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HomeMy WebLinkAboutNCD991278540_20100201_Weyerhaeuser Company_FRBCERCLA SAP QAPP_Monitoring Report OU-3 January 2010-OCRI I I I I I I ·1 I I I I I I I I I I ••••• AMT ....-.,'-. •ENVIRONMENT• ENERGY• ENGINEERING Monitoring Report Operable Unit No. 3 (OU-3) -Former Chlorine Plant Area Domtar Paper Company, LLC, Martin County, North Carolina January 2010 '.i 'e r.·~ .. -~ll\:' CREATING BALANCE'" • I I I I I I I I I I I •• I I .......• RMT A •ENVIRONMENT• ENERGY• ENGlr-JEERING Monitoring Report Operable Unit No. 3 (OU-3) • Former Chlorine Plant Area Domtar Paper Company, LLC, Martin County, North Carolina January 2010 Michael B. Parker, P.E. Senior Client Service Manager RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area /:\ WPGI '/, \J'J711/0-05 J 7 / ',0-l',00001 ,,woo5 J 7 J 0-1-00 J. IXJCX Heather H. Smith Environmental Specialist 010/0 RAil'. Inc. All Righi., Re.wrved 30 Patewood Drive, Suite 100 • Greenville, SC 29615-3535 • {864) 281-0030 • (864) 281-0288 FAX• www.rmtinc.com C R E A T I N G B A L A N C E'" ly '----Dom tar It all bq~ins with ]Ktpcr.' Domtar Paper Company, I.LC Plymouth Mill PO Box 747 Highway 11+9 North Plymouth, NC 27962 T 257.-793·8111 WWW domlai-.com February I, 20 I 0 Mr. Randy Bryant Remedial Project Manager ~:~= ~n,:.~~ SUPERFUND SECTION Certified Mail Returned Receipt Requested United States Environmental Protection Agency. Region 4 Atlanta Federal Center 6 I Forsyth Street, S. W. Atlanta, GA 30303-3104 Subject: Domtar Paper Company, LLC, Plymouth, N.C. Operable Unit No. 3 (OU-3); Former Chlorine Plant Annual Monitoring Report Dear Mr. 13ryant: Enclosed please !ind 3 copies of the Fonner Chlorine Plant Monitoring Report. The purpose of this monitoring report is to present the results of the Former Chlorine Plant Area surface cap containment syste111 inspection and groundwater monitoring events conducted during the week of Decc111ber I, 2009. A copy of the report has also been provided to the North Carolina Department of Environment and Natural Resources. Please contact 111e i r you have questions or co111ments concerning the docu111cnt. Sincerely, iq~ Bill MotTis E;:nvironmental Engineer Domtar Ply111outh Mill xc: Nile Testcrn1,1ii · M:1rcel Sylvestre Diane Hardison I I I I I I I I I I I I I I I I I I I Table of Contents Cert i Ii cat ion .............................................................................................................. . . ... II I. Introduction ....................................................................................................................................... I I.I l.2 Background .............................................................................. . Purpose ........................ . 2. Methods ............................................................................................................. . 3. Results and Discussion ....... . 3.1 3.2 3.3 Surface Cap Containment System Monitoring Groundwater Monitoring ... Recommendations .. List of Tables Table I Table 2 Table 3 List of Figures Figure 1 Figure 2 List of Appendices Historical Groundwakr Elevations ... Historical Mercury Analyses of Groundwater Samples Historical Groundwater Monitoring Field Parnmctcrs ................... . Sample Locations ............ . Water Table Surface December I, 2009 ............................ . Appendix A Analytical Data Appendix l3 Field Notes Appendix C Photographic Log RMT North Carolina. Inc. I Dom/or Paper Company. LLC Monitoring Ncport OU-3 -Former Chlorine />fa111 Area /_-\ J! PG I 'I. ll'JT"·lll/-l/5 ! 7 / I/J41 /J/Jll//2:Rm!r!5 J 7 I I)./ ./HJ I. DOC.I" . ............... I ................. I . ..................... 3 ··········· 5 ... 5 ········ 5 ........ 7 10 ... 11 ......... 14 . ........... 4 CJ Ja111w1y 20 I 0 I I I I ' I I I I I I I I I I I I I I I Certification The hydrogeology work for the Domtar Paper Company, LLC (Domtar), Plymouth Mill in Martin County, North Carolina, was performed by an RMT, Inc. consulting hydrogeologist in support of RMT North Carolina, Inc. RM[ North Carolina, Inc. \ Domtar Paper Company, LLC Monitoring Report OU-3 -F'ormer Chlorine Plant Area /:\ Wl'(Wf, il'f/100-05 I 7 J\O-IIOOOOZIR0005 J 7 I 0-1-/JO 1.lJOCX ii January 2010 I I I I I I I I I I I I I I I I I I I 1.1 Background Section 1 Introduction Opcrahlc Unit No. 3 (OU-3), also referred to as the Fonner Chlorine Plant Arca, is located at the Domtar !'aper Company, LLC (Domtar), Plymouth Mill in Martin County, North Carolina. The Record or Decision (ROD) for this area was issued in September 2003. The negotiated Consent Decree [Civil Action 4:03-CV-90(1-1)(3)] established remedial design (RD) and remedial action (RA) activities for this area. The RA activities were completed during 2006, with the Pre-Final RA inspection accepted as the Final RA inspection under United Stales Environmental Protection Agency (USEPA) approval in August 2006. The Interim RA report was completed and approved by USEPA on September 29, 2006. The Pe1.for111a11ce Sta11dards Venjicatio11 Pla11 (PSVP)fl1r f"ormer Chlori11e I'la111 Arca (RMT, 2005) 'describes procedures !'or the inspection, monitoring, and reporting activities required for the Former Chlorine Plant Area. The PSVP was required by the Statement or Work (SOW) for the Former Chlorine Plant Arca in response lo the USEPA Consent Order Docket No. 98-10-C issued by USEPA on March 24, 1998. The performance monitoring activities for the Formcr_Chlorinc Plant J\rca arc being conducted according to the PSVP and as such have been divided into two lcchnical tasks. The objective or each task is listed below: ■ Task I. Surface Cap Containment System l\1onitoring ■ A surface cap containmcnl syslcm reduces the infiltration of surface water in the vicinity or tht.: Former Chlorine Plant Arca. The objective of the surface cap containment system is to assure that the cover system components arc maintained, including concrete, asphalt, and stormwater system components. The surface cap containment system is inspected on a semiannual basis for surface crncks, holes, depressions, or olhcr signs of surface integrity degradation. Construction of the surface cap containment system was completed in August 2006. Task 2. Groun(hYater !\t1onitoring The objective of the groundwater monitoring program is to assess the effectiveness of the remedy to protect groundwater quality by reducing the migration of mercury from the Former Chlorine Plant J\rca. Institutional controls arc applied to the Former Chlorine Plant J\rca in order to prevent future use of the groundwater as a potable water source. 1.2 Purpose The purpose of this monitoring report is to present the results of the Pormcr Chlorine Plant Arca surface cap containment system inspection (Task I) and groundwater monitoring (Task 2) events conducted during the week or December I, 2009. This report presents surface cap inspection results, and analytical RMT Nor//1 C(lm/inu. Inc. I /Jomtar Paper Company. LLC Moniroring Report OU-3 -Former Clilorine Flont Arct1 I: 111'/'(/ I'/. IP Jll (/1!, l!.1 / 1 I './I.JIii( !IIO]IR/11!/J 5 I 7 ! /!,/./!/II./)( )C.\" .la111wry 20 I 0 I I I I I I I I I I I I I I I I I I I data from groundwater sampling, pre-and post-construction water table elevations, and provides recommendations for modifications in the sampling plan. Water table elevations and mercury concentrations lcir the semiannual sampling events (November 2006, May 2007, November 2007, May 2008 and December 2008) and the subsequent annual monitoring event in December 2009 are compared lo baseline sampling results obtained in February 2006. According to the PSVP, semiannual monitoring was lo he conducted through Fall 2008, followed by annual monitoring until the 5-ycar review. RMT Norrh Carolina, Inc. I Domtar Paper Company, U,C Moniloring Heport OU-3 -Fonner Clilori11e /1/(III( Area I:\ W/'(i l'J. \f' J T111fJ.f! 51711 fJ.f' l!U//f/J:/W/H/517 / I!./-f!II I. OOC r 2 .lw11w,y 20 I 0 I I I I I I I I I I I I I I I I I I I Section 2 Methods /\ baseline sampling event was conducted by RMT North Carolina, Inc. (RMT) during the week of January 22, 2006. This sampling event served as the baseline for the short and long-term performance monitoring or the Former Chlorine Plant J\rca. Remedial activities (target soil excavation, barrier wall installation, and surface capping) took place between March and August 2006. Semiannual sampling events were initiated in November 2006. The initial sampling event served to evaluate any immediate changes in groundwater !low or groundwater mercury concentration levels due to the remedial construction activities as well as a basis for evaluating remedy effectiveness. Subsequent semiannual sampling events look place in May 2007, November 2007, May 2008 and December 2008, followed by the annual monitoring in December 2009. In addition, two new monitoring wells were installed at the Former Chlorine Plant /\rca in November 2007. Groundwater monitoring well locations arc depicted on Figure I. Groundwater samples w1.:rc collected using low !low purge methods in which a minimum or three well volumes of groundwater were removed before sample collection. Groundwater samples were analyzed hy Columbia /\nalylical Services in Jacksonville, Florida lor mercury using USEP/\ Method 245.l. The laboralnry analytical data reports for December 2009 arc included in /\ppcnclix /\ and !he licld notes arc included in Appendix 13. Purge water was contained, sampled, and properly discharged into the on-site was\cwater lrcalmcnl plant (WWTI'). RMT North C(lro/ina, Inc. I Domtar /'oper Company, LLC Monitoring Report OU-3 -Former Ch/or/111: Pion! Area I:\ U 'f'G I"/. 1/'J {)/)II.I/ 517 / ll!-I' f}/)1/l}J; /WI)/} 5 171 /}./ ./)I) I. {J( ,ex 3 .lw11uu)' 20 I 0 I I I I I I I I I I I I I I I I I I I METAL BULKHEAD/ SEA WAl PRoouc TION FA CIUTy @CP-15-1 0 LEGEND 0MW-2-2 CP-U-1 .. APPROXIMATE LOCATION OF FORMER EQUIPMENT AND SUBSURFACE UTILITIES EXISTING EQUIPMENT BURIED CONCRETE SLABS GROUNDWATER MONITORING WELL LOCATION @El CP-11-2 Ii) CP-12-1 CP-12-2 60' SCALE: 1 "= 60' NOTES I. BASE MAP PRODUCED BY PHOTOGRAMMETRIC DAT A SERVICES, INC. 2. DETAILS OF MAP DETERMINED FROM FIGURE 5 OF HLA !1992), WEYERHAEUSER 1951 ENGINEERING DRAWINGS OF THE FORMER CHLORINE PLANT, AND FIELD MEASUREMENTS TAKEN BY WEYERHAEUSER STAFF. DATA TRANSFERRED FROM FIGURE 8 OF HLA !1992). 120' PROJECT: FORMER CHLORINE PLANT AREA DOMTAR PAPER COMPANY MARTIN COUNTY, NORTH CAROLINA SHEET TITLE: SAMPLE LOCATIONS i.:DR=AWN=:..::.BY:.:• ___ .:.DOM=1SCALE1 CHECKED BY1 TAT AS NOTED i.;APPR::..:..:.::0:..:YE=:Dc..::BY:..:•----I0ATE0 PRINTEOa OATEt JANUARY 20IO PRO.I. NO. FLE NO. wto-00-~TI.OH)Olo.dQn FIGURE 1 PalrMood Plaza Ono, Suit9 ,00 30 PaJewood £live Gn,snvile, s.c. 29615-JSJS Phone: 8M-281-0030 Fax: 864-281-0288 I I I I I I 0 I I I I I I I I I Section 3 Results and Discussion This section presents the results or the baseline and scmiannunl surface cap and groundwater monitoring activities. Where applicable, results are compared to data from previous monitoring activities. 3.1 Surface Cap Containment System Monitoring The surface cap containment system is inspected during each semiannual monitoring sampling event as described in the PSYP. The surface cap containment system was inspected for surface cracks, holes, depressions, and other signs of surface integrity degradation. During a site visit conducted by USEPA on November 18, 2009, it was noted that two monitoring wells CP -04-1 and CP-04-3 were rusted and locks nel'.dcd to be replaced. Four monitoring wells covers were replaced and new well lncks were installed on all wells during the annual inspection in December 2009. Photographs taken of the surfocc cap containment system, including the repaired monitoring wells during the December 2009 inspection, arc included in Appendix C. No additional maintenance of the surface cap containment system is recommended at this time. 3.2 Groundwater Monitoring The water table elevations measured during the baseline sampling event in January 2006 and the subsequent semiannual monitoring events arc summarized in Tab!L: I. J\ water t.Jhle map for the December 2009 sampling event is presented in Figure 2. In January 2006, prior to installation of the Waterloo® barrier \Vall, there was a small ridge in the water table surface extending from a mounded area at monitoring well Cl'-10-1 (western end or the Former Chlorine Plant Arca) to a second, lesser mounded area at monitoring well CP-08-1 (northeastern end or the Former Chlorine Pbnt J\rL:a). This ridge was still present during the December 2009 sampling event. On the northern end of this ridge, groundwater flows northward to the Roanoke River. South of the ridge, groundwater appears to flow south and then to the northeast towards monitoring well CP-11-1 where it ultimately discharges into the Roanoke River. The water table is at its lowest elevation at well CP-11-1. The installation of the \Vaterloo® barrier wall had a minor impact on the overall water table surface at the site from November to December 2008. In November 2006, the water level within the confines or the barrier wall (CP-06-1) was 5.89 feet above mean sea level (msl), which is 1.3 to 2.89 feet higher than the water elevations measured in wells surrounding the barrier. In May 2008, the water level within the barrier perimeter was slightly lower with an elevation ol·4.98 feet msl, 0.25 to 2.05 feet higher than the water elevations measured in wells directly surrounding the barrier. In December 2008, the water level within the baiTicr perimeter increased to 5.27 reel ms!, 0.13 to 1.3 feet higher than thl: water elevations RMT North Carolina. Inc. I Dom/ar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine F!a!lt A reo l:l ll'l'Gl'l.1PJ111//J./JJ 17 J\O./ll)U{)021Rff/!()5/ 7 /1/4./HI/ .DO\.\' 5 .lmwa1:11 20 I() I I I I I I D I I I I I I I I I I I measured in wells directly surrounding the harrier. In December 2009, the water level at CP-06-1 (located inside tlie Waterloo® barrier) decreased slightly from 5.27 feet ms! in 2008 to 4.90 feet ms!, with water elevations in wells directly surrounding the harrier ranging from 3.86 feet msl (Cl'-05-1) to 5.09 feet msl (CP 08-1). The water level at CP-06-1 has continued to slightly fluctuate since installation of the barrier. Outside of the barrier perimeter, the water table conligurations in December 2009 are similar to the baseline water table map (January 2006). Table 2 presents the mercury analytical results for groundwater samples collected from the designated wells as outlined in the Perfurn11111ce Standards Verification Plan (RMT 2005). Field parameters measured include pH, specific conductance (SC), dissolved oxygen (DO), turbidity, and temperature arc presented in Table 3. Mercury results were below the method detection limits for most of the groundwater samples collected. The North Carolina groundwater quality standard for mercury is 0.00 I 05 mg/L ( 15 NC/\C 02L.0202, revised April 2005). Mercury concentrations detected during the baseline and semiannual sampling events are summarized as follows: ■ Baseline l\'Jonitoring Event (January 2006)-The concentrations of mercury in monitoring wells CP-02-1, CP-04-1, CP-05-1, and CP-08-1 were above the 2L Standard for mercury in the January 2006 monitoring event. ■ Semiannual J\'Jonitoring Event (November 2006)-Thc conccntra1ions of mercury in monitoring wells CP-01-2, CP-04-1, CP-05-I, and MW-113 were above the 2L Standard for mercury in the November 2007 monitoring event. ■ Semiannual l\.1onitoring Event (]\'lay 2007) -The concentrations or mercury in monitoring wcl!s Cl'-01-2, CP-04-1, CP-05-1, CP-08-1, and MW-I B were above the 2L Standard for mercury in the May 2007 monitoring event. ■ Semiannual l\.1onitoring Event (November 2007) -The concentrations of mercury in nwnitorillg wells CP-01-2, CP-0 l-3R, CP-04-1, CP-05-1, CP-08-1, and CP-08-3 were above the 2L Standard for mercury in the November 2007 monitoring event ■ Semiannual l\.1onitoring Event (!\'lay 2008) -The concentrations of mercury in monitoring wc!ls CP-04-1, CP-05-1, CP-08-1, and MW-113 were above the 2L Standard li>r mercury in the May 2008 monitoring event ■ Semiannual l\.'Jonitoring Event (Dec cm her 2008) -The concentrations of mercury in monitoring wells Cl'-04-1, Cl'-05-I, MW-113, and Cl'-01-2 were above the 2 L Standard for mercury in the December monitoring event ■ Annual i\1onitoring Event (December 2009) -The concentrations of mercury in 1nonitoring wells CP-04-1, CP-05-1, MW-18, CP-08-1, and CP-01-2 were above the 2L Standard for mercury in the December monitoring event. While the concentrations in some wells n.:main slightly above the 2L standard ror mercury, detected mercury concentrations have continued to decline in two of the monitoring wells (CP-04-1 and CP-05-1) from November 2007 to December 2009 monitoring event. Mercury concentrations appear to be !luctuating at RMT North Carolina, Inc. I Domtar !'aper Company. I.LC Mo11itori11g Report OU-3 -Former Chlorine Plant Areo f: 1 fl "PC I' 1, I {'}n!J/1. 1!5 17Jll!4'{/(/f)(J2'.fW{///5171 /)./. /1/) I.[)( x ·x 6 .lanumy 20/0 I I I 0 D I I I I I I I I I I I MW-I B, with detected concentrations above the 2L standard in May 2007 through December 2009, ·compared to a detected concentratioi1 slightly below the 2L standard in November 2007. The mercury concentrations in shallow well CP-08-1 have fluctuated slightly above the North Carolina 2L groundwater standard from May 2007 to May 2008 and again in December 2009 and the detectable mercury concentration foll below the 2L standard in December 2008. Mercury was detected in well CP-01-2 at concentrations above the 2L standard from November 2007 through November 2008, December 2008, and December 2009, compared to non-detect in May 2008. Mercu1y concentrations were above the 2L standard in November 2007 at replacement well Ci'-Ol-3R and CP-08-3 and may have been affected by well construction activities conducted just prior to sampling. Mercury was not detected at wells Cl'-Ol-3R and CP-08-3 from May 2008 through December 2009. The mercury concentrations in deeper well CP-08-2 fluctuated from the baseline sampling event to December 2009 sampling event at concentrations either below the 2L Standard or non-detect. Mercury was detected at a concentration below the 2L Standard in well CP-03-3 in December 2008; however, in December 2009, mercury was non-detect at this location. Nine wells had low levels or detected mercury concentrations below the 2L standards during December 2009 sampling event. Four of the nine wells had detected concentrations for the first time during this monitoring program; however, all concentrations were qualified by the analytical laboratory with a J flag, for estimated concentration between the method reporting limit and method detection limit. The monitoring results continue to show that lhe majority of the wells had no detectable mercury or low concentrations below the ,2L standard. Specifically during December 2009, 16 of the 30 area wells had no detectable concentrations or mercury (consistent with the upgradient wells). Of the five wells that contained mercury above the 2L Standard, three (MW-I 13, CP-01-2, and CP-08-1) arc located north to northeast or the barrier perimeter and two (Cl'-04-1 and CP-05°1) arc located south of the barrier perimeter. At all !Jvc locations, the measured concentrations of mercury were generally consistent ovcr'thc six reported rounds with slight fluctuations on a well by well basis and no increase in the area of impacted groundwater. 3.3 Recommendations The Five-Year Review ortlie performance monitoring and remedy effectiveness evaluation will be prepared by USEPJ\ in 2010. Based on the data trends from the performance monitoring, it is recommended that the annual groundwater monitoring program be refined lo focus on continued monitoring of the following wells on an annual basis: Cl'-04-1, Cl'-05-1, MW-113, and CP-01-2. These wells have had detected mercury concentrations above the 2L standards in the previous two sampling events. In addition, the following wells should be monitored every other year for the next five years in order to continue to ensure remedy effectiveness: CP-06-1, CP-09-1, CP-14-1, CP-07-1, and CP-08-1. The remaining wells should continue to have annual monitoring or water levels. The surface cap containment system should continue to he inspected annually for surface cracks, holes, depressions, or other signs of surface integrity dcgradc.Jtion. RMT North C{/ro/ino, Inc. I Domtar Paper Compony, !JC Monitoring Report OU-3 -Former Chlorine 1~ta11t 1/rea I:\ WJ>G l'I.' f'J r,1)(/./Jj 1711 /1-1:/J//(//!J,RIJ//1!5 / 7111,/ · f!/1 I .DO!.\" 7 ./an11a,y 20 I 0 I I I I I I I I I I I I I I I D E The Five-Year Review of the performance monitoring and remedy effectiveness evaluation will be prepared by USEPA in 2010. Based on the data trends from the performance monitoring, ii is recommended that the annual groundwater monitoring program be refined to focus on continued monitoring of the following wells on an annual basis: CP-04-1, CP-05-1, MW-113, and CP-01-2. These wells have had detected mercury concentrations above the 2L standards in the previous two sampling events. In addition, the following wells should he monitored every other year (beginning in 2011) for the next five years in order to continue to ensure remedy effectiveness: CP-06-1, Cl'-09-1, CP-14-1, Cl'-07-1, and CP-08-1. Well pairs at locations MW-02, CP-10, and CP-11 have had no detections of mercury in at least the past two sampling events and could be decommissioned prior to the 2010 annual monitoring event. The remaining wells should continue to have annual monitoring of water levels until decommissioned. The surface cap containment system should continue to be inspected annually for surface cracks, holes, depressions, or other signs or surface integrity degradation. RMT Norrh Carolina, Inc. I Domtar Pot)er Company, LLC Monitoring Report OU-3 -Former Clilorine /-'!a11t Area f:\Wf'Gl'/,il'J !1/I/J,05/ 7 / ll/.f'fHl//f/}!//Vl//1517 /04-IJII/.DOC\" 8 Jm111my 20/(J I I I I I I I I I I I I I I I I I I I METAL BULKHEAD/ SEA WALL 0CP-13-I 3.64 PRooucr10N F Ac1urr \ \ ' 0 ' CP-12-1 '-@_3.47 LEGEND 0MW-2 3.65 2.s , APPROXIMATE LOCATION OF FORMER EQUIPMENT AND SUBSURFACE UTILITIES EXISTING EQUIPMENT BURIED CONCRETE SLABS GROUNDWATER MONITORING WELL LOCATION WITH GROUNDWATER ELEVATION GROUNDWATER ELEVATION CONTOUR. DASHED WHERE INFERRED. CONTOUR INTERVAL AS SHOWN. '-',cP-12-2 , .. 3 .s 60' SCALE: 1•= 60' NOTES I. BASE MAP PRODUCED BY PHOTOGRAMMETRIC DATA SERVICES, INC. 2. DETAILS OF MAP DETERMINED FROM FIGURE 5 OF HLA (1992>, WEYERHAEUSER 1951 ENGINEERING DRAWINGS OF THE FORMER CHLORINE PLANT, AND FIELD MEASUREMENTS TAKEN BY WEYERHAEUSER STAFF. DATA TRANSFERRED FROM FIGURE 8 OF HLA !1992). 120' PROJECT: FORMER CHLORINE PLANT AREA DOMTAR PAPER COMPANY MARTIN COUNTY, NORTH CAROLINA SHEET TITLE: WATER TABLE SURFACE DECEMBER 1, 2009 DRAWN 8Y1 DOM SCALE, J'C'-HE-Ott:_O_BY-,---,T,cA,,lT AS NOTED APPROVED BYt DATED PRINTEDt OAT[1 JAHUARY 20K) PR0J. NO. Fil.[ N(), WTG-00.5ITLOl-00lo.GQn FIGURE 2 Po/rN,Ood Plaza 0oo, Suits 100 30Patuwoodlkfre GnJsnVW, S.C. 29615-3535 Phone: 864-281-(XJJ() Fax: 864-281-0288 - --- - ----------Table I Historical Groundwater Ele\'alions ~~&~< ~!~•;i;•,}!,c_ro"" 1-· !'/iiT9;i/1 ~•9§NDwATE•\I\ ,.;~orJ;r~;fQ.,,.1, [\c~qli:ioj~:EI~~~ ~~''J:l',!'! -~-ti,to~ '\'GRO~-~c59_u_ ;.hc':}•w t{:-},ftj ::fi'°_EL~Y~:£!~ "/$• ;'°;:_rEf'b-~ ~•:.JLfYt,Tl_~'i-~ t.,-3'wA_1:ER}-,,0 !~...:.__~LE~TJO:-.'_:-•:,_~· ~-j/t~:,'-'.fEi½;;fJ. •• V . 'l': ,.W~J,_E~ ~-:J_!i_f_\',UIO, ~~X T ~-<£,LEV_~TIO. -''>~~•Jft(..s."' • ~; ,/½f (r~--.. ,,,,_ .,~Ht~,i~~ ~tJ.f;; cr.:~i1.1½'·l ~ ·':'.,·'ft,(<i~1)~-'-? ~ 5':li(it~tl~~ ~~11r1:1:11'i"~~ if.ii-\fw~:1 [~,, &"'1rr,1 ·-~'.%+frrt •. :, ~--.. ~ -l"-•, ~ ~•v, "'-'='"• ,..<;?-;:,,-VM•;~---...... ~,:.,;,"'7 •, _-, _.i_.,,t,_,..,~ •·'/ • '4•.:Li,,' ,.. .. ~ -~-'¥"' · • ,J. \,.l's,. _ ;'">'.-_-':,,-,,-r·• ,:Jfi_;:i.'lcJ(,,~'r,L~ -~~s:r: ·-" .t'tti05fJ0/07•;,,J.; ~-,:.r05fil)/()7',;,_:,,'.'"", :,0,11"1106111,::· ... :: ?I-~·i·lli06iO? • .i:;,,,5i;, ,_,J.o;11l/lll!';p,";1 .. 1.1 ~~11,01:ils<,:2 -.,,:,.if1::i01iOS:§ ·., f"; !Zitll/09· ,_"l-,·~1tlllo 1\1\\'.0\B 8.32 4.45 3.S7 3.i4 4.53 05 3.97 3.6 4.72 3.67 4.65 cp.01.2 7.9.1 4.6S cp.01 •. , S.22 NI-,! CP.OJ.3R S.14 NM cr.02.1 7.88 5. ! 5 cr.02.2 7.85 4.90 cp.03.1 7.9-l 4.2i cr.o:i.2 S.09 5, I 0 (p.03.; 8.17 6.0S CP.04-1 7.50 '.IS cr.0.1.2 7.57 4.60 (p.0.1._; 7.46 4.57 cr.os.1 7.75 4_.F) CP-05·2 773 4.77 CP.06-l 7.50 2.02 cr.06.2 7 54 2.25 cr.01.1 8.\6 5.12 cr.01.2 8.11 5.12 cr.03.1 7_51) 2.71 cr.os.2 7.57 -l.58 er.as .. , 8.10 NM (p.Q(). 1 7.4S 5.06 cp.00.2 7.46 4.55 CP·IO·l 7.46 0.93 CP-10·2 7 49 4.48 CP•! 1•! 7.62 6.41 CP·l 1·2 7 69 4.80 CP•l2·1 8 01 5.00 CP-12·2 8.10 5. !6 CP·l3-l ! 1 56 8.51 cr.14.1 11.54 8'9 cr.1s.1 11.54 Nl\1 l\1W•02 "' 4.7 I l\J\V.02•' i. 7-l 4.49 '" .\kas,ircd 111 kc1 \kasu1"d m f~~I ~bo,~ site d~rnm NM <','01 m~a,urc-d. ""II nol acccssabk fl.\ f /" Norrh (",1n,/ma. t,,,-_ I / lo111111r l'apcr ("01111•,111.1· l.f.C .\fomrr,,·mg lfr1,,,n ()l.'.3 · h•mwr Chlorm<' /'/a/II An.'<! r ·n r,,, 1;1•.n ""•"Jin,,,.,,,.,,,_: mmJl'i"<·m,1.,1,, :us 4.79 NM NM NM ~M 2.73 5.42 2.95 5.06 3.67 3.69 2.99 5.14 2.09 5.77 3.72 4.07 2.97 4.7S 2,89 4.27 3.26 4.65 2.% 4.88 5.4S 2.1JO 5.21J 3.14 3.04 5.3 l 2.1J1J 5.25 -US 2.36 2.99 4.71 NM !'JM 2.42 5 92 2.91 4.98 6.53 1.95 3.01 5.02 1.2 l 6.39 2.89 4.99 3.01 5.42 2.9-l 5.39 3.05 8.65 3 05 8,63 :--::-.1 NM 2.70 4.77 ~ 25 4.67 3.14 4.50 J.43 4.45 3.4S 4.05 3.8S NM NM NM NM NM NM NM NM 5JO 2.84 5.03 3.11 4.44 3.70 2.46 4.95 2,93 5.07 2.81 4.9! 2.97 2.79 4.78 3.07 4.74 3.1 l 4.29 3.56 4.25 4.15 3.79 2.52 5.42 2.73 5.21 2.95 4.92 3.17 4.77 3.32 4.5' 3.56 2.40 5.30 2.3 7 5.53 2.64 5.17 3.00 3.43 3.60 3.90 3.67 3.33 3.37 4.13 2.79 -U2 3.15 4.4:1 3.14 4.00 3.57 3, 19 4.35 3.11 4.32 3. 14 3.9--l 3.52 3.10 -U6 3.-19 4.21 3.54 3.89 3.86 2.85 4.54 3. ]() 4.57 3. 16 4,14 3.51J .J.60 2.52 .1.1JS 2.23 5.27 2.60 4.90 4.40 2.75 4,71J 2.44 5. JO 2.32 5.22 2.85 4_()() 3.17 4.85 3.31 4.51 3.65 2.86 4.1J4 3.17 4.86 3.25 4.52 3.59 5.23 2.S6 4.73 2.20 5.39 2.50 5.09 2.86 -l.40 3. l 7 4.27 3.30 3.96 3.61 NM 4.17 3.93 5.95 2. I 5 4.20 3.90 1.56 5 20 2.28 5.35 2.13 5.22 2.26 2.48 4,4 l 3.05 4.42 3.04 3.89 3.57 5.51 I 09 6.37 0.89 6.57 0.85 6.61 2.47 4.35 3.14 4.40 3.09 3.8 ! 3.68 1.23 6.29 1.33 5.75 1.87 5.55 2.07 2.70 4.59 3.10 4.45 3.24 4.20 3.-19 2 59 4.72 3.29 4.79 3.22 4.54 3.47 2.71 4.98 3.12 4.88 3.22 4.63 3.47 2.91 8.33 3 23 8.40 3.16 7.92 3 64 2.91 8.30 '.24 8.39 3.15 7 .90 3.64 Nl\1 NM Nlvl NM NM NM NM 2.64 4.59 2.82 3.76 3.65 4.02 3.39 3.07 4.25 3.-l9 4.13 3.61 3.SS 3.86 January 20/0 - I Table 2 llistorirnl :\1ercury ,\naly\cs of Groundwater S:rn1ples I ~-(:-~~~ ~~ rl · , ,.D,\'I ~: , (m~L) -, I Alluvi:11 aquifrr (water lahlc) 01/24/06 0.001 ! 1/07/06 $i:ttl1t#t-~0.0027~h@!' 05/30/07 F~~o:on1s~ MW-OIB 11/07/07 0.001 I 05/13108 ~~o:001zrt!'~~~ 12/05/08 ~tlIRo:0015,m""~i§t 12/01/09 ~t).00206~~IB; 01125/06 ~o.1,012r.!1-'t~1 I l/08/06 0.0005 05/31/07 <0,0002 C1'·02-l 11/08/07 IJ.0002 05/13/08 <0.0005 12/05108 <0.0005 U 12/02/09 0.0001 I .I I 01/24106 <0.0002 11107/06 <0.0002 05/30/07 <0.0002 CP-03-1 11/07107 <0,0002 05/13/08 <0.0005 12/05/08 <0.0005 U 12/01/09 <0.0005 U 01/25/06 :>:,..~0.0681~~" ! 1/08/06 ~~~11:1184:&t~liM¾-m\' 05/31/07 1ffl.'lMl~~o:oos9~t•!'J I Cl'-0•l-1 I 1/08/07 i'1Ktsi2.l!~o:014sru1~M 05/13/08 ~'.'fillf,i'>;HIJ'.0089l"Et.'tili1i-'\W 12/05/08 fu;".µjj.::.•)\filito:ou1sM!tt~tr.M 12/02/0() [!;;•1\ff1.1!}E~0:110114!ifi:t1/M'.~~ · 01/25/06 ~ .. }.'!',:.~~~'\ 0.0 IO I ~"'~; 11/08/06 \1tJVfil£,_~,1:Wi0Jl27¥i~~W 05/31/07 (';.'~"'J~0.0137!~.;;;ll.J CP-05-1 11/08/07 l'\1:~'°J¼.f,SZY.0.069t~'¾li~"'i~ 05/13/08 l:'fii•~._,~1~0.U'.?:4f,1;;.~1\!1? 12/05/08 1t.~&:n:11019tt.:.Jw_sr;r:;tJ;? I !2/02/()9 ntt~ffi(}t1'!lltl.!lf)757M'!:k?f\!£,!;:,wt! 01/25/06 <0.0002 11107/06 <0.0002 05/0J/99 <0.(1002 CP-07-1 l 1/08/07 <0.(1002 05/13/08 <U.0005 12/05/08 <0.0005 U )2/01/09 <0.0005 lJ 01/25/06 '.~J;tr!"<:':31! 0.00 14 'M" .,"&l:J·.!~ l 1/07/06 0.0004 I 05/30/07 f..'?,iittT*Yf o.oo 15 7,~J,1,1;,~ CP-08-! 11/08/07 ;.~&,::'(r,;:,..1wo:no 12 ~'.:'.ff'%m;;u 05/13/08 -m~'ltl!tl?ikt !Ult 114 :l}"ft'iE.i~Ji'ffi.1: !2/05/08 0.0007 12/01/09 u;:;pJiJi,Wti:> o:oo 1521-i't-3Ml"i\\ml:J I 01/24/06 U.0007 11/08/06 <0.0002 05/31/07 <0.0002 , CP-09-1 I 1/08/07 <0.0002 I 05/13/08 <0.0005 12/05/08 <0.0005 U 12/02/09 (l.00011 .I 0ln4/06 <0.0002 11/08/06 <0.0002 05/31/07 <0.0002 I. CP-10-1 I 1/08/07 <0.0002 05/13/08 <0.0005 12/05/08 <0.0005 U 12/02109 <0.0005 U 01/24/06 <0.0002 I 11107/06 <0.0002 05/30/07 <0.0002 CP-1 !-I 11/07/07 <0.0002 05/U/08 <0.0005 12/05/08 <0.0005 U I 12101/09 <0.0005 U I RMT ,\I,,, ti, r"1 r,/ino. Jnr. I Domrw /'"I'",-c,,,,,,,miy, /J,C Moniw, ing R11mr1 I 01.i-3 -Form,•, 01/ori11(' l'/11111 Area I HJ/~,<'/ 1/'H,/1> 1/\/IJ l!HN~Hl}•/"'}\17//H i,U_\/.1 Jam1<u;r }()/// I I I I I I I I I I I I I I. I I I I Table 2 lfotorical Mercury Analyses of Groundwater Samples Bu~·"-~-~ ~·~ , • ,}l~,-·. -. ' , ', ' ' ' {mi:/1.1 · • 01/24/06 <0.0002 11/07/06 <0.0002 05/J0/07 <0.0002 CP.]2-1 11/07/07 <0.0002 05/13/08 <0.0005 12/05/08 <0,0005 U 12/01/09 <0.0005 U 01/25/06 <0,0002 11/08/06 <0.0002 05/3 !/07 <0,0002 CP-13-1 11/08107 <0.0002 05/13/08 <0.0005 12/05/08 <0.0005 U 12/02/09 0.000 I .I 01/25/06 <0.0002 11/08/0(1 <U.0002 05/31/07 <0.0002 CP-14-1 11/08/07 <0.0002 05/1 3/08 <0.0005 12/05/08 <0,0005 U !2/02109 0.00008 .J CP-!5-1 01/25/06 <0.0002 01/25/06 <0.0002 11/07/06 <0.0002 05/30/07 <0.0002 MW-02 11/07/07 <0.0002 05/!3/08 <0.0005 12/05/08 <0.0005 U 12/01/09 <0.0005 U ,\llu,·i:11 :u•nifcr (-20 fl l'll·,·.1fion) 01/2,1/06 <0.0002 11/07/06 i\lS¼ll;&.1ru-4ilfO.IJ051)•~l>0ilSirdMt 05/30/07 i;~ie-.m.t\io.oo38Z-~&i',,.;;,-.,~ Cl'-01-2 I 1/08/07 fa'.iffe,~S>llF!'kO:oo 11~~».ti;;w 05/13/08 <0.0005 12/05/08 ~SJ:til'~l0.0022~':SL~ 12/02/09 ~~J«s.!Jl' 0: 00 I 5 .WJY;:,.½Sf~ 01/25/06 <0.0002 l 1/08/06 <0.0002 05/31/07 <0,0002 Cl'-02-2 11/08/07 <0.0002 05/13/08 <0.0005 12105/08 <0.0005 U !2/02/09 0.00009 .I 01/24/06 <0,0002 11/07106 0.0004 05/30/07 <0.0002 Cl'-03-2 11/07/07 <0.0002 05/13/08 <0.0005 12/05108 <0.0005 U !2/01/09 <0.0005 U 01/25/06 0.0006 11/08/06 <0,0002 05/31107 <0.0002 Cl'-(M-2 1 l/08107 0.(HJ07 05/13108 <0,0005 12105/08 <0.0005 U 12/02109 <0.0005 lJ 01/25/06 <0_(){)02 11108/06 <0.0002 05/31107 <0.0002 Cl'-05-2 1 ]/08107 <0.0002 05/1 3108 <0.0005 12/05108 <0.0()05 ! J 12/02/09 0.00018 .I 01/25106 0.0002 ] !107106 0.0003 05/30/07 0.0002 Cl'-07-2 11108107 0.IJ00J 05/i3108 <0.0005 12/05/08 <0.0005 lJ 12/01/09 0.00008 .I RMT.\'011/i Caro/i11a. Inc. I Domwr /'nper Com1inm·, 1.1.C .\fom/m·i"g /frpo1·1 OU-3. F0111wr 01/ori11e /'/nm A1<'a I ,,u,;, /'·l'Jr,,,,,.,nNH-OIKJtJN>ll)•/JII!< ,.,, "·' Jum,wy.'()11) I I I I I I I I I I I :I I I. I I I I Tahlc 2 llislorical .\1crcnry Analyses of C.ruundwatcr Samples ~r,wmr!!~~ ~111W.f'if-~ 't~di5 , "')l~~-1~L~' '. ~~-, D,\'l'E~l :-, OOt i111~(R<:u'R~,a ITTA' '' "~~WW. ' ' ' 01/25/06 <0.0002 11/07/06 0.0006 05/30107 0.0007 Cl'-08-2 11/08/07 <0.0002 05/13/08 <0.0005 12/05/08 <0.0005 U 12/01/09 0.00065 01/24/06 <0.0002 l l/08/06 <0.0002 05/31/07 0.0002 CP-09-2 11/08/07 <0.0002 05/13/08 <0.0005 12/05/08 <0.0005 U 12/02/09 <0.0005 U Ul/24/06 <0.0002 1 !/08/06 0.0004 05/31/07 <0.0002 Cl'-I0-2 I !108/07 0.0002 05/13/08 <0.0005 12/05108 <0.0005 U 12/02/09 <(l.0005 ll 01/24/06 <0.0002 11/07/06 <0.0002 05/30/07 <0.0002 Cl'-1 !-2 11/07/07 <0.0002 05/13/08 <0.0005 12/05/08 <0.0005 l J 12101/09 <0.0005 \J 01/24/06 0.0004 11/07/06 0.0002 OS/30/07 0.0002 CJ'-12-2 ! 1/07107 0.0003 05/13/08 <0.0005 12/05/08 <0.0005 I J 12/01/09 0.00008 ., 01/25106 <0.0002 11/07106 <0.0002 OS/30/07 <0.0002 MW-02-2 ! 1/071U7 <0.0002 05/13108 •!(l.()005 12105108 <0.0005 U ]2/01/09 <0.0005 \J .,1:1rinl' ~and Cl'-0J-3 Oln4106 0.0002 ] ]/!4107 ~~14'.'?.1..~ll:0023;S." ... "-~~;!t Cl'-Ol<"m 05/13/08 <0.0005 12/05/08 <0.0005 \J 12/01/09 <0.0005 U 01/24/(J(, <0.0002 11/07/0(, <0.0002 05/30/07 <0.0CXJ2 Cl'-03-3 11/07107 <0.0002 05/t 3108 <(J.0005 !2/05/08 ().00071 12/01109 <0.0005 U 01/25106 <0.000iC) 11108/06 <0.0002 05131/07 <0.0002 CP-04-3 11108/07 <0.0002 05/13/08 <0.0005 12/05/08 <0.0005 U 12/()2109 <O U005 U 1 l/)4/07 t\i;r:¼"irt;(;f;:-.iu tl .002 I X:N:!Jl&It'."'3!:_>R)'. Cl'-08-3 05/18108 <0.0005 12/05/08 <0.0005 U )2101/09 <0.0005 U ''' Sh3'h:d •aluc5 ,nJ,ca1~ ,m c-crcd~nc~ ol 1he North Caruhna groundwater qualny >lan~an1 of II 011105 "'!fl. ( 15A NCAC 21..02112) Well s,1m1•ks Cl'-IJ~.1 atid CJ•.1M.3 wc1e mi1l,,bde<l durn1g samplir,i;: the s..mpl~ lah~te,1 Cf'-0,!-I in lhe f,d,I d1ld in lhe laho,ato11· ,q,0,1 wa; JCl1J,1lly Cl'-ll,1 .. 1,1nd vi,,· vc,sa J fa1ima1e,1 < .\1HL.,. Ml}I. Concenlr,,fion I= than lhc f)uan1'1a1ion Limit. tJ Jhe crnnpouml was analy,ed lo,, bul wJ5 u,,t ,1t·1ec1,·,I ;11 ,,, Jbm·e 1hc Mellmd 1cporting lirn,t (Ml(L) 1/Mf' .Vol"/// C"aJ"o/ina, foe. I /)0111/ar l'opi•r (" 0111p1111y. 1./.C Monitoring lfr111n1 OU-3-r,,rmrr Clrlori11r Plnm .11ro / IJli,;, I 'l'J/,,W, //</1/•IU,HXH!/'IJ/N/'11111, IWJ/ .\/., I I I I I I I I I I I I I I I I Tahle 3 lli\lorical Croundwakr i\1onitorin~ Field l'aramctcrs .,_,,,,f_ {11 ye t -,1 '"l'tf~; '.l't,oiiJj ·~ ~Fe:!'"! ~1,')l $, OXY(;EN gvu1 ~CONDl!ClWIT\' " ~ Tl£MI', , m;:~:ffifl!,: 1 , (~. -~.I~{,~''. f:Jlf :C) Alhn•i;1I m uifor (waler t:1hle) MW-OIB Cl'-02-1 Cl'-0.l-l C!'-O•l-1 Cl'-05-1 Cl'-07-1 Cl'-08-1 Cl'-09-1 Cl'-10-1 CP-11-1 RMT ,\'0,1/1 Cmoli11n, fot. I Domtnr l'ap,•1· Compo11_1·. I.LC Monitoring 1/,•pm I ()(j.J. Fo, me,· 01/oritw /'l,1111 A, rn I u1,;1·1 rJ/1 ... <J!!1!1J<•N•"'l"'•1'J11'U,.J/.1/.\ 01/24106 11/07/06 05/30107 l 1/07/07 05/14/08 12/05108 12/01109 0112510(, 11/08/06 I 1/08/07 05131/07 05/14/08 12/05108 12102109 01/24106 J 1/07/0(, 05/30107 11/07/07 05/13108 12/05/08 12/01/09 01/25/1)6 I !/08/06 051.11/07 I l/08107 0511•1/{)l:I 12/0511)8 12102/(){) 01/25/06 11/08106 OS/3 J/07 11108/07 05/1·1108 12105/08 !2102/()(J OJ/25106 111011or, 05/J0/07 J 1/08/07 05/U/08 12105108 12/0)/0'! 01/25/0{, ! 1/07/06 0513()/()7 ! 1108/07 05113108 12105/08 12/0110') 01(24/0(, l l/08/0r, 05131/07 l 1108/07 05/1,1108 !2105108 12102/0'J 01/24/()(, 1110810(, 05131107 11/08/07 05/14108 /2105108 )2102/09 0)/24106 ! l/07/06 05130107 ! 1107107 05/IJ/08 12105/08 1210!/0() 7.82 0.00 2.68 0.14 0.12 0.21 0.4.1 5.10 0.10 0.31 2.56 0.67 0.7') 0.29 9.90 0.00 2.99 0.24 0.8'J 2.9 1.09 1.(,.1 1.38 4.0U 1.20 3.7 3.98 1.47 5.45 0.13 2.6() 0.39 (l.2(, 0.55 029 J. JJ 0.00 3.18 0.3•1 0.37 0 51 1.2 8,79 5.26 6.59 ,1,45 •l.46 :u, 1.76 7.34 0. I 5 J.38 0.28 0.68 0.88 0.63 (,,20 .H9 3.J 0.77 0,{J! 1.59 0.85 6.87 U.00 2_()() 0J,1 0.91 0.57 0.68 7.29 644 16.4 7.12 744 22.0 7.09 519 20.88 7.26 561 23.47 7.35 636 19.8) 7.45 586 20.23 7.42 406 20.64 6.92 786 22.1 6.30 900 21.8 6.::n '!08 22.91 (,J6 ()7 20.11 6.92 854 19.6) 6.77 786 20.21 7.05 (,44 20.97 7.52 321 12.4 6.69 810 20.2 6.82 298 19.2-1 7.28 600 21.6 7 . .1,5 561 11_3,1 6.77 570 14.46 7.42 510 16.4 7.09 1257 22.1 7.80 1490 21.1 6.68 1790 21.19 8.(,5 1355 22.3 l 8.0! 1501 20.8') 7.44 1265 17.87 7.82 1045 19.U, 8.78 1033 22.1 9.50 1570 20.5 8.7 l I JOO 2 ! .81 9.79 425 21.09 9.72 619 20.76 9.23 727 1(,.57 9.0fi 0.357 l!l..17 7.4] 980 22.1 7.16 IYJO 23.5 7.17 !360 2! 0-1 7.58 !306 23.68 7.72 I 182 20,5(, 7.7·1 !035 20.73 7.58 1220 2 l .24 'J.22 392 21.4 8.56 900 22.2 8.61 (,{}] 25.7 9 . .13 •159 ] '!.51 9.05 6.~8 21.89 7.8-1 263 21.07 9.08 •180 I 'J.81 6.9•\ 905 201 (,.34 %0 22.6 6.J5 661 20.8 6.92 889 22.88 7.05 8•15 18.77 (,.55 910 21.) I 6.71 831 21.01 6.98 6')4 20.1 6.74 940 21.7 6.55 714 22.28 7.27 8}1 21.1 7.65 2'4 2 l.l4 73 606 20.1 l 1.5(, 706 19.7 6.79 422 H,.9 6.05 568 23.1 5.8-1 4(,6 l'J.77 6.34 571 H.l5 6.37 5.19 17.98 IJ.37 6] I 2()_()4 6.49 533 20.99 'rU) I.I 2.1 0.78 0.67 1.17 1.96 2.49 45.5 I 1.0 5.17 5.44 4.2J 5.40 2A3 7.7 3.2 1.% 0.59 2.03 2.77 !.43 11.0 41.2 5.18 5.16 25.2 10.S 3.78 31.9 S•Ll 46,J !•J2 138 8.l.9 63.8 I.(, 6.7 1.32 17.9 4.8 l.48 1.74 17,0 60.1 14.8 8.7(, 4.6 7.25 9.7 3.1 .u 0.(,-1 0.42 2.32 2.92 1.02 !_() o.r, 1.49 0.99 9.75 2.88 l.71 2.(, 1.7 1.8() 8 08 5.89 3.51 0.78 .lanumy ll/lU I I I I I I I I I I I I I .I I I 1, I Table 3 llistorical r:roundwatrr ;\lonitorin~ Ficltl Paramch'rs -Wi>iss7ii:vii1>l//,"< £'tlx\i(•1>Nff~ / : .. ,:,.:;,;:;w, ,;,,; :Ill.' .\k {ml!/l,Jl'Mk11.' 01/2,1106 11107/06 05130/01 Cl'-12-1 11/07/07 05/13/()8 12/05/08 !2/01/09 01/25/06 I J/08/06 05/31107 Cl'-13-1 11/08/07 0511•1108 12/05108 12/02/09 Atluvi:11 i1uuifrr (waft•r tahll') 0)/25106 11/08/0(, 0501/07 Cl'-1•1-1 11/08/07 05/14/08 12/05/08 12/02/09 Cl'-15-1 01{15/06 01{15/06 l 1/07/06 05/."l0/07 MW-02 11/07/()7 05/13108 12105108 12/()1/0') ,\lhn·i:il m uili-r 1-20 fl dn·:11io11) C!'-01-2 Cl'-02-2 Cl'-0.1-2 CP-(M-2 Cl'-05-2 Cl'-07-2 RMT North Cmoli,m, !11r. I Om111r11 l'ap,,, lm111m11_1. f.l.C Moni1mi11g Rqiort OU-3 -Foi me,· C/1/ori11e f'h/111 .4rm /·IIJ"<;,1·1•J/ <HJ/11/1/ r1,,.m11.'1!1"1!l.'/II< <JIii,\/,\ 01/24106 11/0710!, 05/J0/07 I !/08107 05/IJ/08 12/05/08 12102/09 01/25/0(, 11/01@(, 05/J 1/07 l 1/08107 05/1•1/()8 12/05/08 12/0210') 0ln.\t0<, 11107/06 05/.10/07 I 1101,0·1 05/1.l/0H 12/05/0X 12101/0') 01/25/0(, I 1108/06 05/.11/07 ) 1108/07 05/J,1/08 12105108 12/02/09 01/25/0(, 11/08/0h 05131/07 11/08107 05ll4/08 12/05/08 12/02/09 0112510(, I 1/07/0() 05/.10107 11108107 05/J_l/{)8 !2105108 12/0110') 5.33 0.00 3.ll OJ 0.52 0.49 0.6J 6.02 0.18 2.74 0.29 0.-1 05 0.58 5.18 0.13 2.4•1 0.36 0.96 0.82 J.95 6,0 5.00 3.05 (J.84 1.58 4.30 •l.10 ,\.66 5.37 0.00 2.M 0.14 0.3 0.32 0.19 7.11 0.00 2.61 0.17 0.53 0.45 0, 18 7.25 0.00 2.79 0.18 0.(,8 0.71 0.48 4.J l 0.00 2.G 0.2 (),(, 0.56 0.64 5.65 0.00 2.5 0.18 0.28 0.5 0.37 4.20 0.00 2.66 O.J.1 0.25 0.26 0.57 l'sl:i:'i:i'fl(;l.'.~ ~'IJ.~. : <:C)NDl"1('.fi'\;t,1~.? .,.n;Mn:NATIJRR ~i,~ll:f.i~ ~~ 6.72 607 ! 7.5 6 .. n 900 21.9 6.20 671 20.84 6.50 664 23.02 6.60 727 19.29 5.71 (,76 21.16 7.08 869 2(U 7. l 5 8'J7 21.9 6.90 900 23 0 6.59 685 22.8 ! 7.21 580 24.07 7.29 723 22.9 7.2 562 2.H, 7.54 616 ns 6.80 1196 21.6 (,_1(, 1440 23.0 6.38 IJ00 21.14 6.81 t 178 2•1.18 6.8,\ 1153 21.4 6.1,1 102! 23.1 7.12 812 23.26 6J.1 .174 21.8 6.22 432 22.1 6.12 900 21.0 5.91 599 20.81 6.2.l 502 22.2 l 6.6(, 7J5 20.16 (,.42 Sr,'> 18.-12 6.56 603 18.53 7.0l 633 19.5 r,.98 840 19.9 r,.7r, 511 19.84 7.2(, 552 20.2 7.19 5()(, 20.11 7.15 536 20.15 7.32 330 19.9 (,.17 2735 22.1 r,. !O 2470 19."! 6.1(, 1780 19-'17 6.65 !11-1 19.9! 6.71 106! !9.97 6.62 63 l 19.56 r,.93 47') 19.67 7.03 843 17,8 r,.87 900 19.7 6.37 (,88 )8 5') 6,87 (,25 20.0! 6.SJ 873 18.2') 7.0(, 725 19.47 7.02 5()2 18 ') 5.8J 2319 22.1 6.09 1480 21.0 5.65 1290 20.3.l 5.'!') 123,1 2 l .02 (,.03 l."197 20.70 5.95 142.1 20.77 (,.2 ! l 16 21.04 6.24 1406 22.1 6.69 ') JO 21.0 6,04 H'/4 20.41:<, 6.72 H 10 21.14 6.8 %(1 20.8 6.66 !MO 20.9,1 6.88 685 2).().1 6.61 9H 22.1 (,J\2 '>00 21.8 6.62 JOOO 21 6.98 658 22.03 6Ji6 8.17 21..l 7. 13 S0J 21.98 7.2(1 279 21.55 ( - 19.7 8.0 2.82 5.28 4.09 9.95 IA? 22.8 !3.9 2.62 3.7 22.2 6A 6.05 144.0 18.J 10.'1 21.9 40.5 17.8 22.1 36.9 J.7 NM 3.1 2 27 ID 122 2.69 I.I 1.4 o, 0.51 0.57 1.5(, 0 82 12.0 ,. , 1),6•1 {)..18 0.9·1 2.75 0.58 11.0 •15.J 8.52 4.26 2.38 2.76 l.67 •!.I 2.2 0.28 2.-1(, 0.<,1 l.72 0.43 38.3 2.0 0.57 0.55 J.01 1.23 I.SJ 16,6 4.7 0 1,J 0 .lf, 0.7 l.05 ON> Jmmary lll/11 I I I I I I I I I I I I I I I I I I Table 3 llistorkal Groundwalrr J\11witorinJ..: Field l'arnmctcrs -B'!!:!si•ic,Wc~-~,. ~JN,lUCn\·nv, l!UTI~~ UIDll)'c4 . ,::J/.:"i•j:,...;jf<'fi er.ww---.~, ~ ~:_ l1iSfrm) . .,-~¼\f C)~~ I)\ >il 0l/25/06 I J/07/06 05/30/07 CP·0S-2 11/08/07 05/13/08 12/05/08 12101/09 01/24106 l 1/08/06 05131/07 C1'·09-2 l !/08107 05/14108 12/05108 12/02109 01/24106 11/08/06 05/J 1/07 CP-10-2 l 1/08/07 05/14/08 12/05/08 12/02/0() ,\lhn·i,11 ,wuifn (·20 II l'11•valion) CP-11-2 Cl'-12-2 MW-02-2 l\la1 inl· .\mHI CP-01-3 Cl'-0t-3R Cl'-03-3 Cl'-0•l-3 Cl'-08-3 N.\1/' Nmth (molina, li1c. I Domtal' /'apcl' Company L/.C Mo1111mi11g N,'f'(JII OU-3 -Fu,-m,'1 CJ,h,,·it,c f'lam A,-ea ,,,,,.;n·1·11 r,illJ//1 '""'""'-'m•1\!llrH ,.,, 11, 01/24/06 11/07/06 05/30/07 11/07/07 05/13108 12/05/08 12/01109 0!/2•1106 I !/07/06 051]0/07 11107107 05/13108 12/05108 12/0)/()(J 01/25/()(, 11/07106 05/.10/07 11/07/07 05/13/08 12/05/08 12/01/09 01/24/0/) 11/J-1/07 05/14/08 l 2/05/08 12/02/()<J 01/24/06 J 1/07/06 05/.'0/07 l l/07107 05/U/08 12105/0X 121()1/()() 01/25106 11/08106 05/31107 l 1/08/07 05/J.1108 12/05/08 12/02/09 I I/J4/07 05/13/08 !2/0S/08 !2/01109 5. 14 6.80 0.00 7A5 2,8 l (,.93 0,14 7.17 0.32 7.26 0.34 7.34 0.4 7.54 7.23 6.27 0.00 6.06 3.02 5.92 0.2 (>..17 0.69 6.43 0 . .18 6J9 0.29 6.7') 7.02 6.19 0.00 fl.04 2.49 SJB 0.2 l 6.21 0.52 6.25 0.43 6.14 0.2•1 6.4 6J9 7.42 0.00 7.J I 2.94 h.82 0.23 7.38 0.J7 7.49 0.29 7.61 0.'16 7.5J 6.02 7. l 5 0.00 7.00 2.85 6.79 0.19 7.38 0.28 7.49 O . .' 7.J 7 0.5 7.28 4.(,/, 7.25 0.00 r,.95 2.7•1 6.58 0.27 7.4 j 0.5') 7.48 0.2 7.54 0.51 7.46 4.94 7.05 1.03 6.98 0.09 7.03 0 25 (,.93 0.22 7.18 6.51 7.00 0.00 7.13 2.8') 6.77 0.45 (,.93 0.56 h.91 0 88 7.11 0.47 7.0 I 5.02 b.95 0.00 7.08 2.36 6.52 (J.J.l r,.80 {)_l() 6.91 0,37 (i.76 0.9·1 7 0.18 7.49 0.08 7.04 0) 7.07 0.27 6.')4 420 21.4 12.5 537 21.8 3.2 425 20.94 0.44 542 22.17 0.28 542 20.99 0.77 456 23.02 0.92 279 22. l 4.03 239 20.! 23.7 242 20.4 2.4 2370 19.35 0.42 1987 20.66 0.46 1786 19.19 0.79 !5•!0 20.18 1.6 I 869 20.08 0.93 1851 20. l 17.4 1620 21,6 1.2 1500 21.04 0.75 IJ JO 21.61 0.27 l 146 20.5(, 1.04 1165 2 l .05 1.72 915 20.84 1.44 ()ll 18.9 ·l.9 90 20.9 2J 737 l!U 1.28 772 21.51 0.61 769 18.43 0,87 740 20.()2 l.28 7.lJ 20.52 0.-1-1 C),J() 20.5 7 .. ~ 900 21.7 ').5 713 20.')2 0.3 553 22. 12 0.58 516 20,')2 1.05 •163 22.03 1.U 4.15 21.57 0 .. , •! )2 22.1 .to (,),\ 20.8 (U •113 20.84 0 .. ,1 ·188 21.43 U.29 539 20.-!8 ().(,2 5(,5 20.77 0.M 4(,7 20.03 0.77 1•!80 18.7 4--1 I.W20 21.47 X.2 l 5310 19.49 0.7·1 12100 18.82 1.98 10220 19.l•I 0.'/8 1•102 llU 9.0 1390 18.9 55.0 15(,00 19.17 ,, IYJ.10 19.22 0,92 14230 18.98 ,1.(,5 IJ020 18.82 8.19 I !680 18 .. 17 8.5 J 2299 22.1 2J.IJ 765 20.7 1.9 lJ JOO 2Ll2 3.6b 1•1710 20.(1•! l.•U 15520 21.0~ 1.0.l 14200 20.35 .,.01 1225 20.4(, 0.51 40(,50 23 . .' I 12_() 5492 2 ! .23 0,5•1 6732 21.21 1.14 8465 20.53 0.59 }(11!1//!I). ]////) I I I I I 'I I I I I I I I I I I I I RMT North Carolinu, Inc. I Domtar /'aper Company, LLC Mo11itori11g Report OU-3 -FOrmer Chlorine P/0111 A rC({ I: I ll'f'GI' /, lf'JIV///-11517 / I l/,fll)f !/// i:!IH/J(H! 5 I 7 I 1)4 ./1/J I. /JO<.\ A-I Appendix A Analytical Data Ja1111my 20 I 0 I I I I I I I I I I I I I I I I I I ~ Columbia ~.l Analytical Services· www caslab.cmn December 24, 2009 Service Request No: .10906031 Heather Smith RMT Inc. 30 Patewood Drive Suite I 00 Patcwood Plaza One Greenville, SC 29615-3535 Laboratory Results for: Domtar Former Chlorine Plant/5171.04 Dear Heather: Enclosed arc the results of the sample(s) submitted to our laboratory 011 December 5, 2009. For your reference, these analyses have been assigned our service request number ,J0906031. All analyses were perrormed according to our laboratory's quality assurance program. The test results meet requirements of the NELAP standards except as noted in the case narrative report. All results arc intended to be considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for use or less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. Please contact me if you have any questions. My extension is 4408. You may also contact me via email at TKissingcr@caslab.com. Respectfully submitted, Columbia Analytical Services, Inc. Tom Kissinger Project Manager Page I of ----- CAS Jacksonville is NLLA C-accredi1ed by 1he SI ale uf Florida. #E82502. 01hcr s/a/e accrcdi1a1ions include: Georgia. #958: Kenlucky. 1163: Louisiana, #02086: Norlh Carolina, #527: Soulh Carolin". #9602 /00/; Texas. #T/04704197-09-lX I I I I I I I I I I I I I I I I I I I Client: Project: Sample Matrix: COLUMBIA ANALYTICAL SERVICES, INC. Domtar Paper C1)mpany Domtar Fonner Chlorine Plant water CASE NARRATIVE Service Request No.: Date Received: J090C,03\ 12/5/09 All analyses were perfonncd consistent with the quality assurance program of Columbia Analytical Scrvlc<.:s, Inc. (CAS). This report contains analytical results for samples designated for Tier II data ddivcrab!cs, including results of QC samples analyzed from this delivery group. Whcn appropriate to the procedure, method blank results have been reported with each analytical test. Analytical procedures performed by the lab are validated in accordancl'. with NELAC standards. Parameters that arc included in the NELAC Fields of Testing but arc not inc\udcd in the lab's NELAC accreditation an; identified in the discussion of each analytical procedure. Sample Receipt. 36 water samples were received for analysis Jt Columbia Analytical Services on 12/5/09. The samples were received in good condition and consistent with the accompanying chain of custody form. Samples arc refrigerated at 4±2')C upon receipt at the lab except for aqueous samples designated for metals analyses, which were stored at room temperature. l\:lcrcury by CV AA No problems were ob.served with this delivc1y group. 2 I I I I I I I I I I I I I I I I I I I * !.ncrganic Data The result is ~m ourlier. See G~sc 11a1Tativc. The control limit criteria are not applicable. See case narrative. B E J u z The analyte was found in the associated method blank at a level that is significant relative to the sample result. The result is an estimated amou_nt because the value exceeded the instrument calibration range. l X The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL. The compound was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. Too many colonies were present (TNTC). The numeric value represents the filtration volume. The MRL/MDL has been elevated due to matrix interference. See case narrative. Metals Data * The result is an outlier. Sec case narrative. ~ The control limit crilcri~1 :.ire nClt <.1pplicabk. See case 1nrrat!'.·~- The result is an ..:stim:~led cnncentratic,n th:n is kss than 1hc MF.L t·,ut g_rl':11'::r ll·.:m ()i" cq1d tn 1h~ i, !Di_ f-: Thi_: rcpoi"l!.X! ..-,1h1c i~ cstinn1cd hcc:n.1.-.;~-<'f th::--;•:·::.·sc1:•:•.: ,,f 1:1:ili"i·-. i:1tL·:·l"crc•;·,:.:;.' \1 Th,..· dup\ic:!lt' i;1je..:1i.:sn pn:cisi,·,n w::'.: :w1 IT'L'i. N The (-.fo:,"i.-: Spil:c ~~1111;)\c n:c1_)\·cry i~ !11,t \\·:1hir, ,::,t"itn1I ii::::i::. '<._:...: :..:::s;c :·1::;·:·:'.ti··.·:..'. S The r~:::1.il! w:iS ·J...'.tcnnincrJ hy ,1\1.::thud 1.if Su10,.Li:·d _,-\Jdiiic1:-is (\·IS/.). U The cc•rnpound v..-:J.s :.rn~:lyzcd fnr. h~ll ,_.._•::;; 1w1 dc!-:.·Cl:.:d {_"\'<(~n-ll·~·tc-:.:t"') ::i (li" ::!),,u..: 1!1c f\1R[_:~·iL)L \\' The post-di~estion spike for f"urn::1ec .'-\/\ :11nlysis is cir.!; llf cnnr;-nl li:~1i:s. \t,')1ik sc:rnpk :1hs(_1rh :i1c~· ::-: l~·.,s th;!:1 50''.,;; or spike :.ibsorbcncc. The ~vlRL/lvlDL has hcl'n clc\·2tcd c!u;.' 1-~1 n~~11ri:-: it:1L:rti..:rL'iKs: . .\ ~l~C c~:sc /lJJTClli\"~. + The c011cki1ion CPtrfri:ic111 t(,r the [\·!S.-'\ i:; ks'.:-tli::n rJ.~_HJ). * Organic Data The rcsult is an outlier. SL'c cast: n:.iiTJti\'C. Thl: control limit criteria c1rc ;1ot applic..tble. See CJ.Se 112r;·ati\"e. The tentatively identified cDmpound is a susp\:.'ctcd alclol-ct)ndcns3lion product. ,\ ll C The an:ilyte was found in the asso-:..:iatt.:d mctl10d bbnk Jt a level that is signiC1c<illl rclativL'. t0 the s;1mplc n:suit. The analyte was qualiwti,·cly confinned tising GC/!"v!S tcchniquL'.S. pattern rcu,~nitinn, ll!' by comparing to D E .I N p u X historlca! (!ma. The reported n.:sult is f"wm .i dilu1ion. The result is o.n ,:stimJtecl amount because t!K value exce .. -d,..·d lhl' inqrumc;1! c.i.!ibratic1n r:i.r~8e. The result is an l'stirnatl'd conce11tr:11ion th.i.t is less th:m the MRL hut greater than or equal w the l\·lDL . The result is presumptive. The analyte was tentatively identified, but u confrnnatii:.m an::lysis was 1101 pcrfom1cd. The GC or HPLC confirmation criteria were cxccc:dcd. The relative percent difference: is grc:c.1tcr th.'.ln 4(J~,-(I hetwec:n the iWO anulytical results (2:?1//1 for CLP Pesticides) The compound \\'J.5 analyzed f(lr. brn was not Jcu:cted ('·!\lon-clctect··) at or .:ibove the JvlRL1!'vlDL. The MRU'."v1DL h3~ t1cen ele\·a1cd clue 10 a chwmato;;raphic interference. Ste CO.Sl' narraiivc. Prlroleum Hydrocarbon Specific F The chromatc,graphic i1nsnprint of the sornple matches the elution pattern of the calihrotiun s•.anda;d. L Thl' chromJtogrnphic :·mgcrprint of the SJmple resembh:s a petroleum proclucl, hut the elution p:..!:tcrn indic:iti..:~ the presence of :i greater amou1E of lighter mo!ccular weight consti1uents than tl1c calihra11nn str:mbrcL H The chromo.tographic iingcrprint of the sample resembles a petroleum ;:-:roduct, hut the elution pJtlcrn indic:i!cs 1he presence of 3 greater amount of hcavier molt:cubr weight constituents limn the ca\ib:-:1tio11 slc1miard. 0 The chromatogr:iphic fingeqJrint of the sample resembles an oil, but docs not ma1ch the calibration standarJ. Y The chromatographic lingerprint of the sample resembles a petroleum product eluting in opproxirnatel\· the correct carbon range. but the elution pattc111 docs not match the calibr;:ition sta11c!c1rc!. Z Thc chromatographic fingerprint ci(1cs not resL'.mblc a petroleum product. 3 I I ASTM I A2LA CARE I CAS Number CFC CFU I DEC DEQ I DHS DOE DOH I Ei' . .\ [L:\i1 GC I GC.''."1S 1..l.iFT I kl klCL I !vlDL h1Pl✓ :\•1P..L I l-.JA NC 1· :-1c..:,s1 \!) !'JIOSH I PQL RCR.-\ I SIM TPH I I I I I .--\cronyrus An_1eiic::,n Society for Testing and {v'!;:1tt:ria!s Americ3n Association for Labor3t01y AccrcditJ.tion California Air Resources Board Chemical Abstract Service registry Number Chlorofluorocarbon Colony-Forming Unit Department of Environmental Conservation Department of Environmental Quality Deportment of Health Services Dcpartmenl nf Ecology Dcp:1:-tm:.:ni ,,fi-lcJith (i:.i.s Ch1·c,matc1gr:1fi!;y L(.'akin~ L;i1cicr;i·(iu11d F11cl T:rnL Mnciificcl !'."1:1ximum Cc'llt:1111inant Le,·d is th-:.:: highc~i ;·,cnlii:c~il-ik '-',.\t1..:•..:m;·.:ih.1:: c.j .~cr[--.,c;;~,1~-~ ;.iik1,,·1;d 1;1 drinking ,,,-~~t:!r ;:i.s cst:ibiish;:d by the USEl'A. J\·ktiwd l}.:kction Limii Most Probabk Number Hethod Repo:1.ing Limit Not .t\ppliecible Not Calcub1cd National lnstitut:.: for Occuparion;d S3fcry and HL.:alfr, Practical Quantit:nion Limit Resource Const:n·a~ion and Recovery Act Stk:ct:-::d lon Monitniing Tr:icc 1::n:1 is the ccn::eilltJtion of ar, ~1.1..:ly1c th::11 is ic::;s than the f'(JL ~1u1 :;n.:ai~i-th~u1 c,i· cqu3] t1J ::1~· MDL 4 I Client: RMT Inc. Project: Domtar Former Chlorine Plant/5171.04 I I I I I I I I I I I I I I I I I SAMPLE# 10906031-00 I 10906031-002 10906031-003 1090603 1-004 10906031-005 10906031-006 10906031-007 10906031-008 10906031-009 10906031-0 I 0 1090603 1-0 I I 10906031-012 1090603 1-013 1090603I-014 10906031-015 10906031-016 1090603I-017 10906031-0 I 8 10906031-019 1090603 I -020 10906031-021 10906031-022 10906031-023 J0906031-024 J090603 I -025 10906031-026 J0906031-027 1090603 1-028 J090603 I -029 J090603 I -030 J090603 I -03 I 10906031-032 10906031-033 J090603 l-034 J090603 I -035 .10906031-036 l'rintctJ ! 2/24/0() 6:36 SAMPLE CROSS-REFERENCE CLIENT SAMPLE ID MW-2-2 MW-2 CP-03-1 CP-03-2 CP-03-3 CP-11-1 CP-11-2 CP-12-1 CP-12-2 DU-09401 FBLK-09401 CP-08-3 CP-08-2 CP-08-1 CP-07-1 CP-07-2 MW-113 CP-04-3 CP-04-2 DU-09.402 Cl'-04-1 CP-05-1 CP-05-2 FBLK-09402 CP-02-1 CP-02-2 CP-01-2 CP-13-1 Cl'-14-1 CP-09-1 Cl'-09-2 Ci'-10-1 Cl'-I 0-2 FBLK-09403 CP-01-3R DU-09403 Sample Summary Service Rc(1ucst: 10906031 DATE TIME 12/1/0<) 09:15 12/1 /09 09:50 I 2/l /09 10:05 12/1/09 10:20 I 2/l /09 10:40 12/1 /09 10:55 12/1 /09 I 1:10 12/1/09 11 :35 12/1/09 12:00 12/1 /09 00:00 12/1 /09 14:50 12/1/09 16:20 12/1/09 16:35 12/1/09 16:50 12/1 /09 17:00 12/1 /09 17: 15 12/1/0</ 17:45 12/2/09 08:35 12/2/09 08:50 12/2/09 00:00 12/2/09 09:05 12/2/0'J 09:20 12/2/09 09:40 12/2/09 09:55 12/2/09 10:05 12/2/09 10:25 I 2/2/09 10:45 12/2/09 11: 10 12/2/09 11 :30 12/2/09 13:20 12/2/09 13:35 12/2/09 13:55 12/2/09 14:10 12/2/09 14:20 12/2/09 17:10 12/2/09 00:00 5 Page I of I I CULUMlnA ANALYTICAL SERVICES, INC. /\nalyt ical Repot1 Clicnl: Domtar Industries Service Request: )0906031 I Project: Domtar Former Chlorine Plant/5171.04 Date Collected: 121 I /09 -121 2109 Sample Matrix: Water Date Received: 121 5109 Prep Method: Mclhod Units: 11g/L I Analysis Method: 245.1 Basis: Ni\ Mercury, Total I Sample Name Dilution Date Date Lah Code Result Q MRL MDL Factor Extracted Analyzed I MW-2-2 1090603 1-00 I ND lJ 0.50 0.08 121 8/09 1219109 14:26 MW-2 J090603 l -002 ND lJ 0.50 0.08 121 8109 1219109 14:28 CP-03-1 J090603 l-003 ND lJ 0.50 0.08 1218109 1219109 14:32 CP-03-2 10906031-004 ND lJ 0.50 0.08 121 8109 1219109 14:41 I CP-03-3 1090603 l-005 ND lJ 0.50 0.08 121 8/09 1219109 14:43 CP-11-1 J0906031-006 ND lJ 0.50 0.08 121 8109 1219/09 14:4,J Cl'-\ 1-2 10906031-007 ND lJ a.so 0.08 121 8109 1219109 14:45 I Cl'-12-1 10906031-008 ND lJ 0.50 0.08 121 8109 1219109 14:47 Cl'-I 2-2 10906031-009 0.08 J 0.50 0.08 121 8/09 1219/09 1,1:5 I DU-0940 I J0906031-0 I 0 ND lJ 0.50 0.08 121 8109 1219109 14:53 I FBLK-09401 10906031-011 ND lJ 0.50 0.08 121 8109 1219109 14:54 CP-08-3 10906031-012 ND lJ 0.50 0.08 121 8/09 1219/09 14:56 CP-08-2 J090603 l-O I 3 0.65 0.50 0.08 121 8109 1219/09 14:57 CP-08-1 J090603\-0l4 1.52 0.50 0.08 121 8109 1219109 14:59 I Ci'-07-1 10906031-0 I 5 ND lJ 0.50 0.08 121 8/09 1219109 15:00 Cl'-07-2 )0906031-016 0.08 J 0.50 0.08 121 8109 1219109 15 :02 MW-113 10906031-017 2.06 0.50 0.08 121 8109 1219109 15:03 I CP-04-3 J090603 l-O I 8 ND lJ 0.50 0.08 12110109 12111/0912:48 ' Cl'-O,J-2 1090603 1-019 ND lJ 0.50 0.08 12110109 12/\110912:52 DU-09402 J0906031-020 ND u 0.50 0.08 12110109 12111109 12:58 CP-04-1 )090603 1-021 1.14 0.50 0.08 12110109 12111109 13:00 I Cl'-05-1 J090603 1-022 7.57 0.50 0.08 12110109 12/\\/0913:01 CP-05-2 ,]090603, 1-023 0.18 J 0.50 0.08 12110109 12111/09 13:03 FBLK-09402 J0906031 -024 ND lJ 0.50 0.08 12110/09 12111/09 13:04 I Cl'-02-1 10906031-025 0.11 J 0.50 0.08 12110109 12111109 13:06 CP-02-2 ]0906031-026 0.09 J 0.50 0.08 12110/09 12111109 13:19 CP-01-2 J090603 J -027 I.SO 0.50 0.08 12110109 12111/09 13:20 . Cl'-13-1 10906031-028 0.10 J 0.50 0.08 12110109 12111109 13:22 ICl'-14-1 J090603 l-029 0.08 1 0.50 0.08 12110109 12111109 13:23 CP-09-1 1090603 1-03 0 (I.I I J 0.50 0.08 12110/09 12111109 13:25 CP-09-2 )0906031-031 ND lJ 0.50 0.08 12110/09 12111109 13:26 ICl'-10-1 10906031-032 ND lJ 0.50 0.08 12110/09 12/\ 1109 13:28 CP-10-2 )0906031-033 ND lJ 0.50 0.08 12110109 12111109 13:29 FBLK-09403 J090603 I -034 ND lJ 0.50 0.08 12110109 12111109 13:30 IC\'-01-JR )0906031-035 ND lJ 0.50 0.08 12110/09 12111109 13:32 DU-09403 J090603 l -036 ND lJ 0.50 0.08 12110109 1211 I 109 18:48 Method Blank J090603 l-Mll I ND lJ 0.50 0.08 121 8109 12/9109 14:06 Method Blank J090603 l-MB2 I ND lJ 0.50 0.08 12110109 12111109 12:42 ICommn>ls: Printed 12/15/09 17:18 Fo1111 1/\ I .-1 JI fl< 1w 2' S 1:1 r li ms' I ,in 1\ H l'p~\A 11;1 lyt ic~ 1 lkpor1. rpt Super Set Rckrencc· 09.()()()()16,11) r!."v OU I Client: I Project: Sample Matrix: I I Sample Name: Lah Code: I Analytical Method: Prep Method: I Analytc Name Mercu,y, Total I I I I I I I I I I l'rin!cd 12/ t 5/09 17: IX COLUMBIA ANALYTICAL SERVICES, INC. QA/QC Report Domtar Industries Domtar Fonner Chlorine Plant/5I71.04 Water CP-03-1 1090603 1-003 245.1 Method Matrix Spike Summary l\11crcury, Total (Cold Vapor, Manual) Service Request: 10906031 Date Collected: 12/1/09 Date Received: 12/5/09 Date Analyzed: 12/ 9/09 Units: µg/L Basis: NA Matrix Spike Duplicate Matrix Spike Sample Result ND Result 5.18 10906031-MS I Amount % Rec 5.00 104 Matrix Spike Summary .10906031-DMSI 1½, Rec RPI) Result Amount 11/0 Rec Limits RPD Limit 5.23 5.00 105 70 -130 20 I I Client: Project: Sample Matrix: I I Sample Name: Lah Code: I Analytical Method: Prep Method: I Analytc Name Mcrc111y. Total I I I I I I I I I I Pri111cd 12/ I 5/(Y..) I 7: IX COLUMIIIA ANALYTICAL SERVICES, INC. QNQC Report Domtar Industries Domtar Fonner Chlorine Plant/5171.04 Water CP-04-3 .10906031-0 I 8 245.1 Method Matrix Spike Sunun:.uy Mercury, Total (Cold Vapor, Manual) Service Request: 10906031 Date Collected: 12/2/09 Date Received: 12/5/09 Date Analyzed: 12/11/09 Units: µg/L llasis: NA Matrix Spike Duplicate Matrix Spike Sample Result ND Result 4.55 J0906031-MS2 Amount 0./4, Rec 5.00 91 Matrix Spike Sunnnary J090603 l-DMS2 1¼, Rec RPD Result Amount 11/0 Rec Limits RPD Limit 4.63 5.00 93 70 -130 2 20 Sup1.:rSct Reference: 09-000018)415 rev 00 I I Client: Project: Sample Matrix: I I S,1111plc Name: Lah Code: I Analytical Method: Prep Method: I Analytc Name I I I I I I I I I I Mercury, Total l'rintcd 12/15/09 t 7: 18 COLUMBIA ANALYTICAL SERVICES, INC. QA/QC Report Domtar Industries Domtar Fonner Chlorine Plant/5171.04 Water CP-02-1 J090603 l-025 245.1 Method Matrix Spike Summary Mercury, Total (Cold Vapor, Manual) Service Request: ]0906031 llate Collected: 12/2/09 Date Received: 12/5/09 Date Analyzed: 12/11/09 Units: µg/L Basis: NA Matrix Spike Duplicate Matrix Spike Sample Result 0.11 Result 4.85 J0906031-MS3 Amount 0/4, Rec 5.00 95 ,".1atrix Spike Summary J090603 I-OMS3 Result Amount 4.86 5.00 11/.i Rec Rl'D %1 Rec Limits RPD Limit 95 70 -130 0 20 I', In flow 2' S!a r li111s··, Li ms [{cp~IM ;i I rixSpi kt·. rpl Superset Rcfr1cncc 09-00001~-11) rn· 00 I I Client: Project: Sample Matrix: I I I Analyte Name Mercury, Total I I I I I I I I I I I I Printed 12/15/09 17:18 COLUMBIA ANALYTICAL SERVICES, INC. QA/QC Report Domtar Industries Domtar Fonner Chlorine Plant/5171.04 Water Lah Control Sample Summary Mercury, Total (Cold Vapor, Manual) Melhod 245.1 Lah Control Sample 10906031-LCS I Result Expected 0/4, Rec 5.15 5.00 103 Lab Control Sample Summary '1/o Rec Limits 85 -115 1 •• I allow 1 •'"""""'Lim, Reps' l~bCoo<ml S"" ,pie. o>< Service Request: )0906031 Date Analyzed: 12/9/09 Unils: µg/L Basis: NA SupcrSc! Rcti:rcncc: ()()-fJ(H1l\:)9·115 rev 00 I Clicnl: I Project: Sample Matrix: I I I Analytc Name Mercury, Total I I I I I I I I I I I Printed I 2/ l 5/09 17: 18 COLUMBIA ANALYTICAL SERVICES, INC. QA/QC Rcporl Domtar Industries Domtar Former Chlorine Plant/5171.04 Water Lab Control Sample Summary Mercury, Total (Cold Vapor, Manual) Method 245.1 Lah Control Sample J090603 i-LCS2 Result ExpectCd '½, Rec 5.03 5.00 101 Lab Control Sampk Summary 11/0 Rec Limits 85 -115 Service Requesl: 10906031 Date Analyzed: 12/11/09 Units: 11g/L Basis: NA I I I I I I I I I I I I I I I I I I I ! 2 3 4 (, ,. I ~ ,_ C) iO I I 12 13 14 15 Colun1hia Analytir:al Ser-\'ices, inc. Coo!~r Receipt Fonn Were custody seals on outside of cooler? If yes, how many and where9 Were seals intact and si[o•riature and date correct0 Were custody papers properly filled out? COC# TcmptTattire 0r cookr{s) upnn receipt \Vti\: Jc,_: (I!" ],,._-;.:: [\1ci::~ p-.--<:1: Did "11 h(,ri.lc::-Cl:'!"!VC !]1 g1,_•C••:! c;~;-;(:;;iun ( unhrc,l,:,:;~. T~ipc <i/'packin):: n~<i:cri;:;l pi·•.::::;ct,l -::1C. ,'! \Vcr-:.· (d ! honk i:1bc!~ C(1rnpick (_ s: i ;;7 !-~] C iD. i'.'i\S:..:;·,:;1'.i:1n. etc. Diel :il! hnttlc )uhei.s ;:1;id l<tgs c:grcc' ·,vi 1 h Cl..'.~;tndy pupl'.rs? \\·'en.: llic CCi!TC1.:l b(\ti.ks USl'(l Lr th•c tes!s indi•.:atl:d'? --, ,_ V,·'~~·~_,,dtt-1· ;he preseri't'd bc,aks rc.::(:i\·ec! with :he a;mrqJriat.:: pr•,'~.::;·\·ziti\'C .. ' -~ <2 H2S(JJ pH<: Zn.-\c~.r\'~:CJH rH:->9 N:-i0!-1 p/-1>1.:: (_ '. __ <.T• ;:ti,•-: ;1dditior1~ :1,.trd b~+•w --Were all samples recciH::cl \\·ithin analysis holding timcs··.1 Were VO:\ -,•iJi\ checked f"or a·:~scnc1.._. uf ,1ir bubbk::-;'.' ! f prt:Sl'ilt. llOLC bL'lO\\" \\'lie re did the houics origin,1tc? ( ( Yes ex: l on lid Yes Yc.s (7 Ve~ .. ·. k~· '; i,0 No No No 0. q r~~--- k·.:' ! ':::· '> \:,.1 NIA -- !<,.-\ Jv -e -fti h r, I Bubbl<e cv,r,_.f) ( ,-.cs) !~iu t~i:\ ( Y,-s') '.\t.' :<'A (\:~ ) ;'\(1 N1A ~.,c(i -'.?/') -~0) Ni:\ HCi pl-1<2 ~ i\"o N-::\ Yes Ne, (~ (c\S ' ) Clirnt Sample lD Reagent Lot# ml added Initials rDu·J-'\ HAio-, <\,,of.I;>. 0, \ )L. il/)/,,r, /v{c, C/J_o/-3R u,1J/ f,1.,)e,,Lr il, .,_ -, Sl /lh/c,; { '-'_;' j Additi0nal comments and/or ~~:planc.tion ofall discrepanc'.es noted aboYe: Client approval to run s:unpks if discrepancies noted: 12 Date: ' I -- - --- ---- -- - -- -- -- Bollie CO(!~ "I: ----· •tl,l ·•1:a I. - -----------CHAIN OF CUSTODY RECORD - - -77344 30 Patewood Drive, Suite 100, Patewood Plaza One, Greenville, SC 29615-3535 Phone 864/281-0030 • Fax 864/281-0288 Date Time Sample Station ID CP--I-J cP-11- IJDO cP-/o2--J- SPECIAL INSTRUCTIONS SA d y (Signature) /J-4-6? Date/Time Received by (Signotur fJ[x Relinquished by (Signature) Dale/Time Re~uished by (Signature) Date/Time Received by (Signatu Custody Seal: Present/ Absent Intact/Not Intact Seal #s F-268 (10/08) Filtered (Yes/No) Pre~erved [Code) WITH SAMPLES D Flammable 0 Corrosive 0 Highly Toxic 0 Other /list} WHITE-lABORATORY COPY Comments: C-H2S04 D-NaOH E-HCI F-METHANOL G- Turn Around (circle one) Normal Rush Report Due ___________ _ (For Lab Use Only) Receipt Temp: Temp Blank Y N YELLOW-REPORT APPENDIX Receipt pH (Wet/Metals) PINK-SAMPLER/SUBMITTER - - -----------------RNIT CHAIN OF CUSTODY RECORD 7 7 3 4 3 30 Patewood Drive, Suite 100, Patewood Plaza One, Greenville, SC 29615-3535 Phone 864/281-0030 • Fax 864/281-0288 Project/Client: Sample Stotion ID ci o I cP-Cfl-d-- SPECIAL INSTRUCTIONS SAM PL a lure) Dote/Time Received by (Signature) Dote/Time J-4-(jq Relinquished by (Signature) Dote/Time Refi,\quished by (Signature) Dote/Time c tY-. /J.-~-6~ Received by (Signature) f0Tirne /2-)09 I /3 Dote/Time Custody Seal: Present/ Absent Intact/Not Intact Seal #s F 268 (10/08) Preserved (Code) HAZARDS ASSOCIATED WITH SAMPLES D Flammable 0 Corrosive 0 Highly Toxic D Other [list) WHITE-LA.BORA.TORY COPY Comments: C-H2S0.4 D-NoOH E-HCI F-METHANOL G- Turn Around (circle one) Normal Rush Report Due ___________ _ (For Lob Use Only) Receipt Temp: Temp Blank Y N YElLOW-REPORT APPENDIX Receipt pH (Wet/Metal,) PINK-SAMPLER/SUBMITTER --·--RNIT ---------CHAIN OF CUSTODY RECORD ------77342 30 Patewood Drive, Suite 100, Patewood Plaza One, Greenville, SC 29615-3535 Phone 864/281-0030 • Fax 864/281-0288 Sample Station ID c.P-l/- P-1~- C D-D9- SPECIAL INSTRUCTIONS Date/Time R~~r t~Sig~;~~ -lf1 -llq Relinquished by [Signature) Date/Time R:::P: /L nature) Rel;:;;quished by (Signature) Date/Time Received by [Signature) Custody Seal: Present/ Absent Intact/Not Intact Seal #s F-268 (10/08) Date/Time Filteced [Yes/No) Preserved (Code) HAZARDS ASSOCIATED Turn Around (circle one) WITH SAMPLES D Flammable Report Due Comments: Normal C-H2S04 D-NoOH E-HCI F-METHANOL G- Rush 0 Corrosive (For Lab Use Only) □ Highly Toxic Receipt Temp: Receipt pH O Other (list) Temp Blank y N (Wet/Metals) WHITE-LABORATORY COPY YELLOW-REPORT APPENDIX PINK-SAMPlER/SUBMITTER - - - ----------- - - - -77341 RNIT CHAIN OF CUSTODY RECORD 30 Patewood Drive, Suite 100, Patewood Plaza One, Greenville, SC 29615-3535 Phone 864/281-0030 • Fax 864/281-0288 Project/Client: Lob No. Yr.cti Dole Time SPECIAL INSTRUCTIONS Sample Station ID Ds ignoture) Date/Time Received b (Si nature) Dole/Time ;}-L/-tf? ~( --oq Relinquished by (Signature) Dote/Time _!?le/Time rz)~;or /f3 Relin1:iui,hed by [Signature) Dote/Time Date/Time' Custody Seal: Present/ Absent lntocl/Not lntocl Seal #, Preserved (Code) HAZARDS ASSOCIATED WITH SAMPLES D Flammable D Corrosive D Highly Toxic D Other (list! Comments: Turn Around (circle one) Normal C-H2SOJ 0-NaOH E-HCI F-METHANOL G- Rush Report Due ____________ _ (For Lob Use Only) Receipt Temp: Temp Blank Y N Receipt pH [Wet/Metal,) - F-268 (10/08) WHITE-LABORATORY COPY YELLOW-REPORT APPENDIX PINK-SAMPLER/SUBMITTER 00 --- -- -- -- -- -- --Sample Collection Checklist for Domtar Former Chlorine Plant December 2009 Project: Domtar CAS Labs Project Number: 5171.04 Sample Date: Week of 12/7/2009 9143 Philips Highway, Suite 200 Jacksonville, FL 32256 Type of Turnaround: Standard Contac1: Tom Kissinger OC Package: N/A CP-01-2 CP-01-3 CP-0i•3A CP-02-1 CP-02-2 CP-04,1 C?-04-2 CP-05-1 CP-05-2 CP-06-1 CP-06-2 904-739-2277 lab 904-739-2011 fax X 54.8 X 12.1 X 30.2 X 11.5 X 30.2 X 50 X 10.8 X 30 X CP-07-1 12 x CP-07-2 30 x CP-08-1 12.5 x X X X X X X X X X X X X X RMT Project Manager: Mike Parker AMT Project Contact: Heather Smith AMT Alterna:e Contacts: Travis Tarbet Work Order Prepared By/Date: TAT 11/10/2009 Work Order OCed By/Date: HHS GROUNDWATER 1---'CccP~--"O"-B-cc2~-+----"'3"-0.c:8 __ -+----'x'---+----"-----I-----------------~ CP-08-3 50.98 x X CP-03-1 12.2 x CP-03-2 29.5 x CP·03·3 51 X CP·09·1 12 x C0·09·2 28 x CP·10-1 12 x CP·10·2 28 x CP·11·1 14 x CP-11·2 28 x CP·12-1 12 x CP·12·2 27 x CP·13·1 15 x CP•1.:!•1 16 x CP·15-1 ,'v1W•2 13 X MW•2·2 27 X Analytical Method: Analyze for total mercury using USEPA method 245.1 Sample Containers: 125 ml ultra clean glass bottle with HNO3 preservative. Volume: minimum 125 ml cou_ec_t),tiet~:d~·piiCiiteS:an9.):f!eiCf~1"a:~~~\-/'J·f~\~;t·- X X X X X X X X X X X X X X Abandoned 3/08 X X Rr-,1T. Inc. f Domtar Company C :()acLJm~n" .;nd Sor,mg••C,>l'lAT'L.-,c~I S~1M,;s:Tem))O'~'Y ln!ein~, FU•s'Ca,wnt 0u'IM-'OTFHG54DII llOMWD fl)"' - - - December 2009 I I I I I I I I I I I I I I I I I I I RMT North Carolina. Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 • Former Chlorine Plo11t Area l:l!l'f'GV/,IPJT,/IIJ-115/ 7 /i/1411)1//lf/2 Rf!/10.\17 f/l.t-0/1/ .f)OC\" B-1 Appendix B Field Notes .lw1w1ty 20 I 0 . .. . . ... . -·---···---·······--···"·-------····--·---· -········-· -·-····· -----· . ' ... . . ... . ---· ---··-----·-··-·. r·-----·····-·-· . . r~-};-"':cf ~fh'/ ~ 1/'o;r , 5'3 .. ······-·········· .. ·--· ................. -'-lQ11 ·~ HJ . .. . . .. . . . :~Q . f I _;__~("'() . ___ :: . -_ ... -~15~) ~-&-~01 w w···•····. ··y)nJL····. ···1s9. .. . .h9. · 1 Ll'.S. . . . bQ: 1-'e1 .· . .ij'J01-..... --.. --. .. -.. .. . . .. -. 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I I· .. i I ; j • i I ; ' ' I : I 'T-3,~to~ OVl>O ' : I i I : . l - ; \ i ' ·-------··--···-·· ------·--·-··---·· ·-·-.. . . -· --_iJJr .. ---··---·---·· ·····--··· ..... ·--Q39 ---------·--nG.-iL\s·· ..... ·5-Q~h::cr ---~ . ~CJ -■--... , ---... - -·-i ------■-'------"---~t______ca~__,,~~---==-b::1- •5J0 ·-· r -. . . .. . .. --1-·· bQ-z-te I I I I I I I I I I I I I I I I I I Well Repairs and Well Abandonment Domtar Paper Company Plymouth, North Carolina Below is a summary of the work perfmmed at the above site (12/1-12/3/09): Well Repairs l) Removed & replaced (4) 8" flush covers and J plugs 2) 5 wells -grouted in 2" PVC riser inside flush cover and put on J plugs 3) 4 wells -tapped out bolt holes and put in new bolts and new J plugs 4) 5 wells -cut down ½" wells and replaced J plugs 5) Total 1 plugs installed - I 8 Well Abandonments 1) (2) ½" wells -grouted to surface and pulled covers a) (1) -38 ft. deep b) (I) -40 ft. deep 2) (l) 4" well -plugged screen and grouted to surface -165 ft. deep - - ---RINIT - -- - - --··-CHAIN OF CUSTODY RECORD -a·:• 77344 30 Patewood Drive, Suite 100, Patewood Plaza One, Greenville, SC 29615-3535 Filtered (Yei/No) /N ./ / . / / / 7 / / . Phone 864/281-0030 '. Fax 864/281-0288 . Preserved {Code) / K / . / / /./ / / -;- Pro~tl7 /, OY Project/Client: 0Mv\ior 00, '. PRES~RVED CODES § . Project Man~Contact Pe7n: . ,;:,0 . ·A.~NONE r ~I . C,:.· B-HN03 5 C ~e; /Y'\ \ Vr trr H -::, /\ \ ' I'\ _r, 0 0"' C-H2S0, E .!: X '},.4-,<-; \ D-NoOH ~ J2 Yr,09 · Z C c< 0 \.,-.) - 0 ~ '?-<:'' · E-HCI lob No. .£ U· F-METHANOL ~o Date Time Sample Slalion ID· Comments: G C1/ .ocir~ /'(I (u-J -1:. I Gt, l 1/-._ I 1rAr;o (Y1UJ-.} . I ·. / '{_ I I ()O'( cP-6s-l I l Y, . . . /C'w() CP-D?,-J-. I . y_ I C'I-/Q cP-03-3 I y__ \ /OS\ cP--1I-I I 1' •• I \ II I fl cP-11 ° 1 I ( I 'i \ I l3C,: C P-b)., I I \ ' 'I, /JOO cP-/J.-J_ I \ . '{.._ /°ju-Cffe/o I I . --I 'K SPECIAL INSTRUCTIONS . \ -A -· · . R711-/-i\l -12:i 71 <_. . s:/L\ Rtt~Y/~g:~u~~ •Date/Time Received by [Signatun,J,/l Date/Time HAZARDS ASSOCIATED Turn Around (circle one)· Normal Rush ~(Jt K 11-(/-(fl WITH SAMPLES D Flommoble Report Due . Relinquished by (Signature) Dole/Time . Received by (Signature) Date/Time 0 Corro.sive [For Lab Use Only) . . □ Highly Toxic Relinquished by (Signature) · Dol~/Time Received by. (Signature) Date/Time □ Olhei llisl) Receipt .Temp: Receipt pH · . Temp Blank .Y N (WetiMetals) . Cuslody Seal: Present/ Absenl Intact/Not lnlact Seal#s ... F-268 (10/08) WHITE-LABORATORY COPY YEUOW-REPORT APPENDIX . PINK-SAMPLER/SU.BMITTER - -.. -RNIT --- - - -----CHAIN OF CUSTODY RECORD -·----------77343 30 Patel'1ood Drive, Suite 100, Patewood Plaza One, Greenville, SC 29615-3535 Filtered ~~s/Na) /4_(7 7 7 .· / / /· / / . Phone 864/281'0030 • Fax 864/281-0288 Preserved (Code] /P. / 7 -;; / / ./ / / Pro~tlli. oL/ Proiect/Client: \)r, -f · e,o PRESERVED CODES ,r'\\ :ar § A-NONE Proiec/\~a-g~:o:TI ;;o/ kl. S fA 1 ~ h ~e, ~ ~ q_..00:. ·. B-_HNO, ID ~ C-.H2S04 ..!l ID rz-" E .S >< ~-\' ..)'-0-NaOH Yr. Qj_ z~ o? /> \; - 0 j ~ t E-HCI lab No. _gu F-METHANOL Date Time Sample Station ID .20 ' Comments: G . /J/1 /C/C:.D fkL(-oqqo/ I !')I I\'. iG:,JQ cP-r:is--~ ( r,1, I I 1/. ' .. 10s c;-cP-bS-J. I I 1Y . lb~D cP-tiB-1 J Y.. I 1/00 C D-/\7 -I I 'f.._ . . . . Ill\ . C'D-bl-J. .. 'I-... I -. -. I 17-i~ tY\uJ~ IQ . I Y. /J_/_:i Of)?:,( cP-tJ-/-?, ( • I\! 1, L, cf:-F,D C P-Cf-1-d-I . I 'l. . IJ LJ-6q lf t0.. \ ,1----( SPECIAL INSTRUCTIONS \ /.......___ f\r SAMPLER R~in~uu ighature) Date/Time . Received by (Signature) Date/Time HAZARDS ASSOCIATED Turn Around (circle one) Normal Rush '-) I . ,, (_X_ /J . l/ -(jq r(Jt'I.. rJ-l/-oCJ WITH SAMPLES D Flammable Report_Due Relinquished by (Signature) Date/Time Received by (Signature) .Date/Time D Corro_sive IF.or Lob Use Only) . □ Highly Toxic Relinquished by (Signature) Date/Time ·. Received _by (Signature) · Date/Time Receipt Temp: _Receipt pH I D Other (list) Temp Blank y N (Wet/Metals) . . . . . . Custody Seal: Prese_nt/ Absent Intact/Not Intact Seal #s ·.· . F-268 (10/08) WHITE-LABORATORY COPY YELLOW-REPORT-APPENDIX PINK~SAMPI.ER/S_UBMIITTR --··-··-··-,_ RNIT -·-··-··-- -CHAIN Of CUSTODY RECORD -·:···-,···,-·,, .. _ .. ,,,.,_ ... ,,,,,._.,;,,,,-·•. . 77342 30 Pate\'lood Drive, Suite 1mi, Patewood Plaza One, Greenviile, SC 29615-3535 .· Phone 864/281-0030 • Fax 864/281-0288 Project No. 1 1 1 t:;, /1 6'1 Project/Client; D 1 · · · 0,rvn-a, · · Dote Tim.e Sample Stotion ID : SPECIAL INSTRUCTIONS SAMPL~ Rf/inqu1h J y'ISignalure) Date/Time "1\,U/ X Ll-~-l)q ' Relinquished by !Signature) Date/Time Received by !Signature) Relinquished by !Signature)· Date/Time Received by !Signature) Custody Seal: Present/ Absent · In.tact/Not Intact Seal #s ,, ' F-26B (10/08) . Date/Time Date/Time . Date/Time . ~--'--fi-'-lter-ed-lYe-s/N~o)_/4...,./7--'-r· -✓.,..,,-7....:,. -/~· ,-/-,-, .. -/-. ,-. /----,---,,-/- · Preserved !Code) /i / · / -/ / / / · / · / ' ' .. ,. ' ' ' ' ' ' ' · comments: .. ' ', ' ' PRESERVED CODES .'A-;NONE --~-_:HNO3 C-H2S04 D-:: NaOH E-HCI , F '--METHANOL . G HAZARDS ASSOCIATED , WITH SAMP(ES • Turn Around (circle one) Normal · Rush 0 Flommoble . 0 Corrosive □ Highly Toxic O Other (list) :Report Due ------'--'--'---'-----'- . I . WHITE-lABORATORY COPY. !For Lab Use Only) Receipt Terrip: Temp Blank Y N YELLow,.:REPORT APPENDIX Receipt pH (Wet/Metals) PINK-SAMPLER/SUBMITTER ' - - ---RNIT ---·----CHAIN OF CUSTODY RECORD -· ---····,-·,,-, 77341 - 30 Patewocid Drive, Suite 100, Patewood Plaza One, Greenville, SC 29615,3535 filtered (Ye,/No) /4/ / / / / / /7 / Phone 864/281,0030 • Fax 864/281-0288 Preserved (Code) /1~ / / / / / / / / Project/ Client: I_) i. Prot:_t/~/. ['}{ ,,,o I (){\1\-+~r-PRESERVED .CODES § .. Proje/~~onoµ:~nr:~r7 M. 0 . . A-NONE ·d! B-HN03 ~f\s-~ 1-~ ~ q_.0 ~ ~ C-H2S04 · -" ~ 0" E . =: X ),,.4,,' D-NaOH ~ 2 Z C i,2 '?-~◊ ~" Lob No. YrO9 - 0 ~ E-HCI J2U /-METHANOL ,Q 0 Date Time Somple Station ID Comments: G i:l L-,, I s:S <::" c~-a9-J.,, I ;;,, ) 't I I :<,c_ C:::: CP-IDsl I I 1 I c../ I 1'i cP-10-J-I \ '{ \ llfJO f'.'.'." 8,LV -6qi_/ O?, I l:ir l'i \ 17/n cl)-6 I-ZR I GuJ 'l . . - . --i 'iU-Cffl/ Os I 0.JJ X .. SPECIAL INSTRUCTIONS \ .------.. -. SAMPLE} Rf tjhe~ ~y f ignature) Date/Time · Received by (Signature) Date/Time HAZARDS ASSOCIATED Turn Around (circle one) Normal Rush "v. -II \.I i.J-L/-(f1 ~eJt'i'. IJ-l/-oq WITH SAMPLES D Flommoble · Report Due Relinquished by (Signoture) Date/Time Received by (Signature) Dote/Time D Corrosive (For Lob Use Only) · . · D Highly Toxic Relinquished by (Signature) Dote/Time Received by (Signature) Date/Time D · Other (li,t) Receipt Temp: Receipt pH · Temp. Blank y N (Wet/Metals) ' . Custody Seal: Present/ Absent lntoct/Not Intact Seal#s . : . · . .· . .. F-268 (10/08) .. WHITE-LABORATORY COPY YELLOW-REPORT APPENDIX PINKC..SAMPLER/SUBMITTER I I I I I I I I I I I I I I I I I I I RMT North Caroli 110, Inc. I Domtar Paper Company, LLC Mo11i10ri11g Report OU-3 -Former Chlorine /'/ant Arca I:\ tr'!'G l'l If' J]'.{JIJ-I) 5 / 7 / ll).fl/H/()l/2,Rf!l//151 71 IJ.I. f}(! I. DOCX C-1 Appendix C Photographic Log Ja1111my 2010 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. Description MW-2 Photo No. 2 Description MW-2-2 Date 12/01 /09 Date 12/01/09 RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area /·\WPGVL\PJ71()().0J 171\04\00001\ROOOJ/ 7104-001.DOCX C-2 Jan11a1y 2010 I I I I I I I I I I ,, I I I I I I I I Photographic Log Photo No. 3 Description CP-11-1 Photo No. 4 Description CP-11-2 Date 12/01/09 Date 12/01/09 RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area l:\WPGVL\PJnOQ.nJ / 7 l l/J4\00(){)}1R(){){)J 17104-001.DOCX C-3 Januaty 2010 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. 5 Description CP-07-1 Photo No. 6 Description CP-07-2 Date 12/0 1/09 Date 12/0 1/09 RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area /:\WPGVL\P.fT1()().0J 171'1!41/)()()()]\R(/()()J 17 /04-00/.DOCX C-4 January 2010 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. 7 Description CP-08-3 Photo No. 8 Description CP-08-1 Date 12/01 /09 Date 12/0 1/09 RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area i'\WPGVL \P .171()().05171\04100001\ROOOJ I 7104-1/01.DOCX C-5 Janumy2010 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. 9 Description CP-12-2 Photo No. 10 Description CP-12-1 Date 12/01/09 Date 12/01/09 RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area l:\WPGVL\P J11(J().05/ 7 /11!4\00002\RO/)/)J 17104-00/.DOCX C-6 January 2010 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. 11 Description CP-05-1 Photo No. 12 Description CP-05-2 Date 12/02/09 Date 12/02/09 RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area l:\WPGVL \Pf/1()().0J I 7 l\/J4\(J()()()]\R/J/JOJ 17 /04-001.DOCX C-7 January 2010 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. 13 Description CP-02-1 Photo No. 14 Description CP-02-2 Date 12/03/09 Date 12/03/09 RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area l·\WPGJIL \PJnOO-O!J/ 7 /\()4100001\ROOO!J I 7 /04-00/.DOCX C-8 January 2010 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. 15 Description CP-0l -3R Photo No. 16 Description Date 12/03/09 Date 12/03/09 CP-08-2 replaced surface completion. RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area l:IH'PGVL\P .171()().05/ 7 /104\000011R0005/ 7 /04-001.DOCX C-9 Jan11a1y 2010 I I I I I I I I I I I I I I I I I I I Photo No. 17 Description CP-03-1 Photo No. 18 Description CP-03-3 Date 12/03/09 Date 12/03/09 Photographic Log RMT North Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area C-10 l:\WPGVL\PJ71/)().05/7 /\04\(l()(}/}2\R()/)/)5/ 7/04-00I.DOCX Janua,y 20 I 0 I I I I I I I I I I I I I I I I I I I Photographic Log Photo No. 19 Description CP-03-2 Photo No. 20 Description Date 12/03/09 Date 12/03/09 CP-04-1, CP-04-2, and CP-04-3, replaced surface completions. RMT Nor1h Carolina, Inc. I Domtar Paper Company, LLC Monitoring Report OU-3 -Former Chlorine Plant Area l:\WPGVL\P JT1()().0J 17111)4\0000llR()(l()J 17 /04-1)0/,DOCX C-11 January 20/0