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HomeMy WebLinkAboutNCD980843346_19910806_Aberdeen Pesticides Dump_FRBCERCLA ROD_Record of Decision OU-2-OCRI I I I I I I I I I I I I I I DRAFlj \'i;;;:~~~·•.:.,i,·-~·" ______ , ____ ,'-'-....:..._". --. [BECORD OF DECISIOH OPERABLE UNIT ONE SURFACE AND SUBSURFACE SOIL CONTAMINATION AKEHDED RECORD OF DECISIOH OPERABLE UNIT TWO STOCKPILE OF CONTAMINATED SOIL -FAIRWAY SIX AREA AUG O 6 1991 .----- ABERDEEN PESTICIDE DUMPS SITE OPERABLE UNIT ONE MOORE COUNTY, ABERDEEN, NORTE CAROLINA PREPARED BY TEE U.S. ENVIRONMENTAL PROTECTION AGENCY REGION IV ATLANTA, GEORGIA THIS RECORD OF DECISION CONTAINS TEE FOLLOWING PARTS: PART I -'l'BE DECLARATION PART II -'l'BE DECISION SUHKARY PART III -THE RESPONSIVENESS SUHKARY AUGUST 1991 PART ,I, --DECLARATION FOR THE RECORD OF DECISION (ROD) site Name and LOcation Aberdeen Pesticide Dumps site (Operable Unit One) Aberdeen, Moore County, North Carolina statement of Basis and Purpose This decision document represents the selected remedial action for the Aberdeen Pesticide Dumps Site developed in accordance with the Comprehensive Environmental Response, compensation and Liability Act of 1980 (CERCLA), as amended by the superfund Amendments and Reauthorization Act of 1986 (SARA) and, to the extent practicable, the National Oil and Hazardous Substances Pollution contingency Plan (NCP). This decision is based upon the contents of the administrative record for the Aberdeen Pesticide Dumps site. The State of North Carolina concurs on the selected remedy. Assessment of the site Actual or threatened releases of hazardous substances from this site, if not addressed by implementing the response action selected in this Record of Decision (ROD), may present an imminent and substantial endangerment to public health, welfare, or the environment. Description of the Selected Remedy This interim remedy addresses source control of groundwater contamination via soil contamination by eliminating or reducing the continuing risks posed by the site. The major components of the selected remedy include: 0 0 0 0 0 0 0 0 0 Treatability study using ex-situ thermal desorption; Excavation of an estimated 99,193 cubic yards of contaminated soil; Decontamination of 123,933 cubic yards of contaminated soil from all areas comprising the site using on-site ex-situ thermal desorption process (includes 3200 cy and 22,000 cy of previously excavated and stockpiled contaminated soil at the Mciver and Fairway Six Areas, respectively); Proper transportation and storage of RCRA hazardous wastes; Treatment.of the concentrated organic contaminants, which will be vendor specific; Sample and analysis of the treatment residue; On-site disposal of the non-hazardous treated soil into the original excavated areas, backfilling with soil to grade and. revegetation with native grasses; On-site solidification and disposal of treatment residue remaining hazardous after thermal treatment; and sample and analysis of potential trench areas at Farm chemicals, Fairway Six and Twin Sites Areas; I I I I I I I I I I I I I I I I I I I -I I I I I I I I I I I I I I I 0 Lateral and vertical characterization through sample and analysis of Mciver Area C; and ·0 Asbestos removal and building demolition at the Farm chemicals Area and proper disposal of building debris offsite. Description of the Contingency Remedy The contingency remedy includes all items under the selected remedy with the exception of the treatment technology. Incineration will be used to treat the contaminated soil should the results of the treatability study conclude that thermal desorption is ineffective in rendering the soils non-hazardous or proves to be cost prohibitive. Description of the ROD Amendment for Operable unit Two, now designated as Operable unit Four A Record of Decision for Operable Unit Two signed by Region IV'S Administrator on June 30, 1989 is amended to fundamentally change the selected remedy from incineration to thermal desorption. A contingency remedy, incineration, will apply should thermal desorption not meet EPA's criteria, in which case the contingency remedy would be implemented. Operable Unit Two, now designated as Operable Unit Four, will be combined with Operable unit one for the purpose of excavation and treatment of contaminated soils at the site. statutory Determinations The selected remedy and the contingency remedy are both protective of human health and the environment, complies with Federal and state requirements that are legally applicable or relevant and appropriate to the remedial action, and are cost-effective. The selected and contingency remedies utilize permanent solutions and alternative treatment (or resource recovery) technology to the maximum extent practicable, and satisfies the statutory preference for remedies that employ treatment that reduces toxicity, mobility, or volume as a principal element. Because neither of these remedies will not result in hazardous substances remaining on site above health-based levels, the five-year facility review will not apply to this action. Greer c. Tidwell Regional Administrator Date I I I I I I I I I I I I I I I I I I PART II -THE DECISION SUHHARY TABLE OF CONTENTS section Page 1.0 SITE NAME, LOCATION, AND DESCRIPTION ••••••••••••••••••••••••••••••l l. l Farm chemicals Area •••.•••••••••••••••••••••••••••••••••••••••• 1 l. 2 Twin Sites Area ••••••••••••••••••••••••••••••••••••••••••••••• 3 l. 3 Fairway Six Area .............................................. 4 1. 4 Mc Iver Area •••••••.•• _ ••••••••••••••••••••••••.•.•.•.•.••• -.-.-.-••••••• 4 Ls Route 211 Area •••••••••••••••••••••••••••••••••••••••••••••••• 4 ·2.0 SITE HISTORY AND ENFORCEMENT ACTIVITIES •••••••••••••••••••••••••••8 2 .1 site History •••••••••••••••••••••••••••••••••••••••••••••••••• 8 2. 1. 1 Farm Chemicals Area •••••••••••••.•••••••••••••••••••.••• 8 2. 1. 2 Twin Site Area •••••••••••••••••••••••••••••••••••••••••• 9 2. l. 3 Fairway six Area ••••.•••••••••••••••••••••••••••••••••• 11 2. l. 4 Mc Iver Area ••••••••••••••.••••••••••••••••••••••••••••• 12 2.1.5 Route 211 Area ..•••.••••••••..•••.•.••••••••••••••••••• 14 2 .2 Enforcement Activities •••••••••••••••••.••••••••••••••••••••• 14 3.0 HIGHLIGHTS OF COMMUNITY PARTICIPATION ••••••••••••••••••••••••••••15 4.0 SCOPE AND ROLE OF OPERABLE UNITS WITHIN SITE STRATEGY •••••••••••• 16 5. 0 SUMMARY OF SITE CHARACTERISTICS •••••••••••••••••••••••••••••••••• 17 5 .1 Farm Chemicals Area •••••••••••••••••••••••••••••••••••••••••• 17 5.2 Twin Sites Area •••••••••.••••••••••••••.•.••••••••••••••••••• 22 5. 3 Fairway six Area ••••••••••••••••••••••••••••••••••••••••••••• 2 8 5.4 Mciver Area •••••••••••••••••••••••••••.•••••••••••••••••••••• 34 5 • 5 Route 211 Are a .•••••••••••••.•••••••••.•••••••••••••••••••••• 4 0 6. 0 SUMMARY OF SITE RISKS •••••••••••••••••••.•••••••••••••••••••••.•• 45 6 .1 contaminants of concern ............. ~ ........................ 45 6.2 Exposure Assessment .......................................... 47 6.3 summary of Toxicological criteria •••••••••••••••••••••••••••• 51 6. 4 Risk characterization ••••••••••••••••••••••••••••••••••••••• ·• 53 6. 4 .1 Farm Chemicals Area •••••••••••••••••••••••••••••••••••• 53 6.4.2 Twin sites Area •••.•••••••••••••••••••••••••••••••••••• 55 6.4.3 Fairway Six Area ••••••••••••••••••••••••••••••••••••••• 57 6.4.4 Mciver Area •••••••••••••••••••••••••••••••••••••••••••• 57 6.4.5 Route 211 Area ••••••••••••••••••••••••••••••••••••••••• 57 • i TABLE OF CONTENTS CONTD s.ection Page 7. 0 DESCRIPTION OF ALTERNATIVES ••••••••••••••••••••••••••••••••••••••• 61 8.0 SUMMARY OF COMPARATIVE ANALYSIS OF ALTERNATIVES ••••••••••••••••••• 72 9 • 0 THE SELECTED REMEDY •••••••••••••••••••••••••••••••••••••••••••••• 7 6 9 .1 Common Elements •• , •..•••••••••••••••.•.••.•••••••• ; ..•.•.••. 76 9 .2 Elements Unique to Each Area ................................ 86 9.3 Contingency for soils Remediation •.••......••..••••••••••••• 89 10.0 AMENDMENT TO OPERABLE UNIT TWO RECORD OF DECISION •••••••••••••••• 90 11. 0 THE STATUTORY DETERMINATIONS ••••••••••••••••••••••••••••••••••••• 9 3 11.1 Protection of Human Health and the Environment •..••••••••••• 94 11.2 compliance with Applicable or Relevant Appropriate Requirements ......................... 9 4 11. 3 Cost-effectiveness •••••••••••••••••••••...•...•.•••.•••••.•• 94 11.4 utilization of Permanent Solutions and Alternative Treatment Technologies or Resource Recovery Technologies to the Maximum Extent Practicable ............•.........•.... 95 11.5 Preference for Treatment as a Principal Element ........•..•• 95 ATTACHMENT State Letter of Concurrence ii I I I I ' I I I I I I I I I I I I I I I Figure I Figure 1. Figure 2. Figure 3. I Figure 4. Figure 5. Figure 6. I Figure 7. Figure 8. I Figure 9. I Figure 10. I Figure 11. Figure 12. I Figure 13. I Figure 14. Figure 15. I Figure 16. Figure 17. I Figure 18. Figure 19. Figure 20. I Figure 21. I I I I I I FIGURES Page site Map -Aberdeen Pesticide Dumps Site ••••••••••••••.•• 2 Site Layout -Farm chemicals Area ••••••••••••.••..••••••• 3 Site Layout -Twin Sites Area ••••••••••.•..•••••....••••• 4 site Layout -Fairway six Area .•••...•.•••••••••.•••••••• 6 Site Layout -Mc Iver Area •.••••..•..•..•••••••••••••••••. 6 Site Layout -Route 211 Area •••••••••......•••••.•••.•..• 7 Total Pesticide Concentrations In surficial and Subsurface soils and Location of suspected Buried Trenches-at the Farm chemicals Area •••••••••••.••••••••• 20 Area of Contaminated soil Reguiring Remediation at the Farm Chemicals Area ••.•••.•••••••••••.•.•••••••••••• 2 3 Total Pesticide Concentrations In surficial and subsurface soils and Location of suspected Buried · Trenches at the Twin Sites Area .••••.•••.•.••••.•••.•••. 27 Area of Contaminated Soil Reguiring Remediation at the Twin Sites Area ••••...•.••..•.•...•......••.......•. 29 Total Pesticide concentrations In surficial and Subsurface Soils and Location of suspected Buried Trenches at the Fairway Six Area •••••••••••••••••••••••• 33 Area of contaminated Soil Reguiring Remediation at the Fairway Six Area •••••••••••••••••••••••••••••••.•••• 35 Total Pesticide concentrations In surficial and subsurface Soils at the Mciver Area ..•••.•••....•...•.•• 38 Area of contaminated soil Reguiring Remediation at the Mciver Area ••••••••••••••••••.•••••••••••••.•••••••• 41 Total Pesticide concentrations In surficial and Subsurface Soils at the Route 211 Area ••••••••••••••••.• 44 Area of Contaminated soil Requiring Remediation at the Route 211 Area .....•...•••.•.•.•.••.•••••.•..•...•.. 46 Area Reguiring Excavation at the Farm chemicals Area •.•• 78 Area Reguiring Area Reguiring Area Reguiring Area Requiring Excavation at Excavation at Excavation at Excavation at iii the the the the TWin sites Area •••••••• 7 8 Fairway six Area ••••••• 7 9 Mciver Area ............ 7 9 Route 211 Area .......•. 8 0 Table Table l. Table 2. Table 3. Table 4. Table 5. Table 6. Table 7. Table 8. Table 9. Table 10. Table 11. Table 12. Table 13. Table 14 • . Table 15. TABLES sample Matrix for the Farm chemicals Area •••••.••••••••.• 17 Significant Contaminants and Their Maximum Concentrations at the Farm Chemicals Area ..••••••..•••••• 18 Sample Matrix for the TWin sites Area •....••..•..•.•••••• 24 Significant Contaminants and Their Maximum Concentrations at the TWin Sites Area .....••...•••••••••. 25 sample Matrix ~or the Fairway Six Area ..••••••••••.•••.•. 30 significant Contaminants and Their Maximum Concentrations at the Fairway six Area .•.••.•.••••••••••• 31 Sample Matrix for the Mciver Area .•.•••••••.•..•••••.•.•• 36 Significant contaminants and Their Maximum concentrations at the Mciver Area •••.•..•••••••......•.•• 37 sample Matrix for the Route 211 Area ••••..••••••••••••••• 40 Significant contaminants and Their Maximum Concentrations at the Route 211 Area ...•••••••....••••••• 42 Contaminants of concern and Exposure Concentrations For All Environmental Media •••••.•.•....••••••••••••••••• 48 Estimated Exposure Frequencies For Target Populations Under Current and Future Land Use Conditions •••••• : •••..• 50 Exposure Time or Ingestion Rate Per Event ••.••••••••••••. 50 summary of Toxicological Criteria •••••.•..•.•.••••••••••. 52 current Land Use Risk Characterization - Farm Chemicals Area ••••••••••••......••• _ ••••••••...•••••• 54 Table 16. Future Land Use Risk characterization - Table 17. Table 18. Table 19. Table 20. Table 21. Table 22. Table 23 •· Table 24. Table 25. Table 26. Table 27. Table 28. Table 29. Table 30. Table 31. Farm chemicals Area •••••..•..•••.•••••••••••..••••••••••. 54 Current Land Use Risk characterization -TWin Sites Area .56 Future Land use Risk Characterization -Twin sites Area .. 56 current Land use Risk characterization - Fairway Six Area ......................................... 58 Future Land Use Risk characterization -Fairway Six Area .58 Current Land Use Risk characterization -Mciver Area ..... 59 Future Land Use Risk characterization -Mciver Area ...... 59 Current Land Use Risk characterization -Route 211 Area .. 60 Future Land Use Risk Characterization -Route 211 Area ••• 60 Summary of the Comparative Analysis of the Alternatives •. 74 Cost Summary for Alternative 7-Low Temperature Thermal Desorption •••.••••••..•...••••••••..••••••••••••• 77 Volume of Material Requiring Remediation for cleanup to 10-6aealth Based Levels at Each Area •••••••• 80 Lifetime Excess Cancer Risk Target cleanup Goals I I I for soil at Each Area ••.••••••••••••••.•••••••••.•••.•.•.• 81 Alternate Treatability Variance Levels and Technologies for structural/Functional Groups ••••••••••......•••••••••• 85 Maximum Allowed Concentrations for RCRA Delisting Decision Making •••••••.•.•.••..••••...•.•••••••••••••••.•• 87 cost Summary for the Contingency Remedy .•••••••.••....•..• 91 iv I I I I I I I I I I I I I ! I I I I I I I I I I I I I I I I I I I l.0 SITE NAME, LOCATION AND DESCRIPTION The Aberdeen Pesticide Dumps Site (the •site"), consisting of five distinct areas, is located near the town of Aberdeen, Moore County, North Carolina (Figure l). The five separate areas are Farm Chemicals, Twin Sites, Fairway Six, Mciver and Route 211. All of the areas are located in the •sandhills Region• of the Atlantic coastal Plain Province. The Region is characterized by rolling hills with 200-300 feet of topographic relief. The primary aquifer in the Aberdeen area, the sandhills aquifer, is comprised of both the Middendorf and, where present, the overlying Pinehurst Formations. _The thickness of the aquifer varies with topographic relief and ranges_from a few feet in the stream valleys to 300-feet at the crest of the higher ridges. Soils in the area of the five sites belong to the candor series. Characteristics of this series are well to very well drained sandy surface soils and sandy to sandy clay loam soils of the coastal Plain uplands. These· sandy soils have excellent permeability and are ineffective as filters when used for waste disposal. According to the 1980 census, the population within the study area is about 2,000. However, more recent information obtained from the Town of Aberdeen indicates that the population in 1988 was about 2,735. Groundwater is the main water supply within a three mile radius of Aberdeen. Twelve municipal water wells operated by the Town of Aberdeen draw water from the sandhills aquifer. The system currently has l,640 hookups, but the exact number of people served is unknown. However, the Town Manager estimates that about 3,500 people are served by the Town supply. The remaining population of about l,5O0 -2,000 people are served by private·wells. The Aberdeen area is primarily residential with some light industry. The Twin, Fairway Six, and Mciver Areas are all zoned residential, while the Farm Chemicals Area is zoned commercial/residential. The Route 211 Area is zoned industrial, being included in a small strip of land which offsets the railroad tracks with an industrial zoning. The area outside this industrial zoning is zoned residential. The primary recreation in the area is golf with 36 championship golf courses within a 10-mile radius of Aberdeen. There are no endangered species or critical habitats, national parks, national wildlife refuges or Indian reservations in the vicinity of Aberdeen. Four of the five areas are in the Aberdeen creek drainage basin. The Route 211 Area is outside the drainage basin. Aberdeen creek is a north - south flowing tributary to Drowning Creek with a drainage area of approximately 38 square miles. Figure 1 shows the location of each area and the Town of Aberdeen. The site location and description of each area are summarized below. 1.1 Farm Chemicals Area The Farm Chemicals Area is located immediately south of North Carolina Highway 5 (Pinehurst Road), on the western corporate limit of the I fly SWy {RIIFS) • "'Carvlln■ " IJ.!;f/!11; --1----, -' .. SCALE: \00, XO)l'Ul ~ --- \ I I I I I I I I I I I I I I I I I I I Town of Aberdeen, and west of Pages Lake (Figure 2). latitude 35°08'24"N; longitude 79°25'58". According the estimated population within a 1-mile distance of than 1,000. Coordinates are: to the 1980 census, the area is greater The Area is situated on flat terrain •• However, downgradient (north) of the Area and at a distance of approximately 500-700 feet is Pages Lake, which is used far swimming, fishing, and general recreational use. It is a man-made body that is fed by Aberdeen Creek, which flows to the south. The land to the south and west of the Area is occupied by commercial or light industrial properties. Residential property bounds the .Area to the east. The nearest residents live approximately 250 feet-from-the-Area. North of the Area is Highway5and directly across Highway 5 is the Twin Site Area. The Area accommodates an abandoned chemical blending facility consisting of 14 structures. 1.2 Twin Sites Area The Twin Site Area lies immediately north of Highway 5, at the western corporate limit of the Town of Aberdeen, and west of Pages Lake. Coordinates of the Area are: latitude 35°08'24"N; longitude 79°25'58"W. The estimated population within a 1-mile distance of the Area is greater than 1,000. ABERDEEN HOSIERY AEPCO Not1h @ Allnldlal ffi11llgltlcn'Ft1slblllty SI\J!tr (RLf'S) Aberdeen Pttllddt Dumps S111 Awdttn, Moon County, North Clrollnt SCALE: Figure 2. Site Layout -Farm chemicals Area. 3 The Twin Sites Area·consist of three disposal areas (Figure 3). Area A and Bare both open dumps within wooded areas. Area A is approximately 400' x 250'; Area Bis approximately 235' x 120'; and the two areas lie approximately 350' from one another. Pesticide-like materials are buried and partially visible in a small patch of woods in Area c.between Areas A and B. Since most of the pesticide-like materials are buried, the dimensions cf Area Care unknown. The Twin sites Area is situated on moderately sloping terrain (5%) in a N-NE direction towards Pages Lake. Pages Lake is about 350 feet downgradient from the disposal areas. Groundwater seeps and standing water pools are formed between the disposal areas and Pages Lake. south of the Area is Highway 5. East of the Area is wooded property. A road bounds the western edge of the Area. North of the Area is Pages Lake. The nearest residents live about 350' upgradient from disposal Area B. A Jaycees But and Boy scout camp are located 350' downgradient of the Twin Sites Area. Although the Jaycees But had not been used since 1985, the facility has been used as a day center by a drug rehabilitation group since August 1990. The Boy scout camp is used 2-3 times per week for scout meetings and activities, but is not used as a camping area. However, during a recent EPA site visit a newly constructed beach area was observed directly downgradient of the Boy Scout Camp along the western shore of Pages Lake. AEPCO = NORf"OU( 1--... -"-h--l Remedlll lnve1tlg1t100'F111lblllty Study {RllfS) AbenSetn Ptstlcldt Durnpt s11, @ --Coon~.-Cnllna -370,--Elevatlon (FNt. Mean Sea leveT) (-_: ', Arau of Densa Vegetation Fence SCALE: f • 1 Figure 3. site Layout -Twin sites Area. PAGES LAKE -·- +- I I I i I I I I I I I I i I I I I I I I I I I I I I I I I I I I I I I 1.3 Fairway six Area The Fairway six Area is situated off NC Highway 5 west at "The Pit• Golf Links. coordinates of the area are latitude 35°08'~0"N; longitude 79°27'27"W. Located about 1.6 miles west-northwest of the Aberdeen Corporate limits, the Area is rural and sparsely populated. The estimated population within a 1-mile.distance of the Area is less than 1,000. The Area consists of a cleared area utilized during a test burn conducted in December 1986, an area of surface contamination (approximately 345' x 225') on the south and north sides of Fairway No. 6 immediately adjacent to the tee area, and six excavated trenches (Figure 4). The Area is-•bound-to the north by the-P"it · Golf Links golf course. South, east and west of the Area is wooded property which is privately owned and was once planned for residential development. At the Fairway Six Area, the general topography dips gently to the northeast (1.5% grade) towards the golf course lake. Two swells drain surface water from the area of known contamination. Due to prior removal actions at the Area, surface runoff from the immediate area drains into the existing trenches. 1.4 Mciver Area The Mciver Area is located approximately 0.5 mile north of the junction of SR 1112 and SR 1106, west of Aberdeen (Figure 5). The coordinates are approximately latitude 35°07'40"N; longitude 79°27'40"W. The estimated population within a 1-mile distance of the Area is approximately 300. Situated in a sparsely populated rural area, the Mciver Area consists of three disposal areas: Area A -primarily a rubble dump known as "Luck's Landfill". Area B -also known as the "bag site" consist of a natural depression approximately one acre in size and 15 feet deep. Area C -located between Areas A and B covers approximately 22,000 square feet. Land use in the area is primarily agricultural. other land use in the area is the landfill itself (Area A) and a borrow pit nearby that is used by Bill Luck. The Area is bound to the north by an unnamed tributary of Aberdeen creek. This tributary lies approximately 100 feet north of Area Band flows east-southeast into Aberdeen creek. 1.5 Route 211 Area The Route 211 Area is located in Moore County approximately 1 mile east of the Town of Aberdeen (Figure 6). It is in a wooded area roughly 1,000 feet southwest of Route 211 East and is accessible by an unpaved road. The coordinates of the Area are latitude 35°07'02"N; longitude 79°23'4l"W. - - ) > ~ ~~ "'-+ '--- -,_- + ---~c,-.--~ ,:::.---........... c,1---- FIGURE 'I. site Layout -Fairway Six Area. --Ill .. - ------ AEPCO :::: ::::'!."';!;.":"--. IM1l l'?77h Arni of R-,noval ,..,._,..._C....,,Ml>IIIIC...... "<-"LP Action SCAlf: • "'"' - FIGURE s-·. Site Layout -Mciver Area. - - .. -- -- I I I I I I I I I I I I I I I I I I I AEPCO North @ II i" D -::::- ---------- Aemedlal rrtt1tigallon'Fuslb11Uy Study (RI/FS) Aberdeen Pt1llclde Dumps su, Abtrdttn, Moorl County, Nol1tl ClfOIINI I = --450---Elevation (Feet, Mean Sea Lewi) ~ Surface Depreuion EEffi Commerclal/lndustrlalFacllity ■ Buildlng SCALE: O Figure 6. site Layout -Route 211 Area. , .. - The Area is an old sand mining pit or basin, the bottom of which approximates a circle 78 feet in diameter and 8-20 feet deep. The area of contamination is estimated to be approximately 0.11 acres. The Area _is located in a sparsely populated area. The land surrounding the Area is generally pine woods with scattered abandoned sand-mining pits. The Area is approximately 1,000 feet southwest of Route 211 East and 100 feet northeast of the main track of the Aberdeen and Rockfish Railroad. TWo active commercial/industrial facilities are known to be located within 1,000-2,000 feet·of the Area. The nearest homes are located 0.25 to 1 mile from the Area. The population within 1 mile of the Area was estimated at 543 residents. The Area is basically a basin, separated from surface water by areas of higher elevation. However, groundwater in the area may be threatened by the site contaminants. Two community water supply systems use groundwater within 3 miles of the Area. Homes and businesses not served by community systems are believed to be on private wells. Local well logs show the upper portion of the aquifer to be the source of drinking water. The water table is as high as 15 feet below the land surface. l 2.0 SITE HISTORY AND ENFORCEMENT ACTIVITIES 2.1 site History 2.1.1 Farm chemicals Area Pesticides were produced at the Farm chemicals Area plant from 1936 to 1978. Taylor Chemicals owned and operated the plant from 1936 to 1964. In 1964, Grower Service bought-out Taylor Chemicals. Grower Service, operating under the name E-Z Flo and a subsidiary of union Carbide, operated the facility until it was purchased by Farm Chemicals, Inc. in 1972. Farm Chemicals, Inc. is the current owner. Taylor Chemicals was reportedly one of the largest pesticide product distributors in North Carolina in tpe 1940s. Their operations consisted of purchasing technical grade pesticide dusts and blending them with fillers such as sodium bicarbonate for application under the br_and name •superkill•. In 1955, Taylor chemicals registered over 60 different grades of superkill. The number of registered superkill blends increased to between 90 and 110 during 1962-1965. Raw pesticide materials included sulphur, DDT, toxaphene, parathion, aldrin, benzenehexachloride (BHC), chlordane, dieldrin, endrin, and malathion. Among Taylor's major products were cotton dust 3-5-40 (3% BHC, 5% DDT, and 40% sulphur), 20% toxaphene dust, and 60% tox~phene dust. During Farm Chemicals' ownership, the plant was known in the chemical industry as a blending, as opposed to a manufacturing plant. The blending process was an all-liquid one. Basically, the plant purchased raw materials such a parathion, EPN, and toxaphene from·standard vendors in the industry, mixed these raw materials in desired combinations (along with an emulsifying agent) to produce a marketable product. The products were principally soil micronutrients and insecticides for cotton· producers. Storage containers for the products were· either 55-gallon steel drums, or 5-gallon (usually plastic) containers of micronutrients. The mixing-blending process utilized a 2,000 gallon mixing vat in which desirable ratios of technical materials were combined with an emulsifying agent to produce a marketable product. The end product was then placed in 55-gallon steel drums, sealed, labeled and placed in above-ground storage until it was removed for the appropriate agricultural usage. The residual product, which did not fill the last 55-gallon drum in the blending cycle, was marked and identified as to batch number, product, and number of pounds. These partially filled drums were sealed and stored until the next batch of similar product was scheduled for formulation, at which time sufficient quantities of product were available to fill the semi-filled drums. Any broken containers of technical materials were placed in salvage containers immediately upon discovery, the· ·relevant vendors were notified, and such materials were shipped back to the originating company for their disposal. Prior to 198~, Farm Chemicals released empty technical material containers to commercial companies specializing in reclaiming these containers. Residual wastes from containers were -held in storage prior to their release to the commercial reclaimers •. When the wastes were in a diluted state,. they were spread on farmland owned by the company or _its stockholders,: according to recommended usage. The company also donated empty and cleaned drum containers to the general public for use as trash-burning receptacles. This practice was eventually curtailed I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I when more stringent storage practices were introduced at Farm Chemicals. The plant's continuous process of blending and storing full containers, as well as incomplete quantities of product continued. A 1,200-gallon truck was acquired to facilitate the temporary storage of residual materials until they could be removed for spreading on company farmland. A residual build-up of triple-washed drum containers occurred due to decreased demand by commercial reclaimers. Hence, many of these drums were transported to a local landfill site for subsequent removal, washing, and further disposal in accordance with more recent regulations. The solvent xylene was used to clean the 2,000 gallon stainless steel mixing vats after each blending process was completed. Wastes from cleaning vats were placed in temporary storage in the mobile J,200 gallon tank for removal and spreading on company farmland. During the site reconnaissance conducted by EPA's remedial contractor, the REM V Team, sulfur and possibly pesticide-like odors were noticed on site. crystallized finger-shaped substances (presumed to be pesticide) with yellowish or black tips were found on site. The chemicals or materials were similar to those identified at the TWin sites Area across the street from the Farm chemicals Area. Between May 11-16, 1986, high frequency ground penetrating radar (GPR), terrain conductivity, and magnetic field surveys were conducted on the southern portion of the plant. The GPR profiles indicated the presence of an extensive trench system underlying the southern portion of the Farm chemicals• property. Low terrain conductivity measurements over the trench area suggested nonconductive trench contents; i.e., paper, plastic, and drums. Augering confirmed the nature of the trench contents and subsequent analysis of subsurface material revealed contamination by several pesticides and PCBS. Scattered spots of magnetic field anomalies were also detected, possibly indicating the presence of buried metallic objects (E~A-TAT, July 1986). The GPR survey was extended onto the Brooks-Perkins property south of and immediately behind Farm ·hemicals' property. This survey identified a possible trench like structure along with several buried drum like objects. Terrain conductivity and magnetic field surveys were not conducted to verify the GPR findings due to time constraints. It was recommended at the conclusion of the GPR survey that additional data be collected to verify the findings (EPA-TAT, July 1986). Four soils samples from the southern part of the Farm chemicals' property and the adjacent Brooks-Perkins property were collected and analyzed. A soil sample collected at a depth of 7 feet on the Farm Chemicals• property confirmed the presence of a buried trench with contamination levels of 800 ppm 4,4'-DDT and 100 ppm PCBs. 2.1.2 TWin sites Area The North Carolina state Division of Highways reported the first disposal area discovered at the TWin Sites Area to the NC SIIWMB in July 1984. NC SIIWMB performed investigative work in August 1984, and learned of another nearby disposal area through an employee of the Town of Aberdeen. A third disposal area was suspected and subsequently confirmed during the remedial investigation. Waste types and disposal methods are similar for all areas. The disposal areas will be referred to individually when necessary as Area A, Area B.,, and Area C. Taylor chemicals Company, the name printed on toxaphene bags:found on site, indicates that it is possible that disposal activities may date back as early as 1936. On October 22, 1984, RCRA 3012 personnel of the NC SBWMB conducted a site investigation at the Twin sites Area. Pesticides bags and colored powdery material (believed to be pesticides) lay strewn over Areas A and B. Strong odors were noticed during the investigation. The moderately sloping terrain has facilitated considerable contaminant run-off in the direction of Pages Lake. samples of the wastes and soil were collected from Areas A and B. Laboratory analyses showed the presence of DDD, DDT, toxaphene, aldrin, heptachlor, lindane, dieldrin, and lead. During the site reconnaissance by the REM V Team and EPA personnel on October 26, 1987, a third area (hereinafter known as Area C) of possible pesticide disposal was found between disposal Areas A and B. sulfur-and possibly pesticide-like odors were noticed. Crystallized finger-shaped substances (presumed to be pesticides) with yellowish or black tips were found throughout the three disposal areas. In 1985, EPA initiated an emergency response cleanup at the Twin Sites Area during the periods of June 17th through the 24th and July 30th ·through August 5th. seventy-one truck loads of surface contaminants containing pesticides and contaminated soil were excavated from Area B. After partial excavation of Area A; an approximately 200' x 20' x 10' deep trench containing pesticide wastes (concentrations up to 1,000 ppm) was identified. A total of 165 truck loads of pesticide waste were excavated from Area A. contaminants from the Twin Sites Area were shipped to the GSX facility at Pinewood, s.c. for disposal. During the site restoration, about 6,500 cubic yards of additional pesticide wastes were discovered in Area A. Since these wastes did not appear to pose an immediate threat, they were not excavated as a part of the emergency response cleanup. contamination detected in 4 municipal wells and 3 private wells caused the EPA to reevaluate the Twin sites Area in May 1986. Geophysical surveys (ground penetrating radar (GPR), terrain conductivity, and magnetometer) and limited groundwater and soil sampling were conducted between May 11-16, 1986 at and around Area A to identify and delineate potential contamination sources. These surveys suggested that no substantial trench structures or subsurface metallic debris remained in Area A after the 1985 emergency cleanup activities. Terrain conductivity findings did indicate the existence of a residual contaminant plume. A groundwater sample, taken from the top of the water table (13 feet below the surface) near the center of Area A, confirmed this contamination. Concentrations of up to 76.6 ppb of lindane were reported. soil samples showed the area just west. of Area A to be free of pesticide contamination, however samples collected at the northern edge of the excavated area (depths of 11 and 4-6 fe,et,) 10 I I I I i I I I I I _ ..... ~ I I I I I I I I I I I I I i I I I I I I I I I I I I I I revealed that extensive contamination still existed on the Area. Concentrations of up to 19 ppm lindane and nearly 300 ppm for the other BBC isomers were reported along with elevated levels of DDT, DDD, DDE, aldrin, heptachlor, endrin ketone, and chlordane. An additional geophysical investigation was conducted with an EM-31 terrain conductivity meter during March 1987. Other than some residual contamination, no new pesticide deposits were found during this survey (Roy F. Weston, Inc., no date). The area covered by the survey is unknown. 2.1.3 Fairway six Area Prior to devel9pment_of "The Pit" Golf Links, the site was a field within a wooded area. Access to this field was possible via two dirt roads from NC Highway 5. NC SHWMB personnel discovered the. site in August 1984 through an employee of the Town of Aberdeen, who indicated that pesticide wastes had been disposed of at and around the Area from time to time for a number of years. on October 22, 1984, RCRA 3012 personnel of the NC SHWMB conducted a site investigation at the Fairway six Area. During the investigation, household rubbish, old car parts, etc., were observed within the vicinity of the Area. The general area, therefore, is believed to have served as a trash dump for many years prior to .the construction of the "Pit" golf course. Records of waste disposal activity do not exist. several pesticide bags labeled "toxaphene" were noted, as were colored powders and fines believed to be waste chemicals, possibly pesticides. The most prevalent indication of pesticides, however, was strong chemical odor. Samples of these wastes and soils were collected in October 1984 before EPA emergency removal action and subsequent analysis revealed the presence of 2,253 ppm DDT, 573 ppm DDD, 601 ppm toxaphene, and traces of lindane. EPA initiated an emergency response actions at the site Area on June 25, 1985. The materials on the surface and in Trench No. 1 were excavated and transported to the GSX facility in Pinewood, south Carolina for disposal. During the site restoration, Trench No. 2 was discovered, excavated, and the material was shipped to the GSX facility. Emergency response action at the Fairway six Area initially terminated on July 16, 1985·. As a result of the identification of pesticide contamination in the drinking water in 4 municipal wells and 3 private wells, the EPA reevaluated the Fairway six Area in May 1986. Ground penetrating radar (GPR), terrain conductivity, and soil sampling (4 sta~ions) studies were conducted at the Area during May 11-16, 1986. The geophysical surveys revealed a third buried trench ranging in depth from 4 to 10 feet and containing highly conductive material. Exploratory augering and sampling verified the presence of pesticide contamination up to 1,500 ppm. Trench No. 3 was estimated to contain 12 million pounds of pesticide wastes. I I ------------- During December 10-12, 1986, the EPA Emergency Response Team conducted a test burn of contaminated soil at the Area. Twelve thousand pounds of material were incinerated in an a-million BTU rotary kiln mobile incinerator owned and operated by Vesta Tech Ltd. contaminated disposable supplies and incinerator residue were stored in 55-gallon drums on-site. An EPA Technical Assistance Team conducted another geophysical survey with an EM-31 terrain conductivity meter at the Area on March 10, 1987. During this investigation, the fourth pesticide trench was discovered with pesticide contamination levels up to 1,500 ppm. Excavation of the most recently discovered pesticide wastes (in Trench Nos. 3 and 4) began in August 1988. During this activity, two additional pesticide waste trenches·were discovered, Trench Nos. 5 and 6. This material was also excavated; screened, and stockpiled adjacent to the Area •. The stockpile is isolated from the environment with both bottom and top liners of 30-mil PVC plastic. These liners were chemically affixed to prevent migration of this material from the stockpile, while the top liner was also weighed down by rubber tires. The stockpile area was enclosed by a 6-foot fence with a locked gate on the west side near the northwest corner. The dimensions of the pile are roughly 215• x 110• x 28•. It is estimated to contain about 22,000 cubic yards of pesticide-contaminated materials. The waste pile was designated as Operable Unit Two (OU Two) within the overall site strategy for the Aberdeen Pesticide Dumps Site. From March 30, 1989 to May 14, 1989, a REM V Remedial Investigation Team conducted a Feasibility study on OU Two. A Record of Decision was signed on June 30, 1989. The selected remedy included on-site incineration and on-site disposal of the residual ash. A potentially responsible party has agreed to implement the remedy. However, field activity has been postponed pending the outcome of the remedy selection for Operable Unit One. The PRP will undertake measures to ensure liner integrity of the soil stockpile.during this period until field activities begin. 2.1.4 Mciver Area The Mciver Area was discovered in November 1984 when NC Department of Agriculture (NCDA) personnel found 200-300 55-gallon pesticide drums dumped in a rubble landfill ( known as "Lucks Landfill" and Area A), Further investigation revealed that parathion residues remained in at least some of the drums. During the initial investigations by the NC SHWMB, a second area (Area B, previously known as the Bag Site) was discovered approximately 1,000 feet to the northwest of Area A. Area B consists of an approximately one-acre tract where trash, old building materials, and a large number of bags containing pesticides and pesticide residue had been dumped. The bags were allegedly disposed by GEIGY chemical, who once had a pesticide formulation plant in Aberdeen, located along Route 211. The disposal dates are estimated to be late'1960s to early 1970s. The property on which the site lies is owned by the estate of Rev. Mary E. and John Mciver. Their heirs include Rev. Ruth Monroe, who lives about 1,000 feet from the site. Part of the property was leased by Bill Luck, I 2.. I I I I i I I I I I I I I I I I I I I I I I I I I I I I I I I I I. I I I I I and is known as "Luck's Landfill." According to Rev. Monroe, Area A had been used for an undetermined number of years as a rubble dump. Access to this Area was not controlled. Although several contractors apparently used the site to dump rubble, Bill Luck seems to have been the primary user. Area A was investigated after it was discovered that 200 to 300 pesticide drums had been dumped there. Apparently no environmentally related permits were obtained for the Area during its use. In January 1985 Farm chemicals, Inc., Bill Luck and Luck's construction company agreed to remediate Area A in accordance with a State issued Administrative Order. The remediation consisted of the following: • • • • Removal of 686 drums. Drums were triple-rinsed,_crushed and disposed of in the Moore county landfill. Five of the 686 drums had liquid in them. Three of these ruptured during the removal. As a result, contaminated soil was removed from this area. Post-removal soil sampling and analysis indicated that parathion remained in the soil. Confirmation sampling indicated two areas were contaminated at depths up to 24 inches. Farm Chemicals then removed 2 to 2.5 feet of soil in those areas and back filled the holes with clean fill. Representatives of North Carolina Department of Bu.man Resources overviewed the removal activities at Area A and determined that Area A of the site had been remediated. As a result of these actions, and the concurrence of North Carolina, EPA considers Area A to be completely remediated. Therefore, EPA focused its remedial investigation in Area B only. Area B of the site is presently inactive. According to Rev. Monroe, dumping occurred at Area B approximately 20 to 30 years ago, when pesticide bags containing residues and old pesticides were simply dumped on the land surface. Access to Area B has reportedly never been controlled. The EPA initiated cleanup and removal actions at Area Bon June 10-16, 1985. Immediate removal activity resulted in disposal of pesticide waste at the GSX facility in Pinewood, South Carolina. In March of 1989, during the remedial field investigations, a new area of dumped pesticide-like wastes was discovered between Areas "A" and "B". The area, identified as Area C was appr'oximately 75·-x 300 feet and had a strong chemical odor. The waste material (mostly decomposed cardboard drums with fine grained white to light grayish, and some tarry black material) rose 2 -4 feet above ground surface. The edge of the wastes was within 50 feet of the unnamed tributary to Aberdeen creek which lies just north of the site. An EPA emergency response action resulted in the excavation and stockpiling of approximately 3,200 cubic yards of pesticide wastes and contaminated soil. The method of containment and isolation of the stockpile (i.e. liners and fence) was the same as was used for the stockpile at the Fairway six Area. /J 2. 1.5 Route 211 '.Area. ;, Prior to 1964, the Route 211 Area was reportedly used as a sand-mining pit by Superior Stone Company of Raleigh, North Carolina. The period during which the Area was actively mineq is unknown at this. time. In 1959, American-Marietta purchased both the Route 211 Area and Superior stone Company. The current la~d owner reportedly discovered the waste pile in the pit shortly after purchasing the property in 1964. However, the Area appears to have remained unchanged and unused since that time. There is no indication that any regulatory action had been taken at the Area or that any environmentally related permits have been issued. On July 12, 1985, NC SBWMB personnel inspected the Area. It appeared that waste had been dumped in a pile on the southwest slope of the pit. The pile contained decomposing cardboard containers, bags, and wastes ranging from white-tan powders to dark-brown tarry residues. Samples from the pile and the downgradient soil were collected. Laboratory analyses indicated the presence of alpha-, beta-, and delta-Bae·, ODE, ODD, DDT, heptachlor, and chlordane. Some or all of these compounds were detected in samples taken from the waste pile and the downgradient surface soil. EPA initiated an emergency response action at the Route 211 Area between June 4-6, 1986. Five truck loads of surface contaminants or approximately 100 cubic yards of pesticides aAd contaminated soil were excavated from the basin and disposed of at the GSX facility in Pinewood, south Carolina. In May 1989, during the installation of monitoring wells around the Area, about 200 cubic yards of material which appeared to be similar to other pesticide wastes found at the Area were discovered on the ground and partially buried in a hillside about 100 yards north of the Area. This material was removed by the EPA's Emergency Response Team during June 1989 and stockpiled with that material excavated from Area C of the Mciver Area. 2.2 Enforcement Activities The Aberdeen Pesticides Dumps site was proposed for inclusion on the National Priorities List (NPL) in January 1987 and became final on the NPL on March 31, 1989, Federal Register No. 54, Vol. 61 .. A potentially responsible party (PRP) search conducted in 1985 identified several PRPs. On May 15, 1985 and September 30, 1985, EPA notified PRPs of the conditions at the Site and their potential liability for the costs of remediating such conditions. certain information was also requested of the PRPs. The notified PRPs were also ,invited to participate in a removal " of hazardous substarices from the site. No PRPs came forward to take action at the site. On April 13, 1987 EPA sent special notice letters to four identified PRPs and requested voluntary performance of a RI/FS to abate any release or threatened release of hazardous substances. None of the PRPs notified agreed to perform the requested work. EPA therefore, proceeded to conduct .the RI/FS utilizing the superfund Trust money. Following a remedy selection for OU Two (Fairway Six Stockpile) in June 1989, EPA issued special notice letters to twenty-two PRPs on Dec'ember 21, I L( I I I I I I I I I I -~~ I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1989. The special notice letter invited PRPs to enter into negotiations for implementation of remedial action at ou TWo. Due to the lack of PRP interest to voluntarily implement the selected remedy, EPA issued Uni- lateral Adminstrative orders to four PRPs during the week of March 5, 1990. One PRP, Union carbide, agreed to implement the selected remedy at OU TWo. ) on June 28, 1991, EPA issued a general notice letter to 19 PRPs. The notice letter provided an opportunity for the PRPs to meet with EPA in o'rder for EPA to begin facilitating cooperation and coordination among all parties ·involved. Following issuance of this Record of Decision, special notice letters, pursuant to CERCLA Section 122(e), will be issued to the PRPs. The special notice letters will request voluntary participation by the PRPs in implementation of the selected remedy for OU one. The Department of Justice (DOJ) filed a lawsuit ori behalf of EPA Region IV against five defendants on March 31, 1989, pursuant to CERCLA section 107 for recovery of past and future response costs. The suit is docketed as civil Action No. c-89-231-R and was filed ~n the u.s. District court for Middle District of North Carolina, Rockingham Division, Greensboro, North Carolina. As new information became available, the lawsuit was amen_ded to add 15 new parties responsible for site contamination. 3.0 HIGHLIGHTS OF COMMUNITY PARTICIPATION A Community Relations Plan for the Aberdeen Pesticide Dumps Site was finalized in April 1988. This document lists contacts and interested parties throughout government and the local community. It also establishes communication pathways to ensure timely dissemination of pertinent information. A fact sheet outlining the remedial investigation sampling program was distributed in June 1988. subsequently, an availability session was held on July 18, 1988 at the Aberdeen Railroad Depot to answer questions concerning the upcoming RI/FS activities. The RI/FS and the Proposed Plan for ou one were released to the public on May 23, 1991. sections 113(k)(l)(B)(i-v) and 117 of CERCLA, as amended by SARA, requires EPA to establish administrative records containing documents used to select response actions under CERCLA. All documents were made available in both the administrative record and information repository maintained at the Aberdeen Town Ball. A public comment period was held from May 23, 1991 to July 24, 1991 and upon request was extended an additional 15 days to August 8, 1991. A public meeting was held on May 30, 1991 to present the results of the RI/FS and EPA's preferred alternative as presented in the Proposed Plan for the Site. A transcript of the May 30, 1991 public meeting is available for review in the Administrative Record. Prior to the May 30 meeting a public notice was provided in two local newspapers. The public meeting was also announced in the Proposed Plan fact sheet which was distributed to approximately 200 interested parties. In addition to the May 30, 1991 public meeting, an Availability session was held on July 2, 1991 at the request of local citizens. The availability session was held in order that the public had ample time to review the administrative record and become knowledgeable on the basis for EPA•s proposal of a preferred alternative. EPA staff at the availability • session included te.chnical experts, legal counsel, a regional toxicologist and community relations support. All comments which·were received by EPA prior to the end of the public comment period, including those expressed verbally at the public meeting, are addressed in the Responsiveness summary which is Part III of this Record of Decision. 4.0 SCOPE AND ROLE OF OPERABLE UNITS WITHIN SITE STRATEGY As with many Superfund sites, the problems at the Aberdeen Pesticide Dumps site are complex. As a result, EPA has organized the work into three manageable components called Operable Units (OU). Operable Unit·one (OU One) consist of surface and subsurface soil contamination at the five areas comprising the site. In this ROD for OU one, EPA is selecting an interim remedial action for source control of contaminated groundwater. This operable unit will address contaminated surface and subsurface soil at all of the five areas of the Aberdeen Pesticide Dumps Site. This operable unit poses one of the principal threats to human health and the environment because of the risks from possible ingestion, inhalation or dermal contact with contaminated soils. Moreover, contaminated soil remains· a continuing source for contaminant migration from the soil into the underlying groundwater which is the sole source of drinking water for the local residents. The purpose of this response is to prevent current or future exposure to the contaminated soils and to reduce _contaminate migration into the groundwater. Operable Unit Two (OU Two) was designated for remediation of contaminated soil excavated and now stored in the Fairway six stockpile in 1988. A Record of Decision signed on June 30, 1989 for OU Two selected on-site incineration of pesticide laden soil and debris and on-site disposal of the treated residuals. After receipt of a Unilateral Administrative Order, union carbide agreed in March 1990 to implement the selected remedy. However, upon request by union carbide, EPA has allowed a postponement of implementation of the selected remedy for OU Two pending the issuance of this Record of Decision for OU one. Because the operable units are related on the basis of geography, contain similar or identical wastes and are related based on the threat posed, Operable Units One and Two will be combined for purposes of implementing this Record of Decision's selected remedy. Further discussion for the basis of this revision on OU Two is provided in Section 10.0 AMENDMENT TO OPERABLE UNIT TWO RECORD OF DECISION. OU Two henceforward will be referred to as operable unit Four. Operable Unit Three (OU Three) was designated for addressing groundwater contamination at the five areas comprising the site. In addition, an ecological assessment currently under review at all five areas comprising the site will also be addressed and is designated as OU Three. Operable Unit Four (OU Four), because of EPA's ROD tracking system, the former operable unit Two henceforward will be referred to as ou ,,Four. An amendment .to ,OU· Two's ROD is considered a new ROD and therefore an,: operable unit.designation is assigned. • I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 5.0 SUMMARY OF SITE CHARACTERISTICS 5.l Farm Chemicals Area 5.l.l Surface Soils (Farm Chemicals Area) The Farm Chemicals Area operated as a previous pesticide formulation facility. A total of 49 samples were collected during the field investigation for pesticide analysis. TWo background stations were selected in the area surrounding the Farm Chemicals Area. A total of 24 stations were sampled at two depths (3-4 and 5-6 feet) with the exception of stations SSS-115 (3-4 feet), SSS-122 (5-6 feet) and SSS-119 and SSS-123 (surficial sample). Seven of these samples were al~o analyzed for TCL metals, total organic-content, cation exchange capacity, and percent moisture. Table l presents the number of samples collected in soil, tanks, drums, insulation and air, in addition to the type of analysis performed on these samples. The significant cont~inants and· their maximum concentrations for all media at the Farm Chemicals Area are presented in Table 2. TABLE 1 SAMPLE MATRIX FOR THE FARM CHEMICALS AREA No. of No. of sample Depth Samples Media Location stations (feet) Yieled Analysis surface Background 2 2-4 1 Pesticides, PCBs Soils on-site 24 0-6 44 Pesticides, PCBS Duplicates 3 3 Pesticides, PCBs Splits 7 Pesticides, PCBs, TCL Metals, TOC/CEC % Moisture sub-Background l 22-70 3 Pesticides, PCBs, surface TCL Metals, TOC/CEC Soils % Moisture on-site 5 20-64 17 Pesticides, PCBs, TCL Metals, TOC/CEC % Moisture Miscellaneous Insulation ll NA ll Asbestos Containers 13 NA 13 Pesticides, PCBs, (4 swabs, 9 liquid) TCL Metals, TOC/CEC svocs Air on-site 1 NA l Pesticides, PCBs, Asbestos /1 TABLE Z SIGNIFICANT CONTAMINANTS AND THEIR MAXIMUM CONCENTRATIONS FARM CHEMICALS A(Efi CHEMICAL SS (mg/kg) SI) (mg/kg) SB (r,g/kg) SW (ug/l) GIi (ug/ll AIR (ng/l) FISH (r,g/kg) ANTIMONY ARSENIC BARIIM BERYLLIIM CAOMIIM CHRCMIIM COBALT COPPER LEAD MANGANESE MERCURY NICKEL SELENIIM SILVER , VANADIIM ZINC 5,000 360 110,000 20,000 150 2.4 31,000 NA NA NA NA NA NA NA NA NA NA NA NA 11A 11A 11A 11A 3 74 8.7 58 15 NA NA 11A NA NA NA 11A 11A 11A 11A NA 11A NA 11A 11A 11A 100 6 430 2,400 5 4,100 6,000 11A NA NA NA NA 11A 11A 11A 11A 11A 11A NA· NA NA 11A 11A NA NA NA NA NA NA NA 11A 11A NA 11A 11A NA NA 11A 11A CHEMICAL 1,1,1•TRICHLOROETHANE 1,1•DICHLOROETHENE 1,2·DICHLOROETHAJIE BENZENE SS (ug/kg) SI) (ug/kg) SB (ug/kg) SW (u;/l) GIi (ug/l) AIR (ng/l) FISH (11111/kg) CARBON DISULFIDE CARBON TETRACHLORIDE. ETHYL BENZENE TETRACHLOROETHENE TOLUENE TRICHLOROETHENE XYLENES (TOTAL) 1,2,4·TRICHLOR06ENZENE 2,4'DIMETHYLPHENOL 2-METHYLNAPHTHALENE BIS(2·ETHYLHEXYL)PHTHALATE NAPHTHALENE 4,4'·000 4,4'·DDE 4,4'-DDT ALDRIN ALPHA·BHC BETA·BHC DELTA•BHC DIELDRIN ENOOSULFAN 11 (BETA) ENDRIN ENOR IN UT ONE GAMMA·BHC GAMMA·CHLORDANE HEPTACHLOR HEPTACHLOR EPOXIDE TOXAPHENE NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 11A 230,000 a,ooo 13,000,000 590 8,800,000 420,000 540,000 2,400 97 1,300,000 640 660 3,200,000 11A 11A 11A NA 11A 11A 11A NA 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 52,000 200,000 NA 11A 11A 11A NA 650 120 1,300 160 85 52 100 4,500 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A NA 11A 500 21 6,700 17,000 970 1,100 17 64,000 11 48 9 13 18 9 6.9 0.4 o. 1 0.2 0.4 10 11A NA 11A 11A 11A 11A 11A 11A NA 11A 11A 11A 11A 11A 11A 11A 0.035 0.14 0.56 0.018 0.061 0.3 0.014 0.048 0.013 . 2.a SS -Surficfal 1oil; SO• Sedhnent; S8 -Sf.bsurface ao;t; SW• Surface water; GW • Gro.ndwater; AIR· Air; FISH· Fish tissue; 11A • Not available (enalysf• ••• not perfonoe<I) or not ■wlfcabla. 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A r~, ............... 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Across the Farm Chemicals Area, fourteen different pesticide species were detected in the soil samples. Species, frequency of detection (number of positive values over total number of samples not including split samples), and the concentration range are summarized, in decreasing order of detection. Pesticide Frequency of Species Detection Concentration tug/kgl 4,4'-0DT 41/47 (87%) 84 -13,000,000 toxaphene 29/47 ( 70%) 450 -3,200,000 alpha-BHC 26/47 (55%) 8.4 -8,800,888 gamma-BHC 19/47 (40%) 9 -1,300.,_000 beta-BHC --15/47 (32%) 11 -420,000 4,4'-00D 13/47 (28%) 34 -230,000 4,4'-DDE 13/47 (2 8%) 22 -230,000 delta-BHC 12/47 (26%) 9.5 -540,000 dieldrin 9/47 (19%) 39 -3,600 ~ aldrin 5/47 ( 11%) 82 -590 gamma-chlordane 4/47 ( 9 % ) 89 -640 heptachlor 4/47 ( 9 % ) 12 -660 endrin ketone 2/47 (4%) 18 -97 methyloxychlor 1/47 (2%) 84 In general, most of the areas of elevated pesticide concentrations are located either near the edges of buildings and/or loading dock areas, or in suspected (or known) buried trench areas identified in the geophysical survey. No PCBs were detected. Total pesticide concentrations in surface soil samples is shown in Figure -1-. No background sample for metals was collected. However, the metals analyses from the shallow subsurface soil sample from the background monitoring well for this area was used for comparison. Except for station SSS-119, surficial soils samples revealed metals and.concentrations typical of the area and mainly comparable to background, except for elevated lead levels at the shallow interval at two stations detecting 21 and 26 mg/kg. Foreign material was encountered during augering at both these stations, and may be related to these elevated concentrations of lead. station SSS-119 was collected from an area of stained soil and pesticide-like material. Arsenic was found at an extremely elevated concentration, 5,000 ppm. Lead was also found here at 20,000 ppm, much greater than that found elsewhere on-site. For the purpose cf a baseline risk assessment, all compounds present at a maximum concentration greater than 5 times the laboratory blank concentration were evaluated. Exceptions to this include acetone, methylene chloride, toluene, 2-butanone, and phthalates which were evaluated if present at concentrations greater than 10 times the corresponding laboratory blank concentrations. The organic contaminants of concern for the surficial soil media at the Farm chemicals Area include: alpha-BHC, beta-BHC, delta-BHC, gamma-BHC, 4,4'-DDD, 4,4'-DDE, 4,4'-DDT, aldrin, dieldrin, delta-chlordane, heptachlor, endrin ketone, and toxaphene. Metals of concern for this area include: arsenic, lead, barium, copper, manganese, nickel, and zinc. / 'l N () - 0 111 ' "'-'"""' lo.ce\k,t,) 1-..-.-.0, .o f'L w .. 1) :r•.:.:~;-""------J:-, ,s·-te1 10·-,ro DENSE TREES sss-121" • ,_ .. ,,---- 0°~ ~ ~ f) C' u A (J 0 NORFOLK '" "' • J4D <...:.J10 J10 ·-11 Jso ·-~ ·-~ N.C. ){-){-.. • FENCING IC • ~ .. ......,,. ){ • m suRnaAJ.. SOII./SU1lSURfAC( SOIL SA1,1Pl( LOc.-.noN AtmfdLal lnvnllgallon/FHtlbllltJ Study (RIIFS) . Abttdlen Putldde Dump1 SIie .r-~ . O£J'nt Of" S.I.MPU: (fl) ., TOT-'L P(STICIO( CONCENTR.-.nON (u9/k9) ~ KNO'M-1 TROIOi AA(A Aben:teen, Mooni County, NOf1h C.rolll\l FIGURE 7 -II!!!!! 1!!!111 (2J POT£NT\Al 0A SUSJ'[Cml TRDICtt AAEA SCALt Total pesticide concentrations in surficial and subsurface soils and location of suspected buried trenches -Farm Chemicals Area. (: -.. --1!111 ... ,oo -- I I I I I I I I I I I I I I I I I I I 5.1.2 subsurface Soils (Farm chemicals Area) Nineteen subsurface soil samples were collected from the monitoring wells installed during the field investigation. Samples were collected at three intervals: one taken above the water table, one from the capillary fringe zone, and one from the interval where the well screen was installed. samples collected from boring l-MW-01 were used to evaluate background conditions. The significant subsurface soil contaminants and their maximum concentrations are presented in Table 2. Elevated levels of 4,4'-DDT,-DDD,-DDE (120-1,300 ppb) and toxaphene (4,500 ppb) were found in subsurface soil samples collected at 20 feet below ground surface. BBC isomers and 4,4'-DDT were identified at a depth of 35 feet. below ground surface at concentrations of 52-160 ppb-and 66 ppb respectively. The pesticide contamination detected·in the subsurface soil samples demonstrates downward migration of these contaminants. Ethyl benzene and total xylenes, which were detected in at least one sample from four of the five on-site borings, were the only voes found in significant concentrations. As with the pesticide concentrations, samples from the boring for l-MW-04 were the most contaminated with voes. The shallow sample contained ethyl benzene and total xylenes at concentrations of 1,400 and 10,000 ug/kg, respectively; while the water table sample was most contaminated with 52,000 and 200,000 ug/kg of these contaminants detected. Further downward migration of these voes was evident, as trace levels were detected in the deepest sample (ll and 50 ug/kg, respectively). Total pesticide concentration for the subsurface soil samples are shown in Figure 7. Metals detected in samples from the borings on-site were mainly typical of those found in the area, and concentrations of most of them were comparable to background levels. However, elevated concentrations of several metals were detected in the deepest sample from l-MW-06 at a depth of 55 feet. Metals present in concentrations greater than 2 times the Contract Required Detection Limit (CRDL) included: aluminum, calcium, chromium, iron, lead, vanadium, and zinc. Total organic carbon, cation exchange capacity, and percent moisture analysis for these samples ranged from 110-15,000, l.9-4 meq/kg, and 3-21 percent, respectively. Organic subsurface soil contaminants meeting the minimum concentration requirements for evaluation under the baseline risk assessment are as follows: 4,4-DDD, 4,4-DDE, 4,4-DDT, alpha-BBC, beta-BBC, delta-BBC, gamma-BBC, and toxaphene. Metal contaminants evaluated for this area include: chromium, barium, cobalt, copper, manganese, vanadium, and zinc. 5.1.3 Tank/Drum/Insulation (Farm chemicals Area) The Farm Chemicals Area is the only area at the site containing buildings/structures. There are ll buildings and 3 above ground storage tanks at this site. Soil samples collected near the foundations of several of the buildings contained highly elevated levels of pesticides. Eleven insulation samples were collected from these buildings, consisting of both blown-on insulation and pipe-wrap types for asbestos analysis. Three samples taken from pipe-wrap insulation near the warehouse just south of the mixing vat area were positive for asbestos (20-40%). Three of nine building samples revealed levels of asbestos up to 40%. 21 Residual material's in drums and containers in sever~l of the on-site buildings were sampled and analyzed for pesticides, PCBs, voes, and TCL Metals. On-site drums, 5-gallon buckets and tanks were sampled. PCBs were not detected in any samples. One liquid sample collected from a tank contained 490,000 ppm toxaphene. swab samples from a mixing vat and sump area revealed pesticide residues. Most tank samples revealed elevated levels of voes. SVOCs were also detected in the liquid tank sample. Metals were detected in the liquid tank and swab samples. 5.1.4 Air (Farm Chemicals Area) One air sample collected at the Farm Chemicals Area was analyzed for pesticides, PCBs, and asbestos. Laboratory results revealed ten pesticide species ranging from 0.013-2.8 ug/m3 • These pesticides included alpha-BBC, gamma-BBC, heptachlor, aldrin, dieldrin, gamma-chlordane, toxaphene, 4,4'-DDD, 4,4'-DDE, and 4,4'-DDT. Asbestos and PCBs were not detected in the on-site air sample. 5:1.5 Area of contamination (Farm Chemicals Area) Two known buried trenches and one suspected trench are contained within the boundaries of this area. one of the known trenches is located in the southern portion of the area and probably consists of a system of multiple trenches based on geophysical ~urvey results. The outline of these trenches is fairly well defined; however, their depths are unknown. For volume estimation purposes it is assumed that almost the entire southern portion of the area will have to be excavated/treated. The other known trench is located in the central area of the site and was confirmed by surficial and subsurface soil sampling. However, the boundaries of this trench are not clearly established .. One sample collected in the suspected trench area in the eastern portion of the area contains a total pesticide concentration in excess of 3,000 ug/kg at a depth of 5 to 6 feet. Further sampling should be conducted in this area to verify the presence of a trench; however, this relatively small area is assumed to require remediation. As mentioned above, for volume estimates these trenches (and underlying contaminated soils) are assumed to extend to a depth of 15 feet below grade. To reach the target cleanup goals at a 10-• health based level, the total volume of material to be remediated from the Farm chemicals Area is estimated to be 1,307,962 cubic feet or 48,443 cubic yards. _Areas requiring excavation are presented in Figure 8. 5.2 Twin Sites Area 5.2.l Surface Soils (Twin Sites Area) The TWin Sites Area consists of three disposal areas (Areas "A", "B", and "C") located on adjacent properties. A total of 32 sampling stations were selected for the Twin Sites Area. Three background samples were collected surrounding the perifery of the on-site sampling grid and analyzed for ·pesticides and PCBs. Although no background surface soil samples were analyzed for metals, background comparison levels were obtained from subsurface soil sample SUB-201 collected at 15 feet below grade. The remaining 55,. samples were collected f_rom 29 stations located within the z.?... , .. {" I I I I I I ·- I I 1·1 I I I I I • I I I I N l,J -,_ DENSE TREES Ill AEPCO North (f) -----·-------= -----------~ UUTHERN \ ,,----. 0°~ ~ ' \I:,-c ~ /") 0 u 10 c> • Remdll ~wtsdg16M'Ftaslblllty Study (RIIFSJ ,lbffdtt,n it.ttcidt Oumpt Sit, Abffl!rrn, Moor, County, North Carollna "' SAMPl.£ LOCATION O(Plll OF SAMP1£ (f"l) -TOTAJ.. f'(STICIOE CONCDflRATION (u9j\:9) AAEA 0:CAVATrtl TO 15 fITT BG\. AREA O'CAVAllll 1tl 10 FTET Bet. AA(A D:C"VAlrn TO 5 mT SCl FIGURE P. Area of contaminated soil requiring remediation at the Farm chemicals Area. SSS-107 ,-.1,no :!"•1.ll4 ENSE rn s grid area and analyzed'for pesticides and PCBs. These samples ranged in depth from O -5,:;feet below grade. Six of the on-site samples were also analyzed for TCL metals, total organic content, cation exchange capability, and percent moisture. Table 3 lists the samples collected in soil and.air in addition to the type of analysis performed on these samples. The significant contaminants and their maximum concentrations for all media at the Twin Sites Area are presented in Table 4. TABLE 3 SAMPLE MATRIX FOR THE TWIN SITES AREA No. of No. of Sample Depth Samples Media Location stations (feet) Yieled Analysis surface Background 3 3 & 5 3 Pesticides, PCBs Soil on-site 26 0 -5 49 Pesticides, PCBS 3 0 -5 6 Pesticides, PCBs, TCL Metals, TOC, CEC, % Moisture Sub-Background 1 15-51 3 Pesticides, PCBs, surface voes, TCL Metals, Soil TOC (one sample), % Moisture on-site 4 3-25 12 Pesticides, PCBs, -voes, TCL Metals, TOC, CEC, % Moisture Air on-site 1 NA 1 Pesticides, PCBS Fifty percent of the on-site stations revealed pesticide contamination at concentrations greater than 2 times the CRDL. The pesticides detected, their frequency of detection, and concentration ranges are summarized below. Pesticide Frequency of Species Detection Concentration tug/kg) 4,4'-DDT 21/55 ND -340,000 alpha-BBC 19/55 ND -440,000 beta-BBC 18/55 ND -35,000 delta-BBC 14/55 ND -160,000 gamma-BBC 13/55 ND -160,000 4,4'-DDD 13/55 ND -11,000 ·. toxaphene 4/55 ND -340,000 dieldrin 4/55 ND -1,100 aldrin 3/55 ND -390 2t/ I I I I I I I I 1,·: I I I :I I I I I I I I I I I I I I I I I I I I I I TABLE L/ SIGNIFICAN: CONTAMINANTS .AND THEIR MAXIMUM CONCENTRATIONS TWIN 6r1e· s ,I/,?;; rl CHEMICAL ss (m;/kg) SD (m;/kg) SB (m;/kgl SW (ug/l) GIi (ug/l) AIR (ng/ll FISH (m;/kg) ------------------------------------------·-------------------------------------------------------------------- ANTIMOIIY 430 NA ARSENIC 3.3 94 4.2 11A BARIIM 32 69 4.4 40 38 11A 0.91 BERYLLIIM 1 .9 11A CAl>MIIM 3.4 2.6 11A CHA~IIM ---15 65 9 11A 0.25 COBALT 4.6 a 6 11A COPPER 36 120 180 11A 0.71 LEAD 4.7 290 11 51 9 11A MANGANESE 7.6 24 15 940 210 11A 0.96 MERCURY 0.13 11A 0.71 NICKEL 79 36 NA SELENIIM NA 0.42 SILVER 22 NA VANADIIM 24 600 19 42 11A ZINC 5.8 1,900 800 540 NA 1a --------------------------------------------------------------------------------------------------------------- CHEMICAL ss (ug/kg) SD (ug/kg) SB (ug/kgl SW (ug/l) GIi (ug/1) AIR (ng/ll flSH (m;/kg) ------------------------------------------·-------------------------------------------····-----------------~--- 1,1,1•TAICHLOROETHANE NA 100 11A 11A 1,1·01CHLOROETHENE NA NA NA 1,2·DICHLOROETHANE 11A 520 6 200 NA 11A BENZENE 11A 11A NA CARBOII DISULFIDE 11A 11A NA CARBOII TETRACHLORIDE 11A NA NA ETHYL BENZENE NA 46,000 4 2100 600 11A NA TETRACHLOROETHENE 11A 69 1 9 NA NA TOlUENE 11A 260 98 36 11A 11A TR I CHLOROETHENE NA 11A NA XYLENE$ (TOTAL) NA 250,000 19 8,400 2,90D 11A 11A ··------------------------····--···---···-······ ............. -.. --.... ---. ........... --········· -····-·····- 1,2,4·TRICHLOR08ENZENE NA 11A 11A NA 22 11A 2,4·DIMETHYLPHENOl NA 11A 11A 11A 6 11A 2·METHYLNAPHTHALENE 11A 11A 11A 11A 11A BIS(2·ETNYLHEXYL)PHTHALATE 11A 11A 11A 11A 11A 6.5 NAPHTHALENE 11A NA 11A NA 11A ----····---····-····-·-··· ··········-·····--·-·-····---···· -···--····-----····-----------··· ------------ 4.4'·000 11,000 51,000 37'0 1. 7 0.056 0.009 4,4'·DDE 37,000 4,400 480 0.011 0.015 4,4'•0DT 340,000 56,000 5,900 o.n D.045 0.009 ALDRIN 390 3.5 ALPHA·BHC 440,000 6,100 130 11 10 0.440 0.012 BETA·BHC 35,000 1,600 330 6. 1 5 O.D18 D.006 DELTA·BHC 160,000 2,300 9.2 18 O.D15 0.016 DIELDRIN 1,100 150 ENDOSULfAN II (BETA) 160 ENORIN ENDRIN KETONE 22 a1 2. 1 GAMIIA·BHC 160,000 9.1 4. 1 o.on 0.002 GAMIIA·CHLORDAIIE HEPTACHLOR 42 0.032 HEPTACHLOR EPOXIDE TOXAPNENE 340,000 ··-·····--···········--··--···--·-····--···---···-·-················--·-----·-··········-------·-·····--······· SS -Surficial soil; SD • Sedfant; SI -SI.Durfee• soil; SW • Surface water; GW -Grouidwater; AJA· Air; FISH· Fish tfa1ue; NA· Not ava;lable (analyafa 1111 not perforaed) or not applfcable. endosulfan I 4,4'-DDE heptachlor . 2/55 2/55 1/55 ND -160 ND -37,000 ND -42 The sampling stations were located either in or adjacent to suspected burial areas as identified during the geophysical survey. The BBC isomers in addition to 4,4'-DDT, and 4,4'-DDD, account for most of the contamination for this area. station SSS-218, located south of Area c, was the most contaminated with total pesticide concentrations of 1,162,800 ug/kg at a depth of 3 feet below grade. Sample sss-227, located in Area A, was the second most contaminated with a total pesticide concentration of 1,146,000 ug/kg at a depth of 3 feet below grade. Pesticide contamination in surface soil samples SSS-230 and SSS-224 suggests the existence of additional buried material southeast of Area A. PCBs were not detected in any of the surface soil samples. Total pesticide concentrations for the surface soils are shown in Figure 9. Several metals were detected in the six on-site samples analyzed for metals at concentrations greater than 2 times the CRDL. The contaminants detected in these samples included aluminum, calcium, chromium, copper, lead, iron, and vanadium in maximum concentrations (mg/kg) of 12,000, 220,000, 15, 36, 4.7, 7,800, and 24, respectively. other·analysis for these samples included total organic content (ND to 5,900 mg/kg), cation exchange capacity (1.8 to 16 meq/kg), and percent moisture (4 to 34 percent). Based on the qualifications required for the baseline risk a~sessment, the following organic compounds were evaluated as contaminants of concern for . the surficial soil media at th.e Twin sites Area: alpha-BBC, beta-BBC, gamma-BBC, delta-BBC, 4,4'-DDD, 4,4'-DDE, 4,4'-DDT, aldrin, dieldrin, heptachlor, toxaphene, endrin ketone, and endosulfan I. The metal contaminants. of concern include chromium, barium, coppe_r, mangane-se, mercury, vanadium and zinc. 5.2.2 Subsurface soils (Twin sites Area) A total of 15 subsurface soil samples were collected from the 5 borings labeled 2-MW-01 through 2-MW-05. These samples were analyzed for pesticides, PCBs, voes, TCL metals, and percent moisture. Eight of these samples were also analyzed for total organic carbon and three were analyzed for cation exchange capacity. Station SUB-201, located in the southwest corner of the area, was used to evaluate background conditions. The significant subsurface soil contaminants and their maximum concentrations are presented in Table· 1 Pesticide contamination was detected only in samples collected from stations SUB-203 and SUB-204. Sample SUB-203, directly downgradient from Area •A11 , contained the greatest level of tot~l pesticide concentrations at 6,730 ug/kg from a depth of 3 feet. 4,4'-DDT comprised over 50 percent of the total pesticide contamination det~cted in this sample. Xylene was the only voe detected in the subsurface soil samples at concentrations· greater than 2 times the CRDL. Concentrations for this contaminant ranged from 11 -19 ug/kg and were detected in the shallow and deep interval at SUB-202 and in all three intervals in SUB-204. PCBs were not detected in any of the subsurface soil samples. The t-~-t-al pesticide concentrations for subsurface soils are shown in Figure ,_. I ,, I I I I I I I ·I 1, I I I I I 'I I I -- l'\l ---J AEPCO Nonh (f) ----... -----.. -.. ----·-··1 = I ' ' I ' • ' 4)~ ¥ 0 RemNlel lmestlga11onlf ... lblllty Study (Rl/fS) AbenlNn PNllc:lda Dumpa stte AbardNn, Moor. County, Ho,th C.rolln,, FIGURE '/ 1~·-r10 r ,. ss SSi226 ,r. 3.,32300 ~-~•-am AREA sss-221e A ss •1146.000 ~ -2~9 ·• ""~ 3" .. ~.120 • EB Surflclal/Subsurface Soll Sample Depth of Sample 3· .. 2.geo Depth of Sample (ft)= Total Pesticide Concentration {ug/kg) . O Suspected Trench Area SCALE: Ff . Total pesticide concentrations in surficial and subsurface soils and location of suspected buried trenches -Twin sites Area. --.. PAGES LAKE + several metals were present in the subsurface soil samples in concentrations in excess of 2 times the CRDL. These contaminants included aluminum, arsenic, cadmium, chromium, lead, and manganese. With the exception of aluminum, all of the metals detected were located in the eastern portion of the area at stations SUB-202 and SUB-204. The percent moisture for these samples ranged from 9. to 20 percent. The total organic carbon (TOC) for the seven on-site samples analyzed for TOC ranged from 170 to 1,000 mg/kg. Cation exchange capacity was analyzed for in three samples, with values ranging from 2.7 to 3.9 meq/kg. Organic subsurface soil contaminants meeting the minimum concentration requirements for evaluation under the baseline risk assessment are as follows: 4,4'-DDD, 4,4'-DDE, 4,4'-DDT, alpha-BBC, beta-BHC, delta-BBC, gamma-BBC, dieldrin, endrin ketone, 1,2-dichloroethane, ethyl benzene, and xylene. Metal contaminants evaluated for this area include arsenic, cadmium, barium, vanadium, manganese and lead. 5.2.3 Air (Twin Sites Area) One air sample was collected from the Twin Sites Area and analyzed for pesticides and PCBs. Laboratory results indicate that this sample contained alpha-BBC, beta-BBC, delta-BBC, gamma-BBC, heptachlor, 4,4'-DDD, 4,4'-DDE and 4,4'-DDT .. concentrations for these pesticides ranged from 0.011 to 0.44 ug/m'. PCBs were not detected in this sample. 5.2.4 Area of contamination (Twin sites Area) Area C is a known pesticide disposal area where, unlike Areas A and B, a removal action has not occured to date. The exact boundaries of this disposal area are unknown, however, for volumetric estimation the visibly contaminated area at the ground surface is assumed to extend to a depth of 15 feet. Because Area A has undergone a prior removal action, only 10 feet of material was estimated for remediation. Both the areal and vertical extent of the contamination is not well defined due to the limited sampling conducted in these areas. Residual levels for total pesticide contamination exceeded 1,162,800 ug/kg for surface soil samples. The areas outlined1 for excavation were delineated using the surface soil sampling results. To obtain the target 10-• health-based cleanup level for this area, the estimated volume of material requiring remediation is 718,632 cubic feet or 26,616 cubic yards. Areas requiring excavation are presented in Figure 10. 5.3 Fairway six Area 5.3.l surface soils (Fairway six Area) The Fairway six Area consists of a pesticide disposal area located on the north and south side of fairway number six of "The Pit" Golf Links. A total of 37 sampling stations were.selected for this area including 4 background stations located around the perifery of the grid area. Two samples were collected at background station sss-314 at depths of 2-3 feet and 5-6 feet, while a single sample was collected at 5-6 feet for the remaining background stations. Two samples were collected from each station within the on-site grid area at depths ranging from 2-7 feet, ~· I I I I I I I I I I, I I, I I I · .. I I I I. AEPCO North (f) -- ~222 ~ f ,-,:;,-,:,__ DENS( + "' '-.,. • sss--m SSS-220 •l•II D Remedlll iwtsllgadONftulbfllty Studi {RI/FS) Abtrdetn Ptslldde Dump1 S119 Aberdun, Moon County, Horii C.rdlna o~n Surflclal, Oeplh (fl):: Total Pes11clde Concentration (uglkg) Area Excavated to 5 Feet BGL Area Excavated to 10 Feet BGL Area Excavated to 15 Feel BGL SCALE: FIGURE JO. Area of contaminated soil requiring remediation at the Twin sites Area. i l l PAGES + LAKE + = except·ifor .:SSS'-339, where only a single sample was collected. All of the samples collected·· were analyzed for pes'ticides only. Six of these samples were also analyzed for TCL metals, total organic carbon, cation exchange capacity, and percent moisture. Table 5 list.s the samples collected in soil and air in addition to the type of analysis performed on these samples. Significant contaminants and their maximum concentrations for all media at the Fairway six Area are presented in Table 6. TABLE 5 SAMPLE MATRIX FOR THE FAIRWAY SIX AREA No. of No. of Sample Depth Samples Media Location stations (feet) Yieled Analysis surface Background 4 2-3, 5-6 5 Pesticides Soils on-site 25 2-7 57 Pesticides I on-site 6 2-7 12 Pesticides, CEC TCL Metals, TOC, % Moisture sub- surface Background l 21-70 3 Pesticides, PCBs, soils voes, TCL Metals, TOC, CEC on-site 6 7-115 14 Pesticides, PCBs, voes, TCL Metals, TOC, CEC (one sample) Air on-site l NA l Pesticides, PCBs Of the 33 soil sampling stations at the Fairway Six Area, 23 contained detectable levels of pesticides. Pesticides were found at both depths sampled at 20 of the 33 stations. Seven of the 10 stations which contained no pesticide contamination were 'concentrated in the north and northeastern 200 feet of the grid area. The remaining 3 stations were concentrated in the southeastern section of the grid area. Thirteen pesticides were identified within the sampling grid. The types, frequency of detection, and concentration range are summarized below. Pesticide Frequency of Species Detection Concentration lug/kg) 4,4-DDT 43/69 (62%) 18" -210,000 alpha-BBC: 28/69 (41%) 9. 4• -10,000 beta-BHC 26/69 (38%) 8. 4• -4,800 4, 4-DDD , '·: 22/69 ( 32%) 20· 2,300 delta-BBC ''..-. 23/69 (33%) 8. 3· 1,800 30 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I TABLE SIGNIFICANT CONTAMINANTS AND THEIR MAXIMUM CONCENTRATIONS FAIRWAY SIX 1//c'1~ CHEMICAL SS-(m;/kg) SO (m;/kg) SB (m;/kg) SW (u;/l) GIi (u;/l) AIR (ng/l) FISH (m;/kg) ANTIMONY 11A ARSENIC BAR II.JI 12 56 12 11A 11A ,. 1 BERYL LIi.Ji NA CADMII.JI 11A CHROMII.JI 20 COBALT COPPER 12 LEAD MANGANESE 23 MERCURY 0.15 NlCKEL SE LEN II.JI e. 1 8.4 32 240 11A 0.32 11A 11A 110 11A 4.4 210 11A 0.22 11A 0.67 150 11A 3.2 11A 0.42 SILVER 11A VANADII.JI 180 16 11A ZINC 30 11A 61 CHEMICAL SS (u;/kg) SO (u;/kg) SB (u;/kg) SW (UQ/l) GW (u;/l) AIR (ng/l) FISH (1119/kg) 1,1,1·TRICHLOROETHANE NA 2 e 11A 11A 1,1·DICHLOROETHENE NA 5 2 11A 11A 1,2·.DICHLOROETHANE 11A 11A 11A BENZENE 11A 1 11A 11A CARBOII DISULFIDE 11A 60 11A 11A CARBOII TETRACHLORIDE 11A 2 11A 11A ETHYL BENZENE 11A 11A 11A TETRACHLOROETHENE 11A 3 11A 11A TOLUENE 11A 11A 11A TRICHLOROETHENE NA 11A 11A XYLENES (TOTAL) 11A 11A 11A ·-·····--------------------------···-.............. ·---------· ---------·· -----······ ----··--·--·-----------1,2,4·TRICHLOROBENZENE 11A NA 11A 11A 21 NA 2,4·DIMETHYLPHENOL 11A 11A 11A 11A 11A 2·METHYLNAPHTHALENE 11A 11A 11A 11A 11A BIS(2•ETHYLHEXYL)PHTHALATE 11A 11A NA NA 11A 3.3 NAPHTHALENE 11A 11A 11A 11A 11A --------------------------.. .. .. . .. .. .. ----·------·----------------····· ----------------------............... 4,4'·000 9,300 71 52 0.012 0.018 4,4'•DOE 1,800 150 30 0.006 0.018 4,4' ·DDT 210,D00 1, 100 710 0.035 0.016 ALDRIN 200.0 C 0.07 ALPHA·BHC 10,000 550 0.7 7.8 0.032 0.016 BETA·BHC 4,800 22 260 7 0.006 0.006 DEL TA·BHC . 1,800 130 13 0.022 DIELDRIN 360 ENDOSIJLFAN 11 (BETA) ENDRIN ENDRIN ICETOIIE 80 GAMMA·BHC 1,600 120 0.4 0.002 GAMMA-CHLORDANE HEPTACHLOR 930 0.01 HEPTACHLOR EPOXIDE 10 TOXAPHENE 12,000 -----------------------------------------------------------------------------------------------------······-··· SS • Surffcfal aofl; SD· Sedl11ent; SI• SU:.Urf■ce aotl; SW -Surface water; GW -Grcan::lwater; AIR· Afr; FISH -Ffsh tissue; NA -Not ava;lable (anelysfa was not perfo,-.,d) or rot applicable. 3/ gamma-BHC 13/69 (19%) 0. 5· -1,600 dieldrin 6/69 (9%) 17• 360 4,4-DDE 6/69 (9%) 10· -1,800 toxaphene 5/69 (7%) 210· -12,000 heptachlor 3/69 (4%) 18 -930 aldrin 3/69 (4%) 16 -200 endrin ketone 3/69 (4%) 16. -80 heptachlor epoxide 1/69 ( 1 % ) 10· . Indicated concentration below two times the CRDL. Total pesticide concentrations at the shallow interval (2-3 feet) ranged from non-detect (ND) to 214,230 ug/kg, while those at the deeper interval (5-6 feet) ranged from ND to 14,770 ug/kg. Jotal pesticide concentrations increased with depth only at stations SSS-310, -317, 318, -334, and -338. Because much of the area has been disturbed during the excavation.of the buried trenches, it is unknown whether the elevated levels found at depth are due to downward migration of the contaminants or are residues of buried material. Total pesticide conentrations in the surface soils are shown in Figure 11. several metals were detected in the 6 samples collected for this analysis in concentrations greater than 2 times the CRDL. These contaminants included aluminum, chromium, iron, lead, magnesium, manganese, vanadium, and zinc. Th.e six samples collected for metals analysis were also analyzed for percent moisture (5 -9 percent), total organic carbon (ND - 2,200 mg/kg), and cation exchange capacity (3.4 -11 meq/kg), Based on the qualifications required for the baseline risk assessment, the following organic compounds were evaluated as contaminants of concern for the surficial soil media at the Fairway Six Area: alpha-BHC, beta-BHC, gamma-BBC, delta-BBC, 4,4'-DDD, 4,4'-DDE, 4,4'-DDT, aldrin, dieldrin, delta-chlordane, heptachlor, heptachlor epoxide, toxaphene, and endrin ketone. The metal contaminants of concern include chromium, barium, copper, manganese, mercury, vanadium and zinc. 5.3.2 subsurface soils (Fairway six Area) Three subsurface soil samples were generally collected from each of the six on-site moni taring wells: one above the water table ("A"), one from the capillary fringe zone ("B"), and one from the well screen interval ("C"). A total of 18 samples were collected from 7 to 115 feet below grade and were analyzed for pesticides, PCBs, voes, and TCL Metals. one sample was analyzed for CEC. samples collected from boring 3-MW-01 (SUB-301) were used to evaluate,background conditions. The significant subsurface soil contaminants and their maximum concentrations are presented in Table 6. Borings for wells 3-MW-02, 3-MW-03, and 3-MW-04 were contaminated with at least two BHC isomers, 4,4'-DDT and 4,4'-DDD. Sample SUB-303A, collected at a depth of 13.5 feet, contained the greatest concentration of total pesticides, 1,702 ug/kg. The total pestide concentrations in subsurface soils are ·.shown in Figure 11. .3 '2.. r I I I I I I I I I I I I I I 1. I I I I I I I I I I I I I I I I I I I I I I SSS-398 • 5'•NO AEPCO North @ FIGURE // + J • ., ~ •NO SS-J25 + ,, .!!,.,--==- + ~(.6 5 •NO "' ' SSS-J18 WW-OJ J •NO ffiu•-1as2 s--JtJ Z• •300 SSS-J\4 • Y•HD S'•NO -j- ""' '--" + SUrflclal/Subalrfac. soll MmPI• Sample dl,pth ■ Total Pfftlc:ldll Conc:.nt...tlon (~) SU.,.c:ted tffllch Prwloualy EzcnetM TNnch + SCALE: 1 a • ,. Total pesticide concentrations in surficial and subsurface soils and location of suspected buried trenches -Fairway six Area. 33 r ( Acetone was found in.both the shallow and mid-level depth samples in boring 3-MW-02 at concenrtations of 5,400 and 560 ug/kg, respectively. Acetone was also detected in the deepest sample at 3-MW-03 and 3-MW-04 at 500 and 460 ug/kg, respectively. carbon disulfide was present in sample 3-MW-06 at a concentrations of 60 ug/kg. PCBs were not detected in any of these samples. Several metals were detected in the subsurface soil samples at concentrations greater than 2 times the CRDL. These contaminants include aluminum, chromium, copper, iron, lead, manganese, and vanadium. Total organic carbon was detected in 4 of the 5 on-site borings ranging from ND to 1,700 mg/kg. These levels generally decreased with depth. A cation exchange capacity of 103 meq/kg was observed for sample SUB-303C. Subsurface soil contaminants of concern meeting the minimum concentrations requirements for evaluation under the baseline risk assessment are as follows: 4,4'-DDD, 4,4'-DDE, 4,4'-DDT, alpha-BHC, beta-BHC, delta-BHC, and gamma-BHC. Manganese was the only metal contaminant evaluated for this area. 5.3.3 Air (Fairway Six Area) One air sample collected at the Fairway six Area was analyzed for pesticides and PCBs. This sample was contaminated with alpha-BHC, beta-BBC, heptachlor, 4,4~-DDD, 4,4'-DDE, and 4,4'-DDT. Concentrations for these contaminants ranged from 0.006 t6 0.035 ug/m'. PCBs were not detected in this sample. 5.3.4 Area of·contamination (Fairway six Area) Residual levels for total pesticide contamination exceeded 214,230 ug/kg for surface ;oil samples. Total pesticide levels up to 1,702 ug/kg were also detected in the subsurface soil samples. To obtain the target 10-• health-based cleanup level for this Area, the estimated volume of material requiring.remediation is 444,220 cubic feet, or 16,453 cubic yards. An additional 22,000 cubic yards of material stockpiled at this Area during the emergency removal action conducted in 1988 will also require remediation. Areas requiring excavation are presented in Figure 12. 5.4 Mciver Area 5.4.l surface soils (Mciver Area) . ' One background station (SSS-407) was selected for the Mciver Area and was located 400 feet southwest of Area B. This sample was collected at a depth of 3-4 feet. A total of 8 stations were sampled within the grid of Area B. Samples were collected at depths of 3-4 and 5-6 feet at seven of these stations, two of which also had surficial samples collected. Station.sss-403 was sampled at 3-4 feet only due to auger refusal. A single sample (SSS-404) was split and analyzed for TCL metals, TOC, CEC, and percent moisture. This yielded 19 samples collected for pesticide analysis (including 1 duplicate). Table 7 lists the samples collected in soil in addition to the type of analysis performed on these samples.·. The significant contaminants and their maximum concentrations for all,media at the Mc Iver .Area· are·, :presented in Table 8. I I I I I I I I I I I I I I ; ...__ \I I ) I I • I I I I I I I I I I I I I I SSS-J98 • s·-i,o AEPCO North (i) I T I -,- SSS-J14 e J'•~J 5'•'iC Remedlll lnvt1tlg1IIM'Fuslblllty Study {RI/FS) Abffl1ttn Ptslltlde Dumps S111 Aberdeen,~ Coonty, North Carolina -• u . J•NO SSS-32~ 5•NO • J •NO 19~ S•NO SS-325 -1 29 '~:::-::: -~~ ,,, SSS-33-4 ~J'•NO -~ J-25"6 5•1'10 ,:,5. -1 260 :jJ£1"-..._ ' SSS-JH! _.; ., ' Lllilli); • Swfldll S.lfOlt loettlon ""' SSS-337 -e:-W~ ·-n.eoo ·~E,\00 +sss-,,. • r.... DI~ (ft)• Total Pfltleldl Cor,e. (ll;,'I:;) C) Ar• Pm-loualy E.rcavei.d § ArM E.rcavmd ID 5 ~I BOL fS.:SJ Nu [leant.cl ID 1B F.11 SGL J •NO 5•J\1 SCALE: 1 11 111 + + ( - FIGURE/~. Area of contaminated soil requiring remediation at the Fairway Six Area. .1 TABLE 7 SAMPLE MATRIX FOR THE MCIVER AREA No. of No. of sample Depth Samples Media Location stations (feet) Yieled Analysis surface Background l 3-4 l Pesti'cides soils on-site 8 0-6 18 Pesticides on-site l 3-4 l Pesticides, TCL (Split) Metals, TOC, CEC, % Moisture Sub-Background l 6, 18, 3 Pesticides, surface 64 PCBs, voes, soils TCL Metals on-site l 8, 9, 3 Pesticides, (split) 44 PCBs, voes, TCL Metals TOC, CEC The background sample (SSS-407) revealed no pesticide contamination. of the 8 soil sampling stations collected at Area B, 6 revealed detectable levels of pesticides, with all but one containing at least 4 different pesticides. BBC isomers detected in the surficial soil samples included alpha-BBC, beta-BBC, gamma-BBC, and delta-BBC in concentrations (ug/kg) up to 430,000, 79,000, 16,000, and 32,000, respectively. other pesticides detected included 4,4'-DDT; -DDD, -DDE, and toxaphene in concentrations (ug/kg) up to 180,000, 22,000, 7,400, and 160,000, respectively. stations sss-401, sss-404, and sss-405 contained the highest concentration of total pesticides at all depth intervals. The total pesticide concentration at both depth intervals in the surficial soils appears to be associated with proximity to the exc~vated Area B. It should be noted that samples sss-402 and SSS-406, collected from the excavation area, contained little or no pesticide contamination. Figure 13 show the total pesticide concentrations for the surficial soils. The pesticides detected, their frequency of detection, and concentration ranges are summarized below. Pesticide Frequency of Species Detection Concentration lug/kg) 4,4'-DDT 10/18 (56%) 85 -180,000 alpha-BBC 10/18 (56%) 20 -430,000 beta-BBC 9/18 (50%) 35 -79,000 delta-BBC 7/18 (39%) 11· -32,000 gamma-BBC (lindane) 6/18 (33%) 10· -16,000 4,4'-DDD 5/18 (28%) 87 -22,000 I I I I I I I I I I I I I I I I I I I I I • I I I I I I I I I I I TABLE f SIGNIFICANT CONTAMINANTS AND THEIR MAXIMUM CONCENTRATIONS McIVER A-<cA CHENICAL ANTIMONY ARSENIC BARll.04 BERYLLll.04 CADNll.04 CHRCJ41l.04 C06ALT COPPER LEAD MANGANESE HERCJRY NICrEL SELENll.04 SILVER VANADllJI ZINC CHENICAL 1,1 11•TRICHLOROETHANE 1,1·01CHLOROETHENE 1,2•DICHLOROETHANE BENZENE CARBON DISULFIDE CARBON TETRACHLORIDE ETHYL BENZENE TETRACHLOROETHENE TOLUENE TRICHLOROETHENE XYLENES (TOTAL) ········------·······--··· 1,2,4·TRICHLORO&l:NZENE 2,4•DIMETHYLPHENOL 2·HETHYLNAPHTHALENE BIS(2·ETHYLHEXYL)PHTHALATE NAPHTHALENE ················----------4,4·, ·DOD 4,4'-DDE 4,4'·0DT ALDRIN ALPHA·BHC BETA·BHC DELTA·BHC DIELDRIN ENDOSULFAII II <BETA) ENORIN ENORIN KETONE GA14MA·BHC GA14MA•CHLORl)ANE HEPTACHLOR HEPTACHLOR EPOXIDE TOXAPHENE SS (11111/k;l SI> (11111/k;J SB (11111/k;J SIi (ug/l) GW (ug/ll AIR (n;/l) FISH (11111/kgJ 34 8.3 30 10 4.5 12 15 4.4 27 10 54 NA NA NA NA NA NA- NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA SS (ug/kg) SI> (ug/kg) SB (ug/kg) SIi (ug/l) GW (ug/l) AIR (n;/l) FISH (1111/kg) NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2 NA NA . ----·. --.. ----------- ---------------------· .............. ----------· ·-----------NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA ------····· ....... ---... .. ....... --.. --------·---------······· ---------·· ·-----------22,000 210 320 NA NA 7,400 83 NA NA 180,000 1,700 0.03 NA NA NA NA 430,000 83 0.065 D.02 NA NA 79,000 22 74 0.14 0.03 NA NA 32,000 200 0.083 0.02 NA NA o. 11 NA NA NA NA o.11 NA NA NA NA 16,000 25 0.01 NA NA 25 NA NA NA NA NA NA 160,000 2,600 NA NA -------------------------------------------------------------···················-------------------------------SS • 5urffclal aofl; SO· Sedfaent; SB• Sl.bl:urface soil; SW -Surface water; G\I • Grouidwater; All• Air; FISH• fl1h tl11ue; NA• Not 1vall1ble (analyol1 ,.., not perfonmd) or not applicable. 37 ~NSE IBEES !. 407 l". Actual Loco11on ,'5()· fl· AEPCO MC1-C •408.86 ,;, 0 7SE TREES " 1---No-rt_h_-1 Remedial lrivesllg1Uon/Ft11lblllty Study (RIIFS) Ablnleen Ptttlclde Dumps SIii . Ci:) Abenleer., Moon County, Nol1h Clrollna 4-IIW-02 e---a•.49z1 9"•J92 44'aJ2 S i40J J'a142 LEGEND: eEB ,· .. 147 Surflclal/Subsurrace soll sample Depth of sample (ftl • Total Pesticide Concentratlon {ug/kg> SCALE: I .. 1 ___ _,395'-.. 'Co~ ..... ··· .-, .' ' in surficial and subsurface FIGURE /J • Total pesticide_concfntr~ti,ops -. --.. .. -soj .. -Mciver Ar---I.Ill .. -----11!1 I I I I I I I I I I I I I I I I I I 4,4'-DDE toxaphene 4/18 2/18 (22%) (11%) 21* -7,400 11,000 -160,000 Indicated concentration below two times the eRDL. A single on-site station (SSS-404) was analyzed for TeL metals. Because the background surficial soil station was not analyzed for metals, the shallow subsurface soil sample for the background well for this area was used as a comparative background sample. The metals detected in the on-site surficial soil sample were typical of the Aberdeen area and were comparable in concentration to the background sample. Metals detected at 2 times the cRDL include aluminum, chromium, and manganese, at concentration (mg/kg) of 2,100, 4.3, and 10, respectively. Based on the qualifications ·required for the baseline risk assessment, the following organic compounds were evaluated as contaminants of concern for the surficial soil media at the Mciver Area: alpha-BEe, beta-BEe, gamma-BEe, delta-BEe, 4,4-DDD, 4,4-DDE, 4,4-DDT, and toxaphene. The metal contaminants of concern include manganese and zinc. 5.4.2 Subsurface Soils (Mciver Area) Three subsurface soil samples were collected from each boring for the 2 monitoring wells installed for this area. These samples were collected above the water table (suffix "A"), one from the capillary fringe zone ("B"), and one from the interval where the well screen was installed ("e"). Depths for these samples ranged from 6 to 64 feet below grade. All samples were analyzed for pesticides, PeBs, voes, and TeL metals (RI 4-130). The significant subsurface soil contaminants and their maximum concentrations are presented in Table 8. Background sample SUB-401B contained a trace of alpha-BEe (27 ug/kg) but is not thought to be site related and may indicate another source of contamination. No PeBs were detected in any samples collected from this boring. The on-site borings revealed considerable subsurface contamination with pesticides. BEe isomers were common to all the on-site samples with the shallowest interval (SUB-402A) containing several other pesticides including 4,4'-DDT, 4,4'-DDD, 4,4'-DDE, toxaphene, and total chlordane in concentrations (ug/kg) of 1,700, 320, 83, 2,600, and 55, respectively. Figure 13 shows the total pesticide concentrations for the subsurface soils. sample SUB-402B contained the only significant levels of voes -acetone (260 ug/kg) and chlorobenzene (45 ug/kg). Trace levels of xylene and chlorobenzene were present in samples SUB-402B and SUB-402e, respectively. Total organic carbon analysis was performed on all samples collected from station SUB-402 with a range of 230-1,400 mg/kg. A single sample (SUB-402e) was analyzed for cation exchange capacity which was detected at 3.4 meq/kg. several metals were detected from the on-site station for this area. The following metals were present in concentrations greater than 2 times the CRDL: aluminum, calcium, chromium, iron, lead, manganese, and vanadium. Based on the qualifications required for the baseline risk assessment, the following organic compounds were evaluated as contaminants of concern: 4,4'-DDD, 4,4'-DDE,..".4,4'-DDT, alpha-BBC, beta-BBC, delta-BBC, gamma-BBC, alpha-chlordane,.: delta-chlordane, toxaphene, chlorobenzene, acetone, and xylene. The metal·.:contaminants of concern included: barium and manganese. 5.4.3 Area of contamination (Mciver Area) Total pesticide levels exceeded 926,400 ug/kg for surface soil collected west of Area "A". A single s~bsurface station (SUB-402).presented a maximum total pesticide concentration of 4,921 ug/kg at a depth of 8 feet. To adequately quantify the extent of subsurface soil contamination, additional samples will be required. To obtain the target 10-• health-based cleanup level for this area, the estimated volume of material requiring remediation is 74,000 cubic feet, or 2,740 cubic.yards. An additional 3,200 cubic yards of material currently stockpiled at this site during the emergency removal action conducted in May 1989 will also require remediation. Areas requiring remediation are presented in Figure 14. · 5.5 Route 211 Area 5.5.1 Surface soils (Route 211 Area) A total of five sampling stations were selected for this area in addition to a background station located 200 feet northwest of the sand basin and labeled sss-591. The five on-site surface soil samples were located within the old sand mining basin were analyzed for pesticides. A total of 10 samples were collected from this area and analyzed for pesticides. surface soil sample sss-502B was the only sample analyzed for metals at this area. Table 9 lists the soil samples collected in addition to the type of analysis performed on these samples. The significant contaminants and their maximum concentrations for all media at the Route 211 Area are presented in Table 10. TABLE 9 SAMPLE MATRIX FOR THE ROUTE 211 AREA No. of No. of Sample Depth samples Media Location stations (feet) Yieled Analysis surface \ Background 1 2 1 Pesticides Soil.a on-site 4 2 & 5 8 Pesticides on-site 1 0 1 Pesti~ides, TCL Metals Sub-Background 1 5-32 3 Pesticides, PCBs, surface voes, TCL Metals soils on-site 2 5-32 6 Pesticides, PCBs, voes, TCL Metals L(D I I I I I I I I I I I I I I I I I - ---- AEPCO North ~ 110-C ___.,,,.---.•408.88 ,,,,,-~ 0£NSE TREES R8tll8dlll lnve1Ug1Uon/Featlblll1J Study (RI/FS) Abfflleen Pesticide Dumps Site Abenlee11, Moore Count,, North Carolina S -403 • J'-142 e $ SU!fldll/SublurflOI Sample LOClllan r... Depth (ft)• Total P9otlcldl c...www,ballan (ug/llg) § Ar• E1Cav■t■d III S Feet BGL Ar• ERaolllld lo 10 Feel BGl SCALE: I FIGURE!¥. Area of contaminated soil requiring remediation at the Mciver Area. I • X TABLE 10 SIGNIFICANT CONTAMINANTS AND THEIR MAXIMUM CONCENTRATIONS ;',. ROUTE 211 AeeA CKEMJCAL SS (IIIG/k;l SD (111G/kg) S8 (IIIG/k;) SIi (u;/1) GIi (u;/1) AIR (ng/1) FISK (11111/t;) AIITIMOIIY ARSENIC v BARILtl BERYLLILtl CADMILtl CKRCIIILtl , C08ALT COPPER •LEAD · ,,. MANGANESE ·, MERCURY ; NICKEL SELENILtl SILVER VANADILtl ZINC 8.6 7. 1 1,200 4,800 5.3 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A NA 9.Z 3.4 24 11A 11A 11A 11A 11A 11A 11A . 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 20 11A 11A 11A 11A 60 11A 11A 11A 11A 11A 11A 10 ; 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A CHEMICAL SS (u;/k;l SD (u;/t;) SB (u;/t;l SIi (ug/1) GIi (u;/1) AIR (nail) FISK (11111/k;l . 1,1,l•TRICKLOROETKANE 1,1•DICKLOROETKENE 1,Z'DICKLOROETKANE BENZENE CARBOII DISULFIDE CARBOII TETRACHLORIDE ETKYL BENZENE TETRACKLOROETKENE v'TOLUENE TRICKLOROETKENE XYLENE$ (TOTAL) 1,Z,4·TRICKLOR06ENZENE Z,4·DIMETKYLPKEN0L 2·NETKYLNAPKTKALENE BIS(Z·ETKYLKEXYL)PKTKALATE NAPKTKALENE 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A ---·-------11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 5 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 1 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A ,.IIA 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A 11A -4,4'•D00 60,000 NA KA kA IA ,4,4'·00E 11A 11A 11A 11A J4,4'-DDT 1,200,000 NA n,ooo KA 0.05 KA KA ALDRIN 11A 11A 11A 11A ALPKA·BKC 2,200,000 11A 11A 0.02 11A 11A . BETA·BKC 120,000 11A 11A 0.04 11A 11A , DELTA·BKC 18,000 NA 11A 0.03 11A 11A DIELDRIN NA 11A 11A 11A ENOOSULfAll IJ (BETA) 11A 11A 11A 11A ENOR IN 11A 11A 11A 11A ENDRI N KETONE 11A 11A 11A 11A · GAMMA·BKC 41,000 11A 11A 0.02 11A 11A GAMMA·CKLORDAIIE 11A 11A 11A 11A KEPTACKLOR 11A 11A 11A 11A NEPTACKLOR EPOXIOE 11A 11A 11A · 11A v TOXAPHENE 2,300,000 NA 63,000 NA NA NA ···················-························································································--- SS • Surficfel aoll; SO· Sediaent; SB• 51.bsurfece 10il; SW• Surface water; Glil • Grou-dwater; AIR. Air; FISK. fish tissue; NA. Not available (anelytll VIS not perfonoecl) or not lf'Pllcable. J/ 2.. I I I I I I I I I I -:-:.; J., I I I I I I I I I I I I I I I I I I I I I I I I I I I I Four of the five surface soil sample stations exhibited contamination with pesticides. These pesticides include alpha-BBC, beta-BBC, delta-BBC, and gamma-BBC, 4,4'-DDT, 4,4'-DDD, and toxaphene in concentrations (ug/kg) up to 2,200,000, 120,000, 18,000, 41,000, 60,000, 1,200,000, and 2,300,000, respectively. station sss-501, located in the center of the basin, was the most contaminated with total pesticide concentrations of 5,939,000, 36,430, and 59,650 ug/kg at depths of 0, 2, and 5 feet below grade, respectively. Sample SSS-505, located on the western side of the basin, was the second most contaminated surficial soil sample location. Toxaphene comprised over 99% of the total pesticide contamination of 200,360 and 13,075 ug/kg at depths of 2 and 5 feet below grade, respectively. Figure 15 shows the total pesticide concentations in the surface soils. Several metals were detected in the single on-site sample analyzed for metals in concentrations up to 2 times the CRDL. The contaminants detected in this sample included magnesium, manganese, and mercury in concentrations (mg/kg) of 3,800, 1,200, and 4,800, respectively.· The mercury concentration in this sample far exceeded.the concentrations detected for any other site area. To qualify the extent of mercury present for this area, additional sampling will be required. Based on the qualifications required for the baseline risk a.ssessment, the following organic compounds were evaluated as contaminants of concern for the surficial soil media at the Route 211 Area: alpha-BBC, beta-BBC, gamma-BBC, and delta-BBC, 4,4'-DDD, 4,4'-DDE, 4,4'-DDT, and toxaphene. Metals of concern for this site include nickel, barium, cobalt, manganese, mercury, and thallium. 5.5.2 subsurface Soils (Route 211 Area) Three boring locations adjacent to the sand basin were utilized for the collection of subsurface soil samples. A total of 9 samples were collected from 5 to 32 feet below grade and analyzed for pesticides, PCBs, voes, and TCL metals. station SUB-501 located at boring 5-MW-01 is considered to be either upgradient or sidegradient of the areas of known contamination based on groundwater flow direction to the west-northwest or to the southeast. The significant subsurface soil contaminants and their maximum concentrations are presented in Table 10. Both 4,4'-DDT and toxaphene were detected in boring 5-MW-03 at concentrations (ug/kg) of 33,000 and 63,000, respectively. Trace amounts of 4,4'-DDT were detected in boring 5-MW-02 at 5 and 15 feet below grade. Total pesticide concentration for the subsurface soils are shown in Figure 15. Acetone was the primary voe contaminant in the subsurface soil samples. The highest concentration (3,300 mg/kg) was present in boring 5-MW-03 at 7 feet below grade. Acetone was also detected in boring 5-MW-02 at 15 and 24 feet below grade in concentrations of 1,100 and 750 ug/kg, respectively. Trace amounts of chloroform, bromodichloromethane, trichloroethene, and toluene were also detected in boring 5-MW-02. Several metals were detected in samples collected on-site which exceeded 2 times the CRDL. These contaminants include aluminum, chromium, iron, lead, and manganese. L/3 - 40 ( ___________ __..•'> J::~({~oooo ~Q~NO s·~s9,65o~SS-"501..,.. 5'DND 1 ,5-;::-..... ,.... .. \ ~s~• 0 ·. • •·•••• sJ.~04 s-:;J.: ~{;r~?r~ .. : .. ,JJ:~gY•·~Nb ••"' .·.~-50,3, .· · ~· ---- 46 5-MW- - - - - - - .... ~ 45------5'$2 -------::::.--" = + AEPCO North @ - . ::,...;:: c--.;.:_ _____ .,,,, Remedial lnvesUgaUon/Feaslblllly Study (RIIFS} Abenleen Pesticide Dumps Site Aberdeen, Moor8 County, North Carolina LEGEND: 9 0 Surf1c1al/SubSurface soll sample r-1•1 Depth or sample <rt)· Total Pestlc1de Concentration <ug/kg) ; . I J5 SCALE: J etilltrf'IIIIJ I .. - ., ., 40 ,. - 0 NSE TREES • s \ DENSE TREE;\ I , .. - I I I I I I I I I I I I I I I I I I I subsurface soil contaminants meeting the minimum concentration requirements for evaluation under the baseline risk assessment are: acetone, toluene, 4,4'-DDD, 4,4'-DDE, 4,4'-DDT, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, and toxaphene. Metal contaminants evaluated for this site include lead, manganese, and barium. 5.5.3 Area of Contamination (Route 211 Area) Residual levels for total pesticide contamination documented in the RI exceeded 5,000,000 ug/kg in surface soils near the center of the basin. Total pesticide levels up to 13,075 ug/kg were also detected at depths up to 5 feet for the western section of the basin. A subsurface soil sample collected 20 feet east of the basin n~~ monitoring well 5-MW-03 contained 96,000 ug/kg of total pesticides (4,4-DDT and toxaphene). This elevated level may be indicative of additional buried material and may also require remedial action. To obtain the target 10-• health-based cleanup level for this area, the estimated volume of material requiring remediation is 121,000 cubic feet, or 4,481 cubic yards. Figure 16 shows the area of contaminated soil requiring remediation. 6.0 SUMMARY OF SITE RISKS The Aberdeen Pesticides Dumps site is releasing contaminants to the environment. chapter 6 of the RI entitled "Baseline Risk Assessment" presents the results of a comprehensive risk assessment that addresses the potential threats to public health and the environment posed by the site under current and future conditions assuming that no remedial actions take place and that no restrictions are placed on future use of the Site. The risk assessment consists of hazard identification of the contaminants of concern, an expos~re assessment, identification of toxicological criteria, and risk characterization. Because the site consists of five separate areas, each area was treated separately in the risk assessment. Each part of the risk assessment is discussed below. 6.1 Contaminants of Concern Data collected during the RI were reviewed and evaluated to determine the •contaminants of concern" at the site which are most likely to pose risks to public health. These contaminants were chosen for each environmental media sampled (e.g., groundwater, surficial soil), based on screening criteria including frequency of occurrence in each media, presence at levels considered to be greater than background, associatiOn with site activities, either due to Site related concentration gradients or through historical data on waste disposal, and comparison of levels found in quality control (QC) samples, if applicable. Once these contaminants of concern were identified, exposure concentrations in each media were estimated. The maximum concentrations detected were compared to the calculated 95% confidence level of the arithmetic average of all detects, and the lower of these values was chosen as the estimated exposure concentration. Table 11 identifies the contaminants of concern AEPCO Nor1h ~ Remedial bwesUgadowFeallblllty Study (RIIFS) Abenleen Pesdelde Dumps SIie Aberdeen, Moont Coooty. Nor1h Clrollnl LEGEND · -~-591 {150' North) J'•ND e fB Surflclll/Subaurflcl Sample L-tton r• Doplh (II)• Tolll l'Ntlclde Co,-matlon (~) ISS] Ar• Emnled ID 10 felt BGI. ,. SCALE: I FIGURE /~, Area of contaminated soil requiring remediation at the Route 211 Area. D SE TIIEES t, \ J5 DENSE TREE\ 40 J • ,L ------------------- I I I I I I I I I I I I I I I I I I I for each area and the reasonable maximum exposure concentration in each media sampled which was analyzed in the risk assessment. 6.2 Exposure Assessment The exposure assessment identified potential pathways and routes for contaminants of concern to reach receptors and the estimated contaminant concentration at the points of exposure. Contaminant release mechanisms from environmental media, based on relevant hydrologic and hydrogeologic information (fate and transport, and other pertinent site-specific information, such as local land and water use or demographic information), were also presented. Tables 12 and 13 provide~ the estimated exposure frequencies and estimated time of exposure per event for target populations under current and future land use conditions at the site. current and future land use conditions for each area are discussed below. The Farm chemicals Area is located in a residential/industrial zone. The property is secured by a chainlink fence. Currently, Farm Chemicals has closed its operation at the facility, therefore a current on-site worker scenario was not assumed. Since the area is totally fenced in and locked, site trespassing is highly unlikely. At the time of the remedial investigation, an employee of Farm Chemicals was living at the site or at least spending a few nights a week there. For future land use this area may be reopened as a pesticide blending/mixing production facility or be converted into a residential community. Thus, the target populations at the Farm Chemicals Area under current and future land use are: 0 0 on-site adult and child residents (current & future) on-site adult workers (future) The Twin sites Area, located approximately 400 feet north of the Farm chemicals Area, is in an open area surrounded by woods. The nearest residents live about .350 • upgradient from the area. This area and its surroundings are zoned residential. However, the county may change the zoning to recreational use, since the area is approximately 350 feet from Pages Lake. Based on these possibilities of future'land use and current land use conditions, the target populations are: 0 0 0 0 adult and child residents nearby (current) site trespassers (current) on-site adult and child resident (future) recreational adult and child users (future) The Fairway Six Area is partially located on the sixth fairway of the Pit Golf Links golf course. The golf course, located in a rural,' sparsely populated area, is frequently visited by golfers and workers. The southern half of the site is located on private property which could be developed into a residential community. Thus, target populations under current and future land use are: 0 0 0 0 on-site workers (current and future) residents nearby or site trespassers, adults and children (current and future) golfers (current and future) on-site adult and child resident (future) '17 -1:::. ""' \ - -....... --... -... ------.. -- cwrNICAl ··------------------------..,, ... ua■1c ... , .. NITl.lll.11 ... , .. ._, .. <OUI.J ._.. lW -1( NlltUIJ ■Ital RlHl\.111 SILVI■ VAUDU.M WIC ·------······-··---------· 1.1.1•tl1Clft.mto!t11Alrf I, l•DICJl'll'.IN'.JfTNfll 1,Z•DIClflOROITIIAJft: ll■ztlll! CAlmlDISU."Df CAIi-tUUClfLmlDf nm. IHZ!llf flTIACllt.OIUTNfl! Tot.WIil tllCJI\.OIO!Tlfllf ITlUH (TOTAl) ············-········--·-- 1,z.,-,11m01101t11r• Z,4•DINT91lLPlfflDl Z·•tnLIIAPIITUL(lf( lll(Z·fTITlllfXTL),Nfltl.Uff --······--··-·-······--·-·--,., .... ,., ... ,., ... , MNI■ IOU•lllt KTA·IIC Dll.lA·INC OIII.Dltl lll90IUI..FU , •.. II (HTA). 1-1■ QT(llf ---URll:.~WLORDAII! •PllClll.o■ TABLE // CONTAMINANTS OF CONCERN AND EXPOSURE CONCENTRATIONS FOR ALL ENVIRONMENTAL MEDIA FARM CHEMICALS AND TWIN SITES AREAS ---.. ----. ··----------------········ ----------------------------------------------------------····----------· Tvl11. Sites .AUA .....•....•............•. Farm Chemicals Area ... --. -----. -·--.. --. ---. -. -....... IOlld C...,.;, Ll""ld 1..,11 -~~Hf.111. -~.l3~'-t). All 111 ---------------------------········ ------------.--•·· ss GW (ug/1) II • .... ., ., C..,11 ---.. ----.. ----·-····· .. ---. ----. ---········ ------------------------------··· -----------............ uo J,:,00 J7,'11 Z,'6J,OOO ICIO Z1, 191 n,,., ffl 194.0CIO ,., ,,zo, l,ffl ffl 10,IH SJ,119 Z!O • J,ffl , .. • ,,.,, n.2111 se.m 710 ,. 5', 172,000 ' ,.no 91,051 1'.1 • 9,BS4.000 S, 162 7,ffl 16,966 NO '°' 110 78,000 87 no Z,000 1DJ 11,91111 ,. 420 n ''·"' no,rn, "·' 15,ZM,000 '·'·" ,.,eo 603,017 11,000 "' '4ll ........ ---.. --....... -·········· ·····----------. ------. ---.. -----. --------... .••...••... ··--·· ..... 388 ICIO ZI 161 67.1 ,.w IJ,011 "·"' "' ilOO no " I ' 1146 • JI ,. ,, ,,.,°' "·"° l,ffl 1,91111 ------------...... -... . ----. --... .....••.... ··-········ --········· -·········· ............. -···--····· , .. n J8 • .. ' " '·'°° ---·-·····-------····· ............. ................ .............. ............ ............ ----······· ··········· ... ••• •--,,.m 0.0, O.CIOCIOJS ,.m ,,.m ••• ••• '·" , __ , 645 D.OS O.OCI01' 1.m 1,U7 " 9'S9,500 0.0, 0.-z,, ,a 11.m ,., O.D •••• ··-' O.CIOCIOII ·41 ,., ICIO , .. 10 ··-57,57, " O.DDDD6t n,191 Z,'15 11 , O.DDDDDZS J,IJO 799 6.Z J ' O,CIOCIOII Z9.Z71 ,.z 18 D.CIOCIOIS 37, "' ,., O.CIOOOOZS ,z.u, tilt 16' Z6D o., D.OOOJ ZIJ o., ZJ D.Z 11.0 o., II.I o.• o.oaoon 89,475 ID O.OD0014 ,,. 12:J OD ,., ,., ,. , ,.. 0.--,. O.CIOCIOIJ .. , 0.- IIIPTAC111.C. ~POXID! o.ooa 21,on ,~.,, 296,212 ·······,·:···············-----···························-·-······ ····································-··························-······· FISIIII :'"_f.flh tlttut; GU• Gr~■ter: SD • SedlMnt; SS • Surffcfal ~o~l; SV • ~face vater -·-.. -- - ------· -- - -----------TABLE // CONTAMINANTS OF CONCERN AND EXPOSURE CONCENTRATIONS FOR ALL ENVIRONMENTAL MEDIA FAIRWAY SIX, MCIVER AND ROUTE 211 AREAS - Mciver Area ... liill -------················ Fairvay _ Six _Are" ......................... . ---·········-·-----·······--------------------- CNfNICAL u,u •• , HAMIC ...... lll'fLl llll ~, .. ClaCllltll cmALI aJPNa UJID -· ll(IIQlaJ IICUL •u•n• IILVl:I fMUIIII YAUDUII ZIIIC 1,1,1-,a1c1tOI0(1.- 1,1-01C1IUIIOf,•111 1,Z·IICllOIO(I,._ a-• -IIU.flDl -TlllAClllOIIDl IT111'1. a■n• • 11t1AC11Lcaau•• ·-· tllCIIUIIGlt•• fftl•I (TOTAi.i 1,J,4•JIICIII.OIGll1Dlil Z,4·Dlll(IITlNIOI. z.,.,_..._._ lll(Z•llffl_...)PIIIIIUTI --·-.. , .... 4 4••DOI ,:,, .• , ....... ALPM·IIC nu-- DILtA·UC DIIUMIII r-•• II <•IA> ,_,. ,_, __ -----ca- .. ----------- '·'" IS,O,S 10,7'2 11,441 117 111,5ZZ Z4,269 HJ 1JZ IZ,09J z,.1 611 Z91 in 54.4 16.6 IJO llPUCllOI 66.Z •PTACIILCII IPCIIJDI 5. 1V Solid (uo/t1I ll"'ld luo/11 ID ----------- ,,.ooo a.100 250,000 16,000 z 5 z J .... ······· 71 150 ,.100 5 zz J ' flSN --.. -... --. ,. 100 J20 110,000 ,,.,oo zzo 670 J,ZOO 420 61,000 J,JOO ·····-····· II 11 16 16 5.1 zz 1.9 N ··········· o.oo, D.1145, 0.0455 D.7 D.OZZ, O.DZZ, 0.4 GIi IIJ 167 116 7.J z 20 ............ 0.05 0.05 0.05 D.07 1.1 ,., IJ O.IIZ5 All (Ull/11 ··-·····-·· D.-IZ •--D.OOOOJl o.-,z D.000006 D.DOOOOZS o.DOOOOZS 0.-1 .. 10,000 4,400 ··········· ,.101 1.,00 J4,24D IO, 151 14,718 ,.,1, Z,ffl TCIII.... l,J70 JO,Z65 Solid luo/kll ll..-ld (uo/11 ID 5,000 4,500 Z7 ,000 .........•• ZID ,,_, "·' • zz a • SIi 10 a.as o.a, D.05 0.065 0.14 O.OIJ 0.11 Cl.II o.oz, QI 54 a.a, a.a, Cl.DJ Cl.OZ Cl.DJ ·Cl.OZ 0.01 ···································································································· ················································· FISH• ffsh tfssl.M; C\I • Grouidwater; SD• S.c:tlment; SS • Surfici■l 10ft; SW· 'surface w■ter --1111 ·······················- Route 211 Area -~~llkl. -~t,,u,t~ -_. .. .. 7,100 1,200.000 4,I00,000 5,300 10.000 ZD 60 10 I ·····-····· ······----· 17,619 0.05 ... , D.OS »4,9M D.OS 641,nD D.OZ JS,• O.IK ,.u, Cl.OJ 12, 1,a Cl.OZ TABLE l Z.. ESTIMATED EXPOSURE FREQUENCIES FOR TARGET POPULATIONS UNDER CURRENT AND FUTURE LAND USE CONDITIONS TARGET PCIIUUTICll·SPECIFIC [xPOSURE fll:EQUlNCl CdaYI or events/yHr) .. -.. ---... ·-. -----------.. ---·. ---.. ----------------------·-· ---.... Oral Dennal Jrheletion cFAIOI CHEMICALS SITE> Current Lal"ld UH Condition: Onslu ruidenta -Adults ON.lu ruidenta -Children Future Land UH Condition: Onsite tHidenU Adults Onsfte residents Chlldr., Onsi u worker Adul ta <T'JIN SITE• Current Land UH Condition: Near tiU residents • Adult& Near alu r••fdenta • Children Site trnpHHtS AOJlta Site trespasHrs Children Future Land UH Con:lition: Crisiu residents AdJlta Onsit• r"Hidfflu Children RecrHtfonal users • AO.lits Rec:rHt IONl l users Children <FAIRWAY SIX SITE> Current l Future Land UH Conditions: Siu trespassers • Ad.Jlta Site trnpassera • Children Onsite workers A111lts <OklYH SITE> Current L..-d UH Condlttan: Siu trespasser. • Adults Site trnpeuers -Childr., Future Land UH Condition: Onslte ruidentl • Ad.llta Onslta ruldenta · Oii ldren <ROJTE 211 SITE► Current Land US• Condition; SS FISH SW GW 170 365 52 0 170 365 52 0 170 365 52 365 170 365 52 365 250 0 0 250 85 05 42 42 171) 171) 05 .. 42 42 250 17 17 171) 171) 365 365 0 0 365 365 0 0 0 0 365 0 0 l6S 365 52 52 0 0 52 52 52 52 0 0 26 0 0 52 52 0 0 0 0 365 365 0 0 0 0 0 0 0 365 365 Site trH~uer9 • Aa.llts 17 0 0 0 Site trHpuHr9 · Q\fldran 17 0 Fun.ire (and UH Condition; 0 0 Onaite rnident• -AO.llt• 170 365 52 l6S 0'\sit• rnidents • 0\fldren 170 365 52 365 <RECIEATIONAL USE► Current l Future Land US• Conditions: GolfiC'ISII at FSS Aa.llts 52 0 0 0 ss so 170 52 170 52 170 52 170 52 25D D 05 .. 42 42 171) 171l 05 85, 42 42 250 17 17 171l 171l 17 17 171) 171l 52 52 52 0 0 52 52 52 " 0 0 26 0 0 52 52 0 0 52 52 0 SW CW 52 0 52 0 52 365 52 365 0 0 52 52 0 -o 52 52 52 52 0 0 26 0 0 52 52 0 0 0 0 365 365 0 0 0 0 0 0 0 365 365 ss cw 365 0 365 0 365 365 365 365 250 0 " 05 42 42 365 365 " " 42 42 250 17 17 365 365 0 0 0 0 365 365 -0 0 0 0 0 0 0 365 365 0 0 17 0 0 0 17 0 52 365 365 365 52 365 365 365 0 O 52 0 SD • Sediment: SS -SUrflclal ao1l; SW Surface water; QI Gr-ou-dwater; fSS • hir-way Six Site TABLE 13 EXPOSURE TIME OR INGESTION RATE PER EVENT ------------------------------------------------------------------------ I I I DERMAL I I INHALATION I I ORAL I MEDIA I I (hours/day•) 11 (hours/day•) I I (grlll or ltr/day) I I -I I Adult Child I I Adult Child I I Adult Child I 1------------------11---------------11---------------11----------------1 I Surficial soil I I 2 I 4 I I 2 I 4 I I o. l I o. 2 I I 11 I 11 I 11 I I I Sediment I I 2 I 4 I I 2 I 4 I I o. l I o. 2 I I 11 I 11 I 11 I I !Surface Water I I 2.6 I 2.6 I I N/A I N/A I I 0.13 I 0.13 I I I I I I I I I I I I I Groundwater I I o. 2 I o. 2 I I o. 2 I o. 2 I I 2 I l . L I . 11 I 11 I 11 I I IF1sh II N/A IN/A 11 N/A IN/A 11 6.5 I 6,5 I ------------------------------------------------------------------------ *or event I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I The Mciver Area is in a sparsely populated rural area on land that is partly wood and partly cleared for agriculture. This area is residentially zoned. Despite its remote location, residential housing may be built at this site in the future. Thus, the target populations under current and future land use are: 0 0 residents nearby or site trespassers, adult and children (current) on-site adult and child residents (future) The Route 211 Area, located in a sparsely populated area, is generally surrounded by pine woods with scattered abandoned sand-mining pits. The mining may be reactivated in the future. However, the site is also located in a zoned residential area, which may be developed into a community in the futllre. Two active "cc>mmercial/industrial facilities are located between 1,000 -2,000 feet of the area. For a conservative risk assessment, the target populations under current and future land use are: 0 0 residents nearby or site trespasser, adults and children (current) on-site child and adult residents (future) The exposure pathways for all areas under current and future land use are similar or are identical. The risk to future residents at Mciver and Route 211 Areas of ingestion of contaminated fish and dermal contact with or ingestion of sediments and surface water was estimated by assuming that the future residents at both sites will use Pages Lake for recreational purposes. Exposure pathways are: Dermal contact with or ingestion of surface soil and exposed wastes Inhalation of suspended particulate generated from contaminated soils and exposed wastes Dermal contact with or ingestion of sediments and surface waste Inhalation during showering with, dermal contact with, and ingestion of contamiriated groundwater Ingestion of contaminated biota and food 6.3 summary of Toxicological criteria Available toxicologic criteria for contaminants of concern are summarized in Table 14 and are used in estimating risks to site contaminants. This table contains information on: Carcinogenicity Carcinogenic weight of evidence Tumor sites via oral and inhalation routes Carcinogenic slope factors (g*) via oral and inhalation routes Noncarcinogenicity chronic and subchronic reference doses (RfDs) via oral and inhalation routes Chronic and subchronic critical effects via oral and inhalation routes Slope (g*) or cancer potency factors (CPF) have been developed by EPA's Carcinogenic Assessment Group for estimating excess lifetime cancer risks associated with exposure to potentially carcinogenic chemicals. slope "' "' TABLE /II SUMMARY OF TOXICOLOGICAL CRITERIA ... n• .. ••••••• .. ••••••• .. •••••••••••••••••••••• .... •••••••••••••• .... ••••• .. •• .. •• .. ••• .. •••• .. •• .. •••••••••••••• .... ••• .. •• .. 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Cloulfltd u to ~-n tuclro,anltltr. --.. .. -- - -... --.. - - --- I I I I I I I I I I I I I I I I I I factors, which are expressed in units of (kg-day/mg), are multiplied by the estimated intake of a potential carcinogen, in mg/kg-day, to provide an upper~bound estimate of the excess lifetime cancer risk associated with exposure at that intake level. The term •upperbound" reflects the conservative estimate of the ,risks calculated from the CPF. Use of this approach makes underestimation of the actual cancer risk highly unlikely. cancer potency factors are derived from the results of human epidemiological studies or chronic animal bioassays to which animal-to-human extrapolation and uncertainty factors have been applied. Reference doses (RFDs) have been developed by EPA for indicating the potential for adverse health effects from exposure to chemicals exhibiting noncarcinogenic effects. RfDs, which are expressed in units of mg/kg-day, areestimates-of lifetime daily exposure levels tor humans, including - sensitive individuals. Estimated intakes of chemicals from environmental media (e.g., the amount of a chemical ingested from contaminated drinking water) can be compared to the RfD. RfDs are derived from human epidemiological studies or animal studies to which uncertainty factors have been applied (e.g., to account for the use of animal data to predict effects on humans). These uncertainty factors help ensure that the RfDs will not underestimate the potential for adverse noncarcinogenic effects to occur. 6.4 Risk characterization Using the input parameters described above, lifetime excess cancer rates (LECRs), which estimate the carcinogenic risks posed by the contaminants of concerns at the Aberdeen Pesticide Dumps Site were calculated. This unit of risk estimates the number of excess cancer cases caused by exposure to the site contaminants (e.g., an LECR of 1 x lo-' means that 1 excess case of cancer per 1,000,000 people could be expected). EPA's target risk range for aggregated LECR is 1 x lo-• to 1 x 10-•. In addition, the hazard index (HI), which is a quantitative measure of the possibility of adverse health effects from exposure to non-carcinogens, was calculated. A HI value of greater than 1.0 indicates that the potential exists for adverse health effects to occur from the assumed exposure pathways and durations, and that remedial action may be warranted for the site. Although LECRs and His were calculated for both current and future land use scenarios at the site, in the interest of conservatism the worst case scenarios are carried through as being representative of the risks posed by the Site. Future land use by on-site residents was the worst case scenario at all of the areas. A portion of the Fairway Six Area, because it is partially situated on a golf course, was also evaluated under an on-site adult worker as the worst case scenario. Considering that no long term remedial action takes place at the Site, the potential carcinogenic and noncarcinogenic risks to the population under current and future land use scenarios are discussed below. 6.4.1 Farm Chemicals Area Tables 15 and 16 summarize the quantitative estimates of risk under the current and future land use scenario for each target population at the Farm TABLE ✓~- CURRENT Land Use Risk Characterization Farm Chemicals Area ·carCinogenic !Uantitative Exposed Major Routes LECR Major A=•e•aee.es0s0m0e0n0ts_ _______ :cticsek,·_.sEasetcicmcae.ct,ec._ ____ "PcoeePaucl0actcic·o"-"n~ ___ ;Oefc..,Esx,popoescuereeL ________ VYJla;l0ueec_ ____ _,c,ocnetorcic·beua,tsosrcos LECR Noncarcinogenic Assessment HI Chronic HI Subchronic HI Subchronic Carcinogenic Assessment LECR LECR Noncarcinogenic Assessment HI Chronic HI Subchronic HI Sut;chronic HI Chronic HI Subchronic 7. 2 6. 7 109.3 Adult Resident Adult Resident Adult Resident Child Resident Ingestion of SS Dermal Contact ss Dermal Contact SD Inhalation SS Ingestion of ss Dermal Contact ss Ingestion SS Dermal con~act SS Ingestion SS Dermal Contact SS TABLE I fo 3 X 10-4 4 X 10-4 5 x 10-5 4 X 10-J HI Value 4.2 2.4 4.0 2.2 34.6 73.1 FUTURE Land Use Risk Characterizatic~ Farm Chemicals Area Quantitative Risk Estimate 48.9 38.1 236.8 19.6 12.1 Exposed Population Adult Resident Adult Worker Adult Resident Adult Resident Child Resident Adult Worker Adult Worker Major Routes Of Exposure Iflgestion ss Ingestion GW Dermal contact ss Inhalation ss Inhalation GW Ingestion GW Inhalation SS Ingestion GW Inhalation GW Ingestion SS Inhalation GW Ingestion GW Ingestion ss Ingestion SS Ingestion GW Dermal contact ss Inhalation GW Ingestion SS Ingestion GW Dermal Contacts~ Ingestion SS Ingestion GW :..,;:;cR Va:!_i..:e 4 X 4 X 1 X 10-4- lC-3 10-?. HI Value 14.4 27.2 4.2 26.9 4.4 4.D 34.6 9,7 73.1 117. 7 6.2 9.8 3.5 5.9 3.0 alpha-BHC, DDT toxaphene alpha-BHC arsenic arsenic, arsenic, arsenic, arsenic, arsenic, arsenic, Maj:J!" Cont.:::-.:._tc.-::.::irs COpfe=, OCT ccppe1:", DDT ccpper, copper, DDT DDT ODT DDT alp!:.c1-E!lC, DDT, beta-3r:r:i: garr~"T,.s-31-:C, Toxaphene alp:7~-:i;:::, beta-BHC, gc..-."T.-:.-::i::c DDT' ,-,.::_,;:-:a-BHC, tox.3.:--:E;';a:> arser..:._c chror.o:.i.:.r.: alpr'.3.-2!'.C arser,.:._:: ethyl b2~~ene, manga~e2.~ tot.al xj·!.enes arsenic, 4,4'-DDT total xylenes, manganese copper,. :z:i.nc arsenic, copper, 4,4'-[CT arsenic, copper, 4,4•-r.=:.r chr:::mit.:rn, copper, :z:i::c ar~enic, copper, 4,4•-~~! total xylenes arsenic, copper, 4,4'-DDT chromium, copper, etr.y~ benzene 4,4'-DDT arsenic, cop?E;r, 4,4'-DDT arsenic, copper, 4,4'-D~T I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Chemicals Area. The total LECR for current adult residents via all exposure pathways is 5 x 10·' with inhalation of arsenic as a significant contributor. While the chronic and subchronic Bis are fairly low for current adult residents, the subchronic BI for a current child resident is 109.3. The major contaminant contributors are arsenic, copper, and DDT. At the Farm Chemicals Area the total LECR for future adult on-site residents via all exposure pathways is 9 x 10·' with arsenic and alpha-BBC contributing about 45% and 22% of the total carcinogenic risk, respectively. However, arsenic was detected at a very elevated level in only one sample in the limited data population (4 detects in seven samples, 3 of which were trace concentrations). If this one sample is an isolated "'hot spot,• the LECR posed by arsenic may be overestimated. The chronic and subchronic BIS for adult residents were quite elevated (48.9 and 38.1, respectively), while the subchronic BI for a child resident was extremely elevated (236.8). Inhalation of groundwater contributes about one half of the risk for each target population, with ingestion of groundwater and surficial soil also significant exposure pathways. Dermal contact with surficial soil contributes about one third of the subchronic risk posed to future on-site child residents. The contaminants which are major contributors to the HI are xylene, 4,4'-DDT, and several inorganics (arsenic, copper, and manganese). 6.4.2 Twin Sites Area Tables 17 and 18 summarize the quantitative estimates of risk under the current and future land use scenario for each target population at the Twin Sites Area. The total LECR for current adult residents near the site and adult trespassers are 2 x 10·• and 5 x 10·•, respectively. Ingestion of surficial soil and dermal contact with sediment and surficial soil are major routes of exposure. Alpha-BBC, toxaphene and 4,4'-DDT are major contaminants. Except for current child residents near the site, chronic and subchronic Bis were less than 1.0. The BI subchronic for a current child resident nearby was 2.7 with ingestion of fish as the primary pathway. At the Twin Sites Area the total LECR for future adult on-site residents was 2 x 10·', _with ingestion of groundwater as the primary source of risk. Alpha-BHC, aldrin, and beta-BHC were the contaminants contributing most of the total carcinogenic risk. The chronic and subchronic His for future adult residents were elevated (38.2 and 37.2, respectively), while the subchronic HI for a future child resident was also very elevated (86.8). Ingestion of groundwater contributes about 90% of the risk for each target population, while inhalation of groundwater is also a significant exposure pathway. BI values for dermal contact with surficial soil and ingestion of fish from Pages Lake exceed 1.0 for subchronic risk to future on-site child residents. The contaminants which are major contributors to the HI are antimony, aldrin and xylene (and 4,4'-DDT and mercury for children); although the uncertainty factor associated with antimony is high because it was found at a trace level in only l of 4 groundwater samples. ss Carcinog•nic A111e■■inent LECH IZCR Noncarcinog■nic A•■e1111ment HI chronic HI Subchronic HI subchronic HI ~hronic HI subchroi:iic BI subchronic TABLE L1 CURREii'? Land Ooe Riek Characterization TWin sites Area Quantitatiff hp<>■od Na.jar Roat•• LEOI Ri■k l•tlll.ftt Populat!op Of !p:gpo■ure Yalp• ' • 10-4 Adult Re■ldent Inge■tlon 88 • • 10-S Near Bite Dermal contact .. 5 • 10-S Dermal contact SD 5 • 10-S ' • 10-S Adult Tr•■pa■■er :rng•■tion 88 ' • 10-S Dermal Contact •• ' • 10-S SI Yalu■ o., Adult Jte■id■nt Inga■tion Fi■h 0. J Near Sita Dermal contact SD 0,2 0,6 Adult Ra■ident Inge■tion Fi■ h o. J Near Site oennal contact SD 0.2 ,., Child Re■ident Ingestion l.' Near Site oennal Contact •• 0.' 0, 04 Adult Traapa■■er Ingetion 86 0.02 Dennal contact ., 0.02 0.03 Adult Treepa■■•r Ingeetion •• 0.013 Dermal Contact •• 0.014 0.06 Child Tre ■pa■■er Inge■tion 88 0, l Dermal contact •• 0, 5 T?.3::_:c: , l FUTURE Land use :,.:._3:.: c:-: :::.·;;.ct.er::.:·.:.: .:.en Twir. ~i:.as ;...::.·2,:-~ Najar contributor■ alpha-BBC alpha-BBC alpha-BBC, 4,4•-001' alph.o.-1:!!!C, t-:::::,phane alpba-BHC, toxapb■n• mercury 4,4'-DDT t11ercury 4,4'-DOT mercury 4,4'-DOT 4,4'-0DT 4,4'-DDT 4,4•-DOT 4,4'-DDT 4,4•-DOT 4,4'-DDT Care inogenic Q1.:ant i ':at i ve Ex?osed L"::C~. ~-,;·':::- ehesasee0se,es0rn0e0c0.t~ _______ 0R0iascSc•sEcsa,t"'"""'•ctcee__ ____ _.p,c0cecs·;l0aot"icccce, ____ sc""___c'c•···--., .. ,.,, _______ \c'•e·c!"•,,.:-c_ _____ ...c··"-~--,._,:_:.:; ~:.:: :· s LECR Adult ResiC.a:1::: LECR Recreational Noncarcinogenic Assessment HI Chronic 38.3• Adult Resident HI Subchronic 37.2* Adult Resident HI Subchronic 86.8* Child Resident HI Chronii:: 0.31 Recreational User (Adult) HI Subchronic 0.26 Recreatinnal User (Adult) HI Subchronic 1.46 Recreational User (Child) •Antimony detected in groundwater at a concentratiori of 0.43 moat to the HI for chronic.exposure at the Twin Sites Area. ~e:·:-.?.: Co:--.ta::::: ::::·.,=.:.:i::::..or. GW ::-.:_;c,.=:tic:1 SS )er::-,al C=ntac::: £5 te:-µ.al Ccr.:::ac-..: s:, Ingestion GW Ingestion c;; Ingestion GW Dermal Contact SD Dermal Contact SD Dermal Contact ss 1 X 1c·: 2 x l~ -., 4 X 10 1 X 10-• 5 X 10-:: HI Valt.:e 35.8 37.2 75.9 0.21 0.2 0.9 mg/1 and a detection frequency of 1/4. The uncertainty of the estimated HI is a~~.--..:: .. 2;::::, --···-•.. · .. = =~==:=:~~. ~~~=~~- a:pt-.2.-3?-:•: 4,4•-::r, a:~ta-S~C a:1:::i::1::r.::, a2.::fri.~ ar.ti.::.c.::,·, aldr :.r: ar.ti::ior.y, aldrin 4,4'-DDT 4,4'-DDT 4,4'-DDT _., It contributes the expected to be high. I I I I I I I I I ., .. I •-.~ I I I I I I I I I I· I I I I I I I I I I I I I I I I I I 6.4.3 Fairway Six Area Tables 19 and 20 sutnmarize the quantitative estimates of risk under the current and future land use scenarios for each target population at the Fairway Six Area. The total LECR for a current and future adult worker was 5 x 10-• with inhalation of surficial soil as a major source of risk. Arsenic, alpha-BHC, and 4,4'-DDT were the contaminants contributing most of the total carcinogenic risk. The subchronic and chronic His for all target population were insignificant (up to 0.67). ()i.,cd J,; (µ.)Jit"'I •• -t.J.,..; ~' -lo ,-,)e ;U.J ;,J,.J,. 6.4.4 Mciver Area Tables 21 and 22 summarize the quantitative estimates of risk under the. current a~d future"land use scenario for each target population at the Mciver Area. The total LECR for current adult trespassers at the Mciver Area is 4 x 10-•. Inhalation of and dermal contact with surficial are the major sources of risk with alpha-BBC as the primary contaminant contributor. The chronic and subchronic His were insignificant for all target populations. The total LECR for future adult residents was 4 x 10-•, with ingestion of and dermal contact with surficial soil driving the risk. Alpha-BBC contributed most of the carcinogenic risk, with 4,4'-DDT, beta-BBC, and toxaphene also contributing significantly. The chronic and subchronic His for adults were less than 1.0 (0.8 and 0.6, respectively), while the subchronic HI for a future child resident was slightly elevated (3.9). Dermal contact with surficial soil presents a significant portion of the site-specific risk, with ingestion of fish from Pages Lake also contributing to the overall risk (because all the Areas are reasonably close to Pages Lake, recreational use of this lake was included in the risk assessment for each Area). The contaminants which are major contributors to the HI are 4,4'-DDT (surficial soils) and mercury (fish in Pages Lake) • 6.4.5 Route 211 Area Tables 23 and 24 summarize the quantitative estimates of risk under the current and future land use scenario for each target population at the Route 211 Area. At the Route 211 Area the total LECR for future adult residents was 3 x 10-3 , with surficial soil being the major contributor. Alpha-BHC provided much of the total carcinogenic risk via the oral and dermal pathways. The chronic and subchronic His for adults were elev~ted (15.2 and 14.9, respectively), while the subchronic HI for children was extremely elevated (202.8). Ingestion of and dermal contact with surficial soil contribute at least 95% of the·risk for each target population. In each case, mercury contributed about 90% of this risk. However, the·uncerta·inty is high because it was detected at a very elevated level (4,800 mg/kg) in the only surficial soil sample that was analyzed for inorganics at the Route 211 Area. Additional sampling must be conducted to determine if this concentration of mercury is representative of surficial soils at the site, or if it is an isolated "hot spot• (in which case the risk may be overestimated). TABLE /? CURRENT Land Use Risk Characterization Fairway Six Area .I I Carcinogenic Quantitative Exposed .!ajar Major Routes LECR I rAeses,e.,.sos"mce"-!ln,tc_ ______ _,,Roiaseks__,Eese.staiem"a"tse.__ ____ ___,Psoapau,...1,a,toiaoen,_ ___ --".L-"-'""'-""-""--------_.:'"'"-"-"-------·ontr Of Exposure Value LECR LECR LECR Noncarcinogenic Assessment HI HI HI HI HI HI HI Chronic SuCchronic Subchror.ic Ch:::cnic Eubchronic Ch::o:.ic Su~,::hrcnic Ca:::-cicogenic Azsessment LECR HI Chronic Adult Trespasser Inhalation ss Dermal Contact ss 5 x l □-S Adult Worker Inhalation ss Ingestion ss Ingestion Fish Dermal Contact ss Adult Golfer Ingestion SS Dermal Contact ss Inhalation ss 0.02 Adult Trespasser Ingestion ss Dermal contact ss 0.014 Adult Trespasser Ingestion ss Dermal contact ss 0.26 Child Trespasser Dermal contact ss 0.68 Adult Worker Ingestion Fish 0.65 Adult Worker Ingestion Fish 0.02 Adult Golfer Ingestion ss Dermal contact ss 0.02 Adult Golfer Ingestion ss Dermal contact ss TABLE 2 D FUTURE Land Use Risk Characterization Fairway Six Area Qua:1titative Risk Estimate 1.1 X 10-3 2.4 X 10-3 .0001 .001 Exposed Population Adult Resident Child Resident Adult Resident Child Resident Major Routes Of Exposure Inhalation Oust Dermal C~ntact cw Ingestion SS Ingestion SS 5 1 3 5 7 6 1 l 6 X 10-6 X 10-6 X 1□-5 X 10-6 X 10-6 X 10-6 X 10-6 X 1□-6 X 10-6 HI Value 0.01 0.01 0.007 0.006 0,2 0.57 o. 56 0.01 0.01 0.01 0.01 LECR Value 9.9 X 10-4 1.~ X 10-3 HI Value .0001 .001 :;hromium ~,4'-DDT, alpha-BHC chromium 4,4'-DDT, alpha-BHC bis(2-ethylhexyl)-I· phthalate, alpha-BHC 4, 4 •-DDT, alpha-BHC I 4,4"-DDT, alpha-BHC 4,4'-DDT, alpha-BHC chromium vanadium, 4,4'-DDT vanadium, 4.4'-DDT vanadium, 4,4'-DDT vanadium, 4,4'-DDT 4,4'-DDT copper, mercury copper, mercury vanadium, 4,4'-DDT vanadium, 4,4'-DDT vanadi'..lm, 4,4'-DDT vanadium, 4,4'-DDT Major Contributors I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Carcinogenic Assessment LECR Nonca!:"cinogenic Assessment HI Chronic HI Subchronic H: St:bchronic TABLE Z. / CURRENT Land Use Risk Characterization Mciver Area Quantitative Risk E!"timate --0:01 0.01 a. 2; Exposed Population Adult Trespasser Adult Trespasser Adult Trespasser Child Trespasse::- TA3L3 Z Z. Major Routes Of Exposure In9'estion ss Dermal Contact ss Ingestion ss Dermal Contact ss Ingestion ss Dermal Contact ss Dermal Contact ss ~']':'Ur,.£ La:-!.C. Use Risk Characterization Melve~ .h.rea Ca!.·:; i :--.c:;i-12::ic Ass;:,_5sr",0"o"t~----=Ri_?:: i:.:otir:-.a::~ Expose,:: Pcpula:.:i.,:,r: ~!ajar P:outes o: Ex~osure LECR Value Nor.ca~·c .:nogenic Ai: S<?(l s::-.e1: t HI Chrcnic HI Sub::::ronic H! Subchronic 3.9 Adult Resident Adt!lt. Re'=i.de:i'.:: Child Rec: i.Cs:-;t: :r.gest.icn SS 2 X 10-4 ::er~al Contact SS 2 X 10-4 HI Val~e !ngestian Fish 0.28 Dernal Contact SD 0.22 Ingestion Fish 0.28 De:::-:nal Contact SD Ir.gestion Fish 1.2 De::~al Contact ss 1.8 LECR Value HI Value .005 .006 .005 .005 0.18 Major Contributors alpha-BBC alpha-BHC 4,4'-DDT 4.4'-DDT 4,4'-DDT 4,4'-DDT 4,4'-DDT Major Contribc:'.::ors alpha-BHC, toxaphene, 4,4'-DDT alpha-BHC, toxaphene, 4,4'-DDT mercury 4,4'-DDT mercury 4,4'-DDT mercury 4,4'-DDT Carcinogenic Assessment LECR r{oncarcinogenic As~E-ssment HI Chronic HI Subchronic !-!I Subchronic Quantitative TABLE 2'.3 CURRENT Land Use Risk Characterization Route 211 Area Exposed Major R~utes Risk Estimate Population Of Exposure 3 X 1□-4 Adult Trespasser Ingestion ss 1 Dennal Contact 5S 2 1.45• Adult Trespasser Ingestion S5 1.43• Adult Trespasser Ingestion S5 20.1• Child Trespasser Ingestion ss Dermal contact 55 LECR Value X 10-4 X 10-4 HI Value 1.13 1.12 9.7 10.4 Major Cor.tril "Jtors 4, 4 '-DC,T, alpha-BHC, ·:oxaphene 4,4'-DDT, alpha-BHC, tox,.1phene mercury mercury merc:.iry .mercury, 4,4'-DDT ~Mercury contributes more than 90'l of the total HI for chronic effects. However, mercury was detected at a cc~centration of 4,800 mg/kg in the only surficial soil sample was analyzed for inorganics at the Route 211 Area. Thus, the uncer~ainty for the c~ronic effects is expected to be significantly high. 1:,.~,.-:arc incgP.:1 :.c dss-~ ... _-__ _ n: S':Jbchronic H! S.ibch::-or.:.c \ TABLE 2.'( FUTURE Land Use Risk Characterization Route 211 Ar~a Q ·.. e Expo5ed Major Routes LECR Major R~: :~ ~;: :,,, ,0'_,-~~,0,,_ _____ PE.Qosos·,,,lca>:tc>L' oQ'ln ____ OQff__!E"xsoeoQ!!eau;rae'------,---V'ieaJlcu"e'-_____ CScEocneterci,· bs,;auataoerc-'s Adc1lt Res.:.dent l 5. 2.,. Adult Resident 14.9* Adult Resident 202.5 Child Resident Ingestion SS Dermal Contact SS Ingestion 55 Dermal Contact ss Ingestion S5 Dermal Contact 55 Ingestion ss Dermal Contact 55 1 X 2 X HI ~ 11.3 3.14 11.2 3.1 97.0 103.8 alpha-BHC, to!:aphene alpha-BHC, tcxaphene mercury mercury mercury mercury mercury mercury I I I .i I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 7.0 DESCRIPTION OF ALTERNATIVES The goal of remedial action at the Aberdeen Pesticide Dumps Site is to prevent, reduce or mitigate and·minimize potential or current risks to public health, welfare, and the environment posed by contaminants at the site. Technically applicable technologies that were judged to be potentially viable to meet the cleanup objectives for the Site were identified, screened, and assessed. These technologies were further evaluated and screened as to their effectiveness, implementability, and relative cost in comparison with other technologies that accomplish the same objective for the same media. Technologies surviving the initial screening were developed and screened further to eliminate those · technologies that have adverse impact on human health and the environment, are not applicabletothe contaminant and media at the Site, or are much more expensive to implement than other alternatives that provide essentially the same level of protection. ""d Two cost eatima~ s are provided in the descri tion of alternatives below. Two cost estimates were calculated in the Feasibility Study The first cost discussed represents a total cost estimate if the selected remedy were implemented at one central location. Present worth (base) cost estimates at each area are also provided. All cost discussed are the. base cost estimate. One of the reasons for presenting cost information in this format is to illustrate that a coordinated response action is more cost effective than independently responding to each area. seven remedial alternatives were developed for the contaminated soils which focus on reducing human exposure to contaminated soil as well as preventing further migration to other media. A comprehensive description of each alternative evaluated in detail is provided below; Alternative 1: No Action The No Action alternative serves as a baseline which other remedial technolOgies can be measured and is retained for a comparative analysis as required by the NCP. Under the No Action alternative the Site is left "as is" and no actions are taken to monitor, control or clean-up the contamination. This alternative does not reduce the potential for contaminant migration from the site nor does it minimize or eliminate the potential exposure to the on-site contaminants or those that have migrated off-site. The No Action alternative does not meet the remedial objectives of the FS. Alternative 2: Environmental Monitoring The Environmental Monitoring alternative is similar to the No Action alternative, except that certain actions are taken to better define the extent of contamination and limit public contact with it. Although this alternative is not required, it is retained as a modified baseline to aid in the comparison with other alternatives. 6 I The Environmental Monitoring alternative calls for the installation of additional monitoring wells to better define the extent of the contamination in the groundwate.r by identifying the boundaries of the contaminated plumes and utilizing institutional controls (fencing and signs) to reduce public contact with contaminated media.· on-site areas of soil contamination will be fenced and posted, while off-site areas where contaminated groundwater discharges will only be posted. No effort will be made to mitigate the migration of contaminants; thus continued environmental damage will occur via surface water runoff (sediment transport) and groundwater migration. Further bioaccumulation of site contaminants will continue. Environmental monitoring will consist of collecting soil and groundwater samples annually, conducting laboratory analysis of these samples, consolidating the laboratory data, inspecting fences and posted warning signs, and preparing an annual summary report which includes a comparison with previously collected data and identification of new areas of concern due to contaminant migration. TWelve 4-inch stainless steel monitoring wells, averaging 40 feet in depth, will have to be installed to better define the extent of groundwater contamination. The number of monitoring wells be to be installed at each area are listed below. Monitoring well locations are identified in section 4 of the FS. ~ Farm Chemicals TWin Sites Fairway Six Mciver Route 211 Number of wells 5 3 2 1 1 Because this alternative would result in contaminants remaining on-site, CERCLA requires that the site be reviewed every five years. If justified by the review, remedial actions would be implemented at that time to remove or treat the wastes. This alternative would only take a few weeks to implement at a capital base cost of $650,000. Capital cost includes construction of the monitoring wells and fences, sampling and analysis, report preparation, mobilization and demobilization. operation and maintenance cost are estimated at $72,000. Estimated base present worth is $1,777,000. Present worth cost summary by Area is: ~ Farm Chemicals TWin sites Fairway Six Mciver Route 211 TOTAL Present Worth Base $515,000 $584,000 $562,000 $409,000 $412,000 $2,482,000 I I I I I i I I I I I I I I I I • I I I I I I I I I I I I I I I Alternative 3: Kultimedia cap (Alternative 3 -Option Bin FS) Multimedia capping is a method of source control containment remedy to prevent the continued contamination of groundwater and direct exposure to humans. Under this alternative, an impermeable/low permeable cap would be constructed over the contaminated wastes/soils, surface runoff would be diverted by regrading, and site access would be restricted by fencing contaminated areas. Environmental monitoring would confirm whether contaminants are migrating off-site, while periodic inspection and repairs of the cap will be required. The multimedia cap will consist of, from bottom to top, the following layers: compacted native soil used to level the area, compacted clay, a synthetic membrane, granular drainage, a filter fabric, compacted native soil, and a topsoil layer to support vegetation. Implementation of this alternative does not provide compliance with current ARARs since no remedial measures are undertaken and current conditions exceed Federal and State ARARs. The approximate area, in acres, covered by the cap at each Area is: Area Farm Chemicals TWin Sites Fairway Six Mciver Route 211 Acres 5 4 4 l l On each of the Areas, surface water will be diverted away from the cap to prevent its erosion and possible exposure of the contaminated soils. The entire area will be fenced and posted to further prevent human contact with highly contaminated soils, and to reduce potential vandalism. The capped areas will be hydro-seeded to help prevent erosion.· In areas where the groundwater is close to or within the contaminated material either the water table would have to be lowered via extraction wells or subsurface_ drains or the contaminated material has to ~e excavated and moved to a higher elevation prior to capping. Lowering the water table would require treatment and disposal of contaminated water. However, moving or consolidating contaminated material within each area of contamination would not constitute disposal/placement under RCRA. The proposed cap at the Farm Chemicals Area encompasses almost the entire area. The on-site buildings probably would have to be demolished prior to construction of the cap. swab samples from the building material must be collected and tested for RCRA hazardous characteristics. If it is found to be hazardous the material must be decontaminated prior to disposal.· This can be accomplished by using a high pressure steam cleaner, solvents, or scabbling (i.e., stripping the top layer of concrete). It is assumed that the building debris will be disposed of in the local municipal landfill. ~ 63 Construction of the cap at the five areas is estimated to take less than one year at an estimated capital cost of $6,537,000. ·Long-term operation and maintenance is estimated at $185,000. Present worth cost is $9,848,000. should capping of the Areas be financed and implemented by different paying parties, the estimated present worth cost by Area is: Area Farm chemicals Twin sites Fairway six Present Worth Base $3,844,000 $2,715,000 $2,674,000 $1,176,000 Mc Iver Route 211 $1. 154,000 TOTAL $11,563,000 Alternative 4: on-Site Incineration (Alternative 5 in FS) Incineration is a thermal treatment technology which utilizes elevated temperatures to destroy or detoxify hazardous waste. Under this alternative, contaminated soil and debris are incinerated on-site. Residual ash from the incinerator would be buried on-site in a non-RCRA landfill and covered with clean fill. use of a mobile rotary kiln incinerator was assumed for cost estimation, due to their relative abundance and availability. However, other types Of incinerators that provide equal or better performance should be considered when bidding the project. Incineration is the Best Demonstrated Available Technology (BDAT) for halogenated organic compounds, which includes most of the pesticides found at the site. This alternative consists of the following remedial activities: 0 0 0 0 0 0 0 mobilizing the incinerator in·a centralized area; excavating pesticide contaminated material; transporting the material to the centralized area; homogenizing and sizing the material for incineration; incinerating the waste; on-site treatment of process wastewater or scrubber blowdown sludge by reinjection into the incinerator; and on-site non-RCRA disposin9 of incinerator ash. Incineration destroys or detoxifies organic contaminants and generally converts them to co2 H20 vapor, so2 and NOx off-gases and ash. since many of the contaminants are chlorinated, hydrochloric acid (HCl) will be generated as an off-gas •and must be removed with an acid gas scrubber before discharge to the atmosphere. Prior to incineration, the material will be passed through a shredder and power-screens for sizing. The properly sized contaminated material will then be fed into the incineration unit. In order to maintain a readily. available feed for the incinerator a "waste pile" must be maintained on-site. This waste pile will constitute placement of hazardous waste upder RCRA. Therefore, it will have to comply with RCRA regulations as specified in CFR 265·,Subpart L, such as a bottom liner, run-off management system ( leachate collection system), wind dispersion controls·, and closure. However,-. because this is considered an "on-site" CERCLA response_ action, no permits are necessai:-y. I I I I I I I I I' I -.. -:... I I I I ' i I I I I I I I I I I I I I I I I I I I I I I Operation of the incineration unit will be in compliance with RCRA regulations (particularly Subpart o, 40 CFR 264), including performance standards. The incinerator and air pollution control unit will be operated so that: 0 0 0 0 An operating temperature in the kiln of l,800°F is maintained at all times to ensure that any volatile and semi-volatile organic constituents in the waste stream are driven out of the ash and that the fixed carbon remaining in the ash is minimized; An operating temperature in the afterburner of 2,000°F is maintained at all times to oxidize and destroy all remaining ' organic substances prior ~o exiting the afterburner and entering the pollution control system; The incinerator will be capable of achieving a destruction and removal efficiency (DRE) of 99.99% for all designated principal organic hazardous constituents; and The air pollution control system will achieve performance standards of (l) hydrogen chloride of less than 4 pounds/hour and (2) particulate matter of less than 0.08 grains per day ft3 in the exhaust gas corrected oxygen content. One localized area of the Farm Chemicals site (area of sss-119) was contaminated with extremely elevated levels of pesticides and inorganics (metals such as lead and arsenic) and is believed to be associated with a spill. This and any other area determined to be contaminated with high concentrations of inorganics should be isolated from the rest of the material and treated separately to isolate the ash. Ash from the incineration of this material will likely contain high levels of inorganics and may not pass RCRA characteristic testing, and need additional treatment (stabilization/solidification) and testing prior to disposal. The amount of highly contaminated material in the area of sample SSS-119 is unknown; but is believed to be very small. The bulk of the contaminated soil and debris to be treated is low in inorganics, thus the ash should pass RCRA characteristic testing and be non-hazardous. RCRA characteristic testing of ash from the 1986 test burn at the Fairway six Area was non-hazardous. For convenience and practicality, the on-site incineration unit will be mobilized at a centralized location. This procedure will save time and money by avoiding the necessity of setting-up and breaking-down the unit at.each Area. The NCP (1990) states that CERCLA has broad discretion to treat noncontiguous facilities as one site for the purpose of taking response action. However, wastes transported between sites must be manifested as required by RCRA. The areas that require excavation based on the 106 health-based target cleanup levels are shown in Figures 17 through 21 in section 9.0 of this document. During the excavation at Farm Chemicals Area, some of the buildings may have to be demolished because their foundations will be undermined. These buildings will be disposed of in a manner similar to the one described in Alternative 3-Multimedia cap. Following tre~tment,_the volume of residual ash is dependant on the composition of the feed.material -the greater the percentage of incombustible inorganics (i.e., most soil forming minerals), the greater the residual ash. Volume reduction of material in buried trenches is expected to be greater than that for the contaminated soils, the volume of which should o_nly be reduced by a maximum of 10-15·%. The major cost associated with this alternative are for the excavation and incineration of the·contaminated material. On-site incineration cost estimates range from $200 -$350 per ton with $250 per ton used for .estimating purposes. Excavation cost estimates ranged from $10-$18 per cubic yard, with $12 per cubic yard being used for estimating purposes. Under this alternative various on and off-site disposal options considered depending on the nature of the treatment residuals. eStimates for incineration and disposal are discussed below. Option 1 -on-site Non RCRA Ash Disposal (Alternative 5. -option A-1 in FS) were Cost Under option l, after confirming through sampling and analysis that the incinerator ash is non-hazardous, the ash would be disposed on-site in the area where the soil originated. The ash would be covered with clean fill and revegetated. Capital and present worth costs are estimated at $48,638,000 and $50,439,000, respectively. Present worth cost estimates for implementing this remedy at each Area are: ~ Farm chemicals Twin sites Fairway six Mciver Route 211 TOTAL Present Worth Base $24,384,000 $13,439,000 $ 8,792,000 $ 3,515,000 $ 3,084,000. $53,214,000 Option 2 -on-site Non RCRA Ash Disposal After solidification/Stabilization (Alternative 5 -option A-2 in FS) Under Option 2, if the ash remaining after treatment is hazardous, or the treatment goals are not achieved, additional treatment through stabilization/solidification would be required prior to disposing the ash on-site. The ash will be mixed with the stabilizing/Solidifying agents and allowed to cure. The solidified mass must undergo additional RCRA characteristic testing and be determined non-hazardous level. As mentioned above, disposal of the material will be transported back to each Area and disposed back into the excavated area. However, the volume will increase approximately 20% due 3 to the addition of the solidification agents (assuming 1 yd3 equ_als 1 ton). ; .. ·::,, , .. ' ;., I I I I I I I I I I I I I I I I ; I I -I I I I I I I I I I I I I I I The addition of the stabilization/solidification costs is $2,977,000. These costs ranged from $30 -$50 per cubic yard, with $30 per cubic yard used for cost estimation purposes. Estimated capital and present worth cost are $53,269,000 and $55,070,000, respectively. Present worth cost estimates for implementing this remedy at each Area are: ~ Farm Chemicals TWin Sites Fairway Six Mciver Route 211 TOTAL Present worth Base $27,285,000 $15,033,000 $ 9,777,000 $ 3,799,000 $ 3,353,000 $59,247,000 Option 3 -Off-site Municipal Landfill Ash Disposal (Alternative _5 -Option B in FS) Under Option 3 the non-hazardous ash is disposed of in an off-site municipal landfill. The ash will be loaded into trucks and transported to the local municipal landfill, a distance of less than 5 miles. If the ash is tested hazardous, secondary treatment, such as stabilization/ solidification, can be performed with the solidified mass being retested prior to disposal. The excavated areas will be backfilled with clean fill material and revegetated. It is estimated to cost $10 per cubic yard or ton to dispose-of the treated soil in the local municipal landfill. A cost estimate of $15 was used for the disposal cost estimate, which also includes transportation to the landfill. Estimated capital and present worth for this option is $51,026,000, and $52,842,000, respectively. Present worth cost estimates for implementing this remedy at each Area are: ~ Farm Chemicals TWin Sites Fairway Six Mciver Route 211 TOTAL Present Worth Base $24,958,000 $13,905,000 $ 9,081,000 $ 3,558,000 $ 3,165,000 $54,667,000 Option 4 -Off-site RCRA Landfill Ash Disposal (Alternative 5 -Option Din FS) Under Option 4 the ash would be disposed of in an off-site RCRA subtitle c facility. It is assumed that the hazardous compone~ts are inorganic. The organics should be destroyed in the incineration process. Ash from the incinerator would be loaded into trucks and hauled to the RCRA facility for treatment (stabilization/solidification) and ultimate 61 disposal. The Laidlaw Facility in south Carolina, located approximately 150 miles south of Aberdeen, was used for RCRA disposal cost estimating. Excavated trenches would be backfilled with clean fill material and revegetated. Disposal cost estimates from the Laidlaw Facility with stabilization/ solidification were $250 per ton with an additional $30 per ton charge for out of state wastes (a total of $280.00 per ton, excluding state tax). Estimated capital and present worth cost are $91,733,000 and $93,534,000 respectively. Total operation and maintenance cost are $115,000. Present worth cost for implementing this alternative/option at individual areas are presented below. ~ Farm Chemicals Twin Sites Fairway Six Mciver Route 211 TOTAL Present Worth Base $45,876,000 $25,400,000 $16,186,000 $ 5,944,000 $ 5,098,000 $98,504,000 Alternative 5: Off-site Incineration (Alternative 6 in FS) Under this alternative the contaminated material would be excavated and transported to an off-site incinerator for thermal treatment and disposal. Contaminated soil and debris will be excavated and transported to an off-site incinerator where organic contaminants will be thermally destroyed, with the ash disposed of in a RCRA subtitle c landfill. The contaminated material would be excavated then transported to an off-site incineration facility and treated prior to disposal. Due to the type and volume of material to be treated, only three facilities were considered to be capable of handling the material. All of these facilities operate rotary kiln incinerators. operator Chemical waste management Chemical Waste Management Rollins Location Sauget, Illinois Port Arthur, Texas Deer Park, Texas Approx. Miles from site 800 1000 1300 Selection of the actual off-site incineration facility that would accept the excavated wastes from the site depends on the availability of incinerator capacity. Due to the Land Disposal Restriction regulations incineration capacity is limited, which may hinder the implementation of this alternative. This shortage in capacity may require the excavation and transport of material to a facility in stages as capacity becomes available. This staging could prolong the length of time for the remediation of the contaminated soils from the site from less than a year to several years. The incineration facility is responsible for the proper treatment of the contaminated material in accordance with RCRA incinerator regulations and final disposal of the residual ash. The Areas requiring excavation are shown in Figures 17 through 21 in Section 9.0 of this document. I I I I I I I I I ,:: ,. ::r. I I I I I I I ., ~~- I I I I I I I I I I I I I I I I I I I I Alternative 5, the most costly of the alternatives, has a total present worth of $207,327,000. The major costs are for the incineration and transportation of the contaminated material. Although cost is over 1 order of magnitude greater than comparable alternatives, this alternative was retained to allow for off-site treatment. The incineration cost estimates ranged from 45 to 90 cents per pound ($900 to $1800 per ton), and were a factor of the BTU content of the material. For cost estimation, 60 cents per pound ($1200 per ton) was assumed. Transportation costs of $4.00 per loaded mile, over a distance of 900 miles were used for the cost estimation. Capital costs are estimated at $205,549,000 with annual operation and main~en_ance of $114,000. Present worth cost estimates for implementing this remedy at each Area are: Area Farm Chemical TWin sites Fairway six Mciver Route 211 TOTAL Present Worth Base $99,088,000 $54,490,000 $33,991,000 $24,880,000 $ 9,665,000 $222,114,000 Alternative 6: In-situ vitification (Alternative 7 in FS) Under this alternative, the contaminated soil and debris will be vitrified in place. The resulting mass of glassy material will be tested for hazardous characteristics and left in place if it is found non-hazardous. In-situ vitrification (ISV) is an innovative thermal treatment technology which virtually eliminates handling of the contaminated material. This is accomplished by inserting electrodes into the soil and flowing an intense electrical current between them which heats the adjacent soil to 2,900 - 3,600'F, thus causing it to melt. Organic pollutants are thermally decomposed (pyrolyzed), while non-volatile inorganics are dissolved in place and incorporated into the melt. Volatile organic and inorganic off-gases are collected by a negative pressure hood installed above the treatment area and processing in the off-gas treatment system. The resulting end product is an inert, extremely stable glass-like solid mass with a smaller volume (typically 20 -40%) than the original soil/waste. When the melt has encompassed the entire treatment volume, it is left to cool (several months) and is then covered with clean fill material and revegetated. The power source may either be a local utility or, in a remote area, a diesel gen~rator. The estimated area of contaminated soil and debris requiring vitrification is identical to the areas requiring excavation that was shown in Figures 17 through 21 in Section 9.0 of this document. The estimated volume of the site material to be treated including a 5% overmelt is: 6 '1 Area Farm chemicals Twin sites Fairway six Mciver* Route 211 Total volume { ydl .1. 50,865 27,947 17,276 6,237 4 705 107,030 *Volume includes the 3,200 yd3 of contaminated material stockpiled at the Mciver Area. Areas estimated to require remediation to a depth of only five feet may need to be excavated and consolidated in a deeper configuration to facilitate the ISV process. Similarly, the stockpiled material at the Mciver Area must be transferred to a trench in order to vitrify it. In order to monitor the effectiveness of this technology, soil samples are collected ·adjacent to the outer edge of the melt to be certain that it has incorporated the desired area/volume. When the melt has cooled and hardened, samples of the glass are obtained and tested for RCRA toxic characteristics. All data indicate that the residual glass monolith will be very.resistant to leaching, and will require no future monitoring or remediation. The maximum area which this technology can treat with one setting of the electrodes .is approximately 30 x 30 ft; the maximum depth is.also 30 'feet. Only 800 to 1,000 tons of material can be treated per setting; which, for the most soil matrix applications, limits the volume per treatment to slightly less than the maximum dimensions. The many site- and application-specific variables of this technology necessitate treatability and pilot scale studies before full-scale operation: Cost for the ISV process includes treatability and pilot-scale tests, mobilization and demobilization of the vitrification unit, and the estimated cost per ton for the vitrification operations.· costs which are not included, because a site visit by the contractor has not occurred, are site characterization, site preparation/construction operations, permitting/regulatory compliance, dewatering operations (may be required in the northern areas of the Twin sites Area), site res·toration, delisting of the remaining vitrified masses (if necessary), and secondary waste disposal. Estimated capital and present worth cost are $50,257,000, and $52,101,000, respectively. Annual operation and maintenance are estimated at $117,000. Implementation time is estimated to be 3 years. Present worth costs for implementing this alternative at each Area are: ~ Farm Chemicals Twin sites Fairway six Mciver Route 211 TOTAL Present Worth Base $24,648,000 $13,761,000 $ 8,864,000 $ 3,584,000 $ 2,786,000 $53,643,000 70. I I I I I I I I I .. I .:: .:.; I I I I 'I I I I I I I I -I I I I I I I I I I I I I I I Al.ternative 7: Thermal Desorption/Separation (Alternative Bin FS) Under this alternative, contaminated soil and debri~ are excavated and treated utilizing low temperature thermal technology. Treated soil will be tested for RCRA characteristics and returned to the excavated area if found to be non-hazardous. This alternative consists of excavating contaminated soil and debris and treating it with thermal desorption/ separation. The volume of contaminated soil and debris and the excavation procedures are identical to those described in section 9.0 of this document (Figures 17 through 21). Treatment will consist of volatilizing the organic contaminants at a temperature generally less than .l'000°F with the off-gases being_treated to prevent the release of contaminants. off-gas treatment varies depending on"the vendor,-butusually consists of either, (1) thermal oxidation in a secondary thermal oxidation chamber similar to incinerators; (2) condensing and concentrating the organics into a significantly smaller mass for further treatment (incineration); or (3) passing the off-gases through activated carbon to adsorb in the contaminants and then regenerating the carbon. For cost estimation purposes, it was assumed that a smaller concentrated organic mass would require incineration in an off-site RCRA facility. The volume or weight of the condensed mass depends on the amount of organics present in the soil at each area. To approximate a volume or weight for post treatment, the average total pesticide concentration (mg/kg) at each area was converted to percent organics and was assumed to be representative of all the material excavated from that area. The percent organics was multiplied by the volume/weight of material to be excavated (assuming 1 yd3 of material weighs 1 ton) to obtain, the resulting weight of condensate for additional treatment. The volume of material to be treated at each area and the resulting condensate for post treatment is estimated to be, Excavated Material Percent condensate ~ {tons} Organics* (tons} Farm Chemicals 48,443 0.056 27 .13 Twin Sites 26,616 0.005 1.33 Fairway Six 16,453 0.0007 0.1 Mciver 5,940 0.006 0.35 Route 211 4,481 0.057 ~ TOTAL 101,933 31.46 * Total pesticides only The off-gases will pass through an air pollution control system consisting of cyclonic separators and baghouse and scrubbers to remove particulates and BCL either prior to or after treatment of the off-gases, depending on the treatment system. scrubber blowdown water can either be reprocessed through the system or treated with activated carbon and then used to quench the treated (hot) soil. Typically, air emitted to the atmosphere is passed thorough a bed of activated carbon to insure that it is free of contaminants. 71 Treated soil will be analyzed for RCRA hazardous characteristics and disposed back into the excavated area if found non-hazardous. If hazardous due to inorganics, the treated soil must undergo additional treatment, such as stabilization/solidification, and retesting prior to disposal. If hazardous due to organics, the soil will be reprocessed to remove the organics in it to below toxic levels. Any stockpile of contaminated material must meet RCRA storage requirements to prevent further contamination of the environment. ·As with Alternative 4 (On-site Incineration), this alternative can be implemented on each individual area at a central location. The thermal desorption system would be located in a centralized area. suspected areas with high inorganic contamination (localized spills) should be isolated and treated separately to minimize _the potential for secondary treatment of the soil. The major costs associated with this alternative are for the excavation of contaminated soil and debris, treatment of the soil and returning the soil to the excavated areas. The cost ranges from approximately $50 to $225 per ton, and is dependent on the type of system/vendor. Additionally, some price estimates included the post treatment costs, s.uch as regeneration of carbon. The cost variations should-be taken into consideration if this alternative is chosen for remediation. For cost estimating purposes, a base cost of $125 per ton was assumed for treatment of the soil, with a +40% and -30% cost variation for the high and low cost estimates, respectively. Additionally, the cost for transporting, treating, and disposing of a residual organic contaminated ma·ss in a RCRA facility was also included in this estimate. Estimated capital and present worth cost are $27,314,000 and $29,115,000, respectively. Should this alternative be financed and implemented by different parties at each indiyidual area, the estimated present worth • cost is as follows: Area Farm chemicals TWi~ Sites Fairway Six Mciver Route 211 TOTAL Present Worth Base $14,010,000 $ 7,867,000 $ 5,350,000 $ 2,316,000 $ 2,138,000 $31,681,000 The estimated time required to complete the soil/remediation with one mobile thermal desorption unit is approximately 2.3 years, assuming a process rate of 5 tons per hour. 8. 0 SUMMARY OF _.COMPARATIVE ,'ANALYSIS OF ALTERNATIVES The remedial alternatives developed during the Aberdeen Pesticide Dumps site FS were',evaluated by.· the u.s. EPA and the NCDEHNR using nine!', criteria.. The>advantages and disadvantages of each alternative were then compared to identify the·alternative providing the best balance among these nine.criteria·defined below. 72.. I I I I I I I I I' ~ I L:.: I I I I I I •• . ., : .. ~ ,,,. I I I I • I I I I I I I I I I I I I I I overall Protection of Buman Health and the Environment addresses whether a remedy provides adequate protection and describes how risks posed through each pathway are eliminated, reduced, or controlled through treatment, engineering controls, or institutional controls. Compliance with Applicable or Relevant and Appropriate Requirements · A~ts (ARARB) addresses whether a remedy will meet Federal and state~or justifies a waiver . Long-term Effectiveness and Permanence refers to expected residual risk and the ability of a remedy to maintain reliable protection of human health and the environment over time, once clean-up goals have been met. Reduction of Toxicity, Kobility or Volume Through Treatment is the anticipated performance of the treatment technologies a remedy.may employ. Short-term Effectiveness involves the period of time needed to achieve protection and any adverse impacts on human health and the environment= that may be posed during the construction and implementation period, until cleanup objectives are achieved. Dnplementability is the technical and administrative feasibility of a remedy, including the availability of materials and services needed to implement a particular option. Cost includes estimated capital and operation and maintenance costs, as well as present-worth costs. State Acceptance should be used to indicate the support agencies comments. cornrnnnity Acceptance summarizes the public's general response to the alternatives described in the Proposed Plan and RI/FS Report. The specific responses to public comments are addressed in the Responsiveness Summary. A matrix summarizing the comparative analysis of criteria ~y criteria basis is presented in Table discussion expounds on the information provided in alternatives on a The following Table overall Protection of Buman Health and the Environment: Alternatives 4 through 7 offer the most protection to human health and the environment by thermally destroying the organic contaminants by eliminating, reducing, or controlling risk through treatment. The No Action And Environmental Monitoring alternatives do not protect human health and the environment and the long-term protection of a multimedia cap is questionable. The preferred alternative would treat the organic contaminants in the soils to eliminate unacceptable risks from direct contact. Treatment of contaminated soils would subsequently eliminate the migration of contaminants into the underlying groundwater ~quifer. Compliance with ARARs: All of the alternatives except No Action and Environmental Monitoring will comply with the existing ARARs. Alternative 6 ISV, treats the contaminated soil and debris in place, thus RCRA Land Disposal Restrictions (LDRS) should not be applicable. In Alternatives 4 and 5, excavating and stockpiling of contaminated soil and debris are necessary. This will constitute placement of contaminated material, thus LDRs will be applicable. 73 summary of the comparative Analysis of the Alternatives ••••••••••••••••••••■■■•••••••••••••••••••••u■■••••*••••••••••••••■■■■ • ••••••••••• .. ••nn·■u■■ ■■■■■ •••••••••••••• .. •••••• .. •••••••••••••••••••■■■•■■■■■■ • .. ••••••••••••••• .. ••••••••••••••• .. •••••••••••••••••••••••••••••• .... ••- PrOtKt lo,, of N......., C~tlan::• l0n9-1 .. r,,, {ffKtiv.--l~ticr, of To•lclty, Ulort•Ul'9 $Ute c-...hy COST UlEIHiTIVt: N .. lth I E,.,,,\ror......t with AU.h rwn I Pe"""~' J1ot>ili1y or Yot._ fff«tlnnen l~t-,,ubillty Acc~un::e Acc:et,tan::e C,ipltal O IN ,rH.,..t llwt't. ···················· ······················ ················· ················-··· .... ·-· ............................... -···· ··-·· .............. ····· ....... .... ............. ············ -···· ....... --··········· .... z,,.aaa ,_ Wo ,t,c:tlon .,, No rtmrdi1t •ction None I, t1kffl to rf'd..c• the risk posf!'d by the ,i te ···················· ···--········-·-······ ················· ··············--···· ·······-·········· fnvlr-Ul l'lonhortrot O"•r• incr1tHtd \/Ill not c~ly s-H Alt. 1 p,...tilic •w•rtnru by wi1h .U.U:1. idirr1tifil'l9 currffll •rd Curr.-nt l•ve\1 futur• ,rn• of of cont.-ination c:on11r11lnation. •o ucttd NC & ftd. \II t l not lrcr11n or drcr1t1111 th1t rhk poud by th• ,t t•. '" ..... .... "·"'° ,_ 711,000 ""' 100,000 199,000 .... 255,000 ...................................... -· ..... ·········. .. .. ......... ...... .. ·········· ............ ··••········· ·-1.m,aor: Cont .. inatld ar11s f11lly i-.,1-•n.-d Ult fff"Ctd or po'tt.d. \Ii I I Should taka • hw rid.Jc• upo<Jur• ..,.,ths to cOl!t)llfla. thrQO..J9h po.bl le .... 650,000 ,_ 5n,ooo ..... Ml,000 .... n,ooo ,_ n.ooo ..... Ol,000 ,_ 1,691,000 .. .. z,nz.~ r....-di•l 1c:1lon llkffl. AO.II. ············ ...................................... ·-....................... -··· ..................................................................... -· ............... ········· .. . ....................... ··········-·· aw1r-..<J. A •inor incruH in risk can bf' UP"(tf!'d. Enlly 1-.,1_.-.tlfd, Capptl'l9 is , .... 6,517,000 ,_ .... 185,000 ,_ laH 9,8411,000 ,_ Nut ti.di• , .. fffOfelln In r~ll'l9 \/ill c~ly 1h1t ri,k pond by th• with .OA.lls •it1t Long· tffffl 1tfft'Ctivff>t'1s h quntion■ble ard 1houtd oot bit c~id..r.-d n , per1M~t 1olut ion. Dt>1t't not rrd.c1t 1h11 to•icity, robillty or volUl'le.of tht' contlllfllin.ants. ···················· ······················ ················· ···················· 0n-,t11 lnclrwntton, "-On-1\u .... h Oi1pout, Oro1nic: c:ont-in.anl1 1r1t d,u1royf!'d, uh a.st no! bit ICU. huardooa. ,rovidn ~:~~l !:: ~:/lnen 1t<Wit0t'fllent. lncirwr■tioro procn, wt 11 C:CffPlY will All AR.Altl Oroanlc: conr .. inanh hd.Jul 1o~icily ,rd are dr<J!royf!'d, nh vol....,.. thrQO..J9h i't oot 11:Clt.l tr1t1t.....,1. haurdous. (>uv•tion will incruse fugi1iv1t O.,st ..-d oroenie v1por,. En,,i1lons fr011 th1t incinerator 1hould bit frH of ccmrori conHruc:tlon prac:tlc:1t. Should t1k1t Ins than • yur to eOl!t)lflll. lllobite lnc!neretor, lfl avaltabl• fr011 • l'U!Oltr of vffldors. (nt■-tfd C:l:lfPl•t tDl"I In ■qvox. 2.n ~ars, with -trcl,wrator. 5,861,000 ..... 8,588,000 1!3,000 ""' 210,000 9,on,aoo .. ... 12,J41i1,000 ················· ···········•····· ············ ············ ············· lne 48,653,000 ,_ 41,799,000 ""' 66,083,000 ..... 115,000 ,_ 115,000 ""' 1Jl,000 .... 50,Ut,OOCI ,_ 68, 16',IOO .... 45,5tr,• ...... ·············· ·········. ········· .................................................... ········· ............................ ·-·· ·········· ... ·············· ····-·····-······ ····-···-··· ········-··· -------······ cont•i~u • .... 51,269,000 ,_ . ... 115,000 ,_ .... 55,070,IDO ,_ On-,111 Jnclrwntlon, o,-,it• Ash Dl~•l, s-11 Alt. 5 ·A-1 s-H Alt. 5 A-1 Same H Alt. 5 A·I s-II Alt. 5 A·1 ................................................................................................ ····· ... ········ .. ·······• ····-·· ............. ·•······· ·······. ---·············· an-,lt, Jnclner•tlon, bh Dhpoul In fu'llclpel L~flll s-11 Alt. 5 ·A·l s-H Alt. 5 A-1 Sanir H Alt. 5 A-1 s-11 Alt. 5 A·1 .. ······-······ ................................. ······· ....................... . an-,lt• lnclNntlon, Off•1lt• ICU .lth Ol1po11t, s-H Alt. 5·A s-H Alt. 5·A ...... -·. .. . . . . . . . . . . ............ ·-·...... . ......... ---. . . . . . -...... -. -. . . . . . . . . .................. -. . . . ... -. . .. . . . . . . .. . .. . . .. . . . . . . . . .. . . . . . . . ............. -. . .. ·-....... ···-.. f11lly 19')1-ttd hc:aHlior, Is • c-c:-truc:tlon pf' Kt I Cl• D"Pffldl Ot1 th• avtlllbllhy of lnr::inrrttlDl"I c:epec:hy. Should raq.,lr11 ,bout • ~•r to 1-.,t-t. Off-sit• lncl,-r,tlon I Hh DI spout s-11 Alt. 5·A s-II -'lt. 5·A E•c•v•tlon will incr11H fuoltl"' 0...t erd org•nlc: vapors. ····-··············• .......... ······· ....... --·· .. ········· .......... -· ..................... ····· ............. ····· ........................ ··-........ ···•··· .. ···········•····· C-r•tn ,..,,.,., D~Otlth• ,,...\t•bltty of th• ln·•ttu ln•,ltu Yltrlflcetior, Cfntln Siu) Low t~r•tur, The.-..t OHorpt I on with On•1lt1 Ion· ICU. Soll Oi1poul Oroanle eont•lnanu an dntro)"t'd .-.rt lnoroeniu tr• lncorporattd In th• _, t. Oro•lnlc: cont•l,-,u ara th1t.--lly drstroytd. Solt -t pan ICIU hHtrdoo.n ch,ract.rht le t1t'tt Ing VI trl fleet Ion prOC:MI will c~ly 111th AR.Alt, appl lcllble to lncirwretion LODT wilt e°""ly w! th •ti ,ppl I cable AllAR,. 11\ll providlt a 1tffe-ctive long·t1t,.., ■rd P"r.,.r>lt<'lt rltfflrdi ■tion Organic cont""i,-.nu ar• dr11royM. 5oi l ~t not bit RCRA huardous. Yltriflc1tlon P,-OC"'" rffl.JCH the to•lc:lty, "'<>hi\ity, .--.::l vOIUlllt of !hit weSIH. l!ltdo.JCH to•ldty and volUl'le lhrOV!ih ~~~!~ ~,. fuoittv• Mt l•wt n,ch IHI th,n with ucavnlon. E•c■vn Ion wl l l incrH11t fugitive tiu.t and org,nlc vapor1. E_t,lone fr-thl LOOI llllt 1hould bit frtt of con I .,.1 nant •. vhrt fic:atlon 1.r1I t. C~l1ttl01"1 ti• about :, ~an. lDOT sys,t-1r1 av•llll.ble fr0111 11tv1r•I wndor1. htt-tad c~t•tiOl'I In app,ro•. z.n .,...n. 48,186,000 ., ... n, 116,000 .... ········ ''" 51,026,000 ,_ 46,041,000 ""' 69,Zl0,000 ············ .... 91,731,000 ,_ ll,451,000 ""' 12,,,n.000 ··-········· .... Z0,,'49,000 ,_ 11),049,000 ""' 269,571,000 ··-···-····· .... 50,257,000 ,_ 45,221,000 ""' 65,791i,OOO . ........... ''" Z7,l14,000 ,_ 10,201,000 ""' -11,a.11,000 115,000 ""' 133,000 --·········· .... 116,000 ,_ 115,000 ""' 131,000 ······· ····-. ... 115,000 ,_ 115,000 .... 111,000 ..... ··--·-· . ... 114,000 ,_ 114,000 ""' 111,000 -·······-··· .... 117,000 ,_ 117,000 .... 1JS,OOO ............ .... 115,000 ,_ 115,000 ""' 113,000 49,914,IOO .... 74,llt,IOO ............. .... 52,Ml,D ,_ 41,&Jt,IOO .... 11,111,IOO -····· ....... '"' 9l,5k,OOO ,_ 14,249,000 .. .. 126,655,000 --··········. .... Z07,J21,000 ,_ 1116,IZ4,000 .... ZTl,621,000 ··-·-········ .... ,z. 101,000 ,_ 47,061,000 .... 61,920,000 ············· -29,IIS,IOO ,_ 4J,9l0,000 .... 22,010,000 •••••••••••••••••••••••••••~H••■n•u , •• ,nu••••••••••••••• •■n■•■:■H■■■•• • •• u•••••••• • eu su•••• •• •••"•n•■■■u•■•• .. ••••••••••••••••••:s••••~~• ••••• .. ••••• .. ••••••••••••••••••••••••••••••••••••••••••••••••••••••!•••••••••• -- ----... ---.. -- I I I I -I I I I I I I I I I I I I Long-term Effectiveness and Permanence: Alternatives 4 thro~gh 7 offer long-term effectiveness and permanence for remediation of the site. However, in Alternatives 4, 5, and 7, inorganic contaminants are not volatilized or oxidized and remain in the soil, which may require additional treatment to stabilize them. In Alternative 6, inorganic contaminants are incorporated into a melt/glassy mass, which is very resistant to erosion and are considered immobile. Und~r Alternatives 1, 2, and 3 the contaminated material and wastes will remain on-site; therefore, the long-term effectiveness of these alternatives is questionable, and they are not considered to be permanent remedial solutions. ( Reduction of Toxicity,_ Mobility, or Volume of the ContEll!inants Through Treatment: Alternatives 4 through 7 reduce the toxicity, volume and/or mobility of the contaminants through treatment and do not require long term management and monitoring of the wastes. Alternatives 1, 2, and 3 leave contaminated soil and wastes on-site. untreated wastes amy cause future environmental problems and will require long-term management and monitoring. Short-term Effectiveness: All of the alternatives that require some form of remedialtion will temporarily increase the risks to public health and the environment during their :implementation. However, these risks can be minimized by implementing proper dust and vapor control measures, and on-site workers can be protected by wearing personal protection equipment. Alternatives 1 and 2 will not significantly increase either the risk posed by each area above its current level, or the short term risks. Implementability: All of the alternatives are implementable. Implementation of Alternatives 4, 6, and 7 may depend on the availability of mobile incineration, ISV, and thermal desorption equipment, respectively. Mobile incineration equipment is available from numerous companies; however, ISV equipment is only available from a single company. Thermal desorption equipment is available from several companies; however, each system differs in the way it treats the off-gases, which must be considered when choosing a vendor. Alternative 5 Off-site Incineration, may have to be implemented in stages, depending on off-site incinerator capacity. Cost: The present worth cost of the various alternatives range from $1,777,000 for Environmental Monitoring to $203,327,000 for off-site Incineration. obviously, the alternatives that require treatment and/or off-site disposal are the most expensive, but are also the most protective of human health and the environment. Alternative 5 ·off-site Incineration is 7 times more expensive then other alternatives offering·the same level of protection. EPA believes that the most cost-effective alternative is Alternative 8-Excavation, on-site Thermal Desorption, on-site Ash Disposal at a present worth cost of $29,115,000 which provides the greatest protection to human health and the environment for the cost. State Acceptance: The state of North Carolina concurs with this selected remedy. Community Acceptance: 9.0 THE SELECTED REMEDY The selected remedy is Alternative ?-Excavation, On-site Thermal Desorption, on-site Disposal. Table 26 provides a detailed cost summary for Alternative 7. Common elements of the sele.cted remedy to each area are discussed below. 9.1 Common Elements EXcavation Goals Excavation of contaminated soil will be required at each Area of the Site. Areas requiring excavation are identified in Figures 17 through 21 • The total volume of contaminated soil requiring excavation from the Site is 99,193 cubic yards. The depths at which Areas are to be excavated and the volume requiring remediation are identified in Table 27. Included in the volume to be remediated are 3,200 cy of previously excavated and stockpiled contaminated soil at the Mciver Area. Volume by Area of contaminated soil requiring excavation and remediation is: ~ Volume to be Excavated Volume to be Remediated Farm Chemicals 48,443 cubic yards 48,443 cubic yards TWin sites Area 26,616 cubic yards 26,616 cubic yards Fairway six Area 16,45~ cubic yards 16,453 cubic yards Mciver Area 2,740 cubic yards 5,940 cubic yards Route 211 Area 4,481 cubic yards 4,481 cubic yards Total 99,193 cubic yards 101,933 cubic yards The soil cleanup goals or dig up goals are identified in Table 28. Cleanup goals were developed for the protection of direct contact with contaminated soil and are at the 10-6 end of the protective risk ·range. These cleanup goals are further supported bi the summers Model which was applied to each Area to estimate if the 10-health based levels would also be protective of groundwater. only contaminants for which there exists documented physical/chemical data were modeled. In order to meet North Carolina standards for the protection of groundwater, cleanup levels must be established at 10-6 health based levels. Centralized Location for Treatment CERCLA section 104(d)(4) allows EPA to treat noncontiguous areas as one site for the purpose of taking response action. The Site is comprised of five noncontiguous areas which are reasonably close to one another (all areas are within a 3 mile radius). The wastes are similar or identical, and are appropriate for like treatment. Moreover, all areas are related on the basis of the threat, or potential threat to the public health or welfare or the environment. All areas comprising the Site fall outside of EPA's protective risk range between 10-4 and 10-6 • Treatment at a central location is cost-effective, more efficient and is in the best interests of achieving a sound and expeditious environmental cleanup at the site. 7(p I I I I I I I I I ~ , .... I i I I I I I I I I I I I I -I I I I I I I I I I I I I I I TABLE 2~ cost summary for Alternative 7 Low Temperature Thermal Desorption ···········••·············•·••··•·· ............................................... -............................. _________ ..................... ___________________________________________ _ ,. u.,!TAL COSTS: COST ELEIIEIT TOTAL IASE COST IIIGM '"" .................. um . ....................... ·························· ························· CIUAITITT UNIT COST '•rc.,,t•• ANO.JIil IS) ,ercfflt•• Aaoo..r,t (I) Pffc..-.t .. Aac:u'lt (I) ·-· ·········· ......... ············ ...... ············································--··· ......... -····· ......... ........ ............ ········· I.I CAPITAL COST ITEMS: A. Acc■11 l~oveamt and Security INd 1-.pr-U 4000 " '" 1160,000 "' 1164,000 ·101 1144,000 ClHrlng 1., AC 15,000 t.8,000 m 19,000 ·101 17,000 fencing 4000 " "' S60,000 "' 169,000 .,. 1'7,000 I. A■botstH ll'IIIIIVII 300 " " 11,080 2,X 11,000 " 11,000 c. lulldh,g o-\ltlon 160,750 " " 1322,000 "' 1403,000 •\01 1290,000 (lnc:ludlng ~on .-.d dllpoul In Jiv,lclpel lardflll) D, Soll/Wlltll hc1v1tton 98,733 CT '12 1,,,as,000 "' 11,422,000 ·101 11,067,000 l. Load Tru.:IU (111 1-heh) 15S of hc...-u Ion 1118,000 m 120S,OOO ... 1169,000 f. tr-porutlon (5 •lln I 14 per •Ill) 6,loa Truc:kl ,20 1126,000 ,.. 1151,000 ·101 1113,000 G. Shrt'd 1nd Stu 111t.rt1\ 113,543 CT " ll41,000 "' 1392,000 .,,. 1171,000 II. On•tltl LDCT TrHtaent Cl1~/ton or CT) 116,743 CT 1125 114,593,000 401 1.20,00,000 •301 rl0,215,000 I. TrHtablllty Tntll'III \ L.li.._1150,000 1150,000 "' 1173,000 ·5l 1143,000 J, LMd' Tr-port to Off·1lt1 ICU '•clllty 2 Tn.clr.• Sl,600 17,000 2111· ---18,000-·101 ... ooo (31.l Tona of Conderaed Cont-lMl'IU) ,. Off•,ttl lnclNrUlon u S0.60 /lb 62.600 " ..... 1:sa,000 ,.. 146,000 •\01 134,000 L heir.fill with lrHted Sot\ (10X rld.ctlon) 102, 1"9 er 110 11,022,000 m 11,17',000 .,. 1971,000 Ill, hckftll 1o1tth ti,., ,Ill 11,]54 CT 110 1114,000 "' 1131,000 .,. 1,oa,000 •· Gro.rdw,t1r Mont torlnQ w,t 1, 12 " Sl,600 143,000 ,.. 152,000 •\01 Sl9,000 O, llydro SNdlng IS AC 11,000 115,000 ,.. 118,000 •\01 114,000 ,. fllonltorl!'III S~llng "' .. "' 123,000 ,.. m,ooo •\01 121,000 Laboratory Analysl, ., " 11,000 ..,_,,. ,.. 198,000 ·IOI 174,000 leport ,r~ratton 100 " '" "·"" 201 110,000 •101 17,000 0, Mobtllutlon/Domblttutton \ , .... 1250,000 1250,000 251 131],000 .... ll00,000 ········ ............ ......... ········•···· ......... ............ 1.2 UTIMATEO WIU.L Cl»T ,,. IHl,n6,000 "' S.ZS,3US,OOO '" 113,1151,000 \ ., UVEL Of 110,LTII/SAft:TT PttlTECTION (1 l It• 1,2) 10:r. C/D 11 ,!73,000 20I 1/C S5 , 064 , 000 10X Cl'O 11,)85,000 1.4 flULTII 'SAffff OtTt:a:UG (I of It.-1.2 and 1.3) n 1412,000 n ..... ooo n SSOS,000 ,., M 01 ITEIIS 1.2, 1.3, ANO 1.4 ,,. 121,011,000 '" 1]0, 990,000 .,. 115,541,000 ,., COIITUGEICT (S of It .. 1.5) ,.. 14,202,000 201 16,198,000 201 Sl, 1011,000 10• ,2,101,000 "' 14,640,000 101 11,554,000 ,., UITITUTIOltAL Alltl UGIIHIIIG (S of It-1.5) ........................................................................................................................................................................... 141,1137,000 120, 201, 000 1.e lOTAL (STJJIIATEO WITAL COl1 CYa\UI ACU"lded Off) (Si..a of It-1.5, 1.6, end 1.7) 121,314,000 '" ,,. "' 153.001 74.001. 1.9 ,uctllf Of TOTAL IJ.st COST (I) ·····-···················· .. ··· .. ·····---·---····· .. ···---· .. ···-.. --.................... ---........ -----····---······-----················ • Jncludlne ov,rhuod, ta.,rcten, and profit .. Perc.nt-,, OV'tr the bllH coat appllcabl• to l~IYIO..l coat It• only. 1/A • lot -wticKII• All valUl'S rou,d,ecl oft to the ntarHt 11,000'•• ·····················--··--····· .. ··· .. ······---·······--····---·---·····-··-·-······--···-··-···-·--·· II. 0' Ill COSTS: II.A Arn.ial llonltortl'III Cost Slbtot■I 11,1 Arn.iat Optr,tlon, Jllalntel'W"IC,, & lntpectlon a. ln■pe,ctlon b, Oper■t ton C, ll■tnt..-..nc:e lASE• .......... 1113,000 ......... 1113,000 "'° " 11,600 IIIGII ....................... Percfflt•• ,._,,., (1,) ......... ·•·········· "' 1110,000 ······--· ............ ,,. 1130,000 "" "" \Ol " 101 11,800 ............ '"' ••··············•··•··· ,,rcent•• -'-U,t (SJ ......... •••·•••·••·· Ol 1113,000 ......... ........... ,,. 1113,000 "' "'" ... " ... 11,500 ......... ............ s..btotat • 12,400 1/A 12,700 tl./A 12,300 ····························--············--·································· .. ······· .. ···································· 11.C TOTAL .I.IOIUAL O ' Ill COST 1115,000 ,,. 1133,000 ,,. 1115,000 11.D PEIICOIC JIIAJoi: ITSllll IEPAll cmr••· Sll,000 tl/A 115,000 I/A 112,000 .................................................................................................................................. • lnc:li.dtr,. ~. l:lur'dtrl, and profit. -Perc-.nt.,. ..,.,. Ute t.H coat • ... lh• coat 1o1llt Incur orca -ry 5 .,..a,. at 5S of th• -of It• l.1·A end •• ti/A • lot appl lubl• All val-. ra.rd■c:I off to tha nnrnt 1100•■: ..:I. •Jor tot ■la rCIU'l:Md off to th• Na,....t 11,000'•• ............................................ ----.. --.. ···-------···--·····-·---·----·-----···-........................ . 11!. SEIISJTl'IITT .uALTSIS AND PlfS(IIT IM:alll: Ill.A SUS1TIYl11' UALTSIS: s-ltivlty factor ........................ 1. w11t,1Soll E•ca••tlon 2. On•,ltl lnc:1,-ratton 3. Tr-porutlon of A•h 4, A•h tllsp:,ul Ill.I COST YUIATIOII: J1.r1ttflcatton for COl'lltderatlon .......................... UncertalntlH In -at• characttrtntc■ llaJor cost lt-Jllajor con I 1• Jllajor cost tt-,.,,,. •25 to ·SS •25 to ·101 •20 10 ·101 •25 to •20X Justification for •ene• . ..................... . Unc,rtalntlH tn tha q.ant\ty of ,,..,ta to t. ellcavated. Uncart1lnttH tn th• duration •rd cnt of lnc:lntratton. Unc•rt1lnttes In th• hauling dtn.-.ca. Uncartatnt\H In off•■itl ICA.I. dlspou\ cost. Capt la\ Cost■ (S) ""' 0 & II Cost 0/YHr) PrHtnt worth (I)• OUCIIPTIClf la■• ,_ .... """ ,_ laH """ ,_ ................................................. TOTAL COST 127,314,000 141,1137,000 120,201,000 1115,000 1113,000 1115,000 129,115,000 143,920,000 122,001,000 SAL YAGE YALU( SO SO SO SO SO SO SO SO SO ............................................................................................................................................. TOTAL 127,31',,000 141,IJ7,000 IZ0,203,000 1115,000 1113,000 1115,000 129,11S,CIOO 14],920,000 122,001,000 --·-··-··-·--·-------------------------• lnc:li.dl,. capital, ...... 1 01.11, W'd perlodlc •Je,r ..,.. •• ,.,.,,. -u. All wl~ ~ off to UHi ,,..rHt ,1,000•1. 17 ,.rcent Varl•tlon frca In• • so.a •24.41 --·----·-· DENSE TREES VUfri[RN FIGURE 17. Area requiring excavation at the Farm chemicals Area. _ _,,,.._........., so...,,,,-s, ----....~-----C-..-,.Nen•c..•-. , Surflclel tSubwrt,c. S.,,,plo location O.ptl'I (rt) : To~I PHIICIOII Conconlr,!lon !ugl'kgj ffl A•-Uc.w .. ..:I to 5 F .. 1 BGL ,.,.,. E.lcawat..:1 lo 10 t=.et BGL Ar-bc,vatod lo 15 fffl BGL ~~:ll •· + a,. •r:'.: ~ ~~ 1~ -,. m-11•" 111 Ul,-i:,o ..... ::: -~~ ' -~ •m FIGURE if .·Area requiring excavation at the Twin Sites Area. 7f PAGES LAKE I I I I I I I I I I + I + I I I I I •• '· .;i~; I I I I I I --1 I I I I I I I I I I I I I I + Ir l ----/-J • + ! i(ii) J cl -. ; : + + ,, // ,, // // II --(-... ,:,i ';' -~ . :-:-.-f ~ "( FIGURE /1 . Area requiring excavation at the Fairway Six Area. AEPCO -, .. , ....... llfaslbllly SOldy (Rl.fS) ---Site --eount,,llor'II- OENSC mus _,_ (ft)■T-P..clddl m4iskA•~ ~■IFMll8CI. ~•11F..t1Gl. SCALE: I • • FIGURE zc. Area requiring excavation at the Mciver Area. 7'1 -·- North @ + AtlNdlllllmdg I l'ftnfblltySludy(Rl,f'Sl ---Sill AblrdNn, lloor9 C<utty, Nari\ Cnllna J.EGElll2 e e Wrri"l I 1M,... Loelllon .... Dlpll(ft)•Tolll~ O...ea:balc.1fl9't;) IS.'SJ k•~•10Fat IGL SCALE; I • FIGURE 2/. Area requiring excavation at the Route 211 Area. TABLE 27 VOLUMES OF MATERlAL REQUIRING REMEDIATION FOR CLEANUP TO LECR OF u!O~ SOLID MEDIA foUfl CIIEllltALI IITt ScuU.,.m lr-1'1 C.,,tr■l Tr...:11 Ent•"',~ 10' h-tlcrt 5' l.<.c-tta,i ..... ,,_. Arn C Trrct, 10' bu.,etlon 5' t:a.c ... •1t0fl SJ:,toul fAII\IAT SIX IHI tr...-r;t! Uoci;pit• 10' hce,,.th1n 5' hcavatlcri S<&lt~UL IOJ'II 211 SIU to• ~tlai, TOTAL llllTtll.lL to II PCAVAT[ll 576,000 cf :soa,ooo cf J.6,000 cf 271,000 cf 111,000 cf t,l01,000 cf 140,625 cf 135,000 cf lH,SOO cf 17,500 cf l4l,500 cf 100,1'50 cf 444,ZSO cf 116,400 cf '6,000 cf 1,000 ci 160,40il cf 1l1,000 cf 121,GO:il cf ro 11.m cy ,,. ,,, cy ,,mcy 10,296 ey 4,J7'0 cy 5,208 cy 5,000 cy 1l, 167 ,:y J,16' cy u.,,, Q' 12,m cv l,7J1 cy ],200 cy l,""4 cy ... " 5,"'4 cy 4,4"1 cy 4,411 cy 101,913 cy I •• I ,·-( I I \ I ~-'\ I I I I I I I I I I I I I I I I I -I I I I I TABLE J-J_ Lifetime Excess Cancer Risk Target Cleanup (Excavation) Levels For Soils At Each Area Farm Chemicals Area Residual LECR of lxlo-6 lne Line list Tar-get Clean Up Con::rr-:r1tion {ug/11:g) --·························· Target ············l············I············ ....... ~~: ~~ '. ............... ~:~~;:: ~.:: :~~::: l: ::[ :: l:~:;~::::.;; f:;~~ .: : : : :~~:: :: :1::: ::J: :: : 1::::: ;r::: L1'£Tll'!E EXCESS All:SENIC IIICX:El ' ''·DDO ,·,•-ooe ,:,•-oor ALDRZ• AlPHA•BHC IETA·IHC 01£LDRUI CAM.I, • I HC KEPTACHLOII: TOXAPH(NE CANCER RA TE: TOTAL ·•ThHe lewls should bt 250 ug/kg to Dt-et grOU"Q,jater AR.lits. 2,463,000 2,000 15,97'5 "'' 959,500 100 57,574 29,278 260 89,47'5 94 2M,212 •• .. 1E·06 6E·08 9"·05 5E•07 1E ·04 2E·OS 1£-06 JE-05 1E-07 9E•05 JE·OL •• .. 1E·06 7E·OS 1E·04 6€·07 1£-04 2£-05 1E·06 4E-05 1e-01 1E·04 4E·04 •• " 1£·05 6£-08 1E·05 2£-06 1E-07 •• 1£·08 1E·05 -----. -. -. 4E·03 1.2£-07 •• 1.2E·07 •• 1.ZE-07 •• 1. 2£-07 1 .2E-O7 1.2E·07 1.2E-07 •• 1.2E-O7 ......... 9.6£-07 Fairway Six Area Residual LECR of lxl0-6 • • • • ,.n, " 1,217 •• 66 230 26 318 .. 376 --·-··-····· " " , ,47'5 •• ~.0,41-•• 56 197 22 2n • • 322 ·····--····· 74 .. •• .. -----9,-757-•• ,., 2,049 2l1 .. .. 3,353 ··········-· ..... --.. -. ---· .. -.... --. -...... ------· ..... ----. ----. --·--. --... -... --.. -. -------.. -. -.. --· -----... -...... ·•· -----y.,.. .. , Cl..., Uc CO"C ... tru\o, (U'i'l/t;) ······--···--·-···············--·-···-·· or,t o.,,--L IM•IUiCl"I ··-·······--------· ---------- lHEilJll.E UCES~ C,.WCER tAiE: Cill0.11.111 15,0]5.D .. .. .. )(-05 1 .5E·07 " ···: ···· 1···: ···· IS .......... .. " 4,4'·000 563.0 71.0 ..... ,. ... 1E·Oll .. .. •• .. ... .. 4,4'·00E 1]2. 0 150.0 2E·Oll ,. ... 4E·08 .. .. •• ... .. .. 4,4' ·00? 12,a,;].O ,. 100.0 2'·06 ,. ... U-•07 2E-07 1.5E·07 ,ll0I.IN 26.! 2£•07 2E·07 •• ,, ... 1 .5E·07 .. , "'' ... 9,07'0 20 20 .. • • ALPIIA·ll!C 61!.D 5.0 2'·06 2E·06 ]E·08 2E•07 1 .5E·07 .. " ... ... IETA·IHC l9\.D 22.0 2£-07 lE·07 ]E·Oll 2E·08 1 .5E-07 21' 146 •• .. 01El0111 "·' 4E·07 4E·07 .. 4(-05 1.5E•07 20 20 •• .. ~ -I HC 130.0 , .. ,. ... ..... 5E·09 .. •• •• ... .. .. tfEPUCHLCII 66.2 1E·07 1E·07 •• lf:•08 •• •• .. ... .. M"EPlACIIU:JR EPOIIOE '5.2 2E·G8 ,. ... •• 21!•09 . , ... ... .. ... TOUPl!hE 1,]7'0.0 6E·07 SE:·07 ... ,. ... 1.5E•07 '" '" ... ... ··---··············-··-···-·-· ----------------· ...... --···-···· ---···· ... ----------TOU.l 5.7(-06 6.0l-06 4.2'£·07 J.1E·0'5 1.11!•06 Target ClHn•~ l ... t (1.11g/lr:g) 74 • • 1,47'5 .. 1,041 .. 56 197 Z2 in• .. 322" ------------- hr11<tt ct .. an Up L....el, (U'i'l/kg) ... ----.. -----. -. --- ---"·,,·1····"'···· "'' 20 .. , .. 20 %57 . ......... tool P"tidde ccn:tntr,tlan 1,496 I ti 'I TABLE J!.L Lifetime Excess Cancer Riek Target Cleanup (Excavation) Levels For Soils At Each Area Mciver Area Residual·LECR of lxl0-6 Bese Line Risk Target Clean Up Levels (ug/kg) Oral Dermal lrY'lalation Che-mi cal ss ss ss LIFETll'!E EXCESS CAMCER. RATE: 4,41 ·000 ,. 101 3E·07 3E-07 NA 1.SE-07 2,155 1,844 NA 4,4'-00E 1,400 1E-07 2E·07 NA 1.SE-07 1,521 1,301 NA 4,4' ·DOT 34,240 3E-06 4E-06 3E-08 1.SE-07 1,521 l, 301 NA ALF'HA·BHC 80,158 1£-Qi, 2E·04 1E-Oo 1.SE-07 8, 70 10,716 BETA·BHC 14,-718 8E-06 9E-06 6E-05 1.SE-07 287 246 NA GAMMA·BHC 2,985 1E-06 1E-06 NA 1.SE-07 398 340 NA TOXAPHEME 30,265 -------------------------------------------TOTAL 167,867 1.CE-05 1E-05 TE-Ol! 1.SE-07 ------------------------------------1.TE-04 2.0E-04 1.3E-06 1.1E-06 Route 211 Area Residual LECR of lxlo-6 470 402 NA . --. ------------------------6,435 5,505 10,716 I I .... l,i,w litir. I p.~ ... : ::u ... ~ :.-l ..... ,ti) II I l·········•··················I T1r9,t l·············•················!I ?11r,.t I (ace-sun I 0,.•l I O•,-\IJm•l1ti0""1! Cl .. ,,~ I :,I(· I 0~,...,..l jlrT••ta.i,....,!j c:un ~ I IC-=..,.,t,.nionl··· .. ··•JH .. ••··l··········I 1.-l 1··•······[·········1····•·····!1 1,.,....1 I. o.-iul I w,a/lr.9 I ss f ss J u IAll 10t.rt"! s:: \ ss I ss II cwi;nei I 1----------· -·---------·-------------· ---· · · ----· -·-· · -·-· -· ·-· · · -· -· · · -· -· -------·-· I -· · · · · · · · · · · · · · · · · · · -· · · ·--·--·· · ·-· ---· · · i ILJFETJME o:ass c.ucu UTE: I [11 ,,t tu I I •ICUL S,)00.D U IA 3E-~ U I u 11A IU. II I I I I ,.,•-000 I 17,i!ii'V.o U•06 tt:·06 ..,. 1.n.01 2.~.:.3 2.~? u 11 2.~ I I "·''·Dllf I a.s u-10 p.Of:·09 1 ,u, 11,1. MA u u I! I J "·''•COT I 35'-,920.0 3E·05 I U·~ I U:·07 1.7i•07 1.r:?.:. 1,.:.:-; t.:.l-:-:Z II ,.,~ I a.r.•iu-111c I ..,""8,9'lo.o U·03 I n:·Ol f lE-05 1.n:-01 O! ao ,.,~ II ao I 1EU.•111c I 35,&es.o ;n.05 I 2£·0'5 I '-E·07 1.11.01 3Z!l 2n 1:s, tl11 11 2:"9 ..,.__..,.cc t u. ne.o 5E·06 I 5E·06 I u 1.n.01 ,si l.:.e "' 11 l"'6 I t01u11c11E f ,112,,n.o J ZE·O. I JE·04 I 5E·06 I 1.n-01 1 533 '-!lo 2'-,&-42 II ,~o I I-·-···-·-········-··-··-······ I··--··--····· I········ 1-···-· ··I·········· I··--··-·-· I········· I········· l ·· · ·······II····-····· I I tOUl I I 1E·Ol I 2t·Ol I 3£-~ I _1.0E·Oo I I I II I ...................................................................................... --....................... ·---............ -. Tar-get Clean Up Level (ug/lr.g) • 1,841, 1,301 1,301 70 246 340 402 ----------5,504 . .,_ _,i,;i:,.__ I I I I I I I I I I . I I I I I ·I I I I I I I I -I I I I I I I I I I I I I I I The Fairway six and Mciver Areas were both considered as the central location for treatment and were subjected to public collllllent. The Fairway Six Area has been selected as the central location for treatment. The rational donsidered for selecting this Area include: The volume of contaminated soil requiring treatment at the Fairway six Area (a total of 38,453 cy, includes 22,000 cy from OU Two) represents 31% of the total volume requiring treatment versus the volume of contaminated soil at the Mciver Area (a total of 5,940 cy) representing 5% of the total volume requiring treatment; The distance from the Farm Chemicals and Twin Sites Areas to the Fairway Six Area ~s approximately 1.75 miles while the distance to the Mciver Area from the Farm Chemicals and Twin sites Areas is approximately 4.5 miles. the Farm chemicals, Twin the total volume of soil The contaminated soil requiring treatment at sites and Fairway six Areas represents 92% of requiring treatment; Transportation of contaminated soil to the Fairway Six Area is through a sparsely populated industrial area while transportation to the Mciver Area would be through a populated residential area increasing the short-term risks to residents; Noise pollution would be a nuisance to nearby residence due to the 24 hour a day operations. A resident lives approximately 1000 feet from the Mciver Area. Transportation and Storage The contaminated soil meets EPA's criteria in determining whether a CERCLA waste is a hazardous waste. The waste is a characteristic waste because of its toxicity and a listed waste because it contains P and u listed waste codes. When the waste is excavated and moved out of its Area of contamination (AOC) for treatment, placement will occur and RCRA's Land Disposal Restrictions become applicable. Transportation of the Site hazardous waste from one AOC to another will be subject to RCRA manifest requirements. RCRA storage requirements of hazardous waste prior to treatment are applicable at this Site. Temporary storage·of waste residuals after treatment will also be required until the waste residuals are delisted as a RCRA hazardous waste. Treatment of Contaminated Soil and Off-Gases The treatment technology selected for remediation of pesticide contaminated soils is thermal desorption which will be implemented on the Site at the selected centralized location. Thermal desorption is an innovative treatment technology which utilizes indirect heat to volatilize the organic contaminants from the soil. The contaminants are captured in an off-gas and are further treated to permanently destroy the toxic contaminants. Off-gas treatment varies depending on the vendor, but usually consists of either: (l) thermal oxidation in a secondary thermal oxidation chamber similar to incinerators; (2) condensing and concentrating the organics into a significantly smaller mass for further treatment (incineration); or (3) passing the off gases through activated carbon to adsorb the contaminants and then regenerating the carbon. This Record of Decision will not select the off gas treatment so as not to limit vendor competition. However, EPA will review and approve the secondary treatment prior to implementation. Treatment Goals The treatment goals for the site are RCRA Land Disposal Restriction standards and RCRA delisting requirements. Because the LDR treatment standards are based on treating less complex matrices of industrial process wastes, a treatability variance is sought to comply with the LORs. This variance does not remove the requirement to treat restricted soil and debris wastes, rather it allows alternate treatment levels based on data from actual treatment of soil, or best management practices for debris. These levels become the treatment standard that must be met. Table -~l identifies alternate treatability variance.levels which must be attained. A percent reductiori of organic site contaminants must be reduced to between 90 -99.99. percent depending on the structural/. functional group or groups applicable to the site. verification testing using the Toxic Characteristic Leaching Procedure must be performed to demonstrate that the RCRA listed waste is no longer characteristic for the organic constituents. Although.inorganic constituents are not the primary contaminants of concern at the Site, there are localized hot spots with elevated metal contamination. These areas will be segregated before and after treatment. sample collection and analysis will be the same as discussed above for the inorganic constituents. If the treatment residuals do not meet the alternate treatability variance levels as identified in Table _li, further treatment through immobilization will be required in order to meet treatment goals.· rsed The best demonstrated available technology used to -set LDR standards at the Site is incineration. A treatability variance is also sought in order to not unnecessarily restrict the development and u~e of an alternate and innovative treatment technology, thermal desorption, for remediating the Site. Delisting of RCRA Hazardous Waste Once a waste is identified as a RCRA hazardous waste and it is moved out of the AOC for treatment, it must be handled as a hazardous waste even after treatment based on the derived-from rule [40 CFR 261.3(c)(2)]. Waste to be delisted must be managed as hazardous until it has been analyzed in accordance with sampling .and analysis requirements. Delisting of a hazardous,wastec requires a demonstration that a listed RCRA hazardous waste no.longer meets any of· the criteria under which the waste was listed. To··demonstrate compliance, verification testing will be required following."teatment'·of the wastes to confirm that delisting. levels are attained. Verification'testing will be collection of samples of the treatment residuals<and analysis of those samples for total and TCLP leachate concentrations··of inorganic and organic constituents. {-. I I I I I I I I I --· .. I --I I I I I I .. , . ,· !--:. I . .,. .. I I I I I I -I I I I I I I I I I I I I I I TABLE Z 'j Alternate Treatability Variance Levels and Technologies for Structural/Functional Groups -Non-Pow 0.5 -10 . 100 ·-. c1o:on11 o.ocm, -o.06 o.5 PCS. 0.1 -10 Herbicides 0.002 -ci.02 Halogenatsd 0.5 -<40 Pheno<• HaJog8!'\4t8d 0.5 - 2 Aliot'lat!C:3 Halogenated 0.5 -20 Cyci>eo Nitrated 2.5 -10 Aromatics HaUN'tlCyClic:8 0.5 -20 Polynuc...,. A,cma,c, 011181' Polar Organics ,-:i;~-6-~-G~~ICS Antimony Arsenic 8'num Chromium Nickel Sel9l"lium Vanadium cacm,um Mercury 0.5 -20 o.s -,o 0.1 -0.2 0.3 - 1 0.1 -40 0.5-6 0.5 - l 0.005 0.2 -20 0.2 -2 o., -3 O.oo::2 - O 008 100 0.2 <CO "' 200 ,a.coo 200 <CO 100 ·•.•· 2 10 <CO 120 20 0.05 200 "' 300 0.08 go -"9.9 Sl0 -99.9 SlO -99.9 90-.. 96 -99.9 QO -99.9 99.9 -99.99 !ilO -Sl9.!il 90-.. 90-.. .· ....• ,<< '"''" 00-.. 90 -99.9 90-99 95 -99.9 96 -99.9 90-99 90-99 95 -99.9 99 -~.!ii 90 -99 Tech 0 le QtH tt\at tlChieved recommended -concentration guidance- Dec:hlomdon, Soi Wa:stw,g, Th9nnlll DNtruction ~Treatment~ Soil Wastiing, -Oes,rucoon -~ Biological Treatment. Law Temp. ~. Soil Washing, Thermal DestnJc.1lon . ~~ Low Temp. Stripping, So,i Wa:.r re ~ Tl'MtrT'lent, Soil Washng ,_ D"""'°""" ~.ale:=, Low T.,,-,p, Sb'ipping. Soil Wa.s~r:-1:; .,,,.-,.-\•;; :',:-.-/:i_..i:t=.':"::··~,-,: ., lmmo0di%anon lmmoblliza1X.ln, Sod W1:st11na Immobilization lmmot:,dization, Soll Washing lmmobda.don. Sod Wastung 1mmo01bzabon lmmo01!1Zlltion lmt'T'IObllizatlon. Soil Washing lmmoblliza!lo1"1. Soi! Wash1f"IQ lmmobll1zatl0r'I TCLP al.so~~ uud ~fl rvafuotvlg wan,, in ..,/,i,;J, O'JC'l-10 an l'IDl a pnnc'.pal corwuiuru 1.Aat'haw bu" ln'CUd INOUV, .vi i,,v,,c,t,i~ prcxt:u. O!Mr uCMD~:1 moy ~ wt:d if tnaiahiiily m,d.ia or o/Nr VlformalUNt in.die.au., U1Ql ~ C41'1 ad,ir,,,t 1M MCf:UIJry conul'llrGllDn "' f"'-rr:tru-rtlWctlOn. rwi~. In addition, once sufficient data are collected on the waste and its pot.ential fate and transport, models are run to evaluate the dilution and attenuation of constituents at a hypothetical receptor well. The calculated concentrations of constituents at the hypothetical receptor well must at least meet the health-based levels used for delisting decisions for the waste to be successfully delisted, Table ...l.~ identifies the maximum allowed concentrations for specific constituents based on the current health-based levels (l0-6 risk). Disposal of Treatment Residuals When the treatment goals are attained, and the listed waste residuals are delisted, the residuals will be transported and redeposited in the area from where they originated. The areas will be backfilled with fill material to grade and then revegetated with native grasses. Identification of Hazardous Waste Site All areas of the Site shall have proper warning signs posted in a visible location in order to provide site control where humans have access to the release. 9.2 Elements Unique to Each Area The selected remedy involves elements which are unique to certain areas.of the Site and are discussed below by Area. Farm chemicals Area The Farm chemicals Area has 14 structures/buildings within its boundary. some of the buildings/structures at the area should be demolished and removed to facilitate the remediation of contaminated soils. soil samples collected near the foundations of several of the buildings contained very elevated levels of pesticides; the foundations may be contaminated. These foundations probably would be undermined during excavation. In addition, three pipe insulation samples collected in and around buildings 17 and 19 ( see Figure 2 in Section 1. 0 of this report) .contained 40%, 20%, and 37%, of asbestos. Proper procedures must be followed in removing and disposing of the asbestos containing pipe insulation before destruction of the southernmost Warehouse. The building debris will be subject to RCRA characteristic hazardous waste testing; if found non-hazardou·s, it may be disposed of in the nearest municipal landfill. If it is found hazardous because of halogenated organic compound (HOC) contamination, a treatability variance for this material may be necessary. The treatment standard required by the LDRs for the HOC contamination present at the Farm chemicals Area· is incineration. This is an inappropriate treatment technology for building debris, thus triggering the need for a treatability variance. In this case, best management practices, such as decontamination or destruction, will be employed which lower contamination to the aiternate treatment levels of the treatability variance. The material will then be suitable for land disposal. I I I I I I I I I I I I I I I I I () p') . -l!!I l!!!!!I .. .. - - - - - - -11!1 -I - - - - - containers consisting of several 55-gallon drums, 1-gallon containers, and 5-gallon buckets are located within several buildings on the area. Any tank/drums/buckets containing pesticides or volatile or semivolatile organic compounds must be decontaminated prior to offsite disposal of the solid waste. The hazardous waste resulting from the decontamination process will be collected, stored and then treated in the thermal desorber unit when it is in full scale operation. A localized, stained area near surficial soil sample 119 contained very elevated levels of several metals. This area must be further characterized and segregated during excavation and thermal desoption to minimize the need for secondary treatment due to metal toxicity in the treatment residuals. Any area found to contain elevated levels of metals should be handled and treated in the same manner. The remedial investigation identified potential or suspected trench areas at the area. Further sampling is ·needed to confirm the presence of buried trenches and then to fully characterize the vertical and lateral extent of contamination. TWin Sites Area Geophysical survey results identified six suspected trench areas. several of these trenches coincide with areas of highly contaminated surficial soil samples. Additional sampling is needed to confirm the presence of buried trenches and then.to fully characterize the vertical and lateral extent of contamination. Fencing around the site is required to provide area control precautions where humans or animals have access to the release. Fairway six Area The remedial investigation geophysical surveys indicate that as many as seven additional trenches may be located at the area. Further sampling is needed to confirm the presence of buried trenches and then to fully _characterize the vertical and lateral extent of contamination. HCJ:ver Area The main area of contamination is located to the northwest of the known area of con~amination, Area B, and may represent an additional area of contamination. Further sampling is needed to delineate this area. Area C was excavated by EPA's Emergency Response Team in 1989. This material is stockpiled onsite and was included in the volume of soil requiring treatment at the Mciver Area. Additional sampling is needed to fully characterize the lateral and vertical extent of residual contamination in Area C. The cleanup or excavation goals for Mciver Area B identified in Table 28 will apply to Area c as well. Any residual contamination exceeding the cleanup goals identified in Table L~ will be excavated and treated in the thermal desorber unit. tJ ;z:.. I I I I I I I I I I I I I I I I I I I I I I I -I I I I I I I I I I I I I I I Route 211 Area Mercury was detected at a very elevated level in one soil sample. Additional sampling is needed to confirm and delineate the extent of this contamination. Areas containing elevated metal contamination must be segregated during handling and treatment to minimize the potential for secondary treatment. 9.3 Contingency for soils Remediation A contingency ROD is appropriate when the performance of an innovative treatment technology appears to be the most promising option, but additional testing _will be needed during remedial design to verify the technology's performance capabilities; in this case, a more "proven approach" is identified as a contingency remedy. Should implementation of the thermal desorption method (Alternative 7) prove ineffective for remediation of soils by not meeting soil treatment levels, Alternative 4, Option 1 would be the Agency's contingency alternative. All aspects of Alternative 4, Option 1 are identical to those of Alternative 7, except that contaminated soils would be remediated using on-site incineration. The criteria that EPA will use to decide to implement the contingency option as opposed to the selected remedy are: 0 0 0 Failure to meet treatability variance levels identified in Table Failure to meet TCLP requirements; or Significant cost increase for thermal desorption which would exceed the cost estimate of on-site incineration. All components of the contingency remedy, Alternative 4, Option 1 are the same as the selected remedy, Alternative 7, with the exception of the treatment technology, incineration. Under Alfernative 4, Option 1, contaminated soil and debris are incinerated on-site in a centralized mobile incinerator. For cost estimation, a mobile rotary kiln incinerator was assumed due to their relative abundance and availability. However, other types of incinerators that provide equal or better performance should be considered when bidding the project. This alternative consists of the following remedial activities: 0 0 0 0 0 0 0 mobilizing the incinerator in a centralized area (Fairway six); excavating pesticide contaminated material from each area of the site; transporting the material to the centralized area; homogenizing and sizing the material for incineration; incinerating the waste; on-site treating of process wastewater or scrubber blowdown sludge by reinjection into the incinerator; a" d demobilization. Prior to incineration, the material will be passed through a shredder and power-screens for sizing. The properly sized contaminants will then be fed into the incineration unit. In order to maintain a readily available feed for the incinerator a "Waste Pile" must be maintained on-site. This waste pile will constitute placement under RCRA. Therefore, it will have to comply with RCRA regulations as specified in CFR 265 Subpart L. Operation of the incineration unit will be in compliance with RCRA regulations (particularly Subpart o, 40 CFR 264), including performance standards. The incinerator and air pollution control unit will be operated so that: 0 0 An operating temperature in the kiln of l,800°F is maintained at all tim1;1s tp ensure thi;lt any volatile and semi-volatile / r 5 .,;< C• .. ~•~•"-tf, IJ.•if< .stvt•"l . .v. J,,v,,, o-.f ,/. f'.., ~,I, ~Al fi,J ~ -/1'1t ci....bo~ t<M..,.0•0J '' 15 /""w4 ~Miit:rJ, an operating temperature in the afterburner of 2,000°F is maintained at all times to oxidize and destroy all remaining organic substances prior to exiting the afterburner and entering the pollution control system; o the incinerator will be capable of achieving a destruction and removal efficiency (DRE) of 99.99% for all designated principal organic hazardous constituents; and o the air pollution control system will achieve performance standards of (l) hydrogen chloride of less than 4 pounds/hour and (2) particulate matter of less than 0.08 grains per dry ft3 in the exhaust gas corrected to a 7 percent oxygen content. Excess quenching and scrubber water, if any, will be reinjected into the incinerator for disposal. Air pollution control wastes or sludges will be reinjected in the incinerator for further treatment. Incinerator ash will be collected, tested.for RCRA characteristics, transported back to the area from where it originated for on-site disposal. Alternative 4, Option 1, like Alternative 7, utilizes a thermal treatment to reme'diate contaminated site soils, but Alternative 4 would involve the use of an on-site incinerator which would destroy the organics present in site soils rather than cause a physical separation of organics from the soils by the thermal desorption technology. The use of thermal treatment of soils will ensure that contaminant levels are permanently reduced, thus eliminating a current source of ground-water contamination. Table 3 I provides a cost summary for Alternative 4, Option 1. 10.0 AMENDMENT TO OPERABLE UNIT TWO RECORD OF DECISION The Fairway six Disposal Site, Operable Unit Two, is located adjacent to the sixth fairway of the Pit Golf Links golf course in Aberdeen, North Carolina. The site is currently an enforcement lead site with EPA providing oversight of site activities. This amendment is being provided in accordance with CERCLA section 117(c) and the National contingency Plan (NCP) 40 C.F.R. section 300.435(C)(2)(i). The amendment will become part of the administrative record file for OU Two and OU One which is located at the site repository. The Fairway Six Disposal site was one of four areas used as a disposal area in Aberdeen, NC. The general area is believed to have served as a trash dump for many years prior to the construction of the golf course. After an investigation by EPA's Emergency Response Section in 1985 and 1986, two removal actions were conducted at the site. The first removal action conducted in 1985 resulted in the excavation and offsite disposal I I 1/\ -11. g tLi ., l I I I I I I I I I I I I I 1, I I I I I I I -I I I I I I I I I I I I I I I TABLE 3 I Cost summary for the contingency Remedy for .Alternative 4-on-site Incineration .................................... ·-·----·-·· ......................................................................... -.... _ .............. _______________ .., ___ _ ,. C..UIT.I.L COSTS: COit (LENUT TOTAL IASl COST "'' "" .................. "'" ························ ......................... ························· QUI.IT\ T1' ''"' "" '•rcW1t•• .uQJIIT (I) ,•rc..,t•• ,.,_,,., (I) ,.,.c.-.t•• -.1(S) ·····································-················ ............ ············ ············ ,. ' WITAL con ITOtS: A. ACCHI 1.-ov-t Wld S.wrlty load IIIP!'ft-U 4,000 " '" 1160,000 "' 1114,000 .,,,, 1144,000 tlnrl,. '., " n,ooo "·"' '" '9,000 .,,,, 17,000 ,_1,. '·"" " "' "'·""' "' 169,000 ... '57,000 ,. AlbHlN 1-.,l 300 " ., 11,000 ,,. 11,000 "' '1,000 C. lu\ld("'J OftlCILttlon 160,1'0 " ., n22,ooo ... 1403,000 .,,,, Sl90,000 (lncludl"'II OKon ....:I dhpou\ In ..._.,le!~\ L.-.dftlt) ,. Soll/I/HIit hc•v1tton 98,73:S " "' 11,195,000 '" 11,422,000 ., .. 11,067,000 ,. Load Trucu ( II. r-£ach) 151'. of bCIIV■tlon 1178,000 "' llOS,000 ... IU,9,000 ,. Tr-partnlon c5 •tln ii 14 per •tit> 6,30.!J Truell -szo-.,2,.000 "" 1151,000 . '"' 111:S,OOO ,. Shred I Sl1• 111urhl 113,543 CT ., Sl41,000 "' '392,000 ... 1124,000 M. ~-,ltt lnchwratton (llSO/ton or CY) 116,743 CT IZ50 129,186,000 '" U5,02l,000 ., .. IZ6,Z67,000 I. Truubtllty Tntlr.o ' L .Su■ 1150,COO 1150,000 "' 1171,000 ... 1141,000 J. A ■h 0hpoul.(AIIIIM 151'. 1.0..Ctlon) 99,232 CT "' 1992,000 ... 11,190,000 .,,,, 1891,000 '· hekfill .. tth c1 • .,, Ht\ 11,511 CT '" S1~,000 "' 1201,000 ... 1166,000 L. Groo.rdw■Ur lklnttorlng lil■ l\1 " .. U,600 143,000 ... 152,000 . '"' 139,000 II. "ydro SHdtng ,. " 11,000 115,000 '" 111,000 .,,,, 114,000 '· llonltOrl"'II S~llna "' " "' 12:S,000 "" 121,000 ., .. 121,000 L ■bornory ._n■lyel ■ .. .. 11,000 112,000 ... 19$,000 ., .. 174,000 hpart Prl'per■tton "' " '" s.e,000 '"' 110,000 ., .. 17,000 o. Motil l tutlon/0.-;,b!\ tut Ion ' L,Su■ 1290,000 1290,000 m ll6J,000 .... 1232,000 ............ . ........... ·•·········· ,.. ESTHUTEO CAPITAL COST .,. 133,3'5,000 ,,. IJ9, 992 , 000 .,. 130,0Zl,OOO ,., UVU Of MEALTN/Uf£TY PROTECTIOII (l A It• 1.2) 101 C/tl S3,3l5,000 lOi 1/C 17,991,000 101'. C/0 U,IXl],000 L4 ~EALTM • unn IICIIITtalNG (I of ,._ 1.2 Wd I.]) '., "'"' ITEIIS 1.2, 1.3, AIIO 1.4 ,., CC:WTIWCENCT (I'. of II• 1.5) ,., IUTITIJTIOIU.L AICI fWCIIIUUIG {I'. of It• 1.5) t.a TOTAL UTIIUTnl CAPITAL COST (Yalu. IIIU'ldlld Off) (S,.. of It-1.5, 1.6, ....:I 1.7) 1.9 ,ucoT o, TOTA\. IAR: COST (I'.) .. .,, '"' '" 17l4, 000 .. 1960,000 .. 1661,000 137,414,000 .,. 14!,950,000 .,. U:S,692,000 S7,4Sl,000 "" H,190,000 ... u,ne,ooo U,741,000 "' 11.:su,000 '"' U,369,000 148,638,000 ,,. 166, 0113, 000 .,. 14:S, 1'99, 000 .,. 136,00l 00.001 ···--·············--···· .. ······---··-----··--······ .................. -................... -... ■-■ ....... ___ ... ___ ••• _.. .. _ • lncludlno 0¥■f"hHd, bur'doln, ■nd profit •• ,■rcent ... O¥■ r th• b9■■ co■t appl lc■blt to lr&llvlG.al Cllllt 1 t• only. I/A • lot -.1 lnot■ All ... 1 ..... r ........ ■ff t ■ tN ,-r•t 11,000'•• ••--■-■••-----------•----m-•■■--•■--■■•--••-■--■■■--■■••■■ II. 0 I II casts: NICll "" -·--··--IA.SE• Percent .. _,,, '" Ptrcent-_,,, '" ............ ····---· I I.A .,,,_I -lrorll'II to■t 1113,000 "' 1)10,000 " 1113,000 ............ ............ Slbtot■l 1113,000 .,. 1130,000 ,,. 1113,000 II.I .t.rn.,,a\ oi:,.r■tlon, ltlllnt-■, ll'llplCtton ,. Jn1pectlon "" 101 '"' "' "" b. oi:,.rulon e, ll■lnt-• " '" " ... " 11,600 '" 11,100 ... Sl,500 ............ ............ Sl,400 .,. "·"' .,. '2,100 11.C TOTAL AJIWAL 0 & II COIT 1115,000 .,. 1113,000 .,. 1115,000 11.0 PUICDIC IIUOII ffflfll lfP.1.11 COIT-113,000 I/A 11S,000 II/._ 112,000 ·························---···--··---··-··-··---··········---········--•---■•-··--------·--• lncluc:tlne 0¥1rt.■-d, tu-dWI, ■nd profit, •• ,,,.cent.,.. _,. th■ ..._ -,. ••• Th ■ co■t "Ill lror m ~ 5 ,._,.. ■t 5l of tM -of It• 1.1·.I., and l, If.I. • ■ot lllf:IPI lcabl■ All 'l■l"'" l"Olftlad •ff ti t1N _, 1100'■; ft •Jw totolo """"""off 10 th• rw■r·eu 11,000'•· ·----··---------------------------111. SOSITIVITT .1..U\.TIIS Allt N!Rll'T IISTI; 111.A snSn1v1n .....,LHts1 1 • ._..,1111ott hc...-nton 2. ~-•II• lnclrwrnton :,. lulii:11,-. o-iltlan 111.I COST YAl:1.1.TIC.1 J\atltlc■tlon tor C-ldlrnlon LW:ffUIMlft It"! -t■ d\erec:torlnln ■..Jor -t It• 11tJor nat tt• Capital Co■U <I) .,., .... •25 to ·5l •25 to ·101 ■:ro to ·1171 J\atlflntlon for 1.,.. ······················································ uw:,rutntl" '" th• ~tlty 9f -u to N OAc..,•UoCI, \.W:■l'Ult"!tlft It"! tlte l;U'otlon and CNt •f lnc\rwntlon. unurt■lt"!tln In co■t of dilaolltlon. O I I Con U/Teorl ,... Nltih low t ... OEKIIPTIC. I•• ············ ............ ............ . .......... . .,., 161,166,000 TOTAl eon 141,631,000 u.t.YAC.,: VAL.. SO TOTAL 141,631,000 166, Gal, 000 " SM,Oll,000 14:S,799,000 " 14:S, 799,000 1115,000 1133,000 111,,000 150,4J9,000 U H H U ............ ............ ............ . .......... . 1115,000 11:S:S,000 lt1',000 SS0,43',000 " 161,166,000 14S,591,000 " S4S,5t7,000 •t.61 PercMt vorhtlon f,,. ,-, • :ss.n ··-··-·----------------·-·--------·-----;..;;;;..~;;.;;;..;..;..;;.;;;.;,. ________ , __ • lncluc:ttne c119lul, .-n.l 0111, and periodic •Jw .,.t_ ,.,.u-CNU, Alt .. ,two r........:I .ff to tM ,..,..., 11,000'•• of 1,420 tons of pesticide contaminated soil and waste. The second removal conducted in 1988 resulted in the excavation of 29,700 tons of pesticide laden soil and waste. This material was stockpiled on site and covered with a top and bottom PVC liner. on June 30, 1989, the EPA Region IV Administrator signed a Record of Decision f~r OU Two. The selec~ed remedy involved on-site incineration of the stockpiled material, confirmatory analysis of incinerator ash and on-site disposal of incinerator ash. Following a CERCLA Section 106 enforcement action in March 1990, a responsible party (Union Carbide corporation) agreed to implement the remedy at OU TWo. A remedial action work plan was prepared in September 1990 for OU TWo. On September 19, 1990, Union carbide Corporation made a request that EPA postpone implementation of OU TWO until a remedy was selected for OU One. The purpose of Union's proposal was to analyze the viability of combining operable units one and two and subsequently utilize one treatment technology. After evaluation of·union Carbide's request, EPA allowed the extension of the implementation schedule for OU TWO for the following reasons: 0 identification of appropriate cleanup goals not explicitly defined in the ROD; and 0 potential cost savings if incineration were the selected remedy for OU One and the operable units were implemented simultaneously; 0 Union Carbi~e's agreement to take measures for the prevention of any environmental harm resulting from ~he continued existence of the stockpiled material at the ·Fairway six Disposal site; and 0 Union Carbide's agreement to participate in negotiations for OU One. Fundamental differences to the ROD for OU TWO are presented below, followed by a discussion of the basis for those differences. original Remedy Incineration of 22,000 cy of contaminated soil. Performance standards identified as elimination of toxic characteristics (using the EP Toxicity Test) and conformity to background levels determined to be 2.3 ppm total pesticides. NC ROD concurrence identified performance standards based on TCLP to drinking water standards. No haz·ardous process residuals result from the incinerator technology. Modified Remedy Thermal desorption of 22,000 cy of contaminated soil. Performarice standards are identified as elimination of toxic characteristics· (using the TCLP test) and conformity to cleanup levels established for the Fairway six Area identified in this ROD for ou one. The waste will be treated to meet RCRA LOR requirements or other RCRA requirements, Best Demonstrated Available Technology (BOAT) Requirements or obtain a Treatability Variance. Hazardous process residuals resulting from the thermal desorption technology will require furtlier treatment which will be vendor specific. I I I I I I I I I I I I I I I I I I I I I -1 I I I I I I I I I I I I I Estimated present worth cost for on-site incineration is is $14.5 million. Estimated present worth cost for on-site ex-situ thermal desorption at the site $4.3 million. Both technologies, incineration and thermal desorption, utilize thermal treatment which applies an elevated temperature as the primary means to change the chemical, physical, or biological character or composition of the hazardous waste. Incineration is a technology which utilizes combustion through oxidation to destroy the organic contaminants. Off gases from the combustion process are emitted into atmosphere following an air pollution control train. Thermal desorption on the other hand only volatilizes the·organic contaminants from the soil and the off-gases are captured for further treatment. Thermal desorption eliminates the off-gas emissions into the acin6sphere. The May 1991 Feasibility study for OU one supports the proposal that remedy implementation should be conducted at one central location. This is substantiated by the economic impracticability of conducting remediation at each individual area. Therefore, this rational also supports combining remediation for OU Two with OU One. The revised remedy cost of $4.3 million involves treatment of contaminated soil and debris utilizing thermal desorption. Considering the new information that has been developed and the changes that have been made to the selected remedy for OU Two, the EPA and NCDEHNR believe that the remedy remains protective of human health and the environment, complies with federal and state requirements that were identified in the ROD as applicable or relevant and appropriate to this remedial action (at the time the original ROD was signed), and is cost-effective. In addition, the amended remedy utilizes permanent solutions and alternative treatment (or resource recovery) technologies to the maximum extent practicable for this operable unit. 11.0 THE STATUTORY DETERMINATIONS Under its legal authorities, EPA's primary responsibility at Superfund sites is to undertake remedial actions that achieve adequate protection of human health and the environment. In addition, CERCLA Section 121 established several other statutory requirements which must be attained by the selected remedy [NCP 40 C.F.R. Sec. 300.430(f)(ii)A-EJ. The statutory requirements specify that the selected remedial action for this site must meet all of the applicable or relevant and appropriate requirements (ARARs) of both Federal and State unless a waiver is justified. The selected remedy also must be cost effective and utilize permanent solutions and alternative treatment technologies or resource recovery technologies to the maximum extent practicable. Finally, the statute includes a preference for remedies that employ treatment that permanently and significantly reduce the volume, toxicity, or mobility of hazardous wastes as their principal element. The following sections discuss how the selected remedy meets these statutory requirements. ll.l Protection of Human Health and the Environment The selected remedy and contingency remedy protects human health and the environment through thermal treatment of pesticide contaminants in soil. The contaminants will be permanently removed from the soil by thermal desorption or incineration. The volatilized organic contaminants resulting from thermal desorption will be captured and permanently destroyed through secondary treatment. Incineration of the contaminated soil would destroy the organics by combustion and would not require secondary treatment. Treated soils must meet RCRA LOR standards (treatability variance levels), pass RCRA hazardous characteristic testing and meet RCRA delisting requirements. Thus, implementation of either alternative, thermal desorption or incineration would provide sufficient protection to human health and the environment. · Thermal treatment of pesticide contaminated soil will eliminate the threat of exposure to the contaminants from direct contact with or ingestion of contaminated soil. ·The current risks associated with these exposure pathways at each Area falls outside of EPA's protective risk range. Excavation of contaminated soil to cleanup goals established at 10-6 health based levels will provide adequate·protection to human health and the environment. By excavating and treating the contaminated soil to stringent RCRA standards, the selected remedy will further provide protection to the underlying aquifer which is the sole source of drinking water for the local community. 11.2 Compliance with Applicable or Re'ievant and Appropriate ~eguirements The selected alternative, as well as the contingency remedy, will be designed to meet all applicable or relevant and appropriate requirements (ARARs) of Federal and state laws. The ARARs to be attained by the thermal desorption technology are presented below. Action-Specific ARARs: RCRA Manifest Requirements RCRA storage Requirements RCRA Delisting Requirements RCRA Land Disposal Restriction Requirements Chemical-specific ARARs: None Location-specific ARARs: None 11.3 Cost-Effectiveness Alte.rnative 7 affords a high degree of effectiveness by providing protection from direct contact with pesticide contaminated soils. Thermal treatment of contaminated soils will also provide adequate protection to the underlying sole source aquifer by permanently removing the source of contamination. Alternative 7, the least costly alternative, is the most cost-effective alternative which provides the greatest protection to human health and the environment. I ' ' I I I I I I I I .:-.. , I ..::::~ I I I I I I/. I I I I I I I -I I I I I I I I I I I , 11.4 Utilization of Permanent Solutions and Alternative Treatment Technologies or Resource Recovery Technologies to the Maximum Extent Practicable u.s. EPA and the State of North Carolina believe the selected remedy, thermal desorption represents the maximum extent to which permanent solutions and treatment technologies can be utilized in a cost-effective manner for a source control remedy_of contaminated soils at the A1?erdeen Pesticide Dumps Site. of those alternatives that are protective of human health and the environment and comply with ARARs, the State of North Carolina and EPA have determined that this selected remedy provides the best balance of trade-offs in terms of long-term effectiveness and permanence, reduction in toxicity, mobility, or volume achieved through treatment, short-term effectiveness; .implementability, and co~t~- The selection of treatment of the contaminated soil is consistent with program expectations that indicate that highly toxic and mobile waste are a priority for treatment and often necessary to ensure the long-term effectiveness of a remedy. Options evaluated in detail which do not require treatment, such as environmental monitoring and capping, obviously do not meet the statutory requirement for the utilization of permanent solutions. Alternative 7 meets this statutory requirement by providing a permanent solution while utilizing an alternative treatment technology. In the event the contingency remedy will be employed, on-site incineration will also meet the statutory requirement by providing a permanent solution to site contamination which utilizes a treatment technology to the maximum extent practicable. 11.5 Preference for Treatment as a Principal Element By treating the pesticide contaminated soils in a thermal desorption unit, and stabilization/solidification of any residuals with metal- contamination, which may remain hazardous following treatment, the selected remedy addresses one of the principal threats posed by the Site through use of treatment technologies. Therefore, the statutory preference for remedies that employ treatment as a principal element is satisfied. This statutory requirement would also be satisfied by the use of the contingency remedy, on-site incineration.