NCD991278953_19930303_National Starch & Chemical Corp._FRBCERCLA SAP QAPP_Analyrical Sampling Data OU-3 1992 - 1993-OCR

_..,
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION IV
345 COURTLAND STREET. N.E.
ATLANTA, GEORGIA 30365
MAR f 1993
4WD-NSRB
l RECE\\JEO
MAR 8. 1993
Alex Samson
National Starch & Chemical Company
10 Finderne Avenue
summJND SECtlON
Bridgewater, New Jersey 08807
Re: National Starch & Chemical Company Site
Salisbury, North Carolina
Operable Unit 3 -Split Samples
Dear Mr. Samson:
This letter discusses a concern over the enclosed Chain-of-Custody
Form which addresses samples collected during the RI/FS on Operable
Unit 3; the samples were collected during November 7 and 8, 1993.
IT Corporation and EPA's oversight representative, Bob Telford of
CDM both aquired samples for soil samples NS-31. This split sample
was to be analyzed for volatile organics, extractable organics
(BNAsf, and metals. EPA has been trying to get the complete CLP
data package from IT on this sample· for months. Please note the
comment written in the comments section of the Chain-of-custody
form. Splitting samples is a required activity for potentially
responsible party lead sites and.is not considered a reason for not
collecting samples for appropriate analyses. EPA requests an
explanation by March, 9 for the cancellation of the BNA and metals
analyses. The chain-of-custody form shows the sample submitted to
the laboratory for these analyses.
Please do not hesitate
concerning this letter.
number 404/347-1695.
to contact me if you have any questions
I can be contacted at 404/347-7791 or fax
Barbara H. Benoy
Remedial Project Manager
Waste Management Division
cc: c. w.
R.
Fehn, NCS
Smith, WD
Paradowski, NSCC /
B. Nicholson, NCDEHNR
R. Leahy, .ORC
H. Graulich, NSCC
M. Sturdevant, IT
J. Cole, . CDM
Printed on Recycled Paper
m INTERNATIONAL
TECHNOLOGY
CORPORATION
Project Name/No. 1N~-t-" ,, I .si .. --.1/-,o?J.,8
Sample Team Members 2 O !l-1l,,vl/
Profit Center No. 3
Project Manager 41'1· .sf-, --J.. ,~, f-
Purchase Order No. 6 · ,A/ /Ir
Required Report Date 11 1-z./3/'1 z. ('~ ~./-"'d
ANALYSIS REQUEST AND
CHAIN OF CUSTODY RECORD*
Samples Ship~ent Date 7 / / / ? / q c..
Lab Destination 8 T Tt;..', -1'1 -.J .l ld,v,,/c
Reference Uocument No.
Page 1 of
Bill to:5
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Lab Contact 9 JL:.,., La.-J'-'(
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Sample 15 Date/Time 16 Container 1 Sample 1 Pre-19 Requested Testing 2° Condition on 21 Disposal 22
Description/Tvoe Collected T-Volume sen,ative Pl"Qilram · Receiot Record No.
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Special Instructions: 23 3 t-~-------------------------------~------------------------------1 □ Possible Hazard Identification: 24 Sample Disposal: 25 _ 7
Non-hazard _J Flammable .J Skin Irritant .J Poison B .J Unknown ~ Return to Client .J Disposal by La0 Archive ( ~
Turnare':!nd Time Required: 26 I QC Level: 27 i
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TRANSMITTED VIA TELECOM'. rn INTERNATIONAL
TECHNOLOGY
CORPORATION
Ms. Barbara Benoy
Remedial Project Manager
November 24, 1992
Environmental Protection Agency, Region IV
345 Courtland Street, N. E.
Atlanta, Geoq;ia 30365
· IT Project No. 408668.60
GROUNDWATER SAMPLING RESULTS FOR OU3
NATIONAL STARCH AND CHEMICAL COMPANY SJTB
SALlSBJJRY, NORTH CAROLINA
Dear-Barbara:.--

-
-----· --
Enclosed are two.figures for your information. The first figure shows the groundwater sampling
locations and se<:ond figure shows the concentration of 1,2-dichloroethane at the points that have
been sampled and analyzed to date. The analytical results of samples collected today will be
available tomorrow. After those data are received and evaluated NSCC/IT will make a
re<:ommenclation to EPA for additional groundwater screening sampling points.
If you have any questions, please call me.
Sincerely your ,
/?'.A.,,/A-,-1 ~
Michael N. Sturdevant, P.E.
Project Manager
/ms
cc: Hank Graulich, NSCC
Ray Paradowski, NSCC
Alex Samson, NSCC
!lag!onal omce
312 Direc:tors DrJve • Knoxville, Tennessee 37923 • 615~690-321 l
l'r Corpoi',:,tl/c,n I~ a wJJol/y 1.1wot<d :allJx/,JlllrY vi lntem1(JC/cmul TuchnoJogy Corpororton
,...,....__
i ' I
..... , -··" ., ..
• NS-01A
• NS,24
21
10 .6. .6.
•
a A 19 .6. w
GROUNDWATER SAMPLING
LOCATIONS USED
FOR SCAEl!NING
NATIONAL STARCH ANO
:CHEMIOAL COMPANY
SAL/SSUAY N,C,
t:,. t:,.
• t:,. t:,.
NS-01A
• NS,24
!:::,.
1,2·DCA CONCeTRATIONS
IN OROUNDWATl:R
SCREENING SAMPLES
NATIONAL STARCH ANO
CHEMICAL COMPANY
SALISBURY N.C.
\
• • UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION IV
345 COURTLAND STREET. N.E.
ATLANTA. GEORGIA 30365
FEB 1 0 1993
•
4WD-NSRB
Alex Samson
National Starch & Chemical Company
10 Finderne Avenue
Bridgewater, New Jersey 08807
Re: National Starch & Chemical Company Site
Salisbury, North Carolina
Operable Unit 3
Dear Mr. Samson:
HECl:IVED
FEB 1 6 1993
SUPERRIND SECTION
The CLP data package for water samples collected from NS-31 and NS-
32 were received from IT. The package should have included a soil
sample NS-LA-11, and the associated blank and spike soil samples.
In addition, the previous CLP data package that contained soils
sample NS-31 did not include the extractable organic and metals
analyses. The chain-of-custody shows these analyses· were
requested. Please provide the data packages or an explanation by
February 17, 1993.
Please do not hesitate
concerning this letter.
number 404/347-1695.
to contact me if you have any questions
I can be contacted at 404/347-7791 or fax
Barbara H. Benoy
Remedial Project Manager
Waste Management Division
cc: C. Fehn, NCS R. Leahy, ORC
W. Smith, WD H. Graulich, NSCC
R. Paradowski, NSCC / M. Sturdevant, IT
B. Nicholson, NCDEHNR ✓ J. Cole, CDM
Printed on Recycled Pa,ier
• •
September 9, 1992
To: Jack Butler and
National Starch and Chemical Company NPL Site File
From: Bruce Nicholson '1:sttJ
Subj: Telecon with Barbara Benoy, Remedial Project Manager,
U.S. EPA Region IV, [phone].
Barbara Benoy contacted me today to tell me that the plume
periphery sentry monitoring wells southwest of the National Starch
site have turned up with 1,2-dichloroethane (93 ug/liter in one
well and 110 ug/liter in the other wel~. The wells are southwest
of the site boundary, but she could not tell me the exact location
of the wells except to say that they were sentry wells that were
supposed to monitor whether the plume was moving off site. I told
Barbara that I was aware that there were private wells in that
direction. She was also aware of this and said she was meeting
with National Starch tomorrow at 11 AM to discuss the situation.
I requested that she notify National Starch that after reviewing
the location of the sentry wells relative to the residential wells
it is very likely that.the state will request that they sample the
residential wells as soon as possible. I requested a copy of a map
showing the wells in question. She said she would supply it after
talking with National Starch. She welcomed my participation in the
meeting and regreted not telling me of this situation when she was
here last week concerning the Koppers Site.
If possible, I intend to participate in the .meeting via
telephone.
BIN\tel\nssentry
m INTERNAT,NAL
TECHNOLOGY
CORPORATION
TELECOPY NUMBER:
TO:
FROM:
DATE:
NUMBER OF PAGES:
(INCLUDING COVER SHEET)
919-733-4811
Bruce Nicholso11,
NCDEHNR
Mike Sturdevant
IT CorporaJion
•
312 Directors Drive
Knoxville, Tennessee
[phone]
September 14, 1993
3
REMARKS: Proposed procedures and schedule for hydrophobic dyB shake
test at National Starch.
IF ALL PAGES ARE NOT RECEIVED, PLEASE ASK FOR EXTENSION 2223 AT
[phone].
IT Knoxville Fax No. [phone] or [phone]
(Please return when sent)
.;.. • rn INTERNATIONAL
TECHNOLOGY
CORPORATION
Mr. Jon Bornholm
. Remedial Project Manager
September 14, 1993
Environmental Protection Agency, Region IV
345 Courtland Street, N.E.
Atlanta, Georgia 30365 .
•
OU3 DNAPL Field Test
National Starch and Chemical Company
Dear Jon:
IT Project No. 409806.60
Enclosed as Attachment A is the planned . procedure for conducting the NCDEHNR
recommended field test to determine a presence or absence of DNAPL in Area II subsurface
soil. Given your approval, we are planning to conduct ·the field test on September 22-23.
Please let me know, if you approve of the procedure and the scheduled dates for performance.
~ ~/
Michael N. Sturdevant, P.E.
Project Manager
cc:. Abu Alam, NSCC
Hank Graulich, NSCC
Bruce Nicholson, NCDEHNR
Ray Paradowski, NSCC
Judy Reagan,IT
Alex Samson, NSCC
Jonathan Shireman, IT
Regional Ofiice
312 Director, Drive• 1~'1or,11le, Ter,nes.see 37923, 615-690-3211
IT Corporation is a whoUv ownt•d subsld!o:y o~ htomotzoncf Toi;hno!ogy Co~poratto~
• !NT.TIONAL TECHNOLOGY CORPCf<AT:O~J
2
•ATIACHMENT A
· Procedures for
Hydrophobic Dye Field Test to Detect NAPL
at National Starch and Chemical Company Site
Salisbury, North Carolina
September 14, I 993
Background
The NCDEHNR has requested that National Starch determine if there" is a presence or absence of dense non-aqueous phase liquid (DNAPL) in the .subsurface soil near Area II at the site. The procedure as recommended by NCDEHNR is described in detail in the Fall 1992 issue of Ground Water Monitoring Review, the article is titled "Evaloation of Visual Methods to Detect NAPL in Soil and Water" by Robert M. Cohen, Anthony P. Bryda, Scott T. Shaw, and Charles P. Spaulding.
Sample Location
One boring will be drilled near boring location SBA2-20 where the highest detectable concentration of 1,2-DCA was recorded. The boring will be drilled through the concrete to either the water table or to refusal. Soil samples (maximum of three) for the field test wiJl be collected from zones which indicate the highest concentration of detectable organic based on the readings from an Organic Vapor Analyzer. The sample collection and decontamination procedures will follow the EPA approved Final RI/FS Work Plan for OU3.
Field Test Procedure
The following steps will be followed after collection of soil samples:
1. Weigh out 20 grams of soil for the test and place in 4 oz. glass jar. 2. Add 40 ml of distilled water to the soil and mix.
3. Add 1 mg of hydrophobic dye and shake 10 seconds.
4. Visually inspect the sample to determine the presence or absence of NAPL by looking for a red tinted liquid on wall of jar. If no free product is present dye will remain as small black specks on wall of glass jar. If minute free-product is present a light dispersion of red dye will occur.
OP PACifS
IT CORPORA:rIOB
312 DIRECTORS DRIVJf
JIJIOXV:!LL'&, fll 37923
(615} 690-3211
• •
ffLBCX>Pr ~
D:!SCARD PnCirlf SBJl'r
PLDS:B llZ'I'CJRN
D' ALL P.At:BS ARB' BO'l' RKCHIVZD, PLKASZ ASX FOR lU.i'BRsION 2223 · AT
'1.'1lB ABOVB BUlOiXR. 2'HABX YOO.
n' DO%VILU ru so. 615/690-3626 OR
6l5/690-4652
TELECOPY NUMBER:
TO:
COPY .REQDBS'l'
(io;}s47-/~Js-
,,,:3~ !etc·=---&.A-6> v £~A 7
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DATE;
NUHBER OF PAGES
IT CORPORATION
312 DIRECTORS DRIVE .·
KNOXVILLE, TN 37923
[phone]
I
5 (INCLUDING COVER SHEET)
DISCARD WHEN SENT
PLEASE RETURN ~
IF ALL PAGES ARE NOT RECEIVED, PLEASE ASK FOR EXTENSION 2223 AT THE ABOVE NUMBER. THANK YOU.
IT KNOXVILLE FAX NO. 615/690-3626 OR
615/690-4652
VOU..TILE ORGANI~ALists CATA SH!:!T • Ti'll?71"D
Lab Na111Q: I'l'AS-PJOXVIt,I,Fi cantr11.ct:
Lab Cede: I'l'S'fU Caao NO,: 51410 SAS No,: soo No,: TWP6
Matrix: (aoil/water) WATRR Lab Sample IOI 52449
sample lrl't/vol; 5,0 (g/m:t.) mi_ Lab File ID: K2449
Level: ( low/111111d) LOW Date REICfiliVed: 0!5/l!i/92
% Moiatuz:-e: not doc. -Date Analyzed: 06/15/92
column: (packjcap) CAP Oilution Factor: 1,00
CONCENTRATION ~"NITS:
C::AS NO, COMPOUND (Ug/L or uq/Kg) :Q;LL Q
74-87-3---------Chloromathana 10 u
74•83•9---------Brcmcmothana 10 tl
75-01-4---------Vinyl cnlcirid.o 10 V
7S•OO-J---------Chloroethana 10 u
75-0i-2---------Mathylena Chlor1do 5 u
67-64•1--·------Acatcne '2\0 ~ ZD
" ,,,.,.. "I " • • . • --~ ..
----
75•15•0---------carbon Di•ulfide 5 u
75-35•4---------1,1-oichloroetheno 5 lJ
75•J4•l---------1,1-oichl0roethano 5 t,)'
540-59-0--------1,2-oichlaroet.~•ne (total)_ 5 u
67•66-3---------Chloroform 5 u
101-oe-2--------1,2-cicnlorcethano s u
78-93-3---------2-Butanona l.O tr
7l-55-6---~-----1,1,1-Tri0hloroethane !S u
55•23-5---------carbcn Tetrachloride 5 u
108-05-4-----•--Vintl Acetato 10 u
75-27-4•••------Br~dichlorOlllethanm 5 u
7B-e1-5---------1,2-oichloropr0pane 5 u
l004l-01-5------oia•1,3-Diehloropropene 5 u
79•01-6---------Trichloroethone
, u
124-48-1--------Dibromcx,hloromethane !5 u
79-00•5•--------1,1 1 2-Triohlaroethano 5 ti
71•43-2---------!en1ene s u
100&1-02-6------Trane-1,J-Dichloropropene_ 5 u
75-25-2---------Bramofor:m 5 u
1oe-10-1-•------4-Methyl-2-P•ntanone 10 u
5g1-1e-6-•------2-HRxanone 10 u
127-19•4••------Totrachloroethene 15 u
7g.34-s---------1,1,2,2-Tetraohl0roethane_ 5 u
108-88-l•-------Tolumna 5 u
108•90-7--------Chlorobenzene 5 u
100•41-4--------Ethyl~enzan• 5 u
100-42-!5·--•----Styrana 5 u
lJJ0-20-7-------Xylo"a•(toeal) 5 u
FORM I VOA 1/87 R&V,
VOl.l\TILB ORGANI~.ALYSIS DATA SHE~T • EPA SAMPLE NO.
TWP7
Lab Name: ITAB•KNQXYILI~ contract:
Ca&o No.: 51410 SAS No.: soo No.; TWP§
Matrix: ( 11oil/w11tQr) WATEB Lab sample lD: K2448
Sample wt/vol: ~.o (g/l!IL) MIL_. Lab File IDI K2448
Lovel: (low/111od) tow Date R1caiv1d: 0!5/15/92
% Moiaturel not doc. Date Analyz•d: 05/15/93
Column: (pilck/Cllp) CAP Dilution Faotor: 1,00
CONCENTRATION UNITS:
CAS NO. COMFOUNO (uq/L or ug/Kg) ~-Q
74-87-3---------Chloromethane 10 lJ
74-83-9---------Bromomethano 10 t1
75•01-4---------vinyl Chlorid.• 10 \'.J'
75•00-3--•------cnloroethane :i.o u
75-09-l---------Kathylone Chlorido 5 u
67•S4-l---------Acetone 190
197 13 1 A4eyle11!,11'll• .. w a-
75•1,-0----•----CArbon DiGult!ae !5 u
75.3,.4---------1,1-Diohlorootnone ?i u
75-34-3---------l,l•Dichloroathane ~ u
,40-59-0--------1,2•Dichlorcethena (total)_ 9 u
67-66-3---------Chloroform s u
107-06•2--------1,2-Cichloroeth~ne 5 TJ
78-93-3---------2-B~tancne lO u
11-,5-6---------1,1,1-Trichloroethane 5 u
56-ll-s---------c~rhcn Tot~achlorid• 5 u
ioa-o&-4--------vinyl Acetate 10 u
75-27-4---------Bromodicbloromethano !5 u
78-87-5---------1,2-Dic:hloropropano 5 u
ioo61-01-s------cia•l,J•Oichlor0~ropone ti u
79-01-6----v••--Trichloroethono ! u
124-48•l•-------Dibromochlorcmothane 5 u
79-00.-5••-----•-l, l, 2•'1'ric;:hloroot.h1i.ne 5 u
71-4J-2---------Ben2ene 5 u
100~1-o~-~------Trcna-l,J-olchioropropen•_ !I u
75-25-2---~~----eroaofon 5 u
1oa-10-1--------4-Methyl•2-Pan~anone 10 u
5gi-70-6--------~-Hmxanone 10 lJ
1~7-18-4--------Tetrachloroothene 5 u
79-34-5---------1,1,2,2-T•trachloroothanc_ !5 u
lOB-88-3------•-Tolumne 5 u
108-io-1--------Chlorohenzene 5 u
100-41-4--------Bthylbenzene 5 u
100-42-5--------strnne s u
. i~,o-ao-7-------xy onee(,o~~!l 5 u
FORM I VOA 1/87 Rev.
VOLATILJ: ORCANI-~ALYSIS DATA SHEET • tPl\ SAMPLE NO,
• TWJ?f,
Lab Nama: ITAS-JSNOXVJI:I:l'i Contract:
LaJ;i Code: ITSTU CQse No.: 51410 SAS No.: SDC No.: TWr6
Matrix: (&oil/Water) WATER Lo.b Sample ID; lit 4 47
Sampl61 wt/vol: 5.0 {g/mL) Hll..-IAb l'ile IO; K25iZ
level: (low/med.) LOW Date Receiva~: 05/15/91_
% Moi:stura1 net dmc::i, oata Analyzed: 05/15/22
Colunm1 (paek/oap) CAP Dilution Factor: J., 00
CONCENTRATION TJNITSI
CAS NO. COMPOUND (ug/L or ug/KgJ l,Z!U~ Q
74•87•3--•-----•Chloromathane 10 u
74-8J-9---------Bromomathane 10 u
75-01-4---------Vinyl Chloride 10. u
75-00-3---------Chloroethana 10 TJ
75-09-2---------Methylena Chloride 5 tr
67-64-l••-----•-Ac~tona 'SOC) ~ :Zb .. ,,._ ...... . ·-• ·~ •---
' 75~15-o=--------carhon Oi•~lfide
-~
!! u
75-35-4---------1,l-Diehloroethane !S u
75•34•3•--------1 1 1-oichlorc::iethona 5 'C1
e40-S9-a--------1,2-oichloroathanQ (total)_ !! u
67-66-3•-------•chloroform !I u
107-06-~--------1,2-Dichloroothane 5 u
78-93-3---------2-Butanone 10 u
71•55•6---------l,l,l-T:1ohloroethane 5 V
56•23•5---------carbon Tatra~hloride 5 u
108-05•4--------vinyl Acet•ta l0 u
75-27-4-------~-Bro=odiohloromiithano 5 u
78-87-5---------1,a-oiohloropropane !I u
10061-01-s------cia-l,3•0ichloropropane 5 u
79•01-6•--------Triohloroethena · !5 IJ
124•48-l•-------Dibromochloromethane 5 0
7~-00-s---------1,1,2-Triehloroethane 5 u
71-43-,---------Benzene 5 u
10061-02·6·•----Trana-l,J•Diohlorop~opene_ 5 u
75-25-2-~-------erozotoz:,n. 5 u
lOa-1O-1--------4-Methyl-2-Pontanone 10 u
591-7B-6--------2-Hoxanon• lO u
127-18-4--------Tetraohloroethene 6 u
79-J4-5---------l l 2 2-Tetrachloroathane 5 u , , , -
108-88-J-------•Toluone 5 u
lOi-90•7--------Chlorobenzene 5 0
100-41-4--------Ethylben1ene 5 u
100-42-s--------styrat\a 5 u
lJJo-20-1-------Xyleno ■(Eotal) 5 u
J'OftM I VOA l/67 Rev,
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LEGEND: E WAITR mo
,m PROPOSED~~~~ POIITTS "' SEDIMENT
GROUNDWATER ~ PROPOSED POIW ~ 5.'MPUHG
STING SAPROUTE a EXI ITORING WEI.L UON
NG BEDROCK e r~ORING WEl.L
. FIGURE AL~~Allotl MAP SAMPLE
, NA TICWAL STf~ANY
WO CHD,1/CA C
.1 SALISBWIY. N
· JNTI:Rff !llOHAL , r-z:":I fl:CHNOWGY
:, ~ CORPORATION ~
4WD-NSRE C) /,
DATE:_J_/-l·r; 9 D
REGION IV
'345 COURTLANO 5TR£.E:T. N.E.
ATL..ANTA., GF.,ORGIA 30~l-:,';i
FAX COVER SHE,'!:
FAX NUKBER: FTS 257-2684
co;l.H:SRCIA.L 404/347-2684
PLEASE CONTACT 404/347-7791
---· --· -----"
------·
if any pr-oblems occur with thi9
trai,smlttal.
-------__ ,. __ ,_, ____ -------
··---·------.-----.. ---· ------
• • RESULTS OF THE
VOLATILE ORGANIC COMPOUND
SAMPLING PROGRAM
NORTHEAST TRIBUTARY
NATIONAL STARCH AND CHEMICAL COMPANY
INTRODUCTION
Surface water, surface sediment, and soil samples were collected
at National starch and Chemical Company (NSCC) between July 10
and July 13, 1990 for analysis to determine the __ levels _of
volatile organic compounds (VOC) on the Target Compound List
(TCL). The sampling points are shown·on Figure 1 (enclosed).
Water and sediment samples were collected from the stream along
' the eastern edge of the plant boundary, referred to as the
northeast tributary.
Soil samples were collected from three sampling points along
seven sampling transects oriented perpendicular to the creek.
Two soil samples were collected at each soil sampling point, from
0.5 to 1.0 and 3.0 to 3,5 feet, using a stainless steel hand
auger and
detector.
screened for voes using an HNu photoionization
The sample which showed the higher screening value was
collected for analysis. If the samples exhibited the same
screening value the following procedure was employed:
The 0.5 to i.o (shallow) foot sample was taken from the
sampling point nearest the plant, point A on Figure 1,
The 3.0 to 3.5 (deep) sample was chosen from the point
nearest the stream, point Con Figure 1,
The deep and shallow samples were collected alternately from
the intermediary point, point Bon Figure 1,
In practice, only the deep sample adjacent to the stream
exhibited positive screening values, In two cases, to confirm
findings of the sampling procedure, a sample was submitted for
analysis from both the deep and shallow samples.
NS005
July 23, 1990, DRAFT# 0 1
• •
The analytical results of this sampling program are summarized in
Tables 1 through 3 and the distribution maps enclosed. Volatile
organic compounds of concern found in the stream water and
surface sediments were 1,2-dichloroethane (DCA) and toluene.
Acetone and methylene chloride were detected in surface water
samples but are also reported in the applicable method blank,
DCA was detected in four of the six water samples and in three of
seven sediment samples. Toluene was found
sediment sample each. DCA ranges from 160
billion (ppb) in surface water and 980 to
in only one water and
to 1700 parts per
--3400 ppb in sediment.
Toluene occurs in surface water at 9 ppb and in sediment at 5
ppb, Methylene chloride was detected in the surface sediments (4
to 11 ppb) but not in the applicable method blank.
A much larger suite of voes were detected in the soil sediments
than appeared in the surface waters and sediments, Compounds
detected but not found in the method blanks included vinyl
chloride, 1,2-dichloroethene, DCA, 2-butonone, toluene,
ethylbenzene, and xylene. While vinyl chloride'was detected in
two samples, it was not present at a quantifiable level. The
presence of acetone at levels above the detection limit. in a
number of samples suggests that this compound is occurring in the
soil and is not necessarily a laboratory contaminant. DCA was
found in four of the 23 samples analyzed ranging from 57 to 1700
ppb. Toluene occurred in 18 of the samples ranging from 6 to 170
ppb. DCA and toluene were the only voes reported from all three
media sampled and therefore the distribution of these compounds
will be the focus of this report.
NS005
July 23, 1990, DRAFT# 0
• • DISTRIBUTION OF DeA
Distribution of DCA in surface water, sediment, and soil found as
a result of this investigation are shown in draft figures
enclosed with this report. The highest levels and widest
distribution of DCA is in surface water and sediments.· There
appears to be no correlation between the level of oeA in the
channel sediment sample and corresponding surface water sample.
However, because of the generally high levels of'oeA found in the
surface sediments, and overall absence or relative low
concentrations of DeA in soil sample from the 3 .·o to 3 ."5 foot
interval the most probable source of oeA in the stream water is
the channel sediments.
Soil samples were collected to establish the level of voes in· the
soil column and to provide a preliminary concentration profile in
the vadose zone. Ground water was encountered in the sampling
points adjacent to the stream channel at about 2.5 feet. oeA was
reported from the deep samples at so-01e, and S0-06C, and from
the shallow sample at S0-05B. The level of DCA at depth in soil
at so-o?e is comparable to the levels found in the stream
sediments and surface water at the adjacent point, SW/SE-14,
Levels of oeA found in surface water and surface sediments in the
stream channel are far in excess of the levels of DCA round in
the soil samples except for the deep sample at S0-07C.
One surface water and sediment sampling point, SW/SE-15, was
added to the sampling program to evaluate the possibility off-
site migration of voes. This point is located at the northern
boundary of the Nscc property (Figure 1) where the northeast
tributary exits the site. As seen from Tables 1 and 2 none of
the TeL compounds were detected at this location.
NS005
July 23, 1990, DRAFT# 0 3
I l
• •
DISTRIBUTION OF TOLUENE
Distribution of toluene in surface water, sediment, and soil
found as a result of this investigation are shown in draft
figures enclosed with this report. Toluene is more wide spread
than DCA in soils, but at much lower levels. While toluene is
widely distributed in soils, this compound is found in only one
surface water/sediment sample,
CONCLUSIONS
Two voes of concern have been identified during this
investigation, DCA and toluene,
DCA was detected most often in·surface water and surface sediment
samples collected, but there is no detectable off-site migration
taking place. There are three soil sample points where DCA was
·detected, one of which exhibits DCA concentration close to that
found in the adjacent _surface water/surface sediment sampling
adjacent point.
Toluene is present ·at low concentrations in most soil samples,
however is present in only one surface water and surface sediment
sample.
NS005
July 23, 1990, DRAFT# 0 4
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"j,0-1 $0'-....,_L,_~ llibUf'U;tT -(~
S,Jf';:s.E·IS, -•~C[ Mfifl ,llCI K~f ~il .,,_11!11
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i • '--ST11£.loM •o
s-.( .._..,1 '1fs-u,o,.
'SC,i,L(
•~ •ff.'""'•~ "I. ..,s'°"'
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[!i co,_....,. ---
JtAT°"""'L SU,.il'(t< .l,H[; (t£1,,C1(.<,L .(:O ..... AJO'
CUlol.R ~<; 1111.»,0 l'\..U,l
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~tOl,OIIAl A(MlfDIAl .. W:S.1Ma,"fC)frl
~ Tltt~U.R• Cn.a"A(TCfl:IZ._T,ON
TABl.E ., . ~TJOIIAL STARCH: CRG.6.NJC ANALYSJS RESt.l.TS fR{JI( ~FACE UATER SAMPLES COllECTEO JULY 10, 1990
SAM'I.E IUll!OtS
JDEWTI FIED wPJITI TA TIC..
01.GAIH C ClM'CIM)S LIMITs" 511-09 SIHO
DATE 7/10 7/10
TARGET COIPO.Oll LIST Sl.16ST AIICE S FCU.O IW SAMPLES
b .ethyl ene ch l or i de 5
acetone 10 6,/'
11 2-dichloroet:hane 10 160 11,l)(l
toluene 5 g
Quanitation limit.
b --Indicat~ organic cOlllpOU'ICb. that were not detected.
c: INA. not applicable~ s8fIPle could not be collected.
5"-H
7/10
d Reported concentration is below the cp.rantitation l ialt.
· e Ccnipou-d is also present in the aethod blank.
003,
S11-12
7/10
WAC
5de "" I/A
~A
(Coocentrations ar-e in ug/l (p,x>))
DIR I CATE
S'1-13 5'1-14 5'1-14 5'1-15
7/10 7/10 7/11 7/13
tie t1"' tie
880 1700 1100
SW-TRIP
SW·R BLAIII( VBLIC2
7/10 7/10 7/16
• tie ~ 4de 4
•
TABlE 2. IIATlOIL\L STARCH: Ol!GAIIIC ANALYSIS RESULTS FR01 SU!fACE SED!NEIIT SAll'I.ES OOLLECTEO .ULY 10, 1990
-LE IUIBER
Concentrati ens are in ug/kg (J:l'O) on a dry 110i11ht
lDENTlflEO OUAIIT IT A Tl ON
CIIGAII IC CIH'CUIIDS LINITs" SE-09 SE-10 SE· 11 SE-12 SE·B SE-14
DATE 7/10 7/10 7/10 7/10 7/10 7/10
PERCE)jl MOJSTLOIE 36 34 65 25 30 28
TAR{;ET COIPCUII) UST SlJIISTAIICES FC1NI IN-LES
-.ethylene d'llor-ide s
1t'
8 11b 10 C ,b
acetcoe 10 66
1 ~2-dichloroethane 10 9IIO zb ,}> 3400 1200
2"-Butancne 10
toluene 5 Sb
a Ouanitation l iaits are OOSed on wet weights of the soaples. b Reported conc,entr-ation is below the quantit.aticn liSlit. adjusted for aoisture content.
:::: ·· Indicates organic c~ that were oot detected.
d Kethod blank VBlK2 7/16 and Trip Bl-7/13, Table 3 llff>lY
SE-15
7/13
26
6bd
basis
VBU1
7/16
•
•
TABLE 3. IIATIOIW. ST..W:H: ORGIJIIC AIW.YSJS RESUI.TS FRDI SOIL SNl'\.ES COC.LECTEII JJI.T· 11 TO 13, 1990
SAHPL£ IUllER
Concentrations are in ug/kg (R=fJ-) on a dry weight basis.
IDENT1flEO
ORG,Ul!C ~S
OEPTM [WTERV-'l.
PE= 11'.llSTIJl!E
TAAacT ~ LI ST
Sll!STAWCES fCllJIII IM
SAl4'LES
vinyl chloride
aethylene chlodde
acetone
carbon disulfide
1,2-dichloroetnene-
dilorofona
. 1,2-dichlOf'oethelne
2-Butanone
toluene
e-thylberu.ene
xy.lenes (total)
DATE
Cl.lMIT IT AT l OIi
UNITS"
10
5
10 s
5
5
10
10
5
s
5
S0·01A
0.5·1.0
7/13
16
b ..
ac
6cd
1cd
25
15
S0-018 S0-01C
3.0-3.S 3.0-3.S
7/13 7/13
25 15
\Oc
jcd
6c
rd
led led
16 8
7
37 25
8 Quanitetion l i■fts are bm.ed on wet weights of the ss.plies.
b • -1o:1; cat es orgoni c ~ that wene not detected.
C C CllpOl,.ft] i s a l so fOl.lld i n ae tho:i bl enk.
S0·02A S0·02B S0-02C
0.5-1.0 0.5·1.0 3.0-3.5
7/13 7/13 7/13
15 17 35
4d
6c 6cd 8c
4cd 25C IJ~ 3
led 1cd
3C
30
~ 170
8 zd 12 33
d Reported an:entration is. below the q.mntltation lf■it,. adjusted for .:>isture content ..
003
S0-03A
0.5-1.0
7/13
21,
S0·03B
3.0-3.5
7/13
34
S0-03C
0.5-1.0
7/13
31
11
1~
z<:l
1 of 3
S0·03C
3.0-3.5
7/13
ZB •
~
14
,d
•
+
J
D
'>
TAlllE 3. (a:wT.) IATIOIW. STARCH: OltGAIIIC /JIALTSIS RESULTS fllOI SOlL SAIW'I.ES <XX.LECTED JU.. Y 11 TO 13, 1990
SAMPLE IUIBER
Concentrations ~re in ugtk-g
[DENT IF I ED
Ol!GAMJC IXH'!Ul)S SO-OU. S0-048 S0-04C
OEPTM IMTERVAL 0.5·1.0 0.5-1.0 3.0-3.5
DATE 7/12 7/12 7/11
PERCOIT MO[S~E u 20 I!
T~T o::w'0..11) llSl QlMJITl TA.Tl CII
SWSIAIICES fOJ.1,1) IN UM!Ts"
SAK't.ES
vir,yl chloride 10 . -b
methylene chloride-5 6; 38c 4cd
acetone 10 ad
zed carbon disulfide 5
1~2·dichloroethene 5
ch t orofor,a 5
1,2-dichloroet:hl!ne 10
2-Butanor-.? 10
toluene s 6
ethyl benzene 5 zd 3d 5d xyleoes (total) 5
: Ouani tat ion l iai ts are based on wet weights of the ~es.
•-Indicates organic C0llp0Ulds that wet"'e not detected.
S0-05A 50·058
0.5-1.0 0.5-1.0
7/12 7/12
22 19
31c 3~ ii° 11
630
64d 29
6
26 10
c aapou1d is also fot.nd in tM wethod blenlc..
d Reported conc:entretion is below the quantitation l i■it adjusted for aois.ture content
003
(i:pi:>J en .a· a-y wei !!#It
DUPLICATE
S0-05C so-osc
3.0-3.5 3.0-l.5
7/11 7/11
7
BC 6c ~ ·2 ~
13d
3 1~_:
14 10
2 of 3
basis
S0-0,,,. S0-068 S0-06C S0-07A so-078
0.5-1.0 3.0-3.5 3.0-3.5 0.5-1.0 3.0-3.5
7/12 7/12 7/11 7/12 7/12
24 22 23 21
1.
"' 6cd 16c -,c_ 6cd
3d 5d 30cd 12d 6d
2
57 -;_4
13 7 41d 22 25
!f 6d 4
18 11 9
•
TAIILE 3.{COIIT.) IIATI~ STARCH: ORGNIIC AIIAL\'SIS RESU.TS fl!(l'I SOIL ~LES COLLECTED .-JLl 11 10 13, 1990
SAll'I.E WIMBER
Concentrations are in ug/kg (ppl>) "" a dry ""igt,t basis
IDENTIFIED DlPI. I CA 1 E
OlG.'JIIC IXN'O.Jll)S SO-OJl: 50-071:. S0·07C
DEPTH INTEaYAI. 0.5-1.0 3.0·3.S 3.0-J.S
D•TE 7/11 7/11 7/11
PERCEll'T NOISTURE 42 35 35
TARGET CCK'Cl.lrl) UST CIUJJfT 1T A TI OM
SUBS T AliCES flUO IN LIHITS8
SA>IPI.ES
vinyl dltoride 10 --C
methylene chloride 5 10d # s;,d
acetcne 10 4~ 37"
carbon disulfide 5 10
1,2-dichlor,oetMne 5
chtoroforl"J 5
1,2 ·didl Lorcothone 10 1,!00 1100
2-Sutanone 10
toluene 5 15 21e
ethyU:ieru:ene 5 9e
xylenes (total} 5 2"
a VBl.(1 7/~6/90 applies to R-11 ard lRJP BLAII( 7/13/90.
VSLX2 7/16/90 applies to S0-1A, B, ani C to S0-03.A, B, and C.
VBU(1 7/17/90 applfes. to .S0-07A and 8 to S0-07A. an::f 8.
VBLKl and VBL(.2 e,:pty to S0-4C to S0-07t: 8nd SIJ-140.
b Quanitat ion l \.-rits arr based on wet wei!;#l,ts of the SMples.
c - · Indicetes organic coqxiu-.ds that were oot detected. d Conipou,d is also reported in. the appl,icable 1t11ethod btant
TRIP R-10 TRIP
BlANI( BU.II(
7/12 7/12 7/U
sl-,de'
2" 2~
r Rq::,orted concentration is be-low ~ q.mntir.ri,tion l iait .. after adjusting for wetness facto;.
003
R-11 wu:,a
7/13 7/16
1"
3"
11 ·
3 of 3
Vllu:2 VIIU:1 VIILU . VBl.i:2
7/16 7/17 7/19 7/19
•
3" Cl" 1e 2"
6
3"
. 1e
,e
•
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I
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UNITED Sl'Al'ES ENVffiOmiENTAL PROTECTION AGENCY
REGION IV
345 COURTI.AND S11lEET, N.E.
ATI.ANTA, GEORGIA. 30365
FACSIMI.LE TRANSMITTAL COVER SHEET
Date· \p -() · 9 !) Time: -'\~I• ...... I....J.~'-----'60 a.m. D p.m.
To, 1?:>r:uci.. 1'J ', c rJo) Boo
Company/Organization: _________________________ _
Phone Number: ----------rax Number: 919 -'.] 3 o· qi 11
Number of Pages Sent (Including T/.?is Cover Sbeel), _ _.5--:..,_ __ _
Please comae/ Bm·bam Benoy if tbis fax is l'CJCeived poorly or i11comple1e.
FROM: Barbara Benoy, Remedial Project Manager
Nonh Carolina Section
No11h Superfund Remedial Branch
\Vaste Management Division
Phone Number: c104) y;7. 7791
FTS: 257-7791
rax Number: [phone]
FTS: 257-1695
NOTES: _____________________________
_
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COMDSNTIIIA'l'IO>f l1Hl1'S i
tug/t. or uf/1(;) UQ(.t,
76•00•)•~•-•••••Chlo:tOQthana
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4800
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170
170
75•i4•i-~••w•••11 1•»1ahloroathanu lie6i1)_:_
170
940•19•0--------1,a-r>ichlo:r:o~ 170
6'1-66-i-~-... ••••-chloroto& ,. • 170
101-ce-a-------1,2~bioblQroot6~na 1,0
71•93-3••------i~&~t•l\DI\Q _ -~
71•1a-1-------1,1,1-"1:richl.oroa'Uii\o
• 330
1'70
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101•08•4•••--•••~inyl AOllt&u 330
71•37•4••-•--•--~iebl~M~
170
78•81•9••••-••••1 3•D1Clbl.ot°faop&\"'11 1.70
1oc,1wo1-1------alo-1,,-PlQh orop~opene 1'70
7t•01•G••••·•-•-'r~iait\1oroothemci
170
li4•4&•i-----••Dilll!'lmOObl~r=cQra~e 170
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71•4)•2••·--·••&an;en&
170
100&1-oa-6-----:re.na-1,S-bllliorop~~-170
75-as-a---------~foffl · 170
1oa-10-1-••·---,-no~y1-2-ioi\€cinori°G 330
S91•78-6·•----2•HeKll.~DI\O ,:so
1:17•10•4••-•••--Tftraohlo:r:co\heiicii
:1.10
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10 ■-Ge•)•--•••••TOl'IIGllla 170
100•10~7••••-•-chl.o~btlnmGM
170
100-,1-,--------Rthylbllm.RBM 110
1ao-,a-,--------atr;:no .. Ill 170
l))O•a0-7•-----JCr.~nosltotalJ 170
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