MS/MSD than the advised QC limits. The MS/MSD was reanalyzed
with consistently high results. The values were consistent but do not appear to be due to matrix
interference. Overall the analyses looked good. There were no problems seen in final data review.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September IO, 1992
Client Project ID: National Starch
VOLATILE ORGANIC TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: NS-29
Lab Sample ID: TI4570
Compound Concentration Compound
chloromethane 10 u 1. 2-dichloropropane
bromomethane IO u cis-1.3-dichloropropene
vinyl chloride IO u trichloroethene
chloroethane IO u dibromochlorometbane
methylene chloride 2 BJ 1.1.2-trichloroetbane
acetone 2.700 BD benzene
carbon disulfide 5 u trans-1.3-dichloropropcne
I, 1-dichloroethene 5 u bromoform
I. 1-dichloroethane 5 u 4-methyl-2-pentanone
1.2-dichloroethene (total) 5 u 2-hex.anone
chloroform 5 u tetrachloroethene
1.2-dichloroethane 110 l. l ,2,2-tetrachloroethane
2-butanone 18 -toluene
I. I. I -trichloroethane 5 u chlorobenzene
carbon tetrachloride 5 u ethylbcnzenc
vinyl acetate IO u styrene
bromodichloromethane 5 u xylenes (total)
8 Analyte was found in the blank as well as the sample.
D Compound analyzed at a secondary dilution factor.
IT ANALYTICAL SERVICES
58 I 5 MIDDLEBROOK P!Kt
KNOXVILLE. TN
Job Number: ITEK S~ l "6
Concentration
98
5 u
5 u
5 u
5 u
5 u
5 u
5 u
10 u
10 u
5 u
5 u
20
5 u
5 u
5 u
4 J
U Compound was analyzed for but not detected. Toe number is the detection limit for the sample.
J lndicates an estimated value less than the detection limit.
Date of Analysis: 09/04/92
Dilution Factor: LOO
3 IVOLATU.E·.TCL.fRM ; '~:
IT Corporation
September I 0. 1992
Client Project ID: National Starch
lT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52 ! "t'
WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Results in µg/liter (ppb)
Client Sample ID: NS-29 DL
Lab Sample ID: TI4570/TT457! MS/TI4572 MSD
Compound
1.1-dichloroethene
trichJoroethene
benzene
toluene
chlorobenzene
Compound
1.1-dichloroethene
trichloroethene
benzene
toluene
chlorobenzene
'"Values outside required QC limits.
RPD :;; Relative Percent Difference
Cone. Spike
Added
1.250
1.250
1.250
1.250
1.250
Cone.
Spike Added
1.250
l.250
1.250
1.250
1.250
Sam~le Cone.
130 u
130 u
130 u
25.5
130 u
MSD Cone.
1,790
I.630
1.450
I.500
1,570
MS Cone. MS % Rec.
I.800 144
l,560 125 •
1.420 114
l.490 117
l.550 124
MSD % Rec. % RPD
143
130 • -4
116 -2
118 -I
126 -2
l} -Compound was analyzed for but not detected. The number is the detection limit for the sample.
Date of Analysis: 09/04192
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 10, I 992
Client Project ID: National Starch
VOLATILE ORGANIC TARGET cm1POCND UST
Results in µgiliter (ppb)
Sample ~atrix: Water
Client Sample ID: NS-30
Lab Sample ID: TI4573
Comg:ound Concentration Compound
chloromethane IO u 1.2--dichloropropane
bro mo methane IO u cis-1.3-dichloropropene
vinyl chloride IO u trichloroethene
chloroethane IO u dibromochloromethane
methylene chloride 3 BJ I, 1.2-trichloroetbane
acetone 29 B benzene
carbon disulfide 5 u trans-l ,3--dicbloropropene
l, l -dichloroetbene 5 u bromoform
l .1-dichloroethane 5 u 4-methyl-2-pentanone
l .2-dichloroethene (total) 5 u 2-hexanone
chloroform 5 u tetrachloroethene
1.2-dichloroetbane 5 u 1. 1.2.2-tetrachloroetbane
2-butanone IO u toluene
I, I, I -trichloroethane 5 u chlorobenzene
carbon tetradtloride 5 u ethyl benzene
vinyl acetate IO u styrene
bromodichloromethane 5 u xylene, (tot.al)
A.nalyte was found in the blank as well as the sample.
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVIUE. TN
Job Number: ITEK 52176
Concentration
5
5 u
5 u
5 u
5 u
5 u
5 u
5 u
IO u
10 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
B
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than thC detection limit.
Date of Analysis: 09/04/92
Dilution Factor: l.00
5 '.VOLATILE T•·
IT Corporation
September IO, I 992
Client Project ID: National Starch
VOLATILE ORGANIC TARGET COMPOUND UST
Client Sample ID: Trip Blank
Lab Sample ID: TT4574
Compound
chloromethane
bromornethane
vinyl ch.loride
chloroetbane
methylene chloride
acetone
carbon disulfide
l .1-dichloroetbene
1.1-dichloroethane
1.:-dichloroethene (total)
chloroform
1.2-dichloroethane
2-butanone
l, 1.1-trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethanc
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-dichloropropane
10 u cis-1,3-dichloropropene
10 u trichloroethene
10 u dibromochlorometbane
·2 BJ l, 1,2-trichlorocthanc
20 8 benzene
5 u trans-1,3-dichloropropene
5 u bromoform
5 u 4-metbyl-2-pentanone
5 u 2-bexanone
5 u tetrachlorocthcne
5 u 1, 1,2.2-tetrach!oroethane
IO u toluene
5 u chlorobenzene
5 u ethylbenz,ne
IO u styrene
5 u xylenes (total)
Analyte was found in the blank as well as the sample.
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52176
Concentration
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
IO u
IO u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
8
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Date of Analysis: 09/04192
Dilution Factor: 1.00
6 WOU.Tn.EIT(L FAAI ~ l.' ~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 10, 1992
Client Project ID: National Starch
VOLATILE ORGANIC TARGET COMPOUND LIST
Client Sample ID: Method Blank
Lab Sample ID: VB0904
Comeound
chloromethane
bro mo methane
vinyl chloride
chloroetbane
methylene chloride
acetone
carbon disulfide
I, 1-dichloroethene
1.1-dichloroetbane
1,2-dichloroethene (total)
chloroform
1.2-dichloroethane
2-butanone
I, I. I -trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
Results in /Lg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u l .2-dichloropropane
10 u cis-1.3-dichloropropene
10 u trich.loroethene
10 u dibromochloromcthane
2 J 1, 1,2-trichloroethane
24 benzene
5 u trans-l .3-dichloropropene
5 u bromoform
5 u 4-methyl-2-pentanone
5 u 2-hexanone
5 u tetrachloroetbene
5 u 1.1,2.2-tetrachloroetbane
10 u toluene
5 u chlorobenzcne
5 u ethyl benzene
10 u styrene
5 u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52176
Concentration
5 u
5 u
5 u
5 u
5 u
5 u
5 C
5 u
10 u
10 l!
5 u
5 u
5 u
5 u
5 u
5 u
5 u
u
J
DL
Compound was analyzed for but not detected. Toe number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Dilution.
Date of Analysis: 09/04/92
This method blank applies to the following samples: NS-29, NS-29 DL.
7
IT Corporation
September IO, 1992
Client Project ID: National Starch
VOLATILE ORGANIC TARGET COMPOUND LIST
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: Method Blank 2
Lab Sample ID: VB09042
Compound Concentration Compound
chloromethane 10 u 1, 2-dichloropropane
bromomethane 10 u cis-1.3-dichloropropene
vinyl chloride 10 u trichloroethene
chloroetbane 10 u dibromochlorometbane
methylene chloride 5 1.1,2-trichloroetbane
acetone 27 benzene
carbon disulfide 5 u trans-1.3-dichloropropene
l, l -dichloroetbene 5 u bromoform.
l, 1-dichloroethane 5 u 4-methyl-2-pentanone
1.2-dichloroethene (total) 5 u 2-hcxanone
chloroform 5 u tetrachloroethene
l ,Z-dichloroethane 5 u 1.1.2.2-tetrachloroethane
2-butanone 10 u toluene
1.1.1-trichloroethane 5 u chlorobenzene
carbon tetrachloride 5 u ethylbenzene
vinyl acetate 10 u styrene
bromodichloromethane s u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK S2 I 76
Concentration
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
10 u
10 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
u
DL
Compound was analyzed for but not detccte.d. The number is the detection limit for the sample.
Dilution.
Date of Analysis: 09/04/92
This method blank applies to the following samples: NS-29 DL MS. NS-29 DL MSD, NS-30, and Trip Blank.
8 1VOLATILEITC'L.FR.\I ~ ' · ->:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
i
I
I,
I ,,
I'
I
I
I
I
IT Corporation
September 10, 1992
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Client Project ID: National Starch Job Number: ITEK 52176
WATER SURROGATE PERCENT RECOVERY SUMMARY
VOLATILE
Toluene-D8 Bromofluorobenzene 1,2 Dich.loroethane-D4
Client Samele ID (88-1 JO%)• (86-115 % )* (76-114%)*
NS-29 107 !02 !09
NS-29 DL 99 97 97
NS-29 DL MS 96 95 97
NS-29 DL MSD 96 94 94
NS-30 99 97 100
Trip Blank 92 90 90
Method Blank I 95 93 89
Method Blank 2 I05 105 102
DL = Dilution.
*Values in parenthesis represent required QC limits.
9 REC :.-\.FRM
™---. INTERNATIONAL
TECHNOLOGY
CORPORATION
3. Relinquished by
(Sigmnure/AfhhRt.io,,)
Comments: 29
ANALYSIS REQUEST AND
CHAIN OF CUSTODY RECORD*
Refer'ence Document No.
Page 1 of
Date: 3. Received by Date:
Time: fSrgrmturP./1\111hAt1onl Time:
37960.~
I
I
I
I
I
'I.
II
.I
1.
I
I
@ INTERNATIONAL
TECHNOLOGY
CORPORATION
IT Corporation
312 Directors Drive
Knoxville, TN 37923
Attn: Mike Sturdevant
Job Number: ITEK 52177
ANALYTICAL
SERVICES
CERTIFICATE OF ANA.LYSIS
This is the Certificate of Analysis for the following samples:
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
08/27/92
Two (2)
Water
September 17, 1992
P.O. Number: 408668.009.60
On 08/27/92, two (2) water samples arrived at the ITAS-Knoxville, Tennessee, laboratory from IT
Corporation, Knoxville, Tennessee in support of the National Starch project. The list of analytical tests
performed, as well as date of receipt and analysis, can be found in the attached report.
II. Analvtical Results/Methodology
The analytical results for this report are presented by analytical test. Each set of data will include sample
identification information and the analytical results. Please note that the data are not blank corrected.
The samples were analyzed for Target Compound List (TCL) semivolatiles by gas chromatography/mass
spectroscopy (GC/MS) in accordance with the EPA CLP 2/88 Statement of Work.
The samples were analyzed for Target Analyte List (T AL) metals by cold vapor atomic absorption
spectroscopy (CV AA), graphite furnace atomic absorption spectroscopy (GFAA), and inductively coupled
plasma spectroscopy (ICP) in accordance with the EPA CLP ILMO I Statement of Work.
Reviewed and Approved: t', ,.,., -.U1, , ~ /4~-% /
Alyce R'. Moore
Laboratory Manager
IT Analytical Services. 5815 Middlebrook Pike. Knoxville. TN 37921
IT Corporation
September 17, 1992
Client Project ID: National Starch
m. Quality Control
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE TN
Job Number: ITEK 52178
The semivolatiles analyses were performed by direct injection of sample extract on a Restek XTI-5
capillary column on a Finnigan 4500 GC/MS/DS. The sample analyses went well. Overall, both method
QC and analyses looked good. Associated QC samples were analyzed with ITAS project ITEK 52178,
sample DW-11. There were no problems seen in final data review.
The samples were digested on 08/28/92 for ICP and GFAA. The samples were prepared just prior to
analysis for mercury by CV AA on 08/31/92. The GFAA analyses for arsenic, lead, selenium, and thallium
were performed from 08/31 through 09/01/92. The remaining metals were analyzed by ICP on 09/02/92.
All run QC was acceptable. A duplicate/spike pair was prepared using sample NS-29. Spike recovery
(accuracy) results were within acceptance limits for all parameters except for cadmium by ICP analysis and
lead and thallium by GFAA analysis. Post-digestion spikes were performed which confirmed matrix
interferences for all three analytes. Duplicate RPD (precision) results were within acceptance limits for all
parameters. No problems were encountered.
2
I
I
·I
I
I
.I
I
I
I
I
.i
I
I
··• I
i
I
.1
I
I
I
I
I
I
I
I
i
I
I
i
,I
I
I
IT Corporation
September 17, 1992
Client Project ID: National Starch
Client Sample ID: Method Blank
Lab Sample ID: BLl450
Com12:ound
phenol
bis(2-chloroethyl)ether
2-chlorophenol
l ,3-dichlorobcnzene
1,4-dichlorobenzene
benzyl alcohol
1,2-dichlorobcnzene
2-methylphenol
bi s(2-chlo roisop ropy 1 )ether
4-methylphenol
n-nitroso-di-n-propylaminc
hexachloroctbane
nitrobcnzene
isopborone
2-nitrophenol
2,4-dimethylphenol
benzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
IO u bis(2-chloroethoxy)methane
IO u 2,4-dichlorophenol
IO u I, 2, 4-trichlorobenzene
IO u naphthalene
IO u 4-cb.loroaniline
10 u hexachlorobutadiene
10 u 4-chloro-3-methylphenol
10 u 2-methylnaphthalene
10 u hexachlorocyclopcntadiene
IO u 2,4,6-trichlorophenol
IO u 2,4,5-trichlorophenol
IO u :-chloronaphthalene
IO u 2-nitroaniline
IO u dimethyl phthalate
IO u acenaphthylcnc
10 u 2,6-dinitrotolucne
50 u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52178
Concentration
IO u
IO u
IO u
10 u
10 u
IO u
IO u
IO u
10 u
IO u
50 u
IO u
50 u
10 u
IO u
10 u
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysis:
09/01/92
09/03/92
3
IT Corporation
September 17, 1992
Client Project ID: National Starch
!T ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVl!.LE. TN
Job Number: ITEK 52178
SEMIVOLATILE TARGET COMPOUND LIST (continued)
Results in /Lg/liter (ppb)
Sample Matrix: Water
Client Sample ID: Method Blank
Lab Sample ID: BL1450
Compound Concentration Compound
3-nitroaniline 50 u anthracene
acenaphthene IO u di-n-butylphthalate
2,4-dinitrophenol 50 u fluoranthenc
4-nitrophcnol 50 u pyrene
dibenzofuran IO u butylbcnzylphthalate
2, 4-dinitrotoluene 10 u 3 ,3' -dichlorobcnzidine
diethylphthalate 10 u bcnzo(a)anthracene
4-chlorophenyl-phenylether IO u chrysene
fluorene 10 u bis(2-<:thylhexyl)phthalate
4-nitroaniline 50 u di-n-octy lphthalate
4,6-dinitro-2-methylphenol 50 u bcnzo(b)fluoranthene
n-nitrosodiphenylamine1 10 u bcnzo(k)fluoranthene
4-bromophenyl-phenylether IO u benzo(a)pyrene
bexachlorobenzcne 10 u indeno( 1,2,3-cd)pyrene
pentachlorophenol 50 u dibcnzo(a,h)anthracene
pbenanthrene 10 u bcnzo(g,h,i)perylene
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
lndicates an estimated value less than the detection limit.
Detected as diphenylamine.
Date of Extraction:
Date of Analysis:
09/01/92
09/03/92
4
ConcentraTion
IO u
IO u
IO u
10 u
IO u
20 u
IO u
IO u
IO u
10 u
IO u
IO u
IO u
IO u
IO u
IO u
I
I
I
I
I
I
I
I
i
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-1
t
.I
I
I
I
I
IT Corporation
September 17, 1992
Client Project ID: National Starch
Clieot Sample ID: NS-29
Lab Sample ID: TT4579
Com1:1:ound
pheool
bis(2-chloroethyl)ether
2-chlorophenol
1,3-dichlorobcnzene
l, 4-dichlorobcnzcnc
benzyl alcohol
1,2-dichlorobenzene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hcxachloroctbane
nitrobcnzene
isophorone
2-nitropbenol
2,4-dimethylphenol
benzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
IO u bis(2-chloroethoxy)methane
67, 2,4-dichlorophenol
IO u 1,2,4-trichlorobenune
10 u naphthalene
IO u 4-chloroaniline
IO u hexachlorobutadienc
IO u 4-chloro-3-methylphenol
10 u 2-methylnaphthalene
IO u hexachlorocyclopentadienc
IO u 2,4,6-trichlorophenol
IO u 2,4,5-trichlorophenol
IO u 2-chloronaphthalene
10 u 2-nitroaniline
10 u dimethyl phthalate
10 u acenaphthylenc
10 u 2,6-dinitrotoluenc
50 u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE TN
Job Number: ITEK 52178
Concentration
10 u
IO u
IO u
IO u
10 u
IO u
IO u
IO u
IO u
IO u
50 u
IO u
50 u
10 u
IO u
IO u
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
lndicates an estimated value less than the detection limit.
Date of Extraction:
Date of Analysi,:
Dilution Factor:
09/01/92
09/03/92
LO
5
IT Corporation
September 17, 1992
Client Project ID: National Starch
fT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52178
SEMIVOLATILE TARGET COMPOUND LIST (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample fD: NS-29
Lab Sample fD: TT4579
Compound Concentration Compound
3-nitroaniline 50 u anthracene
acenaphthene 10 u di-n-butylphtbalate
2,4-dinitrophenol 50 u fluoranthene
4-nitrophenol 50 u pyrene
dibenzofuran 10 u butylbenzylphtbalate
2, 4-dinitrotoluene 10 u 3 ,3 '-dichlorobenzidine
diethylphthalate 10 u benzo(a)anthracene
4-chlorophenyl-phenylether 10 u chrysene
fluorcne 10 u bis(2-ethylhexyl)phtbalate
4-nitroaniline 50 u di-n-octylphtbalate
4,6-dinitro-2-methylphenol 50 u benzo(b)fluorantbene
n-nitrosodiphenylamine1 10 u benzo(k)fluorantbene
4-bromophenyl-phenyletber 10 u benzo(a)pyrene
hexachlorobenzene 10 u indeno( I, 2,3-cd)pyrene
pentachlorophenol 50 u dibenzo(a,h)antbracene
phenanthrcne 10 u benzo(g,h,i)perylene
u
1
Compound was analyud for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Date of Extraction:
Date of Analysis:
Dilution Factor:
09/01/92
09/03/92
1.0
6
ConcentraTion
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
2 J
10 u
10 u
10 u
10 u
10 u
10 u
10 u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 17, 1992
Client Project ID: National Starch
Client Sample ID:
uib Sample ID:
?io (,/,i'f)
NS$•"'
TI4580
SEMIVOLATILE TARGET COMPOUND LIST
Results in µg/liter (ppb)
Sample Matrix: Water
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE TN
Job Number: ITEK 52178
I Compound Concentration Compound Concentration
I
I
.I
I
I ,,
I
I
I
I
i
I
phenol
bis(2-chlorocthyl)ether
2-chlorophenol
1,3-dichlorobenz.cne
l .4-dichlorobenz.ene
benzyl alcohol
1,2-dichlorobenz.ene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
bexachloroethane
nitrobenz.ene
isophorone
2-nitropbenol
2,4-dimethylphenol
bcnzoic acid
10
38
IO
JO
10
JO
2
IO
IO
IO
10
IO
10
10
10
IO
so
u bis(2-chloroethoxy)methane
2,4-dichlorophenol
u 1, 2,4-trichlorobenzene
u naphthalene
u 4-chloroaniline
u bexachlorobutadiene
] 4-chloro-3-methylphenoJ
u 2-methylnaphthalene
u hexachlorocyclopenbldiene
u 2,4,6-trichlorophenol
u 2,4,5-trichlorophenol
u 2-chloronaphthalene
u 2-nitroaniline
u dimethyl phthalate
u acenaphthylene
u 2,6-dinitrotoluene
u
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
lndicates an estimated value less than the detection limit.
Date of Extraction:
Date of 1alysis:
Dilution ,.-actor:
09/01/92
09/03/92
1.0
7
JO u
IO u
JO u
IO u
IO u
JO u
IO u
IO u
JO u
IO u
50 u
IO u
50 u
10 u
10 u
IO u
IT Corporation
September 17, 1992
Client Project ID: National Starch
IT ANALTTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52178
SEMIVOLA TILE TARGET COMPOUND UST (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: Ns-N~{'
Lab Sample ID: TT4580
Compound Concentration Compound
3-nitroaniline 50 u anthracene
accnaphthene 10 u di-n-butylphthalate
2,4-dinitrophenol 50 u fluoranthene
4-nitrophenol 50 u pyrene
dibenzofuran 10 u butylbenzylphthalate
2. 4-dinitrotoluene 10 u 3 ,3' -dichlorobenzidine
diethy I phthalate 10 u benzo(a)anthracene
4-chlorophenyl-phenylether 10 u chrysene
fluorene 10 u bis(2-<:thylhexyl)phthalate
4-nitroaniline 50 u di-n-octylphthalate
4,6-dinitro-2-methylphenol 50 u benzo(b)fluoranthene
n-nitrosodiphcnylamine1 10 u benzo(k)fluoranthene
4-bromophenyl-phenylether 10 u benzo(a)pyrene
hexachlorobcnzcne 10 u indeno( 1,2,3-cd)pyrene
pentach.lorophenol 50 u dibenzo(a,h)anthracene
phenanthrene 10 u benzo(g,h,i)perylene
u
J
Compound was analyzed. for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Date of Extraction:
Date of Analysis:
Dilution Factor:
09/01/92
09/03/92
1.0
8
ConcentraTion
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
I
I
I
I
I
I
I
' I
I
I
I
I
I
I
'I
I
i
1
I
I
I
I
I
I
I ,,
I
I
I
I
I
II
I
I
IT Corporation
September 17, 1992
Client Project ID: National Starch
IT ANALYTICAL SERVICES
58 15 MIDDLEBROOK PIKE
KNOXVILLE TN
Job Number: ITEK 52178
WATER SURROGATE PERCENT RECOVERY SUMMARY
SEMI-VOLATILE
2,4,6-
Nitro-2-Fluoro-Tcrphcnyl-2-Fluoro-Tribromo-
Benzene-D5 Biphcnyl D14 Phenol-OS Phenol Phenol
Client Sample ID (35-114%)• (43-116%)• (33-141 %)• (10-94%)• (21-100%)• (10-123%)•
NS-29 84 85 87 35 56 103
NS_)q~f/~) 103 104 89 21 34 n
Method Blank 90 93 90 38 60 100
•Values in parentheses represent required QC limits.
9 \.REC'.:C.FR.M
IT Coq,oration
September 17, 1992
Client Project ID: National Starch
METALS TARGET ANALYTE LIST
Client Sample ID: Method Blank
Lab Sample ID: PBWC5237/PBWI0659
Results in µg/liter (ppb)
Sample Matrix: Water
Compound Concentration Compound
aluminum -139.870 B magnesium
antimony 30.000 u manganese
arsenic 2.000 u mercury
barium 2.000 u nickel
beryllium :1.200_ B potassium
cadmium 5.000 u selenium
calcium 30.000 u silver
chromium 10.000 u sodium
cobalt -21.070 B thallium
copper -11.980 B vanadium
iron -11.870 B zinc
lead 2.000 u
Date of Digestion: 08/28/92
Date of Analysis: 09/02/92 (ICP), 08/31/92 and 09/01/92 (GFAA), 08/31/92
IT ANALYTICAL SERVICES
58 15 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52178
Concentration
-129.880 B
-2.390 B
0.200 u
20.000 u
-2,723.010 B
2.000 u
5.000 u
200.000 u
2.000 u
-14.730 B
5.000 u
(CVAA)
u
B
Compound was analyzed for but not detected. The number is the detection limit for the sample. Value greater than instrument detection limit, but less than contract required quantitation limit.
10 IMETALS\TAL.FRM ~IIJ.'-7.:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
September 17, 1992
Client Project ID: National Starch
Client Sample rD:
. Lab Sample rD:
Compound
aluminum
antimony
arsenic
NS-29
TT4575
METALS TARGET ANALYTE UST
Results in l'g/liter (ppb)
Sample Matrix: Water
Concentration Compound
62.2 B
30.0 U
2.0 U
85.8 B
1.0 U
S.O U
magnesium
manganese
mercury
nickel
potassium
selenium
barium
beryllium
cadmium
calcium
chromium
cobalt
copper
190,000 silver
iron
lead
Date of Digestion: 08/28/92
· 32.6
20.0 U
10.0 U
568
2.0 U
sodium
thallium
vanadium
zinc
Date of Analysis: 09/02/92 (ICP), 08/31/92 and 09/01/92 (GFAA), 08/31/92 (CVAA)
IT ANALTTICAL SERVICES
58 I 5 MIDDLEBROOK PIKE KNOXVILLE. TN
Job Number: ITEK 52178
Concentration
IS, 700
582
0.20 u
20.0 u
1,000 u
2.0 u
5.0 u
16,300
2.0 u
I0.0 u
·.164
U Compound was analyzed for but not detected. The number is the dete.ction limit for the sample. B Value greater than instrument detection limit, but less than contract required quantitation limit.
I I IMETALS\TALFRM ~:1>'11'.:
IT Corporation IT ANALYTICAL SERVICES
September 17, 1992 5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Client Project ID: National Starch Job Number: ITEK 52178
MATRIX SPIKE SAMPLE RECOVERY
Results in l'g/liter (ppb)
Sample Matrix: Water
Client Sample ID: NS-29S
Lab Sample ID: TI4577-S
Control Spiked
Limit% R SamI:!le Result Sam~:le Result SQike Added % Recoverv
aluminum 75-125 2,043.9400 62.2100 B 2,000.00 99. 1
antimony 75-125 422. 1500 30.0000 u 500.00 84.4
arsenic 75-125 35.5800 2.0000 u 40.00 89.0
barium 75-125 I.961.8500 85.7600 B 2,000.00 93.8
beryllium 75-125 53.2700 1.0000 u 50.00 106.5
cadmium 75-125 14.2900 5.0000 u 50.00 28.6
chromium 75-125 226.4700 32.5900 200.00 96.9
cobalt 75-125 464.8700 20.0000 u 500.00. 93.0
copper 75-125 233.5600 10.0000 u 250.00 93.4
iron 75-125 1,601.2700 568.4100 I.000.00 103.3
lead 75-125 9.9000 2.0000 u 20.00 49.5
manganese 75-125 1,024.8900 582.0200 500.00 88.6
mercury 75-125 1.0500 0.2000 u 1.00 105.0
nickel 75-125 495.2900 20.0000 u 500.00 99.1
selenium 75-125 9. 1300 2.0000 u 10.00 91.3
silver 75-125 45.9800 5.0000 u 50.00 92.0
thallium 75-125 29. 1600 2.0000 u 50.00 58.3
vanadium 75-125 486.1300 10.0000 u 500.00 97.2
zinc 75-125 560.6900 164. 1400 500.00 79.3
Date of Digestion: 08/28/92
Date of Analysis: 09/02/92 (ICP), 08/31/92 and 09/01/92 (GFAA), 08/31/92 (CV AA)
u
B
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Value greater than instrument detection limit, but less than contract re.quire.d quantitation limit.
12
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
••
I
ii
I
I
I
m
I
I
fl
I
I
I
I
I
IT Corporation
September 17, 1992
Client Project ID: National Starch
POST DIGEST SPIKE SAMPLE RECOVERY
Results in µg/liter (ppb)
Sample Matrix: Water
Client Sample ID: NS-29A
Lab Sample ID: TT4585-A
Control Spiked
Limit% R Samele Result Samele Result
aluminum 2,095.43 62.21 B
antimony 428.21 30.00 u
barium 1,959.15 85.76 B
beryllium 53.71 1.00 u
cadmium 18.00 5.00 u
chromium 227.77 32.59
cobalt 470.98 20.00 u
copper 236.33 10.00 u
iron 1,583.12 568.41
lead 12.01 2.00 u
manganese 1,019.10 582.02
nickel 497.35 20.00 u
silver 47.49 5.00 u
tballium 34.28 2.00 u
vanadium 490.59 10.00 u
zinc 647.07 164. 14
Date of Digestion: 08/28/92
Date of Analysis: 09/02/92 (ICP), 08/31/92 and 09/01/92 (GF AA), 08/31/92 (CV AA)
IT ANALYTICAL SERVICES
58 15 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52178
Sei.ke Added % Recoven,
2,000.0 101.7
500.0 85.6
2,000.0 93.7
50.0 107.4
50.0 36.0
200.0 97.6
500.0 94.2
250.0 94.5
1,000.0 101.5
20.0 60.0
500.0 87.4
500.0 99.5
50.0 95.0
50.0 68.6
500.0 98. I
500.0 96.6
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
13 IMETALS'.TAL.FRM ~11 3,q,:
IT Corporation
September 17, I 992
Client Project ID: National Starch
Client Sample ID: NS-29D
Lab Sample ID: IT4576-D
Parameter Control Limits
aluminum
antimony
arsenic
barium
beryllium
cadmium 5.0
calcium
chromium 10.0
cobalt
copper
iron
lead
Date of Digestion: 08/28/92
DUPLICATE ANALYSIS
Results in µg/liter (ppb)
Sample Matrix: Water
Original Sample Duplicate
62.2100 B 62.1700
30.0000 u 30.0000
2.0000 u 2.0000
°'85.760(f B ·82.7900
1.0000 u 1.0000
5.0000 u 5.0000
190,328.8800 184,178.7400
32.5900 34.3900
20.0000 u 20.0000
10.0000 u 10.0000
568.4100 560.2500
2.0000 u 2.0000
Date of Analysis: 09/02/92 (ICP), 08/31/92 and 09/01/92 (GFAA), 08/31/92 (CVAA)
RPD = Relative percent difference
B
u
u
B
u
u
u
u
u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 52178
RPO
0.1
3.5
3.3
5.4
1.4
U -Compound was analyzed for but not detected. The number is the detection limit for the sample.
14 IMETAI..SITA.L.FRM ~11319-:
I
I
I
I
I
I
i
·I
I
I
I
I
I
i
,1
I
I
I
I
I
I
I
.I
I
'I
I
I
I
I
I
I
' I
I
I
I
IT Corporation
September 17, 1992
Client Project ID: National Starch
Client Sample ID: NS-29D
Lab Sample ID: TI4576-D
Parameter
magnesium
manganese
mercury
nickel
potassium
selenium
silver
sodium
thallium
vanadium
zinc
Date of Digestion: 08/28/92
Control Limits
5,000.0
0.2
5,000.0
DUPLICATE ANALYSIS (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Original Sample Duplicate
'.15,714.7200 • 15,201.0400
582.0200 563.3000
0.2000 u 0.2000
20.0000 u 20.0000
1,000.0000 u 1,000.0000
2.0000 u 2.0000
5.0000 u 5.0000
16,318.0200 15,712.8900
2.0000 u 2.0000
10.0000 u 10.0000
164.1400 164.6800
Date of Analysis: 09/02/92 (ICP), 08/31/92 and 09/01/92 (GFAA), 08/31/92 (CV AA)
RPD = Relative percent difference
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
u
u
u
u
u
u
u
Job Number: ITEK 52178
RPD
3.3
3.3
3.8
0.3
U • Compound was analyzed for but not detected. The number is the detection limit for the sample.
15 \META.LS\TAJ..FJIM 41\J,q,:
IT Corporation
September 17, 1992
Client Project ID: National Starch
Client Sample ID: NS-30
lab Sample ID: TI4578
ComQound
aluminum
antimony
arsenic
barium
beryllium
cadmium
METALS TARGET ANALYTE LIST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
188 B magnesium
30.0 u manganese
2.0 u mercury
· 40.3 B nickel
1.0 u potassium
5.0 u selenium
calcium 167,000 silver
chromium 10.0 u sodium
cobalt 20.0 u thallium
copper 12.6 B vanadium
iron 395 :zinc
lead 2.0 u
Date of Digestion: 08/28/92
Date of Analysis: 09/02/92 (ICP), 08/31/92 and 09/01/92 (GFAA), 08/31/92 (CV AA)
IT ANALYTICAL SERVICES 5815 MIDDLEBROOK PIKE KNOXVIUE. TN
Job Number: ITEK 52 I 78
Concentration
30,000
.1,820
0.20 u
20.0 u
1,000 u
2.0 u
5.0 u
18,800
2.0 u
19.6 B
·81.6
u
B
Compound was analyzed for but not detected. The number is the detection limit for the sample. Value greater .than instniment detection limit, but less than contract required quantitation limit.
16 \METALl'ITAI..FRAt .i11J,"9':
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m INTERNATIONAL
TECHNOLOGY
CORPORATION
ANAL VSIS REQUEST AND
CHAIN OF CUSTODY RECORD*
Samples Shipment Date 7 8 /z r./ f Z..
Reference Document No.
Page 1 of 379603
~
Project Name/No. 1N,l,0 ,,0 fsl•·~io,J<c"~
;ample Team Members 2 D ,j,{o//o...,e If___ _.
Profit Center No. 3 . .. _ -.3 'i 73 _ .
Required Report Date 1~ ,i .1.<-. '1 ol J_,/_u
Sample 14 Sample 15 Date/Time 16
Number Description/Type Collected
/V..s-30 c..,1,_,,., /,.i,.__-+.,. 'e/(2-.~//Z-·1: q
f • ., / .. ~ /"IL.
.Nc:,-.52) 'r.,,,. I 1.,.-+e,.,,,,,-II '.LD
,1-LS -30 CJ U-✓ I !,J .,_,fc V
8/,:,,C(qi,_,
II', 7 I
1\/.S 2_q c.r =; I w ---t~-8/Z..<./"4_ J'-i:o
' i .., f'i:.1.( n.
A I ' 2. 'i C./," ,. t,J "-''' ~ /LI! O<:'"
1-J.S.~z. 4 rf,,",,) /. r . -fe .r ~f-' /'17.. 'r ; "' (,,
r
'
Lab Destination 8 ::Z-T1+J-I~ . .1J1,.._!,,.,o/c ___
1 ■111~• .1111h.,■~ l ■h1
Container 1 Sample 1 Pre-19 Requested T eating 20
June Volume aervative Proqram
1/z._ I· f·, 1/,__ f,f.,,. /IN03 rr'l.:I.JJ n/..,.:,{L-:Z-c..L.,
I t,-ny I /,f,,,. Le.,._ ~,b<-,,.. n.r,/ 11-,. "--~
2 -'(OM/ Jo,.,/ ,I<. ....
votLs <.It:, r //-LI ,., '< ~ \
"r/1../.f>r '/,.f,fv /-I ,J C!3
M,./-.. /..S ',(, J., --r; ~
I I ,./-,v-
#<../' /:,{ \ I I.le. -ref' /) Iv 4-
2-~ t,O~ I s n~. I JC<._ --;tJ;.' ~ r /.1<_ I v'tl l'.\---.s -
Special Instruction~ ?3 I'!' /\/,,
/-.;)(._ i 0..J /'~.J.7 I-· .fc_ t\.'11\ fyJr._j
c~l,,,o.JL,. (A~~(,/_, '.1 •. /(.,J 0 ( /{,,--/0 J.-/.,,-,~,o.··•.eJ C•
Possible Hazard Identification: 24 ' . /
. ,.t.._. •)< \/ , lie_ , r✓J --···
Condition on 21 Disposal 22
Receiot Record No. I/, oK ~~ I l7-9z c..: ,_ A..,__ ,; Lh 1;,,/,,d
., .
., I,
..
'\/0/:J.v C,--1 I./
'
Non-hazard _J Flammable J Skin Irritant J Poison 8 'J Unknown '){_
Sample Disposal: 25 o/.t /
Return to Client J Disposal by Lab Archive. .. . -·· (mos I
Turnaround Time Required: 26 o, Iv ((,-1D ,1~y '\ I ~ Level: 27 ' . I
Normal ',,( Rush )9 R. ,a ( ., y D 4-.s I ILJ IILJ Proiect Soecific (soecifvr ... .... ----.. -----·-
1. Relinquished by 2a.:z),.,,..,~ 1/./ 110 .. '-,,, Date _,'Jc._c.,_/ '?.L. 1. Received by 2a ~~;.., .-..,/ IZ,,c.17><..J..S. Date: ... ?/2:-':/'i' c..
(Signature/ Affibetion) :::Z:-T r ov.,.,,, Time. ~~: oQ fSognatuce/AH,J,ation) fl,,t, ti e,.38,~ 7<a93,Y Time:/,::::,.::,
2. Relinquished by Date: 2. Received b¼~ Date: Y,-2'11'Z--
15'gnature/Affibet.ionJ ------------------MM -·· Time: [S,gnature/Atfiliat.ion) ✓.., .1 • Time: /1,rZc,
3. Relinquished by Date: 3. Received by Date:
l&Qnature/Affibet.JonJ Time: ·-------------------·· ----· [Signature/ Aff1hat.1on) Time:
Comments: 29
;n.e S .2/?7
0 ;. •
u
e 0 n a
3 u • ~ < • • " u • •
-< • 0 ~
• n n 0 u
OJ • • a • D
0
0 ,
3
0 ,
• D • 0 • a ~ ,
C :s
D ~ •
--- - -
-· - -_ ..... _ - - - -
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
rn INTERNATIONAL
TECHNOLOGY
CORPORATION
IT Corporation
312 Directors Drive
Knoxville, TN 37923
Attn: Mike Sturdevant
ANALYTICAL
SERVICES
CERTIF1CATE OF ANALYSIS
January 28. 1993
Job Number: ITEK 53103 (Corrected Certificate) P.O. Number: 408668.009.61
This is the Certificate of Analysis for the following samples:
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
l 2/ 19/92
Four (4)
Water -three (3); Trip Blank -one (I)
On 12/19/92, three (3) water samples and one (I) trip blank arrived at the ITAS-Knoxville, Tennessee.
laboratory from IT Corporation, Knoxville, Tennessee in support of the National Starch project. The list of
analytical tests performed, as well as date of receipt and analysis, can be found in the attached report.
II. Analytical Results/Methodology
The analytical results for this report are presented by analytical test. Each set of data will include sample
identification information and the analytical results. Please note that the data are not blank corrected.
The samples were analyzed for Target Compound List (TCL) volatiles by gas chromatography/mass
spectroscopy (GC/MS) in accordance with the EPA CLP 2/88 Statement of Work.
Reviewed and Approved:
/i --:,.--,
i /;/ _ ✓-. //_,t~u, 1..,?(/(''/ /(. ~
Alyce'R. Moore
Laboratory Manager
A:nencan Cour.c!l o! !:.-::e:..:'7· >:-:: :...::::-)ra::-ir1es
:r.:er:-;::::c:--.-:::1 A.sscc::::::or. al E:::.::: · · · -~->:·:-:: :·.;;: .::::-o::::to::es
_;,;-:-.i=:::-:::~. _.'....;;soc:c::c::. '.::::r :..::.:: · ~-: :·i . .:..::::~::::·::::. ::n
IT Analytical Services. 5815 Middlebrook Pike, Knoxville, TN 37921
IT Corporation
January 19, 1993
Client Project ID: National Starch
II. Analytical Results/Methodology (continued)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53103
The samples were analyzed for Target Compound List (TCL) semivolatiles by gas chromatography/mass
spectroscopy (GC/MS) in accordance with the EPA CLP 2/88 Statement of Work.
The samples were analyzed for Target Analyte List (TAL) metals by cold vapor atomic absorption
spectroscopy (CV AA), graphite furnace atomic absorption spectroscopy (GFAA), and inductively coupled plasma spectroscopy (ICP) in accordance with the EPA CLP IIMO I Statement of Work.
m. Quality Control
The volatiles analyses were perfonned by purge and trap with a J&W DB-624 megabore column on a Finnigan OWA GC/MS/DS. The sample analyses went well. A large non-target peak was seen in some analyses. A matrix spike/matrix spike duplicate was perfonned on sample NS-32 with acceptable results. There were no problems seen in final data review.
The semivolatiles analyses were perfonned by direct injection of sample extract on a Restek XTI-5
capillary column on a Finnigan 4500 GC/MS/DS. The sample analyses went well. The MS/MSD on sample NS-32 had four percent recoveries high, but there were no major outliers. Also, the results were consistent and there were .no noncompliant RPDs. This appeared to be a function of the extraction and the reponed data were considered reliable. There were no problems seen in final data review.
Data were reponed with qualifiers as follows:
U -Compound analyzed for but not detected; value given is quantitation limit.
E -Compound exceeded calibration range.
D -Compound analyzed at secondary dilution.
J -Compound detected but below quantitation limit; value estimated.
B -Compound found in method blank.
The samples were digested on 12/30/92 for ICP and 12/30/92 for GFAA. The samples for mercury
analysis were prepared just prior to analysis. The CV AA analysis for mercury was performed on 12/30/92; the GFAA analyses for arsenic, lead, selenium, and thallium were perfonned on 12/30/92
through 01/05/93; the remaining metals were analyzed by ICP on 01/04/93. All run QC was acceptable.
A duplicate/spike pair was prepared using sample number NS-32. Spike recovery (accuracy) results were within acceptance limits for all parameters by ICP, GFAA and CV AA analyses. Duplicate RPO (precision) results were within acceptance limits for all parameters by ICP, GFAA, and CV AA analyses. Slightly
elevated detection limits for selenium were reponed due to matrix interferences. No other problems were
encountered.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
B
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
January 19, 1993
Client Project ID: National Starch
m. Quality Control (continued)
Data were reported with qualifiers as follows:
"C" Qualifiers
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53103
U Compound was analyzed for but not detected. The number is the detection limit for the sample. B Value greater than instrument detection limit, but less than contract required quantitation limit.
"Q" Qualifiers
• Duplicate analysis outside control limits .
Spiked sample recovery outside control limits. N
w Post-digestion spike for GFAA was out of control limits (85-115%), while sample absorbance was less than 50 % of spike absorbance. s The reported value was determined by method of standard additions.
"M" Qualifiers
P Analysis performed by ICP.
V Analysis performed by CV AA.
F Analysis performed by GFAA.
C Cyanide analysis by manual distillation/colorimetric determination.
Miscellaneous
D -Duplicate.
S -Spike.
NR -Not required.
G Native analyte > 4 times spike added, therefore, acceptance criteria do not apply.
X -Detection limits higher than normal due to sample matrix interferences.
3
lA
VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO.
Lab Name: ITAS-KNOXVILLE contract:
NS31
Lab Code: ITSTU Case No.: 53103 SAS No.: SOG No.: NS31
Matrix: ( soil/water) WATER Lab Sample IO: VV3293
Sample wt/vol: 5.0 (g/mL) ML Lab File ID: VV3293R
Level: ( low/med) LOW Date Received: 121'.191'.92
% Moisture: not dee. Date Analyzed: 121'.221'.92
Column: (pack/cap) CAP Dilution Factor: 1.0
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG£'.L Q
74-87-3---------Chloromethane 10 u 74-83-9---------Bromomethane 10 u 75-01-4---------Vinyl Chloride 10 u
75-00-3---------Chloroethane 10 u
75-09-2---------Methylene Chloride 5 u
67-64-1---------Acetone 10 u
75-15-0---------carbon Disulfide 5 u
75-35-4---------1,1-Dichloroethene 5 u
75-34-3---------1,1-Dichloroethane 5 u
540-59-0--------1,2-Dichloroethene (total)_ 5 u
67-66-3---------Chloroform 16 107-06-2--------1,2-Dichloroethane 22
78-93-3---------2-Butanone 18
71-55-6---------1,1,1-Trichloroethane 5 u
56-23-5---------Carbon Tetrachloride 5 u
108-05-4--------Vinyl Acetate 10 u
75-27-4---------Bromodichloromethane 5 u
78-87-5---------1,2-Dichloropropane 34
10061-01-5------cis-l,3-Dichloropropene 5 u
79-01-6---------Trichloroethene 5 u
124-48-1--------Dibromochloromethane 5 u
79-00-5---------1,1,2-Trichloroethane 5 u
71-43-2---------Benzene 5 u
10061-02-6------trans-l,3-Dichloropropene __ 5 u
75-25-2---------Bromoform 5 u
108-10-1--------4-Methyl-2-Pentanone 10 u
591-78-6--------2-Hexanone 10 u
127-18-4--------Tetrachloroethene 5 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 5 u
108-88-3--------Toluene 7
108-90-7--------Chlorobenzene 5 u
100-41-4--------Ethylbenzene 5 u
100-42-5--------styrene 5 u
1330-20-7-------Xylene (total) 5 u
FORM I VOA 1/87 Rev.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I,
I
I
m
R
0
ti
I
I
I
I
I
I
I
I
lA EPA SAMPLE NO.
VOLATILE ORGANICS ANALYSIS DATA SHEET
NS31B
Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No.: SDG No.: NS31
Matrix: (soil/water) WATER Lab Sample ID: VV3294
Sample wt/vol: 5.0 (g/mL) file__ Lab File ID: VV3294
Level: (low/med) LOW Date Received: 12/19/92
% Moisture: not dee. Date Analyzed: 12/22/92
Column: {pack/cap) CAP Dilution Factor: 1.0
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
74-87-3---------Chloromethane 10 u
74-83-9---------Bromomethane 10 u
75-01-4---------Vinyl Chloride 10 u
75-00-3---------Chloroethane 10 u
75-09-2---------Methylene Chloride 6 B
67-64-1---------Acetone 10 u
75-15-0---------Carbon Disulfide 5 u
75-35-4---------1,1-Dichloroethene 5 u
75-34-3---------1,1-Dichloroethane 5 u
540-59-0--------1,2-Dichloroethene (total)_ 5 u
67-66-3---------Chloroform 14
107-06-2--------1,2-Dichloroethane 27
78-93-3---------2-Butanone 16
71-55-6---------1,1,1-Trichloroethane 5 u
56-23-5---------carbon Tetrachloride 5 u
108-05-4--------Vinyl Acetate 10 u
75-27-4---------Bromodichloromethane 5 u
78-87-5---------1,2-Dichloropropane 40
10061-01-5------cis-1,3-Dichloropropene 5 u
79-01-6---------Trichloroethene 5 u
124-48-1--------Dibromochloromethane 5 u
79-00-5---------1,1,2-Trichloroethane 5 u
71-43-2---------Benzene 5 u
10061-02-6------trans-l,3-Dichloropropene __ 5 u
75-25-2---------Bromoform 5 u
108-10-1--------4-Methyl-2-Pentanone 10 u
591-78-6--------2-Hexanone 10 u
127-18-4--------Tetrachloroethene 5 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 5 u
108-88-3--------Toluene 8
108-90-7--------Chlorobenzene 5 u
100-41-4--------Ethylbenzene 5 u
100-42-5--------styrene 5 u
1330-20-7-------Xylene (total) I JJ 15 J
FORM I VOA 1/87 Rev.
lA
VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO.
Lab Name: ITAS-KNOXVILLE Contract:
NS32
Lab Code: ITSTU Case No.: 53103 SAS No.: SDG No.: NS31
Matrix: ( soil/water) WATER Lab Sample ID: VV3295
Sample wt/vol: 5.0 (g/mL) ~ Lab File ID: VV3295
Level: (low/med) LOW Date Received: 12l'.19l'.92
% Moisture: not dee. Date Analyzed: 12l'.22l'.92
Column: (pack/cap) CAP Dilution Factor: 1.0 -
CAS NO. COMPOUND CONCENTRATION UNITS:
(ug/L or ug/Kg) UGl'.L Q
74-87-3---------Chloromethane 10 u 74-83-9---------Bromomethane 10 u 75-01-4---------Vinyl Chloride 10 u 75-00-3---------Chloroethane 10 u 75-09-2---------Methylene Chloride 5 u 67-64-1---------Acetone 10 u 75-15-o---------carbon Disulfide 5 u 75-35-4---------1,1-Dichloroethene 5 u 75-34-3---------1,1-Dichloroethane 5 u 540-59-0--------1,2-Dichloroethene (total)_ 5 u 67-66-3---------Chloroform 5 u 107-06-2--------1,2-Dichloroethane 5 u 78-93-3---------2-Butanone 10 u 71-55-6---------1,1,1-Trichloroethane 5 u 56-23-5---------Carbon Tetrachloride 5 u 108-05-4--------Vinyl Acetate 10 u
75-27-4---------Bromodichloromethane 5 u
78-87-5---------1,2-Dichloropropane 5 u
10061-01-5------cis-l,3-Dichloropropene 5 u
79-01-6---------Trichloroethene 5 u 124-48-1--------Dibromochloromethane 5 u
79-00-5---------1,1,2-Trichloroethane 5 u
71-43-2---------Benzene 5 u
10061-02-6------trans-l,3-Dichloropropene __ 5 u
75-25-2---------Bromoform 5 u
108-10-1--------4-Methyl-2-Pentanone 10 u
591-78-6--------2-Hexanone 10 u
127-18-4--------Tetrachloroethene 5 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 5 u
108-88-3--------Toluene 5 u
108-90-7--------Chlorobenzene 5 u
100-41-4--------Ethylbenzene 5 u
100-42-5--------styrene 5 u
1330-20-7-------Xylene (total) 5 u
FORM I VOA 1/87 Rev.
I
I
,I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
3A
WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No.: SDG No.: NS31
Matrix Spike -EPA Sample No.: ~N~S~3~2 ____ _
SPIKE SAMPLE MS MS QC
ADDED CONCENTRATION CONCENTRATION % LIMITS
COMPOUND (ug/L) (ug/L) (ug/L) REC # REC. ======================== ========= ============= ============= ====== ==::::::::==
1,1-Dichloroethene 50.0 0 51.2 102 61-145
Trichloroethene 50.0 0 50.0 100 71-120
Benzene 50.0 0 43.6 87 76-127
Toluene 50.0 0 45.8 92 76-125
Chlorobenzene 50.0 0 47.6 95 75-130
SPIKE MSD MSD
ADDED CONCENTRATION % % QC LIMITS
COMPOUND (ug/L) (ug/L) REC # RPD # RPD REC. ======================== -------=-============= ====== ====== ====== ======
1,1-Dichloroethene 50.0 53.5 107 -5 14
Trichloroethene 50.0 51. 0 102 -2 14
Benz.ene 50.0 43.7 87 0 11
Toluene 50.0 45.4 91 l 13
Chlorobenzene 50.0 48.4 97 -2 13
# Column to be used to flag recovery and RPO values with an asterisk
• Values outside of QC limits
RPD: o out of 5 outside limits
Spike Recovery: O out of _lQ outside limits
COMMENTS: CLP,53103,NS3l,NS32,LOW,WATER,VV3295,VOA,EPA,
OWA3:5ML PURGED W/ 50PPB IS+SS
FORM III VOA-1
61-145
71-120
76-127
76-125
75-130
1/87 ?.ev.
lA
VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO.
Lab Name: ITAS-KNOXVILLE Contract:
TRIPBLANK
Lab Code: ITSTU Case No.: 53103 SAS No.: SDG No.: NS3l
Matrix: ( soil/water) WATER Lab sample ID: VV3298
sample wt/vol: 5.0 (g/mL) !&_ Lab File ID: VV3298
Level: (low/med) LOW Date Received: 12,'.19,'.92
% Moisture: not dee. Date Analyzed: 12,'.22,'.92
Column: (pack/cap) CAP Dilution Factor: l.O
CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG,'.L Q
' 74-87-3---------Chloromethane 10 u
74-83-9---------Bromomethane 10 u 75-01-4---------Vinyl Chloride 10 u 75-00-3---------Chloroethane 10 u 75-09-2---------Methylene Chloride 2 BJ 67-64-1---------Acetone 10 u 75-15-o---------carbon Disulfide 5 u
75-35-4---------1,l-Dichloroethene 5 u
75-34-3---------l,l-Dichloroethane 5 u
540-59-0--------l,2-Dichloroethene (total)_ 5 u
67-66-3---------Chloroform 5 u
107-06-2--------1,2-Dichloroethane 5 u 78-93-3---------2-Butanone 10 u
71-55-6---------1,1,1-Trichloroethane 5 u
56-23-5---------carbon Tetrachloride 5 u
108-05-4--------Vinyl Acetate 10 u 75-27-4---------Bromodichloromethane 5 u
78-87-5---------1,2-Dichloropropane 5 u
10061-01-5------cis-l,3-Dichloropropene 5 u
79-01-6---------Trichloroethene 5 u
124-48-1--------Dibromochloromethane 5 u
79-00-5---------1,1,2-Trichloroethane 5 u
71-43-2---------Benzene 5 u
10061-02-6------trans-1,3-Dichloropropene __ 5 u
75-25-2---------Bromoform 5 u
108-10-1--------4-Methyl-2-Pentanone 10 u
591-78-6--------2-Hexanone 10 u
127-18-4--------Tetrachloroethene 5 u
79-34-5---------1,1,2,2-Tetrachloroethane __ 5 u
108-88-3--------Toluene 5 u
108-90-7--------Chlorobenzene 5 u
100-41-4--------Ethylbenzene 5 u
100-42-5--------styrene 5 u
1330-20-7-------Xylene (total) 5 u
FORM I VOA 1/87 Rev.
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
I
I
I
B
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
lA
VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO.
Lab Name: ITAS-KNOXVILLE Contract:
VBLKl
Lab Code: ITSTU Case No.: 53103 SAS No.: SOG No.: NS31
Matrix: ( soil/water) WATER Lab Sample IO: VB12224
Sample wt/vol: 5.0 (g/mL) ~ Lab File IO: VB12224
Level: (low/med) LOW Date Received:
% Moisture: not dee. Date Analyzed: 12L22L92
Column: (pack/cap) CAP Dilution Factor: 1.0 -
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UGLL Q
74-87-3---------Chloromethane 10 u 74-83-9---------Bromomethane 10 u 75-01-4---------Vinyl Chloride 10 u 75-00-3---------Chloroethane 10 u 75-09-2---------Methylene Chloride 2 J -67-64-1---------Acetone 10 u 75-15-o---------carbon Disulfide 5 u 75-35-4---------1,1-Dichloroethene 5 u 75-34-3---------1,1-Dichloroethane 5 u 540-59-0--------1,2-Dichloroethene (total)_ 5 u 67-66-3---------Chloroform 5 u 107-06-2--------1,2-0ichloroethane 5 u 78-93-3---------2-Butanone 10 u 71-55-6---------1,1,1-Trichloroethane 5 u 56-23-5---------carbon Tetrachloride 5 u 108-05-4--------Vinyl Acetate 10 u 75-27-4---------Bromodichloromethane 5 u 78-87-5---------1,2-Dichloropropane 5 u 10061-01-5------cis-l,3-0ichloropropene 5 u 79-01-6---------Trichloroethene 5 u 124-48-1--------Dibromochloromethane 5 u 79-00-5---------1,1,2-Trichloroethane 5 u 71-43-2---------Benzene 5 u 10061-02-6------trans-l,3-Dichloropropene __ 5 u 75-25-2---------Bromoform 5 u 108-10-1--------4-Methyl-2-Pentanone 10 u 591-78-6--------2-Hexanone 10 u 127-18-4--------Tetrachloroethene 5 u 79-34-5---------1,1,2,2-Tetrachloroethane __ 5 u 108-88-3--------Toluene 5 u 108-90-7--------Chlorobenzene 5 u 100-41-4--------Ethylbenzene 5 u 100-42-5--------styrene 5 u 1330-20-7-------Xylene (total) 5 u
FORM I VOA 1/87 Rev.
1B EPA SAMPLE NO. SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
NS31 Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No.: ~N~A,..._ __ SDG No.: NS31
Matrix: ( soil/water) WATER Lab Sample ID: VV3299
Sample wt/vol: 1000 (g/mL) !:&.._ Lab File ID: VV3299
Level: (low/med) LOW Date Received: 121'.'.191'.'.92
\ Moisture: not dee. dee. Date Extracted: 121'.'.231'.'.92
Extraction: ( SepF /Cont/Sonc) SEPF Date Analyzed: Oli'.091'.'.93
GPC Cleanup: (Y/N) !i..._ pH: Dilution Factor: 1.0
CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UGl'.'.L Q
108-95-2--------Phenol 43
lll-44-4--------bis(2-Chloroethyl)Ether 28 95-57-8---------2-Chlorophenol 10 u 541-73-1--------1,3-Dichlorobenzene 10 u
106-46-7--------1,4-Dichlorobenzene 10 u 100-51-6--------Benzyl Alcohol 10 u 95-50-1---------1,2-Dichlorobenzene 10 u
95-48-7---------2-Methylphenol 10 u 108-60-1--------bis(2-Chloroisopropyl)Ether_ 10 u 106-44-5--------4-Methylphenol 10 u
621-64-7--------N-Nitroso-Di-n-Propylamine_-_ 10 u 67-72-1---------Hexachloroethane 10 u
98-95-3---------Nitrobenzene 10 u
78-59-1---------Isophorone 10 u
88-75-5---------2-Nitrophenol 10 u
105-67-9--------2,4-Dimethylphenol 10 u
65-85-0---------Benzoic Acid 6 J
111-91-1--------bis(2-Chloroethoxy)Methane __ 10 u
120-83-2--------2,4-Dichlorophenol 10 u
120-82-1--------1,2,4-Trichlorobenzene 10 u
91-20-3---------Naphthalene 10 u
106-47-8--------4-Chloroaniline 10 u
87-68-3---------Hexachlorobutadiene 10 u
59-50-7---------4-Chloro-3-Methylphenol 10 u
91-57-6---------2-Methylnaphthalene 10 u
77-47-4---------Hexachlorocyclopentadiene __ 10 u
88-06-2---------2,4,6-Trichlorophenol 10 u
95-95-4---------2,4,5-Trichlorophenol 50 u
91-58-7---------2-Chloronaphthalene 10 u
88-74-4---------2-Nitroaniline 50 u
131-11-3--------Dimethyl Phthalate 10 u
208-96-8--------Acenaphthylene 10 u
606-20-2--------2,6-Dinitrotoluene 10 u
FORM I SV-1 1/87 Rev.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
lC EPA SAMPLE NO.
SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
NS31
Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No.: ~N~A __ _ SDG No.: NS31
Matrix: (soil/water) WATER Lab Sample ID: VV3299
Sample wt/vol: 1000 (g/mL) ~ Lab File ID: VV3299
Level: (low/med) LOW Date Received: 12,:19,:92
% Moisture: not dee. dee. Date Extracted: 12,:23,:92
Extraction: ( SepF / Cont/ Sonc) SEPF Date Analyzed: 01,:09i93
GPC Cleanup: (Y/N) L pH: Dilution Factor: 1.0
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG,:L Q
99-09-2---------3-Nitroaniline 50 u
83-32-9---------Acenaphthene 10 u
51-28-5---------2,4-Dinitrophenol 50 u
100-02-7--------4-Nitrophenol 50 u
132-64-9--------Dibenzofuran 10 u
121-14-2--------2,4-Dinitrotoluene 10 u
84-66-2---------Diethylphthalate 10 u
7005-72-3-------4-Chlorophenyl-phenylether __ 10 u
86-73-7---------Fluorene 10 u
100-01-6--------4-Nitroaniline 50 u
534-52-1--------4,6-Dinitro-2-Methylphenol __ 50 u
86-30-6---------N-Nitrosodiphenylamine (l) __ 10 u
101-55-3--------4-Bromophenyl-phenylether __ 10 u
118-74-1--------Hexachlorobenzene 10 u
87-86-5---------Pentachlorophenol 50 u
85-01-8---------Phenanthrene 10 u
120-12-1--------Anthracene 10 u
84-74-2---------Di-n-Butylphthaiate 10 u
206-44-0--------Fluoranthene 10 u
129-00-0--------Pyrene 10 u
85-68-7---------Butylbenzylphthalate 10 u
91-94-1---------3,3'-Dichlorobenzidine 20 u
56-55-3---------Benzo(a)Anthracene 10 u
218-01-9--------Chrysene 10 u
117-81-7--------bis(2-Ethylhexyl)Phthalate_ 10
117-84-0--------Di-n-Octyl Phthalate 10 u
205-99-2--------Benzo(b)Fluoranthene 10 u
207-08-9--------Benzo(k)Fluoranthene 10 u
50-32-8---------Benzo(a)Pyrene 10 u
193-39-5--------Indeno(l,2,3-cd)Pyrene 10 u
53-70-3---------Dibenz(a,h)Anthracene 10 u
191-24-2--------Benzo(g,h,i)Perylene 10 u
(1) -Cannot be separated from D1phenylam1ne
FORM I SV-2 1/87 Rev.
1B EPA SAMPLE NO.
SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
NS31B Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No.: :..:.N'--'A __ _ SDG No.: NS31
Matrix: ( soil/water) WATER Lab Sample ID: VV3300
sample wt/vol: 1000 (g/mL) ML Lab File ID: VV3300
Level: (low/med) LOW Date Received: 12/19/92
% Moisture: not dee. dee. Date Extracted: 12/23/92
Extraction: ( SepF / cont/ sonc) SEPF Date Analyzed: 01/10/93
GPC Cleanup: (Y/N) N pH: Dilution Factor: 1.0
CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
108-95-2--------Phenol 57
lll-44-4--------bis(2-Chloroethyl)Ether 28
95-57-8---------2-Chlorophenol 10 u
541-73-1--------1,3-Dichlorobenzene 10 u -
106-46-7--------1,4-Dichlorobenzene 10 u
100-51-6--------Benzyl Alcohol 10 u
95-50-1---------1,2-Dichlorobenzene 10 u
95-48-7---------2-Methylphenol 10 u
108-60-l--------bis(2-Chloroisopropyl)Ether_ 10 u
106-44-5--------4-Methylphenol 10 u
621-64-7--------N-Nitroso-Di-n-Propylamine __ 10 u
67-72-1---------Hexachloroethane 10 u
98-95-3---------Nitrobenzene 10 u
78-59-1---------Isophorone 10 u
88-75-5---------2-Nitrophenol 10 u
105-67-9--------2,4-Dimeth¥lphenol 10 u
65-85-0---------Benzoic Acid 9 J
111-91-1--------bis(2-Chloroethoxy)Methane __ 10 u
120-83-2--------2,4-Dichlorophenol 10 u
120-82-1--------1,2,4-Trichlorobenzene 10 u
91-20-3---------Naphthalene 10 u
106-47-8--------4-Chloroaniline 10 u
87-68-3---------Hexachlorobutadiene 10 u
59-50-7---------4-Chloro-3-Methylphenol 10 u
91-57-6---------2-Methylnaphthalene 10 u
77-47-4---------Hexachlorocyclopentadiene __ 10 u
88-06-2---------2,4,6-Trichlorophenol 10 u
95-95-4---------2,4,5-Trichlorophenol 50 u
91-58-7---------2-Chloronaphthalene 10 u
88-74-4---------2-Nitroaniline 50 u
131-11-3--------Dimethyl Phthalate 10 u
208-96-8--------Acenaphthylene 10 u
606-20-2--------2,6-Dinitrotoluene 10 u
FORM I SV-1 1/87 Rev.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
fl
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
lC EPA SAMPLE NO.
SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
NS31B
Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No. : ~N=A __ _ SDG No.: NS31
Matrix: (soil/water) WATER Lab Sample ID: VV3300
Sample wt/vol: 1000 (g/mL) ~ Lab File ID: VV3300
Level: (low/med) LOW Date Received: 12L'.19L'.92
% Moisture: not dee. dee. Date Extracted: 12L'.23L'.92
Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: OlL'.lOL'.93
GPC Cleanup: (Y/N) L pH: Dilution Factor: 1.0
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UGL'.L Q
99-09-2---------3-Nitroaniline 50 u
83-32-9---------Acenaphthene 10 u
51-28-5---------2,4-Dinitrophenol 50 u
100-02-1--------4-Nitrophenol 50 u
132-64-9--------Dibenzofuran 10 u
121-14-2--------2,4-Dinitrotoluene 10 u
84-66-2---------Diethylphthalate 10 u
7005-72-3-------4-Chlorophenyl-phenylether __ 10 u
86-73-7---------Fluorene 10 u
100-01-6--------4-Nitroaniline 50 u
534-52-1--------4,6-Dinitro-2-Methylphenol __ 50 u
86-30-6---------N-Nitrosodiphenylamine (l) __ 10 u
101-55-3--------4-Bromophenyl-phenylether __ 10 u
118-74-1--------Hexachlorobenzene 10 u
87-86-5---------Pentachlorophenol 50 u
85-01-8---------Phenanthrene 10 u
120-12-1--------Anthracene 10 u
84-74-2---------Di-n-Butylphthalate 10 u
206-44-0--------Fluoranthene 10 u
129-0o-o--------Pyrene 10 u
85-68-7---------Butylbenzylphthalate 10 u
91-94-1---------3,3'-Dichlorobenzidine 20 u
56-55-3---------Benzo(a)Anthracene 10 u
218-01-9--------Chrysene 10 u
ll7-81-7--------bis(2-Ethylhexyl)Phthalate 22
117-84-0--------Di-n-octyl Phthalate --10 u
205-99-2--------Benzo(b)Fluoranthene 10 u
207-08-9--------Benzo(k)Fluoranthene 10 u
50-32-8---------Benzo(a)Pyrene 10 u
193-39-5--------Indeno(l,2,3-cd)Pyrene 10 u
53-70-3---------Dibenz(a,h)Anthracene 10 u
191-24-2--------Benzo(g,h,i)Perylene 10 u
(l) -cannot be separated from Diphenylamine
FORM I SV-2 1/87 Rev.
1B
SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO.
Lab Name: ITAS-KNOXVILLE Contract:
NS32
Lab Code: ITSTU Case No.: 53103 SAS No. : "N~A~--SDG No.: NS3l
Matrix: (soil/water) WATER Lab Sample ID: VV3301
Sample wt/vol: 1000 (g/mL) ML Lab File ID: VV330l
Level: (low/med) LOW Date Received: 12,:'.19,:'.92
% Moisture: not dee. dee. Date Extracted: 12,:'.23,:'.92
Extraction: (SepF/Cont/Sonc) ~ Date Analyzed: 01,:'.10,:'.93
GPC Cleanup: (Y/N) L pH: Dilution Factor: 1.0
CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG,:'.L Q
108-95-2--------Phenol 10 u
lll-44-4--------bis(2-Chloroethyl)Ether 10 u 95-57-8---------2-Chlorophenol 10 u 541-73-1--------1,3-Dichlorobenzene 10 u 106-46-7--------1,4-Dichlorobenzene 10 u 100-51-6--------Benzyl Alcohol 10 u
95-50-1---------l,2-Dichlorobenzene 10 u 95-48-7---------2-Methylphenol 10 u
108-60-l--------bis(2-Chloroisopropyl)Ether_ 10 u 106-44-5--------4-Methylphenol 10 u 621-64-7--------N-Nitroso-Di-n-Propylamine __ 10 u
67-72-1---------Hexachloroethane 10 u 98-95-3---------Nitrobenzene 10 u 78-59-1---------Isophorone 10 u
88-75-5---------2-Nitrophenol 10 u
105-67-9--------2,4-Dimethylphenol 10 u 65-85-o---------Benzoic Acid 50 u
lll-91-l--------bis(2-Chloroethoxy)Methane __ 10 u
120-83-2--------2,4-Dichlorophenol 10 u
120-s2-1--------l,2,4-Trichlorobenzene 10 u
91-20-3---------Naphthalene 10 u
106-47-8--------4-Chloroaniline 10 u
87-68-3---------Hexachlorobutadiene 10 u
59-50-7---------4-Chloro-3-Methylphenol 10 u
91-57-6---------2-Methylnaphthalene 10 u
77-47-4---------Hexachlorocyclopentadiene __ 10 u
88-06-2---------2,4,6-Trichlorophenol 10 u
95-95-4---------2,4,5-Trichlorophenol 50 u
91-58-7---------2-Chloronaphthalene 10 u
88-74-4---------2-Nitroaniline 50 u
131-11-3--------Dimethyl Phthalate 10 u
208-96-8--------Acenaphthylene· 10 u
606-20-2--------2,6-Dinitrotoluene 10 u
FORM I SV-1 1/87 Rev.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
lC EPA SAMPLE NO.
SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
NS32
Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No. : '-'N-"A'----SDG No.: NS31
Matrix: (soil/water) WATER Lab Sample ID: VV3301
Sample wt/vol: 1000 (g/mL) !:!k_ Lab File ID: VV3301
Level: (low/med) LOW Date Received: 12/19/92 I % Moisture: not dee. dee. Date Extracted: 12/23/92
I
I
I
I
I
I
I
I
I
I
I
I
Extraction: (SepF/Cont/Sonc) Date Analyzed: 01/10/93
GPC Cleanup: (Y/N) .!L_ pH: Dilution Factor: 1.0
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
99-09-2---------3-Nitroaniline 50 u
83-32-9---------Acen~phthene 10 u
Sl-28-s-~-------2,4-Dinitrophenol so u
100-02-7--------4-Nitrophenol 50 u
132-64-9--------Dibenzofuran 10 u
121-14-2--------2,4-Dinitrotoluene 10 u
84-66-2---------Diethylphthalate 10 u
?OOS-72-3-------4-Chlorophenyl-phenylether __ 10 u
86-73-7---------Fluorene 10 u
100-01-6--------4-Nitroaniline so u
S34-S2-1--------4,6-Dinitro-2-Methylphenol __ so u
86-30-6---------N-Nitrosodiphenylamine (1) __ 10 u
101-SS-3--------4-Bromophenyl-phenylether __ 10 u
118-74-1--------Hexachlorobenzene 10 u
87-86-S---------Pentachlorophenol so u
BS-01-8---------Phenanthrene 10 u
120-12-1--------Anthracene 10 u
84-74-2---------Di-n-Butylphthalate 10 u
206-44-0--------Fluoranthene 10 u
129-00-o--------Pyrene 10 u
85-68-7---------Butylbenzylphthalate 10 u
91-94-1---------3,3'-Dichlorobenzidine 20 u
S6-SS-3---------Benzo(a)Anthracene 10 u
218-01-9--------Chrysene 10 u
117-81-7--------bis(2-Ethylhexyl)Phthalate_ 4 J
117-84-0--------Di-n-Octyl Phthalate 10 u
20S-99-2--------Benzo(b)Fluoranthene 10 u
207-08-9--------Benzo(k)Fluoranthene 10 u
S0-32-8---------Benzo(a)Pyrene 10 u
193-39-S--------Indeno(l,2,3-cd)Pyrene 10 u
S3-70-3---------Dibenz(a,h)Anthracene 10 u
191-24-2--------Benzo(g,h,i)Perylene 10 u
(l) -Cannot be separated from Diphenylamine
FORM I SV-2 1/87 Rev.
JC
WATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITS TU Case No.: 53103 SAS No.: ,_,N.,,,A'----SDG No.: NS31
Matrix Spike -EPA Sample No.: NS32 ==-----
SPIKE SAMPLE MS MS QC ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND (ug/L) (ug/L) (ug/L) REC # REC. ======================== ========= -==------=---============= ====== ====== Phenol 400 0 153 38 12-86 2-Chlorophenol 400 0 290 72 27-123 1,4-Dichlorobenzene 200 0 196 98 • 36 97 N-Nitroso-di-n-prop:-rrf 200 0 182 91 41 116 1,2,4-Trichlorobenzene 200 0 215 108 • 39 98 4-Chloro-3-methylphenoI 400 0 266 66 23 97 Acenaphthene 200 0 220 110 46-118 4-Nitrophenol 400 0 95.6 24 10-80 2,4-Dinitrotoluene 200 0 193 96 24-96 Pentachlorophenol 400 0 193 48 9-103 Pyrene 200 0 188 94 26-127
SPIKE MSD MSD
ADDED CONCENTRATION % % QC LIMITS COMPOUND (ug/L) (ug/L) REC # RPD # RPD ---=========------------========= ============= ====== ====== ====== Phenol 400 163 41 -8 42
2-Chlorophenol 400 334 84 -15 40 i',4-Dichlorobenzene 200 194 97 l 28 N-Nitroso-di-n-prop:-rrf 200 176 88 3 38
1,2,4-Trichlorobenzene_ 200 214 107 • l 28
4-Chloro-3-methylphenol 400 320 80 -19 42 Acenaphthene 200 218 109 l 31
4-Nitro1henol 400 109 27 -12 50 2,4-Din trotoluene 200 197 98 • -2 38
Pentachlorophenol 400 290 72 -40 50
Pyrene 200 186 93 l 31
(1) N-Nitroso-di-n-propylamine
# Column to be used to flag recovery and RPD values with an asterisk
• Values outside of QC limits
RPD: O out of 11 outside limits
Spike Recovery: -4-out of ...1£ outside limits
COMMENTS: CLP,53103,,NS32,LOW,WATER,VV3301,BNA,EPA,
INST:4500:RESTEK XTI (30*;32MM/1L'M) 40-325@10D/M: 2UL INJ
REC.
======
12-86
27-123
36 97
41 116
39 98
23 97
4 6-118
10-80
24-96
9-103
26-127
FORM III SV-1 1/87 Rev.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
•
D
I
·1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
lB EPA SAMPLE NO.
SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
SBLKi ._
Lab Name: ITAS-KNOXVILLE Contract:
Lab Code: ITSTU Case No.: 53103 SAS No. : "'N'-'A~--SDG No.: NS31
Matrix: (soil/water) WATER Lab Sample ID: BL2801
Sample wt/vol: 1000 (g/mL) ML Lab File ID: BL2801
Level: ( low/med) LOW Date Received: 12Ll9L92
% Moisture: not dee. dee. Date Extracted: 12L23L92
Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 01L09L93
GPC Cleanup: (Y/N) !i._ pH: Dilution Factor: 1.0
CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UGLL Q
108-95-2--------Phenol. 10 u
lll-44-4--------bis(2-Chloroethyl)Ether 10 u
95-57-8---------2-Chlorophenol 10 u 541-73-1--------1,3-Dichlorobenzene 10 u 106-46-7--------1,4-Dichlorobenzene 10 u 100-51-6--------Benzyl Alcohol 10 u
95-50-1---------1,2-Dichlorobenzene 10 u 95-48-7---------2-Methylphenol 10 u
108-60-l--------bis(2-Chloroisopropyl)Ether_ 10 u 106-44-5--------4-Methylphenol 10 u 621-64-7--------N-Nitroso-Di-n-Propylamine __ 10 u 67-72-1---------Hexachloroethane 10 u 98-95-3---------Nitrobenzene 10 u
78-59-1---------Isophorone 10 u 88-75-5---------2-Nitrophenol 10 u 105-67-9--------2,4-Dimethylphenol 10 u
65-85-o---------Benzoic Acid 50 u lll-91-1--------bis(2-Chloroethoxy)Methane __ 10 u
120-83-2--------2,4-Dichlorophenol 10 u
120-82-1--------1,2,4-Trichlorobenzene 10 u
91-20-3---------Naphthalene 10 u 106-47-8--------4-Chloroaniline 10 u
87-68-3---------Hexachlorobutadiene 10 u 59-50-7---------4-Chloro-3-Methylphenol 10 u 91-57-6---------2-Methylnaphthalene 10 u
77-47-4---------Hexachlorocyclopentadiene __ 10 u 88-06-2---------2,4,6-Trichlorophenol 10 u
95-95-4---------2,4,5-Trichlorophenol 50 u
91-58-7---------2-Chloronaphthalene 10 u
88-74-4---------2-Nitroaniline 50 u
131-11-3--------Dimethyl Phthalate 10 u
208-96-8--------Acenaphthylene 10 u
606-20-2--------2,6-Dinitrotoluene 10 u
FORM I SV-1 1/87 Rev.
lC SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO.
Lab Name: ITAS-KNOXVILLE Contract: SBLKl
Lab Code: ITSTU Case No.: 53103 SAS No. : '-'N"'A,__ __ SDG No.: NS31
Matrix: ( soil/water) WATER Lab Sample ID: BL2801
sample wt/vol: 1000 (g/mL) !1k.._ Lab File ID: BL2801
Level: (low/med) LOW Date Received: 12/19/92
% Moisture: not dee. dee. Date Extracted: 12/23/92
Extraction: (SepF/Cont/Sonc) ~ Date Analyzed: 01/09/93
GPC Cleanup: (Y/N) N pH: Dilution Factor: 1.0
CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
99-09-2---------3-Nitroaniline so u 83-32-9---------Acenaphthene 10 u 51-28-5---------2,4-Dinitrophenol so u 100-02-7--------4~Nitrophenol so u t-132-64-9--------Dibenzofuran 10 u 121-14-2--------2,4-Dinitrotoluene 10 u 84-66-2---------Diethylphthalate 10 u 7005-72-3-------4-Chlorophenyl-phenylether __ 10 u 86-73-7---------Fluorene 10 u 100-01-6--------4-Nitroaniline so u 534-52-1--------4,6-Dinitro-2-Methylphenol __ so u 86-30-6---------N-Nitrosodiphenylamine (1) __ 10 u 101-55-3--------4-Bromophenyl-phenylether __ 10 u 118-74-1--------Hexachlorobenzene 10 u 87-86-5---------Pentachlorophenol so u 85-01-8---------Phenanthrene 10 u 120-12-1--------Anthracene 10 u 84-74-2---------Di-n-Butylphthalate 10 u 206-44-0--------Fluoranthene 10 u 129-00-o--------Pyrene 10 u 85-68-7---------Butylbenzylphthalate 10 u 91-94-1---------3,3'-Dichlorobenzidine 20 u 56-55-3---------Benzo(a)Anthracene 10 u 218-01-9--------Chrysene 10 u
117-81-7--------bis(2-Ethylhexyl)Phthalate 10 u 117-84-0--------Di-n-Octyl Phthalate --10 u 205-99-2--------Benzo(b)Fluoranthene 10 u 207-08-9--------Benzo(k)Fluoranthene 10 u 50-32-8---------Benzo(a)Pyrene 10 u 193-39-5--------Indeno(l,2,3-cd)Pyrene 10 u
53-70-3---------Dibenz(a,h)Anthracene 10 u
191-24-2--------Benzo(g,h,i)Perylene 10 u
(1) -Cannot be separated from Diphenylamine
FORM I SV-2 1/87 Rev.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
U.S. EPA -CLP
1
INORGANIC ANALYSES DATA SHEET
Lab Name: ITAS_KNOXVILLE _____ _ Contract: NAT._STARC
EPA SAMPLE NO.
NS-31B
I Lab Code: ITSTU
Matrix (soil/water): WATER
Case No.: 53103 SAS No.: ___ SDG No.: NS-31
Lab Sample ID: VV3305
Date Received: 12/19/92 I Level (low/med):
% Solids:
LOW_
o.o
I
I
I
I
I
I
I
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No.
7429-90-5
7440-36-0
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4 7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7439-97-6
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
I Color Before: COLORLESS
Color After: COLORLESS
I Comments:
I
I
I
I
I
I
Analyte Concentration C Q
Aluminum :!400 -
Antimony-30.0 u
Arsenic -2.4 B Barium -221
Beryll'Ium 1.3 13
Cadmium 5.0 u Calcium-2!!0000 Chromium-64.2 -
Cobalt 20.0 u Copper--21.9 B Iron --4250 -Lead 3.8 w Magnesium J.270 Ii ---
Manganese 64.6
Mercury 0.20 u Nickel 37.3 B Potass'Ium 18300 Selenium 4.0 u
Silver -5.0 u Sodium --19700
Thallium 2.0 u w Vanadium-J.0. 0 u ---
Zinc 74.1
Cyanii'Ie ---
Clarity Before: CLEAR_
Clarity After: CLEAR_
FORM I -IN
M
is-p-
F-p-
p-
p-
p p-
p-
p-
p-
F-p-
p-
CV p p-
F-
p-
p-
F-
p-
p-
NR:
-
Texture:
Artifacts:
3/90
U.S. EPA -CLP
1
INORGANIC ANALYSES DATA SHEET
Lab Name: ITAS_KNOXVILLE. ____ _ Contract: NAT._STARC
SAS No.: Lab Code: ITSTU_ Case No.: 53103
EPA SAMPLE NO.
NS-32
SDG No.: NS-31_
Matrix (soil/water): WATER
Level (low/med):
% Solids:
LOW
_o.o
Lab Sample ID: VV3306 __
Date Received: 12/19/92
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No.
7429-90-5
7440-36-0
7440-38-2
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-92-1
7439-95-4
7439-96-5
7439-97-6
7440-02-0
7440-09-7
7782-49-2
7440-22-4
7440-23-5
7440-28-0
7440-62-2
7440-66-6
Color Before: COLORLESS
Color After: COLORLESS
Comments:
Analyte Concentration C Q
Aluminum 26~1l -
Antimony-30.0 u Arsenic -2.0 u Barium -87.5 B Berylliuiii 1.0 u Cadmium 5.0 u Calcium-51200
Chromium 10.0 u Cobalt 20.0 u Copper--14.3 B Iron --3470 Lead 2.0 u Magnesium !!980 Manganese 143 -
Mercury u.20 u Nickel -20.0 u Potassiuiii 2380 B Selenium_ 4.0 u Silver 5.0 u Sodium--8660 Thallium 2.0 u w Vanadium-J.0. 0 u ---
Zinc 15.8 B Cyaniae_ --
Clarity Before: CLEAR_
Clarity After: CLEAR_
FORM I -IN
M
~ p-
F-p-
p-
p-
p-
p-
p-
p-
p-
F-p-
p-
CV p p-
F-p-
p-
F-p-
p-
NR:
-
Texture:
Artifacts:
3/90
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
U.S. EPA -CLP
5A EPA SAMPLE NO. SPIKE SAMPLE RECOVERY
Lab Name: ITAS_KNOXVILLE, ____ _ I NS-32S Contract: NAT._STARC ______ _
Lab Code: ITSTU_ Case No. : 53103 SAS No.: SDG No.: NS-31_
Level (low/med): LOW Matrix (soil/water): WATER_
t Solids for Sample: o.o
Concentration Units (ug/L or mg/kg dry weight): UG/L_
Control V\/33ox-s
Limit Spiked Sample Sample Spike Analyte tR Result (SSR) C Result (SR) C Added (SA)
Aluminum 75-125 4,... 1.4. Juuu 2o.l9.62uu 2000.00 Antimony-75-125-519.6800----30.0000 u --500.00 Arsenic -75-125-2055.2500--40.0000 u 2000.00 Barium -75-125-2058.5200--87.5100 B --2000.00 Beryllium 75-125-55.6900= -1. 0000 u --50.00 cadmium 75-125= 41.6300 5.0000 u 50.00 Calcium-- -
Chromium_ 75-125 213.0000 -10.0000 u 200.00 Cobalt 75-125-498.8700--20.0000 u 500.00 Copper 75-125-260.2400--14.3000 B 250.00 Iron 75-125-4613.1400--3474.0100 1000.00 Lead 75-125= 498.9300= ---40.0000 u --500.00 Magnesium
Manganese 15-125 633.7900 -143.4300 -500.00 Mercury 75-125-0.9200--0.2000 u 1.00 Nickel -75-125= 505.9300= -20.0000 u 500.00 Potassiuiii
Selenium_ 75-125 1946.3500 -60.0000 u 2000.00 Silver 75-125= 47.9800= -5.0000 u --50.00 Sodium--
Thalliwn 75-125 2003.2200 -40.0000 u 2000.00 Vanadium-75-125= 497.3100--10.0000 u --500.00 Zinc -75-125 504.9000= -15.7500 B 500.00 cyaniae_ ---
tR Q M
99.2 -p--
--ro3.9 p-
-102.0 -p-
98.6 -p-
--r11.4 -p-
-83.3 -p----~ 1o6.5 -p -99.8 p-
--98.4 -p-
--r13.9 -p-
99.8 -p----~ 98.1 -p
--92.0 -CV --ro1.2 p -~
97.3 p
-96.0 -p
-NR
100.2 p -99.5 -p-
--97.8 -p----NR -
I Comments:
----
I
I
I
I
I
I
I
FORM V (Part 1) -IN 3/90
U.S. EPA -CLP
5A EPA SAMPLE NO. SPIKE SAMPLE RECOVERY
Lab Name: ITAS KNOXVILLE ____ _ I NS-32S Contract: NAT._STARC ______ _
Lab Code: ITSTU Case No.: 53103
Matrix (soil/water): WATER
% Solids for Sample: _o.o
SAS No.: SDG No.: NS-31_
Level (low/med): LOW_
Concentration Units (ug/L or mg/kg dry weight): UG/L_
control 1111;301-s
Limit Spiked Sample Sample Spike Analyte %R Result (SSR) C Result (SR) C Added (SA) %R Q M
Aluminum -lffi Antimony---NR Arsenic -75-125 43.6500 -2.0000 u 40.00 1o9.1 -F Barium --

-
--NR Berylliuiii ---NR Cadmium ---NR Calcium----NR Chromium ---NR Cobalt ---NR Copper----NR ~ Iron ----NR Lead 75-125 19.7300 -2.0000 u 20.00 98.6 -F Magnesium --

-
---NR Manganese ---NR Mercury ---NR Nickel ----NR Potassiuiii ---NR Selenium_ 75-125 9.7400 n 4.0000 u 10.00 97.4 -F Silver -----NR Sodium-----NR Thalliwn 75-125 43.5000 -2.0000 u 50.00 87.0 -F Vanadium-------NR Zinc ---NR Cyaniae ---NR -------
Comments:
FORM V (Part 1) -IN 3/90
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I U.S. EPA -CLP
5B
POST'DIGEST SPIKE SAMPLE RECOVERY
EPA SAMPLE NO.
I Lab Name: ITAS_KNOXVILLE ____ _ Contract: NAT._STARC NS-32A
I Lab Code: ITSTU _
Matrix (soil/water)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,I
I
Control
Limit Analyte %R
Aluminum Antimony-
Arsenic -
Barium -
BeryllTuiii
Cadmium Calcium-
Chromium_
Cobalt Copper--
Iron --
Lead
Magnesium
Manganese
Mercury Nickel -
Potassium
Selenium
Silver Sodium--
Thallium
Vanadium-
Zinc -
Cyaniae_
Comments:
Case No.: 53103
WATER
SAS No.: SDG No.: NS-31_
Level (low/med): LOW
Concentration units: ug/L
\/\/~~O<.-A
Spiked Sample Sam~le Result (SSR) C Resul (SR) C Added (SA) %R Q M
4:>.D. :>.< 2oi9.62 2000.0 95.2 -I> 512.56---30.00-u --500.0 ~02.5 -p-
2022.02---40.00-u 2000.0 101.1 -p-
2006.71---87.51-B --2000.0 -96.0 -p-
53.20---1.00-u --50.0 ~06.4 -p-
40.76---5.oo: u 50.0 81.5 -p-----~ 208.28 -10.00 u 200.0 Io4.I -p 490.89---20.00 -u 500.0 -98.2 -p-
254.29---14.30 -B 250.0 --96.0 -p-
4446.50---3474.01-1000.0 --97.2 -p-
492.84 -40.00-u --500.0 98.6 -p------~ 622.43 -!43. 43 -500.0 95.8 -p - ------~ 502.29 -20.00 u 500.0 100.5 -p ---- -~ 1920.32 -60.00 u 2000.0 96.0 -p
43.63 ---5.00-u --50.0 --87.3 -p-------NR: !988.55 -40.00 u 2000.0 99.4 -p
488.84--10.00 -u --500.0 --97.8 -p-
513.08--15.75-B 500.0 =99.5 -p---Nii: ------ -
FORM V (Part 2) -IN 3/90
U.S. EPA -CLP
6
DUPLICATES •
Lab Name: ITAS_KNOXVILLE, ____ _
Lab Code: ITSTU_ Case No.: 53103
Contract: NAT._STARC
SAS No.:
EPA SAMPLE NO.
NS-32D
SDG No.: NS-31
Matrix (soil/water): WATER
% Solids for Sample: _o.o
Level (low/med): _LOW_
% Solids for Duplicate: __ o.o
Concentration Units (ug/L or mg/kg dry weight): UG/L_
Control Vv'330'l-·D
Analyte Limit Sample (S) C Duplicate (D) C RPO Q M
-Aluminum Zo.!9.6.!00 '!b.l/. vol.lo 0.5 -tr Antim9ny= 30.0000 u 30.0000 u --p-
Arsenic 10.0 40.0000 u 40.0000 u -p-
Barium ----87.5100 B 86.6300 B 1.0 -p-
BeryllTiiiii 1. 0000 u 1. 0000 u --- -p-
Cadmium 5.0 5.0000 u 5.0000 u -p-
Calcium--51218.3400 50942.7900 0.5 -p-
Chromium_ 10.0 --10.0000 u --10.0000 u --- -p-
Cobalt ---20.0000 u 20.0000 u -p-
Copper--14.3000 B 13.6300 B 4.8 -p-
Iron --3474.0100 3463.4900 --0.3 - -p-
Lead 40.0000 u 40.0000 u --- -p-
Magnesium _5000.0_ 8975.4300 8905.1500 0.8 -p-
Manganese 143.4300 -143.1700 -=0.2 --p-
Mercury 0.2 0.2000 u 0.2000 u --CV Nickel --20.0000 u 20.0000 u -p PotassTiiiii 2380.9800 B 2309.7400 B 3.0 -p-
Selenium_ 60.0000 u 60.0000 u --- -p-
Silver 5.0000 u 5.0000 u -p-
Sodium--5000.0 8656.3700 8547.8900 1. 3 -p-
Thalliwn -10.0 -40.0000 u 40.0000 u ----p-
Vanadium= -10.0000 u 10.0000 u -p-
Zinc 15.7500 B 18.6500 B 16.9 -p-
Cyaniae_ - --Nil: ------
FORM VI -IN
3/90
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
U.S. EPA -CLP
6
DUPLICATES
EPA SAMPLE NO.
NS-32D Lab Name: ITAS_KNOXVILLE _____ _ Contract: NAT. STARC
SAS No.: I Lab Code: ITSTU
Matrix (soil/water):
I % Solids for Sample:
Case No.: 53103
WATER
_o.o
SDG No.: NS-31_
Level (low/med): LOW - -
% Solids for Duplicate: __ o.o
Concentration Units (ug/L or mg/kg dry weight): UG/L_
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Analyte
Aluminum
Antimony-
Arsenic -Barium -
BeryllTwii
Cadmium Calcium-
Chromium_
Cobalt
Copper ·
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
PotassTwii
Selenium_
Silver Sodium--
ThalliUJD
Vanadium:
Zinc
cyaniae_
Control
Limit sample (S) C
-
2.0000 u
-------
2.0000 u
----
4.0000 u
-
2.0000 u
----
FORM VI
vv3301--P
Duplicate (D) C
-
2.0000 u
-------
2.0000 u
----
4.0000 u
-
2.0000 u
----
-IN
RPD Q
--------------------------
M
Fm
NR
F
~
NR
NR
NR
NR
NR
NR
NR
F ~
NR
NR
NR
NR
F
N R
NR
F
N
N
~
R
R
3/90
U.S. EPA -CLP
3
BLANKS
Lab Name: ITAS_KNOXVILLE _____ _ contract: NAT._STARC
Lab Code: ITSTU_ Case No.: 53103 SAS No.:
Preparation Blank Matrix (soil/water): WATER
Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_
Initial
Calib. Continuing Calibration Blank Blank (ug/L) Analyte (ug/L) C 1 C 2 C 3 C
Aluminum 40.0 u 40.u u 4U. U_ u ___ 4U.U_ u Antimony---30.0-u --30.0-u --30.0-u 30.0 u Arsenic -==40.0-u --40.0-u --40.0-u --40.0-u Barium 2.0-u --2.0-u --2.0-u --2.0-u BeryllTiiiii 1.0-u 1.0-u 1.0-u 1.0= u Cadmium 5.0-u 5. o-u 5. o= u 5.0 u Calcium-30.0-u 30.0-u 30.0 u 30.0-u Chromium --10.0-u --10.0-u --10.0-u ==10.0-u Cobalt ---20.0-u --20.0-u --20.0 -u 20.0-u Copper= --10.0-u --10.0-u --10.0-u --10.0-u Iron --10.0-u --10.0-u --10.0-u --10.0-u Lead ==40.0-u --40.0-u --40.0-u --40.0-u Magnesium 30.0-u --30.0-u --30.0-u --30.0-u Manganese 2.0-u --2.0-u --2.0-u --2.0= u Mercury 0.2 -u 0.2-u 0.2-u 0.2 u Nickel -20.0-u 20.0-u 20.0-u 20.0-u PotassTiiiii ----r1roo.o-u ----r1roo.o-u ----r1roo.o-u ----r1roo.o-u Selenium 60.0-u -60.0-u -60.0 -u -60.0-u Silver ---5.0-u --5.0-u --5.0 -u 5.0-u Sodium--200.0-u 200.0-u 200.0 -u 200.0-u Thallium --40.0-u --40.0-u --40.0-u --40.0-u Vanadium= ==10.0-u --10.0-u --10.0-u --10.0-u Zinc 5.o-u --5.0-u --5.0= u --5.0= u Cyanide --

-

-
-

-

-

-
FORM III -IN
SDG No.: NS-31
Psw-C53i+ UAA
P&.l ·TI 4:l.l? I cf
PreJi>a-ration Blank C M
_40. 0uu u ~ --30.000 u p-
==40.000 u p-
2.000 u p-
1.200 B p-
5.000 u· p-
30.000 u p-
--10.000 u p-
--20.000 u p-
--10.000 u p-
==10.000 u p-
40.000 u p-
==30.000 u p-
2.000 u p-,-
0.200 u cV: 20.000 u p
----r1roo.ooo u p-
60.000 u p---5.000 u p-
200.000 u p---40.000 u p---10.000 u p---5.000 u p-
-N'.IC ---
3/90
I
I
I
I
I
I
I
I
I
I
I
I
I
u
I
I
I
I
I
I
I
U.S. EPA -CLP
3
BLANKS
I Lab Name: ITAS_KNOXVILLE _____ _ Contract: NAT. STARC
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Lab Code: ITSTU Case No.: 53103 SAS No.:
Preparation Blank Matrix (soil/water): WATER
Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_
Initial
Calib. continuing Calibration
Blank Blank (ug/L) Analyte (ug/L) C 1 C 2 C 3 C
Aluminum -Antimony----
Arsenic -2 . !l u 2 • !l u 2 • !l u 2. !l u Barium ----
Berylliwii ----
Cadmium ----
Calcium-----
Chromium_ ----
Cobalt ----
Copper------
Iron ----
Lead 2. !l u 2. !l u 2. !l u 2. !l u Magnesium ----
Manganese ----
Mercury ----
Nickel -----
Potassiuiii ----
Selenium_ 2. !l u 2. !l u 2.0 u 2.0 u Silver ----
Sodium------
Thalliuin 2.0 u 2.0 u 2 . !l u 2.0 u
Vanadium: ----
Zinc ----
cyaniae_ ------------
FORM III -IN
SDG No.: NS-31
pe,w · Tl42.l
PreJ?a-
ration
Blank C M
mr -NR-
2.!l!l!l u F N1< -NR--NR--NR--NR--NR--NR--NR= 2.!l!l!l u F
N1< -NR--NR--NR--NR-
2.000 u F
Nl:r -NR 2.000 u F -
Nl:r -NR--NR-----
3/90
--
~ INTERNATIONAL
TECHNOLOGY
CORPORA TJON
Project Nmne/No. 1N,,f:..,, .J ...Sf .. ,.~ h,,.,(,,1.8
Sample Team MP.rnbers 'D. fl,// oc,, I/
Profit Center No. 3 /Y 3? 7 'L
. •1 , , ProJect Manager f"l:/lr.!_ w, , ,,l. v·,,
Purchase Order No. 6 ,,.J / rf-
Required Report Date 11 / / 7 / q 2...
Sample t-1
Number
ANALYSIS REQUEST AND
CHAIN OF CUSTODY RECORD•
Samples Shi~ment Date 7 12/0· / 7 z_
Lab Destination R J::T<N -r,: J. J t ~ ... le
Lab Contact 9 /L:~ L~ ,-, , ...,
,.., . ft.-, ._j -f,..,,.,,-.J .~~. -,-.
Project Contact/Phone 12 (i,,,-) •9~ _,,_, /
f-t .{,. -•~I ~••j.1Yl<IJ
Carrier/Waybill No. 13 4G 07"1.:!fl ?'ly
ram
Reference Document No. 3 7 9 9 8 8
Page 1 of _2=_
B,11 to:5
Condition on 21 Disposal 22
Record No.
1 z.. .lfc...( '!' -N.s-32.. cf, .. ✓
c../,.,
--=-=--+------:-""'"""""'+-;-;'¥.-!-i:--;--t~r'i''1:Yr=.2..+-"-:k=L"----+-v_,,_--'a==-----+=--""""'""'ll"-~t"-r'"""~-------i~ /25:>,/
/ . 1',)c,-1 L-w_-1-,, I /.-f.r
Ut•·Y lJ., f; ' ~"GI~. I
c.../, <-y <,.J -+, / h0 .... I
c/c1•/ w~-fe, I /.f._,,
t:'1 • i I ,,f, , ,;-en~./
cJu-r i,J ,J,,,.. /zc,..J
cf,...,. /w~-k, I /. ft.,-
2. Relinquished by Date: 2. Received by Date: /,;, -/J'--? z "
15,gnRtl.Jf'f!/AffibRtion] Time: fSignalun'!/Af11!n1I.Nllll Time: 0 '1,:; s
3. Relinquished by Date: 3. Received by Date:
!SignRture/Aff,h1Jl.1!>!1] Time: fS.gnatlwP./f\lf,1,;it,on) Time:
Comments: 29
MCA .l/1<,191
iiiiil I!!!!! - - - - -- - - - - -
-------------------rn INTERNATIONAL
TECHNOLOGY
CORPORATION
Project Name N -•I. , ·" / ..5-/ .. • · 1•
Sample 1·1 Sample I~
Number Description/Tvn1t
/ .,., /.J!.-.J/ A cJr:.c-,f / W ~ -f, v
~-/.3 I Cl,"' I, J. f~.,,
,"'J...15, -/JI C(,.,,, I w-{c.v
V N~ -13 I <.J, .. / I (,.J . .--1, ,
\ -U, •v, /4.1,. fc .-/..J\. -/),>
r NS JJ 2-, c.1,,., I 1-v,-r.,,,
./ Al.<, -/32.. C/r,v I w .. +, ✓
,,, NJ. -}3J, cf,,,, /u./;
--N5-3 2-c..tc, -I w .. f~ -
/ vNS-3. l.. G/,. r /1./ ,, -fc Y-v J,.., I w .-1.,,, .,., N.S. -2, 2..
ANALYSIS REQUEST AND
CHAIN OF CUSTODY RECORD (cont.)*
Refm·ence Document No.'" 2 1 '1 '/ :i_J_
Page____Lof __2
Project No. L.{2,lrl, (, J' Samples Shipment Date f <-/I a/-, L
IM.Jl1■111
Date/Time 16 Container 1 ' 8■mple1R Pre-19 Requeeted Testing 20 Cond"rtion on 21 llitlpoul 22 :;;:
Collected T-Volume aervathm DNmram A .......... "' , Rocord No. i: tz/13/," l / :;l_}·.YJ• 1 I .::-=~I ::Z-c (!_
f'1 • -f../4 3"( DJ: ;i,'lp _,
/L; l L ,. .. t:r ;f.r,J(). /2·lt..,1 0
!Z(/1 I• L L-40., f 7~<-y m
;JC>... I t· ,I' 't f...1
n <-!~· -~ '-I a 4--~ n /7;:,,c, a, ; Hi 0
IZ.//8/qz_ / ~t'.:..4✓ -3 , . ':-1-' : !\I . 1;;: '{ I ,I,.,..,, -:r..c.. {3rJ 4-'. J . '., . /7 !3:-. ' ' ' .. .r • . ,3
12-1,~ l~L 1-/1,,.-/ .CZ. <
('1, 1~6. ..
U,'"J, I/.+. r
m
/ 7. >t:, /~IV(<), J '. ~ .. .,,
n/1,3/ql.. t-#CJ-..1 ~c,_/ 7c.<.. . ,!, .... ..
"JG'f-, .. 17; 4', cf•,~-.,,. /.t L/ } ·.;; ... ·. ~ .
I~/ 18/~ L I (.,1/:..,..._--.r
!3,-.Jl4-/7; vr-G....-,~._,,.-lf l.f._,. 7L<,. ..; I ' .. 11..(,~/~z_ -/1.~-v
IIA✓
::Zee
/YI, l-6 0
/7 ,..,,, <-!: ; [ '--£.I ;.J(]' ~
12./fd/•1-/'... I /, fy ' ~ 7, '-('1, J~ 10 ffi
/8 :u, ~1t" 1, / /,./, ✓ 1.-J,-x,. ii
n IL/18/qL d-..J:;:J Ii<>,/
:Tee.. \J O i+-"1..s /,.,_,r 2 /',I','> "✓ /,/ '-I . .,-... .
t'L(t8l'1L 1--/1,-<t:,....-~.c.
f,J A.I i'/--"1/.sl,,,.,,r ....._ .... j-✓ I J . .f,, /., ' \''l , / <,,J -\ ., '. IL/f8f7L /'--[:';' /:::OJ. I -;,-.~ (", . ,j,j_., -r:i11~ I
/s-:r> ~(:,// /-/ ,JQ,. .
Al5o ~·cl .
(J) .. ..
+;,I. \.,~k CT m n ~
~ ,!.
".t:/2.. 0 .. ,
I 3 ... i I It Q -~ .. n
~ 'l!.
3 .. q
C g
0 0 ..
I
I
I
I
I
@ INTERNATIONAL
TECHNOLOGY
CORPORATION
IT Corporation
312 Directors Drive
Knoxville, TN 37923
Attn: Mike Sturdevant
Job Number: ITEK 53438
ANALYTICAL
SERVICES
CERTIF1CATE OF ANALYSIS
March 11, 1993
P.O. Number: 408668.19.10
I This is the Certificate of Analysis for the following samples:
I
I
I
I
I
I
I
I
I
I
I
I
I
Client Project ID:
Date Received by Lab:
Number of Samples:
Sample Type:
I. Introduction
National Starch
02/18/93
Four (4)
Water
On 02/18/93, four (4) water samples arrived at the ITAS-Knoxville, Tennessee, laboratory from IT
Corporation, Knoxville, Tennessee in support of the National Starch project. The list of analytical tests
performed, as well as date of receipt and analysis, can be found in the attached report.
II. Analytical Results/Methodology
The analytical results for this report are presented by analytical test. Each set of data will include sample
identification information and the analytical results. Please note that the data are not blank corrected.
The samples were analyzed for Target Compound List (TCL) volatiles and semivolatiles by gas
chromatography/mass spectroscopy (GC/MS) in accordance with the EPA CLP 2/88 Statement of Work.
Reviewed and Approved:
Al;, Moore
Laboratory Manager
Amencan Council ot Independent Laboratones
!ntemat1onal A.ssoc1at1on o! Environmental Testing Lcborato11es
A.rnencan A.ssoc1ation !or Laboratory Accred1tat1on
IT Analytical Services. 5815 Middlebrook Pike, Knoxville, TN 37921 681,1-89
IT Corporation
March 11, 1993
Client Project ID: National Starch
II. Analytical Results/Methodology (continued)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVIUE, TN
Job Number: ITEK 53438
The samples were analyzed for Target Analyte List (T AL) metals by cold vapor atomic absorption
spectroscopy (CV AA), graphite furnace atomic absorption spectroscopy (GFAA), and inductively coupled
plasma spectroscopy (ICP) in accordance with the EPA CLP IIM0l Statement of Work.
The samples were analyzed for chloride based on EPA method 325.3.
The total dissolved solids (IDS) content of the samples was determined using EPA method 160.1.
m. Quality Control
The volatiles analyses were performed by purge and trap with a J&W DB-624 megabore column on a
Finnigan OWA GC/MS/DS. The sample analyses went well. Dilutions were necessary for samples NS29-
2/93 and NS31-2/93 for acetone. 1,2-Dichloropropane was higher than the method linear limit in NS29-
2/93 and below the linear limit in NS29-2/93 DL, but there was good agreement between the two results
indicating good analytical integrity for the results obtained. There were no problems seen in final data
review.
The semivolatiles analyses were performed by direct injection of sample extract on a Restek XTI-5
capillary column on a Finnigan 4500 GC/MS/DS. The most commonly seen target analyte was bis(2-
chloroethyl)ether. The sample analyses went well. There were no problems seen in final data review.
The samples were digested on 02/22/93 for ICP and 02/22/93 for GFAA. The samples for mercury
analysis were prepared just prior to analysis. The CV AA analysis for mercury was performed on
02/23/93; the GFAA analyses for arsenic, lead, selenium, and thallium were performed on 02/23-24/93;
the remaining metals were analyzed by ICP on 02/25/93. All run QC was acceptable. No problems were
encountered.
The samples were analyzed for chloride using the mercuric nitrate titrimetric procedure with HACH
reagents. No problems were encountered.
The TDS content of the samples was determined gravimetrically by filtration and evaporation of the filtrate
to a constant weight at 180°C. No problems were encountered.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS29-2/93
I.ab Sample ID: VV623S
Comoound
chloromethane
bro mo methane
vinyl chloride
chlorocthane
methylene chloride
acetone
carbon disulfide
l , 1-dichloroethene
l , 1-dichloroethane
1,2-dichloroethene (total)
chloroform
1,2-dichloroethane
2-butanone
1, 1, I -trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
ConcentratiQD Compound
10 u 1,2-dicbloropropane
10 u cis-1,3-dichlu1opropend
10 u tricbloroetbme
10 u dibromocbloromethane
3 BJ 1,1,2-trichloroethane
12,000 D bemene
8 ' trans-1,3-dichloropropene
s u bromoform
s u 4-methyl-2-pentanone
5 u 2-hexanone
s u tetrachloroetheoe
llO l, 1,2,2-tetnchloroethane
48 toluene
s u chlorobemene
5 u ethylbemene
10 u styrene
5 u xylenea (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
Concentration
350 D
s u
s u
s u
s u
s u
s u
s u
10 u
10 u
5 u
s u
60
5 u
s u
5 u
12
u
J
B
D
Compound was analy,:od for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Analyte was found in the blank as well as the sample.
Compound analy,:od at a secondary dilution factor.
Date of Analysis: 02/24/93
Dilution Factor: 1.0
3 \YOI.ATU.E\TCL.FIM 4/IWl
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS30-2/93
Lab Sample ID: VV6236
CoD1DOund
chloromethane
bromomethanc
vinyl chloride
chloroethane
methylene chloride
acetone
carbon disulfide
l, 1-dichloroethene
1, 1-dichloroethane
1,2-dichloroethene (total)
chlon:,form
1,2-dichloroethane
2-butanonc
l, 1, 1-trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
250 u 1,2-dichloropropane
250 u cis-1,3-dichl01op1ope...
250 u trichloroethme
250 u dibromochloromethane
48 BJ 1, 1 ,2-trichloroethane
2,900 benzene
120 u trans-1,3-dichloropropene
120 u bromoform
120 u 4-methyl-2-pentanone
120 u 2-hexanone
120 u tetrachloroetheoe
79 1 1,1,2,2-tetrachloroethanc
250 u toluene
120 u chlombenzene
120 u ethyl benzene
250 u styrene
120 u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
ConcentratiQD
190
120 u
120 u
120 u
120 u
120 u
120 u
120 u
250 u
250 u
120 u
120 u
34 1
120 u
120 u
120 u
120 u
u
J
B
Compound was analyzed for but not detected. The number is the detection limit for the sample.
lndicales an estimated value leas than the detection limit.
Analyte was found in the blank u well as the sample.
Date of Analysis: 02/24/93
Dilution Factor: 25
4 \VOIATD.B\TCL.nll 4'Jl/9'J
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, I 993
Client Project ID: National Starch
Client Sample ID: NS31-2/93
Lab Sample ID: VV6237
Compound
chloromethane
bromomethane
vinyl chloride
chloroelhane
methylene chloride
acetone
carbon disulfide
I , 1-<lichloroethene
I, 1-dichloroethane
1,2-dichloroethene (total)
chloroform.
1,2-dichloroelhane
2-butanone
I , 1, I -trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in 11g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-dichloropropane
10 u cis-1,3-dichloropropene
10 u trichloroelbme
3 J dibromochloromethane
3 BJ I, 1,2-trichloroethane
4,700 D benzene
s u trans-1,3-dichloropropene
s u bromoform
s u 4-methyl-2-pentanone
s u 2-hexanone
2 J tetrachlorocthcnc
100 1, 1,2,2-tetnchloroelhane
18 toluene
s u chloroben=e
s u ethylben=e
10 u styrene
s u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
170
s u
s u
s u
s u
s u
s u
s u
10 u
10 u
s u
s u
34
s u
2 J
s u
6
u
J
B
D
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Analyte was found in the blank as well as the aample.
Compound analyzed at a secondary dilution factor.
Date of Analysis: 02/24/93
Dilution Factor: 1.0
s \VOU111Jro'CLFIM 4'13.9J
IT Cmporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS32-2/93
Lab Sample ID: VV6238
Com(!Qund
chloromethane
bromomethane
vinyl chloride
chloroethane
methylene chloride
acelone
carbon disulfide
l, 1-<lichloroethene
l, 1-<lichloroethane
1,2-<lichloroethene (total)
chloroform
1,2-<lichloroethane
2-butanone
I, I, I -trichloroethane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND usr
Results in l'g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-<lichloropropane
10 u cis-1,3-<lichloropropene
10 u trichloroethene
10 u dibromochloromethane
2 BJ 1,1,2-trichloroethane
10 u benzme
s u trans-1,3-<lichloropropene
s u bromoform
s u 4-methyl-2-pentanone
s u 2-hexanone
s u tetracltloroethene
s u 1, 1,2,2-tetrachloroethane
7 J toluene
s u chlorobcmene
s u ethylbenzme
10 u styrene
s u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
s u
s u
s u
s u
s u
s u
s u
s u
10 u
10 u
s u
s u
s u
s u
s u
s u
s u
U Compound was analyzed for but not detectt>d. The number is the delection limit for the aample.
J Indicate& an estimated value less than the detection limit.
B Analyte was found in the blank as well aa the aample.
Date of Analysis: 02/24/93
Dilution Factor: 1.0
6 \VOU.11Lml'a...FIII 4/ll/91
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, I 993
Client Project ID: National Starch
Client Sample ID: Method Blank
Lab Sample ID: VB0224
ComRQund
chloromcthanc
bromomethaoe
vinyl chloride
chloroethane
methylene chloride
acetone
carbon disulfide
l , 1-<lichloroethene
l, 1-<lichloroethane
1,2-<lichloroethene (total)
chloroform.
1,2-<lichloroethane
2-butanonc
l, l, 1-trichlorocthane
carbon tetrachloride
vinyl acetate
bromodichloromethane
VOLATILE ORGANIC TARGET COMPOUND UST
Results in 14g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u 1,2-<lichloropropane
10 u cis-1,3-<lichloropropene
10 u trichloroelh<:ne
10 u dibromochloromethane
2 J 1, 1,2-trichloroethane
10 u benzene
s u trsns-1,3-<lichloropropene
s u bromoform
s u 4-methyl-2-pentanone
s u 2-hexanone
s u telnlchloroetbene
s u l, 1,2,2-tetrachloroethane
10 u toluene
s u chlorobcnzene
s u ethylbenzene
10 u styrene
s u xylenes (total)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
s u
s u
s u
s u
s u
s u
s u
s u
10 u
10 u
s u
s u
s u
s u
s u
s u
s u
u
J
B
Compound waa analyzed for but not delected. The number is the delection limit for the aample.
Indicates an estimated value less than the delection limit.
Analyte waa found in the blank aa well as the aample.
Date of Analysis: 02/24/'n
7 \VOL\T1LE\1'CL.FDC 4113.92
IT Corporation
March 11, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
WATER SURROGATE PERCENT RECOVERY SUMMARY
•
DL
Tolucne-D8
Client Sampl~ ID (88-110%)•
NS29-2/93 103
NS29-2/93 DL 104
NS30-2/93 IOI
NS31-2/93 105
NS31-2/93 DL 99
NS32-2/93 102
Method Blank 104
Valueo in parenU-. 1ep1eawt ,equind QC limilB .
Dilution
VOLATILE
Bromofluorobenzme 1,2 Dichloroethane-D4
(86-115%)• (76-114%)•
103 100
108 83
103 81
108 96
100 84
106 89
107 90
8 \VOI.A'l'1Um'a-PIM 411Wl
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, I 993
Client Project ID: National Starch
Client Sample ID: NS29-2/93
Lab Sample ID: VV6247
Compound
phenol
bis(2-chloroethyl)ether
2-chlorophenol
1,3-<lichlorobenzene
1,4-dichlorobenz.enc
benzyl alcohol
1,2-<lichlorobenzene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-<li-n-propylamine
hexachloroethano
nitrobcnzcne
isopborone
2-nitrophenol
2,4-<limethylphenol
bcnzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in l'g/liter (ppb)
Sample Matrix: Water
Concentration Compound
to u bis(2-chloroethoxy)methane
190 2,4-<lichlorophenol
10 u 1,2,4-trichlorobenzene
to u naphthalene
10 u 4-chloroaniline
10 u hexachlorobutadiene
to u 4-chloro-3-methylphenol
10 u 2-methylnaphtbaleoe
10 u hexachlorocyclopentadiene
5 1 2,4,6-trichloropheool
10 u 2,4,5-trichlorophenol
10 u 2-chloroaaphtbalene
10 u 2-ni troaniline
to u dimethyl phtbalate
to u acenaphthylene
10 u 2,6-<linitrotoluene
52 u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentrati29
10 u
10 u
10 u
to u
10 u
to u
10 u
10 u
10 u
10 u
52 u
10 u
52 u
to u
10 u
10 u
U Compound was analy""1 for but not detected. The number is the detection limit for the aample.
J Indicates an estimated value less than the detection limit.
Extraction Date:
Analysis Date:
Dilution Factor:
02/22/93
03/02/93
1.00
9 \BUYOA.ffCLnM 4113192
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS29-2/93
Lab Sample ID: VV6247
Compound
3-nitroaniline
acenaphthene
2,4-<linitrophenol
4-nitrophenol
dibenz.ofuran
2,4-<linitrotoluene
diethylphthalate
4-<:hlorophenyl-phenylether
fluorcne
4-nitroaniline
4,6-<linitro-2-methylphenol
n-nitrooodiphenylamine1
4-bromophenyl-phenylether
hexachlorobenzene
pentachlorophenol
phenanthrene
SEMIVOLATILE TARGET COMPOUND UST (continued)
Results in l'g/liter (ppb)
Sample Matrix: Water
Copcentratiog Compound
52 u anthracene
10 u di-n-butylphthalate
52 u fluoranthme
52 u pyrme
10 u butylbenzylphthalate
10 u 3,3'-<lichlorobmzidine
10 u benzo(a)anthracene
10 u chryaene
10 u bis(2~thylhexyl)phthalate
52 u di-n-<>etylphthalate
52 u benm(b )fluoranthene
10 u benm(lc)fluonntbme
10 u benzo(a)pyrene
10 u indeno( 1,2,3-<:d)pyrene
52 u dibenzo(a,h)anthracene
10 u benzo(g,h,i)pe,ylene
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
10 u
10 u
21 u
10 u
10 u
2 1
10 u
10 u
10 u
10 u
10 u
10 u
10 u
u
J
I
Compound was analyzed for but not detected. The number is the detection limit for the aample.
Indicates an estimated value leas than the detection limit.
Detected as diphenylamine.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
Dilution Factor: LOO
10 \SIMIVOAvra..PDI 4'11.92
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS30-2/93
lAb Sample ID: VV6248
Compound
phenol
bis(2-<:hloroethyl)ether
2-<:hlorophenol
1,3-<lichlorobenzene
1,4-<lichlorobenz.ene
benzyl alcohol
1,2-<lichlorobenz.ene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hexachloroelhane
nitrobenz.ene
isophorone
2-nitrophenol
2,4-<limethy!pheno!
bcnzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in 14g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-<:hloroethoxy)methane
44 2,~ichlorophenol
10 u 1,2,4-trichlorobenzme
10 u naphthalene
10 u 4-<:hloroaniline
10 u hexachlorobutadiene
10 u 4-<:hloro-3-methylphenol
10 u 2-methylnaphthalene
10 u hexachlorocyclopentadiene
10 u 2,4,6-trichlorophenol
10 u 2,4,5-trichlorophenol
10 u 2-<:hlomruqib!haJ..,.,
10 u 2-nitroaniline
10 u dimethyl phthalate
10 u acenaphthy!ene
10 u 2,6-<linitrotoluene
50 u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
50 u
10 u
50 u
10 u
JO u
10 u
U Compound was analyzed for but not detected, The number is the delection limit for the sample.
J Indicates an estimated value leas than the detection limit.
Extraction Dare: 02/22/93
Analysis Date: 03/02/93
Dilution Factor: 1.0
II ISDOYOAffQ..nM 4()3192
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS30-2/93
Lab Sample ID: YV6248
ComI!Qund
3-nitroaniline
acenaphthene
2,4-dinitrophenol
4-nitrophenol
dibenz.ofuran
2,4-dinitrotoluene
diethylphthalate
4-chlorophenyl-phenylether
fluorene
4-nitroaniline
4,6-<linitro-2-methylphenol
n-nitrooodipbeoylamine1
4-bromophenyl-phenylether
hexachlorobenz.ene
pentach!orophenol
phenanthrene
SEMIVOLATILE TARGET COMPOUND UST (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
50 u anthracene
10 u di-n-butylphthalate
50 u fluonntbm<,
50 u ~
10 u butylbenzylphthalate
10 u 3 ,3' -<iichlorobenzidine
10 u benzo(a)anthracene
10 u chrysene
10 u bis(2-dhylhexyl)phthalate
so u di-n-octylphthalale
50 u benzo(b)fluoranthene
10 u btm.o(k)fluonnlheoe
10 u benzo(a)pyrme
10 u indeno(l,2,3-<:d)pyrene
50 u dibenzo(a,h)anthracene
10 u benzo(g,h,i)perylene
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
ConcentratiQD
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
2 1
10 u
10 u
10 u
10 u
10 u
10 u
10 u
u
J
I
Compound was analyzed for but not detected. The number is the detection limit for the sample,
Indicates an estimated value leas than the detection limit.
Detected as diphenylamine.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
Dilution Factor: 1.0
12 \EOYOAffCLFDI 4nWl
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, I 993
Client Project ID: National Starch
Client Sample ID: NS31-2/93
lab Sample ID: VV6249
Com~und
phenol
bis(2-<:hloroethyl)elher
2-<:hlorophonol
1,3-dichlorobonzene
1,4-dichlorobonzene
benzyl alcohol
1,2-dichlorobonzene
2-methylphenol
bis(2-<:hloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hexachloroethane
nitrobcnzcne
isophorone
2-nitrophenol
2,4-dimethylphenol
henwic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-ehloroethoxy)methane
71 2,4-dichlorophenol
10 u 1,2,4-trichlorobonzone
10 u naphthalene
10 u 4-<:hloroaniline
10 u hexachlorobutadione
10 u 4-<:hloro-3-methylphonol
10 u 2-methylnaphthalone
10 u hexachlorocyclopentadiene
10 u 2,4,6-trichlorophenol
10 u 2,4,S-trichlorophonol
10 u 2-<:hloronaphthalone
10 u 2-nitroaniline
10 u dimethyl phthalate
10 u aconaphthylone
10 u 2,6-dinitrotoluene
4 J
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
so u
10 u
so u
10 u
10 u
10 u
U Compound was analyzed for but not detected. The number is the detection limit for the aample.
J Indicate& an estimated value less than the detection limit.
Extraction Date:
Analysis Date:
Dilution Factor:
02/22/93
03/02/93
1.0
13 \SEMIY'OA'\1'CL.FIM 411:Jm
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS31-2/93
Lab Sample ID: VV6249
Compound
3-nitroaniline
acenaphthene
2,4-<linitrophenol
4-nitrophenol
dibenrofuran
2,4-<linitrotoluene
diethylphthalate
4-chlorophenyl-phenylether
fluorene
4-nitroaniline
4,6-<linitro-2-methylphenol
n-nitrosodiphenylamine1
4-bromophenyl-phenylether
hexachlorobenzene
pentachlorophenol
phenanthrene
SEMIVOLATILE TARGET COMPOUND UST (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
so u anthracene
10 u di-n-butylphthalate
so u fluorantheue
so u pymie
10 u butylbenzylphthalate
10 u 3 ,3 '-dichlorobenzidine
10 u benm(a)anthracene
10 u chrysene
10 u bis(2~thylhexyl)phthalate
so u di-n-octylphthalate
so u benm(b )fluoranthene
10 u benzo(k:)fluorantbem,
10 u benm(a)pyrene
10 u indeno( 1,2,3-cd)pyrene
so u dibenm(a,h)anthracene
10 u benzo(g,h,i)perylene
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
3 J
10 u
10 u
10 u
10 u
10 u
10 u
10 u
u
J
Compound was analy,:ed for but not detected. The number is the .detection limit for the 9111J1ple.
Indicates an estimated value lesa than the detection limit.
Detected as diphenylamine.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
Dilution Factor: 1.0
14 ISEMIVOATI'CLf'IM 411ll92
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT CoipOration
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS32·2/93
Lab Sample ID: VV6250
Compound
phenol
bis(2-cbloroethyl)ether
2-cblorophenol
1,3-<licblorobenune
1,4--dichlorobenz.ene
benzyl alcohol
1,2-<licblorobenu:ne
2-methylphenol
bis(2-cbloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylaminc
beucbloroethane
nitrobcnz.ene
isopboronc
2-nitrophenol
2.~imethylphenol
benzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in 14g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-cbloroetboxy)metbane
10 u 2,~icblorophenol
10 u 1,2,4-tricblorobmz.eno
10 u naphthalene
10 u 4-chloroaniline
10 u heucblorobutadiene
10 u 4-cbloro--3•methylphenol
10 u 2-methylnaphthalene
10 u heucblorocyclopentadiene
10 u 2,4,6-tricblorophenol
10 u 2,4,S-trichloropbenol
10 u 2-cblc,,nnapb!bal-
10 u 2-nitroaniline
10 u dimethyl phthalate
10 u acenaphthylene
10 u 2,6-<linitrotoluene
50 u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
so u
10 u
so u
10 u
10 u
10 u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
J Indicates an estimated value less than the detection limit.
Extraction Date:
Analysis Date:
Dilution Factor:
02/22/93
03/02/93
1.0
IS \SEMIVOA\TCI...PDI 4flll9'2
IT Cmporation
March 11, I 993
Client Project ID: National Starch
Client Sample ID: NS32-2/93
Lab Sample ID: VV6250
ComQQund
3-nitroaniline
acenaphthene
2,4-dinitrophenol
4-nitrophenol
dibenzofuran
2,4-<linitrotoluene
diethylphthalate
4-chloropheoyl-phenylether
fluorenc
4•nitroaniline
4,6-<linitro-2-methylphcnol
n-nilroflod.ipbenylamine1
4-bromophenyl-pheoylether
bexachlorobenzene
pentachloropheool
pheoanthrene
SEMIVOLATILE TARGET COMPOUND UST (continued)
Result, in 1<g/liter (ppb)
Sample Matrix: Water
Con~tration Compound
so u anthracene
10 u di-n-butylphthalate
so u tluoranthmo,
so u pyrene
10 u butylbenzylphthalate
10 u 3,3' -<lichlorobenzidine
10 u benm(a)anthracene
10 u chrysene
10 u bis(2~ylhexyl)phthalate
so u di-n-octylphthalate
so u benzo(b)fluoranthene
10 u bmm(k)ftuoranlbme
10 u benm(a)pyrene
10 u indeno( l ,2,3~)pyrene
so u dibenm(a,h)anthracene
10 u benzo(g,h,i)perylene
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
3 J
10 u
10 u
10 u
10 u
10 u
10 u
10 u
u
J
Compound was analy:r.ed for but not detected. The number is the detection limit for the sample,
Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Extraction Date:
Analysis Date:
Dilution Factor:
02/22/93
03/02/93
1.0
16 \.1BOVOA\TtLJIIM 4'1:w2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: Method Blank
Lab Sample ID: Bl3J95
ComR,gund
phenol
bis(2-,,hloroethyl)ether
2-,,hlorophenol
J ,3-dichlorobem.cne
1,4-dichlorobcnzcnc
benzyl alcohol
J, 2-dichlorobenzene
2-methylphenol
bis(2-,,hloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hexachloroethane
nitrobem.ene
isophoronc
2-nitrophenol
2,4-dimethylphenol
benzoic acid
SEMIVOLATILE TARGET COMPOUND UST
Results in J'g/liter (ppb)
Sample Matrix: Water
Concentration Compound
10 u bis(2-,,hloroethoxy)methane
JO u 2,4-dichlorophenol
JO u 1,2,4-trichlorobenzme
10 u naphthalene
JO u 4-chloroaniline
10 u bexachlorobu!Jldiene
10 u 4-chloro-3-methylphenol
10 u 2-methylnaphthalene
10 u hexachlorocyclopentadiene
10 u 2,4,6-trichlorophenol
10 u 2,4,5-trichlorophenol
10 u 2-,,hloronaphlhalme
JO u 2-nitroaniline
10 u dimethyl phthalate
10 u acenaphthylene
10 u 2,6-dinitrotoluene
so u
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
JO u
JO u
10 u
10 u
10 u
10 u
10 u
so u
10 u
so u
10 u
10 u
10 u
u
]
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Extraction Date:
Analysis Date:
02/22/93
03/02/93
17 \BOYOA\Ta..PRM 411,..,,
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: Method Blank
Lab Sample ID: Bl3195
Compound
3-nitroaniline
acenaphthene
2,~initrophenol
4-nitrophenol
dibenzofuran
2,~initrotoluene
diethylphthalate
4-<:hlorophenyl-phenylether
fluorcne
4-nitroaniline
4,6-<linitro-2-methylphenol
n-nilrolodiphenylamine1
4-bromophenyl-phenylether
hexachlorobenzene
pentachlorophenol
pbenanthrene
SEMIVOLATILE TARGET COMPOUND UST (continued)
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
50 u anthracene
10 u di-n-butylphthalate
50 u fluoranthene
50 u pyrene
10 u butylbenzylphthalate
10 u 3 ,3 '-<lichlorobenzidine
10 u benzo(a)anthracene
10 u chlyaene
10 u bis(2~ylhexyl)phthalate
50 u di-n-<>etylphthalate
50 u benm(b)fluoranthene
10 u benm(k)ftuoranlbme
10 u benzo(a)pyrene
10 u indeno( 1,2,3-<:d)pyrene
50 u dibenzo(a,h)anthracene
10 u benzo(g,h,i)perylene
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
10 u
10 u
10 u
10 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
u
J
Compound was analyzed for but not detected. The number is the detection limit for the sample.
Indicates an estimated value less than the detection limit.
Detected as diphenylamine.
Extraction Date: 02/22/93
Analysis Date: 03/02/93
18 ISDIIYOAffa-l'DI 411"'2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Cotp0ration
March II, 1993
Client Project ID: National Starch
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
I
I
I
I
I
I
WATER SURROGATE PERCENT RECOVERY SUMMARY
I
I
I
I
Client Sample ID
NS29-2/93
NS30-2/93
NS31-2/93
NS32-2/93
Method Blank
Nitro-
Benzene-D5
/35-114%)•
76
64
68
71
73
2-Auoro-
Biphenyl
/43-116%)•
73
66
68
74
73
I •Values in parentheaea 1Cpn.a:nt ,~uired QC limits.
I
I
I
I
I
I
I
I
SEMI-VOLATILE
2,4,6-
Terphenyl-2-Fluoro-Tribromo-
D14 Pbenol-D5 Phenol Phenol
/33-141%)• /10-94%)• 121-100%)• 110-123%)•
76 36 62 107
73 34 58 81
76 36 61 117
84 28 48 97
71 26 40 76
19 131:M1VOAff'a...FIM 4/IWl
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS29-2/93
Lab Sample ID: YV6243
Co!!!eQund
aluminum
antimony
arsenic
barium
beryllium
cadmium
METALS TARGET ANALYTE UST
Results in µg/liter (ppb)
Sample Matrix: Water
Concentration Compound
258 magnesium
30.0 u rnanpoeee
2.0 u mercury
182 B nickel
1.0 u potassium
s.o u aelenium.
calcium 197,000 silver
chromium 11.1 sodium
cobalt 20.0 u thallium
copper 10.0 u vanadium
iron 448 zinc
lead 2.0 u
Date of Digeation: 02/22/93
Date of Analysis: 02/25/93 (ICP), 02/23, 02/24/93 (GFAA), 02/23/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
ConcentratiQD
15,100
475
0.20 u
20.0 u
1,380 B
2.0 u
s.o u
16,000
2.0 u
10.0 u
10.3 B
U Compound waa analyzed for but not detected. The numbe, ia the detection limit for the aample.
B -Value greater than instrument detection limit, but leaa than conlnlct required quantitation limit.
20 \IDOYOA.fl'Q.JIDI 411:Mt'l
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, I 993
Client Project ID: National Starch
Client Sample ID: NS30-2/93
Lab Sample ID: VV6244
Compound
aluminum
antimony
anenic
barium
beryllium
cadmium
METALS TARGET ANALYI'E UST
Results in ,.gJliter (ppb)
Sample Matrix: Water
Concentration Compound
40.0 u magnesium
30.0 u manganese
2.0 u meroury
23.4 B nickel
1.0 u potaasium
5.0 u aelenium
calcium 151,000 silver
chromium 10.0 u sodium
cobalt 20.0 u tballium
copper 10.0 u vanadium
iron 93.S B zinc
lead 2.0 u
Date of Digestion: 02/22/93
Date of Analysis: 02/25/93 (ICP), 02/23, 02/24/93 (GFAA), 02/23/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
15,900
839
0.20 u
20.0 u
1,350 B
2.0 u
5.0 u
13,900
2.0 u
10.0 u
8.2 B
u
B
Compound wu analyzed for but not detected. 1be number i• the detection limit for the sample.
Value greater than instrument detection limit, but less than contract required quantitation limit.
21 \S&OYOA\TCLPDI 4/'IS/92
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS31-2/93
Lab Sample ID: VV6245
Compound
aluminum
antimony
arsenic
barium
beryllium
cadmium
METALS TARGET ANALYTE UST
Results in ,.glliter (ppb)
Sample Matrix: Water
Concentration Compound
172 B magnesium
30.0 u manganoae
2.0 u mercwy
193 B nickel
1.0 u potasaium
5.0 u aelenium
calcium 242,000 silver
chromium 11.5 sodium
cobalt 20.0 u thallium
copper 10.0 u vanadium
iron 1,380 zinc
lead 2.0 u
Date of Digestion: 02/22/93
Date of Analysis: 02/25/93 (ICP), 02/23, 02/24/93 (GFAA), 02/23/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
223 B
11.9
0.20 u
39.3 B
10,000
2.0 u
5.0 u
19,900
2.0 u
10.0 u
27.9
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
B -Value greater than instrument detection limit, but less than contract required quantitation limit.
22 \IIMIVOAffl1.JID( "'l:l,91
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: NS32-2193
Lab Sample ID: VV6246
Compound
aluminum
antimony
arsenic
barium
beryllium
cadmium
calcium
chromium
cobalt
copper
iron
lead
Date of Digestion: 02122193
METALS TARGET ANALYI'E UST
Results in l'g/liter (ppb)
Sample Matrix: Water
Concentration Compound
61.1 B magnesium
30.0 u rnanpaee
2.0 u morcmy
65.8 B nickel
1.0 u potassium
5.0 u selenium
38,500 silver
10.0 u sodium
20.0 u thallium
10.0 u vanadium
165 :rill<:
2.0 u
Date of Analysis: 02/25/93 (ICP), 02/23, 02/24/93 (GFAA), 02/23/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVIIJ.E, TN
Job Number: ITEK 53438
Concentration
6,360
80.6
0.20 u
20.0 u
1,980 B
2.0 u
5.0 u
6,300
2.0 u
10.0 u
6.4 B
u
B
Compound was analyu,d for but not detected. The number is the detection limit for the aample.
Value greater than instrument detection limit, but less than contract ffijuired quantitation limit.
23 \BGYOA.ff'CLPIM 41'1WJ
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID: Method Blank
METALS TARGET ANALYTE UST
Results in µg/liter (ppb)
Sample Matrix: Water
Lab Sample ID: PBWC5464/PBWI1716
Compound Concentration Compound
aluminum 40.000 u magnesium
antimony 30.000 u man-
anenic 40.000 u mercury
barium 2.000 u nickel
beryllium 1.000 u potassium
cadmium 5.000 u selenium
calcium 778.380 B silver
chromium 10.000 u sodium
cobalt 20.000 u thallium
copper 10.000 u vanadium
iron 10.000 u zinc
lead 40.000 u
Date of Digestion: 02/22/93
Date of Analysis: 02/25/93 (ICP), 02/23, 02/24/93 (GFAA), 02/23/93 (CV AA)
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Concentration
194.800 B
2.000 u
0.200 u
20.000 u
1,000.000 u
60.000 u
5.000 u
495.130 B
40.000 u
10.000 u
5.000 u
U Compound was analyzed for but not detected. The number is the detection limit for the sample.
B • Value greater than instrument detection limit, but less than contract requmd quantitation limit.
24 \E,(IV()A,\TCLFU,( "1l.92
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Corporation
Man:h 11, 1993
Client Project ID: National Starch
Client Project ID: Method Blank
Lab Sample ID: PBWil718
Compound
arsenic
lead
selenium
thallium
Date of Digestion: 02/22/'TJ
Date of Analysis: 02/23, 02/24/'TJ
METALS ANALYSIS
Results in 11g/litcr (ppb)
Sample Matrix: Water
Result
2.000 U
2.000 U
2.000 U
2.000 U
IT ANALYTICAL SERVICES
58 l 5 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
U -Compound waa analyzed for but not detected. The number is the detection limit for the aample.
25 ISIMIYOAlTCL.FIM Cfl:W.Z
IT Corporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID
Method Blank
NS29-2/93
NS30-2/93
NS31-2/93
NS32-2/93
Analyoia Dale: 02/19/93
CHLORIDE ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Lab Sample ID
P47S9
YV6239
VV6240
YV6241
VV6242
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE, TN
Job Number: ITEK 53438
Result
0.5 u
84
22
IS
2.0
U • Compound was analyzed for but not detected. The number is the detection limit for the sample.
26 \SEIIIVOAff'a-PQf 4'1:W.Z
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
IT Cmporation
March 11, 1993
Client Project ID: National Starch
Client Sample ID
Method Blank
NS29-2/93
NS30-2/93
NS31-2/93
NS32-2/93
AnaJym Date: 02/19/93
TOTAL DISSOLVED SOLIDS ANALYSIS
Results in mg/liter (ppm)
Sample Matrix: Water
Lab Sampl~ ID
P476S
VV6239
VV6240
VV6241
VV6242
IT ANALYTICAL SERVICES
5815 MIDDLEBROOK PIKE
KNOXVILLE. TN
Job Number: ITEK 53438
Result
22
1,020
634
706
207
U · Compound was analyzed for but not detected. The nwnbc, is the detection limit for the sample.
27 \SIIMIYOAtra..nM: 411:wl
I
I
c-r:;-;:i INTERNATIONAL ANALYSIS REQUEST AND fJ..J ~o~~~~~ 1-· I I, CHAIN OF CUSTODY RECORD* ;V-1 10"-'/l s;. 4~( ti c-, Proj,Act Name/No. 1 <,/Og c-6 fl b./c'.samples Shipment Date 7 2 -f 7 -/ 3
Sample Team Members 2 / // FtVd / 6)" Lab Destination 8 / T /J-_s r?'} f' L
Reference Document No. 3 2 2 8 I I
Page 1 of __
Bill to 5 11/,11-:c,,,,.q/ sJ-1-<< h
::x, &-#' /./<'.JS C: c. Y. I 1/'. /cJ
Profit Center No. 3 Lab Contact 9
Project Manager4 ()1./<t: 5fvr.devih-r Project Contact/Phone 12 (?o'f) 63 l-6"«'/Report to: 10 Ke(/,'µ p,,rc 12
Purchase Order No. 6 . . / Carrier/Waybill No._13 _ .. 5 · -19 · 41o7</<:o..S
Required Report Date 11 /Voll "1/), · ------· AfZ -.-,~ ...... -■ -,...a.a;..;;=~==;;;;..;~.....;.....;.....;.....; .... "-,
Semple 14
Number
N5:) c7 4
N530 il
f/5"),/ 4
N c,3 2. i4
~15 , c, G
/\t<: -=ID [3
Ns3 r n
N <; ~ J fl..
Sample 15
"n/Tvna
Date/Time 16 Container' Sample 1 Pre-19 Requ-feating 20 Collectad r-Volume aenra--ram
2-1?-'i..7
I <;_b
I
BN4
I
, I I .
7
Special Instructions: 23 A.vv rJ ,,,:,, -J.,~.v <
Possible Hazard ldentification:'24
'I
Non-hazard I ..J Flammable ..J Skin Irritant J . v I Sample )isposal: 25 · Poison B J Unknown .4. Return to Client j Disposal by LabA:{ Turnaround Time Required: 26
Normal l'itf Rushlj . ,1
1 Reli~quished by 2-f. (. /}//,
(Signeture/Affiliationl ,,.. 1 : n/ ,~e ~
2. Relinquished by (' /
[Sigrieture/AffilietionJ /
I QC Level: 27 ' , -l.•l<f II J Ill . .J Proiect Saecific (s · • · ;_,.,. ;_~
Date:
Time:
' .. r) ...C; } 1. Received by 28 ~ / \:,,... ·· X"~oO P/11 (Srgnature/AlfillRtJOnJ /r'd )....
Date:
Time: 2. Received by
(Signeture/AffillRtionJ
3. Relinquished by
(Signeture/Affil1Frt..ionJ Date:
Time:
I r _A<.
3. Received by
[Signature/ flffrlmtionj
Comments: 29
,
Archive
.._,22
Aec:ardNo.
7 1993
(mos.)
Date: .2-tfs-"13
Time: 0~15'
Date:
Time:
------------------
-------------------rn INTERNATIONAL ANALYSIS REQUEST AND Reference Document No . .) ii O 1 1
TECHNOLOGY / _ ( ~ CHAIN OF CUSTODY RECORD* Page 2 of _2._ CORPORATION .>I /i )/"} :1,,<•1f IHll c.3 ,, I /. I '_L... /
Proj~ctName/No.1 fDS6{%.IC/./D SamplesShipmentDate 7 2-(l-1 Billto:5 ;v,t;,,~,r-.>7 ?Y<tr
Sample Team Members 2 /. //c:-¥ky Lab Destination 8 / ;i'/5 /11 f'c. 3,!:, If,-,Vo86/&' /',/ /U
Profit Center No. 3 Lab Contact 9 _/:-.
Project Manager• ,ti,/( 17 S/.,,/tkc•,,i..,-/project Contact/Phone 'Ve:? sJ 6 _J ,J-t!/? i;;-eport to: 10 j(ev,-,.._, P,1c /.(_
Purchase Order No. 6 Carrier /Waybill No. _13
I Required Report Date 1 1 Nc!1.A1,t1 li1D!IDIIII -
,-.■L,■!11 .. ·--
Sample 14 Sample 15 16 Container1 Bample1 -•9 Requeeted Teetlng 20 Condition on 21 Disposal 22 Date/Time
Number Det,crintinn/T..,.. Collec:ted T..,.. Volume aen,atiwe -ram R-Record No.
/v5.29 C ~.,.,,J w "'f F(/._
2 -/ 7-'V rh~h'c I /... IIAV:. r11 E0 I <; -2L ..-or Q,f_} ~/,,y/j>.3 JC:55
N5.3D C '
2-11-'i_>
J
'. l •v. l. t :.1 •. _l;
JSi./5 . --
,_ -.......
Ns3/ C -i.-f7A3 I \. ::, : P-.
I r;-30
N532 C 2 -17:J? lio I / I I/ ! '/ ~/
IVS J 'l /-:) 2--1 } -'J_J c./,1 CC l'/l.ft!,r1I 1+cl 1/1)/-J 1 <;('(' c-' "11'~
2 -I 7-'13 ,~ ; -' . .
)\)S-36 n I c '(c; ~ ' I • . • •
Jv53 I i.-, l·'i.3 ·• " 0 / 'i <0
N, ~, 0 I I/ 2. • I J-Cµ J6o, ' '/
II/ I/ \ {/
Special Instructions: 23 /J~ V n, ,C~ f:c1-vs-(.,/I /<. ft-,-.✓ fl4clc ( ~/20D I
Possible Hazard ldentification:'2• I Sample Disposal: 25
Non-hazard '..l Flammable .J Skin Irritant .J Poison B .J Unknown ..l" Return to Client ..I Disposal by Lab lit-Archive (mos.)
Turna~i ,nd Tim1; _Required: 26 J Q~Level: 27
Proiect Specific (snRc~'.,. · · Normal . Fb;l,.J . I. II . .J Ill . .J --. -
1 . Relinq, ished by J; /)~ Date: Z .:....1 l-';J, 1 . Received by 28 le7 Y Date: 2-/?-9_.J
15,gnature/Affihlltion) _ ,~ Time: <2 {Jc) . ~ !Signature/ Afftl1Ation) Time: 3,a::, ,,.,,.,.,
2. Relinquished by (/ Date: 2. Received by .2?31-' Date: -.J.-1 ,-1.3 ' !Signature/Affi~stion] Time: (Signature/ Aff1hAtion) ("r.45 Time: O'TtS
3. Relinquished by Date: 3. Received by
,
Date: [Stgn8ture/Affihation) Time: !Si9n11ture/ AffihatiOflJ Time:
Comments: 29
L /ff,e s 3?".3P