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HomeMy WebLinkAboutNCD991278953_19880902_National Starch & Chemical Corp._FRBCERCLA ROD_Draft Record of Decision-OCRI I I I I I I I I I I I I I I MEM)RANOOM DATE: SUBJECI': 'ID: UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION IV 345 COURTLAND STREET ATLANTA. GEORGIA 30385 September 2, 1988 Recot"d of Decision (ROD) National Starch Site Salisbury, NC Giezelle Bennet~ Superfurxl Project Manager ROD Review Team -Lee Crosby, NC Solid & Hazardous Waste Gail Vanderhoogt, water Doug Lair, ESD Wade Knight, E.SD Riess. Collier, US F&W Cody Jackscn, ATSDR Winston Smith, Air I Attached is the Record of Decisicn for the National Starch Site located in Salisbury, NC. Please provide any comments to me no later than September 14, 1988. Along with any collllllel1ts, please include a statement of concurrence from your division/agency. If you have any questions, please give me a call at 404/347-7791. Thank you for prompt attention to this matter. I I ENFORCEl-lENI' I REl::ORD OF DEJ:ISICN REMEDIAL ALTERNATIVE SELECI'ICN I I Nl\T[CJIJAL STARO! AND OID1ICAL CORP. SITE SALISBURY, RCWIN COUNrY NJRIH CAROLINA I I PREPARED BY: US ENVIRCNflJI'AL PROI'El:'I'ICN AGFN:::Y I RillICN DJ AI'UINrA, GEDRGIA I I I I I I DRAFT I I I . I I I I I I I I I I I I I I I I I I I ,I I I DEUARATICN FOR 'IHE REX:ORD OF DEX:ISICN Site Name an;l. Lcx:ation National Starch and Cllemical Corp:iration SaliSbury, Rowan County, N:lrth Carolina Statement of Purrose This decision document represents the selected remedial action for this site developed in accordance with CERCIA, as amended by SARA, and to the extent practicable, the National contingency Plan. Description of the selected Remedy Gro\Jl1CMater Installation of a gro\Jl1CMater interception and extraction system down gradient of the trench disp:>sal area. The extracted groundwater will be discharged to the Salisbury 1.-0IW. The level and degree of pretreatment of the extracted groundwater will depend on the effluent limits set by the 1.-0IW. The range of pretreatment for the extracted groundwater includes airstripping, filtration through activated carbon filter, metal rerroval, and treatment through the company's existing lagoon system. Groundwater remediation will be performed until all contaminated water meets the cleanup goals specified in the attached SUmrary of Alternative Selection. Surface Water A rronitoring program will be establiShed for surface water/sediment. Additional soil samples will be collected in the vicinity of the eastern tributary and in the vicinity of a suspected storage area to detennine if another source, other than the trench area, is res.{X)nsible for the surface water/sediment contamination found. The surface water/sediment rronitoring will continue until the contamination identified during the RI has dissipated. Soil During the Remedial Design Stage, additional soil samples will be taken throughout the trench area. If the analysis confirms the results of the RI and indicates only residual contamination, then no further action will be taken on the soils. If, however, the analysis indicates extensive contamination, then in-situ soil flushing will be conducted in the trench area until the soil meets the cleanup goals specified in the attached SUl11T\ar'{ of Alternative Selection. Declaration Tile State of N:lrth Carolina has concurred on the selected remedy. This remedy is supi:orted by the Administrative Record. DRAFT I I I I I I I I I I I I I I I I I I "'Ille selected remedy is protective of human health and the environment, attains Federal and state requirements that are applicable or relevant and appropriate, and is cost-effective. This remedy satisfies the preference for treatrrent that reduces toxicity, nobility, or volume as a principle element. Finally it is detennined that this remedy utilizes permanent solutions and alternative treatment technologies to the maximum extent practicable" Greer c. Tidwell Regional i"drninistrator Date DRAFT I •• I I I I I I I I I I I I I I I I I NATICNAL STARCH AND CHEMIO'.L CORP, SITE SALISBURY, RCWAN COUNIT, MJRili Cl\ROLIN1\. PREPARED BY: U, S, ENVIRO:JMENrAL PROrEx::ITCN AGEN:Y REBICN DJ ATIAN:rA, GEXJRGIA DRAFT I I I I I I I I I I I I I I I I I TI\BLE OF CCM'ENI'S PAGE l • O INl'RODlx:TICN ................................................................ . 1. l Site Location and Description .......................................... . l. 2 Site History ........................................................... . 2 . 0 ENFORCEMENI' ANALYSIS . . . • . . . . . . . . . • . . • . . • . . . . . . . . . • . • • . • . . . • ................ . 3 . 0 CURRENI' SITE S'JA'IUS . . . . . • . . . . . . .......•..•.....••.....•..•................... 3 .1 Hydrogeologic Setting .................................................. . 3. 2 Site Contamination ..................................................... . 3. 3 Receptors .............................................................. . 4. 0 CLEANUP CRITERIA 4. l Groundwater Remediation ................................................ . 4. 2 Soil Remediation ....................................................... . 4.3 SUrface Water/Sediment Remediation ..................................... . 5.0 ALTERNATIVES EVALUATICN .................................................... . 5. l Groundwater Alternatives ............................................... . 5.2 Soil Alternatives ...................................................... . 6.0 REX:Cf,MENDED ALTERNATIVES ................................................... . 6.1 Description of Reconrnended Renedy ...................................... . 6.2 Operation and Maintenance .............................................. . 6.3 Cost of Reconmended Alternatives ....................................... . 6. 4 Schedule ............................................................... . 6.5 Future Actions ......................................................... . 6.6 Consistency with other Environmental Laws .............................. . 7. 0 CCl-T-1UNITY REIATICNS ........................................................ . DRAFT I I I I I I I I I I I I I I I I I I Lisr OF FIGURES Figure 1-Site Location Figure 2-Land Use Figure 3-Site Map Figure 4-Soil Sampling Locations Figure 5-SUrface Water/Sediment Sampling Locations Figure 6-Grolllldwater Sampling Locations LIST OF TABLES Table 1-soil Analytical Results Table 2-SUrface Water/Sediment Analytical Results Table 3-Groundwater Analytical Results Table 4-Groundwater Cleanup Goals Table 5-Soil Cleanup Goals Table 6-Groundwater Technologies Table 7-Groundwater Alternatives Table 8-soil Alternatives DRAFT I •• I I I I I I I I I I I ,I I I I I l . 0 lNI'RODUCI'ICN ENFORCEMENr RElXlRD OF DEx::ISICI\I Slff1ARY OF REMEDIAL ALTERNATIVE SELEl:TICI\I NATICNAL STARGI & GIEMICAL CORP. SITE SALISBURY, RCWIN COUNI'Y, NJRill CAROLINA The National Starch and Chemical Corp:>ration Site was proi:osed for inclusion on the National Priorities List (NPL) in April 1985 and reproi:osed in JlIDe 1988. The National Starch Site has been the subject of a Ranedial Investigation (RI) and Feasibility Study (FS) perfonned by the resi:onsible party, National Starch, under an Administrative Order by Consent dated December l, 1986. The RI rei:ort, which examines air, sediment, soil, surface water, and groundwater contamination at the site was completed on JlIDe 21, 1988. The FS, which develops and examines alternatives for remediation of the site, was issued in draft form to the µ.iblic on September 2, 1988. The Record of Decision has been prepared to sumnarize the remedial alternative selection process and to present the selected remedial alternative. 1. l SITE UXATICN AND DESCRIPI'ICN The National Starch and Chemical Corp:ir:ation Site is located in Rowan county, North carolina, approximately five miles south of the city of 5alisbury. (Figure 1). salisbury is located about 40 miles northeast of OJarlotte, North Carolina. According to 1986 statistics, Rowan CoW1ty covers 517 square miles with a i:oi:ulation of 104,678. The i:oPJlation of the city of Salisbury as of 1986, is 23,931. In general, land use of the areas intrediately adjacent to the site is a mixture · of residential and industrial developnents (Figure 2). The east side of the site, on the opi:osi te side of Cedar Springs Road, is an industrial park primarily consisting of warehousing type operations. A farm is adjacent to the south side of the site. Grants Creek forms the western boundary of the site. The Little Acres M::Jbile Home Subdivision adjoins the extrene southwestern corner of the site. A housing developnent, called Kings Forest, is adjacent to the north side of the site. The site actually forms the east, west, and sout11 boundaries of the developnent, such that the site is adjacent to the backyards of a number of homes in the developnent. A second developnent, Stonybrook, lies across Airp:>rt Road on the northern side of the site. The Rowan County airi:ort is located to the northeast of the site and the Rowan ColIDty Landfill to the north of the airp:>rt. The National Starch and Chemical Corp:>ration owns a 500 acre industrial site known as the Cedar Springs Road Plant. Hazardous waste was disi:osed of on an approximate five acre area of the site. The production facility is located in t11e extrene southeastern i:ortion of the site. (Figure 3). DRAFT -r--r--r- • --I --,-, r----- - ,-- • Cedar Springs Road Plant -----, -----, Figure I Vicinity Map Cedar Springs Road Plant NOTE: Taken from Work Plan for RI/FS (reference 1). (0 IN RElATION TO THE NATIONAL STARCH SITE /~ I ~M \"' r-~~ ,,....__,,. ? '.,\ ~ . \ ~ t, v "#'~ ~ -Q _r , ( \ . ' ,' (:Y ( -,. TIIAILER P/\RK I (I I. '1 MIL( k' ===~==-·=---:::a·==·===:iesa='=::::===":="~:::==~~= I~ o --k~ ~ ~ = ~nCT CONTOUR INTERVAL 10 FEET n·6 u@:E. d-, ----·-·--· ,, __ , __ ·-------~---- i -I WOODS 1 0 500 - -- - - . I 1 i PRETREATMENT HOLDING LAGOONS WOODS I • l I . .,, ll 0 .,, C, ll I CD 'o C z 0 > ll -< SCALE IN FEET \ · FIGURE NO. "2 5 3 I I I I I I I I I I I I I I I I I I I 1.2 Site History In Septenber 1968, Proctor Olemical Cornpilfly p.rrchased the 465-acre Ced.tr Springs Road property. Within the next year, Proctor Olemical was acquired by National Starch and operated as a separate subsidiary. Construction of the Cedar Springs Road plant began in 1970. On January 1, 1983, Proctor Olemical Compi311Y was dissolved and its operations merged with National Starch. The National Starch facility is primarily a rranufacturing plant for textile finishing chenicals and custom specialty chemicals. Production takes place on a batch basis and varies depending up:m denand. From 1971 to 1978, National Starch disposed of approximately 350,000 gallons of reaction vessel wash waters in trenches constructed in a 5-acre tract of land located behind the plant. The corrosive reaction vessel wash water consisted predominantly of salt brines and sulfuric acid solutions and contained trace quantities of solvents. The wastes were disposed of in several trenches approximately 200 to 300 feet long and 8 feet deep. The trenches ran both east to west and north to south. Liquid effluent from the plant production area flowed into the easterrmost pretreatment holding lagoon, which was unlined, and then was pJITIPed to an active trench in the trench area. Each trench was used until liquid no longer readily percolated into the ground. Afterwards the trench was backfilled and seeded, and a new trench was constructed. In 1976, eight rronitoring wells were installed around the site by National Starch to determine if the trenching operations were impacting grouru:lwater quality. Four of these rronitoring wells were installed adjacent to or wit11in the trench area. l'bnitoring revealed that shallow grouru:lwater imnediately within and adjacent to the trench area was contaminated. In June 1977, " sampling by the North Carolina Department of Natural and Economic Resources, Division of Environmental Management (DEM) verified National Starch's earlier conclusion that some of the rronitoring wells were contaminated. Based on analysis of samples taken at that time, DEM requested that National Starch cease onsite waste disposal activities. Since 1978, production plant process waters have been directed to a pretreatment facility located adjacent to and south of the production area. The waste stream goes through presettling and surface aeration in holding lagoons prior to controlled discharge to the Salisbury µJblicly owned treatment works (FOIW). The objectives of the site investigation were to: * Determine the nature and extent of grouru:lwater, surface water, soi 1, and sediment contamination on and adjacent to the site. * Determine the attentuative and adsorptive properties of the shallow saturated media. DRAFT I I I I I I I I I I I I I I I I I I I * Determine and describe on-site and off-site features that could affect the methods of containrrent or cleanup. * Determine the extent , if any, to which the site !X)Sed an inminent hazard to p.!blic health or the envirornnent. The purpose of the feasibility study was to develop and examine remedial alternatives for the site, and to screen these alternatives on the basis of protection of lllillBTl health and the envirornnent, cost-effectiveness and technical unplementability. In accordance with the comprehensive Environmental Res!X)nse, Compensation and Liability Act of 1980 (CERCIA), as amended by the SUperfllild Amendments and Reauthorization Act of 1986 (SARA), alternatives in which treatment would permanently and significantly reduce the volume, toxicity, or rrobility of the hazardous substances at the site were preferred over those alternatives not involving sueh treatment.• 2.0 ENFORCEMENT ANALYSIS The National Starch Site was pro!X)sed for inclusion to the NPL in April 1985 and EPA assumed lead res!X)nsibility for the site at that time. The current owner and operator, National Starch and Chemical Cor!X)ration agreed to perfonn the RI/FS. A notice letter was sent to National Starch on May 30, 1986. Negotiations for the RI/FS Consent Agreement were concluded with the signing of the document by both EPA and National s_tarch on Decenber 1, 1986. 3.0 CURRENI' SITE STATUS 3.1 HYDRCGffiLCGIC SEITIN3 The geologic framework of Rowan County forms two distinct aquifers. The first is a sllallow aquifer created by the saprolite. The second is a bedrock aquifer formed by the crystalline rocks. The two aquifers are interconnected with the clay-rich saprolite acting as a storage reservoir of ground wastes for t11e lower crystalline rocks. As a result, both t11e upper and lower aquifers can be considered unconfined despite the tendency of water levels within the crystalline rock aquifer to display artesian conditions. Water levels wit11in t11e deep aquifer tend to use to levels near the upper water table across t11e county, indicating a hydraulic connection between the two. Well yields are predictably low within the upper aquifer and tend to range between 3 to 5 gallons per minute. successful wells drilled withing the bedrock aquifer generally nave higher yields than those in the saprolite aquifer and average approximately 40 to 50 gallons per minute. Grants Creek delineates the westernrrost property line and flows in a northeasterly direction. Grants Creek flows approximately 12 miles beyond t11e National Starch property before reaching the Yadkin River. It joins t11e Yadkin River approximately 2 miles below the water supply intake for the City of sa1isbury. S11eet surface runoff, concentrated toward the middle of t11e former trench area, carries surficial drainage from the trench area. DRAFT I I I I I I I I I I I I I I I I I I I Three unnamed tributaries of Grants Creek traverse the National Starch site. The first stream passes within 200 yards of the front of the plant ( the eastern tributary), .i:aralleling Cedar Springs Road and leaves the property to the north. A small intermittent stream forms the southwestern site l::oundary (the southwestern tributary). The USGS quadrangle indicates a third SI1'all stream positioned in the northwest quadrant of the property (the northwest tributary). Grants Creek and the unnamed tributaries receive the surface water runoff from the former trench area. 3. 2 SITE CCNJ'AMINATICN The National Starch Site contains two main areas designated as the trench area and the wastewater lagoon area. Soi 1, groundwater, surface water and sediment samples have been collected in and arrnmd each area and analyzed. All samples liave been analyzed for Hazardous Substances List (HSL) volatiles, semivolatiles and metals. SOILS Soil composite samples were collected from five J::oreholes from the trench area. ( Figure 4) • Tile samples represent a comp::isite over o to 15 feet from each of the five J::oreholes BH-01 through BH-05. The analytical results for the composite l::orehole soil samples are shown in Table 1. Three discreet soil samples were collected from monitoring well l::oreholes as split spoon samples were being.taken continuously. These three soil samples were analyzed because they caused the field HNu meter to register a reading above background or 5pµn. The soil samples were collected from BH-N507, · EN-NS16 and BH-N508. The analytical results are shown in Table 1. ·During the scoping of the RI/FS, the waste disposal practices were believed to be fairly well docLRnented, and the soil sampling program was designed to determine the levels and types of residual contamination remaining in the soil. As shown in the table, the soil samples contain organic contamination. l\clditional soil samples will be collected during the remedial design to provide additional source characterization and to support the chosen remedy. SURFACE WATER/SEDIMENr The surface water and sediment sampling locations are shown on Figure 5. The results of the analyses are given in Table 2. In addition, EPA took additional surface water/sediment samples from an eastern tributary in response to nearby residents complaints. Both studies revealed high levels of contamination in t11e eastern tributary on site. Off-site samples were not , sri.iaeed found to be contaminated. 'I11e source of contamination in the surface water has not been identified; neit11er surface water run-off nor groundwater discharge has been ruled out as a potential source. Mdi.tional sampling will be conducted in this area during the remedial design to determine if another source exists in this part of tl1e National Starch property. DRAFT I 1· I I I I I I I I I I I I I I I I l' 0 0 z z " ► z u -w . ~ C 0 ~ ~ 0 ~ .. w :; 0 C ~ C C ~ • m z • C C 0 "' N ., N ,-. " z z l N TEST PIT ~ TEST PIT O Q #3 BH03 ~- OBH04 N0X 101L. STOCKPILE AREA 1 • 'NCENTRATION_UNITS IN ug/kg ORY WEIGHT -'!OT DETECTED 0ETECTION LIMIT APPROXIMATELY 10 · •. 'ilGHER THAN STATED DETECTION LIMIT FIGURE 5-1 rn INTERNATIONAL TECHNOLOGY CORPORATION C: a:._ ___________ __,.,..... __ _ 5-2 I I I I I I I I I I I I I I I I I I I 6Ho1 Parameters Methylene chloride Acetone 1,2-dichloroethane 2-But:anone Toluene Ethylbenzene Total xylenes !ID -Nondetectable 73N -NSD7 13 1,. _ N so8 11;,N-N5\(o Parameter Acetone 1,2-dichloroethane Toluene 1,2-dichloropropane Bis(2-chloroethyl)ether -, • I ,._.' ' .__ Concentration (ug/Kg dry 1<t) ND-9 ND-3300 ND-820 ND-18 ND-210 ND-48 ND-250 Concentration ( ug/Kg dry 1,t. ) 2100 -30998 ND-210 ND-620 ND-72 ND-1100 Detection Levels 5 7 7 15 7 7 7 Detection Levels 500 50 50 50 330 I I I I I I I I I I I I I I I I I I 0 z " z • .. "' 0 .. "' 0 .. z ~ -.. 0 " = -"' .. ;; .. 0 z -u ~ ~ 0 "' ~ ... :z: ::s ... .... < .;_ ,i u ~ ..; 0 "' ~ .. ~ m z • .. <= 0 Scale: l" = 2,000" SURFACE WATER SAMPLE ANALYTICAL DATA FOR 1,2-DICHLOROETHANE FIGURE 5-7 CONCENTRATION UNITS IN , ND -NOT DETECTED @ I:Nc":::<N.!'..,!ON.r TEC='NOLOGY COR?ORXI!ON I I I I I I I I I I I I I I I I I I I I .. " 0 .. " ~ -.. Q " :: -" ◄ ~ ... "' :z ... .... < a: ai " ~ .; 0 " ~ .. • .. z • .. C 0 SEDIMENT SAMPLE ANALYTICAL DATA FOR 1,2-DICHLOROETHANE FIGURE 5-10 @ IN7::'.RNATION.; TEC~NOLOGY COR!'OR.:...TION I I I I I I I I I I I m m R g g D 0 3 5 1• N ------ • I NATIONAL STARCH PROPERTY . LINE FIGURE 3 s-fl NATIONAL STARCH CEDAR SPRINGS ROAD SITE SAMPLING LOCATIONS JUNE 17, 1987 \. NS-\. NS-Sl . AIRPORT ROAD --------- EA~ PREPARED BY ENVIRONMENTAL SERVICES DIVISION HAZARDOUS WASTE SECTION rt 1000' 2000' SCA1£ APPROXIWA 1E I 'I ------------------- __,._ Vl I I-' I-' Methylene chloride SE1 SW1 SE2 8(7) SW2 SE3 SWl ..-,-. , . SE4 I " SES ,,, '-C -~--':": .~ -. 7, ~ :..·- SEt, SW6 SE10 -,,, 6) . SW10 SE 11 -SW11 SE12 SW12 ,;)...- Table -5-f. Surface Water/Sediment Organic Analytical Data Summary National Starch and Chemical Corporation RI/FS ' Date of Sampling -March 1987 1 , 2-d ichloro-ButylbenzKl-Bis(2-ethylhexyl)-Acetone ethane phthalate phthalatea · 44(7) 18(7) 1400(50) 65(7) 1800(440) 3200(440) 42(8) 1500(520) 3400(520) 33(9 l 50(6) 1000(410) 2700(410) 29(6) 116(6) 18( 7) asuspected of representing sampling error. SE -JJg/kg SW -JJg/1 ( ) repre_sents detection limit Di-n-butyl- phthalatea 449(430) I TABLE 3 I I ANALYTICAL DATA SUMMARY· WATER SAMPLES NATIONAL STARCH AND CHEMICAL CEDAR SPRINGS ROAD SITE ROWAN COUNTY, NORTH CAROLINA JUNE 17, 1987 I I I INORGANIC ELEMENT/COMPOUND BARIUM I STRONTIUM TITANIUM VANADIUM I ALUMINUM MANGANESE I CALCIUM MAGNESIUM I IRON SODIUM EXTRACTABLE ORGANIC COMPOUNDS I ETHYLHEXANOIC ACID I PHOSPHORIC ACID,TRIETHYL ESTER (DIMETHYLETHYL)PROPENAMIDE (DIMETHYLETHYL)PROPENAMIDE (2 ISOMERS) l UNIDENTIFIED COMPOUND IPURGEABLE ORGANIC COMPOUNDS 1,2-DICHLOROETHANE I NS-W3 NS-W4 CONTROL FENCE 06/17/87 06/17/87 1655 1730 UG/L UG/L 32 21 63 110 40 15 3100 230 200 160 MG/L MG/L 6.8 13 3.3 5.4 3.5 1.1 4. 2 13 UG/L UG/L UG/L 4JN 25JN 3JN lOOJ UG/L 4400J ·*********************••••••••k**"lrlr***********-lrlr***************** '**FOOTNOTES*** I I I J ESTIMATED VALUE PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED NS-W2 AIRPORT ROAD 06/17/87 1539 UG/L 46 310 200 MG/L 31 13 0.39 9.6 UG/L 20JN 50J UG/L NS-Wl MENSTER PROPERTY 06/17/87 1402 UG/L 47 280 210 MG/L 28 12 0.31 9.2 UG/L 20JN 40J UG/L TABLE 4 I I I I I ANALYTICAL DATA SUMMARY -SEDIMENT SAMPLES NATIONAL STARCH AND CHEMICAL CEDAR SPRINGS ROAD SITE ROWAN COUNTY, NORTH CAROLINA JUNE 17, 1987 I INORGANIC ELEMENT/COMPOUND BARIUM I CHROMIUM COPPER NICKEL I STRONTIUM TITANIUM VANADIUM YTTRIUM I ZING ALUMINUM MANGANESE I CALCIUM MAGNESIUM IRON I EXTRACTABLE ORGANIC COMPOUNDS HEXAGHLOROBUTADIENE I • BENZOIG ACID PETROLEUM PRODUCT 2 UNIDENTIFIED COMPOUNDS I BIPHENYL BIS(PHENYLMETHYL)BENZENEMETHANAMINE DIPHENYLETHANEDIONE I HEXADEGANOIG ACID OXYBISBENZJ!:NE PURGEABLE ORGANIC COMPOUNDS I 1,2-DIGHLOROETHANE NS-S3 NS-S4 CONTROL FENCE 06/17/87 06/17/87 1700 1735 MG/KG MG/KG 40 49 31 71 34 62 7.5 14 13 520 860 140 240 16 7.8 18 43 11000 22000 150 640 1300 1300 610 1000 22000 61000 UG/KG UG/KG 400J 520J N 3000J lOOJN 700JN 200JN lOOOJN 900JN 200JN UG/KG UG/KG 3400JN I**********~****************:************************************ ***FOOTNOTES*** ,I J ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL WAS ANALYZED FOR BUT NOT DETECTED I I ' 'i NS-S2 AIRPORT ROAD 06/17/87 1545 MG/KG 37 58 ' 30 17 590 140 6.8 22 10000 470 3900 2200 34000 UG/KG UG/KG NS-Sl MENSTER PROPERTY 06/17/87 1420 MG/KG 52 44 21 13 550 98 5.7 23 8500 490 2500 1900 25000 UG/KG UG/KG I •• I I I I I I I I I I I I I I I I I QUlNU,JATER During the renedial investigation, 23 rronitoring wells were installed; 17 shallow wells to sample water in the saprolite and six deep wells to sample water fran the bedrock aquifer. Locations of the wells are shown on Figure 6 and the sampling results are given in Table 3. Data collected from the grolllldwater wells indicated that the two water-bearing zones (shallow and deep) are interconnected. Three areas were targeted for grolllldwater investigation at this site: the wastewater treatment lagoons, the area just west of the plant between the plant and trench area (where soil fran wastewater lagoon retrofitting was stockpiled and aerated, releasing volatile organics to the atrrosphere) and the trench area. Tile data from t11e groundwater wells in the vicinity of the stockpile area and the wastewater treatment lagoons did not sllow any impact on grolllldwater. Tile grow1dwater in the trench area was fow1d to be lligllly contaminated. Contaminants, rrostly in the form of volatile and base neutral organics, are present in both the saprolite and bedrock aquifers. Tllis contamination, llowever, is still confined within the property bow1dary of National Starch. 3.3 REDPIDRS Based upon the data gathered during the RI and biological resources identified on and in the vicinity of the site, the potential hl.Illlan and environmental receptors include the following: * Nearby population t11at uses grolllldwater for drinking purposes. Tllese ·residents rely on groundwater wells for their water supply. * Nearby population t11at uses grow1dwater for domestic purposes other t11an drinking, such as showering, bathing, food preparation, clothes washing, lawn or garden watering, etc. * Recreational users of surface waters fran Grants Creek and other unnamed tributaries. * Hl.IlllanS consuming game animals (fish, small animals) t11at can be contaminated by i.nfestion of bioaccumulative contaminants. * ]lqUatic biota, faW1a, and flora in and arow1d the site t11at may be stressed. * Persons t11at come into direct dermal contact with contaminants present at tl1e site. * on site remediation workers t11at inhale elevated concentrations of volatiles during soil disturbance or t11at have direct dermal contact with contaminated soil. DRAFT -- / SE/SW·ll SE/SW· . '••·•. - -- - - - -- -- - - fxlsttnQ and Proposed Envtroninenlal Honttorln9 Points (Phase II Honttortng Points Underlined) -- --- -------------------Vl • .... 0, mu w-3 iA!!OIAL SIAICH I CBIKICIL COIP. II/PS GIODID mu DATA SUNIUII 1111 COOCIDlflllODi ID ug/1 m,pt cblorid• 111/ll, pH, ud ,pocitlc couductm,.J I L I I. I ~ I I I I l I I I I I I I I I I I I I I I I_ 1_;;·1 I I I ~ It I I I .I 1-I I I I I I I:: I I I .: I ~ I I. I :i I I -~ I I I I I I ~ I I I I I I I ! I I I i: I i: I! I ::; I '; I I ~ I I I I O I I ~ I I I I I I I .ti I I IEIEI IEl~l~l~I I I Ill l~I 1 •. 1 I I I l~I I 1-::111.~l~l'.::l.:!IEl-l_l.l~l.;l~I l~I l~I I l.~l~I I I Q I ';; I :: I -;:. I • I !. I --,· I = I 2 I ·~ I .~ I ~ I Q I : I :-I z I ·~ I u I I ~ I ·::; I I I --, I ;;; I :. I -; I -: I :; I -: I :; I :: I -:: I '=' I :; I --, 1·-;:. I : I .~ I -;:. I .:e I ~ I :. 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' .. ;iufqlJ0J0Lq)fJl l 1 l1I ! ! ! ! ! : : : ! l l : 0 t o I I I I I I I o I --------·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-· . ' . ' ' ' ' ' . . ' ' . ' ' . I O I O I I I -0 ' I I I O I - I -I I.IOjO.IOL•) : ! : : : ! : : : : ! : : : : -: 0 I O O I I I O O I I I O I I I --------·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-· ' . . ' . ' ' . . ' ' iUIOIOJOfq3fQl'li ! : : : : ·::::: : . ' . . ' ' . . ' . . ' . . ' ' . . --------0 -0 -0 -0 - I - • -0 -0 -I - ' -0 - • -0 -I -o -I - I -0 0 0 0 0 0 I I t O O I I •P!JO\ql LlaiA l ! ! l l 1 : l l i ! l I I O I O f O t O I O I --------·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-· I O I I O I I I I O I I I t I I I .. ·-·-· .. ' . ·-· ·-·-·-·-..... ,,_, '!UUJf : ! : ! ! : : ! : ,::,,, : : ~ : : : ! ; : ' ' . ' . . . ' . -' ' ' ' . ' ' ' --------·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-· ' . . ' . ' ' . . ' ' ' . J1q1a(l.lqi10Jo1q:>-Z)l\9 l l 1 1 : l 1 l ~ : ~ ! : l ~ l l l 0 0 0 I O O O • -I -0 I • ,-1 0 I --------·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-·-· t O • • 0 0 0 0 I O I O O O I ♦ • • o o o o •••-•-•-•-•Go.no , , au1q}aoJ01q,,oz·1: l l::: :-:-:~:~:i:~;-; l l ' ' ' . . . ' . . - . ~ ..... ' .... ' . ' . --------·-·-·-·-·-·-·-·-·-·-·~" ..... _._,_._,_. ' ' . . . . . . . . . ' . ' ' . ' ' ' ' . ' . . ' . . ' ' ' . . ' . ' ' ·~· ...... ·-· ...... ·-· ,,_, ·-·~· .... ·-·-· _________ :-:_:-:_:-:_:~:_:~:_:~:_:~:~:~:~:~: 5-19 ~ = . - Q --..... =-0 ~ --, = ---u ~ ~ =~= :a :: ... ~ ~-. : :: : ..; = : Q =- 0 ---.. ""'~ -;;;: : ~ .. ;~=-·· ~- ~ ~ . ~ ~ 0 ";i;~!:li. » 0 Q= = ~.., =: .-::: .::!:::a::a. Q ---. Cl .. _, .. ., __ ~-~ :;:· ~.: :: ~ Q ~ . - I I I I I I I I I I I I I I I I I I I l 4.0 CT,FANUP CRITERIA The extent of contamination was defined in Section 3.0. CUrrent Site Status. This section examines the relevance and appropriateness of water quality criteria urxier the circumstances of release of contaminants at this Site. Based upon criteria found to be relevant and appropriate, the minimum goals of remedial action at this site have been developed. 4. 1 rnOlJl'Ja-JATER · Rfr!EDIATICN In determining the degree of groundwater cleanup, section 12l(d) of the Superfund Amendments and Reauthorization Act of 1986 (SARA) requires tllat tile selected remedial actions establisll a level or standard of control which complies with all "applicable or relevant and appropriate requiranents · (ARARs)." Growldwater in the area is classified as Class IIA, a =rent source of drinking water, using the us EPA Groundwater Classifications Guidelines of December 1986. The value to• society of Class IIA groWldwater resources supports restoration of t11is contaminated groundwater to levels protective of human heal th and the environment. A 1988 survey of existing off-site water supply wells revealed a total of 1,539 llomes within a 3-mile radius of the site tllat are outside the limits of the city water lines. The closest well is located 2,200 feet northeast of the site. Future exposure to contaminated water is estimated based upon the possibility of a well being placed on the site and producing water containing the 11\3.Ximum levels of contaminants detected in rronitoring wells during the remedial investigation. Based upon groundwater classification and future exposure, remediation of the groundwater to reduce contaminants to levels protective of human health and the environment would be necessary. Growldwater cleanup goals given in Table 4 meet these requiranents. Because Section 121 of SARA requires consideration of potential as well as =rent groundwater use, the levels of contaminants in tile groundwater must be reduced to acceptable levels. Tlle conclusion of the above discussion is tllat a no-action alternative for growldwater would be out of compliance with Section 121 of SARA, which requires cleanup of contaminated groundwater to levels which are protective of human l1ealth and the environment. Classification of the groundwater and the potential future use of the growldwater indicates tllat present contaminant levels in the groundwater are not acceptable. Indicator chemicals were used to establish cleanup goals for groundwater. Indicator chemicals were selected based on the results of previous sampling activities and the =rent RI results. All indicator chemicals analyzed for in the RI were utilized in the Public Health Evaluation. DRAFT I I I I I I I I I I I I I I I I Compound Acetone Arsenic Benzene Bis (2-chloroethyl) ether Ollorofonn 1,2 Dichloroethane 1,1 Dichoroethylene Ethyl Benzene ~~thylene 01loride 1,1,2-Trichloroethane TrichLoroethylene Toluene Vinyl 01loride Xylene DRAF~i~ TABLE 4 GROUNr::WATER CLEANUP GCli\LS Maximum Cleanup source Observed Concentration S,QgJ, (ug/1) (ug/1) 89,000 3500 160 50 l 8 5 1 14,000 10 2 49 100 350,000 5 1 11 7 l 1500 680 l 8 5 11 0.6 10 5 6000 2,000 l 90 2 1 3800 440 1 ( l) National Primary Drinking Water Standards Maximum Contaminant Level (M:L) (2) Set as low as feasible based on analytical methOdology DRAFT I I I I I I I I I I I I I I I 4. 2 SOIL REMEOIATICN The Public Health Assessment determined that risks to hum3I1 health as a result of exp::isure to on-site contaminants via inhalation, ingestion and dermal contact are low under present use conditions at t11e Site. Contaminants remaining in the soil will , however, continue to leach into the groundwater. Based u.:on the data obtained during tlle RI, soil contamination is significantly lower that the contamination present in tlle groundwater. The contaminant levels in tlle soil are expected to decline as groundwater remediation continues. Reinediation of soils is not expected at this time. However, additional soil samples taken during the RD will eitller supp:,rt tlle decision for non-remediation of the soils at tlle site or suggest that some remediation of soils is appropriate. Soil cleanup goals have been established. The cleanup goals presented in Table 5 are estimates of contaminant concentrations in soil at tlle National Starch Site that would not result in future exceedances of NPI:WS in groundwater at tlle source area due to leaching of soil contaminants. DRAFT I I I I I I I I I I I I I I I I I I I Compound Acetone 1,2-Dichloroethane Benzene Ollorofonn Ethyl Benzene 'Ibluene Xylene TABLE 5 SOIL CLE'\NUP GOi\LS Maximum concentration Detected (ug/kg) 30,998 820 ND ND 48 620 250 Cleanup Goal (ugjkg) 103.0 1 5 78 8002 814 884 DRAFT I I I I I I I I I I I I I I I I I I I l 4. 3 SURFACE WATER/SEDIMEN!' REMEDIATICN Surface water and sediment contamination have been detected in streams on-site. 'llle source of this contamination has not been detennined. The contaminant levels are expected to decline as groundwater ranediation continues, if the groundwater in the trench area is the source of the contamination. Additional 'soil sampling in the vicinity of the eastern tributary to detennine if a source, other than the trench area, exists will be conducted. If another source is found, it will be ranediated. Thus, it was concluded that Elirect renediation of the surface water and sediment is not necessary. 5.0 ALTERNATIVF.S EVALUATICN The purfOse of renedial action at the National Starch Site is to mitigate and minimize contamination in the groundwater and in the soils, if needed, and to reduce p:itential risks to human health and the envirornnent. The primary cleanup objective, based on regulatory rEqUirements and the level of contamination found at the site, was to restore contaminated groundwater to levels protective of human health and the environment. Groundwater An initial screening of p:issible technologies was performed to identify those wt1ich best meet the criteria of Section 300. 68 of the National Contingency Plan (N:::P) Table 6. Following the initial screening of technologies, p:itential renedial action alternatives were identified and analyzed. These alternatives were further screened and those which best satisfied the cleanup objectives, while also being cost effective and tectmically feasible were developed further (Table 7). 5 . 1 GROUNl:xJATER ALTERNATIVF.S ALTERNATIVE 1: J:\O ACTICN This alternative includes no renedial action measures, but will include continued groundwater and surface water monitoring and the filing of a deed restriction identifying the areas of contamination. The deed restriction will prevent on-site develoµnent in the trench area and prevent on-site use of the groundwater. contamination, over time, will be reduced because of biodegradation, chemical transformation, soil attenuation of contaminants, and dilution. However, given rJ1e contaminant concentrations at the Site, the time rEqUired to significantly reduce contaminant levels is unrealistic. No action does not provide permanent source control. ALTERNATIVE 2: OFF-SITE DISPOSAL OF rncJlJNJ»lATER 'ID RCRA TSD FACILITY '!11is alternative includes the extraction of contaminated groundwater, t11e collection of groundwater at a central on-site location, and the off-site_ disp:isal of the collected groundwater by bulk tank til.lllkS to a RCRA Treatment, Storage and Disp:isal (TSD) facility. -- Ground Water •nera I Response --- Action Remedial Technology 10 action None •nstitutional Access restr.lctlons· ,.1ct ions - - Table 5-2. NaB1 sR an.Jlanic ... po,·-···-- Control Technologies tor Ground Water Contamination - Prbcess Option Not appl I cable Oeed restrictions Effectiveness Does not ensure achievement of remedial action objectives Effect I veness depends on con- tinued future Implementation; does not reduce contamination lmplementabi I ity N/A; will lil<.ely require long- term man i tor Ing Legat requirements ---- Cost Status Low O&M ( I ong-Retained t erm monitoring) Neg I lg Ible Retained Alternative water supply New community wel I Effective In preventing use of contaminated ground water; no contamination reduction Conventional dril I Ing method requires local permit Moderate capital,-Dismlsst low O&M Containment -'"" C, ::0 :l> I i I CEE I 3635C 06/2B/B6 F3 Mani tor Ing Cap Vertical barriers Ground water man I tor Ing Clay and sol I Multi layered cap Slurry wall Grout curtain Useful tor documenting con- ditions; does not mitigate contamination Effective against vertical leaching al contaminants Into ground wateri sus- ceptible to cracking Effective; least susceptible to cracking Not feasible because ground water Is contaminated within the fractured bedrock Not effective because ol fractured bedrock Easily implemented; serves to monitor contamination, not mitigate contamination Easily lmplementedi restriction on future land use; does not address major risks at site Easily implementedi restriction on future land use Olff lcult to verity continuity ol slurry or backf 11 I Oif f icult to verify continuity of wall; must tie into impervious zone Low capital, low O&M Retaine Lo.,. capital, Reta int lo.,. maintenance Moderate capital, Retain low maintenance High capital. Oismi· low O!M High capital. lo.,. O&M Dismi -----·--- . Ground Water. General Response Act Ion Containment (con•i nued) Remedial Technology Horizontal barriers Col lectlon/treat-Extraction ment/discharge CEE13635C 06/28/BL F} Subsurface drains Physical/chemical Treatment • Process Option Sheet pl le Grout Injection Extraction wel Is/ deep wel I system Interceptor trenches Neutral lzatlon Precipitation/ flocculation Ion exchange Air stripping ----Table 5-2. (Continued) Effectiveness Not effective because ot fractured bedrock Not effective because ot fractured bedrock Effectiveness can be verlf led by monitoring; performance is sensitive to design; collected water must be treated or disposed of Effective for downgradlent fracture.flow Intercept Ion ---- lmplementabil ity Oif f icult to key to bedrock; excavation required; I imi ted 50 feet Continuity Is dlttlcult to verity Easily implemented; continued O&M required no to Very difficult to implement; requires deep trenching through rock Effective and reliable for Readily Implemented stab I I lzlng pH of ground water prior to treatment Effective and rel I able; Readily implemented requires sludge disposal Not an effective process when deal Ing with sal lne water conditions that exist at site Effective for removal of volatl le organics; not appl I- cable to lnorganics Ground water would require pre- treatment before Implementing this option Easily implemented; existing aeration basins on-site may be app I icable -... - Cost Statui High capital, Olsmis low O&M High capital, Oismis lo• O&M Moderate c~pl tal ,· Retai1 moderate O&M High capital, low O&M Oismi Low capital, Retai moderate O&M Moderate capital, Reta moderate O&M High capital, high O&M Dlsa Moderate capital, Rat moderate O&M -- Ground Water ..:neral Response Action --- Remedial Technology :ol lection/treor-Physlcal/chemlcal .,ent /discharge (continued) C, =ti ~ -,-, -; CEE IJ635C 06/28/88 F 3 treatment (cont I nued) Biological treatment In situ treatment -- Process Option Steam stripping E11aporatlon Reverse osmosis Fl I tr at ion Carbon adsorption Biological degradation Treatment in existing lagoons Biodegradatlon - Effect h,eness Effective for removal of volatile organics; not appli- cable to inorganics Effective if properly designed Effective In concentrating the salts In wastewater; may be considered as a pretreatment step Effective in reducing sus- pended sol ids prior to further treatment Not effective for Inorganic contaminants; not as effective for water soluble compounds Effective under good process control conditions Effective In air stripping volatl le organics may be eff iclent bloreactors Not effective in fractured bedrock and sal lne water conditions ------- tmplementabi I lty Cost Status Because at high chloride, Moderate capital, Olsmlsse content equipme~t may require high O&M alloy materials tor construction Would require bench-scale testing and continued O&M , Readily implemented; membranes may foul If solubility limits are exceeded Readily Implemented Readily implemented Readily implemented using conventional equipment Readily implemented, wi I I require testing High capita I, high O&M High capital, moderate O&M Low capital, moderate O&M High capital, high O&M Low capital, moderate O&M Low capital, moderate O&M Not easl ly implemented; requires High capital, bench-scale testing; would moderate O&M require numerous wells tor injection Dismiss ◄ 01 smi ss Retal01 Rett1i n Retai, Olsm r-•1 Ground Water General Response Actfon L Remedial Technology Col lectlon/treot-On-site discharge ment/dlscharge (continued) CfE13635C 06/28/88 I 3 oft-site discharge Process Option Chemical treatment Local stream RCRA facl I lty Sewer Llne/POTW Table 5-2. (Continued) Effectiveness Not effective In fractured bedrock Effective and rel lob le Effective and rel iabl8, but requires transportation Effective and rel I able -- lmplementabi I lty Not easily implemented, would require numerous wel Is for .1 nject Ion Not eas i I y implementedj NPDES permit required Permits required Readily implemented through eMistlng se•er I ine to POTW If pretreatment standards are met -- Cost High capital, high O&M High capital, high O&M High capital, low O&M Low capital, moderate O!M - Stat Dismi Dlsml Retai Retai I I I I I I I I I I I I I I I I I I I Alternative 1 No Action Long-term CM !IOl1itoring Alternative 2 CM recovery off-site disposal Alternative 3 CM Recovery Direct Discharge to PCllW Alternative 4 CM Recovery Pre-Treatment/Air Stripping Discharge to PCllW Alternative 5 CM Recovery Pre-Treatment/Lagoon System Discharge to PCllW TABLE 7 GR:lllN™ATER ALTERNATIVES REOOCE'S M/T/V <n;'l' Minor Reductions in Contaminant $119,000 volume will require an extended time period. Provides permanent and significant reductions in M/T/V Provides permanent and Significant reductions in M/T/V Provides permanent and significant reductions in M/T/V Provides permanent and significant reductions in M/T/V $103,377,000 $391,000 $6,765,000 $739,000- $3,337,000 DRAFT I I I I I I I I I I I I I I I I I I I Groundwater will be extracted at a rate of 50,000 gallons per day and will be placed in an aoove ground tank for no n-ore than 90 days. The tanks wi 11 store the extracted groundwater until it is transferred to bulk tank trucks and transported to a RCRA TSD facility. Continued groundwater n-onitoring will be perfonned after rsroval of the contaminated groundwater to verify the effectiveness of the groundwater extraction operation. This alternative would meet groundwater remedial action objectives by rsroving the contaminated groundwater but will not destroy the contaminants. Thus, it is not considered a permanent remedy. ALTERNATIVE 3: GRQUN[WATER EXl'RACITCN AND DI;OiARGE DIRECTLY 'IO POIW This alternative involves extracting the contaminated groundwater and discharging it to the Salisbury Kf1W for treatment. The Kf1W is a 5 million gallon per day biological treatment plant. Bench-scale testing may be required by the POIW to determine if the POIW is capable of treating this contaminated groundwater. National Starch currently discharges plant wastewater effluent to a sewer line connected to the POIW. The extracted groundwater would be discharged into the existing sewer line. The discharge to the Salisbury Kf1W will have to be negotiated with t11e City of Salisbury. Groundwater will be extracted for an estimated ten years, until the groundwater at the site meets the ARARs established for this site. ALTERNATIVE 4: GROUNlNIATER EXTRACTICN. PRE-TREA'IMENI' BY AIR Sl'RIPPIN3/METhLS REMJVAL. DISCHARGE 'IO roIW In this alternative, the groundwater will be extracted, treated to meet acceptable effluent limits of the POIW, once negotiated, then discharged to the 1-0IW. The treatrrent process will include pi adjustment, precipitation, flocculation, and clarification for metals removal; and. air stripping with fume incineration followed by biotreatirent to remove the HSL organics, and to reduce COD and BOD. The process would be designed to meet all pretreatment requirements for producing a final effluent suitable for discharge to t11e Salisbury 1-0IW. Groundwater will be extracted for an estimated ten years, until the groundwater at the site meets the ARARs established for this site. DRAFT I I I I I I I I I I I I I I I I I I I ALTERNATIVE 5: GRCJUNa-lATER EXTRACTICN. PRE-TRUfil1ENI' IN EXISTIN, LAGCXN SYSTEM. DISCHARGE 'ID PQIW This alternative includes the extraction of groundwater, pretreatment as required to allow the groundwater to be combined with the current plant effluent and treated in the existing lagoons for discharge to the Salisbury FOIW. The level of pretreatment required will depend on the effluent limits set by the P01W. T11e pretreatment syst6Tl nay include metals renoval by lime precipitation, stripping of volatile organics or treatment with activated carbon. Groundwater will be extracted for an estinated ten years, until the groundwater at the site meets the ARARs established for this site. SOILS An initial screening of possible technologies was performed to identify those c;J1ich best meet the criteria of Section 300.68 of the N:P (Table 8). 5.2 SOIL ALTERNATIVES ALTERNATIVE l: l'D-ACTICN Tllis alteniative would allow for the naturally occurring leaching or cleaning of soil. A deed restriction would be filed identifying the areas of contamination. Contamination will be-reduced overtime because of bioctegradation, volatilization and soil attenuation of contaminants. Additional soil sampling will be conducted to verify that the entire trench area soils contain only residual contamination and does not contain any areas of "high" contamination. .. The no-action alternative does not provide any additional mitigation to the soil contamination beyond the natural processes. ALTERNATIVE 2: SITE CAPPIN:; T11is alten1ative involves the capping of all past trench disposal areas at the site. This alternative will reduce the rate of migration of contaminants into t11e groundwater from the unsaturated soils that underlie the trench areas. A clay cap will be constructed from soil excavated on site. The cap construction will consist of: * Native soil to bring the area to t11e appropriate grade and establish a foundation for the final cover. * A 2-foot layer of clay, corrq:,acted *Topsoil to support vegetation *Revegetation *Drainage !>walls and ditches to prevent run-on and prorrote runoff from .the cap. •me trench area is approxinately 150 ,ooo square feet. DRAFT Ground Water General Response Action Remedial Technology No action None !nstitutional Access restrictions actions Containment CEE148658 07/27/88 F? Cap Vertical barriers C, :::0 ::x::,- 1 i --t Table 5-2. National Starch and Chemlcal Corporation RI/FS Screening Control Technologies for Sol I Contamination Process Option Not applicable Deed restrictions Clay and soi I Multi layered cap Slurry wal I Grout curtain Effectiveness N/A Effective in I imitlng use of trench area Effective against vertical leaching of contaminants into ground water; sus- ceptible to cracking Effective; least susceptible to cracking Not feasible because ground water Is contaminated within the fractured bedrock Not effective because of fractured bedrock lmplementabi I ity NIA; w i 11 1 lkel y require long- term monitoring Legal requirements Easily implemented; restriction on future land use Easily implemented; restriction on future land use Oif f icult to verify continuity of slurry or backf ii I Diff lcult to verify continuity of ,,,:,11; must tie into impervious zone Cost Low O&M ( long- term monitoring) Neg I igible Low capital, low maintenance Stat Retai Retai Retai Moderate capital, Reta ii low maintenance High capital, low O&.M High capital, low O&.M Dismi'. Oismh. ----'iii Ground Water General Response Act ion Containment (continued) iiiii -- Remedial Technology Surface controls Excavation/ Removal Treatment Act i_on CEE148658 07/27/68 F2 .;....~-, CJ :::0 :x::,. I I -I r ' 1tment -- - Process Option Sheet pi le Diversion/grading/ sol I stabi I izatlon Excavation Soil washing Sol I farming Solidification/ fixation ---Table 5-2. (Continued) Effectiveness Not effective because of fractured bedrock May divert run-on; soi I stab I I izatlon may decrease Inf I ltratlon Effective for removal of contaminants in sol I, but requires disposal Water can be effective since volatiles of concern are highly soluble. Requires excavation and the treatment of water. Clayey soi I can hinder removal efficiencies. Poor track record; may not treat to desired levels Effectiveness is dependent on ambient temperatures. precipitation and wind. May not conform to air release regulations for volatl le compounds. Not an effective method for organic compounds. l!!!!!!!!!I l!!!!!!!I I!!!!! I!!!!! I!!!!! l!!!!!!!!9 em lmplementabi I ity Cost Status Diff !cult to key to bedrock; no High capital, Dismiss excavation· required; I imited to 50 feet Eas1·1y implemented Read I ly implemented with conventional construction equipment Implemented using commercially avai I able mining and chemical processing equipment Easily implemented. Requires excavation of contaminated soi Is and spredding over large area with surface water control. Readily implemented by excavating and mixing soi I with the additive low 04N Low capital, low O&M High capital, low 0.!M High capital, Moderate 0.!M Retaine, Dismissc High capita I, Oismisst high O&M Moderate capital, Oismisst low 0.!M -- Sol I General Response Action C, :::0 ~ il --4 Excavation/ disposal action ;EE I 48658 07/21/BB F2 --- Remedial Technology In situ treatment Thermal treatment Off-site disposal --llll!!IJ ~ l!!!!a l!!!!!L .. .. • • Process Option Subsurface bloreclamatlon Sol I flushing Soil venting· Rotary ki In incinerator RCRA taci I ity On-Site landf i I I Table 5-2. (Continued) E f feet I veness lmplementabi I ity Effectiveness is dependent Readily implemented by on soll uniformity (I.e. grain horizontal Irrigation. May size, porosity, Ph, etc.) require bench-scale testing; poor track record for this type of geologic setting Effectiveness Is dependent on Not readily Implemented in soil uniformity and abi I lty to clayey soi Is would require capture the leachate numerous injection/extraction welts Not an effective method for Not readily implemented in tight clayey soi IS clayey sol ls, would require pressurized air injection Effectiveness is dependent on operation of incinerator Effective and reliable, but requires transportation Effectiveness is dependent .·design·, construction and continued inspection Clayey soi Is may require longer residence time thereby increas- ing O&M. Avai labi I ity of incinerators is questionable. Permits required Difficult to obtain regulatory agency permit approval !!!!!I ~ Cost l!!!!!!!I -- Status Moderate capital, Dismiss. moderate O&M Moderate capital, Oismlsst moderate 04M Moderate capita I, Di smi sst moderate O&M High capital, IOw O&M, High capital, low 04M High capital Moderate O&M Reta i nee Retaineu Oismissu D I I I I I I I I I I I I I I I I I Alternative 1 No ActlOO Natural Soil Flushing Soil Sampling Alternative 2 site Capping Alternative 3 Soil Excavat1cn On-Site Incineration Alternative 4 Soil Excavat1cn Off-Site Dispoeal Alternative 5 In-S1t:lll Soil Flushing / TABLE 8 SOIL ALTERNATIVES Reduces M/T/V Reductions in Ca!taminant volume overtime Reducticn in Caitaminant 1-bbility. Provides permanent and significant reductions in M/T/V Reduction in Caitaminant M/T/V en-site. Reducticn in Ca!taminant M/T/V Cost $44,000 $216,200 $26,000,000 $27,000,000 DRAFT I I I I I I I I I I I I I I I I I I I Because of its low penneability ( <10-7 an;second) capping will significantly reduce infiltration and therefore, reduce the rate of transi:ort of additional contaminants into the groundwater. This alternative, however, does not reduce the soil contamination present at the site. ALTERNATIVE 3: EXCAVATICN AND IN:INERATICN This alternative involves on-site incineration of excavated soils from the trench area. :rrie approximate volume of soils to be remediated is 125,000 cubic yards. The soil can be incinerated at rates up to 20 tons/year. Emissions and effluents will be treated, rronitored, and controlled to levels within current regulatory limits. Incinerated material will be analyzed prior to replacenent in disi:osal areas to ensure that remediation and ARAR levels have been achieved. After replacing the incinerated soils, the disi:osal areas will be given topsoil and revegetated. ALTERNATIVE 4: EXCAVATICN AND OFF-SITE DISKlSAL In this alternative, 125,000 cubic yards of contaminated soil in the trench area would be excavated and transi:orte;I to a secure landfill for disµ:,sal. The 125 ,ooo cubic yards only addresses the soil in the unsaturated zone; the contaminated soil in the saturated zone wou.J.d not be excavated. ALTERNATIVE 5: SOIL FLUSHIN, In this alternative, water would be applied to the contaminated soils in-situ and collected at well i:oints for treatrrent. The flushing would continue until the soil in the trench area rreets the soil ARAR.s identified in Section 4. Injection and extraction wells would be placed to optimize rrobilization and subsequent collection of contaminants. 6. 0 REX::CM1ENDED ALTERNATIVES 6.1 DESCRIPTICN OF Rf£fM")OOF'D R™EDY TJ1e recOlllllE!Ilded alternative for remediation of groundwater is Alternative 3 which includes the extraction of groundwater and discharge to the POIW. The reconmended alternative for remediation of soil is Alternative l which is no-action but contains additional sarrpling requirenents. These reconmended alternatives rreet the requirenents of The National Oil and Hazardous SUbstances Contingency Plan (N:::P) , 40 CFR 300. 68 ( j) , and the Superfund Amendments and Reauthorization Act of 1986 (SARA). This reconmended remedy permanently and significantly reduces the volume of hazardous substances · in the groundwater, and reduces the volume of contaminants in the soil. DRAFT D I E I I I I I I I I I I 6 • 2 OPERATICN AND l'1"JNI'EN'\N: After the renedy is completed, no long term operation and maintenance will be required other than rronitoring requirements. 6 . 3 cosr OF RED:M1ENPill ALTERNATIVES Capital costs for groundwater remediation is $101,000 with system operating and maintenance cost at $43,000 per year, which includes sampling and analysis. The total present worth of the groundwater remediation is $391,000. The total present worth of the soil alternative is $44,000, which includes a one-time fee of $1,000 for the deed restriction and $43,000 for the additional soil sampling needed to back-up the chosen alternative. The total present worth cost of this remedy, including l:xlth soil and groundwater remediation is $434,000. 6 . 4 5'.:HEI)lJLE Tl1e planned schedule for remedial activities at the National Starch Site will be governed by the signing of the consent Decree and the finalization of the site on the NPL, but tentatively is as follows: September 1988-Approve Record of Decision January 1989-Sign consent Decree. February 1989-Begin Remedial Design July 1989-Complete Remedial Design August 1989-Begin M::>bilization 6. 5 FUl'lJRE ACTICNS Groundwater, surface water, and soil rronitoring will be required throughout the remedial activities to assure the effectiveness of the cleanup. 6. 6 CCNSISTEN::Y WI'IH QIHER ElWIRCNMENW, LAWS Remedial actions performed under CERCIA must comply with all applicable Federal and State regulations. All alternatives considered for the National Starch site were evaluated on the basis of the degree to which they complied with these regulations. The reconrnended alternatives were found to meet or exceed all applicable enviromnental laws, as discussed below: * Resource conservation and Recovery Act The Resource Conservation and Recovery Act is not applicable. * Clean Water Act Contamination was detected in surface water and sediment samples on-site. The groundwater remediation and the additional soil sampling will delete the source of any future contamination. DRAFT I I I I I I I I I I I I I * Flood plain Management Executive Order 11988 DRAFT 'Ille site does not lie within a flood plain and thus is not subject to the requirements of E.O. 11988. * Department of Transp:irtation Transp:irt of hazardous substances is regulated by the Department of Transportation (oor). The alternative chosen does not involve transportation of hazardous waste. * Occupational Safety and Health i'dministration A health and safety plan will be developed during renedial design will be followed during field activities to assure that regulations of the Occupational Safety and Health Administration (OSHA) are followed. * Safe Drinking.Water Act Maximum Contaminant Levels (M:::Ls) established under the Safe Drinking Water Act were found to be relevant and appropriate to remedial action at the National Starch Site. The cleanup goals for groundwater were established in Section 4. * National Pollutant Discharge Elimination System Treated groundwater will be discharged to the local KJlW, therefore, a National Pollutant Discharge Elimination System pennit is not applicable. * Endangered Species Act The reconmended renedial alternative is protective of species listed as endangered or threatened under the Endangered Species Act. Requirements of the Interagency Section 7 consultation Process, 50 CFR, Part 402, will be met. The Department of the Interior, Fish and Wildlife service will be consulted during renedial design to assure that any endangered or threatened species are not adversely i.Jrpacted by implementation of this reiredy. * Ambient Air Quality Standards 'Il1e groundwater treatment systems will be designed and rronitored to assure that air emissions meet all State and Federal standards. * State Drinking water Standar• . . \, ..,__ ._,_ Maximum contaminaJ ,' Carolina regulatio, ;;\· Drinking Water Act, · .•. 7 . 0 CCJ,MUNITY RELATICNS .1lhi1ed by tJ,e State of N::>rth •.l from tllOse of the .Federal Safe .:B Iret. Fact sheets were transmitted in February 1987, to interested.parties, residents near the Site, media and state, local and federal officials before t11e RI ,,;ork be5on o.+ ..J-1.-,_, S;-/e_. E I I I I I I \I I I I I I I I I I I An information repository was established at the Rowan Col.ilty Library in Salisbury, ~rth Carolina. A J:'c]blic meeting was held on April 2, 1987, at the Civic Center in Salisbury to discuss the RI/FS activities and to introduce SUperfund to the comnuni ty. Another public nee-ting was held on M:lrch 31, 1988, at the Ci vie Center in Salisbury to discuss the results of the RI. The final J:'c]blic meeting was held on September 14, 1988, at the Civic Center in Salisbury to discuss the alternatives from the Feasibility Study and describe EPA's preferred remedial alternative. The three-week public CO!Tille!1t period ended on septenber 23, 1988. A Responsiveness Surm1ary has been prepared to surrrnarize comrunity concerns and EPA'q cormu.mity relations activities. ORI\FT ..